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Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
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1

MEMORANDUM GY  

Office of Legacy Management (LM)

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2

COLOMBIA GUYANA VENEZUELA FR.  

E-Print Network [OSTI]

PERU CHILE ARGENTINA PARAGUAY BOLIVIA COLOMBIA GUYANA SURINAME URUGUAY VENEZUELA FR. GUIANA POPULATION DENSITY, 2000 Population density measures the number of persons per square kilometer of land area the population grids and thus may appear coarse. Lambert Azimuthal Equal Area Projection ´ 0 500 1,000 km

Columbia University

3

Preparing Guyana's REDD+ Participation: Developing Capacities...  

Open Energy Info (EERE)

AgencyCompany Organization Guyana Forestry Commission, The Government of Norway Sector Land Focus Area Forestry Topics Implementation, Policiesdeployment programs,...

4

Guyana-Caribbean Community (CARICOM) Sustainable Energy Roadmap...  

Open Energy Info (EERE)

Guyana-Caribbean Community (CARICOM) Sustainable Energy Roadmap and Strategy AgencyCompany Organization Inter-American Development Bank, World Watch Institute (WWI) Sector...

5

NEGATION IN GUIANESE LOKONO/ARAWAK Guianese Lokono/Arawak is spoken in the lowlands of the Guianas, Guyana,  

E-Print Network [OSTI]

of the Guianas, Guyana, Suriname, the French Overseas department of Guiana, and Venezuelan Guayana. Some speakers

Boyer, Edmond

6

Loanwords in Kali'na, a Cariban language of French Guyana Odile Renault-Lescure  

E-Print Network [OSTI]

. It is constituted by the five Guianas: Venezuelan Guiana, (formerly British) Guyana, Suriname, French Guiana distributed in these countries. 11.141 live in Venezuela, 3000 in Guyana (Forte 2000), 3000 in Suriname (Boven% in Suriname; there is no precise data for French Guiana, but the rate is high). The Kali'na people speak

Boyer, Edmond

7

CHECKLIST OF THE PLANTS OF THE GUIANAS (Guyana, Surinam, French Guiana)  

E-Print Network [OSTI]

CHECKLIST OF THE PLANTS OF THE GUIANAS (Guyana, Surinam, French Guiana) 2nd Edition J. Boggan, V;#12;CHECKLIST OF THE PLANTS OF THE GUIANAS (Guyana, Surinam, French Guiana) 2nd Edition J. Boggan, V. Funk, C, Surinam, French Guiana) 2nd Edition 1st Edition: December 1992 2nd Edition: February 1997 Published

Mathis, Wayne N.

8

Guyana's Low Carbon Development Strategy | Open Energy Information  

Open Energy Info (EERE)

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9

GeoloGy (Geol) Robinson Foundation  

E-Print Network [OSTI]

182 GeoloGy (Geol) Robinson Foundation PROFESSOR HARBoR ASSOCIATE PROFESSORS KNAPP, CONNORS ASSISTANT PROFESSORS GREER, RAHL MAJORS BACHELOR OF SCIENCE Amajor in geology leading to a Bachelor of Science degree consists of 50 credits as follows: 1. Geology160,185,211,311,330,350,andacom- prehensive

Dresden, Gregory

10

2008 Building Energy2008 Building Energyg gy Efficiency Standards  

E-Print Network [OSTI]

Buildings p , p g , Luminaire Power, etc. for Nonresidential Buildings 4 #12;What is New for 2008? R d l B ld What is New for 2008? R d l B ldResidential BuildingsResidential Buildings Mandatory Measures2008 Building Energy2008 Building Energyg gy Efficiency Standards g gy Efficiency Standardsfficie

11

2008 Residential2008 Residential Energy Plan ReviewEnergy Plan Reviewe gy la eviewe gy la eview  

E-Print Network [OSTI]

2008 Residential2008 Residential Energy Plan ReviewEnergy Plan Reviewe gy la eviewe gy la eview #12;2008 Residential Energy Plan2008 Residential Energy Plan Review ChecklistReview Checklist Simplification ChecklistsOther Available Checklists 2005 and 2008 Residential Energy Documentation2005 and 2008 Residential

12

Guyana-ClimateWorks Low Carbon Growth Planning Support | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Power BasicsGermany: EnergyPower Finance Jump to: navigation, searchGuyana's

13

First records of 10 bat species in Guyana and comments on diversity of bats in Iwokrama Forest  

E-Print Network [OSTI]

.g., Eisenberg, 1989) from mammals reported in Venezuela (e.g ., Handley, 1976) and Suriname (e.g., Husson, 1978). Two recent publications (Parker et al., 1993; Smith and Kerry, 1996) reported on separate, small single-site collections from Guyana.... In the Guianan subregion, this species was known by one specimen from Venezuela (McCarthy and Ochoa, 1991), two from Suriname (Husson, 1962; Williams et a/., 1983), and one from French Guiana (Simmons and Handley, 1998). Previously, the genus was considered...

Lim, Burton K.; Engstrom, Mark D.; Timm, Robert M.; Anderson, Robert P.; Watson, L. Cynthia

1999-12-01T23:59:59.000Z

14

4Li  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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15

5Li  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICS H.CarbonMarchTHE ADVANCEDProducingLi

16

9Li  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICSHe β- DecayBe General Tables8 2BBBeHeHeLi

17

10Li  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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18

07Li  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNG IHDR€ÍSolar Energy41 (Dollars andUsing Artificial Barriers to NewJulyLi

19

Figure 1:Energy Consumption in USg gy p 1E Roberts, Energy in US  

E-Print Network [OSTI]

Figure 1:Energy Consumption in USg gy p 2008 1E Roberts, Energy in US Source: www.eia.gov #12 National Academy of Science 2009 #12;Figure 8: US Production of Primary Energy by Fuel 8E Roberts, Energy Consumption and Production 13E Roberts, Energy in US EIA Annual Energy Outlook 2012 #12;Figure 14: Oil Price

Sutton, Michael

20

Shell-shocked diffusion model for the light curve of SN2006gy  

E-Print Network [OSTI]

We explore a simple model for the high luminosity of SN 2006gy involving photon diffusion of shock-deposited thermal energy. The distinguishing property of the model is that the large ``stellar'' radius of 160 AU required to prevent adiabatic losses is not the true stellar radius, but rather, the radius of an opaque, unbound circumstellar envelope, created when 10 Msun was ejected in the decade before the supernova in an eruption analogous to that of eta Carinae. The supernova light is produced primarily by diffusion of thermal energy following the passage of the blast wave through this shell. This model differs from traditional models of supernova debris interacting with external CSM in that here the shell is optically thick and the escape of radiation is delayed. We show that any model attempting to account for SN2006gy's huge luminosity with radiation emitted by ongoing CSM interaction fails for the following basic reason: the CSM density required to achieve the observed luminosity makes the same circumstellar envelope opaque, forcing a thermal diffusion solution. In our model, the weaker CSM interaction giving rise to SN2006gy's characteristic Type IIn spectrum and soft X-rays is not linked to the power source of the visual continuum; instead, it arises after the blast wave breaks free of the opaque shell into the surrounding wind. While a simple diffusion model can explain the gross properties of the early light curve of SN2006gy, it predicts that the light curve must plummet rapidly at late-times, unless an additional power source is present.

Nathan Smith; Richard McCray

2007-10-18T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Dan Li: Curriculum Vitae  

E-Print Network [OSTI]

Aug 27, 2014 ... Curriculum Vitae. Dan Li. Contact Information. Department of Mathematics,. Purdue University. 150 N. University Street,. West Lafayette, IN...

Dan Li

2014-08-27T23:59:59.000Z

22

Neutron spectroscopic factors of 7Li and astrophysical 6Li(n,g)7Li reaction rates  

E-Print Network [OSTI]

Angular distributions of the 7Li(6Li,6Li)7Li elastic scattering and the 7Li(6Li,7Li_{g.s.})6Li, 7Li(6Li,7Li*_{0.48})6Li transfer reactions at Ec.m. = 23.7 MeV were measured with the Q3D magnetic spectrograph. The optical potential of 6Li+7Li was obtained by fitting the elastic scattering differential cross sections. Based on the distorted wave Born approximation (DWBA) analysis, spectroscopic factors of 7Li=6Li+n were determined to be 0.73 +- 0.05 and 0.90 +- 0.09 for the ground and first exited states in 7Li, respectively. Using the spectroscopic factors, the cross sections of the 6Li(n,g)7Li direct neutron capture reactions and the astrophysical 6Li(n,g)7Li reaction rates were derived.

Jun Su; Zhihong Li; Bing Guo; Xixiang Bai; Zhichang Li; Jiancheng Liu; Youbao Wang; Gang Lian; Sheng Zeng; Baoxiang Wang; Shengquan Yan; Yunju Li; Ertao Li; Qiwen Fan; Weiping Liu

2010-01-25T23:59:59.000Z

23

GyPSuM: A Detailed Tomographic Model of Mantle Density and Seismic Wave Speeds  

SciTech Connect (OSTI)

GyPSuM is a tomographic model fo mantle seismic shear wave (S) speeds, compressional wave (P) speeds and detailed density anomalies that drive mantle flow. the model is developed through simultaneous inversion of seismic body wave travel times (P and S) and geodynamic observations while considering realistic mineral physics parameters linking the relative behavior of mantle properties (wave speeds and density). Geodynamic observations include the (up to degree 16) global free-air gravity field, divergence of the tectonic plates, dynamic topography of the free surface, and the flow-induced excess ellipticity of the core-mantle boundary. GyPSuM is built with the philosophy that heterogeneity that most closely resembles thermal variations is the simplest possible solution. Models of the density field from Earth's free oscillations have provided great insight into the density configuration of the mantle; but are limited to very long-wavelength solutions. Alternatively, simply scaling higher resolution seismic images to density anomalies generates density fields that do not satisfy geodynamic observations. The current study provides detailed density structures in the mantle while directly satisfying geodynamic observations through a joint seismic-geodynamic inversion process. Notable density field observations include high-density piles at the base of the superplume structures, supporting the fundamental results of past normal mode studies. However, these features are more localized and lower amplitude than past studies would suggest. When we consider all seismic anomalies in GyPSuM, we find that P and S-wave speeds are strongly correlated throughout the mantle. However, correlations between the high-velocity S zones in the deep mantle ({approx} 2000 km depth) and corresponding P-wave anomalies are very low suggesting a systematic divergence from simplified thermal effects in ancient subducted slab anomalies. Nevertheless, they argue that temperature variations are the primary cause of P-wave, S-wave, and density anomalies in the mantle.

Simmons, N A; Forte, A M; Boschi, L; Grand, S P

2010-03-30T23:59:59.000Z

24

Thermal Stability of LiPF6 Salt and Li-ion Battery Electrolytes Containing LiPF6  

E-Print Network [OSTI]

of LiPF 6 Salt and Li-ion Battery Electrolytes ContainingLiPF 6 in prototypical Li-ion battery solvents was studied6 and the prototypical Li- ion battery solvents EC, PC, DMC

Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

2006-01-01T23:59:59.000Z

25

On LiF:Mg,Cu,P and LiF:Mg,Ti phosphors high & ultra-high dose features  

E-Print Network [OSTI]

LiF:Mg,Ti and LiF:Mg,Cu,P are well known thermoluminescence (TL) dosimetry materials since many years. A few years ago their properties seemed well known and it was widely believed that they are not suitable for the measurement of doses above the saturation level of the TL signal, which for both materials occur at about 1 kGy. The high-dose high-temperature TL emission of LiF:Mg,Cu,P observed at the IFJ in 2006, which above 30 kGy takes the form of the so-called TL peak B, opened the way to use this material for measuring the dose in the high and ultra-high range, in particular for the monitoring of ionizing radiation around the essential electronic elements of high-energy accelerators, also fission and fusion facilities, as well as for emergency dosimetry. This discovery initiated studies of high and ultra-high dose characteristics of both of these phosphors, which turned out to be significantly different in many aspects. These studies not only strive to refine the method for measuring high doses based on th...

Obryk, Barbara; de Barros, Vinicius S; Guzzo, Pedro L; Bilski, Pawe?

2013-01-01T23:59:59.000Z

26

eGY-Africa: Addressing the Digital Divide for Science in Africa  

SciTech Connect (OSTI)

Adoption of information and communication technologies and access to the Internet is expanding in Africa, but because of the rapid growth elsewhere, a Digital Divide between Africa and the rest of the world exists, and the gap is growing. In many sub-Saharan African countries, education and research sector suffers some of the worst deficiencies in access to the Internet, despite progress in development of NRENs - National Research and Education (cyber) Networks. By contrast, it is widely acknowledged in policy statements from the African Union, the UN, and others that strength in this very sector provides the key to meeting and sustaining Millennium Development Goals. Developed countries with effective cyber-capabilities proclaim the benefits to rich and poor alike arising from the Information Revolution. This is but a dream for many scientists in African institutions. As the world of science becomes increasingly Internet-dependent, so they become increasingly isolated. eGY-Africa is a bottom-up initiative by African scientists and their collaborators to try to reduce this Digital Divide by a campaign of advocacy for better institutional facilities. Four approaches are being taken. The present status of Internet services, problems, and plans are being mapped via a combination of direct measurement of Internet performance (the PingER Project) and a questionnaire-based survey. Information is being gathered on policy statements and initiatives aimed at reducing the Digital Divide, which can be used for arguing the case for better Internet facilities. Groups of concerned scientists are being formed at the national, regional levels in Africa, building on existing networks as much as possible. Opinion in the international science community is being mobilized. Finally, and perhaps most important of all, eGY-Africa is seeking to engage with the many other programs, initiatives, and bodies that share the goal of reducing the Digital Divide - either as a direct policy objective, or indirectly as a means to an end, such as the development of an indigenous capability in science and technology for national development. The expectation is that informed opinion from the scientific community at the institutional, national, and international levels can be used to influence the decision makers and donors who are in a position to deliver better Internet capabilities.

Barton, C.E.; /Australian Natl. U., Canberra; Amory-Mazaudier, C.; /Lab.Phys.Plasmas, Saint Maur des Fosses; Barry, B.; /Assoc.African Univ., Accra; Chukwuma; /Olabisi Onabanjo U.; Cottrell, R.L.; /SLAC; Kalim, U.; /Pakistan Natl. U.; Mebrahtu, A.; /Mekelle U.; Petitdidier, M.; /Lab. d'Atmos., Velizy; Rabiu, B.; /Federal Tech. U., Akure; Reeves, C.; /Earthworks bv, Delft; ,

2010-06-16T23:59:59.000Z

27

Guyana Francesa 1. Introduction  

E-Print Network [OSTI]

dense et le reste de mangroves, savanes, forêts secondaires et cultures sur la côte, entre le Surinam Maroni . Là, un bac permet de passer le fleuve Maroni, et de gagner Paramaribo, capitale du Surinam. A l particulièrement soutenue par l'immigration en provenance du Surinam. 3. Données politiques et régionales et

Paris-Sud XI, Université de

28

5Li General Tables  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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29

5Li.PDF  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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30

9Li General Tables  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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31

9Li.PDF  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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32

10Li General Tables  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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33

Set To Save *and* AB 811Set To Save and AB 811 Energy Independence Program (EIP)gy p g ( )  

E-Print Network [OSTI]

; download documents. 5) Strongly suggest a energy survey/audit. 6) Proactively call/e-mail to updateSet To Save *and* AB 811Set To Save and AB 811 Energy Independence Program (EIP)gy p g ( ) Lessons, Office of Energy ManagementPatrick Conlon, Director, Office of Energy Management 73-710 Fred Waring Drive

Kammen, Daniel M.

34

M(.)Ll:CULAR PluAuculAcon.c)Gy, 6, 391-401 Ligand Interaction with Hemoprotein P-450  

E-Print Network [OSTI]

M(.)Ll:CULAR PluAuculAcon.c)Gy, 6, 391-401 391 Ligand Interaction with Hemoprotein P-450 Ill of High- and Low-Spin P-450 C. H. E. ,JEFCOATE, R. L. CALABRESE, AN!) J. L. GAYLOR Section of Biochemistry to octylaminie, of tine absolute amounts of inigh- arid loss--spins formsss of huemoproteini P-450 of rabbit

Calabrese, Ronald

35

California Reach StandardsCalifornia Reach Standards for Building Energy Efficiencyfor Building Energy Efficiencyo u d g e gy c e cyo u d g e gy c e cy  

E-Print Network [OSTI]

Fraction or 95% water heater efficiencyor 95% water heater efficiency Tier I · 95% of Energy Budget ­ Tier td Li hti· High Efficacy Outdoor Lighting · Service Water Heating in Large Restaurants ­ 15% Solar, Part 11 - Residential Changes since May 2012 Proposal · Removal of Maximum Hot Water Pipe Volume from

36

Thermoluminescence (TL) Analysis and Fading Studies of Naturally Occurring Salt Irradiated by 500 mGy Gamma Rays  

SciTech Connect (OSTI)

The aim of the present study was to investigate the potential of the naturally occurring salt for the dosimetry purposes, using TL. The fine powder samples (20 mg) were irradiated by {gamma}- rays from 500 mGy to 2500 mGy by using Theratron-780C Cobalt-60 source, however, this paper discusses about 500 mGy only. The TL glow curve peak parameters were studied by using Chen's peak shape equation. TL glow curves were compared with fitted curves using glow curve deconvolution (GCD) method by using Kitis expression. The kinetic parameter values (E, b and s) so calculated, are in good agreement with those available in literature. The calculated energy values were also verified by using various heating rate (VHR) method. {chi}{sup 2} test and figure of merit (FOM) calculation was done to accept the goodness of fit between the curves. Fading studies of the sample showed a good fitting between the curves. The analysis suggests that natural salt should be considered for dosimetry purposes.

Tiwari, Ramesh Chandra; Pau, Kham Suan [Department of Physics, Mizoram University: Tanhril Campus, Aizawl-796004, Mizoram (India)

2011-10-20T23:59:59.000Z

37

Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Milling of the LiNH2 + LiH Hydrogen Storage System. Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System. Abstract: Ball milling of the LiNH2 + LiH storage system was...

38

7Li General Tables  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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39

7Li.PDF  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICSHe β- Decay Evaluated7-ID ThirdBBeLi General

40

8Li General Tables  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICSHe β- DecayBe General Tables Theβ--DecayLi

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

8Li.PDF  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICSHe β- DecayBe General Tables Theβ--DecayLi

42

Jun Li | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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43

C LI CI  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntown Site -MiamiYVE r. aw wL2--\Burris;zJy,LI

44

Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries  

E-Print Network [OSTI]

12 for High Rate Li-ion Batteries A. Jaiswal 1 , C. R. Hornenext generation of Li-ion batteries for consumer electronics

Jaiswal, A.

2010-01-01T23:59:59.000Z

45

Bovine babesiosis in Guyana: a comparison of the indirect fluorescent antibody (IFA) and complement-fixation (CF) tests in determining the prevalence of Babesia bigemina and Babesia bovis infections  

E-Print Network [OSTI]

BOVINE BABESIOSIS IN GUYANA: A COMPARISON OF THE INDIREC T FLUORESCENT ANTIBODY (IFA) AND COMPLEMENT-FIXATION (CF) TESTS IN DETERMINING THE PREVALENCF. OF BABESIA BIGEMINA AND BABESIA BOVIS INFECTIONS A Thesis by LENNOX MORTIMER APPLEWHAITE... FLUORESCENT ANTIBODY (IFA) AND COMPLE1YIENT-FIXATION (CF ) TES TS IN DETERMINING THE PREVAI ENCE OF BABES IA B1GEMINA AND BABESIA BOVIS INFECTIONS A Thesis by LENNOX MORTIMER APPLErJHAITE Appro red as to sty1e and content by: (Chairman of Committee...

Applewhaite, Lennox Mortimer

2012-06-07T23:59:59.000Z

46

Identity of Passive Film Formed on Aluminum in Li-ion Battery Electrolytes with LiPF6  

E-Print Network [OSTI]

Film on Aluminum in Li-ion Battery Electrolytes with LiPFFormed on Aluminum in Li-ion Battery Electrolytes with LiPFbattery charging. From the prospective of maintaining a functioning cathode in Li-ion

Zhang, Xueyuan; Devine, T.M.

2008-01-01T23:59:59.000Z

47

Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI  

SciTech Connect (OSTI)

Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA- and TDI- anions coordinate Li+ cations. To explore this in-depth, crystal structures are reported here for two solvates with LiDCTA: (G2)1:LiDCTA and (G1)1:LiDCTA with diglyme and monoglyme, respectively, and seven solvates with LiTDI: (G1)2:LiTDI, (G2)2:LiTDI, (G3)1:LiTDI, (THF)1:LiTDI, (EC)1:LiTDI, (PC)1:LiTDI and (DMC)1/2:LiTDI with monoglyme, diglyme, triglyme, tetrahydrofuran, ethylene carbonate, propylene carbonate and dimethyl carbonate, respectively. These latter solvate structures are compared with the previously reported acetonitrile (AN)2:LiTDI structure. The solvates indicate that the LiTDI salt is much less associated than the LiDCTA salt and that the ions in LiTDI, when aggregated in solvates, have a very similar TDI-...Li+ cation mode of coordination through both the anion ring and cyano nitrogen atoms. Such coordination facilitates the formation of polymeric ion aggregates, instead of dimers. Insight into such ion speciation is instrumental for understanding the electrolyte properties of aprotic solvent mixtures with these salts.

McOwen, Dennis W.; Delp, Samuel A.; Paillard, Elie; Herriot, Cristelle; Han, Sang D.; Boyle, Paul D.; Sommer, Roger D.; Henderson, Wesley A.

2014-04-17T23:59:59.000Z

48

Making Li-air batteries rechargeable: material challenges. |...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Li-air batteries rechargeable: material challenges. Making Li-air batteries rechargeable: material challenges. Abstract: A Li-air battery could potentially provide three to five...

49

Development of Li+ alumino-silicate ion source  

E-Print Network [OSTI]

yellow line) from a ?-Spodumene Li test source, operated atexceeding 1200 0 C. ?-spodumene and ? eucryptite Li sourcesdeveloping high quality ?-spodumene and ?-eucryptite Li ion

Roy, P.K.

2009-01-01T23:59:59.000Z

50

Mixed Salts of LiTFSI and LiBOB for Stable LiFePO4-Based Batteries...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in LiTFSI-based electrolytes effectively prevents the severe corrosion to Al current collectors that often is observed in LiTFSI-based electrolytes, which have high thermal...

51

Improved Positive Electrode Materials for Li-ion Batteries  

E-Print Network [OSTI]

of the assembled Li-ion battery, such as the operating1-4: Schematic of a Li-ion battery. Li + ions are shuttledprocessing of active Li-ion battery materials. Various

Conry, Thomas Edward

2012-01-01T23:59:59.000Z

52

Capacity Fade Studies of LiCoO2 Based Li-ion Cells Cycled at  

E-Print Network [OSTI]

in capacity of commercially available Sony 18650 Cells cycled at different temperatures. Perform rate of a Sony 18650 Li-ion cell Cathode (positive electrode) - LiCoO2. Anode (negative electrode) - MCMB. Cell capacity ­ 1.8 Ah #12;Characteristics of a Sony 18650 Li-ion cell Characteristics Positive LiCoO2 Negative

Popov, Branko N.

53

Interactions and dynamics in Li+Li2 ultracold collisions Marko T. Cvitas,a  

E-Print Network [OSTI]

Interactions and dynamics in Li+Li2 ultracold collisions Marko T. Cvitas,a Pavel Soldn electronic state 4 A of lithium trimer is developed and used to study spin-polarized Li+Li2 collisions There is great interest in the properties of molecules formed in laser-cooled atomic gases by processes

Honvault, Pascal

54

Facile synthesis of Li2Spolypyrrole composite structures for high-performance Li2S cathodes  

E-Print Network [OSTI]

Facile synthesis of Li2Spolypyrrole composite structures for high-performance Li2S cathodes Zhi demon- strate facile, in situ synthesis of Li2Spolypyrrole composites for use as high-performance Li2S polysulfides during cycling. Poly- pyrrole, being a conducting polymer, also helps to facilitate elec- tronic

Cui, Yi

55

Li ion migration in Li3PO4 electrolytes: Effects of O vacancies and N substitutions  

E-Print Network [OSTI]

Li ion migration in Li3PO4 electrolytes: Effects of O vacancies and N substitutions Y. A. Dua and N structures of isolated defects associated with extrinsic Li ion vacancies and interstitials. In particular the combination of an O vacancy and a N substitution, stabilizing a Li ion vacancy. We also studied the effects

Holzwarth, Natalie

56

Multidose Stereotactic Radiosurgery (9 Gy 3) of the Postoperative Resection Cavity for Treatment of Large Brain Metastases  

SciTech Connect (OSTI)

Purpose: To evaluate the clinical outcomes with linear accelerator-based multidose stereotactic radiosurgery (SRS) to large postoperative resection cavities in patients with large brain metastases. Methods and Materials: Between March 2005 to May 2012, 101 patients with a single brain metastasis were treated with surgery and multidose SRS (9 Gy 3) for large resection cavities (>3 cm). The target volume was the resection cavity with the inclusion of a 2-mm margin. The median cavity volume was 17.5 cm{sup 3} (range, 12.6-35.7 cm{sup 3}). The primary endpoint was local control. Secondary endpoints were survival and distant failure rates, cause of death, performance measurements, and toxicity of treatment. Results: With a median follow-up of 16 months (range, 6-44 months), the 1-year and 2-year actuarial survival rates were 69% and 34%, respectively. The 1-year and 2-year local control rates were 93% and 84%, with respective incidences of new distant brain metastases of 50% and 66%. Local control was similar for radiosensitive (non-small cell lung cancer and breast cancer) and radioresistant (melanoma and renal cell cancer) brain metastases. On multivariate Cox analysis stable extracranial disease, breast cancer histology, and Karnofsky performance status >70 were associated with significant survival benefit. Brain radionecrosis occurred in 9 patients (9%), being symptomatic in 5 patients (5%). Conclusions: Adjuvant multidose SRS to resection cavity represents an effective treatment option that achieves excellent local control and defers the use of whole-brain radiation therapy in selected patients with large brain metastases.

Minniti, Giuseppe, E-mail: gminniti@ospedalesantandrea.it [Radiation Oncology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy) [Radiation Oncology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy); Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy); Esposito, Vincenzo [Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy)] [Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy); Clarke, Enrico; Scaringi, Claudia [Radiation Oncology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy)] [Radiation Oncology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy); Lanzetta, Gaetano [Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy)] [Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy); Salvati, Maurizio [Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy) [Department of Neurological Sciences, Scientific Institute IRCCS Neuromed, Pozzilli (Italy); Neurosurgery Unit, Umberto I Hospital, University Sapienza, Rome (Italy); Raco, Antonino [Neurosurgery Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy)] [Neurosurgery Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy); Bozzao, Alessandro [Neuroradiology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy)] [Neuroradiology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy); Maurizi Enrici, Riccardo [Radiation Oncology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy)] [Radiation Oncology Unit, Sant' Andrea Hospital, University Sapienza, Rome (Italy)

2013-07-15T23:59:59.000Z

57

Thermal Stability of LiPF6 Salt and Li-ion Battery ElectrolytesContaining LiPF6  

SciTech Connect (OSTI)

The thermal stability of the neat LiPF6 salt and of 1 molal solutions of LiPF6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line FTIR. Pure LiPF6 salt is thermally stable up to 380 K in a dry inert atmosphere, and its decomposition path is a simple dissociation producing LiF as solid and PF5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF6 and water vapor to form POF3 and HF. No new products were observed in 1 molal solutions of LiPF6 in EC, DMC and EMC by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 358 K for 300 420 hrs. did not produce any significant quantity of new products as well. In particular, noalkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

2006-03-08T23:59:59.000Z

58

Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Growth Process of Li2S2Li2S in Lithium-Sulfur Batteries. Abstract: Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially...

59

Coulomb dissociation of [sup 11]Li  

SciTech Connect (OSTI)

Kinematically complete measurements for Coulomb dissociation of [sup 11]Li into [sup 9]Li+2[ital n] were made at 28 MeV/nucleon. The [ital n]-[ital n] correlation function suggests a large source size for the two-neutron emission. The electromagnetic excitation spectrum of [sup 11]Li has a peak, as anticipated in low-energy dipole resonance models, but a large post-breakup Coulomb acceleration of the [sup 9]Li fragment is observed, indicating a very short lifetime of the excited state and favoring direct breakup as the dissociation mechanism.

Ieki, K.; Sackett, D.; Galonsky, A.; Bertulani, C.A.; Kruse, J.J.; Lynch, W.G.; Morrissey, D.J.; Orr, N.A.; Schulz, H.; Sherrill, B.M.; Sustich, A.; Winger, J.A. (National Superconducting Cyclotron Laboratory and Department of Physics, Michigan State Unversity, East Lansing, Michigan 48824 (United States)); Deak, F.; Horvath, A.; Kiss, A. (Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7 H-1088 Budapest 8 (Hungary)); Seres, Z. (KFKI Research Institute for Particle and Nuclear Physics of the Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary)); Kolata, J.J. (Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)); Warner, R.E. (Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States)); Humphrey, D.L. (Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States))

1993-02-08T23:59:59.000Z

60

Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries  

SciTech Connect (OSTI)

The electrochemical performances of nanoscale LiFePO4 and Li4Ti5O12 materials are described in this communication. The nanomaterials were synthesized by pyrolysis of an aerosol precursor. Both compositions required moderate heat-treatment to become electrochemically active. LiFePO4 nanoparticles were coated with a uniform, 2-4 nm thick carbon-coating using an organic precursor in the heat treatment step and showed high tap density of 1.24 g/cm3, in spite of 50-100 nm particle size and 2.9 wtpercent carbon content. Li4Ti5O12 nanoparticles were between 50-200 nm in size and showed tap density of 0.8 g/cm3. The nanomaterials were tested both in half cell configurations against Li-metal and also in LiFePO4/Li4Ti5O12 full cells. Nano-LiFePO4 showed high discharge rate capability with values of 150 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 charges. Nano-Li4Ti5O12 also showed high charge capability with values of 148 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 discharges; the discharge (lithiation) capability was comparatively slower. LiFePO4/Li4Ti5O12 full cells deliver charge/discharge capacity values of 150 and 122 mAh/g at C/5 and 5C, respectively.

Jaiswal, A.; Horne, C.R.; Chang, O.; Zhang, W.; Kong, W.; Wang, E.; Chern, T.; Doeff, M. M.

2009-08-04T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries  

E-Print Network [OSTI]

1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

62

Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications  

E-Print Network [OSTI]

Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed : 10.1149/2.064209jes #12;Over the past 15 years, Li-ion batteries have received much attention

Paris-Sud XI, Université de

63

Effects of O vacancies and N or Si substitutions on Li+ migration in Li3PO4 electrolytes  

E-Print Network [OSTI]

Effects of O vacancies and N or Si substitutions on Li+ migration in Li3PO4 electrolytes from first constructed realistic models of various types of isolated defects in crystalline Li3PO4 involving O vacancies on the production and migration of mobile Li ions. We find that mobile Li-ion vacancies are stabilized by removing

Holzwarth, Natalie

64

Low Dose Radiation Response Curves, Networks and Pathways in Human Lymphoblastoid Cells Exposed from 1 to 10 cGy of Acute Gamma Radiation  

SciTech Connect (OSTI)

We investigated the low dose dependency of the transcriptional response of human cells to characterize the shape and biological functions associated with the dose response curve and to identify common and conserved functions of low dose expressed genes across cells and tissues. Human lymphoblastoid (HL) cells from two unrelated individuals were exposed to graded doses of radiation spanning the range of 1-10 cGy were analyzed by transcriptome profiling, qPCR and bioinformatics, in comparison to sham irradiated samples. A set of {approx}80 genes showed consistent responses in both cell lines; these genes were associated with homeostasis mechanisms (e.g., membrane signaling, molecule transport), subcellular locations (e.g., Golgi, and endoplasmic reticulum), and involved diverse signal transduction pathways. The majority of radiation-modulated genes had plateau-like responses across 1-10 cGy, some with suggestive evidence that transcription was modulated at doses below 1 cGy. MYC, FOS and TP53 were the major network nodes of the low-dose response in HL cells. Comparison our low dose expression findings in HL cells with those of prior studies in mouse brain after whole body exposure, in human keratinocyte cultures, and in endothelial cells cultures, indicates that certain components of the low dose radiation response are broadly conserved across cell types and tissues, independent of proliferation status.

Wyrobek, A. J.; Manohar, C. F.; Nelson, D. O.; Furtado, M. R.; Bhattacharya, M. S.; Marchetti, F.; Coleman, M.A.

2011-04-18T23:59:59.000Z

65

LI  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcG ENERGYELIkNATIONHEALXH: l ._I5097-MSLEd:JCD\

66

Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems  

SciTech Connect (OSTI)

Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

Natalie J. Gese; Batric Pesic

2013-03-01T23:59:59.000Z

67

Characterization of Materials for Li-ion Batteries: Success Stories...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success...

68

Characterization of Li-ion Batteries using Neutron Diffraction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques 2011 DOE...

69

Mixed Salts of LiTFSI and LiBOB for Stable LiFePO4-Based Batteries at Elevated Temperatures  

SciTech Connect (OSTI)

To achieve stable long-term cycling stability at elevated temperatures, mixed salts of LiTFSI and LiBOB are used to replace LiPF6 salt in non-aqueous electrolytes for LiFePO4-based batteries. It is found that adding LiBOB in LiTFSI-based electrolytes effectively prevents the severe corrosion to Al current collectors that often is observed in LiTFSI-based electrolytes, which have high thermal stability. The cells using LiTFSI-LiBOB-based electrolytes demonstrate superior high temperature (60 ?C) stability and very similar room temperature performance (i.e., cycling stability and rate capability) when compared to cells using the LiPF6-based electrolyte.

Chen, Xilin; Xu, Wu; Engelhard, Mark H.; Zheng, Jianming; Zhang, Yaohui; Ding, Fei; Qian, Jiangfeng; Zhang, Jiguang

2014-01-13T23:59:59.000Z

70

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network [OSTI]

thermal stability of the Li-ion battery. CONCLUSIONS CoatingPDDA. EC- AFM studies on Li-ion battery electrodes offered

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

71

Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu  

E-Print Network [OSTI]

Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu://pop.aip.org/about/rights_and_permissions #12;Active control of the resistive wall mode with power saturation Li Li,1,a) Yue Liu,1 and Yueqiang, 116024, People's Republic of China 2 Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX

72

Project Leader: Dr. Peiwen (Perry) Li  

Broader source: Energy.gov (indexed) [DOE]

Li peiwen@email.arizona.edu MOTIVATION The use of nitrate salts as heat-transfer fluids (HTFs) in concentrating solar power (CSP) systems has been investigated for decades....

73

Negative Electrodes for Li-Ion Batteries  

SciTech Connect (OSTI)

Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

Kinoshita, Kim; Zaghib, Karim

2001-10-01T23:59:59.000Z

74

Ambient Operation of Li/Air Batteries  

SciTech Connect (OSTI)

In this work, Li/air batteries based on nonaqueous electrolytes were investigated in ambient conditions (with an oxygen partial pressure of 0.21 atm and relative humidity of ~20%). A heat-sealable polymer membrane was used as both an oxygen-diffusion membrane and as a moisture barrier for Li/air batteries. The membrane also can minimize the evaporation of the electrolyte from the batteries. Li/air batteries with this membrane can operate in ambient conditions for more than one month with a specific energy of 362 Wh kg-1, based on the total weight of the battery including its packaging. Among various carbon sources used in this work, Li/air batteries using Ketjenblack (KB) carbon-based air electrodes exhibited the highest specific energy. However, KB-based air electrodes expanded significantly and absorbed much more electrolyte than electrodes made from other carbon sources. The weight distribution of a typical Li/air battery using the KB-based air electrode was dominated by the electrolyte (~70%). Lithium-metal anodes and KB-carbon anodes account for only 5.12% and 5.78% of the battery weight, respectively. We also found that only ~ 20% of the mesopore volume of the air electrode was occupied by reaction products after discharge. To further improve the specific energy of the Li/air batteries, the microstructure of the carbon electrode needs to be further improved to absorb much less electrolyte while still holding significant amounts of reaction products

Zhang, Jiguang; Wang, Deyu; Xu, Wu; Xiao, Jie; Williford, Ralph E.

2010-07-01T23:59:59.000Z

75

Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage  

SciTech Connect (OSTI)

i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

Wang, Wei; Choi, Daiwon; Yang, Zhenguo

2013-01-01T23:59:59.000Z

76

REGULAR ARTICLE Variational grand-canonical electronic structure of Li+Li  

E-Print Network [OSTI]

, is applied to the di-lithium (Li?Li) system at temperatures around T & 104 K and electronic chemical the other is ``spin polarized''. This crossing causes near-dis- continuous jumps in calculated properties in strong laser interaction with matter, nuclear and shock- wave physics, astrophysics, and liquid metals [1

Baer, Roi

77

Excitation functions of {sup 6,7}Li+{sup 7}Li reactions at low energies  

SciTech Connect (OSTI)

Differential cross sections of {sup 6,7}Li+{sup 7}Li nuclear reactions have been measured at forward angles (10 deg. and 20 deg.), using particle identification detector telescopes, over the energy range 2.75-10.00 MeV. Excitation functions have been obtained for low-lying residual-nucleus states. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) at beam energy about 8 MeV, first observed by Wyborny and Carlson in 1971 at 0 deg., has been observed at 10 deg., but is less evident at 20 deg. The cross section obtained for the {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(g.s,0{sup +}) reaction is about ten times smaller. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) reaction could correspond to excited states in {sup 14}C, at excitation energies around 30 MeV.

Prepolec, L.; Soic, N.; Blagus, S.; Miljanic, D.; Siketic, Z.; Skukan, N.; Uroic, M. [Ruder Boskovic Institute, Bijenicka c. 54, HR-10000 Zagreb (Croatia); Milin, M. [Faculty of Science, University of Zagreb, Bijenicka c. 32, HR-10000 Zagreb (Croatia)

2009-08-26T23:59:59.000Z

78

Quickest Spectrum Sensing in Cognitive Radio Husheng Li, Chengzhi Li and Huaiyu Dai  

E-Print Network [OSTI]

1 Quickest Spectrum Sensing in Cognitive Radio Husheng Li, Chengzhi Li and Huaiyu Dai Abstract spectrum sensing in secondary radio systems without data fusion centers. Performance is evaluated using to detect the primary radio signal. The fundamental limits of spectrum sensing are discussed in [15] while

Dai, Huaiyu

79

Rate-dependent morphology of Li2O2 growth in Li-O2 batteries  

E-Print Network [OSTI]

Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes, based on a theory of electrochemical non-equilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.

Horstmann, B; Mitchell, R; Bessler, W G; Shao-Horn, Y; Bazant, M Z

2013-01-01T23:59:59.000Z

80

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode. LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion...

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

First-principles investigation of Li intercalation kinetics in phospho-olivines  

E-Print Network [OSTI]

This thesis focuses broadly on characterizing and understanding the Li intercalation mechanism in phospho-olivines, namely LiFePO? and Li(Fe,Mn)PO?, using first-principles calculations. Currently Li-ion battery technology ...

Malik, Rahul

2013-01-01T23:59:59.000Z

82

Investigation of Mechanical Activation on Li-N-H Systems Using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Investigation of Mechanical Activation on Li-N-H Systems Using 6Li...

83

Hydrogen storage in LiH: A first principle study  

SciTech Connect (OSTI)

First principles calculations have been performed on the Lithium hydride (LiH) using the full potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory. We have extended our calculations for LiH+2H and LiH+6H in NaCl structure. The structural stability of three compounds have been studied. It is found that LiH with 6 added Hydrogen atoms is most stable. The obtained results for LiH are in good agreement with reported experimental data. Electronic structures of three compounds are also studied. Out of three the energy band gap in LiH is ?3.0 eV and LiH+2H and LiH+6H are metallic.

Banger, Suman, E-mail: sumanphy28@gmail.com; Nayak, Vikas, E-mail: sumanphy28@gmail.com; Verma, U. P., E-mail: sumanphy28@gmail.com [School of Studies in Physics, Jiwaji University, Gwalior-474011 (India)

2014-04-24T23:59:59.000Z

84

Protection of Li Anodes Using Dual Phase Electrolytes  

Broader source: Energy.gov (indexed) [DOE]

50 full charge-discharge cycles in the laboratory scale Li-S cells. Partners BASF SE, Germany * Development of Li-S battery materials 3 Project Objectives * Develop a unique...

85

Development of Li+ alumino-silicate ion source  

E-Print Network [OSTI]

Development of a Li + alumino-silicate ion source ? P. K.kinetic energy. Alumino-silicates sources of K + and Cs +and sintering the Li alumino- silicate to the substrate to

Roy, P.K.

2009-01-01T23:59:59.000Z

86

Lithium Source For High Performance Li-ion Cells  

Broader source: Energy.gov (indexed) [DOE]

New cathode and anode electrodes are required to improve the energy density of Li-ion cells for transportation technologies. The cost of Li-ion systems for transportation...

87

Thin, Flexible Secondary Li-Ion Paper Liangbing Hu,  

E-Print Network [OSTI]

Thin, Flexible Secondary Li-Ion Paper Batteries Liangbing Hu, Hui Wu, Fabio La Mantia, Yuan Yang, secondary Li-ion batteries are key components in por- table electronics due to their high power and energy integrated all of the components of a Li-ion battery into a single sheet of paper with a simple lamination

Cui, Yi

88

Corrosion of lithium in LiCl-LiOH-H/sub 2/O-system solutions  

SciTech Connect (OSTI)

This communication presents the results of an investigation of the corrosion of lithium in solutions of the system LiCl-LiOH-H/sub 2/O at 298 K. The reaction rate of lithium with the electrolyte was calculated on the basis of volumetric measurements. The investigation was carried out in a standard electrochemical cell furnished with a branch pipe for the collection of hydrogen. The results demonstrated that in the absence of polarization the lithium corrosion rate decreased as the concentration of lithium chloride in the electrolyte increased, and also that at lower concentrations of LiOH, additions of LiCl exerted a stronger influence on the corrosion rate of the metal.

Demidov, A.I.; Kungurtsev, O.A.; Morachevskii, A.G.

1988-07-10T23:59:59.000Z

89

Allen Clement1 , Harry Li1  

E-Print Network [OSTI]

BAR Primer Allen Clement1 , Harry Li1 , Jeff Napper1 , Jean-Philippe Martin2 , Lorenzo Alvisi1 , Mike Dahlin1 1 University of Texas at Austin, 2 Microsoft Research Cambridge 1 {aclement, harry, jmn synchronous Repeated Terminating Reliable Broadcast (R- TRB) problem statement, leads to a provably BAR

Alvisi, Lorenzo

90

DlcSsoo |LI Metallurgy Department  

E-Print Network [OSTI]

DlcSsoo |LI s TT^rrrc^ G en 2 L-V I 7 Ris-R-523 Metallurgy Department Progress Report;Ris-R-523 METALLURGY DEPARTMENT PROGRESS REPORT FOR THE PERIOD 1 JANUARY TO 31 DECEMBER 1984 Abstract. The activities of the Metallurgy Department at Ris during 1984 are described. The work is presented in three

91

Dingzeyu Li LE Schapiro (CEPSR), Columbia University  

E-Print Network [OSTI]

Dingzeyu Li LE Schapiro (CEPSR), Columbia University West th St New York, NY , USA ( ) - dli@cs.columbia.edu http://www.cs.columbia.edu/~dli/ Education Columbia University, New York, USA Sept. - present - PhD Research, Advisor: Changxi Zheng, Columbia Computer Graphics Group, Columbia University, New York, Aug

Grinspun, Eitan

92

Forensic Computing Xiang Li and Jennifer Seberry  

E-Print Network [OSTI]

Forensic Computing Xiang Li and Jennifer Seberry #3; Abstract Technology is rapidly changing continuously improve to keep one step ahead. Computer forensics has become a specialized and accepted forensic software is also widely used during the whole process of computer forensic investigation

Seberry, Jennifer

93

Performance study of commercial LiCoO2 and spinel-based Li-ion cells  

E-Print Network [OSTI]

-ion cells and Sony 18650 cells using non-stoichiometric spinel and LiCoO2, respectively, as positive at the cathode and loss of active material at both electrodes due to electrolyte oxidation. For the Sony cells Science B.V. All rights reserved. Keywords: Li-ion cells; LiCoO2; Cell-Batt1 ; Capacity fade; Sony 18650

Popov, Branko N.

94

Nonequilibrium Phase Transformation and Particle Shape Effect in LiFePO4 Materials for Li-Ion Batteries  

E-Print Network [OSTI]

-induced nonequilibrium phenomenon in Li-ion batteries. A theoretical anal- ysis is presented to show for Li-ion batteries as power sources in transporta- tion and future energy landscape requires transformaiton in Li ion batteries, especially on meta- stable miscibility gap distortion and discharge behaviors

Liu, Fuqiang

95

Is there a bound dineutron in {sup 11}Li?  

SciTech Connect (OSTI)

Photodisintegration of {sup 11}Li was accomplished by sending a beam of {sup 11}Li at 28 MeV/nucleon through the equivalent photon field of a lead target. By measuring the complete kinematics of the disintegration products, {sup 9}Li+{ital n}+{ital n}, we constructed the correlation of the angle between the two neutrons in the rest frame of the {sup 11}Li. The correlation is independent of angle. This result argues against the existence of a bound dineutron in the ground state of {sup 11}Li. {copyright} {ital 1996 The American Physical Society.}

Ieki, K.; Galonsky, A.; Sackett, D.; Kruse, J.J.; Lynch, W.G.; Morrissey, D.J.; Orr, N.A.; Sherrill, B.M.; Winger, J.A. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)] [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Deak, F.; Horvath, A.; Kiss, A. [Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7, H-1088 Budapest 8 (Hungary)] [Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7, H-1088 Budapest 8 (Hungary); Seres, Z. [Central Research Institute for Physics, Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary)] [Central Research Institute for Physics, Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary); Kolata, J.J. [Physics Department, University of Notre Dame, Notre Dame, Indiana 46556 (United States)] [Physics Department, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Warner, R.E. [Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States)] [Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States); Humphrey, D.L. [Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States)] [Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States)

1996-10-01T23:59:59.000Z

96

Making Li-air batteries rechargeable: material challenges  

SciTech Connect (OSTI)

A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

2013-02-25T23:59:59.000Z

97

Electrolyte effects in Li(Si)/FeS{sub 2} thermal batteries  

SciTech Connect (OSTI)

The most common electrochemical couple for thermally activated (``thermal``) batteries is the Li-alloy/FeS{sub 2} system. The most common Li-alloys used for anodes are 20% Li-80% Al and 44% Li-56% Si (by weight); liquid Li immobilized with iron powder has also been used. The standard electrolyte that has been used in thermal batteries over the years is the LiCl-KCl eutectic that melts at 352{degrees}C. The LiCl-LiBr-LiF eutectic had the best rate and power characteristics. This electrolyte melts at 436{degrees}C and shows very low polarization because of the absence of Li+ gradients common with the LiCl-KCl eutectic. The low-melting electrolytes examined included a KBr-LiBr-LiCl eutectic (melting at 321{degrees}C), a LiBr-KBr-LiF eutectic (melting at 313{degrees}C), and a CsBr-LiBr-KBr eutectic (melting at 238{degrees}C). The CsBr-based salt had poor conductivity and was not studied further. The LiBr-KBr-LiF eutectic outperformed the KBr-LiBr-LiCl eutectic and was selected for more extensive testing. Because of their lower melting points and larger liquidi relative to the LiCl-KCl eutectic, the low-melting electrolytes are prime candidates for long-life applications (i.e., for activated lives of one hour or more). This paper will detail the relative performance of the Li(Si)/FeS{sub 2} couple using primarily the LiCl-KCl (standard) eutectic, the LiCl-LiBr-LiF (all-Li) eutectic, and the LiBr-KBr-LiF (low-melting) eutectic electrolytes. Most of the tests were conducted with 5-cell batteries; validation tests were also carried out with appropriate full-sized batteries.

Guidotti, R.A.; Reinhardt, F.W.

1994-10-01T23:59:59.000Z

98

Spectroscopy of Lambda-9Li by electroproduction  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The cross section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.360.08 (stat.) 0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; Boeglin, W. U.; Breuer, H.; Brindza, P.; Bydzovsky, P.; Camsonne, A.; Chang, C. C.; Chen, J. -P.; Choi, Seonho; Chudakov, E. A.; Cisbani, E.; Colilli, S.; Coman, L.; Craver, B. J.; De Cataldo, G.; de Jager, C. W.; De Leo, R.; Deur, A. P.; Ferdi, C.; Feuerbach, R. J.; Folts, E.; Fratoni, R.; Frullani, S.; Garibaldi, F.; Gayou, O.; Giuliani, F.; Gomez, J.; Gricia, M.; Hansen, J. O.; Hayes, D.; Higinbotham, D. W.; Holmstrom, T. K.; Hyde, C. E.; Ibrahim, H. F.; Iodice, M.; Jiang, X.; Kaufman, L. J.; Kino, K.; Kross, B.; Lagamba, L.; LeRose, J. J.; Lindgren, R. A.; Lucentini, M.; Margaziotis, D. J.; Markowitz, P.; Meziani, Z. E.; McCormick, K.; Michaels, R. W.; Millener, D. J.; Miyoshi, T.; Moffit, B.; Monaghan, P. A.; Moteabbed, M.; Camacho, C. Munoz; Nanda, S.; Nappi, E.; Nelyubin, V. V.; Norum, B. E.; Okasyasu, Y.; Paschke, K. D.; Perdrisat, C. F.; Piasetzky, E.; Punjabi, V. A.; Qiang, Y.; Reimer, P. E.; Reinhold, J.; Reitz, B.; Roche, R. E.; Rodriguez, V. M.; Saha, A.; Santavenere, F.; Sarty, A. J.; Segal, J.; Shahinyan, A.; Singh, J.; Sirca, S.; Snyder, R.; Solvignon, P. H.; Sotona, M.; Subedi, R.; Sulkosky, V. A.; Suzuki, T.; Ueno, H.; Ulmer, P. E.; Veneroni, P.; Voutier, E.; Wojtsekhowski, B. B.; Zheng, X.; Zorn, C.

2015-03-01T23:59:59.000Z

99

Preparing Guyana's REDD+ Participation: Developing Capacities for  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Powerstories onFocusOskiPhilips ColorLoadingTechnologiesMonitoring, Reporting

100

Guyana: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Power BasicsGermany: EnergyPower Finance Jump to: navigation,

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1  

E-Print Network [OSTI]

Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1 , Wen Chao Lee1 This study demonstrates the feasibility of using water and the contents of waste Li-ion batteries for the electrodes in a Li-liquid battery system. Li metal was collected electrochemically from a waste Li

Zhou, Yaoqi

102

Li overlayer formation, oxidation and sputtering characteristics of Al-Li alloys and W/Al-Li composites for fusion applications  

SciTech Connect (OSTI)

The next generation of long pulse fusion devices will impose severe requirements on the properties of plasma-facing materials. In devices such as ITER, a divertor design is being considered, using a divertor plate which would be either tungsten or a low-Z material such as graphite or beryllium. Strongly segregating lithium alloys have been proposed as a means of producing a self-sustaining low-Z overlayer which lowers plasma Z{sub eff} and resists self-sputtering. Aluminum-lithium alloys are among the better-characterized lithium-bearing alloys, and it has been demonstrated that lithium segregates strongly in aluminum. However, aluminum has a relatively low melting point, and for low lithium concentrations, the lithium diffusion rate is too slow to replenish lithium at the rate at which it is eroded by the incoming plasma. It has been suggested previously that the superionic {beta} phase Al-Li alloy (48--54 at. % Li) should have high enough diffusivity to be able to replenish surface lithium, and that incorporation of the {beta}-phase AlLi in a composite with tungsten would provide high temperature strength and melt layer stability, along with significantly better thermal conductivity than pure tungsten. Such a composite has been fabricated, as well as a variation containing titanium as a means of controlling oxidation at grain boundaries. The Li overlayer formation, erosion, and replenishment are characterized for the {beta}-phase LiAl alloy, and W-AlLi and W-Ti-AlLi composites. It is found that if there is no oxide layer to inhibit the Li segregation, Li diffusion is extremely rapid, and an oxygen-free Li overlayer is formed which is stable under continuous ion beam sputtering. 21 refs., 7 figs.

Krauss, A.R. (Argonne National Lab., IL (USA)); DeWald, A.B.; Scott, P.; Savage, H. (Corium Industries, Inc., Atlanta, GA (USA))

1990-01-01T23:59:59.000Z

103

Protection of Li Anodes Using Dual Phase Electrolytes  

Broader source: Energy.gov (indexed) [DOE]

cells with high energy anode and dual-phase electrolyte systems Partners BASF SE, Germany * Development of Li-S battery materials 3 Relevance. Project Objectives. * Develop a...

104

High Voltage Electrolytes for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

or otherwise restricted information High Voltage Electrolytes for Li-ion Batteries Vehicle Technologies Program 2 Overview * Start: Sep 2008 * End: Sep 2011 * 20 %...

105

Characterization of Materials for Li-ion Batteries: Success Stories...  

Broader source: Energy.gov (indexed) [DOE]

Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2010 Vehicle Technologies Annual Merit Review and Peer...

106

Characterization of Li-ion Batteries using Neutron Diffraction...  

Broader source: Energy.gov (indexed) [DOE]

Li-ion batteries Using Neutron Diffraction and Infrared Imaging Techniques: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2011 Vehicle...

107

Investigation of critical parameters in Li-ion battery electrodes...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of critical parameters in Li-ion battery electrodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

108

Primordial Li abundance and massive particles  

SciTech Connect (OSTI)

The problem of the observed lithium abundance coming from the Big Bang Nucleosynthesis is as of yet unsolved. One of the proposed solutions is including relic massive particles into the Big Bang Nucleosynthesis. We investigated the effects of such particles on {sup 4}HeX{sup -}+{sup 2}H{yields}{sup 6}Li+X{sup -}, where the X{sup -} is the negatively charged massive particle. We demonstrate the dominance of long-range part of the potential on the cross-section.

Latin-Capital-Letter-Eth apo, H. [Department of Physics, Akdeniz University, TR-07058, Antalya (Turkey)

2012-10-20T23:59:59.000Z

109

LiDAR | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place:Keystone CleanLaton,LearnLeupp SchoolLewisville isLiDAR

110

I I LI I L I  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1f\lMUC4cb90,fiom I - Copy'LI

111

Ying Li | Argonne Leadership Computing Facility  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout SRNL Home SRNLSecurityNationalComplexYing Li Margaret

112

A=10Li (74AJ01)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy Level Diagrams for74AJ01) (Not illustrated) 10Li is

113

A=13Li (1986AJ01)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy Level1980AJ01)90AJ01)86AJ01) (Not illustrated) 13Li

114

A=14Li (1981AJ01)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See the Isobar1AJ01) (Not illustrated) 14Li

115

A=15Li (1986AJ01)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See the59AJ76)6AJ01) (Not illustrated) 15Li

116

A=16Li (1993TI07)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04) (See93TI07) (Not1982AJ01)Li (1993TI07) (Not

117

A=18Li (1995TI07)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See Energy0AJ04)86AJ04) (Not6AJ04)95TI07) (Not illustrated)Li

118

A=20Li (1998TI06)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See the Isobar98TI06) (See Energy LevelHeLi

119

A=8Li (66LA04)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See 8Li (66LA04) (See Energy

120

A=8Li (74AJ01)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07) (See4AJ01)59AJ76) (See 8Li (66LA04) (See

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Homogeneous Factorisations of Graphs and Michael Giudici a, Cai Heng Li a  

E-Print Network [OSTI]

Homogeneous Factorisations of Graphs and Digraphs Michael Giudici a, Cai Heng Li a Primoz Potocnik@maths.uwa.edu.au (Michael Giudici), li@maths.uwa.edu.au (Cai Heng Li), primoz.potocnik@fmf.uni-lj.si (Primoz Preprint

Giudici, Michael

122

Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge  

E-Print Network [OSTI]

Using a novel electrochemical phase-field model, we question the common belief that LiXFePO? nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition ...

Bai, Peng

123

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

as cathode materials for Li-ion battery. Physica B-CondensedHigh Energy High Power Li-ion Battery Cathode Materials AHigh Energy High Power Li-ion Battery Cathode Materials A

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

124

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network [OSTI]

Ethylene Carbonate in Li-Ion Battery Electrolyte Guoyingof a commercial Li-ion battery electrolyte containing 2 %are an important part of Li-ion battery technology yet their

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

125

A HIGH CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGET HEATING EXPERIMENTS  

E-Print Network [OSTI]

CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGETCURRENT DENSITY LI + ALUMINO-SILICATE ION SOURCE FOR TARGETcm) Li + doped alumino-silicate source with a pulse duration

Roy, Prabir K.

2011-01-01T23:59:59.000Z

126

Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li  

E-Print Network [OSTI]

Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li Lithium-halogen exchange reactions are essentially inert. 2 t-BuLi t-BuI + RLi t-BuLi isobutene + isobutane + LiI Lithium-halogen exchange reactions, and lithium iodide. H OEtBr H H OEtLi H1.1 eq n-BuLi Et2O, !80 C Lau, K. S.; Schlosser, M. J. Org. Chem. 1978

127

Molecular dynamics simulation of Li surface erosion and bubble formation  

E-Print Network [OSTI]

.49.Sf Keywords: Liquid metal; Lithium; Ion-surface interactions 1. Introduction Bombardment Structure and dynamical properties of liquid Li containing He atoms were studied by the Molecular Dynamics characteristics of light low-energy ions on a liquid Li surface and their diffusion properties have attracted much

Harilal, S. S.

128

Implications of Li divertor and other liquid-metal technologies  

E-Print Network [OSTI]

plasma-facing systems can rapidly remove heat. h Continuous recovery of damaged surfaces exposed to large. Nuclear Mater. 290-293 (2001) 19. #12;Secondary ion fraction and deuterium- saturation studies of liquid (sputteringions/sputteredatoms) Incident particle energy (eV) Secondary Li ion fraction (non D-sat.) Secondary Li

129

Ethylmethylcarbonate, a promising solvent for Li-ion rechargeable batteries  

SciTech Connect (OSTI)

Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li-ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent (LiAsF{sub 6}, LiPF{sub 6}, etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li-ion battery systems as compared with the other two open-chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, ROCO{sub 2}Li, and Li{sub 2}CO{sub 3} species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.

Ein-Eli, Y.; Thomas, S.R.; Koch, V. [Covalent Associates Inc., Woburn, MA (United States); Aurbach, D.; Markovsky, B.; Schechter, A. [Bar-Ilan Univ., Ramat Gan (Israel). Dept. of Chemistry

1996-12-01T23:59:59.000Z

130

The prospects for highbeta tokamaks with Li walls 1  

E-Print Network [OSTI]

stream Plasma Plasma edge Electrode Insulator Electrode Li outlet Helium atmosphere Supporting bands:5) The the diamagnetic drag parameter PD PD #17; #22; 0 #27;h 2 V 12r I TFC I Li #28; 1 (2:6) determines the drag force

Zakharov, Leonid E.

131

Statistical Design of Experiment for Li-ion Cell Formation Parameters...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Statistical Design of Experiment for Li-ion Cell Formation Parameters using Gen3 Electrode Materials: Final Summary Statistical Design of Experiment for Li-ion Cell Formation...

132

E-Print Network 3.0 - al-li-cu alloy part Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

molds. Materials investigated are Al-Li-Mg and Al-Li-Cu... . Compared with copper, magnesium gives a better combination of fluidity and ... Source: Ecole Polytechnique, Centre...

133

Thermal Instability of Olivine-Type LiMnP04 Cathodes  

E-Print Network [OSTI]

In the presence of a Li-ion battery electrolyte, delithiatedion battery electrolyte is also evaluated, and its impact on the safety of high energy phosphate Li-

Chen, Guoying

2010-01-01T23:59:59.000Z

134

Characterization of LI+ Alumino-Silicate Ion Source for Target Heating Experiments  

E-Print Network [OSTI]

OF LI + ALUMINO-SILICATE ION SOURCE FOR TARGET HEATINGcm) Li + doped alumino-silicate source to pro- duce shortdiameter lithium alumino-silicate ion source is presented.

Roy, P.K.

2013-01-01T23:59:59.000Z

135

Localization of vacancies and mobility of lithium ions in Li{sub 2}ZrO{sub 3} as obtained by {sup 6,7}Li NMR  

SciTech Connect (OSTI)

The {sup 6,7}Li NMR spectra and the {sup 7}Li spinlattice relaxation rate were measured on polycrystalline samples of Li{sub 2}ZrO{sub 3}, synthesized at 1050 K and 1300 K. The {sup 7}Li NMR lines were attributed to corresponding structural positions of lithium Li1 and Li2 by comparing the EFG components with those obtained in the first-principles calculations of the charge density in Li{sub 2}ZrO{sub 3}. For both samples the line width of the central {sup 7}Li transition and the spinlattice relaxation time decrease abruptly at the temperature increasing above ?500 K, whereas the EFG parameters are averaged (??{sub Q}?=42 (5) kHz) owing to thermally activated diffusion of lithium ions. - Graphical abstract: Path of lithium ion hopping in lithium zirconate Li{sub 2}ZrO{sub 3}. - Highlights: Polycrystalline samples Li{sub 2}ZrO{sub 3} with monoclinic crystal structure synthesized at different temperatures were investigated by {sup 6,7}Li NMR spectroscopy. Two {sup 6,7}Li NMR lines were attributed to the specific structural positions Li1 and Li2. The distribution of vacancies was clarified for both lithium sites. The activation energy and pathways of lithium diffusion in Li{sub 2}ZrO{sub 3} were defined.

Baklanova, Ya. V., E-mail: baklanovay@ihim.uran.ru [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation); Arapova, I. Yu.; Buzlukov, A.L.; Gerashenko, A.P.; Verkhovskii, S.V.; Mikhalev, K.N. [Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, 18 Kovalevskaya str., 620990 Ekaterinburg (Russian Federation); Denisova, T.A.; Shein, I.R.; Maksimova, L.G. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation)

2013-12-15T23:59:59.000Z

136

An attempt to study LiH and Li{sub 2} molecules by high resolution pulsed laser spectroscopy  

SciTech Connect (OSTI)

As we start a program to study alkali hydrides and dimers, we have developed a two-step photoionisation experiment on Li{sub 2} molecules based on the use of an atomic beam and two pulsed dye lasers. The first resonant step which excites the A {sup 1}{sigma}{sub u}{sup +}-X {sup 1}{sigma}{sub g}{sup +}Li{sub 2} dimer systems is a home-made cw-seeded DCM dye laser with a laser linewidth of 55 MHz (FWHM) and near the Fourier transform limit. The second step is a larger width fixed frequency UV laser which allows the photoionisation of the selectively excited molecules. The three {sup 6}Li{sub 2}, {sup 6}Li {sup 7}Li and {sup 7}Li{sub 2} spectra are recorded simultaneously by the use of a doubly-accelerating time-of-flight ion analyser. Comparison between recorded and calculated absorption spectra using Dunham parameters found in the literature is satisfactory. To develop similar pulsed high-resolution investigations in LiH, we have characterized our molecular beam by using the laser induced fluorescence (LIF) technique with a cw blue dye laser. Two Franck-Condon LiH Doppler-free resonances have been observed.

Bouloufa, Nadia; Cabaret, Louis; Cacciani, Patrice; Camus, Pierre; Pitcheev, Boris; Vetter, Raymond [Laboratoire Aime Cotton, CNRS II, Bat 505, Campus d'Orsay, 91405 Orsay Cedex (France)

1998-12-16T23:59:59.000Z

137

Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Citation: Zheng J, J Xiao, X Yu, L Kovarik, M Gu, F Omenya, X Chen, XQ Yang, J Liu, GL Graff, MS Whittingham, and J Zhang.2012."Enhanced Li+ ion transport in LiNi0.5Mn1.5O4...

138

E F F I C I E N CY A N D R E N E W A B L E E N E R GY D IV I S I O N CALIFORNIA ENERGY COMMISSION  

E-Print Network [OSTI]

. If this system is not installed properly, it not only wastes energy, but money as well. To prevent this, do two of the conditioned air into the attic or crawl space. Leaky ducts waste energy and make energy bills higher thanBLUEPRI NT E F F I C I E N CY A N D R E N E W A B L E E N E R GY D IV I S I O N CALIFORNIA ENERGY

139

E F F I C I E N CY A N D R E N E W A B L E E N E R GY D IV I S I O N CALIFORNIA ENERGY COMMISSION  

E-Print Network [OSTI]

BLUEPRI NT E F F I C I E N CY A N D R E N E W A B L E E N E R GY D IV I S I O N CALIFORNIA ENERGYHERSComplianceDocumentationRegisteredonorAfterOctober1,2010 B l u e p r i n t 9 8 N o v e m b e r D e c e m b e r 2 0 1 0 Residential Radiant Barrier

140

E F F I C I E N CY A N D R E N E W A B L E E N E R GY D IV I S I O N CALIFORNIA ENERGY COMMISSION  

E-Print Network [OSTI]

the California Energy Commission recognizes for certifying the solar reflectance and thermal emittance valuesBLUEPRI NT E F F I C I E N CY A N D R E N E W A B L E E N E R GY D IV I S I O N CALIFORNIA ENERGY Efficiency Standards WHAT ARE COOL ROOFS? The term cool roof refers to a roofing product with high solar

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Structure of neutron-rich Isotopes {sup 8}Li and {sup 9}Li and allowance for it in elastic scattering  

SciTech Connect (OSTI)

The differential cross sections for elastic proton scattering on the unstable neutron-rich nuclei {sup 8}Li and {sup 9}Li at E = 700 and 60 MeV per nucleon were considered. The {sup 8}Li nucleus was treated on the basis of the three-body {alpha}-t-n model, while the {sup 9}Li nucleus was considered within the {alpha}-t-n and {sup 7}Li-n-n models. The cross sections in question were calculated within Glauber diffraction theory. A comparison of the results with available experimental data made it possible to draw conclusions on the quality of the wave functions and potential used in the calculations.

Ibraeva, E. T., E-mail: ibr@inp.k [National Nuclear Center of the Republic of Kazakhstan, Institute for Nuclear Physics (Kazakhstan); Zhusupov, M. A.; Imambekov, O.; Sagindykov, Sh. Sh. [Al Farabi Kazakh National University (Kazakhstan)

2008-07-15T23:59:59.000Z

142

LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery  

DOE Patents [OSTI]

This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

Ko, Suk M. (Huntsville, AL)

1980-01-01T23:59:59.000Z

143

Effects of Nonaqueous Electrolytes on Primary Li-Air Batteries  

SciTech Connect (OSTI)

The effects of nonaqueous electrolytes on the performance of primary Li-air batteries operated in dry air environment have been investigated. Organic solvents with low volatility and low moisture absorption are necessary to minimize the change of electrolyte compositions and the reaction between Li anode and water during the discharge process. The polarity of aprotic solvents outweighs the viscosity, ion conductivity and oxygen solubility on the performance of Li-air batteries once these latter properties attain certain reasonable level, because the solvent polarity significantly affects the number of tri-phase regions formed by oxygen, electrolyte, and active carbons (with catalyst) in the air electrode. The most feasible electrolyte formulation is the system of LiTFSI in PC/EC mixtures, whose performance is relatively insensitive to PC/EC ratio and salt concentration. The quantity of such electrolyte added to a Li-air cell has notably effects on the discharge performance of the Li-air battery as well, and a maximum in capacity is observed as a function of electrolyte amount. The coordination effect from the additives or co-solvents [tris(pentafluorophenyl)borane and crown ethers in this study] also greatly affects the discharge performance of a Li-air battery.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-06-14T23:59:59.000Z

144

Effects of electrolyte salts on the performance of Li-O2 batteries  

SciTech Connect (OSTI)

It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

2013-02-05T23:59:59.000Z

145

Carbonophosphates: A New Family of Cathode Materials for Li-Ion Batteries Identified Computationally  

E-Print Network [OSTI]

Carbonophosphates: A New Family of Cathode Materials for Li-Ion Batteries Identified ABSTRACT: The tremendous growth of Li-ion batteries into a wide variety of applications is setting new applications from portable electronics to electric vehicles. A critical element of a Li-ion battery is the Li

Ceder, Gerbrand

146

On the Origin and Implications of Li$_2$O$_2$ Toroid Formation in Nonaqueous Li-O$_2$ Batteries  

E-Print Network [OSTI]

The lithium-air (Li-O$_2$) battery has received enormous attention as a possible alternative to current state-of-the-art rechargeable Li-ion batteries given their high theoretical specific energy. However, the maximum discharge capacity in nonaqueous Li-O$_2$ batteries is limited to a small fraction of its theoretical value due to the insulating nature of lithium peroxide, Li$_2$O$_2$, the battery$'$s primary discharge product. In this work, we show that the inclusion of trace amounts of electrolyte additives, such as H$_2$O, significantly improve the capacity of the Li-O$_2$ battery. These additives trigger a solution-based growth mechanism due to their solvating properties, thereby circumventing the Li$_2$O$_2$ conductivity limitation. Experimental observations and a growth model imply that this solution mechanism is responsible for Li$_2$ toroid formation. We present a general formalism describing an additive$'$s tendency to trigger the solution process, providing a rational design route for electrolytes t...

Aetukuri, Nagaphani B; Garca, Jeannette M; Krupp, Leslie E; Viswanathan, Venkatasubramanian; Luntz, Alan C

2014-01-01T23:59:59.000Z

147

Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}  

DOE Patents [OSTI]

Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

Marshall, C.D.; Payne, S.A.; Krupke, W.F.

1996-05-14T23:59:59.000Z

148

Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6  

DOE Patents [OSTI]

Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

Marshall, Christopher D. (Livermore, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA)

1996-01-01T23:59:59.000Z

149

Methods and preliminary measurement results of liquid Li wettability  

SciTech Connect (OSTI)

A test of lithium wettability was performed in high vacuum (< 3 10{sup ?4} Pa). High magnification images of Li droplets on stainless steel substrates were produced and processed using the MATLAB{sup } program to obtain clear image edge points. In contrast to the more standard ?/2 or polynomial fitting methods, ellipse fitting of the complete Li droplet shape resulted in reliable contact angle measurements over a wide range of contact angles. Using the ellipse fitting method, it was observed that the contact angle of a liquid Li droplet on a stainless steel substrate gradually decreased with increasing substrate temperature. The critical wetting temperature of liquid Li on stainless steel was observed to be about 290?C.

Zuo, G. Z., E-mail: zuoguizh@ipp.ac.cn; Hu, J. S.; Ren, J.; Sun, Z.; Yang, Q. X.; Li, J. G. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China)] [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Zakharov, L. E.; Mansfield, D. K. [Princeton Plasma Physics Laboratory, MS-27 P.O. Box 451, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, MS-27 P.O. Box 451, Princeton, New Jersey 08543 (United States)

2014-02-15T23:59:59.000Z

150

Transport and Failure in Li-ion Batteries | Stanford Synchrotron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well predicted by the...

151

Development of High Energy Cathode for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

for Li-ion Batteries Ji-Guang Zhang and Jun Liu Pacific Northwest National Laboratory 2010 DOE Vehicle Technologies Program Review June 7-11, 2010 Project ID: ES056 This...

152

Stability of polymer binders in Li-O2 batteries  

SciTech Connect (OSTI)

A number of polymers with various chemical structures were studied as binders for air electrodes in Li-O2 batteries. The nature of the polymer significantly affects the binding properties in the carbon electrodes thus altering the discharge performance of Li-O2 batteries. Stability of polymers to the aggressive reduced oxygen species generated during discharge was tested by ball milling them with KO2 and Li2O2, respectively. Most of the polymers decomposed under these conditions and mechanisms of the decompositions are proposed for some of the polymers. Polyethylene was found to have excellent stability and is suggested as robust binder for air electrodes in Li-O2 batteries.

Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Li, Xiaohong S.; Zhang, Jiguang

2013-06-24T23:59:59.000Z

153

2010 DOE, Li-Ion Battery Cell Manufacturing  

Broader source: Energy.gov (indexed) [DOE]

otherwise restricted information" 2010 DOE, Li-Ion Battery Cell Manufacturing Kee Eun LG Chem Ltd.Compact Power Inc. Jun 8 th 2010 Project ID ARRAVT001 "This presentation does...

154

atoms li na: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ground (doublet) atomic 2S(L 0)-state. It is straightforward to generalize our analysis to other bound states of the three-electron Li atom. Alexei M. Frolov; David M....

155

Development of High Capacity Anode for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

stability of Si-based anode. 4 Milestones * Synthesize and characterize TiO 2 Graphene and SnO 2 Graphene nano-composite as anode for Li-ion batteries. - on going *...

156

Construction of a Li Ion Battery (LIB) Cathode Production Plant...  

Broader source: Energy.gov (indexed) [DOE]

Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio Project ID ARRAVT008 Joe DiCarlo BASF Corporation May 11, 2011 "This presentation does not contain...

157

Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4  

E-Print Network [OSTI]

correlate well with the better cycling performance of Al-doped LiMn2O4 in our Li-ion battery tests: LiAl0Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4 Yuan Yang, Chong Xie nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials

Cui, Yi

158

High Voltage Electrolytes for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

Program 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh 80th 1st 50th 1.0 m LiPF 6 in ECEMC (30:70) with 1% ARL-3 on LiNi 0.5 Mn 1.5 O 4 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh...

159

Comparison of Small Polaron Migration and Phase Separation in Olivine LiMnPO? and LiFePO? using Hybrid Density Functional Theory  

E-Print Network [OSTI]

Using hybrid density functional theory based on the Heyd-Scuseria-Ernzerhof (HSE06) functional, we compared polaron migration and phase separation in olivine LiMnPO? to LiFePO?. The barriers for free hole and electron ...

Ong, Shyue Ping

160

Lithium hydroxide, LiOH, at elevated densities  

SciTech Connect (OSTI)

We discuss the high-pressure phases of crystalline lithium hydroxide, LiOH. Using first-principles calculations, and assisted by evolutionary structure searches, we reproduce the experimentally known phase transition under pressure, but we suggest that the high-pressure phase LiOH-III be assigned to a new hydrogen-bonded tetragonal structure type that is unique amongst alkali hydroxides. LiOH is at the intersection of both ionic and hydrogen bonding, and we examine the various ensuing structural features and their energetic driving mechanisms. At P = 17 GPa, we predict another phase transition to a new phase, Pbcm-LiOH-IV, which we find to be stable over a wide pressure range. Eventually, at extremely high pressures of 1100 GPa, the ground state of LiOH is predicted to become a polymeric structure with an unusual graphitic oxygen-hydrogen net. However, because of its ionic character, the anticipated metallization of LiOH is much delayed; in fact, its electronic band gap increases monotonically into the TPa pressure range.

Hermann, Andreas [School of Physics and Astronomy and Centre for Science at Extreme Conditions, The University of Edinburgh, Edinburgh EH9 3JZ (United Kingdom); Ashcroft, N. W. [Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, New York 14853 (United States); Hoffmann, Roald [Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853 (United States)

2014-07-14T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Interactions of Relativistic $^6$Li Nuclei with Photoemulsion Nuclei  

E-Print Network [OSTI]

Inelastic interactions of nuclei accelerated to a momentum of 4.5 GeV/$c$ per projectile nucleon with photoemulsion nuclei have been investigated. The main features of these interactions - mean ranges of $^6$Li nuclei, mean multiplicities of secondaries, the isotopic composition of fragments, fragmentation channels, and the mean transverse momenta of projectile fragments - have been measured. The probability of the charge-exchange reaction featuring lithium nuclei has been determined. The results obtained for the $^6$Li nucleus have been compared with data for other nuclei. The observed features of $^6$Li interactions with other nuclei indicate that the $^6$Li structure in the form of the loosely bound system consisting of an $\\alpha$-particle and a deuteron cluster clearly manifests itself in these interactions. Events resulting in the coherent dissociation of $^6$Li nuclei into $^4$He+$d$, $^3$He+$t$, and $t+d+p$ and involving low-lying excitations of $^6$Li have been observed.

Adamovich, M I; Larionova, V G; Peresadko, N G; Kharlamov, S P; Bogdanov, V G; Plyushchev, V A; Solovyeva, Z I; 10.1063/S6208-1378(99)007788

2011-01-01T23:59:59.000Z

162

Interactions of Relativistic $^6$Li Nuclei with Photoemulsion Nuclei  

E-Print Network [OSTI]

Inelastic interactions of nuclei accelerated to a momentum of 4.5 GeV/$c$ per projectile nucleon with photoemulsion nuclei have been investigated. The main features of these interactions - mean ranges of $^6$Li nuclei, mean multiplicities of secondaries, the isotopic composition of fragments, fragmentation channels, and the mean transverse momenta of projectile fragments - have been measured. The probability of the charge-exchange reaction featuring lithium nuclei has been determined. The results obtained for the $^6$Li nucleus have been compared with data for other nuclei. The observed features of $^6$Li interactions with other nuclei indicate that the $^6$Li structure in the form of the loosely bound system consisting of an $\\alpha$-particle and a deuteron cluster clearly manifests itself in these interactions. Events resulting in the coherent dissociation of $^6$Li nuclei into $^4$He+$d$, $^3$He+$t$, and $t+d+p$ and involving low-lying excitations of $^6$Li have been observed.

M. I. Adamovich; I. A. Konorov; V. G. Larionova; N. G. Peresadko; S. P. Kharlamov; V. G. Bogdanov; V. A. Plyushchev; Z. I. Solovyeva

2011-09-29T23:59:59.000Z

163

Identity of Passive Film Formed on Aluminum in Li-ion BatteryElectrolytes with LiPF6  

SciTech Connect (OSTI)

The passive film that forms on aluminum in 1:1 ethylene carbonate + ethylmethyl carbonate with 1.2M LiPF{sub 6} and 1:1 ethylene carbonate + dimethyl carbonate with 1.0M LiPF{sub 6} was investigated by a combination of electrochemical quartz crystal microbalance measurements (EQCM), electrochemical impedance spectroscopy (EIS), and x-ray photoelectron spectroscopy. During anodic polarization of aluminum a film of AlF{sub 3} forms on top of the air-formed oxide, creating a duplex, or two-layered film. The thickness of the AlF{sub 3} increases with the applied potential. Independent measurements of film thickness by EQCM and EIS indicate that at a potential of 5.5V vs. Li/Li{sup +}, the thickness of the AlF{sub 3} is approximately 1 nm.

Zhang, Xueyuan; Devine, T.M.

2006-09-01T23:59:59.000Z

164

Structural Evolution and Li Dynamics in Nanophase Li3PS4 by Solid-State and Pulsed Field Gradient NMR  

SciTech Connect (OSTI)

The ceramic lithium ion conductor -Li3PS4 has a disordered and nanoporous structure that leads to an enhancement in ionic conductivity by some three orders of magnitude compared to the crystalline phase. The phase is prepared by thermal treatment of an inorganic-organic complex based on Li3PS4 and THF. Multinuclear (1H, 6,7Li, 31P) solid state NMR spectroscopy is used to characterize the structural phase evolution of the starting material at various steps in the thermal treatment. The phase formed after high temperature treatment is recognized as spectroscopically distinct from the bulk -Li3PS4 compound. Also formed is an amorphous lithium thiophosphate phase that is metastable as verified by annealing over an extended period. Lithium ion self-diffusion coefficients are measurable by standard pulsed gradient NMR methods at 100oC and with values consistent with the high ionic conductivity previously reported for this material.

Gobet, Mallory [Hunter College of the City University of New York] [Hunter College of the City University of New York; Greenbaum, Steve [Hunter College of the City University of New York] [Hunter College of the City University of New York; Sahu, Gayatri [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

2014-01-01T23:59:59.000Z

165

The partially reversible formation of Li-metal particles on a solid Li electrolyte: applications toward nanobatteries  

SciTech Connect (OSTI)

The feasibility of large-scale implementation of Li-air batteries (LABs) hinges on understanding the thermodynamic and kinetic factors that control charge-discharge rates, efficiency and life times. Here, the kinetics of bias-induced reactions is explored locally on the surface of Li-ion conductive glass ceramics, a preferred electrolyte for LABs, using direct current-voltage and strain spectroscopies. Above a critical bias, particle growth kinetics were found to be linear in both the bias and time domains. Partial reversibility was observed for Li particles as evidenced by the presence of anodic peaks following the Li{sup +} reduction, as well an associated reduction in particle height. The degree of reversibility was highest for the smallest particles formed. These observations thus suggest the possibility of producing nanobatteries with an active anode volume of the order of 0.1 al.

Arruda, Thomas M [ORNL; Kumar, Amit [ORNL; Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL

2012-01-01T23:59:59.000Z

166

Electrochemical Behavior and Li Diffusion Study of LiCoO? Thin Film Electrodes Prepared by PLD  

E-Print Network [OSTI]

Preferred c-axis oriented LiCoO? thin films were prepared on the SiO?/Si (SOS) substrates by pulsed laser deposition (PLD). Thin film electrodes without carbon and binder are ideal samples to study the electrochemical ...

Xia, H.

167

Identifying the structure of the intermediate, Li_2/3CoPO_4, formed during electrochemical cycling of LiCoPO_4  

E-Print Network [OSTI]

, USA # Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, USA KEYWORDS: Lithium cobalt phosphate, nuclear magnetic resonance spectroscopy, X-ray diffraction, Li-ion batteries, cathodes, olivine... the b-direction. INTRODUCTION Olivine-type LiFePO4 1 has been extensively studied as a promising cathode material for Li-ion batteries, due to its good reversibility, safe operating voltage (3.45 V vs. Li/Li+) and high reversible capacity2 of 160 m...

Strobridge, Fiona C.; Clment, Raphale J.; Leskes, Michal; Middlemiss, Derek S.; Borkiewicz, Olaf J.; Wiaderek, Kamila M.; Chapman, Karena W.; Chupas, Peter J.; Grey, Clare P.

2014-10-09T23:59:59.000Z

168

DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries  

E-Print Network [OSTI]

power systems for automobiles. Electric vehicles (EVs) represent one of the main alternatives source. However, the present electric vehicles, powered by Li ion batteries, are limited in power in the cities produced by the fossil fuel-powered vehicles (FFVs) is forcing the development of alternative

Thygesen, Kristian

169

High Performance Cathodes for Li-Air Batteries  

SciTech Connect (OSTI)

The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

Xing, Yangchuan

2013-08-22T23:59:59.000Z

170

RenGyS | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to: navigation, searchVirginia Blue Ridge And PiedmontReminderville, Ohio:RenGen Energy

171

In-situ raman microscopy of individual LiNi0.8Co0.15Al0.05O2 particles in the Li-ion battery composite cathode  

E-Print Network [OSTI]

2 Particles in the Li-ion Battery Composite Cathode Jingleidegradation of various Li-ion battery systems has been the

Lei, Jinglei; McLarnon, Frank; Kostecki, Robert

2004-01-01T23:59:59.000Z

172

Li/Ca, B/Ca, and Mg/Ca Composition of Cultured Sea Urchin Spines and Paleo-Echinoderms Measured Using a Secondary Ion Mass Spectrometer  

E-Print Network [OSTI]

Benthic Foraminiferal Li/Ca: Insights into Cenozoic seawaterFig. 2). More recently, Li/Ca ratios in inorganic calciteresulting in higher Li/Ca ratios in calcite. a. 12 Li/Ca (

Nguyen, Trung Timothy Do

2013-01-01T23:59:59.000Z

173

1st Observation of the (Li-6, He-8) Reaction  

E-Print Network [OSTI]

PHYSICAL REVIEW C VOLUME 37, NUMBER 6 First observation of the ( Li, 'He) reaction JUNE 1988 C. A. Gagliardi, D. R. Semon, E. Takada, * D. M. Tanner, and R. E. Tribble Cyclotron Institute, Texas A&M University, College Station, Texas 77843... (Received 18 February 1988) We have measured the cross section of the Al( Li, He) Si reaction. At a scattering angle of 5.5' and a beam energy of 92.5 MeV, we find the laboratory cross section to populate the 'Si ground state doublet to be 3.6+1.0 nb...

Gagliardi, Carl A.; Semon, D. R.; Takada, E.; Tanner, D. M.; Tribble, Robert E.

1988-01-01T23:59:59.000Z

174

Rituels aux divinites locales de Kheng 'Bu li (Bhoutan central)  

E-Print Network [OSTI]

'ai reu beaucoup de donations en nature".18Padma gling pa ne mentionne donc pas dans sa biographie qu'il a "ouvertla porte" de 'Bu li, pays cach (sbas yul) comme le veut la tradition locale. Or,s'il avait accompli une action aussi prestigieuse... lha de 'Bu li29 et est marie au btsan (skyeslha). Tous les villageois doivent tre propres et sans pollution (grib), ce quiexclut les femmes en priode de menstruations et les personnes ayant eu undcs dans leur maison. Ce lac est en fait le bla...

Pommaret, Franoise

2004-01-01T23:59:59.000Z

175

Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Free Synthesis of LiV3O8 Nanorods as a Cathode Material for High-Rate Secondary Lithium Batteries . Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material for...

176

Lithium fluoride (LiF) crystal for parametric X-ray (PXR) production  

E-Print Network [OSTI]

Lithium fluoride (LiF) crystal for parametric X-ray (PXR) production B. Sones *, Y. Danon, R 2004 Abstract Parametric X-ray (PXR) production is reported using lithium fluoride (LiF) as a target

Danon, Yaron

177

BornOppenheimer breakdown in a combined-isotopomer analysis system of Li2  

E-Print Network [OSTI]

of 6,7 Li2 , and new Fourier transform data for the homonuclear lithium dimers. They are combined nonhydride systems for studying such interactions. Moreover, in view of the prominence of Li2 in studies

Le Roy, Robert J.

178

Thermal end effects on electroosmotic flow in a capillary Xiangchun Xuan, David Sinton, Dongqing Li *  

E-Print Network [OSTI]

Thermal end effects on electroosmotic flow in a capillary Xiangchun Xuan, David Sinton, Dongqing Li [16,17] etc.). Using caged-dye based flow visualization, Sinton and Li [18] found a slight curvature

Xuan, Xiangchun "Schwann"

179

Thermal Instability of Olivine-Type LiMnP04 Cathodes  

E-Print Network [OSTI]

Standard for Lithium Batteries, document 1642, 3 rd Edition,of high energy phosphate Li-ion batteries is discussed. 2.g. Thermal runaway of Li-ion batteries occurs when the heat

Chen, Guoying

2010-01-01T23:59:59.000Z

180

Preparation and electrochemical investigation of Li2CoPO4F cathode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electrochemical investigation of Li2CoPO4F cathode material forlithium-ion batteries. Preparation and electrochemical investigation of Li2CoPO4F cathode material forlithium-ion...

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Investigation of the Rechargeability of Li-O2 Batteries in Non...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Abstract: In order to...

182

Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Presentation from the U.S. DOE Office of...

183

Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CellPack Level Models for Automotive Li-Ion Batteries with Experimental Validation Development of CellPack Level Models for Automotive Li-Ion Batteries with Experimental...

184

Co-synthesis of LiFePO4 and Carbon Nanotubes  

E-Print Network [OSTI]

of LiFePO 4 and carbon nanotubes potentially bypassessynthesis of LiFePO 4 and Carbon Nanotubes James Wilcox* ,that multi-walled carbon nanotubes (MWCNTs, Figure 1) and

Wilcox, James; Doeff, Marca M.

2006-01-01T23:59:59.000Z

185

Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes. Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes. Abstract:...

186

Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-Ion Polymer Battery Cell Manufacturing Plant in USA Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

187

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. Abstract: Silicon is...

188

Effects of Laser Energy and Wavelength on the Analysis of LiFePO4...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser Assisted Atom Probe Tomography. Effects of Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser...

189

Li+ alumino-silicate ion source development for the Neutralized Drift Compression Experiment (NDCX-II)  

E-Print Network [OSTI]

LBNL-3748E Li+ alumino-silicate ion source development for05CH11231. Li + alumino-silicate ion source development forlithium from the alumino-silicate material either as ions or

Roy, P.K.

2011-01-01T23:59:59.000Z

190

Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...  

Broader source: Energy.gov (indexed) [DOE]

Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP...

191

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

lithium battery cathode. Electrochemical and Solid Statebattery performance of LiMn2O4 cathode. Solid State Ionics,

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

192

Rate coefficient for the chemi-ionization in slow Li*(n)+Li and Na*(n)+Na collisions  

SciTech Connect (OSTI)

The chemi-ionization processes in slow-atom-Rydberg-atom collisions are considered in this paper. A version of the semiclassical method of rate coefficient calculation that is free of the presumptions which significantly limited its applicability previously is presented. The method is applied to the cases of Li*(n)+Li and Na*(n)+Na collisions for the principal quantum numbers 5{<=}n{<=}25 and temperatures 600{<=}T{<=}1200 K. The results of calculation of the rate coefficients of the corresponding chemi-ionization processes are compared to the existing experimental data from the literature.

Ignjatovic, Lj.M.; Mihajlov, A.A. [Institute of Physics, P. O. Box 68, 11080 Zemun, Belgrade (Serbia and Montenegro)

2005-08-15T23:59:59.000Z

193

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)  

E-Print Network [OSTI]

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

Collum, David B.

194

Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries  

E-Print Network [OSTI]

Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries Dmitry Ruzmetov, all-solid-state Li ion batteries (LIBs) with high specific capacity and small footprint are highly to their high-energy density, Li ion batteries (LIBs) are attractive for these applications, and all-solid-state

Rubloff, Gary W.

195

The Senior University Ref. no. LiU-2010-00209  

E-Print Network [OSTI]

permeate all operations. LiU's long-term goals for the work environment are that LiU shall as an attractive work and study space. ! ! Work environment efforts LiU shall conduct work environment efforts' and the student unions. ! ! The work environment efforts shall be a natural part of all daily operations. In order

Zhao, Yuxiao

196

Stochastic reconstruction and electrical transport studies of porous cathode of Li-ion batteries  

E-Print Network [OSTI]

of the Li-ion batteries through developing electrode materials [1e5], reducing size [6] and optimizing shape,13], as one of the main factors limiting Li-ion battery performance, has not been resolved. Fundamental the ulti- mate performance and stability. Theoretical work of Li-ion batteries has focused on macroscopic

Liu, Fuqiang

197

Comment on Li pellet conditioning in tokamak fusion test reactor R. V. Budny  

E-Print Network [OSTI]

Comment on Li pellet conditioning in tokamak fusion test reactor R. V. Budny Princeton Plasma; published online 9 September 2011) Li pellet conditioning in TFTR results in a reduction of the edge technique for introducing Li is via pellet injection. This was pioneered in ALCATOR- CMOD where it was first

Budny, Robert

198

Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB  

E-Print Network [OSTI]

pitting corrosion of aluminum in 1M LiTFSI. The protectiveAnodic Polarization of Aluminum in 1:1 EC+DMC with 1M LiBOBdeposited thin film of aluminum in 1:1 EC+DMC with 1M LiBOB.

Zhang, Xueyuan; Devine, Thomas M.

2008-01-01T23:59:59.000Z

199

Li2O Particulate Flow Concept, APPLE APEX Interim Report November, 1999  

E-Print Network [OSTI]

Li2O Particulate Flow Concept, APPLE APEX Interim Report November, 1999 9-1 CHAPTER 9: Li2O PARTICULATE FLOW CONCEPT ­ APPLE DESIGN Contributors Lead Author: Dai Kai Sze Dai Kai Sze, Zhanhe Wang (ANL Particulate Flow Concept, APPLE APEX Interim Report November, 1999 9-2 9. LI2O PARTICULATE FLOW CONCEPT

California at Los Angeles, University of

200

Studies on Capacity Fade of Spinel based Li-Ion Batteries  

E-Print Network [OSTI]

Studies on Capacity Fade of Spinel based Li-Ion Batteries by P. Ramadass , A. Durairajan, Bala S To characterize the capacity fade phenomena of Li- ion batteries. To decrease the capacity fade on both positive the change in capacity of commercially available spinel based Li-ion Cells (Cellbatt cells). Study

Popov, Branko N.

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Development of First Principles Capacity Fade Model for Li-Ion Cells  

E-Print Network [OSTI]

developed to simulate the capacity fade of Li-ion batteries. Incorporation of a continuous occurrence a first principles capacity fade model for Li-ion batteries. Darling and Newman1 made a first attempt into a lithium-ion battery model. The model explains the self-discharge process occurring in Li-ion cells

Popov, Branko N.

202

Conduction in Multiphase ParticulateFibrous Networks Simulations and Experiments on Li-ion Anodes  

E-Print Network [OSTI]

promising Li-ion battery technologies incorporate nanoarchitectured carbon networks, typically in the form electronically February 7, 2003. Several promising Li-ion battery technologies incorporate nanoarchitecturedConduction in Multiphase Particulate?Fibrous Networks Simulations and Experiments on Li-ion Anodes

Sastry, Ann Marie

203

Engineering Recently, we created the first Li-ion electrochemical cell  

E-Print Network [OSTI]

characterization of Li-ion battery materials. In this presentation, I'll first review our latest progress of using for understanding important processes in Li-ion batteries. For example, liquid cells are required in order impact on the design of Li-ion batteries. Finally I will discuss outstanding challenging issues

204

Electrochimica Acta 51 (2006) 20122022 A generalized cycle life model of rechargeable Li-ion batteries  

E-Print Network [OSTI]

­discharge model to simulate the cycle life behavior of rechargeable Li-ion batteries has been developed. The model and Newman [4] made a first attempt to model the parasitic reaction in Li-ion batteries by assuming a solvent and reversible capacity loss due to the growth and dissolution of SEI film in Li-ion batteries. Ramadass et al

Popov, Branko N.

205

NANOMATERIALS FOR HIGH CAPACITY LI-ION BATTERIES Taylor Grieve, Iowa State University, SURF 2009 Fellow  

E-Print Network [OSTI]

NANOMATERIALS FOR HIGH CAPACITY LI-ION BATTERIES Taylor Grieve, Iowa State University, SURF 2009 energy storage devices continues to grow. Lithium-ion (Li-ion) secondary, or renewable, batteries are of interest due to their high energy and power characteristics. Performance enhancements of Li- ion batteries

Li, Mo

206

Short communication Enhanced autonomic shutdown of Li-ion batteries by polydopamine  

E-Print Network [OSTI]

Short communication Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated Accepted 9 July 2014 Available online 17 July 2014 Keywords: Li-ion batteries Thermal shutdown Polyethylene binder, applied onto a battery anode surface, dried, and incorporated into Li-ion coin cells. FTIR

Sottos, Nancy R.

207

New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy  

E-Print Network [OSTI]

an average voltage of 2.2 V vs Li/Li+ (about 60% of the voltage of conventional Li-ion batteries nanowires R echargeable batteries are critical power sources for mobile applications such as portable-11 the relatively low charge capacity of cathodes remains the limiting factor preventing higher energy density

Cui, Yi

208

Solar Photovoltaic Capacity F t P f d P li  

E-Print Network [OSTI]

6/19/2013 1 Solar Photovoltaic ­ Capacity F t P f d P li Generating Resources Advisory Committee Advisor Model (SAM), version 2013.1.15 Technology: Solar PV (PVWatts system model)Technology: Solar PV (MWh) (First year output, each year thereafter degrades 0.5%) 6 #12;6/19/2013 4 Shape of PNW Solar PV

209

-OK 8>00jigLi Metallurgy Department  

E-Print Network [OSTI]

-OK 8>00jigLi 00 tf) Ris-M-28B Metallurgy Department Publications 1988 Ris National Laboratory, DK-4000 Roskilde, Denmark August 1989 #12;Metallurgy Department Publications 1988 Edited by A by the staffof the Metallurgy Department during 1988 is given. The list comprises journal papers, conference

210

Generic Multiversion STM Li Lu and Michael L. Scott  

E-Print Network [OSTI]

Generic Multiversion STM Li Lu and Michael L. Scott Computer Science Department, University of Rochester Rochester, NY 14627-0226 USA {llu,scott}@cs.rochester.edu Abstract. Multiversion software by the National Science Foundation under grants CCR- 0963759, CCF-1116055, and CNS-1116109. Y. Afek (Ed.): DISC

Scott, Michael L.

211

Neutronic assessment of He-cooled molten Li fusion blanket  

SciTech Connect (OSTI)

This study is intended to assess overall neutronic performances of He-cooled molten Li (HCML) blanket with a reflector and investigate the impact of {sup 6}Li enrichment on tritium breeding ratio (TBR). To precisely evaluate the neutronic performances of the reflected HCML blanket, three-dimensional D-shape torus model is utilized and Monte-Carlo calculations are performed. In this study, the neutronic characteristics of five potential reflector candidates are compared and the reflected blanket is also optimized from the neutronic point of view. Taking into account the material availability and potential safety features, a high-density graphite reflector can be a practical choice for a high-performance HCML blanket. The graphite-reflected HCML blanket shows the best performances when the reflector is placed such that the blanket is divided into a thick front region and a thin back region. The HCML blanket with a slightly-enriched Li (8-10 wt% {sup 6}Li) breeder shows the highest TBR. (authors)

Han, B. [Nuclear Engineering Dept., Seoul National Univ., San 56-1, Shinlim-dong, Kwanak-gu, Seoul (Korea, Republic of); Kim, Y. [Korea Atomic Energy Research Inst., 150, Deokjin-dong, Yuseong-gu, Daejeon (Korea, Republic of); Kim, C. H. [Nuclear Engineering Dept., Seoul National Univ., San 56-1, Shinlim-dong, Kwanak-gu, Seoul (Korea, Republic of)

2006-07-01T23:59:59.000Z

212

Overview of design activities for Li/V blankets  

SciTech Connect (OSTI)

Recent fusion power plant design studies in the US have been conducted within the ARIES project. The most recent design of Li/V blankets was conducted as part of the ARIES-RS design. The ARIES-RS fusion power plant design study is based on reversed-shear (RS) physics with a Li/V (lithium breeder and vanadium structure) blanket. The reversed-shear discharge has been documented in many large tokamak experiments. The plasma in the RS mode has a high beta, low current, and low current drive requirement. Therefore, it is an attractive physics regime for a fusion power plant. The blanket system based on a Li/V has high temperature operating capability, good tritium breeding, excellent high heat flux removal capability, long structural life time, low activation, low after heat and good safety characteristics. For these reasons, the ARIES-RS reactor study selected Li/V as the reference blanket. The combination of attractive physics and attractive blanket engineering is expected to result in a superior power plant design.

Sze, D.K.; Mattas, R.F.

1997-12-31T23:59:59.000Z

213

How Many Species Can Two Essential Resources Support? Bingtuan Li #  

E-Print Network [OSTI]

and for two species to coexist, driving the others to extinction. In case n = 3, it is shown that every extinct. Every solution approaches a singlespecies or twospecies steady state. However, as already notedHow Many Species Can Two Essential Resources Support? Bingtuan Li # Department of Mathematics

214

Phase transitions in the adsorption system Li/Mo(112)  

E-Print Network [OSTI]

Experimental studies of the phase transitions in the adsorption system Li/Mo(112) are presented. This system is a model system for highly anisotropic interactions. From measurements of the half-widths of the low-energy electron diffraction spot...

Fedorus, A.; Kolthoff, D.; Koval, V.; Lyuksyutov, Igor F.; Naumovets, AG; Pfnur, H.

2000-01-01T23:59:59.000Z

215

Carbon Nanotube GHz Nano-Resonator Shengdong Li1  

E-Print Network [OSTI]

Carbon Nanotube GHz Nano-Resonator Shengdong Li1 , Zhen Yu1 , Sheng-Feng Yen1 , Peter J. Burke1 walled carbon nanotube. Both semiconducting and metallic nanotubes are measured. Using a semiconducting signal processing components based on carbon nanotubes. Index Terms -- Nanotechnology, Resonators, Tuning

Tang, William C

216

A Lattice Energy Calculation for LiH Frank Rioux  

E-Print Network [OSTI]

energy operators for each of the electrons, and an electron-electron potential energy operator. HLi 1 2 r d d 2 1 r1 1 r2 1 r12 = When the trial wavefunction and the appropriate energy operator is usedA Lattice Energy Calculation for LiH Frank Rioux Lithium hydride is a white crystalline solid

Rioux, Frank

217

LiU E-Press Newsletter Autumn, 2006  

E-Print Network [OSTI]

that virtually all Ph.D., licentiate and undergraduate theses are published on the internet through E at least 90% of the Ph.D. the- ses, licentiate theses and undergraduate theses that are produced at Li publishing of articles. Licentiate theses follow a similar trend (and percentages) to those shown for Ph

Zhao, Yuxiao

218

High Voltage Electrolytes for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

0.992 0.994 0.996 0.998 1 0 100 200 300 400 500 600 700 Baseline: 1.2 M LiPF 6 in ECEMC (30:70) Baseline + 5 mM PFBP Baseline + 10 mM AFAC Cycle Number ANL LMNOGR Full Cells...

219

The Grid Workloads Archive Alexandru Iosup a,, Hui Li b  

E-Print Network [OSTI]

The Grid Workloads Archive Alexandru Iosup a,, Hui Li b , Mathieu Jan a , Shanny Anoep a , Catalin, The Netherlands Abstract While large grids are currently supporting the work of thousands of scientists, very or no traces of grid workloads available to the grid researcher and practitioner. To address this problem

Iosup, Alexandru

220

Lithium Lorentz Force Accelerator Thruster (LiLFA)  

E-Print Network [OSTI]

Argon Flow Copper Water Flow Piston/Lithium Feeding System Lithium Flow Pipes Heaters Heaters MAI Li procedure · Fire the thruster! #12;Previous Firing #12;Conclusions · Heaters and Thermocouples · Water Vacuum Pumps Thrust Stand Main Tank Water Line In Water Line Out Power Lines Computer Data Acquisition

Petta, Jason

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Method for treating electrolyte to remove Li.sub.2 O  

DOE Patents [OSTI]

A method of removing Li.sub.2 O present in an electrolyte predominantly of LiCl and KCl. The electrolyte is heated to a temperature not less than about 500.degree. C. and then Al is introduced into the electrolyte in an amount in excess of the stoichiometric amount needed to convert the Li.sub.2 O to a Li-Al alloy and lithium aluminate salt. The salt and aluminum are maintained in contact with agitation for a time sufficient to convert the Li.sub.2 O.

Tomczuk, Zygmunt (Lockport, IL); Miller, William E. (Naperville, IL); Johnson, Gerald K. (Downers Grove, IL); Willit, James L. (Batavia, IL)

1998-01-01T23:59:59.000Z

222

Maximum Li storage in Si nanowires for the high capacity three-dimensional Li-ion battery  

E-Print Network [OSTI]

, such as fuel cells and secondary batteries. Here we report a coin-type Si nanowire NW half-cell Li-ion battery is the central research subject in various energy conversion systems, such as solar cells, fuel cells must be optimally coordinated.7 In this respect, Si nanowire NW arrays can serve as the high capacity

Jo, Moon-Ho

223

LiMnPO4 Nanoplate Grown via Solid-State Reaction in Molten Hydrocarbon for Li-ion Battery Cathode  

SciTech Connect (OSTI)

Electrochemically active LiMnPO4 nanoplates have been synthesized via novel single step solid state reaction in molten hydrocarbon. The LiMnPO4 prepared show unique porous nanoplate shape ~50nm in thickness with highly preferred crystallographic orientation. The reversible cycling of carbon coated LiMnPO4 show flat potential at 4.1 V vs. Li with specific capacity reaching up to 168mAh/g and excellent cycling performance using only galvanostatic charging / discharging mode.

Choi, Daiwon; Wang, Donghai; Bae, In-Tae; Xiao, Jie; Nie, Zimin; Wang, Wei; Viswanathan, Vilayanur V.; Lee, Yun Jung; Zhang, Jiguang; Graff, Gordon L.; Yang, Zhenguo; Liu, Jun

2010-08-11T23:59:59.000Z

224

Corrosion and anodic behavior of lithium in solutions of the system LiC1-LiOH-H/sub 2/O  

SciTech Connect (OSTI)

The study of the electrochemical behavior of lithium in aqueous electrolyte solutions is of interest to the development of water-activated electrochemical cells. This paper reports the results of a study of the electrochemical behavior of lithium in solutions of the system LiC1-LiOH-H/sub 2/O ( /SUP m/ LiC1 = 0.4-1.2, /SUP m/ LiOH = 3.1-4.2, where m is the molality) at 298 K. Solutions of the specificed compositions have the highest conductivity in this system. The LiC1 and LiOH concentrations in solutions of the specified compositions were found by analytical determination of their chloride and hydroxide ion contents. The investigations show that addition of lithium chloride to the LiOH-H/sub 2/O electrolyte lowers the rate of lithium corrosion in solution by a factor of 1.5-4. The influence of added LiC1 on the corrosion rate of the metal is stronger in electrolytes of lower LiOH concentrations.

Konstantinova, M.V.; Demidov, A.I.; Morachevskii, A.G.

1986-03-10T23:59:59.000Z

225

Enhanced rate capability of LiMn0.9Mg0.1PO4 nanoplates by reduced graphene oxide/carbon double coating for Li-ion batteries  

E-Print Network [OSTI]

coating for Li-ion batteries Sungun Wi a , Jaewon Kim a , Seunghoon Nam a , Joonhyeon Kang a , Sangheon March 2014 Available online 12 March 2014 Keywords: Li-ion battery LiMnPO4 Reduced graphene oxide Charge) nanoplates are intro- duced as a cathode material for Li-ion batteries with excellent rate capability

Park, Byungwoo

226

The predicted crystal structure of Li4C6O6, an organic cathode material for Li-ion batteries, from first-principles multi-level computational methods  

E-Print Network [OSTI]

The predicted crystal structure of Li4C6O6, an organic cathode material for Li-ion batteries, from details for the electrochemical properties of these organic electrodes (chemical potential for Li ion the optimum positions of Li ions intercalated within each C6O6 framework. 3. We then optimized each

Goddard III, William A.

227

The Stability of Organic Solvents and Carbon Electrode in Nonaqueous Li-O2 Batteries  

SciTech Connect (OSTI)

The effect of different kinds of aprotic organic solvents on the discharge performance and discharge products in Li-O2 batteries was systematically investigated. The discharge products deposited in air cathodes were analyzed by X-ray diffraction, in situ gas chromatography/mass spectroscopy and X-ray photoelectron spectroscopy. We found that a significant amount of Li2O2 can be formed in glyme-based electrolytes during the discharge process, while only small amount of Li2O2 is produced in electrolytes of phosphate, nitrile, ionic liquid and sulfoxide. However, in all the seven types of solvent systems we studied, Li2CO3 and LiF were still formed as byproducts whose compositions are strongly related to the solvents. Li2CO3 is produced not from the carbon air electrode but from oxidation and decomposition of the solvent as we verified by using a 13C-labeled carbon electrode and the solid-state 13C-MAS NMR technique. The formation of Li2CO3 and LiF during discharge will greatly reduce the Coulombic efficiency and cycle life of the Li-air batteries. Therefore, better electrolytes that can ensure the formation of Li2O2 but minimize other reaction products formed on air electrodes of Li-air batteries need to be further investigated.

Xu, Wu; Hu, Jian Z.; Engelhard, Mark H.; Towne, Silas A.; Hardy, John S.; Xiao, Jie; Feng, Ju; Hu, Mary Y.; Zhang, Jian; Ding, Fei; Gross, Mark E.; Zhang, Jiguang

2012-05-18T23:59:59.000Z

228

On the electrochemical reactivity and design of NiP2 negative electrodes for secondary Li-ion batteries  

E-Print Network [OSTI]

commercialisation, rechargeable Li-ion batteries are widely accepted, and are becoming the main power source1 On the electrochemical reactivity and design of NiP2 negative electrodes for secondary Li-ion study of cubic and monoclinic NiP2 polymorphs towards Li, as candidate for anodic applications for Li-ion

Boyer, Edmond

229

Effect of LiAlO{sub 2} nanoparticle filler concentration on the electrical properties of PEOLiClO{sub 4} composite  

SciTech Connect (OSTI)

Highlights: ? Structural modification of nano LiAlO{sub 2} filler increased conductivity. ? Good ionic conductivity for (LiAlO{sub 2}){sub 1.5}(PEO){sub 11}(LiClO{sub 4}) at room temperature. ? Nano LiAlO{sub 2} filler enhanced both ion migration and orientation. ? High dielectric properties for (LiAlO{sub 2}){sub 1.5}(PEO){sub 11}(LiClO{sub 4}) at room temperature. - Abstract: Nano-composite polymer electrolytes are receiving attention as potential candidates to be used as electrolyte membranes in lithium polymer batteries and other devices. In this work, polyethylene oxideLiClO{sub 4} based composite polymer electrolyte was prepared by solution casting method. The effect of LiAlO{sub 2} nanoparticle ceramic filler concentration on the structure and electrical conduction of the composite was studied. Nano-LiAlO{sub 2} was synthesized by solgel method. The samples were characterized using X-ray diffraction, Fourier Transmission-Infra Red, Differential Scanning Calorimetry, and tested by dielectric properties, Direct and Alternating current measurements as well as by impedance spectroscopy. All samples showed a behavior referring to an ionic conduction. Generally, the melting temperature of the polymer electrolyte decreased with filler concentration. Both thermal property and filler concentration influenced conductivity value. At room temperature, the highest ionic conductivity was 9.76 10{sup ?5} ohm{sup ?1} cm{sup ?1} for sample with a composition of (LiAlO{sub 2}){sub 1.5}(polyethylene oxide){sub 11}(LiClO{sub 4}). All results were correlated and discussed.

Masoud, E.M., E-mail: emad_masoud1981@yahoo.com [Chemistry Department, Faculty of Science, Benha University, Benha (Egypt); El-Bellihi, A.-A.; Bayoumy, W.A.; Mousa, M.A. [Chemistry Department, Faculty of Science, Benha University, Benha (Egypt)

2013-03-15T23:59:59.000Z

230

Subbarrier fusion of {sup 9}Li with {sup 70}Zn  

SciTech Connect (OSTI)

The cross section for the fusion of {sup 9}Li with {sup 70}Zn was measured for seven projectile energies spanning the subbarrier and near-barrier region (E{sub c.m.} ranging from 9.7 to 13.4 MeV) using the ISAC facility at TRIUMF. {gamma}-ray spectroscopy of the irradiated target foils along with {beta} counting of the chemically separated Ge and As evaporation residues were used to measure the fusion cross sections. Statistical model calculations were used to correct for the yields of any unobserved nuclei. The observed fusion excitation function shows significant subbarrier fusion enhancement with a large deduced value of the fusion radius, R{sub B}=12.1{+-}1.0 fm. Coupled-channels calculations do not account for the observed subbarrier enhancement. The implications of this finding for understanding the fusion of {sup 11}Li are discussed.

Loveland, W.; Vinodkumar, A. M.; Naik, R. S.; Sprunger, P. H.; Matteson, B.; Neeway, J. [Department of Chemistry, Oregon State University, Corvallis, Oregon 97331 (United States); Trinczek, M.; Dombsky, M.; Machule, P.; Ottewell, D. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada); Cross, D. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada); Department of Chemistry, Simon Fraser University, Burnaby, British Columbia, V5A 1S6 (Canada); Gagnon, K.; Mills, W. J. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada); Department of Physics, Simon Fraser University, Burnaby, British Columbia, V5A 1S6 (Canada)

2006-12-15T23:59:59.000Z

231

Electrochemical properties of all solid state Li/S battery  

SciTech Connect (OSTI)

All-solid-state lithium/sulfur (Li/S) battery is prepared using siloxane cross-linked network solid electrolyte at room temperature. The solid electrolytes show high ionic conductivity and good electrochemical stability with lithium and sulfur. In the first discharge curve, all-solid-state Li/S battery shows three plateau potential regions of 2.4 V, 2.12 V and 2.00 V, respectively. The battery shows the first discharge capacity of 1044 mAh g{sup ?1}-sulfur at room temperature. This first discharge capacity rapidly decreases in 4th cycle and remains at 512 mAh g{sup ?1}-sulfur after 10 cycles.

Yu, Ji-Hyun; Park, Jin-Woo; Wang, Qing; Ryu, Ho-Suk; Kim, Ki-Won [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)] [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of); Ahn, Jou-Hyeon [Department of Chemical and Biological Engineering, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering, Gyeongsang National University, Jinju 660-701 (Korea, Republic of); Kang, Yongku [Korea Research Institute of Chemical Technology, Daejeon 305-600 (Korea, Republic of)] [Korea Research Institute of Chemical Technology, Daejeon 305-600 (Korea, Republic of); Wang, Guoxiu [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of) [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of); School of Chemistry and Forensic Science, University of Technology Sydney, Broadway, Sydney, NSW 2007 (Australia); Ahn, Hyo-Jun, E-mail: ahj@gnu.ac.kr [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)] [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)

2012-10-15T23:59:59.000Z

232

Corrosion behavior of 8090 Al-Li alloy  

SciTech Connect (OSTI)

An evaluation was conducted of the corrosion behavior of 8090 aluminum-lithium (Al-Li) alloy (UNS A98090), when aged under various conditions and subjected to corrosion in a solution of 3.5% NaCl + 1% H[sub 2]O[sub 2]. Susceptibility to pitting, intergranular corrosion, and exfoliation corrosion was shown to be influenced by heat treatment, which reduced from natural aging, through overaging to peak aging, Materials with peak aging showed low corrosion resistance. The decreased corrosion resistance corresponded to decreased corrosion potential of the alloy. Insoluble constituents were susceptible to corrosion. The corrosion extended along grain boundaries. Al-Li alloys showed mismatched tensile strength and stress corrosion resistance. The growth rate of stress corrosion cracks was large in the peak-aged state. The growth rate was strengthened by overaging, but tensile strength was reduced. That problem was solved by retrogression and reaging processing.

Hu, Z.Q.; Zhang, Y.; Liu, Y.L. (Academia Sinica, Shenyang (China). Inst. of Metal Research); Zhu, Z.Y. (Academia Sinica, Shenyang (China). Inst. of Corrosion and Protection of Metals)

1993-06-01T23:59:59.000Z

233

LiDAR (Laney, 2005) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey, Washington:Lakeville,LeightonLeola,Meadow,LevyLexingtonLeyden, NewLiDAR

234

Solvate Structures and Computational/Spectroscopic Characterization of LiBF4 Electrolytes  

SciTech Connect (OSTI)

Crystal structures have been determined for both LiBF4 and HBF4 solvates?(acetonitrile)2:LiBF4, (ethylene glycol diethyl ether)1:LiBF4, (diethylene glycol diethyl ether)1:LiBF4, (tetrahydrofuran)1:LiBF4, (methyl methoxyacetate)1:LiBF4, (suc-cinonitrile)1:LiBF4, (N,N,N',N",N"-pentamethyldiethylenetriamine)1:HBF4, (N,N,N',N'-tetramethylethylenediamine)3/2:HBF4 and (phenanthroline)2:HBF4. These, as well as other known LiBF4 solvate structures, have been characterized by Raman vibrational spectroscopy to unambiguously assign the anion Raman band positions to specific forms of BF4-...Li+ cation coordination. In addition, complementary DFT calculations of BF4-...Li+ cation complexes have provided additional insight into the challenges associated with accurately interpreting the anion interactions from experimental Raman spectra. This information provides a crucial tool for the characterization of the ionic association interactions within electrolytes.

Seo, D. M.; Boyle, Paul D.; Allen, Joshua L.; Han, Sang D.; Jonsson , Erlendur; Johansson, Patrik; Henderson, Wesley A.

2014-07-21T23:59:59.000Z

235

Revisit Carbon/Sulfur Composite for Li-S Batteries  

SciTech Connect (OSTI)

To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

2013-07-23T23:59:59.000Z

236

High Capacity Pouch-Type Li-air Batteries  

SciTech Connect (OSTI)

The pouch-type Li-air batteries operated in ambient condition are reported in this work. The battery used a heat sealable plastic membrane as package material, O2 diffusion membrane and moisture barrier. The large variation in internal resistance of the batteries is minimized by a modified separator which can bind the cell stack together. The cells using the modified separators show improved and repeatable discharge performances. It is also found that addition of about 20% of 1,2-dimethoxyethane (DME) in PC:EC (1:1) based electrolyte solvent improves can improve the wetability of carbon electrode and the discharge capacities of Li-air batteries, but further increase in DME amount lead to a decreased capacity due to increase electrolyte loss during discharge process. The pouch-type Li-air batteries with the modified separator and optimized electrolyte has demonstrated a specific capacity of 2711 mAh g-1 based on carbon and a specific energy of 344 Wh kg-1 based on the complete batteries including package.

Wang, Deyu; Xiao, Jie; Xu, Wu; Zhang, Jiguang

2010-05-05T23:59:59.000Z

237

Predictive Models of Li-ion Battery Lifetime (Presentation)  

SciTech Connect (OSTI)

Predictive models of Li-ion battery reliability must consider a multiplicity of electrochemical, thermal and mechanical degradation modes experienced by batteries in application environments. Complicating matters, Li-ion batteries can experience several path dependent degradation trajectories dependent on storage and cycling history of the application environment. Rates of degradation are controlled by factors such as temperature history, electrochemical operating window, and charge/discharge rate. Lacking accurate models and tests, lifetime uncertainty must be absorbed by overdesign and warranty costs. Degradation models are needed that predict lifetime more accurately and with less test data. Models should also provide engineering feedback for next generation battery designs. This presentation reviews both multi-dimensional physical models and simpler, lumped surrogate models of battery electrochemical and mechanical degradation. Models are compared with cell- and pack-level aging data from commercial Li-ion chemistries. The analysis elucidates the relative importance of electrochemical and mechanical stress-induced degradation mechanisms in real-world operating environments. Opportunities for extending the lifetime of commercial battery systems are explored.

Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G.; Shi, Y.; Pesaran, A.

2014-09-01T23:59:59.000Z

238

Development of Li+ alumino-silicate ion source  

SciTech Connect (OSTI)

To uniformly heat targets to electron-volt temperatures for the study of warm dense matter, one strategy is to deposit most of the ion energy at the peak of energy loss (dE/dx) with a low (E< 5 MeV) kinetic energy beam and a thin target[1]. Lower mass ions have a peak dE/dx at a lower kinetic energy. To this end, a small lithium (Li+) alumino-silicate source has been fabricated, and its emission limit has been measured. These surface ionization sources are heated to 1000-1150 C where they preferentially emit singly ionized alkali ions. Alumino-silicates sources of K+ and Cs+ have been used extensively in beam experiments, but there are additional challenges for the preparation of high-quality Li+ sources: There are tighter tolerances in preparing and sintering the alumino-silicate to the substrate to produce an emitter that gives uniform ion emission, sufficient current density and low beam emittance. We report on recent measurements ofhigh ( up to 35 mA/cm2) current density from a Li+ source. Ion species identification of possible contaminants is being verified with a Wien (E x B) filter, and via time-of-flight.

Roy, P.K.; Seidl, P.A.; Waldron, W.; Greenway, W.; Lidia, S.; Anders, A.; Kwan, J.

2009-04-21T23:59:59.000Z

239

Asymptotic normalization coefficients for B-8 -> Be-7+p from a study of Li-8 -> Li-7+n  

E-Print Network [OSTI]

nuclei, and charge symmetry implies that the spectroscopic amplitudes for the proton single particle orbitals entering the 8B wave 0556-2813/2003/67~6!/062801~5!/$20.00 67 062801- B\\7Be?p from a study of 8Li\\7Li?n ,1 Y.-W. Lui,1 A. M. Mukhamedzhanov.../Oxford University Press, New York, 1983!. @29# L. Trache, A. Azhari, H.L. Clark, C.A. Gagliardi, Y.-W. Lui, A.M. Mukhamedzhanov, R.E. Tribble, and F. Carstoiu, Phys. Rev. C 61, 024612 ~2000!. @30# M. Rhoades-Brown, M.H. Macfarlane, and S.C. Pieper, Phys. Rev. C...

Trache, L.; Azhari, A.; Carstoiu, F.; Clark, HL; Gagliardi, Carl A.; Lui, YW; Mukhamedzhanov, AM; Tang, X.; Timofeyuk, N.; Tribble, Robert E.

2003-01-01T23:59:59.000Z

240

Effect of Li Promoter on titania-supported Rh catalyst for ethanol formation from CO hydrogenation  

SciTech Connect (OSTI)

The addition of 0.10wt% Li to Rh/TiO2 more than doubled the CO conversion for CO hydrogenation while increasing ethanol selectivity. The addition of Li also increases formation of C2 oxygenates at the expense of C1 species, methanol and methane. This is attributed to enhanced dispersion of Rh by Li that appears to reduce dissociation of CO, which previous studies have shown requires large ensembles of Rh atoms on the surface. Li promotion appears to increase the associatively adsorbed CO, allowing for increased H2 chemisorption on the surface compared to the dissociative adsorption of the same number of CO atoms. This increases selectivity to ethanol compared to the unpromoted catalysts. CO-TPD shows more reactive adsorbed CO species on the Li-promoted catalyst. FTIR results suggest that Li promotion alters CO bonding at bridged or interfacial sites and its effect is more structural than electronic.

Egbebi, Adefemi [Louisiana State University; Overbury, Steven {Steve} H [ORNL; Schwartz, Viviane [ORNL; Spivey, James J [Louisiana State University

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Crystal structure and chemical bonding of novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}  

SciTech Connect (OSTI)

A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} has been synthesized using the high-temperature reaction method and characterized by both powder and single-crystal X-ray diffractions. The title compound crystallized in the orthorhombic crystal system (space group Immm, Z=2, Pearson symbol oI78) with fifteen crystallographically unique atomic positions in the asymmetric unit, and the lattice parameters are refined as a=4.5244(4) A, b=6.9932(6) A, and c=53.043(5) A. The complex crystal structure of the title compound can be described as a 2:1 intergrowth of two closely related compounds: La{sub 2}Li{sub 2}Ge{sub 3} (Ce{sub 2}Li{sub 2}Ge{sub 3}-type) and La{sub 3}Li{sub 4}Ge{sub 4} (Zr{sub 3}Cu{sub 4}Si{sub 4}-type) acting like 'building-blocks' along the c-axis. Six La sites are categorized into three distinct types based on the local coordination environment showing the coordination numbers of 12-14. Three unique Li sites are placed in the centers of local tetrahedra formed by four Ge atoms which eventually construct Ge{sub 2} dimers or 1-dimensional cis-/trans-Ge chains. Theoretical investigations using the tight-binding linear muffin-tin orbital (LMTO) method provide rationales for an improved structural stability and for unique local coordination geometries established by anionic elements including [LiGe{sub 4}] tetrahedra, cis-/trans-Ge chain and Ge{sub 2} dimers. - Graphical abstract: Reported is a novel ternary Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}. The complex crystal structure can be viewed as a simple combination of two closely related known compounds acting as 'building-blocks', La{sub 2}Li{sub 2}G{sub 3} and La{sub 3}Li{sub 4}Ge{sub 4}, in a 2:1 stoichiometric ratio. Highlights: Black-Right-Pointing-Pointer A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} was synthesized. Black-Right-Pointing-Pointer The complex crystal structure was easily explained as a combination of two known compounds. Black-Right-Pointing-Pointer Theoretical calculations indicated that the Fermi level was located near the pseudogap.

Jung, Yaho; Nam, Gnu; Jeon, Jieun; Kim, Youngjo [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of)] [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of); You, Tae-Soo, E-mail: tsyou@chungbuk.ac.kr [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of)] [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of)

2012-12-15T23:59:59.000Z

242

IV. -PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE  

E-Print Network [OSTI]

IV. - PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE P. BERNSTEIN and T'effet photomagnCtique dans le ferrite Fez,I oLi0.45Mn0.4504 au moyen de la variation de la perm investigated in a Fez.loLi0.45Mn0.4504ferrite by looking at the variations of the permeability under light

Paris-Sud XI, Université de

243

Thermal Abuse Modeling of Li-Ion Cells and Propagation in Modules (Presentation)  

SciTech Connect (OSTI)

The objectives of this paper are: (1) continue to explore thermal abuse behaviors of Li-ion cells and modules that are affected by local conditions of heat and materials; (2) use the 3D Li-ion battery thermal abuse 'reaction' model developed for cells to explore the impact of the location of internal short, its heating rate, and thermal properties of the cell; (3) continue to understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-ion cells and modules; and (4) explore the use of the developed methodology to support the design of abuse-tolerant Li-ion battery systems.

Kim, G.-H.; Pesaran, A.; Smith, K.

2008-05-01T23:59:59.000Z

244

Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte  

SciTech Connect (OSTI)

In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

2011-07-01T23:59:59.000Z

245

Structural Analysis of Southern Dixie Valley using LiDAR and...  

Open Energy Info (EERE)

Structural Analysis of Southern Dixie Valley using LiDAR and Low-Sun-Angle Aerial Photography, NAS Fallon Geothermal Exploration Project, Dixie Valley, Nevada Jump to: navigation,...

246

Study of Li-ion Cell Formation Parameters using "Gen3" Electrode...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

merit08gering1.pdf More Documents & Publications Statistical Design of Experiment for Li-ion Cell Formation Parameters using Gen3 Electrode Materials: Final Summary Vehicle...

247

Li+ alumino-silicate ion source development for the Neutralized Drift Compression Experiment (NDCX)  

E-Print Network [OSTI]

Li + alumino-silicate ion source development for theresults on lithium alumino-silicate ion source developmentfor a lithium alumino-silicate source is determined by the

Roy, Prabir K.

2010-01-01T23:59:59.000Z

248

First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System  

SciTech Connect (OSTI)

Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

2011-07-28T23:59:59.000Z

249

Investigation on the Charging Process of Li2O2-Based Air Electrodes in Li-O2 Batteries with Organic Carbonate Electrolytes  

SciTech Connect (OSTI)

The charge processes of Li-O2 batteries were investigated by analyzing the gas evolution by in situ gas chromatography-mass spectroscopy (GC/MS) technique. The mixture of Li2O2/Fe3O4/Super P carbon/polyvinylidene fluoride (PVDF) was used as the starting air electrode material and 1M LiTFSI in carbonate-based solvents was used as electrolyte. It was found that Li2O2 is reactive to 1-methyl-2-pyrrolidinone and PVDF binder used in the electrode preparation. During the 1st charge (up to 4.6 V), O2 was the main component in the gases released. The amount of O2 measured by GC/MS was consistent with the amount of Li2O2 decomposed in the electrochemical process as measured by the charge capacity, indicative of the good chargeability of Li2O2. However, after the cell was discharged to 2.0 V in O2 atmosphere and re-charged to ~ 4.6 V in the second cycle, CO2 was dominant in the released gases. Further analysis of the discharged air electrode by X-ray diffraction and Fourier transform infrared spectroscopy indicated that lithium-containing carbonate species (lithium alkyl carbonate and/or Li2CO3) were the main reaction products. Therefore, compatible electrolyte and electrodes as well as the electrode preparation procedures need to be developed for long term operation of rechargeable Li-O2 or Li-air batteries.

Xu, Wu; Viswanathan, Vilayanur V.; Wang, Deyu; Towne, Silas A.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Zhang, Jiguang

2011-04-15T23:59:59.000Z

250

Optical-Model Parameters for the C-12(li-7,li-7)c-12 Reaction at 63 and 78.7 Mev  

E-Print Network [OSTI]

PHYSICAL REVIE% C VOLUME 22, NUMBER 4 OCTOBER 1980 Optical model parameters for the "C('Li,'Li)"C reaction at 63 and 78.7 MeV A. F. Zeller, *Y. -W. Lui, R. E. Tribble, and D. M. Tanner Cyclot'ron Institute, Texas Ac%M University, College Station... extracted from I i inelastic scattering. 1538 ZELLER, LUI, TRIBBLE, AND TANNER 22 IV. CONCLUSION The present analysis of the 'Li scattering on "C shows that a single potential set does not ap- pear to describe the data in the energy range from 48 to 78...

Zeller, A. F.; Lui, YW; Tribble, Robert E.; Tanner, D. M.

1980-01-01T23:59:59.000Z

251

LiWall Fusion - The New Concept of Magnetic Fusion  

SciTech Connect (OSTI)

Utilization of the outstanding abilities of a liquid lithium layer in pumping hydrogen isotopes leads to a new approach to magnetic fusion, called the LiWall Fusion. It relies on innovative plasma regimes with low edge density and high temperature. The approach combines fueling the plasma by neutral injection beams with the best possible elimination of outside neutral gas sources, which cools down the plasma edge. Prevention of cooling the plasma edge suppresses the dominant, temperature gradient related turbulence in the core. Such an approach is much more suitable for controlled fusion than the present practice, relying on high heating power for compensating essentially unlimited turbulent energy losses.

L.E. Zakharov

2011-01-12T23:59:59.000Z

252

Making Li-air batteries rechargeable: material challenges. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and InterfacesAdministration -Lowellfor 2013 |Spherical Effective UseLi-air

253

Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /  

E-Print Network [OSTI]

active material for Li-ion battery, Fe2OF4. ElectrochemistryIron Fluoride, in a Li Ion Battery: A Solid-State NMR, X-raymaterials for Li-ion battery133 8.2. P2 type

Lee, Dae Hoe

2013-01-01T23:59:59.000Z

254

Guyana REDD+ Investment Fund (GRIF) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio:Greer County is a county inAl.,20454°, -74.0037505° Loading

255

Guyana-Regional Implementation Plan for CARICOM's Climate Change  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio:Greer County is a county inAl.,20454°, -74.0037505°

256

Guyana-Caribbean Community (CARICOM) Sustainable Energy Roadmap and  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to:Photon Place:Net JumpStrategy | Open Energy Information

257

Investigation of Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Field  

SciTech Connect (OSTI)

Abstract The significantly enhanced spectral resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical environmental changes associated with mechanical activation of Li-N-H system using high energy balling milling. Complementary to ultra-high field studies, the hydrogen discharge dynamics are investigated using variable temperature in situ 1H MAS NMR at 7.05 tesla field. The significantly enhanced spectral resolution using ultra-high filed of 21.1 tesla was demonstrated along with several major findings related to mechanical activation, including the upfield shift of the resonances in 6Li MAS spectra induced by ball milling, more efficient mechanical activation with ball milling at liquid nitrogen temperature than with ball milling at room temperature, and greatly enhanced hydrogen discharge exhibited by the liquid nitrogen ball milled samples.

Hu, Jian Zhi; Kwak, Ja Hun; Yang, Zhenguo; Osborn, William; Markmaitree, Tippawan; Shaw, Leonard D.

2008-07-15T23:59:59.000Z

258

E-Print Network 3.0 - alkali metal li Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

them together with a variety of optical data for alkali metals, and for Li... mopt PH PJM Li 1.153 1.526 Na 1.049 1.040 K 1.014 0.983 Rb 0.977 0.909 Cs 0.983 0.872 55 13...

259

A new family of locally 5arc transitive Michael Giudici a, Cai Heng Li a  

E-Print Network [OSTI]

A new family of locally 5­arc transitive graphs Michael Giudici a, Cai Heng Li a Cheryl E. Praeger@maths.uwa.edu.au (Cai Heng Li), praeger@maths.uwa.edu.au (Cheryl E. Praeger). Preprint submitted to Elsevier Science 17

Giudici, Michael

260

Static magnetic and microwave properties of Li-ferrite films prepared by pulsed laser deposition  

E-Print Network [OSTI]

Static magnetic and microwave properties of Li-ferrite films prepared by pulsed laser deposition F University, Fort Collins, Colorado 80523 Highly textured Li-ferrite films have been synthesized by pulsed approaching 1000 °C the growth mode was predominantly 333 . A similar growth mode was recently reported for Ni-ferrite

Patton, Carl

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For...

262

LiDAR observations of offshore winds at future wind turbine operating heights  

E-Print Network [OSTI]

LiDAR observations of offshore winds at future wind turbine operating heights Alfredo Peña1 , Sven at the Horns Rev offshore wind farm. The influence of atmospheric stability on the surface layer wind shear: Charnock, LiDAR, Marine boundary layer, Offshore, Surface layer, Wind profile. 1 Introduction There is

263

AN OBATA-TYPE THEOREM IN CR GEOMETRY SONG-YING LI AND XIAODONG WANG  

E-Print Network [OSTI]

AN OBATA-TYPE THEOREM IN CR GEOMETRY SONG-YING LI AND XIAODONG WANG Abstract. We discuss a sharp. 1 #12;2 SONG-YING LI AND XIAODONG WANG the proof of the Bochner formula in [G]. Due to this error

Wang, Xiaodong

264

Ultra-high hydrogen storage capacity of Li-decorated graphyne: A first-principles prediction  

SciTech Connect (OSTI)

Graphyne, consisting of sp- and sp{sup 2}-hybridized carbon atoms, is a new member of carbon allotropes which has a natural porous structure. Here, we report our first-principles calculations on the possibility of Li-decorated graphyne as a hydrogen storage medium. We predict that Li-doping significantly enhances the hydrogen storage ability of graphyne compared to that of pristine graphyne, which can be attributed to the polarization of H{sub 2} molecules induced by the charge transfer from Li atoms to graphyne. The favorite H{sub 2} molecules adsorption configurations on a single side and on both sides of a Li-decorated graphyne layer are determined. When Li atoms are adsorbed on one side of graphyne, each Li can bind four H{sub 2} molecules, corresponding to a hydrogen storage capacity of 9.26 wt. %. The hydrogen storage capacity can be further improved to 15.15 wt. % as graphyne is decorated by Li atoms on both sides, with an optimal average binding energy of 0.226 eV/H{sub 2}. The results show that the Li-decorated graphyne can serve as a high capacity hydrogen storage medium.

Zhang Hongyu; Zhang Meng; Zhao Lixia; Luo Youhua [Department of Physics, East China University of Science and Technology, Shanghai 200237 (China); Zhao Mingwen; Bu Hongxia; He Xiujie [School of Physics and State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 Shandong (China)

2012-10-15T23:59:59.000Z

265

High Energy Density Cathode for Lithium Batteries: From LiCoO_(2) to Sulfur  

E-Print Network [OSTI]

addressed, i.e. the safety hazard resulted from the Li dendrite formation on the Li metal anode and the poor cyclability arising from the polysulfides shuttle. Firstly, to overcome the safety issue, this dissertation reported a lithiated Si-S (LSS) battery...

Pu, Xiong

2014-05-29T23:59:59.000Z

266

Thermodynamic stability of oxide, nitride, and carbide coating materials in liquid Sn25Li  

E-Print Network [OSTI]

Thermodynamic stability of oxide, nitride, and carbide coating materials in liquid Sn­25Li S of various oxides, carbides, and nitrides in Sn­Li is estimated as a function of lithium composition K most of the studied nitrides, carbides, and some oxides were found to be stable (DrG > 0). However

Ghoniem, Nasr M.

267

Geospatial revolution and remote sensing LiDAR in Mesoamerican archaeology  

E-Print Network [OSTI]

#12;Geospatial revolution and remote sensing LiDAR in Mesoamerican archaeology Arlen F. Chasea,1. The impor- tance of this geospatial innovation is demonstrated with newly acquired LiDAR data from in the remote geospatial imaging of cultural landscapes, including ancient communities and their anthropogenic

Weishampel, John F.

268

MHD Analysis of Dual Coolant Pb-17Li Blanket for ARIES-CS C. Mistrangelo1  

E-Print Network [OSTI]

MHD Analysis of Dual Coolant Pb-17Li Blanket for ARIES-CS C. Mistrangelo1 , A. R. Raffray2 of California, San Diego, La Jolla, CA 92093-0438, USA, rraffray@ucsd.edu A dual coolant Pb-17Li (DCLL) blanket of magnetohydrodynamic (MHD) flows in the poloidal channels that distribute the liquid metal in the breeder units has

Raffray, A. Ren

269

Improved Capacity Retention for LiVO[subscript 2] by Cr Substitution  

E-Print Network [OSTI]

We present a layered Li-intercalation oxide that operates on the V[superscript 3+]/V[superscript 4+] redox couple. The stabilization effect of adding a +3 element into the layered LiVO[subscript 2] has been studied by first ...

Ma, Xiaohua

270

SPECIAL ISSUE: Quantitative Models for Energy Systems SPECIAL EDITORS: Chung-Li Tseng  

E-Print Network [OSTI]

to mitigate transmission congestion, which can subsequently change locational marginal prices of the network la Torre and Antonio J. Conejo 52 Impact of Phase Shifters on Locational Prices Bo Lu, Zuyi Li Shifters on Locational Prices" by Bo Lu, Zuyi Li, and Mohammand Shahidehpour, proposes using phase shifters

Tseng, Chung-Li

271

A Model Reduction Framework for Efficient Simulation of Li-Ion Batteries  

E-Print Network [OSTI]

of degradation processes in lithium-ion batteries, the modelling of cell dynamics at the mircometer scale lithium-ion batteries is the deposition of metallic lithium at the negative battery electrode (LiA Model Reduction Framework for Efficient Simulation of Li-Ion Batteries Mario Ohlberger Stephan

272

LiFTinG: Lightweight Freerider-Tracking in Gossip Rachid Guerraoui  

E-Print Network [OSTI]

by simulations and PlanetLab experiments. In a 300-node system, where a stream of 674 kbps is broadcast, LiFTinGLiFTinG: Lightweight Freerider-Tracking in Gossip Rachid Guerraoui EPFL rachid.guerraoui@epfl.ch K IIT Guwahati swagatika@iitg.ernet.in Abstract This paper presents LiFTinG, the first protocol

Guerraoui, Rachid

273

Doped LiFePO? cathodes for high power density lithium ion batteries  

E-Print Network [OSTI]

Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

Bloking, Jason T. (Jason Thompson), 1979-

2003-01-01T23:59:59.000Z

274

Degradation of Li/S Battery Electrodes Studied Using X-ray Phase Contrast Tomography  

E-Print Network [OSTI]

the Li-ion battery market. This can be explained by their high energy density, high operating voltage1 Degradation of Li/S Battery Electrodes Studied Using X-ray Phase Contrast Tomography L. Zielkea. Zengerlea,f and S. Thielea,g Lithium/sulphur batteries are promising candidates for future energy storage

Schmidt, Volker

275

Study on generating of thermal neutron scattering cross sections for LiH  

SciTech Connect (OSTI)

LiH is designated as a promising moderator and shielding material because of its low density, high melting point and large fraction of H atoms. However, lack of the thermal neutron cross sections of LiH makes numerical calculation deviate from experimental data to some extent. As a result, it is necessary to study LiH thermal kernel effect. The phonon property of LiH has been investigated by first-principles calculations using the plane-wave pseudo potential method with CASTEP code. The scattering law and the thermal neutron scattering cross sections for Li and H have been generated using this distribution. The results have been compared with zirconium hydride data. The GASKET and NJOY/LEAPR codes have been used in the calculation of scattering law, whose results have been compared with the reference; the discrepancy mainly comes from phonon spectrums and its expansion. LEAPR had the capability to compute scattering through larger energy and momentum transfers than GASKET did. By studying LiH phonon spectrum and constructing the model of LiH thermal kernel and scattering matrix, the ACE format LiH thermal neutron cross sections for MCNP software could be made and used for reactor Neutronics calculation. (authors)

Wang, L.; Jiang, X.; Zhao, Z.; Chen, L. [Northwest Institute of Nuclear Technology, Xi'an 710024 (China)

2013-07-01T23:59:59.000Z

276

Modeling Residential Urban Areas from Dense Aerial LiDAR Point Clouds  

E-Print Network [OSTI]

Modeling Residential Urban Areas from Dense Aerial LiDAR Point Clouds Qian-Yi Zhou and Ulrich models for residential areas from aerial LiDAR scans. The key differ- ence between downtown area modeling and residential area modeling is that the latter usually contains rich vegetation. Thus, we propose a robust

Shahabi, Cyrus

277

Complete Residential Urban Area Reconstruction from Dense Aerial LiDAR Point Clouds  

E-Print Network [OSTI]

Complete Residential Urban Area Reconstruction from Dense Aerial LiDAR Point Clouds Qian-Yi Zhou area modeling and residential area modeling is that the latter usually con- tains rich vegetation. Thus representing the 3D urban reality of residential areas. Keywords: urban modeling, LiDAR, residential area

Shahabi, Cyrus

278

Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries  

E-Print Network [OSTI]

Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf of composite materials used in Li-ion batteries. In this paper, we develop a stochastic simulation model in 3D, Stochastic Simulation Model, Structural Analysis, Marked Point Process, Germ-Grain Model, Model Fitting

Schmidt, Volker

279

Nano-Structured Li3V2(PO4)3 /Carbon Composite for High Rate Lithium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nano-Structured Li3V2(PO4)3 Carbon Composite for High Rate Lithium Ion Batteries. Nano-Structured Li3V2(PO4)3 Carbon Composite for High Rate Lithium Ion Batteries. Abstract:...

280

Interpolating Vancouver's Daily Ambient PM10 Field Li Sun James V. Zidek Nhu D. Le Haluk Ozkaynak  

E-Print Network [OSTI]

Interpolating Vancouver's Daily Ambient PM10 Field Li Sun James V. Zidek Nhu D. Le Haluk Ozkaynak the Center's primary funding. #12;Interpolating Vancouver's Daily Ambient PM10 Field Li Sun1 , James V Zidek1

Washington at Seattle, University of

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

High-Rate Cathodes Based on Li3V2(PO4)3 Nanobelts Prepared via...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cathodes Based on Li3V2(PO4)3 Nanobelts Prepared via Surfactant-Assisted Fabrication. Abstract: In this work, we synthesized monoclinic Li3V2(PO4)3 nanobelts via a single-step,...

282

Raman Spectroscopic and Visible Absorption Investigation of LiCrSi2O6 Pyroxene Under Pressure  

E-Print Network [OSTI]

symmetry.6,7 Spodumene (LiAlSi2O6) and LiCrSi2O6 behave similarly at the phase transition; both go from 6

Downs, Robert T.

283

Sub- and above barrier fusion of loosely bound $^6$Li with $^{28}$Si  

E-Print Network [OSTI]

Fusion excitation functions are measured for the system $^6$Li+$^{28}$Si using the characteristic $\\gamma$-ray method, encompassing both the sub-barrier and above barrier regions, viz., $E_{lab}$= 7-24 MeV. Two separate experiments were performed, one for the above barrier region ($E_{lab}$= 11-24 MeV) and another for the below barrier region ($E_{lab}$= 7-10 MeV). The results were compared with our previously measured fusion cross section for the $^7$Li+$^{28}$Si system. We observed enhancement of fusion cross section at sub-barrier regions for both $^6$Li and $^7$Li, but yield was substantially larger for $^6$Li. However, for well above barrier regions, similar type of suppression was identified for both the systems.

Mandira Sinha; H. Majumdar; P. Basu; Subinit Roy; R. Bhattacharya; M. Biswas; M. K. Pradhan; R. Palit; I. Mazumdar; S. Kailas

2010-05-07T23:59:59.000Z

284

Fusion Engineering and Design 81 (2006) 461467 An overview of dual coolant Pb17Li breeder first wall and blanket  

E-Print Network [OSTI]

. Helium is used to cool the first wall and blanket structure, and the self-cooled breeder Pb17Li.V. All rights reserved. Keywords: Blanket; Pb17Li breeder; Dual-coolant; Helium-cooled; ITER coolant Pb17Li liquid breeder (DCLL) blanket design, a con- cept that has been explored extensively

Abdou, Mohamed

2006-01-01T23:59:59.000Z

285

Fusion Engineering and Design 41 (1998) 371376 The ARIES-RS power core--recent development in Li/V  

E-Print Network [OSTI]

on reversed-shear (RS) physics with a Li/V (lithium breeder and vanadium structure) blanket. The reversed for a fusion power plant. The blanket system based on Li/V has high temperature operating capability, good Li/V as the reference blanket. The combination of attractive physics and attractive blanket

California at San Diego, University of

1998-01-01T23:59:59.000Z

286

Thermal stability of LiPF6EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea  

E-Print Network [OSTI]

Thermal stability of LiPF6±EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea , Ralph study of the LiPF6±EC:EMC electrolyte. The effect of different variables on its thermal stability was evaluated: salt (LiPF6) concentration effect, solvents, EC:EMC ratios, and heating rates. Hermetically

287

Journal of Power Sources 126 (2004) 193202 Li-ion microbatteries generated by a laser direct-write method  

E-Print Network [OSTI]

to fabricate Li-ion microbatteries. The battery electrodes are made by the laser-induced forward transfer. Keywords: Microbattery; Battery; Li-ion; Direct-write; Laser 1. Introduction A current trend in technologyJournal of Power Sources 126 (2004) 193­202 Li-ion microbatteries generated by a laser direct

Arnold, Craig B.

288

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Matthew T. McDowell,  

E-Print Network [OSTI]

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Nian Liu,, Hui Wu nanoparticle, Li-ion battery, anode, yolk-shell, solid-electrolyte interphase, in situ TEM Electrochemical anode that is currently used in Li-ion batteries.2 Among all the alloy anodes, silicon has the highest

Cui, Yi

289

Figure 1. Schematic drawing showing the components of a Li-ion battery cell and the information that can be  

E-Print Network [OSTI]

Figure 1. Schematic drawing showing the components of a Li-ion battery cell and the information Proposals In Situ Electron Microscopy and Spectroscopy Studies of Interfaces in Advanced Li-ion Batteries) such as Li-ion batteries are complex multi- component systems that incorporate widely dissimilar phases

290

Microstructure Reconstruction and Direct Evaluation of Li-Ion Battery Cathodes Fuqiang Liu* and N A Siddique  

E-Print Network [OSTI]

Microstructure Reconstruction and Direct Evaluation of Li-Ion Battery Cathodes Fuqiang Liu* and N of Texas at Arlington, Arlington, Texas 76019, USA High-capacity Li-ion batteries are among the best of the major challenges in Li-ion batteries is to improve mass transport across multiple phase interfaces

Liu, Fuqiang

291

Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable Batteries  

E-Print Network [OSTI]

Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable, metal phosphides MPn, M = transition metal ions as attractive Li-ion anode materials have received lithium reactions, i MPn LixMPn simple Li-ion interca- lation and ii MPn M LixM + LixP alloying followed

Cho, Jaephil

292

Robustness analysis of State-of-Charge estimation methods for two types of Li-ion batteries  

E-Print Network [OSTI]

Robustness analysis of State-of-Charge estimation methods for two types of Li-ion batteries estimation Li-ion battery Robustness analysis a b s t r a c t Battery State of Charge (SOC) estimation. This paper analyzes the robustness of SOC estimation algorithms for two types of Li-ion batteries under

Peng, Huei

293

Investigation of a thermoluminescent dosimeter mixture between LiF:Mg,Ti and Li2B4O7 in a solid form  

E-Print Network [OSTI]

on this data the minimal detectable dose was calculated to be 0.58 mGy, or three times the standard deviation of the background. A fading study revealed a percent loss of 65.6% in 7 days for one set of dosimeters, and 18.4% in 26 days in another. The dosimeters...

Walkowicz, Joshua Peter

1996-01-01T23:59:59.000Z

294

Diciembre 2012 Cuando el manglar  

E-Print Network [OSTI]

cientifica Actualité scientifique Los manglares de las Guyanas --Guyana francesa, Surinam y Guyana--, que se

295

Magnetic phase diagram of magnetoelectric LiMnPO4  

SciTech Connect (OSTI)

The nature of the spin-flop (SF) transition in the magnetoelectric quasi-2D Heisenberg system LiMnPO4 is studied in fields applied along the a axis. A refinement of the magnetic structure using neutron diffraction data in the SF phase reveals that the spins reorient from being parallel to the a axis to be nearly along the c axis at magnetic fields between 4 and 4.7 T, depending on temperature. The low-field antiferromagnetic phase boundary is shown to join the spin-flop line tangentially at the so-called bicritical point, where there is a suppression of the ordering temperature. At the bicritical field, we observe an increased intensity of the Lorentz broadened elastic scattering at magnetic Bragg peaks above TN as compared to zero field and 10 T, without an increase in peak width. This suggests an increased density of fluctuations at the bicritical field as compared to zero field.

Toft-Petersen, Rasmus; Andersen, Niels H.; Li, Haifeng; Li, Jiying; Tian, Wei; Budko, Serguei L.; Jensen, Thomas B.S.; Niedermayer, Christof; Laver, Mark; Zaharko, Oksana; Lynn, Jeffrey W.; Vaknin, David

2012-06-14T23:59:59.000Z

296

Elastic Hadron Scattering on Li Isotopes at Intermediate Energies  

SciTech Connect (OSTI)

The elastic scattering of hadrons (protons, charged pions, and positively charged kaons) on {sup 6,7,8}Li nuclei is analyzed on the basis of Glauber-Sitenko diffraction theory. A few nuclear-wave-function versions found within two- and three-particle potential cluster models are used in the calculations. It is shown that the application of these wave functions in diffraction theory makes it possible to describe adequately the experimental differential cross sections and analyzing powers in hadron scattering at intermediate energies. In this study, particular attention is given to a comparison of the scattering of different particles on the same target nucleus, as well as to a comparison of scattering of particles of the same sort on different target nuclei.

Zhusupov, M.A.; Imambekov, O. [Institute of Experimental and Theoretical Physics, Kazakh State University, ul. Timiryazeva 46, Almaty, 480121 (Kazakhstan); Ibraeva, E.T. [Institute of Nuclear Physics, National Nuclear Center of the Republic of Kazakhstan, Almaty, 480082 (Kazakhstan)

2005-01-01T23:59:59.000Z

297

Formation of Interfacial Layer and Long-Term Cylability of Li-O-2 Batteries  

SciTech Connect (OSTI)

Extended cycling of the Li-O2 battery under full discharge/charge conditions is achievable upon selection of appropriate electrode materials and cycling protocol. However, the decomposition of the side products also contribute to the observed good cycling behavior of high capacity Li-O2 batteries. Quantitative analyses of the discharge and charge products reveals a quick switch from the predominant formation of Li2O2 to the predominant formation of side products during the first a few cycles of the Li-O2 batteries. After the switch, cycling stabilizes with a repeatable formation of Li2O2/side products at ~1:2 ratio. CNTs/Ru composite electrodes exhibits lower charge voltage and deliver 50 full discharge-charge cycles without sharp capacity drop. Ru coated glass carbon electrode can lead to more than 500 cycles without change in its cycling profiles. The better understanding on Li-O2 reaction processes developed in this work may lead to the further improvement on the long term cycling behavior of high capacity Li-O2 batteries.

Nasybulin, Eduard N.; Xu, Wu; Mehdi, Beata L.; Thomsen, Edwin C.; Engelhard, Mark H.; Masse, Robert C.; Bhattacharya, Priyanka; Gu, Meng; Bennett, Wendy D.; Nie, Zimin; Wang, Chong M.; Browning, Nigel D.; Zhang, Jiguang

2014-07-28T23:59:59.000Z

298

Density functional theory study of the mechanism of Li diffusion in rutile RuO{sub 2}  

SciTech Connect (OSTI)

First-principle calculations are carried out to study the diffusion of Li ions in rutile structure RuO{sub 2}, a material for positive electrodes in rechargeable Li ion batteries. The calculations focus on migration pathways and energy barriers for diffusion in Li-poor and Li-rich phases using the Nudged Elastic Band Method. Diffusion coefficients estimated based on calculated energy barriers are in good agreement with experimental values reported in the literature. The results confirm the anisotropic nature of diffusion of Li ions in one-dimensional c channels along the [001] crystalline direction of rutile RuO{sub 2} and show that Li diffusion in the Li-poor phase is faster than in the Li-rich phase. The findings of fast Li diffusion and feasible Li insertion at low temperatures in the host rutile RuO{sub 2} suggest this material is a good ionic conductor for Li transport. The finding also suggests possible means for enhancing the performance of RuO{sub 2}-based electrode materials.

Jung, Jongboo; Cho, Maenghyo [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of)] [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); Zhou, Min, E-mail: min.zhou@gatech.edu [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of) [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); George W. Woodruff School of Mechanical Engineering, School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0405 (United States)

2014-01-15T23:59:59.000Z

299

In situ formation of micron-scale Li-metal anodes with high cyclability  

SciTech Connect (OSTI)

Scanning probe microscopy methods have been used to fabricate and cycle micron-scale Li anodes deposited electrochemically under nanofabricated Au current collectors. An average Li volume of 5 10^8 nm3 was deposited and cycled with 100 % coulombic efficiency for ~ 160 cycles. Integrated charge/discharge values agree with before/after topography, as well as in situ dilatometry, suggesting this is a reliable method to study solid-state electrochemical processes. In this work we illustrate the possibility to deposit highly cyclable nanometer thick Li electrodes by mature SPM and nanofab techniques which can pave the way for inexpensive nanoscale battery arrays.

Arruda, Thomas M [ORNL] [ORNL; Lawton, Jamie S [ORNL] [ORNL; Kumar, Amit [Oak Ridge National Laboratory (ORNL)] [Oak Ridge National Laboratory (ORNL); Unocic, Raymond R [ORNL] [ORNL; Kravchenko, Ivan I [ORNL] [ORNL; Zawodzinski, Thomas A [ORNL] [ORNL; Jesse, Stephen [ORNL] [ORNL; Kalinin, Sergei V [ORNL] [ORNL; Balke, Nina [ORNL] [ORNL

2014-01-01T23:59:59.000Z

300

Fusion reactions in collisions induced by Li isotopes on Sn targets  

SciTech Connect (OSTI)

Fusion cross sections for the {sup 6}Li+{sup 120}Sn and {sup 7}Li+{sup 119}Sn systems have been measured. We aim to search for possible effects due to the different neutron transfer Q-values, by comparing the fusion cross sections for the two systems below the barrier. This experiment is the first step of a wider systematic aiming to study the above problems in collisions induced by stable and unstable Li isotopes on tin all forming the same compound nucleus.

Fisichella, M.; Shotter, A. C.; Di Pietro, A.; Figuera, P.; Lattuada, M.; Marchetta, C.; Musumarra, A.; Pellegriti, M. G.; Ruiz, C.; Scuderi, V.; Strano, E.; Torresi, D.; Zadro, M. [Dipartimento di Fisica, Universita di Messina, Messina (Italy) and INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy); School of Physics and Astronomy, University of Edinburgh, Edinburgh (United Kingdom) and TRIUMF, Vancouver (Canada); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania, Italy and Dipartimento di Fisica ed Astronomia, Universita di Catania, Catania (Italy); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy); INFN- Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy) and Dipartimento di Fisica ed Astronomia, Universita di Catania, Catania (Italy); TRIUMF, Vancouver (Canada); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy) and Dipartimento di Fisica ed Astronomia, Universita di Catania, Catania (Italy); Ruder Boskovic Institute, Zagreb (Croatia)

2012-10-20T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


302

Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms of intermediate phases from quantum mechanics  

E-Print Network [OSTI]

Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms in decomposition of the potential hydrogen storage material LiAlH4 . First, we explore the decomposition mechanism of monoclinic LiAlH4 into monoclinic Li3AlH6 plus face-centered cubic fcc Al and hydrogen. We find

Goddard III, William A.

303

Observations of the Li, Be, and B isotopes and Constraints on Cosmic-ray Propagation  

SciTech Connect (OSTI)

The abundance of Li, Be, and B isotopes in galactic cosmic rays (GCR) between E=50-200 MeV/nucleon has been observed by the Cosmic Ray Isotope Spectrometer (CRIS) on NASA's ACE mission since 1997 with high statistical accuracy. Precise observations of Li, Be, B can be used to constrain GCR propagation models. We find that a diffusive reacceleration model with parameters that best match CRIS results (e.g. B/C, Li/C, etc) are also consistent with other GCR observations. A {approx}15-20% overproduction of Li and Be in the model predictions is attributed to uncertainties in the production cross-section data. The latter becomes a significant limitation to the study of rare GCR species that are generated predominantly via spallation.

de Nolfo, Georgia A.; Moskalenko, I.V.; Binns, W.R.; Christian, E.R.; Cummings, A.C.; Davis, A.J.; George, J.S.; Hink, P.L.; Israel, M.H.; Leske, R.A.; Lijowski, M.; Mewaldt, R.A.; Stone, E.C.; Strong, A.W.; von Rosenvinge, T.T.; Wiedenbeck, M.E.; Yanasak, N.E.; /NASA, Goddard /Stanford U., HEPL /Washington U., St. Louis /NASA, Headquarters/Caltech, SRL /Aerospace Corp. /Garching, Max Planck Inst., MPE /Caltech, JPL; ,

2006-11-15T23:59:59.000Z

304

Study on LiCl waste salt treatment process by layer melt crystallization  

SciTech Connect (OSTI)

Layer melt crystallization operated in a static mode has been applied to separate Group I and II chlorides from surrogate LiCl waste salt. The effects of operating conditions such as crystal growing rate(or flux) and initial impurity concentration on separation (or concentration) of cesium, strontium and barium involved in a LiCl melts were analyzed. In a layer crystallization process, separation was impaired by occlusion of impurities and by residual melt adhering to LiCl crystal after at the end of the process. The crystal growth rate strongly affects the crystal structure, therefore the separation efficiency, while the effect of the initial Cs and Sr concentration in LiCl molten salt was nearly negligible. (authors)

Cho, Yung-Zun; Lee, Tae-Kyo; Choi, Jung-Hoon; Eun, Hee-Chul; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il [Korea Atomic Energy Research Institute, 1045 Daedeok-daero, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

305

The Li'an ("Docketing") Process: Barriers to Initiating Lawsuits in China and Possible Reforms  

E-Print Network [OSTI]

Supreme People's Court ("SPC") found it necessary to pro-note 10, at 88-9. The 1999 SPC Five Year Reform Program ("On May 29, 1997, the SPC issued the Li'an ("Docketing") Work

Cheuk, Andrea

2008-01-01T23:59:59.000Z

306

Water Rock Interaction [WRI 14] Chemical weathering of granitic rocks: experimental approach and Pb-Li  

E-Print Network [OSTI]

and Li isotopic compositions of a rainwater solution in equilibrium with a granite powder. Experiments is lower than 400 mg/L [3]. With this method using multi-collection on Faraday cups, the Tl correction

Paris-Sud XI, Université de

307

Co-synthesis of LiFePO4 and Carbon Nanotubes  

E-Print Network [OSTI]

as low as 0.1% have been reported for nanotubes in epoxy. 8of LiFePO 4 and carbon nanotubes potentially bypassesthat multi-walled carbon nanotubes (MWCNTs, Figure 1) and

Wilcox, James; Doeff, Marca M.

2006-01-01T23:59:59.000Z

308

Nanosheet-structured LiV3O8 with high capacity and excellent...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Highly stable LiV3O8 with a nanosheet-structure was successfully prepared using polyethylene glycol (PEG) polymer in the precursor solution as the structure modifying agent,...

309

Solving Regular Tree Grammar Based Constraints Yanhong A. Liu Ning Li Scott D. Stoller  

E-Print Network [OSTI]

Solving Regular Tree Grammar Based Constraints Yanhong A. Liu Ning Li Scott D. Stoller July 2000 and is then simpli ed according to a set of simpli cation rules to produce the solution. Usually, the constraints

Stoller, Scott

310

Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition  

E-Print Network [OSTI]

LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

Xia, Hui

311

Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet)  

SciTech Connect (OSTI)

Repurposing Li-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications.

Not Available

2014-01-01T23:59:59.000Z

312

E-Print Network 3.0 - al-li alloy c458 Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

c458 Search Powered by Explorit Topic List Advanced Search Sample search results for: al-li alloy c458 Page: << < 1 2 3 4 5 > >> 1 Title of Publication> TMS (The...

313

Significant Cost Improvement of Li-Ion Cells Through Non-NMP...  

Broader source: Energy.gov (indexed) [DOE]

P.I. Yongkyu Son Johnson Controls 2014 DOE Vehicle Technologies Program Review June 17, 2014 Project ID : ES133 Significant Cost Improvement of Li-ion Cells Through Non-NMP...

314

Spatial Sound Rendering Using Measured Room Impulse Responses Yan Li, Peter F. Driessen  

E-Print Network [OSTI]

Spatial Sound Rendering Using Measured Room Impulse Responses Yan Li, Peter F. Driessen Dept, Banff Centre Banff, Alberta, Canada Abstract-- Spatial sound rendering has many applications different quality and complexity requirements. This paper presents a new spatial sound rendering framework

Driessen, Peter F.

315

High Energy Density Li-ion Cells for EVs Based on Novel, High...  

Broader source: Energy.gov (indexed) [DOE]

Storage Systems Vehicle Technologies Annual Merit Review 6182014 1 High Energy Density Li-ion Cells for EV's Based on Novel, High Voltage Cathode Material Systems Keith D. Kepler...

316

Chronopotentiometry of Sm(II) and Pm(III) in molten LiCl-KCl eutectic.  

E-Print Network [OSTI]

??Samarium (III) and promethium (III) were studied by chronopotentiometry in a molten LiCl-KC1 eutectic. Tungsten electrodes were used to avoid alloying effects encountered with platinum (more)

Nixon, Richard Allen

1966-01-01T23:59:59.000Z

317

An ultra-compact and efficient Li-ion battery charger circuit for biomedical applications  

E-Print Network [OSTI]

This paper describes an ultra-compact analog lithium-ion (Li-ion) battery charger for wirelessly powered implantable medical devices. The charger presented here takes advantage of the tanh output current profile of an ...

Do Valle, Bruno Guimaraes

318

Traka yon kretyen pandan vwayaj li : adaptasyon liv Pilgrims Progress" / John Bunyan  

E-Print Network [OSTI]

nan syM la. 4 Li fe lekti yon I6t pasaj nan Bib la: Moun mwen fe gras la ap viv, paske li gen konfyans nan mwen. Men, si 1 vire do 1 tounen fe bak, li p ap fe ke m kontan. 5 Levanjil esplike Kretyen paw6l la konsa: Men sa ki rive, ou te kite... rekonpans li nan lemonn ki ap vini an. 27 Entepret: Ougenrezon. Bagay nou wb ak je p ap dire non. Se sa je pa we ki etenl.4 Le sa a nan rev la, mwen wb Entprt pran men Kretyen epi 1 mennen 1 devan yon mi, kote ki te gen yon gwo dife k ap boule...

Paultre, Carrie?; Bunyan, John; Ross, Jim D.; Freeman, Bryant C.

2000-01-01T23:59:59.000Z

319

Proceedings of the AD HOC Workshop on Ceramics for Li/FeS{sub 2} batteries  

SciTech Connect (OSTI)

Representatives from industry, the U.S. Advanced Battery Consortium (USABC), DOE, national laboratories, and other govt agencies met to develop recommendations and actions for accelerating the development of ceramic components critical to the successful introduction of the Li/FeS{sub 2} bipolar battery for electric vehicles. Most of the workshop is devoted to electrode materials, bipolar designs, separators, and bipolar plates. The bulk of this document is viewographs and is divided into: ceramics, USABC overview, SAFT`s Li/FeS{sub 2} USABC program, bipolar Li/FeS{sub 2} component development, design requirements for bipolar plates, separator design requirements, compatibility of ceramic insulators with lithium, characterization of MgO for use in separators, resistivity measurements of separators, sintered AlN separators for LiMS batteries, etc.

Not Available

1993-12-31T23:59:59.000Z

320

How smooth is a devil's staircase? F.M. Dekking & Wenxia Li y  

E-Print Network [OSTI]

How smooth is a devil's staircase? F.M. Dekking #3; & Wenxia Li y Abstract Let the Cantor set C. Consider the distribution function which is often referred to as the Devil's staircase (for a = 1 3 ): F (x

Li, Wenxia

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Electrochemical evaluation of LiCoO2 synthesized by decomposition and intercalation of hydroxides  

E-Print Network [OSTI]

in commercial lithi- um-ion battery manufacturing [4±6]. Synthesis of LiCoO2 is typically carried out by a solid-state March 1998; accepted in revised form 19 May 1998 LiCoO2 has been synthesized by a solid-state synthesis the electrochemical perfor- mance. In a previous paper [13], we reported a new solid- state reaction method that can

Sadoway, Donald Robert

322

Electrochemical Performance of LiMnPO4 Synthesized with Off-Stoichiometry  

E-Print Network [OSTI]

of LiMPO4 compounds is of interest as cathode ma- terials for rechargeable lithium batteries. LiFePO4 has been in- tensely studied and several techniques such as carbon coating, coat- ing with a metallic2PO4 using heat-treatments at 350°C for 10 h and at 700°C for 10 h under Ar or air atmosphere

Ceder, Gerbrand

323

Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes  

SciTech Connect (OSTI)

Nanostructured ion beam-modified Ge electrodes fabricated directly on Ni current collector substrates were found to exhibit excellent specific capacities during electrochemical cycling in half-cell configuration with Li metal for a wide range of cycling rates. Structural characterization revealed that the nanostructured electrodes lose porosity during cycling but maintain excellent electrical contact with the metallic current collector substrate. These results suggest that nanostructured Ge electrodes have great promise for use as high performance Li ion battery anodes.

Rudawski, N. G.; Darby, B. L.; Yates, B. R.; Jones, K. S. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400 (United States); Elliman, R. G. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200 (Australia); Volinsky, A. A. [Department of Mechanical Engineering, University of South Florida, Tampa Florida 33620 (United States)

2012-02-20T23:59:59.000Z

324

NREL's PHEV/EV Li-Ion Battery Secondary-Use Project  

SciTech Connect (OSTI)

Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) is restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the Li-ion battery's cost via reuse in other applications after it is retired from service in the vehicle, when the battery may still have sufficient performance to meet the requirements of other energy storage applications.

Newbauer, J.; Pesaran, A.

2010-06-01T23:59:59.000Z

325

Synthesis and Characterization of Lithium Bis(fluoromalonato)borate (LiBFMB) for Lithium Ion Battery Applications  

SciTech Connect (OSTI)

A new orthochelated salt, lithium bis(monofluoromalonato)borate (LiBFMB), has been synthesized and purified for the first time for application in lithium ion batteries. The presence of fluorine in the borate anion of LiBFMB increases its oxidation potential and also facilitates ion dissociation, as reflected by the ratio of ionic conductivity measured by electrochemical impedance spectroscopy ( exp) and that by ion diffusivity coefficients obtained using pulsed field gradient nuclear magnetic resonance (PFG-NMR) technique ( NMR). Half-cell tests using 5.0 V lithium nickel manganese oxide (LiNi0.5Mn1.5O4) as a cathode and EC/DMC/DEC as a solvent reveals that the impedance of the LiBFMB cell is much larger than those of LiPF6 and LiBOB based cells, which results in lower capacity and poor cycling performance of the former. XPS spectra of the cycled cathode electrode suggest that because of the stability of the LiBFMB salt, the solid electrolyte interphase (SEI) formed on the cathode surface is significantly different from those of LiPF6 and LiBOB based electrolytes, resulting in more solvent decomposition and thicker SEI layer. Initial results also indicate that using high dielectric constant solvent PC alters the surface chemistry, reduces the interfacial impedance, and enhances the performance of LiBFMB based 5.0V cell.

Liao, Chen [ORNL] [ORNL; Han, Kee Sung [ORNL] [ORNL; Baggetto, Loic [ORNL] [ORNL; Hillesheim, Daniel A [ORNL] [ORNL; Custelcean, Radu [ORNL] [ORNL; Lee, Dr. Eun-Sung [University of Texas at Austin] [University of Texas at Austin; Guo, Bingkun [ORNL] [ORNL; Bi, Zhonghe [ORNL] [ORNL; Jiang, Deen [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL; Hagaman, Edward {Ed} W [ORNL; Brown, Gilbert M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Manthiram, Arumugam [University of Texas at Austin] [University of Texas at Austin; Dai, Sheng [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL

2014-01-01T23:59:59.000Z

326

The Puzzling Li-rich Red Giant Associated with NGC 6819  

E-Print Network [OSTI]

A Li-rich red giant star (2M19411367+4003382) recently discovered in the direction of NGC 6819 belongs to the rare subset of Li-rich stars that have not yet evolved to the luminosity bump, an evolutionary stage where models predict Li can be replenished. The currently favored model to explain Li enhancement in first-ascent red giants like 2M19411367+4003382 requires deep mixing into the stellar interior. Testing this model requires a measurement of 12C/13C, which is possible to obtain from APOGEE spectra. However, the Li-rich star also has abnormal asteroseismic properties that call into question its membership in the cluster, even though its radial velocity and location on color-magnitude diagrams are consistent with membership. To address these puzzles, we have measured a wide array of abundances in the Li-rich star and three comparison stars using spectra taken as part of the APOGEE survey to determine the degree of stellar mixing, address the question of membership, and measure the surface gravity. We con...

Carlberg, Joleen K; Cunha, Katia; Majewski, Steven R; Meszaros, Szabolcs; Shetrone, Matthew; Prieto, Carlos Allende; Bizyaev, Dmitry; Stassun, Keivan G; Fleming, Scott W; Zasowski, Gail; Hearty, Fred; Nidever, David L; Schneider, Donald P; Holtzman, Jon A; Frinchaboy, Peter M

2015-01-01T23:59:59.000Z

327

Delayed neutron emission probabilities of Li-F nuclides  

SciTech Connect (OSTI)

Delayed neutron emission probabilities (P{sub n}) have been measured for 18 nuclides ranging from {sup 9}Li to {sup 25}F. Neutron-rich nuclides were produced by reaction of 800 MeV p on a {sup 232}Th target at the LAMPF accelerator at Los Alamos National Laboratory. Recoil nuclides were individually identified as to their mass, nuclear charged, and ionic charge by use of the Time-of-Flight Isochronous (TOFI) spectrometer. The distribution of time intervals between the arrival of a specific ion and the subsequent detection of a neutron was determined. The P{sub n} was calculated from the total number of ions observed, the initial neutron count rate, the neutron counting efficiency, and the half-life. The technique is shown to be valid for half-lives ranging from 10 ms ({sup 15}B) to 4 s ({sup 17}N) and for P{sub n} values as low as 0.3% ({sup 13}B). Delayed neutron emission has been measured for {sup 12}Be, {sup 14}B, {sup 17}C, {sup 18}N, {sup 21}N, and {sup 25}F for the first time. A small branch for beta-delayed two-neutron emission was observed in {sup 15}B (P{sub 2n} = 0.4 {plus minus} 0.2%). 14 refs., 6 figs., 1 tab.

Reeder, P.L.; Warner, R.A.; Hensley, W.K. (Pacific Northwest Lab., Richland, WA (USA)); Vieira, D.J.; Wouters, J.M. (Los Alamos National Lab., NM (USA))

1989-09-01T23:59:59.000Z

328

Cylindrical target Li-beam-driven hohlraum experiments  

SciTech Connect (OSTI)

The authors performed a series of experiments on the Particle Beam Fusion Accelerator II (PBFA II) in May, 1994, and obtained a brightness temperature of 61 {+-} 2 eV for an ion-beam heated hohlraum. The hohlraum was a 4-mm-diameter, right-circular cylinder with a 1.5-mm-thick gold wall, a low-density CH foam fill, and a 1.5- or 3-mm-diameter diagnostic aperture in the top. The nominal parameters of the radially-incident PBFA II Li ion beam were 9 MeV peak energy ({approximately}10 MeV at the gas cell) at the target at a peak power of 2.5 {+-} 0.3 TW/cm{sup 2} and a 15 ns pulse width. Azimuthal variations in intensity of a factor of 3, with respect to the mean, were observed. Nonuniformities in thermal x-ray emission across the area of the diagnostic hole were also observed. Time-dependent hole-closure velocities were measured: the time-averaged velocity of {approximately}2 cm/{micro}s is in good agreement with sound speed estimates. Unfolded x-ray spectra and brightness temperatures as a function of time are reported and compared to simulations. Hole closure corrections are discussed with comparisons between XRD and bolometer measurements. Temperature scaling with power on target is also presented.

Derzon, M.S.; Aubert, J.; Chandler, G.A. [and others

1998-06-01T23:59:59.000Z

329

Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F) as cathode materials for lithium ion battery from atomistic simulation  

SciTech Connect (OSTI)

Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) have been investigated from atomistic simulation. In order to predict the characteristics of these materials as cathode materials for lithium ion batteries, structural property, defect chemistry, and Li{sup +} ion transportation property are characterized. The coreshell model with empirical force fields is employed to reproduce the unit-cell parameters of crystal structure, which are in good agreement with the experimental data. In addition, the formation energies of intrinsic defects (Frenkel and antisite) are determined by energetics calculation. From migration energy calculations, it is found that these flurophosphates have a 3D Li{sup +} ion diffusion network forecasting good Li{sup +} ion conducting performances. Accordingly, we expect that this study provides an atomic scale insight as cathode materials for lithium ion batteries. - Graphical abstract: Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F). Display Omitted - Highlights: Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) are investigated from classical atomistic simulation. The unit-cell parameters from experimental studies are reproduced by the coreshell model. Li{sup +} ion conducting Li{sub 2}MPO{sub 4}F has a 3D Li{sup +} ion diffusion network. It is predicted that Li/Co or Li/Ni antisite defects are well-formed at a substantial concentration level.

Lee, Sanghun, E-mail: sh0129.lee@samsung.com; Park, Sung Soo, E-mail: sung.s.park@samsung.com

2013-08-15T23:59:59.000Z

330

Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte  

SciTech Connect (OSTI)

Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

2014-08-25T23:59:59.000Z

331

Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O$_2$ battery capacity  

E-Print Network [OSTI]

Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge facing nonaqueous Li-O$_2$ batteries is the electronically insulating nature of the primary discharge product, lithium peroxide, which passivates the battery cathode as it is formed, leading to low ultimate cell capacities. Recently, strategies to enhance solubility to circumvent this issue have been reported, but rely upon electrolyte formulations that further decrease the overall electrochemical stability of the system, thereby deleteriously affecting battery rechargeability. In this study, we report that a significant enhancement (greater than four-fold) in Li-O$_2$ cell capacity is possible by appropriately selecting the salt anion in the electrolyte solution. Using $^7$Li nuclear magnetic resonance and modeling, we confirm that this improvement is a result of enhanced Li...

Burke, Colin M; Khetan, Abhishek; Viswanathan, Venkatasubramanian; McCloskey, Bryan D

2015-01-01T23:59:59.000Z

332

Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density  

SciTech Connect (OSTI)

Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

2014-07-01T23:59:59.000Z

333

Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries  

SciTech Connect (OSTI)

Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially three to five times higher energy density than that of traditional lithium ion batteries. However, the dissolution and precipitation of soluble polysulfides during cycling initiate a series of key-chain reactions that significantly shorten battery life. Herein, we demonstrate that through a simple but effective strategy, significantly improved cycling performance is achieved for high sulfur loading electrodes through controlling the nucleation and precipitation of polysulfieds on the electrode surface. More than 400 or 760 stable cycling are successfully displayed in the cells with locked discharge capacity of 625 mAh g-1 or 500 mAh g-1, respectively. The nucleation and growth process of dissolved polysulfides has been electrochemically altered to confine the thickness of discharge products passivated on the cathode surface, increasing the utilization rate of sulfur while avoiding severe morphology changes on the electrode. More importantly, the exposure of new lithium metal surface to the S-containing electrolyte is also greatly reduced through this strategy, largely minimizing the anode corrosion caused by polysulfides. This work interlocks the electrode morphologies and its evolution with electrochemical interference to modulate cell performances by using Li-S system as a platform, providing different but critical directions for this community.

Zheng, Jianming; Gu, Meng; Wang, Chong M.; Zuo, Pengjian; Koech, Phillip K.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

2013-09-20T23:59:59.000Z

334

http://lez1.pppl.gov/pub/LiWTokamak.ps http://lez1.pppl.gov/pub/LiWTokamak.pdf  

E-Print Network [OSTI]

with the modest cost of about 20 MW of electric power for driving the streams, the magnetic propulsion allows to the surface by the I pol #2;B tor electromagnetic force, where I pol represents the externally driven electric: The intrinsic inhomogeneity of the I pol #2;B tor force drives the liquid Li along the walls (see Fig. 1) from

Zakharov, Leonid E.

335

Air stable Al2O3-coated Li2NiO2 cathode additive as a surplus current consumer in a Li-ion cell  

E-Print Network [OSTI]

cathode additive is prepared by coating with Al iso-propoxide on Li2NiO2, obtained from firing exothermic reaction with an electrolyte during the overcharging process, which may result in a short-circuiting of the cell.5­9 A combination of the temperature increase and the internal short circuit of the cell

Cho, Jaephil

336

Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4  

E-Print Network [OSTI]

-generation batteries that can replace conventional combustion technologies [16­21]. Although the stability of oxygen Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA 2 German Aerospace Center continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes

Bazant, Martin Z.

337

Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries  

SciTech Connect (OSTI)

Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation Li-ion rechargeable battery and LiCoO2 cathode is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

Katiyar, Ram S; Gmez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

2009-01-19T23:59:59.000Z

338

Principal Investigator Department Title Thrust Area Dr. Gang Li Physics Current Sheet Structures in the Inner Heliosphere 1500  

E-Print Network [OSTI]

Principal Investigator Department Title Thrust Area Dr. Gang Li Physics Current Sheet. Zuejing Xing Accounting/Finance Why are IPOs Underpriced? The Role of Institutional Ownership 3000 Dr

Alabama in Huntsville, University of

339

Primary and secondary lithium passivation characteristics and effects in the Li/SO sub 2 couple  

SciTech Connect (OSTI)

This paper presents a study of the characteristics and effects of the lithium passivation layer in the lithium sulfur dioxide (Li/SO{sub 2}) cell. Four aspects have been investigated: passivation layer-induced polarization; effects of long-term, low discharge rates; chemistry of the lithium passivation layer; and kinetics of the passivation layer growth. Polarization studies showed that an initial polarization (voltage delay) was in some cases followed by a secondary polarization. Studies of the effects of long-term, low discharge rates indicated that low discharge rates modified the lithium passivation layer, which resulted in increased lithium corrosion and decreased cell capacity. The degradation was greater at higher temperature. Results of the studies of the chemistry and formation kinetics of the lithium passivation layer were interpreted in terms of a primary layer, which was responsible for the passivation, and a thicker, porous secondary layer. Formation of the secondary layer is exacerbated by partial discharge. The secondary layer results from precipitation of the Li corrosion products, and was found to contain Li{sub 2}S{sub 2}O{sub 4}, Li{sub 2}S{sub 2}O{sub 5}, and Li{sub 2}S{sub n}O{sub 6}, where n > 2. The primary layer is responsible for the initial polarization (voltage delay) under load, whereas the secondary layer induces a second polarization that inhibits high-rate discharge.

Bittner, H.F. (Aerospace Corp., Los Angeles, CA (USA). Chemistry and Physics Lab.)

1989-11-01T23:59:59.000Z

340

Pushing the Theoretical Limit of Li-CFx Batteries: A Tale of Bi-functional Electrolyte  

SciTech Connect (OSTI)

In a typical battery, electrodes deliver capacities less or equal the theoretical maxima of the electrode materials.1 The inert electrolyte functions solely as the ionic conductor without contribution to the cell capacity because of its distinct mono-function in the concept of conventional batteries. Here we demonstrate that the most energy-dense Li-CFx battery2 delivers a capacity exceeding the theoretical maximum of CFx with a solid electrolyte of Li3PS4 (LPS) that has dual functions: as the inert electrolyte at the anode and the active component at the cathode. Such a bi-functional electrolyte reconciles both inert and active characteristics through a synergistic discharge mechanism of CFx and LPS. Li3PS4 is known as an inactive solid electrolyte with a broad electrochemical window over 5 V.3 The synergy at the cathode is through LiF, the discharge product of CFx, which activates the electrochemical discharge of LPS at a close electrochemical potential of CFx. Therefore, the solid-state Li-CFx batteries output 126.6% energy beyond their theoretic limits without compromising the stability of the cell voltage. The extra energy comes from the electrochemical discharge of LPS, the inert electrolyte. This bi-functional electrolyte revolutionizes the concept of conventional batteries and opens a new avenue for the design of batteries with an unprecedentedly high energy density.

Rangasamy, Ezhiylmurugan [ORNL] [ORNL; Li, Juchuan [ORNL] [ORNL; Sahu, Gayatri [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Universality of weakly bound dimers and Efimov trimers close to Li-Cs Feshbach resonances  

E-Print Network [OSTI]

We study the interspecies scattering properties of ultracold Li-Cs mixtures in their two energetically lowest spin channels in the magnetic field range between 800 G and 1000 G. Close to two broad Feshbach resonances we create weakly bound LiCs dimers by radio-frequency association and measure the dependence of the binding energy on the external magnetic field strength. Based on the binding energies and complementary atom loss spectroscopy of three other Li-Cs s-wave Feshbach resonances we construct precise molecular singlet and triplet electronic ground state potentials using a coupled-channels calculation. We extract the Li-Cs interspecies scattering length as a function of the external field and obtain almost a ten-fold improvement in the precision of the values for the pole positions and widths of the s-wave Li-Cs Feshbach resonances as compared to our previous work [Pires \\textit{et al.}, Phys. Rev. Lett. \\textbf{112}, 250404 (2014)]. We discuss implications on the Efimov scenario and the universal geome...

Ulmanis, J; Pires, R; Kuhnle, E D; Weidemller, M; Tiemann, E

2015-01-01T23:59:59.000Z

342

Microwave Plasma Chemical Vapor Deposition of Carbon Coatings on LiNi1/3Co1/3Mn1/3O2 for Li-Ion Battery Composite Cathodes  

E-Print Network [OSTI]

O 2 for Li-ion Battery Composite Cathodes Marek L. MarcinekRaman spectroscopy. The composite LiNi 1/3 Co 1/3 Mn 1/3 O 2electronic contact within the composite cathode and does not

Doeff, M.M.

2012-01-01T23:59:59.000Z

343

Thermochemistry of phosphorus oxynitrides: PON and LiNaPON glasses  

SciTech Connect (OSTI)

High-temperature solution calorimetry has been very useful in elucidating the energetics of many oxide materials. Recently, a sodium molybdate melt, 3Na{sub 2}O{center{underscore}dot}4MoO{sub 3}, has been shown to be very effective for nitride calorimetry. This methodology has now been used to determine the energetics of formation of phosphorus oxynitride PON samples and of a series of LiNaPON oxynitride glasses. The magnitude of the energetics of nitrogen/oxygen substitution within PON and LiNaPON glasses has been correctly evaluated by using N-N, O-O, P-N, and P-O bond strengths. The in-situ precipitation of metallic particles from corresponding oxides in LiNaPON glasses has been predicted from high-temperature solution calorimetry results and appropriate thermodynamic cycles. The results constitute the first set of energetic data on nitridophosphates.

Tessier, F.; Navrotsky, A.; Le Sauze, A.; Marchand, R.

2000-01-01T23:59:59.000Z

344

Electrochemical Behavior of Lithium in LiOH-H/sub 2/O-System Solutions  

SciTech Connect (OSTI)

A study of the anodic behavior and corrosion of lithium in LiOH-H/sub 2/O-system solutions at 298 /SUP o/ K is made. Anodic potentiodynamic and galvanostatic polarization plots were taken with a P-5827M potentiostat and displayed on a PDP-4 flatbed X-Y recorder. The potentiodynamic polarization curves were taken at a scanning rate of 80 mV/sec where the data were almost reproducible. Ptentiodynamic polarization plots taken for solutions of various LiOH concentrations are shown. Corrosion of the lithium in the aqueous electrolyte was studied volumetrically. Data obtained on lithium corrosion in solutions of the LiOH-H/sub 2/O system confirm the postualte that a lithium hydroxide concentration of more than 4 m densifies passive film on the lithium electrode.

Demidov, A.I.; Gerasimenko, L.N.; Konstantinova, M.V.; Morachevskii, A.G.

1985-04-10T23:59:59.000Z

345

The ARIES-RS power core -- Recent development in Li/V designs  

SciTech Connect (OSTI)

The ARIES-RS fusion power plant design study is based on reversed-shear (RS) physics with a Li/V (lithium breeder and vanadium structure) blanket. The reversed-shear discharge has been documented in many large tokamak experiments. The plasma in the RS mode has a high beta, low current, and low current drive requirements. Therefore, it is an attractive physics regime for a fusion power plant. The blanket system based on a Li/V has high temperature operating capability, good tritium breeding, excellent high heat flux removal capability, long structural life time, low activation, low after heat and good safety characteristics. For these reasons, the ARIES-RS reactor study selected Li/V as the reference blanket. The combination of attractive physics and attractive blanket engineering is expected to result in a superior power plant design. This paper summarizes the power core design of the ARIES-RS power plant study.

Sze, D.K.; Billone, M.C.; Hua, T.Q. [and others

1997-04-01T23:59:59.000Z

346

Fusion of $^{6}$Li with $^{159}$Tb} at near barrier energies  

E-Print Network [OSTI]

Complete and incomplete fusion cross sections for $^{6}$Li+$^{159}$Tb have been measured at energies around the Coulomb barrier by the $\\gamma$-ray method. The measurements show that the complete fusion cross sections at above-barrier energies are suppressed by $\\sim$34% compared to the coupled channels calculations. A comparison of the complete fusion cross sections at above-barrier energies with the existing data of $^{11,10}$B+$^{159}$Tb and $^{7}$Li+$^{159}$Tb shows that the extent of suppression is correlated with the $\\alpha$-separation energies of the projectiles. It has been argued that the Dy isotopes produced in the reaction $^{6}$Li+$^{159}$Tb, at below-barrier energies are primarily due to the $d$-transfer to unbound states of $^{159}$Tb, while both transfer and incomplete fusion processes contribute at above-barrier energies.

M. K. Pradhan; A. Mukherjee; P. Basu; A. Goswami; R. Kshetri; R. Palit; V. V. Parkar; M. Ray; Subinit Roy; P. Roy Chowdhury; M. Saha Sarkar; S. Santra

2011-06-10T23:59:59.000Z

347

Fusion of {sup 6}Li with {sup 159}Tb at near-barrier energies  

SciTech Connect (OSTI)

Complete and incomplete fusion cross sections for {sup 6}Li + {sup 159}Tb have been measured at energies around the Coulomb barrier by the {gamma}-ray method. The measurements show that the complete fusion cross sections at above-barrier energies are suppressed by {approx}34% compared to coupled-channel calculations. A comparison of the complete fusion cross sections at above-barrier energies with the existing data for {sup 11,10}B + {sup 159}Tb and {sup 7}Li + {sup 159}Tb shows that the extent of suppression is correlated with the {alpha} separation energies of the projectiles. It has been argued that the Dy isotopes produced in the reaction {sup 6}Li + {sup 159}Tb at below-barrier energies are primarily due to the d transfer to unbound states of {sup 159}Tb, while both transfer and incomplete fusion processes contribute at above-barrier energies.

Pradhan, M. K.; Mukherjee, A.; Basu, P.; Goswami, A.; Kshetri, R.; Roy, Subinit; Chowdhury, P. Roy; Sarkar, M. Saha; Palit, R.; Parkar, V. V.; Santra, S.; Ray, M. [Nuclear Physics Division, Saha Institute of Nuclear Physics, 1/AF, Bidhan Nagar, Kolkata-700064 (India); Department of Nuclear and Atomic Physics, Tata Institute of Fundamental Research, Mumbai-400005 (India); Nuclear Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India); Department of Physics, Behala College, Parnasree, Kolkata-700060 (India)

2011-06-15T23:59:59.000Z

348

Materials for Better Li-based Storage Systems for a "Green Energy Society"  

ScienceCinema (OSTI)

Li-ion batteries are strongly considered for powering the upcoming generations of HEVs and PHEVs, but there are still the issues of safety and costs in terms of materials resources and abundances, synthesis, and recycling processes. Notions of materials having minimum footprint in nature, made via eco-efficient processes, must be integrated in our new research towards the next generation of sustainable and "greener" Li-ion batteries. In this July 13, 2009 talk sponsored by Berkeley Lab's Environental Energy Technologies Division, Jean-Marie Tarascon, a professor at the University of Picardie (Amiens), discuss Eco-efficient synthesis via hydrothermal/solvothermal processes using latent bases as well as structure directing templates or other bio-related approaches of LiFePO4 nanopowders.

Jean-Marie Tarascon

2010-01-08T23:59:59.000Z

349

Detailed Hydrographic Feature Extraction from High-Resolution LiDAR Data  

SciTech Connect (OSTI)

Detailed hydrographic feature extraction from high-resolution light detection and ranging (LiDAR) data is investigated. Methods for quantitatively evaluating and comparing such extractions are presented, including the use of sinuosity and longitudinal root-mean-square-error (LRMSE). These metrics are then used to quantitatively compare stream networks in two studies. The first study examines the effect of raster cell size on watershed boundaries and stream networks delineated from LiDAR-derived digital elevation models (DEMs). The study confirmed that, with the greatly increased resolution of LiDAR data, smaller cell sizes generally yielded better stream network delineations, based on sinuosity and LRMSE. The second study demonstrates a new method of delineating a stream directly from LiDAR point clouds, without the intermediate step of deriving a DEM. Direct use of LiDAR point clouds could improve efficiency and accuracy of hydrographic feature extractions. The direct delineation method developed herein and termed mDn, is an extension of the D8 method that has been used for several decades with gridded raster data. The method divides the region around a starting point into sectors, using the LiDAR data points within each sector to determine an average slope, and selecting the sector with the greatest downward slope to determine the direction of flow. An mDn delineation was compared with a traditional grid-based delineation, using TauDEM, and other readily available, common stream data sets. Although, the TauDEM delineation yielded a sinuosity that more closely matches the reference, the mDn delineation yielded a sinuosity that was higher than either the TauDEM method or the existing published stream delineations. Furthermore, stream delineation using the mDn method yielded the smallest LRMSE.

Danny L. Anderson

2012-05-01T23:59:59.000Z

350

ATMOSPHERIC COMPOSITION OF WEAK G BAND STARS: CNO AND Li ABUNDANCES  

SciTech Connect (OSTI)

We determined the chemical composition of a large sample of weak G band stars-a rare class of G and K giants of intermediate mass with unusual abundances of C, N, and Li. We have observed 24 weak G band stars with the 2.7 m Harlan J. Smith Telescope at the McDonald Observatory and derived spectroscopic abundances for C, N, O, and Li, as well as for selected elements from Na-Eu. The results show that the atmospheres of weak G band stars are highly contaminated with CN-cycle products. The C underabundance is about a factor of 20 larger than for normal giants and the {sup 12}C/{sup 13}C ratio approaches the CN-cycle equilibrium value. In addition to the striking CN-cycle signature the strong N overabundance may indicate the presence of partially ON-cycled material in the atmospheres of the weak G band stars. The exact mechanism responsible for the transport of the elements to the surface has yet to be identified but could be induced by rapid rotation of the main sequence progenitors of the stars. The unusually high Li abundances in some of the stars are an indicator for Li production by the Cameron-Fowler mechanism. A quantitative prediction of a weak G band star's Li abundance is complicated by the strong temperature sensitivity of the mechanism and its participants. In addition to the unusual abundances of CN-cycle elements and Li, we find an overabundance of Na that is in accordance with the NeNa chain running in parallel with the CN cycle. Apart from these peculiarities, the element abundances in a weak G band star's atmosphere are consistent with those of normal giants.

Adamczak, Jens; Lambert, David L., E-mail: adamczak@astro.as.utexas.edu [McDonald Observatory, University of Texas, Austin, TX 78712 (United States)

2013-03-10T23:59:59.000Z

351

Diversification of the Core Bromelioids with a focus on the genus Aechmea: phylogeny, morphology, and climate tolerance  

E-Print Network [OSTI]

French Guiana, Guyana, Suriname, 15) Caribbean, 16)14) Venezuela, Guyane, Guyana, Suriname, 15) Caribbean, 16)

Sass, Chodon

2011-01-01T23:59:59.000Z

352

School of Art & Design Postgraduate International Scholarship Opportunities 2014 / 15  

E-Print Network [OSTI]

, Venezuela, Guyana, Suriname, French Guyana, Brazil, Ecuador, Peru, Bolivia, Paraguay, Uruguay, Argentina

Evans, Paul

353

School of Architecture, Design and the Built Environment Postgraduate International Scholarship Opportunities 2014 / 15  

E-Print Network [OSTI]

, Venezuela, Guyana, Suriname, French Guyana, Brazil, Ecuador, Peru, Bolivia, Paraguay, Uruguay, Argentina

Evans, Paul

354

December 2012 When mangroves  

E-Print Network [OSTI]

cientifica Actualité scientifique The mangrove forests in the Guyanas (French Guiana, Surinam and Guyana

355

Report for in-situ 7Li NMR experiment in PNNL Phase -1  

SciTech Connect (OSTI)

To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

Hu, Jian Zhi [Pacific Northwest National Laboratory

2014-08-19T23:59:59.000Z

356

Passivation of Aluminum in Lithium-ion Battery Electrolytes withLiBOB  

SciTech Connect (OSTI)

A combination of cyclic polarization tests, electrochemical impedance spectroscopy, and electrochemical quartz crystal microbalance (EQCM) measurements indicate a film is formed when aluminum is polarized above 4.5V in 1:1 EC+DMC with 1M LiBOB. The quantity of film that is formed increases with increasing applied potential. Results of EQCM tests suggest the film is AlBO{sub 3}. The film is very protective against corrosion and inhibits pitting corrosion of aluminum in normally corrosive 1M LiTFSI.

Zhang, Xueyuan; Devine, Thomas M.

2006-09-09T23:59:59.000Z

357

Effect of flame-retarding additives on surface chemistry in Li-ion batteries  

SciTech Connect (OSTI)

This study examined the properties of 1 wt.% vinylene carbonate (VC), vinyl ethylene carbonate (VEC), and diphenyl octyl phosphate (DPOF) additive electrolytes as a promising way of beneficially improving the surface and cell resistance of Li-ion batteries. Surface film formation on the negative and positive electrodes was analyzed by electrochemical impedance spectroscopy (EIS), Fourier transform infrared (FT-IR) spectroscopy, and scanning electron microscopy (SEM). In conclusion, EIS, FT-IR spectroscopy and SEM results confirmed that DPOF is an excellent additive to the electrolyte in the Li-ion batteries due to the improved co-intercalation of the solvent molecules.

Nam, N.D.; Park, I.J. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)] [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, J.G., E-mail: kimjg@skku.ac.kr [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, H.S. [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)] [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)

2012-10-15T23:59:59.000Z

358

Superplastic forming characteristics of 2090 (OE-16) and 8090 (SP) Al-Li alloys  

E-Print Network [OSTI]

SUPERPLASTIC FORMING CHARACTERISTICS OF 2090 (OE-16) AND 8090 (SP) AL-LI ALLOYS A Thesis by RAZAQ H. KHAZI-SYED Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1992 Major Subject: Mechanical Engineering SUPERPLASTIC FORMING CHARACTERISTICS OF 2090(OE-16) AND 8090 (SP) AL-LI ALLOYS A Thesis by RAZAQ H. KHAZI-SYED Approved as to style and content by: R. E. Goforth (Chair...

Khazi-Syed, Razaq H.

1992-01-01T23:59:59.000Z

359

Functional Analysis of Cardiac MR Images using SPHARM Heng Huanga, Li Shenb, James Forda, Fillia Makedona, Rong Zhangc  

E-Print Network [OSTI]

Functional Analysis of Cardiac MR Images using SPHARM Modeling Heng Huanga, Li Shenb, James Forda relationship with stages of disease. At the same time, Further author information: (Send correspondence to Heng Huang) Heng Huang: E-mail: hh@cs.dartmouth.edu, Telephone: 1 603 646 1694 Li Shen: lshen

Huang, Heng

360

Simply AlF3-treated Li4Ti5O12 composite anode materials for stable...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and...

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Mixed Ionic and Electronic Conduction in Li3PO4 Electrolyte for a CO2 Gas Sensor  

E-Print Network [OSTI]

equilib- rium potential types, are most promising for CO2 monitoring among the solid-state and Measurements, The Ohio State University, Columbus, Ohio 43210, USA An electrochemical CO2 gas sensor using Li2. Because Li3PO4 electrolyte has been fabricated as a Lipon glass thin film in battery applications,14

Dutta, Prabir K.

362

A synthesis of LiFePO{sub 4} starting from FePO{sub 4} under reducing atmosphere  

SciTech Connect (OSTI)

A fast and easy way to produce LiFePO{sub 4} starting from FePO{sub 4}, used as iron and phosphorus source, is proposed. 5% hydrogen is employed as a reducing agent and various compounds containing lithium as lithiation agents. The selected lithiation agents included: LiCl, CH{sub 3}COOLi, LiOH, Li{sub 2}S, LiH, and Li{sub 2}CO{sub 3}. Solid state synthesis is used for the LiFePO{sub 4} preparation and the so obtained materials are structurally characterized by XRD. The materials are used to fabricate composite electrode and their specific capacity is evaluated by low rate galvanostatic charge/discharge cycles (C/10 rate). Among the various lithium salts, the acetate give rise to the LiFePO{sub 4} with the best electrochemical performance. The morphology of this material is further investigated by SEM microscopy and the specific capacity is evaluated as a function of the discharge rate and the cycle number.

Prosini, Pier Paolo [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome, Italy and DInESto, Drive the Innovation in Energy Storage, Via Provin (Italy); Cento, Cinzia; Masci, Amedeo; Carewska, Maria; Gislon, Paola [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome (Italy)

2014-06-19T23:59:59.000Z

363

Mechanical property, biocorrosion and in vitro biocompatibility evaluations of MgLi(Al)(RE) alloys for future cardiovascular stent  

E-Print Network [OSTI]

February 2013 Keywords: MgLi-based alloys Biodegradable Corrosion Biocompatibility In vitro a b s t r a c to the presence of lithium. To improve the mechanical strengths of MgLi binary alloys, aluminum and rare earth- corrosion behavior were evaluated by using optical microscopy, X-ray diffraction, scanning electronic

Zheng, Yufeng

364

A techno-economic analysis and optimization of Li-ion batteries for light-duty passenger vehicle electrification  

E-Print Network [OSTI]

A techno-economic analysis and optimization of Li-ion batteries for light-duty passenger vehicle thickness a b s t r a c t We conduct a techno-economic analysis of Li-ion NMC-G prismatic pouch battery

McGaughey, Alan

365

MODELING LIQUID METAL CORROSION IN A FERRITIC STEEL PbLi SYSTEM WITH AND WITHOUT A MAGNETIC FIELD  

E-Print Network [OSTI]

MODELING LIQUID METAL CORROSION IN A FERRITIC STEEL ­ PbLi SYSTEM WITH AND WITHOUT A MAGNETIC FIELD associated with corrosion of ferritic steel in the flowing eutectic alloy lead-lithium (PbLi). New computer to perform more analysis and comparisons against available experimental data on corrosion in various flow

Abdou, Mohamed

366

Particle-size and morphology dependence of the preferred interface orientation in LiFePO4 nano-  

E-Print Network [OSTI]

Particle-size and morphology dependence of the preferred interface orientation in LiFePO4 nano insights into the equilibrium properties and potential two-phase lithiation mechanisms in LiFePO4 nano, if experimentally-relevant nano-particles were to (de)lithiate under a thermodynamic two-phase mechanism

Ceder, Gerbrand

367

Quadruple Adaptive Observer of the Core Temperature in Cylindrical Li-ion Batteries and their Health Monitoring  

E-Print Network [OSTI]

Quadruple Adaptive Observer of the Core Temperature in Cylindrical Li-ion Batteries to an effective thermal management system and to maintain safety, performance, and longevity of these Li-Ion. Dyche Anderson Abstract-- Temperature monitoring is a critical issue for lithium ion batteries. Since

Stefanopoulou, Anna

368

Applied Surface Science 266 (2013) 516 Interphase chemistry of Si electrodes used as anodes in Li-ion batteries  

E-Print Network [OSTI]

in Li-ion batteries Catarina Pereira-Nabaisa,b , Jolanta S´wiatowskaa, , Alexandre Chagnesb, , Franc made to increase the energy density of lithium-ion batteries (LiB), namely for electric vehicle applications. One way to improve the energy density of a battery is to use high specific capacity materials, e

Boyer, Edmond

369

Adaptation of an Electrochemistry-based Li-Ion Battery Model to Account for Deterioration Observed Under Randomized Use  

E-Print Network [OSTI]

Adaptation of an Electrochemistry-based Li-Ion Battery Model to Account for Deterioration Observed). In this paper, we use an electrochemistry-based lithium ion (Li-ion) battery model developed in (Daigle, Moffett Field, CA 94035 matthew.j.daigle@nasa.gov ABSTRACT Tracking the variation in battery dynamics

Daigle, Matthew

370

Tunable blue light source by intracavity frequency doubling of a Cr-LiSrAIF6 laser  

E-Print Network [OSTI]

Tunable blue light source by intracavity frequency doubling of a Cr- LiSrAIF6 laser Franqois-switched operation at 10 kHz was intracavity frequency doubled by using a LiIOl crystal. The 230 ns tunable blue lasers emitting in the blue-green wavelength range are expected to be the key components for optical

Paris-Sud XI, Université de

371

Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /  

E-Print Network [OSTI]

in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction,in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction,

Lee, Dae Hoe

2013-01-01T23:59:59.000Z

372

MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System  

E-Print Network [OSTI]

compared to the lithium-electron interaction in x Li FeP04 (by Fermi contact interactions between the lithium ions andlithium ions in LiFePC^ suggests a modification of the Fe -O-P interaction.

Cabana, Jordi

2010-01-01T23:59:59.000Z

373

Study of MHD Corrosion and Transport of Corrosion Products of Ferritic/Martensitic Steels in the Flowing PbLi and its Application to Fusion Blanket  

E-Print Network [OSTI]

components of a liquid breeder blanket of a fusion powerPb-17Li breeder first wall and blanket concept developmentPb-17Li breeder first wall and blanket concept development

Saeidi, Sheida

2014-01-01T23:59:59.000Z

374

Adiabatic Channel Capture Theory Applied to Cold Atom-Molecule Reactions: Li + CaH -> LiH + Ca at 1 K  

E-Print Network [OSTI]

We use quantum and classical adiabatic capture theories to study the chemical reaction Li + CaH -> LiH + Ca. Using a recently developed ab initio potential energy surface, which provides an accurate representation of long-range interactions in the entrance reaction channel, we calculate the adiabatic channel potentials by diagonalizing the atom-molecule Hamiltonian as a function of the atom-molecule separation. The resulting adiabatic channel potentials are used to calculate both the classical and quantum capture probabilities as a function of collision energy, as well as the temperature dependencies of the partial and total reaction rates. The calculated reaction rate agrees well with the measured value at 1 K [V. Singh et al., Phys. Rev. Lett. 108, 203201 (2012)], suggesting that the title reaction proceeds without an activation barrier. The calculated classical adiabatic capture rate agrees well with the quantum result in the multiple partial wave regime of relevance to the experiment. Significant differen...

Tscherbul, Timur V

2014-01-01T23:59:59.000Z

375

GY EERE PROJECT MANAGEMENT CENTER NEPA DETERMINATION RECIPIENT...  

Broader source: Energy.gov (indexed) [DOE]

heating and domestic hot water systems, and ice making machines and installing an energy efficient geothermal heating, cooling , and refrigeration system as building...

376

In-situ X-ray absorption spectroscopy analysis of capacity fade in nanoscale-LiCoO{sub 2}  

SciTech Connect (OSTI)

The local structure of nanoscale (?1040 nm) LiCoO{sub 2} is monitored during electrochemical cycling utilizing in-situ X-ray absorption spectroscopy (XAS). The high surface area of the LiCoO{sub 2} nanoparticles not only enhances capacity fade, but also provides a large signal from the particle surface relative to the bulk. Changes in the nanoscale LiCoO{sub 2} metal-oxide bond lengths, structural disorder, and chemical state are tracked during cycling by adapting the delta mu (??) technique in complement with comprehensive extended X-ray absorption fine structure (EXAFS) modeling. For the first time, we use a ?? EXAFS method, and by comparison of the difference EXAFS spectra, extrapolate significant coordination changes and reduction of cobalt species with cycling. This combined approach suggests LiCo site exchange at the surface of the nanoscale LiCoO{sub 2} as a likely factor in the capacity fade and irreversible losses in practical, microscale LiCoO{sub 2}. - Graphical abstract: Electrochemical cycling of Li-ion batteries has strong impact on the structure and integrity of the cathode active material particularly near the surface/electrolyte interface. In developing a new method, we have used in-situ X-ray absorption spectroscopy during electrochemical cycling of nanoscale LiCoO{sub 2} to track changes during charge and discharge and between subsequent cycles. Using difference spectra, several small changes in Co-O bond length, Co-O and Co-Co coordination, and site exchange between Co and Li sites can be tracked. These methods show promise as a new technique to better understand processes which lead to capacity fade and loss in Li-ion batteries. - Highlights: A new method is developed to understand capacity fade in Li-ion battery cathodes. Structural changes are tracked during Li intercalation/deintercalation of LiCoO{sub 2}. Surface structural changes are emphasized using nanoscale-LiCoO{sub 2} and difference spectra. Full multiple scattering calculations are used to support ?? analysis.

Patridge, Christopher J. [NRC/NRL Cooperative Research Associate, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Love, Corey T., E-mail: corey.love@nrl.navy.mil [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Swider-Lyons, Karen E. [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Twigg, Mark E. [Electronics Science and Technology Division, Code 6812, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Ramaker, David E. [Chemistry Division, Code 6189, U.S. Naval Research laboratory, Washington, DC 20375 (United States)

2013-07-15T23:59:59.000Z

377

Spin-waves in antiferromagnetic single-crystal LiFePO4 Jiying Li,* Vasile O. Garlea, Jerel L. Zarestky, and David Vaknin  

E-Print Network [OSTI]

-wave theory by including in the spin Hamiltonian in-plane nearest- and next-nearest-neighbor interactions J1 and J2 , inter-plane nearest-neighbor interactions J and a single-ion anisotropy D . A weak 0 number s : 75.25. z, 75.30.Ds, 75.50.Ee I. INTRODUCTION Lithium-orthophosphates LiMPO4 M=Mn,Fe,Co,Ni have

Vakni, David

378

Ab initio structure search and in situ 7Li NMR studies of discharge products in the Li-S battery system  

E-Print Network [OSTI]

of discharge and most of the intermediate polysulfides are retained inside the cathode matrix.8 Lowe et al. also used in situ XRD and coupled it with absorption spectroscopy to show that a limited number of polysulfide intermediates are involved... to correctly describe the system, which includes the activity of the solvent. However, the suggested discharge profile for a pure solid-state cathode (Figure 1c) could explain the mechanisms observed for Li?S batteries that utilize ceramic and even polymer...

See, Kimberly A.; Leskes, Michal; Griffin, John M.; Britto, Sylvia; Matthews, Peter D.; Emly, Alexandra; Van der Ven, Anton; Wright, Dominic S.; Morris, Andrew J.; Grey, Clare P.; Seshadri, Ram

2014-11-10T23:59:59.000Z

379

Biased interface between solid ion conductor LiBH{sub 4} and lithium metal: A first principles molecular dynamics study  

SciTech Connect (OSTI)

We use first-principles molecular dynamics to study the electrochemical solid-solid interface between lithium metal and lithium electrolyte LiBH{sub 4}. An external bias is applied by using an effective screening medium. We observe large polarization in the LiBH{sub 4}, because the lithium cations in LiBH{sub 4} are shifted more on one side of the double-well potential of Li{sup +}. This results in a large potential drop in the interface region and a large double-layer capacity corresponding to ca. 70 ?F/cm{sup 2}. H-coordination to the Li atoms plays an important role in the charge-transfer reaction and ion transfer.

Ikeshoji, Tamio [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan) [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Ando, Yasunobu; Otani, Minoru; Tsuchida, Eiji [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan)] [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan)] [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan) [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan)

2013-09-23T23:59:59.000Z

380

Three-phase model for the reversible lithiation/delithiation of SnO anodes in Li-ion batteries  

E-Print Network [OSTI]

Using first-principles calculations, we propose a microscopic model to explain the reversible lithiation/delithiation of tin-oxide anodes in lithium-ion batteries. When the irreversible regime ends, the anode grains consist of layers of Li-oxide separated by Sn bilayers. During the following reversible lithiation, the Li-oxide undergoes two phase transformations that give rise to a Li-enrichment of the oxide and the formation of a SnLi composite. The anode grain structure stays layered and ordered with an effective theoretical reversible capacity of 4.5 Li per Sn atom. The predicted anode volume expansion and voltage profile agree well with experiments, contrary to existing models.

Pedersen, Andreas; Luisier, Mathieu

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Correlation between biaxial stress and free exciton transition in AlN B. N. Pantha, N. Nepal, T. M. Al Tahtamouni, M. L. Nakarmi, J. Li,  

E-Print Network [OSTI]

. Nepal, T. M. Al Tahtamouni, M. L. Nakarmi, J. Li, J. Y. Lin, and H. X. Jianga Department of Physics

Jiang, Hongxing

382

Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method  

SciTech Connect (OSTI)

In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.8439910{sup ?10} and 8.5988810{sup ?10} cm{sup 2} s{sup ?1}, respectively.

Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng [Chemical Engineering, Sepuluh Nopember Institute of Technology, Kampus Sukolilo Surabaya Indonesia 60111 (Indonesia)

2014-02-24T23:59:59.000Z

383

Li/Ca, B/Ca, and Mg/Ca Composition of Cultured Sea Urchin Spines and Paleo-Echinoderms Measured Using a Secondary Ion Mass Spectrometer  

E-Print Network [OSTI]

Li/Ca was normalized to HTP-CC standard, B/Ca was normalizednormalized to calcites (CAL-HTP and UCI) for Li and Mg and aintensity ratios of Li/Ca (CAL-HTP), B/Ca (M93), and Mg/Ca (

Nguyen, Trung Timothy Do

2013-01-01T23:59:59.000Z

384

Studies on Capacity Fade of Spinel-Based Li-Ion Batteries Ramadass Premanand, Anand Durairajan,* Bala Haran,** Ralph White,*** and  

E-Print Network [OSTI]

Studies on Capacity Fade of Spinel-Based Li-Ion Batteries Ramadass Premanand, Anand Durairajan of South Carolina, Columbia, South Carolina 29208, USA The performance of Cell-Batt® Li-ion cells using in Mn content with cycling. These studies indicate that capacity fade of spinel-based Li-ion cells can

385

TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations by operando-XRD and Mossbauer techniques  

E-Print Network [OSTI]

TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations We report the electrochemical study of TiSnSb towards Li, as a negative electrode for Li-ion batteries. TiSnSb can reversibly take up more than 5 lithiums per formula unit leading to reversible

Boyer, Edmond

386

Abstract--A novel, accurate, compact, and power efficient Lith-ium-Ion (Li-Ion) battery charger designed to yield maximum  

E-Print Network [OSTI]

1 Abstract-- A novel, accurate, compact, and power efficient Lith- ium-Ion (Li-Ion) battery charger battery, linear charger, switching charger. I. INTRODUCTION ITHIUM-ION (Li-Ion) batteries are widely used of Li-Ion batteries to over-charged voltages im- poses stringent charge requirements on the design

Rincon-Mora, Gabriel A.

387

Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles Yi Zeng1, Martin Z. Bazant1,2  

E-Print Network [OSTI]

Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles Yi Zeng1, Martin Z. Bazant1,2 1 particle. This general approach extends previous Li-ion battery models, which either neglect phase theory for Li-ion batteries [13, 18] with Butler-Volmer kinetics and concentration depen- dent

Bazant, Martin Z.

388

ccsd00000540 Production of Long-Lived Ultracold Li 2 Molecules from a Fermi gas  

E-Print Network [OSTI]

and sign of the scattering length. In bosonic samples, the collapse of Bose-Einstein condensates (BEC a Fermi gas J. Cubizolles 1 , T. Bourdel 1 , S. J. J. M. F. Kokkelmans 1 , G.V. Shlyapnikov 1;2;3 and C-bound Li2 molecules from a degenerate two component Fermi gas by sweeping a magnetic #12;eld across

389

A Bragg grating on LiNbO? waveguide for velocity-matching of electrooptic modulators  

E-Print Network [OSTI]

.07 []m period grating was realized on a single mode Ti:LiNbO? waveguide using a holographic process and reactive ion etching (RIE). A TiO? etching rate of about 100 [A]/min is achieved by RIE with a CHF?, Ar and He gas mixture. A 1.07 []m period, 0.23[]m...

Wang, Ruiyu

2001-01-01T23:59:59.000Z

390

on behalf of China National Stroke Registry (CNSR) Investigators Wang, Hao Li and Yongjun Wang  

E-Print Network [OSTI]

on behalf of China National Stroke Registry (CNSR) Investigators Wang, Hao Li and Yongjun Wang Role Interrelationship Among Common Medical Complications After Acute Stroke: Pneumonia Print ISSN. is published by the American Heart Association, 7272 Greenville Avenue, Dallas, TX 75231Stroke doi: 10

Shen, Haipeng

391

Energy Impact of Secure Computation on a Handheld Device Zhiyuan Li  

E-Print Network [OSTI]

Energy Impact of Secure Computation on a Handheld Device Zhiyuan Li Rong Xu Department of Computer is an important approach to save the energy consumption while improving perfor- mance for wireless networked. In this paper, we measure the energy con- sumption characteristics of multimedia applications on a handheld

Li, Zhiyuan

392

Energy Impact of Secure Computation on a Handheld Device # Zhiyuan Li + Rong Xu  

E-Print Network [OSTI]

and mobile computing. Many architectural and software e#orts have been initiated to improve the energy eEnergy Impact of Secure Computation on a Handheld Device # Zhiyuan Li + Rong Xu Department#oading is an important approach to save the energy consumption while improving perfor­ mance for wireless networked

Li, Zhiyuan

393

EECS: An Energy Efficient Clustering Scheme in Wireless Sensor , Chengfa Li1  

E-Print Network [OSTI]

' limited power, innovative techniques that im- prove energy efficiency to prolong the network lifetime lifetime greatly with a chain topology. But the delay is signif- icant although the energy is savedEECS: An Energy Efficient Clustering Scheme in Wireless Sensor Networks Mao Ye1 , Chengfa Li1

Wu, Jie

394

Optical Flow Estimation using Laplacian Mesh Energy Wenbin Li Darren Cosker Matthew Brown Rui Tang  

E-Print Network [OSTI]

Optical Flow Estimation using Laplacian Mesh Energy Wenbin Li Darren Cosker Matthew Brown Rui Tang.p.cosker,m.brown,r.tang}@bath.ac.uk Abstract In this paper we present a novel non-rigid optical flow algorithm for dense image correspondence and non-rigid registration. The algorithm uses a unique Laplacian Mesh Energy term to encourage local

Martin, Ralph R.

395

ON THE APPLICATION OF LOAD RELAXATION IN CHARACTERIZING SUPERPLASTIC Al-Li 8090  

E-Print Network [OSTI]

ON THE APPLICATION OF LOAD RELAXATION IN CHARACTERIZING SUPERPLASTIC Al-Li 8090 F. Booeshaghi and H is typically calculated as the slope of the log versus log curve where is the steady state flow stress test, and load relaxation tests. In this paper, the use of the load relaxation experiment to obtain

Garmestani, Hamid

396

Earth Observations for rapid response to large earthquakes Supervisors: Dr Zhenhong Li and Prof Trevor Hoey  

E-Print Network [OSTI]

Earth Observations for rapid response to large earthquakes Supervisors: Dr Zhenhong Li and Prof Trevor Hoey School of Geographical and Earth Sciences, University of Glasgow, UK Earthquakes, together of the earth system; they are messengers of the fundamental processes that shape the surface of the Earth

Guo, Zaoyang

397

Coupled displacive and orderdisorder dynamics in LiNbO3 by molecular-dynamics simulation  

E-Print Network [OSTI]

.1063/1.1669063 Ferroelectric lithium niobate (LiNbO3) has emerged as an important material in surface acoustic wave devices1 the structure and properties of materials. Indeed, atomic-level simulations have been used previously-dynamics MD simulations described here we treat the Coulomb interactions using a direct summation method

Gopalan, Venkatraman

398

SEVERE PARTICULATE POLLUTION IN LANZHOU Peter C. Chu, Yuchun Chen*, Shihua Lu*, Zhenchao Li*, Yaqiong Lu**  

E-Print Network [OSTI]

SEVERE PARTICULATE POLLUTION IN LANZHOU CHINA Peter C. Chu, Yuchun Chen*, Shihua Lu*, Zhenchao Li and fall, but much worse in winter, reaching low to mid alert level of air pollution. Since 1999 increasing, and become major pollutants. The mean concentration of PM10 is 2.56 mg m-3 . Even in summer

Chu, Peter C.

399

An Efficient Method for Constructing Personal DataSpace Yukun Li, Xiaofeng Meng, Yubo Kou  

E-Print Network [OSTI]

An Efficient Method for Constructing Personal DataSpace Yukun Li, Xiaofeng Meng, Yubo Kou School--With increment of personal data amount, how to efficiently manage Personal DataSpace(PDS) becomes a serious information management systems, such as desktop search tools, and etc. Keywords-Personal DataSpace; Rules

400

Exploring Personal CoreSpace for DataSpace Yukun Li and Xiaofeng Meng  

E-Print Network [OSTI]

Exploring Personal CoreSpace for DataSpace Management Yukun Li and Xiaofeng Meng School increment of personal data amount, how to efficiently search Personal DataSpace(PDS) becomes an interesting. These queries can't be supported well by current personal data management tools. The aim of this paper

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A novel solid-state self powered neutron detector Nicholas LiCausi*a  

E-Print Network [OSTI]

A novel solid-state self powered neutron detector Nicholas LiCausi*a , Justin Dingleyb , Yaron procedures. Keywords: Neutron detector, thermal neutrons, solid-state detector, DRIE, computer simulations 1 source and could be entirely self-powered. With no moving parts it would be robust and work in a variety

Danon, Yaron

402

Block Copolymer Solid Battery Electrolyte with High Li-Ion Transference Number  

E-Print Network [OSTI]

Block Copolymer Solid Battery Electrolyte with High Li-Ion Transference Number Ayan Ghosh number TLi+ value of 0.9 at room temperature 21­23°C . The solid-state flexible, translucent polymer of withstanding such high voltage conditions. Unlike traditional liquid electrolytes, solid-state polymer electro

Rubloff, Gary W.

403

A NEWTON METHOD FOR AMERICAN OPTION PRICING THOMAS F. COLEMAN, YUYING LI, AND ARUN VERMA  

E-Print Network [OSTI]

in the American option valuation. We illustrate that the proposed method on aver- age solves a discretized problem curve. American option valuation has been an active research area; many methods have been proposedA NEWTON METHOD FOR AMERICAN OPTION PRICING THOMAS F. COLEMAN, YUYING LI, AND ARUN VERMA December

Li, Yuying

404

Short-Term Generation Asset Valuation Chung-Li Tseng, Graydon Barz  

E-Print Network [OSTI]

Short-Term Generation Asset Valuation Chung-Li Tseng, Graydon Barz Department of Civil Engineering 94305, USA chungli@eng.umd.edu, gbarz@leland.stanford.edu Abstract In this paper we present a method for valuing a power plant over a short-term period using Monte Carlo sim- ulation. The power plant valuation

405

Chemical weathering of granitic rock: experiments and Pb-Li isotopes tracing Romain Millot  

E-Print Network [OSTI]

is to better constrain the processes of water/rock interactions both in terms of source (dissolutionChemical weathering of granitic rock: experiments and Pb-Li isotopes tracing Romain Millot Philippe of weathering. In order to go further and to better characterize water/rock interactions, we performed

Paris-Sud XI, Universit de

406

A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a,  

E-Print Network [OSTI]

A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a, , R in paleoceanography. We present evidence from ten equatorial Pacific Ocean sediment cores to show that the deep Pacific Ocean likely stored more carbon during the last glacial period than the Holocene

Sachs, Julian P.

407

Solid State NMR Studies of Li-Rich NMC Cathodes: Investigating...  

Broader source: Energy.gov (indexed) [DOE]

in dQdV plots center of mass of Li shifts in NMR spectra shift to lower frequencies. 2.0 2.5 3.0 3.5 4.0 4.5 dQdV Voltage NMR11 Cycle 2 NMR14 Cycle 11 NMR 14 NMR 11 NMR 15...

408

Toward Harnessing User Feedback For Machine Learning Simone Stumpf, Vidya Rajaram, Lida Li, Margaret Burnett,  

E-Print Network [OSTI]

Toward Harnessing User Feedback For Machine Learning Simone Stumpf, Vidya Rajaram, Lida Li University School of Electrical Engineering and Computer Science Corvallis, OR 97331 USA 1 to the learning algorithm. The results show that user feedback has the potential to significantly improve machine

409

Vapor Deposition of Ruthenium from an Amidinate Precursor Huazhi Li,a  

E-Print Network [OSTI]

Vapor Deposition of Ruthenium from an Amidinate Precursor Huazhi Li,a Damon B. Farmer,b Roy G School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, USA October 11, 2007. Thin films of ruthenium have many current and potential appli- cations. They can be used

410

Vapor Deposition of Ruthenium from an Amidinate Precursor Huazhi Li,a  

E-Print Network [OSTI]

Vapor Deposition of Ruthenium from an Amidinate Precursor Huazhi Li,a Damon B. Farmer,b Roy G. Gordon* ,a Youbo Lin,b Joost Vlassakb a Department of Chemistry and Chemical Biology and b School and potential applications. They can be used as electrodes for capacitors, in which their high work function

411

PID Admittance Control for an Upper Limb Exoskeleton Wen Yu, Jacob Rosen, Xiaoou Li  

E-Print Network [OSTI]

PID Admittance Control for an Upper Limb Exoskeleton Wen Yu, Jacob Rosen, Xiaoou Li Abstract PID control. Three force sensors in the upper-level send desired trajectories to the lower, a model-free PID type admittance control is applied, whose parameters can be designed by human impedance

Rosen, Jacob

412

Dynamic control of wind turbines Andrew Kusiak*, Wenyan Li, Zhe Song  

E-Print Network [OSTI]

Dynamic control of wind turbines Andrew Kusiak*, Wenyan Li, Zhe Song Department of Mechanical Keywords: Wind turbine Wind energy Data mining Model predictive control Evolutionary computation algorithm Control strategy optimization a b s t r a c t The paper presents an intelligent wind turbine control

Kusiak, Andrew

413

Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications  

SciTech Connect (OSTI)

Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

Kam, Kinson; Doeff, Marca M.

2010-12-01T23:59:59.000Z

414

Mercury Flow through a Long Curved Pipe Wenhai Li & Foluso Ladeinde  

E-Print Network [OSTI]

Mercury Flow through a Long Curved Pipe Wenhai Li & Foluso Ladeinde Department of Mechanical Engineering Stony Brook University Summary The flow of mercury in a long, curved pipe is simulated that includes the effects of the viscosity of mercury, turbulence in the pipe, pressure force, and pipe friction

McDonald, Kirk

415

Li Conductivity in LixMPO4 ,,M Mn, Fe, Co, Ni... Olivine Materials  

E-Print Network [OSTI]

diffusivity may become quite relevant. In addition, the role of electrical vs. ionic conductivity is not clear and an estimate for Li diffusion constants, in the absence of electrical conductivity constraints, is made energy barriers to cross between the channels. Without electrical conductivity limitations the intrinsic

Ceder, Gerbrand

416

A new communication paradigm for mobile TV over cellular network Dr. Hongxiang Li  

E-Print Network [OSTI]

A new communication paradigm for mobile TV over cellular network Dr. Hongxiang Li Electrical terrestrial TV network and propose a new mobile TV communication paradigm that is radically different from and communication theory (i.e., Network Coding and Dirty Paper Coding) in the new mobile TV system design. Despite

417

Friedman et al. on Eagly & Wood ...1059 Kenrick & Li on Eagly & Wood ......1060  

E-Print Network [OSTI]

Comment Contents Friedman et al. on Eagly & Wood ...1059 Kenrick & Li on Eagly & Wood ......1060 Kleyman on Eagly & Wood ............ 1061 Wood & Eagly reply ....................... 1062 Chan on Peng J. Scheyd University of Texas at Austin Eagly and Wood (June 1999) argued that social structural

Pillow, Jonathan

418

Gravity inversion using a binary formulation Richard A. Krahenbuhl* and Yaoguo Li  

E-Print Network [OSTI]

Gravity inversion using a binary formulation Richard A. Krahenbuhl* and Yaoguo Li Gravity contrast that gives rise to zero gravity response on the surface. As a result, part of the salt structure structure using gravity data can be divided into two general categories. The first are interface inversions

419

Charge-Transfer-Induced Cesium Superlattices on Graphene Can-Li Song,1,2  

E-Print Network [OSTI]

Charge-Transfer-Induced Cesium Superlattices on Graphene Can-Li Song,1,2 Bo Sun,3 Yi-Lin Wang,1 Ye) adsorption on graphene formed on a 6H-SiC(0001) substrate by a combined scanning tunneling microscopy-defined 6 6 substrate superstructure and on multilayer graphene. By finely controlling the graphene

Wang, Wei Hua

420

High-capacity Li2Sgraphene oxide composite cathodes with stable cycling performance  

E-Print Network [OSTI]

oxide onto the surface of Li2S through favorable lithiumoxygen interactions helps to minimize and grid energy storage applica- tions.16 Although rechargeable lithium-ion batteries are widely used-mentioned applications.16 The major limiting factor in lithium-ion batteries today is the low theoretical capacity

Cui, Yi

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Strong and ductile nanostructured Cu-carbon nanotube composite Hongqi Li,1,a  

E-Print Network [OSTI]

Strong and ductile nanostructured Cu-carbon nanotube composite Hongqi Li,1,a Amit Misra,1 Zenji composite grain size 25 nm with high strength and good ductility was developed. Pillar testing reveals properties make CNTs an ideal nanoscale reinforcement to tailor multifunctional composites with optimal

Zhu, Yuntian T.

422

Method for improving voltage regulation of batteries, particularly Li/FeS/sub 2/ thermal batteries  

DOE Patents [OSTI]

Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS/sub 2/ system.

Godshall, N.A.

1986-06-10T23:59:59.000Z

423

Automated Self-Assembly Programming Paradigm: Initial Investigations Lin Li, Natalio Krasnogor, Jon Garibaldi  

E-Print Network [OSTI]

Automated Self-Assembly Programming Paradigm: Initial Investigations Lin Li, Natalio Krasnogor, Jon This paper presents a model that simulates a self- assembly process for software components. Initial inves- tigations on the Automated Self-Assembly Programming Paradigm (ASAP2 ) is presented whereby software compo

Aickelin, Uwe

424

Prediction of the AL index using solar wind Xinlin Li,1,2,5  

E-Print Network [OSTI]

Prediction of the AL index using solar wind parameters Xinlin Li,1,2,5 Kap Soo Oh,1,3 and M. [1] Two empirical models, one simple, one more complex, are introduced to predict the AL index are based on solar wind and magnetometer data from the year 1995. The simple model predicts the 10-min

Li, Xinlin

425

The study of threshold behaviour of effective potential for $^{6}$Li+$^{58,64}$Ni systems  

E-Print Network [OSTI]

The elastic scattering for $^6$Li+$^{64}$Ni system was measured in the bombarding energy range of 13 MeV $\\leq$ $E_{lab}$ $\\leq$ 26 MeV. A phenomenological optical model analysis was performed and the behaviour of the surface strengths of the potential components with decreasing energy was extracted. A further analysis of the measured angular distributions, along with the existing data for $^6$Li+$^{58}$Ni, was performed with two different model potentials - one with the folded potential normalized with a complex factor (OMP1) and the other with a {\\it hybrid} potential composed of a renormalized folded real and a phenomenological imaginary (OMP2) potential components - were used in the calculation. All the model potentials predict similar energy dependent behaviour for the interaction potential around the barrier. The observed energy dependence of the strengths of the real and imaginary potentials corroborate with the dispersion relation prediction for both the $^6$Li+$^{64}$Ni and $^6$Li+$^{58}$Ni systems. Though the evidence of breakup is distinct in the energy variation of the potential strengths, close to the barrier the variation is more in the line of conventional threshold anomaly. Also the threshold behaviour of the interaction potential does not indicate any distinct isotopic dependence.

M. Biswas; Subinit Roy; M. Sinha; M. K. Pradhan; A. Mukherjee; P. Basu; H. Majumdar; K. Ramachandran; A. Shrivastava

2008-01-30T23:59:59.000Z

426

Computer Vision Technology for Applications to Assist Blind Dr. Ying-Li Tian, Associate Professor  

E-Print Network [OSTI]

Professor Dept of Electrical Engineering The City College, City University of New York Time: 2:00 pm, March-Li Tian is an associate professor in the Department of Electrical Engineering at the City College of New of the inventors of the IBM Smart Surveillance Solutions (SSS) product and was leading the video analytics team

Zhu, Zhigang

427

Novel Magnesium Alloys Developed for Biomedical Application: A Review Nan Li, Yufeng Zheng*  

E-Print Network [OSTI]

Novel Magnesium Alloys Developed for Biomedical Application: A Review Nan Li, Yufeng Zheng* State in the development of magnesium alloys both for industrial and biomedical applications. Industrial interest in magnesium alloys is based on strong demand of weight reduction of transportation vehicles for better fuel

Zheng, Yufeng

428

ENERGY EFFICIENT TURBO BASED SPACE-TIMECODER YumingZhu, Laura Li and ChaitaliChakrabarti  

E-Print Network [OSTI]

ENERGY EFFICIENT TURBO BASED SPACE-TIMECODER YumingZhu, Laura Li and ChaitaliChakrabarti Department that Space-Time code is an effective approach to increasing the data rate over wireless channels. Turbo of the Turbo codes. In this paper, we compare two Turbo-based Space-Time Codes and their approximate versions

Kambhampati, Subbarao

429

Results from Infrared Spectral Observation of 1991 Total Solar Eclipse Hui Li and Jianqi You  

E-Print Network [OSTI]

et al. 1992; Deming et al. 1992; Sime and Streete 1993). The solar eclipse observation team of ChinaResults from Infrared Spectral Observation of 1991 Total Solar Eclipse Hui Li and Jianqi You Purple Mountain Observatory, CAS, Nanjing 210008, P. R. China Abstract. We describe in this paper the data

Li, Hui

430

REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE  

SciTech Connect (OSTI)

Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

2013-08-06T23:59:59.000Z

431

SFU LiFeLong Learning 2011/2012 Community Report  

E-Print Network [OSTI]

Learning 2 #12;Appendix 1: Organizational Structure [ 28 ] Appendix 2: Enrolment [ 29 ] Appendix 3: FinanceSFU LiFeLong Learning 2011/2012 Community Report #12;As part of the engaged university, SFU Lifelong Learning takes pride in helping people in our community enhance their lives through education. We

432

Nonlinear Control Via PDC: The TORA System Example Hua Wang and Jing Li  

E-Print Network [OSTI]

Nonlinear Control Via PDC: The TORA System Example Hua Wang and Jing Li Dept. of Electrical the stabilty of the system. The PDC controller design is to derive each control rule for each linear model­S model, we can analyze or design the PDC controller. In this paper, our main focus is on a nonlinear

433

Maps preserving the joint numerical radius distance of operators Chi-Kwong Li  

E-Print Network [OSTI]

Maps preserving the joint numerical radius distance of operators Chi-Kwong Li and Edward Poon Dedicated to Professor David Lutzer on the occasion of his retirement. Abstract Denote the joint numerical radius of an m-tuple of bounded operators A = (A1, . . . , Am) by w(A). We give a complete description

Li, Chi-Kwong

434

Emergence and control of heat current from strict zero thermal bias Jie Ren* and Baowen Li  

E-Print Network [OSTI]

energy transport. An open question is whether we can create and control heat current at strict zero future. Heat transfers spontaneously from a high temperature to a low one; thus, the control of heatEmergence and control of heat current from strict zero thermal bias Jie Ren* and Baowen Li NUS

Li, Baowen

435

3D Interactive Room Organizer Eranda De Alwis and Baihua Li  

E-Print Network [OSTI]

3D Interactive Room Organizer Eranda De Alwis and Baihua Li Department of Computing and Mathematics in position. To resolve the problem, we present the prototype implementation of a web-based 3D interactive to interact with furniture and other elements in the room, and arrange them properly in 3D world. The user can

Li, Baihua

436

Relative grain boundary area and energy distributions in nickel Jia Li, Shen J. Dillon 1  

E-Print Network [OSTI]

Relative grain boundary area and energy distributions in nickel Jia Li, Shen J. Dillon 1 , Gregory boundary energies and areas are inversely correlated. 2009 Acta Materialia Inc. Published by Elsevier Ltd and focused ion beam serial sectioning. These data have been used to determine the relative areas of different

Rohrer, Gregory S.

437

Scaling IP Multicast on Datacenter Topologies Xiaozhou Li and Michael J. Freedman  

E-Print Network [OSTI]

Scaling IP Multicast on Datacenter Topologies Xiaozhou Li and Michael J. Freedman Princeton datacenter applications' communication. Unfor- tunately, traditional protocols for managing IP multicast structure of modern datacenter networks in order to build the first scale-out multicast architecture. In our

Singh, Jaswinder Pal

438

Structure and Dynamics of Colliding Plasma Jets C. K. Li,1,* D. D. Ryutov,2  

E-Print Network [OSTI]

Structure and Dynamics of Colliding Plasma Jets C. K. Li,1,* D. D. Ryutov,2 S. X. Hu,3 M. J at various angles shed light on the structures and dynamics of these collisions. The observations compare noncollinear jets, the observed flow structure is similar to the analytic model's prediction of a character

439

Partial Encryption of Compressed Images and Videos \\Lambda Howard Cheng y and Xiaobo Li z  

E-Print Network [OSTI]

Partial Encryption of Compressed Images and Videos \\Lambda Howard Cheng y and Xiaobo Li z, if not impossible, to carry out real­time secure image and video communication and processing. Methods have been of the compressed data. Partial encryption is applied to several image and video compression algorithms

Cheng, Howard

440

Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries  

E-Print Network [OSTI]

with graphene. Incorporation of graphene increases thermal conductivity of phase change materials. Graphene that common PCMs are characterized by very low thermal conductivity, K, with typical values in the range of 0Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Electrostatic Energy Harvester and Li-Ion Charger Circuit for Micro-Scale Applications  

E-Print Network [OSTI]

, low duty-cycle task multiplex- ing, and smart power-aware networks, the energy stored in micro- scaleElectrostatic Energy Harvester and Li-Ion Charger Circuit for Micro-Scale Applications Erick O micro-systems like biomedical implants and ad-hoc wireless transceiver micro-sensors continue

Rincon-Mora, Gabriel A.

442

Remanence enhancement in magnetically interacting particles Heliang Qu and Jiang Yu Li*  

E-Print Network [OSTI]

, which completely characterizes the remanence of magnets if the exchange coupling is negligible of remanence for most permanent magnets, the re- cent development of exchange-spring magnets make the asRemanence enhancement in magnetically interacting particles Heliang Qu and Jiang Yu Li* Department

Li, Jiangyu

443

Cooling output optimization of an air handling unit Andrew Kusiak *, Mingyang Li  

E-Print Network [OSTI]

supply temperature and supply air temperature in response to the dynamic cooling load and changingCooling output optimization of an air handling unit Andrew Kusiak *, Mingyang Li Department mining Neural network Multi-objective optimization Evolutionary computation Dynamic modeling Cooling

Kusiak, Andrew

444

Frequent Pattern Mining for Kernel Trace Data Christopher LaRosa, Li Xiong, Ken Mandelberg  

E-Print Network [OSTI]

, application programmers, operating systems engineers, and security analysts. In the systems area, data miningFrequent Pattern Mining for Kernel Trace Data Christopher LaRosa, Li Xiong, Ken Mandelberg patterns and other recurring runtime execution patterns in operating system trace logs, we employ data

Xiong, Li

445

Mining Logs Files for Computing System Management Wei Peng, Tao Li  

E-Print Network [OSTI]

reporting, asynchronous data collection, and temporal characteristics in data representation. FirstMining Logs Files for Computing System Management Wei Peng, Tao Li School of Computer Science experts through a knowledge acquisition process to translate domain knowl- edge into operating rules

Li, Tao

446

Profile-Driven Energy Reduction in Network-on-Chips Feihui Li, Guangyu Chen, Mahmut Kandemir  

E-Print Network [OSTI]

connect and manage communications among a variety of design elements and Intellectual Property (IP) blocksProfile-Driven Energy Reduction in Network-on-Chips Feihui Li, Guangyu Chen, Mahmut Kandemir Department of computer Science and Engineering The Pennsylvania State University, USA {feli

Budiu, Mihai

447

Modular Dual Coolant Pb-17Li Blanket Design For ARIES-CS Compact Stellarator Power Plant  

E-Print Network [OSTI]

of the study. The preferred blanket concept is a dual coolant blanket with a He- cooled ferritic steel firstModular Dual Coolant Pb-17Li Blanket Design For ARIES-CS Compact Stellarator Power Plant X.R. Wanga from the engineering effort during the second phase of ARIES-CS study on the conceptual design

Raffray, A. René

448

Electronic Origin For The Phase Transition From Amorphous LixSi To Crystalline Li15Si4  

SciTech Connect (OSTI)

Silicon has been widely explored as an anode material for lithium ion battery. Upon lithiation, silicon transforms to amorphous LixSi (a-LixSi) via electrochemical driven solid state amorphization. With increasing lithium concentration, a-LixSi transforms to crystalline Li15Si4 (c-Li15Si4). The mechanism of this crystallization process is not known. In this paper, we report the fundamental characteristics of the phase transition of a-LixSi to c-Li15Si4 using in-situ scanning transmission electron microscopy (STEM), electron energy loss spectroscopy (EELS), and density function theory (DFT) calculation. We find that when the lithium concentration in a-LixSi reaches a critical value of x = 3.75, the a-Li3.75Si spontaneously and congruently transforms to c-Li15Si4 by a process that is solely controlled by the lithium concentration in the a-LixSi, involving neither large scale atomic migration nor phase separation. DFT calculations indicate that c-Li15Si4 formation is favored over other possible crystalline phases due to the similarity in electronic structure with a-Li3.75Si.

Gu, Meng; Wang, Zhiguo; Connell, Justin G.; Perea, Daniel E.; Lauhon, Lincoln J.; Gao, Fei; Wang, Chong M.

2013-06-24T23:59:59.000Z

449

Effect of MoS{sub 2} on hydrogenation storage properties of LiBH{sub 4}  

SciTech Connect (OSTI)

The hydrogen storage properties of LiBH{sub 4} ball milled with 20 wt% MoS{sub 2} have been investigated. It shows that the LiBH{sub 4} doped with MoS{sub 2} exhibits favorable hydrogenation and dehydrogenation properties in terms of decomposition temperature and hydriding/dehydriding reversibility. The sample with MoS{sub 2} starts to release hydrogen at 230 C and has a decrease of 80 C in contrast with pristine LiBH{sub 4}. Furthermore, for the second cycle, the LiBH{sub 4} with MoS{sub 2} maintains a reversible hydrogen storage capacity of about 8.0 wt% which is almost identical with the first cycle under 5 MPa at 550 C. Analyzed by the XRD and the FTIR results, LiBH{sub 4} can be regenerated after re-hydrogenation under a relatively mild condition by adding MoS{sub 2}. The improvement of the hydrogenation and dehydrogenation properties mainly results from the formation of Li{sub 2}S and MoB{sub 2} during ball milling. -- Graphical abstract: Hydrogen absorption curves of LiBH{sub 4} doped with MoS{sub 2} for five cycles at 400 C. Highlights: The hydrogen absorption capacity is nearly the same for 5 cycles at 400 C. The sample with MoS{sub 2} starts to release hydrogen at 230 C. The coexistence of MoB{sub 2} and Li{sub 2}S catalyzes the decomposition of LiBH{sub 4}.

Liang, Dan [College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Han, Shumin, E-mail: hanshm@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Wang, Jiasheng [College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Zhang, Wei [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Zhao, Xin; Zhao, Ziyang [College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China)

2014-03-15T23:59:59.000Z

450

Electrolyte Solvation and Ionic Association. V. Acetonitrile-Lithium Bis(fluorosulfonyl)imide (LiFSI) Mixtures  

SciTech Connect (OSTI)

Electrolytes with the salt lithium bis(fluorosulfonyl)imide (LiFSI) have been evaluated relative to comparable electrolytes with other lithium salts. Acetonitrile (AN) has been used as a model electrolyte solvent. The information obtained from the thermal phase behavior, solvation/ionic association interactions, quantum chemical (QC) calculations and molecular dynamics (MD) simulations (with an APPLE&P many-body polarizable force field for the LiFSI salt) of the (AN)n-LiFSI mixtures provides detailed insight into the coordination interactions of the FSI- anions and the wide variability noted in the electrolyte transport property (i.e., viscosity and ionic conductivity).

Han, Sang D.; Borodin, Oleg; Seo, D. M.; Zhou, Zhi B.; Henderson, Wesley A.

2014-09-30T23:59:59.000Z

451

A Computational Investigation of Li(subscript 9)M(subscript 3)(P(subscript 2)O(subscript 7))(subscript 3)(PO(subscript 4))(subscript 2) (M = V, Mo) as Cathodes for Li Ion Batteries  

E-Print Network [OSTI]

Cathodes with high energy density and safety are sought to improve the performance of Li ion batteries for electric vehicle and consumer electronics applications. In this study, we examine the properties of the potential ...

Jain, Anubhav

452

Three-Dimensionally Ordered Macroporous Li4Ti5O12: Effect of Wall Structure on Electrochemical Properties  

E-Print Network [OSTI]

Three-Dimensionally Ordered Macroporous Li4Ti5O12: Effect of Wall Structure on Electrochemical, and the materials evaluated in lithium ion battery cells. The 3DOM architecture was found to markedly improve

Poeppelmeier, Kenneth R.

453

Astrophysical S factor for the radiative-capture reaction p{sup 6}Li {yields} {sup 7}Be{gamma}  

SciTech Connect (OSTI)

A new measurement of differential cross sections for elastic p{sup 6}Li scattering in the energy range 0.35-1.2 MeV was performed. A partial-wave analysis of the data obtained in this way was carried out, and potentials simulating the p{sup 6}Li interaction were constructed. Various experiments devoted to studying elastic p{sup 6}Li scattering over the broad energy range of 0.5-50 MeV were analyzed on the basis of the optical model. By using the potentials obtained from the partial-wave analysis, the possibility of describing the astrophysical S factor for radiative proton capture on {sup 6}Li at low energies was considered within the potential cluster model involving forbidden states.

Dubovichenko, S. B., E-mail: sergey@dubovichenko.ru [National Space Agency of the Republic of Kazakhstan, Fessenkov Astrophysical Institute, National Center of Space Research and Technology (Kazakhstan); Burtebaev, N., E-mail: burteb@inp.kz; Zazulin, D. M.; Kerimkulov, Zh. K. [National Nuclear Center of Republic of Kazakhstan, Institute of Nuclear Physics (Kazakhstan); Amar, A. S. A. [Al-Farabi Kazakh National University (Kazakhstan)

2011-07-15T23:59:59.000Z

454

Vehicle Technologies Office Merit Review 2014: Advanced High Energy Li-Ion Cell for PHEV and EV Applications  

Broader source: Energy.gov [DOE]

Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced high energy Li-ion cell for PHEV...

455

OpcnGL Extensions and Restrictions for PixclFlo\\v UHivP.rsity or Nor! li Cnrolilla  

E-Print Network [OSTI]

.1.1 Example. 7.2 1.~sing Shadns .. 7.2.1 ExamplP. 7.3 Shading API Definitions 7.4 To liP Dmw . . . . . . 8

North Carolina at Chapel Hill, University of

456

Solving Regular Tree Grammar Based Constraints ? Yanhong A. Liu 1 , Ning Li 2 , and Scott D. Stoller 1  

E-Print Network [OSTI]

Solving Regular Tree Grammar Based Constraints ? Yanhong A. Liu 1 , Ning Li 2 , and Scott D and is then simpli#12;ed according to a set of simpli#12;cation rules to produce the solution. Usually

Liu, Yanhong Annie

457

Isotopic Tailoring to Improve the Breeding Capability of the Sn-Li Eutectic in Liquid First Wall Fusion Blanket Concepts  

SciTech Connect (OSTI)

Due to its low vapor pressure, the Sn-Li eutectic has been identified as a potential breeder for deployment in the liquid first wall (FW)/Blanket concepts under investigation in the APEX study for high power density fusion reactors. However, its breeding capability is limited. This drawback is rather improved due to the neutron multiplication via Sn(n,2n) reactions. However, the 'local' tritium breeding ratio (TBR) was found to be still on the marginal side (even with 90%Li-6 enrichment). Aside from using a beryllium multiplier, other means to improve the capability of Sn-Li for breeding are explored. In this paper, we show that by isotopic tailoring of Tin in the Sn-Li breeder, one can achieve substantial improvement in TBR in addition to attaining significant reduction in the activation level in this material.

Youssef, Mahmoud Z. [University of California-Los Angeles (United States)

2003-09-15T23:59:59.000Z

458

Designing materials for energy storage with high power and energy density : LiFePO? cathode material  

E-Print Network [OSTI]

LiFePO? has drawn a lot of attention as a cathode material in lithium rechargeable batteries because its structural and thermal stability, its inexpensive cost, and environmental friendliness meet the requirements of power ...

Kang, Byoungwoo

2010-01-01T23:59:59.000Z

459

Energy-Saving Control of an Unstable Valve with a MR Brake QingHui Yuan and Perry Y. Li  

E-Print Network [OSTI]

to the effect of flow induced forces, QingHui Yuan is with Eaton Corporation Innovation Center, Eden Prairie, MN. QinghuiYuan@eaton.com P. Y. Li is with the Department of Mechanical Engineering, University of Minnesota

Li, Perry Y.

460

LINKPING UNIVERSITY DECISION Rector's Office 2005-09-12 Dnr LiU 1088/05-10  

E-Print Network [OSTI]

.D., Licentiate, Master's and undergraduate theses at LiU E-Press As a result of the decision of the University such as scientific journals). In the short term, focus will be on publishing Ph.D., Licentiate, Master

Zhao, Yuxiao

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions  

SciTech Connect (OSTI)

Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

2009-03-15T23:59:59.000Z

462

Neutron scattering study on cathode LiMn{sub 2}O{sub 4} and solid electrolyte 5(Li{sub 2}O)(P{sub 2}O{sub 5})  

SciTech Connect (OSTI)

Neutron scattering is very important technique in order to investigate the energy storage materials such as lithium-ion battery. The unique advantages, neutron can see the light atoms such as Hydrogen, Lithium, and Oxygen, where those elements are negligible by other corresponding X-ray method. On the other hand, the energy storage materials, such as lithium ion battery is very important for the application in the electric vehicles, electronic devices or home appliances. The battery contains electrodes (anode and cathode), and the electrolyte materials. There are many challenging to improve the existing lithium ion battery materials, in order to increase their life time, cyclic ability and also its stability. One of the most scientific challenging is to investigate the crystal structure of both electrode and electrolyte, such as cathodes LiCoO{sub 2}, LiMn{sub 2}O{sub 4} and LiFePO{sub 4}, and solid electrolyte Li{sub 3}PO{sub 4}. Since all those battery materials contain Lithium ions and Oxygen, the used of neutron scattering techniques to study their structure and related properties are very important and indispensable. This article will review some works of investigating electrodes and electrolytes, LiMn{sub 2}O{sub 4} and 5(Li{sub 2}O)(P{sub 2}O{sub 5}), by using a high resolution powder diffraction (HRPD) at the multipurpose research reactor, RSG-Sywabessy of the National Nuclear Energy Agency (BATAN), Indonesia.

Kartini, E., E-mail: kartini@batan.go.id; Putra, Teguh P., E-mail: kartini@batan.go.id; Jahya, A. K., E-mail: kartini@batan.go.id; Insani, A., E-mail: kartini@batan.go.id [Technology Center for Nuclear Industry Materials, National Nuclear Energy Agency, Serpong 15314 (Indonesia); Adams, S. [Department of Materials Science and Engineering, National University of Singapore, Singapore-117576 (Singapore)

2014-09-30T23:59:59.000Z

463

Deuteron scattering on {sup 6}Li at an energy of 25 MeV  

SciTech Connect (OSTI)

At an energy of 25 MeV and in the angular range 7{sup o}-175{sup o} in the laboratory frame, angular distributions were measured for elastic deuteron scattering on {sup 6}Li nuclei and for the respective inelastic-scattering processes accompanied by the transitions to the ground state (1+) of the {sup 6}Li nucleus and to its excited state at E{sub x} = 2.186 MeV (J{sup {pi}} = 3{sup +}). The resulting data were analyzed on the basis of the optical model of the nucleus and the coupled-reaction-channel method with allowance for the mechanism of alpha-particle-cluster exchange. It is shown that only upon including, in the analysis, channel coupling and the exchange mechanism can the experimental cross sections for elastic and inelastic scattering be reproduced over the entire range of angles.

Burtebayev, N. [National Nuclear Center of the Republic of Kazakhstan, Institute of Nuclear Physics (Kazakhstan); Artemov, S. V. [Uzbek Academy of Sciences, Institute of Nuclear Physics (Uzbekistan); Duisebayev, B. A.; Kerimkulov, Zh. K. [National Nuclear Center of the Republic of Kazakhstan, Institute of Nuclear Physics (Kazakhstan); Kuranov, S. B. [Uzbek Academy of Sciences, Institute of Nuclear Physics (Uzbekistan); Sakuta, S. B., E-mail: sakuta@dni.polyn.kiae.s [Russian Research Center Kurchatov Institute (Russian Federation)

2010-05-15T23:59:59.000Z

464

The High-Resolution Lightweight Telescope for the EUV (HiLiTE)  

SciTech Connect (OSTI)

The High-resolution Lightweight Telescope for the EUV (HiLiTE) is a Cassegrain telescope that will be made entirely of Silicon Carbide (SiC), optical substrates and metering structure alike. Using multilayer coatings, this instrument will be tuned to operate at the 465 {angstrom} Ne VII emission line, formed in solar transition region plasma at {approx}500,000 K. HiLiTE will have an aperture of 30 cm, angular resolution of {approx}0.2 arc seconds and operate at a cadence of {approx}5 seconds or less, having a mass that is about 1/4 that of one of the 20 cm aperture telescopes on the Atmospheric Imaging Assembly (AIA) instrument aboard NASA's Solar Dynamics Observatory (SDO). This new instrument technology thus serves as a path finder to a post-AIA, Explorer-class missions.

Martinez-Galarce, D S; Boerner, P; Soufli, R; De Pontieu, B; Katz, N; Title, A; Gullikson, E M; Robinson, J C; Baker, S L

2008-06-02T23:59:59.000Z

465

Importance of $1n$-stripping process in the $^{6}$Li+$^{159}$Tb reaction  

E-Print Network [OSTI]

The inclusive cross sections of the $\\alpha$-particles produced in the reaction $^{6}$Li+$^{159}$Tb have been measured at energies around the Coulomb barrier. The measured cross sections are found to be orders of magnitude larger than the calculated cross sections of $^{6}$Li breaking into $\\alpha$ and $d$ fragments, thus indicating contributions from other processes. The experimental cross sections of $1n$-stripping and $1n$-pickup processes have been determined from an entirely different measurement, reported earlier. Apart from incomplete fusion and/ $d$-transfer processes, the $1n$-stripping process is found to be a significant contributor to the inclusive $\\alpha$-particle cross sections in this reaction.

M. K. Pradhan; A. Mukherjee; Subinit Roy; P. Basu; A. Goswami; R. Kshetri; R. Palit; V. V. Parkar; M. Ray; M. Saha Sarkar; S. Santra

2013-12-10T23:59:59.000Z

466

Role of the cluster structure of $^7$Li in the dynamics of fragment capture  

E-Print Network [OSTI]

Exclusive measurements of prompt $\\gamma$-rays from the heavy-residues with various light charged particles in the $^7$Li + $^{198}$Pt system, at an energy near the Coulomb barrier (E/$V_b$ $\\sim$ 1.6) are reported. Recent dynamic classical trajectory calculations, constrained by the measured fusion, $\\alpha$ and $t$ capture cross-sections have been used to explain the excitation energy dependence of the residue cross-sections. These calculations distinctly illustrate a two step process, breakup followed by fusion in case of the capture of $t$ and $\\alpha$ clusters; whereas for $^{6}$He + $p$ and $^{5}$He + $d$ configurations, massive transfer is inferred to be the dominant mechanism. The present work clearly demonstrates the role played by the cluster structures of $^7$Li in understanding the reaction dynamics at energies around the Coulomb barrier.

A. Shrivastava; A. Navin; A. Diaz-Torres; V. Nanal; K. Ramachandran; M. Rejmund; S. Bhattacharyya; A. Chatterjee; S. Kailas; A. Lemasson; R. Palit; V. V. Parkar; R. G. Pillay; P. C. Rout; Y. Sawant

2012-12-17T23:59:59.000Z

467

Preliminary Analysis on Linac Oscillation Data LI05-19 and Wake Field Energy Loss in FACET Commissioning 2012  

SciTech Connect (OSTI)

In this note, preliminary analysis on linac ocsillation data in FACET linac LI05-09 plus LI11-19 is presented. Several quadrupoles are identified to possibly have different strength, compared with their designed strength in the MAD optics model. The beam energy loss due to longitudinal wake fields in the S-band linac is also analytically calculated, also by LITRACK numerical simulations.

Sun, Yipeng; /SLAC

2012-07-23T23:59:59.000Z

468

Synthesis of rock-salt type lithium borohydride and its peculiar Li{sup +} ion conduction properties  

SciTech Connect (OSTI)

The high energy density and excellent cycle performance of lithium ion batteries makes them superior to all other secondary batteries and explains why they are widely used in portable devices. However, because organic liquid electrolytes have a higher operating voltage than aqueous solution, they are used in lithium ion batteries. This comes with the risk of fire due to their flammability. Solid electrolytes are being investigated to find an alternative to organic liquid. However, the nature of the solid-solid point contact at the interface between the electrolyte and electrode or between the electrolyte grains is such that high power density has proven difficult to attain. We develop a new method for the fabrication of a solid electrolyte using LiBH{sub 4,} known for its super Li{sup +} ion conduction without any grain boundary contribution. The modifications to the conduction pathway achieved by stabilizing the high pressure form of this material provided a new structure with some LiBH{sub 4}, more suitable to the high rate condition. We synthesized the H.P. form of LiBH{sub 4} under ambient pressure by doping LiBH{sub 4} with the KI lattice by sintering. The formation of a KI - LiBH{sub 4} solid solution was confirmed both macroscopically and microscopically. The obtained sample was shown to be a pure Li{sup +} conductor despite its small Li{sup +} content. This conduction mechanism, where the light doping cation played a major role in ion conduction, was termed the Parasitic Conduction Mechanism. This mechanism made it possible to synthesize a new ion conductor and is expected to have enormous potential in the search for new battery materials.

Miyazaki, R.; Maekawa, H.; Takamura, H., E-mail: takamura@material.tohoku.ac.jp [Department of Materials Science, Graduate School of Engineering, Tohoku University Aramaki Aoba 6-6-11-301-2-2, Sendai, Miyagi 980-8579 (Japan)

2014-05-01T23:59:59.000Z

469

Elaboration and Characterization of a Free Standing LiSICON Membrane for Aqueous Lithium-Air Battery  

E-Print Network [OSTI]

: Metal-air battery, Lithium anode, Li2O - Al2O3 - TiO2 - P2O5 system, LiPON, Solid electrolyte 1. Introduction Metal-air batteries are based on the use of a metal negative electrode in combination-sur-Loing, France Abstract In order to develop a LISICON separator for an aqueous lithium-air battery, a thin

Paris-Sud XI, Université de

470

Effects of Nb-doped on the structure and electrochemical performance of LiFePO{sub 4}/C composites  

SciTech Connect (OSTI)

The olivine-type niobium doping Li{sub 1?x}Nb{sub x}FePO{sub 4}/C (x=0, 0.005, 0.010, 0.015, 0.025) cathode materials were synthesized via a two-step ball milling solid state reaction. The effects of Nb doping were charactered by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), galvanostatic intermittent titration technique (GITT), cyclic voltammetry (CV), electrochemical impedance spectra (EIS) and galvanostatic chargedischarge. It is found that Nb doping enlarges the interplanar distance of crystal plane parallel to [0 1 0] direction in LiFePO{sub 4}. In other words, it widens the one dimensional diffusion channels of Li{sup +} along the [0 1 0] direction. Electrochemical test results indicate that the Li{sub 0.99}Nb{sub 0.01}FePO{sub 4}/C composite exhibits the best electrochemical performance with initial special discharge capacity of 139.3 mA h g{sup ?1} at 1 C rate. The present synthesis route is promising in making the solid state reaction method more practical for preparation of the LiFePO{sub 4} material. - Graphical abstract: The proper amount of Nb doping widens the one dimensional diffusion channels of Li{sup +} along the [0 1 0] direction. Display Omitted - Highlights: The Nb doping LiFePO{sub 4}/C is prepared by a facile two-step ball milling solid state reaction. The sample possesses the better high-rate performance. The tap density of Li{sub 0.99}Nb{sub 0.01}FePO{sub 4}/C sample is 1.76 g cm{sup ?3}.

Ma, Zhipeng [Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); Shao, Guangjie, E-mail: shaoguangjie@ysu.edu.cn [Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China); State Key Laboratory of Metastable Materials Science and Technology, Qinhuangdao 066004 (China); Wang, Guiling; Zhang, Ying; Du, Jianping [Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China)

2014-02-15T23:59:59.000Z

471

Dislocation mechanics of high rate deformations Ron Armstrong* (and Qizhen Li**)  

E-Print Network [OSTI]

Dislocation mechanics of high rate deformations Ron Armstrong* (and Qizhen Li**) *University/dt) = (1/m)b (1/m)(d/dt)bxd 8 charts 1.a. TASRA, Zerilli-Armstrong (Z-A) and Johnson-Cook relations 1.b) (Hall-Petch) Twinning: T = 0T + kT-1/2 ; kT > k R.W. Armstrong, "Thermal Activation ­ Strain Rate

Maryland at College Park, University of

472

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

SciTech Connect (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

White, Ralph E.; Popov, Branko N.

2002-10-31T23:59:59.000Z

473

Anionic states of LiFLi Maciej Gutowski and Jack Simons  

E-Print Network [OSTI]

;,'symmetry and which have vertical detachment energies of 0.94 and 0.89 eV, respectively. The LiFLi+ cation earlier.3-7 DR anions, such as the Td iso- mer of NH, or the C3, isomer of H30-, consist of a closed-shell experimentally studied yet. II. COMPUTATIONAL ASPECTS For the lithium atom, we used the Dunning (9s5p/ 3~2~) one

Simons, Jack

474

Studies of Optical Damage in Photorefractive Single LiNbO3 Crystals using Imaging Polarimetry  

E-Print Network [OSTI]

The optical damage of photorefractive material, single LiNbO3 crystal, is experimentally studied. The specimen has been illuminated with the radiation of continuous Ar-laser (the wavelength of 488 nm) focused to 35?m spot. The induced birefringence map is obtained by means of imaging polarimeter. Promising resources of the experimental setup for detecting laser-induced damage in photorefractive materials is demonstrated.

O. Krupych; I. Smaga; R. Vlokh

2007-08-15T23:59:59.000Z

475

Inclusion property of Cs, Sr, and Ba impurities in LiCl crystal formed by layer-melt crystallization  

SciTech Connect (OSTI)

Pyroprocessing is one of the promising technologies enabling the recycling of spent nuclear fuels from a commercial light water reactor (LWR). In general, pyroprocessing uses dry molten salts as electrolytes. In particular, LiCl waste salt after pyroprocessing contains highly radioactive I/II group fission products mainly composed of Cs, Sr, and Ba impurities. Therefore, it is beneficial to reuse LiCl salt in the pyroprocessing as an electrolyte for economic and environmental issues. Herein, to understand the inclusion property of impurities within LiCl crystal, the physical properties such as lattice parameter change, bulk modulus, and substitution enthalpy of a LiCl crystal having 0-6 at% Cs{sup +} or Ba{sup 2+} impurities under existence of 1 at% Sr{sup 2+} impurity were calculated via the first-principles density functional theory. The substitution enthalpy of LiCl crystals having 1 at% Sr{sup 2+} showed slightly decreased value than those without Sr{sup 2+} impurity. Therefore, through the substitution enthalpy calculation, it is expected that impurities will be incorporated within LiCl crystal as co-existed form rather than as a single component form. (authors)

Choi, Jung-Hoon; Cho, Yung-Zun; Lee, Tae-Kyo; Eun, Hee-Chul; Kim, Jun-Hong; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il [Nuclear Fuel Cycle Waste Treatment Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

476

Far-infrared study of K giants in the solar neighborhood: Connection between Li enrichment and mass-loss  

E-Print Network [OSTI]

We searched for a correlation between the two anomalous properties of K giants: Li enhancement and IR excess from an unbiased survey of a large sample of RGB stars. A sample of 2000 low-mass K giants with accurate astrometry from the Hipparcos catalog was chosen for which Li abundances have been determined from low-resolution spectra. Far-infrared data were collected from the $WISE$ and $IRAS$ catalogs. To probe the correlation between the two anomalies, we supplemented 15 Li-rich K giants discovered from this sample with 25 known Li-rich K giants from other studies. Dust shell evolutionary models and spectral energy distributions were constructed using the code DUSTY to estimate different dust shell properties, such as dust evolutionary time scales, dust temperatures, and mass-loss rates. Among 2000 K giants, we found about two dozen K giants with detectable far-IR excess, and surprisingly, none of them are Li-rich. Similarly, the 15 new Li-rich K giants that were identified from the same sample show no evid...

Kumar, Y Bharat; Muthumariappan, C; Zhao, G

2015-01-01T23:59:59.000Z

477

General limit on the relation between abundances of D and $^7$Li in big bang nucleosynthesis with nucleon injections  

E-Print Network [OSTI]

The injections of energetic hadrons could have occurred in the early universe by decays of hypothetical long-lived exotic particles. The injections induce the showers of nonthermal hadrons via nuclear scattering. Neutrons generated at these events can react with $^7$Be nuclei and reduce $^7$Be abundance solving a problem of the primordial $^7$Li abundance. We suggest that thermal neutron injection is a way to derive a model independent conservative limit on the relation between abundances of D and $^7$Li in a hadronic energy injection model. We emphasize that an uncertainty in cross sections of inelastic $n+p$ scattering affects the total number of induced neutrons, which determines final abundances of D and $^7$Li. In addition, the annihilations of antinucleons with $^4$He result in higher D abundance and trigger nonthermal $^6$Li production. It is concluded that a reduction of $^7$Li abundance from a value in the standard big bang nucleosynthesis (BBN) model down to an observational two $\\sigma$ upper limit is necessarily accompanied by an undesirable increase of D abundance up to at least an observational 12 $\\sigma$ upper limit from observations of quasi-stellar object absorption line systems. The effects of antinucleons and secondary particles produced in the hadronic showers always lead to a severer constraint. The BBN models involving any injections of extra neutrons are thus unlikely to reproduce a small $^7$Li abundance consistent with observations.

Motohiko Kusakabe; Myung-Ki Cheoun; K. S. Kim

2014-04-11T23:59:59.000Z

478

Structural transitions of ternary imide Li{sub 2}Mg(NH){sub 2} for hydrogen storage  

SciTech Connect (OSTI)

Phase transitions and energetic properties of Li{sub 2}Mg(NH){sub 2} with different crystal structures are investigated by experiments and first-principles calculations. The Li{sub 2}Mg(NH){sub 2} with the primitive cubic and orthorhombic structure is obtained by dynamically dehydrogenating a Mg(NH{sub 2}){sub 2}-2LiH mixture up to 280?C under an initial vacuum and 9.0?bars H{sub 2}, respectively. It is found that the obtained orthorhombic Li{sub 2}Mg(NH){sub 2} is converted to a primitive cubic structure as the dehydrogenation temperature is further increased to 400?C or performed by a 36?h of high-energetic ball milling. Moreover, the primitive cubic phase can be converted to an orthorhombic phase after heating at 280?C under 9.0?bars H{sub 2} for 1?h. Thermodynamic calculations show that the orthorhombic phase is the ground state structure of Li{sub 2}Mg(NH){sub 2}. The mechanism for phase transitions of Li{sub 2}Mg(NH){sub 2} is also discussed from the angle of energy.

Liang, C. [College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014 (China); State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Gao, M. X.; Pan, H. G., E-mail: hgpan@zju.edu.cn; Liu, Y. F. [State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province and Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

2014-08-25T23:59:59.000Z

479

Three-dimensional graphene/LiFePO{sub 4} nanostructures as cathode materials for flexible lithium-ion batteries  

SciTech Connect (OSTI)

Graphical abstract: Graphene/LiFePO{sub 4} composites as a high-performance cathode material for flexible lithium-ion batteries have been prepared by using a co-precipitation method to synthesize graphene/LiFePO4 powders as precursors and then followed by a solvent evaporation process. - Highlights: Flexible LiFePO{sub 4}/graphene films were prepared first time by a solvent evaporation process. The flexible electrode exhibited a high discharge capacity without conductive additives. Graphene network offers the electrode adequate strength to withstand repeated flexing. - Abstract: Three-dimensional graphene/LiFePO{sub 4} nanostructures for flexible lithium-ion batteries were successfully prepared by solvent evaporation method. Structural characteristics of flexible electrodes were investigated by X-ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy (SEM). Electrochemical performance of graphene/LiFePO{sub 4} was examined by a variety of electrochemical testing techniques. The graphene/LiFePO{sub 4} nanostructures showed high electrochemical properties and significant flexibility. The composites with low graphene content exhibited a high capacity of 163.7 mAh g{sup ?1} at 0.1 C and 114 mAh g{sup ?1} at 5 C without further incorporation of conductive agents.

Ding, Y.H., E-mail: yhding@xtu.edu.cn [College of Chemical Engineering, Xiangtan University, Hunan 411105 (China); Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China); Ren, H.M. [Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China); Huang, Y.Y. [BTR New Energy Materials Inc., Shenzhen 518000 (China); Chang, F.H.; Zhang, P. [Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China)

2013-10-15T23:59:59.000Z

480

Impedance spectroscopy study of SiO2-Li2O:Nd2O3 glasses  

SciTech Connect (OSTI)

In the present study, neodymium-doped lithium silicate glasses have been prepared by the conventional melt-quenching technique. The dielectric properties, electric modulus and electrical conductivity of SiO2-Li2O (SiLi-0Nd) and SiO2-Li2O:Nd2O3 (SiLi-1.35Nd) have been studied from 1 Hz to 1 MHz in the 333 423 K temperature range. At a given temperature and frequency, we observe that the resistivity increases while the conductivity accordingly decreases when neodymium ions are added to the glass matrix. The activation energy of two distinct regions was evaluated from the ln( dc)=f(1/T) plot and was found to be E1(T<363K)=0.61(0.66)eV and E2(T>363K)=1.26(1.09)eV for SiLi-0Nd (SiLi-1,35Nd). The dielectric constant ( Re) decreases while the dielectric loss (tan ( )) increases under Nd2O3 doping. We also observe that for both glasses, Re and tan ( ) tend to increase with increasing temperature and decrease with increasing frequency.

Pereia, R. [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil] [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil; Gozzo, C B [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil] [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil; Guedes, I. [Universidade Federal do Ceara, Ceara, Brazil] [Universidade Federal do Ceara, Ceara, Brazil; Boatner, Lynn A [ORNL] [ORNL; Terezo, A J [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil] [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil; Costa, M M [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil] [LACANM Laboratrio de Caracterizao em Novos Materiais - Brazil

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gy guyana li" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Lithium Diffusion in the Post-Recombination Universe and Spatial Variation of [Li/H  

E-Print Network [OSTI]

The observed amount of lithium for low metallicity population II stars (known as the Spite plateau) is a factor of $\\sim 3-5$ lower than the predictions of the standard cosmology. Since the observations are limited to the local Universe (halo stars, globular clusters and satellites of the Milky Way) it is possible that certain physical processes may have led to the spatial separation of lithium and local reduction of [Li/H]. We study the question of lithium diffusion after the cosmological recombination in sub-Jeans dark matter haloes, taking into account that more than 95% of lithium remains in the singly-ionized state at all times. Large scattering cross sections on the rest of the ionized gas leads to strong coupling of lithium to protons and its initial direction of diffusion coincides with that of H$^+$. In the rest frame of the neutral gas this leads to the diffusion of H$^+$ and Li$^+$ out of overdensities with the trend of reducing [Li/H] in the minima of gravitational wells relative to the primordial value. We quantify this process and argue that, with certain qualifications, it may have played a significant role in creating local lithium deficiency within the primordial dark matter haloes, comparable to those observed along the Spite plateau.

Maxim Pospelov; Niayesh Afshordi

2012-08-03T23:59:59.000Z

482

Optimized Operating Range for Large-Format LiFePO4/Graphite Batteries  

SciTech Connect (OSTI)

e investigated the long-term cycling performance of large format 20Ah LiFePO4/graphite batteries when they are cycled in various state-of-charge (SOC) ranges. It is found that batteries cycled in the medium SOC range (ca. 20~80% SOC) exhibit superior cycling stability than batteries cycled at both ends (0-20% or 80-100%) of the SOC even though the capcity utilized in the medium SOC range is three times as large as those cycled at both ends of the SOC. Several non-destructive techniques, including a voltage interruption approach, model-based parameter identification, electrode impedance spectra analysis, ?Q/?V analysis, and entropy change test, were used to investigate the performance of LiFePO4/graphite batteries within different SOC ranges. The results reveal that batteries at the ends of SOC exhibit much higher polarization impedance than those at the medium SOC range. These results can be attributed to the significant structural change of cathode and anode materials as revealed by the large entropy change within these ranges. The direct correlation between the polarization impedance and the cycle life of the batteries provides an effective methodology for battery management systems to control and prolong the cycle life of LiFePO4/graphite and other batteries.

Jiang, Jiuchun; Shi, Wei; Zheng, Jianming; Zuo, Pengjian; Xiao, Jie; Chen, Xilin; Xu, Wu; Zhang, Jiguang

2014-06-01T23:59:59.000Z

483

Single crystal growth and characterization of nearly stoichiometric LiVO{sub 2}  

SciTech Connect (OSTI)

LiVO{sub 2} undergoes an imperfectly understood orbital ordering transition near 500 K resulting in a loss of magnetic moment below the transition. Studies of the transition have been hampered by a lack of high-quality stoichiometric single crystals. Here we report the growth and basic characterization of large, nearly stoichiometric LiVO{sub 2} single crystals. The crystals were characterized by magnetic susceptibility, electrical resistivity, differential scanning calorimetry, and specific heat measurements over a temperature range from 2 to 650 K. A first-order phase transition with large hysteresis near T{sub t}{approx}500 K was observed in all measurements. An anisotropy of the order of 100 was observed in the in-plane versus out-of-plane resistivity, and the inferred semiconducting energy gap was 0.18 eV for TLiVO{sub 2} single crystals at temperatures below and above T{sub t}. Superlattice reflections were observed below T{sub t} and disappeared upon heating above the phase transition temperature. Upon cooling below T{sub t}, the supperlattice spots reappeared. Bright field electron micrographs indicate that the crystals develop a roughly hexagonal network of cracks.

Tian, W.; Chisholm, M.F.; Khalifah, P.G.; Jin, R.; Sales, B.C.; Nagler, S.E.; Mandrus, D

2004-07-02T23:59:59.000Z

484

Improved layered mixed transition metal oxides for Li-ion batteries  

SciTech Connect (OSTI)

Recent work in our laboratory has been directed towards development of mixed layered transition metal oxides with general composition Li[Ni, Co, M, Mn]O2 (M=Al, Ti) for Li ion battery cathodes. Compounds such as Li[Ni1/3Co1/3Mn1/3]O2 (often called NMCs) are currently being commercialized for use in consumer electronic batteries, but the high cobalt content makes them too expensive for vehicular applications such as electric vehicles (EV), plug-in hybrid electric vehicles (PHEVs), or hybrid electric vehicles (HEVs). To reduce materials costs, we have explored partial or full substitution of Co with Al, Ti, and Fe. Fe substitution generally decreases capacity and results in poorer rate and cycling behavior. Interestingly, low levels of substitution with Al or Ti improve aspects of performance with minimal impact on energy densities, for some formulations. High levels of Al substitution compromise specific capacity, however, so further improvements require that the Ni and Mn content be increased and Co correspondingly decreased. Low levels of Al or Ti substitution can then be used offset negative effects induced by the higher Ni content. The structural and electrochemical characterization of substituted NMCs is presented in this paper.

Doeff, Marca M.; Conry, Thomas; Wilcox, James

2010-03-05T23:59:59.000Z

485

A HIGH CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGET HEATING EXPERIMENTS  

SciTech Connect (OSTI)

The NDCX-II accelerator for target heating experiments has been designed to use a large diameter ({approx_equal} 10.9 cm) Li{sup +} doped alumino-silicate source with a pulse duration of 0.5 {micro}s, and beam current of {approx_equal} 93 mA. Characterization of a prototype lithium alumino-silicate sources is presented. Using 6.35mm diameter prototype emitters (coated on a {approx_equal} 75% porous tungsten substrate), at a temperature of {approx_equal} 1275 C, a space-charge limited Li{sup +} beam current density of {approx_equal} 1 mA/cm{sup 2} was measured. At higher extraction voltage, the source is emission limited at around {approx_equal} 1.5 mA/cm{sup 2}, weakly dependent on the applied voltage. The lifetime of the ion source is {approx_equal} 50 hours while pulsing the extraction voltage at 2 to 3 times per minute. Measurements show that the life time of the ion source does not depend only on beam current extraction, and lithium loss may be dominated by neutral loss or by evaporation. The life time of a source is around {ge} 10 hours in a DC mode extraction, and the extracted charge is {approx_equal} 75% of the available Li in the sample. It is inferred that pulsed heating may increase the life time of a source.

Roy, Prabir K.; Greenway, Wayne G.; Kwan, Joe W.; Seidl, Peter A.; Waldron, William L.

2011-03-23T23:59:59.000Z

486

Depth distribution of lithium in oxidized binary Al-Li alloys determined by secondary ion mass spectrometry and neutron depth profiling  

SciTech Connect (OSTI)

Oxidation of binary Al-Li alloys during short exposures at 530 C and long exposures at 200 C was studied with regard to the Li distribution. Secondary ion mass spectrometry (SIMS) and neutron depth profiling (NDP) were used to obtain quantitative Li depth profiles across the surface oxide layer and the underlying alloy. The underlying alloy was depleted in Li as a result of oxidation at 530 and 200 C. The SIMS and NDP results showed good mutual agreement and were used to evaluate the oxide thickness, the Li concentration at the oxide-ally interface, and the mass balance between oxide and alloy. The Li depletion profiles in the alloy were also calculated using the interdiffusion coefficients reported in the literature and compared with the measured profiles; the two profiles differed at 530 C but showed good agreement at 200 C.

Soni, K.K. (Univ. of Chicago, IL (United States)); Williams, D.B. (Lehigh Univ., Bethlehem, PA (United States)); Newbury, D.E.; Chi, P.; Downing, R.G.; Lamaza, G. (National Inst. of Standards and Technology, Gaithersburg, MD (United States))

1993-01-01T23:59:59.000Z

487

Electronic, structural, phonon dynamical, and CO{sub 2} capture properties of LiMZrO{sub 3} (M=Na, K) by ab initio thermodynamic investigation  

SciTech Connect (OSTI)

The electronic, structural and phonon properties of LiMZrO{sub 3} (M=Na, K) were investigated by the density functional theory and lattice phonon dynamics. Their thermodynamic properties for CO{sub 2} absorption/desorption were analyzed in comparison with the corresponding M{sub 2}ZrO{sub 3}. Two substituted configurations of LiMZrO{sub 3} were created from Li{sub 2}ZrO{sub 3}. Both types of LiNaZrO3 have direct band gaps with values of 3.84 eV and 3.49 eV respectively. While in the case of LiKZrO{sub 3}, one type has an indirect band gap of 3.79 eV between ? and M high symmetric points while another has a direct band gap of 3.12 eV. The phonon dispersions and phonon density of states of LiMZrO{sub 3} were calculated with the direct method. From the calculated thermodynamic properties of LiMZrO{sub 3} reacting with CO{sub 2}, our results showed that by doping Na into Li{sub 2}ZrO{sub 3}, the obtained new solid LiNaZrO{sub 3} has better performance as a CO{sub 2} sorbent applying to post-combustion capture technology. For K doping into Li{sub 2}ZrO{sub 3}, our calculated thermodynamic results showed that the new solid LiKZrO{sub 3} does not gain improvement on its CO{sub 2} capture performance because its regeneration temperature is much higher than Li{sub 2}ZrO{sub 3}.

Duan, Yuhua

2014-01-01T23:59:59.000Z

488

Google:[Leonid Zakharov] http://w3.pppl.gov/~zakharov LiWall Fusion and its 3 step R&D program  

E-Print Network [OSTI]

Google:[Leonid Zakharov] http://w3.pppl.gov/~zakharov LiWall Fusion and its 3 step R&D program Bibble of the 70s") LiWF NBI heating/fueling + Lithium Pumping PFC. No cold particles except He. vskip1em Issue LiWF Current BBBL-70s concept of "fusion" The target RDF (Reactor Dev.Facility, neutron

Zakharov, Leonid E.

489

Combined effect of chemical pressure and valence electron concentration through the electron-deficient Li substitution on the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system  

SciTech Connect (OSTI)

Four members of the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system have been prepared by high-temperature reaction method and characterized by X-ray diffractions. All compounds crystallize in the orthorhombic Gd{sub 5}Si{sub 4}-type structure (space group Pnma, Pearson code oP16) with bonding interactions for interslab Ge{sub 2} dimers. The Li substitution for rare-earth elements in the RE{sub 4}LiGe{sub 4} system leads to a combined effect of the increased chemical pressure and the decreased valance electron concentration (VEC), which eventually results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type with all broken interslab GeGe bond for the parental RE{sub 5}Ge{sub 4} to the Gd{sub 5}Si{sub 4}-type structure for the ternary RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. Site-preference between rare-earth metals and Li is proven to generate energetically the most favorable atomic arrangements according to coloring-problem, and the rationale is provided using both the size-factor and the electronic-factor related, respectively, to site-volume and electronegativity as well as QVAL values. Tight-binding, linear-muffin-tin-orbital (TB-LMTO) calculations are performed to investigate electronic densities of states (DOS) and crystal orbital Hamilton population (COHP) curves. The influence of reduced VEC for chemical bonding including the formation of interslab Ge{sub 2} dimers is also discussed. The magnetic property measurements prove that the non-magnetic Li substitution leads to the ferromagnetic (FM)-like ground state for Ce{sub 4}LiGe{sub 4} and the co-existence of antiferromagntic (AFM) and FM ground states for Sm{sub 4}LiGe{sub 4}. - Graphical abstract: Reported is a combined effect of the chemical pressure and the reduced VEC caused by the smaller monovalent non-magnetic Li substitution for the larger trivalent magnetic rare-earth metals in the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. This results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type to the Gd{sub 5}Si{sub 4}-type structure and the changes in magnetic properties. Display Omitted - Highlights: Four Li-containing intermetallic compounds RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr and Sm) were synthesized. The combined effect of the chemical pressure and the reduced VEC caused by Li substitution for a rare-earth metal results in the structure transformation. Electronic structures and magnetic properties of title compounds were thoroughly investigated.

Nam, Gnu; Jeon, Jieun; Kim, Youngjo [Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763 (Korea, Republic of); Kwon Kang, Sung [Department of Chemistry, Chungnam National University, Daejeon, Chungnam 305-764 (Korea, Republic of); Ahn, Kyunghan [Advanced Materials Research Center, Samsung Advanced Institute of Technology, Yongin-si, Gyeonggi-do 446-712 (Korea, Republic of); You, Tae-Soo, E-mail: tsyou@chungbuk.ac.kr [Department of Chemistry, Chungbuk National University, Cheongju, Chungbuk 361-763 (Korea, Republic of)

2013-09-15T23:59:59.000Z

490

Ab initio study of H, He, Li and Be impurity effect in tungsten ?3{112} and ?27{552} grain boundaries  

SciTech Connect (OSTI)

Density functional theory calculations were performed to study the effects of H, He, Li and Be on the cohesion of W ?3<110>{112} and ?27<110>{552} grain boundaries (GBs). In ?3, Li causes the strongest embrittlement, while in ?27 it is He. In both GBs, H slightly reduces the cohesion. Compared to He and Li, H exhibits much stronger attractive binding with W that may inhibit subsequent segregation of Li and He to the GBs. In ?3, Be decreases the cohesion. However, in ?27, Be strengthens the cohesion in several interstitial positions by increasing the bonding across the interface or by inducing GB restructuring.

Setyawan, Wahyu; Kurtz, Richard J.

2014-03-13T23:59:59.000Z

491

Study of particle unstable states in $9_{Be}$ by time-of-flight spectroscopy of Beta-delayed neutrons from $9_{Li}, pt.1  

E-Print Network [OSTI]

Study of particle unstable states in $9_{Be}$ by time-of-flight spectroscopy of Beta-delayed neutrons from $9_{Li}, pt.1

CERN. Geneva. Proton Synchrotron and Synchrocyclotron Committee

1983-01-01T23:59:59.000Z

492

Study of particle unstable states in $9_{Be}$ by time-of-flight spectroscopy of Beta-delayed neutrons from $9_{Li}, pt.2  

E-Print Network [OSTI]

Study of particle unstable states in $9_{Be}$ by time-of-flight spectroscopy of Beta-delayed neutrons from $9_{Li}, pt.2

CERN. Geneva. Proton Synchrotron and Synchrocyclotron Committee

1983-01-01T23:59:59.000Z

493

MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System  

E-Print Network [OSTI]

Introduction Lithium-ion batteries have played a centralas current commercial Li-ion batteries currently do not meetnext generation of batteries designed for transportation '

Cabana, Jordi

2010-01-01T23:59:59.000Z

494

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

for Rechargeable Lithium Batteries. J. Electrochem. Soc.Materials for Lithium Batteries. J. Electrochem. Soc. 148,LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

Doeff, Marca M

2010-01-01T23:59:59.000Z

495

Combustion Synthesis of Nanoparticulate LiMgxMn1-xPO4 (x=0, 0.1, 0.2) Carbon Composites  

E-Print Network [OSTI]

for Rechargeable Lithium Batteries. J. Electrochem. Soc.4 V Cathode Materials for Lithium Batteries. J. Electrochem.LiMnPO 4 for Lithium Ion Batteries. Electrochem. and Solid

Doeff, Marca M

2010-01-01T23:59:59.000Z

496

Spectroscopy of particle-phonon coupled states in 133Sb by the cluster transfer reaction of 132Sn on 7Li: an advanced test of nuclear interactions  

E-Print Network [OSTI]

Spectroscopy of particle-phonon coupled states in 133Sb by the cluster transfer reaction of 132Sn on 7Li: an advanced test of nuclear interactions

Leoni S, University of Milano and INFN Milano (Italy); Bocchi G, University of Milano and INFN Milano (Italy); Bottoni S, University of Milano and INFN Milano (Italy); Bracco A, University of Milano and INFN Milano (Italy); Camera F, University of Milano and INFN Milano (Italy; Crespi F, University of Milano and INFN Milano (Italy); Morales A, University of Milano and INFN Milano (Italy); Fornal B, IFJ-PAN Krakow (Poland); Szpak B, IFJ-PAN Krakow (Poland); Bednarczyk P, IFJ-PAN Krakow (Poland); Cieplicka N, IFJ-PAN Krakow (Poland); Krolas W, IFJ-PAN Krakow ( Poland); Maj A, IFJ-PAN Krakow (Poland); Rusek K, Heavy Ion Laboratory University of Warsaw (Poland); Bazzacco D, INFN Padova (Italy); Lunardi S, University of Padova and INFN Padova (Italy); Mengoni D, University of Padova and INFN Padova (Italy); Recchia F, University of Padova and INFN Padova (Italy); Ur C, INFN Padova (Italy); Valiente-Dobon J, LNL-INFN (Italy); Gramegna F, LNL-INFN (Italy); Marchi T, LNL-INFN (Italy); Huyse M, KU Leuven (Belgium); Raabe R, KU Leuven (Belgium); VanDuppen P, KU Leuven (Belgium); Sferrazza M, Universit libre de Bruxelles (Belgium); Georgiev G, CSNSM Orsay (France); Blazhev A, Institut fur Kernphysik der Universitat zu Kln (Germany); Rosiak D, Institut fur Kernphysik der Universitat zu Kln (Germany); Siebeck B, Institut fur Kernphysik der Universitat zu Kln (Germany); Seidlitz M, Institut fur Kernphysik der Universitat zu Kln (Germany); Reiter P, Institut fur Kernphysik der Universitat zu Kln (Germany); Warr N, Institut fur Kernphysik der Universitat zu Koln (Germany); Hartig AL, TU Darmstadt (Germany); Henrich C, TU Darmstadt (Germany); Ilieva S, TU Darmstadt (Germany); Kroell T, TU Darmstadt (Germany); Thurauf M, TU Darmstadt (Germany); Gernhaeuser R, TU Munchen (Germany); Mucher D, TU Munchen (Germany); Janssens R, Argonne National Laboratory (USA); Carpenter MP, Argonne National Laboratory (USA); Zhu S, Argonne National Laboratory (USA); Kowalska M, ISOLDE-CERN (Switzerland); CERN. Geneva. ISOLDE and neutron Time-of-Flight Experiments Committee; INTC

2014-01-01T23:59:59.000Z

497

An overview of dual coolant Pb-17Li breeder first wall and blanket concept development for the US ITER-TBM design  

SciTech Connect (OSTI)

An attractive blanket concept for the fusion reactor is the dual coolant Pb-17Li liquid (DCLL) breeder design. Reduced activation ferritic steel (RAFS) is used as the structural material. Helium is used to cool the first wall and blanket structure, and the self-cooled breeder Pb-17LI is circulated for power conversion and for tritium breeding. A SiCf/SiC composite insert is used as the magnetohydrodynamic (MHD) insulation to reduce the impact from the MHD pressure drop of the circulating Ph-17Li and as the thermal insulator to separate the high temperature Pb-17Li from the helium cooled RAFS structure.

Wong, Clement; Malang, S.; Sawan, M.; Dagher, Mohamad; Smolentsev, S.; Merrill, Brad; Youssef, M.; Reyes, Susanna; Sze, Dai Kai; Morley, Neil B.; Sharafat, Shahran; Calderoni, P.; Sviatoslavsky, G.; Kurtz, Richard J.; Fogarty, Paul J.; Zinkle, Steven J.; Abdou, Mohamed A.

2006-02-01T23:59:59.000Z

498

H+ diffusion and electrochemical stability of Li1+x+yAlxTi2-xSiyP3-yO12 glass in aqueous Li/air battery electrolytes  

SciTech Connect (OSTI)

It is well known that LATP (Li1+x+y AlxTi2?x SiyP3?yO12) glass is a good lithium ion conductor. However, the interaction between LATP glass and H+ ions (including its diffusion and surface adsorption) needs to be well understood before the long-term application of LATP glass in an aqueous electrolyte based Li-air batteries where H+ always present. In this work, we investigate the H+ ion diffusion properties in LATP glass and their surface interactions using both experimental and modeling approaches. Our analysis indicates that the apparent H+ related current observed in the initial cyclic voltammetry scan should be attributed to the adsorption of H+ ions on the LATP glass rather than the bulk diffusion of H+ ions in the glass. Furthermore, the density functional theory calculations indicate that the H+ ion diffusion energy barrier (3.21 eV) is much higher than that of Li+ ion (0.79 eV) and Na+ ion (0.79 eV) in NASICON type LiTi2(PO4)3 material. As a result, the H+ ion conductivity in LATP glass is negligible at room temperature. However, significant surface corrosion was found after the LATP glass was soaked in strong alkaline electrolyte for extended time. Therefore, appropriate electrolytes have to be developed to prevent the corrosion of LATP glass before its practical application for Li-air batteries using aqueous electrolyte.

Ding, Fei; Xu, Wu; Shao, Yuyan; Chen, Xilin; Wang, Zhiguo; Gao, Fei; Liu, Xingjiang; Zhang, Jiguang

2012-09-15T23:59:59.000Z

499

Preferential growth orientation of laser-patterned LiNbO{sub 3} crystals in lithium niobium silicate glass  

SciTech Connect (OSTI)

Dots and lines consisting of LiNbO{sub 3} crystals are patterned on the surface of 1CuO-40Li{sub 2}O-32Nb{sub 2}O{sub 5}-28SiO{sub 2} (mole ratio) glass by irradiations of continuous-wave Nd:YAG laser (wavelength: {lambda}=1064 nm), diode laser ({lambda}=795 nm), and Yb:YVO{sub 4} fiber laser ({lambda}=1080 nm), and the feature of laser-patterned LiNbO{sub 3} crystal growth is examined from linearly polarized micro-Raman scattering spectrum measurements. LiNbO{sub 3} crystals with the c-axis orientation are formed at the edge parts of the surface and cross-section of dots. The growth direction of an LiNbO{sub 3} along the laser scanning direction is the c-axis. It is proposed that the profile of the temperature distribution in the laser-irradiated region and its change along laser scanning would be one of the most important conditions for the patterning of crystals with a preferential growth orientation. Laser irradiation giving a narrow width is also proposed to be one of the important factors for the patterning of LiNbO{sub 3} crystal lines with homogeneous surface morphologies. -- Graphical abstract: Polarized optical microscope observations for the surface and cross-section of the dot obtained by LD laser ({lambda}=795 nm) irradiations of P=1.4 W and t=20 s in Cu-LNS glass. Schematic model for the orientation of LiNbO{sub 3} crystals at the edge parts of the surface and cross-section of the dot is also shown. Display Omitted Research highlights: > Dots and lines with LiNbO{sub 3} crystals are patterned on the glass surface by laser irradiations. > LiNbO{sub 3} crystals with the c-axis orientation are formed at the edge parts of the surface and cross-section of dots. > The profile of the temperature distribution in the laser-irradiated region is one of the most important conditions for the patterning of highly oriented crystals.

Komatsu, T., E-mail: komatsu@mst.nagaokaut.ac.j [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Koshiba, K.; Honma, T. [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2011-02-15T23:59:59.000Z

500

EXAFS and FT-IR Characterization of Mn and Li Promoted Titania-Supported Rh Catalysts for CO Hydrogenation  

SciTech Connect (OSTI)

The effect of Li and Mn promoters on the structure and selectivity of supported Rh catalysts for CO hydrogenation reaction was examined. Infrared spectroscopy and X-ray absorption were used to investigate the adsorption of reactants and local structure of Rh. These techniques were used in combination with reactivity, H{sub 2} chemisorption, and temperature programmed studies to correlate structural characteristics with activity and selectivity during CO hydrogenation of unpromoted Rh/TiO{sub 2} and three promoted Rh catalysts: Rh-Li/TiO{sub 2}, Rh-Mn/TiO{sub 2}, and Rh-Li-Mn/TiO{sub 2}. The presence of a promoter slightly decreases the Rh clusters size; however, no evidence for an electronic effect induced by the presence of Li and Mn was found. Higher turnover frequencies were found for the promoted catalysts, which also showed the lower dispersion. The Li promoter introduces a weakened CO adsorption site that appears to enhance the selectivity to C{sub 2+} oxygenates. The selectivity to C{sub 2+} oxygenates varies inversely with the reducibility of Rh metal, that is, the lower the Rh reducibility, the higher the selectivity.

V Schwartz; A Campos; A Egbebi; J Spivey; S Overbury

2011-12-31T23:59:59.000Z