Sample records for greenhouse gas co2

  1. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions to reflect, adsorb and emit the solar energy. However, the continuous emissions of CO2 into the atmosphere

  2. GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2)

    E-Print Network [OSTI]

    Green, Donna

    GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2) from the combustion. Figure 1 Global Carbon Dioxide Emissions: 1850­2030 1850 1860 1870 1880 1890 1900 1910 1920 1930 1940- related CO2 emissions have risen 130-fold since 1850--from 200 million tons to 27 billion tons a year

  3. Atmospheric CO2 concentrations during ancient greenhouse climates were similar

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Atmospheric CO2 concentrations during ancient greenhouse climates were similar to those predicted atmospheric CO2 concentrations (½CO2atm) during Earth's ancient greenhouse episodes is essential for accurately predicting the response of future climate to elevated CO2 levels. Empirical estimates of ½CO2atm

  4. Falsification Of The Atmospheric CO2 Greenhouse Effects

    E-Print Network [OSTI]

    Learned, John

    Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3 Contents Abstract 2 1 Introduction 6 1.1 Problem background

  5. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas1 emissions into the atmosphere2

    E-Print Network [OSTI]

    Boyer, Edmond

    ppm in the pre-industrial revolution to 37942 ppm in 2005, rising faster in the last 10 years (average atmospheric CO2 concentration doubles the pre-industrial revolution concentration (IPCC,49 2007a 36 insu-00351929,version1-12Jan2009 #12;1. Introduction37 38 Coal caused the first industrial

  6. CO2 levels during the greenhouse of the Paleocene

    E-Print Network [OSTI]

    Shull, Kenneth R.

    to reconstruct CO2 concentrations during this period of global warming 56 million years ago. 56 million year oldCO2 levels during the greenhouse of the Paleocene Eocene Thermal Maximum (PETM) Francesca A. Mc, Boulder #12;Estimating paleopCO2 0 5 10 15 20 25 30 0 500 1000 1500 2000 2500 3000 Meter Level, start

  7. Constitutional Implications of Regional CO2 Cap-and-Trade Programs: The Northeast Regional Greenhouse Gas Initiative as a Case in Point

    E-Print Network [OSTI]

    Funk, William

    2009-01-01T23:59:59.000Z

    on the purchase of out-of- RGGI electricity generating CO 2CONSTITUTIONAL IMPLICATIONS OF RGGI "(i) to study state andGas Initiative, About RGGI, http://www.rggi. org/about (last

  8. Carbon Emissions Primer Symposium on Greenhouse Gas andSymposium on Greenhouse Gas and

    E-Print Network [OSTI]

    6/5/2013 1 Carbon Emissions Primer Symposium on Greenhouse Gas andSymposium on Greenhouse Gas) · Simple, somewhat inflexible · Do not price emissions directly Carbon taxes · Use market forces Council June 4, 2013 Portland, OR 1 CO2 Chemistry 1 molecule of CO 1 atom carbon1 molecule of CO2 = 1 atom

  9. Transportation and Greenhouse Gas Emissions: Measurement, Causation and Mitigation

    E-Print Network [OSTI]

    .S. CO2 emissions sources. U.S. CO2 transportation emissions sources by mode. #12;Center% of the carbon dioxide we produce. As such it is a leading candidate for greenhouse gas ((GHG) (CO2, NH4, HFCsTransportation and Greenhouse Gas Emissions: Measurement, Causation and Mitigation Oak Ridge

  10. MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

  11. A Novel Paradigm in Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    emission [1, 2]. Moreover, water vapor is also a naturally occurring greenhouse gas and accounts for the largest percent- age of the greenhouse effect, between 36% and 66% in terms of radiation absorbance. Water). Yet the radiative importance of water vapor is less than that of CO2, CH4, and N2O, because

  12. Biomass torrefaction and CO2 capture using mining wastes A new approach for reducing greenhouse gas emissions of co-firing plants

    E-Print Network [OSTI]

    Devernal, Anne

    for an efficient biomass/coal co-firing could thus be further enhanced by curbing the overall process CO2 emissions as well as using ionic-liquid-impregnated torrefac- tion to increase birch wood constituents' torrefaction saturation, and carbon monoxide and methane concen- trations on mining residues CO2 uptake was studied

  13. Greenhouse Gas Emissions (Minnesota)

    Broader source: Energy.gov [DOE]

    This statute sets goals for the reduction of statewide greenhouse gas emissions by at least 15 percent by 2015, 30 percent by 2025, and 80 percent by 2050, calculated relative to 2005 levels. These...

  14. On the scattering-greenhouse effect of CO2 ice clouds

    E-Print Network [OSTI]

    Pierrehumbert, Raymond

    On the scattering-greenhouse effect of CO2 ice clouds R. T. Pierrehumbert C. Erlick Department in J. Atmos. Sci. #12;Scattering Greenhouse Effect on Early Mars Page 2 Abstract We offer some remarks on the greenhouse effect due to high clouds which reflect thermal infrared radiation, but do not absorb or emit it

  15. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYCO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  16. Greenhouse Gas Basics

    Broader source: Energy.gov [DOE]

    Greenhouse gases are trace gases in the lower atmosphere that trap heat through a natural process called the "greenhouse effect."

  17. Greenhouse Gas Guidance and Reporting

    Broader source: Energy.gov [DOE]

    Federal agencies are required to inventory and manage their greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change.

  18. Guidance on measuring and reporting Greenhouse Gas

    E-Print Network [OSTI]

    Guidance on measuring and reporting Greenhouse Gas (GHG) emissions from freight transport This guidance provides clear instructions on calculating the greenhouse gas (GHG) emissions from freight and report your greenhouse gas emissions', by providing more specific information and examples relating

  19. Climate Insights 101 Questions and Discussion Points Module 1, Lesson 1: CO2 and the Greenhouse Effect

    E-Print Network [OSTI]

    Pedersen, Tom

    Effect 1 Climate Insights 101 Questions and Discussion Points Module 1, Lesson 1: CO2 and the Greenhouse Effect Available at http://pics.uvic.ca/education/climate-insights-101 1. CO2 and the Greenhouse Effect Questions: How did the term "greenhouse effect" originate? Why did it stick in the public imagination? Why

  20. Resources on Greenhouse Gas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    resources for reporting annual greenhouse gas activities. FedCenter Greenhouse Gas Inventory Reporting Website: Features additional information, training, and tools to assist...

  1. Federal Greenhouse Gas Inventories and Performance | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal Agency Progress Toward Reduction Targets Fiscal Year (FY) 2012 Greenhouse Gas Inventory: Government Totals FY 2011 Greenhouse Gas Inventory: Government Totals FY 2010...

  2. The Anthropogenic Perturbation of Atmospheric CO2 and the Climate System

    E-Print Network [OSTI]

    Fortunat, Joos

    of carbon dioxide (CO2), a powerful greenhouse gas (GHG), are redistributed within the climate system

  3. Economically Efficient Operation of CO2 Capturing Process Part I: Self-optimizing Procedure for Selecting the Best Controlled Variables

    E-Print Network [OSTI]

    Skogestad, Sigurd

    the greenhouse gas CO2 that causes global warming. Due to the effect of CO2 emissions on global warming

  4. Regional GHG Emissions O tlook Greenhouse Gas and the Regional

    E-Print Network [OSTI]

    6/5/2013 1 Regional GHG Emissions O tlook Greenhouse Gas and the Regional Power System Symposium Regional GHG Emissions ­ Outlook June 4, 2013 Steven Simmons CO2 Emission Outlook for the Pacific NW (ID-MT- OR-WA) Key Factors that determine Emissions Levels 1 Demand & Conservation 50 60 70 2 1. Demand

  5. Life Cycle Greenhouse Gas Emissions from Solar Photovoltaics

    E-Print Network [OSTI]

    Life Cycle Greenhouse Gas Emissions from Solar Photovoltaics Over the last thirty years, hundreds and utility-scale solar photovoltaic (PV) systems. These LCAs have yielded wide-ranging results. Variation of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. ~40 g CO2

  6. ANALYSIS OF MEASURES FOR REDUCING TRANSPORTATION SECTOR GREENHOUSE GAS

    E-Print Network [OSTI]

    (CO2) emission reduction estimates were obtained for each of the measures. The package of measures the problem of reducing greenhouse gas (GHG) emissions from the Canadian transportation sector. Reductions-makers will require estimates of both the potential emission reductions and the costs or benefits associated

  7. Greenhouse Gas Reductions: SF6

    ScienceCinema (OSTI)

    Anderson, Diana

    2013-04-19T23:59:59.000Z

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas ? one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  8. Federal Greenhouse Gas Inventories and Performance

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program provides performance data illustrating federal agency progress in meeting the greenhouse gas reduction targets established under Executive Order (E.O.) 13514, as well as the comprehensive greenhouse gas inventories as reported by federal agencies.

  9. Greenhouse Gas Emissions Reduction Act (Maryland)

    Broader source: Energy.gov [DOE]

    The Greenhouse Gas Emissions Reduction Act requires the Department of the Environment to publish and update an inventory of statewide greenhouse gas emissions for calendar year 2006 and requires...

  10. Greenhouse Gas Program Overview (Revised) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-06-01T23:59:59.000Z

    Overview of the Federal Energy Management Program (FEMP) Greenhouse Gas program, including Federal requirements, FEMP services, and contacts.

  11. Danish Greenhouse Gas Reduction Scenarios for 2020

    E-Print Network [OSTI]

    Environmental Protection Agency, Danish Energy Authority and Danish Ministry of Finance. The consultancy reportDanish Greenhouse Gas Reduction Scenarios for 2020 and 2050 February 2008 Prepared by Ea Energy 54 2.9 ENERGY RESOURCES 55 3 DANISH GREENHOUSE GAS EMISSION 58 3.1 GREENHOUSE GAS SOURCES 58 4

  12. RESEARCH ROADMAP FOR GREENHOUSE GAS INVENTORY

    E-Print Network [OSTI]

    RESEARCH ROADMAP FOR GREENHOUSE GAS INVENTORY METHODS Prepared For: California Energy Commission Consulting · Riitta Pipatti, IPCC Task Force on National Greenhouse Gas Inventories · Dennis Rolston Agency · Fabian Wagner, IPCC Task Force on National Greenhouse Gas Inventories · Wilfried Winiwarter

  13. Greenhouse gas emissions in biogas production systems

    E-Print Network [OSTI]

    Dittert, Klaus; Senbayram, Mehmet; Wienforth, Babette; Kage, Henning; Muehling, Karl H

    2009-01-01T23:59:59.000Z

    Augustin J et al. Automated gas chromatographic system forof the atmospheric trace gases methane, carbon dioxide, andfuel consumption and of greenhouse gas (GHG) emissions from

  14. enhancing greenhouse gas "sinks," such as forests). The report identifies strategies that

    E-Print Network [OSTI]

    to limit greenhouse gas emissions (e.g., through energy efficiency and low carbon energy sources). At the current rate of U.S. emissions (roughly 7 Gt CO2-eq per year), the proposed budget would be "spent" well and natural ecosys- tems around the world. The largest overall source of greenhouse gas emissions

  15. Predicting Greenhouse Gas Emissions and Soil Carbon from Changing Pasture to an Energy Crop

    E-Print Network [OSTI]

    DeLucia, Evan H.

    Predicting Greenhouse Gas Emissions and Soil Carbon from Changing Pasture to an Energy Crop 4493 g CO2 eq?m22 over 15 years of energy cane production. Cultivation of energy cane on former pasture Greenhouse Gas Emissions and Soil Carbon from Changing Pasture to an Energy Crop. PLoS ONE 8(8): e72019. doi

  16. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01T23:59:59.000Z

    Article Correction to Carbon sequestration and greenhouseCor- rection to Carbon sequestration and greenhouse gas1 ] In the paper Carbon sequestration and greenhouse gas

  17. Greenhouse gas emissions from alternative futures of deforestation and agricultural management in the

    E-Print Network [OSTI]

    Vermont, University of

    Greenhouse gas emissions from alternative futures of deforestation and agricultural management climate. We examine scenarios of deforestation and postclearing land use to estimate the future (2006.8 to 15.9 Pg CO2-equivalents (CO2-e) from 2006 to 2050. Deforestation is the largest source of green

  18. Greenhouse gas mitigation by agricultural intensification

    E-Print Network [OSTI]

    Burney, J. A; Davis, S. J; Lobell, D. B

    2010-01-01T23:59:59.000Z

    et al. (2007) Agriculture. Climate Change 2007: Mitigationagricultures future contributions to climate change,agriculture greenhouse gas emissions mitigation carbon price | land use change | climate

  19. Reduction of Greenhouse Gas Emissions (Connecticut)

    Broader source: Energy.gov [DOE]

    This section sets state goals to reduce greenhouse gas emissions to 10 percent below 1990 levels by 2020 and 80 percent below 1990 levels by 2050.

  20. Separation of CO2 from flue gas using electrochemical cells

    SciTech Connect (OSTI)

    Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

    2010-06-01T23:59:59.000Z

    ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

  1. Federal Register Notice for Life Cycle Greenhouse Gas Perspective...

    Energy Savers [EERE]

    Federal Register Notice for Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Federal Register Notice for Life Cycle Greenhouse Gas...

  2. Oldenburg and Pan CO2 as Cushion Gas for CAES 1

    E-Print Network [OSTI]

    Eisen, Michael

    Oldenburg and Pan CO2 as Cushion Gas for CAES 1 CO2 as Cushion Gas for Compressed Air Energy Compressed Air Oldenburg, C.M., Energy&Fuels, 17(1), 240­246, 2003. #12;Oldenburg and Pan CO2 as Cushion Gas as Cushion Gas for CAES 3 Renewables Need Energy Storage Source: Samir Succar, IAC Workshop, October 2005

  3. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27T23:59:59.000Z

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  4. Shale gas production: potential versus actual greenhouse gas emissions*

    E-Print Network [OSTI]

    Shale gas production: potential versus actual greenhouse gas emissions* Francis O, monitor and verify greenhouse gas emissions and climatic impacts. This reprint is one of a series intended Environ. Res. Lett. 7 (2012) 044030 (6pp) doi:10.1088/1748-9326/7/4/044030 Shale gas production: potential

  5. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and...

  6. The Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigerati...

    Open Energy Info (EERE)

    Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigeration and Air Conditioning Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol...

  7. Shale gas production: potential versus actual greenhouse gas emissions

    E-Print Network [OSTI]

    OSullivan, Francis Martin

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

  8. First Direct Observation of CO2's Greenhouse Effect at the Earth...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Direct Observation of Carbon Dioxide's Increasing Greenhouse Effect at Earth's Surface First Direct Observation of Carbon Dioxide's Increasing Greenhouse Effect at Earth's...

  9. Integrated Energy and Greenhouse Gas Management System

    E-Print Network [OSTI]

    Spates, C. N.

    2010-01-01T23:59:59.000Z

    With Climate Change legislation on the horizon, the need to integrate energy reduction initiatives with greenhouse gas reduction efforts is critical to manufactures competitiveness and financial strength going forward. MPC has developed...

  10. Greenhouse Gas Mitigation Planning for Business Travel

    Broader source: Energy.gov [DOE]

    Business travel is among the largest sources of Scope 3 greenhouse gas (GHG) emissions accounted for by Federal agencies. For some agencies, business travel can represent up to 60% of Scope 3...

  11. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    fuels (eg diesel, compressed natural gas). Electricity (infossil fuels, such as compressed natural gas and liquefied

  12. Low-cost multispectral vegetation imaging system for detecting leaking CO2 gas

    E-Print Network [OSTI]

    Shaw, Joseph A.

    Low-cost multispectral vegetation imaging system for detecting leaking CO2 gas Justin A. Hogan,1 sequestration sites for possible leaks of the CO2 gas from underground reservoirs, a low-cost multispectral are then flagged for closer inspection with in-situ CO2 sensors. The system is entirely self

  13. Solubility trapping in formation water as dominant CO2 sink in natural gas fields

    E-Print Network [OSTI]

    Haszeldine, Stuart

    LETTERS Solubility trapping in formation water as dominant CO2 sink in natural gas fields Stuart M removal in nine natural gas fields in North America, China and Europe, using noble gas and carbon isotope tracers. The natural gas fields investigated in our study are dominated by a CO2 phase and provide

  14. CONTROL DESIGN FOR A GAS TURBINE CYCLE WITH CO2 CAPTURE CAPABILITIES

    E-Print Network [OSTI]

    Foss, Bjarne A.

    . The exhaust gas from a gas turbine with CO2 as working fluid, is used as heating medium for a steam cycleCONTROL DESIGN FOR A GAS TURBINE CYCLE WITH CO2 CAPTURE CAPABILITIES Dagfinn Snarheim Lars Imsland. of Science and Technology, 7491 Trondheim Abstract: The semi-closed oxy-fuel gas turbine cycle has been

  15. Climate change : enhanced : recent reductions in China's greenhouse gas emissions.

    SciTech Connect (OSTI)

    Streets, D. G.; Jiang, K.; Hu, X.; Sinton, J. E.; Zhang, X.-Q.; Xu, D.; Jacobson, M. Z.; Hansen, J. E.; Decision and Information Sciences; Energy Research Inst.; LBNL; Chinese Academy of Forestry; Stanford Univ.; NASA Goddard Inst. for Space Studies

    2001-11-30T23:59:59.000Z

    Using the most recent energy and other statistical data, we have estimated the annual trends in China's greenhouse gas emissions for the period 1990 to 2000. The authors of this Policy Forum calculate that CO2 emissions declined by 7.3% between 1996 and 2000, while CH4 emissions declined by 2.2% between 1997 and 2000. These reductions were due to a combination of energy reforms, economic restructuring, forestry policies, and economic slowdown. The effects of these emission changes on global mean temperatures are estimated and compared with the effects of concurrent changes in two aerosol species, sulfate and black carbon.

  16. Long-wave infrared imaging of vegetation for detecting leaking CO2 gas

    E-Print Network [OSTI]

    Shaw, Joseph A.

    Long-wave infrared imaging of vegetation for detecting leaking CO2 gas Jennifer E. Johnson Joseph A for detecting leaking CO2 gas Jennifer E. Johnson,a Joseph A. Shaw,a Rick Lawrence,b Paul W. Nugent,a Laura M of these calibrated imagers is imaging of vegetation for CO2 gas leak detection. During a four-week period

  17. CONTROL ISSUES IN THE DESIGN OF A GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    CONTROL ISSUES IN THE DESIGN OF A GAS TURBINE CYCLE FOR CO2 CAPTURE Query Sheet Q1: AU: short title OF A GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland, Dagfinn Snarheim, and Bjarne A. Foss Department-closed / gas turbine cycle for capture. Some control strategies and their interaction with the process design

  18. Calculation of CO2 column heights in depleted gas fields from known pre-production gas column heights

    E-Print Network [OSTI]

    Calculation of CO2 column heights in depleted gas fields from known pre-production gas column that the CO2 is in a dense phase (either liquid or supercritical). Accurate assessment of the storage capacity also requires an estimation of the amount of CO2 that can be safely stored beneath the reservoir seal

  19. Fiscal Year 2010 Greenhouse Gas Inventory

    E-Print Network [OSTI]

    Escher, Christine

    Fiscal Year 2010 Greenhouse Gas Inventory OREGON STATE UNIVERSITY #12;OREGON STATE UNIVERSITYGHG UNIVERSITYGHG Report - FY10 3 Acknowledgments Due to the broad scope of this inventory, a large number of people Oil: Amber Sams · Enterprise Rent-A-Car: Davion Reese · First Student: Brian Maxwell · Good Company

  20. Fiscal Year 2009 Greenhouse Gas Inventory

    E-Print Network [OSTI]

    Escher, Christine

    Fiscal Year 2009 Greenhouse Gas Inventory Oregon State University Greg Smith Sustainability Program #12;Acknowledgments Due to the broad scope of this inventory, a large number of people from many - First Student: Brian Maxwell - Carson Oil: Gena Conner Government Organizations - Baker County: Jason

  1. 2 Key Achievements 7 Greenhouse Gas Reduction

    E-Print Network [OSTI]

    Princeton University Reports Contents 2 Key Achievements 7 Greenhouse Gas Reduction Campus Energy was established in 2008, the University has invested $5.3 million in energy-savings projects, resulting in annual of a 5.2-megawatt solar collector field. · Audit the remaining 20 of the top 50 energy- consuming

  2. Fiscal Year 2007 Greenhouse Gas Inventory

    E-Print Network [OSTI]

    Escher, Christine

    Fiscal Year 2007 Greenhouse Gas Inventory Greg Smith Brandon Trelstad OSU Facilities Services June #12;#12;Acknowledgments Due to the broad scope of this inventory, a large number of people from many, geothermal, tidal or sea currents etc. (7) "OUS Method" refers to the inventory for FY07 that is similar

  3. [Page Intentionally Left Blank] Life Cycle Greenhouse Gas Emissions from

    E-Print Network [OSTI]

    Reuter, Martin

    ..........................................................................11 4.2 Conventional Jet Fuel from Crude Oil2 June #12;[Page Intentionally Left Blank] #12;Life Cycle Greenhouse Gas Emissions from Alternative .......................................5 3.1 Life cycle Greenhouse Gas Emissions

  4. Delaware Greenhouse Gas Reduction Projects Grant Program (Delaware)

    Broader source: Energy.gov [DOE]

    The Delaware Greenhouse Gas Reduction Projects Grant Program is funded by the Greenhouse Gas Reduction Projects Fund, established by the Act to Amend Title 7 of the Delaware Code Relating to a...

  5. CO2-Driven Enhanced Gas Recovery and Storage in Depleted Shale Reservoir-A Numerical Simulation Study

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    injection into saline aquifer, CO2-EOR, CO2-ECBM, and so forth, have been studied to minimize the CO22-EOR, CO2-ECBM, and so forth, have been studied to minimize the CO2 release into the atmosphere1 CO2-Driven Enhanced Gas Recovery and Storage in Depleted Shale Reservoir- A Numerical Simulation

  6. Graduate Opportunities in Atmospheric Modeling to Understand Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Lin, John Chun-Han

    Graduate Opportunities in Atmospheric Modeling to Understand Greenhouse Gas Emissions University://www.atmos.utah.edu/) seeks multiple graduate students to study greenhouse gas emissions associated with urban development greenhouse gas emissions. Samples of guiding questions as part of the projects include: · What can explain

  7. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31T23:59:59.000Z

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris CO2 capture membrane was scaled up with MTRs commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Services Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  8. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623Primary MetalsOrigin State Glossary

  9. Clouds in the atmospheres of extrasolar planets. IV. On the scattering greenhouse effect of CO2 ice particles: Numerical radiative transfer studies

    E-Print Network [OSTI]

    Kitzmann, D; Rauer, H

    2013-01-01T23:59:59.000Z

    Owing to their wavelengths dependent absorption and scattering properties, clouds have a strong impact on the climate of planetary atmospheres. Especially, the potential greenhouse effect of CO2 ice clouds in the atmospheres of terrestrial extrasolar planets is of particular interest because it might influence the position and thus the extension of the outer boundary of the classic habitable zone around main sequence stars. We study the radiative effects of CO2 ice particles obtained by different numerical treatments to solve the radiative transfer equation. The comparison between the results of a high-order discrete ordinate method and simpler two-stream approaches reveals large deviations in terms of a potential scattering efficiency of the greenhouse effect. The two-stream methods overestimate the transmitted and reflected radiation, thereby yielding a higher scattering greenhouse effect. For the particular case of a cool M-type dwarf the CO2 ice particles show no strong effective scattering greenhouse eff...

  10. Gas-phase CO2 emission toward Cepheus A East: the result of shock activity?

    E-Print Network [OSTI]

    P. Sonnentrucker; E. Gonzlez-Alfonso; D. A. Neufeld; E. A. Bergin; G. J. Melnick; W. J. Forrest; J. L. Pipher; D. M. Watson

    2006-09-05T23:59:59.000Z

    We report the first detection of gas-phase CO2 emission in the star-forming region Cepheus A East, obtained by spectral line mapping of the v2 bending mode at 14.98 micron with the Infrared Spectrograph (IRS) instrument onboard the Spitzer Space Telescope. The gaseous CO2 emission covers a region about 35'' x 25'' in extent, and results from radiative pumping by 15 micron continuum photons emanating predominantly from the HW2 protostellar region. The gaseous CO2 exhibits a temperature distribution ranging from 50 K to 200 K. A correlation between the gas-phase CO2 distribution and that of H2 S(2), a tracer of shock activity, indicates that the CO2 molecules originate in a cool post-shock gas component associated with the outflow powered by HW2. The presence of CO2 ice absorption features at 15.20 micron toward this region and the lack of correlation between the IR continuum emission and the CO2 gas emission distribution further suggest that the gaseous CO2 molecules are mainly sputtered off grain mantles -- by the passage of slow non-dissociative shocks with velocities of 15-30 km/s -- rather than sublimated through grain heating.

  11. Greenhouse Gas Management Program Overview (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-11-01T23:59:59.000Z

    Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluorocarbons (PFCs), hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF{sub 6}). Human activities have caused a rapid increase in GHG concentrations. This rising level contributes to global climate change, which contributes to environmental and public health problems.

  12. Evaluating greenhouse gas emissions inventories for agricultural burning using satellite observations of active fires

    E-Print Network [OSTI]

    Lin, Hsiao-Wen; Jin, Yufang; Giglio, Louis; Foley, Jonathan A; Randerson, James T

    2012-01-01T23:59:59.000Z

    2729 in T. Wirth, editor. Inventory of U.S. greenhouse gasfor national greenhouse gas inventories. Volume 2.National Greenhouse Gas Inventories Programme Task Force

  13. Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics

    E-Print Network [OSTI]

    Gerlich, Gerhard

    2007-01-01T23:59:59.000Z

    The atmospheric greenhouse effect, an idea that authors trace back to the traditional works of Fourier 1824, Tyndall 1861 and Arrhenius 1896 and is still supported in global climatology essentially describes a fictitious mechanism in which a planetary atmosphere acts as a heat pump driven by an environment that is radiatively interacting with but radiatively equilibrated to the atmospheric system. According to the second law of thermodynamics such a planetary machine can never exist. Nevertheless, in almost all texts of global climatology and in a widespread secondary literature it is taken for granted that such mechanism is real and stands on a firm scientific foundation. In this paper the popular conjecture is analyzed and the underlying physical principles are clarified. By showing that (a) there are no common physical laws between the warming phenomenon in glass houses and the fictitious atmospheric greenhouse effects, (b) there are no calculations to determine an average surface temperature of a planet, ...

  14. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01T23:59:59.000Z

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  15. Improving UK greenhouse gas emission estimates using tall tower observations

    E-Print Network [OSTI]

    Howie, James Edward

    2014-06-30T23:59:59.000Z

    Greenhouse gases in the Earths atmosphere play an important role in regulating surface temperatures. The UK is signatory to international agreements that legally commit the UK to reduce its greenhouse gas emissions, and ...

  16. Combined-cycle solarised gas turbine with steam, organic and CO2 bottoming cycles

    E-Print Network [OSTI]

    Combined-cycle solarised gas turbine with steam, organic and CO2 bottoming cycles John Pye, Keith of the technical feasibility a solarised combined-cycle gas turbines with a dish concentrator, with several, optimised for the new SG4 collector. This study aims to determine whether a combined-cycle gas turbine (CCGT

  17. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-08-15T23:59:59.000Z

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and not only by PV during sunny on-peak hours.

  18. Computational investigation of thermal gas separation for CO2 capture.

    SciTech Connect (OSTI)

    Gallis, Michail A.; Bryan, Charles R.; Brady, Patrick Vane; Torczynski, John Robert; Brooks, Carlton, F.

    2009-09-01T23:59:59.000Z

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 09-1351, 'Computational Investigation of Thermal Gas Separation for CO{sub 2} Capture'. Thermal gas separation for a binary mixture of carbon dioxide and nitrogen is investigated using the Direct Simulation Monte Carlo (DSMC) method of molecular gas dynamics. Molecular models for nitrogen and carbon dioxide are developed, implemented, compared to theoretical results, and compared to several experimental thermophysical properties. The molecular models include three translational modes, two fully excited rotational modes, and vibrational modes, whose degree of excitation depends on the temperature. Nitrogen has one vibrational mode, and carbon dioxide has four vibrational modes (two of which are degenerate). These models are used to perform a parameter study for mixtures of carbon dioxide and nitrogen confined between parallel walls over realistic ranges of gas temperatures and nominal concentrations of carbon dioxide. The degree of thermal separation predicted by DSMC is slightly higher than experimental values and is sensitive to the details of the molecular models.

  19. The Greenhouse Gas Protocol Initiative: Allocation of Emissions...

    Open Energy Info (EERE)

    Allocation of Emissions from a Combined Heat and Power Plant Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol Initiative: Allocation of...

  20. Navigating the Numbers: Greenhouse Gas Data and International...

    Open Energy Info (EERE)

    Name: Navigating the Numbers: Greenhouse Gas Data and International Climate Policy AgencyCompany Organization: World Resources Institute Sector: Energy, Land Topics:...

  1. Verifying Greenhouse Gas Emissions: Methods to Support International...

    Open Energy Info (EERE)

    Greenhouse Gas Emissions: Methods to Support International Climate Agreements AgencyCompany Organization: Board on Atmospheric Sciences and Climate Sector: Energy, Land...

  2. Energy Department Assisting Launch of Low Greenhouse Gas-Emitting...

    Broader source: Energy.gov (indexed) [DOE]

    Launch of Low Greenhouse Gas-Emitting Jet Fuels Crow Nation Students Participate in Algae Biomass Research Project Secretary Chu Announces 100 Million for Advanced Research...

  3. DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas...

    Energy Savers [EERE]

    greenhouse gas emissions - the technology component of a comprehensive U.S. approach to climate change. The technologies developed under the Climate Change Technology program...

  4. Greenhouse Gas Guidance and Reporting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and manage their greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change. Federal Guidance Read the White House Council on Environmental Quality's...

  5. Costa Rica-Mitigation of Greenhouse Gas Emissions through Avoided...

    Open Energy Info (EERE)

    Avoided Deforestation of Tropical Rainforests on Privately-owned Lands in High Conservation Value Areas Jump to: navigation, search Name Costa Rica-Mitigation of Greenhouse Gas...

  6. South Africa - Greenhouse Gas Emission Baselines and Reduction...

    Open Energy Info (EERE)

    Potentials from Buildings Jump to: navigation, search Name South Africa - Greenhouse Gas Emission Baselines and Reduction Potentials from Buildings AgencyCompany Organization...

  7. The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased...

    Open Energy Info (EERE)

    Purchased Electricity Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased Electricity AgencyCompany...

  8. Analysis of U.S. Greenhouse Gas Tax Proposals

    E-Print Network [OSTI]

    Metcalf, Gilbert E.

    The U.S. Congress is considering a set of bills designed to limit the nations greenhouse gas (GHG)

  9. Greenhouse Gas Emissions Impacts of Liberalizing Trade in Environmenta...

    Open Energy Info (EERE)

    Goods Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Greenhouse Gas Emissions Impacts of Liberalizing Trade in Environmental Goods AgencyCompany...

  10. Greenhouse Gas Emissions from Aviation and Marine Transportation...

    Open Energy Info (EERE)

    and Policies Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potentials and Policies...

  11. NETL - Petroleum-Based Fuels Life Cycle Greenhouse Gas Analysis...

    Open Energy Info (EERE)

    - Petroleum-Based Fuels Life Cycle Greenhouse Gas Analysis 2005 Baseline Model Jump to: navigation, search Tool Summary LAUNCH TOOL Name: NETL - Petroleum-Based Fuels Life Cycle...

  12. Survey Employees to Evaluate Greenhouse Gas Emissions Profile for Commuting

    Broader source: Energy.gov [DOE]

    For evaluating a greenhouse gas (GHG) profile for employee commuting, data on behavior and attitudes are best collected through an agency-wide survey.

  13. Federal Agency Progress Toward Greenhouse Gas Reduction Targets

    Broader source: Energy.gov [DOE]

    Excel spreadsheet shows overall government and federal agency reductions in scope 1 and 2 greenhouse gas (GHG) emissions and in indirect scope 3 GHG emissions categories.

  14. Mexico - Greenhouse Gas Emissions Baselines and Reduction Potentials...

    Open Energy Info (EERE)

    Baselines and Reduction Potentials from Buildings Jump to: navigation, search Name Mexico - Greenhouse Gas Emissions Baselines and Reduction Potentials from Buildings Agency...

  15. Hybrid heat exchange for the compression capture of CO2 from recirculated flue gas

    SciTech Connect (OSTI)

    Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.

    2004-01-01T23:59:59.000Z

    An approach proposed for removal of CO2 from flue gas cools and compresses a portion of a recirculated flue-gas stream, condensing its volatile materials for capture. Recirculating the flue gas concentrates SOx, H2O and CO2 while dramatically reducing N2 and NOx, enabling this approach, which uses readily available industrial components. A hybrid system of indirect and direct-contact heat exchange performs heat and mass transfer for pollutant removal and energy recovery. Computer modeling and experimentation combine to investigate the thermodynamics, heat and mass transfer, chemistry and engineering design of this integrated pollutant removal (IPR) system.

  16. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    per kWh), but that CO2 emissions from hydropower plantswill be less than CO2 emissions from fossil-fuel plants.kg/ha) 2. Difference in CO2 emissions vs. control plot (kg/

  17. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    SciTech Connect (OSTI)

    Greenblatt, Jeffery B.

    2013-10-10T23:59:59.000Z

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants, targets were less well-defined, but while all three scenarios were able to make significant reductions in ROG, NOx and PM2.5 both statewide and in the two regional air basins, they may nonetheless fall short of what will be required by future federal standards. Specifically, in Scenario 1, regional NOx emissions are approximately three times the estimated targets for both 2023 and 2032, and in Scenarios 2 and 3, NOx emissions are approximately twice the estimated targets. Further work is required in this area, including detailed regional air quality modeling, in order to determine likely pathways for attaining these stringent targets.

  18. Reduced Regeneration Energy CO2 Adsorbent | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest RegionatSearch Welcome to theNewsCenterandGas SeparationsRelevant to

  19. Biomimetic Membrane for CO2 Capture from Flue Gas

    SciTech Connect (OSTI)

    Michael C. Trachtenberg

    2007-05-31T23:59:59.000Z

    These Phase III experiments successfully addressed several issues needed to characterize a permeator system for application to a pulverized coal (PC) burning furnace/boiler assuming typical post-combustion cleanup devices in place. We completed key laboratory stage optimization and modeling efforts needed to move towards larger scale testing. The SOPO addressed six areas. Task 1--Post-Combustion Particle Cleanup--The first object was to determine if the Carbozyme permeator performance was likely to be reduced by particles (materials) in the flue gas stream that would either obstruct the mouth of the hollow fibers (HF) or stick to the HF bore wall surface. The second, based on the Acceptance Standards (see below), was to determine whether it would be preferable to clean the inlet gas stream (removing acid gases and particulates) or to develop methods to clean the Carbozyme permeator if performance declined due to HF block. We concluded that condensation of particle and particulate emissions, in the heat exchanger, could result in the formation of very sticky sulfate aerosols with a strong likelihood of obtruding the HF. These must be managed carefully and minimized to near-zero status before entering the permeator inlet stream. More extensive post-combustion cleanup is expected to be a necessary expense, independent of CO{sub 2} capture technology This finding is in agreement with views now emerging in the literature for a variety of CO{sub 2} capture methods. Task 2--Water Condensation--The key goal was to monitor and control temperature distributions within the permeator and between the permeator and its surroundings to determine whether water condensation in the pores or the HF bore would block flow, decreasing performance. A heat transfer fluid and delivery system were developed and employed. The result was near isothermal performance that avoided all instances of flow block. Direct thermocouple measurements provided the basis for developing a heat transfer model that supports prediction of heat transfer profiles for larger permeators Tasks 3. 4.1, 4.2--Temperature Range of Enzymes--The goal was to determine if the enzyme operating temperature would limit the range of thermal conditions available to the capture system. We demonstrated the ability of various isozymes (enzyme variants) to operate from 4-85 C. Consequently, the operating characteristics of the enzyme are not a controlling factor. Further, any isozyme whose upper temperature bound is at least 10 C greater than that of the planned inlet temperature will be stable under unanticipated, uncontrolled 'hiccups' in power plant operation. Task 4.4, 4.4--Examination of the Effects of SOx and NOx on Enzyme Activity (Development of Flue Gas Composition Acceptance Standards)--The purpose was to define the inlet gas profile boundaries. We examined the potential adverse effects of flue gas constituents including different acids from to develop an acceptance standard and compared these values to actual PC flue gas composition. Potential issues include changes in pH, accumulation of specific inhibitory anions and cations. A model was developed and validated by test with a SO{sub 2}-laden stream. The predicted and actual data very largely coincided. The model predicted feed stream requirements to allow continuous operation in excess of 2500 hours. We developed operational (physical and chemical) strategies to avoid or ameliorate these effects. Avoidance, the preferred strategy (noted above), is accomplished by more extensive cleanup of the flue gas stream. Task 5--Process Engineering Model--We developed a process-engineering model for two purposes. The first was to predict the physical and chemical status at each test point in the design as a basis for scale-up. The second was to model the capital and operating cost of the apparatus. These were accomplished and used to predict capex, opex and cost of energy. Task 6--Preliminary Commercialization Plan--We carried out analyses of the market and the competition by a variety of parameters. The conclusion was that there is a l

  20. Selection of coals of different maturities for CO2 Storage by modelling of CH4 and CO2 adsorption isotherms

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of this study is to compare and model pure gas sorption isotherms (CO2 and CH4) for well-characterised coals of different maturities to determine the most suitable coal for CO2 storage. Carbon dioxide and methane; Coals; Methane and carbon dioxide adsorption; Modelling isotherms 1. Introduction CO2 is a greenhouse

  1. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  2. GHG Emissions from Hydropower Reservoirs The role of hydropower reservoirs in contributing to greenhouse gas (GHG) emissions is poorly

    E-Print Network [OSTI]

    to characterize carbon dioxide (CO2) and methane (CH4) emissions from hydropower reservoirs in the US SoutheastGHG Emissions from Hydropower Reservoirs The role of hydropower reservoirs in contributing to greenhouse gas (GHG) emissions is poorly understood, but recent studies have indicated that GHG emissions

  3. Spatial and temporal variability of annual greenhouse gas fluxes from a constructed wetland in an arid region

    E-Print Network [OSTI]

    Hall, Sharon J.

    (CO2). - Many constructed treatment wetland systems (CWS) have been developed to remove nutrients fromSpatial and temporal variability of annual greenhouse gas fluxes from a constructed wetland of Sustainability, 3Wetland Ecosystem Ecology Lab, Arizona State University, Tempe, AZ, USA. - Wetlands support

  4. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31T23:59:59.000Z

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

  5. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    SciTech Connect (OSTI)

    Zoback, Mark; Kovscek, Anthony; Wilcox, Jennifer

    2013-09-30T23:59:59.000Z

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  6. PG&E's Renewable Portfolio Standard & Greenhouse Gas Compliance

    E-Print Network [OSTI]

    PG&E's Renewable Portfolio Standard & Greenhouse Gas Compliance Fong Wan Senior Vice President, Energy Procurement 9/5/13 California Power Markets Symposium #12;1. PG&E Renewable Portfolio Standard 2. AB32 and Greenhouse Gas Legislation Outline #12;PG&E's Electric Generation Portfolio *Note: Other

  7. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30T23:59:59.000Z

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  8. Weigel, Southworth, and Meyer 1 Calculators for Estimating Greenhouse Gas Emissions from Public

    E-Print Network [OSTI]

    Weigel, Southworth, and Meyer 1 Calculators for Estimating Greenhouse Gas Emissions from Public Greenhouse Gas Emissions from Public Transit Agency Vehicle Fleet Operations ABSTRACT This paper reviews calculation tools available for quantifying the greenhouse gas emissions associated with different types

  9. CO2 gas/oil ratio prediction in a multi-component reservoir by combined seismic and electromagnetic imaging

    E-Print Network [OSTI]

    Hoversten, G.M.; Gritto, Roland; Washbourne, John; Daley, Tom

    2002-01-01T23:59:59.000Z

    CO 2 flooding of an oil reservoir are inverted to producein a complex reservoir containing oil, water, hydrocarbonincluding oil, water and gas) and reservoir pressure. The

  10. CO2 gas production understanding above a partly flooded coal post-mining area

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    - The Westphalian deposit is constituted by numerous exploited coal seams of different thicknesses. These seamsCO2 gas production understanding above a partly flooded coal post-mining area Candice Lagnya, a former coal mining area. To understand the origin of this production, a borehole of 90 meters deep

  11. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01T23:59:59.000Z

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the as built design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  12. Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced

    SciTech Connect (OSTI)

    Kara G. Cafferty; Erin M. Searcy; Long Nguyen; Sabrina Spatari

    2014-11-01T23:59:59.000Z

    To meet Energy Independence and Security Act (EISA) cellulosic biofuel mandates, the United States will require an annual domestic supply of about 242 million Mg of biomass by 2022. To improve the feedstock logistics of lignocellulosic biofuels and access available biomass resources from areas with varying yields, commodity systems have been proposed and designed to deliver on-spec biomass feedstocks at preprocessing depots, which densify and stabilize the biomass prior to long-distance transport and delivery to centralized biorefineries. The harvesting, preprocessing, and logistics (HPL) of biomass commodity supply chains thus could introduce spatially variable environmental impacts into the biofuel life cycle due to needing to harvest, move, and preprocess biomass from multiple distances that have variable spatial density. This study examines the uncertainty in greenhouse gas (GHG) emissions of corn stover logisticsHPL within a bio-ethanol supply chain in the state of Kansas, where sustainable biomass supply varies spatially. Two scenarios were evaluated each having a different number of depots of varying capacity and location within Kansas relative to a central commodity-receiving biorefinery to test GHG emissions uncertainty. Monte Carlo simulation was used to estimate the spatial uncertainty in the HPL gate-to-gate sequence. The results show that the transport of densified biomass introduces the highest variability and contribution to the carbon footprint of the logistics HPL supply chain (0.2-13 g CO2e/MJ). Moreover, depending upon the biomass availability and its spatial density and surrounding transportation infrastructure (road and rail), logistics HPL processes can increase the variability in life cycle environmental impacts for lignocellulosic biofuels. Within Kansas, life cycle GHG emissions could range from 24 to 41 g CO2e/MJ depending upon the location, size and number of preprocessing depots constructed. However, this range can be minimized through optimizing the siting of preprocessing depots where ample rail infrastructure exists to supply biomass commodity to a regional biorefinery supply system

  13. CO2 Sequestration short course

    SciTech Connect (OSTI)

    DePaolo, Donald J. [Lawrence Berkeley National Laboratory; Cole, David R [The Ohio State University; Navrotsky, Alexandra [University of California-Davis; Bourg, Ian C [Lawrence Berkeley National Laboratory

    2014-12-08T23:59:59.000Z

    Given the publics interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  14. Nuclear Power PROS -`No' greenhouse gas emissions

    E-Print Network [OSTI]

    Toohey, Darin W.

    uranium hexafluoride reacting with moisture in air creates the immediate danger of HF hydrogen fluoride or ammonia; hydrofluoric acid is also used in the conversion process) -CO2 emissions involved in mining gases / acid rain: emits Hg, CO2, CO, SOx, NOx (there are pollution controls on SOx and Hg which makes

  15. E-Print Network 3.0 - anthropogenic greenhouse-gas forcings Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geosciences ; Environmental Sciences and Ecology 12 European Greenhouse Gas Emissions Trading: A System in Transition* Summary: European Greenhouse Gas Emissions Trading: A...

  16. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis...

    Broader source: Energy.gov (indexed) [DOE]

    Manufacturing Energy Use and Greenhouse Gas Emissions Analysis, November 2012 U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis, November 2012 The report ranks...

  17. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumbenergyuselossemissionslg.gif How...

  18. Greenhouse Gas Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in the lower atmosphere that trap heat through a natural process called the "greenhouse effect." This process keeps the planet habitable. International research has linked...

  19. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30T23:59:59.000Z

    The United States wishes to decrease foreign energy dependence by utilizing the countrys significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  20. Estonian greenhouse gas emissions inventory report

    SciTech Connect (OSTI)

    Punning, J.M.; Ilomets, M.; Karindi, A.; Mandre, M.; Reisner, V. [Inst. of Ecology, Tallinn (Estonia); Martins, A.; Pesur, A. [Inst. of Energy Research, Tallinn (Estonia); Roostalu, H.; Tullus, H. [Estonian Agricultural Univ., Tartu (Estonia)

    1996-07-01T23:59:59.000Z

    It is widely accepted that the increase of greenhouse gas concentrations in the atmosphere due to human activities would result in warming of the Earth`s surface. To examine this effect and better understand how the GHG increase in the atmosphere might change the climate in the future, how ecosystems and societies in different regions of the World should adapt to these changes, what must policymakers do for the mitigation of that effect, the worldwide project within the Framework Convention on Climate Change was generated by the initiative of United Nations. Estonia is one of more than 150 countries, which signed the Framework Convention on Climate Change at the United Nations Conference on Environment and Development held in Rio de Janeiro in June 1992. In 1994 a new project, Estonian Country Study was initiated within the US Country Studies Program. The project will help to compile the GHG inventory for Estonia, find contemporary trends to investigate the impact of climate change on the Estonian ecosystems and economy and to formulate national strategies for Estonia addressing to global climate change.

  1. Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study

    SciTech Connect (OSTI)

    Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

    2012-05-03T23:59:59.000Z

    It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

  2. What does stabilizing greenhouse gas concentrations mean?

    E-Print Network [OSTI]

    Jacoby, Henry D.; Schmalensee, Richard.; Reiner, David M.

    The MIT Emissions Prediction and Policy Analysis (EPPA) model is applied to an exploration of the national emissions obligations that would be required to stabilize atmospheric CO2 concentrations at levels now under active ...

  3. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    , . promoter . 1.2 CO2 HBGS process CO2 , CO2 . CO2 , IGCC (Integrated Gasification Combined Cycle) (fuel gas) CO2 . IGCC CO2 H2 . (gasification) CO H2 (water gas shift reaction) H2 CO CO2 . CO2 H2 turbine H2 . H2 , CO2 #12;. fuel gas CO2 40%, 60% H2 . fuel gas (gasification) HBGS process . CO2 CO2 . venture

  4. Biochar amendment and greenhouse gas emissions from agricultural soils

    E-Print Network [OSTI]

    Case, Sean Daniel Charles

    2013-11-28T23:59:59.000Z

    The aim of this study was to investigate the effects of biochar amendment on soil greenhouse gas (GHG) emissions and to elucidate the mechanisms behind these effects. I investigated the suppression of soil carbon dioxide ...

  5. Interagency Pilot of Greenhouse Gas Accounting Tools: Lessons Learned

    SciTech Connect (OSTI)

    Carpenter, A.; Hotchkiss, E.; Kandt, A.

    2013-02-01T23:59:59.000Z

    The Greater Yellowstone Area (GYA) and Tongass National Forest (Tongass) partnered with the National Renewable Energy Laboratory (NREL) to conduct a pilot study of three greenhouse gas (GHG) inventorying tools.

  6. Greenhouse Gas Programs, Energy Efficiency, and the Industrial Sector

    E-Print Network [OSTI]

    Zhou, A.; Tutterow, V.; Harris, J.

    The United States has made significant progress in reducing total energy use through energy efficiency improvements over the past decade, yet the United States still ranks as the highest absolute greenhouse gas (GHG) emitter in the world with 23...

  7. Secretary of Energy Memorandum on DOE Greenhouse Gas Emission...

    Office of Environmental Management (EM)

    to a low-carbon economy. We must also lead by example in reducing greenhouse gas emissions associated with our own operations and facilities. On October 5,2009, the...

  8. Impacts of greenhouse gas mitigation policies on agricultural land

    E-Print Network [OSTI]

    Wang, Xiaodong, Ph. D. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    Greenhouse gas (GHG) emissions are widely acknowledged to be responsible for much of the global warming in the past century. A number of approaches have been proposed to mitigate GHG emissions. Since the burning of ...

  9. Fiscal Year 2012 Greenhouse Gas Inventory: Government Totals

    Broader source: Energy.gov [DOE]

    Excel spreadsheet shows scope 1, 2, and 3 greenhouse gas inventories reported by federal agencies in fiscal year 2012. It includes emissions from sources not subject to the reduction targets.

  10. Detection of Greenhouse-Gas-Induced Climatic Change

    SciTech Connect (OSTI)

    Jones, P.D.; Wigley, T.M.L.

    1998-05-26T23:59:59.000Z

    The objective of this report is to assemble and analyze instrumental climate data and to develop and apply climate models as a basis for (1) detecting greenhouse-gas-induced climatic change, and (2) validation of General Circulation Models.

  11. Deep cuts in household greenhouse gas emissions Andrew Blakers

    E-Print Network [OSTI]

    Deep cuts in household greenhouse gas emissions Andrew Blakers Director, Centre for Sustainable Energy Systems Australian National University Ph 61 2 6125 5905 Andrew.blakers@anu.edu.au Web: http

  12. Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31T23:59:59.000Z

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  13. Greenhouse Gas Inventory and Registry (Iowa)

    Broader source: Energy.gov [DOE]

    The Iowa Department of Natural Resources is required to establish a method for collecting emissions estimates from producers of greenhouse gases. Reporting is mandatory for some entities, and the...

  14. Large Greenhouse Gas Emissions from a Temperate Peatland Pasture

    E-Print Network [OSTI]

    Kelly, Maggi

    as a by product of the conversion of organic sediment into oil, so natural gas deposits usually are found is CO2. There are important other drivers: · methane (contributes to warming, one molecule of CH4 fossil fuels (coal, oil, natural gas) to produce energy. Almost all energy on earth ultimately comes from

  15. Detection of greenhouse-gas-induced climatic change

    SciTech Connect (OSTI)

    Wigley, T.M.L.; Jones, P.D.

    1992-07-15T23:59:59.000Z

    The aims of the US Department of Energy's Carbon Dioxide Research Program are to improve assessments of greenhouse-gas-induced climatic change and to define and reduce uncertainties through selected research. This project will address: The regional and seasonal details of the expected climatic changes; how rapidly will these changes occur; how and when will the climatic effects of CO[sub 2] and other greenhouse gases be first detected; and the relationships between greenhouse-gas-induced climatic change and changes caused by other external and internal factors. The present project addresses all of these questions. Many of the diverse facets of greenhouse-gas-related climate research can be grouped under three interlinked subject areas: modeling, first detection and supporting data. This project will include the analysis of climate forcing factors, the development and refinement of transient response climate models, and the use of instrumental data in validating General Circulation Models (GCMs).

  16. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01T23:59:59.000Z

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  17. Mixed Ionic and Electronic Conduction in Li3PO4 Electrolyte for a CO2 Gas Sensor

    E-Print Network [OSTI]

    Dutta, Prabir K.

    equilib- rium potential types, are most promising for CO2 monitoring among the solid-state and Measurements, The Ohio State University, Columbus, Ohio 43210, USA An electrochemical CO2 gas sensor using Li2. Because Li3PO4 electrolyte has been fabricated as a Lipon glass thin film in battery applications,14

  18. Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power

    E-Print Network [OSTI]

    Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power Over the last thirty years, moreMineLand Rehabilitation · PowerGeneration · System/PlantOperation andMaintenance · AuxiliaryNaturalGas Combustion · Coal-scale concentrating solar power (CSP) systems. These LCAs have yielded wide-ranging results. Variation could

  19. Greenhouse gas emissions of biofuels, Improving Life Cycle Assessments by taking into

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Greenhouse gas emissions of biofuels, Improving Life Cycle Assessments by taking into account local.......................................................................................................................................................14 Chapter 1 Biofuels, greenhouse gases and climate change 1 Introduction

  20. College Of Wooster 2012 Greenhouse Gas Emissions From Coal and Natural Gas Combustion Default Values From EPA Greenhouse Gas Rule

    E-Print Network [OSTI]

    Wilson, Mark A.

    56410 CO2 = 1 X 10 -3 X Fuel X HHV X EF Where CO2 = Annual CO2 mass emissions for the specific fuel type high heat value. EF =Fuel default CO2 Emission Factor from Table C-1Page 56410 CO2 Coal CO2 = 1 X 10 -3 Default CO2 Emission Factor For Bituminous Coal = 93.40 kg/mmbtu Default CH4 Emission Factor

  1. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05T23:59:59.000Z

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions. These technology pathways (which are described in greater detail in Appendix B, Technology Pathways) address three areas: energy efficiency, clean energy, and carbon sequestration (removing carbon from emissions and enhancing carbon storage). Based on an assessment of each of these technology pathways over a 30-year planning horizon, the directors of the Department of Energy's (DOE's) national laboratories conclude that success will require pursuit of multiple technology pathways to provide choices and flexibility for reducing greenhouse gas emissions. Advances in science and technology are necessary to reduce greenhouse gas emissions from the United States while sustaining economic growth and providing collateral benefits to the nation.

  2. Oxidation in Environments with Elevated CO2 Levels

    SciTech Connect (OSTI)

    Gordon H. Holcomb

    2009-05-01T23:59:59.000Z

    Efforts to reduce greenhouse gas emissions from fossil energy power productions focus primarily on either pre- or post-combustion removal of CO2. The research presented here examines corrosion and oxidation issues associated with two types of post-combustion CO2 removal processesoxyfuel combustion in refit boilers and oxyfuel turbines.

  3. CO2 Enhanced Oil Recovery Feasibility Evaluation for East Texas Oil Field

    E-Print Network [OSTI]

    Lu, Ping

    2012-08-31T23:59:59.000Z

    Carbon dioxide enhanced oil recovery (CO2-EOR) has been undergoing for four decades and is now a proven technology. CO2-EOR increases oil recovery, and in the meantime reduces the greenhouse gas emissions by capture CO2 underground. The objectives...

  4. NREL: Sustainable NREL - Greenhouse Gas Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions andData and Resources NREL resourceEnergy Systems IntegrationGreenhouse

  5. Airborne greenhouse gas (GHG) measurements provide essential constraints for estimating surface emissions. Until recently, dedicated research-grade instruments have been required

    E-Print Network [OSTI]

    GHG columns · Quantifying local to regional GHG enhancements for emissions inventory verificationAbstract Airborne greenhouse gas (GHG) measurements provide essential constraints for estimating with another Cessna 210 over Central California quantified enhancements in CO2 and CH4 from urban

  6. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    T. L. e. a. Cottengim, Unaccounted-for Gas Project, Pacific1995). Determination of Unaccounted-for-Gas Distribution,publishes estimates of "unaccounted for" gas, but this is an

  7. II. Greenhouse gas markets, carbon dioxide credits and biofuels17

    E-Print Network [OSTI]

    15 II. Greenhouse gas markets, carbon dioxide credits and biofuels17 The previous chapter analysed biofuels production. GHG policies18 that create a carbon price either through an emissions trading system or directly by taxing GHG emissions also generate increased demand for biofuels. They do so by raising

  8. U.S. Agriculture's Role Greenhouse Gas Emission Mitigation World

    E-Print Network [OSTI]

    McCarl, Bruce A.

    U.S. Agriculture's Role in a Greenhouse Gas Emission Mitigation World: An Economic Perspective and Research Associate, respectively, Department of Agricultural Economics, Texas A&M University. Seniority of Authorship is shared. This research was supported by the Texas Agricultural Experiment Station through

  9. Land Use Greenhouse Gas Emissions from Conventional Oil

    E-Print Network [OSTI]

    Turetsky, Merritt

    emissions of California crude and in situ oil sands production (crude refineryLand Use Greenhouse Gas Emissions from Conventional Oil Production and Oil Sands S O N I A Y E H and Alberta as examples for conventional oil production as well as oil sands production in Alberta

  10. An Assessment of Greenhouse Gas Emissions-Weighted

    E-Print Network [OSTI]

    Economic Analysis ­ Greenhouse Gas Emissions Prepared by Hawai`i Natural Energy Institute School of Ocean and Earth Science and Technology University of Hawai`i And University of Hawai`i Economic Research, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned

  11. California's Greenhouse Gas Policies: How Do They Add Up?

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    regulations, aimed, for instance, at altering electricity fuel choice, household energy use, and automotive California is implementing a broad portfolio of regulations aimed at reducing greenhouse gas emissions. However, many of these policies, if undertaken without the cooperation of neighboring states may result

  12. The Agricultural Sector and Greenhouse Gas Mitigation Model (ASMGHG)

    E-Print Network [OSTI]

    McCarl, Bruce A.

    ...................................................................................37 3.5.1.1 Direct Carbon Emissions Through Fossil Fuel Use.....................38 3.5.1.2 Indirect.5.2.2 Production of Fossil Fuel Substitutes...........................................49 3.5.2.3 Conversion Taxes and Sequestration Subsidies...............................66 3.8.2.4 Special Greenhouse Gas

  13. Determining Air Quality and Greenhouse Gas Impacts of

    E-Print Network [OSTI]

    Dabdub, Donald

    Determining Air Quality and Greenhouse Gas Impacts of Hydrogen Infrastructure and Fuel Cell of hydrogen infrastructure and hydrogen fuel cell vehicles (HFCVs) to replace gasoline internal combustion generation and the other includes more fossil fuel sources. The two scenarios encompass a variety of hydrogen

  14. Greenhouse gas emissions from cultivation of energy crops may affect the sustainability of biofuels.

    E-Print Network [OSTI]

    Ambus, Per

    2011-01-01T23:59:59.000Z

    ??Agro-biofuels are expected to reduce the emissions of greenhouse gases because CO2 emitted during the combustion of the biofuels has recently been taken from the (more)

  15. Energy and Greenhouse Gas Impacts of Biofuels: A Framework for Analysis

    E-Print Network [OSTI]

    Kammen, Daniel M.; Farrell, Alexander E; Plevin, Richard J; Jones, Andrew; Nemet, Gregory F; Delucchi, Mark

    2008-01-01T23:59:59.000Z

    Greenhouse Gas Impacts of Biofuels Wang, M. (2001) "Energy & Greenhouse Gas Impacts of Biofuels Fuels and MotorLifecycle Analysis of Biofuels." Report UCD-ITS-RR-06-08.

  16. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric...

  17. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck...

  18. Idaho National Laboratorys Greenhouse Gas FY08 Baseline

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2011-06-01T23:59:59.000Z

    A greenhouse gas (GHG) inventory is a systematic attempt to account for the production and release of certain gasses generated by an institution from various emission sources. The gasses of interest are those which have become identified by climate science as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2008 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. Concern about the environmental impact of GHGs has grown in recent years. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of a baseline estimate of total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions in the future, and such documentation will require knowledge of a baseline against which reductions can be measured. INL's FY08 GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three Scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL's organizational boundaries but are a consequence of INL's activities). This inventory found that INL generated a total of 113,049 MT of CO2-equivalent emissions during FY08. The following conclusions were made from looking at the results of the individual contributors to INL's baseline GHG inventory: (1) Electricity (including the associated transmission and distribution losses) is the largest contributor to INL's GHG inventory, with over 50% of the CO2e emissions; (2) Other sources with high emissions were stationary combustion (facility fuels), waste disposal (including fugitive emissions from the onsite landfill and contracted disposal), mobile combustion (fleet fuels), employee commuting, and business air travel; and (3) Sources with low emissions were wastewater treatment (onsite and contracted), fugitive emissions from refrigerants, and business ground travel (in personal and rental vehicles). This report details the methods behind quantifying INL's GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by the Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only that large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  19. The Essential Role of State Enforcement in the Brave New World of Greenhouse Gas Emission Limits

    E-Print Network [OSTI]

    Bogoshian, Matt; Alex, Ken

    2009-01-01T23:59:59.000Z

    greenhouse gas emissions trading market, the Regionalwith respect to emissions trading markets. 23 We must have a

  20. SMARTTool Greenhouse Gas Inventory Report Reporting Entity: University of Northern British Columbia

    E-Print Network [OSTI]

    Northern British Columbia, University of

    Reporting Year: Calendar Year 2010 Greenhouse Gases in Tonnes Measure Quantity CO2 CH4 N2O tCO2e1 Scope 1.30 Emissions from Biomass Total Biomass Emissions 0.83 0.00 0.00 0.83 Total Emissions, Calendar Year 2010 5

  1. California's Greenhouse Gas Policies: Local Solutions to a Global Problem?

    E-Print Network [OSTI]

    Bushnell, Jim B; Peterman, Carla Joy; Wolfram, Catherine D

    2007-01-01T23:59:59.000Z

    the Path of Chinas CO2 Emissions: Offsetting Kyoto andTable 3: Growth in CO2 Emissions from Electricity by1990-2004 1990 CO2 emissions (MMT) 2004 CO2 emissions (MMT)

  2. Regional GHG Emissions Stat s Greenhouse Gas and the Regional

    E-Print Network [OSTI]

    (milliontonsCO2) Petroleum + Pet Coke Natural Gas Coal 8 0.0 10.0 20.0 1995 1996 1997 1998 1999 2000 2001 2002 and ½ Valmy coal plants) 2 #12;6/5/2013 2 GHG Emissions by Economic Sector in the Pacific Northwest (2010 Renewables 7 6%In 2011, the region 0.2% 6.4% Coal, 15.7% Nuclear, 2.0% 7.6%, g generated ~27,000 MWa ­ 68

  3. U.S. Greenhouse Gas Intensity and the Global Climate Change Initiative (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01T23:59:59.000Z

    On February 14, 2002, President Bush announced the Administrations Global Climate Change Initiative. A key goal of the Climate Change Initiative is to reduce U.S. greenhouse gas intensity by 18% over the 2002 to 2012 time frame. For the purposes of the initiative, greenhouse gas intensity is defined as the ratio of total U.S. greenhouse gas emissions to economic output.

  4. Leaf gas exchange and carbohydrate concentrations in Pinus pinaster plants subjected to elevated CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to elevated CO2 and a soil drying cycle Catherine Picon-Cochard Jean-Marc Guehl Unité de recherches en.) were acclimated for 2 years under ambient (350 ?mol mol-1)and elevated (700 ?mol mol-1) CO2 concentrations ([CO2]). In the summer of the second growing season, the plants were subjected to a soil drying

  5. Progress in Photovoltaics Research and Applications, 14:179-190, 2006 Energy Pay-Back and Life Cycle CO2 Emissions of the BOS in an

    E-Print Network [OSTI]

    Cycle CO2 Emissions of the BOS in an Optimized 3.5 MW PV Installation J.M. Mason1 , V.M. Fthenakis2 , T-cycle greenhouse gas emissions are 29 kg CO2-eq. /m2 . From field measurements, the energy payback time (EPT, energy payback, greenhouse gas emissions #12;INTRODUCTION This study is a life-cycle analysis

  6. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    combustion (N2O emissions peak with particle sizes of about 1 mm), and gas residence time within and after the fixed bed (

  7. How secure is CO2 storage? Leakage mechanisms of natural CO2 reservoirs

    E-Print Network [OSTI]

    technology available to reduce greenhouse gas emissions from large point sources such as power plants and the burial of organic rich rocks such as coal seams.2 We have compiled the first global dataset on natural CO ­ but not necessarily leaking. Figure 4: Diagram showing the state of CO2 in the studied reservoirs. Supercritical

  8. Physical and chemical effects of CO2 storage in saline aquifers of the southern North Sea

    E-Print Network [OSTI]

    Heinemann, Niklas

    2013-07-01T23:59:59.000Z

    One of the most promising mitigation strategies for greenhouse gas accumulation in the atmosphere is carbon capture and storage (CCS). Deep saline aquifers are seen as the most efficient carbon dioxide (CO2) storage sites, ...

  9. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R [eds.] [eds.

    1991-09-01T23:59:59.000Z

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  10. Life Cycle Analysis on Greenhouse Gas (GHG) Emissions of Marcellus Shale Gas Supporting Information

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Life Cycle Analysis on Greenhouse Gas (GHG) Emissions of Marcellus Shale Gas Supporting Information 1. GHG Emissions Estimation for Production of Marcellus Shale Gas 1.1 Preparation of Well Pad estimate from Columbia University shows the size of a multi-well pad of Marcellus Shale averages 20

  11. Research on Greenhouse-Gas-Induced Climate Change

    SciTech Connect (OSTI)

    Schlesinger, M. E.

    2001-07-15T23:59:59.000Z

    During the 5 years of NSF grant ATM 95-22681 (Research on Greenhouse-Gas-Induced Climate Change, $1,605,000, 9/15/1995 to 8/31/2000) we have performed work which we are described in this report under three topics: (1) Development and Application of Atmosphere, Ocean, Photochemical-Transport, and Coupled Models; (2) Analysis Methods and Estimation; and (3) Climate-Change Scenarios, Impacts and Policy.

  12. Using Coupled Harmonic Oscillators to Model Some Greenhouse Gas Molecules

    SciTech Connect (OSTI)

    Go, Clark Kendrick C.; Maquiling, Joel T. [Department of Physics, Ateneo de Manila University, Katipunan Avenue, Quezon City (Philippines)

    2010-07-28T23:59:59.000Z

    Common greenhouse gas molecules SF{sub 6}, NO{sub 2}, CH{sub 4}, and CO{sub 2} are modeled as harmonic oscillators whose potential and kinetic energies are derived. Using the Euler-Lagrange equation, their equations of motion are derived and their phase portraits are plotted. The authors use these data to attempt to explain the lifespan of these gases in the atmosphere.

  13. Idaho National Laboratory FY12 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2013-03-01T23:59:59.000Z

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2012 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho.

  14. Idaho National Laboratory's FY11 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2012-03-01T23:59:59.000Z

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2011 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho.

  15. Evaluate Greenhouse Gas Reduction Strategies for Employee Commuting

    Broader source: Energy.gov [DOE]

    This section will help agencies to determine the most visible alternatives to single occupancy vehicle (SOV) commuting at the agencies major worksites establish the number of employees that may reasonably switch to non-SOV methods and estimate the resulting impact greenhouse gas (GHG) emissions at their worksites. Learn how to: Identify relevant alternatives and supporting strategies Evaluate potential adoption of alternatives Estimate the GHG emission impact

  16. Kalman-filtered compressive sensing for high resolution estimation of anthropogenic greenhouse gas emissions from sparse measurements.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet [Carnegie Institution for Science, Stanford, CA; Michalak, Anna M. [Carnegie Institution for Science, Stanford, CA; van Bloemen Waanders, Bart Gustaaf [Sandia National Laboratories, Albuquerque NM; McKenna, Sean Andrew [IBM Research, Mulhuddart, Dublin, Ireland

    2013-09-01T23:59:59.000Z

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. The limited nature of the measured data leads to a severely-underdetermined estimation problem. If the estimation is performed at fine spatial resolutions, it can also be computationally expensive. In order to enable such estimations, advances are needed in the spatial representation of ffCO2 emissions, scalable inversion algorithms and the identification of observables to measure. To that end, we investigate parsimonious spatial parameterizations of ffCO2 emissions which can be used in atmospheric inversions. We devise and test three random field models, based on wavelets, Gaussian kernels and covariance structures derived from easily-observed proxies of human activity. In doing so, we constructed a novel inversion algorithm, based on compressive sensing and sparse reconstruction, to perform the estimation. We also address scalable ensemble Kalman filters as an inversion mechanism and quantify the impact of Gaussian assumptions inherent in them. We find that the assumption does not impact the estimates of mean ffCO2 source strengths appreciably, but a comparison with Markov chain Monte Carlo estimates show significant differences in the variance of the source strengths. Finally, we study if the very different spatial natures of biogenic and ffCO2 emissions can be used to estimate them, in a disaggregated fashion, solely from CO2 concentration measurements, without extra information from products of incomplete combustion e.g., CO. We find that this is possible during the winter months, though the errors can be as large as 50%.

  17. Observation of CH4 and other Non-CO2 Green House Gas Emissions from California

    SciTech Connect (OSTI)

    Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

    2009-01-09T23:59:59.000Z

    In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

  18. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Agency (IEA), 2004c. CO2 emissions from fuel combustion,12. Global Energy-Related CO2 Emissions by End-Use Sector,2030. Energy-Related CO2 Emissions (GtC) Transport Buildings

  19. Meta-Analysis of Estimates of Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power: Preprint

    SciTech Connect (OSTI)

    Heath, G. A.; Burkhardt, J. J.

    2011-09-01T23:59:59.000Z

    In reviewing life cycle assessment (LCA) literature of utility-scale CSP systems, this analysis focuses on clarifying central tendency and reducing variability in estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emission estimates passing screens for quality and relevance: 19 for parabolic trough technology and 17 for power tower technology. The interquartile range (IQR) of published GHG emission estimates was 83 and 20 g CO2eq/kWh for trough and tower, respectively, with medians of 26 and 38 g CO2eq/kWh. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. Compared to the published estimates, IQR was reduced by 69% and median increased by 76% for troughs. IQR was reduced by 26% for towers, and median was reduced by 34%. A second level of harmonization was applied to five well-documented trough LC GHG emission estimates, harmonizing to consistent values for GHG emissions embodied in materials and from construction activities. As a result, their median was further reduced by 5%, while the range increased by 6%. In sum, harmonization clarified previous results.

  20. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Not Available

    1997-10-01T23:59:59.000Z

    This report serves as the technology basis of a needed national climate change technology strategy, with the confidence that a strong technology R&D program will deliver a portfolio of technologies with the potential to provide very substantial greenhouse gas emission reductions along with continued economic growth. Much more is needed to define such a strategy, including identification of complementary deployment policies and analysis to support the seeping and prioritization of R&D programs. A national strategy must be based upon governmental, industrial, and academic partnerships.

  1. Greenhouse gas emissions control by economic incentives: Survey and analysis

    SciTech Connect (OSTI)

    South, D.W.; Kosobud, R.F.; Quinn, K.G.

    1991-01-01T23:59:59.000Z

    This paper presents a survey of issues and concerns raised in recent literature on the application of market-based approaches to greenhouse effect policy with an emphasis on tradeable emission permits. The potential advantages of decentralized decision-making -- cost-effectiveness or allocation efficiency, stimulation of innovations, and political feasibility are discussed. The potential difficulties of data recording, monitoring, enforcement, and of creating viable emission permit contracts and markets are examined. Special attention is given to the problem of designing a greenhouse effect policy that is cost-effective over time, a problem that has been given little attention to date. Proposals to reduce or stabilize greenhouse gas emission (especially CO{sub 2}) in the short run require high carbon tax rates or permit prices and impose heavy adjustment costs on the fossil fuel industry. A more cost-effective time path of permit prices is proposed that achieves the same long-run climate change stabilization goals. 21 refs., 3 figs.

  2. Greenhouse gas emissions control by economic incentives: Survey and analysis

    SciTech Connect (OSTI)

    South, D.W.; Kosobud, R.F.; Quinn, K.G.

    1991-12-31T23:59:59.000Z

    This paper presents a survey of issues and concerns raised in recent literature on the application of market-based approaches to greenhouse effect policy with an emphasis on tradeable emission permits. The potential advantages of decentralized decision-making -- cost-effectiveness or allocation efficiency, stimulation of innovations, and political feasibility are discussed. The potential difficulties of data recording, monitoring, enforcement, and of creating viable emission permit contracts and markets are examined. Special attention is given to the problem of designing a greenhouse effect policy that is cost-effective over time, a problem that has been given little attention to date. Proposals to reduce or stabilize greenhouse gas emission (especially CO{sub 2}) in the short run require high carbon tax rates or permit prices and impose heavy adjustment costs on the fossil fuel industry. A more cost-effective time path of permit prices is proposed that achieves the same long-run climate change stabilization goals. 21 refs., 3 figs.

  3. Evaluating greenhouse gas emissions from hydropower complexes on large rivers in Eastern Washington

    SciTech Connect (OSTI)

    Arntzen, Evan V.; Miller, Benjamin L.; O'Toole, Amanda C.; Niehus, Sara E.; Richmond, Marshall C.

    2013-03-15T23:59:59.000Z

    Water bodies, such as freshwater lakes, are known to be net emitters of carbon dioxide (CO2), and methane (CH4). In recent years, significant greenhouse gas (GHG) emissions from tropical, boreal, and mid-latitude reservoirs have been reported. At a time when hydropower is increasing worldwide, better understanding of seasonal and regional variation in GHG emissions is needed in order to develop a predictive understanding of such fluxes within man-made impoundments. We examined power-producing dam complexes within xeric temperate locations in the northwestern United States. Sampling environments on the Snake (Lower Monumental Dam Complex) and Columbia Rivers (Priest Rapids Dam Complex) included tributary, mainstem, embayment, forebay, and tailrace areas during winter and summer 2012. At each sampling location, GHG measurement pathways included surface gas flux, degassing as water passed through dams during power generation, ebullition within littoral embayments, and direct sampling of hyporheic pore-water. Measurements were also carried out in a free-flowing reach of the Columbia River to estimate unaltered conditions. Surface flux resulted in very low emissions, with reservoirs acting as a sink for CO2 (up to 262 mg m-2 d-1, which is within the range previously reported for similarly located reservoirs). Surface flux of methane remained below 1 mg CH4 m-2d-1, a value well below fluxes reported previously for temperate reservoirs. Water passing through hydroelectric projects acted as a sink for CO2 during winter and a small source during summer, with mean degassing fluxes of 117 and 4.5 t CO2 d-1, respectively. Degassing of CH4 was minimal, with mean fluxes of 3.1 10-6 and 5.6 10-4 t CH4 d-1 during winter and summer, respectively. Gas flux due to ebullition was greater in coves located within reservoirs than in coves within the free flowing Hanford Reachand CH4 flux exceeded that of CO2. Methane emissions varied widely across sampling locations, ranging from 10.5 to 1039 mg CH4 m-2 d-1, with mean fluxes of 324 mg CH4 m-2 d-1in Lower Monumental Dam reservoir and 482 mg CH4 m-2d-1 in the Priest Rapids Dam reservoir. The magnitude of methane flux due to ebullition was unexpectedly high, and falls within the range recently reported for other temperate reservoirs around the world, further suggesting that this methane source should be considered in estimates of global greenhouse gas emissions. Methane flux from sediment pore-water within littoral embayments averaged 4.2 mg m-2 d-1 during winter and 8.1 mg m-2 d-1 during summer, with a peak flux of 19.8 mg m-2d-1 (at the same location where CH4 ebullition was also the greatest). Carbon dioxide flux from sediment pore-water averaged approximately 80 mg m-2d-1 with little difference between winter and summer. Similar to emissions from ebullition, flux from sediment pore-water was higher in reservoirs than in the free flowing reach.

  4. Remediation of CO2 Leakage from Deep Saline Aquifer Storage Based on Reservoir and Pollution

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and of the Council of 23 April 2009 on the geological storage of carbon dioxide IEA-GHG, 2007. Remediation of Leakage from CO2 Storage Reservoirs. IEA Greenhouse Gas R&D Programme, 2007/11, September 2007. Le Guenan T : review and modelling., in CO2NET 2009 Annual Seminar Agenda - Trondheim - Norway - 18-19 June 2009. Xu T

  5. The best use of biomass? Greenhouse gas lifecycle analysis of predicted pyrolysis biochar systems.

    E-Print Network [OSTI]

    Hammond, James A R

    2009-01-01T23:59:59.000Z

    ??Life cycle analysis is carried out for 11 predicted configurations of pyrolysis biochar systems to determine greenhouse gas balance, using an original spreadsheet model. System (more)

  6. Vehicle Investment and Operating Costs and Savings for Greenhouse Gas Mitigation Strategies

    Broader source: Energy.gov [DOE]

    To help estimate costs of implementing greenhouse gas (GHG) mitigation strategies for vehicles, the table below provides the initial investment, operating costs, and operating savings for each strategy.

  7. Investigation of greenhouse gas reduction strategies by industries : an enterprise systems architecting approach

    E-Print Network [OSTI]

    Tanthullu Athmaram, Kumaresh Babu

    2012-01-01T23:59:59.000Z

    This thesis explores an enterprise systems architecting approach to investigate the greenhouse gas reduction strategies followed by industries, especially for automotive industry and Information Technology industry. The ...

  8. 2005 Inventory of Greenhouse Gas Emissions Ascribable to the University of Washington

    E-Print Network [OSTI]

    Kaminsky, Werner

    2005 Inventory of Greenhouse Gas Emissions Ascribable to the University of Washington October 2007....................................................................................................................4 Corporate vs. Geographic Inventories...........................................................................4 Inventory Protocol

  9. E-Print Network 3.0 - agroecosystem greenhouse gas Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Research and Demonstration Project Summary: rates of energy return, greater soil carbon sequestration, and reduced greenhouse gas emissions... and belowground pools and...

  10. Life cycle greenhouse gas emissions of Marcellus shale gas This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Life cycle greenhouse gas emissions of Marcellus shale gas This article has been downloaded from.1088/1748-9326/6/3/034014 Life cycle greenhouse gas emissions of Marcellus shale gas Mohan Jiang1 , W Michael Griffin2,3 , Chris greenhouse gas (GHG) emissions from the production of Marcellus shale natural gas and compares its emissions

  11. Speaker to Address Impact of Natural Gas Production on Greenhouse Gas Emissions When used for power generation, Marcellus Shale natural gas can significantly reduce carbon

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    generation, Marcellus Shale natural gas can significantly reduce carbon dioxide emissions, but questions have been raised whether development of shale gas resources results in an overall lower greenhouse gas, "Life Cycle Greenhouse Gas Emissions of Marcellus Shale Gas," appeared in Environmental Research Letters

  12. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    on significant levels of hydroelectric power have a lowerhas a high share of hydroelectric power has the lowest CO 2

  13. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    energy efficiency requirements. In this work, we estimate the CO 2 abatement potential in the California commercial sector and report

  14. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    Inherently, natural gas combustion produces significantlygas turbines were fuel gas combustion devices and that theyof greenhouse gas emissions released during combustion. 5 0

  15. INTRODUCTION Greenhouse Gas Emissions in an Urban Environment

    E-Print Network [OSTI]

    Hall, Sharon J.

    . Emissions of CO2, N2O, and CH4 in periodically flooded patch types during Winter 2013. We sampled three: How are emissions of CO2, CH4, and N2O distributed across the urban landscape? Q2: Are aquatic, and CH4 fluxes during Winter 2013 (Figs. 1 & 2). · Generally, CO2 emissions were highest within all patch

  16. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R [eds.] [eds.

    1991-09-01T23:59:59.000Z

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  17. numerical methodology to model and monitor co2 sequestration

    E-Print Network [OSTI]

    santos,,,

    CO2 sequestration is a means of mitigating the greenhouse effect [1]. Geologic sequestration involves injecting CO2 into a target geologic formation at depths...

  18. Post Doctoral Research Fellowship Simulating the greenhouse gas emission from boreal region reservoirs

    E-Print Network [OSTI]

    of greenhouse gases from northern boreal reservoirs as part of a Natural Sciences and Engineering Research modified the DeNitrification-DeComposition (DNDC) model to simulate the exchange of CO2 between boreal by the creation of reservoirs for the production of hydro-electricity. We have recently developed a water column

  19. Advancing Development and Greenhouse Gas Reductions in Vietnam's Wind Sector

    SciTech Connect (OSTI)

    Bilello, D.; Katz, J.; Esterly, S.; Ogonowski, M.

    2014-09-01T23:59:59.000Z

    Clean energy development is a key component of Vietnam's Green Growth Strategy, which establishes a target to reduce greenhouse gas (GHG) emissions from domestic energy activities by 20-30 percent by 2030 relative to a business-as-usual scenario. Vietnam has significant wind energy resources, which, if developed, could help the country reach this target while providing ancillary economic, social, and environmental benefits. Given Vietnam's ambitious clean energy goals and the relatively nascent state of wind energy development in the country, this paper seeks to fulfill two primary objectives: to distill timely and useful information to provincial-level planners, analysts, and project developers as they evaluate opportunities to develop local wind resources; and, to provide insights to policymakers on how coordinated efforts may help advance large-scale wind development, deliver near-term GHG emission reductions, and promote national objectives in the context of a low emission development framework.

  20. Uncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal

    E-Print Network [OSTI]

    Jaramillo, Paulina

    analyses involving coal. Greenhouse gas emissions from fuel use and methane releases at coal mines, fuel.5 million metric tons of methane emissions. Close to 95% of domestic coal was consumed by the electricityUncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal Aranya Venkatesh

  1. Economic Potential of Biomass Based Fuels for Greenhouse Gas Emission Mitigation

    E-Print Network [OSTI]

    McCarl, Bruce A.

    Words): Use of biofuels diminishes fossil fuel combustion thereby also reducing net greenhouse gasEconomic Potential of Biomass Based Fuels for Greenhouse Gas Emission Mitigation Uwe A. Schneider emissions. However, subsidies are needed to make agricultural biofuel production economically feasible

  2. Should a vehicle fuel economy standard be combined with an economy-wide greenhouse gas

    E-Print Network [OSTI]

    Should a vehicle fuel economy standard be combined with an economy-wide greenhouse gas emissions: globalchange@mit.edu Website: http://globalchange.mit.edu/ #12;Should a vehicle fuel economy standard be combined with an economy-wide greenhouse gas emissions constraint? Implications for energy and climate

  3. Modeling impacts of carbon sequestration on net greenhouse gas emissions from agricultural soils in China

    E-Print Network [OSTI]

    Modeling impacts of carbon sequestration on net greenhouse gas emissions from agricultural soils impacts of carbon sequestration on net greenhouse gas emissions from agricultural soils in China, Global Biogeochem. Cycles, 23, GB1007, doi:10.1029/2008GB003180. 1. Introduction [2] Carbon (C) sequestration has

  4. Overview of Avista GHG Modeling NPCC Greenhouse Gas and the Regional Power System Conference

    E-Print Network [OSTI]

    Natural Gas CO2 Emissions A Bridge to a Low Carbon Future, or the Future? 815 1,190 lbs/MWh Gas CCCT has ~35% of coal emissions on a per-MWh basis Gas CT has ~50% of coal emissions on a per-MWh basis 119 119 210 CCCT CT Colstrip 3/4 #12;6/5/2013 2 Avista CO2 Emissions Forecast Rising emissions overall

  5. MODELING, IDENTIFICATION AND CONTROL, 2006, VOL. 00, NO. 0, 000000 Control Design for a Gas Turbine Cycle with CO2 Capture

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING, IDENTIFICATION AND CONTROL, 2006, VOL. 00, NO. 0, 000­000 Control Design for a Gas capture The semi-closed oxy-fuel gas turbine cycle has been suggested in (Ulizar and Pilidis, 1997 in Section 2), is based on concept (c) above. The exhaust gas from a gas turbine with CO2 as working fluid

  6. atmospheric co2 content: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  7. atmospheric co2 concentrations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  8. atmospheric co2 concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  9. atmospheric co2 measurements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  10. atmospheric co2 variations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  11. atmospheric co2 mixing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

  12. Modeling of CO2 storage in aquifers

    E-Print Network [OSTI]

    santos,,,

    Feb 6, 2011 ... atmosphere, increasing its temperature (greenhouse effect). To minimize climate change impacts, geological sequestration of CO2 is an...

  13. CHBE 484: Term Report Greenhouse Gas Emissions Analysis

    E-Print Network [OSTI]

    .59 tonnes of CO2 will need to be eliminated in order to reduce the projected total carbon emissions of 2020 in carpooling, and the implementation of SkyTrain with increased carpooling. From literature the carbon intensity of cars, conventional and trolley buses, and SkyTrains are found to be 286.0 g/CO2, 1752.0 g/CO2

  14. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Energy Consumption 11and a decomposition of energy consumption to understand theData Historical energy consumption and energy-related CO 2

  15. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01T23:59:59.000Z

    D. C. Lal, R. (2004), Carbon emission from farm operations,facts: Average carbon dioxide emissions resulting fromcalculation of carbon dioxide (CO 2 ) emissions from fuel

  16. Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health

    SciTech Connect (OSTI)

    West, Jason; Smith, Steven J.; Silva, Raquel; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zacariah; Fry, Meridith M.; Anenberg, Susan C.; Horowitz, L.; Lamarque, Jean-Francois

    2013-10-01T23:59:59.000Z

    Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. Relative to a reference scenario, global GHG mitigation in the RCP4.5 scenario avoids 0.50.2, 1.30.6, and 2.21.6 million premature deaths in 2030, 2050, and 2100, from changes in fine particulate matter and ozone. Global average marginal co-benefits of avoided mortality are $40-400 (ton CO2)-1, exceeding marginal abatement costs in 2030 and 2050, and within the low range of costs in 2100. East Asian co-benefits are 10-80 times the marginal cost in 2030. These results indicate that transitioning to a low-carbon future might be justified by air quality and health co-benefits.

  17. Injection, flow, and mixing of CO2 in porous media with residual gas.

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Doughty, C.A.

    2010-09-01T23:59:59.000Z

    Geologic structures associated with depleted natural gas reservoirs are desirable targets for geologic carbon sequestration (GCS) as evidenced by numerous pilot and industrial-scale GCS projects in these environments world-wide. One feature of these GCS targets that may affect injection is the presence of residual CH{sub 4}. It is well known that CH{sub 4} drastically alters supercritical CO{sub 2} density and viscosity. Furthermore, residual gas of any kind affects the relative permeability of the liquid and gas phases, with relative permeability of the gas phase strongly dependent on the time-history of imbibition or drainage, i.e., dependent on hysteretic relative permeability. In this study, the effects of residual CH{sub 4} on supercritical CO{sub 2} injection were investigated by numerical simulation in an idealized one-dimensional system under three scenarios: (1) with no residual gas; (2) with residual supercritical CO{sub 2}; and (3) with residual CH{sub 4}. We further compare results of simulations that use non-hysteretic and hysteretic relative permeability functions. The primary effect of residual gas is to decrease injectivity by decreasing liquid-phase relative permeability. Secondary effects arise from injected gas effectively incorporating residual gas and thereby extending the mobile gas plume relative to cases with no residual gas. Third-order effects arise from gas mixing and associated compositional effects on density that effectively create a larger plume per unit mass. Non-hysteretic models of relative permeability can be used to approximate some parts of the behavior of the system, but fully hysteretic formulations are needed to accurately model the entire system.

  18. Federal, state and utility roles in reducing new building greenhouse gas emissions

    SciTech Connect (OSTI)

    Johnson, J.A.; Shankle, D. [Pacific Northwest Lab., Richland, WA (United States); Boulin, J. [USDOE, Washington, DC (United States)

    1995-03-01T23:59:59.000Z

    This paper will explore the role of implementation of building energy codes and standards in reducing US greenhouse gas emissions. It will discuss the role of utilities in supporting the US Department of Energy (DOE) and the Environmental Protection Agency in improving the efficiency of new buildings. The paper will summarize Federal policies and programs that improve code compliance and increase overall greenhouse gas emission reductions. Finally, the paper will discuss the role of code compliance and the energy and greenhouse gas emission reductions that have been realized from various Federal, State and utility programs that enhance compliance.

  19. Estimating the potential of greenhouse gas mitigation in Kazakhstan

    SciTech Connect (OSTI)

    Monacrovich, E.; Pilifosova, O.; Danchuck, D. [Kazakh Scientific-Research Hydrometeorlogical Institute, Almaty (Kazakhstan)] [and others

    1996-09-01T23:59:59.000Z

    As part of the studies related to the obligations of the UN Framework Convention on Climate Change, the Republic of Kazakhstan started activities to inventory greenhouse gas (GHG) emissions and assess of GHG mitigation options, The objective of this paper is to present an estimate of the possibility of mitigating GHG emissions and determine the mitigation priorities. It presents a compilation of the possible options and their assessment in terms of major criteria and implementation feasibility. Taking into account the structure of GHG emissions in Kazakhstan in 1990, preliminary estimates of the potential for mitigation are presented for eight options for the energy sector and agriculture and forestry sector. The reference scenario prepared by expert assessments assumes a reduction of CO{sub 2} emissions in 1996-1998 by about 26% from the 1990 level due to general economic decline, but then emissions increase. It is estimated that the total potential for the mitigation of CO{sub 2} emissions for the year 2000 is 3% of the CO{sub 2} emissions in the reference scenario. The annual reduction in methane emissions due to the estimated options can amount to 5%-6% of the 1990 level. 10 refs., 1 fig., 4 tabs.

  20. Idaho National Laboratory's FY13 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2014-03-01T23:59:59.000Z

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2013 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho. This report details the methods behind quantifying INLs GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only the large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  1. Co2 geological sequestration

    SciTech Connect (OSTI)

    Xu, Tianfu

    2004-11-18T23:59:59.000Z

    Human activities are increasingly altering the Earth's climate. A particular concern is that atmospheric concentrations of carbon dioxide (CO{sub 2}) may be rising fast because of increased industrialization. CO{sub 2} is a so-called ''greenhouse gas'' that traps infrared radiation and may contribute to global warming. Scientists project that greenhouse gases such as CO{sub 2} will make the arctic warmer, which would melt glaciers and raise sea levels. Evidence suggests that climate change may already have begun to affect ecosystems and wildlife around the world. Some animal species are moving from one habitat to another to adapt to warmer temperatures. Future warming is likely to exceed the ability of many species to migrate or adjust. Human production of CO{sub 2} from fossil fuels (such as at coal-fired power plants) is not likely to slow down soon. It is urgent to find somewhere besides the atmosphere to put these increased levels of CO{sub 2}. Sequestration in the ocean and in soils and forests are possibilities, but another option, sequestration in geological formations, may also be an important solution. Such formations could include depleted oil and gas reservoirs, unmineable coal seams, and deep saline aquifers. In many cases, injection of CO2 into a geological formation can enhance the recovery of hydrocarbons, providing value-added byproducts that can offset the cost of CO{sub 2} capture and sequestration. Before CO{sub 2} gas can be sequestered from power plants and other point sources, it must be captured. CO{sub 2} is also routinely separated and captured as a by-product from industrial processes such as synthetic ammonia production, H{sub 2} production, and limestone calcination. Then CO{sub 2} must be compressed into liquid form and transported to the geological sequestration site. Many power plants and other large emitters of CO{sub 2} are located near geological formations that are amenable to CO{sub 2} sequestration.

  2. The CO2 Gas Cherenkov Detectors for the Je erson Lab Hall A Spectrometers

    E-Print Network [OSTI]

    obtained by using a wavelength shifter coated on the photocathode glass window. With such an improvement and in the hadron arm, by combining the information coming from a silica aerogel Cherenkov counter 2,3 , a gas

  3. Optimal Process Design for Coupled CO2 Sequestration and Enhanced Gas Recovery in Carbonate Reservoirs

    E-Print Network [OSTI]

    Odi, Uchenna

    2013-12-09T23:59:59.000Z

    Increasing energy demand combined with public concern for the environment obligates the oil industry to supply oil and natural gas to the public while minimizing the carbon footprint due to its activities. Today, fossil fuels are essential...

  4. Economics of Lifecycle analysis and greenhouse gas regulations

    E-Print Network [OSTI]

    Rajagopal, Deepak

    2009-01-01T23:59:59.000Z

    estimate 8. Price of coal energy: average delivered price toin gCO2e/liter Price of coal energy 0.0020 ($/MJ) Price of0.09 uses only coal based energy net GHG displacement if

  5. Air Emmissions Trading Program/Regional Greenhouse Gas Initiative...

    Broader source: Energy.gov (indexed) [DOE]

    carbon dioxide emissions budget trading program. The program includes a statewide annual CO2 budget allowance of 8,620,460 tons between 2009 and 2014; beginning in 2015 and ending...

  6. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Agency (IEA), 2004c. CO2 emissions from fuel combustion,of Carbon Dioxide Emissions on GNP Growth: Interpretation ofD. , 2000. Special Report on Emissions Scenarios: Report of

  7. Initiation of long, free-standing Z-discharges by CO2 laser gas heating

    SciTech Connect (OSTI)

    Nieman, C.; Tauschwitz, A.; Penache, D.; Neff, S.; Knobloch, R.; Birkner, R.; Presura, R.; Hoffmann, D.H.H.; Yu, S.S.; Sharp, W.M.

    2004-04-19T23:59:59.000Z

    High current discharge channels can neutralize both current and space charge of very intense ion beams. Therefore they are considered as an interesting alternative for the final focus and beam transport in a heavy ion beam fusion reactor. At the GSI accelerator facility, 50 cm long, stable, free-standing discharge channels with currents in excess of 40 kA in 2 to 25 mbar ammonia (NH{sub 3}) gas are investigated for heavy ion beam transport studies. The discharges are initiated by a CO{sub 2} laser pulse along the channel axis before the discharge is triggered. Resonant absorption of the laser, tuned to the {nu}{sub 2} vibration of the ammonia molecule, causes strong gas heating. Subsequent expansion and rarefaction of the gas prepare the conditions for a stable discharge to fulfill the requirements for ion beam transport. This paper describes the laser-gas interaction and the discharge initiation mechanism. We report on the channel stability and evolution, measured by fast shutter and streak imaging techniques. The rarefaction of the laser heated gas is studied by means of a hydrocode simulation.

  8. Supercritical CO2 direct cycle Gas Fast Reactor (SC-GFR) concept.

    SciTech Connect (OSTI)

    Wright, Steven Alan; Parma, Edward J., Jr.; Suo-Anttila, Ahti Jorma (Computational Engineering Analysis, Albuquerque, NM); Al Rashdan, Ahmad (Texas A& M University, College Station, TX); Tsvetkov, Pavel Valeryevich (Texas A& M University, College Station, TX); Vernon, Milton E.; Fleming, Darryn D.; Rochau, Gary Eugene

    2011-05-01T23:59:59.000Z

    This report describes the supercritical carbon dioxide (S-CO{sub 2}) direct cycle gas fast reactor (SC-GFR) concept. The SC-GFR reactor concept was developed to determine the feasibility of a right size reactor (RSR) type concept using S-CO{sub 2} as the working fluid in a direct cycle fast reactor. Scoping analyses were performed for a 200 to 400 MWth reactor and an S-CO{sub 2} Brayton cycle. Although a significant amount of work is still required, this type of reactor concept maintains some potentially significant advantages over ideal gas-cooled systems and liquid metal-cooled systems. The analyses presented in this report show that a relatively small long-life reactor core could be developed that maintains decay heat removal by natural circulation. The concept is based largely on the Advanced Gas Reactor (AGR) commercial power plants operated in the United Kingdom and other GFR concepts.

  9. Shale-Gas Experience as an Analog for Potential Wellbore Integrity Issues in CO2 Sequestration

    SciTech Connect (OSTI)

    Carey, James W. [Los Alamos National Laboratory; Simpson, Wendy S. [Los Alamos National Laboratory; Ziock, Hans-Joachim [Los Alamos National Laboratory

    2011-01-01T23:59:59.000Z

    Shale-gas development in Pennsylvania since 2003 has resulted in about 19 documented cases of methane migration from the deep subsurface (7,0000) to drinking water aquifers, soils, domestic water wells, and buildings, including one explosion. In all documented cases, the methane leakage was due to inadequate wellbore integrity, possibly aggravated by hydrofracking. The leakage of methane is instructive on the potential for CO{sub 2} leakage from sequestration operations. Although there are important differences between the two systems, both involve migrating, buoyant gas with wells being a primary leakage pathway. The shale-gas experience demonstrates that gas migration from faulty wells can be rapid and can have significant impacts on water quality and human health and safety. Approximately 1.4% of the 2,200 wells drilled into Pennsylvania's Marcellus Formation for shale gas have been implicated in methane leakage. These have resulted in damage to over 30 domestic water supplies and have required significant remediation via well repair and homeowner compensation. The majority of the wellbore integrity problems are a result of over-pressurization of the wells, meaning that high-pressure gas has migrated into an improperly protected wellbore annulus. The pressurized gas leaks from the wellbore into the shallow subsurface, contaminating drinking water or entering structures. The effects are localized to a few thousands of feet to perhaps two-three miles. The degree of mixing between the drinking water and methane is sufficient that significant chemical impacts are created in terms of elevated Fe and Mn and the formation of black precipitates (metal sulfides) as well as effervescing in tap water. Thus it appears likely that leaking CO{sub 2} could also result in deteriorated water quality by a similar mixing process. The problems in Pennsylvania highlight the critical importance of obtaining background data on water quality as well as on problems associated with previous (legacy) oil and gas operations. The great majority of the leakage issues in Pennsylvania are due to improperly abandoned wells, however in the media there is no clear distinction between past and present problems. In any case, significant analytical work is required to attribute differing sources of methane (or CO{sub 2} in the case of sequestration). In Pennsylvania, a relatively lax regulatory environment appears to have contributed to the problem with inadequate oversight of well design and testing to ensure well integrity. New rules were adopted at the end of 2010, and it will be interesting to observe whether methane leakage problems are significantly reduced.

  10. A Strategy for a Global Observing System for Verification of National Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Prinn, Ronald G.

    With the risks of climate change becoming increasingly evident, there is growing discussion regarding international treaties and national regulations to lower greenhouse gas (GHG) emissions. Enforcement of such agreements ...

  11. Estimate Costs to Implement Greenhouse Gas Mitigation Strategies for Vehicles and Mobile Equipment

    Broader source: Energy.gov [DOE]

    Once a Federal agency identifies the various strategic opportunities to reduce greenhouse gas (GHG) emissions for vehicles and mobile equipment, it is necessary to evaluate the associated costs of adopting each strategy.

  12. Life-Cycle Greenhouse Gas and Energy Analyses of Algae Biofuels Production

    E-Print Network [OSTI]

    Life-Cycle Greenhouse Gas and Energy Analyses of Algae Biofuels Production Transportation Energy The Issue Algae biofuels directly address the Energy Commission's Public Interest Energy Research fuels more carbonintensive than conventional biofuels. Critics of this study argue that alternative

  13. Carbon Prices and Automobile Greenhouse Gas Emissions: The Extensive and Intensive Margins

    E-Print Network [OSTI]

    Knittel, Christopher Roland

    The transportation sector accounts for nearly one third of the United States' greenhouse gas emissions. While over the past number of decades, policy makers have avoided directly pricing the externalities from vehicles, ...

  14. Greenhouse Gas Mitigation as a Structural Change and Policies that Offset Its Depressing Effects

    E-Print Network [OSTI]

    Babiker, Mustafa H.M.

    The current economic modeling of emissions limitations does not embody economic features that are likely to be particularly important in the short term, yet the politics of limiting greenhouse gas emissions are often ...

  15. Title: Net Energy Ratio and Greenhouse Gas Analysis of a Biogas Power Plant

    E-Print Network [OSTI]

    Bauer, Wolfgang

    of a Biogas Power Plant Author: W. Bauer Author Affiliation: Department and greenhouse gas analysis for a 1.45 MW (0.71 MW electrical) biogas power plant

  16. Estimate Costs to Implement Greenhouse Gas Mitigation Strategies for Employee Commuting

    Broader source: Energy.gov [DOE]

    For greenhouse gas (GHG) mitigation, once a Federal agency identifies the employee commute alternatives and supporting strategies that will most effectively reduce trips to the worksite, costs of encouraging adoption of those methods can be estimated.

  17. Greenhouse gas emissions from contrasting beef production systems

    E-Print Network [OSTI]

    Ricci, Patricia

    2014-06-30T23:59:59.000Z

    Agriculture has been reported to contribute a significant amount of greenhouse gases to the atmosphere among other anthropogenic activities. With still more than 870 million people in the world suffering from under-nutrition ...

  18. Comparing the effects of greenhouse gas emissions on global warming

    E-Print Network [OSTI]

    Eckaus, Richard S.

    1990-01-01T23:59:59.000Z

    Policies dealing with global warming require a measure of the effects of the emissions of greenhouse gases that create different magnitudes of instantaneous radiative forcing and have different lifetimes. The Global Warming ...

  19. PRELIMINARY CHARACTERIZATION OF CO2 SEPARATION AND STORAGE PROPERTIES OF COAL GAS RESERVOIRS

    SciTech Connect (OSTI)

    John Kemeny; Satya Harpalani

    2004-03-01T23:59:59.000Z

    An attractive alternative of sequestering CO{sub 2} is to inject it into coalbed methane reservoirs, particularly since it has been shown to enhance the production of methane during near depletion stages. The basis for enhanced coalbed methane recovery and simultaneous sequestration of carbon dioxide in deep coals is the preferential sorption property of coal, with its affinity for carbon dioxide being significantly higher than that for methane. Yet, the sorption behavior of coal under competitive sorptive environment is not fully understood. Hence, the original objective of this research study was to carry out a laboratory study to investigate the effect of studying the sorption behavior of coal in the presence of multiple gases, primarily methane, CO{sub 2} and nitrogen, in order to understand the mechanisms involved in displacement of methane and its movement in coal. This had to be modified slightly since the PVT property of gas mixtures is still not well understood, and any laboratory work in the area of sorption of gases requires a definite equation of state to calculate the volumes of different gases in free and adsorbed forms. This research study started with establishing gas adsorption isotherms for pure methane and CO{sub 2}. The standard gas expansion technique based on volumetric analysis was used for the experimental work with the additional feature of incorporating a gas chromatograph for analysis of gas composition. The results were analyzed first using the Langmuir theory. As expected, the Langmuir analysis indicated that CO{sub 2} is more than three times as sorptive as methane. This was followed by carrying out a partial desorption isotherm for methane, and then injecting CO{sub 2} to displace methane. The results indicated that CO{sub 2} injection at low pressure displaced all of the sorbed methane, even when the total pressure continued to be high. However, the displacement appeared to be occurring due to a combination of the preferential sorption property of coal and reduction in the partial pressure of methane. As a final step, the Extended Langmuir (EL) model was used to model the coal-methane-CO{sub 2} binary adsorption system. The EL model was found to be very accurate in predicting adsorption of CO{sub 2}, but not so in predicting desorption of methane. The selectivity of CO{sub 2} over methane was calculated to be 4.3:1. This is, of course, not in very good agreement with the measured values which showed the ratio to be 3.5:1. However, the measured results are in good agreement with the field observation at one of the CO{sub 2} injection sites. Based on the findings of this study, it was concluded that low pressure injection of CO{sub 2} can be fairly effective in displacing methane in coalbed reservoirs although this might be difficult to achieve in field conditions. Furthermore, the displacement of methane appears to be not only due to the preferential sorption of methane, but reduction in partial pressure as well. Hence, using a highly adsorbing gas, such as CO{sub 2}, has the advantages of inert gas stripping and non-mixing since the injected gas does not mix with the recovered methane.

  20. Reply to "Comment on 'Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics' by Joshua B. Halpern, Christopher M. Colose, Chris Ho-Stuart, Joel D. Shore, Arthur P. Smith, J\\"org Zimmermann"

    E-Print Network [OSTI]

    Gerlich, Gerhard; 10.1142/S0217979210055573

    2010-01-01T23:59:59.000Z

    It is shown that the notorious claim by Halpern et al. recently repeated in their comment that the method, logic, and conclusions of our "Falsification Of The CO2 Greenhouse Effects Within The Frame Of Physics" would be in error has no foundation. Since Halpern et al. communicate our arguments incorrectly, their comment is scientifcally vacuous. In particular, it is not true that we are "trying to apply the Clausius statement of the Second Law of Thermodynamics to only one side of a heat transfer process rather than the entire process" and that we are "systematically ignoring most non-radiative heat flows applicable to Earth's surface and atmosphere". Rather, our falsification paper discusses the violation of fundamental physical and mathematical principles in 14 examples of common pseudo-derivations of fictitious greenhouse effects that are all based on simplistic pictures of radiative transfer and their obscure relation to thermodynamics, including but not limited to those descriptions (a) that define a "Pe...

  1. Highly Stable Porphyrinic Zr-MOFs for CO2 Fixation | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area.Portal Solar PhotovoltaicCenter for GasCapacities

  2. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries & Fuel Cells In ThisMetalCenter for Gas

  3. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-01-01T23:59:59.000Z

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700C) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

  4. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    produced. Primary energy associated with coal products wasUse EJ China Residential Energy Use Gas Coal Oil Biomass GasUse EJ China Residential Energy Use Gas Coal Oil Gas Biomass

  5. An Economic Exploration of Biofuel basedAn Economic Exploration of Biofuel based Greenhouse Gas Emission MitigationGreenhouse Gas Emission Mitigation

    E-Print Network [OSTI]

    McCarl, Bruce A.

    An Economic Exploration of Biofuel basedAn Economic Exploration of Biofuel based Greenhouse Gas Afforestation, Forest management, Biofuels, Ag soil, Animals, Fertilization, Rice, Grassland expansion, Manure of Biofuel strategies Examine the dynamics of mitigation strategies #12;PolicyPolicy ContextContext U

  6. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    all fuels including electricity and syngas will be used forGas Electricity Biomass Syngas Space Heating Coal Oil Gas

  7. Measurements of 222Rn, 220Rn, and CO Emissions in Natural CO2 Fields in Wyoming: MVA Techniques for Determining Gas Transport and Caprock Integrity

    SciTech Connect (OSTI)

    Kaszuba, John; Sims, Kenneth

    2014-09-30T23:59:59.000Z

    An integrated field-laboratory program evaluated the use of radon and CO2 flux measurements to constrain source and timescale of CO2 fluxes in environments proximate to CO2 storage reservoirs. By understanding the type and depth of the gas source, the integrity of a CO2 storage reservoir can be assessed and monitored. The concept is based on correlations of radon and CO2 fluxes observed in volcanic systems. This fundamental research is designed to advance the science of Monitoring, Verification, and Accounting (MVA) and to address the Carbon Storage Program goal of developing and validating technologies to ensure 99 percent storage performance. Graduate and undergraduate students conducted the research under the guidance of the Principal Investigators; in doing so they were provided with training opportunities in skills required for implementing and deploying CCS technologies. Although a final method or tool was not developed, significant progress was made. The field program identified issues with measuring radon in environments rich in CO2. Laboratory experiments determined a correction factor to apply to radon measurements made in CO2-bearing environments. The field program also identified issues with radon and CO2-flux measurements in soil gases at a natural CO2 analog. A systematic survey of radon and CO2 flux in soil gases at the LaBarge CO2 Field in Southwest Wyoming indicates that measurements of 222Rn (radon), 220Rn (thoron), and CO2 flux may not be a robust method for monitoring the integrity of a CO2 storage reservoir. The field program was also not able to correlate radon and CO2 flux in the CO2-charged springs of the Thermopolis hydrothermal system. However, this part of the program helped to motivate the aforementioned laboratory experiments that determined correction factors for measuring radon in CO2-rich environments. A graduate student earned a Master of Science degree for this part of the field program; she is currently employed with a geologic consulting company. Measurement of radon in springs has improved significantly since the field program first began; however, in situ measurement of 222Rn and particularly 220Rn in springs is problematic. Future refinements include simultaneous salinity measurements and systematic corrections, or adjustments to the partition coefficient as needed for more accurate radon concentration determination. A graduate student earned a Master of Science degree for this part of the field program; he is currently employed with a geologic consulting company. Both graduate students are poised to begin work in a CCS technology area. Laboratory experiments evaluated important process-level fundamentals that effect measurements of radon and CO2. Laboratory tests established that fine-grained source minerals yield higher radon emissivity compared to coarser-sized source minerals; subtleties in the dataset suggest that grain size alone is not fully representative of all the processes controlling the ability of radon to escape its mineral host. Emissivity for both 222Rn and 220Rn increases linearly with temperature due to reaction of rocks with water, consistent with faster diffusion and enhanced mineral dissolution at higher temperatures. The presence of CO2 changes the relative importance of the factors that control release of radon. Emissivity for both 222Rn and 220Rn in CO2-bearing experiments is greater at all temperatures compared to the experiments without CO2, but emissivity does not increase as a simple function of temperature. Governing processes may include a balance between enhanced dissolution versus carbonate mineral formation in CO2-rich waters.

  8. Modeling Gas Transport in the Shallow Subsurface During the ZERT CO2 Release Test

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.; Lewicki, Jennifer L.; Dobeck, Laura; Spangler, Lee

    2009-01-15T23:59:59.000Z

    We used the multiphase and multicomponent TOUGH2/EOS7CA model to carry out predictive simulations of CO{sub 2} injection into the shallow subsurface of an agricultural field in Bozeman, Montana. The purpose of the simulations was to inform the choice of CO{sub 2} injection rate and design of monitoring and detection activities for a CO{sub 2} release experiment. The release experiment configuration consists of a long horizontal well (70 m) installed at a depth of approximately 2.5 m into which CO{sub 2} is injected to mimic leakage from a geologic carbon sequestration site through a linear feature such as a fault. We estimated the permeability of the soil and cobble layers present at the site by manual inversion of measurements of soil CO{sub 2} flux from a vertical-well CO{sub 2} release. Based on these estimated permeability values, predictive simulations for the horizontal well showed that CO{sub 2} injection just below the water table creates an effective gas-flow pathway through the saturated zone up to the unsaturated zone. Once in the unsaturated zone, CO{sub 2} spreads out laterally within the cobble layer, where liquid saturation is relatively low. CO{sub 2} also migrates upward into the soil layer through the capillary barrier and seeps out at the ground surface. The simulations predicted a breakthrough time of approximately two days for the 100kg d{sup -1} injection rate, which also produced a flux within the range desired for testing detection and monitoring approaches. The seepage area produced by the model was approximately five meters wide above the horizontal well, compatible with the detection and monitoring methods tested. For a given flow rate, gas-phase diffusion of CO{sub 2} tends to dominate over advection near the ground surface, where the CO{sub 2} concentration gradient is large, while advection dominates deeper in the system.

  9. Idaho National Laboratorys FY09 & FY10 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2011-06-01T23:59:59.000Z

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2009 and 2010 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions. INL's GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL's organizational boundaries, but are a consequence of INL's activities). This inventory found that INL generated 103,590 and 102,413 MT of CO2-equivalent emissions during FY09 and FY10, respectively. The following conclusions were made from looking at the results of the individual contributors to INL's FY09 and FY10 GHG inventories: (1) Electricity (including the associated transmission and distribution losses) is the largest contributor to INL's GHG inventory, with over 50% of the CO2e emissions; (2) Other sources with high emissions were stationary combustion (facility fuels), waste disposal (including fugitive emissions from the onsite landfill and contracted disposal), mobile combustion (fleet fuels), employee commuting, and business air travel; and (3) Sources with low emissions were wastewater treatment (onsite and contracted), fugitive emissions from refrigerants, and business ground travel (in personal and rental vehicles). This report details the methods behind quantifying INL's GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by the Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only that large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  10. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied...

    Broader source: Energy.gov (indexed) [DOE]

    gas (GHG) perspective? *How do those results compare with natural gas sourced from Russia and delivered to the same European and Asian markets via pipeline? Life Cycle GHG...

  11. Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Fisher, II, James C

    2013-12-31T23:59:59.000Z

    The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

  12. Development of Fly Ash Derived Sorbents to Capture CO2 from Flue Gas of Power Plants

    SciTech Connect (OSTI)

    M. Mercedes Maroto-Valer; John M. Andresen; Yinzhi Zhang; Zhe Lu

    2003-12-31T23:59:59.000Z

    This research program focused on the development of fly ash derived sorbents to capture CO{sub 2} from power plant flue gas emissions. The fly ash derived sorbents developed represent an affordable alternative to existing methods using specialized activated carbons and molecular sieves, that tend to be very expensive and hinder the viability of the CO{sub 2} sorption process due to economic constraints. Under Task 1 'Procurement and characterization of a suite of fly ashes', 10 fly ash samples, named FAS-1 to -10, were collected from different combustors with different feedstocks, including bituminous coal, PRB coal and biomass. These samples presented a wide range of LOI value from 0.66-84.0%, and different burn-off profiles. The samples also spanned a wide range of total specific surface area and pore volume. These variations reflect the difference in the feedstock, types of combustors, collection hopper, and the beneficiation technologies the different fly ashes underwent. Under Task 2 'Preparation of fly ash derived sorbents', the fly ash samples were activated by steam. Nitrogen adsorption isotherms were used to characterize the resultant activated samples. The cost-saving one-step activation process applied was successfully used to increase the surface area and pore volume of all the fly ash samples. The activated samples present very different surface areas and pore volumes due to the range in physical and chemical properties of their precursors. Furthermore, one activated fly ash sample, FAS-4, was loaded with amine-containing chemicals (MEA, DEA, AMP, and MDEA). The impregnation significantly decreased the surface area and pore volume of the parent activated fly ash sample. Under Task 3 'Capture of CO{sub 2} by fly ash derived sorbents', sample FAS-10 and its deashed counterpart before and after impregnation of chemical PEI were used for the CO{sub 2} adsorption at different temperatures. The sample FAS-10 exhibited a CO{sub 2} adsorption capacity of 17.5mg/g at 30 C, and decreases to 10.25mg/g at 75 C, while those for de-ashed counterpart are 43.5mg/g and 22.0 mg/g at 30 C and 75 C, respectively. After loading PEI, the CO{sub 2} adsorption capacity increased to 93.6 mg/g at 75 C for de-ashed sample and 62.1 mg/g at 75 C for raw fly ash sample. The activated fly ash, FAS-4, and its chemical loaded counterparts were tested for CO{sub 2} capture capacity. The activated carbon exhibited a CO{sub 2} adsorption capacity of 40.3mg/g at 30 C that decreased to 18.5mg/g at 70 C and 7.7mg/g at 120 C. The CO{sub 2} adsorption capacity profiles changed significantly after impregnation. For the MEA loaded sample the capacity increased to 68.6mg/g at 30 C. The loading of MDEA and DEA initially decreased the CO{sub 2} adsorption capacity at 30 C compared to the parent sample but increased to 40.6 and 37.1mg/g, respectively, when the temperature increased to 70 C. The loading of AMP decrease the CO{sub 2} adsorption capacity compared to the parent sample under all the studied temperatures. Under Task 4 'Comparison of the CO{sub 2} capture by fly ash derived sorbents with commercial sorbents', the CO{sub 2} adsorption capacities of selected activated fly ash carbons were compared to commercial activated carbons. The CO{sub 2} adsorption capacity of fly ash derived activated carbon, FAS-4, and its chemical loaded counterpart presented CO{sub 2} capture capacities close to 7 wt%, which are comparable to, and even better than, the published values of 3-4%.

  13. CO2-Binding Organic Liquids Gas Capture with Polarity-Swing-Assisted Regeneration Full Technology Feasibility Study B1 - Solvent-based Systems

    SciTech Connect (OSTI)

    Heldebrant, David J

    2014-08-31T23:59:59.000Z

    PNNL, Fluor Corporation and Queens University (Kingston, ON) successfully completed a three year comprehensive study of the CO2BOL water-lean solvent platform with Polarity Swing Assisted Regeneration (PSAR). This study encompassed solvent synthesis, characterization, environmental toxicology, physical, thermodynamic and kinetic property measurements, Aspen Plus modeling and bench-scale testing of a candidate CO2BOL solvent molecule. Key Program Findings The key program findings are summarized as follows: PSAR favorably reduced stripper duties and reboiler temperatures with little/no impact to absorption column >90% CO2 capture was achievable at reasonable liquid-gas ratios in the absorber High rich solvent viscosities (up to 600 cP) were successfully demonstrated in the bench-scale system. However, the projected impacts of high viscosity to capital cost and operational limits compromised the other levelized cost of electricity benefits. Low thermal conductivity of organics significantly increased the required cross exchanger surface area, and potentially other heat exchange surfaces. CO2BOL had low evaporative losses during bench-scale testing There was no evidence of foaming during bench scale testing Current CO2BOL formulation costs project to be $35/kg Ecotoxicity (Water Daphnia) was comparable between CO2BOL and MEA (169.47 versus 103.63 mg/L) Full dehydration of the flue gas was determined to not be economically feasible. However, modest refrigeration (13 MW for the 550 MW reference system) was determined to be potentially economically feasible, and still produce a water-lean condition for the CO2BOLs (5 wt% steady-state water loading). CO2BOLs testing with 5 wt% water loading did not compromise anhydrous performance behavior, and showed actual enhancement of CO2 capture performance. Mass transfer of CO2BOLs was not greatly impeded by viscosity Facile separation of antisolvent from lean CO2BOL was demonstrated on the bench cart No measurable solvent degradation was observed over 4 months of testing even with 5 wt% water present

  14. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    utility electricity and natural gas purchases, amortized capital and maintenance costs for distributed generation (

  15. Chapter Four Assessing the Air Pollution, Greenhouse Gas, Air Quality, and Health Benefits of Clean Energy Initiatives

    E-Print Network [OSTI]

    unknown authors

    Many states and localities are exploring or implementing clean energy policies to achieve greenhouse gas (GHG) and criteria air pollutant1 emission reductions. Document map Chapter one

  16. Greenhouse gas performance standards: From each according to his emission intensity or from each according to his emissions?

    E-Print Network [OSTI]

    Rajagopal, Deepak

    2013-01-01T23:59:59.000Z

    2009. Stephen P Holland. Emissions taxes versus intensityindustrys greenhouse gas emissions. Environmental Research2008. John CV Pezzey. Emission taxes and tradeable permits a

  17. Carbon Geography: The Political Economy of Congressional Support for Legislation Intended to Mitigate Greenhouse Gas Production

    SciTech Connect (OSTI)

    Cragg, Michael; Zhou, Yuyu; Gurney, Kevin R.; Kahn, Matthew

    2013-04-01T23:59:59.000Z

    Over the last five years, the U.S Congress has voted on several pieces of legislation intended to sharply reduce the nations greenhouse gas emissions. Given that climate change is a world public bad, standard economic logic would predict that the United States would ?free ride? and wait for other nations to reduce their emissions. Within the Congress, there are clear patterns to who votes in favor of mitigating greenhouse gas emissions. This paper presents a political economy analysis of the determinants of ?pro-green? votes on such legislation. Conservatives consistently vote against such legislation. Controlling for a Representatives ideology, representatives from richer districts and districts with a lower per-capita carbon dioxide footprint are more likely to vote in favor of climate change mitigation legislation. Representatives from districts where industrial emissions represent a larger share of greenhouse gas emissions are more likely to vote no.

  18. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29T23:59:59.000Z

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  19. Greenhouse Gas Reductions: SF6 | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor'sshortGeothermalGoGreen Engineering andGreenGreenhouse

  20. Estimating the benefits of greenhouse gas emission reduction from agricultural policy reform

    SciTech Connect (OSTI)

    Adger, W.N. (Univ. of East Anglia, Norwich (United Kingdom). Centre for Social and Economic Research on the Global Environment); Moran, D.C. (Univ. College, London (United Kingdom). Centre for Social and Economic Research on the Global Environment)

    1993-09-01T23:59:59.000Z

    Land use and agricultural activities contribute directly to the increased concentrations of atmospheric greenhouse gases. Economic support in industrialized countries generally increases agriculture's contribution to global greenhouse gas concentrations through fluxes associated with land use change and other sources. Changes in economic support offers opportunities to reduce net emissions, through this so far has gone unaccounted. Estimates are presented here of emissions of methane from livestock in the UK and show that, in monetary terms, when compared to the costs of reducing support, greenhouse gases are a significant factor. As signatory parties to the Climate Change Convection are required to stabilize emissions of all greenhouse gases, options for reduction of emissions of methane and other trace gases from the agricultural sector should form part of these strategies.

  1. DOE Partner Begins Injecting 50,000 Tons of CO2 in Michigan Basin

    Broader source: Energy.gov [DOE]

    Building on an initial injection project of 10,000 metric tons of carbon dioxide into a Michigan geologic formation, a U.S. Department of Energy team of regional partners has begun injecting 50,000 additional tons into the formation, which is believed capable of storing hundreds of years worth of CO2, a greenhouse gas that contributes to climate change.

  2. THE ECONOMICS OF CO2 SEPARATION AND CAPTURE Howard J. Herzog

    E-Print Network [OSTI]

    of which will be explored later in this paper. The process of producing this high purity, high pressure CO2 into oil reservoirs to increase the mobility of the oil and, therefore, the productivity of the reservoir for reducing greenhouse gas emissions that can complement the current strategies of improving energy efficiency

  3. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Burkhardt, J. J.; Heath, G.; Cohen, E.

    2012-04-01T23:59:59.000Z

    In reviewing life cycle assessment (LCA) literature of utility-scale concentrating solar power (CSP) systems, this analysis focuses on reducing variability and clarifying the central tendency of published estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emissions estimates passing screens for quality and relevance: 19 for parabolic trough (trough) technology and 17 for power tower (tower) technology. The interquartile range (IQR) of published estimates for troughs and towers were 83 and 20 grams of carbon dioxide equivalent per kilowatt-hour (g CO2-eq/kWh),1 respectively; median estimates were 26 and 38 g CO2-eq/kWh for trough and tower, respectively. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. The IQR and median were reduced by 87% and 17%, respectively, for troughs. For towers, the IQR and median decreased by 33% and 38%, respectively. Next, five trough LCAs reporting detailed life cycle inventories were identified. The variability and central tendency of their estimates are reduced by 91% and 81%, respectively, after light harmonization. By harmonizing these five estimates to consistent values for global warming intensities of materials and expanding system boundaries to consistently include electricity and auxiliary natural gas combustion, variability is reduced by an additional 32% while central tendency increases by 8%. These harmonized values provide useful starting points for policy makers in evaluating life cycle GHG emissions from CSP projects without the requirement to conduct a full LCA for each new project.

  4. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    holidays ICE: Internal combustion engine, GT: Gas turbine,indicate that internal combustion engines (ICE) with heatdominance of internal combustion engines with heat exchanger

  5. California's Greenhouse Gas Policies: Local Solutions to a Global Problem?

    E-Print Network [OSTI]

    Bushnell, Jim B; Peterman, Carla Joy; Wolfram, Catherine D

    2007-01-01T23:59:59.000Z

    natural gas plants to follow load as the more nimble,that annual load-growth in the five states follows the 10

  6. Performance Analysis of a Transcritical CO2 Heat Pump Water Heater Incorporating a Brazed-Plate Gas-cooler.

    E-Print Network [OSTI]

    Murray, PORTIA

    2015-01-01T23:59:59.000Z

    ??This study focuses on the experimental testing and numerical modeling of a 4.5 kW transcritical CO2 heat pump water heater at Queens University in the (more)

  7. Analytical Estimation of CO2 Storage Capacity in Depleted Oil and Gas Reservoirs Based on Thermodynamic State Functions

    E-Print Network [OSTI]

    Valbuena Olivares, Ernesto

    2012-02-14T23:59:59.000Z

    Numerical simulation has been used, as common practice, to estimate the CO2 storage capacity of depleted reservoirs. However, this method is time consuming, expensive and requires detailed input data. This investigation proposes an analytical method...

  8. CO2 gas/oil ratio prediction in a multi-component reservoir bycombined seismic and electromagnetic imaging

    SciTech Connect (OSTI)

    Hoversten, G.M.; Gritto, Roland; Washbourne, John; Daley, Tom

    2002-08-28T23:59:59.000Z

    Crosswell seismic and electromagnetic data sets taken before and during CO2 flooding of an oil reservoir are inverted to produce crosswell images of the change in compressional velocity, shear velocity and electrical conductivity during a CO2 injection pilot study. A rock properties model is developed using measured log porosity, fluid saturations, pressure, temperature, bulk density, sonic velocity and electrical conductivity. The parameters of the rock properties model are found by an L1-norm simplex minimization of predicted and observed compressional velocity and density. A separate minimization using Archie's law provides parameters for modeling the relations between water saturation, porosity and the electrical conductivity. The rock properties model is used to generate relationships between changes in geophysical parameters and changes in reservoir parameters. The electrical conductivity changes are directly mapped to changes in water saturation. The estimated changes in water saturation are used with the observed changes in shear wave velocity to predict changes in reservoir pressure. The estimation of the spatial extent and amount of CO2 relies on first removing the effects of the water saturation and pressure changes from the observed compressional velocity changes, producing a residual compressional velocity change. The residual compressional velocity change is then interpreted in terms of increases in the CO2 /oil ratio. Resulting images of CO2/oil ratio show CO2 rich zones that are well correlated with the location of injection perforations with the size of these zones also correlating to the amount of injected CO2. The images produced by this process are better correlated to the location and amount of injected CO2 than are any of the individual images of change in geophysical parameters.

  9. TECHNICAL REPORTS The greenhouse gas (GHG) impact of composting a range

    E-Print Network [OSTI]

    Brown, Sally

    TECHNICAL REPORTS 1396 The greenhouse gas (GHG) impact of composting a range of potential by composting and GHG emissions during composting. The primary carbon credits associated with composting are through CH4 avoidance when feedstocks are composted instead of landfilled (municipal solid waste

  10. 2007-No54-BoilingPoint Health and Greenhouse Gas Impacts of Biomass and Fossil Fuel

    E-Print Network [OSTI]

    Kammen, Daniel M.

    2007-No54-BoilingPoint Theme Health and Greenhouse Gas Impacts of Biomass and Fossil Fuel Energy of fossil-fuel energy systems. These scenarios are analysed for various environmental and health impacts from fossil fuels and other energy sources reported by IEA []. In all of these countries except Kenya

  11. Bioenergy crop greenhouse gas mitigation potential under a range of management practices

    E-Print Network [OSTI]

    DeLucia, Evan H.

    Bioenergy crop greenhouse gas mitigation potential under a range of management practices T A R A W been proposed as viable bioenergy crops because of their potential to yield harvest- able biomass-senescence harvests are a more effective means than maximizing yield potential. Keywords: bioenergy, feedstocks, GHG

  12. IMproved Assessment of the Greenhouse gas balance of bioeNErgy pathways (IMAGINE)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    IMproved Assessment of the Greenhouse gas balance of bioeNErgy pathways (IMAGINE) Evaluation - ENERBIO Livrable D4.1 : GHG balances of bioenergy pathways Mars 2012 Nathalie GAGNAIRE, Benoît GABRIELLE sources by bioenergy mostly hinges on the uncertainty on the magnitude of nitrous oxide (N2O) emissions

  13. Response to Comment on "Prevented Mortality and Greenhouse Gas Emissions from Historical and Projected Nuclear Power"

    E-Print Network [OSTI]

    Response to Comment on "Prevented Mortality and Greenhouse Gas Emissions from Historical, and properly (sustain- ably) designed biomass energy (e.g., see ref 3). This is rooted in the fact that wind production by 2022 following Japan's Fukushima nuclear accident. Despite a major, laudable expansion of wind

  14. U.S. Greenhouse Gas Intensity and the Global Climate Change Initiative (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    On February 14, 2002, President Bush announced the Administrations Global Climate Change Initiative. A key goal of the Climate Change Initiative is to reduce U.S. greenhouse gas (GHG) intensity-defined as the ratio of total U.S. GHG emissions to economic output-by 18% over the 2002 to 2012 time frame.

  15. Greenhouse Gas Pollution in the Stratosphere Due to Increasing Airplane Traffic, Effects On the Environment

    E-Print Network [OSTI]

    Murty, Katta G.

    Greenhouse Gas Pollution in the Stratosphere Due to Increasing Airplane Traffic, Effects On the Environment Katta G. Murty Department of Industrial and Operations Engineering University of Michigan, Ann to tremendous increases in the construction of huge airport facilities, the development of large jumbo

  16. Scaling Behavior of the Life Cycle Energy of Residential Buildings and Impacts on Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Hall, Sharon J.

    Scaling Behavior of the Life Cycle Energy of Residential Buildings and Impacts on Greenhouse Gas the single-family detached homes ana- lyzed. Figure A shows that the energy used on-site during the construction phase of a single story 1,500 ft2 home corresponds to 5.10% the total energy used in the life

  17. ESTIMATING THE IMPACT OF DEMOGRAPHICS AND AUTOMOTIVE TECHNOLOGIES ON GREENHOUSE GAS

    E-Print Network [OSTI]

    Hellinga, Bruce

    McNally, MASc Candidate Bruce Hellinga, PhD, PEng Department of Civil Engineering University of Transportation Engineers to be held May 12-15, 2002 in Ottawa Ontario #12;1 Estimating the Impact of Demographics and Automotive Technologies on Greenhouse Gas Emissions Ryan McNally, MASc Candidate Bruce Hellinga, PhD, PEng

  18. Determine Vehicle Usage and Refueling Trends to Minimize Greenhouse Gas Emissions

    Broader source: Energy.gov [DOE]

    Once a Federal agency has identified its most important mobile greenhouse gas (GHG) emission sources overall, it can work with individual sites to determine vehicle usage and refueling trends. Agencies can compare the results of this analysis to internal standards and requirements to identify GHG mitigation opportunities for assets that are underperforming or underutilized.

  19. Carbon and nitrogen dynamics in bioenergy ecosystems: 2. Potential greenhouse gas emissions and global

    E-Print Network [OSTI]

    Zhuang, Qianlai

    Carbon and nitrogen dynamics in bioenergy ecosystems: 2. Potential greenhouse gas emissions) from bioenergy ecosystems with a biogeochemical model AgTEM, assuming maize (Zea mays L.), switchgrass ha?1 yr?1 . Among all three bioenergy crops, Miscanthus is the most biofuel productive and the least

  20. Tax-versus-trading and efficient revenue recycling as issues for greenhouse gas abatement

    E-Print Network [OSTI]

    Pezzey, Jack

    Tax-versus-trading and efficient revenue recycling as issues for greenhouse gas abatement Final abatement, using the first multi-party model to include both tax-versus-trading under uncertainties of an emissions tax over emissions (permit) trading in handling abatement-cost uncertainties, from that shown

  1. Greenhouse-gas emission targets for limiting global warming to 2 6C

    E-Print Network [OSTI]

    Imamoglu, Atac

    LETTERS Greenhouse-gas emission targets for limiting global warming to 2 6C Malte Meinshausen1. Frame6,7 & Myles R. Allen7 More than 100 countries have adopted a global warming limit of 2 6C or below levels in 2050 are robust indicators of the probability that twenty-first century warming will not exceed

  2. The hydrogen energy economy: its long-term role in greenhouse gas reduction

    E-Print Network [OSTI]

    Watson, Andrew

    The hydrogen energy economy: its long-term role in greenhouse gas reduction Geoff Dutton, Abigail for Climate Change Research Technical Report 18 #12;The Hydrogen Energy Economy: its long term role 2005 This is the final report from Tyndall research project IT1.26 (The Hydrogen energy economy: its

  3. Quantitative analysis of factors affecting greenhouse gas emissions at institutions of higher education

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    States, emissions from buildings comprise 40% of energy consumption and carbon emissions, not including to have 10 times more effect on emissions per square meter than space such as classroom and office, while to the institution's own greenhouse gas emission reductions, energy and water conservation, and other sustainability

  4. Assessing the fuel Use and greenhouse gas emissions of future light-duty vehicles in Japan

    E-Print Network [OSTI]

    Nishimura, Eriko

    2011-01-01T23:59:59.000Z

    Reducing greenhouse gas (GHG) emissions is of great concern in Japan, as well as elsewhere, such as in the U.S. and EU. More than 20% of GHG emissions in Japan come from the transportation sector, and a more than 70% ...

  5. The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1

    E-Print Network [OSTI]

    technologies. · Coal Conversion Technologies. Coal-based power generation technologies were analyzed in detail1 The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1 , James Katzer1 1 M coal can make to the growing world energy demand during a period of increasing concern about global

  6. Potential for Biofuel-based Greenhouse Gas Emission Mitigation: Rationale and Potential

    E-Print Network [OSTI]

    McCarl, Bruce A.

    1 Potential for Biofuel-based Greenhouse Gas Emission Mitigation: Rationale and Potential By Bruce biofuel usage. Biofuel feedstocks are a source of raw material that can be transformed into petroleum for coal. In the USA, liquid fuel biofuel production has not proven to be broadly economically feasible

  7. Energy, environmental and greenhouse gas effects of using alternative fuels in cement production

    E-Print Network [OSTI]

    Columbia University

    1 Energy, environmental and greenhouse gas effects of using alternative fuels in cement to an increase of AF use from 8.7% to 20.9% of the total energy consumption. 2. One of the alternative fuels used cement industry produces about 3.3 billion tonnes of cement annually. Cement production is energy

  8. Economic Implications of International Participation Alternatives for Agricultural Greenhouse Gas Emission Mitigation

    E-Print Network [OSTI]

    McCarl, Bruce A.

    of International Participation Alternatives for Agricultural Greenhouse Gas Emission Mitigation Abstract The world of biofuels. However, such options can be competitive with domestic food production. In a free trade arena of effects that would be observed due to the simplifying cost assumptions, indicate compliance causes supply

  9. Hybrid modeling of industrial energy consumption and greenhouse gas emissions with an application to Canada

    E-Print Network [OSTI]

    implemented in Canada, what would be the response of the industrial sector in terms of energy consumptionHybrid modeling of industrial energy consumption and greenhouse gas emissions with an application for modeling industrial energy consumption, among them a series of environmental and security externalities

  10. 8 Prospects for Biological Carbon Sinks in Greenhouse Gas Emissions Trading Systems

    E-Print Network [OSTI]

    8 Prospects for Biological Carbon Sinks in Greenhouse Gas Emissions Trading Systems John Reilly1. With emissions trading, emitters who found they could cheaply reduce their emissions might have allowances- ing Australia, Canada, Japan and Russia. This group also pushed strongly for inter- national emissions

  11. A graphical technique for explaining the relationship between energy security and greenhouse gas emissions

    E-Print Network [OSTI]

    Hughes, Larry

    ERG/200806 A graphical technique for explaining the relationship between energy security and the differences between energy security and greenhouse gas emissions. This paper presents a graphical technique. This paper presents a graphical technique for illustrating the relationship between energy security

  12. California's Greenhouse Gas Policies: Local Solutions to a Global Problem?

    E-Print Network [OSTI]

    Bushnell, Jim B; Peterman, Carla Joy; Wolfram, Catherine D

    2007-01-01T23:59:59.000Z

    RPS programs of states in the WECC is from The Database forRenewables Natural Gas Oil Coal AZ-NM OR-WA Rest of WECCTotal WECC % Total WECC Source: Platts Powerdat database.

  13. Northern California CO2 Reduction Project

    SciTech Connect (OSTI)

    Hymes, Edward

    2010-06-16T23:59:59.000Z

    C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

  14. Greenhouse Gas Return on Investment: A New Metric for Energy Technology

    E-Print Network [OSTI]

    Reich-Weiser, Corinne; Dornfeld, David; Horne, Steve

    2008-01-01T23:59:59.000Z

    Statistics Electrolux CO2 emissions (most recent) byAdditionally, there are CO2 emissions associated with theonly accounts for the CO2 emissions associated with fuel

  15. Assessment of basic research needs for greenhouse gas control technologies

    SciTech Connect (OSTI)

    Benson, S.M.; Chandler, W.; Edmonds, J.; Houghton, J.; Levine, M.; Bates, L.; Chum, H.; Dooley, J.; Grether, D.; Logan, J.; Wiltsee, G.; Wright, L.

    1998-09-01T23:59:59.000Z

    This paper is an outgrowth of an effort undertaken by the Department of Energy's Office of Energy Research to assess the fundamental research needs to support a national program in carbon management. Five topics were identified as areas where carbon management strategies and technologies might be developed: (1) capture of carbon dioxide, decarbonization strategies, and carbon dioxide disposal and utilization; (2) hydrogen development and fuel cells; (3) enhancement of the natural carbon cycle; (4) biomass production and utilization; and (5) improvement of the efficiency of energy production, conversion, and utilization. Within each of these general areas, experts came together to identify targets of opportunity for fundamental research likely to lead to the development of mid- to long-term solutions for stabilizing or decreasing carbon dioxide and other greenhouse gases in the atmosphere. Basic research to support the options outlined above are far reaching-from understanding natural global processes such as the ocean and terrestrial carbon cycles to development of new materials and concepts for chemical separation. Examples of fundamental research needs are described in this paper.

  16. Influence of capillary pressure on CO2 storage and monitoring

    E-Print Network [OSTI]

    gabriela

    solutions to mitigate the greenhouse effect. We are interested in analyzing the influence of capillary pressure on CO2 in- jection, storage and monitoring in saline...

  17. Mexico joins the venture: Joint Implementation and Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Imaz, M.; Gay, C.; Friedmann, R.; Goldberg, B.

    1998-11-01T23:59:59.000Z

    Joint Implementation (JI) and its pilot phase of Activities Implemented Jointly (AIJ) are envisioned as an economic way of reducing global emissions of greenhouse gases. This paper draws upon the Mexican experience with AIJ to identify Mexican concerns with AIJ/JI and proposed solutions to these. Three approved Mexican AIJ projects (Ilumex, Scolel Te, and Salicornia) are described in detail. The Ilurnex project promotes the use of compact fluorescent lamps in Mexican homes of the States of Jalisco and Nuevo Leon, to reduce electric demand. Scolel Te is a sustainable forest management project in Chiapas. Salicornia examines the potential for carbon sequestration with a Halophyte-based crop irrigated with saline waters in Sonora. These three projects are reviewed to clarify the issues and concerns that Mexico has with AIJ and JI and propose measures to deal with them. These initial Mexican AIJ projects show that there is a need for creation of standard project evaluation procedures, and criteria and institutions to oversee project design, selection, and implementation. Further JI development will be facilitated by national and international clarification of key issues such as additionality criteria, carbon-credit sharing, and valuation of non-GHG environmental and/or social benefits and impacts for AIJ projects. Mexico is concerned that JI funding could negatively impact official development assistance or that OECD countries will use JI to avoid taking significant GHG mitigation actions in their own countries. The lack of carbon credit trading in the AIJ stage must be removed to provide useful experience on how to share carbon credits. National or international guidelines are needed to ensure that a portion of the carbon credits is allocated to Mexico.

  18. QGESS: CO2 Impurity Design Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10. Shah, Minish. Capturing CO2 from Oxy-Fuel Combustion Flue Gas. Cottbus, Germany : Praxair Inc., 2005. 11. Spitznogle, Gary O. CO2 Impurity Specification at AEP Mountaineer....

  19. Analytical solution for Joule-Thomson cooling during CO2 geo-sequestration in depleted oil and gas reservoirs

    E-Print Network [OSTI]

    Mathias, S.A.

    2010-01-01T23:59:59.000Z

    sequestration in depleted oil and gas reservoirs Simon A.1. Introduction Depleted oil and gas reservoirs (DOGRs)

  20. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: AlternativeEnvironment,Institutes and1 SpecialMaximizingResidential Buildings »CoilGas Reductions

  1. Greenhouse Gas Inventory Development Toolkit | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartmentAUDIT REPORTOpen EnergyBoard" form. ToGestionSolar Inc GTSGreenhouse Gas

  2. Impact of Sorption Isotherms on the Simulation of CO2-Enhanced Gas Recovery and Storage Process in Marcellus Shale

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    and kerogen surfaces, very similar to the way methane is stored within coal beds. It has been demonstrated in gassy coals that on average; CO2 is preferentially adsorbed, displacing methane at a ratio of two for one or more. Black shale reservoirs may react similarly and desorb methane in the presence

  3. Greenhouse Gases | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gases Greenhouse Gases Executive Order 13514 requires Federal agencies to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate...

  4. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31T23:59:59.000Z

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  5. The Techno-economic Impacts of Using Wind Power and Plug-In Hybrid Electric Vehicles for Greenhouse Gas

    E-Print Network [OSTI]

    Victoria, University of

    The Techno-economic Impacts of Using Wind Power and Plug-In Hybrid Electric Vehicles for Greenhouse reliance on fossil fuels. Plug-In Hybrid Electric Vehicles (PHEVs) and wind power represent two practical Electric Vehicles for Greenhouse Gas Mitigation in Canada by Brett Kerrigan B.Eng., Carleton University

  6. Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans

    E-Print Network [OSTI]

    Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European determinants of life cycle emissions of greenhouse gases linked to the life cycle of biodiesel from European rapeseed and Brazilian soybeans. For biodiesel from European rapeseed and for biodiesel from Brazilian

  7. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18T23:59:59.000Z

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

  8. Renewable portfolio standards, Greenhouse gas reduction, and Long-Line transmission investments in the WECC

    SciTech Connect (OSTI)

    Olson, Arne; Orans, Ren; Allen, Doug; Moore, Jack; Woo, C.K.

    2009-11-15T23:59:59.000Z

    New, long-distance transmission lines to remote areas with concentrations of high-quality renewable resources can help western states meet the challenges of increasing renewable energy procurement and reducing greenhouse gas emissions more cost-effectively than reliance on local resources alone. The approach applied here to the Western Electricity Coordinating Council is useful for an initial determination of the net benefits of long-line transmission between regions with heterogeneous resource quality. (author)

  9. California Greenhouse Gas Emissions Standards for Light-Duty Vehicles (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01T23:59:59.000Z

    In July 2002, California Assembly Bill 1493 (A.B. 1493) was signed into law. The law requires that the California Air Resources Board (CARB) develop and adopt, by January 1, 2005, greenhouse gas emission standards for light-duty vehicles that provide the maximum feasible reduction in emissions. In estimating the feasibility of the standard, CARB is required to consider cost-effectiveness, technological capability, economic impacts, and flexibility for manufacturers in meeting the standard.

  10. Detection of greenhouse-gas-induced climatic change. Progress report, July 1, 1994--July 31, 1995

    SciTech Connect (OSTI)

    Jones, P.D.; Wigley, T.M.L.

    1995-07-21T23:59:59.000Z

    The objective of this research is to assembly and analyze instrumental climate data and to develop and apply climate models as a basis for detecting greenhouse-gas-induced climatic change, and validation of General Circulation Models. In addition to changes due to variations in anthropogenic forcing, including greenhouse gas and aerosol concentration changes, the global climate system exhibits a high degree of internally-generated and externally-forced natural variability. To detect the anthropogenic effect, its signal must be isolated from the ``noise`` of this natural climatic variability. A high quality, spatially extensive data base is required to define the noise and its spatial characteristics. To facilitate this, available land and marine data bases will be updated and expanded. The data will be analyzed to determine the potential effects on climate of greenhouse gas and aerosol concentration changes and other factors. Analyses will be guided by a variety of models, from simple energy balance climate models to coupled atmosphere ocean General Circulation Models. These analyses are oriented towards obtaining early evidence of anthropogenic climatic change that would lead either to confirmation, rejection or modification of model projections, and towards the statistical validation of General Circulation Model control runs and perturbation experiments.

  11. Estimating the greenhouse gas benefits of forestry projects: A Costa Rican Case Study

    SciTech Connect (OSTI)

    Busch, Christopher; Sathaye, Jayant; Sanchez Azofeifa, G. Arturo

    2000-09-01T23:59:59.000Z

    If the Clean Development Mechanism proposed under the Kyoto Protocol is to serve as an effective means for combating global climate change, it will depend upon reliable estimates of greenhouse gas benefits. This paper sketches the theoretical basis for estimating the greenhouse gas benefits of forestry projects and suggests lessons learned based on a case study of Costa Rica's Protected Areas Project, which is a 500,000 hectare effort to reduce deforestation and enhance reforestation. The Protected Areas Project in many senses advances the state of the art for Clean Development Mechanism-type forestry projects, as does the third-party verification work of SGS International Certification Services on the project. Nonetheless, sensitivity analysis shows that carbon benefit estimates for the project vary widely based on the imputed deforestation rate in the baseline scenario, e.g. the deforestation rate expected if the project were not implemented. This, along with a newly available national dataset that confirms other research showing a slower rate of deforestation in Costa Rica, suggests that the use of the 1979--1992 forest cover data originally as the basis for estimating carbon savings should be reconsidered. When the newly available data is substituted, carbon savings amount to 8.9 Mt (million tones) of carbon, down from the original estimate of 15.7 Mt. The primary general conclusion is that project developers should give more attention to the forecasting land use and land cover change scenarios underlying estimates of greenhouse gas benefits.

  12. Plant power : the cost of using biomass for power generation and potential for decreased greenhouse gas emissions

    E-Print Network [OSTI]

    Cuellar, Amanda Dulcinea

    2012-01-01T23:59:59.000Z

    To date, biomass has not been a large source of power generation in the United States, despite the potential for greenhouse gas (GHG) benefits from displacing coal with carbon neutral biomass. In this thesis, the fuel cycle ...

  13. U.S. Greenhouse Gas Cap-and-Trade Proposals: Application of a Forward-Looking Computable General Equilibrium Model

    E-Print Network [OSTI]

    Gurgel, Angelo C.

    We develop a forward-looking version of the MIT Emissions Prediction and Policy Analysis (EPPA) model, and apply it to examine the economic implications of proposals in the U.S. Congress to limit greenhouse gas (GHG) ...

  14. Behavior-Based Transportation Greenhouse Gas Mitigation Under the Clean Development Mechanism Transport-Efficient Development in Nanchang, China

    E-Print Network [OSTI]

    Zegras, P. Christopher

    We propose a methodology, consistent with the Kyoto Protocol?s Clean Development Mechanism (CDM), to quantify the greenhouse gas (GHG) emission reduction benefits of transport efficient development (TED). TED aims to reduce ...

  15. Life cycle assessment of greenhouse gas emissions and non-CO? combustion effects from alternative jet fuels

    E-Print Network [OSTI]

    Stratton, Russell William

    2010-01-01T23:59:59.000Z

    The long-term viability and success of a transportation fuel depends on both economic and environmental sustainability. This thesis focuses specifically on assessing the life cycle greenhouse gas (GHG) emissions and non-CO ...

  16. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01T23:59:59.000Z

    of Geologic Storage of CO2, in Carbon Dioxide Capture forFormations - Results from the CO2 Capture Project: GeologicBenson, Process Modeling of CO2 Injection into Natural Gas

  17. Battery-Powered Electric and Hybrid Electric Vehicle Projects to Reduce Greenhouse Gas Emissions: A Resource for Project Development

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2002-07-31T23:59:59.000Z

    The transportation sector accounts for a large and growing share of global greenhouse gas (GHG) emissions. Worldwide, motor vehicles emit well over 900 million metric tons of carbon dioxide (CO2) each year, accounting for more than 15 percent of global fossil fuel-derived CO2 emissions.1 In the industrialized world alone, 20-25 percent of GHG emissions come from the transportation sector. The share of transport-related emissions is growing rapidly due to the continued increase in transportation activity.2 In 1950, there were only 70 million cars, trucks, and buses on the worlds roads. By 1994, there were about nine times that number, or 630 million vehicles. Since the early 1970s, the global fleet has been growing at a rate of 16 million vehicles per year. This expansion has been accompanied by a similar growth in fuel consumption.3 If this kind of linear growth continues, by the year 2025 there will be well over one billion vehicles on the worlds roads.4 In a response to the significant growth in transportation-related GHG emissions, governments and policy makers worldwide are considering methods to reverse this trend. However, due to the particular make-up of the transportation sector, regulating and reducing emissions from this sector poses a significant challenge. Unlike stationary fuel combustion, transportation-related emissions come from dispersed sources. Only a few point-source emitters, such as oil/natural gas wells, refineries, or compressor stations, contribute to emissions from the transportation sector. The majority of transport-related emissions come from the millions of vehicles traveling the worlds roads. As a result, successful GHG mitigation policies must find ways to target all of these small, non-point source emitters, either through regulatory means or through various incentive programs. To increase their effectiveness, policies to control emissions from the transportation sector often utilize indirect means to reduce emissions, such as requiring specific technology improvements or an increase in fuel efficiency. Site-specific project activities can also be undertaken to help decrease GHG emissions, although the use of such measures is less common. Sample activities include switching to less GHG-intensive vehicle options, such as electric vehicles (EVs) or hybrid electric vehicles (HEVs). As emissions from transportation activities continue to rise, it will be necessary to promote both types of abatement activities in order to reverse the current emissions path. This Resource Guide focuses on site- and project-specific transportation activities. .

  18. CO2 sequestration | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 sequestration CO2 sequestration Leads No leads are available at this time. Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on...

  19. Detection of greenhouse-gas-induced climatic change. Progress report, 1 December 1991--30 June 1992

    SciTech Connect (OSTI)

    Wigley, T.M.L.; Jones, P.D.

    1992-07-15T23:59:59.000Z

    The aims of the US Department of Energy`s Carbon Dioxide Research Program are to improve assessments of greenhouse-gas-induced climatic change and to define and reduce uncertainties through selected research. This project will address: The regional and seasonal details of the expected climatic changes; how rapidly will these changes occur; how and when will the climatic effects of CO{sub 2} and other greenhouse gases be first detected; and the relationships between greenhouse-gas-induced climatic change and changes caused by other external and internal factors. The present project addresses all of these questions. Many of the diverse facets of greenhouse-gas-related climate research can be grouped under three interlinked subject areas: modeling, first detection and supporting data. This project will include the analysis of climate forcing factors, the development and refinement of transient response climate models, and the use of instrumental data in validating General Circulation Models (GCMs).

  20. The Greenhouse Effect without Feedbacks

    E-Print Network [OSTI]

    The Greenhouse Effect without Feedbacks #12;Three Pillars Behind Climate Change! #12;1. Global. Greenhouse Gases have been on the increase. #12;3. The Greenhouse effect is a powerful theory that explains! natural greenhouse effect! · an empirical introduction #12;Moral of the story: The doubling of CO2 causes

  1. Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals

    Broader source: Energy.gov [DOE]

    Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Suresh Babu, Senior Program Manager, Biomass Program Development, Brookhaven National Laboratory

  2. Greenhouse gas emission impacts of alternative-fueled vehicles: Near-term vs. long-term technology options

    SciTech Connect (OSTI)

    Wang, M.Q.

    1997-05-20T23:59:59.000Z

    Alternative-fueled vehicle technologies have been promoted and used for reducing petroleum use, urban air pollution, and greenhouse gas emissions. In this paper, greenhouse gas emission impacts of near-term and long-term light-duty alternative-fueled vehicle technologies are evaluated. Near-term technologies, available now, include vehicles fueled with M85 (85% methanol and 15% gasoline by volume), E85 (85% ethanol that is produced from corn and 15% gasoline by volume), compressed natural gas, and liquefied petroleum gas. Long-term technologies, assumed to be available around the year 2010, include battery-powered electric vehicles, hybrid electric vehicles, vehicles fueled with E85 (ethanol produced from biomass), and fuel-cell vehicles fueled with hydrogen or methanol. The near-term technologies are found to have small to moderate effects on vehicle greenhouse gas emissions. On the other hand, the long-term technologies, especially those using renewable energy (such as biomass and solar energy), have great potential for reducing vehicle greenhouse gas emissions. In order to realize this greenhouse gas emission reduction potential, R and D efforts must continue on the long-term technology options so that they can compete successfully with conventional vehicle technology.

  3. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott [ORNL; Theiss, Timothy J [ORNL; Bunce, Michael [ORNL

    2012-01-01T23:59:59.000Z

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  4. Evaluation of metrics and baselines for tracking greenhouse gas emissions trends: Recommendations for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Murtishaw, Scott; Worrell, Ernst

    2003-06-01T23:59:59.000Z

    Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California Energy Commission (Energy Commission) related to the Registry in three areas: (1) assessing the availability and usefulness of industry-specific metrics, (2) evaluating various methods for establishing baselines for calculating GHG emissions reductions related to specific actions taken by Registry participants, and (3) establishing methods for calculating electricity CO2 emission factors. The third area of research was completed in 2002 and is documented in Estimating Carbon Dioxide Emissions Factors for the California Electric Power Sector (Marnay et al., 2002). This report documents our findings related to the first areas of research. For the first area of research, the overall objective was to evaluate the metrics, such as emissions per economic unit or emissions per unit of production that can be used to report GHG emissions trends for potential Registry participants. This research began with an effort to identify methodologies, benchmarking programs, inventories, protocols, and registries that u se industry-specific metrics to track trends in energy use or GHG emissions in order to determine what types of metrics have already been developed. The next step in developing industry-specific metrics was to assess the availability of data needed to determine metric development priorities. Berkeley Lab also determined the relative importance of different potential Registry participant categories in order to asses s the availability of sectoral or industry-specific metrics and then identified industry-specific metrics in use around the world. While a plethora of metrics was identified, no one metric that adequately tracks trends in GHG emissions while maintaining confidentiality of data was identified. As a result of this review, Berkeley Lab recommends the development of a GHG intensity index as a new metric for reporting and tracking GHG emissions trends.Such an index could provide an industry-specific metric for reporting and tracking GHG emissions trends to accurately reflect year to year changes while protecting proprietary data. This GHG intensity index changes

  5. Beyond the Inventory: An Interagency Collaboration to Reduce Greenhouse Gas Emissions in the Greater Yellowstone Area

    SciTech Connect (OSTI)

    Kandt, A.; Hotchkiss, E.; Fiebig, M.

    2010-10-01T23:59:59.000Z

    As one of the largest, intact ecosystems in the continental United States, land managers within the Greater Yellowstone Area (GYA) have recognized the importance of compiling and understanding agency greenhouse gas (GHG) emissions. The 10 Federal units within the GYA have taken an active role in compiling GHG inventories on a unit- and ecosystem-wide level, setting goals for GHG mitigation, and identifying mitigation strategies for achieving those goals. This paper details the processes, methodologies, challenges, solutions, and lessons learned by the 10 Federal units within the GYA throughout this ongoing effort.

  6. Preliminary Estimates of Combined Heat and Power Greenhouse GasAbatement Potential for California in 2020

    SciTech Connect (OSTI)

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare,Kristina

    2007-07-31T23:59:59.000Z

    The objective of this scoping project is to help the California Energy Commission's (CEC) Public Interest Energy Research (PIER) Program determine where it should make investments in research to support combined heat and power (CHP) deployment. Specifically, this project will: {sm_bullet} Determine what impact CHP might have in reducing greenhouse gas (GHG) emissions, {sm_bullet} Determine which CHP strategies might encourage the most attractive early adoption, {sm_bullet} Identify the regulatory and technological barriers to the most attractive CHP strategies, and {sm_bullet} Make recommendations to the PIER program as to research that is needed to support the most attractive CHP strategies.

  7. Assess Site Factors That Affect Employee Commuting Options for Greenhouse Gas Profile

    Broader source: Energy.gov [DOE]

    After establishing an employee commuting behavior baseline for evaluating a greenhouse gas (GHG) profile, analyze the specific characteristics of the agency's major worksites to help determine which alternative commute methods and work arrangements are viable and what types of strategies may be most effective for promoting those alternatives. It is recommended that worksite-level data collection focus on worksites with the: Largest number of employees, or clusters of worksites with large employee populations in an area with diverse commuting infrastructure options (e.g., Washington, DC, metropolitan area) Greatest proportion of total commute emissions Highest commuting emissions per person than agency average.

  8. The RCP Greenhouse Gas Concentrations and their Extensions from 1765 to 2300

    SciTech Connect (OSTI)

    Meinshausen, Malte; Smith, Steven J.; Calvin, Katherine V.; Daniel, John S.; Kainuma, M.; Lamarque, J.-F.; Matsumoto, Ken ichi; Montzka, S.; Raper, S.; Riahi, Keywan; Thomson, Allison M.; Velders, G.J.M; Van Vuuren, Detlef

    2011-08-01T23:59:59.000Z

    We present the greenhouse gas concentrations for the Representative Concentration Pathways (RCPs) and their extensions beyond 2100, the Extended Concentration Pathways (ECPs). These projections include all major anthropogenic greenhouse gases and are a result of a multi-year effort to produce new scenarios for climate change research. We first compiled a suite of observations and emissions estimates for greenhouse gases (GHGs) through the historical period (1750-2005). For the 21st century, we start from emissions projected by four different Integrated Assessment Models for 2005-2100. We harmonize these emissions to allow inter-comparability of scenarios and to achieve a smooth transition from historical data. These harmonized emissions are then used to derive future GHG concentrations. We also present the GHG concentrations for one supplementary extension, which illustrates the emissions implications of attempting to go back to ECP4.5 concentration levels after emissions in the 21st century followed RCP6. Corresponding radiative forcing values are also presented for the RCP and ECPs.

  9. Air-sea gas exchange of CO 2 and DMS in the North Atlantic by eddy covariance

    E-Print Network [OSTI]

    Miller, Scott D; Marandino, Christa A; De Bruyn, Warren; Saltzman, Eric S; McCormick, C.

    2009-01-01T23:59:59.000Z

    measurements of the air/sea flux of dimethylsulfide over the2008a), Open ocean DMS air/sea fluxes over the eastern SouthE. S. Saltzman (2008b), DMS air/sea flux and gas transfer

  10. The California Climate Action Registry: Development of methodologies for calculating greenhouse gas emissions from electricity generation

    SciTech Connect (OSTI)

    Price, Lynn; Marnay, Chris; Sathaye, Jayant; Muritshaw, Scott; Fisher, Diane; Phadke, Amol; Franco, Guido

    2002-08-01T23:59:59.000Z

    The California Climate Action Registry, which will begin operation in Fall 2002, is a voluntary registry for California businesses and organizations to record annual greenhouse gas emissions. Reporting of emissions in the Registry by a participant involves documentation of both ''direct'' emissions from sources that are under the entity's control and ''indirect'' emissions controlled by others. Electricity generated by an off-site power source is considered to be an indirect emission and must be included in the entity's report. Published electricity emissions factors for the State of California vary considerably due to differences in whether utility-owned out-of-state generation, non-utility generation, and electricity imports from other states are included. This paper describes the development of three methods for estimating electricity emissions factors for calculating the combined net carbon dioxide emissions from all generating facilities that provide electricity to Californians. We find that use of a statewide average electricity emissions factor could drastically under- or over-estimate an entity's emissions due to the differences in generating resources among the utility service areas and seasonal variations. In addition, differentiating between marginal and average emissions is essential to accurately estimate the carbon dioxide savings from reducing electricity use. Results of this work will be taken into consideration by the Registry when finalizing its guidance for use of electricity emissions factors in calculating an entity's greenhouse gas emissions.

  11. Microbial communities and greenhouse gas emissions associated with the biodegradation of specified risk material in compost

    SciTech Connect (OSTI)

    Xu, Shanwei [Department of Agricultural, Food and Nutritional Science, University of Alberta, Edmonton, Alberta, Canada T6G 2P5 (Canada); Agriculture and Agri-Food Canada, Lethbridge Research Centre, P.O. Box 3000, Lethbridge, Alberta, Canada T1J 4B1 (Canada); Reuter, Tim [Alberta Agriculture and Rural Development, Lethbridge, Alberta, Canada T1J 4V6 (Canada); Gilroyed, Brandon H. [Agriculture and Agri-Food Canada, Lethbridge Research Centre, P.O. Box 3000, Lethbridge, Alberta, Canada T1J 4B1 (Canada); Tymensen, Lisa [Alberta Agriculture and Rural Development, Lethbridge, Alberta, Canada T1J 4V6 (Canada); Hao, Yongxin; Hao, Xiying [Agriculture and Agri-Food Canada, Lethbridge Research Centre, P.O. Box 3000, Lethbridge, Alberta, Canada T1J 4B1 (Canada); Belosevic, Miodrag [Department of Biological Science, University of Alberta, Edmonton, Alberta, Canada T6G 2E9 (Canada); Leonard, Jerry J. [Department of Agricultural, Food and Nutritional Science, University of Alberta, Edmonton, Alberta, Canada T6G 2P5 (Canada); McAllister, Tim A., E-mail: tim.mcallister@agr.gc.ca [Agriculture and Agri-Food Canada, Lethbridge Research Centre, P.O. Box 3000, Lethbridge, Alberta, Canada T1J 4B1 (Canada)

    2013-06-15T23:59:59.000Z

    Highlights: ? Addition of feathers altered bacterial and fungal communities in compost. ? Microbial communities degrading SRM and compost matrix were distinct. ? Addition of feathers may enrich for microbial communities that degrade SRM. ? Inclusion of feather in compost increased both CH{sub 4} and N{sub 2}O emissions from compost. ? Density of methanogens and methanotrophs were weakly associated with CH{sub 4} emissions. - Abstract: Provided that infectious prions (PrP{sup Sc}) are inactivated, composting of specified risk material (SRM) may be a viable alternative to rendering and landfilling. In this study, bacterial and fungal communities as well as greenhouse gas emissions associated with the degradation of SRM were examined in laboratory composters over two 14 day composting cycles. Chicken feathers were mixed into compost to enrich for microbial communities involved in the degradation of keratin and other recalcitrant proteins such as prions. Feathers altered the composition of bacterial and fungal communities primarily during the first cycle. The bacterial genera Saccharomonospora, Thermobifida, Thermoactinomycetaceae, Thiohalospira, Pseudomonas, Actinomadura, and Enterobacter, and the fungal genera Dothideomycetes, Cladosporium, Chaetomium, and Trichaptum were identified as candidates involved in SRM degradation. Feathers increased (P < 0.05) headspace concentrations of CH{sub 4} primarily during the early stages of the first cycle and N{sub 2}O during the second. Although inclusion of feathers in compost increases greenhouse gas emissions, it may promote the establishment of microbial communities that are more adept at degrading SRM and recalcitrant proteins such as keratin and PrP{sup Sc}.

  12. Sector trends and driving forces of global energy use and greenhouse gas emissions: focus in industry and buildings

    SciTech Connect (OSTI)

    Price, Lynn; Worrell, Ernst; Khrushch, Marta

    1999-09-01T23:59:59.000Z

    Disaggregation of sectoral energy use and greenhouse gas emissions trends reveals striking differences between sectors and regions of the world. Understanding key driving forces in the energy end-use sectors provides insights for development of projections of future greenhouse gas emissions. This report examines global and regional historical trends in energy use and carbon emissions in the industrial, buildings, transport, and agriculture sectors, with a more detailed focus on industry and buildings. Activity and economic drivers as well as trends in energy and carbon intensity are evaluated. The authors show that macro-economic indicators, such as GDP, are insufficient for comprehending trends and driving forces at the sectoral level. These indicators need to be supplemented with sector-specific information for a more complete understanding of future energy use and greenhouse gas emissions.

  13. Reliable Muddle: Transportation Scenarios for the 80% Greenhouse Gas Reduction Goal for 2050 (Presentation)

    SciTech Connect (OSTI)

    Melaina, M.; Webster, K.

    2009-10-28T23:59:59.000Z

    Presentation describing transportation scenarios for meeting the 2050 DOE goal of reducing greenhouse gases by 80%.

  14. Communication to the 10th International Conference on Greenhouse Gas Control Technologies (GHGT 10), Amsterdam, September 19-23, 2010.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    inaugurated in 2010. Apart from enhanced oil recovery projects or projects where the captured CO2 is a fatal is then injected through a reworked existing well into the depleted natural gas field of Rousse 1 rock formation 4: The reservoir pressure, currently 30 bars, should be increased to 70 bars post injection, which remains well

  15. The Impacts of Alternative Patterns of Urbanization on Greenhouse Gas Emissions in an Agricultural County

    E-Print Network [OSTI]

    Wheeler, Stephen

    2013-01-01T23:59:59.000Z

    building emissions somewhat lower, and single- family detached homes producing 33% more GHG (as CO 2 equivalent) from energy

  16. The effects of gas-fluid-rock interactions on CO2 injection and storage: Insights from reactive transport modeling

    SciTech Connect (OSTI)

    Xiao, Y.; Xu, T.; Pruess, K.

    2008-10-15T23:59:59.000Z

    Possible means of reducing atmospheric CO{sub 2} emissions include injecting CO{sub 2} in petroleum reservoirs for Enhanced Oil Recovery or storing CO{sub 2} in deep saline aquifers. Large-scale injection of CO{sub 2} into subsurface reservoirs would induce a complex interplay of multiphase flow, capillary trapping, dissolution, diffusion, convection, and chemical reactions that may have significant impacts on both short-term injection performance and long-term fate of CO{sub 2} storage. Reactive Transport Modeling is a promising approach that can be used to predict the spatial and temporal evolution of injected CO{sub 2} and associated gas-fluid-rock interactions. This presentation will summarize recent advances in reactive transport modeling of CO{sub 2} storage and review key technical issues on (1) the short- and long-term behavior of injected CO{sub 2} in geological formations; (2) the role of reservoir mineral heterogeneity on injection performance and storage security; (3) the effect of gas mixtures (e.g., H{sub 2}S and SO{sub 2}) on CO{sub 2} storage; and (4) the physical and chemical processes during potential leakage of CO{sub 2} from the primary storage reservoir. Simulation results suggest that CO{sub 2} trapping capacity, rate, and impact on reservoir rocks depend on primary mineral composition and injecting gas mixtures. For example, models predict that the injection of CO{sub 2} alone or co-injection with H{sub 2}S in both sandstone and carbonate reservoirs lead to acidified zones and mineral dissolution adjacent to the injection well, and carbonate precipitation and mineral trapping away from the well. Co-injection of CO{sub 2} with H{sub 2}S and in particular with SO{sub 2} causes greater formation alteration and complex sulfur mineral (alunite, anhydrite, and pyrite) trapping, sometimes at a much faster rate than previously thought. The results from Reactive Transport Modeling provide valuable insights for analyzing and assessing the dynamic behaviors of injected CO{sub 2}, identifying and characterizing potential storage sites, and managing injection performance and reducing costs.

  17. Estakhri and Saylak 1 Potential for Reduced Greenhouse Gas Emissions in Texas Through the Use of

    E-Print Network [OSTI]

    per cent of CO2 emissions come from the combustion of fossil fuels, and approximately 30% of those emissions are from the transportation sector. The next largest source of CO2 emissions is from the manufacture of cement and account for approximately 10% of all CO2 emissions (1). When faced

  18. DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2005-01-30T23:59:59.000Z

    For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

  19. Opportunities to change development pathways toward lower greenhouse gas emissions through energy efficiency

    SciTech Connect (OSTI)

    Alterra, Swart; Masanet, Eric; Lecocq, Franck; Najam, Adil; Schaeffer, Robert; Winkler, Harald; Sathaye, Jayant

    2008-07-04T23:59:59.000Z

    There is a multiplicity of development pathways in which low energy sector emissions are not necessarily associated with low economic growth. However, changes in development pathways can rarely be imposed from the top. On this basis, examples of energy efficiency opportunities to change development pathways toward lower emissions are presented in this paper. We review opportunities at the sectoral and macro level. The potential for action on nonclimate policies that influence energy use and emissions are presented. Examples are drawn from policies already adopted and implemented in the energy sector. The paper discusses relationships between energy efficiency policies and their synergies and tradeoffs with sustainable development and greenhouse gas emissions. It points to ways that energy efficiency could be mainstreamed into devel?opment choices.

  20. Idaho National Laboratory (INL) Site Greenhouse Gas (GHG) Monitoring Plan - 40 CFR 98

    SciTech Connect (OSTI)

    Deborah L. Layton; Kimberly Frerichs

    2011-12-01T23:59:59.000Z

    The purpose of this Greenhouse Gas (GHG) Monitoring Plan is to meet the monitoring plan requirements of Title 40 of the Code of Federal Regulations Part 98.3(g)(5). This GHG Monitoring Plan identifies procedures and methodologies used at the Idaho National Laboratory Site (INL Site) to collect data used for GHG emissions calculations and reporting requirements from stationary combustion and other regulated sources in accordance with 40 CFR 98, Subparts A and other applicable subparts. INL Site Contractors determined subpart applicability through the use of a checklist (Appendix A). Each facility/contractor reviews operations to determine which subparts are applicable and the results are compiled to determine which subparts are applicable to the INL Site. This plan is applicable to the 40 CFR 98-regulated activities managed by the INL Site contractors: Idaho National Laboratory (INL), Idaho Cleanup Project (ICP), Advanced Mixed Waste Treatment Project (AMWTP), and Naval Reactors Facilities (NRF).

  1. Idaho National Laboratory (INL) Site Greenhouse Gas (GHG) Monitoring Plan - 40 CFR 98

    SciTech Connect (OSTI)

    Deborah L. Layton; Kimberly Frerichs

    2010-07-01T23:59:59.000Z

    The purpose of this Greenhouse Gas (GHG) Monitoring Plan is to meet the monitoring plan requirements of Title 40 of the Code of Federal Regulations Part 98.3(g)(5). This GHG Monitoring Plan identifies procedures and methodologies used at the Idaho National Laboratory Site (INL Site) to collect data used for GHG emissions calculations and reporting requirements from stationary combustion and other regulated sources in accordance with 40 CFR 98, Subparts A and other applicable subparts. INL Site Contractors determined subpart applicability through the use of a checklist (Appendix A). Each facility/contractor reviews operations to determine which subparts are applicable and the results are compiled to determine which subparts are applicable to the INL Site. This plan is applicable to the 40 CFR 98-regulated activities managed by the INL Site contractors: Idaho National Laboratory (INL), Idaho Cleanup Project (ICP), Advanced Mixed Waste Treatment Project (AMWTP), and Naval Reactors Facilities (NRF).

  2. Novel Processes for Power Plant with CO2 Capture.

    E-Print Network [OSTI]

    Ekre, Kjetil Vinjerui

    2012-01-01T23:59:59.000Z

    ?? The purpose of this thesis was to examine different technologies, which enhances the CO2 partial pressure in the flue gas from the natural gas (more)

  3. Study of CO2 Mobility Control Using Cross-linked Gel Conformance Control and CO2 Viscosifiers in Heterogeneous Media

    E-Print Network [OSTI]

    Cai, Shuzong

    2011-10-21T23:59:59.000Z

    result, early gas breakthrough has been a very common problem in CO2-related projects, reducing the overall sweep efficiency of CO2 flooding. This research aims at improving the CO2 flood efficiency using cross-linked gel conformance control and CO2...

  4. Measuring Abatement Potentials When Multiple Change is Present: The Case of Greenhouse Gas Mitigation in U.S. Agriculture and Forestry

    E-Print Network [OSTI]

    McCarl, Bruce A.

    Measuring Abatement Potentials When Multiple Change is Present: The Case of Greenhouse Gas;Measuring Abatement Potentials When Multiple Change is Present: The Case of Greenhouse Gas Mitigation in U.S. Agriculture and Forestry Uwe A. Schneider and Bruce A. McCarl Keywords Abatement Function, Agricultural Sector

  5. Water Quality Co-effects of Greenhouse Gas Mitigation in US Agriculture Subhrendu K. Pattanayak, Bruce A. McCarl, Allan J. Sommer, Brian C. Murray, Timothy

    E-Print Network [OSTI]

    McCarl, Bruce A.

    greenhouse gas (GHG) emission offset strategies in U.S. agriculture by linking a national level agriculturalWater Quality Co-effects of Greenhouse Gas Mitigation in US Agriculture Subhrendu K. Pattanayak sector model (ASMGHG) to a national level water quality model (NWPCAM). The simulated policy scenario

  6. Molasses for ethanol: the economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis of sugarcane ethanol

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Molasses for ethanol: the economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis of sugarcane ethanol This article has been downloaded from IOPscience. Please scroll for ethanol: the economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis

  7. Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions

    SciTech Connect (OSTI)

    Malhotra, Vivak

    2014-06-30T23:59:59.000Z

    The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ? T ? 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (? 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale cores, which were pressurized with high pressure CO2, determine the fate of sequestered CO2 in these cores. Our results suggested that Illinois bituminous coal in its unperturbed state, i.e., when not pressurized with CO2, showed large variations in the mechanical properties. Modulus varied from 0.7 GPa to 3.4 GPa even though samples were extracted from a single large chunk of coal. We did not observe any glass transition for Illinois bituminous coal at - 100oC ? T ? 300oC, however, when the coal was pressurized with CO2 at ambient ? P ? 20.7 MPa, the viscosity of the coal decreased and inversely scaled with the CO2 pressure. The decrease in viscosity as a function of pressure could pose CO2 injection problems for coal as lower viscosity would allow the solid coal to flow to plug the fractures, fissures, and cleats. Our experiments also showed a very small fraction of CO2 was absorbed in coal; and when CO2 pressurized coals were exposed to atmospheric conditions, the loss of CO2 from coals was massive. Half of the sequestered gas from the coal cores was lost in less than 20 minutes. Our shockwave experiments on Illinois bituminous coal, New Albany shale (Illinois), Devonian shale (Ohio), and Utica shale (Ohio) presented clear evidence that the significant emission of the sequestered CO2 from these formations cannot be discounted during seismic activity, especially if caprock is compromised. It is argued that additional shockwave studies, both compressive and transverse, would be required for successfully mapping the risks associated with sequestering high pressure CO2 in coal and shale formations.

  8. Comparing the greenhouse gas emissions from three alternative waste combustion concepts

    SciTech Connect (OSTI)

    Vainikka, Pasi, E-mail: pasi.vainikka@vtt.fi [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Tsupari, Eemeli; Sipilae, Kai [VTT, Koivurannantie 1, FIN 40101 Jyvaeskylae (Finland); Hupa, Mikko [Aabo Akademi Process Chemistry Centre, Piispankatu 8, FIN 20500 Turku (Finland)

    2012-03-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

  9. Optimal control system design of an acid gas removal unit for an IGCC power plants with CO2 capture

    SciTech Connect (OSTI)

    Jones, D.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Future IGCC plants with CO{sub 2} capture should be operated optimally in the face of disturbances without violating operational and environmental constraints. To achieve this goal, a systematic approach is taken in this work to design the control system of a selective, dual-stage Selexol-based acid gas removal (AGR) unit for a commercial-scale integrated gasification combined cycle (IGCC) power plant with pre-combustion CO{sub 2} capture. The control system design is performed in two stages with the objective of minimizing the auxiliary power while satisfying operational and environmental constraints in the presence of measured and unmeasured disturbances. In the first stage of the control system design, a top-down analysis is used to analyze degrees of freedom, define an operational objective, identify important disturbances and operational/environmental constraints, and select the control variables. With the degrees of freedom, the process is optimized with relation to the operational objective at nominal operation as well as under the disturbances identified. Operational and environmental constraints active at all operations are chosen as control variables. From the results of the optimization studies, self-optimizing control variables are identified for further examination. Several methods are explored in this work for the selection of these self-optimizing control variables. Modifications made to the existing methods will be discussed in this presentation. Due to the very large number of candidate sets available for control variables and due to the complexity of the underlying optimization problem, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS) and the Parallel Computing toolbox from Mathworks. The second stage is a bottom-up design of the control layers used for the operation of the process. First, the regulatory control layer is designed followed by the supervisory control layer. Finally, an optimization layer is designed. In this paper, the proposed two-stage control system design approach is applied to the AGR unit for an IGCC power plant with CO{sub 2} capture. Aspen Plus Dynamics is used to develop the dynamic AGR process model while MATLAB is used to perform the control system design and for implementation of model predictive control (MPC).

  10. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2007-06-30T23:59:59.000Z

    In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

  11. The effects of potential changes in United States beef production on global grazing systems and greenhouse gas emissions

    E-Print Network [OSTI]

    Zhou, Yaoqi

    and greenhouse gas emissions Jerome Dumortier1 , Dermot J Hayes2 , Miguel Carriquiry2 , Fengxia Dong3 , Xiaodong in the U.S. causes a net increase in GHG emissions on a global scale. We couple a global agricultural production in the United States. The effects on emissions from agricultural production (i.e., methane

  12. State and Regional Comprehensive Carbon Pricing and Greenhouse Gas Regulation in the Power Sector under the EPA's Clean Power Plan

    E-Print Network [OSTI]

    California at Davis, University of

    1 State and Regional Comprehensive Carbon Pricing and Greenhouse Gas Regulation in the Power Sector goal of comprehensive carbon pricing along with various other policies (LCFS) · Into this setting drops rate" and the role of renewable energy and energy efficiency in the rate targets and in compliance

  13. Greenhouse Gas Mitigation Through Energy Crops in the U.S. With Implications for Asian-Pacific Countries

    E-Print Network [OSTI]

    McCarl, Bruce A.

    into energy crop production will most likely carry this price through increased purchasing cost and all energy the production of energy crops and other agricultural mitigation strategies. This analysis estimates the economicGreenhouse Gas Mitigation Through Energy Crops in the U.S. With Implications for Asian

  14. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles

    E-Print Network [OSTI]

    ) Note: PSAT included after-treatment thermal efficiency penalty to the diesel fuel economy · CD ElectricWell-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Amgad engine vehicles (ICEVs) Regular hybrid electric vehicles (HEVs) Plug-in hybrid electric vehicles (PHEVs

  15. Emissions trading to reduce greenhouse gas emissions in the United States : the McCain-Lieberman Proposal

    E-Print Network [OSTI]

    Paltsev, Sergey.

    The Climate Stewardship Act of 2003 (S. 139) is the most detailed effort to date to design an economy-wide cap-and-trade system for US greenhouse gas emissions reductions. The Act caps sectors at their 2000 emissions in ...

  16. Molasses for ethanol: The economic and environmental impacts of a new pathway for the lifecycle greenhouse gas

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Molasses for ethanol: The economic and environmental impacts of a new pathway for the lifecycle greenhouse gas analysis of sugarcane ethanol Anand R Gopal1,4,6 and Daniel M Kammen1,2,3,5 1 Energy supplying country for the production of sugarcane ethanol; fresh mill-pressed cane juice from a Brazilian

  17. Fuel-Cycle Fossil Energy Use and Greenhouse Gas Emissions of Fuel Ethanol Produced from U.S. Midwest Corn

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    #12;Fuel-Cycle Fossil Energy Use and Greenhouse Gas Emissions of Fuel Ethanol Produced from U essential to an informed choice about the corn-to-ethanol cycle are in need of updating, thanks to scientific and technological advances in both corn farming and ethanol production; and (2) generalized

  18. Optimal design and allocation of electrified vehicles and dedicated charging infrastructure for minimum life cycle greenhouse gas emissions and cost

    E-Print Network [OSTI]

    Michalek, Jeremy J.

    for minimum life cycle greenhouse gas emissions and cost Elizabeth Traut a,n , Chris Hendrickson b,1 , Erica and dedicated workplace charging infrastructure in the fleet for minimum life cycle cost or GHG emissions over vehicle and battery costs are the major drivers for PHEVs and BEVs to enter and dominate the cost

  19. CO2 Capture with Enzyme Synthetic Analogue

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-03-01T23:59:59.000Z

    Project overview provides background on carbonic anhydrase transport mechanism for CO2 in the human body and proposed approach for ARPA-E project to create a synthetic enzyme analogue and utilize it in a membrane for CO2 capture from flue gas.

  20. Life Cycle Greenhouse Gas Analysis of Natural Gas Extraction & Delivery in the United Statesy

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    ? 7 #12;Domestic Natural Gas Consumption Sectoral Trends and Projections: 2010 Total Consumption = 23 Timothy J. Skone, P.E. Office of Strategic Energy Analysis and Planning May 12 2011May 12, 2011 Presented for reducing 2 GHG emissions? #12;Question #1: Who is NETL? 3 #12;National Energy Technology Laboratory MISSION

  1. Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change. Learn about: Basics: Read an overview of greenhouse gases Federal...

  2. EMSL - CO2 sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    co2-sequestration en Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on Alumina. http:www.emsl.pnl.govemslwebpublications...

  3. Exploring the effects of data quality, data worth, and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST Inversion

    SciTech Connect (OSTI)

    Fang, Zhufeng; Hou, Zhangshuan; Lin, Guang; Engel, David W.; Fang, Yilin; Eslinger, Paul W.

    2014-04-01T23:59:59.000Z

    This study examined the impacts of reservoir properties on CO2 migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO2 monitoring data such as saturation distribution. The injection reservoir was assumed to be located 1400-1500 m below the ground surface such that CO2 remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO2 injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended up to 8000 m from the injection well. The CO2 migration was simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). We adopted a nonlinear parameter estimation and optimization modeling software package, PEST, for automated reservoir parameter estimation. We explored the effects of data quality, data worth, and data redundancy on the detectability of reservoir parameters using CO2 saturation monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO2 saturation monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy.

  4. Large releases from CO2 storage reservoirs: analogs, scenarios,and modeling needs

    SciTech Connect (OSTI)

    Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist,Jonny; Tsang, Chin-Fu; Karimjee, Anhar

    2005-09-01T23:59:59.000Z

    While the purpose of geologic storage in deep salineformations is to trap greenhouse gases underground, the potential existsfor CO2 to escape from the target reservoir, migrate upward alongpermeable pathways, and discharge at the land surface. In this paper, weevaluate the potential for such CO2 discharges based on the analysis ofnatural analogs, where large releases of gas have been observed. We areparticularly interested in circumstances that could generate sudden,possibly self-enhancing release events. The probability for such eventsmay be low, but the circumstances under which they occur and thepotential consequences need to be evaluated in order to designappropriate site-selection and risk-management strategies. Numericalmodeling of hypothetical test cases is suggested to determine criticalconditions for large CO2 releases, to evaluate whether such conditionsmaybe possible at designated storage sites, and, if applicable, toevaluate the potential impacts of such events as well as designappropriate mitigation strategies.

  5. E-Print Network 3.0 - atmospheric co2 emissions Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University Collection: Environmental Sciences and Ecology 16 EARTH'S CLIMATE, THE GREENHOUSE EFFECT, AND ENERGY Summary: al. Mauna Loa - Keeling 12;ATMOSPHERIC CO2 EMISSIONS Time...

  6. A Comparative Evaluation of Greenhouse Gas Emission Reduction Strategies for the Maritime Shipping and Aviation Sectors

    E-Print Network [OSTI]

    Hansen, Mark; Smirti, Megan; Zou, Bo

    2008-01-01T23:59:59.000Z

    General Ship Res Inst (US),Tokyo Shibaura Electric CO (US),America, General Electric Little change in Lower energy CO 2

  7. A Comparative Evaluation of Greenhouse Gas Emission Reduction Strategies for the Maritime Shipping and Aviation Sectors

    E-Print Network [OSTI]

    Hansen, Mark; Smirti, Megan; Zou, Bo

    2008-01-01T23:59:59.000Z

    2001) The impact of CO 2 emissions trading on the EuropeanJ. D. et al. (2007) Emissions Trading for internationalinvestigating an open emission trading system for aviation

  8. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01T23:59:59.000Z

    2 exposure in both CO 2 -EOR and natural CO 2 reservoirs (as enhanced oil recovery (EOR) and enhanced gas recovery (2 field injections for CCS-EOR, where the water quality of

  9. Formation Damage due to CO2 Sequestration in Saline Aquifers

    E-Print Network [OSTI]

    Mohamed, Ibrahim Mohamed 1984-

    2012-10-25T23:59:59.000Z

    Carbon dioxide (CO2) sequestration is defined as the removal of gas that would be emitted into the atmosphere and its subsequent storage in a safe, sound place. CO2 sequestration in underground formations is currently being considered to reduce...

  10. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-12-16T23:59:59.000Z

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

  11. Julian Cleary, Nigel T. Roulet and Tim R. Moore Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Roulet, Nigel T.

    ) emissions from land use, fossil fuel combustion, and peat decomposition, contributes to Canada's net the rate of in situ decomposition through greater diffusion of oxygen, increasing CO2 emissions, manufacturing, use, and disposition (12, 13). GHG emissions, comprising carbon dioxide (CO2), methane (CH4

  12. Plant-wide dynamic simulation of an IGCC plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2009-01-01T23:59:59.000Z

    To eliminate the harmful effects of greenhouse gases, especially that of CO2, future coalfired power plants need to consider the option for CO2 capture. The loss in efficiency for CO2 capture is less in an Integrated Gasification Combined Cycle (IGCC) plant compared to other conventional coal combustion processes. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. With this objective in mind, a detailed plant-wide dynamic simulation of an IGCC plant with CO2 capture has been developed. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of about 96 mol% of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. The clean syngas is sent to a gas turbine (GT) followed by a heat recovery steam generator (HRSG). The steady state results are validated with data from a commercial gasifier. A 5 % ramp increase in the flowrate of coal is introduced to study the system dynamics. To control the conversion of CO at a desired level in the WGS reactors, the steam/CO ratio is manipulated. This strategy is found to be efficient for this operating condition. In the absence of an efficient control strategy in the AGR process, the environmental emissions exceeded the limits by a great extent.

  13. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15T23:59:59.000Z

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  14. Estimating the supply and demand for deep geologic CO2 storage capacity over the course of the 21st Century: A meta-analysis of the literature

    SciTech Connect (OSTI)

    Dooley, James J.

    2013-08-05T23:59:59.000Z

    Whether there is sufficient geologic CO2 storage capacity to allow CCS to play a significant role in mitigating climate change has been the subject of debate since the 1990s. This paper presents a meta- analysis of a large body of recently published literature to derive updated estimates of the global deep geologic storage resource as well as the potential demand for this geologic CO2 storage resource over the course of this century. This analysis reveals that, for greenhouse gas emissions mitigation scenarios that have end-of-century atmospheric CO2 concentrations of between 350 ppmv and 725 ppmv, the average demand for deep geologic CO2 storage over the course of this century is between 410 GtCO2 and 1,670 GtCO2. The literature summarized here suggests that -- depending on the stringency of criteria applied to calculate storage capacity global geologic CO2 storage capacity could be: 35,300 GtCO2 of theoretical capacity; 13,500 GtCO2 of effective capacity; 3,900 GtCO2, of practical capacity; and 290 GtCO2 of matched capacity for the few regions where this narrow definition of capacity has been calculated. The cumulative demand for geologic CO2 storage is likely quite small compared to global estimates of the deep geologic CO2 storage capacity, and therefore, a lack of deep geologic CO2 storage capacity is unlikely to be an impediment for the commercial adoption of CCS technologies in this century.

  15. 23 23.2 23.4 23.6 23.8 24 24.2 (24) (3-minute) reference gas intervals: 450 ppm co2, sf=10 Hz

    E-Print Network [OSTI]

    Saltzman, Eric

    23 23.2 23.4 23.6 23.8 24 24.2 446 447 448 449 450 451 452 453 454 455 456 (24) (3-minute) reference gas intervals: 450 ppm co2, sf=10 Hz co2 day of year 2006 licormotionmodel.m, licormotionmodel.pdf, 15-Jun-2006, 14:16:6 #12;0.5 1 1.5 2 2.5 3 3.5 4 x 10 4 440 450 460 (24) concatenated (3-minute

  16. E-Print Network 3.0 - aggressive city greenhouse-gas Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    noted earlier, the majority of aviation emissions... a significant impact on the greenhouse effect.29 Concern regarding ... Source: George Mason University, Center for Air...

  17. E-Print Network 3.0 - annual greenhouse gas Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory, bo Akademi University, Collection: Fossil Fuels ; Physics 49 THE GREENHOUSE EFFECT Stephen E. Schwartz Summary: . D. Keeling ICE CORES SIPLE STATION ANTARCTICA...

  18. Transitional strategies for the reduction of "greenhouse gas" emission in the United States electric power sector

    E-Print Network [OSTI]

    Monroe, Burt L.

    1990-01-01T23:59:59.000Z

    Environmental issues have become increasingly important in the political arena, particularly with growing concern over the "greenhouse effect," a potential global climatic warming caused by increases in anthropogenic ...

  19. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z [University of Cincinnati; Dong, J. H. [University of Cincinnati

    2008-10-01T23:59:59.000Z

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  20. A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K. [Los Alamos National Laboratory; Dimotakis, Paul E. [JPL/CAL Tech; Rotman, Douglas A. [Lawrence Livermore National Laboratory; Walker, Bruce C. [Sandia National Laboratory

    2011-09-26T23:59:59.000Z

    This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS.

  1. Non-Kyoto Radiative Forcing in Long-Run Greenhouse Gas Emissions and Climate Change Scenarios

    SciTech Connect (OSTI)

    Rose, Steven K.; Richels, Richard G.; Smith, Steven J.; Riahi, Keywan; Stefler, Jessica; Van Vuuren, Detlef

    2014-04-27T23:59:59.000Z

    Climate policies designed to achieve climate change objectives must consider radiative forcing from the Kyoto greenhouse gas, as well as other forcing constituents, such as aerosols and tropospheric ozone. Net positive forcing leads to global average temperature increases. Modeling of non-Kyoto forcing is a relatively new component of climate management scenarios. Five of the nineteen models in the EMF-27 Study model both Kyoto and non-Kyoto forcing. This paper describes and assesses current non-Kyoto radiative forcing modeling within these integrated assessment models. The study finds negative forcing from aerosols masking significant positive forcing in reference non-climate policy projections. There are however large differences across models in projected non-Kyoto emissions and forcing, with differences stemming from differences in relationships between Kyoto and non-Kyoto emissions and fundamental differences in modeling structure and assumptions. Air pollution and non-Kyoto forcing decline in the climate policy scenarios. However, non-Kyoto forcing appears to be influencing mitigation results, including allowable carbon dioxide emissions, and further evaluation is merited. Overall, there is substantial uncertainty related to non-Kyoto forcing that must be considered.

  2. Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils

    SciTech Connect (OSTI)

    Jeremy Semrau; Sung-Woo Lee; Jeongdae Im; Sukhwan Yoon; Michael Barcelona

    2010-09-30T23:59:59.000Z

    The overall objective of this project, 'Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils' was to develop effective, efficient, and economic methodologies by which microbial production of nitrous oxide can be minimized while also maximizing microbial consumption of methane in landfill cover soils. A combination of laboratory and field site experiments found that the addition of nitrogen and phenylacetylene stimulated in situ methane oxidation while minimizing nitrous oxide production. Molecular analyses also indicated that methane-oxidizing bacteria may play a significant role in not only removing methane, but in nitrous oxide production as well, although the contribution of ammonia-oxidizing archaea to nitrous oxide production can not be excluded at this time. Future efforts to control both methane and nitrous oxide emissions from landfills as well as from other environments (e.g., agricultural soils) should consider these issues. Finally, a methanotrophic biofiltration system was designed and modeled for the promotion of methanotrophic activity in local methane 'hotspots' such as landfills. Model results as well as economic analyses of these biofilters indicate that the use of methanotrophic biofilters for controlling methane emissions is technically feasible, and provided either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive.

  3. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    MW Reciprocating Engine 3 MW Gas Turbine 1 MW ReciprocatingEngine 5 MW Gas Turbine 3MW Gas Turbine 40 MW Gas Turbine 1 MW Reciprocating Engine

  4. CO{sub 2} Allowance Allocation in the Regional Greenhouse Gas Initiative and the Effect on Electricity Investors

    SciTech Connect (OSTI)

    Burtraw, Dallas; Kahn, Danny; Palmer, Karen

    2006-03-01T23:59:59.000Z

    The Regional Greenhouse Gas Initiative among Northeastern states is expected to lead to an increase in the price of electricity in the region and beyond. In the RGGI region, changes in the value of electricity-generating assets may be positive or negative, while changes outside the Northeast are virtually always positive. For stakeholders in the industry, the change depends on the portfolio of assets held by affected firms. (author)

  5. Using Cool Roofs to Reduce Energy Use, Greenhouse Gas Emissions, and Urban Heat-island Effects: Findings from an India Experiment

    SciTech Connect (OSTI)

    Akbari, Hashem; Xu, Tengfang; Taha, Haider; Wray, Craig; Sathaye, Jayant; Garg, Vishal; Tetali, Surekha; Babu, M. Hari; Reddy, K. Niranjan

    2011-05-25T23:59:59.000Z

    Cool roofs, cool pavements, and urban vegetation reduce energy use in buildings, lower local air pollutant concentrations, and decrease greenhouse gas emissions from urban areas. This report summarizes the results of a detailed monitoring project in India and related simulations of meteorology and air quality in three developing countries. The field results quantified direct energy savings from installation of cool roofs on individual commercial buildings. The measured annual energy savings potential from roof-whitening of previously black roofs ranged from 20-22 kWh/m2 of roof area, corresponding to an air-conditioning energy use reduction of 14-26% in commercial buildings. The study estimated that typical annual savings of 13-14 kWh/m2 of roof area could be achieved by applying white coating to uncoated concrete roofs on commercial buildings in the Metropolitan Hyderabad region, corresponding to cooling energy savings of 10-19%. With the assumption of an annual increase of 100,000 square meters of new roof construction for the next 10 years in the Metropolitan Hyderabad region, the annual cooling energy savings due to whitening concrete roof would be 13-14 GWh of electricity in year ten alone, with cumulative 10-year cooling energy savings of 73-79 GWh for the region. The estimated savings for the entire country would be at least 10 times the savings in Hyderabad, i.e., more than 730-790 GWh. We estimated that annual direct CO2 reduction associated with reduced energy use would be 11-12 kg CO2/m2 of flat concrete roof area whitened, and the cumulative 10-year CO2 reduction would be approximately 0.60-0.65 million tons in India. With the price of electricity estimated at seven Rupees per kWh, the annual electricity savings on air-conditioning would be approximately 93-101 Rupees per m2 of roof. This would translate into annual national savings of approximately one billion Rupees in year ten, and cumulative 10-year savings of over five billion Rupees for cooling energy in India. Meteorological simulations in this study indicated that a reduction of 2C in air temperature in the Hyderabad area would be likely if a combination of increased surface albedo and vegetative cover are used as urban heat-island control strategies. In addition, air-temperature reductions on the order of 2.5-3.5C could be achieved if moderate and aggressive heat-island mitigation measures are adopted, respectively. A large-scale deployment of mitigation measures can bring additional indirect benefit to the urban area. For example, cooling outside air can improve the efficiency of cooling systems, reduce smog and greenhouse gas (GHG) emissions, and indirectly reduce pollution from power plants - all improving environmental health quality. This study has demonstrated the effectiveness of cool-roof technology as one of the urban heat-island control strategies for the Indian industrial and scientific communities and has provided an estimate of the national energy savings potential of cool roofs in India. These outcomes can be used for developing cool-roof building standards and related policies in India. Additional field studies, built upon the successes and lessons learned from this project, may be helpful to further confirm the scale of potential energy savings from the application of cooler roofs in various regions of India. In the future, a more rigorous meteorological simulation using urbanized (meso-urban) meteorological models should be conducted, which may produce a more accurate estimate of the air-temperature reductions for the entire urban area.

  6. Rcupration assiste d'hydrocarbures, conventionnels ou non, par injection de CO2.

    E-Print Network [OSTI]

    Canet, Léonie

    · Récupération d' hydrocarbures conventionnels - CO2 ­ EOR enhanced oil recovery - CO2 ­ EGR enhanced gas-combustion (gas processing) 7 EOR 1986 Sleipner CO2 Injection Norway Pre-combustion (gas processing) 1 (+ 0 EOR 2000 Enid Fertilizer Plant United States Pre-combustion (fertiliser) 0.7 EOR 1982 In Salah CO2

  7. Opportunities to change development pathways toward lower greenhouse gas emissions through energy efficiency

    E-Print Network [OSTI]

    Sathaye, Jayant

    2010-01-01T23:59:59.000Z

    2 Primary energy supply per unit of GDP (excluding biomass;is defined as energy use per unit of GDP and is an aggregateenergy sector. Much of the variations of CO 2 emissions per unit of GDP

  8. Energy and greenhouse gas emission effects of corn and cellulosic ethanol with technology improvements and land use changes.

    SciTech Connect (OSTI)

    Wang, M.; Han, J.; Haq, Z; Tyner, .W.; Wu, M.; Elgowainy, A. (Energy Systems)

    2011-05-01T23:59:59.000Z

    Use of ethanol as a transportation fuel in the United States has grown from 76 dam{sup 3} in 1980 to over 40.1 hm{sup 3} in 2009 - and virtually all of it has been produced from corn. It has been debated whether using corn ethanol results in any energy and greenhouse gas benefits. This issue has been especially critical in the past several years, when indirect effects, such as indirect land use changes, associated with U.S. corn ethanol production are considered in evaluation. In the past three years, modeling of direct and indirect land use changes related to the production of corn ethanol has advanced significantly. Meanwhile, technology improvements in key stages of the ethanol life cycle (such as corn farming and ethanol production) have been made. With updated simulation results of direct and indirect land use changes and observed technology improvements in the past several years, we conducted a life-cycle analysis of ethanol and show that at present and in the near future, using corn ethanol reduces greenhouse gas emission by more than 20%, relative to those of petroleum gasoline. On the other hand, second-generation ethanol could achieve much higher reductions in greenhouse gas emissions. In a broader sense, sound evaluation of U.S. biofuel policies should account for both unanticipated consequences and technology potentials. We maintain that the usefulness of such evaluations is to provide insight into how to prevent unanticipated consequences and how to promote efficient technologies with policy intervention.

  9. Putting policy in drive : coordinating measures to reduce fuel use and greenhouse gas emissions from U.S. light-duty vehicles

    E-Print Network [OSTI]

    Evans, Christopher W. (Christopher William)

    2008-01-01T23:59:59.000Z

    The challenges of energy security and climate change have prompted efforts to reduce fuel use and greenhouse gas emissions in light-duty vehicles within the United States. Failures in the market for lower rates of fuel ...

  10. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01T23:59:59.000Z

    such as depleted oil and gas reservoirs, unminable coaltakes place in depleted oil or gas reservoirs (IAE, 2003).of CO 2 in depleted oil and gas reservoirs. J Can Pet

  11. Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

    E-Print Network [OSTI]

    electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gas two-thirds), CO2, water vapor, oxygen, and minor components such as carbon monoxide, nitrogen oxides

  12. Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery

    SciTech Connect (OSTI)

    Yang Na [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Zhang Hua, E-mail: zhanghua_tj@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); Chen Miao; Shao Liming [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China); He Pinjing, E-mail: xhpjk@tongji.edu.cn [State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, 1239 Siping Road, Shanghai 200092 (China)

    2012-12-15T23:59:59.000Z

    Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

  13. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Warner, E. S.; Heath, G. A.

    2012-04-01T23:59:59.000Z

    A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

  14. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01T23:59:59.000Z

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  15. Insights from EMF Associated Agricultural and Forestry Greenhouse Gas Mitigation Studies

    SciTech Connect (OSTI)

    McCarl, Bruce A.; Murray, Brian; Kim, Man-Keun; Lee, Heng-Chi; Sands, Ronald D.; Schneider, Uwe

    2007-11-19T23:59:59.000Z

    Integrated assessment modeling (IAM) as employed by the Energy Modeling Forum (EMF) generally involves a multi-sector appraisal of greenhouse gas emission (GHGE) mitigation alternatives and climate change effects typically at the global level. Such a multi-sector evaluation encompasses potential climate change effects and mitigative actions within the agricultural and forestry (AF) sectors. In comparison with many of the other sectors covered by IAM, the AF sectors may require somewhat different treatment due to their critical dependence upon spatially and temporally varying resource and climatic conditions. In particular, in large countries like the United States, forest production conditions vary dramatically across the landscape. For example, some areas in the southern US present conditions favorable to production of fast growing, heat tolerant pine species, while more northern regions often favor slower-growing hardwood and softwood species. Moreover, some lands are currently not suitable for forest production (e.g., the arid western plains). Similarly, in agriculture, the US has areas where citrus and cotton can be grown and other areas where barley and wheat are more suitable. This diversity across the landscape causes differential GHGE mitigation potential in the face of climatic changes and/or responses to policy or price incentives. It is difficult for a reasonably sized global IAM system to reflect the full range of sub-national geographic AF production possibilities alluded to above. AF response in the face of climate change altered temperature precipitation regimes or mitigation incentives will likely involve region-specific shifts in land use and agricultural/forest production. This chapter addresses AF sectoral responses in climate change mitigation analysis. Specifically, we draw upon US-based studies of AF GHGE mitigation possibilities that incorporate sub-national detail drawing largely on a body of studies done by the authors in association with EMF activities. We discuss characteristics of AF sectoral responses that could be incorporated in future IAM efforts in climate change policy.

  16. Life Cycle Greenhouse Gas Emissions of Utility-Scale Wind Power: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Dolan, S. L.; Heath, G. A.

    2012-04-01T23:59:59.000Z

    A systematic review and harmonization of life cycle assessment (LCA) literature of utility-scale wind power systems was performed to determine the causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions. Screening of approximately 240 LCAs of onshore and offshore systems yielded 72 references meeting minimum thresholds for quality, transparency, and relevance. Of those, 49 references provided 126 estimates of life cycle GHG emissions. Published estimates ranged from 1.7 to 81 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), with median and interquartile range (IQR) both at 12 g CO{sub 2}-eq/kWh. After adjusting the published estimates to use consistent gross system boundaries and values for several important system parameters, the total range was reduced by 47% to 3.0 to 45 g CO{sub 2}-eq/kWh and the IQR was reduced by 14% to 10 g CO{sub 2}-eq/kWh, while the median remained relatively constant (11 g CO{sub 2}-eq/kWh). Harmonization of capacity factor resulted in the largest reduction in variability in life cycle GHG emission estimates. This study concludes that the large number of previously published life cycle GHG emission estimates of wind power systems and their tight distribution suggest that new process-based LCAs of similar wind turbine technologies are unlikely to differ greatly. However, additional consequential LCAs would enhance the understanding of true life cycle GHG emissions of wind power (e.g., changes to other generators operations when wind electricity is added to the grid), although even those are unlikely to fundamentally change the comparison of wind to other electricity generation sources.

  17. & MetalOrganic Frameworks Enhancing CO2 Separation Ability of a MetalOrganic Framework

    E-Print Network [OSTI]

    Paik Suh, Myunghyun

    that it is a promising material for sequestering CO2 from landfill gas. Introduction Metal­organic frameworks have been considered as promising materials for separating CO2 from landfill gas and industrial flue gas due

  18. Modeling & learning from the design recommendations for California's Greenhouse Gas Cap-and-Trade System

    E-Print Network [OSTI]

    Fernandes, Chester, S.M. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    Climate Change has become a Major issue beginning with our generation. Governments the world over are now recognizing that industry cannot continue to pollute in a business-as-usual manner. Emitting Greenhouse gases has a ...

  19. Incentive-based approaches for mitigating greenhouse gas emissions : issues and prospects for India

    E-Print Network [OSTI]

    Gupta, Shreekant.

    As a consequence of the flexibility mechanisms incorporated in the Kyoto Protocol, incentive-based policies such as emissions trading and the clean development mechanism are being widely discussed in the context of greenhouse ...

  20. Detection of greenhouse-gas-induced climatic change. Progress report, 1 December 1991--30 June 1994

    SciTech Connect (OSTI)

    Wigley, T.M.L.; Jones, P.D.

    1994-07-01T23:59:59.000Z

    In addition to changes due to variations in greenhouse gas concentrations, the global climate system exhibits a high degree of internally-generated and externally-forced natural variability. To detect the enhanced greenhouse effect, its signal must be isolated from the ``noise`` of this natural climatic variability. A high quality, spatially extensive data base is required to define the noise and its spatial characteristics. To facilitate this, available land and marine data bases will be updated and expanded. The data will be analyzed to determine the potential effects on climate of greenhouse gas concentration changes and other factors. Analyses will be guided by a variety of models, from simple energy balance climate models to ocean General Circulation Models. Appendices A--G contain the following seven papers: (A) Recent global warmth moderated by the effects of the Mount Pinatubo eruption; (B) Recent warming in global temperature series; (C) Correlation methods in fingerprint detection studies; (D) Balancing the carbon budget. Implications for projections of future carbon dioxide concentration changes; (E) A simple model for estimating methane concentration and lifetime variations; (F) Implications for climate and sea level of revised IPCC emissions scenarios; and (G) Sulfate aerosol and climatic change.

  1. Synthesis, characterization and performance of single-component CO2-binding organic liquids (CO2BOL) for post combustion CO2 capture

    SciTech Connect (OSTI)

    Koech, Phillip K.; Heldebrant, David J.; Rainbolt, James E.; Zheng, Feng; Smurthwaite, Tricia D.

    2010-03-31T23:59:59.000Z

    Carbon dioxide (CO2) emission to the atmosphere will increase significantly with the shift to coal powered plants for energy generation. This increase in CO2 emission will contribute to climate change. There is need to capture and sequester large amounts of CO2 emitted from these coal power plants in order to mitigate the environmental effects. Here we report the synthesis, characterization and system performance of multiple third generation CO2 binding organic liquids (CO2BOLs) as a solvent system for post combustion gas capture. Alkanolguanidines and alkanolamidines are single component CO2BOLs that reversibly bind CO2 chemically as liquid zwitterionic amidinium / guanidinium alkylcarbonates. Three different alkanolguanidines and alkanolamidines were synthesized and studied for CO2 capacity and binding energetics. Solvent performance of these three CO2BOLs was evaluated by batch-wise CO2 uptake and release over multiple cycles. Synthesis of CO2BOLs, characterization, CO2 uptake, selectivity towards CO2 as well as solvent tolerance to water will be discussed.

  2. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01T23:59:59.000Z

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  3. Potential for CO2 Sequestration and Enhanced Coalbed Methane Production, Blue Creek Field, NW Black Warrior Basin, Alabama

    E-Print Network [OSTI]

    He, Ting

    2011-02-22T23:59:59.000Z

    Carbon dioxide (CO2) is a primary source of greenhouse gases. Injection of CO2 from power plants near coalbed reservoirs is a win-win method to reducing emissions of CO2 to the atmosphere. Limited studies have investigated CO2 sequestration...

  4. Implementing greenhouse gas emissions caps: A case study of the Los Angeles Department of Water and Power

    SciTech Connect (OSTI)

    Carlson, A.E. [University of California Los Angeles, Los Angeles, CA (United States). School for Law

    2008-08-15T23:59:59.000Z

    Our almost forty-year experience with landmark federal environmental statutes, demonstrates unequivocally that implementing grand and noble environmental goals is an arduous and difficult experience. California is now embarking on a similar project: implementing the country's most ambitious greenhouse gas emissions limitations, including rolling back the state's emissions to 1990 levels by 2020. The state's leadership on climate change legislation deserves significant praise. But the hard work in actually achieving emissions limits is just beginning. In this Essay, Professor Ann Carlson provides a case study of the country's largest municipally owned utility - the Los Angeles Department of Water and Power (DWP) - and the challenges it will face in holding its emissions to 1990 levels by 2020. The case study is particularly useful to anticipate challenges utilities across the country will face if the federal government also mandates greenhouse gas emissions reductions. The DWP's energy mix, with its heavy reliance on coal, looks quite similar to the energy mix of the country as a whole (and quite different from the rest of California's electricity market). The challenges are daunting. They include shifting rapidly to renewable energy sources in the face of labor pressures to have DWP own its own sources; building miles of transmission lines to bring the renewable energy to DWP's customer base; repowering natural gas facilities while attempting to comply with stringent Clean Water Act requirements; and eliminating the utility's reliance on coal over the next two decades. These efforts will raise complex environmental and other value clashes, pitting those concerned about jobs, water pollution, species protection, and aesthetic harms against a utility admirably committed to cutting its greenhouse gas emissions significantly. Whether and how we resolve these clashes remains an open and contested question.

  5. Spatial Disaggregation of CO2 Emissions for the State of California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; de la Rue du Can, Stephane; Wenzel, Tom; Fischer, Marc

    2008-06-11T23:59:59.000Z

    This report allocates California's 2004 statewide carbon dioxide (CO2) emissions from fuel combustion to the 58 counties in the state. The total emissions are allocated to counties using several different methods, based on the availability of data for each sector. Data on natural gas use in all sectors are available by county. Fuel consumption by power and combined heat and power generation plants is available for individual plants. Bottom-up models were used to distribute statewide fuel sales-based CO2 emissions by county for on-road vehicles, aircraft, and watercraft. All other sources of CO2 emissions were allocated to counties based on surrogates for activity. CO2 emissions by sector were estimated for each county, as well as for the South Coast Air Basin. It is important to note that emissions from some sources, notably electricity generation, were allocated to counties based on where the emissions were generated, rather than where the electricity was actually consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported from other states and international marine bunker fuels, were not included in the analysis. California Air Resource Board (CARB) does not include CO2 emissions from interstate and international air travel, in the official California greenhouse gas (GHG) inventory, so those emissions were allocated to counties for informational purposes only. Los Angeles County is responsible for by far the largest CO2 emissions from combustion in the state: 83 Million metric tonnes (Mt), or 24percent of total CO2 emissions in California, more than twice that of the next county (Kern, with 38 Mt, or 11percent of statewide emissions). The South Coast Air Basin accounts for 122 MtCO2, or 35percent of all emissions from fuel combustion in the state. The distribution of emissions by sector varies considerably by county, with on-road motor vehicles dominating most counties, but large stationary sources and rail travel dominating in other counties.The CO2 emissions data by county and source are available upon request.

  6. Achieving a ten percent greenhouse gas reduction by 2020 Response to

    E-Print Network [OSTI]

    Hughes, Larry

    gases with different global warming potentials, all equated to that of CO2. For example, methane has a GWP of 21, which means a tonne of methane has a global warming potential equivalent to 21 tonnes below the levels that were emitted in the year 1990 by the year 2020, as outlined in the New England

  7. Strategies for the Commercialization and Deployment of Greenhouse Gas Intensity-Reducing Technologies and Practices

    SciTech Connect (OSTI)

    Committee on Climate Change Science and Technology Integration (CCCSTI)

    2009-01-01T23:59:59.000Z

    New technologies will be a critical component--perhaps the critical component--of our efforts to tackle the related challenges of energy security, climate change, and air pollution, all the while maintaining a strong economy. But just developing new technologies is not enough. Our ability to accelerate the market penetration of clean energy, enabling, and other climate-related technologies will have a determining impact on our ability to slow, stop, and reverse the growth in greenhouse gas (GHG) emissions. Title XVI, Subtitle A, of the Energy Policy Act of 2005 (EPAct 2005) directs the Administration to report on its strategy to promote the commercialization and deployment (C&D) of GHG intensity-reducing technologies and practices. The Act also requests the Administration to prepare an inventory of climate-friendly technologies suitable for deployment and to identify the barriers and commercial risks facing advanced technologies. Because these issues are related, they are integrated here within a single report that we, representing the Committee on Climate Change Science and Technology Integration (CCCSTI), are pleased to provide the President, the Congress, and the public. Over the past eight years, the Administration of President George W. Bush has pursued a series of policies and measures aimed at encouraging the development and deployment of advanced technologies to reduce GHG emissions. This report highlights these policies and measures, discusses the barriers to each, and integrates them within a larger body of other extant policy. Taken together, more than 300 policies and measures described in this document may be viewed in conjunction with the U.S. Climate Change Technology Program's (CCTP's) Strategic Plan, published in September 2006, which focuses primarily on the role of advanced technology and associated research and development (R&D) for mitigating GHG emissions. The CCTP, a multi-agency technology planning and coordination program, initiated by President Bush, and subsequently authorized in EPAct2005, is responsible for preparing this report on behalf CCCSTI. This report systematically examines the market readiness of key technologies important to meeting climate change mitigation goals. It assesses the barriers and business risks impeding their progress and greater market application. Importantly, by documenting the hundreds of Federal policies, programs, regulations, incentives, and other activities that are in effect and operating today to address these barriers, it provides a broad context for evaluating the adequacy of current policy and the potential need, if any, for additional measures that might be undertaken by government or industry. Finally, it draws conclusions about the current situation, identifies gaps and opportunities, and suggests analytical principles that should be applied to assess and formulate policies and measures to accelerate the commercialization and deployment of these technologies.

  8. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01T23:59:59.000Z

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James OBrien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  9. Greenhouse Emission Reductions and Natural Gas Vehicles: A Resource Guide on Technology Options and Project Development

    SciTech Connect (OSTI)

    Orestes Anastasia; NAncy Checklick; Vivianne Couts; Julie Doherty; Jette Findsen; Laura Gehlin; Josh Radoff

    2002-09-01T23:59:59.000Z

    Accurate and verifiable emission reductions are a function of the degree of transparency and stringency of the protocols employed in documenting project- or program-associated emissions reductions. The purpose of this guide is to provide a background for law and policy makers, urban planners, and project developers working with the many Greenhouse Gas (GHG) emission reduction programs throughout the world to quantify and/or evaluate the GHG impacts of Natural Gas Vehicle (NGVs). In order to evaluate the GHG benefits and/or penalties of NGV projects, it is necessary to first gain a fundamental understanding of the technology employed and the operating characteristics of these vehicles, especially with regard to the manner in which they compare to similar conventional gasoline or diesel vehicles. Therefore, the first two sections of this paper explain the basic technology and functionality of NGVs, but focus on evaluating the models that are currently on the market with their similar conventional counterparts, including characteristics such as cost, performance, efficiency, environmental attributes, and range. Since the increased use of NGVs, along with Alternative Fuel Vehicle (AFVs) in general, represents a public good with many social benefits at the local, national, and global levels, NGVs often receive significant attention in the form of legislative and programmatic support. Some states mandate the use of NGVs, while others provide financial incentives to promote their procurement and use. Furthermore, Federal legislation in the form of tax incentives or procurement requirements can have a significant impact on the NGV market. In order to implement effective legislation or programs, it is vital to have an understanding of the different programs and activities that already exist so that a new project focusing on GHG emission reduction can successfully interact with and build on the experience and lessons learned of those that preceded it. Finally, most programs that deal with passenger vehicles--and with transportation in general--do not address the climate change component explicitly, and thus there are few GHG reduction goals that are included in these programs. Furthermore, there are relatively few protocols that exist for accounting for the GHG emissions reductions that arise from transportation and, specifically, passenger vehicle projects and programs. These accounting procedures and principles gain increased importance when a project developer wishes to document in a credible manner, the GHG reductions that are achieved by a given project or program. Section four of this paper outlined the GHG emissions associated with NGVs, both upstream and downstream, and section five illustrated the methodology, via hypothetical case studies, for measuring these reductions using different types of baselines. Unlike stationary energy combustion, GHG emissions from transportation activities, including NGV projects, come from dispersed sources creating a need for different methodologies for assessing GHG impacts. This resource guide has outlined the necessary context and background for those parties wishing to evaluate projects and develop programs, policies, projects, and legislation aimed at the promotion of NGVs for GHG emission reduction.

  10. Detection of greenhouse-gas-induced climatic change. Progress report, 1 December 1992--30 June 1993

    SciTech Connect (OSTI)

    Wigley, T.M.L.; Jones, P.D.

    1993-07-09T23:59:59.000Z

    The aims of the US Department of Energy`s Carbon Dioxide Research Program are to improve assessments of greenhouse-gas-induced climatic change and to define and reduce uncertainties through selected research. The main research areas covered by this proposal are (b), First Detection and (c) Supporting Data. The project will also include work under area (a), Modeling: specifically, analysis of climate forcing factors, the development and refinement of transient response climate models, and the use of instrumental data in validating General Circulating Models (GCMs).

  11. Project Information Form Project Title Working toward a policy framework for reducing greenhouse gas

    E-Print Network [OSTI]

    California at Davis, University of

    Provided (by each agency or organization) US DOT $37,874 Total Project Cost $37,874 Agency ID or ContractProject Information Form Project Title Working toward a policy framework for reducing greenhouse of Research Project This white paper is concerned with a preliminary investigation of the extent to which

  12. Integrated Chemical Complex and Cogeneration Analysis System: Energy Conservation and Greenhouse Gas Management Solutions

    E-Print Network [OSTI]

    Pike, Ralph W.

    19f Integrated Chemical Complex and Cogeneration Analysis System: Energy Conservation and Cogeneration Analysis System is an advanced technology for energy conservation and pollution prevention, Beaumont, TX 77710, hopperjr@hal.lamar.edu, yawscl@hal.lamar.edu Key words; Energy Conservation, Greenhouse

  13. Building Commissioning: A Golden Opportunity for Reducing Energy Costs and Greenhouse-gas Emissions

    SciTech Connect (OSTI)

    Mills, Evan

    2009-07-16T23:59:59.000Z

    The aim of commissioning new buildings is to ensure that they deliver, if not exceed, the performance and energy savings promised by their design. When applied to existing buildings, commissioning identifies the almost inevitable 'drift' from where things should be and puts the building back on course. In both contexts, commissioning is a systematic, forensic approach to quality assurance, rather than a technology per se. Although commissioning has earned increased recognition in recent years - even a toehold in Wikipedia - it remains an enigmatic practice whose visibility severely lags its potential. Over the past decade, Lawrence Berkeley National Laboratory has built the world's largest compilation and meta-analysis of commissioning experience in commercial buildings. Since our last report (Mills et al. 2004) the database has grown from 224 to 643 buildings (all located in the United States, and spanning 26 states), from 30 to 100 million square feet of floorspace, and from $17 million to $43 million in commissioning expenditures. The recorded cases of new-construction commissioning took place in buildings representing $2.2 billion in total construction costs (up from 1.5 billion). The work of many more commissioning providers (18 versus 37) is represented in this study, as is more evidence of energy and peak-power savings as well as cost-effectiveness. We now translate these impacts into avoided greenhouse gases and provide new indicators of cost-effectiveness. We also draw attention to the specific challenges and opportunities for high-tech facilities such as labs, cleanrooms, data centers, and healthcare facilities. The results are compelling. We developed an array of benchmarks for characterizing project performance and cost-effectiveness. The median normalized cost to deliver commissioning was $0.30/ft2 for existing buildings and $1.16/ft2 for new construction (or 0.4% of the overall construction cost). The commissioning projects for which data are available revealed over 10,000 energy-related problems, resulting in 16% median whole-building energy savings in existing buildings and 13% in new construction, with payback time of 1.1 years and 4.2 years, respectively. In terms of other cost-benefit indicators, median benefit-cost ratios of 4.5 and 1.1, and cash-on-cash returns of 91% and 23% were attained for existing and new buildings, respectively. High-tech buildings were particularly cost-effective, and saved higher amounts of energy due to their energy-intensiveness. Projects with a comprehensive approach to commissioning attained nearly twice the overall median level of savings and five-times the savings of the least-thorough projects. It is noteworthy that virtually all existing building projects were cost-effective by each metric (0.4 years for the upper quartile and 2.4 years for the lower quartile), as were the majority of new-construction projects (1.5 years and 10.8 years, respectively). We also found high cost-effectiveness for each specific measure for which we have data. Contrary to a common perception, cost-effectiveness is often achieved even in smaller buildings. Thanks to energy savings valued more than the cost of the commissioning process, associated reductions in greenhouse gas emissions come at 'negative' cost. In fact, the median cost of conserved carbon is negative - -$110 per tonne for existing buildings and -$25/tonne for new construction - as compared with market prices for carbon trading and offsets in the +$10 to +$30/tonne range. Further enhancing the value of commissioning, its non-energy benefits surpass those of most other energy-management practices. Significant first-cost savings (e.g., through right-sizing of heating and cooling equipment) routinely offset at least a portion of commissioning costs - fully in some cases. When accounting for these benefits, the net median commissioning project cost was reduced by 49% on average, while in many cases they exceeded the direct value of the energy savings. Commissioning also improves worker comfort, mitigates indoor air quality problems

  14. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    generation: 50% of electricity from central grid natural gas plantsgeneration: 100% of electricity from central grid natural gas plantselectricity comes from central station natural-gas- fired combined cycle generation, and the other half comes from natural-gas-fired single cycle plants.

  15. Uncertainty quantification for CO2 sequestration and enhanced oil recovery

    E-Print Network [OSTI]

    Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia, Wei; Lee, Si-Yong; McPherson, Brian; Ampomah, William; Grigg, Reid

    2014-01-01T23:59:59.000Z

    This study develops a statistical method to perform uncertainty quantification for understanding CO2 storage potential within an enhanced oil recovery (EOR) environment at the Farnsworth Unit of the Anadarko Basin in northern Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil-water flow and reactive transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major uncertainty metrics: net CO2 injection, cumulative oil production, cumulative gas (CH4) production, and net water injection. A global sensitivity and response surface analysis indicates that reservoir permeability, porosity, and thickness are the major intrinsic reservoir parameters that control net CO2 injection/storage and oil/gas recovery rates. The well spacing and the initial water saturation also have large impact on the oil/gas recovery rates. Further, this study has revealed key insights into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s...

  16. A greenhouse-gas information system monitoring and validating emissions reporting and mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K [Los Alamos National Laboratory; Dimotakis, Paul E [JPL/CAL TECH; Roman, Douglas A [LLNL; Walker, Bruce C [SNL

    2011-09-26T23:59:59.000Z

    Current GHG-mitigating regimes, whether internationally agreed or self-imposed, rely on the aggregation of self-reported data, with limited checks for consistency and accuracy, for monitoring. As nations commit to more stringent GHG emissions-mitigation actions and as economic rewards or penalties are attached to emission levels, self-reported data will require independent confirmation that they are accurate and reliable, if they are to provide the basis for critical choices and actions that may be required. Supporting emissions-mitigation efforts and agreements, as well as monitoring energy- and fossil-fuel intensive national and global activities would be best achieved by a process of: (1) monitoring of emissions and emission-mitigation actions, based, in part, on, (2) (self-) reporting of pertinent bottom-up inventory data, (3) verification that reported data derive from and are consistent with agreed-upon processes and procedures, and (4) validation that reported emissions and emissions-mitigation action data are correct, based on independent measurements (top-down) derived from a suite of sensors in space, air, land, and, possibly, sea, used to deduce and attribute anthropogenic emissions. These data would be assessed and used to deduce and attribute measured GHG concentrations to anthropogenic emissions, attributed geographically and, to the extent possible, by economic sector. The validation element is needed to provide independent assurance that emissions are in accord with reported values, and should be considered as an important addition to the accepted MRV process, leading to a MRV&V process. This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS. Present monitoring systems would be heavily relied on in any GHGIS implementation at the outset and would likely continue to provide valuable future contributions to GHGIS. However, present monitoring systems were developed to serve science/research purposes. This study concludes that no component or capability presently available is at the level of technological maturity and readiness required for implementation in an operational GHGIS today. However, purpose-designed and -built components could be developed and implemented in support of a future GHGIS. The study concludes that it is possible to develop and provide a capability-driven prototype GHGIS, as part of a Phase-1 effort, within three years from project-funding start, that would make use of and integrate existing sensing and system capabilities. As part of a Phase-2 effort, a requirem

  17. Development of methodologies for calculating greenhouse gas emissions from electricity generation for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Marnay, Chris; Sathaye, Jayant; Murtishaw, Scott; Fisher, Diane; Phadke, Amol; Franco, Guido

    2002-04-01T23:59:59.000Z

    The California Climate Action Registry, which will begin operation in Fall 2002, is a voluntary registry for California businesses and organizations to record annual greenhouse gas emissions. Reporting of emissions in the Registry by a participant involves documentation of both ''direct'' emissions from sources that are under the entity's control and ''indirect'' emissions controlled by others. Electricity generated by an off-site power source is considered to be an indirect emission and must be included in the entity's report. Published electricity emissions factors for the State of California vary considerably due to differences in whether utility-owned out-of-state generation, non-utility generation, and electricity imports from other states are included. This paper describes the development of three methods for estimating electricity emissions factors for calculating the combined net carbon dioxide emissions from all generating facilities that provide electricity to Californians. We fi nd that use of a statewide average electricity emissions factor could drastically under- or over-estimate an entity's emissions due to the differences in generating resources among the utility service areas and seasonal variations. In addition, differentiating between marginal and average emissions is essential to accurately estimate the carbon dioxide savings from reducing electricity use. Results of this work will be taken into consideration by the Registry when finalizing its guidance for use of electricity emissions factors in calculating an entity's greenhouse gas emissions.

  18. CO{sub 2} allowance allocation in the Regional Greenhouse Gas Initiative and the effect on electricity investors

    SciTech Connect (OSTI)

    Dallas Burtraw; Danny Kahn; Karen Palmerook

    2005-12-15T23:59:59.000Z

    The Regional Greenhouse Gas Initiative (RGGI) is an effort by nine Northeast and Mid-Atlantic states to develop a regional, mandatory, market-based cap-and-trade program to reduce greenhouse gas (GHG) emissions from the electricity sector. The initiative is expected to lead to an increase in the price of electricity in the RGGI region and beyond. The implications of these changes for the value of electricity-generating assets and the market value of the firms that own them depends on the initial allocation of carbon dioxide allowances, the composition of generating assets owned by the firm, and the locations of those assets. Changes in asset values inside the RGGI region may be positive or negative, whereas changes outside of the RGGI region are almost always positive but nonetheless vary greatly. Viewing changes at the firm level aggregates and moderates both positive and negative effects on market value compared with what would be observed by looking at changes at individual facilities. Nonetheless, a particular firm's portfolio of assets is unlikely to reflect the overall composition of assets in the industry as a whole, and some firms are likely to do substantially better or worse than the industry average. 16 refs., 4 figs.

  19. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01T23:59:59.000Z

    trends for four types of electric power plants equipped with CO 2 capture systems: pulverized coal (PC) and natural gas

  20. A Feasibility Study of Non-Seismic Geophysical Methods for Monitoring Geologic CO2 Sequestration

    E-Print Network [OSTI]

    Gasperikova, Erika; Hoversten, G. Michael

    2006-01-01T23:59:59.000Z

    combined CO 2 enhanced oil recovery (EOR) and sequestrationis introduced for enhanced oil/gas recovery or for geologic

  1. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect (OSTI)

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30T23:59:59.000Z

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  2. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01T23:59:59.000Z

    coal mining, petroleum extraction and refining, coking, andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking and

  3. Greenhouse Gas Return on Investment: A New Metric for Energy Technology

    E-Print Network [OSTI]

    Reich-Weiser, Corinne; Dornfeld, David; Horne, Steve

    2008-01-01T23:59:59.000Z

    Gas INTRODUCTION Alternative energy technologies such asmotivations of alternative energy technologies: mitigatingaddresses the goal of alternative energy technology

  4. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Greenhouse gases andGreenhouse gases and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    in gas turbinecombustion in gas turbine HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Effect of COEffect-depleting gases ·· COCO22 removal for gas purificationremoval for gas purification ·· COCO22 removal for greenhouse gas emissions reductionremoval for greenhouse gas emissions reduction ·· Other greenhouse gases

  5. Author's personal copy International Journal of Greenhouse Gas Control 7 (2012) 2029

    E-Print Network [OSTI]

    Johnson, Peter D.

    in geological formations (such as depleted oil and gas reservoirs, deep brine-filled permeable formations, coal for oil and gas exploration and production, gas permeable channels/faults in the caprocks (Annunziatellis et al., 2008), or geomechanical disruptions due to increased pressure in the reservoir, etc. (Gasda

  6. DOE Honors WIPP Representative for Cutting Travel Costs, Greenhouse...

    Energy Savers [EERE]

    DOE Honors WIPP Representative for Cutting Travel Costs, Greenhouse Gas Emissions DOE Honors WIPP Representative for Cutting Travel Costs, Greenhouse Gas Emissions June 29, 2012 -...

  7. Knowledge Partnership for Measuring Air Pollution and Greenhouse...

    Open Energy Info (EERE)

    Measuring Air Pollution and Greenhouse Gas Emissions in Asia Jump to: navigation, search Name Knowledge Partnership for Measuring Air Pollution and Greenhouse Gas Emissions in Asia...

  8. ATF CO2 LASER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    *Operate at low pressure <<1 atm *Bandwidth P (10 atm supports a picosecond pulse) 4 Ultrafast gas lasers require high pressure Inverse Fourier Transform for discrete spectrum...

  9. International Journal of Greenhouse Gas Control 6 (2012) 6976 Contents lists available at SciVerse ScienceDirect

    E-Print Network [OSTI]

    : Pre-combustion CO2 capture Shifted syngas Chrysotile Steam-assisted carbonation Magnesium hydride a b to decarbonize shifted syngas in integrated gasification combined cycle plants was examined in this work from in a basket reactor using model (H2O/H2/CO2) shifted syngas where CO2 uptakes were measured after 1 h

  10. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01T23:59:59.000Z

    that support more load following and peaking generation withfor natural gas- fired load following and peaking generationneeded less load- following and peaking generation. Growth

  11. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01T23:59:59.000Z

    China Electricity Council. partial load in the evening whenof coal units run at partial load would make gas attractivemonth that is run at partial load, while other generators

  12. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    to lower the carbon intensity of the power generationelectricity grid carbon-intensities are considered: importance of grid carbon intensity. Natural-gas-fired CHP

  13. Multi-objective fuel policies: Renewable fuel standards versus Fuel greenhouse gas intensity standards

    E-Print Network [OSTI]

    Rajagopal, Deepak

    2010-01-01T23:59:59.000Z

    Gas Reductions under Low Carbon Fuel Standards? Americanto Implement the Low Carbon Fuel Standard, Volume I Sta?Paper Series Multi-objective fuel policies: Renewable fuel

  14. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01T23:59:59.000Z

    renewables, including large hydropower, by 2020. In 2009,coal mining and hydropower), iron and steel, machinery, andoil, and natural gas. Hydropower, nuclear, and wind energy

  15. Challenges and Opportunities for Regulating Greenhouse Gas Emissions at the State, Regional and Local Level

    E-Print Network [OSTI]

    Doyle, Jim

    2009-01-01T23:59:59.000Z

    house Gas Initiative (RGGI). Shortly thereafter, Westernof Northeast states for the RGGI and Western states for theperspective. .For example, the RGGI states have already ad-

  16. Energy Consumption, Efficiency, Conservation, and Greenhouse Gas Mitigation in Japan's Building Sector

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    i n g s , including Fluorocarbon Leakage: Study o f Thermalgreenhouse gas emissions o f fluorocarbon leakage associatedwarming Impact o f Fluorocarbons used i n Thermal Insulation

  17. Inducinga CO2 leak into ashallow aquifer (CO2FieldLab EUROGIA+ project): Monitoring the CO2 plume in groundwaters.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    (saline aquifer, depleted oil/gas reservoir), aquifers are ubiquitousin the overlying sedimentary pile in case of unwanted CO2leakages from a storage site. Independently from the nature of the reservoir

  18. Development and application of the EPIC model for carbon cycle, greenhouse-gas mitigation, and biofuel studies

    SciTech Connect (OSTI)

    Izaurralde, Roberto C.; Mcgill, William B.; Williams, J.R.

    2012-06-01T23:59:59.000Z

    This chapter provides a comprehensive review of the EPIC model in relation to carbon cycle, greenhouse-gas mitigation, and biofuel applications. From its original capabilities and purpose (i.e., quantify the impacts or erosion on soil productivity), the EPIC model has evolved into a comprehensive terrestrial ecosystem model for simulating with more or less process-level detail many ecosystem processes such as weather, hydrology, plant growth and development, carbon cycle (including erosion), nutrient cycling, greenhouse-gas emissions, and the most complete set of manipulations that can be implemented on a parcel of land (e.g. tillage, harvest, fertilization, irrigation, drainage, liming, burning, pesticide application). The chapter also provides details and examples of the latest efforts in model development such as the coupled carbon-nitrogen model, a microbial denitrification model with feedback to the carbon decomposition model, updates on calculation of ecosystem carbon balances, and carbon emissions from fossil fuels. The chapter has included examples of applications of the EPIC model in soil carbon sequestration, net ecosystem carbon balance, and biofuel studies. Finally, the chapter provides the reader with an update on upcoming improvements in EPIC such as the additions of modules for simulating biochar amendments, sorption of soluble C in subsoil horizons, nitrification including the release of N2O, and the formation and consumption of methane in soils. Completion of these model development activities will render an EPIC model with one of the most complete representation of biogeochemical processes and capable of simulating the dynamic feedback of soils to climate and management in terms not only of transient processes (e.g., soil water content, heterotrophic respiration, N2O emissions) but also of fundamental soil properties (e.g. soil depth, soil organic matter, soil bulk density, water limits).

  19. Greenhouse Gas Concerns and Power Sector Planning (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01T23:59:59.000Z

    Concerns about potential climate change driven by rising atmospheric concentrations of Greenhouse Gases (GHG) have grown over the past two decades, both domestically and abroad. In the United States, potential policies to limit or reduce GHG emissions are in various stages of development at the state, regional, and federal levels. In addition to ongoing uncertainty with respect to future growth in energy demand and the costs of fuel, labor, and new plant construction, U.S. electric power companies must consider the effects of potential policy changes to limit or reduce GHG emissions that would significantly alter their planning and operating decisions. The possibility of such changes may already be affecting planning decisions for new generating capacity.

  20. CO2 Reduction through Optimization of Steam Network in Petroleum Refineries: Evaluation of New Scenario

    E-Print Network [OSTI]

    Manesh, M. H. K; Khodaie, H.; Amidpour, M.

    2008-01-01T23:59:59.000Z

    Steam network of petroleum refinery is energy intensive, and consequently contribute significantly to the greenhouse gases emissions. A simple model for the estimation of CO2 emissions associated with operation of steam network as encountered...

  1. Chemical Looping Combustion for inherent CO2 capture in a

    E-Print Network [OSTI]

    HRSG Stack Steam TurbineFuel Compr. Air Flue gas H2O CO2 to compression Depleted air HP Steam not possible with Ni/NiO 6 CLC in a combined cycle power plant Fuel Reactor Air Reactor Gas Turbine Gas Turbine) ­ adiabatic, 20 bar Stoichiometric MeO Air-fuel ratio Stoichiometric ­ 3*Stoicihometric Gas turbine

  2. Methodology for Assessing Greenhouse Gas Emissions and Assessing Mitigation Options for On-Road Mobile Sources Project for the Houston-Galveston Area Council

    E-Print Network [OSTI]

    Methodology for Assessing Greenhouse Gas Emissions and Assessing Mitigation Options for On reductions in GHG, and b) use analytical tools/methods to assess the emissions reductions possible through and prioritized based on factors such as cost effectiveness, potential for emission reductions, and applicability

  3. Accepted for publication in Energy Policy Greenhouse-gas Emissions from Solar Electric-and Nuclear Power: A Life-cycle

    E-Print Network [OSTI]

    Accepted for publication in Energy Policy Greenhouse-gas Emissions from Solar Electric- and Nuclear, photovoltaic, nuclear, life cycle 1 #12;Introduction The production of energy by burning fossil fuels generates, it is envisioned that expanding generation technologies based on nuclear power and renewable energy sources would

  4. Executive Summary of the Inventory of U.S. Greenhouse Gas Emissions and Sinks: 19902009 1 n emissions inventory that identifies and quantifies a country's primary anthropogenic1

    E-Print Network [OSTI]

    Little, John B.

    Executive Summary of the Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990­2009 1 n emissions inventory that identifies and quantifies a country's primary anthropogenic1 In 1992, the United climate change. This inventory adheres to both (1) a comprehensive and detailed set of methodologies

  5. Pilot application of PalmGHG, the RSPO greenhouse gas calculator for oil palm products , Chase L.D.C.b

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Pilot application of PalmGHG, the RSPO greenhouse gas calculator for oil palm products Bessou C.1016/j.jclepro.2013.12.008 (Pre-proof version) ABSTRACT The Roundtable on Sustainable Palm Oil (RSPO) is a non-profit association promoting sustainable palm oil through a voluntary certification scheme. Two

  6. SUBTASK 2.19 OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE

    SciTech Connect (OSTI)

    Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

    2014-12-31T23:59:59.000Z

    Carbon dioxide (CO2) is produced in large quantities during electricity generation and by industrial processes. These CO2 streams vary in terms of both composition and mass flow rate, sometimes substantially. The impact of a varying CO2 stream on pipeline and storage operation is not fully understood in terms of either operability or infrastructure robustness. This study was performed to summarize basic background from the literature on the topic of operational flexibility of CO2 transport and storage, but the primary focus was on compiling real-world lessons learned about flexible operation of CO2 pipelines and storage from both large-scale field demonstrations and commercial operating experience. Modeling and pilot-scale results of research in this area were included to illustrate some of the questions that exist relative to operation of carbon capture and storage (CCS) projects with variable CO2 streams. It is hoped that this reports real-world findings provide readers with useful information on the topic of transport and storage of variable CO2 streams. The real-world results were obtained from two sources. The first source consisted of five full-scale, commercial transportstorage projects: Sleipner, Snhvit, In Salah, Weyburn, and Illinois BasinDecatur. These scenarios were reviewed to determine the information that is available about CO2 stream variability/intermittency on these demonstration-scale projects. The five projects all experienced mass flow variability or an interruption in flow. In each case, pipeline and/or injection engineers were able to accommodate any issues that arose. Significant variability in composition has not been an issue at these five sites. The second source of real- world results was telephone interviews conducted with experts in CO2 pipeline transport, injection, and storage during which commercial anecdotal information was acquired to augment that found during the literature search of the five full-scale projects. The experts represented a range of disciplines and hailed from North America and Europe. Major findings of the study are that compression and transport of CO2 for enhanced oil recovery (EOR) purposes in the United States has shown that impurities are not likely to cause transport problems if CO2 stream composition standards are maintained and pressures are kept at 10.3 MPa or higher. Cyclic, or otherwise intermittent, CO2 supplies historically have not impacted in-field distribution pipeline networks, wellbore integrity, or reservoir conditions. The U.S. EOR industry has demonstrated that it is possible to adapt to variability and intermittency in CO2 supply through flexible operation of the pipeline and geologic storage facility. This CO2 transport and injection experience represents knowledge that can be applied in future CCS projects. A number of gaps in knowledge were identified that may benefit from future research and development, further enhancing the possibility for widespread application of CCS. This project was funded through the Energy & Environmental Research CenterU.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

  7. A methodology for assessing MIT's energy used and greenhouse gas emissions

    E-Print Network [OSTI]

    Groode, Tiffany Amber, 1979-

    2004-01-01T23:59:59.000Z

    (cont.) actions can be made to decrease losses and therefore increase plant efficiencies. As production efficiencies are maximized, fuel use and thus emissions are minimized. From fiscal year 1998 to 2003, the gas turbine ...

  8. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    for out-of-state coal generation, then clearly the GHGElectricity Generation (TWh/a) Natural Gas Coal Natural Gascoal becomes the marginal fuel. Note that the marginal generation

  9. International Journal of Greenhouse Gas Control 18 (2013) 277284 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Perfect, Ed

    into the atmosphere by large point sources such as fossil fuel power plants and cement opera- tions. The technology for carbon capture and storage already exists and is currently implemented by the oil and natural gas

  10. Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potential and Policies

    E-Print Network [OSTI]

    McCollum, David L; Gould, Gregory; Greene, David L

    2010-01-01T23:59:59.000Z

    Liquefied natural gas (LNG), Wind power (sails) Aviationand Policies the use of LNG will result in a small 2 percentbe a much greater potential to use LNG aboard most ships if

  11. Simulation assessment of CO2 sequestration potential and enhanced methane recovery in low-rank coalbeds of the Wilcox Group, east-central Texas

    E-Print Network [OSTI]

    Hernandez Arciniegas, Gonzalo

    2006-10-30T23:59:59.000Z

    Carbon dioxide (CO2) from energy consumption is a primary source of greenhouse gases. Injection of CO2 from power plants in coalbed reservoirs is a plausible method for reducing atmospheric emissions, and it can have the additional benefit...

  12. Strategic Eurasian Natural Gas Model for Energy Security

    E-Print Network [OSTI]

    Chyong, Chi-Kong; Hobbs, Benjamin F.

    2011-04-06T23:59:59.000Z

    capacities would constitute 23% of the EUs 4 Natural gas is in a favourable position in the European electricity generation industry, especially in the context of regulating greenhouse gas emissions... . Gas-fired power plants emit roughly half the CO2 per KWh of electricity output compared to coal-fired power plants. 5 Although, on average, annual growth in gas consumption in Europe during the past twenty years exceeded the annual growth of energy...

  13. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01T23:59:59.000Z

    National Greenhouse Gas Inventories Reference Manual (VolumeNational Greenhouse Gas Inventories: the Workbook (VolumeN ATIONAL L ABORATORY Inventory of Chinas Energy-Related CO

  14. CO2 capture processes in power plants - Le captage du CO2 dans les centrales thermiques

    E-Print Network [OSTI]

    Chakib Bouallou

    2010-08-12T23:59:59.000Z

    This review is devoted to assess and compare various processes aiming at recover CO2 from power plants fed with natural gas (NGCC) and pulverized coal (PC). These processes are post combustion CO2 capture using chemical solvents, natural gas reforming for pre-combustion capture and oxy-fuel combustion with cryogenic recovery of CO2. These processes were evaluated to give some clues for choosing the best option for each type of power plant. The comparison of these various concepts suggests that, in the short and medium term, chemical absorption is the most interesting process for NGCC power plants. For CP power plants, oxy-combustion can be a very interesting option, as well as post-combustion capture by chemical solvents.

  15. Reducing Greenhouse Emissions and Fuel Consumption

    E-Print Network [OSTI]

    Shaheen, Susan; Lipman, Timothy

    2007-01-01T23:59:59.000Z

    climate change/stern_re- view_report.cfm. (2006). RGGI.Greenhouse Gas Initiative (RGGI): An Initia tive of theGreenhouse Gas Initia tive (RGGI). Currently, Connecticut,

  16. The water-gas shift (WGS) reaction (CO + H2O = CO2+ H2) is an important reaction for hydrogen upgrading during fuel

    E-Print Network [OSTI]

    Napp, Nils

    -treatment units in practical low-temperature PEM fuel cell systems, whereby the deleterious CO should be totally for hydrogen upgrading during fuel gas processing. Emerging applications in fuel cells require active, non-pyrophoric, and cost-effective catalysts. Along with a new group of platinum catalysts with atomically dispersed Pt

  17. The impact of municipal solid waste treatment methods on greenhouse gas emissions in Lahore, Pakistan

    SciTech Connect (OSTI)

    Batool, Syeda Adila [Department of Space Science, Punjab University, Lahore 54600 (Pakistan)], E-mail: aadila_batool@yahoo.com; Chuadhry, Muhammad Nawaz [College of Earth and Environmental Sciences, University of the Punjab, Lahore (Pakistan)], E-mail: muhammadnawazchaudhry@yahoo.com

    2009-01-15T23:59:59.000Z

    The contribution of existing municipal solid waste management to emission of greenhouse gases and the alternative scenarios to reduce emissions were analyzed for Data Ganj Bukhsh Town (DGBT) in Lahore, Pakistan using the life cycle assessment methodology. DGBT has a population of 1,624,169 people living in 232,024 dwellings. Total waste generated is 500,000 tons per year with an average per capita rate of 0.84 kg per day. Alternative scenarios were developed and evaluated according to the environmental, economic, and social atmosphere of the study area. Solid waste management options considered include the collection and transportation of waste, collection of recyclables with single and mixed material bank container systems (SMBCS, MMBCS), material recovery facilities (MRF), composting, biogasification and landfilling. A life cycle inventory (LCI) of the six scenarios along with the baseline scenario was completed; this helped to quantify the CO{sub 2} equivalents, emitted and avoided, for energy consumption, production, fuel consumption, and methane (CH{sub 4}) emissions. LCI results showed that the contribution of the baseline scenario to the global warming potential as CO{sub 2} equivalents was a maximum of 838,116 tons. The sixth scenario had a maximum reduction of GHG emissions in terms of CO{sub 2} equivalents of -33,773 tons, but the most workable scenario for the current situation in the study area is scenario 5. It saves 25% in CO{sub 2} equivalents compared to the baseline scenario.

  18. Greenhouse Gas Emissions from U.S. Hydropower Reservoirs: FY2011 Annual Progress Report

    SciTech Connect (OSTI)

    Stewart, Arthur J [ORNL; Mosher, Jennifer J [ORNL; Mulholland, Patrick J [ORNL; Fortner, Allison M [ORNL; Phillips, Jana Randolph [ORNL; Bevelhimer, Mark S [ORNL

    2012-05-01T23:59:59.000Z

    The primary objective of this study is to quantify the net emissions of key greenhouse gases (GHG) - notably, CO{sub 2} and CH{sub 4} - from hydropower reservoirs in moist temperate areas within the U.S. The rationale for this objective is straightforward: if net emissions of GHG can be determined, it would be possible to directly compare hydropower to other power-producing methods on a carbon-emissions basis. Studies of GHG emissions from hydropower reservoirs elsewhere suggest that net emissions can be moderately high in tropical areas. In such areas, warm temperatures and relatively high supply rates of labile organic matter can encourage high rates of decomposition, which (depending upon local conditions) can result in elevated releases of CO{sub 2} and CH{sub 4}. CO{sub 2} and CH{sub 4} emissions also tend to be higher for younger reservoirs than for older reservoirs, because vegetation and labile soil organic matter that is inundated when a reservoir is created can continue to decompose for several years (Galy-Lacaux et al. 1997, Barros et al. 2011). Water bodies located in climatically cooler areas, such as in boreal forests, could be expected to have lower net emissions of CO{sub 2} and CH{sub 4} because their organic carbon supplies tend to be relatively recalcitrant to microbial action and because cooler water temperatures are less conducive to decomposition.

  19. ENVIRONMENTAL ASSESSMENT OF GEOLOGIC STORAGE OF CO2 Jason J. Heinrich, Howard J. Herzog, David M. Reiner

    E-Print Network [OSTI]

    analogs: acid gas injection (AGI), enhanced oil recovery (EOR), natural gas storage, and CO2 transportENVIRONMENTAL ASSESSMENT OF GEOLOGIC STORAGE OF CO2 * Jason J. Heinrich, Howard J. Herzog, David M of reducing CO2 emissions. The storage of CO2 in underground geologic reservoirs is one such idea that employs

  20. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J. (Energy Systems)

    2012-07-06T23:59:59.000Z

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  1. Greenhouse gas emissions and the surface transport of freight in Canada

    E-Print Network [OSTI]

    of several pre-defined factors to changes in energy consumption and energy-related gas emissions (Ang appearing to be rising proportionally as a transportation mode. Federal government initiatives on the US the transportation sector (Office of Energy Efficiency, 2004); a rise of nearly 25% over 1990. The geographical

  2. Multi-objective fuel policies: Renewable fuel standards versus Fuel greenhouse gas intensity standards

    E-Print Network [OSTI]

    Rajagopal, Deepak

    2010-01-01T23:59:59.000Z

    the energy security bene?ts of reduced u.s. oil imports.security, namely, the share of alternatives to crude oil (oil such as o?-shore petroleum, and coal/gas based liquids, can be considered better for energy security (

  3. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01T23:59:59.000Z

    CO 2 escapes the reservoir through the abandoned well. Theof the abandoned well and the gas reservoir is calculated by4 reservoir 1.e-12 1.e-14 8.4e-4 Fracture or abandoned well

  4. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    in depleted or abandoned oil and gas reservoirs; how- ever,abandoned wells represent a potentially direct route from reservoirabandoned in the 1930s with no barrier installed after it encountered a natural CO 2 reservoir

  5. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01T23:59:59.000Z

    in depleted or abandoned oil and gas reservoirs; how- ever,oil well abandoned in the 1930s with no barrier installed after it encountered a natural CO 2 reservoir

  6. Developing a monitoring and verification plan with reference to the Australian Otway CO2 pilot project

    SciTech Connect (OSTI)

    Dodds, K.; Daley, T.; Freifeld, B.; Urosevic, M.; Kepic, A.; Sharma, S.

    2009-05-01T23:59:59.000Z

    The Australian Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) is currently injecting 100,000 tons of CO{sub 2} in a large-scale test of storage technology in a pilot project in southeastern Australia called the CO2CRC Otway Project. The Otway Basin, with its natural CO{sub 2} accumulations and many depleted gas fields, offers an appropriate site for such a pilot project. An 80% CO{sub 2} stream is produced from a well (Buttress) near the depleted gas reservoir (Naylor) used for storage (Figure 1). The goal of this project is to demonstrate that CO{sub 2} can be safely transported, stored underground, and its behavior tracked and monitored. The monitoring and verification framework has been developed to monitor for the presence and behavior of CO{sub 2} in the subsurface reservoir, near surface, and atmosphere. This monitoring framework addresses areas, identified by a rigorous risk assessment, to verify conformance to clearly identifiable performance criteria. These criteria have been agreed with the regulatory authorities to manage the project through all phases addressing responsibilities, liabilities, and to assure the public of safe storage.

  7. International Journal of Greenhouse Gas Control 5 (2011) 15071516 Contents lists available at SciVerse ScienceDirect

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    -surface and ground surface and determine if it originates from a deep storage site or a different source is critical a Scottish Carbon Capture and Storage, School of GeoSciences, The University of Edinburgh, Grant Institute capture and storage Geochemical tracing of CO2 Noble gases Carbon isotopes Geological storage of CO2

  8. CO2-avskiljning med syrgasfrbrnning -nya tekniska mjligheter

    E-Print Network [OSTI]

    Lemurell, Stefan

    with power and industrial sectors #12;Air-Fuel Combustion Air Fuel Flue gas CO2: 10-20 % N2: 60-70% Combustion Process #12;Oxy-Fuel vs. Air-Fuel Combustion - principle changes Principle changes: · Feed gas composition · Concentration of N2 · Recycle of flue gas · Concentration of combustion products · Residence

  9. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01T23:59:59.000Z

    of U.S. Croplands for Biofuels Increases Greenhouse GasesGHG Emissions from Biofuels . in STEPS Research Symposium .NRDC, Growing Energy: How Biofuels Can Help End America's

  10. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W. Keith

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    : The upstream oil and gas industry routinely injects CO2 underground to enhance oil recovery (CO2- EOR). A bit more than 2,000 km of CO2 pipelines have been laid in Texas to provide for CO2-EOR. In these operations-used, since operators must pay for the CO2. Yet at the end of an EOR operation a major fraction of CO2

  11. Impact of the renewable oxygenate standard for reformulated gasoline on ethanol demand, energy use, and greenhouse gas emissions

    SciTech Connect (OSTI)

    Stork, K.C.; Singh, M.K.

    1995-04-01T23:59:59.000Z

    To assure a place for renewable oxygenates in the national reformulated gasoline (RFG) program, the US Environmental Protection Agency has promulgated the renewable oxygenate standard (ROS) for RFG. It is assumed that ethanol derived from corn will be the only broadly available renewable oxygenate during Phase I of the RFG program. This report analyzes the impact that the ROS could have on the supply of ethanol, its transported volume, and its displacement from existing markets. It also considers the energy and crude oil consumption and greenhouse gas (GHG) emissions that could result from the production and use of various RFGs that could meet the ROS requirements. The report concludes that on the basis of current and projected near-term ethanol capacity, if ethanol is the only available renewable oxygenate used to meet the requirements of the ROS, diversion of ethanol from existing use as a fuel is likely to be necessary. Year-round use of ethanol and ETBE would eliminate the need for diversion by reducing winter demand for ethanol. On an RFG-program-wide basis, using ethanol and ETBE to satisfy the ROS can be expected to slightly reduce fossil energy use, increase crude oil use, and have essentially no effect on GHG emissions or total energy use relative to using RFG oxygenated only with MTBE.

  12. Transportation Energy Futures Series: Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-01T23:59:59.000Z

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  13. THE GREENHOUSE EFFECT Stephen E. Schwartz

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    THE GREENHOUSE EFFECT Stephen E. Schwartz Atmospheric Sciences Division CSSP Lecture July 30, 2002 . . . IS TO PUT TWO PEOPLE IN IT! #12;YOUR FAMILY'S CONTRIBUTION TO THE GREENHOUSE EFFECT 0.8 0.6 0.4 0.2 0.0 CO2 of carbon a year in the form of carbon dioxide. #12;YOUR CONTRIBUTION TO THE GREENHOUSE EFFECT At half

  14. Eco-efficiency for greenhouse gas emissions mitigation of municipal solid waste management: A case study of Tianjin, China

    SciTech Connect (OSTI)

    Zhao Wei, E-mail: zhaowei.tju@gmail.com [College of Civil Engineering and Architecture, Liaoning University of Technology, 121000 Jinzhou (China); Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands); Huppes, Gjalt, E-mail: huppes@cml.leidenuniv.nl [Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands); Voet, Ester van der, E-mail: Voet@cml.leidenuniv.nl [Institute of Environmental Sciences (CML), Leiden University, P.O. Box 9518, 2300RA Leiden (Netherlands)

    2011-06-15T23:59:59.000Z

    The issue of municipal solid waste (MSW) management has been highlighted in China due to the continually increasing MSW volumes being generated and the limited capacity of waste treatment facilities. This article presents a quantitative eco-efficiency (E/E) analysis on MSW management in terms of greenhouse gas (GHG) mitigation. A methodology for E/E analysis has been proposed, with an emphasis on the consistent integration of life cycle assessment (LCA) and life cycle costing (LCC). The environmental and economic impacts derived from LCA and LCC have been normalized and defined as a quantitative E/E indicator. The proposed method was applied in a case study of Tianjin, China. The study assessed the current MSW management system, as well as a set of alternative scenarios, to investigate trade-offs between economy and GHG emissions mitigation. Additionally, contribution analysis was conducted on both LCA and LCC to identify key issues driving environmental and economic impacts. The results show that the current Tianjin's MSW management system emits the highest GHG and costs the least, whereas the situation reverses in the integrated scenario. The key issues identified by the contribution analysis show no linear relationship between the global warming impact and the cost impact in MSW management system. The landfill gas utilization scenario is indicated as a potential optimum scenario by the proposed E/E analysis, given the characteristics of MSW, technology levels, and chosen methodologies. The E/E analysis provides an attractive direction towards sustainable waste management, though some questions with respect to uncertainty need to be discussed further.

  15. Separation of CO2 from CH4 Using Mixed-Ligand Metal-Organic Youn-Sang Bae,

    E-Print Network [OSTI]

    and landfill gas, where methane is the major component. The presence of CO2 reduces the energy content

  16. CO2 escapes in the Laacher See region, East Eifel, Germany: application of natural analogue onshore and offshore geochemical monitoring

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    performing CO2 sequestration in depleted oil/gas reservoirs or deep saline aquifers (Gale, 2004; Gapillou et

  17. Using ArcGIS to extrapolate greenhouse gas emissions on the Pengxi River, a tributary of the Three Gorges Reservoir in China

    E-Print Network [OSTI]

    Yasarer, Lindsey

    2014-11-19T23:59:59.000Z

    Using ArcGIS to extrapolate greenhouse gas emissions on the Pengxi River, a tributary of the Three Gorges Reservoir in China Lindsey MW Yasarer, PhD Candidate, University of Kansas Dr. Zhe Li, Associate Professor, Chongqing University Dr...D Student, Chongqing University Zhengyu Zhang and Xiao Yao, Masters Students, Chongqing University CSTEC: China Science and Technology Exchange Center NSF EAPSI Program The research was funded by the National Natural Science Foundation of China...

  18. Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasifiction combined sycle (IGCC) power plant with CO2 capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01T23:59:59.000Z

    Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS) and the Parallel Computing toolbox from Mathworks. In this presentation, we will share our experience in setting up parallel computing using GA in the MATLAB environment and present the overall approach for achieving higher computational efficiency in this framework.

  19. 1. Introduction The atmospheric greenhouse effect is the basic mechanism

    E-Print Network [OSTI]

    1. Introduction The atmospheric greenhouse effect is the basic mechanism whereby absorbed solar system of the Earth is endowed with a moderately strong greenhouse effect that is characterized by non CO2. There is a strong feedback contribution to the greenhouse effect by water vapor and clouds

  20. International Experience with Key Program Elements of Industrial Energy Efficiency or Greenhouse Gas Emissions Reduction Target-Setting Programs

    E-Print Network [OSTI]

    Price, Lynn; Galitsky, Christina; Kramer, Klaas Jan

    2008-01-01T23:59:59.000Z

    of companies with the Danish Energy Agency, were made forMay 29, 2003. Danish Energy Agency, 2000. Green Taxes forDanish CO 2 -Tax Scheme, in International Energy Agency,

  1. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01T23:59:59.000Z

    IGCC, w/o or w/ CCS) Carbon Intensity of Electricity (gCO2-reductions to fuel carbon intensity in Efficient Biofuelsreductions to fuel carbon intensity in Electric- drive

  2. Marginal Abatement Costs and Marginal Welfare Costs for Greenhouse Gas Emissions Reductions: Results from the EPPA Model

    E-Print Network [OSTI]

    Morris, Jennifer

    Marginal abatement cost (MAC) curves, relationships between tons of emissions abated and the CO2 (or GHG) price, have been widely used as pedagogic devices to illustrate simple economic concepts such as the benefits of ...

  3. Mixed-Matric Membranes for CO2 and H2 Gas Separations Using Metal-Organic Framework and Mesoporus Hybrid Silicas

    SciTech Connect (OSTI)

    Inga Musselman; Kenneth Balkus, Jr.; John Ferraris

    2009-01-07T23:59:59.000Z

    In this work, we have investigated the separation performance of polymer-based mixed-matrix membranes containing metal-organic frameworks and mesoporous hybrid silicas. The MOF/Matrimid{reg_sign} and MOP-18/Matrimid{reg_sign} membranes exhibited improved dispersion and mechanical strength that allowed high additive loadings with reduced aggregation, as is the case of the 80 wt% MOP-18/Matrimid{reg_sign} and the 80% (w/w) Cu-MOF/Matrimid{reg_sign} membranes. Membranes with up to 60% (w/w) ZIF-8 content exhibited similar mechanical strength and improved dispersion. The H{sub 2}/CO{sub 2} separation properties of MOF/Matrimid{reg_sign} mixed-matrix membranes was improved by either keeping the selectivity constant and increasing the permeability (MOF-5, Cu-MOF) or by improving both selectivity and permeability (ZIF-8). In the case of MOF-5/Matrimid{reg_sign} mixed-matrix membranes, the H{sub 2}/CO{sub 2} selectivity was kept at 2.6 and the H{sub 2} permeability increased from 24.4 to 53.8 Barrers. For the Cu-MOF/Matrimid{reg_sign} mixed-matrix membranes, the H{sub 2}/CO{sub 2} selectivity was kept at 2.05 and the H{sub 2} permeability increased from 17.1 to 158 Barrers. These two materials introduced porosity and uniform paths that enhanced the gas transport in the membranes. When ZIF-8/Matrimid{reg_sign} mixed-matrix membranes were studied, the H{sub 2}/CO{sub 2} selectivity increased from 2.9 to 4.4 and the permeability of H{sub 2} increased from 26.5 to 35.8 Barrers. The increased H{sub 2}/CO{sub 2} selectivity in ZIF-8/Matrimid{reg_sign} membranes was explained by the sieving effect introduced by the ZIF-8 crystals (pore window 0.34 nm) that restricted the transport of molecules larger than H{sub 2}. Materials with microporous and/or mesoporous cavities like carbon aerogel composites with zeolite A and zeolite Y, and membranes containing mesoporous ZSM-5 showed sieving effects for small molecules (e.g. H{sub 2} and CO{sub 2}), however, the membranes were most selective for CO{sub 2} due to the strong interaction of the zeolites with CO{sub 2}. For example, at 30 wt% ZSM-5 loading, the CO{sub 2}/CH{sub 4} selectivity increased from 34.7 (Matrimid{reg_sign}) to 56.4. The large increase in selectivity was the result of the increase in CO{sub 2} permeability from 7.3 (Matrimid{reg_sign}) to 14.6 Barrers. At 30 wt% ZSM-5 loading, the H{sub 2}/CH{sub 4} separation was also improved from 83.3 (Matrimid{reg_sign}) to 136.7 with an increase in H{sub 2} permeability from 17.5 (Matrimid{reg_sign}) to 35.3 Barrers. The 10% carbon aerogel-zeolite A and -zeolite Y composite/Matrimid{reg_sign} membranes exhibited an increase in the CO{sub 2}/CH{sub 4} separation from 34.7 to 71.5 (zeolite A composite) and to 57.4 (zeolite Y composite); in addition, the membrane exhibited an increase in the CO{sub 2}/N{sub 2} separation from 33.1 to 50 (zeolite A composite) and to 49.4 (zeolite Y composite), indicating that these type of materials have affinity for CO{sub 2}. The inclusion of mesoporosity enhanced the dispersion of the additive allowing loadings of up to 30% (w/w) without the formation of non-selective voids.

  4. Capturing CO2 from Air Anca Timofte

    E-Print Network [OSTI]

    Fischlin, Andreas

    Capturing CO2 from Air Anca Timofte Climeworks AG Birchstrasse 155, 8050 Zürich www.climeworks.com, contact@climeworks.com Carbon Mitigation Lecture, 27 October 2014 #12;Air Climeworks CO2 capture plant CO2-free air Pure CO2 #12;3 Climeworks Products Demonstrator · 1 ton CO2 per year · Online since 12

  5. Nitrogen availability and indirect measurements of greenhouse gas emissions from aerobic and anaerobic biowaste digestates applied to agricultural soils

    SciTech Connect (OSTI)

    Rigby, H.; Smith, S.R., E-mail: s.r.smith@imperial.ac.uk

    2013-12-15T23:59:59.000Z

    Highlights: Nitrogen release in digestate-amended soil depends on the digestate type. Overall N release is modulated by digestate mineral and mineralisable N contents. Microbial immobilisation does not influence overall release of digestate N in soil. Digestate physical properties and soil type interact to affect overall N recovery. High labile C inputs in digestate may promote denitrification in fine-textured soil. - Abstract: Recycling biowaste digestates on agricultural land diverts biodegradable waste from landfill disposal and represents a sustainable source of nutrients and organic matter (OM) to improve soil for crop production. However, the dynamics of nitrogen (N) release from these organic N sources must be determined to optimise their fertiliser value and management. This laboratory incubation experiment examined the effects of digestate type (aerobic and anaerobic), waste type (industrial, agricultural and municipal solid waste or sewage sludge) and soil type (sandy loam, sandy silt loam and silty clay) on N availability in digestate-amended soils and also quantified the extent and significance of the immobilisation of N within the soil microbial biomass, as a possible regulatory mechanism of N release. The digestate types examined included: dewatered, anaerobically digested biosolids (DMAD); dewatered, anaerobic mesophilic digestate from the organic fraction of municipal solid waste (DMADMSW); liquid, anaerobic co-digestate of food and animal slurry (LcoMAD) and liquid, thermophilic aerobic digestate of food waste (LTAD). Ammonium chloride (NH{sub 4}Cl) was included as a reference treatment for mineral N. After 48 days, the final, maximum net recoveries of mineral N relative to the total N (TN) addition in the different digestates and unamended control treatments were in the decreasing order: LcoMAD, 68%; LTAD, 37%, DMAD, 20%; and DMADMSW, 11%. A transient increase in microbial biomass N (MBN) was observed with LTAD application, indicating greater microbial activity in amended soil and reflecting the lower stability of this OM source, compared to the other, anaerobic digestate types, which showed no consistent effects on MBN compared to the control. Thus, the overall net release of digestate N in different soil types was not regulated by N transfer into the soil microbial biomass, but was determined primarily by digestate properties and the capacity of the soil type to process and turnover digestate N. In contrast to the sandy soil types, where nitrate (NO{sub 3}{sup -}) concentrations increased during incubation, there was an absence of NO{sub 3}{sup -} accumulation in the silty clay soil amended with LTAD and DMADMSW. This provided indirect evidence for denitrification activity and the gaseous loss of N, and the associated increased risk of greenhouse gas emissions under certain conditions of labile C supply and/or digestate physical structure in fine-textured soil types. The significance and influence of the interaction between soil type and digestate stability and physical properties on denitrification processes in digestate-amended soils require urgent investigation to ensure management practices are appropriate to minimise greenhouse gas emissions from land applied biowastes.

  6. Combustion-Assisted CO2 Capture Using MECC Membranes

    SciTech Connect (OSTI)

    Sherman, Steven R [ORNL; Gray, Dr. Joshua R. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Brinkman, Dr. Kyle S. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Huang, Dr. Kevin [University of South Carolina, Columbia

    2012-01-01T23:59:59.000Z

    Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO2 from power plant flue gas. Here a modified MECC CO2 capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO2 driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO2 in the flue gas may be captured, and a compressed CO2 product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO2 capture system, and has the potential to meet U.S. DOE s goal that deployment of a CO2 capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

  7. Interaction between CO2-rich solutions and reservoir-seal rocks. Experimentation

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    coal systems 5.Use of CO2 in enhanced coal bed methane recovery 6.Other suggested options (basalts, oilInteraction between CO2-rich solutions and reservoir-seal rocks. Experimentation María García formations (after Cook, 1999). Geological Storage Options for CO2 1.Depleted oil and gas reservoirs 2.Use

  8. The effect of CO2 on the plasma remediation of NxOy Ann C. Gentilea)

    E-Print Network [OSTI]

    Kushner, Mark

    The effect of CO2 on the plasma remediation of NxOy Ann C. Gentilea) and Mark J. Kushnerb repetitively pulsed dielectric barrier discharges. As combustion effluents contain large percentages of CO2, in this paper we discuss the consequences of CO2 in the gas mixture on the efficiency of remediation

  9. Changes in seal capacity of fractured claystone caprocks induced by dissolved and gaseous CO2 seepage

    E-Print Network [OSTI]

    Luquot, Linda

    Changes in seal capacity of fractured claystone caprocks induced by dissolved and gaseous CO2; accepted 17 June 2008; published 31 July 2008. [1] Claystone caprocks are often the ultimate seal for CO2 underground storage when residual CO2 gas reaches the reservoir top due to buoyancy. Permeability changes

  10. EQUILIBRIUM DATA OF CO2-BASED SEMI-CLATHRATES FROM QUATERNARY AMMONIUM SOLUTIONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of Carbone dioxide by gas hydrate formation is a new process for separating CO2 from flue gases Mines de SAINT- ETIENNE, FRANCE ABSTRACT CO2 mitigation represents a major industrial and scientific, especially for the industries in which the gases to be treated are well localized. CO2 capture by using

  11. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06T23:59:59.000Z

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  12. E85, Flex-Fuel Vehicles, and AB 1493 Integrating biofuels into California's vehicular greenhouse gas regulations

    E-Print Network [OSTI]

    Kammen, Daniel M.

    E85, Flex-Fuel Vehicles, and AB 1493 Integrating biofuels into California's vehicular greenhouse.................................................................................................. 5 1.1.3 CALIFORNIA CLEAN FUELS PROGRAM ....................................... 6 1.1.5 AB 1007: THE ALTERNATIVE FUELS PLAN

  13. Large releases from CO2 storage reservoirs: Analogs, scenarios, and modeling needs

    E-Print Network [OSTI]

    Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist, Jonny; Tsang, Chin-Fu; Karimjee, Anhar

    2006-01-01T23:59:59.000Z

    abandoned wells is a major concern for storage of CO 2 in depleted or near-depleted oil and gas reservoirs [

  14. Large releases from CO2 storage reservoirs: analogs, scenarios, and modeling needs

    E-Print Network [OSTI]

    Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist, Jonny; Tsang, Chin-Fu; Karimjee, Anhar

    2005-01-01T23:59:59.000Z

    abandoned wells is a major concern for storage of CO 2 in depleted or near-depleted oil and gas reservoirs [

  15. Large Releases from CO2 Storage Reservoirs: A Discussion of Natural Analogs, FEPS, and Modeling Needs

    E-Print Network [OSTI]

    Birkholzer, J.; Pruess, K.; Lewicki, J.L.; Rutqvist, J.; Tsang, C-F.; Karimjee, A.

    2008-01-01T23:59:59.000Z

    abandoned wells is a major concern for geological storage of CO 2 in depleted or near-depleted oil and gas reservoirs [

  16. Highlights of the 2009 SEG summer research workshop on "CO2 Sequestration Geophysics"

    E-Print Network [OSTI]

    Lumley, D.

    2010-01-01T23:59:59.000Z

    industrial applications, the CO 2 generated cannot easily be reduced by energy conservation or efficiency measures (for example LNG liquid natural gas

  17. Surface CO2 leakage during the first shallow subsurface CO2 release experiment

    E-Print Network [OSTI]

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2008-01-01T23:59:59.000Z

    numbered 0-6. Plots of F CO2 measured along the surface wellin Figure 2. Figure 2. Log F CO2 maps for measurements madeof soil CO 2 flux (F CO2 ). The surface leakage onset,

  18. Dewetting of silica surfaces upon reactions with supercritical CO2 and brine: Pore-scale studies in micromodels

    E-Print Network [OSTI]

    Kim, Y.

    2013-01-01T23:59:59.000Z

    CO 2 injected into depleted oil reservoirs may have faster2 sequestration in depleted oil and gas reservoirs - caprocksaline aquifers, depleted oil and gas reservoirs, unmineable

  19. Evaluation of Efficiency Activities in the Industrial Sector Undertaken in Response to Greenhouse Gas Emission Reduction Targets

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    of a flue gas condenser with a steam boiler. ? Improvedsteam dryers by gas ? Dryers and filtration equipment ? Applied CHP ? Purchased flue gas condensers ?

  20. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01T23:59:59.000Z

    Hydrogen (Natural Gas, pipeline) Hydrogen (Natural Gas,liquid H2 truck) Hydrogen (Coal, pipeline) Electricity (production? Hydrogen Production Mix Natural Gas, pipeline,