National Library of Energy BETA

Sample records for greenhouse gas co2

  1. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO 2 concentration data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ogle, Stephen; Davis, Kenneth J.; Lauvaux, Thomas; Schuh, Andrew E.; Cooley, Dan; West, Tristram O.; Heath, L.; Miles, Natasha; Richardson, S. J.; Breidt, F. Jay; et al

    2015-03-10

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country’s contribution to GHG concentrations in the atmosphere. Verification could include a variety of evidence, but arguably the most convincing verification would be confirmation of a change in GHG concentrations in the atmosphere that is consistent with reported emissions to the UNFCCC. We report here on a case study evaluating this option based on a prototype atmospheric CO2 measurement network deployed in the Mid-Continent Region of themore » conterminous United States. We found that the atmospheric CO2 measurement data did verify the accuracy of the emissions inventory within the confidence limits of the emissions estimates, suggesting that this technology could be further developed and deployed more widely in the future for verifying reported emissions.« less

  2. Greenhouse Gas Source Attribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Source Attribution - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  3. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) Greenhouse Gas Emissions Overview Diagram Notes [a] CO2 emissions related to petroleum consumption (includes 64 MMTCO2 of non-fuel-related emissions). [b] CO2 emissions related to coal consumption (includes 0.3 MMTCO2 of non-fuel-related emissions). [c] CO2 emissions related to natural gas consumption (includes 13 MMTCO2 of

  4. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    1. Greenhouse Gas Emissions Overview 1.1 Total emissions Total U.S. anthropogenic (human-caused) greenhouse gas emissions in 2009 were 5.8 percent below the 2008 total (Table 1). The decline in total emissions-from 6,983 million metric tons carbon dioxide equivalent (MMTCO2e) in 2008 to 6,576 MMTCO2e in 2009-was the largest since emissions have been tracked over the 1990-2009 time frame. It was largely the result of a 419-MMTCO2e drop in carbon dioxide (CO2) emissions (7.1 percent). There was a

  5. Bioenergy Impacts … Greenhouse Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    researchers at Argonne National Laboratory developed the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model to develop non-food biofuels from agricultural residues, forestry trimmings, energy crops, and algae that have greater greenhouse gas reduction benefits compared to petroleum fuels. Greenhouse gas emission data is helping researchers develop more sustainable biofuels

  6. Optima: Low Greenhouse Gas Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OPTIMA: Low Greenhouse Gas Fuels Blake Simmons Bioenergy 2015 June 24, 2015 2 Defining and Developing New Fuels * Workflow - Survey what fuels are available today - Provide fuel...

  7. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energys National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of staining upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  8. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tech/NETL Research | Department of Energy Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia Tech/NETL Research Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia Tech/NETL Research October 20, 2015 - 8:14am Addthis Researchers from Virginia Tech are injecting CO2 into coal seams in three locations in Buchanan County, Va., as part of an NETL-sponsored CO2 storage research project associated with enhanced gas recovery. Researchers from Virginia Tech are

  9. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Office of Scientific and Technical Information (OSTI)

    Novel CO 2 Adsorbents for Capture of CO 2 from Flue Gas Extended Abstract # 2007-A-504-AWMA Daniel J. Fauth 1 , Thomas P. Filburn 2 , McMahan L. Gray 1 , Sheila W. Hedges 1 , James S. Hoffman 1 , and Henry W. Pennline 1 1 United States Department of Energy, National Energy Technology Laboratory, 626 Cochrans Mill Road, P.O. Box 10940, Pittsburgh, Pennsylvania 15236-0940 2 Department of Mechanical Engineering, 200 Bloomfield Avenue, University of Hartford, West Hartford, Connecticut 06117-1599

  10. Sandia Energy - Greenhouse Gas Source Attribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analyzer for measuring CO2, CH4, and H2O using cavity-ringdown spectrometry (Picarro)1; a gas analyzer for measuring CO2, H2O, and d13C-CO2 using cavity-ringdown spectrometry...

  11. Reversible Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Yonker, Clement R.; Rainbolt, James E.; Zheng, Feng

    2010-08-31

    Acid gas scrubbing technology is predominantly aqueous alkanolamine based. Of the acid gases, CO2, H2S and SO2 have been shown to be reversible, however there are serious disadvantages with corrosion and high regeneration costs. The primary scrubbing system composed of monoethanolamine is limited to 30% by weight because of the highly corrosive solution. This gravimetric limitation limits the CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the system. Furthermore the scrubbing system has a large energy penalty from pumping and heating the excess water required to dissolve the MEA bicarbonate salt. Considering the high specific heat of water (4 j/g-1K-1), low capacities and the high corrosion we set out to design a fully organic solvent that can chemically bind all acid gases i.e. CO2 as reversible alkylcarbonate ionic liquids or analogues thereof. Having a liquid acid gas carrier improves process economics because there is no need for excess solvent to pump and to heat. We have demonstrated illustrated in Figure 1, that CO2-binding organic liquids (CO2BOLs) have a high CO2 solubility paired with a much lower specific heat (<1.5 J/g-1K-1) than aqueous systems. CO2BOLs are a subsection of a larger class of materials known as Binding Organic Liquids (BOLs). Our BOLs have been shown to reversibly bind and release COS, CS2, and SO2, which we denote COSBOLS, CS2BOLs and SO2BOLs. Our BOLs are highly tunable and can be designed for post or pre-combustion gas capture. The design and testing of the next generation zwitterionic CO2BOLs and SO2BOLs are presented.

  12. Greenhouse Gas Reductions: SF6

    ScienceCinema (OSTI)

    Anderson, Diana

    2013-04-19

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas ? one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  13. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  14. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of an NETL-sponsored CO2 storage research project ... teamed with the National Energy Technology Laboratory ... of CO2 into a coalbed methane field in Buchanan County, ...

  15. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas

    Office of Environmental Management (EM)

    from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States This analysis calculates the life cycle greenhouse gas (GHG) emissions for regional coal and imported natural gas power in Europe and Asia. The primary research questions are as follows: *How does exported liquefied natural gas (LNG) from the U.S. compare

  16. Greenhouse Gas Technology Center | Open Energy Information

    Open Energy Info (EERE)

    Name: Greenhouse Gas Technology Center Place: North Carolina Zip: 27709 Product: North Carolina-based partnership focused on environmental technology verification. References:...

  17. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States On May 29, 2014, the Department of Energy's (DOE) Office of Fossil Energy announced the availability for public review and comment the report Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States (LCA GHG Report).

  18. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas

  19. Reduced Regeneration Energy CO2 Adsorbent | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Reduced Regeneration Energy CO2 Adsorbent

  20. Agriculture and Land Use National Greenhouse Gas Inventory Software...

    Open Energy Info (EERE)

    Agriculture and Land Use National Greenhouse Gas Inventory Software Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Agriculture and Land Use National Greenhouse Gas...

  1. IPCC Guidelines for National Greenhouse Gas Inventories | Open...

    Open Energy Info (EERE)

    Guidelines for National Greenhouse Gas Inventories Jump to: navigation, search Tool Summary Name: IPCC Guidelines for National Greenhouse Gas Inventories AgencyCompany...

  2. Ethiopia-National Greenhouse Gas Emissions Baseline Scenarios...

    Open Energy Info (EERE)

    National Greenhouse Gas Emissions Baseline Scenarios: Learning from Experiences in Developing Countries Jump to: navigation, search Name Ethiopia-National Greenhouse Gas Emissions...

  3. Managing the National Greenhouse Gas Inventory Process | Open...

    Open Energy Info (EERE)

    Managing the National Greenhouse Gas Inventory Process Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Managing the National Greenhouse Gas Inventory Process Agency...

  4. EIA Energy Efficiency-Energy Related Greenhouse Gas Emissions...

    U.S. Energy Information Administration (EIA) Indexed Site

    Related Greenhouse Gas Emissions Links Energy Related Greenhouse Gas Emissions Links Posted Date: May 2007 Page Last Modified: September 2010 EIA Links Disclaimer: These pages...

  5. Regional Greenhouse Gas Initiative Inc RGGI | Open Energy Information

    Open Energy Info (EERE)

    Greenhouse Gas Initiative Inc RGGI Jump to: navigation, search Name: Regional Greenhouse Gas Initiative, Inc (RGGI) Place: New York Zip: NY 10007 Sector: Services Product: New...

  6. Energy Information Administration--Energy and Greenhouse Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Efficiency > Energy and Greenhouse Gas Analysis Energy and Greenhouse Gas Analysis Posted Date: October 1999 Page Last Modified: August 2007 This section contains analysis covering...

  7. Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation...

    Open Energy Info (EERE)

    Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation Potential in Agriculture) Jump to: navigation, search Logo: Monitoring and Assessment of Greenhouse Gas...

  8. Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Greenhouse Gas Emissions: The Combined Potential of Hybrid Technology and Behavioral Adaptation Title Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas...

  9. Greenhouse gas mitigation options for Washington State

    SciTech Connect (OSTI)

    Garcia, N.

    1996-04-01

    President Clinton, in 1993, established a goal for the United States to return emissions of greenhouse gases to 1990 levels by the year 2000. One effort established to help meet this goal was a three part Environmental Protection Agency state grant program. Washington State completed part one of this program with the release of the 1990 greenhouse gas emissions inventory and 2010 projected inventory. This document completes part two by detailing alternative greenhouse gas mitigation options. In part three of the program EPA, working in partnership with the States, may help fund innovative greenhouse gas reduction strategies. The greenhouse gas control options analyzed in this report have a wide range of greenhouse gas reductions, costs, and implementation requirements. In order to select and implement a prudent mix of control strategies, policy makers need to have some notion of the potential change in climate, the consequences of that change and the uncertainties contained therein. By understanding the risks of climate change, policy makers can better balance the use of scarce public resources for concerns that are immediate and present against those that affect future generations. Therefore, prior to analyzing alternative greenhouse gas control measures, this report briefly describes the phenomenon and uncertainties of global climate change, and then projects the likely consequences for Washington state.

  10. NREL: Sustainable NREL - Greenhouse Gas Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Reduction A leader in federal greenhouse gas (GHG) management, NREL has conducted GHG inventories, developed reduction goals, and reported emissions since 2000. NREL was the first federal facility to become a partner in the Environmental Protection Agency's Climate Leaders program, and has played a critical support role in the development of federal guidelines for GHG accounting and reporting through DOE's Federal Energy Management Program. Carbon Neutrality NREL is committed to

  11. Bibliography of greenhouse-gas reduction strategies

    SciTech Connect (OSTI)

    Tompkins, M.M.; Mintz, M.M.

    1995-03-01

    A bibliography of greenhouse-gas reduction strategies has been compiled to assist the Climate change Action Plan Task Force in their consideration of strategies to reduce greenhouse-gas emissions from personal motor vehicles. The document contains a summary of the literature, including it major directions and implications; and annotated listing of 32 recent pertinent documents; and a listing of a larger group of related reports.

  12. Conversion of Waste CO2 and Shale Gas to High-Value Chemicals | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Conversion of Waste CO2 and Shale Gas to High-Value Chemicals Conversion of Waste CO2 and Shale Gas to High-Value Chemicals The project aims to develop, build, operate, and validate a laboratory-scale continuous process that converts waste CO2 from industrial sources from shale gas into commodity chemical intermediates. PDF icon Factsheet More Documents & Publications CX-010693: Categorical Exclusion Determination AMO PEER REVIEW, MAY 28-29, 2015 Waste Treatment and

  13. CO2 utilization and storage in shale gas reservoirs: Experimental results and economic impacts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schaef, Herbert T.; Davidson, Casie L.; Owen, Antionette Toni; Miller, Quin R. S.; Loring, John S.; Thompson, Christopher J.; Bacon, Diana H.; Glezakou, Vassiliki Alexandra; McGrail, B. Peter

    2014-12-31

    Natural gas is considered a cleaner and lower-emission fuel than coal, and its high abundance from advanced drilling techniques has positioned natural gas as a major alternative energy source for the U.S. However, each ton of CO2 emitted from any type of fossil fuel combustion will continue to increase global atmospheric concentrations. One unique approach to reducing anthropogenic CO2 emissions involves coupling CO2 based enhanced gas recovery (EGR) operations in depleted shale gas reservoirs with long-term CO2 storage operations. In this paper, we report unique findings about the interactions between important shale minerals and sorbing gases (CH4 and CO2) andmore » associated economic consequences. Where enhanced condensation of CO2 followed by desorption on clay surface is observed under supercritical conditions, a linear sorption profile emerges for CH4. Volumetric changes to montmorillonites occur during exposure to CO2. Theory-based simulations identify interactions with interlayer cations as energetically favorable for CO2 intercalation. Thus, experimental evidence suggests CH4 does not occupy the interlayer and has only the propensity for surface adsorption. Mixed CH4:CO2 gas systems, where CH4 concentrations prevail, indicate preferential CO2 sorption as determined by in situ infrared spectroscopy and X-ray diffraction techniques. Collectively, these laboratory studies combined with a cost-based economic analysis provide a basis for identifying favorable CO2-EOR opportunities in previously fractured shale gas reservoirs approaching final stages of primary gas production. Moreover, utilization of site-specific laboratory measurements in reservoir simulators provides insight into optimum injection strategies for maximizing CH4/CO2 exchange rates to obtain peak natural gas production.« less

  14. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  15. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    Contacts This report, Emissions of Greenhouse Gases in the United States 2009, was prepared under the general direction of John Conti, Assistant Administrator for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. General questions concerning the content of this report may be directed to the Office of Communications at 202/586-8800. Technical information concerning the content of the report may be obtained from Perry Lindstrom at 202/586-0934 (email,

  16. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris CO2 capture membrane was scaled up with MTRs commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Services Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  17. Greenhouse Gas Emissions and Fuel Use

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gas Emissions and Fuel Use within the Natural Gas Supply Chain - Sankey Diagram Methodology James Bradbury, Zachary Clement, and Adrian Down Office of Energy Policy and Systems Analysis U.S. Department of Energy July, 2015 2 Acknowledgements The authors are grateful for excellent technical reviews and other contributions provided by several individuals. Within the Department of Energy, input was provided by Judi Greenwald, Elke Hodson and Diana Bauer. External reviewers included the

  18. Federal Register Notice for Life Cycle Greenhouse Gas Perspective on

    Office of Environmental Management (EM)

    Exporting Liquefied Natural Gas from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Federal Register Notice for Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States The Office of Fossil Energy of the Department of Energy gives notice of the availability of the report Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

  19. Secretary of Energy Memorandum on DOE Greenhouse Gas Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    including strategies for: reducing greenhouse gas emissions; using water more efficiently; promoting pollution prevention and eliminating waste; constructing high performance ...

  20. Annual Greenhouse Gas and Sustainability Data Report | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Greenhouse Gas and Sustainability Data Report Annual Greenhouse Gas and Sustainability Data Report This Excel workbook (version 6-1) is a tool to use for comprehensive reporting of fiscal year 2015 for energy, costs, square footage, and associated operational data for calculating and reporting greenhouse gas data. This document is to be used by top-tier Federal departments and agencies. This Data Report collects agency-aggregated data necessary for calculating scope 1, 2, and 3 greenhouse gas

  1. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  2. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy myth versus facts about biofuels and greenhouse gas emissions. PDF icon Biofuels & Greenhouse Gas Emissions: Myths versus Facts More Documents & Publications Microsoft Word - 47C468D4-69BA-281F40.doc Biofuels & Greenhouse Gas Emissions: Myths versus Facts

  3. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy myths versus facts of ethanol and greenhouse gas emissions. PDF icon Biofuels & Greenhouse Gas Emissions: Myths versus Facts More Documents & Publications Biofuels & Greenhouse Gas Emissions: Myths versus Facts Microsoft Word - 47C468D4-69BA-281F40.doc

  4. SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 | Department

    Energy Savers [EERE]

    of Energy SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 File SUMMARY_GREENHOUSE_GAS_EMISSIONS_DATA_WORKSHEET_JANUARY_2015.xlsx More Documents & Publications Attachment C - Summary GHG Emissions Data FINAL Attachment C Summary GHG Emissions Data FINAL Full Service Leased Space Data Report

  5. Asia Least-Cost Greenhouse Gas Abatement Study | Open Energy...

    Open Energy Info (EERE)

    Gas Abatement Study Jump to: navigation, search Name Asia Least-Cost Greenhouse Gas Abatement Study (ALGAS) AgencyCompany Organization Global Environment Facility,...

  6. Navigating the Numbers: Greenhouse Gas Data and International...

    Open Energy Info (EERE)

    Gas Data and International Climate Policy1 Overview "This report examines greenhouse gas (GHG) emissions at the global, national, sectoral, and fuel levels and identifies...

  7. Insights into the structure of mixed CO2/CH4 in gas hydrates

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Chakoumakos, Bryan C; Keffer, David J.; Huq, Ashfia; Phelps, Tommy Joe

    2015-01-01

    The exchange of CO2 for CH4 in natural gas hydrates is an attractive approach to methane for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x 5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. High-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules that form the surrounding cages, and resulted in a reduction in the unit cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. These results provide important insights on the impact and mechanisms for exchanging CH4 and CO2.

  8. Greenhouse Gas Management Program Overview (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-11-01

    Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluorocarbons (PFCs), hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF{sub 6}). Human activities have caused a rapid increase in GHG concentrations. This rising level contributes to global climate change, which contributes to environmental and public health problems.

  9. Modelling the deployment of CO2 storage in U.S. gas-bearing shales

    SciTech Connect (OSTI)

    Davidson, Casie L.; Dahowski, Robert T.; Dooley, James J.; McGrail, B. Peter

    2014-10-23

    The proliferation of commercial development in U.S. gas-bearing shales helped to drive a twelve-fold increase in domestic gas production between 2000 and 2010, and the nations gas production rates continue to grow. While shales have long been regarded as a desirable caprock for CCS operations because of their low permeability and porosity, there is increasing interest in the feasibility of injecting CO2 into shales to enhance methane recovery and augment CO2 storage. Laboratory work published in recent years observes that shales with adsorbed methane appear to exhibit a stronger affinity for CO2 adsorption, offering the potential to drive additional CH4 recovery beyond primary production and perhaps the potential to store a larger volume of CO2 than the volume of methane displaced. Recent research by the authors on the revenues associated with CO2-enhanced gas recovery (CO2-EGR) in gas-bearing shales estimates that, based on a range of EGR response rates, the average revenue per ton of CO2 for projects managed over both EGR and subsequent storage-only phases could range from $0.50 to $18/tCO2. While perhaps not as profitable as EOR, for regions where lower-cost storage options may be limited, shales could represent another early opportunity storage option if proven feasible for reliable EGR and CO2 storage. Significant storage potential exists in gas shales, with theoretical CO2 storage resources estimated at approximately 30-50 GtCO2. However, an analysis of the comprehensive cost competitiveness of these various options is necessary to understand the degree to which they might meaningfully impact U.S. CCS deployment or costs. This preliminary analysis shows that the degree to which EGR-based CO2 storage could play a role in commercial-scale deployment is heavily dependent upon the offsetting revenues associated with incremental recovery; modeling the low revenue case resulted in only five shale-based projects, while under the high revenue case, shales accounted for as much as 20 percent of total U.S. storage in the first 20 years of deployment. Interestingly, even in this highest revenue case, there appear to be no negative-cost projects that would be profitable in a no-policy environment as modeled under the assumptions employed. While this reflects a very first look at the potential for shales, it is clear that more laboratory and experimental work are needed to reduce uncertainty in key variables and begin to differentiate and identify high-potential shales for early pilot study.

  10. Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels and Chemicals | Department of Energy conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Suresh Babu, Senior Program Manager, Biomass Program Development, Brookhaven National Laboratory PDF icon b13_babu_1-d.pdf More Documents & Publications GBTL

  11. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Natural Gas System; Sankey Diagram Methodology Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology As natural gas travels through ...

  12. Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use

    SciTech Connect (OSTI)

    Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

    2012-07-31

    field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

  13. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    SciTech Connect (OSTI)

    Zoback, Mark; Kovscek, Anthony; Wilcox, Jennifer

    2013-09-30

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  14. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-08-15

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and not only by PV during sunny on-peak hours.

  15. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH

    Office of Scientific and Technical Information (OSTI)

    DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012 (Conference) | SciTech Connect GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012 Citation Details In-Document Search Title: GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012 Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions

  16. Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks

    Energy Savers [EERE]

    Public Comment | Department of Energy Greenhouse Gas Reporting Guidance, Seeks Public Comment Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks Public Comment March 22, 2005 - 10:54am Addthis Program Will Ensure Greater Accuracy & Completeness WASHINGTON, D.C. - The U.S. Department of Energy (DOE) today asked for further public comment on its revised guidelines for voluntary reporting of greenhouse gas emissions, sequestration and emission reductions. The program

  17. OPTIMA: Low Greenhouse Gas Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OPTIMA: Low Greenhouse Gas Fuels OPTIMA: Low Greenhouse Gas Fuels Plenary IV: Fuels of the Future: Accelerating the Co-Optimization of Fuels and Engines OPTIMA: Low Greenhouse Gas Fuels Blake Simmons, Biofuels Program Lead, Sandia National Laboratories PDF icon simmons_bioenergy_2015.pdf More Documents & Publications Optima: Co-Optimization of Fuels and Engines Optima Stakeholder Listening Day Agenda Optima Program Overview

  18. DOE Technical Assistance on Greenhouse Gas Reduction Strategies in the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electric Power Sector | Department of Energy DOE Technical Assistance on Greenhouse Gas Reduction Strategies in the Electric Power Sector DOE Technical Assistance on Greenhouse Gas Reduction Strategies in the Electric Power Sector The U.S. Department of Energy (DOE) will continue to offer analysis and technical support for state, local, tribal and regional planning efforts related to reducing greenhouse gas emissions in the electric power sector. DOE is ready to support state, local, and

  19. Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Employer-Subsidized Commuting Options | Department of Energy 9: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options Fact #879: June 29, 2015 Greenhouse Gas Abatement Costs for Employer-Subsidized Commuting Options Providing workplace charging is one of the more effective ways for businesses to reduce the greenhouse gas emissions of their employees' daily commute. Offering a bike purchase subsidy can be even more cost effective but may not be suitable for

  20. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and

    Energy Savers [EERE]

    Climate Change in NEPA Reviews | Department of Energy Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews On December 18, 2014, CEQ released revised draft guidance for public comment that describes how Federal departments and agencies should consider the effects of greenhouse gas emissions and climate change in their National Environmental Policy

  1. CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas

    Energy Savers [EERE]

    Emissions and the Effects of Climate Change in NEPA Reviews | Department of Energy Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews December 22, 2014 - 12:59pm Addthis The Council on Environmental Quality (CEQ) issued revised draft guidance on consideration of greenhouse gas (GHG) emissions and the effects of

  2. Greenhouse Gas Emissions Reduction Benefits of Workplace Charging |

    Office of Environmental Management (EM)

    Department of Energy Greenhouse Gas Emissions Reduction Benefits of Workplace Charging Greenhouse Gas Emissions Reduction Benefits of Workplace Charging Reducing greenhouse gas emissions (GHG) from employees' commutes, also known as Scope 3 emissions, is a top priority for many organizations interested in minimizing their carbon footprint. Scope 3 emissions are indirect GHG emissions from sources not owned or directly controlled by the organization but are related to their activities,

  3. Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation...

    Open Energy Info (EERE)

    the MAGHG project is to support developing countries assess and report their greenhouse gas (GHG) emissions from agriculture, including assessment of mitigation options for...

  4. NETL - Petroleum-Based Fuels Life Cycle Greenhouse Gas Analysis...

    Open Energy Info (EERE)

    search Tool Summary LAUNCH TOOL Name: NETL - Petroleum-Based Fuels Life Cycle Greenhouse Gas Analysis 2005 Baseline Model AgencyCompany Organization: National Energy Technology...

  5. Verifying Greenhouse Gas Emissions: Methods to Support International...

    Open Energy Info (EERE)

    Climate Agreements Jump to: navigation, search Tool Summary Name: Verifying Greenhouse Gas Emissions: Methods to Support International Climate Agreements AgencyCompany...

  6. Greenhouse Gas Emission Trends and Projections in Europe 2009...

    Open Energy Info (EERE)

    Liechtenstein, Poland and Turkey provided updated information on emission projections and national programmes in 2009." References "Greenhouse Gas Emission Trends and...

  7. #AskBerkeleyLab: Jeff Greenblatt Talks Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Greenblatt, Jeff

    2015-02-02

    We received questions from our social media audience around California's goal to dramatically reduce its greenhouse gas emissions by 2030. Berkeley Lab scientist Jeff Greenblatt answers them here.

  8. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Climate Change in NEPA Reviews Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews On December 18, 2014, CEQ released ...

  9. Greenhouse Gas Services AES GE EFS | Open Energy Information

    Open Energy Info (EERE)

    Services (AESGE EFS) Place: Arlington, Virginia Zip: 22203-4168 Product: Develop and invest in a range of projects that reduce greenhouse gas emissions that produce verified GHG...

  10. The Greenhouse Gas Protocol Initiative: Measurement and Estimation...

    Open Energy Info (EERE)

    GHG Emissions AgencyCompany Organization: World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Greenhouse Gas Phase:...

  11. Greenhouse Gas Emissions from Aviation and Marine Transportation...

    Open Energy Info (EERE)

    and Policies Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potentials and Policies...

  12. GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy...

    Open Energy Info (EERE)

    a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential...

  13. The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (carbon dioxide, methane, nitrous oxide, and carbon dioxide equivalent) for each facility as well as total...

  14. The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (including carbon dioxide, methane, nitrous oxide, carbon dioxide equivalent, and biogenic carbon dioxide) for each...

  15. DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of new and advanced technologies that avoid, reduce, or capture and store greenhouse gas emissions - the technology component of a comprehensive U.S. approach to climate change. ...

  16. Greenhouse Gas Initiative Scenario Database | Open Energy Information

    Open Energy Info (EERE)

    TOOL Name: Greenhouse Gas Initiative Scenario Database AgencyCompany Organization: Science for Global Insight Sector: Climate, Energy, Land Topics: Baseline projection, GHG...

  17. PPPL Celebrates Earth Day with Reduction in Greenhouse Gas Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PPPL Celebrates Earth Day with Reduction in Greenhouse Gas Emissions By Patti Wieser April 25, 2011 Tweet Widget Google Plus One Share on Facebook PPPL's Tim Stevenson takes...

  18. The Greenhouse Gas Protocol Initiative: Sector Specific Tools...

    Open Energy Info (EERE)

    World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Industry, Greenhouse Gas Phase: Determine Baseline, Evaluate...

  19. Greenhouse Gas Training Program for Inventory and Mitigation...

    Open Energy Info (EERE)

    divisionsfuture-perfect Country: South Korea Eastern Asia Language: English References: Greenhouse Gas Training Program for Inventory and Mitigation Modeling1...

  20. The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary...

    Open Energy Info (EERE)

    Interface: Spreadsheet Website: www.ghgprotocol.orgcalculation-toolsall-tools Cost: Free References: Stationary Combustion Guidance1 The Greenhouse Gas Protocol tool for...

  1. The Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigerati...

    Open Energy Info (EERE)

    Interface: Spreadsheet Website: www.ghgprotocol.orgcalculation-toolsall-tools Cost: Free References: Refrigerant Guide1 The Greenhouse Gas Protocol tool for refrigeration is...

  2. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    SciTech Connect (OSTI)

    Greenblatt, Jeffery B.

    2013-10-10

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants, targets were less well-defined, but while all three scenarios were able to make significant reductions in ROG, NOx and PM2.5 both statewide and in the two regional air basins, they may nonetheless fall short of what will be required by future federal standards. Specifically, in Scenario 1, regional NOx emissions are approximately three times the estimated targets for both 2023 and 2032, and in Scenarios 2 and 3, NOx emissions are approximately twice the estimated targets. Further work is required in this area, including detailed regional air quality modeling, in order to determine likely pathways for attaining these stringent targets.

  3. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2014-06-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

  4. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Reductions - Case Study, 2013 | Department of Energy Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study, 2013 Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study, 2013 BroadRock Renewables LLC, in collaboration with DCO Energy, operates combined cycle electric generating plants at the Central Landfill in Johnston, Rhode Island, and Olinda Alpha Landfill in Brea, California. The Rhode

  5. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  6. CO2 Sequestration short course

    SciTech Connect (OSTI)

    DePaolo, Donald J.; Cole, David R; Navrotsky, Alexandra; Bourg, Ian C

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  7. Flue Gas Perification Utilizing SOx/NOx Reactions During Compression of CO2 Derived from Oxyfuel Combustion

    SciTech Connect (OSTI)

    Kevin Fogash

    2010-09-30

    The United States wishes to decrease foreign energy dependence by utilizing the countrys significant coal reserves, while stemming the effects of global warming from greenhouse gases. In response to these needs, Air Products has developed a patented process for the compression and purification of the CO2 stream from oxyfuel combustion of pulverized coal. The purpose of this project was the development and performance of a comprehensive experimental and engineering evaluation to determine the feasibility of purifying CO2 derived from the flue gas generated in a tangentially fired coal combustion unit operated in the oxy-combustion mode. Following the design and construction of a 15 bar reactor system, Air Products conducted two test campaigns using the slip stream from the tangentially fired oxy-coal combustion unit. During the first test campaign, Air Products evaluated the reactor performance based on both the liquid and gaseous reactor effluents. The data obtained from the test run has enabled Air Products to determine the reaction and mass transfer rates, as well as the effectiveness of the reactor system. During the second test campaign, Air Products evaluated reactor performance based on effluents for different reactor pressures, as well as water recycle rates. Analysis of the reaction equations indicates that both pressure and water flow rate affect the process reaction rates, as well as the overall reactor performance.

  8. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  9. EIA - Greenhouse Gas Emissions - Land use

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Additionally, the CO2 released from biofuel or bioenergy combustion is assumed to be fully ... There has been gradual growth of biofuel consumption in the commercial sector. Industrial ...

  10. Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  11. Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnershipmore » Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.« less

  12. Evaluating Impacts of CO2 Gas Intrusion Into a Confined Sandstone aquifer: Experimental Results

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

    2014-12-31

    Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

  13. Selective CO2 Capture from Flue Gas Using Metal-Organic Frameworks?A Fixed Bed Study

    SciTech Connect (OSTI)

    Liu, Jian; Tian, Jian; Thallapally, Praveen K.; McGrail, B. Peter

    2012-05-03

    It is important to capture carbon dioxide from flue gas which is considered to be the main reason to cause global warming. CO2/N2 separation by novel adsorbents is a promising method to reduce CO2 emission but effect of water and CO2/N2 selectivity is critical to apply the adsorbents into practical applications. A very well known, Metal Organic Framework, NiDOBDC (Ni-MOF-74 or CPO-27-Ni) was synthesized through a solvothermal reaction and the sample (500 to 800 microns) was used in a fixed bed CO2/N2 breakthrough study with and without H2O. The Ni/DOBDC pellet has a high CO2 capacity of 3.74 mol/kg at 0.15 bar and a high CO2/N2 selectivity of 38, which is much higher than those of reported MOFs and zeolites under dry condition. Trace amount of water can impact CO2 adsorption capacity as well as CO2/N2 selectivity for the Ni/DOBDC. However, Ni/DOBDC can retain a significant CO2 capacity and CO2/N2 selectivity at 0.15 bar CO2 with 3% RH water. These results indicate a promising future to use the Ni/DOBDC in CO2 capture from flue gas.

  14. Greenhouse Gas Reductions: SF6 | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Reductions: SF6 Share Description Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas - one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6

  15. Estonian greenhouse gas emissions inventory report

    SciTech Connect (OSTI)

    Punning, J.M.; Ilomets, M.; Karindi, A.; Mandre, M.; Reisner, V.; Martins, A.; Pesur, A.; Roostalu, H.; Tullus, H.

    1996-07-01

    It is widely accepted that the increase of greenhouse gas concentrations in the atmosphere due to human activities would result in warming of the Earth`s surface. To examine this effect and better understand how the GHG increase in the atmosphere might change the climate in the future, how ecosystems and societies in different regions of the World should adapt to these changes, what must policymakers do for the mitigation of that effect, the worldwide project within the Framework Convention on Climate Change was generated by the initiative of United Nations. Estonia is one of more than 150 countries, which signed the Framework Convention on Climate Change at the United Nations Conference on Environment and Development held in Rio de Janeiro in June 1992. In 1994 a new project, Estonian Country Study was initiated within the US Country Studies Program. The project will help to compile the GHG inventory for Estonia, find contemporary trends to investigate the impact of climate change on the Estonian ecosystems and economy and to formulate national strategies for Estonia addressing to global climate change.

  16. EIA - Greenhouse Gas Emissions - Table-Figure Notes and Sources

    Gasoline and Diesel Fuel Update (EIA)

    A1. Notes and Sources Tables Chapter 1: Greenhouse gas emissions overview Table 1. U.S. emissions of greenhouse gases, based on global warming potential, 1990-2009: Sources: Emissions: EIA estimates. Data in this table are revised from the data contained in the previous EIA report, Emissions of Greenhouse Gases in the United States 2008, DOE/EIA-0573(2008) (Washington, DC, December 2009). Global warming potentials: Intergovernmental Panel on Climate Change, Climate Change 2007: The Physical

  17. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis...

    Office of Environmental Management (EM)

    Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumbenergyuselossemissionslg.gif How...

  18. Idaho National Laboratory’s FY14 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Frerichs, Kimberly Irene

    2015-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2014 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions. INL’s GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL’s organizational boundaries, but are a consequence of INL’s activities). This inventory found that INL generated 73,521 metric tons (MT) of CO2 equivalent (CO2e ) emissions during FY14. The following conclusions were made from looking at the results of the individual contributors to INL’s FY14 GHG inventory: • Electricity (including the associated transmission and distribution losses) is the largest contributor to INL’s GHG inventory, with over 50% of the CO2e emissions • Other sources with high emissions were stationary combustion (facility fuels), employee commuting, mobile combustion (fleet fuels), business air travel, and waste disposal (including fugitive emissions from the onsite landfill and contracted disposal) • Sources with low emissions were wastewater treatment (onsite and contracted), business ground travel (in personal and rental vehicles), and fugitive emissions from refrigerants. This report details the methods behind quantifying INL’s GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only the large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  19. Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Devenney, Martin; Gilliam, Ryan; Seeker, Randy

    2013-08-01

    The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

  20. Interagency Pilot of Greenhouse Gas Accounting Tools: Lessons Learned

    SciTech Connect (OSTI)

    Carpenter, A.; Hotchkiss, E.; Kandt, A.

    2013-02-01

    The Greater Yellowstone Area (GYA) and Tongass National Forest (Tongass) partnered with the National Renewable Energy Laboratory (NREL) to conduct a pilot study of three greenhouse gas (GHG) inventorying tools.

  1. DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas Emissions

    Energy Savers [EERE]

    through Deployment of Advanced Technology | Department of Energy Draft Strategic Plan for Reducing Greenhouse Gas Emissions through Deployment of Advanced Technology DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas Emissions through Deployment of Advanced Technology September 22, 2005 - 10:45am Addthis WASHINGTON, DC - The Department of Energy today released for public review and comment a plan for accelerating the development and reducing the cost of new and advanced

  2. Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Energy Lab Sets Aggressive Greenhouse Gas Reduction Goal NREL pledges to cut carbon footprint, impact on environment by 75 percent December 4, 2007 The U.S. Department of Energy's National Renewable Energy Laboratory (NREL) has pledged to reduce its greenhouse gas emissions by 75 percent from 2005 to 2009. The new goal is part of NREL's participation in the Environmental Protection Agency's (EPA) Climate Leaders program and was announced at the Climate Leaders meeting in Boulder, Colo.,

  3. FETC Programs for Reducing Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Ruether, J.A.

    1998-02-01

    Mark Twain once quipped that everyone talks about the weather but no one does anything about it. With interest in global climate change on the rise, researchers in the fossil-energy sector are feeling the heat to provide new technology to permit continued use of fossil fuels but with reduced emissions of so-called `greenhouse gases.` Three important greenhouse gases, carbon dioxide, methane, and nitrous oxide, are released to the atmosphere in the course of recovering and combusting fossil fuels. Their importance for trapping radiation, called forcing, is in the order given. In this report, we briefly review how greenhouse gases cause forcing and why this has a warming effect on the Earth`s atmosphere. Then we discuss programs underway at FETC that are aimed at reducing emissions of methane and carbon dioxide.

  4. Mitigating Greenhouse Gas Emissions: Voluntary Reporting 1996

    Reports and Publications (EIA)

    1997-01-01

    Presents information on voluntary actions to reduce greenhouse gases or remove such gases from the atmosphere in 1995. It provides an overview of participation in the Voluntary Reporting Program, a perspective on the composition of activities reported, and a review of some key issues in interpreting and evaluating achievements associated with reported emissions mitigation initiatives.

  5. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions. These technology pathways (which are described in greater detail in Appendix B, Technology Pathways) address three areas: energy efficiency, clean energy, and carbon sequestration (removing carbon from emissions and enhancing carbon storage). Based on an assessment of each of these technology pathways over a 30-year planning horizon, the directors of the Department of Energy's (DOE's) national laboratories conclude that success will require pursuit of multiple technology pathways to provide choices and flexibility for reducing greenhouse gas emissions. Advances in science and technology are necessary to reduce greenhouse gas emissions from the United States while sustaining economic growth and providing collateral benefits to the nation.

  6. Natural Gas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of injecting captured carbon dioxide (CO2) into organic-rich rocks, deep underground, to permanently store the greenhouse gas while simultaneously recovering natural gas. ...

  7. Low-Energy CO2 Capture through Cooperative Adsorption | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Low-Energy CO2 Capture through Cooperative Adsorption

  8. Enhanced CO2 Capture in Metal-Organic Frameworks | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Enhanced CO2 Capture in Metal-Organic Frameworks

  9. Stimulus CO2 adsorption in Metal-Organic Frameworks | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Stimulus CO2 adsorption in Metal-Organic Frameworks

  10. Greenhouse gas emissions from landfill leachate treatment plants: A

    Office of Scientific and Technical Information (OSTI)

    comparison of young and aged landfill (Journal Article) | SciTech Connect Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill Citation Details In-Document Search Title: Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill Highlights: * Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup -1}. * Fresh leachate owned extremely low ORP and high organic

  11. Pre-Designed Single-Molecule Traps for CO2 Capture | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Pre-Designed Single-Molecule Traps for CO2 Capture

  12. Highly Stable Porphyrinic Zr-MOFs for CO2 Fixation | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Highly Stable Porphyrinic Zr-MOFs for CO2 Fixation

  13. Understanding CO2 dynamics inside open-metal sites MOFs | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Understanding CO2 dynamics inside open-metal sites MOFs

  14. Idaho National Laboratorys Greenhouse Gas FY08 Baseline

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2011-06-01

    A greenhouse gas (GHG) inventory is a systematic attempt to account for the production and release of certain gasses generated by an institution from various emission sources. The gasses of interest are those which have become identified by climate science as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2008 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. Concern about the environmental impact of GHGs has grown in recent years. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of a baseline estimate of total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions in the future, and such documentation will require knowledge of a baseline against which reductions can be measured. INL's FY08 GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three Scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL's organizational boundaries but are a consequence of INL's activities). This inventory found that INL generated a total of 113,049 MT of CO2-equivalent emissions during FY08. The following conclusions were made from looking at the results of the individual contributors to INL's baseline GHG inventory: (1) Electricity (including the associated transmission and distribution losses) is the largest contributor to INL's GHG inventory, with over 50% of the CO2e emissions; (2) Other sources with high emissions were stationary combustion (facility fuels), waste disposal (including fugitive emissions from the onsite landfill and contracted disposal), mobile combustion (fleet fuels), employee commuting, and business air travel; and (3) Sources with low emissions were wastewater treatment (onsite and contracted), fugitive emissions from refrigerants, and business ground travel (in personal and rental vehicles). This report details the methods behind quantifying INL's GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by the Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only that large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  15. Idaho National Laboratorys Greenhouse Gas FY08 Baseline

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2010-09-01

    A greenhouse gas (GHG) inventory is a systematic attempt to account for the production and release of certain gasses generated by an institution from various emission sources. The gasses of interest are those which have become identified by climate science as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2008 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. Concern about the environmental impact of GHGs has grown in recent years. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of a baseline estimate of total GHGs generated at the INL. Additionally, the INL has a desire to see how its emissions compare with similar institutions, including other DOE-sponsored national laboratories. Executive Order 13514 requires that federally-sponsored agencies and institutions document reductions in GHG emissions in the future, and such documentation will require knowledge of a baseline against which reductions can be measured. INLs FY08 GHG inventory was calculated according to methodologies identified in Federal recommendations and an as-yet-unpublished Technical and Support Document (TSD) using operational control boundary. It measures emissions generated in three Scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INLs organizational boundaries but are a consequence of INLs activities). This inventory found that INL generated a total of 114,256 MT of CO2-equivalent emissions during fiscal year 2008 (FY08). The following conclusions were made from looking at the results of the individual contributors to INLs baseline GHG inventory: Electricity is the largest contributor to INLs GHG inventory, with over 50% of the net anthropogenic CO2e emissions Other sources with high emissions were stationary combustion, fugitive emissions from the onsite landfill, mobile combustion (fleet fuels) and the employee commute Sources with low emissions were contracted waste disposal, wastewater treatment (onsite and contracted) and fugitive emissions from refrigerants. This report details the methods behind quantifying INLs GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to stress that the methodology behind this inventory followed guidelines that have not yet been formally adopted. Thus, some modification of the conclusions may be necessary as additional guidance is received. Further, because this report differentiates between those portions of the INL that are managed and operated by the Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only that large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  16. EIA - Greenhouse Gas Emissions - High-GWP gases

    Gasoline and Diesel Fuel Update (EIA)

    5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA

  17. Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products: Implications for U.S. Petroleum Fuels Title Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands...

  18. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels ... More Documents & Publications Well-to-Wheels Analysis of Energy Use and Greenhouse Gas ...

  19. Observation of CH4 and other Non-CO2 Green House Gas Emissions from California

    SciTech Connect (OSTI)

    Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

    2009-01-09

    In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

  20. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumb_energyuse_loss_emissions_lg.gif How effectively is energy used in U.S. manufacturing? How much greenhouse gas (GHG) is emitted from combustion in manufacturing operations? The U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis from the Oak Ridge National Laboratory traces energy from supply (fuel, electricity, and

  1. Fact #608: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 8: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990 Fact #608: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990 In October of 2009, the United Nations (UN) released greenhouse gas inventory data for 1990 to 2007 for all countries that submitted data in accordance with the UN Framework Convention on Climate Change (UNFCCC). Between 1990 and 2007, total aggregate greenhouse gas (GHG) emissions for all reporting countries declined by 3.9%

  2. U.S. Greenhouse Gas Intensity and the Global Climate Change Initiative (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    On February 14, 2002, President Bush announced the Administrations Global Climate Change Initiative. A key goal of the Climate Change Initiative is to reduce U.S. greenhouse gas intensity by 18% over the 2002 to 2012 time frame. For the purposes of the initiative, greenhouse gas intensity is defined as the ratio of total U.S. greenhouse gas emissions to economic output.

  3. Microsoft Word - NETL-TRS-4-2014_CO2 Storage and Enhanced Gas Recovery_20140924.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation of CO 2 Storage and Enhanced Gas Recovery in Depleted Shale Gas Formations Using a Dual- Porosity/Dual-Permeability, Multiphase Reservoir Simulator 25 September 2014 Office of Fossil Energy NETL-TRS-4-2014 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or

  4. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  5. EIA-Voluntary Reporting of Greenhouse Gases Program - Greenhouse Gases and

    Gasoline and Diesel Fuel Update (EIA)

    Global lWarming Potentials (GWP) Greenhouse Gases and Global Warming Potentials (GWP) Voluntary Reporting of Greenhouse Gases Program Greenhouse Gases and Global Warming Potentials (GWP) (From Appendix E of the instructions to Form EIA-1605) GREENHOUSE GAS NAME GREENHOUSE GAS CODE FORMULA GWP TAR1 AR42 (1) Carbon Dioxide CO2 CO2 1 1 (2) Methane CH4 CH4 23 25 (3) Nitrous Oxide N2O N2O 296 298 (4) Hydroflourocarbons HFC-23 (trifluoromethane) 15 CHF3 12000 14800 HFC-32 (difluoromethane) 16

  6. Using Coupled Harmonic Oscillators to Model Some Greenhouse Gas Molecules

    SciTech Connect (OSTI)

    Go, Clark Kendrick C.; Maquiling, Joel T.

    2010-07-28

    Common greenhouse gas molecules SF{sub 6}, NO{sub 2}, CH{sub 4}, and CO{sub 2} are modeled as harmonic oscillators whose potential and kinetic energies are derived. Using the Euler-Lagrange equation, their equations of motion are derived and their phase portraits are plotted. The authors use these data to attempt to explain the lifespan of these gases in the atmosphere.

  7. Idaho National Laboratory's FY11 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2012-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2011 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho.

  8. Idaho National Laboratory FY12 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2013-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2012 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho.

  9. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Marnay, Chris; Stadler, Michael; Lipman, Tim; Lai, Judy; Cardoso, Goncalo; Megel, Olivier

    2009-09-01

    The motivation and objective of this research is to determine the role of distributed generation (DG) in greenhouse gas reductions by: (1) applying the Distributed Energy Resources Customer Adoption Model (DER-CAM); (2) using the California Commercial End-Use Survey (CEUS) database for commercial buildings; (3) selecting buildings with electric peak loads between 100 kW and 5 MW; (4) considering fuel cells, micro-turbines, internal combustion engines, gas turbines with waste heat utilization, solar thermal, and PV; (5) testing of different policy instruments, e.g. feed-in tariff or investment subsidies.

  10. Kalman-filtered compressive sensing for high resolution estimation of anthropogenic greenhouse gas emissions from sparse measurements.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-09-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. The limited nature of the measured data leads to a severely-underdetermined estimation problem. If the estimation is performed at fine spatial resolutions, it can also be computationally expensive. In order to enable such estimations, advances are needed in the spatial representation of ffCO2 emissions, scalable inversion algorithms and the identification of observables to measure. To that end, we investigate parsimonious spatial parameterizations of ffCO2 emissions which can be used in atmospheric inversions. We devise and test three random field models, based on wavelets, Gaussian kernels and covariance structures derived from easily-observed proxies of human activity. In doing so, we constructed a novel inversion algorithm, based on compressive sensing and sparse reconstruction, to perform the estimation. We also address scalable ensemble Kalman filters as an inversion mechanism and quantify the impact of Gaussian assumptions inherent in them. We find that the assumption does not impact the estimates of mean ffCO2 source strengths appreciably, but a comparison with Markov chain Monte Carlo estimates show significant differences in the variance of the source strengths. Finally, we study if the very different spatial natures of biogenic and ffCO2 emissions can be used to estimate them, in a disaggregated fashion, solely from CO2 concentration measurements, without extra information from products of incomplete combustion e.g., CO. We find that this is possible during the winter months, though the errors can be as large as 50%.

  11. CO2-Binding Organic Liquids, an Integrated Acid Gas Capture System

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.; Zheng, Feng

    2011-04-01

    Amine systems are effective for CO2 capture, but they are still inefficient because the solvent regeneration energy is largely defined by the amount of water in the process. Most amines form heat-stable salts with SO2 and COS resulting in parasitic solvent loss and degradation. Stripping the CO2-rich solvent is energy intensive it requires temperatures above 100 ?C due to the high specific heat and heat of vaporization of water. CO2-capture processes could be much more energy efficient in a water free amine process. In addition, if the capture-material is chemically compatible with other acid gases, less solvent would be lost to heat-stable salts and the process economics would be further improved. One such system that can address these concerns is Binding Organic Liquids (BOLs), a class of switchable ionic liquids.

  12. Evaluating Impacts of CO2 and CH4 Gas Intrusion into an Unconsolidated Aquifer: Fate of As and Cd

    SciTech Connect (OSTI)

    Lawter, Amanda R.; Qafoku, Nikolla; Shao, Hongbo; Bacon, Diana H.; Brown, Christopher F.

    2015-07-10

    Abstract The sequestration of carbon dioxide (CO2) in deep underground reservoirs has been identified as an important strategy to decrease atmospheric CO2 levels and mitigate global warming, but potential risks on overlying aquifers currently lack a complete evaluation. In addition to CO2, other gases such as methane (CH4) may be present in storage reservoirs. This paper explores for the first time the combined effect of leaking CO2 and CH4 gasses on the fate of major, minor and trace elements in an aquifer overlying a potential sequestration site. Emphasis is placed on the fate of arsenic (As) and cadmium (Cd) released from the sediments or present as soluble constituents in the leaking brine. Results from macroscopic batch and column experiments show that the presence of CH4 (at a concentration of 1 % in the mixture CO2/CH4) does not have a significant effect on solution pH or the concentrations of most major elements (such as Ca, Ba, and Mg). However, the concentrations of Mn, Mo, Si and Na are inconsistently affected by the presence of CH4 (i.e., in at least one sediment tested in this study). Cd is not released from the sediments and spiked Cd is mostly removed from the aqueous phase most likely via adsorption. The fate of sediment associated As [mainly sorbed arsenite or As(III) in minerals] and spiked As [i.e., As5+] is complex. Possible mechanisms that control the As behavior in this system are discussed in this paper. Results are significant for CO2 sequestration risk evaluation and site selection and demonstrate the importance of evaluating reservoir brine and gas stream composition during site selection to ensure the safest site is being chosen.

  13. NETL CO2 Storage Frequently Asked Questions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Storage Frequently Asked Questions faq-header-big.jpg A combined portfolio of carbon management options for fossil fuel use can be implemented to manage current emission levels of greenhouse gases (GHGs) while enhancing energy security and building the technologies and knowledge base for export to other countries faced with reducing emissions. The U.S. portfolio includes Use of fuels with reduced carbon intensity: renewables, nuclear, and natural gas. Adoption of more efficient technologies

  14. ARM - Measurement - Carbon dioxide (CO2) concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Carbon dioxide (CO2) concentration The amount of carbon dioxide, a heavy, colorless greenhouse gas, per unit of volume. Categories Atmospheric Carbon Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  15. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology

    Broader source: Energy.gov [DOE]

    As natural gas travels through infrastructure, from well-head to customer meter, small portions are routinely used as fuel, vented, flared, or inadvertently leaked to the atmosphere. This paper describes the analytical and methodological basis for three diagrams that illustrate the natural gas losses and greenhouse gas emissions that result from these processes. The paper examines these emissions in some detail, focusing in particular on the production, processing, transmission and storage, and distribution segments of natural gas infrastructure.

  16. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Not Available

    1997-10-01

    This report serves as the technology basis of a needed national climate change technology strategy, with the confidence that a strong technology R&D program will deliver a portfolio of technologies with the potential to provide very substantial greenhouse gas emission reductions along with continued economic growth. Much more is needed to define such a strategy, including identification of complementary deployment policies and analysis to support the seeping and prioritization of R&D programs. A national strategy must be based upon governmental, industrial, and academic partnerships.

  17. Conversion of Waste CO2 & Shale Gas to High Value Chemicals

    Broader source: Energy.gov (indexed) [DOE]

    Sadesh Sookraj, EVP Chemicals, Novomer (Presenter) U.S. DOE Advanced Manufacturing Office Program Review Meeting Washington, D.C. May 28-29, 2015 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective  Overall Objective - To develop, build, and validate a semi- integrated laboratory scaled continuous process with capacity of 5kg/day to make CO2-based drop-in chemicals.  Achieve industry leading cost for Acrylic Acid,

  18. Conversion of Waste CO2 and Shale Gas to High Value Chemicals

    Office of Environmental Management (EM)

    Scott Allen, Novomer U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective  Novomer is developing a new route to Acrylic Acid and Acrylates using proprietary catalysts and processing  The Novomer route will use ethylene as the feedstock instead of propylene and will use Praxair's CO2 to CO technology  Using Ethylene and CO as

  19. Meta-Analysis of Estimates of Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power: Preprint

    SciTech Connect (OSTI)

    Heath, G. A.; Burkhardt, J. J.

    2011-09-01

    In reviewing life cycle assessment (LCA) literature of utility-scale CSP systems, this analysis focuses on clarifying central tendency and reducing variability in estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emission estimates passing screens for quality and relevance: 19 for parabolic trough technology and 17 for power tower technology. The interquartile range (IQR) of published GHG emission estimates was 83 and 20 g CO2eq/kWh for trough and tower, respectively, with medians of 26 and 38 g CO2eq/kWh. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. Compared to the published estimates, IQR was reduced by 69% and median increased by 76% for troughs. IQR was reduced by 26% for towers, and median was reduced by 34%. A second level of harmonization was applied to five well-documented trough LC GHG emission estimates, harmonizing to consistent values for GHG emissions embodied in materials and from construction activities. As a result, their median was further reduced by 5%, while the range increased by 6%. In sum, harmonization clarified previous results.

  20. Evaluating greenhouse gas emissions from hydropower complexes on large rivers in Eastern Washington

    SciTech Connect (OSTI)

    Arntzen, Evan V.; Miller, Benjamin L.; O'Toole, Amanda C.; Niehus, Sara E.; Richmond, Marshall C.

    2013-03-15

    Water bodies, such as freshwater lakes, are known to be net emitters of carbon dioxide (CO2), and methane (CH4). In recent years, significant greenhouse gas (GHG) emissions from tropical, boreal, and mid-latitude reservoirs have been reported. At a time when hydropower is increasing worldwide, better understanding of seasonal and regional variation in GHG emissions is needed in order to develop a predictive understanding of such fluxes within man-made impoundments. We examined power-producing dam complexes within xeric temperate locations in the northwestern United States. Sampling environments on the Snake (Lower Monumental Dam Complex) and Columbia Rivers (Priest Rapids Dam Complex) included tributary, mainstem, embayment, forebay, and tailrace areas during winter and summer 2012. At each sampling location, GHG measurement pathways included surface gas flux, degassing as water passed through dams during power generation, ebullition within littoral embayments, and direct sampling of hyporheic pore-water. Measurements were also carried out in a free-flowing reach of the Columbia River to estimate unaltered conditions. Surface flux resulted in very low emissions, with reservoirs acting as a sink for CO2 (up to –262 mg m-2 d-1, which is within the range previously reported for similarly located reservoirs). Surface flux of methane remained below 1 mg CH4 m-2d-1, a value well below fluxes reported previously for temperate reservoirs. Water passing through hydroelectric projects acted as a sink for CO2 during winter and a small source during summer, with mean degassing fluxes of –117 and 4.5 t CO2 d-1, respectively. Degassing of CH4 was minimal, with mean fluxes of 3.1 × 10-6 and –5.6 × 10-4 t CH4 d-1 during winter and summer, respectively. Gas flux due to ebullition was greater in coves located within reservoirs than in coves within the free flowing Hanford Reach–and CH4 flux exceeded that of CO2. Methane emissions varied widely across sampling locations, ranging from 10.5 to 1039 mg CH4 m-2 d-1, with mean fluxes of 324 mg CH4 m-2 d-1in Lower Monumental Dam reservoir and 482 mg CH4 m-2d-1 in the Priest Rapids Dam reservoir. The magnitude of methane flux due to ebullition was unexpectedly high, and falls within the range recently reported for other temperate reservoirs around the world, further suggesting that this methane source should be considered in estimates of global greenhouse gas emissions. Methane flux from sediment pore-water within littoral embayments averaged 4.2 mg m-2 d-1 during winter and 8.1 mg m-2 d-1 during summer, with a peak flux of 19.8 mg m-2d-1 (at the same location where CH4 ebullition was also the greatest). Carbon dioxide flux from sediment pore-water averaged approximately 80 mg m-2d-1 with little difference between winter and summer. Similar to emissions from ebullition, flux from sediment pore-water was higher in reservoirs than in the free flowing reach.

  1. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions Recovery Act Funding Supports Two Large Landfill Projects BroadRock Renewables, LLC built two high efficiency electricity generating facilities that utilize landfill gas in California and Rhode Island. The two projects received a total of $25 million in U.S. Department of Energy funding from the American Recovery and Reinvestment Act (ARRA) of 2009. Private-sector cost share for the projects totaled

  2. NREL Develops More Precise Look at Cradle-to-Grave Greenhouse Gas Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Energy Technologies - News Releases | NREL NREL Develops More Precise Look at Cradle-to-Grave Greenhouse Gas Emissions for Energy Technologies May 4, 2012 A new approach to assessing greenhouse-gas emissions from coal, wind, solar and other energy technologies paints a much more precise picture of cradle-to-grave emissions and should help sharpen decisions on what new energy projects to build. The method - a harmonization of widely variant estimates of greenhouse gas emissions by the

  3. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Across the Continental United States | Department of Energy Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Data analysis from this study will provide insight into real-world performance of current emissions reduction devices, under various operating conditions, and with respect to greenhouse gas emissions. PDF icon p-03_carder.pdf

  4. Fact #589: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Standards | Department of Energy 9: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas Emissions Standards Fact #589: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas Emissions Standards On September 15, the U.S. Environmental Protection Agency (EPA) and U.S. Department of Transportation's National Highway Traffic Safety Administration (NHTSA) jointly announced a proposal to establish national standards for greenhouse gas (GHG) emissions and Corporate Average

  5. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental...

  6. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  7. Microsoft Word - NETL-TRS-4-2014_CO2 Storage and Enhanced Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Depleted Shale Gas Formations Using a Dual- PorosityDual-Permeability, Multiphase Reservoir Simulator 1 EXECUTIVE SUMMARY The Industrial Carbon Management Initiative (ICMI)...

  8. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium

  9. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  10. 11,970,363 Metric Tons of CO2 Injected as of February 23, 2016 | Department

    Energy Savers [EERE]

    of Energy 11,970,363 Metric Tons of CO2 Injected as of February 23, 2016 11,970,363 Metric Tons of CO2 Injected as of February 23, 2016 This carbon dioxide (CO2) has been injected in the United States as part of DOE's Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the annual greenhouse gas emissions from 210,526 passenger vehicles. The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program

  11. First U.S. Large-Scale CO2 Storage Project Advances | Department of Energy

    Office of Environmental Management (EM)

    First U.S. Large-Scale CO2 Storage Project Advances First U.S. Large-Scale CO2 Storage Project Advances April 6, 2009 - 1:00pm Addthis Washington, DC - Drilling nears completion for the first large-scale carbon dioxide (CO2) injection well in the United States for CO2 sequestration. This project will be used to demonstrate that CO2 emitted from industrial sources - such as coal-fired power plants - can be stored in deep geologic formations to mitigate large quantities of greenhouse gas

  12. 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015 | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015 11,202,720 Metric Tons of CO2 Injected as of October 14, 2015 This carbon dioxide (CO2) has been injected in the United States as part of DOE's Clean Coal Research, Development, and Demonstration Programs. One million metric tons of CO2 is equivalent to the annual greenhouse gas emissions from 210,526 passenger vehicles. The projects currently injecting CO2 within DOE's Regional Carbon Sequestration Partnership Program

  13. CO2 Tech | Open Energy Information

    Open Energy Info (EERE)

    produces and installs equipment for controlling and measuring atmospheric emissions and greenhouse gases for a wide variety of industries. References: CO2 Tech1 This article is...

  14. Advancing Development and Greenhouse Gas Reductions in Vietnam's Wind Sector

    SciTech Connect (OSTI)

    Bilello, D.; Katz, J.; Esterly, S.; Ogonowski, M.

    2014-09-01

    Clean energy development is a key component of Vietnam's Green Growth Strategy, which establishes a target to reduce greenhouse gas (GHG) emissions from domestic energy activities by 20-30 percent by 2030 relative to a business-as-usual scenario. Vietnam has significant wind energy resources, which, if developed, could help the country reach this target while providing ancillary economic, social, and environmental benefits. Given Vietnam's ambitious clean energy goals and the relatively nascent state of wind energy development in the country, this paper seeks to fulfill two primary objectives: to distill timely and useful information to provincial-level planners, analysts, and project developers as they evaluate opportunities to develop local wind resources; and, to provide insights to policymakers on how coordinated efforts may help advance large-scale wind development, deliver near-term GHG emission reductions, and promote national objectives in the context of a low emission development framework.

  15. Review of the findings of the Ignik Sikumi CO2-CH4 gas hydrate exchange field trial

    SciTech Connect (OSTI)

    Anderson, Brian J.; Boswell, Ray; Collett, Tim S.; Farrell, Helen; Ohtsuka, Satoshi; White, Mark D.

    2014-08-01

    The Ignik Sikumi Gas Hydrate Exchange Field Trial was conducted by ConocoPhillips in partnership with the U.S. Department of Energy, the Japan Oil, Gas, and Metals National Corporation, and the U.S. Geological Survey within the Prudhoe Bay Unit on the Alaska North Slope (ANS) during 2011 and 2012. The 2011 field program included drilling the vertical test well and performing extensive wireline logging through a thick section of gas-hydrate-bearing sand reservoirs that provided substantial new insight into the nature of ANS gas hydrate occurrences. The 2012 field program involved an extended, scientific field trial conducted within a single vertical well (huff-and-puff design) through three primary operational phases: 1) injection of a gaseous phase mixture of CO2, N2, and chemical tracers; 2) flowback conducted at down-hole pressures above the stability threshold for native CH4-hydrate, and 3) extended (30-days) flowback at pressures below the stability threshold of native CH4-hydrate. Ignik Sikumi represents the first field investigation of gas hydrate response to chemical injection, and the longest-duration field reservoir response experiment yet conducted. Full descriptions of the operations and data collected have been fully reported by ConocoPhillips and are available to the science community. The 2011 field program indicated the presence of free water within the gas hydrate reservoir, a finding with significant implications to the design of the exchange trial most notably the use of a mixed gas injectant. While this decision resulted in a complex chemical environment within the reservoir that greatly tests current experimental and modeling capabilities without such a mixture, it is apparent that injection could not have been achieved. While interpretation of the field data are continuing, the primary scientific findings and implications of the program are: 1) gas hydrate destabilizing is self-limiting, dispelling any notion of the potential for uncontrolled destabilization; 2) wells must be carefully designed to enable rapid remediation of well-bore blockages that will occur during any cessation in operations; 3) appropriate gas mixes can be successfully injected into hydrate-bearing reservoirs; 4) sand production can be well-managed through standard engineering controls; 5) reservoir heat exchange during depressurization was much more favorable than expected mitigating concerns for near-well-bore freezing and enabling consideration of more aggressive pressure reduction and; 6) CO2-CH4 exchange can be accomplished in natural reservoirs. The next steps in evaluation of exchange technology should feature multiple well applications; however such field programs will require extensive preparatory experimental and numerical modeling studies and will likely be a secondary priority to further field testing of production through depressurization.

  16. Supercritical CO2 direct cycle Gas Fast Reactor (SC-GFR) concept.

    SciTech Connect (OSTI)

    Wright, Steven Alan; Parma, Edward J., Jr.; Suo-Anttila, Ahti Jorma; Al Rashdan, Ahmad; Tsvetkov, Pavel Valeryevich; Vernon, Milton E.; Fleming, Darryn D.; Rochau, Gary Eugene

    2011-05-01

    This report describes the supercritical carbon dioxide (S-CO{sub 2}) direct cycle gas fast reactor (SC-GFR) concept. The SC-GFR reactor concept was developed to determine the feasibility of a right size reactor (RSR) type concept using S-CO{sub 2} as the working fluid in a direct cycle fast reactor. Scoping analyses were performed for a 200 to 400 MWth reactor and an S-CO{sub 2} Brayton cycle. Although a significant amount of work is still required, this type of reactor concept maintains some potentially significant advantages over ideal gas-cooled systems and liquid metal-cooled systems. The analyses presented in this report show that a relatively small long-life reactor core could be developed that maintains decay heat removal by natural circulation. The concept is based largely on the Advanced Gas Reactor (AGR) commercial power plants operated in the United Kingdom and other GFR concepts.

  17. Shale-Gas Experience as an Analog for Potential Wellbore Integrity Issues in CO2 Sequestration

    SciTech Connect (OSTI)

    Carey, James W.; Simpson, Wendy S.; Ziock, Hans-Joachim

    2011-01-01

    Shale-gas development in Pennsylvania since 2003 has resulted in about 19 documented cases of methane migration from the deep subsurface (7,0000) to drinking water aquifers, soils, domestic water wells, and buildings, including one explosion. In all documented cases, the methane leakage was due to inadequate wellbore integrity, possibly aggravated by hydrofracking. The leakage of methane is instructive on the potential for CO{sub 2} leakage from sequestration operations. Although there are important differences between the two systems, both involve migrating, buoyant gas with wells being a primary leakage pathway. The shale-gas experience demonstrates that gas migration from faulty wells can be rapid and can have significant impacts on water quality and human health and safety. Approximately 1.4% of the 2,200 wells drilled into Pennsylvania's Marcellus Formation for shale gas have been implicated in methane leakage. These have resulted in damage to over 30 domestic water supplies and have required significant remediation via well repair and homeowner compensation. The majority of the wellbore integrity problems are a result of over-pressurization of the wells, meaning that high-pressure gas has migrated into an improperly protected wellbore annulus. The pressurized gas leaks from the wellbore into the shallow subsurface, contaminating drinking water or entering structures. The effects are localized to a few thousands of feet to perhaps two-three miles. The degree of mixing between the drinking water and methane is sufficient that significant chemical impacts are created in terms of elevated Fe and Mn and the formation of black precipitates (metal sulfides) as well as effervescing in tap water. Thus it appears likely that leaking CO{sub 2} could also result in deteriorated water quality by a similar mixing process. The problems in Pennsylvania highlight the critical importance of obtaining background data on water quality as well as on problems associated with previous (legacy) oil and gas operations. The great majority of the leakage issues in Pennsylvania are due to improperly abandoned wells, however in the media there is no clear distinction between past and present problems. In any case, significant analytical work is required to attribute differing sources of methane (or CO{sub 2} in the case of sequestration). In Pennsylvania, a relatively lax regulatory environment appears to have contributed to the problem with inadequate oversight of well design and testing to ensure well integrity. New rules were adopted at the end of 2010, and it will be interesting to observe whether methane leakage problems are significantly reduced.

  18. Rapid, reversible, solid–gas and solution-phase insertion of CO2 into In–P bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore » 2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(μ-Cl)[μ-(i-Pr2P)2N)].« less

  19. Rapid, Reversible, SolidGas and Solution-Phase Insertion of CO 2 into InP Bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four MP bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore2 h in the solidgas reaction. The CO2 complex is stable up to at least 60 C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(?-Cl)[?-(i-Pr2P)2N)].less

  20. Supercritical CO2-Brayton Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas ...

  1. Greenhouse gas emissions from landfill leachate treatment plants...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 54 ENVIRONMENTAL SCIENCES; 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; AGING; CARBON DIOXIDE; GREENHOUSE GASES; LEACHATES; ...

  2. Energy Department Releases New Greenhouse Gas Reporting Guidance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Under the revised guidelines, utilities, manufacturers and other businesses that emit greenhouse gases will be able to register their emission reductions achieved after 2002 if ...

  3. CO2 Utilization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Utilization CO2 Utilization Carbon dioxide (CO2) use and reuse efforts focus on the conversion of CO2 to useable products and fuels that will reduce CO2 emissions in areas where geologic storage may not be an optimal solution. These include: Enhanced Oil/Gas Recovery - Injecting CO2 into depleting oil or gas bearing fields to maximize the amount of CO2 that could be stored as well as maximize hydrocarbon production. View the latest projects selected in FY 2014. CO2 as Feedstock - Use CO2 as

  4. Idaho National Laboratory's FY13 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Kimberly Frerichs

    2014-03-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during Fiscal Year (FY) 2013 by Idaho National Laboratory (INL), a Department of Energy (DOE) sponsored entity, located in southeastern Idaho. This report details the methods behind quantifying INLs GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only the large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  5. Estimating the potential of greenhouse gas mitigation in Kazakhstan

    SciTech Connect (OSTI)

    Monacrovich, E.; Pilifosova, O.; Danchuck, D.

    1996-09-01

    As part of the studies related to the obligations of the UN Framework Convention on Climate Change, the Republic of Kazakhstan started activities to inventory greenhouse gas (GHG) emissions and assess of GHG mitigation options, The objective of this paper is to present an estimate of the possibility of mitigating GHG emissions and determine the mitigation priorities. It presents a compilation of the possible options and their assessment in terms of major criteria and implementation feasibility. Taking into account the structure of GHG emissions in Kazakhstan in 1990, preliminary estimates of the potential for mitigation are presented for eight options for the energy sector and agriculture and forestry sector. The reference scenario prepared by expert assessments assumes a reduction of CO{sub 2} emissions in 1996-1998 by about 26% from the 1990 level due to general economic decline, but then emissions increase. It is estimated that the total potential for the mitigation of CO{sub 2} emissions for the year 2000 is 3% of the CO{sub 2} emissions in the reference scenario. The annual reduction in methane emissions due to the estimated options can amount to 5%-6% of the 1990 level. 10 refs., 1 fig., 4 tabs.

  6. Technology and Greenhouse Gas Emissions: An IntegratedScenario Analysis

    SciTech Connect (OSTI)

    Koomey, J.G.; Latiner, S.; Markel, R.J.; Marnay, C.; Richey, R.C.

    1998-09-01

    This report describes an analysis of possible technology-based scenarios for the U.S. energy system that would result in both carbon savings and net economic benefits. We use a modified version of the Energy Information Administration's National Energy Modeling System (LBNL-NEMS) to assess the potential energy, carbon, and bill savings from a portfolio of carbon saving options. This analysis is based on technology resource potentials estimated in previous bottom-up studies, but it uses the integrated LBNL-NEMS framework to assess interactions and synergies among these options. The analysis in this paper builds on previous estimates of possible "technology paths" to investigate four major components of an aggressive greenhouse gas reduction strategy: (1) the large scale implementation of demand-side efficiency, comparable in scale to that presented in two recent policy studies on this topic; (2) a variety of "alternative" electricity supply-side options, including biomass cofiring, extension of the renewable production tax credit for wind, increased industrial cogeneration, and hydropower refurbishment. (3) the economic retirement of older and less efficient existing fossil-find power plants; and (4) a permit charge of $23 per metric ton of carbon (1996 $/t),l assuming that carbon trading is implemented in the US, and that the carbon permit charge equilibrates at this level. This level of carbon permit charge, as discussed later in the report, is in the likely range for the Clinton Administration's position on this topic.

  7. Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health

    SciTech Connect (OSTI)

    West, Jason; Smith, Steven J.; Silva, Raquel; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zacariah; Fry, Meridith M.; Anenberg, Susan C.; Horowitz, L.; Lamarque, Jean-Francois

    2013-10-01

    Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. Relative to a reference scenario, global GHG mitigation in the RCP4.5 scenario avoids 0.50.2, 1.30.6, and 2.21.6 million premature deaths in 2030, 2050, and 2100, from changes in fine particulate matter and ozone. Global average marginal co-benefits of avoided mortality are $40-400 (ton CO2)-1, exceeding marginal abatement costs in 2030 and 2050, and within the low range of costs in 2100. East Asian co-benefits are 10-80 times the marginal cost in 2030. These results indicate that transitioning to a low-carbon future might be justified by air quality and health co-benefits.

  8. Co-benefits of mitigating global greenhouse gas emissions for future air

    Office of Scientific and Technical Information (OSTI)

    quality and human health (Journal Article) | SciTech Connect Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health Citation Details In-Document Search Title: Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted

  9. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Vehicles | Department of Energy Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Presented at the U.S. Department of EnergyLight Duty Vehicle Workshop in Washington, D.C. on July 26, 2010. PDF icon wtw_analysis_phevs.pdf More Documents & Publications Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles System

  10. Statement from U.S. Energy Secretary Moniz on Mexico's Greenhouse Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Targets | Department of Energy U.S. Energy Secretary Moniz on Mexico's Greenhouse Gas Emissions Targets Statement from U.S. Energy Secretary Moniz on Mexico's Greenhouse Gas Emissions Targets March 27, 2015 - 5:06pm Addthis Dr. Ernest Moniz Dr. Ernest Moniz Secretary of Energy News Media Contact (202) 586-4940 "We warmly welcome the announcement by the Government of Mexico on new greenhouse gas emissions reduction targets. The commitment Mexico has made today sends a strong

  11. Microtrap assembly for greenhouse gas and air pollution monitoring

    DOE Patents [OSTI]

    Mitra, Somenath; Saridara, Chutarat

    2015-08-25

    A microtrap assembly includes a carbon nanotube sorbent. The microtrap assembly may be employed as a preconcentrator operable to deliver a sample to an analytical device to measure the concentrations of greenhouse gases. A system includes a microtrap having a carbon nanotube sorbent for measuring the concentrations of greenhouse gases in a sample.

  12. Measurements of 222Rn, 220Rn, and CO Emissions in Natural CO2 Fields in Wyoming: MVA Techniques for Determining Gas Transport and Caprock Integrity

    SciTech Connect (OSTI)

    Kaszuba, John; Sims, Kenneth

    2014-09-30

    An integrated field-laboratory program evaluated the use of radon and CO2 flux measurements to constrain source and timescale of CO2 fluxes in environments proximate to CO2 storage reservoirs. By understanding the type and depth of the gas source, the integrity of a CO2 storage reservoir can be assessed and monitored. The concept is based on correlations of radon and CO2 fluxes observed in volcanic systems. This fundamental research is designed to advance the science of Monitoring, Verification, and Accounting (MVA) and to address the Carbon Storage Program goal of developing and validating technologies to ensure 99 percent storage performance. Graduate and undergraduate students conducted the research under the guidance of the Principal Investigators; in doing so they were provided with training opportunities in skills required for implementing and deploying CCS technologies. Although a final method or tool was not developed, significant progress was made. The field program identified issues with measuring radon in environments rich in CO2. Laboratory experiments determined a correction factor to apply to radon measurements made in CO2-bearing environments. The field program also identified issues with radon and CO2-flux measurements in soil gases at a natural CO2 analog. A systematic survey of radon and CO2 flux in soil gases at the LaBarge CO2 Field in Southwest Wyoming indicates that measurements of 222Rn (radon), 220Rn (thoron), and CO2 flux may not be a robust method for monitoring the integrity of a CO2 storage reservoir. The field program was also not able to correlate radon and CO2 flux in the CO2-charged springs of the Thermopolis hydrothermal system. However, this part of the program helped to motivate the aforementioned laboratory experiments that determined correction factors for measuring radon in CO2-rich environments. A graduate student earned a Master of Science degree for this part of the field program; she is currently employed with a geologic consulting company. Measurement of radon in springs has improved significantly since the field program first began; however, in situ measurement of 222Rn and particularly 220Rn in springs is problematic. Future refinements include simultaneous salinity measurements and systematic corrections, or adjustments to the partition coefficient as needed for more accurate radon concentration determination. A graduate student earned a Master of Science degree for this part of the field program; he is currently employed with a geologic consulting company. Both graduate students are poised to begin work in a CCS technology area. Laboratory experiments evaluated important process-level fundamentals that effect measurements of radon and CO2. Laboratory tests established that fine-grained source minerals yield higher radon emissivity compared to coarser-sized source minerals; subtleties in the dataset suggest that grain size alone is not fully representative of all the processes controlling the ability of radon to escape its mineral host. Emissivity for both 222Rn and 220Rn increases linearly with temperature due to reaction of rocks with water, consistent with faster diffusion and enhanced mineral dissolution at higher temperatures. The presence of CO2 changes the relative importance of the factors that control release of radon. Emissivity for both 222Rn and 220Rn in CO2-bearing experiments is greater at all temperatures compared to the experiments without CO2, but emissivity does not increase as a simple function of temperature. Governing processes may include a balance between enhanced dissolution versus carbonate mineral formation in CO2-rich waters.

  13. Minimization of steam requirements and enhancement of water-gas shift reaction with warm gas temperature CO2 removal

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Fisher, II, James C

    2013-12-31

    The disclosure utilizes a hydroxide sorbent for humidification and CO.sub.2 removal from a gaseous stream comprised of CO and CO.sub.2 prior to entry into a water-gas-shift reactor, in order to decrease CO.sub.2 concentration and increase H.sub.2O concentration and shift the water-gas shift reaction toward the forward reaction products CO.sub.2 and H.sub.2. The hydroxide sorbent may be utilized for absorbtion of CO.sub.2 exiting the water-gas shift reactor, producing an enriched H.sub.2 stream. The disclosure further provides for regeneration of the hydroxide sorbent at temperature approximating water-gas shift conditions, and for utilizing H.sub.2O product liberated as a result of the CO.sub.2 absorption.

  14. DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site June 3, 2015 - 8:44am Addthis Photo courtesy of Exelis Photo courtesy of Exelis A project that uses lasers to monitor carbon dioxide (CO2) is being analyzed as part of the U.S. Department of Energy's (DOE) drive to improve greenhouse gas-monitoring abilities at CO2 storage sites. The project is managed by the DOE Office of Fossil

  15. Energy Market Impacts of Alternative Greenhouse Gas Intensity Reduction Goals

    Reports and Publications (EIA)

    2006-01-01

    This report responds to a request from Senator Ken Salazar that the Energy Information Administration (EIA) analyze the impacts of implementing alternative variants of an emissions cap-and-trade program for greenhouse gases (GHGs).

  16. DOE Strengthens Public Registry to Track Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Under this program, U.S. companies will submit detailed, annual reports on their emissions and reductions of greenhouse gases, and these reports will become part of the public ...

  17. Electricity price impacts of alternative Greenhouse gas emission cap-and-trade programs

    SciTech Connect (OSTI)

    Edelston, Bruce; Armstrong, Dave; Kirsch, Laurence D.; Morey, Mathew J.

    2009-07-15

    Limits on greenhouse gas emissions would raise the prices of the goods and services that require such emissions for their production, including electricity. Looking at a variety of emission limit cases and scenarios for selling or allocating allowances to load-serving entities, the authors estimate how the burden of greenhouse gas limits are likely to be distributed among electricity consumers in different states. (author)

  18. Land-use change and greenhouse gas emissions from corn and cellulosic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ethanol | Argonne National Laboratory Land-use change and greenhouse gas emissions from corn and cellulosic ethanol July 16, 2013 Tweet EmailPrint The greenhouse gas (GHG) emissions that may accompany land-use change (LUC) from increased biofuel feedstock production are a source of debate in the discussion of drawbacks and advantages of biofuels. Estimates of LUC GHG emissions focus mainly on corn ethanol and vary widely. Increasing the understanding of LUC GHG impacts associated with both

  19. CO2-Binding Organic Liquids Gas Capture with Polarity-Swing-Assisted Regeneration Full Technology Feasibility Study B1 - Solvent-based Systems

    SciTech Connect (OSTI)

    Heldebrant, David J

    2014-08-31

    PNNL, Fluor Corporation and Queens University (Kingston, ON) successfully completed a three year comprehensive study of the CO2BOL water-lean solvent platform with Polarity Swing Assisted Regeneration (PSAR). This study encompassed solvent synthesis, characterization, environmental toxicology, physical, thermodynamic and kinetic property measurements, Aspen Plus™ modeling and bench-scale testing of a candidate CO2BOL solvent molecule. Key Program Findings The key program findings are summarized as follows: • PSAR favorably reduced stripper duties and reboiler temperatures with little/no impact to absorption column • >90% CO2 capture was achievable at reasonable liquid-gas ratios in the absorber • High rich solvent viscosities (up to 600 cP) were successfully demonstrated in the bench-scale system. However, the projected impacts of high viscosity to capital cost and operational limits compromised the other levelized cost of electricity benefits. • Low thermal conductivity of organics significantly increased the required cross exchanger surface area, and potentially other heat exchange surfaces. • CO2BOL had low evaporative losses during bench-scale testing • There was no evidence of foaming during bench scale testing • Current CO2BOL formulation costs project to be $35/kg • Ecotoxicity (Water Daphnia) was comparable between CO2BOL and MEA (169.47 versus 103.63 mg/L) • Full dehydration of the flue gas was determined to not be economically feasible. However, modest refrigeration (13 MW for the 550 MW reference system) was determined to be potentially economically feasible, and still produce a water-lean condition for the CO2BOLs (5 wt% steady-state water loading). • CO2BOLs testing with 5 wt% water loading did not compromise anhydrous performance behavior, and showed actual enhancement of CO2 capture performance. • Mass transfer of CO2BOLs was not greatly impeded by viscosity • Facile separation of antisolvent from lean CO2BOL was demonstrated on the bench cart • No measurable solvent degradation was observed over 4 months of testing – even with 5 wt% water present

  20. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  1. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  2. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  3. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  4. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  5. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse gas-into methanol (CH3OH)-a key commodity used to produce numerous industrial chemicals and fuels. With the help of ambient-pressure x-ray photoelectron spectroscopy (AP-XPS) at the ALS, researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow

  6. Idaho National Laboratorys FY09 & FY10 Greenhouse Gas Report

    SciTech Connect (OSTI)

    Jennifer D. Morton

    2011-06-01

    A greenhouse gas (GHG) inventory is a systematic approach to account for the production and release of certain gases generated by an institution from various emission sources. The gases of interest are those that climate science has identified as related to anthropogenic global climate change. This document presents an inventory of GHGs generated during fiscal year (FY) 2009 and 2010 by Idaho National Laboratory (INL), a Department of Energy (DOE)-sponsored entity, located in southeastern Idaho. In recent years, concern has grown about the environmental impact of GHGs. This, together with a desire to decrease harmful environmental impacts, would be enough to encourage the calculation of an inventory of the total GHGs generated at INL. Additionally, INL has a desire to see how its emissions compare with similar institutions, including other DOE national laboratories. Executive Order 13514 requires that federal agencies and institutions document reductions in GHG emissions. INL's GHG inventory was calculated according to methodologies identified in federal GHG guidance documents using operational control boundaries. It measures emissions generated in three scopes: (1) INL emissions produced directly by stationary or mobile combustion and by fugitive emissions, (2) the share of emissions generated by entities from which INL purchased electrical power, and (3) indirect or shared emissions generated by outsourced activities that benefit INL (occur outside INL's organizational boundaries, but are a consequence of INL's activities). This inventory found that INL generated 103,590 and 102,413 MT of CO2-equivalent emissions during FY09 and FY10, respectively. The following conclusions were made from looking at the results of the individual contributors to INL's FY09 and FY10 GHG inventories: (1) Electricity (including the associated transmission and distribution losses) is the largest contributor to INL's GHG inventory, with over 50% of the CO2e emissions; (2) Other sources with high emissions were stationary combustion (facility fuels), waste disposal (including fugitive emissions from the onsite landfill and contracted disposal), mobile combustion (fleet fuels), employee commuting, and business air travel; and (3) Sources with low emissions were wastewater treatment (onsite and contracted), fugitive emissions from refrigerants, and business ground travel (in personal and rental vehicles). This report details the methods behind quantifying INL's GHG inventory and discusses lessons learned on better practices by which information important to tracking GHGs can be tracked and recorded. It is important to note that because this report differentiates between those portions of INL that are managed and operated by the Battelle Energy Alliance (BEA) and those managed by other contractors, it includes only that large proportion of Laboratory activities overseen by BEA. It is assumed that other contractors will provide similar reporting for those activities they manage, where appropriate.

  7. Efficient electrochemical CO2 conversion powered by renewable energy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R.; Zeng, Chenjie; Jin, Rongchao

    2015-06-29

    The catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspond tomore » conversion rates approaching 0.8–1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 106 mol CO2 molcatalyst–1 during a multiday (36 hours total hours) CO2electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 106 and 4 × 106 molCO2 molcatalyst–1 were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies are sufficient to power larger-scale, tonne per day CO2 conversion systems.« less

  8. Greenhouse gas emissions from forest, land use and biomass burning in Tanzania

    SciTech Connect (OSTI)

    Matitu, M.R.

    1994-12-31

    Carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) gases are the main contributors to the greenhouse effect that consequently results in global warming. This paper examines the sources and sinks of these gases from/to forest, land use and biomass burning and their likely contribution to climate change using IPCC/OECD methodology. Emissions have been calculated in mass units of carbon and nitrogen Emissions and uptake have been summed for each gas and the emissions converted to full molecular weights. Mismanagement of forests and land misuse have contributed much to greenhouse gas emissions in Tanzania. For example, cultivation methods, forest clearing, burning of savannah grass and indiscriminate logging (non-sustainable logging) have contributed significantly to greenhouse gas emissions. These categories contribute more than 90% of total CO{sub 2} emissions. However, the study shows that shifting cultivation, savannah burning and forest clearing for conversion to permanent crop land and pasture are the main contributors.

  9. Northern California CO2 Reduction Project

    SciTech Connect (OSTI)

    Hymes, Edward

    2010-06-16

    C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

  10. DOE Partner Begins Injecting 50,000 Tons of CO2 in Michigan Basin

    Broader source: Energy.gov [DOE]

    Building on an initial injection project of 10,000 metric tons of carbon dioxide into a Michigan geologic formation, a U.S. Department of Energy team of regional partners has begun injecting 50,000 additional tons into the formation, which is believed capable of storing hundreds of years worth of CO2, a greenhouse gas that contributes to climate change.

  11. Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Implications for U.S. Petroleum Fuels | Argonne National Laboratory Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products: Implications for U.S. Petroleum Fuels Title Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products: Implications for U.S. Petroleum Fuels Publication Type Journal Article Year of Publication 2015 Authors Cai, H, Brandt, AR, Yeh, S, Englander, JG, Han, J, Elgowainy, A, M.Q., W Journal Environmental Science & Technology Volume 49 Start

  12. Greenhouse Gas Regional Inventory Protocol (GRIP) Website | Open...

    Open Energy Info (EERE)

    URI: cleanenergysolutions.orgcontentgreenhouse-gas-regional-inventory-pro Language: English Policies: Deployment Programs DeploymentPrograms: "Lead by Example" is not...

  13. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Burkhardt, J. J.; Heath, G.; Cohen, E.

    2012-04-01

    In reviewing life cycle assessment (LCA) literature of utility-scale concentrating solar power (CSP) systems, this analysis focuses on reducing variability and clarifying the central tendency of published estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emissions estimates passing screens for quality and relevance: 19 for parabolic trough (trough) technology and 17 for power tower (tower) technology. The interquartile range (IQR) of published estimates for troughs and towers were 83 and 20 grams of carbon dioxide equivalent per kilowatt-hour (g CO2-eq/kWh),1 respectively; median estimates were 26 and 38 g CO2-eq/kWh for trough and tower, respectively. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. The IQR and median were reduced by 87% and 17%, respectively, for troughs. For towers, the IQR and median decreased by 33% and 38%, respectively. Next, five trough LCAs reporting detailed life cycle inventories were identified. The variability and central tendency of their estimates are reduced by 91% and 81%, respectively, after light harmonization. By harmonizing these five estimates to consistent values for global warming intensities of materials and expanding system boundaries to consistently include electricity and auxiliary natural gas combustion, variability is reduced by an additional 32% while central tendency increases by 8%. These harmonized values provide useful starting points for policy makers in evaluating life cycle GHG emissions from CSP projects without the requirement to conduct a full LCA for each new project.

  14. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  15. Where do California's greenhouse gases come from?

    SciTech Connect (OSTI)

    Fischer, Marc

    2009-01-01

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  16. Regulating greenhouse gas 'leakage': how California can evade the impending constitutional attacks

    SciTech Connect (OSTI)

    Brian H. Potts

    2006-06-15

    Federalist greenhouse gas regulation poses many constitutional pitfalls, and some fear that California's cap-and-trade and procurement cap proposals are vulnerable to constitutional challenge. An attack under the commerce clause seems to pose the biggest threat, but the author proposes an alternative that can eliminate this threat: market participation.

  17. State Commission electricity regulation under Federal Greenhouse gas cap-and-trade policy

    SciTech Connect (OSTI)

    Keeler, Andrew G.

    2008-05-15

    Given the current uncertainty about the timing and severity of greenhouse gas constraints on electric generation that will result from a federal program, commissions need to begin crafting strategies and procedures to best serve the public interest in this new environment. (author)

  18. U.S. Greenhouse Gas Intensity and the Global Climate Change Initiative (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On February 14, 2002, President Bush announced the Administrations Global Climate Change Initiative. A key goal of the Climate Change Initiative is to reduce U.S. greenhouse gas (GHG) intensity-defined as the ratio of total U.S. GHG emissions to economic output-by 18% over the 2002 to 2012 time frame.

  19. Transformative Reduction of Transportation Greenhouse Gas Emissions. Opportunities for Change in Technologies and Systems

    SciTech Connect (OSTI)

    Vimmerstedt, Laura; Brown, Austin; Newes, Emily; Markel, Tony; Schroeder, Alex; Zhang, Yimin; Chipman, Peter; Johnson, Shawn

    2015-04-30

    The transportation sector is changing, influenced by concurrent, ongoing, dynamic trends that could dramatically affect the future energy landscape, including effects on the potential for greenhouse gas emissions reductions. Battery cost reductions and improved performance coupled with a growing number of electric vehicle model offerings are enabling greater battery electric vehicle market penetration, and advances in fuel cell technology and decreases in hydrogen production costs are leading to initial fuel cell vehicle offerings. Radically more efficient vehicles based on both conventional and new drivetrain technologies reduce greenhouse gas emissions per vehicle-mile. Net impacts also depend on the energy sources used for propulsion, and these are changing with increased use of renewable energy and unconventional fossil fuel resources. Connected and automated vehicles are emerging for personal and freight transportation systems and could increase use of low- or non-emitting technologies and systems; however, the net effects of automation on greenhouse gas emissions are uncertain. The longstanding trend of an annual increase in transportation demand has reversed for personal vehicle miles traveled in recent years, demonstrating the possibility of lower-travel future scenarios. Finally, advanced biofuel pathways have continued to develop, highlighting low-carbon and in some cases carbon-negative fuel pathways. We discuss the potential for transformative reductions in petroleum use and greenhouse gas emissions through these emerging transportation-sector technologies and trends and present a Clean Transportation Sector Initiative scenario for such reductions, which are summarized in Table ES-1.

  20. White House Announces New Executive Order To Reduce Greenhouse Gas Emissions in the Federal Government

    Broader source: Energy.gov [DOE]

    The White House today announced that President Obama will issue a new executive order that will cut the federal government's greenhouse gas emissions 40% over the next decade (from 2008 levels) and increase the share of electricity the federal government consumes from renewable sources to 30%.

  1. A review of water and greenhouse gas impacts of unconventional natural gas development in the United States

    SciTech Connect (OSTI)

    Arent, Doug; Logan, Jeff; Macknick, Jordan; Boyd, William; Medlock , Kenneth; O'Sullivan, Francis; Edmonds, James A.; Clarke, Leon E.; Huntington, Hill; Heath, Garvin; Statwick, Patricia M.; Bazilian, Morgan

    2015-01-01

    This paper reviews recent developments in the production and use of unconventional natural gas in the United States with a focus on water and greenhouse gas emission implications. If unconventional natural gas in the U.S. is produced responsibly, transported and distributed with little leakage, and incorporated into integrated energy systems that are designed for future resiliency, it could play a significant role in realizing a more sustainable energy future; however, the increased use of natural gas as a substitute for more carbon intensive fuels will alone not substantially alter world carbon dioxide concentration projections.

  2. Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2007-03-31

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

  3. A Reliable Muddle: Transportation Scenarios for the 80% Greenhouse Gas Reduction Goal for 2050 (Presentation)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reliable Muddle: Transportation Scenarios for the 80% Greenhouse Gas Reduction Goal for 2050 California Air Resource Board Scenario Meeting Marc Melaina Karen Webster October 28, 2009 Sacramento, California NREL/PR-560-47003 National Renewable Energy Laboratory Innovation for Our Energy Future Presentation Overview 2 Intro: Reducing LDV GHGs to 80% below 1990 levels * Transportation sector-specific emissions data and policy concerns. Part 1: Metrics for the 80% goal: A Pyramid Framework * Three

  4. Advancing Development and Greenhouse Gas Reductions in Vietnams Wind Sector

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advancing Development and Greenhouse Gas Reductions in Vietnam's Wind Sector June 19, 2014 Daniel Bilello, Jessica Katz, Sean Esterly National Renewable Energy Laboratory Matthew Ogonowski U.S. Agency for International Development EC-LEDS is managed by the U.S. Agency for International Development (USAID) and Department of State with support from the U.S. Department of Energy, U.S. Environmental Protection Agency, U.S. Department of Agriculture, and U.S. Forest Service. Printed with a

  5. California Greenhouse Gas Emissions Standards for Light-Duty Vehicles (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    In July 2002, California Assembly Bill 1493 (A.B. 1493) was signed into law. The law requires that the California Air Resources Board (CARB) develop and adopt, by January 1, 2005, greenhouse gas emission standards for light-duty vehicles that provide the maximum feasible reduction in emissions. In estimating the feasibility of the standard, CARB is required to consider cost-effectiveness, technological capability, economic impacts, and flexibility for manufacturers in meeting the standard.

  6. References and Appendices: U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis, November 2012

    Energy Savers [EERE]

    4 U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis REFERENCES AMO (Advanced Manufacturing Office), EERE (Energy Efficiency and Renewable Energy). 2012a. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators. U.S. Department of Energy. http://www1.eere.energy.gov/manufacturing/tech_deployment/pdfs/steam22_backpressure.pdf AMO (Advanced Manufacturing Office), EERE (Energy Efficiency and Renewable Energy). 2012b. Improving Steam System Performance: A

  7. Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of

    Broader source: Energy.gov (indexed) [DOE]

    Plug-In Hybrid Electric Vehicles | Department of Energy This report examines energy use and emissions from primary energy source through vehicle operation to help researchers understand the impact of the upstream mix of electricity generation technologies for recharging plug-in hybrid electric vehicles (PHEVs), as well as the powertrain technology and fuel sources for PHEVs. PDF icon Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles More

  8. Estimating the greenhouse gas benefits of forestry projects: A Costa Rican Case Study

    SciTech Connect (OSTI)

    Busch, Christopher; Sathaye, Jayant; Sanchez Azofeifa, G. Arturo

    2000-09-01

    If the Clean Development Mechanism proposed under the Kyoto Protocol is to serve as an effective means for combating global climate change, it will depend upon reliable estimates of greenhouse gas benefits. This paper sketches the theoretical basis for estimating the greenhouse gas benefits of forestry projects and suggests lessons learned based on a case study of Costa Rica's Protected Areas Project, which is a 500,000 hectare effort to reduce deforestation and enhance reforestation. The Protected Areas Project in many senses advances the state of the art for Clean Development Mechanism-type forestry projects, as does the third-party verification work of SGS International Certification Services on the project. Nonetheless, sensitivity analysis shows that carbon benefit estimates for the project vary widely based on the imputed deforestation rate in the baseline scenario, e.g. the deforestation rate expected if the project were not implemented. This, along with a newly available national dataset that confirms other research showing a slower rate of deforestation in Costa Rica, suggests that the use of the 1979--1992 forest cover data originally as the basis for estimating carbon savings should be reconsidered. When the newly available data is substituted, carbon savings amount to 8.9 Mt (million tones) of carbon, down from the original estimate of 15.7 Mt. The primary general conclusion is that project developers should give more attention to the forecasting land use and land cover change scenarios underlying estimates of greenhouse gas benefits.

  9. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

  10. Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors (Transportation Energy Futures Series)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DEMAND Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors TRANSPORTATION ENERGY FUTURES SERIES: Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors A Study Sponsored by U.S. Department of Energy Office of Energy Efficiency and Renewable Energy March 2013 Prepared by CAMBRIDGE SYSTEMATICS Cambridge, MA 02140 under subcontract DGJ-1-11857-01 Technical monitoring performed by NATIONAL

  11. Battery-Powered Electric and Hybrid Electric Vehicle Projects to Reduce Greenhouse Gas Emissions: A Resource for Project Development

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2002-07-31

    The transportation sector accounts for a large and growing share of global greenhouse gas (GHG) emissions. Worldwide, motor vehicles emit well over 900 million metric tons of carbon dioxide (CO2) each year, accounting for more than 15 percent of global fossil fuel-derived CO2 emissions.1 In the industrialized world alone, 20-25 percent of GHG emissions come from the transportation sector. The share of transport-related emissions is growing rapidly due to the continued increase in transportation activity.2 In 1950, there were only 70 million cars, trucks, and buses on the worlds roads. By 1994, there were about nine times that number, or 630 million vehicles. Since the early 1970s, the global fleet has been growing at a rate of 16 million vehicles per year. This expansion has been accompanied by a similar growth in fuel consumption.3 If this kind of linear growth continues, by the year 2025 there will be well over one billion vehicles on the worlds roads.4 In a response to the significant growth in transportation-related GHG emissions, governments and policy makers worldwide are considering methods to reverse this trend. However, due to the particular make-up of the transportation sector, regulating and reducing emissions from this sector poses a significant challenge. Unlike stationary fuel combustion, transportation-related emissions come from dispersed sources. Only a few point-source emitters, such as oil/natural gas wells, refineries, or compressor stations, contribute to emissions from the transportation sector. The majority of transport-related emissions come from the millions of vehicles traveling the worlds roads. As a result, successful GHG mitigation policies must find ways to target all of these small, non-point source emitters, either through regulatory means or through various incentive programs. To increase their effectiveness, policies to control emissions from the transportation sector often utilize indirect means to reduce emissions, such as requiring specific technology improvements or an increase in fuel efficiency. Site-specific project activities can also be undertaken to help decrease GHG emissions, although the use of such measures is less common. Sample activities include switching to less GHG-intensive vehicle options, such as electric vehicles (EVs) or hybrid electric vehicles (HEVs). As emissions from transportation activities continue to rise, it will be necessary to promote both types of abatement activities in order to reverse the current emissions path. This Resource Guide focuses on site- and project-specific transportation activities. .

  12. ARM - Measurement - Carbon dioxide (CO2) flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon dioxide, a heavy, colorless greenhouse gas. Categories Atmospheric Carbon, Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  13. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    SciTech Connect (OSTI)

    Shen, Bo; Price, Lynn K; Lu, Hongyou; Liu, Xu; Tsen, Katherine; Xiangyang, Wei; Yunpeng, Zhang; Jian, Guan; Rui, Hou; Junfeng, Zhang; Yuqun, Zhuo; Shumao, Xia; Yafeng, Han; Manzhi, Liu

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  14. Greenhouse Gases Converted to Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gases Converted to Fuel Greenhouse Gases Converted to Fuel carbon-conversion-fig-1.jpg Key Challenges: An important strategy for reducing global CO2 emissions calls for...

  15. Ancient Lava Flows Trap CO2 for Long-Term Storage in Big Sky Injection

    Broader source: Energy.gov [DOE]

    How can a prehistoric volcanic eruption help us reduce the amount of CO2 released into the atmosphere today? The answer is found in the basalt formations created by the lava – formations that can be used as sites for injecting carbon dioxide (CO2) captured from industrial sources in a process called carbon capture and storage. The Big Sky Carbon Sequestration Partnership recently injected 1,000 metric tons of CO2 into the Grande Ronde Basalt Formation in eastern Washington. This first-of-its kind injection is part of research meant to determine if basalt formations could provide a long-term solution for storing CO2, a potent greenhouse gas.

  16. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis Smirniotis

    2002-09-17

    A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

  17. Spatial and Temporal Correlates of Greenhouse Gas Diffusion from a Hydropower Reservoir in the Southern United States

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mosher, Jennifer; Fortner, Allison M.; Phillips, Jana Randolph; Bevelhimer, Mark S.; Stewart, Arthur; Troia, Matthew J.

    2015-10-29

    Emissions of CO2 and CH4 from freshwater reservoirs constitute a globally significant source of atmospheric greenhouse gases (GHGs), but knowledge gaps remain with regard to spatiotemporal drivers of emissions. We document the spatial and seasonal variation in surface diffusion of CO2 and CH4 from Douglas Lake, a hydropower reservoir in Tennessee, USA. Monthly estimates across 13 reservoir sites from January to November 2010 indicated that surface diffusions ranged from 236 to 18,806 mg m-2 day-1 for CO2 and 0 to 0.95 mg m-2 day-1 for CH4. Next, we developed statistical models using spatial and physicochemical variables to predict surface diffusionsmore » of CO2 and CH4. Models explained 22.7 and 20.9% of the variation in CO2 and CH4 diffusions, respectively, and identified pH, temperature, dissolved oxygen, and Julian day as the most informative important predictors. These findings provide baseline estimates of GHG emissions from a reservoir in eastern temperate North America a region for which estimates of reservoir GHGs emissions are limited. Our statistical models effectively characterized non-linear and threshold relationships between physicochemical predictors and GHG emissions. Further refinement of such models will aid in predicting current GHG emissions in unsampled reservoirs and forecasting future GHG emissions.« less

  18. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott; Theiss, Timothy J; Bunce, Michael

    2012-01-01

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  19. Beyond the Inventory: An Interagency Collaboration to Reduce Greenhouse Gas Emissions in the Greater Yellowstone Area

    SciTech Connect (OSTI)

    Kandt, A.; Hotchkiss, E.; Fiebig, M.

    2010-10-01

    As one of the largest, intact ecosystems in the continental United States, land managers within the Greater Yellowstone Area (GYA) have recognized the importance of compiling and understanding agency greenhouse gas (GHG) emissions. The 10 Federal units within the GYA have taken an active role in compiling GHG inventories on a unit- and ecosystem-wide level, setting goals for GHG mitigation, and identifying mitigation strategies for achieving those goals. This paper details the processes, methodologies, challenges, solutions, and lessons learned by the 10 Federal units within the GYA throughout this ongoing effort.

  20. Effects of Travel Reduction and Efficient Driving on Transportation: Energy Use and Greenhouse Gas Emissions

    Broader source: Energy.gov [DOE]

    Numerous transportation strategies are directed at reducing energy use and greenhouse gas (GHG) emissions by changing the behavior of individual drivers or travelers. These behavioral changes may have the effect of reducing travel, shifting travel to more efficient modes, or improving the efficiency of existing travel. Since the 1970s, federal, regional, state and municipal agencies have tried to reduce energy use, emissions, and congestion by influencing travel behavior. This report reviews and summarizes the literature on relationships between these strategies and transportation-related energy use and GHG emissions to examine how changes to travel behavior can reduce transportation energy use and discuss the potential for federal actions to affect travel behavior.

  1. Greenhouse gas emission impacts of electric vehicles under varying driving cycles in various counties and US cities

    SciTech Connect (OSTI)

    Wang, M.Q.; Marr, W.W.

    1994-02-10

    Electric vehicles (EVs) can reduce greenhouse gas emissions, relative to emissions from gasoline-fueled vehicles. However, those studies have not considered all aspects that determine greenhouse gas emissions from both gasoline vehicles (GVs) and EVs. Aspects often overlooked include variations in vehicle trip characteristics, inclusion of all greenhouse gases, and vehicle total fuel cycle. In this paper, we estimate greenhouse gas emission reductions for EVs, including these important aspects. We select four US cities (Boston, Chicago, Los Angeles, and Washington, D.C.) and six countries (Australia, France, Japan, Norway, the United Kingdom, and the United States) and analyze greenhouse emission impacts of EVs in each city or country. We also select six driving cycles developed around the world (i.e., the US federal urban driving cycle, the Economic Community of Europe cycle 15, the Japanese 10-mode cycle, the Los Angeles 92 cycle, the New York City cycle, and the Sydney cycle). Note that we have not analyzed EVs in high-speed driving (e.g., highway driving), where the results would be less favorable to EVs; here, EVs are regarded as urban vehicles only. We choose one specific driving cycle for a given city or country and estimate the energy consumption of four-passenger compact electric and gasoline cars in the given city or country. Finally, we estimate total fuel cycle greenhouse gas emissions of both GVs and EVs by accounting for emissions from primary energy recovery, transportation, and processing; energy product transportation; and powerplant and vehicle operations.

  2. Energy Market and Economic Impacts Proposal to Reduce Greenhouse Gas Intensity with a Cap and Trade System

    Reports and Publications (EIA)

    2007-01-01

    This report was prepared by the Energy Information Administration (EIA), in response to a September 27, 2006, request from Senators Bingaman, Landrieu, Murkowski, Specter, Salazar, and Lugar. The Senators requested that EIA assess the impacts of a proposal that would regulate emissions of greenhouse gases (GHGs) through an allowance cap-and-trade system. The program would set the cap to achieve a reduction in emissions relative to economic output, or greenhouse gas intensity.

  3. Contribution of cooperative sector recycling to greenhouse gas emissions reduction: A case study of Ribeiro Pires, Brazil

    SciTech Connect (OSTI)

    King, Megan F.; Gutberlet, Jutta

    2013-12-15

    Highlights: Cooperative recycling achieves environmental, economic and social objectives. We calculate GHG emissions reduction for a recycling cooperative in So Paulo, Brazil. The cooperative merits consideration as a Clean Development Mechanism (CDM) project. A CDM project would enhance the achievements of the recycling cooperative. National and local waste management policies support the recycling cooperative. - Abstract: Solid waste, including municipal waste and its management, is a major challenge for most cities and among the key contributors to climate change. Greenhouse gas emissions can be reduced through recovery and recycling of resources from the municipal solid waste stream. In So Paulo, Brazil, recycling cooperatives play a crucial role in providing recycling services including collection, separation, cleaning, stocking, and sale of recyclable resources. The present research attempts to measure the greenhouse gas emission reductions achieved by the recycling cooperative Cooperpires, as well as highlight its socioeconomic benefits. Methods include participant observation, structured interviews, questionnaire application, and greenhouse gas accounting of recycling using a Clean Development Mechanism methodology. The results show that recycling cooperatives can achieve important energy savings and reductions in greenhouse gas emissions, and suggest there is an opportunity for Cooperpires and other similar recycling groups to participate in the carbon credit market. Based on these findings, the authors created a simple greenhouse gas accounting calculator for recyclers to estimate their emissions reductions.

  4. Environmental implications of alternative-fueled automobiles: Air quality and greenhouse gas tradeoffs

    SciTech Connect (OSTI)

    MaClean, H.L.; Lave, L.B.

    2000-01-15

    The authors analyze alternative fuel-powerstrain options for internal combustion engine automobiles. Fuel/engine efficiency, energy use, pollutant discharges, and greenhouse gas emissions are estimated for spark and compression ignited, direct injected (DI), and indirect injected (II) engines fueled by conventional and reformulated gasoline, reformulated diesel, compressed natural gas (CNG), and alcohols. Since comparisons of fuels and technologies in dissimilar vehicles are misleading, the authors hold emissions level, range, vehicle size class, and style constant. At present, CNG vehicles have the best exhaust emissions performance while DI diesels have the worst. Compared to a conventional gasoline fueled II automobile, greenhouse gases could be reduced by 40% by a DI CNG automobile and by 25% by a DI diesel. Gasoline- and diesel-fueled automobiles are able to attain long ranges with little weight or fuel economy penalty. CNG vehicles have the highest penalty for increasing range, due to their heavy fuel storage systems, but are the most attractive for a 160-km range. DI engines, particularly diesels, may not be able to meet strict emissions standards, at least not without lowering efficiency.

  5. Reliable Muddle: Transportation Scenarios for the 80% Greenhouse Gas Reduction Goal for 2050 (Presentation)

    SciTech Connect (OSTI)

    Melaina, M.; Webster, K.

    2009-10-28

    Presentation describing transportation scenarios for meeting the 2050 DOE goal of reducing greenhouse gases by 80%.

  6. Exploring the effects of data quality, data worth, and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST Inversion

    SciTech Connect (OSTI)

    Fang, Zhufeng; Hou, Zhangshuan; Lin, Guang; Engel, David W.; Fang, Yilin; Eslinger, Paul W.

    2014-04-01

    This study examined the impacts of reservoir properties on CO2 migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO2 monitoring data such as saturation distribution. The injection reservoir was assumed to be located 1400-1500 m below the ground surface such that CO2 remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO2 injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended up to 8000 m from the injection well. The CO2 migration was simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). We adopted a nonlinear parameter estimation and optimization modeling software package, PEST, for automated reservoir parameter estimation. We explored the effects of data quality, data worth, and data redundancy on the detectability of reservoir parameters using CO2 saturation monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO2 saturation monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy.

  7. CO2-driven Enhanced Oil Recovery as a Stepping Stone to What?

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2010-07-14

    This paper draws heavily on the authors’ previously published research to explore the extent to which near term carbon dioxide-driven enhanced oil recovery (CO2-EOR) can be “a stepping stone to a long term sequestration program of a scale to be material in climate change risk mitigation.” The paper examines the historical evolution of CO2-EOR in the United States and concludes that estimates of the cost of CO2-EOR production or the extent of CO2 pipeline networks based upon this energy security-driven promotion of CO2-EOR do not provide a robust platform for spurring the commercial deployment of carbon dioxide capture and storage technologies (CCS) as a means of reducing greenhouse gas emissions. The paper notes that the evolving regulatory framework for CCS makes a clear distinction between CO2-EOR and CCS and the authors examine arguments in the technical literature about the ability for CO2-EOR to generate offsetting revenue to accelerate the commercial deployment of CCS systems in the electric power and industrial sectors of the economy. The authors conclude that the past 35 years of CO2-EOR in the U.S. have been important for boosting domestic oil production and delivering proven system components for future CCS systems. However, though there is no reason to suggest that CO2-EOR will cease to deliver these benefits, there is also little to suggest that CO2-EOR is a necessary or significantly beneficial step towards the commercial deployment of CCS as a means of addressing climate change.

  8. Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions

    SciTech Connect (OSTI)

    Malhotra, Vivak

    2014-06-30

    The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ≤ T ≤ 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (≤ 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale cores, which were pressurized with high pressure CO2, determine the fate of sequestered CO2 in these cores. Our results suggested that Illinois bituminous coal in its unperturbed state, i.e., when not pressurized with CO2, showed large variations in the mechanical properties. Modulus varied from 0.7 GPa to 3.4 GPa even though samples were extracted from a single large chunk of coal. We did not observe any glass transition for Illinois bituminous coal at - 100oC ≤ T ≤ 300oC, however, when the coal was pressurized with CO2 at ambient ≤ P ≤ 20.7 MPa, the viscosity of the coal decreased and inversely scaled with the CO2 pressure. The decrease in viscosity as a function of pressure could pose CO2 injection problems for coal as lower viscosity would allow the solid coal to flow to plug the fractures, fissures, and cleats. Our experiments also showed a very small fraction of CO2 was absorbed in coal; and when CO2 pressurized coals were exposed to atmospheric conditions, the loss of CO2 from coals was massive. Half of the sequestered gas from the coal cores was lost in less than 20 minutes. Our shockwave experiments on Illinois bituminous coal, New Albany shale (Illinois), Devonian shale (Ohio), and Utica shale (Ohio) presented clear evidence that the significant emission of the sequestered CO2 from these formations cannot be discounted during seismic activity, especially if caprock is compromised. It is argued that additional shockwave studies, both compressive and transverse, would be required for successfully mapping the risks associated with sequestering high pressure CO2 in coal and shale formations.

  9. U.S. Energy and Greenhouse Gas Model V2.0-2.X

    Energy Science and Technology Software Center (OSTI)

    2004-11-01

    The IJ.S. Energy and Greenhouse Gas Model (USEGM) is designed as a high-level dynamic simulation model to facilitate policy discussions on a real-time basis. The model focuses on U.S. energy demand by economic and electric power sectors through 2025, and is driven by gross domestic product (GOP), energy prices, energy intensities, and population effects. Price and GDP effects on energy demand are captured using a distributed lag model that allows demand to change over severalmore » years in response to price and GOP changes in a given year. Fuel allocation in the electricity sector is determined using a logistic formulation that takes into account relative electricity costs and existing capital allocation. Model outputs include energy demand by sector and type, carbon dioxide emissions, and oil import requirements.« less

  10. Idaho National Laboratory (INL) Site Greenhouse Gas (GHG) Monitoring Plan - 40 CFR 98

    SciTech Connect (OSTI)

    Deborah L. Layton; Kimberly Frerichs

    2011-12-01

    The purpose of this Greenhouse Gas (GHG) Monitoring Plan is to meet the monitoring plan requirements of Title 40 of the Code of Federal Regulations Part 98.3(g)(5). This GHG Monitoring Plan identifies procedures and methodologies used at the Idaho National Laboratory Site (INL Site) to collect data used for GHG emissions calculations and reporting requirements from stationary combustion and other regulated sources in accordance with 40 CFR 98, Subparts A and other applicable subparts. INL Site Contractors determined subpart applicability through the use of a checklist (Appendix A). Each facility/contractor reviews operations to determine which subparts are applicable and the results are compiled to determine which subparts are applicable to the INL Site. This plan is applicable to the 40 CFR 98-regulated activities managed by the INL Site contractors: Idaho National Laboratory (INL), Idaho Cleanup Project (ICP), Advanced Mixed Waste Treatment Project (AMWTP), and Naval Reactors Facilities (NRF).

  11. Opportunities to change development pathways toward lower greenhouse gas emissions through energy efficiency

    SciTech Connect (OSTI)

    Alterra, Swart; Masanet, Eric; Lecocq, Franck; Najam, Adil; Schaeffer, Robert; Winkler, Harald; Sathaye, Jayant

    2008-07-04

    There is a multiplicity of development pathways in which low energy sector emissions are not necessarily associated with low economic growth. However, changes in development pathways can rarely be imposed from the top. On this basis, examples of energy efficiency opportunities to change development pathways toward lower emissions are presented in this paper. We review opportunities at the sectoral and macro level. The potential for action on nonclimate policies that influence energy use and emissions are presented. Examples are drawn from policies already adopted and implemented in the energy sector. The paper discusses relationships between energy efficiency policies and their synergies and tradeoffs with sustainable development and greenhouse gas emissions. It points to ways that energy efficiency could be mainstreamed into devel?opment choices.

  12. Idaho National Laboratory (INL) Site Greenhouse Gas (GHG) Monitoring Plan - 40 CFR 98

    SciTech Connect (OSTI)

    Deborah L. Layton; Kimberly Frerichs

    2010-07-01

    The purpose of this Greenhouse Gas (GHG) Monitoring Plan is to meet the monitoring plan requirements of Title 40 of the Code of Federal Regulations Part 98.3(g)(5). This GHG Monitoring Plan identifies procedures and methodologies used at the Idaho National Laboratory Site (INL Site) to collect data used for GHG emissions calculations and reporting requirements from stationary combustion and other regulated sources in accordance with 40 CFR 98, Subparts A and other applicable subparts. INL Site Contractors determined subpart applicability through the use of a checklist (Appendix A). Each facility/contractor reviews operations to determine which subparts are applicable and the results are compiled to determine which subparts are applicable to the INL Site. This plan is applicable to the 40 CFR 98-regulated activities managed by the INL Site contractors: Idaho National Laboratory (INL), Idaho Cleanup Project (ICP), Advanced Mixed Waste Treatment Project (AMWTP), and Naval Reactors Facilities (NRF).

  13. Methods for ensuring compliance in an international greenhouse gas trading system

    SciTech Connect (OSTI)

    Hargrave, T.; Helme, E.A.

    1998-12-31

    At the third Conference of the Parties to the UN Framework Convention on Climate Change held in December, 1997, the international community established binding greenhouse gas (GHG) emissions obligations for industrialized countries. The Parties to the new Kyoto Protocol also agreed on the use of a number of market-based mechanisms, including international GHG emissions trading. These market mechanisms were of critical to the importance because they have the potential to significantly reduce the costs of treaty compliance. In principle, an international cap-and-trade system appears to be one of the most cost-effective means of reducing GHG emissions. Maintaining the integrity of the trading system is of primary importance in ensuring that trading helps countries to meet their GHG commitments. This paper explores methods for ensuring compliance in an international greenhouse gas trading system, starting with a discussion of preconditions for participation in trading and then moving to features of an international compliance system. Achieving maximum compliance with international requirements may best be accomplished by limiting participation in trading to Annex I countries that maintain strong domestic compliance systems. Prior to the climate negotiations in Kyoto in December 1997, the US Administration proposed a number of preconditions for participation in trading, including the adoption of international measurement standards and the establishment of domestic compliance and enforcement programs. This paper explores these and other preconditions, including the establishment of tough domestic financial penalties on companies that exceed allowed emissions and seller responsibility for the delivery of real reductions. The paper also discusses several necessary features of the international compliance system.

  14. Development of a Novel Gas Pressurized Process-Based Technology for CO2 Capture from Post-Combustion Flue Gases Preliminary Year 1 Techno-Economic Study Results and Methodology for Gas Pressurized Stripping Process

    SciTech Connect (OSTI)

    Chen, Shiaoguo

    2013-03-01

    Under the DOE’s Innovations for Existing Plants (IEP) Program, Carbon Capture Scientific, LLC (CCS) is developing a novel gas pressurized stripping (GPS) process to enable efficient post-combustion carbon capture (PCC) from coal-fired power plants. A technology and economic feasibility study is required as a deliverable in the project Statement of Project Objectives. This study analyzes a fully integrated pulverized coal power plant equipped with GPS technology for PCC, and is carried out, to the maximum extent possible, in accordance to the methodology and data provided in ATTACHMENT 3 – Basis for Technology Feasibility Study of DOE Funding Opportunity Number: DE-FOA-0000403. The DOE/NETL report on “Cost and Performance Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity (Original Issue Date, May 2007), NETL Report No. DOE/NETL-2007/1281, Revision 1, August 2007” was used as the main source of reference to be followed, as per the guidelines of ATTACHMENT 3 of DE-FOA-0000403. The DOE/NETL-2007/1281 study compared the feasibility of various combinations of power plant/CO2 capture process arrangements. The report contained a comprehensive set of design basis and economic evaluation assumptions and criteria, which are used as the main reference points for the purpose of this study. Specifically, Nexant adopted the design and economic evaluation basis from Case 12 of the above-mentioned DOE/NETL report. This case corresponds to a nominal 550 MWe (net), supercritical greenfield PC plant that utilizes an advanced MEAbased absorption system for CO2 capture and compression. For this techno-economic study, CCS’ GPS process replaces the MEA-based CO2 absorption system used in the original case. The objective of this study is to assess the performance of a full-scale GPS-based PCC design that is integrated with a supercritical PC plant similar to Case 12 of the DOE/NETL report, such that it corresponds to a nominal 550 MWe supercritical PC plant with 90% CO2 capture. This plant has the same boiler firing rate and superheated high pressure steam generation as the DOE/NETL report’s Case 12 PC plant. However, due to the difference in performance between the GPS-based PCC and the MEA-based CO2 absorption technology, the net power output of this plant may not be exactly at 550 MWe.

  15. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO₂ conversion into carbon-neutral fuels and chemicals November 6, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Environmentalists have long lamented the destructive effects of greenhouse gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,

  16. Comparing the greenhouse gas emissions from three alternative waste combustion concepts

    SciTech Connect (OSTI)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilae, Kai; Hupa, Mikko

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

  17. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study

    SciTech Connect (OSTI)

    2013-04-30

    BroadRock Renewables, LLC built two high efficiency electricity generating facilities that utilize landfill gas in California and Rhode Island. The two projects received a total of $25 million in U.S. Department of Energy funding from the American Recovery and Reinvestment Act (ARRA) of 2009. Private-sector cost share for the projects totaled approximately $186 million.

  18. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  19. Plant-wide dynamic simulation of an IGCC plant with CO2 capture

    SciTech Connect (OSTI)

    Bhattacharyya, D.; Turton, R.; Zitney, S.

    2009-01-01

    To eliminate the harmful effects of greenhouse gases, especially that of CO2, future coalfired power plants need to consider the option for CO2 capture. The loss in efficiency for CO2 capture is less in an Integrated Gasification Combined Cycle (IGCC) plant compared to other conventional coal combustion processes. However, no IGCC plant with CO2 capture currently exists in the world. Therefore, it is important to consider the operability and controllability issues of such a plant before it is commercially built. With this objective in mind, a detailed plant-wide dynamic simulation of an IGCC plant with CO2 capture has been developed. The plant considers a General Electric Energy (GEE)-type downflow radiant-only gasifier followed by a quench section. A two-stage water gas shift (WGS) reaction is considered for conversion of about 96 mol% of CO to CO2. A two-stage acid gas removal (AGR) process based on a physical solvent is simulated for selective capture of H2S and CO2. The clean syngas is sent to a gas turbine (GT) followed by a heat recovery steam generator (HRSG). The steady state results are validated with data from a commercial gasifier. A 5 % ramp increase in the flowrate of coal is introduced to study the system dynamics. To control the conversion of CO at a desired level in the WGS reactors, the steam/CO ratio is manipulated. This strategy is found to be efficient for this operating condition. In the absence of an efficient control strategy in the AGR process, the environmental emissions exceeded the limits by a great extent.

  20. The potential for biomass to mitigate greenhouse gas emissions in the Northeastern US. Northeast Regional Biomass Program

    SciTech Connect (OSTI)

    Bernow, S.S.; Gurney, K.; Prince, G.; Cyr, M.

    1992-04-01

    This study, for the Northeast Regional Biomass Program (NRBP) of the Coalition of Northeast Governors (CONEG), evaluates the potential for local, state and regional biomass policies to contribute to an overall energy/biomass strategy for the reduction of greenhouse gas releases in the Northeastern United States. Biomass is a conditionally renewable resource that can play a dual role: by reducing emissions of greenhouse gases in meeting our energy needs; and by removing carbon from the atmosphere and sequestering it in standing biomass stocks and long-lived products. In this study we examine the contribution of biomass to the energy system in the Northeast and to the region`s net releases of carbon dioxide and methane, and project these releases over three decades, given a continuation of current trends and policies. We then compare this Reference Case with three alternative scenarios, assuming successively more aggressive efforts to reduce greenhouse gas emissions through strategic implementation of energy efficiency and biomass resources. Finally, we identify and examine policy options for expanding the role of biomass in the region`s energy and greenhouse gas mitigation strategies.

  1. Hydrogen production and delivery analysis in US markets : cost, energy and greenhouse gas emissions.

    SciTech Connect (OSTI)

    Mintz, M.; Gillette, J.; Elgowainy, A.

    2009-01-01

    Hydrogen production cost conclusions are: (1) Steam Methane Reforming (SMR) is the least-cost production option at current natural gas prices and for initial hydrogen vehicle penetration rates, at high production rates, SMR may not be the least-cost option; (2) Unlike coal and nuclear technologies, the cost of natural gas feedstock is the largest contributor to SMR production cost; (3) Coal- and nuclear-based hydrogen production have significant penalties at small production rates (and benefits at large rates); (4) Nuclear production of hydrogen is likely to have large economies of scale, but because fixed O&M costs are uncertain, the magnitude of these effects may be understated; and (5) Given H2A default assumptions for fuel prices, process efficiencies and labor costs, nuclear-based hydrogen is likely to be more expensive to produce than coal-based hydrogen. Carbon taxes and caps can narrow the gap. Hydrogen delivery cost conclusions are: (1) For smaller urban markets, compressed gas delivery appears most economic, although cost inputs for high-pressure gas trucks are uncertain; (2) For larger urban markets, pipeline delivery is least costly; (3) Distance from hydrogen production plant to city gate may change relative costs (all results shown assume 100 km); (4) Pipeline costs may be reduced with system 'rationalization', primarily reductions in service pipeline mileage; and (5) Liquefier and pipeline capital costs are a hurdle, particularly at small market sizes. Some energy and greenhouse gas Observations: (1) Energy use (per kg of H2) declines slightly with increasing production or delivery rate for most components (unless energy efficiency varies appreciably with scale, e.g., liquefaction); (2) Energy use is a strong function of production technology and delivery mode; (3) GHG emissions reflect the energy efficiency and carbon content of each component in a production-delivery pathway; (4) Coal and natural gas production pathways have high energy consumption and significant GHG emissions (in the absence of carbon caps, taxes or sequestration); (5) Nuclear pathway is most favorable from energy use and GHG emissions perspective; (6) GH2 Truck and Pipeline delivery have much lower energy use and GHG emissions than LH2 Truck delivery; and (7) For LH2 Truck delivery, the liquefier accounts for most of the energy and GHG emissions.

  2. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-12-16

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

  3. Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2009 … Main Text

    National Nuclear Security Administration (NNSA)

    Emissions from Metallurgical Coke Production (Thousand Metric Tons) .............................................................................................................. 4-40 Table 4-56: Production and Consumption Data for the Calculation of CO 2 Emissions from Metallurgical Coke Production (million ft 3 ) ............................................................................................................................................ 4-41 Table 4-57: CO 2 Emission Factors

  4. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  5. Evaluation of metrics and baselines for tracking greenhouse gas emissions trends: Recommendations for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Murtishaw, Scott; Worrell, Ernst

    2003-06-01

    Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California Energy Commission (Energy Commission) related to the Registry in three areas: (1) assessing the availability and usefulness of industry-specific metrics, (2) evaluating various methods for establishing baselines for calculating GHG emissions reductions related to specific actions taken by Registry participants, and (3) establishing methods for calculating electricity CO2 emission factors. The third area of research was completed in 2002 and is documented in Estimating Carbon Dioxide Emissions Factors for the California Electric Power Sector (Marnay et al., 2002). This report documents our findings related to the first areas of research. For the first area of research, the overall objective was to evaluate the metrics, such as emissions per economic unit or emissions per unit of production that can be used to report GHG emissions trends for potential Registry participants. This research began with an effort to identify methodologies, benchmarking programs, inventories, protocols, and registries that u se industry-specific metrics to track trends in energy use or GHG emissions in order to determine what types of metrics have already been developed. The next step in developing industry-specific metrics was to assess the availability of data needed to determine metric development priorities. Berkeley Lab also determined the relative importance of different potential Registry participant categories in order to asses s the availability of sectoral or industry-specific metrics and then identified industry-specific metrics in use around the world. While a plethora of metrics was identified, no one metric that adequately tracks trends in GHG emissions while maintaining confidentiality of data was identified. As a result of this review, Berkeley Lab recommends the development of a GHG intensity index as a new metric for reporting and tracking GHG emissions trends.Such an index could provide an industry-specific metric for reporting and tracking GHG emissions trends to accurately reflect year to year changes while protecting proprietary data. This GHG intensity index changes while protecting proprietary data. This GHG intensity index would provide Registry participants with a means for demonstrating improvements in their energy and GHG emissions per unit of production without divulging specific values. For the second research area, Berkeley Lab evaluated various methods used to calculate baselines for documentation of energy consumption or GHG emissions reductions, noting those that use industry-specific metrics. Accounting for actions to reduce GHGs can be done on a project-by-project basis or on an entity basis. Establishing project-related baselines for mitigation efforts has been widely discussed in the context of two of the so-called ''flexible mechanisms'' of the Kyoto Protocol to the United Nations Framework Convention on Climate Change (Kyoto Protocol) Joint Implementation (JI) and the Clean Development Mechanism (CDM).

  6. Microsoft Word - CO2 Supplement.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding the Decline in Carbon Dioxide Emissions in 2009 1 EIA projects carbon dioxide (CO2) emissions from fossil fuels in 2009 to be 5.9 percent below the 2008 level in the Short-Term Energy Outlook, October 2009 (STEO) (Table 1). Projected coal CO2 emissions fall by 10.1 percent in 2009, primarily because of lower consumption for electricity generation. Coal accounts for 63 percent of the total decline in CO2 emissions from fossil fuels this year. Forecast lower natural gas and petroleum

  7. Near-Surface Co2 Monitoring And Analysis To Detect Hidden Geothermal...

    Open Energy Info (EERE)

    at dispersing CO2 seepage. In natural ecological systems in the absence of geothermal gas emissions, near-surface CO2 fluxes and concentrations are predominantly controlled by...

  8. Estimating the supply and demand for deep geologic CO2 storage capacity over the course of the 21st Century: A meta-analysis of the literature

    SciTech Connect (OSTI)

    Dooley, James J.

    2013-08-05

    Whether there is sufficient geologic CO2 storage capacity to allow CCS to play a significant role in mitigating climate change has been the subject of debate since the 1990s. This paper presents a meta- analysis of a large body of recently published literature to derive updated estimates of the global deep geologic storage resource as well as the potential demand for this geologic CO2 storage resource over the course of this century. This analysis reveals that, for greenhouse gas emissions mitigation scenarios that have end-of-century atmospheric CO2 concentrations of between 350 ppmv and 725 ppmv, the average demand for deep geologic CO2 storage over the course of this century is between 410 GtCO2 and 1,670 GtCO2. The literature summarized here suggests that -- depending on the stringency of criteria applied to calculate storage capacity global geologic CO2 storage capacity could be: 35,300 GtCO2 of theoretical capacity; 13,500 GtCO2 of effective capacity; 3,900 GtCO2, of practical capacity; and 290 GtCO2 of matched capacity for the few regions where this narrow definition of capacity has been calculated. The cumulative demand for geologic CO2 storage is likely quite small compared to global estimates of the deep geologic CO2 storage capacity, and therefore, a lack of deep geologic CO2 storage capacity is unlikely to be an impediment for the commercial adoption of CCS technologies in this century.

  9. Alternatives to Traditional Transportation Fuels 1994 Volume 2 Greenhouse Gas Emissions

    Reports and Publications (EIA)

    1996-01-01

    This report provides information on greenhouse gases GHGs) as required by Section 503 a(4) and b(3) of the Energy Policy Act of 1992 (EPACT).

  10. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a methodmore » for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.« less

  11. Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils

    SciTech Connect (OSTI)

    Jeremy Semrau; Sung-Woo Lee; Jeongdae Im; Sukhwan Yoon; Michael Barcelona

    2010-09-30

    The overall objective of this project, 'Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils' was to develop effective, efficient, and economic methodologies by which microbial production of nitrous oxide can be minimized while also maximizing microbial consumption of methane in landfill cover soils. A combination of laboratory and field site experiments found that the addition of nitrogen and phenylacetylene stimulated in situ methane oxidation while minimizing nitrous oxide production. Molecular analyses also indicated that methane-oxidizing bacteria may play a significant role in not only removing methane, but in nitrous oxide production as well, although the contribution of ammonia-oxidizing archaea to nitrous oxide production can not be excluded at this time. Future efforts to control both methane and nitrous oxide emissions from landfills as well as from other environments (e.g., agricultural soils) should consider these issues. Finally, a methanotrophic biofiltration system was designed and modeled for the promotion of methanotrophic activity in local methane 'hotspots' such as landfills. Model results as well as economic analyses of these biofilters indicate that the use of methanotrophic biofilters for controlling methane emissions is technically feasible, and provided either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive.

  12. Impacts of Vehicle Weight Reduction via Material Substitution on Life-Cycle Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Kelly, Jarod C.; Sullivan, John L.; Burnham, Andrew; Elgowainy, Amgad

    2015-10-20

    This study examines the vehicle-cycle impacts associated with substituting lightweight materials for those currently found in light-duty passenger vehicles. We determine part-based energy use and greenhouse gas (GHG) emission ratios by collecting material substitution data from both the literature and automotive experts and evaluating that alongside known mass-based energy use and GHG emission ratios associated with material pair substitutions. Several vehicle parts, along with full vehicle systems, are examined for lightweighting via material substitution to observe the associated impact on GHG emissions. Results are contextualized by additionally examining fuel-cycle GHG reductions associated with mass reductions relative to the baseline vehicle during the use phase and also determining material pair breakeven driving distances for GHG emissions. The findings show that, while material substitution is useful in reducing vehicle weight, it often increases vehicle-cycle GHGs depending upon the material substitution pair. However, for a vehicles total life cycle, fuel economy benefits are greater than the increased burdens associated with the vehicle manufacturing cycle, resulting in a net total life-cycle GHG benefit. The vehicle cycle will become increasingly important in total vehicle life-cycle GHGs, since fuel-cycle GHGs will be gradually reduced as automakers ramp up vehicle efficiency to meet fuel economy standards.

  13. Non-Kyoto Radiative Forcing in Long-Run Greenhouse Gas Emissions and Climate Change Scenarios

    SciTech Connect (OSTI)

    Rose, Steven K.; Richels, Richard G.; Smith, Steven J.; Riahi, Keywan; Stefler, Jessica; Van Vuuren, Detlef

    2014-04-27

    Climate policies designed to achieve climate change objectives must consider radiative forcing from the Kyoto greenhouse gas, as well as other forcing constituents, such as aerosols and tropospheric ozone. Net positive forcing leads to global average temperature increases. Modeling of non-Kyoto forcing is a relatively new component of climate management scenarios. Five of the nineteen models in the EMF-27 Study model both Kyoto and non-Kyoto forcing. This paper describes and assesses current non-Kyoto radiative forcing modeling within these integrated assessment models. The study finds negative forcing from aerosols masking significant positive forcing in reference non-climate policy projections. There are however large differences across models in projected non-Kyoto emissions and forcing, with differences stemming from differences in relationships between Kyoto and non-Kyoto emissions and fundamental differences in modeling structure and assumptions. Air pollution and non-Kyoto forcing decline in the climate policy scenarios. However, non-Kyoto forcing appears to be influencing mitigation results, including allowable carbon dioxide emissions, and further evaluation is merited. Overall, there is substantial uncertainty related to non-Kyoto forcing that must be considered.

  14. Novel pathways for fuels and lubricants from biomass optimized using life-cycle greenhouse gas assessment

    SciTech Connect (OSTI)

    Balakrishnan, Madhesan; Sacia, Eric R.; Sreekumar, Sanil; Gunbas, Gorkem; Gokhale, Amit A.; Scown, Corinne D.; Toste, F. Dean; Bell, Alexis T.

    2015-06-08

    Decarbonizing the transportation sector is critical to achieving global climate change mitigation. Although biofuels will play an important role in conventional gasoline and diesel applications, bioderived solutions are particularly important in jet fuels and lubricants, for which no other viable renewable alternatives exist. Producing compounds for jet fuel and lubricant base oil applications often requires upgrading fermentation products, such as alcohols and ketones, to reach the appropriate molecular-weight range. Ketones possess both electrophilic and nucleophilic functionality, which allows them to be used as building blocks similar to alkenes and aromatics in a petroleum refining complex. Here, we develop a method for selectively upgrading biomass-derived alkyl methyl ketones with >95% yields into trimer condensates, which can then be hydrodeoxygenated in near-quantitative yields to give a new class of cycloalkane compounds. The basic chemistry developed here can be tailored for aviation fuels as well as lubricants by changing the production strategy. We demonstrate that a sugarcane biorefinery could use natural synergies between various routes to produce a mixture of lubricant base oils and jet fuels that achieve net life-cycle greenhouse gas savings of up to 80%.

  15. A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K.; Dimotakis, Paul E.; Walker, Bruce C.

    2011-09-26

    This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS.

  16. Incorporating Agricultural Management Practices into the Assessment of Soil Carbon Change and Life-Cycle Greenhouse Gas Emissions of Corn Stover Ethanol Production

    SciTech Connect (OSTI)

    Qin, Zhangcai; Canter, Christina E.; Dunn, Jennifer B.; Mueller, Steffen; Kwon, Ho-young; Han, Jeongwoo; Wander, Michelle M.; Wang, Michael

    2015-09-01

    Land management practices such as cover crop adoption or manure application that can increase soil organic carbon (SOC) may provide a way to counter SOC loss upon removal of stover from corn fields for use as a biofuel feedstock. This report documents the data, methodology, and assumptions behind the incorporation of land management practices into corn-soybean systems that dominate U.S. grain production using varying levels of stover removal in the GREETTM (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) model and its CCLUB (Carbon Calculator for Land Use change from Biofuels production) module. Tillage (i.e., conventional, reduced and no tillage), corn stover removal (i.e., at 0, 30% and 60% removal rate), and organic matter input techniques (i.e., cover crop and manure application) are included in the analysis as major land management practices. Soil carbon changes associated with land management changes were modeled with a surrogate CENTURY model. The resulting SOC changes were incorporated into CCLUB while GREET was expanded to include energy and material consumption associated with cover crop adoption and manure application. Life-cycle greenhouse gas (GHG) emissions of stover ethanol were estimated using a marginal approach (all burdens and benefits assigned to corn stover ethanol) and an energy allocation approach (burdens and benefits divided between grain and stover ethanol). In the latter case, we considered corn grain and corn stover ethanol to be produced at an integrated facility. Life-cycle GHG emissions of corn stover ethanol are dependent upon the analysis approach selected (marginal versus allocation) and the land management techniques applied. The expansion of CCLUB and GREET to accommodate land management techniques can produce a wide range of results because users can select from multiple scenario options such as choosing tillage levels, stover removal rates, and whether crop yields increase annually or remain constant. In a scenario with conventional tillage and a 30% stover removal rate, life-cycle GHG emissions for a combined gallon of corn grain and stover ethanol without cover crop adoption or manure application are 49 g CO2eq MJ-1, in comparison with 91 g CO2eq MJ-1 for petroleum gasoline. Adopting a cover crop or applying manure reduces the former ethanol life-cycle GHG emissions by 8% and 10%, respectively. We considered two different life cycle analysis approaches to develop estimates of life-cycle GHG emissions for corn stover ethanol, marginal analysis and energy allocation. In the same scenario, this fuel has GHG emissions of 12 20 g CO2eq MJ-1 (for manure and cover crop application, respectively) and 45 48 g CO2eq MJ-1 with the marginal approach and the energy allocation approach, respectively.

  17. Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reduction | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Covalent Organic Frameworks Comprising Cobalt Porphyrins for Catalytic CO2 Reduction

  18. CO{sub 2} Allowance Allocation in the Regional Greenhouse Gas Initiative and the Effect on Electricity Investors

    SciTech Connect (OSTI)

    Burtraw, Dallas; Kahn, Danny; Palmer, Karen

    2006-03-01

    The Regional Greenhouse Gas Initiative among Northeastern states is expected to lead to an increase in the price of electricity in the region and beyond. In the RGGI region, changes in the value of electricity-generating assets may be positive or negative, while changes outside the Northeast are virtually always positive. For stakeholders in the industry, the change depends on the portfolio of assets held by affected firms. (author)

  19. Energy and greenhouse gas emission effects of corn and cellulosic ethanol with technology improvements and land use changes.

    SciTech Connect (OSTI)

    Wang, M.; Han, J.; Haq, Z; Tyner, .W.; Wu, M.; Elgowainy, A.

    2011-05-01

    Use of ethanol as a transportation fuel in the United States has grown from 76 dam{sup 3} in 1980 to over 40.1 hm{sup 3} in 2009 - and virtually all of it has been produced from corn. It has been debated whether using corn ethanol results in any energy and greenhouse gas benefits. This issue has been especially critical in the past several years, when indirect effects, such as indirect land use changes, associated with U.S. corn ethanol production are considered in evaluation. In the past three years, modeling of direct and indirect land use changes related to the production of corn ethanol has advanced significantly. Meanwhile, technology improvements in key stages of the ethanol life cycle (such as corn farming and ethanol production) have been made. With updated simulation results of direct and indirect land use changes and observed technology improvements in the past several years, we conducted a life-cycle analysis of ethanol and show that at present and in the near future, using corn ethanol reduces greenhouse gas emission by more than 20%, relative to those of petroleum gasoline. On the other hand, second-generation ethanol could achieve much higher reductions in greenhouse gas emissions. In a broader sense, sound evaluation of U.S. biofuel policies should account for both unanticipated consequences and technology potentials. We maintain that the usefulness of such evaluations is to provide insight into how to prevent unanticipated consequences and how to promote efficient technologies with policy intervention.

  20. Using Cool Roofs to Reduce Energy Use, Greenhouse Gas Emissions, and Urban Heat-island Effects: Findings from an India Experiment

    SciTech Connect (OSTI)

    Akbari, Hashem; Xu, Tengfang; Taha, Haider; Wray, Craig; Sathaye, Jayant; Garg, Vishal; Tetali, Surekha; Babu, M. Hari; Reddy, K. Niranjan

    2011-05-25

    Cool roofs, cool pavements, and urban vegetation reduce energy use in buildings, lower local air pollutant concentrations, and decrease greenhouse gas emissions from urban areas. This report summarizes the results of a detailed monitoring project in India and related simulations of meteorology and air quality in three developing countries. The field results quantified direct energy savings from installation of cool roofs on individual commercial buildings. The measured annual energy savings potential from roof-whitening of previously black roofs ranged from 20-22 kWh/m2 of roof area, corresponding to an air-conditioning energy use reduction of 14-26% in commercial buildings. The study estimated that typical annual savings of 13-14 kWh/m2 of roof area could be achieved by applying white coating to uncoated concrete roofs on commercial buildings in the Metropolitan Hyderabad region, corresponding to cooling energy savings of 10-19%. With the assumption of an annual increase of 100,000 square meters of new roof construction for the next 10 years in the Metropolitan Hyderabad region, the annual cooling energy savings due to whitening concrete roof would be 13-14 GWh of electricity in year ten alone, with cumulative 10-year cooling energy savings of 73-79 GWh for the region. The estimated savings for the entire country would be at least 10 times the savings in Hyderabad, i.e., more than 730-790 GWh. We estimated that annual direct CO2 reduction associated with reduced energy use would be 11-12 kg CO2/m2 of flat concrete roof area whitened, and the cumulative 10-year CO2 reduction would be approximately 0.60-0.65 million tons in India. With the price of electricity estimated at seven Rupees per kWh, the annual electricity savings on air-conditioning would be approximately 93-101 Rupees per m2 of roof. This would translate into annual national savings of approximately one billion Rupees in year ten, and cumulative 10-year savings of over five billion Rupees for cooling energy in India. Meteorological simulations in this study indicated that a reduction of 2C in air temperature in the Hyderabad area would be likely if a combination of increased surface albedo and vegetative cover are used as urban heat-island control strategies. In addition, air-temperature reductions on the order of 2.5-3.5C could be achieved if moderate and aggressive heat-island mitigation measures are adopted, respectively. A large-scale deployment of mitigation measures can bring additional indirect benefit to the urban area. For example, cooling outside air can improve the efficiency of cooling systems, reduce smog and greenhouse gas (GHG) emissions, and indirectly reduce pollution from power plants - all improving environmental health quality. This study has demonstrated the effectiveness of cool-roof technology as one of the urban heat-island control strategies for the Indian industrial and scientific communities and has provided an estimate of the national energy savings potential of cool roofs in India. These outcomes can be used for developing cool-roof building standards and related policies in India. Additional field studies, built upon the successes and lessons learned from this project, may be helpful to further confirm the scale of potential energy savings from the application of cooler roofs in various regions of India. In the future, a more rigorous meteorological simulation using urbanized (meso-urban) meteorological models should be conducted, which may produce a more accurate estimate of the air-temperature reductions for the entire urban area.

  1. An expanded review and comparison of greenhouse gas emissions from fossil fuel and geothermal electrical generating facilities

    SciTech Connect (OSTI)

    Booth, R.B.; Neil, P.E.

    1998-12-31

    This paper provides a review of the greenhouse gas emissions due to fossil fuel and geothermal electrical generation and to the emissions of their respective support activities. These support activities consist of, exploration, development, and transportation aspects of the fuel source, including waste management. These support activities could amount to an additional 6% for coal, 22% for oil, 13% for natural gas and 1% for geothermal. The presented methodologies and underlying principles can be used to better define the resultant emissions, rankings and global impacts of these electrical generating industries.

  2. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  3. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Warner, E. S.; Heath, G. A.

    2012-04-01

    A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

  4. Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery

    SciTech Connect (OSTI)

    Yang Na; Zhang Hua; Chen Miao; Shao Liming; He Pinjing

    2012-12-15

    Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

  5. Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems - A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems - A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions May 2005 Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems - A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions Norman Brinkman, General Motors Corporation Michael Wang, Argonne National Laboratory Trudy Weber, General Motors Corporation Thomas Darlington, Air Improvement Resource, Inc. May

  6. Spatial Disaggregation of CO2 Emissions for the State of California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; de la Rue du Can, Stephane; Wenzel, Tom; Fischer, Marc

    2008-06-11

    This report allocates California's 2004 statewide carbon dioxide (CO2) emissions from fuel combustion to the 58 counties in the state. The total emissions are allocated to counties using several different methods, based on the availability of data for each sector. Data on natural gas use in all sectors are available by county. Fuel consumption by power and combined heat and power generation plants is available for individual plants. Bottom-up models were used to distribute statewide fuel sales-based CO2 emissions by county for on-road vehicles, aircraft, and watercraft. All other sources of CO2 emissions were allocated to counties based on surrogates for activity. CO2 emissions by sector were estimated for each county, as well as for the South Coast Air Basin. It is important to note that emissions from some sources, notably electricity generation, were allocated to counties based on where the emissions were generated, rather than where the electricity was actually consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported from other states and international marine bunker fuels, were not included in the analysis. California Air Resource Board (CARB) does not include CO2 emissions from interstate and international air travel, in the official California greenhouse gas (GHG) inventory, so those emissions were allocated to counties for informational purposes only. Los Angeles County is responsible for by far the largest CO2 emissions from combustion in the state: 83 Million metric tonnes (Mt), or 24percent of total CO2 emissions in California, more than twice that of the next county (Kern, with 38 Mt, or 11percent of statewide emissions). The South Coast Air Basin accounts for 122 MtCO2, or 35percent of all emissions from fuel combustion in the state. The distribution of emissions by sector varies considerably by county, with on-road motor vehicles dominating most counties, but large stationary sources and rail travel dominating in other counties.The CO2 emissions data by county and source are available upon request.

  7. Global warming commitment concept and its application for relative evaluation of greenhouse gas current and future radiative forcing

    SciTech Connect (OSTI)

    Karol, I.L.; Frolkis, V.A.; Kiselev, A.A.

    1996-12-31

    The Global Warming Commitment (GWC) of gas X relative to standard gas A for time period T is proposed, as determined by the formula GWC{sub X}{sup T} = {integral}RF{sub X}(t)dt/{integral}RF{sub A}(t)dt both integrals between limits 0 and T, where RF{sub X}(t) = {Delta}F{sub X}(t) is the Radiative Forcing (RF) of gas X (the net total radiation flux change at the tropopause level caused by the gas X content variation during the 0 to t time period). The well known Global Warming Potential (GWP) is determined by the same formula, where {Delta}F{sub x}(t) is due to instantaneous releases into the atmosphere of the same definite mass (1 kg) of gas X and of standard gas A. In GWC the actual measured or modeled gas contents evolutions are used for estimation of gas X relative input into the current and future greenhouse warming. GWC of principal Greenhouse Gases (GG) are calculated and analyzed for the time period before 1990, based on observed GG content evolution. For periods from now to 2050 the modeled global GG content projections from radiative photochemical atmospheric model are used for several of IPCC-94 scenarios of GG anthropogenic emissions up to 2050. The GWC of CH{sub 4}, N{sub 2}O and CFCs with CO{sub 2} as standard GG are 2--4 times lower, and they are much more accurately reflecting the reality in the above periods than the widely used RFs of these GG relative to GG of CO{sub 2}, when the GG content evolutions during the time period T is not considered.

  8. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluating a new approach to CO2 capture and storage Evaluating a new approach to CO2 capture and storage In a perspective paper published in Greenhouse Gases: Science and Technology, researchers examined a new approach that could potentially overcome many barriers to deployment and jumpstart this process on a commercial scale. September 13, 2015 Map of the contiguous United States shows the location of facilities that produce high-value chemicals/products and the amount of carbon dioxide

  9. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  10. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James OBrien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  11. Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced Biomass Feedstock Logistics Supply Chains in Kansas

    SciTech Connect (OSTI)

    Cafferty, Kara G.; Searcy, Erin M.; Nguyen, Long; Spatari, Sabrina

    2014-11-01

    To meet Energy Independence and Security Act (EISA) cellulosic biofuel mandates, the United States will require an annual domestic supply of about 242 million Mg of biomass by 2022. To improve the feedstock logistics of lignocellulosic biofuels and access available biomass resources from areas with varying yields, commodity systems have been proposed and designed to deliver on-spec biomass feedstocks at preprocessing “depots”, which densify and stabilize the biomass prior to long-distance transport and delivery to centralized biorefineries. The harvesting, preprocessing, and logistics (HPL) of biomass commodity supply chains thus could introduce spatially variable environmental impacts into the biofuel life cycle due to needing to harvest, move, and preprocess biomass from multiple distances that have variable spatial density. This study examines the uncertainty in greenhouse gas (GHG) emissions of corn stover logisticsHPL within a bio-ethanol supply chain in the state of Kansas, where sustainable biomass supply varies spatially. Two scenarios were evaluated each having a different number of depots of varying capacity and location within Kansas relative to a central commodity-receiving biorefinery to test GHG emissions uncertainty. Monte Carlo simulation was used to estimate the spatial uncertainty in the HPL gate-to-gate sequence. The results show that the transport of densified biomass introduces the highest variability and contribution to the carbon footprint of the logistics HPL supply chain (0.2-13 g CO2e/MJ). Moreover, depending upon the biomass availability and its spatial density and surrounding transportation infrastructure (road and rail), logistics HPL processes can increase the variability in life cycle environmental impacts for lignocellulosic biofuels. Within Kansas, life cycle GHG emissions could range from 24 to 41 g CO2e/MJ depending upon the location, size and number of preprocessing depots constructed. However, this range can be minimized through optimizing the siting of preprocessing depots where ample rail infrastructure exists to supply biomass commodity to a regional biorefinery supply system

  12. Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill

    SciTech Connect (OSTI)

    Wang, Xiaojun; Jia, Mingsheng; Chen, Xiaohai; Xu, Ying; Lin, Xiangyu; Kao, Chih Ming; Chen, Shaohua

    2014-07-15

    Highlights: • Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup −1}. • Fresh leachate owned extremely low ORP and high organic matter content. • Strong CH{sub 4} emissions occurred in the fresh leachate ponds, but small in the aged. • N{sub 2}O emissions became dominant in the treatment units of both systems. • 8.45–11.9% of nitrogen was removed as the form of N{sub 2}O under steady-state. - Abstract: With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH{sub 4} emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m{sup −2} h{sup −1}) extremely higher than those of N{sub 2}O (0.028–0.41 mg N m{sup −2} h{sup −1}). In contrast, the emission values for both CH{sub 4} and N{sub 2}O were low for the aged leachate tank. N{sub 2}O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N{sub 2}O emission based on both leachate treatment systems was estimated to be 7.99 g N{sub 2}O–N capita{sup −1} yr{sup −1}. An increase of 80% in N{sub 2}O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO{sub 2}, with a small portion as CH{sub 4} (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO{sub 2} eq yr{sup −1}, respectively, for a total that could be transformed to 9.09 kg CO{sub 2} eq capita{sup −1} yr{sup −1}.

  13. Strategies for the Commercialization and Deployment of Greenhouse Gas Intensity-Reducing Technologies and Practices

    SciTech Connect (OSTI)

    Committee on Climate Change Science and Technology Integration

    2009-01-01

    New technologies will be a critical component--perhaps the critical component--of our efforts to tackle the related challenges of energy security, climate change, and air pollution, all the while maintaining a strong economy. But just developing new technologies is not enough. Our ability to accelerate the market penetration of clean energy, enabling, and other climate-related technologies will have a determining impact on our ability to slow, stop, and reverse the growth in greenhouse gas (GHG) emissions. Title XVI, Subtitle A, of the Energy Policy Act of 2005 (EPAct 2005) directs the Administration to report on its strategy to promote the commercialization and deployment (C&D) of GHG intensity-reducing technologies and practices. The Act also requests the Administration to prepare an inventory of climate-friendly technologies suitable for deployment and to identify the barriers and commercial risks facing advanced technologies. Because these issues are related, they are integrated here within a single report that we, representing the Committee on Climate Change Science and Technology Integration (CCCSTI), are pleased to provide the President, the Congress, and the public. Over the past eight years, the Administration of President George W. Bush has pursued a series of policies and measures aimed at encouraging the development and deployment of advanced technologies to reduce GHG emissions. This report highlights these policies and measures, discusses the barriers to each, and integrates them within a larger body of other extant policy. Taken together, more than 300 policies and measures described in this document may be viewed in conjunction with the U.S. Climate Change Technology Program's (CCTP's) Strategic Plan, published in September 2006, which focuses primarily on the role of advanced technology and associated research and development (R&D) for mitigating GHG emissions. The CCTP, a multi-agency technology planning and coordination program, initiated by President Bush, and subsequently authorized in EPAct2005, is responsible for preparing this report on behalf CCCSTI. This report systematically examines the market readiness of key technologies important to meeting climate change mitigation goals. It assesses the barriers and business risks impeding their progress and greater market application. Importantly, by documenting the hundreds of Federal policies, programs, regulations, incentives, and other activities that are in effect and operating today to address these barriers, it provides a broad context for evaluating the adequacy of current policy and the potential need, if any, for additional measures that might be undertaken by government or industry. Finally, it draws conclusions about the current situation, identifies gaps and opportunities, and suggests analytical principles that should be applied to assess and formulate policies and measures to accelerate the commercialization and deployment of these technologies.

  14. Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2009 … Main Text

    National Nuclear Security Administration (NNSA)

    xiii Table 4-82: HCFC-22 Production (Gg) .................................................................................................................. 4-61 Table 4-83: Quantitative Uncertainty Estimates for HFC-23 Emissions from HCFC-22 Production (Tg CO 2 Eq. and Percent) .................................................................................................................................................................... 4-62 Table 4-84: Emissions of HFCs and PFCs from ODS

  15. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect (OSTI)

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  16. Greenhouse Emission Reductions and Natural Gas Vehicles: A Resource Guide on Technology Options and Project Development

    SciTech Connect (OSTI)

    Orestes Anastasia; NAncy Checklick; Vivianne Couts; Julie Doherty; Jette Findsen; Laura Gehlin; Josh Radoff

    2002-09-01

    Accurate and verifiable emission reductions are a function of the degree of transparency and stringency of the protocols employed in documenting project- or program-associated emissions reductions. The purpose of this guide is to provide a background for law and policy makers, urban planners, and project developers working with the many Greenhouse Gas (GHG) emission reduction programs throughout the world to quantify and/or evaluate the GHG impacts of Natural Gas Vehicle (NGVs). In order to evaluate the GHG benefits and/or penalties of NGV projects, it is necessary to first gain a fundamental understanding of the technology employed and the operating characteristics of these vehicles, especially with regard to the manner in which they compare to similar conventional gasoline or diesel vehicles. Therefore, the first two sections of this paper explain the basic technology and functionality of NGVs, but focus on evaluating the models that are currently on the market with their similar conventional counterparts, including characteristics such as cost, performance, efficiency, environmental attributes, and range. Since the increased use of NGVs, along with Alternative Fuel Vehicle (AFVs) in general, represents a public good with many social benefits at the local, national, and global levels, NGVs often receive significant attention in the form of legislative and programmatic support. Some states mandate the use of NGVs, while others provide financial incentives to promote their procurement and use. Furthermore, Federal legislation in the form of tax incentives or procurement requirements can have a significant impact on the NGV market. In order to implement effective legislation or programs, it is vital to have an understanding of the different programs and activities that already exist so that a new project focusing on GHG emission reduction can successfully interact with and build on the experience and lessons learned of those that preceded it. Finally, most programs that deal with passenger vehicles--and with transportation in general--do not address the climate change component explicitly, and thus there are few GHG reduction goals that are included in these programs. Furthermore, there are relatively few protocols that exist for accounting for the GHG emissions reductions that arise from transportation and, specifically, passenger vehicle projects and programs. These accounting procedures and principles gain increased importance when a project developer wishes to document in a credible manner, the GHG reductions that are achieved by a given project or program. Section four of this paper outlined the GHG emissions associated with NGVs, both upstream and downstream, and section five illustrated the methodology, via hypothetical case studies, for measuring these reductions using different types of baselines. Unlike stationary energy combustion, GHG emissions from transportation activities, including NGV projects, come from dispersed sources creating a need for different methodologies for assessing GHG impacts. This resource guide has outlined the necessary context and background for those parties wishing to evaluate projects and develop programs, policies, projects, and legislation aimed at the promotion of NGVs for GHG emission reduction.

  17. Building Commissioning: A Golden Opportunity for Reducing Energy Costs and Greenhouse-gas Emissions

    SciTech Connect (OSTI)

    Mills, Evan

    2009-07-16

    The aim of commissioning new buildings is to ensure that they deliver, if not exceed, the performance and energy savings promised by their design. When applied to existing buildings, commissioning identifies the almost inevitable 'drift' from where things should be and puts the building back on course. In both contexts, commissioning is a systematic, forensic approach to quality assurance, rather than a technology per se. Although commissioning has earned increased recognition in recent years - even a toehold in Wikipedia - it remains an enigmatic practice whose visibility severely lags its potential. Over the past decade, Lawrence Berkeley National Laboratory has built the world's largest compilation and meta-analysis of commissioning experience in commercial buildings. Since our last report (Mills et al. 2004) the database has grown from 224 to 643 buildings (all located in the United States, and spanning 26 states), from 30 to 100 million square feet of floorspace, and from $17 million to $43 million in commissioning expenditures. The recorded cases of new-construction commissioning took place in buildings representing $2.2 billion in total construction costs (up from 1.5 billion). The work of many more commissioning providers (18 versus 37) is represented in this study, as is more evidence of energy and peak-power savings as well as cost-effectiveness. We now translate these impacts into avoided greenhouse gases and provide new indicators of cost-effectiveness. We also draw attention to the specific challenges and opportunities for high-tech facilities such as labs, cleanrooms, data centers, and healthcare facilities. The results are compelling. We developed an array of benchmarks for characterizing project performance and cost-effectiveness. The median normalized cost to deliver commissioning was $0.30/ft2 for existing buildings and $1.16/ft2 for new construction (or 0.4% of the overall construction cost). The commissioning projects for which data are available revealed over 10,000 energy-related problems, resulting in 16% median whole-building energy savings in existing buildings and 13% in new construction, with payback time of 1.1 years and 4.2 years, respectively. In terms of other cost-benefit indicators, median benefit-cost ratios of 4.5 and 1.1, and cash-on-cash returns of 91% and 23% were attained for existing and new buildings, respectively. High-tech buildings were particularly cost-effective, and saved higher amounts of energy due to their energy-intensiveness. Projects with a comprehensive approach to commissioning attained nearly twice the overall median level of savings and five-times the savings of the least-thorough projects. It is noteworthy that virtually all existing building projects were cost-effective by each metric (0.4 years for the upper quartile and 2.4 years for the lower quartile), as were the majority of new-construction projects (1.5 years and 10.8 years, respectively). We also found high cost-effectiveness for each specific measure for which we have data. Contrary to a common perception, cost-effectiveness is often achieved even in smaller buildings. Thanks to energy savings valued more than the cost of the commissioning process, associated reductions in greenhouse gas emissions come at 'negative' cost. In fact, the median cost of conserved carbon is negative - -$110 per tonne for existing buildings and -$25/tonne for new construction - as compared with market prices for carbon trading and offsets in the +$10 to +$30/tonne range. Further enhancing the value of commissioning, its non-energy benefits surpass those of most other energy-management practices. Significant first-cost savings (e.g., through right-sizing of heating and cooling equipment) routinely offset at least a portion of commissioning costs - fully in some cases. When accounting for these benefits, the net median commissioning project cost was reduced by 49% on average, while in many cases they exceeded the direct value of the energy savings. Commissioning also improves worker comfort, mitigates indoor air quality problems

  18. ARM - Instrument - co2flx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentsco2flx Documentation CO2FLX : Handbook ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Carbon Dioxide Flux Measurement Systems (CO2FLX) Instrument Categories Atmospheric Carbon General Overview The Southern Great Plains (SGP) carbon dioxide flux (CO2 flux) measurement systems provide half-hour average fluxes of CO2, H2O (latent heat), and sensible heat. The fluxes are obtained by the eddy

  19. Flint Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Flint Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Flint...

  20. Bigfork Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Bigfork Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Bigfork Greenhouses Greenhouse Low Temperature Geothermal Facility Facility...

  1. Crook's Greenhouse Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Crook's Greenhouse Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Crook's Greenhouse Greenhouse Low Temperature Geothermal Facility Facility...

  2. Castlevalley Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Castlevalley Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Castlevalley Greenhouses Greenhouse Low Temperature Geothermal Facility...

  3. A greenhouse-gas information system monitoring and validating emissions reporting and mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K; Dimotakis, Paul E; Walker, Bruce C

    2011-09-26

    Current GHG-mitigating regimes, whether internationally agreed or self-imposed, rely on the aggregation of self-reported data, with limited checks for consistency and accuracy, for monitoring. As nations commit to more stringent GHG emissions-mitigation actions and as economic rewards or penalties are attached to emission levels, self-reported data will require independent confirmation that they are accurate and reliable, if they are to provide the basis for critical choices and actions that may be required. Supporting emissions-mitigation efforts and agreements, as well as monitoring energy- and fossil-fuel intensive national and global activities would be best achieved by a process of: (1) monitoring of emissions and emission-mitigation actions, based, in part, on, (2) (self-) reporting of pertinent bottom-up inventory data, (3) verification that reported data derive from and are consistent with agreed-upon processes and procedures, and (4) validation that reported emissions and emissions-mitigation action data are correct, based on independent measurements (top-down) derived from a suite of sensors in space, air, land, and, possibly, sea, used to deduce and attribute anthropogenic emissions. These data would be assessed and used to deduce and attribute measured GHG concentrations to anthropogenic emissions, attributed geographically and, to the extent possible, by economic sector. The validation element is needed to provide independent assurance that emissions are in accord with reported values, and should be considered as an important addition to the accepted MRV process, leading to a MRV&V process. This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS. Present monitoring systems would be heavily relied on in any GHGIS implementation at the outset and would likely continue to provide valuable future contributions to GHGIS. However, present monitoring systems were developed to serve science/research purposes. This study concludes that no component or capability presently available is at the level of technological maturity and readiness required for implementation in an operational GHGIS today. However, purpose-designed and -built components could be developed and implemented in support of a future GHGIS. The study concludes that it is possible to develop and provide a capability-driven prototype GHGIS, as part of a Phase-1 effort, within three years from project-funding start, that would make use of and integrate existing sensing and system capabilities. As part of a Phase-2 effort, a requirements-driven, operational GHGIS could be developed, within ten years from project funding start. That schedule is driven by the development and long lead-times for some system components. The two efforts would be focused on different deliverables but could commence concurrently, to save time, if that was deemed desirable. We note that, developing and supporting an operational GHGIS will require a new approach and management, sustained funding and other support, as well as technical advances and development of purpose-built components that meet the requisite specifications. A functioning GHGIS will provide the basis for reasoned choices on how best to respond to rising GHG levels, especially when proposed U.S. actions are compared with or conditioned on the actions of other nations.

  4. Trinity CO2 LLC | Open Energy Information

    Open Energy Info (EERE)

    CO2 LLC Jump to: navigation, search Name: Trinity CO2 LLC Place: Texas Product: String representation "Trinity CO2 LLC ... smission lines." is too long. References: Trinity CO2...

  5. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    greenhouse gas emissions and improve fuel economy. EPA is finalizing the first-ever national greenhouse gas (GHG) emissions standards under the Clean Air Act References...

  6. SUBTASK 2.19 – OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE

    SciTech Connect (OSTI)

    Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

    2014-12-31

    Carbon dioxide (CO2) is produced in large quantities during electricity generation and by industrial processes. These CO2 streams vary in terms of both composition and mass flow rate, sometimes substantially. The impact of a varying CO2 stream on pipeline and storage operation is not fully understood in terms of either operability or infrastructure robustness. This study was performed to summarize basic background from the literature on the topic of operational flexibility of CO2 transport and storage, but the primary focus was on compiling real-world lessons learned about flexible operation of CO2 pipelines and storage from both large-scale field demonstrations and commercial operating experience. Modeling and pilot-scale results of research in this area were included to illustrate some of the questions that exist relative to operation of carbon capture and storage (CCS) projects with variable CO2 streams. It is hoped that this report’s real-world findings provide readers with useful information on the topic of transport and storage of variable CO2 streams. The real-world results were obtained from two sources. The first source consisted of five full-scale, commercial transport–storage projects: Sleipner, Snøhvit, In Salah, Weyburn, and Illinois Basin–Decatur. These scenarios were reviewed to determine the information that is available about CO2 stream variability/intermittency on these demonstration-scale projects. The five projects all experienced mass flow variability or an interruption in flow. In each case, pipeline and/or injection engineers were able to accommodate any issues that arose. Significant variability in composition has not been an issue at these five sites. The second source of real- world results was telephone interviews conducted with experts in CO2 pipeline transport, injection, and storage during which commercial anecdotal information was acquired to augment that found during the literature search of the five full-scale projects. The experts represented a range of disciplines and hailed from North America and Europe. Major findings of the study are that compression and transport of CO2 for enhanced oil recovery (EOR) purposes in the United States has shown that impurities are not likely to cause transport problems if CO2 stream composition standards are maintained and pressures are kept at 10.3 MPa or higher. Cyclic, or otherwise intermittent, CO2 supplies historically have not impacted in-field distribution pipeline networks, wellbore integrity, or reservoir conditions. The U.S. EOR industry has demonstrated that it is possible to adapt to variability and intermittency in CO2 supply through flexible operation of the pipeline and geologic storage facility. This CO2 transport and injection experience represents knowledge that can be applied in future CCS projects. A number of gaps in knowledge were identified that may benefit from future research and development, further enhancing the possibility for widespread application of CCS. This project was funded through the Energy & Environmental Research Center–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

  7. Well-to-wheels Analysis of Energy Use and Greenhouse Gas Emissions of Hydrogen Produced with Nuclear Energy

    SciTech Connect (OSTI)

    Wu, Ye; Wang, Michael Q.; Vyas, Anant D.; Wade, David C.; Taiwo, Temitope A.

    2004-07-01

    A fuel-cycle model-called the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model-has been developed at Argonne National Laboratory to evaluate well-to-wheels (WTW) energy and emission impacts of motor vehicle technologies fueled with various transportation fuels. The GREET model contains various hydrogen (H{sub 2}) production pathways for fuel-cell vehicles (FCVs) applications. In this effort, the GREET model was expanded to include four nuclear H{sub 2} production pathways: (1) H{sub 2} production at refueling stations via electrolysis using Light Water Reactor (LWR)-generated electricity; (2) H{sub 2} production in central plants via thermo-chemical water cracking using steam from High Temperature Gas cooled Reactor (HTGR); (3) H{sub 2} production in central plants via high-temperature electrolysis using HTGR-generated electricity and steam; and (4) H{sub 2} production at refueling stations via electrolysis using HTGR-generated electricity The WTW analysis of these four options include these stages: uranium ore mining and milling; uranium ore transportation; uranium conversion; uranium enrichment; uranium fuel fabrication; uranium fuel transportation; electricity or H{sub 2} production in nuclear power plants; H{sub 2} transportation; H{sub 2} compression; and H{sub 2} FCVs operation. Due to large differences in electricity requirements for uranium fuel enrichment between gas diffusion and centrifuge technologies, two scenarios were designed for uranium enrichment: (1) 55% of fuel enriched through gaseous diffusion technology and 45% through centrifuge technology (the current technology split for U.S. civilian nuclear power plants); and (2) 100% fuel enrichment using the centrifuge technology (a future trend). Our well-to-pump (WTP) results show that significant reductions in fossil energy use and greenhouse gas (GHG) emissions are achieved by nuclear-based H{sub 2} compared to natural gas-based H{sub 2} production via steam methane reforming for a unit of H{sub 2} delivered at refueling stations. In particular, 73-98% of GHG emissions and 81- 99% of fossil energy use are reduced by nuclear-based H{sub 2} relative to natural gas-based H{sub 2}, depending on the uranium enrichment technology and type of nuclear reactor used. When H{sub 2} is applied to FCVs, the WTW results also show large benefit in reducing fossil energy use and GHG emissions. (authors)

  8. Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4, and CH4/N2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by ZIFs | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Molecular Simulation Studies of Separation of CO2/N2, CO2/CH4, and CH4/N2 by ZIFs Previous Next List Bei Liu and Berend Smit, J. Phys. Chem. C, 2010, 114 (18), pp 8515-8522 DOI: 10.1021/jp101531m Abstract Image Abstract In this work, molecular simulations were performed to evaluate the separation performance of two typical zeolitic imidazolate frameworks (ZIFs), ZIF-68 and ZIF-69, for CO2/N2, CO2/CH4,

  9. Greenhouse Gas Concerns and Power Sector Planning (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01

    Concerns about potential climate change driven by rising atmospheric concentrations of Greenhouse Gases (GHG) have grown over the past two decades, both domestically and abroad. In the United States, potential policies to limit or reduce GHG emissions are in various stages of development at the state, regional, and federal levels. In addition to ongoing uncertainty with respect to future growth in energy demand and the costs of fuel, labor, and new plant construction, U.S. electric power companies must consider the effects of potential policy changes to limit or reduce GHG emissions that would significantly alter their planning and operating decisions. The possibility of such changes may already be affecting planning decisions for new generating capacity.

  10. Oxy-Combustion CO2 Control | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (N2) found in air from the combustion process, resulting in flue gas composed of CO2, water (H2O), contaminants from the fuel (including coal ash), and other gases that...

  11. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sector to continue generating electricity at coal-fired and natural-gas power plants. The strategy involves capturing and compressing CO2 at large, stationary sources, such as...

  12. NETL - World CO2 Emissions - Projected Trends Tool | Open Energy...

    Open Energy Info (EERE)

    to look at both total and power sector CO2 emissions from the use of coal, oil, or natural gas, over the period 1990 to 2030. One can use the tool to compare five of the larger...

  13. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Postcombustion Carbon Dioxide Capture | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for Postcombustion Carbon Dioxide Capture

  14. Bliss Greenhouse Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Bliss Greenhouse Greenhouse Low Temperature Geothermal Facility Facility Bliss Greenhouse...

  15. Watch Our CO2 Drop | Department of Energy

    Energy Savers [EERE]

    Watch Our CO2 Drop Watch Our CO2 Drop

  16. CO2 Removal using a Synthetic Analogue of Carbonic Anhydrase

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-09-14

    Project attempts to develop a synthetic analogue for carbonic anhydrase and incorporate it in a membrane for separation of CO2 from coal power plant flue gas. Conference poster presents result of first 9 months of project progress including concept, basic system architecture and membrane properties target, results of molecular modeling for analogue - CO2 interaction, and next steps of testing analogue resistance to flue gas contaminants.

  17. Natural Gas Methane Emissions in the United States Greenhouse Gas Inventory: Sources, Uncertainties and Opportunities for Improvement

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-11-19

    Presentation summarizing key findings of a Joint Institute for Strategic Energy Analysis Report at an Environmental Protection Agency workshop: 'Stakeholder Workshop on EPA GHG Data on Petroleum and Natural Gas Systems' on November 19, 2015. For additional information see the JISEA report, 'Estimating U.S. Methane Emissions from the Natural Gas Supply Chain: Approaches, Uncertainties, Current Estimates, and Future Studies' NREL/TP-6A50-62820.

  18. HIGH-TEMPERATURE CO-ELECTROLYSIS OF H2O AND CO2 FOR SYNGAS PRODUCTION

    SciTech Connect (OSTI)

    Stoots, C.M.

    2006-11-01

    Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen content (an example is the Athabasca Oil Sands). Additionally, the higher contents of sulfur and nitrogen of these resources requires processes such as hydrotreating to meet environmental requirements. In the mean time, with the price of oil currently over $50 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. The syngas can then be used for synthetic fuel production. This program is a combination of experimental and computational activities. Since the solid oxide electrolyte material is a conductor of oxygen ions, CO can be produced by electrolyzing CO2 sequestered from some greenhouse gas-emitting process. Under certain conditions, however, CO can further electrolyze to produce carbon, which can then deposit on cell surfaces and reduce cell performance. The understanding of the co-electrolysis of steam and CO2 is also complicated by the competing water-gas shift reaction. Results of experiments and calculations to date of CO2 and CO2/H2O electrolysis will be presented and discussed. These will include electrolysis performance at various temperatures, gas mixtures, and electrical settings. Product gas compositions, as measured via a gas analyser, and their relationship to conversion efficiencies will be presented. These measurements will be compared to predictions obtained from chemical equilibrium computer codes. Better understanding of the feasibility of producing syngas using high-temperature electrolysis will initiate the systematic investigation of nuclear-powered synfuel production as a bridge to the future hydrogen economy and ultimate independence from foreign energy resources.

  19. Greenhouse Gas Emissions from U.S. Hydropower Reservoirs: FY2011 Annual Progress Report

    SciTech Connect (OSTI)

    Stewart, Arthur J; Mosher, Jennifer J; Mulholland, Patrick J; Fortner, Allison M; Phillips, Jana Randolph; Bevelhimer, Mark S

    2012-05-01

    The primary objective of this study is to quantify the net emissions of key greenhouse gases (GHG) - notably, CO{sub 2} and CH{sub 4} - from hydropower reservoirs in moist temperate areas within the U.S. The rationale for this objective is straightforward: if net emissions of GHG can be determined, it would be possible to directly compare hydropower to other power-producing methods on a carbon-emissions basis. Studies of GHG emissions from hydropower reservoirs elsewhere suggest that net emissions can be moderately high in tropical areas. In such areas, warm temperatures and relatively high supply rates of labile organic matter can encourage high rates of decomposition, which (depending upon local conditions) can result in elevated releases of CO{sub 2} and CH{sub 4}. CO{sub 2} and CH{sub 4} emissions also tend to be higher for younger reservoirs than for older reservoirs, because vegetation and labile soil organic matter that is inundated when a reservoir is created can continue to decompose for several years (Galy-Lacaux et al. 1997, Barros et al. 2011). Water bodies located in climatically cooler areas, such as in boreal forests, could be expected to have lower net emissions of CO{sub 2} and CH{sub 4} because their organic carbon supplies tend to be relatively recalcitrant to microbial action and because cooler water temperatures are less conducive to decomposition.

  20. Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report

    SciTech Connect (OSTI)

    Fischer, ML

    2016-01-01

    The vertical distributions of CO2, CH4, and other gases provide important constraints when determining terrestrial and ocean sources and sinks of carbon and other biogeochemical processes in the Earth system. The U.S. Department of Energy's (DOE) Office of Biological and Environmental Research and the National Oceanic and Atmospheric Administration's Earth System Research Laboratory to quantify the vertically resolved distribution of atmospheric carbon-cycle gases(CO2, CH4 ) within approximately 99% of the atmospheric column at the DOE ’s Atmospheric Radiation Measurement Southern Great Plains (SGP) site in Oklahoma . During the 2012 to 2014 campaign period, 12 successful Air C ore flights were conducted from the SGP site . In addition to providing critical data for evaluating remote sensing and earth system models, valuable lessons were learned that motivate improvements to the sampling and recovery systems and campaign logistics . With the launch of the Orbiting Carbon Observatory - 2 (OCO - 2) and Greenhouse gases Observing Satellite ( GOSAT ) satellites, we look forward to proposing additional sampling and analysis efforts at the SGP site and at other sites to characterize the vertical distribution of CO2, CH4 over time and space.

  1. Comparing large scale CCS deployment potential in the USA and China: a detailed analysis based on country-specific CO2 transport & storage cost curves

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Davidson, Casie L.; Dooley, James J.

    2011-04-18

    The United States and China are the two largest emitters of greenhouse gases in the world and their projected continued growth and reliance on fossil fuels, especially coal, make them strong candidates for CCS. Previous work has revealed that both nations have over 1600 large electric utility and other industrial point CO2 sources as well as very large CO2 storage resources on the order of 2,000 billion metric tons (Gt) of onshore storage capacity. In each case, the vast majority of this capacity is found in deep saline formations. In both the USA and China, candidate storage reservoirs are likely to be accessible by most sources with over 80% of these large industrial CO2 sources having a CO2 storage option within just 80 km. This suggests a strong potential for CCS deployment as a meaningful option to efforts to reduce CO2 emissions from these large, vibrant economies. However, while the USA and China possess many similarities with regards to the potential value that CCS might provide, including the range of costs at which CCS may be available to most large CO2 sources in each nation, there are a number of more subtle differences that may help us to understand the ways in which CCS deployment may differ between these two countries in order for the USA and China to work together - and in step with the rest of the world - to most efficiently reduce greenhouse gas emissions. This paper details the first ever analysis of CCS deployment costs in these two countries based on methodologically comparable CO2 source and sink inventories, economic analysis, geospatial source-sink matching and cost curve modeling. This type of analysis provides a valuable insight into the degree to which early and sustained opportunities for climate change mitigation via commercial-scale CCS are available to the two countries, and could facilitate greater collaboration in areas where those opportunities overlap.

  2. Mixed-Matric Membranes for CO2 and H2 Gas Separations Using Metal-Organic Framework and Mesoporus Hybrid Silicas

    SciTech Connect (OSTI)

    Inga Musselman; Kenneth Balkus, Jr.; John Ferraris

    2009-01-07

    In this work, we have investigated the separation performance of polymer-based mixed-matrix membranes containing metal-organic frameworks and mesoporous hybrid silicas. The MOF/Matrimid{reg_sign} and MOP-18/Matrimid{reg_sign} membranes exhibited improved dispersion and mechanical strength that allowed high additive loadings with reduced aggregation, as is the case of the 80 wt% MOP-18/Matrimid{reg_sign} and the 80% (w/w) Cu-MOF/Matrimid{reg_sign} membranes. Membranes with up to 60% (w/w) ZIF-8 content exhibited similar mechanical strength and improved dispersion. The H{sub 2}/CO{sub 2} separation properties of MOF/Matrimid{reg_sign} mixed-matrix membranes was improved by either keeping the selectivity constant and increasing the permeability (MOF-5, Cu-MOF) or by improving both selectivity and permeability (ZIF-8). In the case of MOF-5/Matrimid{reg_sign} mixed-matrix membranes, the H{sub 2}/CO{sub 2} selectivity was kept at 2.6 and the H{sub 2} permeability increased from 24.4 to 53.8 Barrers. For the Cu-MOF/Matrimid{reg_sign} mixed-matrix membranes, the H{sub 2}/CO{sub 2} selectivity was kept at 2.05 and the H{sub 2} permeability increased from 17.1 to 158 Barrers. These two materials introduced porosity and uniform paths that enhanced the gas transport in the membranes. When ZIF-8/Matrimid{reg_sign} mixed-matrix membranes were studied, the H{sub 2}/CO{sub 2} selectivity increased from 2.9 to 4.4 and the permeability of H{sub 2} increased from 26.5 to 35.8 Barrers. The increased H{sub 2}/CO{sub 2} selectivity in ZIF-8/Matrimid{reg_sign} membranes was explained by the sieving effect introduced by the ZIF-8 crystals (pore window 0.34 nm) that restricted the transport of molecules larger than H{sub 2}. Materials with microporous and/or mesoporous cavities like carbon aerogel composites with zeolite A and zeolite Y, and membranes containing mesoporous ZSM-5 showed sieving effects for small molecules (e.g. H{sub 2} and CO{sub 2}), however, the membranes were most selective for CO{sub 2} due to the strong interaction of the zeolites with CO{sub 2}. For example, at 30 wt% ZSM-5 loading, the CO{sub 2}/CH{sub 4} selectivity increased from 34.7 (Matrimid{reg_sign}) to 56.4. The large increase in selectivity was the result of the increase in CO{sub 2} permeability from 7.3 (Matrimid{reg_sign}) to 14.6 Barrers. At 30 wt% ZSM-5 loading, the H{sub 2}/CH{sub 4} separation was also improved from 83.3 (Matrimid{reg_sign}) to 136.7 with an increase in H{sub 2} permeability from 17.5 (Matrimid{reg_sign}) to 35.3 Barrers. The 10% carbon aerogel-zeolite A and -zeolite Y composite/Matrimid{reg_sign} membranes exhibited an increase in the CO{sub 2}/CH{sub 4} separation from 34.7 to 71.5 (zeolite A composite) and to 57.4 (zeolite Y composite); in addition, the membrane exhibited an increase in the CO{sub 2}/N{sub 2} separation from 33.1 to 50 (zeolite A composite) and to 49.4 (zeolite Y composite), indicating that these type of materials have affinity for CO{sub 2}. The inclusion of mesoporosity enhanced the dispersion of the additive allowing loadings of up to 30% (w/w) without the formation of non-selective voids.

  3. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  4. Designing optimal greenhouse gas observing networks that consider performance and cost

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lucas, D. D.; Yver Kwok, C.; Cameron-Smith, P.; Graven, H.; Bergmann, D.; Guilderson, T. P.; Weiss, R.; Keeling, R.

    2014-12-23

    Emission rates of greenhouse gases (GHGs) entering into the atmosphere can be inferred using mathematical inverse approaches that combine observations from a network of stations with forward atmospheric transport models. Some locations for collecting observations are better than others for constraining GHG emissions through the inversion, but the best locations for the inversion may be inaccessible or limited by economic and other non-scientific factors. We present a method to design an optimal GHG observing network in the presence of multiple objectives that may be in conflict with each other. As a demonstration, we use our method to design a prototypemore » network of six stations to monitor summertime emissions in California of the potent GHG 1,1,1,2-tetrafluoroethane (CH2FCF3, HFC-134a). We use a multiobjective genetic algorithm to evolve network configurations that seek to jointly maximize the scientific accuracy of the inferred HFC-134a emissions and minimize the associated costs of making the measurements. The genetic algorithm effectively determines a set of "optimal" observing networks for HFC-134a that satisfy both objectives (i.e., the Pareto frontier). The Pareto frontier is convex, and clearly shows the tradeoffs between performance and cost, and the diminishing returns in trading one for the other. Without difficulty, our method can be extended to design optimal networks to monitor two or more GHGs with different emissions patterns, or to incorporate other objectives and constraints that are important in the practical design of atmospheric monitoring networks.« less

  5. Designing optimal greenhouse gas observing networks that consider performance and cost

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lucas, D. D.; Yver Kwok, C.; Cameron-Smith, P.; Graven, H.; Bergmann, D.; Guilderson, T. P.; Weiss, R.; Keeling, R.

    2015-06-16

    Emission rates of greenhouse gases (GHGs) entering into the atmosphere can be inferred using mathematical inverse approaches that combine observations from a network of stations with forward atmospheric transport models. Some locations for collecting observations are better than others for constraining GHG emissions through the inversion, but the best locations for the inversion may be inaccessible or limited by economic and other non-scientific factors. We present a method to design an optimal GHG observing network in the presence of multiple objectives that may be in conflict with each other. As a demonstration, we use our method to design a prototypemore » network of six stations to monitor summertime emissions in California of the potent GHG 1,1,1,2-tetrafluoroethane (CH2FCF3, HFC-134a). We use a multiobjective genetic algorithm to evolve network configurations that seek to jointly maximize the scientific accuracy of the inferred HFC-134a emissions and minimize the associated costs of making the measurements. The genetic algorithm effectively determines a set of "optimal" observing networks for HFC-134a that satisfy both objectives (i.e., the Pareto frontier). The Pareto frontier is convex, and clearly shows the tradeoffs between performance and cost, and the diminishing returns in trading one for the other. Without difficulty, our method can be extended to design optimal networks to monitor two or more GHGs with different emissions patterns, or to incorporate other objectives and constraints that are important in the practical design of atmospheric monitoring networks.« less

  6. CO2 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Our Jobs Our Jobs Working at NNSA Blog Home CO2 CO2 'Underground battery' could store renewable energy, sequester CO2 This integrated system would store carbon dioxide in an...

  7. Co2balance | Open Energy Information

    Open Energy Info (EERE)

    balance Jump to: navigation, search Name: Co2balance Place: United Kingdom Sector: Carbon Product: Carbon offset provider based in Somerset, UK. References: Co2balance1 This...

  8. Factor CO2 | Open Energy Information

    Open Energy Info (EERE)

    Factor CO2 Jump to: navigation, search Name: Factor CO2 Place: Bilbao, Spain Zip: 48008 Product: Spain-based consultancy specializing in climate change projects. References: Factor...

  9. Jackson Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Jackson Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Jackson...

  10. Benefits of Greenhouse Gas Mitigation on the Supply, Management, and Use of Water Resources in the United States

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Strzepek, K.; Neumann, Jim; Smith, Joel; Martinich, Jeremy; Boehlert, Brent; Hejazi, Mohamad I.; Henderson, Jim; Wobus, Cameron; Jones, Russ; Calvin, Katherine V.; et al

    2014-11-29

    Climate change impacts on water resources in the U.S. are likely to be far-reaching and substantial, because the water sector spans many parts of the economy, from supply and demand for agriculture, industry, energy production, transportation and municipal use to damages from natural hazards. This paper provides impact and damage estimates from five water resource-related models in the CIRA frame work, addressing drought risk, flooding damages, water supply and demand, and global water scarcity. The four models differ in the water system assessed, their spatial scale, and the units of assessment, but together they provide a quantitative and descriptive richnessmore » in characterizing water resource sector effects of climate change that no single model can capture. The results also address the sensitivity of these estimates to greenhouse gas emission scenarios, climate sensitivity alternatives, and global climate model selection. While calculating the net impact of climate change on the water sector as a whole may be impractical, because each of the models applied here uses a consistent set of climate scenarios, broad conclusions can be drawn regarding the patterns of change and the benefits of GHG mitigation policies for the water sector. Two key findings emerge: 1) climate mitigation policy substantially reduces the impact of climate change on the water sector across multiple dimensions; and 2) the more managed the water resources system, the more tempered the climate change impacts and the resulting reduction of impacts from climate mitigation policies.« less

  11. Transportation Energy Futures Series: Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-01

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  12. Benefits of Greenhouse Gas Mitigation on the Supply, Management, and Use of Water Resources in the United States

    SciTech Connect (OSTI)

    Strzepek, K.; Neumann, Jim; Smith, Joel; Martinich, Jeremy; Boehlert, Brent; Hejazi, Mohamad I.; Henderson, Jim; Wobus, Cameron; Jones, Russ; Calvin, Katherine V.; Johnson, D.; Monier, Erwan; Strzepek, J.; Yoon, Jin-Ho

    2014-11-29

    Climate change impacts on water resources in the U.S. are likely to be far-reaching and substantial, because the water sector spans many parts of the economy, from supply and demand for agriculture, industry, energy production, transportation and municipal use to damages from natural hazards. This paper provides impact and damage estimates from five water resource-related models in the CIRA frame work, addressing drought risk, flooding damages, water supply and demand, and global water scarcity. The four models differ in the water system assessed, their spatial scale, and the units of assessment, but together they provide a quantitative and descriptive richness in characterizing water resource sector effects of climate change that no single model can capture. The results also address the sensitivity of these estimates to greenhouse gas emission scenarios, climate sensitivity alternatives, and global climate model selection. While calculating the net impact of climate change on the water sector as a whole may be impractical, because each of the models applied here uses a consistent set of climate scenarios, broad conclusions can be drawn regarding the patterns of change and the benefits of GHG mitigation policies for the water sector. Two key findings emerge: 1) climate mitigation policy substantially reduces the impact of climate change on the water sector across multiple dimensions; and 2) the more managed the water resources system, the more tempered the climate change impacts and the resulting reduction of impacts from climate mitigation policies.

  13. Transportation Energy Futures Series. Effects of the Built Environment on Transportation. Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-15

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  14. Eco-efficiency for greenhouse gas emissions mitigation of municipal solid waste management: A case study of Tianjin, China

    SciTech Connect (OSTI)

    Zhao Wei; Huppes, Gjalt; Voet, Ester van der

    2011-06-15

    The issue of municipal solid waste (MSW) management has been highlighted in China due to the continually increasing MSW volumes being generated and the limited capacity of waste treatment facilities. This article presents a quantitative eco-efficiency (E/E) analysis on MSW management in terms of greenhouse gas (GHG) mitigation. A methodology for E/E analysis has been proposed, with an emphasis on the consistent integration of life cycle assessment (LCA) and life cycle costing (LCC). The environmental and economic impacts derived from LCA and LCC have been normalized and defined as a quantitative E/E indicator. The proposed method was applied in a case study of Tianjin, China. The study assessed the current MSW management system, as well as a set of alternative scenarios, to investigate trade-offs between economy and GHG emissions mitigation. Additionally, contribution analysis was conducted on both LCA and LCC to identify key issues driving environmental and economic impacts. The results show that the current Tianjin's MSW management system emits the highest GHG and costs the least, whereas the situation reverses in the integrated scenario. The key issues identified by the contribution analysis show no linear relationship between the global warming impact and the cost impact in MSW management system. The landfill gas utilization scenario is indicated as a potential optimum scenario by the proposed E/E analysis, given the characteristics of MSW, technology levels, and chosen methodologies. The E/E analysis provides an attractive direction towards sustainable waste management, though some questions with respect to uncertainty need to be discussed further.

  15. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  16. Synechococcus elongatus UTEX 2973, a fast growing cyanobacterial chassis for biosynthesis using light and CO2

    SciTech Connect (OSTI)

    Yu, Jingjie; Liberton, Michelle; Cliften, Paul F.; Head, Richard D.; Jacobs, Jon M.; Smith, Richard D.; Koppenaal, David W.; Brand, Jerry J.; Pakrasi, Himadri B.

    2015-01-30

    Photosynthetic microbes are of emerging interest as production organisms in biotechnology because they can grow autotrophically using sunlight, an abundant energy source, and CO2, a greenhouse gas. Important traits for such microbes are fast growth and amenability to genetic manipulation. Here we describe Synechococcus elongatus UTEX 2973, a unicellular cyanobacterium capable of rapid autotrophic growth, comparable to heterotrophic industrial hosts such as yeast. Synechococcus 2973 can be readily transformed for facile generation of desired knockout and knock-in mutations. Genome sequencing coupled with global proteomics studies revealed that Synechococcus 2973 is a close relative of the widely studied cyanobacterium Synechococcus elongatus PCC 7942, an organism that grows more than two times slower. A small number of nucleotide changes are the only significant differences between the genomes of these two cyanobacterial strains. Thus, our study has unraveled genetic determinants necessary for rapid growth of cyanobacterial strains of significant industrial potential.

  17. Synechococcus elongatus UTEX 2973, a fast growing cyanobacterial chassis for biosynthesis using light and CO2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Jingjie; Liberton, Michelle; Cliften, Paul F.; Head, Richard D.; Jacobs, Jon M.; Smith, Richard D.; Koppenaal, David W.; Brand, Jerry J.; Pakrasi, Himadri B.

    2015-01-30

    Photosynthetic microbes are of emerging interest as production organisms in biotechnology because they can grow autotrophically using sunlight, an abundant energy source, and CO2, a greenhouse gas. Important traits for such microbes are fast growth and amenability to genetic manipulation. Here we describe Synechococcus elongatus UTEX 2973, a unicellular cyanobacterium capable of rapid autotrophic growth, comparable to heterotrophic industrial hosts such as yeast. Synechococcus 2973 can be readily transformed for facile generation of desired knockout and knock-in mutations. Genome sequencing coupled with global proteomics studies revealed that Synechococcus 2973 is a close relative of the widely studied cyanobacterium Synechococcus elongatusmore » PCC 7942, an organism that grows more than two times slower. A small number of nucleotide changes are the only significant differences between the genomes of these two cyanobacterial strains. Thus, our study has unraveled genetic determinants necessary for rapid growth of cyanobacterial strains of significant industrial potential.« less

  18. Wards Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Wards Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Wards Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Wards...

  19. Liskey Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Liskey Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Liskey Greenhouses Greenhouse Low Temperature Geothermal Facility Facility Liskey...

  20. The Greenhouse Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name The Greenhouse Greenhouse Low Temperature Geothermal Facility Facility The Greenhouse Sector...

  1. Warm Springs Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Warm Springs Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Warm Springs Greenhouses Greenhouse Low Temperature Geothermal Facility...

  2. Where Greenhouse Gases Come From | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Where Greenhouse Gases Come From In the United States, greenhouse gas emissions come primarily from the burning of fossil fuels in energy use. Carbon Dioxide Carbon Dioxide is the main greenhouse gas. In 2013, 82% of human-caused greenhouse gas emissions were carbon dioxide emissions, resulting from the burning of fossil fuels, solid waste, trees, wood, and other chemical reactions. Methane and Other Gases Another greenhouse gas, methane, comes from landfills, coal mines, oil and natural gas

  3. CO2 Dynamics in a Metal-Organic Framework with Open Metal Sites | Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome CO2 Dynamics in a Metal-Organic Framework with Open Metal Sites

  4. Probing CO2 Adsorption in Metal-Organic Frameworks with Open Metal Sites |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Probing CO2 Adsorption in Metal-Organic Frameworks with Open Metal Sites

  5. Nitrogen availability and indirect measurements of greenhouse gas emissions from aerobic and anaerobic biowaste digestates applied to agricultural soils

    SciTech Connect (OSTI)

    Rigby, H.; Smith, S.R.

    2013-12-15

    Highlights: Nitrogen release in digestate-amended soil depends on the digestate type. Overall N release is modulated by digestate mineral and mineralisable N contents. Microbial immobilisation does not influence overall release of digestate N in soil. Digestate physical properties and soil type interact to affect overall N recovery. High labile C inputs in digestate may promote denitrification in fine-textured soil. - Abstract: Recycling biowaste digestates on agricultural land diverts biodegradable waste from landfill disposal and represents a sustainable source of nutrients and organic matter (OM) to improve soil for crop production. However, the dynamics of nitrogen (N) release from these organic N sources must be determined to optimise their fertiliser value and management. This laboratory incubation experiment examined the effects of digestate type (aerobic and anaerobic), waste type (industrial, agricultural and municipal solid waste or sewage sludge) and soil type (sandy loam, sandy silt loam and silty clay) on N availability in digestate-amended soils and also quantified the extent and significance of the immobilisation of N within the soil microbial biomass, as a possible regulatory mechanism of N release. The digestate types examined included: dewatered, anaerobically digested biosolids (DMAD); dewatered, anaerobic mesophilic digestate from the organic fraction of municipal solid waste (DMADMSW); liquid, anaerobic co-digestate of food and animal slurry (LcoMAD) and liquid, thermophilic aerobic digestate of food waste (LTAD). Ammonium chloride (NH{sub 4}Cl) was included as a reference treatment for mineral N. After 48 days, the final, maximum net recoveries of mineral N relative to the total N (TN) addition in the different digestates and unamended control treatments were in the decreasing order: LcoMAD, 68%; LTAD, 37%, DMAD, 20%; and DMADMSW, 11%. A transient increase in microbial biomass N (MBN) was observed with LTAD application, indicating greater microbial activity in amended soil and reflecting the lower stability of this OM source, compared to the other, anaerobic digestate types, which showed no consistent effects on MBN compared to the control. Thus, the overall net release of digestate N in different soil types was not regulated by N transfer into the soil microbial biomass, but was determined primarily by digestate properties and the capacity of the soil type to process and turnover digestate N. In contrast to the sandy soil types, where nitrate (NO{sub 3}{sup -}) concentrations increased during incubation, there was an absence of NO{sub 3}{sup -} accumulation in the silty clay soil amended with LTAD and DMADMSW. This provided indirect evidence for denitrification activity and the gaseous loss of N, and the associated increased risk of greenhouse gas emissions under certain conditions of labile C supply and/or digestate physical structure in fine-textured soil types. The significance and influence of the interaction between soil type and digestate stability and physical properties on denitrification processes in digestate-amended soils require urgent investigation to ensure management practices are appropriate to minimise greenhouse gas emissions from land applied biowastes.

  6. Evaluation of Efficiency Activities in the Industrial Sector Undertaken in Response to Greenhouse Gas Emission Reduction Targets

    SciTech Connect (OSTI)

    Price, Lynn; de la Rue du Can, Stephane; Lu, Hongyou; Horvath, Arpad

    2010-05-21

    The 2006 California Global Warming Solutions Act calls for reducing greenhouse gas (GHG) emissions to 1990 levels by 2020. Meeting this target will require action from all sectors of the California economy, including industry. The industrial sector consumes 25% of the energy used and emits 28% of the carbon dioxide (CO{sub 2}) produced in the state. Many countries around the world have national-level GHG reduction or energy-efficiency targets, and comprehensive programs focused on implementation of energy efficiency and GHG emissions mitigation measures in the industrial sector are essential for achieving their goals. A combination of targets and industry-focused supporting programs has led to significant investments in energy efficiency as well as reductions in GHG emissions within the industrial sectors in these countries. This project has identified program and policies that have effectively targeted the industrial sector in other countries to achieve real energy and CO{sub 2} savings. Programs in Ireland, France, The Netherlands, Denmark, and the UK were chosen for detailed review. Based on the international experience documented in this report, it is recommended that companies in California's industrial sector be engaged in a program to provide them with support to meet the requirements of AB32, The Global Warming Solution Act. As shown in this review, structured programs that engage industry, require members to evaluate their potential efficiency measures, plan how to meet efficiency or emissions reduction goals, and provide support in achieving the goals, can be quite effective at assisting companies to achieve energy efficiency levels beyond those that can be expected to be achieved autonomously.

  7. Leakage of CO2 from geologic storage: Role of secondaryaccumulation at shallow depth

    SciTech Connect (OSTI)

    Pruess, K.

    2007-05-31

    Geologic storage of CO2 can be a viable technology forreducing atmospheric emissions of greenhouse gases only if it can bedemonstrated that leakage from proposed storage reservoirs and associatedhazards are small or can be mitigated. Risk assessment must evaluatepotential leakage scenarios and develop a rational, mechanisticunderstanding of CO2 behavior during leakage. Flow of CO2 may be subjectto positive feedbacks that could amplify leakage risks and hazards,placing a premium on identifying and avoiding adverse conditions andmechanisms. A scenario that is unfavorable in terms of leakage behavioris formation of a secondary CO2 accumulation at shallow depth. This paperdevelops a detailed numerical simulation model to investigate CO2discharge from a secondary accumulation, and evaluates the role ofdifferent thermodynamic and hydrogeologic conditions. Our simulationsdemonstrate self-enhancing as well as self-limiting feedbacks.Condensation of gaseous CO2, 3-phase flow of aqueous phase -- liquid CO2-- gaseous CO2, and cooling from Joule-Thomson expansion and boiling ofliquid CO2 are found to play important roles in the behavior of a CO2leakage system. We find no evidence that a subsurface accumulation of CO2at ambient temperatures could give rise to a high-energy discharge, aso-called "pneumatic eruption."

  8. Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATKs design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

  9. Well-to-wheels energy use and greenhouse gas emissions analysis of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Burnham, A.; Wang, M.; Molburg, J.; Rousseau, A.; Energy Systems

    2009-03-31

    Researchers at Argonne National Laboratory expanded the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model and incorporated the fuel economy and electricity use of alternative fuel/vehicle systems simulated by the Powertrain System Analysis Toolkit (PSAT) to conduct a well-to-wheels (WTW) analysis of energy use and greenhouse gas (GHG) emissions of plug-in hybrid electric vehicles (PHEVs). The WTW results were separately calculated for the blended charge-depleting (CD) and charge-sustaining (CS) modes of PHEV operation and then combined by using a weighting factor that represented the CD vehicle-miles-traveled (VMT) share. As indicated by PSAT simulations of the CD operation, grid electricity accounted for a share of the vehicle's total energy use, ranging from 6% for a PHEV 10 to 24% for a PHEV 40, based on CD VMT shares of 23% and 63%, respectively. In addition to the PHEV's fuel economy and type of on-board fuel, the marginal electricity generation mix used to charge the vehicle impacted the WTW results, especially GHG emissions. Three North American Electric Reliability Corporation regions (4, 6, and 13) were selected for this analysis, because they encompassed large metropolitan areas (Illinois, New York, and California, respectively) and provided a significant variation of marginal generation mixes. The WTW results were also reported for the U.S. generation mix and renewable electricity to examine cases of average and clean mixes, respectively. For an all-electric range (AER) between 10 mi and 40 mi, PHEVs that employed petroleum fuels (gasoline and diesel), a blend of 85% ethanol and 15% gasoline (E85), and hydrogen were shown to offer a 40-60%, 70-90%, and more than 90% reduction in petroleum energy use and a 30-60%, 40-80%, and 10-100% reduction in GHG emissions, respectively, relative to an internal combustion engine vehicle that used gasoline. The spread of WTW GHG emissions among the different fuel production technologies and grid generation mixes was wider than the spread of petroleum energy use, mainly due to the diverse fuel production technologies and feedstock sources for the fuels considered in this analysis. The PHEVs offered reductions in petroleum energy use as compared with regular hybrid electric vehicles (HEVs). More petroleum energy savings were realized as the AER increased, except when the marginal grid mix was dominated by oil-fired power generation. Similarly, more GHG emissions reductions were realized at higher AERs, except when the marginal grid generation mix was dominated by oil or coal. Electricity from renewable sources realized the largest reductions in petroleum energy use and GHG emissions for all PHEVs as the AER increased. The PHEVs that employ biomass-based fuels (e.g., biomass-E85 and -hydrogen) may not realize GHG emissions benefits over regular HEVs if the marginal generation mix is dominated by fossil sources. Uncertainties are associated with the adopted PHEV fuel consumption and marginal generation mix simulation results, which impact the WTW results and require further research. More disaggregate marginal generation data within control areas (where the actual dispatching occurs) and an improved dispatch modeling are needed to accurately assess the impact of PHEV electrification. The market penetration of the PHEVs, their total electric load, and their role as complements rather than replacements of regular HEVs are also uncertain. The effects of the number of daily charges, the time of charging, and the charging capacity have not been evaluated in this study. A more robust analysis of the VMT share of the CD operation is also needed.

  10. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Cost Model FENETL CO2 Transport Cost Model About the model: This model was developed to estimate the cost of transporting a user-specified mass rate of CO2 by pipeline...

  11. Coal-Derived Warm Syngas Purification and CO2 Capture-Assisted Methane Production

    SciTech Connect (OSTI)

    Dagle, Robert A.; King, David L.; Li, Xiaohong S.; Xing, Rong; Spies, Kurt A.; Zhu, Yunhua; Rainbolt, James E.; Li, Liyu; Braunberger, B.

    2014-10-31

    Gasifier-derived syngas from coal has many applications in the area of catalytic transformation to fuels and chemicals. Raw syngas must be treated to remove a number of impurities that would otherwise poison the synthesis catalysts. Inorganic impurities include alkali salts, chloride, sulfur compounds, heavy metals, ammonia, and various P, As, Sb, and Se- containing compounds. Systems comprising multiple sorbent and catalytic beds have been developed for the removal of impurities from gasified coal using a warm cleanup approach. This approach has the potential to be more economic than the currently available acid gas removal (AGR) approaches and improves upon currently available processes that do not provide the level of impurity removal that is required for catalytic synthesis application. Gasification also lends itself much more readily to the capture of CO2, important in the regulation and control of greenhouse gas emissions. CO2 capture material was developed and in this study was demonstrated to assist in methane production from the purified syngas. Simultaneous CO2 sorption enhances the CO methanation reaction through relaxation of thermodynamic constraint, thus providing economic benefit rather than simply consisting of an add-on cost for carbon capture and release. Molten and pre-molten LiNaKCO3 can promote MgO and MgO-based double salts to capture CO2 with high cycling capacity. A stable cycling CO2 capacity up to 13 mmol/g was demonstrated. This capture material was specifically developed in this study to operate in the same temperature range and therefore integrate effectively with warm gas cleanup and methane synthesis. By combining syngas methanation, water-gas-shift, and CO2 sorption in a single reactor, single pass yield to methane of 99% was demonstrated at 10 bar and 330oC when using a 20 wt% Ni/MgAl2O4 catalyst and a molten-phase promoted MgO-based sorbent. Under model feed conditions both the sorbent and catalyst exhibited favorable stability after multiple test cycles. The cleanup for warm gas cleanup of inorganics was broken down into three major steps: chloride removal, sulfur removal, and the removal for a multitude of trace metal contaminants. Na2CO3 was found to optimally remove chlorides at an operating temperature of 450C. For sulfur removal two regenerable ZnO beds are used for bulk H2S removal at 450C (<5 ppm S) and a non-regenerable ZnO bed for H2S polishing at 300C (<40 ppb S). It was also found that sulfur from COS could be adsorbed (to levels below our detection limit of 40 ppb) in the presence of water that leads to no detectable slip of H2S. Finally, a sorbent material comprising of Cu and Ni was found to be effective in removing trace metal impurities such as AsH3 and PH3 when operating at 300C. Proof-of-concept of the integrated cleanup process was demonstrated with gasifier-generated syngas produced at the Western Research Institute using Wyoming Decker Coal. When operating with a ~1 SLPM feed, multiple inorganic contaminant removal sorbents and a tar-reforming bed was able to remove the vast majority of contaminants from the raw syngas. A tar-reforming catalyst was employed due to the production of tars generated from the gasifier used in this particular study. It is envisioned that in a real application a commercial scale gasifier operating at a higher temperature would produce lesser amount of tar. Continuous operation of a poison-sensitive copper-based WGS catalyst located downstream from the cleanup steps resulted in successful demonstration. ?

  12. Identification of Fragile Microscopic Structures during Mineral Transformations in Wet Supercritical CO2

    SciTech Connect (OSTI)

    Arey, Bruce W.; Kovarik, Libor; Qafoku, Odeta; Wang, Zheming; Hess, Nancy J.; Felmy, Andrew R.

    2013-04-01

    In this study we examine the nature of highly fragile reaction products that form in low water content super critical carbon dioxide (scCO2) using a combination of scanning electron microscopy/focus ion beam (SEM/FIB), confocal Raman spectroscopy, helium ion microscopy (HeIM), and transmission electron microscopy (TEM). HeIM images show these precipitates to be fragile rosettes that can readily decompose even under slight heating from an electron beam. Using the TEM revealed details on the interfacial structure between the newly formed surface precipitates and the underlying initial solid phases. The detailed microscopic analysis revealed that the growth of the precipitates either followed a tip growth mechanism with precipitates forming directly on the forsterite surface if the initial solid was non-porous (natural forsterite) or growth from the surface of the precipitates where fluid was conducted through the porous (nanoforsterite) agglomerates to the growth center. The mechanism of formation of the hydrated/hydroxylated magnesium carbonate compound (HHMC) phases offers insight into the possible mechanisms of carbonate mineral formation from scCO2 solutions which has recently received a great deal of attention as the result of the potential for CO2 to act as an atmospheric greenhouse gas and impact overall global warming. The techniques used here to examine these fragile structures an also be used to examine a wide range of fragile material surfaces. SEM and FIB technologies have now been brought together in a single instrument, which represents a powerful combination for the studies in biological, geological and materials science.

  13. SANS Investigations of CO2 Adsorption in Microporous Carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bahadur, Jitendra; Melnichenko, Yuri B; He, Lilin; Contescu, Cristian I; Gallego, Nidia C; Carmichael, Justin R

    2015-08-07

    The high pressure adsorption behavior of CO2 at T = 296 K in microporous carbon was investigated by small-angle neutron scattering (SANS) technique. A strong densification of CO2 in micropores accompanied by non-monotonic adsorption-induced pore deformation was observed. The density of confined CO2 increases rapidly with pressure and reaches the liquid –like density at 20 bar, which corresponds to the relative pressure of P/Psat ~0.3. At P > 20 bar density of confined CO2 increases slowly approaching a plateau at higher pressure. The size of micropores first increases with pressure, reaches a maximum at 20 bar,more » and then decreases with pressure. A complementary SANS experiment conducted on the same microporous carbon saturated with neutron-transparent and non-adsorbing inert gas argon shows no deformation of micropores at pressures up to ~200 bars. This result demonstrates that the observed deformation of micropores in CO2 is an adsorption-induced phenomenon, caused by the solvation pressure - induced strain and strong densification of confined CO2 .« less

  14. The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Lai, Judy; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal

    2010-06-01

    The Ernest Orlando Lawrence Berkeley National Laboratory (LBNL) is working with the California Energy Commission (CEC) to determine the potential role of commercial-sector distributed energy resources (DER) with combined heat and power (CHP) in greenhouse gas emissions (GHG) reductions. Historically, relatively little attention has been paid to the potential of medium-sized commercial buildings with peak electric loads ranging from 100 kW to 5 MW. In our research, we examine how these medium-sized commercial buildings might implement DER and CHP. The buildings are able to adopt and operate various technologies, e.g., photovoltaics (PV), on-site thermal generation, heat exchangers, solar thermal collectors, absorption chillers, batteries and thermal storage systems. We apply the Distributed Energy Resources Customer Adoption Model (DER-CAM), which is a mixed-integer linear program (MILP) that minimizes a site?s annual energy costs and/or CO2 emissions. Using 138 representative mid-sized commercial sites in California, existing tariffs of major utilities, and expected performance data of available technologies in 2020, we find the GHG reduction potential for these buildings. We compare different policy instruments, e.g., a CO2 pricing scheme or a feed-in tariff (FiT), and show their contributions to the California Air Resources Board (CARB) goals of additional 4 GW CHP capacities and 6.7 Mt/a GHG reduction in California by 2020. By applying different price levels for CO2, we find that there is competition between fuel cells and PV/solar thermal. It is found that the PV/solar thermal adoption increases rapidly, but shows a saturation at high CO2 prices, partly due to limited space for PV and solar thermal. Additionally, we find that large office buildings are good hosts for CHP in general. However, most interesting is the fact that fossil-based CHP adoption also increases with increasing CO2 prices. We will show service territory specific results since the attractiveness of DER varies widely by climate zone and service territory.

  15. Implications of High Renewable Electricity Penetration in the U.S. for Water Use, Greenhouse Gas Emissions, Land-Use, and Materials Supply

    Broader source: Energy.gov [DOE]

    Recent work found that renewable energy could supply 80% of electricity demand in the contiguous United States in 2050 at the hourly level. This paper explores some of the implications of achieving such high levels of renewable electricity for supply chains and the environment in scenarios with renewable supply up to such levels. Transitioning to high renewable electricity supply would lead to significant reductions in greenhouse gas emissions and water use, with only modest land-use implications. While renewable energy expansion implies moderate growth of the renewable electricity supply chains, no insurmountable long-term constraints to renewable electricity technology manufacturing capacity or materials supply are identified.

  16. CO2 Compression | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Compression CO2 Compression The CO2 captured from a power plant must be compressed from near atmospheric pressure to a pressure between 1,500 and 2,200 psi to be transported via pipeline and then injected into an underground storage site. The compression of CO2 represents a potentially large auxiliary power load on the overall power plant system. For example, in an August 2007 study conducted for NETL, CO2 compression was accomplished using a six-stage centrifugal compressor with interstage

  17. Forest succession at elevated CO2

    SciTech Connect (OSTI)

    Clark, James S.; Schlesinger, William H.

    2002-02-01

    We tested hypotheses concerning the response of forest succession to elevated CO2 in the FACTS-1 site at the Duke Forest. We quantified growth and survival of naturally recruited seedlings, tree saplings, vines, and shrubs under ambient and elevated CO2. We planted seeds and seedlings to augment sample sites. We augmented CO2 treatments with estimates of shade tolerance and nutrient limitation while controlling for soil and light effects to place CO2 treatments within the context of natural variability at the site. Results are now being analyzed and used to parameterize forest models of CO2 response.

  18. INTERNATIONAL COLLABORATION ON CO2 SEQUESTRATION

    SciTech Connect (OSTI)

    H.J. Herzog; E.E. Adams

    2000-08-23

    The specific objective of our project on CO{sub 2} ocean sequestration is to investigate its technical feasibility and to improve the understanding of any associated environmental impacts. Our ultimate goal is to minimize any impacts associated with the eventual use of ocean carbon sequestration to reduce greenhouse gas concentrations in the atmosphere. The project will continue through March 31, 2002, with a field experiment to take place in the summer of 2001 off the Kona Coast of Hawaii. At GHGT-4 in Interlaken, we presented a paper detailing our plans. The purpose of this paper is to present an update on our progress to date and our plans to complete the project. The co-authors of this paper are members of the project's Technical Committee, which has been formed to supervise the technical aspects and execution of this project.

  19. Techno-economic analysis of wood biomass boilers for the greenhouse industry

    SciTech Connect (OSTI)

    Chau, J.; Sowlati, T.; Sokhansanj, Shahabaddine; Bi, X.T.; Preto, F.; Melin, Staffan

    2009-01-01

    The objective of this study is to perform a techno-economic analysis on a typical wood pellet and wood residue boiler for generation of heat to an average-sized greenhouse in British Columbia. The variables analyzed included greenhouse size and structure, boiler efficiency, fuel types, and source of carbon dioxide (CO2) for crop fertilization. The net present value (NPV) show that installing a wood pellet or a wood residue boiler to provide 40% of the annual heat demand is more economical than using a natural gas boiler to provide all the heat at a discount rate of 10%. For an assumed lifespan of 25 years, a wood pellet boiler system could generate NPV of C$259,311 without electrostatic precipitator (ESP) and C$74,695 with ESP, respectively. While, installing a wood residue boiler with or without an ESP could provide NPV of C$919,922 or C$1,104,538, respectively. Using a wood biomass boiler could also eliminate over 3000 tonne CO2 equivalents of greenhouse gases annually. Wood biomass combustion generates more particulate matters than natural gas combustion. However, an advanced emission control system could significantly reduce particulate matters emission from wood biomass combustion which would bring the particulate emission to a relatively similar level as for natural gas.

  20. EPA's Recent Advance Notice on Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EPA's Recent Advance Notice on Greenhouse Gases EPA's Recent Advance Notice on Greenhouse Gases Summary EPA's advanced notice of proposed rulemaking on mobile sources of greenhouse gas emissions. PDF icon deer08_charmley.pdf More Documents & Publications EPA Diesel Update Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews EPA Mobile Source Rule Update

  1. Well-to-wheels analysis of energy use and greenhouse gas emissions of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Han, J.; Poch, L.; Wang, M.; Vyas, A.; Mahalik, M.; Rousseau, A.

    2010-06-14

    Plug-in hybrid electric vehicles (PHEVs) are being developed for mass production by the automotive industry. PHEVs have been touted for their potential to reduce the US transportation sector's dependence on petroleum and cut greenhouse gas (GHG) emissions by (1) using off-peak excess electric generation capacity and (2) increasing vehicles energy efficiency. A well-to-wheels (WTW) analysis - which examines energy use and emissions from primary energy source through vehicle operation - can help researchers better understand the impact of the upstream mix of electricity generation technologies for PHEV recharging, as well as the powertrain technology and fuel sources for PHEVs. For the WTW analysis, Argonne National Laboratory researchers used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model developed by Argonne to compare the WTW energy use and GHG emissions associated with various transportation technologies to those associated with PHEVs. Argonne researchers estimated the fuel economy and electricity use of PHEVs and alternative fuel/vehicle systems by using the Powertrain System Analysis Toolkit (PSAT) model. They examined two PHEV designs: the power-split configuration and the series configuration. The first is a parallel hybrid configuration in which the engine and the electric motor are connected to a single mechanical transmission that incorporates a power-split device that allows for parallel power paths - mechanical and electrical - from the engine to the wheels, allowing the engine and the electric motor to share the power during acceleration. In the second configuration, the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle; thus, the engine never directly powers the vehicle's transmission. The power-split configuration was adopted for PHEVs with a 10- and 20-mile electric range because they require frequent use of the engine for acceleration and to provide energy when the battery is depleted, while the series configuration was adopted for PHEVs with a 30- and 40-mile electric range because they rely mostly on electrical power for propulsion. Argonne researchers calculated the equivalent on-road (real-world) fuel economy on the basis of U.S. Environmental Protection Agency miles per gallon (mpg)-based formulas. The reduction in fuel economy attributable to the on-road adjustment formula was capped at 30% for advanced vehicle systems (e.g., PHEVs, fuel cell vehicles [FCVs], hybrid electric vehicles [HEVs], and battery-powered electric vehicles [BEVs]). Simulations for calendar year 2020 with model year 2015 mid-size vehicles were chosen for this analysis to address the implications of PHEVs within a reasonable timeframe after their likely introduction over the next few years. For the WTW analysis, Argonne assumed a PHEV market penetration of 10% by 2020 in order to examine the impact of significant PHEV loading on the utility power sector. Technological improvement with medium uncertainty for each vehicle was also assumed for the analysis. Argonne employed detailed dispatch models to simulate the electric power systems in four major regions of the US: the New England Independent System Operator, the New York Independent System Operator, the State of Illinois, and the Western Electric Coordinating Council. Argonne also evaluated the US average generation mix and renewable generation of electricity for PHEV and BEV recharging scenarios to show the effects of these generation mixes on PHEV WTW results. Argonne's GREET model was designed to examine the WTW energy use and GHG emissions for PHEVs and BEVs, as well as FCVs, regular HEVs, and conventional gasoline internal combustion engine vehicles (ICEVs). WTW results are reported for charge-depleting (CD) operation of PHEVs under different recharging scenarios. The combined WTW results of CD and charge-sustaining (CS) PHEV operations (using the utility factor method) were also examined and reported. According to the utility factor method, the share of vehicle miles traveled during CD operation is 25% for PHEV10 and 51% for PHEV40. Argonne's WTW analysis of PHEVs revealed that the following factors significantly impact the energy use and GHG emissions results for PHEVs and BEVs compared with baseline gasoline vehicle technologies: (1) the regional electricity generation mix for battery recharging and (2) the adjustment of fuel economy and electricity consumption to reflect real-world driving conditions. Although the analysis predicted the marginal electricity generation mixes for major regions in the United States, these mixes should be evaluated as possible scenarios for recharging PHEVs because significant uncertainties are associated with the assumed market penetration for these vehicles. Thus, the reported WTW results for PHEVs should be directly correlated with the underlying generation mix, rather than with the region linked to that mix.

  2. The Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    2009-01-18

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH,

  3. The Rosetta Resources CO2 Storage Project - A WESTCARB GeologicPilot Test

    SciTech Connect (OSTI)

    Trautz, Robert; Benson, Sally; Myer, Larry; Oldenburg, Curtis; Seeman, Ed; Hadsell, Eric; Funderburk, Ben

    2006-01-30

    WESTCARB, one of seven U.S. Department of Energypartnerships, identified (during its Phase I study) over 600 gigatonnesof CO2 storage capacity in geologic formations located in the Westernregion. The Western region includes the WESTCARB partnership states ofAlaska, Arizona, California, Nevada, Oregon and Washington and theCanadian province of British Columbia. The WESTCARB Phase II study iscurrently under way, featuring three geologic and two terrestrial CO2pilot projects designed to test promising sequestration technologies atsites broadly representative of the region's largest potential carbonsinks. This paper focuses on two of the geologic pilot studies plannedfor Phase II -referred to-collectively as the Rosetta-Calpine CO2 StorageProject. The first pilot test will demonstrate injection of CO2 into asaline formation beneath a depleted gas reservoir. The second test willgather data for assessing CO2 enhanced gas recovery (EGR) as well asstorage in a depleted gas reservoir. The benefit of enhanced oil recovery(EOR) using injected CO2 to drive or sweep oil from the reservoir towarda production well is well known. EaR involves a similar CO2 injectionprocess, but has received far less attention. Depleted natural gasreservoirs still contain methane; therefore, CO2 injection may enhancemethane production by reservoir repressurization or pressure maintenance.CO2 injection into a saline formation, followed by injection into adepleted natural gas reservoir, is currently scheduled to start inOctober 2006.

  4. CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mg2(dobdc) | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome /CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc) Previous Next List Zoey R. Herm, Rajamani Krishna, Jeffrey R. Long, Microporous Mesoporous Mater., 151, 481-487 (2012) DOI: 10.1016/j.micromeso.2011.09.004 Full-size image (38 K) Abstract: High-pressure separations of binary and ternary mixtures of CO2, CH4, and H2 are relevant to carbon dioxide capture as well as hydrogen

  5. CO2-selective, Hybrid Membranes by Silation of Alumina

    SciTech Connect (OSTI)

    Luebke, D.R.; Pennline, H.W.

    2007-09-01

    Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of ?-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of CO2-phillic groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated ?-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin polymer-like surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.

  6. CO2 Europipe | Open Energy Information

    Open Energy Info (EERE)

    www.co2europipe.eu Equivalent URI: cleanenergysolutions.orgcontentco2-europipe Language: English Policies: "Deployment Programs,Regulations,Financial Incentives" is not in...

  7. CO2 Conference Presentation | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    CO2 Conference Presentation More Documents & Publications POWER-GEN Conference Presentation U.S. Energy Association Presentation EEI Environment Meetings Presentation...

  8. solvents-co2-capture-pitt | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solvents for CO2 Capture Project No.: R&D 048 The most attractive physical solvents for carbon dioxide (CO2) capture are those having such properties as high thermal stability, extremely low vapor pressures, nonflammability, and nontoxicity. Such materials not only have the potential to capture CO2 with minimal solvent loss in the gas stream but are expected to be environmentally benign. NETL's Office of Research and Development is conducting a study involving one general type of

  9. Exploring the effects of data quality, data worth, and redundancy of CO2

    Office of Scientific and Technical Information (OSTI)

    gas pressure and saturation data on reservoir characterization through PEST Inversion (Journal Article) | SciTech Connect Exploring the effects of data quality, data worth, and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST Inversion Citation Details In-Document Search Title: Exploring the effects of data quality, data worth, and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST Inversion This study

  10. Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program

    SciTech Connect (OSTI)

    Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing; Stacy VanDeveer

    2005-07-01

    A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

  11. An Integrated Framework for CO2 Accounting and Risk Analysis in CO2-EOR

    Office of Scientific and Technical Information (OSTI)

    Sites (Technical Report) | SciTech Connect An Integrated Framework for CO2 Accounting and Risk Analysis in CO2-EOR Sites Citation Details In-Document Search Title: An Integrated Framework for CO2 Accounting and Risk Analysis in CO2-EOR Sites An integrated framework for CO2 accounting and risk analysis of CO2-EOR Authors: Dai, Zhenxue [1] ; Viswanathan, Hari S. [1] ; Middleton, Richard Stephen [1] ; Fessenden-Rahn, Julianna Eileen [1] + Show Author Affiliations Los Alamos National Lab.

  12. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2

    Office of Scientific and Technical Information (OSTI)

    leakage into aquifers (Journal Article) | SciTech Connect analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers Citation Details In-Document Search Title: Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in

  13. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J.

    2011-04-01

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  14. Control of Greenhouse Gas Emissions by Optimal DER Technology Investment and Energy Management in Zero-Net-Energy Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Siddiqui, Afzal; Marnay, Chris; Aki, Hirohisa; Lai, Judy

    2009-08-10

    The U.S. Department of Energy has launched the commercial building initiative (CBI) in pursuit of its research goal of achieving zero-net-energy commercial buildings (ZNEB), i.e. ones that produce as much energy as they use. Its objective is to make these buildings marketable by 2025 such that they minimize their energy use through cutting-edge, energy-efficiency technologies and meet their remaining energy needs through on-site renewable energy generation. This paper examines how such buildings may be implemented within the context of a cost- or CO2-minimizing microgrid that is able to adopt and operate various technologies: photovoltaic modules (PV) and other on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and passive/demand-response technologies. A mixed-integer linear program (MILP) that has a multi-criteria objective function is used. The objective is minimization of a weighted average of the building's annual energy costs and CO2 emissions. The MILP's constraints ensure energy balance and capacity limits. In addition, constraining the building's energy consumed to equal its energy exports enables us to explore how energy sales and demand-response measures may enable compliance with the ZNEB objective. Using a commercial test site in northernCalifornia with existing tariff rates and technology data, we find that a ZNEB requires ample PV capacity installed to ensure electricity sales during the day. This is complemented by investment in energy-efficient combined heat and power (CHP) equipment, while occasional demand response shaves energy consumption. A large amount of storage is also adopted, which may be impractical. Nevertheless, it shows the nature of the solutions and costs necessary to achieve a ZNEB. Additionally, the ZNEB approach does not necessary lead to zero-carbon (ZC) buildings as is frequently argued. We also show a multi-objective frontier for the CA example, whichallows us to estimate the needed technologies and costs for achieving a ZC building or microgrid.

  15. The CO2 Reduction Potential of Combined Heat and Power in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Lipman, Tim; Megel, Olivier; Ganguly, Srirupa; Siddiqui, Afzal; Lai, Judy

    2009-11-16

    The Ernest Orlando Lawrence Berkeley National Laboratory (LBNL) is working with the California Energy Commission (CEC) to determine the potential role of commercial sector distributed generation (DG) with combined heat and power (CHP) capability deployment in greenhouse gas emissions (GHG) reductions. CHP applications at large industrial sites are well known, and a large share of their potential has already been harvested. In contrast, relatively little attention has been paid to the potential of medium-sized commercial buildings, i.e., ones with peak electric loads ranging from 100 kW to 5 MW. We examine how this sector might implement DG with CHP in cost minimizing microgrids that are able to adopt and operate various energy technologies, such as solar photovoltaics (PV), on-site thermal generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We apply a mixed-integer linear program (MILP) that minimizes a site's annual energy costs as its objective. Using 138 representative mid-sized commercial sites in California (CA), existing tariffs of three major electricity distribution ultilities plus a natural gas company, and performance data of available technology in 2020, we find the GHG reduction potential for this CA commercial sector segment, which represents about 35percent of total statewide commercial sector sales. Under the assumptions made, in a reference case, this segment is estimated to be capable of economically installing 1.4 GW of CHP, 35percent of the California Air Resources Board (CARB) statewide 4 GW goal for total incremental CHP deployment by 2020. However, because CARB's assumed utilization is far higherthan is found by the MILP, the adopted CHP only contributes 19percent of the CO2 target. Several sensitivity runs were completed. One applies a simple feed-in tariff similar to net metering, and another includes a generous self-generation incentive program (SGIP) subsidy for fuel cells. The feed-in tariff proves ineffective at stimulating CHP deployment, while the SGIP buy down is more powerful. The attractiveness of CHP varies widely by climate zone and service territory, but in general, hotter inland areas and San Diego are the more attractive regions because high cooling loads achieve higher equipment utilization. Additionally, large office buildings are surprisingly good hosts for CHP, so large office buildings in San Diego and hotter urban centers emerge as promising target hosts. Overall the effect on CO2 emissions is limited, never exceeding 27percent of the CARB target. Nonetheless, results suggest that the CO2 emissions abatement potential of CHP in mid-sized CA buildings is significant, and much more promising than is typically assumed.

  16. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Postcombustion Carbon Dioxide Capture | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Large CO2 Adsorption in Aluminosilicate Zeolites for Postcombustion Carbon Dioxide Capture Previous Next List Jihan Kim, Li-Chiang Lin, Joseph A. Swisher, Maciej Haranczyk, and Berend Smit, J. Am. Chem. Soc., 2012, 134 (46), pp 18940-18943 DOI: 10.1021/ja309818u Abstract Image Abstract: Large-scale simulations of aluminosilicate zeolites were conducted to identify

  17. INTERNATIONAL COLLABORATION ON CO2 SEQUESTRATION

    SciTech Connect (OSTI)

    H.J. Herzog; E.E. Adams

    1999-08-23

    The ocean represents the largest potential sink for anthropogenic CO{sub 2}. In order to better understand this potential, Japan, Norway, and the United States signed a Project Agreement for International Collaboration on CO{sub 2} Ocean Sequestration in December 1997; since that time, Canada and ABB (Switzerland) have joined the project. The objective of the project is to investigate the technical feasibility of, and improve understanding of the environmental impacts from, CO{sub 2} ocean sequestration in order to minimize the impacts associated with the eventual use of this technique to reduce greenhouse gas concentrations in the atmosphere. The project will continue through March 31, 2002, with a field experiment to take place in the summer of 2000 off the Kona Coast of Hawaii. The implementing research organizations are the Research Institute of Innovative Technology for the Earth (Japan), the Norwegian Institute for Water Research (Norway), and the Massachusetts Institute of Technology (USA). The general contractor for the project will be the Pacific International Center for High Technology Research in Hawaii. A Technical Committee has been formed to supervise the technical aspects and execution of this project. The members of this committee are the co-authors of this paper. In this paper we discuss key issues involved with the design, ocean engineering, measurements, siting, and costs of this experiment.

  18. Phase-Changing Ionic Liquids: CO2 Capture with Ionic Liquids Involving Phase Change

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Notre Dame is developing a new CO2 capture process that uses special ionic liquids (ILs) to remove CO2 from the gas exhaust of coal-fired power plants. ILs are salts that are normally liquid at room temperature, but Notre Dame has discovered a new class of ILs that are solid at room temperature and change to liquid when they bind to CO2. Upon heating, the CO2 is released for storage, and the ILs re-solidify and donate some of the heat generated in the process to facilitate further CO2 release. These new ILs can reduce the energy required to capture CO2 from the exhaust stream of a coal-fired power plant when compared to state-ofthe- art technology.

  19. Burgett Geothermal Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Burgett Geothermal Greenhouses Sector Geothermal energy Type Greenhouse Location Cotton City, New Mexico Coordinates Show Map Loading map... "minzoom":false,"mappingservice"...

  20. Edward's Greenhouses Greenhouse Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    of Technology's Geo-Heat Center Retrieved from "http:en.openei.orgwindex.php?titleEdward%27sGreenhousesGreenhouseLowTemperatureGeothermalFacility&oldid305261" ...

  1. Novel CO2 Binding Mechanism Determined via in-situ Absorption Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Theory | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Novel CO2 Binding Mechanism Determined via in-situ Absorption Spectroscopy & Theory

  2. 10,651,176 Metric Tons of CO2 Injected as of September 16, 2015...

    Broader source: Energy.gov (indexed) [DOE]

    Products has successfully retrofitted its two Port Arthur SMRs with a vacuum swing adsorption system to separate the CO2 from the process gas stream, followed by compression and...

  3. ARM - What are Greenhouse Gases?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What are Greenhouse Gases? Carbon Dioxide Methane Gas Oxides of Nitrogen Halocarbons Ozone Water Vapor Greenhouse gases are atmospheric gases that trap infrared radiation emitted from the earth, lower atmosphere, or clouds or aerosols and, as

  4. Near-Surface CO2 Monitoring And Analysis To Detect Hidden Geothermal Systems

    SciTech Connect (OSTI)

    Lewicki, Jennifer L.; Oldenburg, Curtis M.

    2005-01-19

    ''Hidden'' geothermal systems are systems devoid of obvious surface hydrothermal manifestations. Emissions of moderate-to-low solubility gases may be one of the primary near-surface signals from these systems. We investigate the potential for CO2 detection and monitoring below and above ground in the near-surface environment as an approach to exploration targeting hidden geothermal systems. We focus on CO2 because it is the dominant noncondensible gas species in most geothermal systems and has moderate solubility in water. We carried out numerical simulations of a CO2 migration scenario to calculate the magnitude of expected fluxes and concentrations. Our results show that CO2 concentrations can reach high levels in the shallow subsurface even for relatively low geothermal source CO2 fluxes. However, once CO2 seeps out of the ground into the atmospheric surface layer, winds are effective at dispersing CO2 seepage. In natural ecological systems in the absence of geothermal gas emissions, near-surface CO2 fluxes and concentrations are predominantly controlled by CO2 uptake by photosynthesis, production by root respiration, microbial decomposition of soil/subsoil organic matter, groundwater degassing, and exchange with the atmosphere. Available technologies for monitoring CO2 in the near-surface environment include the infrared gas analyzer, the accumulation chamber method, the eddy covariance method, hyperspectral imaging, and light detection and ranging. To meet the challenge of detecting potentially small-magnitude geothermal CO2 emissions within the natural background variability of CO2, we propose an approach that integrates available detection and monitoring techniques with statistical analysis and modeling strategies. The proposed monitoring plan initially focuses on rapid, economical, reliable measurements of CO2 subsurface concentrations and surface fluxes and statistical analysis of the collected data. Based on this analysis, are as with a high probability of containing geothermal CO2 anomalies can be further sampled and analyzed using more expensive chemical and isotopic methods. Integrated analysis of all measurements will determine definitively if CO2 derived from a deep geothermal source is present, and if so, the spatial extent of the anomaly. The suitability of further geophysical measurements, installation of deep wells, and geochemical analyses of deep fluids can then be determined based on the results of the near surface CO2 monitoring program.

  5. Energy Efficiency and Renewable Energy Research, Development, and Deployment in Meeting Greenhouse Gas Mitigation Goals: The Case of the Lieberman-Warner Climate Security Act of 2007 (S.2191)

    SciTech Connect (OSTI)

    Showalter, S.; Wood, F.; Vimmerstedt, L.

    2010-06-01

    The U.S. federal government is considering actions to reduce greenhouse gas emissions. Renewable energy and energy efficiency technologies could help reduce greenhouse gas emissions, so the cost of these technologies could significantly influence the overall cost of meeting greenhouse gas limits. This paper examines the potential benefit of reduced technology cost by analyzing the case of the Lieberman-Warner Climate Security Act of 2007 (S.2191). This act had a goal of reducing national carbon emissions in 2050 to levels 72 percent below 2006 emission levels. In April 2008, the U.S. Department of Energy, Energy Information Administration (EIA) published an analysis of the effects of S.2191 on the U.S. energy sector. This report presents a similar analysis: both analyses examined the impacts of S.2191, and both used versions of the National Energy Modeling System. The analysis reported here used modified technology assumptions to reflect U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE) program goals. The results show that achieving EERE program goals could reduce the cost of meeting greenhouse gas limits, reduce the cost of renewable electricity generation and biofuels, and reduce energy intensity.

  6. Energy Efficiency and Renewable Energy Research, Development, and Deployment in Meeting Greenhouse Gas Mitigation Goals. The Case of the Lieberman-Warner Climate Security Act of 2007 (S. 2191)

    SciTech Connect (OSTI)

    Showalter, Sharon

    2010-06-01

    The U.S. federal government is considering actions to reduce greenhouse gas emissions. Renewable energy and energy efficiency technologies could help reduce greenhouse gas emissions, so the cost of these technologies could significantly influence the overall cost of meeting greenhouse gas limits. This paper examines the potential benefit of reduced technology cost by analyzing the case of the Lieberman-Warner Climate Security Act of 2007 (S.2191). This act had a goal of reducing national carbon emissions in 2050 to levels 72 percent below 2006 emission levels. In April 2008, the U.S. Department of Energy, Energy Information Administration (EIA) published an analysis of the effects of S.2191 on the U.S. energy sector. This report presents a similar analysis: both analyses examined the impacts of S.2191, and both used versions of the National Energy Modeling System. The analysis reported here used modified technology assumptions to reflect U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE) program goals. The results show that achieving EERE program goals could reduce the cost of meeting greenhouse gas limits, reduce the cost of renewable electricity generation and biofuels, and reduce energy intensity.

  7. CENIT CO2 | Open Energy Information

    Open Energy Info (EERE)

    and develop new solutions to reducing CO2 emissions from fossil fuel combustion during electricity generation. References: CENIT-CO21 This article is a stub. You can help...

  8. ARM - Campaign Instrument - co2air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Airborne Carbon Dioxide Analyzer System (CO2AIR) Instrument Categories...

  9. ARM - Campaign Instrument - co2flx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Dioxide Flux Measurement Systems (CO2FLX) Instrument Categories...

  10. CO2 | OpenEI Community

    Open Energy Info (EERE)

    cities CO2 emissions OpenEI suburbs US New research from the University of California-Berkeley shows that those who live in cities in the United States have significantly smaller...

  11. CO2-Based Glue - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Energy Efficiency Building Energy Efficiency Advanced Materials Advanced Materials Find More Like This Return to Search CO2-Based Glue An environmentally friendly epoxy that utilizes CO2 as a starting material National Energy Technology Laboratory Contact NETL About This Technology Weights suspended by plates that are held together with the adhesive Weights suspended by plates that are held together with the adhesive Plates held together by adhesive. Weights were suspended from the

  12. Observational determination of surface radiative forcing by CO2 from 2000 to 2010

    SciTech Connect (OSTI)

    Feldman, Daniel R.; Collins, William D.; Gero, P. Johnathan; Torn, Margaret S.; Mlawer, Eli J.; Shippert, Timothy R.

    2015-02-25

    The climatic impact of CO2 and other greenhouse gases is usually quantified in terms of radiative forcing1, calculated as the difference between estimates of the Earth’s radiation field from pre-industrial and present-day concentrations of these gases. Radiative transfer models calculate that the increase in CO2 since 1750 corresponds to a global annual-mean radiative forcing at the tropopause of 1.82 ± 0.19 W m-2 (ref. 2). However, despite widespread scientific discussion and modelling of the climate impacts of well-mixed greenhouse gases, there is little direct observational evidence of the radiative impact of increasing atmospheric CO2. Here we present observationally based evidence of clear-sky CO2 surface radiative forcing that is directly attributable to the increase, between 2000 and 2010, of 22 parts per million atmospheric CO2. The time series of this forcing at the two locations—the Southern Great Plains and the North Slope of Alaska—are derived from Atmospheric Emitted Radiance Interferometer spectra3 together with ancillary measurements and thoroughly corroborated radiative transfer calculations4. The time series both show statistically significant trends of 0.2 W m-2 per decade (with respective uncertainties of ±0.06 W m-2 per decade and ±0.07 W m-2 per decade) and have seasonal ranges of 0.1–0.2 W m-2. This is approximately ten per cent of the trend in downwelling longwave radiation5, 6, 7. These results confirm theoretical predictions of the atmospheric greenhouse effect due to anthropogenic emissions, and provide empirical evidence of how rising CO2 levels, mediated by temporal variations due to photosynthesis and respiration, are affecting the surface energy balance.

  13. An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors

    SciTech Connect (OSTI)

    Townsend, Aaron K.; Webber, Michael E.

    2012-07-15

    This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

  14. Misrepresentation of the IPCC CO2 emission scenarios

    SciTech Connect (OSTI)

    Manning, Martin; Edmonds, James A.; Emori, S.; Grubler, Arnulf; Hibbard, Kathleen A.; Joos, Fortunat; Kainuma, M.; Keeling, Ralph; Kram, Tom; Manning, Andrew; Meinhausen, Malte; Moss, Richard H.; Nakicenovic, Nebojsa; Riahi, Keywan; Rose, Steven K.; Smith, Steven J.; Swart, Robert; Van Vuuren, Detlef

    2010-06-01

    Estimates of recent fossil fuel CO2 emissions have been compared with the IPCC SRES (Special Report on Emission Scenarios) emission scenarios that had been developed for analysis of future climate change, impacts and mitigation. In some cases this comparison uses averages across subgroups of SRES scenarios and for one category of greenhouse gases (industrial sources of CO2). That approach can be misleading and cause confusion as it is inconsistent with many of the papers on future climate change projections that are based on a specific subset of closely scrutinized SRES scenarios, known as illustrative marker scenarios. Here, we show that comparison between recent estimates of fossil fuel emissions trends and the SRES illustrative marker scenarios leads to the conclusion that recent trends are not outside the SRES range. Furthermore, the recent economic downturn appears to have brought actual emission back toward the middle of the SRES illustrative marker scenarios. We also note that SRES emission scenarios are designed to reflect potential alternative long-term trends in a world without climate policy intervention and the trend in the resulting climate change is not sensitive to short-term fluctuations.

  15. Carbon emissions and sequestration in forests: Case studies from seven developing countries. Volume 2, Greenhouse gas emissions from deforestration in the Brazilian Amazon

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J.; Fearnside, P.M.

    1992-08-01

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as ``committed carbon,`` or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil`s use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  16. Spatial and Temporal Correlates of Greenhouse Gas Diffusion from a Hydropower Reservoir in the Southern United States

    SciTech Connect (OSTI)

    Mosher, Jennifer; Fortner, Allison M.; Phillips, Jana Randolph; Bevelhimer, Mark S.; Stewart, Dr. Arthur; Troia, Matthew J.

    2015-10-29

    Emissions of CO2 and CH4 from freshwater reservoirs constitute a globally significant source of atmospheric greenhouse gases (GHGs), but knowledge gaps remain with regard to spatiotemporal drivers of emissions. We document the spatial and seasonal variation in surface diffusion of CO2 and CH4 from Douglas Lake, a hydropower reservoir in Tennessee, USA. Monthly estimates across 13 reservoir sites from January to November 2010 indicated that surface diffusions ranged from 236 to 18,806 mg m-2 day-1 for CO2 and 0 to 0.95 mg m-2 day-1 for CH4. Next, we developed statistical models using spatial and physicochemical variables to predict surface diffusions of CO2 and CH4. Models explained 22.7 and 20.9% of the variation in CO2 and CH4 diffusions, respectively, and identified pH, temperature, dissolved oxygen, and Julian day as the most informative important predictors. These findings provide baseline estimates of GHG emissions from a reservoir in eastern temperate North America a region for which estimates of reservoir GHGs emissions are limited. Our statistical models effectively characterized non-linear and threshold relationships between physicochemical predictors and GHG emissions. Further refinement of such models will aid in predicting current GHG emissions in unsampled reservoirs and forecasting future GHG emissions.

  17. Data Assimilation Tools for CO2 Reservoir Model Development – A Review of Key Data Types, Analyses, and Selected Software

    SciTech Connect (OSTI)

    Rockhold, Mark L.; Sullivan, E. C.; Murray, Christopher J.; Last, George V.; Black, Gary D.

    2009-09-30

    Pacific Northwest National Laboratory (PNNL) has embarked on an initiative to develop world-class capabilities for performing experimental and computational analyses associated with geologic sequestration of carbon dioxide. The ultimate goal of this initiative is to provide science-based solutions for helping to mitigate the adverse effects of greenhouse gas emissions. This Laboratory-Directed Research and Development (LDRD) initiative currently has two primary focus areas—advanced experimental methods and computational analysis. The experimental methods focus area involves the development of new experimental capabilities, supported in part by the U.S. Department of Energy’s (DOE) Environmental Molecular Science Laboratory (EMSL) housed at PNNL, for quantifying mineral reaction kinetics with CO2 under high temperature and pressure (supercritical) conditions. The computational analysis focus area involves numerical simulation of coupled, multi-scale processes associated with CO2 sequestration in geologic media, and the development of software to facilitate building and parameterizing conceptual and numerical models of subsurface reservoirs that represent geologic repositories for injected CO2. This report describes work in support of the computational analysis focus area. The computational analysis focus area currently consists of several collaborative research projects. These are all geared towards the development and application of conceptual and numerical models for geologic sequestration of CO2. The software being developed for this focus area is referred to as the Geologic Sequestration Software Suite or GS3. A wiki-based software framework is being developed to support GS3. This report summarizes work performed in FY09 on one of the LDRD projects in the computational analysis focus area. The title of this project is Data Assimilation Tools for CO2 Reservoir Model Development. Some key objectives of this project in FY09 were to assess the current state-of-the-art in reservoir model development, the data types and analyses that need to be performed in order to develop and parameterize credible and robust reservoir simulation models, and to review existing software that is applicable to these analyses. This report describes this effort and highlights areas in which additional software development, wiki application extensions, or related GS3 infrastructure development may be warranted.

  18. Rate of H2S and CO2 attack on pozzolan-amended Class H well cement...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: International Journal of Greenhouse Gas Control; Journal Volume: 27 Publisher: Elsevier Research Org: National Energy Technology Laboratory - ...

  19. Hopewell Beneficial CO2 Capture for Production of Fuels, Fertilizer and Energy

    SciTech Connect (OSTI)

    UOP; Honeywell Resins & Chemicals; Honeywell Process Solutions; Aquaflow Bionomics Ltd

    2010-09-30

    For Phase 1 of this project, the Hopewell team developed a detailed design for the Small Scale Pilot-Scale Algal CO2 Sequestration System. This pilot consisted of six (6) x 135 gallon cultivation tanks including systems for CO2 delivery and control, algal cultivation, and algal harvesting. A feed tank supplied Hopewell wastewater to the tanks and a receiver tank collected the effluent from the algal cultivation system. The effect of environmental parameters and nutrient loading on CO2 uptake and sequestration into biomass were determined. Additionally the cost of capturing CO2 from an industrial stack emission at both pilot and full-scale was determined. The engineering estimate evaluated Amine Guard technology for capture of pure CO2 and direct stack gas capture and compression. The study concluded that Amine Guard technology has lower lifecycle cost at commercial scale, although the cost of direct stack gas capture is lower at the pilot scale. Experiments conducted under high concentrations of dissolved CO2 did not demonstrate enhanced algae growth rate. This result suggests that the dissolved CO2 concentration at neutral pH was already above the limiting value. Even though dissolved CO2 did not show a positive effect on biomass growth, controlling its value at a constant set-point during daylight hours can be beneficial in an algae cultivation stage with high algae biomass concentration to maximize the rate of CO2 uptake. The limited enhancement of algal growth by CO2 addition to Hopewell wastewater was due at least in part to the high endogenous CO2 evolution from bacterial degradation of dissolved organic carbon present at high levels in the wastewater. It was found that the high level of bacterial activity was somewhat inhibitory to algal growth in the Hopewell wastewater. The project demonstrated that the Honeywell automation and control system, in combination with the accuracy of the online pH, dissolved O2, dissolved CO2, turbidity, Chlorophyll A and conductivity sensors is suitable for process control of algae cultivation in an open pond systems. This project concluded that the Hopewell wastewater is very suitable for algal cultivation but the potential for significant CO2 sequestration from the plant stack gas emissions was minimal due to the high endogenous CO2 generation in the wastewater from the organic wastewater content. Algae cultivation was found to be promising, however, for nitrogen remediation in the Hopewell wastewater.

  20. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650C in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late in Phase 1 an opportunity arose to collaborate with another turbine-development team to construct a shared s-CO2 test facility. The synergy of the combined effort would result in greater facility capabilities than either separate project could produce and would allow for testing of both turbine designs within the combined budgets of the two projects. The project team requested a no-cost extension to Phase 1 to modify the subsequent work based on this collaborative approach. DOE authorized a brief extension, but ultimately opted not to pursue the collaborative facility and terminated the project.

  1. Hunter Hot Spring Greenhouse Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Hunter Hot Spring Greenhouse Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name Hunter Hot Spring Greenhouse Greenhouse Low Temperature Geothermal...

  2. High Country Rose Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    Rose Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name High Country Rose Greenhouses Greenhouse Low Temperature Geothermal Facility...

  3. Uncertainty analyses of CO2 plume expansion subsequent to wellbore...

    Office of Scientific and Technical Information (OSTI)

    in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. ... The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the ...

  4. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    An Integrated Framework for CO2 Accounting and Risk Analysis in CO2-EOR Sites Citation Details In-Document Search Title: An Integrated Framework for CO2 Accounting and Risk...

  5. Capital investment requirements for greenhouse gas emissions mitigation in power generation on near term to century time scales and global to regional spatial scales

    SciTech Connect (OSTI)

    Chaturvedi, Vaibhav; Clarke, Leon E.; Edmonds, James A.; Calvin, Katherine V.; Kyle, G. Page

    2014-11-01

    Electrification plays a crucial role in cost-effective greenhouse gas emissions mitigation strategies. Such strategies in turn carry implications for financial capital markets. This paper explores the implication of climate mitigation policy for capital investment demands by the electric power sector on decade to century time scales. We go further to explore the implications of technology performance and the stringency of climate policy for capital investment demands by the power sector. Finally, we discuss the regional distribution of investment demands. We find that stabilizing GHG emissions will require additional investment in the electricity generation sector over and above investments that would be need in the absence of climate policy, in the range of 16 to 29 Trillion US$ (60-110%) depending on the stringency of climate policy during the period 2015 to 2095 under default technology assumptions. This increase reflects the higher capital intensity of power systems that control emissions. Limits on the penetration of nuclear and carbon capture and storage technology could increase costs substantially. Energy efficiency improvements can reduce the investment requirement by 8 to21 Trillion US$ (default technology assumptions), depending on climate policy scenario with higher savings being obtained under the most stringent climate policy. The heaviest investments in power generation were observed in the China, India, SE Asia and Africa regions with the latter three regions dominating in the second half of the 21st century.

  6. 2015 CO2 Capture Technology Meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 Capture Technology Meeting 2015 NETL CO2 CAPTURE TECHNOLOGY MEETING June 23-26, 2015 Meeting Summary Previous Proceedings 2014: NETL CO2 Capture Technology Meeting 2013: NETL CO2 Capture Technology Meeting 2012: NETL CO2 Capture Technology Meeting Proceedings of the 2015 NETL CO2 Capture Technology Meeting Table of Contents Presentations Tuesday, June 23, 2015 Opening/Overview Systems Studies and Modeling Post-Combustion Membrane-Based Capture Wednesday, June 24, 2015 Post-Combustion

  7. Reversible Alteration of CO2 Adsorption upon Photochemical or Thermal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Treatment in a Metal-Organic Framework | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Reversible Alteration of CO2 Adsorption upon Photochemical or Thermal Treatment in a Metal-Organic Framework Previous Next List Jinhee Park , Daqiang Yuan , Khanh T. Pham , Jian-Rong Li , Andrey Yakovenko , and Hong-Cai Zhou, J. Am. Chem. Soc., 2012, 134 (1), pp 99-102 DOI: 10.1021/ja209197f Abstract Image Abstract: A metal-organic framework (MOF) for reversible

  8. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    of Publication: United States Language: English Subject: Environmental Sciences(54) Environmental Protection; CO2 Accounting, Risk Analysis, CO2 Sequestration, Sensitivity...

  9. Grangemouth Advanced CO2 Capture Project GRACE | Open Energy...

    Open Energy Info (EERE)

    Grangemouth Advanced CO2 Capture Project GRACE Jump to: navigation, search Name: Grangemouth Advanced CO2 Capture Project (GRACE) Place: United Kingdom Sector: Carbon Product:...

  10. CO2 Global Solutions International | Open Energy Information

    Open Energy Info (EERE)

    Global Solutions International Jump to: navigation, search Name: CO2 Global Solutions International Place: Madrid, Spain Zip: 28001 Sector: Carbon Product: CO2 Global Solutions is...

  11. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    Conference: EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2 Citation Details In-Document Search Title: EGS rock reactions ...

  12. Meeting the CO2 Challenge DEER 2002 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the CO2 Challenge DEER 2002 Meeting the CO2 Challenge DEER 2002 2002 DEER Conference Presentation: Ricardo PDF icon 2002deergraham.pdf More Documents & Publications Application...

  13. Theoretical Synthesis of Mixed Materials for CO2 Capture Applications...

    Office of Scientific and Technical Information (OSTI)

    Theoretical Synthesis of Mixed Materials for CO2 Capture Applications Citation Details In-Document Search Title: Theoretical Synthesis of Mixed Materials for CO2 Capture...

  14. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow ... Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated ...

  15. Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II

    SciTech Connect (OSTI)

    George J. Koperna Jr.; Vello A. Kuuskraa; David E. Riestenberg; Aiysha Sultana; Tyler Van Leeuwen

    2009-06-01

    This report serves as the final technical report and users manual for the 'Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II SBIR project. Advanced Resources International has developed a screening tool by which users can technically screen, assess the storage capacity and quantify the costs of CO2 storage in four types of CO2 storage reservoirs. These include CO2-enhanced oil recovery reservoirs, depleted oil and gas fields (non-enhanced oil recovery candidates), deep coal seems that are amenable to CO2-enhanced methane recovery, and saline reservoirs. The screening function assessed whether the reservoir could likely serve as a safe, long-term CO2 storage reservoir. The storage capacity assessment uses rigorous reservoir simulation models to determine the timing, ultimate storage capacity, and potential for enhanced hydrocarbon recovery. Finally, the economic assessment function determines both the field-level and pipeline (transportation) costs for CO2 sequestration in a given reservoir. The screening tool has been peer reviewed at an Electrical Power Research Institute (EPRI) technical meeting in March 2009. A number of useful observations and recommendations emerged from the Workshop on the costs of CO2 transport and storage that could be readily incorporated into a commercial version of the Screening Tool in a Phase III SBIR.

  16. Synthetic Catalysts for CO2 Storage: Catalytic Improvement of Solvent Capture Systems

    SciTech Connect (OSTI)

    None

    2010-08-15

    IMPACCT Project: LLNL is designing a process to pull CO2 out of the exhaust gas of coal-fired power plants so it can be transported, stored, or utilized elsewhere. Human lungs rely on an enzyme known as carbonic anhydrase to help separate CO2 from our blood and tissue as part of the normal breathing process. LLNL is designing a synthetic catalyst with the same function as this enzyme. The catalyst can be used to quickly capture CO2 from coal exhaust, just as the natural enzyme does in our lungs. LLNL is also developing a method of encapsulating chemical solvents in permeable microspheres that will greatly increase the speed of binding of CO2. The goal of the project is an industry-ready chemical vehicle that can withstand the harsh environments found in exhaust gas and enable new, simple process designs requiring less capital investment.

  17. Geological Sequestration of CO2 by Hydrous Carbonate Formation with Reclaimed Slag

    SciTech Connect (OSTI)

    Von L. Richards; Kent Peaslee; Jeffrey Smith

    2008-02-06

    The concept of this project is to develop a process that improves the kinetics of the hydrous carbonate formation reaction enabling steelmakers to directly remove CO2 from their furnace exhaust gas. It is proposed to bring the furnace exhaust stream containing CO2 in contact with reclaimed steelmaking slag in a reactor that has an environment near the unit activity of water resulting in the production of carbonates. The CO2 emissions from the plant would be reduced by the amount sequestered in the formation of carbonates. The main raw materials for the process are furnace exhaust gases and specially prepared slag.

  18. Second Phase of Innovative Technology Project to Capture CO2, Produce

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biofuels Launched in Ohio | Department of Energy Second Phase of Innovative Technology Project to Capture CO2, Produce Biofuels Launched in Ohio Second Phase of Innovative Technology Project to Capture CO2, Produce Biofuels Launched in Ohio August 9, 2012 - 1:00pm Addthis Washington, DC - A novel method to capture carbon dioxide (CO2) from flue gas and produce biofuels has been formally launched in the second phase of a Department of Energy (DOE) project at a nursery in Ohio. Successful

  19. Large-scale Screening of Zeolite Structures for CO2 Membrane Separations |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Large-scale Screening of Zeolite Structures for CO2 Membrane Separations Previous Next List J. Kim, M. Abouelnasr, L.-C. Lin, and B. Smit, J Am Chem Soc, 135, 7545-7552 (2013) DOI: 10.1021/ja400267g Abstract: We have conducted large-scale screening of zeolite materials for CO2/CH4 and CO2/N2 membrane separation applications using the free energy landscape of the guest molecules inside these porous materials. We

  20. CO2 Induced Phase Transitions in Diamine-Appended Metal-Organic Frameworks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome CO2 Induced Phase Transitions in Diamine-Appended Metal-Organic Frameworks Previous Next List Vlaisavljevich, Bess; Odoh, Samuel O.; Schnell, Sondre K.; Dzubak, Allison; Lee, Kyuho; Planas, Nora; Neaton, Jeffrey B.; Gagliardi, Laura; and Smit, Berend. CO2 Induced Phase Transitions in Diamine-Appended Metal-Organic Frameworks. Chem. Sci., 6, 5177-5185 (2015). DOI: 10.1039/c5sc01828e CO2 induced phase

  1. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil...

  2. Effect of temperature and CO2 concentration on laser-induced breakdown

    Office of Scientific and Technical Information (OSTI)

    spectroscopy measurements of alkali fume. (Journal Article) | SciTech Connect temperature and CO2 concentration on laser-induced breakdown spectroscopy measurements of alkali fume. Citation Details In-Document Search Title: Effect of temperature and CO2 concentration on laser-induced breakdown spectroscopy measurements of alkali fume. Laser-induced breakdown spectroscopy (LIBS) was used in the evaluation of aerosol concentration in the exhaust of an oxygen/natural-gas glass furnace.

  3. Hybrid Solvent-Membrane CO2 Capture: A Solvent/Membrane Hybrid Post-combustion CO2 Capture Process for Existing Coal-Fired Power Plants

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: The University of Kentucky is developing a hybrid approach to capturing CO2 from the exhaust gas of coal-fired power plants. In the first, CO2 is removed as flue gas is passed through an aqueous ammonium-based solvent. In the second, carbon-rich solution from the CO2 absorber is passed through a membrane that is designed to selectively transport the bound carbon, enhancing its concentration on the permeate side. The team’s approach would combine the best of both membrane- and solventbased carbon capture technologies. Under the ARPA-E award, the team is enabling the membrane operation to be a drop-in solution.

  4. Using hyperspectral plant signatures for CO2 leak detection during the 2008 ZERT CO2 sequestration field experiment in Bozeman, Montana

    SciTech Connect (OSTI)

    Male, E.J.; Pickles, W.L.; Silver, E.A.; Hoffmann, G.D.; Lewicki, J.; Apple, M.; Repasky, K.; Burton, E.A.

    2009-11-01

    Hyperspectral plant signatures can be used as a short-term, as well as long-term (100-yr timescale) monitoring technique to verify that CO2 sequestration fields have not been compromised. An influx of CO2 gas into the soil can stress vegetation, which causes changes in the visible to nearinfrared reflectance spectral signature of the vegetation. For 29 days, beginning on July 9th, 2008, pure carbon dioxide gas was released through a 100-meter long horizontal injection well, at a flow rate of 300 kg/day. Spectral signatures were recorded almost daily from an unmown patch of plants over the injection with a ''FieldSpec Pro'' spectrometer by Analytical Spectral Devices, Inc. Measurements were taken both inside and outside of the CO2 leak zone to normalize observations for other environmental factors affecting the plants.

  5. FUEL CONSUMPTION AND COST SAVINGS OF CLASS 8 HEAVY-DUTY TRUCKS POWERED BY NATURAL GAS

    SciTech Connect (OSTI)

    Gao, Zhiming; LaClair, Tim J; Daw, C Stuart; Smith, David E

    2013-01-01

    We compare the fuel consumption and greenhouse gas emissions of natural gas and diesel heavy-duty (HD) class 8 trucks under consistent simulated drive cycle conditions. Our study included both conventional and hybrid HD trucks operating with either natural gas or diesel engines, and we compare the resulting simulated fuel efficiencies, fuel costs, and payback periods. While trucks powered by natural gas engines have lower fuel economy, their CO2 emissions and costs are lower than comparable diesel trucks. Both diesel and natural gas powered hybrid trucks have significantly improved fuel economy, reasonable cost savings and payback time, and lower CO2 emissions under city driving conditions. However, under freeway-dominant driving conditions, the overall benefits of hybridization are considerably less. Based on payback period alone, non-hybrid natural gas trucks appear to be the most economic option for both urban and freeway driving environments.

  6. Continuous CO2 extractor and methods

    SciTech Connect (OSTI)

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  7. 10-MW Supercritical-CO2 Turbine

    Broader source: Energy.gov [DOE]

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  8. ARM - Campaign Instrument - co2lidar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lidar Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Carbon Dioxide Doppler Lidar (CO2LIDAR) Instrument Categories Cloud Properties Campaigns Remote Cloud Sensing (RCS) Field Evaluation [ Download Data ] Southern Great Plains, 1994.04.01 - 1994.05.31 Primary Measurements Taken The following measurements are those considered scientifically relevant. Refer to the datastream (netcdf) file headers for the list of all available

  9. Enhanced Coal Bed Methane Recovery and CO2 Sequestration in the Powder River Basin

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-06-01

    Unminable coal beds are potentially large storage reservoirs for the sequestration of anthropogenic CO2 and offer the benefit of enhanced methane production, which can offset some of the costs associated with CO2 sequestration. The objective of this report is to provide a final topical report on enhanced coal bed methane recovery and CO2 sequestration to the U.S. Department of Energy in fulfillment of a Big Sky Carbon Sequestration Partnership milestone. This report summarizes work done at Idaho National Laboratory in support of Phase II of the Big Sky Carbon Sequestration Partnership. Research that elucidates the interaction of CO2 and coal is discussed with work centering on the Powder River Basin of Wyoming and Montana. Sorption-induced strain, also referred to as coal swelling/shrinkage, was investigated. A new method of obtaining sorption-induced strain was developed that greatly decreases the time necessary for data collection and increases the reliability of the strain data. As coal permeability is a strong function of sorption-induced strain, common permeability models were used to fit measured permeability data, but were found inadequate. A new permeability model was developed that can be directly applied to coal permeability data obtained under laboratory stress conditions, which are different than field stress conditions. The coal permeability model can be used to obtain critical coal parameters that can be applied in field models. An economic feasibility study of CO2 sequestration in unminable coal seams in the Powder River Basin of Wyoming was done. Economic analyses of CO2 injection options are compared. Results show that injecting flue gas to recover methane from CBM fields is marginally economical; however, this method will not significantly contribute to the need to sequester large quantities of CO2. Separating CO2 from flue gas and injecting it into the unminable coal zones of the Powder River Basin seam is currently uneconomical, but can effectively sequester over 86,000 tons (78,200 Mg) of CO2 per acre while recovering methane to offset costs. The cost to separate CO2 from flue gas was identified as the major cost driver associated with CO2 sequestration in unminable coal seams. Improvements in separations technology alone are unlikely to drive costs low enough for CO2 sequestration in unminable coal seams in the Powder River Basin to become economically viable. Breakthroughs in separations technology could aid the economics, but in the Powder River Basin, they cannot achieve the necessary cost reductions for breakeven economics without incentives.

  10. Opportunities for market-based programs worldwide that reduce greenhouse gas emissions: Initial Observations from Missions to the Philippines, South Africa, and Mexico

    SciTech Connect (OSTI)

    Stanton-Hoyle, D.R.

    1998-07-01

    Globally, governments and industries are implementing innovative voluntary programs to reduce greenhouse gas emissions. Often these programs encourage groups to use cost effective technologies that capture market-based forces. These programs are successful because they capitalize on existing opportunities where both the environment and the participants can benefit (i.e., win-win opportunities). This paper documents efforts to investigate these kinds of win-win opportunities in three developing countries: the Philippines, South Africa, and Mexico. Initial observations are provided as fresh information from the field, drawing on six missions during the last nine months. Utility costs, interest rates, and overall economic health appear to critically affect opportunities in each country. By contrast, details of heating, ventilating and air-conditioning (HVAC) design and local climate were often important differences between countries. These affect opportunities, for example, to achieve significant savings from cooling systems or not. Looking at the success of ESCOs was somewhat surprising. One might expect to see the most successful ESCO activity where utility costs are high and upgrade opportunities are plentiful (such as in the Philippines). This was not the case, however, as research in the Philippines did not reveal even one active ESCO contract yet. Design practices for new construction were in need of the same thing that helps US design teams do a better job of energy-efficient design, better communications between design team members. Finally, industrial firms were doing a variety of EE upgrades in each country, but this level of activity was relatively small compared to what should be cost effective.

  11. "GREENHOUSE GAS NAME","GREENHOUSE GAS CODE","FORMULA","GWP"

    U.S. Energy Information Administration (EIA) Indexed Site

    Trifluoride","NF3","NF3",10800,17200 "1 Intergovernmental Panel on Climate Change, Climate Change 2001: The Scientific Basis (Cambridge, UK: Cambridge University Press, 2001). ...

  12. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known signal-to-noise problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  13. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  14. A Review of Hazardous Chemical Species Associated with CO2 Capturefrom Coal-Fired Power Plants and Their Potential Fate in CO2 GeologicStorage

    SciTech Connect (OSTI)

    Apps, J.A.

    2006-02-23

    Conventional coal-burning power plants are major contributors of excess CO2 to the atmospheric inventory. Because such plants are stationary, they are particularly amenable to CO2 capture and disposal by deep injection into confined geologic formations. However, the energy penalty for CO2 separation and compression is steep, and could lead to a 30-40 percent reduction in useable power output. Integrated gas combined cycle (IGCC) plants are thermodynamically more efficient, i.e.,produce less CO2 for a given power output, and are more suitable for CO2 capture. Therefore, if CO2 capture and deep subsurface disposal were to be considered seriously, the preferred approach would be to build replacement IGCC plants with integrated CO2 capture, rather than retrofit existing conventional plants. Coal contains minor quantities of sulfur and nitrogen compounds, which are of concern, as their release into the atmosphere leads to the formation of urban ozone and acid rain, the destruction of stratospheric ozone, and global warming. Coal also contains many trace elements that are potentially hazardous to human health and the environment. During CO2 separation and capture, these constituents could inadvertently contaminate the separated CO2 and be co-injected. The concentrations and speciation of the co-injected contaminants would differ markedly, depending on whether CO2 is captured during the operation of a conventional or an IGCC plant, and the specific nature of the plant design and CO2 separation technology. However, regardless of plant design or separation procedures, most of the hazardous constituents effectively partition into the solid waste residue. This would lead to an approximately two order of magnitude reduction in contaminant concentration compared with that present in the coal. Potential exceptions are Hg in conventional plants, and Hg and possibly Cd, Mo and Pb in IGCC plants. CO2 capture and injection disposal could afford an opportunity to deliberately capture environmental pollutants in the gaseous state and co-inject them with the CO2, in order to mitigate problems associated with solid waste disposal in surface impoundments. Under such conditions, the injected pollutant concentrations could be roughly equivalent to their concentrations in the coal feed. The fate of the injected contaminants can only be determined through further testing and geochemical modeling. However, the concentrations of inadvertent contaminants in the injected CO2 would probably be comparable to their ambient concentrations in confining shales of the injection zone. In general, the aqueous concentrations of hazardous constituents in distal parts of the injection zone, regardless of source, are likely to be limited by equilibrium with respect to coexisting solid phases under the acid conditions induced by the dissolved high pressure CO2, rather than by the initial concentrations of injected contaminants. Therefore, even if a deliberate policy of contaminant recovery and injection were to be pursued, water quality in USDWs would more likely depend on thermodynamic controls governing aqueous contaminant concentrations in the presence of high pressure CO2 rather than in the injected CO2. The conclusions reached in this report are preliminary, and should be confirmed through more comprehensive data evaluation and supporting geochemical modeling.

  15. Supercritical CO2 Tech Team | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Supercritical CO2 Tech Team Supercritical CO2 Tech Team Supercritical CO2 Tech Team The purpose of the Supercritical Carbon Dioxide (sCO2) Technology Team is to use a collaborative approach to develop and facilitate commercialization of sCO2 energy conversion technology. Within the Department of Energy (DOE), SCO2 Brayton Cycle energy conversion could benefit research and development efforts in the offices of Nuclear Energy, Fossil Energy and Energy Efficiency and Renewable Energy. The Tech Team

  16. The Greenhouse Gases, Regulated Emissions, and Energy Use in...

    Open Energy Info (EERE)

    Energy Use in Transportation Model (GREET Fleet) AgencyCompany Organization: Argonne National Laboratory Sector: Energy Focus Area: Greenhouse Gas, Transportation Phase:...

  17. CEQ Issues Revised Draft Guidance on Consideration of Greenhouse...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Change in NEPA Reviews CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews December 22, 2014 - ...

  18. Knowledge Partnership for Measuring Air Pollution and Greenhouse...

    Open Energy Info (EERE)

    Knowledge Partnership for Measuring Air Pollution and Greenhouse Gas Emissions in Asia Jump to: navigation, search Name Knowledge Partnership for Measuring Air Pollution and...

  19. Integration & Co-development of a Geophysical CO2 Monitoring Suite

    SciTech Connect (OSTI)

    Friedmann, S J

    2007-07-24

    Carbon capture and sequestration (CCS) has emerged as a key technology for dramatic short-term reduction in greenhouse gas emissions in particular from large stationary. A key challenge in this arena is the monitoring and verification (M&V) of CO2 plumes in the deep subsurface. Towards that end, we have developed a tool that can simultaneously invert multiple sub-surface data sets to constrain the location, geometry, and saturation of subsurface CO2 plumes. We have focused on a suite of unconventional geophysical approaches that measure changes in electrical properties (electrical resistance tomography, electromagnetic induction tomography) and bulk crustal deformation (til-meters). We had also used constraints of the geology as rendered in a shared earth model (ShEM) and of the injection (e.g., total injected CO{sub 2}). We describe a stochastic inversion method for mapping subsurface regions where CO{sub 2} saturation is changing. The technique combines prior information with measurements of injected CO{sub 2} volume, reservoir deformation and electrical resistivity. Bayesian inference and a Metropolis simulation algorithm form the basis for this approach. The method can (a) jointly reconstruct disparate data types such as surface or subsurface tilt, electrical resistivity, and injected CO{sub 2} volume measurements, (b) provide quantitative measures of the result uncertainty, (c) identify competing models when the available data are insufficient to definitively identify a single optimal model and (d) rank the alternative models based on how well they fit available data. We present results from general simulations of a hypothetical case derived from a real site. We also apply the technique to a field in Wyoming, where measurements collected during CO{sub 2} injection for enhanced oil recovery serve to illustrate the method's performance. The stochastic inversions provide estimates of the most probable location, shape, volume of the plume and most likely CO{sub 2} saturation. The results suggest that the method can reconstruct data with poor signal to noise ratio and use hard constraints available from many sites and applications. External interest in the approach and method is high, and already commercial and DOE entities have requested technical work using the newly developed methodology for CO{sub 2} monitoring.

  20. Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy

    SciTech Connect (OSTI)

    Arey, Bruce W.; Kovarik, Libor; Wang, Zheming; Felmy, Andrew R.

    2011-10-10

    The capture and storage of carbon dioxide and other greenhouse gases in deep geologic formations represents one of the most promising options for mitigating the impacts of greenhouse gases on global warming. In this regard, mineral-fluid interactions are of prime importance since such reactions can result in the long term sequestration of CO2 by trapping in mineral phases. Recently it has been recognized that interactions with neat to water-saturated non-aqueous fluids are of prime importance in understanding mineralization reactions since the introduced CO2 is likely to contain water initially or soon after injection and the supercritical CO2 (scCO2) is less dense than the aqueous phase which can result in a buoyant scCO2 plume contacting the isolating caprock. As a result, unraveling the molecular/microscopic mechanisms of mineral transformation in neat to water saturated scCO2 has taken on an added important. In this study, we are examining the interfacial reactions of the olivine mineral forsterite (Mg2SiO4) over a range of water contents up to and including complete water saturation in scCO2. The surface precipitates that form on the reacted forsterite grains are extremely fragile and difficult to experimentally characterize. In order to address this issue we have developed experimental protocols for preparing and imaging electron-transparent samples from fragile structures. These electron-transparent samples are then examined using a combination of STEM/EDX, FIB-TEM, and helium ion microscope (HIM) imaging (Figures 1-3). This combination of capabilities has provided unique insight into the geochemical processes that occur on scCO2 reacted mineral surfaces. The experimental procedures and protocols that have been developed also have useful applications for examining fragile structures on a wide variety of materials. This research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research located at Pacific Northwest National Laboratory.

  1. Electrolysis byproduct D2O provides a third way to mitigate CO2

    SciTech Connect (OSTI)

    Schenewerk, William Ernest

    2009-09-01

    Rapid atomic power deployment may be possible without using fast breeder reactors or making undue demands on uranium resource. Using by-product D2O and thorium-U233 in CANDU and RBMK piles may circumvent need for either fast breeder reactors or seawater uranium. Atmospheric CO2 is presently increasing 2.25%/year in proportion to 2.25%/year exponential fossil fuel consumption increase. Roughly 1/3 anthropologic CO2 is removed by various CO2 sinks. CO2 removal is modelled as being proportional to 45-year-earlier CO2 amount above 280 ppm-C Water electrolysis produces roughly 0.1 kg-D20/kWe-y. Material balance assumes each electrolysis stage increases D2O bottoms concentration times 3. Except for first two electrolysis stages, all water from hydrogen consumption is returned to electrolysis. The unique characteristic of this process is the ability to economically burn all deuterium-enriched H2 in vehicles. Condensate from vehicles returns to appropriate electrolysis stage. Fuel cell condensate originally from reformed natural gas may augment second-sage feed. Atomic power expansion is 5%/year, giving 55000 GWe by 2100. World primary energy increases 2.25%/y, exceeding 4000 EJ/y by 2100. CO2 maximum is roughly 600 ppm-C around year 2085. CO2 declines back below 300 ppm-C by 2145 if the 45-year-delay seawater sink remains effective.

  2. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    A2. Glossary Acid stabilization: A circumstance where the pH of the waste mixture in an animal manure management system is maintained near 7.0, optimal conditions for methane production. Aerobic bacteria: Microorganisms living, active, or occurring only in the presence of oxygen. Aerobic decomposition: The breakdown of a molecule into simpler molecules or atoms by microorganisms under favorable conditions of oxygenation. Aerosols: Airborne particles. Afforestation: Planting of new forests on

  3. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    grasslands 34 Net carbon dioxide sequestration in U.S. urban trees, yard trimmings, and food scraps 35 Emissions of carbon dioxide from biofuelbioenergy use by sector and fuel

  4. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  5. International CO2 Power Cycles Symposium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    International CO2 Power Cycles Symposium March 29-31, 2016 Accommodations Hilton Palacio Del Rio 200 South Alamo Street San Antonio, TX 78205 (210) 222-1400 The Hilton Palacio Del Rio Hotel is set on the banks of San Antonio's River Walk, this city center hotel is within close walking distance of a number of great San Antonio attractions. The overnight room rate for federal employees with a valid government ID is $120.00 plus 16.75% tax (prevailing government per diem), for non-government

  6. CO2 Heat Pump Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO 2 Heat Pump Water Heater 2014 Building Technologies Office Peer Review Evaporator Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Project Summary Timeline: Start date: Oct 1, 2009 Planned end date: Sep 30, 2015 Key Milestones 1. Optimize wrap-around coil; Dec 2013 2. Achieve EF>2.0; March 2014 Budget: Total DOE $ to date: $2,147k Total future DOE $: $200k Target Market/Audience: Residential electric water heating Key Partners: GE Appliances CRADA partner Project Goal:

  7. Developing a Comprehensive Risk Assessment Framework for Geological Storage CO2

    SciTech Connect (OSTI)

    Duncan, Ian

    2014-08-31

    The operational risks for CCS projects include: risks of capturing, compressing, transporting and injecting CO₂; risks of well blowouts; risk that CO₂ will leak into shallow aquifers and contaminate potable water; and risk that sequestered CO₂ will leak into the atmosphere. This report examines these risks by using information on the risks associated with analogue activities such as CO2 based enhanced oil recovery (CO2-EOR), natural gas storage and acid gas disposal. We have developed a new analysis of pipeline risk based on Bayesian statistical analysis. Bayesian theory probabilities may describe states of partial knowledge, even perhaps those related to non-repeatable events. The Bayesian approach enables both utilizing existing data and at the same time having the capability to adsorb new information thus to lower uncertainty in our understanding of complex systems. Incident rates for both natural gas and CO2 pipelines have been widely used in papers and reports on risk of CO2 pipelines as proxies for the individual risk created by such pipelines. Published risk studies of CO2 pipelines suggest that the individual risk associated with CO2 pipelines is between 10-3 and 10-4, which reflects risk levels approaching those of mountain climbing, which many would find unacceptably high. This report concludes, based on a careful analysis of natural gas pipeline failures, suggests that the individual risk of CO2 pipelines is likely in the range of 10-6 to 10-7, a risk range considered in the acceptable to negligible range in most countries. If, as is commonly thought, pipelines represent the highest risk component of CCS outside of the capture plant, then this conclusion suggests that most (if not all) previous quantitative- risk assessments of components of CCS may be orders of magnitude to high. The potential lethality of unexpected CO2 releases from pipelines or wells are arguably the highest risk aspects of CO2 enhanced oil recovery (CO2-EOR), carbon capture, and storage (CCS). Assertions in the CCS literature, that CO2 levels of 10% for ten minutes, or 20 to 30% for a few minutes are lethal to humans, are not supported by the available evidence. The results of published experiments with animals exposed to CO2, from mice to monkeys, at both normal and depleted oxygen levels, suggest that lethal levels of CO2 toxicity are in the range 50 to 60%. These experiments demonstrate that CO2 does not kill by asphyxia, but rather is toxic at high concentrations. It is concluded that quantitative risk assessments of CCS have overestimated the risk of fatalities by using values of lethality a factor two to six lower than the values estimated in this paper. In many dispersion models of CO2 releases from pipelines, no fatalities would be predicted if appropriate levels of lethality for CO2 had been used in the analysis.

  8. A Feasibility Study of Non-Seismic Geophysical Methods forMonitoring Geologic CO2 Sequestration

    SciTech Connect (OSTI)

    Gasperikova, Erika; Hoversten, G. Michael

    2006-07-01

    Because of their wide application within the petroleumindustry it is natural to consider geophysical techniques for monitoringof CO2 movement within hydrocarbon reservoirs, whether the CO2 isintroduced for enhanced oil/gas recovery or for geologic sequestration.Among the available approaches to monitoring, seismic methods are by farthe most highly developed and applied. Due to cost considerations, lessexpensive techniques have recently been considered. In this article, therelative merits of gravity and electromagnetic (EM) methods as monitoringtools for geological CO2 sequestration are examined for two syntheticmodeling scenarios. The first scenario represents combined CO2 enhancedoil recovery (EOR) and sequestration in a producing oil field, theSchrader Bluff field on the north slope of Alaska, USA. The secondscenario is a simplified model of a brine formation at a depth of 1,900m.

  9. Molecular Simulation Study of the Competitive Adsorption of H2O and CO2 in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zeolite 13X | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Simulation Study of the Competitive Adsorption of H2O and CO2 in Zeolite 13X Previous Next List Lennart Joos, Joseph A. Swisher, and Berend Smit, Langmuir 29, 15936-15942 (2013) DOI: 10.1021/la403824g Abstract Image Abstract: The presence of H2O in postcombustion gas streams is an important technical issue for deploying CO2-selective adsorbents. Because of its permanent dipole, H2O can interact

  10. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  11. Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers

    SciTech Connect (OSTI)

    Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; Yin, Xiaolong; Pruess, Karsten; Oldenburg, Curt; Winterfeld, Philip; Zhang, Ronglei

    2014-09-30

    This report is the final scientific one for the award DE- FE0000988 entitled Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers. The work has been divided into six tasks. In task, Development of a Three-Phase Non-Isothermal CO2 Flow Module, we developed a fluid property module for brine-CO2 mixtures designed to handle all possible phase combinations of aqueous phase, sub-critical liquid and gaseous CO2, supercritical CO2, and solid salt. The thermodynamic and thermophysical properties of brine-CO2 mixtures (density, viscosity, and specific enthalpy of fluid phases; partitioning of mass components among the different phases) use the same correlations as an earlier fluid property module that does not distinguish between gaseous and liquid CO2-rich phases. We verified the fluid property module using two leakage scenarios, one that involves CO2 migration up a blind fault and subsequent accumulation in a secondary parasitic reservoir at shallower depth, and another investigating leakage of CO2 from a deep storage reservoir along a vertical fault zone. In task, Development of a Rock Mechanical Module, we developed a massively parallel reservoir simulator for modeling THM processes in porous media brine aquifers. We derived, from the fundamental equations describing deformation of porous elastic media, a momentum conservation equation relating mean stress, pressure, and temperature, and incorporated it alongside the mass and energy conservation equations from the TOUGH2 formulation, the starting point for the simulator. In addition, rock properties, namely permeability and porosity, are functions of effective stress and other variables that are obtained from the literature. We verified the simulator formulation and numerical implementation using analytical solutions and example problems from the literature. For the former, we matched a one-dimensional consolidation problem and a two-dimensional simulation of the Mandel-Cryer effect. For the latter, we obtained a good match of temperature and gas saturation profiles, and surface uplift, after injection of hot fluid into a model of a caldera structure. In task, Incorporation of Geochemical Reactions of Selected Important Species, we developed a novel mathematical model of THMC processes in porous and fractured saline aquifers, simulating geo-chemical reactions associated with CO2 sequestration in saline aquifers. Two computational frameworks, sequentially coupled and fully coupled, were used to simulate the reactions and transport. We verified capabilities of the THMC model to treat complex THMC processes during CO2 sequestration by analytical solutions and we constructed reactive transport models to analyze the THMC process quantitatively. Three of these are 1D reactive transport under chemical equilibrium, a batch reaction model with equilibrium chemical reactions, and a THMC model with CO2 dissolution. In task Study of Instability in CO2 Dissolution-Diffusion-Convection Processes, We reviewed literature related to the study of density driven convective flows and on the instability of CO2 dissolution-diffusion-convection processes. We ran simulations that model the density-driven flow instability that would occur during CO2 sequestration. CO2 diffused through the top of the system and dissolved in the aqueous phase there, increasing its density. Density fingers formed along the top boundary, and coalesced into a few prominent ones, causing convective flow that forced the fluid to the system bottom. These simulations were in two and three dimensions. We ran additional simulations of convective mixing with density contrast caused by variable dissolved CO2 concentration in saline water, modeled after laboratory experiments in which supercritical CO2 was circulated in the headspace above a brine saturated packed sand in a pressure vessel. As CO2 dissolved into the upper part of the saturated sand, liquid phase density increases causing instability and setting off convective mixing. We obtained good agreement

  12. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2008-02-29

    There is growing interest regarding the potential size of a future U.S. dedicated CO2 pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale. In trying to understand the potential scale of a future national CO2 pipeline network, comparisons are often made to the existing pipeline networks used to deliver natural gas and liquid hydrocarbons to markets within the U.S. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The data presented here suggest that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a significant obstacle for the commercial deployment of CCS technologies.

  13. CO2 Capture and Regeneration at Low Temperatures: Novel Non-Aqueous CO2 Solvents and Capture Process with Substantially Reduced Energy Penalties

    SciTech Connect (OSTI)

    None

    2010-07-01

    IMPACCT Project: RTI is developing a solvent and process that could significantly reduce the temperature associated with regenerating solvent and CO2 captured from the exhaust gas of coal-fired power plants. Traditional CO2 removal processes using water-based solvents require significant amount of steam from power plants in order to regenerate the solvent so it can be reused after each reaction. RTIs solvents can be better at absorbing CO2 than many water-based solvents, and are regenerated at lower temperatures using less steam. Thus, industrial heat that is normally too cool to re-use can be deployed for regeneration, rather than using high-value steam. This saves the power plant money, which results in increased cost savings for consumers.

  14. REDUCING UNCERTAINTIES IN MODEL PREDICTIONS VIA HISTORY MATCHING OF CO2 MIGRATION AND REACTIVE TRANSPORT MODELING OF CO2 FATE AT THE SLEIPNER PROJECT

    SciTech Connect (OSTI)

    Zhu, Chen

    2015-03-31

    An important question for the Carbon Capture, Storage, and Utility program is “can we adequately predict the CO2 plume migration?” For tracking CO2 plume development, the Sleipner project in the Norwegian North Sea provides more time-lapse seismic monitoring data than any other sites, but significant uncertainties still exist for some of the reservoir parameters. In Part I, we assessed model uncertainties by applying two multi-phase compositional simulators to the Sleipner Benchmark model for the uppermost layer (Layer 9) of the Utsira Sand and calibrated our model against the time-lapsed seismic monitoring data for the site from 1999 to 2010. Approximate match with the observed plume was achieved by introducing lateral permeability anisotropy, adding CH4 into the CO2 stream, and adjusting the reservoir temperatures. Model-predicted gas saturation, CO2 accumulation thickness, and CO2 solubility in brine—none were used as calibration metrics—were all comparable with the interpretations of the seismic data in the literature. In Part II & III, we evaluated the uncertainties of predicted long-term CO2 fate up to 10,000 years, due to uncertain reaction kinetics. Under four scenarios of the kinetic rate laws, the temporal and spatial evolution of CO2 partitioning into the four trapping mechanisms (hydrodynamic/structural, solubility, residual/capillary, and mineral) was simulated with ToughReact, taking into account the CO2-brine-rock reactions and the multi-phase reactive flow and mass transport. Modeling results show that different rate laws for mineral dissolution and precipitation reactions resulted in different predicted amounts of trapped CO2 by carbonate minerals, with scenarios of the conventional linear rate law for feldspar dissolution having twice as much mineral trapping (21% of the injected CO2) as scenarios with a Burch-type or Alekseyev et al.–type rate law for feldspar dissolution (11%). So far, most reactive transport modeling (RTM) studies for CCUS have used the conventional rate law and therefore simulated the upper bound of mineral trapping. However, neglecting the regional flow after injection, as most previous RTM studies have done, artificially limits the extent of geochemical reactions as if it were in a batch system. By replenishing undersaturated groundwater from upstream, the Utsira Sand is reactive over a time scale of 10,000 years. The results from this project have been communicated via five peer-reviewed journal articles, four conference proceeding papers, and 19 invited and contributed presentations at conferences and seminars.

  15. CO2 stimulation of photosynthesis is not sustained during long-term (12 years) FACE treatments in Liquidambar styraciflua

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Warren, Jeffrey; Jensen, Anna M; Medlyn, Belinda; Norby, Richard J; Tissue, David Thomas

    2015-01-01

    Elevated atmospheric CO2 (eCO2) often increases photosynthetic CO2 assimilation (A) in field studies of temperate tree species, although there is evidence that the increases may decline through time due to biochemical and morphological acclimation, and environmental constraints. Indeed, at the free air CO2 enrichment (FACE) study in Oak Ridge, Tennessee, A was increased in 12-year-old sweetgum trees following two years of ~40% enhancement of CO2. A was re-assessed a decade later to determine if initial enhancement of CO2 was sustained through time. Measurements were conducted at prevailing CO2 and temperature on detached, re-hydrated branches using a portable gas exchange system.more » Photosynthetic CO2 response curves (A-Ci curves) were contrasted with earlier measurements using consistent leaf photosynthesis model equations. Relationships between maximum electron transport rate (Jmax), maximum Rubisco activity (Vcmax) and foliar nitrogen (N) and chlorophyll content were assessed. In 1999, light-saturated photosynthesis (Asat) for eCO2 treatments was 15.4 0.8 mol m-2 s-1, 22% higher than aCO2 treatments (P<0.01). By 2009, Asat declined to <50% of 1999 values, and there was no longer a significant effect of eCO2 (Asat = 6.9 or 5.7 0.7 mol m-2 s-1 for eCO2 or aCO2, respectively). In 1999, there was no treatment effect on area-based foliar N; however, by 2008, N content in eCO2 foliage was 17% less than in aCO2 foliage. Photosynthetic N use efficiency (Asat:N) was greater in eCO2 in 1999 resulting in greater Asat despite similar N content, but the enhanced efficiency in eCO2 trees was lost as foliar N declined to sub-optimal levels. There was no treatment difference in the declining linear relationships between Jmax or Vcmax with declining N, or in the ratio of Jmax:Vcmax through time. Results suggest that initial enhancement of photosynthesis to elevated CO2 will not be sustained through time if nitrogen becomes limited.« less

  16. CO2 stimulation of photosynthesis is not sustained during long-term (12 years) FACE treatments in Liquidambar styraciflua

    SciTech Connect (OSTI)

    Warren, Jeffrey; Jensen, Anna M; Medlyn, Belinda; Norby, Richard J; Tissue, David Thomas

    2015-01-01

    Elevated atmospheric CO2 (eCO2) often increases photosynthetic CO2 assimilation (A) in field studies of temperate tree species, although there is evidence that the increases may decline through time due to biochemical and morphological acclimation, and environmental constraints. Indeed, at the free air CO2 enrichment (FACE) study in Oak Ridge, Tennessee, A was increased in 12-year-old sweetgum trees following two years of ~40% enhancement of CO2. A was re-assessed a decade later to determine if initial enhancement of CO2 was sustained through time. Measurements were conducted at prevailing CO2 and temperature on detached, re-hydrated branches using a portable gas exchange system. Photosynthetic CO2 response curves (A-Ci curves) were contrasted with earlier measurements using consistent leaf photosynthesis model equations. Relationships between maximum electron transport rate (Jmax), maximum Rubisco activity (Vcmax) and foliar nitrogen (N) and chlorophyll content were assessed. In 1999, light-saturated photosynthesis (Asat) for eCO2 treatments was 15.4 0.8 mol m-2 s-1, 22% higher than aCO2 treatments (P<0.01). By 2009, Asat declined to <50% of 1999 values, and there was no longer a significant effect of eCO2 (Asat = 6.9 or 5.7 0.7 mol m-2 s-1 for eCO2 or aCO2, respectively). In 1999, there was no treatment effect on area-based foliar N; however, by 2008, N content in eCO2 foliage was 17% less than in aCO2 foliage. Photosynthetic N use efficiency (Asat:N) was greater in eCO2 in 1999 resulting in greater Asat despite similar N content, but the enhanced efficiency in eCO2 trees was lost as foliar N declined to sub-optimal levels. There was no treatment difference in the declining linear relationships between Jmax or Vcmax with declining N, or in the ratio of Jmax:Vcmax through time. Results suggest that initial enhancement of photosynthesis to elevated CO2 will not be sustained through time if nitrogen becomes limited.

  17. CO2 Capture and Storage Project, Education and Training Center...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of CO2 each year. When operations begin in 2013, the CO2 will be captured from Archer Daniels Midland's ethanol plant in Decatur, transported via a mile-long pipeline, and...

  18. Shell Future Fuels and CO2 | Open Energy Information

    Open Energy Info (EERE)

    Shell Future Fuels and CO2 Jump to: navigation, search Name: Shell Future Fuels and CO2 Place: Glasgow, Scotland, United Kingdom Zip: G1 9BG Sector: Hydro, Hydrogen Product:...

  19. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  20. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    up with a net reduction in the CO2 emitted. Thus, effective catalysts that can lower the energy requirements for CO2 chemical reactions are an important part of the equation....

  1. Secretary Chu Announces Six Projects to Convert Captured CO2...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Novomer's novel catalyst technology enables CO2 to react with petrochemical epoxides to create a family of thermoplastic polymers that are up to 50 percent by weight CO2. The ...

  2. CantorCO2e | Open Energy Information

    Open Energy Info (EERE)

    CantorCO2e Jump to: navigation, search Name: CantorCO2e Place: London, Greater London, United Kingdom Zip: E14 5RD Product: London-headquartered emissions broker and fund manager...

  3. CO2 Capture Poject CCP | Open Energy Information

    Open Energy Info (EERE)

    CO2 Capture Poject CCP Jump to: navigation, search Name: CO2 Capture Poject (CCP) Place: United Kingdom Sector: Carbon Product: CCP is a partnership of energy companies and...

  4. Post-Combustion CO2 Control | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Compressing captured CO2 from atmospheric pressure to pipeline pressure (1,200-2,200 ... NETL's post-combustion CO2 control technology R&D program includes projects directed at ...

  5. CO2 Saline Storage Demonstration in Colorado Sedimentary Basins...

    Office of Scientific and Technical Information (OSTI)

    One such option is to store at least some emitted CO2 underground. In this NETL-sponsored CO2 sequestration project, the Colorado School of Mines and our partners at the University ...

  6. CO2ReMoVe | Open Energy Information

    Open Energy Info (EERE)

    of industrial, research and service organizations with experience in CO2 geological storage. References: CO2ReMoVe1 This article is a stub. You can help OpenEI by expanding...

  7. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    a synthesis of net land-atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990-2009. Only CO2 is considered, not methane or...

  8. CO2 Injection Begins in Illinois | Department of Energy

    Office of Environmental Management (EM)

    CO2 Injection Begins in Illinois CO2 Injection Begins in Illinois November 17, 2011 - 12:00pm Addthis Washington, DC - The Midwest Geological Sequestration Consortium (MGSC), one of seven regional partnerships created by the U.S. Department of Energy (DOE) to advance carbon storage technologies nationwide, has begun injecting carbon dioxide (CO2) for their large-scale CO2 injection test in Decatur, Illinois. The test is part of the development phase of the Regional Carbon Sequestration

  9. Risk Evaluation for CO2 Geosequestration in the Knox Supergroup, Illinois Basin Final Report

    SciTech Connect (OSTI)

    Hnottavange-Telleen, Ken; Leetaru, Hannes

    2014-09-30

    This report describes a process and provides seed information for identifying and evaluating risks pertinent to a hypothetical carbon dioxide (CO2) capture and sequestration (CCS) project. In the envisioned project, the target sequestration reservoir rock is the Potosi Formation of the Knox Supergroup. The Potosi is identified as a potential target formation because (1) at least locally, it contains vuggy to cavernous layers that have very high porosity, and (2) it is present in areas where the deeper Mt. Simon Sandstone (a known potential reservoir unit) is absent or nonporous. The key report content is discussed in Section 3.3, which describes two lists of Features, Events, and Processes (FEPs) that should be considered during the design stage of such a project. These lists primarily highlight risk elements particular to the establishment of the Potosi as the target formation in general. The lists are consciously incomplete with respect to risk elements that would be relevant for essentially all CCS projects regardless of location or geology. In addition, other risk elements specific to a particular future project site would have to be identified. Sources for the FEPs and scenarios listed here include the iconic Quintessa FEPs list developed for the International Energy Agency Greenhouse Gas (IEAGHG) Programme; previous risk evaluation projects executed by Schlumberger Carbon Services; and new input solicited from experts currently working on aspects of CCS in the Knox geology. The projects used as sources of risk information are primarily those that have targeted carbonate reservoir rocks similar in age, stratigraphy, and mineralogy to the Knox-Potosi. Risks of using the Potosi Formation as the target sequestration reservoir for a CCS project include uncertainties about the levels of porosity and permeability of that rock unit; the lateral consistency and continuity of those properties; and the ability of the project team to identify suitable (i.e., persistently porous and permeable) injection depths within the overall formation. Less direct implications include the vertical position of the Potosi within the rock column and the absence of a laterally extensive shale caprock immediately overlying the Potosi. Based on modeling work done partly in association with this risk report, risks that should also be evaluated include the ability of available methods to predict and track the development of a CO2 plume as it migrates away from the injection point(s). The geologic and hydrodynamic uncertainties present risks that are compounded at the stage of acquiring necessary drilling and injection permits. It is anticipated that, in the future, a regional geologic study or CO2-emitter request may identify a small specific area as a prospective CCS project site. At that point, the FEPs lists provided in this report should be evaluated by experts for their relative levels of risk. A procedure for this evaluation is provided. The higher-risk FEPs should then be used to write project-specific scenarios that may themselves be evaluated for risk. Then, actions to reduce and to manage risk can be described and undertaken. The FEPs lists provided as Appendix 2 should not be considered complete, as potentially the most important risks are ones that have not yet been thought of. But these lists are intended to include the most important risk elements pertinent to a Potosi-target CCS project, and they provide a good starting point for diligent risk identification, evaluation, and management.

  10. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  11. Metal Organic Framework Research: High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture

    SciTech Connect (OSTI)

    None

    2010-08-01

    IMPACCT Project: LBNL is developing a method for identifying the best metal organic frameworks for use in capturing CO2 from the flue gas of coal-fired power plants. Metal organic frameworks are porous, crystalline compounds that, based on their chemical structure, vary considerably in terms of their capacity to grab hold of passing CO2 molecules and their ability to withstand the harsh conditions found in the gas exhaust of coal-fired power plants. Owing primarily to their high tunability, metal organic frameworks can have an incredibly wide range of different chemical and physical properties, so identifying the best to use for CO2 capture and storage can be a difficult task. LBNL uses high-throughput instrumentation to analyze nearly 100 materials at a time, screening them for the characteristics that optimize their ability to selectively adsorb CO2 from coal exhaust. Their work will identify the most promising frameworks and accelerate their large-scale commercial development to benefit further research into reducing the cost of CO2 capture and storage.

  12. CO2 Heat Pump Water Heater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater CO2 Heat Pump Water Heater Prototype<br /> Credit: Oak Ridge National Lab CO2 Heat Pump Water Heater Prototype Credit: Oak Ridge National Lab Lead Performer: Oak Ridge National Laboratory - Oak Ridge, TN Partners: General Electric Appliances - Louisville, KY DOE Funding: $2,147,000 Cost Share: Provided by CRADA partner Project Term: 10/1/2009 - 9/30/2015 Project Objective This project is developing a carbon dioxide (CO2) heat pump water

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  14. Exploring the activity of a novel Au/TiC(001) model catalyst towards CO and CO2 hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Asara, Gian Giacomo; Ricart, Josep M.; Rodriguez, Jose A.; Illas, Francesc

    2015-02-02

    Small metallic nanoparticles supported on transition metal carbides exhibit an unexpected high activity towards a series of chemical reactions. In particular, the Au/TiC system has proven to be an excellent catalyst for SO2 decomposition, thiophene hydrodesulfurization, O2 and H2 dissociation and the water gas shift reaction. Recent studies have shown that Au/TiC is a very good catalyst for the reverse water–gas shift (CO2 + H2 → CO + H2O) and CO2 hydrogenation to methanol. The present work further expands the range of applicability of this novel type of systems by exploring the catalytic activity of Au/TiC towards the hydrogenation ofmore » CO or CO2 with periodic density functional theory (DFT) calculations on model systems. Hydrogen dissociates easily on Au/TiC but direct hydrogenation of CO to methanol is hindered by very high activation barriers implying that, on this model catalyst, methanol production from CO2 involves the hydrogenation of a HOCO-like intermediate. Thus, when dealing with mixtures of syngas (CO/CO2/H2/H2O), CO could be transformed into CO2 through the water gas shift reaction with subsequent hydrogenation of CO2 to methanol.« less

  15. Project Profile: Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components

    Office of Energy Efficiency and Renewable Energy (EERE)

    GE, under the Physics of Reliability: Evaluating Design Insights for Component Technologies in Solar (PREDICTS) Program will be leveraging internally developed models to predict the reliability of hybrid gas bearing (HGB) and dry gas seal (DGS) components in the turboexpander of a supercritical CO2 turbine. The Bayesian model is to include phase changes, low cycle fatigue/high cycle fatigue, dynamic instabilities, and corrosion processes.

  16. Hybrid Membrane/Absorption Process for Post-combustion CO2 Capture

    SciTech Connect (OSTI)

    Li, Shiguang; Shou, S.; Pyrzynski, Travis; Makkuni, Ajay; Meyer, Howard

    2013-12-31

    This report summarizes scientific/technical progress made for bench-scale membrane contactor technology for post-combustion CO2 capture from DOE Contract No. DE-FE-0004787. Budget Period 1 (BP1) membrane absorber, Budget Period 2 (BP2) membrane desorber and Budget Period 3 (BP3) integrated system and field testing studies have been completed successfully and met or exceeded the technical targets (? 90% CO2 removal and CO2 purity of 97% in one membrane stage). Significant breakthroughs are summarized below: BP1 research: The feasibility of utilizing the poly (ether ether ketone), PEEK, based hollow fiber contractor (HFC) in combination with chemical solvents to separate and capture at least 90% of the CO2 from simulated flue gases has been successfully established. Excellent progress has been made as we have achieved the BP1 goal: ? 1,000 membrane intrinsic CO2 permeance, ? 90% CO2 removal in one stage, ? 2 psi gas side pressure drop, and ? 1 (sec)-1 mass transfer coefficient. Initial test results also show that the CO2 capture performance, using activated Methyl Diethanol Amine (aMDEA) solvent, was not affected by flue gas contaminants O2 (~3%), NO2 (66 ppmv), and SO2 (145 ppmv). BP2 research: The feasibility of utilizing the PEEK HFC for CO2-loaded solvent regeneration has been successfully established High CO2 stripping flux, one order of magnitude higher than CO2 absorption flux, have been achieved. Refined economic evaluation based on BP1 membrane absorber and BP2 membrane desorber laboratory test data indicate that the CO2 capture costs are 36% lower than DOEs benchmark amine absorption technology. BP3 research: A bench-scale system utilizing a membrane absorber and desorber was integrated into a continuous CO2 capture process using contactors containing 10 to 20 ft2 of membrane area. The integrated process operation was stable through a 100-hour laboratory test, utilizing a simulated flue gas stream. Greater than 90% CO2 capture combined with 97% CO2 product purity was achieved throughout the test. Membrane contactor modules have been scaled from bench scale 2-inch diameter by 12-inch long (20 ft2 membrane surface area) modules to 4-inch diameter by 60-inch long pilot scale modules (165 ft2 membrane surface area). Pilot scale modules were tested in an integrated absorption/regeneration system for CO2 capture field tests at a coal-fired power plant (Midwest Generations Will County Station located in Romeoville, IL). Absorption and regeneration contactors were constructed utilizing high performance super-hydrophobic, nano-porous PEEK membranes with CO2 gas permeance of 2,000 GPU and a 1,000 GPU, respectively. Field tests using aMDEA solvent achieved greater than 90% CO2 removal in a single stage. The absorption mass transfer coefficient was 1.2 (sec)-1, exceeding the initial target of 1.0 (sec)-1. This mass transfer coefficient is over one order of magnitude greater than that of conventional gas/liquid contacting equipment. The economic evaluation based on field tests data indicates that the CO2 capture cost associated with membrane contactor technology is $54.69 (Yr 2011$)/tonne of CO2 captured when using aMDEA as a solvent. It is projected that the DOEs 2025 cost goal of $40 (Yr 2011$)/tonne of CO2 captured can be met by decreasing membrane module cost and by utilizing advanced CO2 capture solvents. In the second stage of the field test, an advanced solvent, Hitachis H3-1 was utilized. The use of H3-1 solvent increased mass transfer coefficient by 17% as compared to aMDEA solvent. The high mass transfer coefficient of H3-1 solvent combined with much more favorable solvent regeneration requirements, indicate that the projected savings achievable with membrane contactor process can be further improved. H3-1 solvent will be used in the next pilot-scale development phase. The integrated absorption/regeneration process design and high performance membrane contactors developed in the current bench-scale program will be used as the base technology for future pilot-scale development.

  17. Ligand-Assisted Enhancement of CO2 Capture in Metal-Organic Frameworks |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Ligand-Assisted Enhancement of CO2 Capture in Metal-Organic Frameworks Previous Next List R. Poloni, B. Smit, and J. B. Neaton, J. Am. Chem. Soc. 134 (15), 6714 (2012) DOI: 10.1021/ja2118943 Abstract Image Abstract: Using density functional theory with a van der Waals-corrected functional, we elucidate how CO2 binds to a novel "BTT-type" metal-organic framework (MOF) featuring open metal centers. We

  18. CO2 Capture by Metal-Organic Frameworks with van der Waals Density

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionals | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome CO2 Capture by Metal-Organic Frameworks with van der Waals Density Functionals Previous Next List R. Poloni, B. Smit, and J. B. Neaton, J. Phys. Chem. A 116 (20), 4957 (2012) DOI: 10.1021/jp302190v Abstract Image Abstract We use density functional theory calculations with van der Waals corrections to study the role of dispersive interactions on the structure and binding of CO2 within two distinct

  19. Hindering effects in diffusion of CO2/CH4 mixtures in ZIF-8 crystals |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Hindering effects in diffusion of CO2/CH4 mixtures in ZIF-8 crystals Previous Next List C. Chmelik, J. van Baten, and R. Krishna, J. Membr. Sci. 397, 87 (2012) DOI: 10.1016/j.memsci.2012.01.013 Full-size image (22 K) Abstract Cage-type micro-porous materials such as LTA, CHA, SAPO-34, DDR, ERI, ZIF-7, and ZIF-8 have significant potential for use in membrane technologies for CO2 capture. The permeation

  20. Understanding CO2 Dynamics in Metal-Organic Frameworks wit Open Metal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sites | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome CO2 Dynamics in Metal-Organic Frameworks wit Open Metal Sites Previous Next List Li-Chiang Lin, Jihan Kim, Xueqian Kong, Eric Scott, Thomas M. McDonald, Jeffrey R. Long, Jeffrey A. Reimer, and Berend Smit, Angew. Chem. Int. Ed.,52, 4410-4413 (2013) DOI: 10.1002/anie.201300446 mcontent.gif Abstract: Metal-organic frameworks such as Mg-MOF-74 possess open metal sites that interact strongly with CO2.

  1. A comparison of the CO2 capture characteristics of zeolites and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    metal-organic frameworks | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome comparison of the CO2 capture characteristics of zeolites and metal-organic frameworks Previous Next List Rajamani Krishna, Jasper M. van Baten, Sep. Purif. Technol., 87, 120-126 (2012) DOI: 10.1016/j.seppur.2011.11.031 Full-size image (58 K) Abstract: Considerable progress has been made in recent years on the development of novel adsorbents for CO2 capture. Pressure swing adsorption

  2. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

  3. Modeling global atmospheric CO2 with improved emission inventories and CO2 production from the oxidation of other carbon species

    SciTech Connect (OSTI)

    Nassar, Ray; Jones, DBA; Suntharalingam, P; Chen, j.; Andres, Robert Joseph; Wecht, K. J.; Yantosca, R. M.; Kulawik, SS; Bowman, K; Worden, JR; Machida, T; Matsueda, H

    2010-01-01

    The use of global three-dimensional (3-D) models with satellite observations of CO2 in inverse modeling studies is an area of growing importance for understanding Earth s carbon cycle. Here we use the GEOS-Chem model (version 8-02-01) CO2 mode with multiple modifications in order to assess their impact on CO2 forward simulations. Modifications include CO2 surface emissions from shipping (0.19 PgC yr 1), 3-D spatially-distributed emissions from aviation (0.16 PgC yr 1), and 3-D chemical production of CO2 (1.05 PgC yr 1). Although CO2 chemical production from the oxidation of CO, CH4 and other carbon gases is recognized as an important contribution to global CO2, it is typically accounted for by conversion from its precursors at the surface rather than in the free troposphere. We base our model 3-D spatial distribution of CO2 chemical production on monthly-averaged loss rates of CO (a key precursor and intermediate in the oxidation of organic carbon) and apply an associated surface correction for inventories that have counted emissions of CO2 precursors as CO2. We also explore the benefit of assimilating satellite observations of CO into GEOS-Chem to obtain an observation-based estimate of the CO2 chemical source. The CO assimilation corrects for an underestimate of atmospheric CO abundances in the model, resulting in increases of as much as 24% in the chemical source during May June 2006, and increasing the global annual estimate of CO2 chemical production from 1.05 to 1.18 Pg C. Comparisons of model CO2 with measurements are carried out in order to investigate the spatial and temporal distributions that result when these new sources are added. Inclusion of CO2 emissions from shipping and aviation are shown to increase the global CO2 latitudinal gradient by just over 0.10 ppm (3%), while the inclusion of CO2 chemical production (and the surface correction) is shown to decrease the latitudinal gradient by about 0.40 ppm (10%) with a complex spatial structure generally resulting in decreased CO2 over land and increased CO2 over the oceans. Since these CO2 emissions are omitted or misrepresented in most inverse modeling work to date, their implementation in forward simulations should lead to improved inverse modeling estimates of terrestrial biospheric fluxes.

  4. Energy-transformation properties and mechanisms in transverse-flow-discharged CO2 lasers

    SciTech Connect (OSTI)

    Zhongxiang, W.

    1991-12-10

    We simulated, calculated, and analyzed the effects on the various energy state transformation properties of dielectric media of such factors as dielectric media gas pressures, flow speeds, light cavity position, strength of radiation in the cavity, degree of output coupling, and other similar factors in transverse flow discharged CO2 laser devices. This article did concrete calculations of the corresponding energy transformation properties for the apparatus and the conditions in reference (transverse flow, discharge, CO2 laser device, dielectric medium constituent ratio of CO2:N2:H = 5:17:78, an initial temperature of 293K, a discharge current of 2A, E/N: 2.15X10-16 V/cm2, light cavity 160 cm2 long, height 1.8cm, as well as other parameters).

  5. Capture and Sequestration of CO2 at the Boise White Paper Mill

    SciTech Connect (OSTI)

    B.P. McGrail; C.J. Freeman; G.H. Beeman; E.C. Sullivan; S.K. Wurstner; C.F. Brown; R.D. Garber; D. Tobin E.J. Steffensen; S. Reddy; J.P. Gilmartin

    2010-06-16

    This report documents the efforts taken to develop a preliminary design for the first commercial-scale CO2 capture and sequestration (CCS) project associated with biomass power integrated into a pulp and paper operation. The Boise Wallula paper mill is located near the township of Wallula in Southeastern Washington State. Infrastructure at the paper mill will be upgraded such that current steam needs and a significant portion of the current mill electric power are supplied from a 100% biomass power source. A new biomass power system will be constructed with an integrated amine-based CO2 capture plant to capture approximately 550,000 tons of CO2 per year for geologic sequestration. A customized version of Fluor Corporations Econamine Plus carbon capture technology will be designed to accommodate the specific chemical composition of exhaust gases from the biomass boiler. Due to the use of biomass for fuel, employing CCS technology represents a unique opportunity to generate a net negative carbon emissions footprint, which on an equivalent emissions reduction basis is 1.8X greater than from equivalent fossil fuel sources (SPATH and MANN, 2004). Furthermore, the proposed project will offset a significant amount of current natural gas use at the mill, equating to an additional 200,000 tons of avoided CO2 emissions. Hence, the total net emissions avoided through this project equates to 1,100,000 tons of CO2 per year. Successful execution of this project will provide a clear path forward for similar kinds of emissions reduction that can be replicated at other energy-intensive industrial facilities where the geology is suitable for sequestration. This project also represents a first opportunity for commercial development of geologic storage of CO2 in deep flood basalt formations. The Boise paper mill site is host to a Phase II pilot study being carried out under DOEs Regional Carbon Partnership Program. Lessons learned from this pilot study and other separately funded projects studying CO2 sequestration in basalts will be heavily leveraged in developing a suitable site characterization program and system design for permanent sequestration of captured CO2. The areal extent, very large thickness, high permeability in portions of the flows, and presence of multiple very low permeability flow interior seals combine to produce a robust sequestration target. Moreover, basalt formations are quite reactive with water-rich supercritical CO2 and formation water that contains dissolved CO2 to generate carbonate minerals, providing for long-term assurance of permanent sequestration. Sub-basalt sediments also exist at the site providing alternative or supplemental storage capacity.

  6. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    2010-07-15

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  7. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  8. North America's net terrestrial CO2 exchange with the atmosphere 1990–2009

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    King, Anthony W.; Andres, Robert; Davis, Kenneth J.; Hafer, M.; Hayes, Daniel J.; Huntzinger, Deborah N.; de Jong, Bernardus; Kurz, Werner; McGuire, A. David; Vargas, Rodrigo; et al

    2015-01-21

    Scientific understanding of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO2 emissions by managing terrestrial carbon uptake. Toward that understanding and as a contribution to the REgional Carbon Cycle Assessment and Processes (RECCAP) project, this paper provides a synthesis of net land–atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990–2009. Only CO2 is considered, not methane or other greenhouse gases. This synthesis is based on results from three different methods: atmospheric inversion, inventory-based methods and terrestrial biosphere modeling. All methods indicate that the North Americanmore » land surface was a sink for atmospheric CO2, with a net transfer from atmosphere to land. Estimates ranged from -890 to -280 Tg C yr-1, where the mean of atmospheric inversion estimates forms the lower bound of that range (a larger land sink) and the inventory-based estimate using the production approach the upper (a smaller land sink). This relatively large range is due in part to differences in how the approaches represent trade, fire and other disturbances and which ecosystems they include. Integrating across estimates, \\"best\\" estimates (i.e., measures of central tendency) are -472 ± 281 Tg C yr-1 based on the mean and standard deviation of the distribution and -360 Tg C yr-1 (with an interquartile range of -496 to -337) based on the median. Considering both the fossil fuel emissions source and the land sink, our analysis shows that North America was, however, a net contributor to the growth of CO2 in the atmosphere in the late 20th and early 21st century. With North America's mean annual fossil fuel CO2 emissions for the period 1990–2009 equal to 1720 Tg C yr-1 and assuming the estimate of -472 Tg C yr-1 as an approximation of the true terrestrial CO2 sink, the continent's source : sink ratio for this time period was 1720:472, or nearly 4:1.« less

  9. 10 MW Supercritical CO2 Turbine Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 MW Supercritical CO2 Turbine Project 10 MW Supercritical CO2 Turbine Project This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23-25, 2013 near Phoenix, Arizona. PDF icon csp_review_meeting_042313_turchi.pdf More Documents & Publications 10-Megawatt Supercritical Carbon Dioxide Turbine - FY13 Q2 10-MW Supercritical-CO2 Turbine Degradation Mechanisms and Development of Protective Coatings for TES and HTF Containment Materials

  10. Site Characterization of Promising Geologic Formations for CO2 Storage |

    Energy Savers [EERE]

    Department of Energy Site Characterization of Promising Geologic Formations for CO2 Storage Site Characterization of Promising Geologic Formations for CO2 Storage In September 2009, the U.S. Department of Energy announced the award of 11 projects with a total project value of $75.5 million* to conduct site characterization of promising geologic formations for CO2 storage. These Recovery Act projects will increase our understanding of the potential for these formations to safely and

  11. Researchers Uncover Copper's Potential for Reducing CO2 Emissions in

    Energy Savers [EERE]

    Chemical Looping | Department of Energy Researchers Uncover Copper's Potential for Reducing CO2 Emissions in Chemical Looping Researchers Uncover Copper's Potential for Reducing CO2 Emissions in Chemical Looping February 18, 2016 - 11:33am Addthis Researchers Uncover Copper’s Potential for Reducing CO2 Emissions in Chemical Looping Copper. It's been used in wires, pipes, and pennies for decades. Ancient Egyptians used it to sterilize wounds and clean drinking water. Today some hospitals

  12. Development of a Dry Sorbent-based Post-Combustion CO2 Capture Technology for Retrofit in Existing Power Plants

    SciTech Connect (OSTI)

    Nelson, Thomas; Coleman, Luke; Anderson, Matthew; Gupta, Raghubir; Herr, Joshua; Kalluri, Ranjeeth; Pavani, Maruthi

    2009-12-31

    The objective of this research and development (R&D) project was to further the development of a solid sorbent-based CO2 capture process based on sodium carbonate (i.e. the Dry Carbonate Process) that is capable of capturing>90% of the CO2 as a nearly pure stream from coal-fired power plant flue gas with <35% increase in the cost of electrictiy (ICOE).

  13. co2 capture meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2013 NETL CO2 Capture Technology Meeting July 8-11, 2013 Previous Proceedings 2012: NETL CO2 Capture Technology Meeting Proceedings of the 2013 NETL CO2 Capture Technology Meeting Table of Contents Presentations Monday, July 8 Opening/Overview Post-Combustion Sorbent-Based Capture Tuesday, July 9 Post-Combustion Solvent-Based Capture CO2 Compression Wednesday, July 10 Post-Combustion Membrane-Based Capture Pre-Combustion Capture Projects Thursday, July 11 ARPA-E Capture Projects System Studies

  14. CO2 Emissions from Fuel Combustion | Open Energy Information

    Open Energy Info (EERE)

    from international marine and aviation bunkers, and other relevant information" Excel Spreadsheet References "CO2 Emissions from Fuel Combustion" Retrieved from "http:...

  15. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolutionprecipitation reactions in the...

  16. High Co2 Emissions Through Porous Media- Transport Mechanisms...

    Open Energy Info (EERE)

    Co2 Emissions Through Porous Media- Transport Mechanisms And Implications For Flux Measurement And Fractionation Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  17. Pre-Combustion CO2 Control | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... pipeline, and injected into the Weyburn oilfield in Saskatchewan, Canada. NETL's pre-combustion CO2 control technology R&D includes internal and external research projects ...

  18. Hyperspectral Geobotanical Remote Sensing For Co2 Storage Monitoring...

    Open Energy Info (EERE)

    Hyperspectral Geobotanical Remote Sensing For Co2 Storage Monitoring Jump to: navigation, search OpenEI Reference LibraryAdd to library Book: Hyperspectral Geobotanical Remote...

  19. Tool for calculation of CO2 emissions from organisations | Open...

    Open Energy Info (EERE)

    lt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":"" Hide Map Language: English Tool for calculation of CO2 emissions from organisations Screenshot...

  20. Photosynthetic Conversion of CO2 to Fuels and Chemicals using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photosynthetic Conversion of CO 2 to Fuels and Chemicals using Cyanobacteria Accelerating Innovation Webinar August 8, 2012 Jianping Yu, Ph.D., Senior Scientist * Many eukaryotic ...

  1. Efficient Theoretical Screening of Solid Sorbents for CO2 Capture...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Efficient Theoretical Screening of Solid Sorbents for CO2 Capture Applications* Citation Details In-Document Search Title: Efficient Theoretical Screening of Solid...

  2. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Citation Details In-Document Search Title:...

  3. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow the adsorption and activation of CO2,...

  4. Regenerable Sorbent Technique for Capturing CO2 Using Immobilized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary This technology allows for optimal CO2 removal capacity for a given absorption and regeneration reactor size. Management of water loading in this manner allows...

  5. CO2 Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana

    SciTech Connect (OSTI)

    Frailey, Scott M.; Krapac, Ivan G.; Damico, James R.; Okwen, Roland T.; McKaskle, Ray W.

    2012-03-30

    The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO2) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO2 storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO2 flooding. As part of the MGSC???????¢????????????????s Validation Phase (Phase II) studies, the small injection pilot test was conducted at the Bald Unit site within the Mumford Hills Field in Posey County, southwestern Indiana, which was chosen for the project on the basis of site infrastructure and reservoir conditions. Geologic data on the target formation were extensive. Core analyses, porosity and permeability data, and geophysical logs from 40 wells were used to construct cross sections and structure contour and isopach maps in order to characterize and define the reservoir architecture of the target formation. A geocellular model of the reservoir was constructed to improve understanding of CO2 behavior in the subsurface. At the time of site selection, the Field was under secondary recovery through edge-water injection, but the wells selected for the pilot in the Bald Unit had been temporarily shut-in for several years. The most recently shut-in production well, which was surrounded by four nearby shut-in production wells in a five-spot pattern, was converted to CO2 injection for this pilot. Two additional wells outside the immediate five-spot pattern, one of which was an active producer, were instrumented to measure surface temperature and pressure. The CO2 injection period lasted from September 3, 2009, through December 14, 2010, with one three-month interruption caused by cessation of CO2 deliveries due to winter weather. Water was injected into the CO2 injection well during this period. A total of 6,300 tonnes (6,950 tons) of CO2 were injected into the reservoir at rates that generally ranged from 18 to 32 tonnes (20 to 35 tons) per day. The CO2 injection bottomhole pressure generally remained at 8.3 to 9.0 MPag (1,200 to 1,300 psig). The CO2 injection was followed by continued monitoring for nine months during post-CO2 water injection. A monitoring, verification, and accounting (MVA) program was designed to determine the fate of injected CO2. Extensive periodic sampling and analysis of brine, groundwater, and produced gases began before CO2 injection and continued through the monitored waterflood periods. Samples were gathered from production wells and three newly installed groundwater monitoring wells. Samples underwent geochemical and isotopic analyses to reveal any CO2-related changes. Groundwater and kinetic modeling and mineralogical analysis were also employed to better understand the long-term dynamics of CO2 in the reservoir. No CO2 leakage into groundwater was detected, and analysis of brine and gas chemistry made it possible to track the path of plume migration and infer geochemical reactions and trapping of CO2. Cased-hole logging did not detect any CO2 in the near-wellbore region. An increase in CO2 concentration was first detected in February 2010 from the gas present in the carboy during brine sampling; however, there was no appreciable gas volume associated with the detection of CO2. The first indication of elevated gas rates from the commingled gas of the pilot???????¢????????????????s production wells occurred in July 2010 and reached a maximum of 0.36 tonnes/day (0.41 tons/day) in September 2010. An estimated 27 tonnes (30 tons) of CO2 were produced at the surface from the gas separator at the tank battery from September 3, 2009, through September 11, 2011, representing 0.5% of the injected CO2. Consequently, 99.5% of the injected CO2 was stored at the Bald Unit Field after nine months of post-CO2 injection monitoring. Project improved oil recovery (IOR) was estimated at 412 m3 (2,590 bbl) and CO2 EOR as 325 m3 (2,045 bbl), although estimation of an EOR baseline was difficult because recovery was also increased by preproject well work. These figures would have been higher if not for variations in oil production rate due to winter weather. Oil production rates did not return to preshut-in level after the lengthy winter injection hiatuses, but remained elevated relative to production rates immediately before the pilot. The pilot was designed to measure and record data that could be used to calibrate a reservoir simulation model of the Clore sandstone to project the EOR potential of a larger-scale project at the Bald Unit. A model calibrated to field data (including geologic data and oil and water production) was used to assess the full-field EOR potential of the Field. Projections based on these models indicated that full-field CO2 injection for 20 years could have 12% oil recovery or 27,000 scm (170,000 stb) with a CO2 net utilization of 4,900 scm/scm (31,000 scf/stb). The potential CO2 storage is estimated to be 193,600 to 277,450 tonnes (213,000 to 305,200 tons).

  6. PASSIVE WIRELESS SURFACE ACOUSTIC WAVE SENSORS FOR MONITORING SEQUESTRATION SITES CO2 EMISSION

    SciTech Connect (OSTI)

    Wang, Yizhong; Chyu, Minking; Wang, Qing-Ming

    2012-11-30

    University of Pittsburgh’s Transducer lab has teamed with the U.S. Department of Energy’s National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient CO2 measuring technologies for geological sequestration sites leakage monitoring. A passive wireless CO2 sensing system based on surface acoustic wave technology and carbon nanotube nanocomposite was developed. Surface acoustic wave device was studied to determine the optimum parameters. Delay line structure was adopted as basic sensor structure. CNT polymer nanocomposite was fabricated and tested under different temperature and strain condition for natural environment impact evaluation. Nanocomposite resistance increased for 5 times under pure strain, while the temperature dependence of resistance for CNT solely was -1375ppm/℃. The overall effect of temperature on nanocomposite resistance was -1000ppm/℃. The gas response of the nanocomposite was about 10% resistance increase under pure CO2. The sensor frequency change was around 300ppm for pure CO2. With paralyne packaging, the sensor frequency change from relative humidity of 0% to 100% at room temperature decreased from over 1000ppm to less than 100ppm. The lowest detection limit of the sensor is 1% gas concentration, with 36ppm frequency change. Wireless module was tested and showed over one foot transmission distance at preferred parallel orientation.

  7. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

  8. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-04-20

    There is growing interest regarding the potential size of a future U.S. dedicated carbon dioxide (CO2) pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale within the United States. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies (so called WRE450 and WRE550 stabilization scenarios) and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The analysis reveals that between 11,000 and 23,000 additional miles of dedicated CO2 pipeline might be needed in the U.S. before 2050 across these two cases. While that is a significant increase over the 3,900 miles that comprise the existing national CO2 pipeline infrastructure, it is critically important to realize that the demand for additional CO2 pipeline capacity will unfold relatively slowly and in a geographically dispersed manner as new dedicated CCS-enabled power plants and industrial facilities are brought online. During the period 2010-2030, the growth in the CO2 pipeline system is on the order of a few hundred to less than a thousand miles per year. In comparison during the period 1950-2000, the U.S. natural gas pipeline distribution system grew at rates that far exceed these projections in growth in a future dedicated CO2 pipeline system. This analysis indicates that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a major obstacle for the commercial deployment of CCS technologies in the U.S. Nevertheless, there will undoubtedly be some associated regulatory and siting issues to work through but these issues should not be unmanageable based on the size of infrastructure requirements alone.

  9. Chemical Impact of Elevated CO2on Geothermal Energy Production

    Broader source: Energy.gov [DOE]

    This is a two phase project to assess the geochemical impact of CO2on geothermal energy production by: analyzing the geochemistry of existing geothermal fields with elevated natural CO2; measuring realistic rock-water rates for geothermal systems using laboratory and field-based experiments to simulate production scale impacts.

  10. ENHANCED PRACTICAL PHOTOSYNTHETIC CO2 MITIGATION

    SciTech Connect (OSTI)

    Dr. Gregory Kremer; Dr. David J. Bayless; Dr. Morgan Vis; Dr. Michael Prudich; Dr. Keith Cooksey; Dr. Jeff Muhs

    2002-01-15

    This quarterly report documents significant achievements in the Enhanced Practical Photosynthetic CO{sub 2} Mitigation project during the period from 10/3/2001 through 1/02/2002. Most of the achievements are milestones in our efforts to complete the tasks and subtasks that constitute the project objectives. Our research team has made significant progress towards completion of our Phase I objectives, and our current efforts remain focused on fulfilling these research objectives in accordance with the project timeline. Overall, we believe that we are on schedule to complete Phase I activities by 10/2002, which is the milestone date from the original project timeline. Specific results and accomplishments for the fourth quarter of 2001 include: (1) New procedures and protocols have been developed to increase the chances of successful implementation in the bioreactor of organisms that perform well in the lab. The new procedures include pre-screening of organisms for adhesion characteristics and a focus on identifying the organisms with maximum growth rate potential. (2) Preliminary results show an increase in adhesion to glass and a decrease in overall growth rates when using growth media prepared with tap water rather than distilled water. (3) Several of the organisms collected from Yellowstone National Park using the new procedures are currently being cultured in preparation for bioreactor tests. (4) One important result from a test of growth surface temperature distribution as a function of gas stream and drip-fluid temperatures showed a high dependence of membrane temperature on fluid temperature, with gas stream temperature having minimal effect. This result indicates that bioreactor growth surface temperatures can be controlled using fluid delivery temperature. The possible implications for implementation of the bioreactor concept are encouraging, since it may be possible to use the bioreactor with very high gas stream temperatures by controlling the temperature of the organisms with the fluid temperature. (5) Investigation of growth surface materials continues, with Omnisil and Scotch Brite emerging as the leading candidates. More investigation of these and other material types is still needed to determine the best material for particular combinations of organisms and harvesting methods. (6) Tests of harvesting methods and harvesting system designs have shown that desirable levels of ''percentage algae removal'' can be achieved for particular organisms and growth surface materials, for example Cyanidium on polyester felt. Additional testing continues to better characterize sensitivity of the ''percentage removal'' to various system design parameters, but these tests have been delayed due to the lack of suitable organisms for the tests. (7) The solar collectors and the pilot-scale bioreactor light distribution panels for the deep-penetration hybrid solar lighting system have been designed. One solar lighting system (solar collector tracking unit, fiber optic light transmission cables, light distribution panels) is almost completely prepared for installation during the next quarter in the pilot scale bioreactor system. (8) Pressure drop results from tests on the enhanced mass transfer CO{sub 2} absorption technique (the translating slug flow reactor) are encouraging, with reasonable values of 2.5 psi maximum over an 11.48 meter distance between pressure taps for test conditions of 0.6 m/sec slug velocity and approximately 10 m/sec gas velocity. Preparations are under way for CO{sub 2} scrubbing tests.

  11. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    1999-05-01

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  12. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration

    SciTech Connect (OSTI)

    Zuo, Lin; Benson, Sally M.

    2013-01-01

    A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

  13. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    so it is easier to transform it into something else. This requires exposing the CO2 to an energy source in combination with a catalyst such as pyridinium. Researchers have shown...

  14. Does elevated CO2 alter silica uptake in trees?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fulweiler, Robinson W.; Maguire, Timothy J.; Carey, Joanna C.; Finzi, Adrien C.

    2015-01-13

    Human activities have greatly altered global carbon (C) and Nitrogen (N) cycling. In fact, atmospheric concentrations of carbon dioxide (CO2) have increased 40% over the last century and the amount of N cycling in the biosphere has more than doubled. In an effort to understand how plants will respond to continued global CO2 fertilization, longterm free-air CO2 enrichment experiments have been conducted at sites around the globe. Here we examine how atmospheric CO2 enrichment and N fertilization affects the uptake of silicon (Si) in the Duke Forest, North Carolina, a stand dominated by Pinus taeda (loblolly pine), and five hardwoodmore » species. Specifically, we measured foliar biogenic silica concentrations in five deciduous and one coniferous species across three treatments: CO2 enrichment, N enrichment, and N and CO2 enrichment. We found no consistent trends in foliar Si concentration under elevated CO2, N fertilization, or combined elevated CO2 and N fertilization. However, two-thirds of the tree species studied here have Si foliar concentrations greater than well-known Si accumulators, such as grasses. Based on net primary production values and aboveground Si concentrations in these trees, we calculated forest Si uptake rates under control and elevated CO2 concentrations. Due largely to increased primary production, elevated CO2 enhanced the magnitude of Si uptake between 20 and 26%, likely intensifying the terrestrial silica pump. This uptake of Si by forests has important implications for Si export from terrestrial systems, with the potential to impact C sequestration and higher trophic levels in downstream ecosystems.« less

  15. Comparative soil CO2 flux measurements and geostatisticalestimation methods on masaya volcano, nicaragua

    SciTech Connect (OSTI)

    Lewicki, J.L.; Bergfeld, D.; Cardellini, C.; Chiodini, G.; Granieri, D.; Varley, N.; Werner, C.

    2004-04-27

    We present a comparative study of soil CO{sub 2} flux (F{sub CO2}) measured by five groups (Groups 1-5) at the IAVCEI-CCVG Eighth Workshop on Volcanic Gases on Masaya volcano, Nicaragua. Groups 1-5 measured F{sub CO2} using the accumulation chamber method at 5-m spacing within a 900 m{sup 2} grid during a morning (AM) period. These measurements were repeated by Groups 1-3 during an afternoon (PM) period. All measured F{sub CO2} ranged from 218 to 14,719 g m{sup -2}d{sup -1}. Arithmetic means and associated CO{sub 2} emission rate estimates for the AM data sets varied between groups by {+-}22%. The variability of the five measurements made at each grid point ranged from {+-}5 to 167% and increased with the arithmetic mean. Based on a comparison of measurements made by Groups 1-3 during AM and PM times, this variability is likely due in large part to natural temporal variability of gas flow, rather than to measurement error. We compared six geostatistical methods (arithmetic and minimum variance unbiased estimator means of uninterpolated data, and arithmetic means of data interpolated by the multiquadric radial basis function, ordinary kriging, multi-Gaussian kriging, and sequential Gaussian simulation methods) to estimate the mean and associated CO{sub 2} emission rate of one data set and to map the spatial F{sub CO2} distribution. While the CO{sub 2} emission rates estimated using the different techniques only varied by {+-}1.1%, the F{sub CO2} maps showed important differences. We suggest that the sequential Gaussian simulation method yields the most realistic representation of the spatial distribution of F{sub CO2} and is most appropriate for volcano monitoring applications.

  16. CO2 Sequestration short course (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical...

  17. Natural CO2 Analogs for Carbon Sequestration

    SciTech Connect (OSTI)

    Scott H. Stevens; B. Scott Tye

    2005-07-31

    The report summarizes research conducted at three naturally occurring geologic CO{sub 2} fields in the US. The fields are natural analogs useful for the design of engineered long-term storage of anthropogenic CO{sub 2} in geologic formations. Geologic, engineering, and operational databases were developed for McElmo Dome in Colorado; St. Johns Dome in Arizona and New Mexico; and Jackson Dome in Mississippi. The three study sites stored a total of 2.4 billion t (46 Tcf) of CO{sub 2} equivalent to 1.5 years of power plant emissions in the US and comparable in size with the largest proposed sequestration projects. The three CO{sub 2} fields offer a scientifically useful range of contrasting geologic settings (carbonate vs. sandstone reservoir; supercritical vs. free gas state; normally pressured vs. overpressured), as well as different stages of commercial development (mostly undeveloped to mature). The current study relied mainly on existing data provided by the CO{sub 2} field operator partners, augmented with new geochemical data. Additional study at these unique natural CO{sub 2} accumulations could further help guide the development of safe and cost-effective design and operation methods for engineered CO{sub 2} storage sites.

  18. Cooperative Insertion of CO2 in Diamine-Appended Metal-Organic Frameworks |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Insertion of CO2 in Diamine-Appended Metal-Organic Frameworks Previous Next List Thomas M. McDonald, Jarad A. Mason, Xueqian Kong, Eric D. Bloch, David Gygi, Alessandro Dani, Valentina Crocellà, Filippo Giordanino, Samuel O. Odoh, Walter S. Drisdell, Bess Vlaisavljevich, Allison L. Dzubak, Roberta Poloni, Sondre K. Schnell, Nora Planas, Kyuho Lee, Tod Pascal, Liwen F. Wan, David Prendergast, Jeffrey B. Neaton,

  19. Probing the Mechanism of CO2 Capture in Diamine-Appended Metal-Organic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frameworks using Measured and Simulated X-ray Spectroscopy | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Probing the Mechanism of CO2 Capture in Diamine-Appended Metal-Organic Frameworks using Measured and Simulated X-ray Spectroscopy Previous Next List Drisdell, Walter S.; Poloni, Robert; McDonald, Thomas M.; Pasal, Tod A.; Wan, Liwen F.; Pemmaraju, C. Das; Vlaisavljevich, Bess; Odoh, Samuel O.; Neaton, Jeffrey B.; Long, Jeffrey R.; Prendergast, David;

  20. CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents

    SciTech Connect (OSTI)

    2010-10-01

    IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.