Sample records for ground-level ozone limits

  1. Ground-level ozone in the 21st century: future trends,

    E-Print Network [OSTI]

    Ground-level ozone in the 21st century: future trends, impacts and policy implications October 2008. Courtesy of Dr Mhairi Coyle, CEH Edinburgh. #12;Ground-level ozone in the 21st century: future trends Limited #12;Ground-level ozone in the 21st century I October 2008 I iiiThe Royal Society Ground

  2. Modeling Transport E ects on Ground-Level Ozone Using a

    E-Print Network [OSTI]

    Huang, Su-Yun

    Modeling Transport E ects on Ground-Level Ozone Using a Non-Stationary Space-Time Model Hsin on Ground-Level Ozone 1 #12;Summary This article presents a novel autoregressive space-time model for ground-level ozone data, which models not only spatio-temporal dynamics of hourly ozone con- centrations, but also

  3. INTERRELAITONS BETWEEN VARIABILITY OF GROUND-LEVEL OZONE AND LAND COVER CHANGE

    E-Print Network [OSTI]

    Wang, Y.Q. "Yeqiao"

    to reduce ground-level ozone concentrations, including removal of highway tolls, use of vapor recovery million (ppm) over one-hour period. Air quality reports show that northeast United States has been

  4. Reducing the contribution of the power sector to ground-level ozone pollution : an assessment of time-differentiated pricing of nitrogen oxide emissions

    E-Print Network [OSTI]

    Craig, Michael T. (Michael Timothy)

    2014-01-01T23:59:59.000Z

    Nitrogen oxide (NOx) is a prevalent air pollutant across the United States and a requisite precursor for tropospheric (ground-level) ozone formation. Both pollutants significantly impact human health and welfare, so National ...

  5. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  6. THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, Carol [Savannah River Site (SRS), Aiken, SC (United States). Savannah River Remediation, LLC; Osterberg, Paul [Fauske and Associates, LLC, Burr Ridge, IL (United States); Johnson, Tom [Fauske and Associates, LLC, Burr Ridge, IL (United States); Frawely, Thomas [Fauske and Associates, LLC, Burr Ridge, IL (United States)

    2013-01-23T23:59:59.000Z

    The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

  7. The 1996 and 1997 Paso del Norte ozone studies: An overview of the field studies and data analyses

    SciTech Connect (OSTI)

    MacDonald, C.P.; Roberts, P.T.; Main, H.H.; Dye, T.S.; Coe, D.L.; Yarbrough, J.

    1999-07-01T23:59:59.000Z

    This paper summarizes the measurement campaigns of the 1996 and 1997 Paso del Norte Ozone Studies, the resultant data sets, and the findings and conclusions that arose from subsequent data analyses. The purpose of these data analyses was to develop an understanding of the significant chemical and physical processes that lead to high concentrations of ozone in the Paso del Norte study region which includes El Paso, TX; Sunland Park, NM; and Juarez, Mexico. High ozone concentrations resulted from a combination of conditions, including slow convective boundary layer (CBL) growth, reduced CBL depth, light surface winds, and high concentrations of ozone precursor at ground level in the morning. Synoptic-scale meteorological conditions observed during high ozone episodes included an upstream aloft high-pressure system, and aloft warming. Aloft carryover of ozone and ozone precursors did not significantly contribute to the surface ozone concentration. Furthermore, hydrocarbon and NO{sub x} data, although spatially limited, showed that the system is more often NO{sub x}-limited rather than VOC-limited.

  8. Detection of 6 November 1997 Ground Level Event by Milagrito

    E-Print Network [OSTI]

    Atkins, R; Berley, D; Chen, M L; Coyne, D G; Delay, R S; Dingus, B L; Dorfan, D E; Ellsworth, R W; Evans, D; Falcone, A D; Fleysher, L; Fleysher, R; Gisler, G; Goodman, J A; Haines, T J; Hoffman, C M; Hugenberger, S; Kelley, L A; Leonor, I; Macri, J R; McConnell, M; McCullough, J F; McEnery, J E; Miller, R S; Mincer, A I; Morales, M F; Némethy, P; Ryan, J M; Schneider, M; Shen, B; Shoup, A L; Sinnis, G; Smith, A J; Sullivan, G W; Thompson, T N; Tümer, T O; Wang, K; Wascko, M O; Westerhoff, S; Williams, D A; Yang, T; Yodh, G B

    1999-01-01T23:59:59.000Z

    Solar Energetic Particles from the 6 November 1997 solar flare/CME(coronal mass ejection) with energies exceeding 10 GeV have been detected by Milagrito, a prototype of the Milagro Gamma Ray Observatory. While particle acceleration beyond 1 GeV at the Sun is well established, few data exist for protons or ions beyond 10 GeV. The Milagro observatory, a ground based water Cherenkov detector designed for observing very high energy gamma ray sources, can also be used to study the Sun. Milagrito, which operated for approximately one year in 1997/98, was sensitive to solar proton and neutron fluxes above ~5- 10 GeV. Milagrito operated in a scaler mode, which was primarily sensitive to muons, low energy photons, and electrons, and the detector operated in a mode sensitive to showers and high zenith angle muons. In its scaler mode, Milagrito registered a rate increase coincident with the 6 November 1997 ground level event observed by Climax and other neutron monitors. A preliminary analysis suggests the presence of >...

  9. Detection of 6 November 1997 Ground Level Event by Milagrito

    E-Print Network [OSTI]

    R. Atkins; W. Benbow; D. Berley; M. -L. Chen; D. G. Coyne; R. S. Delay; B. L. Dingus; D. E. Dorfan; R. W. Ellsworth; D. Evans; A. Falcone; L. Fleysher; R. Fleysher; G. Gisler; J. A. Goodman; T. J. Haines; C. M. Hoffman; S. Hugenberger; L. A. Kelley; I. Leonor; J. Macri; M. McConnell; J. F. McCullough; J. E. McEnery; R. S. Miller; A. I. Mincer; M. F. Morales; P. Nemethy; J. M. Ryan; M. Schneider; B. Shen; A. Shoup; G. Sinnis; A. J. Smith; G. W. Sullivan; T. N. Thompson; O. T. Tumer; K. Wang; M. O. Wascko; S. Westerhoff; D. A. Williams; T. Yang; G. B. Yodh

    1999-06-24T23:59:59.000Z

    Solar Energetic Particles from the 6 November 1997 solar flare/CME(coronal mass ejection) with energies exceeding 10 GeV have been detected by Milagrito, a prototype of the Milagro Gamma Ray Observatory. While particle acceleration beyond 1 GeV at the Sun is well established, few data exist for protons or ions beyond 10 GeV. The Milagro observatory, a ground based water Cherenkov detector designed for observing very high energy gamma ray sources, can also be used to study the Sun. Milagrito, which operated for approximately one year in 1997/98, was sensitive to solar proton and neutron fluxes above ~5- 10 GeV. Milagrito operated in a scaler mode, which was primarily sensitive to muons, low energy photons, and electrons, and the detector operated in a mode sensitive to showers and high zenith angle muons. In its scaler mode, Milagrito registered a rate increase coincident with the 6 November 1997 ground level event observed by Climax and other neutron monitors. A preliminary analysis suggests the presence of >10 GeV particles.

  10. Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux measurements

    E-Print Network [OSTI]

    Silver, Whendee

    Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux Abstract High ground-level ozone concentrations are typical of Mediterranean climates. Plant exposure to this oxidant is known to reduce carbon assimilation. Ozone damage has been traditionally measured through

  11. Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis) in Great Smoky Mountains

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis ``Capsule'': Ground-level ozone causes deleterious effects to cutleaf coneflower and crown-beard in Great Smoky Mountains National Park. Abstract Incidence and severity of visible foliar ozone injury on cutleaf

  12. THE EFFECT OF THE PRESENCE OF OZONE ON THE LOWER FLAMMABILITY LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, C.

    2012-01-12T23:59:59.000Z

    The Enhanced Chemical Cleaning (ECC) process uses ozone to effect the oxidation of metal oxalates produced during the dissolution of sludge in the Savannah River Site (SRS) waste tanks. The ozone reacts with the metal oxalates to form metal oxide and hydroxide precipitants, and the CO{sub 2}, O{sub 2}, H{sub 2}O and any unreacted O{sub 3} gases are discharged into the vapor space. In addition to the non-radioactive metals in the waste, however, the SRS radioactive waste also contains a variety of radionuclides, hence, hydrogen gas is also present in the vapor space of the ECC system. Because hydrogen is flammable, the impact of this resultant gas stream on the Lower Flammability Limit (LFL) of hydrogen must be understood for all possible operating scenarios of both normal and off-normal situations, with particular emphasis at the elevated temperatures and pressures of the typical ECC operating conditions. Oxygen is a known accelerant in combustion reactions, but while there are data associated with the behavior of hydrogen/oxygen environments, recent, relevant studies addressing the effect of ozone on the flammability limit of hydrogen proved scarce. Further, discussions with industry experts verified the absence of data in this area and indicated that laboratory testing, specific to defined operating parameters, was needed to comprehensively address the issue. Testing was thus designed and commissioned to provide the data necessary to support safety related considerations for the ECC process. A test matrix was developed to envelope the bounding conditions considered credible during ECC processing. Each test consists of combining a gas stream of high purity hydrogen with a gas stream comprised of a specified mixture of ozone and oxygen in a temperature and pressure regulated chamber such that the relative compositions of the two streams are controlled. The gases are then stirred to obtain a homogeneous mixture and ignition attempted by applying 10J of energy to a fuse wire. A gas combination is considered flammable when a pressure rise of 7% of the initial absolute pressure is observed. The specified testing methodology is consistent with guidelines established in ASTM E-918-83 (2005) 'Standard Practices for Determining Limits of Flammability of Chemicals at Elevated Temperature and Pressure'.

  13. A ground level gamma-ray burst observed in association with rocket-triggered lightning

    E-Print Network [OSTI]

    Florida, University of

    A ground level gamma-ray burst observed in association with rocket-triggered lightning J. R. Dwyer 2004; published 13 March 2004. [1] We report the observation of an intense gamma-ray burst observed lightning channel with gamma-ray energies extending up to more than 10 MeV. The burst consisted of 227

  14. ESTIMATING GROUND-LEVEL SOLAR RADIATION AND EVAPOTRANSPIRATION IN PUERTO RICO

    E-Print Network [OSTI]

    Gilbes, Fernando

    1 ESTIMATING GROUND-LEVEL SOLAR RADIATION AND EVAPOTRANSPIRATION IN PUERTO RICO USING SATELLITE between the methods. A comparison between estimated and observed solar radiation is also presented for the period April 1 through June 21, 2009, which indicates a need for calibration of the solar radiation

  15. The urinary excretion of unchanged d-amphetamine by rats at ground level and at altitude

    E-Print Network [OSTI]

    Harwell, James Franklin

    1968-01-01T23:59:59.000Z

    divided into 3 equal groups. One group received ammonium chloride to acidify the urine, a second group received sodium bicarbonate to alkalinize the urine, and the third group received distilled water. Immediately after receiving the pretreatment... solutions each rat was in3ected subcutaneously with d-amphetamine sulfate at the rate of 3 mg/kg body weight. Each rat was put into a metabolic cage and a 4 hour urine sample was collected at ground level. After a rest period of at least 48 hours...

  16. web page: http://w3.pppl.gov/~ zakharov At the ground level of integrated modeling1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    web page: http://w3.pppl.gov/~ zakharov At the ground level of integrated modeling1 Leonid E-independent environment and integrating them with its capabilities (e.g., java). (f) . . . of other integrations (WEB of D

  17. Modelling surface ozone during the 2003 heat-wave in the UK 

    E-Print Network [OSTI]

    Vieno, Massimo; Dore, A J; Stevenson, David S; Doherty, Ruth; Heal, Mathew R; Reis, Stefan; Hallsworth, Stephen; Tarrason, L; Wind, P; Fowler, David; Simpson, David; Sutton, Mark A

    2010-01-01T23:59:59.000Z

    of ground-level ozone (O3) during the extreme August 2003 heat-wave. Meteorology is generated by the Weather Research and Forecast (WRF) model, nudged every six hours with reanalysis data. We focus on SE England, where hourly average O3 reached up to 140 ppb...

  18. A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani

    E-Print Network [OSTI]

    Corani, Giorgio

    in air pollution studies because of their impact on human health and agricultural crops and forests. High,guariso@elet.polimi.it Abstract: Ground level ozone pollution is a complex phenomenon heavily affecting industrialized and pop problem that determines the least cost alternatives to obtain a given air quality standard. The decision

  19. Quantifying the contributions to stratospheric ozone changes from ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Quantifying the contributions to stratospheric ozone changes from ozone depleting substances Chemistry and Physics Quantifying the contributions to stratospheric ozone changes from ozone depleting by different combinations of long-lived Greenhouse Gases (GHGs) and Ozone Depleting Substances (ODSs

  20. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01T23:59:59.000Z

    Global and zonal total ozone variations estimated fromon multidecadal total ozone simulations, J. Geophys. Res. ,and J. A. Logan (2007), Ozone climatolo- gical profiles for

  1. The Ozone Hole Some perspective

    E-Print Network [OSTI]

    Toohey, Darin W.

    The Ozone Hole · Some perspective · The British Antarctic Survey · The "Ozone Hole" · International of the predicted ozone losses! This was quite a controversy. Ultimately, ozone losses started appearing in the late 1980s (see Figure below), but by then, there was already a credibility issue for ozone scientists. #12

  2. Midlatitude Ozone: Loss and Trends

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 17 Midlatitude Ozone: Loss and Trends ATOC/CHEM 5151 #12;2 Importance of midlatitude ozone · Covers most of the world's populated areas · Provides protection from UV #12;3 Ozone loss picture, c. 1988 #12;4 Lower vs. Upper stratosphere #12;5 Ozone loss, post 1988 · Discovery of ozone hole

  3. Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: Algorithm description and validation

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment October 2005. [1] Ozone profiles are derived from back scattered radiance spectra in the ultraviolet (289­339 nm) measured by the Global Ozone Monitoring Experiment (GOME) using the optimal estimation technique

  4. Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles.

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles breaks down before sunlight returns: smaller ozone hole { Formation of polar stratospheric clouds (PSC #3; Photo-initiation reactions: Cl 2 h#23; ! 2Cl HOCl h#23; ! OH + Cl #3; Rapid destruction of ozone

  5. 6, 74277469, 2006 Linear ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 7427­7469, 2006 Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Chemistry and Physics Discussions Evaluation of linear ozone photochemistry parametrizations Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Abstract Introduction

  6. NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY

    E-Print Network [OSTI]

    vi NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY Prepared as a NARSTO initiative, this tropospheric O3 in the accompanying Textbox, the NARSTO Ozone Assessment contains two product components. The first of these is a set aspects of tropospheric ozone pollution. The second component, the NARSTO Ozone Assessment Document

  7. Estimating GroundEstimating Ground--Level Solar RadiationLevel Solar Radiation and Evapotranspiration In Puerto Ricoand Evapotranspiration In Puerto Rico

    E-Print Network [OSTI]

    Gilbes, Fernando

    Estimating GroundEstimating Ground--Level Solar RadiationLevel Solar Radiation radiation, therefore, solar radiation measurements throughout the island are essential. #12;Currently, including solar radiation ·In PR, solar radiation is only available at selected locations. · The majority

  8. Artificial ozone holes

    E-Print Network [OSTI]

    S. N. Dolya

    2014-10-18T23:59:59.000Z

    This article considers an opportunity of disinfecting a part of the Earth surface, occupying a large area of ten thousand square kilometers. The sunlight will cause dissociation of molecular bromine into atoms; each bromine atom kills thirty thousand molecules of ozone. Each bromine plate has a mass of forty milligrams grams and destroys ozone in the area of hundred square meters. Thus, to form the ozone hole over the area of ten thousand square kilometers, it is required to have the total mass of bromine equal to the following four tons.

  9. Cros S., Wald L., 2003. Survey of the main databases providing solar radiation data at ground level. In Proceedings of the 23rd EARSeL Annual Symposium "Remote Sensing in Transition", 2-4 June 2003, Ghent,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Cros S., Wald L., 2003. Survey of the main databases providing solar radiation data at ground level providing solar radiation data at the ground level S. Cros & L. Wald Remote Sensing and Modeling Group, Ecole des Mines de Paris, France Keywords: solar radiation, database, information system, climatology

  10. 5, 59575985, 2005 European ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract Introduction explain the trends in European ozone levels? J. E. Jonson 1 , D. Simpson 1 , H. Fagerli 1 , and S. Solberg License. 5957 #12;ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract

  11. 6, 56715709, 2006 Hemispheric ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page Chemistry and Physics Discussions Hemispheric ozone variability indices derived from satellite observations.erbertseder@dlr.de) 5671 #12;ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page

  12. 4, 32853332, 2004 Tropospheric ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 3285­3332, 2004 Tropospheric ozone over Equatorial Africa B. Sauvage et al. Title Page and Physics Discussions Tropospheric ozone over Equatorial Africa: regional aspects from the MOZAIC data B Correspondence to: B. Sauvage (saub@aero.obs-mip.fr) 3285 #12;ACPD 4, 3285­3332, 2004 Tropospheric ozone over

  13. 5, 38113845, 2005 Antarctic ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al. Title Page Discussions Indicators of Antarctic ozone depletion G. E. Bodeker 1 , H. Shiona 1 , and H. Eskes 2 1 National Commons License. 3811 #12;ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al

  14. Assimilation of Aura ozone data

    E-Print Network [OSTI]

    Assimilation of Aura ozone data I. Stajner, H. Hayashi, K. Wargan, L.-P. Chang, and S. Pawson Global Modeling and Assimilation Office (GMAO) NASA/Goddard AGU Fall meeting December 2004 #12;2 Ozone assimilation at GMAO · Total ozone columns and stratospheric profiles from SBUV/2 instrument are assimilated

  15. 2, 921942, 2002 Global ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 921­942, 2002 Global ozone forecasting H. J. Eskes et al. Title Page Abstract Introduction Geophysical Society 2002 Atmospheric Chemistry and Physics Discussions Global ozone forecasting based on ERS-2 July 2002 Correspondence to: H. J. Eskes (eskes@knmi.nl) 921 #12;ACPD 2, 921­942, 2002 Global ozone

  16. 6, 51375162, 2006 Oceanic ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W. Fairall et al. Title Page Abstract Discussions Water-side turbulence enhancement of ozone deposition to the ocean C. W. Fairall1 , D. Helmig2 , L. Fairall (chris.fairall@noaa.gov) 5137 #12;ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W

  17. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31T23:59:59.000Z

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  18. Ozone decomposition in water solutions 

    E-Print Network [OSTI]

    Hewes, Cecil Grayson

    1969-01-01T23:59:59.000Z

    OF LITERATUR 1V Vi ~ V111 III ~ EXPERIMENTAL SYSTEM AND ITS OPERATION 14 IV. DISCUSS10N OF RESULTS AND COiJCLUSION. . . 24 i~JOMENCLATUHE. BIBLIOGRAPIFY APPENDIX I. WASTE WATER REGENERATION BY OZONATION. II. AMINE REMOVAL BY OZONATION...ATER SOLUTIONS OF pH 8. XIII. REACTION RATE CONSTANTS FOR THE D'COMPOSITION OF OZONE IN INTER SOLUTIONS OF pH 8. XIV COD REMOVAL BY OZONE XV. OZONIZATION OF MATER CONTAINIiNG RESIDUAL AMINE. 57 60 LIST OF FIGURES FIGURE 1. FIOW DIAGRAM OF THZ...

  19. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

    1999-01-01T23:59:59.000Z

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  20. N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone"

    E-Print Network [OSTI]

    Heller, Barbara

    as well. Images identified with "ozone" in the title are as follows: C187 Ozone Diagram C879 Lungs of two Toxicity Dr. Hans-Georg Clamann, physiologist C2346 Ozone Toxicity, M. King C2347 Ozone Toxicity, Pvt. D. F. Smith, Jr. Sgt. J. C. Rawdon C2348 Ozone Toxicity, S. Mittler, F. J. Hennigan C2349 Ozone Toxicity Pvt

  1. Solving the Tulsa ozone problem

    SciTech Connect (OSTI)

    Wagner, K.K. [Atmospheric Information Systems, Norman, OK (United States); Wilson, J.D. [Wilson Consulting Group, Tulsa, OK (United States); Gibeau, E. [Aeromet Inc., Tulsa, OK (United States)

    1998-12-31T23:59:59.000Z

    Local governments and interested parties in Tulsa, Oklahoma are planning actions to keep Tulsa in compliance with the ozone ambient air quality standard. Based on recent data Tulsa exceeds the new eight hour average national ambient air quality standard for ozone and occasionally exceeds the previous one hour standard. Currently, Tulsa is in attainment of the former one-hour ozone standard. The first planning step is to integrate the existing information about Tulsa`s ozone problem. Prior studies of Tulsa ozone are reviewed. Tulsa`s recent air quality and meteorological monitoring are evaluated. Emission inventory estimates are assessed. Factors identified with Tulsa`s ozone problem are the transport of ozone and precursor gases, a possible role for biogenic emissions, and a simplistic ozone forecasting method. The integration of information found that current air quality and meteorological monitoring is meager. Observations of volatile organic compounds and NO{sub y} are absent. Prior intensive studies in 1977 and 1985 are more than ten years old and lack relevance to today`s problem. Emission inventory estimates are scarce and uncertain. The current knowledge base was judged inadequate to properly characterize the present ozone problem. Actions are recommended to enlarge the information base to address Tulsa`s ozone problem.

  2. Spectroscopic measurement of bromine oxide and ozone in the high Arctic during Polar Sunrise Experiment 1992

    SciTech Connect (OSTI)

    Hausmann, M.; Platt, U. [Universitaet Heidelberg (Germany)] [Universitaet Heidelberg (Germany)

    1994-12-20T23:59:59.000Z

    The authors report the measurement of BrO radical densities and ozone in the Arctic troposphere by means of differential optical absorption using very long paths. They observed levels of BrO which varied from below the detection limit to 17 ppt. Such concentrations alone cannot account for the catalytic destruction of ozone observed during periods of episodic ozone variation. The authors offer a model which involves BrO catalyzed reactions, advection, and atmospheric mixing which they argue could account for the observed ozone depletions.

  3. 6, 66276694, 2006 linearized ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al. Title Chemistry and Physics Discussions CHEM2D-OPP: A new linearized gas-phase ozone photochemistry.mccormack@nrl.navy.mil) 6627 #12;ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al

  4. Nonaqueous ozonation of vulcanized rubber

    SciTech Connect (OSTI)

    Serkiz, S.M.

    1999-12-07T23:59:59.000Z

    A process and resulting product are provided in which a solid particulate, such as vulcanized crumb rubber, has the surface functional groups oxidized by ozonation using a nonpolar solvent. The ozonation process renders the treated crumb rubber more suitable for use in new rubber formulations. As a result, larger loading levels of the treated crumb rubber can be used in new rubber mixtures.

  5. Nonaqueous ozonation of vulcanized rubber

    SciTech Connect (OSTI)

    Serkiz, Steven M. (Aiken, SC)

    1999-01-01T23:59:59.000Z

    A process and resulting product is provided in which a solid particulate, such as vulcanized crumb rubber, has the surface functional groups oxidized by ozonation using a nonpolar solvent. The ozonation process renders the treated crumb rubber more suitable for use in new rubber formulations. As a result, larger loading levels of the treated crumb rubber can be used in new rubber mixtures.

  6. Multi-model assessment of stratospheric ozone return dates and ozone recovery in

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Multi- model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models of stratospheric ozone return dates and ozone recovery in CCMVal-2 models V. Eyring1, I. Cionni1, G. E. Bodeker2, A September 2010 ­ Published: 7 October 2010 Abstract. Projections of stratospheric ozone from a suite

  7. Phenomena that influence high ozone concentrations in the Paso del Norte area

    SciTech Connect (OSTI)

    MacDonald, C.P.; Roberts, P.T.; Main, H.H.; Dye, T.S. [Sonoma Technology, Inc., Santa Rosa, CA (United States); Yarbrough, J. [EPA, Dallas, TX (United States)

    1998-12-31T23:59:59.000Z

    This paper summarizes the results of analyses of meteorological and air quality data for the 1996 Paso del Norte Ozone Study. The purpose of these data analyses was to develop an understanding of the significant chemical and physical processes which lead to high concentrations of ozone in the Paso del Norte study region which includes El Paso, TX; Sunland Park, NM; and Juarez, Mexico. This analysis has shown that the high ozone concentrations are a result of slow convective boundary layer growth, reduced convective boundary layer depth, light surface winds, and high morning surface ozone precursor concentrations. Overlying meteorological conditions observed during high ozone episodes include an upstream aloft high pressure system, aloft warming, and weak surface pressure gradients. The analysis has also shown that aloft carryover of ozone and ozone precursors does not significantly contribute to the surface ozone concentration. Furthermore, hydrocarbon and NO{sub x} data, although spatially limited, show that the system is most often NO{sub x} rather than VOC limited.

  8. EARTH OBSERVATION 400M Indians Endangered By Ozone

    E-Print Network [OSTI]

    Singh, Ramesh P.

    has been linked to increases in skin cancer rates. All rights reserved. © 2004 United Press using satellite and limited ground observations, the Press Trust of India reported Tuesday. The rate the reasons for the depletion, th e report states. Ozone is an important atmospheric trace gas that blocks

  9. Oceanic alkyl nitrates as a natural source of tropospheric ozone

    E-Print Network [OSTI]

    Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

    2008-01-01T23:59:59.000Z

    Chemical transport model ozone simulations for spring 2001ozonesondes, and Total Ozone Mapping Spectrometer columns,behaviour of tropospheric ozone precursors in a global 3-D

  10. Intercontinental Impacts of Ozone Pollution on Human Mortality

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    relationships for ozone pollution. J. Geophys. Res. 2009,benefits of mitigating ozone pollution with methane emissioninfluence of European pollution on ozone in the Near East

  11. Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    Part I: NO x , PAN and Ozone Relationships, J. Atmos.Bromine measurements in ozone depleted air over the Arcticto springtime tropospheric ozone maxima using TOPSE measure-

  12. Lefvre M., Cros S., Albuisson M., Wald L., 2003. Developing a database using Meteosat data for the de-livery of solar radiation assessments at ground level. In Proceedings of the 23rd EARSeL Annual Symposium

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    for the de- livery of solar radiation assessments at ground level. In Proceedings of the 23rd EARSeL Annual, Meteosat, solar radiation, climatology, database, information system ABSTRACT: An information system, called HelioClim, is offered for answering the needs for long-term time-series of solar radiation data

  13. ATOC 3500/CHEM 3151 Spring 2014 Stratospheric Ozone Destruction in the "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC 3500/CHEM 3151 Spring 2014 Problem 15 Stratospheric Ozone Destruction in the "Ozone Hole" The figure below shows typical observations of the total amount of ozone in a layer of air 8 km thick between 12 and 20 km over the South Pole (recall that we like to express the `thickness of ozone

  14. Ozone Reductions using Residential Building Envelopes

    E-Print Network [OSTI]

    Ozone Reductions using Residential Building Envelopes I.S. Walker, M.H. Sherman and W.W. Nazaroff or adequacy of the information in this report. #12;Arnold Schwarzenegger Governor Ozone Reductions Using

  15. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097­10129, 2007 Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Page Abstract Introduction

  16. 5, 243286, 2005 Retrieval of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 243­286, 2005 Retrieval of ozone column content during SOLVE II J. M. Livingston et al and Physics Discussions Retrieval of ozone column content from airborne Sun photometer measurements during Aerospace Center), Oberpfaffenhofen, Wessling, Germany 243 #12;ACPD 5, 243­286, 2005 Retrieval of ozone

  17. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  18. 6, 43254340, 2006 Scaling in ozone and

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title Chemistry and Physics Discussions Long-memory processes in global ozone and temperature variations C #12;ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title

  19. 7, 22492274, 2007 Vertical ozone over

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean and Central Europe P. D a Creative Commons License. Atmospheric Chemistry and Physics Discussions Vertical ozone measurements (kalabokas pavlos@yahoo.gr) 2249 #12;ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean

  20. 8, 31433162, 2008 Total ozone over

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 3143­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Chemistry and Physics Discussions Total column ozone variations over oceanic region around Indian sub­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Abstract Introduction

  1. 8, 50075060, 2008 Evaluation of ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 5007­5060, 2008 Evaluation of ozone trends from g-b FTIR observations C. Vigouroux et al.0 License. Atmospheric Chemistry and Physics Discussions Evaluation of tropospheric and stratospheric ozone Publications on behalf of the European Geosciences Union. 5007 #12;ACPD 8, 5007­5060, 2008 Evaluation of ozone

  2. 8, 49114947, 2008 NOx-induced ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract Chemistry and Physics Discussions Model simulations of stratospheric ozone loss caused by enhanced on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

  3. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  4. 6, 84578483, 2006 Low ozone over the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 8457­8483, 2006 Low ozone over the UK M. Keil et al. Title Page Abstract Introduction Discussions The January 2006 low ozone event over the UK M. Keil, D. R. Jackson, and M. C. Hort Met Office 2006 Correspondence to: M. Keil (mike.keil@metoffice.gov.uk) 8457 #12;ACPD 6, 8457­8483, 2006 Low ozone

  5. 5, 96419668, 2005 The origin of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 9641­9668, 2005 The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions-5-9641 European Geosciences Union Atmospheric Chemistry and Physics Discussions The origin of ozone V. Grewe The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions References Tables Figures Back

  6. 6, 39133943, 2006 Svalbard total ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 3913­3943, 2006 Svalbard total ozone C. Vogler et al. Title Page Abstract Introduction Discussions Re-evaluation of the 1950­1962 total ozone record from Longyearbyen, Svalbard C. Vogler 1 , S. Br total ozone C. Vogler et al. Title Page Abstract Introduction Conclusions References Tables Figures Back

  7. 3, 187223, 2003 TOMS cloudy ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 3, 187­223, 2003 TOMS cloudy ozone anomaly X. Liu et al. Title Page Abstract Introduction Geosciences Union 2003 Atmospheric Chemistry and Physics Discussions Occurrence of ozone anomalies over cloudy 2003 Correspondence to: X. Liu (xliu@nsstc.uah.edu) 187 #12;ACPD 3, 187­223, 2003 TOMS cloudy ozone

  8. 3, 10811107, 2003 Mid-latitude ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 3, 1081­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page-dimensional model study of long-term mid-high latitude lower stratosphere ozone changes M. P. Chipperfield School­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page Abstract Introduction

  9. Ozone: Integrating Structured and Semistructured Data ?

    E-Print Network [OSTI]

    Abiteboul, Serge

    Ozone: Integrating Structured and Semistructured Data ? Tirthankar Lahiri 1 , Serge Abiteboul 2 language, and we implement our extensions in a system called Ozone. In our approach, structured data may full knowledge of structure. Ozone also enhances both ODMG/OQL and OEM/Lorel by virtue

  10. 4, 21672238, 2004 Ozone loss and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 2167­2238, 2004 Ozone loss and chlorine activation in the Arctic winters 1991­2003 S Union 2004 Atmospheric Chemistry and Physics Discussions Ozone loss and chlorine activation Correspondence to: S. Tilmes (simone.tilmes@t-online.de) 2167 #12;ACPD 4, 2167­2238, 2004 Ozone loss and chlorine

  11. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01T23:59:59.000Z

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  12. 2, 15091543, 2002 Ozone production

    E-Print Network [OSTI]

    Boyer, Edmond

    .atmos-chem-phys.org/acpd/2/1509/ c European Geosciences Union 2002 Atmospheric Chemistry and Physics Discussions Ozone as a consequence of local catabatic winds. Aver- age mid-day peroxy radical concentrations at Mt. Cimone; Atlas and Ridley, 1996; Fischer et al., 1998; Zanis et al., 2000a, b). Often, free tropospheric

  13. Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam

    SciTech Connect (OSTI)

    Pratt, A. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Department of Physics, University of York, Heslington, York YO10 5DD (United Kingdom); Graziosi, P.; Bergenti, I.; Dediu, A. [CNR – ISMN, Consiglio Nazionale delle Ricerche – Istituto per lo Studio dei Materiali Nanostrutturati, v. Gobetti 101, 40129 Bologna (Italy); Prezioso, M. [Department of Electrical and Computer Engineering, Harold Frank Hall, University of California, Santa Barbara, California 93106 (United States); Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-07-15T23:59:59.000Z

    We present a novel method of delivering a low-concentration (<15%) ozone beam to an ultra-high vacuum environment for the purpose of cleaning and dosing experimental samples through oxidation processing. The system described is safe, low-cost, and practical and overcomes the limitations of ozone transport in the molecular flow environment of high or ultrahigh vacuum whilst circumventing the use of pure ozone gas which is potentially highly explosive. The effectiveness of this method in removing surface contamination is demonstrated through comparison of high-temperature annealing of a simple oxide (MgO) in ozone and oxygen environments as monitored using quadrupole mass spectroscopy and Auger electron spectroscopy. Additionally, we demonstrate the potential of ozone for obtaining clean complex oxide surfaces without the need for high-temperature annealing which may significantly alter surface structure.

  14. The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone

    E-Print Network [OSTI]

    Dominici, Francesca

    The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone for Ozone and Risk of Mortality and the Adequacy of Current Ozone Regulations Michelle L. Bell,1 Roger D.432.3817 E-mail: michelle.bell@yale.edu 1 #12;Running Title: Ozone and mortality: exposure

  15. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine 

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01T23:59:59.000Z

    Ozone, a phytotoxic air pollutant, is formed from photochemical reactions of hydrocarbons and nitrogen oxides in the troposphere. Ozone is taken into the plant through the stomata, and quickly broken down into hydroxyl radicals. These hydroxyl...

  16. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    Jan de Leeuw; Shuojun Wang

    2011-01-01T23:59:59.000Z

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  17. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    de Leeuw, Jan; Wang, Shuojun

    2007-01-01T23:59:59.000Z

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  18. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01T23:59:59.000Z

    carbon filters for the control of ozone, sulfur dioxide, andMendell (2008). "Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  19. oZONE Faculty and Staff Enrolling Students

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Enrolling Students Log in to ozone.ou.edu. Click the Advising tab. Please lecture schedule CRN ­ Course Reference Number In oZONE the Registration Add Errors will display one

  20. Improving ozone profile retrieval from spaceborne UV backscatter

    E-Print Network [OSTI]

    Haak, Hein

    Chapter 2 Improving ozone profile retrieval from spaceborne UV backscatter spectrometers using convergence behaviour diagnostics Abstract The Ozone Profile Algorithm (OPERA), developed at KNMI, retrieves the vertical ozone distribution from nadir spectral satellite measurements of back scattered sunlight

  1. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01T23:59:59.000Z

    particles produced by ozone/limonene reactions in indoor airgas-phase reactions of ozone with organic compounds underNazaroff, W.W. , 2008. Ozone levels in passenger cabins of

  2. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  3. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01T23:59:59.000Z

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  4. Y-12 Plant Stratospheric Ozone Protection plan

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The Y-12 Plant staff is required by Lockheed Martin Energy Systems (Energy Systems) (formerly Martin Marietta Energy Systems) standard ESS-EP-129 to develop and implement a Stratospheric Ozone Protection Program which will minimize emissions of ozone-depleting substances to the environment and maximize the use of ozone-safe alternatives in order to comply with Title VI of the 1990 Clean Air Act (CAA) Amendments and the implementing regulations promulgated by the Environmental Protection Agency (EPA). This plan describes the requirements, initiatives, and accomplishments of the Y-12 Plant Stratospheric Ozone Protection Program.

  5. Tropospheric Ozone Pollution and Personal Exposure

    E-Print Network [OSTI]

    Toohey, Darin W.

    ://www.nctcog.org/trans/air/ozone/formation.gif #12;Health Effects · Chest pain, coughing, throat irritation, and congestion · Wheezing and difficulty

  6. The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination

    E-Print Network [OSTI]

    Thompson, Anne

    iii ABSTRACT The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination with other instruments tropospheric ozone residual (TOR) can be derived. In this study, the trajectory

  7. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Energy Savers [EERE]

    DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

  8. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Office of Environmental Management (EM)

    More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

  9. atmospheric ozone increases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    polar vortex and its changes for GHGs increase and ozone depletion and possible feedback of the stratospheric polar vortex to changes in GHGs and ozone, as simulated by...

  10. Tropospheric Ozone ATOC/CHEM 5151

    E-Print Network [OSTI]

    Toohey, Darin W.

    polymers, such as rubber #12;12 Tropospheric ozone distribution · Generally increases with altitude) ( production! #12;18 Ozone production CO + OH CO2 + H loss · Photolysis (1.4 x 1011 cm-2 s-1) · Oxidation of CO (3.5 x 1011 cm-2 s-1) 4. Chemical production

  11. 5, 90039038, 2005 Ozone in Europe

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in the at- mospheric boundary layer, a low total ozone column and a reduced cloud cover, all favouring ozone 2003. In this paper we5 argue that a number of positive feedback effects between the weather conditions as the increased temperature and solar radiation indicate that biogenic emissions in Europe were increased during

  12. Study of air pollution: Effects of ozone on neuropeptide-mediated responses in human subjects. Final report

    SciTech Connect (OSTI)

    Boushey, H.A.

    1991-11-01T23:59:59.000Z

    The study examined the hypothesis that ozone inactivates the enzyme, neutral endopeptidase, responsible for limiting the effects of neuropeptides released from afferent nerve endings. Cough response of capsaicin solution delivered from a nebulizer at 2 min. intervals until two or more coughs were produced. Other endpoints measured included irritative symptoms as rated by the subjects on a nonparametric scale, spirometry, of each concentration of ozone were compared to those of filtered air in a single-blind randomized sequence. The results indicate that a 2 h. exposure to 0.4 ppm of ozone with intermittent light exercise alters the sensitivity of airway nerves that mediate the cough response to inhaled materials. This dose of ozone also caused a change in FEV1. A lower level of ozone, 0.02 ppm, caused a change in neither cough threshold nor FEV1, even when the duration of exposure was extended to three hours. The findings are consistent with the author's hypothesis that ozone may sensitize nerve endings in the airways by inactivating neutral endopeptidase, an enzyme that regulates their activity, but they do not demonstrate that directly examining an effect directly mediated by airway nerves allows detection of effects of ozone at doses below those causing effects detected by standard tests of pulmonary function.

  13. Summertime total ozone variations over middle and polar latitudes

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Summertime total ozone variations over middle and polar latitudes 1234567 89A64BC7DEF72B4 467342 $7D425BE27B725CE9393BE647 #12;Summertime total ozone variations over middle and polar latitudes and summertime ozone over middle and polar latitudes is analyzed using zonally averaged total ozone data. Short

  14. Ozone Depletion 2. O 3 generation and depletion

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion Outline: 1. O 3 , O 2 evolution 2. O 3 generation and depletion 3. Antarctic ozone 2 converted to ozone via: O 2 h#23; ! 2O #3; O #3; +O 2 ! O 3 + heat #15; O 3 absorbs near #21;#1;l #15; Decreasing l increases transmittance Imagine all ozone in atmosphere forming a thin layer

  15. Tropospheric Ozone Satellite Retrievals in the Pacific Northwest

    E-Print Network [OSTI]

    Collins, Gary S.

    Tropospheric Ozone Satellite Retrievals in the Pacific Northwest Jacqueline Costello1, Farren: Tropospheric ozone is difficult to retrieve from satellites because of the abundance of ozone in the stratosphere. Tropospheric ozone has become a significant environmental issue and can be exacerbated by UT

  16. Speeding up Ozone Profile Retrieval using Machine Learning Techniques

    E-Print Network [OSTI]

    Emmerich, Michael

    Speeding up Ozone Profile Retrieval using Machine Learning Techniques L.M. Strijbosch April 25 to the process of ozone profile retrieval, a method for retrieving a global ozone distribution from satellite Machines are selected to replace the forward model, which is the slowest part of ozone profile retrieval

  17. Effects of stratospheretroposphere chemistry coupling on tropospheric ozone

    E-Print Network [OSTI]

    Effects of stratospheretroposphere chemistry coupling on tropospheric ozone Wenshou Tian,1,2 Martyn in both the troposphere and stratosphere. The modeled total column ozone agrees well with Total Ozone Mapping Spectrometer observations. Modeled ozone profiles in the upper troposphere and lower stratosphere

  18. Atmospheric ozone and colors of the Antarctic twilight sky

    E-Print Network [OSTI]

    Lee Jr., Raymond L.

    Atmospheric ozone and colors of the Antarctic twilight sky Raymond L. Lee, Jr.,1, * Wolfgang Meyer absorption at longer wavelengths by ozone's Chappuis bands. Because stratospheric ozone is greatly depleted correlations between ozone concentration and twilight colors. We also used a spectroradiometer at a midlatitude

  19. Exposure to Particulate Matter and Ozone of Outdoor Origin in Singapore

    E-Print Network [OSTI]

    Gall, Elliott T; Chen, Ailu; Chang, Victor; Nazaroff, William W

    2015-01-01T23:59:59.000Z

    ulate matter (PM) or ozone, at concentration increments of ~SL, Samet JM, Dominici F. Ozone and short-term mortality inthe penetration of ambient ozone into residential buildings.

  20. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01T23:59:59.000Z

    of healthy young volunteers to ozone causes cardiovasculareffects of five common ozone-initiated terpene reactiondecay rates, and removal of ozone and their relation to

  1. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    2008. Learning about ozone depletion. Climatic Change 89(1–and Physics of Stratospheric Ozone. San Diego, CA: AcademicPhotochemical behavior of the ozone layer. Report Number

  2. LARGE MULTICONFIGURATION SELF-CONSISTENT-FIELD WAVEFUNCTIONS FOR THE OZONE MOLECULE

    E-Print Network [OSTI]

    Schaefer III., Henry F.

    2013-01-01T23:59:59.000Z

    theory comparable to that employed here for ozone. HoweverB (cyclopentadiyl) > B (ozone) > B (methylene), based onfor the its state of ozone near geometry. Coefficients of

  3. Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.

    E-Print Network [OSTI]

    Destaillats, Hugo

    2012-01-01T23:59:59.000Z

    from Ozone Reaction with HVAC Filters Hugo Destaillats,from Ozone Reaction with HVAC Filters Hugo Destaillatsfrom Ozone Reaction with HVAC Filters Hugo Destaillats

  4. Ozone Climatologies Figure 1: Ozone climatology for control run in kg/m(a), percentage change in

    E-Print Network [OSTI]

    Feigon, Brooke

    Ozone Climatologies (a) (b) (c) Figure 1: Ozone climatology for control run in kg/m³(a), percentage change in ozone for the perturbed runs; tropopause region (b), whole stratosphere (c). Determining the impact of lower stratospheric ozone depletion on Southern Hemisphere climate Sarah P.E. Keeley and Nathan

  5. oZONE Faculty and Staff Exporting and Importing Grades

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Exporting and Importing Grades Exporting/Importing Grades in oZONE The new - Log in to ozone.ou.edu using your OU Net ID (4+4) as you would in any other OU system. Click Importing Grades from a Exported oZONE template If you exported a course template from the oZONE grading

  6. Ozone determination in different copying centers 

    E-Print Network [OSTI]

    Lai, Chen-Fu

    1993-01-01T23:59:59.000Z

    Photocopying machines have been in existence for forty years: however, few people recognize their potential to create a human health hazard by ozone emission. This study was designed to determine the photocopier's emission rate and evaluate tile...

  7. Ozone treatment of biomass to enhance digestibility 

    E-Print Network [OSTI]

    Almendarez, Maria Elena

    2000-01-01T23:59:59.000Z

    is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

  8. Ozone treatment of biomass to enhance digestibility

    E-Print Network [OSTI]

    Almendarez, Maria Elena

    2000-01-01T23:59:59.000Z

    is very resistant to enzymatic degradation. Lignocellulosic materials require pretreatment to enhance their digestibility. The main objective of this research was to further enhance the digestibility of biomass (bagasse) with ozonation as a follow...

  9. Methane production from ozonated pulp mill effluent

    SciTech Connect (OSTI)

    Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

    1980-07-01T23:59:59.000Z

    A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

  10. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. 2005 Diesel Engine Emissions...

  11. LAB DOCUMENTATION MEASUREMENT OF OZONE EMISSION AND PARTICLE REMOVAL

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    PURIFIERS Stephen A. Mang,1 Maggie L. Walser,1 John M. Laux,2 Sergey A. Nizkorodov1* 1. Department............................................................. 12 III. Ozone Emission Rates from More Powerful Ozone Generators

  12. Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong-Hoo Park a

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong Received in revised form 26 May 2010 Accepted 2 June 2010 Keywords: Ozone fluxes Citrus Tropospheric ozone climates. In the summer, orchards in California experience high levels of tropospheric ozone, formed

  13. What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found in the strato-

    E-Print Network [OSTI]

    What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found it represents only a tiny fraction of the atmosphere, ozone is crucial for life on Earth. Ozone--acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. With- out ozone, the Sun

  14. The impact of interannual variability on multidecadal total ozone simulations

    E-Print Network [OSTI]

    Jackman, Charles H.

    to reinforce the chemical ozone depletion caused by the enhanced aerosol loading following the eruption of Mt

  15. Arctic ozone loss and climate sensitivity: Updated threedimensional model study

    E-Print Network [OSTI]

    Feng, Wuhu

    Arctic ozone loss and climate sensitivity: Updated three­dimensional model study Chipperfield winter­spring chemical ozone loss from 1991 2003, its observed correlation with low temperatures. CTM throughout studied. The model reproduces large column winters also captures shape of ozone loss profile

  16. ORIGINAL CONTRIBUTION Ozone and Short-term Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    ORIGINAL CONTRIBUTION Ozone and Short-term Mortality in 95 US Urban Communities, 1987-2000 MichelleD E XPOSURE TO TROPOSPHERIC OZONE is widespread in the United States,1,2 occurring also outside southernCalifornia,whereozone formation was first recognized.3 Short- term exposure to ozone has been

  17. Quantum origin of an anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Quantum origin of an anomalous isotope effect in ozone formation D. Babikov *, B.K. Kendrick, R mechanical calculations of the ðJ ¼ 0Þ energies and lifetimes of the metastable states of ozone on a new effect in the reaction that forms ozone because of their role in the energy transfer mechanism, in which

  18. Relative importance of radical families The "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    · Relative importance of radical families · The "Ozone Hole" · Introduction to heterogeneous chemistry Tuesday, March 8, 2011 #12;Review of important points so far Stratospheric ozone is only produced with these parameters Sir Sydney Chapman nearly got it right. He could account for the formation of the ozone layer

  19. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  20. The Ozone Layer in the 21st Lead Authors

    E-Print Network [OSTI]

    Robock, Alan

    CHAPTER 6 The Ozone Layer in the 21st Century Lead Authors: G.E. Bodeker D.W. Waugh Coauthors: H;#12;CHAPTER 6 THE OZONE LAYER IN THE 21ST CENTURY Contents SCIENTIFIC SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.5 6.2 A FRAMEWORK FOR EVALUATING CHANGES IN OZONE ABUNDANCES

  1. Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer

    E-Print Network [OSTI]

    Oppenheimer, Michael

    Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 ozone depletion has been much studied as a case history in the interaction between environmental science the photochemistry of ozone in order to illustrate how scientific learning has the potential to mislead policy makers

  2. On the statistical modeling of persistence in total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    On the statistical modeling of persistence in total ozone anomalies 1234567 89A64BC7DEF72B4 F9BC4B725CE9393BE647 #12;On the statistical modeling of persistence in total ozone anomalies D. I ozone anomalies on monthly to interannual timescales. Such a model is usually characterized by the Hurst

  3. Ozone Treatments of Fresh Atlantic Cod, Gadus morhua

    E-Print Network [OSTI]

    Ozone Treatments of Fresh Atlantic Cod, Gadus morhua ELINOR M. RAVESI, JOSEPH J. L1CCIARDELLO and LINDA D. RACICOT Introduction The strong oxidizing nature of ozone, known since its discovery in 1840 (1977) cited in a review article numerous reports of the successful use of ozone to I) control microbial

  4. Chemistry climate model simulations of1 spring Antarctic ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Chemistry climate model simulations of1 spring Antarctic ozone 1234567 89A64BC7DEF72B4 19B34EE3293C climate model simulations of spring Antarctic ozone John Austin,1,2 H. Struthers,3 J. Scinocca,4 D. A) and Intergovernmental Panel on Climate Change A1b Scenario. The simulations of the Antarctic ozone hole are compared

  5. Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E for their species effectiveness in reducing ozone concentrations in a simulated indoor environment. Continuously supply system were used to simulate an indoor environment in which ozone concentrations could be measured

  6. oZONE Faculty and Staff Course Overrides

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Course Overrides and the Registration Add Errors They Resolve Departments of the overrides within the registration component of oZONE. We have, however, retained a few instances where some. There is also a link to this document on the Student Training and Instructions page in the oZONE info site

  7. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01T23:59:59.000Z

    and exposed to LSX ambient ozone for two months. Arrows indicate pestained SDS-PAGE molecular weight standards (kD) and Rubisco large subunit. Lane R = pure spinach Rubisco large subunit. Lanes 1 and 2 = control seedlings in the Ozoban study. Lanes 3 and 4... radicals are produced during normal metabolism when oxygen is reduced to water. Grimes et al. (1983) studied the products that form from ozone in cells and found no detectable superoxide radicals, leading them to propose that either ozone or hydroxyl...

  8. Tropospheric column ozone: matching individual profiles from Aura OMI and TES with a chemistry-transport model

    E-Print Network [OSTI]

    Tang, Q.; Prather, M. J

    2012-01-01T23:59:59.000Z

    Science Objectives of the Ozone Monitoring In- strument,G. J. , and Logan, J. A. : Ozone climatolog- ical profilestroposphere ex- change ozone flux related to deep

  9. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01T23:59:59.000Z

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  10. The Effects of Gaseous Ozone and Nitric Acid Deposition on two Crustose Lichen Species From Joshua Tree National Park

    E-Print Network [OSTI]

    Hessom, Elizabeth Curie

    2012-01-01T23:59:59.000Z

    photosynthetic rate responses to ozone in some foliose andof gaseous nitric acid and ozone on lichens. Dissertations &with nitric acid and ozone. Environmental Pollution, In

  11. Could the Earth's surface Ultraviolet irradiance be blamed for the global warming? (II) ----Ozone layer depth reconstruction via HEWV effect

    E-Print Network [OSTI]

    Chen, Jilong; Zheng, Yujun

    2014-01-01T23:59:59.000Z

    It is suggested by Chen {\\it et al.} that the Earth's surface Ultraviolet irradiance ($280-400$ nm) could influence the Earth's surface temperature variation by "Highly Excited Water Vapor" (HEWV) effect. In this manuscript, we reconstruct the developing history of the ozone layer depth variation from 1860 to 2011 based on the HEWV effect. It is shown that the reconstructed ozone layer depth variation correlates with the observational variation from 1958 to 2005 very well ($R=0.8422$, $P>99.9\\%$). From this reconstruction, we may limit the spectra band of the surface Ultraviolet irradiance referred in HEWV effect to Ultraviolet B ($280-320$ nm).

  12. Nuclear conflict and ozone depletion Quick summary

    E-Print Network [OSTI]

    Toohey, Darin W.

    Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

  13. Policy Response to Stratospheric Ozone Loss

    E-Print Network [OSTI]

    Toohey, Darin W.

    #12;12 In terms of human impact #12;13 How do we know what to regulate? · Need a metric for assessing on stratospheric ozone ­ Some significant global warming potential (GWP) ­ Concern about breakdown products ­ trifluoroacetyl halides (TFAs) #12;20 Global Warming Potentials Compound Estimated Atmospheric (at time horizons

  14. Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution

    E-Print Network [OSTI]

    Thompson, Anne

    Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution Anne M activities lead to intense smoke haze and ozone formation. The first ozone soundings in the heart surface ozone was over 90 ppbv and column tropospheric ozone exceeded 50 DU. These values are higher than

  15. Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy

    E-Print Network [OSTI]

    Brown, Matthew A.

    2008-01-01T23:59:59.000Z

    J. C. , Reactivity of ozone on solid potassium iodide.and mechanisms of aqueous ozone reactions with bromide,for Dry Deposition of Ozone to Seawater Surfaces. Journal of

  16. OZONE INDUCED CONDUCTANCE INCREASES ASSAYED WITH LIPID IMPREGNATED FILTER MEMBRANES-EFFECT OF VITAMIN E

    E-Print Network [OSTI]

    Sheih, P.K

    2011-01-01T23:59:59.000Z

    29-44. R. L. Heath (1975) Ozone, in Response of Plants toSince it is possible that ozone absorption "is incompleteof the filter. After the ozone treatment was stopped the

  17. Application of gaseous disinfectants ozone and chlorine dioxide for inactivation of Bacillus subtilis spores

    E-Print Network [OSTI]

    Aydogan, Ahmet

    2006-01-01T23:59:59.000Z

    inhibitor line Ozone Generator Oxygen Concentrator CellSequal oxygen concentrator and Pure-O-Tech ozone generator.This oxygen is then supplied into the ozone generator for

  18. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    SciTech Connect (OSTI)

    Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

    2009-09-01T23:59:59.000Z

    This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

  19. The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters 

    E-Print Network [OSTI]

    Buys, Ronald Earl

    1980-01-01T23:59:59.000Z

    as solids retention time increased. COD concentration decreased after ozonation and its percent removal increased with a lengthening of the solids retention time, Ozone consumption decreased and the ratio of COD reduction to ozone consumed increased..., with and without ozonation. . . . . . . . . . . . . 22 Effect of solids retention time on COD removal. Effect of solids retention time on ozone concentration consumed. 27 Effect of solids retention time on the ratio of COD reduction to ozone consumed. 28...

  20. Ozone treatment in a closed culture system for Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Yamaguchi, Ryoji

    1978-01-01T23:59:59.000Z

    removed from test aquaria, OTN reagent was added and color development was measured spectrophotometrically. Air mixed with ozone gas was injected into test solutions by diffuser (aquarium air stone) under specified conditions of temperature (28 C... of its high reactivity, ozone has been used for treating water to remove dissolved organic and inorganic wastes (Torricelli, 1959; Diaper, 1972) . The effectiveness of ozonation has been discussed by Dickerman et al. (1954), Fetner and Ingols (1959...

  1. airborne antarctic ozone: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  2. antarctic ozone recovery: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  3. antarctic ozone hole: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  4. antarctic ozone experiment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  5. antarctic ozone depletion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    winter weather conditions: Severe cold and isolated air ow: circumpolar vortex North pole vortex breakdown replenishes ozone layer from outside: mixes air 12; E11;ects...

  6. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01T23:59:59.000Z

    An evaluation of different scrubber materials. Environmentalrun periodically. Inline ozone scrubbers were used for VOCwith a commercial, KI-filled scrubber (P/N WAT054420; Waters

  7. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01T23:59:59.000Z

    from the material balance on ozone (equation 4-1). S [O 3 ](equation 5-2, which reflects a steady-state material balance

  8. E-Print Network 3.0 - ambient ozone growth Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate and Environment (Climate) Impacts of ozone on trees and crops Summary: and carbon sequestration. Vegetation exposure to ozone reduces photosynthesis, growth, and...

  9. Application of gaseous disinfectants ozone and chlorine dioxide for inactivation of Bacillus subtilis spores

    E-Print Network [OSTI]

    Aydogan, Ahmet

    2006-01-01T23:59:59.000Z

    of gaseous ozone for MRSA decontamination of hospital side-H. ; Kamiki, T. , “Ozone decontamination of bioclean rooms”,Nelson, P.E. , “Decontamination of bacillus thuringiensis

  10. Herbivores and nutrients control grassland plant diversity via light limitation.

    SciTech Connect (OSTI)

    Borer, Elizabeth T. [Department of Ecology, Evolution, and Behavior, University of Minnesota; et al, et al

    2014-01-01T23:59:59.000Z

    Human alterations to nutrient cycles1,2 and herbivore communities3–7 are affecting global biodiversity dramatically2. Ecological theory predicts these changes should be strongly counteractive: nutrient addition drives plant species loss through intensified competition for light, whereas herbivores prevent competitive exclusion by increasing ground-level light, particularly in productive systems8,9. Here we use experimental data spanning a globally relevant range of conditions to test the hypothesis that herbaceous plant species losses caused by eutrophication may be offset by increased light availability due to herbivory. This experiment, replicated in 40 grasslands on 6 continents, demonstrates that nutrients and herbivores can serve as counteracting forces to control local plant diversity through light limitation, independent of site productivity, soil nitrogen, herbivore type and climate. Nutrient addition consistently reduced local diversity through light limitation, and herbivory rescued diversity at sites where it alleviated light limitation. Thus, species loss from anthropogenic eutrophication can be ameliorated in grasslands where herbivory increases ground-level light.

  11. URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA

    E-Print Network [OSTI]

    Boyer, Edmond

    Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

  12. Validation of satellite ozone profile retrievals using Beijing ozonesonde data

    E-Print Network [OSTI]

    Pan, Laura

    year time period (September 2002 to July 2005) are used to evaluate the performance of ozone profile, the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua satellite and the Microwave Limb Sounder (MLS) on the NASA Aura satellite. Since the Global Positioning System ozone sensors (GPSO3) used in Beijing

  13. Atmospheric Environment 41 (2007) 31513160 Ozone removal by HVAC filters

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Atmospheric Environment 41 (2007) 3151­3160 Ozone removal by HVAC filters P. Zhao, J.A. Siegel�, R May 2006; accepted 14 June 2006 Abstract Residential and commercial HVAC filters that have been loaded of the relative importance of HVAC filters as a removal mechanism for ozone in residential and commercial

  14. Proceedings: Indoor Air 2005 OZONE REMOVAL BY RESIDENTIAL HVAC FILTERS

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Proceedings: Indoor Air 2005 2366 OZONE REMOVAL BY RESIDENTIAL HVAC FILTERS P Zhao1,2 , JA Siegel1, Austin, Texas 78758, USA ABSTRACT HVAC filters have a significant influence on indoor air quality% for Filter #2 at a face velocity of 0.81 cm/s. The potential for HVAC filters to affect ozone concentrations

  15. Reactive uptake of ozone at simulated leaf surfaces: implications for "non-stomatal" ozone flux 

    E-Print Network [OSTI]

    Cape, J Neil; Hamilton, Richard P; Heal, Mathew R

    2009-01-01T23:59:59.000Z

    The reaction of ozone (O3) with ?-pinene has been studied as a function of temperature and relative humidity and in the presence of wax surfaces that simulate a leaf surface. The objective was to determine whether the presence of a wax surface...

  16. An ozone climatology of the Dallas-Fort Worth area and its relationship to meteorology

    E-Print Network [OSTI]

    Nobis, Timothy Edward

    1998-01-01T23:59:59.000Z

    , no extensive studies on ozone in this area have been published. This study presents a broad overview of the ozone problem in the DFW area. An ozone spatial and temporal climatology was constructed using ozone data at 23 different monitoring sites from 1980...

  17. Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Aakash C. Rai1

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Dynamics2 3 10 Ozone is a major pollutant of indoor air. Many studies have demonstrated the adverse health effect of11 ozone and the byproducts generated as a result of ozone-initiated reactive chemistry

  18. Improving total column ozone retrievals by using cloud pressures derived from Raman scattering in the UV

    E-Print Network [OSTI]

    Joiner, Joanna

    Improving total column ozone retrievals by using cloud pressures derived from Raman scattering resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals. By default, the TOMS

  19. An intramolecular theory of the mass-independent isotope effect for ozone. I.

    E-Print Network [OSTI]

    Hathorn, Bryan C.

    An intramolecular theory of the mass-independent isotope effect for ozone. I. B. C. Hathorn and R-independent isotope effect for ozone formation and dissociation is described. The experiments include the enrichment and asymmetric ozone isotopomers, the enrichment of ozone formed from heavily enriched oxygen isotopes

  20. Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1

    E-Print Network [OSTI]

    Son, Seok-Woo

    Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1 Neil F. Tandon,2 Lorenzo M cooling resulting from ozone depletion has only recently been examined and a comprehensive picture on the stratospheric ozone forcing used, we here show that stratospheric ozone affects the entire atmospheric

  1. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 VOCsVOCs,, PAHsPAHs, soot, tar, CO, soot, tar, CO

    E-Print Network [OSTI]

    Zevenhoven, Ron

    of tar (from biomass gasificationbiomass gasification)) ·· COCO see: www.hut.fi/~see: www-level ozone in Europeand ground-level ozone in Europe VOC emissions (VOC emissions (inclincl. methane). methane) in Europe, 1994 (tonnes)in Europe, 1994 (tonnes) Ground-level ozone in Europe,Ground-level ozone

  2. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01T23:59:59.000Z

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  3. Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects

    E-Print Network [OSTI]

    Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects on photosynthesis to a complex canopy architecture§ M.J. Martina, *, G.E. Hosta; accepted 17 July 2001 ``Capsule'': A process model is described that predicts the relative effects of ozone

  4. Global Health and Economic Impacts of Future Ozone Pollution

    E-Print Network [OSTI]

    Webster, Mort D.

    We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the ...

  5. air pollutants ozone: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E ndoor air pollution is ranked as one of the world's greatest public health risks (Wolverton,...

  6. Process-scale modeling of elevated wintertime ozone in Wyoming.

    SciTech Connect (OSTI)

    Kotamarthi, V. R.; Holdridge, D. J.; Environmental Science Division

    2007-12-31T23:59:59.000Z

    Measurements of meteorological variables and trace gas concentrations, provided by the Wyoming Department of Environmental Quality for Daniel, Jonah, and Boulder Counties in the state of Wyoming, were analyzed for this project. The data indicate that highest ozone concentrations were observed at temperatures of -10 C to 0 C, at low wind speeds of about 5 mph. The median values for nitrogen oxides (NOx) during these episodes ranged between 10 ppbv and 20 ppbv (parts per billion by volume). Measurements of volatile organic compounds (VOCs) during these periods were insufficient for quantitative analysis. The few available VOCs measurements indicated unusually high levels of alkanes and aromatics and low levels of alkenes. In addition, the column ozone concentration during one of the high-ozone episodes was low, on the order of 250 DU (Dobson unit) as compared to a normal column ozone concentration of approximately 300-325 DU during spring for this region. Analysis of this observation was outside the scope of this project. The data analysis reported here was used to establish criteria for making a large number of sensitivity calculations through use of a box photochemical model. Two different VOCs lumping schemes, RACM and SAPRC-98, were used for the calculations. Calculations based on this data analysis indicated that the ozone mixing ratios are sensitive to (a) surface albedo, (b) column ozone, (c) NOx mixing ratios, and (d) available terminal olefins. The RACM model showed a large response to an increase in lumped species containing propane that was not reproduced by the SAPRC scheme, which models propane as a nearly independent species. The rest of the VOCs produced similar changes in ozone in both schemes. In general, if one assumes that measured VOCs are fairly representative of the conditions at these locations, sufficient precursors might be available to produce ozone in the range of 60-80 ppbv under the conditions modeled.

  7. Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause-Based Climatology and Optimal Estimation Approach

    E-Print Network [OSTI]

    Pan, Laura

    Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause for retrieving atmospheric ozone profile information from advanced satellite infrared sounders, this study investigates various methods to optimize ozone retrievals. A set of retrieval experiments has been performed

  8. Experimental investigation of factors limiting slow axis beam quality in 9xx nm high power broad area diode lasers

    SciTech Connect (OSTI)

    Winterfeldt, M., E-mail: martin.winterfeldt@fbh-berlin.de; Crump, P.; Wenzel, H.; Erbert, G.; Tränkle, G. [Ferdinand-Braun-Institut, Leibniz-Institut für Höchstfrequenztechnik, Gustav-Kirchhoff-Str. 4, 12489 Berlin (Germany)

    2014-08-14T23:59:59.000Z

    GaAs-based broad-area diode lasers are needed with improved lateral beam parameter product (BPP{sub lat}) at high power. An experimental study of the factors limiting BPP{sub lat} is therefore presented, using extreme double-asymmetric (EDAS) vertical structures emitting at 910?nm. Continuous wave, pulsed and polarization-resolved measurements are presented and compared to thermal simulation. The importance of thermal and packaging-induced effects is determined by comparing junction -up and -down devices. Process factors are clarified by comparing diodes with and without index-guiding trenches. We show that in all cases studied, BPP{sub lat} is limited by a non-thermal BPP ground-level and a thermal BPP, which depends linearly on self-heating. Measurements as a function of pulse width confirm that self-heating rather than bias-level dominates. Diodes without trenches show low BPP ground-level, and a thermal BPP which depends strongly on mounting, due to changes in the temperature profile. The additional lateral guiding in diodes with trenches strongly increases the BPP ground-level, but optically isolates the stripe from the device edges, suppressing the influence of the thermal profile, leading to a BPP-slope that is low and independent of mounting. Trenches are also shown to initiate strain fields that cause parasitic TM-polarized emission with large BPP{sub lat}, whose influence on total BPP{sub lat} remains small, provided the overall polarization purity is >95%.

  9. Royal Swedish Academy of Sciences 2005 http://www.ambio.kva.se

    E-Print Network [OSTI]

    the environment from acidification and eutrophication and to reduce exposures to ground-level ozone. However) described the effects of shipping emissions on acidification, eutrophication, and ground-level ozone

  10. Observations of the Temperature Dependent Response of Ozone to NOx Reductions in an Urban Plume

    SciTech Connect (OSTI)

    LaFranchi, B W; Goldstein, A H; Cohen, R C

    2011-01-25T23:59:59.000Z

    Observations of NO{sub x} in the Sacramento, CA region show that mixing ratios decreased by 30% between 2001 and 2008. Here we use an observation-based method to quantify net ozone production rates in the outflow from the Sacramento metropolitan region and examine the O{sub 3} decrease resulting from reductions in NO{sub x} emissions. This observational method does not rely on assumptions about detailed chemistry of ozone production, rather it is an independent means to verify and test these assumptions. We use an instantaneous steady-state model as well as a detailed 1-D plume model to aid in interpretation of the ozone production inferred from observations. In agreement with the models, the observations show that early in the plume, the NO{sub x} dependence for O{sub x} (O{sub x} = O{sub 3}+NO{sub 2}) production is strongly coupled with temperature, suggesting that temperature dependent biogenic VOC emissions can drive O{sub x} production between NO{sub x}-limited and NO{sub x}-suppressed regimes. As a result, NO{sub x} reductions were found to be most effective at higher temperatures over the 7 year period. We show that violations of the California 1-hour O{sub 3} standard (90 ppb) in the region have been decreasing linearly with decreases in NO{sub x} (at a given temperature) and predict that reductions of NO{sub x} concentrations (and presumably emissions) by an additional 30% (relative to 2007 levels) will eliminate violations of the state 1 hour standard in the region. If current trends continue, a 30% decrease in NO{sub x} is expected by 2012, and an end to violations of the 1 hour standard in the Sacramento region appears to be imminent.

  11. Past changes in the vertical distribution of ozone – Part 3: Analysis and interpretation of trends

    E-Print Network [OSTI]

    Harris, N. R. P.; Hassler, B.; Tummon, F.; Bodeker, G. E.; Hubert, D.; Petropavlovskikh, I.; Steinbrecht, W.; Anderson, J.; Bhartia, P. K.; Boone, C. D.; Bourassa, A.; Davis, S. M.; Degenstein, D.; Delcloo, A.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Jones, N.; Kurylo, M. J.; Kyrölä, E.; Laine, M.; Leblanc, S. T.; Lambert, J.-C.; Liley, B.; Mahieu, E.; Maycock, A.; de Mazière, M.; Parrish, A.; Querel, R.; Rosenlof, K. H.; Roth, C.; Sioris, C.; Staehelin, J.; Stolarski, R. S.; Stübi, R.; Tamminen, J.; Vigouroux, C.; Walker, K.; Wang, H. J.; Wild, J.; Zawodny, J. M.

    2015-03-23T23:59:59.000Z

    Trends in the vertical distribution of ozone are reported and compared for a number of new and recently revised datasets. The amount of ozone-depleting compounds in the stratosphere (as measured by Equivalent Effective Stratospheric Chlorine – EESC...

  12. A delayed effect of ozone fumigation on photosynthesis of Norway spruce

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    A delayed effect of ozone fumigation on photosynthesis of Norway spruce D. Eamus1 A.W. Davis J into the long-lastincl effects of ozone fumiga- tion upon photosynthesis of Norway spruce. Measurements were

  13. E-Print Network 3.0 - acid regulates ozone-induced Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ozone-induced Search Powered by Explorit Topic List Advanced Search Sample search results for: acid regulates ozone-induced Page: << < 1 2 3 4 5 > >> 1 Plant Molecular Biology 51:...

  14. Comparison of three vertically resolved ozone data sets: climatology, trends and radiative forcings

    E-Print Network [OSTI]

    Hassler, B.

    Climate models that do not simulate changes in stratospheric ozone concentrations require the prescription of ozone fields to accurately calculate UV fluxes and stratospheric heating rates. In this study, three different ...

  15. Gille-ESYS 10 1 Is I had a billion dollars to save the ozone layer ....

    E-Print Network [OSTI]

    Gille, Sarah T.

    Gille-ESYS 10 1 Is I had a billion dollars to save the ozone layer .... The scene: A backyard-destroying metered dose inhalers? If I had a billion dollars to save the ozone layer, I'd spend it all to get rid to save the ozone layer, I'd worry more about methyl bromide, which is not only an ozone destroyer

  16. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F. [Russian Academy of Sciences, Kemerovo (Russian Federation)

    2007-05-15T23:59:59.000Z

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  17. Meteorological Simulations of Ozone Episode Case Days during the 1996 Paso del Norte Ozone Study

    SciTech Connect (OSTI)

    Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

    1999-02-01T23:59:59.000Z

    Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13,1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were petiormed using the HOTMAC mesoscale meteorological model using a 1,2,4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11-13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawirisonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. We found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

  18. Meteorological simulations of ozone episode case days during the 1996 Paso del Norte ozone study

    SciTech Connect (OSTI)

    Brown, M.J.; Costigan, K.; Muller, C.; Wang, G.

    1999-07-01T23:59:59.000Z

    Meteorological simulations centered around the border cities of El Paso and Ciudad Juarez have been performed during an ozone episode that occurred on Aug. 13, 1996 during the 1996 Paso del Norte Ozone Study field campaign. Simulations were performed using the HOTMAC mesoscale meteorological model using a 1, 2, 4, and 8 km horizontal grid size nested mesh system. Investigation of the vertical structure and evolution of the atmospheric boundary layer for the Aug. 11--13 time period is emphasized in this paper. Comparison of model-produced wind speed profiles to rawinsonde and radar profiler measurements shows reasonable agreement. A persistent upper-level jet was captured in the model simulations through data assimilation. In the evening hours, the model was not able to produce the strong wind direction shear seen in the radar wind profiles. Based on virtual potential temperature profile comparisons, the model appears to correctly simulate the daytime growth of the convective mixed layer. However, the model underestimates the cooling of the surface layer at night. The authors found that the upper-level jet significantly impacted the turbulence structure of the boundary layer, leading to relatively high turbulent kinetic energy (tke) values aloft at night. The model indicates that these high tke values aloft enhance the mid-morning growth of the boundary layer. No upper-level turbulence measurements were available to verify this finding, however. Radar profiler-derived mixing heights do indicate relatively rapid morning growth of the mixed layer.

  19. Development of an ozone climatology for Harris County, Texas

    SciTech Connect (OSTI)

    Balentine, H.W.; Carter, J.C. (Radian Corp., Austin, TX (USA)); Preston, J. (Tenneco Polymers, Houston, TX (US))

    1987-01-01T23:59:59.000Z

    The Houston Regional Monitoring Corporation (HRM) has performed continuous ambient air quality and meteorological monitoring in the Ship Channel area of east Harris County since August 1981. The HRM monitoring network is one of the largest Environmental Protection Agency (EPA) approved Prevention of Significant Deterioration (PSD) monitoring network in the United States operated by an industrial group. As an adjunct to its monitoring. HRM has funded extensive meteorological and statistical analyses of ozone monitoring data in Harris County. One of the goals of these studies was to determine those meteorological conditions responsible for the formation of elevated ozone concentrations in Harris County. The analyses performed included the use of principal component analysis and cluster analysis. These analysis techniques have individually been applied to ozone and air quality research problems. The combined use of these techniques in this analysis, however, is a unique application of these statistical tools to an ozone air quality analysis. As a result of these analyses, a climatology of those episodes conducive to elevated ozone formation in Harris County was developed.

  20. Comparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane

    E-Print Network [OSTI]

    Jacobson, Mark

    Comparison of model estimates of the effects of aviation emissions on atmospheric ozone and methane is the effects of aviation emissions on ozone and atmospheric chemistry. In this study the effects of aviation emissions on atmospheric ozone for 2006 and two projections for 2050 are compared among seven models

  1. Efficient quantum-classical method for computing thermal rate constant of recombination: Application to ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    : Application to ozone formation Mikhail V. Ivanov and Dmitri Babikov Citation: J. Chem. Phys. 136, 184304 (2012 for computing thermal rate constant of recombination: Application to ozone formation Mikhail V. Ivanov of ozone. Comparison of the predicted rate vs. experimental result is presented. © 2012 American Institute

  2. Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun

    E-Print Network [OSTI]

    Folkins, Ian

    Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun Department] The climatological ozone profile in the tropics is shaped like an ``S,'' with a minimum at the surface, a maximum. These features can be reproduced by a very simple model whose only free parameter is the mean ozone mixing ratio

  3. Ozone database in support of CMIP5 simulations: results and corresponding

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing 1234567 Attribution 3.0 License. Atmospheric Chemistry and Physics Ozone database in support of CMIP5 simulations 2011 Abstract. A continuous tropospheric and stratospheric ver- tically resolved ozone time series

  4. A review of statistical methods for the meteorological adjustment of tropospheric ozone

    E-Print Network [OSTI]

    Washington at Seattle, University of

    A review of statistical methods for the meteorological adjustment of tropospheric ozone Mary Lou adjustment of tropospheric ozone Mary Lou Thompson1 Joel Reynolds1 Lawrence H. Cox2 Peter Guttorp1 Paul D.larry@epamail.epa.gov ABSTRACT: A variety of statistical methods for meteorological adjustment of ozone have been proposed

  5. Effects of ozone cooling in the tropical lower stratosphere and upper troposphere

    E-Print Network [OSTI]

    Effects of ozone cooling in the tropical lower stratosphere and upper troposphere Piers M. Forster lower stratosphere and upper troposphere and elucidate the key role of ozone changes in driving of tropical ozone decreases at 70 hPa and lower pressures can lead to significant cooling not only

  6. THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING BAYESIAN MODELS

    E-Print Network [OSTI]

    West, Mike

    THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING University. The authors thank Alex Guenther for supplying the high frequency ozone concentration measurements a multiscale Bayesian model for separating ozone (O 3 ) concentration turbulent fluctuations from such inherent

  7. Ensemble-based air quality forecasts: A multimodel approach applied to ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1 21 September 2006. [1] The potential of ensemble techniques to improve ozone forecasts ozone-monitoring networks. We found that several linear combinations of models have the potential

  8. Conditional quantiles when the covariates are curves : an application to Ozone pollution

    E-Print Network [OSTI]

    Bercu, Bernard

    Conditional quantiles when the covariates are curves : an application to Ozone pollution forecasting Summary This work deals with the study of pollution data with the aim of forecas- ting the Ozone of the maximum of Ozone one day kno- wing one or several of these functional variables the day before. To do this

  9. Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a)

    E-Print Network [OSTI]

    Reid, Scott A.

    Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a) Brian K for an anomalous isotope effect in ozone formation is given in terms of the energy transfer mechanism, where the metastable states of ozone are formed first, and then stabilized by collisions with other atoms. Unusual

  10. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean 

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31T23:59:59.000Z

    Despite the known reactivity of ozone (O_(3)) in water and ozone’s environmental importance in the atmosphere, there are relatively few studies published examining the chemistry of O_(3) in seawater. This study focused on developing a flow injection...

  11. Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air Purifiers

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air ozone (O3) during operation, either in- tentionally or as a byproduct of air ionization standards. Sev- eral types of air purifiers were tested for their ability to produce ozone in various indoor

  12. Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone treatment

    E-Print Network [OSTI]

    Parikh, Atul N.

    Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone (structure code: MFI) following a previously published procedure. The films were illuminated using an ozone. Results presented here indicate that the UV/ozone treatment under nominally room temperature conditions

  13. EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH

    E-Print Network [OSTI]

    McKendry, Ian

    EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH, hourly average ozone concentrations were mea- sured at three sites of differing elevation (188, 588. Sites experienced ozone concentrations ranging from 0 to 88 ppb in 2001, and 0 to 96 ppb in 2002. Daily

  14. Seasonal persistence of northern low-and middle-latitude anomalies of ozone and

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases #12;Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases 10 July 2008; accepted 23 July 2008; published 11 November 2008. [1] Analysis of observed ozone

  15. Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend

    E-Print Network [OSTI]

    Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend W. J. Collins, R of circulation changes in a changed climate on the exchange of ozone between the stratosphere and the troposphere. We have identified an increase in the net transport of ozone into the troposphere in the future

  16. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. , NO. , PAGES 1?? , Analysis of 19701995 Trends in Tropospheric Ozone at

    E-Print Network [OSTI]

    Jacob, Daniel J.

    in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS­CHEM Model Andrew C. Fusco Department. The causes of trends in tropospheric ozone at Northern Hemisphere mid­ latitudes from 1970 to 1995 to investigate the sensitivity of tropospheric ozone with respect to (1) changes in the anthropogenic emission

  17. The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation

    E-Print Network [OSTI]

    Waugh, Darryn W.

    The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation Luke D impact on tropospheric circulation causes significant changes to the distribution of ozone. Here we derive the lower tropospheric to lower stratospheric ozone response to ENSO from observations

  18. Semiclassical molecular dynamics simulations of ultrafast photodissociation dynamics associated with the Chappuis band of ozone

    E-Print Network [OSTI]

    Miller, William H.

    with the Chappuis band of ozone Victor S. Batista and William H. Millera) Department of Chemistry, University A ) of ozone following photoexcitation of the molecule in the gas phase with visible light. Our algorithm and recurrence events, as well as an interpretation of experimental studies of the Chappuis band of ozone

  19. Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery 1234567 89A64BC7DEF72B4BE647 #12;Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery J. F. Scinocca,1. [1] We investigate the sensitivity of Northern Hemisphere polar ozone recovery to a scenario in which

  20. PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on

    E-Print Network [OSTI]

    PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone. Kelly*1 The corrosion of Ag in an atmosphere of ozone and humidity with or without irradiation corrosion product to chloride in the reduction solution. The presence of both ozone and UV radiation

  1. How Bromate and Ozone Concentrations can be Modelled at Full Scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 How Bromate and Ozone Concentrations can be Modelled at Full Scale based on Lab-Scale Experiments ­ A Case Study Running head title How to model bromate & ozone at full scale based on lab tests Pierre-scale modelling study of an industrial ozonation unit for practical application. The modelling framework combines

  2. A global picture of the seasonal persistence of stratospheric ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    A global picture of the seasonal persistence of stratospheric ozone anomalies 1234567 89A64BC7DEF72 ozone anomalies S. Tegtmeier,1,2 V. E. Fioletov,1 and T. G. Shepherd3 Received 13 August 2009; revised in vertical profiles of stratospheric ozone, in both equatorial and extratropical regions, have been shown

  3. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  4. Analytica Chimica Acta 573574 (2006) 913 Metal oxide thin films as sensing layers for ozone detection

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Analytica Chimica Acta 573­574 (2006) 9­13 Metal oxide thin films as sensing layers for ozone. Their structural, electrical and ozone sensing properties were analyzed. Structural investigations carried out with ultraviolet light and subsequent oxidation in ozone atmosphere at room temperature. © 2006 Elsevier B.V. All

  5. Technical note Barriers and opportunities for passive removal of indoor ozone

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Technical note Barriers and opportunities for passive removal of indoor ozone Elliott T. Gall presents a Monte Carlo simulation to assess passive removal materials (PRMs) that remove ozone of homes in Houston, Texas, were taken from the literature and combined with back- ground ozone removal

  6. Evaluating Ozone Air Pollution Effects on Pines in the Western United States

    E-Print Network [OSTI]

    Standiford, Richard B.

    Evaluating Ozone Air Pollution Effects on Pines in the Western United States United States. Evaluating ozone air pollution effects on pines in the western United States. Gen. Tech. Rep. PSW­GTR­155. Historical and technical background is provided about ozone air pollution effects on ponderosa (Pinus

  7. Semiclassical wave packet study of anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Semiclassical wave packet study of anomalous isotope effect in ozone formation Evgeny Vetoshkin represent the metastable O3 * species and play a central role in the process of ozone formation.1063/1.2778432 I. INTRODUCTION Ozone O3 is formed in the stratosphere as a product of the following recombination

  8. Impact of long-range correlations on trend detection in total ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of long-range correlations on trend detection in total ozone 1234567 89A64BC7DEF72B4 F9BC4B725CE9393BE647 #12;Impact of long-range correlations on trend detection in total ozone Dmitry I; accepted 28 March 2007; published 24 July 2007. [1] Total ozone trends are typically studied using linear

  9. Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY

    E-Print Network [OSTI]

    Steinhoff, Heinz-Jürgen

    Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY G; revised 4 May 2005; accepted 13 May 2005; published 20 August 2005. [1] We use atmospheric ozone density profiles between 35 and 65 km altitude derived from SCIAMACHY limb measurements to quantify the ozone

  10. The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest

    E-Print Network [OSTI]

    Collins, Gary S.

    The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest also acts as an antioxidant within a plant, reacting and neutralizing ozone and peroxides, though , and reacts photochemically in the presence of NOx to produce tropospheric ozone. The Model of Emissions

  11. Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone

    E-Print Network [OSTI]

    Barthelat, Francois

    Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated) to investigate the sludge reduction potential of partially ozonating sludge return activated sludge (RAS

  12. Growth and crown architecture of two aspen genotypes exposed to interacting ozone and carbon dioxide

    E-Print Network [OSTI]

    Growth and crown architecture of two aspen genotypes exposed to interacting ozone and carbon To study the impact of ozone (O3) and O3 plus CO2 on aspen growth, we planted two trembling aspen clones growth and modified crown architecture of both aspen clones. Ozone exposure decreased leaf, stem, branch

  13. 1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.

    E-Print Network [OSTI]

    Crambes, Christophe

    Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

  14. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Gordon, C.J.; Jarema, K.A.; MacPhail, R.C. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Cascio, W.E. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Phillips, P.M. [Toxicity Assessment Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Ledbetter, A.D.; Schladweiler, M.C. [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Andrews, D. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Miller, D. [Curriculum in Toxicology, University of North Carolina, Chapel Hill, NC (United States); Doerfler, D.L. [Research Cores Unit, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Kodavanti, U.P., E-mail: kodavanti.urmila@epa.gov [Environmental Public Health Division, National Health and Environmental Effects Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

    2013-12-15T23:59:59.000Z

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  15. Ozone treatment in a closed culture system for Macrobrachium rosenbergii

    E-Print Network [OSTI]

    Yamaguchi, Ryoji

    1978-01-01T23:59:59.000Z

    media was brought to 3. 0 ppt with "Instant Ocean" salt and pH was adjusted with either sodium hydroxide or sulfuric acid. 2. The accumulation of residual ozone was investigated in the tap water-based culture medium alone and with 12 ppm total ammonia..., turbidity and other organic substances was very effective, but no significant reduction in ammonia nitrogen content wss achieved, unless an oyster shell filter was introduced in the media. fea lty f tf 1 * 9 11 9 b*Mt ~btt demonstrated. Ozone...

  16. Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great by symptoms of foliar ozone injury. Abstract The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts

  17. Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a,*, Daniel J. Jacob a,b

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a Accepted 23 May 2011 Keywords: Air quality Ozone Kalman filter Assimilation Remote sensing a b s t r a c satellite measurements of ozone in different spectral regions to constrain surface ozone concentrations

  18. Sea Breeze characteristics during a high ozone event over Houston

    E-Print Network [OSTI]

    Naumann, Stephanie Alaine

    2001-01-01T23:59:59.000Z

    During August 29 through September 2, 2000, high surface ozone levels were observed over Houston, Texas. Observational and MM5 model data were used to evaluate the land/sea breeze event that occurred each day. The model did well in accurately...

  19. Original article Effects of tropospheric ozone on white clover plants

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Effects of tropospheric ozone on white clover plants exposed in open-top chambers concentration in a large part of Europe is high enough to cause visible injury to sensitive plants and several site are evaluated using white clover plants. Plants were exposed to the air and sprayed with water

  20. Comment on "Tropospheric temperature response to stratospheric ozone recovery in

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    to stratospheric ozone recovery, it is necessary to run coupled atmosphere-ocean climate models with stratospheric-of-the-art chemistry-climate model cou- pled to a three-dimensional ocean model. In contrast to Hu et al., we find is uncertain due to the large compensation between the short- wave warming due to increased penetration

  1. Massive global ozone loss predicted following regional nuclear conflict

    E-Print Network [OSTI]

    than previous ``nuclear winter/UV spring'' calculations, which did not adequately represent depletion. black carbon geoengineering nuclear winter stratospheric ozone atmospheric chemistry In the early that came to be known as ``nuclear winter'' (1­4)] prompted intense public debate about previous assumptions

  2. Dispersion modeling of ground-level area sources of particulate

    E-Print Network [OSTI]

    Fritz, Bradley Keith

    1998-01-01T23:59:59.000Z

    , as shown by Equation 3. f(z) = exp ?, + exp? Y This curve represents the distribution of pollutant in the y-z plane. At any point y, a fraction of the total area of the curve [1] is determined The width of the curve depends on o?, a dispersion... the terminal settling velocity. Equation 6 and 7 are used. C p p dp g 18' where: t-o. ss, 'I C = 1+ ? 2. 514+ 0. 8e d (Eq. 6) (Eq 7) V, = Terminal Settling Velocity [m/s] C = Cunningham's Correction Factor [1/1] p, = density; 1500 [kg/m'] ) = gas...

  3. P ORNiiTM-7004 Results of Ground Level Radiation

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTuba City, Arizona, DisposalFourthN V O 1 8 7 +NewAugust 4,P -.,. ~ * *

  4. Process Limits on Euclid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Process Limits Process Limits Limit Hard Soft core file size (blocks) 0 unlimited data seg size (kbytes) unlimited unlimited scheduling priority 0 0 file size (blocks) unlimited...

  5. Sum frequency generation and catalytic reaction studies of the removal of the organic capping agents from Pt nanoparticles by UV-ozone treatment

    E-Print Network [OSTI]

    Aliaga, Cesar

    2010-01-01T23:59:59.000Z

    and (b) after 2 hours of UV/ozone treatment. (a) 50nm (b)a) before and (b) after UV/ozone treatment for 270 minutes.from Pt nanoparticles by UV-ozone treatment Cesar Aliaga, †

  6. FORMATION OF MOLECULAR OXYGEN AND OZONE ON AMORPHOUS SILICATES

    SciTech Connect (OSTI)

    Jing Dapeng; He Jiao; Vidali, Gianfranco [Physics Department, Syracuse University, Syracuse, NY 13244 (United States); Brucato, John Robert; Tozzetti, Lorenzo [Osservatorio Astrofisico di Arcetri, INAF, I-50125 Florence (Italy); De Sio, Antonio [Department of Physics and Astronomy, University of Florence, I-50125 Florence (Italy)

    2012-09-01T23:59:59.000Z

    Oxygen in the interstellar medium is seen in the gas phase, in ices (incorporated in H{sub 2}O, CO, and CO{sub 2}), and in grains such as (Mg{sub x} Fe{sub 1-x} )SiO{sub 3} or (Mg{sub x} Fe{sub 1-x} ){sub 2}SiO{sub 4}, 0 < x < 1. In this investigation, we study the diffusion of oxygen atoms and the formation of oxygen molecules and ozone on the surface of an amorphous silicate film. We find that ozone is formed at low temperature (<30 K), and molecular oxygen forms when the diffusion of oxygen atoms becomes significant, at around 60 K. This experiment, besides being the first determination of the diffusion energy barrier (1785 {+-} 35 K) for oxygen atoms on a silicate surface, suggests bare silicates as a possible storage place for oxygen atoms in low-A{sub v} environments.

  7. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01T23:59:59.000Z

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  8. CF[sub 3] chemistry: Potential implications for stratospheric ozone

    SciTech Connect (OSTI)

    Ko, M.K.W.; Sze, N.D.; Rodriguez, J.M.; Weistenstein, D.K.; Heisey, C.W. (Atmospheric and Environmental Research, Inc., Cambridge, MA (United States)); Wayne, R.P.; Biggs, P.; Canosa-Mas, C.E. (Univ. of Oxford, Oxford (United Kingdom)); Sidebottom, H.W.; Treacy, J. (Univ. College, Dublin (Ireland))

    1994-01-15T23:59:59.000Z

    The authors address questions about the chemistry of CF[sub 3] bearing compounds in the atmosphere, and the impact that the existence of and reaction rate constants for such species may have on stratospheric ozone. Species considered include CF[sub 3], CF[sub 3]O, CF[sub 3]O[sub 2], CF[sub 3]OH, CF[sub 3]OOH, CF[sub 3]ONO[sub 2], CF[sub 3]O[sub 2]NO[sub 2], and CF[sub 3]OOCl. Based on their calculational results, the authors suggest a number of experimental measurements which should substantially decrease uncertainties associated with the role of CF[sub 3] species in atmospheric chemistry related to ozone.

  9. Meeting the New Ozone Standard: Challenges and Opportunities

    Broader source: Energy.gov [DOE]

    This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

  10. E-Print Network 3.0 - ameliorate ozone effects Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: students confuse the relationship between the ozone hole and the greenhouse effect, thus confusing... , and to suggest more effective teaching methods. 2....

  11. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    E-Print Network [OSTI]

    Destaillats, Hugo

    2012-01-01T23:59:59.000Z

    were preceded by an ozone scrubber (# WAT054420, Waters, MA)Atmospheric Environment of the scrubbers was verified underconditions. A new scrubber was used in each individual test

  12. Plasma Chemistry and Plasma Processing, Vol. 22, No. 4, December 2002 ( 2002) Ozone Production in the Positive DC Corona

    E-Print Network [OSTI]

    Chen, Junhong

    Plasma Chemistry and Plasma Processing, Vol. 22, No. 4, December 2002 ( 2002) Ozone Production the distribution of ozone, but does not affect the rate of production. KEY WORDS: Corona discharge; corona plasma

  13. High ozone concentrations on hot days: The role of electric power demand and NOx1 , Linda Hembeck1

    E-Print Network [OSTI]

    Dickerson, Russell R.

    of tropospheric17 ozone, leading to concerns that global warming may exacerbate smog episodes. This18 widely1 High ozone concentrations on hot days: The role of electric power demand and NOx1 emissions2 3 Park,10 MD 20742, U.S.11 12 Key words: power plant emissions, ozone production efficiency, climate

  14. Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace

    E-Print Network [OSTI]

    Collins, Gary S.

    Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace been done to determine vertical ozone profiles, especially in environments such as the northern mixed forest where this field campaign is being run. What past research that has been done has shown that ozone

  15. Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region, induced by dynamic processes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region September 1998 / Revised: 25 January 1999 / Accepted: 26 January 1999 Abstract. The total ozone distribution before. A spatial pattern correlation between the zonally asymmetric part of total ozone

  16. The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations on an accurate potential energy surface

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations present an ab initio potential energy surface for the ground electronic state of ozone. It is global, i. All bound states of nonrotating ozone up to more than 99% of the dissociation energy are calculated

  17. The Huggins band of ozone: Unambiguous electronic and vibrational Zheng-Wang Qu, Hui Zhu, Motomichi Tashiro, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: Unambiguous electronic and vibrational assignment Zheng-Wang Qu, Hui Zhu 12 February 2004; accepted 2 March 2004 The Huggins band of ozone is investigated by means of exact.1063/1.1711589 Because of the importance of ozone for the shielding of harmful UV light, its photophysics has been

  18. LA RPARTITION DE L'OZONE ATMOSPHRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER.

    E-Print Network [OSTI]

    Boyer, Edmond

    LA RÉPARTITION DE L'OZONE ATMOSPHÉRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER. Observatoire observations en déter- minant la distribution de l'ozone par une série de Charlier du type A. En général on ne peut déterminer que la quantité totale d'ozone et la hauteur moyenne de la distribution, ces quantités

  19. Photodissociation of Ozone from 321 to 329 nm: The Relative Yields P2) with O2(X 3

    E-Print Network [OSTI]

    Houston, Paul L.

    Photodissociation of Ozone from 321 to 329 nm: The Relative Yields of O(3 P2) with O2(X 3 g - ), O2 Supporting Information ABSTRACT: Product imaging of O(3 P2) following dissociation of ozone has been used to determine the relative yields of the product channels O(3 P2) + O2(X 3 g - ) of ozone. All three channels

  20. Ozone production efficiency in an urban area Lawrence I. Kleinman, Peter H. Daum, Yin-Nan Lee, Linda J. Nunnermacker,

    E-Print Network [OSTI]

    Ozone production efficiency in an urban area Lawrence I. Kleinman, Peter H. Daum, Yin-Nan Lee; accepted 1 August 2002; published 14 December 2002. [1] Ozone production efficiency can be defined and observational results on ozone production efficiency based on measurements made from aircraft flights

  1. Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH*. Nicolas MOSER**, Caroline CHARPENTIER*, Alexis MOQUET*,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH, Switzerland E-mail : Isabelle.Zdanevitch(a),iner is.fr (corresponding author) ABSTRACT Ozone is actually one by continuous monitors but a better information on ozone levels would be given by a denser monitoring network

  2. Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA

    E-Print Network [OSTI]

    Pan, Laura

    Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA) are used to examine the quality of the Atmospheric Infrared Sounder (AIRS) v4 vertical ozone profile range), AIRS ozone mixing ratios are larger than ozonesonde measurements, and at higher altitudes ($100

  3. The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov; accepted 16 September 2004 The Huggins band of ozone is investigated by means of dynamics calculations American Institute of Physics. DOI: 10.1063/1.1814098 I. INTRODUCTION Because of the importance of ozone

  4. 3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1

    E-Print Network [OSTI]

    Standiford, Richard B.

    3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1 Abstract Plants react biochemically to ozone in three phases: with constitutive chemicals in the apoplastic, plant reactions with ozone result in constitutive molecules such as the ozonolysis of ethylene

  5. Atmospheric Environment 39 (2005) 13731382 A hierarchical Bayesian model to estimate and forecast ozone

    E-Print Network [OSTI]

    Irwin, Mark E.

    2005-01-01T23:59:59.000Z

    reserved. Keywords: Statistical model; Space­time models; Air pollution; Ozone; Meteorology 1. Introduction describing the spatial­temporal behavior of ambient air pollutants such as ozone (O3) and particulate matter. Statistical space­time models are useful for illuminating relationships between different air pollutants

  6. Proceedings: Indoor Air 2005 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    indoor sources such as photocopiers, laser printers or air purifiers, outdoor ozone is the main source generated using pure oxygen (Air Liquide, 99.999 % O2) through an UV light generator (Pen Ray, model SOG 1Proceedings: Indoor Air 2005 2118 REACTIONS BETWEEN OZONE AND BUILDING PRODUCTS: IMPACT ON PRIMARY

  7. Separating the dynamical effects of climate change and ozone depletion. Part

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    ) fixed at 1960 levels and ozone depleting substances (ODSs) varying in time, 2) ODSs fixed at 1960 levels averaged wave drag in SH spring and summer, as well as for final warming dates. Ozone depletion a significant impact on the stratosphere on both a global and a regional scale. Over the past three decades

  8. PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure

    E-Print Network [OSTI]

    in industrial processes is increasing. Applications for ozone include treatment of waste water, water to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration

  9. Atmospheric Environment 38 (2004) 647649 New Directions: Stratospheric ozone recovery in a changing

    E-Print Network [OSTI]

    Cordero, Eugene

    2004-01-01T23:59:59.000Z

    Atmospheric Environment 38 (2004) 647­649 New Directions: Stratospheric ozone recovery by the United Nations to address this global problem. Fig. 1 shows the predicted trends in the stratospheric with the predictions shown in Fig. 1. Future ozone recovery is primarily linked to halogen loading in the stratosphere

  10. White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure

    E-Print Network [OSTI]

    Collins, Gary S.

    White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure Daniel M on a large scale in forests. Monoterpene and sesquiterpene emissions from trees significantly contribute investigates the effect of an abiotic stress, specifically acute ozone exposure, on the terpene emissions

  11. Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion of Silver

    E-Print Network [OSTI]

    Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion The corrosion of Ag contaminated with NaCl particles in gaseous environments containing humidity and ozone analyzed using a coulometric reduction technique. The atmospheric corrosion of Ag was greatly accelerated

  12. The impact of large scale biomass production on ozone air pollution in Joost B. Beltman a

    E-Print Network [OSTI]

    Utrecht, Universiteit

    The impact of large scale biomass production on ozone air pollution in Europe Joost B. Beltman by up to 25% and 40%. Air pollution mitigation strategies should consider land use management. a r t i Poplar a b s t r a c t Tropospheric ozone contributes to the removal of air pollutants from

  13. Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A and unpainted drywall as passive ozone control surfaces in a room-sized laboratory chamber. Mean deposition-50%, resulted in increased reactivity for activated carbon. In our model for a typical house, about 35

  14. Can ozone depletion and global warming interact to produce rapid climate change?

    E-Print Network [OSTI]

    Limpasuvan, Varavut

    Can ozone depletion and global warming interact to produce rapid climate change? Dennis L. Hartmann of Climate Change (IPCC) assess- ment of the status of global warming, which reported that winter stratospheric ozone depletion and greenhouse warming are possible. These interactions may be responsible

  15. NORTHEASTERN NATURALIST2009 16(2):307313 Variation in Ozone Sensitivity Within Indian Hemp and

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    NORTHEASTERN NATURALIST2009 16(2):307­313 Variation in Ozone Sensitivity Within Indian Hemp , and Dennis R. Decoteau1 Abstract - Sixteen selections of Apocynum cannabinum (Indian Hemp) and nine, adaxial stipple, similar to symptoms ascribed to ambient ozone in the field. Indian Hemp was more

  16. The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCOSystems Analysis Success| Department of Energy The Weekend Ozone Effect -

  17. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01T23:59:59.000Z

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  18. Elm leaf beetle performance on ozone-fumigated elm. Forest Service research paper (Final)

    SciTech Connect (OSTI)

    Barger, J.H.; Hall, R.W.; Townsend, A.M.

    1992-01-01T23:59:59.000Z

    Leaves (1986) from elm hybrids ('Pioneer', 'Homestead', '970') previously fumigated in open-top chambers with ozone or with charcoal-filtered air (CFA) were evaluated for water and nitrogen content or were fed to adult elm leaf beetles (ELB), Xanthogaleruca = (Pyrrhalta) luteola (Muller), to determine host suitability for beetle fecundity and survivorship. ELB females fed ozone-fumigated leaves laid significantly fewer eggs than females fed CFA-fumigated leaves. Leaf nitrogen or water content was unaffected. Hybrid '970' (1988) was fumigated with CFA or with ozone concentrations to determine effects on ELB fecundity, leaf consumption, and survivorship. Significantly fewer eggs were laid at the higher concentration of ozone. Because higher levels of ozone are found in urban areas and because municipalities often replace American elms, Ulmus americana L., with Dutch elm disease-resistant elm hybrids that are susceptible to ELB defoliation, it is important to explore the relationships between ozone sensitivity of elm and susceptibility to ELB herbivory before recommending replacement use of these elms to municipal arborists. The study was conducted to determine whether ozone pollution influences host quality of elm for ELB and how ELB fecundity, leaf consumption rate, and survivorship are affected.

  19. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15T23:59:59.000Z

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  20. Microarray-based analysis of survival of soil microbial community during ozonation

    SciTech Connect (OSTI)

    Wang, Jian; Van Nostrand, Joy D.; He, Zhili; Wu, Liyou; Deng, Ye; Zhang, Xu; Zhou, Jizhong; Li, Guanghe

    2010-05-17T23:59:59.000Z

    A 15 h ozonation was performed on bioremediated soil to remove recalcitrant residual oil. To monitor the survival of indigenous microorganisms in the soil during in-situ chemical oxidation(ISCO) culturing and a functional genearray, GeoChip, was used to examine the functional genes and structure of the microbial community during ozonation (0h, 2h, 4h, 6h, 10hand15h). Breakthrough ozonation decreased the population of cultivable heterotrophic bacteria by about 3 orders of magnitude. The total functional gene abundance and diversity decreased during ozonation, as the number of functional genes was reduced by 48percent after 15 h. However, functional genes were evenly distributed during ozonation as judged by the Shannon-Weaver Evenness index. A sharp decrease in gene number was observed in the first 6 h of ozonation followed by a slower decrease in the next 9 h, which was consistent with microbial populations measured by a culture based method. Functional genes involved in carbon, nitrogen, phosphors and sulfur cycling, metal resistance and organic remediation were detected in all samples. Though the pattern of gene categories detected was similar for all time points, hierarchica lcluster of all functional genes and major functional categories all showed a time-serial pattern. Bacteria, archaea and fungi decreased by 96.1percent, 95.1percent and 91.3percent, respectively, after 15 h ozonation. Delta proteobacteria, which were reduced by 94.3percent, showed the highest resistance to ozonation while Actinobacteria, reduced by 96.3percent, showed the lowest resistance. Microorganisms similar to Rhodothermus, Obesumbacterium, Staphylothermus, Gluconobacter, and Enterococcus were dominant at all time points. Functional genes related to petroleum degradation decreased 1~;;2 orders of magnitude. Most of the key functional genes were still detected after ozonation, allowing a rapid recovery of the microbial community after ozonation. While ozone had a large impact on the indigenous soil microorganisms, a fraction of the key functional gene-containing microorganisms survived during ozonation and kept the community functional.

  1. Oxidation of methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by ozone and combined ozone/hydrogen peroxide

    SciTech Connect (OSTI)

    Leitner, N.K.V.; Papailhou, A.L.; Croue, J.P.; Dore, M. (Univ. de Poitiers (France)); Peyrot, J. (British Petroleum, Harfleur (France))

    1994-01-01T23:59:59.000Z

    The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O[sub 3]/H[sub 2]O[sub 2]. batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH[degree]-radical with MTBE and ETBE (k[sub OH[degree]/ETBE]/k[sub OH[degree]//MTBE] = 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE an ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds. 10 refs., 10 figs., 1 tab.

  2. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Larry LaBuz; Rui Afonso

    2005-03-31T23:59:59.000Z

    This is the fourth quarterly report under DOE Cooperative Agreement No.: DE-FC26-03NT41730. Due a number of circumstances, mostly associated with subcontractor agreements, the actual beginning of the project was delayed from its original award date of March 5, 2003. DOE's Project Manager was kept informed (verbally) by PPL's Project Manager throughout this period. Because of this delay, this is the fourth quarterly report and it refers to the time period from January to March 2004. The on-site deployment and testing of the ozonation system took place during this period. This report summarizes these activities including some preliminary results. No significant issues or concerns are identified.

  3. Parallel ozone monitoring study performed in the Ojai Valley, California

    SciTech Connect (OSTI)

    Mikel, D.K. [Ventura County Air Pollution Control District, CA (United States)

    1998-12-31T23:59:59.000Z

    The Ventura County Air Pollution Control District (also known as the District) Monitoring and Technical Services Division, relocated the State and Local Air Monitoring Station (SLAMS) for the Ojai Valley. The SLAMS was located on property that was being abandoned and sold by the County of Ventura, thus necessitating a station relocation. From August 3, through October 31, 1995, the District performed parallel ozone monitoring at two sites. The former site was located at 1768 Maricopa Road, Ojai, California (AIRS Site 06111-1003) and the existing site at 1201 Ojai Avenue, Ojai California (County Fire Station {number_sign}21). This paper outlines the process of parallel monitoring, the statistical tests used and their justification. In addition, there is a discussion on station equivalency.

  4. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    www.epa.gov/ozone/science/ods/index.html. U.S. Environmentaltook action in phasing out ODS, there has been increasingEPA’s authority to regulate ODS is set out in Title VI of

  5. Real-World Studies of Ambient Ozone Formation as a Function of...

    Office of Environmental Management (EM)

    -- Washington D.C. ace29lawson.pdf More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Health Impacts Program DOE's...

  6. Atmospheric Environment 39 (2005) 28292838 Diurnal and seasonal cycles of ozone precursors observed from

    E-Print Network [OSTI]

    Wingenter, Oliver W.

    characteristics. Ethane and propane, largely originated from leakage of natural gas or liquefied petroleum gases) and nitrogen oxides (NO+NO2 ¼ NOx), ozone is photochemically pro- duced and can accumulate to hazardous levels

  7. Ozone response to emission changes: a modeling study during the MCMA-2006/MILAGRO Campaign

    E-Print Network [OSTI]

    Song, Jihee

    The sensitivity of ozone production to precursor emissions was investigated under five different meteorological conditions in the Mexico City Metropolitan Area (MCMA) during the MCMA-2006/MILAGRO field campaign using the ...

  8. Climatology and trends in the forcing of the stratospheric ozone transport

    E-Print Network [OSTI]

    Monier, Erwan

    A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer continuity equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40). In ...

  9. Climatology and Trends in the Forcing of the Stratospheric Ozone Transport

    E-Print Network [OSTI]

    Monier, Erwan

    A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer transport equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re- Analysis (ERA-40). In ...

  10. Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas

    E-Print Network [OSTI]

    Nam, Junsang

    2007-01-01T23:59:59.000Z

    High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

  11. Ozone (o3) efficacy on reduction of phytophthora capsici in recirculated horticultural irrigation water 

    E-Print Network [OSTI]

    McDonald, Garry Vernon

    2009-05-15T23:59:59.000Z

    Microorganisms that cause plant disease have been isolated in recirculated irrigation water and increase the risks of disease incidence in horticultural operations. Ozone is an effective oxidizer used to disinfect drinking water supplies and treat...

  12. Examination of the Effects of Sea Salt Aerosols on Southeast Texas Ozone and Secondary Organic Aerosol 

    E-Print Network [OSTI]

    Benoit, Mark David

    2013-02-06T23:59:59.000Z

    study these interactions. This is important because the EPA has considered tightening the standards for both ozone and particulate matter. Industries would then need to reduce emissions or move farther from current sources of Cl or NOx pollution....

  13. Isolation and characterization of five ozone-inductible cDNA clones from Atriplax canescens (saltbush) 

    E-Print Network [OSTI]

    No, Eun-Gyu

    1994-01-01T23:59:59.000Z

    Prolonged exposure of plants to ozone inhibits growth and development and produces visible signs of damage. Within a few hours of exposure, certain biochemical alterations have been observed with the induction of several stress-related proteins...

  14. An ozone climatology of the Dallas-Fort Worth area and its relationship to meteorology 

    E-Print Network [OSTI]

    Nobis, Timothy Edward

    1998-01-01T23:59:59.000Z

    The Environmental protection agency has established a hics. National Ambient Air Quality Standard for surface ozone through the Clean Air Act and its amendments. The Dallas / Fort Worth area is in violation of these standards, and to date...

  15. Evaluation of a novel ozone generation technique for disinfection of poultry hatchers and processed broiler carcasses 

    E-Print Network [OSTI]

    Ramirez, Gerardo Arturo

    1994-01-01T23:59:59.000Z

    When comparing electrochemically generated ozone(03)(2.94.2 wt % inside the (hatcher) and formaldehyde (16 n-A formalin + 7.5 g potassium pertnanganate) for disinfection of Salmonella enteiltidis (SE) contaminated agar plates and typical hatchery...

  16. Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies

    E-Print Network [OSTI]

    Williams, James Jason

    1999-01-01T23:59:59.000Z

    Experiments were conducted to determine the quantity and conditions of electrochemical ozonation (O?) that maximize the dissolution of the lignin-cellulose complex. Combination treatments of anhydrous ammonia (NH?) and O? were also assessed...

  17. Environmental Air and water pollution, extinction of species, depletion of ozone in the stratosphere,

    E-Print Network [OSTI]

    Kurapov, Alexander

    ecosystem ecology, environmental health, and environmental conservation and sustainability. The curriculumEnvironmental Sciences Air and water pollution, extinction of species, depletion of ozone to examine and understand complex environmental issues, to predict environmental change, and to participate

  18. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2015-01-01T23:59:59.000Z

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore »same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  19. Ozone predictabilities due to meteorological uncertainties in the Mexico City basin using ensemble forecasts

    E-Print Network [OSTI]

    Bei, Naifang

    The purpose of the present study is to investigate the sensitivity of ozone (O3)[(O subscript 3)] predictions in the Mexico City Metropolitan Area (MCMA) to meteorological initial uncertainties and planetary boundary layer ...

  20. 1996 Paso del Norte ozone study VOC measurements

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.; Ramadan, A.B.

    1999-07-01T23:59:59.000Z

    Ambient air VOC samples were collected at surface air quality monitoring sites, near sources of interest, and aloft on the US and Mexican side of the border during a six week period of the 1996 Paso del Norte Ozone Study. On nine intensive operations (IOP) days, when high ozone concentrations were forecast, five 2-hr samples were collected at five IOP sites, three on the US side and two on the Mexican side. Six special survey sites on the US side and two on the Mexican side were sampled to characterize up-wind, down-wind and other emissions. In Ciudad Juarez, rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane and butane fuels, and an industrial manufacturing site were sampled. Carbonyl samples were collected at three surface sites. Carbonyl and canister grab samples were also collected during aircraft and hot air balloon flights. Most of the hydrocarbon samples were collected in electro-polished stainless steel canisters which were returned to laboratories for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration GC-FID. The carbonyl samples were collected on DNPH impregnated C-18 Sep-Pak cartridges and analyzed by HPLC to quantify 13, C-1 to C-8 species. This paper presents the spatial and temporal characteristics of VOC species concentrations and compositions to examine the differences and similarities of the various locations and time periods. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations being recorded in the morning at three vehicle-dominated sites, two in Ciudad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Ciudad Juarez, were the most abundant hydrocarbons. The most abundant carbonyls were acetaldehyde and acetone.

  1. Ozone (o3) efficacy on reduction of phytophthora capsici in recirculated horticultural irrigation water

    E-Print Network [OSTI]

    McDonald, Garry Vernon

    2009-05-15T23:59:59.000Z

    through enriched environments, or by interfering with water treatment systems such as filtration (MacDonald et al., 1994). Phytophthora, in particular, has been reported as a major contaminant of recirculated nursery irrigation water (MacDonald et al... environment which allows for greater electrochemical ozone formation. The Nafion membrane, as mentioned, is highly resistant to chemical attack by ozone. A final cathode reaction involves reducing oxygen from ambient air and protons (H + ) flowing from...

  2. Formation of ozone and oxidation of methane in a direct current corona discharge

    E-Print Network [OSTI]

    Tangirala, Umashanker

    1976-01-01T23:59:59.000Z

    FORMATION OF OZONE AND OXIDATION OF METHANE IN A DIRECT CURRENT CORONA DISCHARGE A Thesis by UMASHANKER TANGIRALA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE May 1976 Major Subject: Chemical Engineering FORMATION OF OZONE AND OXIDATION OF METHANE IN A DIRECT CURRENT CORONA DISCHARGE A Thesis by UMASHANKER TANGIRALA Approved as to style and content by: (Chairman of Committee) ( ad of Department...

  3. Apply early! Limited enrollment.

    E-Print Network [OSTI]

    volcano. Experience the culture and history of Hawaii, and the impact of human activitiesApply early! Limited enrollment. Environmental Science in the Hawaiian Islands Observe, research

  4. Optimization of stabilized leachate treatment using ozone/persulfate in the advanced oxidation process

    SciTech Connect (OSTI)

    Abu Amr, Salem S. [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Aziz, Hamidi Abdul, E-mail: cehamidi@eng.usm.my [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Adlan, Mohd Nordin [School of Civil Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)

    2013-06-15T23:59:59.000Z

    Highlights: ? Ozone and persulfate reagent (O{sub 3}/S{sub 2}O{sub 8}{sup 2-}) was used to treat stabilized leachate. ? Central composite design (CCD) with response surface methodology (RSM) was applied. ? Operating variables including ozone and persulfate dosage, pH variance, and reaction time. ? Optimum removal of COD, color, and NH{sub 3}–N was 72%, 96%, and 76%, respectively. ? A good value of ozone consumption (OC) obtained with 0.60 (kg O{sub 3}/kg COD). - Abstract: The objective of this study was to investigate the performance of employing persulfate reagent in the advanced oxidation of ozone to treat stabilized landfill leachate in an ozone reactor. A central composite design (CCD) with response surface methodology (RSM) was applied to evaluate the relationships between operating variables, such as ozone and persulfate dosages, pH, and reaction time, to identify the optimum operating conditions. Quadratic models for the following four responses proved to be significant with very low probabilities (<0.0001): COD, color, NH{sub 3}–N, and ozone consumption (OC). The obtained optimum conditions included a reaction time of 210 min, 30 g/m{sup 3} ozone, 1 g/1 g COD{sub 0}/S{sub 2}O{sub 8}{sup 2-} ratio, and pH 10. The experimental results were corresponded well with predicted models (COD, color, and NH{sub 3}–N removal rates of 72%, 96%, and 76%, respectively, and 0.60 (kg O{sub 3}/kg COD OC). The results obtained in the stabilized leachate treatment were compared with those from other treatment processes, such as ozone only and persulfate S{sub 2}O{sub 8}{sup 2-} only, to evaluate its effectiveness. The combined method (i.e., O{sub 3}/S{sub 2}O{sub 8}{sup 2-}) achieved higher removal efficiencies for COD, color, and NH{sub 3}–N compared with other studied applications. Furthermore, the new method is more efficient than ozone/Fenton in advanced oxidation process in the treatment of the same studied leachate.

  5. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, Duncan W. (Santa Fe, NM); Mattes, Benjamin R. (Santa Fe, NM); Koskelo, Aaron C. (Los Alamos, NM); Heeger, Alan J. (Santa Barbara, CA); Robinson, Jeanne M. (Los Alamos, NM); Smilowitz, Laura B. (Los Alamos, NM); Klimov, Victor I. (Los Alamos, NM); Cha, Myoungsik (Goleta, CA); Sariciftci, N. Serdar (Santa Barbara, CA); Hummelen, Jan C. (Groningen, NL)

    1998-01-01T23:59:59.000Z

    Optical limiting materials. Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO.sub.2) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400-1100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes.

  6. The influence of cosmic rays on the size of the Antarctic Ozone Hole

    E-Print Network [OSTI]

    M. Alvarez Madrigal; J. Perez Peraza; V. M. Velasco

    2010-01-15T23:59:59.000Z

    The Antarctic region in which severe ozone depletion has taken place is known as the ozone hole. This region has two basic indicators: the area, where the ozone abundance is low (size), and the quantity of ozone mass deficit (depth). The energetic particles that penetrate deeply into the atmosphere and galactic cosmic rays (GCR) modify the ozone abundance in the stratosphere. With this research project, we are looking for evidence of a connection between variations in the cosmic ray flux and variations in the size of the ozone hole. In addition, we are looking for signs of the kind of processes that physically connect GCR fluxes with variations in the stratospheric ozone hole size (OHS) in the Antarctic region. With this goal in mind, we also analyze here the atmospheric temperature (AT) anomalies, which have often been linked with such variations. Using Morlet's wavelet spectral analysis to compute the coherence between two time series, we found that during the analyzed period (1982-2005), there existed a common signal of around 3 and 5 years between the OHS and GCR time series, during September and November, respectively. In both cases, the relationship showed a time-dependent anti-correlation between the two series. On the other hand, for October the analysis showed a time-dependent correlation that occurs around 1.7 years. These results seem to indicate that there exist at least two kinds of modulation processes of GCR fluxes on the OHS that work simultaneously but that change their relative relevance along the timeline.

  7. A Kalman-filter bias correction of ozone deterministic, ensemble-averaged, and probabilistic forecasts

    SciTech Connect (OSTI)

    Monache, L D; Grell, G A; McKeen, S; Wilczak, J; Pagowski, M O; Peckham, S; Stull, R; McHenry, J; McQueen, J

    2006-03-20T23:59:59.000Z

    Kalman filtering (KF) is used to postprocess numerical-model output to estimate systematic errors in surface ozone forecasts. It is implemented with a recursive algorithm that updates its estimate of future ozone-concentration bias by using past forecasts and observations. KF performance is tested for three types of ozone forecasts: deterministic, ensemble-averaged, and probabilistic forecasts. Eight photochemical models were run for 56 days during summer 2004 over northeastern USA and southern Canada as part of the International Consortium for Atmospheric Research on Transport and Transformation New England Air Quality (AQ) Study. The raw and KF-corrected predictions are compared with ozone measurements from the Aerometric Information Retrieval Now data set, which includes roughly 360 surface stations. The completeness of the data set allowed a thorough sensitivity test of key KF parameters. It is found that the KF improves forecasts of ozone-concentration magnitude and the ability to predict rare events, both for deterministic and ensemble-averaged forecasts. It also improves the ability to predict the daily maximum ozone concentration, and reduces the time lag between the forecast and observed maxima. For this case study, KF considerably improves the predictive skill of probabilistic forecasts of ozone concentration greater than thresholds of 10 to 50 ppbv, but it degrades it for thresholds of 70 to 90 ppbv. Moreover, KF considerably reduces probabilistic forecast bias. The significance of KF postprocessing and ensemble-averaging is that they are both effective for real-time AQ forecasting. KF reduces systematic errors, whereas ensemble-averaging reduces random errors. When combined they produce the best overall forecast.

  8. Synchronization of Limit Sets

    E-Print Network [OSTI]

    Changpin Li; Weihua Deng

    2005-10-10T23:59:59.000Z

    In this Letter, we derive a sufficient condition of synchronizing limit sets (attractors and repellers) by using the linear feedback control technique proposed here. There examples are included. The numerical simulations and computer graphics show that our method work well.

  9. Quantum Limits of Thermometry

    E-Print Network [OSTI]

    Thomas M. Stace

    2010-06-08T23:59:59.000Z

    The precision of typical thermometers consisting of $N$ particles is shot noise limited, improving as $\\sim1/\\sqrt{N}$. For high precision thermometry and thermometric standards this presents an important theoretical noise floor. Here it is demonstrated that thermometry may be mapped onto the problem of phase estimation, and using techniques from optimal phase estimation, it follows that the scaling of the precision of a thermometer may in principle be improved to $\\sim1/N$, representing a Heisenberg limit to thermometry.

  10. Hydrocarbon source apportionment for the 1996 Paso del Norte ozone study

    SciTech Connect (OSTI)

    Fujita, E.M.

    1999-07-01T23:59:59.000Z

    This paper provides a summary of the nonmethane hydrocarbon (NMHC) source apportionments performed at Desert Research Institute as part of the 1996 Paso del Norte Ozone Study. Version 8 of the Chemical Mass Balance (CMB) receptor model was applied to a total of 2232 hourly automated gas chromatography (auto-GC) and 225 two-hour canister samples. The auto-GC system was operated by the Texas Natural Resource Conservation Commission at one site in central El Paso. Two-hour canister samples were collected five times per day at 0500--0700, 0700--0900, 0900--1100, 1100--1300, and 1500--1700 MST during intensive study periods at one urban and one rural site on each side of the border. Gasoline vehicle exhaust accounts for one-half to two-thirds of NMHC in Juarez and El Paso with highest contributions during the morning and afternoon commute periods. Emissions from diesel exhaust and propane buses are both 2 to 5% of NMHC in Juarez and less than 2% in El Paso. The average sum of liquid gasoline and gasoline vapor increases during the day in Juarez from 2% at 0600 to about 8% at 1600. Diurnal and day-of-the-week patterns in the liquid gasoline contributions are essentially identical to the corresponding patterns for motor vehicle exhaust. These patterns suggest that a large fraction of the liquid gasoline contribution is associated with tailpipe emissions rather than evaporative emissions from either vehicle or industrial sources. Additionally, the contributions of liquid gasoline are strongly correlated with vehicle exhaust with respect to wind direction. The sum of the two sources put the upper limit for tailpipe contributions at 60 to 70%t of NMHC.

  11. 47th AIAA Aerospace Science Meeting and Exhibit, 5-8 January 2009, Orlando, Florida The Dynamics of Unsteady Detonation in Ozone

    E-Print Network [OSTI]

    The Dynamics of Unsteady Detonation in Ozone Tariq D. Aslam , Los Alamos National Laboratory, Los Alamos, New. Introduction We significantly extend calculations of unsteady detonation in ozone mixtures first reported

  12. On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California

    E-Print Network [OSTI]

    Pusede, S. E.

    The San Joaquin Valley (SJV) experiences some of the worst ozone air quality in the US, frequently exceeding the California 8 h standard of 70.4 ppb. To improve our understanding of trends in the number of ozone violations ...

  13. Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.

    SciTech Connect (OSTI)

    Whitfield, R. G.

    1999-03-04T23:59:59.000Z

    This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

  14. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-01-01T23:59:59.000Z

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  15. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-11-01T23:59:59.000Z

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  16. Fading of alizarin and related artists's pigments by atmospheric ozone: reaction products and mechanisms

    SciTech Connect (OSTI)

    Grosjean, D.; Whitmore, P.M.; De Moor, C.P.; Cass, G.R.; Druzik, J.R.

    1987-07-01T23:59:59.000Z

    The colorants alizarin and Alizarin Crimson (a calcium-aluminum lake pigment) and their simple structural homologue anthraquinone were deposited on silica gel, cellulose, and Teflon substrates and exposed in the dark to ozone in purified air (approx.0.4 ppm O/sub 3/ for 95 days and approx.10 ppm O/sub 3/ for 18-80 h). Exposed and control samples were analyzed by mass spectrometry. Alizarin Crimson reacted with ozone on all substrates, yielding phthalic acid (major), benzoic acid (minor), and other minor and unidentified products. Anthraquinone did not react with ozone irrespective of conditions. Alizarin did not react on Teflon or cellulose but reacted on silica gel to yield phthalic acid (major) and other products. A chemical mechanism responsible for the fading of these alizarin-related colorants by ozone is suggested that is consistent with the products distribution, the observed reactivity sequence, and the observed substrate-specific effects. The possible application of this work to predicting the ozone fastness of other alizarin-related pigments is discussed briefly. 33 references, 5 figures.

  17. Contrasting Surface Ozone and Particulate Matter measurements with meteorological conditions in South Florida and its possible impacts on the number of Asthma cases: Five years of correlations.

    E-Print Network [OSTI]

    Miami, University of

    Contrasting Surface Ozone and Particulate Matter measurements with meteorological conditions, wind speed and direction), and air quality indicators (ozone O3 and particulate matter PM2.5) are presented in this study. Surface Ozone and Particulate Matter have been both important triggers of asthma

  18. Interaction of Gas-Phase Ozone at 296 K with Unsaturated Self-Assembled Monolayers: A New Look at an Old System

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Interaction of Gas-Phase Ozone at 296 K with Unsaturated Self-Assembled Monolayers: A New Look The oxidation of organics adsorbed on surfaces by ozone is of fundamental chemical interest and potentially- FTIR using ozone concentrations that spanned 5 orders of magnitude, from 1011 to 1016 molecules cm-3

  19. Effects of ozone on the common bed bug (Cimex lectularius) James Feston, Marissa McDonough, Linda Mason, Timothy Gibb, Kurt Saltzmann

    E-Print Network [OSTI]

    Ginzel, Matthew

    Effects of ozone on the common bed bug (Cimex lectularius) James Feston, Marissa McDonough, Linda of ozone in stored maize. Journal of Stored Products Research 37(4): 371-382. McDonough, M., Mason, L., Woloshuk, C. 2011. Susceptibility of stored product insects to high concentrations of ozone at different

  20. Ozone fluxes in a Pinus ponderosa ecosystem are dominated by non-stomatal processes: Evidence from long-term continuous measurements

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone fluxes in a Pinus ponderosa ecosystem are dominated by non-stomatal processes: Evidence from and Atmospheric Research Utrecht, Utrecht University, Utrecht, The Netherlands 1. Introduction Ozone is considered one of the most dangerous oxidant molecules for plants (UNECE, 2004; EPA, 2007). Ozone concentra- tion

  1. Source Contributions to VOC's to Ozone Formation in Southeast Texas Using a Source-oriented Air Quality Model 

    E-Print Network [OSTI]

    Krishnan, Anupama

    2011-08-08T23:59:59.000Z

    Houston-Galveston-Brazoria area is in severe non-attainment status for ozone compliance. Source-oriented mechanistic modeling was used to determine the major sources of VOCs that contributes to ozone formation during the Texas Air Quality Study (Tex...

  2. Higher surface ozone concentrations over the Chesapeake Bay than over the adjacent land: Observations and models from the

    E-Print Network [OSTI]

    Dickerson, Russell R.

    , in high enough concentrations, is a hazardous secondary air pollutant regulated by the United States t s Observations of ozone are higher over the Chesapeake Bay than areas upwind on land. Dry deposition rates, slower dry deposition rates, and other lesser mechanisms, contribute to the local maximum of ozone over

  3. Impact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F. Maupetit

    E-Print Network [OSTI]

    Boyer, Edmond

    indoor air quality (IAQ) since they produce secondary pollutants, mainly aldehydes which are known to document the impact on IAQ of outdoor ozone during summer air pollution episodes. For this purpose, a oneImpact of ozone on indoor air quality: a preliminary field study M. Nicolas, O. Ramalho, F

  4. Source Contributions to VOC's to Ozone Formation in Southeast Texas Using a Source-oriented Air Quality Model

    E-Print Network [OSTI]

    Krishnan, Anupama

    2011-08-08T23:59:59.000Z

    Houston-Galveston-Brazoria area is in severe non-attainment status for ozone compliance. Source-oriented mechanistic modeling was used to determine the major sources of VOCs that contributes to ozone formation during the Texas Air Quality Study (Tex...

  5. Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2

    E-Print Network [OSTI]

    Wu, Shiliang

    1 Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2 3 emissions of ozone precursors. The climate and16 emission effect in combination will increase afternoon mean increases18 in global (excluding China) anthropogenic emissions, 37% to Chinese emission19 increases

  6. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, D.W.; Mattes, B.R.; Koskelo, A.C.; Heeger, A.J.; Robinson, J.M.; Smilowitz, L.B.; Klimov, V.I.; Cha, M.; Sariciftci, N.S.; Hummelen, J.C.

    1998-04-21T23:59:59.000Z

    Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO{sub 2}) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400--1,100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes. 5 figs.

  7. Laboratory measurement of secondary pollutant yields from ozone reaction with HVAC filters.

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Zhang, Jianshun (Jensen); Fisk, William J.

    2009-09-09T23:59:59.000Z

    We used Proton Transfer Reaction - Mass Spectrometry (PTR-MS) and conventional sampling methods to monitor and identify trace level organic pollutants formed in heterogeneous reactions between ozone and HVAC filters in real time. Experiments were carried out using a bench-scale flow tube reactor operating with dry air and humidified air (50% RH), at realistically high ozone concentrations (150 ppbv). We explored different filter media (i.e., fiberglass and cotton/polyester blends) and different particle loadings (i.e., clean filter and filters loaded with particles for 3 months at the Lawrence Berkeley National Laboratory and the Port of Oakland, CA). Detailed emission dynamics of very low levels of certain organic pollutants from filter media upon ozone exposure in the presence of moisture have been obtained and analyzed.

  8. Thermochemical Kinetics for Multireference Systems: Addition Reactions of Ozone

    SciTech Connect (OSTI)

    Zhao, Yan; Tishchenko, Oksana; Gour, Jeffrey R.; Li, Wei; Lutz, Jesse; Piecuch, Piotr; Truhlar, Donald G.

    2009-05-14T23:59:59.000Z

    The 1,3-dipolar cycloadditions of ozone to ethyne and ethene provide extreme examples of multireference singlet-state chemistry, and they are examined here to test the applicability of several approaches to thermochemical kinetics of systems with large static correlation. Four different multireference diagnostics are applied to measure the multireference characters of the reactants, products, and transition states; all diagnostics indicate significant multireference character in the reactant portion of the potential energy surfaces. We make a more complete estimation of the effect of quadruple excitations than was previously available, and we use this with CCSDT/CBS estimation of Wheeler et al. (Wheeler, S. E.; Ess, D. H.; Houk, K. N. J. Phys. Chem. A 2008, 112, 1798.) to make new best estimates of the van der Waals association energy, the barrier height, and the reaction energy to form the cycloadduct for both reactions. Comparing with these best estimates, we present comprehensive mean unsigned errors for a variety of coupled cluster, multilevel, and density functional methods. Several computational aspects of multireference reactions are considered: (i) the applicability of multilevel theory, (ii) the convergence of coupled cluster theory for reaction barrier heights, (iii) the applicability of completely renormalized coupled cluster methods to multireference systems, (iv) the treatment by density functional theory, (v) the multireference perturbation theory for multireference reactions, and (vi) the relative accuracy of scaling-type multilevel methods as compared with additive ones. It is found that scaling-type multilevel methods do not perform better than the additive-type multilevel methods. Among the 48 tested density functionals, only M05 reproduces the best estimates within their uncertainty. Multireference perturbation theory based on the complete-active-space reference wave functions constructed using a small number of reaction-specific active orbitals gives accurate forward barrier heights; however, it significantly underestimates reaction energies.

  9. NRF2 activation is involved in ozonated human serum upregulation of HO-1 in endothelial cells

    SciTech Connect (OSTI)

    Pecorelli, Alessandra [Department of Molecular and Developmental Medicine, University of Siena (Italy); Child Neuropsychiatry Unit, University Hospital, AOUS, Siena (Italy); Bocci, Velio [Department of Physiology, University of Siena (Italy); Acquaviva, Alessandra [Department of Molecular and Developmental Medicine, University of Siena (Italy); Belmonte, Giuseppe [Department of Biomedical Sciences, University of Siena (Italy); Gardi, Concetta [Department of Molecular and Developmental Medicine, University of Siena (Italy); Virgili, Fabio [INRAN, Rome (Italy); Ciccoli, Lucia [Department of Molecular and Developmental Medicine, University of Siena (Italy); Valacchi, Giuseppe, E-mail: giuseppe.valacchi@unife.it [Department of Life Sciences and Biotechnology, University of Ferrara (Italy); Department of Food and Nutrition, Kyung Hee University, Seoul (Korea, Republic of)

    2013-02-15T23:59:59.000Z

    During the last decade, it has been shown that the activation of NRF2 and the binding to electrophile-responsive element (EpREs), stimulates the expression of a great number of genes responsible for the synthesis of phase I and phase II proteins, including antioxidants enzymes and heme oxygenase-1 (HO-1). This critical cell response occurs in cardiovascular, degenerative and chronic infective diseases aggravated by a chronic oxidative stress. In our previous reports we have shown that ozonated plasma is able to up-regulate HO-1 expression in endothelial cells. In the present work we investigated a candidate mechanism involved in this process. After treatment with increasing doses of ozonated serum (20, 40 and 80 ?g/mL O{sub 3} per mL of serum), a clear dose dependent activation of NRF2 and the subsequent induction of HO-1 and NAD(P)H quinone oxidoreductase 1(NQO1) was observed. This effect was also present when cells were treated with serum and hydrogen peroxide (H{sub 2}O{sub 2}) or serum and 4-hydroxynonenal (4HNE). Moreover, the treatment with ozonated serum was associated with a dose-dependent activation of extracellular-signal-regulated kinases (ERK1/2) and p38 MAP kinases (p38), not directly involved in NRF2 activation. These data, provide a new insight on the mechanism responsible for the induction of HO-1 expression by ozonated serum in the endothelium, and have a practical importance as an expedient approach to the treatment of patients with both effective orthodox drugs and ozonated autohemotherapy, targeted to the restoration of redox homeostasis. - Highlights: ? Endothelial HO1 is upregulated by ozonated plasma ? This activation is induced by NRF2 and it is ERK independent. ? 4HNE and H{sub 2}O{sub 2} are the main molecules involved in this process. ? Ozonated plasma induced a hormetic effect ? Combination of orthodox medicine and ozonated plasma can be a useful treatment.

  10. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jérémie; Brunner, Gregory; Zhang, Jianshun (Jensen); Fisk, William J.

    2011-05-01T23:59:59.000Z

    Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

  11. 19USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. A variety of vascular plant species exhibit typical foliar injury symptoms when exposed to ambient ozone, making

    E-Print Network [OSTI]

    Standiford, Richard B.

    exhibit typical foliar injury symptoms when exposed to ambient ozone, making them useful as bioindicators ozone monitors are not available. Bioindicators are often introduced plant species known as sentinels. They are known to be sensitive to ozone and will respond rapidly if they are given special care to ensure ozone

  12. Indoor Secondary Pollutants from Household Product Emissions inthe Presence of Ozone: A Bench-Scale Chamber Study

    SciTech Connect (OSTI)

    Destaillats, Hugo; Lunden, Melissa M.; Singer, Brett C.; Coleman,Beverly K.; Hodgson, Alfred T.; Weschler, Charles J.; Nazaroff, William W.

    2005-10-01T23:59:59.000Z

    Ozone-driven chemistry is a major source of indoor secondary pollutants of health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields under most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of ultrafine particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10{sup 5} molecules cm{sup -3} were measured. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate test, we exposed the dry residue of two products to ozone in the chamber and observed the formation of gas-phase and particle-phase secondary oxidation products.

  13. Fault current limiter

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2013-10-08T23:59:59.000Z

    A fault current limiter (FCL) includes a series of high permeability posts for collectively define a core for the FCL. A DC coil, for the purposes of saturating a portion of the high permeability posts, surrounds the complete structure outside of an enclosure in the form of a vessel. The vessel contains a dielectric insulation medium. AC coils, for transporting AC current, are wound on insulating formers and electrically interconnected to each other in a manner such that the senses of the magnetic field produced by each AC coil in the corresponding high permeability core are opposing. There are insulation barriers between phases to improve dielectric withstand properties of the dielectric medium.

  14. A Spatial Econometric Approach to Measuring Pollution Externalities: An Application to Ozone Smog

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    to analyze air pollution externalities. State-by-state source-receptor transfer coefficients that can be used of the six cri- teria pollutants for which National Ambient Air Quali- ty Standards have been establishedA Spatial Econometric Approach to Measuring Pollution Externalities: An Application to Ozone Smog C

  15. Thickness influence on surface morphology and ozone sensing properties of nanostructured ZnO transparent

    E-Print Network [OSTI]

    , 71004 Heraklion, Crete, Greece Available online 19 January 2006 Abstract Transparent zinc oxide (Zn Keywords: Zinc oxide; PLD; AFM; Ozone 1. Introduction Zinc oxide (ZnO) is an n-type semiconductor devices [3], varistors, planar optical waveguides [4], transparent electrodes [5,6], ultraviolet

  16. Author's personal copy Digestive utilization of ozone-exposed forage by rabbits (Oryctolagus cuniculus)

    E-Print Network [OSTI]

    Ditchkoff, Steve

    Author's personal copy Digestive utilization of ozone-exposed forage by rabbits (Oryctolagus Digestibility Forage quality Herbivore nutrition Phenolics Rabbits Southern Piedmont a b s t r a c t A mixture) in a digestibility experiment. Forages and feed refusals were analyzed for concentrations of total cell wall

  17. A possible mechanism for combined chlorine and bromine catalyzed destruction of tropospheric ozone in the arctic

    SciTech Connect (OSTI)

    Le Bras, G. [Laboratoire de Combustion et Systemes Reactifs, Orleans (France)] [Laboratoire de Combustion et Systemes Reactifs, Orleans (France); Platt, U. [Univ. of Heidelberg (Germany)] [Univ. of Heidelberg (Germany)

    1995-03-01T23:59:59.000Z

    The authors make use of measured BrO radical densities, and ClO radical densities inferred from hydrocarbon measurements, made in the arctic troposphere, to calculate ozone depletion rates which would be expected in the spring. These rates compare favorably with field measurements.

  18. An ozone depletion event in the sub-arctic surface layer over Hudson Bay, Canada

    E-Print Network [OSTI]

    Chance, Kelly

    in the ozone destruction has been summarized by Barrie and Platt (1997), Barrie et al. (1998 involving bromine dominate (Le Bras and Platt 1995; Foster et al. 2001; Spicer et al. 2002). The active bromine is considered to ultimately derive from sea salt bromide (Platt and Moortgat 1999

  19. Earth'sFuture Multidecadal global cooling and unprecedented ozone loss

    E-Print Network [OSTI]

    Robock, Alan

    Earth'sFuture Multidecadal global cooling and unprecedented ozone loss following a regional nuclear inertia and albedo effects in the ocean and expanded sea ice. The combined cooling and enhanced UV would put significant pressures on global food supplies and could trigger a global nuclear famine. Knowledge

  20. Substitutes for ozone depleting aerosol electrical contact cleaners and cleaner/lubricants. Technical report

    SciTech Connect (OSTI)

    Bevilacqua, P.; Clark, K.G.

    1996-01-24T23:59:59.000Z

    With the production of Class I Ozone Depleting Substances discontinued as of January 1996, it became necessary to identify suitable replacements for chlorofluorocarbon (CFC-113) and trichloroethane (TCA) based electrical contact cleaners and cleaner/lubricant products. Two hydrochlorofluorocarbon (HCFC-141b) blends were identified as substitutes and recommended for interim use.

  1. Simulated observation of tropospheric ozone and CO with the Tropospheric Emission Spectrometer

    E-Print Network [OSTI]

    Oxford, University of

    , simulated concentrations of ozone and CO from the GEOS- CHEM global three-dimensional (3-D) model the TES orbit track are sampled from the model 3-D time-varying fields with cloudy scenes (50-60% of total briefly from the space shuttle by the Measurement of Air Pollution From Satellites (MAPS) experiment

  2. Interactions of ozone and pathogens on the surface structure of Norway spruce needles

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Interactions of ozone and pathogens on the surface structure of Norway spruce needles K. Ojanperä S and pathogens. It also acts as a barrier to air pollutants (Jeffree, 1986). The epicuticular wax of Norway and then a plate-like wax structure (Sauter and Voss, 1986). The life span of healthy needles of Norway spruce

  3. Kudzu (Pueraria montana) invasion doubles emissions of nitric oxide and increases ozone pollution

    E-Print Network [OSTI]

    Mickley, Loretta J.

    Kudzu (Pueraria montana) invasion doubles emissions of nitric oxide and increases ozone pollution) The nitrogen-fixing legume kudzu (Pueraria montana) is a wide- spread invasive plant in the southeastern United the effects of kudzu invasions on soils and trace N gas emissions at three sites in Madison County, Georgia

  4. Synthesis of nickel–zinc ferrite magnetic nanoparticle and dye degradation using photocatalytic ozonation

    SciTech Connect (OSTI)

    Mahmoodi, Niyaz Mohammad, E-mail: mahmoodi@icrc.ac.ir [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of); Bashiri, Marziyeh; Moeen, Shirin Jebeli [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of)] [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of)

    2012-12-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Nickel–zinc ferrite magnetic nanoparticle (NZFMN) was synthesized and characterized. ? Dye degradation by photocatalytic ozonation using NZFMN was studied. ? Formate, acetate and oxalate were detected as dominant dye degradation aliphatic intermediates. ? Nitrate, sulfate and chloride ions were detected as mineralization products of dyes. ? NZFMN was an effective magnetic nanocatalyst to degrade dyes. -- Abstract: In this paper, nickel–zinc ferrite magnetic nanoparticle (NZFMN) was synthesized and its dye degradation ability using photocatalytic ozonation was investigated. The NZFMN was characterized by X-ray diffraction (XRD), scanning electron microscopic (SEM), Fourier transforms infrared (FTIR) and alternative gradient force magnetometer (AGFM). Reactive Red 198 (RR198) and Direct Green 6 (DG6) were used as dye models. UV–vis and ion chromatography (IC) analyses were employed to study dye degradation. The effects of operational parameters on decolorization such as NZFMN dosage, dye concentration, salt and pH were studied. RR198 and DG6 were completely decolorized (100%) by photocatalytic ozonation using NZFMN. Formate, acetate and oxalate anions were detected as dominant aliphatic intermediates. Nitrate, sulfate and chloride ions were detected as mineralization products of dyes. Results showed that the photocatalytic ozonation using NZFMN was a very effective method for dye degradation.

  5. The Role of Material Porosity on Ozone Uptake for Metakaolin-Concrete Surfaces

    E-Print Network [OSTI]

    Siegel, Jeffrey

    promise for both the reduction of carbon dioxide emissions associated with cement manufacturing and indoor on the concrete specimens. Carbon-filtered room air was conditioned to achieve the desired (1) relative humidity rates were checked using a bubble flow meter (Gilibrator 2, Gilian, Sensidyne, LP) and ozone

  6. Modeling impacts of geomagnetic field variations on middle atmospheric ozone responses to solar proton

    E-Print Network [OSTI]

    Wehrli, Bernhard

    events (SPEs) the flux of high-energy protons from the Sun is markedly increased. In order to investigateModeling impacts of geomagnetic field variations on middle atmospheric ozone responses to solar charged particles of solar and cosmic origin. Therefore variations of the geomagnetic field occurring

  7. Natural ozone scavenger prevents asthma in sensitized rats Ehud Keinan,a,*,

    E-Print Network [OSTI]

    Keinan, Ehud

    in asthma involves a vicious circle of ozone production and recruitment of white blood cells, which pro, could be used for pro- phylactic treatment of asthma. In particular, volatile, unsaturated monoterpenes, and stimulation of neural reflexes and mucus-secreting glands.5 Chronic inflam- mation may result in airway

  8. Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2

    E-Print Network [OSTI]

    Weber, Rodney

    1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 Problem 1: Nighttime loss of NOx in the lower troposphere proceeds by: 1 Air Pollution Physics and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

  9. Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde column measurements

    E-Print Network [OSTI]

    Chance, Kelly

    Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde emission estimates are highly uncertain because of a lack of direct observations. Formaldehyde (HCHO the observation of this trace gas to help constrain isoprene emissions. We use HCHO column observations from

  10. (Limiting the greenhouse effect)

    SciTech Connect (OSTI)

    Rayner, S.

    1991-01-07T23:59:59.000Z

    Traveler attended the Dahlem Research Conference organized by the Freien Universitat, Berlin. The subject of the conference was Limiting the Greenhouse Effect: Options for Controlling Atmospheric CO{sub 2} Accumulation. Like all Dahlem workshops, this was a meeting of scientific experts, although the disciplines represented were broader than usual, ranging across anthropology, economics, international relations, forestry, engineering, and atmospheric chemistry. Participation by scientists from developing countries was limited. The conference was divided into four multidisciplinary working groups. Traveler acted as moderator for Group 3 which examined the question What knowledge is required to tackle the principal social and institutional barriers to reducing CO{sub 2} emissions'' The working rapporteur was Jesse Ausubel of Rockefeller University. Other working groups examined the economic costs, benefits, and technical feasibility of options to reduce emissions per unit of energy service; the options for reducing energy use per unit of GNP; and the significant of linkage between strategies to reduce CO{sub 2} emissions and other goals. Draft reports of the working groups are appended. Overall, the conference identified a number of important research needs in all four areas. It may prove particularly important in bringing the social and institutional research needs relevant to climate change closer to the forefront of the scientific and policy communities than hitherto.

  11. The Limits of Quintessence

    SciTech Connect (OSTI)

    Caldwell, R.R.; Linder, Eric V.

    2005-05-24T23:59:59.000Z

    We present evidence that the simplest particle-physics scalar-field models of dynamical dark energy can be separated into distinct behaviors based on the acceleration or deceleration of the field as it evolves down its potential towards a zero minimum. We show that these models occupy narrow regions in the phase-plane of w and w', the dark energy equation-of-state and its time-derivative in units of the Hubble time. Restricting an energy scale of the dark energy microphysics limits how closely a scalar field can resemble a cosmological constant. These results, indicating a desired measurement resolution of order \\sigma(w')\\approx (1+w), define firm targets for observational tests of the physics of dark energy.

  12. Re-evaluation of total and Umkehr ozone data from NOAA-CMDL Dobson spectrophotometer observatories. Final report

    SciTech Connect (OSTI)

    Komhyr, W.D.; Quincy, D.M.; Grass, R.D.; Koenig, G.L. [Univ. of Colorado, Boulder, CO (United States)] [Univ. of Colorado, Boulder, CO (United States); [National Oceanic and Atmospheric Administration, Boulder, CO (United States). Climate Monitoring and Diagnostics Lab.

    1995-12-01T23:59:59.000Z

    This report describes work to improve the quality of total ozone and Umkehr data obtained in the past at the NOAA Climate Monitoring and Diagnostics Laboratory and the Dobson spectrophotometer ozone observatories. The authors present results of total ozone data re-evaluations for ten stations: Byrd, Antarctica; Fairbanks, Alaska; Hallett, Antarctica; Huancayo, Peru; Haute Provence, France; Lauder, New Zealand; Perth, Australia; Poker Flat, Alaska; Puerto Montt, Chile; and South Pole, Antarctica. The improved data will be submitted in early 1996 to the World Meteorological Organization (WMO) World Ozone Data Center (WODC), and the Atmospheric Environment Service for archiving. Considerable work has been accomplished, also, in reevaluating Umkehr data from seven of the stations, viz., Huancayo, Haute Provence, Lauder, Perth, Poker Flat, Boulder, Colorado; and Mauna Loa, Hawaii.

  13. A Comparative Study of Ozone and Ultraviolet Light/Hydrogen Peroxide for Decolorizing Textile Dyeing Waste Water 

    E-Print Network [OSTI]

    Namboodri, C. G.; Perkins, W. S.; Walsh, W. K.

    1994-01-01T23:59:59.000Z

    Decolorizing textile mill spent dyebath effluents with UV radiation in the presence of hydrogen peroxide (UV/peroxide) and with ozone was investigated. Direct, disperse, and acid dyes with known chemical structures were decolorized. The dyes...

  14. Effects of a modular two-step ozone-water and annealing process on silicon carbide graphene

    SciTech Connect (OSTI)

    Webb, Matthew J., E-mail: matthew.webb@cantab.net; Lundstedt, Anna; Grennberg, Helena [Department of Chemistry—BMC, Uppsala University, Box 576, SE-751 23 Uppsala (Sweden); Polley, Craig; Niu, Yuran; Zakharov, Alexei A.; Balasubramanian, Thiagarajan [MAX IV Laboratory, Lund University, 22100 Lund (Sweden); Dirscherl, Kai [DFM—Danish Fundamental Metrology, Matematiktorvet 307, DK-2800 Lyngby (Denmark); Burwell, Gregory; Guy, Owen J. [College of Engineering, Faraday Tower, Singleton Park, Swansea University, Swansea SA2 8PP (United Kingdom); Palmgren, Pål [VG Scienta Scientific AB, Box 15120, Vallongatan 1, SE-750 15 Uppsala (Sweden); Yakimova, Rositsa [Department of Physics, Chemistry, and Biology, Linköping University, SE-581 83 Linköping (Sweden)

    2014-08-25T23:59:59.000Z

    By combining ozone and water, the effect of exposing epitaxial graphene on silicon carbide to an aggressive wet-chemical process has been evaluated after high temperature annealing in ultra high vacuum. The decomposition of ozone in water produces a number of oxidizing species, however, despite long exposure times to the aqueous-ozone environment, no graphene oxide was observed after the two-step process. The systems were comprehensively characterized before and after processing using Raman spectroscopy, core level photoemission spectroscopy, and angle resolved photoemission spectroscopy together with low energy electron diffraction, low energy electron microscopy, and atomic force microscopy. In spite of the chemical potential of the aqueous-ozone reaction environment, the graphene domains were largely unaffected raising the prospect of employing such simple chemical and annealing protocols to clean or prepare epitaxial graphene surfaces.

  15. Ozone effects on net primary production and carbon sequestration in the conterminous United States using a biogeochemistry model

    E-Print Network [OSTI]

    Felzer, Benjamin Seth.; Kicklighter, David W.; Melillo, Jerry M.; Wang, Chien.; Zhuang, Qianlai.; Prinn, Ronald G.

    The effects of air pollution on vegetation may provide an important control on the carbon cycle that has not yet been widely considered. Prolonged exposure to high levels of ozone, in particular, has been observed to inhibit ...

  16. Past and Future Effects of Ozone on Net Primary Production and Carbon Sequestration Using a Global Biogeochemical Model

    E-Print Network [OSTI]

    Felzer, Benjamin Seth.

    Exposure of plants to ozone inhibits photosynthesis and therefore reduces vegetation production and carbon sequestration. Simulations with the Terrestrial Ecosystem Model (TEM) for the historical period (1860-1995) show ...

  17. Dmitri Babikov (dmitri.babikov@mu.edu; 288-3538) Quantum Origin of Anomalous Isotope Effect in Ozone Formation

    E-Print Network [OSTI]

    Reid, Scott A.

    -Function Analyses of photocatalytic hybrid materials for solar energy conversion James Kincaid Effect in Ozone Formation · Mixed Quantum/Classical Theory for Collisional Energy Transfer: The Intriguing Story of the Iso-Halons Mark Steinmetz (mark

  18. Growth, physiology, and [delta] 13C of loblolly and shortleaf pine as affected by ozone and soil water deficit 

    E-Print Network [OSTI]

    Elsik, Christine Golemboski

    1992-01-01T23:59:59.000Z

    not only vitality of humans, animals, and plants, but also has an economic impact on agriculture and forestry. Air pollution has been shown to reduce agricultural crop and forest productivity. Ozone (0, ), a photochemical oxidant produced by a series.... 4 to 90 days. As an air mass containing 0, and its precursors moves, there is continued addition of pollutants I'rom new sources, so that 0, is continuously being produced and consumed during transport (Heck 1984). EFFECTS OF OZONE ON TREE...

  19. Demonstration of Advanced Technologies for Multi-Load Washers in Hospitality and Healthcare – Ozone Based Laundry Systems

    SciTech Connect (OSTI)

    Boyd, Brian K.; Parker, Graham B.; Petersen, Joseph M.; Sullivan, Greg; Goetzler, W.; Sutherland, T. A.; Foley, K. J.

    2014-08-14T23:59:59.000Z

    The objective of this demonstration project was to evaluate market-ready retrofit technologies for reducing the energy and water use of multi-load washers in healthcare and hospitality facilities. Specifically, this project evaluated laundry wastewater recycling technology in the hospitality sector and ozone laundry technology in both the healthcare and hospitality sectors. This report documents the demonstration of ozone laundry system installations at the Charleston Place Hotel in Charleston, Sout Carolina, and the Rogerson House assisted living facility in Boston, Massachusetts.

  20. Surfactants containing radioactive run-offs: Ozone treatment, influence on nuclear power plants water waste special treatment

    SciTech Connect (OSTI)

    Prokudina, S.A.; Grachok, M.A. [Belarussian State Economic Univ., Minsk (Belarus)

    1993-12-31T23:59:59.000Z

    The authors discuss the problems encountered in the efficiency of radioactive waste treatment in nuclear power plants in Kursk. The ozonization of aqueous solutions of surfactants was carried out in the laboratory`s ozonization system. The surfactants which are discharged to the ion exchangers deteriorate resins, clog up the ion exchangers, and decrease filtration velocity. Therefore, this investigation focused on finding a method to increase the efficiency of this treatment process.

  1. Membrane contactor/separator for an advanced ozone membrane reactor for treatment of recalcitrant organic pollutants in water

    SciTech Connect (OSTI)

    Chan, Wai Kit, E-mail: kekyeung@ust.hk [Department of Chemical and Biomolecular Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Joueet, Justine; Heng, Samuel; Yeung, King Lun [Department of Chemical and Biomolecular Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Schrotter, Jean-Christophe [Water Research Center of Veolia, Anjou Recherche, Chemin de la Digue, BP 76. 78603, Maisons Laffitte, Cedex (France)

    2012-05-15T23:59:59.000Z

    An advanced ozone membrane reactor that synergistically combines membrane distributor for ozone gas, membrane contactor for pollutant adsorption and reaction, and membrane separator for clean water production is described. The membrane reactor represents an order of magnitude improvement over traditional semibatch reactor design and is capable of complete conversion of recalcitrant endocrine disrupting compounds (EDCs) in water at less than three minutes residence time. Coating the membrane contactor with alumina and hydrotalcite (Mg/Al=3) adsorbs and traps the organics in the reaction zone resulting in 30% increase of total organic carbon (TOC) removal. Large surface area coating that diffuses surface charges from adsorbed polar organic molecules is preferred as it reduces membrane polarization that is detrimental to separation. - Graphical abstract: Advanced ozone membrane reactor synergistically combines membrane distributor for ozone, membrane contactor for sorption and reaction and membrane separator for clean water production to achieve an order of magnitude enhancement in treatment performance compared to traditional ozone reactor. Highlights: Black-Right-Pointing-Pointer Novel reactor using membranes for ozone distributor, reaction contactor and water separator. Black-Right-Pointing-Pointer Designed to achieve an order of magnitude enhancement over traditional reactor. Black-Right-Pointing-Pointer Al{sub 2}O{sub 3} and hydrotalcite coatings capture and trap pollutants giving additional 30% TOC removal. Black-Right-Pointing-Pointer High surface area coating prevents polarization and improves membrane separation and life.

  2. COMMENTARY:Limits to adaptation

    SciTech Connect (OSTI)

    Preston, Benjamin L [ORNL

    2013-01-01T23:59:59.000Z

    An actor-centered, risk-based approach to defining limits to social adaptation provides a useful analytic framing for identifying and anticipating these limits and informing debates over society s responses to climate change.

  3. Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

  4. Resonating Valence Bond Quantum Monte Carlo: Application to the ozone molecule

    E-Print Network [OSTI]

    Sam Azadi; Ranber Singh; Thomas D. Kühne

    2015-02-24T23:59:59.000Z

    We study the potential energy surface of the ozone molecule by means of Quantum Monte Carlo simulations based on the resonating valence bond concept. The trial wave function consists of an antisymmetrized geminal power arranged in a single-determinant that is multiplied by a Jastrow correlation factor. Whereas the determinantal part incorporates static correlation effects, the augmented real-space correlation factor accounts for the dynamics electron correlation. The accuracy of this approach is demonstrated by computing the potential energy surface for the ozone molecule in three vibrational states: symmetric, asymmetric and scissoring. We find that the employed wave function provides a detailed description of rather strongly-correlated multi-reference systems, which is in quantitative agreement with experiment.

  5. Resonating Valence Bond Quantum Monte Carlo: Application to the ozone molecule

    E-Print Network [OSTI]

    Azadi, Sam; Kühne, Thomas D

    2015-01-01T23:59:59.000Z

    We study the potential energy surface of the ozone molecule by means of Quantum Monte Carlo simulations based on the resonating valence bond concept. The trial wave function consists of an antisymmetrized geminal power arranged in a single-determinant that is multiplied by a Jastrow correlation factor. Whereas the determinantal part incorporates static correlation effects, the augmented real-space correlation factor accounts for the dynamics electron correlation. The accuracy of this approach is demonstrated by computing the potential energy surface for the ozone molecule in three vibrational states: symmetric, asymmetric and scissoring. We find that the employed wave function provides a detailed description of rather strongly-correlated multi-reference systems, which is in quantitative agreement with experiment.

  6. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L. [Pacific Northwest Lab., Richland, WA (United States); Koss, T.C. [USDOE Assistant Secretary for Environment, Safety, and Health, Washington, DC (United States). Office of Environmental Guidance

    1992-10-01T23:59:59.000Z

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  7. Formation of ozone and oxidation of methane in a direct current corona discharge 

    E-Print Network [OSTI]

    Tangirala, Umashanker

    1976-01-01T23:59:59.000Z

    if they are not deliberately maintained below toxic levels. This kind of air pollution problem is quite different from that of industrial emissions as it calls for the removal of mere traces of contaminant from large volumes of gas. For this purpose, conventional treatment... current corona discharge reactor, over a wide range of experimental conditions. The experi- mental variables were corona current, voltage, reactor radius ratio (Ri/R2), gas flow rate and temperature. Generally, more ozone was produced in the negative...

  8. Past changes in the vertical distribution of ozone – Part 1: Measurement techniques, uncertainties and availability

    E-Print Network [OSTI]

    Hassler, B.; Petropavlovskikh, I.; Staehelin, J.; August, T.; Bhartia, P. K.; Clerbaux, C.; Degenstein, D.; Maziere, M. De; Dinelli, B. M.; Dudhia, A.; Dufour, G.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Granville, J.; Harris, N. R. P.; Hoppel, K.; Hubert, D.; Kasai, Y.; Kurylo, M. J.; Kyrola, E.; Lambert, J.-C.; Levelt, P. F.; McElroy, C. T.; McPeters, R. D.; Munro, R.; Nakajima, H.; Parrish, A.; Raspollini, P.; Remsberg, E. E.; Rosenlof, K. H.; Rozanov, A.; Sano, T.; Sasano, Y.; Shiotani, M.; Smit, H. G. J.; Stiller, G.; Tamminen, J.; Tarasick, D. W.; Urban, J.; van der A, R. J.; Veefkind, J. P.; Vigouroux, C.; von Clarmann, T.; von Savigny, C.; Walker, K. A.; Weber, M.; Wild, J.; Zawodny, J. M.

    2014-05-21T23:59:59.000Z

    , Germany 28Research Institute for Sustainable Humanosphere, Kyoto University, Kyoto, Japan 29Association of International Research Initiatives for Environmental Studies, Tokyo, Japan 30Research Centre Jülich, Institute for Energy and Climate Research... Sciences, Göteborg, Sweden Published by Copernicus Publications on behalf of the European Geosciences Union. 1396 B. Hassler et al.: Ozone profile measurements 34Institut für Physik, Ernst-Moritz-Arndt-Universität Greifswald, Greifswald, Germany 35...

  9. Effects of ozone on the respiratory health, allergic sensitization, and cellular immune system in children

    SciTech Connect (OSTI)

    Zwick, H.; Popp, W.; Wagner, C.; Reiser, K.; Schmoeger, J.B.; Boeck, A.H.; Herkner, K.; Radunsky, K. (Pulmonary Department, Krankenhaus Lainz, Vienna (Austria))

    1991-11-01T23:59:59.000Z

    To investigate the lasting effects of high ozone concentrations under environmental conditions, we examined the respiratory health, pulmonary function, bronchial hyperresponsiveness to methacholine, allergic sensitization, and lymphocyte subpopulations of 10- to 14-yr-old children. A total of 218 children recruited from an area with high ozone concentrations (Group A) were tested against 281 children coming from an area with low ozone concentrations (Group B). As to subjective complaints, categorized as 'usually cough with or without phlegm,' 'breathlessness,' and 'susceptibility to chest colds,' there was no difference between the two groups. The lung function parameters were similar, but in Group A subjects' bronchial hyperresponsiveness occurred more frequently and was found to be more severe than in Group B (29.4 versus 19.9%, p less than 0.02; PD20 2,100 {plus minus} 87 versus 2,350 {plus minus} 58 micrograms, p less than 0.05). In both groups the number of children who had been suffering from allergic diseases and sensitization to aeroallergens, found by means of the skin test, was the same. Comparison of the total IgE levels showed no difference at all between the two groups. As far as the white blood cells are concerned, the total and differential cell count was the same, whereas lymphocyte subpopulations showed readily recognizable changes.

  10. Secondary organic aerosol from ozone-initiated reactions with terpene-rich household products

    SciTech Connect (OSTI)

    Coleman, Beverly; Coleman, Beverly K.; Lunden, Melissa M.; Destaillats, Hugo; Nazaroff, William W.

    2008-01-01T23:59:59.000Z

    We analyzed secondary organic aerosol (SOA) data from a series of small-chamber experiments in which terpene-rich vapors from household products were combined with ozone under conditions analogous to product use indoors. Reagents were introduced into a continuously ventilated 198 L chamber at steady rates. Consistently, at the time of ozone introduction, nucleation occurred exhibiting behavior similar to atmospheric events. The initial nucleation burst and growth was followed by a period in which approximately stable particle levels were established reflecting a balance between new particle formation, condensational growth, and removal by ventilation. Airborne particles were measured with a scanning mobility particle sizer (SMPS, 10 to 400 nm) in every experiment and with an optical particle counter (OPC, 0.1 to 2.0 ?m) in a subset. Parameters for a three-mode lognormal fit to the size distribution at steady state were determined for each experiment. Increasing the supply ozone level increased the steady-state mass concentration and yield of SOA from each product tested. Decreasing the air-exchange rate increased the yield. The steady-state fine-particle mass concentration (PM1.1) ranged from 10 to> 300 mu g m-3 and yields ranged from 5percent to 37percent. Steady-state nucleation rates and SOA mass formation rates were on the order of 10 cm-3 s-1 and 10 mu g m-3 min-1, respectively.

  11. The Transition to Experiencing: I. Limited Learning and Limited Experiencing

    E-Print Network [OSTI]

    Indiana University

    The Transition to Experiencing: I. Limited Learning and Limited Experiencing Simona Ginsburg route for the transition from sensory processing to unlimited experiencing, or basic consciousness. We the transition. We believe that the raw mate- rial from which feelings were molded by natural selection

  12. Limit theory for overfit models

    E-Print Network [OSTI]

    Calhoun, Grayson Ford

    2009-01-01T23:59:59.000Z

    theory. . . . . . . . . . . . . . . . . . . . . . . . .1.2 Asymptotic Theory and Main Results . . . . . . . . .Chapter 2 Limit theory for comparing over?t models out-of-

  13. Low-Temperature Ozone Exposure Technique to Modulate the Stoichiometry of WO(x) Nanorods and Optimize the Electrochromic Performance

    SciTech Connect (OSTI)

    Lin, F.; Li, C. P.; Chen, G.; Tenent, R. C.; Wolden, C. A.; Gillaspie, D. T.; Dillon, A. C.; Richards, R. M.; Engtrakul, C.

    2012-06-29T23:59:59.000Z

    A low-temperature ozone exposure technique was employed for the post-treatment of WO{sub x} nanorod thin films fabricated from hot-wire chemical vapor deposition (HWCVD) and ultrasonic spray deposition (USD) techniques. The resulting films were characterized with x-ray diffraction (XRD), transmission electron microscopy (TEM), Raman spectroscopy, UV-vis-NIR spectroscopy and x-ray photoelectron spectroscopy (XPS). The stoichiometry and surface crystallinity of the WO{sub x} thin films were subsequently modulated upon ozone exposure and thermal annealing without particle growth. The electrochromic performance was studied in a LiClO{sub 4}-propylene carbonate electrolyte, and the results suggest that the low-temperature ozone exposure technique is superior to the traditional high-temperature thermal annealing (employed to more fully oxidize the WO{sub x}). The optical modulation at 670 nm was improved from 35% for the as-deposited film to 57% for the film after ozone exposure at 150 C. The coloration efficiency was improved and the switching speed to the darkened state was significantly accelerated from 18.0 s for the as-deposited film to 11.8 s for the film after the ozone exposure. The process opens an avenue for low-temperature and cost-effective manufacturing of electrochromic films, especially on flexible polymer substrates.

  14. Ozone generation by negative direct current corona discharges in dry air fed coaxial wire-cylinder reactors

    SciTech Connect (OSTI)

    Yehia, Ashraf [Department of Physics, Faculty of Science, Assiut University, Assiut 71516, Egypt and Department of Physics, College of Science and Humanitarian Studies in Alkharj, Salman bin Abdulaziz University, P.O. Box 83, Alkharj 11942 (Saudi Arabia)] [Department of Physics, Faculty of Science, Assiut University, Assiut 71516, Egypt and Department of Physics, College of Science and Humanitarian Studies in Alkharj, Salman bin Abdulaziz University, P.O. Box 83, Alkharj 11942 (Saudi Arabia); Mizuno, Akira [Department of Environmental and Life Sciences, Toyohashi University of Technology, Tempaku-cho, Toyohashi 441-8580 (Japan)] [Department of Environmental and Life Sciences, Toyohashi University of Technology, Tempaku-cho, Toyohashi 441-8580 (Japan)

    2013-05-14T23:59:59.000Z

    An analytical study was made in this paper for calculating the ozone generation by negative dc corona discharges. The corona discharges were formed in a coaxial wire-cylinder reactor. The reactor was fed by dry air flowing with constant rates at atmospheric pressure and room temperature, and stressed by a negative dc voltage. The current-voltage characteristics of the negative dc corona discharges formed inside the reactor were measured in parallel with concentration of the generated ozone under different operating conditions. An empirical equation was derived from the experimental results for calculating the ozone concentration generated inside the reactor. The results, that have been recalculated by using the derived equation, have agreed with the experimental results over the whole range of the investigated parameters, except in the saturation range for the ozone concentration. Therefore, the derived equation represents a suitable criterion for expecting the ozone concentration generated by negative dc corona discharges in dry air fed coaxial wire-cylinder reactors under any operating conditions in range of the investigated parameters.

  15. FUEL CASK IMPACT LIMITER VULNERABILITIES

    SciTech Connect (OSTI)

    Leduc, D; Jeffery England, J; Roy Rothermel, R

    2009-02-09T23:59:59.000Z

    Cylindrical fuel casks often have impact limiters surrounding just the ends of the cask shaft in a typical 'dumbbell' arrangement. The primary purpose of these impact limiters is to absorb energy to reduce loads on the cask structure during impacts associated with a severe accident. Impact limiters are also credited in many packages with protecting closure seals and maintaining lower peak temperatures during fire events. For this credit to be taken in safety analyses, the impact limiter attachment system must be shown to retain the impact limiter following Normal Conditions of Transport (NCT) and Hypothetical Accident Conditions (HAC) impacts. Large casks are often certified by analysis only because of the costs associated with testing. Therefore, some cask impact limiter attachment systems have not been tested in real impacts. A recent structural analysis of the T-3 Spent Fuel Containment Cask found problems with the design of the impact limiter attachment system. Assumptions in the original Safety Analysis for Packaging (SARP) concerning the loading in the attachment bolts were found to be inaccurate in certain drop orientations. This paper documents the lessons learned and their applicability to impact limiter attachment system designs.

  16. Performance Limits for Cherenkov Instruments

    E-Print Network [OSTI]

    W. Hofmann

    2006-03-17T23:59:59.000Z

    The performance of Cherenkov instruments for the detection of very high energy gamma rays is ultimately limited by the fluctuations in the development of air showers. With particular emphasis on the angular resolution, the ultimate performance limits are investigated on the basis of simulations.

  17. Congressional Request Limiting the Magnitude

    E-Print Network [OSTI]

    as goals? Target: limit U.S. GHG emissions (e.g., national emission budget, or percent reduction) What is a reasonable share of U.S. emission reductions relative to the global targets? What is the implied emissions on atmospheric GHG concentrations? Target: limit atmospheric GHG concentrations (e.g., 450, 550 ppm CO2,eq) How

  18. Plastics and elastomers: Ozone degradation. January 1973-December 1989 (A Bibliography from the Rubber and Plastics Research Association data base). Report for January 1973-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-03-01T23:59:59.000Z

    This bibliography contains citations concerning the effects of ozone exposure on various plastics and elastomers. Polyamides, polypropylenes, polyvinyl chlorides, polystyrenes, polyethylenes, and natural and synthetic rubbers are among the plastics and elastomers tested following various concentrations of ozone exposure. Antioxidants, antiozonants, and stabilizers are also mentioned. (This updated bibliography contains 238 citations, 19 of which are new entries to the previous edition.)

  19. Comparison of Aermod and ISCST3 Models for Particulate Emissions from Ground Level Sources 

    E-Print Network [OSTI]

    Botlaguduru, Venkata Sai V.

    2010-07-14T23:59:59.000Z

    Emission factors (EFs) and results from dispersion models are key components in the air pollution regulatory process. The EPA preferred regulatory model changed from ISCST3 to AERMOD in November, 2007. Emission factors are used in conjunction...

  20. Large-Scale Urban Modeling by Combining Ground Level Panoramic and Aerial Imagery

    E-Print Network [OSTI]

    Shahabi, Cyrus

    building or part of a build- ing. Due to error propagation, they are difficult to scale up to model aerial image, we can identify the footprints(up to a common scale) of the buildings, in- cluding of multiple tall buildings. Existing methods for large-scale modeling mostly de- pend on remote sensing

  1. Air dispersion modeling of particulate matter from ground-level area sources 

    E-Print Network [OSTI]

    Meister, Michael Todd

    2000-01-01T23:59:59.000Z

    State Air Pollution Regulatory Agencies (SAPRAs) often use dispersion modeling to predict downwind concentrations of particulate matter (PM) from a facility. As such, a facility may be granted or denied an operating permit ...

  2. Response of atmospheric ground level temperatures to changes in the total solar irradiance

    E-Print Network [OSTI]

    Erlykin, Anatoly

    2015-01-01T23:59:59.000Z

    The attribution of part of global warming to changes in the total solar irradiance (TSI) is an important topic which is not, yet, fully understood. Here, we examine the TSI induced temperature (T) changes on a variety of time scales, from one day to centuries and beyond, using a variety of assumptions. Also considered is the latitude variation of the T-TSI correlations, where it appears that over most of the globe there is a small increase in the sensitivity of temperature to TSI in time. It is found that the mean global sensitivity (alpha)measured in K(Wm-2)-1 varies from about 0.003 for 1 day, via 0.05 for 11-years to about 0.2 for decades to centuries. We conclude that mean global temperature changes related to TSI are not significant from 1975 onwards. Before 1975, when anthropogenic gases were less important, many of the temperature changes can be attributed to TSI variations. Over much longer periods of time, from Kyear to Myear, the TSI changes are more efficient still, the sensitivity alpha increasing...

  3. Comparison of Aermod and ISCST3 Models for Particulate Emissions from Ground Level Sources

    E-Print Network [OSTI]

    Botlaguduru, Venkata Sai V.

    2010-07-14T23:59:59.000Z

    setup parameters .................................................................................. 32 Figure 6. Cattle feedlot with a TEOM sampler .............................................................. 35 Figure 7. Wind rose for feedlot E... when solar radiation > 800 W/m2 .................................................................... 54 Figure 20. Variance in AERMOD and ISCST3 concentrations as a function of wind speed...

  4. Detection of the 6 November 1997 Ground Level Event by Abe D. Falcone, for Milagro Collaboration

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Collaboration University of New Hampshire, Space Science Center, Morse Hall, Durham, NH 03824 USA Abstract. Solar Energetic Particles (SEPs) with energies exceeding 10 GeV associated with the 6 November 1997 for observing very high energy gamma ray sources, can also be used to study the Sun. Milagrito, which operated

  5. Detection of 6 November 1997 Ground Level Event by for Milagro collaboration

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    collaboration 1 Space Science Center, University of New Hampshire, Durham, NH 03824 USA Abstract Solar Energetic Particles from the 6 November 1997 solar flare/CME(coronal mass ejection) with energies exceeding 10 GeV. The Milagro observatory, a ground based water Cherenkov detector designed for observing very high energy gamma

  6. Characterization of ammonia emissions from ground level area sources at central texas dairies

    E-Print Network [OSTI]

    Mutlu, Atilla

    2009-05-15T23:59:59.000Z

    ) to potentially develop source specific NH3 emission control strategies. The GLAS including open-lots, free-stall barns, separated solids, primary and secondary lagoons and milking parlor were sampled to estimate NH3 emissions. In the first study, assessment...

  7. Nitrogen management is essential to prevent tropical oil palm plantations from causing ground-level

    E-Print Network [OSTI]

    on the assumption that palm oil is an ``environmentally friendly'' fuel feedstock. Here we show, using measurementsNitrogen management is essential to prevent tropical oil palm plantations from causing ground the Industrial Revolution. Among the most widespread trop- ical crops is oil palm (Elaeis guineensis): global

  8. Air dispersion modeling of particulate matter from ground-level area sources

    E-Print Network [OSTI]

    Meister, Michael Todd

    2000-01-01T23:59:59.000Z

    obtained from a dispersion model. The model currently approved by EPA, the Industrial Source Complex, Version 3 - Short Term (ISC3-ST), over-predicts downwind concentrations of PM by as much two orders of magnitude. As a result, a facility may be denied a...

  9. Afghanistan Wind Power Density at 50-m Above Ground Level GIS Data -

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat 1AMEE JumpAeroWind Inc.

  10. GROUND LEVEL INVESTIGATION OF ANOMALOUS RADIATION LEVELS IN NIAGARA FALLS, NEW YORK

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling CorpNewCF INDUSTRIES,L? . -. .- *' * ..+GROUND

  11. Predicting tropospheric ozone and hydroxyl radical in a global, three-dimensional, chemistry, transport, and deposition model

    SciTech Connect (OSTI)

    Atherton, C.S.

    1995-01-05T23:59:59.000Z

    Two of the most important chemically reactive tropospheric gases are ozone (O{sub 3}) and the hydroxyl radical (OH). Although ozone in the stratosphere is a necessary protector against the sun`s radiation, tropospheric ozone is actually a pollutant which damages materials and vegetation, acts as a respiratory irritant, and is a greenhouse gas. One of the two main sources of ozone in the troposphere is photochemical production. The photochemistry is initiated when hydrocarbons and carbon monoxide (CO) react with nitrogen oxides (NO{sub x} = NO + NO{sub 2}) in the presence of sunlight. Reaction with the hydroxyl radical, OH, is the main sink for many tropospheric gases. The hydroxyl radical is highly reactive and has a lifetime on the order of seconds. Its formation is initiated by the photolysis of tropospheric ozone. Tropospheric chemistry involves a complex, non-linear set of chemical reactions between atmospheric species that vary substantially in time and space. To model these and other species on a global scale requires the use of a global, three-dimensional chemistry, transport, and deposition (CTD) model. In this work, I developed two such three dimensional CTD models. The first model incorporated the chemistry necessary to model tropospheric ozone production from the reactions of nitrogen oxides with carbon monoxide (CO) and methane (CH{sub 4}). The second also included longer-lived alkane species and the biogenic hydrocarbon isoprene, which is emitted by growing plants and trees. The models` ability to predict a number of key variables (including the concentration of O{sub 3}, OH, and other species) were evaluated. Then, several scenarios were simulated to understand the change in the chemistry of the troposphere since preindustrial times and the role of anthropogenic NO{sub x} on present day conditions.

  12. Effects of ambient ozone on respiratory function and symptoms in Mexico City schoolchildren

    SciTech Connect (OSTI)

    Castillejos, M.; Gold, D.R.; Dockery, D.; Tosteson, T.; Baum, T.; Speizer, F.E. (Universidad Autonoma Metropolitana-X, Mexico City, (Mexico))

    1992-02-01T23:59:59.000Z

    The effects of ambient ozone (O3) on respiratory function and acute respiratory symptoms were evaluated in 143 7- to 9-yr-old schoolchildren followed longitudinally at 1- to 2-wk intervals over a period of 6 months at three schools in Pedregal, Mexico City. The maximum O3 level exceeded the World Health Organization guideline of 80 ppb and the U.S. standard of 120 ppb in every week. For an increase from lowest to highest in the mean O3 level during the 48 hr before spirometry (53 ppb), logistic regression estimated relative odds of 1.7 for a child reporting cough/phlegm on the day of spirometry. For the full population, the mean O3 level during the hour before spirometry, not adjusted for temperature and humidity, predicted a significant decrement in FVC but not in FEV1 or FEF25-75. In contrast, the mean O3 level during the previous 24-, 48-, and 168-h periods predicted significant decrements in FEV1 and FEF25-75 but not in FVC. Ozone was consistently associated with a greater decrement in lung function for the 15 children with chronic phlegm as compared with the children without chronic cough, chronic phlegm, or wheeze. Ozone in the previous 24-, 48-, and 168-h periods predicted decrements in FEV1 for children of mothers who were current or former smokers, but not for children of mothers who were never smokers. Many of these effects were reduced in multiple regression analyses including temperature and humidity, as temperature and O3 were highly correlated.

  13. Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region

    SciTech Connect (OSTI)

    Steiner, A. L.; Tawfik, A. B.; Shalaby, A.; Zakey, A. S.; Abdel Wahab, M. M.; Salah, Z.; Solmon, F.; Sillman, S.; Zaveri, Rahul A.

    2014-04-16T23:59:59.000Z

    An integrated chemistry-climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on Greater Cairo (GC) region. The densley populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjuction with natural sources such as dust and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average-ground-based NO2 observations of 40-60 ppb are substantially higher than modeled estimates (5-10 ppb), likely due to model grid resolution, improper boundary layer representation, and poor emissions inventories. Observed ozone concentrations range from 35 ppb (winter) to 80 ppb (summer). The model reproduces the seasonal cycle fairly well, but modeled summer ozone is understimated by approximately 15 ppb and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry-climate model captures the springtime peak aerosol optical depth (AOD) of 0.7-1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta, yet the model underestimates this fall observed AOD peak, as standard emissions inventories underestimate this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities are needed to improve air quality simulations in this region.

  14. Carbonyl products of the gas phase reaction of ozone with symmetrical alkenes

    SciTech Connect (OSTI)

    Grosjean, E.; Grosjean, D. [DGA, Inc., Ventura, CA (United States)] [DGA, Inc., Ventura, CA (United States)

    1996-06-01T23:59:59.000Z

    In this study, carbonyl products have been identified and their yields measured in experiments involving the gas phase reaction of ozone with the eight symmetrical alkenes ethylene, cis-3-hexene, cis-4-octene, trans-4-octene, cis-5-decene, trans-5-decene, trans-2, 5-dimethyl-3-hexene, and (cis+trans)-3,4-dimethyl-3-hexene in purified air. Sufficient cyclohexane was added to scavenge the hydroxyl radical (OH) in order to minimize the reaction of OH with the alkenes and with their carbonyl products. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with simple reaction mechanism. Carbonyls other than the primary carbonyls R{sub 1}COR{sub 2} were identified as products. Their formation is discussed in terms of subsequent reactions of the R{sub 1}R{sub 2}COO biradicals CH{sub 3}CH{sub 2}CHOO, CH{sub 3}(CH{sub 2}){sub 2}CHOO, CH{sub 3}(CH{sub 2}){sub 3}CHOO, (CH{sub 3}){sub 2}CHCHOO, and C{sub 2}H{sub 5}C(CH{sub 3})OO. Similarities and differences are discussed for cis and trans isomers and for biradical reactions as a function of the nature and number of the substituents. The results are compared to those for the biradicals H{sub 2}COO, CH{sub 3}CHOO, and (CH{sub 3}){sub 2}COO from simpler symmetrical alkenes and contribute to a better understanding of the ozone-alkene reaction under atmospheric conditions. 51 refs., 1 fig., 3 tabs.

  15. Lagrangian methods for climatological analysis of regional atmospheric transport with an emphasis on Texas ozone exceedances

    E-Print Network [OSTI]

    Dexheimer, Darielle Nicole

    2004-11-15T23:59:59.000Z

    . ............ 43 19 48-hour backward trajectory for Event 2. Ozone values for 1998-08- 15?1998-08-17 are also shown. ...................... 45 20 Geopotential height in m at 1000 hPa on 1998-08-16 at 18Z and a plot of surface weather on 1998-08-17 at 0Z provided....1) for all possible delta-function initial conditions (all x0), that is, partialdiffG partialdifft +v ?nablaG =0,G(x, x0,t0)=delta(x -x0). (3.2) The principal advantage of this solution technique is that, if G can be found, the solution to (3...

  16. Highly reproducible and reliable metal/graphene contact by ultraviolet-ozone treatment

    SciTech Connect (OSTI)

    Li, Wei [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China); Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Hacker, Christina A.; Cheng, Guangjun; Hight Walker, A. R.; Richter, Curt A.; Gundlach, David J., E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn [Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Liang, Yiran; Tian, Boyuan; Liang, Xuelei, E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn; Peng, Lianmao [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China)

    2014-03-21T23:59:59.000Z

    Resist residue from the device fabrication process is a significant source of contamination at the metal/graphene contact interface. Ultraviolet Ozone (UVO) treatment is proven here, by X-ray photoelectron spectroscopy and Raman measurement, to be an effective way of cleaning the metal/graphene interface. Electrical measurements of devices that were fabricated by using UVO treatment of the metal/graphene contact region show that stable and reproducible low resistance metal/graphene contacts are obtained and the electrical properties of the graphene channel remain unaffected.

  17. Passive fault current limiting device

    DOE Patents [OSTI]

    Evans, Daniel J. (Wheeling, IL); Cha, Yung S. (Darien, IL)

    1999-01-01T23:59:59.000Z

    A passive current limiting device and isolator is particularly adapted for use at high power levels for limiting excessive currents in a circuit in a fault condition such as an electrical short. The current limiting device comprises a magnetic core wound with two magnetically opposed, parallel connected coils of copper, a high temperature superconductor or other electrically conducting material, and a fault element connected in series with one of the coils. Under normal operating conditions, the magnetic flux density produced by the two coils cancel each other. Under a fault condition, the fault element is triggered to cause an imbalance in the magnetic flux density between the two coils which results in an increase in the impedance in the coils. While the fault element may be a separate current limiter, switch, fuse, bimetal strip or the like, it preferably is a superconductor current limiter conducting one-half of the current load compared to the same limiter wired to carry the total current of the circuit. The major voltage during a fault condition is in the coils wound on the common core in a preferred embodiment.

  18. Passive fault current limiting device

    DOE Patents [OSTI]

    Evans, D.J.; Cha, Y.S.

    1999-04-06T23:59:59.000Z

    A passive current limiting device and isolator is particularly adapted for use at high power levels for limiting excessive currents in a circuit in a fault condition such as an electrical short. The current limiting device comprises a magnetic core wound with two magnetically opposed, parallel connected coils of copper, a high temperature superconductor or other electrically conducting material, and a fault element connected in series with one of the coils. Under normal operating conditions, the magnetic flux density produced by the two coils cancel each other. Under a fault condition, the fault element is triggered to cause an imbalance in the magnetic flux density between the two coils which results in an increase in the impedance in the coils. While the fault element may be a separate current limiter, switch, fuse, bimetal strip or the like, it preferably is a superconductor current limiter conducting one-half of the current load compared to the same limiter wired to carry the total current of the circuit. The major voltage during a fault condition is in the coils wound on the common core in a preferred embodiment. 6 figs.

  19. Terrestrial Ozone Depletion Due to a Milky Way Gamma-Ray Burst

    E-Print Network [OSTI]

    Brian C. Thomas; Charles H. Jackman; Adrian L. Melott; Claude M. Laird; Richard S. Stolarski; Neil Gehrels; John K. Cannizzo; Daniel P. Hogan

    2005-02-10T23:59:59.000Z

    Based on cosmological rates, it is probable that at least once in the last Gy the Earth has been irradiated by a gamma-ray burst in our Galaxy from within 2 kpc. Using a two-dimensional atmospheric model we have performed the first computation of the effects upon the Earth's atmosphere of one such impulsive event. A ten second burst delivering 100 kJ/m^2 to the Earth penetrates to the stratosphere and results in globally averaged ozone depletion of 35%, with depletion reaching 55% at some latitudes. Significant global depletion persists for over 5 years after the burst. This depletion would have dramatic implications for life since a 50% decrease in ozone column density results in approximately three times the normal UVB flux. Widespread extinctions are likely, based on extrapolation from UVB sensitivity of modern organisms. Additional effects include a shot of nitrate fertilizer and NO2 opacity in the visible providing a cooling perturbation to the climate over a similar timescale. These results lend support to the hypothesis that a GRB may have initiated the late Ordovician mass extinction (Melott et al. 2004).

  20. Isotope separation of {sup 17}O by photodissociation of ozone with near-infrared laser irradiation

    SciTech Connect (OSTI)

    Hayashida, Shigeru; Kambe, Takashi; Sato, Tetsuya; Igarashi, Takehiro [Tsukuba Laboratories, Taiyo Nippon Sanso Corporation, 10 Okubo Tsukuba-shi, Ibaraki 300-2611 (Japan); Kuze, Hiroaki [Center for Environmental Remote Sensing, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba, 263-8522 (Japan)

    2012-04-01T23:59:59.000Z

    Oxygen-17 is a stable oxygen isotope useful for various diagnostics in both engineering and medical applications. Enrichment of {sup 17}O, however, has been very costly due to the lack of appropriate methods that enable efficient production of {sup 17}O on an industrial level. In this paper, we report the first {sup 17}O-selective photodissociation of ozone at a relatively high pressure, which has been achieved by irradiating a gas mixture of 10 vol% O{sub 3}-90 vol% CF{sub 4} with narrowband laser. The experiment was conducted on a pilot-plant scale. A total laser power of 1.6 W was generated by external-cavity diode lasers with all the laser wavelengths fixed at the peak of an absorption line of {sup 16}O{sup 16}O{sup 17}O around 1 {mu}m. The beams were introduced into a 25 -m long photoreaction cell under the sealed-off condition with a total pressure of 20 kPa. Lower cell temperature reduced the background decomposition of ozone, and at the temperature of 158 K, an {sup 17}O enrichment factor of 2.2 was attained.

  1. Page 1 of 14 UNSW Foundation Limited

    E-Print Network [OSTI]

    New South Wales, University of

    , Coca-Cola Amatil Limited and Ingeus Limited. David is Chairman of the National E-Health Transition

  2. GEOPHYSICAL RESEARCH LETTERS, VOL. 27, NO. 21, PAGES 3465-3468, NOVEMBER 1, 2000 Increasing background ozone in surface air

    E-Print Network [OSTI]

    Lin, C.-Y. Cynthia

    that an important consideration for pollution control strategies is the O3 back- ground present in surface air over background ozone in surface air over the United States C.-Y. Cynthia Lin, Daniel J. Jacob, J. William Munger in surface air over the United States from 1980 to 1998 is examined using monthly probability distributions

  3. The effects of ethylenediurea and sodium erythorbate on photosynthetic function of ozone-exposed loblolly pine seedlings 

    E-Print Network [OSTI]

    Kuehler, Eric Anthony

    1995-01-01T23:59:59.000Z

    In separate experiments, ozone-sensitive loblolly pine (Pinus taeda L.) seedlings were treated with either 0 ppm, 150 ppm or 300 ppm ethylenediurea (EDU) or 0 ppm, 1030 ppm, or 2060 ppm Ozoban every 14 days. The seedlings were grown in open...

  4. COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls

    E-Print Network [OSTI]

    Zare, Richard N.

    COMBUSTION AND FLAME 24, 27-34 (1975) 27 Flame Emission Studies of Ozone with Metal Alkyls: Zn (CH3 of combustion. Premixed [2, 3] anddiffusion [4] flames of metal alkyl compounds have been carried out to deter- tageous to study the combustion of polyatomic molecules under single-collision conditions, i

  5. Plasma Chemistry and Plasma Processing, Vol. 23, No. 3, September 2003 ( 2003) Ozone Production in the Negative DC Corona

    E-Print Network [OSTI]

    Chen, Junhong

    Plasma Chemistry and Plasma Processing, Vol. 23, No. 3, September 2003 ( 2003) Ozone Production to the effect of discharge polarity on the number of energetic electrons in the corona plasma. The number of electrons is one order of magnitude greater and the chemically reactiûe plasma region extends beyond

  6. An evaluation of infrared microwindows for ozone retrievals using the Eureka Bruker 125HR Fourier transform spectrometer

    E-Print Network [OSTI]

    Strong, Kimberly

    made in the laboratory in 1839 by Sch¨onbein [1,2]. It is well known as an important component of our atmo- sphere, as it strongly absorbs solar ultraviolet (UV) radiation. Total ozone column measurementsDirect journal homepage: www.elsevier.com/locate/jqsrt Journal of Quantitative Spectroscopy & Radiative Transfer

  7. Dmitri Babikov (dmitri.babikov@mu.edu; 288-3538) Quantum Origin of Anomalous Isotope Effect in Ozone Formation

    E-Print Network [OSTI]

    Reid, Scott A.

    of photocatalytic hybrid materials for solar energy conversion James Kincaid (james.kincaid@mu.edu; 288 in Ozone Formation Mixed Quantum/Classical Theory for Collisional Energy Transfer Computational Study-Halons Mark Steinmetz (mark.steinmetz@mu.edu; 288-3535) Photochemically Removable Protecting Groups Qadir

  8. Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3]) have the poten-

    E-Print Network [OSTI]

    Summary Elevated concentrations of atmospheric carbon dioxide ([CO2]) and tropospheric ozone ([O3 gases (greenhouse gases) altered by human activities (IPCC 2007), only carbon dioxide (CO2 vegeta- tion properties affect local and regional climate, as well as how atmospheric forcing

  9. The effects of ethylenediurea and sodium erythorbate on photosynthetic function of ozone-exposed loblolly pine seedlings

    E-Print Network [OSTI]

    Kuehler, Eric Anthony

    1995-01-01T23:59:59.000Z

    -top chambers in east Texas for one growing season beginning in April 1994 while being exposed to either sub-ambient (CF), approximate ambient (NF), 1.5Y,, 2.OX, or 2.5X ambient ozone levels. Net photosynthesis (A), stomatal conductance (g), and chloroplast...

  10. Scattering resonances as viscosity limits

    E-Print Network [OSTI]

    Maciej Zworski

    2015-05-04T23:59:59.000Z

    Using the method of complex scaling we show that scattering resonances of $ - \\Delta + V $, $ V \\in L^\\infty_{\\rm{c}} ( \\mathbb R^n ) $, are limits of eigenvalues of $ - \\Delta + V - i \\epsilon x^2 $ as $ \\epsilon \\to 0+ $. That justifies a method proposed in computational chemistry and reflects a general principle for resonances in other settings.

  11. GEOFIZIKA VOL. 30 2013 Original scientific paper

    E-Print Network [OSTI]

    Fernandez, Thomas

    , in final form 11 March 2013 ground-level ozone (O3) has been a serious air pollution problem for several. SAMADIANFARD ET AL.: COMPARATIVE ANALYSIS OF OzONE LEVEL PREDICTION ... by air pollution. As one of major among pollutants because it is not emitted directly into the air. This is the main reason why ozone

  12. Summary of Dissolved Concentration Limits

    SciTech Connect (OSTI)

    Yueting Chen

    2001-06-11T23:59:59.000Z

    According to the Technical Work Plan titled Technical Work Plan for Waste Form Degradation Process Model Report for SR (CRWMS M&O 2000a), the purpose of this study is to perform abstractions on solubility limits of radioactive elements based on the process-level information and thermodynamic databases provided by Natural Environment Program Operations (NEPO) and Waste Package Operations (WPO). The scope of this analysis is to produce solubility limits as functions, distributions, or constants for all transported radioactive elements identified by the Performance Assessment Operations (PAO) radioisotope screening. Results from an expert elicitation for solubility limits of most radioactive elements were used in the previous Total System Performance Assessments (TSPAs). However, the elicitation conducted in 1993 does not meet the criteria set forth by the U.S. Nuclear Regulatory Commission (NRC) due to lack of documentation and traceability (Kotra et al. 1996, Section 3). Therefore, at the Waste Form Abstraction Workshop held on February 2-4, 1999, at Albuquerque, New Mexico, the Yucca Mountain Site Characterization Project (YMP) decided to develop geochemical models to study solubility for the proposed Monitored Geologic Repository. WPO/NEPO is to develop process-level solubility models, including review and compilation of relevant thermodynamic data. PAO's responsibility is to perform abstractions based on the process models and chemical conditions and to produce solubility distributions or response surfaces applicable to the proposed repository. The results of this analysis and conceptual model will feed the performance assessment for Total System Performance Assessment--Site Recommendation (TSPA-SR) and Total System Performance Assessment--License Application (TSPA-LA), and to the Waste Form Degradation Process Model Report section on concentration limits.

  13. Fundamental Limits to Cellular Sensing

    E-Print Network [OSTI]

    Pieter Rein ten Wolde; Nils B. Becker; Thomas E. Ouldridge; A. Mugler

    2015-05-25T23:59:59.000Z

    In recent years experiments have demonstrated that living cells can measure low chemical concentrations with high precision, and much progress has been made in understanding what sets the fundamental limit to the precision of chemical sensing. Chemical concentration measurements start with the binding of ligand molecules to receptor proteins, which is an inherently noisy process, especially at low concentrations. The signaling networks that transmit the information on the ligand concentration from the receptors into the cell have to filter this noise extrinsic to the cell as much as possible. These networks, however, are also stochastic in nature, which means that they will also add noise to the transmitted signal. In this review, we will first discuss how the diffusive transport and binding of ligand to the receptor sets the receptor correlation time, and then how downstream signaling pathways integrate the noise in the receptor state; we will discuss how the number of receptors, the receptor correlation time, and the effective integration time together set a fundamental limit on the precision of sensing. We then discuss how cells can remove the receptor noise while simultaneously suppressing the intrinsic noise in the signaling network. We describe why this mechanism of time integration requires three classes of resources---receptors and their integration time, readout molecules, energy---and how each resource class sets a fundamental sensing limit. We also briefly discuss the scheme of maximum-likelihood estimation, the role of receptor cooperativity, and how cellular copy protocols differ from canonical copy protocols typically considered in the computational literature, explaining why cellular sensing systems can never reach the Landauer limit on the optimal trade-off between accuracy and energetic cost.

  14. ARM - Ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat fluxChinaNews : AMFAlaskaNewsOxides of

  15. Waste tank characterization sampling limits

    SciTech Connect (OSTI)

    Tusler, L.A.

    1994-09-02T23:59:59.000Z

    This document is a result of the Plant Implementation Team Investigation into delayed reporting of the exotherm in Tank 241-T-111 waste samples. The corrective actions identified are to have immediate notification of appropriate Tank Farm Operations Shift Management if analyses with potential safety impact exceed established levels. A procedure, WHC-IP-0842 Section 12.18, ``TWRS Approved Sampling and Data Analysis by Designated Laboratories`` (WHC 1994), has been established to require all tank waste sampling (including core, auger and supernate) and tank vapor samples be performed using this document. This document establishes levels for specified analysis that require notification of the appropriate shift manager. The following categories provide numerical values for analysis that may indicate that a tank is either outside the operating specification or should be evaluated for inclusion on a Watch List. The information given is intended to translate an operating limit such as heat load, expressed in Btu/hour, to an analysis related limit, in this case cesium-137 and strontium-90 concentrations. By using the values provided as safety flags, the analytical laboratory personnel can notify a shift manager that a tank is in potential violation of an operating limit or that a tank should be considered for inclusion on a Watch List. The shift manager can then take appropriate interim measures until a final determination is made by engineering personnel.

  16. [Frontiers in Bioscience, 5, a10-17, May 1, 2000] UV-OZONE ASHING OF CELLS AND TISSUES FOR SPATIALLY RESOLVED TRACE ELEMENT ANALYSIS

    E-Print Network [OSTI]

    Gilbert, Pupa Gelsomina De Stasio

    TABLE OF CONTENTS 1. Abstract 2. Introduction 3. Materials and methods 3.1. UV/ozone oven 3.2. Total Organic Carbon (TOC) analysis 3.3. Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES) 3

  17. The signature of ozone depletion on tropical temperature trends, as revealed by their seasonal cycle in model integrations with single forcings

    E-Print Network [OSTI]

    Polvani, Lorenzo M.

    [1] The effect of ozone depletion on temperature trends in the tropical lower stratosphere is explored with an atmospheric general circulation model, and directly contrasted to the effect of increased greenhouse gases and ...

  18. A cost-effectiveness analysis of alternative ozone control strategies : flexible nitrogen oxide (NOx) abatement from power plants in the eastern United States

    E-Print Network [OSTI]

    Sun, Lin, S.M. Massachusetts Institute of Technology

    2009-01-01T23:59:59.000Z

    Ozone formation is a complex, non-linear process that depends on the atmospheric concentrations of its precursors, nitrogen oxide (NOx) and Volatile Organic Compounds (VOC), as well as on temperature and the available ...

  19. Effects of ozone exposure on 'Golden' papaya fruit by photoacoustic phase-resolved method: Physiological changes associated with carbon dioxide and ethylene emission rates during ripening

    SciTech Connect (OSTI)

    Correa, Savio Figueira; Brito Paiva, Luisa; Mota do Couto, Flavio; Gomes da Silva, Marcelo; Silva Sthel, Marcelo; Vargas, Helion [Laboratorio de Ciencias Fisicas, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Avenida Alberto Lamego 2000, Parque California 28013-602, Campos dos Goytacazes, Rio de Janeiro (Brazil); Mota, Leonardo [Laboratorio de Ciencias Fisicas, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Avenida Alberto Lamego 2000, Parque California 28013-602, Campos dos Goytacazes, Rio de Janeiro (Brazil); Fraunhofer Institut fuer Bauphysik, Nobelstrasse 12, Vaihingen 70569, Stuttgart, Baden Wuerttemberg (Germany); Goncalves de Oliveira, Jurandi [Laboratorio de Melhoramento Genetico Vegetal, Universidade Estadual do Norte Fluminense Darcy Ribeiro, Avenida Alberto Lamego 2000, Parque California 28013-602, Campos dos Goytacazes, Rio de Janeiro (Brazil); Miklos, Andras [Fraunhofer Institut fuer Bauphysik, Nobelstrasse 12, Vaihingen 70569, Stuttgart, Baden Wuerttemberg (Germany)

    2011-06-01T23:59:59.000Z

    This work addresses the effects of ozone activity on the physiology of 'Golden' papaya fruit. Depth profile analysis of double-layer biological samples was accomplished using the phase-resolved photoacoustic spectroscopy. The feasibility of the method was demonstrated by singling out the spectra of the cuticle and the pigment layers of papaya fruit. The same approach was used to monitor changes occurring on the fruit during ripening when exposed to ozone. In addition, one has performed real time studies of fluorescence parameters and the emission rates of carbon dioxide and ethylene. Finally, the amount of pigments and the changes in waxy cuticle have been monitored. Results indicate that a fruit deliberately subjected to ozone at a level of 6 ppmv underwent ripening sooner (at least 24-48 h) than a fruit stored at ambient conditions. Moreover, ozone caused a reduction in the maximum quantum yield of photosynthetic apparatus located within the skin of papaya fruit.

  20. Quantifying foliar responses of white ash to ozone and simulated acid precipitation: An assessment proposal for forest exposure studies. Forest Service research paper. (Final)

    SciTech Connect (OSTI)

    Dochinger, L.S.; Jensen, K.F.

    1990-04-01T23:59:59.000Z

    Seedlings populations represent an important linkage for assessing the effect of air pollution on forests. The study examines the foliar responses of white ash seedlings to ozone and acid precipitation as a means of identifying atmospheric deposition effects on forests.

  1. Gradient limits and SCRF performance.

    SciTech Connect (OSTI)

    Norem, J.; Pellin, M.

    2007-01-01T23:59:59.000Z

    Superconducting rf gradients are limited by a number of mechanisms, among them are field emission, multipactor, Lorentz detuning, global and local heating, quench fields, Q-Slope, assembly defects, and overall power use. We describe how each of these mechanisms interacts with the cavity fields and show how significant improvements may be possible assuming improvements in control over the cavity surface. New techniques such as Atomic Layer Deposition (ALD), the use of layered composites, Gas Cluster Ion Beam (GCIB) smoothing and Dry Ice Cleaning (DIC) have been proposed as ways to control the surface.

  2. Dose Limits | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,Office of Policy,Policy ActDetroit7471 FederalDonna Friend Donna FriendLimits

  3. Ablamp Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDIT REPORT Americium/Curium Vitrification4th DayANVAblamp Limited Jump

  4. Novacem Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |JilinLuOpenNorth AmericaNorthwest Rural PubNova AlincaNovacem Limited

  5. Bioethanol Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,Belcher HomesLyons Biomass FacilityBioethanol Limited

  6. Lysanda Limited | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |JilinLu an Group Jump to: navigation,LushuiLyme, NewLyonLysanda Limited

  7. Improved mechanical properties and ozone resistance of radiation-cured SBR. Final report, Dec 88-Jun 91. [Styrene Butadiene Rubber

    SciTech Connect (OSTI)

    Basfar, A.A.; Silverman, J.

    1991-08-01T23:59:59.000Z

    This report is a continuation and extension of the work of the earlier Army contract, where the superiority of the electron beam cured styrene butadiene rubber (SBR) tank pads to the sulfur cured pads was demonstrated. The focus of the present study is the investigation of the extraordinary ozone resistance of our radiation cured SBR, and also on possible alternatives for SBR, butadiene rubber (BR) in particular, as a tank pad compound. Base formulations of a fully sulfur cured system were established with 5% reproducibility, and results were confirmed by mechanical properties measurements on identical formulations from Belvoir Research Development and Engineering Center (BRDEC). Constant mechanical properties as a function of exposure to ozone indicate either competitive cross-linking and scissioning reactions or a 'protective' effect caused by higher terminal vinyl concentrations in the radiation cured formulations.

  8. Potential of Ozone Formation by the Smog Mechanism to shield the surface of the Early Earth from UV radiation?

    E-Print Network [OSTI]

    John Lee Grenfell; Barbara Stracke; Beate Patzer; Ruth Titz; Heike Rauer

    2006-09-08T23:59:59.000Z

    We propose that the photochemical smog mechanism produced substantial ozone (O3) in the troposphere during the Proterozoic, which contributed to ultraviolet (UV) radiation shielding hence favoured the establishment of life. The smog mechanism is well-established and is associated with pollution hazes which sometimes cover modern cities. The mechanism proceeds via the oxidation of volatile organic compounds (VOCs) such as methane (CH4) in the presence of UV radiation and nitrogen oxides (NOx). It would have been particularly favoured during the Proterozoic given the high levels of CH4 (up to 1000 ppm) recently suggested. Proterozoic UV levels on the surface of the Earth were generally higher compared with today, which would also have favoured the mechanism. On the other hand, Proterozoic O2 required in the final step of the smog mechanism to form O3 was less abundant compared with present times. Further, results are sensitive to Proterozoic NOx concentrations, which are challenging to predict, since they depend on uncertain quantities such as NOx source emissions and OH concentrations. We review NOx sources during the Proterozoic and apply a photochemical box model having methane oxidation with NOx, HOx and Ox chemistry to estimate the O3 production from the smog mechanism. Runs suggest the smog mechanism during the Proterozoic can produce about double present day ozone columns for NOx levels of 1.53 10-9 by volume mixing ratio, which was attainable according to our NOx source analysis, with 1 per-cent present atmospheric levels (PALs) of O2. Clearly, forming ozone in the troposphere is a trade-off for survivability. On the one hand harmful UV is blocked, but on the other hand ozone is a respiratory irratant, which becomes fatal at concentrations exceeding about 1 ppmv.

  9. Growth, physiology, and [delta] 13C of loblolly and shortleaf pine as affected by ozone and soil water deficit

    E-Print Network [OSTI]

    Elsik, Christine Golemboski

    1992-01-01T23:59:59.000Z

    44 48 CHAPTER Page VI STABLE CARBON ISOTOPE COMPOSITION AND LEAF INTERNAL CARBON DIOXIDE CONCENTRATION OF LOBLOLLY AND SHORTLEAF PINE AS AFFECTED BY OZONE AND WATER STRESS Introduction Experimental Methods Results . Discussion Summary..., ) and two water regimes (well-watered and water- stressed) during one growing in season open-top field chambers equipped with fixed raincaps. Conventional methods were used to measure growth, biomass allocation, foliar chlorophyll concentration...

  10. Physics of the Shannon Limits

    E-Print Network [OSTI]

    Merhav, Neri

    2009-01-01T23:59:59.000Z

    We provide a simple physical interpretation, in the context of the second law of thermodynamics, to the information inequality (a.k.a. the Gibbs' inequality, which is also equivalent to the log-sum inequality), asserting that the relative entropy between two probability distributions cannot be negative. Since this inequality stands at the basis of the data processing theorem (DPT), and the DPT in turn is at the heart of most, if not all, proofs of converse theorems in Shannon theory, it is observed that conceptually, the roots of fundamental limits of Information Theory can actually be attributed to the laws of physics, in particular, to the second law of thermodynamics, and at least indirectly, also to the law of energy conservation. By the same token, in the other direction: one can view the second law as stemming from information-theoretic principles.

  11. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, Daniel M.; Rosen, Robert S.

    2005-04-19T23:59:59.000Z

    A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.

  12. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, D.M.; Rosen, R.S.

    1998-06-30T23:59:59.000Z

    A cartridge primer is described which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML`s would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers. 10 figs.

  13. Limits to the lunar atmosphere

    SciTech Connect (OSTI)

    Morgan, T.H. (National Aeronautics and Space Administration, Washington, D.C. (USA)); Shemansky, D.E. (Univ. of Arizona, Tucson (USA))

    1991-02-01T23:59:59.000Z

    The presence of sodium and potassium on the Moon implies that other more abundant species should be present. Volatile molecules like H{sub 2}O are significantly more abundant than sodium in any of the proposed external atmospheric sources. Source mechanisms which derive atoms from the surface should favor abundant elements in the regolith. It is therefore puzzling that the Apollo ultraviolet spectrometer experiment set limits on the density of oxygen of N{sub O} < 5 {times} 10{sup 2} cm{sup {minus}3}, and that the Apollo Lunar Atmospheric Composition Experiment data imply N{sub O} < 50 cm{sup {minus}3} above the subsolar point. These limits are surprisingly small relative to the measured value for sodium. A simple consideration of sources and sinks predicts significantly greater densities of oxygen. It is possible but doubtful that the Apollo measurements occur ed during an epoch in which source rates were small. A preferential loss process for oxygen on the darkside of the Moon is considered in which ionization by electron capture in surface collisions leads to escape through acceleration in the local electric field. Cold trapping in permanently shadowed regions as a net sink is considered and discounted, but the episodic nature of cometary insertion may allow formation of ice layers which act as a stablized source of OH. On the basis of an assumed meteoroid impact source, the authors predict a possible emission brightness of {approximately} 50 R in the OH(A {minus} X)(0,0) band above the lunar bright limb. A very uncertain small comet source of H{sub 2}O could raise this value by more than two orders of magnitude.

  14. Modeling the impacts of biomass burning on air quality in and around Mexico City

    E-Print Network [OSTI]

    Lei, W.

    The local and regional impacts of open fires and trash burning on ground-level ozone (O[subscript 3]) and fine carbonaceous aerosols in the Mexico City Metropolitan Area (MCMA) and surrounding region during two high fire ...

  15. Time and location differentiated NOX control in competitive electricity markets using cap-and-trade mechanisms

    E-Print Network [OSTI]

    Martin, Katherine C.

    2007-01-01T23:59:59.000Z

    Due to variations in weather and atmospheric chemistry, the timing and location of nitrogen oxide (NOX) reductions determine their effectiveness in reducing ground-level ozone, which adversely impacts human health. Electric ...

  16. A methodology to evaluate energy savings and NOx emissions reductions from the adoption of the 2000 International Energy Conservation Code (IECC) to new residences in non-attainment and affected counties in Texas 

    E-Print Network [OSTI]

    Im, Piljae

    2004-09-30T23:59:59.000Z

    Currently, four areas of Texas have been designated by the United States Environmental Protection Agency (EPA) as non-attainment areas because they exceeded the national one-hour ground-level ozone standard of 0.12 ...

  17. Photon and graviton mass limits

    SciTech Connect (OSTI)

    Nieto, Michael [Los Alamos National Laboratory; Goldhaber Scharff, Alfred [SUNY

    2008-01-01T23:59:59.000Z

    We review past and current studies of possible long-distance, low-frequency deviations from Maxwell electrodynamics and Einstein gravity. Both have passed through three phases: (1) Testing the inverse-square laws of Newton and Coulomb, (2) Seeking a nonzero value for the rest mass of photon or graviton, and (3) Considering more degrees of freedom, allowing mass while preserving gauge or general-coordinate invariance. For electrodynamics there continues to be no sign of any deviation. Since our previous review the lower limit on the photon Compton wavelength (associated with weakening of electromagnetic fields in vacuum over large distance scale) has improved by four orders of magnitude, to about one astronomical unit. Rapid current progress in astronomical observations makes it likely that there will be further advances. These ultimately could yield a bound exceeding galactic dimensions, as has long been contemplated. Meanwhile, for gravity there have been strong arguments about even the concept of a graviton rest mass. At the same time there are striking observations, commonly labeled 'dark matter' and 'dark energy' that some argue imply modified gravity. This makes the questions for gravity much more interesting. For dark matter, which involves increased attraction at large distances, any explanation by modified gravity would be qualitatively different from graviton mass. Because dark energy is associated with reduced attraction at large distances, it might be explained by a graviton-mass-like effect.

  18. Kinetic limits of dynamical systems

    E-Print Network [OSTI]

    Jens Marklof

    2014-08-06T23:59:59.000Z

    Since the pioneering work of Maxwell and Boltzmann in the 1860s and 1870s, a major challenge in mathematical physics has been the derivation of macroscopic evolution equations from the fundamental microscopic laws of classical or quantum mechanics. Macroscopic transport equations lie at the heart of many important physical theories, including fluid dynamics, condensed matter theory and nuclear physics. The rigorous derivation of macroscopic transport equations is thus not only a conceptual exercise that establishes their consistency with the fundamental laws of physics: the possibility of finding deviations and corrections to classical evolution equations makes this subject both intellectually exciting and relevant in practical applications. The plan of these lectures is to develop a renormalisation technique that will allow us to derive transport equations for the kinetic limits of two classes of simple dynamical systems, the Lorentz gas and kicked Hamiltonians (or linked twist maps). The technique uses the ergodic theory of flows on homogeneous spaces (homogeneous flows for short), and is based on joint work with Andreas Str\\"ombergsson.

  19. Respiratory responses of vigorously exercising children to 0. 12 ppm ozone exposure

    SciTech Connect (OSTI)

    McDonnell, W.F. 3d.; Chapman, R.S.; Leigh, M.W.; Strope, G.L.; Collier, A.M.

    1985-10-01T23:59:59.000Z

    Changes in respiratory function have been suggested for children exposed to less than 0.12 ppm ozone (O3) while engaged in normal activities. Because the results of these studies have been confounded by other variables, such as temperature or the presence of other pollutants or have been questioned as to the adequacy of exposure measurements, the authors determined the acute response of children exposed to 0.12 ppm O3 in a controlled chamber environment. Twenty-three white males 8 to 11 yr of age were exposed once to clean air and once to 0.12 ppm O3 in random order. Exposures were for 2.5 h and included 2 h of intermittent heavy exercise. Measures of forced expiratory volume in one second (FEV1) and the symptom cough were determined prior to and after each exposure. A significant decline in FEV1 was found after the O3 exposure compared to the air exposure, and it appeared to persist for 16 to 20 h. No significant increase in cough was found due to O3 exposure. Forced vital capacity, specific airways resistance, respiratory frequency, tidal volume, and other symptoms were measured in a secondary exploratory analysis of this study.

  20. Comparison of the responses of children and adults to acute ozone exposure

    SciTech Connect (OSTI)

    McDonnell, W.F.; Chapman, R.S.; Horstman, D.H.; Leigh, M.W.; Salaam, S.A.

    1986-07-01T23:59:59.000Z

    The purpose of the paper is to compare the results of two studies in which the respiratory responses of children and adults to acute ozone (O/sub 3/) exposure were measured. Forty-two 18-30 year old males were exposed for 2.5 hours in a controlled environmental chamber to either 0.0 or 0.12 ppm O3 while performing intermittent heavy exercise. Twenty-two 8-11 year old males were exposed in a similar manner to both air and 0.12 ppm O3. Measures of respiratory symptoms and function were made before and after exposure. Adults experienced an increase in the symptom cough and decrements in forced vital capacity and some measures of forced expiratory flow. Children experienced similar decrements in pulmonary function, but had no increase in symptoms. The authors concluded that as measured by pulmonary function children appear to be no more responsive to O3 exposure than are adults and may experience fewer symptoms.

  1. Paso del Norte pilot border study of ozone precursors and air toxics

    SciTech Connect (OSTI)

    Zielinska, B.; Sheetz, L.; Harshfield, G. [Desert Research Institute, Reno, NV (United States)] [and others

    1996-12-31T23:59:59.000Z

    A comprehensive monitoring program for ozone precursors and air toxics in the Paso del Norte border area is planned by the U.S. EPA for the Summer of 1996. A pilot study was carried out in October 1995 in the Paso del Norte area (El Paso, Texas, Ciudad Juarez, Chihuahua, and Sunland Park, New Mexico) to test the appropriateness of proposed sampling and analysis methods and to provide preliminary data to be used for planning the Summer 1996 study. Two monitoring sites were selected, one in Ciudad Juarez, and one in the El Paso area. Samples were collected every second day from October 21 to October 31, from 0300 to 0900 hr using stainless steel canisters (for VOC in the C{sub 2}-C{sub 12} range), Tenax-TA solid adsorbent cartridges (for C{sub 8}-C{sub 20} hydrocarbons). DNPH impregnated C{sub 18} Sep-Pack cartridges (for carbonyl compounds) and Teflon impregnated glass fiber filters followed by PUF/YAD/PUF {open_quotes}sandwich{close_quotes} cartridges (for SVOC). This paper discusses the data set obtained from the analyses of these samples. 6 refs., 7 figs.

  2. Infrared limit in external field scattering

    E-Print Network [OSTI]

    Andrzej Herdegen

    2012-05-17T23:59:59.000Z

    Scattering of electrons/positrons by external classical electromagnetic wave packet is considered in infrared limit. In this limit the scattering operator exists and produces physical effects, although the scattering cross-section is trivial.

  3. Fractal Graphics Proprietary Limited 39 Fairway, Nedlands,

    E-Print Network [OSTI]

    Boschetti, Fabio

    1 Fractal Graphics Proprietary Limited 39 Fairway, Nedlands, Western Australia, Australia 6009 djh@fractalgraphics.com.au 2 Fractal Graphics Proprietary Limited 39 Fairway, Nedlands, Western Australia, Australia 6009 nja

  4. FUNDAMENTAL PERFORMANCE LIMITS OF WIRELESS SENSOR NETWORKS

    E-Print Network [OSTI]

    Li, Baochun

    FUNDAMENTAL PERFORMANCE LIMITS OF WIRELESS SENSOR NETWORKS ZHIHUA HU, BAOCHUN LI Abstract. Understanding the fundamental performance limits of wireless sensor networks is critical towards. Key words. Wireless sensor networks, network capacity, network lifetime. 1. Introduction. When

  5. Neural substrates of cognitive capacity limitations

    E-Print Network [OSTI]

    Buschman, Tim

    Cognition has a severely limited capacity: Adult humans can retain only about four items “in mind”. This limitation is fundamental to human brain function: Individual capacity is highly correlated with intelligence measures ...

  6. Implementing Risk-Limiting Audits in California

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    cast09.pdf. Philip B. Stark. Risk-limiting post-electionthe N.J. law the ?rst “risk-based statistical audit law. ”Holt bill does not limit risk. The Holt bill has a clause

  7. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, J.R.

    1997-02-04T23:59:59.000Z

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  8. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL)

    1997-01-01T23:59:59.000Z

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  9. Air-Quality Data from NARSTO (North American Research Strategy for Tropospheric Ozone)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    NARSTO is a public/private partnership dedicated to improving management of air quality in North America. It was established on February 13, 1995 when representatives of Canada, the United States, and Mexico signed the NARSTO Charter in a ceremony at the White House. The Department of Energy is one of the charter members providing funding. The central programmatic goal of NARSTO is to provide data and information for use in the determination of workable, efficient, and effective strategies for local and regional ozone and fine particle management. Since its founding, NARSTO has completed three major scientific Assessments of critical air quality management issues. NARSTO maintains the Quality Systems Science Center and the NARSTO Data Archive for storing data from NARSTO Affiliated Research Activities and making these data available to the scientific community. NARSTO also facilitates activities, such as the Reactivity Research Working Group, which provide critical reviews of the state of the science in areas of interest to air quality policy makers. In January 1997, the U.S. Department of Energy's Environmental Sciences Division announced their sponsorship of the NARSTO Quality Systems Science Center (QSSC). The QSSC is located at the Oak Ridge National Laboratory within the Carbon Dioxide Information Analysis Center (CDIAC). Quality Assurance and Data Management assistance and guidelines are provided by the QSCC, along with access to data files. The permanent data archive is maintained by the NASA EOSDIS Distributed Active Archive Center at the Langley Research Center. The archived data can be reached by a link from the QSSC.(Specialized Interface) See also the NARSTO web site at http://www.narsto.org/

  10. Air pollution and childhood respiratory health: Exposure to sulfate and ozone in 10 Canadian Rural Communities

    SciTech Connect (OSTI)

    Stern, B.R.; Raizenne, M.E.; Burnett, R.T.; Jones, L.; Kearney, J.; Franklin, C.A. (Environmental Health Directorate, Ottawa, Ontario (Canada))

    1994-08-01T23:59:59.000Z

    This study was designed to examine differences in the respiratory health status of preadolescent school children, aged 7-11 years, who resided in 10 rural Canadian communities in areas of moderate and low exposure to regional sulfate and ozone pollution. Five of the communities were located in central Saskatchewan, a low-exposure region, and five were located in southwestern Ontario, an area with moderately elevated exposures resulting from long-range atmospheric transport of polluted air masses. In this cross-sectional study, the child's respiratory symptoms and illness history were evaluated using a parent-completed questionnaire, administered in September 1985. Respiratory function was assessed once for each child in the schools between October 1985 and March 1986, by the measurement of pulmonary function for forced vital capacity (FVC), forced expiratory volume in 1 sec (FEV[sub 1.0]), peak expiratory flow rate (PEFR), mean forced expiratory flow rate during the middle half of the FVC curve (FEF[sub 25-75]), and maximal expiratory flow at 50% of the expired vital capacity (V[sub 50]max). After controlling for the effects of age, sex, parental smoking, parental education and gas cooking, no significant regional differences were observed in rates of chronic cough or phlegm, persistent wheeze, current asthma, bronchitis in the past year, or any chest illness that kept the child at home for 3 or more consecutive days during the previous year. Children living in southwestern Ontario had statistically significant (P < 0.01) mean decrements of 1.7% in FVC and 1.3% in FEV[sub 1.0] compared with Saskatchewan children, after adjusting for age, sex, weight, standing height, parental smoking, and gas cooking. There were no statistically significant regional differences in the pulmonary flow parameters (P > 0.05). 54 refs., 1 fig., 7 tabs.

  11. The pulmonary response of white and black adults to six concentrations of ozone

    SciTech Connect (OSTI)

    Seal, E. Jr.; McDonnell, W.F.; House, D.E.; Salaam, S.A.; Dewitt, P.J.; Butler, S.O.; Green, J.; Raggio, L. (Environmental Protection Agency, Chapel Hill, NC (United States))

    1993-04-01T23:59:59.000Z

    Many early studies of respiratory responsiveness to ozone (O3) were done on healthy, young, white males. The purpose of this study was to determine whether gender or race differences in O3 response exist among white and black, males and females, and to develop concentration-response curves for each of the gender-race groups. Three hundred seventy-two subjects (n > 90 in each gender-race group), ages 18 to 35 yr, were exposed once for 2.33 h to 0.0 (purified air), 0.12, 0.18, 0.24, 0.30, or 0.40 ppm O3. Each exposure was preceded by baseline pulmonary function tests and a symptom questionnaire. The first 2 h of exposure included alternating 15-min periods of rest and exercise on a motorized treadmill producing a minute ventilation (VE) of 25 L/min/m2 body surface area (BSA). After exposure, subjects completed a set of pulmonary function tests and a symptom questionnaire. Lung function and symptom responses were expressed as percent change from baseline and analyzed using a nonparametric two factor analysis of variance. Three primary variables were analyzed: FEV1, specific airway resistance (SRaw), and cough. Statistical analysis demonstrated no significant differences in response to O3 among the individual gender-race groups. For the group as a whole, changes in the variables FEV1, SRaw, and cough were first noted at 0.12, 0.18, and 0.18 ppm O3, respectively. Adjusted for exercise difference, concentration-response curves for FEV1 and cough among white males were consistent with previous reports (1).

  12. An examination of utility emissions contributions to elevated ozone concentrations in the Chicago area

    SciTech Connect (OSTI)

    Fernau, M.E.; Guziel, K.A.; South, D.W.

    1993-05-01T23:59:59.000Z

    In order to reduce the pollutant load to the atmosphere and subsequent damaging effects, Titles I and IV of the Clean Air Act Amendments of 1990 (CAAAs) require reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NO{sub x}), and volatile organic compounds (VOCs). Title IV is aimed at reducing acidic deposition and requires utilities to reduce SO{sub 2} and NO{sub x} emissions to specified levels. As a consequence of this, many utilities will have to install SO{sub 2} and NO{sub x} control technologies. Title I is concerned with bringing regions into compliance with the National Ambient Air Quality Standards (NAAQS) for the criteria pollutants, among which is ozone (O{sub 3}). The NAAQS for O{sub 3} is 120 ppb (parts per billion by volume) hourly average concentration, not to be exceeded four times in three years. O{sub 3} is a secondary pollutant formed in the atmosphere when NO{sub x} and VOCs react together in the presence of sunlight. Utilities are a significant source of NO{sub x} and an unimportant source of VOCs. In the past, O{sub 3} control strategy has focused on reducing VOC emissions because of the possibility that reducing NO{sub x} actually might make O{sub 3} concentrations higher. However, this approach has not worked, perhaps because of underestimation of natural and manmade VOC emissions and transport of O{sub 3} from other regions. Computer modeling has shown that for many highly polluted areas massive NO{sub x} reductions may be necessary in addition to or in place of VOC controls. Utilities are a potential source of these NO{sub x} reductions.

  13. Respiratory health effects associated with ambient sulfates and ozone in two rural Canadian communities

    SciTech Connect (OSTI)

    Stern, B.; Jones, L.; Raizenne, M.; Burnett, R.; Meranger, J.C.; Franklin, C.A.

    1989-06-01T23:59:59.000Z

    A cross-sectional epidemiological study investigating the respiratory health of children in two Canadian communities was conducted in 1983-1984 in Tillsonburg, Ontario, located in a region of moderately elevated concentrations of transported air pollutants, and in Portage la Prairie, Manitoba, situated in a low pollution area. There were no significant local sources of industrial emissions in either community. Seven hundred and thirty-five children aged 7-12 were studied in the first town and 895 in the second. Respiratory health was assessed by the measurement of the forced vital capacity (FVC) and forced expiratory volume in 1 sec (FEV1.0) of each child, and by evaluation of the child's respiratory symptoms and illnesses using a parent-completed questionnaire. Sulfur dioxide (SO2), sulfate, and particulate nitrate levels were significantly higher in Tillsonburg than in Portage la Prairie (P less than 0.05), but nitrogen dioxide (NO2) and inhalable particles (PM10) differed little between the communities. Historical data in the vicinity of Tillsonburg indicated that average annual levels of sulfates, total nitrates, and ozone (O3) did not vary markedly in the 9-year period preceding the study. The results show that Tillsonburg children had statistically significant (P less than 0.001) lower levels of 2% for FVC and 1.7% for FEV1.0 as compared with children in Portage la Prairie. These differences could not be explained by parental smoking or education, the use of gas cooking or wood heating fuels, pollution levels on the day of testing, or differences in age, sex, height, or weight. With the exception of inhalant allergies, which occurred more frequently in Tillsonburg children, the prevalence of chronic respiratory symptoms and illnesses was similar in the two communities.

  14. An examination of utility emissions contributions to elevated ozone concentrations in the Chicago area

    SciTech Connect (OSTI)

    Fernau, M.E.; Guziel, K.A.; South, D.W.

    1993-01-01T23:59:59.000Z

    In order to reduce the pollutant load to the atmosphere and subsequent damaging effects, Titles I and IV of the Clean Air Act Amendments of 1990 (CAAAs) require reductions in emissions of sulfur dioxide (SO[sub 2]), nitrogen oxides (NO[sub x]), and volatile organic compounds (VOCs). Title IV is aimed at reducing acidic deposition and requires utilities to reduce SO[sub 2] and NO[sub x] emissions to specified levels. As a consequence of this, many utilities will have to install SO[sub 2] and NO[sub x] control technologies. Title I is concerned with bringing regions into compliance with the National Ambient Air Quality Standards (NAAQS) for the criteria pollutants, among which is ozone (O[sub 3]). The NAAQS for O[sub 3] is 120 ppb (parts per billion by volume) hourly average concentration, not to be exceeded four times in three years. O[sub 3] is a secondary pollutant formed in the atmosphere when NO[sub x] and VOCs react together in the presence of sunlight. Utilities are a significant source of NO[sub x] and an unimportant source of VOCs. In the past, O[sub 3] control strategy has focused on reducing VOC emissions because of the possibility that reducing NO[sub x] actually might make O[sub 3] concentrations higher. However, this approach has not worked, perhaps because of underestimation of natural and manmade VOC emissions and transport of O[sub 3] from other regions. Computer modeling has shown that for many highly polluted areas massive NO[sub x] reductions may be necessary in addition to or in place of VOC controls. Utilities are a potential source of these NO[sub x] reductions.

  15. Impact limiter retention using a tape joint

    SciTech Connect (OSTI)

    Gonzales, A.; Eakes, R.G.

    1986-01-01T23:59:59.000Z

    The Beneficial Uses Shipping System (BUSS) Cask employs polyurethane foam impact limiters that fit onto the ends of the cask. A foam impact limiter takes energy out of a system during a hypothetical accident condition by allowing foam crush and large deformations to occur. This, in turn, precludes high stresses or deformations from occurring to the cask. Because of the need to transmit significant amounts of heat to the environment, the BUSS cask impact limiters were designed to shield a minimum amount of the cask surface area. With this design impact limiter retention after the initial impact resulting from the 9 meter regulatory drops becomes a concern. Retention is essential to ensure the cask does not experience higher stresses during any secondary or rebound effects without impact limiters than it does during the 9 meter regulatory drop with impact limiters in place.

  16. The Chandrasekhar limit for quark stars

    E-Print Network [OSTI]

    Shibaji Banerjee; Sanjay K. Ghosh; Sibaji Raha

    2000-01-14T23:59:59.000Z

    The Chandrasekhar limit for quark stars is evaluated from simple energy balance relations, as proposed by Landau for white dwarfs or neutron stars. It has been found that the limit for quark stars depends on, in addition to the fundamental constants, the Bag constant.

  17. 6/3/2013 Page 1 of 9 Ozone SOP Standard Operating Procedures

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Flash point: not applicable Lower explosion limit: not applicable Upper explosion statement(s) H270 May cause or intensify fire; oxidizer. H315 In case of fire: Stop leak if safe to do so. P260 Do not breathe

  18. Self-triggering superconducting fault current limiter

    DOE Patents [OSTI]

    Yuan, Xing (Albany, NY); Tekletsadik, Kasegn (Rexford, NY)

    2008-10-21T23:59:59.000Z

    A modular and scaleable Matrix Fault Current Limiter (MFCL) that functions as a "variable impedance" device in an electric power network, using components made of superconducting and non-superconducting electrically conductive materials. The matrix fault current limiter comprises a fault current limiter module that includes a superconductor which is electrically coupled in parallel with a trigger coil, wherein the trigger coil is magnetically coupled to the superconductor. The current surge doing a fault within the electrical power network will cause the superconductor to transition to its resistive state and also generate a uniform magnetic field in the trigger coil and simultaneously limit the voltage developed across the superconductor. This results in fast and uniform quenching of the superconductors, significantly reduces the burnout risk associated with non-uniformity often existing within the volume of superconductor materials. The fault current limiter modules may be electrically coupled together to form various "n" (rows).times."m" (columns) matrix configurations.

  19. Products and Mechanisms of the Reaction of Oleic Acid with Ozone and Nitrate Radical Hui-Ming Hung, Yasmine Katrib, and Scot T. Martin*

    E-Print Network [OSTI]

    the addition of ozone to the double bond of oleic acid, which yields a primary ozonide (molozonide).21 The high-energy chromatography-mass spectrometry (GC-MS), and liquid chromatography-mass spectrometry (LC-MS) are used, and -NO2 are observed in the infrared spectra, and high molecular weight molecules are formed

  20. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    SciTech Connect (OSTI)

    Leng, Xiang [Brookhaven National Lab. (BNL), Upton, NY (United States); Bozovic, Ivan [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on the same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.

  1. A real time model to forecast 24 hours ahead, ozone peaks and exceedance levels. Model based on artificial neural networks, neural classifier and weather predictions.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    on artificial neural networks, neural classifier and weather predictions. Application in an urban atmosphere - will be solved. Keywords: Artificial neural network; Multilayer Perceptron; ozone modelling; statistical stepwise and Software 22, 9 (2007) 1261-1269" DOI : 10.1016/j.envsoft.2006.08.002 #12;Abstract A neural network combined

  2. Potential impacts of climate change on tropospheric ozone in California: a preliminary episodic modeling assessment of the Los Angeles basin and the Sacramento valley

    SciTech Connect (OSTI)

    Taha, Haider

    2001-01-01T23:59:59.000Z

    In this preliminary and relatively short modeling effort, an initial assessment is made for the potential air quality implications of climate change in California. The focus is mainly on the effects of changes in temperature and related meteorological and emission factors on ozone formation. Photochemical modeling is performed for two areas in the state: the Los Angeles Basin and the Sacramento Valley.

  3. Estimation of Flammability Limits of Selected Fluorocarbons with F(sub 2) and CIF(sub3)

    SciTech Connect (OSTI)

    Trowbridge, L.D.

    1999-09-01T23:59:59.000Z

    During gaseous diffusion plant operations, conditions leading to the formation of flammable gas mixtures may occasionally arise. Currently, these could consist of the evaporative coolant CFC-114 and fluorinating agents such as F(sub 2) and CIF(sub 3). Replacement of CFC-114 with non-ozone-depleting substitutes such as c-C(sub 4)F(sub 8) and C(sub 4)F(sub 10) is planned. Consequently, in the future, these too must be considered potential ''fuels'' in flammable gas mixtures. Two questions of practical interest arise: (1) can a particular mixture sustain and propagate a flame if ignited, and (2) what is the maximum pressure that can be generated by the burning (and possibly exploding) gas mixture, should ignite? Experimental data on these systems are limited. To assist in answering these questions, a literature search for relevant data was conducted, and mathematical models were developed to serve as tools for predicting potential detonation pressures and estimating (based on empirical correlations between gas mixture thermodynamics and flammability for known systems) the composition limits of flammability for these systems. The models described and documented in this report are enhanced versions of similar models developed in 1992.

  4. Compliance with the Clean Air Act Title VI Stratospheric Ozone Protection Program requirements at U.S. DOE Oak Ridge Reservation Facilities

    SciTech Connect (OSTI)

    Humphreys, M.P.; Atkins, E.M.

    1999-07-01T23:59:59.000Z

    The Title VI Stratospheric Ozone Protection Program of the Clean Air Act (CAA) requires promulgation of regulations to reduce and prevent damage to the earth's protective ozone layer. Regulations pursuant to Title VI of the CAA are promulgated in the Code of Federal Regulations (CFR) at Title 40 CFR, Part 822. The regulations include ambitious production phaseout schedules for ozone depleting substances (ODS) including chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), halons, carbon tetrachloride, and methyl chloroform under 40 CFR 82, Subpart A. The regulations also include requirements for recycling and emissions reduction during the servicing of refrigeration equipment and technician certification requirements under Subpart F; provisions for servicing of motor vehicle air conditioners under Subpart B; a ban on nonessential products containing Class 1 ODS under Subpart C; restrictions on Federal procurement of ODS under Subpart D; labeling of products using ODS under Subpart E; and the Significant New Alternatives Policy Program under Subpart G. This paper will provide details of initiatives undertaken at US Department of Energy (DOE) Oak Ridge Reservation (ORR) Facilities for implementation of requirements under the Title VI Stratospheric Ozone Protection Program. The Stratospheric Ozone Protection Plans include internal DOE requirements for: (1) maintenance of ODS inventories; (2) ODS procurement practices; (3) servicing of refrigeration and air conditioning equipment; (4) required equipment modifications or replacement; (5) technician certification training; (6) labeling of products containing ODS; (7) substitution of chlorinated solvents; and (8) replacement of halon fire protection systems. The plans also require establishment of administrative control systems which assure that compliance is achieved and maintained as the regulations continue to develop and become effective.

  5. Long-time limit of correlation functions

    E-Print Network [OSTI]

    Thomas Franosch

    2014-07-31T23:59:59.000Z

    Auto-correlation functions in an equilibrium stochastic process are well-characterized by Bochner's theorem as Fourier transforms of a finite symmetric Borel measure. The existence of a long-time limit of these correlation functions depends on the spectral properties of the measure. Here we provide conditions applicable to a wide-class of dynamical theories guaranteeing the existence of the long-time limit. We discuss the implications in the context of the mode-coupling theory of the glass transition where a non-trivial long-time limit signals an idealized glass state.

  6. Limit of light coupling into solar cells

    E-Print Network [OSTI]

    Naqavi, A; Ballif, C; Scharf, T; Herzig, H P

    2013-01-01T23:59:59.000Z

    We introduce a limit for the strength of coupling light into the modes of solar cells. This limit depends on both a cell's thickness and its modal properties. For a cell with refractive index n and thickness d, we obtain a maximal coupling rate of 2c*sqrt(n^2-1)/d where c is speed of light. Our method can be used in the design of solar cells and in calculating their efficiency limits; besides, it can be applied to a broad variety of resonant phenomena and devices.

  7. Quantum Cryptography Approaching the Classical Limit

    E-Print Network [OSTI]

    Weedbrook, Christian

    We consider the security of continuous-variable quantum cryptography as we approach the classical limit, i.e., when the unknown preparation noise at the sender’s station becomes significantly noisy or thermal (even by as ...

  8. Infinite volume limit for the dipole gas

    E-Print Network [OSTI]

    J. Dimock

    2009-04-28T23:59:59.000Z

    We consider a classical dipole gas in with low activity and show that the pressure has a limit as the volume goes to infinity. The result is obtained by a renormalization group analysis of the model.

  9. Heisenberg-limited metrology with information recycling

    E-Print Network [OSTI]

    Simon A. Haine; Stuart S. Szigeti; Matthias D. Lang; Carlton M. Caves

    2015-05-01T23:59:59.000Z

    Information recycling has been shown to improve the sensitivity of atom interferometers by exploiting atom-light entanglement. In this paper, we apply information recycling to an interferometer where the input quantum state has been partially transferred from some donor system. We demonstrate that when the quantum state of this donor system is from a particular class of number-correlated Heisenberg-limited states, information recycling yields a Heisenberg-limited phase measurement. Crucially, this result holds irrespective of the fraction of the quantum state transferred to the interferometer input and also for a general class of number-conserving quantum-state-transfer processes, including ones that destroy the first-order phase coherence between the branches of the interferometer. This result could have significant applications in Heisenberg-limited atom interferometry, where the quantum state is transferred from a Heisenberg-limited photon source, and in optical interferometry where the loss can be monitored.

  10. Can Eutrophication Influence Nitrogen vs. Phosphorus Limitation?

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Can Eutrophication Influence Nitrogen vs. Phosphorus Limitation? George Gregory Bates College, originating largely from septic systems and fertilizers, have caused significant eutrophication in freshwater nitrogen and phosphorus grew the highest concentration of phytoplankton, but eutrophic ponds grew a mean

  11. Some Fundamental Limitations for Cognitive Radio

    E-Print Network [OSTI]

    Sahai, Anant

    ' & $ % Some Fundamental Limitations for Cognitive Radio Anant Sahai Wireless Foundations, UCB EECS program November 1 at BWRC Cognitive Radio Workshop #12;' & $ % Outline 1. Why cognitive radios? 2 November 1 at BWRC Cognitive Radio Workshop #12;' & $ % Apparent spectrum allocations · Traditional

  12. Diffusion-Limited Aggregation on Curved Surfaces

    E-Print Network [OSTI]

    Choi, J.

    We develop a general theory of transport-limited aggregation phenomena occurring on curved surfaces, based on stochastic iterated conformal maps and conformal projections to the complex plane. To illustrate the theory, we ...

  13. Climate Prediction: The Limits of Ocean Models

    E-Print Network [OSTI]

    Stone, Peter H.

    We identify three major areas of ignorance which limit predictability in current ocean GCMs. One is the very crude representation of subgrid-scale mixing processes. These processes are parameterized with coefficients whose ...

  14. Performance limits of axial turbomachine stages

    E-Print Network [OSTI]

    Hall, David Kenneth

    2011-01-01T23:59:59.000Z

    This thesis assesses the limits of stage efficiency for axial compressor and turbine stages. A stage model is developed, consisting of a specified geometry and a surface velocity distribution with turbulent boundary layers. ...

  15. Representation of Limited Rights Data and Restricted Computer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data...

  16. Limits of Equivalence: Thinking Gay Male Subjectivity Outside Feminist Theory

    E-Print Network [OSTI]

    Galloway, Samuel R.

    2010-01-01T23:59:59.000Z

    Limits of Equivalence: Thinking Gay Male Subjectivityor this limit of equivalence? The problem, of course, ispaper, the limits of equivalence emerge: while all subjects

  17. Inequality design limits in optimal aerodynamic shapes

    E-Print Network [OSTI]

    Seaman, Charles Knight

    1968-01-01T23:59:59.000Z

    ACKNOWLEDGMENTS I would like to thank Mr. Stan Lowy for his assistance. ABSTRACT The investigation is concerned with ways of including design con- straints in the problem of optimum aerodynamic shapes. Inequality constraints are examined in the report as one... means of describing design limits in the optimization problem. The use of inequality con- straints to consider design limits in a variational solution is illustrated with an example problem. In the example problem, the admissable profiles for a...

  18. Improved limits on scalar weak couplings

    SciTech Connect (OSTI)

    Adelberger, E.G. (PPE Division, CERN, CH-1211 Geneve 23 (Switzerland) Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-05-10T23:59:59.000Z

    I point out that [beta]-delayed proton spectroscopy is a powerful probe of possible scalar contributions to nuclear [beta] decay, and use Schardt and Riisager's data on the shape of the beta-delayed proton peaks from the superallowed decays of [sup 32]Ar and [sup 33]Ar to set improved upper limits on such couplings. Implications of these limits for leptoquark masses are mentioned.

  19. In-field results of SNCR/SCR hybrid on a group 1 boiler in the ozone transport region

    SciTech Connect (OSTI)

    Boyle, J.M.; Urbas, J.

    1998-07-01T23:59:59.000Z

    Electric utilities within the Ozone Transport Region must prepare for seasonal and potentially piecemeal NO{sub x} reductions to meet Title 1 requirements. In order to achieve additional NO{sub x} reductions beyond the existing SNCR System in a manner, which allows maximum flexibility at minimum cost. GPU GENCO, in cooperation with the DOE, EPRI, PETC, and PERC, has chosen to field demonstrate a SNCR/SCR hybrid system. Commercially known as NO{sub x}OUT CASCADE, the system employs a urea based SNCR system to produce a managed level of ammonia slip, which in turn charges an in duct SCR element. The system is presently scheduled for initial operation in October 1997. This paper discusses the decision path associated with the project, including design and operating criteria, performance expectations, retrofit considerations, testing protocol, and current results.

  20. Time-Resolved Molecular Characterization of Limonene/Ozone Aerosol using High-Resolution Electrospray Ionization Mass Spectrometry

    SciTech Connect (OSTI)

    Bateman, Adam P.; Nizkorodov, Serguei; Laskin, Julia; Laskin, Alexander

    2009-09-09T23:59:59.000Z

    Molecular composition of limonene/O3 secondary organic aerosol (SOA) was investigated using high-resolution electrospray ionization mass spectrometry (HR-ESI-MS) as a function of reaction time. SOA was generated by ozonation of D-limonene in a reaction chamber and sampled at different time intervals using a cascade impactor. The SOA samples were extracted into acetonitrile and analyzed using a HR-ESI-MS instrument with a resolving power of 100,000 (m/?m). The resulting mass spectra provided detailed information about the extent of oxidation inferred from the O:C ratios, double bond equivalency (DBE) factors, and aromaticity indexes (AI) in hundreds of identified individual SOA species.

  1. Federal Aviation Administration: High Altitude Pollution Program, third biennial report prepared in accordance with the Stratospheric Ozone Protection Provision, section 153(g), of the Clean Air Act amendments of 1977. Report for Jan 80-Dec 81

    SciTech Connect (OSTI)

    Not Available

    1981-12-01T23:59:59.000Z

    The impact of high altitude aviation on stratospheric ozone is now believed to be a decrease in total columnar ozone for flights above 15 km (about 49,000 feet). The model calculations also show that the current subsonic fleet (and the fleet foreseeable to 1990) will result in a net ozone increase of about 1 percent, considering normal flight altitudes. Whatever the net change in total column ozone, increases or depletions will occur at different altitudes. These are expected to have subtle influences on atmospheric circulation, the effects of which are only beginning to be understood. As a formal program, the High Altitude Pollution Program will be terminated in 1982 with the issuance of a final report. The FAA will continue to maintain and update, as appropriate, its capability to make quantitative assessments of the environmental effects of cruise-altitude emissions, and will monitor and assist, as possible, other research programs, both here and abroad.

  2. A global inventory of ecosystem sources of methyl bromide, an ozone destroying gas 

    E-Print Network [OSTI]

    Fenney, Gareth

    2008-12-11T23:59:59.000Z

    and anthropogenically produced. Biomass burning, salt marsh and agriculture are reported as the largest natural sources. However, there exists a need for a global inventory as current budget estimates are uncertain, based on limited data and show a 45Gg yr-1 discrepancy...

  3. On the Eddington limit in accretion discs

    E-Print Network [OSTI]

    D. Heinzeller; W. J. Duschl

    2006-10-25T23:59:59.000Z

    Although the Eddington limit has originally been derived for stars, recently its relevance for the evolution of accretion discs has been realized. We discuss the question whether the classical Eddington limit - which has been applied globally for almost all calculations on accretion discs - is a good approximation if applied locally in the disc. For this purpose, a critical accretion rate corresponding to this type of modified classical Eddington limit is calculated from thin alpha-disc models and slim disc models. We account for the non-spherical symmetry of the disc models by computing the local upper limits on the accretion rate from vertical and radial force equilibria separately. It is shown that the results can differ considerably from the classical (global) value: The vertical radiation force limits the maximum accretion rate in the inner disc region to much less than the classical Eddington value in thin alpha-discs, while it allows for significantly higher accretion rates in slim discs. We discuss the implications of these results for the evolution of accretion discs and their central objects.

  4. Constructing Amplitudes from Their Soft Limits

    SciTech Connect (OSTI)

    Boucher-Veronneau, Camille; Larkoski, Andrew J.; /SLAC

    2011-12-09T23:59:59.000Z

    The existence of universal soft limits for gauge-theory and gravity amplitudes has been known for a long time. The properties of the soft limits have been exploited in numerous ways; in particular for relating an n-point amplitude to an (n-1)-point amplitude by removing a soft particle. Recently, a procedure called inverse soft was developed by which 'soft' particles can be systematically added to an amplitude to construct a higher-point amplitude for generic kinematics. We review this procedure and relate it to Britto-Cachazo-Feng-Witten recursion. We show that all tree-level amplitudes in gauge theory and gravity up through seven points can be constructed in this way, as well as certain classes of NMHV gauge-theory amplitudes with any number of external legs. This provides us with a systematic procedure for constructing amplitudes solely from their soft limits.

  5. The limited validity of the Kubo formula

    E-Print Network [OSTI]

    Steinhoff, Heinz-Jürgen

    The limited validity of the Kubo formula for thermal conduction J. Gemmer, UniversitË?at Osnabr; Transport phenomena and Kubo formula Normal transport phenomena: ``field driven'' j = L F F electric current (#) F = -#V Kubo formula (KF): L F (#) = 1 V # # 0 dt e -i#t # # 0 d# Tr{â??# 0 â?? j(0) â?? j(t + i

  6. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    NA

    2004-11-22T23:59:59.000Z

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this modeling activity is to predict dissolved concentrations or solubility limits for 14 elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) important to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are in the form of tabulated functions with pH and log (line integral) CO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. The output data from this report are fundamental inputs for Total System Performance Assessment for the License Application (TSPA-LA) to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for all of the actinides. These models cover broad ranges of environmental conditions so that they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  7. Flexible moldable conductive current-limiting materials

    SciTech Connect (OSTI)

    Shea, John Joseph (Pittsburgh, PA); Djordjevic, Miomir B. (Milwaukee, WI); Hanna, William Kingston (Pittsburgh, PA)

    2002-01-01T23:59:59.000Z

    A current limiting PTC device (10) has two electrodes (14) with a thin film of electric conducting polymer material (20) disposed between the electrodes, the polymer material (20) having superior flexibility and short circuit performance, where the polymer material contains short chain aliphatic diepoxide, conductive filler particles, curing agent, and, preferably, a minor amount of bisphenol A epoxy resin.

  8. IRS Contribution Limits and OSU Retirement Programs

    E-Print Network [OSTI]

    Veiga, Pedro Manuel Barbosa

    Impact: OTRS requires contributions on total compensation (salary plus benefits) without regardIRS Contribution Limits and OSU Retirement Programs The OSU Defined Contribution Plan (DCP), (for Revenue Code 401(a). The Internal Revenue Code restrictions on employer-paid contributions make

  9. Extending the Upper Temperature Limit for Life

    E-Print Network [OSTI]

    Lovley, Derek

    ) un- der N2-CO2 (80:20) in sealed culture tubes that con- tained formate (10 mM) as the electron donor that permit strain 121 to grow at such high temperatures are unknown. It is gen- erally assumed that the upperExtending the Upper Temperature Limit for Life Kazem Kashefi and Derek R. Lovley* The upper

  10. Physical limits of Communication Madhu Sudan1

    E-Print Network [OSTI]

    Sudan, Madhu

    Physical limits of Communication Madhu Sudan1 1 Microsoft Research New England, One Memorial Drive by a particle may flip during transmission, and delay, where the particle's arrival time at a © Madhu Sudan, Germany #12;Madhu Sudan 5 destination may not correspond exactly to its departure time. In particular we

  11. Physical Limitations on Mining Natural Earth Systems

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    Physical Limitations on Mining Natural Earth Systems A view of the Himalayas from Lhasa Tad Patzek of fossil fuels ("resources") left all over the Earth The resource size (current balance of a banking flow-based solutions (wind turbines, photovoltaics, and biofuels) will require most radical changes

  12. Half-life Limit of 19Mg

    E-Print Network [OSTI]

    N. Frank; T. Baumann; D. Bazin; R. R. C. Clement; M. W. Cooper; P. Heckman; W. A. Peters; A. Stolz; M. Thoennessen; M. S. Wallace

    2003-10-17T23:59:59.000Z

    A search for 19Mg was performed using projectile fragmentation of a 150 MeV/nucleon 36Ar beam. No events of 19Mg were observed. From the time-of-flight through the fragment separator an upper limit of 22 ns for the half-life of 19Mg was established.

  13. Economic Growth, Physical Limits and Liveability

    E-Print Network [OSTI]

    on criteria air contaminants, water use, land use, greenhouse gas emissions and solid waste disposal and population growth, impose the physical limits and then simulate household and firm responses to policy and assess the resulting implications for liveability in the region. I measure liveability using 24

  14. Environmental factors affecting the permitting of a gas turbine cogeneration system located in an area designated non-attainment for ozone and carbon monoxide

    SciTech Connect (OSTI)

    Memarzadeh, F. [National Inst. of Health, Bethesda, MD (United States). Office of Research

    1994-12-31T23:59:59.000Z

    This paper will describe air permitting regulations that apply to a new cogeneration facility or the modification of any existing facility. The permitting depends on several factors including the attainment status of the emitted criteria pollutants within the project area, with the facility classified as either a ``major new source`` or a ``major modification``. Depending on the attainment status of a given pollutant, either the Prevention of Significant Deterioration (PSD) or the Non-attainment area (NAA) regulations (Title I of the Clean Air Act Amendments of 1990) will apply for that pollutant. Since the greatest percentage of emissions generated by a gas turbine are nitrogen oxides (ozone precursors) and carbon monoxide this paper presents an overview of clean air regulations pertinent to those areas of the country that are designated as attaining the National Ambient Air Quality Standards (NAAQS) for sulphur dioxide (SO{sub 2}), particulate matter (PM), nitrogen oxides (NO{sub x}) and lead (Pb), and as areas of nonattainment for ozone (O{sub 3}) and carbon monoxide (CO). A hypothetical case is presented and all the environmental issues such as applicability of PSD and NAA regulations, available pollution offsets, and air quality compliance requirements for a modification to an existing facility located in a serious ozone and moderate carbon monoxide non-attainment area will be illustrated.

  15. How energy conservation limits our measurements

    E-Print Network [OSTI]

    Miguel Navascues; Sandu Popescu

    2014-04-25T23:59:59.000Z

    Observations in Quantum Mechanics are subject to complex restrictions arising from the principle of energy conservation. Determining such restrictions, however, has been so far an elusive task, and only partial results are known. In this paper we discuss how constraints on the energy spectrum of a measurement device translate into limitations on the measurements which we can effect on a target system with non-trivial energy operator. We provide efficient algorithms to characterize such limitations and we quantify them exactly when the target is a two-level quantum system. Our work thus identifies the boundaries between what is possible or impossible to measure, i.e., between what we can see or not, when energy conservation is at stake.

  16. Flow reversal power limit for the HFBR

    SciTech Connect (OSTI)

    Cheng, Lap Y.; Tichler, P.R.

    1995-10-01T23:59:59.000Z

    The High Flux Beam Reactor (HFBR) undergoes a buoyancy-driven reversal of flow in the reactor core following certain postulated accidents. Uncertainties about the afterheat removal capability during the flow reversal has limited the reactor operating power to 30 MW. An experimental and analytical program to address these uncertainties is described in this report. The experiments were single channel flow reversal tests under a range of conditions. The analytical phase involved simulations of the tests to benchmark the physical models and development of a criterion for dryout. The criterion is then used in simulations of reactor accidents to determine a safe operating power level. It is concluded that the limit on the HFBR operating power with respect to the issue of flow reversal is in excess of 60 MW.

  17. Polymer Quantum Mechanics and its Continuum Limit

    E-Print Network [OSTI]

    Alejandro Corichi; Tatjana Vukasinac; Jose A. Zapata

    2007-08-22T23:59:59.000Z

    A rather non-standard quantum representation of the canonical commutation relations of quantum mechanics systems, known as the polymer representation has gained some attention in recent years, due to its possible relation with Planck scale physics. In particular, this approach has been followed in a symmetric sector of loop quantum gravity known as loop quantum cosmology. Here we explore different aspects of the relation between the ordinary Schroedinger theory and the polymer description. The paper has two parts. In the first one, we derive the polymer quantum mechanics starting from the ordinary Schroedinger theory and show that the polymer description arises as an appropriate limit. In the second part we consider the continuum limit of this theory, namely, the reverse process in which one starts from the discrete theory and tries to recover back the ordinary Schroedinger quantum mechanics. We consider several examples of interest, including the harmonic oscillator, the free particle and a simple cosmological model.

  18. Diffusion limited reactions in confined environments

    E-Print Network [OSTI]

    Jeremy D. Schmit; Ercan Kamber; Jané Kondev

    2007-11-19T23:59:59.000Z

    We study the effect of confinement on diffusion limited bimolecular reactions within a lattice model where a small number of reactants diffuse amongst a much larger number of inert particles. When the number of inert particles is held constant the rate of the reaction is slow for small reaction volumes due to limited mobility from crowding, and for large reaction volumes due to the reduced concentration of the reactants. The reaction rate proceeds fastest at an intermediate confinement corresponding to volume fraction near 1/2 and 1/3 in two and three dimensions, respectively. We generalize the model to off-lattice systems with hydrodynamic coupling and predict that the optimal reaction rate for monodisperse colloidal systems occurs when the volume fraction is ~0.18. Finally, we discuss the application of our model to bimolecular reactions inside cells as well as the dynamics of confined polymers.

  19. Mass and temperature limits for blackbody radiation

    E-Print Network [OSTI]

    Alessandro Pesci

    2006-03-24T23:59:59.000Z

    A spherically symmetric distribution of classical blackbody radiation is considered, at conditions in which gravitational self-interaction effects become not negligible. Static solutions to Einstein field equations are searched for, for each choice of the assumed central energy density. Spherical cavities at thermodynamic equilibrium, i.e. filled with blackbody radiation, are then studied, in particular for what concerns the relation among the mass M of the ball of radiation contained in them and their temperature at center and at the boundary. For these cavities it is shown, in particular, that: i) there is no absolute limit to M as well to their central and boundary temperatures; ii) when radius R is fixed, however, limits exist both for mass and for boundary energy density rho_B: M temperature) of the ball of radiation.

  20. Toxicity Data to Determine Refrigerant Concentration Limits

    SciTech Connect (OSTI)

    Calm, James M.

    2000-09-30T23:59:59.000Z

    This report reviews toxicity data, identifies sources for them, and presents resulting exposure limits for refrigerants for consideration by qualified parties in developing safety guides, standards, codes, and regulations. It outlines a method to calculate an acute toxicity exposure limit (ATEL) and from it a recommended refrigerant concentration limit (RCL) for emergency exposures. The report focuses on acute toxicity with particular attention to lethality, cardiac sensitization, anesthetic and central nervous system effects, and other escape-impairing effects. It addresses R-11, R-12, R-22, R-23, R-113, R-114, R-116, R-123, R-124, R-125, R-134, R-134a, R-E134, R-141b, R-142b, R-143a, R-152a, R-218, R-227ea, R-236fa, R-245ca, R-245fa, R-290, R-500, R-502, R-600a, R-717, and R-744. It summarizes additional data for R-14, R-115, R-170 (ethane), R-C318, R-600 (n-butane), and R-1270 (propylene) to enable calculation of limits for blends incorporating them. The report summarizes the data a nd related safety information, including classifications and flammability data. It also presents a series of tables with proposed ATEL and RCL concentrations-in dimensionless form and the latter also in both metric (SI) and inch-pound (IP) units of measure-for both the cited refrigerants and 66 zerotropic and azeotropic blends. They include common refrigerants, such as R-404A, R-407C, R-410A, and R-507A, as well as others in commercial or developmental status. Appendices provide profiles for the cited single-compound refrigerants and for R-500 and R-502 as well as narrative toxicity summaries for common refrigerants. The report includes an extensive set of references.

  1. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    P. Bernot

    2005-07-13T23:59:59.000Z

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this activity is to predict dissolved concentrations or solubility limits for elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) relevant to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are provided in the form of tabulated functions with pH and log fCO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. Even though selection of an appropriate set of radionuclides documented in Radionuclide Screening (BSC 2002 [DIRS 160059]) includes actinium, transport of Ac is not modeled in the total system performance assessment for the license application (TSPA-LA) model because of its extremely short half-life. Actinium dose is calculated in the TSPA-LA by assuming secular equilibrium with {sup 231}Pa (Section 6.10); therefore, Ac is not analyzed in this report. The output data from this report are fundamental inputs for TSPA-LA used to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for the actinides discussed in this report. These models cover broad ranges of environmental conditions so they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  2. Probabilistic Turing Machine and Landauer Limit

    E-Print Network [OSTI]

    Marco Frasca

    2012-06-04T23:59:59.000Z

    We show the equivalence between a probabilistic Turing machine and the time evolution of a one-dimensional Ising model, the Glauber model in one dimension, equilibrium positions representing the results of computations of the Turing machine. This equivalence permits to map a physical system on a computational system providing in this way an evaluation of the entropy at the end of computation. The result agrees with Landauer limit.

  3. Probabilistic Turing Machine and Landauer Limit

    E-Print Network [OSTI]

    Frasca, Marco

    2012-01-01T23:59:59.000Z

    We show the equivalence between a probabilistic Turing machine and the time evolution of a one-dimensional Ising model, the Glauber model in one dimension, equilibrium positions representing the results of computations of the Turing machine. This equivalence permits to map a physical system on a computational system providing in this way an evaluation of the entropy at the end of computation. The result agrees with Landauer limit.

  4. Ideal Quantum Gases with Planck Scale Limitations

    E-Print Network [OSTI]

    Rainer Collier

    2015-03-14T23:59:59.000Z

    A thermodynamic system of non-interacting quantum particles changes its statistical distribution formulas if there is a universal limitation for the size of energetic quantum leaps (magnitude of quantum leaps smaller than Planck energy). By means of a restriction of the a priori equiprobability postulate one can reach a thermodynamic foundation of these corrected distribution formulas. The number of microstates is determined by means of a suitable counting method and combined with thermodynamics via the Boltzmann principle. The result is that, for particle energies that come close to the Planck energy, the thermodynamic difference between fermion and boson distribution vanishes. Both distributions then approximate a Boltzmann distribution. The wave and particle character of the quantum particles, too, can be influenced by choosing the size of the temperature and particle energy parameters relative to the Planck energy, as you can see from the associated fluctuation formulas. In the case of non-relativistic degeneration, the critical parameters Fermi momentum (fermions) and Einstein temperature (bosons) vanish as soon as the rest energy of the quantum particles reaches the Planck energy. For the Bose-Einstein condensation there exists, in the condensation range, a finite upper limit for the number of particles in the ground state, which is determined by the ratio of Planck mass to the rest mass of the quantum particles. In the relativistic high-temperature range, the energy densities of photon and neutrino radiation have finite limit values, which is of interest with regard to the start of cosmic expansion.

  5. Assessing Possibilities & Limits for Solar Cells

    E-Print Network [OSTI]

    Nayak, Pabitra K; Cahen, David

    2011-01-01T23:59:59.000Z

    What are the solar cell efficiencies that we can strive towards? We show here that several simple criteria, based on cell and module performance data, serve to evaluate and compare all types of today's solar cells. Analyzing these data allows to gauge in how far significant progress can be expected for the various cell types and, most importantly from both the science and technology points of view, if basic bounds, beyond those known today, may exist, that can limit such progress. This is important, because half a century after Shockley and Queisser (SQ) presented limits, based on detailed balance calculations for single absorber solar cells, those are still held to be the only ones, we need to consider; most efforts to go beyond SQ are directed towards attempts to circumvent them, primarily via smart optics, or optoelectronics. After formulating the criteria and analyzing known loss mechanisms, use of such criteria suggests - additional limits for newer types of cells, Organic and Dye-Sensitized ones, and th...

  6. Means for limiting and ameliorating electrode shorting

    DOE Patents [OSTI]

    Van Konynenburg, Richard A. (Livermore, CA); Farmer, Joseph C. (Tracy, CA)

    1999-01-01T23:59:59.000Z

    A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  7. Means for limiting and ameliorating electrode shorting

    SciTech Connect (OSTI)

    Konynenburg, R.A. van; Farmer, J.C.

    1999-11-09T23:59:59.000Z

    A fuse and filter arrangement is described for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  8. Limitations and improvements for harmonic generation measurements

    SciTech Connect (OSTI)

    Best, Steven; Croxford, Anthony; Neild, Simon [Department of Mechanical Engineering, Queens Building, University Walk, Bristol BS8 1TR (United Kingdom)

    2014-02-18T23:59:59.000Z

    A typical acoustic harmonic generation measurement comes with certain limitations. Firstly, the use of the plane wave-based analysis used to extract the nonlinear parameter, ?, ignores the effects of diffraction, attenuation and receiver averaging which are common to most experiments, and may therefore limit the accuracy of a measurement. Secondly, the method usually requires data obtained from a through-transmission type setup, which may not be practical in a field measurement scenario where access to the component is limited. Thirdly, the technique lacks a means of pinpointing areas of damage in a component, as the measured nonlinearity represents an average over the length of signal propagation. Here we describe a three-dimensional model of harmonic generation in a sound beam, which is intended to provide a more realistic representation of a typical experiment. The presence of a reflecting boundary is then incorporated into the model to assess the feasibility of performing single-sided measurements. Experimental validation is provided where possible. Finally, a focusing acoustic source is modelled to provide a theoretical indication of the afforded advantages when the nonlinearity is localized.

  9. Clean Cities ozone air quality attainment and maintenance strategies that employ alternative fuel vehicles, with special emphasis on natural gas and propane

    SciTech Connect (OSTI)

    Santini, D.J.; Saricks, C.L.

    1998-08-04T23:59:59.000Z

    Air quality administrators across the nation are coming under greater pressure to find new strategies for further reducing automotive generated non-methane hydrocarbon (NMHC) and nitrogen oxide (NOx) emissions. The US Environmental Protection Agency (EPA) has established stringent emission reduction requirements for ozone non-attainment areas that have driven the vehicle industry to engineer vehicles meeting dramatically tightened standards. This paper describes an interim method for including alternative-fueled vehicles (AFVs) in the mix of strategies to achieve local and regional improvements in ozone air quality. This method could be used until EPA can develop the Mobile series of emissions estimation models to include AFVs and until such time that detailed work on AFV emissions totals by air quality planners and emissions inventory builders is warranted. The paper first describes the challenges confronting almost every effort to include AFVs in targeted emissions reduction programs, but points out that within these challenges resides an opportunity. Next, it discusses some basic relationships in the formation of ambient ozone from precursor emissions. It then describes several of the salient provisions of EPA`s new voluntary emissions initiative, which is called the Voluntary Mobile Source Emissions Reduction Program (VMEP). Recent emissions test data comparing gaseous-fuel light-duty AFVs with their gasoline-fueled counterparts is examined to estimate percent emissions reductions achievable with CNG and LPG vehicles. Examples of calculated MOBILE5b emission rates that would be used for summer ozone season planning purposes by an individual Air Quality Control Region (AQCR) are provided. A method is suggested for employing these data to compute appropriate voluntary emission reduction credits where such (lighter) AFVs would be acquired. It also points out, but does not quantify, the substantial reduction credits potentially achievable by substituting gaseous-fueled for gasoline-fueled heavy-duty vehicles. Finally, it raises and expands on the relevance of AFVs and their deployment to some other provisions embedded in EPA`s current guidance for implementing 1-hour NAAQS--standards which currently remain in effect--as tools to provide immediate reductions in ozone, without waiting for promised future clean technologies.

  10. Karnataka Power Corporation Limited and National Thermal Power...

    Open Energy Info (EERE)

    Limited and National Thermal Power Corporation JV Jump to: navigation, search Name: Karnataka Power Corporation Limited and National Thermal Power Corporation JV Place: India...

  11. Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolyte Fuel Cell Lifetime Limitations: The Role of Electrocatalyst Degradation Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role of Electrocatalyst Degradation...

  12. (Expired) Nationwide Limited Public Interest Waiver for LED Lighting...

    Energy Savers [EERE]

    (Expired) Nationwide Limited Public Interest Waiver for LED Lighting and HVAC Units: February 11, 2010 (Expired) Nationwide Limited Public Interest Waiver for LED Lighting and HVAC...

  13. Thickness dependent self limiting 1-D tin oxide nanowire arrays...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dependent self limiting 1-D tin oxide nanowire arrays by nanosecond pulsed laser irradiation. Thickness dependent self limiting 1-D tin oxide nanowire arrays by nanosecond pulsed...

  14. Pulmonary function and symptom responses after 6. 6-hour exposure to 0. 12-ppm ozone with moderate exercise (journal version)

    SciTech Connect (OSTI)

    Folinsbee, L.J.; Horstman, D.H.; McDonnell, W.F.

    1988-01-01T23:59:59.000Z

    Episodes occasionally occur when ambient ozone (O/sub 3/) levels remain at or near 0.12 ppm for more than 6 h. The hypothesis that prolonged exposure to 0.12 ppm O/sub 3/ would result in progressively larger changes in respiratory function and symptoms over time was tested. Ten nonsmoking males (18-35 yr) were exposed once to clear air (CA) and once to 0.12 pp, O/sub 3/ for 6.75 h. Exposures consisted of six 50-min exercise periods, each followed by 10-min rest and measurement; a 45-min lunch period followed the third exercise period. Exercise ventilation averaged approximately 40 1/min. Forced expiratory and inspiratory spirometry and respiratory symptoms were measured prior to exposure and after each exercise. Increases in the symptom ratings of cough and pain on deep inspiration were observed with O/sub 3/ exposure but not with CA. Airway reactivity to methacholine was approximately doubled following O/sub 3/ exposure. Spirometry results indicate that prolonged exposure to 0.12 ppm O/sub 3/ results in a marked increase in non-specific airway reactivity and progressive changes in respiratory function.

  15. Limiter H-mode experiments on TFTR

    SciTech Connect (OSTI)

    Bush, C.E. (Oak Ridge National Lab., TN (USA)); Bretz, N.L.; Fredrickson, E.D.; McGuire, K.M.; Nazikian, R.; Park, H.K.; Schivell, J.; Taylor, G.; Bitter, M.; Budny, R.; Cohen, S.A.; Kilpatrick, S.J.; LeBlanc, B.; Manos, D.M.; Meade, D.; Paul, S.F.; Scott, S.D.; Stratton, B.C.; Synakowski, E.J.; Towner, H.H.; Wieland, R.M.; Arunasalam, V.; Bateman, G.; Bell, M.G.; Bell, R.; Boivin, R.; Cavallo, A.; Cheng, C.Z.; Chu, T.K.; Co

    1991-05-01T23:59:59.000Z

    Limiter H-modes with centrally peaked density profiles have been obtained in TFTR using a highly conditioned graphite limiter. The transition to these centrally peaked H-modes takes place from the supershot to the H-mode rather than the usual L- to H-mode transition observed on other tokamaks. Bidirectional beam heating is required to induce the transition. Density peaking factors, n{sub e}(0)/, greater than 2.3 are obtained and at the same time the H-mode characteristics are similar to those of limiter H-modes on other tokamaks, while the global confinement, {tau}{sub E}, can be >2.5 times L-mode scaling. The transport analysis of the data shows that transport in these H-modes is similar to that of supershots within the inner 0.6 m core of the plasma, but the stored electron energy (calculated using measured values of T{sub e} and n{sub e}) is higher for the H-mode at the plasma edge. Microwave scattering data for the edge plasma shows broad spectra at k = 5.5 cm{sup {minus}1} which begin at the drop in D{sub {alpha}} radiation and are strongly shifted in the electron diamagnetic drift direction. At the same time, beam emission spectroscopy (BES) shows a coherent mode near the boundary which propagates in the ion direction with m = 15--20 at 20--30 kHz. During the ELM event these apparent rotations cease and Mirnov fluctuations in the frequency range of 50--500 kHz increase in intensity. 16 refs., 8 figs.

  16. Unitary limit in cross Andreev transport

    E-Print Network [OSTI]

    I. A. Sadovskyy; G. B. Lesovik; V. M. Vinokur

    2014-12-28T23:59:59.000Z

    Crossed Andreev reflection (CAR) in which Cooper pair splits into two spin- and energy entangled electrons that leave a superconductor through respective spatially separated leads is one of the most promising approaches to generating pairs of entangled electrons. However, while the conventional (local) Andreev reflection occurs with the probability of unity, the probability of CAR is significantly suppressed. Here we propose a hybrid normal metal-superconductor setup that enables achieving a unitary limit of cross Andreev transport, i.e. CAR with the probability of unity thus offering the outcome of the entangled electrons with the 100% efficiency.

  17. Torque limited drive for manual valves

    DOE Patents [OSTI]

    Elliott, Philip G. (Metropolis, IL); Underwood, Daniel E. (Paducah, KY)

    1989-01-01T23:59:59.000Z

    The present invention is directed to a torque-limiting handwheel device for preventing manual valves from being damaged due to the application of excessive torque during the opening or closing operation of the valves. Torque can only be applied when ridges in the handwheel assembly engage in channels machined in the face of the baseplate. The amount of torque required for disengagement of the ridges from the channels is determined by the force exerted by various Bellville springs and the inclination of the side faces of the channels.

  18. Radiation from charges in the continuum limit

    SciTech Connect (OSTI)

    Ianconescu, Reuven [Shenkar College of Engineering and Design, Ramat Gan 52526 (Israel)

    2013-06-15T23:59:59.000Z

    It is known that an accelerating charge radiates according to Larmor formula. On the other hand, any DC current following a curvilinear path, consists of accelerating charges, but in such case the radiated power is 0. The scope of this paper is to analyze and quantify how a system of charges goes from a radiating state to a non radiating state when the charges distribution goes to the continuum limit. Understanding this is important from the theoretical point of view and the results of this work are applicable to particle accelerator, cyclotron and other high energy devices.

  19. Transcending the Limits of Turing Computability

    E-Print Network [OSTI]

    Vadim A. Adamyan; Cristian S. Calude; Boris S. Pavlov

    2003-05-11T23:59:59.000Z

    Hypercomputation or super-Turing computation is a ``computation'' that transcends the limit imposed by Turing's model of computability. The field still faces some basic questions, technical (can we mathematically and/or physically build a hypercomputer?), cognitive (can hypercomputers realize the AI dream?), philosophical (is thinking more than computing?). The aim of this paper is to address the question: can we mathematically build a hypercomputer? We will discuss the solutions of the Infinite Merchant Problem, a decision problem equivalent to the Halting Problem, based on results obtained in \\cite{Coins,acp}. The accent will be on the new computational technique and results rather than formal proofs.

  20. New limits for neutrinoless tau decays

    E-Print Network [OSTI]

    Ammar, Raymond G.; Baringer, Philip S.; Bean, Alice; Besson, David Zeke; Coppage, Don; Darling, C.; Davis, Robin E. P.; Kotov, S.; Kravchenko, I.; Kwak, Nowhan; Zhou, L.

    1998-05-01T23:59:59.000Z

    double beta decays, neutrino oscillations, Z!l11l22 decays, and other rare pro- cesses. In particular, there are strict limits on muon neutrino- less decays: B(m!eg),4.9310211 and B(m!eee),2.4 310212 at 90% confidence level @18#. However, lepton num- ber... particles and on the new coupling constants. The most optimistic branching fraction predictions are at the level of about 1026. Constraints on lepton flavor violation come from studies of rare and forbidden K , p, and m decays, e-m conversions, neutrinoless...