National Library of Energy BETA

Sample records for greenhouse gas phase

  1. Bioenergy Impacts … Greenhouse Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Laboratory developed the Greenhouse gases, Regulated Emissions, and Energy ... crops, and algae that have greater greenhouse gas reduction benefits compared to ...

  2. Greenhouse Gas Source Attribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Source Attribution - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs

  3. OPTIMA: Low Greenhouse Gas Fuels

    Broader source: Energy.gov [DOE]

    Plenary IV: Fuels of the Future: Accelerating the Co-Optimization of Fuels and Engines OPTIMA: Low Greenhouse Gas Fuels Blake Simmons, Biofuels Program Lead, Sandia National Laboratories

  4. The Greenhouse Gas Protocol Initiative: Measurement and Estimation...

    Open Energy Info (EERE)

    GHG Emissions AgencyCompany Organization: World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Greenhouse Gas Phase:...

  5. The Greenhouse Gas Protocol Initiative: Sector Specific Tools...

    Open Energy Info (EERE)

    World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Industry, Greenhouse Gas Phase: Determine Baseline, Evaluate...

  6. Greenhouse Gas Reductions: SF6

    ScienceCinema (OSTI)

    Anderson, Diana

    2013-04-19

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas ? one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  7. SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 SUMMARYGREENHOUSEGASEMISSIONSDATAWORKSHEETJANUARY20...

  8. Greenhouse Gas Technology Center | Open Energy Information

    Open Energy Info (EERE)

    Name: Greenhouse Gas Technology Center Place: North Carolina Zip: 27709 Product: North Carolina-based partnership focused on environmental technology verification. References:...

  9. Federal Register Notice for Life Cycle Greenhouse Gas Perspective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Federal Register Notice for Life Cycle Greenhouse Gas Perspective on Exporting Liquefied ...

  10. EIA Energy Efficiency-Energy Related Greenhouse Gas Emissions...

    U.S. Energy Information Administration (EIA) Indexed Site

    Related Greenhouse Gas Emissions Links Energy Related Greenhouse Gas Emissions Links Posted Date: May 2007 Page Last Modified: September 2010 EIA Links Disclaimer: These pages...

  11. Regional Greenhouse Gas Initiative Inc RGGI | Open Energy Information

    Open Energy Info (EERE)

    Greenhouse Gas Initiative Inc RGGI Jump to: navigation, search Name: Regional Greenhouse Gas Initiative, Inc (RGGI) Place: New York Zip: NY 10007 Sector: Services Product: New...

  12. Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation...

    Open Energy Info (EERE)

    Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation Potential in Agriculture) Jump to: navigation, search Logo: Monitoring and Assessment of Greenhouse Gas...

  13. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Biofuels & Greenhouse Gas Emissions: Myths versus Facts (107.15 KB) More Documents & Publications Biofuels & Greenhouse Gas Emissions: Myths versus Facts Microsoft Word - ...

  14. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department...

    Energy Savers [EERE]

    myth versus facts about biofuels and greenhouse gas emissions. Biofuels & Greenhouse Gas Emissions: Myths versus Facts (166.88 KB) More Documents & Publications Microsoft Word - ...

  15. Energy Information Administration--Energy and Greenhouse Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Efficiency > Energy and Greenhouse Gas Analysis Energy and Greenhouse Gas Analysis Posted Date: October 1999 Page Last Modified: August 2007 This section contains analysis covering...

  16. DOE Strengthens Public Registry to Track Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Public Registry to Track Greenhouse Gas Emissions DOE Strengthens Public Registry to Track Greenhouse Gas Emissions April 17, 2006 - 10:20am Addthis Announces Revised Guidelines ...

  17. Energy Department Releases New Greenhouse Gas Reporting Guidance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Greenhouse Gas Reporting Guidance, Seeks Public Comment Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks Public Comment March 22, 2005 - 10:54am Addthis ...

  18. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate ...

  19. Agriculture and Land Use National Greenhouse Gas Inventory Software...

    Open Energy Info (EERE)

    Agriculture and Land Use National Greenhouse Gas Inventory Software Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Agriculture and Land Use National Greenhouse Gas...

  20. IPCC Guidelines for National Greenhouse Gas Inventories | Open...

    Open Energy Info (EERE)

    Guidelines for National Greenhouse Gas Inventories Jump to: navigation, search Tool Summary Name: IPCC Guidelines for National Greenhouse Gas Inventories AgencyCompany...

  1. Greenhouse Gas Reductions: SF6 | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Reductions: SF6 Share Description Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of...

  2. Ethiopia-National Greenhouse Gas Emissions Baseline Scenarios...

    Open Energy Info (EERE)

    National Greenhouse Gas Emissions Baseline Scenarios: Learning from Experiences in Developing Countries Jump to: navigation, search Name Ethiopia-National Greenhouse Gas Emissions...

  3. Managing the National Greenhouse Gas Inventory Process | Open...

    Open Energy Info (EERE)

    Managing the National Greenhouse Gas Inventory Process Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Managing the National Greenhouse Gas Inventory Process Agency...

  4. Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Greenhouse Gas Emissions: The Combined Potential of Hybrid Technology and Behavioral Adaptation Title Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas...

  5. Greenhouse gas mitigation options for Washington State

    SciTech Connect (OSTI)

    Garcia, N.

    1996-04-01

    President Clinton, in 1993, established a goal for the United States to return emissions of greenhouse gases to 1990 levels by the year 2000. One effort established to help meet this goal was a three part Environmental Protection Agency state grant program. Washington State completed part one of this program with the release of the 1990 greenhouse gas emissions inventory and 2010 projected inventory. This document completes part two by detailing alternative greenhouse gas mitigation options. In part three of the program EPA, working in partnership with the States, may help fund innovative greenhouse gas reduction strategies. The greenhouse gas control options analyzed in this report have a wide range of greenhouse gas reductions, costs, and implementation requirements. In order to select and implement a prudent mix of control strategies, policy makers need to have some notion of the potential change in climate, the consequences of that change and the uncertainties contained therein. By understanding the risks of climate change, policy makers can better balance the use of scarce public resources for concerns that are immediate and present against those that affect future generations. Therefore, prior to analyzing alternative greenhouse gas control measures, this report briefly describes the phenomenon and uncertainties of global climate change, and then projects the likely consequences for Washington state.

  6. Reservoir Greenhouse Gas Emissions at Russian HPP

    SciTech Connect (OSTI)

    Fedorov, M. P.; Elistratov, V. V.; Maslikov, V. I.; Sidorenko, G. I.; Chusov, A. N.; Atrashenok, V. P.; Molodtsov, D. V.; Savvichev, A. S.; Zinchenko, A. V.

    2015-05-15

    Studies of greenhouse-gas emissions from the surfaces of the world’s reservoirs, which has demonstrated ambiguity of assessments of the effect of reservoirs on greenhouse-gas emissions to the atmosphere, is analyzed. It is recommended that greenhouse- gas emissions from various reservoirs be assessed by the procedure “GHG Measurement Guidelines for Fresh Water Reservoirs” (2010) for the purpose of creating a data base with results of standardized measurements. Aprogram for research into greenhouse-gas emissions is being developed at the St. Petersburg Polytechnic University in conformity with the IHA procedure at the reservoirs impounded by the Sayano-Shushenskaya and Mainskaya HPP operated by the RusHydro Co.

  7. Bibliography of greenhouse-gas reduction strategies

    SciTech Connect (OSTI)

    Tompkins, M.M.; Mintz, M.M.

    1995-03-01

    A bibliography of greenhouse-gas reduction strategies has been compiled to assist the Climate change Action Plan Task Force in their consideration of strategies to reduce greenhouse-gas emissions from personal motor vehicles. The document contains a summary of the literature, including it major directions and implications; and annotated listing of 32 recent pertinent documents; and a listing of a larger group of related reports.

  8. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  9. Annual Greenhouse Gas and Sustainability Data Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Greenhouse Gas and Sustainability Data Report Annual Greenhouse Gas and Sustainability Data Report This Excel workbook (version 6-1) is a tool to use for comprehensive reporting of fiscal year 2015 for energy, costs, square footage, and associated operational data for calculating and reporting greenhouse gas data. This document is to be used by top-tier Federal departments and agencies. This Data Report collects agency-aggregated data necessary for calculating scope 1, 2, and 3 greenhouse gas

  10. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER...

    Office of Scientific and Technical Information (OSTI)

    ... CONVERSION; ENGINES; EXPLORATION; FUEL CELLS; GAS TURBINES; GREENHOUSE GASES; HOT WATER; INTERNAL COMBUSTION ENGINES; NATURAL GAS; THERMAL RECOVERY; TURBINES; WASTE HEAT; WASTES

  11. Asia Least-Cost Greenhouse Gas Abatement Study | Open Energy...

    Open Energy Info (EERE)

    Gas Abatement Study Jump to: navigation, search Name Asia Least-Cost Greenhouse Gas Abatement Study (ALGAS) AgencyCompany Organization Global Environment Facility,...

  12. Navigating the Numbers: Greenhouse Gas Data and International...

    Open Energy Info (EERE)

    Gas Data and International Climate Policy1 Overview "This report examines greenhouse gas (GHG) emissions at the global, national, sectoral, and fuel levels and identifies...

  13. Greenhouse Gas Management Program Overview (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-11-01

    Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2}), methane (CH{sub 4

  14. Using Coupled Harmonic Oscillators to Model Some Greenhouse Gas Molecules

    SciTech Connect (OSTI)

    Go, Clark Kendrick C.; Maquiling, Joel T.

    2010-07-28

    Common greenhouse gas molecules SF{sub 6}, NO{sub 2}, CH{sub 4}, and CO{sub 2} are modeled as harmonic oscillators whose potential and kinetic energies are derived. Using the Euler-Lagrange equation, their equations of motion are derived and their phase portraits are plotted. The authors use these data to attempt to explain the lifespan of these gases in the atmosphere.

  15. Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Employer-Subsidized Commuting Options | Department of Energy 9: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options Providing workplace charging is one of the more effective ways for businesses to reduce the greenhouse gas emissions of their employees' daily commute. Offering a bike purchase subsidy can be even more cost effective but may not be suitable for

  16. Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Employer-Subsidized Commuting Options - Dataset | Department of Energy 9: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options - Dataset Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options - Dataset Excel file and dataset for Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options fotw#879_web.xlsx (18.59 KB) More Documents & Publications Vehicle Technologies Office Fall 2015 Quarterly

  17. Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Public Comment | Department of Energy Greenhouse Gas Reporting Guidance, Seeks Public Comment Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks Public Comment March 22, 2005 - 10:54am Addthis Program Will Ensure Greater Accuracy & Completeness WASHINGTON, D.C. - The U.S. Department of Energy (DOE) today asked for further public comment on its revised guidelines for voluntary reporting of greenhouse gas emissions, sequestration and emission reductions. The program

  18. CEQ Releases Final Guidance on Consideration of Greenhouse Gas Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Effects of Climate Change in NEPA | Department of Energy CEQ Releases Final Guidance on Consideration of Greenhouse Gas Emissions and Effects of Climate Change in NEPA CEQ Releases Final Guidance on Consideration of Greenhouse Gas Emissions and Effects of Climate Change in NEPA August 3, 2016 - 1:58pm Addthis CEQ released its Final Guidance for Federal Departments and Agencies on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in National Environmental Policy

  19. Buildings Greenhouse Gas Mitigation Estimator Worksheet | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Buildings Greenhouse Gas Mitigation Estimator Worksheet Buildings Greenhouse Gas Mitigation Estimator Worksheet Excel tool helps agencies estimate the greenhouse gas (GHG) mitigation reduction from implementing energy efficiency measures across a portfolio of buildings. It is designed to be applied to groups of office buildings. For example, at a program level (regional or site) that can be summarized at the agency level. While the default savings and cost estimates apply to office

  20. Greenhouse Gas Emissions from Aviation and Marine Transportation...

    Open Energy Info (EERE)

    and Policies Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potentials and Policies...

  1. #AskBerkeleyLab: Jeff Greenblatt Talks Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Greenblatt, Jeff

    2015-02-02

    We received questions from our social media audience around California's goal to dramatically reduce its greenhouse gas emissions by 2030. Berkeley Lab scientist Jeff Greenblatt answers them here.

  2. Greenhouse Gas Services AES GE EFS | Open Energy Information

    Open Energy Info (EERE)

    Services (AESGE EFS) Place: Arlington, Virginia Zip: 22203-4168 Product: Develop and invest in a range of projects that reduce greenhouse gas emissions that produce verified GHG...

  3. Analysis shows greenhouse gas emissions similar for shale, crude...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Michael Wang, Argonne senior scientist and lead on the GREET model Analysis shows greenhouse gas emissions similar for shale, crude oil By Tona Kunz * October 15, 2015 Tweet ...

  4. GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy...

    Open Energy Info (EERE)

    a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential...

  5. The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (carbon dioxide, methane, nitrous oxide, and carbon dioxide equivalent) for each facility as well as total...

  6. The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (including carbon dioxide, methane, nitrous oxide, carbon dioxide equivalent, and biogenic carbon dioxide) for each...

  7. Greenhouse Gas Initiative Scenario Database | Open Energy Information

    Open Energy Info (EERE)

    TOOL Name: Greenhouse Gas Initiative Scenario Database AgencyCompany Organization: Science for Global Insight Sector: Climate, Energy, Land Topics: Baseline projection, GHG...

  8. The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary...

    Open Energy Info (EERE)

    Interface: Spreadsheet Website: www.ghgprotocol.orgcalculation-toolsall-tools Cost: Free References: Stationary Combustion Guidance1 The Greenhouse Gas Protocol tool for...

  9. The Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigerati...

    Open Energy Info (EERE)

    Interface: Spreadsheet Website: www.ghgprotocol.orgcalculation-toolsall-tools Cost: Free References: Refrigerant Guide1 The Greenhouse Gas Protocol tool for refrigeration is...

  10. Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation...

    Open Energy Info (EERE)

    the MAGHG project is to support developing countries assess and report their greenhouse gas (GHG) emissions from agriculture, including assessment of mitigation options for...

  11. NETL - Petroleum-Based Fuels Life Cycle Greenhouse Gas Analysis...

    Open Energy Info (EERE)

    search Tool Summary LAUNCH TOOL Name: NETL - Petroleum-Based Fuels Life Cycle Greenhouse Gas Analysis 2005 Baseline Model AgencyCompany Organization: National Energy Technology...

  12. Verifying Greenhouse Gas Emissions: Methods to Support International...

    Open Energy Info (EERE)

    Climate Agreements Jump to: navigation, search Tool Summary Name: Verifying Greenhouse Gas Emissions: Methods to Support International Climate Agreements AgencyCompany...

  13. Greenhouse Gas Emission Trends and Projections in Europe 2009...

    Open Energy Info (EERE)

    Liechtenstein, Poland and Turkey provided updated information on emission projections and national programmes in 2009." References "Greenhouse Gas Emission Trends and...

  14. Greenhouse Gas Training Program for Inventory and Mitigation...

    Open Energy Info (EERE)

    divisionsfuture-perfect Country: South Korea Eastern Asia Language: English References: Greenhouse Gas Training Program for Inventory and Mitigation Modeling1...

  15. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology As natural gas travels through infrastructure, from well-head to customer meter, small ...

  16. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  17. Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook (Technical...

    Office of Scientific and Technical Information (OSTI)

    Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook Citation Details In-Document Search Title: Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook The Greenhouse Gas ...

  18. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUID BED BOILERS (Phase II--Evaluation of the Oxyfuel CFB Concept)

    SciTech Connect (OSTI)

    John L. Marion; Nsakala ya Nsakala

    2003-11-09

    The overall project goal is to determine if carbon dioxide can be captured and sequestered at a cost of about $10/ton of carbon avoided, using a newly constructed Circulating Fluidized Bed combustor while burning coal with a mixture of oxygen and recycled flue gas, instead of air. This project is structured in two Phases. Phase I was performed between September 28, 2001 and May 15, 2002. Results from Phase I were documented in a Topical Report issued on May 15, 2003 (Nsakala, et al., 2003), with the recommendation to evaluate, during Phase II, the Oxyfuel-fired CFB concept. DOE NETL accepted this recommendation, and, hence approved the project continuation into Phase II. Phase 2. The second phase of the project--which includes pilot-scale tests of an oxygen-fired circulating fluidized bed test facility with performance and economic analyses--is currently underway at ALSTOM's Power Plant Laboratories, located in Windsor, CT (US). The objective of the pilot-scale testing is to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in oxygen/carbon dioxide mixtures. Results will be used in the design of oxygen-fired CFB boilers--both retrofit and new Greenfield--as well as to provide a generic performance database for other researchers. At the conclusion of Phase 2, revised costs and performance will be estimated for both retrofit and new Greenfield design concepts with CO2 capture, purification, compression, and liquefaction.

  19. Estonian greenhouse gas emissions inventory report

    SciTech Connect (OSTI)

    Punning, J.M.; Ilomets, M.; Karindi, A.; Mandre, M.; Reisner, V.; Martins, A.; Pesur, A.; Roostalu, H.; Tullus, H.

    1996-07-01

    It is widely accepted that the increase of greenhouse gas concentrations in the atmosphere due to human activities would result in warming of the Earth`s surface. To examine this effect and better understand how the GHG increase in the atmosphere might change the climate in the future, how ecosystems and societies in different regions of the World should adapt to these changes, what must policymakers do for the mitigation of that effect, the worldwide project within the Framework Convention on Climate Change was generated by the initiative of United Nations. Estonia is one of more than 150 countries, which signed the Framework Convention on Climate Change at the United Nations Conference on Environment and Development held in Rio de Janeiro in June 1992. In 1994 a new project, Estonian Country Study was initiated within the US Country Studies Program. The project will help to compile the GHG inventory for Estonia, find contemporary trends to investigate the impact of climate change on the Estonian ecosystems and economy and to formulate national strategies for Estonia addressing to global climate change.

  20. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis...

    Office of Environmental Management (EM)

    Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumbenergyuselossemissionslg.gif How...

  1. Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs forEmployer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options Fact 879: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting ...

  2. Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs forEmployer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options - Dataset Fact 879: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized ...

  3. Greenhouse gas reduction strategy: A team approach to resource management

    SciTech Connect (OSTI)

    Ngai, C.C.; Borchert, G.; Ho, K.T.; Lee, S.

    1996-12-31

    In spite of the conflicting evidence of global warming due to greenhouse gas emission, PanCanadian accepts the reduction of greenhouse gas as both a political and environmental reality. While PanCanadian is committed to participate in the government and industry sponsored voluntary climate change challenge, we are also acutely aware of its potential impact on our competitiveness considering our status as a hydrocarbon producer and exporter. This paper describes a multi-discipline team approach to the challenge of reducing greenhouse gas. This includes identification of all greenhouse gas emission sources, listing the opportunities and relative impact of each remedial solution, and estimated cost associated with the reduction. Both immediate solutions and long term strategies are explored. This includes energy conservation, improving process efficiency and promoting environmental training and awareness programs. A number of important issues become evident in greenhouse gas reduction related to the exploration and production of hydrocarbons: depleting pressure and water encroachment in reservoirs; energy required for producing oil as opposed to producing gas; and public perception of flaring as compared with venting. A cost and benefit study of greenhouse gas reduction opportunities in terms of net present values is discussed. This paper describes a process that can be adapted by other producers in managing air emissions.

  4. Interagency Pilot of Greenhouse Gas Accounting Tools: Lessons Learned

    SciTech Connect (OSTI)

    Carpenter, A.; Hotchkiss, E.; Kandt, A.

    2013-02-01

    The Greater Yellowstone Area (GYA) and Tongass National Forest (Tongass) partnered with the National Renewable Energy Laboratory (NREL) to conduct a pilot study of three greenhouse gas (GHG) inventorying tools.

  5. Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal NREL pledges to cut carbon footprint, impact on environment by 75 percent December 4, 2007 The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) has pledged to reduce its greenhouse gas emissions by 75 percent from 2005 to 2009. The new goal is part of NREL's participation in the Environmental Protection Agency's (EPA) Climate Leaders program and was announced at the Climate Leaders meeting in Boulder, Colo.,

  6. DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    through Deployment of Advanced Technology | Department of Energy Draft Strategic Plan for Reducing Greenhouse Gas Emissions through Deployment of Advanced Technology DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas Emissions through Deployment of Advanced Technology September 22, 2005 - 10:45am Addthis WASHINGTON, DC - The Department of Energy today released for public review and comment a plan for accelerating the development and reducing the cost of new and advanced

  7. FETC Programs for Reducing Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Ruether, J.A.

    1998-02-01

    Mark Twain once quipped that everyone talks about the weather but no one does anything about it. With interest in global climate change on the rise, researchers in the fossil-energy sector are feeling the heat to provide new technology to permit continued use of fossil fuels but with reduced emissions of so-called `greenhouse gases.` Three important greenhouse gases, carbon dioxide, methane, and nitrous oxide, are released to the atmosphere in the course of recovering and combusting fossil fuels. Their importance for trapping radiation, called forcing, is in the order given. In this report, we briefly review how greenhouse gases cause forcing and why this has a warming effect on the Earth`s atmosphere. Then we discuss programs underway at FETC that are aimed at reducing emissions of methane and carbon dioxide.

  8. Mitigating Greenhouse Gas Emissions: Voluntary Reporting 1996

    Reports and Publications (EIA)

    1997-01-01

    Presents information on voluntary actions to reduce greenhouse gases or remove such gases from the atmosphere in 1995. It provides an overview of participation in the Voluntary Reporting Program, a perspective on the composition of activities reported, and a review of some key issues in interpreting and evaluating achievements associated with reported emissions mitigation initiatives.

  9. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions

  10. Greenhouse Gas Emissions and Fuel Use

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... 1: Natural gas flaring associated with crude oil production ......as "lease and plant fuel" and for "pipeline and distribution use." 1 * Venting: The ...

  11. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

    Office of Energy Efficiency and Renewable Energy (EERE)

    This analysis calculates the life cycle greenhouse gas (GHG) emissions for regional coal and imported natural gas power in Europe and Asia. The primary research questions are as follows:...

  12. EIA - Greenhouse Gas Emissions - High-GWP gases

    Gasoline and Diesel Fuel Update (EIA)

    5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA

  13. Table 2. U.S. greenhouse gas intensity and related factors, 1990...

    U.S. Energy Information Administration (EIA) Indexed Site

    greenhouse gas intensity and related factors, 1990 to 2009" ,1990,1991,1992,1993,1994,1995...2638.4,12976.2,13228.9,13228.8,12880.6 "Greenhouse Gas Emissions (MMTCO2e)",6133.236268,60...

  14. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck ...

  15. Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign...

    Office of Scientific and Technical Information (OSTI)

    Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report Citation Details In-Document Search Title: Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report ...

  16. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Presented at ...

  17. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumb_energyuse_loss_emissions_lg.gif How effectively is energy used in U.S. manufacturing? How much greenhouse gas (GHG) is emitted from combustion in manufacturing operations? The U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis from the Oak Ridge National Laboratory traces energy from supply (fuel, electricity, and

  18. Fact #608: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 8: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990 Fact #608: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990 In October of 2009, the United Nations (UN) released greenhouse gas inventory data for 1990 to 2007 for all countries that submitted data in accordance with the UN Framework Convention on Climate Change (UNFCCC). Between 1990 and 2007, total aggregate greenhouse gas (GHG) emissions for all reporting countries declined by 3.9%

  19. Statement from U.S. Energy Secretary Moniz on Mexico's Greenhouse Gas Emissions Targets

    Broader source: Energy.gov [DOE]

    Secretary Moniz welcomes the announcement by the Government of Mexico on new greenhouse gas emissions reduction targets.

  20. U.S. Greenhouse Gas Intensity and the Global Climate Change Initiative (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    On February 14, 2002, President Bush announced the Administrations Global Climate Change Initiative. A key goal of the Climate Change Initiative is to reduce U.S. greenhouse gas intensity by 18% over the 2002 to 2012 time frame. For the purposes of the initiative, greenhouse gas intensity is defined as the ratio of total U.S. greenhouse gas emissions to economic output.

  1. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

    Broader source: Energy.gov [DOE]

    On May 29, 2014, the Department of Energy’s (DOE) Office of Fossil Energy announced the availability for public review and comment the report Life Cycle Greenhouse Gas Perspective on Exporting...

  2. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  3. Research on Greenhouse-Gas-Induced Climate Change

    SciTech Connect (OSTI)

    Schlesinger, M. E.

    2001-07-15

    During the 5 years of NSF grant ATM 95-22681 (Research on Greenhouse-Gas-Induced Climate Change, $1,605,000, 9/15/1995 to 8/31/2000) we have performed work which we are described in this report under three topics: (1) Development and Application of Atmosphere, Ocean, Photochemical-Transport, and Coupled Models; (2) Analysis Methods and Estimation; and (3) Climate-Change Scenarios, Impacts and Policy.

  4. Microbial Community Dynamics Dominate Greenhouse Gas Production in Thawing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Permafrost | U.S. DOE Office of Science (SC) Microbial Community Dynamics Dominate Greenhouse Gas Production in Thawing Permafrost Biological and Environmental Research (BER) BER Home About Research Facilities Science Highlights Searchable Archive of BER Highlights External link Benefits of BER Funding Opportunities Biological & Environmental Research Advisory Committee (BERAC) Community Resources Contact Information Biological and Environmental Research U.S. Department of Energy

  5. Idaho National Laboratory's FY11 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2012-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2011 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho.

  6. Idaho National Laboratory FY12 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2013-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2012 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho.

  7. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Marnay, Chris; Stadler, Michael; Lipman, Tim; Lai, Judy; Cardoso, Goncalo; Megel, Olivier

    2009-09-01

    The motivation and objective of this research is to determine the role of distributed generation (DG) in greenhouse gas reductions by: (1) applying the Distributed Energy Resources Customer Adoption Model (DER-CAM); (2) using the California Commercial End-Use Survey (CEUS) database for commercial buildings; (3) selecting buildings with electric peak loads between 100 kW and 5 MW; (4) considering fuel cells, micro-turbines, internal combustion engines, gas turbines with waste heat utilization, solar thermal, and PV; (5) testing of different policy instruments, e.g. feed-in tariff or investment subsidies.

  8. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology

  9. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology

    Office of Energy Efficiency and Renewable Energy (EERE)

    As natural gas travels through infrastructure, from well-head to customer meter, small portions are routinely used as fuel, vented, flared, or inadvertently leaked to the atmosphere. This paper describes the analytical and methodological basis for three diagrams that illustrate the natural gas losses and greenhouse gas emissions that result from these processes. The paper examines these emissions in some detail, focusing in particular on the production, processing, transmission and storage, and distribution segments of natural gas infrastructure.

  10. Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Diagnostics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear

  11. Life Cycle Greenhouse Gas Emissions: Natural Gas and Power Production

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Decrease 48% Decrease 90% Carbon Capture at the Power Plant Results in 80% Reduction in LC GHG Emissions for Coal-fired Power Plants and 70% Reduction for Natural Gas- fired ...

  12. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Not Available

    1997-10-01

    This report serves as the technology basis of a needed national climate change technology strategy, with the confidence that a strong technology R&D program will deliver a portfolio of technologies with the potential to provide very substantial greenhouse gas emission reductions along with continued economic growth. Much more is needed to define such a strategy, including identification of complementary deployment policies and analysis to support the seeping and prioritization of R&D programs. A national strategy must be based upon governmental, industrial, and academic partnerships.

  13. New Generating Technology to Reduce Greenhouse Gas Emissions

    U.S. Energy Information Administration (EIA) Indexed Site

    Generating Technology to Reduce Greenhouse Gas Emissions ENERGY INFORMATION ADMINISTRATION 30 TH BIRTHDAY CONFERENCE April 7, 2008 Linda G. Stuntz Stuntz, Davis & Staffier, P.C. Stuntz, Davis & Staffier, P.C. 2 The Target * Energy related emissions of CO2 will increase by about 16% in AEO 2008 Reference Case between 2006 and 2030 (5,890 MM metric tons to 6,859 MM metric tons). (#s from Caruso Senate Energy testimony of 3/4/08). * Last year, emissions from electricity generation were 40%

  14. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Across the Continental United States | Department of Energy Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Data analysis from this study will provide insight into real-world performance of current emissions reduction devices, under various operating conditions, and with respect to greenhouse gas emissions. p-03_carder.pdf

  15. ARM - Field Campaign - Full-column Greenhouse Gas Sampling 2012-2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsFull-column Greenhouse Gas Sampling 2012-2014 Campaign Links Final Campaign Report ARM Data Discovery Browse Data Related Campaigns Full-column Greenhouse Gas Sampling 2015-2017 2015.03.01, Fischer, SGP Balloon-Borne Full-column Greenhouse Gas Profiling 2014.03.01, Fischer, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Full-column Greenhouse Gas Sampling 2012-2014 2012.01.13 - 2014.02.28 Lead Scientist : Marc Fischer

  16. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  17. Advancing Development and Greenhouse Gas Reductions in Vietnam's Wind Sector

    SciTech Connect (OSTI)

    Bilello, D.; Katz, J.; Esterly, S.; Ogonowski, M.

    2014-09-01

    Clean energy development is a key component of Vietnam's Green Growth Strategy, which establishes a target to reduce greenhouse gas (GHG) emissions from domestic energy activities by 20-30 percent by 2030 relative to a business-as-usual scenario. Vietnam has significant wind energy resources, which, if developed, could help the country reach this target while providing ancillary economic, social, and environmental benefits. Given Vietnam's ambitious clean energy goals and the relatively nascent state of wind energy development in the country, this paper seeks to fulfill two primary objectives: to distill timely and useful information to provincial-level planners, analysts, and project developers as they evaluate opportunities to develop local wind resources; and, to provide insights to policymakers on how coordinated efforts may help advance large-scale wind development, deliver near-term GHG emission reductions, and promote national objectives in the context of a low emission development framework.

  18. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews

    Broader source: Energy.gov [DOE]

    On December 18, 2014, CEQ released revised draft guidance for public comment that describes how Federal departments and agencies should consider the effects of greenhouse gas emissions and climate change in their National Environmental Policy Act reviews. The revised draft guidance supersedes the draft greenhouse gas and climate change guidance released by CEQ in February 2010.

  19. Federal Register Notice for Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy of the Department of Energy gives notice of the availability of the report Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United...

  20. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-08-15

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and

  1. Greenhouse gas emissions from landfill leachate treatment plants...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 54 ENVIRONMENTAL SCIENCES; 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; AGING; CARBON DIOXIDE; GREENHOUSE GASES; LEACHATES; ...

  2. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and

  3. Technology and Greenhouse Gas Emissions: An IntegratedScenario Analysis

    SciTech Connect (OSTI)

    Koomey, J.G.; Latiner, S.; Markel, R.J.; Marnay, C.; Richey, R.C.

    1998-09-01

    This report describes an analysis of possible technology-based scenarios for the U.S. energy system that would result in both carbon savings and net economic benefits. We use a modified version of the Energy Information Administration's National Energy Modeling System (LBNL-NEMS) to assess the potential energy, carbon, and bill savings from a portfolio of carbon saving options. This analysis is based on technology resource potentials estimated in previous bottom-up studies, but it uses the integrated LBNL-NEMS framework to assess interactions and synergies among these options. The analysis in this paper builds on previous estimates of possible "technology paths" to investigate four major components of an aggressive greenhouse gas reduction strategy: (1) the large scale implementation of demand-side efficiency, comparable in scale to that presented in two recent policy studies on this topic; (2) a variety of "alternative" electricity supply-side options, including biomass cofiring, extension of the renewable production tax credit for wind, increased industrial cogeneration, and hydropower refurbishment. (3) the economic retirement of older and less efficient existing fossil-find power plants; and (4) a permit charge of $23 per metric ton of carbon (1996 $/t),l assuming that carbon trading is implemented in the US, and that the carbon permit charge equilibrates at this level. This level of carbon permit charge, as discussed later in the report, is in the likely range for the Clinton Administration's position on this topic.

  4. Idaho National Laboratory's FY13 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2014-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2013 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho. This report details the methods behind quantifying INL’s GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only the large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  5. Estimating the potential of greenhouse gas mitigation in Kazakhstan

    SciTech Connect (OSTI)

    Monacrovich, E.; Pilifosova, O.; Danchuck, D.

    1996-09-01

    As part of the studies related to the obligations of the UN Framework Convention on Climate Change, the Republic of Kazakhstan started activities to inventory greenhouse gas (GHG) emissions and assess of GHG mitigation options, The objective of this paper is to present an estimate of the possibility of mitigating GHG emissions and determine the mitigation priorities. It presents a compilation of the possible options and their assessment in terms of major criteria and implementation feasibility. Taking into account the structure of GHG emissions in Kazakhstan in 1990, preliminary estimates of the potential for mitigation are presented for eight options for the energy sector and agriculture and forestry sector. The reference scenario prepared by expert assessments assumes a reduction of CO{sub 2} emissions in 1996-1998 by about 26% from the 1990 level due to general economic decline, but then emissions increase. It is estimated that the total potential for the mitigation of CO{sub 2} emissions for the year 2000 is 3% of the CO{sub 2} emissions in the reference scenario. The annual reduction in methane emissions due to the estimated options can amount to 5%-6% of the 1990 level. 10 refs., 1 fig., 4 tabs.

  6. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    SciTech Connect (OSTI)

    Greenblatt, Jeffery B.

    2013-10-10

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants

  7. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Vehicles | Department of Energy Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Presented at the U.S. Department of EnergyLight Duty Vehicle Workshop in Washington, D.C. on July 26, 2010. wtw_analysis_phevs.pdf (272.71 KB) More Documents & Publications Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles System

  8. ARM - Field Campaign - Balloon-Borne Full-column Greenhouse Gas Profiling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsBalloon-Borne Full-column Greenhouse Gas Profiling ARM Data Discovery Browse Data Related Campaigns Full-column Greenhouse Gas Sampling 2012-2014 2012.01.13, Fischer, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Balloon-Borne Full-column Greenhouse Gas Profiling 2014.03.01 - 2015.02.28 Lead Scientist : Marc Fischer For data sets, see below. Abstract In this DOE-NOAA collaboration, we produced vertically resolved

  9. Microtrap assembly for greenhouse gas and air pollution monitoring

    DOE Patents [OSTI]

    Mitra, Somenath; Saridara, Chutarat

    2015-08-25

    A microtrap assembly includes a carbon nanotube sorbent. The microtrap assembly may be employed as a preconcentrator operable to deliver a sample to an analytical device to measure the concentrations of greenhouse gases. A system includes a microtrap having a carbon nanotube sorbent for measuring the concentrations of greenhouse gases in a sample.

  10. Gas-phase chemical dynamics

    SciTech Connect (OSTI)

    Weston, R.E. Jr.; Sears, T.J.; Preses, J.M.

    1993-12-01

    Research in this program is directed towards the spectroscopy of small free radicals and reactive molecules and the state-to-state dynamics of gas phase collision, energy transfer, and photodissociation phenomena. Work on several systems is summarized here.

  11. Land-use change and greenhouse gas emissions from corn and cellulosic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Land-use change and greenhouse gas emissions from corn and cellulosic ethanol July 16, ... Estimates of LUC GHG emissions focus mainly on corn ethanol and vary widely. Increasing ...

  12. DOE Technical Assistance on Greenhouse Gas Reduction Strategies in the Electric Power Sector

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) will continue to offer analysis and technical support for state, local, tribal and regional planning efforts related to reducing greenhouse gas emissions in the...

  13. Energy Department Releases Draft Advanced Fossil Energy Solicitation to Support Reductions in Greenhouse Gas Pollution

    Broader source: Energy.gov [DOE]

    As part of President Obama’s Climate Action Plan, DOE announced today a draft loan guarantee solicitation for innovative and advanced fossil energy projects and facilities that substantially reduce greenhouse gas and other air pollution.

  14. Energy Market Impacts of Alternative Greenhouse Gas Intensity Reduction Goals

    Reports and Publications (EIA)

    2006-01-01

    This report responds to a request from Senator Ken Salazar that the Energy Information Administration (EIA) analyze the impacts of implementing alternative variants of an emissions cap-and-trade program for greenhouse gases (GHGs).

  15. NREL Assesses Strategies Needed for Light-Duty Vehicle Greenhouse Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduction - News Releases | NREL NREL Assesses Strategies Needed for Light-Duty Vehicle Greenhouse Gas Reduction Solutions including electric and hydrogen fuel cell vehicles, vehicle connectivity, and automation examined August 8, 2016 The White House wants to cut U.S. greenhouse gas (GHG) emissions by 80 percent by 2050, but the goal raises questions about one of the greatest sources of those pollutants, light-duty vehicles (LDVs). The Energy Department's National Renewable Energy

  16. Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plug-In Hybrid Electric Vehicles | Department of Energy Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles This report examines energy use and emissions from primary energy source through vehicle operation to help researchers understand the impact of the upstream mix of electricity generation technologies for recharging plug-in hybrid electric vehicles

  17. Electricity price impacts of alternative Greenhouse gas emission cap-and-trade programs

    SciTech Connect (OSTI)

    Edelston, Bruce; Armstrong, Dave; Kirsch, Laurence D.; Morey, Mathew J.

    2009-07-15

    Limits on greenhouse gas emissions would raise the prices of the goods and services that require such emissions for their production, including electricity. Looking at a variety of emission limit cases and scenarios for selling or allocating allowances to load-serving entities, the authors estimate how the burden of greenhouse gas limits are likely to be distributed among electricity consumers in different states. (author)

  18. Guidance on Consideration of Greenhouse Gas Emissions and the Effects of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Climate Change in National Environmental Policy Act Reviews (CEQ, 2016) | Department of Energy on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in National Environmental Policy Act Reviews (CEQ, 2016) Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in National Environmental Policy Act Reviews (CEQ, 2016) The Council on Environmental Quality (CEQ) released its Final Guidance for Federal Departments and Agencies on

  19. Idaho National Laboratory’s FY14 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Frerichs, Kimberly Irene

    2015-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2014 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions. INL’s GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL’s organizational boundaries, but are a consequence of INL’s activities). This inventory found that INL generated 73,521 metric tons (MT) of CO2 equivalent (CO2e ) emissions during FY14. The following conclusions were made from looking at the results of the individual contributors to INL’s FY14 GHG inventory: • Electricity (including the associated transmission and distribution losses) is the largest contributor to INL’s GHG inventory, with over 50% of the CO2e emissions • Other sources with high emissions were

  20. Idaho National Laboratory’s Greenhouse Gas FY08 Baseline

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2010-09-01

    A greenhouse gas (GHG) inventory is a systematic attempt to account for the production and release of certain gasses generated by an institution from various emission sources. The gasses of interest are those which have become identified by climate science as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2008 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. Concern about the environmental impact of GHGs has grown in recent years. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of a baseline estimate of total GHGs generated at the INL. Additionally, the INL has a desire to see how its emissions compare with similar institutions, including other DOE-sponsored national laboratories. Executive Order 13514 requires that federally-sponsored agencies and institutions document reductions in GHG emissions in the future, and such documentation will require knowledge of a baseline against which reductions can be measured. INL’s FY08 GHG inventory was calculated according to methodologies identified in Federal recommendations and an as-yet-unpublished Technical and Support Document (TSD) using operational control boundary. It measures emissions generated in three Scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL’s organizational boundaries but are a consequence of INL’s activities). This inventory found that INL generated a total of 114,256 MT of CO2-equivalent emissions during fiscal year 2008 (FY08). The following conclusions were made from looking at the results of the individual contributors to INL

  1. Idaho National Laboratory’s Greenhouse Gas FY08 Baseline

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2011-06-01

    A greenhouse gas (GHG) inventory is a systematic attempt to account for the production and release of certain gasses generated by an institution from various emission sources. The gasses of interest are those which have become identified by climate science as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2008 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. Concern about the environmental impact of GHGs has grown in recent years. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of a baseline estimate of total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions in the future, and such documentation will require knowledge of a baseline against which reductions can be measured. INL's FY08 GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three Scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL's organizational boundaries but are a consequence of INL's activities). This inventory found that INL generated a total of 113,049 MT of CO2-equivalent emissions during FY08. The following conclusions were made from looking at the results of the individual contributors to INL's baseline GHG inventory: (1) Electricity (including the associated transmission and distribution losses) is the

  2. Greenhouse gas emissions from forest, land use and biomass burning in Tanzania

    SciTech Connect (OSTI)

    Matitu, M.R.

    1994-12-31

    Carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) gases are the main contributors to the greenhouse effect that consequently results in global warming. This paper examines the sources and sinks of these gases from/to forest, land use and biomass burning and their likely contribution to climate change using IPCC/OECD methodology. Emissions have been calculated in mass units of carbon and nitrogen Emissions and uptake have been summed for each gas and the emissions converted to full molecular weights. Mismanagement of forests and land misuse have contributed much to greenhouse gas emissions in Tanzania. For example, cultivation methods, forest clearing, burning of savannah grass and indiscriminate logging (non-sustainable logging) have contributed significantly to greenhouse gas emissions. These categories contribute more than 90% of total CO{sub 2} emissions. However, the study shows that shifting cultivation, savannah burning and forest clearing for conversion to permanent crop land and pasture are the main contributors.

  3. Table 3. Distribution of total U.S. greenhouse gas emissions by sector, 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    Distribution of total U.S. greenhouse gas emissions by sector, 2009 " "Greenhouse Gas and Source","Sector" ,"Residential","Commercial","Industrial","Transportation","Total" "Carbon Dioxide" " Energy-Related",1172.297835,1012.323586,1417.683142,1757.250685,5359.555248 " Industrial Processes",,,87.282832,,87.282832 "Total CO2",1172.297835,1012.323586,1504.965974,1757.250685,5446.83808

  4. Greenhouse Gas Regional Inventory Protocol (GRIP) Website | Open...

    Open Energy Info (EERE)

    URI: cleanenergysolutions.orgcontentgreenhouse-gas-regional-inventory-pro Language: English Policies: Deployment Programs DeploymentPrograms: "Lead by Example" is not...

  5. Performance analysis of a latent heat storage system with phase change material for new designed solar collectors in greenhouse heating

    SciTech Connect (OSTI)

    Benli, Hueseyin; Durmus, Aydin

    2009-12-15

    The continuous increase in the level of greenhouse gas emissions and the rise in fuel prices are the main driving forces behind the efforts for more effectively utilize various sources of renewable energy. In many parts of the world, direct solar radiation is considered to be one of the most prospective sources of energy. In this study, the thermal performance of a phase change thermal storage unit is analyzed and discussed. The storage unit is a component of ten pieced solar air collectors heating system being developed for space heating of a greenhouse and charging of PCM. CaCl{sub 2}6H{sub 2}O was used as PCM in thermal energy storage with a melting temperature of 29 C. Hot air delivered by ten pieced solar air collector is passed through the PCM to charge the storage unit. The stored heat is utilized to heat ambient air before being admitted to a greenhouse. This study is based on experimental results of the PCM employed to analyze the transient thermal behavior of the storage unit during the charge and discharge periods. The proposed size of collectors integrated PCM provided about 18-23% of total daily thermal energy requirements of the greenhouse for 3-4 h, in comparison with the conventional heating device. (author)

  6. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  7. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied...

    Office of Environmental Management (EM)

    The primary research questions are as follows: *How does exported liquefied natural gas (LNG) from the U.S. compare with regional coal (or other LNG sources) for electric power ...

  8. State Commission electricity regulation under Federal Greenhouse gas cap-and-trade policy

    SciTech Connect (OSTI)

    Keeler, Andrew G.

    2008-05-15

    Given the current uncertainty about the timing and severity of greenhouse gas constraints on electric generation that will result from a federal program, commissions need to begin crafting strategies and procedures to best serve the public interest in this new environment. (author)

  9. Transformative Reduction of Transportation Greenhouse Gas Emissions. Opportunities for Change in Technologies and Systems

    SciTech Connect (OSTI)

    Vimmerstedt, Laura; Brown, Austin; Newes, Emily; Markel, Tony; Schroeder, Alex; Zhang, Yimin; Chipman, Peter; Johnson, Shawn

    2015-04-30

    The transportation sector is changing, influenced by concurrent, ongoing, dynamic trends that could dramatically affect the future energy landscape, including effects on the potential for greenhouse gas emissions reductions. Battery cost reductions and improved performance coupled with a growing number of electric vehicle model offerings are enabling greater battery electric vehicle market penetration, and advances in fuel cell technology and decreases in hydrogen production costs are leading to initial fuel cell vehicle offerings. Radically more efficient vehicles based on both conventional and new drivetrain technologies reduce greenhouse gas emissions per vehicle-mile. Net impacts also depend on the energy sources used for propulsion, and these are changing with increased use of renewable energy and unconventional fossil fuel resources. Connected and automated vehicles are emerging for personal and freight transportation systems and could increase use of low- or non-emitting technologies and systems; however, the net effects of automation on greenhouse gas emissions are uncertain. The longstanding trend of an annual increase in transportation demand has reversed for personal vehicle miles traveled in recent years, demonstrating the possibility of lower-travel future scenarios. Finally, advanced biofuel pathways have continued to develop, highlighting low-carbon and in some cases carbon-negative fuel pathways. We discuss the potential for transformative reductions in petroleum use and greenhouse gas emissions through these emerging transportation-sector technologies and trends and present a Clean Transportation Sector Initiative scenario for such reductions, which are summarized in Table ES-1.

  10. White House Announces New Executive Order To Reduce Greenhouse Gas Emissions in the Federal Government

    Broader source: Energy.gov [DOE]

    The White House today announced that President Obama will issue a new executive order that will cut the federal government's greenhouse gas emissions 40% over the next decade (from 2008 levels) and increase the share of electricity the federal government consumes from renewable sources to 30%.

  11. U.S. Greenhouse Gas Intensity and the Global Climate Change Initiative (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On February 14, 2002, President Bush announced the Administrations Global Climate Change Initiative. A key goal of the Climate Change Initiative is to reduce U.S. greenhouse gas (GHG) intensity-defined as the ratio of total U.S. GHG emissions to economic output-by 18% over the 2002 to 2012 time frame.

  12. Regulating greenhouse gas 'leakage': how California can evade the impending constitutional attacks

    SciTech Connect (OSTI)

    Brian H. Potts

    2006-06-15

    Federalist greenhouse gas regulation poses many constitutional pitfalls, and some fear that California's cap-and-trade and procurement cap proposals are vulnerable to constitutional challenge. An attack under the commerce clause seems to pose the biggest threat, but the author proposes an alternative that can eliminate this threat: market participation.

  13. Assessment of basic research needs for greenhouse gas control technologies

    SciTech Connect (OSTI)

    Benson, S.M.; Chandler, W.; Edmonds, J.; Houghton, J.; Levine, M.; Bates, L.; Chum, H.; Dooley, J.; Grether, D.; Logan, J.; Wiltsee, G.; Wright, L.

    1998-09-01

    This paper is an outgrowth of an effort undertaken by the Department of Energy's Office of Energy Research to assess the fundamental research needs to support a national program in carbon management. Five topics were identified as areas where carbon management strategies and technologies might be developed: (1) capture of carbon dioxide, decarbonization strategies, and carbon dioxide disposal and utilization; (2) hydrogen development and fuel cells; (3) enhancement of the natural carbon cycle; (4) biomass production and utilization; and (5) improvement of the efficiency of energy production, conversion, and utilization. Within each of these general areas, experts came together to identify targets of opportunity for fundamental research likely to lead to the development of mid- to long-term solutions for stabilizing or decreasing carbon dioxide and other greenhouse gases in the atmosphere. Basic research to support the options outlined above are far reaching-from understanding natural global processes such as the ocean and terrestrial carbon cycles to development of new materials and concepts for chemical separation. Examples of fundamental research needs are described in this paper.

  14. A review of water and greenhouse gas impacts of unconventional natural gas development in the United States

    SciTech Connect (OSTI)

    Arent, Doug; Logan, Jeff; Macknick, Jordan; Boyd, William; Medlock , Kenneth; O'Sullivan, Francis; Edmonds, James A.; Clarke, Leon E.; Huntington, Hill; Heath, Garvin; Statwick, Patricia M.; Bazilian, Morgan

    2015-01-01

    This paper reviews recent developments in the production and use of unconventional natural gas in the United States with a focus on water and greenhouse gas emission implications. If unconventional natural gas in the U.S. is produced responsibly, transported and distributed with little leakage, and incorporated into integrated energy systems that are designed for future resiliency, it could play a significant role in realizing a more sustainable energy future; however, the increased use of natural gas as a substitute for more carbon intensive fuels will alone not substantially alter world carbon dioxide concentration projections.

  15. Greenhouse gas mitigation in a carbon constrained world - the role of CCS in Germany

    SciTech Connect (OSTI)

    Schumacher, Katja; Sands, Ronald D.

    2009-01-05

    In a carbon constrained world, at least four classes of greenhouse gas mitigation options are available: energy efficiency, switching to low or carbon-free energy sources, introduction of carbon dioxide capture and storage along with electric generating technologies, and reductions in emissions of non-CO2 greenhouse gases. The contribution of each option to overall greenhouse gas mitigation varies by cost, scale, and timing. In particular, carbon dioxide capture and storage (CCS) promises to allow for low-emissions fossil-fuel based power generation. This is particularly relevant for Germany, where electricity generation is largely coal-based and, at the same time, ambitious climate targets are in place. Our objective is to provide a balanced analysis of the various classes of greenhouse gas mitigation options with a particular focus on CCS for Germany. We simulate the potential role of advanced fossil fuel based electricity generating technologies with CCS (IGCC, NGCC) as well the potential for retrofit with CCS for existing and currently built fossil plants from the present through 2050. We employ a computable general equilibrium (CGE) economic model as a core model and integrating tool.

  16. Impacts of Vehicle Weight Reduction via Material Substitution on Life-Cycle Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Kelly, Jarod C.; Sullivan, John L.; Burnham, Andrew; Elgowainy, Amgad

    2015-10-20

    This study examines the vehicle-cycle impacts associated with substituting lightweight materials for those currently found in light-duty passenger vehicles. We determine part-based energy use and greenhouse gas (GHG) emission ratios by collecting material substitution data from both the literature and automotive experts and evaluating that alongside known mass-based energy use and GHG emission ratios associated with material pair substitutions. Several vehicle parts, along with full vehicle systems, are examined for lightweighting via material substitution to observe the associated impact on GHG emissions. Results are contextualized by additionally examining fuel-cycle GHG reductions associated with mass reductions relative to the baseline vehicle during the use phase and also determining material pair breakeven driving distances for GHG emissions. The findings show that, while material substitution is useful in reducing vehicle weight, it often increases vehicle-cycle GHGs depending upon the material substitution pair. However, for a vehicle’s total life cycle, fuel economy benefits are greater than the increased burdens associated with the vehicle manufacturing cycle, resulting in a net total life-cycle GHG benefit. The vehicle cycle will become increasingly important in total vehicle life-cycle GHGs, since fuel-cycle GHGs will be gradually reduced as automakers ramp up vehicle efficiency to meet fuel economy standards.

  17. The Greenhouse Gases, Regulated Emissions, and Energy Use in...

    Open Energy Info (EERE)

    Energy Use in Transportation Model (GREET Fleet) AgencyCompany Organization: Argonne National Laboratory Sector: Energy Focus Area: Greenhouse Gas, Transportation Phase:...

  18. References and Appendices: U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis, November 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis REFERENCES AMO (Advanced Manufacturing Office), EERE (Energy Efficiency and Renewable Energy). 2012a. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators. U.S. Department of Energy. http://www1.eere.energy.gov/manufacturing/tech_deployment/pdfs/steam22_backpressure.pdf AMO (Advanced Manufacturing Office), EERE (Energy Efficiency and Renewable Energy). 2012b. Improving Steam System Performance: A

  19. California Greenhouse Gas Emissions Standards for Light-Duty Vehicles (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    In July 2002, California Assembly Bill 1493 (A.B. 1493) was signed into law. The law requires that the California Air Resources Board (CARB) develop and adopt, by January 1, 2005, greenhouse gas emission standards for light-duty vehicles that provide the maximum feasible reduction in emissions. In estimating the feasibility of the standard, CARB is required to consider cost-effectiveness, technological capability, economic impacts, and flexibility for manufacturers in meeting the standard.

  20. Estimating the greenhouse gas benefits of forestry projects: A Costa Rican Case Study

    SciTech Connect (OSTI)

    Busch, Christopher; Sathaye, Jayant; Sanchez Azofeifa, G. Arturo

    2000-09-01

    If the Clean Development Mechanism proposed under the Kyoto Protocol is to serve as an effective means for combating global climate change, it will depend upon reliable estimates of greenhouse gas benefits. This paper sketches the theoretical basis for estimating the greenhouse gas benefits of forestry projects and suggests lessons learned based on a case study of Costa Rica's Protected Areas Project, which is a 500,000 hectare effort to reduce deforestation and enhance reforestation. The Protected Areas Project in many senses advances the state of the art for Clean Development Mechanism-type forestry projects, as does the third-party verification work of SGS International Certification Services on the project. Nonetheless, sensitivity analysis shows that carbon benefit estimates for the project vary widely based on the imputed deforestation rate in the baseline scenario, e.g. the deforestation rate expected if the project were not implemented. This, along with a newly available national dataset that confirms other research showing a slower rate of deforestation in Costa Rica, suggests that the use of the 1979--1992 forest cover data originally as the basis for estimating carbon savings should be reconsidered. When the newly available data is substituted, carbon savings amount to 8.9 Mt (million tones) of carbon, down from the original estimate of 15.7 Mt. The primary general conclusion is that project developers should give more attention to the forecasting land use and land cover change scenarios underlying estimates of greenhouse gas benefits.

  1. CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews

    Broader source: Energy.gov [DOE]

    The Council on Environmental Quality (CEQ) issued revised draft guidance on consideration of greenhouse gas (GHG) emissions and the effects of climate change in National Environmental Policy Act (NEPA) reviews on December 18, 2014

  2. DOE’s Carbon Storage Advances Featured in Special Issue of International Journal of Greenhouse Gas Control

    Office of Energy Efficiency and Renewable Energy (EERE)

    A special issue of the International Journal of Greenhouse Gas Control (IJGGC) was released on August 17, 2016 highlighting carbon-storage research conducted under the Energy Department’s National Risk Assessment Partnership (NRAP).

  3. Greenhouse gas mitigation technology results of CO{sub 2} capture & disposal studies

    SciTech Connect (OSTI)

    Audus, H.; Riemer, P.W.F.; Ormerod, W.G.

    1995-12-31

    In response to the increase in the global concentrations of greenhouse gases, the IEA Greenhouse Gas R&D Programme is carrying out an assessment of greenhouse gas abatement technologies with particular reference to carbon dioxide emissions from fossil-fuel power generation systems. The Programme has examined, on a consistent basis, the options available for capturing and disposing of the CO{sub 2} product from a range of gas and coal fired power generation plant types, each with an output of 500MW(e). Systems under consideration include PF+FGD, IGCC, NGCC and a CO{sub 2}/O{sub 2} recycle scheme. CO{sub 2} capture technologies considered include chemical and physical absorption, solid adsorption, cryogenics, membrane separation and gas separation membranes. Carbon dioxide disposal options considered are; disposal in the oceans, in aquifers, in depleted gas reservoirs and terrestrial storage as a solid. In addition, a number of studies have evaluated the utilisation of CO{sub 2} for enhanced oil recovery and the manufacture of chemicals, including a detailed investigation of dimethyl carbonate production. Comparison is also made with the alternative stance of compensatory forest plantations and substitution of fossil fuels with biomass. Emphasis has been placed on a requirement to determine the impact of the various technologies on the cost of electricity generation. This has been achieved by analysing the core of specific schemes, on a common basis, and comparative results are presented for various CO{sub 2} abatement options. A member of studies have also been carried out to evaluate transport options and the environmental impact of these technology combinations for carbon dioxide disposal. The results indicate that by combining the most favourable technologies for CO{sub 2} capture and disposal to efficient power generation technology, electricity generation costs could be increased by around 50%. Alternative schemes have similar or even greater cost penalties.

  4. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  5. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    SciTech Connect (OSTI)

    Shen, Bo; Price, Lynn K; Lu, Hongyou; Liu, Xu; Tsen, Katherine; Xiangyang, Wei; Yunpeng, Zhang; Jian, Guan; Rui, Hou; Junfeng, Zhang; Yuqun, Zhuo; Shumao, Xia; Yafeng, Han; Manzhi, Liu

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  6. Energy-saving options for the mitigation of greenhouse gas emissions from the Mongolian energy sector

    SciTech Connect (OSTI)

    Dorjpurev, J.; Purevjal, O.; Erdenechimeg, Ch.

    1996-12-31

    The Energy sector is the largest contributor to GHG emission in Mongolia. The Energy sector emits 54 percent of CO2 and 4 percent of methane. All emissions of other greenhouse gases are accounted from energy related activities. The activities in this sector include coal production, fuel combustion, and biomass combustion at the thermal power stations and in private houses (stoves) for heating purposes. This paper presents some important Demand-side options considered for mitigation of CO2 emissions from energy sector such as Energy Conservation in Industrial Sector and in Buildings. Changes in energy policies and programmes in the Mongolian situation that promote more efficient and sustainable practices are presented in the paper. These energy saving measures will not only help reduce greenhouse gas emissions, but will also promote economic development and alleviate other environmental problems.

  7. Greenhouse gas emission impacts of alternative-fueled vehicles: Near-term vs. long-term technology options

    SciTech Connect (OSTI)

    Wang, M.Q.

    1997-05-20

    Alternative-fueled vehicle technologies have been promoted and used for reducing petroleum use, urban air pollution, and greenhouse gas emissions. In this paper, greenhouse gas emission impacts of near-term and long-term light-duty alternative-fueled vehicle technologies are evaluated. Near-term technologies, available now, include vehicles fueled with M85 (85% methanol and 15% gasoline by volume), E85 (85% ethanol that is produced from corn and 15% gasoline by volume), compressed natural gas, and liquefied petroleum gas. Long-term technologies, assumed to be available around the year 2010, include battery-powered electric vehicles, hybrid electric vehicles, vehicles fueled with E85 (ethanol produced from biomass), and fuel-cell vehicles fueled with hydrogen or methanol. The near-term technologies are found to have small to moderate effects on vehicle greenhouse gas emissions. On the other hand, the long-term technologies, especially those using renewable energy (such as biomass and solar energy), have great potential for reducing vehicle greenhouse gas emissions. In order to realize this greenhouse gas emission reduction potential, R and D efforts must continue on the long-term technology options so that they can compete successfully with conventional vehicle technology.

  8. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott; Theiss, Timothy J; Bunce, Michael

    2012-01-01

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  9. Understanding the Design and Performance of Emissions Trading Systems for Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Toman, M.

    1999-01-31

    Research Spotlight presents new research findings and projects underway at Resources for the Future that are relevant to the analysis of climate change policy. As interest in greenhouse gas trading policies grows in the United States and other Annex I countries, so does the need for stronger analytical tools. The paper by Tietenberg in this collection lays out some of the principal conceptual issues that analysts face in providing more accurate and relevant tools and results for decisionmakers. In this paper we build on Tietenberg's analysis to consider some of the key modeling challenges that analysts face in developing an improved capacity for quantitatively assessing real-world policies.

  10. Preliminary Estimates of Combined Heat and Power Greenhouse GasAbatement Potential for California in 2020

    SciTech Connect (OSTI)

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare,Kristina

    2007-07-31

    The objective of this scoping project is to help the California Energy Commission's (CEC) Public Interest Energy Research (PIER) Program determine where it should make investments in research to support combined heat and power (CHP) deployment. Specifically, this project will: {sm_bullet} Determine what impact CHP might have in reducing greenhouse gas (GHG) emissions, {sm_bullet} Determine which CHP strategies might encourage the most attractive early adoption, {sm_bullet} Identify the regulatory and technological barriers to the most attractive CHP strategies, and {sm_bullet} Make recommendations to the PIER program as to research that is needed to support the most attractive CHP strategies.

  11. Beyond the Inventory: An Interagency Collaboration to Reduce Greenhouse Gas Emissions in the Greater Yellowstone Area

    SciTech Connect (OSTI)

    Kandt, A.; Hotchkiss, E.; Fiebig, M.

    2010-10-01

    As one of the largest, intact ecosystems in the continental United States, land managers within the Greater Yellowstone Area (GYA) have recognized the importance of compiling and understanding agency greenhouse gas (GHG) emissions. The 10 Federal units within the GYA have taken an active role in compiling GHG inventories on a unit- and ecosystem-wide level, setting goals for GHG mitigation, and identifying mitigation strategies for achieving those goals. This paper details the processes, methodologies, challenges, solutions, and lessons learned by the 10 Federal units within the GYA throughout this ongoing effort.

  12. Effects of Travel Reduction and Efficient Driving on Transportation: Energy Use and Greenhouse Gas Emissions

    Broader source: Energy.gov [DOE]

    Numerous transportation strategies are directed at reducing energy use and greenhouse gas (GHG) emissions by changing the behavior of individual drivers or travelers. These behavioral changes may have the effect of reducing travel, shifting travel to more efficient modes, or improving the efficiency of existing travel. Since the 1970s, federal, regional, state and municipal agencies have tried to reduce energy use, emissions, and congestion by influencing travel behavior. This report reviews and summarizes the literature on relationships between these strategies and transportation-related energy use and GHG emissions to examine how changes to travel behavior can reduce transportation energy use and discuss the potential for federal actions to affect travel behavior.

  13. Greenhouse gas emission impacts of electric vehicles under varying driving cycles in various counties and US cities

    SciTech Connect (OSTI)

    Wang, M.Q.; Marr, W.W.

    1994-02-10

    Electric vehicles (EVs) can reduce greenhouse gas emissions, relative to emissions from gasoline-fueled vehicles. However, those studies have not considered all aspects that determine greenhouse gas emissions from both gasoline vehicles (GVs) and EVs. Aspects often overlooked include variations in vehicle trip characteristics, inclusion of all greenhouse gases, and vehicle total fuel cycle. In this paper, we estimate greenhouse gas emission reductions for EVs, including these important aspects. We select four US cities (Boston, Chicago, Los Angeles, and Washington, D.C.) and six countries (Australia, France, Japan, Norway, the United Kingdom, and the United States) and analyze greenhouse emission impacts of EVs in each city or country. We also select six driving cycles developed around the world (i.e., the US federal urban driving cycle, the Economic Community of Europe cycle 15, the Japanese 10-mode cycle, the Los Angeles 92 cycle, the New York City cycle, and the Sydney cycle). Note that we have not analyzed EVs in high-speed driving (e.g., highway driving), where the results would be less favorable to EVs; here, EVs are regarded as urban vehicles only. We choose one specific driving cycle for a given city or country and estimate the energy consumption of four-passenger compact electric and gasoline cars in the given city or country. Finally, we estimate total fuel cycle greenhouse gas emissions of both GVs and EVs by accounting for emissions from primary energy recovery, transportation, and processing; energy product transportation; and powerplant and vehicle operations.

  14. Energy Market and Economic Impacts Proposal to Reduce Greenhouse Gas Intensity with a Cap and Trade System

    Reports and Publications (EIA)

    2007-01-01

    This report was prepared by the Energy Information Administration (EIA), in response to a September 27, 2006, request from Senators Bingaman, Landrieu, Murkowski, Specter, Salazar, and Lugar. The Senators requested that EIA assess the impacts of a proposal that would regulate emissions of greenhouse gases (GHGs) through an allowance cap-and-trade system. The program would set the cap to achieve a reduction in emissions relative to economic output, or greenhouse gas intensity.

  15. Contribution of cooperative sector recycling to greenhouse gas emissions reduction: A case study of Ribeirão Pires, Brazil

    SciTech Connect (OSTI)

    King, Megan F.; Gutberlet, Jutta

    2013-12-15

    Highlights: • Cooperative recycling achieves environmental, economic and social objectives. • We calculate GHG emissions reduction for a recycling cooperative in São Paulo, Brazil. • The cooperative merits consideration as a Clean Development Mechanism (CDM) project. • A CDM project would enhance the achievements of the recycling cooperative. • National and local waste management policies support the recycling cooperative. - Abstract: Solid waste, including municipal waste and its management, is a major challenge for most cities and among the key contributors to climate change. Greenhouse gas emissions can be reduced through recovery and recycling of resources from the municipal solid waste stream. In São Paulo, Brazil, recycling cooperatives play a crucial role in providing recycling services including collection, separation, cleaning, stocking, and sale of recyclable resources. The present research attempts to measure the greenhouse gas emission reductions achieved by the recycling cooperative Cooperpires, as well as highlight its socioeconomic benefits. Methods include participant observation, structured interviews, questionnaire application, and greenhouse gas accounting of recycling using a Clean Development Mechanism methodology. The results show that recycling cooperatives can achieve important energy savings and reductions in greenhouse gas emissions, and suggest there is an opportunity for Cooperpires and other similar recycling groups to participate in the carbon credit market. Based on these findings, the authors created a simple greenhouse gas accounting calculator for recyclers to estimate their emissions reductions.

  16. The California Climate Action Registry: Development of methodologies for calculating greenhouse gas emissions from electricity generation

    SciTech Connect (OSTI)

    Price, Lynn; Marnay, Chris; Sathaye, Jayant; Muritshaw, Scott; Fisher, Diane; Phadke, Amol; Franco, Guido

    2002-08-01

    The California Climate Action Registry, which will begin operation in Fall 2002, is a voluntary registry for California businesses and organizations to record annual greenhouse gas emissions. Reporting of emissions in the Registry by a participant involves documentation of both ''direct'' emissions from sources that are under the entity's control and ''indirect'' emissions controlled by others. Electricity generated by an off-site power source is considered to be an indirect emission and must be included in the entity's report. Published electricity emissions factors for the State of California vary considerably due to differences in whether utility-owned out-of-state generation, non-utility generation, and electricity imports from other states are included. This paper describes the development of three methods for estimating electricity emissions factors for calculating the combined net carbon dioxide emissions from all generating facilities that provide electricity to Californians. We find that use of a statewide average electricity emissions factor could drastically under- or over-estimate an entity's emissions due to the differences in generating resources among the utility service areas and seasonal variations. In addition, differentiating between marginal and average emissions is essential to accurately estimate the carbon dioxide savings from reducing electricity use. Results of this work will be taken into consideration by the Registry when finalizing its guidance for use of electricity emissions factors in calculating an entity's greenhouse gas emissions.

  17. Environmental implications of alternative-fueled automobiles: Air quality and greenhouse gas tradeoffs

    SciTech Connect (OSTI)

    MaClean, H.L.; Lave, L.B.

    2000-01-15

    The authors analyze alternative fuel-powerstrain options for internal combustion engine automobiles. Fuel/engine efficiency, energy use, pollutant discharges, and greenhouse gas emissions are estimated for spark and compression ignited, direct injected (DI), and indirect injected (II) engines fueled by conventional and reformulated gasoline, reformulated diesel, compressed natural gas (CNG), and alcohols. Since comparisons of fuels and technologies in dissimilar vehicles are misleading, the authors hold emissions level, range, vehicle size class, and style constant. At present, CNG vehicles have the best exhaust emissions performance while DI diesels have the worst. Compared to a conventional gasoline fueled II automobile, greenhouse gases could be reduced by 40% by a DI CNG automobile and by 25% by a DI diesel. Gasoline- and diesel-fueled automobiles are able to attain long ranges with little weight or fuel economy penalty. CNG vehicles have the highest penalty for increasing range, due to their heavy fuel storage systems, but are the most attractive for a 160-km range. DI engines, particularly diesels, may not be able to meet strict emissions standards, at least not without lowering efficiency.

  18. Greenhouse gas mitigation options in the forestry sector of The Gambia: Analysis based on COMAP model

    SciTech Connect (OSTI)

    Jallow, B.P.

    1996-12-31

    Results of the 1993 Greenhouse Gas Emissions Inventory of The Gambia showed net CO{sub 2} emissions of over (1.66 x 10{sup 6} tons) and 1% was due to uptake by plantations (0.01 x 10{sup 6} tons). This is a clear indication that there is need to identify changes in the land-use policy, law and tenure that discourages forest clearing at the same time significantly influencing the sustainable distribution of land among forestry, rangeland and livestock, and agriculture. About 11% of the total area of The Gambia is either fallow or barren flats that once supported vegetation and hence is still capable of supporting vegetation. The US Country Study Programme has provided the Government of The Gambia through the National Climate Committee funds to conduct Assessment of Mitigation Options to Reduce Greenhouse Gas Emissions. The Forestry Sector is one area for which assessment is being conducted. The assessment is expected to end in September 1996. The Comprehensive Mitigation Analysis Process (COMAP) is one of the Models supplied to the National Climate Committee by the Lawrence Berkeley Laboratory, on behalf of the US Country Study Programme, and is being used to conduct the analysis in The Gambia.

  19. Reliable Muddle: Transportation Scenarios for the 80% Greenhouse Gas Reduction Goal for 2050 (Presentation)

    SciTech Connect (OSTI)

    Melaina, M.; Webster, K.

    2009-10-28

    Presentation describing transportation scenarios for meeting the 2050 DOE goal of reducing greenhouse gases by 80%.

  20. Sector trends and driving forces of global energy use and greenhouse gas emissions: focus in industry and buildings

    SciTech Connect (OSTI)

    Price, Lynn; Worrell, Ernst; Khrushch, Marta

    1999-09-01

    Disaggregation of sectoral energy use and greenhouse gas emissions trends reveals striking differences between sectors and regions of the world. Understanding key driving forces in the energy end-use sectors provides insights for development of projections of future greenhouse gas emissions. This report examines global and regional historical trends in energy use and carbon emissions in the industrial, buildings, transport, and agriculture sectors, with a more detailed focus on industry and buildings. Activity and economic drivers as well as trends in energy and carbon intensity are evaluated. The authors show that macro-economic indicators, such as GDP, are insufficient for comprehending trends and driving forces at the sectoral level. These indicators need to be supplemented with sector-specific information for a more complete understanding of future energy use and greenhouse gas emissions.

  1. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO 2 concentration data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ogle, Stephen; Davis, Kenneth J.; Lauvaux, Thomas; Schuh, Andrew E.; Cooley, Dan; West, Tristram O.; Heath, L.; Miles, Natasha; Richardson, S. J.; Breidt, F. Jay; et al

    2015-03-10

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country’s contribution to GHG concentrations in the atmosphere. Verification could include a variety of evidence, but arguably the most convincing verification would be confirmation of a change in GHG concentrations in the atmosphere that is consistent with reported emissions to the UNFCCC. We report here on a case study evaluating this option based on a prototype atmospheric CO2 measurement network deployed in the Mid-Continent Region of themore » conterminous United States. We found that the atmospheric CO2 measurement data did verify the accuracy of the emissions inventory within the confidence limits of the emissions estimates, suggesting that this technology could be further developed and deployed more widely in the future for verifying reported emissions.« less

  2. Idaho National Laboratory (INL) Site Greenhouse Gas (GHG) Monitoring Plan - 40 CFR 98

    SciTech Connect (OSTI)

    Deborah L. Layton; Kimberly Frerichs

    2010-07-01

    The purpose of this Greenhouse Gas (GHG) Monitoring Plan is to meet the monitoring plan requirements of Title 40 of the Code of Federal Regulations Part 98.3(g)(5). This GHG Monitoring Plan identifies procedures and methodologies used at the Idaho National Laboratory Site (INL Site) to collect data used for GHG emissions calculations and reporting requirements from stationary combustion and other regulated sources in accordance with 40 CFR 98, Subparts A and other applicable subparts. INL Site Contractors determined subpart applicability through the use of a checklist (Appendix A). Each facility/contractor reviews operations to determine which subparts are applicable and the results are compiled to determine which subparts are applicable to the INL Site. This plan is applicable to the 40 CFR 98-regulated activities managed by the INL Site contractors: Idaho National Laboratory (INL), Idaho Cleanup Project (ICP), Advanced Mixed Waste Treatment Project (AMWTP), and Naval Reactors Facilities (NRF).

  3. Idaho National Laboratory (INL) Site Greenhouse Gas (GHG) Monitoring Plan - 40 CFR 98

    SciTech Connect (OSTI)

    Deborah L. Layton; Kimberly Frerichs

    2011-12-01

    The purpose of this Greenhouse Gas (GHG) Monitoring Plan is to meet the monitoring plan requirements of Title 40 of the Code of Federal Regulations Part 98.3(g)(5). This GHG Monitoring Plan identifies procedures and methodologies used at the Idaho National Laboratory Site (INL Site) to collect data used for GHG emissions calculations and reporting requirements from stationary combustion and other regulated sources in accordance with 40 CFR 98, Subparts A and other applicable subparts. INL Site Contractors determined subpart applicability through the use of a checklist (Appendix A). Each facility/contractor reviews operations to determine which subparts are applicable and the results are compiled to determine which subparts are applicable to the INL Site. This plan is applicable to the 40 CFR 98-regulated activities managed by the INL Site contractors: Idaho National Laboratory (INL), Idaho Cleanup Project (ICP), Advanced Mixed Waste Treatment Project (AMWTP), and Naval Reactors Facilities (NRF).

  4. U.S. Energy and Greenhouse Gas Model V2.0-2.X

    Energy Science and Technology Software Center (OSTI)

    2004-11-01

    The IJ.S. Energy and Greenhouse Gas Model (USEGM) is designed as a high-level dynamic simulation model to facilitate policy discussions on a real-time basis. The model focuses on U.S. energy demand by economic and electric power sectors through 2025, and is driven by gross domestic product (GOP), energy prices, energy intensities, and population effects. Price and GDP effects on energy demand are captured using a distributed lag model that allows demand to change over severalmore » years in response to price and GOP changes in a given year. Fuel allocation in the electricity sector is determined using a logistic formulation that takes into account relative electricity costs and existing capital allocation. Model outputs include energy demand by sector and type, carbon dioxide emissions, and oil import requirements.« less

  5. Calculators for Estimating Greenhouse Gas Emissions from Public Transit Agency Vehicle Fleet Operations

    SciTech Connect (OSTI)

    Weigel, Brent; Southworth, Frank; Meyer, Michael D

    2010-01-01

    This paper reviews calculation tools available for quantifying the greenhouse gas emissions associated with different types of public transit service, and their usefulness in helping a transit agency to reduce its carbon footprint through informed vehicle and fuel procurement decisions. Available calculators fall into two categories: registry/inventory based calculators most suitable for standardized voluntary reporting, carbon trading, and regulatory compliance; and multi-modal life cycle analysis calculators that seek comprehensive coverage of all direct and indirect emissions. Despite significant progress in calculator development, no single calculator as yet contains all of the information needed by transit agencies to develop a truly comprehensive, life cycle analysis-based accounting of the emissions produced by its vehicle fleet operations, and for a wide range of vehicle/fuel technology options.

  6. Opportunities to change development pathways toward lower greenhouse gas emissions through energy efficiency

    SciTech Connect (OSTI)

    Alterra, Swart; Masanet, Eric; Lecocq, Franck; Najam, Adil; Schaeffer, Robert; Winkler, Harald; Sathaye, Jayant

    2008-07-04

    There is a multiplicity of development pathways in which low energy sector emissions are not necessarily associated with low economic growth. However, changes in development pathways can rarely be imposed from the top. On this basis, examples of energy efficiency opportunities to change development pathways toward lower emissions are presented in this paper. We review opportunities at the sectoral and macro level. The potential for action on nonclimate policies that influence energy use and emissions are presented. Examples are drawn from policies already adopted and implemented in the energy sector. The paper discusses relationships between energy efficiency policies and their synergies and tradeoffs with sustainable development and greenhouse gas emissions. It points to ways that energy efficiency could be mainstreamed into devel?opment choices.

  7. Methods for ensuring compliance in an international greenhouse gas trading system

    SciTech Connect (OSTI)

    Hargrave, T.; Helme, E.A.

    1998-12-31

    At the third Conference of the Parties to the UN Framework Convention on Climate Change held in December, 1997, the international community established binding greenhouse gas (GHG) emissions obligations for industrialized countries. The Parties to the new Kyoto Protocol also agreed on the use of a number of market-based mechanisms, including international GHG emissions trading. These market mechanisms were of critical to the importance because they have the potential to significantly reduce the costs of treaty compliance. In principle, an international cap-and-trade system appears to be one of the most cost-effective means of reducing GHG emissions. Maintaining the integrity of the trading system is of primary importance in ensuring that trading helps countries to meet their GHG commitments. This paper explores methods for ensuring compliance in an international greenhouse gas trading system, starting with a discussion of preconditions for participation in trading and then moving to features of an international compliance system. Achieving maximum compliance with international requirements may best be accomplished by limiting participation in trading to Annex I countries that maintain strong domestic compliance systems. Prior to the climate negotiations in Kyoto in December 1997, the US Administration proposed a number of preconditions for participation in trading, including the adoption of international measurement standards and the establishment of domestic compliance and enforcement programs. This paper explores these and other preconditions, including the establishment of tough domestic financial penalties on companies that exceed allowed emissions and seller responsibility for the delivery of real reductions. The paper also discusses several necessary features of the international compliance system.

  8. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study

    SciTech Connect (OSTI)

    2013-04-30

    BroadRock Renewables, LLC built two high efficiency electricity generating facilities that utilize landfill gas in California and Rhode Island. The two projects received a total of $25 million in U.S. Department of Energy funding from the American Recovery and Reinvestment Act (ARRA) of 2009. Private-sector cost share for the projects totaled approximately $186 million.

  9. Comparing the greenhouse gas emissions from three alternative waste combustion concepts

    SciTech Connect (OSTI)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilae, Kai; Hupa, Mikko

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

  10. Gas-phase propane fuel delivery system

    SciTech Connect (OSTI)

    Clements, J.

    1991-04-30

    This patent describes a gas-phase fuel delivery system for delivering a vapor phase fuel independent of exterior temperatures. It comprises:a storage tank for storing a volume of fuel; a regulator in fluid communication with the tank for receiving fuel from the tank and for outputting the fuel in a vapor phase; a pressure sensor in fluid communication with the tank for monitoring pressure within the tank, the pressure sensor being operative to generate a pump enable signal when the pressure within the tank is less than a predetermined threshold; a pump in fluid communication with the tank.

  11. Renewable energy development in China: Resource assessment, technology status, and greenhouse gas mitigation potential

    SciTech Connect (OSTI)

    Wan, Y.; Renne, O.D.; Junfeng, Li

    1996-12-31

    China, which has pursued aggressive policies to encourage economic development, could experience the world`s fastest growth in energy consumption over the next two decades. China has become the third largest energy user in the world since 1990 when primary energy consumption reached 960 million tons of coal equivalent (tce). Energy use is increasing at an annual rate of 6-7% despite severe infrastructure and capital constraints on energy sector development. Energy consumption in China is heavily dominated by coal, and fossil fuels provide up to 95% of all commercial energy use. Coal currently accounts for 77% of total primary energy use; oil, 16%; hydropower, 5%; and natural gas, 2%. Coal is expected to continue providing close to three-quarters of all energy consumed, and the amount of coal used is expected to triple by year 2020. Currently, renewable energy resources (except for hydropower) account for only a fraction of total energy consumption. However, the estimated growth in greenhouse gas emissions, as well as serious local and regional environmental pollution problems caused by combustion of fossil fuels, provides strong arguments for the development of renewable energy resources. Renewable energy potential in China is significantly greater than that indicated by the current level of use. With a clear policy goal and consistent efforts from the Government of China, renewables can play a far larger role in its future energy supply.

  12. Hydrogen production and delivery analysis in US markets : cost, energy and greenhouse gas emissions.

    SciTech Connect (OSTI)

    Mintz, M.; Gillette, J.; Elgowainy, A.

    2009-01-01

    Hydrogen production cost conclusions are: (1) Steam Methane Reforming (SMR) is the least-cost production option at current natural gas prices and for initial hydrogen vehicle penetration rates, at high production rates, SMR may not be the least-cost option; (2) Unlike coal and nuclear technologies, the cost of natural gas feedstock is the largest contributor to SMR production cost; (3) Coal- and nuclear-based hydrogen production have significant penalties at small production rates (and benefits at large rates); (4) Nuclear production of hydrogen is likely to have large economies of scale, but because fixed O&M costs are uncertain, the magnitude of these effects may be understated; and (5) Given H2A default assumptions for fuel prices, process efficiencies and labor costs, nuclear-based hydrogen is likely to be more expensive to produce than coal-based hydrogen. Carbon taxes and caps can narrow the gap. Hydrogen delivery cost conclusions are: (1) For smaller urban markets, compressed gas delivery appears most economic, although cost inputs for high-pressure gas trucks are uncertain; (2) For larger urban markets, pipeline delivery is least costly; (3) Distance from hydrogen production plant to city gate may change relative costs (all results shown assume 100 km); (4) Pipeline costs may be reduced with system 'rationalization', primarily reductions in service pipeline mileage; and (5) Liquefier and pipeline capital costs are a hurdle, particularly at small market sizes. Some energy and greenhouse gas Observations: (1) Energy use (per kg of H2) declines slightly with increasing production or delivery rate for most components (unless energy efficiency varies appreciably with scale, e.g., liquefaction); (2) Energy use is a strong function of production technology and delivery mode; (3) GHG emissions reflect the energy efficiency and carbon content of each component in a production-delivery pathway; (4) Coal and natural gas production pathways have high energy consumption

  13. The potential for biomass to mitigate greenhouse gas emissions in the Northeastern US. Northeast Regional Biomass Program

    SciTech Connect (OSTI)

    Bernow, S.S.; Gurney, K.; Prince, G.; Cyr, M.

    1992-04-01

    This study, for the Northeast Regional Biomass Program (NRBP) of the Coalition of Northeast Governors (CONEG), evaluates the potential for local, state and regional biomass policies to contribute to an overall energy/biomass strategy for the reduction of greenhouse gas releases in the Northeastern United States. Biomass is a conditionally renewable resource that can play a dual role: by reducing emissions of greenhouse gases in meeting our energy needs; and by removing carbon from the atmosphere and sequestering it in standing biomass stocks and long-lived products. In this study we examine the contribution of biomass to the energy system in the Northeast and to the region`s net releases of carbon dioxide and methane, and project these releases over three decades, given a continuation of current trends and policies. We then compare this Reference Case with three alternative scenarios, assuming successively more aggressive efforts to reduce greenhouse gas emissions through strategic implementation of energy efficiency and biomass resources. Finally, we identify and examine policy options for expanding the role of biomass in the region`s energy and greenhouse gas mitigation strategies.

  14. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-12-16

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

  15. Receptors useful for gas phase chemical sensing

    SciTech Connect (OSTI)

    Jaworski, Justyn W; Lee, Seung-Wuk; Majumdar, Arunava; Raorane, Digvijay A

    2015-02-17

    The invention provides for a receptor, capable of binding to a target molecule, linked to a hygroscopic polymer or hydrogel; and the use of this receptor in a device for detecting the target molecule in a gaseous and/or liquid phase. The invention also provides for a method for detecting the presence of a target molecule in the gas phase using the device. In particular, the receptor can be a peptide capable of binding a 2,4,6-trinitrotoluene (TNT) or 2,4,-dinitrotoluene (DNT).

  16. A greenhouse-gas information system monitoring and validating emissions reporting and mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K; Dimotakis, Paul E; Walker, Bruce C

    2011-09-26

    Current GHG-mitigating regimes, whether internationally agreed or self-imposed, rely on the aggregation of self-reported data, with limited checks for consistency and accuracy, for monitoring. As nations commit to more stringent GHG emissions-mitigation actions and as economic rewards or penalties are attached to emission levels, self-reported data will require independent confirmation that they are accurate and reliable, if they are to provide the basis for critical choices and actions that may be required. Supporting emissions-mitigation efforts and agreements, as well as monitoring energy- and fossil-fuel intensive national and global activities would be best achieved by a process of: (1) monitoring of emissions and emission-mitigation actions, based, in part, on, (2) (self-) reporting of pertinent bottom-up inventory data, (3) verification that reported data derive from and are consistent with agreed-upon processes and procedures, and (4) validation that reported emissions and emissions-mitigation action data are correct, based on independent measurements (top-down) derived from a suite of sensors in space, air, land, and, possibly, sea, used to deduce and attribute anthropogenic emissions. These data would be assessed and used to deduce and attribute measured GHG concentrations to anthropogenic emissions, attributed geographically and, to the extent possible, by economic sector. The validation element is needed to provide independent assurance that emissions are in accord with reported values, and should be considered as an important addition to the accepted MRV process, leading to a MRV&V process. This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a

  17. Alternatives to Traditional Transportation Fuels 1994 Volume 2 Greenhouse Gas Emissions

    Reports and Publications (EIA)

    1996-01-01

    This report provides information on greenhouse gases GHGs) as required by Section 503 a(4) and b(3) of the Energy Policy Act of 1992 (EPACT).

  18. Evaluating greenhouse gas emissions from hydropower complexes on large rivers in Eastern Washington

    SciTech Connect (OSTI)

    Arntzen, Evan V.; Miller, Benjamin L.; O'Toole, Amanda C.; Niehus, Sara E.; Richmond, Marshall C.

    2013-03-15

    Water bodies, such as freshwater lakes, are known to be net emitters of carbon dioxide (CO2), and methane (CH4). In recent years, significant greenhouse gas (GHG) emissions from tropical, boreal, and mid-latitude reservoirs have been reported. At a time when hydropower is increasing worldwide, better understanding of seasonal and regional variation in GHG emissions is needed in order to develop a predictive understanding of such fluxes within man-made impoundments. We examined power-producing dam complexes within xeric temperate locations in the northwestern United States. Sampling environments on the Snake (Lower Monumental Dam Complex) and Columbia Rivers (Priest Rapids Dam Complex) included tributary, mainstem, embayment, forebay, and tailrace areas during winter and summer 2012. At each sampling location, GHG measurement pathways included surface gas flux, degassing as water passed through dams during power generation, ebullition within littoral embayments, and direct sampling of hyporheic pore-water. Measurements were also carried out in a free-flowing reach of the Columbia River to estimate unaltered conditions. Surface flux resulted in very low emissions, with reservoirs acting as a sink for CO2 (up to –262 mg m-2 d-1, which is within the range previously reported for similarly located reservoirs). Surface flux of methane remained below 1 mg CH4 m-2d-1, a value well below fluxes reported previously for temperate reservoirs. Water passing through hydroelectric projects acted as a sink for CO2 during winter and a small source during summer, with mean degassing fluxes of –117 and 4.5 t CO2 d-1, respectively. Degassing of CH4 was minimal, with mean fluxes of 3.1 × 10-6 and –5.6 × 10-4 t CH4 d-1 during winter and summer, respectively. Gas flux due to ebullition was greater in coves located within reservoirs than in coves within the free flowing Hanford Reach–and CH4 flux exceeded that of CO2. Methane emissions varied widely across sampling locations

  19. A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K.; Dimotakis, Paul E.; Walker, Bruce C.

    2011-09-26

    This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS.

  20. Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils

    SciTech Connect (OSTI)

    Jeremy Semrau; Sung-Woo Lee; Jeongdae Im; Sukhwan Yoon; Michael Barcelona

    2010-09-30

    The overall objective of this project, 'Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils' was to develop effective, efficient, and economic methodologies by which microbial production of nitrous oxide can be minimized while also maximizing microbial consumption of methane in landfill cover soils. A combination of laboratory and field site experiments found that the addition of nitrogen and phenylacetylene stimulated in situ methane oxidation while minimizing nitrous oxide production. Molecular analyses also indicated that methane-oxidizing bacteria may play a significant role in not only removing methane, but in nitrous oxide production as well, although the contribution of ammonia-oxidizing archaea to nitrous oxide production can not be excluded at this time. Future efforts to control both methane and nitrous oxide emissions from landfills as well as from other environments (e.g., agricultural soils) should consider these issues. Finally, a methanotrophic biofiltration system was designed and modeled for the promotion of methanotrophic activity in local methane 'hotspots' such as landfills. Model results as well as economic analyses of these biofilters indicate that the use of methanotrophic biofilters for controlling methane emissions is technically feasible, and provided either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive.

  1. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a methodmore » for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.« less

  2. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    SciTech Connect (OSTI)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a method for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.

  3. Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health

    SciTech Connect (OSTI)

    West, Jason; Smith, Steven J.; Silva, Raquel; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zacariah; Fry, Meridith M.; Anenberg, Susan C.; Horowitz, L.; Lamarque, Jean-Francois

    2013-10-01

    Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. Relative to a reference scenario, global GHG mitigation in the RCP4.5 scenario avoids 0.50.2, 1.30.6, and 2.21.6 million premature deaths in 2030, 2050, and 2100, from changes in fine particulate matter and ozone. Global average marginal co-benefits of avoided mortality are $40-400 (ton CO2)-1, exceeding marginal abatement costs in 2030 and 2050, and within the low range of costs in 2100. East Asian co-benefits are 10-80 times the marginal cost in 2030. These results indicate that transitioning to a low-carbon future might be justified by air quality and health co-benefits.

  4. Meta-Analysis of Estimates of Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power: Preprint

    SciTech Connect (OSTI)

    Heath, G. A.; Burkhardt, J. J.

    2011-09-01

    In reviewing life cycle assessment (LCA) literature of utility-scale CSP systems, this analysis focuses on clarifying central tendency and reducing variability in estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emission estimates passing screens for quality and relevance: 19 for parabolic trough technology and 17 for power tower technology. The interquartile range (IQR) of published GHG emission estimates was 83 and 20 g CO2eq/kWh for trough and tower, respectively, with medians of 26 and 38 g CO2eq/kWh. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. Compared to the published estimates, IQR was reduced by 69% and median increased by 76% for troughs. IQR was reduced by 26% for towers, and median was reduced by 34%. A second level of harmonization was applied to five well-documented trough LC GHG emission estimates, harmonizing to consistent values for GHG emissions embodied in materials and from construction activities. As a result, their median was further reduced by 5%, while the range increased by 6%. In sum, harmonization clarified previous results.

  5. Non-Kyoto Radiative Forcing in Long-Run Greenhouse Gas Emissions and Climate Change Scenarios

    SciTech Connect (OSTI)

    Rose, Steven K.; Richels, Richard G.; Smith, Steven J.; Riahi, Keywan; Stefler, Jessica; Van Vuuren, Detlef

    2014-04-27

    Climate policies designed to achieve climate change objectives must consider radiative forcing from the Kyoto greenhouse gas, as well as other forcing constituents, such as aerosols and tropospheric ozone. Net positive forcing leads to global average temperature increases. Modeling of non-Kyoto forcing is a relatively new component of climate management scenarios. Five of the nineteen models in the EMF-27 Study model both Kyoto and non-Kyoto forcing. This paper describes and assesses current non-Kyoto radiative forcing modeling within these integrated assessment models. The study finds negative forcing from aerosols masking significant positive forcing in reference non-climate policy projections. There are however large differences across models in projected non-Kyoto emissions and forcing, with differences stemming from differences in relationships between Kyoto and non-Kyoto emissions and fundamental differences in modeling structure and assumptions. Air pollution and non-Kyoto forcing decline in the climate policy scenarios. However, non-Kyoto forcing appears to be influencing mitigation results, including allowable carbon dioxide emissions, and further evaluation is merited. Overall, there is substantial uncertainty related to non-Kyoto forcing that must be considered.

  6. Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenatio...

    Office of Scientific and Technical Information (OSTI)

    Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol Citation Details In-Document Search Title: Synergistic Catalysis between Pd and Fe in Gas Phase ...

  7. CO{sub 2} Allowance Allocation in the Regional Greenhouse Gas Initiative and the Effect on Electricity Investors

    SciTech Connect (OSTI)

    Burtraw, Dallas; Kahn, Danny; Palmer, Karen

    2006-03-01

    The Regional Greenhouse Gas Initiative among Northeastern states is expected to lead to an increase in the price of electricity in the region and beyond. In the RGGI region, changes in the value of electricity-generating assets may be positive or negative, while changes outside the Northeast are virtually always positive. For stakeholders in the industry, the change depends on the portfolio of assets held by affected firms. (author)

  8. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Amgad Elgowainy and Michael Wang Center for Transportation Research Argonne National Laboratory LDV Workshop July26, 2010 2 2 2 Team Members 2  ANL's Energy Systems (ES) Division  Michael Wang (team leader)  Dan Santini  Anant Vyas  Amgad Elgowainy  Jeongwoo Han  Aymeric Rousseau  ANL's Decision and Information Sciences (DIS) Division:  Guenter Conzelmann  Leslie Poch 

  9. Energy and greenhouse gas emission effects of corn and cellulosic ethanol with technology improvements and land use changes.

    SciTech Connect (OSTI)

    Wang, M.; Han, J.; Haq, Z; Tyner, .W.; Wu, M.; Elgowainy, A.

    2011-05-01

    Use of ethanol as a transportation fuel in the United States has grown from 76 dam{sup 3} in 1980 to over 40.1 hm{sup 3} in 2009 - and virtually all of it has been produced from corn. It has been debated whether using corn ethanol results in any energy and greenhouse gas benefits. This issue has been especially critical in the past several years, when indirect effects, such as indirect land use changes, associated with U.S. corn ethanol production are considered in evaluation. In the past three years, modeling of direct and indirect land use changes related to the production of corn ethanol has advanced significantly. Meanwhile, technology improvements in key stages of the ethanol life cycle (such as corn farming and ethanol production) have been made. With updated simulation results of direct and indirect land use changes and observed technology improvements in the past several years, we conducted a life-cycle analysis of ethanol and show that at present and in the near future, using corn ethanol reduces greenhouse gas emission by more than 20%, relative to those of petroleum gasoline. On the other hand, second-generation ethanol could achieve much higher reductions in greenhouse gas emissions. In a broader sense, sound evaluation of U.S. biofuel policies should account for both unanticipated consequences and technology potentials. We maintain that the usefulness of such evaluations is to provide insight into how to prevent unanticipated consequences and how to promote efficient technologies with policy intervention.

  10. An expanded review and comparison of greenhouse gas emissions from fossil fuel and geothermal electrical generating facilities

    SciTech Connect (OSTI)

    Booth, R.B.; Neil, P.E.

    1998-12-31

    This paper provides a review of the greenhouse gas emissions due to fossil fuel and geothermal electrical generation and to the emissions of their respective support activities. These support activities consist of, exploration, development, and transportation aspects of the fuel source, including waste management. These support activities could amount to an additional 6% for coal, 22% for oil, 13% for natural gas and 1% for geothermal. The presented methodologies and underlying principles can be used to better define the resultant emissions, rankings and global impacts of these electrical generating industries.

  11. Gas phase thermochemistry of organogermanium compounds

    SciTech Connect (OSTI)

    Engel, J.P.

    1993-12-07

    A variety of silyl- and alkyl-germylene precursors have been synthesized and subsequently pyrolyzed in the gas phase. Arrhenius parameters were obtained employing a pulsed-stirred flow reactor for these unimolecular decompositions. These precursors are divided into two major categories by mechanism of germylene extrusion: {alpha}-elimination precursors and germylacetylenes. The extrusion of germylenes from germylacetylene precursors is of primary interest. A mechanism is proposed employing a germacyclopropene intermediate. Evidence supporting this mechanism is presented. In the process of exploring germylacetylenes as germylene precursors, an apparent dyatropic rearrangement between germanium and silicon was observed. This rearrangement was subsequently explored.

  12. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Warner, E. S.; Heath, G. A.

    2012-04-01

    A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

  13. Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery

    SciTech Connect (OSTI)

    Yang Na; Zhang Hua; Chen Miao; Shao Liming; He Pinjing

    2012-12-15

    Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

  14. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  15. Peru`s national greenhouse gas inventory, 1990. Peru climate change country study

    SciTech Connect (OSTI)

    1996-07-01

    The aim of this study has been to determine the Inventory and to propose greenhouse gases mitigation alternatives in order to face the future development of the country in a clean environmental setting, improving in this way the Peruvian standard of life. The main objective of this executive summary is to show concisely the results of the National Inventory about greenhouse gases emitted by Peru in 1990.

  16. Global warming commitment concept and its application for relative evaluation of greenhouse gas current and future radiative forcing

    SciTech Connect (OSTI)

    Karol, I.L.; Frolkis, V.A.; Kiselev, A.A.

    1996-12-31

    The Global Warming Commitment (GWC) of gas X relative to standard gas A for time period T is proposed, as determined by the formula GWC{sub X}{sup T} = {integral}RF{sub X}(t)dt/{integral}RF{sub A}(t)dt both integrals between limits 0 and T, where RF{sub X}(t) = {Delta}F{sub X}(t) is the Radiative Forcing (RF) of gas X (the net total radiation flux change at the tropopause level caused by the gas X content variation during the 0 to t time period). The well known Global Warming Potential (GWP) is determined by the same formula, where {Delta}F{sub x}(t) is due to instantaneous releases into the atmosphere of the same definite mass (1 kg) of gas X and of standard gas A. In GWC the actual measured or modeled gas contents evolutions are used for estimation of gas X relative input into the current and future greenhouse warming. GWC of principal Greenhouse Gases (GG) are calculated and analyzed for the time period before 1990, based on observed GG content evolution. For periods from now to 2050 the modeled global GG content projections from radiative photochemical atmospheric model are used for several of IPCC-94 scenarios of GG anthropogenic emissions up to 2050. The GWC of CH{sub 4}, N{sub 2}O and CFCs with CO{sub 2} as standard GG are 2--4 times lower, and they are much more accurately reflecting the reality in the above periods than the widely used RFs of these GG relative to GG of CO{sub 2}, when the GG content evolutions during the time period T is not considered.

  17. Building Commissioning: A Golden Opportunity for Reducing Energy Costs and Greenhouse-gas Emissions

    SciTech Connect (OSTI)

    Mills, Evan

    2009-07-16

    available revealed over 10,000 energy-related problems, resulting in 16% median whole-building energy savings in existing buildings and 13% in new construction, with payback time of 1.1 years and 4.2 years, respectively. In terms of other cost-benefit indicators, median benefit-cost ratios of 4.5 and 1.1, and cash-on-cash returns of 91% and 23% were attained for existing and new buildings, respectively. High-tech buildings were particularly cost-effective, and saved higher amounts of energy due to their energy-intensiveness. Projects with a comprehensive approach to commissioning attained nearly twice the overall median level of savings and five-times the savings of the least-thorough projects. It is noteworthy that virtually all existing building projects were cost-effective by each metric (0.4 years for the upper quartile and 2.4 years for the lower quartile), as were the majority of new-construction projects (1.5 years and 10.8 years, respectively). We also found high cost-effectiveness for each specific measure for which we have data. Contrary to a common perception, cost-effectiveness is often achieved even in smaller buildings. Thanks to energy savings valued more than the cost of the commissioning process, associated reductions in greenhouse gas emissions come at 'negative' cost. In fact, the median cost of conserved carbon is negative - -$110 per tonne for existing buildings and -$25/tonne for new construction - as compared with market prices for carbon trading and offsets in the +$10 to +$30/tonne range. Further enhancing the value of commissioning, its non-energy benefits surpass those of most other energy-management practices. Significant first-cost savings (e.g., through right-sizing of heating and cooling equipment) routinely offset at least a portion of commissioning costs - fully in some cases. When accounting for these benefits, the net median commissioning project cost was reduced by 49% on average, while in many cases they exceeded the direct value of the

  18. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  19. Strategies for the Commercialization and Deployment of Greenhouse Gas Intensity-Reducing Technologies and Practices

    SciTech Connect (OSTI)

    Committee on Climate Change Science and Technology Integration

    2009-01-01

    New technologies will be a critical component--perhaps the critical component--of our efforts to tackle the related challenges of energy security, climate change, and air pollution, all the while maintaining a strong economy. But just developing new technologies is not enough. Our ability to accelerate the market penetration of clean energy, enabling, and other climate-related technologies will have a determining impact on our ability to slow, stop, and reverse the growth in greenhouse gas (GHG) emissions. Title XVI, Subtitle A, of the Energy Policy Act of 2005 (EPAct 2005) directs the Administration to report on its strategy to promote the commercialization and deployment (C&D) of GHG intensity-reducing technologies and practices. The Act also requests the Administration to prepare an inventory of climate-friendly technologies suitable for deployment and to identify the barriers and commercial risks facing advanced technologies. Because these issues are related, they are integrated here within a single report that we, representing the Committee on Climate Change Science and Technology Integration (CCCSTI), are pleased to provide the President, the Congress, and the public. Over the past eight years, the Administration of President George W. Bush has pursued a series of policies and measures aimed at encouraging the development and deployment of advanced technologies to reduce GHG emissions. This report highlights these policies and measures, discusses the barriers to each, and integrates them within a larger body of other extant policy. Taken together, more than 300 policies and measures described in this document may be viewed in conjunction with the U.S. Climate Change Technology Program's (CCTP's) Strategic Plan, published in September 2006, which focuses primarily on the role of advanced technology and associated research and development (R&D) for mitigating GHG emissions. The CCTP, a multi-agency technology planning and coordination program, initiated by

  20. Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill

    SciTech Connect (OSTI)

    Wang, Xiaojun; Jia, Mingsheng; Chen, Xiaohai; Xu, Ying; Lin, Xiangyu; Kao, Chih Ming; Chen, Shaohua

    2014-07-15

    Highlights: • Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup −1}. • Fresh leachate owned extremely low ORP and high organic matter content. • Strong CH{sub 4} emissions occurred in the fresh leachate ponds, but small in the aged. • N{sub 2}O emissions became dominant in the treatment units of both systems. • 8.45–11.9% of nitrogen was removed as the form of N{sub 2}O under steady-state. - Abstract: With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH{sub 4} emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m{sup −2} h{sup −1}) extremely higher than those of N{sub 2}O (0.028–0.41 mg N m{sup −2} h{sup −1}). In contrast, the emission values for both CH{sub 4} and N{sub 2}O were low for the aged leachate tank. N{sub 2}O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N{sub 2}O emission based on both leachate treatment systems was estimated to be 7.99 g N{sub 2}O–N capita{sup −1} yr{sup −1}. An increase of 80% in N{sub 2}O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO{sub 2}, with a small portion as CH{sub 4} (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO{sub 2} eq yr{sup −1}, respectively, for a total that could be transformed to 9.09 kg CO{sub 2} eq capita{sup −1} yr{sup −1}.

  1. Idaho National Laboratory’s FY09 & FY10 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2011-06-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2009 and 2010 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions. INL's GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL's organizational boundaries, but are a consequence of INL's activities). This inventory found that INL generated 103,590 and 102,413 MT of CO2-equivalent emissions during FY09 and FY10, respectively. The following conclusions were made from looking at the results of the individual contributors to INL's FY09 and FY10 GHG inventories: (1) Electricity (including the associated transmission and distribution losses) is the largest contributor to INL's GHG inventory, with over 50% of the CO2e emissions; (2) Other sources

  2. Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced Biomass Feedstock Logistics Supply Chains in Kansas

    SciTech Connect (OSTI)

    Cafferty, Kara G.; Searcy, Erin M.; Nguyen, Long; Spatari, Sabrina

    2014-11-01

    To meet Energy Independence and Security Act (EISA) cellulosic biofuel mandates, the United States will require an annual domestic supply of about 242 million Mg of biomass by 2022. To improve the feedstock logistics of lignocellulosic biofuels and access available biomass resources from areas with varying yields, commodity systems have been proposed and designed to deliver on-spec biomass feedstocks at preprocessing “depots”, which densify and stabilize the biomass prior to long-distance transport and delivery to centralized biorefineries. The harvesting, preprocessing, and logistics (HPL) of biomass commodity supply chains thus could introduce spatially variable environmental impacts into the biofuel life cycle due to needing to harvest, move, and preprocess biomass from multiple distances that have variable spatial density. This study examines the uncertainty in greenhouse gas (GHG) emissions of corn stover logisticsHPL within a bio-ethanol supply chain in the state of Kansas, where sustainable biomass supply varies spatially. Two scenarios were evaluated each having a different number of depots of varying capacity and location within Kansas relative to a central commodity-receiving biorefinery to test GHG emissions uncertainty. Monte Carlo simulation was used to estimate the spatial uncertainty in the HPL gate-to-gate sequence. The results show that the transport of densified biomass introduces the highest variability and contribution to the carbon footprint of the logistics HPL supply chain (0.2-13 g CO2e/MJ). Moreover, depending upon the biomass availability and its spatial density and surrounding transportation infrastructure (road and rail), logistics HPL processes can increase the variability in life cycle environmental impacts for lignocellulosic biofuels. Within Kansas, life cycle GHG emissions could range from 24 to 41 g CO2e/MJ depending upon the location, size and number of preprocessing depots constructed. However, this

  3. Greenhouse Emission Reductions and Natural Gas Vehicles: A Resource Guide on Technology Options and Project Development

    SciTech Connect (OSTI)

    Orestes Anastasia; NAncy Checklick; Vivianne Couts; Julie Doherty; Jette Findsen; Laura Gehlin; Josh Radoff

    2002-09-01

    Accurate and verifiable emission reductions are a function of the degree of transparency and stringency of the protocols employed in documenting project- or program-associated emissions reductions. The purpose of this guide is to provide a background for law and policy makers, urban planners, and project developers working with the many Greenhouse Gas (GHG) emission reduction programs throughout the world to quantify and/or evaluate the GHG impacts of Natural Gas Vehicle (NGVs). In order to evaluate the GHG benefits and/or penalties of NGV projects, it is necessary to first gain a fundamental understanding of the technology employed and the operating characteristics of these vehicles, especially with regard to the manner in which they compare to similar conventional gasoline or diesel vehicles. Therefore, the first two sections of this paper explain the basic technology and functionality of NGVs, but focus on evaluating the models that are currently on the market with their similar conventional counterparts, including characteristics such as cost, performance, efficiency, environmental attributes, and range. Since the increased use of NGVs, along with Alternative Fuel Vehicle (AFVs) in general, represents a public good with many social benefits at the local, national, and global levels, NGVs often receive significant attention in the form of legislative and programmatic support. Some states mandate the use of NGVs, while others provide financial incentives to promote their procurement and use. Furthermore, Federal legislation in the form of tax incentives or procurement requirements can have a significant impact on the NGV market. In order to implement effective legislation or programs, it is vital to have an understanding of the different programs and activities that already exist so that a new project focusing on GHG emission reduction can successfully interact with and build on the experience and lessons learned of those that preceded it. Finally, most programs

  4. Selective gas adsorption and unique phase transition properties...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains Previous Next List Yangyang Liu, Ying-Pin ...

  5. Selective gas adsorption and unique phase transition properties...

    Office of Scientific and Technical Information (OSTI)

    Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains Citation Details In-Document...

  6. Development of methodologies for calculating greenhouse gas emissions from electricity generation for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Marnay, Chris; Sathaye, Jayant; Murtishaw, Scott; Fisher, Diane; Phadke, Amol; Franco, Guido

    2002-04-01

    The California Climate Action Registry, which will begin operation in Fall 2002, is a voluntary registry for California businesses and organizations to record annual greenhouse gas emissions. Reporting of emissions in the Registry by a participant involves documentation of both ''direct'' emissions from sources that are under the entity's control and ''indirect'' emissions controlled by others. Electricity generated by an off-site power source is considered to be an indirect emission and must be included in the entity's report. Published electricity emissions factors for the State of California vary considerably due to differences in whether utility-owned out-of-state generation, non-utility generation, and electricity imports from other states are included. This paper describes the development of three methods for estimating electricity emissions factors for calculating the combined net carbon dioxide emissions from all generating facilities that provide electricity to Californians. We fi nd that use of a statewide average electricity emissions factor could drastically under- or over-estimate an entity's emissions due to the differences in generating resources among the utility service areas and seasonal variations. In addition, differentiating between marginal and average emissions is essential to accurately estimate the carbon dioxide savings from reducing electricity use. Results of this work will be taken into consideration by the Registry when finalizing its guidance for use of electricity emissions factors in calculating an entity's greenhouse gas emissions.

  7. Assessment of well-to-wheel energy use and greenhouse gas emissions of Fischer-Tropsch diesel.

    SciTech Connect (OSTI)

    Wang, M.

    2001-12-13

    The middle distillate fuel produced from natural gas (NG) via the Fischer-Tropsch (FT) process has been proposed as a motor fuel for compression-ignition (CI) engine vehicles. FT diesel could help reduce U.S. dependence on imported oil. The U.S. Department of Energy (DOE) is evaluating the designation of FT diesel as an alternative motor fuel under the 1992 Energy Policy Act (EPACT). As part of this evaluation, DOE has asked the Center for Transportation Research at Argonne National Laboratory to conduct an assessment of well-to-wheels (WTW) energy use and greenhouse gas (GHG) emissions of FT diesel compared with conventional motor fuels (i.e., petroleum diesel). For this assessment, we applied Argonne's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model to conduct WTW analysis of FT diesel and petroleum diesel. This report documents Argonne's assessment. The results are presented in Section 2. Appendix A describes the methodologies and assumptions used in the assessment.

  8. Hydrocarbon radical thermochemistry: Gas-phase ion chemistry techniques

    SciTech Connect (OSTI)

    Ervin, Kent M.

    2014-03-21

    Final Scientific/Technical Report for the project "Hydrocarbon Radical Thermochemistry: Gas-Phase Ion Chemistry Techniques." The objective of this project is to exploit gas-phase ion chemistry techniques for determination of thermochemical values for neutral hydrocarbon radicals of importance in combustion kinetics.

  9. Address to the international workshop on greenhouse gas mitigation, technologies and measures

    SciTech Connect (OSTI)

    Kant, A.

    1996-12-31

    The Netherlands has a long history in combatting natural forces for it`s mere survival and even creation. Around half of the country was not Yet existent around 2000 years ago: it was still below sea level that time. Building dikes and the discovery of eolic energy applied in windmills, allowing to pump water from one side of the dike to the other, are technologies that gradually shaped the country into its current form, a process that continues to materialize till the present day. Water has not always been an enemy of the country. In the Hundred Year War with Spain, during which the country was occupied territory for most of the time, the water was used to drive the Spanish armies from the country. As large parts are well below sea level breaking the dikes resulted in flooding the country which made the armoury of the Spanish army useless. In this way they had to give up the siege of several major Dutch cities that time. These events marked the gradual liberation of the Dutch territory. Consequently, in the discussion on adaption and prevention of the greenhouse effect the Netherlands has a clear stand. The greenhouse effect will occur anyway, even if countries deploy all possible counter measures at once. So their aim is to prevent the occurrence of the greenhouse effect to the highest extent possible, and to protect the most vulnerable areas meanwhile, especially the coastal zones. In order to reach these goals the Dutch government has established a Joint Implementation Experimental Programme in accordance with the provisions made by the Conference of Parties in Berlin (1995).

  10. Flint Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Flint Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Flint...

  11. Bigfork Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Bigfork Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Bigfork Greenhouses Greenhouse Low Temperature Geothermal Facility Facility...

  12. Crook's Greenhouse Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Crook's Greenhouse Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Crook's Greenhouse Greenhouse Low Temperature Geothermal Facility Facility...

  13. Castlevalley Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Castlevalley Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Castlevalley Greenhouses Greenhouse Low Temperature Geothermal Facility...

  14. Well-to-wheels Analysis of Energy Use and Greenhouse Gas Emissions of Hydrogen Produced with Nuclear Energy

    SciTech Connect (OSTI)

    Wu, Ye; Wang, Michael Q.; Vyas, Anant D.; Wade, David C.; Taiwo, Temitope A.

    2004-07-01

    A fuel-cycle model-called the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model-has been developed at Argonne National Laboratory to evaluate well-to-wheels (WTW) energy and emission impacts of motor vehicle technologies fueled with various transportation fuels. The GREET model contains various hydrogen (H{sub 2}) production pathways for fuel-cell vehicles (FCVs) applications. In this effort, the GREET model was expanded to include four nuclear H{sub 2} production pathways: (1) H{sub 2} production at refueling stations via electrolysis using Light Water Reactor (LWR)-generated electricity; (2) H{sub 2} production in central plants via thermo-chemical water cracking using steam from High Temperature Gas cooled Reactor (HTGR); (3) H{sub 2} production in central plants via high-temperature electrolysis using HTGR-generated electricity and steam; and (4) H{sub 2} production at refueling stations via electrolysis using HTGR-generated electricity The WTW analysis of these four options include these stages: uranium ore mining and milling; uranium ore transportation; uranium conversion; uranium enrichment; uranium fuel fabrication; uranium fuel transportation; electricity or H{sub 2} production in nuclear power plants; H{sub 2} transportation; H{sub 2} compression; and H{sub 2} FCVs operation. Due to large differences in electricity requirements for uranium fuel enrichment between gas diffusion and centrifuge technologies, two scenarios were designed for uranium enrichment: (1) 55% of fuel enriched through gaseous diffusion technology and 45% through centrifuge technology (the current technology split for U.S. civilian nuclear power plants); and (2) 100% fuel enrichment using the centrifuge technology (a future trend). Our well-to-pump (WTP) results show that significant reductions in fossil energy use and greenhouse gas (GHG) emissions are achieved by nuclear-based H{sub 2} compared to natural gas-based H{sub 2} production via steam

  15. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO 2 concentration data

    SciTech Connect (OSTI)

    Ogle, Stephen; Davis, Kenneth J.; Lauvaux, Thomas; Schuh, Andrew E.; Cooley, Dan; West, Tristram O.; Heath, L.; Miles, Natasha; Richardson, S. J.; Breidt, F. Jay; Smith, Jim; McCarty, Jessica L.; Gurney, Kevin R.; Tans, P. P.; Denning, Scott

    2015-03-10

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country’s contribution to GHG concentrations in the atmosphere. Verification could include a variety of evidence, but arguably the most convincing verification would be confirmation of a change in GHG concentrations in the atmosphere that is consistent with reported emissions to the UNFCCC. We report here on a case study evaluating this option based on a prototype atmospheric CO2 measurement network deployed in the Mid-Continent Region of the conterminous United States. We found that the atmospheric CO2 measurement data did verify the accuracy of the emissions inventory within the confidence limits of the emissions estimates, suggesting that this technology could be further developed and deployed more widely in the future for verifying reported emissions.

  16. White House Announces New Executive Order To Reduce Greenhouse...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    White House Announces New Executive Order To Reduce Greenhouse Gas Emissions in the Federal Government White House Announces New Executive Order To Reduce Greenhouse Gas Emissions ...

  17. Fact #589: September 21, 2009 Proposed Fuel Economy and Greenhouse...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    21, 2009 Proposed Fuel Economy and Greenhouse Gas Emissions Standards Fact 589: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas Emissions Standards On September ...

  18. CEQ Issues Revised Draft Guidance on Consideration of Greenhouse...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas ...

  19. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    greenhouse gas emissions and improve fuel economy. EPA is finalizing the first-ever national greenhouse gas (GHG) emissions standards under the Clean Air Act References...

  20. Greenhouse Gas Concerns and Power Sector Planning (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01

    Concerns about potential climate change driven by rising atmospheric concentrations of Greenhouse Gases (GHG) have grown over the past two decades, both domestically and abroad. In the United States, potential policies to limit or reduce GHG emissions are in various stages of development at the state, regional, and federal levels. In addition to ongoing uncertainty with respect to future growth in energy demand and the costs of fuel, labor, and new plant construction, U.S. electric power companies must consider the effects of potential policy changes to limit or reduce GHG emissions that would significantly alter their planning and operating decisions. The possibility of such changes may already be affecting planning decisions for new generating capacity.

  1. Development and application of the EPIC model for carbon cycle, greenhouse-gas mitigation, and biofuel studies

    SciTech Connect (OSTI)

    Izaurralde, Roberto C.; Mcgill, William B.; Williams, J.R.

    2012-06-01

    This chapter provides a comprehensive review of the EPIC model in relation to carbon cycle, greenhouse-gas mitigation, and biofuel applications. From its original capabilities and purpose (i.e., quantify the impacts or erosion on soil productivity), the EPIC model has evolved into a comprehensive terrestrial ecosystem model for simulating with more or less process-level detail many ecosystem processes such as weather, hydrology, plant growth and development, carbon cycle (including erosion), nutrient cycling, greenhouse-gas emissions, and the most complete set of manipulations that can be implemented on a parcel of land (e.g. tillage, harvest, fertilization, irrigation, drainage, liming, burning, pesticide application). The chapter also provides details and examples of the latest efforts in model development such as the coupled carbon-nitrogen model, a microbial denitrification model with feedback to the carbon decomposition model, updates on calculation of ecosystem carbon balances, and carbon emissions from fossil fuels. The chapter has included examples of applications of the EPIC model in soil carbon sequestration, net ecosystem carbon balance, and biofuel studies. Finally, the chapter provides the reader with an update on upcoming improvements in EPIC such as the additions of modules for simulating biochar amendments, sorption of soluble C in subsoil horizons, nitrification including the release of N2O, and the formation and consumption of methane in soils. Completion of these model development activities will render an EPIC model with one of the most complete representation of biogeochemical processes and capable of simulating the dynamic feedback of soils to climate and management in terms not only of transient processes (e.g., soil water content, heterotrophic respiration, N2O emissions) but also of fundamental soil properties (e.g. soil depth, soil organic matter, soil bulk density, water limits).

  2. Calculate Gas Phase Transport Properties of Pure Species and Mixtures

    Energy Science and Technology Software Center (OSTI)

    1997-10-20

    DRFM is a set of routines and data bases used to calculate gas phase transport properties of pure species and mixtures. The program(s) may stand alone or may be used as part of a larger simulation.

  3. Natural Gas Methane Emissions in the United States Greenhouse Gas Inventory: Sources, Uncertainties and Opportunities for Improvement

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-11-19

    Presentation summarizing key findings of a Joint Institute for Strategic Energy Analysis Report at an Environmental Protection Agency workshop: 'Stakeholder Workshop on EPA GHG Data on Petroleum and Natural Gas Systems' on November 19, 2015. For additional information see the JISEA report, 'Estimating U.S. Methane Emissions from the Natural Gas Supply Chain: Approaches, Uncertainties, Current Estimates, and Future Studies' NREL/TP-6A50-62820.

  4. CEQ Extends Comment Period on Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews

    Broader source: Energy.gov [DOE]

    The Council on Environmental Quality (CEQ) has extended by 30 days the comment period on its revised draft guidance on consideration of greenhouse gas (GHG) emissions and the effects of climate change in NEPA reviews. The comment period now ends on March 25, 2015.

  5. Bliss Greenhouse Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Bliss Greenhouse Greenhouse Low Temperature Geothermal Facility Facility Bliss Greenhouse...

  6. Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report

    SciTech Connect (OSTI)

    Fischer, M. L.; Sweeney, C.

    2016-01-01

    The vertical distributions of CO2, CH4, and other gases provide important constraints when determining terrestrial and ocean sources and sinks of carbon and other biogeochemical processes in the Earth system. The U.S. Department of Energy's (DOE) Office of Biological and Environmental Research and the National Oceanic and Atmospheric Administration's Earth System Research Laboratory to quantify the vertically resolved distribution of atmospheric carbon-cycle gases(CO2, CH4 ) within approximately 99% of the atmospheric column at the DOE ’s Atmospheric Radiation Measurement Southern Great Plains (SGP) site in Oklahoma . During the 2012 to 2014 campaign period, 12 successful Air C ore flights were conducted from the SGP site . In addition to providing critical data for evaluating remote sensing and earth system models, valuable lessons were learned that motivate improvements to the sampling and recovery systems and campaign logistics . With the launch of the Orbiting Carbon Observatory - 2 (OCO - 2) and Greenhouse gases Observing Satellite ( GOSAT ) satellites, we look forward to proposing additional sampling and analysis efforts at the SGP site and at other sites to characterize the vertical distribution of CO2, CH4 over time and space.

  7. Greenhouse Gas Emissions from U.S. Hydropower Reservoirs: FY2011 Annual Progress Report

    SciTech Connect (OSTI)

    Stewart, Arthur J; Mosher, Jennifer J; Mulholland, Patrick J; Fortner, Allison M; Phillips, Jana Randolph; Bevelhimer, Mark S

    2012-05-01

    The primary objective of this study is to quantify the net emissions of key greenhouse gases (GHG) - notably, CO{sub 2} and CH{sub 4} - from hydropower reservoirs in moist temperate areas within the U.S. The rationale for this objective is straightforward: if net emissions of GHG can be determined, it would be possible to directly compare hydropower to other power-producing methods on a carbon-emissions basis. Studies of GHG emissions from hydropower reservoirs elsewhere suggest that net emissions can be moderately high in tropical areas. In such areas, warm temperatures and relatively high supply rates of labile organic matter can encourage high rates of decomposition, which (depending upon local conditions) can result in elevated releases of CO{sub 2} and CH{sub 4}. CO{sub 2} and CH{sub 4} emissions also tend to be higher for younger reservoirs than for older reservoirs, because vegetation and labile soil organic matter that is inundated when a reservoir is created can continue to decompose for several years (Galy-Lacaux et al. 1997, Barros et al. 2011). Water bodies located in climatically cooler areas, such as in boreal forests, could be expected to have lower net emissions of CO{sub 2} and CH{sub 4} because their organic carbon supplies tend to be relatively recalcitrant to microbial action and because cooler water temperatures are less conducive to decomposition.

  8. A TECHNICAL, ECONOMIC AND ENVIRONMENTAL ASSESSMENT OF AMINE-BASED CO2 CAPTURE TECHNOLOGY FOR POWER PLANT GREENHOUSE GAS CONTROL

    SciTech Connect (OSTI)

    Edward S. Rubin; Anand B. Rao

    2002-10-01

    Capture and sequestration of CO{sub 2} from fossil fuel power plants is gaining widespread interest as a potential method of controlling greenhouse gas emissions. Performance and cost models of an amine (MEA)-based CO{sub 2} absorption system for post-combustion flue gas applications have been developed, and integrated with an existing power plant modeling framework that includes multi-pollutant control technologies for other regulated emissions. The integrated model has been applied to study the feasibility and cost of carbon capture and sequestration at both new and existing coal-burning power plants. The cost of carbon avoidance was shown to depend strongly on assumptions about the reference plant design, details of the CO{sub 2} capture system design, interactions with other pollution control systems, and method of CO{sub 2} storage. The CO{sub 2} avoidance cost for retrofit systems was found to be generally higher than for new plants, mainly because of the higher energy penalty resulting from less efficient heat integration, as well as site-specific difficulties typically encountered in retrofit applications. For all cases, a small reduction in CO{sub 2} capture cost was afforded by the SO{sub 2} emission trading credits generated by amine-based capture systems. Efforts are underway to model a broader suite of carbon capture and sequestration technologies for more comprehensive assessments in the context of multi-pollutant environmental management.

  9. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life

  10. Designing optimal greenhouse gas observing networks that consider performance and cost

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lucas, D. D.; Yver Kwok, C.; Cameron-Smith, P.; Graven, H.; Bergmann, D.; Guilderson, T. P.; Weiss, R.; Keeling, R.

    2014-12-23

    Emission rates of greenhouse gases (GHGs) entering into the atmosphere can be inferred using mathematical inverse approaches that combine observations from a network of stations with forward atmospheric transport models. Some locations for collecting observations are better than others for constraining GHG emissions through the inversion, but the best locations for the inversion may be inaccessible or limited by economic and other non-scientific factors. We present a method to design an optimal GHG observing network in the presence of multiple objectives that may be in conflict with each other. As a demonstration, we use our method to design a prototypemore » network of six stations to monitor summertime emissions in California of the potent GHG 1,1,1,2-tetrafluoroethane (CH2FCF3, HFC-134a). We use a multiobjective genetic algorithm to evolve network configurations that seek to jointly maximize the scientific accuracy of the inferred HFC-134a emissions and minimize the associated costs of making the measurements. The genetic algorithm effectively determines a set of "optimal" observing networks for HFC-134a that satisfy both objectives (i.e., the Pareto frontier). The Pareto frontier is convex, and clearly shows the tradeoffs between performance and cost, and the diminishing returns in trading one for the other. Without difficulty, our method can be extended to design optimal networks to monitor two or more GHGs with different emissions patterns, or to incorporate other objectives and constraints that are important in the practical design of atmospheric monitoring networks.« less

  11. Designing optimal greenhouse gas observing networks that consider performance and cost

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lucas, D. D.; Yver Kwok, C.; Cameron-Smith, P.; Graven, H.; Bergmann, D.; Guilderson, T. P.; Weiss, R.; Keeling, R.

    2015-06-16

    Emission rates of greenhouse gases (GHGs) entering into the atmosphere can be inferred using mathematical inverse approaches that combine observations from a network of stations with forward atmospheric transport models. Some locations for collecting observations are better than others for constraining GHG emissions through the inversion, but the best locations for the inversion may be inaccessible or limited by economic and other non-scientific factors. We present a method to design an optimal GHG observing network in the presence of multiple objectives that may be in conflict with each other. As a demonstration, we use our method to design a prototypemore » network of six stations to monitor summertime emissions in California of the potent GHG 1,1,1,2-tetrafluoroethane (CH2FCF3, HFC-134a). We use a multiobjective genetic algorithm to evolve network configurations that seek to jointly maximize the scientific accuracy of the inferred HFC-134a emissions and minimize the associated costs of making the measurements. The genetic algorithm effectively determines a set of "optimal" observing networks for HFC-134a that satisfy both objectives (i.e., the Pareto frontier). The Pareto frontier is convex, and clearly shows the tradeoffs between performance and cost, and the diminishing returns in trading one for the other. Without difficulty, our method can be extended to design optimal networks to monitor two or more GHGs with different emissions patterns, or to incorporate other objectives and constraints that are important in the practical design of atmospheric monitoring networks.« less

  12. Constant volume gas cell optical phase-shifter

    DOE Patents [OSTI]

    Phillion, Donald W.

    2002-01-01

    A constant volume gas cell optical phase-shifter, particularly applicable for phase-shifting interferometry, contains a sealed volume of atmospheric gas at a pressure somewhat different than atmospheric. An optical window is present at each end of the cell, and as the length of the cell is changed, the optical path length of a laser beam traversing the cell changes. The cell comprises movable coaxial tubes with seals and a volume equalizing opening. Because the cell is constant volume, the pressure, temperature, and density of the contained gas do not change as the cell changes length. This produces an exactly linear relationship between the change in the length of the gas cell and the change in optical phase of the laser beam traversing it. Because the refractive index difference between the gas inside and the atmosphere outside is very much the same, a large motion must be made to change the optical phase by the small fraction of a wavelength that is required by phase-shifting interferometry for its phase step. This motion can be made to great fractional accuracy.

  13. Transportation Energy Futures Series: Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-01

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  14. Transportation Energy Futures Series. Effects of the Built Environment on Transportation. Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-15

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  15. Benefits of Greenhouse Gas Mitigation on the Supply, Management, and Use of Water Resources in the United States

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Strzepek, K.; Neumann, Jim; Smith, Joel; Martinich, Jeremy; Boehlert, Brent; Hejazi, Mohamad I.; Henderson, Jim; Wobus, Cameron; Jones, Russ; Calvin, Katherine V.; et al

    2014-11-29

    Climate change impacts on water resources in the U.S. are likely to be far-reaching and substantial, because the water sector spans many parts of the economy, from supply and demand for agriculture, industry, energy production, transportation and municipal use to damages from natural hazards. This paper provides impact and damage estimates from five water resource-related models in the CIRA frame work, addressing drought risk, flooding damages, water supply and demand, and global water scarcity. The four models differ in the water system assessed, their spatial scale, and the units of assessment, but together they provide a quantitative and descriptive richnessmore » in characterizing water resource sector effects of climate change that no single model can capture. The results also address the sensitivity of these estimates to greenhouse gas emission scenarios, climate sensitivity alternatives, and global climate model selection. While calculating the net impact of climate change on the water sector as a whole may be impractical, because each of the models applied here uses a consistent set of climate scenarios, broad conclusions can be drawn regarding the patterns of change and the benefits of GHG mitigation policies for the water sector. Two key findings emerge: 1) climate mitigation policy substantially reduces the impact of climate change on the water sector across multiple dimensions; and 2) the more managed the water resources system, the more tempered the climate change impacts and the resulting reduction of impacts from climate mitigation policies.« less

  16. Benefits of Greenhouse Gas Mitigation on the Supply, Management, and Use of Water Resources in the United States

    SciTech Connect (OSTI)

    Strzepek, K.; Neumann, Jim; Smith, Joel; Martinich, Jeremy; Boehlert, Brent; Hejazi, Mohamad I.; Henderson, Jim; Wobus, Cameron; Jones, Russ; Calvin, Katherine V.; Johnson, D.; Monier, Erwan; Strzepek, J.; Yoon, Jin-Ho

    2014-11-29

    Climate change impacts on water resources in the U.S. are likely to be far-reaching and substantial, because the water sector spans many parts of the economy, from supply and demand for agriculture, industry, energy production, transportation and municipal use to damages from natural hazards. This paper provides impact and damage estimates from five water resource-related models in the CIRA frame work, addressing drought risk, flooding damages, water supply and demand, and global water scarcity. The four models differ in the water system assessed, their spatial scale, and the units of assessment, but together they provide a quantitative and descriptive richness in characterizing water resource sector effects of climate change that no single model can capture. The results also address the sensitivity of these estimates to greenhouse gas emission scenarios, climate sensitivity alternatives, and global climate model selection. While calculating the net impact of climate change on the water sector as a whole may be impractical, because each of the models applied here uses a consistent set of climate scenarios, broad conclusions can be drawn regarding the patterns of change and the benefits of GHG mitigation policies for the water sector. Two key findings emerge: 1) climate mitigation policy substantially reduces the impact of climate change on the water sector across multiple dimensions; and 2) the more managed the water resources system, the more tempered the climate change impacts and the resulting reduction of impacts from climate mitigation policies.

  17. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Burkhardt, J. J.; Heath, G.; Cohen, E.

    2012-04-01

    In reviewing life cycle assessment (LCA) literature of utility-scale concentrating solar power (CSP) systems, this analysis focuses on reducing variability and clarifying the central tendency of published estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emissions estimates passing screens for quality and relevance: 19 for parabolic trough (trough) technology and 17 for power tower (tower) technology. The interquartile range (IQR) of published estimates for troughs and towers were 83 and 20 grams of carbon dioxide equivalent per kilowatt-hour (g CO2-eq/kWh),1 respectively; median estimates were 26 and 38 g CO2-eq/kWh for trough and tower, respectively. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. The IQR and median were reduced by 87% and 17%, respectively, for troughs. For towers, the IQR and median decreased by 33% and 38%, respectively. Next, five trough LCAs reporting detailed life cycle inventories were identified. The variability and central tendency of their estimates are reduced by 91% and 81%, respectively, after light harmonization. By harmonizing these five estimates to consistent values for global warming intensities of materials and expanding system boundaries to consistently include electricity and auxiliary natural gas combustion, variability is reduced by an additional 32% while central tendency increases by 8%. These harmonized values provide useful starting points for policy makers in evaluating life cycle GHG emissions from CSP projects without the requirement to conduct a full LCA for each new project.

  18. Eco-efficiency for greenhouse gas emissions mitigation of municipal solid waste management: A case study of Tianjin, China

    SciTech Connect (OSTI)

    Zhao Wei; Huppes, Gjalt; Voet, Ester van der

    2011-06-15

    The issue of municipal solid waste (MSW) management has been highlighted in China due to the continually increasing MSW volumes being generated and the limited capacity of waste treatment facilities. This article presents a quantitative eco-efficiency (E/E) analysis on MSW management in terms of greenhouse gas (GHG) mitigation. A methodology for E/E analysis has been proposed, with an emphasis on the consistent integration of life cycle assessment (LCA) and life cycle costing (LCC). The environmental and economic impacts derived from LCA and LCC have been normalized and defined as a quantitative E/E indicator. The proposed method was applied in a case study of Tianjin, China. The study assessed the current MSW management system, as well as a set of alternative scenarios, to investigate trade-offs between economy and GHG emissions mitigation. Additionally, contribution analysis was conducted on both LCA and LCC to identify key issues driving environmental and economic impacts. The results show that the current Tianjin's MSW management system emits the highest GHG and costs the least, whereas the situation reverses in the integrated scenario. The key issues identified by the contribution analysis show no linear relationship between the global warming impact and the cost impact in MSW management system. The landfill gas utilization scenario is indicated as a potential optimum scenario by the proposed E/E analysis, given the characteristics of MSW, technology levels, and chosen methodologies. The E/E analysis provides an attractive direction towards sustainable waste management, though some questions with respect to uncertainty need to be discussed further.

  19. Freeze drying for gas chromatography stationary phase deposition

    DOE Patents [OSTI]

    Sylwester, Alan P.

    2007-01-02

    The present disclosure relates to methods for deposition of gas chromatography (GC) stationary phases into chromatography columns, for example gas chromatography columns. A chromatographic medium is dissolved or suspended in a solvent to form a composition. The composition may be inserted into a chromatographic column. Alternatively, portions of the chromatographic column may be exposed or filled with the composition. The composition is permitted to solidify, and at least a portion of the solvent is removed by vacuum sublimation.

  20. Gas phase chemical detection with an integrated chemical analysis system

    SciTech Connect (OSTI)

    CASALNUOVO,STEPHEN A.; FRYE-MASON,GREGORY CHARLES; KOTTENSTETTE,RICHARD; HELLER,EDWIN J.; MATZKE,CAROLYN M.; LEWIS,PATRICK R.; MANGINELL,RONALD P.; BACA,ALBERT G.; HIETALA,VINCENT M.

    2000-04-12

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample preconcentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described.

  1. International Energy Agency (IEA) Greenhouse Gas (GHG) Weyburn-Midale CO₂ Monitoring and Storage Project

    SciTech Connect (OSTI)

    Sacuta, Norm; Young, Aleana; Worth, Kyle

    2015-12-22

    The IEAGHG Weyburn-Midale CO₂ Monitoring and Storage Project (WMP) began in 2000 with the first four years of research that confirmed the suitability of the containment complex of the Weyburn oil field in southeastern Saskatchewan as a storage location for CO₂ injected as part of enhanced oil recovery (EOR) operations. The first half of this report covers research conducted from 2010 to 2012, under the funding of the United States Department of Energy (contract DEFE0002697), the Government of Canada, and various other governmental and industry sponsors. The work includes more in-depth analysis of various components of a measurement, monitoring and verification (MMV) program through investigation of data on site characterization and geological integrity, wellbore integrity, storage monitoring (geophysical and geochemical), and performance/risk assessment. These results then led to the development of a Best Practices Manual (BPM) providing oilfield and project operators with guidance on CO₂ storage and CO₂-EOR. In 2013, the USDOE and Government of Saskatchewan exercised an optional phase of the same project to further develop and deploy applied research tools, technologies, and methodologies to the data and research at Weyburn with the aim of assisting regulators and operators in transitioning CO₂-EOR operations into permanent storage. This work, detailed in the second half of this report, involves seven targeted research projects – evaluating the minimum dataset for confirming secure storage; additional overburden monitoring; passive seismic monitoring; history-matched modelling; developing proper wellbore design; casing corrosion evaluation; and assessment of post CO₂-injected core samples. The results from the final and optional phases of the Weyburn-Midale Project confirm the suitability of CO₂-EOR fields for the injection of CO₂, and further, highlight the necessary MMV and follow-up monitoring required for these operations to be considered

  2. Jackson Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Jackson Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Jackson...

  3. Warm Springs Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Warm Springs Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Warm Springs Greenhouses Greenhouse Low Temperature Geothermal Facility...

  4. Wards Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Wards Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Wards Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Wards...

  5. Liskey Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Liskey Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Liskey Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Liskey...

  6. The Greenhouse Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name The Greenhouse Greenhouse Low Temperature Geothermal Facility Facility The Greenhouse Sector...

  7. Where Greenhouse Gases Come From | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Where Greenhouse Gases Come From In the United States, greenhouse gas emissions come primarily from the burning of fossil fuels in energy use. Carbon Dioxide Carbon Dioxide is the main greenhouse gas. In 2013, 82% of human-caused greenhouse gas emissions were carbon dioxide emissions, resulting from the burning of fossil fuels, solid waste, trees, wood, and other chemical reactions. Methane and Other Gases Another greenhouse gas, methane, comes from landfills, coal mines, oil and natural gas

  8. Nitrogen availability and indirect measurements of greenhouse gas emissions from aerobic and anaerobic biowaste digestates applied to agricultural soils

    SciTech Connect (OSTI)

    Rigby, H.; Smith, S.R.

    2013-12-15

    , indicating greater microbial activity in amended soil and reflecting the lower stability of this OM source, compared to the other, anaerobic digestate types, which showed no consistent effects on MBN compared to the control. Thus, the overall net release of digestate N in different soil types was not regulated by N transfer into the soil microbial biomass, but was determined primarily by digestate properties and the capacity of the soil type to process and turnover digestate N. In contrast to the sandy soil types, where nitrate (NO{sub 3}{sup -}) concentrations increased during incubation, there was an absence of NO{sub 3}{sup -} accumulation in the silty clay soil amended with LTAD and DMADMSW. This provided indirect evidence for denitrification activity and the gaseous loss of N, and the associated increased risk of greenhouse gas emissions under certain conditions of labile C supply and/or digestate physical structure in fine-textured soil types. The significance and influence of the interaction between soil type and digestate stability and physical properties on denitrification processes in digestate-amended soils require urgent investigation to ensure management practices are appropriate to minimise greenhouse gas emissions from land applied biowastes.

  9. Kalman-filtered compressive sensing for high resolution estimation of anthropogenic greenhouse gas emissions from sparse measurements.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-09-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. The limited nature of the measured data leads to a severely-underdetermined estimation problem. If the estimation is performed at fine spatial resolutions, it can also be computationally expensive. In order to enable such estimations, advances are needed in the spatial representation of ffCO2 emissions, scalable inversion algorithms and the identification of observables to measure. To that end, we investigate parsimonious spatial parameterizations of ffCO2 emissions which can be used in atmospheric inversions. We devise and test three random field models, based on wavelets, Gaussian kernels and covariance structures derived from easily-observed proxies of human activity. In doing so, we constructed a novel inversion algorithm, based on compressive sensing and sparse reconstruction, to perform the estimation. We also address scalable ensemble Kalman filters as an inversion mechanism and quantify the impact of Gaussian assumptions inherent in them. We find that the assumption does not impact the estimates of mean ffCO2 source strengths appreciably, but a comparison with Markov chain Monte Carlo estimates show significant differences in the variance of the source strengths. Finally, we study if the very different spatial natures of biogenic and ffCO2 emissions can be used to estimate them, in a disaggregated fashion, solely from CO2 concentration measurements, without extra information from products of incomplete combustion e.g., CO. We find that this is possible during the winter months, though the errors can be as large as 50%.

  10. Evaluation of Efficiency Activities in the Industrial Sector Undertaken in Response to Greenhouse Gas Emission Reduction Targets

    SciTech Connect (OSTI)

    Price, Lynn; de la Rue du Can, Stephane; Lu, Hongyou; Horvath, Arpad

    2010-05-21

    The 2006 California Global Warming Solutions Act calls for reducing greenhouse gas (GHG) emissions to 1990 levels by 2020. Meeting this target will require action from all sectors of the California economy, including industry. The industrial sector consumes 25% of the energy used and emits 28% of the carbon dioxide (CO{sub 2}) produced in the state. Many countries around the world have national-level GHG reduction or energy-efficiency targets, and comprehensive programs focused on implementation of energy efficiency and GHG emissions mitigation measures in the industrial sector are essential for achieving their goals. A combination of targets and industry-focused supporting programs has led to significant investments in energy efficiency as well as reductions in GHG emissions within the industrial sectors in these countries. This project has identified program and policies that have effectively targeted the industrial sector in other countries to achieve real energy and CO{sub 2} savings. Programs in Ireland, France, The Netherlands, Denmark, and the UK were chosen for detailed review. Based on the international experience documented in this report, it is recommended that companies in California's industrial sector be engaged in a program to provide them with support to meet the requirements of AB32, The Global Warming Solution Act. As shown in this review, structured programs that engage industry, require members to evaluate their potential efficiency measures, plan how to meet efficiency or emissions reduction goals, and provide support in achieving the goals, can be quite effective at assisting companies to achieve energy efficiency levels beyond those that can be expected to be achieved autonomously.

  11. Battery-Powered Electric and Hybrid Electric Vehicle Projects to Reduce Greenhouse Gas Emissions: A Resource for Project Development

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2002-07-31

    The transportation sector accounts for a large and growing share of global greenhouse gas (GHG) emissions. Worldwide, motor vehicles emit well over 900 million metric tons of carbon dioxide (CO2) each year, accounting for more than 15 percent of global fossil fuel-derived CO2 emissions.1 In the industrialized world alone, 20-25 percent of GHG emissions come from the transportation sector. The share of transport-related emissions is growing rapidly due to the continued increase in transportation activity.2 In 1950, there were only 70 million cars, trucks, and buses on the world’s roads. By 1994, there were about nine times that number, or 630 million vehicles. Since the early 1970s, the global fleet has been growing at a rate of 16 million vehicles per year. This expansion has been accompanied by a similar growth in fuel consumption.3 If this kind of linear growth continues, by the year 2025 there will be well over one billion vehicles on the world’s roads.4 In a response to the significant growth in transportation-related GHG emissions, governments and policy makers worldwide are considering methods to reverse this trend. However, due to the particular make-up of the transportation sector, regulating and reducing emissions from this sector poses a significant challenge. Unlike stationary fuel combustion, transportation-related emissions come from dispersed sources. Only a few point-source emitters, such as oil/natural gas wells, refineries, or compressor stations, contribute to emissions from the transportation sector. The majority of transport-related emissions come from the millions of vehicles traveling the world’s roads. As a result, successful GHG mitigation policies must find ways to target all of these small, non-point source emitters, either through regulatory means or through various incentive programs. To increase their effectiveness, policies to control emissions from the transportation sector often utilize indirect means to reduce emissions, such

  12. EIA-Voluntary Reporting of Greenhouse Gases Program - Section...

    U.S. Energy Information Administration (EIA) Indexed Site

    Section 1605 Text Voluntary Reporting of Greenhouse Gases Program Section 1605 Text Energy ... national aggregate emissions of each greenhouse gas for each calendar year of the ...

  13. EIA-Voluntary Reporting of Greenhouse Gases Program - Emission...

    U.S. Energy Information Administration (EIA) Indexed Site

    Emission Factors Voluntary Reporting of Greenhouse Gases Program Emission Factors and Global Warming Potentials The greenhouse gas emission factors and global warming potentials ...

  14. Gas phase decontamination of gaseous diffusion process equipment

    SciTech Connect (OSTI)

    Bundy, R.D.; Munday, E.B.; Simmons, D.W.; Neiswander, D.W.

    1994-03-01

    D&D of the process facilities at the gaseous diffusion plants (GDPs) will be an enormous task. The EBASCO estimate places the cost of D&D of the GDP at the K-25 Site at approximately $7.5 billion. Of this sum, nearly $4 billion is associated with the construction and operation of decontamination facilities and the dismantlement and transport of contaminated process equipment to these facilities. In situ long-term low-temperature (LTLT) gas phase decontamination is being developed and demonstrated at the K-25 site as a technology that has the potential to substantially lower these costs while reducing criticality and safeguards concerns and worker exposure to hazardous and radioactive materials. The objective of gas phase decontamination is to employ a gaseous reagent to fluorinate nonvolatile uranium deposits to form volatile LJF6, which can be recovered by chemical trapping or freezing. The LTLT process permits the decontamination of the inside of gas-tight GDP process equipment at room temperature by substituting a long exposure to subatmospheric C1F for higher reaction rates at higher temperatures. This paper outlines the concept for applying LTLT gas phase decontamination, reports encouraging laboratory experiments, and presents the status of the design of a prototype mobile system. Plans for demonstrating the LTLT process on full-size gaseous diffusion equipment are also outlined briefly.

  15. Greenhouse Gas Source Attribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  16. Gas Phase Chemical Detection with an Integrated Chemical Analysis System

    SciTech Connect (OSTI)

    Baca, Albert G.; Casalnuovo, Stephen A.; Frye-Mason, Gregory C.; Heller, Edwin J.; Hietala, Susan L.; Hietala, Vincent M.; Kottenstette, Richard J.; Lewis, Patrick R.; Manginell, Ronald P.; Matzke, Carloyn M.; Reno, John L.; Sasaki, Darryl Y.; Schubert, W. Kent

    1999-07-08

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample concentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described. The design and performance of novel micromachined acoustic wave devices, with the potential for improved chemical sensitivity, are also described.

  17. Well-to-wheels energy use and greenhouse gas emissions analysis of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Burnham, A.; Wang, M.; Molburg, J.; Rousseau, A.; Energy Systems

    2009-03-31

    Researchers at Argonne National Laboratory expanded the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model and incorporated the fuel economy and electricity use of alternative fuel/vehicle systems simulated by the Powertrain System Analysis Toolkit (PSAT) to conduct a well-to-wheels (WTW) analysis of energy use and greenhouse gas (GHG) emissions of plug-in hybrid electric vehicles (PHEVs). The WTW results were separately calculated for the blended charge-depleting (CD) and charge-sustaining (CS) modes of PHEV operation and then combined by using a weighting factor that represented the CD vehicle-miles-traveled (VMT) share. As indicated by PSAT simulations of the CD operation, grid electricity accounted for a share of the vehicle's total energy use, ranging from 6% for a PHEV 10 to 24% for a PHEV 40, based on CD VMT shares of 23% and 63%, respectively. In addition to the PHEV's fuel economy and type of on-board fuel, the marginal electricity generation mix used to charge the vehicle impacted the WTW results, especially GHG emissions. Three North American Electric Reliability Corporation regions (4, 6, and 13) were selected for this analysis, because they encompassed large metropolitan areas (Illinois, New York, and California, respectively) and provided a significant variation of marginal generation mixes. The WTW results were also reported for the U.S. generation mix and renewable electricity to examine cases of average and clean mixes, respectively. For an all-electric range (AER) between 10 mi and 40 mi, PHEVs that employed petroleum fuels (gasoline and diesel), a blend of 85% ethanol and 15% gasoline (E85), and hydrogen were shown to offer a 40-60%, 70-90%, and more than 90% reduction in petroleum energy use and a 30-60%, 40-80%, and 10-100% reduction in GHG emissions, respectively, relative to an internal combustion engine vehicle that used gasoline. The spread of WTW GHG emissions among the different fuel production

  18. A method for direct, semi-quantitative analysis of gas phase...

    Office of Scientific and Technical Information (OSTI)

    ... Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY GC-ICP-MS; Gas phase analysis; Gas chromatography-inducti...

  19. Gas phase fractionation method using porous ceramic membrane

    DOE Patents [OSTI]

    Peterson, Reid A. (Madison, WI); Hill, Jr., Charles G. (Madison, WI); Anderson, Marc A. (Madison, WI)

    1996-01-01

    Flaw-free porous ceramic membranes fabricated from metal sols and coated onto a porous support are advantageously used in gas phase fractionation methods. Mean pore diameters of less than 40 .ANG., preferably 5-20 .ANG. and most preferably about 15 .ANG., are permeable at lower pressures than existing membranes. Condensation of gases in small pores and non-Knudsen membrane transport mechanisms are employed to facilitate and increase membrane permeability and permselectivity.

  20. Influence of corn oil recovery on life-cycle greenhouse gas emissions of corn ethanol and corn oil biodiesel

    SciTech Connect (OSTI)

    Wang, Zhichao; Dunn, Jennifer B.; Han, Jeongwoo; Wang, Michael

    2015-11-04

    Corn oil recovery and conversion to biodiesel has been widely adopted at corn ethanol plants recently. The US EPA has projected 2.6 billion liters of biodiesel will be produced from corn oil in 2022. Corn oil biodiesel may qualify for federal renewable identification number (RIN) credits under the Renewable Fuel Standard, as well as for low greenhouse gas (GHG) emission intensity credits under California’s Low Carbon Fuel Standard. Because multiple products [ethanol, biodiesel, and distiller’s grain with solubles (DGS)] are produced from one feedstock (corn), however, a careful co-product treatment approach is required to accurately estimate GHG intensities of both ethanol and corn oil biodiesel and to avoid double counting of benefits associated with corn oil biodiesel production. This study develops four co-product treatment methods: (1) displacement, (2) marginal, (3) hybrid allocation, and (4) process-level energy allocation. Life-cycle GHG emissions for corn oil biodiesel were more sensitive to the choice of co-product allocation method because significantly less corn oil biodiesel is produced than corn ethanol at a dry mill. Corn ethanol life-cycle GHG emissions with the displacement, marginal, and hybrid allocation approaches are similar (61, 62, and 59 g CO2e/MJ, respectively). Although corn ethanol and DGS share upstream farming and conversion burdens in both the hybrid and process-level energy allocation methods, DGS bears a higher burden in the latter because it has lower energy content per selling price as compared to corn ethanol. As a result, with the process-level allocation approach, ethanol’s life-cycle GHG emissions are lower at 46 g CO2e/MJ. Corn oil biodiesel life-cycle GHG emissions from the marginal, hybrid allocation, and process-level energy allocation methods were 14, 59, and 45 g CO2e/MJ, respectively. Sensitivity analyses were conducted to investigate the influence corn oil yield, soy biodiesel, and

  1. Influence of corn oil recovery on life-cycle greenhouse gas emissions of corn ethanol and corn oil biodiesel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Zhichao; Dunn, Jennifer B.; Han, Jeongwoo; Wang, Michael

    2015-11-04

    Corn oil recovery and conversion to biodiesel has been widely adopted at corn ethanol plants recently. The US EPA has projected 2.6 billion liters of biodiesel will be produced from corn oil in 2022. Corn oil biodiesel may qualify for federal renewable identification number (RIN) credits under the Renewable Fuel Standard, as well as for low greenhouse gas (GHG) emission intensity credits under California’s Low Carbon Fuel Standard. Because multiple products [ethanol, biodiesel, and distiller’s grain with solubles (DGS)] are produced from one feedstock (corn), however, a careful co-product treatment approach is required to accurately estimate GHG intensities of bothmore » ethanol and corn oil biodiesel and to avoid double counting of benefits associated with corn oil biodiesel production. This study develops four co-product treatment methods: (1) displacement, (2) marginal, (3) hybrid allocation, and (4) process-level energy allocation. Life-cycle GHG emissions for corn oil biodiesel were more sensitive to the choice of co-product allocation method because significantly less corn oil biodiesel is produced than corn ethanol at a dry mill. Corn ethanol life-cycle GHG emissions with the displacement, marginal, and hybrid allocation approaches are similar (61, 62, and 59 g CO2e/MJ, respectively). Although corn ethanol and DGS share upstream farming and conversion burdens in both the hybrid and process-level energy allocation methods, DGS bears a higher burden in the latter because it has lower energy content per selling price as compared to corn ethanol. As a result, with the process-level allocation approach, ethanol’s life-cycle GHG emissions are lower at 46 g CO2e/MJ. Corn oil biodiesel life-cycle GHG emissions from the marginal, hybrid allocation, and process-level energy allocation methods were 14, 59, and 45 g CO2e/MJ, respectively. Sensitivity analyses were conducted to investigate the influence corn oil yield, soy biodiesel, and defatted DGS displacement

  2. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry

    SciTech Connect (OSTI)

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-07-01

    The pulp and paper industry accounts for over 12% of total manufacturing energy use in the U.S. (U.S. EIA 1997a), contributing 9% to total manufacturing carbon dioxide emissions. In the last twenty-five years primary energy intensity in the pulp and paper industry has declined by an average of 1% per year. However, opportunities still exist to reduce energy use and greenhouse gas emissions in the manufacture of paper in the U.S. This report analyzes the pulp and paper industry (Standard Industrial Code (SIC) 26) and includes a detailed description of the processes involved in the production of paper, providing typical energy use in each process step. We identify over 45 commercially available state-of-the-art technologies and measures to reduce energy use and calculate potential energy savings and carbon dioxide emissions reductions. Given the importance of paper recycling, our analysis examines two cases. Case A identifies potential primary energy savings without accounting for an increase in recycling, while Case B includes increasing paper recycling. In Case B the production volume of pulp is reduced to account for additional pulp recovered from recycling. We use a discount rate of 30% throughout our analysis to reflect the investment decisions taken in a business context. Our Case A results indicate that a total technical potential primary energy savings of 31% (1013 PJ) exists. For case A we identified a cost-effective savings potential of 16% (533 PJ). Carbon dioxide emission reductions from the energy savings in Case A are 25% (7.6 MtC) and 14% (4.4 MtC) for technical and cost-effective potential, respectively. When recycling is included in Case B, overall technical potential energy savings increase to 37% (1215 PJ) while cost-effective energy savings potential is 16%. Increasing paper recycling to high levels (Case B) is nearly cost-effective assuming a cut-off for cost-effectiveness of a simple payback period of 3 years. If this measure is included, then

  3. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the US pulp and paper industry

    SciTech Connect (OSTI)

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-07-01

    The pulp and paper industry accounts for over 12% of total manufacturing energy use in the US (US EIA 1997a), contributing 9% to total manufacturing carbon dioxide emissions. In the last twenty-five years primary energy intensity in the pulp and paper industry has declined by an average of 1% per year. However, opportunities still exist to reduce energy use and greenhouse gas emissions in the manufacture of paper in the US This report analyzes the pulp and paper industry (Standard Industrial Code (SIC) 26) and includes a detailed description of the processes involved in the production of paper, providing typical energy use in each process step. We identify over 45 commercially available state-of-the-art technologies and measures to reduce energy use and calculate potential energy savings and carbon dioxide emissions reductions. Given the importance of paper recycling, our analysis examines two cases. Case A identifies potential primary energy savings without accounting for an increase in recycling, while Case B includes increasing paper recycling. In Case B the production volume of pulp is reduced to account for additional pulp recovered from recycling. We use a discount rate of 30% throughout our analysis to reflect the investment decisions taken in a business context. Our Case A results indicate that a total technical potential primary energy savings of 31% (1013 PJ) exists. For case A we identified a cost-effective savings potential of 16% (533 PJ). Carbon dioxide emission reductions from the energy savings in Case A are 25% (7.6 MtC) and 14% (4.4 MtC) for technical and cost-effective potential, respectively. When recycling is included in Case B, overall technical potential energy savings increase to 37% (1215 PJ) while cost-effective energy savings potential is 16%. Increasing paper recycling to high levels (Case B) is nearly cost-effective assuming a cut-off for cost-effectiveness of a simple payback period of 3 years. If this measure is included, then the

  4. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the

  5. Evaluation of metrics and baselines for tracking greenhouse gas emissions trends: Recommendations for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Murtishaw, Scott; Worrell, Ernst

    2003-06-01

    Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California

  6. Long-Term Changes in Gas- and Particle-Phase Emissions from On...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline ...

  7. ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT (Technical...

    Office of Scientific and Technical Information (OSTI)

    ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT Citation Details In-Document Search Title: ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT AREVA Federal ...

  8. Implications of High Renewable Electricity Penetration in the U.S. for Water Use, Greenhouse Gas Emissions, Land-Use, and Materials Supply

    Office of Energy Efficiency and Renewable Energy (EERE)

    Recent work found that renewable energy could supply 80% of electricity demand in the contiguous United States in 2050 at the hourly level. This paper explores some of the implications of achieving such high levels of renewable electricity for supply chains and the environment in scenarios with renewable supply up to such levels. Transitioning to high renewable electricity supply would lead to significant reductions in greenhouse gas emissions and water use, with only modest land-use implications. While renewable energy expansion implies moderate growth of the renewable electricity supply chains, no insurmountable long-term constraints to renewable electricity technology manufacturing capacity or materials supply are identified.

  9. Well-to-wheels analysis of energy use and greenhouse gas emissions of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Han, J.; Poch, L.; Wang, M.; Vyas, A.; Mahalik, M.; Rousseau, A.

    2010-06-14

    Plug-in hybrid electric vehicles (PHEVs) are being developed for mass production by the automotive industry. PHEVs have been touted for their potential to reduce the US transportation sector's dependence on petroleum and cut greenhouse gas (GHG) emissions by (1) using off-peak excess electric generation capacity and (2) increasing vehicles energy efficiency. A well-to-wheels (WTW) analysis - which examines energy use and emissions from primary energy source through vehicle operation - can help researchers better understand the impact of the upstream mix of electricity generation technologies for PHEV recharging, as well as the powertrain technology and fuel sources for PHEVs. For the WTW analysis, Argonne National Laboratory researchers used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model developed by Argonne to compare the WTW energy use and GHG emissions associated with various transportation technologies to those associated with PHEVs. Argonne researchers estimated the fuel economy and electricity use of PHEVs and alternative fuel/vehicle systems by using the Powertrain System Analysis Toolkit (PSAT) model. They examined two PHEV designs: the power-split configuration and the series configuration. The first is a parallel hybrid configuration in which the engine and the electric motor are connected to a single mechanical transmission that incorporates a power-split device that allows for parallel power paths - mechanical and electrical - from the engine to the wheels, allowing the engine and the electric motor to share the power during acceleration. In the second configuration, the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle; thus, the engine never directly powers the vehicle's transmission. The power-split configuration was adopted for PHEVs with a 10- and 20-mile electric range because they require frequent use of the engine for acceleration and to provide

  10. The Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    2009-01-18

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH,

  11. Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program

    SciTech Connect (OSTI)

    Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing; Stacy VanDeveer

    2005-07-01

    A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

  12. Application of Phase-field Method in Predicting Gas Bubble Microstructure Evolution in Nuclear Fuels

    SciTech Connect (OSTI)

    Hu, Shenyang Y.; Li, Yulan; Sun, Xin; Gao, Fei; Devanathan, Ramaswami; Henager, Charles H.; Khaleel, Mohammad A.

    2010-04-30

    Fission product accumulation and gas bubble microstructure evolution in nuclear fuels strongly affect thermo-mechanical properties such as thermal conductivity, gas release, volumetric swelling and cracking, and hence the fuel performance. In this paper, a general phase-field model is developed to predict gas bubble formation and evolution. Important materials processes and thermodynamic properties including the generation of gas atoms and vacancies, sinks for vacancies and gas atoms, the elastic interaction among defects, gas re-solution, and inhomogeneity of elasticity and diffusivity are accounted for in the model. The simulations demonstrate the potential application of the phase-field method in investigating 1) heterogeneous nucleation of gas bubbles at defects; 2) effect of elastic interaction, inhomogeneity of material properties, and gas re-solution on gas bubble microstructures; and 3) effective properties from the output of phase-field simulations such as distribution of defects, gas bubbles, and stress fields.

  13. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J.

    2011-04-01

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  14. Next Generation Natural Gas Vehicle Program Phase I: Clean Air...

    Office of Scientific and Technical Information (OSTI)

    AIR PARTNERS; EXHAUST GAS RECIRCULATION; EGR; NOX; NGNGV; ACCOLD; PACCOLD; NATURAL GAS; LNG; DUAL-FUEL; Transportation Word Cloud More Like This Full Text preview image File size ...

  15. Gas Phase Chemical Physics | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Phase Chemical Physics Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Gas Phase Chemical Physics Print Text Size: A A A FeedbackShare Page Gas Phase Chemical Physics (GPCP) research emphasizes studies of the dynamics and rates of chemical reactions at energies characteristic of

  16. Large Eddy Simulation of two phase flow combustion in gas turbines |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Simulation of two phase flow combustion in gas turbines PI Name: Thierry Poinsot PI Email: poinsot@cerfacs.fr Institution: CERFACS Allocation Program: INCITE Allocation Hours at ALCF: 10,000,000 Year: 2011 Research Domain: Chemistry Research in CombustiLETFLOC (Large Eddy Simulation of two phase flow combustion in gas turbines) aims at improving our knowledge of two phase flows and their combustion in gas turbines. This will allow a better assesment of

  17. Energy Efficiency and Renewable Energy Research, Development, and Deployment in Meeting Greenhouse Gas Mitigation Goals: The Case of the Lieberman-Warner Climate Security Act of 2007 (S.2191)

    SciTech Connect (OSTI)

    Showalter, S.; Wood, F.; Vimmerstedt, L.

    2010-06-01

    The U.S. federal government is considering actions to reduce greenhouse gas emissions. Renewable energy and energy efficiency technologies could help reduce greenhouse gas emissions, so the cost of these technologies could significantly influence the overall cost of meeting greenhouse gas limits. This paper examines the potential benefit of reduced technology cost by analyzing the case of the Lieberman-Warner Climate Security Act of 2007 (S.2191). This act had a goal of reducing national carbon emissions in 2050 to levels 72 percent below 2006 emission levels. In April 2008, the U.S. Department of Energy, Energy Information Administration (EIA) published an analysis of the effects of S.2191 on the U.S. energy sector. This report presents a similar analysis: both analyses examined the impacts of S.2191, and both used versions of the National Energy Modeling System. The analysis reported here used modified technology assumptions to reflect U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE) program goals. The results show that achieving EERE program goals could reduce the cost of meeting greenhouse gas limits, reduce the cost of renewable electricity generation and biofuels, and reduce energy intensity.

  18. Energy Efficiency and Renewable Energy Research, Development, and Deployment in Meeting Greenhouse Gas Mitigation Goals. The Case of the Lieberman-Warner Climate Security Act of 2007 (S. 2191)

    SciTech Connect (OSTI)

    Showalter, Sharon

    2010-06-01

    The U.S. federal government is considering actions to reduce greenhouse gas emissions. Renewable energy and energy efficiency technologies could help reduce greenhouse gas emissions, so the cost of these technologies could significantly influence the overall cost of meeting greenhouse gas limits. This paper examines the potential benefit of reduced technology cost by analyzing the case of the Lieberman-Warner Climate Security Act of 2007 (S.2191). This act had a goal of reducing national carbon emissions in 2050 to levels 72 percent below 2006 emission levels. In April 2008, the U.S. Department of Energy, Energy Information Administration (EIA) published an analysis of the effects of S.2191 on the U.S. energy sector. This report presents a similar analysis: both analyses examined the impacts of S.2191, and both used versions of the National Energy Modeling System. The analysis reported here used modified technology assumptions to reflect U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE) program goals. The results show that achieving EERE program goals could reduce the cost of meeting greenhouse gas limits, reduce the cost of renewable electricity generation and biofuels, and reduce energy intensity.

  19. An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors

    SciTech Connect (OSTI)

    Townsend, Aaron K.; Webber, Michael E.

    2012-07-15

    This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

  20. Spatial and Temporal Correlates of Greenhouse Gas Diffusion from a Hydropower Reservoir in the Southern United States

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mosher, Jennifer; Fortner, Allison M.; Phillips, Jana Randolph; Bevelhimer, Mark S.; Stewart, Arthur; Troia, Matthew J.

    2015-10-29

    Emissions of CO2 and CH4 from freshwater reservoirs constitute a globally significant source of atmospheric greenhouse gases (GHGs), but knowledge gaps remain with regard to spatiotemporal drivers of emissions. We document the spatial and seasonal variation in surface diffusion of CO2 and CH4 from Douglas Lake, a hydropower reservoir in Tennessee, USA. Monthly estimates across 13 reservoir sites from January to November 2010 indicated that surface diffusions ranged from 236 to 18,806 mg m-2 day-1 for CO2 and 0 to 0.95 mg m-2 day-1 for CH4. Next, we developed statistical models using spatial and physicochemical variables to predict surface diffusionsmore » of CO2 and CH4. Models explained 22.7 and 20.9% of the variation in CO2 and CH4 diffusions, respectively, and identified pH, temperature, dissolved oxygen, and Julian day as the most informative important predictors. These findings provide baseline estimates of GHG emissions from a reservoir in eastern temperate North America a region for which estimates of reservoir GHGs emissions are limited. Our statistical models effectively characterized non-linear and threshold relationships between physicochemical predictors and GHG emissions. Further refinement of such models will aid in predicting current GHG emissions in unsampled reservoirs and forecasting future GHG emissions.« less

  1. Burgett Geothermal Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Burgett Geothermal Greenhouses Sector Geothermal energy Type Greenhouse Location Cotton City, New Mexico Coordinates Show Map Loading map... "minzoom":false,"mappingservice"...

  2. Edward's Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    of Technology's Geo-Heat Center Retrieved from "http:en.openei.orgwindex.php?titleEdward%27sGreenhousesGreenhouseLowTemperatureGeothermalFacility&oldid305261" ...

  3. ARM - What are Greenhouse Gases?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What are Greenhouse Gases? Carbon Dioxide Methane Gas Oxides of Nitrogen Halocarbons Ozone Water Vapor Greenhouse gases are atmospheric gases that trap infrared radiation emitted from the earth, lower atmosphere, or clouds or aerosols and, as

  4. Assessment of potential life-cycle energy and greenhouse gas emission effects from using corn-based butanol as a transportation fuel.

    SciTech Connect (OSTI)

    Wu, M.; Wang, M.; Liu, J.; Huo, H.; Energy Systems

    2008-01-01

    Since advances in the ABE (acetone-butanol-ethanol) fermentation process in recent years have led to significant increases in its productivity and yields, the production of butanol and its use in motor vehicles have become an option worth evaluating. This study estimates the potential life-cycle energy and emission effects associated with using bio-butanol as a transportation fuel. It employs a well-to-wheels (WTW) analysis tool: the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The estimates of life-cycle energy use and greenhouse gas (GHG) emissions are based on an Aspen Plus(reg. sign) simulation for a corn-to-butanol production process, which describes grain processing, fermentation, and product separation. Bio-butanol-related WTW activities include corn farming, corn transportation, butanol production, butanol transportation, and vehicle operation. In this study, we also analyzed the bio-acetone that is coproduced with bio-butanol as an alternative to petroleum-based acetone. We then compared the results for bio-butanol with those of conventional gasoline. Our study shows that driving vehicles fueled with corn-based butanol produced by the current ABE fermentation process could result in substantial fossil energy savings (39%-56%) and avoid large percentage of the GHG emission burden, yielding a 32%-48% reduction relative to using conventional gasoline. On energy basis, a bushel of corn produces less liquid fuel from the ABE process than that from the corn ethanol dry mill process. The coproduction of a significant portion of acetone from the current ABE fermentation presents a challenge. A market analysis of acetone, as well as research and development on robust alternative technologies and processes that minimize acetone while increase the butanol yield, should be conducted.

  5. Carbon emissions and sequestration in forests: Case studies from seven developing countries. Volume 2, Greenhouse gas emissions from deforestration in the Brazilian Amazon

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J.; Fearnside, P.M.

    1992-08-01

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as ``committed carbon,`` or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil`s use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  6. Spatial and Temporal Correlates of Greenhouse Gas Diffusion from a Hydropower Reservoir in the Southern United States

    SciTech Connect (OSTI)

    Mosher, Jennifer; Fortner, Allison M.; Phillips, Jana Randolph; Bevelhimer, Mark S.; Stewart, Arthur; Troia, Matthew J.

    2015-10-29

    Emissions of CO2 and CH4 from freshwater reservoirs constitute a globally significant source of atmospheric greenhouse gases (GHGs), but knowledge gaps remain with regard to spatiotemporal drivers of emissions. We document the spatial and seasonal variation in surface diffusion of CO2 and CH4 from Douglas Lake, a hydropower reservoir in Tennessee, USA. Monthly estimates across 13 reservoir sites from January to November 2010 indicated that surface diffusions ranged from 236 to 18,806 mg m-2 day-1 for CO2 and 0 to 0.95 mg m-2 day-1 for CH4. Next, we developed statistical models using spatial and physicochemical variables to predict surface diffusions of CO2 and CH4. Models explained 22.7 and 20.9% of the variation in CO2 and CH4 diffusions, respectively, and identified pH, temperature, dissolved oxygen, and Julian day as the most informative important predictors. These findings provide baseline estimates of GHG emissions from a reservoir in eastern temperate North America a region for which estimates of reservoir GHGs emissions are limited. Our statistical models effectively characterized non-linear and threshold relationships between physicochemical predictors and GHG emissions. Further refinement of such models will aid in predicting current GHG emissions in unsampled reservoirs and forecasting future GHG emissions.

  7. CO2 Capture from Flue Gas by Phase Transitional Absorption

    SciTech Connect (OSTI)

    Liang Hu

    2009-06-30

    A novel absorption process called Phase Transitional Absorption was invented. What is the Phase Transitional Absorption? Phase Transitional Absorption is a two or multi phase absorption system, CO{sub 2} rich phase and CO{sub 2} lean phase. During Absorption, CO{sub 2} is accumulated in CO{sub 2} rich phase. After separating the two phases, CO{sub 2} rich phase is forward to regeneration. After regeneration, the regenerated CO{sub 2} rich phase combines CO{sub 2} lean phase to form absorbent again to complete the cycle. The advantage for Phase Transitional Absorption is obvious, significantly saving on regeneration energy. Because CO{sub 2} lean phase was separated before regeneration, only CO{sub 2} rich phase was forward to regeneration. The absorption system we developed has the features of high absorption rate, high loading and working capacity, low corrosion, low regeneration heat, no toxic to environment, etc. The process evaluation shows that our process is able to save 80% energy cost by comparing with MEA process.

  8. EIA-Voluntary Reporting of Greenhouse Gases Program - Why Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Reporting of Greenhouse Gases Program Why Report What Is the Purpose of Form EIA-1605? Form EIA-1605 provides the means for the voluntary reporting of greenhouse gas emissions, ...

  9. Capital investment requirements for greenhouse gas emissions mitigation in power generation on near term to century time scales and global to regional spatial scales

    SciTech Connect (OSTI)

    Chaturvedi, Vaibhav; Clarke, Leon E.; Edmonds, James A.; Calvin, Katherine V.; Kyle, G. Page

    2014-11-01

    Electrification plays a crucial role in cost-effective greenhouse gas emissions mitigation strategies. Such strategies in turn carry implications for financial capital markets. This paper explores the implication of climate mitigation policy for capital investment demands by the electric power sector on decade to century time scales. We go further to explore the implications of technology performance and the stringency of climate policy for capital investment demands by the power sector. Finally, we discuss the regional distribution of investment demands. We find that stabilizing GHG emissions will require additional investment in the electricity generation sector over and above investments that would be need in the absence of climate policy, in the range of 16 to 29 Trillion US$ (60-110%) depending on the stringency of climate policy during the period 2015 to 2095 under default technology assumptions. This increase reflects the higher capital intensity of power systems that control emissions. Limits on the penetration of nuclear and carbon capture and storage technology could increase costs substantially. Energy efficiency improvements can reduce the investment requirement by 8 to21 Trillion US$ (default technology assumptions), depending on climate policy scenario with higher savings being obtained under the most stringent climate policy. The heaviest investments in power generation were observed in the China, India, SE Asia and Africa regions with the latter three regions dominating in the second half of the 21st century.

  10. High Country Rose Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Rose Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name High Country Rose Greenhouses Greenhouse Low Temperature Geothermal Facility...

  11. Hunter Hot Spring Greenhouse Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Hunter Hot Spring Greenhouse Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Hunter Hot Spring Greenhouse Greenhouse Low Temperature Geothermal...

  12. Where do California's greenhouse gases come from?

    SciTech Connect (OSTI)

    Fischer, Marc

    2009-01-01

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  13. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  14. Two-stage coal liquefaction without gas-phase hydrogen

    DOE Patents [OSTI]

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  15. Acid-gas injection encounters diverse H{sub 2}S, water phase changes

    SciTech Connect (OSTI)

    Carroll, J.J.

    1998-03-09

    For acid-gas injection systems, pressure-composition diagrams indicate the significant phase changes that H{sub 2}S and water mixtures can undergo when going from an amine unit to downhole in an injection well. This conclusion of a two-part series describes the importance of considering H{sub 2}S and water phase changes in the design of acid gas injection compressors, pipelines, injection wells, and methanol injection.

  16. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO conversion into carbon-neutral fuels and chemicals November ...

  17. Using Cool Roofs to Reduce Energy Use, Greenhouse Gas Emissions, and Urban Heat-island Effects: Findings from an India Experiment

    SciTech Connect (OSTI)

    Akbari, Hashem; Xu, Tengfang; Taha, Haider; Wray, Craig; Sathaye, Jayant; Garg, Vishal; Tetali, Surekha; Babu, M. Hari; Reddy, K. Niranjan

    2011-05-25

    Cool roofs, cool pavements, and urban vegetation reduce energy use in buildings, lower local air pollutant concentrations, and decrease greenhouse gas emissions from urban areas. This report summarizes the results of a detailed monitoring project in India and related simulations of meteorology and air quality in three developing countries. The field results quantified direct energy savings from installation of cool roofs on individual commercial buildings. The measured annual energy savings potential from roof-whitening of previously black roofs ranged from 20-22 kWh/m2 of roof area, corresponding to an air-conditioning energy use reduction of 14-26% in commercial buildings. The study estimated that typical annual savings of 13-14 kWh/m2 of roof area could be achieved by applying white coating to uncoated concrete roofs on commercial buildings in the Metropolitan Hyderabad region, corresponding to cooling energy savings of 10-19%. With the assumption of an annual increase of 100,000 square meters of new roof construction for the next 10 years in the Metropolitan Hyderabad region, the annual cooling energy savings due to whitening concrete roof would be 13-14 GWh of electricity in year ten alone, with cumulative 10-year cooling energy savings of 73-79 GWh for the region. The estimated savings for the entire country would be at least 10 times the savings in Hyderabad, i.e., more than 730-790 GWh. We estimated that annual direct CO2 reduction associated with reduced energy use would be 11-12 kg CO2/m2 of flat concrete roof area whitened, and the cumulative 10-year CO2 reduction would be approximately 0.60-0.65 million tons in India. With the price of electricity estimated at seven Rupees per kWh, the annual electricity savings on air-conditioning would be approximately 93-101 Rupees per m2 of roof. This would translate into annual national savings of approximately one billion Rupees in year ten, and cumulative 10-year savings of over five billion Rupees for cooling

  18. Opportunities for market-based programs worldwide that reduce greenhouse gas emissions: Initial Observations from Missions to the Philippines, South Africa, and Mexico

    SciTech Connect (OSTI)

    Stanton-Hoyle, D.R.

    1998-07-01

    Globally, governments and industries are implementing innovative voluntary programs to reduce greenhouse gas emissions. Often these programs encourage groups to use cost effective technologies that capture market-based forces. These programs are successful because they capitalize on existing opportunities where both the environment and the participants can benefit (i.e., win-win opportunities). This paper documents efforts to investigate these kinds of win-win opportunities in three developing countries: the Philippines, South Africa, and Mexico. Initial observations are provided as fresh information from the field, drawing on six missions during the last nine months. Utility costs, interest rates, and overall economic health appear to critically affect opportunities in each country. By contrast, details of heating, ventilating and air-conditioning (HVAC) design and local climate were often important differences between countries. These affect opportunities, for example, to achieve significant savings from cooling systems or not. Looking at the success of ESCOs was somewhat surprising. One might expect to see the most successful ESCO activity where utility costs are high and upgrade opportunities are plentiful (such as in the Philippines). This was not the case, however, as research in the Philippines did not reveal even one active ESCO contract yet. Design practices for new construction were in need of the same thing that helps US design teams do a better job of energy-efficient design, better communications between design team members. Finally, industrial firms were doing a variety of EE upgrades in each country, but this level of activity was relatively small compared to what should be cost effective.

  19. Gas phase dispersion in a small rotary kiln

    SciTech Connect (OSTI)

    Spencer, B.B.

    1981-07-01

    A study was made of nonideal flow of gas in a rotary kiln reactor. A rotating tube 0.165 m in diameter by 2.17 m long, with internal lifting flights, was operated at room temperature. Rotational speeds from 2.0 to 7.0 rpm, air flow rates from 0.351 to 4.178 m/sup 3//h, and solid contents of 0.0, 5.1, and 15.3% of tube volume were studied. Residence time distribution of the gas was measured by means of the pulse injection technique using a helium tracer. A model was developed based on dispersive flow that exchanges with a deadwater region. Two parameters, a dispersion number describing bulk gas flow and an interchange factor describing exchange between the flow region and the gas trapped in the solids bed, were sufficient to correlate the data, but these parameters are sensitive to experimental error. The model is applicable to analysis of other flow systems, such as packed beds.

  20. "GREENHOUSE GAS NAME","GREENHOUSE GAS CODE","FORMULA","GWP"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... the Fourth Assessment Report of the Intergovernmental Panel on Climate Change Solomon, S., D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M. Tignor and H.L. Miller (eds.). ...

  1. Knowledge Partnership for Measuring Air Pollution and Greenhouse...

    Open Energy Info (EERE)

    Knowledge Partnership for Measuring Air Pollution and Greenhouse Gas Emissions in Asia Jump to: navigation, search Name Knowledge Partnership for Measuring Air Pollution and...

  2. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    A2. Glossary Acid stabilization: A circumstance where the pH of the waste mixture in an animal manure management system is maintained near 7.0, optimal conditions for methane production. Aerobic bacteria: Microorganisms living, active, or occurring only in the presence of oxygen. Aerobic decomposition: The breakdown of a molecule into simpler molecules or atoms by microorganisms under favorable conditions of oxygenation. Aerosols: Airborne particles. Afforestation: Planting of new forests on

  3. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    860 Form The New Form EIA-860 combines: Form EIA-860 - Annual Electric Generator Report Form EIA-767 - Steam-Electric Plant Operation and Design Report (shown on right) What Do I Need to Do? See if you are required to file the EIA-860. Yes? File the EIA-860 electronically (Available soon!) Not registered for electronic filing? Just send us an email to get registered. EIA-860 Resources Printable form and instructions Answers to Anticipated Questions Summary of new and deleted data elements Having

  4. Optima: Low Greenhouse Gas Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fermentation using genetically tractable systems * Metabolic engineeringsynthetic biology as carve outs that can also leverage activities in DOE-Sc and ARPA-e * Initial focus ...

  5. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    ... that inject and store CO2 underground for the purposes ... production, underground coal mines, industrial ... The project focuses on reducing energy consumption in the ...

  6. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. ... Without the assistance of Science Applications International Corporation (SAIC), this ...

  7. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    grasslands 34 Net carbon dioxide sequestration in U.S. urban trees, yard trimmings, and food scraps 35 Emissions of carbon dioxide from biofuelbioenergy use by sector and fuel

  8. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-09-29

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase is dispersed.

  9. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-03-17

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase id dispersed.

  10. Incorporating Agricultural Management Practices into the Assessment of Soil Carbon Change and Life-Cycle Greenhouse Gas Emissions of Corn Stover Ethanol Production

    SciTech Connect (OSTI)

    Qin, Zhangcai; Canter, Christina E.; Dunn, Jennifer B.; Mueller, Steffen; Kwon, Ho-young; Han, Jeongwoo; Wander, Michelle M.; Wang, Michael

    2015-09-01

    Land management practices such as cover crop adoption or manure application that can increase soil organic carbon (SOC) may provide a way to counter SOC loss upon removal of stover from corn fields for use as a biofuel feedstock. This report documents the data, methodology, and assumptions behind the incorporation of land management practices into corn-soybean systems that dominate U.S. grain production using varying levels of stover removal in the GREETTM (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) model and its CCLUB (Carbon Calculator for Land Use change from Biofuels production) module. Tillage (i.e., conventional, reduced and no tillage), corn stover removal (i.e., at 0, 30% and 60% removal rate), and organic matter input techniques (i.e., cover crop and manure application) are included in the analysis as major land management practices. Soil carbon changes associated with land management changes were modeled with a surrogate CENTURY model. The resulting SOC changes were incorporated into CCLUB while GREET was expanded to include energy and material consumption associated with cover crop adoption and manure application. Life-cycle greenhouse gas (GHG) emissions of stover ethanol were estimated using a marginal approach (all burdens and benefits assigned to corn stover ethanol) and an energy allocation approach (burdens and benefits divided between grain and stover ethanol). In the latter case, we considered corn grain and corn stover ethanol to be produced at an integrated facility. Life-cycle GHG emissions of corn stover ethanol are dependent upon the analysis approach selected (marginal versus allocation) and the land management techniques applied. The expansion of CCLUB and GREET to accommodate land management techniques can produce a wide range of results because users can select from multiple scenario options such as choosing tillage levels, stover removal rates, and whether crop yields increase annually or remain constant

  11. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However

  12. How should greenhouse gas emissions be taken into account in the decision making of municipal solid waste management procurements? A case study of the South Karelia region, Finland

    SciTech Connect (OSTI)

    Hupponen, M. Grönman, K.; Horttanainen, M.

    2015-08-15

    Highlights: • Environmental criteria for the MSW incineration location procurements are needed. • Focus should be placed on annual energy efficiency and on substitute fuels. • In SRF combustion it is crucial to know the share and the treatment of rejects. • The GWP of transportation is a small part of the total emissions. - Abstract: The ongoing trend in the public sector is to make more sustainable procurements by taking into account the impacts throughout the entire life cycle of the procurement. Despite the trend, the only deciding factor can still be the total costs. This article answers the question of how greenhouse gas (GHG) emissions should be taken into account in municipal solid waste (MSW) management when selecting an incineration plant for source separated mixed MSW. The aim is to guide the decision making of MSW management towards more environmentally friendly procurements. The study was carried out by calculating the global warming potentials (GWPs) and costs of mixed MSW management by using the waste composition from a case area in Finland. Scenarios of landfilling and combustion in three actual waste incineration plants were used to recognise the main processes that affect the results. GWP results show that the combustion of mixed MSW is a better alternative than landfilling the waste. The GHG results from combustion are greatly affected by emissions from the combustion and substituted energy production. The significance of collection and transportation is higher from the costs’ perspective than from the point of view of GHG emissions. The main costs, in addition to collection and transportation costs, result from the energy utilization or landfilling of mixed MSW. When tenders are invited for the incineration location of mixed MSW, the main focus should be: What are the annual electricity and heat recovery efficiencies and which are the substituted fuels in the area? In addition, in the case of a fluidized bed combustor it is crucial to

  13. Device for two-dimensional gas-phase separation and characterization of ion mixtures

    DOE Patents [OSTI]

    Tang, Keqi; Shvartsburg, Alexandre A.; Smith, Richard D.

    2006-12-12

    The present invention relates to a device for separation and characterization of gas-phase ions. The device incorporates an ion source, a field asymmetric waveform ion mobility spectrometry (FAIMS) analyzer, an ion mobility spectrometry (IMS) drift tube, and an ion detector. In one aspect of the invention, FAIMS operating voltages are electrically floated on top of the IMS drift voltage. In the other aspect, the FAIMS/IMS interface is implemented employing an electrodynamic ion funnel, including in particular an hourglass ion funnel. The present invention improves the efficiency (peak capacity) and sensitivity of gas-phase separations; the online FAIMS/IMS coupling creates a fundamentally novel two-dimensional gas-phase separation technology with high peak capacity, specificity, and exceptional throughput.

  14. Metal-Organic Framework Thin Films as Stationary Phases in Microfabricated Gas-Chromatography Columns.

    SciTech Connect (OSTI)

    Read, Douglas; Sillerud, Colin Halliday

    2016-01-01

    The overarching goal of this project is to integrate Sandia's microfabricated gas-chromatography ( GC) columns with a stationary phase material that is capable of retaining high-volatility chemicals and permanent gases. The successful integration of such a material with GCs would dramatically expand the repertoire of detectable compounds for Sandia's various microanalysis systems. One such promising class of candidate materials is metal-organic frameworks (MOFs). In this report we detail our methods for controlled deposition of HKUST-1 MOF stationary phases within GC columns. We demonstrate: the chromatographic separation of natural gas; a method for determining MOF film thickness from chromatography alone; and the first-reported GC x GC separation of natural gas -- in general -- let alone for two disparate MOF stationary phases. In addition we determine the fundamental thermodynamic constant for mass sorption, the partition coefficient, for HKUST-1 and several light hydrocarbons and select toxic industrial chemicals.

  15. Life Cycle Assessment of Hydrogen Production via Natural Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to examine the net emissions of greenhouse gases as well as other major ... Completion Report Fuel Use and Greenhouse Gas Emissions from the Natural Gas ...

  16. Measurements and calculations of oscillations and phase relations in the driven gas-phase combustion of acetaldehyde

    SciTech Connect (OSTI)

    Tsujimoto, K.K.; Hjelmfelt, A.; Ross, J. (Department of Chemistry, Stanford University, Stanford, California (USA))

    1991-09-01

    Oscillations in light emission and species concentrations, are measured as periodic perturbations are simultaneously applied to the input rates of acetaldehyde and oxygen in the gas-phase combustion of acetaldehyde in a continuous-flow stirred tank reactor for conditions where the autonomous reaction itself is oscillatory. The experimental results are compared with the predictions of a five-variable thermokinetic model. We measure periodic responses in the fundamental entrainment band (ratio of frequency of perturbation to frequency of response equal to unity) for four different values of phase shift between the acetaldehyde and oxygen perturbation wave forms as we vary the frequency and amplitude of the external periodic perturbations. Outside of the entrainment bands we find quasiperiodic response. We determine the phases of the light emission and six species concentrations, as measured with a mass spectrometer, with respect to the periodic perturbation, the variation of these phases across the fundamental entrainment band for different values of reactant phase shift and for different amplitudes of perturbation, and the effects of the phase shift between the two input perturbations on the light emission response of the system for different frequencies of perturbation. Both the experiments and calculations predict a widening of the entrainment band with an increase in perturbation amplitude, and the same variation in bandwidths for the four values of reactant phase shift studied. The experiments and calculations also predict the same general trends in light phase and species phases (difference between the light emission and species concentrations with respect to the perturbing wave form) as the band is traversed for different amplitudes of perturbation and for different values of reactant phase shift.

  17. Plasma-produced phase-pure cuprous oxide nanowires for methane gas sensing

    SciTech Connect (OSTI)

    Cheng, Qijin Zhang, Fengyan; Yan, Wei; Randeniya, Lakshman; Ostrikov, Kostya

    2014-03-28

    Phase-selective synthesis of copper oxide nanowires is warranted by several applications, yet it remains challenging because of the narrow windows of the suitable temperature and precursor gas composition in thermal processes. Here, we report on the room-temperature synthesis of small-diameter, large-area, uniform, and phase-pure Cu{sub 2}O nanowires by exposing copper films to a custom-designed low-pressure, thermally non-equilibrium, high-density (typically, the electron number density is in the range of 10{sup 11}10{sup 13}?cm{sup ?3}) inductively coupled plasmas. The mechanism of the plasma-enabled phase selectivity is proposed. The gas sensors based on the synthesized Cu{sub 2}O nanowires feature fast response and recovery for the low-temperature (?140?C) detection of methane gas in comparison with polycrystalline Cu{sub 2}O thin film-based gas sensors. Specifically, at a methane concentration of 4%, the response and the recovery times of the Cu{sub 2}O nanowire-based gas sensors are 125 and 147?s, respectively. The Cu{sub 2}O nanowire-based gas sensors have a potential for applications in the environmental monitoring, chemical industry, mining industry, and several other emerging areas.

  18. Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Gasoline Vehicles | Department of Energy Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  19. Gas phase ion-molecule reactions, spectroscopy and dynamics

    SciTech Connect (OSTI)

    Rinden, E.

    1989-01-01

    The chemical reactivity of nitric oxide anion (NO{sup {minus}}) with a variety of organic neurals at ambient and in argon bath gas has been probed using the flowing afterglow technique. The reactions fall into four main classes: electron transfer, dissociative electron transfer and/or displacement, collisional detachment and clustering. Electron transfer can occur when the neutral reactant possesses a positive electron affinity greater than the electron affinity of NO{center dot}, but does not always do so. Bimolecular substitution at sulfur is shown to occur with dimethyl disulfide, but for other substrates, distinguishing between displacement and dissociative electron transfer is not possible. Collisional detachment is the exclusive reaction channel observed for a few of the molecules examined, and occurs to some extent with many of the neutrals tested. Cluster ion formation between NO{sup {minus}} and a number of the reactant neutrals which possess permanent dipole moments is observed. The collected observations are discussed in the general theory of ion-molecule reactions. Cross sections for vibrational relaxation in small ionic systems (Li{sup +}-H{sub 2},Li{sup +}-D{sub 2}, ArH{sup +}-Ar and ArD{sup +}-Ar) have been calculated numerically using the j{sub z}-conserving coupled states approximation (CSA), and contrasted with cross sections calculated by methods which exclude the effects of attractive forces and/or rotation. Both attractive forces and rotations are found to be extremely important contributors to relaxation in ions; in the Li{sup +}-H{sub 2}/D{sub 2} systems these effects are separable whereas in ArH{sup +}/D{sup +}-Ar they are not. Attractive forces substantially enhance the cross sections at all collision energies and are responsible for the general collisional energy dependence of the cross sections. Molecular rotation is found to enhance cross sections most strongly at low collision energies in each system.

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  1. Experimental on two sensors combination used in horizontal pipe gas-water two-phase flow

    SciTech Connect (OSTI)

    Wu, Hao; Dong, Feng

    2014-04-11

    Gas-water two phase flow phenomenon widely exists in production and living and the measurement of it is meaningful. A new type of long-waist cone flow sensor has been designed to measure two-phase mass flow rate. Six rings structure of conductance probe is used to measure volume fraction and axial velocity. The calibration of them have been made. Two sensors have been combined in horizontal pipeline experiment to measure two-phase flow mass flow rate. Several model of gas-water two-phase flow has been discussed. The calculation errors of total mass flow rate measurement is less than 5% based on the revised homogeneous flow model.

  2. DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS

    SciTech Connect (OSTI)

    X. Wang; X. Sun; H. Zhao

    2011-09-01

    In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in

  3. Investigation of gas-phase decontamination of internally radioactively contaminated gaseous diffusion process equipment and piping

    SciTech Connect (OSTI)

    Bundy, R.D.; Munday, E.B.

    1991-01-01

    Construction of the gaseous diffusion plants (GDPs) was begun during World War 2 to produce enriched uranium for defense purposes. These plants, which utilized UF{sub 6} gas, were used primarily for this purpose through 1964. From 1959 through 1968, production shifted primarily to uranium enrichment to supply the nuclear power industry. Additional UF{sub 6}-handling facilities were built in feed and fuel-processing plants associated with the uranium enrichment process. Two of the five process buildings at Oak ridge were shut down in 1964. Uranium enrichment activities at Oak Ridge were discontinued altogether in 1985. In 1987, the Department of Energy (DOE) decided to proceed with a permanent shutdown of the Oak Ridge Gaseous Diffusion Plant (ORGDP). DOE intends to begin decommissioning and decontamination (D D) of ORGDP early in the next century. The remaining two GDPs are expected to be shut down during the next 10 to 40 years and will also require D D, as will the other UF{sub 6}-handling facilities. This paper presents an investigation of gas- phase decontamination of internally radioactively contaminated gaseous diffusion process equipment and piping using powerful fluorinating reagents that convert nonvolatile uranium compounds to volatile UF{sub 6}. These reagents include ClF{sub 3}, F{sub 2}, and other compounds. The scope of D D at the GDPs, previous work of gas-phase decontamination, four concepts for using gas-phase decontamination, plans for further study of gas-phase decontamination, and the current status of this work are discussed. 13 refs., 15 figs.

  4. Measurement and speciation of gas and particulate phase organic acids in an urban environment

    SciTech Connect (OSTI)

    Lawrence, J.; Koutrakis, P.

    1994-12-31

    Organic acids are important contributors to ambient acidity, in both gas and particulate phase. Particulate phase organic acids represent an important fraction of organic particulate matter. This paper presents the results of a field study conducted in Philadelphia, PA, during the summer of 1992, to measure the concentrations of gas and particulate phase organic acids. Formic acid was found to be the most abundant gas phase organic acid, with acetic and propionic acids detected at lower concentrations. Organic acids constituted approximately 5% of the particulate fine mass, whereas sulfate and ammonium constituted 40% and 15%, respectively. Dicarboxylic acids and even-carbon monocarboxylic acids were found to account for a large fraction of particulate weak acidity; odd-carbon monocarboxylic acids accounted for a very small fraction. The pronounced even carbon preference of the monocarboxylic acid distribution suggests a biogenic origin; the dicarboxylic acid distribution may suggest that primary emission is more important than photochemical production. This paper discusses the measurement and analytical techniques used in this study and the chemistry and origins of organic acids.

  5. MOLECULAR SPECTROSCPY AND REACTIONS OF ACTINIDES IN THE GAS PHASE AND CRYOGENIC MATRICES

    SciTech Connect (OSTI)

    Heaven, Michael C.; Gibson, John K.; Marcalo, Joaquim

    2009-02-01

    In this chapter we review the spectroscopic data for actinide molecules and the reaction dynamics for atomic and molecular actinides that have been examined in the gas phase or in inert cryogenic matrices. The motivation for this type of investigation is that physical properties and reactions can be studied in the absence of external perturbations (gas phase) or under minimally perturbing conditions (cryogenic matrices). This information can be compared directly with the results from high-level theoretical models. The interplay between experiment and theory is critically important for advancing our understanding of actinide chemistry. For example, elucidation of the role of the 5f electrons in bonding and reactivity can only be achieved through the application of experimentally verified theoretical models. Theoretical calculations for the actinides are challenging due the large numbers of electrons that must be treated explicitly and the presence of strong relativistic effects. This topic has been reviewed in depth in Chapter 17 of this series. One of the goals of the experimental work described in this chapter has been to provide benchmark data that can be used to evaluate both empirical and ab initio theoretical models. While gas-phase data are the most suitable for comparison with theoretical calculations, there are technical difficulties entailed in generating workable densities of gas-phase actinide molecules that have limited the range of species that have been characterized. Many of the compounds of interest are refractory, and problems associated with the use of high temperature vapors have complicated measurements of spectra, ionization energies, and reactions. One approach that has proved to be especially valuable in overcoming this difficulty has been the use of pulsed laser ablation to generate plumes of vapor from refractory actinide-containing materials. The vapor is entrained in an inert gas, which can be used to cool the actinide species to room

  6. Luther-Emery Phase and Atomic-Density Waves in a Trapped Fermion Gas

    SciTech Connect (OSTI)

    Gao Xianlong; Rizzi, M.; Polini, Marco; Tosi, M. P.; Fazio, Rosario; Campo, V. L. Jr.; Capelle, K.

    2007-01-19

    The Luther-Emery liquid is a state of matter that is predicted to occur in one-dimensional systems of interacting fermions and is characterized by a gapless charge spectrum and a gapped spin spectrum. In this Letter we discuss a realization of the Luther-Emery phase in a trapped cold-atom gas. We study by means of the density-matrix renormalization-group technique a two-component atomic Fermi gas with attractive interactions subject to parabolic trapping inside an optical lattice. We demonstrate how this system exhibits compound phases characterized by the coexistence of spin pairing and atomic-density waves. A smooth crossover occurs with increasing magnitude of the atom-atom attraction to a state in which tightly bound spin-singlet dimers occupy the center of the trap. The existence of atomic-density waves could be detected in the elastic contribution to the light-scattering diffraction pattern.

  7. ASSESSMENT OF SUBSURFACE FATE OF MONOETHANOLAMINE AT SOUR GAS PROCESSING PLANT SITES-PHASE III

    SciTech Connect (OSTI)

    James A. Sorensen

    1999-02-01

    Alkanolamines are commonly used by the natural gas industry to remove hydrogen sulfide, carbon dioxide, and other acid gases from the natural gas in which they occur (''sour'' gas if hydrogen sulfide is present). At sour gas-processing plants, as at all plants that use alkanolamines for acid gas removal (AGR), spills and on-site management of wastes containing alkanolamines and associated reaction products have occasionally resulted in subsurface contamination that is presently the focus of some environmental concern. In 1994, the Energy and Environmental Research Center (EERC) initiated a three-phase program to investigate the natural attenuation processes that control the subsurface transport and fate of the most commonly used alkanolamine in Canada, monoethanolamine (MEA). Funding for the MEA research program was provided by the U.S. Department of Energy (DOE), Canadian Association of Petroleum Producers (CAPP), Canadian Occidental Petroleum Ltd. (CanOxy), Gas Research Institute (GRI), Environment Canada, and the National Energy Board of Canada. The MEA research program focused primarily on examining the biodegradability of MEA and MEA-related waste materials in soils and soil-slurries under a variety of environmentally relevant conditions, evaluating the mobility of MEA in soil and groundwater and the effectiveness of bioremediation techniques for removing contaminants and toxicity from MEA-contaminated soil. The presently inactive Okotoks sour gas-processing plant, owned by CanOxy in Alberta, Canada, was the source of samples and field data for much of the laboratory-based experimental work and was selected to be the location for the field-based efforts to evaluate remediation techniques. The objective of the research program is to provide the natural gas industry with ''real world'' data and insights developed under laboratory and field conditions regarding the effective and environmentally sound use of biological methods for the remediation of soil

  8. Dynamic and spectroscopic characteristics of atmospheric gliding arc in gas-liquid two-phase flow

    SciTech Connect (OSTI)

    Tu, X.; Yu, L.; Yan, J. H.; Cen, K. F.; Cheron, B. G.

    2009-11-15

    In this study, an atmospheric alternating-current gliding arc device in gas-liquid two-phase flow has been developed for the purpose of waste water degradation. The dynamic behavior of the gas-liquid gliding arc is investigated through the oscillations of electrical signals, while the spatial evolution of the arc column is analyzed by high speed photography. Different arc breakdown regimes are reported, and the restrike mode is identified as the typical fluctuation characteristic of the hybrid gliding arc in air-water mixture. Optical emission spectroscopy is employed to investigate the active species generated in the gas-liquid plasma. The axial evolution of the OH (309 nm) intensity is determined, while the rotational and vibrational temperatures of the OH are obtained by a comparison between the experimental and simulated spectra. The significant discrepancy between the rotational and translational temperatures has also been discussed.

  9. Excimer laser photolysis of group 6 metal carbonyls in the gas phase

    SciTech Connect (OSTI)

    Ishikawa, Yoichi; Brown, C.E.; Hackett, P.A.; Rayner, D.M. )

    1990-03-22

    The excimer laser photolysis of Mo(CO){sub 6} in the gas phase has been studied at 351, 308, 248, and 222 nm with laser-based, time-resolved infrared absorption spectroscopy. Results have also been obtained on the 308- and 222-nm photolysis of Cr(CO){sub 6} and on the 222-nm photolysis of W(CO){sub 6}, complementing earlier studies and presenting a complete picture of group 6 metal carbonyl ultraviolet photodecomposition.

  10. Large Eddy Simulation of Two-Phase Flow Combustion in Gas Turbines |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Fields of temperature and pressure in a simulation of a complete helicopter combustion chamber performed on the IBM Blue Gene/P at the ALCF (July 2010). Large Eddy Simulation of Two-Phase Flow Combustion in Gas Turbines PI Name: Thierry Poinsot PI Email: poinsot@cerfacs.fr Institution: CERFACS Allocation Program: INCITE Allocation Hours at ALCF: 8 Million Year: 2010 Research Domain: Chemistry The increase of computer power has allowed science to make

  11. Large-Eddy Simulation of Two-Phase Flow Combustion in Gas Turbines |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Large-Eddy Simulation of Two-Phase Flow Combustion in Gas Turbines PI Name: Thierry Poinsot PI Email: poinsot@cerfacs.fr Institution: CERFACS Allocation Program: INCITE Allocation Hours at ALCF: 10,000,000 Year: 2012 Research Domain: Chemistry Using the capability of the Blue Gene/P supercomputer, CERFACS has been performing top-of-the-line, quality simulations on highly complex cases to numerically model a real combustor. The project focuses on Large

  12. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1995-08-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  13. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  14. Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

    DOE Patents [OSTI]

    Harvey, Scott D [Kennewick, WA

    2011-06-21

    A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

  15. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO₂ conversion into carbon-neutral fuels and chemicals November 6, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Environmentalists have long lamented the destructive effects of greenhouse gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,

  16. DOE Seeks Industry Proposals for Feasibility Study to Produce Greenhouse

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas-Free Hydrogen at Existing Nuclear Power Plants | Department of Energy Proposals for Feasibility Study to Produce Greenhouse Gas-Free Hydrogen at Existing Nuclear Power Plants DOE Seeks Industry Proposals for Feasibility Study to Produce Greenhouse Gas-Free Hydrogen at Existing Nuclear Power Plants April 13, 2006 - 10:19am Addthis WASHINGTON, DC - In support of President Bush's Advanced Energy Initiative (AEI), Secretary of Energy Samuel W. Bodman today announced that the U.S. Department

  17. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A. Spangler, L.R.

    1995-12-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. The EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is unnecessary. A test program was conducted to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative.

  18. Biomass power and conventional fossil systems with and without CO2 sequestration - Comparing the energy balance, greenhouse gas emissions and economics

    SciTech Connect (OSTI)

    Spath, Pamela L.; Mann, Margaret K.

    2004-01-01

    Lifecycle analysis of coal-, natural gas- and biomass-based power generation systems with and without CO2 sequestration. Compares global warming potential and energy balance of these systems.

  19. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    1999-05-01

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  20. ART CCIM Phase II-A Off-Gas System Evaluation Test Plan

    SciTech Connect (OSTI)

    Nick Soelberg; Jay Roach

    2009-01-01

    This test plan defines testing to be performed using the Idaho National Laboratory (INL) engineering-scale cold crucible induction melter (CCIM) test system for Phase II-A of the Advanced Remediation Technologies (ART) CCIM Project. The multi-phase ART-CCIM Project is developing a conceptual design for replacing the joule-heated melter (JHM) used to treat high level waste (HLW) in the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) with a cold crucible induction melter. The INL CCIM test system includes all feed, melter off-gas control, and process control subsystems needed for fully integrated operation and testing. Testing will include operation of the melter system while feeding a non-radioactive slurry mixture prepared to simulate the same type of waste feed presently being processed in the DWPF. Process monitoring and sample collection and analysis will be used to characterize the off-gas composition and properties, and to show the fate of feed constituents, to provide data that shows how the CCIM retrofit conceptual design can operate with the existing DWPF off-gas control system.

  1. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  2. Hydrodynamics during the Deconfinement Phase Transition from a Hadronic Gas to a Colorless QGP

    SciTech Connect (OSTI)

    Ladrem, M.; Zaki-Al-Full, Z.; Herbadji, S.

    2011-10-27

    The collective flow of hot and dense matter (partonic plasma and hadronic gas) created in an ultra relativistic heavy ion collision can be usually described by hydrodynamics if only the thermalization is achieved and if it can be locally maintained during the subsequent expansion. It requires knowledge of the equation of state, which gives a relation between pressure P, energy density {epsilon}, entropy density s and sound velocityc{sub s}, but no detailed knowledge of the microscopic dynamics. After the study of these hydrodynamical collective observables in a previous work, we investigate in the present work some correlations between them outshining some relevant features of the equation of state and the hydrodynamical expansion of the system undergoing a deconfinement phase transition from hadronic gas to colorless quark gluon plasma. We also investigate the finite volume effect on the collective dynamical evolution of the system.

  3. Direct method gas-phase oxygen abundances of four Lyman break analogs

    SciTech Connect (OSTI)

    Brown, Jonathan S.; Croxall, Kevin V.; Pogge, Richard W.

    2014-09-10

    We measure the gas-phase oxygen abundances in four Lyman break analogs using auroral emission lines to derive direct abundances. The direct method oxygen abundances of these objects are generally consistent with the empirically derived strong-line method values, confirming that these objects are low oxygen abundance outliers from the mass-metallicity (MZ) relation defined by star forming Sloan Digital Sky Survey galaxies. We find slightly anomalous excitation conditions (Wolf-Rayet features) that could potentially bias the empirical estimates toward high values if caution is not exercised in the selection of the strong-line calibration. The high rate of star formation and low oxygen abundance of these objects is consistent with the predictions of the fundamental metallicity relation, in which the infall of relatively unenriched gas simultaneously triggers an episode of star formation and dilutes the interstellar medium of the host galaxy.

  4. Entropic description of gas hydrate ice/liquid equilibrium via enhanced sampling of coexisting phases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malolepsza, Edyta; Kim, Jaegil; Keyes, Tom

    2015-04-28

    Metastable β ice holds small guest molecules in stable gas hydrates, so its solid/liquid equilibrium is of interest. However, aqueous crystal/liquid transitions are very difficult to simulate. A new MD algorithm generates trajectories in a generalized NPT ensemble and equilibrates states of coexisting phases with a selectable enthalpy. Furthermore, with replicas spanning the range between β ice and liquid water we find the statistical temperature from the enthalpy histograms and characterize the transition by the entropy, introducing a general computational procedure for first-order transitions.

  5. Gas-phase photocatalytic oxidation: Cost comparison with other air pollution control technologies

    SciTech Connect (OSTI)

    Turchi, C S; Wolfrum, E J; Miller, R A

    1994-11-01

    Gas-phase photocatalytic oxidation (PCO) appears to be particularly well suited for waste streams with low pollutant concentrations (1000 ppm or less) and low to moderate flow rates (< 20,000 cubic feet per minute, cfm). The PCO technology is modular in nature and thus is well suited to treat dispersed or low flow rate streams. This same attribute minimizes the advantages of scale for PCO and makes the technology comparatively less attractive for high volume waste streams. Key advantages for PCO lie in its low operating cost and ability to completely destroy pollutants at ambient temperature and pressure.

  6. Pipeline gas demonstration plant, Phase I. Quarterly technical progress report for September 1980-November 1980

    SciTech Connect (OSTI)

    Eby, R.J.

    1980-12-01

    Work was performed in the following tasks in Phase I of the Pipeline Gas Demonstration Plant Program: Site Evaluation and Selection; Demonstration Plant Environmental Analysis; Feedstock Plans, Licenses, Permits and Easements; Demonstration Plant Definitive Design; Construction Planning; Economic Reassessment; Technical Support; Long Lead Procurement List; and Project Management. The Preliminary Construction Schedule was delivered to the Government on October 3, 1980, constituting an early delivery of the construction schedule called for in the scope of work for Task VI. The major work activity continues to be the effort in Task VI, Demonstration Plant Definitive Design, with two 30% Design Review meetings being held with the Government. Work in Task VII, Construction Planning, was initiated. Work has progressed satisfactorily in the other tasks in support of the Demonstration Plant Program. A Cost Change Proposal was submitted because of an increase in the scope of work and an extension of the schedule for Phase I to 47 months.

  7. Dynamic Modeling Strategy for Flow Regime Transition in Gas-Liquid Two-Phase Flows

    SciTech Connect (OSTI)

    Xia Wang; Xiaodong Sun; Benjamin Doup; Haihua Zhao

    2012-12-01

    In modeling gas-liquid two-phase flows, the concept of flow regimes has been widely used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are flow regime dependent. Current nuclear reactor safety analysis codes, such as RELAP5, classify flow regimes using flow regime maps or transition criteria that were developed for steady-state, fully-developed flows. As twophase flows are dynamic in nature, it is important to model the flow regime transitions dynamically to more accurately predict the two-phase flows. The present work aims to develop a dynamic modeling strategy to determine flow regimes in gas-liquid two-phase flows through introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation of the interfacial area, fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation, and the destruction of the interfacial area, fluid particle coalescence and condensation. For flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shapes, namely group-1 and group-2 bubbles. A preliminary approach to dynamically identify the flow regimes is discussed, in which discriminator s are based on the predicted information, such as the void fraction and interfacial area concentration. The flow regime predicted with this method shows good agreement with the experimental observations.

  8. Critical point of gas-liquid type phase transition and phase equilibrium functions in developed two-component plasma model

    SciTech Connect (OSTI)

    Butlitsky, M. A.; Zelener, B. V.

    2014-07-14

    A two-component plasma model, which we called a shelf Coulomb model has been developed in this work. A Monte Carlo study has been undertaken to calculate equations of state, pair distribution functions, internal energies, and other thermodynamics properties. A canonical NVT ensemble with periodic boundary conditions was used. The motivation behind the model is also discussed in this work. The shelf Coulomb model can be compared to classical two-component (electron-proton) model where charges with zero size interact via a classical Coulomb law. With important difference for interaction of opposite charges: electrons and protons interact via the Coulomb law for large distances between particles, while interaction potential is cut off on small distances. The cut off distance is defined by an arbitrary ? parameter, which depends on system temperature. All the thermodynamics properties of the model depend on dimensionless parameters ? and ? = ?e{sup 2}n{sup 1/3} (where ? = 1/k{sub B}T, n is the particle's density, k{sub B} is the Boltzmann constant, and T is the temperature) only. In addition, it has been shown that the virial theorem works in this model. All the calculations were carried over a wide range of dimensionless ? and ? parameters in order to find the phase transition region, critical point, spinodal, and binodal lines of a model system. The system is observed to undergo a first order gas-liquid type phase transition with the critical point being in the vicinity of ?{sub crit}?13(T{sub crit}{sup *}?0.076),?{sub crit}?1.8(v{sub crit}{sup *}?0.17),P{sub crit}{sup *}?0.39, where specific volume v* = 1/?{sup 3} and reduced temperature T{sup *} = ?{sup ?1}.

  9. Vaccum Gas Tungsten Arc Welding, phase 1. Technical report, October 1993-March 1995

    SciTech Connect (OSTI)

    Weeks, J.L.; Krotz, P.D.; Todd, D.T.; Liaw, Y.K.

    1995-03-01

    This two year program will investigate Vacuum Gas Tungsten Arc Welding (VGTAW) as a method to modify or improve the weldability of normally difficult-to-weld materials. VGTAW appears to offer a significant improvement in weldability because of the clean environment and lower heat input needed. The overall objective of the program is to develop the VGTAW technology and implement it into a manufacturing environment that will result in lower cost, better quality and higher reliability aerospace components for the space shuttle and other NASA space systems. Phase 1 of this program was aimed at demonstrating the process`s ability to weld normally difficult-to-weld materials. Phase 2 will focus on further evaluation, a hardware demonstration and a plan to implement VGTAW technology into a manufacturing environment. During Phase 1, the following tasks were performed: (1) Task 11000 Facility Modification - an existing vacuum chamber was modified and adapted to a GTAW power supply; (2) Task 12000 Materials Selection - four difficult-to-weld materials typically used in the construction of aerospace hardware were chosen for study; (3) Task 13000 VGTAW Experiments - welding experiments were conducted under vacuum using the hollow tungsten electrode and evaluation. As a result of this effort, two materials, NARloy Z and Incoloy 903, were downselected for further characterization in Phase 2; and (4) Task 13100 Aluminum-Lithium Weld Studies - this task was added to the original work statement to investigate the effects of vacuum welding and weld pool vibration on aluminum-lithium alloys.

  10. Enhanced Generic Phase-field Model of Irradiation Materials: Fission Gas Bubble Growth Kinetics in Polycrystalline UO2

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2012-05-30

    Experiments show that inter-granular and intra-granular gas bubbles have different growth kinetics which results in heterogeneous gas bubble microstructures in irradiated nuclear fuels. A science-based model predicting the heterogeneous microstructure evolution kinetics is desired, which enables one to study the effect of thermodynamic and kinetic properties of the system on gas bubble microstructure evolution kinetics and morphology, improve the understanding of the formation mechanisms of heterogeneous gas bubble microstructure, and provide the microstructure to macroscale approaches to study their impact on thermo-mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking. In our previous report 'Mesoscale Benchmark Demonstration, Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing', we developed a phase-field model to simulate the intra-granular gas bubble evolution in a single crystal during post-irradiation thermal annealing. In this work, we enhanced the model by incorporating thermodynamic and kinetic properties at grain boundaries, which can be obtained from atomistic simulations, to simulate fission gas bubble growth kinetics in polycrystalline UO2 fuels. The model takes into account of gas atom and vacancy diffusion, vacancy trapping and emission at defects, gas atom absorption and resolution at gas bubbles, internal pressure in gas bubbles, elastic interaction between defects and gas bubbles, and the difference of thermodynamic and kinetic properties in matrix and grain boundaries. We applied the model to simulate gas atom segregation at grain boundaries and the effect of interfacial energy and gas mobility on gas bubble morphology and growth kinetics in a bi-crystal UO2 during post-irradiation thermal annealing. The preliminary results demonstrate that the model can produce the equilibrium thermodynamic properties and the morphology of gas bubbles at

  11. Greenhouse gas and air pollutant emission reduction potentials of renewable energy - case studies on photovoltaic and wind power introduction considering interactions among technologies in Taiwan

    SciTech Connect (OSTI)

    Yu-Ming Kuo; Yasuhiro Fukushima

    2009-03-15

    To achieve higher energy security and lower emission of greenhouse gases (GHGs) and pollutants, the development of renewable energy has attracted much attention in Taiwan. In addition to its contribution to the enhancement of reliable indigenous resources, the introduction of renewable energy such as photovoltaic (PV) and wind power systems reduces the emission of GHGs and air pollutants by substituting a part of the carbon- and pollutant-intensive power with power generated by methods that are cleaner and less carbon-intensive. To evaluate the reduction potentials, consequential changes in the operation of different types of existing power plants have to be taken into account. In this study, a linear mathematical programming model is constructed to simulate a power mix for a given power demand in a power market sharing a cost-minimization objective. By applying the model, the emission reduction potentials of capacity extension case studies, including the enhancement of PV and wind power introduction at different scales, were assessed. In particular, the consequences of power mix changes in carbon dioxide, nitrogen oxides, sulfur oxides, and particulates were discussed. Seasonally varying power demand levels, solar irradiation, and wind strength were taken into account. In this study, we have found that the synergetic reduction of carbon dioxide emission induced by PV and wind power introduction occurs under a certain level of additional installed capacity. Investigation of a greater variety of case studies on scenario development with emerging power sources becomes possible by applying the model developed in this study. 15 refs., 8 figs., 11 tabs.

  12. TRANSITION STATE FOR THE GAS-PHASE REACTION OF URANIUM HEXAFLUORIDE WITH WATER

    SciTech Connect (OSTI)

    Garrison, S; James Becnel, J

    2008-03-18

    Density Functional Theory and small-core, relativistic pseudopotentials were used to look for symmetric and asymmetric transitions states of the gas-phase hydrolysis reaction of uranium hexafluoride, UF{sub 6}, with water. At the B3LYP/6-31G(d,p)/SDD level, an asymmetric transition state leading to the formation of a uranium hydroxyl fluoride, U(OH)F{sub 5}, and hydrogen fluoride was found with an energy barrier of +77.3 kJ/mol and an enthalpy of reaction of +63.0 kJ/mol (both including zero-point energy corrections). Addition of diffuse functions to all atoms except uranium led to only minor changes in the structure and relative energies of the reacting complex and transition state. However, a significant change in the product complex structure was found, significantly reducing the enthalpy of reaction to +31.9 kJ/mol. Similar structures and values were found for PBE0 and MP2 calculations with this larger basis set, supporting the B3LYP results. No symmetric transition state leading to the direct formation of uranium oxide tetrafluoride, UOF{sub 4}, was found, indicating that the reaction under ambient conditions likely includes several more steps than the mechanisms commonly mentioned. The transition state presented here appears to be the first published transition state for the important gas-phase reaction of UF{sub 6} with water.

  13. Single-step gas phase synthesis of stable iron aluminide nanoparticles with soft magnetic properties

    SciTech Connect (OSTI)

    Vernieres, Jerome Benelmekki, Maria; Kim, Jeong-Hwan; Grammatikopoulos, Panagiotis; Diaz, Rosa E.; Bobo, Jean-François; Sowwan, Mukhles

    2014-11-01

    Soft magnetic alloys at the nanoscale level have long generated a vivid interest as candidate materials for technological and biomedical purposes. Consequently, controlling the structure of bimetallic nanoparticles in order to optimize their magnetic properties, such as high magnetization and low coercivity, can significantly boost their potential for related applications. However, traditional synthesis methods stumble upon the long standing challenge of developing true nanoalloys with effective control over morphology and stability against oxidation. Herein, we report on a single-step approach to the gas phase synthesis of soft magnetic bimetallic iron aluminide nanoparticles, using a versatile co-sputter inert gas condensation technique. This method allowed for precise morphological control of the particles; they consisted of an alloy iron aluminide crystalline core (DO{sub 3} phase) and an alumina shell, which reduced inter-particle interactions and also prevented further oxidation and segregation of the bimetallic core. Remarkably, the as-deposited alloy nanoparticles show interesting soft magnetic properties, in that they combine a high saturation magnetization (170 emu/g) and low coercivity (less than 20 Oe) at room temperature. Additional functionality is tenable by modifying the surface of the particles with a polymer, to ensure their good colloidal dispersion in aqueous environments.

  14. Fundamental limits on gas-phase chemical reduction of NOx in a plasma

    SciTech Connect (OSTI)

    Penetrante, B.M.; Hsiao, M.C.; Merritt, B.T.; Vogtlin, G.E.

    1997-12-31

    In the plasma, the electrons do not react directly with the NOx molecules. The electrons collide mainly with the background gas molecules like N{sub 2}, O{sub 2} and H{sub 2}O. Electron impact on these molecules result partly in dissociation reactions that produce reactive species like N, O and OH. The NOx in the engine exhaust gas initially consist mostly of NO. The ground state nitrogen atom, N, is the only species that could lead to the chemical reduction of NO to N{sub 2}. The O radical oxidizes NO to NO{sub 2} leaving the same amount of NOx. The OH radical converts NO{sub 2} to nitric acid. Acid products in the plasma can easily get adsorbed on surfaces in the plasma reactor and in the pipes. When undetected, the absence of these oxidation products can often be mistaken for chemical reduction of NOx. In this paper the authors will examine the gas-phase chemical reduction of NOx. They will show that under the best conditions, the plasma can chemically reduce 1.6 grams of NOx per brake-horsepower-hour [g(NOx)/bhp-hr] when 5% of the engine output energy is delivered to the plasma.

  15. CASCADER: An M-chain gas-phase radionuclide transport and fate model. Volume 4 -- Users guide to CASCADR9

    SciTech Connect (OSTI)

    Cawlfield, D.E.; Emer, D.F.; Lindstrom, F.T.; Shott, G.J.

    1993-09-01

    Chemicals and radionuclides move either in the gas-phase, liquid-phase, or both phases in soils. They may be acted upon by either biological or abiotic processes through advection and/or dispersion. Additionally during the transport of parent and daughter radionuclides in soil, radionuclide decay may occur. This version of CASCADER called CASCADR9 starts with the concepts presented in volumes one and three of this series. For a proper understanding of how the model works, the reader should read volume one first. Also presented in this volume is a set of realistic scenarios for buried sources of radon gas, and the input and output file structure for CASCADER9.

  16. Statement from U.S. Energy Secretary Moniz on Mexico's Greenhouse...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    "We warmly welcome the announcement by the Government of Mexico on new greenhouse gas emissions reduction targets. The commitment Mexico has made today sends a strong signal of ...

  17. Femtosecond pure-rotational coherent anti-stokes raman scattering gas phase diagnostics.

    SciTech Connect (OSTI)

    Kearney, Sean Patrick; Serrano, Justin Raymond

    2010-12-01

    We discuss recent experiments for the characterization of our femtosecond pure rotational CARS facility for observation of Raman transients in N{sub 2} and atmospheric air. The construction of a simplified femtosecond four-wave mixing system with only a single laser source is presented. Pure-rotational Raman transients reveal well-ordered time-domain recurrence peaks associated with the near-uniform spacing of rotational Raman peaks in the spectral domain. Long-time, 100-ps duration observations of the transient Raman polarization are presented, and the observed transients are compared to simulated results. Fourier transformation of the transients reveals two distinct sets of beat frequencies. Simulation results for temperatures from 300-700 K are used to illustrate the temperature sensitivity of the time-domain transients and their Fourier-transform counterparts. And strategies for diagnostics are briefly discussed. These results are being utilized to develop gas-phase measurement strategies for temperature and species concentration.

  18. Gas-phase study on uridine: Conformation and X-ray photofragmentation

    SciTech Connect (OSTI)

    Itl, Eero Kooser, Kuno; Levola, Helena; Rachlew, Elisabeth; Ha, Dang Trinh; Kukk, Edwin

    2015-05-21

    Fragmentation of RNA nucleoside uridine, induced by carbon 1s core ionization, has been studied. The measurements by combined electron and ion spectroscopy have been performed in gas phase utilizing synchrotron radiation. As uridine is a combination of d-ribose and uracil, which have been studied earlier with the same method, this study also considers the effect of chemical environment and the relevant functional groups. Furthermore, since in core ionization the initial core hole is always highly localized, charge migration prior to fragmentation has been studied here. This study also demonstrates the destructive nature of core ionization as in most cases the C 1s ionization of uridine leads to concerted explosions producing only small fragments with masses ?43 amu. In addition to fragmentation patterns, we found out that upon evaporation the sugar part of the uridine molecule attains hexagonal form.

  19. The Northwest Infrared (NWIR) gas-phase spectral database of industrial and environmental chemicals: Recent updates

    SciTech Connect (OSTI)

    Brauer, Carolyn S.; Johnson, Timothy J.; Blake, Thomas A.; Sharpe, Steven W.; Sams, Robert L.; Tonkyn, Russell G.

    2014-05-22

    With continuing improvements in both standoff- and point-sensing techniques, there is an ongoing need for high-quality infrared spectral databases. The Northwest Infrared Database (NWIR) contains quantitative, gas-phase infrared spectra of nearly 500 pure chemical species that can be used for a variety of applications such as atmospheric monitoring, biomass burning studies, etc. The data, recorded at 0.1 cm-1 resolution, are pressure broadened to one atmosphere (N2) in order to mimic atmospheric conditions. Each spectrum is a composite composed of multiple individual measurements. Recent updates to the database include over 60 molecules that are known or suspected biomass-burning effluents. Examples from this set of measurements will be presented and experimental details will be discussed in the context of the utility of NWIR for environmental applications.

  20. Natural Gas Weekly Update, Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    Gas Prices Contributing to Increases in Greenhouse Gas Emissions: The United States Environmental Protection Agency (EPA) cited increasing natural gas prices as one of three...

  1. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I

    SciTech Connect (OSTI)

    Raymond Hobbs

    2007-05-31

    The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of

  2. The contribution of gas-phase reactions in the Pt-catalyzed conversion of ethane-oxygen mixtures

    SciTech Connect (OSTI)

    Huff, M.C.; Androulakis, I.P.; Sinfelt, J.H.; Reyes, S.C.

    2000-04-01

    This paper presents an analysis of the oxidative dehydrogenation of ethane on platinum-containing monoliths. The purpose of the work is to make a quantitative assessment of the extent to which homogeneous gas-phase reactions contribute to the overall conversion of the ethane. In making the analysis, extensive use is made of kinetic information obtained and compiled by A.M. Dean and associates for elementary homogeneous reaction steps and by L.D. Schmidt and associates for elementary surface reactions. A critical part of the analysis is concerned with accounting for the heat effects and for the reactor temperature gradient resulting therefrom. This is absolutely essential for meeting the objective of this investigation. The rise in temperature as the gases proceed through the reactor is responsible for a very substantial contribution of homogeneous gas-phase reactions in the chemical transformation occurring. one can view the process as a sequential one in which ethane is first oxidized on the platinum surface to CO, CO{sub 2} and H{sub 2}O in the front region of the monolith. The formation of these products causes a substantial temperature increase that drives the dehydrogenation of ethane to ethylene (and acetylene) in the gas phase. The heat required to sustain these endothermic reactions in the tail end of the reaction zone is supplied by exothermic gas-phase oxidation reactions that form additional H{sub 2}O and CO. Overall, the system can be viewed as one in which the catalyst initiates gas-phase chemistry through the acceleration of exothermic reactions at the front of the reactor which increase the downstream temperature to the point where gas-phase reactions occur readily.

  3. Pathways through equilibrated states with coexisting phases for gas hydrate formation

    SciTech Connect (OSTI)

    Malolepsza, Edyta; Keyes, Tom

    2015-12-01

    Under ambient conditions, water freezes to either hexagonal ice or a hexagonal/cubic composite ice. The presence of hydrophobic guest molecules introduces a competing pathway: gas hydrate formation, with the guests in clathrate cages. Here, the pathways of the phase transitions are sought as sequences of states with coexisting phases, using a generalized replica exchange algorithm designed to sample them in equilibrium, avoiding nonequilibrium processes. For a dilute solution of methane in water under 200 atm, initializing the simulation with the full set of replicas leads to methane trapped in hexagonal/cubic ice, while gradually adding replicas with decreasing enthalpy produces the initial steps of hydrate growth. Once a small amount of hydrate is formed, water rearranges to form empty cages, eventually transforming the remainder of the system to metastable β ice, a scaffolding for hydrates. It is suggested that configurations with empty cages are reaction intermediates in hydrate formation when more guest molecules are available. Furthermore, free energy profiles show that methane acts as a catalyst reducing the barrier for β ice versus hexagonal/cubic ice formation.

  4. Pathways through equilibrated states with coexisting phases for gas hydrate formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malolepsza, Edyta; Keyes, Tom

    2015-12-01

    Under ambient conditions, water freezes to either hexagonal ice or a hexagonal/cubic composite ice. The presence of hydrophobic guest molecules introduces a competing pathway: gas hydrate formation, with the guests in clathrate cages. Here, the pathways of the phase transitions are sought as sequences of states with coexisting phases, using a generalized replica exchange algorithm designed to sample them in equilibrium, avoiding nonequilibrium processes. For a dilute solution of methane in water under 200 atm, initializing the simulation with the full set of replicas leads to methane trapped in hexagonal/cubic ice, while gradually adding replicas with decreasing enthalpy produces themore » initial steps of hydrate growth. Once a small amount of hydrate is formed, water rearranges to form empty cages, eventually transforming the remainder of the system to metastable β ice, a scaffolding for hydrates. It is suggested that configurations with empty cages are reaction intermediates in hydrate formation when more guest molecules are available. Furthermore, free energy profiles show that methane acts as a catalyst reducing the barrier for β ice versus hexagonal/cubic ice formation.« less

  5. Method of monitoring photoactive organic molecules in-situ during gas-phase deposition of the photoactive organic molecules

    SciTech Connect (OSTI)

    Forrest, Stephen R.; Vartanian, Garen; Rolin, Cedric

    2015-06-23

    A method for in-situ monitoring of gas-phase photoactive organic molecules in real time while depositing a film of the photoactive organic molecules on a substrate in a processing chamber for depositing the film includes irradiating the gas-phase photoactive organic molecules in the processing chamber with a radiation from a radiation source in-situ while depositing the film of the one or more organic materials and measuring the intensity of the resulting photoluminescence emission from the organic material. One or more processing parameters associated with the deposition process can be determined from the photoluminescence intensity data in real time providing useful feedback on the deposition process.

  6. Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium

    SciTech Connect (OSTI)

    Marcalo, Joaquim; Gibson, John K.

    2009-08-10

    An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.

  7. Greenhouse Gases Converted to Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gases Converted to Fuel Greenhouse Gases Converted to Fuel carbon-conversion-fig-1.jpg Key Challenges: An important strategy for reducing global CO2 emissions calls for...

  8. EIA - Emissions of Greenhouse Gases in the United States 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) This report-the eighteenth annual report-presents the U.S. Energy Information Administration's latest estimates of emissions for carbon dioxide, methane, nitrous oxide, and other greenhouse gases. Download the GHG Report Introduction For this report, activity data on coal and natural gas consumption and electricity sales and losses

  9. EIA - Emissions of Greenhouse Gases in the United States 2009

    Gasoline and Diesel Fuel Update (EIA)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) This report-the eighteenth annual report-presents the U.S. Energy Information Administration's latest estimates of emissions for carbon dioxide, methane, nitrous oxide, and other greenhouse gases. Download the GHG Report Introduction For this report, activity data on coal and natural gas consumption and electricity sales and losses

  10. Evaluation of the Effects of Natural Gas Contaminants on Corrosion in Compressed Natural Gas Storage Systems - Phase II

    SciTech Connect (OSTI)

    Lyle, F.F. Jr.

    1988-01-01

    This report describes a research program that was conducted to define natural gas contaminant levels necessary to insure that internal corrosion of compressed natural gas (CNG) cylinders does not constitute a hazard over the lifetimes of the cylinders. A literature search was performed and companies in the natural gas transmission and distribution industries were contacted: to identify and determine the composition ranges of contaminants in natural gases; and to obtain information regarding corrosion damage of CNG cylinders and cylinder materials. Corrosion and stress corrosion cracking (SCC) tests were performed on the cylinder materials most widely used in CNG cylinders in the United States (4130X and 15B30 steels and 6061-T6 aluminum alloy). Tests were conducted in: natural gases from several producing wells and from an interstate pipeline; and in aqueous solutions saturated with varying concentrations of natural gas contaminants. Also, metallurgical analyses of nine (eight steel and one aluminum), used CNG cylinders were performed. Limiting concentrations of hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}), and other CNG contaminants necessary to prevent internal corrosion of CNG fuel and storage cylinders were defined. This knowledge will minimize potential hazards of using CNG as a vehicle fuel. It should also lead to reduced costs of CNG use, since it has been shown that reduction of contaminants to the very low levels currently specified by the U.S. Department of Transportation (DOT) and the Canadian Transport Commission (CTC) is not necessary. A gas-quality standard based on program results is recommended. The National Fire Protection Association (NFPA) has adopted the recommended gas-quality standard.

  11. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    SciTech Connect (OSTI)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.

  12. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively.more » We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.« less

  13. A Tetrapositive Metal Ion in the Gas Phase: Thorium(IV) Coordinated by Neutral Tridentate Ligands

    SciTech Connect (OSTI)

    Gong, Yu; Hu, Han-Shi; Tian, Guoxin; Rao, Linfeng; Li, Jun; Gibson, John K.

    2013-07-01

    ESI of 1:1 mixtures of Th(ClO₄)₄ and ligand TMOGA in acetonitrile resulted in the observation of the TMOGA supported tetracation, Th(L)₃⁴⁺, in the gas phase. Three TMOGA ligands are necessary to stabilize the tetrapositive thorium ion; no Th(L)₂⁴⁺ or Th(L)₄⁴⁺ was observed. Theoretical calculations reveal that the Th(L)₃⁴⁺ complex possesses C₃ symmetry with the thorium center coordinated by nine oxygen atoms from three ligands, which forms a twisted TPP geometry. Actinide compounds with such a geometry feature a nine-coordinate chiral actinide center. The Th-L binding energy and bond orders of Th(L)n⁴⁺ decrease as the coordination number increases, consistent with the trend of concurrently increasing Th-O distances. The Th-O bonding is mainly electrostatic in nature, but the covalent interactions are not negligible. CID of the Th(L)₃⁴⁺ complex mainly resulted in charge reduction to form Th(L)₂(L-86)³⁺oss of neutral TMOGA was not observed. The protic ligand methanol stabilized only tri- and dications of ligated thorium. The intensity of the Th(L)₃⁴⁺ peak was reduced as the percentage of water increased in the Th(ClO₄)₄/TMOGA solution.

  14. Mechanism of hydrogenation of ethylene via photoproduced unsaturated iron carbonyl in the gas phase

    SciTech Connect (OSTI)

    Onda, Ken; Takahashi, Makoto ); Ishikawa, Yoishi; Sugita, Kyoko; Tanaka, Kazunori; Arai, Shigeyoshi ); Rayner, D.M.; Hackett, P.A. )

    1991-01-24

    The hydrogenation of ethylene via photoproduced coordinatively unsaturated iron carbonyls in the gas phase has been investigated by measuring deuterium distribution in ethanes produced following photolysis of mixtures of Fe(CO){sub 5}, C{sub 2}H{sub 4}, and hydrogen (D{sub 2} or D{sub 2}/H{sub 2}) by monochromatic CW-UV light (ca. 250 nm). When mixtures of Fe(CO){sub 5}, C{sub 2}H{sub 4}, and D{sub 2} are photolyzed, only ethane-1,2-d{sub 2} and ethane-1,1-d{sub 2} are produced. The ratio of ethane-1,2-d{sub 2} to ethane-1,1-d{sub 2}, ranges from 1.5 to 1.9 but does not depend on the irradiation time. When a mixture containing Fe(CO){sub 5}, C{sub 2}H{sub 4}, H{sub 2}, and D{sub 2} was photolyzed, the only additional product was C{sub 2}H{sub 6}. Ethane-d{sub 1} was not observed. These results suggest that both deuterated ethanes are produced in the primary hydrogenation process and that one ethylene molecule reacts with one hydrogen molecule on the metal. Possible hydrogenation mechanisms are discussed in light of the observed results.

  15. Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide

    SciTech Connect (OSTI)

    Gong, Yu; De Jong, Wibe A.; Gibson, John K.

    2015-05-13

    Activation of the oxo bond of uranyl, UO22+, was achieved by collision induced dissociation (CID) of UO2(N3)Cl2 in a quadrupole ion trap mass spectrometer. The gas phase complex UO2(N3)Cl2 was produced by electrospray ionization of solutions of UO2Cl2 and NaN3. CID of UO2(N3)Cl2 resulted in the loss of N2 to form UO(NO)Cl2, in which the inert uranyl oxo bond has been activated. Formation of UO2Cl2 via N3 loss was also observed. Density functional theory computations predict that the UO(NO)Cl2 complex has nonplanar Cs symmetry and a singlet ground state. Analysis of the bonding of the UO(NO)Cl2 complex shows that the side-on bonded NO moiety can be considered as NO3, suggesting a formal oxidation state of U(VI). Activation of the uranyl oxo bond in UO2(N3)Cl2 to form UO(NO)Cl2 and N2 was computed to be endothermic by 169 kJ/mol, which is energetically more favorable than formation of NUOCl2 and UO2Cl2. The observation of UO2Cl2 during CID is most likely due to the absence of an energy barrier for neutral ligand loss.

  16. Oxygenates from light alkanes catalyzed by NO{sub x} in the gas phase

    SciTech Connect (OSTI)

    Otsuka, Kiyoshi; Takahashi, Ryo; Yamanaka, Ichiro

    1999-07-01

    The partial oxidations of light alkanes (methane, ethane, propane, and iso-butane) catalyzed by NO{sub x} in the gas phase have been studied at a pressure of less than 1 bar. For all the alkanes tested, the addition of NO to the mixture of alkanes and O{sub 2} enhanced the selectivities and the yields of oxygenates remarkably. It was suggested that NO{sub 2} generated from NO and O{sub 2} initiated the oxidation of alkanes and would specifically accelerate the C-C bond fission, enhancing the formation of C{sub 1}-oxygenates from ethane, propane, and iso-butane. No{sub 2} and NO would be used as a homogeneous catalyst at >600 C because nitroalkanes formed were decomposed completely, releasing the NO{sub x}. The comparison of the product distributions for the decomposition and oxidation of nitroalkanes and alkylnitrites strongly suggested that the oxygenates (HCHO, CH{sub 3}CHO, and CH{sub 3}COCH{sub 3}) were formed from the corresponding alkylnitrites which must be the reaction intermediates during the oxidation of alkanes with an O{sub 2} and NO mixture.

  17. Tsuji Nurseries Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Nurseries Greenhouse Low Temperature Geothermal Facility Facility Tsuji Nurseries Sector Geothermal energy Type Greenhouse Location Susanville, California Coordinates...

  18. Development of a direct-injected natural gas engine system for heavy-duty vehicles: Final report phase 2

    SciTech Connect (OSTI)

    Cox, G.B.; DelVecchio, K.A.; Hays, W.J.; Hiltner, J.D.; Nagaraj, R.; Emmer, C.

    2000-03-02

    This report summarizes the results of Phase 2 of this contract. The authors completed four tasks under this phase of the subcontract. (1) They developed a computational fluid dynamics (CFD) model of a 3500 direct injected natural gas (DING) engine gas injection/combustion system and used it to identify DING ignition/combustion system improvements. The results were a 20% improvement in efficiency compared to Phase 1 testing. (2) The authors designed and procured the components for a 3126 DING engine (300 hp) and finished assembling it. During preliminary testing, the engine ran successfully at low loads for approximately 2 hours before injector tip and check failures terminated the test. The problems are solvable; however, this phase of the program was terminated. (3) They developed a Decision & Risk Analysis model to compare DING engine technology with various other engine technologies in a number of commercial applications. The model shows the most likely commercial applications for DING technology and can also be used to identify the sensitivity of variables that impact commercial viability. (4) MVE, Inc., completed a preliminary design concept study that examines the major design issues involved in making a reliable and durable 3,000 psi LNG pump. A primary concern is the life of pump seals and piston rings. Plans for the next phase of this program (Phase 3) have been put on indefinite hold. Caterpillar has decided not to fund further DING work at this time due to limited current market potential for the DING engine. However, based on results from this program, the authors believe that DI natural gas technology is viable for allowing a natural gas-fueled engine to achieve diesel power density and thermal efficiency for both the near and long terms.

  19. Underground natural gas storage reservoir management: Phase 2. Final report, June 1, 1995--March 30, 1996

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.V.

    1996-12-31

    Gas storage operators are facing increased and more complex responsibilities for managing storage operations under Order 636 which requires unbundling of storage from other pipeline services. Low cost methods that improve the accuracy of inventory verification are needed to optimally manage this stored natural gas. Migration of injected gas out of the storage reservoir has not been well documented by industry. The first portion of this study addressed the scope of unaccounted for gas which may have been due to migration. The volume range was estimated from available databases and reported on an aggregate basis. Information on working gas, base gas, operating capacity, injection and withdrawal volumes, current and non-current revenues, gas losses, storage field demographics and reservoir types is contained among the FERC Form 2, EIA Form 191, AGA and FERC Jurisdictional databases. The key elements of this study show that gas migration can result if reservoir limits have not been properly identified, gas migration can occur in formation with extremely low permeability (0.001 md), horizontal wellbores can reduce gas migration losses and over-pressuring (unintentionally) storage reservoirs by reinjecting working gas over a shorter time period may increase gas migration effects.

  20. Energy Efficency and Greenhouse Gas Connection

    U.S. Energy Information Administration (EIA) Indexed Site

    Efficiency and Carbon Emissions Efficiency and Carbon Emissions Energy use for various services has a number of impacts on the environment. Energy combustion by-products include...

  1. Recommended Practice for Quantifying Greenhouse Gas Emissions...

    Open Energy Info (EERE)

    Public Transportation Association Website: www.apta.comresourceshottopicssustainabilityDocumentsQuantifying- Transport Toolkit Region(s): Australia & North America...

  2. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    Annual Coal Distribution Report > Annual Coal Distribution Archives Annual Coal Distribution Archive Release Date: February 17, 2011 Next Release Date: December 2011 Domestic coal distribution by origin State, destination State, consumer category, method of transportation; foreign coal distribution by major coal-exporting state and method of transportation; and domestic and foreign coal distribution by origin state. Year Domestic and foreign distribution of U.S. coal by State of origin

  3. EIA - Greenhouse Gas Emissions - Land use

    Gasoline and Diesel Fuel Update (EIA)

    6. Land use 6.1. Total land use, land use change, and forests This chapter presents estimates of carbon sequestration (removal from the atmosphere) and emissions (release into the atmosphere) from forests, croplands, grasslands, and residential areas (urban trees, grass clippings, and food scraps) in the United States. In 2008, land use, land use change, and forests were responsible for estimated net carbon sequestration of 940 MMTCO2e (Table 31), representing 16 percent of total U.S. CO2

  4. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update (EIA)

    3. Methane Emissions 3.1. Total emissions The major sources of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9 percent higher than the 2008 total of 724 MMTCO2e (Table 17). Methane emissions declined steadily from 1990 to 2001, as emissions from coal mining and landfills fell, then rose from 2002 to 2009 as a result of moderate increases in emissions related to energy,

  5. EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    4. Nitrous Oxide Emissions 4.1 Total emissions U.S. nitrous oxide emissions in 2009 were 4 MMTCO2e (1.7 percent) below their 2008 total (Table 22). Sources of U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the majority of agricultural emissions result from nitrogen fertilization of agricultural soils (87 percent of the agriculture total) and management of animal waste (13

  6. INEEL Greenhouse Gas Inventory and Trend Analysis

    SciTech Connect (OSTI)

    Shropshire, David Earl; Teel, Dale Milton

    2000-02-01

    The objective of the INEEL GHG Inventory and Trend Analysis is to establish INEEL expertise in carbon management decision making and policy analysis. This FY-99 effort is the first step toward placing the INEEL in a leadership role within the DOE laboratories to support carbon management systems and analysis.

  7. Baselines for Greenhouse Gas Reductions: Problems, Precedents...

    Open Energy Info (EERE)

    Baseline projection, GHG inventory, Pathways analysis Resource Type: Publications, Lessons learnedbest practices Website: www.p2pays.orgref2221739.pdf References:...

  8. Transformative Reduction of Transportation Greenhouse Gas Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... provide the most benefit in reducing renewable curtailment. ... Initiative Scenario Methods The CTSI Scenario uses a ... Distributed PV 4.80% 6.60% Coal Retirement Schedule 1 "0 ...

  9. NREL: Sustainable NREL - Greenhouse Gas Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and has played a critical support role in the development of federal guidelines for GHG accounting and reporting through DOE's Federal Energy Management Program. Carbon...

  10. Generation, Detection and characterization of Gas-Phase Transition Metal containing Molecules

    SciTech Connect (OSTI)

    Steimle, Timothy

    2015-12-15

    The objective of this project was to generate, detect, and characterize small, gas-phase, metal containing molecules. In addition to being relevant to high temperature chemical environments (e.g. plasmas and combustion), gas-phase experiments on metal containing molecules serve as the most direct link to a molecular-level theoretical model for catalysis. Catalysis (i.e. the addition of a small about of recoverable material to control the rate and direction of a chemical reaction) is critical to the petroleum and pharmaceutical industries as well as environmental remediation. Currently, the majority of catalytic materials are based on very expensive metals such as platinum (Pt), palladium (Pd), iridium (Ir,) rhenium (Re), and rhodium (Rh). For example, the catalyst used for converting linear hydrocarbon molecules (e.g. hexane) to cyclic molecules (e.g. cyclohexane) is a mixture of Pt and Re suspended on alumina. It enables straight chain alkanes to be converted into branched-chain alkanes, cyclohexanes and aromatic hydrocarbons which are used, amongst other things, to enhance the octane number of petrol. A second example is the heterogeneous catalysis used in automobile exhaust systems to: a) decrease nitrogen oxide; b) reduce carbon monoxide; and c) oxidize unburned hydrocarbons. The exhaust is vented through a high-surface area chamber lined with Pt, Pd, and Rh. For example, the carbon monoxide is catalytically converted to carbon dioxide by reaction with oxygen. The research results from this work have been published in readily accessible journals1-28. The ground and excited electronic state properties of small metal containing molecules that we determine were: a) electronic state distributions and lifetimes, b) vibrational frequencies, c) bond lengths and angles, d) hyperfine interactions, e) permanent electric dipole moments, mel, and f) magnetic dipoles, μm. In general terms, μel, gives insight into the charge distribution and mm into

  11. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  12. Rock matrix and fracture analysis of flow in western tight gas sands: Annual report, Phase 3

    SciTech Connect (OSTI)

    Dandge, V.; Graham, M.; Gonzales, B.; Coker, D.

    1987-12-01

    Tight gas sands are a vast future source of natural gas. These sands are characterized as having very low porosity and permeability. The main resource development problem is efficiently extracting the gas from the reservoir. Future production depends on a combination of gas price and technological advances. Gas production can be enhanced by fracturing. Studies have shown that many aspects of fracture design and gas production are influenced by properties of the rock matrix. Computer models for stimulation procedures require accurate knowledge of flow properties of both the rock matrix and the fractured regions. In the proposed work, these properties will be measured along with advanced core analysis procedure aimed at understanding the relationship between pore structure and properties. The objective of this project is to develop reliable core analysis techniques for measuring the petrophysical properties of tight gas sands. Recent research has indicated that the flow conditions in the reservoir can be greatly enhanced by the presence of natural fractures, which serve as a transport path for gas from the less permeable matrix. The study is mainly concerned with the dependence of flow in tight gas matrix and healed tectonic fractures on water saturation and confining pressure. This dependency is to be related to the detailed pore structure of tight sands as typified by cores recovered in the Multi-Well experiment. 22 refs., 34 figs., 9 tabs.

  13. PPPL wins Department of Energy award for reducing greenhouse gases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab wins Department of Energy award for reducing greenhouse gases By Jeanne Jackson DeVoe October 2, 2012 Tweet Widget Google Plus One Share on Facebook PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon dioxide. PPPL reduced leaks of SF6 by 65 percent over three years - reducing overall greenhouse gas

  14. Performances of a bent-crystal spectrometer adapted to resonant x-ray emission measurements on gas-phase samples

    SciTech Connect (OSTI)

    Journel, Loiec; El Khoury, Lara; Marin, Thierry; Guillemin, Renaud; Carniato, Stephane; Avila, Antoine; Delaunay, Renaud; Hague, Coryn F.; Simon, Marc

    2009-09-15

    We describe a bent-crystal spectrometer adapted to measure x-ray emission resulting from core-level excitation of gas-phase molecules in the 0.8-8 keV energy range. The spectrometer is based on the Johann principle, and uses a microfocused photon beam to provide high-resolution (resolving power of {approx}7500). A gas cell was designed to hold a high-pressure (300 mbar) sample of gas while maintaining a high vacuum (10{sup -9} mbar) in the chamber. The cell was designed to optimize the counting rate (2000 cts/s at the maximum of the Cl K{alpha} emission line), while minimizing self-absorption. Example of the K{alpha} emission lines of CH{sub 3}Cl molecules is presented to illustrate the capabilities of this new instrument.

  15. THEORETICAL STUDY ON THE INTERACTION BETWEEN XENON AND POSITIVE SILVER CLUSTERS IN GAS PHASE AND ON THE (001) CHABAZITE SURFACE

    SciTech Connect (OSTI)

    Hunter, D.

    2009-03-16

    A systematic study on the adsorption of xenon on silver clusters in the gas phase and on the (001) surface of silver-exchanged chabazite is reported. Density functional theory at the B3LYP level with the cluster model was employed. The results indicate that the dominant part of the binding is the {sigma} donation, which is the charge transfer from the 5p orbital of Xe to the 5s orbital of Ag and is not the previously suggested d{sub {pi}}-d{sub {pi}} back-donation. A correlation between the binding energy and the degree of {sigma} donation is found. Xenon was found to bind strongly to silver cluster cations and not to neutral ones. The binding strength decreases as the cluster size increases for both cases, clusters in the gas-phase and on the chabazite surface. The Ag{sup +} cation is the strongest binding site for xenon both in gas phase and on the chabazite surface with the binding energies of 73.9 and 14.5 kJ/mol, respectively. The results also suggest that the smaller silver clusters contribute to the negative chemical shifts observed in the {sup 129}Xe NMR spectra in experiments.

  16. http://www.energy.gov/media/F...Biofuels_Lower_Gas_Prices.pdf...

    Broader source: Energy.gov (indexed) [DOE]

    ...F...BiofuelsLowerGasPrices.pdf (52.89 KB) More Documents & Publications Fact Sheet: Gas Prices and Oil Consumption Would Increase Without Biofuels Biofuels & Greenhouse Gas ...

  17. DUST AND GAS IN THE MAGELLANIC CLOUDS FROM THE HERITAGE HERSCHEL KEY PROJECT. II. GAS-TO-DUST RATIO VARIATIONS ACROSS INTERSTELLAR MEDIUM PHASES

    SciTech Connect (OSTI)

    Roman-Duval, Julia; Gordon, Karl D.; Meixner, Margaret; Bot, Caroline; Bolatto, Alberto; Jameson, Katherine; Hughes, Annie; Hony, Sacha; Wong, Tony; Babler, Brian; Bernard, Jean-Philippe; Clayton, Geoffrey C.; Fukui, Yasuo; Galametz, Maud; Galliano, Frederic; Lebouteiller, Vianney; Lee, Min-Young; Israel, Frank; Li, Aigen; and others

    2014-12-20

    The spatial variations of the gas-to-dust ratio (GDR) provide constraints on the chemical evolution and lifecycle of dust in galaxies. We examine the relation between dust and gas at 10-50pc resolution in the Large and Small Magellanic Clouds (LMC and SMC) based on Herschel far-infrared (FIR), H I 21cm, CO, and H? observations. In the diffuse atomic interstellar medium (ISM), we derive the GDR as the slope of the dust-gas relation and find GDRs of 380{sub ?130}{sup +250} 3 in the LMC, and 1200{sub ?420}{sup +1600} 120 in the SMC, not including helium. The atomic-to-molecular transition is located at dust surface densities of 0.05 M {sub ?}pc{sup 2} in the LMC and 0.03 M {sub ?}pc{sup 2} in the SMC, corresponding to A {sub V} ? 0.4 and 0.2, respectively. We investigate the range of CO-to-H{sub 2} conversion factor to best account for all the molecular gas in the beam of the observations, and find upper limits on X {sub CO} to be 6 10{sup 20}cm{sup 2}K{sup 1}km{sup 1} s in the LMC (Z= 0.5 Z {sub ?}) at 15pc resolution, and 4 10{sup 21}cm{sup 2}K{sup 1}km{sup 1} s in the SMC (Z= 0.2 Z {sub ?}) at 45pc resolution. In the LMC, the slope of the dust-gas relation in the dense ISM is lower than in the diffuse ISM by a factor ?2, even after accounting for the effects of CO-dark H{sub 2} in the translucent envelopes of molecular clouds. Coagulation of dust grains and the subsequent dust emissivity increase in molecular clouds, and/or accretion of gas-phase metals onto dust grains, and the subsequent dust abundance (dust-to-gas ratio) increase in molecular clouds could explain the observations. In the SMC, variations in the dust-gas slope caused by coagulation or accretion are degenerate with the effects of CO-dark H{sub 2}. Within the expected 5-20times Galactic X {sub CO} range, the dust-gas slope can be either constant or decrease by a factor of several across ISM phases. Further modeling and observations are required to break the degeneracy

  18. CHEMKIN-III: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics

    SciTech Connect (OSTI)

    Kee, R.J.; Rupley, F.M.; Meeks, E.; Miller, J.A.

    1996-05-01

    This document is the user`s manual for the third-generation CHEMKIN package. CHEMKIN is a software package whose purpose is to facilitate the formation, solution, and interpretation of problems involving elementary gas-phase chemical kinetics. It provides a flexible and powerful tool for incorporating complex chemical kinetics into simulations of fluid dynamics. The package consists of two major software components: an Interpreter and a Gas-Phase Subroutine Library. The Interpreter is a program that reads a symbolic description of an elementary, user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Gas-Phase Subroutine Library. This library is a collection of about 100 highly modular FORTRAN subroutines that may be called to return information on equations of state, thermodynamic properties, and chemical production rates. CHEMKIN-III includes capabilities for treating multi-fluid plasma systems, that are not in thermal equilibrium. These new capabilities allow researchers to describe chemistry systems that are characterized by more than one temperature, in which reactions may depend on temperatures associated with different species; i.e. reactions may be driven by collisions with electrons, ions, or charge-neutral species. These new features have been implemented in such a way as to require little or no changes to CHEMKIN implementation for systems in thermal equilibrium, where all species share the same gas temperature. CHEMKIN-III now has the capability to handle weakly ionized plasma chemistry, especially for application related to advanced semiconductor processing.

  19. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  20. EIA-Voluntary Reporting of Greenhouse Gases Program - What are...

    U.S. Energy Information Administration (EIA) Indexed Site

    What are Greenhouse Gases? Voluntary Reporting of Greenhouse Gases Program What are Greenhouse Gases? Many chemical compounds found in the Earth's atmosphere act as "greenhouse ...

  1. Experimental and numerical investigation of shock wave propagation through complex geometry, gas continuous, two-phase media

    SciTech Connect (OSTI)

    Chien-Chih Liu, J.

    1993-12-31

    The work presented here investigates the phenomenon of shock wave propagation in gas continuous, two-phase media. The motivation for this work stems from the need to understand blast venting consequences in the HYLIFE inertial confinement fusion (ICF) reactor. The HYLIFE concept utilizes lasers or heavy ion beams to rapidly heat and compress D-T targets injected into the center of a reactor chamber. A segmented blanket of falling molten lithium or Li{sub 2}BeF{sub 4} (Flibe) jets encircles the reactor`s central cavity, shielding the reactor structure from radiation damage, absorbing the fusion energy, and breeding more tritium fuel. X-rays from the fusion microexplosion will ablate a thin layer of blanket material from the surfaces which face toward the fusion site. This generates a highly energetic vapor, which mostly coalesces in the central cavity. The blast expansion from the central cavity generates a shock which propagates through the segmented blanket - a complex geometry, gas-continuous two-phase medium. The impulse that the blast gives to the liquid as it vents past, the gas shock on the chamber wall, and ultimately the liquid impact on the wall are all important quantities to the HYLIFE structural designers.

  2. Table 1. U.S. emissions of greenhouse gases, based on global warming potential,

    U.S. Energy Information Administration (EIA) Indexed Site

    emissions of greenhouse gases, based on global warming potential, 1990-2009" " (Million Metric Tons of Carbon Dioxide Equivalent)" " Greenhouse Gas",1990,1991,1992,1993,1994,1995,1996,1997,1998,1999,2000,2001,2002,2003,2004,2005,2006,2007,2008,2009 "Carbon

  3. Excitonic splitting and coherent electronic energy transfer in the gas-phase benzoic acid dimer

    SciTech Connect (OSTI)

    Ottiger, Philipp; Leutwyler, Samuel

    2012-11-28

    The benzoic acid dimer, (BZA){sub 2}, is a paradigmatic symmetric hydrogen bonded dimer with two strong antiparallel hydrogen bonds. The excitonic S{sub 1}/S{sub 2} state splitting and coherent electronic energy transfer within supersonically cooled (BZA){sub 2} and its {sup 13}C-, d{sub 1}-, d{sub 2}-, and {sup 13}C/d{sub 1}- isotopomers have been investigated by mass-resolved two-color resonant two-photon ionization spectroscopy. The (BZA){sub 2}-(h-h) and (BZA){sub 2}-(d-d) dimers are C{sub 2h} symmetric, hence only the S{sub 2} Leftwards-Arrow S{sub 0} transition can be observed, the S{sub 1} Leftwards-Arrow S{sub 0} transition being strictly electric-dipole forbidden. A single {sup 12}C/{sup 13}C or H/D isotopic substitution reduces the symmetry of the dimer to C{sub s}, so that the isotopic heterodimers (BZA){sub 2}-{sup 13}C, (BZA){sub 2}-(h-d), (BZA){sub 2}-(h{sup 13}C-d), and (BZA){sub 2}-(h-d{sup 13}C) show both S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} bands. The S{sub 1}/S{sub 2} exciton splitting inferred is {Delta}{sub exc}= 0.94 {+-} 0.1 cm{sup -1}. This is the smallest splitting observed so far for any H-bonded gas-phase dimer. Additional isotope-dependent contributions to the splittings, {Delta}{sub iso}, arise from the change of the zero-point vibrational energy upon electronic excitation and range from {Delta}{sub iso}= 3.3 cm{sup -1} upon {sup 12}C/{sup 13}C substitution to 14.8 cm{sup -1} for carboxy H/D substitution. The degree of excitonic localization/delocalization can be sensitively measured via the relative intensities of the S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} origin bands; near-complete localization is observed even for a single {sup 12}C/{sup 13}C substitution. The S{sub 1}/ S{sub 2} energy gap of (BZA){sub 2} is {Delta}{sub calc}{sup exc}=11 cm{sup -1} when calculated by the approximate second-order perturbation theory (CC2) method. Upon correction for vibronic

  4. ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; GREENHOUSES...

    Office of Scientific and Technical Information (OSTI)

    fuel-fired peak heating for geothermal greenhouses Rafferty, K. 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; GREENHOUSES; AUXILIARY HEATING; CAPITALIZED COST; OPERATING...

  5. Countryman Well Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Countryman Well Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Countryman Well Greenhouse Low Temperature Geothermal Facility Facility Countryman...

  6. Express Farms Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Express Farms Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Express Farms Greenhouse Low Temperature Geothermal Facility Facility Express Farms...

  7. Solving kinetic equations with adaptive mesh in phase space for rarefied gas dynamics and plasma physics (Invited)

    SciTech Connect (OSTI)

    Kolobov, Vladimir; Arslanbekov, Robert; Frolova, Anna

    2014-12-09

    The paper describes an Adaptive Mesh in Phase Space (AMPS) technique for solving kinetic equations with deterministic mesh-based methods. The AMPS technique allows automatic generation of adaptive Cartesian mesh in both physical and velocity spaces using a Tree-of-Trees data structure. We illustrate advantages of AMPS for simulations of rarefied gas dynamics and electron kinetics on low temperature plasmas. In particular, we consider formation of the velocity distribution functions in hypersonic flows, particle kinetics near oscillating boundaries, and electron kinetics in a radio-frequency sheath. AMPS provide substantial savings in computational cost and increased efficiency of the mesh-based kinetic solvers.

  8. Experimental and numerical investigation of shock wave propagation through complex geometry, gas continuous, two-phase media

    SciTech Connect (OSTI)

    Liu, J. Chien-Chih [California Univ., Berkeley, CA (United States)

    1993-10-01

    The work presented here investigates the phenomenon of shock wave propagation in gas continuous, two-phase media. The motivation for this work stems from the need to understand blast venting consequences in the HYLIFE inertial confinement fusion (ICF) reactor. The HYLIFE concept utilizes lasers or heavy ion beams to rapidly heat and compress D-T targets injected into the center of a reactor chamber. A segmented blanket of failing molten lithium or Li{sub 2}BeF{sub 4} (Flibe) jets encircles the reactors central cavity, shielding the reactor structure from radiation damage, absorbing the fusion energy, and breeding more tritium fuel.

  9. (Limiting the greenhouse effect)

    SciTech Connect (OSTI)

    Rayner, S.

    1991-01-07

    Traveler attended the Dahlem Research Conference organized by the Freien Universitat, Berlin. The subject of the conference was Limiting the Greenhouse Effect: Options for Controlling Atmospheric CO{sub 2} Accumulation. Like all Dahlem workshops, this was a meeting of scientific experts, although the disciplines represented were broader than usual, ranging across anthropology, economics, international relations, forestry, engineering, and atmospheric chemistry. Participation by scientists from developing countries was limited. The conference was divided into four multidisciplinary working groups. Traveler acted as moderator for Group 3 which examined the question What knowledge is required to tackle the principal social and institutional barriers to reducing CO{sub 2} emissions'' The working rapporteur was Jesse Ausubel of Rockefeller University. Other working groups examined the economic costs, benefits, and technical feasibility of options to reduce emissions per unit of energy service; the options for reducing energy use per unit of GNP; and the significant of linkage between strategies to reduce CO{sub 2} emissions and other goals. Draft reports of the working groups are appended. Overall, the conference identified a number of important research needs in all four areas. It may prove particularly important in bringing the social and institutional research needs relevant to climate change closer to the forefront of the scientific and policy communities than hitherto.

  10. Natural gas powered rotary water chiller development. Phase 1. Final report, September 1991-June 1993

    SciTech Connect (OSTI)

    Sanborn, D.F.; Lakowske, R.L.; Byars, M.

    1993-06-01

    Objectives of the project were to evaluate performance and marketability of a rotary engine driven screw compressor for water chiller applications. Choice of a rotary engine was aimed at rotary compressor. Initial testing done with modified stock 13B rotary engine and experimental open compressor. Engine torque not sufficient for 70 ton compressor. Analysis concluded 50 ton best match for air cooled applications and 60 ton best for water cooled to get highest gas COP. Market analysis covered total water chiller market assuming relative costs of power would lead to gas cooling sales. Allowable cost premium for 3 yr payback determined for areas of country. Premium cost of 100 ton air cooled unit estimated and compared to market allowable premiums. Concluded product acceptance will be primarily in niche markets with high local electric power demand charges.

  11. Modeling Gas-Phase Transport in Polymer-Electrolyte FuelCells

    SciTech Connect (OSTI)

    Weber, A.Z.; Newman, J.

    2006-08-17

    In this transaction, the equations and methodology for modeling convection and ordinary, Knudsen, and pressure diffusion of gases in a fuel-cell gas-diffusion layer are described. Some results examining the magnitudes of the various terms are also made. This derivation results in a self-consistent description of the various transport mechanisms and is robust for numerical solutions, especially for conditions involving different flow regimes or where the regime is not known a priori.

  12. Engineering research on positive displacement gas expanders. Phase I technical report

    SciTech Connect (OSTI)

    Lord, R. E.

    1984-02-01

    A research, design, and development program related to positive displacement gas expanders is reported. The objective of this program is to develop and demonstrate a more cost effective gas expander for use in those waste heat recovery systems which utilize an Organic Rankine Cycle. To provide a lower cost machine, the gas expander uses a positive displacement concept, rather than a turbine as currently used. Several positive displacement machine concepts were examined, and various performance measures have been developed for each of the concepts. The machine concepts were: single and multiple cylinder reciprocators, radial piston, roller piston, sliding vane, trochoidal, helical screw, and lobed rotor. For each of the concepts, designs were generated for machines operating with three different sets of operating conditions. These designs were then used to develop measures of efficiency and cost, and to examine other characteristics of the machines, such as development risk and ability to operate with different flow, pressure, and temperature levels. Based upon an evaluation of these characteristics, a specific concept was selected for further development. This concept is a double acting, single cylinder reciprocating machine with crossheads and ceramic liners.

  13. Gas-phase decontamination demonstration on PORTS cell X-25-4-2. Final technology status report

    SciTech Connect (OSTI)

    Riddle, R.J.

    1997-09-01

    The Long-Term, Low Temperature (LTLT) process is a gas-phase in situ decontamination technique which has been tested by LMES/K-25 personnel on the laboratory scale with promising results. The purpose of the Gas-Phase Decontamination Demonstration at PORTS was to evaluate the LTLT process on an actual diffusion cascade cell at conditions similar to those used in the laboratory testing. The demonstration was conducted on PORTS diffusion cell X-25-4-2 which was one of the X-326 Building cells which was permanently shutdown as part of the Suspension of HEU Production at PORTS. The demonstration full-scale test consisted of rendering the cell leak-tight through the installation of Dresser seals onto the process seals, exposing the cell to the oxidants ClF{sub 3} and F{sub 2} for a period of 105 days and evaluating the effect of the clean-up treatment on cell samples and coupons representing the major diffusion cascade materials of construction. The results were extrapolated to determine the effectiveness of LTLT decontamination over the range of historical uranium isotope assays present in the diffusion complex. It was determined that acceptable surface contamination levels could be obtained in all of the equipment in the lower assay cascades which represents the bulk of the equipment contained in the diffusion complex.

  14. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  15. Phase-Contrast MRI and CFD Modeling of Apparent 3He Gas Flow in Rat Pulmonary Airways

    SciTech Connect (OSTI)

    Minard, Kevin R.; Kuprat, Andrew P.; Kabilan, Senthil; Jacob, Rick E.; Einstein, Daniel R.; Carson, James P.; Corley, Richard A.

    2012-08-01

    Phase-contrast (PC) magnetic resonance imaging (MRI) with hyperpolarized 3He is potentially useful for developing and testing patient-specific models of pulmonary airflow. One challenge, however, is that PC-MRI provides apparent values of local 3He velocity that not only depend on actual airflow but also on gas diffusion. This not only blurs laminar flow patterns in narrow airways but also introduces anomalous airflow structure that reflects gas-wall interactions. Here, both effects are predicted in a live rat using computational fluid dynamics (CFD), and for the first time, simulated patterns of apparent 3He gas velocity are compared with in-vivo PC-MRI. Results show (1) that correlations (R2) between measured and simulated airflow patterns increase from 0.23 to 0.79 simply by accounting for apparent 3He transport, and that (2) remaining differences are mainly due to uncertain airway segmentation and partial volume effects stemming from relatively coarse MRI resolution. Higher-fidelity testing of pulmonary airflow predictions should therefore be possible with future imaging improvements.

  16. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil fuels used in power production.The United States is endowed with an abundance of natural gas resources, so increasing use of natural gas power can help strengthen domestic energy security. NETL research efforts enhance technologies that reduce the cost, increase the efficiency, and reduce the environmental risk of

  17. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A. |

    1993-11-01

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  18. CASCADER: An m-chain gas-phase radionuclide transport and fate model. Volume 2, User`s manual for CASCADR8

    SciTech Connect (OSTI)

    Cawlfield, D.E.; Been, K.B.; Emer, D.F.; Lindstrom, F.T.; Shott, G.J.

    1993-06-01

    Chemicals and radionuclides move either in the gas-phase, liquid-phase, or both phases in soils. They may be acted upon by either biological or abiotic processes through advection and/or diffusion. Furthermore, parent and daughter radionuclides may decay as they are transported in the soil. This is volume two to the CASCADER series, titled CASCADR8. It embodies the concepts presented in volume one of this series. To properly understand how the CASCADR8 model works, the reader should read volume one first. This volume presents the input and output file structure for CASCADR8, and a set of realistic scenarios for buried sources of radon gas.

  19. Significant Increase in Hydrogen Photoproduction Rates and Yields by Wild-Type Algae is Detected at High Photobioreactor Gas Phase Volume (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-07-01

    This NREL Hydrogen and Fuel Cell Technical Highlight describes how hydrogen photoproduction activity in algal cultures can be improved dramatically by increasing the gas-phase to liquid-phase volume ratio of the photobioreactor. NREL, in partnership with subcontractors from the Institute of Basic Biological Problems in Pushchino, Russia, demonstrated that the hydrogen photoproduction rate in algal cultures always decreases exponentially with increasing hydrogen partial pressure above the culture. The inhibitory effect of high hydrogen concentrations in the photobioreactor gas phase on hydrogen photoproduction by algae is significant and comparable to the effect observed with some anaerobic bacteria.

  20. Development of a direct-injected natural gas engine system for heavy-duty vehicles: Final report phase 1

    SciTech Connect (OSTI)

    2000-03-02

    The transportation sector accounts for approximately 65% of US petroleum consumption. Consumption for light-duty vehicles has stabilized in the last 10--15 years; however, consumption in the heavy-duty sector has continued to increase. For various reasons, the US must reduce its dependence on petroleum. One significant way is to substitute alternative fuels (natural gas, propane, alcohols, and others) in place of petroleum fuels in heavy-duty applications. Most alternative fuels have the additional benefit of reduced exhaust emissions relative to petroleum fuels, thus providing a cleaner environment. The best long-term technology for heavy-duty alternative fuel engines is the 4-stroke cycle, direct injected (DI) engine using a single fuel. This DI, single fuel approach maximizes the substitution of alternative fuel for diesel and retains the thermal efficiency and power density of the diesel engine. This report summarizes the results of the first year (Phase 1) of this contract. Phase 1 focused on developing a 4-stroke cycle, DI single fuel, alternative fuel technology that will duplicate or exceed diesel power density and thermal efficiency, while having exhaust emissions equal to or less than the diesel. Although the work is currently on a 3500 Series DING engine, the work is viewed as a basic technology development that can be applied to any engine. Phase 1 concentrated on DING engine component durability, exhaust emissions, and fuel handling system durability. Task 1 focused on identifying primary areas (e.g., ignition assist and gas injector systems) for future durability testing. In Task 2, eight mode-cycle-averaged NO{sub x} emissions were reduced from 11.8 gm/hp-hr (baseline conditions) to 2.5 gm/hp-hr (modified conditions) on a 3501 DING engine. In Task 3, a state-of-the-art fuel handling system was identified.

  1. Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

    DOE Patents [OSTI]

    Mahajan, Devinder

    2005-07-26

    The invention provides a homogenous catalyst for the production of methanol from purified synthesis gas at low temperature and low pressure which includes a transition metal capable of forming transition metal complexes with coordinating ligands and an alkoxide, the catalyst dissolved in a methanol solvent system, provided the transition metal complex is not transition metal carbonyl. The coordinating ligands can be selected from the group consisting of N-donor ligands, P-donor ligands, O-donor ligands, C-donor ligands, halogens and mixtures thereof.

  2. Method and apparatus for the gas phase decontamination of chemical and biological agents

    DOE Patents [OSTI]

    O'Neill, Hugh J.; Brubaker, Kenneth L.

    2003-10-07

    An apparatus and method for decontaminating chemical and biological agents using the reactive properties of both the single atomic oxygen and the hydroxyl radical for the decontamination of chemical and biological agents. The apparatus is self contained and portable and allows for the application of gas reactants directly at the required decontamination point. The system provides for the use of ultraviolet light of a specific spectral range to photolytically break down ozone into molecular oxygen and hydroxyl radicals where some of the molecular oxygen is in the first excited state. The excited molecular oxygen will combine with water vapor to produce two hydroxyl radicals.

  3. Low-Level waste phase 1 melter testing off gas and mass balance evaluation

    SciTech Connect (OSTI)

    Wilson, C.N.

    1996-06-28

    Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of Hanford Site tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor demonstration tests.

  4. DESIGN AND DEVELOPMENT OF GAS-LIQUID CYLINDRICAL CYCLONE COMPACT SEPARATORS FOR THREE-PHASE FLOW

    SciTech Connect (OSTI)

    Dr. Ram S. Mohan; Dr. Ovadia Shoham

    2001-10-30

    This report presents a brief overview of the activities and tasks accomplished during the second half year (April 1, 2001-September 30, 2001) of the fourth project year budget period (October 1, 2000-September 30, 2001). An executive summary is presented initially followed by the tasks of the current budget period. Then, detailed description of the experimental and modeling investigations are presented. Subsequently, the technical and scientific results of the activities of this project period are presented with some discussions. The findings of this investigation are summarized in the ''Conclusions'' section followed by relevant references. The fourth project year activities are divided into three main parts, which are carried out in parallel. The first part is continuation of the experimental program that includes a study of the oil/water two-phase behavior at high pressures and control system development for the three-phase GLCC{copyright}. This investigation will be eventually extended for three-phase flow. The second part consists of the development of a simplified mechanistic model incorporating the experimental results and behavior of dispersion of oil in water and water in oil. This will provide an insight into the hydrodynamic flow behavior and serve as the design tool for the industry. Although useful for sizing GLCC{copyright} for proven applications, the mechanistic model will not provide detailed hydrodynamic flow behavior information needed to screen new geometric variations or to study the effect of fluid property variations. Therefore, in the third part, the more rigorous approach of computational fluid dynamics (CFD) will be utilized. Multidimensional multiphase flow simulation at high pressures and for real crude conditions will provide much greater depth into the understanding of the physical phenomena and the mathematical analysis of three-phase GLCC{copyright} design and performance.

  5. DESIGN AND DEVELOPMENT OF GAS-LIQUID CYLINDRICAL CYCLONE COMPACT SEPARATORS FOR THREE-PHASE FLOW

    SciTech Connect (OSTI)

    Dr. Ram S. Mohan; Dr. Ovadia Shoham

    2001-04-30

    This report presents a brief overview of the activities and tasks accomplished during the first half year (October 1, 2000-March 31, 2001) of the fourth project year budget period (October 1, 2000-September 30, 2001). An executive summary is presented initially followed by the tasks of the current budget period. Then, detailed description of the experimental and modeling investigations are presented. Subsequently, the technical and scientific results of the activities of this project period are presented with some discussions. The findings of this investigation are summarized in the ''Conclusions'' section followed by relevant references. The fourth project year activities are divided into three main parts, which are carried out in parallel. The first part is continuation of the experimental program that includes a study of the oil/water two-phase behavior at high pressures and control system development for the three-phase GLCC{copyright}. This investigation will be eventually extended for three-phase flow. The second part consists of the development of a simplified mechanistic model incorporating the experimental results and behavior of dispersion of oil in water and water in oil. This will provide an insight into the hydrodynamic flow behavior and serve as the design tool for the industry. Although useful for sizing GLCC{copyright} for proven applications, the mechanistic model will not provide detailed hydrodynamic flow behavior information needed to screen new geometric variations or to study the effect of fluid property variations. Therefore, in the third part, the more rigorous approach of computational fluid dynamics (CFD) will be utilized. Multidimensional multiphase flow simulation at high pressures and for real crude conditions will provide much greater depth into the understanding of the physical phenomena and the mathematical analysis of three-phase GLCC{copyright} design and performance.

  6. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst

    SciTech Connect (OSTI)

    Yates, I.C.; Satterfield, C.N.

    1988-01-01

    A cobalt Fischer-Tropsch catalyst (CO/MgO/silica) was reduced and slurried in combination with reduced Cu/ZnO/Al[sub 2]0[sub 3] water-gas-shift catalyst. Combined catalyst system was run at fixed process conditions for more than 400 hours. The system showed stable selectivity. The Cu/ZnO/Al[sub 2]0[sub 3] water-gas-shift catalyst remained reasonably active in the presence of the cobalt catalyst. Hydrocarbon selectivity of the cobalt and Cu/ZnO/Al[sub 2]0[sub 3] catalyst system compared favorably to selectivity of iron-based catalysts. Methane selectivity was slightly higher for the cobalt-based system, but C[sub 5][sup +] selectivity was essentially the same. The hydrocarbon product distribution appeared to exhibit a double-a behavior. a[sub 1] was near 0.80 which is higher than that of iron catalysts, while a[sub 2] was calculated to be 0.86 which is somewhat lower than would be typical for an iron-based catalyst.

  7. Gas-Phase Treatment of Technetium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Qafoku, Nikolla

    2014-09-01

    Technetium-99 (Tc-99) is present in the vadose zone of the Hanford Central Plateau and is a concern with respect to the protection of groundwater. The persistence, limited natural attenuation mechanisms, and geochemical behavior of Tc-99 in oxic vadose zone environments must be considered in developing effective alternatives for remediation. This report describes a new in situ geochemical manipulation technique for decreasing Tc-99 mobility using a combination of geochemical Tc-99 reduction with hydrogen sulfide gas and induced sediment mineral dissolution with ammonia vapor, which create conditions for deposition of stable precipitates that decrease the mobility of Tc-99. Laboratory experiments were conducted to examine changes in Tc-99 mobility in vadose zone sediment samples to evaluate the effectiveness of the treatment under a variety of operational and sediment conditions.

  8. Two-beam ultrabroadband coherent anti-Stokes Raman spectroscopy for high resolution gas-phase multiplex imaging

    SciTech Connect (OSTI)

    Bohlin, Alexis; Kliewer, Christopher J.

    2014-01-20

    We propose and develop a method for wideband coherent anti-Stokes Raman spectroscopy (CARS) in the gas phase and demonstrate the single-shot measurement of N{sub 2}, H{sub 2}, CO{sub 2}, O{sub 2}, and CH{sub 4}. Pure-rotational and vibrational O-, Q-, and S- branch spectra are collected simultaneously, with high spectral and spatial resolution, and within a single-laser-shot. The relative intensity of the rotational and vibrational signals can be tuned arbitrarily using polarization techniques. The ultrashort 7 fs pump and Stokes pulses are automatically overlapped temporally and spatially using a two-beam CARS technique, and the crossed probe beam allows for excellent spatial sectioning of the probed location.

  9. Gas-phase reactions of polycyclic aromatic hydrocarbon cations and their nitrogen-containing analogs with H atoms

    SciTech Connect (OSTI)

    Demarais, Nicholas J.; Yang, Zhibo; Bierbaum, Veronica M. [Department of Chemistry and Biochemistry, 215 UCB, University of Colorado, Boulder, CO 80309-0215 (United States); Snow, Theodore P., E-mail: Nicholas.Demarais@Colorado.edu, E-mail: Zhibo.Yang@ou.edu, E-mail: Veronica.Bierbaum@Colorado.edu, E-mail: Theodore.Snow@Colorado.edu [Center for Astrophysics and Space Astronomy, 389 UCB, University of Colorado, Boulder, CO 80309-0389 (United States)

    2014-03-20

    We have studied the reactions of polycyclic aromatic hydrocarbon cations and their nitrogen-containing analogs with H atoms. Reaction rate constants are measured at 300 K using a flowing afterglow-selected ion flow tube. We have implemented the laser induced acoustic desorption technique to allow the study of large, non-volatile species in the gas phase. The extension of this work from previous studies shows that the reactivity of polycyclic aromatic hydrocarbon cations with H atoms reaches a constant value for large cations. There is a small difference in reactivity when comparing molecules of different size and geometry; however, no difference in reactivity was found when nitrogen was incorporated into the ring.

  10. Gas phase C{sub 2}-C{sub 10} organic acids concentrations in the Los Angeles atmosphere

    SciTech Connect (OSTI)

    Nolte, C.G.; Fraser, M.P.; Cass, G.R.

    1999-02-15

    The atmospheric concentrations of gas-phase C{sub 2}--C{sub 10} monocarboxylic and benzoic acids are reported in samples collected during a severe Los Angeles area photochemical smog episode. Average urban concentrations are 10--50 {times} greater than concentrations observed at a remote background location, indicating an anthropogenic origin for these compounds. Average urban concentrations during the episode were 16.1 {micro}g m{sup {minus}3} (6.6 ppb) for acetic acid and 1.67 {micro}g m{sup {minus}3} (0.55 ppb) for propionic acid, with progressively lesser amounts as the carbon chain length of the acids is increased. Spatial and diurnal variations in atmospheric organic acids concentrations point to the importance of both direct emissions from primary sources and formation by photochemical reaction of precursor compounds.

  11. HYDROGEN GREENHOUSE PLANETS BEYOND THE HABITABLE ZONE

    SciTech Connect (OSTI)

    Pierrehumbert, Raymond; Gaidos, Eric E-mail: gaidos@hawaii.edu

    2011-06-10

    We show that collision-induced absorption allows molecular hydrogen to act as an incondensible greenhouse gas and that bars or tens of bars of primordial H{sub 2}-He mixtures can maintain surface temperatures above the freezing point of water well beyond the 'classical' habitable zone defined for CO{sub 2} greenhouse atmospheres. Using a one-dimensional radiative-convective model, we find that 40 bars of pure H{sub 2} on a three Earth-mass planet can maintain a surface temperature of 280 K out to 1.5 AU from an early-type M dwarf star and 10 AU from a G-type star. Neglecting the effects of clouds and of gaseous absorbers besides H{sub 2}, the flux at the surface would be sufficient for photosynthesis by cyanobacteria (in the G star case) or anoxygenic phototrophs (in the M star case). We argue that primordial atmospheres of one to several hundred bars of H{sub 2}-He are possible and use a model of hydrogen escape to show that such atmospheres are likely to persist further than 1.5 AU from M stars, and 2 AU from G stars, assuming these planets have protecting magnetic fields. We predict that the microlensing planet OGLE-05-390Lb could have retained an H{sub 2}-He atmosphere and be habitable at {approx}2.6 AU from its host M star.

  12. The Effects of Oxy-firing Conditions on Gas-phase Mercury Oxidation by Chlorine and Bromine

    SciTech Connect (OSTI)

    Buitrago, Paula; Silcox, Geoffrey

    2010-06-30

    Bench-scale experiments were conducted in a quartz-lined, natural gas-fired reactor with the combustion air replaced with a blend of 27 mole percent oxygen, with the balance carbon dioxide. Quench rates of 210 and 440 K/s were tested. In the absence of sulfur dioxide, the oxy-firing environment caused a remarkable increase in oxidation of mercury by chlorine. At 400 ppm chlorine (as HCl equivalent), air-firing results in roughly 5 percent oxidation. At the same conditions with oxy-firing, oxidation levels are roughly 80 percent. Oxidation levels with bromine at 25 and 50 ppm (as HBr equivalent) ranged from 80 to 95 percent and were roughly the same for oxy- and air-firing conditions. Kinetic calculations of levels of oxidation at air- and oxy-conditions captured the essential features of the experimental results but have not revealed a mechanistic basis for the oxidative benefits of oxy-firing conditions. Mixtures of 25 ppm bromine and 100 and 400 ppm chlorine gave more than 90 percent oxidation. At all conditions, the effects of quench rate were not significant. The presence of 500 ppm SO2 caused a dramatic decline in the levels of oxidation at all oxy-fired conditions examined. This effect suggests that SO2 may be preventing oxidation in the gas phase or preventing oxidation in the wetconditioning system that was used in quantifying oxidized and elemental mercury concentrations. Similar effects of SO2 have been noted with air-firing. The addition of sodium thiosulfate to the hydroxide impingers that are part of wet conditioning systems may prevent liquid-phase oxidation from occurring.

  13. Apparatus and method for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

    2010-05-11

    A dilution apparatus for diluting a gas sample. The apparatus includes a sample gas conduit having a sample gas inlet end and a diluted sample gas outlet end, and a sample gas flow restricting orifice disposed proximate the sample gas inlet end connected with the sample gas conduit and providing fluid communication between the exterior and the interior of the sample gas conduit. A diluted sample gas conduit is provided within the sample gas conduit having a mixing end with a mixing space inlet opening disposed proximate the sample gas inlet end, thereby forming an annular space between the sample gas conduit and the diluted sample gas conduit. The mixing end of the diluted sample gas conduit is disposed at a distance from the sample gas flow restricting orifice. A dilution gas source connected with the sample gas inlet end of the sample gas conduit is provided for introducing a dilution gas into the annular space, and a filter is provided for filtering the sample gas. The apparatus is particularly suited for diluting heated sample gases containing one or more condensable components.

  14. An atmospheric pressure high-temperature laminar flow reactor for investigation of combustion and related gas phase reaction systems

    SciTech Connect (OSTI)

    Oßwald, Patrick; Köhler, Markus

    2015-10-15

    A new high-temperature flow reactor experiment utilizing the powerful molecular beam mass spectrometry (MBMS) technique for detailed observation of gas phase kinetics in reacting flows is presented. The reactor design provides a consequent extension of the experimental portfolio of validation experiments for combustion reaction kinetics. Temperatures up to 1800 K are applicable by three individually controlled temperature zones with this atmospheric pressure flow reactor. Detailed speciation data are obtained using the sensitive MBMS technique, providing in situ access to almost all chemical species involved in the combustion process, including highly reactive species such as radicals. Strategies for quantifying the experimental data are presented alongside a careful analysis of the characterization of the experimental boundary conditions to enable precise numeric reproduction of the experimental results. The general capabilities of this new analytical tool for the investigation of reacting flows are demonstrated for a selected range of conditions, fuels, and applications. A detailed dataset for the well-known gaseous fuels, methane and ethylene, is provided and used to verify the experimental approach. Furthermore, application for liquid fuels and fuel components important for technical combustors like gas turbines and engines is demonstrated. Besides the detailed investigation of novel fuels and fuel components, the wide range of operation conditions gives access to extended combustion topics, such as super rich conditions at high temperature important for gasification processes, or the peroxy chemistry governing the low temperature oxidation regime. These demonstrations are accompanied by a first kinetic modeling approach, examining the opportunities for model validation purposes.

  15. Application of gas-liquid two-phase cross-flow filtration to pilot-scale methane fermentation

    SciTech Connect (OSTI)

    Imasaka, Takuo; So, Hiroyuki; Matsushita, Kohnosuke; Furukawa, Tomoya; Kanekuni, Nobuhiko )

    1993-01-01

    As part of a national project, Aqua-Renaissance '90,' by the MITI, a pilot-scale evaluation of membrane-enhanced anaerobic fermentation, has progressed for the wastewater from a pulp and paper mill. A novel membrane filtration system was newly proposed with the aim of saving energy. That is, a gas-liquid two-phase cross-flow filtration which was generated with liquid circulation by an air-lift pump effect, was combined in the anaerobic bioreactor. It was confirmed that the membrane filtration not only offered very stable and large permeate flux, but enhanced the processing efficiency by retaining the microorganisms in the bioreactor. Furthermore, the power consumption per unit permeate volume in the membrane system of 1.78 kWh/m[sup 3] was achieved, which was a very high-performance result from the viewpoint of saving energy, as compared with 3-5 kWh/m[sup 3] of conventional liquid single-phase cross-flow filtration.

  16. Genesis of a three-phase subsea metering system. [Oil and gas metering systems for subsea operations

    SciTech Connect (OSTI)

    Dowty, E.L.; Hatton, G.J.; Durrett, M.G. ); Dean, T.L.; Jiskoot, R.J.J.

    1993-08-01

    Periodic well flow testing is necessary to monitor well and reservoir performance over time to optimize decisions on well production rates and new well requirements through improved reservoir models, to determine the timing of well workovers, and to identify when wells become uneconomical to produce. A dedicated test separator' conventionally is used to meter individual wells. Fluids from a well are separated into the three component phases (oil, gas, and water) in a large vessel, and the flow rate of each phase is measured on the respective outlet lines from the vessel. The same method currently is used for subsea satellite developments by providing a dedicated test pipeline' from the subsea field to carry a selected well's production to a test separator for metering on the host platform. The capital cost of these systems rises rapidly with distance. Greater distances between the wellhead and flow test system increase the cost of the test pipeline and require larger and hence more expensive slug catchers and risers. Clearly, a subsea-based well-test system could result in large capital cost savings by eliminating the need for conventional test systems. This paper tracks the development of one subsea well test system from conception to field testing on the Tartan. A platform in the North Sea. This work defines the design requirements of the system, reviews system development and fabrication, describes modifications made as a result of initial field tests, and reports the results of topside tests completed through Dec. 1990.

  17. ARM - Methane Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Gas Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Methane Gas Methane gas is another naturally occurring greenhouse gas. It is produced as a result of microbial activity in the absence of oxygen. Pre-industrial concentrations of methane were about 700 ppb and in 1994 they were up

  18. Microhydrated dihydrogen phosphate clusters probed by gas phase vibrational spectroscopy and first principles calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Shou -Tian; Jiang, Ling; Liu, J. W.; Heine, Nadja; Yacovitch, Tara I.; Wende, Torsten; Asmis, Knut R.; Neumark, Daniel M.; Liu, Zhi -Feng

    2015-06-05

    We report infrared multiple photon dissociation (IRMPD) spectra of cryogenically-cooled H2PO4-(H2O)n anions (n = 2–12) in the spectral range of the stretching and bending modes of the solute anion (600–1800 cm-1). The spectra cannot be fully understood using the standard technique of comparison to harmonic spectra of minimum-energy structures; a satisfactory assignment requires considering anharmonic effects as well as entropy-driven hydrogen bond network fluctuations. Aided by finite temperature ab initio molecular dynamics simulations, the observed changes in the position, width and intensity of the IRMPD bands with cluster size are related to the sequence of microsolvation. Due to stronger hydrogenmore » bonding to the two terminal P=O groups, these are hydrated before the two P–OH groups. By n = 6, all four end groups are involved in the hydrogen bond network and by n = 12, the cluster spectra show similarities to the condensed phase spectrum of H2PO4-(aq). Our results reveal some of the microscopic details concerning the formation of the aqueous solvation environment around H2PO4-, provide ample testing grounds for the design of model solvation potentials for this biologically relevant anion, and support a new paradigm for the interpretation of IRMPD spectra of microhydrated ions.« less

  19. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-08-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and is scheduled to be complete by the end of August 2003. The current project status and preliminary monitoring results are summarized in this report.

  20. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-05-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Construction is complete on the 3.5-acre anaerobic cell and liquid addition has commenced. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and construction of the west-side 6-acre anaerobic cell is nearly complete with only the liquid addition system remaining. The current project status and preliminary monitoring results are summarized in this report.

  1. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-12-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The remaining task to be completed is to test the biofilter prior to operation, which is currently anticipated to begin in January 2004. The current project status and preliminary monitoring results are summarized in this report.

  2. Full Scale Bioreactor Landfill for Carbon Sequestration and Greenhouse Emission Control

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Kathy Sananikone; Don Augenstein

    2005-03-30

    The Yolo County Department of Planning and Public Works constructed a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective was to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entailed the construction of a 12-acre module that contained a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells were highly instrumented to monitor bioreactor performance. Liquid addition commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The current project status and preliminary monitoring results are summarized in this report.

  3. EPA's Recent Advance Notice on Greenhouse Gases | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EPA's Recent Advance Notice on Greenhouse Gases EPA's Recent Advance Notice on Greenhouse Gases Summary EPA's advanced notice of proposed rulemaking on mobile sources of greenhouse ...

  4. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as ...

  5. EIA-Voluntary Reporting of Greenhouse Gases Program

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program Voluntary Reporting of Greenhouse Gases Program ***THE VOLUNTARY REPORTING OF GREENHOUSE GASES ("1605(b)") PROGRAM HAS BEEN SUSPENDED.*** This affects ...

  6. Microhydrated dihydrogen phosphate clusters probed by gas phase vibrational spectroscopy and first principles calculations

    SciTech Connect (OSTI)

    Sun, Shou -Tian; Jiang, Ling; Liu, J. W.; Heine, Nadja; Yacovitch, Tara I.; Wende, Torsten; Asmis, Knut R.; Neumark, Daniel M.; Liu, Zhi -Feng

    2015-06-05

    We report infrared multiple photon dissociation (IRMPD) spectra of cryogenically-cooled H2PO4-(H2O)n anions (n = 2–12) in the spectral range of the stretching and bending modes of the solute anion (600–1800 cm-1). The spectra cannot be fully understood using the standard technique of comparison to harmonic spectra of minimum-energy structures; a satisfactory assignment requires considering anharmonic effects as well as entropy-driven hydrogen bond network fluctuations. Aided by finite temperature ab initio molecular dynamics simulations, the observed changes in the position, width and intensity of the IRMPD bands with cluster size are related to the sequence of microsolvation. Due to stronger hydrogen bonding to the two terminal P=O groups, these are hydrated before the two P–OH groups. By n = 6, all four end groups are involved in the hydrogen bond network and by n = 12, the cluster spectra show similarities to the condensed phase spectrum of H2PO4-(aq). Our results reveal some of the microscopic details concerning the formation of the aqueous solvation environment around H2PO4-, provide ample testing grounds for the design of model solvation potentials for this biologically relevant anion, and support a new paradigm for the interpretation of IRMPD spectra of microhydrated ions.

  7. Natural Gas: Lifting Mileage Higher and Higher

    Broader source: Energy.gov [DOE]

    A new Energy Department brochure compares the energy efficiency, greenhouse gas emissions and ranges of the three proposed natural gas passenger vehicle configurations using analysis by Argonne National Laboratory.

  8. Building and using the solar greenhouse

    SciTech Connect (OSTI)

    1983-01-01

    Thorough directions are given for planning, constructing and using a solar greenhouse attached to a house. Included is a method of calculating the savings accruing from the use of the greenhouse. (LEW)

  9. Potential for Microbial Stimulation in Deep Vadose Zone Sediments by Gas-Phase Nutrients

    SciTech Connect (OSTI)

    Li, S.W.; Plymale, A. E.; Brockman, F.J.

    2006-04-05

    Viable microbial populations are low, typically 10{sup 4} cells per gram, in deep vadose zones in arid climates. There is evidence that microbial distribution in these environments is patchy. In addition, infiltration or injection of nutrient-laden water has the potential to spread and drive contaminants downward to the saturated zone. For these reasons, there are uncertainties regarding the feasibility of bioremediation of recalcitrant contaminants in deep vadose zones. The objectives of this study were to investigate the occurrence of denitrifying activity and gaseous carbon-utilizing activity in arid-climate deep vadose zone sediments contaminated with, and/or affected by past exposure to, carbon tetrachloride (CT). These metabolisms are known to degrade CT and/or its breakdown product chloroform under anoxic conditions. A second objective was to determine if CT would be degraded in these sediments under unsaturated, bulk-phase aerobic incubation conditions. Both denitrifier population (determined by MPN) and microbial heterotrophic activity (measured by mineralization of 14-C labeled glucose and acetate) were relatively low and the sediments with greater in situ moisture (10-21% versus 2-7%) tended to have higher activities. When sediments were amended with gaseous nutrients (nitrous oxide and triethyl/tributyl phosphate) and gaseous C sources (a mixture of methane, ethane, propylene, propane, and butane) and incubated for 6 months, approximately 50% of the samples showed removal of one or more gaseous C sources, with butane most commonly used (44% of samples), followed by propylene (42%), propane (31%), ethane (22%), and methane (4%). Gaseous N and gaseous P did not stimulate removal of gaseous C substrates compared to no addition of N and P. CT and gaseous C sources were spiked into the sediments that removed gaseous C sources to determine if hydrocarbon-degraders have the potential to degrade CT under unsaturated conditions. In summary, gaseous C sources

  10. Natural Gas Infrastructure Modernization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Infrastructure Modernization Natural Gas Infrastructure Modernization A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. In order to help modernize the nation's natural gas

  11. EIA's Energy in Brief: What are greenhouse gases and how much are emitted

    Gasoline and Diesel Fuel Update (EIA)

    by the United States? greenhouse gases and how much are emitted by the United States? Last Updated: January 20, 2016 Greenhouse gases trap heat from the sun and warm the planet's surface. Most U.S. greenhouse gas emissions are related to energy production and consumption. Most of those emissions are carbon dioxide (CO2) from the burning of fossil fuels. From 1990 to 2014, energy-related carbon dioxide emissions in the United States increased on average by about 0.3% per year. Because

  12. The gas phase emitter effect of lanthanum within ceramic metal halide lamps and its dependence on the La vapor pressure and operating frequency

    SciTech Connect (OSTI)

    Ruhrmann, C.; Hoebing, T.; Bergner, A.; Groeger, S.; Awakowicz, P.; Mentel, J.; Denissen, C.; Suijker, J.

    2015-08-07

    The gas phase emitter effect increases the lamp lifetime by lowering the work function and, with it, the temperature of the tungsten electrodes of metal halide lamps especially for lamps in ceramic vessels due to their high rare earth pressures. It is generated by a monolayer on the electrode surface of electropositive atoms of certain emitter elements, which are inserted into the lamp bulb by metal iodide salts. They are vaporized, dissociated, ionized, and deposited by an emitter ion current onto the electrode surface within the cathodic phase of lamp operation with a switched-dc or ac-current. The gas phase emitter effect of La and the influence of Na on the emitter effect of La are studied by spatially and phase-resolved pyrometric measurements of the electrode tip temperature, La atom, and ion densities by optical emission spectroscopy as well as optical broadband absorption spectroscopy and arc attachment images by short time photography. An addition of Na to the lamp filling increases the La vapor pressure within the lamp considerably, resulting in an improved gas phase emitter effect of La. Furthermore, the La vapor pressure is raised by a heating of the cold spot. In this way, conditions depending on the La vapor pressure and operating frequency are identified, at which the temperature of the electrodes becomes a minimum.

  13. Implementation and evaluation of online gas-phase chemistry within a regional climate model (RegCM-CHEM4)

    SciTech Connect (OSTI)

    Shalaby, A. K.; Zakey, A. S.; Tawfik, A. B.; Solmon, F.; Giorgi, Filippo; Stordal, F.; Sillman, S.; Zaveri, Rahul A.; Steiner, A. L.

    2012-05-22

    The RegCM-CHEM4 is a new online climate-chemistry model based on the International Centre for Theoretical Physics (ICTP) regional climate model (RegCM4). Tropospheric gas-phase chemistry is integrated into the climate model using the condensed version of the Carbon Bond Mechanism (CBM-Z; Zaveri and Peters, 1999) with a fast solver based on radical balances. We evaluate the model over Continental Europe for two different time scales: (1) an event-based analysis of the ozone episode associated with the heat wave of August 2003 and (2) a climatological analysis of a sixyear simulation (2000-2005). For the episode analysis, model simulations show good agreement with European Monitoring and Evaluation Program (EMEP) observations of hourly ozone over different regions in Europe and capture ozone concentrations during and after the August 2003 heat wave event. For long-term climate simulations, the model captures the seasonal cycle of ozone concentrations with some over prediction of ozone concentrations in non-heat wave summers. Overall, the ozone and ozone precursor evaluation shows the feasibility of using RegCM-CHEM4 for decadal-length simulations of chemistry-climate interactions.

  14. Near ultraviolet photochemistry of 2-bromo- and 2-iodothiophene: Revealing photoinduced ring opening in the gas phase?

    SciTech Connect (OSTI)

    Marchetti, Barbara; Karsili, Tolga N. V.; Ashfold, Michael N. R.; Kelly, Orla; Kapetanopoulos, Panos

    2015-06-14

    Velocity map imaging methods, with a new and improved ion optics design, have been used to explore the near ultraviolet photodissociation dynamics of gas phase 2-bromo- and 2-iodothiophene molecules. In both cases, the ground (X) and spin-orbit excited (X*) (where X = Br, I) atom products formed at the longest excitation wavelengths are found to recoil with fast, anisotropic velocity distributions, consistent with prompt CX bond fission following excitation via a transition whose dipole moment is aligned parallel to the breaking bond. Upon tuning to shorter wavelengths, this fast component fades and is progressively replaced by a slower, isotropic recoil distribution. Complementary electronic structure calculations provide a plausible explanation for this switch in fragmentation behaviournamely, the opening of a rival CS bond extension pathway to a region of conical intersection with the ground state potential energy surface. The resulting ground state molecules are formed with more than sufficient internal energy to sample the configuration space associated with several parent isomers and to dissociate to yield X atom products in tandem with both cyclic and ring-opened partner fragments.

  15. Gas-Phase Reactions of Doubly Charged Lanthanide Cations with Alkanes and Alkenes. Trends in Metal(2+) Reactivity

    SciTech Connect (OSTI)

    Gibson, John K.; Marcalo, Joaquim; Santos, Marta; Pires de Matos, Antonio; Haire, Richard G.

    2008-12-08

    The gas-phase reactivity of doubly-charged lanthanide cations, Ln2+ (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), with alkanes (methane, ethane, propane, n-butane) and alkenes (ethene, propene, 1-butene) was studied by Fourier transform ion cyclotron resonance mass spectrometry. The reaction products consisted of different combinations of doubly-charged organometallic ions?adducts or species formed via metal-ion-induced hydrogen, dihydrogen, alkyl, or alkane eliminations from the hydrocarbons?and singly-charged ions that resulted from electron, hydride, or methide transfers from the hydrocarbons to the metal ions. The only lanthanide cations capable of activating the hydrocarbons to form doubly-charged organometallic ions were La2+, Ce2+, Gd2+, and Tb2+, which have ground-state or low-lying d1 electronic configurations. Lu2+, with an accessible d1 electronic configuration but a rather high electron affinity, reacted only through transfer channels. The remaining Ln2+ reacted via transfer channels or adduct formation. The different accessibilities of d1 electronic configurations and the range of electron affinities of the Ln2+ cations allowed for a detailed analysis of the trends for metal(2+) reactivity and the conditions for occurrence of bond activation, adduct formation, and electron, hydride, and methide transfers.

  16. A VUV photoionization measurement and ab-initio calculation of the ionization energy of gas phase SiO2

    SciTech Connect (OSTI)

    Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B.

    2008-12-05

    In this work we report on the detection and vacuum-ultraviolet (VUV) photoionization of gas phase SiO2 generated in situ via laser ablation of silicon in a CO2 molecular beam. The resulting species are investigated by single photon ionization with tunable VUV synchrotron radiation and mass analyzed using reflectron mass spectrometry. Photoionization efficiency (PIE) curves are recorded for SiO and SiO2 and ionization energy estimates are revealed from such measurements. A state-to-state ionizationenergy of 12.60 (+-0.05) eV is recorded by fitting two prominent peaks in the PIE curve for the following process: 1SUM O-Si-O --> 2PRODg [O-Si-O]+. Electronic structure calculations aid in the interpretation of the photoionization process and allow for identification of the symmetric stretch of 2PRODg [O-Si-O]+ which is observed in the PIE spectrum to be 0.11 eV (890 cm-1) above the ground state of the cation and agrees with the 892 cm-1 symmetric stretch frequency calculated at the CCSD(T)/aug-cc-pVTZ level.

  17. Gas Phase Photoacoustic Spectroscopy in the long-wave IR using Quartz Tuning Forks and Amplitude Modulated Quantum Cascade Lasers

    SciTech Connect (OSTI)

    Wojcik, Michael D.; Phillips, Mark C.; Cannon, Bret D.

    2006-12-31

    A paper to accompany a 20 minute talk about the progress of a DARPA funded project called LPAS. ABSTRACT: We demonstrate the performance of a novel long-wave infrared photoacoustic laser absorbance spectrometer for gas-phase species using an amplitude modulated (AM) quantum cascade (QC) laser and a quartz tuning fork microphone. Photoacoustic signal was generated by focusing the output of a Fabry-Perot QC laser operating at 8.41 micron between the legs of a quartz tuning fork which served as a transducer for the transient acoustic pressure wave. The QC laser was modulated at the resonant frequency of the tuning fork (32.8 kHz). This sensor was calibrated using the infrared absorber Freon-134a by performing a simultanious absorption measurement using a 35 cm absorption cell. The NEAS of this instrument was determined to be 2 x 10^-8 W cm^-1 /Hz^1/2 and the fundamental sensitivity of this technique is limited by the noise floor of the tuning fork itself.

  18. Gas phase measurements of mono-fluoro-benzoic acids and the dimer of 3-fluoro-benzoic acid

    SciTech Connect (OSTI)

    Daly, Adam M.; Carey, Spencer J.; Pejlovas, Aaron M.; Li, Kexin; Kukolich, Stephen G.; Kang, Lu

    2015-04-14

    The microwave spectrum of the mono-fluoro-benzoic acids, 2-fluoro-, 3-fluoro-, and 4-fluoro-benzoic acid have been measured in the frequency range of 4-14 GHz using a pulsed beam Fourier transform microwave spectrometer. Measured rotational transition lines were assigned and fit using a rigid rotor Hamiltonian. Assignments were made for 3 conformers of 2-fluorobenzoic acid, 2 conformers of 3-fluorobenzoic acid, and 1 conformer of 4-fluorobenzoic acid. Additionally, the gas phase homodimer of 3-fluorobenzoic acid was detected, and the spectra showed evidence of proton tunneling. Experimental rotational constants are A(0{sup +}) = 1151.8(5), B(0{sup +}) = 100.3(5), C(0{sup +}) = 87.64(3) MHz and A(0{sup ?}) = 1152.2(5), B(0{sup ?}) = 100.7(5), C(0{sup ?}) = 88.85(3) MHz for the two ground vibrational states split by the proton tunneling motion. The tunneling splitting (?E) is approximately 560 MHz. This homodimer appears to be the largest carboxylic acid dimer observed with F-T microwave spectroscopy.

  19. Ruthenium trisbipyridine as a candidate for gas-phase spectroscopic studies in a Fourier transform mass spectrometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Scott, Jill R.; Ham, Jason E.; Durham, Bill; Tremblay, Paul L.

    2004-01-01

    Metal polypyridines are excellent candidates for gas-phase optical experiments where their intrinsic properties can be studied without complications due to the presence of solvent. The fluorescence lifetimes of [Ru(bpy) 3 ] 1+ trapped in an optical detection cell within a Fourier transform mass spectrometer were obtained using matrix-assisted laser desorption/ionization to generate the ions with either 2,5-dihydroxybenzoic acid (DHB) or sinapinic acid (SA) as matrix. All transients acquired, whether using DHB or SA for ion generation, were best described as approximately exponential decays. The rate constant for transients derived using DHB as matrix was 4×10 7 s −1 ,more » while the rate constant using SA was 1×10 7 s −1 . Some suggestions of multiple exponential decay were evident although limited by the quality of the signals. Photodissociation experiments revealed that [Ru(bpy) 3 ] 1+ generated using DHB can decompose to [Ru(bpy) 2 ] 1+ , whereas ions generated using SA showed no decomposition. Comparison of the mass spectra with the fluorescence lifetimes illustrates the promise of incorporating optical detection with trapped ion mass spectrometry techniques.« less

  20. Greenhouse gases mitigation options and strategies for Tanzania

    SciTech Connect (OSTI)

    Mwandosya, M.J.; Meena, H.E.

    1996-12-31

    Tanzania became a party to the United Nations Framework on Climate Change (UN FCCC) when she ratified the Convention in March, 1996. Now that Tanzania and other developing countries are Parties to the UN FCCC, compliance with its provisions is mandatory. The legal requirements therefore provide a basis for their participation in climate change studies and policy formulation. All parties to the Convention are required by Article 4.1 of the United Nations Convention on Climate Change (UN FCCC) to develop, periodically update, publish, and make available national inventories of anthropogenic emissions and removal of greenhouse gases that are not controlled by the Montreal Protocol. This study on possible options for the mitigation of greenhouse gases in Tanzania is a preliminary effort towards the fulfilment of the obligation. In order to fulfil their obligations under the UN FCCC and have a meaningful mitigation assessment, identification and quantification of anthropogenic sources of atmospheric emissions of greenhouse gases in the country was undertaken. In this respect, the study of anthropogenic emissions by source and removals by sink of GHGs in Tanzania was done with the main objective of increasing the quantity and quality of base-line data available in order to further scientific understanding of the relationship of greenhouse gas emissions to climate change. Furthermore, the study facilitated identification of national policy and technological options that could reduce the level of emissions in the country.

  1. Business Case for Compressed Natural Gas in Municipal Fleets

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    ... cost-effectiveness, more- consistent operational costs, increased energy security, reduced greenhouse gas emissions, reduced local air pollution, and reduced noise pollution. ...

  2. Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  3. Phase-field simulations of intragranular fission gas bubble evolution in UO2 under post-irradiation thermal annealing

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2013-05-15

    Fission gas bubble is one of evolving microstructures, which affect thermal mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking, in operating nuclear fuels. Therefore, fundamental understanding of gas bubble evolution kinetics is essential to predict the thermodynamic property and performance changes of fuels. In this work, a generic phasefield model was developed to describe the evolution kinetics of intra-granular fission gas bubbles in UO2 fuels under post-irradiation thermal annealing conditions. Free energy functional and model parameters are evaluated from atomistic simulations and experiments. Critical nuclei size of the gas bubble and gas bubble evolution were simulated. A linear relationship between logarithmic bubble number density and logarithmic mean bubble diameter is predicted which is in a good agreement with experimental data.

  4. DISCOVERY OF THE METHOXY RADICAL, CH{sub 3}O, TOWARD B1: DUST GRAIN AND GAS-PHASE CHEMISTRY IN COLD DARK CLOUDS

    SciTech Connect (OSTI)

    Cernicharo, J.; Jimenez-Escobar, A.; Munoz Caro, G. M.; Marcelino, N.; Roueff, E.; Gerin, M.

    2012-11-10

    We report on the discovery of the methoxy radical (CH{sub 3}O) toward the cold and dense core B1-b based on the observation, with the IRAM 30 m radio telescope, of several lines at 3 and 2 mm wavelengths. Besides this new molecular species we also report on the detection of many lines arising from methyl mercaptan (CH{sub 3}SH), formic acid (HCOOH), propynal (HCCCHO), acetaldehyde (CH{sub 3}CHO), dimethyl ether (CH{sub 3}OCH{sub 3}), methyl formate (CH{sub 3}OCOH), and the formyl radical (HCO). The column density of all these species is {approx_equal}10{sup 12} cm{sup -2}, corresponding to abundances of {approx_equal}10{sup -11}. The similarity in abundances for all these species strongly suggest that they are formed on the surface of dust grains and ejected to the gas phase through non-thermal desorption processes, most likely cosmic rays or secondary photons. Nevertheless, laboratory experiments indicate that the CH{sub 3}O isomer released to the gas phase is CH{sub 2}OH rather than the methoxy one. Possible gas-phase formation routes to CH{sub 3}O from OH and methanol are discussed.

  5. Geothermal greenhouse development | Open Energy Information

    Open Energy Info (EERE)

    LibraryAdd to library Journal Article: Geothermal greenhouse development Author P. J. Lienau Published Journal Geo-Heat Center, 1990 DOI Not Provided Check for DOI...

  6. Nakashima Nurseries Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Facility Nakashima Nurseries Sector Geothermal energy Type Greenhouse Location Coachella, California Coordinates 33.6803003, -116.173894 Show Map Loading map......

  7. Low Temperature Direct Use Greenhouse Geothermal Facilities ...

    Open Energy Info (EERE)

    Low Temperature Direct Use Greenhouse Geothermal Facilities Jump to: navigation, search Loading map... "format":"googlemaps3","type":"ROADMAP","types":"ROADMAP","SATELLITE","HYBR...

  8. SWTDI Geothermal Aquaculture Facility Greenhouse Low Temperature...

    Open Energy Info (EERE)

    Geothermal Facility Facility SWTDI Geothermal Aquaculture Facility Sector Geothermal energy Type Greenhouse Location Las Cruces, New Mexico Coordinates 32.3123157,...

  9. Cliffs Minerals, Inc. Eastern Gas Shales Project, Ohio No. 5 well - Lorain County. Phase II report. Preliminary laboratory results

    SciTech Connect (OSTI)

    1980-04-01

    The US Department of Energy is funding a research and development program entitled the Eastern Gas Shales Project designed to increase commercial production of natural gas in the eastern United States from Middle and Upper Devonian Shales. The program's objectives are as follows: (1) to evaluate recoverable reserves of gas contained in the shales; (2) to enhanced recovery technology for production from shale gas reservoirs; and (3) to stimulate interest among commercial gas suppliers in the concept of producing large quantities of gas from low-yield, shallow Devonian Shale wells. The EGSP-Ohio No. 5 well was cored under a cooperative cost-sharing agreement between the Department of Energy (METC) and Columbia Gas Transmission Corporation. Detailed characterization of the core was performed at the Eastern Gas Shale Project's Core Laboratory. At the well site, suites of wet and dry hole geophysical logs were run. Characterization work performed at the Laboratory included photographic logs, lithologic logs, fracture logs, measurements of core color variation, and stratigraphic interpretation of the cored intervals. In addition samples were tested for physical properties by Michigan Technological University. Physical properties data obtained were for: directional ultrasonic velocity; directional tensile strength; strength in point load; and trends of microfractures.

  10. Proceedings of the Great Lakes Solar Greenhouse Conference V

    SciTech Connect (OSTI)

    Currin, C.G. (ed.)

    1983-01-01

    Proceedings of the Fifth Great Lakes Greenhouse Conference are presented. Topics included are: a review of a greenhouses, greenhouses as integral part of an earth-sheltered home, solar architecture, design criteria, heat contribution for solar greenhouses, and the future of solar greenhouses.

  11. Proceedings of the Great Lakes Solar Greenhouse Conference V

    SciTech Connect (OSTI)

    Currin, C.G. (ed.)

    1983-01-01

    Proceedings of the Fifth Great Lakes Solar Greenhouse Conference are presented. Topics included are a review of greenhouses, greenhouses as integral part of an earth-sheltered house, solar architecture, design criteria, heat contribution from solar greenhouses, and the future for solar greenhouses.

  12. Method and apparatus for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl [Pinson, AL; Felix, Larry Gordon [Pelham, AL; Snyder, Todd Robert [Birmingham, AL

    2008-02-12

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  13. Method and apparatus maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl; Felix, Larry Gordon; Snyder, Todd Robert

    2009-12-15

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  14. LANDFILL GAS CONVERSION TO LNG AND LCO{sub 2}. PHASE 1, FINAL REPORT FOR THE PERIOD MARCH 1998-FEBRUARY 1999

    SciTech Connect (OSTI)

    COOK,W.J.; NEYMAN,M.; SIWAJEK,L.A.; BROWN,W.R.; VAN HAUWAERT,P.M.; CURREN,E.D.

    1998-02-25

    Process designs and economics were developed to produce LNG and liquid carbon dioxide (CO{sub 2}) from landfill gas (LFG) using the Acrion CO{sub 2} wash process. The patented Acrion CO{sub 2} wash process uses liquid CO{sub 2} to absorb contaminants from the LFG. The process steps are compression, drying, CO{sub 2} wash contaminant removal and CO{sub 2} recovery, residual CO{sub 2} removal and methane liquefaction. Three flowsheets were developed using different residual CO{sub 2} removal schemes. These included physical solvent absorption (methanol), membranes and molecular sieves. The capital and operating costs of the flowsheets were very similar. The LNG production cost was around ten cents per gallon. In parallel with process flowsheet development, the business aspects of an eventual commercial project have been explored. The process was found to have significant potential commercial application. The business plan effort investigated the economics of LNG transportation, fueling, vehicle conversion, and markets. The commercial value of liquid CO{sub 2} was also investigated. This Phase 1 work, March 1998 through February 1999, was funded under Brookhaven National laboratory contract 725089 under the research program entitled ``Liquefied Natural Gas as a Heavy Vehicle Fuel.'' The Phase 2 effort will develop flowsheets for the following: (1) CO{sub 2} and pipeline gas production, with the pipeline methane being liquefied at a peak shaving site, (2) sewage digester gas as an alternate feedstock to LFG and (3) the use of mixed refrigerants for process cooling. Phase 2 will also study the modification of Acrion's process demonstration unit for the production of LNG and a market site for LNG production.

  15. Greenhouse Gas Laser Imaging Tomography Experiment (GreenLITE): Evaluation of a new method to look at high resolution spatial/temporal distributions of carbon over key sub km sites

    SciTech Connect (OSTI)

    Dobler, Jeremy; Zaccheo, T. Scott; Blume, Nathan; Braun, Michael; Perninit, Timothy; McGregor, Doug; Botos, Chris; Dobeck, Laura

    2015-01-01

    Recently a new laser based approach for measuring area with potential for producing 2D estimates of the concentration spatial distribution has been developed through a cooperative agreement with the National Energy and Technology Laboratory of the Department of Energy, Exelis Inc. and AER Inc. The new approach is based on a pair of continuous wave intensity modulated laser absorption spectrometer transceivers, combined with a series of retro reflectors located around the perimeter of the area being monitored. The main goal of this cooperative agreement is monitoring, reporting and verification for ground carbon capture and storage projects. The system was recently tested at the Zero Emission Research and Technology site in Bozeman, MT, with underground leak rates ranging from 0.1 – 0.3 metric ton per day (T/d), as well as a 0.8 T/d surface release. Over 200 hours of data were collected over a rectangular grid 180m x 200m between August 18th and September 9th. In addition, multiple days of in situ data were acquired for the same site, using a Licor gas analyzer systems. Initial comparisons between the laser-based system and the in situ agree very well. The system is designed to operate remotely and transmit the data via a 3G/4G connection along with weather data for the site. An all web-based system ingests the data, populates a database, performs the inversion to ppm CO2 using the Line-by-Line Radiative Transfer Model (LBLRTM), and displays plots and statistics for the retrieved data. We will present an overview of the GreenLITE measurement system, outline the retrieval and reconstruction approach, and discuss results from extensive field testing.

  16. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    1997-10-01

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  17. The role of clouds and oceans in global greenhouse warming. Final report

    SciTech Connect (OSTI)

    Hoffert, M.I.

    1996-10-01

    This research focuses on assessing connections between anthropogenic greenhouse gas emissions and global climatic change. it has been supported since the early 1990s in part by the DOE ``Quantitative Links`` Program (QLP). A three-year effort was originally proposed to the QLP to investigate effects f global cloudiness on global climate and its implications for cloud feedback; and to continue the development and application of climate/ocean models, with emphasis on coupled effects of greenhouse warming and feedbacks by clouds and oceans. It is well-known that cloud and ocean processes are major sources of uncertainty in the ability to predict climatic change from humankind`s greenhouse gas and aerosol emissions. And it has always been the objective to develop timely and useful analytical tools for addressing real world policy issues stemming from anthropogenic climate change.

  18. HFCs contribution to the greenhouse effect. Present and projected estimations

    SciTech Connect (OSTI)

    Libre, J.M.; Elf-Atochem, S.A.

    1997-12-31

    This paper reviews data that can be used to calculate hydrofluorocarbon (HFC) contribution to the greenhouse effect and compare it to other trace gas contributions. Projections are made for 2010 and 2100 on the basis of available emission scenarios. Industrial judgement on the likelihood of those scenarios is also developed. Calculations can be made in two different ways: from Global Warming Potential weighted emissions of species or by direct calculation of radiative forcing based on measured and projected atmospheric concentrations of compounds. Results show that HFCs corresponding to commercial uses have a negligible contribution to the greenhouse effect in comparison with other trace gases. The projected contributions are also very small even if very high emission scenarios are maintained for decades. In 2010 this contribution remains below 1%. Longer term emissions projections are difficult. However, based on the IPCC scenario IS92a, in spite of huge emissions projected for the year 2100, the HFC contribution remains below 3%. Actually many factors indicate that the real UFC contribution to the greenhouse effect will be even smaller than presented here. Low emissive systems and small charges will likely improve sharply in the future and have drastically improved in the recent past. HFC technology implementation is likely to grow in the future, reach a maximum before the middle of the next century; the market will stabilise driven by recycling, closing of systems and competitive technologies. This hypothesis is supported by previous analysis of the demand for HTCs type applications which can be represented by {open_quotes}S{close_quotes} type curves and by recent analysis indicating that the level of substitution of old products by HFCs is growing slowly. On the basis of those data and best industrial judgement, the contribution of HFCs to the greenhouse effect is highly likely to remain below 1% during the next century. 11 refs., 2 figs., 5 tabs.

  19. Cliffs Minerals, Inc. Eastern Gas Shales Project, Ohio No. 6 series: Gallia County. Phase II report. Preliminary laboratory results

    SciTech Connect (OSTI)

    1980-06-01

    The US Department of Energy is funding a research and development program entitled the Eastern Gas Shales Project designed to increase commercial production of natural gas in the eastern United States from Middle and Upper Devonian Shales. On September 28, 1978 the Department of Energy entered into a cooperative agreement with Mitchell Energy Corporation to explore Devonian shale gas potential in Gallia County, Ohio. Objectives of the cost-sharing contract were the following: (1) to select locations for a series of five wells to be drilled around the periphery of a possible gas reservoir in Gallia County, Ohio; (2) to drill, core, log, case, fracture, clean up, and test each well, and to monitor production from the wells for a five-year period. This report summarizes the procedures and results of core characterization work performed at the Eastern Gas Shales Project Core Laboratory on core retrieved from the Gallia County EGSP wells, designated OH No. 6/1, OH No. 6/2, OH No. 6/3, OH No. 6/4, and OH No. 6/5. Characterization work performed includes photographic logs, fracture logs, measurements of core color variation, and stratigraphic interpretation of the cored intervals. In addition the following tests were performed by Michigan Technological University to obtain the following data: directional ultrasonic velocity; directional tensile strength, strength in point load; trends of microfractures; and hydraulic fracturing characteristics.

  20. Emissions of greenhouse gases in the United States, 1985--1990

    SciTech Connect (OSTI)

    Not Available

    1993-11-10

    The Earth`s capacity to support life depends on the moderating influences of gases that envelop the planet and warm its surface and protect it from harmful radiation. These gases are referred to as ``greenhouse gases.`` Their warming capacity, called ``the greenhouse effect,`` is essential to maintaining a climate hospitable to all plant, animal, and human life. In recent years, however, there has been increasing concern that human activity may be affecting the intricate balance between the Earth`s absorption of heat from the sun and its capacity to reradiate excess heat back into space. Emissions of greenhouse gases from human activities may be an important mechanism that affects global climate. Thus, research is intensifying to improve our understanding of the role human activities might play in influencing atmospheric concentrations of greenhouse gases. On the basis of scientific findings of the past few decades, the US Government and the international community at large are now taking steps toward stabilizing greenhouse gas emissions. This report contributes to that process. Mandated by Congress this report provides estimates of US emissions of the principal greenhouse gases--carbon dioxide, methane, nitrous oxide, chlorofluorcarbons, carbon monoxide, nitrogen oxides, and nonmethane volatile organic compounds. Estimates are for the period 1985 to 1990. Preliminary estimates for 1991 have also been included, whenever data were available.

  1. Milgro No. 2 Greenhouse Low Temperature Geothermal Facility ...

    Open Energy Info (EERE)

    Milgro No. 2 Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Milgro No. 2 Greenhouse Low Temperature Geothermal Facility Facility Milgro No. 2...

  2. Big Bend Preventorium Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Big Bend Preventorium Greenhouse Low Temperature Geothermal Facility Facility Big Bend...

  3. Weiser Hot Springs Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Hot Springs Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Weiser Hot Springs Greenhouse Low Temperature Geothermal Facility Facility Weiser Hot...

  4. Donlay Ranch Hot Spring Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Donlay Ranch Hot Spring Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Donlay Ranch Hot Spring Greenhouse Low Temperature Geothermal Facility...

  5. Utah Roses Greenhouse Low Temperature Geothermal Facility | Open...

    Open Energy Info (EERE)

    Roses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Utah Roses Greenhouse Low Temperature Geothermal Facility Facility Utah Roses Sector...

  6. Cal Flint Floral Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Cal Flint Floral Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Cal Flint Floral Greenhouse Low Temperature Geothermal Facility Facility Cal Flint...

  7. Cove Hot Spring Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Cove Hot Spring Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Cove Hot Spring Greenhouse Low Temperature Geothermal Facility Facility Cove Hot...

  8. Hunt Brothers Floral Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Brothers Floral Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Hunt Brothers Floral Greenhouse Low Temperature Geothermal Facility Facility Hunt...

  9. Chico Hot Springs Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Chico Hot Springs Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Chico Hot Springs Greenhouse Low Temperature Geothermal Facility Facility Chico...

  10. Canyon Bloomers, Inc Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Canyon Bloomers, Inc Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Canyon Bloomers, Inc Greenhouse Low Temperature Geothermal Facility Facility...

  11. Green Canyon Hot Springs Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Green Canyon Hot Springs Greenhouse Low Temperature Geothermal Facility Facility Green Canyon Hot...

  12. OSTIblog Articles in the greenhouse gases Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    greenhouse gases Topic Carbon Sequestration - Helping to Save Our Beautiful World by Kathy ... Related Topics: carbon dioxide, carbon sequestration, climate change, greenhouse gases

  13. EIA-Voluntary Reporting of Greenhouse Gases Program - About the...

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program About the 1605(b) Program History Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases ...

  14. EIA-Voluntary Reporting of Greenhouse Gases Program - Under Constructi...

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program This Page is Currently Under Construction Please check back at a later time For more information on the Voluntary Reporting of Greenhouse Gases ...

  15. EIA-Voluntary Reporting of Greenhouse Gases Program -Data and...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data and Reports Voluntary Reporting of Greenhouse Gases Program Data and Reports The first reporting cycle under the revised Voluntary Reporting of Greenhouse Gases Program closed ...

  16. EIA-Voluntary Reporting of Greenhouse Gases Program - Getting...

    U.S. Energy Information Administration (EIA) Indexed Site

    Getting Started Voluntary Reporting of Greenhouse Gases Program Getting Started Form ... The Voluntary Reporting of Greenhouse Gases Program suggests that prospective reporters ...

  17. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    U.S. Energy Information Administration (EIA) Indexed Site

    Program Voluntary Reporting of Greenhouse Gases Program Original 1605(b) Program Section 1605(b) of the Energy Policy Act of 1992 established the Voluntary Reporting of Greenhouse ...

  18. EIA-Voluntary Reporting of Greenhouse Gases Program - Contact

    U.S. Energy Information Administration (EIA) Indexed Site

    Contact Voluntary Reporting of Greenhouse Gases Program Contact For more information on the Voluntary Reporting of Greenhouse Gases Program, contact us via e-mail, phone, fax, or ...

  19. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program Original 1605(b) Program Calculation Tools The workbooks below were developed to assist participants in the original Voluntary Reporting of Greenhouse ...

  20. J & K Growers Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    J & K Growers Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name J & K Growers Greenhouse Low Temperature Geothermal Facility Facility J & K Growers...