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Sample records for groundwater surface water

  1. February 2016 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site April .........5 Water Sampling Field Activities Verification ...

  2. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2014

    SciTech Connect (OSTI)

    2013-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2014 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP during CY 2014 to achieve the following goals: 􀁸 to protect the worker, the public, and the environment; 􀁸 to maintain surveillance of existing and potential groundwater contamination sources; 􀁸 to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; 􀁸 to identify and characterize long-term trends in groundwater quality at Y-12; and 􀁸 to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12.

  3. August 2015 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2015 LMSTUB.........7 Water Sampling Field Activities Verification ...

  4. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2012

    SciTech Connect (OSTI)

    Elvado Environmental, LLC

    2011-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2012 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2012 is in accordance with the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge along the boundary of the Oak Ridge Reservation. Modifications to the CY 2012 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. Each modification to the monitoring program will be approved by the Y-12 GWPP manager and documented as an addendum to this sampling and analysis plan. The following sections of this report provide details regarding

  5. September 2015 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site February 2016 LMS/SHP/S00915 This page intentionally left blank U.S. Department of Energy DVP-September 2015, Shiprock, New Mexico February 2016 RINs 15097348 and 15097349 Page i Contents Sampling Event Summary ...............................................................................................................1 Planned Sampling Map Shiprock, New Mexico, Disposal Site

  6. January 2016 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Processing Site

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Processing Site March 2016 LMS/GJT/S00116 This page intentionally left blank U.S. Department of Energy DVP-January 2016, Grand Junction, Colorado March 2016 RIN 15127576 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Processing Site, Sample Location Map

  7. November 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites February 2016 LMS/RFN/RFO/S01115 This page intentionally left blank U.S. Department of Energy DVP-November 2015, Rifle, Colorado February 2016 RINs 15107463 and 15107464 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned Sampling Map

  8. River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zachara, John M.; Chen, Xingyuan; Murray, Chris; Hammond, Glenn

    2016-03-04

    A well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. As a result of water tablemore » elevation fluctuations, river water intrusion, and changes in groundwater flow directions, time series trends for Uaq and SpC were found to be complex and displayed large temporal and well-to-well variability. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in Uaq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized Uaq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. Moreover, while Uaq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

  9. River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zachara, John M.; Chen, Xingyuan; Murray, Chris; Hammond, Glenn

    2016-03-04

    In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time series trendsmore » for Uaq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in Uaq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized Uaq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While Uaq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

  10. May 2012 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2012-12-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 9-10, 2012, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the site boundaries have not been affected by project-related contaminants.

  11. May 2011 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2011-12-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 16-17, 2011, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed by the U.S. Environmental Protection Agency (EPA) Radiation&Indoor Environments National Laboratory in Las Vegas, Nevada. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry, and for tritium using the conventional method. Tritium was not measured using the enrichment method because the EPA laboratory no longer offers that service. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the boundaries have not been affected by project-related contaminants.

  12. May 2013 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2013-10-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 14-16, 2013, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location CER #1 Black Sulphur. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods.

  13. Overview of groundwater and surface water standards pertinent to the Idaho National Engineering Laboratory. Revision 3

    SciTech Connect (OSTI)

    Lundahl, A.L.; Williams, S.; Grizzle, B.J.

    1995-09-01

    This document presents an overview of groundwater- and surface water-related laws, regulations, agreements, guidance documents, Executive Orders, and DOE orders pertinent to the Idaho National Engineering Laboratory. This document is a summary and is intended to help readers understand which regulatory requirements may apply to their particular circumstances. However, the document is not intended to be used in lieu of applicable regulations. Unless otherwise noted, the information in this report reflects a summary and evaluation completed July 1, 1995. This document is considered a Living Document, and updates on changing laws and regulations will be provided.

  14. Ground-water in Texas

    SciTech Connect (OSTI)

    Ward-McLemore, E.

    1985-01-01

    Amount 61% of the water used by Texans is ground-water. Some areas, both municipal and rural, depend entirely on ground-water. In many areas long term withdrawal is lowering the water levels, causing surface land subsidence, salt-water encroachment, and reducing future reservoir availability. The increasing probability of seepage from radioactive and toxic wastes, herbicide residues, septic systems, and oilfield brines is threatening dangerous contamination of fresh ground-water reservoirs. The Texas Department of Water Resources, the Texas Department of Health, State and private colleges and universities, the US Geological Survey, the Environmental Protection Agency, various underground water districts, among others, are cooperating with concerned hydrologists in a concentrated program to increase the efficiency of ground-water use and development, preserve the aquifer reservoirs, and decrease the pollution potential. 88 references.

  15. June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites

    Office of Legacy Management (LM)

    June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites November 2015 LMS/RFL/S00615 This page intentionally left blank U.S. Department of Energy DVP-June and July 2015, Old and New Rifle, Colorado November 2015 RINs 15067100, 15067101, and 15077206 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned

  16. Ground-water flow and ground- and surface-water interaction at the Weldon Spring quarry, St. Charles County, Missouri

    SciTech Connect (OSTI)

    Imes, J.L.; Kleeschulte, M.J.

    1997-12-31

    Ground-water-level measurements to support remedial actions were made in 37 piezometers and 19 monitoring wells during a 19-month period to assess the potential for ground-water flow from an abandoned quarry to the nearby St. Charles County well field, which withdraws water from the base of the alluvial aquifer. From 1957 to 1966, low-level radioactive waste products from the Weldon Spring chemical plant were placed in the quarry a few hundred feet north of the Missouri River alluvial plain. Uranium-based contaminants subsequently were detected in alluvial ground water south of the quarry. During all but flood conditions, lateral ground-water flow in the bedrock from the quarry, as interpreted from water-table maps, generally is southwest toward Little Femme Osage Creek or south into the alluvial aquifer. After entering the alluvial aquifer, the ground water flows southeast to east toward a ground-water depression presumably produced by pumping at the St. Charles County well field. The depression position varies depending on the Missouri River stage and probably the number and location of active wells in the St. Charles County well field.

  17. A modeling study of irrigation effects on global surface water and groundwater resources under a changing climate

    SciTech Connect (OSTI)

    Leng, Guoyong; Huang, Maoyi; Tang, Qiuhong; Leung, Lai-Yung R.

    2015-08-25

    In this paper, the effects of irrigation on global surface water (SW) and groundwater (GW) resources are investigated by performing simulations using Community Land Model 4.0 (CLM4) at 0.5-degree resolution driven by downscaled/bias-corrected historical simulations and future projections from five General Circulation Models (GCMs) for 1950-2099. For each climate scenario, three sets of numerical experiments were configured: (1) a control experiment (CTRL) in which all crops are assumed to be rainfed; (2) an irrigation experiment (IRRIG) in which the irrigation module using only SW for irrigation is activated; and (3) a groundwater pumping experiment (PUMP) in which a groundwater pumping scheme coupled with the irrigation module is activated for conjunctive use of SW and GW for irrigation. The parameters associated with irrigation and groundwater pumping are calibrated based on a global inventory of census-based SW and GW use compiled by the Food and Agricultural Organization (FAO). Our results suggest that irrigation could lead to two major opposing effects: SW depletion/GW accumulation in regions with irrigation primarily fed by SW, and SW accumulation/GW depletion in regions with irrigation fed primarily by GW. Furthermore, irrigation depending primarily on SW tends to have larger impacts on low-flow than high-flow conditions, suggesting the potential to increase vulnerability to drought. By the end of the 21st century (2070-2099), climate change significantly increases (relative to 1971-2000) irrigation water demand across the world. Combined with the increased temporal-spatial variability of water supply, this may lead to severe issues of local water scarcity for irrigation. Regionally, irrigation has the potential to aggravate/alleviate climate-induced changes of SW/GW although such effects are negligible when averaged globally. Our results emphasize the importance of accounting for irrigation effects and irrigation sources in regional climate change impact

  18. A modeling study of irrigation effects on global surface water and groundwater resources under a changing climate

    SciTech Connect (OSTI)

    Leng, Guoyong; Huang, Maoyi; Tang, Qiuhong; Leung, Lai-Yung R.

    2015-08-25

    Abstract In this study, the effects of irrigation on global surface water (SW) and groundwater (GW) resources are investigated by performing simulations using Community Land Model 4.0 (CLM4) at 0.5-degree resolution driven by downscaled/bias-corrected historical simulations and future projections from five General Circulation Models (GCMs) for 1950-2099. For each climate scenario, three sets of numerical experiments were configured: (1) a control experiment (CTRL) in which all crops are assumed to be rainfed; (2) an irrigation experiment (IRRIG) in which the irrigation module using only SW for irrigation is activated; and (3) a groundwater pumping experiment (PUMP) in which a groundwater pumping scheme coupled with the irrigation module is activated for conjunctive use of SW and GW for irrigation. The parameters associated with irrigation and groundwater pumping are calibrated based on a global inventory of census-based SW and GW use compiled by the Food and Agricultural Organization (FAO). Our results suggest that irrigation could lead to two major opposing effects: SW depletion/GW accumulation in regions with irrigation primarily fed by SW, and SW accumulation/GW depletion in regions with irrigation fed primarily by GW. Furthermore, irrigation depending primarily on SW tends to have larger impacts on low-flow than high-flow conditions, suggesting the potential to increase vulnerability to drought. By the end of the 21st century (2070-2099), climate change significantly increases (relative to 1971-2000) irrigation water demand across the world. Combined with the increased temporal-spatial variability of water supply, this may lead to severe issues of local water scarcity for irrigation. Regionally, irrigation has the potential to aggravate/alleviate climate-induced changes of SW/GW although such effects are negligible when averaged globally. Our results emphasize the importance of accounting for irrigation effects and irrigation sources in regional climate change

  19. A modeling study of irrigation effects on global surface water and groundwater resources under a changing climate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Guoyong; Huang, Maoyi; Tang, Qiuhong; Leung, Lai-Yung R.

    2015-08-25

    In this paper, the effects of irrigation on global surface water (SW) and groundwater (GW) resources are investigated by performing simulations using Community Land Model 4.0 (CLM4) at 0.5-degree resolution driven by downscaled/bias-corrected historical simulations and future projections from five General Circulation Models (GCMs) for 1950-2099. For each climate scenario, three sets of numerical experiments were configured: (1) a control experiment (CTRL) in which all crops are assumed to be rainfed; (2) an irrigation experiment (IRRIG) in which the irrigation module using only SW for irrigation is activated; and (3) a groundwater pumping experiment (PUMP) in which a groundwater pumpingmore » scheme coupled with the irrigation module is activated for conjunctive use of SW and GW for irrigation. The parameters associated with irrigation and groundwater pumping are calibrated based on a global inventory of census-based SW and GW use compiled by the Food and Agricultural Organization (FAO). Our results suggest that irrigation could lead to two major opposing effects: SW depletion/GW accumulation in regions with irrigation primarily fed by SW, and SW accumulation/GW depletion in regions with irrigation fed primarily by GW. Furthermore, irrigation depending primarily on SW tends to have larger impacts on low-flow than high-flow conditions, suggesting the potential to increase vulnerability to drought. By the end of the 21st century (2070-2099), climate change significantly increases (relative to 1971-2000) irrigation water demand across the world. Combined with the increased temporal-spatial variability of water supply, this may lead to severe issues of local water scarcity for irrigation. Regionally, irrigation has the potential to aggravate/alleviate climate-induced changes of SW/GW although such effects are negligible when averaged globally. Our results emphasize the importance of accounting for irrigation effects and irrigation sources in regional climate change

  20. July 2015 Groundwater and Surface Water Sampling at the Naturita, Colorado, Processing Site

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Naturita, Colorado, Processing Site October 2015 LMS/NAP/S00715 This page intentionally left blank U.S. Department of Energy DVP-July 2015, Naturita, Colorado October 2015 RIN 15077222 Page i Contents Sampling Event Summary ...............................................................................................................1 Data Assessment Summary

  1. Surface Water Transport for the F/H Area Seepage Basins Groundwater Program

    SciTech Connect (OSTI)

    Chen, Kuo-Fu

    1995-08-29

    The contribution of the F- and H-Area Seepage Basins (FHSBs) tritium releases to the tritium concentration in the Savannah River are presented in this report. WASP5 was used to simulate surface water transport for tritium releases from the FHSBs. The WASP5 model was qualified with the 1993 tritium measurements at US Highway 301. The tritium concentrations in Fourmile Branch and the Savannah River were calculated for tritium releases from FHSBs. The calculated tritium concentrations above normal environmental background in the Savannah River, resulting from FHSBs releases, drop from 1.25 pCi/ml (<10% of EPA Drinking Water Guide) in 1995 to 0.0056 pCi/ml in 2045.

  2. Characterization of Surface Water/Groundwater Exchange Regulating Uranium Transport Using Electrical Imaging and Distributed Temperature Sensing Methods

    SciTech Connect (OSTI)

    Lee D. Slater; Dimitrios Ntarlagiannis; Fred Day-Lewis; Kisa Mwakanyamale; Roelof J Versteeg; Andy Ward; Christopher Strickland; Carole D. Johnson; John Lane

    2010-10-01

    A critical challenge in advancing prediction of solute transport between contaminated aquifers and rivers is improving understanding of how fluctuations in river stage, combined with subsurface heterogeneity, impart spatiotemporal complexity to solute exchange along river corridors. Here, we explored the use of continuous waterborne electrical imaging (CWEI), in conjunction with fiber-optic distributed temperature sensor (FO-DTS) monitoring, to improve the conceptual model for uranium transport within the river corridor at the Hanford 300 Area. We first inverted CWEI (resistivity and induced polarization) datasets for distributions of electrical resistivity and polarizability, from which the spatial complexity of the primary hydrogeologic units was reconstructed. Variations in the depth to the interface between the overlying coarse-grained, high permeability Hanford formation and the underlying finer grained, less permeable Ringold formation, an important contact that limits vertical migration of contaminants, were resolved along ~3 km of the river corridor centered on the 300 Area. Polarizability images were translated into lithologic images using established relationships between polarizability and surface area normalized to pore volume (Spor). Spatial variability in the thickness of the Hanford formation captured in the CWEI datasets indicates that previous studies based on borehole projections and drive-point and multi-level sampling overestimate the contributing area for uranium exchange within the Columbia River at the Hanford 300 Area. The FO- DTS data recorded along a 1.5 km of cable with a 1-m spatial resolution and 5-minute sampling interval revealed sub-reaches showing (1) temperature anomalies (relatively warm in winter and cool in summer) and, (2) a strong correlation between temperature and river stage (negative in winter and positive in summer), both indicative of reaches of enhanced surface water/groundwater exchange. The FO-DTS datasets confirm the

  3. Surface and groundwater management in surface mined-land reclamation

    SciTech Connect (OSTI)

    Evoy, B.; Holland, M.

    1990-06-01

    This report provides information on surface water and groundwater management for use in the mined-land reclamation planning process in California. Mined-land reclamation, as defined by the California Surface Mining and Reclamation Act, is the combination of land treatments which prevent or minimize water degradation, air pollution, damage to aquatic or wildlife habitat, and erosion resulting from a surface mining operation. Surface water and groundwater management play an integral role in nearly every reclamation plan. Groundwater and surface water runoff (both onto and off of the site) must often be evaluated (1) to design flooding and erosion protection measures such as drainage channels, levees, culverts, or riprap; (2) to prepare and carry out a successful revegetation program; (3) to design stable final slopes; (4) to maximize potential available water for the operation and reclamation stages; (5) to prevent the discharge of contaminants from mine processes or from mined areas; and (6) to limit long-term leachate formation and movement from tailings, pit, or waste rock disposal areas. This report is a guide for mine operators, local government, planners, and plan reviewers.

  4. Procedures for ground-water investigations

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  5. Conjunctive Surface and Groundwater Management in Utah. Implications...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah. Implications for Oil Shale and Oil Sands Development Citation Details In-Document Search Title: Conjunctive Surface and ...

  6. Source Water and Groundwater Withdrawal Permit Application Process...

    Open Energy Info (EERE)

    Permit Application Process Guidance Citation Vermont Department of Environmental Conservation. 2015. Source Water and Groundwater Withdrawal Permit Application Process...

  7. Procedures for ground-water investigations

    SciTech Connect (OSTI)

    Not Available

    1989-09-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water investigations are carried out to fulfill the requirements for the US Department of Energy (DOE) to meet the requirements of DOE Orders. Investigations are also performed for various clients to meet the requirements of the Resource Conservation and Recovery Act of 1976 (RCRA) and the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA). National standards including procedures published by the American Society for Testing and Materials (ASTM) and the US Geological Survey were utilized in developing the procedures contained in this manual.

  8. http://www.lvvwd.com/about/wr_groundwater.html

    National Nuclear Security Administration (NNSA)

    Water Resources Groundwater About 10 percent of the Las Vegas Valley's water comes from groundwater, which is a water supply under the Earth's surface. In some areas, water...

  9. Vermont Drinking Water and Groundwater Protection Division Permit...

    Open Energy Info (EERE)

    2015 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Vermont Drinking Water and Groundwater Protection Division Permit Fees...

  10. Hanford Site ground-water monitoring for 1994

    SciTech Connect (OSTI)

    Dresel, P.E.; Thorne, P.D.; Luttrell, S.P.

    1995-08-01

    This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1994 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiologic and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1994 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1993 and June 1994. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal.

  11. RCRA ground-water monitoring: Draft technical guidance

    SciTech Connect (OSTI)

    Not Available

    1992-11-01

    The manual was prepared to provide guidance for implementing the ground-water monitoring regulations for regulated units contained in 40 CFR Part 264 Subpart F and the permitting standards of 40 CFR Part 270. The manual also provides guidance to owners and operators of treatment, storage, and disposal facilities (TSDFs) that are required to comply with the requirements of 40 CFR Part 264 Subparts J (Tank Systems), K (Surface Impoundments), L (Waste Piles), N (Landfills), and X (Miscellaneous Units). This document updates technical information contained in other sources of U.S. EPA guidance, such as chapter eleven of SW-846 (Revision O, September 1986) and the Technical Enforcement Guidance Document (TEGD).

  12. Procedures for ground-water investigations. Revision 1

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  13. Ground-water data for 1990--91 and ground-water withdrawals for 1951--91, Nevada Test Site and vicinity, Nye County, Nevada

    SciTech Connect (OSTI)

    Wood, D.B.; Reiner, S.R.

    1996-12-31

    This report presents selected ground-water data collected from wells and test holes at and in the vicinity of the Nevada Test Site. Depth-to-water measurements were made at 74 sites at and in the vicinity of the Nevada Test Site during water years 1990--91. Measured depths to water ranged from 301 to 2,215 feet below land surface and measured altitudes of the ground-water surface at the Nevada Test Site ranged from 2,091 to 6,083 feet above sea level. Depth-to-water measurements were obtained by a combination of wire-line, electric-tape, iron-horse, and steel-tape methods. Available historic withdrawal and depth-to-water data for ground-water supply wells have been included to show changes through time. Water samples were collected and analyzed for tritium concentrations at 15 sites during water years 1990--91. Tritium concentrations in bailed water samples ranged from below detection limits to 5,550,000 picocuries per liter. Tritium concentrations in samples from three wells exceeded drinking water standards established by the US Environmental Protection Agency. All three wells are separate piezometers contained within a single test hole near an area of extensive underground nuclear testing.

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data ...

  15. Use of Electrical Imaging and Distributed Temperature Sensing Methods to Characterize Surface Water-Groundwater Exchange Regulating Uranium Transport at the Hanford 300 Area, Washington

    SciTech Connect (OSTI)

    Slater, Lee; Ntarlagiannis, Dimitrios; Day-Lewis, Frederick D.; Mwakanyamale, Kisa; Versteeg, Roelof J.; Ward, Anderson L.; Strickland, Christopher E.; Johnson, Carole D.; Lane, John W.

    2010-10-31

    A critical challenge in advancing prediction of solute transport between contaminated aquifers and rivers is improving understanding of how fluctuations in river stage, combined with subsurface heterogeneity, impart spatiotemporal complexity to solute exchange along river corridors. Here, we explored the use of waterborne geoelectrical imaging, in conjunction with fiber-optic distributed temperature sensor (DTS) monitoring, to improve the conceptual model for uranium transport within the hyporheic corridor at the Hanford 300 Area. We first inverted waterborne geoelectrical (resistivity and induced polarization) datasets for distributions of electrical resistivity and polarizability, from which the spatial complexity of the primary hydrogeologic units was reconstructed. Variations in the depth to the interface between the overlying coarse-grained, high permeability Hanford formation and the underlying finer-grained, less permeable Ringold formation, an important contact that limits vertical migration of contaminants, were resolved along ~3 km of the river corridor centered on the 300 Area. Polarizability images were translated into lithologic images using established relationships between polarizability and surface area normalized to pore volume (Spor). The spatial variability captured in the geoelectrical datasets indicates that previous studies based on borehole projections and point probing overestimate the contributing area for uranium exchange within the Columbia River at the Hanford 300 Area. The DTS data recorded on 1. 5 km of cable with a 1 m spatial resolution and 5 minute sampling interval revealed sub-reaches showing (1) high temperature anomalies and, (2) a strong negative correlation between temperature and river stage, both indicative of groundwater influxes during winter months. The DTS datasets confirm the hydrologic significance of the variability identified in the geoelectrical imaging and reveal a pattern of highly focused hyporheic exchange, with

  16. Hanford Site ground-water monitoring for 1993

    SciTech Connect (OSTI)

    Dresel, P.E.; Luttrell, S.P.; Evans, J.C.

    1994-09-01

    This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1993 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1993 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1992 and June 1993. The greatest declines occurred in the 200-West Area. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal. Water levels remained nearly constant in the vicinity of B Pond, as a result of continued disposal to the pond. Water levels measured from wells in the unconfined aquifer north and east of the Columbia River indicate that the primary source of recharge is irrigation practices.

  17. Selection of clc, cba, and fcb chlorobenzoate-catabolic genotypes from groundwater and surface waters adjacent to the Hyde Park, Niagara Falls, chemical landfill

    SciTech Connect (OSTI)

    Peel, M.C.; Wyndham, R.C.

    1999-04-01

    The frequency of isolation of three nonhomologous chlorobenzoate catabolic genotypes (clc, cba, and fbc) was determined for 464 isolates from freshwater sediments and groundwater in the vicinity of the Hyde Park industrial landfill site in the Niagara watershed. Samples were collected from both contaminated and noncontaminated sites during spring, summer, and fall and enriched at 4, 22, or 32 C with micromolar to millimolar concentrations of chlorobenzoates and 3-chlorobiphenyl. Hybridization at moderate stringency to restriction-digested genomic DNA with DNA probes revealed the chlorocatechol 1,2-dioxygenase operon (clcABD), the 3-chlorobenzoate 3,4-(4,5)-dioxygenase operon (cbaABC), and the 4-chlorobenzoate dehalogenase (fcbB) gene in isolates enriched from all contaminated sites in the vicinity of the industrial landfill. Nevertheless, the known genes were found in less than 10% of the isolates from the contaminated sites, indicating a high level of genetic diversity in the microbial community. The known genotypes were not enriched from the noncontaminated control sites nearby. The clc, cba, and fcb isolates were distributed across five phenotypically distinct groups based on Biolog carbon source utilization, with the breadth of the host range decreasing in the order clc > cba > fcb. Restriction fragment length polymorphism (RFLP) patterns showed that the cba genes were conserved in all isolates whereas the clc and fcb genes exhibited variation in RFLP patterns.

  18. A Guide for Using the Transient Ground-Water Flow Model of the Death Valley Regional Ground-Water Flow System, Nevada and California

    SciTech Connect (OSTI)

    Joan B. Blainey; Claudia C. Faunt, and Mary C. Hill

    2006-05-16

    This report is a guide for executing numerical simulations with the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California using the U.S. Geological Survey modular finite-difference ground-water flow model, MODFLOW-2000. Model inputs, including observations of hydraulic head, discharge, and boundary flows, are summarized. Modification of the DVRFS transient ground-water model is discussed for two common uses of the Death Valley regional ground-water flow system model: predictive pumping scenarios that extend beyond the end of the model simulation period (1998), and model simulations with only steady-state conditions.

  19. Conjunctive management of surface and groundwater resources under projected future climate change scenarios

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mani, Amir; Tsai, Frank T. -C.; Kao, Shih-Chieh; Naz, Bibi S.; Ashfaq, Moetasim; Rastogi, Deeksha

    2016-06-16

    Our study introduces a mixed integer linear fractional programming (MILFP) method to optimize conjunctive use of future surface water and groundwater resources under projected climate change scenarios. The conjunctive management model maximizes the ratio of groundwater usage to reservoir water usage. Future inflows to the reservoirs were estimated from the future runoffs projected through hydroclimate modeling considering the Variable Infiltration Capacity model, and 11 sets of downscaled Coupled Model Intercomparison Project phase 5 global climate model projections. Bayesian model averaging was adopted to quantify uncertainty in future runoff projections and reservoir inflow projections due to uncertain future climate projections. Optimizedmore » conjunctive management solutions were investigated for a water supply network in northern Louisiana which includes the Sparta aquifer. Runoff projections under climate change scenarios indicate that runoff will likely decrease in winter and increase in other seasons. Ultimately, results from the developed conjunctive management model with MILFP indicate that the future reservoir water, even at 2.5% low inflow cumulative probability level, could counterbalance groundwater pumping reduction to satisfy demands while improving the Sparta aquifer through conditional groundwater head constraint.« less

  20. GWVis: A Tool for Comparative Ground-Water Data Visualization

    SciTech Connect (OSTI)

    Best, Daniel M.; Lewis, Robert R.

    2010-11-01

    The Ground-Water Visualization application (GWVis) presents ground-water data visually in order to educate the public on ground-water issues. It is also intended for presentations to government and other funding agencies. Current three dimensional models of ground-water are overly complex, while the two dimensional representations (i.e., on paper) are neither comprehensive, nor engaging. At present, GWVis operates on water head elevation data over a given time span, together with a matching (fixed) underlying geography. Two elevation scenarios are compared with each other, typically a control data set (actual field data) and a simulation. Scenario comparison can be animated for the time span provided. We developed GWVis using the Python programming language, associated libraries, and pyOpenGL extension packages to improve performance and control of attributes of the mode (such as color, positioning, scale, and interpolation). GWVis bridges the gap between two dimensional and dynamic three dimensional research visualizations by providing an intuitive, interactive design that allows participants to view the model from different perspectives and to infer information about scenarios. By incorporating scientific data in an environment that can be easily understood, GWVis allows the information to be presented to a large audience base.

  1. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........9 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Static Water Level Data ...

  2. Ground-Water Table and Chemical Changes in an Alluvial Aquifer...

    Office of Environmental Management (EM)

    Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical ...

  3. Selected ground-water data for Yucca Mountain Region, Southern Nevada and Eastern California, through December 1997

    SciTech Connect (OSTI)

    La Camera, Richard J.; Locke, Glenn L.; Munson, Rodney H.

    1999-07-30

    Data on ground-water levels, discharges, and withdrawals from a variety of ground-water sources in the study area are reported for calendar year 1997.

  4. Effect of faulting on ground-water movement in the Death Valley region, Nevada and California

    SciTech Connect (OSTI)

    Faunt, C.C.

    1997-12-31

    This study characterizes the hydrogeologic system of the Death Valley region, an area covering approximately 100,000 square kilometers. The study also characterizes the effects of faults on ground-water movement in the Death Valley region by synthesizing crustal stress, fracture mechanics,a nd structural geologic data. The geologic conditions are typical of the Basin and Range Province; a variety of sedimentary and igneous intrusive and extrusive rocks have been subjected to both compressional and extensional deformation. Faulting and associated fracturing is pervasive and greatly affects ground-water flow patterns. Faults may become preferred conduits or barriers to flow depending on whether they are in relative tension, compression, or shear and other factors such as the degree of dislocations of geologic units caused by faulting, the rock types involved, the fault zone materials, and the depth below the surface. The current crustal stress field was combined with fault orientations to predict potential effects of faults on the regional ground-water flow regime. Numerous examples of fault-controlled ground-water flow exist within the study area. Hydrologic data provided an independent method for checking some of the assumptions concerning preferential flow paths. 97 refs., 20 figs., 5 tabs.

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Groundwater and Surface Water Sampling at the Slick Rock, Colorado, Processing Sites .........7 Water Sampling Field Activities Verification ...

  6. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and May 2014 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal .........9 Water Sampling Field Activities Verification ...

  7. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........3 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Natural Gas Analysis Data ...

  8. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Rulison, Colorado, Site October 2015 LMS.........5 Water Sampling Field Activities Verification ...

  9. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Time-Concentration Graph ...

  10. September 2004 Water Sampling

    Office of Legacy Management (LM)

    2015 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site .........9 Water Sampling Field Activities Verification ...

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    3 Groundwater and Surface Water Sampling at the Monument Valley, Arizona, Processing Site .........7 Water Sampling Field Activities Verification ...

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    July 2015 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing .........5 Water Sampling Field Activities Verification ...

  13. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site .........5 Water Sampling Field Activities Verification ...

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Monticello, Utah, Processing Site January .........7 Water Sampling Field Activities Verification ...

  15. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........3 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Time-Concentration Graphs ...

  16. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........7 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data Static ...

  17. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data Static ...

  18. WAC - 173-200 Water Quality Standards for Groundwaters of the...

    Open Energy Info (EERE)

    These rules establish ground water quality standards to protect the environment and human health and protection of existing and future beneficial uses of groundwaters in...

  19. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface ...

  20. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

  1. Guidelines for the Protection of Surface and Groundwater Resources...

    Open Energy Info (EERE)

    and Groundwater Resources During Exploration Drilling Author Government of Western Australia Organization Department of Mines and Petroleum Published NA, 2002 DOI Not Provided...

  2. Update to the Ground-Water Withdrawals Database for the Death Valley REgional Ground-Water Flow System, Nevada and California, 1913-2003

    SciTech Connect (OSTI)

    Michael T. Moreo; and Leigh Justet

    2008-07-02

    Ground-water withdrawal estimates from 1913 through 2003 for the Death Valley regional ground-water flow system are compiled in an electronic database to support a regional, three-dimensional, transient ground-water flow model. This database updates a previously published database that compiled estimates of ground-water withdrawals for 1913–1998. The same methodology is used to construct each database. Primary differences between the 2 databases are an additional 5 years of ground-water withdrawal data, well locations in the updated database are restricted to Death Valley regional ground-water flow system model boundary, and application rates are from 0 to 1.5 feet per year lower than original estimates. The lower application rates result from revised estimates of crop consumptive use, which are based on updated estimates of potential evapotranspiration. In 2003, about 55,700 acre-feet of ground water was pumped in the DVRFS, of which 69 percent was used for irrigation, 13 percent for domestic, and 18 percent for public supply, commercial, and mining activities.

  3. Appendix D Surface Water and Ground Water Time-Concentration...

    Office of Legacy Management (LM)

    Surface Water and Ground Water Time-Concentration Plots, Stream Discharge Measurements, Ground Water Level Data, and Ground Water Well Hydrographs This page intentionally left ...

  4. Code System for Performance Assessment Ground-water Analysis for Low-level Nuclear Waste.

    Energy Science and Technology Software Center (OSTI)

    1994-02-09

    Version 00 The PAGAN code system is a part of the performance assessment methodology developed for use by the U. S. Nuclear Regulatory Commission in evaluating license applications for low-level waste disposal facilities. In this methodology, PAGAN is used as one candidate approach for analysis of the ground-water pathway. PAGAN, Version 1.1 has the capability to model the source term, vadose-zone transport, and aquifer transport of radionuclides from a waste disposal unit. It combines themore » two codes SURFACE and DISPERSE which are used as semi-analytical solutions to the convective-dispersion equation. This system uses menu driven input/out for implementing a simple ground-water transport analysis and incorporates statistical uncertainty functions for handling data uncertainties. The output from PAGAN includes a time- and location-dependent radionuclide concentration at a well in the aquifer, or a time- and location-dependent radionuclide flux into a surface-water body.« less

  5. Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

    SciTech Connect (OSTI)

    Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; Johnson, Jeffrey N.

    2015-04-18

    Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on two general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.

  6. Drought resilience of the California Central Valley surface-groundwater-conveyance system

    SciTech Connect (OSTI)

    Miller, N.L.; Dale, L.L.; Brush, C.; Vicuna, S.; Kadir, T.N.; Dogrul, E.C.; Chung, F.I.

    2009-05-15

    A series of drought simulations were performed for the California Central Valley using computer applications developed by the California Department of Water Resources and historical datasets representing a range of droughts from mild to severe for time periods lasting up to 60 years. Land use, agricultural cropping patterns, and water demand were held fixed at the 2003 level and water supply was decreased by amounts ranging between 25 and 50%, representing light to severe drought types. Impacts were examined for four hydrologic subbasins, the Sacramento Basin, the San Joaquin Basin, the Tulare Basin, and the Eastside Drainage. Results suggest the greatest impacts are in the San Joaquin and Tulare Basins, regions that are heavily irrigated and are presently overdrafted in most years. Regional surface water diversions decrease by as much as 70%. Stream-to-aquifer flows and aquifer storage declines were proportional to drought severity. Most significant was the decline in ground water head for the severe drought cases, where results suggest that under these scenarios the water table is unlikely to recover within the 30-year model-simulated future. However, the overall response to such droughts is not as severe as anticipated and the Sacramento Basin may act as ground-water insurance to sustain California during extended dry periods.

  7. Ground-water solutes and eolian processes: An example from the High Plains of Texas

    SciTech Connect (OSTI)

    Wood, W.W.; Sanford, W.E. (Geological Survey, Reston, VA (United States))

    1992-01-01

    Eolian dunes associated with saline-lake basins are important geologic features in arid and semiarid areas. The authors propose that eolian processes may also be important in controlling solute concentration and composition of ground water in these environments. A study of Double Lakes on the Southern High Plains of Texas suggests that approximately 200 megagrams of chloride enters this topographically closed basin from the surrounding water table aquifer, direct precipitation and surface runoff. Solute-transport simulation suggest that approximately 70 of the 200 megagrams of the chloride annually leaves the basin by diffusion and ground-water advection through a 30 meter-thick shale underlying the lake. The remaining 130 megagrams is hypothesized to be removed by eolian processes. Closed water-table contours around the lake and a hydrologic analysis suggest that it is improbable that solutes will reach the surrounding water-table aquifer by ground-water transport from this lake system. The conceptual eolian-transport model is further supported by observed chloride profiles in the unsaturated zone. When analyzed with estimates of recharge fluxes, these profiles suggest that approximately 150 megagrams of chloride enter the unsaturated zone downwind of the lake annually. Thus two independent methods suggest that 130 to 150 megagrams of chloride enter the unsaturated zone downwind of the lake annually. Thus two independent methods suggest that 130 to 150 megagrams of chloride are removed from the basin annually by eolian process and redeposited downwind of the lake. Eolian input to the ground water is consistent with the observed plume shape as well as with the solute and isotopic composition of ground water in the water-table aquifer downwind of the lake basin.

  8. Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; Johnson, Jeffrey N.

    2015-04-18

    Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on twomore » general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.« less

  9. Hanford Site ground-water monitoring for July through December 1987

    SciTech Connect (OSTI)

    Evans, J.C.; Dennison, D.I.; Bryce, R.W.; Mitchell, P.J.; Sherwood, D.R.; Krupka, K.M.; Hinman, N.W.; Jacobson, E.A.; Freshley, M.D.

    1988-12-01

    The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between July and December 1987 included monitoring ground-water elevations across the Site, monitoring hazardous chemicals and radionuclides in ground water, geochemical evaluations of unconfined ground-water data, and calibration of ground-water flow and transport models. Water levels continued to rise in areas receiving increased recharge (e.g., beneath B Pond) and decline in areas where the release of water to disposal facilities has been terminated (e.g., U Pond). The major areas of ground-water contamination defined by monitoring activities are (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and 200-West Areas; (3) hexavalent chromium contamination in the 100-B, 100-D, 100-F, 100-H, 100-K, and 200-West Areas; (4) chlorinated hydrocarbons in the vicinity of the Central Landfill and 300 Area; (5) uranium in the 100-F, 100-H, 200-West, and 300 Areas; and (6) tritium and nitrate across the Site. The MINTEQ geochemical code was used to identify chemical reactions that may be affecting the concentrations of dissolved hazardous chemicals in the unconfined ground water. Results indicate that many cations are present mainly as dissolved carbonate complexes and that a majority of the ground-water samples are in near equilibrium with carbonate minerals (e.g., calcite, dolomite, otavite).

  10. EA-1155: Ground-water Compliance Activities at the Uranium Mill Tailings Site, Spook, Wyoming

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to comply with the Environmental Protection Agency's ground-water standards set forth in 40 CFR 192 at the Spook, Wyoming Uranium Mill...

  11. Ground-water monitoring compliance plan for the Hanford Site Solid Waste Landfill

    SciTech Connect (OSTI)

    Fruland, R.M.

    1986-10-01

    Washington state regulations required that solid waste landfill facilities have ground-water monitoring programs in place by May 27, 1987. This document describes the well locations, installation, characterization studies and sampling and analysis plan to be followed in implementing the ground-water monitoring program at the Hanford Site Solid Waste Landfill (SWL). It is based on Washington Administrative Code WAC 173-304-490. 11 refs., 19 figs., 4 tabs.

  12. Evaluation of the US Geological Survey ground-water data-collection program in Hawaii, 1992. Water-resources investigations

    SciTech Connect (OSTI)

    Anthony, S.S.

    1997-12-31

    This report describes an evaluation of the 1992 USGS ground-water data-collection program in Hawaii. The occurrence of ground water in the Hawaiian islands is briefly described. Objectives for the data-collection program are identified followed by a description of well networks needed to prepare maps of water levels and chloride concentrations. For the islands of Oahu, Kauai, Maui, Molokai, and Hawaii, the wells in the 1992 ground-water data-collection program are described followed by maps showing the distribution and magnitude of pumpage, and the distribution of proposed pumped wells. Wells in the 1992 USGS ground-water data-collection program that provide useful data for mapping water levels and chloride concentrations are identified followed by locations where additional wells are needed for water-level and chloride-concentration data. In addition, a procedure to store and review data is described.

  13. Characterization of Flow Paths, Residence Time and Media Chemistry in Complex Landscapes to Integrate Surface, Groundwater and Stream Processes and Inform Models of Hydrologic and Water Quality Response to Land Use Activities; Savannah River Site

    SciTech Connect (OSTI)

    Bitew, Menberu; Jackson, Rhett

    2015-02-01

    The objective of this report is to document the methodology used to calculate the three hydro-geomorphic indices: C Index, Nhot spot, and Interflow Contributing Area (IFC Area). These indices were applied in the Upper Four Mile Creek Watershed in order to better understand the potential mechanisms controlling retention time, path lengths, and potential for nutrient and solute metabolism and exchange associated with the geomorphic configurations of the upland contributing areas, groundwater, the riparian zone, and stream channels.

  14. Field-deployable, nano-sensing approach for real-time detection of free mercury, speciation and quantification in surface stream waters and groundwater samples at the U.S. Department of Energy contaminated sites

    SciTech Connect (OSTI)

    Campiglia, Andres D.; Hernandez, Florencio E.

    2014-08-28

    The detrimental effects on human health caused by long-term exposure to trace contamination of toxic metals have been documented in numerous epidemiological and toxicological studies. The fact that metals are non-biodegradable and accumulate in the food chain poses a severe threat to the environment and human health. Their monitoring in drinking water, aquatic ecosystems, food and biological fluids samples is then essential for global sustainability. While research efforts employing established methodology continue to advance conceptual/computational models of contaminant behavior, the increasing awareness and public concern with environmental and occupational exposure to toxic metals calls for sensing devices capable to handle on-site elemental analysis in short analysis time. Field analysis with potable methodology prevents unnecessary scrutiny of un-contaminated samples via laboratory-bound methods, reduces analysis cost and expedites turnaround time for decision making and remediation purposes. Of particular toxicological interest are mercury and its species. Mercury is recognized as a major environmental pollution issue. The field-portable sensor developed in this project provides a unique and valuable tool for the on-site, real-time determination of inorganic mercury in surface waters. The ability to perform on-site analysis of mercury should prove useful in remote locations with difficult accessibility. It should facilitate data collection from statistically meaningful population sizes for a better understanding of the dose-effect role and the water-soil-plant-animal-human transfer mechanisms. The acquired knowledge should benefit the development of efficient environmental remediation processes, which is extremely relevant for a globally sustainable environment.

  15. Conjunctive Surface and Groundwater Management in Utah. Implications...

    Office of Scientific and Technical Information (OSTI)

    Unconventional fuel development will require scarce water resources. In an environment characterized by scarcity, and where most water resources are fully allocated, prospective ...

  16. Hydrogeologic controls on ground-water and contaminant discharge to the Columbia River near the Hanford Townsite

    SciTech Connect (OSTI)

    Luttrell, S.P.; Newcomer, D.R.; Teel, S.S.; Vermeul, V.R.

    1992-11-01

    The purpose of this study is to quantify ground-water and contaminant discharge to the Columbia River in the Hanford Townsite vicinity. The primary objectives of the work are to: describe the hydrogeologic setting and controls on ground-water movement and contaminant discharge to the Columbia River; understand the river/aquifer relationship and its effects on contaminant discharge to the Columbia River; quantify the ground-water and contaminant mass discharge to the Columbia River; and provide data that may be useful for a three-dimensional model of ground-water flow and contaminant transport in the Hanford Townsite study area. The majority of ground-water contamination occurs within the unconfined aquifer; therefore, ground-water and contaminant discharge from the unconfined aquifer is the emphasis of this study. The period of study is primarily from June 1990 through March 1992.

  17. Shallow ground-water flow, water levels, and quality of water, 1980-84, Cowles Unit, Indiana Dunes National Lakeshore

    SciTech Connect (OSTI)

    Cohen, D.A.; Shedlock, R.J.

    1986-01-01

    The Cowles Unit of Indiana Dunes National Lakeshore in Porter County, northwest Indiana, contains a broad dune-beach complex along the southern shoreline of Lake Michigan and a large wetland, called the Great Marsh, that occupies the lowland between the shoreline dunes and an older dune-beach complex farther inland. Water levels and water quality in the surficial aquifer were monitored from 1977 to 1984 near settling ponds on adjacent industrial property at the western end of the Cowles Unit. Since 1980, when the settling pond bottoms were sealed, these intradunal lowlands contained standing water only during periods of high snowmelt or rainfall. Water level declines following the cessation of seepage ranged from 6 feet at the eastern-most settling pond to nearly 14 feet at the western-most pond. No general pattern of water table decline was observed in the Great Marsh or in the shoreline dune complex at distances > 3,000 ft east or north of the settling ponds. Since the settling ponds were sealed, the concentration of boron has decreased while concentrations of cadmium, arsenic, zinc, and molybdenum in shallow ground-water downgradient of the ponds show no definite trends in time. Arsenic, boron and molybdenum have remained at concentrations above those of shallow groundwater in areas unaffected by settling pond seepage. 11 refs., 10 figs., 1 tab.

  18. Groundwater Monitoring

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Monitoring Groundwater Monitoring LANL maintains an extensive groundwater monitoring and surveillance program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at Los Alamos National Laboratory RELATED IMAGES http://farm4.staticflickr.com/3749/9827580556_473a91fd78_t.jpg Enlarge

  19. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect (OSTI)

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  20. 40 CFR 265 interim-status ground-water monitoring plan for the 2101-M pond

    SciTech Connect (OSTI)

    Chamness, M.A.; Luttrell, S.P.; Dudziak, S.

    1989-03-01

    This report outlines a ground-water monitoring plan for the 2101-M pond, located in the southwestern part of the 200-East Area on the Hanford Site in south-central Washington State. It has been determined that hazardous materials may have been discharged to the pond. Installation of an interim-status ground-water monitoring system is required under the Resource Conservation and Recovery Act to determine if hazardous chemicals are moving out of the pond. This plan describes the location of new wells for the monitoring system, how the wells are to be completed, the data to be collected, and how those data can be used to determine the source and extent of any ground-water contamination from the 2101-M pond. Four new wells are planned, one upgradient and three downgradient. 35 refs., 12 figs., 9 tabs.

  1. Potential effects of the Hawaii geothermal project on ground-water resources on the Island of Hawaii

    SciTech Connect (OSTI)

    Sorey, M.L.; Colvard, E.M.

    1994-07-01

    This report provides data and information on the quantity and quality of ground-water resources in and adjacent to proposed geothermal development areas on the Island of Hawaii Geothermal project for the development of as much as 500 MW of electric power from the geothermal system in the East Rift Zone of Kilauea Volcano. Data presented for about 31 wells and 8 springs describe the chemical, thermal, and hydraulic properties of the ground-water system in and adjacent to the East Rift Zone. On the basis of this information, potential effects of this geothermal development on drawdown of ground-water levels and contamination of ground-water resources are discussed. Significant differences in ground-water levels and in the salinity and temperature of ground water within the study area appear to be related to mixing of waters from different sources and varying degrees of ground-water impoundment by volcanic dikes. Near Pahoa and to the east, the ground-water system within the rift is highly transmissive and receives abundant recharge from precipitation; therefore, the relatively modest requirements for fresh water to support geothermal development in that part of the east rift zone would result in minimal effects on ground-water levels in and adjacent to the rift. To the southwest of Pahoa, dike impoundment reduces the transmissivity of the ground-water system to such an extent that wells might not be capable of supplying fresh water at rates sufficient to support geothermal operations. Water would have to be transported to such developments from supply systems located outside the rift or farther downrift. Contaminant migration resulting from well accidents could be rapid because of relatively high ground-water velocities in parts of the region. Hydrologic monitoring of observation wells needs to be continued throughout development of geothermal resources for the Hawaii Geothermal Project to enable the early detection of leakage and migration of geothermal fluids.

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater, Surface Water, and Alternate Water Supply System Sampling at the Riverton, Wyoming, Processing Site December 2013 LMSRVTS00913 This page intentionally left blank ...

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Tuba City, Arizona Disposal Site June 2015 .........7 Water Sampling Field Activities Verification ...

  4. Ground-water chemistry of a fen-wetland complex in northeastern Illinois

    SciTech Connect (OSTI)

    Panno, S.V.; Hensel, B.R.; Cartwright, K.; Krapac, I.G. ); Nuzzo, V. )

    1992-01-01

    Construction of homes within the watershed of a fen-wetland complex has resulted in encroachment of ground water-borne anthropogenic contaminants into 3 high-quality fens. The study area is located in northeastern Illinois and is situated at the base of a Wisconsinan moraine. The upper 15 to 45 m of glacial drift consists of permeable sand and gravel, overlain by 3 to 6 m of peat and marl. Ground-water samples were collected quarterly for 1.25 years from sand and gravel aquifers, and peat and marl of the fens, and analyzed for inorganic constituents. Density, cover and vigor data on threatened, endangered and selected common plant species in the fens were collected in conjunction with ground-water sampling. Ground water of the complex is of the Ca-HCO[sub 3] to Ca-Mg-HCO[sub 3] type which is typical of ground water of glacial deposits of North America. Contaminant plumes at this site are enriched in Ca, Mg, Na, Cl, NO[sub 3], SO[sub 4], with higher specific conductance and alkalinity. Some recharge areas within the complex yield ground-water samples containing 200--500 mg/L SO[sub 4]. Although this ground water is entering the fens, ground water from peat and marl in the fens contains an order of magnitude lower concentration of SO[sub 4] due to reducing conditions therein. Progressive enrichment of Cl and NO[sub 3], and decrease in Eh is occurring in recharge areas nearest housing developments, suggesting progressive degradation of ground-water quality. Mineral content of ground water appears to have the most significant affect on plant diversity within the fens. A specific conductance of greater than 100 [mu]s/cm in shallow fen ground water correlates well with the encroachment and proliferation of Typha angustifolia L. (narrow-leaf cattail) into areas of highly diverse flora.

  5. Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Details Activities (3) Areas (2) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Field...

  6. Near-surface groundwater responses to injection of geothermal wastes

    SciTech Connect (OSTI)

    Arnold, S.C.

    1984-06-01

    Experiences with injecting geothermal fluids have identified technical problems associated with geothermal waste disposal. This report assesses the feasibility of injection as an alternative for geothermal wastewater disposal and analyzes hydrologic controls governing the upward migration of injected fluids. Injection experiences at several geothermal developments are presented, including: Raft River, Salton Sea, East Mesa, Otake and Hatchobaru in Japan, and Ahuachapan in El Salvador. Hydrogeologic and design/operational factors affecting the success of an injection program are identified. Hydrogeologic factors include subsidence, near-surface effects of injected fluids, and seismicity. Design/operational factors include hydrodynamic breakthrough, condition of the injection system and reservoir maintenance. Existing and potential effects of production/injection on these factors are assessed.

  7. Drinking Water and Groundwater Protection Division File Transfer...

    Open Energy Info (EERE)

    File Transfer Protocol (FTP) Site Instructions Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Instructions: Drinking Water and...

  8. Hanford Site ground-water monitoring for January through June 1988

    SciTech Connect (OSTI)

    Evans, J.C.; Bryce, R.W.; Sherwood, D.R.

    1989-05-01

    The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between January and June 1988 included monitoring ground-water elevations across the Site, and monitoring hazardous chemicals and radionuclides in ground water. Water levels continued to rise in areas receiving increased recharge (e.g., beneath B Pond) and decline in areas where the release of water to disposal facilities has been terminated (e.g., U Pond). The major areas of ground-water contamination defined by monitoring activities are (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and 200-West Areas; (3) hexavalent chromium contamination in the 100-B, 100-D, 100-F, 100-H, 100-K, and 200-West Areas; (4) chlorinated hydrocarbons in the vicinity of the Solid Waste Landfill and 300 Area; (5) uranium in the 100-F, 100-H, 200-West, and 300 Areas; and (6) tritium and nitrate across the Site. In addition, several new analytical initiatives were undertaken during this period. These include cyanide speciation in the BY Cribs plume, inductively coupled argon plasma/mass spectrometry (ICP/MS) measurements on a broad selection of samples from the 100, 200, 300, and 600 Areas, and high sensitivity gas chromatography measurements performed at the Solid Waste Landfill-Nonradioactive Dangerous Waste Landfill. 23 figs., 25 tabs.

  9. Interim site characterization report and ground-water monitoring program for the Hanford site solid waste landfill

    SciTech Connect (OSTI)

    Fruland, R.M.; Hagan, R.A.; Cline, C.S.; Bates, D.J.; Evans, J.C.; Aaberg, R.L.

    1989-07-01

    Federal and state regulations governing the operation of landfills require utilization of ground-water monitoring systems to determine whether or not landfill operations impact ground water at the point of compliance (ground water beneath the perimeter of the facility). A detection-level ground-water monitoring system was designed, installed, and initiated at the Hanford Site Solid Waste Landfill (SWL). Chlorinated hydrocarbons were detected at the beginning of the ground-water monitoring program and continue to be detected more than 1 year later. The most probable source of the chlorinated hydrocarbons is washwater discharged to the SWL between 1985 and 1987. This is an interim report and includes data from the characterization work that was performed during well installation in 1987, such as field observations, sediment studies, and geophysical logging results, and data from analyses of ground-water samples collected in 1987 and 1988, such as field parameter measurements and chemical analyses. 38 refs., 27 figs., 8 tabs.

  10. Finding Balance Between Biological Groundwater Treatment and Treated Injection Water

    SciTech Connect (OSTI)

    Carlson, Mark A.; Nielsen, Kellin R.; Byrnes, Mark E.; Simmons, Sally A.; Morse, John J.; Geiger, James B.; Watkins, Louis E.; McFee, Phillip M.; Martins, K.

    2015-01-14

    At the U.S. Department of Energy’s Hanford Site, CH2M HILL Plateau Remediation Company operates the 200 West Pump and Treat which was engineered to treat radiological and chemical contaminants in groundwater as a result of the site’s former plutonium production years. Fluidized bed bioreactors (FBRs) are used to remove nitrate, metals, and volatile organic compounds. Increasing nitrate concentrations in the treatment plant effluent and the presence of a slimy biomass (a typical microorganism response to stress) in the FBRs triggered an investigation of nutrient levels in the system. Little, if any, micronutrient feed was coming into the bioreactors. Additionally, carbon substrate (used to promote biological growth) was passing through to the injection wells, causing biological fouling of the wells and reduced specific injectivity. Adjustments to the micronutrient feed improved microorganism health, but the micronutrients were being overfed (particularly manganese) plugging the injection wells further. Injection well rehabilitation to restore specific injectivity required repeated treatments to remove the biological fouling and precipitated metal oxides. A combination of sulfamic and citric acids worked well to dissolve metal oxides and sodium hypochlorite effectively removed the biological growth. Intensive surging and development techniques successfully removed clogging material from the injection wells. Ultimately, the investigation and nutrient adjustments took months to restore proper balance to the microbial system and over a year to stabilize injection well capacities. Carefully tracking and managing the FBRs and well performance monitoring are critical to balancing the needs of the treatment system while reducing fouling mechanisms in the injection wells.

  11. June 2015 Groundwater and Surface Water Sampling at the Green...

    Office of Legacy Management (LM)

    ... DVP-June 2015, Green River, Utah U.S. Department of Energy RIN 15067102 August 2015 Page 12 Inductively Coupled Plasma Interference Check Sample Analysis Interference check samples ...

  12. Ground-water monitoring at the Hanford Site, January-December 1984

    SciTech Connect (OSTI)

    Cline, C.S.; Rieger, J.T.; Raymond, J.R.

    1985-09-01

    This program is designed to evaluate existing and potential pathways of exposure to radioactivity and hazardous chemicals from site operations. This document contains an evaluation of data collected during CY 1984. During 1984, 339 monitoring wells were sampled at various times for radioactive and nonradioactive constituents. Two of these constituents, specifically, tritium and nitrate, have been selected for detailed discussion in this report. Tritium and nitrate in the primary plumes originating from the 200 Areas continue to move generally eastward toward the Columbia River in the direction of ground-water flow. The movement within these plumes is indicated by changes in trends within the analytical data from the monitoring wells. No discernible impact on ground water has yet been observed from the start-up of the PUREX plant in December 1983. The shape of the present tritium plume is similar to those described in previous ground-water monitoring reports, although slight changes on the outer edges have been noted. Radiological impacts from two potential pathways for radionuclide transport in ground water to the environment are discussed in this report. The pathways are: (1) human consumption of ground water from onsite wells, and (2) seepage of ground water into the Columbia River. Concentrations of tritium in spring samples that were collected and analyzed in 1983, and in wells sampled adjacent to the Columbia River in 1984 confirmed that constituents in the ground water are entering the river via springs and subsurface flow. The primary areas where radionuclides enter the Columbia River via ground-water flow are the 100-N and 300 Areas and the shoreline adjacent to the Hanford Townsite. 44 refs., 25 figs., 11 tabs.

  13. Revised ground-water monitoring compliance plan for the 300 area process trenches

    SciTech Connect (OSTI)

    Schalla, R.; Aaberg, R.L.; Bates, D.J.; Carlile, J.V.M.; Freshley, M.D.; Liikala, T.L.; Mitchell, P.J.; Olsen, K.B.; Rieger, J.T.

    1988-09-01

    This document contains ground-water monitoring plans for process-water disposal trenches located on the Hanford Site. These trenches, designated the 300 Area Process Trenches, have been used since 1973 for disposal of water that contains small quantities of both chemicals and radionuclides. The ground-water monitoring plans contained herein represent revision and expansion of an effort initiated in June 1985. At that time, a facility-specific monitoring program was implemented at the 300 Area Process Trenches as part of a regulatory compliance effort for hazardous chemicals being conducted on the Hanford Site. This monitoring program was based on the ground-water monitoring requirements for interim-status facilities, which are those facilities that do not yet have final permits, but are authorized to continue interim operations while engaged in the permitting process. The applicable monitoring requirements are described in the Resource Conservation and Recovery Act (RCRA), 40 CFR 265.90 of the federal regulations, and in WAC 173-303-400 of Washington State's regulations (Washington State Department of Ecology 1986). The program implemented for the process trenches was designed to be an alternate program, which is required instead of the standard detection program when a facility is known or suspected to have contaminated the ground water in the uppermost aquifer. The plans for the program, contained in a document prepared by the US Department of Energy (USDOE) in 1985, called for monthly sampling of 14 of the 37 existing monitoring wells at the 300 Area plus the installation and sampling of 2 new wells. 27 refs., 25 figs., 15 tabs.

  14. Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions...

    Office of Science (SC) Website

    Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as ... Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as ...

  15. Category:Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Surface Water Sampling page? For detailed information on...

  16. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Citation Details In-Document Search Title: Ecological Screening Values for Surface Water, Sediment, and Soil ...

  17. Improved Design Tools for Surface Water and Standing Column Well...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems This project ...

  18. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Friday, G. P. 54 ENVIRONMENTAL SCIENCES; SOILS; SURFACE WATERS; SEDIMENTS; ECOLOGICAL CONCENTRATION; ENVIRONMENTAL...

  19. air_water.cdr

    Office of Legacy Management (LM)

    122011 Air Monitoring Groundwater Monitoring Surface Water Monitoring A continuously operating air monitoring network was in place from 1986 through 2000 for the Weldon Spring ...

  20. Selected Ground-Water Data for Yucca Mountain Region, Southern Nevada and Eastern California, January 2000-December 2002

    SciTech Connect (OSTI)

    Locke, Glenn L. [US Geological Survey, Carson City, NV (United States); La Camera, Richard J. [US Geological Survey, Carson City, NV (United States)

    2003-12-31

    The U.S. Geological Survey, in support of the U.S. Department of Energy, Yucca Mountain Project, collects, compiles, and summarizes hydrologic data in the Yucca Mountain region. The data are collected to allow assessments of ground-water resources during activities to determine the potential suitability or development of Yucca Mountain for storing high-level nuclear waste. Data on ground-water levels at 35 wells and a fissure (Devils Hole), ground-water discharge at 5 springs and a flowing well, and total reported ground-water withdrawals within Crater Flat, Jackass Flats, Mercury Valley, and the Amargosa Desert are tabulated from January 2000 through December 2002. Historical data on water levels, discharges, and withdrawals are graphically presented to indicate variations through time. A statistical summary of ground-water levels at seven wells in Jackass Flats is presented for 19922002 to indicate potential effects of ground-water withdrawals associated with U.S. Department of Energy activities near Yucca Mountain. The statistical summary includes the annual number of measurements, maximum, minimum, and median water-level altitudes, and average deviation of measured water-level altitudes compared to selected baseline periods. Baseline periods varied for 198593. At six of the seven wells in Jackass Flats, the median water levels for 2002 were slightly higher (0.32.4 feet) than for their respective baseline periods. At the remaining well, data for 2002 was not summarized statistically but median water-level altitude in 2001 was 0.7 foot higher than that in its baseline period.

  1. Groundwater contamination from stormwater infiltration

    SciTech Connect (OSTI)

    Pitt, R.; Clark, S.; Parmer, K.

    1995-10-01

    The research summarized here was conducted during the first year of a 3-yr cooperative agreement (CR819573) to identify and control stormwater toxicants, especially those adversely affecting groundwater. The purpose of this research effort was to review the groundwater contamination literature as it relates to stormwater. Prior to urbanization groundwater is recharged by rainfall-runoff and snowmelt infiltrating through pervious surfaces including grasslands and woods. This infiltrating water is relatively uncontaminated. Urbanization, however, reduces the permeable soil surface area through which recharge by infiltration occurs. This results in much less groundwater recharge and greatly increased surface runoff. In addition the waters available for recharge carry increased quantities of pollutants. With urbanization, waters having elevated contaminant concentrations also recharge groundwater including effluent from domestic septic tanks, wastewater from percolation basins and industrial waste injection wells, infiltrating stormwater, and infiltrating water from agricultural irrigation. The areas of main concern that are covered by this paper are: the source of the pollutants, stormwater constituents having a high potential to contaminate groundwater, and the treatment necessary for stormwater.

  2. Results of a ground-water and DNAPL recovery and containment strategy

    SciTech Connect (OSTI)

    Mazierski, P.F.; Connor, J.M. )

    1993-10-01

    Ground-water contamination and dense nonaqueous phase liquids (DNAPL) were discovered at the DuPont Necco Park Landfill in Niagara Falls, New York, shortly after the facility was closed in the late 1970s. The facility received a variety of solid and liquid process wastes, including chlorinated volatile and semivolatile organic compounds. A number of proactive response activities--including the operation of a ground-water recovery system, installation of a grout curtain, and DNAPL recovery--were implemented by DuPont concurrent with site characterization. These efforts minimized off-site contaminant migration and removed most of the recoverable free-phase DNAPL prior to completion of the full site characterization. Site investigations to characterize hydrogeologic controls over occurrence and migration of ground water and DNAPL revealed with distinct water-bearing zones beneath the site. A DNAPL recovery program, using gas-driven pump assemblies, was initiated in early 1989 at a small group of wells where DNAPL was frequently observed. The volume of recovered DNAPL declined over the next four years from a peak of 397 gallons per month in 1989 to little or no recovery in recent months.

  3. Technical Basis for Evaluating Surface Barriers to Protect Groundwater from Deep Vadose Zone Contamination

    SciTech Connect (OSTI)

    Fayer, Michael J.; Ward, Anderson L.; Freedman, Vicky L.

    2010-02-03

    This document presents a strategy for evaluating the effectiveness of surface barriers for site-specific deep vadose zone remediation. The strategy provides a technically defensible approach to determine the depth to which a surface barrier can effectively isolate contaminants in the vadose at a specific site as a function of subsurface properties, contaminant distribution, barrier design, and infiltration control performance. The strategy also provides an assessment of additional data and information needs with respect to surface barrier performance for deep vadose zone applications. The strategy addresses the linkage between surface barriers and deep vadose zone in situ remediation activities, monitoring issues, and emerging science, technology, and regulatory objectives. In short, the report documents the existing knowledge base, identifies knowledge needs (based on data gaps), and suggests tasks whose outcomes will address those knowledge needs. More important, the report serves as a starting point to engage the regulator and stakeholder community on the viability of deploying surface barriers for deep vadose zone contamination. As that engagement unfolds, a systematic methodology can be formalized and instituted. The strategy is focused on deep vadose zone contamination and the methods needed to determine the impact to groundwater from those deep vadose zone contaminants. Processes that affect surface barrier performance, recharge in the areas surrounding the surface barrier, and the near-surface vadose zone beneath the barrier are acknowledged but are not addressed by this strategy. In addition, the collection of site-specific data on contaminant distribution and geologic structure and properties are programmatic responsibilities and are not provided by this strategy.

  4. Hanford Site ground-water monitoring for April through June 1987

    SciTech Connect (OSTI)

    Evans, J.C.; Mitchell, P.J.; Dennison, D.I.

    1988-01-01

    Pacific Northwest Laboratory (PNL) is conducting ground-water monitoring at the Hanford Site. Results for monitoring by PNL and Westinghouse Hanford Company (WHC) during April-June 1987 show that certain regulated hazardous materials and radionuclides exist in Hanford Site ground waters. The presence of regulated constituents in the ground water derives both from site operations and from natural sources. The major contamination problems defined by recent monitoring activities are carbon tetrachloride in the 200 West Area; cyanide in and north of the 200 East Area; hexavalent chromium contamination in the 100B, 100D, 100K, and 100H areas; chlorinated hydrocarbons in the vicinity of the Central Landfill; uranium at the 216-U-1 and 216-U-2 cribs in the 200 West Area; tritium across the site; and nitrate across the site. The distribution of hazardous materials related to site operations is more limited than the distribution of tritium and nitrate. 8 refs., 22 figs., 5 tabs.

  5. Hydrogeologic evaluation and numerical simulation of the Death Valley regional ground-water flow system, Nevada and California

    SciTech Connect (OSTI)

    D`Agnese, F.A.; Faunt, C.C.; Turner, A.K.; Hill, M.C.

    1997-12-31

    Yucca Mountain is being studied as a potential site for a high-level radioactive waste repository. In cooperation with the U.S. Department of Energy, the U.S. Geological Survey is evaluating the geologic and hydrologic characteristics of the ground-water system. The study area covers approximately 100,000 square kilometers between lat 35{degrees}N., long 115{degrees}W and lat 38{degrees}N., long 118{degrees}W and encompasses the Death Valley regional ground-water flow system. Hydrology in the region is a result of both the and climatic conditions and the complex described as dominated by interbasinal flow and may be conceptualized as having two main components: a series of relatively shallow and localized flow paths that are superimposed on deeper regional flow paths. A significant component of the regional ground-water flow is through a thick Paleozoic carbonate rock sequence. Throughout the regional flow system, ground-water flow is probably controlled by extensive and prevalent structural features that result from regional faulting and fracturing. Hydrogeologic investigations over a large and hydrogeologically complex area impose severe demands on data management. This study utilized geographic information systems and geoscientific information systems to develop, store, manipulate, and analyze regional hydrogeologic data sets describing various components of the ground-water flow system.

  6. Ground-water surveillance at the Hanford Site for CY 1983

    SciTech Connect (OSTI)

    Prater, L.S.; Rieger, J.T.; Cline, C.S.; Jensen, E.J.; Liikala, T.L.; Oster, K.R.

    1984-07-01

    Operations at the Hanford Site have resulted in the discharge of large volumes of process cooling water and other waste waters to the ground. These effluents contain low level of radioactive and chemical substances. During 1983, 328 monitoring wells were sampled at various times for radioactive and chemical constituents. Three of these constituents, specifically tritium, nitrate, and gross beta activity, were selected for detailed discussion in this report because they are more readily transported in the ground water than some of the other constituents. Transport of these constituents in the ground water has resulted in the formation of plumes that can be mapped by contouring the analytical data obtained from the monitoring wells. This report describes recent changes in the configuration of the tritium, nitrate and gross beta plumes. Changes or trends in contaminant levels in wells located within both the main plumes (originating from the 200 Areas) and the smaller plumes are discussed in this report. Two potential pathways for radionuclide transport from the ground water to the environmental are discussed in this report, and the radiological impacts are examined. In addition to describing the present status of the ground water beneath the Hanford Site, this report contains the results of studies conducted in support of the ground-water surveillance effort during CY 1983. 21 references, 26 figures, 5 tables.

  7. Groundwater Database

    Broader source: Energy.gov [DOE]

    DOE has one of the largest ground water contamination problems and subsequent cleanup responsibilities for a single entity in the world, in terms of the sheer volume of affected groundwater, number...

  8. TECHNICAL BASIS FOR EVALUATING SURFACE BARRIERS TO PROTECT GROUNDWATER FROM DEEP VADOSE ZONE CONTAMINATION

    SciTech Connect (OSTI)

    FAYER JM; FREEDMAN VL; WARD AL; CHRONISTER GB

    2010-02-24

    tasks to achieve those outcomes. Full understanding of contaminant behavior in the deep vadose zone is constrained by four key data gaps: limited access; limited data; limited time; and the lack of an accepted predictive capability for determining whether surface barriers can effectively isolate deep vadose zone contaminants. Activities designed to fill these data gaps need to have these outcomes: (1) common evaluation methodology that provides a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination; (2) deep vadose zone data that characterize the lithology, the spatial distribution of moisture and contaminants, the physical, chemical, and biological process that affect the mobility of each contaminant, and the impacts to the contaminants following placement of a surface barrier; (3) subsurface monitoring to provide subsurface characterization of initial conditions and changes that occur during and following remediation activities; and (4) field observations that span years to decades to validate the evaluation methodology. A set of six proposed tasks was identified to provide information needed to address the above outcomes. The proposed tasks are: (1) Evaluation Methodology - Develop common evaluation methodology that will provide a clear, consistent, and defensible basis for evaluating groundwater impacts caused by placement of a surface barrier above deep vadose zone contamination. (2) Case Studies - Conduct case studies to demonstrate the applicability ofthe common evaluation methodology and provide templates for subsequent use elsewhere. Three sites expected to have conditions that would yield valuable information and experience pertinent to deep vadose zone contamination were chosen to cover a range of conditions. The sites are BC Cribs and Trenches, U Plant Cribs, and the T Farm Interim Cover. (3) Subsurface Monitoring Technologies - Evaluate minimally invasive

  9. Reactive chemical transport in ground-water hydrology: Challenges to mathematical modeling

    SciTech Connect (OSTI)

    Narasimhan, T.N.; Apps, J.A.

    1990-07-01

    For a long time, earth scientists have qualitatively recognized that mineral assemblages in soils and rocks conform to established principles of chemistry. In the early 1960's geochemists began systematizing this knowledge by developing quantitative thermodynamic models based on equilibrium considerations. These models have since been coupled with advective-dispersive-diffusive transport models, already developed by ground-water hydrologists. Spurred by a need for handling difficult environmental issues related to ground-water contamination, these models are being improved, refined and applied to realistic problems of interest. There is little doubt that these models will play an important role in solving important problems of engineering as well as science over the coming years. Even as these models are being used practically, there is scope for their improvement and many challenges lie ahead. In addition to improving the conceptual basis of the governing equations, much remains to be done to incorporate kinetic processes and biological mediation into extant chemical equilibrium models. Much also remains to be learned about the limits to which model predictability can be reasonably taken. The purpose of this paper is to broadly assess the current status of knowledge in modeling reactive chemical transport and to identify the challenges that lie ahead.

  10. 40 CFR 265 interim status indicator-evaluation ground-water monitoring plan for the 216-B-63 trench

    SciTech Connect (OSTI)

    Bjornstad, B.N.; Dudziak, S.

    1989-03-01

    This document outlines a ground-water monitoring plan for the 216-B-63 trench located in the northeast corner of the 200-East Area on the Hanford Site in southeastern Washington State. It has been determined that hazardous materials (corrosives) were disposed of to the trench during past operations. Installation of an interim-status ground-water monitoring system is required to determine whether hazardous chemicals are leaching to the ground water from beneath the trench. This document summarizes the existing data that are available from near the 216-B-63 trench and presents a plan to determine the extent of ground-water contamination, if any, derived from the trench. The plan calls for the installation of four new monitoring wells located near the west end of the trench. These wells will be used to monitor ground-water levels and water quality immediately adjacent to the trench. Two existing RCRA monitoring wells, which are located near the trench and hydraulically upgradient of it, will be used as background wells. 46 refs., 15 figs., 12 tabs.

  11. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an ... August 1, 2013 Conceptual model of water movement and geology at Los Alamos National ...

  12. Protection of the Groundwater Resource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection of the Groundwater Resource Protection of the Groundwater Resource Monitoring wells act as sentinels between suspected LANL contamination and the water supply. August 1,...

  13. December 2015 Groundwater and Surface Waater Sampling at the Grand Junction, Colorado, Site

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Grand Junction, Colorado, Site March 2016 LMS/GJO/S01215 This page intentionally left blank U.S. Department of Energy DVP-December 2015, Grand Junction, Colorado March 2016 RIN 15117528 Page i Contents Sampling Event Summary ...............................................................................................................1 Data Assessment Summary

  14. Water Quality Surface and Ground | Open Energy Information

    Open Energy Info (EERE)

    Water Quality Surface and Ground Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWaterQualitySurfaceandGround&oldid612197" Feedback...

  15. Removing High Explosives from Groundwater

    Broader source: Energy.gov [DOE]

    LOS ALAMOS, N.M. – In an initiative supported by EM, Los Alamos National Laboratory’s Corrective Actions Program is addressing high explosive contamination in surface water and groundwater at a location this summer in the forests surrounding the laboratory.

  16. Hoe Creek groundwater restoration, 1989

    SciTech Connect (OSTI)

    Renk, R.R.; Crader, S.E.; Lindblom, S.R.; Covell, J.R.

    1990-01-01

    During the summer of 1989, approximately 6.5 million gallons of contaminated groundwater were pumped from 23 wells at the Hoe Creek underground coal gasification site, near Gillette, Wyoming. The organic contaminants were removed using activated carbon before the water was sprayed on 15.4 acres at the sites. Approximately 2647 g (5.8 lb) of phenols and 10,714 g (23.6 lb) of benzene were removed from the site aquifers. Phenols, benzene, toluene, ethylbenzene, and naphthalene concentrations were measured in 43 wells. Benzene is the only contaminant at the site exceeds the federal standard for drinking water (5 {mu}g/L). Benzene leaches into the groundwater and is slow to biologically degrade; therefore, the benzene concentration has remained high in the groundwater at the site. The pumping operation affected groundwater elevations across the entire 80-acre site. The water levels rebounded quickly when the pumping operation was stopped on October 1, 1989. Removing contaminated groundwater by pumping is not an effective way to clean up the site because the continuous release of benzene from coal tars is slow. Benzene will continue to leach of the tars for a long time unless its source is removed or the leaching rate retarded through mitigation techniques. The application of the treated groundwater to the surface stimulated plant growth. No adverse effects were noted or recorded from some 60 soil samples taken from twenty locations in the spray field area. 20 refs., 52 figs., 8 tabs.

  17. An Update of the Analytical Groundwater Modeling to Assess Water Resource Impacts at the Afton Solar Energy Zone

    SciTech Connect (OSTI)

    Quinn, John J.; Greer, Christopher B.; Carr, Adrianne E.

    2014-10-01

    The purpose of this study is to update a one-dimensional analytical groundwater flow model to examine the influence of potential groundwater withdrawal in support of utility-scale solar energy development at the Afton Solar Energy Zone (SEZ) as a part of the Bureau of Land Management’s (BLM’s) Solar Energy Program. This report describes the modeling for assessing the drawdown associated with SEZ groundwater pumping rates for a 20-year duration considering three categories of water demand (high, medium, and low) based on technology-specific considerations. The 2012 modeling effort published in the Final Programmatic Environmental Impact Statement for Solar Energy Development in Six Southwestern States (Solar PEIS; BLM and DOE 2012) has been refined based on additional information described below in an expanded hydrogeologic discussion.

  18. Particulate, colloidal, and solution phase associations of plutonium, americium, and uranium in surface and groundwater at the Rocky Flats Plant, Colorado

    SciTech Connect (OSTI)

    Harnish, R.A.; McKnight, D.M.; Ranville, J.F.; Stephens, V.C.; Honeyman, B.D.

    1993-12-31

    With the cessation of plutonium processing at the D.O.E.-administered Rocky Flats Plant near Denver, CO, the focus of activities at the facility has switched to contaminant assessment and potential remediation strategies. In this context the authors began a study in 1991 to determine the potential for colloid-facilitated transport of the actinides Pu, Am, and in surface- and groundwater at this site. Using the technique of tangential flow ultrafiltration, the authors isolated particles from four size fractions at one groundwater well and two surface water seeps to determine the distribution of Pu, Am, and U among particulate, colloidal, and dissolved aqueous phases. Analysis of particle isolates and filtrate fractions showed significant associations of Am and Pu with colloidal and particulate size particles; uranium isotopes were associated mainly with low molecular weight organic species. The results indicate a potential for colloidal-facilitated transport of the actinides Pu and Am and a significant contribution by low molecular weight natural organic matter to uranium transport.

  19. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    SciTech Connect (OSTI)

    Birkholzer, Jens; Apps, John; Zheng, Liange; Zhang, Yingqi; Xu, Tianfu; Tsang, Chin-Fu

    2008-10-01

    One promising approach to reduce greenhouse gas emissions is injecting CO{sub 2} into suitable geologic formations, typically depleted oil/gas reservoirs or saline formations at depth larger than 800 m. Proper site selection and management of CO{sub 2} storage projects will ensure that the risks to human health and the environment are low. However, a risk remains that CO{sub 2} could migrate from a deep storage formation, e.g. via local high-permeability pathways such as permeable faults or degraded wells, and arrive in shallow groundwater resources. The ingress of CO{sub 2} is by itself not typically a concern to the water quality of an underground source of drinking water (USDW), but it will change the geochemical conditions in the aquifer and will cause secondary effects mainly induced by changes in pH, in particular the mobilization of hazardous inorganic constituents present in the aquifer minerals. Identification and assessment of these potential effects is necessary to analyze risks associated with geologic sequestration of CO{sub 2}. This report describes a systematic evaluation of the possible water quality changes in response to CO{sub 2} intrusion into aquifers currently used as sources of potable water in the United States. Our goal was to develop a general understanding of the potential vulnerability of United States potable groundwater resources in the event of CO{sub 2} leakage. This goal was achieved in two main tasks, the first to develop a comprehensive geochemical model representing typical conditions in many freshwater aquifers (Section 3), the second to conduct a systematic reactive-transport modeling study to quantify the effect of CO{sub 2} intrusion into shallow aquifers (Section 4). Via reactive-transport modeling, the amount of hazardous constituents potentially mobilized by the ingress of CO{sub 2} was determined, the fate and migration of these constituents in the groundwater was predicted, and the likelihood that drinking water

  20. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater, Surface Water, Produced Water, and Natural Gas Sampling at the Gasbuggy, New Mexico, Site October 2014 LMSGSBS00614 Available for sale to the public from: U.S. ...

  1. Groundwater monitoring system

    DOE Patents [OSTI]

    Ames, Kenneth R.; Doesburg, James M.; Eschbach, Eugene A.; Kelley, Roy C.; Myers, David A.

    1987-01-01

    A groundwater monitoring system includes a bore, a well casing within and spaced from the bore, and a pump within the casing. A water impermeable seal between the bore and the well casing prevents surface contamination from entering the pump. Above the ground surface is a removable operating means which is connected to the pump piston by a flexible cord. A protective casing extends above ground and has a removable cover. After a groundwater sample has been taken, the cord is disconnected from the operating means. The operating means is removed for taking away, the cord is placed within the protective casing, and the cover closed and locked. The system is thus protected from contamination, as well as from damage by accident or vandalism.

  2. Mitigative techniques and analysis of generic site conditions for ground-water contamination associated with severe accidents

    SciTech Connect (OSTI)

    Shafer, J.M.; Oberlander, P.L.; Skaggs, R.L.

    1984-04-01

    The purpose of this study is to evaluate the feasibility of using ground-water contaminant mitigation techniques to control radionuclide migration following a severe commercial nuclear power reactor accident. The two types of severe commercial reactor accidents investigated are: (1) containment basemat penetration of core melt debris which slowly cools and leaches radionuclides to the subsurface environment, and (2) containment basemat penetration of sump water without full penetration of the core mass. Six generic hydrogeologic site classifications are developed from an evaluation of reported data pertaining to the hydrogeologic properties of all existing and proposed commercial reactor sites. One-dimensional radionuclide transport analyses are conducted on each of the individual reactor sites to determine the generic characteristics of a radionuclide discharge to an accessible environment. Ground-water contaminant mitigation techniques that may be suitable, depending on specific site and accident conditions, for severe power plant accidents are identified and evaluated. Feasible mitigative techniques and associated constraints on feasibility are determined for each of the six hydrogeologic site classifications. The first of three case studies is conducted on a site located on the Texas Gulf Coastal Plain. Mitigative strategies are evaluated for their impact on contaminant transport and results show that the techniques evaluated significantly increased ground-water travel times. 31 references, 118 figures, 62 tables.

  3. Inversion of Gravity Data to Define the Pre-Cenozoic Surface and Regional Structures Possibly Influencing Groundwater Flow in the Rainier Mesa Region, Nye County, Nevada.

    SciTech Connect (OSTI)

    Thomas G. Hildenbrand; Geoffrey A. Phelps; Edward A. Mankinen

    2006-09-21

    A three-dimensional inversion of gravity data from the Rainier Mesa area and surrounding regions reveals a topographically complex pre-Cenozoic basement surface. This model of the depth to pre-Cenozoic basement rocks is intended for use in a 3D hydrogeologic model being constructed for the Rainier Mesa area. Prior to this study, our knowledge of the depth to pre-Cenozoic basement rocks was based on a regional model, applicable to general studies of the greater Nevada Test Site area but inappropriate for higher resolution modeling of ground-water flow across the Rainier Mesa area. The new model incorporates several changes that lead to significant improvements over the previous regional view. First, the addition of constraining wells, encountering old volcanic rocks lying above but near pre-Cenozoic basement, prevents modeled basement from being too shallow. Second, an extensive literature and well data search has led to an increased understanding of the change of rock density with depth in the vicinity of Rainier Mesa. The third, and most important change, relates to the application of several depth-density relationships in the study area instead of a single generalized relationship, thereby improving the overall model fit. In general, the pre-Cenozoic basement surface deepens in the western part of the study area, delineating collapses within the Silent Canyon and Timber Mountain caldera complexes, and shallows in the east in the Eleana Range and Yucca Flat regions, where basement crops out. In the Rainier Mesa study area, basement is generally shallow (< 1 km). The new model identifies previously unrecognized structures within the pre-Cenozoic basement that may influence ground-water flow, such as a shallow basement ridge related to an inferred fault extending northward from Rainier Mesa into Kawich Valley.

  4. Montana Surface Water Application for Beneficial Use (DNRC Form...

    Open Energy Info (EERE)

    for Beneficial Use (DNRC Form 600 GW) Citation Montana Department of Natural Resources & Conservation. Form: Montana Surface Water Application for Beneficial Use (DNRC Form 600...

  5. Montana Surface Water Application for Beneficial Use (DNRC Form...

    Open Energy Info (EERE)

    Beneficial Use (DNRC Form 600 SW) Citation Montana Department of Natural Resources and Conservation. Form: Montana Surface Water Application for Beneficial Use (DNRC Form 600...

  6. Surface Water Sampling At Raft River Geothermal Area (1973) ...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Raft River Geothermal Area (1973) Exploration Activity Details Location...

  7. Surface Water Sampling At Chena Geothermal Area (Holdmann, Et...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Chena Geothermal Area (Holdmann, Et Al., 2006) Exploration Activity...

  8. Texas Surface Water Quality Standards Webpage | Open Energy Informatio...

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Texas Surface Water Quality Standards Webpage Citation Texas Commission on...

  9. Structure of water adsorbed on a mica surface

    SciTech Connect (OSTI)

    Park, Sung-Ho; Sposito, Garrison

    2002-01-29

    Monte Carlo simulations of hydration water on the mica (001) surface under ambient conditions revealed water molecules bound closely to the ditrigonal cavities in the surface, with a lateral distribution of approximately one per cavity, and water molecules interposed between K{sup +} counter ions in a layer situated about 2.5 {angstrom} from a surface O along a direction normal to the (001) plane. The calculated water O density profile was in quantitative agreement with recent X-ray reflectivity measurements indicating strong lateral ordering of the hydration water but liquid-like disorder otherwise.

  10. Reconnaissance of ground-water quality in the Papio-Missouri river natural resources district, Eastern Nebraska, July through September 1992. Water resources investigation

    SciTech Connect (OSTI)

    Verstraeten, I.M.; Ellis, M.J.

    1995-12-31

    The purpose of this report is to describe the water quality of the principal aquifers in the study area. Wells representative of the geology and land use in the study area were selected for water-quality sampling. Variations in constituent concentration among aquifers are discussed. The report describes the spatial distributions of dissolved nitrite plus-nitrate as nitrogen and triazine and other acetanilide herbicides and evaluates the effects of cropland application of nitrogen and herbicides on the ground-water quality within the study area. The report also summarizes the concentrations of dissolved major and trace constituents including radionuclide activity and concentration.

  11. Summary of hydrogeologic controls on ground-water flow at the Nevada Test Site, Nye County, Nevada

    SciTech Connect (OSTI)

    Laczniak, R.J.; Cole, J.C.; Sawyer, D.A.; Trudeau, D.A.

    1996-07-01

    The underground testing of nuclear devices has generated substantial volumes of radioactive and other chemical contaminants below ground at the Nevada Test Site (NTS). Many of the more radioactive contaminants are highly toxic and are known to persist in the environment for thousands of years. In response to concerns about potential health hazards, the US Department of Energy, under its Environmental Restoration Program, has made NTS the subject of a long-term investigation. Efforts will assess whether byproducts of underground testing pose a potential hazard to the health and safety of the public and, if necessary, will evaluate and implement steps to remediate any of the identified dangers. Ground-water flow is the primary mechanism by which contaminants can be transported significant distances away from the initial point of injection. Flow paths between contaminant sources and potential receptors are separated by remote areas that span tens of miles. The diversity and structural complexity of the rocks along these flow paths complicates the hydrology of the region. Although the hydrology has been studied in some detail, much still remains uncertain about flow rates and directions through the fractured-rock aquifers that transmit water great distances across this arid region. Unique to the hydrology of NTS are the effects of underground testing, which severely alter local rock characteristics and affect hydrologic conditions throughout the region. This report summarizes what is known and inferred about ground-water flow throughout the NTS region. The report identifies and updates what is known about some of the major controls on ground-water flow, highlights some of the uncertainties in the current understanding, and prioritizes some of the technical needs as related to the Environmental Restoration Program. 113 refs.

  12. Concentrations of 23 trace elements in ground water and surface water at and near the Idaho National Engineering Laboratory, Idaho, 1988--91

    SciTech Connect (OSTI)

    Liszewski, M.J.; Mann, L.J.

    1993-12-31

    Analytical data for 23 trace elements are reported for ground- and surface-water samples collected at and near the Idaho National Engineering Laboratory during 1988--91. Water samples were collected from 148 wells completed in the Snake River Plain aquifer, 18 wells completed in discontinuous deep perched-water zones, and 1 well completed in an alluvial aquifer. Surface-water samples also were collected from three streams, two springs, two ponds, and one lake. Data are categorized by concentrations of total recoverable of dissolved trace elements. Concentrations of total recoverable trace elements are reported for unfiltered water samples and include results for one or more of the following: aluminum, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, selenium, silver, and zinc. Concentrations of dissolved trace elements are reported for water samples filtered through a nominal 0.45-micron filter and may also include bromide, fluoride, lithium, molybdenum, strontium, thallium, and vanadium. Concentrations of dissolved hexavalent chromium also are reported for many samples. The water samples were analyzed at the US Geological Survey`s National Water Quality Laboratory in Arvada, Colorado. Methods used to collect the water samples and quality assurance instituted for the sampling program are described. Concentrations of chromium equaled or exceeded the maximum contaminant level at 12 ground-water quality monitoring wells. Other trace elements did not exceed their respective maximum contaminant levels.

  13. WAC - 173-210A Water Quality Standards for Surface Waters of...

    Open Energy Info (EERE)

    0A Water Quality Standards for Surface Waters of the State of Washington Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation:...

  14. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Appendix B of Attachment 3: Groundwater hydrology report, Attachment 4: Water resources protection strategy, Final

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    Attachment 3 Groundwater Hydrology Report describes the hydrogeology, water quality, and water resources at the processing site and Dry Flats disposal site. The Hydrological Services calculations contained in Appendix A of Attachment 3, are presented in a separate report. Attachment 4 Water Resources Protection Strategy describes how the remedial action will be in compliance with the proposed EPA groundwater standards.

  15. Nano-Cone Textures Generate Extremely "Robust" Water- Repellant Surfaces

    SciTech Connect (OSTI)

    2013-10-30

    High-speed video of water droplets bouncing off a surface textured with nanocones.The scientists filmed the droplets using a camera capable of capturing 30,000 frames per second.

  16. Hawaii Application for Surface Water Use Permit for Proposed...

    Open Energy Info (EERE)

    for Proposed New Use in a Designated Surface Water Management Area (DLNR Form SWUPA-N) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Hawaii...

  17. EA-1093: Surface Water Drainage System, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to correct deficiencies in, and then to maintain, the surface water drainage system serving the U.S. Department of Energy's Rocky Flats...

  18. New Mexico Surface Water Quality Bureau Federal Dredge and Fill...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: New Mexico Surface Water Quality Bureau Federal Dredge and Fill Permits webpage Author New Mexico...

  19. Fermilab | Tritium at Fermilab | Tritium in Surface Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Water Fermilab map Fermilab has conducted an environmental monitoring program on site for roughly 40 years. In November of 2005, for the first time, we detected low levels of tritium in Indian Creek, one of three creeks that travel through the Fermilab site. Low but measurable levels of tritium continue to be detected in Indian Creek. All tritium levels found on site are well below any federal health and environmental standards. The Department of Energy standard for surface water is

  20. Protection of the Groundwater Resource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection of the Groundwater Resource Protection of the Groundwater Resource Monitoring wells act as sentinels between suspected LANL contamination and the water supply. August 1, 2013 Where to place a sentinel well Where

  1. Groundwater Screen

    Energy Science and Technology Software Center (OSTI)

    1993-11-09

    GWSCREEN was developed for assessment of the groundwater pathway from leaching of radioactive and non radioactive substances from surface or buried sources and release to percolation ponds. The code calculates the limiting soil concentration or effluent release concentration such that, after leaching and transport to the aquifer, regulatory contaminant levels in groundwater are not exceeded. The code uses a mass conservation approach to model three processes: Contaminant release from a source volume, contaminant transport inmore » the unsaturated zone, and contaminant transport in the saturated zone. The source model considers the sorptive properties and solubility of the contaminant. Transport in the unsaturated zone is described by a plug flow model. Transport in the saturated zone is calculated with a semi-analytical solution to the advection dispersion equation in groundwater. Concentration as a function of time at a user specified receptor point and maximum concentration averaged over the exposure interval are also calculated. In addition, the code calculates transport and impacts of radioactive progeny. Input to GWSCREEN is through one, free format ASCII file. This code was designed for assessment and screening of the groundwater pathway when field data is limited. It was not intended to be a predictive tool.« less

  2. Surface-enhanced raman spectroscopy substrate for arsenic sensing in groundwater

    SciTech Connect (OSTI)

    Yang, Peidong; Mulvihill, Martin; Tao, Andrea R.; Sinsermsuksakul, Prasert; Arnold, John

    2015-06-16

    A surface-enhanced Raman spectroscopy (SERS) substrate formed from a plurality of monolayers of polyhedral silver nanocrystals, wherein at least one of the monolayers has polyvinypyrrolidone (PVP) on its surface, and thereby configured for sensing arsenic is described. Highly active SERS substrates are formed by assembling high density monolayers of differently shaped silver nanocrystals onto a solid support. SERS detection is performed directly on this substrate by placing a droplet of the analyte solution onto the nanocrystal monolayer. Adsorbed polymer, polyvinypyrrolidone (PVP), on the surface of the nanoparticles facilitates the binding of both arsenate and arsenite near the silver surface, allowing for highly accurate and sensitive detection capabilities.

  3. An Ontology Design Pattern for Surface Water Features

    SciTech Connect (OSTI)

    Sinha, Gaurav; Mark, David; Kolas, Dave; Varanka, Dalia; Romero, Boleslo E; Feng, Chen-Chieh; Usery, Lynn; Liebermann, Joshua; Sorokine, Alexandre

    2014-01-01

    Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities can be found due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology. It can then be used to systematically incor-porate concepts that are specific to a culture, language, or scientific domain. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex surface water ontologies. A fundamental distinction is made in this on-tology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is imple-mented in OWL, but Description Logic axioms and a detailed explanation is provided. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. A discussion about why there is a need to complement the pattern with other ontologies, es-pecially the previously developed Surface Network pattern is also provided. Fi-nally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through a few queries and annotated geospatial datasets.

  4. A three-dimensional numerical model of predevelopment conditions in the Death Valley regional ground-water flow system, Nevada and California

    SciTech Connect (OSTI)

    D'Agnese, F.A.; O'Brien, G.M.; Faunt, C.C.; Belcher, W.R.; San Juan, Carma

    2002-11-22

    In the early 1990's, two numerical models of the Death Valley regional ground-water flow system were developed by the U.S. Department of Energy. In general, the two models were based on the same basic hydrogeologic data set. In 1998, the U.S. Department of Energy requested that the U.S. Geological Survey develop and maintain a ground-water flow model of the Death Valley region in support of U.S. Department of Energy programs at the Nevada Test Site. The purpose of developing this ''second-generation'' regional model was to enhance the knowledge and understanding of the ground-water flow system as new information and tools are developed. The U.S. Geological Survey also was encouraged by the U.S. Department of Energy to cooperate to the fullest extent with other Federal, State, and local entities in the region to take advantage of the benefits of their knowledge and expertise. The short-term objective of the Death Valley regional ground-water flow system project was to develop a steady-stat e representation of the predevelopment conditions of the ground-water flow system utilizing the two geologic interpretations used to develop the previous numerical models. The long-term objective of this project was to construct and calibrate a transient model that simulates the ground-water conditions of the study area over the historical record that utilizes a newly interpreted hydrogeologic conceptual model. This report describes the result of the predevelopment steady-state model construction and calibration.

  5. Y-12 Groundwater Protection Program Groundwater Monitoring Data Compendium, Revision 1

    SciTech Connect (OSTI)

    2006-12-01

    This document is a compendium of water quality and hydrologic characterization data obtained through December 2005 from the network of groundwater monitoring wells and surface water sampling stations (including springs and building sumps) at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee that have been sampled since January 2003. The primary objectives of this document, hereafter referenced as the Y-12 Groundwater Protection Program (GWPP) Compendium, are to: (1) Serve as a single-source reference for monitoring data that meet the requirements of the Y-12 GWPP, as defined in the Y-12 GWPP Management Plan (BWXT Y-12 L.L.C. [BWXT] 2004); (2) Maintain a detailed analysis and evaluation of the monitoring data for each applicable well, spring, and surface water sampling station, with a focus on results for the primary inorganic, organic, and radiological contaminants in groundwater and surface water at Y-12; and (3) Ensure retention of ''institutional knowledge'' obtained over the long-term (>20-year) history of groundwater and surface water monitoring at Y-12 and the related sources of groundwater and surface water contamination. To achieve these goals, the Y-12 GWPP Compendium brings together salient hydrologic, geologic, geochemical, water-quality, and environmental compliance information that is otherwise disseminated throughout numerous technical documents and reports prepared in support of completed and ongoing environmental contamination assessment, remediation, and monitoring activities performed at Y-12. The following subsections provide background information regarding the overall scope and format of the Y-12 GWPP Compendium and the planned approach for distribution and revision (i.e., administration) of this ''living'' document.

  6. Calendar Year 2000 Groundwater Monitoring Report for the Groundwater Protection Program, U.S. Department of Energy, Y-12 National Security Complex Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2001-03-01

    This report contains the groundwater and surface water monitoring data that were obtained at the US Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) in Oak Ridge, Tennessee, during calendar year (CY) 2000. These monitoring data were collected for the specific purposes of DOE Order 5400.1 site surveillance monitoring and exit pathway/perimeter monitoring, as described in the ''Environmental Monitoring Plan for the Oak Ridge Reservation'' (DOE 1996). Site surveillance monitoring provides data regarding the quality of groundwater and surface water in areas that are, or could be, affected by operations at Y-12. Exit pathway/perimeter monitoring provides data regarding the quality of groundwater and surface water where contaminants from Y-12 are most likely to migrate beyond the boundaries of the DOE Oak Ridge Reservation (ORR). The CY 2000 groundwater and surface water monitoring data presented in this report were obtained under the auspices of the Y-12 Groundwater Protection Program (GWPP), managed by Lockheed Martin Energy Systems, Inc. (LMES) (January-October, 2000) and by BWXT Y-12, L.L.C. (November-December, 2000), and the Water Resources Restoration Program (WRRP), which is managed by Bechtel Jacobs Company LLC. Combining the monitoring results obtained under both the Y-12 GWPP and the WRRP enables this report to serve as a consolidated reference for the groundwater and surface water monitoring data obtained at Y-12 during CY 2000.

  7. Properties of water surface discharge at different pulse repetition rates

    SciTech Connect (OSTI)

    Ruma,; Yoshihara, K.; Hosseini, S. H. R. Sakugawa, T.; Akiyama, H.; Akiyama, M.; Lukeš, P.

    2014-09-28

    The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000 Hz, with 0.5 J per pulse energy output at 25 kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H₂O₂) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H₂O₂ and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

  8. Ground-water geochemistry and radionuclide activity in the Cambrian-Ordovician aquifer of Dodge and Fond du Lac counties, Wisconsin. Technical report

    SciTech Connect (OSTI)

    Weaver, T.R.; Bahr, J.M.; Anderson, M.P.

    1990-01-01

    Analyses of groundwater from wells in the Cambrian-Ordovician aquifer of eastern Wisconsin indicate that regions of the aquifer contain elevated concentrations of dissolved solids, chloride and sulfate. Groundwater from several wells in the area also approach or exceed the current drinking water standard for combined radium activity. Significant changes in groundwater chemistry occur where the aquifer becomes confined by the Maquoketa shale. Concentrations of Cl(-), SO4(2-) and Na(+) increase in the confined region, and the highest combined radium activities are typically observed in the area. Geochemical modeling implies that the observed changes in major ion groundwater chemistry occur in response to the presence of the confining unit which may act as a source of SO4(2-), through gypsum dissolution, and Na(+), through cation exchange. A finite difference groundwater flow model was linked to a particle tracking routine to determine groundwater flow paths and residence times in the aquifer near the boundary between unconfined and confined conditions. Results suggest that the presence of the confining unit produces a vertically stratified flow regime in the confined region.

  9. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small moleculesilica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (?hads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 3.1 kJ/mol water) and ethanol (-78.0 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing watersilica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  10. The ecological evaluation of surface water outfalls at a manufacturing plant in New Jersey

    SciTech Connect (OSTI)

    Harman, C.R.; Gilchrist, W.

    1995-12-31

    Historic metal machining operations at a manufacturing plant in northern New Jersey had resulted in the contamination of three surface water outfalls leading from the plant to a second-order stream used for trout fishing. The outfalls were fed by a combination of non-contact cooling water, stormwater runoff and groundwater infiltration. The outfalls ranged in length from 180 meters to 600 meters. All three of the outfalls pass through forested wetland areas and contained emergent wetland pockets. The ecological evaluation consisted of the collection of sediment samples to evaluate the extent of chemical contamination and the evaluation of the biological integrity of a portion of the surface water outfalls. Additionally, an ecological characterization of the surrounding habitat was prepared. Sediment sampling indicated elevated concentrations of antimony, cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc. Nickel concentrations were the most significant, with concentrations ranging up to 9,850 mg/kg. PCB concentrations ranged between 0.45 mg/kg and 6.4 mg/kg. Elevated concentrations of metals and PCBs were detected to a sediment depth of 45 centimeters. To evaluate the potential for biological impacts from the metals in the sediments, a modified Rapid Bioassessment Protocol 1 evaluation was conducted on the macroinvertebrate population. The results of the evaluation indicated a very sparse macroinvertebrate community. Those organisms that were identified were typical of highly contaminated surface water system. The surrounding wetland systems appeared to be unaffected by the outfall contamination. Based on the results of the first phase of the ecological evaluation, a program of additional sediment sampling and further biological evaluation was prepared.

  11. LANL Water Protection Status Report - FY12 3rd Qtr. (Apr thru Jun 2012)

    SciTech Connect (OSTI)

    Douglass, Craig R.

    2012-07-12

    Continued monitoring of the Buckman Direct Diversion and Los Alamos County Water Supply Wells; Groundwater Protection - Continued implementation of the Interim Facility-Wide Groundwater Monitoring Plan (IFGMP); Surface Water Protection - Continued protection of surface water through implementation of the Individual Stormwater Permit (IP); Buckman Early Notification System operability at 100% per MOU Requirements.

  12. Energy Landscape of Water and Ethanol on Silica Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reachingmore » its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.« less

  13. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  14. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer

    SciTech Connect (OSTI)

    Jurss, Jonah W.; Concepcion, Javier C.; Norris, Michael R.; Templeton, Joseph L.; Meyer, Thomas J.

    2010-04-08

    Single-electron activation of multielectron catalysis has been shown to be viable in catalytic water oxidation with stepwise proton-coupled electron transfer, leading to high-energy catalytic precursors. For the blue dimer, cis,cis-[(bpy)2(H2O)RuIIIORuIII(H2O)(bpy)2]4+, the first well-defined molecular catalyst for water oxidation, stepwise 4e-/4H+ oxidation occurs to give the reactive precursor [(O)RuVORuV(O)]4+. This key intermediate is kinetically inaccessible at an unmodified metal oxide surface, where the only available redox pathway is electron transfer. We report here a remarkable surface activation of indium-tin oxide (In2O3:Sn) electrodes toward catalytic water oxidation by the blue dimer at electrodes derivatized by surface phosphonate binding of [Ru(4,4'-((HO)2P(O)CH2)2bpy)2(bpy)]2+. Surface binding dramatically improves the rate of surface oxidation of the blue dimer and induces water oxidation catalysis.

  15. Radiolysis Concerns for Water Shielding in Fission Surface Power Applications

    SciTech Connect (OSTI)

    Schoenfeld, Michael P.; Anghaie, Samim

    2008-01-21

    This paper presents an overview of radiolysis concerns with regard to water shields for fission surface power. A review of the radiolysis process is presented and key parameters and trends are identified. From this understanding of the radiolytic decomposition of water, shield pressurization and corrosion are identified as the primary concerns. Existing experimental and modeling data addressing concerns are summarized. It was found that radiolysis of pure water in a closed volume results in minimal, if any net decomposition, and therefore reduces the potential for shield pressurization and corrosion.

  16. Wetland Water Cooling Partnership: The Use of Constructed Wetlands to Enhance Thermoelectric Power Plant Cooling and Mitigate the Demand of Surface Water Use

    SciTech Connect (OSTI)

    Apfelbaum, Steven; Duvall, Kenneth; Nelson, Theresa; Mensing, Douglas; Bengtson, Harlan; Eppich, John; Penhallegon, Clayton; Thompson, Ry

    2013-09-30

    Through the Phase I study segment of contract #DE-NT0006644 with the U.S. Department of Energy’s National Energy Technology Laboratory, Applied Ecological Services, Inc. and Sterling Energy Services, LLC (the AES/SES Team) explored the use of constructed wetlands to help address stresses on surface water and groundwater resources from thermoelectric power plant cooling and makeup water requirements. The project objectives were crafted to explore and develop implementable water conservation and cooling strategies using constructed wetlands (not existing, naturally occurring wetlands), with the goal of determining if this strategy has the potential to reduce surface water and groundwater withdrawals of thermoelectric power plants throughout the country. Our team’s exploratory work has documented what appears to be a significant and practical potential for augmenting power plant cooling water resources for makeup supply at many, but not all, thermoelectric power plant sites. The intent is to help alleviate stress on existing surface water and groundwater resources through harvesting, storing, polishing and beneficially re-using critical water resources. Through literature review, development of conceptual created wetland plans, and STELLA-based modeling, the AES/SES team has developed heat and water balances for conventional thermoelectric power plants to evaluate wetland size requirements, water use, and comparative cooling technology costs. The ecological literature on organism tolerances to heated waters was used to understand the range of ecological outcomes achievable in created wetlands. This study suggests that wetlands and water harvesting can provide a practical and cost-effective strategy to augment cooling waters for thermoelectric power plants in many geographic settings of the United States, particularly east of the 100th meridian, and in coastal and riverine locations. The study concluded that constructed wetlands can have significant positive

  17. Water and Carbon Dioxide Adsorption at Olivine Surfaces

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Bylaska, Eric J.; Felmy, Andrew R.

    2013-11-14

    Plane-wave density functional theory (DFT) calculations were performed to simulate water and carbon dioxide adsorption at the (010) surface of five olivine minerals, namely, forsterite (Mg2SiO4), calcio-olivine (Ca2SiO4), tephroite (Mn2SiO4), fayalite (Fe2SiO4), and Co-olivine (Co2SiO4). Adsorption energies per water molecule obtained from energy minimizations varied from -78 kJ mol-1 for fayalite to -128 kJ mol-1 for calcio-olivine at sub-monolayer coverage and became less exothermic as coverage increased. In contrast, carbon dioxide adsorption energies at sub-monolayer coverage ranged from -20 kJ mol-1 for fayalite to -59 kJ mol-1 for calcio-olivine. Therefore, the DFT calculations show a strong driving force for carbon dioxide displacement by water at the surface of all olivine minerals in a competitive adsorption scenario. Additionally, adsorption energies for both water and carbon dioxide were found to be more exothermic for the alkaline-earth (AE) olivines than for the transition-metal (TM) olivines and to not correlate with the solvation enthalpies of the corresponding divalent cations. However, a correlation was obtained with the charge of the surface divalent cation indicating that the more ionic character of the AE cations in the olivine structure relative to the TM cations leads to greater interactions with adsorbed water and carbon dioxide molecules at the surface and thus more exothermic adsorption energies for the AE olivines. For calcio-olivine, which exhibits the highest divalent cation charge of the five olivines, ab initio molecular dynamics simulations showed that this effect leads both water and carbon dioxide to react with the surface and form hydroxyl groups and a carbonate-like species, respectively.

  18. Surface Water Data at Los Alamos National Laboratory 1998 Water Year

    SciTech Connect (OSTI)

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    1999-02-01

    The principal investigators collected and computed surface water discharge data from 19 stream-gaging stations that cover most of Los Alamos National Laboratory. Also included are discharge data from three springs that flow into Caiion de Vane.

  19. Uranium in US surface, ground, and domestic waters. Volume 2

    SciTech Connect (OSTI)

    Drury, J.S.; Reynolds, S.; Owen, P.T.; Ross, R.H.; Ensminger, J.T.

    1981-04-01

    The report Uranium in US Surface, Ground, and Domestic Waters comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium conentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms.

  20. Heterogeneous nucleation of naphthalene vapor on water surface

    SciTech Connect (OSTI)

    Smolik, J.; Schwarz, J.

    1997-01-15

    Transfer processes between drops and gas play an important role in many natural and industrial processes, as absorption of gaseous pollutants by water drops in the atmosphere, combustion of fuel droplets, spray drying, synthesis of nanopowders, wet-dry desulfurization or extinguishing of hot combustion gases. The evaporation of a water drop into a ternary gaseous mixture of air, steam, and naphthalene vapor was investigated. The experimental results were compared with a theoretical prediction based on a numerical solution of coupled boundary layer equations for heat and mass transfer from a drop moving in ternary gas. In the experiments the naphthalene vapor condensed on the water drop as a supercooled liquid even at temperatures far below the melting point of naphthalene. The condensation on drop surface is discussed in terms of classical theory of heterogeneous nucleation on smooth surfaces.

  1. Surface water data at Los Alamos National Laboratory: 2009 water year

    SciTech Connect (OSTI)

    Ortiz, David; McCullough, Betsy

    2010-05-01

    The principal investigators collected and computed surface water discharge data from 73 stream-gage stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs two that flow into Caon de Valle and one that flows into Water Canyon.

  2. Surface water data at Los Alamos National Laboratory: 2008 water year

    SciTech Connect (OSTI)

    Ortiz, David; Cata, Betsy; Kuyumjian, Gregory

    2009-09-01

    The principal investigators collected and computed surface water discharge data from 69 stream-gage stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs two that flow into Caon de Valle and one that flows into Water Canyon.

  3. Surface Water Data at Los Alamos National Laboratory: 1999 Water Year

    SciTech Connect (OSTI)

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    2000-04-01

    The principal investigators collected and computed surface water discharge data from 22 stream-gaging stations that cover most of Los Alamos National Laboratory with one at Bandelier National Monument. Also included are discharge data from three springs that flow into Canon de Valle and nine partial-record storm water stations.

  4. Surface Water Data at Los Alamos National Laboratory 2006 Water Year

    SciTech Connect (OSTI)

    R.P. Romero, D. Ortiz, G. Kuyumjian

    2007-08-01

    The principal investigators collected and computed surface water discharge data from 44 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data for 44 stations.

  5. Surface Water Data at Los Alamos National Laboratory: 2002 Water Year

    SciTech Connect (OSTI)

    D.A. Shaull; D. Ortiz; M.R. Alexander; R.P. Romero

    2003-03-03

    The principal investigators collected and computed surface water discharge data from 34 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data from 16 stations.

  6. Surface Water Data at Los Alamos National Laboratory 2000 Water Year

    SciTech Connect (OSTI)

    D.A.Shaull; M.R.Alexander; R.P.Reynolds; R.P.Romero; E.T.Riebsomer; C.T.McLean

    2001-06-02

    The principal investigators collected and computed surface water discharge data from 23 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs, two that flow into Canon del Valle and one that flows into Water Canyon.

  7. The use of plants to enhance microbial degradation of de-icing agents in soil and surface water

    SciTech Connect (OSTI)

    Rice, P.J.; Coats, J.R.; Anderson, T.A.

    1995-12-31

    Significant quantities of ethylene glycol (EG) and propylene glycol (PG) enter the environment through de-icing of aircraft, spills, and improper disposal of used antifreeze. An estimated 80% of the de-icing fluids spill onto the ground, which may lead to the contamination of soil, surface water, and groundwater. EG and PG contamination of surface waters creates a high biological oxygen demand (BOD) that can adversely impact aquatic communities. Plants and rhizosphere soils have been shown to enhance the degradation of organic pollutants in the soil. The research investigates the use of vegetation to enhance the transformation of EG and PG in soil by studying the fate of these chemicals in nonrhizosphere and rhizosphere soils at three temperatures ({minus}10 C, 0 C, 20 C). Terrestrial and aquatic emergent plants were evaluated as a cost-effective and aesthetically pleasing way to remediate and restore soil and surface waters contaminated with chemical de-icing agents. Additional surface runoff and vegetated undisturbed soil column studies were used to determine the influence of vegetation on the prevention of offsite movement by surface runoff and infiltration. Enhanced degradation of EG occurred in all the rhizosphere soils in comparison to the nonrhizosphere and autoclaved soils. After 28 days at 0 C, 40%, 41%, and 18% of applied EG degraded to CO{sub 2} in the Medicago sativa (alfalfa) and Festuca arundinacea (tall fescue) rhizosphere soil, and nonrhizosphere soil, respectively.

  8. Observation of dynamic water microadsorption on Au surface

    SciTech Connect (OSTI)

    Huang, Xiaokang, E-mail: xiaokang.huang@tqs.com; Gupta, Gaurav; Gao, Weixiang; Tran, Van; Nguyen, Bang; McCormick, Eric; Cui, Yongjie; Yang, Yinbao; Hall, Craig; Isom, Harold [TriQuint Semiconductor, Inc., 500 W Renner Road, Richardson, Texas 75080 (United States)

    2014-05-15

    Experimental and theoretical research on water wettability, adsorption, and condensation on solid surfaces has been ongoing for many decades because of the availability of new materials, new detection and measurement techniques, novel applications, and different scales of dimensions. Au is a metal of special interest because it is chemically inert, has a high surface energy, is highly conductive, and has a relatively high melting point. It has wide applications in semiconductor integrated circuitry, microelectromechanical systems, microfluidics, biochips, jewelry, coinage, and even dental restoration. Therefore, its surface condition, wettability, wear resistance, lubrication, and friction attract a lot of attention from both scientists and engineers. In this paper, the authors experimentally investigated Au{sub 2}O{sub 3} growth, wettability, roughness, and adsorption utilizing atomic force microscopy, scanning electron microscopy, reflectance spectrometry, and contact angle measurement. Samples were made using a GaAs substrate. Utilizing a super-hydrophilic Au surface and the proper surface conditions of the surrounding GaAs, dynamic microadsorption of water on the Au surface was observed in a clean room environment. The Au surface area can be as small as 12??m{sup 2}. The adsorbed water was collected by the GaAs groove structure and then redistributed around the structure. A model was developed to qualitatively describe the dynamic microadsorption process. The effective adsorption rate was estimated by modeling and experimental data. Devices for moisture collection and a liquid channel can be made by properly arranging the wettabilities or contact angles of different materials. These novel devices will be very useful in microfluid applications or biochips.

  9. Porosity distribution in Wolfcamp strata, Palo Duro basin, Texas panhandle: implications for deep-basin ground-water flow

    SciTech Connect (OSTI)

    Conti, R.D.; Wirojanagud, P.

    1984-04-01

    Average-porosity distributions in the Wolfcamp deep-basin aquifer are critical to discernment of the geographic trends in effective-porosity in the Palo Duro basin. Precise data are used to improved resolution of porosity values for computer-simulated areal ground-water modeling. Assessing vertical distributions of lithology and porosity in each well studied involves analysis of crossplotted neutron- and density-porosity log responses. This method more accurately identifies lithology and porosity than does the commonly employed crossplotted neutron-porosity and sonic (interval travel time) responses. Log-derived average-porosity distributions yield information about effective pore volume (i.e., movable water) in the Wolfcamp aquifer and enhance the accuracy of estimated of travel times and velocities of brines in basinwide traverses. Mathematical analysis of average travel time and total effective pore volume yield estimates of the rates of annual discharge from the Wolfcamp aquifer in the Palo Duro basin. Based on average flush rates between 2.2 and 1.5 m.y., annual discharge rates from the Wolfcamp aquifer across the northern and eastern basin boundaries, are about 3.6 x 10/sup 5/ m/sup 3/ year/sup -1/ to 5.3 x 10/sup 5/m/sup 3/ year/sup -1/.

  10. Radiogenic and Stable Isotope and Hydrogeochemical Investigation of Groundwater, Pajarito Plateau and Surrounding Areas, New Mexico

    SciTech Connect (OSTI)

    Patrick Longmire, Michael Dale, Dale Counce, Andrew Manning, Toti Larson, Kim Granzow, Robert Gray, and Brent Newman

    2007-07-15

    From October 2004 through February 2006, Los Alamos National Laboratory, the New Mexico Environment Department-Department of Energy Oversight Bureau, and the United States Geological Survey conducted a hydrochemical investigation. The purpose of the investigation was to evaluate groundwater flow paths and determine groundwater ages using tritium/helium-3 and carbon-14 along with aqueous inorganic chemistry. Knowledge of groundwater age and flow paths provides a technical basis for selecting wells and springs for monitoring. Groundwater dating is also relevant to groundwater resource management, including aquifer sustainability, especially during periods of long-term drought. At Los Alamos, New Mexico, groundwater is either modern (post-1943), submodern (pre-1943), or mixed (containing both pre- and post-1943 components). The regional aquifer primarily consists of submodern groundwater. Mixed-age groundwater results from initial infiltration of surface water, followed by mixing with perched alluvial and intermediate-depth groundwater and the regional aquifer. No groundwater investigation is complete without using tritium/helium-3 and carbon-14 dating methods to quantify amounts of modern, mixed, and/or submodern components present in samples. Computer models of groundwater flow and transport at Los Alamos should be calibrated to groundwater ages for perched intermediate zones and the regional aquifer determined from this investigation. Results of this study clearly demonstrate the occurrence of multiple flow paths and groundwater ages occurring within the Sierra de los Valles, beneath the Pajarito Plateau, and at the White Rock Canyon springs. Localized groundwater recharge occurs within several canyons dissecting the Pajarito Plateau. Perched intermediate-depth groundwater and the regional aquifer beneath Pueblo Canyon, Los Alamos Canyon, Sandia Canyon, Mortandad Canyon, Pajarito Canyon, and Canon de Valle contain a modern component. This modern component consists

  11. Performance of a selective surfaced water wall retrofit

    SciTech Connect (OSTI)

    Arasteh, D.; Harrje, D.T.; Nall, D.H.; Settles, G.S.

    1980-01-01

    The results of a successful passive water wall design and implementation in a suburban central New Jersey home are presented. The unique aspects of this work include the use of a selective surface coating on the exterior face of the thermal mass, the use of low-cost materials, and detailed performance measurements of the wall and home. The overall approach was to evaluate the retrofit possibilities of such a passive solar addition. Material costs of approximately $650 make this water wall design an attractive candidate for the do-it-yourself home retrofit. The wall performed well in supplying almost 20% of the winter heating requrements for the entire house. Compared to night insulation, the selective surface proved to be slightly less effective but much more economical.

  12. Microsoft Word - Groundwater Discharge Permit

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    State Renews Groundwater Discharge Permit for WIPP CARLSBAD, N.M., September 11, 2008 - The New Mexico Environment Department (NMED) has renewed the U.S. Department of Energy's (DOE) Waste Isolation Pilot Plant (WIPP) groundwater discharge permit until 2013. The permit regulates the discharge of water from WIPP facilities and operations to lined ponds, which protect groundwater resources. The permit allows WIPP to discharge domestic wastewater, non-hazardous wastewater and storm water into 13

  13. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect (OSTI)

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  14. May and June 2015 Groundwater and Surface Water Sampling at the...

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma Interference Check Sample Analysis Interference check samples ... Inductively Coupled Plasma Interference Check Sample Analysis Interference check samples ...

  15. April 2012 Groundwater and Surface Water Sampling at the Salmon, Mississippi, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2012-10-12

    Sampling and analysis were conducted on April 16-19, 2012, as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office Of Legacy Management Sites (LMS/PLN/S04351, continually updated). Duplicate samples were collected from locations SA1-1-H, HMH-5R, SA3-4-H, SA1-2-H, Pond W of GZ, and SA5-4-4. One trip blank was collected during this sampling event.

  16. Ground-water monitoring compliance projects for Hanford Site facilities: Progress Report for the Period July 1 to September 30, 1987

    SciTech Connect (OSTI)

    Not Available

    1987-11-01

    This report documents the progress of four Hanford Site ground-water monitoring projects for the period from July 1 to September 310, 1987. The four disposal facilities are the 300 Area Process Trenches, 183-H Solar Evaporation Basins, 200 Area Low-Level Burial Grounds, and Nonradioactive Dangerous Waste (NRDW) Landfill. This report is the fifth in a series of periodic status reports. During this reporting period, field activities consisted of completing repairs on five monitoring wells originally present around the 183-H Basins and completing construction of 25 monitoring wells around the 200 Area Burial Grounds. The 14 wells in the 200 East Area were completed by Kaiser Engineers Hanford (KEH) and the 11 wells in the 200 West Area were compelted by ONWEGO Well Drilling. The NRDW Landfill interim characterization report was submitted to the WDOE and the USEPA in August 1987. Analytical results for the 300 Area, 183-H, and the NRDW Landfill indicate no deviations from previously established trends. Results from the NRDW Land-fill indiate that the facility has no effect on the ground-water quality beneath the facility, except for the detection of coliform bacteria. A possible source of this contamination is the solid-waste lanfill (SWL) adjacent to the NRDW Landfill. Ground-water monitoring data for the NRDW and SWL will be evaluated together in the future. Aquifer testing was completed in the 25 new wells surrounding the 200 Area buiral grounds. 13 refs., 19 refs., 13 tabs.

  17. Colloid characterization and quantification in groundwater samples

    SciTech Connect (OSTI)

    K. Stephen Kung

    2000-06-01

    should be analyzed for colloid size and concentration shortly after they have been collected. A prolonged waiting period after sampling will affect the colloid size distribution as well as colloid concentration resulting from the changes of water chemical properties. The data also shows that sample containers, filter materials, and labware that are used for colloid analyses should be cleaned by specially treated low-colloid-containing water. Water used for sample dilution should be verified for total colloidal particle concentration. They then analyzed freshly collected groundwater from NTS wells ER-20-5{number_sign}1 and {number_sign}3. Results show that these groundwater samples have similar colloid concentrations and particle size distributions. For the particle size range between 50- and 200-nm, about ten trillion (1E10) colloidal particles per liter are present in these water samples. Most of these colloidal particles are less than 100 mm in size. For example, more than 98% of the colloids are smaller than 100 nm in size in the ER-20-5 {number_sign}1 sample. Furthermore, it was found that the smaller the sizes of colloid, the higher the colloid concentration present in the water. For another site at NTS, Cheshire, they had analyzed two zones of groundwater samples. For water samples collected from the lower water zone (near the underground detonation cavity about 3,700 feet of slanted depth from the surface), the colloid concentration was about 5E12 particles per liter. About 20 times less than the lower zone of total colloids was found in water samples collected from the upper aquifer (around 2,511 feet of slanted depth), although colloid size distributions from these two zones appear to be rather similar.

  18. Oil spreading in surface waters with an ice cover

    SciTech Connect (OSTI)

    Yapa, P.D.; Weerasuriya, S.A.; Belaskas, D.P.; Chowdhury, T.

    1993-02-01

    A study of oil spreading in surface waters in the presence of a floating ice cover is presented. The ice can be solid or fragmented. Both axi-symmetrical and uni-directional spreading are studied. The report describes the analytical and numerical model development, the experimental set-up, results from the laboratory experiments, and their comparison with the derived theory and the numerical simulation. To analyze the spreading of oil under solid ice, new equations are derived. These equations consider gravity (buoyancy) - inertia phase, gravity (buoyancy) - viscous phase, and the termination of spreading during the buoyancy - surface tension phase. The derivation considers both the constant discharge mode and the constant volume mode. Therefore, a complete description of the spreading phenomena from the time of initial spill to termination of spreading is presented. The emphasis of the study is on the dominant spreading mechanism for oil under ice, which is the buoyancy-viscous phase.

  19. Novel Americium Treatment Process for Surface Water and Dust Suppression Water

    SciTech Connect (OSTI)

    Tiepel, E.W.; Pigeon, P.; Nesta, S.; Anderson, J.

    2006-07-01

    The Rocky Flats Environmental Technology Site (RFETS), a former nuclear weapons production plant, has been remediated under CERCLA and decommissioned to become a National Wildlife Refuge. The site conducted this cleanup effort under the Rocky Flats Cleanup Agreement (RFCA) that established limits for the discharge of surface and process waters from the site. At the end of 2004, while a number of process buildings were undergoing decommissioning, routine monitoring of a discharge pond (Pond A-4) containing approximately 28 million gallons of water was discovered to have been contaminated with a trace amount of Americium-241 (Am-241). While the amount of Am-241 in the pond waters was very low (0.5 - 0.7 pCi/l), it was above the established Colorado stream standard of 0.15 pCi/l for release to off site drainage waters. The rapid successful treatment of these waters to the regulatory limit was important to the site for two reasons. The first was that the pond was approaching its hold-up limit. Without rapid treatment and release of the Pond A-4 water, typical spring run-off would require water management actions to other drainages onsite or a mass shuttling of water for disposal. The second reason was that this type of contaminated water had not been treated to the stringent stream standard at Rocky Flats before. Technical challenges in treatment could translate to impacts on water and secondary waste management, and ultimately, cost impacts. All of the technical challenges and specific site criteria led to the conclusion that a different approach to the treatment of this problem was necessary and a crash treatability program to identify applicable treatment techniques was undertaken. The goal of this program was to develop treatment options that could be implemented very quickly and would result in the generation of no high volume secondary waste that would be costly to dispose. A novel chemical treatment system was developed and implemented at the RFETS to treat Am

  20. EPA's groundwater protection strategy

    SciTech Connect (OSTI)

    Smith, J. )

    1992-06-01

    What the EPA, working jointly with the states, hopes to accomplish over the next ten years in order to integrate and coordinate all the groundwater programs within the agency is discussed. Although many other EPA programs such as Superfund, Clean Air Act, and Wetlands Management are often highlighted in the media, EPA does not down rate the importance of groundwater protection. Indeed as a resource, it is one of the most important commodities. Groundwater is the basis for life in this country. Recharge rates are no where near what the withdrawal rates are in many areas of the country. Twenty-five percent of all the potable water comes from groundwater. Groundwater supplies 50 percent of the needs for all the US population. If you include strictly rural areas, it supplies 95 percent of all the use. Something that most people who are not groundwater hydrologists would not think about is the fact that groundwater is a recharge mechanism that provides over 30 percent of the flow in streams and major rivers.

  1. Surface Chemistry of GaP(001) and InP(001) in Contact with Water...

    Office of Scientific and Technical Information (OSTI)

    Surface Chemistry of GaP(001) and InP(001) in Contact with Water Citation Details In-Document Search Title: Surface Chemistry of GaP(001) and InP(001) in Contact with Water ...

  2. Status of understanding of the saturated-zone ground-water flow system at Yucca Mountain, Nevada, as of 1995

    SciTech Connect (OSTI)

    Luckey, R.R.; Tucci, P.; Faunt, C.C.; Ervin, E.M.

    1996-12-31

    Yucca Mountain, which is being studied extensively because it is a potential site for a high-level radioactive-waste repository, consists of a thick sequence of volcanic rocks of Tertiary age that are underlain, at least to the southeast, by carbonate rocks of Paleozoic age. Stratigraphic units important to the hydrology of the area include the alluvium, pyroclastic rocks of Miocene age (the Timber Mountain Group; the Paintbrush Group; the Calico Hills Formation; the Crater Flat Group; the Lithic Ridge Tuff; and older tuffs, flows, and lavas beneath the Lithic Ridge Tuff), and sedimentary rocks of Paleozoic age. The saturated zone generally occurs in the Calico Hills Formation and stratigraphically lower units. The saturated zone is divided into three aquifers and two confining units. The flow system at Yucca Mountain is part of the Alkali Flat-Furnace Creek subbasin of the Death Valley groundwater basin. Variations in the gradients of the potentiometric surface provided the basis for subdividing the Yucca Mountain area into zones of: (1) large hydraulic gradient where potentiometric levels change at least 300 meters in a few kilometers; (2) moderate hydraulic gradient where potentiometric levels change about 45 meters in a few kilometers; and (3) small hydraulic gradient where potentiometric levels change only about 2 meters in several kilometers. Vertical hydraulic gradients were measured in only a few boreholes around Yucca Mountain; most boreholes had little change in potentiometric levels with depth. Limited hydraulic testing of boreholes in the Yucca Mountain area indicated that the range in transmissivity was more than 2 to 3 orders of magnitude in a particular hydrogeologic unit, and that the average values for the individual hydrogeologic units generally differed by about 1 order of magnitude. The upper volcanic aquifer seems to be the most permeable hydrogeologic unit, but this conclusion was based on exceedingly limited data.

  3. Diagnosis of Solar Water Heaters Using Solar Storage Tank Surface Temperature Data: Preprint

    SciTech Connect (OSTI)

    Burch, J.; Magnuson, L.; Barker, G.; Bullwinkel, M.

    2009-04-01

    Study of solar water heaters by using surface temperature data of solar storage tanks to diagnose proper operations.

  4. Oahu Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for the island of Oahu. Data is from the following sources: Rotzoll, K., A.I. El-Kadi. 2007. Numerical Ground-Water Flow Simulation for Red Hill Fuel Storage Facilities, NAVFAC Pacific, Oahu, Hawaii - Prepared TEC, Inc. Water Resources Research Center, University of Hawaii, Honolulu.; Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume VII – Island of Oahu Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.; and Whittier, R. and A.I. El-Kadi. 2009. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. December 2009.

  5. AGENDA ADEP Surface Water Protection Project NPDES Storm Water Individual Permit Bi-Annual Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AGENDA ADEP Surface Water Protection Project NPDES Storm Water Individual Permit Bi-Annual Update Public Meeting January 22, 2014 5:30-7:30 p.m. Cities of Gold Conference Center Pojoaque, New Mexico 5:30 p.m. Poster Session 5:50 p.m. Welcome Steve Veenis 6:00 p.m. Flooding Events Fall 2013 Armand Groffman 6:15 p.m. IP Compliance for 2013 Jeff Walterscheid Kate Lynnes 6:35 p.m. IP Corrective Action Screening Process Thaddeus Kostrubala 6:45 p.m. Permit Renewal Kate Lynnes 7:00 p.m. Communities

  6. Modular, multi-level groundwater sampler

    DOE Patents [OSTI]

    Nichols, Ralph L.; Widdowson, Mark A.; Mullinex, Harry; Orne, William H.; Looney, Brian B.

    1994-01-01

    Apparatus for taking a multiple of samples of groundwater or pressure measurements from a well simultaneously. The apparatus comprises a series of chambers arranged in an axial array, each of which is dimensioned to fit into a perforated well casing and leave a small gap between the well casing and the exterior of the chamber. Seals at each end of the container define the limits to the axial portion of the well to be sampled. A submersible pump in each chamber pumps the groundwater that passes through the well casing perforations into the gap from the gap to the surface for analysis. The power lines and hoses for the chambers farther down the array pass through each chamber above them in the array. The seals are solid, water-proof, non-reactive, resilient disks supported to engage the inside surface of the well casing. Because of the modular design, the apparatus provides flexibility for use in a variety of well configurations.

  7. groundwater | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Monitoring at NETL-Albany Ground Water Testing Program NETL is committed to the safety and health of its employees and of nearby residents and to protecting the environment. As part of a DOE environmental protection program, NETL initiated a ground water monitoring program in 2001 with the Oregon Department of Environmental Quality (DEQ) to evaluate the groundwater flowing beneath the Albany, OR facility. Ground water monitoring wells were installed at that time, and periodic samples

  8. Microsoft Word - 2014_1Qtr_Water_Protection_010914.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EP2014-0002 LA-UR-14-20093 Groundwater Protection Surface Water Protection LANL Water Protection Status Report - Fiscal Year 2014 First Quarter (October to December 2013) * An...

  9. Linear relationship between water wetting behavior and microscopic interactions of super-hydrophilic surfaces

    SciTech Connect (OSTI)

    Liu, Jian; Guo, Pan; University of Chinese Academy of Sciences, Beijing 100049 ; Wang, Chunlei; Shi, Guosheng Fang, Haiping

    2013-12-21

    Using molecular dynamics simulations, we show a fine linear relationship between surface energies and microscopic Lennard-Jones parameters of super-hydrophilic surfaces. The linear slope of the super-hydrophilic surfaces is consistent with the linear slope of the super-hydrophobic, hydrophobic, and hydrophilic surfaces where stable water droplets can stand, indicating that there is a universal linear behavior of the surface energies with the water-surface van der Waals interaction that extends from the super-hydrophobic to super-hydrophilic surfaces. Moreover, we find that the linear relationship exists for various substrate types, and the linear slopes of these different types of substrates are dependent on the surface atom density, i.e., higher surface atom densities correspond to larger linear slopes. These results enrich our understanding of water behavior on solid surfaces, especially the water wetting behaviors on uncharged super-hydrophilic metal surfaces.

  10. Hanford Story: Groundwater - Questions - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Hanford Story Hanford Story: Groundwater - Questions The Hanford Story Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size How did contamination get into the groundwater beneath the Hanford Site? What has caused the level of contamination to decrease over the years? What is the 2015 vision for Hanford? What is the goal of the water treatment systems and facilities? What is being done to treat groundwater to remove contamination? Is contaminated groundwater

  11. Monitoring probe for groundwater flow

    DOE Patents [OSTI]

    Looney, B.B.; Ballard, S.

    1994-08-23

    A monitoring probe for detecting groundwater migration is disclosed. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow. 4 figs.

  12. Monitoring probe for groundwater flow

    DOE Patents [OSTI]

    Looney, Brian B.; Ballard, Sanford

    1994-01-01

    A monitoring probe for detecting groundwater migration. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow.

  13. Groundwater Withdrawal Permit Application | Open Energy Information

    Open Energy Info (EERE)

    Withdrawal Permit ApplicationLegal Abstract This application initiates the Drinking Water and Groundwater Protection Division's, a division of the Department of Environmental...

  14. Evapotranspiration Dynamics and Effects on Groundwater Recharge...

    Office of Scientific and Technical Information (OSTI)

    Vegetation type and health had a significant effect on the site water balance. Plant cover ... Heavy grazing increased groundwater recharge (PPT > ET over the 13-year period). ...

  15. Effect of Surface Oxidation on Interfacial Water Structure at a Pyrite (100) Surface as Studied by Molecular Dynamics Simulation

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.; Wick, Collin D.

    2015-06-01

    In the first part of this paper, a Scanning Electron Microscopy and contact angle study of a pyrite surface (100) is reported describing the relationship between surface oxidation and the hydrophilic surface state. In addition to these experimental results, the following simulated surface states were examined using Molecular Dynamics Simulation (MDS): fresh unoxidized (100) surface; polysulfide at the (100) surface; elemental sulfur at the (100) surface. Crystal structures for the polysulfide and elemental sulfur at the (100) surface were simulated using Density Functional Theory (DFT) quantum chemical calculations. The well known oxidation mechanism which involves formation of a metal deficient layer was also described with DFT. Our MDS results of the behavior of interfacial water at the fresh and oxidized pyrite (100) surfaces without/with the presence of ferric hydroxide include simulated contact angles, number density distribution for water, water dipole orientation, water residence time, and hydrogen-bonding considerations. The significance of the formation of ferric hydroxide islands in accounting for the corresponding hydrophilic surface state is revealed not only from experimental contact angle measurements but also from simulated contact angle measurements using MDS. The hydrophilic surface state developed at oxidized pyrite surfaces has been described by MDS, on which basis the surface state is explained based on interfacial water structure. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE funded work performed by Liem X. Dang. Battelle operates the Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES.

  16. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W.; Reinhard, Martin

    2002-01-01

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  17. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an extensive groundwater monitoring and surveillance program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at Los Alamos National Laboratory RELATED IMAGES http://farm4.staticflickr.com/3749/9827580556_473a91fd78_t.jpg Enlarge http://farm3.staticflickr.com/2856/9804364405_b25f74cbb2_t.jpg En

  18. Evaluation of select trade-offs between ground-water remediation and waste minimization for petroleum refining industry

    SciTech Connect (OSTI)

    Andrews, C.D.; McTernan, W.F.; Willett, K.K.

    1996-08-01

    An investigation comparing environmental remediation alternatives and attendant costs for a hypothetical refinery site located in the Arkansas River alluvium was completed. Transport from the land`s surface to and through the ground water of three spill sizes was simulated, representing a base case and two possible levels of waste minimization. Remediation costs were calculated for five alternative remediation options, for three possible regulatory levels and alternative site locations, for four levels of technology improvement, and for eight different years. It is appropriate from environmental and economic perspectives to initiate significant efforts and expenditures that are necessary to minimize the amount and type of waste produced and disposed during refinery operations; or conversely, given expected improvements in technology, is it better to wait until remediation technologies improve, allowing greater environmental compliance at lower costs? The present work used deterministic models to track a light nonaqueous phase liquid (LNAPL) spill through the unsaturated zone to the top of the water table. Benzene leaching from LNAPL to the ground water was further routed through the alluvial aquifer. Contaminant plumes were simulated over 50 yr of transport and remediation costs assigned for each of the five treatment options for each of these years. The results of these efforts show that active remediation is most cost effective after a set point or geochemical quasi-equilibrium is reached, where long-term improvements in technology greatly tilt the recommended option toward remediation. Finally, the impacts associated with increasingly rigorous regulatory levels present potentially significant penalties for the remediation option, but their likelihood of occurrence is difficult to define.

  19. NNSS Groundwater

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Devils Hole meeting puts focus on NNSS groundwater. See page 8. See page 7. Moniz Confirmed Energy Secretary; Replaces Chu Dr. Ernest Moniz was officially sworn in as the 13th ...

  20. NMAC 20.6.2 Ground and Surface Water Protection | Open Energy...

    Open Energy Info (EERE)

    6.2 Ground and Surface Water Protection Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: NMAC 20.6.2 Ground and Surface...

  1. Radio-Ecological Conditions of Groundwater in the Area of Uranium Mining and Milling Facility - 13525

    SciTech Connect (OSTI)

    Titov, A.V.; Semenova, M.P.; Seregin, V.A.; Isaev, D.V.; Metlyaev, E.G. [FSBU SRC A.I.Burnasyan Federal Medical Biophysical Center of FMBA of Russia, Zhivopisnaya Street, 46, Moscow (Russian Federation)] [FSBU SRC A.I.Burnasyan Federal Medical Biophysical Center of FMBA of Russia, Zhivopisnaya Street, 46, Moscow (Russian Federation); Glagolev, A.V.; Klimova, T.I.; Sevtinova, E.B. [FSESP 'Hydrospecgeologiya' (Russian Federation)] [FSESP 'Hydrospecgeologiya' (Russian Federation); Zolotukhina, S.B.; Zhuravleva, L.A. [FSHE 'Centre of Hygiene and Epidemiology no. 107' under FMBA of Russia (Russian Federation)] [FSHE 'Centre of Hygiene and Epidemiology no. 107' under FMBA of Russia (Russian Federation)

    2013-07-01

    Manmade chemical and radioactive contamination of groundwater is one of damaging effects of the uranium mining and milling facilities. Groundwater contamination is of special importance for the area of Priargun Production Mining and Chemical Association, JSC 'PPMCA', because groundwater is the only source of drinking water. The paper describes natural conditions of the site, provides information on changes of near-surface area since the beginning of the company, illustrates the main trends of contaminators migration and assesses manmade impact on the quality and mode of near-surface and ground waters. The paper also provides the results of chemical and radioactive measurements in groundwater at various distances from the sources of manmade contamination to the drinking water supply areas. We show that development of deposits, mine water discharge, leakages from tailing dams and cinder storage facility changed general hydro-chemical balance of the area, contributed to new (overlaid) aureoles and flows of scattering paragenetic uranium elements, which are much smaller in comparison with natural ones. However, increasing flow of groundwater stream at the mouth of Sukhoi Urulyungui due to technological water infiltration, mixing of natural water with filtration streams from industrial reservoirs and sites, containing elevated (relative to natural background) levels of sulfate-, hydro-carbonate and carbonate- ions, led to the development and moving of the uranium contamination aureole from the undeveloped field 'Polevoye' to the water inlet area. The aureole front crossed the southern border of water inlet of drinking purpose. The qualitative composition of groundwater, especially in the southern part of water inlet, steadily changes for the worse. The current Russian intervention levels of gross alpha activity and of some natural radionuclides including {sup 222}Rn are in excess in drinking water; regulations for fluorine and manganese concentrations are also in excess

  2. Post-Closure Groundwater Monitoring Plan for the 1324-N Surface Impoundment and 1324-NA Percolation Pond

    SciTech Connect (OSTI)

    Hartman, Mary J.

    2004-04-02

    The 1324-N Surface Impoundment and the 1324-NA Percolation Pond, located in the 100-N Area of the Hanford Site, are regulated under the Resource Consevation and Recovery Act (RCRA). Surface and underground features of the facilities have been removed and laboratory analyses showed that soil met the closure performance standards. These sites have been backfilled and revegetated.

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........7 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Time-Concentration Graphs ...

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Hydrographs Time-Concentration ...

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Hydrograph Time-Concentration ...

  6. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Time-Concentration Graphs ...

  7. INTEC Groundwater Monitoring Report 2006

    SciTech Connect (OSTI)

    J. R. Forbes S. L. Ansley M. Leecaster

    2007-02-01

    This report summarizes 2006 perched water and groundwater monitoring activities at the Idaho Nuclear Technology and Engineering Center (INTEC) located at the Idaho National Laboratory (INL). During 2006, groundwater samples were collected from a total of 22 Snake River Plain Aquifer (SRPA) monitoring wells, plus six aquifer wells sampled for the Idaho CERCLA Disposal Facility (ICDF) monitoring program. In addition, perched water samples were collected from 21 perched wells and 19 suction lysimeters. Groundwater and perched water samples were analyzed for a suite of radionuclides and inorganic constituents. Laboratory results in this report are compared to drinking water maximum contaminant levels (MCLs). Such comparison is for reference only and it should be noted that the Operable Unit 3-13 Record of Decision does not require that perched water comply with drinking water standards.

  8. Environmental Sciences Division Groundwater Program Office. Annual report, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-09-30

    This first edition of the Martin Marietta Energy Systems, Inc., (Energy Systems) Groundwater Program Annual Report summarizes the work carried out by the Energy Systems GWPO for fiscal year (FY) 1993. This introductory section describes the GWPO`s staffing, organization, and funding sources. The GWPO is responsible for coordination and oversight for all components of the groundwater program at the three Oak Ridge facilities [ORNL, the Oak Ridge Y-12 Plant, and the Oak Ridge K-25 Site], and the PGDP and PORTS, respectively. Several years ago, Energy systems senior management recognized that the manner in which groundwater activities were conducted at the five facilities could result in unnecessary duplication of effort, inadequate technical input to decisions related to groundwater issues, and could create a perception within the regulatory agencies of a confusing and inconsistent approach to groundwater issues at the different facilities. Extensive interactions among management from Environmental Compliance, Environmental Restoration (ER), Environmental Sciences Division, Environmental Safety and Health, and the five facilities ultimately led to development of a net technical umbrella organization for groundwater. On April 25, 1991, the GWPO was authorized to be set up within ORNL thereby establishing a central coordinating office that would develop a consistent technical and administrative direction for the groundwater programs of all facilities and result in compliance with all relevant U.S. Environmental Protection Agency (EPA) regulations such as RCRA and Comprehensive Environmental Restoration, Compensation and Liability Act (CERCLA) as well as U.S. Department of Energy (DOE) regulations and orders. For example, DOE Order 5400.1, issued on November 9, 1988, called for each DOE facility to develop an environmental monitoring program for all media (e.g., air, surface water, and groundwater).

  9. Environmental geochemistry for surface and subsurface waters in the Pajarito Plateau and outlying areas, New Mexico

    SciTech Connect (OSTI)

    Blake, W.D.; Goff, F.; Adams, A.I.; Counce, D.

    1995-05-01

    This report provides background information on waters in the Los Alamos and Santa Fe regions of northern New Mexico. Specifically, the presented data include major element, trace element, and isotope analyses of 130 water samples from 94 different springs, wells, and water bodies in the area. The region considered in this study extends from the western edge of the Valles Caldera to as far east as Santa Fe Lake. For each sample, the presented analysis includes fourteen different major elements, twenty-six trace elements, up to five stable isotopes, and tritium. In addition, this data base contains certain characteristics of the water that are calculated from the aforementioned raw data, including the water`s maximum and minimum residence times, as found from tritium levels assuming no contamination, the water`s recharge elevation, as found from stable isotopes, and the charge balance of the water. The data in this report are meant to provide background information for investigations in groundwater hydrology and geochemistry, and for environmental projects. For the latter projects, the presented information would be useful for determining the presence of contamination it any one location by enabling one to compare potential contaminant levels to the background levels presented here. Likely locations of interest are those possibly effected by anthropogenic activities, including locations in and around Los Alamos National Laboratory, White Rock Canyon, and developed areas in the Rio Grande Valley.

  10. Estimated Water Flows in 2005: United States

    SciTech Connect (OSTI)

    Smith, C A; Belles, R D; Simon, A J

    2011-03-16

    Flow charts depicting water use in the United States have been constructed from publicly available data and estimates of water use patterns. Approximately 410,500 million gallons per day of water are managed throughout the United States for use in farming, power production, residential, commercial, and industrial applications. Water is obtained from four major resource classes: fresh surface-water, saline (ocean) surface-water, fresh groundwater and saline (brackish) groundwater. Water that is not consumed or evaporated during its use is returned to surface bodies of water. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states in addition to Puerto Rico and the Virgin Islands) and one national water flow chart representing a comprehensive systems view of national water resources, use, and disposition.

  11. Surface Water Sampling At Chena Geothermal Area (Waring, Et Al...

    Open Energy Info (EERE)

    calcium and magnesium concentrations were measured, with elevated levels of silica and sulfate. Surface fumarole gases were tested with a flame to indicate carbon dioxide...

  12. Calendar Year 2007 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Elvado Environmental LLC

    2008-12-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2007 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2007 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2007 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by BWXT Y-12, L.L.C. (BWXT), and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). In December 2007, the BWXT corporate name was changed to Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12), which is applied to personnel and organizations throughout CY 2007 for this report. Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2007 monitoring results fulfill requirements of

  13. Water adsorption induced in-plane domain switching on BaTiO{sub 3} surface

    SciTech Connect (OSTI)

    Li, X.; Bai, Y.; Su, Y. J.; Wang, B. C.

    2015-09-07

    In this study, the influences of the adsorption of water molecules on the changes in the atomic and electric structures of BaTiO{sub 3} surface were investigated using ab initio calculation. Water molecules are molecularly and dissociatively adsorbed on the BaTiO{sub 3} surface, which makes electrons transfer from water molecules to the BaTiO{sub 3} surface. The redistribution of electrons in the BaTiO{sub 3} surface layers weakens the Ba-O interactions and strengthens the Ti-O interactions, so that the Ti atom shifts in TiO{sub 2} plane, i.e., an in-plane domain switching. The adsorption of water molecules on BaTiO{sub 3} surfaces also results in a reduction in the surface rumpling.

  14. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  15. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  16. September 2004 Water Sampling

    Office of Legacy Management (LM)

    February 2015 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Site April 2015 LMS/GJO/S00215 This page intentionally left blank U.S. Department of Energy DVP-February 2015, Grand Junction, Colorado, Site April 2015 RIN 15026795 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Site Sample Location Map

  17. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Slick Rock East and West, Colorado, Processing Sites November 2013 LMS/SRE/SRW/S0913 This page intentionally left blank U.S. Department of Energy DVP-September 2013, Slick Rock, Colorado November 2013 RIN 13095593 Page i Contents Sampling Event Summary ...............................................................................................................1 Slick Rock East and West, Colorado, Processing Sites, Sample Location Map

  18. Calendar Year 2008 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Elvado Environmental LLC

    2009-12-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2008 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2008 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2008 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2008 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the

  19. Calendar Year 2010 Groundwater Monitoring Report, U.S. Department Of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Elvado Environmental LLC

    2011-12-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2010 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2010 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2010 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2010 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the

  20. Calendar Year 2011 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Elvado Environmental LLC,

    2012-12-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2011 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2011 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12. The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. This report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and known extent of groundwater contamination. The CY 2011 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by the DOE Environmental Management (EM) contractor responsible for environmental cleanup on the ORR. In August 2011, URS | CH2M Oak Ridge LLC (UCOR) replaced Bechtel Jacobs Company LLC (BJC) as the DOE EM contractor. For this report, BJC/UCOR will be referenced as the managing contractor for CY 2011. Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC/UCOR (i.e., coordinating sample collection and sharing data) ensures

  1. Calendar Year 2001 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2002-03-31

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2001 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) in Oak Ridge, Tennessee. The monitoring data were obtained from groundwater and surface water sampling locations within three hydrogeologic regimes at Y-12. The following sections of this report provide details regarding the CY 2001 groundwater and surface water monitoring activities in the Bear Creek, East Fork, and Chestnut Ridge Regimes. Section 2 identifies the sampling locations in each hydrogeologic regime and the corresponding sampling frequency during CY 2001, along with the associated quality assurance/quality control (QA/QC) sampling. Section 3 describes groundwater and surface water sample collection and Section 4 identifies the field measurements and laboratory analytes for each sampling location. Section 5 outlines the data management protocols and data quality objectives (DQOs). Section 6 describes the groundwater elevation monitoring in each regime during CY 2001 and Section 7 lists the documents cited for more detailed operational, regulatory, and technical information.

  2. Site characterization plan for groundwater in Waste Area Grouping 1 at Oak Ridge National Laboratory, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Lee, R.R.; Curtis, A.H.; Houlberg, L.M.; Purucker, S.T.; Singer, M.L.; Tardiff, M.F.; Wolf, D.A.

    1994-07-01

    The Waste Area Grouping (WAG) 1 Groundwater Operable Unit (OU) at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, is undergoing a site characterization to identify environmental contamination that may be present. This document, Site Characterization Report for Groundwater in Waste Area Grouping I at Oak Ridge National Laboratory, Oak Ridge, Tennessee, identifies areas of concern with respect to WAG 1 groundwater and presents the rationale, justification, and objectives for conducting this continuing site characterization. This report summarizes the operations that have taken place at each of the areas of concern in WAG 1, summarizes previous characterization studies that have been performed, presents interpretations of previously collected data and information, identifies contaminants of concern, and presents an action plan for further site investigations and early actions that will lead to identification of contaminant sources, their major groundwater pathways, and reduced off-site migration of contaminated groundwater to surface water. Site characterization Activities performed to date at WAG I have indicated that groundwater contamination, principally radiological contamination, is widespread. An extensive network of underground pipelines and utilities have contributed to the dispersal of contaminants to an unknown extent. The general absence of radiological contamination in surface water at the perimeter of WAG 1 is attributed to the presence of pipelines and underground waste storage tank sumps and dry wells distributed throughout WAG 1 which remove more than about 40 million gal of contaminated groundwater per year.

  3. Method of and device for detecting oil pollutions on water surfaces

    DOE Patents [OSTI]

    Belov, Michael Leonidovich; Gorodnichev, Victor Aleksandrovich; Kozintsev, Valentin Ivanovich; Smimova, Olga Alekseevna; Fedotov, Yurii Victorovich; Khroustaleva, Anastasiva Michailovnan

    2008-08-26

    Detection of oil pollution on water surfaces includes providing echo signals obtained from optical radiation of a clean water area at two wavelengths, optically radiating an investigated water area at two wavelengths and obtaining echo signals from the optical radiation of the investigated water area at the two wavelengths, comparing the echo signals obtained from the radiation of the investigated area at two wavelengths with the echo signals obtained from the radiation of the clean water area, and based on the comparison, determining presence or absence of oil pollution in the investigated water area.

  4. Improved Design Tools for Surface Water and Standing Column Well Heat Pump

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems | Department of Energy Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems This project will improve the capability of engineers to design heat pump systems that utilize surface water or standing column wells (SCW) as their heat sources and sinks. gshp_spitler_design_tools.html_.pdf (286.01 KB) More Documents & Publications City of Eagan …Civic Ice Arena Renovation

  5. Nationwide water availability data for energy-water modeling.

    SciTech Connect (OSTI)

    Tidwell, Vincent Carroll; Zemlick, Katie M.; Klise, Geoffrey Taylor

    2013-11-01

    The purpose of this effort is to explore where the availability of water could be a limiting factor in the siting of new electric power generation. To support this analysis, water availability is mapped at the county level for the conterminous United States (3109 counties). Five water sources are individually considered, including unappropriated surface water, unappropriated groundwater, appropriated water (western U.S. only), municipal wastewater and brackish groundwater. Also mapped is projected growth in non-thermoelectric consumptive water demand to 2035. Finally, the water availability metrics are accompanied by estimated costs associated with utilizing that particular supply of water. Ultimately these data sets are being developed for use in the National Renewable Energy Laboratories' (NREL) Regional Energy Deployment System (ReEDS) model, designed to investigate the likely deployment of new energy installations in the U.S., subject to a number of constraints, particularly water.

  6. Effects of uranium-mining releases on ground-water quality in the Puerco River Basin, Arizona and New Mexico

    SciTech Connect (OSTI)

    Van Metre, P.C.; Wirt, L.; Lopes, T.J.; Ferguson, S.A.

    1997-12-31

    The purpose of this report is to describe: (1) the water quality of the Puerco River alluvial aquifer, (2) the movement of water between the Puerco River and underlying alluvial aquifer, and (3) changes in the water quality of the alluvial and bedrock aquifers related to releases of contaminants by uranium-mining activities. This report focuses on the alluvial aquifer near the reach of the Puerco River that was subjected to continuous flow containing mine-dewatering effluents and to flow containing mine-dewatering effluents and to flow from the tailings-pond spill.

  7. Kauai Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for Kauai. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014.; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume IV – Island of Kauai Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2015.

  8. Kauai Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for Kauai. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014.; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report Volume IV Island of Kauai Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2015.

  9. Clean Boiler Water-side Heat Transfer Surfaces - Steam Tip Sheet #7

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  10. 5 CCR 1002-31 Basic Standards and Methodologies for Surface Water...

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: 5 CCR 1002-31 Basic Standards and Methodologies for Surface Water RegulationLegal Abstract...

  11. NMSA 72-5 Appropriation and Use of Surface Water | Open Energy...

    Open Energy Info (EERE)

    5 Appropriation and Use of Surface Water Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: NMSA 72-5 Appropriation and Use of...

  12. "Nanoengineered Surfaces for Efficiency Enhancements in Energy and Water",

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professor Kripa Varansi, Massachusetts Institute of Technology | Princeton Plasma Physics Lab October 24, 2012, 4:15pm Colloquia MBG Auditorium "Nanoengineered Surfaces for Efficiency Enhancements in Energy and Water", Professor Kripa Varansi, Massachusetts Institute of Technology Thermal-fluid-surface interactions are ubiquitous in multiple industries including Energy, Water, Agriculture, Transportation, Electronics Cooling, Buildings, etc. Over the years, these systems have been

  13. Molecular Dynamics Simulation and Analysis of Interfacial Water at Selected Sulfide Mineral Surfaces under Anaerobic Conditions

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.

    2014-04-10

    In this paper, we report on a molecular dynamics simulation (MDS) study of the behavior of interfacial water at selected sulfide mineral surfaces under anaerobic conditions. The study revealed the interfacial water structure and wetting characteristics of the pyrite (100) surface, galena (100) surface, chalcopyrite (012) surface, sphalerite (110) surface, and molybdenite surfaces (i.e., the face, armchair-edge, and zigzag-edge surfaces), including simulated contact angles, relative number density profiles, water dipole orientations, hydrogen-bonding, and residence times. For force fields of the metal and sulfur atoms in selected sulfide minerals used in the MDS, we used the universal force field (UFF) and another set of force fields optimized by quantum chemical calculations for interactions with interfacial water molecules at selected sulfide mineral surfaces. Simulation results for the structural and dynamic properties of interfacial water molecules indicate the natural hydrophobic character for the selected sulfide mineral surfaces under anaerobic conditions as well as the relatively weak hydrophobicity for the sphalerite (110) surface and two molybdenite edge surfaces. Part of the financial support for this study was provided by the U.S. Department of Energy (DOE) under Basic Science Grant No. DE-FG-03-93ER14315. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE, funded work performed by Liem X. Dang. Battelle operates Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES. The authors are grateful to Professor Tsun-Mei Chang for valuable discussions.

  14. Groundwater Monitoring

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at...

  15. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  16. Compendium of ordinances for groundwater protection

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage in agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.

  17. Surface water supply for the Clearlake, California Hot Dry Rock Geothermal Project

    SciTech Connect (OSTI)

    Jager, A.R.

    1996-03-01

    It is proposed to construct a demonstration Hot Dry Rock (HDR) geothermal plant in the vicinity of the City of Clearlake. An interim evaluation has been made of the availability of surface water to supply the plant. The evaluation has required consideration of the likely water consumption of such a plant. It has also required consideration of population, land, and water uses in the drainage basins adjacent to Clear Lake, where the HDR demonstration project is likely to be located. Five sources were identified that appear to be able to supply water of suitable quality in adequate quantity for initial filling of the reservoir, and on a continuing basis, as makeup for water losses during operation. Those sources are California Cities Water Company, a municipal supplier to the City of Clearlake; Clear Lake, controlled by Yolo County Flood Control and Water Conservation District; Borax Lake, controlled by a local developer; Southeast Regional Wastewater Treatment Plant, controlled by Lake County; and wells, ponds, and streams on private land. The evaluation involved the water uses, water rights, stream flows, precipitation, evaporation, a water balance, and water quality. In spite of California`s prolonged drought, the interim conclusion is that adequate water is available at a reasonable cost to supply the proposed HDR demonstration project.

  18. Groundwater quality assessment for the Upper East Fork Poplar Creek Hydrogeologic Regime at the Y-12 Plant. 1991 groundwater quality data and calculated rate of contaminant migration

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This report contains groundwater quality data obtained during the 1991 calendar year at several waste management facilities and petroleum fuel underground storage tank (UST) sites associated with the Y-12 Plant. These sites are within the Upper East Fork Poplar Creek Hydrogeologic Regime (UEFPCHR), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring and remediation. This report was prepared for informational purposes. Included are the analytical data for groundwater samples collected from selected monitoring wells during 1991 and the results for quality assurance/quality control (QA/QC) samples associated with each groundwater sample. This report also contains summaries of selected data, including ion-charge balances for each groundwater sample, a summary of analytical results for nitrate (a principle contaminant in the UEFPCHR), results of volatile organic compounds (VOCs) analyses validated using the associated QA/QC sample data, a summary of trace metal concentrations which exceeded drinking-water standards, and a summary of radiochemical analyses and associated counting errors.

  19. The effect of plutonium dioxide water surface coverage on the generation of hydrogen and oxygen

    SciTech Connect (OSTI)

    Veirs, Douglas K.; Berg, John M.; Crowder, Mark L.

    2012-06-20

    The conditions for the production of oxygen during radiolysis of water adsorbed onto plutonium dioxide powder are discussed. Studies in the literature investigating the radiolysis of water show that both oxygen and hydrogen can be generated from water adsorbed on high-purity plutonium dioxide powder. These studies indicate that there is a threshold in the amount of water below which oxygen is not generated. The threshold is associated with the number of monolayers of adsorbed water and is shown to occur at approximately two monolayers of molecularly adsorbed water. Material in equilibrium with 50% relative humidity (RH) will be at the threshold for oxygen generation. Using two monolayers of molecularly adsorbed water as the threshold for oxygen production, the total pressure under various conditions is calculated assuming stoichiometric production of hydrogen and oxygen. The specific surface area of the oxide has a strong effect on the final partial pressure. The specific surface areas resulting in the highest pressures within a 3013 container are evaluated. The potential for oxygen generation is mitigated by reduced relative humidity, and hence moisture adsorption, at the oxide surface which occurs if the oxide is warmer than the ambient air. The potential for oxygen generation approaches zero as the temperature difference between the ambient air and the material approaches 6 C.

  20. Modular, multi-level groundwater sampler

    DOE Patents [OSTI]

    Nichols, R.L.; Widdowson, M.A.; Mullinex, H.; Orne, W.H.; Looney, B.B.

    1994-03-15

    An apparatus is described for taking a multiple of samples of groundwater or pressure measurements from a well simultaneously. The apparatus comprises a series of chambers arranged in an axial array, each of which is dimensioned to fit into a perforated well casing and leave a small gap between the well casing and the exterior of the chamber. Seals at each end of the container define the limits to the axial portion of the well to be sampled. A submersible pump in each chamber pumps the groundwater that passes through the well casing perforations into the gap from the gap to the surface for analysis. The power lines and hoses for the chambers farther down the array pass through each chamber above them in the array. The seals are solid, water-proof, non-reactive, resilient disks supported to engage the inside surface of the well casing. Because of the modular design, the apparatus provides flexibility for use in a variety of well configurations. 3 figures.

  1. Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

    SciTech Connect (OSTI)

    Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

    2010-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

  2. Soil & Groundwater Remediation | Department of Energy

    Office of Environmental Management (EM)

    The inventory at the DOE sites includes 6.5 trillion liters of contaminated groundwater, an amount equal to about four times the daily U.S. water consumption, and 40 million cubic ...

  3. Treatment Resin Reduces Costs, Materials in Hanford Groundwater...

    Office of Environmental Management (EM)

    southeast Washington state. The material, an ion exchange resin, is used in groundwater treatment systems to strip contaminants from the water-in this case, hexavalent...

  4. Groundwater Sampling At Kilauea East Rift Geothermal Area (Cox...

    Open Energy Info (EERE)

    groundwater can be a useful geochemical indicator for geothermal exploration when other water chemistry techniques are ambiguous. This research was useful for locating some areas...

  5. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-01-01

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  6. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-12-31

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  7. Groundwater Monitoring Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Monitoring Network Groundwater Monitoring Network The network includes 92 natural sources, 102 regional aquifer wells, 41 intermediate-depth wells and springs, and 67 wells in alluvium in canyons. August 1, 2013 Map of LANL's groundwater monitoring network Map of LANL's groundwater monitoring network

  8. Y-12 Groundwater Protection Program Calendar Year 2000 Groundwater Monitoring Data Evaluation Report for the Bear Creek Hydrogeologic Regime at the U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2001-09-01

    This report presents an evaluation of the groundwater and surface water monitoring data obtained during calendar year (CY) 2000 in the Bear Creek Hydrogeologic Regime (Bear Creek Regime). The Bear Creek Regime encompasses many confirmed and potential sources of groundwater and surface water contamination associated with the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) in Oak Ridge, Tennessee (Figure A.1). Prepared by the Y-12 Groundwater Protection Program (GWPP), this report addresses applicable provisions of DOE Order 5400.1 (General Environmental Protection Program) that require: (1) an evaluation of the quantity and quality of groundwater and surface water in areas that are, or could be, affected by Y-12 operations, (2) an evaluation of groundwater and surface water quality in areas where contaminants from Y-12 operations are most likely to migrate beyond the DOE Oak Ridge Reservation (ORR) property line, and (3) an evaluation of long-term trends in groundwater quality at Y-12. The following sections of this report contain relevant background information (Section 2.0); describe the results of the respective data evaluations required under DOE Order 5400.1 (Section 3.0); summarize significant findings of each evaluation (Section 4.0); and list the technical reports and regulatory documents cited for more detailed information (Section 5.0). Illustrations (maps and trend graphs) are presented in Appendix A. Brief data summary tables referenced in each section are contained within the sections. Supplemental information and extensive data tables are provided in Appendix B.

  9. TECHNICAL EVALUATION OF THE INTERACTION OF GROUNDWATER WITH THE COLUMBIA RIVER AT THE DEPARTMENT OF ENERGY HANFORD SITE 100-D AREA

    SciTech Connect (OSTI)

    PETERSEN SW

    2008-11-05

    water and site groundwater in this zone has been estimated to be equal parts of groundwater and river water, a wide range of mixing ratios likely occurs at various times of the day and year. The degree of mixing and dilution appears to be greatly influenced by the river stage and other groundwater/surface water interaction. The extent of mixing, thus, has implications for the design and operation of the groundwater remediation systems. Improved understanding of this 'dilution' mechanism is needed to design an optimum 'systems approach' to accelerate remediation of the near-shore contaminant plumes. More information on the pathway from near-river mapped plumes to riverbed receptor locations is also needed to develop a defensible proposed plan for a future ROD for final remedial action of contaminated groundwater. In April 2008, an expert panel of scientists was convened to review existing information and provide observations and suggestions to improve the current understanding of groundwater surface water interactions in the 100 Areas (primarily focusing on 100-D Area), and to identify what additional analyses or approaches may provide critical information needed to design and implement remediation systems that will minimize impacts to river aquatic systems. Specific objectives provided to the panel included: (1) comment on approaches and methods to improve the current understanding of groundwater-surface water interactions, specifically how contaminated groundwater enters the riverbed and how this relates to remediation of chromate in the groundwater in the 100 Areas; (2) evaluate past and current data collection methods, data analysis techniques, assumptions, and groundwater transport and mixing mechanisms; (3) evaluate the current monitoring network (monitoring wells, aquifer tubes, and shoreline/river monitoring); (4) evaluate the role played by modeling; and (5) suggest additional research to fill data gaps and perform modeling.

  10. Electric double layer at metal oxide surfaces: Static properties of the cassiterite - Water Interface

    SciTech Connect (OSTI)

    Vlcek, Lukas; Zhang, Zhan; Machesky, Michael L.; Wesolowski, David J

    2007-04-01

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn

  11. Electric double layer at metal oxide surfaces:static properties of the cassiterite-water interface.

    SciTech Connect (OSTI)

    Vlcek, L.; Zhang, Z.; Machesky, M .L.; Fenter, P.; Rosenqvist, J.; Wesolowski, D. J.; Anovitz, L. M.; Predota, M.; Cummings, P. T.; Vanderbilt Univ.; ORNL; Univ. of South Bohimia; Illinois State Water Survey

    2007-03-24

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn

  12. Recent California water transfers: Emerging options in water management. Final report

    SciTech Connect (OSTI)

    Lund, J.R.; Israel, M.

    1992-12-01

    Report examines the recent use of water transfers in California. Emphasis is on the use of water transfers during the current drought and how planners and operators of federal, state, and local systems can integrate water transfers into the planning and operations of their systems. Through the California experience, the study identifies motivations for incorporating water transfers into water supply systems, reviews a variety of water transfer types, and discusses the integration of water transfers with traditional supply argumentation and water conservation measures. Limitations, constraints, and difficulties for employing water transfers within existing systems are also discussed. The study focuses primarily on the technical, planning, and operational aspects of water transfers, rather than the legal, economic, and social implications. Water transfers, Water management, Water bank, Water supply, Water use, Water institutions, Infrastructure, California state water project, Water rights, Drought, Surface water, Groundwater.

  13. Groundwater - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Richland Operations Office Richland Operations Office River Corridor Central Plateau Groundwater PHOENIX Groundwater Annual Reports Mission Support Newsroom Groundwater Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size 200WPumpandTreat 200 West Pump and Treat The groundwater treatment project includes a number of injection and extraction wells feeding five pump and treat facilities in the 100 Area near the reactors, as well as a state-of-the-art

  14. Economic consequences of land surface subsidence

    SciTech Connect (OSTI)

    Fowler, L.C.

    1981-06-01

    Overdraft in the Santa Clara Valley, Calif., groundwater basin caused land surface subsidence over an area of 63,000 ha with a maximum depression of 3.6 m from 1912-67. Since cessation of overdraft and replenishment of groundwater levels in 1969, there has been no significant land surface subsidence. During the period of active subsidence, water well casings buckled, sewers lost capacity as a result of changes in slope, and roads and railroads had to be raised. These damages are estimated at over $130 million. (1 graph, 1 map, 6 photos, 2 references, 1 table)

  15. Calendar year 1993 groundwater quality report for the Upper East Fork Poplar Creek Hydrogeologic Regime, Y-12 Plant, Oak Ridge, Tennessee. 1993 groundwater quality data and calculated rate of contaminant migration, Part 1

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    This report contains groundwater quality data obtained during the 1993 calendar year (CY) at several waste management facilities and petroleum fuel underground storage tank (UST) sites associated with the US Department of Energy (DOE) Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. These sites are within the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), which is one of three regimes defined for the purposes of groundwater and surface-water quality monitoring at the Y-12 Plant. The Environmental Management Department of the Y-12 Plant Health, Safety, Environment, and Accountability Organization manages the groundwater monitoring activities in each regime as part of the Y-12 Plant Groundwater Protection Program (GWPP). The annual groundwater report for the East Fork Regime is completed in two-parts; Part 1 (this report) containing the groundwater quality data and Part 2 containing a detailed evaluation of the data. The primary purpose of this report is to serve as a reference for the groundwater data obtained each year under the lead of the Y-12 Plant GWPP. However, because it contains information needed to comply with the Resource Conservation and Recovery Act (RCRA) interim status assessment monitoring reporting requirements, this report is submitted to the Tennessee Department of Health and Environment (TDEC) by the RCRA reporting deadline.

  16. A User’s Guide to the Comprehensive Water Quality Database for Groundwater in the Vicinity of the Nevada Test Site, Rev. No.: 1

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-09-01

    This water quality database (viz.GeochemXX.mdb) has been developed as part of the Underground Test Area (UGTA) Program with the cooperation of several agencies actively participating in ongoing evaluation and characterization activities under contract to the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO). The database has been constructed to provide up-to-date, comprehensive, and quality controlled data in a uniform format for the support of current and future projects. This database provides a valuable tool for geochemical and hydrogeologic evaluations of the Nevada Test Site (NTS) and surrounding region. Chemistry data have been compiled for groundwater within the NTS and the surrounding region. These data include major ions, organic compounds, trace elements, radionuclides, various field parameters, and environmental isotopes. Colloid data are also included in the database. The GeochemXX.mdb database is distributed on an annual basis. The extension ''XX'' within the database title is replaced by the last two digits of the release year (e.g., Geochem06 for the version released during the 2006 fiscal year). The database is distributed via compact disc (CD) and is also uploaded to the Common Data Repository (CDR) in order to make it available to all agencies with DOE intranet access. This report provides an explanation of the database configuration and summarizes the general content and utility of the individual data tables. In addition to describing the data, subsequent sections of this report provide the data user with an explanation of the quality assurance/quality control (QA/QC) protocols for this database.

  17. Complexity of Groundwater Contaminants at DOE Sites

    SciTech Connect (OSTI)

    Hazen, T.C.; Faybishenko, B.; Jordan, P.

    2010-12-03

    The U.S. Department of Energy (DOE) is responsible for the remediation and long-term stewardship of one of the world's largest groundwater contamination portfolios, with a significant number of plumes containing various contaminants, and considerable total mass and activity. As of 1999, the DOE's Office of Environmental Management was responsible for remediation, waste management, or nuclear materials and facility stabilization at 144 sites in 31 states and one U.S. territory, out of which 109 sites were expected to require long-term stewardship. Currently, 19 DOE sites are on the National Priority List. The total number of contaminated plumes on DOE lands is estimated to be 10,000. However, a significant number of DOE sites have not yet been fully characterized. The most prevalent contaminated media are groundwater and soil, although contaminated sediment, sludge, and surface water also are present. Groundwater, soil, and sediment contamination are present at 72% of all DOE sites. A proper characterization of the contaminant inventory at DOE sites is critical for accomplishing one of the primary DOE missions -- planning basic research to understand the complex physical, chemical, and biological properties of contaminated sites. Note that the definitions of the terms 'site' and 'facility' may differ from one publication to another. In this report, the terms 'site,' 'facility' or 'installation' are used to identify a contiguous land area within the borders of a property, which may contain more than one plume. The term 'plume' is used here to indicate an individual area of contamination, which can be small or large. Even though several publications and databases contain information on groundwater contamination and remediation technologies, no statistical analyses of the contaminant inventory at DOE sites has been prepared since the 1992 report by Riley and Zachara. The DOE Groundwater Data Base (GWD) presents data as of 2003 for 221 groundwater plumes at 60 DOE sites

  18. A technical approach to groundwater contamination problems

    SciTech Connect (OSTI)

    Burton, J.C.; Leser, C.; Rose, C.M.

    1993-06-01

    Argonne National Laboratory has been performing technical investigations at sites in Nebraska and Kansas that have identified groundwater contamination by carbon tetrachloride. This comprehensive program will ultimately provide the affected communities with safe drinking water. The first step in the program is to evaluate the available data and identify sites that will require an Alternate Water Supply Study (AWSS). The objective of the AWSS is to identify options for providing a safe drinking water supply to all users, in compliance with the Safe Drinking Water Act. The AWSS consists of an engineering and cost evaluation followed by implementation of the selected alternative. For sites with contamination less than a specific concentration, the AWSS is regarded as a satisfactory long term solution, and no further action is taken. For those sites with concentrations above that specific limit, the AWSS implementation is regarded as only a stopgap measure, and the site is selected for additional remedial action. The first step of the remedial action is an Expedited Site Characterization (ESC). The ESC was developed at Argonne to decrease the cost and time of the remedial investigation and feasibility study while producing a high-quality technical investigation. The ESC is designed to characterize the contaminant plume configuration and movement, which requires an understanding of the geological and hydrogeologic controls on groundwater movement as well as the nature and extent of any remaining carbon tetrachloride source in the soils. The ESC program uses a multidisciplinary technical approach that incorporates geology, geochemistry, geohydrology, and geophysics. Field activities include sampling, chemical analysis, and borehole and surface geophysical surveys.

  19. Nitrate Biogeochemistry and Reactive Transport in California Groundwater: LDRD Final Report

    SciTech Connect (OSTI)

    Esser, B K; Beller, H; Carle, S; Cey, B; Hudson, G B; Leif, R; LeTain, T; Moody-Bartel, C; Moore, K; McNab, W; Moran, J; Tompson, A

    2006-02-24

    Nitrate is the number one drinking water contaminant in the United States. It is pervasive in surface and groundwater systems,and its principal anthropogenic sources have increased dramatically in the last 50 years. In California alone, one third of the public drinking-water wells has been lost since 1988 and nitrate contamination is the most common reason for abandonment. Effective nitrate management in groundwater is complicated by uncertainties related to multiple point and non-point sources, hydrogeologic complexity, geochemical reactivity, and quantification of denitrification processes. In this paper, we review an integrated experimental and simulation-based framework being developed to study the fate of nitrate in a 25 km-long groundwater subbasin south of San Jose, California, a historically agricultural area now undergoing rapid urbanization with increasing demands for groundwater. The modeling approach is driven by a need to integrate new and archival data that support the hypothesis that nitrate fate and transport at the basin scale is intricately related to hydrostratigraphic complexity, variability of flow paths and groundwater residence times, microbial activity, and multiple geochemical reaction mechanisms. This study synthesizes these disparate and multi-scale data into a three-dimensional and highly resolved reactive transport modeling framework.

  20. Beneficial effects of groundwater entry into liquid-dominated geothermal systems

    SciTech Connect (OSTI)

    Lippmann, M.J. ); Truesdell, A.H. )

    1990-04-01

    In all active liquid-dominated geothermal systems there is continuous circulation of mass and transfer of heat, otherwise they would slowly cool and fade away. In the natural state these systems are in dynamic equilibrium with the surrounding colder groundwater aquifers. The ascending geothermal fluids cool conductively, boil, or mix with groundwaters, and ultimately may discharge at the surface as fumaroles or hot springs. With the start of fluid production and the lowering of reservoir pressure, the natural equilibrium is disrupted and cooler groundwater tends to enter the reservoir. Improperly constructed or damaged wells, and wells located near the margins of the geothermal system, exhibit temperature reductions (and possibly scaling from mixing of chemically distinct fluids) as the cooler-water moves into the reservoir. These negative effects, especially in peripheral wells are, however, compensated by the maintenance of reservoir pressure and a reduction in reservoir boiling that might result in mineral precipitation in the formation pores and fractures. The positive effect of cold groundwater entry on the behavior of liquid-dominated system is illustrated by using simple reservoir models. The simulation results show that even though groundwater influx into the reservoir causes cooling of fluids produced from wells located near the cold-water recharge area, it also reduces pressure drawdown and boiling in the exploited zone, and sweeps the heat stored in the reservoir rocks toward production wells, thus increasing the productive life of the wells and field. 9 refs.

  1. Water balance in the Amazon basin from a land surface model ensemble

    SciTech Connect (OSTI)

    Getirana, Augusto; Dutra, Emanuel; Guimberteau, Matthieu; Kam, Jonghun; Li, Hongyi; Decharme, Bertrand; Zhang, Zhengqiu J.; Ducharne, Agnes; Boone, Aaron; Balsamo, Gianpaolo; Rodell, Matthew; Mounirou Toure, Ally; Xue, Yongkang; Peters-Lidard, Christa D.; Kumar, Sujay V.; Arsenault, Kristi Rae; Drapeau, Guillaume; Leung, Lai-Yung R.; Ronchail, Josyane; Sheffield, Justin

    2014-12-06

    Despite recent advances in modeling and remote sensing of land surfaces, estimates of the global water budget are still fairly uncertain. The objective of this study is to evaluate the water budget of the Amazon basin based on several state-of-the-art land surface model (LSM) outputs. Water budget variables [total water storage (TWS), evapotranspiration (ET), surface runoff (R) and baseflow (B)] are evaluated at the basin scale using both remote sensing and in situ data. Fourteen LSMs were run using meteorological forcings at a 3-hourly time step and 1-degree spatial resolution. Three experiments are performed using precipitation which has been rescaled to match monthly global GPCP and GPCC datasets and the daily HYBAM dataset for the Amazon basin. R and B are used to force the Hydrological Modeling and Analysis Platform (HyMAP) river routing scheme and simulated discharges are compared against observations at 165 gauges. Simulated ET and TWS are compared against FLUXNET and MOD16A2 evapotranspiration, and GRACE TWS estimates in different catchments. At the basin scale, simulated ET ranges from 2.39mm.d-1 to 3.26mm.d-1 and a low spatial correlation between ET and P indicates that evapotranspiration does not depend on water availability over most of the basin. Results also show that other simulated water budget variables vary significantly as a function of both the LSM and precipitation used, but simulated TWS generally agree at the basin scale. The best water budget simulations resulted from experiments using the HYBAM dataset, mostly explained by a denser rainfall gauge network the daily rescaling.

  2. Groundwater Open House! THE SCIENCE CONTINUES The Science Continues

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Welcome to the Groundwater Open House! THE SCIENCE CONTINUES The Science Continues As part of a long-term monitoring program, ongoing scientific studies will continue into the future to identify where contaminated groundwater is located, in which direction it flows and its rate of movement. Find the latest data on posters marked with this symbol. YOUR WATER IS SAFE The Groundwater is Safe Public water supply is safe from the impacts of historic underground nuclear testing. Current research

  3. Numerical Simulation of Groundwater Withdrawal at the Nevada Test Site

    SciTech Connect (OSTI)

    Carroll, Rosemary; Giroux, Brian; Pohll, Greg; Hershey, Ronald; Russell, Charles; Howcroft, William

    2004-01-28

    Alternative uses of the Nevada Test Site (NTS) may require large amounts of water to construct and/or operate. The only abundant source of water at the NTS is groundwater. This report describes preliminary modeling to quantify the amount of groundwater available for development from three hydrographic areas at the NTS. Modeling was conducted with a three-dimensional transient numerical groundwater flow model.

  4. UMTRA water sampling and analysis plan, Green River, Utah

    SciTech Connect (OSTI)

    Papusch, R.

    1993-12-01

    The purpose of this water sampling and analysis plan (WSAP) is to provide a basis for groundwater and surface water sampling at the Green River Uranium Mill Tailing Remedial Action (UMTRA) Project site. This WSAP identifies and justifies the sampling locations, analytical parameters, detection limits, and sampling frequency for the monitoring locations.

  5. Tuning the interaction between propagating and localized surface plasmons for surface enhanced Raman scattering in water for biomedical and environmental applications

    SciTech Connect (OSTI)

    Shioi, Masahiko; Jans, Hilde; Lodewijks, Kristof; Van Dorpe, Pol; Lagae, Liesbet; Kawamura, Tatsuro

    2014-06-16

    With a view to biomedical and environmental applications, we investigate the plasmonic properties of a rectangular gold nanodisk array in water to boost surface enhanced Raman scattering (SERS) effects. To control the resonance wavelengths of the surface plasmon polariton and the localized surface plasmon, their dependence on the array period and diameter in water is studied in detail using a finite difference time domain method. A good agreement is obtained between calculated resonant wavelengths and those of gold nanodisk arrays fabricated using electron beam lithography. For the optimized structure, a SERS enhancement factor of 7.8 × 10{sup 7} is achieved in water experimentally.

  6. Surface modification of cellulose acetate membrane using thermal annealing to enhance produced water treatment

    SciTech Connect (OSTI)

    Kusworo, T. D. Aryanti, N. Firdaus, M. M. H.; Sukmawati, H.

    2015-12-29

    This study is performed primarily to investigate the effect of surface modification of cellulose acetate using thermal annealing on the enhancement of membrane performance for produced water treatment. In this study, Cellulose Acetate membranes were casted using dry/wet phase inversion technique. The effect of additive and post-treatment using thermal annealing on the membrane surface were examined for produced water treatment. Therma annealing was subjected to membrane surface at 60 and 70 °C for 5, 10 and 15 second, respectively. Membrane characterizations were done using membrane flux and rejection with produced water as a feed, Scanning Electron Microscopy (SEM) and Fourier Transform Infra Red (FTIR) analysis. Experimental results showed that asymmetric cellulose acetate membrane can be made by dry/wet phase inversion technique. The results from the Scanning Electron Microscopy (FESEM) analysis was also confirmed that polyethylene glycol as additivie in dope solution and thermal annealing was affected the morphology and membrane performance for produced water treatment, respectively. Scanning electron microscopy micrographs showed that the selective layer and the substructure of membrane became denser and more compact after the thermal annealing processes. Therefore, membrane rejection was significantly increased while the flux was slighty decreased, respectively. The best membrane performance is obtained on the composition of 18 wt % cellulose acetate, poly ethylene glycol 5 wt% with thermal annealing at 70° C for 15 second.

  7. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and September 2013 Groundwater and Surface Water Sampling at the Durango, Colorado, Disposal and Processing Sites March 2014 LMS/DUD/DUP/S00613 This page intentionally left blank U.S. Department of Energy DVP-June and September 2013, Durango, Colorado March 2014 RIN 13055370 and 13085577 Page i Contents Sampling Event Summary ...............................................................................................................1 Durango, Colorado, Disposal Site Sample Location Map-June

  8. The Hanford Story: Groundwater

    Broader source: Energy.gov [DOE]

    This second chapter of The Hanford Story explains how more than 100 square miles of groundwater under the Hanford Site became contaminated and what workers are doing to restore groundwater to its highest beneficial use.

  9. Nevada National Security Site Groundwater Program

    ScienceCinema (OSTI)

    None

    2014-10-28

    From 1951 to 1992, the Unites States government conducted 828 underground nuclear tests at the Nevada National Security Site. About one-third of these tests occurred near, below or within the water table - the very top portion of the groundwater layer where rock and soil are completely saturated with water. As a result, some groundwater was contaminated. The U.S. Department of Energy (DOE) began exploring the effects of groundwater contamination in the 1970s. Though contamination from underground testing has never been detected on public land, the DOE was committed to developing an advanced, reliable monitoring network that ensures the long-term protection of the public. An intensive groundwater investigation program was launched in 1989.

  10. Watershed response and land energy feedbacks under climate change depend upon groundwater.

    SciTech Connect (OSTI)

    Maxwell, R M; Kollet, S J

    2008-06-10

    Human induced climate change will have a significant impact on the hydrologic cycle, creating changes in fresh water resources, land cover, and feedbacks that are difficult to characterize, which makes it an issue of global importance. Previous studies have not included subsurface storage in climate change simulations and feedbacks. A variably-saturated groundwater flow model with integrated overland flow and land surface model processes is used to examine the interplay between coupled water and energy processes under climate change conditions. A case study from the Southern Great Plains (SGP) USA, an important agricultural region that is susceptible to drought, is used as the basis for three scenarios simulations using a modified atmospheric forcing dataset to reflect predicted effects due to human-induced climate change. These scenarios include an increase in the atmospheric temperature and variations in rainfall amount and are compared to the present-day climate case. Changes in shallow soil saturation and groundwater levels are quantified as well as the corresponding energy fluxes at the land surface. Here we show that groundwater and subsurface lateral flow processes are critical in understanding hydrologic response and energy feedbacks to climate change and that certain regions are more susceptible to changes in temperature, while others to changes in precipitation. This groundwater control is critical for understanding recharge and drought processes, possible under future climate conditions.

  11. UMTRA project technical assistance contractor quality assurance implementation plan for surface and ground water

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The Uranium Mill Tailings Remedial Action (UMTRA) Project Technical Assistance Contractor (TAC) Quality Assurance Implementation Plan (QAIP) outlines the primary requirements for integrating quality functions for TAC technical activities applied to the surface and ground water phases of the UMTRA Project. The QAIP is subordinate to the latest issue of the UMTRA Project TAC Quality Assurance Program Plan (QAPP). The QAIP addresses technical aspects of the TAC UMTRA Project surface and ground water programs. The QAIP is authorized and approved by the TAC Project Manager and QA manager. The QA program is designed to use monitoring, audit, and surveillance functions as management tools to ensure that all Project organization activities are carried out in a manner that will protect public health and safety, promote the success of the UMTRA Project and meet or exceed contract requirements.

  12. X-701B Groundwater Remedy Portsmouth Ohio

    Office of Environmental Management (EM)

    X-701B Groundwater Remediation ETR Report Date: December 2008 ETR-20 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the X-701B Groundwater Remedy, Portsmouth, Ohio Why DOE-EM Did This Review The Department of Energy (DOE) Portsmouth Paducah Project Office (PPPO) has responsibility for remediation of the X-701B ground water plume with the key contaminant of trichloroethene (TCE). The remedy has been divided into four phases: Phase I-

  13. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    SciTech Connect (OSTI)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  14. Calendar Year 2002 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2003-03-31

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2002 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2002 monitoring data were obtained from groundwater and surface water sampling locations in three hydrogeologic regimes at Y-12. The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge south of Y-12. The sections of this report provide details regarding the CY 2002 groundwater and surface water monitoring activities in the Bear Creek, East Fork, and Chestnut Ridge Regimes. Section 2 describes the monitoring programs implemented by the Y-12 GWPP and BJC during CY 2002. Section 3 identifies the sampling locations in each hydrogeologic regime and the corresponding sampling frequency during CY 2002, along with the associated quality assurance/quality control (QA/QC) sampling. Section 4 describes groundwater and surface water sample collection and Section 5 identifies the field measurements and laboratory analytes for each sampling location. Section 6 outlines the data management protocols and data quality objectives (DQOs). Section 7 describes the groundwater elevation monitoring in each regime during CY 2002 and Section 8 lists the documents cited for more detailed operational, regulatory, and technical information.

  15. Raman spectroscopy of solutions and interfaces containing nitrogen dioxide, water, and 1,4 dioxane: Evidence for repulsion of surface water by NO{sub 2} gas

    SciTech Connect (OSTI)

    Murdachaew, Garold; Varner, Mychel E.; Veer, Wytze E. van der; Gerber, R. Benny; Phillips, Leon F.

    2014-05-14

    The interaction of water, 1,4 dioxane, and gaseous nitrogen dioxide, has been studied as a function of distance measured through the liquid-vapour interface by Raman spectroscopy with a narrow (<0.1 mm) laser beam directed parallel to the interface. The Raman spectra show that water is present at the surface of a dioxane-water mixture when gaseous NO{sub 2} is absent, but is virtually absent from the surface of a dioxane-water mixture when gaseous NO{sub 2} is present. This is consistent with recent theoretical calculations that show NO{sub 2} to be mildly hydrophobic.

  16. Calendar Year 2004 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    N /A

    2005-09-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2004 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2004 monitoring data were obtained from groundwater and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge south of Y-12. The CY 2004 monitoring data were obtained under the Y-12 Groundwater Protection Program (GWPP) managed by BWXT Y-12, L.L.C. (BWXT) and several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Data contained in this report meet applicable requirements of DOE Order 450.1 (Environmental Protection Program) regarding evaluation of groundwater and surface water quality in areas: (1) which are, or could be, affected by operations at Y-12 (surveillance monitoring); and (2) where contaminants from Y-12 are most likely to migrate beyond the boundaries of the ORR (exit pathway/perimeter monitoring). However, detailed analysis, evaluation, and interpretation of the CY 2004 monitoring data is deferred to the Y-12 Groundwater Protection Program Groundwater Monitoring Data Compendium (BWXT 2005). For each monitoring well, spring, and surface water sampling station included in this report, the GWPP Compendium provides: (1) pertinent well installation and construction information; (2) a complete sampling history, including sampling methods and

  17. Calendar Year 2005 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2006-09-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2005 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2005 monitoring data were obtained from groundwater and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge south of Y-12. The CY 2005 monitoring data were obtained under the Y-12 Groundwater Protection Program (GWPP) managed by BWXT Y-12, L.L.C. (BWXT) and several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Data contained in this report meet applicable requirements of DOE Order 450.1 (Environmental Protection Program) regarding evaluation of groundwater and surface water quality in areas: (1) which are, or could be, affected by operations at Y-12 (surveillance monitoring); and (2) where contaminants from Y-12 are most likely to migrate beyond the boundaries of the ORR (exit pathway/perimeter monitoring). However, detailed analysis, evaluation, and interpretation of the CY 2005 monitoring data is deferred to the ''Y-12 Groundwater Protection Program Groundwater Monitoring Data Compendium'' (BWXT 2006). For each monitoring well, spring, and surface water sampling station included in this report, the GWPP Compendium provides: (1) pertinent well installation and construction information; (2) a complete sampling history, including sampling methods and

  18. Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems (DE-EE0002961)

    SciTech Connect (OSTI)

    Spitler, J. D.; Culling, J. R.; Conjeevaram, K.; Ramesh, M.; Selvakumar, M.

    2012-11-30

    Ground-source heat pump (GSHP) systems are perhaps the most widely used “sustainable” heating and cooling systems, with an estimated 1.7 million installed units with total installed heating capacity on the order of 18 GW. They are widely used in residential, commercial, and institutional buildings. Standing column wells (SCW) are one form of ground heat exchanger that, under the right geological conditions, can provide excellent energy efficiency at a relatively low capital cost. Closed-loop surface water heat pump (SWHP) systems utilize surface water heat exchangers (SWHE) to reject or extract heat from nearby surface water bodies. For building near surface water bodies, these systems also offer a high degree of energy efficiency at a low capital cost. However, there have been few design tools available for properly sizing standing column wells or surface water heat exchangers. Nor have tools for analyzing the energy consumption and supporting economics-based design decisions been available. The main contributions of this project lie in providing new tools that support design and energy analysis. These include a design tool for sizing surface water heat exchangers, a design tool for sizing standing column wells, a new model of surface water heat pump systems implemented in EnergyPlus and a new model of standing column wells implemented in EnergyPlus. These tools will better help engineers design these systems and determine the economic and technical feasibility.

  19. Development of HUMASORB{trademark}, a lignite derived humic acid for removal of metals and organic contaminants from groundwater

    SciTech Connect (OSTI)

    Sanjay, H.G.; Srivastave, K.C.; Walia, D.S.

    1995-10-01

    Heavy metal and organic contamination of surface and groundwater systems is a major environmental concern. The contamination is primarily due to improperly disposed industrial wastes. The presence of toxic heavy metal ions, volatile organic compounds (VOCs) and pesticides in water is of great concern and could affect the safety of drinking water. Decontamination of surface and groundwater can be achieved using a broad spectrum of treatment options such as precipitation, ion-exchange, microbial digestion, membrane separation, activated carbon adsorption, etc. The state of the art technologies for treatment of contaminated water however, can in one pass remediate only one class of contaminants, i.e., either VOCs (activated carbon) or heavy metals (ion exchange). This would require the use of at a minimum, two different stepwise processes to remediate a site. The groundwater contamination at different Department of Energy (DOE) sites (e.g., Hanford) is due to the presence of both VOCs and heavy metals. The two-step approach increases the cost of remediation. To overcome the sequential treatment of contaminated streams to remove both organics and metals, a novel material having properties to remove both classes of contaminants in one step is being developed as part of this project.The objective of this project is to develop a lignite-derived adsorbent, Humasorb{sup TM} to remove heavy metals and organics from ground water and surface water streams.

  20. AUTOMATED WATER LEVEL MEASUREMENTS IN SMALL-DIAMETER AQUIFER TUBES

    SciTech Connect (OSTI)

    PETERSEN SW; EDRINGTON RS; MAHOOD RO; VANMIDDLESWORTH PE

    2011-01-14

    Groundwater contaminated with hexavalent chromium, strontium-90, and uranium discharges into the Columbia River along approximately 16 km (10 mi) of the shoreline. Various treatment systems have and will continue to be implemented to eliminate the impact of Hanford Site contamination to the river. To optimize the various remediation strategies, it is important to understand interactions between groundwater and the surface water of the Columbia River. An automated system to record water levels in aquifer sampling tubes installed in the hyporheic zone was designed and tested to (1) gain a more complete understanding of groundwater/river water interactions based on gaining and losing conditions ofthe Columbia River, (2) record and interpret data for consistent and defensible groundwater/surface water conceptual models that may be used to better predict subsurface contaminant fate and transport, and (3) evaluate the hydrodynamic influence of extraction wells in an expanded pump-and-treat system to optimize the treatment system. A system to measure water levels in small-diameter aquifer tubes was designed and tested in the laboratory and field. The system was configured to allow manual measurements to periodically calibrate the instrument and to permit aquifer tube sampling without removing the transducer tube. Manual measurements were collected with an e-tape designed and fabricated especially for this test. Results indicate that the transducer system accurately records groundwater levels in aquifer tubes. These data are being used to refine the conceptual and numeric models to better understand interactions in the hyporheic zone of the Columbia River and the adjacent river water and groundwater, and changes in hydrochemistry relative to groundwater flux as river water recharges the aquifer and then drains back out in response to changes in the river level.

  1. Appendix K Disposal Cell Groundwater Monitoring Plan

    Office of Legacy Management (LM)

    K Disposal Cell Groundwater Monitoring Plan

  2. East Maui Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for East Maui. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume V – Island of Maui Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.

  3. Hawaii Island Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for Hawaii Island. Data is from the following sources: Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume II – Island of Hawaii Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008; and Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014.

  4. West Maui Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for West Maui. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume V – Island of Maui Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.

  5. West Maui Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for West Maui. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report Volume V Island of Maui Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.

  6. Influences of Peat, Surface and Subsurface Water, and Snow on Active Layer Thickness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Atchley, Adam; Coon, Ethan T.; Painter, Scott L; Harp, Dylan; Wilson, Cathy

    2016-01-01

    The effect of three environmental conditions: 1) thickness of organic soil, 2) snow depth, and 3) soil moisture content or water table height above and below the soil surface, on active layer thickness (ALT) are investigated using an ensemble of 1D thermal hydrology models. Sensitivity analyses of the ensemble exposed the isolated influence of each environmental condition on ALT and their multivariate interactions. The primary and interactive influences are illustrated in the form of color maps of ALT change. Results show that organic layer acts as a strong insulator, and its thickness is the dominant control of ALT, but themore » strength of the effect of organic layer thickness is dependent on the saturation state. Snow depth, subsurface saturation, and ponded water depth are strongly codependent and positively correlated to ALT.« less

  7. Calendar Year 2006 Groundwater Monitoring Report, U.S Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    N /A

    2007-09-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2006 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2006 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12 (Figure A.1). The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2006 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by BWXT Y-12, L.L.C. (BWXT), and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., preparing SAPs, coordinating sample collection, and sharing data) ensures that the CY 2006 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the groundwater and

  8. UMTRA project technical assistance contractor quality assurance implementation plan for surface and ground water, Revision 2

    SciTech Connect (OSTI)

    1995-11-01

    This document contains the Technical Assistance Contractor (TAC) Quality Assurance Implementation Plan (QAIP) for the Uranium Mill Tailings Remedial Action (UMTRA) Project. The QAIP outlines the primary requirements for integrating quality functions for TAC technical activities applied to the surface and ground water phases of the UMTRA Project. The QA program is designed to use monitoring, audit, and surveillance activities as management tools to ensure that UMTRA Project activities are carried out in amanner to protect public health and safety, promote the success of the UMTRA Project, and meet or exceed contract requirements.

  9. Quantifying the impacts of land surface schemes and dynamic vegetation on the model dependency of projected changes in surface energy and water budgets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Miao; Wang, Guiling; Chen, Haishan

    2016-03-01

    Assessing and quantifying the uncertainties in projected future changes of energy and water budgets over land surface are important steps toward improving our confidence in climate change projections. In our study, the contribution of land surface models to the inter-GCM variation of projected future changes in land surface energy and water fluxes are assessed based on output from 19 global climate models (GCMs) and offline Community Land Model version 4 (CLM4) simulations driven by meteorological forcing from the 19 GCMs. Similar offline simulations using CLM4 with its dynamic vegetation submodel are also conducted to investigate how dynamic vegetation feedback, amore » process that is being added to more earth system models, may amplify or moderate the intermodel variations of projected future changes. Projected changes are quantified as the difference between the 2081–2100 period from the Representative Concentration Pathway 8.5 (RCP8.5) future experiment and the 1981–2000 period from the historical simulation. Under RCP8.5, projected changes in surface water and heat fluxes show a high degree of model dependency across the globe. Although precipitation is very likely to increase in the high latitudes of the Northern Hemisphere, a high degree of model-related uncertainty exists for evapotranspiration, soil water content, and surface runoff, suggesting discrepancy among land surface models (LSMs) in simulating the surface hydrological processes and snow-related processes. Large model-related uncertainties for the surface water budget also exist in the Tropics including southeastern South America and Central Africa. Moreover, these uncertainties would be reduced in the hypothetical scenario of a single near-perfect land surface model being used across all GCMs, suggesting the potential to reduce uncertainties through the use of more consistent approaches toward land surface model development. Under such a scenario, the most significant reduction is likely to

  10. Effect of Cu2+ Activation on Interfacial Water Structure at the Sphalerite Surface as Studied by Molecular Dynamics Simulation

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.; Wick, Collin D.

    2015-12-10

    In the first part of this paper, an experimental contact angle study of the fresh and Cu2+ activated sphalerite-ZnS surface as well as the covellite-CuS (001) surface is reported describing the increased hydrophobic character of the surface during Cu2+ activation. In addition to these experimental results, the fresh sphalerite-ZnS (110), copper-zinc sulfide-CuZnS2 (110), villamaninite- CuS2 (100), and covellite-CuS (001) surfaces were examined using Molecular Dynamics Simulation (MDS). Our MDS results on the behavior of interfacial water at the fresh sphalerite-ZnS (110), copper-zinc sulfide-CuZnS2 (110), villamaninite-CuS2 (100), and covellite-CuS (001) surfaces include simulated contact angles, water number density distribution, water dipole orientation, water residence time, and hydrogen-bonding considerations. The copper content at the Cu2+ activated sphalerite surface seems to account for the increased hydrophobicity as revealed by both experimental and MD simulated contact angle measurements. The relatively greater hydrophobic character developed at the Cu2+ activated sphalerite surface and at the copper-zinc sulfide surface has been described by MDS, based on the structure of interfacial water and its dynamic properties. L.X.D. acknowledges funding from the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  11. Groundwater Monitoring Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    92 natural sources, 102 regional aquifer wells, 41 intermediate-depth wells and springs, and 67 wells in alluvium in canyons. August 1, 2013 Map of LANL's groundwater...

  12. Assessment of potential impacts of major groundwater contaminants to fall chinook salmon (Oncorhynchus tshawytscha) in the Hanford Reach, Columbia River

    SciTech Connect (OSTI)

    Geist, D.R.; Poston, T.M.; Dauble, D.D.

    1994-10-01

    Past operations of Hanford Site facilities have contaminated the groundwater adjacent to the Hanford Reach of the Columbia River, Washington, with various chemical and radiological constituents. The groundwater is hydraulically connected to the river and contains concentrations of contaminants that sometimes exceed federal and/or state drinking water standards or standards for the protection of aquatic life. For example, concentrations of chromium in shoreline seeps and springs at most 100 Area operable units exceed concentrations found to be toxic to fish. Nitrate and tritium concentrations in shoreline seeps are generally below drinking water standards and concentrations potentially toxic to aquatic life, but nitrate concentrations may be high enough to synergistically interact with and exacerbate chromium toxicity. The Hanford Reach also supports the largest run of fall chinook salmon (Oncorhynchus tshawytscha) in the Columbia River Basin. Numbers of fall chinook salmon returning to the Hanford Reach have increased relative to other mainstem populations during the last 30 years. Groundwater discharge appears to occur near some salmon spawning areas, but contaminants are generally not detectable in surface water samples. The concentration and potential toxicity of contaminants in the interstitial waters of the substrate where fall chinook salmon embryogenesis occurs are presently unknown. New tools are required to characterize the extent of groundwater contaminant discharge to the Hanford Reach and to resolve uncertainties associated with assessment of potential impacts to fall chinook salmon.

  13. Evaluation of surface water treatment and discharge options for the Weldon Spring Site Remedial Action Project

    SciTech Connect (OSTI)

    Goyette, M.L.; MacDonell, M.M.

    1992-09-01

    The US Department of Energy (DOE), under its Environmental Restoration and Waste Management Program, is responsible for conducting response actions at the Weldon Spring site in St. Charles County, Missouri. The site consists of two noncontiguous areas: (1) the chemical plant area, which includes four raffinate pits and two small ponds, and (2) a 3.6-ha (9-acre) quarry located about 6.4 km (4 mi) southwest of the chemical plant area. Both of these areas became chemically and radioactively contaminated as a result of processing and disposal activities that took place from the 1940s through 1960s. The Weldon Spring site, located about 48 km (30 mi) west of St. Louis, is listed on the National Priorities List of the US Environmental Protection Agency. Nitroaromatic explosives were processed by the Army at the chemical plant area during the 1940s, and radioactive materials were processed by DOE`s predecessor agency (the Atomic Energy Commission) during the 1950s and 1960s. Overall remediation of the Weldon Spring site is being addressed through the Weldon Spring Site Remedial Action Project, and it consists of several components. One component is the management of radioactively and chemically contaminated surface water impoundments at the chemical plant area -- i.e., the four raffinate pits, Frog Pond, and Ash Pond which was addressed under a separate action and documented in an engineering evaluation/cost analysis report. This report discusses the evaluation of surface water treatment at the Weldon Spring site.

  14. TRITIUM UNCERTAINTY ANALYSIS FOR SURFACE WATER SAMPLES AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Atkinson, R.

    2012-07-31

    Radiochemical analyses of surface water samples, in the framework of Environmental Monitoring, have associated uncertainties for the radioisotopic results reported. These uncertainty analyses pertain to the tritium results from surface water samples collected at five locations on the Savannah River near the U.S. Department of Energy's Savannah River Site (SRS). Uncertainties can result from the field-sampling routine, can be incurred during transport due to the physical properties of the sample, from equipment limitations, and from the measurement instrumentation used. The uncertainty reported by the SRS in their Annual Site Environmental Report currently considers only the counting uncertainty in the measurements, which is the standard reporting protocol for radioanalytical chemistry results. The focus of this work is to provide an overview of all uncertainty components associated with SRS tritium measurements, estimate the total uncertainty according to ISO 17025, and to propose additional experiments to verify some of the estimated uncertainties. The main uncertainty components discovered and investigated in this paper are tritium absorption or desorption in the sample container, HTO/H{sub 2}O isotopic effect during distillation, pipette volume, and tritium standard uncertainty. The goal is to quantify these uncertainties and to establish a combined uncertainty in order to increase the scientific depth of the SRS Annual Site Environmental Report.

  15. Surface water drainage system. Environmental assessment and finding of no significant impact

    SciTech Connect (OSTI)

    1996-05-01

    This Environmental Assessment (EA) is written pursuant to the National Environmental Policy Act (NEPA). The document identifies and evaluates the action proposed to correct deficiencies in, and then to maintain, the surface water drainage system serving the Department of Energy`s Rocky Flats Environmental Technology Site (Site), located north of Golden, Colorado. Many of the activities proposed would not normally be subject to this level of NEPA documentation. However, in many cases, maintenance of the system has been deferred to the point that wetlands vegetation has become established in some ditches and culverts, creating wetlands. The proposed activities would damage or remove some of these wetlands in order to return the drainage system to the point that it would be able to fully serve its intended function - stormwater control. The Department of Energy (DOE) regulations require that activities affecting environmentally sensitive areas like wetlands be the subject of an EA. Most portions of the surface water drainage system are presently inadequate to convey the runoff from a 100-year storm event. As a result, such an event would cause flooding across much of the Site and possibly threaten the integrity of the dams at the terminal ponds. Severe flooding would not only cause damage to facilities and equipment, but could also facilitate the transport of contaminants from individual hazardous substance sites (IHSSs). Uncontrolled flow through the A- and B-series ponds could cause contaminated sediments to become suspended and carried downstream. Additionally, high velocity flood flows significantly increase erosion losses.

  16. Calendar Year 2009 Groundwater Monitoring Report, U.S. Department of Energy, Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Elvado Environmental LLC

    2010-12-01

    This report contains the groundwater and surface water monitoring data that were obtained during calendar year (CY) 2009 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (hereafter referenced as Y-12) on the DOE Oak Ridge Reservation (ORR) in Oak Ridge, Tennessee. The CY 2009 monitoring data were obtained from wells, springs, and surface water sampling locations in three hydrogeologic regimes at Y-12. The Bear Creek Hydrogeologic Regime (Bear Creek Regime) encompasses a section of Bear Creek Valley (BCV) between the west end of Y-12 and the west end of the Bear Creek Watershed (directions are in reference to the Y-12 grid system). The Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime) encompasses the Y-12 industrial facilities and support structures in BCV. The Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime) encompasses a section of Chestnut Ridge directly south of Y-12. Section 2 of this report provides background information pertinent to groundwater and surface water quality monitoring in each hydrogeologic regime, including the topography and bedrock geology, surface water drainage, groundwater system, and extent of groundwater contamination. The CY 2009 groundwater and surface water monitoring data in this report were obtained from sampling and analysis activities implemented under the Y-12 Groundwater Protection Program (GWPP) managed by Babcock & Wilcox Technical Services Y-12, LLC (B&W Y-12) and from sampling and analysis activities implemented under several monitoring programs managed by Bechtel Jacobs Company LLC (BJC). Cooperative implementation of the monitoring programs directed by the Y-12 GWPP and BJC (i.e., coordinating sample collection and sharing data) ensures that the CY 2009 monitoring results fulfill requirements of all the applicable monitoring drivers with no duplication of sampling and analysis efforts. Section 3 of this report contains a summary of information regarding the groundwater and

  17. Appendix B Ground Water Management Policy

    Office of Legacy Management (LM)

    Ground Water Management Policy for the Monticello Mill Tailings Site and Adjacent Areas ... OF NATURAL RESOURCES DIVISION OF WATER RIGHTS Ground-Water Management Policy for ...

  18. Projected Changes in Mean and Interannual Variability of Surface Water over Continental China

    SciTech Connect (OSTI)

    Leng, Guoyong; Tang, Qiuhong; Huang, Maoyi; Hong, Yang; Leung, Lai-Yung R.

    2015-05-01

    Five General Circulation Model (GCM) climate projections under the RCP8.5 emission scenario were used to drive the Variable Infiltration Capacity (VIC) hydrologic model to investigate the impacts of climate change on hydrologic cycle over continental China in the 21st century. The bias-corrected climatic variables were generated for the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR5) by the Inter-Sectoral Impact Model Intercomparison Project (ISI-MIP). Results showed much larger fractional changes of annual mean Evaportranspiration (ET) per unit warming than the corresponding fractional changes of Precipitation (P) per unit warming across the country especially for South China, which led to notable decrease of surface water variability (P-E). Specifically, negative trends for annual mean runoff up to -0.33%/decade and soil moisture trends varying between -0.02 to -0.13%/decade were found for most river basins across China. Coincidentally, interannual variability for both runoff and soil moisture exhibited significant positive trends for almost all river basins across China, implying an increase in extremes relative to the mean conditions. Noticeably, the largest positive trends for runoff variability and soil moisture variability, which were up to 38 0.41%/decade and 0.90%/decade, both occurred in Southwest China. In addition to the regional contrast, intra-seasonal variation was also large for the runoff mean and runoff variability changes, but small for the soil moisture mean and variability changes. Our results suggest that future climate change could further exacerbate existing water-related risks (e.g. floods and droughts) across China as indicated by the marked decrease of surface water amounts combined with steady increase of interannual variability throughout the 21st century. This study highlights the regional contrast and intra-seasonal variations for the projected hydrologic changes and could provide muti

  19. Molecular dynamics study of saltsolution interface: Solubility and surface charge of salt in water

    SciTech Connect (OSTI)

    Kobayashi, Kazuya; Liang, Yunfeng E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Sakka, Tetsuo

    2014-04-14

    The NaCl saltsolution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl saltsolution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a saltsolution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  20. Groundwater Level Status Report for Fiscal Year 2007 - Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Shannon P. Allen, Richard J. Koch

    2008-03-17

    The status of groundwater level monitoring at Los Alamos National Laboratory in Fiscal Year 2007 is provided in this report. The Groundwater Level Monitoring Project was instituted in 2005 to provide a framework for the collection and processing of quality controlled groundwater level data. This report summarizes groundwater level data for 166 monitoring wells, including 45 regional aquifer wells, 25 intermediate wells, and 96 alluvial wells, and 11 water supply wells. Pressure transducers were installed in 133 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well.

  1. Correlation of Oil-Water and Air-Water Contact Angles of Diverse Silanized Surfaces and Relationship to Fluid Interfacial Tensions

    SciTech Connect (OSTI)

    Grate, Jay W.; Dehoff, Karl J.; Warner, Marvin G.; Pittman, Jonathan W.; Wietsma, Thomas W.; Zhang, Changyong; Oostrom, Martinus

    2012-02-24

    The use of air-water, {Theta}{sub wa}, or air-liquid contact angles is customary in surface science, while oil-water contact angles {Theta}{sub ow}, are of paramount importance in subsurface multiphase flow phenomena including petroleum reocovery, nonaqueous phase liquid fate and transport, and geological carbon sequestration. In this paper we determine both the air-water and oil-water contact angles of silica surfaces modified with a diverse selection of silanes, using hexadecane as the oil. The silanes included alkylsilanes, alkylarylsilanes, and silanes with alkyl or aryl groups that are functionalized with heteroatoms such as N, O, and S. These silanes yielded surfaces with wettabilities from water-wet to oil wet, including specific silanized surfaces functionalized with heteroatoms that yield intermediate wet surfaces. The oil-water contact angles for clean and silanized surfaces, excluding one partially fluorinated surface, correlate linearly with air-water contact angles with a slope of 1.41 (R = 0.981, n = 13). These data were used to examine a previously untested theoretical treatment relating air-water and oil-water contact angles in terms of fluid interfacial energies. Plotting the cosines of these contact angles against one another, we obtain a linear relationship in excellent agreement with the theoretical treatment; the data fit cos {Theta}{sub ow} = 0.667 cos {Theta}{sub ow} + 0.384 (R = 0.981, n = 13), intercepting cos {Theta}{sub ow} = -1 at -0.284. The theoretical slope, based on the fluid interfacial tensions {Theta}{sub wa}, {Theta}{sub ow}, and {Theta}{sub oa}, is 0.67. We also demonstrate how silanes can be used to alter the wettability of the interior of a pore network micromodel device constructed in silicon/silica with a glass cover plate. Such micromodels are used to study multiphase flow phenomena. The contact angle of the resulting interior was determined in situ. An intermediate wet micromodel gave a contact angle in excellent agreement

  2. Nevada National Security Site 2014 Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site

    SciTech Connect (OSTI)

    Hudson, David

    2015-02-19

    This report is a compilation of the groundwater sampling results from the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada National Security Site, Nye County, Nevada. Groundwater samples from the aquifer immediately below the Area 5 RWMS have been collected and analyzed and static water levels have been measured in this aquifer since 1993. This report updates these data to include the 2014 results. Analysis results for leachate contaminants collected from the mixed-waste cell at the Area 5 RWMS (Cell 18) are also included. During 2014, groundwater samples were collected and static water levels were measured at three wells surrounding the Area 5 RWMS. Groundwater samples were collected at wells UE5PW-1, UE5PW-2, and UE5PW-3 on March 11 and August 12, 2014, and static water levels were measured at each of these wells on March 10, June 2, August 11, and October 14, 2014. Groundwater samples were analyzed for the following indicators of contamination: pH, specific conductance, total organic carbon, total organic halides, and tritium. General water chemistry (cations and anions) was also measured. Results from samples collected in 2014 are within the limits established by agreement with the Nevada Division of Environmental Protection for each analyte. The data from the shallow aquifer indicate that there has been no measurable impact to the uppermost aquifer from the Area 5 RWMS, and there were no significant changes in measured groundwater parameters compared to previous years. Leachate from above the primary liner of Cell 18 drains into a sump and is collected in a tank at the ground surface. Cell 18 began receiving waste in January 2011. Samples were collected from the tank when the leachate volume approached the 3,000-gallon tank capacity. Leachate samples have been collected 16 times since January 2011. During 2014, samples were collected on February 25, March 5, May 20, August 12, September 16, November 11, and December 16. Each leachate sample was

  3. Situ treatment of contaminated groundwater

    DOE Patents [OSTI]

    McNab, Jr., Walt W.; Ruiz, Roberto; Pico, Tristan M.

    2001-01-01

    A system for treating dissolved halogenated organic compounds in groundwater that relies upon electrolytically-generated hydrogen to chemically reduce the halogenated compounds in the presence of a suitable catalyst. A direct current is placed across at least a pair, or an array, of electrodes which are housed within groundwater wells so that hydrogen is generated at the cathode and oxygen at the anode. A pump is located within the well housing in which the cathode(s) is(are) located and draws in groundwater where it is hydrogenated via electrolysis, passes through a well-bore treatment unit, and then transported to the anode well(s) for reinjection into the ground. The well-bore treatment involves a permeable cylinder located in the well bore and containing a packed bed of catalyst material that facilitates the reductive dehalogenation of the halogenated organic compounds by hydrogen into environmentally benign species such as ethane and methane. Also, electro-osmatic transport of contaminants toward the cathode also contributes to contaminant mass removal. The only above ground equipment required are the transfer pipes and a direct circuit power supply for the electrodes. The electrode wells in an array may be used in pairs or one anode well may be used with a plurality of cathode wells. The DC current flow between electrode wells may be periodically reversed which controls the formation of mineral deposits in the alkaline cathode well-bore water, as well as to help rejuvenate the catalysis.

  4. Partial oxidation of landfill leachate in supercritical water: Optimization by response surface methodology

    SciTech Connect (OSTI)

    Gong, Yanmeng; Wang, Shuzhong; Xu, Haidong; Guo, Yang; Tang, Xingying

    2015-09-15

    Highlights: • Partial oxidation of landfill leachate in supercritical water was investigated. • The process was optimized by Box–Behnken design and response surface methodology. • GY{sub H2}, TRE and CR could exhibit up to 14.32 mmol·gTOC{sup −1}, 82.54% and 94.56%. • Small amounts of oxidant can decrease the generation of tar and char. - Abstract: To achieve the maximum H{sub 2} yield (GY{sub H2}), TOC removal rate (TRE) and carbon recovery rate (CR), response surface methodology was applied to optimize the process parameters for supercritical water partial oxidation (SWPO) of landfill leachate in a batch reactor. Quadratic polynomial models for GY{sub H2}, CR and TRE were established with Box–Behnken design. GY{sub H2}, CR and TRE reached up to 14.32 mmol·gTOC{sup −1}, 82.54% and 94.56% under optimum conditions, respectively. TRE was invariably above 91.87%. In contrast, TC removal rate (TR) only changed from 8.76% to 32.98%. Furthermore, carbonate and bicarbonate were the most abundant carbonaceous substances in product, whereas CO{sub 2} and H{sub 2} were the most abundant gaseous products. As a product of nitrogen-containing organics, NH{sub 3} has an important effect on gas composition. The carbon balance cannot be reached duo to the formation of tar and char. CR increased with the increase of temperature and oxidation coefficient.

  5. Paddy field, groundwater and land subsidence

    SciTech Connect (OSTI)

    Wen, L.J.

    1995-12-31

    Through many years of research and technical interchange both at home and abroad, it is commonly recognized that paddy fields possess the functions of micro-climate adjustment, flood detection and prevention, soil and water conservation, river-flow stabilization, soil salinization prevention, water purification, groundwater recharge, rural area beautification and environmental protection which are all beneficial to the public. In recent years, the global environmental problems have become a series concern throughout the world. These include the broken ozone layer, green house effects, acid rain, land desertion, tropical rain forest disappearing etc. Among them, rain forest disappearing draws great attention. Both rain forests and paddy fields are in tropical areas. They have similar functions and are disappearing because of economic pressure. This paper describes the special functions of paddy fields on water purification, ground water recharge and prevention of land subsidence, and reiterates groundwater utilization and land subsidence prevention measures. In view of the importance of groundwater resources, paddy fields, which can not be replaced by any other artificial groundwater recharge facilities, should not be reduced in acreage, nor can they be left idle. Paddy fields shall be properly maintained and managed in order to strengthen their special functions in the years to come even under heavy pressure from foreign countries.

  6. Polycyclic aromatic hydrocarbons in surface waters of Alessandria District, South Eastern Piedmont (Italy)

    SciTech Connect (OSTI)

    Trova, C.; Cossa, G.; Gandolfo, G.

    1992-10-01

    Polynuclear aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants. Because of the high toxicity of some polycyclic compounds, such as benzopyrenes, the determination of their levels in air, water, soil and aquatic organisms was the object of several papers. Anthropogenic pyrolitic and combustion processes, related to industrial plants, domestic heating, automobile traffic, are the major sources of these compounds; from these sources they enter atmospheric environment where their concentration is reduced by scavenging during precipitation events: rain, snow and fog in urban areas usually show high contents of PAHs. Dry and wet atmospheric polluted depositions effluents transport appreciable amounts of PAHs to aquatic environment, where they are rapidly taken up and accumulated by both fish and shellfish. Alessandria District, in South-Eastern Piedmont (Italy), lies in the middle of Torino-Milano-Genova industrial area: in addition to local sources, a relatively long range transport of polluted air masses may conduct to this region atmospheric contaminants, such as polynuclear compounds, that can enter fluvial environments through meteoric precipitation. The object of this work was to evaluate PAH content in surface waters flowing across the described territory. Samplings were carried on during winter season, when the concentration of these pollutants usually reaches the highest levels. 8 refs., 4 figs., 2 tabs.

  7. System for collecting products dumped on the surface of a mass of water

    SciTech Connect (OSTI)

    Carro, F.J.

    1982-06-01

    A system for collecting products dumped on the surface of a mass of water includes cages to be arranged at the sides of a tanker. Each cage is preferably prismatic in shape. The height of the cages is such that when the tanker is at ballast, the lower parts of the cages will be submerged while the upper parts will be above the maximum loading line of the tanker. The cages are fastened to the sides of the tanker by freely rotating connection points. In the interiors of the cages is housed a series of floating suction pump inlet members or housings, likewise prismatic in shape, having appropriate dimensions to permit a great sensitivity to the least fluctuating movements of the liquid surface. The complete face of each suction pump inlet member, which is oriented in the direction of travel of the tanker, is provided with an opening which has a height such that the lower edge thereof will be positioned below the floating line of the suction pumps at an approximate depth of 0.01 meter.

  8. Surface and bulk crystallization of amorphous solid water films: Confirmation of “top-down” crystallization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yuan, Chunqing; Smith, R. Scott; Kay, Bruce D.

    2016-01-11

    Here, the crystallization kinetics of nanoscale amorphous solid water (ASW) films are investigated using temperature-programmed desorption (TPD) and reflection absorption infrared spectroscopy (RAIRS). TPD measurements are used to probe surface crystallization and RAIRS measurements are used to probe bulk crystallization. Isothermal TPD results show that surface crystallization is independent of the film thickness (from 100 to 1000 ML). Conversely, the RAIRS measurements show that the bulk crystallization time increases linearly with increasing film thickness. These results suggest that nucleation and crystallization begin at the ASW/vacuum interface and then the crystallization growth front propagates linearly into the bulk. This mechanism wasmore » confirmed by selective placement of an isotopic layer (5% D2O in H2O) at various positions in an ASW (H2O) film. In this case, the closer the isotopic layer was to the vacuum interface, the earlier the isotopic layer crystallized. These experiments provide direct evidence to confirm that ASW crystallization in vacuum proceeds by a “top-down” crystallization mechanism.« less

  9. Results of groundwater monitoring and vegetation sampling at Everest, Kansas, in 2009 .

    SciTech Connect (OSTI)

    LaFreniere, L. M.; Environmental Science Division

    2010-05-13

    effectively, identified by the existing network of monitoring points and have not changed significantly during the CCC/USDA investigation program. The carbon tetrachloride distribution within the plume has continued to evolve, however, with relatively constant or apparently decreasing contaminant levels at most sampling locations. In response to these findings, the KDHE requested that the CCC/USDA develop a plan for annual monitoring of the groundwater and surface water at Everest, to facilitate continued tracking of the carbon tetrachloride plume at this site (KDHE 2009a). A recommendation for annual sampling (for analyses of VOCs) of 16 existing groundwater monitoring points within and near the identified contaminant migration pathway and surface water sampling at 5 locations along the intermittent creek west (downgradient) of the identified plume was presented by the CCC/USDA (Appendix A) and approved by the KDHE (2009b) for implementation. The monitoring wells will be sampled according to the low-flow procedure, and sample preservation, shipping, and analysis activities will be consistent with previous work at Everest. The annual sampling will continue until identified conditions at the site indicate a technical justification for a change. This report summarizes the results of sampling and monitoring activities conducted at the Everest site since completion of the April 2008 groundwater sampling event (Argonne 2008). The investigations performed during the current review period (May 2008 to October 2009) were as follows: (1) With one exception, the KDHE-approved groundwater and surface water monitoring points were sampled on April 24-27, 2009. In this event, well PT1 was inadvertently sampled instead of the adjacent well MW04. This investigation represents the first groundwater and surface water sampling event performed under the current plan for annual monitoring approved by the KDHE. (2) Ongoing monitoring of the groundwater levels at Everest is performed with KDHE

  10. Mapping water availability, projected use and cost in the western United States

    SciTech Connect (OSTI)

    Vincent C. Tidwell; Barbara D. Moreland; Katie M. Zemlick; Barry L. Roberts; Howard D. Passell; Daniel Jensen; Christopher Forsgren; Gerald Sehlke; Margaret A. Cook; Carey W. King

    2014-06-01

    New demands for water can be satisfied through a variety of source options. In some basins surface and/or groundwater may be available through permitting with the state water management agency (termed unappropriated water), alternatively water might be purchased and transferred out of its current use to another (termed appropriated water), or non-traditional water sources can be captured and treated (e.g., wastewater). The relative availability and cost of each source are key factors in the development decision. Unfortunately, these measures are location dependent with no consistent or comparable set of data available for evaluating competing water sources. With the help of western water managers, water availability was mapped for over 1200 watersheds throughout the western US. Five water sources were individually examined, including unappropriated surface water, unappropriated groundwater, appropriated water, municipal wastewater and brackish groundwater. Also mapped was projected change in consumptive water use from 2010 to 2030. Associated costs to acquire, convey and treat the water, as necessary, for each of the five sources were estimated. These metrics were developed to support regional water planning and policy analysis with initial application to electric transmission planning in the western US.

  11. Analysis of Ground-Water Levels and Associated Trends in Yucca Flat, Nevada Test Site, Nye County, Nevada, 1951-2003

    SciTech Connect (OSTI)

    J.M. Fenelon

    2005-10-05

    Almost 4,000 water-level measurements in 216 wells in the Yucca Flat area from 1951 to 2003 were quality assured and analyzed. An interpretative database was developed that describes water-level conditions for each water level measured in Yucca Flat. Multiple attributes were assigned to each water-level measurement in the database to describe the hydrologic conditions at the time of measurement. General quality, temporal variability, regional significance, and hydrologic conditions are attributed for each water-level measurement. The database also includes narratives that discuss the water-level history of each well. Water levels in 34 wells were analyzed for variability and for statistically significant trends. An attempt was made to identify the cause of many of the water-level fluctuations or trends. Potential causes include equilibration following well construction or development, pumping in the monitoring well, withdrawals from a nearby supply well, recharge from precipitation, earthquakes, underground nuclear tests, land subsidence, barometric pressure, and Earth tides. Some of the naturally occurring fluctuations in water levels may result from variations in recharge. The magnitude of the overall water-level change for these fluctuations generally is less than 2 feet. Long-term steady-state hydrographs for most of the wells open to carbonate rock have a very similar pattern. Carbonate-rock wells without the characteristic pattern are directly west of the Yucca and Topgallant faults in the southwestern part of Yucca Flat. Long-term steady-state hydrographs from wells open to volcanic tuffs or the Eleana confining unit have a distinctly different pattern from the general water-level pattern of the carbonate-rock aquifers. Anthropogenic water-level fluctuations were caused primarily by water withdrawals and nuclear testing. Nuclear tests affected water levels in many wells. Trends in these wells are attributed to test-cavity infilling or the effects of

  12. POSTCLOSURE GROUNDWATER REMEDIATION AND MONITORING AT THE SANITARY LANDFILL, SAVANNAH RIVER SITE TRANSITIONING TO MONITORED NATURAL ATTENUATION

    SciTech Connect (OSTI)

    Ross, J; Walt Kubilius, W; Thomas Kmetz, T; D Noffsinger, D; Karen M Adams, K

    2006-11-17

    Resource Conservation and Recovery Act (RCRA) requirements for hazardous waste facilities include 30 years of post-closure monitoring. The use of an objective-based monitoring strategy allows for a significant reduction in the amount of groundwater monitoring required, as the groundwater remediation transitions from an active biosparging system to monitored natural attenuation. The lifecycle of groundwater activities at the landfill has progressed from detection monitoring and plume characterization, to active groundwater remediation, and now to monitored natural attenuation and postclosure monitoring. Thus, the objectives of the groundwater monitoring have changed accordingly. Characterization monitoring evaluated what biogeochemical natural attenuation processes were occurring and determined that elevated levels of radium were naturally occurring. Process monitoring of the biosparging system required comprehensive sampling network up- and down-gradient of the horizontal wells to verify its effectiveness. Currently, the scope of monitoring and reporting can be significantly reduced as the objective is to demonstrate that the alternate concentration limits (ACL) are being met at the point of compliance wells and the maximum contaminant level (MCL) is being met at the surface water point of exposure. The proposed reduction is estimated to save about $2M over the course of the remaining 25 years of postclosure monitoring.

  13. ICDP Complex Groundwater Monitoring Plan REV 5

    SciTech Connect (OSTI)

    Cahn, L. S.

    2007-08-09

    This Groundwater Monitoring Plan, along with the Quality Assurance Project Plan for Waste Area Groups 1, 2, 3, 4, 5, 6, 7, 10, and Removal Actions, constitutes the sampling and analysis plan for groundwater and perched water monitoring at the Idaho CERCLA Disposal Facility (ICDF). A detection monitoring system was installed in the Snake River Plan Aquifer to comply with substantive requirements of "Releases from Solid Waste Management Units" of the Resource Conservation and Recovery Act. This detection monitoring wells constructed in the Snake River Plain Aquifer.

  14. Radionuclide release from PWR fuels in a reference tuff repository groundwater subsquently changed to Radionuclide release from PWR fuels in J-13 well water

    SciTech Connect (OSTI)

    Wilson, C.N.; Oversby, V.M.

    1985-04-01

    The Nevada Nuclear Waste Storage Investigations Project (NNWSI) is studying the suitability of the welded devitrified Topopah Spring tuff at Yucca Mountain, Nye County, Nevada, for potential use as a high level nuclear waste repository. In support of the Waste Package task of NNWSI, tests have been conducted under ambient air environment to measure radionuclide release from two pressurized water reactor (PWR) spent fuels in water obtained from the J-13 well near the Yucca Mountain site. Four specimen types, representing a range of fuel physical conditions that may exist in a failed waste canister containing a limited amount of water were tested. The specimen types were: (1) fuel rod sections split open to expose bare fuel particles; (2) rod sections with water-tight end fittings with a 2.5-cm long by 150-{mu}m wide slit through the cladding; (3) rod sections with water-tight end fittings and two 200-{mu}m diameter holes through the cladding; and (4) undefected rod segments with water-tight end fittings. Radionuclide release results from the first 223-day test runs on H.B. Robinson spent fuel specimens in J-13 water are reported and compared to results from a previous test series in which similar Turkey Point reactor spent fuel specimens were tested in deionized water. Selected initial results are also given for Turkey Point fuel specimens tested in J-13 water. Results suggest that the actinides Pu, Am, Cm and Np are released congruently with U as the UO{sub 2} spent fuel matrix dissolves. Fractional release of {sup 137}Cs and {sup 99}Tc was greater than that measured for the actinides. Generally, lower radionuclide releases were measured for the H.B. Robinson fuel in J-13 water than for Turkey Point Fuel in deionized water.

  15. Plan for Using Solar-Powered Jack Pumps to Sample Groundwater at the Nevada Test Site

    SciTech Connect (OSTI)

    David Hudson, Charles Lohrstorfer, Bruce Hurley

    2007-05-03

    Groundwater is sampled from 39 monitoring wells on the Nevada Test Site (NTS) as part of the Routine Radiological Environmental Monitoring Program. Many of these wells were not designed or constructed for long-term groundwater monitoring. Some have extensive completion zones and others have obstructions such as pumps and tubing. The high-volume submersible pumps in some wells are unsuitable for long-term monitoring and result in large volumes of water that may have to be contained and characterized before subsequent disposition. The configuration of most wells requires sampling stagnant well water with a wireline bailer. Although bailer sampling allows for the collection of depth-discrete samples, the collected samples may not be representative of local groundwater because no well purging is done. Low-maintenance, solar-powered jack pumps will be deployed in nine of these onsite monitoring wells to improve sample quality. These pumps provide the lift capacity to produce groundwater from the deep aquifers encountered in the arid environment of the NTS. The water depths in these wells range from 700 to 2,340 ft below ground surface. The considerable labor and electrical power requirements of electric submersible pumps are eliminated once these pumps are installed. Access tubing will be installed concurrent with the installation of the pump string to provide downhole access for water-level measurements or other wireline instruments. Micro-purge techniques with low pump rates will be used to minimize purge volumes and reduce hydraulic gradients. The set depths of the pumps will be determined by the borehole characteristics and screened interval.

  16. Natural radionuclides in groundwaters

    SciTech Connect (OSTI)

    Laul, J.C.

    1990-01-01

    The U-234 and Th-230 radionuclides are highly retarded by factors of 10{sup 4} to 10{sup 5} in basalt groundwater (Hanford) and briny groundwaters from Texas and geothermal brine from the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na{sup +} and Cl{sup {minus}} ions and RaCl{sub 2} is soluble in brines. Pb-210 is soluble in SSGF brine, probably as a chloride complex. The U-234/Th-230 ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. 19 refs., 3 figs.

  17. Characterization of uranium and plutonium in surface-waters and sediments collected at the Rocky Flats Facility

    SciTech Connect (OSTI)

    Efurd, D.W.; Rokop, D.J.; Aguilar, R.D.; Roensch, F.R.; Perrin, R.E.; Banar, J.C.

    1994-05-01

    This study was initiated to characterize actinides in environmental samples collected at the Rocky Flats Plant (RFP). Thermal Ionization Mass Spectrometry (TIMS) measurement techniques were used to measure the plutonium and uranium content of water and sediment samples collected from the ponds used to control surface-waters on-site at RFP. TIMS was also used to separate the uranium into anthropogenic and naturally occurring components. The results of these studies are presented.

  18. Potassium ferrate treatment of RFETS` contaminated groundwater

    SciTech Connect (OSTI)

    1995-01-01

    The potassium ferrate treatment study of Rocky Flats Environmental Technology Site (RFETS) groundwater was performed under the Sitewide Treatability Studies Program (STSP). This study was undertaken to determine the effectiveness of potassium ferrate in a water treatment system to remove the contaminants of concern (COCS) from groundwater at the RFETS. Potassium ferrate is a simple salt where the iron is in the plus six valence state. It is the iron at the plus six valence state (Fe {sup +6}) that makes it an unique water treatment chemical, especially in waters where the pH is greater than seven. In basic solutions where the solubility of the oxides/hydroxides of many of the COCs is low, solids are formed as the pH is raised. By using ferrate these solids are agglomerated so they can be effectively removed by sedimentation in conventional water treatment equipment. The objective of this study was to determine the quality of water after treatment with potassium ferrate and to determine if the Colorado Water Quality Control Commission (CWQCC) discharge limits for the COCs listed in Table 1.0-1 could be met. Radionuclides in the groundwater were of special concern.

  19. Hydrated goethite ([alpha]-FeOOH) (1 0 0 ) interface structure: Ordered water and surface functional groups

    SciTech Connect (OSTI)

    Ghose, Sanjit K.; Waychunas, Glenn A.; Trainor, Thomas P.; Eng, Peter J.

    2010-03-16

    Goethite({alpha}-FeOOH), an abundant and highly reactive iron oxyhydroxide mineral, has been the subject of numerous studies of environmental interface reactivity. However, such studies have been hampered by the lack of experimental constraints on aqueous interface structure, and especially of the surface water molecular arrangements. Structural information of this type is crucial because reactivity is dictated by the nature of the surface functional groups and the structure or distribution of water and electrolyte at the solid-solution interface. In this study we have investigated the goethite (1 0 0) surface using surface diffraction techniques, and have determined the relaxed surface structure, the surface functional groups, and the three dimensional nature of two distinct sorbed water layers. The crystal truncation rod (CTR) results show that the interface structure consists of a double hydroxyl, double water terminated interface with significant atom relaxations. Further, the double hydroxyl terminated surface dominates with an 89% contribution having a chiral subdomain structure on the (1 0 0) cleavage faces. The proposed interface stoichiometry is ((H{sub 2}O)-(H{sub 2}O)-OH{sub 2}-OH-Fe-O-O-Fe-R) with two types of terminal hydroxyls; a bidentate (B-type) hydroxo group and a monodentate (A-type) aquo group. Using the bond-valence approach the protonation states of the terminal hydroxyls are predicted to be OH type (bidentate hydroxyl with oxygen coupled to two Fe{sup 3+} ions) and OH{sub 2} type (monodentate hydroxyl with oxygen tied to only one Fe{sup 3+}). A double layer three dimensional ordered water structure at the interface was determined from refinement of fits to the experimental data. Application of bond-valence constraints to the terminal hydroxyls with appropriate rotation of the water dipole moments allowed a plausible dipole orientation model as predicted. The structural results are discussed in terms of protonation and H-bonding at the

  20. Buildings Energy Data Book: 8.2 Residential Sector Water Consumption

    Buildings Energy Data Book [EERE]

    1 Residential Water Use by Source (Million Gallons per Day) Year 1980 3,400 1985 3,320 1990 3,390 1995 3,390 2000 (3) (3) 3,590 2005 3,830 Note(s): Source(s): 29,430 25,600 1) Public supply water use: water withdrawn by public and private water suppliers that furnish water to at least 25 people or have a minimum of 15 connections. 2) Self-supply water use: Water withdrawn from a groundwater or surface-water source by a user rather than being obtained from a public supply. 3) USGS did not provide

  1. Applying GIS characterizing and modeling contaminant transport in surface water at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Becker, N.M.; Van Eeckhout, E.; David, N.A.; Irvine, J.M.

    1995-10-01

    During World War II, Los Alamos, New Mexico was chosen as the site for the secret development of the first atomic bomb. The remote location in the southwestern United States was ideal for such a project. After the war, research activities continued at the Los Alamos installation, focusing on new nuclear weapons models as well as greater effectiveness and reliability of existing weapons. Due to the emphasis on nuclear and non-nuclear weapons development as well as associated nuclear research, a large inventory of radionuclides and heavy metals have been tested, expended, and disposed of in the local environment, a high plateau of tuffaceous volcanic rocks incised by deep canyons in a semi-arid climate. In recent years an intensive evaluation of the environmental, impact of weapons testing at Los Alamos and elsewhere has been undertaken. GIS system utilization and image processing of past and current data has been an important part of this evaluation. Important problems can be more easily displayed and understood using this methodology. The main objective in this paper is to illustrate how transport of depleted uranium and associated heavy metals (copper in this case) used in dynamic testing of weapons components at open air firing sites can be evaluated and visualized. In our studies, surface water has been found to be the predominant transport mechanism. We have sampled soils, sediments, fallout, runoff water and snowmelt over a number of years in order to understand contaminant transport on- and offsite. Statistical analyses of these data have assisted in our characterization of issues such as contaminant variability, spatially and temporally, as well as in development of transport rates.

  2. Design of electric-field assisted surface plasmon resonance system for the detection of heavy metal ions in water

    SciTech Connect (OSTI)

    Kyaw, Htet Htet; Boonruang, Sakoolkan E-mail: waleed.m@bu.ac.th; Mohammed, Waleed S. E-mail: waleed.m@bu.ac.th; Dutta, Joydeep

    2015-10-15

    Surface Plasmon Resonance (SPR) sensors are widely used in diverse applications. For detecting heavy metal ions in water, surface functionalization of the metal surface is typically used to adsorb target molecules, where the ionic concentration is detected via a resonance shift (resonance angle, resonance wavelength or intensity). This paper studies the potential of a possible alternative approach that could eliminate the need of using surface functionalization by the application of an external electric field in the flow channel. The exerted electrical force on the ions pushes them against the surface for enhanced adsorption; hence it is referred to as “Electric-Field assisted SPR system”. High system sensitivity is achieved by monitoring the time dynamics of the signal shift. The ion deposition dynamics are discussed using a derived theoretical model based on ion mobility in water. On the application of an appropriate force, the target ions stack onto the sensor surface depending on the ionic concentration of target solution, ion mass, and flow rate. In the experimental part, a broad detection range of target cadmium ions (Cd{sup 2+}) in water from several parts per million (ppm) down to a few parts per billion (ppb) can be detected.

  3. Oxidative particle mixtures for groundwater treatment

    DOE Patents [OSTI]

    Siegrist, Robert L.; Murdoch, Lawrence C.

    2000-01-01

    The invention is a method and a composition of a mixture for degradation and immobilization of contaminants in soil and groundwater. The oxidative particle mixture and method includes providing a material having a minimal volume of free water, mixing at least one inorganic oxidative chemical in a granular form with a carrier fluid containing a fine grained inorganic hydrophilic compound and injecting the resulting mixture into the subsurface. The granular form of the inorganic oxidative chemical dissolves within the areas of injection, and the oxidative ions move by diffusion and/or advection, therefore extending the treatment zone over a wider area than the injection area. The organic contaminants in the soil and groundwater are degraded by the oxidative ions, which form solid byproducts that can sorb significant amounts of inorganic contaminants, metals, and radionuclides for in situ treatment and immobilization of contaminants. The method and composition of the oxidative particle mixture for long-term treatment and immobilization of contaminants in soil and groundwater provides for a reduction in toxicity of contaminants in a subsurface area of contamination without the need for continued injection of treatment material, or for movement of the contaminants, or without the need for continuous pumping of groundwater through the treatment zone, or removal of groundwater from the subsurface area of contamination.

  4. The Savannah River Site's groundwater monitoring program

    SciTech Connect (OSTI)

    Not Available

    1991-05-06

    The Environmental Protection Department/Environmental Monitoring Section (EPD/EMS) administers the Savannah River Site's (SRS) Groundwater Monitoring Program. During third quarter 1990 (July through September) EPD/EMS conducted routine sampling of monitoring wells and drinking water locations. EPD/EMS established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria do not define contamination levels; instead they aid personnel in sample scheduling, interpretation of data, and trend identification. The flagging criteria are based on detection limits, background levels in SRS groundwater, and drinking water standards. All analytical results from third quarter 1990 are listed in this report, which is distributed to all site custodians. One or more analytes exceeded Flag 2 in 87 monitoring well series. Analytes exceeded Flat 2 for the first since 1984 in 14 monitoring well series. In addition to groundwater monitoring, EPD/EMS collected drinking water samples from SRS drinking water systems supplied by wells. The drinking water samples were analyzed for radioactive constituents.

  5. Independent technical evaluation and recommendations for contaminated groundwater at the department of energy office of legacy management Riverton processing site

    SciTech Connect (OSTI)

    Looney, Brain B.; Denham, Miles E.; Eddy-Dilek, Carol A.

    2014-04-01

    The U.S. Department of Energy Office of Legacy Management (DOE-LM) manages the legacy contamination at the Riverton, WY, Processing Site – a former uranium milling site that operated from 1958 to 1963. The tailings and associated materials were removed in 1988-1989 and contaminants are currently flushing from the groundwater. DOE-LM commissioned an independent technical team to assess the status of the contaminant flushing, identify any issues or opportunities for DOE-LM, and provide key recommendations. The team applied a range of technical frameworks – spatial, temporal, hydrological and geochemical – in performing the evaluation. In each topic area, an in depth evaluation was performed using DOE-LM site data (e.g., chemical measurements in groundwater, surface water and soil, water levels, and historical records) along with information collected during the December 2013 site visit (e.g., plant type survey, geomorphology, and minerals that were observed, collected and evaluated).

  6. Cumulative hydrologic impact assessments on surface-water in northeastern Wyoming using HEC-1; a pilot study

    SciTech Connect (OSTI)

    Anderson, A.J.; Eastwood, D.C.; Anderson, M.E.

    1997-12-31

    The Surface Mining Control and Reclamation Act of 1977 requires that areas in which multiple mines will affect one watershed be analyzed and the cumulative impacts of all mining on the watershed be assessed. The purpose of the subject study was to conduct a cumulative hydrologic impact assessment (CHIA) for surface-water on a watershed in northeastern Wyoming that is currently being impacted by three mines. An assessment of the mining impact`s affect on the total discharge of the watershed is required to determine whether or not material damage to downstream water rights is likely to occur as a result of surface mining and reclamation. The surface-water model HEC-1 was used to model four separate rainfall-runoff events that occurred in the study basin over three years (1978-1980). Although these storms were used to represent pre-mining conditions, they occurred during the early stages of mining and the models were adjusted accordingly. The events were selected for completeness of record and antecedent moisture conditions (AMC). Models were calibrated to the study events and model inputs were altered to reflect post-mining conditions. The same events were then analyzed with the new model inputs. The results were compared with the pre-mining calibration. Peak flow, total discharge and timing of flows were compared for pre-mining and post-mining models. Data were turned over to the State of Wyoming for assessment of whether material damage to downstream water rights is likely to occur.

  7. Leakage and Sepage of CO2 from Geologic Carbon SequestrationSites: CO2 Migration into Surface Water

    SciTech Connect (OSTI)

    Oldenburg, Curt M.; Lewicki, Jennifer L.

    2005-06-17

    Geologic carbon sequestration is the capture of anthropogenic carbon dioxide (CO{sub 2}) and its storage in deep geologic formations. One of the concerns of geologic carbon sequestration is that injected CO{sub 2} may leak out of the intended storage formation, migrate to the near-surface environment, and seep out of the ground or into surface water. In this research, we investigate the process of CO{sub 2} leakage and seepage into saturated sediments and overlying surface water bodies such as rivers, lakes, wetlands, and continental shelf marine environments. Natural CO{sub 2} and CH{sub 4} fluxes are well studied and provide insight into the expected transport mechanisms and fate of seepage fluxes of similar magnitude. Also, natural CO{sub 2} and CH{sub 4} fluxes are pervasive in surface water environments at levels that may mask low-level carbon sequestration leakage and seepage. Extreme examples are the well known volcanic lakes in Cameroon where lake water supersaturated with respect to CO{sub 2} overturned and degassed with lethal effects. Standard bubble formation and hydrostatics are applicable to CO{sub 2} bubbles in surface water. Bubble-rise velocity in surface water is a function of bubble size and reaches a maximum of approximately 30 cm s{sup -1} at a bubble radius of 0.7 mm. Bubble rise in saturated porous media below surface water is affected by surface tension and buoyancy forces, along with the solid matrix pore structure. For medium and fine grain sizes, surface tension forces dominate and gas transport tends to occur as channel flow rather than bubble flow. For coarse porous media such as gravels and coarse sand, buoyancy dominates and the maximum bubble rise velocity is predicted to be approximately 18 cm s{sup -1}. Liquid CO{sub 2} bubbles rise slower in water than gaseous CO{sub 2} bubbles due to the smaller density contrast. A comparison of ebullition (i.e., bubble formation) and resulting bubble flow versus dispersive gas transport for CO

  8. 2012 Groundwater Monitoring Report Project Shoal Area Subsurface Corrective Action Unit 447

    SciTech Connect (OSTI)

    2013-03-01

    The Project Shoal Area (PSA) in Nevada was the site of a 12-kiloton underground nuclear test in 1963. Although the surface of the site has been remediated, investigation of groundwater contamination resulting from the test is still in the corrective action process. Annual sampling and hydraulic head monitoring are conducted at the site as part of the subsurface corrective action strategy. Analytical results from the 2012 monitoring are consistent with those of the previous years, with tritium detected only in well HC-4. The tritium concentration in groundwater from well HC-4 remains far below the U.S. Environmental Protection Agency-established maximum contaminant level of 20,000 picocuries per liter. Concentrations of total uranium and gross alpha were also detected during this monitoring period, with uranium accounting for nearly all the gross alpha activity. The total uranium concentrations obtained from this monitoring period were consistent with previous results and reflect a slightly elevated natural uranium concentration, consistent with the mineralized geologic terrain. Isotopic ratios of uranium also indicate a natural source of uranium in groundwater, as opposed to a nuclear-test-related source. Water level trends obtained from the 2012 water level data were consistent with those of previous years. The corrective action strategy for the PSA is currently focused on revising the site conceptual model (SCM) and evaluating the adequacy of the current monitoring well network. Some aspects of the SCM are known; however, two major concerns are the uncertainty in the groundwater flow direction and the cause of rising water levels in site wells west of the shear zone. Water levels have been rising in the site wells west of the shear zone since the first hydrologic characterization wells were installed in 1996. While water levels in wells west of the shear zone continue to rise, the rate of increase is less than in previous years. The SCM will be revised, and an

  9. A detection-level hazardous waste ground-water monitoring compliance plan for the 200 areas low-level burial grounds and retrievable storage units

    SciTech Connect (OSTI)

    Not Available

    1987-02-01

    This plan defines the actions needed to achieve detection-level monitoring compliance at the Hanford Site 200 Areas Low-Level Burial Grounds (LLBG) in accordance with the Resource Conservation and Recovery Act (RCRA). Compliance will be achieved through characterization of the hydrogeology and monitoring of the ground water beneath the LLBG located in the Hanford Site 200 Areas. 13 refs., 20 figs.

  10. Influence of particle size and water coverage on the thermodynamic properties of water confined on the surface of SnO2 cassiterite nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor; Ross, Dr. Nancy; Parker, Stewart F.; Kolesnikov, Alexander I; Woodfield, Brian; Woodfield, K; Rytting, M; Boerio-Goates, Juliana; Navrotsky, Alexandra

    2011-01-01

    Inelastic neutron scattering (INS) data for SnO2 nanoparticles of three different sizes and varying hydration levels are presented. Data were recorded on five nanoparticle samples that had the following compositions: 2 nm SnO2*0.82H2O, 6 nm SnO2*0.055H2O, 6 nm SnO2*0.095H2O, 20 nm SnO2*0.072H2O, and 20 nm SnO2*0.092H2O. The isochoric heat capacity and vibrational entropy values at 298 K for the water confined on the surface of these nanoparticles were calculated from the vibrational density of states that were extracted from the INS data. This study has shown that the hydration level of the SnO2 nanoparticles influences the thermodynamic properties of the water layers and, most importantly, that there appears to be a critical size limit for SnO2 between 2 and 6 nm below which the particle size also affects these properties and above which it does not. These results have been compared with those for isostructural rutile-TiO2 nanoparticles [TiO2*0.22H2O and TiO2*0.37H2O], which indicated that water on the surface of TiO2 nanoparticles is more tightly bound and experiences a greater degree of restricted motion with respect to water on the surface of SnO2 nanoparticles. This is believed to be a consequence of the difference in chemical composition, and hence surface properties, of these metal oxide nanoparticles.

  11. Hanford Site groundwater monitoring for fiscal year 1996

    SciTech Connect (OSTI)

    Hartman, M.J.; Dresel, P.E.; Borghese, J.V.

    1997-02-01

    This report presents the results of groundwater and vadose-zone monitoring for fiscal year (FY) 1996 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that affected groundwater quality on the site. Characterization and monitoring of the vadose zone during FY 1996 comprised primarily spectral gamma logging, soil-gas monitoring, and electrical resistivity tomography. Water-level monitoring was performed to evaluate groundwater-flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Water levels over most of the Hanford Site continued to decline between June 1995 and June 1996. Groundwater chemistry was monitored to track the extent of contamination, to note trends, and to identify emerging groundwater-quality problems. The most widespread radiological contaminant plumes were tritium and iodine-129. Smaller plumes of strontium-90, technetium-99, and plutonium also were present at levels above the U.S. Environmental Protection Agency or State of Washington interim drinking water standards. Uranium concentrations greater than the proposed drinking water standard were also observed. Nitrate, fluoride, chromium, carbon tetrachloride, chloroform, trichloroethylene, and cis-1,2-dichlomethylene were present in groundwater samples at levels above their U.S. Environmental Protection Agency or State of Washington maximum contaminant levels. The nitrate plume is the most extensive. Three-dimensional, numerical, groundwater models were applied to the Hanford Site to predict contaminant-flow paths and the impact of operational changes on site groundwater conditions. Other models were applied to assess the performance of three separate pump-and-treat systems.

  12. Fernald Environmental Management Project Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Fernald Environmental Management Project Archived Soil & Groundwater Master Reports Fernald Environmental Management Project Archived Soil & Groundwater Master Reports Fernald ...

  13. Miamisburg Environmental Management Project Archived Soil & Groundwate...

    Office of Environmental Management (EM)

    Miamisburg Environmental Management Project Archived Soil & Groundwater Master Reports Miamisburg Environmental Management Project Archived Soil & Groundwater Master Reports ...

  14. Sanitary Landfill Groundwater Monitoring Report - Fourth Quarter 1998 and 1998 Summary

    SciTech Connect (OSTI)

    Chase, J.

    1999-04-09

    A maximum of fifty-three wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water permit and as part of the SRS Groundwater Monitoring Program.

  15. In situ groundwater bioremediation

    SciTech Connect (OSTI)

    Hazen, Terry C.

    2009-02-01

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  16. Effect of surface free energies on the heterogeneous nucleation of water droplet: A molecular dynamics simulation approach

    SciTech Connect (OSTI)

    Xu, W.; Lan, Z.; Peng, B. L.; Wen, R. F.; Ma, X. H.

    2015-02-07

    Heterogeneous nucleation of water droplet on surfaces with different solid-liquid interaction intensities is investigated by molecular dynamics simulation. The interaction potentials between surface atoms and vapor molecules are adjusted to obtain various surface free energies, and the nucleation process and wetting state of nuclei on surfaces are investigated. The results indicate that near-constant contact angles are already established for nano-scale nuclei on various surfaces, with the contact angle decreasing with solid-liquid interaction intensities linearly. Meanwhile, noticeable fluctuation of vapor-liquid interfaces can be observed for the nuclei that deposited on surfaces, which is caused by the asymmetric forces from vapor molecules. The formation and growth rate of nuclei are increasing with the solid-liquid interaction intensities. For low energy surface, the attraction of surface atoms to water molecules is comparably weak, and the pre-existing clusters can depart from the surface and enter into the bulk vapor phase. The distribution of clusters within the bulk vapor phase becomes competitive as compared with that absorbed on surface. For moderate energy surfaces, heterogeneous nucleation predominates and the formation of clusters within bulk vapor phase is suppressed. The effect of high energy particles that embedded in low energy surface is also discussed under the same simulation system. The nucleation preferably initiates on the high energy particles, and the clusters that formed on the heterogeneous particles are trapped around their original positions instead of migrating around as that observed on smooth surfaces. This feature makes it possible for the heterogeneous particles to act as fixed nucleation sites, and simulation results also suggest that the number of nuclei increases monotonously with the number of high energy particles. The growth of nuclei on high energy particles can be divided into three sub-stages, beginning with the formation

  17. Surface modification of ultra thin PES-zeolite using thermal annealing to increase flux and rejection of produced water treatment

    SciTech Connect (OSTI)

    Kusworo, T. D. Widayat,; Pradini, A. W.; Armeli, Y. P.

    2015-12-29

    Membrane technology is an alternative of water treatment based on filtration that is being developed. Surface Modification using heat treatment has been investigated to improve the performance of ultra thin PES-Zeolite nanocomposite membrane for produced water treatment from Pertamina Balongan. Two types of membranes with surface modification and without modification were prepared to study the effect of surface modification on its permeation properties. Asymmetric ultra thin PES-Zeolite nanocomposite membrane for produced water treatment was casted using the dry/wet phase inversion technique from dope solutions containing polyethersulfone, N-methyl-2-pyrrolidone (NMP) as a solvent and zeolite as a filler. Experimental results showed that the heat treatment at near glass transition temperature was increase the rejection of COD, Turbidity and ion Ca{sup 2+}. The better adherence of zeolite particles in the polymer matrix combined with formation of charge transfer complexes (CTCs) and cross-linking might be the main factors to enhance the percent of rejection. Field emission scanning electron microscopy (FESEM) micrographs showed that the selective layer and the substructure of PES-zeolite membrane became denser and more compact after the heat treatment. The FESEM micrographs also showed that the heat treatment was increased the adherence of zeolite particle and polymer. Membranes treated at 180 °C for 15 seconds indicated increase the rejection and small decrease in flux for produced water treatment.

  18. 2011 Groundwater Monitoring and Inspection Report Gnome-Coach Site, New Mexico

    SciTech Connect (OSTI)

    2012-02-01

    Gnome-Coach was the site of a 3-kiloton underground nuclear test in 1961. Surface and subsurface contamination resulted from the underground nuclear testing, post-test drilling, and groundwater tracer test performed at the site. The State of New Mexico is currently proceeding with a conditional certificate of completion for the surface. As for the subsurface, monitoring activities that include hydraulic head monitoring and groundwater sampling of the wells onsite are conducted as part of the annual site inspection. These activities were conducted on January 19, 2011. The site roads, monitoring well heads, and the monument at surface ground zero were observed as being in good condition at the time of the site inspection. An evaluation of the hydraulic head data obtained from the site indicates that water levels in wells USGS-4 and USGS-8 appear to respond to the on/off cycling of the dedicated pump in well USGS-1 and that water levels in wells LRL-7 and DD-1 increased during this annual monitoring period. Analytical results obtained from the sampling indicate that concentrations of tritium, strontium-90, and cesium-137 were consistent with concentrations from historical sampling events.

  19. What waters does LANL protect?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    does LANL protect? Google Earth Tour: Waters around LANL Jemez Mountains Headwaters Watersheds The Rio Grande Buckman Direct Diversion Project Groundwater in the Regional Aquifer...

  20. Paducah Site Undergoing Steady Groundwater Cleanup with Variety of Methods

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Site Undergoing Steady Groundwater Cleanup with Variety of Methods Paducah Site Undergoing Steady Groundwater Cleanup with Variety of Methods June 1, 2012 - 12:00pm Addthis The yellow outline depicts an area southeast of the C-400 Cleaning Building, background, where electrical resistance heating will be used to remove trichloroethene (TCE) down to 60 feet below ground. Electrodes will heat the chemical into a vapor that can be pumped to the surface and treated in the

  1. 3D Simulation of Missing Pellet Surface Defects in Light Water Reactor Fuel Rods

    SciTech Connect (OSTI)

    B.W. Spencer; J.D. Hales; S.R. Novascone; R.L. Williamson

    2012-09-01

    The cladding on light water reactor (LWR) fuel rods provides a stable enclosure for fuel pellets and serves as a first barrier against fission product release. Consequently, it is important to design fuel to prevent cladding failure due to mechanical interactions with fuel pellets. Cladding stresses can be effectively limited by controlling power increase rates. However, it has been shown that local geometric irregularities caused by manufacturing defects known as missing pellet surfaces (MPS) in fuel pellets can lead to elevated cladding stresses that are sufficiently high to cause cladding failure. Accurate modeling of these defects can help prevent these types of failures. Nuclear fuel performance codes commonly use a 1.5D (axisymmetric, axially-stacked, one-dimensional radial) or 2D axisymmetric representation of the fuel rod. To study the effects of MPS defects, results from 1.5D or 2D fuel performance analyses are typically mapped to thermo-mechanical models that consist of a 2D plane-strain slice or a full 3D representation of the geometry of the pellet and clad in the region of the defect. The BISON fuel performance code developed at Idaho National Laboratory employs either a 2D axisymmetric or 3D representation of the full fuel rod. This allows for a computational model of the full fuel rod to include local defects. A 3D thermo-mechanical model is used to simulate the global fuel rod behavior, and includes effects on the thermal and mechanical behavior of the fuel due to accumulation of fission products, fission gas production and release, and the effects of fission gas accumulation on thermal conductivity across the fuel-clad gap. Local defects can be modeled simply by including them in the 3D fuel rod model, without the need for mapping between two separate models. This allows for the complete set of physics used in a fuel performance analysis to be included naturally in the computational representation of the local defect, and for the effects of the

  2. Surface topography of a palladium cathode after electrolysis in heavy water

    SciTech Connect (OSTI)

    Silver, D.S. ); Dash, J.; Keefe, P.S. )

    1993-12-01

    Electrolysis was performed with a palladium cathode and an electrolyte containing both hydrogen and deuterium ions. The cathode bends toward the anode during this process. Examination of both the concave and the convex surfaces with the scanning electron microscope, scanning tunneling microscope, and atomic force microscope shows unusual surface characteristics. Rimmed craters with faceted crystals inside and multitextural surfaces were observed on an electrolyzed palladium cathode but not on palladium that has not been electrolyzed. 9 refs., 9 figs.

  3. Geologic mapping for groundwater resource protection and assessment

    SciTech Connect (OSTI)

    Shafer, J.M. . Earth Sciences and Resources Inst.); Berg, R.C. )

    1993-03-01

    Groundwater is a vital natural resource in the US and around the world. In order to manage and protect this often threatened resource one must better understand its occurrence, extent, and susceptibility to contamination. Geologic mapping is a fundamental approach to developing more detailed and accurate assessments of groundwater resources. The stratigraphy and lithology of earth materials provide the framework for groundwater systems, whether they are deep confined aquifers or shallow, water table environments. These same earth materials control, in large part, the rates of migration of water and contaminants into and through groundwater systems thus establishing the potential yields of the systems and their vulnerability to contamination. Geologic mapping is used to delineate and display the vertical sequencing of earth materials either in cross-section or over lateral areas as in the stack-unit geologic map. These geologic maps, along with supportive hydrogeologic information, are used to identify the three-dimensional positioning and continuity of aquifer and non-aquifer earth materials. For example, detailed stack-unit mapping to a depth of 30 meters has been completed for a portion of a northern Illinois county. Groundwater contamination potentials were assigned to various vertical sequences of materials. Where aquifers are unconfined, groundwater contamination potentials are greatest. Conversely, other considerations being equal, the thicker the confining unit, the lower the contamination potential. This information is invaluable for land use decision-making; water supply assessment, development, and management; and environmental protection planning.

  4. COMPARISON OF RESULTS FOR QUARTER 5 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE ERWIN TENNESSEE

    SciTech Connect (OSTI)

    2013-09-23

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on August 21, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference, are tabulated. All DER values were less than 3 and results are consistent with low (e.g., background) concentrations.

  5. COMPOUNDING EFFECTS OF FLUID CONFINEMENT AND SURFACE STRAIN ON THE WET-DRY TRANSITION AND DYNAMICS OF GRAPHENE-WATER SYSTEMS

    SciTech Connect (OSTI)

    Chialvo, Ariel A; Vlcek, Lukas; Cummings, Peter

    2015-01-01

    We studied the link between the water-mediated (tensile or compressive) strain-driven hydration free energy changes in the association process involving finite-size graphene surfaces, the resulting water-graphene interfacial behavior, and the combined effect of surface strain and fluid confinement on the thermodynamic response functions and the dynamics of water. We found that either small surface corrugation (compressive strain) or surface stretching (tensile strain) is able to enhance significantly the water-graphene hydrophobicity relative to that of the unstrained surface, an effect that exacerbates the confinement impact on the isothermal compressibility and isobaric thermal expansivity of confined water, as well as on the slowing down of its dynamics that gives rise to anomalous diffusivity.

  6. COMPOUNDING EFFECTS OF FLUID CONFINEMENT AND SURFACE STRAIN ON THE WET-DRY TRANSITION AND DYNAMICS OF GRAPHENE-WATER SYSTEMS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chialvo, Ariel A; Vlcek, Lukas; Cummings, Peter

    2015-01-01

    We studied the link between the water-mediated (tensile or compressive) strain-driven hydration free energy changes in the association process involving finite-size graphene surfaces, the resulting water-graphene interfacial behavior, and the combined effect of surface strain and fluid confinement on the thermodynamic response functions and the dynamics of water. We found that either small surface corrugation (compressive strain) or surface stretching (tensile strain) is able to enhance significantly the water-graphene hydrophobicity relative to that of the unstrained surface, an effect that exacerbates the confinement impact on the isothermal compressibility and isobaric thermal expansivity of confined water, as well as on themoreslowing down of its dynamics that gives rise to anomalous diffusivity.less

  7. Purge water management system

    DOE Patents [OSTI]

    Cardoso-Neto, Joao E.; Williams, Daniel W.

    1996-01-01

    A purge water management system for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  8. Purge water management system

    DOE Patents [OSTI]

    Cardoso-Neto, J.E.; Williams, D.W.

    1995-01-01

    A purge water management system is described for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  9. Innovative Use of Cr(VI) Plume Depictions and Pump-and-Treat Capture Analysis to Estimate Risks of Contaminant Discharge to Surface Water at Hanford Reactor Areas

    SciTech Connect (OSTI)

    Miller, Chuck W.; Hanson, James P.; Ivarson, Kristine A.; Tonkin, M.

    2015-01-14

    The Hanford Site nuclear reactor operations required large quantities of high-quality cooling water, which was treated with chemicals including sodium dichromate dihydrate for corrosion control. Cooling water leakage, as well as intentional discharge of cooling water to ground during upset conditions, produced extensive groundwater recharge mounds consisting largely of contaminated cooling water and resulted in wide distribution of hexavalent chromium (Cr[VI]) contamination in the unconfined aquifer. The 2013 Cr(VI) groundwater plumes in the 100 Areas cover approximately 6 km2 (1500 acres), primarily in the 100-HR-3 and 100-KR-4 groundwater operable units (OUs). The Columbia River is a groundwater discharge boundary; where the plumes are adjacent to the Columbia River there remains a potential to discharge Cr(VI) to the river at concentrations above water quality criteria. The pump-and-treat systems along the River Corridor are operating with two main goals: 1) protection of the Columbia River, and 2) recovery of contaminant mass. An evaluation of the effectiveness of the pump-and-treat systems was needed to determine if the Columbia River was protected from contamination, and also to determine where additional system modifications may be needed. In response to this need, a technique for assessing the river protection was developed which takes into consideration seasonal migration of the plume and hydraulic performance of the operating well fields. Groundwater contaminant plume maps are generated across the Hanford Site on an annual basis. The assessment technique overlays the annual plume and the capture efficiency maps for the various pump and treat systems. The river protection analysis technique was prepared for use at the Hanford site and is described in detail in M.J. Tonkin, 2013. Interpolated capture frequency maps, based on mapping dynamic water level observed in observation wells and derived water levels in the vicinity of extraction and injection wells

  10. In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental Study

    SciTech Connect (OSTI)

    Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

    2015-09-15

    In situ arsenic removal from groundwater by an iron coating method has great potential to be a cost effective and simple groundwater remediation technique, especially in rural and remote areas where groundwater is used as the main source of drinking water. The in situ arsenic removal technique was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions., Its effectiveness was then evaluated in an actual high-arsenic groundwater environment. The mechanism of arsenic removal by the iron coating was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, an electron microprobe, and Fourier transformation infrared spectroscopy. A 4-step alternative cycle aquifer iron coating method was developed. A continuous injection of 5 mmol/L FeSO4 and 2.5 mmol/L NaClO for 96 hours can create a uniform coating of crystalline goethite on the surface of quartz sand in the columns without causing clogging. At a flow rate of 0.45 cm/min of the injection reagents (vi), the time for arsenic (as Na2HAsO4) to pass through the iron-coated quartz sand column was approximately 35 hours, which was much longer than that for tracer fluorescein sodium (approximately 2 hours). The retardation factor of arsenic was 23, and its adsorption capacity was 0.11 mol As per mol Fe, leading to an excellent arsenic removal. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As (V) and Fe (II) reagents. When the arsenic content in the groundwater was 233 ?g/L, the aqueous phase arsenic was completely removed with an arsenic adsorption of 0.05 mol As per mol Fe. Arsenic fixation resulted from a process of adsorption/co-precipitation, in which arsenic and iron likely formed the arsenic-bearing iron mineral phases with poor crystallinity by way of bidentate binuclear complexes. Thus, the high arsenic removal efficiency of the technique likely resulted from the

  11. A groundwater flow and transport model of long-term radionuclide migration in central Frenchman flat, Nevada test site

    SciTech Connect (OSTI)

    Kwicklis, Edward Michael [Los Alamos National Laboratory; Becker, Naomi M [Los Alamos National Laboratory; Ruskauff, Gregory [NAVARRO-INTERA, LLC.; De Novio, Nicole [GOLDER AND ASSOC.; Wilborn, Bill [US DOE NNSA NSO

    2010-11-10

    A set of groundwater flow and transport models were created for the Central Testing Area of Frenchman Flat at the former Nevada Test Site to investigate the long-term consequences of a radionuclide migration experiment that was done between 1975 and 1990. In this experiment, radionuclide migration was induced from a small nuclear test conducted below the water table by pumping a well 91 m away. After radionuclides arrived at the pumping well, the contaminated effluent was discharged to an unlined ditch leading to a playa where it was expected to evaporate. However, recent data from a well near the ditch and results from detailed models of the experiment by LLNL personnel have convincingly demonstrated that radionuclides from the ditch eventually reached the water table some 220 m below land surface. The models presented in this paper combine aspects of these detailed models with concepts of basin-scale flow to estimate the likely extent of contamination resulting from this experiment over the next 1,000 years. The models demonstrate that because regulatory limits for radionuclide concentrations are exceeded only by tritium and the half-life of tritium is relatively short (12.3 years), the maximum extent of contaminated groundwater has or will soon be reached, after which time the contaminated plume will begin to shrink because of radioactive decay. The models also show that past and future groundwater pumping from water supply wells within Frenchman Flat basin will have negligible effects on the extent of the plume.

  12. Effect of metal ion intercalation on the structure of MXene and water dynamics on its internal surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Osti, Naresh C.; Naguib, Michael; Ostadhossein, Alireza; Kent, Paul R. C.; Dyatkin, Boris; Rother, Gernot; Heller, William T.; Adri C. T. van Duin; Gogotsi, Yury; Mamontov, Eugene; et al

    2016-03-24

    MXenes are a recently discovered class of 2D materials with an excellent potential for energy storage applications. Because MXene surfaces are hydrophilic and attractive interaction forces between the layers are relatively weak, water molecules can spontaneously intercalate at ambient humidity and significantly influence the key properties of this 2D material. Using complementary X-ray and neutron scattering techniques, we demonstrate that intercalation with potassium cations significantly improves structural homogeneity and water stability in MXenes. Furthermore, in agreement with molecular dynamics simulations, intercalated potassium ions reduce the water self-diffusion coefficient by 2 orders of magnitude, suggesting greater stability of hydrated MXene againstmore » changing environmental conditions.« less

  13. Surface water processes in the Indonesian Throughflow as documented by a high-resolution coral (Delta)14C record

    SciTech Connect (OSTI)

    Fallon, S J; Guilderson, T P

    2008-04-23

    To explore the seasonal to decadal variability in surface water masses that contribute to the Indonesian Throughflow we have generated a 115-year bi-monthly coral-based radiocarbon time-series from a coral in the Makassar Straits. In the pre-bomb (pre-1955) era from 1890 to 1954, the radiocarbon time series occasionally displays a small seasonal signal (10-15{per_thousand}). After 1954 the radiocarbon record increases rapidly, in response to the increased atmospheric {sup 14}C content caused by nuclear weapons testing. From 1957 to 1986 the record displays clear seasonal variability from 15 to 60{per_thousand} and the post-bomb peak (163 per mil) occurred in 1974. The seasonal cycle of radiocarbon can be attributed to variations of surface waters passing through South Makassar Strait. Southern Makassar is under the influence of the Northwest Monsoon, which is responsible for the high Austral summer radiocarbon (North Pacific waters) and the Southeast Monsoon that flushes back a mixture of low (South Pacific and upwelling altered) radiocarbon water from the Banda Sea. The coral record also shows a significant {sup 14}C peak in 1955 due to bomb {sup 14}C water advected into this region in the form of CaCO{sub 3} particles (this implies that the particles were advected intact and then become entrapped in the coral skeleton--is this what we really mean? Wouldn't even fine particles settle out over the inferred transit time from Bikini to MAK?) or water particles with dissolved labeled CO{sub 2} produced during fallout from the Castle tests in 1954.

  14. Final report on the Groundwater Isotope Project in the Brentwood Region of East Contra Costa County, California

    SciTech Connect (OSTI)

    Davisson, M.L.; Campbell, K.R.

    1995-05-01

    Groundwater in the Brentwood region has been characterized using isotope hydrology techniques and have addressed resource issues regarding the future sustainability of groundwater, maintenance of existing supplies, and exploration of new supplies. The stable isotopes of oxygen and hydrogen indicate that groundwater is derived from two sources: ancient rain recharge, and recharge of agricultural irrigation water. Rain derived groundwater ages range from <1000 to {approximately}12,000 years old. Agricultural recharge groundwater is <80 years and has recharged much of the basin on average to {approximately}125 fbs. The agricultural water recharges >10 times faster than natural rain water and hence, represents the principal recharge component. The agricultural recharge at the present time provides groundwater quantities to the basin that exceed the yearly water supply demand. With increasing urban development and retiring agricultural land, the availability of groundwater will decrease. Safe yield projections for the groundwater have been modeled to show that safe groundwater yields range between 30 to 120 acre-ft/mi{sup 2} per year for a population of 70,000 people. This will only account for {approximately}3 to 11 % of the total water demand. Furthermore, much of this groundwater may need well head treatment for water quality problems.

  15. Superfund record of decision (EPA Region 9): Newmark Groundwater Contamination Site, San Bernardino, CA, August 1993

    SciTech Connect (OSTI)

    Not Available

    1993-08-04

    This decision document presents the selected remedial action for the Newmark Operable Unit, Newmark Groundwater Contamination Superfund site. EPA has selected an interim remedy for the Newmark plume of groundwater contamination in the Newmark Groundwater Contamination Superfund Site. This portion of the site cleanup is referred to as the Newmark Operable Unit (OU). The Newmark OU is an interim action focusing on contamination in the undergound water supply in the Bunker Hill Basin of San Bernardino, north and east of the Shandin Hills.

  16. Waste Isolation Pilot Plant Groundwater Protection Management Program Plan

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services

    2005-07-01

    The DOE established the Groundwater Monitoring Program (GMP) (WP 02-1) to monitor groundwater resources at WIPP. In the past, the GMP was conducted to establish background data of existing conditions of groundwater quality and quantity in the WIPP vicinity, and to develop and maintain a water quality database as required by regulation. Today the GMP is conducted consistent with 204.1.500 NMAC (New MexicoAdministrative Code), "Adoption of 40 CFR [Code of Federal Regulations] Part 264,"specifically 40 CFR §264.90 through §264.101. These sections of 20.4.1 NMAC provide guidance for detection monitoring of groundwater that is, or could be, affected by waste management activities at WIPP. Detection monitoring at WIPP is designed to detect contaminants in the groundwater long before the general population is exposed. Early detection will allow cleanup efforts to be accomplished before any exposure to the general population can occur. Title 40 CFR Part 264, Subpart F, stipulates minimum requirements of Resource Conservation and Recovery Act of 1976 (42 United States Code [U.S.C.] §6901 et seq.) (RCRA) groundwater monitoring programs including the number and location of monitoring wells; sampling and reporting schedules; analytical methods and accuracy requirements; monitoring parameters; and statistical treatment of monitoring data. This document outlines how WIPP intends to protect and preserve groundwater within the WIPP Land Withdrawal Area (WLWA). Groundwater protection is just one aspect of the WIPP environmental protection effort. An overview of the entire environmental protection effort can be found in DOE/WIPP 99-2194, Waste Isolation Pilot Plant Environmental Monitoring Plan. The WIPP GMP is designed to statistically determine if any changes are occurring in groundwater characteristics within and surrounding the WIPP facility. If a change is noted, the cause will then be determined and the appropriate corrective action(s) initiated.

  17. Annual report of groundwater monitoring at Everest, Kansas in 2011.

    SciTech Connect (OSTI)

    LaFreniere, L. M.

    2011-12-19

    trace increases in carbon tetrachloride concentrations observed in 2010 at locations SB63 and SB64 were notable because of the locations proximity to the downgradient intermittent creek. However, these increases were not confirmed in sampling in 2011. (5) The results of the April 2011 monitoring event continue to support the interpretation, made during the 9-yr observation period from 2001 to 2010, that the migration rate for contamination in groundwater toward the intermittent creek is very slow. (6) No carbon tetrachloride was detected in five samples of surface water collected from the intermittent creek west of the former CCC/USDA facility and the Nigh property, or in tree branch tissue samples collected at locations along the banks of the creek. These observations indicate that the carbon tetrachloride contamination identified at Everest has, to date, not impacted the surface waters of the intermittent creek.

  18. Topology of the Adiabatic Potential Energy Surfaces for theResonance States of the Water Anion

    SciTech Connect (OSTI)

    Haxton, Daniel J.; Rescigno, Thomas N.; McCurdy, C. William

    2005-04-15

    The potential energy surfaces corresponding to the long-lived fixed-nuclei electron scattering resonances of H{sub 2}O relevant to the dissociative electron attachment process are examined using a combination of ab initio scattering and bound-state calculations. These surfaces have a rich topology, characterized by three main features: a conical intersection between the {sup 2}A{sub 1} and {sup 2}B{sub 2} Feshbach resonance states; charge-transfer behavior in the OH ({sup 2}{Pi}) + H{sup -} asymptote of the {sup 2}B{sub 1} and {sup 2}A{sub 1} resonances; and an inherent double-valuedness of the surface for the {sup 2}B{sub 2} state the C{sub 2v} geometry, arising from a branch-point degeneracy with a {sup 2}B{sub 2} shape resonance. In total, eight individual seams of degeneracy among these resonances are located.

  19. Carbon 14 measurements in surface water CO{sub 2} from the Atlantic, India, and Pacific Oceans, 1965--1994

    SciTech Connect (OSTI)

    Nydal, R.; Brenkert, A.L.; Boden, T.A.

    1998-03-01

    In the 1960s, thermonuclear bomb tests released significant pulses of radioactive carbon-14 ({sup 14}C) into the atmosphere. These major perturbations allowed scientists to study the dynamics of the global carbon cycle by calculating rates of isotope exchange between the atmosphere and ocean waters. A total of 950 ocean surface water observations were made from 1965 through 1994. The measurements were taken at 30 stations in the Atlantic Ocean, 14 stations in the Indian Ocean, and 38 stations in the Pacific Ocean. Thirty-two of the 950 samples were taken in the Atlantic Ocean during the R/V Andenes research cruise. {sup 14}C was measured in 871 of the 950 samples, and those measurements have been corrected ({Delta}{sup 14}C) for isotopic fractionation and radioactive decay. The {Delta}{sup 14}C values range between {minus}113.3 and 280.9 per mille and have a mean value of 101.3 per mille. The highest yearly mean (146.5 per mille) was calculated for 1969, the lowest yearly mean value was calculated for 1990 (67.9 per mille) illustrating a decrease over time. This decrease was to be expected as a result of the ban on atmospheric thermonuclear tests and the slow mixing of the ocean surface waters with the deeper layers.

  20. Water Resources Data Ohio: Water year 1994. Volume 1, Ohio River Basin excluding Project Data

    SciTech Connect (OSTI)

    1994-12-31

    The Water Resources Division of the US Geological Survey (USGS) in cooperation with State agencies, obtains a large amount of data each water year (a water year is the 12-month period from October 1 through September 30 and is identified by the calendar year in which it ends) pertaining to the water resources of Ohio. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, they are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for streamflow-gaging stations, miscellaneous sites, and crest-stage stations; (2) stage and content records for streams, lakes, and reservoirs; (3) water-quality data for streamflow-gaging stations, wells, synoptic sites, and partial-record sit -aid (4) water-level data for observation wells. Locations of lake-and streamflow-gaging stations, water-quality stations, and observation wells for which data are presented in this volume are shown in figures 8a through 8b. The data in this report represent that part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Ohio. This series of annual reports for Ohio began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report was changed to present (in two or three volumes) data on quantities of surface water, quality of surface and ground water, and ground-water levels.

  1. User`s Guide: Database of literature pertaining to the unsaturated zone and surface water-ground water interactions at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Hall, L.F.

    1993-05-01

    Since its beginnings in 1949, hydrogeologic investigations at the Idaho National Engineering Laboratory (INEL) have resulted in an extensive collection of technical publications providing information concerning ground water hydraulics and contaminant transport within the unsaturated zone. Funding has been provided by the Department of Energy through the Department of Energy Idaho Field Office in a grant to compile an INEL-wide summary of unsaturated zone studies based on a literature search. University of Idaho researchers are conducting a review of technical documents produced at or pertaining to the INEL, which present or discuss processes in the unsaturated zone and surface water-ground water interactions. Results of this review are being compiled as an electronic database. Fields are available in this database for document title and associated identification number, author, source, abstract, and summary of information (including types of data and parameters). AskSam{reg_sign}, a text-based database system, was chosen. WordPerfect 5.1{copyright} is being used as a text-editor to input data records into askSam.

  2. Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135

    SciTech Connect (OSTI)

    Michalski, Casey C.; DiSalvo, Rick; Boylan, John

    2013-07-01

    DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

  3. Decoupling Bulk and Surface Contributions in Water- Splitting Photocatalysts by In Situ Ultrafast Spectroscopy

    SciTech Connect (OSTI)

    Appavoo, Kannatassen; Mingzhao, Liu; Black, Charles T.; Sfeir, Matthew Y.

    2015-05-10

    By performing ultrafast emission spectroscopy in an operating, bias-controlled photoelectrochemical cell, we distinguish between bulk (charge transport) and surface (chemical reaction) recombination processes in a nanostructured photocatalyst and correlate its electronic properties directly with its incident-photon-to-current efficiency.

  4. Forest Irrigation Of Tritiated Water: A Proven Tritiated Water Management Tool

    SciTech Connect (OSTI)

    Vangelas, Karen; Blount, Gerald; Kmetz, Thomas; Prater, Phil

    2012-11-08

    Tritium releases from the Old Radioactive Waste Burial Ground (ORWBG) at the SRS in South Carolina has impacted groundwater and surface water. Tritiated groundwater plumes discharge into Fourmile Branch which is a small tributary of the Savannah River, a regional water resource. Taking advantage of the groundwater flow paths and the local topography a water collection and irrigation system was constructed and has been used at the SRS for over a decade to reduce these tritiated water releases to Fourmile Branch. The tritiated water is transferred to the atmosphere by evaporation from the pond surface, and after irrigation, wetted surface evaporation and evapotranspiration through the forest vegetation. Over the last decade SRS has irrigated over 120,000,000 gallons of tritiated water, which diverted over 6000 curies away from Fourmile Branch and the Savannah River. The system has been effective in reducing the flux of tritiated groundwater by approximately 70%. Mass balance studies of tritium in the forest soils before operations and over the last decade indicate that approximately 90% of the tritiated water that is irrigated is transferred to the atmosphere. Dose studies indicate that exposure to site workers and offsite maximally exposed individual is very low, approximately 6 mrem/year and 0.004 mrem/year, respectively. To consistently meet the flux reduction goal of tritium into Fourmile Branch optimization activities are proposed. These efforts will increase irrigation capacity and area. An additional 17 acres are proposed for an expansion of the area to be irrigated and a planting of approximately 40 acres of pine forest plantations is underway to expand irrigation capacity. Co-mingled with the tritiated groundwater are low concentrations of chlorinated volatile organic compounds (cVOCs), and 1,4-dioxane. Research studies and SRS field data indicate the forest irrigation system may have an added benefit of reducing the mass of these co-contaminants via

  5. Implementation of ORR Groundwater Strategy

    Office of Environmental Management (EM)

    ... modeling * Summary of progress in annual Remediation Effectiveness Report Groundwater Program ... * first sampling event in FY 2015 Q2 was successfully completed ...

  6. Stable isotope and groundwater flow dynamics of agricultural irrigation recharge into groundwater resources of the Central Valley, California

    SciTech Connect (OSTI)

    Davisson, M.L.; Criss, R.E.

    1995-01-01

    Intensive agricultural irrigation and overdraft of groundwater in the Central Valley of California profoundly affect the regional quality and availability of shallow groundwater resources. In the natural state, the {delta}{sup 18}O values of groundwater were relatively homogeneous (mostly -7.0 {+-} 0.5{per_thousand}), reflecting local meteoric recharge that slowly (1-3m/yr) flowed toward the valley axis. Today, on the west side of the valley, the isotope distribution is dominated by high {sup 18}O enclosures formed by recharge of evaporated irrigation waters, while the east side has bands of low {sup 18}O groundwater indicating induced recharge from rivers draining the Sierra Nevada mountains. Changes in {delta}{sup 18}O values caused by the agricultural recharge strongly correlate with elevated nitrate concentrations (5 to >100 mg/L) that form pervasive, non-point source pollutants. Small, west-side cities dependent solely on groundwater resources have experienced increases of >1.0 mg/L per year of nitrate for 10-30 years. The resultant high nitrates threaten the economical use of the groundwater for domestic purposes, and have forced some well shut-downs. Furthermore, since >80% of modern recharge is now derived from agricultural irrigation, and because modern recharge rates are {approximately}10 times those of the natural state, agricultural land retirement by urbanization will severely curtail the current safe-yields and promote overdraft pumping. Such overdrafting has occurred in the Sacramento metropolitan area for {approximately}40 years, creating cones of depression {approximately}25m deep. Today, groundwater withdrawal in Sacramento is approximately matched by infiltration of low {sup 18}O water (-11.0{per_thousand}) away from the Sacramento and American Rivers, which is estimated to occur at 100-300m/year from the sharp {sup 18}O gradients in our groundwater isotope map.

  7. Classification of groundwater at the Nevada Test Site

    SciTech Connect (OSTI)

    Chapman, J.B.

    1994-08-01

    Groundwater occurring at the Nevada Test Site (NTS) has been classified according to the ``Guidelines for Ground-Water Classification Under the US Environmental Protection Agency (EPA) Ground-Water Protection Strategy`` (June 1988). All of the groundwater units at the NTS are Class II, groundwater currently (IIA) or potentially (IIB) a source of drinking water. The Classification Review Area (CRA) for the NTS is defined as the standard two-mile distance from the facility boundary recommended by EPA. The possibility of expanding the CRA was evaluated, but the two-mile distance encompasses the area expected to be impacted by contaminant transport during a 10-year period (EPA,s suggested limit), should a release occur. The CRA is very large as a consequence of the large size of the NTS and the decision to classify the entire site, not individual areas of activity. Because most activities are located many miles hydraulically upgradient of the NTS boundary, the CRA generally provides much more than the usual two-mile buffer required by EPA. The CRA is considered sufficiently large to allow confident determination of the use and value of groundwater and identification of potentially affected users. The size and complex hydrogeology of the NTS are inconsistent with the EPA guideline assumption of a high degree of hydrologic interconnection throughout the review area. To more realistically depict the site hydrogeology, the CRA is subdivided into eight groundwater units. Two main aquifer systems are recognized: the lower carbonate aquifer system and the Cenozoic aquifer system (consisting of aquifers in Quaternary valley fill and Tertiary volcanics). These aquifer systems are further divided geographically based on the location of low permeability boundaries.

  8. Remediation of Organic and Inorganic Arsenic Contaminated Groundwater using a Nonocrystalline TiO2 Based Adsorbent

    SciTech Connect (OSTI)

    Jing, C.; Meng, X; Calvache, E; Jiang, G

    2009-01-01

    A nanocrystalline TiO2-based adsorbent was evaluated for the simultaneous removal of As(V), As(III), monomethylarsonic acid (MMA), and dimethylarsinic acid (DMA) in contaminated groundwater. Batch experimental results show that As adsorption followed pseudo-second order rate kinetics. The competitive adsorption was described with the charge distribution multi-site surface complexation model (CD-MUSIC). The groundwater containing an average of 329 ?g L-1 As(III), 246 ?g L-1 As(V), 151 ?g L-1 MMA, and 202 ?g L-1 DMA was continuously passed through a TiO2 filter at an empty bed contact time of 6 min for 4 months. Approximately 11 000, 14 000, and 9900 bed volumes of water had been treated before the As(III), As(V), and MMA concentration in the effluent increased to 10 ?g L-1. However, very little DMA was removed. The EXAFS results demonstrate the existence of a bidentate binuclear As(V) surface complex on spent adsorbent, indicating the oxidation of adsorbed As(III). A nanocrystalline TiO2-based adsorbent could be used for the simultaneous removal of As(V), As(III), MMA, and DMA in contaminated groundwater.

  9. Literature and data review for the surface-water pathway: Columbia River and adjacent coastal areas

    SciTech Connect (OSTI)

    Walters, W.H.; Dirkes, R.L.; Napier, B.A.

    1992-04-01

    As part of the Hanford Environmental Dose Reconstruction Project, Pacific Northwest Laboratory reviewed literature and data on radionuclide concentrations and distribution in the water, sediment, and biota of the Columbia River and adjacent coastal areas. Over 600 documents were reviewed including Hanford reports, reports by offsite agencies, journal articles, and graduate theses. Certain radionuclide concentration data were used in preliminary estimates of individual dose for the 1964--1966 time period. This report summarizes the literature and database review and the results of the preliminary dose estimates.

  10. Literature and data review for the surface-water pathway: Columbia River and adjacent coastal areas

    SciTech Connect (OSTI)

    Walters, W.H.; Dirkes, R.L.; Napier, B.A.

    1992-11-01

    As part of the Hanford Environmental Dose Reconstruction (HEDR) Project, Battelle, Pacific Northwest Laboratories reviewed literature and data on radionuclide concentrations and distribution in the water, sediment, and biota of the Columbia River and adjacent coastal areas. Over 600 documents were reviewed including Hanford reports, reports by offsite agencies, journal articles, and graduate theses. Radionuclide concentration data were used in preliminary estimates of individual dose for the period 1964 through 1966. This report summarizes the literature and database reviews and the results of the preliminary dose estimates.

  11. TWDB Groundwater Conservation Districts website | Open Energy...

    Open Energy Info (EERE)

    TWDB Groundwater Conservation Districts website Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: TWDB Groundwater Conservation...

  12. Groundwater Periodic Monitoring Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Groundwater Periodic Monitoring Reports Groundwater Periodic Monitoring Reports Topic: David Rhodes DOE, Provided Information on the Watersheds at LANL and the Monitoring Schedule ...

  13. California Groundwater Management Plans | Open Energy Information

    Open Energy Info (EERE)

    Groundwater Management Plans Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: California Groundwater Management PlansLegal Published...

  14. Anatomy of a Groundwater Uranium Plume

    Office of Energy Efficiency and Renewable Energy (EERE)

    Groundwater containing legacy contaminants (pollutants that remain after their sources have been controlled) moves through aquifers in response to the hydraulic gradient. As the groundwater moves,...

  15. 300 Area Process Trenches Groundwater Monitoring Plan

    SciTech Connect (OSTI)

    Lindberg, Jonathan W.; Chou, Charissa J.

    2001-08-13

    This document is a proposed groundwater monitoring plan for the 300 Area process trenches to comply with RCRA final status, corrective action groundwater monitoring.

  16. COMPARISON OF RESULTS FOR QUARTER 2 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

    SciTech Connect (OSTI)

    2013-01-21

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on November 15, 2012. Representatives from the U.S. Nuclear Regulatory Commission and Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and the results are compared using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that, at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2012). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, all DER values were less than 3 and results are consistent with low (e.g., background) concentrations.

  17. Groundwater surveillance plan for the Oak Ridge Reservation

    SciTech Connect (OSTI)

    Forstrom, J.M.; Smith, E.D.; Winters, S.L.; Haase, C.S.; King, H.L.; McMaster, W.M.

    1994-07-01

    US Department of Energy (DOE) Order 5400.1 requires the preparation of environmental monitoring plans and implementation of environmental monitoring programs for all DOE facilities. The order identifies two distinct components of environmental monitoring, namely effluent monitoring and environmental surveillance. In general, effluent monitoring has the objectives of characterizing contaminants and demonstrating compliance with applicable standards and permit requirements, whereas environmental surveillance has the broader objective of monitoring the effects of DOE activities on on- and off-site environmental and natural resources. The purpose of this document is to support the Environmental Monitoring Plan for the Oak Ridge Reservation (ORR) by describing the groundwater component of the environmental surveillance program for the DOE facilities on the ORR. The distinctions between groundwater effluent monitoring and groundwater surveillance have been defined in the Martin Marietta Energy Systems, Inc., Groundwater Surveillance Strategy. As defined in the strategy, a groundwater surveillance program consists of two parts, plant perimeter surveillance and off-site water well surveillance. This document identifies the sampling locations, parameters, and monitoring frequencies for both of these activities on and around the ORR and describes the rationale for the program design. The program was developed to meet the objectives of DOE Order 5400.1 and related requirements in DOE Order 5400.5 and to conform with DOE guidance on environmental surveillance and the Energy Systems Groundwater Surveillance Strategy.

  18. Intermittent Elevated Radium Concentrations in Coastal Plain Groundwater of South Carolina, U.S.A.

    SciTech Connect (OSTI)

    Denham, Miles; Millings, Margaret; Noonkester, Jay

    2005-09-22

    To learn the cause of intermittent radium concentrations in groundwater of Coastal Plain aquifers, 31 groundwater wells in South Carolina, U.S.A. were sampled for radium and other geochemical parameters. Sediments cored from near the well screens were also sampled to examine any relationship between sediment properties and radium concentration in the groundwater. Elevated radium concentrations only occurred in groundwater with low electrical conductivity and pH values below 6.3. The adsorption edge for radium on hematite--a major surface active mineral in these aquifers--is at a pH value of about 6. Near this value, small changes in pH can result in significant adsorption or desorption of radium. In groundwater with initially low alkalinity, small intermittent decreases in partial pressure of carbon dioxide in groundwater cause decreases in pH and desorption of radium. The result is intermittent elevated radium concentrations.

  19. Modelling On Photogeneration Of Hydroxyl Radical In Surface Waters And Its Reactivity Towards Pharmaceutical Wastes

    SciTech Connect (OSTI)

    Das, Radha; Vione, Davide; Rubertelli, Francesca; Maurino, Valter; Minero, Claudio; Barbati, Stephane; Chiron, Serge

    2010-10-26

    This paper reports a simple model to describe the formation and reactivity of hydroxyl radicals in the whole column of freshwater lakes. It is based on empirical irradiation data and is a function of the water chemical composition (the photochemically significant parameters NPOC, nitrate, nitrite, carbonate and bicarbonate), the lake conformation best expressed as the average depth, and the water absorption spectrum in a simplified Lambert-Beer approach. The purpose is to derive the lifetime of dissolved molecules, due to reaction with OH, on the basis of their second-order rate constants with the hydroxyl radical. The model was applied to two compounds of pharmaceutical wastes ibuprofen and carbamazepine, for which the second-order rate constants for reaction with the hydroxyl radical were measured by means of the competition kinetics with 2-propanol. The measured values of the rate constants are 1.0x10{sup 10} and 1.6x10{sup 10} M{sup -1} s{sup -1} for ibuprofen and carbamazepine, respectively. The model suggests that the lifetime of a given compound can be very variable in different lakes, even more than the lifetime of different compounds in the same lake. It can be concluded that as far as the reaction with OH, is concerned the concepts of photolability and photostability, traditionally attached to definite compounds, are ecosystem-dependent at least as much as they depend on the molecule under consideration.

  20. High-frequency monitoring of water fluxes and nutrient loads to assess the effects of controlled drainage on water storage and nutrient transport

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rozemeijer, J. C.; Visser, A.; Borren, W.; Winegram, M.; van der Velde, Y.; Klein, J.; Broers, H. P.

    2016-01-19

    High nitrogen (N) and phosphorus (P) fluxes from upstream agriculture threaten aquatic ecosystems in surface waters and estuaries, especially in areas characterized by high agricultural N and P inputs and densely drained catchments like the Netherlands. Controlled drainage has been recognized as an effective option to optimize soil moisture conditions for agriculture and to reduce unnecessary losses of fresh water and nutrients. This is achieved by introducing control structures with adjustable overflow levels into subsurface tube drain systems. A small-scale (1 ha) field experiment was designed to investigate the hydrological and chemical changes after introducing controlled drainage. Precipitation rates andmore » the response of water tables and drain fluxes were measured in the periods before the introduction of controlled drainage (2007–2008) and after (2009–2011). For the N and P concentration measurements, auto-analyzers for continuous records were combined with passive samplers for time-averaged concentrations at individual drain outlets. The experimental setup enabled the quantification of changes in the water and solute balance after introducing controlled drainage. The results showed that introducing controlled drainage reduced the drain discharge and increased the groundwater storage in the field. To achieve this, the overflow levels have to be elevated in early spring, before the drain discharge stops due to dryer conditions and falling groundwater levels. The groundwater storage in the field would have been larger if the water levels in the adjacent ditch were controlled as well by an adjustable weir. The N concentrations and loads increased, which was largely related to elevated concentrations in one of the three monitored tube drains. The P loads via the tube drains reduced due to the reduction in discharge after introducing controlled drainage. Furthermore, this may be counteracted by the higher groundwater levels and the larger contribution

  1. Use of Remote Technology in the Surface Water Environmental Monitoring Program at SRS Reducing Measurements in the Field - 13336

    SciTech Connect (OSTI)

    Eddy, T.; Terry, B.; Meyer, A.; Hall, J.; Allen, P.; Hughey, D.; Hartley, T.

    2013-07-01

    There are a wide range of sensor and remote technology applications available for use in environmental monitoring programs. Each application has its own set of limitations and can be challenging when attempting to utilize it under diverse environmental field conditions. The Savannah River Site Environmental Monitoring Program has implemented several remote sensing and surface water flow technologies that have increased the quality of the data while reducing the number of field measurements. Implementation of this technology reduced the field time for personnel that commute across the Savannah River Site (SRS) over a span of 310 square miles. The wireless surface water flow technology allows for immediate notification of changing field conditions or equipment failure thus reducing data-loss or erroneous field data and improving data-quality. This wireless flow technology uses the stage-to-flow methodology coupled with implementation of a robust highly accurate Acoustic Doppler Profiler system for measuring discharge under various field conditions. Savings for implementation of the wireless flow application and Flowlink{sup R} technology equates to approximately 1175 hours annually for the radiological liquid effluent and surveillance programs. The SonTek River Suveyor and Flowtracker technologies are utilized for calibration of the wireless flow monitoring devices in the site streams and validation of effluent flows at the SRS. Implementation of similar wireless devices is also planned in the National Pollutant Discharge Elimination System (NPDES) Storm-water Monitoring Program. SRS personnel have been developing a unique flow actuator device. This device activates an ISCO{sup TM} automated sampler under flowing conditions at storm-water outfall locations across the site. This technology is unique in that it was designed to be used under field conditions with rapid changes in flow and sedimentation where traditional actuators have been unsuccessful in tripping the

  2. Quantifying groundwater travel time near managed recharge operations using 35S as an intrinsic tracer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urióstegui, Stephanie H.; Bibby, Richard K.; Esser, Bradley K.; Clark, Jordan F.

    2016-04-23

    By identifying groundwater retention times near managed aquifer recharge (MAR) facilities is a high priority for managing water quality, especially for operations that incorporate recycled wastewater. In order to protect public health, California guidelines for Groundwater Replenishment Reuse Projects require a minimum 2–6 month subsurface retention time for recycled water depending on the level of disinfection, which highlights the importance of quantifying groundwater travel times on short time scales. This study developed and evaluated a new intrinsic tracer method using the naturally occurring radioisotope sulfur-35 (35S). The 87.5 day half-life of 35S is ideal for investigating groundwater travel times onmore » the <1 year timescale of interest to MAR managers. Natural concentrations of 35S found in water as dissolved sulfate (35SO4) were measured in source waters and groundwater at the Rio Hondo Spreading Grounds in Los Angeles County, CA, and Orange County Groundwater Recharge Facilities in Orange County, CA. 35SO4 travel times are comparable to travel times determined by well-established deliberate tracer studies. The study also revealed that 35SO4 in MAR source water can vary seasonally and therefore careful characterization of 35SO4 is needed to accurately quantify groundwater travel time. But, more data is needed to fully assess whether or not this tracer could become a valuable tool for managers.« less

  3. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15

    Single-column modeling (SCM) is one of the key elements of Atmospheric Radiation Measurement (ARM) research initiatives for the development and testing of various physical parameterizations to be used in general circulation models (GCMs). The data required for use with an SCM include observed vertical profiles of temperature, water vapor, and condensed water, as well as the large-scale vertical motion and tendencies of temperature, water vapor, and condensed water due to horizontal advection. Surface-based measurements operated at ARM sites and upper-air sounding networks supply most of the required variables for model inputs, but do not provide the horizontal advection term of condensed water. Since surface cloud radar and microwave radiometer observations at ARM sites are single-point measurements, they can provide the amount of condensed water at the location of observation sites, but not a horizontal distribution of condensed water contents. Consequently, observational data for the large-scale advection tendencies of condensed water have not been available to the ARM cloud modeling community based on surface observations alone. This lack of advection data of water condensate could cause large uncertainties in SCM simulations. Additionally, to evaluate GCMs’ cloud physical parameterization, we need to compare GCM results with observed cloud water amounts over a scale that is large enough to be comparable to what a GCM grid represents. To this end, the point-measurements at ARM surface sites are again not adequate. Therefore, cloud water observations over a large area are needed. The main goal of this project is to retrieve ice water contents over an area of 10 x 10 deg. surrounding the ARM sites by combining surface and satellite observations. Built on the progress made during previous ARM research, we have conducted the retrievals of 3-dimensional ice water content by combining surface radar/radiometer and satellite measurements, and have produced 3

  4. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The Environmental Monitoring Section of the Environmental and Health Protection (EHP) Department administers the Savannah River Site's Groundwater Monitoring Program. During fourth quarter 1989 (October--December), EHP conducted routine sampling of monitoring wells and drinking water locations. EHP collected the drinking water samples from Savannah River Site (SRS) drinking water systems supplied by wells. EHP established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria aid personnel in sample scheduling, interpretation of data, and trend identification. An explanation of flagging criteria for the fourth quarter is presented in the Flagging Criteria section of this document. All analytical results from fourth quarter 1989 are listed in this report, which is distributed to all waste-site custodians.

  5. Four-dimensional electrical conductivity monitoring of stage-driven river water intrusion: Accounting for water table effects using a transient mesh boundary and conditional inversion constraints

    SciTech Connect (OSTI)

    Johnson, Tim; Versteeg, Roelof; Thomle, Jon; Hammond, Glenn; Chen, Xingyuan; Zachara, John

    2015-08-01

    Our paper describes and demonstrates two methods of providing a priori information to the surface-based time-lapse three-dimensional electrical resistivity tomography (ERT) problem for monitoring stage-driven or tide-driven surface water intrusion into aquifers. First, a mesh boundary is implemented that conforms to the known location of the water table through time, thereby enabling the inversion to place a sharp bulk conductivity contrast at that boundary without penalty. Moreover, a nonlinear inequality constraint is used to allow only positive or negative transient changes in EC to occur within the saturated zone, dependent on the relative contrast in fluid electrical conductivity between surface water and groundwater. A 3-D field experiment demonstrates that time-lapse imaging results using traditional smoothness constraints are unable to delineate river water intrusion. The water table and inequality constraints provide the inversion with the additional information necessary to resolve the spatial extent of river water intrusion through time.

  6. Remedial Investigation work plan for Bear Creek Valley Operable Unit 4 (shallow groundwater in Bear Creek Valley) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    To effectively evaluate the cumulative impact of releases from multiple sources of contamination, a structured approach has been adopted for Oak Ridge Reservation (ORR) based on studies of the groundwater and surface water separate from studies of the sources. Based on the realization of the complexity of the hydrogeologic regime of the ORR, together with the fact that there are numerous sources contributing to groundwater contamination within a geographical area, it was agreed that more timely investigations, at perhaps less cost, could be achieved by separating the sources of contamination from the groundwater and surface water for investigation and remediation. The result will be more immediate attention [Records of Decision (RODS) for interim measures or removal actions] for the source Operable Units (OUs) while longer-term remediation investigations continue for the hydrogeologic regime`s, which are labeled as integrator OUs. This Remedial Investigation work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to the unit. Taking advantage of the historical data base and ongoing monitoring activities and applying the observational approach to focus data gathering activities will allow the Feasibility Study to evaluate all probable or likely alternatives.

  7. F-Area Acid/Caustic Basin groundwater monitoring report

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-03-01

    This progress report for fourth quarter 1991 and 1992 summary from the Savannah River Plant includes discussion on the following topics: groundwater monitoring data; analytical results exceeding standards; upgradient versus downgradient results; turbidity results exceeding standards; water elevations, flow directions, and flow rates.

  8. Inorganic soil and groundwater chemistry near Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Moore, G.K.

    1995-03-01

    Near-surface soils, boreholes, and sediments near the Paducah Gaseous Diffusion Plant (PGDP) were sampled in 1989-91 as were monitoring wells, TVA wells, and privately-owned wells. Most wells were sampled two or three times. The resulting chemical analyses have been published in previous reports and have been previously described (CH2M HILL 1991, 1992; Clausen et al. 1992). The two reports by CH2M HILL are controversial, however, because, the concentrations of some constituents were reported to exceed background levels or drinking water standards and because both on-site (within the perimeter fence at PGDP) and off-site pollution was reported to have occurred. The groundwater samples upon which these interpretations were based may not be representative, however. The CH2M HILL findings are discussed in the report. The purpose of this report is to characterize the inorganic chemistry of groundwater and soils near PGDP, using data from the CH2M HILL reports (1991, 1992), and to determine whether or not any contamination has occurred. The scope is limited to analysis and interpretation of data in the CH2M HILL reports because previous interpretations of these data may not be valid, because samples were collected in a relatively short period of time at several hundred locations, and because the chemical analyses are nearly complete. Recent water samples from the same wells were not considered because the characterization of inorganic chemistry for groundwater and soil requirements only one representative sample and an accurate analysis from each location.

  9. Groundwater Availability Within the Salton Sea Basin Final Report

    SciTech Connect (OSTI)

    Tompson, A; Demir, Z; Moran, J; Mason, D; Wagoner, J; Kollet, S; Mansoor, K; McKereghan, P

    2008-01-11

    It is widely recognized that increasing demands for water in Southern California are being affected by actions to reduce and redirect the amount of water imported from the Colorado River. In the Imperial Valley region, for example, import reductions will not only affect agricultural users but also could produce significant collateral impacts on the level and quality of water in the Salton Sea, its regional ecology, or even the long term air quality in the greater basin. The notion of using groundwater in the Imperial Valley as an additional source for agricultural or domestic needs, energy production, or Salton Sea restoration efforts, so as to offset reductions in imported water, is not a new concept. Even though it has been discussed recently (e.g., LLNL, 2002), the idea goes back, in part, to several studies performed by the US Department of Interior and other agencies that have indicated that there may be substantial, usable amounts of groundwater in some portions of the Imperial Valley. It has been estimated, for example, that between 1.1 and 3 billion acre-feet (AF) of groundwater lie within the extended, deep basin underlying the valley and Salton Sea region, even though much of it may be unrecoverable or too poor in its quality (Imperial County, 1997). This is a significant volume with respect to the total annual precipitation volume received in California, whose average is close to 200 million (or 0.2 billion) AF per year (DWR, 1998), and especially with respect to the total annual precipitation received in the Salton Sea watershed itself, which we estimate (Appendix A) to be approximately 2.5 million acre feet (MAF) per year. Clearly, a thorough appraisal of the groundwater resources in the Imperial Valley and Salton Sea region--i.e., an assessment of their overall physical availability--will be needed to determine how they can be used and managed to suit new or redirected demands in the region. Development of an improved or updated groundwater assessment

  10. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1995-01-24

    An apparatus and method are described for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants. An oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth. Withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene. 3 figures.

  11. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, Terry C.; Fliermans, Carl B.

    1995-01-01

    An apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants; an oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth; withholding it periodicially forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene.

  12. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1994-01-01

    Disclosed is an apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid (NF) is selected to simulated the growth and reproduction of indigenous subsurface microorganisms capable of degrading the contaminants; an oxygenated fluid (OF) is selected to create an aerobic environment with anaerobic pockets. NF is injected periodically while OF is injected continuously and both are extracted so that both are drawn across the plume. NF stimulates microbial colony growth; withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is acceptable. NF can be methane and OF be air, for stimulating production of methanotrophs to break down chlorohydrocarbons, especially TCE and tetrachloroethylene.

  13. Groundwater heat pumps: an examination of hydrogeologic, environmental, legal, and economic factors affecting their use. Volume II. Appendix D, state hydrogeologic descriptions and maps

    SciTech Connect (OSTI)

    Armitage, Dana M.; Bacon, Douglas J.; Massey-Norton, John T.; Miller, James M.

    1980-11-01

    This appendix to the groundwater heat pump report contains hydrogeologic descriptions of the 48 conterminous US with data on ground water quality.

  14. 2012 Groundwater Monitoring and Inspection Report Gnome-Coach, New Mexico, Site

    SciTech Connect (OSTI)

    2013-03-01

    Gnome-Coach was the site of a 3-kiloton underground nuclear test conducted in 1961. Surface and subsurface contamination resulted from the underground nuclear testing, post-test drilling, and a groundwater tracer test performed at the site. Surface reclamation and remediation began after the underground testing. A Completion Report was prepared, and the State of New Mexico is currently proceeding with a conditional certificate of completion for the surface. Subsurface corrective action activities began in 1972 and have generally consisted of annual sampling and monitoring of wells near the site. In 2008, the annual site inspections were refined to include hydraulic head monitoring and collection of samples from groundwater monitoring wells onsite using the low-flow sampling method. These activities were conducted during this monitoring period on January 18, 2012. Analytical results from this sampling event indicate that concentrations of tritium, strontium-90, and cesium-137 were generally consistent with concentrations from historical sampling events. The exceptions are the decreases in concentrations of strontium-90 in samples from wells USGS-4 and USGS-8, which were more than 2.5 times lower than last year's results. Well USGS-1 provides water for livestock belonging to area ranchers, and a dedicated submersible pump cycles on and off to maintain a constant volume in a nearby water tank. Water levels in wells USGS-4 and USGS-8 respond to the on/off cycling of the water supply pumping from well USGS-1. Well LRL-7 was not sampled in January, and water levels were still increasing when the transducer data were downloaded in September. A seismic reflection survey was also conducted this year. The survey acquired approximately 13.9 miles of seismic reflection data along 7 profiles on and near the site. These activities were conducted from February 23 through March 10, 2012. The site roads, monitoring well heads, and the monument at surface ground zero were in good

  15. Protective structures on the surface of zirconium components of light water reactor cores: Formation, testing, and prototype equipment

    SciTech Connect (OSTI)

    Begrambekov, L. B.; Gordeev, A. A.; Evsin, A. E. Ivanova, S. V.; Kaplevsky, A. S.; Sadovskiy, Ya. A.

    2015-12-15

    The results of tests of plasma treatment of zirconium and deposition of protective yttrium coatings used as the methods of protection of zirconium components of light water reactor cores against hydrogenation are detailed. The amount of hydrogen in the treated sample exposed to superheated steam for 2500 h at temperature T = 400°C and pressure p = 1 atm was five times lower than the corresponding value for the untreated one. The amount of hydrogen in the sample coated with yttrium remained almost unchanged in 4000 h of exposure. A plasma method for rapid testing for hydrogen resistance is proposed. The hydrogenation rate provided by this method is 700 times higher than that in tests with superheated steam. The results of preliminary experiments confirm the possibility of constructing a unit for batch processing of the surfaces of fuel rod claddings.

  16. Soil & Groundwater Home - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil & Groundwater Home Soil & Groundwater Home Annual Reports Environmental Data Access Administrative Record Soil & Groundwater Home Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size Soil & Groundwater Home Annual Reports Environmental Data Access Administrative Record Share on Last Updated 08/28/2016 4:15

  17. COMPARISON OF RESULTS FOR QUARTER 4 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUELS SERVICES SITE, ERWIN, TN

    SciTech Connect (OSTI)

    none,

    2013-08-15

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on June 12, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER ≤ 3 indicates at a 99% confidence interval that split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report specifies 95% confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0014 was the exception. The ORAU gross beta result of 6.30 ± 0.65 pCi/L from location NRD is well above NFS's non-detected result of 1.56 ± 0.59 pCi/L. NFS's data package includes no detected result for any radionuclide at location NRD. At NRC's request, ORAU performed gamma spectroscopic analysis of sample 5198W0014 to identify analytes contributing to the relatively elevated gross beta results. This analysis identified detected amounts of naturally-occurring constituents, most notably Ac-228 from the thorium decay series, and does not suggest the presence of site-related contamination.

  18. The Savannah River Site's Groundwater Monitoring Program, first quarter 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The Environmental Monitoring Section of the Environmental and Health Protection (EHP) Department administers the Savannah River Site's Groundwater Monitoring Program. During first quarter 1989 (January--March), EHP conducted routine sampling of monitoring wells and drinking water locations. EHP collected the drinking water samples from Savannah River Site (SRS) drinking water systems supplied by wells. EHP established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria aid personnel in sample scheduling, interpretation of data, and trend identification. The flagging criteria are based on detection limits, background levels in SRS groundwater, and drinking water standards. An explanation of flagging criteria for the first quarter is presented in the Flagging Criteria section of this document. All analytical results from first quarter 1989 are listed in this report, which is distributed to all waste-site custodians.

  19. The Savannah River Site's Groundwater Monitoring Program, third quarter 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The Environmental Monitoring Section of the Environmental and Health Protection (EHP) Department administers the Savannah River Site's Groundwater Monitoring Program. During third quarter 1989 (July--September), EHP conducted routine sampling of monitoring wells and drinking water locations. EHP collected the drinking water samples from Savannah River Site (SRS) drinking water systems supplied by wells. EHP established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria do not define contamination levels; instead they aid personnel in sample scheduling, interpretation of data, and trend identification. The flagging criteria are based on detection limits, background levels in SRS groundwater, and drinking water standards. An explanation of flagging criteria for the third quarter is presented in the Flagging Criteria section of this document. All analytical results from third quarter 1989 are listed in this report, which is distributed to all waste-site custodians.

  20. The Savannah River Site's Groundwater Monitoring Program, second quarter 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The Environmental Monitoring Section of the Environmental and Health Protection (EHP) Department administers the Savannah River Site's Groundwater Monitoring Program. During second quarter 1989 (April--June), EHP conducted routine sampling of monitoring wells and drinking water locations. EHP collected the drinking water samples from Savannah River Site (SRS) drinking water systems supplied by wells. EHP established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria aid personnel in sample scheduling, interpretation of data, and trend identification. The flagging criteria are based on detection limits, background levels in SRS groundwater, and drinking water standards. An explanation of flagging criteria for the second quarter is presented in the Flagging Criteria section of this document. All analytical results from second quarter 1989 are listed in this report, which is distributed to all waste-site custodians.

  1. Groundwater contamination. Volume 2: Management, containment, risk assessment and legal issues

    SciTech Connect (OSTI)

    Rail, C.D.

    2000-07-01

    This book explains in a comprehensive way the sources for groundwater contamination, the regulations governing it, and the technologies for abating it. Volume 2 discusses aquifer management, including technologies to control and stabilize multiple influxes into the water table. This volume outlines strategies for stormwater control and groundwater restoration and presents numerous case histories of site analysis and remediation based on DOE and state documents. Among the many new features of this edition are a full discussion of risk assessment, the preparation of groundwater protection plans, and references linking the text to over 2,300 water-related Web sites.

  2. Hanford Site groundwater monitoring for Fiscal Year 1997

    SciTech Connect (OSTI)

    Hartman, M.J.; Dresel, P.E.

    1998-02-01

    This report presents the results of groundwater and vadose-zone monitoring for fiscal year (FY) 1997 on the Hanford Site, Washington. Soil-vapor extraction continued in the 200-West Area to remove carbon tetrachloride from the vadose zone. Characterization and monitoring of the vadose zone comprised primarily spectral gamma logging, soil-vapor monitoring, and analysis and characterization of sediments sampled below a vadose-zone monitoring well. Source-term analyses for strontium-90 in 100-N Area vadose-zone sediments were performed using recent groundwater-monitoring data and knowledge of strontium`s ion-exchange properties. Water-level monitoring was performed to evaluate groundwater-flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Water levels over most of the Hanford Site continued to decline between June 1996 and June 1997. Water levels near the Columbia River increased during this period because the river stage was unusually high. Groundwater chemistry was monitored to track the extent of contamination, to note trends, and to identify emerging groundwater-quality problems. The most widespread radiological contaminant plumes were tritium and iodine-129. Concentrations of technetium-99, uranium, strontium-90, and carbon-14 also exceeded drinking water standards in smaller plumes. Plutonium and cesium-137 exceeded standards only near the 216-B-5 injection well. Derived concentration guide levels specified in U.S. Department of Energy Order 5400.5 were exceeded for tritium, uranium, strontium-90, and plutonium in small plumes or single wells. Nitrate is the most extensive chemical contaminant. Carbon tetrachloride, chloroform, chromium, cis-1,2-dichloroethylene, fluoride, and trichloroethylene also were present in smaller areas at levels above their maximum contaminant levels. Cyanide concentrations were elevated in one area but were below the maximum contaminant level.

  3. A perimeter-based groundwater protection strategy for waste management units at a petroleum refinery

    SciTech Connect (OSTI)

    Wenzlau, R.K.

    1996-12-01

    This article presents a groundwater management strategy and its application to regulatory compliance for the Shell Oil Company Martinez Manufacturing Complex, a refinery located within northern California. The purpose of the strategy is to protect the beneficial uses of groundwater which are present beyond the facility boundary while recognizing the occurrence of limited degradation of groundwater upgradient of the perimeter. The strategy applies perimeter-based groundwater monitoring and control to two general sources of groundwater quality degradation: historic spill and leak sites and inactive waste management units. To regulate the groundwater contaminant plumes originating form historic spill and leak sites the California Regional Water Quality Control Board (Regional Board) has issued Site Cleanup Requirements (SCR). To satisfy the SCR Shell developed in 1989 a Basin Boundary Control Plan as the first implementation of the groundwater strategy. To regulate groundwater quality impacts from solid waste management units, the Regional Board issues Waste Discharge Requirements (WDR). In 1995 the Regional Board issued revised WDR that established consistency between waste management unit regulation and the facility groundwater management strategy. The Regional Board made two findings that allowed this consistency. The first finding was that the Points of Compliance for all 23 solid waste management units are at the down-gradient perimeter of the facility. The second finding was that all waste management units were within corrective action, regardless of whether a known release of waste constituents occurred from a given waste unit.

  4. Groundwater Report Goes Online, Interactive

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – EM’s Richland Operations Office (RL) has moved its 1,200-page annual report on groundwater monitoring to a fully online and interactive web application.

  5. NNSS Hosts Groundwater Open House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Survey of the Bay Area NNSS Hosts Groundwater Open House A RSL helicopter spent part of August conducting aerial radiation flyovers in the California Bay Area. The team rocked the competition and chiseled out an impressive second place finish recently in the Security Protection Officer competition. Groundwater was the topic of discussion at a recent open house. See page 12. See page 5. See page 8. Enterprise Publication "ONEVOICE" Replaces Spotlight and SiteLines The Nevada National

  6. Groundwater recharge from Long Lake, Indiana Dunes National Lakeshore

    SciTech Connect (OSTI)

    Isiorho, S.A.; Beeching, F.M. (Indiana Univ., Fort Wayne, IN (United States). Geosciences Dept.); Whitman, R.L.; Stewart, P.M. (National Park Services, Porter, IN (United States). Indiana Dunes National Lakeshore); Gentleman, M.A.

    1992-01-01

    Long Lake, located between Lake Michigan and the Dune-complexes of Indiana Dunes, was formed during Pleistocene and Holocene epochs. The lake is currently being studied to understand the detailed hydrology. One of the objective of the study is to understand the hydrologic relationship between the lake and a water treatment holding pond to the northeast. Understanding the water movement between the two bodies of water, if any, would be very important in the management and protection of nature preserves in the area. Seepage measurement and minipiezometric tests indicate groundwater recharge from Long Lake. The groundwater recharge rate is approximately 1.40 to 22.28 x 10[sup [minus]4] m/day. An estimate of the amount of recharge of 7.0 x 10[sup 6] m[sup 3]/y may be significant in terms of groundwater recharge of the upper aquifer system of the Dunes area. The water chemistry of the two bodies of water appears to be similar, however, the pH of the holding pond is slightly alkaline (8.5) while that of Long Lake is less alkaline (7.7). There appears to be no direct contact between the two bodies of water (separated by approximately six meters of clay rich sediment). The geology of the area indicates a surficial aquifer underlying Long Lake. The lake should be regarded as a recharge area and should be protected from pollutants as the degradation of the lake would contaminate the underlying aquifer.

  7. Water resources development in Santa Clara Valley, California: insights into the human-hydrologic relationship

    SciTech Connect (OSTI)

    Reynolds, Jesse L.; Narasimhan, T.N.

    2000-06-01

    Groundwater irrigation is critical to food production and, in turn, to humankind's relationship with its environment. The development of groundwater in Santa Clara Valley, California during the early twentieth century is instructive because (1) responses to unsustainable resource use were largely successful; (2) the proposals for the physical management of the water, although not entirely novel, incorporated new approaches which reveal an evolving relationship between humans and the hydrologic cycle; and (3) the valley serves as a natural laboratory where natural (groundwater basin, surface watershed) and human (county, water district) boundaries generally coincide. Here, I investigate how water resources development and management in Santa Clara Valley was influenced by, and reflective of, a broad understanding of water as a natural resource, including scientific and technological innovations, new management approaches, and changing perceptions of the hydrologic cycle. Market demands and technological advances engendered reliance on groundwater. This, coupled with a series of dry years and laissez faire government policies, led to overdraft. Faith in centralized management and objective engineering offered a solution to concerns over resource depletion, and a group dominated by orchardists soon organized, fought for a water conservation district, and funded an investigation to halt the decline of well levels. Engineer Fred Tibbetts authored an elaborate water salvage and recharge plan that optimized the local water resources by integrating multiple components of the hydrologic cycle. Informed by government investigations, groundwater development in Southern California, and local water law cases, it recognized the limited surface storage possibilities, the spatial and temporal variability, the relatively closed local hydrology, the interconnection of surface and subsurface waters, and the value of the groundwater basin for its storage, transportation, and treatment

  8. Expediting Groundwater Sampling at Hanford and Making It Safer

    SciTech Connect (OSTI)

    Connell, Carl W. Jr.; Carr, Jennifer S.; Hildebrand, R. Douglas; Schatz, Aaron L.; Conley, S. F.; Brown, W. L.

    2013-01-22

    The CH2M HILL Plateau Remediation Company (CHPRC) manages the groundwatermonitoring programs at the Department of Energy's 586-square-mile Hanford site in southeastern Washington state. These programs are regulated by the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), and the Atomic Energy Act (AEA). The purpose of monitoring is to track existing groundwater contamination from past practices, as well as other potential contamination that might originate from RCRA treatment, storage, and disposal (TSD) facilities. An integral part of the groundwater-monitoring program involves taking samples of the groundwater and measuring the water levels in wells scattered across the site. Each year, more than 1,500 wells are accessed for a variety of reasons.

  9. Tracer advection by steady groundwater flow in a stratified aquifer

    SciTech Connect (OSTI)

    Sposito, Garrison; Weeks, Scott W.

    1997-01-02

    The perfectly stratified aquifer has often been investigated as a simple, tractable model for exploring new theoretical issues in subsurface hydrology. Adopting this approach, we show that steady groundwater flows in the perfectly stratified aquifer are always confined to a set of nonintersecting permanent surfaces, on which both streamlines and vorticity lines lie. This foliation of the flow domain exists as well for steady groundwater flows in any isotropic, spatially heterogeneous aquifer. In the present model example it is a direct consequence of the existence of a stream function, we then demonstrate that tracer plume advection by steady groundwater flow in a perfectly stratified aquifer is never ergodic, regardless of the initial size of the tracer plume. This nonergodicity, which holds also for tracer advection in any isotropic, spatially heterogeneous aquifer, implies that stochastic theories of purely advective tracer plume movement err in assuming ergodic behavior to simplify probabilistic calculations of plume spatial concentration moments.

  10. Addressing Chromium in Groundwater

    Office of Energy Efficiency and Renewable Energy (EERE)

    From 1956 to 1972, a non-nuclear power plant at Los Alamos National Laboratory periodically flushed water out of its cooling towers into Sandia Canyon. The water contained chromium, which was commonly used throughout the industry as a corrosion inhibitor in cooling tower systems.

  11. Communication: Salt-induced water orientation at a surface of non-ionic surfactant in relation to a mechanism of Hofmeister effect

    SciTech Connect (OSTI)

    Hishida, Mafumi; Kaneko, Yohei; Okuno, Masanari; Yamamura, Yasuhisa; Ishibashi, Taka-aki; Saito, Kazuya

    2015-05-07

    The behavior of water molecules at the surface of nonionic surfactant (monomyristolein) and effects of monovalent ions on the behavior are investigated using the heterodyne-detected vibrational sum frequency generation spectroscopy. It is found that water molecules at the surface are oriented with their hydrogen atoms pointing to the bulk, and that the degree of orientation depends on the anion strongly but weakly on the cation. With measured surface potentials in those saline solutions, it is concluded that the heterogeneous distribution of anions and cations in combination with the nonionic surfactant causes the water orientation. This heterogeneous distribution well explains the contrasting order of anions and cations with respect to the ion size in the Hofmeister series.

  12. EM Soil and Groundwater Database Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EM Soil and Groundwater Database Reports EM Soil and Groundwater Database Reports Brookhaven National Laboratory - HFBR Tritium Groundwater Database Report - Brookhaven National ...

  13. Field site investigation: Effect of mine seismicity on groundwater hydrology

    SciTech Connect (OSTI)

    Ofoegbu, G.I.; Hsiung, S.; Chowdhury, A.H.; Philip, J.

    1995-04-01

    The results of a field investigation on the groundwater-hydrologic effect of mining-induced earthquakes are presented in this report. The investigation was conducted at the Lucky Friday Mine, a silver-lead-zinc mine in the Coeur d`Alene Mining District of Idaho. The groundwater pressure in sections of three fracture zones beneath the water table was monitored over a 24-mo period. The fracture zones were accessed through a 360-m-long inclined borehole, drilled from the 5,700 level station of the mine. The magnitude, source location, and associated ground motions of mining-induced seismic events were also monitored during the same period, using an existing seismic instrumentation network for the mine, augmented with additional instruments installed specifically for the project by the center for Nuclear Waste Regulatory Analyses (CNWRA). More than 50 seismic events of Richter magnitude 1.0 or larger occurred during the monitoring period. Several of these events caused the groundwater pressure to increase, whereas a few caused it to decrease. Generally, the groundwater pressure increased as the magnitude of seismic event increased; for an event of a given magnitude, the groundwater pressure increased by a smaller amount as the distance of the observation point from the source of the event increased. The data was examined using regression analysis. Based on these results, it is suggested that the effect of earthquakes on groundwater flow may be better understood through mechanistic modeling. The mechanical processes and material behavior that would need to be incorporated in such a model are examined. They include a description of the effect of stress change on the permeability and water storage capacity of a fracture rock mass; transient fluid flow; and the generation and transmission of seismic waves through the rock mass.

  14. Par Pond water balance

    SciTech Connect (OSTI)

    Hiergesell, R.A.; Dixon, K.L.

    1996-06-01

    A water budget for the Par Pond hydrologic system was established in order to estimate the rate of groundwater influx to Par Pond. This estimate will be used in modeling exercises to predict Par Pond reservoir elevation and spillway discharge in the scenario where Savannah River water is no longer pumped and discharged into Par Pond. The principal of conservation of mass was used to develop the water budget, where water inflow was set equal to water outflow. Components of the water budget were identified, and the flux associated with each was determined. The water budget was considered balanced when inflow and outflow summed to zero. The results of this study suggest that Par Pond gains water from the groundwater system in the upper reaches of the reservoir, but looses water to the groundwater system near the dam. The rate of flux of groundwater from the water table aquifer into Par Pond was determined to be 13 cfs. The rate of flux from Par Pond to the water table aquifer near the dam was determined to be 7 cfs.

  15. COMPARISON OF RESULTS FOR QUARTER 3 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

    SciTech Connect (OSTI)

    none,

    2013-05-28

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on March 20, 2013. Representatives from the U.S. Nuclear Regulatory Commission and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0012 was the exception. The ORAU result of 9.23 ± 0.73 pCi/L from location MCD is well above NFS's result of -0.567 ± 0.63 pCi/L (non-detected). NFS's data package included a detected result for U-233/234, but no other uranium or plutonium detection, and nothing that would suggest the presence of beta-emitting radionuclides. The ORAU laboratory reanalyzed sample 5198W0012 using the remaining portion of the sample volume and a result of 11.3 ± 1.1 pCi/L was determined. As directed, the laboratory also counted the filtrate using gamma spectrometry analysis and

  16. Environmental impact of APC residues from municipal solid waste incineration: Reuse assessment based on soil and surface water protection criteria

    SciTech Connect (OSTI)

    Quina, Margarida J.; Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

    2011-09-15

    Highlights: > The Dutch Building Material Decree (BMD) was used to APC residues from MSWI. > BMD is a straightforward tool to calculate expectable loads to the environment of common pollutants. > Chloride load to the environment lead to classification of building material not allowed. > At least a pre-treatment (e.g. washing) is required in order to remove soluble salts. > The stabilization with phosphates or silicates eliminate the problem of heavy metals. - Abstract: Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of 'building material not allowed'. The treatments with phosphates or silicates are able to solve the problem of heavy metals, but

  17. A Coupled Modeling System to Simulate Water Resources in the Rio Grande Basin

    SciTech Connect (OSTI)

    Bossert, J.E.; Breshears, D.D.; Campbell, K.; Costigan, K.R.; Greene, R.K.; Keating, E.H.; Kleifgen, L.M.; Langley, D.L.; Martens, S.N.; Sanderson, J.G.; Springer, E.P.; Stalker, J.R.; Tartakovsky, D.M.; Winter, C.L.; Zyvoloski, G.A.

    1999-01-11

    Limited availability of fresh water in arid and semi-arid regions of the world requires prudent management strategies from accurate, science-based assessments. These assessments demand a thorough understanding of the hydrologic cycle over long time periods within the individual water-sheds that comprise large river basins. Measurement and simulation of the hydrologic cycle is a tremendous challenge, involving a coupling between global to regional-scale atmospheric precipitation processes with regional to local-scale land surface and subsurface water transport. Los Alamos National Laboratory is developing a detailed modeling system of the hydrologic cycle and applying this tool at high resolution to assess the water balance within the upper Rio Grande river basin. The Rio Grande is a prime example of a river system in a semiarid environment, with a high demand from agricultural, industrial, recreational, and municipal interests for its water supply. Within this river basin, groundwater supplies often augment surface water. With increasing growth projected throughout the river basin, however, these multiple water users have the potential to significantly deplete groundwater resources, thereby increasing the dependence on surface water resources.

  18. Hanford Site Groundwater Monitoring for Fiscal Year 1998

    SciTech Connect (OSTI)

    Hartman, M.J.

    1999-03-24

    This report presents the results of groundwater and vadose-zone monitoring and remediation for fiscal year (FY) 1998 on the Word Site, Washington. Soil-vapor extraction in the 200-West Area removed 777 kg of carbon tetrachloride in FY 1998, for a total of 75,490 kg removed since remediation began in 1992. Spectral gamma logging and evaluation of historical gross gamma logs near tank farms and liquid-disposal sites in the 200 Areas provided information on movement of contaminants in the vadose zone. Water-level monitoring was performed to evaluate groundwater-flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Water levels over most of the Hanford Site continued to decline between June 1997 and June 1998. The most widespread radiological contaminant plumes in groundwater were tritium and iodine-129. Concentrations of technetium-99, uranium, strontium-90, and carbon-14 also exceeded drinking water standards in smaller plumes. Plutonium and cesium-137 exceeded standards only near the 216-B-5 injection well. Derived concentration guide levels specified in U.S. Department of Energy Order 5400.5 were exceeded for tritium, uranium, strontium-90, and plutonium in small plumes or single wells. One well completed in the basalt-confined aquifer beneath the 200-East Area exceeded the drinking water standard for technetium-99. Nitrate is the most extensive chemical contaminant. Carbon tetrachloride, chloroform, chromium, cis-l, Z-dichloroethylene, fluoride, and trichloroethylene also were present in smaller areas at levels above their maximum contaminant levels. Cyanide concentrations were elevated in one area but were below the maximum contaminant level. Tetrachloroethylene exceeded its maximum contaminant level in several wells in the 300 Area for the first time since the 1980s. Metals such as aluminum, cadmium, iron, manganese, and nickel exceeded their maximum contaminant levels in filtered samples from numerous

  19. Use of serospecific biocarrier compositions for enhanced biodegradation and bioremediation of groundwater

    DOE Patents [OSTI]

    Fliermans, C.B.

    1995-01-01

    A composition and method for using the composition for degrading pollutants in-situ is presented. The composition comprises a biocarrier coated with an antigen-specific antibody that attracts and binds pollution-degrading antigens. The biocarrier, which is preferably in the form of glass microspheres, is coated with one or more strains of antibody. The antibody may be placed into the ground in or near the source of pollutants where it may attract antigens present and bind them, or the antibodies may be first exposed to the antigens and then placed in the ground. Alternatively, the coated biocarriers may be used to degrade pollutants in ground water pumped to the surface and through a biofilter containing the biocarriers. The remediated groundwater can then be returned to the soil.

  20. Use of serospecific biocarrier compositions for enhanced biodegradation and bioremediation of groundwater

    DOE Patents [OSTI]

    Fliermans, Carl B.

    1999-01-01

    A composition and method for using the composition for degrading pollutants in-situ. The composition comprises a biocarrier coated with an antigen-specific antibody that attracts and binds pollution-degrading antigens. The biocarrier, which is preferably in the form of glass microspheres, is coated with one or more strains of antibody. The antibody may be placed into the ground in or near the source of pollutants where it may attract antigens present and bind them, or the antibodies may be first exposed to the antigens and then placed in the ground. Alternatively, the coated biocarriers may be used to degrade pollutants in ground water pumped to the surface and through a biofilter containing the biocarriers. The remediated groundwater can then be returned to the soil.

  1. Groundwater quality assessment plan for the 1324-N/NA Site: Phase 1 (first determination)

    SciTech Connect (OSTI)

    Hartman, M.J.

    1998-05-01

    The 1324-N Surface Impoundment and 1324-NA Percolation Pond (1324-N/NA Site) are treatment/storage/disposal sites regulated under the Resource Conservation and Recovery Act of 1976 (RCRA). They are located in the 100-N Area of the Hanford Site, and were used to treat and dispose of corrosive waste from a water treatment plant. Groundwater monitoring under an interim-status detection program compared indicator parameters from downgradient wells to background values established from an upgradient well. One of the indicator parameters, total organic carbon (TOC), exceeded its background value in one downgradient well, triggering an upgrade from a detection program to an assessment program. This plan presents the first phase of the assessment program.

  2. Evapotranspiration Within the Groundwater Model Domain of the Tuba City, Arizona, Disposal Site Interim Report

    SciTech Connect (OSTI)

    None, None

    2015-03-01

    The revised groundwater model includes estimates of evapotranspiration (ET). The types of vegetation and the influences of ET on groundwater hydrology vary within the model domain. Some plant species within the model domain, classified as phreatophytes, survive by extracting groundwater. ET within these plant communities can result in a net discharge of groundwater if ET exceeds precipitation. Other upland desert plants within the model domain survive on meteoric water, potentially limiting groundwater recharge if ET is equivalent to precipitation. For all plant communities within the model domain, excessive livestock grazing or other disturbances can tip the balance to a net groundwater recharge. This task characterized and mapped vegetation within the groundwater model domain at the Tuba City, Arizona, Site, and then applied a remote sensing algorithm to estimate ET for each vegetation type. The task was designed to address five objectives: 1. Characterize and delineate different vegetation or ET zones within the groundwater model domain, focusing on the separation of plant communities with phreatophytes that survive by tapping groundwater and upland plant communities that are dependent on precipitation. 2. Refine a remote sensing method, developed to estimate ET at the Monument Valley site, for application at the Tuba City site. 3. Estimate recent seasonal and annual ET for all vegetation zones, separating phreatophytic and upland plant communities within the Tuba City groundwater model domain. 4. For selected vegetation zones, estimate ET that might be achieved given a scenario of limited livestock grazing. 5. Analyze uncertainty of ET estimates for each vegetation zone and for the entire groundwater model domain.

  3. Quantum calculations of the IR spectrum of liquid water using ab initio and model potential and dipole moment surfaces and comparison with experiment

    SciTech Connect (OSTI)

    Liu, Hanchao; Wang, Yimin; Bowman, Joel M.

    2015-05-21

    The calculation and characterization of the IR spectrum of liquid water have remained a challenge for theory. In this paper, we address this challenge using a combination of ab initio approaches, namely, a quantum treatment of IR spectrum using the ab initio WHBB water potential energy surface and a refined ab initio dipole moment surface. The quantum treatment is based on the embedded local monomer method, in which the three intramolecular modes of each embedded H{sub 2}O monomer are fully coupled and also coupled singly to each of six intermolecular modes. The new dipole moment surface consists of a previous spectroscopically accurate 1-body dipole moment surface and a newly fitted ab initio intrinsic 2-body dipole moment. A detailed analysis of the new dipole moment surface in terms of the coordinate dependence of the effective atomic charges is done along with tests of it for the water dimer and prism hexamer double-harmonic spectra against direct ab initio calculations. The liquid configurations are taken from previous molecular dynamics calculations of Skinner and co-workers, using the TIP4P plus E3B rigid monomer water potential. The IR spectrum of water at 300 K in the range of 0–4000 cm{sup −1} is calculated and compared with experiment, using the ab initio WHBB potential and new ab initio dipole moment, the q-TIP4P/F potential, which has a fixed-charged description of the dipole moment, and the TTM3-F potential and dipole moment surfaces. The newly calculated ab initio spectrum is in very good agreement with experiment throughout the above spectral range, both in band positions and intensities. This contrasts to results with the other potentials and dipole moments, especially the fixed-charge q-TIP4P/F model, which gives unrealistic intensities. The calculated ab initio spectrum is analyzed by examining the contribution of various transitions to each band.

  4. A NEW SOURCE OF CO{sub 2} IN THE UNIVERSE: A PHOTOACTIVATED ELEY-RIDEAL SURFACE REACTION ON WATER ICES

    SciTech Connect (OSTI)

    Yuan, Chunqing; Cooke, Ilsa R.; Yates, John T. Jr.

    2014-08-20

    CO{sub 2} is one of the most abundant components of ices in the interstellar medium; however, its formation mechanism has not been clearly identified. Here we report an experimental observation of an Eley-Rideal-type reaction on a water ice surface, where CO gas molecules react by direct collisions with surface OH radicals, made by photodissociation of H{sub 2}O molecules, to produce CO{sub 2} ice on the surface. The discovery of this source of CO{sub 2} provides a new mechanism to explain the high relative abundance of CO{sub 2} ice in space.

  5. Environmental Tracers for Determining Water Resource Vulnerability to Climate Change

    SciTech Connect (OSTI)

    Singleton, M

    2009-07-08

    to alpine stream baseflow. This research is showing that groundwater in alpine areas spends between a few years to several decades in the saturated zone below the surface, before feeding into streams or being pumped for use. This lag time may act to reduce the impact on water resources from extreme wet or dry years. Furthermore, our measurements show that the temperature of water when it reaches the water table during recharge is 4 to 9 degrees higher than would be expected for direct influx of snowmelt, and that recharge likely occurs over diffuse vegetated areas, rather than along exposed rock faces and fractures. These discoveries have implications for how alpine basins will respond to climate effects that lead to more rain than snow and earlier snow pack melting.

  6. Fiscal Year 2009 Annual Report for Operable Unit 3-14, Tank Farm Soil and INTEC Groundwater

    SciTech Connect (OSTI)

    Forsythe, Howard S.

    2010-04-10

    This annual report summarizes maintenance, monitoring, and inspection activities performed to implement the selected remedy for Waste Area Group 3, Operable Unit 3-14, Tank Farm soil and groundwater at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory Site. Results from monitoring perched water and groundwater at the Idaho Nuclear Technology and Engineering Center are also presented.

  7. Final report : groundwater monitoring at Morrill, Kansas, in September 2005 and March 2006, with expansion of the monitoring network in January 2006.

    SciTech Connect (OSTI)

    LaFreniere, L. M.; Environmental Science Division

    2007-06-30

    evaluation of the potential for reductive dechlorination processes. Preliminary screening of groundwater parameters provided inadequate evidence that reductive dechlorination of carbon tetrachloride is taking place at some locations on the former CCC/USDA property. Groundwater levels measured manually in October 2005, March 2006, and June 2006 were used to map the potentiometric surface at Morrill. The results were generally consistent with each other and with previous measurements, indicating a groundwater flow direction to the south-southeast from the former CCC/USDA facility. Data recorders installed in wells MW1S-MW8S in July 2004 are gathering long-term data on the groundwater elevation and gradient. Data downloaded in August 2004, March 2005, October 2005, and June 2006 indicate that two relatively upgradient wells near the former CCC/USDA facility responded distinctly to apparent rainfall/recharge events. In contrast, two downgradient wells south of the former facility showed virtually no response, probably because of the damping influence of the nearby surface drainages and shallow groundwater at their locations. The first two monitoring events of the planned two-year monitoring program for Morrill have demonstrated no clear pattern of changes in carbon tetrachloride concentrations, though the contaminated zone has expanded toward the intermittent stream. Argonne recommends that the monitoring program continue as approved and that surface water samples be collected in future monitoring events (September 2006, March 2007, and September 2007).

  8. Hanford Site Groundwater Monitoring for Fiscal Year 2003

    SciTech Connect (OSTI)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2004-04-12

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2003 (October 2002 through September 2003) on the U.S. Department of Energy's Hanford Site, Washington. The most extensive contaminant plumes in groundwater are tritium, iodine-129, and nitrate, which all had multiple sources and are very mobile in groundwater. The largest portions of these plumes are migrating from the central Hanford Site to the southeast, toward the Columbia River. Concentrations of tritium, nitrate, and some other contaminants continued to exceed drinking water standards in groundwater discharging to the river in some locations. However, contaminant concentrations in river water remained low and were far below standards. Carbon tetrachloride and associated organic constituents form a relatively large plume beneath the central part of the Hanford Site. Hexavalent chromium is present in smaller plumes beneath the reactor areas along the river and beneath the central part of the site. Strontium-90 exceeds standards beneath all but one of the reactor areas, and technetium-99 and uranium are present in the 200 Areas. Uranium exceeds standards in the 300 Area in the south part of the Hanford Site. Minor contaminant plumes with concentrations greater than standards include carbon-14, cesium-137, cis-1,2-dichloroethene, cyanide, fluoride, plutonium, and trichloroethene. Monitoring for the ''Comprehensive Environmental Response, Compensation, and Liability Act'' is conducted in 11 groundwater operable units. The purpose of this monitoring is to define and track plumes and to monitor the effectiveness of interim remedial actions. Interim groundwater remediation in the 100 Areas continued with the goal of reducing the amount of chromium (100-K, 100-D, and 100-H) and strontium-90 (100-N) reaching the Columbia River. The objective of two interim remediation systems in the 200 West Area is to prevent the spread of carbon tetrachloride and technetium-99

  9. Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO{sub 2} using tetrakis(dimethylamido)titanium and water

    SciTech Connect (OSTI)

    Sperling, Brent A. Hoang, John; Kimes, William A.; Maslar, James E.; Steffens, Kristen L.; Nguyen, Nhan V.

    2014-05-15

    Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120 ms. At 190 °C and 240 °C, a decrease in the absorption from adsorbed TDMAT is observed without any evidence of an adsorbed product. Ex situ measurements indicate that this behavior is not associated with an increase in the impurity concentration or a dramatic change in the growth rate. A desorbing decomposition product is consistent with these observations. RAIRS also indicates that dehydroxylation of the growth surface occurs only among one type of surface hydroxyl groups. Molecular water is observed to remain on the surface and participates in reactions even at a relatively high temperature (110 °C) and with long purge times (30 s)

  10. 2012 Groundwater Monitoring Report Central Nevada Test Area, Subsurface Corrective Action Unit 443

    SciTech Connect (OSTI)

    2013-04-01

    The Central Nevada Test Area was the site of a 0.2- to 1-megaton underground nuclear test in 1968. The surface of the site has been closed, but the subsurface is still in the corrective action process. The corrective action alternative selected for the site was monitoring with institutional controls. Annual sampling and hydraulic head monitoring are conducted as part of the subsurface corrective action strategy. The site is currently in the fourth year of the 5-year proof-of-concept period that is intended to validate the compliance boundary. Analytical results from the 2012 monitoring are consistent with those of previous years. Tritium remains at levels below the laboratory minimum detectable concentration in all wells in the monitoring network. Samples collected from reentry well UC-1-P-2SR, which is not in the monitoring network but was sampled as part of supplemental activities conducted during the 2012 monitoring, indicate concentrations of tritium that are consistent with previous sampling results. This well was drilled into the chimney shortly after the detonation, and water levels continue to rise, demonstrating the very low permeability of the volcanic rocks. Water level data from new wells MV-4 and MV-5 and recompleted well HTH-1RC indicate that hydraulic heads are still recovering from installation and testing. Data from wells MV-4 and MV-5 also indicate that head levels have not yet recovered from the 2011 sampling event during which several thousand gallons of water were purged. It has been recommended that a low-flow sampling method be adopted for these wells to allow head levels to recover to steady-state conditions. Despite the lack of steady-state groundwater conditions, hydraulic head data collected from alluvial wells installed in 2009 continue to support the conceptual model that the southeast-bounding graben fault acts as a barrier to groundwater flow at the site.

  11. Isobaric groundwater well

    DOE Patents [OSTI]

    Hubbell, Joel M.; Sisson, James B.

    1999-01-01

    A method of measuring a parameter in a well, under isobaric conditions, including such parameters as hydraulic gradient, pressure, water level, soil moisture content and/or aquifer properties the method as presented comprising providing a casing having first and second opposite ends, and a length between the ends, the casing supporting a transducer having a reference port; placing the casing lengthwise into the well, second end first, with the reference port vented above the water table in the well; and sealing the first end. A system is presented for measuring a parameter in a well, the system comprising a casing having first and second opposite ends, and a length between the ends and being configured to be placed lengthwise into a well second end first; a transducer, the transducer having a reference port, the reference port being vented in the well above the water table, the casing being screened across and above the water table; and a sealing member sealing the first end. In one embodiment, the transducer is a tensiometer transducer and in other described embodiments, another type transducer is used in addition to a tensiometer.

  12. Shiprock Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Environmental Management (EM)

    Shiprock Archived Soil & Groundwater Master Reports Shiprock Archived Soil & Groundwater Master Reports Shiprock Archived Soil & Groundwater Master Reports Shiprock - Shiprock (19.31 KB) More Documents & Publications Slick Rock Archived Soil & Groundwater Master Reports Tuba City Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports

  13. Spook Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Environmental Management (EM)

    Spook Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports Spook - Spook (17.91 KB) More Documents & Publications Tuba City Archived Soil & Groundwater Master Reports Slick Rock Archived Soil & Groundwater Master Reports Weldon Spring Site Archived Soil & Groundwater Master Reports

  14. Water resources and the urban environment

    SciTech Connect (OSTI)

    Loucks, E.D.

    1998-07-01

    140 abstracts from the conference cover topics such as urban stormwater management; geographic information systems, hydrologic and hydraulic computer modeling; groundwater analysis and management; drinking water supply and quality; and international water resources issues.

  15. Water-Level Data Analysis for the Saturated Zone Site-Scale Flow and Transport Model

    SciTech Connect (OSTI)

    P. Tucci

    2001-12-20

    This Analysis/Model Report (AMR) documents an updated analysis of water-level data performed to provide the saturated-zone, site-scale flow and transport model (CRWMS M&O 2000) with the configuration of the potentiometric surface, target water-level data, and hydraulic gradients for model calibration. The previous analysis was presented in ANL-NBS-HS-000034, Rev 00 ICN 01, Water-Level Data Analysis for the Saturated Zone Site-Scale Flow and Transport Model (USGS 2001). This analysis is designed to use updated water-level data as the basis for estimating water-level altitudes and the potentiometric surface in the SZ site-scale flow and transport model domain. The objectives of this revision are to develop computer files containing (1) water-level data within the model area (DTN: GS010908312332.002), (2) a table of known vertical head differences (DTN: GS0109083 12332.003), and (3) a potentiometric-surface map (DTN: GS010608312332.001) using an alternate concept from that presented in ANL-NBS-HS-000034, Rev 00 ICN 01 for the area north of Yucca Mountain. The updated water-level data include data obtained from the Nye County Early Warning Drilling Program (EWDP) and data from borehole USW WT-24. In addition to being utilized by the SZ site-scale flow and transport model, the water-level data and potentiometric-surface map contained within this report will be available to other government agencies and water users for ground-water management purposes. The potentiometric surface defines an upper boundary of the site-scale flow model, as well as provides information useful to estimation of the magnitude and direction of lateral ground-water flow within the flow system. Therefore, the analysis documented in this revision is important to SZ flow and transport calculations in support of total system performance assessment.

  16. RDX in Groundwater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RDX in Groundwater RDX in Groundwater Topic: Tim Goering LANL, Provided Information on the RDX Groundwater Plume that is Located Under Technical Area 16 at Los Alamos. Information on Monitoring and Possible Clean-up Solutions was Given. RDX Update - July 8, 2015 (1.97

  17. Buildings Energy Data Book: 8.3 Commercial Sector Water Consumption

    Buildings Energy Data Book [EERE]

    1 Commercial Water Use by Source (Million Gallons per Day) Year 1980 - - - 1985 5,710 1,230 1990 5,900 2,390 1995 6,690 2,890 2000 (3) 7,202 3,111 2005 (3) 7,102 3,068 Note(s): Source(s): 10,314 10,171 1) Public supply water use: water withdrawn by public and private water suppliers that furnish water to at least 25 people or have a minimum of 15 connections. 2) Self-supply water use: Water withdrawn from a groundwater or surface-water source by a user rather than being obtained from a public

  18. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Green River, Utah, Disposal Site August 2014 LMSGRN.........7 Water Sampling Field Activities Verification ...

  19. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Rio Blanco, Colorado, Site October 2014 LMSRBLS00514 .........5 Water Sampling Field Activities Verification ...

  20. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........9 Water Sampling Field Activities Verification ... Data Durango Processing Site Surface Water Quality Data Equipment Blank Data Static ...

  1. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monticello, Utah, Processing Site July 2015 LMSMNT.........7 Water Sampling Field Activities Verification ...

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Rio Blanco, Colorado, Site October 2015 LMSRBLS00515 .........5 Water Sampling Field Activities Verification ...

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monticello, Utah, Processing Site July 2014 LMSMNT.........7 Water Sampling Field Activities Verification ...

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Naturita, Colorado Processing Site October 2013 LMSNAP.........5 Water Sampling Field Activities Verification ...

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2013 LMSTUB.........9 Water Sampling Field Activities Verification ...

  6. Evolution of a Groundwater Treatment System-Rocky Flats, Colorado, Site |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Evolution of a Groundwater Treatment System-Rocky Flats, Colorado, Site Evolution of a Groundwater Treatment System-Rocky Flats, Colorado, Site January 13, 2015 - 5:18pm Addthis What does this project do? Goal 1. Protect human health and the environment. A project to reconfigure the East Trenches Plume Treatment System (ETPTS) at the Rocky Flats site, to improve treatment effectiveness and meet the strict water quality standards in the area, is scheduled to be completed

  7. H-Area Seepage Basins groundwater monitoring report. First quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-06-01

    During first quarter 1992, tritium, nitrate, nonvolatile beta, total alpha-emitting radium (radium-224 and radium-226), gross alpha, antimony, mercury, lead, tetrachloroethylene, arsenic, and cadmium exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) in groundwater samples from monitoring wells at the H-Area Seepage Basins (HASB) at the Savannah River Site. This report presents and discusses the groundwater monitoring results in the H-Area for first quarter 1992.

  8. K Basins Groundwater Monitoring Task, K Basins Closure Project: Report for July, August, and September 2006

    SciTech Connect (OSTI)

    Peterson, Robert E.

    2006-12-08

    This report provides information on groundwater monitoring at the K Basins during July, August, and September 2006. Conditions remain very similar to those reported in the previous quarterly report, with no evidence in monitoring results to suggest groundwater impact from current loss of basin water to the ground. The K Basins monitoring network will be modified in the coming quarters as a consequence of remedial action at KE Basin, i.e., removal of sludge and basin demolition.

  9. Metallurgical Laboratory Hazardous Waste Management Facility (HWMF) groundwater monitoring report, second quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-09-01

    During second quarter 1992, 18 groundwater monitoring wells of the AMB series at the Metallurgical Laboratory Hazardous Waste Management Facility (Met Lab HWMF) were visited for sampling. Groundwater samples were analyzed for certain heavy metals, indicator parameters, radionuclides, volatile organic compounds, and other constituents. This report describes the results that exceeded the US Environmental Protection Agency Primary Drinking Water Standards (PDWS) and the Savannah River Site flagging criteria during the quarter.

  10. The Savannah River Site's Groundwater Monitoring Program, second quarter 1990

    SciTech Connect (OSTI)

    Not Available

    1991-02-07

    The Environmental Protection Department/Environmental Monitoring Section (EPD/EMS) administers the Savannah River Site's (SRS) Groundwater Monitoring Program. During second quarter 1990 (April through June) EPD/EMS conducted routine sampling of monitoring wells and drinking water locations. EPD/EMS established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria aid personnel in sample scheduling, interpretation of data, and trend identification. The flagging criteria are based on detection limits, background levels in SRS groundwater, and drinking water standards. An explanation of flagging criteria for the second quarter is presented in the Flagging Criteria section of this document. All analytical results from second quarter 1990 are listed in this report.

  11. Radionuclide Sensors for Water Monitoring

    SciTech Connect (OSTI)

    Grate, Jay W.; Egorov, Oleg B.; DeVol, Timothy A.

    2004-06-29

    Radionuclide contamination in the soil and groundwater at U.S. Department of Energy (DOE) sites is a severe problem that requires monitoring and remediation. Radionuclide measurement techniques are needed to monitor surface waters, groundwater, and process waters. Typically, water samples are collected and transported to an analytical laboratory, where costly radiochemical analyses are performed. To date, there has been very little development of selective radionuclide sensors for alpha- and beta-emitting radionuclides such as 90Sr, 99Tc, and various actinides of interest. The objective of this project is to investigate novel sensor concepts and materials for sensitive and selective determination of beta- and alpha-emitting radionuclide contaminants in water. To meet the requirements for low-level, isotope-specific detection, the proposed sensors are based on radiometric detection. As a means to address the fundamental challenge of the short ranges of beta and alpha particle s in water, our overall approach is based on localization of preconcentration/separation chemistries directly on or within the active area of a radioactivity detector. Automated microfluidics is used for sample manipulation and sensor regeneration or renewal. The outcome of these investigations will be the knowledge necessary to choose appropriate chemistries for selective preconcentration of radionuclides from environmental samples, new materials that combine chemical selectivity with scintillating properties, new materials that add chemical selectivity to solid-state diode detectors, new preconcentrating column sensors, and improved instrumentation and signal processing for selective radionuclide sensors. New knowledge will provide the basis for designing effective probes and instrumentation for field and in situ measurements.

  12. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1992-01-10

    The Environmental Protection Department/Environmental Monitoring Section (EPD/EMS) administers the Savannah River Site's (SRS) Groundwater Monitoring Program. During second quarter 1991 EPD/EMS conducted extensive sampling of monitoring wells. EPD/EMS established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria do not define contamination levels; instead, they aid personnel in sample scheduling, interpretation of data, and trend identification. Beginning in 1991, the flagging criteria are based on EPA drinking water standards and method detection limits. A detailed explanation of the current flagging criteria is presented in the Flagging Criteria section of this document. Analytical results from second quarter 1991 are listed in this report.

  13. Theoretical foundation for measuring the groundwater age distribution.

    SciTech Connect (OSTI)

    Gardner, William Payton; Arnold, Bill Walter

    2014-01-01

    In this study, we use PFLOTRAN, a highly scalable, parallel, flow and reactive transport code to simulate the concentrations of 3H, 3He, CFC-11, CFC-12, CFC-113, SF6, 39Ar, 81Kr, 4He and themean groundwater age in heterogeneous fields on grids with an excess of 10 million nodes. We utilize this computational platform to simulate the concentration of multiple tracers in high-resolution, heterogeneous 2-D and 3-D domains, and calculate tracer-derived ages. Tracer-derived ages show systematic biases toward younger ages when the groundwater age distribution contains water older than the maximum tracer age. The deviation of the tracer-derived age distribution from the true groundwater age distribution increases with increasing heterogeneity of the system. However, the effect of heterogeneity is diminished as the mean travel time gets closer the tracer age limit. Age distributions in 3-D domains differ significantly from 2-D domains. 3D simulations show decreased mean age, and less variance in age distribution for identical heterogeneity statistics. High-performance computing allows for investigation of tracer and groundwater age systematics in high-resolution domains, providing a platform for understanding and utilizing environmental tracer and groundwater age information in heterogeneous 3-D systems. Groundwater environmental tracers can provide important constraints for the calibration of groundwater flow models. Direct simulation of environmental tracer concentrations in models has the additional advantage of avoiding assumptions associated with using calculated groundwater age values. This study quantifies model uncertainty reduction resulting from the addition of environmental tracer concentration data. The analysis uses a synthetic heterogeneous aquifer and the calibration of a flow and transport model using the pilot point method. Results indicate a significant reduction in the uncertainty in permeability with the addition of environmental tracer data, relative

  14. Uranium Removal from Contaminated Groundwater by Synthetic Resins

    SciTech Connect (OSTI)

    Phillips, Debra H.; Gu, Baohua; Watson, David B; Parmele, C. S.

    2008-01-01

    Synthetic resins are shown to be effective in removing uranium from contaminated groundwater. Batch and field column tests showed that strong-base anion-exchange resins were more effective in removing uranium from both near-neutral-pH (6.5)- and high-pH (8)-low-nitrate-containing ground waters, than metal-chelating resins, which removed more uranium from acidic-pH (5)-high-nitrate-containing groundwater from the Oak Ridge Reservation (ORR) Y-12 S-3 Ponds area in Tennessee, USA. Dowex 1-X8 and Purolite A-520E anion-exchange resins removed more uranium from high-pH (8)-low-nitrate-containing synthetic groundwater in batch tests than metal-chelating resins. The Dowex{trademark} 21K anion-exchange resin achieved a cumulative loading capacity of 49.8 mg g{sup -1} before breakthrough in a field column test using near-neutral-pH (6.5)-low-nitrate-containing groundwater. However, in an acidic-pH (5)-high-nitrate-containing groundwater, metal-chelating resins Diphonix and Chelex-100 removed more uranium than anion-exchange resins. In 15 mL of acidic-pH (5)-high-nitrate-containing groundwater spiked with 20 mg L{sup -1} uranium, the uranium concentrations ranged from 0.95 mg L{sup -1} at 1-h equilibrium to 0.08 mg L{sup -1} at 24-h equilibrium for Diphonix and 0.17 mg L{sup -1} at 1-h equilibrium to 0.03 mg L{sup -1} at 24-h equilibrium for Chelex-100. Chelex-100 removed more uranium in the first 10 min in the 100 mL of acidic-(pH 5)-high-nitrate-containing groundwater (5 mg L{sup -1} uranium); however, after 10 min, Diphonix equaled or out-performed Chelex-100. This study presents an improved understanding of the selectivity and sorption kinetics of a range of ion-exchange resins that remove uranium from both low- and high-nitrate-containing groundwaters with varying pHs.

  15. Sanitary landfill groundwater monitoring data

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-05-01

    This report for first quarter 1992 contains sanitary landfill groundwater monitoring data for the Savannah River Plant. The data tables presented in this report are copies of draft analytical results and therefore do contain errors. These errors will be corrected when the finalized data is received from the laboratory.

  16. Final report : groundwater monitoring at Centralia, Kansas, inSeptember-October 2005 and March 2006, with expansion of the monitoringnetwork in January 2006.

    SciTech Connect (OSTI)

    LaFreniere, L. M.

    2006-12-07

    -year program. Results of analyses for VOCs showed further increases in contaminant levels and expansion of the carbon tetrachloride plume toward the south and west from the former CCC/USDA facility. The groundwater samples collected in March 2006 were also analyzed for additional groundwater parameters to aid in the evaluation of the potential for reductive dechlorination processes. Preliminary screening of groundwater parameters provided limited evidence that reductive dechlorination of carbon tetrachloride is taking place at some locations on the former CCC/USDA facility. Groundwater levels measured manually in September 2005, March 2006, and June 2006 were used to map the potentiometric surface at Centralia. Overall, these results were consistent with each other and with previous measurements, generally indicating a groundwater flow direction toward the south-southwest from the former CCC/USDA facility. Data recorders installed in wells MW01-MW06 in August 2004 are gathering long-term data on the groundwater elevation and gradient. Data downloaded in March 2005, September 2005, and June 2006 indicate that two wells north and west of the former CCC/USDA facility boundary show distinct, transient and seasonal water level variations. In contrast, two different wells southwest and south of the former facility boundary show virtually no response to the same events. The first two monitoring events of the planned two-year monitoring program for Centralia have demonstrated increased carbon tetrachloride concentrations and lateral expansion of the contaminated zone. Argonne recommends that the CCC/USDA and KDHE project managers consider development and approval of a work plan to expedite the selection and implementation of an active remedial alternative addressing the concentrated areas of groundwater contamination before the end of the two-year monitoring program in 2007.

  17. Crystal Structures, Surface Stability, and Water Adsorption Energies of La-Bastnäsite via Density Functional Theory and Experimental Studies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Srinivasan, Sriram Goverapet; Shivaramaiah, Radha; Kent, Paul R. C.; Stack, Andrew G.; Navrotsky, Alexandra; Riman, Richard; Anderko, Andre; Bryantsev, Vyacheslav S.

    2016-07-11

    Bastnasite is a fluoro-carbonate mineral that is the largest source of rare earth elements such as Y, La and Ce. With increasing demand for REE in many emerging technologies, there is an urgent need for improving the efficiency of ore beneficiation by froth flotation. In order to design improved flotation agents that can selectively bind to the mineral surface, a fundamental understanding of the bulk and surface properties of bastnasite is essential. Density functional theory calculations using the PBEsol exchange correlation functional and the DFT-D3 dispersion correction reveal that the most stable form of La bastnsite is isomorphic to themore » structure of Ce bastnasite belonging to the P2c space group, while the Inorganic Crystal Structure Database structure in the P2m space group is ca. 11.3 kJ/mol higher in energy per LaFCO3 formula unit. We report powder X-ray diffraction measurements on synthetic of La bastnasite to support these theoretical findings. Six different surfaces are studied by DFT, namely [100], [0001], [101], [102], [104] and [112]. Among these, the [100] surface is the most stable with a surface energy of 0.73 J/m2 in vacuum and 0.45 J/m2 in aqueous solution. We predicted the shape of a La bastnasite nanoparticle via thermodynamic Wulff construction to be a hexagonal prism with [100] and [0001] facets, chiseled at its ends by the [101] and [102] facets. The average surface energy of the nanoparticle in the gas phase is estimated to be 0.86 J/m2, in good agreement with a value of 1.11 J/m2 measured by calorimetry. The calculated adsorption energy of a water molecule varies widely with the surface plane and specific adsorption sites on a given surface. Moreover, the first layer of water molecules is predicted to adsorb strongly on the La-bastnasite surface, in agreement with water adsorption calorimetry experiments. Our work provides an important step towards a detailed atomistic understanding of the bastnasite water interface and designing

  18. Review of present groundwater monitoring programs at the Nevada Test Site

    SciTech Connect (OSTI)

    Hershey, R.L.; Gillespie, D.

    1993-09-01

    Groundwater monitoring at the Nevada Test Site (NTS) is conducted to detect the presence of radionuclides produced by underground nuclear testing and to verify the quality and safety of groundwater supplies as required by the State of Nevada and federal regulations, and by U.S. Department of Energy (DOE) Orders. Groundwater is monitored at water-supply wells and at other boreholes and wells not specifically designed or located for traditional groundwater monitoring objectives. Different groundwater monitoring programs at the NTS are conducted by several DOE Nevada Operations Office (DOE/NV) contractors. Presently, these individual groundwater monitoring programs have not been assessed or administered under a comprehensive planning approach. Redundancy exists among the programs in both the sampling locations and the constituents analyzed. Also, sampling for certain radionuclides is conducted more frequently than required. The purpose of this report is to review the existing NTS groundwater monitoring programs and make recommendations for modifying the programs so a coordinated, streamlined, and comprehensive monitoring effort may be achieved by DOE/NV. This review will be accomplished in several steps. These include: summarizing the present knowledge of the hydrogeology of the NTS and the potential radionuclide source areas for groundwater contamination; reviewing the existing groundwater monitoring programs at the NTS; examining the rationale for monitoring and the constituents analyzed; reviewing the analytical methods used to quantify tritium activity; discussing monitoring network design criteria; and synthesizing the information presented and making recommendations based on the synthesis. This scope of work was requested by the DOE/NV Hydrologic Resources Management Program (HRMP) and satisfies the 1993 (fiscal year) HRMP Groundwater Monitoring Program Review task.

  19. Surface water sampling and analysis plan for environmental monitoring in Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Environmental Restoration Program

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This Sampling and Analysis Plan addresses surface water monitoring, sampling, and analysis activities that will be conducted in support of the Environmental Monitoring Plan for Waste Area Grouping (WAG) 6. WAG 6 is a shallow-burial land disposal facility for low-level radioactive waste at the Oak Ridge National Laboratory, a research facility owned by the US Department of Energy and managed by Martin Marietta Energy Systems, Inc. Surface water monitoring will be conducted at nine sites within WAG 6. Activities to be conducted will include the installation, inspection, and maintenance of automatic flow-monitoring and sampling equipment and manual collection of various water and sediment samples. The samples will be analyzed for various organic, inorganic, and radiological parameters. The information derived from the surface water monitoring, sampling, and analysis will aid in evaluating risk associated with contaminants migrating off-WAG, and will be used in calculations to establish relationships between contaminant concentration (C) and flow (Q). The C-Q relationship will be used in calculating the cumulative risk associated with the off-WAG migration of contaminants.

  20. Bore II - Advanced Wellbore Technology Characterizes Groundwater Flow and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contamination - Energy Innovation Portal Geothermal Geothermal Energy Analysis Energy Analysis Find More Like This Return to Search Bore II - Advanced Wellbore Technology Characterizes Groundwater Flow and Contamination Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryBore II, co-developed by Berkeley Lab researchers Frank Hale, Chin-Fu Tsang, and Christine Doughty, provides vital information for solving water quality and supply problems and

  1. Surface water and atmospheric underway carbon data obtained during the World Ocean Circulation Experiment Indian Ocean survey cruises (R/V Knorr, December 1998--January 1996)

    SciTech Connect (OSTI)

    Kozyr, A.; Allison, L.

    1997-11-01

    This data documentation presents the results of the surface water and atmospheric underway measurements of mole fraction of carbon dioxide (xCO{sub 2}), sea surface salinity, and sea surface temperature, obtained during the World Ocean Circulation Experiment (WOCE) Indian Ocean survey cruises (December 1994--January 1996). Discrete and underway carbon measurements were made by members of the CO{sub 2} survey team. The survey team is a part of the Joint Global Ocean Flux Study supported by the US Department of Energy to make carbon-related measurements on the WOCE global survey cruises. Approximately 200,000 surface seawater and 50,000 marine air xCO{sub 2} measurements were recorded.

  2. Nevada National Security Site 2012 Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2013-02-11

    This report is a compilation of the groundwater sampling results from the Area 5 Radioactive Waste Management Site (RWMS). The data have been collected since 1993 and include calendar year 2012 results. During 2012, groundwater samples were collected and static water levels were measured at the three pilot wells surrounding the Area 5 RWMS. Groundwater samples were collected at UE5PW-1, UE5PW-2, and UE5PW-3 on March 21, August 7, August 21, and September 11, 2012, and static water levels were measured at each of the three pilot wells on March 19, June 6, August 2, and October 15, 2012. Groundwater samples were analyzed for the following indicators of contamination: pH, specific conductance, total organic carbon, total organic halides, and tritium. Indicators of general water chemistry (cations and anions) were also measured. Final results from samples collected in 2012 were within the limits established by agreement with the Nevada Division of Environmental Protection for each analyte. These data indicate that there has been no measurable impact to the uppermost aquifer from the Area 5 RWMS. There were no significant changes in measured groundwater parameters compared to previous years. The report contains an updated cumulative chronology for the Area 5 RWMS Groundwater Monitoring Program and a brief description of the site hydrogeology.

  3. Updated Conceptual Model for the 300 Area Uranium Groundwater Plume

    SciTech Connect (OSTI)

    Zachara, John M.; Freshley, Mark D.; Last, George V.; Peterson, Robert E.; Bjornstad, Bruce N.

    2012-11-01

    The 300 Area uranium groundwater plume in the 300-FF-5 Operable Unit is residual from past discharge of nuclear fuel fabrication wastes to a number of liquid (and solid) disposal sites. The source zones in the disposal sites were remediated by excavation and backfilled to grade, but sorbed uranium remains in deeper, unexcavated vadose zone sediments. In spite of source term removal, the groundwater plume has shown remarkable persistence, with concentrations exceeding the drinking water standard over an area of approximately 1 km2. The plume resides within a coupled vadose zone, groundwater, river zone system of immense complexity and scale. Interactions between geologic structure, the hydrologic system driven by the Columbia River, groundwater-river exchange points, and the geochemistry of uranium contribute to persistence of the plume. The U.S. Department of Energy (DOE) recently completed a Remedial Investigation/Feasibility Study (RI/FS) to document characterization of the 300 Area uranium plume and plan for beginning to implement proposed remedial actions. As part of the RI/FS document, a conceptual model was developed that integrates knowledge of the hydrogeologic and geochemical properties of the 300 Area and controlling processes to yield an understanding of how the system behaves and the variables that control it. Recent results from the Hanford Integrated Field Research Challenge site and the Subsurface Biogeochemistry Scientific Focus Area Project funded by the DOE Office of Science were used to update the conceptual model and provide an assessment of key factors controlling plume persistence.

  4. Thermal Removal of Tritium from Concrete and Soil to Reduce Groundwater Impacts - 13197

    SciTech Connect (OSTI)

    Jackson, Dennis G.; Blount, Gerald C.; Wells, Leslie H.; Cardoso, Joao E.; Kmetz, Thomas F.; Reed, Misty L.

    2013-07-01

    Legacy heavy-water moderator operations at the Savannah River Site (SRS) have resulted in the contamination of equipment pads, building slabs, and surrounding soil with tritium. At the time of discovery the tritium had impacted the shallow (< 3-m) groundwater at the facility. While tritium was present in the groundwater, characterization efforts determined that a significant source remained in a concrete slab at the surface and within the associated vadose zone soils. To prevent continued long-term impacts to the shallow groundwater a CERCLA non-time critical removal action for these source materials was conducted to reduce the leaching of tritium from the vadose zone soils and concrete slabs. In order to minimize transportation and disposal costs, an on-site thermal treatment process was designed, tested, and implemented. The on-site treatment consisted of thermal detritiation of the concrete rubble and soil. During this process concrete rubble was heated to a temperature of 815 deg. C (1,500 deg. F) resulting in the dehydration and removal of water bound tritium. During heating, tritium contaminated soil was used to provide thermal insulation during which it's temperature exceeded 100 deg. C (212 deg. F), causing drying and removal of tritium. The thermal treatment process volatiles the water bound tritium and releases it to the atmosphere. The released tritium was considered insignificant based upon Clean Air Act Compliance Package (CAP88) analysis and did not exceed exposure thresholds. A treatability study evaluated the effectiveness of this thermal configuration and viability as a decontamination method for tritium in concrete and soil materials. Post treatment sampling confirmed the effectiveness at reducing tritium to acceptable waste site specific levels. With American Recovery and Reinvestment Act (ARRA) funding three additional treatment cells were assembled utilizing commercial heating equipment and common construction materials. This provided a total

  5. Method and device for removing a non-aqueous phase liquid from a groundwater system

    DOE Patents [OSTI]

    Looney, Brian B.; Rossabi, Joseph; Riha, Brian D.

    2002-01-01

    A device for removing a non-aqueous phase liquid from a groundwater system includes a generally cylindrical push-rod defining an internal recess therein. The push-rod includes first and second end portions and an external liquid collection surface. A liquid collection member is detachably connected to the push-rod at one of the first and second end portions thereof. The method of the present invention for removing a non-aqueous phase liquid from a contaminated groundwater system includes providing a lance including an external hydrophobic liquid collection surface, an internal recess, and a collection chamber at the bottom end thereof. The lance is extended into the groundwater system such that the top end thereof remains above the ground surface. The liquid is then allowed to collect on the liquid collection surface, and flow downwardly by gravity into the collection chamber to be pumped upwardly through the internal recess in the lance.

  6. Hanford Site Groundwater Monitoring for Fiscal Year 1999

    SciTech Connect (OSTI)

    MJ Hartman; LF Morasch; WD Webber

    2000-05-10

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 1999 on the US. Department of Energy's Hanford Site, Washington. Water-level monitoring was performed to evaluate groundwater flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Measurements for site-wide maps were conducted in June in past years and are now measured in March to reflect conditions that are closer to average. Water levels over most of the Hanford Site continued to decline between June 1998 and March 1999. The most widespread radiological contaminant plumes in groundwater were tritium and iodine-129. Concentrations of carbon-14, strontium-90, technetium-99, and uranium also exceeded drinking water standards in smaller plumes. Cesium-137 and plutonium exceeded standards only near the 216-B-5 injection well. Derived concentration guide levels specified in US Department of Energy Order 5400.5 were exceeded for plutonium, strontium-90, tritium, and uranium in small plumes or single wells. Nitrate and carbon tetrachloride are the most extensive chemical contaminants. Chloroform, chromium, cis-1,2dichloroethylene, cyanide, fluoride, and trichloroethylene also were present in smaller areas at levels above their maximum contaminant levels. Metals such as aluminum, cadmium, iron, manganese, and nickel exceeded their maximum contaminant levels in filtered samples from numerous wells; however, in most cases, they are believed to represent natural components of groundwater. ''Resource Conservation and Recovery Act of 1976'' groundwater monitoring continued at 25 waste management areas during fiscal year 1999: 16 under detection programs and data indicate that they are not adversely affecting groundwater; 6 under interim status groundwater quality assessment programs to assess contamination; and 2 under final status corrective-action programs. Another site, the 120-D-1 ponds, was clean closed in

  7. Water-Level Data Analysis for the Saturated Zone Site-Scale Flow and Transport Model

    SciTech Connect (OSTI)

    K. Rehfeldt

    2004-10-08

    This report is an updated analysis of water-level data performed to provide the ''Saturated Zone Site-Scale Flow Model'' (BSC 2004 [DIRS 170037]) (referred to as the saturated zone (SZ) site-scale flow model or site-scale SZ flow model in this report) with the configuration of the potentiometric surface, target water-level data, and hydraulic gradients for calibration of groundwater flow models. This report also contains an expanded discussion of uncertainty in the potentiometric-surface map. The analysis of the potentiometric data presented in Revision 00 of this report (USGS 2001 [DIRS 154625]) provides the configuration of the potentiometric surface, target heads, and hydraulic gradients for the calibration of the SZ site-scale flow model (BSC 2004 [DIRS 170037]). Revision 01 of this report (USGS 2004 [DIRS 168473]) used updated water-level data for selected wells through the year 2000 as the basis for estimating water-level altitudes and the potentiometric surface in the SZ site-scale flow and transport model domain based on an alternative interpretation of perched water conditions. That revision developed computer files containing: Water-level data within the model area (DTN: GS010908312332.002); A table of known vertical head differences (DTN: GS010908312332.003); and A potentiometric-surface map (DTN: GS010608312332.001) using an alternative concept from that presented by USGS (2001 [DIRS 154625]) for the area north of Yucca Mountain. The updated water-level data presented in USGS (2004 [DIRS 168473]) include data obtained from the Nye County Early Warning Drilling Program (EWDP) Phases I and II and data from Borehole USW WT-24. This document is based on Revision 01 (USGS 2004 [DIRS 168473]) and expands the discussion of uncertainty in the potentiometric-surface map. This uncertainty assessment includes an analysis of the impact of more recent water-level data and the impact of adding data from the EWDP Phases III and IV wells. In addition to being utilized

  8. Interplay of confinement and surface energetics in the interaction of water with a metal–organic framework

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2016-03-24

    Here, the enthalpy of water adsorption (Δh) on the metal–organic framework (MOF) HKUST-1 has been determined directly by calorimetry. The most exothermic value of Δh [–119.4 ± 0.5 kJ/(mol of water)] occurs at zero coverage and perhaps represents water confinement in the smallest (4-Å) cages. An intermediate Δh value of –50.2 ± 1.8 kJ/(mol of water) at higher loading probably corresponds to the binding of water on the available Cu nodes and subsequent filling of the largest (11-Å) pores. The weakest interactions take place in the medium (10-Å) cages, showing weak inclusion of water clusters in a limited hydrophobic environment.more » By combining ethanol adsorption calorimetry, mathematical analysis of the slope of the water adsorption isotherm, and the differential enthalpy of water adsorption curve, we are able not only to develop an approach to separate energetically multistage guest–host interactions in complex MOF architectures but also to distinguish a sequence of interactions with very similar energetic effects.« less

  9. Work plan for the Oak Ridge National Laboratory groundwater program: Continuous groundwater collection

    SciTech Connect (OSTI)

    NONE

    1995-08-01

    The continuous collection of groundwater data is a basic and necessary part of Lockeheed Martin Energy Systems` ORNL Environmental Restoration Area-Wide Groundwater Program. Continuous groundwater data consist primarily of continually recorded groundwater levels, and in some instances, specific conductivity, pH, and/or temperature measurements. These data will be collected throughout the ORNL site. This Work Plan (WP) addresses technical objectives, equipment requirements, procedures, documentation requirements, and technical instructions for the acquisition of the continuous groundwater data. Intent of this WP is to provide an approved document that meets all the necessary requirements while retaining the flexibility necessary to effectively address ORNL`s groundwater problems.

  10. Estimations of the extent of migration of surficially applied water for various surface conditions near the potential repository perimeter; Yucca Mountain Site Characterization Project

    SciTech Connect (OSTI)

    Sobolik, S.R.; Fewell, M.E.

    1993-12-01

    The Yucca Mountain Site Characterization Project is studying Yucca Mountain in southwestern Nevada as a potential site for a high-level nuclear waste repository. Site characterization includes surface-based and underground testing. Analyses have been performed to support the design of site characterization activities so to have minimal impact on the ability of the site to isolate waste, and on tests performed as part of the characterization process. Two examples of site characterization activities are the construction of an Exploratory Studies Facility, which may include underground shafts, drifts, and ramps, and surface-based testing activities, which may require borehole drilling, excavation of test pits, and road watering for dust control. The information in this report pertains to two-dimensional numerical calculations modeling the movement of surficially applied water and the potential effects of that water on repository performance and underground experiments. This document contains information that has been used in preparing recommendations for two Yucca Mountain Site Characterization Project documents: Appendix I of the Exploratory Studies Facility Design Requirements document, and the Surface-Based Testing Field Requirements Document.

  11. MEASUREMENTS OF PAST 14C LEVELS AND 13C/12C RATIOS IN THE SURFACE WATERS OF THE WORLD'S SUBPOLAR OCEANS.

    SciTech Connect (OSTI)

    Brown, T A

    2010-04-22

    Under this project we have developed methods that allow the reconstruction of past {sup 14}C levels of the surface waters of the subpolar North Pacific Ocean by measuring the {sup 14}C contents of archived salmon scales. The overall goal of this research was to reduce of the uncertainty in the uptake of fossil CO{sub 2} by the oceans and thereby improve the quantification of the global carbon cycle and to elucidate the fate of anthropogenic CO{sub 2}. Ocean General Circulation Models (OGCMs), with their three dimensional global spatial coverage and temporal modeling capabilities, provide the best route to accurately calculating the total uptake of CO{sub 2} by the oceans and, hence, to achieving the desired reduction in uncertainty. {sup 14}C has played, and continues to play, a central role in the validation of the OGCMs calculations, particularly with respect to those model components which govern the uptake of CO{sub 2} from the atmosphere and the transport of this carbon within the oceans. Under this project, we have developed time-series records of the {sup 14}C levels of the surface waters of three areas of the subpolar North Pacific Ocean. As the previously available data on the time-history of oceanic surface water {sup 14}C levels are very limited, these time-series records provide significant new {sup 14}C data to constrain and validate the OGCMs.

  12. Materials for light-induced water splitting: In situ controlled surface preparation of GaPN epilayers grown lattice-matched on Si(100)

    SciTech Connect (OSTI)

    Supplie, Oliver; May, Matthias M.; Stange, Helena; Hhn, Christian; Lewerenz, Hans-Joachim; Hannappel, Thomas

    2014-03-21

    Energy storage is a key challenge in solar-driven renewable energy conversion. We promote a photochemical diode based on dilute nitride GaPN grown lattice-matched on Si(100), which could reach both high photovoltaic efficiencies and evolve hydrogen directly without external bias. Homoepitaxial GaP(100) surface preparation was shown to have a significant impact on the semiconductor-water interface formation. Here, we grow a thin, pseudomorphic GaP nucleation buffer on almost single-domain Si(100) prior to GaPN growth and compare the GaP{sub 0.98}N{sub 0.02}/Si(100) surface preparation to established P- and Ga-rich surfaces of GaP/Si(100). We apply reflection anisotropy spectroscopy to study the surface preparation of GaP{sub 0.98}N{sub 0.02} in situ in vapor phase epitaxy ambient and benchmark the signals to low energy electron diffraction, photoelectron spectroscopy, and x-ray diffraction. While the preparation of the Ga-rich surface is hardly influenced by the presence of the nitrogen precursor 1,1-dimethylhydrazine (UDMH), we find that stabilization with UDMH after growth hinders well-defined formation of the V-rich GaP{sub 0.98}N{sub 0.02}/Si(100) surface. Additional features in the reflection anisotropy spectra are suggested to be related to nitrogen incorporation in the GaP bulk.

  13. Groundwater Under Review Marathon Man

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Under Review Marathon Man NNSS team welcomes peer review of groundwater program. Nevada Teams compete in the National Science Bowl in Washington. NSTec runner finishes first Boston Marathon. See page 7. See page 6. NNSS Roads Getting a Fresh Makeover Highways, roads, parking lots - any place that has seen at least 60 years of traffic like the Nevada National Security Site (NNSS) has - will experience some normal wear and tear. That is why National Security Technologies (NSTec) is doing some

  14. 2010 Groundwater Monitoring and Inspection Report Gnome-Coach Site, New Mexico

    SciTech Connect (OSTI)

    2011-02-01

    This report presents the 2010 groundwater monitoring results collected by the U.S. Department of Energy (DOE) Office of Legacy Management (LM) at the Gnome-Coach (Gnome) Site in New Mexico (Figure 1). Groundwater monitoring consisted of collecting hydraulic head data and groundwater samples from the wells on site. Historically, the U.S. Environmental Protection Agency (EPA) had conducted these annual activities under the Long-Term Hydrologic Monitoring Program (LTHMP). LM took over the sampling and data collection activities in 2008 but continues to use the EPA Radiation and Indoor Environments National Laboratory in Las Vegas, Nevada, to analyze the water samples. This report summarizes groundwater monitoring and site investigation activities that were conducted at the site during calendar year 2010.

  15. URANIUM-SERIES CONSTRAINTS ON RADIONUCLIDE TRANSPORT AND GROUNDWATER FLOW AT NOPAL I URANIUM DEPOSIT, SIERRA PENA BLANCA, MEXICO

    SciTech Connect (OSTI)

    S. J. Goldstein, S. Luo, T. L. Ku, and M. T. Murrell

    2006-04-01

    Uranium-series data for groundwater samples from the vicinity of the Nopal I uranium ore deposit are used to place constraints on radionuclide transport and hydrologic processes at this site, and also, by analogy, at Yucca Mountain. Decreasing uranium concentrations for wells drilled in 2003 suggest that groundwater flow rates are low (< 10 m/yr). Field tests, well productivity, and uranium isotopic constraints also suggest that groundwater flow and mixing is limited at this site. The uranium isotopic systematics for water collected in the mine adit are consistent with longer rock-water interaction times and higher uranium dissolution rates at the front of the adit where the deposit is located. Short-lived nuclide data for groundwater wells are used to calculate retardation factors that are on the order of 1,000 for radium and 10,000 to 10,000,000 for lead and polonium. Radium has enhanced mobility in adit water and fractures near the deposit.

  16. ARM - Measurement - Sea surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sea surface temperature The temperature of sea water near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  17. Y-12 Groundwater Protection Program Monitoring Optimization Plan for Groundwater Monitoring Wells at the U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2003-09-30

    This document is the monitoring optimization plan for groundwater monitoring wells associated with the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee (Figure 1). The plan describes the technical approach that will be implemented under the Y-12 Groundwater Protection Program (GWPP) to focus available resources on the monitoring wells at Y-12 which provide the most useful hydrologic and water-quality monitoring data. The technical approach is based on the GWPP status designation for each well (Section 2.0). Under this approach, wells granted ''active'' status are used by the GWPP for hydrologic monitoring and/or groundwater sampling (Section 3.0), whereas well granted ''inactive'' status are not used for either purpose. The status designation also determines the frequency at which the GWPP will inspect applicable wells, the scope of these well inspections, and extent of any maintenance actions initiated by the GWPP (Section 4.0). Details regarding the ancillary activities associated with implementation of this plan (e.g., well inspection) are deferred to the referenced GWPP plans and procedures (Section 5.0). This plan applies to groundwater monitoring wells associated with Y-12 and related waste management facilities located within three hydrogeologic regimes (Figure 1): the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek Regime encompasses a section of Bear Creek Valley (BCV) immediately west of Y-12. The East Fork Regime encompasses most of the Y-12 process, operations, and support facilities in BCV and, for the purposes of this plan, includes a section of Union Valley east of the DOE Oak Ridge Reservation (ORR) boundary along Scarboro Road. The Chestnut Ridge Regime is directly south of Y-12 and encompasses a section of Chestnut Ridge that is bound to the

  18. Y-12 Groundwater Protection Program Monitoring Optimization Plan for Groundwater Monitoring Wells at the U.S. Department of Energy Y-12 National Security Complex

    SciTech Connect (OSTI)

    2006-12-01

    This document is the monitoring optimization plan for groundwater monitoring wells associated with the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee (Figure A.1). The plan describes the technical approach that will be implemented under the Y-12 Groundwater Protection Program (GWPP) to focus available resources on the monitoring wells at Y-12 that provide the most useful hydrologic and water-quality monitoring data. The technical approach is based on the GWPP status designation for each well (Section 2.0). Under this approach, wells granted ''active'' status are used by the GWPP for hydrologic monitoring and/or groundwater quality sampling (Section 3.0), whereas wells granted ''inactive'' status are not used for either purpose. The status designation also defines the frequency at which the GWPP will inspect applicable wells, the scope of these well inspections, and extent of any maintenance actions initiated by the GWPP (Section 3.0). Details regarding the ancillary activities associated with implementation of this plan (e.g., well inspection) are deferred to the referenced GWPP plans and procedures (Section 4.0). This plan applies to groundwater wells associated with Y-12 and related waste management areas and facilities located within three hydrogeologic regimes (Figure A.1): the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek Regime encompasses a section of Bear Creek Valley (BCV) immediately west of Y-12. The East Fork Regime encompasses most of the Y-12 process, operations, and support facilities in BCV and, for the purposes of this plan, includes a section of Union Valley east of the DOE Oak Ridge Reservation (ORR) boundary along Scarboro Road. The Chestnut Ridge Regime encompasses a section of Chestnut Ridge directly south of Y-12 that is bound on the

  19. A validation of the [sup 3]H/[sup 3]He method for determining groundwater recharge

    SciTech Connect (OSTI)

    Solomon, D.K. ); Schiff, S.L. ); Poreda, R.J. ); Clarke, W.B. )

    1993-09-01

    Tritium and He isotopes have been measured at a site where groundwater flow is nearly vertical for a travel time of 100 years and where recharge rates are spatially variable. Because the mid-1960s [sup 3]H peak (arising from aboveground testing of thermonuclear devices) is well-defined, the vertical groundwater velocity is known with unusual accuracy at this site. Utilizing [sup 3]H and its stable daughter [sup 3]He to determine groundwater ages, we compute a recharge rate of 0.16 m/yr, which agrees to within about 5% of the value based on the depth of the [sup 3]H peak (measured both in 1986 and 1991) and two-dimensional modeling in an area of high recharge. Zero [sup 3]H/[sup 3]He age occurs at a depth that is approximately equal to the average depth of the annual low water table, even though the capillary fringe extends to land surface during most of the year at the study site. In an area of low recharge (0.05 m/yr) where the [sup 3]H peak (and hence the vertical velocity) is also well-defined, the [sup 3]H/[sup 3]He results could not be used to compute recharge because samples were not collected sufficiently far above the [sup 3]H peak; however, modeling indicates that the [sup 3]H/[sup 3]He age gradient near the water table is an accurate measure of vertical velocities in the low-recharge area. Because [sup 3]H and [sup 3]He have different diffusion coefficients, and because the amount of mechanical mixing is different in the area of high recharge than in the low-recharge area, we have separated the dispersive effects of mechanical mixing from molecular diffusion. We estimate a longitudinal dispersivity of 0.07 m and effective diffusion coefficients for [sup 3]H ([sup 3]HHO) and [sup 3]He of 2.4 x 10[sup [minus]5] and 1.3 x 10[sup [minus]4] m[sup 2]/day, respectively. 26 refs., 8 figs., 1 tab.

  20. Groundwater monitoring at the Waste Isolation Pilot Plant

    SciTech Connect (OSTI)

    Kehrman, R.; Broberg, K.; Tatro, G.; Richardson, R.; Dasczcyszak, W.

    1990-01-01

    This paper discusses the Groundwater Monitoring Program (GPM) being conducted at the Waste Isolation Pilot Plant (WIPP) in Carlsbad, New Mexico. The Regulatory and Environmental Programs (REP) section of the Environment, Safety and Health department (ES H) is responsible for conducting environmental monitoring at the WIPP. Groundwater monitoring is one of the ongoing environmental activities currently taking place. The REP section includes water quality sampling and water level monitoring. The WIPP Project is a research and develop facility designed to demonstrate the safe disposal of defense-generated waste in a geologic repository. Water quality sampling for physical, chemical, and radiological parameters has been an ongoing activity at the WIPP site for the past six years, and will continue through the life of the project. The water quality of a well is sampled while the well is continuously pumped. Serial samples of the pumped water are collected and tested for pH, Eh, temperature, specific gravity, specific conductivity, alkalinity, chlorides, divalent cations, ferrous iron, and total iron. Stabilization of serial sampling parameters determined if a representative sample is being obtained, Representative samples are sent to contract laboratories and analyzed for general chemistry, major cations and anions, and radionuclides. 13 refs., 4 figs., 1 tab.

  1. NNSS Groundwater Program Welcomes Peer Review Team

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 18, 2014 NNSS Groundwater Program Welcomes Peer Review Team Recently, an independent peer review team was invited to assess the groundwater characterization program at the Nevada National Security Site (NNSS). This nationally recognized group of experts, from various external organizations, will examine the computer modeling approach developed to better understand how historic underground nuclear testing in Yucca Flat affected the groundwater. From April 7th to 11th, 2014, five peer

  2. Geologic Water Storage in Pre-Columbian Peru

    SciTech Connect (OSTI)

    Fairley Jr., Jerry P.

    1997-07-14

    Agriculture in the arid and semi-arid regions that comprise much of present-day Peru, Bolivia, and Northern Chile is heavily dependent on irrigation; however, obtaining a dependable water supply in these areas is often difficult. The precolumbian peoples of Andean South America adapted to this situation by devising many strategies for transporting, storing, and retrieving water to insure consistent supply. I propose that the ''elaborated springs'' found at several Inka sites near Cuzco, Peru, are the visible expression of a simple and effective system of groundwater control and storage. I call this system ''geologic water storage'' because the water is stored in the pore spaces of sands, soils, and other near-surface geologic materials. I present two examples of sites in the Cuzco area that use this technology (Tambomachay and Tipon) and discuss the potential for identification of similar systems developed by other ancient Latin American cultures.

  3. Groundwater Update K. Michael Thompson Soil and Groundwater Division Richland Operations Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Update Jon Peschong Richland Operations Office May 2015 2 billion gallons of contaminated groundwater treated tons of contaminants removed in all pump and treat systems since the facilities began operating 12 171 HANFORD SITE GROUNDWATER NUMBERS billion of gallons of groundwater treated in 2014 1.95 tons of contaminants removed in 2014 62 3 Groundwater Key Focus Areas * Expand pump and treat systems - Continue pump and treat operations - Install and connect new and existing wells to maximize

  4. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    SciTech Connect (OSTI)

    Borden, R. E.; Cherry, Robert Stephen

    2000-09-01

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced ~7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe® rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The system was tested in a

  5. Direct Push Groundwater Circulation Wells for Remediation of BTEX and Volatile Organics

    SciTech Connect (OSTI)

    Borden, R.C.; Cherry, R.S.

    2000-09-30

    Direct push groundwater circulation wells (DP-GCW) are a promising technology for remediation of groundwater contaminated with dissolved hydrocarbons and chlorinated solvents. In these wells, groundwater is withdrawn from the formation at the bottom of the well, aerated and vapor stripped and injected back into the formation at or above the water table. Previous field studies have shown that: (a) GCWs can circulate significant volumes of groundwater; and (b) GCWs can effectively remove volatile compounds and add oxygen. In this work, we describe the development and field-testing of a system of DP-GCWs for remediation of volatile organics such as benzene, toluene, ethylbenzene, and toluene (BTEX). The GCWs were constructed with No. 20 slotted well screen (2.4 cm ID) and natural sand pack extending from 1.5 to 8.2 m below grade. Air is introduced {approximately}7.5 m below grade via 0.6 cm tubing. Approximately 15% of the vertical length of the air supply tubing is wrapped in tangled mesh polypropylene geonet drainage fabric to provide surface area for biological growth and precipitation of oxidized iron. These materials were selected to allow rapid installation of the GCWs using 3.8 cm direct push Geoprobe{reg_sign} rods, greatly reducing well installation costs. Laboratory testing of these sparged wells and computational fluid dynamics (CFD) modeling showed that these wells, although they used only about 1 L/min of air, could circulate about 1 L/min of water through the surrounding aquifer. This flow was sufficient to capture all of a flowing contaminant if the wells are sufficiently closely together, about 1 meter on center depending on the air flow rate supplied, in a line across the plume. The CFD work showed the details of this ability to capture, and also showed that unforeseen heterogeneities in the aquifer such as a gradient of permeability or a thin impermeable layer (such as a clay layer) did not prevent the system from working largely as intended. The

  6. Evapotranspiration Dynamics and Effects on Groundwater Recharge...

    Office of Scientific and Technical Information (OSTI)

    Prepared for U.S. DEPARTMENT OF ENERGY Legacy Management This page intentionally ... Tuba City UMTRCA site..... 11 Figure 3. Green LAI within the Tuba City groundwater model ...

  7. DEQ Groundwater Permitting Guidebook | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: DEQ Groundwater Permitting GuidebookPermittingRegulatory GuidanceGuide...

  8. Montana Groundwater Information Center Webpage | Open Energy...

    Open Energy Info (EERE)

    Center Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Groundwater Information Center Webpage Abstract Provides access to...

  9. Vermont Groundwater Withdrawal Report | Open Energy Information

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Vermont Groundwater Withdrawal Report Citation Vermont Agency of Natural...

  10. Hanford Treats Record Amount of Groundwater

    Broader source: Energy.gov [DOE]

    Workers have treated more than 800 million gallons of groundwater at the Hanford Site so far this year, a record annual amount.

  11. Surface Complexation of Neodymium at the Rutile-Water Interface: A Potentiometric and Modeling Study in NaCl Media to 250C

    SciTech Connect (OSTI)

    Ridley, Mora K.; Machesky, Michael L.; Wesolowski, David J; Palmer, Donald

    2005-01-01

    The adsorption of Nd{sup 3+} onto rutile surfaces was examined by potentiometric titration from 25 to 250 C, in 0.03 and 0.30m NaCl background electrolyte. Experimental results show that Nd{sup 3+} sorbs strongly, even at low temperature, with adsorption commencing below the pHznpc of rutile. In addition, there is a systematic increase in Nd{sup 3+} adsorption with increasing temperature. The experimental results were rationalized and described using surface oxygen proton affinities computed from the MUlti SIte Complexation or MUSIC model, coupled with a Stern-based three-layer description of the oxide/water interface. Moreover, molecular-scale information was incorporated successfully into the surface complexation model, providing a unique geometry for the adsorption of Nd{sup 3+} on rutile. The primary mode of Nd{sup 3+} adsorption was assumed to be the tetradentate configuration found for Y{sup 3+} adsorption on the rutile (110) surface from previously described in situ X-ray standing wave experiments, wherein the sorbing cations bond directly with two adjacent ''terminal'' and two adjacent ''bridging'' surface oxygen atoms. Similarly, the adsorption of Na{sup +} counterions was also assumed to be tetradentate, as supported by MD simulations of Na{sup +} interactions with the rutile (110) surface, and by analogous X-ray standing wave results for Rb{sup +} adsorption on rutile. Fitting parameters for Nd{sup 3+} adsorption included binding constants for the tetradentate adsorption complex and capacitance values for the inner-sphere binding plane. In addition, hydrolysis of the tetradentate adsorption complex was permitted and resulted in significantly improved model fits at higher temperature and pH values. The modeling results indicate that the Stern-based MUSIC surface-complexation model adequately accommodates molecular-scale information to uniquely rationalize and describe multivalent ion adsorption systematically into the hydrothermal regime.

  12. Clean option: Berkeley Pit water treatment and resource recovery strategy

    SciTech Connect (OSTI)

    Gerber, M.A.; Orth, R.J.; Elmore, M.R.; Monzyk, B.F.

    1995-09-01

    The US Department of Energy (DOE), Office of Technology Development, established the Resource Recovery Project (RRP) in 1992 as a five-year effort to evaluate and demonstrate multiple technologies for recovering water, metals, and other industrial resources from contaminated surface and groundwater. Natural water resources located throughout the DOE complex and the and western states have been rendered unusable because of contamination from heavy metals. The Berkeley Pit, a large, inactive, open pit copper mine located in Butte, Montana, along with its associated groundwater system, has been selected by the RRP for use as a feedstock for a test bed facility located there. The test bed facility provides the infrastructure needed to evaluate promising technologies at the pilot plant scale. Data obtained from testing these technologies was used to assess their applicability for similar mine drainage water applications throughout the western states and at DOE. The objective of the Clean Option project is to develop strategies that provides a comprehensive and integrated approach to resource recovery using the Berkeley Pit water as a feedstock. The strategies not only consider the immediate problem of resource recovery from the contaminated water, but also manage the subsequent treatment of all resulting process streams. The strategies also employ the philosophy of waste minimization to optimize reduction of the waste volume requiring disposal, and the recovery and reuse of processing materials.

  13. Water adsorption onto Y and V sites at the surface of the YVO{sub 4} photocatalyst and related electronic properties

    SciTech Connect (OSTI)

    Oshikiri, Mitsutake; Matsushita, Akiyuki; Ye, Jinhua; Boero, Mauro

    2009-07-21

    The dynamics of water molecules and the adsorption properties at the V and Y sites on the surface of the photocatalyst YVO{sub 4} have been investigated by first principles molecular dynamics. This system has shown an excellent performance in the production of both hydrogen and oxygen in the ultraviolet region. Yet, its catalytic properties, related to the electronic structure, are poorly understood. Here we show that imperfectly oxygen coordinated V sites (i.e., not fourfold oxygen coordinated vanadium but threefold oxygen coordinated vanadium) exposed on the catalyst surface play a central role in the dissociation of water molecules. By simulating the H{sub 2}O adsorption process and by performing an analysis of the electronic structure of the unoccupied orbitals corresponding to the lowest unoccupied energy level of the system, we can infer that the dissociation of water at these imperfectly oxygen coordinated V sites can promote the proton reduction and is expected to trigger the H{sub 2} generation.

  14. Groundwater monitoring program plan and conceptual site model for the Al-Tuwaitha Nuclear Research Center in Iraq.

    SciTech Connect (OSTI)

    Copland, John Robin; Cochran, John Russell

    2013-07-01

    The Radiation Protection Center of the Iraqi Ministry of Environment is developing a groundwater monitoring program (GMP) for the Al-Tuwaitha Nuclear Research Center located near Baghdad, Iraq. The Al-Tuwaitha Nuclear Research Center was established in about 1960 and is currently being cleaned-up and decommissioned by Iraq's Ministry of Science and Technology. This Groundwater Monitoring Program Plan (GMPP) and Conceptual Site Model (CSM) support the Radiation Protection Center by providing:A CSM describing the hydrogeologic regime and contaminant issues,recommendations for future groundwater characterization activities, anddescriptions of the organizational elements of a groundwater monitoring program. The Conceptual Site Model identifies a number of potential sources of groundwater contamination at Al-Tuwaitha. The model also identifies two water-bearing zones (a shallow groundwater zone and a regional aquifer). The depth to the shallow groundwater zone varies from approximately 7 to 10 meters (m) across the facility. The shallow groundwater zone is composed of a layer of silty sand and fine sand that does not extend laterally across the entire facility. An approximately 4-m thick layer of clay underlies the shallow groundwater zone. The depth to the regional aquifer varies from approximately 14 to 17 m across the facility. The regional aquifer is composed of interfingering layers of silty sand, fine-grained sand, and medium-grained sand. Based on the limited analyses described in this report, there is no severe contamination of the groundwater at Al-Tuwaitha with radioactive constituents. However, significant data gaps exist and this plan recommends the installation of additional groundwater monitoring wells and conducting additional types of radiological and chemical analyses.

  15. Nevada National Security Site 2010 Data Report: Groundwater Monitoring Program Area 5 Radioactive Waste Management Site

    SciTech Connect (OSTI)

    NSTec Environmental Management

    2011-01-01

    This report is a compilation of the groundwater sampling results from the Area 5 Radioactive Waste Management Site (RWMS). The data have been collected since 1993 and include calendar year 2010 results. During 2010, groundwater samples were collected and static water levels were measured at the three pilot wells surrounding the Area 5 RWMS. Samples were collected at UE5PW-1 on March 10 and August 10, 2010; at UE5PW-2 on March 10, August 10, and August 25, 2010; and at UE5PW-3 on March 31, August 10, and August 25, 2010. Static water levels were measured at each of the three pilot wells on March 1, April 26, August 9, and November 9, 2010. Groundwater samples were analyzed for the following indicators of contamination: pH, specific conductance, total organic carbon, total organic halides, and tritium. Indicators of general water chemistry (cations and anions) were also measured. Results from all samples collected in 2010 were within the limits established by agreement with the Nevada Division of Environmental Protection for each analyte. These data indicate that there has been no measurable impact to the uppermost aquifer from the Area 5 RWMS. There were no significant changes in measured groundwater parameters compared to previous years. The report contains an updated cumulative chronology for the Area 5 RWMS Groundwater Monitoring Program and a brief description of the site hydrogeology.

  16. Effects of common groundwater ions on chromate removal by magnetite: Importance of chromate adsorption

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meena, Amanda H.; Arai, Yuji

    2016-04-29

    Reductive precipitation of hexavalent chromium (Cr(VI)) with magnetite is a well-known Cr(VI) remediation method to improve water quality. The rapid (< a few hr) reduction of soluble Cr(VI) to insoluble Cr(III) species by Fe(II) in magnetite has been the primary focus of the Cr(VI) removal process in the past. However, the contribution of simultaneous Cr(VI) adsorption processes in aged magnetite has been largely ignored, leaving uncertainties in evaluating the application of in situ Cr remediation technologies for aqueous systems. In this study, effects of common groundwater ions (i.e., nitrate and sulfate) on Cr(VI) sorption to magnetite were investigated using batchmore » geochemical experiments in conjunction with X-ray absorption spectroscopy. As a result, in both nitrate and sulfate electrolytes, batch sorption experiments showed that Cr(VI) sorption decreases with increasing pH from 4 to 8. In this pH range, Cr(VI) sorption decreased with increasing ionic strength of sulfate from 0.01 to 0.1 M whereas nitrate concentrations did not alter the Cr(VI) sorption behavior. This indicates the background electrolyte specific Cr(VI) sorption process in magnetite. Under the same ionic strength, Cr(VI) removal in sulfate containing solutions was greater than that in nitrate solutions. This is because the oxidation of Fe(II) by nitrate is more thermodynamically favorable than by sulfate, leaving less reduction capacity of magnetite to reduce Cr(VI) in the nitrate media. X-ray absorption spectroscopy analysis supports the macroscopic evidence that more than 75 % of total Cr on the magnetite surfaces was adsorbed Cr(VI) species after 48 h. In conclusion, this experimental geochemical study showed that the adsorption process of Cr(VI) anions was as important as the reductive precipitation of Cr(III) in describing the removal of Cr(VI) by magnetite, and these interfacial adsorption processes could be impacted by common groundwater ions like sulfate and nitrate. The

  17. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at...

  18. Survey of reinjection experience from groundwater cooling applications

    SciTech Connect (OSTI)

    Snyder, M.; Lee, C.H.

    1980-09-01

    The use of groundwater for cooling applications is a common practice throughout the country wherever an adequate supply of water exists. However, the reinjection of the cooling water to water-bearing strata is not as widely practiced. The literature pertaining to reinjection of heated water is not well documented. To fulfill the need for more information, a study was conducted to identify and document at least 30 sites where reinjection of grundwater from cooling applications was being (or had been) performed. The information obtained on each site was compiled and analyzed, the site described briefly and cooling and reinjection problems characterized. The end result of this study was to establish a data base of reinjection experience based on a variety of sites around the country with different hydrogeologic characteristics and cooling systems. These data are presented.

  19. Microsoft Word - 2014_1Qtr_Water_Protection_010914.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EP2014-0002 LA-UR-14-20093 Groundwater Protection Surface Water Protection LANL Water Protection Status Report - Fiscal Year 2014 First Quarter (October to December 2013) * An event is a single-screen well location, each individual well screen for multiscreen wells, spring, or base-flow location. ** San Ildefonso locations included in both the IFGMP and San Ildefonso MOU are identified as San Ildefonso locations for this report. FY13, 4 th Quarter (Jul-Sep) Analytical Summary: Analysis of the 84

  20. Wadter Resources Data Ohio: Water year 1994. Volume 2, St. Lawrence River Basin and Statewide Project Data

    SciTech Connect (OSTI)

    1994-12-31

    The Water Resources Division of the US Geological Survey (USGS), in cooperation with State agencies, obtains a large amount of data each water year (a water year is the 12-month period from October 1 through September 30 and is identified by the calendar year in which it ends) pertaining to the water resources of Ohio. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, they are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for streamflow-gaging stations, miscellaneous sites, and crest-stage stations; (2) stage and content records for streams, lakes, and reservoirs; (3) water-quality data for streamflow-gaging stations, wells, synaptic sites, and partial-record sites; and (4) water-level data for observation wells. Locations of lake- and streamflow-gaging stations, water-quality stations, and observation wells for which data are presented in this volume are shown in figures ga through 8b. The data in this report represent that part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Ohio. This series of annual reports for Ohio began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report was changed to present (in two to three volumes) data on quantities of surface water, quality of surface and ground water, and ground-water levels.