Sample records for grinding steel coke

  1. Specific grinding energy causing thermal damage in precision gear steels

    E-Print Network [OSTI]

    Hatathodi, Srinivas

    2002-01-01T23:59:59.000Z

    of thermal damage for surface grinding of AISI 9310 gear steel using two different grinding wheels and two different coolants. The grinding wheels used for this research are plain alumina wheel-32A80-JVBE and Seeded Gel alumina abrasive-5SG80-JVS...

  2. Specific grinding energy causing thermal damage in helicopter gear steels

    E-Print Network [OSTI]

    Purushothaman, Ganesh Kumaran

    2001-01-01T23:59:59.000Z

    of dynamometer in between machine table and magnetic chuck . . . . . . I 3 . . . 18 . 22 24 Fig 3. 4 Tangential force graph as recorded in the PC using Labtech sol'tware. . . . . , . . . . . . . . 25 Fig . 3. 5. Normal I'orce graph as recorded in the PC.... The spindle speed was held constant throughout the test conditions. The force data was obtained during the grinding process by means of an AMTI force dynamometer. 3. 2 Specimen Preparation Three steel materials v ere investigated. They are AISI 9310, X53...

  3. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  4. Analytical input-output and supply chain study of China's coke and steel sectors

    E-Print Network [OSTI]

    Li, Yu, 1976-

    2004-01-01T23:59:59.000Z

    I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

  5. Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH

    SciTech Connect (OSTI)

    Boak, S.C.; Prucha, D.G.; Turic, H.L.

    1981-01-01T23:59:59.000Z

    Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

  6. Bethlehem Steel announces plans to control coke oven air and water pollution

    SciTech Connect (OSTI)

    Not Available

    1989-08-01T23:59:59.000Z

    Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

  7. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01T23:59:59.000Z

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  8. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J. [Magnitogorsk Integrated Iron and Steel Works, (Russian Federation); Gross, M. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  9. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

    1995-12-01T23:59:59.000Z

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  10. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect (OSTI)

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

    1996-02-01T23:59:59.000Z

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  11. Final environmental information volume for the coke oven gas cleaning project at the Bethlehem Steel Corporation Sparrows Point Plant

    SciTech Connect (OSTI)

    Not Available

    1990-04-24T23:59:59.000Z

    Bethelehem Steel Corporation (BSC) is planning to conduct a demonstration project involving an integrated system that can be retrofitted into coke oven gas handling systems to address a variety of environmental and operational factors in a more cost-effective manner. Successful application of this technology to existing US coke plants could: (1) reduce emissions of sulfur dioxide, cyanide, and volatile organic compounds (including benzene) (2) reduce the cost and handling of processing feed chemicals, (3) disposal costs of nuisance by-products and (4) increase reliability and reduce operation/maintenance requirements for coke oven gas desulfurization systems. The proposed system will remove sulfur from the coke oven gas in the form of hydrogen sulfide using the ammonia indigenous to the gas as the primary reactive chemical. Ammonia and hydrogen cyanide are also removed in this process. The hydrogen sulfide removed from the coke oven gas in routed to a modified Claus plant for conversion to a saleable sulfur by-product. Ammonia and hydrogen cyanide will be catalytically converted to hydrogen, nitrogen, carbon dioxide, and carbon monoxide. The tail gas from the sulfur recovery unit is recycled to the coke oven gas stream, upstream of the new gas cleaning system. The proposed demonstration project will be installed at the existing coke oven facilities at BSC's Sparrows Point Plant. This volume describes the proposed actions and the resulting environmental impacts. 21 refs., 19 figs., 9 tabs.

  12. Experience and results of new heating control system of coke oven batteries at Rautaruukki Oy Raahe Steel

    SciTech Connect (OSTI)

    Swanljung, J.; Palmu, P. [Rautaruukki Oy Raahe Steel (Finland)

    1997-12-31T23:59:59.000Z

    The latest development and results of the heating control system at Raahe Steel are presented in this paper. From the beginning of coke production in Rautaruukki Oy Raahe Steel (October 1987) the heating control systems have been developed. During the first stage of development work at the coking plant (from year 1987 to 1992), when only the first coke oven battery consisting of 35 ovens was in production, the main progress was in the field of process monitoring. After commissioning of the second stage of the coking plant (November 1992), the development of the new heating control model was started. Target of the project was to develop a dynamic control system which guides the heating of batteries through the various process conditions. Development work took three years and the heating control system was commissioned in the year 1995. Principle of the second generation system is an energy balance calculation, coke end temperature determination and dynamic oven scheduling system. The control is based on simultaneous feedforward and feedback control. The fuzzy logic components were added after about one year experience.

  13. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  14. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31T23:59:59.000Z

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  15. Greenhouse Gas Mitigation Options in ISEEM Global Energy Model: 2010-2050 Scenario Analysis for Least-Cost Carbon Reduction in Iron and Steel Sector

    E-Print Network [OSTI]

    Karali, Nihan

    2014-01-01T23:59:59.000Z

    2011. The World Coke & Coking Coal Markets, Global Steel2010. India's Domestic Coking Coal Scenario. New WorldSTEELEASE, 2011. China Coking Coal and Coke Weekly Monitor,

  16. Thermal Effects in Vibration Assisted Grinding

    E-Print Network [OSTI]

    Endres. William J.

    'l 4140 mild steel Hardness : RC19 25.4 x 10.2 x 10 mm Grinding wheel Carborundum 32AR46-JV40 178 mm dia

  17. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31T23:59:59.000Z

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  18. Grinding away

    SciTech Connect (OSTI)

    Korz, T. [Loesche, Duesseldorf (Germany)

    2009-03-15T23:59:59.000Z

    Coal preparation in gasification plants is all too often neglected. The coal gasification industry has experienced enormous growth over the last few years and consequently the demand of coal grinding and drying has also increased. The design and development of coal mills has taken great strides since the first coal grinding plant was delivered to an IGCC power plant in Buggenum, Netherlands. The article describes a typical flow sheet for a coal gasification plant with a possibility of feeding the mill with different types of materials besides coal. 5 figs.

  19. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16T23:59:59.000Z

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  20. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  1. Grinding Wheel System

    DOE Patents [OSTI]

    Malkin, Stephen (Amherst, MA); Gao, Robert (Amherst, MA); Guo, Changsheng (South Windsor, CT); Varghese, Biju (Worthington, OH); Pathare, Sumukh (Waltham, MA)

    2003-08-05T23:59:59.000Z

    A grinding wheel system includes a grinding wheel with at least one embedded sensor. The system also includes an adapter disk containing electronics that process signals produced by each embedded sensor and that transmits sensor information to a data processing platform for further processing of the transmitted information.

  2. Grinding Wheel System

    DOE Patents [OSTI]

    Malkin, Stephen (Amherst, MA); Gao, Robert (Amherst, MA); Guo, Changsheng (South Windsor, CT); Varghese, Biju (Worthington, OH); Pathare, Sumukh (Waltham, MA)

    2006-01-10T23:59:59.000Z

    A grinding wheel system includes a grinding wheel with at least one embedded sensor. The system also includes an adapter disk containing electronics that process signals produced by each embedded sensor and that transmits sensor information to a data processing platform for further processing of the transmitted information.

  3. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E. [British Steel plc, Scunthorpe (United Kingdom). Scunthorpe Works

    1995-12-01T23:59:59.000Z

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  4. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

    1997-12-31T23:59:59.000Z

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  5. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  6. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01T23:59:59.000Z

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  7. Met coke world summit 2005

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  8. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01T23:59:59.000Z

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  9. Energy intensity in China's iron and steel sector

    E-Print Network [OSTI]

    Xu, Jingsi, M.C.P. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    In this study, I examine the spatial and economic factors that influence energy intensity in China's iron and steel sector, namely industrial value added, renovation investment, coke consumption, and local coke supply. ...

  10. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10T23:59:59.000Z

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  11. An environmental impact analysis of grinding

    E-Print Network [OSTI]

    Baniszewski, Beth (Beth Ellen)

    2005-01-01T23:59:59.000Z

    This thesis was intended to investigate the environmental impact of grinding in the United States manufacturing industry. Grinding is an ideal method for producing parts with a fine surface finish and high dimensional ...

  12. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect (OSTI)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  13. Ceramic-bonded abrasive grinding tools

    DOE Patents [OSTI]

    Holcombe, Jr., Cressie E. (Farragut, TN); Gorin, Andrew H. (Knoxville, TN); Seals, Roland D. (Oak Ridge, TN)

    1994-01-01T23:59:59.000Z

    Abrasive grains such as boron carbide, silicon carbide, alumina, diamond, cubic boron nitride, and mullite are combined with a cement primarily comprised of zinc oxide and a reactive liquid setting agent and solidified into abrasive grinding tools. Such grinding tools are particularly suitable for grinding and polishing stone, such as marble and granite.

  14. Ceramic-bonded abrasive grinding tools

    DOE Patents [OSTI]

    Holcombe, C.E. Jr.; Gorin, A.H.; Seals, R.D.

    1994-11-22T23:59:59.000Z

    Abrasive grains such as boron carbide, silicon carbide, alumina, diamond, cubic boron nitride, and mullite are combined with a cement primarily comprised of zinc oxide and a reactive liquid setting agent and solidified into abrasive grinding tools. Such grinding tools are particularly suitable for grinding and polishing stone, such as marble and granite.

  15. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31T23:59:59.000Z

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  16. Grinding assembly, grinding apparatus, weld joint defect repair system, and methods

    DOE Patents [OSTI]

    Larsen, Eric D.; Watkins, Arthur D.; Bitsoi, Rodney J.; Pace, David P.

    2005-09-27T23:59:59.000Z

    A grinding assembly for grinding a weld joint of a workpiece includes a grinder apparatus, a grinder apparatus includes a grinding wheel configured to grind the weld joint, a member configured to receive the grinding wheel, the member being configured to be removably attached to the grinder apparatus, and a sensor assembly configured to detect a contact between the grinding wheel and the workpiece. The grinding assembly also includes a processing circuitry in communication with the grinder apparatus and configured to control operations of the grinder apparatus, the processing circuitry configured to receive weld defect information of the weld joint from an inspection assembly to create a contour grinding profile to grind the weld joint in a predetermined shape based on the received weld defect information, and a manipulator having an end configured to carry the grinder apparatus, the manipulator further configured to operate in multiple dimensions.

  17. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01T23:59:59.000Z

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  18. Method for grinding precision components

    DOE Patents [OSTI]

    Ramanath, Srinivasan (Holden, MA); Kuo, Shih Yee (Westboro, MA); Williston, William H. (Holden, MA); Buljan, Sergej-Tomislav (Acton, MA)

    2000-01-01T23:59:59.000Z

    A method for precision cylindrical grinding of hard brittle materials, such as ceramics or glass and composites comprising ceramics or glass, provides material removal rates as high as 19-380 cm.sup.3 /min/cm. The abrasive tools used in the method comprise a strong, light weight wheel core bonded to a continuous rim of abrasive segments containing superabrasive grain in a dense metal bond matrix.

  19. The push for increased coal injection rates -- Blast furnace experience at AK Steel Corporation

    SciTech Connect (OSTI)

    Dibert, W.A.; Duncan, J.H.; Keaton, D.E.; Smith, M.D. [AK Steel Corp., Middletown, OH (United States)

    1994-12-31T23:59:59.000Z

    An effort has been undertaken to increase the coal injection rate on Amanda blast furnace at AK Steel Corporation`s Ashland Works in Ashland, Kentucky to decrease fuel costs and reduce coke demand. Operating practices have been implemented to achieve a sustained coal injection rate of 140 kg/MT, increased from 100--110 kg/MT. In order to operate successfully at the 140 kg/MT injection rate; changes were implemented to the furnace charging practice, coal rate control methodology, orientation of the injection point, and the manner of distribution of coal to the multiple injection points. Additionally, changes were implemented in the coal processing facility to accommodate the higher demand of pulverized coal; grinding 29 tonnes per hour, increased from 25 tonnes per hour. Further increases in injection rate will require a supplemental supply of fuel.

  20. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  1. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31T23:59:59.000Z

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  2. New coke-sorting system at OAO Koks

    SciTech Connect (OSTI)

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  3. Precision diamond grinding of ceramics and glass

    SciTech Connect (OSTI)

    Smith, S.; Paul, H.; Scattergood, R.O.

    1988-12-01T23:59:59.000Z

    A new research initiative will be undertaken to investigate the effect of machine parameters and material properties on precision diamond grinding of ceramics and glass. The critical grinding depth to initiate the plastic flow-to-brittle fracture regime will be directly measured using plunge-grind tests. This information will be correlated with machine parameters such as wheel bonding and diamond grain size. Multiaxis grinding tests will then be made to provide data more closely coupled with production technology. One important aspect of the material property studies involves measuring fracture toughness at the very short crack sizes commensurate with grinding damage. Short crack toughness value`s can be much less than the long-crack toughness values measured in conventional fracture tests.

  4. Design, construction and start-up of a modern coke plant

    SciTech Connect (OSTI)

    Williams, A.E.

    1983-05-01T23:59:59.000Z

    The planning and design of a 60-oven, 6m replacement coke battery and associated by-products plant for Republic Steel Corp, Chicago, are described together with the constructional methods used and problems experienced through start-up of the facility. Pushing emission control is achieved with a Mitsubishi-type land-based system and changing emission control with a Nippon Steel combination car and land-based system. A Takahax-Hirohax coke-oven gas desulphurization unit is included in the by-product plant. Construction began in March 1979 with the first push in December 1981.

  5. Trends in the automation of coke production

    SciTech Connect (OSTI)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  6. New era for ultrasonic impact grinding

    SciTech Connect (OSTI)

    Calkins, N.C.

    1981-01-01T23:59:59.000Z

    New piezoelectric efficiencies allow impact grinding to progress up to 900 watts and above. This previously little known machining method takes on new importance in cutting and contouring extremely hard refractories and refractory metals such as boron carbide.

  7. Method and apparatus for quenching coke

    SciTech Connect (OSTI)

    Calderon, A.

    1980-07-22T23:59:59.000Z

    A method is described for controlling pollutions during the discharge of coke from a coke oven having a pusher side and a coke discharge opening. The method comprises the steps of moving a carriage into alignment with the coke discharge opening, pushing a body of hot coke out of the discharge opening of the oven, guiding the coke pushed from the oven into a chamber supported on said carriage, quenching the coke by directing liquid at coke which is pushed into said chamber for dropping the temperature of the coke, confining steam and vapor generated during the dropping of the temperature of the coke in the chamber for building a positive pressure within the chamber, forcing the steam and vapors generated from the quenching of the coke out of the chamber through a venturi-like opening by means of the positive pressure built up in the chamber, and spraying liquid at the gases forced through said venturi-like opening by the positive pressure in the chamber for cleaning the gases.

  8. Cryogenic grinding: an efficient method for recycling scrap rubber

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    Cryogenic grinding represents an opportunity for expanding recycling capabilities to a broad range of compounds. Many materials that can be reduced to a powder by conventional coarse grinding can be reduced more efficiently by using a super-cold agent such as liquid nitrogen at -320/sup 0/F to embrittle plastic or rubber polymers before grinding. In addition, cryogenic grinding makes possible the size reduction of many materials that cannot be ground by conventional ambient grinding methods. Some experiences of cryogenic grinding in practice at United Tire and Rubber company, Limited, headquartered in Rexdale, Ontario, are noted. A schematic of such a system is shown.

  9. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01T23:59:59.000Z

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  10. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31T23:59:59.000Z

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  11. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31T23:59:59.000Z

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  12. Estimating Coke and Pepsi's price and advertising strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

    1999-01-01T23:59:59.000Z

    No. 789 ESTIMATING COKE AND PEPSI’ PRICE S AND ADVERTISINGAdvertising Strategies: Coke and Pepsi) by Amos Golan, LarryMarch 1999 Estimating Coke and Pepsi’s Price and Advertising

  13. Modified Dry Grind Ethanol Process Vijay Singh1

    E-Print Network [OSTI]

    Modified Dry Grind Ethanol Process Vijay Singh1 , Kent D. Rausch1 *, Ping Yang2 , Hosein Shapouri3-265-0697). #12;Modified Dry Grind Ethanol Process ­ University of Illinois 2 Table of Contents 1. Introductory.....................................................................................................7 3.2. Dry Grind Ethanol

  14. New designs in the reconstruction of coke-sorting systems

    SciTech Connect (OSTI)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  15. Precision replenishable grinding tool and manufacturing process

    DOE Patents [OSTI]

    Makowiecki, Daniel M. (Livermore, CA); Kerns, John A. (Livermore, CA); Blaedel, Kenneth L. (Livermore, CA); Colella, Nicholas J. (Livermore, CA); Davis, Pete J. (Pleasanton, CA); Juntz, Robert S. (Hayward, CA)

    1998-01-01T23:59:59.000Z

    A reusable grinding tool consisting of a replaceable single layer of abrasive particles intimately bonded to a precisely configured tool substrate, and a process for manufacturing the grinding tool. The tool substrate may be ceramic or metal and the abrasive particles are preferably diamond, but may be cubic boron nitride. The manufacturing process involves: coating a configured tool substrate with layers of metals, such as titanium, copper and titanium, by physical vapor deposition (PVD); applying the abrasive particles to the coated surface by a slurry technique; and brazing the abrasive particles to the tool substrate by alloying the metal layers. The precision control of the composition and thickness of the metal layers enables the bonding of a single layer or several layers of micron size abrasive particles to the tool surface. By the incorporation of an easily dissolved metal layer in the composition such allows the removal and replacement of the abrasive particles, thereby providing a process for replenishing a precisely machined grinding tool with fine abrasive particles, thus greatly reducing costs as compared to replacing expensive grinding tools.

  16. Precision replenishable grinding tool and manufacturing process

    DOE Patents [OSTI]

    Makowiecki, D.M.; Kerns, J.A.; Blaedel, K.L.; Colella, N.J.; Davis, P.J.; Juntz, R.S.

    1998-06-09T23:59:59.000Z

    A reusable grinding tool consisting of a replaceable single layer of abrasive particles intimately bonded to a precisely configured tool substrate, and a process for manufacturing the grinding tool are disclosed. The tool substrate may be ceramic or metal and the abrasive particles are preferably diamond, but may be cubic boron nitride. The manufacturing process involves: coating a configured tool substrate with layers of metals, such as titanium, copper and titanium, by physical vapor deposition (PVD); applying the abrasive particles to the coated surface by a slurry technique; and brazing the abrasive particles to the tool substrate by alloying the metal layers. The precision control of the composition and thickness of the metal layers enables the bonding of a single layer or several layers of micron size abrasive particles to the tool surface. By the incorporation of an easily dissolved metal layer in the composition such allows the removal and replacement of the abrasive particles, thereby providing a process for replenishing a precisely machined grinding tool with fine abrasive particles, thus greatly reducing costs as compared to replacing expensive grinding tools. 11 figs.

  17. Optimal Railroad Rail Grinding for Fatigue Mitigation

    E-Print Network [OSTI]

    Tangtragulwong, Potchara

    2012-02-14T23:59:59.000Z

    This dissertation aims to study the benefit of rail grinding on service life of railroad rails, focusing on failures due to rolling contact fatigue (RCF) at the rail head. Assuming a tangent rail with one-point contact at the running surface, a...

  18. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  19. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15T23:59:59.000Z

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  20. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  1. New and revised standards for coke production

    SciTech Connect (OSTI)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  2. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15T23:59:59.000Z

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  3. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  4. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01T23:59:59.000Z

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  5. A Wavelet-Based Methodology for Grinding Wheel Condition Monitoring

    SciTech Connect (OSTI)

    Liao, T. W. [Louisiana State University; Ting, C.F. [Louisiana State University; Qu, Jun [ORNL; Blau, Peter Julian [ORNL

    2007-01-01T23:59:59.000Z

    Grinding wheel surface condition changes as more material is removed. This paper presents a wavelet-based methodology for grinding wheel condition monitoring based on acoustic emission (AE) signals. Grinding experiments in creep feed mode were conducted to grind alumina specimens with a resinoid-bonded diamond wheel using two different conditions. During the experiments, AE signals were collected when the wheel was 'sharp' and when the wheel was 'dull'. Discriminant features were then extracted from each raw AE signal segment using the discrete wavelet decomposition procedure. An adaptive genetic clustering algorithm was finally applied to the extracted features in order to distinguish different states of grinding wheel condition. The test results indicate that the proposed methodology can achieve 97% clustering accuracy for the high material removal rate condition, 86.7% for the low material removal rate condition, and 76.7% for the combined grinding conditions if the base wavelet, the decomposition level, and the GA parameters are properly selected.

  6. Method for processing coke oven gas

    SciTech Connect (OSTI)

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1980-11-25T23:59:59.000Z

    Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

  7. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  8. Increasing energy efficiency of grinding media through microscale comminution studies

    SciTech Connect (OSTI)

    Lo, Y.C.; Goller, G.A. [GS Technologies/Control International Inc., Salt Lake City, UT (United States)

    1995-12-31T23:59:59.000Z

    Microscale studies involving an ultrafast load cell have been shown to provide direct and accurate measurements of particle strength, particle fracture energy and particle breakage functions under different loading geometry conditions. The effect of grinding media size, shape, density and surface properties on the energy efficiency can be quantitatively determined for different materials to be ground. The applications of microscale comminution studies have been demonstrated to provide good predictions of grinding mill performance with different grinding media.

  9. Grinding tool for making hemispherical bores in hard materials

    DOE Patents [OSTI]

    Duran, E.L.

    1985-04-03T23:59:59.000Z

    A grinding tool for forming hemispherical bores in hard materials such as boron carbide. The tool comprises a hemicircular grinding bit, formed of a metal bond diamond matrix, which is mounted transversely on one end of a tubular tool shaft. The bit includes a spherically curved outer edge surface which is the active grinding surface of the tool. Two coolant fluid ports on opposite sides of the bit enable introduction of coolant fluid through the bore of the tool shaft so as to be emitted adjacent the opposite sides of the grinding bit, thereby providing optimum cooling of both the workpiece and the bit.

  10. Energy efficiency of alternative coke-free metallurgical technologies

    SciTech Connect (OSTI)

    V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

    2009-02-15T23:59:59.000Z

    Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

  11. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  12. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B. [Hoogovens IJmuiden B.V. (Netherlands)

    1995-12-01T23:59:59.000Z

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  13. abrasive grinding wheels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with the Autonomous Intelligent Systems Group Behnke, Sven 426 ME 4171 --HOMEWORK: LIFE-CYCLE DESIGN WHEEL SYNOPSIS OF ASSIGNMENT Engineering Websites Summary: are Cokes in 12-pack...

  14. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15T23:59:59.000Z

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  15. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24T23:59:59.000Z

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  16. Grinding media oscillation: effect on torsional vibrations in tumble mills

    E-Print Network [OSTI]

    Toram, Kiran Kumar

    2005-11-01T23:59:59.000Z

    of oscillation of grinding media on torsional vibrations of the mill. A theoretical model was developed to determine the oscillating frequency of the grinding media. A 12" (0.3 m) diameter tumble mill test rig was built with a 0.5 hp DC motor. The rig is tested...

  17. Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

  18. Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE

    E-Print Network [OSTI]

    Karp, Larry S.

    Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

  19. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07T23:59:59.000Z

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  20. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. (Armco Steel Co., Middletown, OH (United States))

    1993-01-01T23:59:59.000Z

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  1. Applied grinding wheel performance evaluation for optical fabrication

    SciTech Connect (OSTI)

    Piscotty, M.A.; Taylor, J.S.; Blaedel, K.L.

    1996-06-11T23:59:59.000Z

    We are collaborating with the Center for Optics Manufacturing (Rochester NY) to develop fine diamond grinding wheels for spherical grinding of glass optics. A standardized method for evaluating wheel performance includes in-process acoustic emission (AE). This paper includes recent AE measurements taken during the evaluation of several fine diamond grinding wheels and discusses how this new information might relate to the physical performance of the wheels. An interesting observation is also reported on the surface topography of worn bronze wheels using an interferometric profiler.

  2. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  3. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  4. Water protection in coke-plant design

    SciTech Connect (OSTI)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  5. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01T23:59:59.000Z

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  6. Selection of Processes for Welding Steel Rails

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ...._ _) Selection of Processes for Welding Steel Rails by N.S. Tsai* and T.W. Eagar* ABSTRACT 421 The advantages and limitations ofseveral conventional and prospective rail welding processes are reviewed with emphasis on the heat input rate, on joint preparation, on post weld grinding and on resultant metallurgical

  7. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  8. Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

  9. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  10. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  11. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  12. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  13. Low-Rank Coal Grinding Performance Versus Power Plant Performance

    SciTech Connect (OSTI)

    Rajive Ganguli; Sukumar Bandopadhyay

    2008-12-31T23:59:59.000Z

    The intent of this project was to demonstrate that Alaskan low-rank coal, which is high in volatile content, need not be ground as fine as bituminous coal (typically low in volatile content) for optimum combustion in power plants. The grind or particle size distribution (PSD), which is quantified by percentage of pulverized coal passing 74 microns (200 mesh), affects the pulverizer throughput in power plants. The finer the grind, the lower the throughput. For a power plant to maintain combustion levels, throughput needs to be high. The problem of particle size is compounded for Alaskan coal since it has a low Hardgrove grindability index (HGI); that is, it is difficult to grind. If the thesis of this project is demonstrated, then Alaskan coal need not be ground to the industry standard, thereby alleviating somewhat the low HGI issue (and, hopefully, furthering the salability of Alaskan coal). This project studied the relationship between PSD and power plant efficiency, emissions, and mill power consumption for low-rank high-volatile-content Alaskan coal. The emissions studied were CO, CO{sub 2}, NO{sub x}, SO{sub 2}, and Hg (only two tests). The tested PSD range was 42 to 81 percent passing 76 microns. Within the tested range, there was very little correlation between PSD and power plant efficiency, CO, NO{sub x}, and SO{sub 2}. Hg emissions were very low and, therefore, did not allow comparison between grind sizes. Mill power consumption was lower for coarser grinds.

  14. High-speed, low-damage grinding of advanced ceramics Phase 1. Final report

    SciTech Connect (OSTI)

    Kovach, J.A. [Eaton Corp., Willoughby Hills, OH (United States). Mfg. Technologies Center; Malkin, S. [Univ. of Massachusetts (United States)

    1995-03-01T23:59:59.000Z

    In manufacture of structural ceramic components, grinding costs can comprise up to 80% of the entire manufacturing cost. Most of these costs arise from the conventional multi-step grinding process with numerous grinding wheels and additional capital equipment, perishable dressing tools, and labor. In an attempt to reduce structural ceramic grinding costs, a feasibility investigation was undertaken to develop a single step, roughing-finishing process suitable for producing high-quality silicon nitride ceramic parts at high material removal rates at lower cost than traditional, multi-stage grinding. This feasibility study employed combined use of laboratory grinding tests, mathematical grinding models, and characterization of resultant material surface condition. More specifically, this Phase 1 final report provides a technical overview of High-Speed, Low-Damage (HSLD) ceramic grinding and the conditions necessary to achieve the small grain depths of cut necessary for low damage grinding while operating at relatively high material removal rates. Particular issues addressed include determining effects of wheel speed and material removal rate on resulting mode of material removal (ductile or brittle fracture), limiting grinding forces, calculation of approximate grinding zone temperatures developed during HSLD grinding, and developing the experimental systems necessary for determining HSLD grinding energy partition relationships. In addition, practical considerations for production utilization of the HSLD process are also discussed.

  15. Characterization of grinding wheels: An annotated Bibliography. Final report

    SciTech Connect (OSTI)

    McClung, R.W.

    1995-12-01T23:59:59.000Z

    The characteristics of grinding wheels, after both fabrication and periods of operation, have a significant effect on the processed surface and the mechanical properties of advanced ceramics. An extensive literature survey and review has been conducted to determine and catalogue the various characterization methods that have been investigated and reported. Although many of the references have addressed the grinding of metals, the historical and technical merit justify their inclusion in this bibliography. For convenience, the references have been subdivided into nine subheadings: Nondestructive examination; elasticity and stiffness; wheel hardness; topography and profilometry; observation of texture of wheel surfaces wheel wear; in process monitoring of grinding, acoustic emission, other; characteristics of ground surfaces; and miscellaneous.

  16. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs 

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  17. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  18. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  19. Grinding of cement clinkers : linking multi-scale fracture properties to system chemistry, mineralogy and microstructure

    E-Print Network [OSTI]

    Wilson, William, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    Growing environmental concerns encourage the cement industry to improve its environmental performance, which in turn renews the interest in clinker grinding efficiency. Current knowledge on clinker grinding was built over ...

  20. Syncrude coke burned in bubbling fluidized bed

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Syncrude Canada Ltd.'s byproduct coke is high in sulfur (7%) and vanadium (0.2%), and moderate in ash (5.9%). It contains a high proportion of unreactive forms of carbon and is low in volatiles, 6.6%. It is unsuitable for combustion by established technologies, and at present the entire production of over 2000 tons per day is being stockpiled. Experiments with atmospheric fluidized bed combustion (AFBC) are described. The AFBC provides abatement of SO/sub 2/ emissions by means of limestone sorbent fed to the combustor together with the fuel. The pilot plant, combustion efficiency, and sulfur capture are discussed. 3 figures.

  1. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-12-01T23:59:59.000Z

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  2. Innovative coke oven gas cleaning system for retrofit applications. Quarterly technical progress report No. 4, October 1, 1990 to December 31, 1990

    SciTech Connect (OSTI)

    Kwasnoski, D.

    1993-10-22T23:59:59.000Z

    Work on this coke oven gas cleaning demonstration project (CCT-II) this quarter has been focused on Phase IIB tasks, and include engineering, procurement, construction, and training. Additionally, plans for changes in the operating schedule of the coke plant that affect the demonstration project are described. Engineering efforts are nearly complete. Remaining to be finalized is an assessment of electrical heat tracing/insulation needs for pipe lines, assessment of fire protection requirements, and instrument modifications. Procurement of all major equipment items is complete, except for possible additions to fire fighting capabilities. Major focus is on expediting pipe and structural steel to the project site. Civil construction is complete except for minor pads and bases as required for pipe supports, etc. Erection of the hydrogen sulfide and ammonia scrubber vessels is complete. Installation of scrubber vessel internals is underway. A subcontractor has been retained to develop a computerized program for operations and maintenance training for the coke oven gas treatment plant. Recent developments in the coke plant operating plans will result in reductions in the rate of production of coke oven gas to be processed in the demonstration project.

  3. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    DOE Patents [OSTI]

    Gerdemann, Stephen J. (Albany, OR); White, Jack C. (Albany, OR)

    1999-01-01T23:59:59.000Z

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

  4. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    DOE Patents [OSTI]

    Gerdemann, Stephen J. (Albany, OR); White, Jack C. (Albany, OR)

    1998-01-01T23:59:59.000Z

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag.

  5. Recovery of titanium values from titanium grinding swarf by electric furnace smelting

    DOE Patents [OSTI]

    Gerdemann, S.J.; White, J.C.

    1998-08-04T23:59:59.000Z

    A method for the recovery of valuable materials from titanium grinding swarf is provided comprising the steps of sieving the accumulated titanium grinding swarf to remove unwanted coarse trash and grinding wheel fragments, pelletizing, and smelting in an electric arc furnace to produce ferrotitanium and/or high titanium slag. 1 fig.

  6. Fingerprints for Machines Characterization and Optical Identification of Grinding Imprints

    E-Print Network [OSTI]

    Fingerprints for Machines ­ Characterization and Optical Identification of Grinding Imprints Ralf. With this model we demonstrate that our characterization has a false positive rate of approximately 10-20 which of inherent material properties is used for fin- gerprinting in various fields, e.g. chemical fingerprints [10

  7. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    factor of bituminous coal, coking coal, and coke consumed inprice of Bituminous coal, coking coal, and coke consumed in

  8. New process for coke-oven gas desulfurization

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-10-01T23:59:59.000Z

    With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

  9. Method for removal of furfural coke from metal surfaces

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-27T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  10. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    with distance along the reactor, and therefore the coke distribution should follow a similar pattern. A distribution of coke deposits along the reactor was also observed by Noda er al. (1974) in a study of iso-pentane isomerization. In this case the coke..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

  11. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01T23:59:59.000Z

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  12. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Hofherr, K. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  13. Estimating Coke and Pepsi's Price and Advertising Strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

    1998-01-01T23:59:59.000Z

    2b: GME-Nash Estimates of Pepsi’s Strategies (First QuarterStrategy Distributions for Pepsi (First Quarter 1977) a)789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISING STRATEGIES

  14. Problem of improving coke oven gas purification systems

    SciTech Connect (OSTI)

    Goldin, I.A.

    1982-01-01T23:59:59.000Z

    A discussion of the problems of improving desulfurization processes of coke oven gas was presented. Of particular interest were control systems and increasing capacity of the coke ovens. Included in the discussion were the vacuum-carbonate and arsenic-soda sulfur removal systems. Problems involved with these systems were the number of treatment operations, the volume of the reagents used, and the operation of equipment for naphthalene and cyanide removal.

  15. Priorities in the design of chemical shops at coke plants

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  16. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  17. Innovative coal gas cleaning at Sparrows Point Coal Chemical Plant, Maryland for Bethlehem Steel Corporation

    SciTech Connect (OSTI)

    Antrobus, K.; Platts, M. (Davy/Still Otto, Pittsburgh, PA (US)); Harbold, L. (Bethlehem Steel Corp., PA (USA)); Kornosky, R. (Office of Clean Coal Technology, US DOE, Pittsburgh, PA (US))

    1990-01-01T23:59:59.000Z

    In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems associated with an unmarketable ammonium sulfate by-product. Significant reduction in benzene and hydrogen cyanide emissions are also obtained.

  18. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01T23:59:59.000Z

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  19. Application of electrolytic in-process dressing for high-efficiency grinding of ceramic parts. Research activities 1995--96

    SciTech Connect (OSTI)

    Bandyopadhyay, B.P. [Univ. of North Dakota, Grand Forks, ND (United States). Dept. of Mechanical Engineering

    1997-02-01T23:59:59.000Z

    The application of Electrolytic In-Process Dressing (ELID) for highly efficient and stable grinding of ceramic parts is discussed. This research was performed at the Institute of Physical and Chemical Research (RIKEN), Tokyo, Japan, June 1995 through August 1995. Experiments were conducted using a vertical machining center. The silicon nitride work material, of Japanese manufacture and supplied in the form of a rectangular block, was clamped to a vice which was firmly fixed on the base of a strain gage dynamometer. The dynamometer was clamped on the machining center table. Reciprocating grinding was performed with a flat-faced diamond grinding wheel. The output from the dynamometer was recorded with a data acquisition system and the normal component of the force was monitored. Experiments were carried out under various cutting conditions, different ELID conditions, and various grinding wheel bonds types. Rough grinding wheels of grit sizes {number_sign}170 and {number_sign}140 were used in the experiments. Compared to conventional grinding, there was a significant reduction in grinding force with ELID grinding. Therefore, ELID grinding can be recommended for high material removal rate grinding, low rigidity machines, and low rigidity workpieces. Compared to normal grinding, a reduction in grinding ratio was observed when ELID grinding was performed. A negative aspect of the process, this reduced G-ratio derives from bond erosion and can be improved somewhat by adjustments in the ELID current. The results of this investigation are discussed in detail in this report.

  20. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  1. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

    1997-12-31T23:59:59.000Z

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  2. Innovative grinding wheel design for cost-effective machining of advanced ceramics. Phase I, final report

    SciTech Connect (OSTI)

    Licht, R.H.; Ramanath, S.; Simpson, M.; Lilley, E.

    1996-02-01T23:59:59.000Z

    Norton Company successfully completed the 16-month Phase I technical effort to define requirements, design, develop, and evaluate a next-generation grinding wheel for cost-effective cylindrical grinding of advanced ceramics. This program was a cooperative effort involving three Norton groups representing a superabrasive grinding wheel manufacturer, a diamond film manufacturing division and a ceramic research center. The program was divided into two technical tasks, Task 1, Analysis of Required Grinding Wheel Characteristics, and Task 2, Design and Prototype Development. In Task 1 we performed a parallel path approach with Superabrasive metal-bond development and the higher technical risk, CVD diamond wheel development. For the Superabrasive approach, Task 1 included bond wear and strength tests to engineer bond-wear characteristics. This task culminated in a small-wheel screening test plunge grinding sialon disks. In Task 2, an improved Superabrasive metal-bond specification for low-cost machining of ceramics in external cylindrical grinding mode was identified. The experimental wheel successfully ground three types of advanced ceramics without the need for wheel dressing. The spindle power consumed by this wheel during test grinding of NC-520 sialon is as much as to 30% lower compared to a standard resin bonded wheel with 100 diamond concentration. The wheel wear with this improved metal bond was an order of magnitude lower than the resin-bonded wheel, which would significantly reduce ceramic grinding costs through fewer wheel changes for retruing and replacements. Evaluation of ceramic specimens from both Tasks 1 and 2 tests for all three ceramic materials did not show evidence of unusual grinding damage. The novel CVD-diamond-wheel approach was incorporated in this program as part of Task 1. The important factors affecting the grinding performance of diamond wheels made by CVD coating preforms were determined.

  3. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect (OSTI)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  4. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  5. Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*

    E-Print Network [OSTI]

    Lansky, Joshua

    Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm theory. We use these methods to estimate the pricing and adver- tising strategies of Coca-Cola and Pepsi

  6. Coke profile and effect on methane/ethylene conversion process 

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

  7. The interrelationship between environmental goals, productivity improvement, and increased energy efficiency in integrated paper and steel plants

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    This report presents the results of an investigation into the interrelationships between plant-level productivity, energy efficiency, and environmental improvements for integrated pulp and paper mills and integrated steel mills in the US. Integrated paper and steel plants are defined as those facilities that use some form of onsite raw material to produce final products (for example, paper and paperboard or finished steel). Fully integrated pulp and paper mills produce onsite the pulp used to manufacture paper from virgin wood fiber, secondary fiber, or nonwood fiber. Fully integrated steel mills process steel from coal, iron ore, and scrap inputs and have onsite coke oven facilities.

  8. Energy Consumption and Potential for Energy Conservation in the Steel Industry

    E-Print Network [OSTI]

    Hughes, M. L.

    1979-01-01T23:59:59.000Z

    , April 22-25, 1979 IRON ORE REDUCTION STEELMAKING PRIMARY CONVERSION HOT ROLLING FINISHING SIMPLIFIED FLOW SHEET STEEL PRODUCTION PROCESSES Iron Ore & Wastes , Agg lomerating Pellets Ore & Flux Coal ~ " Sinter - Blast ~ Coke Furnaces... - Ovens '( BF Iron Outside ,~., Scrap Open Hearth Furnaces , Ingot Casting Basic Oxygen Furnaces Raw Steel Electric Arc Furnaces Scrap , Primary Rolling Mills Continuous Casting Slabs, Blooms, Billets r Secondary Hot Rolling Bars...

  9. EFFECT OF GRINDING AND PELLETING OF HAY ON COPPER METABOLISM IN SHEEP.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    EFFECT OF GRINDING AND PELLETING OF HAY ON COPPER METABOLISM IN SHEEP. STUDIES WITH RADIOACTIVE was undertaken. The sheep were then given the same lucern hay ground and pelleted (containing 12 mg Cu/kg D

  10. Simultaneous Saccharification and Fermentation of Dry-grind Highly Digestible Grain Sorghum Lines for Ethanol Production

    E-Print Network [OSTI]

    Hernandez, Joan R.

    2010-07-14T23:59:59.000Z

    The potential of high digestible grain sorghum (HDGS) with a modified starch protein endosperm matrix to replace corn in ethanol production was investigated using dry grind simultaneous saccharification and fermentation (SSF). Preliminary...

  11. Coke oven gas desulphurization by the Carl Still process

    SciTech Connect (OSTI)

    Knight, R.E.

    1981-01-01T23:59:59.000Z

    The Steubenville East Coke Plant need a desulfurization process that would desulfurize an eventual 95 million standard cubic feet per day of coke oven gas from an inlet of 450 gr/DSCF to an outlet of 45 gr/DSCF of hydrogen sulfide. The Dravo/Still plant process was selected, due to the use of ammonia which was available in the gas, as the absorbing agent. It was also a proven process. Dravo/Still also was capable of building a sulfuric acid plant. The desulfurization efficiency of the plant has consistently provided an average final gas sulfur loading below the guaranteed 45 gr/DSCF. This removal efficiency has enabled production of an average of 4615 tons per day of 66/sup 0/Be acid. Also SO/sub 2/ to SO/sub 3/ conversion has averaged 98%. 3 figures. (DP)

  12. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01T23:59:59.000Z

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  13. Pipeline charging of coke ovens with a preheated charge

    SciTech Connect (OSTI)

    Karpov, A.V.; Khadzhioglo, A.V.; Kuznichenko, V.M.

    1983-01-01T23:59:59.000Z

    Work to test a pipeline charging method was conducted at the Konetsk Coke Works (a PK-2K coke oven system with a single gas main, oven width 407 mm, height 4300 mm, effective column 20.0 cm/sub 3/). This method consists of transporting the heated coal charge to the ovens through a pipe by means of steam. the charge is transported by high pressure chamber groups, and loaded by means of systems equipped with devices for separation, withdrawal and treatment of the spent steam. The principal goal of the present investigation was to test technical advances in the emission-free charging of preheated charges. The problem was, first, to create a reliable technology for separation of the steam from the charge immediately before loading it into the oven and, second, to provide a total elimination of emissions, thereby protecting the environment against toxic substances.

  14. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  15. Next generation grinding spindle for cost-effective manufacture of advanced ceramic components

    SciTech Connect (OSTI)

    Kovach, J.A.; Laurich, M.A.

    2000-01-01T23:59:59.000Z

    Finish grinding of advanced structural ceramics has generally been considered an extremely slow and costly process. Recently, however, results from the High-Speed, Low-Damage (HSLD) program have clearly demonstrated that numerous finish-process performance benefits can be realized by grinding silicon nitride at high wheel speeds. A new, single-step, roughing-process capable of producing high-quality silicon nitride parts at high material removal rates while dramatically reducing finishing costs has been developed.

  16. New environmental concepts in the chemical and coke industries

    SciTech Connect (OSTI)

    A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

    2007-05-15T23:59:59.000Z

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  17. High speed low damage grinding of advanced ceramics - Phase II Final Report

    SciTech Connect (OSTI)

    Kovach, J.A.; Malkin, S.

    2000-02-01T23:59:59.000Z

    In the manufacture of structural ceramic components, grinding costs can comprise up to 80% of the entire manufacturing cost. As a result, one of the most challenging tasks faced by manufacturing process engineers is the development of a ceramic finishing process to maximize part throughput while minimizing costs and associated scrap levels. The efforts summarized in this report represent the second phase of a program whose overall objective was to develop a single-step, roughing-finishing process suitable for producing high-quality silicon nitride parts at high material removal rates and at substantially lower cost than traditional, multi-stage grinding processes. More specifically, this report provides a technical overview of High-Speed, Low-Damage (HSLD) ceramic grinding which employs elevated wheel speeds to achieve the small grain depths of cut necessary for low-damage grinding while operating at relatively high material removal rates. The study employed the combined use of laboratory grinding tests, mathematical grinding models, and characterization of the resultant surface condition. A single-step, roughing-finishing process operating at high removal rates was developed and demonstrated.

  18. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro [Kobe Steel Ltd. (Japan). Kobe Works

    1997-12-31T23:59:59.000Z

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  19. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31T23:59:59.000Z

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  20. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01T23:59:59.000Z

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  1. The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties

    SciTech Connect (OSTI)

    Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

    2006-07-01T23:59:59.000Z

    In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

  2. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  3. X-ray evaluation of coke-oven gas line deposits

    SciTech Connect (OSTI)

    Swain, Y.T.

    1983-08-01T23:59:59.000Z

    Control of coke-oven gas pipeline deposits has been facilitated through the use of an X-ray technique that provides quantitative data without disrupting plant operations.

  4. Process for dissolving coke oven deposits comprising atomizing a composition containing N-methyl-2-pyrrolidone into the gas lines

    SciTech Connect (OSTI)

    Stafford, M.L.; Nicholson, G.M.

    1993-07-06T23:59:59.000Z

    A method is described for cleaning gas lines in coke oven batteries comprising atomizing a composition into the gas lines of coke oven batteries, where the composition comprises N-methyl-2-pyrrolidone.

  5. Westinghouse Modular Grinding Process - Enhancement of Volume Reduction for Hot Resin Supercompaction - 13491

    SciTech Connect (OSTI)

    Fehrmann, Henning [Westinghouse Electric Germany GmbH, Dudenstr. 44, D-68167 Mannheim (Germany)] [Westinghouse Electric Germany GmbH, Dudenstr. 44, D-68167 Mannheim (Germany); Aign, Joerg [Westinghouse Electric Germany GmbH, Global D and D and Waste Management, Tarpenring 6, D-22419 Hamburg (Germany)] [Westinghouse Electric Germany GmbH, Global D and D and Waste Management, Tarpenring 6, D-22419 Hamburg (Germany)

    2013-07-01T23:59:59.000Z

    In nuclear power plants (NPP) ion exchange (IX) resins are used in several systems for water treatment. Spent resins can contain a significant amount of contaminates which makes treatment for disposal of spent resins mandatory. Several treatment processes are available such as direct immobilization with technologies like cementation, bitumisation, polymer solidification or usage of a high integrity container (HIC). These technologies usually come with a significant increase in final waste volume. The Hot Resin Supercompaction (HRSC) is a thermal treatment process which reduces the resin waste volume significantly. For a mixture of powdered and bead resins the HRSC process has demonstrated a volume reduction of up to 75 % [1]. For bead resins only the HRSC process is challenging because the bead resins compaction properties are unfavorable. The bead resin material does not form a solid block after compaction and shows a high spring back effect. The volume reduction of bead resins is not as good as for the mixture described in [1]. The compaction properties of bead resin waste can be significantly improved by grinding the beads to powder. The grinding also eliminates the need for a powder additive.Westinghouse has developed a modular grinding process to grind the bead resin to powder. The developed process requires no circulation of resins and enables a selective adjustment of particle size and distribution to achieve optimal results in the HRSC or in any other following process. A special grinding tool setup is use to minimize maintenance and radiation exposure to personnel. (authors)

  6. Takahax-Hirohax process for coke oven gas desulfurization

    SciTech Connect (OSTI)

    Gastwirth, H.; Miner, R.; Stengle, W.

    1981-01-01T23:59:59.000Z

    This paper describes the Takahax-Hirohax process to desulfurize coke oven gas and to produce an ammonium sulfate end product. A review is also made of current operating experience and recent technical developments. The Takahax-Hirohax process is extremely useful when the COG contains a suitable ammonia to sulfur ratio and when ammonium sulfate is a desirable end product. No contaminated effluent streams are emitted from the process. The process is simple, reliable, flexible, and responds easily to COG variations. 4 figures, 3 tables. (DP)

  7. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  8. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31T23:59:59.000Z

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  9. Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

  10. Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

  11. Desulphurization of coke oven gas by the Stretford Process

    SciTech Connect (OSTI)

    Plenderleith, J.

    1981-01-01T23:59:59.000Z

    The Stretford process is probably the most effective means available for removing hydrogen sulphide from gas streams. For streams which do not contain hydrogen cyanide or excessive oxygen it should be nearly ideal. However, the large volume of waste liquor generated by fixation of hydrogen cyanide has prevented its widespread adoption for coke oven gas treatment. Investigations of various proposals for treating the waste liquor indicate that the only practicable way of dealing with it is by reductive incineration. Although attempts to apply the Peabody-Holmes reductive incineration process have been disappointing, significant progress in overcoming some of its deficiencies has been made. The Zimpro wet oxidation process will provide a convenient method of treating the HCN scrubber effluent at No. 1 Plant. However, it will not treat the sodium based liquor from the Stretford plant. Its application to Stretford waste treatment is limited to situations where ammonium liquors and ammonium sulphate recovery facilities are available. Commissioning of this plant has been delayed while a defect in the air compressor supplied for the plant is being remedied. When the problem of liquid effluent disposal has been overcome, and if reagent chemicals continue to be available at reasonable prices, the Stretford process will be a good choice for coke oven gas desulphurization. 8 figures.

  12. A comparison of large wheel grinding tasks by heart rate analysis

    E-Print Network [OSTI]

    Vos, Grover Anthony

    1972-01-01T23:59:59.000Z

    A COMPARISON OF LARGE IIIHEEL GRINDING TASMS BY HEART RATF ANALYSIS A Thesis by GROVER ANTHONY VOS Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... August 1972 Ma)or Subject: Industrial Hygiene A COMRARISON OF LARGE IdHEEL GRINDING TASYiS BY HEART RATE ANALYSIS A Thesis by GROVER ANTHONY VOS Approved es to style snd content by: C sirme of Committee (Heed of Depertm ) /[ v Member Member...

  13. Elements of Dry-Grind Corn-Processing Streams 113 Applied Biochemistry and Biotechnology Vol. 134, 2006

    E-Print Network [OSTI]

    of ethanol as a fuel additive, ethanol production has increased markedly in the past decade. Ethanol-grind corn process is one of two technologies used to convert corn into ethanol. In this process, all kernel with solubles; ethanol; dry-grind processing; stillage; syrup; element concentrations. #12;114 Belyea et al

  14. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  15. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15T23:59:59.000Z

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  16. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01T23:59:59.000Z

    In addition, the coking coal market began to deteriorateits permeability. Bituminous, or coking coal, is blended andmerchant coke plants, coking coal is heated in a low-oxygen,

  17. Chapter 7 -Welding The dangers in welding, cutting, heating and grinding should never be underestimated.

    E-Print Network [OSTI]

    36 Chapter 7 - Welding The dangers in welding, cutting, heating and grinding should never and to understand the hazards involved. Spot the hazard Hazards associated with welding include: · The arc itself eyes can become extremely red and sore and in extreme cases suffer permanent damage. · Welding gases

  18. V/. -NEW TECHNOLOGIES AND RELATED TOPICS. SCRATCHING AND GRINDING PARAMETERS OF VARIOUS FERRITES

    E-Print Network [OSTI]

    Boyer, Edmond

    V/. - NEW TECHNOLOGIES AND RELATED TOPICS. SCRATCHING AND GRINDING PARAMETERS OF VARIOUS FERRITES AB. - On dkrit des experiences effectuks sur un grand nombre de ferrites cubiques et hexagonaux : rayage par une durete Vickers. Dans le cas des experiences de meulage, l'energie specifique pour un ferrite hexagonal

  19. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31T23:59:59.000Z

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  20. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  1. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01T23:59:59.000Z

    other bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gasrange for typical NCVs of coking coal of 26.6 to 29.8Mj/kg.

  2. Producing and controlling of the pollutant in the coal`s coking process

    SciTech Connect (OSTI)

    Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

    1997-12-31T23:59:59.000Z

    In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

  3. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  4. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  5. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite 

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    45 Figure 9. Relationship between enhanced coke formation with increasing yields of paraffins and diminishing yields of olefins 46 Figure 10. Gas chromatogram of the concentrated carbon tetrachloride extract of spent catalyst pellets . . . 49...THE NATURE ABD FORMATION OF COKE IB THE REACTIOB OF METHANOL TO HIDROCARBOBS OVER CHABAZITE A Thesis KENNETH WOOT MCLAUGHLLN Submitted to the Graduate College of Texas AAM Univers ty partial. fulfillment nf the req~nt fo~he degree of MASTER...

  6. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  7. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  8. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  9. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  10. Evaluation of peroxyacetic acid as a potential pre-grinding treatment for control of enteric pathogens on fresh beef trim

    E-Print Network [OSTI]

    Ellebracht, John Wayne

    2005-11-01T23:59:59.000Z

    &M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 2004 Major Subject: Animal Science EVALUATION OF PEROXYACETIC ACID AS A POTENTIAL PRE-GRINDING TREATMENT FOR CONTROL...Neill (Member) (Head of Department) August 2004 Major Subject: Animal Science iii ABSTRACT Evaluation of Peroxyacetic Acid as a Potential Pre-Grinding Treatment for Control of Enteric Pathogens on Fresh Beef Trim...

  11. Electrolytic In-process Dressing (ELID) for high-efficiency, precision grinding of ceramic parts: An experiment study

    SciTech Connect (OSTI)

    Bandyopadhyay, B.P.

    1995-08-01T23:59:59.000Z

    This report describes Electrolytic In-process Dressing (ELID) as applied to the efficient, high-precision grinding of structural ceramics, and describes work performed jointly by Dr. B.P. Bandyopadhyay, University of North Dakota, and Dr. R. Ohmori, of the Institute of Physical and Chemical Research (RINEN), Tokyo, Japan, from June through August, 1994. Dr. Ohmori pioneered the novel ELID grinding technology which incorporates electrolytically enhanced, in-process dressing of metal bonded superabrasive wheels. The principle of ELID grinding technology is discussed in the report as will its application for rough grinding and precision grinding. Two types of silicon nitride based ceramics (Kyocerals Si{sub 3}N{sub 4}, and Eaton`s SRBSN) were ground under various conditions with ELID methods. Mirror surface finishes were obtained with {number_sign} 4000 mesh size wheel (average grain size = 4 {mu}m). Results of these investigations are presented in this report. These include the effects of wheel bond type, type of power supply, abrasive grit friability, and cooling fluid composition. The effects of various parameters are discussed in terms of the mechanisms of ELID grinding, and in particular, the manner of boundary layer formation on the wheels and abrasive grit protrusion.

  12. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  13. Dale Coke: Coke Farm

    E-Print Network [OSTI]

    Farmer, Ellen

    2010-01-01T23:59:59.000Z

    the right place to get compost, or how you get the beststerilized or pasteurized our compost before we put it out.

  14. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L. [Bethlehem Steel Corp., Burns Harbor, IN (United States); [Bethlehem Steel Corp., PA (United States)

    1997-12-31T23:59:59.000Z

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  15. Energy Efficiency Improvement by Measurement and Control: A Case Study of Reheating Furnaces in the Steel Industry

    E-Print Network [OSTI]

    Martensson, A.

    , April 22-23, 1992 Table I. Furnace energy use in Sweden, 1989. Source: Jemkontoret, Stockholm, Sweden. Fuel Energy use a [GWh) ([10 9 Btu)) aI 1680 (5732) Propane 1272 (4340) Natural gas 48 (164) Coke oven gas 400 (1365) Electricity (induction...ENERGY EFFICIENCY IMPROVEMENT BY MEASUREMENT AND CONTROL A case study of reheating furnaces in the steel industry Anders Mlirtensson Department of Environmental and Energy Systems Studies Lund University S-22362 Lund Sweden ABSTRACT...

  16. Use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Popov, A.A.; Rezunenko, Yu.I.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution which show that the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be recovered in the form of ethylenethiourea - a marketable byproduct.

  17. The use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Rezunenko, Y.I.; Popov, A.A.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution showed the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be used in the form of ethylenethiourea - a marketable byproduct.

  18. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  19. Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division

    SciTech Connect (OSTI)

    Volkov, E.L.

    1981-01-01T23:59:59.000Z

    Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

  20. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  1. Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore Torquatob)

    E-Print Network [OSTI]

    Torquato, Salvatore

    Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore of a Brownian particle diffusing among a, digitized lattice-based domain of traps. Following the first, the inverse of the trapping rate, is obtained for a variety of configurations involving digitized spheres

  2. A Long, Contingent Path to Comparative Advantage: Industrial Policy and the Japanese Iron and Steel Industry, 1900-1973

    E-Print Network [OSTI]

    ELBAUM, BERNARD

    2006-01-01T23:59:59.000Z

    Overseas Procurement of Coking Coal By the Japanese Steelendowed as Japan in coking coal and iron ore (Yonekura,

  3. CHOPPING VERSUS GRINDING AND PELLETING OF HAY : EFFECT ON AVAILABILITY OF TRACE ELEMENTS (Cu, Zn and Mn)

    E-Print Network [OSTI]

    Boyer, Edmond

    CHOPPING VERSUS GRINDING AND PELLETING OF HAY : EFFECT ON AVAILABILITY OF TRACE ELEMENTS (Cu, Zn often receive ground diets that may or may not be pelleted. We intended to examine the effect of transit) chopped into pieces 3 cm long, or ground in a grinder equipped with a 0.6 mm sieve and pelleted in 6 mm

  4. ITP Steel: Theoretical Minimum Energies to Produce Steel for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000 ITP Steel: Theoretical Minimum Energies to Produce Steel for Selected Conditions, March 2000...

  5. Auto/Steel Partnership: Advanced High-Strength Steel Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced High-Strength Steel Research and Development AutoSteel Partnership: Advanced High-Strength Steel Research and Development 2009 DOE Hydrogen Program and Vehicle...

  6. ITP Steel: Steel Industry Marginal Opportunity Study September...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steel Industry Marginal Opportunity Study September 2005 ITP Steel: Steel Industry Marginal Opportunity Study September 2005 steelmarginalopportunity.pdf More Documents &...

  7. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

    2009-05-15T23:59:59.000Z

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  8. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

    2011-12-15T23:59:59.000Z

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  9. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  10. Choosing a coke-oven gas desulfurization system: a review of current technology

    SciTech Connect (OSTI)

    Lynch, P.A.

    1982-12-01T23:59:59.000Z

    Installation of coke-oven gas desulphurizing systems is primarily the result of air pollution control regulations. Although not currently profitable, operating costs can be minimized by choosing the technology most suited to the particular application. The Stretford Holmes, Takahax/Hirohax, Koppers Vacuum Carbonate, Sulfiban and Dravo/Still processes are discussed, together with criteria for economic analysis based on technical and by-product market evaluations.

  11. Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method

    SciTech Connect (OSTI)

    Ritter, H.

    1985-05-21T23:59:59.000Z

    An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

  12. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01T23:59:59.000Z

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  13. Ultrahigh carbon steels, Damascus steels, and superplasticity

    SciTech Connect (OSTI)

    Sherby, O.D. [Stanford Univ., CA (United States). Dept. of Materials Science and Engineering; Wadsworth, J. [Lawrence Livermore National Lab., CA (United States)

    1997-04-01T23:59:59.000Z

    The processing properties of ultrahigh carbon steels (UHCSs) have been studied at Stanford University over the past twenty years. These studies have shown that such steels (1 to 2.1% C) can be made superplastic at elevated temperature and can have remarkable mechanical properties at room temperature. It was the investigation of these UHCSs that eventually brought us to study the myths, magic, and metallurgy of ancient Damascus steels, which in fact, were also ultrahigh carbon steels. These steels were made in India as castings, known as wootz, possibly as far back as the time of Alexander the Great. The best swords are believed to have been forged in Persia from Indian wootz. This paper centers on recent work on superplastic UHCSs and on their relation to Damascus steels. 32 refs., 6 figs.

  14. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  15. Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks

    SciTech Connect (OSTI)

    S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

  16. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  17. Leaching of indium from obsolete liquid crystal displays: Comparing grinding with electrical disintegration in context of LCA

    SciTech Connect (OSTI)

    Dodbiba, Gjergj, E-mail: dodbiba@sys.t.u-tokyo.ac.jp [Department of System Innovation, Graduate School of Engineering, University of Tokyo (Japan); Nagai, Hiroki; Wang Lipang; Okaya, Katsunori; Fujita, Toyohisa [Department of System Innovation, Graduate School of Engineering, University of Tokyo (Japan)

    2012-10-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Two pre-treatment methods, prior to leaching of indium from obsolete LCD modules, were described. Black-Right-Pointing-Pointer Conventional grinding and electrical disintegration have been evaluated and compared in the context of LCA. Black-Right-Pointing-Pointer Experimental data on the leaching capacity for indium and the electricity consumption of equipment were inputted into the LCA model in order to compare the environmental performance of each method. Black-Right-Pointing-Pointer An estimate for the environmental performance was calculated as the sum of six impact categories. Black-Right-Pointing-Pointer Electrical disintegration method outperforms conventional grinding in all impact categories. - Abstract: In order to develop an effective recycling system for obsolete Liquid Crystal Displays (LCDs), which would enable both the leaching of indium (In) and the recovery of a pure glass fraction for recycling, an effective liberation or size-reduction method would be an important pre-treatment step. Therefore, in this study, two different types of liberation methods: (1) conventional grinding, and (2) electrical disintegration have been tested and evaluated in the context of Life Cycle Assessment (LCA). In other words, the above-mentioned methods were compared in order to find out the one that ensures the highest leaching capacity for indium, as well as the lowest environmental burden. One of the main findings of this study was that the electrical disintegration was the most effective liberation method, since it fully liberated the indium containing-layer, ensuring a leaching capacity of 968.5 mg-In/kg-LCD. In turn, the estimate for the environmental burden was approximately five times smaller when compared with the conventional grinding.

  18. Supporting steel

    SciTech Connect (OSTI)

    Badra, C. [International Trade Commission, Washington, DC (United States)

    1995-10-01T23:59:59.000Z

    The US Department of Energy (DOE) and the American Iron and Steel Institute (AISI) have just completed a pilot program on the technical and economic viability of direct ironmaking by a process based on bath smelting. In this process, oxygen, prereduced iron ore pellets, coal, and flux are charged into a molten slag bath containing a high percentage of carbon. The carbon removes oxygen from the iron ore and generates carbon monoxide and liquid iron. Oxygen is then injected to burn some of the carbon monoxide gas before it leaves the smelting vessel. The partially combusted gas is sued to preheat and prereduced the ore before it is injected into the bath. There are several competing cokeless ironmaking processes in various stages of development around the world. A brief comparison of these processes provides a useful perspective with which to gauge the progress and objectives of the AISI-DOE research initiative. The principal competing foreign technologies include the Corex process, DIOS, HIsmelt, and Jupiter. The advantages of the direct ironmaking process examined by AISI-DOE were not sufficiently demonstrated to justify commercialization without further research. However, enough knowledge was gained from laboratory and pilot testing to teach researchers how to optimize the direct ironmaking process and to provide the foundation for future research. Researchers now better understand issues such as the dissolution of materials, reduction mechanisms and rates, slag foaming and control, the behavior of sulfur, dust generation, and the entire question of energy efficiency--including post combustion and the role of coal/volatile matter.

  19. Comminuting irradiated ferritic steel

    DOE Patents [OSTI]

    Bauer, Roger E. (Kennewick, WA); Straalsund, Jerry L. (Kennewick, WA); Chin, Bryan A. (Auburn, AL)

    1985-01-01T23:59:59.000Z

    Disclosed is a method of comminuting irradiated ferritic steel by placing the steel in a solution of a compound selected from the group consisting of sulfamic acid, bisulfate, and mixtures thereof. The ferritic steel is used as cladding on nuclear fuel rods or other irradiated components.

  20. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A.

    1988-06-01T23:59:59.000Z

    Today's commercially proved technology to recover oil from the Athabasca oil sands, as practiced by Suncor and Syncrude, involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil. Significant amounts of petroleum coke are produced during the bitumen upgrading process. Suncor burns the bulk of its petroleum coke in boilers to fulfill the energy requirements of the entire operation, still meeting government regulations restricting the amount of sulfur dioxide that can be released to the environment. In contrast, Syncrude is able to burn only 20% of its coke production because of high sulphur dioxide emissions from elsewhere in its operations. The boiler ash (Fly ash) which contains appreciable amounts of metals, such as vanadium, nickel, titianium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke fired steam generation plants. There has been relatively little effort made towards the understanding of the chemical or physical nature of these materials. Knowledge of the physico-chemical properties of these materials will be helpful in assessing their beneficiation and potential use as fuel or metallurigcal coke and the feasibility of extracting some metals, especially Ni and V. In this communication the authors report studies of acid demineralization as a means of reducing ash content of these materials for /sup 13/C NMR spectroscopic investigations.

  1. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

    2009-09-15T23:59:59.000Z

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  2. High productivity injection practices at Rouge Steel

    SciTech Connect (OSTI)

    Barker, D.H.; Hegler, G.L.; Falls, C.E. [Rouge Steel Co., Dearborn, MI (United States)

    1995-12-01T23:59:59.000Z

    Rouge Steel Company, located in Dearborn, Michigan, operates two blast furnaces. The smaller of the pair, ``B`` Furnace, has a hearth diameter of 20 feet and 12 tuyeres. It has averaged 2,290 NTHM (net ton of hot metal) per day of 8.2 NTHM per 100 cubic feet of working volume. ``C`` Furnace has a hearth diameter of 29 feet and 20 tuyeres. Both of these furnaces are single tap hole furnaces. Prior to its reline in 1991, ``C`` Furnace was producing at a rate of 3,300 NTHM/day or about 6.25 NTHM/100 cfwv. In November, 1994 it averaged 5,106 NTHM/day or 9.6 NTHM/100 cfwv. This paper discusses how the current production rates were achieved. Also, the areas that needed to be addressed as production increased will be described. These areas include casthouse arrangement and workload, hot metal ladle capacity, slag pot capacity and charging capability. Coupled with the high blast temperature capability, the furnace was provided with a new natural gas injection system that injected the gas through the blowpipes and a natural gas injection system to enrich the stove gas. Following the furnace reline, natural gas has been used in three ways: tuyere level control; combination injection; and stove gas enrichment. Coke consumption rate has also decreased per NTHM.

  3. Reduction of NO[sub x] emissions coke oven gas combustion process

    SciTech Connect (OSTI)

    Terza, R.R. (USS Clairton Works, PA (United States)); Sardesai, U.V. (Westfield Engineering and Services, Inc., Houston, TX (United States))

    1993-01-01T23:59:59.000Z

    The paper describes by-product processing at Clairton Works which uses a unique cryogenic technology. Modifications to the desulfurization facility, nitrogen oxide formation in combustion processes (both thermal and fuel NO[sub x]), and the boilers plants are described. Boilers were used to study the contribution of fuel NO[sub x] formation during the combustion of coke oven gas. Results are summarized. The modifications made to the desulfurization facility resulted in the overall H[sub 2]S emission being reduced by 2-4 grains/100scf and the NO[sub x] emission being reduced by 21-42% in the boiler stacks.

  4. Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine

    E-Print Network [OSTI]

    Yarbrough, Charles Michael

    1984-01-01T23:59:59.000Z

    J/'CA] volume rate of change [m /'CA) ? apparent rate of heat release [kJ/'CA] fuel air ratio [kg/kg] heat transfer coefficient [kJ/m 'K sec] ratio of specific heats connecting rod length [m] fuel lower heating value [kJ/kg] total mass of combustion gas...OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf...

  5. Use of a new microporous insulation in a sub car at Acme Steel

    SciTech Connect (OSTI)

    Harvey, H.; Gamble, F.C.; MacKenzie, I.B.

    1996-12-31T23:59:59.000Z

    Acme Steel Co. is a small integrated steel company headquartered in Riverdale IL., with its blast furnace and coke plant operations located in the city of Chicago. Rail transportation between the two plants is by Conrail with two crews assigned exclusively to Acme. The torpedo cars used for this service are specially reinforced, with 36 in. wheels and additional braking capability for safety on public rail tracks. Over a seven month period, microporous insulating panels 0.28 in. thick in No. 49 sub ladle saved an average 24 degrees in the iron on arrival at the BOF compared to the average for the rest of the fleet. The microporous insulation replaced 0.25 in. of compressed fiber panel.

  6. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  7. Methods of forming steel

    DOE Patents [OSTI]

    Branagan, Daniel J. (Iona, ID); Burch, Joseph V. (Shelley, ID)

    2001-01-01T23:59:59.000Z

    In one aspect, the invention encompasses a method of forming a steel. A metallic glass is formed and at least a portion of the glass is converted to a crystalline steel material having a nanocrystalline scale grain size. In another aspect, the invention encompasses another method of forming a steel. A molten alloy is formed and cooled the alloy at a rate which forms a metallic glass. The metallic glass is devitrified to convert the glass to a crystalline steel material having a nanocrystalline scale grain size. In yet another aspect, the invention encompasses another method of forming a steel. A first metallic glass steel substrate is provided, and a molten alloy is formed over the first metallic glass steel substrate to heat and devitrify at least some of the underlying metallic glass of the substrate.

  8. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  9. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27T23:59:59.000Z

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  10. A steel trap | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    physical and chemical interactions in metallic elements, such as the irradiated ODS steels used in this study. The APT work revealed clear images of the nanoclusters for...

  11. Petroleum Coke

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. IfProved(MillionPrice (Percent)82,516 82,971 84,053 85,190

  12. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office(BillionYearPricePrice (Percent)theCity

  13. Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking

    SciTech Connect (OSTI)

    Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

    2007-09-15T23:59:59.000Z

    1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

  14. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    19 3.4. Coking coal for iron & steels FOB export value for coking coal was relatively stables FOB export value for coking coal significantly increased

  15. The Cylinder: Kinematics of the Nineteenth Century

    E-Print Network [OSTI]

    Müller-Sievers, Helmut

    2012-01-01T23:59:59.000Z

    distillation. The coking of coal as well as the productionin coal mines, in steel and paper mills, in coking plants,

  16. Emerging Energy-efficiency and Carbon Dioxide Emissions-reduction Technologies for the Iron and Steel Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01T23:59:59.000Z

    effective use of non-coking coal and iron-bearing dust andfrom iron ore and non-coking coal. The process was developedBF production in using non-coking coal as reducing agent and

  17. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15T23:59:59.000Z

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  18. Summing up of discussion on improvement trends in coke-oven gas purification flowsheets

    SciTech Connect (OSTI)

    Zemblevskii, K.K.

    1983-01-01T23:59:59.000Z

    Reference is made to a previously published article that included flowsheets for purification of coke-oven gas. It is concluded that the flowsheets for a process using arsenic-soda and vacuum-carbonate methods of sulfur removal in which the gas is cooled to 303-308/sup 0/K are seriously in error. Schemes involving minor refrigeration, sulfur removal by the circulating ammonia method and ammonia recovery as ammonia liquor are seen as promising but in need of further improvement. One scheme discussed (the VUKhIN scheme) involves ammonia recovery by the circulating phosphate method and sulfur removal by the circulating ammonia method is seen as a replacement for the minor refrigeration method. Since liquid ammonia consumption in agriculture is continually increasing, schemes that result in production of liquid ammonia rather than ammonia liquor should be seriously considered.

  19. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  20. Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate

    SciTech Connect (OSTI)

    Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

    2004-07-01T23:59:59.000Z

    Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

  1. How Godzilla Ate Pittsburgh: The Long Rise of the Japanese Iron and Steel Industry, 1900–1973

    E-Print Network [OSTI]

    Bernard Elbaum

    2007-01-01T23:59:59.000Z

    poorly endowed as Japan in coking coal and iron ore (WarrenYawata of iron ore for coking coal and the progressive in-

  2. KONG, JIAN. Infrared-Based Temperature Measurement in Ceramics Grinding and Diesel Exhaust Aftertreatment Filters. (Under the direction of Albert J. Shih)

    E-Print Network [OSTI]

    Shih, Albert J.

    of the temperature distribution on the cavity wall surface in diesel exhaust aftertreatment filters usingABSTRACT KONG, JIAN. Infrared-Based Temperature Measurement in Ceramics Grinding and Diesel Exhaust Aftertreatment Filters. (Under the direction of Albert J. Shih) Non-contact remote-sensing radiation thermometry

  3. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  4. SOLOX coke-oven gas desulfurization ppm levels -- No toxic waste

    SciTech Connect (OSTI)

    Platts, M. (Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)); Tippmer, K. (Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany))

    1994-09-01T23:59:59.000Z

    For sulfur removal from coke-oven gas, the reduction/oxidation processes such as Stretford are the most effective, capable of removing the H[sub 2]S down to ppm levels. However, these processes have, in the past, suffered from ecological problems with secondary pollutant formation resulting from side reactions with HCN and O[sub 2]. The SOLOX gas desulfurization system is a development of the Stretford process in which the toxic effluent problems are eliminated by installing a salt decomposition process operating according to the liquid-phase hydrolysis principle. In this process, the gaseous hydrolysis products H[sub 2]S, NH[sub 3] and CO[sub 2] are returned to the untreated gas, and the regenerated solution is recycled to the absorption process. The blowdown from the absorption circuit is fed into a tube reactor where the hydrolysis process takes place. The toxic salts react with water, producing as reaction products the gases H[sub 2]S, NH[sub 3] and CO[sub 2], and the nontoxic salt Na[sub 2]SO[sub 4]. From the hydrolysis reactor the liquid stream flows into a fractionating crystallization plant. This plant produces a recycle stream of regenerated absorption solution and a second stream containing most of the Na[sub 2]SO[sub 4]. This second stream comprises the net plant waste and can be disposed of with the excess ammonia liquor or sprayed onto the coal.

  5. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

    2008-05-15T23:59:59.000Z

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  6. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  7. Ris-R-1244(EN) Tool Steels

    E-Print Network [OSTI]

    -resistant steels 18 5.5 Hot-work steels 18 5.6 Cold-work steels 19 5.7 High-speed steels (HSSs) 20 Appendix 1 and chromium) furthermore some steel types contains cobalt, which respectively raises the temperature at which.1 Water-hardening steels 17 5.2 Low-alloy special purpose steels 17 5.3 Mould steels 18 5.4 Shock

  8. DISTRIBUTED ENERGY SYSTEMS IN CALIFORNIA'S FUTURE: A PRELIMINARY REPORT, VOLUME I

    E-Print Network [OSTI]

    Authors, Various

    2010-01-01T23:59:59.000Z

    d The predominant use is coking coal for steel production.a,metallurgical grade coal for coking use in steel making (

  9. Clean steels for fusion

    SciTech Connect (OSTI)

    Gelles, D.S.

    1995-03-01T23:59:59.000Z

    Fusion energy production has an inherent advantage over fission: a fuel supply with reduced long term radioactivity. One of the leading candidate materials for structural applications in a fusion reactor is a tungsten stabilized 9% chromium Martensitic steel. This alloy class is being considered because it offers the opportunity to maintain that advantage in the reactor structure as well as provide good high temperature strength and radiation induced swelling and embrittlement resistance. However, calculations indicate that to obtain acceptable radioactivity levels within 500 years after service, clean steel will be required because the niobium impurity levels must be kept below about 2 appm and nickel, molybdenum, nitrogen, copper, and aluminum must be intentionally restricted. International efforts are addressing the problems of clean steel production. Recently, a 5,000 kg heat was vacuum induction melted in Japan using high purity commercial raw materials giving niobium levels less than 0.7 appm. This paper reviews the need for reduced long term radioactivity, defines the advantageous properties of the tungsten stabilized Martensitic steel class, and describes the international efforts to produce acceptable clean steels.

  10. Continuous steel production and apparatus

    DOE Patents [OSTI]

    Peaslee, Kent D. (Rolla, MO); Peter, Jorg J. (McMinnville, OR); Robertson, David G. C. (Rolla, MO); Thomas, Brian G. (Champaign, IL); Zhang, Lifeng (Trondheim, NO)

    2009-11-17T23:59:59.000Z

    A process for continuous refining of steel via multiple distinct reaction vessels for melting, oxidation, reduction, and refining for delivery of steel continuously to, for example, a tundish of a continuous caster system, and associated apparatus.

  11. a coarse grinding with recycling of the largest particles on the hammer-mill only led to a very small decrease in the digestibility of the main components of the diet. It had

    E-Print Network [OSTI]

    Boyer, Edmond

    - a coarse grinding with recycling of the largest particles on the hammer-mill only led to a very the utilization conditions of protein-rich peas in bacon pig feeding (PEREZ, LEUILLET, BOURDON, 1979) led

  12. Reaustenitisation from Bainite in Steels

    E-Print Network [OSTI]

    Takahashi, Manabu

    1993-03-16T23:59:59.000Z

    .7 APPLICATIONS . . . 1.7.1 Ferrite-Martensite dual phase steels 1.7.2 Steels containing some retained austenite 1.7.3 Welding of steels . . . . . . . . . . 1.7.4 Initial austenite grain size . . . . . . . 1.8 TRANSFORMATION FROM AUSTENITE 1.8.1 Widmanstiitten... is important in the production of dual phase steels which have a final microstructure of ferrite and about 20% martensite. These steels have a good combination of strength and uniform ductility, and find applications in the automobile industry. When a fully...

  13. Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector

    E-Print Network [OSTI]

    Xu, T.T.

    2011-01-01T23:59:59.000Z

    around 8-9% for good coking coal (IISI, 1982). Dryingof steam coal and coking coal to be $15/t (IEA, 1995). This

  14. Development and introduction of methods for extracting hydrogen sulfide and hydrogen cyanide from coke-oven gas

    SciTech Connect (OSTI)

    Litvinenko, M.S.; Zaichenko, V.M.

    1980-01-01T23:59:59.000Z

    The progress between 1933 and the present in desulfurizing coal gas from coke ovens and making use of the by-products to produce sulfuric acid, thioyanates, etc. is described. The vacuum carbonate process and the monoethanolamine method are apparently now preferred, but some plants are still using modified arsenic-soda processes. More recently additional by-products have been thiocyanates (for producing acrylonitrile fiber) and hydrogen xanthanates. The production of other organic sulfur and cyanide compounds has been investigated for use as herbicides, corrosion inhibitors, etc. (LTN)

  15. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-08-01T23:59:59.000Z

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  16. Process for dezincing galvanized steel

    DOE Patents [OSTI]

    Morgan, William A. (Hamilton, CA); Dudek, Frederick J. (Arlington Heights, IL); Daniels, Edward J. (Oak Lawn, IL)

    1998-01-01T23:59:59.000Z

    A process for removing zinc from galvanized steel. The galvanized steel is immersed in an electrolyte containing at least about 15% by weight of sodium or potassium hydroxide and having a temperature of at least about 75.degree. C. and the zinc is galvanically corroded from the surface of the galvanized steel. The material serving as the cathode is principally a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series. The corrosion rate may be accelerated by (i) increasing the number density of corrosion sites in the galvanized steel by mechanically abrading or deforming the galvanized steel, (ii) heating the galvanized steel to form an alloy of zinc on the surface of the galvanized steel, (iii) mixing the galvanized steel with a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series, or (iv) moving the galvanized steel relative to itself and to the electrolyte while immersed in the electrolyte.

  17. Sandia National Laboratories: stainless steel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stainless steel Sandia-California Partners with Japanese National Institute of Advanced Industrial Science and Technology (AIST) in Hydrogen-Materials Research On July 26, 2013, in...

  18. Process for dezincing galvanized steel

    DOE Patents [OSTI]

    Morgan, W.A.; Dudek, F.J.; Daniels, E.J.

    1998-07-14T23:59:59.000Z

    A process is described for removing zinc from galvanized steel. The galvanized steel is immersed in an electrolyte containing at least about 15% by weight of sodium or potassium hydroxide and having a temperature of at least about 75 C and the zinc is galvanically corroded from the surface of the galvanized steel. The material serving as the cathode is principally a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series. The corrosion rate may be accelerated by (1) increasing the number density of corrosion sites in the galvanized steel by mechanically abrading or deforming the galvanized steel, (2) heating the galvanized steel to form an alloy of zinc on the surface of the galvanized steel, (3) mixing the galvanized steel with a material having a standard electrode potential which is intermediate of the standard electrode potentials of zinc and cadmium in the electrochemical series, or (4) moving the galvanized steel relative to itself and to the electrolyte while immersed in the electrolyte. 1 fig.

  19. Spider Silk: Sronger than Steel? Nature's Supermaterial

    E-Print Network [OSTI]

    Powers, Alexander

    2013-01-01T23:59:59.000Z

    spider silk were as thick as a steel beam, it would be verysized and much heavier steel. In fact, it would take aboutstrength comparable to that of steel, about 1.5 gigapascals,

  20. Imagining Chivalry: Charles V's Suits of Steel

    E-Print Network [OSTI]

    Machado, Erin Jeannine

    2012-01-01T23:59:59.000Z

    Mail, German, 15 th century. Steel and brass. MetropolitanI. , Innsbruck, ca. 1512-14. Steel, gilded silver, velvet,Elector of Saxony, ca. 1555. Steel, copper alloy (brass),

  1. Startup and initial operation of a DFGD and pulse jet fabric filter system on Cokenergy's Indiana Harbor coke oven off gas system

    SciTech Connect (OSTI)

    Morris, W.J.; Gansley, R.R.; Schaddell, J.G.

    1999-07-01T23:59:59.000Z

    This paper describes the design, initial operation and performance testing of a Dry Flue Gas Desulfurization (DFGD) and Modular Pulse Jet Fabric Filter (MPJFF) system installed at Cokenergy's site in East Chicago, Indiana. The combined flue gas from the sixteen (16) waste heat recovery boilers is processed by the system to control emissions of sulfur dioxide and particulates. These boilers recover energy from coke oven off gas from Indiana Harbor Coke Company's coke batteries. The DFGD system consists of two 100% capacity absorbers. Each absorber vessel uses a single direct drive rotary atomizer to disperse the lime slurry for SO{sub 2} control. The MPJFF consists of thirty two (32) modules arranged in twin sixteen-compartment (16) units. The initial start up of the DFGD/MPJFF posed special operational issues due to the low initial gas flows through the system as the four coke oven batteries were cured and put in service for the first time. This occurred at approximately monthly intervals beginning in March 1998. A plan was implemented to perform a staged startup of the DFGD and MPJFF to coincide with the staged start up of the coke batteries and waste heat boilers. Operational issues that are currently being addressed include reliability of byproduct removal. Performance testing was conducted in August and September 1998 at the inlet of the system and the outlet stack. During these tests, particulate, SO{sub 2}, SO{sub 3}, and HCI emissions were measured simultaneously at the common DFGD inlet duct and the outlet stack. Measurements were also taken for average lime, water, and power consumption during the tests as well as system pressure losses. These results showed that all guarantee parameters were achieved during the test periods. The initial operation and performance testing are described in this paper.

  2. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect (OSTI)

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2009-03-15T23:59:59.000Z

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  3. Switch to duplex stainless steels

    SciTech Connect (OSTI)

    Quik, J.M.A.; Geudeke, M.

    1994-11-01T23:59:59.000Z

    Duplex stainless steels contain approximately equal proportions of ferrite and austenite. These stainless steels have become an established material of construction in the chemical process industries (CPI). Duplexes offer benefits over austenitic stainless steels and carbon steels because of their higher strength, and good toughness and ductility, in combination with equivalent resistance to general corrosion, as well as better resistance to localized corrosion and stress corrosion cracking. Additionally, duplex materials have thermal-conductivity and thermal-expansion coefficients similar to those of ferritic materials, are tough at low (sub-zero) temperatures, and have a high resistance to erosion and abrasion. In some of the highly corrosive environments encountered in the CPI, the super duplex stainless steels offer cost-effective options not possible with the standard austenitic stainless steels. The initial applications were almost exclusively as heat exchanger tubing in water-cooled service. In recent times, duplex stainless steels have been used in the oil, gas, and chemical industries. Examples include service in sweet and mildly sour corrosive environments, on offshore platforms where weight savings can be realized, and as a replacement for standard austenitic stainless steel in chemical-processing plants.

  4. Duplex Stainless Steels Margaret Gorog

    E-Print Network [OSTI]

    Das, Suman

    , substituted for 6% mo SS in bleach plant Hyper DSS, Offshore oil applications Super, Hyper ­ Corrosion11/14/2014 1 Duplex Stainless Steels Margaret Gorog Federal Way, WA Pulp and Paper Corrosion for suction rolls Duplex Stainless Steel · Improved corrosion and more importantly, stress corrosion cracking

  5. Influence of technological factors on statics of hydrogen sulfide absorption from coke-oven gas by the ammonia process

    SciTech Connect (OSTI)

    Nazarov, V.G.; Kamennykh, B.M.; Rus'yanov, N.D.

    1983-01-01T23:59:59.000Z

    The basic technological factors that determine the effectiveness of hydrogen sulfide absorption from coke-oven gas by the cyclic ammonia process are the initial H/sub 2/S content of the gas, the degree of purification, the absorption temperature and the NH/sub 3/ and CO/sub 2/ contents of the absorbent solution. The effects of these factors on the statics of hydrogen sulfide absorption are studied. The investigation is based on the phase-equilibrium distributions of components in the absorption-desorption gas-cleaning cycle. The mathematical model is presented which includes the solution of a system of chemical equilibrium equations for reactions in the solution, material balances, and electrical neutrality. 4 references, 5 figures, 1 table.

  6. Energy Flow Models for the Steel Industry 

    E-Print Network [OSTI]

    Hyman, B.; Andersen, J. P.

    1998-01-01T23:59:59.000Z

    each step is calibrated against Commerce Dept. data. Third, a detailed energy flow model is presented for coke ovens and blast furnaces, two very energy-intensive steps in our seven step model of steelmaking. This process-step model is calibrated...

  7. 2169 steel waveform experiments.

    SciTech Connect (OSTI)

    Furnish, Michael David; Alexander, C. Scott; Reinhart, William Dodd; Brown, Justin L.

    2012-11-01T23:59:59.000Z

    In support of LLNL efforts to develop multiscale models of a variety of materials, we have performed a set of eight gas gun impact experiments on 2169 steel (21% Cr, 6% Ni, 9% Mn, balance predominantly Fe). These experiments provided carefully controlled shock, reshock and release velocimetry data, with initial shock stresses ranging from 10 to 50 GPa (particle velocities from 0.25 to 1.05 km/s). Both windowed and free-surface measurements were included in this experiment set to increase the utility of the data set, as were samples ranging in thickness from 1 to 5 mm. Target physical phenomena included the elastic/plastic transition (Hugoniot elastic limit), the Hugoniot, any phase transition phenomena, and the release path (windowed and free-surface). The Hugoniot was found to be nearly linear, with no indications of the Fe - phase transition. Releases were non-hysteretic, and relatively consistent between 3- and 5-mm-thick samples (the 3 mm samples giving slightly lower wavespeeds on release). Reshock tests with explosively welded impactors produced clean results; those with glue bonds showed transient releases prior to the arrival of the reshock, reducing their usefulness for deriving strength information. The free-surface samples, which were steps on a single piece of steel, showed lower wavespeeds for thin (1 mm) samples than for thicker (2 or 4 mm) samples. A configuration used for the last three shots allows release information to be determined from these free surface samples. The sample strength appears to increase with stress from ~1 GPa to ~ 3 GPa over this range, consistent with other recent work but about 40% above the Steinberg model.

  8. ITP Steel: Energy Use in the U.S. Steel Industry: An Historical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Use in the U.S. Steel Industry: An Historical Perspective and Future Opportunities, September 2000 ITP Steel: Energy Use in the U.S. Steel Industry: An Historical...

  9. Climate VISION: Private Sector Initiatives: Iron and Steel: Resources...

    Office of Scientific and Technical Information (OSTI)

    Industry Associations American Iron and Steel Institute For over a century, North American steel producers have worked as partners and members of the American Iron and Steel...

  10. THE DEVELOPMENT OF MICROSTRUCTURE IN DUPLEX STAINLESS STEEL WELDS

    E-Print Network [OSTI]

    Cambridge, University of

    THE DEVELOPMENT OF MICROSTRUCTURE IN DUPLEX STAINLESS STEEL WELDS by Naseem Issa Abdallah Haddad;The Development of Microstructure in Duplex Stainless Steel Welds Abstract Duplex stainless steels

  11. Auto/Steel Partnership: AHSS Stamping, Strain Rate Characterization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AHSS Stamping, Strain Rate Characterization, Sheet Steel Fatigue, AHSS Joining AutoSteel Partnership: AHSS Stamping, Strain Rate Characterization, Sheet Steel Fatigue, AHSS...

  12. Nonlinear seismic response analysis of steel-concrete composite frames

    E-Print Network [OSTI]

    Barbato, Michele

    2008-01-01T23:59:59.000Z

    formulation of nonlinear steel- concrete composite beam ele-Behaviour of Composite Steel and Concrete Struc- turalE. (2001). “Analysis of steel-concrete composite frames with

  13. Iron and Steel Energy Intensities

    U.S. Energy Information Administration (EIA) Indexed Site

    If you are having trouble, call 202-586-8800 for help. Home > >Energy Users > Energy Efficiency Page > Iron and Steel Energy Intensities First Use of Energy Blue Bullet First Use...

  14. Great Lakes Steel -- PCI facility

    SciTech Connect (OSTI)

    Eichinger, F.T. [BMH Claudius Peters AG, Buxtehude (Germany); Dake, S.H.; Wagner, E.D.; Brown, G.S. [Raytheon Engineers and Constructors, Pittsburgh, PA (United States)

    1997-12-31T23:59:59.000Z

    This paper discusses the planning, design, and start-up of the 90 tph PCI facility for National Steel`s Great Lakes Steel Division in River Rouge, MI. This project is owned and operated by Edison Energy Services, and was implemented on a fast-track basis by Raytheon Engineers and Constructors, Babcock Material Handling, and Babcock and Wilcox. This paper presents important process issues, basic design criteria, an the challenges of engineering and building a state-of-the-art PCI facility in two existing plants. Pulverized coal is prepared at the River Rouge Power Plant of Detroit Edison, is pneumatically conveyed 6,000 feet to a storage silo at Great Lakes Steel, and is injected into three blast furnaces.

  15. Overlay welding irradiated stainless steel

    SciTech Connect (OSTI)

    Kanne, W.R.; Chandler, G.T.; Nelson, D.Z.; Franco-Ferreira, E.A.

    1993-08-01T23:59:59.000Z

    An overlay technique developed for welding irradiated stainless steel may be important for repair or modification of fusion reactor materials. Helium, present due to n,{alpha} reactions, is known to cause cracking using conventional welding methods. Stainless steel impregnated with 3 to 220 appm helium by decay of tritium was used to develop a welding process that could be used for repair. The result was a gas metal arc weld overlay technique with low-heat input and low-penetration into the helium-containing material. Extensive metallurgical and mechanical testing of this technique demonstrated substantial reduction of helium embrittlement damage. The overlay technique was applied to irradiated 304 stainless steel containing 10 appm helium. Surface cracking, present in conventional welds made on the same steel at lower helium concentrations, was eliminated. Underbead cracking, although greater than for tritium charged and aged material, was minimal compared to conventional welding methods.

  16. Welding tritium aged stainless steel

    SciTech Connect (OSTI)

    Kanne, W.R. Jr.

    1993-04-01T23:59:59.000Z

    Stainless steels exposed to tritium become unweldable by conventional methods due to He buildup within the metal matrix. With longer service lives expected for new weapon systems, and service life extensions of older systems, methods for welding/repair on tritium-exposed material will become important. Results are reported that indicate that both solid-state resistance welding and low-heat gas metal arc overlay welding are promising methods for repair or modification of tritium-aged stainless steel.

  17. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect (OSTI)

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2007-07-01T23:59:59.000Z

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  18. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2005-12-01T23:59:59.000Z

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  19. Influence of low and high temperature coking of H-GaMFI propane aromatization catalyst on its surface and catalytic properties

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Devadas, P. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1997-03-01T23:59:59.000Z

    H-Gallosilicate (MFI) (i.e., H-GaMFI) zeolite shows high activity/selectivity in the aromatization of lower alkanes, which is processes of treat practical importance. The high aromatization activity of this catalyst is attributed to its high dehydrogenation activity due to the presence of high dispersed nonframework Ga-oxide species (which are formed during hydrothermal synthesis and/or pretreatments to the zeolite) along with the zeolitic acid sites (or framework Ga), resulting in a bifunctional catalyst. However, this zeolite undergoes fast catalyst deactivation in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization at 500-550{degrees}C for a short time-on-stream (10 h). It is interesting to know the effect of catalyst deactivation due to coking in the propane aromatization for much longer periods both at low (at 400{degrees}C) and high (at 550{degrees}C) temperatures on the product selectivity and also on the surface (viz., sorption capacity, acidity/acid strength distribution) and catalytic properties of the zeolite. The present investigation was undertaken for this purpose. 16 refs., 1 fig., 3 tabs.

  20. India Energy Outlook: End Use Demand in India to 2020

    E-Print Network [OSTI]

    de la Rue du Can, Stephane

    2009-01-01T23:59:59.000Z

    5% of its reserve is coking coal used by the steel industry.imports around 70% of coking coal annually. More recently,

  1. Saturation in ``nonmagnetic'' stainless steel C. Weber and J. Fajansa)

    E-Print Network [OSTI]

    Fajans, Joel

    Saturation in ``nonmagnetic'' stainless steel C. Weber and J. Fajansa) Department of Physics July 1998 Scientific equipment often uses ``nonmagnetic'' stainless steel, relying on the steel's nonmagnetic behavior to leave external magnetic fields unaltered. However, stainless steel's permeability can

  2. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J. [Chester Environmental, Moon Township, PA (United States)

    1995-12-01T23:59:59.000Z

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  3. STEEL STRUCTURES FOR BUILDING IN CHINA PROF. HE MINGXUAN

    E-Print Network [OSTI]

    Cambridge, University of

    STEEL STRUCTURES FOR BUILDING IN CHINA PROF. HE MINGXUAN VICE-PRESIDENT OF CHINA STEEL CONSTRUCTION SOCIETY CHIEF ENGINEER OF BAOSTEEL CONSTRUCTION CO., LTD JULY 6, 2012 LONDON #12;1. STEEL AND STEEL STRUCTURES IN CHINA 2. SOME PROJECTS OF STEEL STRUCTURES FOR HIGH- RISE BUILDINGS IN CHINA #12;STEEL

  4. STUDENT STEEL BRIDGE COMPETITION The mission of the Student Steel Bridge Competition (SSBC) is to supplement

    E-Print Network [OSTI]

    Duchowski, Andrew T.

    1 STUDENT STEEL BRIDGE COMPETITION 2012 RULES #12;2 MISSION The mission of the Student Steel Bridge in a steel structure that meets client specifications and optimizes performance and economy. The SSBC are stimulated to innovate, practice professionalism, and use structural steel efficiently. WELCOME ASCE and AISC

  5. Energy Consumption and Potential for Energy Conservation in the Steel Industry 

    E-Print Network [OSTI]

    Hughes, M. L.

    1979-01-01T23:59:59.000Z

    percent (weight basis) of the input coal is converted to blast furnace coke and coke breeze and the remaining 30 percent is converted to coke oven gas, tar and li~t oils. A number of chemicals are extracted from these streams, and in at least two... in the world are identical. In the iron-ore reduction process there are three separate operations: blast furnaces, ore agglomerating facilities other than the mine-site preparation previously mentioned, and coke ovens -- the blast furnaces being the central...

  6. STEEL: RECENT PUBLICATIONS HAMPSON, G. J., STEEL, R. J., BURGESS,

    E-Print Network [OSTI]

    Yang, Zong-Liang

    , eds., Atlas of Deepwater Outcrops, American Assoc. Petrol. Geol. Studies in Geology 56 YOSHIDA, S of Deepwater Outcrops, American Assoc. Petrol. Geol. Studies in Geology 56 MCLAURIN, B. & STEEL, R. J. (2006 on an Eocene shelf margin, Central Basin, Spitsbergen. Bull. Am. Assoc. Petrol. Geol. 90, 1451-72. #12;

  7. Superplastic deformation in two microduplex stainless steels

    SciTech Connect (OSTI)

    Lesuer, D.R.; Nieh, T.G.; Syn, C.K. [Lawrence Livermore National Lab., CA (United States); Taleff, E.M. [Texas Univ., Austin, TX (United States)

    1996-09-01T23:59:59.000Z

    The deformation behavior and mechanisms of superplastic flow in two microduplex stainless steels (SuperDux64 and Nitronic 19D) were studied at {similar_to}0.7T{sub m}. The two steels differed in initial grain size by a factor of 3. Both steels exhibited solute-drag-controlled grain boundary sliding in a high temperature {gamma}+{delta} phase field. In a lower temperature {gamma}+{sigma} phase field, the fine-grained steel ({bar L}=5{mu}m) exhibited climb-controlled grain boundary sliding and the coarser- grained steel ({bar L}=15{mu}m) exhibited solute-drag-controlled slip creep.

  8. 60 Years of duplex stainless steel applications

    SciTech Connect (OSTI)

    Olsson, J.; Liljas, M. [Avesta Sheffield AB, Avesta (Sweden)

    1994-12-31T23:59:59.000Z

    In this paper the history of wrought duplex stainless steel development and applications is described. Ferritic-austenitic stainless steels were introduced only a few decades after stainless steels were developed. The paper gives details from the first duplex stainless steels in the 1930`s to the super duplex stainless steel development during the 1980`s. During the years much effort has been devoted to production and welding metallurgy as well as corrosion research of the duplex stainless steels. Therefore, duplex stainless steels are to-day established in a wide product range. Numerous important applications are exemplified. In most cases the selection of a duplex steel has been a result of the combination high strength excellent corrosion resistance. In the pulp and paper industry the most interesting use is as vessel material in digesters. For chemical process industry, the duplex steels are currently used in heat exchangers. The largest application of duplex steels exists in the oil and gas/offshore industry. Hundreds of kms of pipelines are installed and are still being installed. An increased use of duplex steels is foreseen in areas where the strength is of prime importance.

  9. Steel project fact sheet: Steel reheating for further processing

    SciTech Connect (OSTI)

    NONE

    1998-04-01T23:59:59.000Z

    Steel reheating is an energy-intensive process requiring uniform temperature distribution within reheating furnaces. Historically, recuperators have ben used to preheat combustion air, thereby conserving energy. More recent innovations include oxygen enrichment and the use of regenerative burners, which provide higher preheat air temperatures than recuperators. These processes have limitations such as equipment deterioration, decreasing energy efficiency over time, high maintenance costs, and increased NO{sub x} emissions with increased air preheat temperature, unless special equipment is used. Praxair, Inc., supplier of oxygen and other industrial gases to the steel industry, proposes to introduce an innovative oxy-fuel burner technology (using 100% oxygen) to the steel reheating industry. Oxy-fuel combustion reduces or eliminates nitrogen in combustion air and substantially reduces waste heat carried out with flue gas. Based on technology currently used in the glass, hazardous waste, and aluminum industries, Praxair has developed and patented low temperature, oxy-fuel burners that can be used in high temperature industrial furnaces where temperature uniformity is critical and extremely low NO{sub x} emissions are desired. The technical goal of the project is to demonstrate the use of oxy-fuel burners in a slab reheat furnace while reducing energy consumption by 45% and NO{sub x} emissions by 90% within the converted furnace zones. Successful implementation of this technology also will eliminate the need to periodically replace recuperators and install NO{sub x} removal equipment.

  10. Duplex stainless steel: From specialty to commodity

    SciTech Connect (OSTI)

    Quick, J.M.A.; Geudeke, M. [Shell Internationale Petroleum Mij. B.V., The Hague (Netherlands)

    1994-12-31T23:59:59.000Z

    Important applications of duplex stainless steel in the oil and chemical industry date from the seventies. Duplex stainless steel is attractive because it combines high mechanical strength, about the same as for carbon steel, and good corrosion resistance particularly against chloride stress corrosion cracking up to about 100 C. This paper highlights a number of examples that are typical for the potential as well as the problems associated with this type of material.

  11. Improving the toughness of ultrahigh strength steel

    E-Print Network [OSTI]

    Soto, Koji

    2002-01-01T23:59:59.000Z

    of the low-alloy steels used in aerospace applications. Thisalloys of each category and their compositions are shown in Table 1.1 with their Aerospace

  12. HYDROGEN EMBRITTLEMENT IN LOW CARBON STEEL

    E-Print Network [OSTI]

    Rafiq A. Siddiqui; Sabah A. Abdul-wahab; Tasneem Pervez; Sayyad Z. Qamar

    Many metals and alloys absorb hydrogen and diffusion of hydrogen under certain conditions can seriously weaken and produces embrittlement in steel. Hydrogen embrittlement is a type of metal deterioration that is related to stress corrosion cracking. Although steels are well known for their susceptibility to hydrogen embrittlement, the mechanism of transportation of hydrogen is not very clear in low carbon steels. Standard tensile steel specimens were hydrogenated from 1 to 5 hours and deformed by cold worked to 50%,60%,70 % 80 % and were investigated for mechanical properties.

  13. MICROSTRUCTURE AND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE PRECIPITATES

    E-Print Network [OSTI]

    Gau, J.S.

    2014-01-01T23:59:59.000Z

    and Properties of Dual-Phase Steels, R. A. Kot and J. W.of Niobium Microalloyed Dual- Phase Steel, MetallurgicalAND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE

  14. FERRITE STRUCTURE AND MECHANICAL PROPERTIES OF LOW ALLOY DUPLEX STEELS

    E-Print Network [OSTI]

    Hoel, R.H.

    2013-01-01T23:59:59.000Z

    and Properties of Dual-Phase Steels, R. A. Kot and J. W.Formable HSLA and Dual Phase Steels, A. T. Davenport, ed. ,Formable HSLA and Dual Phase Steels, A. T. Davenport, ed. ,

  15. Mag-Foot: a steel bridge inspection robot

    E-Print Network [OSTI]

    Asada, Harry

    A legged robot that moves across a steel structure is developed for steel bridge inspection. Powerful permanent magnets imbedded in each foot allow the robot to hang from a steel ceiling powerlessly. Although the magnets ...

  16. Blast damage mitigation of steel structures from near- contact charges

    E-Print Network [OSTI]

    Wolfson, Janet Crumrine

    2008-01-01T23:59:59.000Z

    Depth 6.5 in. 6.5 in. 3 in. .625 in. 1.5 in. Material SteelSteelAluminum Steel Polyurethane Weight 472 lb 472 lb 73 lb 45 lb

  17. PROTON INDUCED SWELLING IN TYPE 316 STAINLESS STEEL

    E-Print Network [OSTI]

    Srivastava, A.K.

    2010-01-01T23:59:59.000Z

    an Austenitic Stainless Steel, USAEC Report ORNL-4580, Oakin Austenitic Stainless Steel, Ref. 5, p. 142. D. I. R.Irradiated 304 Stainless Steel, Ref. 5, p. 499. Table 1.

  18. CRAD, Nuclear Facility Construction - Structural Steel, May 29...

    Broader source: Energy.gov (indexed) [DOE]

    Steel, May 29, 2009 CRAD, Nuclear Facility Construction - Structural Steel, May 29, 2009 May 29, 2009 Nuclear Facility Construction - Structural Steel (HSS CRAD 64-16, Rev. 0) This...

  19. Overview: STEEL Auto/Steel Partnership | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in ManyDepartmentOutreachDepartment ofProgram |Department ofAuto/Steel

  20. ITP Steel: Steel Industry Energy Bandwidth Study October 2004

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy Petroleum Technology Vision 2020 ITPandSteel Industry

  1. ITP Steel: Steel Industry Marginal Opportunity Study September 2005 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy Petroleum Technology Vision 2020 ITPandSteel

  2. ITP Steel: Theoretical Minimum Energies to Produce Steel for Selected

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet),Energy Petroleum Technology Vision 2020 ITPandSteelConditions,

  3. annealed stainless steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: of stainless steel container materials is a potential problem for long-term radioactive waste storage-to-failure of relevant stainless steels in the annealed...

  4. BACKGROUND GLOBAL STEEL OVERCAPACITY and OIL COUNTRY TUBULAR...

    Broader source: Energy.gov (indexed) [DOE]

    surging-steel-imports Strong trade enforcement is especially critical in the market for oil country tubular goods (OCTG), the pipe and steel products used for energy exploration....

  5. advanced bar steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This thesis is devoted to the numerical investigation of mechanical behavior of Dual phase (DP) steels. Such grade of advanced high strength steels (AHSS) is favorable to the...

  6. Friction Stir Spot Welding of Advanced High Strength Steels II...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steels II Friction Stir Spot Welding of Advanced High Strength Steels II 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer...

  7. Development of Steel Fastener Nano-Ceramic Coatings for Corrosion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium Parts (AMD-704) Development of Steel Fastener Nano-Ceramic Coatings for Corrosion Protection of Magnesium...

  8. Climate VISION: Private Sector Initiatives: Iron and Steel: GHG...

    Office of Scientific and Technical Information (OSTI)

    GHG Inventory Protocols Principles for a Steel Industry Methodology for Reporting Carbon-Related Energy Sources and Raw Materials (PDF 48 KB) Download Acrobat Reader Steel Industry...

  9. Monitoring of Fracture Cri0cal Steel Bridges

    E-Print Network [OSTI]

    Minnesota, University of

    #12;Monitoring of Fracture Cri0cal Steel Bridges: Acous0c Emission Sensors system on other fracture cri0cal steel bridges #12;Project Impact #12;Thank

  10. alloy tool steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of weldments of a high strength low alloy(HSLA) steel in a simulated seawater environment. This steel, designated HSLA80, was developed by the United ... Needham, William...

  11. Process for separating, especially in multiple stages, acid components such as CO/sub 2/, HCN and specifically H/sub 2/S, from gases, especially from coke oven gases, by means of ammonia recirculation scrubbing

    SciTech Connect (OSTI)

    Bauer, H.K.; Otte, E.A.W.

    1984-10-16T23:59:59.000Z

    A process of separating in multiple stages acid components in coke oven gas such as CO/sub 2/, HCN and particularly H/sub 2/S by ammonia scrubbing wherein the ammonia used in scrubbing is deacidified to remove the acid components and is recirculated to the scrubbing process at least in part as substantially pure liquid ammonia.

  12. Method for welding chromium molybdenum steels

    DOE Patents [OSTI]

    Sikka, Vinod K. (Clinton, TN)

    1986-01-01T23:59:59.000Z

    Chromium-molybdenum steels exhibit a weakening after welding in an area adjacent to the weld. This invention is an improved method for welding to eliminate the weakness by subjecting normalized steel to a partial temper prior to welding and subsequently fully tempering the welded article for optimum strength and ductility.

  13. A recycling process for dezincing steel scrap

    SciTech Connect (OSTI)

    Dudek, F.J.; Daniels, E.J. (Argonne National Lab., IL (United States)); Morgan, W.A.; Kellner, A.W.; Harrison, J. (Metal Recovery Industries, Inc., Hamilton, ON (Canada))

    1992-01-01T23:59:59.000Z

    In response to the several-fold increase in consumption of galvanized steel in the last decade and the problems associated with refurnacing larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zinc from galvanized ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is electrowon as dendritic powder. The process is effective for zinc, lead, aluminum, and cadmium removal on loose and baled scrap and on all types of galvanized steel. The process has been pilot tested for batch treatment of 1,000 tons of mostly baled scrap. A pilot plant to continuously treat loose scrap is under construction. Use of degalvanized steel scrap decreases raw materials and environmental compliance costs to steel- and iron-makers, may enable integrated steel producers to recycle furnace dusts to the sinter plant, and may enable EAF production of flat products without use of DRI or pig iron. Recycling the components of galvanized steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap.

  14. A recycling process for dezincing steel scrap

    SciTech Connect (OSTI)

    Dudek, F.J.; Daniels, E.J. [Argonne National Lab., IL (United States); Morgan, W.A.; Kellner, A.W.; Harrison, J. [Metal Recovery Industries, Inc., Hamilton, ON (Canada)

    1992-08-01T23:59:59.000Z

    In response to the several-fold increase in consumption of galvanized steel in the last decade and the problems associated with refurnacing larger quantities of galvanized steel scrap, a process is being developed to separate and recover the steel and zinc from galvanized ferrous scrap. The zinc is dissolved from the scrap in hot caustic using anodic assistance and is electrowon as dendritic powder. The process is effective for zinc, lead, aluminum, and cadmium removal on loose and baled scrap and on all types of galvanized steel. The process has been pilot tested for batch treatment of 1,000 tons of mostly baled scrap. A pilot plant to continuously treat loose scrap is under construction. Use of degalvanized steel scrap decreases raw materials and environmental compliance costs to steel- and iron-makers, may enable integrated steel producers to recycle furnace dusts to the sinter plant, and may enable EAF production of flat products without use of DRI or pig iron. Recycling the components of galvanized steel scrap saves primary energy, decreases zinc imports, and adds value to the scrap.

  15. Interaction between stainless steel and plutonium metal

    SciTech Connect (OSTI)

    Dunwoody, John T [Los Alamos National Laboratory; Mason, Richard E [Los Alamos National Laboratory; Freibert, Franz J [Los Alamos National Laboratory; Willson, Stephen P [Los Alamos National Laboratory; Veirs, Douglas K [Los Alamos National Laboratory; Worl, Laura A [Los Alamos National Laboratory; Archuleta, Alonso [Los Alamos National Laboratory; Conger, Donald J [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    Long-term storage of excess plutonium is of great concern in the U.S. as well as abroad. The current accepted configuration involves intimate contact between the stored material and an iron-bearing container such as stainless steel. While many safety scenario studies have been conducted and used in the acceptance of stainless steel containers, little information is available on the physical interaction at elevated temperatures between certain forms of stored material and the container itself. The bulk of the safety studies has focused on the ability of a package to keep the primary stainless steel containment below the plutonium-iron eutectic temperature of approximately 410 C. However, the interactions of plutonium metal with stainless steel have been of continuing interest. This paper reports on a scoping study investigating the interaction between stainless steel and plutonium metal in a pseudo diffusion couple at temperatures above the eutectic melt-point.

  16. Recovery of iron, carbon and zinc from steel plant waste oxides using the AISI-DOE postcombustion smelting technology

    SciTech Connect (OSTI)

    Sarma, B. [Praxair, Inc., Tarrytown, NY (United States); Downing, K.B. [Fluor Daniel, Greenville, SC (United States); Aukrust, E.

    1996-09-01T23:59:59.000Z

    This report describes a process to recover steel plant waste oxides to be used in the production of hot metal. The process flowsheet used at the pilot plant. Coal/coke breeze and iron ore pellets/waste oxides are charged into the smelting reactor. The waste oxides are either agglomerated into briquettes (1 inch) using a binder or micro-agglomerated into pellets (1/4 inch) without the use of a binder. The iron oxides dissolve in the slag and are reduced by carbon to produce molten iron. The gangue oxides present in the raw materials report to the slag. Coal charged to the smelter is both the fuel as well as the reductant. Carbon present in the waste oxides is also used as the fuel/reductant resulting in a decrease in the coal requirement. Oxygen is top blown through a central, water-cooled, dual circuit lance. Nitrogen is injected through tuyeres at the bottom of the reactor for stirring purposes. The hot metal and slag produced in the smelting reactor are tapped at regular intervals through a single taphole using a mudgun and drill system. The energy requirements of the process are provided by (i) the combustion of carbon to carbon monoxide, referred to as primary combustion and (ii) the combustion of CO and H{sub 2} to CO{sub 2} and H{sub 2}O, known as postcombustion.

  17. Automated Steel Cleanliness Analysis Tool (ASCAT)

    SciTech Connect (OSTI)

    Gary Casuccio (RJ Lee Group); Michael Potter (RJ Lee Group); Fred Schwerer (RJ Lee Group); Dr. Richard J. Fruehan (Carnegie Mellon University); Dr. Scott Story (US Steel)

    2005-12-30T23:59:59.000Z

    The objective of this study was to develop the Automated Steel Cleanliness Analysis Tool (ASCATTM) to permit steelmakers to evaluate the quality of the steel through the analysis of individual inclusions. By characterizing individual inclusions, determinations can be made as to the cleanliness of the steel. Understanding the complicating effects of inclusions in the steelmaking process and on the resulting properties of steel allows the steel producer to increase throughput, better control the process, reduce remelts, and improve the quality of the product. The ASCAT (Figure 1) is a steel-smart inclusion analysis tool developed around a customized next-generation computer controlled scanning electron microscopy (NG-CCSEM) hardware platform that permits acquisition of inclusion size and composition data at a rate never before possible in SEM-based instruments. With built-in customized ''intelligent'' software, the inclusion data is automatically sorted into clusters representing different inclusion types to define the characteristics of a particular heat (Figure 2). The ASCAT represents an innovative new tool for the collection of statistically meaningful data on inclusions, and provides a means of understanding the complicated effects of inclusions in the steel making process and on the resulting properties of steel. Research conducted by RJLG with AISI (American Iron and Steel Institute) and SMA (Steel Manufactures of America) members indicates that the ASCAT has application in high-grade bar, sheet, plate, tin products, pipes, SBQ, tire cord, welding rod, and specialty steels and alloys where control of inclusions, whether natural or engineered, are crucial to their specification for a given end-use. Example applications include castability of calcium treated steel; interstitial free (IF) degasser grade slag conditioning practice; tundish clogging and erosion minimization; degasser circulation and optimization; quality assessment/steel cleanliness; slab, billet or bloom disposition; and alloy development. Additional benefits of ASCAT include the identification of inclusions that tend to clog nozzles or interact with refractory materials. Several papers outlining the benefits of the ASCAT have been presented and published in the literature. The paper entitled ''Inclusion Analysis to Predict Casting Behavior'' was awarded the American Iron and Steel Institute (AISI) Medal in 2004 for special merit and importance to the steel industry. The ASCAT represents a quantum leap in inclusion analysis and will allow steel producers to evaluate the quality of steel and implement appropriate process improvements. In terms of performance, the ASCAT (1) allows for accurate classification of inclusions by chemistry and morphological parameters, (2) can characterize hundreds of inclusions within minutes, (3) is easy to use (does not require experts), (4) is robust, and (5) has excellent image quality for conventional SEM investigations (e.g., the ASCAT can be utilized as a dual use instrument). In summary, the ASCAT will significantly advance the tools of the industry and addresses an urgent and broadly recognized need of the steel industry. Commercialization of the ASCAT will focus on (1) a sales strategy that leverages our Industry Partners; (2) use of ''technical selling'' through papers and seminars; (3) leveraging RJ Lee Group's consulting services, and packaging of the product with a extensive consulting and training program; (4) partnering with established SEM distributors; (5) establishing relationships with professional organizations associated with the steel industry; and (6) an individualized plant by plant direct sales program.

  18. Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part II. Recovery of Ammonia from Sour Waters

    E-Print Network [OSTI]

    Poole, L.J.

    2008-01-01T23:59:59.000Z

    Oil Shale Retorting Sour Waters from Petroleum Refining Sour Waters from Coking Operations in the Iron and Steel Industry

  19. Microstructural characterization in dissimilar friction stir welding between 304 stainless steel and st37 steel

    SciTech Connect (OSTI)

    Jafarzadegan, M. [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of) [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of); State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China); Feng, A.H. [State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China)] [State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China); Abdollah-zadeh, A., E-mail: zadeh@modares.ac.ir [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of); Saeid, T. [Advanced Materials Research Center, Sahand University of Technology, P.O. Box: 51335-1996, Tabriz (Iran, Islamic Republic of)] [Advanced Materials Research Center, Sahand University of Technology, P.O. Box: 51335-1996, Tabriz (Iran, Islamic Republic of); Shen, J. [State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China)] [State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China); Assadi, H. [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of)] [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of)

    2012-12-15T23:59:59.000Z

    In the present study, 3 mm-thick plates of 304 stainless steel and st37 steel were welded together by friction stir welding at a welding speed of 50 mm/min and tool rotational speed of 400 and 800 rpm. X-ray diffraction test was carried out to study the phases which might be formed in the welds. Metallographic examinations, and tensile and microhardness tests were used to analyze the microstructure and mechanical properties of the joint. Four different zones were found in the weld area except the base metals. In the stir zone of the 304 stainless steel, a refined grain structure with some features of dynamic recrystallization was evidenced. A thermomechanically-affected zone was characterized on the 304 steel side with features of dynamic recovery. In the other side of the stir zone, the hot deformation of the st37 steel in the austenite region produced small austenite grains and these grains transformed to fine ferrite and pearlite and some products of displacive transformations such as Widmanstatten ferrite and martensite by cooling the material after friction stir welding. The heat-affected zone in the st37 steel side showed partially and fully refined microstructures like fusion welding processes. The recrystallization in the 304 steel and the transformations in the st37 steel enhanced the hardness of the weld area and therefore, improved the tensile properties of the joint. - Highlights: Black-Right-Pointing-Pointer FSW produced sound welds between st37 low carbon steel and 304 stainless steel. Black-Right-Pointing-Pointer The SZ of the st37 steel contained some products of allotropic transformation. Black-Right-Pointing-Pointer The material in the SZ of the 304 steel showed features of dynamic recrystallization. Black-Right-Pointing-Pointer The finer microstructure in the SZ increased the hardness and tensile strength.

  20. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01T23:59:59.000Z

    AND MICROSTRUCTURES OF DUAL PHASE STEELS CONTAINING SILICON,and Microstructures of Dual Phase Steels Containing Silicon,microstructures of selected dual-phase steels in which the

  1. EFFECTS OF MORPHOLOGY ON THE MECHANICAL BEHAVIOR OF DUAL PHASE Fe/Si/C STEELS

    E-Print Network [OSTI]

    Kim, N.J.

    2012-01-01T23:59:59.000Z

    and ductility in dual phase steels. However, it seems thatmechanical behavior of dual phase steels. ACKNOWLEDGEMENTSL INTRODUCTION Dual phase steels whose structures consist of

  2. THE EROSION BEHAVIOR OF STEEL AS A FUNCTION OF MICROSTRUCTURE ON SOLID PARTICLE EROSION

    E-Print Network [OSTI]

    Levy, Alan V.

    2013-01-01T23:59:59.000Z

    of the spheroidized 1075 steel by rolling prior to erosionAbrasive Wear Resistance of Steels. A Review, ~Jear, FIGUREelectron micrographs of 1075 steel in the coarse pearlite,

  3. Beam Energy Scaling on Ion-Induced Electron Yield from K+ Impact on Stainless Steel

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    K + Impact on Stainless Steel Michel Kireeff Covo Lawrence+ ions hit the stainless steel target with energy up to 400energies hitting stainless steel target obtained from

  4. Testing and analysis of structural steel columns subjected to blast loads

    E-Print Network [OSTI]

    Stewart, Lauren K.

    2010-01-01T23:59:59.000Z

    Blast Simulator Testing of Steel Columns and Components. ”Testing of Structural Steel Columns. ” 8 th Internationaland Analysis of Structural Steel Columns Subjected to Blast

  5. A direct displacement-based design of low-rise seismic resistant steel moment frames

    E-Print Network [OSTI]

    Harris, John L.

    2006-01-01T23:59:59.000Z

    The Bending Resistance of Steel Beams. ” J. Struct. Div. ,in the Design of Steel Structures. ” Engineering715- American Institute of Steel Construction (AISC) (2001).

  6. Cyclic behavior and design of steel columns subjected to large drift

    E-Print Network [OSTI]

    Newell, James David

    2008-01-01T23:59:59.000Z

    The Bending Resistance of Steel Beams,” Journal of the2007). “Bolted Flange Plate Steel Moment Connections forSeismic Upgrade of a 15-Story Steel Moment Frame Building –

  7. Lightweight Steel Solutions for Automotive Industry

    SciTech Connect (OSTI)

    Lee, Hong Woo; Kim, Gyosung; Park, Sung Ho [Technical Research Laboratories, POSCO, 699, Gumho-dong, Gwangyang-si, Jeonnam, 545-090 (Korea, Republic of)

    2010-06-15T23:59:59.000Z

    Recently, improvement in fuel efficiency and safety has become the biggest issue in worldwide automotive industry. Although the regulation of environment and safety has been tightened up more and more, the majority of vehicle bodies are still manufactured from stamped steel components. This means that the optimized steel solutions enable to demonstrate its ability to reduce body weight with high crashworthiness performance instead of expensive light weight materials such as Al, Mg and composites. To provide the innovative steel solutions for automotive industry, POSCO has developed AHSS and its application technologies, which is directly connected to EVI activities. EVI is a technical cooperation program with customer covering all stages of new car project from design to mass production. Integrated light weight solutions through new forming technologies such as TWB, hydroforming and HPF are continuously developed and provided for EVI activities. This paper will discuss the detailed status of these technologies especially light weight steel solutions based on innovative technologies.

  8. Case hardenable nickel-cobalt steel

    DOE Patents [OSTI]

    Qian, Yana (Sunnyvale, CA); Olson, Gregory B. (Evanston, IL)

    2012-04-17T23:59:59.000Z

    An advanced secondary hardening carburized Ni--Co steel achieves an improved case hardness of about 68-69 Rc together with nominal core hardness of about 50 Rc.

  9. Light Steel Framing: Improving the Integral Design 

    E-Print Network [OSTI]

    Amundarain, Aitor; Torero, Jose L; Usmani, Asif; Al-Remal, Ahmad M

    2006-09-11T23:59:59.000Z

    Light Steel Framing has been extensively used in cold climate countries due to its good thermal and structural behaviour. Improved thermal behaviour results in positive environmental impact essential for sustainable ...

  10. Transformation Strain and Crystallographic Texture in Steels

    E-Print Network [OSTI]

    Kundu, Saurabh

    Transformation Strain and Crystallographic Texture in Steels By Saurabh Kundu Darwin College, Cambridge University of Cambridge Department of Materials Science and Metallurgy Pembroke Street, Cambridge CB2 3QZ A dissertation submitted for the degree... , Crystallographic tex- ture of stress-affected bainite, Proceedings of the Royal Society of London A, (submitted). Saurabh Kundu March, 2007 ii Acknowledgments I am grateful to the EPSRC, UK and TATA STEEL, India for funding this project. I would also like to thank...

  11. Microstructural studies of advanced austenitic steels

    SciTech Connect (OSTI)

    Todd, J. A.; Ren, Jyh-Ching [University of Southern California, Los Angeles, CA (USA). Dept. of Materials Science

    1989-11-15T23:59:59.000Z

    This report presents the first complete microstructural and analytical electron microscopy study of Alloy AX5, one of a series of advanced austenitic steels developed by Maziasz and co-workers at Oak Ridge National Laboratory, for their potential application as reheater and superheater materials in power plants that will reach the end of their design lives in the 1990's. The advanced steels are modified with carbide forming elements such as titanium, niobium and vanadium. When combined with optimized thermo-mechanical treatments, the advanced steels exhibit significantly improved creep rupture properties compared to commercially available 316 stainless steels, 17--14 Cu--Mo and 800 H steels. The importance of microstructure in controlling these improvements has been demonstrated for selected alloys, using stress relaxation testing as an accelerated test method. The microstructural features responsible for the improved creep strengths have been identified by studying the thermal aging kinetics of one of the 16Ni--14Cr advanced steels, Alloy AX5, in both the solution annealed and the solution annealed plus cold worked conditions. Time-temperature-precipitation diagrams have been developed for the temperature range 600 C to 900 C and for times from 1 h to 3000 h. 226 refs., 88 figs., 10 tabs.

  12. Development of Steel Foam Materials and Structures

    SciTech Connect (OSTI)

    Kenneth Kremer; Anthony Liszkiewicz; James Adkins

    2004-10-20T23:59:59.000Z

    In the past few years there has been a growing interest in lightweight metal foams. Demands for weight reduction, improved fuel efficiency, and increased passenger safety in automobiles now has manufacturers seriously considering the use of metal foams, in contrast to a few years ago, when the same materials would have been ruled out for technical or economical reasons. The objective of this program was to advance the development and use of steel foam materials, by demonstrating the advantages of these novel lightweight materials in selected generic applications. Progress was made in defining materials and process parameters; characterization of physical and mechanical properties; and fabrication and testing of generic steel foam-filled shapes with compositions from 2.5 wt.% to 0.7 wt.% carbon. A means of producing steel foam shapes with uniform long range porosity levels of 50 to 60 percent was demonstrated and verified with NDE methods. Steel foam integrated beams, cylinders and plates were mechanically tested and demonstrated advantages in bend stiffness, bend resistance, and crush energy absorption. Methods of joining by welding, adhesive bonding, and mechanical fastening were investigated. It is important to keep in mind that steel foam is a conventional material in an unconventional form. A substantial amount of physical and mechanical properties are presented throughout the report and in a properties database at the end of the report to support designer's in applying steel foam in unconventional ways.

  13. Irradiation Assisted Grain Boundary Segregation in Steels

    SciTech Connect (OSTI)

    Lu, Zheng; Faulkner, Roy G. [IPTME, Loughborough University, Loughborough, Leics (United Kingdom)

    2008-07-01T23:59:59.000Z

    The understanding of radiation-induced grain boundary segregation (RIS) has considerably improved over the past decade. New models have been introduced and much effort has been devoted to obtaining comprehensive information on segregation from the literature. Analytical techniques have also improved so that chemical analysis of layers 1 nm thick is almost routine. This invited paper will review the major methods used currently for RIS prediction: namely, Rate Theory, Inverse Kirkendall, and Solute Drag approaches. A summary is made of the available data on phosphorus RIS in reactor pressure vessel (RPV) steels. This will be discussed in the light of the predictions of the various models in an effort to show which models are the most reliable and easy to use for forecasting P segregation behaviour in steels. A consequence of RIS in RPV steels is a radiation induced shift in the ductile to brittle transition temperature (DBTT). It will be shown how it is possible to relate radiation-induced P segregation levels to DBTT shift. Examples of this exercise will be given for RPV steels and for ferritic steels being considered for first wall fusion applications. Cr RIS in high alloy stainless steels and associated irradiation-assisted stress corrosion cracking (IASCC) will be briefly discussed. (authors)

  14. Nickel-free duplex stainless steels

    SciTech Connect (OSTI)

    Wang, J.; Uggowitzer, P.J.; Magdowski, R.; Speidel, M.O. [ETH-Zentrum, Zurich (Switzerland). Inst. of Metallurgy] [ETH-Zentrum, Zurich (Switzerland). Inst. of Metallurgy

    1998-12-04T23:59:59.000Z

    It is well known that nitrogen-alloying in steel produces a variety of exceptional properties such as high strength, high ductility and, eventually, resistance to stress corrosion cracking. High-nitrogen steels (HNS), therefore, have recently been developed to enhance the strength and corrosion resistance of stainless steels. However, due to a low solubility of nitrogen in a liquid steel under atmospheric pressure, the production of such high-nitrogen alloys needs high-pressure facilities that cause an extra cost. A possible route of developing high-nitrogen alloys under atmospheric pressure is to choose a duplex microstructure, where the amount of austenite and ferrite phase is nearly equal. A much lower nitrogen content is needed to maintain a 50% austenite phase compared with the necessary addition of nitrogen to reach a 100% austenitic microstructure. In addition, duplex stainless steels (DSS) with 40--60% ferrite can significantly improve the SCC-resistance. The objective of this work was to develop a new group of nickel-free, high strength and corrosion resistant DSS. Nickel was completely replaced by nitrogen in order to enhance SCC resistance and reduce the alloying element cost. The microstructure, mechanical properties, corrosion resistance and cost analysis of new alloys are investigated in comparison with some commercial stainless steels.

  15. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

    2010-07-13T23:59:59.000Z

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  16. Development of Next Generation Heating System for Scale Free Steel Reheating

    SciTech Connect (OSTI)

    Dr. Arvind C. Thekdi

    2006-09-26T23:59:59.000Z

    Teh report describes methods of reheating of steel billets and slabs for hot rolling or forging without forming steel scale.

  17. Dislocation substructure in fatigued duplex stainless steel

    SciTech Connect (OSTI)

    Polak, J. (Ecole Centrale de Lille, Villeneuve d'Ascq (France). Lab. de Mecanique de Lille Inst. of Physical Metallurgy, Brno (Czechoslovakia). Academy of Sciences); Degallaix, S. (Ecole Centrale de Lille, Villeneuve d'Ascq (France). Lab. de Mecanique de Lille); Kruml, T. (Inst. of Physical Metallurgy, Brno (Czechoslovakia). Academy of Sciences)

    1993-12-15T23:59:59.000Z

    Cyclic plastic straining of crystalline materials results in the formation of specific dislocation structures. Considerable progress in mapping and understanding internal dislocation structures has been achieved by studying single crystal behavior: however, most structural materials have a polycrystalline structure and investigations of polycrystals in comparison to single crystal behavior of simple metals prove to be very useful in understanding more complex materials. There are some classes of materials, however, with complicated structure which do not have a direct equivalent in single crystalline form. Moreover, the specific dimensions and shapes of individual crystallites play an important role both in the cyclic stress-strain response of these materials and in the formation of their interior structure in cyclic straining. Austenitic-ferritic duplex stainless steel, which is a kind of a natural composite, is a material of this type. The widespread interest in the application of duplex steels is caused by approximately doubled mechanical properties and equal corrosion properties, when compared with classical austenitic stainless steels. Fatigue resistance of these steels as well as the surface damage evolution in cyclic straining have been studied; however, much less is known about the internal substructure development in cyclic straining. In this study the dislocation arrangement in ferritic and austenitic grains of the austenitic-ferritic duplex steel alloyed with nitrogen and cyclically strained with two strain amplitudes, is reported and compared to the dislocation arrangement found in single and polycrystals of austenitic and ferritic materials of a similar composition and with the surface relief produced in cyclic plastic straining.

  18. Laminar inclusions of duplex stainless steels

    SciTech Connect (OSTI)

    Hudson, M.E. [Fluor Daniel Canada Inc., Calgary, Alberta (Canada)

    1993-12-31T23:59:59.000Z

    Duplex Stainless Steel have been utilized in the offshore petrochemical industries for over twenty years. The steels are normally manufactured to produce a 50:50 duplex austenitic and ferritic microstructure. The microstructure yields the benefits of high strength, corrosion resistance and low thermal expansion. While constructing a high pressure header box for an air cooled heat exchanger, linear indications were observed along the weld preparation faces. These laminations were parallel to the plate surfaces, reminiscent to oxide inclusions found in carbon steel plates manufactured 20 years ago. Concern over premature failure at the highly stressed corner joints resulted in the rejection of the plates. A metallurgical investigation followed. From scanning electron microscopy and energy dispersive x-ray, the indications were shown to be rich in Cr, Mn and Si. The inclusions occurred during steel manufacturing and were most likely due to incorrect removal of oxides at the top of the ingot and/or the exclusion of a secondary remelting process. New plates were ordered with tighter production controls on steel processing. The plates were ultrasonically inspected prior to fabrication and no further problems were discovered.

  19. Electrodynamics in Iron and Steel

    E-Print Network [OSTI]

    John Paul Wallace

    2009-06-03T23:59:59.000Z

    In order to calculate the reflected EM fields at low amplitudes in iron and steel, more must be understood about the nature of long wavelength excitations in these metals. A bulk piece of iron is a very complex material with microstructure, a split band structure, magnetic domains and crystallographic textures that affect domain orientation. Probing iron and other bulk ferromagnetic materials with weak reflected and transmitted inductive low frequency fields is an easy operation to perform but the responses are difficult to interpret because of the complexity and variety of the structures affected by the fields. First starting with a simple single coil induction measurement and classical EM calculation to show the error is grossly under estimating the measured response. Extending this experiment to measuring the transmission of the induced fields allows the extraction of three dispersion curves which define these internal fields. One dispersion curve yielded an exceedingly small effective mass of 1.8 10^{-39}kg (1.3 10^{-9} m_e) for those spin waves. There is a second distinct dispersion curve more representative of the density function of a zero momentum bound state rather than a propagating wave. The third dispersion curve describes a magneto-elastic coupling to a very long wave length propagating mode. These experiments taken together display the characteristics of a high temperature Bose-Einstein like condensation that can be initiated by pumping two different states. A weak time dependent field drives the formation of coupled J=0 spin wave pairs with the reduced effective mass reflecting the increased size of the coherent state. These field can dominate induction measurements well past the Curie temperature.

  20. austenitic steel tp: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  1. afa stainless steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  2. austenitic steels reaction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  3. a 285 steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 46...

  4. aisi steel vliyanie: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 203 Flexural...

  5. aisi 316l steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 238 Flexural...

  6. activation austenitic steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  7. austenitic stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  8. aisi h13 steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 209 Flexural...

  9. austenitic steels approche: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  10. alloy steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 357 Flexural...

  11. alloy steel weldment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 370 Flexural...

  12. austenitic steels wirkung: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  13. aisi-304 stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  14. area stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  15. austenitic steel aisi: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  16. austenitic steels final: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  17. algeciras spain steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 311 Flexural...

  18. activation ferritic steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  19. activation ferritic steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  20. aged stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  1. austenitic stainless steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  2. austenitic steel irradiated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  3. alloy steel exposed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 434 Flexural...

  4. aisi52100 hardened steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 324 Flexural...

  5. austenitic steel type: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude 120 Flexural...

  6. austenite stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  7. austenitic steels amorcage: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  8. austenitic steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  9. alloy steel primary: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut, Claude First Page Previous Page...

  10. austenitic steels irradiated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  11. austentic stainless steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    problem, namely, learning to control a steel mill. By applying BOXES to a model of a skinpass mill (a type of steel mill), we find that the BOXES algorithm can be made Sammut,...

  12. Climate VISION: Private Sector Initiatives: Iron and Steel: Results

    Office of Scientific and Technical Information (OSTI)

    and the Energy Information Agency website for updates. Read the U.S. Steel Industry Energy Efficiency Fact Sheet (PDF 83 KB) Download Acrobat Reader Read Steel Is The New...

  13. Transformation induced plasticity assisted steels: stress or strain affected martensitic

    E-Print Network [OSTI]

    Cambridge, University of

    Transformation induced plasticity assisted steels: stress or strain affected martensitic transformation? S. Chatterjee and H. K. D. H. Bhadeshia* Transformation induced plasticity (TRIP) assisted steels contain a small quantity of carbon enriched retained austenite, which transforms into martensite during

  14. First Structural Steel Erected at NSLS-II

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    Ten steel columns were incorporated into the ever-growing framework for the National Synchrotron Light Source II last week, the first structural steel erected for the future 400,000-square-foot facility.

  15. advanced ferritic steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    behavior of ferrite and dual phase steels Engineering Websites Summary: and dual phase steels C.F. Kuang a,n , J. Li b , S.G. Zhang a , J. Wang b , H.F. Liu b , A.A....

  16. alloy ferritic steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    behavior of ferrite and dual phase steels Engineering Websites Summary: and dual phase steels C.F. Kuang a,n , J. Li b , S.G. Zhang a , J. Wang b , H.F. Liu b , A.A....

  17. advanced ferritic steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    behavior of ferrite and dual phase steels Engineering Websites Summary: and dual phase steels C.F. Kuang a,n , J. Li b , S.G. Zhang a , J. Wang b , H.F. Liu b , A.A....

  18. Friction Stir Spot Welding of Advanced High Strength Steels ...

    Energy Savers [EERE]

    Stir Spot Welding of Advanced High Strength Steels (AHSS) Friction Stir Spot Welding of Advanced High Strength Steels (AHSS) Presentation from the U.S. DOE Office of Vehicle...

  19. Structural Reliability of Bridges Elevated with Steel Pedestals

    E-Print Network [OSTI]

    Bisadi, Vahid 1980-

    2012-09-19T23:59:59.000Z

    seismic regions using statistical tests. Then, to provide a general framework, which can be applied to all bridges that are elevated with steel pedestals, this dissertation develops probabilistic capacity and demand models for steel pedestals considering...

  20. Cartwright on Causality: Methods, Metaphysics, and Modularity Daniel Steel

    E-Print Network [OSTI]

    Steel, Daniel

    Cartwright on Causality: Methods, Metaphysics, and Modularity Daniel Steel Department of Philosophy 503 S Kedzie Hall Michigan State University East Lansing, MI 48824-1032 USA Email: steel@msu.edu #12

  1. G odel's legacy in set theory John R. Steel

    E-Print Network [OSTI]

    Koellner, Peter

    GË? odel's legacy in set theory John R. Steel University of California, Berkeley August 2006 1 #12 generalizes the theory of L, has been developed. (Silver, Kunen, Mitchell, Dodd, Jensen, Martin, Steel, Woodin

  2. Must a Bayesian Accept the Likelihood Principle? Daniel Steel

    E-Print Network [OSTI]

    Fitelson, Branden

    Must a Bayesian Accept the Likelihood Principle? Daniel Steel Department of Philosophy 503 S. Kedzie Hall Michigan State University East Lansing, MI 48824-1032 Email: steel@msu.edu #12;1 1

  3. Inductive Rules, Background Knowledge, and Skepticism Daniel Steel

    E-Print Network [OSTI]

    Steel, Daniel

    Inductive Rules, Background Knowledge, and Skepticism Daniel Steel Department of Philosophy 503 S. Kedzie Hall Michigan State University East Lansing, MI 48823-1032 Email: steel@msu.edu #12;Abstract

  4. Enhanced Inclusion Removal from Steel in the Tundish

    SciTech Connect (OSTI)

    R. C. Bradt; M.A.R. Sharif

    2009-09-25T23:59:59.000Z

    The objective of this project was to develop an effective chemical filtering system for significantly reducing the content of inclusion particles in the steel melts exiting the tundish for continuous casting. This project combined a multi-process approach that aimed to make significant progress towards an "inclusion free" steel by incorporating several interdependent concepts to reduce the content of inclusions in the molten steel exiting the tundish for the caster. The goal is to produce "cleaner" steel.

  5. The anisotropic fatigue behaviour of forged steel ETIENNE PESSARDa

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . This variation has been reported as being 35% for 42CrMo4 steel [7] and 15% for a duplex stainless steel [4] From in the matrix. For instance, Mateo and Lütjering [3-4] showed that for a duplex stainless steel and an aluminium(°)/D(0°) Mateo Duplex Stainless Steel Yield Stress= 610MPa Lütjering Al 7475 Yield Stress= 450MPa

  6. Auto/Steel Partnership: Hydroforming Materials and Lubricant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lightweight Rear Chassis Structures Future Generation Passenger Compartment AutoSteel Partnership: Hydroforming Materials and Lubricant Lightweight Rear Chassis Structures...

  7. Iron and steel industry process model

    SciTech Connect (OSTI)

    Sparrow, F.T.; Pilati, D.; Dougherty, T.; McBreen, E.; Juang, L.L.

    1980-01-01T23:59:59.000Z

    The iron and steel industry process model depicts expected energy-consumption characteristics of the iron and steel industry and ancillary industries for the next 25 years by means of a process model of the major steps in steelmaking, from ore mining and scrap recycling to the final finishing of carbon, alloy, and stainless steel into steel products such as structural steel, slabs, plates, tubes, and bars. Two plant types are modeled: fully integrated mills and mini-mills. User-determined inputs into the model are as follows: projected energy and materials prices; projected costs of capacity expansion and replacement; energy-conserving options, both operating modes and investments; the internal rate of return required on investment; and projected demand for finished steel. Nominal input choices in the model for the inputs listed above are as follows: National Academy of Sciences Committee on Nuclear and Alternative Energy Systems Demand Panel nominal energy-price projections for oil, gas, distillates, residuals, and electricity and 1975 actual prices for materials; actual 1975 costs; new technologies added; 15% after taxes; and 1975 actual demand with 1.5%/y growth. The model reproduces the base-year (1975) actual performance of the industry; then, given the above nominal input choices, it projects modes of operation and capacity expansion that minimize the cost of meeting the given final demands for each of 5 years, each year being the midpoint of a 5-year interval. The output of the model includes the following: total energy use and intensity (Btu/ton) by type, by process, and by time period; energy conservation options chosen; utilization rates for existing capacity; capital-investment decisions for capacity expansion.

  8. Corrosion of carbon steels, stainless steels, and titanium in aqueous lithium bromide solution

    SciTech Connect (OSTI)

    Guinon, J.L.; Garcia-Anton, J.; Perez-Herranz, V. (Univ. Politecnica de Valencia (Spain). Dept. de Ingenieria Quimica y Nuclear); Lacoste, G. (ENSIGC, Toulouse (France))

    1994-03-01T23:59:59.000Z

    Effects of lithium bromide (LiBr) concentration, pH, temperature, exposure time, and the action of some inhibitors on corrosion of several carbon (C) steels, stainless steels (SS), and a titanium (Ti) alloy were studied. Corrosion rates were determined by the polarization resistance method and compared to rates determined by weight-loss measurements. Pitting potentials (E[sub p]) were evaluated in neutral LiBr solution and with different inhibitors. Pit density and average pit depth depended on the metal tested, with lowest values for Ti, the next lowest values for type 316 SS (UNS S31600), and the highest values for UNS G41350 tempered steel.

  9. CE 4990 -Construction Scheduling Week 1: Steel Frame Project

    E-Print Network [OSTI]

    Mukherjee, Amlan

    CE 4990 - Construction Scheduling Week 1: Steel Frame Project Fall 2011 January 13, 2012 Introduction You are a construction manager for a project to build a steel frame for an office building1 of 964 pre-fabricated structural steel members will be used in the construction. The standard bay size

  10. Model coupling friction and adhesion for steel-concrete interfaces

    E-Print Network [OSTI]

    Boyer, Edmond

    Model coupling friction and adhesion for steel- concrete interfaces Michel Raous Laboratoire de: In this paper the interface behaviour between steel and concrete, during pull out tests, is numerically a variable friction coefficient in order to simulate the behaviour of the steel-concrete interface during

  11. Water Modeling of Steel Flow, Air Entrainment and Filtration

    E-Print Network [OSTI]

    Beckermann, Christoph

    Water Modeling of Steel Flow, Air Entrainment and Filtration Christoph Beckermann Associate Beckermann, C., "Water Modeling of Steel Flow, Air Entrainment and Filtration," in Proceedings of the 46th, 1992. #12;Abstract This paper presents an analysis of water modeling of steel pouring to study (1) air

  12. 1D subsurface electromagnetic fields excited by energized steel casing

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    1D subsurface electromagnetic fields excited by energized steel casing Wei Yang1 , Carlos Torres the possibility of enabling steel-cased wells as galvanic sources to detect and quantify spatial variations of electrical conductivity in the subsurface. The study assumes a vertical steel-cased well that penetrates

  13. Reuse of steel and aluminium without melting

    E-Print Network [OSTI]

    Cooper, Daniel

    2014-01-07T23:59:59.000Z

    -of-life metal components that could be reused for each product, the catalogue formed the basis of a set of semi-structured interviews with industrial experts. The results suggest that approximately 30% of steel and aluminium used in current products could... Allwood J.M., Cullen J.M., Cooper D.R., Milford R.L., Patel A.C.H., Carruth M.A., McBrien M., 2010. Conserving our metal energy: avoiding melting steel and aluminium scrap to save energy and carbon. University of Cambridge, ISBN 978-0-903428-30-9 Allwood...

  14. Carbon Diffusion Across Dissimilar Steel Welds

    E-Print Network [OSTI]

    Race, Julia Margaret

    1992-12-08T23:59:59.000Z

    CrMo 0.056 0.40 0.77 0.010 0.012 1.11 0.44 0.035 0.015 lCr1MolV 0.13 0.23 0.50 0.033 0.055 0.41 0.58 0.25 0.252 2 4 Table 1.2: Typical compositions of the commonly used high strength low alloy steels. 1.3.2 High Cr ferritie steels Increasing...

  15. The Signifance of Retained Austenite in Steels

    E-Print Network [OSTI]

    Bhadeshia, H K D H

    1980-02-05T23:59:59.000Z

    . Introduction 90 2. Experimental Method and Techniques 91 3. Results and Discussion 92 4. Summary 94 VIII. An Analysis o£ the Mechanical Properties and Microstructure o£ a High-Silicon Dual-Phase Steel 1. Introduction 2. De£ormation Models 3. Experimental... £ects such that the extent o£ twinning was the greatest when adjacent martensite units had twin-related lattices. The thermodynamics o£ dislocated martensites have been briefly examined, The inhomogeneous de£ormation behaviour o£ dual-phase steels has been analysed in terms...

  16. The corrosion of some stainless steels in a marine mud

    SciTech Connect (OSTI)

    Francis, R.; Byrne, G. [Weir Materials and Foundries Park Works, Manchester (United Kingdom); Campbell, H.S. [Univ. of Surrey (United Kingdom). Dept. of Materials Science and Engineering

    1999-11-01T23:59:59.000Z

    The report presents the results for three alloys: carbon steel, 316L stainless steel and a proprietary super duplex stainless steel (UNS S32760), exposed in a marine mud off the south coast of England for 5 years. Analysis of the mud showed it to be very aggressive using a corrosion index developed at the University of Manchester. Carbon steel showed a typical corrosion rate for microbial attack with pits up to 0.64mm deep. The 316L stainless steel had extensive broad, shallow attack with a few, deeper pits. The Z100 parent pipe and weldments showed no evidence of corrosion attack.

  17. Microstructural Evolution in Power Plant Steels

    E-Print Network [OSTI]

    Cambridge, University of

    energy of the steam is converted to electrical energy by a system of turbines and a generator. Figure 2 temperature as possible. Progress in power-plant alloy design has allowed T1 to be increased from 370 C Steels Pump Cooling water Cooling water Electrical output Condenser Reheat Coal Boiler Superheater Ash HP

  18. Extraordinary Ductility in Albearing TRIP Steel

    E-Print Network [OSTI]

    Cambridge, University of

    .K. Abstract An iron­based alloy system has been developed which exhibits impressive combina- tions of tensile is research in progress on the stronger steels in order to enhance ductility and assess other engineering cooling transformation (DeCooman, 2004; Jacques, 2004; Matsumura et al., 1987a,b; Sakuma et al., 1991

  19. Weldment for austenitic stainless steel and method

    DOE Patents [OSTI]

    Bagnall, Christopher (Hempfield, PA); McBride, Marvin A. (Hempfield, PA)

    1985-01-01T23:59:59.000Z

    For making defect-free welds for joining two austenitic stainless steel mers, using gas tungsten-arc welding, a thin foil-like iron member is placed between the two steel members to be joined, prior to making the weld, with the foil-like iron member having a higher melting point than the stainless steel members. When the weld is formed, there results a weld nugget comprising melted and then solidified portions of the joined members with small portions of the foil-like iron member projecting into the solidified weld nugget. The portions of the weld nugget proximate the small portions of the foil-like iron member which project into the weld nugget are relatively rich in iron. This causes these iron-rich nugget portions to display substantial delta ferrite during solidification of the weld nugget which eliminates weld defects which could otherwise occur. This is especially useful for joining austenitic steel members which, when just below the solidus temperature, include at most only a very minor proportion of delta ferrite.

  20. The Steel Market Today And Tomorrow

    E-Print Network [OSTI]

    Eagar, Thomas W.

    a liability as a benefit. Mature Industry Many observers suggest that the metals industry is based on old straddled the traditional metals industries, as well as the newer "high technol- ogy'' industries, the claim problems have been solved." For example, the scrap rate for the steel industry is extremely low, esp~ dally

  1. Must we use ferritic steel in TBM?

    SciTech Connect (OSTI)

    Salavy, Jean-Francois; Boccaccini, Lorenzo V.; Chaudhuri, Paritosh; Cho, Seungyon; Enoeda, Mikio; Giancarli, Luciano; Kurtz, Richard J.; Luo, Tian Y.; Rao, K. Bhanu Sankara; Wong, Clement

    2010-12-13T23:59:59.000Z

    Mock-ups of DEMO breeding blankets, called Test Blanket Modules (TBMs), inserted and tested in ITER in dedicated equatorial ports directly facing the plasma, are expected to provide the first experimental answers on the necessary performance of the corresponding DEMO breeding blankets. Several DEMO breeding blanket designs have been studied and assessed in the last 20 years. At present, after considering various coolant and breeder combinations, all the TBM concepts proposed by the seven ITER Parties use Reduced-Activation Ferritic/Martensitic (RAFM) steel as the structural material. In order to perform valuable tests in ITER, the TBMs are expected to use the same structural material as corresponding DEMO blankets. However, due to the fact that this family of steels is ferromagnetic, their presence in the ITER vacuum vessel will create perturbations of the ITER magnetic fields that could reduce the quality of the plasma confinement during H-mode. As a consequence, a legitimate question has been raised on the necessity of using RAFM steel for TBMs structural material in ITER. By giving a short description of the main TBM testing objectives in ITER and assessing the consequences of not using such a material, this paper gives a comprehensive answer to this question. According to the working group author of the study, the use of RAFM steel as structural material for TBM is judged mandatory.

  2. Energy Flow Models for the Steel Industry

    E-Print Network [OSTI]

    Hyman, B.; Andersen, J. P.

    Energy patterns in the U. S. steel industry are examined using several models. First is an end-use model based on data in the 1994 Manufacturing Energy Consumption Survey (MECS). Then a seven-step process model is presented and material flow through...

  3. Transformation texture of allotriomorphic ferrite in steel

    E-Print Network [OSTI]

    Cambridge, University of

    Transformation texture of allotriomorphic ferrite in steel D. W. Kim1 , R. S. Qin1 and H. K. D. H into that of the product is mathematically defined. This is not the case when the ferrite forms by a reconstructive mechanism. The allotriomorphic ferrite nucleates heterogeneously at austenite grain boundaries, and although

  4. Avoid stainless steel failures in FGD systems

    SciTech Connect (OSTI)

    Mills, J.P.; Schillmoller, C.M.

    1995-11-01T23:59:59.000Z

    Preventing pitting and localized corrosion is the key to success where low maintenance and high reliability are rime considerations in flue-gas desulfurization (FGD) designs. Knowing when to use a stainless steel, and when not to, is crucial. Operating parameters and environmental factors greatly affect alloy performance, especially pH, temperature, and chloride and oxygen levels. Failures of stainless steels can be avoided by understanding their limits in light of these variables. This article will focus on the capabilities of Types 316L, 317L, 317LM, 317LMN, 904L, and 6% Mo stainless steels and their applications, as well as provide details on unique combination of mechanical properties and corrosion resistance of the 22% Cr duplex and 25% Cr super-duplex stainless steels in acid chloride systems. Guidelines will be presented on methods to prevent intergranular corrosion, stress corrosion cracking, and pitting and crevice corrosion, and what process steps can be taken to assure reasonable performance of marginal alloy selections. Emphasis will be on the lime/limestone wet scrubbing process and the quencher/absorber.

  5. Modelling of Simultaneous Transformations in Steels

    E-Print Network [OSTI]

    Cambridge, University of

    submitted for the degree of Doctor of Philosophy Department of Materials Science and Metallurgy Univesity of Professor H. K. D. H. Bhadeshia in the Department of Materi- als Science and Metallurgy, University in the proceedings of the conference on New Development on Metallurgy and Applications of High Strength Steels

  6. Modelling Precipitation of Carbides in Martensitic Steels

    E-Print Network [OSTI]

    Cambridge, University of

    of Materials Science and Metallurgy, University of Cambridge, between October 2000 and November 2003. Except facilities in the Department of Materials Science and Metallurgy at the University of Cambridge. I would like of the physical metallurgy of secondary hardening steels and the phenomena of hydrogen embrittlement and hydrogen

  7. Mechanical Behavior and Microstructural Development of Low-Carbon Steel and Microcomposite Steel Reinforcement Bars Deformed under Quasi-Static and Dynamic Shear Loading

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    pp. 66–77. 44. G. Krauss: Steels: Processing, Structure, andConf. Super High Strength Steels, AIM, Rome, Italy, 2005,cation for Epoxy-Coated Steel Reinforcing Bars,’’ Annual

  8. Crack stability analysis of low alloy steel primary coolant pipe

    SciTech Connect (OSTI)

    Tanaka, T.; Kameyama, M. [Kansai Electric Power Company, Osaka (Japan); Urabe, Y. [Mitsubishi Heavy Industries, Ltd., Takasago (Japan)] [and others

    1997-04-01T23:59:59.000Z

    At present, cast duplex stainless steel has been used for the primary coolant piping of PWRs in Japan and joints of dissimilar material have been applied for welding to reactor vessels and steam generators. For the primary coolant piping of the next APWR plants, application of low alloy steel that results in designing main loops with the same material is being studied. It means that there is no need to weld low alloy steel with stainless steel and that makes it possible to reduce the welding length. Attenuation of Ultra Sonic Wave Intensity is lower for low alloy steel than for stainless steel and they have advantageous inspection characteristics. In addition to that, the thermal expansion rate is smaller for low alloy steel than for stainless steel. In consideration of the above features of low alloy steel, the overall reliability of primary coolant piping is expected to be improved. Therefore, for the evaluation of crack stability of low alloy steel piping to be applied for primary loops, elastic-plastic future mechanics analysis was performed by means of a three-dimensioned FEM. The evaluation results for the low alloy steel pipings show that cracks will not grow into unstable fractures under maximum design load conditions, even when such a circumferential crack is assumed to be 6 times the size of the wall thickness.

  9. Microscale investigation of the corrosion performances of low-carbon and stainless steels in highly alkaline concretes

    E-Print Network [OSTI]

    Itty, Pierre-Adrien

    2012-01-01T23:59:59.000Z

    FILM FORMED ON DUPLEX STAINLESS STEEL IN HIGHLY ALKALINEouter-layer. On duplex stainless steel (UNS S32101), theto corrosion. Finally, duplex stainless steels contain both

  10. Performance of steel-polymer and ceramic-polymer layered composites and concrete under high strain rate loadings

    E-Print Network [OSTI]

    Samiee, Ahsan

    2010-01-01T23:59:59.000Z

    Performance of Steel-Polyurea Bi-layers Subjected to Impul-Performance of Steel-Polymer-Steel Sandwich Structures Sub- jected to Impulsive

  11. Fabrication procedure effects on fatigue resistance of rib -to-deck welded joints of steel orthotropic bridge decks

    E-Print Network [OSTI]

    Sim, Hyoung-Bo

    2010-01-01T23:59:59.000Z

    details of orthotropic steel deck. ” Proc. , Internationalnew approaches to fatigue evaluation of steel bridges. ”International Journal of Steel Structures, KSSC, Vol. 6, No.

  12. Micromechanisms of ductile fracturing of DH-36 steel plates under impulsive loads and influence of polyurea reinforcing

    E-Print Network [OSTI]

    Amini, M. R.; Nemat-Nasser, S.

    2010-01-01T23:59:59.000Z

    of ductile fracturing of DH-36 steel plates under impulsiveductile fracturing of DH-36 steel plates subjected to blast-microstructure of the deformed steel samples also revealed

  13. Broadening the Statistical Search for Metal Price Super Cycles to Steel and Related Metals

    E-Print Network [OSTI]

    Broadening the Statistical Search for Metal Price Super Cycles to Steel and Related Metals of industrial development and urbanization: steel, pig iron, and molybdenum (a key ingredient in many steel's (2008) econometric search for super cycles in metals prices to our `steel group', defined here as steel

  14. Steel Creek fish: L-Lake/Steel Creek Biological Monitoring Program, January 1986--December 1987

    SciTech Connect (OSTI)

    Paller, M.H.; Heuer, J.H.; Kissick, L.A.

    1988-03-01T23:59:59.000Z

    Fish samples were collected from Steel Creek during 1986 and 1987 following the impoundment of the headwaters of the stream to form L-Lake, a cooling reservoir for L-Reactor which began operating late in 1985. Electrofishing and ichthyoplankton sample stations were located throughout the creek. Fykenetting sample stations were located in the creek mouth and just above the Steel Creek swamp. Larval fish and fish eggs were collected with 0.5 m plankton nets. Multivariate analysis of the electrofishing data suggested that the fish assemblages in Steel Creek exhibited structural differences associated with proximity to L-Lake, and habitat gradients of current velocity, depth, and canopy cover. The Steel Creek corridor, a lotic reach beginning at the base of the L-Lake embankment was dominated by stream species and bluegill. The delta/swamp, formed where Steel Creek enters the Savannah River floodplain, was dominated by fishes characteristic of slow flowing waters and heavily vegetated habitats. The large channel draining the swamp supported many of the species found in the swamp plus riverine and anadromous forms.

  15. Steel Creek fish, L-Lake/Steel Creek Biological Monitoring Program, January 1986--December 1991

    SciTech Connect (OSTI)

    Sayers, R.E. Jr.; Mealing, H.G. III [Normandeau Associates, Inc., New Ellenton, SC (United States)

    1992-04-01T23:59:59.000Z

    The Savannah River Site (SRS) encompasses 300 sq mi of the Atlantic Coastal plain in west-central South Carolina. The Savannah River forms the western boundary of the site. Five major tributaries of the Savannah River -- Upper Three Runs Creek, Four Mile Creek, Pen Branch, Steel Creek, and Lower Three Runs Creek -- drain the site. All but Upper Three Runs Creek receive, or in the past received, thermal effluents from nuclear production reactors. In 1985, L Lake, a 400-hectare cooling reservoir, was built on the upper reaches of Steel Creek to receive effluent from the restart of L-Reactor, and protect the lower reaches from thermal impacts. The lake has an average width of approximately 600 m and extends along the Steel Creek valley approximately 7000 m from the dam to the headwaters. Water level is maintained at a normal pool elevation of 58 m above mean sea level by overflow into a vertical intake tower that has multilevel discharge gates. The intake tower is connected to a horizontal conduit that passes through the dam and releases water into Steel Creek. The Steel Creek Biological Monitoring Program was designed to meet environmental regulatory requirements associated with the restart of L-Reactor and complements the Biological Monitoring Program for L Lake. This extensive program was implemented to address portions of Section 316(a) of the Clean Water Act. The Department of Energy (DOE) must demonstrate that the operation of L-Reactor will not significantly alter the established aquatic ecosystems.

  16. Microstructure/property relationships in dissimilar welds between duplex stainless steels and carbon steels

    SciTech Connect (OSTI)

    Barnhouse, E.J. [Weirton Steel Corp., WV (United States); Lippold, J.C. [Ohio State Univ., Columbus, OH (United States)

    1998-12-01T23:59:59.000Z

    The metallurgical characteristics, toughness and corrosion resistance of dissimilar welds between duplex stainless steel Alloy 2205 and carbon steel A36 have been evaluated. Both duplex stainless steel ER2209 and Ni-based Alloy 625 filler metals were used to join this combination using a multipass, gas tungsten arc welding (GTAW) process. Defect-free welds were made with each filler metal. The toughness of both the 625 and 2209 deposits were acceptable, regardless of heat input. A narrow martensitic region with high hardness was observed along the A36/2209 fusion boundary. A similar region was not observed in welds made with the 625 filler metal. The corrosion resistance of the welds made with 2209 filler metal improved with increasing heat input, probably due to higher levels of austenite and reduced chromium nitride precipitation. Welds made with 625 exhibited severe attack in the root pass, while the bulk of the weld was resistant. This investigation has shown that both filler metals can be used to joint carbon steel to duplex stainless steels, but that special precautions may be necessary in corrosive environments.

  17. TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates

    SciTech Connect (OSTI)

    Veena Sahajwalla; Sushil Gupta

    2005-04-15T23:59:59.000Z

    Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

  18. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01T23:59:59.000Z

    energy use for the pellet production is fuel, so this valueof energy used for the production of pellets, the followingthe energy use for the production of pellet, lime, coke, and

  19. Phase Transformation in Cast Superaustenitic Stainless Steels

    SciTech Connect (OSTI)

    Nathaniel Steven Lee Phillips

    2006-12-12T23:59:59.000Z

    Superaustenitic stainless steels constitute a group of Fe-based alloys that are compositionally balanced to have a purely austenitic matrix and exhibit favorable pitting and crevice corrosion resistant properties and mechanical strength. However, intermetallic precipitates such as sigma and Laves can form during casting or exposure to high-temperature processing, which degrade the corrosion and mechanical properties of the material. The goal of this study was to accurately characterize the solid-solid phase transformations seen in cast superaustenitic stainless steels. Heat treatments were performed to understand the time and temperature ranges for intermetallic phase formations in alloys CN3MN and CK3MCuN. Microstructures were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy and wavelength dispersive spectroscopy (EDS, WDS). The equilibrium microstructures, composed primarily of sigma and Laves within purely austenitic matrices, showed slow transformation kinetics. Factors that determine the extent of transformation, including diffusion, nucleation, and growth, are discussed.

  20. Metallurgical evaluation of recycled stainless steel

    SciTech Connect (OSTI)

    Imrich, K.J.

    1997-01-22T23:59:59.000Z

    Recycled Type 304 stainless steel from both Carolina Metals Inc. (CMI) and Manufacturing Science Corporation (MSC) met all the requirements of ASTM A-240 required by Procurement Specification G-SPP-K-00005 Rev. 4. Mechanical strength and corrosion resistance of the material are adequate for service as burial boxes, overpacks, and drums. Inclusion content of both manufacturer`s material was high, resulting in a corresponding decrease in the corrosion resistance. Therefore, an evaluation of the service conditions should be performed before this material is approved for other applications. These heats of stainless steel are not suitable for fabricating DWPF glass canisters because the inclusion and carbon contents are high. However, MSC has recently installed a vacuum induction furnace capable of producing L grade material with a low inclusion content. Material produced from this furnace should be suitable for canister material if appropriate care is taken during the melting/casting process.

  1. Modelling Precipitation of Carbides in Martensitic Steels

    E-Print Network [OSTI]

    Yamasaki, Shingo

    is greater than the yield stress of many commercial steels. II Sulfide stress corrosion cracking (SSCC) There were cases in which joints of pipes used in oil wells ruptured only a few days after the commencement of operation [45, 46]. These accidents were... -composition IG Intergranular fracture MVC Microvoid coalescence rupture MTDATA Metallurgical and Thermochemical Databank PC Pre-stressed concrete QC Quasi-cleavage fracture SSCC Sulfide stress corrosion cracking TEM Transmission electron microscope TMCP...

  2. Cast Stainless Steel Ferrite and Grain Structure

    SciTech Connect (OSTI)

    Ruud, Clayton O.; Ramuhalli, Pradeep; Meyer, Ryan M.; Mathews, Royce; Diaz, Aaron A.; Anderson, Michael T.

    2012-09-01T23:59:59.000Z

    In-service inspection requirements dictate that piping welds in the primary pressure boundary of light-water reactors be subject to a volumetric examination based on the rules contained within the American Society of Mechanical Engineers Boiler and Pressure Vessel Code, Section XI. The purpose of the inspection is the reliable detection and accurate sizing of service-induced degradation and/or material flaws introduced during fabrication. The volumetric inspection is usually carried out using ultrasonic testing (UT) methods. However, the varied metallurgical macrostructures and microstructures of cast austenitic stainless steel piping and fittings, including statically cast stainless steel and centrifugally cast stainless steel (CCSS), introduce significant variations in the propagation and attenuation of ultrasonic energy. These variations complicate interpretation of the UT responses and may compromise the reliability of UT inspection. A review of the literature indicated that a correlation may exist between the microstructure and the delta ferrite content of the casting alloy. This paper discusses the results of a recent study where the goal was to determine if a correlation existed between measured and/or calculated ferrite content and grain structure in CCSS pipe.

  3. Integrating Steel Production with Mineral Carbon Sequestration

    SciTech Connect (OSTI)

    Klaus Lackner; Paul Doby; Tuncel Yegulalp; Samuel Krevor; Christopher Graves

    2008-05-01T23:59:59.000Z

    The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 years of current US production of CO2. Lastly, a computer model was developed to investigate the impact of various system parameters (recoveries and efficiencies and capacities of different system components) and serpentinite quality as well as incorporation of CO2 from sources outside the steel industry.

  4. Dimensional variability of production steel castings

    SciTech Connect (OSTI)

    Peters, F.E.; Risteu, J.W.; Vaupel, W.G.; DeMeter, E.C.; Voigt, R.C.

    1994-12-31T23:59:59.000Z

    Work is ongoing to characterize the dimensional variability of steel casting features. Data are being collected from castings produced at representative Steel Founders` Society of America foundries. Initial results based on more than 12,500 production casting feature measurements are presented for carbon and low alloy steel castings produced in green sand, no-bake, and shell molds. A comprehensive database of casting, pattern, and feature variables has been developed so that the influence of the variables on dimensional variability can be determined. Measurement system analysis is conducted to insure that large measurement error is not reported as dimensional variability. Results indicate that the dimensional variability of production casting features is less than indicated in current US (SFSA) and international (ISO) standards. Feature length, casting weight, parting line and molding process all strongly influence dimensional variability. Corresponding pattern measurements indicate that the actual shrinkage amount for casting features varies considerably. This variation in shrinkage will strongly influence the ability of the foundry to satisfy customer dimensional requirements.

  5. EAF steel producers and the K061 dilemma

    SciTech Connect (OSTI)

    Prichard, L.C.

    1995-12-31T23:59:59.000Z

    The scrap based steel producers in the United States generate an estimated 650,000 tons of electric arc furnace (EAF) dust annually which is classified as hazardous waste, K061. These scrap based producers commonly referred to as mini-mills represented 39% of the steel produced in 1994. Based upon the EAF plants being installed or planned today, it is a reasonable projection to anticipate 50% of the steel produced in the United States will be by EAF`S. Using a straight line projection of percent of steel produced to tonnage of EAF dust generated, this will result in 833,000 tons of dust being generated upon the completion of these new EAF producing plants, presumably by the year 2000. Because the United States is a capitalistic economy, a steel producer is in business to make a profit therefore dust management becomes a very important variable in the cost of making steel.

  6. The performance of duplex stainless steels in chemical environments

    SciTech Connect (OSTI)

    Francis, R. [Weir Materials Ltd., Manchester (United Kingdom). Park Works

    1994-12-31T23:59:59.000Z

    The process industries have used 300 series stainless steels for many years where the corrosion resistance of carbon steel is inadequate. Where stainless steels have proved inadequate there has been a tendency to utilize high nickel alloys, with a greatly increased cost. The present paper reviews the different grades of duplex stainless steel and shows how their superior corrosion and stress corrosion cracking resistance, plus their high strength, can be utilized to provide cost effective alternatives to the high nickel alloys. The use of alternative design codes to take advantages of the properties of duplex alloys is discussed. Data is presented to show the resistance of duplex stainless steels to a variety of chemical environments. The use of duplex stainless steels and the reason for their selection in a number of applications is reviewed.

  7. Process for the elimination of waste water produced upon the desulfurization of coking oven gas by means of wash solution containing organic oxygen-carrier, with simultaneous recovery of elemental sulfur

    SciTech Connect (OSTI)

    Diemer, P.; Brake, W.; Dittmer, R.

    1985-04-16T23:59:59.000Z

    A process is disclosed for the elimination of waste water falling out with the desulfurization of coking oven gas by means of an organic oxygen carrier-containing washing solution with simultaneous recovery of elemental sulfur. The waste water is decomposed in a combustion chamber in a reducing atmosphere at temperatures between about 1000/sup 0/ and 1100/sup 0/ C. under such conditions that the mole ratio of H/sub 2/S:SO/sub 2/ in the exhaust gas of the combustion chamber amounts to at least 2:1. Sulfur falling out is separated and the sensible heat of the exhaust gas is utilized for steam generation. The cooled and desulfurized exhaust gas is added to the coking oven gas before the pre-cooling. Sulfur falling out from the washing solution in the oxidizer is separated out and lead into the combustion chamber together with the part of the washing solution discharged as waste water from the washing solution circulation. Preferred embodiments include that the sulfur loading of the waste water can amount to up to about 370 kg sulfur per m/sup 3/ waste water; having the cooling of sulfur-containing exhaust gas leaving the combustion chamber follow in a waste heat boiler and a sulfur condenser heated by pre-heated boiler feed water, from which condenser sulfur is discharged in liquid state.

  8. Safety analysis report for packaging (onsite) steel drum

    SciTech Connect (OSTI)

    McCormick, W.A.

    1998-09-29T23:59:59.000Z

    This Safety Analysis Report for Packaging (SARP) provides the analyses and evaluations necessary to demonstrate that the steel drum packaging system meets the transportation safety requirements of HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments, for an onsite packaging containing Type B quantities of solid and liquid radioactive materials. The basic component of the steel drum packaging system is the 208 L (55-gal) steel drum.

  9. Characterization of thermal aging of duplex stainless steel by SQUID

    SciTech Connect (OSTI)

    Isobe, Y.; Kamimura, A.; Aoki, K.; Nakayasu, F. [Nuclear Fuel Industries, Ltd., Osaka (Japan)

    1995-08-01T23:59:59.000Z

    Thermal aging is a growing concern for long-term-aged duplex stainless steel piping in nuclear power plants. Superconducting QUantum Interference Device (SQUID) was used for the detection of thermal aging of SUS329 rolled duplex stainless steel and SCS16 cast duplex stainless steel. It was found that the SQUID output signal pattern in the presence of AC magnetic field applied to the specimen was sensitive to the changes in electromagnetic properties due to thermal aging.

  10. automotive sheet steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and 90, elongated Paris-Sud XI, Universit de 88 Spot weldability of TRIP assisted steels with high carbon and aluminium contents Materials Science Websites Summary:...

  11. ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Nitrogen Control in Ladle and Casting Operations ITP Steel: Hydrogen and Nitrogen Control in Ladle and Casting Operations castingops.pdf More Documents & Publications...

  12. Climate VISION: Private Sector Initiatives: Iron and Steel: GHG...

    Office of Scientific and Technical Information (OSTI)

    chemicals, forest products (such as paper and wood products), glass, metal casting, petroleum and coal products, and steel. As soon as the current briefs are available, we...

  13. analog stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (more) Naraghi, Reza 2009-01-01 2 Quantification of phase transformation in stainless steel 301LN sheets MIT - DSpace Summary: This thesis investigates the large deformation...

  14. arc stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (more) Naraghi, Reza 2009-01-01 2 Quantification of phase transformation in stainless steel 301LN sheets MIT - DSpace Summary: This thesis investigates the large deformation...

  15. Friction Stir Spot Welding of Advanced High Strength Steels ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    does not contain any proprietary or confidential information Friction Stir Spot Welding of Advanced High Strength Steels (AHSS) (13056 ORNL, 13055 PNNL) Friction Stir Spot...

  16. Production design for plate products in the steel industry

    E-Print Network [OSTI]

    Sanjeeb Dash

    2007-04-05T23:59:59.000Z

    Apr 5, 2007 ... Abstract: We describe an optimization tool for a multistage production process for rectangular steel plates. The problem we solve yields a ...

  17. activation martensitic steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modeling and experimental study of brittle fracture in tempered martensitic steels for thermonuclear fusion applications. Open Access Theses and Dissertations Summary: ??In this...

  18. activation martensitic steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modeling and experimental study of brittle fracture in tempered martensitic steels for thermonuclear fusion applications. Open Access Theses and Dissertations Summary: ??In this...

  19. New Austenitic Stainless Steels for Exhaust Components (Agreement...

    Energy Savers [EERE]

    Documents & Publications CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components Vehicle Technologies Office Merit Review 2014: Materials for...

  20. Blast damage mitigation of steel structures from near- contact charges

    E-Print Network [OSTI]

    Wolfson, Janet Crumrine

    2008-01-01T23:59:59.000Z

    OF CALIFORNIA, SAN DIEGO Blast Damage Mitigation of Steel35  Damage Levels Observed in LaboratoryFigure 3.34: Progression of damage for a Ballistic Loading

  1. a537 carbon steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    T300: C strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine materials. MATERIALS AND DESIRED DATA Carbon-Carbon...

  2. Strain Rate Characterization of Advanced High Strength Steels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    design factor - New materials do not have design history available for conventional automotive materials (e.g. mild steel) - This lack of knowledge is compensated by...

  3. Auto/Steel Partnership: Fatigue of AHSS Strain Rate Characterization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fatigue of AHSS Strain Rate Characterization AutoSteel Partnership: Fatigue of AHSS Strain Rate Characterization 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual...

  4. alloyed stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Paris-Sud XI, Universit de 3 Standard test methods for pitting and crevice corrosion resistance of stainless steels and related alloys by use of ferric Chloride solution...

  5. alloy steels etudes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    y-dend rites. (Note: primary y Cambridge, University of 2 Estimation of Atmospheric Corrosion of High-Strength, Low-Alloy Steels Engineering Websites Summary: Estimation of...

  6. alloy coated steels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    y-dend rites. (Note: primary y Cambridge, University of 2 Estimation of Atmospheric Corrosion of High-Strength, Low-Alloy Steels Engineering Websites Summary: Estimation of...

  7. alloy steel transition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    y-dend rites. (Note: primary y Cambridge, University of 2 Estimation of Atmospheric Corrosion of High-Strength, Low-Alloy Steels Engineering Websites Summary: Estimation of...

  8. alloy coated steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    y-dend rites. (Note: primary y Cambridge, University of 2 Estimation of Atmospheric Corrosion of High-Strength, Low-Alloy Steels Engineering Websites Summary: Estimation of...

  9. alloys stainless steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Paris-Sud XI, Universit de 3 Standard test methods for pitting and crevice corrosion resistance of stainless steels and related alloys by use of ferric Chloride solution...

  10. ITP Steel: Energy and Environmental Profile fo the U.S. Iron...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Environmental Profile fo the U.S. Iron and Steel Industry ITP Steel: Energy and Environmental Profile fo the U.S. Iron and Steel Industry steelprofile.pdf More...

  11. CARBON ATOM DISTRIBUTION IN A DUAL PHASE STEEL: AN ATOM PROBE STUDY

    E-Print Network [OSTI]

    Barnard, S.J.

    2014-01-01T23:59:59.000Z

    ATOM DISTRIBUTION IN A DUAL PHASE STEEL: AN ATOM PROBE STUDY~4720 1 U.S.A. IntroductioE. Dual Phase steels are currentlymartensite-austenite dual phase steel, although the results

  12. MICROSTRUCTURE AND MECHANICAL PROPERTIES OF 0.1C STEEL WITH Nb

    E-Print Network [OSTI]

    Gau, Jing-Sheng

    2014-01-01T23:59:59.000Z

    and Properties of Dual-Phase Steels, R. A. Kot and J. W.and Prooerties of Dual-Phase Steels, R. A. Kot and J. W.Prooerties of Vanadium Dual Phase Steel and Cold Pressing

  13. DESIGN OF DUAL PHASE Fe/Mn/C STEEL FOR LOW TEMPERATURE APPLICATION

    E-Print Network [OSTI]

    Kim, Nack-Joon

    2013-01-01T23:59:59.000Z

    and Properties of Dual- Phase Steels, R. A. Kot and J. \\4.and Properties of Dual Phase Steels, R. A. Kot and J. W. ~Formable HSLA and Dual- Phase Steels, A. T. Davenport, ed. ,

  14. A MOSSBAUER STUDY OF AUSTENITE STABILITY AND IMPACT FRACTURE IN Fe - 6 Ni STEEL

    E-Print Network [OSTI]

    Fultz, Brent

    2011-01-01T23:59:59.000Z

    IMPACT FRACTURE IN Fe-6Ni STEEL Brent Thomas Fultz Materialscommercial cryogenic alloy steel was studied with regard toThe Experiments Fe-6Ni-lMn steel plate was received from the

  15. THE EFFECT OF SILICON ON THE ENVIRONMENTAL CRACKING BEHAVIOR OF A HIGH STRENGTH STEEL

    E-Print Network [OSTI]

    Cedeno, M.H.C.

    2010-01-01T23:59:59.000Z

    Low-Alloy, High-Strength Steel, Advanced Research ProjectsTests of High Strength Steels, BISRA Report September 1971.Cracking in High Strength Steels and in Titanium and

  16. People of Steel: The Support of a Town during the Homestead Strike

    E-Print Network [OSTI]

    Partida, Jason

    2013-01-01T23:59:59.000Z

    the riot between the steel strikers and the Pinkertons afterNovember 19, 1892. People of Steel 126 The position you1892, between the Carnegie Steel Company, Limited, and the

  17. WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Morris Jr., J.W.

    2013-01-01T23:59:59.000Z

    of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

  18. Effect of polyurea on dynamic response and fracture resistance of steel plates under impulsive loads

    E-Print Network [OSTI]

    Amini, Mahmoud Reza

    2007-01-01T23:59:59.000Z

    on the dynamic response of steel plates, 2006 SEM AnnualPenetration protection of steel plates with polyurea layer,the post-failure motion of steel plates subjected to blast

  19. Propagating Waves Recorded in the Steel, Moment-Frame Factor Building During Earthquakes

    E-Print Network [OSTI]

    Kohler, Monica; Heaton, Thomas H.; Samuel C. Bradford

    2007-01-01T23:59:59.000Z

    studies of damage to tall steel moment-frame buildings inan instrumented 15-story steel- frame building, EarthquakePropagating Waves in the Steel, Moment-Frame Factor Building

  20. DESIGN OF DUAL PHASE Fe/Mn/C STEEL FOR LOW TEMPERATURE APPLICATION

    E-Print Network [OSTI]

    Kim, Nack-Joon

    2013-01-01T23:59:59.000Z

    and Properties of Dual- Phase Steels, R. A. Kot and J. \\4.Properties of Dual Phase Steels, R. A. Kot and J. W. ~lorrisand Hardenability in Steels, Symp. ASt~. ~. Garvey, Trans.

  1. Identification, Model Updating, and Response Prediction of an Instrumented 15-Story Steel-Frame Building

    E-Print Network [OSTI]

    Skolnik, Derek; Lei, Ying; Yu, Eunjong; Wallace, J W

    2006-01-01T23:59:59.000Z

    A. , 1998. Ductile Design of Steel Structure, McGraw Hill,monitoring of the steel-frame UCLA Factor Building,an Instrumented 15-Story Steel-Frame Building Derek Skolnik,

  2. MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AISI 4340 STEEL MODIFIED WITH ALUMINUM AND SILICON

    E-Print Network [OSTI]

    Bhat, M.S.

    2010-01-01T23:59:59.000Z

    1968), G, Thomas. Iron and Steel Int, 46. 451 (1973), G,Containing High-Strength Steels, Cobalt Monograph Series, A.Strength Structural j Steels," ASTM Spec, Tech, PubL 498,

  3. Performance-Based Seismic Demand Assessment of Concentrically Braced Steel Frame Buildings

    E-Print Network [OSTI]

    Chen, Chui-Hsin

    2010-01-01T23:59:59.000Z

    and Ductility Factors for Steel Frames De- signed According1980), Inelastic Buckling of Steel Struts Under Cyclic LoadBS 5950: Structural use of steel work in building. Part1

  4. THE USE OF MICROSTRUCTURE CONTROL TO TOUGHEN FERRITIC STEELS FOR CRYOGENIC USE. II. Fe-Mn STEELS

    E-Print Network [OSTI]

    Hwang, S.K.

    2010-01-01T23:59:59.000Z

    steels in current use at LNG temperatures and below containtemperature to below LNG temperature. The resulting alloysis suitable for use to below LNG temperature in the grain-

  5. Coking Coal Import Costs - EIA

    Gasoline and Diesel Fuel Update (EIA)

    Import Costs for Selected Countries U.S. Dollars per Metric Ton1 (Average Unit Value, CIF2) Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Belgium 48.67 46.59 49.25 78.98...

  6. Converting Petroleum Coke to Electricity 

    E-Print Network [OSTI]

    Pavone, A.

    1992-01-01T23:59:59.000Z

    will compete economically with conventional coal and nature gas, both of which are currently experiencing low prices. Pipeline quality natural gas at the well is selling on average for $1.50 IM- Btu, while cleaned coal at the mine is under $1.00/M... pneumatically into the firebox. Supplementary fuel (10%) would be necessary to ignite the process. and be required continuously to maintain flame stability Firebox temperatues would average 2000-2500 degF. Air would be introduced at several different stages...

  7. Converting Petroleum Coke to Electricity

    E-Print Network [OSTI]

    Pavone, A.

    Changes in oil refining technology and economics are driving refiners to utilize thermal processes to maximize the conversion of heavy crude oil components to clean products. Since the primary unit operation to accomplish this objective...

  8. Feasibility analysis of recycling radioactive scrap steel

    SciTech Connect (OSTI)

    Nichols, F. [Manufacturing Sciences Corp., Woodland, WA (United States); Balhiser, B. [MSE, Inc., Butte, MT (United States); Cignetti, N. [Cignetti Associates, North Canton, OH (United States)] [and others

    1995-09-01T23:59:59.000Z

    The purpose of this study is to: (1) establish a conceptual design that integrates commercial steel mill technology with radioactive scrap metal (RSM) processing to produce carbon and stainless steel sheet and plate at a grade suitable for fabricating into radioactive waste containers; (2) determine the economic feasibility of building a micro-mill in the Western US to process 30,000 tons of RSM per year from both DOE and the nuclear utilities; and (3) provide recommendations for implementation. For purposes of defining the project, it is divided into phases: economic feasibility and conceptual design; preliminary design; detail design; construction; and operation. This study comprises the bulk of Phase 1. It is divided into four sections. Section 1 provides the reader with a complete overview extracting pertinent data, recommendations and conclusions from the remainder of the report. Section 2 defines the variables that impact the design requirements. These data form the baseline to create a preliminary conceptual design that is technically sound, economically viable, and capitalizes on economies of scale. Priorities governing the design activities are: (1) minimizing worker exposure to radionuclide hazards, (2) maximizing worker safety, (3) minimizing environmental contamination, (4) minimizing secondary wastes, and (5) establishing engineering controls to insure that the plant will be granted a license in the state selected for operation. Section 3 provides details of the preliminary conceptual design that was selected. The cost of project construction is estimated and the personnel needed to support the steel-making operation and radiological and environmental control are identified. Section 4 identifies the operational costs and supports the economic feasibility analysis. A detailed discussion of the resulting conclusions and recommendations is included in this section.

  9. SOLID STATE JOINING OF MAGNESIUM TO STEEL

    SciTech Connect (OSTI)

    Jana, Saumyadeep; Hovanski, Yuri; Pilli, Siva Prasad; Field, David P.; Yu, Hao; Pan, Tsung-Yu; Santella, M. L.

    2012-06-04T23:59:59.000Z

    Friction stir welding and ultrasonic welding techniques were applied to join automotive magnesium alloys to steel sheet. The effect of tooling and process parameters on the post-weld microstructure, texture and mechanical properties was investigated. Static and dynamic loading were utilized to investigate the joint strength of both cast and wrought magnesium alloys including their susceptibility and degradation under corrosive media. The conditions required to produce joint strengths in excess of 75% of the base metal strength were determined, and the effects of surface coatings, tooling and weld parameters on weld properties are presented.

  10. Method for machining steel with diamond tools

    DOE Patents [OSTI]

    Casstevens, J.M.

    1984-01-01T23:59:59.000Z

    The present invention is directed to a method for machine optical quality finishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

  11. Method for machining steel with diamond tools

    DOE Patents [OSTI]

    Casstevens, John M. (Greenville, TX)

    1986-01-01T23:59:59.000Z

    The present invention is directed to a method for machining optical quality inishes and contour accuracies of workpieces of carbon-containing metals such as steel with diamond tooling. The wear rate of the diamond tooling is significantly reduced by saturating the atmosphere at the interface of the workpiece and the diamond tool with a gaseous hydrocarbon during the machining operation. The presence of the gaseous hydrocarbon effectively eliminates the deterioration of the diamond tool by inhibiting or preventing the conversion of the diamond carbon to graphite carbon at the point of contact between the cutting tool and the workpiece.

  12. Heavy-Section Steel Irradiation Program

    SciTech Connect (OSTI)

    Rosseel, T.M.

    2000-04-01T23:59:59.000Z

    Maintaining the integrity of the reactor pressure vessel (RPV) in a light-water-cooled nuclear power plant is crucial in preventing and controlling severe accidents that have the potential for major contamination release. Because the RPV is the only key safety-related component of the plant for which a redundant backup system does not exist, it is imperative to fully understand the degree of irradiation-induced degradation of the RPV's fracture resistance that occurs during service. For this reason, the Heavy-Section Steel Irradiation (HSSI) Program has been established.

  13. Gas Atomization of Stainless Steel - Slow Motion

    SciTech Connect (OSTI)

    None

    2011-01-01T23:59:59.000Z

    Stainless steel liquid atomized by supersonic argon gas into a spray of droplets at ~1800ºC. Atomization of metal requires high pressure gas and specialized chambers for cooling and collecting the powders without contamination. The critical step for morphological control is the impingement of the gas on the melt stream. The video is a black and white high speed video of a liquid metal stream being atomized by high pressure gas. This material was atomized at the Ames Laboratory's Materials Preparation Center http://www.mpc.ameslab.gov

  14. Automated inspection of hot steel slabs

    DOE Patents [OSTI]

    Martin, Ronald J. (Burnsville, MN)

    1985-01-01T23:59:59.000Z

    The disclosure relates to a real time digital image enhancement system for performing the image enhancement segmentation processing required for a real time automated system for detecting and classifying surface imperfections in hot steel slabs. The system provides for simultaneous execution of edge detection processing and intensity threshold processing in parallel on the same image data produced by a sensor device such as a scanning camera. The results of each process are utilized to validate the results of the other process and a resulting image is generated that contains only corresponding segmentation that is produced by both processes.

  15. Automated inspection of hot steel slabs

    DOE Patents [OSTI]

    Martin, R.J.

    1985-12-24T23:59:59.000Z

    The disclosure relates to a real time digital image enhancement system for performing the image enhancement segmentation processing required for a real time automated system for detecting and classifying surface imperfections in hot steel slabs. The system provides for simultaneous execution of edge detection processing and intensity threshold processing in parallel on the same image data produced by a sensor device such as a scanning camera. The results of each process are utilized to validate the results of the other process and a resulting image is generated that contains only corresponding segmentation that is produced by both processes. 5 figs.

  16. Microstructure of Super-duplex Stainless Steels

    E-Print Network [OSTI]

    Sharafi, Shahriar

    1993-12-07T23:59:59.000Z

    .1 Introduction 24 3.2 The Fe-Cr-Ni System . . . . . . . . . . . . 25 3.3 The Alloying Elements in Duplex Stainless Steels 33 3.4 Chromium and Nickel Equivalents . . . . . . . 42 3.5 The Effect of Creq/Nieq Ratio on Equilibrium Volume Fraction of Austenite 43 3... / Austenite Balance 6.1 Introduction . 6.2 Thermodynamic Calculations . . . . . 6.3 Equilibrium Isothermal Heat Treatments 6.4 Effect of Ferrite/ Austenite Balance on Hardness 6.5 Equilibrium Partitioning of Alloying Elements 6.6 Precipitation of Cr2N 6...

  17. Carbon Emissions: Iron and Steel Industry

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321Spain (Million Cubic Feet)Iron and Steel

  18. Kobe Steel Ltd Kobelco | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer Plant Jump to: navigation, search GEOTHERMALTexas: Energy Resources JumpKobe Steel Ltd

  19. JFE Steel Corp | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunanInformation sourceInvensysIsland GasItron IncJFEJFE Steel

  20. Steel Industry Profile | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretaryVideosSpringoutAPBF-DEC NOxBestPractices SteamOfficeSteel

  1. Collection sir Samuel Steele university of alberta libraries

    E-Print Network [OSTI]

    MacMillan, Andrew

    carrière de milicien, de policier à cheval et de soldat. La vaste correspondance entre Steele et sa femme nature personnelle de leur fils, Harwood Steele (1897 à 1978), qui fut soldat, explorateur de l. R #12;7 Le gouvernement canadien envoya une expédition armée de la milice canadienne et des soldats

  2. STEEL PLATE SHEAR WALL BUILDINGS: DESIGN REQUIREMENTS AND RESEARCH

    E-Print Network [OSTI]

    Bruneau, Michel

    , University at Buffalo, Buffalo, NY 14260. #12;plate shear wall design and use of light-gage cold form platesSTEEL PLATE SHEAR WALL BUILDINGS: DESIGN REQUIREMENTS AND RESEARCH Michel Bruneau, P.E. 1 Dr areas. This paper provides an overview of the current state-of-the-art in steel plate shear wall design

  3. Rutherford backscattering analysis of gallium implanted 316 stainless steel 

    E-Print Network [OSTI]

    Ortensi, Javier

    2000-01-01T23:59:59.000Z

    Ion implantation of Ga ions into 316 stainless steel was performed at fluences ranging from 8x10¹? to 10¹? ions/cm². The depth profile of Ga in the steel was analyzed via Rutherford Backscattering and ToFSIMS. The surface effects were...

  4. Welding residual stresses in ferritic power plant steels

    E-Print Network [OSTI]

    Cambridge, University of

    REVIEW Welding residual stresses in ferritic power plant steels J. A. Francis*1 , H. K. D. H require therefore, an accounting of residual stresses, which often are introduced during welding. To do in the estimation of welding residual stresses in austenitic stainless steels. The progress has been less convincing

  5. Cinematography of Resistance Spot Welding of Galvanized Steel Sheet

    E-Print Network [OSTI]

    Eagar, Thomas W.

    Cinematography of Resistance Spot Welding of Galvanized Steel Sheet Preweld and postweld current modifications on the resistance spot welding of galvanized steel sheet ·are analyzed using high phenomena through· out the weld process are discussed. In addition. the duration of current modifi· cation

  6. Plastic strain due to twinning in austenitic TWIP steels

    E-Print Network [OSTI]

    Cambridge, University of

    Plastic strain due to twinning in austenitic TWIP steels B. Qin and H. K. D. H. Bhadeshia* Twinning induced plasticity steels are austenitic alloys in which mechanical twinning is a prominent deformation, Twinning, Twinning induced plasticity, Automobiles Introduction Mechanical twinning is a plastic

  7. Corrosion protection of steel in ammonia/water heat pumps

    DOE Patents [OSTI]

    Mansfeld, Florian B.; Sun, Zhaoli

    2003-10-14T23:59:59.000Z

    Corrosion of steel surfaces in a heat pump is inhibited by adding a rare earth metal salt to the heat pump's ammonia/water working fluid. In preferred embodiments, the rare earth metal salt includes cerium, and the steel surfaces are cerated to enhance the corrosion-inhibiting effects.

  8. CLEAVAGE FRACTURE MICROMECHANISMS RELATED TO WPS EFFECT IN RPV STEEL

    E-Print Network [OSTI]

    Boyer, Edmond

    CLEAVAGE FRACTURE MICROMECHANISMS RELATED TO WPS EFFECT IN RPV STEEL S. R. Bordet1 , B. Tanguy1 , S vessel (RPV) steel. In this purpose, different WPS fracture test results obtained on compact tensile (CT fractographic investigations and finite element (FE) calculations, demonstrate a strong material aspect to WPS

  9. Sigma phase formation kinetics in stainless steel laminate composites

    SciTech Connect (OSTI)

    Wenmen, D.W.; Olson, D.L.; Matlock, D.K. [Colorado School of Mines, Golden, CO (United States)] [and others

    1994-12-31T23:59:59.000Z

    Stainless steel laminate composites were made to simulate weld microstructures. The use of laminates with variations in chemical composition allows for one dimensional analysis of phase transformation associated with the more complex three-dimensional solidification experience of weld metal. Alternate layers of austenitic (304L and 316L) and ferritic (Ebrite) stainless steels allowed for the study of sigma phase formation at the austenite-ferrite interface in duplex stainless steel. Two austenitic stainless steels, 304L (18.5Cr-9.2Ni-0.3Mo) and 316L (16.2Cr-10.1Ni-2.6Mo), and one ferritic stainless steel, Ebrite (26.3Cr-0Ni-1.0Mo) were received in the form of sheet which was laboratory cold rolled to a final thickness of 0.25 mm (0.030 in.). Laminate composites were prepared by laboratory hot rolling a vacuum encapsulated compact of alternating layers of the ferrite steel with either 304L or 316L stainless steel sheets. Laminate composite specimens, which simulate duplex austenite-ferrite weld metal structure, were used to establish the kinetics of nucleation and growth of sigma phase. The factors affecting sigma phase formation were identified. The effects of time, temperature, and transport of chromium and nickel were evaluated and used to establish a model for sigma phase formation in the austenite-ferrite interfacial region. Information useful for designing stainless steel welding consumables to be used for high temperature service was determined.

  10. Welding type 347 stainless steel -- An interpretive report

    SciTech Connect (OSTI)

    Thomas, R.D. Jr.; Messler, R.W. Jr.

    1997-05-01T23:59:59.000Z

    Stainless steels fall into three major classifications: ferritic, austenitic and martensitic. Type 347 stainless steels are classified as austenitic, though, as well be described later, they may contain small amounts of ferrite as well. They are of the 18-8 chromium-nickel type with up to 1% niobium, an element once referred to as columbium. Type 347 stainless steel is the primary focus of this document. Similar stainless steels containing niobium will be included, such as Types 348 and 309Nb, as these are frequently encountered in certain applications in welded construction. Ferritic and duplex stainless steels, some of which may contain niobium, are not within the scope of this report. This report covers the following topics: applicable welding processes; composition; properties; ferrite potential effect of weld thermal cycle; post-weld heat treatments; cracks and microfissures; and industrial applications.

  11. Development of an Energy Conservation Voluntary Agreement, Pilot Project in the Steel Sector in Shandong Province. Project Report to the State Economic and Trade Commission, People's Republic of China

    E-Print Network [OSTI]

    Price, Lynn; Yun, Jiang; Worrell, Ernst; Wenwei, Du; Sinton, Jonathan E.

    2003-01-01T23:59:59.000Z

    sintering, pelleting), ironmaking, steelmaking (basic oxygenfor steelmaking covers ironmaking (including coking andEE_..) The six spreadsheets (ironmaking, BOF, EAF, Casting,

  12. High temperature mechanical strength and microstructural stability of advanced 9-12%Cr steels and ODS steels.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and ODS steels. B. Fournier,1 M. Salvi1 , C. Caës1 , J. Malaplate1 , F. Dalle1 , M. Sauzay1 , Y. de Carlan. In the framework of Generation IV nuclear reactors and for fusion reactors, oxide dispersion strengthened (ODS. In the present article advanced 9-12%Cr steels, including their ODS grades, are tested under creep, fatigue

  13. Early Detection of Steel Rebar Corrosion by Acoustic Emission Monitoring Early Detection of Steel Rebar Corrosion by Acoustic Emission

    E-Print Network [OSTI]

    Early Detection of Steel Rebar Corrosion by Acoustic Emission Monitoring Early Detection of Steel Rebar Corrosion by Acoustic Emission Monitoring Alan D. Zdunek and David Prine BIRL Industrial Research, Evanston, IL 60201 Paper No. 547 presented at CORROSION95, the NACE International Annual Conference

  14. October 14 WA Division Newsletter Page 4 Tool durability and steel microstructure in friction stir welding of mild steel

    E-Print Network [OSTI]

    Cambridge, University of

    ) of aluminium alloys are cost effective and durable, whereas the much larger market for welding of steels for the welding of 7075 aluminium alloy. The results were presented as easy to use maps of "tool durability index- ium alloys has been applied to the FSW of steel. The calculations were extended to predict

  15. Heat Treatment Procedure Qualification for Steel Castings

    SciTech Connect (OSTI)

    Professor Robert C. Voigt

    2003-02-02T23:59:59.000Z

    The science of heat treatment has been well studied and is the basis from which existing specifications and practices for the heat treatment of steel castings have been developed. Although these existing specifications address the general needs of steel castings to be heat-treated, they do not take into account the variability in the parameters that govern the processes. The need for a heat treatment qualification procedure that accounts for this variability during heat treatment is an important step toward heat treatment quality assurance. The variability in temperatures within a heat treatment furnace is one such variable that a foundry has to contend with in its day-to-day activity. Though specifications indicate the temperatures at which a particular heat treatment has to be conducted, heat treatment specifications do not adequately account for all aspects of heat treatment quality assurance. The heat treatment qualification procedure will comprise of a robust set of rules and guidelines that ensure that foundries will still be able to operate within the set of constraints imposed on them by non-deterministic elements within the processes.

  16. Cast alumina forming austenitic stainless steels

    DOE Patents [OSTI]

    Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

    2013-04-30T23:59:59.000Z

    An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

  17. Numerical simulations of welds of thick steel pieces of interest for the thermonuclear fusion ITER machine

    E-Print Network [OSTI]

    Carmignani, B

    2005-01-01T23:59:59.000Z

    Numerical simulations of welds of thick steel pieces of interest for the thermonuclear fusion ITER machine

  18. Spot weldability of d-TRIP steel containing , K. Y. Lee2

    E-Print Network [OSTI]

    Cambridge, University of

    of the strong dual phase steels,10,11 is large when compared with interstitial free or bake hardening steels in Table 1 according to the common standards.21­25 A dual phase steel DP-78026 has in this work been-TRIP steel, designed to retain d-ferrite as a stable phase at all temperatures below melting. Fully

  19. Modelling the role of non metallic inclusions on the anisotropic fatigue behaviour of forged steel

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    reported as being 35% for 42CrMo4 steel [1] and 15% for a duplex stainless steel [2]. To design a forged steel E. Pessard* , F. Morel, A. Morel, D. Bellett LAMPA (EA1427) Arts et Métiers ParisTech Angers 2, Bd. This study aims at describing the high cycle fatigue response of a forged bainitic steel. This material

  20. Differences in synchrotron radiation induced gas desorption from stainless steel and aluminium alloy

    E-Print Network [OSTI]

    Andritschky, M; Mathewson, A G; Souchet, R; Strubin, Pierre M; Trickett, B A

    1990-01-01T23:59:59.000Z

    Differences in synchrotron radiation induced gas desorption from stainless steel and aluminium alloy

  1. NEUTRON DAMAGE IN REACTOR PRESSURE-VESSEL STEEL EXAMINED WITH POSITRON ANNIHILATION LIFETIME SPECTROSCOPY

    E-Print Network [OSTI]

    Motta, Arthur T.

    NEUTRON DAMAGE IN REACTOR PRESSURE-VESSEL STEEL EXAMINED WITH POSITRON ANNIHILATION LIFETIME-vessel steels. We irradiated samples ofASTM A508 nuclear reactor pressure-vessel steel to fast neutron 17 2 (PALS) to study the effects of neutron damage in the steels on positron lifetimes. Non

  2. The morphology and formation mechanism of pearlite in steels

    SciTech Connect (OSTI)

    Zhang, M.-X., E-mail: Mingxing.Zhang@uq.edu.au [Division of Materials, School of Engineering, University of Queensland, St. Lucia, Queensland 4072 (Australia); Kelly, P.M. [Division of Materials, School of Engineering, University of Queensland, St. Lucia, Queensland 4072 (Australia)

    2009-06-15T23:59:59.000Z

    A number of morphological features of pearlite were revealed through scanning electron microscopy using deeply etched specimens. These include cementite branching, bridging, gaps, holes and curvature. The presence of cementite thin films or networks along the austenite grain boundaries in eutectoid steel and at the interface between pearlite and proeutectoid ferrite in hypoeutectoid steel is another characteristic of pearlite. Furthermore, ferrite thin films surrounding the proeutectoid cementite in hypereutectoid steels are also observed. Hence, it is considered that in hypoeutectoid steels the nucleus for pearlite is a film of cementite rather than the expected proeutectoid ferrite and, similarly, in hypereutectoid steels pearlite forms from a ferrite film rather than from proeutectoid cementite. Convergent beam Kikuchi line diffraction was used to accurately determine the orientation relationships between pearlitic constituents and parent austenite in a Hadfields steel. The results show that neither the pearlitic ferrite nor the cementite is crystallographically related to the austenite grain into which the pearlite was growing and to that into which it was not growing. In addition, a new orientation relationship between pearlitic cementite and ferrite in the Hadfield steel was also observed.

  3. Sulphide stress cracking resistance of supermartensitic stainless steel for OCTG

    SciTech Connect (OSTI)

    Scoppio, L.; Barteri, M. [Centro Sviluppo Materiali S.p.A., Rome (Italy); Cumino, G. [Dalmine Tubi Industriali S.r.l., Bergamo (Italy)

    1997-08-01T23:59:59.000Z

    Supermartensitic stainless steels, recently made available as oil country tubular goods (OCTG), have been developed as a valuable cost effective alternative to duplex stainless steel for high CO{sub 2}, medium/high chlorides, and very low H{sub 2}S environments. Experimental tests were carried out to determine the localized corrosion and the sulfide stress cracking (SSC) resistance of supermartensitic steel UNS S41425 to be used as OCTG in slightly sour oil and gas wells and to compare its performance with standard L80 API grade UNS S42000 13% Cr steel, considered as a reference. Supermartensitic steels with yield range as per L80, C95, P110, API5CT, were developed and corrosion and mechanical properties were determined. The influence of different chloride contents (NaCl 10 {divided_by} 50 g/l), hydrogen sulfide partial pressure (0.1 {divided_by} 100 kPa) and pH (2.7 {divided_by} 4.5) has been investigated in order to simulate production service conditions. Modified NACE constant load test and slow strain rate (SSR) test were performed. SSR gave the most severe evaluation for the SSC resistance. In the SSR test supermartensitic steel is deeply influenced by the chloride concentration. Supermartensitic steel corrosion resistance is by far superior to that of 13% Cr.

  4. Phase Transformations in Cast Duplex Stainless Steels

    SciTech Connect (OSTI)

    Yoon-Jun Kim

    2004-12-19T23:59:59.000Z

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by local composition fluctuations in the cast alloy. This may cause discrepancy between thermodynamic prediction and experimental observation.

  5. Yield improvement and defect reduction in steel casting

    SciTech Connect (OSTI)

    Kent Carlson

    2004-03-16T23:59:59.000Z

    This research project investigated yield improvement and defect reduction techniques in steel casting. Research and technology development was performed in the following three specific areas: (1) Feeding rules for high alloy steel castings; (2) Unconventional yield improvement and defect reduction techniques--(a) Riser pressurization; and (b) Filling with a tilting mold; and (3) Modeling of reoxidation inclusions during filling of steel castings. During the preparation of the proposal for this project, these areas were identified by the High Alloy Committee and Carbon and Low Alloy Committee of the Steel Founders' Society of America (SFSA) as having the highest research priority to the steel foundry industry. The research in each of the areas involved a combination of foundry experiments, modeling and simulation. Numerous SFSA member steel foundries participated in the project through casting trials and meetings. The technology resulting from this project will result in decreased scrap and rework, casting yield improvement, and higher quality steel castings produced with less iteration. This will result in considerable business benefits to steel foundries, primarily due to reduced energy and labor costs, increased capacity and productivity, reduced lead-time, and wider use and application of steel castings. As estimated using energy data provided by the DOE, the technology produced as a result of this project will result in an energy savings of 2.6 x 10{sup 12} BTU/year. This excludes the savings that were anticipated from the mold tilting research. In addition to the energy savings, and corresponding financial savings this implies, there are substantial environmental benefits as well. The results from each of the research areas listed above are summarized.

  6. ON QUANTIFICATION OF HELIUM EMBRITTLEMENT IN FERRITIC/MARTENSITIC STEELS

    SciTech Connect (OSTI)

    Gelles, David S.

    2000-12-01T23:59:59.000Z

    Helium accumulation due to transmutation has long been considered a potential cause for embrittlement in ferritic/martensitic steels. Three Charpy impact databases involving nickel- and boron-doped alloys are quantified with respect to helium accumulation, and it is shown that all predict a very large effect of helium production on embrittlement. If these predictions are valid, use of Ferritic/Martensitic steels for Fusion first wall applications is highly unlikely. It is therefore necessary to reorient efforts regarding development of these steels for fusion applications to concentrate on the issue of helium embrittlement.

  7. Stainless steel anodes for alkaline water electrolysis and methods of making

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev

    2014-01-21T23:59:59.000Z

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  8. Diode laser welding of aluminum to steel

    SciTech Connect (OSTI)

    Santo, Loredana; Quadrini, Fabrizio; Trovalusci, Federica [University of Rome Tor Vergata, Department of Mechanical Engineering, Via del Politecnico 1, 00133 Rome (Italy)

    2011-05-04T23:59:59.000Z

    Laser welding of dissimilar materials was carried out by using a high power diode laser to join aluminum to steel in a butt-joint configuration. During testing, the laser scan rate was changed as well as the laser power: at low values of fluence (i.e. the ratio between laser power and scan rate), poor joining was observed; instead at high values of fluence, an excess in the material melting affected the joint integrity. Between these limiting values, a good aesthetics was obtained; further investigations were carried out by means of tensile tests and SEM analyses. Unfortunately, a brittle behavior was observed for all the joints and a maximum rupture stress about 40 MPa was measured. Apart from the formation of intermeltallic phases, poor mechanical performances also depended on the chosen joining configuration, particularly because of the thickness reduction of the seam in comparison with the base material.

  9. Radiation resistant austenitic stainless steel alloys

    DOE Patents [OSTI]

    Maziasz, Philip J. (Oak Ridge, TN); Braski, David N. (Oak Ridge, TN); Rowcliffe, Arthur F. (Oak Ridge, TN)

    1989-01-01T23:59:59.000Z

    An austenitic stainless steel alloy, with improved resistance to radiation-induced swelling and helium embrittlement, and improved resistance to thermal creep at high temperatures, consisting essentially of, by weight percent: from 16 to 18% nickel; from 13 to 17% chromium; from 2 to 3% molybdenum; from 1.5 to 2.5% manganese; from 0.01 to 0.5% silicon; from 0.2 to 0.4% titanium; from 0.1 to 0.2% niobium; from 0.1 to 0.6% vanadium; from 0.06 to 0.12% carbon; from 0.01% to 0.03% nitrogen; from 0.03 to 0.08% phosphorus; from 0.005 to 0.01% boron; and the balance iron, and wherein the alloy may be thermomechanically treated to enhance physical and mechanical properties.

  10. The US steel industry: An energy perspective

    SciTech Connect (OSTI)

    Azimi, S. A.; Lowitt, H. E.

    1988-01-01T23:59:59.000Z

    This report investigates the state of the US steel industry in terms of energy consumption and conservation. The specific objectives were: to update and verify energy and materials consumption data at the various process levels in 1983; to determine the potential energy savings attainable with current (1983), state-of-the-art, and future production practices and technologies (2000); and to identify new areas of research and development opportunity that will enable these potential future savings to be achieved. The results of this study concluded that in year 2000, there is a potential to save between 40% and 46% of the energy used in current production practices, dependent on the projected technology mix. R and D needs and opportunities were identified for the industry. Potential R and D candidates for DOE involvement with the private sector were assessed and selected from the identified list.

  11. Radiation resistant austenitic stainless steel alloys

    DOE Patents [OSTI]

    Maziasz, P.J.; Braski, D.N.; Rowcliffe, A.F.

    1987-02-11T23:59:59.000Z

    An austenitic stainless steel alloy, with improved resistance to radiation-induced swelling and helium embrittlement, and improved resistance to thermal creep at high temperatures, consisting essentially of, by weight percent: from 16 to 18% nickel; from 13 to 17% chromium; from 2 to 3% molybdenum; from 1.5 to 2.5% manganese; from 0.01 to 0.5% silicon; from 0.2 to 0.4% titanium; from 0.1 to 0.2% niobium; from 0.1 to 0.6% vanadium; from 0.06 to 0.12% carbon; from 0.01 to 0.03% nitrogen; from 0.03 to 0.08% phosphorus; from 0.005 to 0.01% boron; and the balance iron, and wherein the alloy may be thermomechanically treated to enhance physical and mechanical properties. 4 figs.

  12. Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector

    E-Print Network [OSTI]

    Xu, T.T.

    2011-01-01T23:59:59.000Z

    Improved Product Quality,” Ironmaking and Steel making 18(pound Investment,” Ironmaking and Steel making,” Anonymous,Oil Through Sintering," Ironmaking and Steel making Dawson,

  13. Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector

    E-Print Network [OSTI]

    Xu, T.T.

    2011-01-01T23:59:59.000Z

    Assessment of Electric Steel making Through the Year 2000,by Injection Technology” Steel Times, October 1994 pp.391-Hanes, C. , 1999. USS/Kobe Steel, Personal communication,

  14. THE INFLUENCE OF RETAINED AUSTENITE ON THE THICK SECTION MECHANICAL PROPERTIES OF A COMMERCIAL LOW ALLOY ULTRA-HIGH STRENGTH STEEL

    E-Print Network [OSTI]

    Horn, R.M.

    2010-01-01T23:59:59.000Z

    of Fracture of High Strength Steels, Final Tech. Report,Arsenal Lab. , K. J. Irvine, Steel Strengthening Mechanisms,Diagrams, United States Steel, Pittsburgh, PA, 1963. E. G.

  15. A COMPARISON OF THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF 300-M STEEL MANUFACTURED BY THE VACUUM ARC REMELT AND THE ELECTROSLAG REMELT PROCESSES

    E-Print Network [OSTI]

    Lechtenberg, Thomas A.

    2011-01-01T23:59:59.000Z

    AND MECHANICAL PROPERTIES OF 300~M STEEL MANUFACTURED BY THEAND MECHANICAL PROPERTIES OF 300~M STEEL MANUFACTURED BY THEArc Remelt (VAR) 300-M steel were measured, These were

  16. Development of sodium silicate adhesives for electrical steel bonding

    E-Print Network [OSTI]

    Marks, Jordan (Jordan Christine)

    2014-01-01T23:59:59.000Z

    Inorganic adhesives have several benefits over traditional joining methods for joining electrical steels used in magnetic cores of numerous industrial applications. As insulators with very high melting temperatures, the ...

  17. Eddy sensors for small diameter stainless steel tubes.

    SciTech Connect (OSTI)

    Skinner, Jack L.; Morales, Alfredo Martin; Grant, J. Brian; Korellis, Henry James; LaFord, Marianne Elizabeth; Van Blarigan, Benjamin; Andersen, Lisa E.

    2011-08-01T23:59:59.000Z

    The goal of this project was to develop non-destructive, minimally disruptive eddy sensors to inspect small diameter stainless steel metal tubes. Modifications to Sandia's Emphasis/EIGER code allowed for the modeling of eddy current bobbin sensors near or around 1/8-inch outer diameter stainless steel tubing. Modeling results indicated that an eddy sensor based on a single axial coil could effectively detect changes in the inner diameter of a stainless steel tubing. Based on the modeling results, sensor coils capable of detecting small changes in the inner diameter of a stainless steel tube were designed, built and tested. The observed sensor response agreed with the results of the modeling and with eddy sensor theory. A separate limited distribution SAND report is being issued demonstrating the application of this sensor.

  18. A structural analysis of the Cardington British Steel corner test 

    E-Print Network [OSTI]

    Gillie, Martin; Usmani, Asif; Rotter, J Michael

    2002-01-01T23:59:59.000Z

    This paper presents a structural analysis of the Cardington British Steel corner test. The test is a analyzes using ABAQUS, the commercial finite element program. The results of the analysis indicate that the response of ...

  19. axially loaded steel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    image correlation and FE analysis Mathematics Websites Summary: conducted on dual-phase high-strength steel in a split-Hopkinson tension bar at a strain-rate in the...

  20. Process to Continuously Melt, Refine, and Cast High Quality Steel

    Broader source: Energy.gov [DOE]

    This factsheet describes a project to conduct research and development targeted at designing an innovative steelmaking process to produce higher quality steel faster than traditional batch processes while consuming less energy and other resources.