National Library of Energy BETA

Sample records for ground-level ozone limits

  1. Potential for savings in compliance costs for reducing ground-level ozone possible by instituting seasonal versus annual nitric oxide emission limits

    SciTech Connect (OSTI)

    Lookman, A.A.

    1996-12-31

    Ground-level ozone is formed in the atmosphere from its precursor emissions, namely nitric oxide (NO{sub x}) and volatile organic compounds (VOC), with its rate of formation dependent on atmospheric conditions. Since ozone levels tend to be highest during the summer months, seasonal controls of precursors have been suggested as a means of reducing the costs of decreasing ozone concentrations to acceptable levels. This paper attempts to quantify what the potential savings if seasonal control were instituted for coal-fired power plants, assuming that only commercially available NO{sub x} control technologies are used. Cost savings through seasonal control is measured by calculating the total annualized cost of NO{sub x} removal at a given amount of seasonal control for different target levels of annual control. For this study, it is assumed that trading of NO{sub x} emissions will be allowed, as has been proposed by the Ozone Transportation Commission (OTC). The problem has been posed as a binary integer linear programming problem, with decision variables being which control to use at each power plant. The results indicate that requiring annual limits which are lower than seasonal limits can substantially reduce compliance costs. These savings occur because requiring stringent compliance only on a seasonal basis allows power plants to use control methods for which the variable costs are paid for only part of the year, and through the use of gas-based controls, which are much cheaper to operate in the summer months.

  2. THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, Carol; Osterberg, Paul; Johnson, Tom; Frawely, Thomas

    2013-01-23

    The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

  3. THE EFFECT OF THE PRESENCE OF OZONE ON THE LOWER FLAMMABILITY LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, C.

    2012-01-12

    The Enhanced Chemical Cleaning (ECC) process uses ozone to effect the oxidation of metal oxalates produced during the dissolution of sludge in the Savannah River Site (SRS) waste tanks. The ozone reacts with the metal oxalates to form metal oxide and hydroxide precipitants, and the CO{sub 2}, O{sub 2}, H{sub 2}O and any unreacted O{sub 3} gases are discharged into the vapor space. In addition to the non-radioactive metals in the waste, however, the SRS radioactive waste also contains a variety of radionuclides, hence, hydrogen gas is also present in the vapor space of the ECC system. Because hydrogen is flammable, the impact of this resultant gas stream on the Lower Flammability Limit (LFL) of hydrogen must be understood for all possible operating scenarios of both normal and off-normal situations, with particular emphasis at the elevated temperatures and pressures of the typical ECC operating conditions. Oxygen is a known accelerant in combustion reactions, but while there are data associated with the behavior of hydrogen/oxygen environments, recent, relevant studies addressing the effect of ozone on the flammability limit of hydrogen proved scarce. Further, discussions with industry experts verified the absence of data in this area and indicated that laboratory testing, specific to defined operating parameters, was needed to comprehensively address the issue. Testing was thus designed and commissioned to provide the data necessary to support safety related considerations for the ECC process. A test matrix was developed to envelope the bounding conditions considered credible during ECC processing. Each test consists of combining a gas stream of high purity hydrogen with a gas stream comprised of a specified mixture of ozone and oxygen in a temperature and pressure regulated chamber such that the relative compositions of the two streams are controlled. The gases are then stirred to obtain a homogeneous mixture and ignition attempted by applying 10J of energy to a fuse wire. A gas combination is considered flammable when a pressure rise of 7% of the initial absolute pressure is observed. The specified testing methodology is consistent with guidelines established in ASTM E-918-83 (2005) 'Standard Practices for Determining Limits of Flammability of Chemicals at Elevated Temperature and Pressure'.

  4. Limiter

    DOE Patents [OSTI]

    Cohen, S.A.; Hosea, J.C.; Timberlake, J.R.

    1984-10-19

    A limiter with a specially contoured front face is provided. The front face of the limiter (the plasma-side face) is flat with a central indentation. In addition, the limiter shape is cylindrically symmetric so that the limiter can be rotated for greater heat distribution. This limiter shape accommodates the various power scrape-off distances lambda p, which depend on the parallel velocity, V/sub parallel/, of the impacting particles.

  5. Limiter

    DOE Patents [OSTI]

    Cohen, Samuel A.; Hosea, Joel C.; Timberlake, John R.

    1986-01-01

    A limiter with a specially contoured front face accommodates the various power scrape-off distances .lambda..sub.p, which depend on the parallel velocity, V.sub..parallel., of the impacting particles. The front face of the limiter (the plasma-side face) is flat with a central indentation. In addition, the limiter shape is cylindrically symmetric so that the limiter can be rotated for greater heat distribution.

  6. Measurement of the solar ultraviolet radiation at ground level in Bangi, Malaysia

    SciTech Connect (OSTI)

    Aljawi, Ohoud; Gopir, Geri; Duay, Abdul Basit

    2015-04-24

    Understanding the amount of ultraviolet (UV) radiation received by human, plant, and animal organisms near the earth’s surface is important to a wide range of fields such as cancer research, agriculture and forestry. The solar ultraviolet spectral irradiance at ground level was measured using the Avantes spectrometer for the period of January to March 2014 at Bangi (2°55´N, 101°46´E, 50 m above sea level) in Malaysia. These data were used to estimate the diurnal variation of UV irradiance (300 – 400 nm). The maximum irradiance of UV radiation was 45 W m{sup −2} on horizontal surface. The maximum irradiance of UV received in the local noon time, and the minimum values of UV irradiance was received in the local morning time. It is found a bigger value of UV radiation was observed on clear sky in January. The estimation of daily flux average of UV irradiance was (921± 91) kJ m{sup −2}.

  7. GROUND LEVEL ENHANCEMENT IN THE 2014 JANUARY 6 SOLAR ENERGETIC PARTICLE EVENT

    SciTech Connect (OSTI)

    Thakur, N.; Gopalswamy, N.; Xie, H.; Mkel, P.; Yashiro, S.; Akiyama, S.; Davila, J. M.

    2014-07-20

    We present a study of the 2014 January 6 solar energetic particle event which produced a small ground level enhancement (GLE), making it the second GLE of this unusual solar cycle 24. This event was primarily observed by the South Pole neutron monitors (increase of ?2.5%) while a few other neutron monitors recorded smaller increases. The associated coronal mass ejection (CME) originated behind the western limb and had a speed of 1960kms{sup 1}. The height of the CME at the start of the associated metric type II radio burst, which indicates the formation of a strong shock, was measured to be 1.61 Rs using a direct image from STEREO-A/EUVI. The CME height at the time of the GLE particle release (determined using the South Pole neutron monitor data) was directly measured as 2.96 Rs based on STEREO-A/COR1 white-light observations. These CME heights are consistent with those obtained for GLE71, the only other GLE of the current cycle, as well as cycle-23 GLEs derived using back-extrapolation. GLE72 is of special interest because it is one of only two GLEs of cycle 24, one of two behind-the-limb GLEs, and one of the two smallest GLEs of cycles 23 and 24.

  8. GIANT GROUND LEVEL ENHANCEMENT OF RELATIVISTIC SOLAR PROTONS ON 2005 JANUARY 20. I. SPACESHIP EARTH OBSERVATIONS

    SciTech Connect (OSTI)

    Bieber, J. W.; Clem, J.; Evenson, P.; Pyle, R.; Saiz, A.; Ruffolo, D. E-mail: clem@bartol.udel.edu E-mail: pyle@bartol.udel.edu E-mail: david.ruf@mahidol.ac.th

    2013-07-10

    A ground level enhancement (GLE) is a solar event that accelerates ions (mostly protons) to GeV range energies in such great numbers that ground-based detectors, such as neutron monitors, observe their showers in Earth's atmosphere above the Galactic cosmic ray background. GLEs are of practical interest because an enhanced relativistic ion flux poses a hazard to astronauts, air crews, and aircraft electronics, and provides the earliest direct indication of an impending space radiation storm. The giant GLE of 2005 January 20 was the second largest on record (and largest since 1956), with up to 4200% count rate enhancement at sea level. We analyzed data from the Spaceship Earth network, supplemented to comprise 13 polar neutron monitor stations with distinct asymptotic viewing directions and Polar Bare neutron counters at South Pole, to determine the time evolution of the relativistic proton density, energy spectrum, and three-dimensional directional distribution. We identify two energy-dispersive peaks, indicating two solar injections. The relativistic solar protons were initially strongly beamed, with a peak maximum-to-minimum anisotropy ratio over 1000:1. The directional distribution is characterized by an axis of symmetry, determined independently for each minute of data, whose angle from the magnetic field slowly varied from about 60 Degree-Sign to low values and then rose to about 90 Degree-Sign . The extremely high relativistic proton flux from certain directions allowed 10 s tracking of count rates, revealing fluctuations of period {approx}> 2 minutes with up to 50% fractional changes, which we attribute to fluctuations in the axis of symmetry.

  9. ARM - Measurement - Ozone Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Ozone Concentration The atmospheric concentration or volume mixing ratio (mole fraction) of Ozone Categories Atmospheric State Instruments The above measurement is...

  10. Coordinated NO{sub x} control strategies: Phase II Title IV, ozone transport region and ozone transport assessment group

    SciTech Connect (OSTI)

    Frazier, W.F.; Dunn, R.M.; Baublis, D.C.

    1998-12-31

    Many electric utilities are faced with future nitrogen oxides (NO{sub x}) reduction requirements. In some instances, these utilities will be affected by multiple regulatory programs. For example, numerous fossil fired plants must comply with Phase II of Title IV of the Clean Air Act Amendments of 1990 (CAAA), state NO{sub x} rules as a result of the recommendations of the Ozone Transport Commission (OTC) and future requirements of the Proposed Rule for Reducing Regional Transport of Ground-Level Ozone (Ozone Transport SIP Rulemaking). This paper provides an overview of NO{sub x} regulatory programs, NO{sub x} compliance planning concepts, and NO{sub x} control technology options that could be components of an optimized compliance strategy.

  11. ARM - Measurement - Ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ozone Ozone measurements are given in Dobson units and are integers with 3...

  12. ARM - Campaign Instrument - ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsozone Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Ozone Monitor (OZONE) Instrument...

  13. Tropospheric ozone in east Asia

    SciTech Connect (OSTI)

    Phadnis, M.J.

    1996-12-31

    An analysis of the observed data for the tropospheric ozone at mid latitudes in east Asia is done. There are three ways by which the tropospheric ozone is calculated, namely: (1) Ozonesonde measurements, (2) Fishman`s method of Residual Ozone and (3) TOMS measurements - an indirect method of calculating tropospheric ozone. In addition the surface ozone values at the network sites in Japan is also considered. The analysis of data is carried out for a period of twelve years from 1979 to 1991. In general it is observed that the tropospheric ozone is more in summer than winter, obviously because of the larger tropopause height in summer. On an average for the period of the analysis, the ozone values are at a high of about 60 DU (dobson units). While in winter the values go down to around 30 DU. Also a time series analysis shows an increasing trend in the values over the years. The ozonesonde values are correlated more to the TOMS tropospheric ozone values. For the stations analyzed in Japan, the TOMS tropospheric ozone values are generally greater than the ozonesonde values. The analysis of the average monthly surface ozone in Japan shows highs in spring and lows in summer. This can be attributed to movement of pollutant laden fronts towards Japan during spring. The highs for surface ozone are about 50 DU while the lows are around 20 DU.

  14. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  15. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F.; Brown, John D.; Whinnery, Jr., LeRoy L.

    1999-01-01

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  16. Ozone Risk Assessment Utilities

    Energy Science and Technology Software Center (OSTI)

    1999-08-10

    ORAMUS is a user-friendly, menu-driven software system that calculates and displays user-selected risk estimates for health effects attributable to short-term exposure to tropospheric ozone. Inputs to the risk assessment are estimates of exposure to ozone and exposure-response relationships to produce overall risk estimates in the form of probability distributions. Three fundamental models are included: headcount risk, benchmark risk, and hospital admissions. Exposure-response relationships are based on results of controlled human exposure studies. Exposure estimates aremore » based on the EPA''s probabilistic national ambient air quality standards (NAAQS) exposure model, pNEM/Osub3, which simulates air quality associated with attainment of alternative NAAQS. Using ORAMUS, risk results for 27 air quality scenarios, air quality in 9 urban areas, 33 health endpoints, and 4 chronic health endpoints can be calculated.« less

  17. Ozone transport commission developments

    SciTech Connect (OSTI)

    Joyce, K.M.

    1995-08-01

    On September 27, 1994, the states of the Ozone Transport Commission (OTC) signed an important memorandum of understanding (MOU) agreeing to develop a regional strategy for controlling stationary sources of nitrogen oxide emissions. Specifically, the states of the Ozone Transport Region, OTR, agreed to propose regulations for the control of NOx emissions from boilers and other indirect heat exchangers with a maximum gross heat input rate of at least 250 million BTU per hour. The Ozone Transport Region was divided into Inner, Outer and Northern Zones. States in the Outer Zone agreed to reduce NOx emissions by 55%. States in the Inner Zone agreed to reduce NOx emissions 65%. Facilities in both zones have the option to emit NOx at a rate no greater than 0.2 pounds per million Btu by May 1, 1999. This option provides fairness for the gas-fired plants which already have relatively low NOx emissions. Additionally, States in the Inner and Outer Zones agreed to reduce their NOx emissions by 75% or to emit NOx at a rate no greater than 0.15 pounds per million BTU by May 1, 2003. The Northern Zone States agree to reduce their rate of NOx emissions by 55% from base year levels by May 1, 2003, or to emit NOx at a rate no greater than 0.2 pounds per million BTU. As part of this MOU, States also agreed to develop a regionwide trading mechanism to provide a cost-effective mechanism for implementing the reductions.

  18. Valuing the ozone-related health benefits of methane emission controls

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarofim, Marcus C.; Waldhoff, Stephanie T.; Anenberg, Susan C.

    2015-06-29

    Methane is a greenhouse gas that oxidizes to form ground-level ozone, itself a greenhouse gas and a health-harmful air pollutant. Reducing methane emissions will both slow anthropogenic climate change and reduce ozone-related mortality. We estimate the benefits of reducing methane emissions anywhere in the world for ozone-related premature mortality globally and for eight geographic regions. Our methods are consistent with those used by the US Government to estimate the social cost of carbon (SCC). We find that the global short- and long-term premature mortality benefits due to reduced ozone production from methane mitigation are (2011) $790 and $1775 per tonnemore » methane, respectively. These correspond to approximately 70 and 150 % of the valuation of methane’s global climate impacts using the SCC after extrapolating from carbon dioxide to methane using global warming potential estimates. Results for monetized benefits are sensitive to a number of factors, particularly the choice of elasticity to income growth used when calculating the value of a statistical life. The benefits increase for emission years further in the future. Regionally, most of the global mortality benefits accrue in Asia, but 10 % accrue in the United States. As a result, this methodology can be used to assess the benefits of methane emission reductions anywhere in the world, including those achieved by national and multinational policies.« less

  19. Nonaqueous ozonation of vulcanized rubber

    DOE Patents [OSTI]

    Serkiz, Steven M.

    1999-01-01

    A process and resulting product is provided in which a solid particulate, such as vulcanized crumb rubber, has the surface functional groups oxidized by ozonation using a nonpolar solvent. The ozonation process renders the treated crumb rubber more suitable for use in new rubber formulations. As a result, larger loading levels of the treated crumb rubber can be used in new rubber mixtures.

  20. Stratospheric ozone protection: The Montreal Protocol and Title VI of the Clean Air Act Amendments of 1990

    SciTech Connect (OSTI)

    Babst, C.R. III

    1993-08-01

    The stratospheric ozone layer protects the surface of the Earth from harmful ultraviolet (UV-B) radiation, which has been causally linked to skin cancer and cataracts, suppression of the human immune system, damage to crops and aquatic organisms, the formation of ground-level zone and the rapid weathering of outdoor plastics. In recent years, scientists have observed a significant deterioration of the ozone layer, particularly over the poles, but increasingly over populated regions as well. This deterioration has been attributed to the atmospheric release of certain man-made halocarbons, including chlorofluorocarbons (CFCs), halons, methyl chloroform and carbon tetrachloride. Once used extensively as propellants for aerosol sprays (but generally banned for such purposes since 1978), CFCs are widely used today as refrigerants, foams and solvents. All of these chlorinated (CFC, methyl chloroform and carbon tetrachloride) and brominated (halon) compounds are classified for regulatory purposes as Class I substances because of their significant ozone-depleting potential. Hydrochlorofluorocarbons (HCFCs), developed as alternatives to CFCs and halons for many different applications, have been classified for regulatory purposes as Class II substances because of their relatively less destructive impact on stratospheric ozone. This paper describes the following regulations to reduce destruction of the ozone layer: the Montreal Protocol; Title VI of the Clean air Act Amendments of 1990; Accelerated Phase-out schedules developed by the countries which signed the Montreal Protocol; Use restrictions; Recycling and Emission reduction requirements; Servicing of motor vehicle air conditions; ban on nonessential products; labeling requirements; safe alternatives. 6 refs.

  1. Promising Technology: Ozone Laundry System for Multiload Clothes Washers

    Broader source: Energy.gov [DOE]

    These laundry systems use ozone as the chemical cleaning agent. The system generates ozone by electrifying oxygen in the air, and then dissolves the ozone in water.

  2. Impacts from a fossil fuel power plant on ozone levels in Memphis, Tennessee

    SciTech Connect (OSTI)

    Mueller, S.F.; Bailey, E.M.

    1998-12-31

    The Tennessee Valley Authority (TVA) Allen power plant is located on the Mississippi River in the southwest corner of Memphis, Tennessee. Allen has three coal-fired cyclone boilers with a rated capacity of 272 MW each. It is a Phase 2 plant under Title IV of the Clean Air Act and is the largest single source of NO{sub x} in the Memphis area. TVA plans to reduce Allen NOx emissions through a combination of burning low-sulfur coal (which has the benefit of reducing NO{sub x} emissions while also reducing SO{sub 2} emissions) and installing gas re-burn technology. A modeling study using the SAI, Inc., UAM-V photochemical model was conducted to examine the potential impacts of NO{sub x} reductions on ozone levels in the Memphis area. A series of four model simulations were made in which different Allen emissions scenarios were examined. The focus period of the photochemical modeling was 11--14 July 1995 when measurements in and near Memphis indicated peak hourly ozone levels of 135--140 ppb. This analysis primarily examined computed impacts within 50 km of Memphis. Allen was computed to contribute as much as 20--30 ppb to ground ozone levels 20-50 km downwind using its NO{sub x} emission rate before Title IV compliance. After compliance it was computed to contribute only about 10--20 ppb. At the same time, maximum daily ozone reductions due to Allen NO{sub x} titration of ozone were between 30 and 60 ppb. These benefits will be reduced by 30--50% after Title IV compliance, and are expected to occur within 30 km of the plant. More model grid cells indicated dis-benefits (net ground-level ozone increases) than benefits on three of the four episode days using the Title IV compliance emission rate. Significant ozone dis-benefits were expected because of the well-documented NO titration of ozone within plumes having a high ratio of NO to volatile organic compounds.

  3. ARM - Measurement - Ozone Column Abundance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Column Abundance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ozone Column Abundance The vertically integrated amount of ozone (commonly measured in Dobson Unit, 1 DU = 134 mmol/m^2) Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  4. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    SciTech Connect (OSTI)

    Jin, Ling; Tonse, Shaheen; Cohan, Daniel S.; Mao, Xiaoling; Harley, Robert A.; Brown, Nancy J.

    2009-05-15

    CMAQ-HDDM is used to determine spatial and temporal variations in ozone limiting reagents and local vs upwind source contributions for an air pollution episode in Central California. We developed a first- and second- order sensitivity analysis approach with the Decoupled Direct Method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a five-day ozone episode (29th July-3rd Aug, 2000). Despite considerable spatial variations, nitrogen oxides (NO{sub x}) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8-hr ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1-hr ozone standard. Inter-basin source contributions of NO{sub x} emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NO{sub x} and AVOC, and the rate coefficient of the OH + NO{sub 2} termination reaction, have the greatest effect on first-order ozone responses to changes in NO{sub x} emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

  5. Relation between Atmospheric Ozone and Geomagnetic Disturbances...

    Office of Scientific and Technical Information (OSTI)

    This involves a decrease of ozone in the 50 to 65 deg N region and an increase south of 50 deg N. Two or three days after the storm, the ozone amount increases in the 50 to 65 deg ...

  6. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  7. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru

    2000-01-01

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  8. Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion

    Office of Scientific and Technical Information (OSTI)

    Prize-winning Research, Massachusetts Institute of Technology (MIT) The Science and Policies of the Ozone Layer -- A Historical Perspective, IDEaS - Nobel Laureate Mario J....

  9. Ozone contactor hydraulic considerations in meeting CT disinfection...

    Office of Scientific and Technical Information (OSTI)

    Optimization of ozone dose and contact time for CT calculations was performed in the pilot plant. Operational guidelines for the application of ozone in Union Hills pilot plant ...

  10. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment

  11. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment 2003 DEER Conference ...

  12. Reformulated Gasoline Use Under the 8-Hour Ozone Rule

    Reports and Publications (EIA)

    2002-01-01

    This paper focuses on the impact on gasoline price and supply when additional ozone non-attainment areas come under the new 8-hour ozone standard.

  13. Effect of Ventilation Strategies on Residential Ozone Levels...

    Office of Scientific and Technical Information (OSTI)

    Effect of Ventilation Strategies on Residential Ozone Levels Citation Details In-Document Search Title: Effect of Ventilation Strategies on Residential Ozone Levels You are...

  14. Effect of Ventilation Strategies on Residential Ozone Levels...

    Office of Scientific and Technical Information (OSTI)

    Effect of Ventilation Strategies on Residential Ozone Levels Citation Details In-Document Search Title: Effect of Ventilation Strategies on Residential Ozone Levels Authors:...

  15. Reactivity of Ozone with Solid Potassium Iodide Investigated...

    Office of Scientific and Technical Information (OSTI)

    Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy Citation Details In-Document Search Title: Reactivity of Ozone with Solid Potassium...

  16. Study of air pollution: Effects of ozone on neuropeptide-mediated responses in human subjects. Final report

    SciTech Connect (OSTI)

    Boushey, H.A.

    1991-11-01

    The study examined the hypothesis that ozone inactivates the enzyme, neutral endopeptidase, responsible for limiting the effects of neuropeptides released from afferent nerve endings. Cough response of capsaicin solution delivered from a nebulizer at 2 min. intervals until two or more coughs were produced. Other endpoints measured included irritative symptoms as rated by the subjects on a nonparametric scale, spirometry, of each concentration of ozone were compared to those of filtered air in a single-blind randomized sequence. The results indicate that a 2 h. exposure to 0.4 ppm of ozone with intermittent light exercise alters the sensitivity of airway nerves that mediate the cough response to inhaled materials. This dose of ozone also caused a change in FEV1. A lower level of ozone, 0.02 ppm, caused a change in neither cough threshold nor FEV1, even when the duration of exposure was extended to three hours. The findings are consistent with the author's hypothesis that ozone may sensitize nerve endings in the airways by inactivating neutral endopeptidase, an enzyme that regulates their activity, but they do not demonstrate that directly examining an effect directly mediated by airway nerves allows detection of effects of ozone at doses below those causing effects detected by standard tests of pulmonary function.

  17. Thermo Scientific Ozone Analyzer Instrument Handbook (Technical...

    Office of Scientific and Technical Information (OSTI)

    The primary measurement output from the Thermo Scientific Ozone Analyzer is the concentration of the analyte (O3) reported at 1-s resolution in units of ppbv in ambient air. Note ...

  18. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Broader source: Energy.gov (indexed) [DOE]

    Ozone Formation as a Function of NOx Reductions Summary and Implications for Air Quality Impacts Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S.

  19. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Iron Catalysis in Oxidations by Ozone Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Ozone is used commercially for treatment of potable and non-potable water, and as an industrial oxidant. ISU and Ames Laboratory researchers have developed a method for using iron in ozone oxidation that significantly improves the speed of oxidation reactions. Description Ozone is recognized as potent and effective oxidizing agent, and has a

  20. Relation between Atmospheric Ozone and Geomagnetic Disturbances (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Relation between Atmospheric Ozone and Geomagnetic Disturbances Citation Details In-Document Search Title: Relation between Atmospheric Ozone and Geomagnetic Disturbances Results are given for a study of the behavior of the mean meridional distribution of total ozone over 15 European stations (38 to 78 deg N) during severe magnetic storms. The storms studied were 14 severe geomagnetic disturbance; in 1957, 1958, and 1959, and the ozone distributions were studied

  1. Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion

    Office of Scientific and Technical Information (OSTI)

    Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion Resources with Additional Information In 1973 Mario Molina ... was a postdoctoral researcher working in the laboratory of F. Sherwood Rowland at the University of California at Irvine ... when he made an unsettling discovery. He had been investigating a class of compounds called chlorofluorocarbons, or CFCs. CFCs were used as refrigerants, aerosol sprays, and in making plastic foams. Molina wondered what happened to them once they

  2. Ozone contactor hydraulic considerations in meeting CT disinfection

    Office of Scientific and Technical Information (OSTI)

    requirements (Journal Article) | SciTech Connect Ozone contactor hydraulic considerations in meeting CT disinfection requirements Citation Details In-Document Search Title: Ozone contactor hydraulic considerations in meeting CT disinfection requirements Tracer studies were performed in bench and pilot scale ozone diffusion contactors to determine actual contact times for the bench and pilot scale units and to characterize the flow pattern through these reactors. It was recognized that the

  3. DOE SC ARM TR 179 Thermo Scientific Ozone Analyzer Instrument...

    Office of Scientific and Technical Information (OSTI)

    ... data increment. Ozone - Mixing volume of O3 in ambient air (no water vapor correction). ... However, the supplied pressure regulator only supplies consistent gauge pressure, not ...

  4. Ozone Removal by Filters Containing Activated Carbon: A Pilot...

    Office of Scientific and Technical Information (OSTI)

    in a commercial building heating, ventilating, and air conditioning (HVAC) system. ... measurements of ozone concentrations in the air upstream and downstream of the filters. ...

  5. Ozone depletion, developing countries, and human rights: Seeking better ground on which to fight for protection of the ozone layer

    SciTech Connect (OSTI)

    Williams, V.

    1995-12-31

    I urge you not to take a complacent view of the situation. The state of depletion of the ozone layer continues to be alarming... In February, 1993, the ozone levels over North America and most of Europe were 20 percent below normal... Even now, millions of tons of CFC [chlorofluorocarbon] products are en route to their fatal stratospheric rendezvous... This exponential increase calls for increased reflection on the state of the ozone layer and calls for bold decisions.

  6. Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Weekend Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. ...

  7. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  8. ARM - Field Campaign - 1999 Northeast Corridor Ozone & Particulate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : 1999 Northeast Corridor Ozone & Particulate Study 1999.07.23 - 1999.08.11 Lead...

  9. Process-scale modeling of elevated wintertime ozone in Wyoming.

    SciTech Connect (OSTI)

    Kotamarthi, V. R.; Holdridge, D. J.; Environmental Science Division

    2007-12-31

    Measurements of meteorological variables and trace gas concentrations, provided by the Wyoming Department of Environmental Quality for Daniel, Jonah, and Boulder Counties in the state of Wyoming, were analyzed for this project. The data indicate that highest ozone concentrations were observed at temperatures of -10 C to 0 C, at low wind speeds of about 5 mph. The median values for nitrogen oxides (NOx) during these episodes ranged between 10 ppbv and 20 ppbv (parts per billion by volume). Measurements of volatile organic compounds (VOCs) during these periods were insufficient for quantitative analysis. The few available VOCs measurements indicated unusually high levels of alkanes and aromatics and low levels of alkenes. In addition, the column ozone concentration during one of the high-ozone episodes was low, on the order of 250 DU (Dobson unit) as compared to a normal column ozone concentration of approximately 300-325 DU during spring for this region. Analysis of this observation was outside the scope of this project. The data analysis reported here was used to establish criteria for making a large number of sensitivity calculations through use of a box photochemical model. Two different VOCs lumping schemes, RACM and SAPRC-98, were used for the calculations. Calculations based on this data analysis indicated that the ozone mixing ratios are sensitive to (a) surface albedo, (b) column ozone, (c) NOx mixing ratios, and (d) available terminal olefins. The RACM model showed a large response to an increase in lumped species containing propane that was not reproduced by the SAPRC scheme, which models propane as a nearly independent species. The rest of the VOCs produced similar changes in ozone in both schemes. In general, if one assumes that measured VOCs are fairly representative of the conditions at these locations, sufficient precursors might be available to produce ozone in the range of 60-80 ppbv under the conditions modeled.

  10. Experimental investigation of factors limiting slow axis beam quality in 9xx nm high power broad area diode lasers

    SciTech Connect (OSTI)

    Winterfeldt, M. Crump, P.; Wenzel, H.; Erbert, G.; Trnkle, G.

    2014-08-14

    GaAs-based broad-area diode lasers are needed with improved lateral beam parameter product (BPP{sub lat}) at high power. An experimental study of the factors limiting BPP{sub lat} is therefore presented, using extreme double-asymmetric (EDAS) vertical structures emitting at 910?nm. Continuous wave, pulsed and polarization-resolved measurements are presented and compared to thermal simulation. The importance of thermal and packaging-induced effects is determined by comparing junction -up and -down devices. Process factors are clarified by comparing diodes with and without index-guiding trenches. We show that in all cases studied, BPP{sub lat} is limited by a non-thermal BPP ground-level and a thermal BPP, which depends linearly on self-heating. Measurements as a function of pulse width confirm that self-heating rather than bias-level dominates. Diodes without trenches show low BPP ground-level, and a thermal BPP which depends strongly on mounting, due to changes in the temperature profile. The additional lateral guiding in diodes with trenches strongly increases the BPP ground-level, but optically isolates the stripe from the device edges, suppressing the influence of the thermal profile, leading to a BPP-slope that is low and independent of mounting. Trenches are also shown to initiate strain fields that cause parasitic TM-polarized emission with large BPP{sub lat}, whose influence on total BPP{sub lat} remains small, provided the overall polarization purity is >95%.

  11. ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE

    SciTech Connect (OSTI)

    Ketusky, E.; Subramanian, K.

    2012-02-29

    At the Savannah River Site (SRS), oxalic acid is currently considered the preferred agent for chemically cleaning the large underground Liquid Radioactive Waste Tanks. It is applied only in the final stages of emptying a tank when generally less than 5,000 kg of waste solids remain, and slurrying based removal methods are no-longer effective. The use of oxalic acid is preferred because of its combined dissolution and chelating properties, as well as the fact that corrosion to the carbon steel tank walls can be controlled. Although oxalic acid is the preferred agent, there are significant potential downstream impacts. Impacts include: (1) Degraded evaporator operation; (2) Resultant oxalate precipitates taking away critically needed operating volume; and (3) Eventual creation of significant volumes of additional feed to salt processing. As an alternative to dealing with the downstream impacts, oxalate decomposition using variations of ozone based Advanced Oxidation Process (AOP) were investigated. In general AOPs use ozone or peroxide and a catalyst to create hydroxyl radicals. Hydroxyl radicals have among the highest oxidation potentials, and are commonly used to decompose organics. Although oxalate is considered among the most difficult organic to decompose, the ability of hydroxyl radicals to decompose oxalate is considered to be well demonstrated. In addition, as AOPs are considered to be 'green' their use enables any net chemical additions to the waste to be minimized. In order to test the ability to decompose the oxalate and determine the decomposition rates, a test rig was designed, where 10 vol% ozone would be educted into a spent oxalic acid decomposition loop, with the loop maintained at 70 C and recirculated at 40L/min. Each of the spent oxalic acid streams would be created from three oxalic acid strikes of an F-area simulant (i.e., Purex = high Fe/Al concentration) and H-area simulant (i.e., H area modified Purex = high Al/Fe concentration) after nearing dissolution equilibrium, and then decomposed to {le} 100 Parts per Million (ppm) oxalate. Since AOP technology largely originated on using ultraviolet (UV) light as a primary catalyst, decomposition of the spent oxalic acid, well exposed to a medium pressure mercury vapor light was considered the benchmark. However, with multi-valent metals already contained in the feed, and maintenance of the UV light a concern; testing was conducted to evaluate the impact from removing the UV light. Using current AOP terminology, the test without the UV light would likely be considered an ozone based, dark, ferrioxalate type, decomposition process. Specifically, as part of the testing, the impacts from the following were investigated: (1) Importance of the UV light on the decomposition rates when decomposing 1 wt% spent oxalic acid; (2) Impact of increasing the oxalic acid strength from 1 to 2.5 wt% on the decomposition rates; and (3) For F-area testing, the advantage of increasing the spent oxalic acid flowrate from 40 L/min (liters/minute) to 50 L/min during decomposition of the 2.5 wt% spent oxalic acid. The results showed that removal of the UV light (from 1 wt% testing) slowed the decomposition rates in both the F & H testing. Specifically, for F-Area Strike 1, the time increased from about 6 hours to 8 hours. In H-Area, the impact was not as significant, with the time required for Strike 1 to be decomposed to less than 100 ppm increasing slightly, from 5.4 to 6.4 hours. For the spent 2.5 wt% oxalic acid decomposition tests (all) without the UV light, the F-area decompositions required approx. 10 to 13 hours, while the corresponding required H-Area decompositions times ranged from 10 to 21 hours. For the 2.5 wt% F-Area sludge, the increased availability of iron likely caused the increased decomposition rates compared to the 1 wt% oxalic acid based tests. In addition, for the F-testing, increasing the recirculation flow rates from 40 liter/minute to 50 liter/minute resulted in an increased decomposition rate, suggesting a better use of ozone.

  12. Projections of Future Summertime Ozone over the U.S.

    SciTech Connect (OSTI)

    Pfister, G. G.; Walters, Stacy; Lamarque, J. F.; Fast, Jerome D.; Barth, Mary; Wong, John; Done, James; Holland, Greg; Bruyere, Cindy

    2014-05-05

    This study uses a regional fully coupled chemistry-transport model to assess changes in surface ozone over the summertime U.S. between present and a 2050 future time period at high spatial resolution (12 km grid spacing) under the SRES A2 climate and RCP8.5 anthropogenic pre-cursor emission scenario. The impact of predicted changes in climate and global background ozone is estimated to increase surface ozone over most of the U.S; the 5th - 95th percentile range for daily 8-hour maximum surface ozone increases from 31-79 ppbV to 30-87 ppbV between the present and future time periods. The analysis of a set of meteorological drivers suggests that these mostly will add to increasing ozone, but the set of simulations conducted does not allow to separate this effect from that through enhanced global background ozone. Statistically the most robust positive feedbacks are through increased temperature, biogenic emissions and solar radiation. Stringent emission controls can counteract these feedbacks and if considered, we estimate large reductions in surface ozone with the 5th-95th percentile reduced to 27-55 ppbV. A comparison of the high-resolution projections to global model projections shows that even though the global model is biased high in surface ozone compared to the regional model and compared to observations, both the global and the regional model predict similar changes in ozone between the present and future time periods. However, on smaller spatial scales, the regional predictions show more pronounced changes between urban and rural regimes that cannot be resolved at the coarse resolution of global model. In addition, the sign of the changes in overall ozone mixing ratios can be different between the global and the regional predictions in certain regions, such as the Western U.S. This study confirms the key role of emission control strategies in future air quality predictions and demonstrates the need for considering degradation of air quality with future climate change in emission policy making. It also illustrates the need for high resolution modeling when the objective is to address regional and local air quality or establish links to human health and society.

  13. Morphological basis of tolerance to ozone

    SciTech Connect (OSTI)

    Evans, M.J.; Dekker, N.P.; Cabral-Anderson, L.J.; Shami, S.G.

    1985-06-01

    The purpose of this research was to study Type 1 epithelial cells in the ozone (O/sub 3/)-tolerant lung epithelium. Rats were made tolerant by exposure to 0.5 ppm O/sub 3/ for 2 days and allowed to recover in air. Reexposure to a lethal concentration of O/sub 3/ (6 ppm) at 3, 7, and 15 days of recovery revealed that tolerance was present at 3 days but almost absent at 7 and 15 days of recovery. Using Type 2 cell proliferation as a means of quantitating Type 1 cell injury, it was observed that when the preexposed rats were reexposed to 0.5 ppm at 3, 7, and 15 days, very little Type 1 cell injury occurred at 3 days. However, at 7 and 15 days the amount of Type 1 cell injury was the same as that associated with the original exposure. To determine whether there was any change in the alveolar epithelial cell populations between the periods of tolerance (3 days) and its decline (7 and 15 days), the percentage of tritiated thymidine (( /sup 3/H)TdR-labeled Type 1 and 2 cells at these times were determined. There was a significant decrease in (/sup 3/H)TdR-labeled Type 1 and 2 cells between the third and fifteenth days of recovery as excess cells were sloughed off and the tissue returned to normal. Using electron microscopic morphometry, Type 1 and 2 cells were then studied during the decline of tolerance. No change was found in the morphology of Type 2 cells; however, the morphology of Type 1 cells revealed a 58% decrease in surface area and a 25% increase in the arithmetic mean thickness when tolerance was present at 3 days. As tolerance declined (7 and 15 days), Type 1 cell morphology returned to normal. It was concluded that tolerance exists when the surface area of a cell exposed to a particular concentration of ozone is small enough so that the existing antioxidant mechanism contained within that cell volume can protect it from damage.

  14. Abiotic ozone and oxygen in atmospheres similar to prebiotic Earth

    SciTech Connect (OSTI)

    Domagal-Goldman, Shawn D.; Segura, Antgona; Claire, Mark W.; Robinson, Tyler D.; Meadows, Victoria S.

    2014-09-10

    The search for life on planets outside our solar system will use spectroscopic identification of atmospheric biosignatures. The most robust remotely detectable potential biosignature is considered to be the detection of oxygen (O{sub 2}) or ozone (O{sub 3}) simultaneous to methane (CH{sub 4}) at levels indicating fluxes from the planetary surface in excess of those that could be produced abiotically. Here we use an altitude-dependent photochemical model with the enhanced lower boundary conditions necessary to carefully explore abiotic O{sub 2} and O{sub 3} production on lifeless planets with a wide variety of volcanic gas fluxes and stellar energy distributions. On some of these worlds, we predict limited O{sub 2} and O{sub 3} buildup, caused by fast chemical production of these gases. This results in detectable abiotic O{sub 3} and CH{sub 4} features in the UV-visible, but no detectable abiotic O{sub 2} features. Thus, simultaneous detection of O{sub 3} and CH{sub 4} by a UV-visible mission is not a strong biosignature without proper contextual information. Discrimination between biological and abiotic sources of O{sub 2} and O{sub 3} is possible through analysis of the stellar and atmospheric contextparticularly redox state and O atom inventoryof the planet in question. Specifically, understanding the spectral characteristics of the star and obtaining a broad wavelength range for planetary spectra should allow more robust identification of false positives for life. This highlights the importance of wide spectral coverage for future exoplanet characterization missions. Specifically, discrimination between true and false positives may require spectral observations that extend into infrared wavelengths and provide contextual information on the planet's atmospheric chemistry.

  15. Real-World Studies of Ambient Ozone Formation as a Function of...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California ...

  16. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F.

    2007-05-15

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  17. Impact of heterogeneous chemistry on model predictions of ozone changes

    SciTech Connect (OSTI)

    Granier, C.; Brasseur, G. )

    1992-11-20

    A two-dimensional chemical/transport model of the middle atmosphere is used to assess the importance of chemical heterogeneous processes in the polar regions (on polar stratospheric clouds (PSCs)) and at other latitudes (on sulfate aerosols). When conversion on type I and type II PSCs of N[sub 2]O[sub 5] into HNO[sub 3] and of CIONO[sub 2] into reactive forms of chlorine is taken into account, enhanced CIO concentrations lead to the formation of a springtime ozone hole over the Antarctic continent; no such major reduction in the ozone column is found in the Arctic region. When conversion of nitrogen and chlorine compounds is assumed to occur on sulfate particles in the lower stratosphere, significant perturbations in the chemistry are also found. For background aerosol conditions, the concentration of nitric acid is enhanced and agrees with observed values, while that of nitrogen oxides is reduced and agrees less than if heterogeneous processes are ignored in the calculations. The concentration of the OH radical is significantly increased. Ozone number density appears to become larger between 16 and 30 km but smaller below 16 km, especially at high latitudes. The ozone column is only slightly modified, except at high latitudes where it is substantially reduced if the CIONO[sub 2] conversion into reactive chlorine is considered. After a large volcanic eruption these changes are further exacerbated. The ozone budget in the lower stratrosphere becomes less affected by nitrogen oxides but is largely controlled by the CIO[sub x] and HO[sub x] chemistries. A substantial decrease in the ozone column is predicted as a result of the Pinatubo volcanic eruption, mostly in winter at middle and high latitudes. 62 refs., 18 figs., 3 tabs.

  18. Volatile organic compound emissions from usaf wastewater treatment plants in ozone nonattainment areas. Master's thesis

    SciTech Connect (OSTI)

    Ouellette, B.A.

    1994-09-01

    In accordance with the 1990 Clean Air Act Amendments (CAAA), this research conducts an evaluation of the potential emission of volatile organic compounds (VOCs) from selected Air Force wastewater treatment plants. Using a conservative mass balance analysis and process specific simulation models, volatile organic emission estimates are calculated for four individual facilities--Edwards AFB, Luke AFB, McGuire AFB, and McClellan AFB--which represent a cross section of the current inventory of USAF wastewater plants in ozone nonattainment areas. From these calculations, maximum facility emissions are determined which represent the upper limit for the potential VOC emissions from these wastewater plants. Based on the calculated emission estimates, each selected wastewater facility is evaluated as a potential major stationary source of volatile organic emissions under both Title I of the 1990 CAAA and the plant's governing Clean Air Act state implementation plan. Next, the potential impact of the specific volatile organics being emitted is discussed in terms of their relative reactivity and individual contribution to tropospheric ozone formation. Finally, a relative comparison is made between the estimated VOC emissions for the selected wastewater facilities and the total VOC emissions for their respective host installations.

  19. P ORNiiTM-7004 Results of Ground Level Radiation

    Office of Legacy Management (LM)

    performed by Health and Safety Research Division Date ... no longer required for nuclear programs has been returned ... and Knolls Atomic Power Laboratory were also stored ...

  20. GROUND LEVEL INVESTIGATION OF ANOMALOUS RADIATION LEVELS IN NIAGARA...

    Office of Legacy Management (LM)

    ;v ;);;J; '9;) -i, - 'L." ; i--j -7,) ;3 i, Work performed by Health and Safety Research Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37630 O&J. 2,7 +, 7&y'...

  1. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V.; Gordon, C.J.; Jarema, K.A.; MacPhail, R.C.; Cascio, W.E.; Phillips, P.M.; Ledbetter, A.D.; Schladweiler, M.C.; Andrews, D.; Miller, D.; Doerfler, D.L.; Kodavanti, U.P.

    2013-12-15

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: Air pollutants have been associated with increased diabetes in humans. Acute ozone exposure produces profound metabolic alterations in rats. Age influences metabolic risk factors in aging BN rats. Acute metabolic effects are reversible and repeated exposure reduces these effects. Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  2. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  3. Meeting the New Ozone Standard: Challenges and Opportunities

    Broader source: Energy.gov [DOE]

    This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

  4. Age-dependent inhibition of pentobarbital sleeping time by ozone in mice and rats

    SciTech Connect (OSTI)

    Canada, A.T.; Calabrese, E.J.; Leonard, D.

    1986-09-01

    The effect of age on the metabolism of pentobarbital in mice and rats was investigated following exposure to 0.3 ppm of ozone for 3.75 hr. Young animals were 2.5 months of age and the mature were 18 months. The pentobarbital sleeping time was significantly prolonged following the ozone exposure in both the mice and rats when compared with an air control. No ozone effect on sleeping time was found in the young animals. The results indicate that there may be an age-related sensitivity to the occurrence of ozone-related inhibition of pentobarbital metabolism.

  5. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Controlling superconductivity in La2-xSrxCuO4+ by ozone and vacuum annealing Citation Details In-Document Search Title: Controlling superconductivity in ...

  6. Limited Test Ban Treaty

    National Nuclear Security Administration (NNSA)

    Detection System (USNDS), which monitors compliance with the international Limited Test Ban Treaty (LTBT). The LTBT, signed by 108 countries, prohibits nuclear testing in the...

  7. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    SciTech Connect (OSTI)

    Kim, Saewung; Kim, So-Young; Lee, Meehye; Shim, Heeyoun; Wolfe, Glenn; Guenther, Alex B.; He, Amy; Hong, Youdeog; Han, Jinseok

    2014-01-01

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Gangzhou, and Beijing are surrounded by densely forested areas and recent research has consistently demonstrated the importance of biogenic volatile organic compounds from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical concentrations, undermine our ability to assess regional photochemical air pollution problems. We present an observational dataset of CO, NOX, SO2, ozone, HONO, and VOCs (anthropogenic and biogenic) from Taehwa Research Forest (TRF) near the Seoul Metropolitan Area (SMA) in early June 2012. The data show that TRF is influenced both by aged pollution and fresh BVOC emissions. With the dataset, we diagnose HOx (OH, HO2, and RO2) distributions calculated with the University of Washington Chemical Box Model (UWCM v 2.1). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that 1) different model simulation scenarios cause systematic differences in HOX distributions especially OH levels (up to 2.5 times) and 2) radical destruction (HO2+HO2 or HO2+RO2) could be more efficient than radical recycling (HO2+NO) especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozone-VOC-NOX sensitivity and oxidation product formation rates. Overall, the VOC limited regime in ozone photochemistry is predicted but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with OVOCs production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher than expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.

  8. Classical and alternative macrophage activation in the lung following ozone-induced oxidative stress

    SciTech Connect (OSTI)

    Sunil, Vasanthi R.; Patel-Vayas, Kinal; Shen, Jianliang; Laskin, Jeffrey D.; Laskin, Debra L.

    2012-09-01

    Ozone is a pulmonary irritant known to cause oxidative stress, inflammation and tissue injury. Evidence suggests that macrophages play a role in the pathogenic response; however, their contribution depends on the mediators they encounter in the lung which dictate their function. In these studies we analyzed the effects of ozone-induced oxidative stress on the phenotype of alveolar macrophages (AM). Exposure of rats to ozone (2 ppm, 3 h) resulted in increased expression of 8-hydroxy-2?-deoxyguanosine (8-OHdG), as well as heme oxygenase-1 (HO-1) in AM. Whereas 8-OHdG was maximum at 24 h, expression of HO-1 was biphasic increasing after 3 h and 4872 h. Cleaved caspase-9 and beclin-1, markers of apoptosis and autophagy, were also induced in AM 24 h post-ozone. This was associated with increased bronchoalveolar lavage protein and cells, as well as matrix metalloproteinase (MMP)-2 and MMP-9, demonstrating alveolar epithelial injury. Ozone intoxication resulted in biphasic activation of the transcription factor, NF?B. This correlated with expression of monocyte chemotactic protein?1, inducible nitric oxide synthase and cyclooxygenase?2, markers of proinflammatory macrophages. Increases in arginase-1, Ym1 and galectin-3 positive anti-inflammatory/wound repair macrophages were also observed in the lung after ozone inhalation, beginning at 24 h (arginase-1, Ym1), and persisting for 72 h (galectin-3). This was associated with increased expression of pro-surfactant protein-C, a marker of Type II cell proliferation and activation, important steps in wound repair. These data suggest that both proinflammatory/cytotoxic and anti-inflammatory/wound repair macrophages are activated early in the response to ozone-induced oxidative stress and tissue injury. -- Highlights: ? Lung macrophages are highly sensitive to ozone induced oxidative stress. ? Ozone induces autophagy and apoptosis in lung macrophages. ? Proinflammatory and wound repair macrophages are activated early after ozone. ? Oxidative stress may contribute to regulating macrophage phenotype and function.

  9. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, Duncan W.; Mattes, Benjamin R.; Koskelo, Aaron C.; Heeger, Alan J.; Robinson, Jeanne M.; Smilowitz, Laura B.; Klimov, Victor I.; Cha, Myoungsik; Sariciftci, N. Serdar; Hummelen, Jan C.

    1998-01-01

    Optical limiting materials. Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO.sub.2) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400-1100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes.

  10. CONTROL LIMITER DEVICE

    DOE Patents [OSTI]

    DeShong, J.A.

    1960-03-01

    A control-limiting device for monltoring a control system is described. The system comprises a conditionsensing device, a condition-varying device exerting a control over the condition, and a control means to actuate the condition-varying device. A control-limiting device integrates the total movement or other change of the condition-varying device over any interval of time during a continuum of overlapping periods of time, and if the tothl movement or change of the condition-varying device exceeds a preset value, the control- limiting device will switch the control of the operated apparatus from automatic to manual control.

  11. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  12. PEAK LIMITING AMPLIFIER

    DOE Patents [OSTI]

    Goldsworthy, W.W.; Robinson, J.B.

    1959-03-31

    A peak voltage amplitude limiting system adapted for use with a cascade type amplifier is described. In its detailed aspects, the invention includes an amplifier having at least a first triode tube and a second triode tube, the cathode of the second tube being connected to the anode of the first tube. A peak limiter triode tube has its control grid coupled to thc anode of the second tube and its anode connected to the cathode of the second tube. The operation of the limiter is controlled by a bias voltage source connected to the control grid of the limiter tube and the output of the system is taken from the anode of the second tube.

  13. The role of developing countries in protecting the ozone layer: An ethical analysis

    SciTech Connect (OSTI)

    Zatz, M.N.

    1994-12-31

    In an effort to reduce the depletion of the stratospheric ozone layer, the nations of the world joined together in a landmark effort to address this most important problem. Unlike many environmental issues which are localized, ozone depletion is an environmental problem which must be addressed on a global scale. In order to successfully halt the depletion of the ozone layer, it is imperative that all countries amend their current practices and reduce their consumption of ozone-depleting substances. This necessity presents an ethical dilemma when assigning responsibility for ozone layer protection among nations. This paper will address the difficulties in dealing with ozone depletion on a global scale and will discuss the ethically correct role which should be assumed by developing countries. After presenting a brief history of the problem of ozone depletion and the measures which have been taken to halt it, this paper will describe an ethical framework in which ozone layer protection policies in developing countries should be evaluated. This framework is based on the concept of balancing morally-correct policies with economically-sound policies. It illustrates, in detail, how the environmental impacts of policies must be considered in conjunction with the impacts of such policies on the lives and well-being of the country`s citizens. The paper presents an ethical analysis of three primary policy options. These options address the phaseout of ozone-depleting substances (such as CFCs) and include: the no-phaseout option, the developed country accelerated phaseout schedule, and the delayed phaseout schedule. Each option is examined within the ethical framework presented earlier in the paper. Finally, the paper concludes by addressing the ethical responsibilities of developed countries. It discusses the various ways in which developed countries should provide aid.

  14. Ozone in sea water. Part 1: Chemistry; Part 2: Corrosion of metals

    SciTech Connect (OSTI)

    Wyllie, W.E. II; Brown, B.E.; Duquette, D.J.

    1995-12-01

    Ozonation of sea water for biofouling control is being utilized in desalination processes, heat exchange systems, as well as in salt water aquariums. The chemistry of ozone in sea water is much more complex than in fresh water due to the high concentration of easily oxidizable, ozone-demanding species and the formation of secondary oxidants. The major secondary oxidant is bromine in the form of hypobromite and hypobromous acid (BrO{sup {minus}}/HOBr) which are formed by oxidation of the bromide ion (Br{sup {minus}}), naturally found in sea water in concentrations of 65 mg/L. HOBr can react again with ozone to return Br{sup {minus}}, resulting in accelerated decomposition of ozone, or to form bromate (BrO{sub 3}{sup {minus}}) The BrO ion is known to interfere with the measurement of residual ozone in sea water, so it is important that the feed gas conditions, solution pH, and the hypobromous and bromate concentrations be reported to quantify the amount of ozone introduced into a system. In 0.5 N NaCl and sea water solutions, ozone appears to stabilize the passivity of passivating metals, but susceptibility to crevice corrosion appears to increase in the same environments. The effect of BrO{sup {minus}}/HOBr on the corrosion of metals in sea water is believed to be similar to chlorine and ozone, in that it acts as a strong oxidizer. However, it is not certain whether BrO{sup {minus}}/HOBr and BrO{sub 3}{sup {minus}} have any damaging effects on protective metal films.

  15. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  16. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum

    Office of Scientific and Technical Information (OSTI)

    annealing (Journal Article) | SciTech Connect Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing Citation Details In-Document Search Title: Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship

  17. Security Clearances; Limitations

    Energy Savers [EERE]

    SEC. 1072. SECURITY CLEARANCES; LIMITATIONS. (a) In General.-Title III of the Intelligence Reform and Terrorism Prevention Act of 2004 (50 U.S.C. 435b) is amended by adding at the end the following new section: "SEC. 3002. SECURITY CLEARANCES; LIMITATIONS. "(a) Definitions.-In this section: "(1) Controlled substance.-The term `controlled substance' has the meaning given that term in section 102 of the Controlled Substances Act (21 U.S.C. 802). "(2) Covered person.-The term

  18. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, D.W.; Mattes, B.R.; Koskelo, A.C.; Heeger, A.J.; Robinson, J.M.; Smilowitz, L.B.; Klimov, V.I.; Cha, M.; Sariciftci, N.S.; Hummelen, J.C.

    1998-04-21

    Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO{sub 2}) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400--1,100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes. 5 figs.

  19. Influence of ozone on pentobarbital pharmacokinetics in mice

    SciTech Connect (OSTI)

    Graham, J.A.; Menzel, D.B.; Mole, M.L.; Miller, F.J.; Gardner, D.E.

    1985-01-01

    It had been shown that 3- to 5-hr exposures to ambient concentrations of ozone (O/sub 3/) increase pentobarbital-induced sleeping time in female mice, hamsters, and rats without decreasing heptatic cytochrome P-450 levels or selected mixed function oxidases. To elucidate potential mechanisms involved, clearance of pentobarbital from the blood of O/sub 3/-exposed mice was examined. Pentobarbital clearance followed first-order kinetics with a one-compartment model. Mice exposed to 1960 micrograms per cu. m. (1ppm) for 5 hr had a 71% increase in the plasma half-life of pentobarbital. It therefore appears possible that pentobarbital-induced sleeping time is increased due to a decrease in hepatic metabolism of pentobarbital.

  20. Environmental Externalities in Electric Power Markets: Acid Rain, Urban Ozone, and Climate Change

    Reports and Publications (EIA)

    1995-01-01

    This article discusses the emissions resulting from the generation of electricity by utilities and their role in contributing to the environmental problems of acid rain, urban ozone, and climate change.

  1. Improved Potential Energy Surface of Ozone Constructed Using the Fitting by Permutationally Invariant Polynomial Function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ayouz, Mehdi; Babikov, Dmitri

    2012-01-01

    New global potential energy surface for the ground electronic state of ozone is constructed at the complete basis set level of the multireference configuration interaction theory. A method of fitting the data points by analytical permutationally invariant polynomial function is adopted. A small set of 500 points is preoptimized using the old surface of ozone. In this procedure the positions of points in the configuration space are chosen such that the RMS deviation of the fit is minimized. New ab initio calculations are carried out at these points and are used to build new surface. Additional points are addedmore » to the vicinity of the minimum energy path in order to improve accuracy of the fit, particularly in the region where the surface of ozone exhibits a shallow van der Waals well. New surface can be used to study formation of ozone at thermal energies and its spectroscopy near the dissociation threshold.« less

  2. Heat flux limiting sleeves

    DOE Patents [OSTI]

    Harris, William G. (Tampa, FL)

    1985-01-01

    A heat limiting tubular sleeve extending over only a portion of a tube having a generally uniform outside diameter, the sleeve being open on both ends, having one end thereof larger in diameter than the other end thereof and having a wall thickness which decreases in the same direction as the diameter of the sleeve decreases so that the heat transfer through the sleeve and tube is less adjacent the large diameter end of the sleeve than adjacent the other end thereof.

  3. Influence of Long-Period Variations of Total Ozone Content on Climate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Change in Twentieth Century Influence of Long-Period Variations of Total Ozone Content on Climate Change in Twentieth Century Zuev, V Institute of Atmospheric Optics Zueva, N. Institute of Atmospheric Optics Bondarenko, S Institute of Atmospheric Optics Category: Atmospheric State and Surface It is shown that during long-term total ozone decrease everywhere at middle and high latitudes there takes place the destruction of balance in global carbon cycle first of all due to reduction of

  4. Spatially Resolved Estimation of Ozone-related Mortality in the United

    Office of Scientific and Technical Information (OSTI)

    States under Two Representative Concentration Pathways (RCPs) and their Uncertainty (Journal Article) | SciTech Connect Spatially Resolved Estimation of Ozone-related Mortality in the United States under Two Representative Concentration Pathways (RCPs) and their Uncertainty Citation Details In-Document Search Title: Spatially Resolved Estimation of Ozone-related Mortality in the United States under Two Representative Concentration Pathways (RCPs) and their Uncertainty BACKGROUND: The spatial

  5. Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High

    Office of Scientific and Technical Information (OSTI)

    Performance Electrochemical Energy Storage (Journal Article) | SciTech Connect Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Citation Details In-Document Search Title: Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Authors: Chen, Xinyi ; Pomerantseva, Ekaterina ; Banerjee, P ; Gregorczyk, Keith ; Ghodssi, Reza ; Rubloff, Gary W Publication Date: 2012-04-10 OSTI

  6. A global analysis of the ozone deficit in the upper stratosphere and lower mesosphere

    SciTech Connect (OSTI)

    Eluszkiewicz, J.; Allen, M. )

    1993-01-20

    The global measurements of temperature, ozone, water vapor, and nitrogen dioxide acquired by the Limb Infrared Monitor of the Stratosphere (LIMS), supplemented by a precomputed distribution of chlorine monoxide, are used to test the balance between odd oxygen production and loss in the upper stratosphere and lower mesosphere. An efficient photochemical equilibrium model, validated by comparison with the results from a fully time-dependent one-dimensional model at selected latitudes, is used in the calculations. The computed ozone abundances are systematically lower than observations for May 1-7, 1979, which suggests, contrary to the conclusions of other recent studies, a problem in model simulations of stratospheric ozone. The ozone deficit' at 30[degrees]N is smaller than previous analyses of LIMS data have indicated. In the stratosphere, this reduction in the deficit is due to the fact that CIO abundances for the 1979 period utilized in this study are much lower than in earlier work, mainly as a result of lower Cl[sub y] concentrations. In the mesosphere, a correlation of the ozone deficit with the distribution of water vapor is indicated. The ozone deficit in the stratosphere can be eliminated by modifying only one model reaction rate: either by decreasing the rate of odd oxygen loss or by increasing the rate of odd oxygen production Cl[sub y] increasing the photodissociation rate of molecular oxygen primarily in the Herzberg continuum and/or invoking photolysis of vibrationally excited molecular oxygen. With the ozone abundances thus increased, a small residual deficit in the lower mesophere can be eliminated by reducing, within the recommended kinetic uncertainties, the efficiency of odd hydrogen-catalyzed odd oxygen loss. With the adjusted model, the calculated ozone abundances for the week of January 1-7. 1979, outside of winter latitudes, also agree with the LIMS observations to within 10%. 49 refs., 15 figs., 1 tab.

  7. Fault current limiter

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2013-10-08

    A fault current limiter (FCL) includes a series of high permeability posts for collectively define a core for the FCL. A DC coil, for the purposes of saturating a portion of the high permeability posts, surrounds the complete structure outside of an enclosure in the form of a vessel. The vessel contains a dielectric insulation medium. AC coils, for transporting AC current, are wound on insulating formers and electrically interconnected to each other in a manner such that the senses of the magnetic field produced by each AC coil in the corresponding high permeability core are opposing. There are insulation barriers between phases to improve dielectric withstand properties of the dielectric medium.

  8. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    SciTech Connect (OSTI)

    Kim, S.; Kim, S. -Y.; Lee, M.; Shim, H.; Wolfe, G. M.; Guenther, A. B.; He, A.; Hong, Y.; Han, J.

    2015-04-29

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Guangzhou, and Beijing are surrounded by densely forested areas, and recent research has consistently demonstrated the importance of biogenic volatile organic compounds (VOCs) from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical, undermine our ability to assess regional photochemical air pollution problems. We present an observational data set of CO, NOx, SO2, ozone, HONO, and VOCs (anthropogenic and biogenic) from Taehwa research forest (TRF) near the Seoul metropolitan area in early June 2012. The data show that TRF is influenced both by aged pollution and fresh biogenic volatile organic compound emissions. With the data set, we diagnose HOx (OH, HO2, and RO2) distributions calculated using the University of Washington chemical box model (UWCM v2.1) with near-explicit VOC oxidation mechanisms from MCM v3.2 (Master Chemical Mechanism). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that (1) different model simulation scenarios cause systematic differences in HOx distributions, especially OH levels (up to 2.5 times), and (2) radical destruction (HO2 + HO2 or HO2 + RO2) could be more efficient than radical recycling (RO2 + NO), especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozoneVOCNOx sensitivity and VOC oxidation product formation rates. Overall, the NOx limited regime is assessed except for the morning hours (8 a.m. to 12 p.m. local standard time), but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with oxygenated VOCs (OVOCs) production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher-than-expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.

  9. (Limiting the greenhouse effect)

    SciTech Connect (OSTI)

    Rayner, S.

    1991-01-07

    Traveler attended the Dahlem Research Conference organized by the Freien Universitat, Berlin. The subject of the conference was Limiting the Greenhouse Effect: Options for Controlling Atmospheric CO{sub 2} Accumulation. Like all Dahlem workshops, this was a meeting of scientific experts, although the disciplines represented were broader than usual, ranging across anthropology, economics, international relations, forestry, engineering, and atmospheric chemistry. Participation by scientists from developing countries was limited. The conference was divided into four multidisciplinary working groups. Traveler acted as moderator for Group 3 which examined the question What knowledge is required to tackle the principal social and institutional barriers to reducing CO{sub 2} emissions'' The working rapporteur was Jesse Ausubel of Rockefeller University. Other working groups examined the economic costs, benefits, and technical feasibility of options to reduce emissions per unit of energy service; the options for reducing energy use per unit of GNP; and the significant of linkage between strategies to reduce CO{sub 2} emissions and other goals. Draft reports of the working groups are appended. Overall, the conference identified a number of important research needs in all four areas. It may prove particularly important in bringing the social and institutional research needs relevant to climate change closer to the forefront of the scientific and policy communities than hitherto.

  10. Timminco Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: Timminco Limited Place: Toronto, Ontario, Canada Zip: M5H 1J9 Product: Canadian manufacturer of magnesium and silicon; operates its...

  11. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-11-01

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  12. Paso del Norte ozone study VOC measurements, 1996

    SciTech Connect (OSTI)

    Seila, R.L.; Main, H.; Arriaga, J.L.; Martinez, G.V.; Ramadan, A.B.

    1999-01-01

    The results of VOC determinations of ambient air samples collected at surface air quality monitoring sites and near sources of interest on the US and Mexican side of the border during six weeks of the 1996 Paso del Norte Ozone Study are reported. Carbonyl samples were collected on DNPH impregnated cartridges at three surface sites and analyzed by HPLC to quantify 13, C-1 to C-8 species. Whole air samples were collected in electro-polished stainless steel canisters which were returned to laboratory for determination of C-2 to C-10+ hydrocarbons by cryogenic preconcentration capillary gas chromatography with flame ionization detection (gc-fid). Several sources were sampled: rush hour traffic, propane-powered bus exhaust, automobile paint shop emissions, propane fuel, petroleum refinery, and industrial manufacturing site. Spatial and temporal characteristics of VOC species concentrations and compositions are presented. Overall surface TNMOC values ranged from 0.1 to 3.4 ppmC with the highest concentrations recorded in the morning at three vehicle-dominated sites, two in Cuidad Juarez and one in downtown El Paso. Toluene in El Paso samples and propane, which is used as a cooking and transportation fuel in Cuidad Juarez, were the most abundant hydrocarbons.

  13. Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.

    SciTech Connect (OSTI)

    Whitfield, R. G.

    1999-03-04

    This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

  14. Post-treatment of fly ash by ozone in a fixed bed reactor

    SciTech Connect (OSTI)

    Kim Hougaard Pedersen; Merc Casanovas Meli; Anker Degn Jensen; Kim Dam-Johansen

    2009-01-15

    The residual carbon in fly ash produced from pulverized coal combustion can adsorb the air-entraining admixtures (AEAs) added to enhance air entrainment in concrete. This behavior of the ash can be suppressed by exposing the fly ash to oxidizing species, which oxidizes the carbon surface and thus prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O{sub 3}/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data. 28 refs., 7 figs., 3 tabs.

  15. Observation of stratospheric trace gases related to ozone depletion in the Antarctic spring

    SciTech Connect (OSTI)

    De Zafra, R.L.; Parrish, A.; Solomon, P.; Barrett, J.W.; Connor, B.; Jaramillo, M. )

    1987-01-01

    During the first National Ozone Expedition (NOZE I), which ran from 21 August to early November 1986 at McMurdo Station, the authors made frequent measurements of chlorine monoxide (CIO), ozone (O{sub 3}), nitrous oxide (N{sub 2}O), and occasional measurements of hydrogen cyanide. Observations were made with a ground-based millimeters wave spectrometer capable of detecting and measuring the pressure broadened rotational emission lines of these molecules in the 260-280 gigahertz frequency range. The spectral bandpass and resolution of the instrument is sufficient to recover altitude distributions over a range of approximately 20-55 kilometers and to detect emission from as low as approximately 13-15 kilometers. Results are given and discussed on the levels of chlorine monoxide, nitrous oxide, and ozone found.

  16. Water relations of differentially irrigated cotton exposed to ozone

    SciTech Connect (OSTI)

    Temple, P.J.

    1990-01-01

    The field study was conducted to test the hypothesis that plants chronically exposed to O{sub 3} may be more susceptible to drought because O{sub 3} typically inhibits root growth and increases shoot-root ratios in plants. Cotton was grown in open-top chambers on Hanford coarse sandy loam in Riverside, CA. Plants were grown under three irrigation regimes: Optimum water for lint production (OW), suboptimum or moderate drought stress (SO), and severely drought stressed (SS) and were exposed to seasonal 12 h (0800-2000) O{sub 3} centrations of 0.015, 0.074, 0.094, or 0.111/microLL. Leaf xylem pressure potentials Psi(sub 1) and soil water content Theta(sub v) were measured weekly from June to October. Mean seasonal Psi(sub 1) increased from -1.89 MPa to -1.72 MPa in low to high O{sub 3} treatments, averaged across soil water regimes. Ozone had no effect on seasonal water use of cotton, but water use efficiency was significantly reduced by O{sub 3} in OW and SO, but not in SS treatments. Drought-stressed plants extracted proportionally greater amounts of water from deeper in the soil profile than OW cotton, and O{sub 3} had no apparent effect on this redistribution of roots in the soil. Since O{sub 3} had no apparent effect on the ability of drought-stressed cotton to maintain Psi(sub 1) and to increase root growth relative to shoot growth, this suggests that O{sub 3} may have little or no effect on the potential of cotton to adapt to or tolerate drought.

  17. Electricity and the Environment - Energy Explained, Your Guide...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... SO2 also exacerbates respiratory illnesses and heart diseases, particularly in children and the elderly. NOx contribute to ground level ozone, which irritates and damages the lungs...

  18. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    SciTech Connect (OSTI)

    Destaillats, Hugo; Chen, Wenhao; Apte, Michael; Li, Nuan; Spears, Michael; Almosni, Jrmie; Brunner, Gregory; Zhang, Jianshun; Fisk, William J.

    2011-05-01

    Prior research suggests that chemical processes taking place on the surface of particle filters employed in buildings may lead to the formation of harmful secondary byproducts. We investigated ozone reactions with fiberglass, polyester, cotton/polyester and polyolefin filter media, as well as hydrolysis of filter media additives. Studies were carried out on unused media, and on filters that were installed for 3 months in buildings at two different locations in the San Francisco Bay Area. Specimens from each filter media were exposed to {approx}150 ppbv ozone in a flow tube under a constant flow of dry or humidified air (50percent RH). Ozone breakthrough was recorded for each sample over periods of {approx}1000 min; the ozone uptake rate was calculated for an initial transient period and for steady-state conditions. While ozone uptake was observed in all cases, we did not observe significant differences in the uptake rate and capacity for the various types of filter media tested. Most experiments were performed at an airflow rate of 1.3 L/min (face velocity = 0.013 m/s), and a few tests were also run at higher rates (8 to 10 L/min). Formaldehyde and acetaldehyde, two oxidation byproducts, were quantified downstream of each sample. Those aldehydes (m/z 31 and 45) and other volatile byproducts (m/z 57, 59, 61 and 101) were also detected in real-time using Proton-Transfer Reaction - Mass Spectrometry (PTR-MS). Low-ppbv byproduct emissions were consistently higher under humidified air than under dry conditions, and were higher when the filters were loaded with particles, as compared with unused filters. No significant differences were observed when ozone reacted over various types of filter media. Fiberglass filters heavily coated with impaction oil (tackifier) showed higher formaldehyde emissions than other samples. Those emissions were particularly high in the case of used filters, and were observed even in the absence of ozone, suggesting that hydrolysis of additives, rather than ozonolysis, is the main formaldehyde source in those filters. Emission rates of formaldehyde and acetaldehyde were not found to be large enough to substantially increase indoor concentrations in typical building scenarios. Nevertheless, ozone reactions on HVAC filters cannot be ignored as a source of low levels of indoor irritants.

  19. COMMENTARY:Limits to adaptation

    SciTech Connect (OSTI)

    Preston, Benjamin L

    2013-01-01

    An actor-centered, risk-based approach to defining limits to social adaptation provides a useful analytic framing for identifying and anticipating these limits and informing debates over society s responses to climate change.

  20. Narrowband filter radiometer for ground-based measurements of global ultraviolet solar irradiance and total ozone

    SciTech Connect (OSTI)

    Petkov, Boyan; Vitale, Vito; Tomasi, Claudio; Bonafe, Ubaldo; Scaglione, Salvatore; Flori, Daniele; Santaguida, Riccardo; Gausa, Michael; Hansen, Georg; Colombo, Tiziano

    2006-06-20

    The ultraviolet narrowband filter radiometer (UV-RAD) designed by the authors to take ground-based measurements of UV solar irradiance, total ozone, and biological dose rate is described, together with the main characteristics of the seven blocked filters mounted on it, all of which have full widths at half maxima that range 0.67 to 0.98 nm. We have analyzed the causes of cosine response and calibration errors carefully to define the corresponding correction terms, paying particular attention to those that are due to the spectral displacements of the filter transmittance peaks from the integer wavelength values. The influence of the ozone profile on the retrieved ozone at large solar zenith angles has also been examined by means of field measurements. The opportunity of carrying out nearly monochromatic irradiance measurements offered by the UV-RAD allowed us to improve the procedure usually followed to reconstruct the solar spectrum at the surface by fitting the computed results, using radiative transfer models with field measurements of irradiance. Two long-term comparison campaigns took place, showing that a mean discrepancy of+0.3% exists between the UV-RAD total ozone values and those given by the Brewer no. 63 spectroradiometer and that mean differences of+0.3% and-0.9% exist between the erythemal dose rates determined with the UV-RAD and those obtained with the Brewer no. 63 and the Brewer no. 104 spectroradiometers, respectively.

  1. Development of pollution reduction strategies for Mexico City: Estimating cost and ozone reduction effectiveness

    SciTech Connect (OSTI)

    Thayer, G.R.; Hardie, R.W.; Barrera-Roldan, A.

    1993-12-31

    This reports on the collection and preparation of data (costs and air quality improvement) for the strategic evaluation portion of the Mexico City Air Quality Research Initiative (MARI). Reports written for the Mexico City government by various international organizations were used to identify proposed options along with estimates of cost and emission reductions. Information from appropriate options identified by SCAQMD for Southem California were also used in the analysis. A linear optimization method was used to select a group of options or a strategy to be evaluated by decision analysis. However, the reduction of ozone levels is not a linear function of the reduction of hydrocarbon and NO{sub x} emissions. Therefore, a more detailed analysis was required for ozone. An equation for a plane on an isopleth calculated with a trajectory model was obtained using two endpoints that bracket the expected total ozone precursor reductions plus the starting concentrations for hydrocarbons and NO{sub x}. The relationship between ozone levels and the hydrocarbon and NO{sub x} concentrations was assumed to lie on this plane. This relationship was used in the linear optimization program to select the options comprising a strategy.

  2. The Impact of Emission and Climate Change on Ozone in the United States under Representative Concentration Pathways (RCPs)

    SciTech Connect (OSTI)

    Gao, Yang; Fu, Joshua S.; Drake, John B.; Lamarque, J.-F.; Liu, Yang

    2013-09-27

    Dynamical downscaling was applied in this study to link the global climate-chemistry model Community Atmosphere Model (CAM-Chem) with the regional models: Weather Research and Forecasting (WRF) Model and Community Multi-scale Air Quality (CMAQ). Two Representative Concentration Pathway (RCP) scenarios (RCP 4.5 and RCP 8.5) were used to evaluate the climate impact on ozone concentrations in 2050s. Ozone concentrations in the lower-mid troposphere (surface to ~300 hPa), from mid- to high latitudes in the Northern Hemisphere (NH), show decreasing trends in RCP 4.5 between 2000s and 2050s, with the largest decrease of 4-10 ppbv occurring in the summer and the fall; and increasing trends (2-12 ppbv) in RCP 8.5 resulting from the increased methane emissions. In RCP 8.5, methane emissions increase by ~60% by the end of 2050s, accounting for more than 90% of ozone increases in summer and fall, and 60-80% in spring and winter. Under the RCP 4.5 scenario, in the summer when photochemical reactions are the most active, the large ozone precursor emissions reduction leads to the greatest decrease of downscaled surface ozone concentrations, ranging from 6 to 10 ppbv. However, a few major cities show ozone increases of 3 to 7 ppbv due to weakened NO titration. Under the RCP 8.5 scenario, in winter, downscaled ozone concentrations increase across nearly the entire continental US in winter, ranging from 3 to 10 ppbv due to increased methane emissions and enhanced stratosphere-troposphere exchange (STE). More intense heat waves are projected to occur by the end of 2050s in RCP 8.5, leading to more than 8 ppbv of the maximum daily 8-hour daily average (MDA8) ozone during the heat wave days than other days; this indicates the dramatic impact heat waves exert on high frequency ozone events.

  3. Lysanda Limited | Open Energy Information

    Open Energy Info (EERE)

    CM8 3GA Product: US-based vehicle engineering consultancy with a technology capable of playing a role in vehicle emissions management. References: Lysanda Limited1 This...

  4. PURAC Limited | Open Energy Information

    Open Energy Info (EERE)

    technology and project management company in the environment sector and specialising in water, wastewater and municpal waste treatment. References: PURAC Limited1 This article...

  5. Solfex Limited | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Solfex Limited Address: Energy Arena Bannister Hall Works Off Shop Lane, Higher Walton Preston, Lancashire PR5 4DZ Place: Preston, United...

  6. Atomic layer deposition of tin oxide and zinc tin oxide using tetraethyltin and ozone

    SciTech Connect (OSTI)

    Warner, Ellis J.; Gladfelter, Wayne L.; Johnson, Forrest; Campbell, Stephen A.

    2015-03-15

    Silicon or glass substrates exposed to sequential pulses of tetraethyltin (TET) and ozone (O{sub 3}) were coated with thin films of SnO{sub 2}. Self-limiting deposition was found using 8 s pulse times, and a uniform thickness per cycle (TPC) of 0.2 nm/cycle was observed in a small, yet reproducible, temperature window from 290 to 320 °C. The as-deposited, stoichiometric SnO{sub 2} films were amorphous and transparent above 400 nm. Interspersing pulses of diethylzinc and O{sub 3} among the TET:O{sub 3} pulses resulted in deposition of zinc tin oxide films, where the fraction of tin, defined as [at. % Sn/(at. % Sn + at. % Zn)], was controlled by the ratio of TET pulses, specifically n{sub TET}:(n{sub TET} + n{sub DEZ}) where n{sub TET} and n{sub DEZ} are the number of precursor/O{sub 3} subcycles within each atomic layer deposition (ALD) supercycle. Based on film thickness and composition measurements, the TET pulse time required to reach saturation in the TPC of SnO{sub 2} on ZnO surfaces was increased to >30 s. Under these conditions, film stoichiometry as a function of the TET pulse ratio was consistent with the model devised by Elliott and Nilsen. The as-deposited zinc tin oxide (ZTO) films were amorphous and remained so even after annealing at 450 °C in air for 1 h. The optical bandgap of the transparent ZTO films increased as the tin concentration increased. Hall measurements established that the n-type ZTO carrier concentration was 3 × 10{sup 17} and 4 × 10{sup 18} cm{sup −3} for fractional tin concentrations of 0.28 and 0.63, respectively. The carrier mobility decreased as the concentration of tin increased. A broken gap pn junction was fabricated using ALD-deposited ZTO and a sputtered layer of cuprous oxide. The junction demonstrated ohmic behavior and low resistance consistent with similar junctions prepared using sputter-deposited ZTO.

  7. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, S.; Kim, S. -Y.; Lee, M.; Shim, H.; Wolfe, G. M.; Guenther, A. B.; He, A.; Hong, Y.; Han, J.

    2015-04-29

    Rapid urbanization and economic development in East Asia in past decades has led to photochemical air pollution problems such as excess photochemical ozone and aerosol formation. Asian megacities such as Seoul, Tokyo, Shanghai, Guangzhou, and Beijing are surrounded by densely forested areas, and recent research has consistently demonstrated the importance of biogenic volatile organic compounds (VOCs) from vegetation in determining oxidation capacity in the suburban Asian megacity regions. Uncertainties in constraining tropospheric oxidation capacity, dominated by hydroxyl radical, undermine our ability to assess regional photochemical air pollution problems. We present an observational data set of CO, NOx, SO2, ozone, HONO,more » and VOCs (anthropogenic and biogenic) from Taehwa research forest (TRF) near the Seoul metropolitan area in early June 2012. The data show that TRF is influenced both by aged pollution and fresh biogenic volatile organic compound emissions. With the data set, we diagnose HOx (OH, HO2, and RO2) distributions calculated using the University of Washington chemical box model (UWCM v2.1) with near-explicit VOC oxidation mechanisms from MCM v3.2 (Master Chemical Mechanism). Uncertainty from unconstrained HONO sources and radical recycling processes highlighted in recent studies is examined using multiple model simulations with different model constraints. The results suggest that (1) different model simulation scenarios cause systematic differences in HOx distributions, especially OH levels (up to 2.5 times), and (2) radical destruction (HO2 + HO2 or HO2 + RO2) could be more efficient than radical recycling (RO2 + NO), especially in the afternoon. Implications of the uncertainties in radical chemistry are discussed with respect to ozone–VOC–NOx sensitivity and VOC oxidation product formation rates. Overall, the NOx limited regime is assessed except for the morning hours (8 a.m. to 12 p.m. local standard time), but the degree of sensitivity can significantly vary depending on the model scenarios. The model results also suggest that RO2 levels are positively correlated with oxygenated VOCs (OVOCs) production that is not routinely constrained by observations. These unconstrained OVOCs can cause higher-than-expected OH loss rates (missing OH reactivity) and secondary organic aerosol formation. The series of modeling experiments constrained by observations strongly urge observational constraint of the radical pool to enable precise understanding of regional photochemical pollution problems in the East Asian megacity region.« less

  8. FUEL CASK IMPACT LIMITER VULNERABILITIES

    SciTech Connect (OSTI)

    Leduc, D; Jeffery England, J; Roy Rothermel, R

    2009-02-09

    Cylindrical fuel casks often have impact limiters surrounding just the ends of the cask shaft in a typical 'dumbbell' arrangement. The primary purpose of these impact limiters is to absorb energy to reduce loads on the cask structure during impacts associated with a severe accident. Impact limiters are also credited in many packages with protecting closure seals and maintaining lower peak temperatures during fire events. For this credit to be taken in safety analyses, the impact limiter attachment system must be shown to retain the impact limiter following Normal Conditions of Transport (NCT) and Hypothetical Accident Conditions (HAC) impacts. Large casks are often certified by analysis only because of the costs associated with testing. Therefore, some cask impact limiter attachment systems have not been tested in real impacts. A recent structural analysis of the T-3 Spent Fuel Containment Cask found problems with the design of the impact limiter attachment system. Assumptions in the original Safety Analysis for Packaging (SARP) concerning the loading in the attachment bolts were found to be inaccurate in certain drop orientations. This paper documents the lessons learned and their applicability to impact limiter attachment system designs.

  9. LANSCE Beam Current Limiter (XL)

    SciTech Connect (OSTI)

    Gallegos, F.R.; Hall, M.J.

    1997-01-01

    The Radiation Security System (RSS) at the Los Alamos Neutron Science Center (LANSCE) is an engineered safety system that provides personnel protection from prompt radiation due to accelerated proton beams. The Beam Current Limiter (XL), as an active component of the RSS, limits the maximum average current in a beamline, thus the current available for a beam spill accident. Exceeding the pre-set limit initiates action by the RSS to mitigate the hazard (insertion of beam stoppers in the low energy beam transport). The beam limiter is an electrically isolated, toroidal transformer and associated electronics. The device was designed to continuously monitor beamline currents independent of any external timing. Fail-safe operation was a prime consideration in its development. Fail-safe operation is defined as functioning as intended (due to redundant circuitry), functioning with a more sensitive fault threshold, or generating a fault condition. This report describes the design philosophy, hardware, implementation, operation, and limitations of the device.

  10. Nuclear Structure at the Limits

    SciTech Connect (OSTI)

    Nazarewicz, W.

    1998-01-12

    One of the frontiers of today?s nuclear science is the ?journey to the limits? of atomic charge and nuclear mass, of neutron-to-proton ratio, and of angular momentum. The tour to the limits is not only a quest for new, exciting phenomena, but the new data are expected, as well, to bring qualitatively new information about the fundamental properties of the nucleonic many-body system, the nature of the nuclear interaction, and nucleonic correlations at various energy-distance scales. In this series of lectures, current developments in nuclear structure at the limits are discussed from a theoretical perspective, mainly concentrating on medium-mass and heavy nuclei.

  11. Nuclear Structure at the Limits

    SciTech Connect (OSTI)

    Nazarewicz, Witold

    1997-12-31

    One of the frontiers of today`s nuclear science is the ``journey to the limits``: of atomic charge and nuclear mass, of neutron-to-proton ratio, and of angular momentum. The tour to the limits is not only a quest for new, exciting phenomena but the new data are expected, as well, to bring qualitatively new information about the fundamental properties of the nucleonic many-body system, the nature of the nuclear interaction, and nucleonic correlations at various energy-distance scales. In this talk, current developments in nuclear structure at the limits are discussed from a theoretical perspective.

  12. Dose Limits | Department of Energy

    Energy Savers [EERE]

    Limits Dose Limits (Question Posted to ERAD in May 2012) Who do you define as a member of the public for the onsite MEI? This question implies that there may be more than one maximally exposed individual (MEI), one on-site and one off-site, when demonstrating compliance with the Public Dose Limit of DOE Order 458.1. Although all potential MEIs should be considered and documented, as well as the calculated doses and pathways considered, the intent of DOE Order 458.1 is in fact to ultimately

  13. Wastewater treatment: Ozonation processes and equipment. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The bibliography contains citations concerning the use of ozone for wastewater disinfection. The citations cover system descriptions and evaluations, comparisons with the chlorination disinfection process, reaction kinetics, and the combination of ozonation with other wastewater treatment methods. The treatment of organic and inorganic compounds in wastewater and municipal water supplies is also discussed. (Contains 250 citations and includes a subject term index and title list.)

  14. Wastewater treatment: Ozonation processes and equipment. (Latest citations from the Selected Water Resources Abstracts database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-03-01

    The bibliography contains citations concerning the use of ozone for wastewater disinfection. The citations cover system descriptions and evaluations, comparisons with the chlorination disinfection process, reaction kinetics, and the combination of ozonation with other wastewater treatment methods. The treatment of organic and inorganic compounds in wastewater and municipal water supplies is also discussed. (Contains 250 citations and includes a subject term index and title list.)

  15. Demonstration of Advanced Technologies for Multi-Load Washers in Hospitality and Healthcare -- Ozone Based Laundry Systems

    SciTech Connect (OSTI)

    Boyd, Brian K.; Parker, Graham B.; Petersen, Joseph M.; Sullivan, Greg; Goetzler, W.; Sutherland, T. A.; Foley, K. J.

    2014-08-14

    The objective of this demonstration project was to evaluate market-ready retrofit technologies for reducing the energy and water use of multi-load washers in healthcare and hospitality facilities. Specifically, this project evaluated laundry wastewater recycling technology in the hospitality sector and ozone laundry technology in both the healthcare and hospitality sectors. This report documents the demonstration of ozone laundry system installations at the Charleston Place Hotel in Charleston, South Carolina, and the Rogerson House assisted living facility in Boston, Massachusetts.

  16. Plaxica Limited | Open Energy Information

    Open Energy Info (EERE)

    Zip: SW7 2AZ Product: UK-based technology company developing a new generation of polymers derived from sustainable resources. References: Plaxica Limited1 This article is a...

  17. Passive fault current limiting device

    DOE Patents [OSTI]

    Evans, D.J.; Cha, Y.S.

    1999-04-06

    A passive current limiting device and isolator is particularly adapted for use at high power levels for limiting excessive currents in a circuit in a fault condition such as an electrical short. The current limiting device comprises a magnetic core wound with two magnetically opposed, parallel connected coils of copper, a high temperature superconductor or other electrically conducting material, and a fault element connected in series with one of the coils. Under normal operating conditions, the magnetic flux density produced by the two coils cancel each other. Under a fault condition, the fault element is triggered to cause an imbalance in the magnetic flux density between the two coils which results in an increase in the impedance in the coils. While the fault element may be a separate current limiter, switch, fuse, bimetal strip or the like, it preferably is a superconductor current limiter conducting one-half of the current load compared to the same limiter wired to carry the total current of the circuit. The major voltage during a fault condition is in the coils wound on the common core in a preferred embodiment. 6 figs.

  18. Passive fault current limiting device

    DOE Patents [OSTI]

    Evans, Daniel J.; Cha, Yung S.

    1999-01-01

    A passive current limiting device and isolator is particularly adapted for use at high power levels for limiting excessive currents in a circuit in a fault condition such as an electrical short. The current limiting device comprises a magnetic core wound with two magnetically opposed, parallel connected coils of copper, a high temperature superconductor or other electrically conducting material, and a fault element connected in series with one of the coils. Under normal operating conditions, the magnetic flux density produced by the two coils cancel each other. Under a fault condition, the fault element is triggered to cause an imbalance in the magnetic flux density between the two coils which results in an increase in the impedance in the coils. While the fault element may be a separate current limiter, switch, fuse, bimetal strip or the like, it preferably is a superconductor current limiter conducting one-half of the current load compared to the same limiter wired to carry the total current of the circuit. The major voltage during a fault condition is in the coils wound on the common core in a preferred embodiment.

  19. Water vapor and ozone profiles with a CO{sub 2} DIAL system in south Italy

    SciTech Connect (OSTI)

    Bellecci, C.; Caputi, G.; De Donato, F.; Gaudio, P.; Valentini, M.

    1996-12-31

    In this paper the authors present the work carried out at the University of Calabria regarding a prototype of a DIAL system. This has been realized for remote pollution monitoring. Most of the efforts have been done to perform several measurements on an horizontal path in order to scan the wide surrounding area. The concentrations of ozone and water vapor have been carried out using two different methods both related with the DIAL technique. With the integrated technique, average concentrations have been evaluated up to 5 km using topographical targets. In the range resolution technique, profiles of ozone and water vapor have been performed up to 700 m with a spatial resolution of about 30 m. Although the system needs a revision in several subsystems of its set-up, the experimentation has pointed out the performance available and the necessary improvements.

  20. Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

  1. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L.; Koss, T.C.

    1992-10-01

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  2. Tropospheric and Lower Stratospheric Ozone Profiles From AERI-X Emission Spectra

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tropospheric and Lower Stratospheric Ozone Profiles From AERI-X Emission Spectra P. F. Fogal and F. J. Murcray Department of Physics and Astronomy University of Denver Denver, Colorado Introduction The University of Denver Atmospheric Emission Radiometric Interferometer-Extended (AERI-X) has been in regular operation at the Southern Great Plains (SGP) Atmospheric Radiation Measurements (ARM) Program site, conditions permitting, since the mid-1990s. We present here the analysis of several spectra

  3. A new feature in the internal heavy isotope distribution in ozone

    SciTech Connect (OSTI)

    Bhattacharya, S. K. Liang, Mao-Chang; Savarino, Joel; Michalski, G.

    2014-10-07

    Ozone produced by discharge or photolysis of oxygen has unusually heavy isotopic composition ({sup 18}O/{sup 16}O and {sup 17}O/{sup 16}O ratio) which does not follow normal mass fractionation rule: δ{sup 17}O ∼ 0.52{sup *}δ{sup 18}O, expressed as an anomaly Δ{sup 17}O = δ{sup 17}O − 0.52{sup *}δ{sup 18}O. Ozone molecule being an open isosceles triangle can have the heavy isotope located either in its apex or symmetric (s) position or the base or asymmetric (as) position. Correspondingly, one can define positional isotopic enrichment, written as δ{sup 18}O (s) or δ{sup 18}O (as) (and similarly for δ{sup 17}O) as well as position dependent isotope anomaly Δ{sup 17}O (s) and Δ{sup 17}O (as). Marcus and co-workers have proposed a semi-empirical model based in principle on the RRKM model of uni-molecular dissociation but with slight modification (departure from statistical randomness assumption for symmetrical molecules) which explains many features of ozone isotopic enrichment. This model predicts that the bulk isotope anomaly is contained wholly in the asymmetric position and the Δ{sup 17}O (s) is zero. Consequently, Δ{sup 17}O (as) = 1.5 {sup *} Δ{sup 17}O (bulk) (named here simply as the “1.5 rule”) which has been experimentally confirmed over a range of isotopic enrichment. We now show that a critical re-analysis of the earlier experimental data demonstrates a small but significant departure from this 1.5 rule at the highest and lowest levels of enrichments. This departure provides the first experimental proof that the dynamics of ozone formation differs from a statistical model constrained only by restriction of symmetry. We speculate over some possible causes for the departure.

  4. Effects of ozone on the respiratory health, allergic sensitization, and cellular immune system in children

    SciTech Connect (OSTI)

    Zwick, H.; Popp, W.; Wagner, C.; Reiser, K.; Schmoeger, J.B.; Boeck, A.H.; Herkner, K.; Radunsky, K. )

    1991-11-01

    To investigate the lasting effects of high ozone concentrations under environmental conditions, we examined the respiratory health, pulmonary function, bronchial hyperresponsiveness to methacholine, allergic sensitization, and lymphocyte subpopulations of 10- to 14-yr-old children. A total of 218 children recruited from an area with high ozone concentrations (Group A) were tested against 281 children coming from an area with low ozone concentrations (Group B). As to subjective complaints, categorized as 'usually cough with or without phlegm,' 'breathlessness,' and 'susceptibility to chest colds,' there was no difference between the two groups. The lung function parameters were similar, but in Group A subjects' bronchial hyperresponsiveness occurred more frequently and was found to be more severe than in Group B (29.4 versus 19.9%, p less than 0.02; PD20 2,100 {plus minus} 87 versus 2,350 {plus minus} 58 micrograms, p less than 0.05). In both groups the number of children who had been suffering from allergic diseases and sensitization to aeroallergens, found by means of the skin test, was the same. Comparison of the total IgE levels showed no difference at all between the two groups. As far as the white blood cells are concerned, the total and differential cell count was the same, whereas lymphocyte subpopulations showed readily recognizable changes.

  5. V Fuels Biodiesel Limited | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel Limited Jump to: navigation, search Name: V-Fuels Biodiesel Limited Place: United Kingdom Product: UK-based biodiesel producers. References: V-Fuels Biodiesel Limited1...

  6. Belize Electricity Limited | Open Energy Information

    Open Energy Info (EERE)

    Belize Electricity Limited Jump to: navigation, search Logo: Belize Electricity Limited Name: Belize Electricity Limited Abbreviation: BEL Address: PO Box 327 Place: Belize City,...

  7. Estimation of the cloud transmittance from radiometric measurements at the ground level

    SciTech Connect (OSTI)

    Costa, Dario; Mares, Oana

    2014-11-24

    The extinction of solar radiation due to the clouds is more significant than due to any other atmospheric constituent, but it is always difficult to be modeled because of the random distribution of clouds on the sky. Moreover, the transmittance of a layer of clouds is in a very complex relation with their type and depth. A method for estimating cloud transmittance was proposed in Paulescu et al. (Energ. Convers. Manage, 75 690–697, 2014). The approach is based on the hypothesis that the structure of the cloud covering the sun at a time moment does not change significantly in a short time interval (several minutes). Thus, the cloud transmittance can be calculated as the estimated coefficient of a simple linear regression for the computed versus measured solar irradiance in a time interval Δt. The aim of this paper is to optimize the length of the time interval Δt. Radiometric data measured on the Solar Platform of the West University of Timisoara during 2010 at a frequency of 1/15 seconds are used in this study.

  8. Use of North American and European air quality networks to evaluate global chemistry-climate modeling of surface ozone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schnell, J. L.; Prather, M. J.; Josse, B.; Naik, V.; Horowitz, L. W.; Cameron-Smith, P.; Bergmann, D.; Zeng, G.; Plummer, D. A.; Sudo, K.; et al

    2015-04-16

    We test the current generation of global chemistry-climate models in their ability to simulate observed, present-day surface ozone. Models are evaluated against hourly surface ozone from 4217 stations in North America and Europe that are averaged over 1° × 1° grid cells, allowing commensurate model-measurement comparison. Models are generally biased high during all hours of the day and in all regions. Most models simulate the shape of regional summertime diurnal and annual cycles well, correctly matching the timing of hourly (~ 15:00) and monthly (mid-June) peak surface ozone abundance. The amplitude of these cycles is less successfully matched. The observedmore » summertime diurnal range (~ 25 ppb) is underestimated in all regions by about 7 ppb, and the observed seasonal range (~ 21 ppb) is underestimated by about 5 ppb except in the most polluted regions where it is overestimated by about 5 ppb. The models generally match the pattern of the observed summertime ozone enhancement, but they overestimate its magnitude in most regions. Most models capture the observed distribution of extreme episode sizes, correctly showing that about 80% of individual extreme events occur in large-scale, multi-day episodes of more than 100 grid cells. The observed linear relationship showing increases in ozone by up to 6 ppb for larger-sized episodes is also matched.« less

  9. Ozone generation by negative direct current corona discharges in dry air fed coaxial wire-cylinder reactors

    SciTech Connect (OSTI)

    Yehia, Ashraf; Mizuno, Akira

    2013-05-14

    An analytical study was made in this paper for calculating the ozone generation by negative dc corona discharges. The corona discharges were formed in a coaxial wire-cylinder reactor. The reactor was fed by dry air flowing with constant rates at atmospheric pressure and room temperature, and stressed by a negative dc voltage. The current-voltage characteristics of the negative dc corona discharges formed inside the reactor were measured in parallel with concentration of the generated ozone under different operating conditions. An empirical equation was derived from the experimental results for calculating the ozone concentration generated inside the reactor. The results, that have been recalculated by using the derived equation, have agreed with the experimental results over the whole range of the investigated parameters, except in the saturation range for the ozone concentration. Therefore, the derived equation represents a suitable criterion for expecting the ozone concentration generated by negative dc corona discharges in dry air fed coaxial wire-cylinder reactors under any operating conditions in range of the investigated parameters.

  10. Tritium Detection Methods and Limitations

    Office of Environmental Management (EM)

    Detection Methods and Limitations Tritium Focus Group Meeting, April 2014 Tom Voss, Northern New Mexico DOE-HDBK-1105-2002 RADIOLOGICAL TRAINING FOR TRITIUM FACILITIES U.S. Department of Energy AREA TRNG Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. DOE-HDBK-1105-2002 Radiological Training for Tritium Facilities U.S. Department of Energy, Radiological Control Programs for Special Tritium Compounds, DOE-STD- draft, Washington, D.C.

  11. Detection of ocean glint and ozone absorption using LCROSS Earth observations

    SciTech Connect (OSTI)

    Robinson, Tyler D.; Ennico, Kimberly; Meadows, Victoria S.; Sparks, William; Schwieterman, Edward W.; Bussey, D. Ben J.; Breiner, Jonathan

    2014-06-01

    The Lunar CRater Observation and Sensing Satellite (LCROSS) observed the distant Earth on three occasions in 2009. These data span a range of phase angles, including a rare crescent phase view. For each epoch, the satellite acquired near-infrared and mid-infrared full-disk images, and partial-disk spectra at 0.26-0.65 μm (λ/Δλ ∼ 500) and 1.17-2.48 μm (λ/Δλ ∼ 50). Spectra show strong absorption features due to water vapor and ozone, which is a biosignature gas. We perform a significant recalibration of the UV-visible spectra and provide the first comparison of high-resolution visible Earth spectra to the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional spectral Earth model. We find good agreement with the observations, reproducing the absolute brightness and dynamic range at all wavelengths for all observation epochs, thus validating the model to within the ∼10% data calibration uncertainty. Data-model comparisons reveal a strong ocean glint signature in the crescent phase data set, which is well matched by our model predictions throughout the observed wavelength range. This provides the first observational test of a technique that could be used to determine exoplanet habitability from disk-integrated observations at visible and near-infrared wavelengths, where the glint signal is strongest. We examine the detection of the ozone 255 nm Hartley and 400-700 nm Chappuis bands. While the Hartley band is the strongest ozone feature in Earth's spectrum, false positives for its detection could exist. Finally, we discuss the implications of these findings for future exoplanet characterization missions.

  12. Effects of ambient ozone on respiratory function and symptoms in Mexico City schoolchildren

    SciTech Connect (OSTI)

    Castillejos, M.; Gold, D.R.; Dockery, D.; Tosteson, T.; Baum, T.; Speizer, F.E. )

    1992-02-01

    The effects of ambient ozone (O3) on respiratory function and acute respiratory symptoms were evaluated in 143 7- to 9-yr-old schoolchildren followed longitudinally at 1- to 2-wk intervals over a period of 6 months at three schools in Pedregal, Mexico City. The maximum O3 level exceeded the World Health Organization guideline of 80 ppb and the U.S. standard of 120 ppb in every week. For an increase from lowest to highest in the mean O3 level during the 48 hr before spirometry (53 ppb), logistic regression estimated relative odds of 1.7 for a child reporting cough/phlegm on the day of spirometry. For the full population, the mean O3 level during the hour before spirometry, not adjusted for temperature and humidity, predicted a significant decrement in FVC but not in FEV1 or FEF25-75. In contrast, the mean O3 level during the previous 24-, 48-, and 168-h periods predicted significant decrements in FEV1 and FEF25-75 but not in FVC. Ozone was consistently associated with a greater decrement in lung function for the 15 children with chronic phlegm as compared with the children without chronic cough, chronic phlegm, or wheeze. Ozone in the previous 24-, 48-, and 168-h periods predicted decrements in FEV1 for children of mothers who were current or former smokers, but not for children of mothers who were never smokers. Many of these effects were reduced in multiple regression analyses including temperature and humidity, as temperature and O3 were highly correlated.

  13. Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region

    SciTech Connect (OSTI)

    Steiner, A. L.; Tawfik, A. B.; Shalaby, A.; Zakey, A. S.; Abdel Wahab, M. M.; Salah, Z.; Solmon, F.; Sillman, S.; Zaveri, Rahul A.

    2014-04-16

    An integrated chemistry-climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on Greater Cairo (GC) region. The densley populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjuction with natural sources such as dust and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average-ground-based NO2 observations of 40-60 ppb are substantially higher than modeled estimates (5-10 ppb), likely due to model grid resolution, improper boundary layer representation, and poor emissions inventories. Observed ozone concentrations range from 35 ppb (winter) to 80 ppb (summer). The model reproduces the seasonal cycle fairly well, but modeled summer ozone is understimated by approximately 15 ppb and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry-climate model captures the springtime peak aerosol optical depth (AOD) of 0.7-1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta, yet the model underestimates this fall observed AOD peak, as standard emissions inventories underestimate this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities are needed to improve air quality simulations in this region.

  14. Highly reproducible and reliable metal/graphene contact by ultraviolet-ozone treatment

    SciTech Connect (OSTI)

    Li, Wei [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China); Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Hacker, Christina A.; Cheng, Guangjun; Hight Walker, A. R.; Richter, Curt A.; Gundlach, David J., E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn [Physical Measurement Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Liang, Yiran; Tian, Boyuan; Liang, Xuelei, E-mail: david.gundlach@nist.gov, E-mail: liangxl@pku.edu.cn; Peng, Lianmao [Key Laboratory for the Physics and Chemistry of Nanodevices and Department of Electronics, Peking University, Beijing 100871 (China)

    2014-03-21

    Resist residue from the device fabrication process is a significant source of contamination at the metal/graphene contact interface. Ultraviolet Ozone (UVO) treatment is proven here, by X-ray photoelectron spectroscopy and Raman measurement, to be an effective way of cleaning the metal/graphene interface. Electrical measurements of devices that were fabricated by using UVO treatment of the metal/graphene contact region show that stable and reproducible low resistance metal/graphene contacts are obtained and the electrical properties of the graphene channel remain unaffected.

  15. Systemic responses to inhaled ozone in mice: cachexia and down-regulation of liver xenobiotic metabolizing genes

    SciTech Connect (OSTI)

    Last, Jerold A. . E-mail: jalast@ucdavis.edu; Gohil, Kishorchandra; Mathrani, Vivek C.; Kenyon, Nicholas J.

    2005-10-15

    Rats or mice acutely exposed to high concentrations of ozone show an immediate and significant weight loss, even when allowed free access to food and water. The mechanisms underlying this systemic response to ozone have not been previously elucidated. We have applied the technique of global gene expression analysis to the livers of C57BL mice acutely exposed to ozone. Mice lost up to 14% of their original body weight, with a 42% decrease in total food consumption. We previously had found significant up-regulation of genes encoding proliferative enzymes, proteins related to acute phase reactions and cytoskeletal functions, and other biomarkers of a cachexia-like inflammatory state in lungs of mice exposed to ozone. These results are consistent with a general up-regulation of different gene families responsive to NF-{kappa}B in the lungs of the exposed mice. In the present study, we observed significant down-regulation of different families of mRNAs in the livers of the exposed mice, including genes related to lipid and fatty acid metabolism, and to carbohydrate metabolism in this tissue, consistent with a systemic cachexic response. Several interferon-dependent genes were down-regulated in the liver, suggesting a possible role for interferon as a signaling molecule between lung and liver. In addition, transcription of several mRNAs encoding enzymes of xenobiotic metabolism in the livers of mice exposed to ozone was decreased, suggesting cytokine-mediated suppression of cytochrome P450 expression. This finding may explain a previously controversial report from other investigators more than 20 years ago of prolongation of pentobarbital sleeping time in mice exposed to ozone.

  16. Use of North American and European air quality networks to evaluate global chemistry–climate modeling of surface ozone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schnell, J. L.; Prather, M. J.; Josse, B.; Naik, V.; Horowitz, L. W.; Cameron-Smith, P.; Bergmann, D.; Zeng, G.; Plummer, D. A.; Sudo, K.; et al

    2015-09-25

    We test the current generation of global chemistry–climate models in their ability to simulate observed, present-day surface ozone. Models are evaluated against hourly surface ozone from 4217 stations in North America and Europe that are averaged over 1° × 1° grid cells, allowing commensurate model–measurement comparison. Models are generally biased high during all hours of the day and in all regions. Most models simulate the shape of regional summertime diurnal and annual cycles well, correctly matching the timing of hourly (~ 15:00 local time (LT)) and monthly (mid-June) peak surface ozone abundance. The amplitude of these cycles is less successfullymore » matched. The observed summertime diurnal range (~ 25 ppb) is underestimated in all regions by about 7 ppb, and the observed seasonal range (~ 21 ppb) is underestimated by about 5 ppb except in the most polluted regions, where it is overestimated by about 5 ppb. The models generally match the pattern of the observed summertime ozone enhancement, but they overestimate its magnitude in most regions. Most models capture the observed distribution of extreme episode sizes, correctly showing that about 80 % of individual extreme events occur in large-scale, multi-day episodes of more than 100 grid cells. The models also match the observed linear relationship between episode size and a measure of episode intensity, which shows increases in ozone abundance by up to 6 ppb for larger-sized episodes. We conclude that the skill of the models evaluated here provides confidence in their projections of future surface ozone.« less

  17. Predicting tropospheric ozone and hydroxyl radical in a global, three-dimensional, chemistry, transport, and deposition model

    SciTech Connect (OSTI)

    Atherton, C.S.

    1995-01-05

    Two of the most important chemically reactive tropospheric gases are ozone (O{sub 3}) and the hydroxyl radical (OH). Although ozone in the stratosphere is a necessary protector against the sun`s radiation, tropospheric ozone is actually a pollutant which damages materials and vegetation, acts as a respiratory irritant, and is a greenhouse gas. One of the two main sources of ozone in the troposphere is photochemical production. The photochemistry is initiated when hydrocarbons and carbon monoxide (CO) react with nitrogen oxides (NO{sub x} = NO + NO{sub 2}) in the presence of sunlight. Reaction with the hydroxyl radical, OH, is the main sink for many tropospheric gases. The hydroxyl radical is highly reactive and has a lifetime on the order of seconds. Its formation is initiated by the photolysis of tropospheric ozone. Tropospheric chemistry involves a complex, non-linear set of chemical reactions between atmospheric species that vary substantially in time and space. To model these and other species on a global scale requires the use of a global, three-dimensional chemistry, transport, and deposition (CTD) model. In this work, I developed two such three dimensional CTD models. The first model incorporated the chemistry necessary to model tropospheric ozone production from the reactions of nitrogen oxides with carbon monoxide (CO) and methane (CH{sub 4}). The second also included longer-lived alkane species and the biogenic hydrocarbon isoprene, which is emitted by growing plants and trees. The models` ability to predict a number of key variables (including the concentration of O{sub 3}, OH, and other species) were evaluated. Then, several scenarios were simulated to understand the change in the chemistry of the troposphere since preindustrial times and the role of anthropogenic NO{sub x} on present day conditions.

  18. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, Daniel M.; Rosen, Robert S.

    2005-04-19

    A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.

  19. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, D.M.; Rosen, R.S.

    1998-06-30

    A cartridge primer is described which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML`s would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers. 10 figs.

  20. Limited-life cartridge primers

    DOE Patents [OSTI]

    Makowiecki, Daniel M.; Rosen, Robert S.

    1998-01-01

    A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.

  1. United Group Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: United Group Limited Place: Perth, Western Australia, Australia Zip: 6001 Product: The United Group Resources (UGL) division is an EPC and...

  2. Tidal Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: Tidal Energy Limited (TEL) Place: Cardiff, Wales, United Kingdom Zip: CF23 8RS Product: Tidal stream device developer. Coordinates:...

  3. Mauktika Energy Limited MEL | Open Energy Information

    Open Energy Info (EERE)

    Mauktika Energy Limited MEL Jump to: navigation, search Name: Mauktika Energy Limited (MEL) Place: Hyderabad, Andhra Pradesh, India Zip: 500033 Sector: Renewable Energy Product:...

  4. Nufcor International Limited Nufcor | Open Energy Information

    Open Energy Info (EERE)

    Limited (Nufcor) Place: United Kingdom Sector: Services Product: UK-based uranium marketing services company. References: Nufcor International Limited (Nufcor)1 This article...

  5. SRSL Ethanol Limited | Open Energy Information

    Open Energy Info (EERE)

    SRSL Ethanol Limited Jump to: navigation, search Name: SRSL Ethanol Limited Place: Mumbai, Maharashtra, India Product: Mumbai-based ethanol subsidiary of Shree Renuka Sugars...

  6. Rix Biodiesel Limited | Open Energy Information

    Open Energy Info (EERE)

    Rix Biodiesel Limited Jump to: navigation, search Name: Rix Biodiesel Limited Place: Hull, United Kingdom Zip: HU8 7JR Product: Manufacture, blends and resells biodiesel....

  7. China Innovation Investment Limited | Open Energy Information

    Open Energy Info (EERE)

    Innovation Investment Limited Jump to: navigation, search Name: China Innovation Investment Limited Place: Hong Kong Sector: Solar Product: Hong Kong-listed alternative energy...

  8. Voith Hydro Wavegen Limited | Open Energy Information

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    Voith Hydro Wavegen Limited Jump to: navigation, search Name: Voith Hydro Wavegen Limited Region: United Kingdom Sector: Marine and Hydrokinetic Website: www.wavegen.co.uk This...

  9. Cape Systems Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: Cape Systems Limited Place: Rock Sound, Bahamas Sector: Services Product: Offers installation and site surveying services for clean...

  10. United Biofuels Private Limited | Open Energy Information

    Open Energy Info (EERE)

    United Biofuels Private Limited Jump to: navigation, search Name: United Biofuels Private Limited Place: Tamil Nadu, India Sector: Biomass Product: India-based owner and operator...

  11. BFC Solutions Limited | Open Energy Information

    Open Energy Info (EERE)

    BFC Solutions Limited Jump to: navigation, search Name: BFC Solutions Limited Place: Taunton, England, United Kingdom Zip: TA1 PEJ Sector: Carbon Product: Somerset-based...

  12. Harvard Dedicated Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Harvard Dedicated Energy Limited Jump to: navigation, search Name: Harvard Dedicated Energy Limited Place: Massachusetts Phone Number: (617) 495-5560 Website: www.energyandfaciliti...

  13. Gujarat Ambuja Cements Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: Gujarat Ambuja Cements Limited Place: Mumbai, India Zip: 400 021 Sector: Biomass Product: Indian cement company. the company...

  14. Catamount Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: Catamount Energy Limited Place: United Kingdom Sector: Wind energy Product: Wind power project developer working on projects in Scotland....

  15. WaikatoLink Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Jump to: navigation, search Name: WaikatoLink Limited Place: New Zealand Sector: Services Product: General Financial & Legal Services ( Individual Angel network )...

  16. Greenergy Biofuels Limited | Open Energy Information

    Open Energy Info (EERE)

    Biofuels Limited Jump to: navigation, search Name: Greenergy Biofuels Limited Place: London, Greater London, United Kingdom Zip: WC1V 7BD Sector: Biofuels Product: Imports, blends...

  17. Transmission Capital Limited | Open Energy Information

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    Transmission Capital Limited Jump to: navigation, search Name: Transmission Capital Limited Place: London, United Kingdom Zip: EC2V 7HR Sector: Renewable Energy, Services Product:...

  18. Impact Capital Partners Limited | Open Energy Information

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    Capital Partners Limited Jump to: navigation, search Name: Impact Capital Partners Limited Place: Los Angeles, California Zip: CA 90067-1509 Product: Los Angeles-based, investment...

  19. Power Projects Limited | Open Energy Information

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    Limited Jump to: navigation, search Name: Power Projects Limited Address: PO Box 25456 Panama Street Place: Wellington Zip: 6146 Region: New Zealand Sector: Marine and Hydrokinetic...

  20. Central Electronics Limited CEL | Open Energy Information

    Open Energy Info (EERE)

    Electronics Limited CEL Jump to: navigation, search Name: Central Electronics Limited (CEL) Place: Sahibabad, Uttar Pradesh, India Zip: 201010 Sector: Solar Product: String...

  1. Universal Carbon Credits Limited | Open Energy Information

    Open Energy Info (EERE)

    Universal Carbon Credits Limited Jump to: navigation, search Name: Universal Carbon Credits Limited Place: London, England, United Kingdom Zip: EC3A6DF Sector: Carbon Product:...

  2. Carbon Trust Enterprises Limited | Open Energy Information

    Open Energy Info (EERE)

    Enterprises Limited Jump to: navigation, search Name: Carbon Trust Enterprises Limited Place: London, United Kingdom Zip: WC2A 2AZ Sector: Carbon Product: Carbon Trust Enterprises...

  3. Carbon Limiting Technologies | Open Energy Information

    Open Energy Info (EERE)

    Limiting Technologies Jump to: navigation, search Name: Carbon Limiting Technologies Place: London, Greater London, United Kingdom Zip: N1 8HA Sector: Carbon Product: UK-based...

  4. Clipper Windpower Europe Limited | Open Energy Information

    Open Energy Info (EERE)

    Clipper Windpower Europe Limited Jump to: navigation, search Name: Clipper Windpower Europe Limited Place: London, Greater London, United Kingdom Zip: SE1 7TJ Sector: Wind energy...

  5. Renewable Fuels Limited RFL | Open Energy Information

    Open Energy Info (EERE)

    Limited RFL Jump to: navigation, search Name: Renewable Fuels Limited (RFL) Place: York, United Kingdom Zip: YO19 6ET Sector: Biomass Product: Supplies various biomass fuels and...

  6. Genotypic variability in ponderosa pine responses to combined ozone and drought stresses

    SciTech Connect (OSTI)

    Temple, P.J.

    1995-06-01

    Five-year-old ponderosa (Pinus ponderosa Laws.) seedlings from 18 half-sib and one full-sib families obtained from the California Tree Improvement Program were harvested after 1, 2, and 3 growing seasons of exposure to three levels of ozone (O{sub 3}) and two levels of available soil water (ASW) in open-top chambers in the California Sierras. Seedlings were evaluated for O{sub 3} injury symptoms, biomass, and radial growth in response to these stresses. Ozone injury responses were highly variable across families, but family rankings for O{sub 3} injury were consistent across years. Family rankings for O{sub 3} injury were highly correlated with those for reductions in biomass and radial growth for trees in the high ASW treatment, but drought-stressed trees showed no consistent relation between foliar 03 injury and reductions in growth. After three seasons of exposure to 88 ppb O{sub 3}, foliar biomass of the three most susceptible families averaged 60% less than trees in the low-O{sub 3} control, while O{sub 3} had no effect on growth of the three most resistant families. Variability across families of growth responses to drought was significantly less than the variability in seedling responses to O{sub 3}.

  7. Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases. Final report

    SciTech Connect (OSTI)

    Prather, Michael J.; Hsu, Juno; Nicolau, Alex; Veidenbaum, Alex; Smith, Philip Cameron; Bergmann, Dan

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  8. NOx Emission Reduction and its Effects on Ozone during the 2008 Olympic Games

    SciTech Connect (OSTI)

    Yang, Qing; Wang, Yuhang; Zhao, Chun; Liu, Zhen; Gustafson, William I.; Shao, Min

    2011-07-15

    We applied a daily-assimilated inversion method to estimate NOx (NO+NO2) emissions for June-September 2007 and 2008 on the basis of the Aura Ozone Monitoring Instrument (OMI) observations of nitrogen dioxide (NO2) and model simulations using the Regional chEmistry and trAnsport Model (REAM). Over urban Beijing, rural Beijing, and the Huabei Plain, OMI column NO2 reductions are approximately 45%, 33%, and 14%, respectively, while the corresponding anthropogenic NOx emission reductions are only 28%, 24%, and 6%, during the full emission control period (July 20 Sep 20, 2008). The emission reduction began in early July and was in full force by July 20, corresponding to the scheduled implementation of emission controls over Beijing. The emissions did not appear to recover after the emission control period. Meteorological change from summer 2007 to 2008 is the main factor contributing to the column NO2 decreases not accounted for by the emission reduction. Model simulations suggest that the effect of emission reduction on ozone concentrations over Beijing is relatively minor using a standard VOC emission inventory in China. With an adjustment of the model emissions to reflect in situ observations of VOCs in Beijing, the model simulation suggests a larger effect of the emission reduction.

  9. Ozone-forming potential of a series of oxygenated organic compounds

    SciTech Connect (OSTI)

    Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. )

    1991-03-01

    An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

  10. Shear wall ultimate drift limits

    SciTech Connect (OSTI)

    Duffey, T.A.; Goldman, A.; Farrar, C.R.

    1994-04-01

    Drift limits for reinforced-concrete shear walls are investigated by reviewing the open literature for appropriate experimental data. Drift values at ultimate are determined for walls with aspect ratios ranging up to a maximum of 3.53 and undergoing different types of lateral loading (cyclic static, monotonic static, and dynamic). Based on the geometry of actual nuclear power plant structures exclusive of containments and concerns regarding their response during seismic (i.e.,cyclic) loading, data are obtained from pertinent references for which the wall aspect ratio is less than or equal to approximately 1, and for which testing is cyclic in nature (typically displacement controlled). In particular, lateral deflections at ultimate load, and at points in the softening region beyond ultimate for which the load has dropped to 90, 80, 70, 60, and 50 percent of its ultimate value, are obtained and converted to drift information. The statistical nature of the data is also investigated. These data are shown to be lognormally distributed, and an analysis of variance is performed. The use of statistics to estimate Probability of Failure for a shear wall structure is illustrated.

  11. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore » same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  12. Controlling superconductivity in La2-xSrxCuO4+δ by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+δ thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore »same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  13. ARM - Ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox ...

  14. Ge Interface Engineering with Ozone-oxidation for Low Interface State Density

    SciTech Connect (OSTI)

    Kuzum, Duygu; Krishnamohan, T.; Pethe, Abhijit J.; Okyay, Ali, K.; Oshima, Yasuhiro; Sun, Yun; McVittie, Jim P.; Pianetta, Piero A.; McIntyre, Paul C.; Saraswat, Krishna C.; /Stanford U., CIS

    2008-06-02

    Passivation of Ge has been a critical issue for Ge MOS applications in future technology nodes. In this letter, we introduce ozone-oxidation to engineer Ge/insulator interface. Interface states (D{sub it}) values across the bandgap and close to conduction bandedge were extracted using conductance technique at low temperatures. D{sub it} dependency on growth conditions was studied. Minimum D{sub it} of 3 x 10{sup 11} cm{sup -2} V{sup -1} was demonstrated. Physical quality of the interface was investigated through Ge 3d spectra measurements. We found that the interface and D{sub it} is strongly affected by the distribution of oxidation states and quality of the suboxide.

  15. Biodiesel Energy Trading Limited | Open Energy Information

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    Limited Jump to: navigation, search Name: Biodiesel Energy Trading Limited Place: London, United Kingdom Zip: W1J 8DY Product: London-based company focused on trading of biodiesel....

  16. IT Power Limited | Open Energy Information

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    IT Power Limited Jump to: navigation, search Name: IT Power Limited Place: Basingstoke, England, United Kingdom Zip: RG24 8AG Sector: Renewable Energy Product: IT Power is a...

  17. EU Energy Wind Limited | Open Energy Information

    Open Energy Info (EERE)

    Wind Limited Jump to: navigation, search Name: EU Energy (Wind) Limited Place: Central Milton Keynes, United Kingdom Zip: K9 1LH Sector: Wind energy Product: The company will be...

  18. Lead Hero Limited | Open Energy Information

    Open Energy Info (EERE)

    Hero Limited Jump to: navigation, search Name: Lead Hero Limited Place: China Product: China-based company that holds a 100% interest in XiAn Lv Jing and a 15.05% interest in...

  19. Graduate Program Time Limits and Work Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time Limits and Work Schedules Graduate Program Time Limits and Work Schedules Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive...

  20. Undergraduate Program Time Limits and Work Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time Limits and Work Schedules Undergraduate Program Time Limits and Work Schedules Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive...

  1. GenDrive Limited | Open Energy Information

    Open Energy Info (EERE)

    GenDrive Limited Jump to: navigation, search Name: GenDrive Limited Place: Cambridge, United Kingdom Zip: CB23 3GY Sector: Renewable Energy, Solar, Wind energy Product: Developing...

  2. Mistral Invest Limited | Open Energy Information

    Open Energy Info (EERE)

    Mistral Invest Limited Jump to: navigation, search Name: Mistral Invest Limited Place: London, United Kingdom Zip: W1U 7DW Sector: Wind energy Product: Private Equity Fund aiming...

  3. Zebec Biogas Limited | Open Energy Information

    Open Energy Info (EERE)

    Zebec Biogas Limited Jump to: navigation, search Name: Zebec Biogas Limited Place: Glasgow, Scotland, United Kingdom Zip: G12 9JD Product: Sotland-based biogas company. The firm is...

  4. Limited English Proficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Limited English Proficiency Limited English Proficiency On August 11, 2000, President Clinton signed Executive Order 13166, "Improving Access to Services for Persons with Limited English Proficiency." The Executive Order requires federal agencies, including the Department of Energy, to examine the programs and services they provide, to determine whether there is a need for language assistance for persons with Limited English proficiency (LEP) related to their programs and services, and

  5. Exorka International Limited | Open Energy Information

    Open Energy Info (EERE)

    Exorka International Limited is a specialist developer of low-temperature geothermal electricity generation, incorporated in England. References: Exorka International...

  6. Undergraduate Program Time Limits and Work Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time Limits and Work Schedules Undergraduate Program Time Limits and Work Schedules Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive environment that is rich in intellectual vitality and opportunities for growth. Contact Student Programs (505) 665-0987 Email Time limits The length of participation in the undergraduate program is limited to a maximum of six years for students pursuing a bachelor's degree and three years for students pursuing an

  7. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, J.R.

    1997-02-04

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  8. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, John R.

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  9. Primordial magnetic field limits from cosmological data

    SciTech Connect (OSTI)

    Kahniashvili, Tina [McWilliams Center for Cosmology and Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Department of Physics, Laurentian University, Ramsey Lake Road, Sudbury, Ontario P3E 2C (Canada); Abastumani Astrophysical Observatory, Ilia State University, 2A Kazbegi Ave, Tbilisi, GE-0160 (Georgia); Tevzadze, Alexander G. [Abastumani Astrophysical Observatory, Ilia State University, 2A Kazbegi Ave, Tbilisi, GE-0160 (Georgia); Faculty of Exact and Natural Sciences, Tbilisi State University, 1 Chavchavadze Avenue, Tbilisi, GE-0128 (Georgia); Sethi, Shiv K. [McWilliams Center for Cosmology and Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Raman Research Institute, Sadashivanagar, Bangalore 560080 (India); Pandey, Kanhaiya [Raman Research Institute, Sadashivanagar, Bangalore 560080 (India); Ratra, Bharat [Department of Physics, Kansas State University, 116 Cardwell Hall, Manhattan, Kansas 66506 (United States)

    2010-10-15

    We study limits on a primordial magnetic field arising from cosmological data, including that from big bang nucleosynthesis, cosmic microwave background polarization plane Faraday rotation limits, and large-scale structure formation. We show that the physically relevant quantity is the value of the effective magnetic field, and limits on it are independent of how the magnetic field was generated.

  10. Removal of pollutant compounds from water supplies using ozone, ultraviolet light, and a counter, current packed column. Master's thesis

    SciTech Connect (OSTI)

    Kelly, E.L.

    1991-01-01

    Many water pollutants are determined to be carcinogenic and often appear in very low concentrations and still pose a health risk. Conventional water treatment processes cannot remove these contaminants and there is a great demand for the development of alternative removal technologies. The use of ozone and ultraviolet light in a counter current packed column could prove to be an effective treatment process to remove these contaminants.

  11. Green Heat Solutions Limited | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Green Heat Solutions Limited Region: Scotland Sector: Marine and Hydrokinetic Website: http: This company is listed in the Marine and Hydrokinetic...

  12. Acquasol Infrastructure Limited | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Acquasol Infrastructure Limited Place: Adelaide, South Australia, Australia Zip: 5000 Sector: Solar Product: Adelaide based solar thermal project and...

  13. Carnegie Wave Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Address: 1 124 Stirling Highway Place: North Fremantle Zip: 6159 Region: Australia Sector: Marine and Hydrokinetic Year Founded: 1993 Website: www.carnegiewave.com...

  14. Power Paper Limited | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Power Paper Limited Place: Kiryat Arye, Petah Tikva, Israel Zip: 49130 Product: Power Paper is a developer of next-generation, printable...

  15. GP Batteries International Limited | Open Energy Information

    Open Energy Info (EERE)

    International Limited is principally engaged in the development, manufacture and marketing of batteries and battery-related products. References: GP Batteries International...

  16. Interim Guidance Regarding Limitations on CERCLA Liability |...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Inner-Office Memorandum: Interim Guidance Regarding Limitations on CERCLA LiabilityPermitting...

  17. Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon...

    Office of Scientific and Technical Information (OSTI)

    Hydrogenation of Dislocation- Limited Heteroepitaxial Silicon Solar Cells Preprint Michael L. Bolen, Sachit Grover, Charles W. Teplin, Howard M. Branz, and Paul Stradins National...

  18. Amperex Technology Limited ATL | Open Energy Information

    Open Energy Info (EERE)

    Technology Limited (ATL) Place: N.T., Hong Kong Product: Designer and manufacturer of Lithium Ion Polymer (LIP) battery cells and batteries for OEM customers making cell phones,...

  19. EVO Electric Limited | Open Energy Information

    Open Energy Info (EERE)

    Greater London, United Kingdom Zip: GU21 5JY Product: EVO Electric Limited develops electrical motors and generators for use in gensets, powertrains, and traction motors in...

  20. 12 Voltz Limited | Open Energy Information

    Open Energy Info (EERE)

    Limited Place: Cumbria, United Kingdom Zip: LA8 9NH Sector: Renewable Energy, Solar, Wind energy Product: Selling and delivering broad range of advanced energy generating...

  1. Caldyne Automatics Limited | Open Energy Information

    Open Energy Info (EERE)

    storage product manufacturer; also makes lighting systems based on solar, wind and solar wind hybrid systems. References: Caldyne Automatics Limited1 This article is a stub....

  2. Maharashtra State Power Generation Company Limited MAHAGENCO...

    Open Energy Info (EERE)

    search Name: Maharashtra State Power Generation Company Limited (MAHAGENCO) Place: Mumbai, Maharashtra, India Zip: 400051 Product: Power generating firm planning to set up a...

  3. Vihaan Networks Limited VNL | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Vihaan Networks Limited (VNL) Place: Gurgaon, Haryana, India Zip: 122015 Sector: Solar Product: Developer of solar-powered GSM system for rural...

  4. Bharat Renewable Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Energy Limited Place: Lucknow, Uttar Pradesh, India Product: Uttar Pradesh-based joint venture company for the production, procurement, cultivation and plantation of crops...

  5. Colony Mills Limited | Open Energy Information

    Open Energy Info (EERE)

    Place: Lahore, Pakistan Sector: Solar Product: Yarn manufacturer, plans to set up solar thermal plant. References: Colony Mills Limited1 This article is a stub. You can help...

  6. Cumbria Wind Farms Limited | Open Energy Information

    Open Energy Info (EERE)

    United Kingdom Zip: SY16 2LW Sector: Services Product: Provides operational and maintenance services in Cumbria, Cornwall and Wales. References: Cumbria Wind Farms Limited1...

  7. Hebei Hydroelectric Company Limited | Open Energy Information

    Open Energy Info (EERE)

    Place: Shijiazhuang, Hebei Province, China Zip: 50011 Sector: Hydro Product: China-based small hydro project developer. References: Hebei Hydroelectric Company Limited1 This...

  8. Proactive Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Energy Product: Scotland-based renewable energy company that is developing a 5MW biogas plant in South Lanarkshire. References: Proactive Energy Limited1 This article is a...

  9. Wedotebary Nigeria Limited | Open Energy Information

    Open Energy Info (EERE)

    Name: Wedotebary Nigeria Limited Place: Bukuru, Nigeria Product: Nigeria-based manufacturing conglomerate. Coordinates: 9.79017, 8.85481 Show Map Loading map......

  10. CarbonPlan Limited | Open Energy Information

    Open Energy Info (EERE)

    as a consultant advising on renewable energy technologies, energy efficiency, & corporate social responsibility. References: CarbonPlan Limited1 This article is a stub. You can...

  11. Local Generation Limited | Open Energy Information

    Open Energy Info (EERE)

    United Kingdom Sector: Biomass Product: UK-based biomass firm developing anaerobic digestion plants. References: Local Generation Limited1 This article is a stub. You can help...

  12. Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon...

    Office of Scientific and Technical Information (OSTI)

    Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint Bolen, M. L.; Grover, S.; Teplin, C. W.; Bobela, D.; Branz, H. M.; Stradins, P. 08 HYDROGEN; 14...

  13. Graduate Program Time Limits and Work Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time Limits and Work Schedules Graduate Program Time Limits and Work Schedules Point your career towards Los Alamos Lab: work with the best minds on the planet in an inclusive environment that is rich in intellectual vitality and opportunities for growth. Contact Student Programs (505) 665-0987 Email Time Limits The length of participation in the graduate program is limited as follows: With a bachelor's pursuing a master's degree: 4 years With a bachelor's pursuing a PhD: 7 years With a master's

  14. Royal Energy Limited REL | Open Energy Information

    Open Energy Info (EERE)

    (REL) Place: Mumbai, Maharashtra, India Zip: 400 016 Product: Mumbai-based ethanol and biodiesel producer. References: Royal Energy Limited (REL)1 This article is a stub. You...

  15. Self-triggering superconducting fault current limiter

    DOE Patents [OSTI]

    Yuan, Xing; Tekletsadik, Kasegn

    2008-10-21

    A modular and scaleable Matrix Fault Current Limiter (MFCL) that functions as a "variable impedance" device in an electric power network, using components made of superconducting and non-superconducting electrically conductive materials. The matrix fault current limiter comprises a fault current limiter module that includes a superconductor which is electrically coupled in parallel with a trigger coil, wherein the trigger coil is magnetically coupled to the superconductor. The current surge doing a fault within the electrical power network will cause the superconductor to transition to its resistive state and also generate a uniform magnetic field in the trigger coil and simultaneously limit the voltage developed across the superconductor. This results in fast and uniform quenching of the superconductors, significantly reduces the burnout risk associated with non-uniformity often existing within the volume of superconductor materials. The fault current limiter modules may be electrically coupled together to form various "n" (rows).times."m" (columns) matrix configurations.

  16. Comparison of the responses of children and adults to acute ozone exposure

    SciTech Connect (OSTI)

    McDonnell, W.F.; Chapman, R.S.; Horstman, D.H.; Leigh, M.W.; Salaam, S.A.

    1986-07-01

    The purpose of the paper is to compare the results of two studies in which the respiratory responses of children and adults to acute ozone (O/sub 3/) exposure were measured. Forty-two 18-30 year old males were exposed for 2.5 hours in a controlled environmental chamber to either 0.0 or 0.12 ppm O3 while performing intermittent heavy exercise. Twenty-two 8-11 year old males were exposed in a similar manner to both air and 0.12 ppm O3. Measures of respiratory symptoms and function were made before and after exposure. Adults experienced an increase in the symptom cough and decrements in forced vital capacity and some measures of forced expiratory flow. Children experienced similar decrements in pulmonary function, but had no increase in symptoms. The authors concluded that as measured by pulmonary function children appear to be no more responsive to O3 exposure than are adults and may experience fewer symptoms.

  17. Respiratory responses of vigorously exercising children to 0. 12 ppm ozone exposure

    SciTech Connect (OSTI)

    McDonnell, W.F. 3d.; Chapman, R.S.; Leigh, M.W.; Strope, G.L.; Collier, A.M.

    1985-10-01

    Changes in respiratory function have been suggested for children exposed to less than 0.12 ppm ozone (O3) while engaged in normal activities. Because the results of these studies have been confounded by other variables, such as temperature or the presence of other pollutants or have been questioned as to the adequacy of exposure measurements, the authors determined the acute response of children exposed to 0.12 ppm O3 in a controlled chamber environment. Twenty-three white males 8 to 11 yr of age were exposed once to clean air and once to 0.12 ppm O3 in random order. Exposures were for 2.5 h and included 2 h of intermittent heavy exercise. Measures of forced expiratory volume in one second (FEV1) and the symptom cough were determined prior to and after each exposure. A significant decline in FEV1 was found after the O3 exposure compared to the air exposure, and it appeared to persist for 16 to 20 h. No significant increase in cough was found due to O3 exposure. Forced vital capacity, specific airways resistance, respiratory frequency, tidal volume, and other symptoms were measured in a secondary exploratory analysis of this study.

  18. OZONE PRODUCTION IN THE PHILADELPHIA URBAN AREA DURING NE-OPS 99.

    SciTech Connect (OSTI)

    KLEINMAN,L.I.; DAUM,P.H.; BRECHTEL,F.; LEE,Y.N.; NUNNERMACKER,L.J.; SPRINGSTON,S.R.; WEINSTEIN-LLOYD,J.

    2001-10-01

    As part of the 1999 NARSTO Northeast Oxidant and Particulate Study (NE-OPS) field campaign, the DOE G-1 aircraft sampled trace gases and aerosols in and around the Philadelphia metropolitan area. Twenty research flights were conducted between July 25 and August 11. The overall goals of these flights were to obtain a mechanistic understanding of O{sub 3} production; to characterize the spatial and temporal behavior of photo-oxidants and aerosols; and to study the evolution of aerosol size distributions, including the process of new particle formation. Within the NE-OPS program, other groups provided additional trace gas, aerosol, and meteorological observations using aircraft, balloon, remote sensing, and surface based instruments (Phillbrick et al., 2000). In this article we provide an overview of the G-1 observations related to O{sub 3} production, focusing on the vertical distribution of pollutants. Ozone production rates are calculated using a box model that is constrained by observed trace gas concentrations. Highest O{sub 3} concentrations were observed on July 31, which we present as a case study. On that day, O{sub 3} concentrations above the 1-hour 120 ppb standard were observed downwind of Philadelphia and also in the plume of a single industrial facility located on the Delaware River south of the city.

  19. Modeling analyses of the effects of changes in nitrogen oxides emissions from the electric power sector on ozone levels in the eastern United States

    SciTech Connect (OSTI)

    Edith Gego; Alice Gilliland; James Godowitch

    2008-04-15

    In this paper, we examine the changes in ambient ozone concentrations simulated by the Community Multiscale Air Quality (CMAQ) model for summer 2002 under three different nitrogen oxides (NOx) emission scenarios. Two emission scenarios represent best estimates of 2002 and 2004 emissions; they allow assessment of the impact of the NOx emissions reductions imposed on the utility sector by the NOx State Implementation Plan (SIP) Call. The third scenario represents a hypothetical rendering of what NOx emissions would have been in 2002 if no emission controls had been imposed on the utility sector. Examination of the modeled median and 95th percentile daily maximum 8-hr average ozone concentrations reveals that median ozone levels estimated for the 2004 emission scenario were less than those modeled for 2002 in the region most affected by the NOx SIP Call. Comparison of the 'no-control' with the '2002' scenario revealed that ozone concentrations would have been much higher in much of the eastern United States if the utility sector had not implemented NOx emission controls; exceptions occurred in the immediate vicinity of major point sources where increased NO titration tends to lower ozone levels. 13 refs., 8 figs., 2 tabs.

  20. Photographic Support Very Limited | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photographic Support Very Limited Photographic Support Very Limited at Lab at This Time Jefferson Lab Public Affairs has extremely limited time to provide photographic support. Two forms of photographic support are currently available: 1. Sign out a camera from Public Affairs (PA) so that you (or your designee) can take the photos you or your department/work center need. 2. If the job requires professional-grade photos, notify PA of the need/photo job - preferably two weeks in advance - so a

  1. Eclectic Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Energy Limited Place: Nottinghamshire, United Kingdom Zip: NG21 9PR Sector: Wind energy Product: Design, manufacture D400, StealthGen micro wind, DuoGen wind and water...

  2. Beam limiter for thermonuclear fusion devices

    DOE Patents [OSTI]

    Kaminsky, Manfred S.

    1976-01-01

    A beam limiter circumscribes the interior surface of a vacuum vessel to inhibit collisions of contained plasma and the vessel walls. The cross section of the material making up the limiter has a flatsided or slightly concave portion of increased width towards the plasma and portions of decreased width towards the interior surface of the vessel. This configuration is designed to prevent a major fraction of the material sputtered, vaporized and blistered from the limiter from reaching the plasma. It also allows adequate heat transfer from the wider to the narrower portions. The preferred materials for the beam limiter are solids of sintered, particulate materials of low atomic number with low vapor pressure and low sputtering and blistering yields.

  3. Principle Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Principle Energy Limited Place: Isle of Man, United Kingdom Zip: 1M1 1LB Sector: Renewable Energy Product: A UK-based renewable energy company focusing on bioethanol projects in...

  4. Adiabatic limits on Riemannian Heisenberg manifolds

    SciTech Connect (OSTI)

    Yakovlev, A A

    2008-02-28

    An asymptotic formula is obtained for the distribution function of the spectrum of the Laplace operator, in the adiabatic limit for the foliation defined by the orbits of an invariant flow on a compact Riemannian Heisenberg manifold. Bibliography: 21 titles.

  5. Greenrock Energy Services Limited | Open Energy Information

    Open Energy Info (EERE)

    Kingdom Zip: EH2 2JG Product: Scotland-based company installing ground source heat pump systems. References: Greenrock Energy Services Limited1 This article is a stub. You...

  6. EarthEnergy Limited | Open Energy Information

    Open Energy Info (EERE)

    Cornwall, United Kingdom Product: EarthEnergy Systems specialises in ground source heat pump systems. References: EarthEnergy Limited1 This article is a stub. You can help OpenEI...

  7. A2Wind Limited | Open Energy Information

    Open Energy Info (EERE)

    Startup with strong capability in carbon fibre design targeting the wind turbine blade space. References: A2Wind Limited1 This article is a stub. You can help OpenEI by...

  8. Crionaig Power Limited | Open Energy Information

    Open Energy Info (EERE)

    government approval for a 140MW, 39-turbine wind farm at Eisgein on the Isle of Lewis. References: Crionaig Power Limited1 This article is a stub. You can help OpenEI by...

  9. Predetermining acceptable noise limits in EXAFS spectra in the limit of

    Office of Scientific and Technical Information (OSTI)

    stochastic noise (Conference) | SciTech Connect Predetermining acceptable noise limits in EXAFS spectra in the limit of stochastic noise Citation Details In-Document Search Title: Predetermining acceptable noise limits in EXAFS spectra in the limit of stochastic noise EXAFS measurements are used to probe a variety of experimental systems, but excel at elucidating local structure in samples which have slight disorder or no long-range crystalline order. Of special interest to the authors is

  10. Modeling regional/urban ozone and particulate matter in Beijing, China.

    SciTech Connect (OSTI)

    Fu, J.S.; Streets, D.G.; Jang, C.J.; Hao, J.; He, K.; Wang, L.; Zhang, Q.

    2009-01-15

    This paper examines Beijing air quality in the winter and summer of 2001 using an integrated air quality modeling system (Fifth Generation Mesoscale Meteorological Model (MM5)/Community Multiscale Air Quality (CMAQ)) in nested mode. The National Aeronautics and Space Administration (NASA) Transport and Chemical Evolution over the Pacific (TRACE-P) emission inventory is used in the 36- (East Asia), 12- (East China), and 4-km (greater Beijing area) domains. Furthermore, we develop a local Beijing emission inventory that is used in the 4-km domain. We also construct a corroborated mapping of chemical species between the TRACE-P inventory and the Carbon Bond IV (CB-IV) chemical mechanism before the integrated modeling system is applied to study ozone (O{sub 3}) and particulate matter (PM) in Beijing. Meteorological data for the integrated modeling runs are extracted from MM5. Model results show O{sub 3} hourly concentrations in the range of 80-159 parts per billion (ppb) during summer in the urban areas and up to 189 ppb downwind of the city. High fine PM (PM2.5) concentrations (monthly average of 75 {mu}g.m{sup -3} in summer and 150 {mu}g.m{sup -3} in winter) are simulated over the metropolitan and down-wind areas with significant secondary constituents. Major sources of particulates were biomass burning, coal combustion and industry. A comparison against available O{sub 3} and PM measurement data in Beijing is described. We recommend refinements to the developed local Beijing emission inventory to improve the simulation of Beijing's air quality. The 4-km modeling configuration is also recommended for the development of air pollution control strategies. 31 refs., 5 figs., 3 tabs.

  11. The combined effects of elevated carbon dioxide and ozone on crop systems

    SciTech Connect (OSTI)

    Miller, J.E.; Heagle, A.S.; Shafer, S.R.; Heck, W.W.

    1994-12-31

    Concentrations of carbon dioxide (CO{sub 2}) and ozone (O{sub 3}) in the troposphere have risen in the last century due to industrialization. Current levels of tropospheric O{sub 3} suppress growth of crops and other plants, and O{sub 3} concentrations may continue to rise with changes in global climate. On the other hand, projected increases in atmospheric concentrations of CO{sub 2} in the next 50 to 100 years are expected to cause significant increases in growth of most species. Since elevated concentrations of these gases will co-occur, it is important to understand their joint action. Until recently, however, the combined effects of O{sub 3} and CO{sub 2} have received little attention. Most publications on combined CO{sub 2} and O{sub 3} effects have described experiments conducted in greenhouse or controlled-environment facilities. To date, data on responses of agricultural species to the combined gases have come from experiments with radish, tomato, white clover, tobacco, or wheat. In most cases, CO{sub 2} stimulated and O{sub 3} suppressed growth of the plant tissues studied, and CO{sub 2} usually attenuated development of O{sub 3}-induced visible injury. Some data have indicated a tendency for CO{sub 2}, in concentrations up to double the current ambient level, to attenuate effects of O{sub 3} on growth, but statistical analyses of such data often have not supported such a conclusion. In this paper, the results of a recent field experiment with soybean are reported, and the results are compared to other similar research with elevated atmospheric concentrations of both O{sub 3} and CO{sub 2}.

  12. The pulmonary response of white and black adults to six concentrations of ozone

    SciTech Connect (OSTI)

    Seal, E. Jr.; McDonnell, W.F.; House, D.E.; Salaam, S.A.; Dewitt, P.J.; Butler, S.O.; Green, J.; Raggio, L. )

    1993-04-01

    Many early studies of respiratory responsiveness to ozone (O3) were done on healthy, young, white males. The purpose of this study was to determine whether gender or race differences in O3 response exist among white and black, males and females, and to develop concentration-response curves for each of the gender-race groups. Three hundred seventy-two subjects (n > 90 in each gender-race group), ages 18 to 35 yr, were exposed once for 2.33 h to 0.0 (purified air), 0.12, 0.18, 0.24, 0.30, or 0.40 ppm O3. Each exposure was preceded by baseline pulmonary function tests and a symptom questionnaire. The first 2 h of exposure included alternating 15-min periods of rest and exercise on a motorized treadmill producing a minute ventilation (VE) of 25 L/min/m2 body surface area (BSA). After exposure, subjects completed a set of pulmonary function tests and a symptom questionnaire. Lung function and symptom responses were expressed as percent change from baseline and analyzed using a nonparametric two factor analysis of variance. Three primary variables were analyzed: FEV1, specific airway resistance (SRaw), and cough. Statistical analysis demonstrated no significant differences in response to O3 among the individual gender-race groups. For the group as a whole, changes in the variables FEV1, SRaw, and cough were first noted at 0.12, 0.18, and 0.18 ppm O3, respectively. Adjusted for exercise difference, concentration-response curves for FEV1 and cough among white males were consistent with previous reports (1).

  13. Air pollution and childhood respiratory health: Exposure to sulfate and ozone in 10 Canadian Rural Communities

    SciTech Connect (OSTI)

    Stern, B.R.; Raizenne, M.E.; Burnett, R.T.; Jones, L.; Kearney, J.; Franklin, C.A. )

    1994-08-01

    This study was designed to examine differences in the respiratory health status of preadolescent school children, aged 7-11 years, who resided in 10 rural Canadian communities in areas of moderate and low exposure to regional sulfate and ozone pollution. Five of the communities were located in central Saskatchewan, a low-exposure region, and five were located in southwestern Ontario, an area with moderately elevated exposures resulting from long-range atmospheric transport of polluted air masses. In this cross-sectional study, the child's respiratory symptoms and illness history were evaluated using a parent-completed questionnaire, administered in September 1985. Respiratory function was assessed once for each child in the schools between October 1985 and March 1986, by the measurement of pulmonary function for forced vital capacity (FVC), forced expiratory volume in 1 sec (FEV[sub 1.0]), peak expiratory flow rate (PEFR), mean forced expiratory flow rate during the middle half of the FVC curve (FEF[sub 25-75]), and maximal expiratory flow at 50% of the expired vital capacity (V[sub 50]max). After controlling for the effects of age, sex, parental smoking, parental education and gas cooking, no significant regional differences were observed in rates of chronic cough or phlegm, persistent wheeze, current asthma, bronchitis in the past year, or any chest illness that kept the child at home for 3 or more consecutive days during the previous year. Children living in southwestern Ontario had statistically significant (P < 0.01) mean decrements of 1.7% in FVC and 1.3% in FEV[sub 1.0] compared with Saskatchewan children, after adjusting for age, sex, weight, standing height, parental smoking, and gas cooking. There were no statistically significant regional differences in the pulmonary flow parameters (P > 0.05). 54 refs., 1 fig., 7 tabs.

  14. Air-Quality Data from NARSTO (North American Research Strategy for Tropospheric Ozone)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    NARSTO is a public/private partnership dedicated to improving management of air quality in North America. It was established on February 13, 1995 when representatives of Canada, the United States, and Mexico signed the NARSTO Charter in a ceremony at the White House. The Department of Energy is one of the charter members providing funding. The central programmatic goal of NARSTO is to provide data and information for use in the determination of workable, efficient, and effective strategies for local and regional ozone and fine particle management. Since its founding, NARSTO has completed three major scientific Assessments of critical air quality management issues. NARSTO maintains the Quality Systems Science Center and the NARSTO Data Archive for storing data from NARSTO Affiliated Research Activities and making these data available to the scientific community. NARSTO also facilitates activities, such as the Reactivity Research Working Group, which provide critical reviews of the state of the science in areas of interest to air quality policy makers. In January 1997, the U.S. Department of Energy's Environmental Sciences Division announced their sponsorship of the NARSTO Quality Systems Science Center (QSSC). The QSSC is located at the Oak Ridge National Laboratory within the Carbon Dioxide Information Analysis Center (CDIAC). Quality Assurance and Data Management assistance and guidelines are provided by the QSCC, along with access to data files. The permanent data archive is maintained by the NASA EOSDIS Distributed Active Archive Center at the Langley Research Center. The archived data can be reached by a link from the QSSC.(Specialized Interface) See also the NARSTO web site at http://www.narsto.org/

  15. Iron(II) catalysis in oxidation of hydrocarbons with ozone in acetonitrile

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bataineh, Hajem; Pestovsky, Oleg; Bakac, Andreja

    2015-02-11

    Oxidation of alcohols, ethers, and sulfoxides by ozone in acetonitrile is catalyzed by submillimolar concentrations of Fe(CH3CN)62+. The catalyst provides both rate acceleration and greater selectivity toward the less oxidized products. For example, Fe(CH3CN)62+-catalyzed oxidation of benzyl alcohol yields benzaldehyde almost exclusively (>95%), whereas the uncatalyzed reaction generates a 1:1 mixture of benzaldehyde and benzoic acid. Similarly, aliphatic alcohols are oxidized to aldehydes/ketones, cyclobutanol to cyclobutanone, and diethyl ether to a 1:1 mixture of ethanol and acetaldehyde. The kinetics of oxidation of alcohols and diethyl ether are first-order in [Fe(CH3CN)62+] and [O3] and independent of [substrate] at concentrations greater thanmore » ~5 mM. In this regime, the rate constant for all of the alcohols is approximately the same, kcat = (8 ± 1) × 104 M–1 s–1, and that for (C2H5)2O is (5 ± 0.5) × 104 M–1 s–1. In the absence of substrate, Fe(CH3CN)62+ reacts with O3 with kFe = (9.3 ± 0.3) × 104 M–1 s–1. The similarity between the rate constants kFe and kcat strongly argues for Fe(CH3CN)62+/O3 reaction as rate-determining in catalytic oxidation. The active oxidant produced in Fe(CH3CN)62+/O3 reaction is suggested to be an Fe(IV) species in analogy with a related intermediate in aqueous solutions. As a result, this assignment is supported by the similarity in kinetic isotope effects and relative reactivities of the two species toward substrates.« less

  16. A brightness exceeding simulated Langmuir limit

    SciTech Connect (OSTI)

    Nakasuji, Mamoru

    2013-08-15

    When an excitation of the first lens determines a beam is parallel beam, a brightness that is 100 times higher than Langmuir limit is measured experimentally, where Langmuir limits are estimated using a simulated axial cathode current density which is simulated based on a measured emission current. The measured brightness is comparable to Langmuir limit, when the lens excitation is such that an image position is slightly shorter than a lens position. Previously measured values of brightness for cathode apical radii of curvature 20, 60, 120, 240, and 480 ?m were 8.7, 5.3, 3.3, 2.4, and 3.9 times higher than their corresponding Langmuir limits, respectively, in this experiment, the lens excitation was such that the lens and the image positions were 180 mm and 400 mm, respectively. From these measured brightness for three different lens excitation conditions, it is concluded that the brightness depends on the first lens excitation. For the electron gun operated in a space charge limited condition, some of the electrons emitted from the cathode are returned to the cathode without having crossed a virtual cathode. Therefore, method that assumes a Langmuir limit defining method using a Maxwellian distribution of electron velocities may need to be revised. For the condition in which the values of the exceeding the Langmuir limit are measured, the simulated trajectories of electrons that are emitted from the cathode do not cross the optical axis at the crossover, thus the law of sines may not be valid for high brightness electron beam systems.

  17. Effect of canopy structure and open-top chamber techniques on micrometeorological parameters and the gradients and transport of water vapor, carbon dioxide and ozone in the canopies of plum trees (`prunus salicina`) in the San Joaquin valley. Final report

    SciTech Connect (OSTI)

    Grantz, D.A.; Vaughn, D.L.; Metheny, P.A.; Malkus, P.; Wosnik, K.

    1995-03-15

    Plum trees (Prunus salicina cv. Casselman) were exposed to ozone in open-top chambers (OTC) or chamberless plots, and trace gas concentrations and microenvironmental conditions were monitored within tree canopies inside the outside the OTC. Concentrations of ozone, carbon dioxide and water vapor, leaf and air temperature, light intensity, and wind speed were measured at nine positions in the tree canopies. The objectives were to: (1) map the distribution of microenvironmental parameters within the canopies inside and outside the OTC; (2) determine transport parameters for gas exchange, and (3) calculate ozone flux. Significant vertical and horizontal gradients were observed; gradients were diminished and often inverted inside relative to outside the OTC due to air distribution at the bottom of the OCT. Ozone flux was readily modeled from measures of stomatal conductance, nonstomatal conductance and ozone concentration at the leaf surface.

  18. Defining coiled tubing limits -- A new approach

    SciTech Connect (OSTI)

    Newman, K.R.; Sathuvalli, U.B.; Stone, L.R.; Wolhart, S.

    1996-12-31

    The burst, collapse and axial load operating limits for Coiled Tubing (CT) are currently established using the Von Mises incipient yield criterion. This criterion has historically been used to calculate the limits for oil country tubular goods (OCTG). The limits according to this criterion are based on the point at which the pipe material reaches a load state in which it begins to yield. Because of the bending that occurs when the CT is spooled on and off the reel, and when it is bent over the guide arch, the CT is already far beyond the yield point before it enters a well. Thus, this criterion does not really apply to CT. This paper describes a research project currently in progress. The purpose of this project is to define a new set of CT limits based on criteria other than incipient yield. This new approach to setting CT operating limits takes into account the internal residual stresses in the CT which are a consequence of repeated bending cycles and the accompanying change in material properties.

  19. Effect of the ozonization of brown coal from the Kansk-Achinsk Basin on its pyrolysis in a mixture with polyethylene

    SciTech Connect (OSTI)

    V.I. Sharypov; N.G. Beregovtsova; S.V. Baryshnikov; B.N. Kuznetsov

    2008-06-15

    It was found that the treatment of brown coal from the Kansk-Achinsk Basin with an ozone-oxygen mixture at 25-100{sup o}C for 1-8 h was accompanied by the formation of oxygen-containing structural groups in the organic matter of coal, the thermal stability of these groups was comparatively low. The preliminary ozonization of coal resulted in an increase in the degree of conversion and the yield of liquid distillation products in the course of coprocessing of coal with polyethylene.

  20. EA-365 Centre Land Trading Limited | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Centre Land Trading Limited EA-365 Centre Land Trading Limited Order Authorizing Centre Land Trading Limited to export electric energy to Canada PDF icon EA-365 Centre Land ...

  1. Representation of Limited Rights Data and Restricted Computer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data and Restricted Computer Software PDF icon Representation of Limited ...

  2. PP-206 Frontera Generation Limited Partnership | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PP-206 Frontera Generation Limited Partnership PP-206 Frontera Generation Limited Partnership Presidential permit authorizing Frontera Generation Limited Partnership to construct,...

  3. Multiple soft limits of cosmological correlation functions

    SciTech Connect (OSTI)

    Joyce, Austin; Khoury, Justin; Simonovi?, Marko E-mail: jkhoury@sas.upenn.edu

    2015-01-01

    We derive novel identities satisfied by inflationary correlation functions in the limit where two external momenta are taken to be small. We derive these statements in two ways: using background-wave arguments and as Ward identities following from the fixed-time path integral. Interestingly, these identities allow us to constrain some of the O(q{sup 2}) components of the soft limit, in contrast to their single-soft analogues. We provide several nontrivial checks of our identities both in the context of resonant non-Gaussianities and in small sound speed models. Additionally, we extend the relation at lowest order in external momenta to arbitrarily many soft legs, and comment on the many-soft extension at higher orders in the soft momentum. Finally, we consider how higher soft limits lead to identities satisfied by correlation functions in large-scale structure.

  4. Limited Conditions of Operations Tracking Program

    Energy Science and Technology Software Center (OSTI)

    1999-12-17

    The Lco tracking program is a computer based solution for tracking time limited action items for Limited Conditions of Operation (LCO) for nuclear and industrial processes. This use is not limited to any process except those not requiring specific action steps and times. The visual and audible assistance the LCO Tracking Program provides significantly reduces the chance of missing crucial actions required for safe operation of any facility in time of limited operations. The LCOmore » Tracking Program maintains all applicable action steps and times for each limited condition for the facility in its data base. The LCO Tracking Program is used to enter that condition by number, and the data base provides the applicble action steps and starts tracking their times based on the time the LCO was entered. The LCO display graphically displays, by colored bar charts, the time expired/time remaining of each specific action item. At 60% time expired, the bar chart turns yellow to caution personnel and then turns red at 90% time expired. Then an audible alarm is sounded at 95% as a warning, to finish or accomplish the required actions to satisfy the requirements. These warning and alarm limits are modifiable by the user and can be set at different values for each action. The display file is dynamic in function, checking every minute, and responds in real time to changes to the LCO Tracking Form file, providing the visual and audible warnings as to the status of the action steps chosen for display. The LCO Tracking Program efficiently tracks action times in minutes or days, up to 2 years. All current LCO''s are easily documentated using the LCO Tracking Form file with ease of printing and disposition. The Lco Tracking Program is designed as a user friendly program with navigational buttons to simplify use.« less

  5. ON COMPUTING UPPER LIMITS TO SOURCE INTENSITIES

    SciTech Connect (OSTI)

    Kashyap, Vinay L.; Siemiginowska, Aneta [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Van Dyk, David A.; Xu Jin [Department of Statistics, University of California, Irvine, CA 92697-1250 (United States); Connors, Alanna [Eureka Scientific, 2452 Delmer Street, Suite 100, Oakland, CA 94602-3017 (United States); Freeman, Peter E. [Department of Statistics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213 (United States); Zezas, Andreas, E-mail: vkashyap@cfa.harvard.ed, E-mail: asiemiginowska@cfa.harvard.ed, E-mail: dvd@ics.uci.ed, E-mail: jinx@ics.uci.ed, E-mail: aconnors@eurekabayes.co, E-mail: pfreeman@cmu.ed, E-mail: azezas@cfa.harvard.ed [Physics Department, University of Crete, P.O. Box 2208, GR-710 03, Heraklion, Crete (Greece)

    2010-08-10

    A common problem in astrophysics is determining how bright a source could be and still not be detected in an observation. Despite the simplicity with which the problem can be stated, the solution involves complicated statistical issues that require careful analysis. In contrast to the more familiar confidence bound, this concept has never been formally analyzed, leading to a great variety of often ad hoc solutions. Here we formulate and describe the problem in a self-consistent manner. Detection significance is usually defined by the acceptable proportion of false positives (background fluctuations that are claimed as detections, or Type I error), and we invoke the complementary concept of false negatives (real sources that go undetected, or Type II error), based on the statistical power of a test, to compute an upper limit to the detectable source intensity. To determine the minimum intensity that a source must have for it to be detected, we first define a detection threshold and then compute the probabilities of detecting sources of various intensities at the given threshold. The intensity that corresponds to the specified Type II error probability defines that minimum intensity and is identified as the upper limit. Thus, an upper limit is a characteristic of the detection procedure rather than the strength of any particular source. It should not be confused with confidence intervals or other estimates of source intensity. This is particularly important given the large number of catalogs that are being generated from increasingly sensitive surveys. We discuss, with examples, the differences between these upper limits and confidence bounds. Both measures are useful quantities that should be reported in order to extract the most science from catalogs, though they answer different statistical questions: an upper bound describes an inference range on the source intensity, while an upper limit calibrates the detection process. We provide a recipe for computing upper limits that applies to all detection algorithms.

  6. Estimation of Flammability Limits of Selected Fluorocarbons with F(sub 2) and CIF(sub3)

    SciTech Connect (OSTI)

    Trowbridge, L.D.

    1999-09-01

    During gaseous diffusion plant operations, conditions leading to the formation of flammable gas mixtures may occasionally arise. Currently, these could consist of the evaporative coolant CFC-114 and fluorinating agents such as F(sub 2) and CIF(sub 3). Replacement of CFC-114 with non-ozone-depleting substitutes such as c-C(sub 4)F(sub 8) and C(sub 4)F(sub 10) is planned. Consequently, in the future, these too must be considered potential ''fuels'' in flammable gas mixtures. Two questions of practical interest arise: (1) can a particular mixture sustain and propagate a flame if ignited, and (2) what is the maximum pressure that can be generated by the burning (and possibly exploding) gas mixture, should ignite? Experimental data on these systems are limited. To assist in answering these questions, a literature search for relevant data was conducted, and mathematical models were developed to serve as tools for predicting potential detonation pressures and estimating (based on empirical correlations between gas mixture thermodynamics and flammability for known systems) the composition limits of flammability for these systems. The models described and documented in this report are enhanced versions of similar models developed in 1992.

  7. Flexible moldable conductive current-limiting materials

    DOE Patents [OSTI]

    Shea, John Joseph; Djordjevic, Miomir B.; Hanna, William Kingston

    2002-01-01

    A current limiting PTC device (10) has two electrodes (14) with a thin film of electric conducting polymer material (20) disposed between the electrodes, the polymer material (20) having superior flexibility and short circuit performance, where the polymer material contains short chain aliphatic diepoxide, conductive filler particles, curing agent, and, preferably, a minor amount of bisphenol A epoxy resin.

  8. Antenna factorization in strongly ordered limits

    SciTech Connect (OSTI)

    Kosower, David A.

    2005-02-15

    When energies or angles of gluons emitted in a gauge-theory process are small and strongly ordered, the emission factorizes in a simple way to all orders in perturbation theory. I show how to unify the various strongly ordered soft, mixed soft-collinear, and collinear limits using antenna factorization amplitudes, which are generalizations of the Catani-Seymour dipole factorization function.

  9. Signatures of a conical intersection in photofragment distributions and absorption spectra: Photodissociation in the Hartley band of ozone

    SciTech Connect (OSTI)

    Picconi, David; Grebenshchikov, Sergy Yu.

    2014-08-21

    Photodissociation of ozone in the near UV is studied quantum mechanically in two excited electronic states coupled at a conical intersection located outside the Franck-Condon zone. The calculations, performed using recent ab initio PESs, provide an accurate description of the photodissociation dynamics across the Hartley/Huggins absorption bands. The observed photofragment distributions are reproduced in the two electronic dissociation channels. The room temperature absorption spectrum, constructed as a Boltzmann average of many absorption spectra of rotationally excited parent ozone, agrees with experiment in terms of widths and intensities of diffuse structures. The exit channel conical intersection contributes to the coherent broadening of the absorption spectrum and directly affects the product vibrational and translational distributions. The photon energy dependences of these distributions are strikingly different for fragments created along the adiabatic and the diabatic paths through the intersection. They can be used to reverse engineer the most probable geometry of the non-adiabatic transition. The angular distributions, quantified in terms of the anisotropy parameter β, are substantially different in the two channels due to a strong anticorrelation between β and the rotational angular momentum of the fragment O{sub 2}.

  10. Iron(II) catalysis in oxidation of hydrocarbons with ozone in acetonitrile

    SciTech Connect (OSTI)

    Bataineh, Hajem; Pestovsky, Oleg; Bakac, Andreja

    2015-02-11

    Oxidation of alcohols, ethers, and sulfoxides by ozone in acetonitrile is catalyzed by submillimolar concentrations of Fe(CH3CN)62+. The catalyst provides both rate acceleration and greater selectivity toward the less oxidized products. For example, Fe(CH3CN)62+-catalyzed oxidation of benzyl alcohol yields benzaldehyde almost exclusively (>95%), whereas the uncatalyzed reaction generates a 1:1 mixture of benzaldehyde and benzoic acid. Similarly, aliphatic alcohols are oxidized to aldehydes/ketones, cyclobutanol to cyclobutanone, and diethyl ether to a 1:1 mixture of ethanol and acetaldehyde. The kinetics of oxidation of alcohols and diethyl ether are first-order in [Fe(CH3CN)62+] and [O3] and independent of [substrate] at concentrations greater than ~5 mM. In this regime, the rate constant for all of the alcohols is approximately the same, kcat = (8 ± 1) × 104 M–1 s–1, and that for (C2H5)2O is (5 ± 0.5) × 104 M–1 s–1. In the absence of substrate, Fe(CH3CN)62+ reacts with O3 with kFe = (9.3 ± 0.3) × 104 M–1 s–1. The similarity between the rate constants kFe and kcat strongly argues for Fe(CH3CN)62+/O3 reaction as rate-determining in catalytic oxidation. The active oxidant produced in Fe(CH3CN)62+/O3 reaction is suggested to be an Fe(IV) species in analogy with a related intermediate in aqueous solutions. As a result, this assignment is supported by the similarity in kinetic isotope effects and relative reactivities of the two species toward substrates.

  11. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    SciTech Connect (OSTI)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 C to 380 C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on the same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.

  12. Approaching the Shockley-Queisser limit: General assessment of the main limiting mechanisms in photovoltaic cells

    SciTech Connect (OSTI)

    Vossier, Alexis Gualdi, Federico; Dollet, Alain; Ares, Richard; Aimez, Vincent

    2015-01-07

    In principle, the upper efficiency limit of any solar cell technology can be determined using the detailed-balance limit formalism. However, “real” solar cells show efficiencies which are always below this theoretical value due to several limiting mechanisms. We study the ability of a solar cell architecture to approach its own theoretical limit, using a novel index introduced in this work, and the amplitude with which the different limiting mechanisms affect the cell efficiency is scrutinized as a function of the electronic gap and the illumination level to which the cell is submitted. The implications for future generations of solar cells aiming at an improved conversion of the solar spectrum are also addressed.

  13. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    P. Bernot

    2005-07-13

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this activity is to predict dissolved concentrations or solubility limits for elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) relevant to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are provided in the form of tabulated functions with pH and log fCO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. Even though selection of an appropriate set of radionuclides documented in Radionuclide Screening (BSC 2002 [DIRS 160059]) includes actinium, transport of Ac is not modeled in the total system performance assessment for the license application (TSPA-LA) model because of its extremely short half-life. Actinium dose is calculated in the TSPA-LA by assuming secular equilibrium with {sup 231}Pa (Section 6.10); therefore, Ac is not analyzed in this report. The output data from this report are fundamental inputs for TSPA-LA used to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for the actinides discussed in this report. These models cover broad ranges of environmental conditions so they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  14. Toxicity Data to Determine Refrigerant Concentration Limits

    SciTech Connect (OSTI)

    Calm, James M.

    2000-09-30

    This report reviews toxicity data, identifies sources for them, and presents resulting exposure limits for refrigerants for consideration by qualified parties in developing safety guides, standards, codes, and regulations. It outlines a method to calculate an acute toxicity exposure limit (ATEL) and from it a recommended refrigerant concentration limit (RCL) for emergency exposures. The report focuses on acute toxicity with particular attention to lethality, cardiac sensitization, anesthetic and central nervous system effects, and other escape-impairing effects. It addresses R-11, R-12, R-22, R-23, R-113, R-114, R-116, R-123, R-124, R-125, R-134, R-134a, R-E134, R-141b, R-142b, R-143a, R-152a, R-218, R-227ea, R-236fa, R-245ca, R-245fa, R-290, R-500, R-502, R-600a, R-717, and R-744. It summarizes additional data for R-14, R-115, R-170 (ethane), R-C318, R-600 (n-butane), and R-1270 (propylene) to enable calculation of limits for blends incorporating them. The report summarizes the data a nd related safety information, including classifications and flammability data. It also presents a series of tables with proposed ATEL and RCL concentrations-in dimensionless form and the latter also in both metric (SI) and inch-pound (IP) units of measure-for both the cited refrigerants and 66 zerotropic and azeotropic blends. They include common refrigerants, such as R-404A, R-407C, R-410A, and R-507A, as well as others in commercial or developmental status. Appendices provide profiles for the cited single-compound refrigerants and for R-500 and R-502 as well as narrative toxicity summaries for common refrigerants. The report includes an extensive set of references.

  15. Means for limiting and ameliorating electrode shorting

    SciTech Connect (OSTI)

    Konynenburg, R.A. van; Farmer, J.C.

    1999-11-09

    A fuse and filter arrangement is described for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  16. Combined SM Higgs Limits at the Tevatron

    SciTech Connect (OSTI)

    Krumnack, N.

    2009-10-01

    We combine results from CDF and D{sup 0} on direct searches for a standard model (SM) Higgs boson (H) in p{bar p} collisions at the Fermilab Tevatron at {radical}s = 1.96 TeV. Compared to the previous Higgs Tevatron combination, more data and new channels WH {yields} {tau}{nu}b{bar b}, VH {yields} {tau}{tau}b{bar b}/jj{tau}{tau}, VH {yields} jjb{bar b}, t{bar t}H {yields} t{bar t}b{bar b} have been added. Most previously used channels have been reanalyzed to gain sensitivity. We use the latest parton distribution functions and gg {yields} H theoretical cross sections when comparing our limits to the SM predictions. With 2.0-3.6 fb{sup -1} of data analyzed at CDF, and 0.9-4.2 fb{sup -1} at D{sup 0}, the 95% C.L. upper limits on Higgs boson production are a factor of 2.5 (0.86) times the SM cross section for a Higgs boson mass of m{sub H} = 115 (165) GeV/c{sup 2}. Based on simulation, the corresponding median expected upper limits are 2.4 (1.1). The mass range excluded at 95% C.L. for a SM Higgs has been extended to 160 < m{sub H} < 170 GeV/c{sup 2}.

  17. Means for limiting and ameliorating electrode shorting

    DOE Patents [OSTI]

    Van Konynenburg, Richard A.; Farmer, Joseph C.

    1999-01-01

    A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.

  18. Limitations and improvements for harmonic generation measurements

    SciTech Connect (OSTI)

    Best, Steven; Croxford, Anthony; Neild, Simon

    2014-02-18

    A typical acoustic harmonic generation measurement comes with certain limitations. Firstly, the use of the plane wave-based analysis used to extract the nonlinear parameter, β, ignores the effects of diffraction, attenuation and receiver averaging which are common to most experiments, and may therefore limit the accuracy of a measurement. Secondly, the method usually requires data obtained from a through-transmission type setup, which may not be practical in a field measurement scenario where access to the component is limited. Thirdly, the technique lacks a means of pinpointing areas of damage in a component, as the measured nonlinearity represents an average over the length of signal propagation. Here we describe a three-dimensional model of harmonic generation in a sound beam, which is intended to provide a more realistic representation of a typical experiment. The presence of a reflecting boundary is then incorporated into the model to assess the feasibility of performing single-sided measurements. Experimental validation is provided where possible. Finally, a focusing acoustic source is modelled to provide a theoretical indication of the afforded advantages when the nonlinearity is localized.

  19. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    SciTech Connect (OSTI)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometer (UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.

  20. Compliance with the Clean Air Act Title VI Stratospheric Ozone Protection Program requirements at U.S. DOE Oak Ridge Reservation Facilities

    SciTech Connect (OSTI)

    Humphreys, M.P.; Atkins, E.M.

    1999-07-01

    The Title VI Stratospheric Ozone Protection Program of the Clean Air Act (CAA) requires promulgation of regulations to reduce and prevent damage to the earth's protective ozone layer. Regulations pursuant to Title VI of the CAA are promulgated in the Code of Federal Regulations (CFR) at Title 40 CFR, Part 822. The regulations include ambitious production phaseout schedules for ozone depleting substances (ODS) including chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), halons, carbon tetrachloride, and methyl chloroform under 40 CFR 82, Subpart A. The regulations also include requirements for recycling and emissions reduction during the servicing of refrigeration equipment and technician certification requirements under Subpart F; provisions for servicing of motor vehicle air conditioners under Subpart B; a ban on nonessential products containing Class 1 ODS under Subpart C; restrictions on Federal procurement of ODS under Subpart D; labeling of products using ODS under Subpart E; and the Significant New Alternatives Policy Program under Subpart G. This paper will provide details of initiatives undertaken at US Department of Energy (DOE) Oak Ridge Reservation (ORR) Facilities for implementation of requirements under the Title VI Stratospheric Ozone Protection Program. The Stratospheric Ozone Protection Plans include internal DOE requirements for: (1) maintenance of ODS inventories; (2) ODS procurement practices; (3) servicing of refrigeration and air conditioning equipment; (4) required equipment modifications or replacement; (5) technician certification training; (6) labeling of products containing ODS; (7) substitution of chlorinated solvents; and (8) replacement of halon fire protection systems. The plans also require establishment of administrative control systems which assure that compliance is achieved and maintained as the regulations continue to develop and become effective.

  1. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometermore » (UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.« less

  2. Torque limited drive for manual valves

    DOE Patents [OSTI]

    Elliott, Philip G.; Underwood, Daniel E.

    1989-01-01

    The present invention is directed to a torque-limiting handwheel device for preventing manual valves from being damaged due to the application of excessive torque during the opening or closing operation of the valves. Torque can only be applied when ridges in the handwheel assembly engage in channels machined in the face of the baseplate. The amount of torque required for disengagement of the ridges from the channels is determined by the force exerted by various Bellville springs and the inclination of the side faces of the channels.

  3. Multi-model Estimates of Intercontinental Source-Receptor Relationships for Ozone Pollution

    SciTech Connect (OSTI)

    Fiore, A M; Dentener, F J; Wild, O; Cuvelier, C; Schultz, M G; Hess, P; Textor, C; Schulz, M; Doherty, R; Horowitz, L W; MacKenzie, I A; Sanderson, M G; Shindell, D T; Stevenson, D S; Szopa, S; Van Dingenen, R; Zeng, G; Atherton, C; Bergmann, D; Bey, I; Carmichael, G; Collins, W J; Duncan, B N; Faluvegi, G; Folberth, G; Gauss, M; Gong, S; Hauglustaine, D; Holloway, T; Isaksen, I A; Jacob, D J; Jonson, J E; Kaminski, J W; Keating, T J; Lupu, A; Marmer, E; Montanaro, V; Park, R; Pitari, G; Pringle, K J; Pyle, J A; Schroeder, S; Vivanco, M G; Wind, P; Wojcik, G; Wu, S; Zuber, A

    2008-10-16

    Understanding the surface O{sub 3} response over a 'receptor' region to emission changes over a foreign 'source' region is key to evaluating the potential gains from an international approach to abate ozone (O{sub 3}) pollution. We apply an ensemble of 21 global and hemispheric chemical transport models to estimate the spatial average surface O{sub 3} response over East Asia (EA), Europe (EU), North America (NA) and South Asia (SA) to 20% decreases in anthropogenic emissions of the O{sub 3} precursors, NO{sub x}, NMVOC, and CO (individually and combined), from each of these regions. We find that the ensemble mean surface O{sub 3} concentrations in the base case (year 2001) simulation matches available observations throughout the year over EU but overestimates them by >10 ppb during summer and early fall over the eastern U.S. and Japan. The sum of the O{sub 3} responses to NO{sub x}, CO, and NMVOC decreases separately is approximately equal to that from a simultaneous reduction of all precursors. We define a continental-scale 'import sensitivity' as the ratio of the O{sub 3} response to the 20% reductions in foreign versus 'domestic' (i.e., over the source region itself) emissions. For example, the combined reduction of emissions from the 3 foreign regions produces an ensemble spatial mean decrease of 0.6 ppb over EU (0.4 ppb from NA), less than the 0.8 ppb from the reduction of EU emissions, leading to an import sensitivity ratio of 0.7. The ensemble mean surface O{sub 3} response to foreign emissions is largest in spring and late fall (0.7-0.9 ppb decrease in all regions from the combined precursor reductions in the 3 foreign regions), with import sensitivities ranging from 0.5 to 1.1 (responses to domestic emission reductions are 0.8-1.6 ppb). High O{sub 3} values are much more sensitive to domestic emissions than to foreign emissions, as indicated by lower import sensitivities of 0.2 to 0.3 during July in EA, EU, and NA when O{sub 3} levels are typically highest, and by the weaker relative response of annual incidences of daily maximum 8-hour average O{sub 3} above 60 ppb to emission reductions in a foreign region (<10-20% of that to domestic) as compared to the annual mean response (up to 50% of that to domestic). Applying the ensemble annual mean results to changes in anthropogenic emissions from 1996 to 2002, we estimate a Northern Hemispheric increase in background surface O{sub 3} of about 0.1 ppb yr{sup -1}, at the low end of the 0.1-0.5 ppb yr{sup -1} derived from observations. From an additional simulation in which global atmospheric methane was reduced, we infer that 20% reductions in anthropogenic methane emissions from a foreign source region would yield an O{sub 3} response in a receptor region that roughly equals that produced by combined 20% reductions of anthropogenic NO{sub x}, NMVOC and CO emissions from the foreign source region.

  4. PP-22 British Columbia Electric Company, Limited | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Limited PP-22 British Columbia Electric Company, Limited Presidential permit authorizing British Columbia Electric Company, Limited to construct, operate, and maintain electric transmission facilities at the U.S-Canadian border. PDF icon PP-22 British Columbia Electric Company, Limited More Documents & Publications PP-22 British Columbia Electric Company, Limited, Amendment 1957

  5. PP-22 British Columbia Electric Company, Limited, Amendment 1957 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Limited, Amendment 1957 PP-22 British Columbia Electric Company, Limited, Amendment 1957 Presidential permit authorizing British Columbia Electric Company, Limited to construct, operate, and maintain electric transmission facilities at the U.S-Canadian border. PDF icon PP-22 British Columbia Electric Company, Limited More Documents & Publications PP-22 British Columbia Electric Company, Limited

  6. Impact Limiter Tests of Four Commonly Used Materials And Limiter Data Base*

    Office of Scientific and Technical Information (OSTI)

    Limiter Tests of Four Commonly Used Materials And Limiter Data Base* W.M. McMurtry and G.F. Hohnstreiter Sandia National Laboratories, Albuquerque, New Mexico, United States of America DISCLAIMER I This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor my agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsi- bility for the accuracy,

  7. Chapter_2_Limited_Areas_Vault-Type_Rooms_and_Temporary_Limited_Areas

    Energy Savers [EERE]

    Limited Areas, VTRs, and Temporary Limited Areas Chapter 2 describes the security procedures adopted by DOE HQ to implement the requirements of the following DOE directives: * DOE Order 473.3, Protection Program Operations * DOE Order 471.6, Change 1, Information Security * DOE Order 475.2A, Identifying Classified Information * Classification Bulletin TNP-32, Classification Guidance for Classified Meeting Locations at DOE/NNSA or DOE/NNSA Contractor Sites or Facilities, dated May 27, 2010 DOE

  8. Chapter_2_Limited_Areas_Vault-Type_Rooms_and_Temporary_Limited_Areas

    Office of Environmental Management (EM)

    Limited Areas, VTRs, and Temporary Limited Areas Chapter 2 describes the security procedures adopted by DOE HQ to implement the requirements of the following DOE directives: * DOE Order 473.3, Protection Program Operations * DOE Order 471.6, Change 1, Information Security * DOE Order 475.2A, Identifying Classified Information * Classification Bulletin TNP-32, Classification Guidance for Classified Meeting Locations at DOE/NNSA or DOE/NNSA Contractor Sites or Facilities, dated May 27, 2010 DOE

  9. SunDwel Solar Limited | Open Energy Information

    Open Energy Info (EERE)

    SunDwel Solar Limited Jump to: navigation, search Logo: SunDwel Solar Limited Name: SunDwel Solar Limited Address: 1 Tower Road Place: Washington, United Kingdom Sector: Solar...

  10. Limited Test Ban Treaty Signed | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Limited Test Ban Treaty Signed Limited Test Ban Treaty Signed Washington, DC The United States, Great Britain, and the Soviet Union sign the Limited Test Ban Treaty prohibiting underwater, atmospheric, and outer space nuclear tests. Nuclear testing continues underground

  11. Self field triggered superconducting fault current limiter

    DOE Patents [OSTI]

    Tekletsadik, Kasegn D.

    2008-02-19

    A superconducting fault current limiter array with a plurality of superconductor elements arranged in a meanding array having an even number of supconductors parallel to each other and arranged in a plane that is parallel to an odd number of the plurality of superconductors, where the odd number of supconductors are parallel to each other and arranged in a plane that is parallel to the even number of the plurality of superconductors, when viewed from a top view. The even number of superconductors are coupled at the upper end to the upper end of the odd number of superconductors. A plurality of lower shunt coils each coupled to the lower end of each of the even number of superconductors and a plurality of upper shunt coils each coupled to the upper end of each of the odd number of superconductors so as to generate a generally orthoganal uniform magnetic field during quenching using only the magenetic field generated by the superconductors.

  12. Instability limits for spontaneous double layer formation

    SciTech Connect (OSTI)

    Carr, J. Jr.; Department of Physics, Texas Lutheran University, Seguin, Texas 78155 ; Galante, M. E.; McCarren, D.; Scime, E. E.; Sears, S.; VanDervort, R. W.; Magee, R. M.; TriAlpha Energy, Inc., Foothill Ranch, California 92610 ; Reynolds, E.

    2013-11-15

    We present time-resolved measurements that demonstrate that large amplitude electrostatic instabilities appear in pulsed, expanding helicon plasmas at the same time as particularly strong double layers appear in the expansion region. A significant cross-correlation between the electrostatic fluctuations and fluctuations in the number of ions accelerated by the double layer electric field is observed. No correlation is observed between the electrostatic fluctuations and ions that have not passed through the double layer. These measurements confirm that the simultaneous appearance of the electrostatic fluctuations and the double layer is not simple coincidence. In fact, the accelerated ion population is responsible for the growth of the instability. The double layer strength, and therefore, the velocity of the accelerated ions, is limited by the appearance of the electrostatic instability.

  13. Authorized limits for Fernald copper ingots

    SciTech Connect (OSTI)

    Frink, N.; Kamboj, S.; Hensley, J.; Chen, S. Y.

    1997-09-01

    This development document contains data and analysis to support the approval of authorized limits for the unrestricted release of 59 t of copper ingots containing residual radioactive material from the U.S. Department of Energy (DOE) Fernald Environmental Management Project (FEMP). The analysis presented in this document comply with the requirements of DOE Order 5400.5, {open_quotes}Radiation Protection of the Public and the Environment,{close_quotes} as well as the requirements of the proposed promulgation of this order as 10 CFR Part 834. The document was developed following the step-by-step process described in the Draft Handbook for Controlling Release for Reuse or Recycle Property Containing Residual Radioactive Material.

  14. Remotely replaceable tokamak plasma limiter tiles

    DOE Patents [OSTI]

    Tsuo, Simon , Langford, Alison A.

    1989-01-01

    U-shaped limiter tiles placed end-to-end over a pair of parallel runners secured to a wall have two rods which engage L-shaped slots in the runners. The short receiving legs of the L-shaped slots are perpendicular to the wall and open away from the wall, while long retaining legs are parallel to and adjacent the wall. A sliding bar between the runners has grooves with clips to retain the rods pressed into receiving legs of the L-shaped slots in the runners. Sliding the bar in the direction of retaining legs of the L-shaped slots latches the tiles in place over the runners. Resilient contact strips between the parallel arms of the U-shaped tiles and the wall assure thermal and electrical contact with the wall.

  15. Neutral depletion and the helicon density limit

    SciTech Connect (OSTI)

    Magee, R. M.; Galante, M. E.; Carr, J. Jr.; Lusk, G.; McCarren, D. W.; Scime, E. E.

    2013-12-15

    It is straightforward to create fully ionized plasmas with modest rf power in a helicon. It is difficult, however, to create plasmas with density >10{sup 20} m{sup ?3}, because neutral depletion leads to a lack of fuel. In order to address this density limit, we present fast (1 MHz), time-resolved measurements of the neutral density at and downstream from the rf antenna in krypton helicon plasmas. At the start of the discharge, the neutral density underneath the antenna is reduced to 1% of its initial value in 15 ?s. The ionization rate inferred from these data implies that the electron temperature near the antenna is much higher than the electron temperature measured downstream. Neutral density measurements made downstream from the antenna show much slower depletion, requiring 14 ms to decrease by a factor of 1/e. Furthermore, the downstream depletion appears to be due to neutral pumping rather than ionization.

  16. Various factors affect coiled tubing limits

    SciTech Connect (OSTI)

    Yang, Y.S.

    1996-01-15

    Safety and reliability remain the primary concerns in coiled tubing operations. Factors affecting safety and reliability include corrosion, flexural bending, internal (or external) pressure and tension (or compression), and mechanical damage due to improper use. Such limits as coiled tubing fatigue, collapse, and buckling need to be understood to avoid disaster. With increased use of coiled tubing, operators will gain more experience. But at the same time, with further research and development of coiled tubing, the manufacturing quality will be improved and fatigue, collapse, and buckling models will become more mature, and eventually standard specifications will be available. This paper reviews the uses of coiled tubing and current research on mechanical behavior of said tubing. It also discusses several models used to help predict fatigue and failure levels.

  17. Dynamically limiting energy consumed by cooling apparatus

    DOE Patents [OSTI]

    Chainer, Timothy J.; David, Milnes P.; Iyengar, Madhusudan K.; Parida, Pritish R.; Schmidt, Roger R.; Schultz, Mark D.

    2015-05-26

    Cooling apparatuses and methods are provided which include one or more coolant-cooled structures associated with an electronics rack, a coolant loop coupled in fluid communication with one or more passages of the coolant-cooled structure(s), one or more heat exchange units coupled to facilitate heat transfer from coolant within the coolant loop, and N controllable components associated with the coolant loop or the heat exchange unit(s), wherein N.gtoreq.1. The N controllable components facilitate circulation of coolant through the coolant loop or transfer of heat from the coolant via the heat exchange unit(s). A controller is coupled to the N controllable components, and dynamically adjusts operation of the N controllable components, based on Z input parameters and one or more specified constraints, to provide a specified cooling to the coolant-cooled structure(s), while limiting energy consumed by the N controllable components, wherein Z.gtoreq.1.

  18. Dynamically limiting energy consumed by cooling apparatus

    DOE Patents [OSTI]

    Chainer, Timothy J.; David, Milnes P.; Iyengar, Madhusudan K.; Parida, Pritish R.; Schmidt, Roger R.; Schultz, Mark D.

    2015-06-09

    Cooling methods are provided which include providing: one or more coolant-cooled structures associated with an electronics rack, a coolant loop coupled in fluid communication with one or more passages of the coolant-cooled structure(s), one or more heat exchange units coupled to facilitate heat transfer from coolant within the coolant loop, and N controllable components associated with the coolant loop or the heat exchange unit(s), wherein N.gtoreq.1. The N controllable components facilitate circulation of coolant through the coolant loop or transfer of heat from the coolant via the heat exchange unit(s). A controller is also provided to dynamically adjust operation of the N controllable components, based on Z input parameters and one or more specified constraints, and provide a specified cooling to the coolant-cooled structure(s), while limiting energy consumed by the N controllable components, wherein Z.gtoreq.1.

  19. (Expired) Nationwide Limited Public Interest Waiver for LED Lighting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Expired) Nationwide Limited Public Interest Waiver for LED Lighting and HVAC Units: February 11, 2010 (Expired) Nationwide Limited Public Interest Waiver for LED Lighting and HVAC ...

  20. Fault Current Limiters (FCL) Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fault Current Limiters (FCL) Fact Sheet Fault Current Limiters (FCL) Fact Sheet Plugging America Into the Future of Power: Superconducting & Solid-state Power Equipment What are ...

  1. Jilin Taihe Wind Power Limited | Open Energy Information

    Open Energy Info (EERE)

    Taihe Wind Power Limited Jump to: navigation, search Name: Jilin Taihe Wind Power Limited Place: Zhenlai, Jilin Province, China Sector: Wind energy Product: Top Well and Tianjin DH...

  2. Tongliao Taihe Wind Power Limited | Open Energy Information

    Open Energy Info (EERE)

    Taihe Wind Power Limited Jump to: navigation, search Name: Tongliao Taihe Wind Power Limited Place: Tongliao City, Inner Mongolia Autonomous Region, China Sector: Wind energy...

  3. Huaneng Shouguang Wind Power Company Limited | Open Energy Information

    Open Energy Info (EERE)

    Huaneng Shouguang Wind Power Company Limited Jump to: navigation, search Name: Huaneng Shouguang Wind Power Company Limited Place: Shouguang, Shandong Province, China Sector: Wind...

  4. BP Energy India Private Limited BPEIPL | Open Energy Information

    Open Energy Info (EERE)

    India Private Limited BPEIPL Jump to: navigation, search Name: BP Energy India Private Limited (BPEIPL) Place: India Sector: Wind energy Product: India-based, subsidiary of Green...

  5. Predetermining acceptable noise limits in EXAFS spectra in the...

    Office of Scientific and Technical Information (OSTI)

    Title: Predetermining acceptable noise limits in EXAFS spectra in the limit of stochastic noise EXAFS measurements are used to probe a variety of experimental systems, but excel at ...

  6. Tianjin DH Power Investment Limited | Open Energy Information

    Open Energy Info (EERE)

    Tianjin DH Power Investment Limited Jump to: navigation, search Name: Tianjin DH Power Investment Limited Place: Tianjin, Tianjin Municipality, China Sector: Wind energy Product:...

  7. Genesis Energy Investment Public Limited Company Genesis Solar...

    Open Energy Info (EERE)

    Investment Public Limited Company Genesis Solar Jump to: navigation, search Name: Genesis Energy Investment Public Limited Company (Genesis Solar) Place: Budapest, Hungary Zip:...

  8. Liaoning Shenhua Xiehe Wind Power Investment Limited | Open Energy...

    Open Energy Info (EERE)

    Shenhua Xiehe Wind Power Investment Limited Jump to: navigation, search Name: Liaoning Shenhua Xiehe Wind Power Investment Limited Place: Liaoning Province, China Sector: Wind...

  9. Jilin CWP Milestone Wind Power Investment Limited | Open Energy...

    Open Energy Info (EERE)

    Jilin CWP Milestone Wind Power Investment Limited Jump to: navigation, search Name: Jilin CWP-Milestone Wind Power Investment Limited Place: Baicheng, Jilin Province, China Sector:...

  10. Birmingham Research and Development Limited BRDL | Open Energy...

    Open Energy Info (EERE)

    Birmingham Research and Development Limited BRDL Jump to: navigation, search Name: Birmingham Research and Development Limited (BRDL) Place: United Kingdom Sector: Services...

  11. Free Stream Capital Partners Limited | Open Energy Information

    Open Energy Info (EERE)

    Capital Partners Limited Jump to: navigation, search Name: Free Stream Capital Partners Limited Place: London, Greater London, United Kingdom Zip: SW1Y 4AA Sector: Wind energy...

  12. Carbon Compliance Acquisition 5 Limited | Open Energy Information

    Open Energy Info (EERE)

    Compliance Acquisition 5 Limited Jump to: navigation, search Name: Carbon Compliance Acquisition 5 Limited Place: Greater London, United Kingdom Zip: EC2M 2TD Sector: Carbon...

  13. Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolyte Fuel Cell Lifetime Limitations: The Role of Electrocatalyst Degradation Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role of Electrocatalyst Degradation ...

  14. Sanraa Media Limited India formerly Sanra Software | Open Energy...

    Open Energy Info (EERE)

    Sanraa Media Limited India formerly Sanra Software Jump to: navigation, search Name: Sanraa Media Limited India (formerly Sanra Software) Place: Chennai, Tamil Nadu, India Zip:...

  15. China Longyuan Power Group Corporation Limited | Open Energy...

    Open Energy Info (EERE)

    Power Group Corporation Limited Jump to: navigation, search Name: China Longyuan Power Group Corporation Limited Place: Beijing, Beijing Municipality, China Zip: 100034 Sector:...

  16. The Department of Energy's Limited English Proficiency Plan ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Department of Energy's Limited English Proficiency Plan The Department of Energy's Limited English Proficiency Plan The identification of reasonable steps to provide oral and ...

  17. Mangalam Bio Energen Private Limited | Open Energy Information

    Open Energy Info (EERE)

    Bio Energen Private Limited Jump to: navigation, search Name: Mangalam Bio-Energen Private Limited Place: Maharashtra, India Sector: Biomass Product: A project developer thats...

  18. TurboTech Precision Engineering Private Limited | Open Energy...

    Open Energy Info (EERE)

    TurboTech Precision Engineering Private Limited Jump to: navigation, search Name: TurboTech Precision Engineering Private Limited Place: Bangalore, India Zip: 560 044 Sector:...

  19. Cleantech Professional Resource Global Limited CPR Global | Open...

    Open Energy Info (EERE)

    Professional Resource Global Limited CPR Global Jump to: navigation, search Name: Cleantech Professional Resource Global Limited (CPR Global) Place: London, United Kingdom Zip:...

  20. Fujian Jinzaoqiao Hydro Power Limited Corporation | Open Energy...

    Open Energy Info (EERE)

    Jinzaoqiao Hydro Power Limited Corporation Jump to: navigation, search Name: Fujian Jinzaoqiao Hydro Power Limited Corporation Place: Ningde, Fujian Province, China Sector: Hydro...

  1. Sri Sai Manasa Nature Tech Pvt Limited | Open Energy Information

    Open Energy Info (EERE)

    Sai Manasa Nature Tech Pvt Limited Jump to: navigation, search Name: Sri Sai Manasa Nature Tech Pvt Limited Place: Hyderabad, Andhra Pradesh, India Zip: 500072 Sector: Services...

  2. Naranja Sahakari Sakkare Karkhane Limited NSSKL | Open Energy...

    Open Energy Info (EERE)

    Sakkare Karkhane Limited (NSSKL) Place: Karnataka, India Product: Karnataka based sugar mill with co-generation activities. References: Naranja Sahakari Sakkare Karkhane Limited...

  3. Karnataka Power Corporation Limited and National Thermal Power...

    Open Energy Info (EERE)

    Power Corporation Limited and National Thermal Power Corporation JV Jump to: navigation, search Name: Karnataka Power Corporation Limited and National Thermal Power Corporation JV...

  4. Earls Nook Limited Formerly Biofuels Corporation Plc | Open Energy...

    Open Energy Info (EERE)

    Earls Nook Limited Formerly Biofuels Corporation Plc Jump to: navigation, search Name: Earls Nook Limited (Formerly Biofuels Corporation Plc) Place: Teeside, United Kingdom Zip:...

  5. IndianOil CREDA Biofuels Limited | Open Energy Information

    Open Energy Info (EERE)

    IndianOil CREDA Biofuels Limited Jump to: navigation, search Name: IndianOil-CREDA Biofuels Limited Place: Mumbai, Chhattisgarh, India Zip: 400 051 Sector: Renewable Energy...

  6. Southwest Wind Farm Private Limited ESS ARR Group | Open Energy...

    Open Energy Info (EERE)

    Southwest Wind Farm Private Limited ESS ARR Group Jump to: navigation, search Name: Southwest Wind Farm Private Limited (ESS ARR Group) Place: Coimbatore, Tamil Nadu, India Zip:...

  7. Notice of Emergency Action - Emergency Order To Resume Limited...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emergency Action - Emergency Order To Resume Limited Operation at the Potomac River ... Notice of Emergency Action - Emergency Order To Resume Limited Operation at the Potomac ...

  8. Theory of factors limiting high gradient operation of warm acceleratin...

    Office of Scientific and Technical Information (OSTI)

    Theory of factors limiting high gradient operation of warm accelerating structures Citation Details In-Document Search Title: Theory of factors limiting high gradient operation of ...

  9. Ecotality Inc formerly Alchemy Enterprises Limited | Open Energy...

    Open Energy Info (EERE)

    Inc formerly Alchemy Enterprises Limited Jump to: navigation, search Name: Ecotality Inc (formerly Alchemy Enterprises Limited) Place: Scottsdale, Arizona Zip: 85251 Sector:...

  10. Nahar Industrial Enterprises Limited NIEL | Open Energy Information

    Open Energy Info (EERE)

    Industrial Enterprises Limited NIEL Jump to: navigation, search Name: Nahar Industrial Enterprises Limited (NIEL) Place: Punjab, India Zip: 140506 Sector: Biomass Product:...

  11. Solar Power Company Limited SPC | Open Energy Information

    Open Energy Info (EERE)

    Solar Power Company Limited SPC Jump to: navigation, search Name: Solar Power Company Limited (SPC) Place: Thailand Sector: Solar Product: Thailand-based company that designs,...

  12. First National Battery PTY Limited FNB Australia | Open Energy...

    Open Energy Info (EERE)

    PTY Limited FNB Australia Jump to: navigation, search Name: First National Battery (PTY) Limited (FNB Australia) Place: Australia Product: Distributes motive power batteries and...

  13. Huadian Inner Mongolia Kailu Wind Power Company Limited | Open...

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    Inner Mongolia Kailu Wind Power Company Limited Jump to: navigation, search Name: Huadian Inner Mongolia Kailu Wind Power Company Limited Place: Jinan, Inner Mongolia Autonomous...

  14. EnviTec Biogas India Private Limited | Open Energy Information

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    Private Limited Jump to: navigation, search Name: EnviTec Biogas India Private Limited Place: India Product: Manufacturer of anaerobic digesters. References: EnviTec Biogas India...

  15. Accelerator physics and technology limitations to ultimate energy...

    Office of Scientific and Technical Information (OSTI)

    technology limitations to ultimate energy and luminosity in very large hadron colliders Citation Details In-Document Search Title: Accelerator physics and technology limitations to ...

  16. Sree Rayalseema Green Energy Limited | Open Energy Information

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    Rayalseema Green Energy Limited Jump to: navigation, search Name: Sree Rayalseema Green Energy Limited Place: Gooty, Andhra Pradesh, India Zip: 515 402 Sector: Biomass Product: A...

  17. The Green Renewable Energy Company Limited | Open Energy Information

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    Renewable Energy Company Limited Jump to: navigation, search Name: The Green Renewable Energy Company Limited Place: London, United Kingdom Sector: Biomass Product: Company to...

  18. Carbon Compliance Acquisition 16 Limited | Open Energy Information

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    Compliance Acquisition 16 Limited Jump to: navigation, search Name: Carbon Compliance Acquisition 16 Limited Place: United Kingdom Zip: LS12DS Product: Security broking and fund...

  19. Chiranjjeevi Wind Energy Limited CWEL | Open Energy Information

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    Chiranjjeevi Wind Energy Limited CWEL Jump to: navigation, search Name: Chiranjjeevi Wind Energy Limited (CWEL) Place: Pollachi, Tamil Nadu, India Zip: 642 002 Sector: Wind energy...

  20. Indian Renewable Energy Development Agency Limited IREDA | Open...

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    Development Agency Limited IREDA Jump to: navigation, search Name: Indian Renewable Energy Development Agency Limited (IREDA) Place: New Delhi, Delhi (NCT), India Zip: 110003...

  1. Allco Renewable Energy Group Limited LLC | Open Energy Information

    Open Energy Info (EERE)

    Allco Renewable Energy Group Limited LLC Jump to: navigation, search Name: Allco Renewable Energy Group Limited, LLC Place: New York, New York Zip: 10005 Sector: Biomass, Solar,...

  2. Sum frequency generation and catalytic reaction studies of the removal of the organic capping agents from Pt nanoparticles by UV-ozone treatment

    SciTech Connect (OSTI)

    Aliaga, Cesar; Park, Jeong Y.; Yamada, Yusuke; Lee, Hyun Sook; Tsung, Chia-Kuang; Yang, Peidong; Somorjai, Gabor A.

    2009-12-10

    We report the structure of the organic capping layers of platinum colloid nanoparticles and their removal by UV-ozone exposure. Sum frequency generation vibrational spectroscopy (SFGVS) studies identify the carbon-hydrogen stretching modes on poly(vinylpyrrolidone) (PVP) and tetradecyl tributylammonium bromide (TTAB)-capped platinum nanoparticles. We found that the UV-ozone treatment technique effectively removes the capping layer on the basis of several analytical measurements including SFGVS, X-ray photoelectron spectroscopy, and diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). The overall shape of the nanoparticles was preserved after the removal of capping layers, as confirmed by transmission electron microscopy (TEM). SFGVS of ethylene hydrogenation on the clean platinum nanoparticles demonstrates the existence of ethylidyne and di-{sigma}-bonded species, indicating the similarity between single-crystal and nanoparticle systems.

  3. The limits of the nuclear landscape

    SciTech Connect (OSTI)

    Nazarewicz, Witold; Erler, J.; Birge, N.; Kortelainen, E. M.; Olsen, E.; Perhac, A.; Stoitsov, M.

    2012-01-01

    In 2011, 100 new nuclides were discovered1. They joined the approximately 3,000 stable and radioactive nuclides that either occur naturally on Earth or are synthesized in the laboratory2,3. Every atomic nucleus, characterized by a specific number of protons and neutrons, occupies a spot on the chart of nuclides, which is bounded by drip lines indicating the values of neutron and proton number at which nuclear binding ends. The placement of the neutron drip line for the heavier elements is based on theoretical predictions using extreme extrapolations, and so is uncertain. However, it is not known how uncertain it is or how many protons and neutrons can be bound in a nucleus. Here we estimate these limits of the nuclear landscape and provide statistical and systematic uncertainties for our predictions. We use nuclear density functional theory, several Skyrme interactions and high-performance computing, and find that the number of bound nuclides with between 2 and 120 protons is around 7,000. We find that extrapolations for drip-line positions and selected nuclear properties, including neutron separation energies relevant to astrophysical processes, are very consistent between the models used.

  4. The ultimate downscaling limit of FETs.

    SciTech Connect (OSTI)

    Mamaluy, Denis; Gao, Xujiao; Tierney, Brian David

    2014-10-01

    We created a highly efficient, universal 3D quant um transport simulator. We demonstrated that the simulator scales linearly - both with the problem size (N) and number of CPUs, which presents an important break-through in the field of computational nanoelectronics. It allowed us, for the first time, to accurately simulate and optim ize a large number of realistic nanodevices in a much shorter time, when compared to other methods/codes such as RGF[~N 2.333 ]/KNIT, KWANT, and QTBM[~N 3 ]/NEMO5. In order to determine the best-in-class for different beyond-CMOS paradigms, we performed rigorous device optimization for high-performance logic devices at 6-, 5- and 4-nm gate lengths. We have discovered that there exists a fundamental down-scaling limit for CMOS technology and other Field-Effect Transistors (FETs). We have found that, at room temperatures, all FETs, irre spective of their channel material, will start experiencing unacceptable level of thermally induced errors around 5-nm gate lengths.

  5. Thermal island destabilization and the Greenwald limit

    SciTech Connect (OSTI)

    White, R. B.; Gates, D. A.; Brennan, D. P.

    2015-02-15

    Magnetic reconnection is ubiquitous in the magnetosphere, the solar corona, and in toroidal fusion research discharges. In a fusion device, a magnetic island saturates at a width which produces a minimum in the magnetic energy of the configuration. At saturation, the modified current density profile, a function of the flux in the island, is essentially flat, the growth rate proportional to the difference in the current at the O-point and the X-point. Further modification of the current density profile in the island interior causes a change in the island stability and additional growth or contraction of the saturated island. Because field lines in an island are isolated from the outside plasma, an island can heat or cool preferentially depending on the balance of Ohmic heating and radiation loss in the interior, changing the resistivity and hence the current in the island. A simple model of island destabilization due to radiation cooling of the island is constructed, and the effect of modification of the current within an island is calculated. An additional destabilization effect is described, and it is shown that a small imbalance of heating can lead to exponential growth of the island. A destabilized magnetic island near the plasma edge can lead to plasma loss, and because the radiation is proportional to plasma density and charge, this effect can cause an impurity dependent density limit.

  6. FAQs for Limited English Proficiency Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FAQs for Limited English Proficiency Program FAQs for Limited English Proficiency Program 1. Q: Who is a Limited English Proficient (LEP) individual? A: Individuals who do not speak English as their primary language and who have a limited ability to read, speak, write, or understand English can be limited English proficient, or "LEP." These individuals may be entitled language assistance with respect to a particular type of service, benefit, or encounter. 2.Q: What are the relevant

  7. Limited Electricity Generation Supply and Limited Natural Gas Supply Cases (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01

    Development of U.S. energy resources and the permitting and construction of large energy facilities have become increasingly difficult over the past 20 years, and they could become even more difficult in the future. Growing public concern about global warming and CO2 emissions also casts doubt on future consumption of fossil fuels -- particularly coal, which releases the largest amount of CO2 per unit of energy produced. Even without regulations to limit greenhouse gas emissions in the United States, the investment community may already be limiting the future use of some energy options. In addition, there is considerable uncertainty about the future availability of, and access to, both domestic and foreign natural gas resources.

  8. Clean Cities ozone air quality attainment and maintenance strategies that employ alternative fuel vehicles, with special emphasis on natural gas and propane

    SciTech Connect (OSTI)

    Santini, D.J.; Saricks, C.L.

    1998-08-04

    Air quality administrators across the nation are coming under greater pressure to find new strategies for further reducing automotive generated non-methane hydrocarbon (NMHC) and nitrogen oxide (NOx) emissions. The US Environmental Protection Agency (EPA) has established stringent emission reduction requirements for ozone non-attainment areas that have driven the vehicle industry to engineer vehicles meeting dramatically tightened standards. This paper describes an interim method for including alternative-fueled vehicles (AFVs) in the mix of strategies to achieve local and regional improvements in ozone air quality. This method could be used until EPA can develop the Mobile series of emissions estimation models to include AFVs and until such time that detailed work on AFV emissions totals by air quality planners and emissions inventory builders is warranted. The paper first describes the challenges confronting almost every effort to include AFVs in targeted emissions reduction programs, but points out that within these challenges resides an opportunity. Next, it discusses some basic relationships in the formation of ambient ozone from precursor emissions. It then describes several of the salient provisions of EPA`s new voluntary emissions initiative, which is called the Voluntary Mobile Source Emissions Reduction Program (VMEP). Recent emissions test data comparing gaseous-fuel light-duty AFVs with their gasoline-fueled counterparts is examined to estimate percent emissions reductions achievable with CNG and LPG vehicles. Examples of calculated MOBILE5b emission rates that would be used for summer ozone season planning purposes by an individual Air Quality Control Region (AQCR) are provided. A method is suggested for employing these data to compute appropriate voluntary emission reduction credits where such (lighter) AFVs would be acquired. It also points out, but does not quantify, the substantial reduction credits potentially achievable by substituting gaseous-fueled for gasoline-fueled heavy-duty vehicles. Finally, it raises and expands on the relevance of AFVs and their deployment to some other provisions embedded in EPA`s current guidance for implementing 1-hour NAAQS--standards which currently remain in effect--as tools to provide immediate reductions in ozone, without waiting for promised future clean technologies.

  9. Pulmonary function and symptom responses after 6. 6-hour exposure to 0. 12-ppm ozone with moderate exercise (journal version)

    SciTech Connect (OSTI)

    Folinsbee, L.J.; Horstman, D.H.; McDonnell, W.F.

    1988-01-01

    Episodes occasionally occur when ambient ozone (O/sub 3/) levels remain at or near 0.12 ppm for more than 6 h. The hypothesis that prolonged exposure to 0.12 ppm O/sub 3/ would result in progressively larger changes in respiratory function and symptoms over time was tested. Ten nonsmoking males (18-35 yr) were exposed once to clear air (CA) and once to 0.12 pp, O/sub 3/ for 6.75 h. Exposures consisted of six 50-min exercise periods, each followed by 10-min rest and measurement; a 45-min lunch period followed the third exercise period. Exercise ventilation averaged approximately 40 1/min. Forced expiratory and inspiratory spirometry and respiratory symptoms were measured prior to exposure and after each exercise. Increases in the symptom ratings of cough and pain on deep inspiration were observed with O/sub 3/ exposure but not with CA. Airway reactivity to methacholine was approximately doubled following O/sub 3/ exposure. Spirometry results indicate that prolonged exposure to 0.12 ppm O/sub 3/ results in a marked increase in non-specific airway reactivity and progressive changes in respiratory function.

  10. The role of EPA`s Acid Rain Division in the Ozone Transport Commission`s NOx budget program

    SciTech Connect (OSTI)

    Schary, C.; Culligan, K.

    1997-12-31

    The Ozone Transport Commission`s (OTC) Nitrogen Oxides (NO{sub x}) Budget Program will implement the emissions reduction goal of the 1994 Memorandum of Understanding between its twelve member states and the District of Columbia. The program will achieve its significant NO{sub x} reductions from electric utilities and industrial boilers using a {open_quotes}cap-and-trade{close_quotes} approach modeled after the US Environmental Protection Agency`s sulfur dioxide emissions trading under the Acid Rain Program. The similarity of the two programs has led to the development of an important partnership between the OTC states and EPA`s Acid Rain Division, Over the past two years, Acid Rain Program staff have shared their technical expertise and assisted extensively in the development of the program`s rules. Leveraging the investment EPA made in the systems used to run the Acid Rain Program, the OTC states have asked the Acid Rain Division to administer the data systems for them, and together are working to expand its existing Emissions Tracking System and to modify a clone of the sulfur dioxide Allowance Tracking System, to fulfill the unique requirements of the NO{sub x} Budget Program. This partnership is an important example of the new type of cooperation and sharing of expertise and resources that should develop between EPA and states as they launch multi-state programs to address regional pollution problems that defy a single-state solution.

  11. EA-365-A Centre Lane Trading Limited | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -A Centre Lane Trading Limited EA-365-A Centre Lane Trading Limited Order authorizing CLT to export electric energy to Canada. PDF icon EA-365-A Centre Lane (CN).pdf More Documents ...

  12. PP-85-3 Boliden Power Limited | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Power Limited to construct, operate, and maintain transmission facilities at the U.S. - Canada Border. PDF icon PP 85-3 Boliden Power Limited More Documents & Publications PP-85-2 ...

  13. CO2e Capital Limited | Open Energy Information

    Open Energy Info (EERE)

    e Capital Limited Jump to: navigation, search Name: CO2e Capital Limited Place: New York City, New York Zip: 10022 Product: New York based merchant bank focused on reducing global...

  14. Dong Energy London Array Limited Formerly known as CORE Ltd ...

    Open Energy Info (EERE)

    Limited is a UK Joint Venture between Farm energy and Energi E2, involved in offshore wind farms in the outer Thames Estuary. References: Dong Energy London Array Limited...

  15. UNEP-Risoe-Economics of GHG Limitations: Country Study Series...

    Open Energy Info (EERE)

    Gas Limitations1 Country study series: Argentina, Ecuador, Estonia, Hungary, Indonesia, Mauritius, Senegal, Vietnam Parallel country studies: Botswana, Tanzania, Zambia...

  16. Investigation of Microscopic Materials Limitations of Superconducting RF

    Office of Scientific and Technical Information (OSTI)

    Cavities (Technical Report) | SciTech Connect Investigation of Microscopic Materials Limitations of Superconducting RF Cavities Citation Details In-Document Search Title: Investigation of Microscopic Materials Limitations of Superconducting RF Cavities The high-field performance of SRF cavities is often limited by breakdown events below the intrinsic limiting surface fields of Nb, and there is abundant evidence that these breakdown events are localized in space inside the cavity. Also, there

  17. Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency | Department of Energy Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency This process heating tip sheet recommends using lower flammable limit monitoring equipment to improve oven efficiency. PROCESS HEATING TIP SHEET #11 PDF icon Use Lower Flammable Limit Monitoring Equipment to Improve Process Oven Efficiency (October 2007) More Documents & Publications Check Burner

  18. PP-206 Frontera Generation Limited Partnership | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Frontera Generation Limited Partnership PP-206 Frontera Generation Limited Partnership Presidential permit authorizing Frontera Generation Limited Partnership to construct, operate, and maintain electric transmission facilities at the U.S-Mexican border. PDF icon PP-206 Frontera Generation Limited Partnership More Documents & Publications Application to Export Electric Energy OE Docket No. EA-403 Frontera Marketing, LLC PP-174 Imperial Irrigation District PP-53 Rio Grande Electric

  19. Limited_Burn_CX_10-26-09.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Limited English Proficiency Limited English Proficiency On August 11, 2000, President Clinton signed Executive Order 13166, "Improving Access to Services for Persons with Limited English Proficiency." The Executive Order requires federal agencies, including the Department of Energy, to examine the programs and services they provide, to determine whether there is a need for language assistance for persons with Limited English proficiency (LEP) related to their programs and services, and

  20. Representation of Limited Rights Data and Restricted Computer Software |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data and Restricted Computer Software PDF icon Representation of Limited Rights Data and Restricted Computer Software More Documents & Publications CLB-1003.PDF&#0; Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses CDLB-1003.PDF&#0;

  1. An alternative approach to achieving water quality-based limits

    SciTech Connect (OSTI)

    Hart, C.M.; Graeser, W.C.

    1995-12-01

    Since May 1982, members of the Iron and Steel Industry have been required to meet effluent limits based on Best Available Technology (BAT) for a process water discharge to receiving stream. US Steel Clairton Works has been successful in meeting these limits in the last three years; however, the current regulatory thrust is toward more stringent limits based on water quality. In cases of smaller streams such as the receiving stream for Clairton Works` process outfall, these limits can be very rigid. This paper will discuss the alternative approaches investigated to meet the new more stringent limits including the solution chosen.

  2. Headquarters Facilities Master Security Plan- Chapter 2, Limited Areas, Vault-Type Rooms and Temporary Limited Areas

    Broader source: Energy.gov [DOE]

    2016 Headquarters Facilities Master Security Plan - Chapter 2, Limited Areas, Vault-Type Rooms and Temporary Limited Areas Describes DOE Headquarters procedures for establishing, maintaining, and deactivating Limited Areas and Vault-Type Rooms and protecting the classified information handled within those Areas.

  3. Conditions for diffusion-limited and reaction-limited recombination in nanostructured solar cells

    SciTech Connect (OSTI)

    Ansari-Rad, Mehdi; Department of Physics, University of Shahrood, Shahrood ; Anta, Juan A.; Arzi, Ezatollah

    2014-04-07

    The performance of Dye-sensitized solar cells (DSC) and related devices made of nanostructured semiconductors relies on a good charge separation, which in turn is achieved by favoring charge transport against recombination. Although both processes occur at very different time scales, hence ensuring good charge separation, in certain cases the kinetics of transport and recombination can be connected, either in a direct or an indirect way. In this work, the connection between electron transport and recombination in nanostructured solar cells is studied both theoretically and by Monte Carlo simulation. Calculations using the Multiple-Trapping model and a realistic trap distribution for nanostructured TiO{sub 2} show that for attempt-to-jump frequencies higher than 10{sup 11}10{sup 13} Hz, the system adopts a reaction limited (RL) regime, with a lifetime which is effectively independent from the speed of the electrons in the transport level. For frequencies lower than those, and depending on the concentration of recombination centers in the material, the system enters a diffusion-limited regime (DL), where the lifetime increases if the speed of free electrons decreases. In general, the conditions for RL or DL recombination depend critically on the time scale difference between recombination kinetics and free-electron transport. Hence, if the former is too rapid with respect to the latter, the system is in the DL regime and total thermalization of carriers is not possible. In the opposite situation, a RL regime arises. Numerical data available in the literature, and the behavior of the lifetime with respect to (1) density of recombination centers and (2) probability of recombination at a given center, suggest that a typical DSC in operation stays in the RL regime with complete thermalization, although a transition to the DL regime may occur for electrolytes or hole conductors where recombination is especially rapid or where there is a larger dispersion of energies of electron acceptors.

  4. Pulmonary function and symptom responses after 6. 6-hour exposure to 0. 12 ppm ozone with moderate exercise

    SciTech Connect (OSTI)

    Folinsbee, L.J.; McDonnell, W.F.; Horstman, D.H.

    1988-01-01

    Episodes occasionally occur when ambient ozone (O/sub 3/) levels remain at or near 0.12 ppm for more than 6 h. Small decrements in lung function have been reported following 2-h exposures to 0.12 ppm O/sub 3/. For short exposures to higher O/sub 3/ concentrations, lung function decrements are a function of exposure duration. Thus, we investigated the hypothesis that prolonged exposure to 0.12 ppm O/sub 3/ would result in progressively larger changes in respiratory function and symptoms over time. Ten nonsmoking males were exposed once to clean air and once to 0.12 ppm O/sub 3/ for 6.6 h. Exposures consisted of six 50-min exercise periods, each followed by 10-min rest and measurement; a 35-min lunch period followed by the third exercise period. Exercise ventilation averaged approximately 40 L/min. Forced expiratory and inspiratory spirometry and respiratory symptoms were measured prior to exposure and after each exercise. Airway reactivity to methacholine was determined after each exposure. After correcting for the air exposures, FEV 1.0 was found to decrease linearly during the O/sub 3/ exposure and was decreased by an average of 13.0 percent at the end of exposure. Decreases in FVC and FEF24-75% were also linear and averaged 8.3 and 17.4 percent, respectively, at the end of exposure. On forced inspiratory tests, the FIVC and FIV05 were decreased 12.6 and 20.7 percent, respectively. Increases in the symptom ratings of cough and pain on deep inspiration were observed with O/sub 3/ exposure but not with clean air. Airway reactivity to methacholine was approximately doubled following O/sub 3/ exposure.

  5. U.S. NO2 trends (2005-2013): EPA Air Quality System (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI)

    Office of Scientific and Technical Information (OSTI)

    Atmospheric Environment 110 (2015) 130-143 Contents lists available at ScienceDirect Atmospheric Environment journal homepage: www.elsevier.com/locate/atmosenv U.S. NO2 trends (2005-2013): EPA Air Quality System (AQS) data versus improved observations from the Ozone Monitoring Instrument (OMI) CrossMark Lok N. Lamsal a b *, Bryan N. Duncan b, Yasuko Yoshida c'b, Nickolay A. Krotkov b, Kenneth E. Pickering b, David G. Streets d, Zifeng Lu d a Goddard Earth Sciences Technology and Research,

  6. Golden Reading Room: Office of Acquisition Documents, Sole of Limited

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Source Justifications | Department of Energy Sole of Limited Source Justifications Golden Reading Room: Office of Acquisition Documents, Sole of Limited Source Justifications Below are electronic versions of Golden Field Office Reading Room documents that were created after November 1, 1996, per the requirements of the Electronic Freedom of Information Act Amendment of 1996. Most documents are available in Adobe Acrobat Portable Document Format (PDF). Sole of Limited Source Justificati

  7. Limited-Notice Performance Test Inspectors Guide | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Limited-Notice Performance Test Inspectors Guide Limited-Notice Performance Test Inspectors Guide October 2014 This document describes the Limited-Notice Performance Testing Program employed by DOE's Office of Enterprise Assessments to evaluate DOE safeguards and security programs. This document is one in a series of Inspectors Guides used by the Office of Security Assessments, within DOE's Office of Enterprise Assessments (EA), to conduct Independent Oversight appraisals of safeguards and

  8. Idaho Cleanup Project Clearance Limits for Personal Property | Department

    Energy Savers [EERE]

    of Energy Idaho Cleanup Project Clearance Limits for Personal Property Idaho Cleanup Project Clearance Limits for Personal Property Kevin Konzen*, CH2M-WG Idaho, LLC ; Craig Nesshoefer, Idaho Cleanup Project Abstract: CH2M-WG Idaho, LLC (CWI) had sought alternative surface clearance limits for personal property from those referenced in DOE Order 458.1, which were approved September 2013 by the Department of Energy. Because much of the property would remain within DOE control, implementation

  9. DOE Orders Mirant Power Plant to Operate Under Limited Circumstances |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Mirant Power Plant to Operate Under Limited Circumstances DOE Orders Mirant Power Plant to Operate Under Limited Circumstances December 20, 2005 - 11:44am Addthis DOE finds emergency; determines plant will help electric reliability WASHINGTON, D.C. - Secretary of Energy Samuel W. Bodman today issued an order requiring Mirant Corporation's Potomac River Generating Station in Alexandria, Virginia (Mirant) to immediately resume limited operation. The order will help provide

  10. DOE Orders Mirant Power Plant to Operate Under Limited Circumstances |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Orders Mirant Power Plant to Operate Under Limited Circumstances DOE Orders Mirant Power Plant to Operate Under Limited Circumstances Docket No. EO-05-01. Order No. 202-05-3: Secretary of Energy Samuel W. Bodman today issued an order requiring Mirant Corporation's Potomac River Generating Station in Alexandria, Virginia (Mirant) to immediately resume limited operation. The order will help provide electric reliability for Washington, D.C., and will do so at the lowest

  11. Representation of Limited Rights Data and Restricted Computer Software |

    Energy Savers [EERE]

    Department of Energy Representation of Limited Rights Data and Restricted Computer Software Representation of Limited Rights Data and Restricted Computer Software Any data delivered under an award resulting from this announcement is subject to the Rights in Data - General or the Rights in Data - Programs Covered Under Special Data Statutes clause (See Intellectual Property Provisions). Under these clauses, the Recipient may withhold from delivery data that qualify as limited rights data or

  12. Optimizing areal capacities through understanding the limitations of

    Office of Scientific and Technical Information (OSTI)

    lithium-ion electrodes (Journal Article) | SciTech Connect Optimizing areal capacities through understanding the limitations of lithium-ion electrodes Citation Details In-Document Search Title: Optimizing areal capacities through understanding the limitations of lithium-ion electrodes Increasing the areal capacity or electrode thickness in lithium ion batteries is one possible means to increase pack level energy density while simultaneously lowering cost. The physics that limit use of high

  13. EA-361 Aquilon Power Limited | Department of Energy

    Energy Savers [EERE]

    Categorical Exclusion (CS) Determination, Office of Electricity Delivery and Energy Reliability (OE): EA-361 Aquilon Power Limited EA-196-B Minnesota Power EA-196-C Minnesota Power

  14. Spark Solar Australia Proprietary Limited | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Spark Solar Australia Proprietary Limited Place: O Connor, Australian Capital Territory, Australia Zip: 2602 Product: Australia-based...

  15. Overcoming the Range Limitation of Medium-Duty Battery Electric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    saecomveh.saejournals.org Overcoming the Range Limitation of Medium-Duty Battery Electric Vehicles through the use of Hydrogen Fuel-Cells Eric Wood, Lijuan Wang, Jeffrey ...

  16. Rucheng County Yuzaikou Hydropower Company Limited | Open Energy...

    Open Energy Info (EERE)

    Place: Nandong Town, Hunan Province, China Zip: 423000 Sector: Hydro Product: Hydroelectric developer References: Rucheng County Yuzaikou Hydropower Company Limited1 This...

  17. Laser selection based on maximum permissible exposure limits...

    Office of Scientific and Technical Information (OSTI)

    Laser selection based on maximum permissible exposure limits for visible and middle-near infrared repetitively pulsed lasers. Citation Details In-Document Search Title: Laser ...

  18. Articulated limiter blade for a tokamak fusion reactor

    DOE Patents [OSTI]

    Doll, David W.

    1985-01-01

    A limiter blade for a large tokomak fusion reactor includes three articulated blade sections for enabling the limiter blade to be adjusted for plasmas of different sizes. Each blade section is formed of a rigid backing plate carrying graphite tiles coated with titanium carbide, and the limiter blade forms a generally elliptic contour in both the poloidal and toroidal directions to uniformly distribute the heat flow to the blade. The limiter blade includes a central blade section movable along the major radius of the vacuum vessel, and upper and lower pivotal blade sections which may be pivoted by linear actuators having rollers held to the back surface of the pivotal blade sections.

  19. Articulated limiter blade for a tokamak fusion reactor

    DOE Patents [OSTI]

    Doll, D.W.

    1982-10-21

    A limiter blade for a large tokomak fusion reactor includes three articulated blade sections for enabling the limiter blade to be adjusted for plasmas of different sizes. Each blade section is formed of a rigid backing plate carrying graphite tiles coated with titanium carbide, and the limiter blade forms a generally elliptic contour in both the poloidal and toroidal directions to uniformly distribute the heat flow to the blade. The limiter blade includes a central blade section movable along the major radius of the vacuum vessel, and upper and lower pivotal blade sections which may be pivoted by linear actuators having rollers held to the back surface of the pivotal blade sections.

  20. Use Lower Flammable Limit Monitoring Equipment to Improve Process...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This process heating tip sheet recommends using lower flammable limit monitoring equipment to improve oven efficiency. PROCESS HEATING TIP SHEET 11 PDF icon Use Lower Flammable ...

  1. GI Power Corporation Limited GIPCL | Open Energy Information

    Open Energy Info (EERE)

    New Delhi, Delhi (NCT), India Zip: 110020 Sector: Wind energy Product: Delhi-based start-up wind project developer. References: GI Power Corporation Limited (GIPCL)1 This...

  2. Recovery Efficiency, False Negative Rate, and Limit of Detection...

    Office of Scientific and Technical Information (OSTI)

    Recovery Efficiency, False Negative Rate, and Limit of Detection Performance of a Validated Macrofoam-Swab Sampling Method with Low Surface Concentrations of Two Bacillus anthracis...

  3. Increasing ask query limit | OpenEI Community

    Open Energy Info (EERE)

    via json. For example, this query only returns two entries: http:en.openei.orgservicesrestutilityrates?versionlatest&formatjsonplain&offset9998&limit30&detailb...

  4. Belgaum Wind Farms Private Limited BWFPL | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Belgaum Wind Farms Private Limited (BWFPL) Place: Mumbai, Maharashtra, India Zip: 400705 Product: Mumbai-based project developer and subsidiary...

  5. Enercon Financial Consultancy Private Limited | Open Energy Informatio...

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Enercon Financial Consultancy Private Limited Place: Mumbai, Maharashtra, India Zip: 400 058 Sector: Wind energy Product: Mumbai-based arm of...

  6. Tehri Hydro Development Corporation Limited | Open Energy Information

    Open Energy Info (EERE)

    Solar, Wind energy Product: Focused on hydro projects; diversifying into solar and wind power. References: Tehri Hydro Development Corporation Limited1 This article is a stub....

  7. Apollo Solar Lanka Limited ASLL | Open Energy Information

    Open Energy Info (EERE)

    Lanka Zip: 10250 Sector: Solar Product: Sri Lankan company that is developing both PV & thermal solar technologies. References: Apollo Solar Lanka Limited (ASLL)1 This article...

  8. GCL Poly Energy Holdings Limited | Open Energy Information

    Open Energy Info (EERE)

    energy enterprise who specialize in developing, managing and operating green energy projects in mainland China. References: GCL-Poly Energy Holdings Limited1 This...

  9. Comments on Emergency Order to Resume Limited Operation at the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Operation at the Potomac River Generating Station, Alexandria, VA from the Chesapeake Climate Action Network. Comments on Emergency Order to Resume Limited Operation at the ...

  10. Call for emission limits heats debate on global warming

    SciTech Connect (OSTI)

    Singer, S.F.

    1997-08-01

    Emission limits on carbon dioxide is recommended by an Intergovernmental Panel in a discussion on global warming. (AIP) {copyright} {ital 1997 American Institute of Physics.}

  11. WIMP Dark Matter Limit-Direct Detection Data and Sensitivity...

    Office of Scientific and Technical Information (OSTI)

    the Interactive Plotter for WIMP Dark Matter Limit-Direct Detection Data on their website. ... Barbara Sponsoring Org: USDOE; National Science Foundation (NSF) Country of Publication: ...

  12. Acquisition Letter on the Implications of Time-Limited Funds

    Broader source: Energy.gov [DOE]

    The attached Acquisition Letter has been issued to provide guidance to Contracting Officers on the implications of time-limited funding on contract planning, award, and administration.

  13. Thermal island destabilization and the Greenwald limit (Journal...

    Office of Scientific and Technical Information (OSTI)

    Details In-Document Search This content will become publicly available on February 24, 2016 Title: Thermal island destabilization and the Greenwald limit Authors: White, R....

  14. UNEP-Risoe-Economics of GHG Limitations: Country Study Series...

    Open Energy Info (EERE)

    Econo References Economics of Greenhouse Gas Limitations1 Country study series: Argentina, Ecuador, Estonia, Hungary, Indonesia, Mauritius, Senegal, Vietnam Parallel country...

  15. WAC - 173 - 221 - Discharge Standards and Effluent Limitations...

    Open Energy Info (EERE)

    - Discharge Standards and Effluent Limitations for Domestic Wastewater Facilities Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document-...

  16. Limits on the thermoacoustic detectability of electric and magnetic charges

    SciTech Connect (OSTI)

    Akerlof, C.W.

    1982-09-01

    The energy loss is estimated for a slow magnetic monopole traveling through a conductor. The thermoacoustic signal derived from this process is compared to the acoustic phonon fluctuation pressure. The results show that single-monopole detectability is strongly limited by thermal noise. These calculations also imply severe limits for the detectability of charged-particle cascades.

  17. Growth behavior and properties of atomic layer deposited tin oxide on silicon from novel tin(II)acetylacetonate precursor and ozone

    SciTech Connect (OSTI)

    Kannan Selvaraj, Sathees; Feinerman, Alan; Takoudis, Christos G.

    2014-01-15

    In this work, a novel liquid tin(II) precursor, tin(II)acetylacetonate [Sn(acac){sub 2}], was used to deposit tin oxide films on Si(100) substrate, using a custom-built hot wall atomic layer deposition (ALD) reactor. Three different oxidizers, water, oxygen, and ozone, were tried. Resulting growth rates were studied as a function of precursor dosage, oxidizer dosage, reactor temperature, and number of ALD cycles. The film growth rate was found to be 0.1??0.01?nm/cycle within the wide ALD temperature window of 175300?C using ozone; no film growth was observed with water or oxygen. Characterization methods were used to study the composition, interface quality, crystallinity, microstructure, refractive index, surface morphology, and resistivity of the resulting films. X-ray photoelectron spectra showed the formation of a clean SnO{sub x}Si interface. The resistivity of the SnO{sub x} films was calculated to be 0.3?? cm. Results of this work demonstrate the possibility of introducing Sn(acac){sub 2} as tin precursor to deposit conducting ALD SnO{sub x} thin films on a silicon surface, with clean interface and no formation of undesired SiO{sub 2} or other interfacial reaction products, for transparent conducting oxide applications.

  18. Three-Dimensional Mapping of Ozone-Induced Injury in the Nasal Airways of Monkeys Using Magnetic Resonance Imaging and Morphometric Techniques

    SciTech Connect (OSTI)

    Carey, Stephen A.; Minard, Kevin R.; Trease, Lynn L.; Wagner, James G.; Garcia, Guilherme M.; Ballinger, Carol A.; Kimbell, Julia; Plopper, Charles G.; Corley, Rick A.; Postlewait, Ed; Harkema, Jack R.

    2007-03-01

    ABSTRACT Age-related changes in gross and microscopic structure of the nasal cavity can alter local tissue susceptibility as well as the dose of inhaled toxicant delivered to susceptible sites. This article describes a novel method for the use of magnetic resonance imaging, 3-dimensional airway modeling, and morphometric techniques to characterize the distribution and magnitude of ozone-induced nasal injury in infant monkeys. Using this method, we are able to generate age-specific, 3-dimensional, epithelial maps of the nasal airways of infant Rhesus macaques. The principal nasal lesions observed in this primate model of ozone-induced nasal toxicology were neutrophilic rhinitis, along with necrosis and exfoliation of the epithelium lining the anterior maxilloturbinate. These lesions, induced by acute or cyclic (episodic) exposures, were examined by light microscopy, quantified by morphometric techniques, and mapped on 3-dimensional models of the nasal airways. Here, we describe the histopathologic, imaging, and computational biology methods developed to efficiently characterize, localize, quantify, and map these nasal lesions. By combining these techniques, the location and severity of the nasal epithelial injury were correlated with epithelial type, nasal airway geometry, and local biochemical and molecular changes on an individual animal basis. These correlations are critical for accurate predictive modeling of exposure-dose-response relationships in the nasal airways, and subsequent extrapolation of nasal findings in animals to humans for developing risk assessment.

  19. Performance limit analysis of a metallic fuel for Kalimer

    SciTech Connect (OSTI)

    Lee, Byoung Oon; Cheon, J.S.; Lee, C.B.

    2007-07-01

    A metallic fuel is being considered as the fuel for SFR in Korea. The metal fuel development for SFR in Korea started in 2007 in the areas of metal fuel fabrication, cladding materials and fuel performance evaluation. The MACSIS code for a metallic fuel has been developed as a steady-state performance computer code. Present study represents the preliminary parametric results for evaluating the design limits of the metal fuel for SFR in Korea. The operating limits were analyzed by the MACSIS code. The modules of the creep rupture strength for the Mod.HT9 and the barrier cladding were inserted. The strain limits and the CDF limit were analyzed for the HT9, and the Mod.HT9. To apply the concept of a barrier cladding, the burnup limit of the barrier cladding was analyzed. (authors)

  20. Investigation of density limit processes in DIII-D

    SciTech Connect (OSTI)

    Maingi, R.; Mahdavi, M.A.; Petrie, T.W.

    1999-02-01

    A series of experiments has been conducted in DIII-D to investigate density-limiting processes. The authors have studied divertor detachment and MARFEs on closed field lines and find semi-quantitative agreement with theoretical calculations of onset conditions. They have shown that the critical density for MARFE onset at low edge temperature scales as I{sub p}/a{sup 2}, i.e. similar to Greenwald scaling. They have also shown that the scaling of the critical separatrix density with heating power at partial detachment onset agrees with Borass` model. Both of these processes yield high edge density limits for reactors such as ITER. By using divertor pumping and pellet fueling they have avoided these and other processes and accessed densities > 1.5{times} Greenwald limit scaling with H-mode confinement, demonstrating that the Greenwald limit is not a fundamental limit on the core density.

  1. Optical limiting device and method of preparation thereof

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Xu, Su; McBranch, Duncan W.

    2003-01-01

    Optical limiting device and method of preparation thereof. The optical limiting device includes a transparent substrate and at least one homogeneous layer of an RSA material in polyvinylbutyral attached to the substrate. The device may be produced by preparing a solution of an RSA material, preferably a metallophthalocyanine complex, and a solution of polyvinylbutyral, and then mixing the two solutions together to remove air bubbles. The resulting solution is layered onto the substrate and the solvent is evaporated. The method can be used to produce a dual tandem optical limiting device.

  2. On the density limit in the helicon plasma sources

    SciTech Connect (OSTI)

    Kotelnikov, Igor A.

    2014-12-15

    Existence of the density limit in the helicon plasma sources is revisited. The low- and high-frequency regimes of a helicon plasma source operation are distinguished. In the low-frequency regime with ω<√(ω{sub ci}ω{sub ce}), the density limit is deduced from the Golant-Stix criterion of the accessibility of the lower hybrid resonance. In the high-frequency case, ω>√(ω{sub ci}ω{sub ce}), an appropriate limit is given by the Shamrai-Taranov criterion. Both these criteria are closely related to the phenomenon of the coalescence of the helicon wave with the Trivelpiece-Gould mode. We draw a conclusion that the derived density limits are not currently achieved in existing devices, perhaps, because of high energy cost of gas ionization.

  3. Limited Test Ban Treaty | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Limited Test Ban Treaty US Air Force Launches Satellite Carrying NNSA-provided Nuclear Detonation Detection Sensors WASHINGTON, D.C. - On Friday, May 16, with the support of the ...

  4. 5 CCR 1002-62 Colorado Regulations for Effluent Limitations ...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 5 CCR 1002-62 Colorado Regulations for Effluent LimitationsLegal Abstract Regulations...

  5. Predetermining acceptable noise limits in EXAFS spectra in the...

    Office of Scientific and Technical Information (OSTI)

    This condition occurs as we approach the signal-to-noise (SN) limit of the technique where the random noise of ... This paper outlines a method of testing model systems in EXAFS ...

  6. Limite Marinha A Estrutura de Pesquisa Climtica do Programa...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de cerca de 1 a 2 km. Num ambiente marinho, as nuvens da camada limite filtram o sol passivamente mas tambm funcionam como sistemas inter- activos que influenciam e...

  7. Limits on Large Extra Dimensions Based on Observations of Neutron...

    Office of Scientific and Technical Information (OSTI)

    theory of Large Extra Dimensions (LED) proposed by Arkani-Hamed, Dimopoulos, and Dvali. ... faint neutron stars (NS). To set limits on LED we use the model of Hannestad and Raffelt ...

  8. Intensity limitations in compact H{sup minus} cyclotrons

    SciTech Connect (OSTI)

    Baartman, R.A.

    1995-12-31

    At TRIUMF, we have demonstrated 2.5 mA in a compact H{sup -} cyclotron. It is worthwhile to explore possibility of going to even higher intensity. In small cyclotrons, vertical focusing vanishes at the center. The space charge tune shift further reduces vertical focusing, thus determining an upper limit on instantaneous current. Limit on average current is of course also dependent upon phase acceptance, but this can be made quite large in an H{sup -} cyclotron. Longitudinal space charge on the first turn can reduce the phase acceptance as well. For finite ion source brightness, another limit comes from bunching efficiency in presence of space charge forces. We present methods of calculating and optimizing these limits. In particular, we show that it is possible to achieve 10mA in a 50 MeV compact H{sup -} cyclotron.

  9. Toroidal band limiter for a plasma containment device

    DOE Patents [OSTI]

    Kelley, George G.

    1978-01-01

    This invention relates to a toroidal plasma confinement device having poloidal and toroidal magnetic fields for confining a toroidal plasma column with a plasma current induced therein along an endless, circular equilibrium axis in a torus vacuum cavity wherein the improvement comprises the use of a toroidal plasma band limiter mounted within the vacuum cavity in such a manner as to ensure that the plasma energy is distributed more uniformly over the limiter surface thereby avoiding intense local heating of the limiter while at the same time substantially preventing damage to the plasma containment wall of the cavity by the energetic particles diffusing out from the confined plasma. A plurality of poloidal plasma ring limiters are also utilized for containment wall protection during any disruptive instability that might occur during operation of the device.

  10. Inherent limitations and current status of the unresolved resonance treatment

    SciTech Connect (OSTI)

    Hwang, R.N.

    1984-01-01

    The two general methods for representing the behavior of the unresolved resonances and the limitations of these methods are discussed. Possible solutions to the problem are considered. 17 references. (WHK)

  11. Limitations on area compression of beams from pierce guns

    SciTech Connect (OSTI)

    Yakovlev, V.P.; Nezhevenko, O.A. [Omega-P Inc., 202008 Yale Station, New Haven, Connecticut 06520-2008 (United States)

    1999-05-01

    An important limitation for rf sources such as klystrons and magnicons, designed for 10{close_quote}s of MW power outputs at cm-wavelengths, is the transverse electron beam size. Cathode current density limits require high beam area compressions to obtain small transverse beam areas for fixed currents. This paper discusses the limitations to high beam area compression, namely geometrical aberrations and thermal spread in transverse velocities. Compensation can oftentimes be introduced for aberrations, but thermal velocity spread presents a fundamental limitation. Examples where subtle compensation strategies were employed are discussed for three guns with 100 MW beam power, and area compressions greater than 2000:1. Two of these guns have already been built. A clear determination of effective cathode temperature has yet to be found experimentally, but possible means to measure it are discussed. {copyright} {ital 1999 American Institute of Physics.}

  12. Topics: Determining the Beta Limit - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining the Beta Limit UW Madison Madison Symmetric Torus Topics: Determining the Beta Limit MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation One of the reasons improved confinement in MST can be described as "tokamak-like"

  13. UCSB researchers uncover fundamental limits on optical transparency in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conducting oxides | Center for Energy Efficient Materials researchers uncover fundamental limits on optical transparency in conducting oxides FOR IMMEDIATE RELEASE Contact information: Hartwin Peelaers, Materials Department, University of California, Santa Barbara, CA 93106-5050 peelaers [at] engineering [dot] ucsb [dot] edu UCSB researchers uncover fundamental limits on optical transparency in conducting oxides Santa Barbara, California, January 8, 2011 Conducting oxides are used as

  14. Comments on Department of Energy's Emergency Order To Resume Limited

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Operation at Mirant's Potomac River Generating Station and Proposed Mirant Compliance Plan | Department of Energy on Department of Energy's Emergency Order To Resume Limited Operation at Mirant's Potomac River Generating Station and Proposed Mirant Compliance Plan Comments on Department of Energy's Emergency Order To Resume Limited Operation at Mirant's Potomac River Generating Station and Proposed Mirant Compliance Plan Docket No. EO-05-01: Riverkeeper, and the Anacostia Riverkeeper at

  15. Evaluation of Cloud-resolving and Limited Area Model Intercomparison

    Office of Scientific and Technical Information (OSTI)

    Simulations using TWP-ICE Observations. Part 1: Deep Convective Updraft Properties (Journal Article) | SciTech Connect 1: Deep Convective Updraft Properties Citation Details In-Document Search Title: Evaluation of Cloud-resolving and Limited Area Model Intercomparison Simulations using TWP-ICE Observations. Part 1: Deep Convective Updraft Properties Ten 3D cloud-resolving model (CRM) simulations and four 3D limited area model (LAM) simulations of an intense mesoscale convective system

  16. Evaluation of Cloud-resolving and Limited Area Model Intercomparison

    Office of Scientific and Technical Information (OSTI)

    Simulations using TWP-ICE Observations. Part 2: Rain Microphysics (Journal Article) | SciTech Connect 2: Rain Microphysics Citation Details In-Document Search Title: Evaluation of Cloud-resolving and Limited Area Model Intercomparison Simulations using TWP-ICE Observations. Part 2: Rain Microphysics Ten 3D cloud-resolving model (CRM) simulations and four 3D limited area model (LAM) simulations of an intense mesoscale convective system observed on January 23-24, 2006 during the Tropical Warm

  17. Stainless steel 304 cladding mechanical properties and limitations during

    Office of Scientific and Technical Information (OSTI)

    steady state operation of U-ZrH TRIGA type fuel. (Conference) | SciTech Connect Stainless steel 304 cladding mechanical properties and limitations during steady state operation of U-ZrH TRIGA type fuel. Citation Details In-Document Search Title: Stainless steel 304 cladding mechanical properties and limitations during steady state operation of U-ZrH TRIGA type fuel. No abstract prepared. Authors: Coats, Richard Lee ; Dohner, Jeffrey Lynn ; Dahl, James J. ; Walker, Sharon Ann ; Greutman,

  18. Accelerator physics and technology limitations to ultimate energy and

    Office of Scientific and Technical Information (OSTI)

    luminosity in very large hadron colliders (Conference) | SciTech Connect Accelerator physics and technology limitations to ultimate energy and luminosity in very large hadron colliders Citation Details In-Document Search Title: Accelerator physics and technology limitations to ultimate energy and luminosity in very large hadron colliders Authors: Bauer, P. ; Limon, P. ; Peggs, Stephen G. ; Syphers, M. ; Solyak, N. Publication Date: 2001-06-01 OSTI Identifier: 1131205 Report Number(s):

  19. Accelerator physics and technology limitations to ultimate energy and

    Office of Scientific and Technical Information (OSTI)

    luminosity in very large hadron colliders (Conference) | SciTech Connect Accelerator physics and technology limitations to ultimate energy and luminosity in very large hadron colliders Citation Details In-Document Search Title: Accelerator physics and technology limitations to ultimate energy and luminosity in very large hadron colliders × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical

  20. Analytical Estimations for Thermal Crosstalk Retention and Scaling Limits

    Office of Scientific and Technical Information (OSTI)

    in Resistive Memory. (Journal Article) | SciTech Connect Analytical Estimations for Thermal Crosstalk Retention and Scaling Limits in Resistive Memory. Citation Details In-Document Search Title: Analytical Estimations for Thermal Crosstalk Retention and Scaling Limits in Resistive Memory. Abstract not provided. Authors: Lohn, Andrew ; Mickel, Patrick R. ; Marinella, Matthew Publication Date: 2014-04-01 OSTI Identifier: 1141816 Report Number(s): SAND2014-2997J 507562 DOE Contract Number:

  1. PROJECT PROFILE: High-resolution Investigations of Transport Limiting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Defects and Interfaces in Thin-Film Photovoltaic Devices | Department of Energy High-resolution Investigations of Transport Limiting Defects and Interfaces in Thin-Film Photovoltaic Devices PROJECT PROFILE: High-resolution Investigations of Transport Limiting Defects and Interfaces in Thin-Film Photovoltaic Devices Funding Opportunity: SuNLaMP SunShot Subprogram: Photovoltaics Location: National Renewable Energy Laboratory, Golden, CO Amount Awarded: $1,000,000 This project will develop the

  2. Use of Authorized Limits During Decontamination and Demolition Phase |

    Energy Savers [EERE]

    Department of Energy Use of Authorized Limits During Decontamination and Demolition Phase Use of Authorized Limits During Decontamination and Demolition Phase Donald Dihel; Orville W. Cypret*; G. Vazquez; W. Alexander Williams Abstract: Protecting the public and the environment against undue risk from radiation associated with radiological activities conducted under the control of the Department of Energy (DOE) is the purpose of DOE environmental radiation protection programs. To meet this

  3. SHOCK EMERGENCE IN SUPERNOVAE: LIMITING CASES AND ACCURATE APPROXIMATIONS

    SciTech Connect (OSTI)

    Ro, Stephen; Matzner, Christopher D.

    2013-08-10

    We examine the dynamics of accelerating normal shocks in stratified planar atmospheres, providing accurate fitting formulae for the scaling index relating shock velocity to the initial density and for the post-shock acceleration factor as functions of the polytropic and adiabatic indices which parameterize the problem. In the limit of a uniform initial atmosphere, there are analytical formulae for these quantities. In the opposite limit of a very steep density gradient, the solutions match the outcome of shock acceleration in exponential atmospheres.

  4. Checkpoint Compression: Its Limitations and Comparisons with other

    Office of Scientific and Technical Information (OSTI)

    Optimizations. (Conference) | SciTech Connect Limitations and Comparisons with other Optimizations. Citation Details In-Document Search Title: Checkpoint Compression: Its Limitations and Comparisons with other Optimizations. Abstract not provided. Authors: Ferreira, Kurt Brian ; Ibtesham, Dewan ; Arnold, Dorian Publication Date: 2013-11-01 OSTI Identifier: 1120837 Report Number(s): SAND2013-9997C 482778 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Conference Resource Relation:

  5. Checkpoint Compression: Its Limits and a Comparison with other

    Office of Scientific and Technical Information (OSTI)

    Optimizations. (Conference) | SciTech Connect Limits and a Comparison with other Optimizations. Citation Details In-Document Search Title: Checkpoint Compression: Its Limits and a Comparison with other Optimizations. Abstract not provided. Authors: Ferreira, Kurt Brian ; Ibtesham, Dewan ; Arnold, Dorian Publication Date: 2013-05-01 OSTI Identifier: 1080332 Report Number(s): SAND2013-4325C 455901 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: IEEE

  6. Representation of Limited Rights Data and Restricted Computer Software

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    REPRESENTATION OF LIMITED RIGHTS DATA AND RESTRICTED COMPUTER SOFTWARE Applicant: Funding Opportunity Announcement/Solicitation No.: (a) Any data delivered under an award resulting from this announcement is subject to the Rights in Data - General or the Rights in Data - Programs Covered Under Special Data Statutes clause (See Intellectual Property Provisions). Under these clauses, the Recipient may withhold from delivery data that qualify as limited rights data or restricted computer software.

  7. Adjustable direct current and pulsed circuit fault current limiter

    DOE Patents [OSTI]

    Boenig, Heinrich J.; Schillig, Josef B.

    2003-09-23

    A fault current limiting system for direct current circuits and for pulsed power circuit. In the circuits, a current source biases a diode that is in series with the circuits' transmission line. If fault current in a circuit exceeds current from the current source biasing the diode open, the diode will cease conducting and route the fault current through the current source and an inductor. This limits the rate of rise and the peak value of the fault current.

  8. Nationwide Limited Public Interest Waiver for LED and HVAC Units |

    Energy Savers [EERE]

    Department of Energy Limited Public Interest Waiver for LED and HVAC Units Nationwide Limited Public Interest Waiver for LED and HVAC Units PDF icon eere_nationwide_public_interest_waiver More Documents & Publications Nationwide Nonavailability Waiver: February 11, 2010 (Please note, the waiver for LED traffic signals has been withdrawn effective December 1, 2010) Nationwide Nonavailability Waiver: November 5, 2010 Amended Nationwide Nonavailability Waiver: November 5, 2010

  9. Thermal island destabilization and the Greenwald limit (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Thermal island destabilization and the Greenwald limit Citation Details In-Document Search Title: Thermal island destabilization and the Greenwald limit Magnetic reconnection is ubiquitous in the magnetosphere, the solar corona, and in toroidal fusion research discharges. In a fusion device, a magnetic island saturates at a width which produces a minimum in the magnetic energy of the configuration. At saturation, the modified current density profile, a function of the flux in

  10. Operating limit evaluation for disposal of uranium enrichment plant wastes

    SciTech Connect (OSTI)

    Lee, D.W.; Kocher, D.C.; Wang, J.C.

    1996-02-01

    A proposed solid waste landfill at Paducah Gaseous Diffusion Plant (PGDP) will accept wastes generated during normal plant operations that are considered to be non-radioactive. However, nearly all solid waste from any source or facility contains small amounts of radioactive material, due to the presence in most materials of trace quantities of such naturally occurring radionuclides as uranium and thorium. This paper describes an evaluation of operating limits, which are protective of public health and the environment, that would allow waste materials containing small amounts of radioactive material to be sent to a new solid waste landfill at PGDP. The operating limits are expressed as limits on concentrations of radionuclides in waste materials that could be sent to the landfill based on a site-specific analysis of the performance of the facility. These limits are advantageous to PGDP and DOE for several reasons. Most importantly, substantial cost savings in the management of waste is achieved. In addition, certain liabilities that could result from shipment of wastes to a commercial off-site solid waste landfill are avoided. Finally, assurance that disposal operations at the PGDP landfill are protective of public health and the environment is provided by establishing verifiable operating limits for small amounts of radioactive material; rather than relying solely on administrative controls. The operating limit determined in this study has been presented to the Commonwealth of Kentucky and accepted as a condition to be attached to the operating permit for the solid waste landfill.

  11. Toroidal midplane neutral beam armor and plasma limiter

    DOE Patents [OSTI]

    Kugel, Henry W.; Hand, Jr, Samuel W.; Ksayian, Haig

    1986-01-01

    For use in a tokamak fusion reactor having a midplane magnetic coil on the inner wall of an evacuated toriodal chamber within which a neutral beam heated, fusing plasma is magnetically confined, a neutral beam armor shield and plasma limiter is provided on the inner wall of the toroidal chamber to shield the midplane coil from neutral beam shine-thru and plasma deposition. The armor shield/plasma limiter forms a semicircular enclosure around the midplane coil with the outer surface of the armor shield/plasma limiter shaped to match, as closely as practical, the inner limiting magnetic flux surface of the toroidally confined, indented, bean-shaped plasma. The armor shield/plasma limiter includes a plurality of semicircular graphite plates each having a pair of coupled upper and lower sections with each plate positioned in intimate contact with an adjacent plate on each side thereof so as to form a closed, planar structure around the entire outer periphery of the circular midplane coil. The upper and lower plate sections are adapted for coupling to heat sensing thermocouples and to a circulating water conduit system for cooling the armor shield/plasma limiter.The inner center portion of each graphite plate is adapted to receive and enclose a section of a circular diagnostic magnetic flux loop so as to minimize the power from the plasma confinement chamber incident upon the flux loop.

  12. ARM - Instrument - ozone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ship Ronald H. Brown; AMF2 MAG M1 Browse Data Browse Plots Los Angeles, CA to Honolulu, HI - container ship Horizon Spirit; AMF2 retired MAO S1 Browse Data Browse Plots...

  13. Comparison of predicted ground-level airborne radionuclide concentrations to measured values resulting from operation of the Los Alamos Meson Physics Facility. Master's thesis

    SciTech Connect (OSTI)

    Hoak, W.V.

    1993-05-01

    A comparison study of measured and predicted downwind radionuclide concentrations from the Los Alamos Meson Physics Facility (LAMPF) was performed. The radionuclide emissions consist primarily of the radioisotopes 11C, 13N, and 150. The gases, vented to the outside environment by a stack located at the facility, potentially increase the radiation exposure at the facility boundary. Emission rate, meteorological, and radiation monitoring station data were collected between September 26, 1992 and October 3, 1992. The meteorological and emission data were input to the Clean Air Act Assessment Package-1988 (CAP88-PC) computer code. The downwind radionuclide air concentrations predicted by the code were compared to the air concentrations measured by the monitoring stations. The code was found to slightly over-predict downwind concentrations during unstable atmospheric conditions. For stable atmospheric conditions, the code was not useful for predicting downwind air concentrations. This is thought to be due to an underestimation of horizontal dispersion.

  14. Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005-2014

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Z.; Streets, D. G.; de Foy, B.; Lamsal, L. N.; Duncan, B. N.; Xing, J.

    2015-05-28

    Satellite remote sensing of tropospheric nitrogen dioxide (NO2) can provide valuable information for estimating surface nitrogen oxides (NOx) emissions. Using an exponentially-modified Gaussian (EMG) method and taking into account the effect of wind on observed NO2 distributions, we estimate three-year moving-average emissions of summertime NOx from 35 US urban areas directly from NO2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following the conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NOx emissions from each urban area by applying the EMG method to OMI data with windmore » speeds greater than 3–5 m s-1. Meanwhile, we find that OMI NO2 observations under weak-wind conditions (i.e., < 3 m s-1) are qualitatively better correlated with the surface NOx source strength in comparison to all-wind OMI maps; and therefore we use them to calculate the satellite-observed NO2 burdens of urban areas and compare with NOx emission estimates. The EMG results show that OMI-derived NOx emissions are highly correlated (R > 0.93) with weak-wind OMI NO2 burdens as well as bottom-up NOx emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous, EMG-obtained, effective NO2 lifetimes (~3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO2 chemical lifetimes. In general, isolated urban areas with NOx emission intensities greater than ~ 2 Mg h-1 produce statistically significant weak-wind signals in three-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NOx emissions over all selected US urban areas decreased by 49%, consistent with reductions of 43, 47, 49, and 44% in the total bottom-up NOx emissions, the sum of weak-wind OMI NO2 columns, the total weak-wind OMI NO2 burdens, and the averaged NO2 concentrations, respectively, reflecting the success of NOx control programs for both mobile sources and power plants. The decrease rates of these NOx-related quantities are found to be faster (i.e., -6.8 to -9.3% yr-1) before 2010 and slower (i.e., -3.4 to -4.9% yr-1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NOx emissions, the weak-wind OMI NO2 burdens, and ground-based NO2 measurements; and high correlations are found for all urban areas (median R = 0.8), particularly large ones (R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NOx emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.« less

  15. Reconstruction and Prediction of Variations of Total Ozone and Associated Variations of UV-B Solar Radiation for Subarctic Regions Based of Dendrochronologic Data

    SciTech Connect (OSTI)

    Zuev, V.V.; Bondarenko, S.L.

    2005-03-18

    Variations of dendrochronologic parameters, especially annual ring density, significantly reflect the physiological tree response to systematic variations of solar UV-B radiation, taking place on monthly and longer timescales during growing season. Such variations of UV-B radiation are totally governed by variations of total ozone (TO). Thus, in any dendrochronologic signal, especially for coniferous trees, there is also a recorded response to TO variations, characterizing variations of UV-B radiation. Because a monitoring of global TO distribution is regularly performed since 1979 using TOMS satellite instrumentation, there appears a possibility to reconstruct TO behavior in the past practically at any point of dendrochronologic monitoring network. The reconstruction is performed by the method of linear regression, based on significant correlation of annual ring density of coniferous trees and TO for coordinates of denrochronologic signal. The present report considers the Subarctic latitudes, which are characterized by considerable TO variations in the second half of twentieth century.

  16. Excess Surface Area in Bioelectrochemical Systems Causes ion Transport Limitations

    SciTech Connect (OSTI)

    Harrington, Timothy D.; Babauta, Jerome T.; Davenport, Emily K.; Renslow, Ryan S.; Beyenal, Haluk

    2015-05-01

    We investigated ion transport limitations on 3D graphite felt electrodes by growing Geobacter sulfurreducens biofilms with advection to eliminate external mass transfer limitations. We characterized ion transport limitations by: (i) showing that serially increasing NaCl concentration up to 200mM increased current linearly up to a total of þ273% vs. 0mM NaCl under advective conditions; (ii) growing the biofilm with a starting concentration of 200mM NaCl, which led to a maximum current increase of 400% vs. current generation without NaCl, and (iii) showing that un-colonized surface area remained even after steadystate current was reached. After accounting for iR effects, we confirmed that the excess surface area existed despite a non-zero overpotential. The fact that the biofilm was constrained from colonizing and producing further current under these conditions confirmed the biofilms under study here were ion transport-limited. Our work demonstrates that the use of high surface area electrodes may not increase current density when the system design allows ion transport limitations to become dominant.

  17. New Stochastic Annual Limits on Intake for Selected Radionuclides

    SciTech Connect (OSTI)

    Carbaugh, Eugene H.

    2009-08-24

    Annual limits on intake (ALI) have historically been tabulated by the International Commission on Radiological Protection (e.g., ICRP 1979, 1961) and also by the Environmental Protection Agency (EPA 1988). These compilations have been rendered obsolete by more recent ICRP dosimetry methods, and, rather than provide new ALIs, the ICRP has opted instead to provide committed dose coefficients from which an ALI can be determined by a user for a specific set of conditions. The U.S. Department of Energy historically has referenced compilations of ALIs and has defined their method of calculation in its radiation protection regulation (10 CFDR 835), but has never provided a specific compilation. Under June 2007 amendments to 10 CFR 835, ALIs can be calculated by dividing an appropriate dose limit, either 5-rem (0.05 Sv) effective dose or 50 rem (0.5 Sv) equivalent dose to an individual organ or tissue, by an appropriate committed dose coefficient. When based on effective dose, the ALI is often referred to as a stochastic annual limit on intake (SALI), and when based on the individual organ or tissue equivalent limit, it has often been called a deterministic annual limit on intake (DALI).

  18. TFCX pumped limiter and vacuum pumping system design and analysis

    SciTech Connect (OSTI)

    Haines, J.R.

    1985-04-01

    Impurity control system design and performance studies were performed in support of the Tokamak Fusion Core Experiment (TFCX) pre-conceptual design. Efforts concentrated on pumped limiter and vacuum pumping system design configuration, thermal/mechanical and erosion lifetime performance of the limiter protective surface, and helium ash removal performance. The reference limiter design forms a continuous toroidal belt at the bottom of the device and features a flat surface with a single leading edge. The vacuum pumping system features large vacuum ducts (diameter approximately 1 m) and high-speed, compound cryopumps. Analysis results indicate that the limiter/vacuum pumping system design provides adequate helium ash removal. Erosion, primarily by disruption-induced vaporization and/or melting, limits the protective surface lifetime to about one calendar year or only about 60 full-power hours of operation. In addition to evaluating impurity control system performance for nominal TFCX conditions, these studies attempt to focus on the key plasma physics and engineering design issues that should be addressed in future research and development programs.

  19. Limited-memory adaptive snapshot selection for proper orthogonal decomposition

    SciTech Connect (OSTI)

    Oxberry, Geoffrey M.; Kostova-Vassilevska, Tanya; Arrighi, Bill; Chand, Kyle

    2015-04-02

    Reduced order models are useful for accelerating simulations in many-query contexts, such as optimization, uncertainty quantification, and sensitivity analysis. However, offline training of reduced order models can have prohibitively expensive memory and floating-point operation costs in high-performance computing applications, where memory per core is limited. To overcome this limitation for proper orthogonal decomposition, we propose a novel adaptive selection method for snapshots in time that limits offline training costs by selecting snapshots according an error control mechanism similar to that found in adaptive time-stepping ordinary differential equation solvers. The error estimator used in this work is related to theory bounding the approximation error in time of proper orthogonal decomposition-based reduced order models, and memory usage is minimized by computing the singular value decomposition using a single-pass incremental algorithm. Results for a viscous Burgers’ test problem demonstrate convergence in the limit as the algorithm error tolerances go to zero; in this limit, the full order model is recovered to within discretization error. The resulting method can be used on supercomputers to generate proper orthogonal decomposition-based reduced order models, or as a subroutine within hyperreduction algorithms that require taking snapshots in time, or within greedy algorithms for sampling parameter space.

  20. SULFATE SOLUBILITY LIMIT VERIFICATION FOR DWPF SLUDGE BATCH 7A

    SciTech Connect (OSTI)

    Billings, A.

    2011-04-19

    During processing at the Defense Waste Processing Facility (DWPF), high sulfate concentrations in the feed are a concern to DWPF as it can lead to the formation of a detrimental, sulfate-rich, molten salt phase on the surface of the glass melt pool. To avoid these issues, a sulfate concentration limit was implemented into the Product Composition Control System (PCCS). Related to SB7a frit development efforts, the Savannah River National Laboratory (SRNL) assessed the viability of using the current 0.6 wt % SO{sub 4}{sup 2-} limit set for SB6 (in glass) and the possibility of increasing the SO{sub 4}{sup 2-} solubility limit in PCCS to account for anticipated sulfur concentrations, targeted waste loadings, and inclusion of secondary streams (e.g., Actinide Removal Process (ARP)) with two recommended frits (Frit 418 and Frit 702) for SB7a processing. For a nominal SB7a blend with a 63 inch SB6 heel remaining in Tank 40 (projection SB7a-63), a 0.60 wt% SO{sub 4}{sup 2-} in glass limit was determined for waste loadings of 34 wt% up to 40 wt% with Frit 418 based on crucible melts with batched chemicals. SRNL also examined the inclusion of ARP for the same blending scenario (SB7a-63-ARP) with Frit 418 and at least a 0.6 wt% SO{sub 4}{sup 2-} level, and waste loadings of 34 wt% to 40 wt% were also acceptable. When a visible yellow and/or white sulfate salt layer was visible on the surface of any cooled glass, it was assumed to have surpassed the solubility limit of SO{sub 4}{sup 2-} for that particular composition. All of the glasses fabricated at these concentrations did not exhibit a sulfate rich salt layer on the surface of the glass melt and retained the majority of the batched SO{sub 4}{sup 2-}. At higher levels of SO{sub 4}{sup 2-} 'spiked' into the projected sludge compositions over the aforementioned interval of waste loadings, with Frit 418, low viscosity sulfur layers were observed on the surface of glass melts which confirm exceeding the solubility limit. The same sludge scenarios were also tested with Frit 702 and all glasses did not exhibit sulfur layers on the surfaces of the glass melts at spiking levels up to 0.80 wt% SO{sub 4}{sup 2-}. An ultimate SO{sub 4}{sup 2-} limit was not defined with Frit 702, but if projected SO{sub 4}{sup 2-} concentrations are expected to increase with the onset of SB7a processing, a higher limit is achievable with Frit 702 than is achievable with Frit 418. Given the anticipated concentration of SO{sub 4}{sup 2-} for SB7a, a SO{sub 4}{sup 2-} limit of 0.6 wt % SO{sub 4}{sup 2-} is recommended for processing using Frit 418. Once the confirmed SB7a composition is known and should a higher limit be needed, SRNL can re-evaluate the limit based on the actual composition and provide an updated recommendation. It has been observed that higher levels of SO{sub 4}{sup 2-} in glass can be retained with compositional changes to the frit, as was demonstrated by the glasses fabricated using Frit 702. SRNL also recommends the continuation of studies to define a more 'global' sulfate concentration limit to account for future sludge batch composition uncertainties.

  1. Plasmonic trace sensing below the photon shot noise limit

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pooser, Raphael C.; Lawrie, Benjamin J.

    2015-12-09

    Plasmonic sensors are important detectors of biochemical trace compounds, but those that utilize optical readout are approaching their absolute limits of detection as defined by the Heisenberg uncertainty principle in both differential intensity and phase readout. However, the use of more general minimum uncertainty states in the form of squeezed light can push the noise floor in these sensors below the shot noise limit (SNL) in one analysis variable at the expense of another. Here, we demonstrate a quantum plasmonic sensor whose noise floor is reduced below the SNL in order to perform index of refraction measurements with sensitivities unobtainablemore » with classical plasmonic sensors. The increased signal-to-noise ratio can result in faster detection of analyte concentrations that were previously lost in the noise. As a result, these benefits are the hallmarks of a sensor exploiting quantum readout fields in order to manipulate the limits of the Heisenberg uncertainty principle.« less

  2. The fundamental downscaling limit of field effect transistors

    SciTech Connect (OSTI)

    Mamaluy, Denis Gao, Xujiao

    2015-05-11

    We predict that within next 15 years a fundamental down-scaling limit for CMOS technology and other Field-Effect Transistors (FETs) will be reached. Specifically, we show that at room temperatures all FETs, irrespective of their channel material, will start experiencing unacceptable level of thermally induced errors around 5-nm gate lengths. These findings were confirmed by performing quantum mechanical transport simulations for a variety of 6-, 5-, and 4-nm gate length Si devices, optimized to satisfy high-performance logic specifications by ITRS. Different channel materials and wafer/channel orientations have also been studied; it is found that altering channel-source-drain materials achieves only insignificant increase in switching energy, which overall cannot sufficiently delay the approaching downscaling limit. Alternative possibilities are discussed to continue the increase of logic element densities for room temperature operation below the said limit.

  3. Plasmonic trace sensing below the photon shot noise limit

    SciTech Connect (OSTI)

    Pooser, Raphael C.; Lawrie, Benjamin J.

    2015-12-09

    Plasmonic sensors are important detectors of biochemical trace compounds, but those that utilize optical readout are approaching their absolute limits of detection as defined by the Heisenberg uncertainty principle in both differential intensity and phase readout. However, the use of more general minimum uncertainty states in the form of squeezed light can push the noise floor in these sensors below the shot noise limit (SNL) in one analysis variable at the expense of another. Here, we demonstrate a quantum plasmonic sensor whose noise floor is reduced below the SNL in order to perform index of refraction measurements with sensitivities unobtainable with classical plasmonic sensors. The increased signal-to-noise ratio can result in faster detection of analyte concentrations that were previously lost in the noise. As a result, these benefits are the hallmarks of a sensor exploiting quantum readout fields in order to manipulate the limits of the Heisenberg uncertainty principle.

  4. The Ginibre evolution in the large-N limit

    SciTech Connect (OSTI)

    Tribe, Roger Zaboronski, Oleg

    2014-06-15

    We analyse statistics of the real eigenvalues of gl(N, R)-valued Brownian motion (the Ginibre evolution) in the limit of large N. In particular, we calculate the limiting two-time correlation function of spin variables associated with real eigenvalues of the Ginibre evolution. We also show how the formalism of spin variables can be used to compute the fixed time correlation functions of real eigenvalues discovered originally by Forrester and Nagao [“Eigenvalue statistics of the real Ginibre ensemble,” Phys. Rev. Lett. 99(5), 050603 (2007)] and Borodin and Sinclair [“The Ginibre ensemble of real random matrices and its scaling limits,” Commun. Math. Phys. 291(1), 177–224 (2009)].

  5. Optical limiting effects in nanostructured silicon carbide thin films

    SciTech Connect (OSTI)

    Borshch, A A; Starkov, V N; Volkov, V I; Rudenko, V I; Boyarchuk, A Yu; Semenov, A V

    2013-12-31

    We present the results of experiments on the interaction of nanosecond laser radiation at 532 and 1064 nm with nanostructured silicon carbide thin films of different polytypes. We have found the effect of optical intensity limiting at both wavelengths. The intensity of optical limiting at ? = 532 nm (I{sub cl} ? 10{sup 6} W cm{sup -2}) is shown to be an order of magnitude less than that at ? = 1064 nm (I{sub cl} ? 10{sup 7} W cm{sup -2}). We discuss the nature of the nonlinearity, leading to the optical limiting effect. We have proposed a method for determining the amount of linear and two-photon absorption in material media. (nonlinear optical phenomena)

  6. Testing of Liquid Lithium Limiters in CDX-U

    SciTech Connect (OSTI)

    R. Majeski; R. Kaita; M. Boaz; P. Efthimion; T. Gray; B. Jones; D. Hoffman; H. Kugel; J. Menard; T. Munsat; A. Post-Zwicker; V. Soukhanovskii; J. Spaleta; G. Taylor; J. Timberlake; R. Woolley; L. Zakharov; M. Finkenthal; D. Stutman; G. Antar; R. Doerner; S. Luckhardt; R. Seraydarian; R. Maingi; M. Maiorano; S. Smith; D. Rodgers

    2004-07-30

    Part of the development of liquid metals as a first wall or divertor for reactor applications must involve the investigation of plasma-liquid metal interactions in a functioning tokamak. Most of the interest in liquid-metal walls has focused on lithium. Experiments with lithium limiters have now been conducted in the Current Drive Experiment-Upgrade (CDX-U) device at the Princeton Plasma Physics Laboratory. Initial experiments used a liquid-lithium rail limiter (L3) built by the University of California at San Diego. Spectroscopic measurements showed some reduction of impurities in CDX-U plasmas with the L3, compared to discharges with a boron carbide limiter. While no reduction in recycling was observed with the L3, which had a plasma-wet area of approximately 40 cm2, subsequent experiments with a larger area fully toroidal lithium limiter demonstrated significant reductions in both recycling and in impurity levels. Two series of experiments with the toroidal limiter have now be en performed. In each series, the area of exposed, clean lithium was increased, until in the latest experiments the liquid-lithium plasma-facing area was increased to 2000 cm2. Under these conditions, the reduction in recycling required a factor of eight increase in gas fueling in order to maintain the plasma density. The loop voltage required to sustain the plasma current was reduced from 2 V to 0.5 V. This paper summarizes the technical preparations for lithium experiments and the conditioning required to prepare the lithium surface for plasma operations. The mechanical response of the liquid metal to induced currents, especially through contact with the plasma, is discussed. The effect of the lithium-filled toroidal limiter on plasma performance is also briefly described.

  7. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally measured extinction limits at different mixture conditions. To extend the study to a commercial fuel, the flame extinction limit for Birmingham natural gas (a blend of 95% methane, 5% ethane and 5% nitrogen) was experimentally determined and was found to be 3.62% fuel in the air-fuel mixture.

  8. Fault current limiter with shield and adjacent cores

    DOE Patents [OSTI]

    Darmann, Francis Anthony; Moriconi, Franco; Hodge, Eoin Patrick

    2013-10-22

    In a fault current limiter (FCL) of a saturated core type having at least one coil wound around a high permeability material, a method of suppressing the time derivative of the fault current at the zero current point includes the following step: utilizing an electromagnetic screen or shield around the AC coil to suppress the time derivative current levels during zero current conditions.

  9. The limit of strength and toughness of steel

    SciTech Connect (OSTI)

    Guo, Zhen

    2001-12-17

    The ideal structural steel combines high strength with high fracture toughness. This dissertation discusses the governing principles of strength and toughness, along with the approaches that can be used to improve these properties and the inherent limits to how strong and tough a steel can be.

  10. High voltage fault current limiter having immersed phase coils

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2014-04-22

    A fault current limiter including: a ferromagnetic circuit formed from a ferromagnetic material and including at least a first limb, and a second limb; a saturation mechanism surrounding a limb for magnetically saturating the ferromagnetic material; a phase coil wound around a second limb; a dielectric fluid surrounding the phase coil; a gaseous atmosphere surrounding the saturation mechanism.

  11. Fault current limiter and alternating current circuit breaker

    DOE Patents [OSTI]

    Boenig, Heinrich J.

    1998-01-01

    A solid-state circuit breaker and current limiter for a load served by an alternating current source having a source impedance, the solid-state circuit breaker and current limiter comprising a thyristor bridge interposed between the alternating current source and the load, the thyristor bridge having four thyristor legs and four nodes, with a first node connected to the alternating current source, and a second node connected to the load. A coil is connected from a third node to a fourth node, the coil having an impedance of a value calculated to limit the current flowing therethrough to a predetermined value. Control means are connected to the thyristor legs for limiting the alternating current flow to the load under fault conditions to a predetermined level, and for gating the thyristor bridge under fault conditions to quickly reduce alternating current flowing therethrough to zero and thereafter to maintain the thyristor bridge in an electrically open condition preventing the alternating current from flowing therethrough for a predetermined period of time.

  12. Fault current limiter and alternating current circuit breaker

    DOE Patents [OSTI]

    Boenig, H.J.

    1998-03-10

    A solid-state circuit breaker and current limiter are disclosed for a load served by an alternating current source having a source impedance, the solid-state circuit breaker and current limiter comprising a thyristor bridge interposed between the alternating current source and the load, the thyristor bridge having four thyristor legs and four nodes, with a first node connected to the alternating current source, and a second node connected to the load. A coil is connected from a third node to a fourth node, the coil having an impedance of a value calculated to limit the current flowing therethrough to a predetermined value. Control means are connected to the thyristor legs for limiting the alternating current flow to the load under fault conditions to a predetermined level, and for gating the thyristor bridge under fault conditions to quickly reduce alternating current flowing therethrough to zero and thereafter to maintain the thyristor bridge in an electrically open condition preventing the alternating current from flowing therethrough for a predetermined period of time. 9 figs.

  13. ARM: Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Yan Shi; Laura Riihimaki

    1994-01-07

    Surface Radiation Measurement Quality Control testing, including climatologically configurable limits

  14. Emissions of nitrogen oxides from US urban areas: estimation from Ozone Monitoring Instrument retrievals for 2005-2014

    SciTech Connect (OSTI)

    Lu, Z.; Streets, D. G.; de Foy, B.; Lamsal, L. N.; Duncan, B. N.; Xing, J.

    2015-05-28

    Satellite remote sensing of tropospheric nitrogen dioxide (NO2) can provide valuable information for estimating surface nitrogen oxides (NOx) emissions. Using an exponentially-modified Gaussian (EMG) method and taking into account the effect of wind on observed NO2 distributions, we estimate three-year moving-average emissions of summertime NOx from 35 US urban areas directly from NO2 retrievals of the Ozone Monitoring Instrument (OMI) during 2005–2014. Following the conclusions of previous studies that the EMG method provides robust and accurate emission estimates under strong-wind conditions, we derive top-down NOx emissions from each urban area by applying the EMG method to OMI data with wind speeds greater than 3–5 m s-1. Meanwhile, we find that OMI NO2 observations under weak-wind conditions (i.e., < 3 m s-1) are qualitatively better correlated with the surface NOx source strength in comparison to all-wind OMI maps; and therefore we use them to calculate the satellite-observed NO2 burdens of urban areas and compare with NOx emission estimates. The EMG results show that OMI-derived NOx emissions are highly correlated (R > 0.93) with weak-wind OMI NO2 burdens as well as bottom-up NOx emission estimates over 35 urban areas, implying a linear response of the OMI observations to surface emissions under weak-wind conditions. The simultaneous, EMG-obtained, effective NO2 lifetimes (~3.5 ± 1.3 h), however, are biased low in comparison to the summertime NO2 chemical lifetimes. In general, isolated urban areas with NOx emission intensities greater than ~ 2 Mg h-1 produce statistically significant weak-wind signals in three-year average OMI data. From 2005 to 2014, we estimate that total OMI-derived NOx emissions over all selected US urban areas decreased by 49%, consistent with reductions of 43, 47, 49, and 44% in the total bottom-up NOx emissions, the sum of weak-wind OMI NO2 columns, the total weak-wind OMI NO2 burdens, and the averaged NO2 concentrations, respectively, reflecting the success of NOx control programs for both mobile sources and power plants. The decrease rates of these NOx-related quantities are found to be faster (i.e., -6.8 to -9.3% yr-1) before 2010 and slower (i.e., -3.4 to -4.9% yr-1) after 2010. For individual urban areas, we calculate the R values of pair-wise trends among the OMI-derived and bottom-up NOx emissions, the weak-wind OMI NO2 burdens, and ground-based NO2 measurements; and high correlations are found for all urban areas (median R = 0.8), particularly large ones (R up to 0.97). The results of the current work indicate that using the EMG method and considering the wind effect, the OMI data allow for the estimation of NOx emissions from urban areas and the direct constraint of emission trends with reasonable accuracy.

  15. Anisotropic charged impurity-limited carrier mobility in monolayer phosphorene

    SciTech Connect (OSTI)

    Ong, Zhun-Yong; Zhang, Gang; Zhang, Yong Wei

    2014-12-07

    The room temperature carrier mobility in atomically thin 2D materials is usually far below the intrinsic limit imposed by phonon scattering as a result of scattering by remote charged impurities in its environment. We simulate the charged impurity-limited carrier mobility ? in bare and encapsulated monolayer phosphorene. We find a significant temperature dependence in the carrier mobilities (? ? T{sup ??}) that results from the temperature variability of the charge screening and varies with the crystal orientation. The anisotropy in the effective mass leads to an anisotropic carrier mobility, with the mobility in the armchair direction about one order of magnitude larger than in the zigzag direction. In particular, this mobility anisotropy is enhanced at low temperatures and high carrier densities. Under encapsulation with a high-? overlayer, the mobility increases by up to an order of magnitude although its temperature dependence and its anisotropy are reduced.

  16. Homogenization limit for a multiband effective mass model in heterostructures

    SciTech Connect (OSTI)

    Morandi, O.

    2014-06-15

    We study the homogenization limit of a multiband model that describes the quantum mechanical motion of an electron in a quasi-periodic crystal. In this approach, the distance among the atoms that constitute the material (lattice parameter) is considered a small quantity. Our model include the description of materials with variable chemical composition, intergrowth compounds, and heterostructures. We derive the effective multiband evolution system in the framework of the kp approach. We study the well posedness of the mathematical problem. We compare the effective mass model with the standard kp models for uniform and non-uniforms crystals. We show that in the limit of vanishing lattice parameter, the particle density obtained by the effective mass model, converges to the exact probability density of the particle.

  17. Global limits and interference patterns in dark matter direct detection

    SciTech Connect (OSTI)

    Catena, Riccardo; Gondolo, Paolo

    2015-08-13

    We compare the general effective theory of one-body dark matter nucleon interactions to current direct detection experiments in a global multidimensional statistical analysis. We derive exclusion limits on the 28 isoscalar and isovector coupling constants of the theory, and show that current data place interesting constraints on dark matter-nucleon interaction operators usually neglected in this context. We characterize the interference patterns that can arise in dark matter direct detection from pairs of dark matter-nucleon interaction operators, or from isoscalar and isovector components of the same operator. We find that commonly neglected destructive interference effects weaken standard direct detection exclusion limits by up to one order of magnitude in the coupling constants.

  18. Correlation and image compression for limited-bandwidth CCD.

    SciTech Connect (OSTI)

    Thompson, Douglas G.

    2005-07-01

    As radars move to Unmanned Aerial Vehicles with limited-bandwidth data downlinks, the amount of data stored and transmitted with each image becomes more significant. This document gives the results of a study to determine the effect of lossy compression in the image magnitude and phase on Coherent Change Detection (CCD). We examine 44 lossy compression types, plus lossless zlib compression, and test each compression method with over 600 CCD image pairs. We also derive theoretical predictions for the correlation for most of these compression schemes, which compare favorably with the experimental results. We recommend image transmission formats for limited-bandwidth programs having various requirements for CCD, including programs which cannot allow performance degradation and those which have stricter bandwidth requirements at the expense of CCD performance.

  19. Electromagnetic field limits set by the V-Curve.

    SciTech Connect (OSTI)

    Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Hudson, Howard Gerald

    2014-07-01

    When emitters of electromagnetic energy are operated in the vicinity of sensitive components, the electric field at the component location must be kept below a certain level in order to prevent the component from being damaged, or in the case of electro-explosive devices, initiating. The V-Curve is a convenient way to set the electric field limit because it requires minimal information about the problem configuration. In this report we will discuss the basis for the V-Curve. We also consider deviations from the original V-Curve resulting from inductive versus capacitive antennas, increases in directivity gain for long antennas, decreases in input impedance when operating in a bounded region, and mismatches dictated by transmission line losses. In addition, we consider mitigating effects resulting from limited antenna sizes.

  20. Limited Personal Use of Government Office Equipment including Information Technology

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-01-07

    The Order establishes requirements and assigns responsibilities for employees' limited personal use of Government resources (office equipment and other resources including information technology) within DOE, including NNSA. The Order is required to provide guidance on appropriate and inappropriate uses of Government resources. This Order was certified 04/23/2009 as accurate and continues to be relevant and appropriate for use by the Department. Certified 4-23-09. No cancellation.

  1. Dark matter limits froma 15 kg windowless bubble chamber

    SciTech Connect (OSTI)

    Szydagis, Matthew Mark; /Chicago U.

    2010-12-01

    The COUPP collaboration has successfully used bubble chambers, a technology previously applied only to high-energy physics experiments, as direct dark matter detectors. It has produced the world's most stringent spin-dependent WIMP limits, and increasingly competitive spin-independent limits. These limits were achieved by capitalizing on an intrinsic rejection of the gamma background that all other direct detection experiments must address through high-density shielding and empirically-determined data cuts. The history of COUPP, including its earliest prototypes and latest results, is briefly discussed in this thesis. The feasibility of a new, windowless bubble chamber concept simpler and more inexpensive in design is discussed here as well. The dark matter limits achieved with a 15 kg windowless chamber, larger than any previous COUPP chamber (2 kg, 4 kg), are presented. Evidence of the greater radiopurity of synthetic quartz compared to natural is presented using the data from this 15 kg device, the first chamber to be made from synthetic quartz. The effective reconstruction of the three-dimensional positions of bubbles in a highly distorted optical field, with ninety-degree bottom lighting similar to cloud chamber lighting, is demonstrated. Another innovation described in this thesis is the use of the sound produced by bubbles recorded by an array of piezoelectric sensors as the primary means of bubble detection. In other COUPP chambers, cameras have been used as the primary trigger. Previous work on bubble acoustic signature differentiation using piezos is built upon in order to further demonstrate the ability to discriminate between alpha- and neutron-induced events.

  2. Model Captures How Nitrogen Limitation Affects Hydrological Processes |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. DOE Office of Science (SC) Model Captures How Nitrogen Limitation Affects Hydrological Processes Biological and Environmental Research (BER) BER Home About Research Facilities Science Highlights Searchable Archive of BER Highlights External link Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC) Community Resources Contact Information Biological and Environmental Research U.S. Department of Energy SC-23/Germantown Building 1000

  3. Thermal Cooling Limits of Sbotaged Spent Fuel Pools

    SciTech Connect (OSTI)

    Dr. Thomas G. Hughes; Dr. Thomas F. Lin

    2010-09-10

    To develop the understanding and predictive measures of the post loss of water inventory hazardous conditions as a result of the natural and/or terrorist acts to the spent fuel pool of a nuclear plant. This includes the thermal cooling limits to the spent fuel assembly (before the onset of the zircaloy ignition and combustion), and the ignition, combustion, and the subsequent propagation of zircaloy fire from one fuel assembly to others

  4. Representation of Limited Rights Data and Restricted Computer Software

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 2005 Applicant Name___________________________________ Announcement Number______________________________ Representation of Limited Rights Data and Restricted Computer Software (a) Any data delivered under an award resulting from this announcement is subject to the Rights in Data - General or the Rights in Data - Programs Covered Under Special Data Statutes clause (See Intellectual Property Provisions at http://www.gc.energy.gov/financial_assistance_awards.htm). Under these clauses, the

  5. LIMIT ON THE MUON NEUTRINO MAGNETIC MOMENT AND A MEASUREMENT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LIMIT ON THE MUON NEUTRINO MAGNETIC MOMENT AND A MEASUREMENT OF THE CCPIP TO CCQE CROSS SECTION RATIO A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requirements for the degree of Doctor of Philosophy in The Department of Physics And Astronomy by Serge Ouedraogo B.S. in Physics, University of Arkansas at Little Rock, 2001 M.S., Louisiana State University, 2004 December 2008 In loving memory

  6. Combined upper limit for SM Higgs at the Tevatron

    SciTech Connect (OSTI)

    Penning, Bjorn; /Fermilab

    2009-01-01

    We combine results from CDF and D0 on direct searches for a standard model (SM) Higgs boson (H) in p{bar p} collisions at the Fermilab Tevatron at {radical}s = 1.96 TeV. Compared to the previous Higgs Tevatron combination, more data and new channels (WH {yields} {tau}{nu}b{bar b}, VH {yields} {tau}{tau}b{bar b}/jj{tau}{tau}, VH {yields} jjb{bar b}, t{bar t}H {yields} t{bar t}b{bar b}) have been added. Most previously used channels have been reanalyzed to gain sensitivity. We use the latest parton distribution functions and gg {yields} H theoretical cross sections when comparing our limits to the SM predictions. With 2.0-3.6 fb{sup -1} of data analyzed at CDF, and 0.9-4.2 fb{sup -1} at D0, the 95%C.L. upper limits on Higgs boson production are a factor of 2.5 (0.86) times the SM cross section for a Higgs boson mass of m{sub H} = 115 (165) GeV/c{sup 2}. Based on simulation, the corresponding median expected upper limits are 2.4 (1.1). The mass range excluded at 95% C.L. for a SM Higgs has been extended to 160 < m{sub H} < 170 GeV/c{sup 2}.

  7. NEW LIMITS ON GAMMA-RAY EMISSION FROM GALAXY CLUSTERS

    SciTech Connect (OSTI)

    Griffin, Rhiannon D.; Dai, Xinyu; Kochanek, Christopher S. E-mail: xdai@ou.edu

    2014-11-01

    Galaxy clusters are predicted to produce γ-rays through cosmic ray interactions and/or dark matter annihilation, potentially detectable by the Fermi Large Area Telescope (Fermi-LAT). We present a new, independent stacking analysis of Fermi-LAT photon count maps using the 78 richest nearby clusters (z < 0.12) from the Two Micron All Sky Survey cluster catalog. We obtain the lowest limit on the photon flux to date, 2.3 × 10{sup –11} photons cm{sup –2} s{sup –1} (95% confidence) per cluster in the 0.8-100 GeV band, which corresponds to a luminosity limit of 3.5 × 10{sup 44} photons s{sup –1}. We also constrain the emission limits in a range of narrower energy bands. Scaling to recent cosmic ray acceleration and γ-ray emission models, we find that cosmic rays represent a negligible contribution to the intra-cluster energy density and gas pressure.

  8. Toroidal midplane neutral beam armor and plasma limiter

    DOE Patents [OSTI]

    Kugel, H.W.; Hand, S.W. Jr.; Ksayian, H.

    1985-05-31

    This invention contemplates an armor shield/plasma limiter positioned upon the inner wall of a toroidal vacuum chamber within which is magnetically confined an energetic plasma in a tokamak nuclear fusion reactor. The armor shield/plasma limiter is thus of a general semi-toroidal shape and is comprised of a plurality of adjacent graphite plates positioned immediately adjacent to each other so as to form a continuous ring upon and around the toroidal chamber's inner wall and the reactor's midplane coil. Each plate has a generally semi-circular outer circumference and a recessed inner portion and is comprised of upper and lower half sections positioned immediately adjacent to one another along the midplane of the plate. With the upper and lower half sections thus joined, a channel or duct is provided within the midplane of the plate in which a magnetic flux loop is positioned. The magnetic flux loop is thus positioned immediately adjacent to the fusing toroidal plasma and serves as a diagnostic sensor with the armor shield/plasma limiter minimizing the amount of power from the energetic plasma as well as from the neutral particle beams heating the plasma incident upon the flux loop.

  9. Safety assessment of historical masonry churches based on pre-assigned kinematic limit analysis, FE limit and pushover analyses

    SciTech Connect (OSTI)

    Milani, Gabriele Valente, Marco

    2014-10-06

    This study presents some results of a comprehensive numerical analysis on three masonry churches damaged by the recent Emilia-Romagna (Italy) seismic events occurred in May 2012. The numerical study comprises: (a) pushover analyses conducted with a commercial code, standard nonlinear material models and two different horizontal load distributions; (b) FE kinematic limit analyses performed using a non-commercial software based on a preliminary homogenization of the masonry materials and a subsequent limit analysis with triangular elements and interfaces; (c) kinematic limit analyses conducted in agreement with the Italian code and based on the a-priori assumption of preassigned failure mechanisms, where the masonry material is considered unable to withstand tensile stresses. All models are capable of giving information on the active failure mechanism and the base shear at failure, which, if properly made non-dimensional with the weight of the structure, gives also an indication of the horizontal peak ground acceleration causing the collapse of the church. The results obtained from all three models indicate that the collapse is usually due to the activation of partial mechanisms (apse, faade, lateral walls, etc.). Moreover the horizontal peak ground acceleration associated to the collapse is largely lower than that required in that seismic zone by the Italian code for ordinary buildings. These outcomes highlight that structural upgrading interventions would be extremely beneficial for the considerable reduction of the seismic vulnerability of such kind of historical structures.

  10. Varying properties along lengths of temperature limited heaters

    SciTech Connect (OSTI)

    Vinegar, Harold J.; Xie, Xueying; Miller, David Scott; Ginestra, Jean Charles

    2011-07-26

    A system for heating a subsurface formation is described. The system includes an elongated heater in an opening in the formation. The elongated heater includes two or more portions along the length of the heater that have different power outputs. At least one portion of the elongated heater includes at least one temperature limited portion with at least one selected temperature at which the portion provides a reduced heat output. The heater is configured to provide heat to the formation with the different power outputs. The heater is configured so that the heater heats one or more portions of the formation at one or more selected heating rates.

  11. A LIMITED LIABILITY PARTNERSHIP 1050 Thomas Jefferson Street, NW

    Energy Savers [EERE]

    A LIMITED LIABILITY PARTNERSHIP 1050 Thomas Jefferson Street, NW Seventh Floor Washington, DC 20007 (202) 298-1800 Phone (202) 338-2416 Fax MEMORANDUM TO: DOE Office of General Counsel FROM: Doug Smith DATE: August 29, 2013 RE: Record of Communication Concerning Ceiling Fan and Ceiling Fan Light Kit Framework Document-Docket No. EERE-2012-BT-STD-0045 This memo provides an overview of communications made to DOE staff on the subject of possible changes to standards and test procedures for ceiling

  12. Other Contracting Authority NNSA ORGANIZATION HCA LIMIT PHONE NUMBER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Other Contracting Authority NNSA ORGANIZATION HCA LIMIT PHONE NUMBER NNSA HQ, NA-63, Deputy Director, Office of Acquisition and Supply Management Barbara H. Stearrett > $25M 202-586-7439 NNSA Service Center, Associate Director, Office of Business Services, Albuquerque, NM Donald J. Garcia < or equal to $25M 505-845-5878 Site offices do not have any HCA authority. NNSA SITE OFFICE CO NAME PHONE M&O CONTRACTOR NAME Bettis/Knolls Atomic Power Laboratory Mark Dickinson 202-781-6237 Bechtel

  13. Temporary Emergency Exposure Limits for Chemicals: Methods and Practice

    Energy Savers [EERE]

    DOE-HDBK-1046-2008 August 2008 DOE HANDBOOK TEMPORARY EMERGENCY EXPOSURE LIMITS FOR CHEMICALS: METHODS AND PRACTICE U.S. Department of Energy AREA EMER Washington, D.C. 20585 DOE-HDBK-1046-2008 ii DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. DOE-HDBK-1046-2008 iii Available on the Department of Energy Technical Standards Program Web site at http://www.hss.energy.gov/nuclearsafety/techstds/ DOE-HDBK-1046-2008 iv FOREWORD In 2005, the Office of Emergency

  14. New Limit on Time-Reversal Violation in Beta Decay

    SciTech Connect (OSTI)

    Mumm, H. P.; Chupp, T. E.; Cooper, R. L.; Coulter, K. P.; Freedman, S. J.; Fujikawa, B. K.; Garcia, A.; Jones, G. L.; Nico, J. S.; Thompson, A. K.; Trull, C. A.; Wietfeldt, F. E.; Wilkerson, J. F.

    2011-09-02

    We report the results of an improved determination of the triple correlation DP{center_dot}(p{sub e}xp{sub v}) that can be used to limit possible time-reversal invariance in the beta decay of polarized neutrons and constrain extensions to the standard model. Our result is D=[-0.96{+-}1.89(stat){+-}1.01(sys)]x10{sup -4}. The corresponding phase between g{sub A} and g{sub V} is {phi}{sub AV}=180.013 deg. {+-}0.028 deg. (68% confidence level). This result represents the most sensitive measurement of D in nuclear {beta} decay.

  15. Method and apparatus to trigger superconductors in current limiting devices

    DOE Patents [OSTI]

    Yuan, Xing; Hazelton, Drew Willard; Walker, Michael Stephen

    2004-10-26

    A method and apparatus for magnetically triggering a superconductor in a superconducting fault current limiter to transition from a superconducting state to a resistive state. The triggering is achieved by employing current-carrying trigger coil or foil on either or both the inner diameter and outer diameter of a superconductor. The current-carrying coil or foil generates a magnetic field with sufficient strength and the superconductor is disposed within essentially uniform magnetic field region. For superconductor in a tubular-configured form, an additional magnetic field can be generated by placing current-carrying wire or foil inside the tube and along the center axial line.

  16. The Penetrant System Monitoring (PSM) panel: Its use and limitations

    SciTech Connect (OSTI)

    Robinson, S.J. [Sherwin Inc., South Gate, CA (United States)

    1996-12-31

    In the last several years, the Penetrant System Monitoring (PSM) panel has been increasingly used for purposes for which it was never intended. Intended originally for use by penetrant system operators, the PSM panel is increasingly being used by material control departments and by process engineering departments. This paper`s purpose is to describe and give guidance concerning the proper use and maintenance of PSM panels. It recounts the evolution of penetrant system test panels, and compares how the different types of panels are made. It discusses the limitations of the PSM panel as used by the material control department, the process engineering department, and the production line.

  17. Special Analysis: Revision of Saltstone Vault 4 Disposal Limits (U)

    SciTech Connect (OSTI)

    Cook, J

    2005-05-26

    New disposal limits have been computed for Vault 4 of the Saltstone Disposal Facility based on several revisions to the models in the existing Performance Assessment and the Special Analysis issued in 2002. The most important changes are the use of a more rigorous groundwater flow and transport model, and consideration of radon emanation. Other revisions include refinement of the aquifer mesh to more accurately model the footprint of the vault, a new plutonium chemistry model accounting for the different transport properties of oxidation states III/IV and V/VI, use of variable infiltration rates to simulate degradation of the closure system, explicit calculation of gaseous releases and consideration of the effects of settlement and seismic activity on the vault structure. The disposal limits have been compared with the projected total inventory expected to be disposed in Vault 4. The resulting sum-of-fractions of the 1000-year disposal limits is 0.2, which indicates that the performance objectives and requirements of DOE 435.1 will not be exceeded. This SA has not altered the conceptual model (i.e., migration of radionuclides from the Saltstone waste form and Vault 4 to the environment via the processes of diffusion and advection) of the Saltstone PA (MMES 1992) nor has it altered the conclusions of the PA (i.e., disposal of the proposed waste in the SDF will meet DOE performance measures). Thus a PA revision is not required and this SA serves to update the disposal limits for Vault 4. In addition, projected doses have been calculated for comparison with the performance objectives laid out in 10 CFR 61. These doses are 0.05 mrem/year to a member of the public and 21.5 mrem/year to an inadvertent intruder in the resident scenario over a 10,000-year time-frame, which demonstrates that the 10 CFR 61 performance objectives will not be exceeded. This SA supplements the Saltstone PA and supersedes the two previous SAs (Cook et al. 2002; Cook and Kaplan 2003).

  18. Detailed balance limit of power conversion efficiency for organic photovoltaics

    SciTech Connect (OSTI)

    Seki, Kazuhiko; Furube, Akihiro; Yoshida, Yuji

    2013-12-16

    A fundamental difference between inorganic photovoltaic (IPV) and organic photovoltaic (OPV) cells is that charges are generated at the interface in OPV cells, while free charges can be generated in the bulk in IPV cells. In OPV cells, charge generation involves intrinsic energy losses to dissociate excitons at the interface between the donor and acceptor. By taking into account the energy losses, we show the theoretical limits of the power conversion efficiency set by radiative recombination of the carriers on the basis of the detailed balance relation between radiation from the cell and black-body radiation.

  19. A recipe for the construction of confidence limits

    SciTech Connect (OSTI)

    Iain A Bertram et al.

    2000-04-12

    In this note, the authors present the recipe recommended by the Search Limits Committee for the construction of confidence intervals for the use of D0 collaboration. In another note, currently in preparation, they present the rationale for this recipe, a critique of the current literature on this topic, and several examples of the use of the method. This note is intended to fill the need of the collaboration to have a reference available until the more complete note is finished. Section 2 introduces the notation used in this note, and Section 3 contains the suggested recipe.

  20. AN EXPERIMENT ON THE LIMITS OF QUANTUM ELECTRODYNAMICS HEPL-170

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tt^ \ # AN EXPERIMENT ON THE LIMITS OF QUANTUM ELECTRODYNAMICS HEPL-170 l6K/Gen-2 *'%.. W. C, Barber, Burton Rlchter, and W. Ko H. Panofsky, Stanford University, Facsimile Price $_ M i c r o f i l m Price $ A v a i l a b l e from the O f f i c e o f Technical Services Department of Commerce Washington 25, D. C. and G. K. O'Neill and B. Gittelman, Princeton University Internal Report Not to be Published June 1959 Supported by the joint program of the Office of Naval Research and the U. S. Atomic

  1. Torque limit of PM motors for field-weakening region operation

    DOE Patents [OSTI]

    Royak, Semyon; Harbaugh, Mark M.

    2012-02-14

    The invention includes a motor controller and technique for controlling a permanent magnet motor. In accordance with one aspect of the present technique, a permanent magnet motor is controlled by receiving a torque command, determining a physical torque limit based on a stator frequency, determining a theoretical torque limit based on a maximum available voltage and motor inductance ratio, and limiting the torque command to the smaller of the physical torque limit and the theoretical torque limit. Receiving the torque command may include normalizing the torque command to obtain a normalized torque command, determining the physical torque limit may include determining a normalized physical torque limit, determining a theoretical torque limit may include determining a normalized theoretical torque limit, and limiting the torque command may include limiting the normalized torque command to the smaller of the normalized physical torque limit and the normalized theoretical torque limit.

  2. Collective Effects in a Diffraction Limited Storage Ring

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nagaoka, Ryutaro; Bane, Karl L.F.

    2015-10-20

    Our paper gives an overview of collective effects that are likely to appear and possibly limit the performance in a diffraction-limited storage ring (DLSR) that stores a high-intensity ultra-low-emittance beam. Beam instabilities and other intensity-dependent effects that may significantly impact the machine performance are covered. The latter include beam-induced machine heating, Touschek scattering, intra-beam scattering, as well as incoherent tune shifts. The general trend that the efforts to achieve ultra-low emittance result in increasing the machine coupling impedance and the beam sensitivity to instability is reviewed. The nature of coupling impedance in a DLSR is described, followed by a seriesmore » of potentially dangerous beam instabilities driven by the former, such as resistive-wall, TMCI (transverse mode coupling instability), head-tail and microwave instabilities. Additionally, beam-ion and CSR (coherent synchrotron radiation) instabilities are also treated. Means to fight against collective effects such as lengthening of the bunch with passive harmonic cavities and bunch-by-bunch transverse feedback are introduced. Numerical codes developed and used to evaluate the machine coupling impedance, as well as to simulate beam instability using the former as inputs are described.« less

  3. Strain-Based Acceptance Criteria for Energy-Limited Events

    SciTech Connect (OSTI)

    Spencer D. Snow; Dana K. Morton

    2009-07-01

    The American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel (B&PV) Code was primarily written with stress-based acceptance criteria. These criteria are applicable to force, displacement, and energy-controlled loadings and ensure a factor of safety against failure. However, stress-based acceptance criteria are often quite conservative for one time energy-limited events such as accidental drops and impacts. For several years, the ASME Working Group on Design of Division 3 Containments has been developing the Design Articles for Section III, Division 3, “Containments for Transportation and Storage of Spent Nuclear Fuel and High-Level Radioactive Material and Waste,” and has wanted to establish strain-based acceptance criteria for accidental drops of containments. This Division 3 working group asked the Working Group on Design Methodology (WGDM) to assist in developing these strain-based acceptance criteria. This paper discusses the current proposed strain-based acceptance criteria, associated limitations of use, its background development, and the current status.

  4. On squeezed limits in single-field inflation. Part I

    SciTech Connect (OSTI)

    Flauger, Raphael; Green, Daniel; Porto, Rafael A. E-mail: dgreen@stanford.edu

    2013-08-01

    The n-point correlation functions in single-field inflation obey a set of consistency conditions in the exact squeezed limit which are not present in multi-field models, and thus are powerful tools to distinguish between the two. However, these consistency conditions may be violated for a finite range of scales in single-field models, for example by departures from the Bunch-Davies state. These excited states may be the consequence of interactions during inflation, or may be a remnant of the era that preceded inflation. In this paper we analyze the bispectrum, and show that in the regime of theoretical control the resulting signal in the squeezed limit remains undetectably small in all known models which continuously excite the state. We also show that the signal remains undetectably small if the initial state is related to the Bunch-Davies state by a Bogoliubov transformation and the energy density in the state is small enough so that the usual slow-roll conditions are obeyed. Bogoliubov states that lead to violations of the slow-roll conditions, as well as more general excited states, require more careful treatment and will be discussed in a separate publication.

  5. The tokamak density limit: A thermo-resistive disruption mechanism

    SciTech Connect (OSTI)

    Gates, D. A.; Brennan, D. P.; Delgado-Aparicio, L.; White, R. B.

    2015-06-15

    The behavior of magnetic islands with 3D electron temperature and the corresponding 3D resistivity effects on growth are examined for islands with near-zero net heating in the island interior. We refer to the resulting class of non-linearities as thermo-resistive effects. In particular, the effects of varying impurity mix on the previously proposed local island onset threshold [Gates and Delgado-Aparicio, Phys. Rev. Lett. 108, 165004 (2012)] are examined and shown to be consistent with the well established experimental scalings for tokamaks at the density limit. A surprisingly simple semi-analytic theory is developed which imposes the effects of heating/cooling in the island interior as well as the effects of island geometry. For the class of current profiles considered, it is found that a new term that accounts for the thermal effects of island asymmetry is required in the modified Rutherford equation. The resultant model is shown to exhibit a robust onset of a rapidly growing tearing modeconsistent with the disruption mechanism observed at the density limit in tokamaks. A fully non-linear 3D cylindrical calculation is performed that simulates the effect of net island heating/cooling by raising/suppressing the temperature in the core of the island. In both the analytic theory and the numerical simulation, the sudden threshold for rapid growth is found to be due to an interaction between three distinct thermal non-linearities which affect the island resistivity, thereby modifying the growth dynamics.

  6. Orbital ferromagnetism and the Chandrasekhar mass-limit

    SciTech Connect (OSTI)

    Akbari-Moghanjoughi, M.

    2012-05-15

    In this paper, we use quantum magnetohydrodynamic as well as magnetohydrostatic (MHS) models for a zero-temperature Fermi-Dirac plasma to show the fundamental role of Landau orbital ferromagnetism (LOFER) on the magnetohydrostatic stability of compact stars. It is revealed that the generalized flux-conserved equation of state of form B={beta}{rho}{sup 2s/3} only with conditions 0{<=}s{<=}1 and 0{<=}{beta}<{radical}(2{pi}) can lead to a stable compact stellar configuration. The distinct critical value {beta}{sub cr}={radical}(2{pi}) is shown to affect the magnetohydrostatic stability of the LOFER (s = 1) state and the magnetic field strength limit on the compact stellar configuration. Furthermore, the value of the parameter {beta} is remarked to fundamentally alter the Chandrasekhar mass-radius relation and the known mass-limit on white dwarfs when the star is in LOFER state. Current findings can help to understand the role of flux-frozen ferromagnetism and its fundamental role on hydrostatic stability of relativistically degenerate super-dense plasmas such as white dwarfs.

  7. Measurements of Martin-Puplett Interferometer Limitations using Blackbody Source

    SciTech Connect (OSTI)

    Evtushenko, Pavel E.; Klopf, John M.

    2013-06-01

    Frequency domain measurements with Martin-Puplett interferometer is one of a few techniques capable of bunch length measurements at the level of ~ 100 fs. As the bunch length becomes shorter, it is important to know and be able to measure the limitations of the instrument in terms of shortest measurable bunch length. In this paper we describe an experiment using a blackbody source with the modified Martin-Puplett interferometer that is routine- ly used for bunch length measurements at the JLab FEL, as a way to estimate the shortest, measurable bunch length. The limitation comes from high frequency cut-off of the wire-grid polarizer currently used and is estimated to be 50 fs RMS. The measurements are made with the same Golay cell detector that is used for beam measure- ments. We demonstrate that, even though the blackbody source is many orders of magnitude less bright than the coherent transition or synchrotron radiation, it can be used for the measurements and gives a very good signal to noise ratio in combination with lock-in detection. We also compare the measurements made in air and in vacuum to characterize the very strong effect of the atmospheric absorption.

  8. Superconducting fault current-limiter with variable shunt impedance

    DOE Patents [OSTI]

    Llambes, Juan Carlos H; Xiong, Xuming

    2013-11-19

    A superconducting fault current-limiter is provided, including a superconducting element configured to resistively or inductively limit a fault current, and one or more variable-impedance shunts electrically coupled in parallel with the superconducting element. The variable-impedance shunt(s) is configured to present a first impedance during a superconducting state of the superconducting element and a second impedance during a normal resistive state of the superconducting element. The superconducting element transitions from the superconducting state to the normal resistive state responsive to the fault current, and responsive thereto, the variable-impedance shunt(s) transitions from the first to the second impedance. The second impedance of the variable-impedance shunt(s) is a lower impedance than the first impedance, which facilitates current flow through the variable-impedance shunt(s) during a recovery transition of the superconducting element from the normal resistive state to the superconducting state, and thus, facilitates recovery of the superconducting element under load.

  9. On the Alignment Limit of the NMSSM Higgs Sector

    SciTech Connect (OSTI)

    Carena, Marcela; Haber, Howard E.; Low, Ian; Shah, Nausheen R.; Wagner, Carlos E. M.

    2015-10-30

    The Next-to-Minimal Supersymmetric extension of the Standard Model (NMSSM) with a Higgs boson of mass 125 GeV can be compatible with stop masses of order of the electroweak scale, thereby reducing the degree of fine-tuning necessary to achieve electroweak symmetry breaking. Moreover, in an attractive region of the NMSSM parameter space, corresponding to the \\alignment limit" in which one of the neutral Higgs fields lies approximately in the same direction in field space as the doublet Higgs vacuum expectation value, the observed Higgs boson is predicted to have Standard- Model-like properties. We derive analytical expressions for the alignment conditions and show that they point toward a more natural region of parameter space for electroweak symmetry breaking, while allowing for perturbativity of the theory up to the Planck scale. Additionally, the alignment limit in the NMSSM leads to a well defined spectrum in the Higgs and Higgsino sectors, and yields a rich and interesting Higgs boson phenomenology that can be tested at the LHC. We discuss the most promising channels for discovery and present several benchmark points for further study.

  10. Air quality implications associated with the selection of power plants in the Pacific Northwest

    SciTech Connect (OSTI)

    Baechler, M.C.; Glantz, C.S.; Edelmen, P.C.

    1993-11-01

    This assessment models emission inventories and pollutant emission rates for fossil fuel power plants. Ground-level air concentration of nitrogen oxides, sulfur dioxide and TSP are predicted. Pollutant deposition, non-acidic deposition, acidic deposition, ozone impacts, and visibility attenuation are considered. Human health effects, wildlife effects, effects on plants and crops, and residual environmental impacts are estimated from predicted emissions.

  11. Demand, Supply, and Price Outlook for Reformulated Motor Gasoline 1995

    Reports and Publications (EIA)

    1994-01-01

    Provisions of the Clean Air Act Amendments of 1990 designed to reduce ground-level ozone will increase the demand for reformulated motor gasoline in a number of U.S. metropolitan areas. This article discusses the effects of the new regulations on the motor gasoline market and the refining industry.

  12. Investigation of Knock limited Compression Ratio of Ethanol Gasoline Blends

    SciTech Connect (OSTI)

    Szybist, James P; Youngquist, Adam D; Wagner, Robert M; Moore, Wayne; Foster, Matthew; Confer, Keith

    2010-01-01

    Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock limited compression ratio of ethanol gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single cylinder direct injection spark ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT conditions to determine the knock limited compression ratio (CR) of ethanol fuel blends. The geometric compression ratio is varied by changing pistons, producing CR from 9.2 to 13.66. The effective CR is varied using an electro-hydraulic valvetrain that changed the effective trapped displacement using both Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC). The EIVC and LIVC strategies result in effective CR being reduced while maintaining the geometric expansion ratio. It was found that at substantially similar engine conditions, increasing the ethanol content of the fuel results in higher engine efficiency and higher engine power. These can be partially attributed to a charge cooling effect and a higher heating valve of a stoichiometric mixture for ethanol blends (per unit mass of air). Additional thermodynamic effects on and a mole multiplier are also explored. It was also found that high CR can increase the efficiency of ethanol fuel blends, and as a result, the fuel economy penalty associated with the lower energy content of E85 can be reduced by about a third. Such operation necessitates that the engine be operated in a de-rated manner for gasoline, which is knock-prone at these high CR, in order to maintain compatibility. By using EIVC and LIVC strategies, good efficiency is maintained with gasoline, but power is reduced by about 34%.

  13. PP-22-1 British Columbia Electric Company, Limited | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 British Columbia Electric Company, Limited PP-22-1 British Columbia Electric Company, Limited Presidential permit authorizing British Columbia Electric Company, Limited to construct, operate, and maintain electric transmission facilities at the U.S-Canadian border. PDF icon PP-22-1 British Columbia Electric Company, Limited More Documents & Publications PP-22 British Columbia Electric Company, Limited PP-22 British Columbia Electric Company, Limited, Amendment 1957 PP-22-4 British Columbia

  14. Short wavelength limits of current shot noise suppression

    SciTech Connect (OSTI)

    Nause, Ariel; Dyunin, Egor; Gover, Avraham

    2014-08-15

    Shot noise in electron beam was assumed to be one of the features beyond control of accelerator physics. Current results attained in experiments at Accelerator Test Facility in Brookhaven and Linac Coherent Light Source in Stanford suggest that the control of the shot noise in electron beam (and therefore of spontaneous radiation and Self Amplified Spontaneous Emission of Free Electron Lasers) is feasible at least in the visible range of the spectrum. Here, we present a general linear formulation for collective micro-dynamics of e-beam noise and its control. Specifically, we compare two schemes for current noise suppression: a quarter plasma wavelength drift section and a combined drift/dispersive (transverse magnetic field) section. We examine and compare their limits of applicability at short wavelengths via considerations of electron phase-spread and the related Landau damping effect.

  15. Enhanced optical limiting effects of graphene materials in polyimide

    SciTech Connect (OSTI)

    Gan, Yao; Feng, Miao; Zhan, Hongbing

    2014-04-28

    Three different graphene nanostructure suspensions of graphene oxide nanosheets (GONSs), graphene oxide nanoribbons (GONRs), and graphene oxide quantum dots (GOQDs) are prepared and characterized. Using a typical two-step method, the GONSs, GONRs, and GOQDs are incorporated into a polyimide (PI) matrix to synthesize graphene/PI composite films, whose nonlinear optical (NLO) and optical limiting (OL) properties are investigated at 532?nm in the nanosecond regime. The GONR suspension exhibits superior NLO and OL effects compared with those of GONSs and GOQDs because of its stronger nonlinear scattering and excited-state absorption. The graphene/PI composite films exhibit NLO and OL performance superior to that of their corresponding suspensions, which is attributed primarily to a combination of nonlinear mechanisms, charge transfer between graphene materials and PI, and the matrix effect.

  16. Investigation of fundamental limits to beam brightness available from photoinjectors

    SciTech Connect (OSTI)

    Bazarov, Ivan

    2015-07-09

    The goal of this project was investigation of fundamental limits to beam brightness available from photoinjectors. This basic research in accelerator physics spanned over 5 years aiming to extend the fundamental understanding of high average current, low emittance sources of relativistic electrons based on photoemission guns, a necessary prerequisite for a new generation of coherent X-ray synchrotron radiation facilities based on continuous duty superconducting linacs. The program focused on two areas critical to making advances in the electron source performance: 1) the physics of photocathodes for the production of low emittance electrons and 2) control of space charge forces in the immediate vicinity to the cathode via 3D laser pulse shaping.

  17. Possible high power limitations from RF pulsed heating

    SciTech Connect (OSTI)

    Pritzkau, D.P.; Bowden, G.B.; Menegat, A.; Siemann, R.H. [Stanford Linear Accelerator Center, Stanford University, California 94309 (United States)

    1999-05-01

    One of the possible limitations to achieving high power in RF structures is damage to metal surfaces due to RF pulsed heating. Such damage may lead to degradation of RF performance. An experiment to study RF pulsed heating on copper has been developed at SLAC. The experiment consists of operating two pillbox cavities in the TE{sub 011} mode using a 50 MW X-Band klystron. The estimated temperature rise of the surface of copper is 350&hthinsp;{degree}C for a power input of 20 MW to each cavity with a pulse length of 1.5 {mu}s. Preliminary results from an experiment performed earlier are presented. A revised design for continued experiments is also presented along with relevant theory and calculations. {copyright} {ital 1999 American Institute of Physics.}

  18. Atomic Energy of Canada Limited LIQUID DYNAMICS FROM NEUTRON SPECTROMETRY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Energy of Canada Limited LIQUID DYNAMICS FROM NEUTRON SPECTROMETRY CRNP-1121 by B.N. BRO CKHOUSE, J. BERGSMA, B.A. D A S A N N A C H A R Y A a n d N.K. POPE C h a l k River, O n t a r i o O c t o b e r , 1962 AECL-1576 DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. L E G A L N O T I C E T h i s r e p o r t h a s b e e n r e l e a s e d t o t h e U n i t e d S t a t e s A t o m i c E n e r g

  19. Current parallel I/O limitations to scalable data analysis.

    SciTech Connect (OSTI)

    Mascarenhas, Ajith Arthur; Pebay, Philippe Pierre

    2011-07-01

    This report describes the limitations to parallel scalability which we have encountered when applying our otherwise optimally scalable parallel statistical analysis tool kit to large data sets distributed across the parallel file system of the current premier DOE computational facility. This report describes our study to evaluate the effect of parallel I/O on the overall scalability of a parallel data analysis pipeline using our scalable parallel statistics tool kit [PTBM11]. In this goal, we tested it using the Jaguar-pf DOE/ORNL peta-scale platform on a large combustion simulation data under a variety of process counts and domain decompositions scenarios. In this report we have recalled the foundations of the parallel statistical analysis tool kit which we have designed and implemented, with the specific double intent of reproducing typical data analysis workflows, and achieving optimal design for scalable parallel implementations. We have briefly reviewed those earlier results and publications which allow us to conclude that we have achieved both goals. However, in this report we have further established that, when used in conjuction with a state-of-the-art parallel I/O system, as can be found on the premier DOE peta-scale platform, the scaling properties of the overall analysis pipeline comprising parallel data access routines degrade rapidly. This finding is problematic and must be addressed if peta-scale data analysis is to be made scalable, or even possible. In order to attempt to address these parallel I/O limitations, we will investigate the use the Adaptable IO System (ADIOS) [LZL+10] to improve I/O performance, while maintaining flexibility for a variety of IO options, such MPI IO, POSIX IO. This system is developed at ORNL and other collaborating institutions, and is being tested extensively on Jaguar-pf. Simulation code being developed on these systems will also use ADIOS to output the data thereby making it easier for other systems, such as ours, to process that data.

  20. Wind Power Plant Enhancement with a Fault-Current Limiter: Preprint

    SciTech Connect (OSTI)

    Muljadi, E.; Gevorgian, V.; DeLaRosa, F.

    2011-03-01

    This paper investigates the capability of a saturable core fault-current limiter to limit the short circuit current of different types of wind turbine generators.

  1. Preliminary upper limit on BR(D{sup {+-}}{r_arrow}{pi}{sup {...

    Office of Scientific and Technical Information (OSTI)

    Preliminary upper limit on BR(Dsup +-rarrowpisup +-musup +musup -) Citation Details In-Document Search Title: Preliminary upper limit on BR(Dsup ...

  2. Survey Date Agent CAS Limit Type TWA/STEL/Excur % OEL OEL Air...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Survey Date Agent CAS Limit Type TWASTELExcur % OEL OEL Air Conc Farm Specific Location ... Survey Date Agent CAS Limit Type TWASTELExcur % OEL OEL Air Conc Farm Specific Location ...

  3. Peak Dose Assessment for Proposed DOE-PPPO Authorized Limits

    SciTech Connect (OSTI)

    Maldonado, Delis

    2012-06-01

    The Oak Ridge Institute for Science and Education (ORISE), a U.S. Department of Energy (DOE) prime contractor, was contracted by the DOE Portsmouth/Paducah Project Office (DOE-PPPO) to conduct a peak dose assessment in support of the Authorized Limits Request for Solid Waste Disposal at Landfill C-746-U at the Paducah Gaseous Diffusion Plant (DOE-PPPO 2011a). The peak doses were calculated based on the DOE-PPPO Proposed Single Radionuclides Soil Guidelines and the DOE-PPPO Proposed Authorized Limits (AL) Volumetric Concentrations available in DOE-PPPO 2011a. This work is provided as an appendix to the Dose Modeling Evaluations and Technical Support Document for the Authorized Limits Request for the C-746-U Landfill at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky (ORISE 2012). The receptors evaluated in ORISE 2012 were selected by the DOE-PPPO for the additional peak dose evaluations. These receptors included a Landfill Worker, Trespasser, Resident Farmer (onsite), Resident Gardener, Recreational User, Outdoor Worker and an Offsite Resident Farmer. The RESRAD (Version 6.5) and RESRAD-OFFSITE (Version 2.5) computer codes were used for the peak dose assessments. Deterministic peak dose assessments were performed for all the receptors and a probabilistic dose assessment was performed only for the Offsite Resident Farmer at the request of the DOE-PPPO. In a deterministic analysis, a single input value results in a single output value. In other words, a deterministic analysis uses single parameter values for every variable in the code. By contrast, a probabilistic approach assigns parameter ranges to certain variables, and the code randomly selects the values for each variable from the parameter range each time it calculates the dose (NRC 2006). The receptor scenarios, computer codes and parameter input files were previously used in ORISE 2012. A few modifications were made to the parameter input files as appropriate for this effort. Some of these changes included increasing the time horizon beyond 1,050 years (yr), and using the radionuclide concentrations provided by the DOE-PPPO as inputs into the codes. The deterministic peak doses were evaluated within time horizons of 70 yr (for the Landfill Worker and Trespasser), 1,050 yr, 10,000 yr and 100,000 yr (for the Resident Farmer [onsite], Resident Gardener, Recreational User, Outdoor Worker and Offsite Resident Farmer) at the request of the DOE-PPPO. The time horizons of 10,000 yr and 100,000 yr were used at the request of the DOE-PPPO for informational purposes only. The probabilistic peak of the mean dose assessment was performed for the Offsite Resident Farmer using Technetium-99 (Tc-99) and a time horizon of 1,050 yr. The results of the deterministic analyses indicate that among all receptors and time horizons evaluated, the highest projected dose, 2,700 mrem/yr, occurred for the Resident Farmer (onsite) at 12,773 yr. The exposure pathways contributing to the peak dose are ingestion of plants, external gamma, and ingestion of milk, meat and soil. However, this receptor is considered an implausible receptor. The only receptors considered plausible are the Landfill Worker, Recreational User, Outdoor Worker and the Offsite Resident Farmer. The maximum projected dose among the plausible receptors is 220 mrem/yr for the Outdoor Worker and it occurs at 19,045 yr. The exposure pathways contributing to the dose for this receptor are external gamma and soil ingestion. The results of the probabilistic peak of the mean dose analysis for the Offsite Resident Farmer indicate that the average (arithmetic mean) of the peak of the mean doses for this receptor is 0.98 mrem/yr and it occurs at 1,050 yr. This dose corresponds to Tc-99 within the time horizon of 1,050 yr.

  4. Connecting apparatus for limited rotary of rectilinear motion (II)

    DOE Patents [OSTI]

    Hardin, Jr., Roy T.; Kurinko, Carl D.

    1981-01-01

    Apparatus for providing connection between two members having relative movement in a horizontal plane in a rotary or linear fashion. The apparatus includes a set of vertical surfaces affixed to each of the members, laterally aligned across a selected vertical gap. A number of cables or hoses, for electrical, hydraulic, or pneumatic connection are arranged between consecutive surfaces in a C-shaped traveling loop, connected through their end portions to the two respective members, so that through a sliding motion portions of the cable are transferred from between one set of surfaces to the other aligned set, across the gap, upon relative motion of the members. A number of flexible devices are affixed to the upper set of surfaces for supporting the upper portion of each looped cable. The apparatus is particularly adaptable to an area having limited lateral clearances and requiring signal level separation between electrical cables, such as found in the rotating plugs and associated equipment of the reactor vessel head of a nuclear reactor.

  5. Tritium handling experience at Atomic Energy of Canada Limited

    SciTech Connect (OSTI)

    Suppiah, S.; McCrimmon, K.; Lalonde, S.; Ryland, D.; Boniface, H.; Muirhead, C.; Castillo, I.

    2015-03-15

    Canada has been a leader in tritium handling technologies as a result of the successful CANDU reactor technology used for power production. Over the last 50 to 60 years, capabilities have been established in tritium handling and tritium management in CANDU stations, tritium removal processes for heavy and light water, tritium measurement and monitoring, and understanding the effects of tritium on the environment. This paper outlines details of tritium-related work currently being carried out at Atomic Energy of Canada Limited (AECL). It concerns the CECE (Combined Electrolysis and Catalytic Exchange) process for detritiation, tritium-compatible electrolysers, tritium permeation studies, and tritium powered batteries. It is worth noting that AECL offers a Tritium Safe-Handling Course to national and international participants, the course is a mixture of classroom sessions and hands-on practical exercises. The expertise and facilities available at AECL is ready to address technological needs of nuclear fusion and next-generation nuclear fission reactors related to tritium handling and related issues.

  6. Innovative Feed-In Tariff Designs that Limit Policy Costs

    SciTech Connect (OSTI)

    Kreycik, C.; Couture, T. D.; Cory, K. S.

    2011-06-01

    Feed-in tariffs (FITs) are the most prevalent renewable energy policy used globally to date, and there are many benefits to the certainty offered in the marketplace to reduce development risks and associated financing costs and to grow the renewable energy industry. However, concerns over escalating costs in jurisdictions with FIT policies have led to increased attention on cost control in renewable energy policy design. In recent years, policy mechanisms for containing FIT costs have become more refined, allowing policymakers to exert greater control on policy outcomes and on the resulting costs to ratepayers. As policymakers and regulators in the United States begin to explore the use of FITs, careful consideration must be given to the ways in which policy design can be used to balance the policies' advantages while bounding its costs. This report explores mechanisms that policymakers have implemented to limit FIT policy costs. If designed clearly and transparently, such mechanisms can align policymaker and market expectations for project deployment. Three different policy tools are evaluated: (1) caps, (2) payment level adjustment mechanisms, and (3) auction-based designs. The report employs case studies to explore the strengths and weaknesses of these three cost containment tools. These tools are then evaluated with a set of criteria including predictability for policymakers and the marketplace and the potential for unintended consequences.

  7. Beyond the Brillouin limit with the Penning fusion experiment

    SciTech Connect (OSTI)

    Barnes, D.C.; Mitchell, T.B.; Schauer, M.M.

    1996-11-09

    Several years ago, it was proposed that a dense nonneutral plasma could be produced in a Penning trap. Nonneutral plasmas have excellent confinement. Thus, such a dense plasma might produce simultaneously high density and good confinement (as needed for fusion). Recently, this theoretical conjecture has been demonstrated in a small (3 mm radius) electron experiment (PFX). Densities up to 35 times the Brillouin density (limiting number density in a static trap) have been inferred from the observed strong (100:1) spherical focussing. Electrons are injected at low energy from a single pole of the sphere. A surprising observation is the self-organization of the system into a spherical state, which occurs precisely when the trap parameters are adjusted to produce a spherical well. This organization is observed by a bootstrapping which produces a hysteresis. Additional observations which confirm the dense spherical focus are energy-scattered electrons and deflections of an electron probe beam by the space charge of the central focus.

  8. Fireproof impact limiter aggregate packaging inside shipping containers

    DOE Patents [OSTI]

    Byington, Gerald A.; Oakes, Jr., Raymon Edgar; Feldman, Matthew Rookes

    2001-01-01

    The invention is a product and a process for making a fireproof, impact limiter, homogeneous aggregate material for casting inside a hazardous material shipping container, or a double-contained Type-B nuclear shipping container. The homogeneous aggregate material is prepared by mixing inorganic compounds with water, pouring the mixture into the void spaces between an inner storage containment vessel and an outer shipping container, vibrating the mixture inside the shipping container, with subsequent curing, baking, and cooling of the mixture to form a solidified material which encapsulates an inner storage containment vessel inside an outer shipping container. The solidified material forms a protective enclosure around an inner storage containment vessel which may store hazardous, toxic, or radioactive material. The solidified material forms a homogeneous fire-resistant material that does not readily transfer heat, and provides general shock and specific point-impact protection, providing protection to the interior storage containment vessel. The material is low cost, may contain neutron absorbing compounds, and is easily formed into a variety of shapes to fill the interior void spaces of shipping containers.

  9. Message passing with a limited number of DMA byte counters

    DOE Patents [OSTI]

    Blocksome, Michael; Chen, Dong; Giampapa, Mark E.; Heidelberger, Philip; Kumar, Sameer; Parker, Jeffrey J.

    2011-10-04

    A method for passing messages in a parallel computer system constructed as a plurality of compute nodes interconnected as a network where each compute node includes a DMA engine but includes only a limited number of byte counters for tracking a number of bytes that are sent or received by the DMA engine, where the byte counters may be used in shared counter or exclusive counter modes of operation. The method includes using rendezvous protocol, a source compute node deterministically sending a request to send (RTS) message with a single RTS descriptor using an exclusive injection counter to track both the RTS message and message data to be sent in association with the RTS message, to a destination compute node such that the RTS descriptor indicates to the destination compute node that the message data will be adaptively routed to the destination node. Using one DMA FIFO at the source compute node, the RTS descriptors are maintained for rendezvous messages destined for the destination compute node to ensure proper message data ordering thereat. Using a reception counter at a DMA engine, the destination compute node tracks reception of the RTS and associated message data and sends a clear to send (CTS) message to the source node in a rendezvous protocol form of a remote get to accept the RTS message and message data and processing the remote get (CTS) by the source compute node DMA engine to provide the message data to be sent.

  10. Performance limits of plasmon-enhanced organic photovoltaics

    SciTech Connect (OSTI)

    Karatay, Durmus U.; Ginger, David S.; Salvador, Michael; Yao, Kai; Jen, Alex K.-Y.

    2014-07-21

    We use a combination of experiment and modeling to explore the promise and limitations of using plasmon-resonant metal nanoparticles to enhance the device performance of organic photovoltaics (OPVs). We focus on optical properties typical of the current generation of low-bandgap donor polymers blended with the fullerene (6,6)-phenyl C{sub 71}-butyric acid methyl ester (PC{sub 71}BM) and use the polymer poly(indacenodithiophene-co-phenanthro[9,10-b]quinoxaline) (PIDT-PhanQ) as our test case. We model the optical properties and performance of these devices both in the presence and absence of a variety of colloidal silver nanoparticles. We show that for these materials, device performance is sensitive to the relative z-position and the density of nanoparticles inside the active layer. Using conservative estimates of the internal quantum efficiency for the PIDT-PhanQ/PC{sub 71}BM blend, we calculate that optimally placed silver nanoparticles could yield an enhancement in short-circuit current density of over 31% when used with???80-nm-thick active layers, resulting in an absolute increase in power conversion efficiency of up to ?2% for the device based on optical engineering.

  11. First wall and limiter surfaces for plasma devices

    DOE Patents [OSTI]

    Krauss, Alan R.; Gruen, Dieter M.

    1983-01-01

    For a plasma device, a surface of a first wall or limiter with reduced loss of metal by erosion is provided by forming a monolayer of an alkali or alkaline earth metal on a substrate of a more negative metal. The surface exhibits a reduced loss of metal by erosion and particularly by sputtering and an increased secondary ion/neutral ratio resulting in a greater return of atoms escaping from the surface. In another aspect of the invention, the substrate includes a portion of the second metal and serves to replenish the surface layer with atoms of the second metal. In one process associated with self-generating desired surface, the metals as an alloy are selected to provide a first layer having a high concentration of the second metal in contrast to a very low concentration in the second layer and bulk to result in a surface with a monolayer of the second metal. When the combination of metals results in an intermetallic compound, selective removal of the first metal during an initial bombardment stage provides the surface layer with a predominance of the second metal.

  12. Spatially Resolved Estimation of Ozone-related Mortality in the United States under Two Representative Concentration Pathways (RCPs) and their Uncertainty

    SciTech Connect (OSTI)

    Kim, Young-Min; Zhou, Ying; Gao, Yang; Fu, Joshua S.; Johnson, Brent; Huang, Cheng; Liu, Yang

    2015-01-01

    BACKGROUND: The spatial pattern of the uncertainty in climate air pollution health impact has rarely been studied due to the lack of high-resolution model simulations, especially under the latest Representative Concentration Pathways (RCPs). OBJECTIVES: We estimated county-level ozone (O3) and PM2.5 related excess mortality (EM) and evaluated the associated uncertainties in the continental United States in the 2050s under RCP4.5 and RCP8.5. METHODS: Using dynamically downscaled climate model simulations, we calculated changes in O3 and PM2.5 levels at 12 km resolution between the future (2057-2059) and present (2001-2004) under two RCP scenarios. Using concentration-response relationships in the literature and projected future populations, we estimated EM attributable to the changes in O3 and PM2.5. We finally analyzed the contribution of input variables to the uncertainty in the county-level EM estimation using Monte Carlo simulation. RESULTS: O3-related premature deaths in the continental U.S. were estimated to be 1,082 deaths/year under RCP8.5 (95% confidence interval (CI): -288 to 2,453), and -5,229 deaths/year under RCP4.5 (-7,212 to -3,246). Simulated PM2.5 changes resulted in a significant decrease in EM under the two RCPs. The uncertainty of O3-related EM estimates was mainly caused by RCP scenarios, whereas that of PM2.5-related EMs was mainly from concentration-response functions. CONCLUSION: EM estimates attributable to climate change-induced air pollution change as well as the associated uncertainties vary substantially in space, and so are the most influential input variables. Spatially resolved data is crucial to develop effective mitigation and adaptation policy.

  13. Development of Occupational Exposure Limits for the Hanford Tank Farms

    SciTech Connect (OSTI)

    Still, Kenneth; Gardner, Donald; Snyder, Robert; Anderson, Thomas; Honeyman, James; Timchalk, Charles

    2010-04-01

    Production of plutonium for the United States nuclear weapons program from the 1940s to the 1980s generated 53 million gallons of radioactive chemical waste, which is storedin 177 underground tanks at the Hanford Site in southeastern W 18 ashington State. Recent 19 attempts to begin the retrieval and treatment of these wastes require moving the waste to 20 more modern tanks results in potential exposure of the workers to unfamiliar odors 21 emanating from headspace in the tanks. Given the unknown risks involved, workers 22 were placed on supplied air respiratory protection. CH2M HILL, the managers of the 23 Hanford Site Tank Farms, asked an Independent Toxicology Panel (ITP) to assist them in issues relating to an Industrial Hygiene and risk assessment problem. The ITP was called upon to help determine the risk of exposure to vapors from the tanks, and in general develop a strategy for solution of the problem. This paper presents the methods used to determine the chemicals of potential concern (COPC) and the resultant development of screening values and Acceptable Occupational Exposure Limits (AOELs) for these COPCs. A total of 1,826 chemicals were inventoried and evaluated. Over 1,500 chemicals were identified in the waste tanks headspaces and more than 600 of these were assigned screening values; 72 of these compounds were recommended for AOEL development. Included in this list of 72 were 57 COPCs identified by the ITP and of these 47 were subsequently assigned AOELs. An exhaustive exposure assessment strategy was developed by the CH2M HILL industrial hygiene department to evaluate these COPCs.

  14. An efficient extrapolation to the (T)/CBS limit

    SciTech Connect (OSTI)

    Ranasinghe, Duminda S.; Barnes, Ericka C.

    2014-05-14

    We extrapolate to the perturbative triples (T)/complete basis set (CBS) limit using double ? basis sets without polarization functions (Wesleyan-1-Triples-2? or Wes1T-2Z) and triple ? basis sets with a single level of polarization functions (Wesleyan-1-Triples-3? or Wes1T-3Z). These basis sets were optimized for 102 species representing the first two rows of the Periodic Table. The species include the entire set of neutral atoms, positive and negative atomic ions, as well as several homonuclear diatomic molecules, hydrides, rare gas dimers, polar molecules, such as oxides and fluorides, and a few transition states. The extrapolated Wes1T-(2,3)Z triples energies agree with (T)/CBS benchmarks to within 0.65 mE{sub h}, while the rms deviations of comparable model chemistries W1, CBS-APNO, and CBS-QB3 for the same test set are 0.23 mE{sub h}, 2.37 mE{sub h}, and 5.80 mE{sub h}, respectively. The Wes1T-(2,3)Z triples calculation time for the largest hydrocarbon in the G2/97 test set, C{sub 6}H{sub 5}Me{sup +}, is reduced by a factor of 25 when compared to W1. The cost-effectiveness of the Wes1T-(2,3)Z extrapolation validates the usefulness of the Wes1T-2Z and Wes1T-3Z basis sets which are now available for a more efficient extrapolation of the (T) component of any composite model chemistry.

  15. Limitations of the planning organ at risk volume (PRV) concept

    SciTech Connect (OSTI)

    Stroom, Joep C. [Netherlands Cancer Institute, Department of Radiation Oncology, Amsterdam (Netherlands)]. E-mail: j.stroom@nki.nl; Heijmen, Ben J.M. [Erasmus MC-Daniel den Hoed Cancer Center, Department of Radiation Oncology, Rotterdam (Netherlands)

    2006-09-01

    Purpose: Previously, we determined a planning target volume (PTV) margin recipe for geometrical errors in radiotherapy equal to M{sub T} = 2{sigma} + 0.7{sigma}, with {sigma} and {sigma} standard deviations describing systematic and random errors, respectively. In this paper, we investigated margins for organs at risk (OAR), yielding the so-called planning organ at risk volume (PRV). Methods and Materials: For critical organs with a maximum dose (D{sub max}) constraint, we calculated margins such that D{sub max} in the PRV is equal to the motion averaged D{sub max} in the (moving) clinical target volume (CTV). We studied margins for the spinal cord in 10 head-and-neck cases and 10 lung cases, each with two different clinical plans. For critical organs with a dose-volume constraint, we also investigated whether a margin recipe was feasible. Results: For the 20 spinal cords considered, the average margin recipe found was: M{sub R} = 1.6{sigma} + 0.2{sigma} with variations for systematic and random errors of 1.2{sigma} to 1.8{sigma} and -0.2{sigma} to 0.6{sigma}, respectively. The variations were due to differences in shape and position of the dose distributions with respect to the cords. The recipe also depended significantly on the volume definition of D{sub max}. For critical organs with a dose-volume constraint, the PRV concept appears even less useful because a margin around, e.g., the rectum changes the volume in such a manner that dose-volume constraints stop making sense. Conclusion: The concept of PRV for planning of radiotherapy is of limited use. Therefore, alternative ways should be developed to include geometric uncertainties of OARs in radiotherapy planning.

  16. Measuring the Interestingness of Articles in a Limited User Environment

    SciTech Connect (OSTI)

    Pon, R K

    2008-10-06

    Search engines, such as Google, assign scores to news articles based on their relevancy to a query. However, not all relevant articles for the query may be interesting to a user. For example, if the article is old or yields little new information, the article would be uninteresting. Relevancy scores do not take into account what makes an article interesting, which varies from user to user. Although methods such as collaborative filtering have been shown to be effective in recommendation systems, in a limited user environment, there are not enough users that would make collaborative filtering effective. A general framework, called iScore, is presented for defining and measuring the 'interestingness' of articles, incorporating user-feedback. iScore addresses various aspects of what makes an article interesting, such as topic relevancy, uniqueness, freshness, source reputation, and writing style. It employs various methods to measure these features and uses a classifier operating on these features to recommend articles. The basic iScore configuration is shown to improve recommendation results by as much as 20%. In addition to the basic iScore features, additional features are presented to address the deficiencies of existing feature extractors, such as one that tracks multiple topics, called MTT, and a version of the Rocchio algorithm that learns its parameters online as it processes documents, called eRocchio. The inclusion of both MTT and eRocchio into iScore is shown to improve iScore recommendation results by as much as 3.1% and 5.6%, respectively. Additionally, in TREC11 Adaptive Filter Task, eRocchio is shown to be 10% better than the best filter in the last run of the task. In addition to these two major topic relevancy measures, other features are also introduced that employ language models, phrases, clustering, and changes in topics to improve recommendation results. These additional features are shown to improve recommendation results by iScore by up to 14%. Due to varying reasons that users hold regarding why an article is interesting, an online feature selection method in naive Bayes is also introduced. Online feature selection can improve recommendation results in iScore by up to 18.9%. In summary, iScore in its best configuration can outperform traditional IR techniques by as much as 50.7%. iScore and its components are evaluated in the news recommendation task using three datasets from Yahoo! News, actual users, and Digg. iScore and its components are also evaluated in the TREC Adaptive Filter task using the Reuters RCV1 corpus.

  17. Electron-limiting defect complex in hyperdoped GaAs: The D D...

    Office of Scientific and Technical Information (OSTI)

    Electron-limiting defect complex in hyperdoped GaAs: The D D X center Prev Next Title: Electron-limiting defect complex in hyperdoped GaAs: The D D X center Authors: Ma, Jie ...

  18. PP-85-2 Boliden Westmin (Canada) Limited | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Westmin (Canada) Limited to construct, operate and maintain electric transmission facilities at the U.S. - Canada Border. PDF icon PP-85-2 Boliden Westmin (Canada) Limited More ...

  19. Henan Mingdu Wind Power Co Ltd aka He Nan Ming Du Feng Dian Limited...

    Open Energy Info (EERE)

    Mingdu Wind Power Co Ltd aka He Nan Ming Du Feng Dian Limited Company Jump to: navigation, search Name: Henan Mingdu Wind Power Co Ltd (aka He Nan Ming Du Feng Dian Limited...

  20. Flow reversal power limit for the HFBR (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Flow reversal power limit for the HFBR Citation Details In-Document Search Title: Flow reversal power limit for the HFBR You are accessing a document from the Department of ...