National Library of Energy BETA

Sample records for granular zero-valent iron

  1. Performance of a Permeable Reactive Barrier Using Granular Zero-Valent

    Energy Savers [EERE]

    Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site | Department of Energy of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site PDF icon Performance of a

  2. Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008

    Broader source: Energy.gov [DOE]

    Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008

  3. Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable

    Energy Savers [EERE]

    Reactive Barrier, Monticello, Utah | Department of Energy Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah PDF icon Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah More

  4. Reduction of Aromatic Hydrocarbons by Zero-Valent Iron and Palladium Catalyst

    SciTech Connect (OSTI)

    Kim, Young-Hun; Shin, Won Sik; Ko, Seok-Oh; Kim, Myung-Chul

    2004-03-31

    Permeable reactive barrier (PRB) is an alternative technology for soil and groundwater remediation. Zero valent iron, which is the most popular PRB material, is only applicable to halogenated aliphatic organics and some heavy metals. The objective of this study was to investigate reductive dechlorination of halogenated compounds and reduction of non-halogenated aromatic hydrocarbons using zero valent metals (ZVMs) and catalysts as reactive materials for PRBs. A group of small aromatic hydrocarbons such as monochlorophenols, phenol and benzene were readily reduced with palladium catalyst and zero valent iron. Poly-aromatic hydrocarbons (PAHs) were also tested with the catalysts and zero valent metal combinations. The aromatic rings were reduced and partly reduced PAHs were found as the daughter compounds. The current study demonstrates reduction of aromatic compounds by ZVMs and modified catalysts and implicates that PRB is applicable not only for halogenated organic compounds but nonhalogenated aromatic compounds such as PAHs.

  5. Calcite precipitation dominates the electrical signatures of zero valent iron columns under simulated field conditions

    SciTech Connect (OSTI)

    Wu, Yuxin; Versteeg, R.; Slater, L.; LaBrecque, D.

    2009-06-01

    Calcium carbonate is a secondary mineral precipitate influencing zero valent iron (ZVI) barrier reactivity and hydraulic performance. We conducted column experiments to investigate electrical signatures resulting from concurrent CaCO{sub 3} and iron oxides precipitation under simulated field geochemical conditions. We identified CaCO{sub 3} as a major mineral phase throughout the columns, with magnetite present primarily close to the influent based on XRD analysis. Electrical measurements revealed decreases in conductivity and polarization of both columns, suggesting that electrically insulating CaCO{sub 3} dominates the electrical response despite the presence of electrically conductive iron oxides. SEM/EDX imaging suggests that the electrical signal reflects the geometrical arrangement of the mineral phases. CaCO{sub 3} forms insulating films on ZVI/magnetite surfaces, restricting charge transfer between the pore electrolyte and ZVI particles, as well as across interconnected ZVI particles. As surface reactivity also depends on the ability of the surface to engage in redox reactions via charge transfer, electrical measurements may provide a minimally invasive technology for monitoring reactivity loss due to CaCO{sub 3} precipitation. Comparison between laboratory and field data shows consistent changes in electrical signatures due to iron corrosion and secondary mineral precipitation.

  6. Foam-assisted delivery of nanoscale zero valent iron in porous media

    SciTech Connect (OSTI)

    Ding, Yuanzhao; Liu, Bo; Shen, Xin; Zhong, Lirong; Li, Xiqing

    2013-09-01

    Foam is potentially a promising vehicle to deliver nanoparticles for vadose zone remediation as foam can overcome the intrinsic problems associated with solution-based delivery, such as preferential flow and contaminant mobilization. In this work, the feasibility of using foam to deliver nanoscale zero valent iron (nZVI) in unsaturated porous media was investigated. Foams generated using surfactant sodium lauryl ether sulfate (SLES) showed excellent ability to carry nZVI. SLES and nZVI concentrations in the foaming solutions did not affect the percentages of nZVI concentrations in foams relative to nZVI concentrations in the solutions. When foams carrying nZVI were injected through the unsaturated columns, the fractions of nZVI exiting the column were much higher than those when nZVI was injected in liquid. The enhanced nZVI transport implies that foam delivery could significantly increase the radius of influence of injected nZVI. The type and concentrations of surfactants and the influent nZVI concentrations did not noticeably affect nZVI transport during foam delivery. In contrast, nZVI retention increased considerably as the grain size of porous media decreased. Oxidation of foam-delivered nZVI due to oxygen diffusion into unsaturated porous media was visually examined using a flow cell. It was demonstrated that if foams are injected to cover a deep vadose zone layer, oxidation would only cause a small fraction of foam-delivered nZVI to be oxidized before it reacts with contaminants.

  7. An Experimental Study of Micron-Size Zero-Valent Iron Emplacement in Permeable Porous Media Using Polymer-Enhanced Fluids

    SciTech Connect (OSTI)

    Oostrom, Mart; Wietsma, Thomas W.; Covert, Matthew A.; Vermeul, Vince R.

    2005-12-22

    At the Hanford Site, an extensive In Situ Redox Manipulation (ISRM) permeable reactive barrier was installed to prevent chromate from reaching the Columbia River. However, chromium has been detected in several wells, indicating a premature loss of the reductive capacity in the aquifer. One possible cause for premature chromate breakthrough is associated with the presence of high-permeability zones in the aquifer. In these zones, groundwater moves relatively fast and is able to oxidize iron more rapidly. There is also a possibility that the high-permeability flow paths are deficient in reducing equivalents (e.g. reactive iron), required for barrier performance. One way enhancement of the current barrier reductive capacity can be achieved is by the addition of micron-scale zero-valent iron to the high-permeability zones within the aquifer. The potential emplacement of zero-valent iron (Fe0) into high-permeability Hanford sediments (Ringold Unit E gravels) using shear-thinning fluids containing polymers was investigated in three-dimensional wedge-shaped aquifer models. Polymers were used to create a suspension viscous enough to keep the Fe0 in solution for extended time periods to improve colloid movement into the porous media without causing a permanent detrimental decrease in hydraulic conductivity. Porous media were packed in the wedge-shaped flow cell to create either a heterogeneous layered system with a high-permeability zone in between two low-permeability zones or a high-permeability channel surrounded by low-permeability materials. The injection flow rate, polymer type, polymer concentration, and injected pore volumes were determined based on preliminary short- and long-column experiments.

  8. Uranium(VI) reduction by nanoscale zero-valent iron in anoxic batch systems: The role of Fe(II) and Fe(III)

    SciTech Connect (OSTI)

    Yan, Sen; Chen, Yongheng; Xiang, Wu; Bao, Zhengyu; Liu, Chongxuan; Deng, Baolin

    2014-12-01

    The role of Fe(II) and Fe(III) on U(VI) reduction by nanoscale zerovalent iron (nanoFe0) was investigated using two iron chelators 1,10-phenanthroline and triethanolamine (TEA) under a CO2-free anoxic condition. The results showed U(VI) reduction was strongly inhibited by 1,10-phenanthroline and TEA in a pH range from 6.92 to 9.03. For instance, at pH 6.92 the observed U(VI) reduction rates decreased by 80.7% and 82.3% in the presence of 1,10-phenanthroline and TEA, respectively. The inhibition was attributed to the formation of stable complexes between 1,10-phenanthroline and Fe(II) or TEA and Fe(III). In the absence of iron chelators, U(VI) reduction can be enhanced by surface-bound Fe(II) on nanoFe0. Our results suggested that Fe(III) and Fe(II) probably acted as an electron shuttle to mediate the transfer of electrons from nanoFe0 to U(VI), therefore a combined system with Fe(II), Fe(III) and nanoFe0 can facilitate the U(VI) reductive immobilization in the contaminated groundwater.

  9. Perspectives from the Board's Technical Staff

    Office of Environmental Management (EM)

    Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site | Department of Energy of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site PDF icon Performance of a

  10. Iron optimization for Fenton-driven oxidation of MTBE-spent granular activated carbon

    SciTech Connect (OSTI)

    Scott G. Huling; Patrick K. Jones; Tony R. Lee

    2007-06-01

    Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) was accomplished through the addition of iron (Fe) and hydrogen peroxide (H{sub 2}O{sub 2}) (15.9 g/L; pH 3). The GAC used was URV, a bituminous-coal based carbon. The Fe concentration in GAC was incrementally varied (1020-25 660 mg/kg) by the addition of increasing concentrations of Fe solution (FeSO4{center_dot}7H{sub 2}O). MTBE degradation in Fe-amended GAC increased by an order of magnitude over Fe-unamended GAC and H{sub 2}O{sub 2} reaction was predominantly (99%) attributed to GAC-bound Fe within the porous structure of the GAC. Imaging and microanalysis of GAC particles indicated limited penetration of Fe into GAC. The optimal Fe concentration was 6710 mg/kg (1020 mg/kg background; 5690 mg/kg amended Fe) and resulted in the greatest MTBE removal and maximum Fe loading oxidation efficiency (MTBE oxidized (g)/Fe loaded to GAC(mg/Kg)). At lower Fe concentrations, the H{sub 2}O{sub 2} reaction was Fe limited. At higher Fe concentrations, the H{sub 2}O{sub 2} reaction was not entirely Fe limited, and reductions in GAC surface area, GAC pore volume, MTBE adsorption, and Fe loading oxidation efficiency were measured. Results are consistent with nonuniform distribution of Fe, pore blockage in H{sub 2}O{sub 2} transport, unavailable Fe, and limitations in H{sub 2}O{sub 2} diffusive transport, and emphasize the importance of optimal Fe loading. 22 refs., 6 figs., 2 tabs.

  11. CERCLA Sites Quality Assurance Project Plan | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CERCLA Sites Quality Assurance Project Plan CERCLA Sites Quality Assurance Project Plan CERCLA Sites Quality Assurance Project Plan PDF icon CERCLA Sites Quality Assurance Project Plan More Documents & Publications Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Closure Sites Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site

  12. Disposal Authorization Statement

    Office of Environmental Management (EM)

    November 2005 Through February 2008 | Department of Energy Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 PDF icon Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005

  13. Microsoft Word - S01394_PRB_ZVI.DOC

    Office of Legacy Management (LM)

    GJ719-2004 ESL-RPT-2004-06 Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site September 2004 Prepared by Environmental Sciences Laboratory U.S. Department of Energy Grand Junction, Colorado This page intentionally blank Signature Page Document Number S0139400 PRB Using Granular ZVI-2004 Annual Report U.S. Department of Energy Page iv September 2004 End of current text Document Number S0139400 Contents U.S.

  14. Dynamic granularity of imaging systems

    SciTech Connect (OSTI)

    Geissel, Matthias; Smith, Ian C.; Shores, Jonathon E.; Porter, John L.

    2015-11-04

    Imaging systems that include a specific source, imaging concept, geometry, and detector have unique properties such as signal-to-noise ratio, dynamic range, spatial resolution, distortions, and contrast. Some of these properties are inherently connected, particularly dynamic range and spatial resolution. It must be emphasized that spatial resolution is not a single number but must be seen in the context of dynamic range and consequently is better described by a function or distribution. We introduce the dynamic granularity Gdyn as a standardized, objective relation between a detectors spatial resolution (granularity) and dynamic range for complex imaging systems in a given environment rather than the widely found characterization of detectors such as cameras or films by themselves. We found that this relation can partly be explained through consideration of the signals photon statistics, background noise, and detector sensitivity, but a comprehensive description including some unpredictable data such as dust, damages, or an unknown spectral distribution will ultimately have to be based on measurements. Measured dynamic granularities can be objectively used to assess the limits of an imaging systems performance including all contributing noise sources and to qualify the influence of alternative components within an imaging system. Our article explains the construction criteria to formulate a dynamic granularity and compares measured dynamic granularities for different detectors used in the X-ray backlighting scheme employed at Sandias Z-Backlighter facility.

  15. Dynamic granularity of imaging systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Geissel, Matthias; Smith, Ian C.; Shores, Jonathon E.; Porter, John L.

    2015-11-04

    Imaging systems that include a specific source, imaging concept, geometry, and detector have unique properties such as signal-to-noise ratio, dynamic range, spatial resolution, distortions, and contrast. Some of these properties are inherently connected, particularly dynamic range and spatial resolution. It must be emphasized that spatial resolution is not a single number but must be seen in the context of dynamic range and consequently is better described by a function or distribution. We introduce the “dynamic granularity” Gdyn as a standardized, objective relation between a detector’s spatial resolution (granularity) and dynamic range for complex imaging systems in a given environment rathermore » than the widely found characterization of detectors such as cameras or films by themselves. We found that this relation can partly be explained through consideration of the signal’s photon statistics, background noise, and detector sensitivity, but a comprehensive description including some unpredictable data such as dust, damages, or an unknown spectral distribution will ultimately have to be based on measurements. Measured dynamic granularities can be objectively used to assess the limits of an imaging system’s performance including all contributing noise sources and to qualify the influence of alternative components within an imaging system. Our article explains the construction criteria to formulate a dynamic granularity and compares measured dynamic granularities for different detectors used in the X-ray backlighting scheme employed at Sandia’s Z-Backlighter facility.« less

  16. Field Projects: Cañon City, Colorado

    Broader source: Energy.gov [DOE]

    In June 2000, Cotter Corporation installed a PRB at its uranium ore processing millsite in Cañon City, Colorado. The PRB contains zero-valent iron (ZVI) that treated molybdenum and uranium...

  17. Field Projects: Monticello, Utah

    Broader source: Energy.gov [DOE]

    A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM managed remediation of...

  18. Impact compaction of a granular material

    SciTech Connect (OSTI)

    Fenton, Gregg; Asay, Blaine; Dalton, Devon

    2015-05-19

    The dynamic behavior of granular materials has importance to a variety of engineering applications. Structural seismic coupling, planetary science, and earth penetration mechanics, are just a few of the application areas. Although the mechanical behavior of granular materials of various types have been studied extensively for several decades, the dynamic behavior of such materials remains poorly understood. High-quality experimental data are needed to improve our general understanding of granular material compaction physics. This study will describe how an instrumented plunger impact system can be used to measure pressure-density relationships for model materials at high and controlled strain rates and subsequently used for computational modeling.

  19. Shear dispersion in dense granular flows

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Christov, Ivan C.; Stone, Howard A.

    2014-04-18

    We formulate and solve a model problem of dispersion of dense granular materials in rapid shear flow down an incline. The effective dispersivity of the depth-averaged concentration of the dispersing powder is shown to vary as the Péclet number squared, as in classical Taylor–Aris dispersion of molecular solutes. An extension to generic shear profiles is presented, and possible applications to industrial and geological granular flows are noted.

  20. Contact micromechanics in granular media with clay

    SciTech Connect (OSTI)

    Ita, S.L.

    1994-08-01

    Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

  1. Impact compaction of a granular material

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fenton, Gregg; Asay, Blaine; Dalton, Devon

    2015-05-19

    The dynamic behavior of granular materials has importance to a variety of engineering applications. Structural seismic coupling, planetary science, and earth penetration mechanics, are just a few of the application areas. Although the mechanical behavior of granular materials of various types have been studied extensively for several decades, the dynamic behavior of such materials remains poorly understood. High-quality experimental data are needed to improve our general understanding of granular material compaction physics. This study will describe how an instrumented plunger impact system can be used to measure pressure-density relationships for model materials at high and controlled strain rates and subsequentlymore » used for computational modeling.« less

  2. Studies of the regeneration of activated bauxite used as granular...

    Office of Scientific and Technical Information (OSTI)

    Studies of the regeneration of activated bauxite used as granular sorbent for the control ... bauxite used as granular sorbent for the control of alkali vapors from hot flue gas of ...

  3. Pressure-shear experiments on granular materials.

    SciTech Connect (OSTI)

    Reinhart, William Dodd; Thornhill, Tom Finley, III; Vogler, Tracy John; Alexander, C. Scott

    2011-10-01

    Pressure-shear experiments were performed on granular tungsten carbide and sand using a newly-refurbished slotted barrel gun. The sample is a thin layer of the granular material sandwiched between driver and anvil plates that remain elastic. Because of the obliquity, impact generates both a longitudinal wave, which compresses the sample, and a shear wave that probes the strength of the sample. Laser velocity interferometry is employed to measure the velocity history of the free surface of the anvil. Since the driver and anvil remain elastic, analysis of the results is, in principal, straightforward. Experiments were performed at pressures up to nearly 2 GPa using titanium plates and at higher pressure using zirconium plates. Those done with the titanium plates produced values of shear stress of 0.1-0.2 GPa, with the value increasing with pressure. On the other hand, those experiments conducted with zirconia anvils display results that may be related to slipping at an interface and shear stresses mostly at 0.1 GPa or less. Recovered samples display much greater particle fracture than is observed in planar loading, suggesting that shearing is a very effective mechanism for comminution of the grains.

  4. Frictional granular mechanics: A variational approach

    SciTech Connect (OSTI)

    Holtzman, R.; Silin, D.B.; Patzek, T.W.

    2009-10-16

    The mechanical properties of a cohesionless granular material are evaluated from grain-scale simulations. Intergranular interactions, including friction and sliding, are modeled by a set of contact rules based on the theories of Hertz, Mindlin, and Deresiewicz. A computer generated, three-dimensional, irregular pack of spherical grains is loaded by incremental displacement of its boundaries. Deformation is described by a sequence of static equilibrium configurations of the pack. A variational approach is employed to find the equilibrium configurations by minimizing the total work against the intergranular loads. Effective elastic moduli are evaluated from the intergranular forces and the deformation of the pack. Good agreement between the computed and measured moduli, achieved with no adjustment of material parameters, establishes the physical soundness of the proposed model.

  5. Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics

    Broader source: Energy.gov [DOE]

    The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics.

  6. Continuum modeling of diffusion and dispersion in dense granular flows

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Continuum modeling of diffusion and dispersion in dense granular flows Citation Details In-Document Search Title: Continuum modeling of diffusion and dispersion in dense granular flows Authors: Christov, Ivan C [1] ; Stone, Howard A [2] + Show Author Affiliations Los Alamos National Laboratory [Los Alamos National Laboratory Mechanical & Aerospace Engineering, Princeton University [Mechanical & Aerospace Engineering, Princeton University Publication

  7. Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135

    SciTech Connect (OSTI)

    Michalski, Casey C.; DiSalvo, Rick; Boylan, John

    2013-07-01

    DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

  8. Dispersion enhanced metal/zeolite catalysts

    DOE Patents [OSTI]

    Sachtler, W.M.H.; Tzou, M.S.; Jiang, H.J.

    1987-03-31

    Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

  9. Dispersion enhanced metal/zeolite catalysts

    DOE Patents [OSTI]

    Sachtler, Wolfgang M. H.; Tzou, Ming-Shin; Jiang, Hui-Jong

    1987-01-01

    Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

  10. Comparison of Mesomechanical and Continuum Granular Flow Models for Ceramics

    SciTech Connect (OSTI)

    Curran, D. R.

    2006-07-28

    Constitutive models for the shear strength of ceramics undergoing fracture are needed for modeling long rod and shaped-charge jet penetration events in ceramic armor. The ceramic material ahead of the penetrator has been observed to be finely comminuted material that flows around the nose of the eroding penetrator (Shockey et al.). The most-used continuum models are of the Drucker-Prager type with an upper cutoff, or of the Mohr-Coulomb type with strain rate dependence and strain softening. A disadvantage of such models is that they have an unclear connection to the actual microscopic processes of granular flow and comminution. An alternate approach is to use mesomechanical models that describe the dynamics of the granular flow, as well as containing a description of the granular comminution and resultant material softening. However, a disadvantage of the mesomechanical models is that they are computationally more burdensome to apply. In the present paper, we compare the behaviors of a mesomechanical model, FRAGBED2, with the Walker and Johnson-Holmquist continuum models, where the granular material is subjected to simple strain histories under various confining pressures and strain rates. We conclude that the mesomechanical model can provide valuable input to the continuum models, both in interpretation of the continuum models' parameters and in suggesting their range of applicability.

  11. Sealing of boreholes using natural, compatible materials: Granular salt

    SciTech Connect (OSTI)

    Finley, R.E.; Zeuch, D.H.; Stormont, J.C.; Daemen, J.J.K.

    1994-05-01

    Granular salt can be used to construct high performance permanent seals in boreholes which penetrate rock salt formations. These seals are described as seal systems comprised of the host rock, the seal material, and the seal rock interface. The performance of these seal systems is defined by the complex interactions between these seal system components through time. The interactions are largely driven by the creep of the host formation applying boundary stress on the seal forcing host rock permeability with time. The immediate permeability of these seals is dependent on the emplaced density. Laboratory test results suggest that careful emplacement techniques could results in immediate seal system permeability on the order of 10{sup {minus}16} m{sup 2} to 10{sup {minus}18} m{sup 2} (10{sup {minus}4} darcy to 10{sup {minus}6}). The visco-plastic behavior of the host rock coupled with the granular salts ability to ``heal`` or consolidate make granular salt an ideal sealing material for boreholes whose permanent sealing is required.

  12. Shear dispersion in dense granular flows (Journal Article) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Shear dispersion in dense granular flows Citation Details In-Document Search Title: Shear dispersion in dense granular flows We formulate and solve a model problem of dispersion of dense granular materials in rapid shear flow down an incline. The effective dispersivity of the depth-averaged concentration of the dispersing powder is shown to vary as the Péclet number squared, as in classical Taylor-Aris dispersion of molecular solutes. An extension to generic shear profiles is

  13. Method and means for continuous precipitation of easy-dry, granular uranium peroxide

    DOE Patents [OSTI]

    Cahill, Allen E. (Roland, IA); Burkhart, deceased, Lawrence E. (late of Ames, IA)

    1992-02-28

    A method and means for continuous precipitation of granular uranium peroxide. The reaction vessel and agitation method practiced in it avoid filter plugging and caking problems.

  14. Electrical and thermal transport properties of iron and iron...

    Office of Scientific and Technical Information (OSTI)

    Electrical and thermal transport properties of iron and iron-silicon alloy at high pressure Citation Details In-Document Search Title: Electrical and thermal transport properties ...

  15. Modeling granular phosphor screens by Monte Carlo methods

    SciTech Connect (OSTI)

    Liaparinos, Panagiotis F.; Kandarakis, Ioannis S.; Cavouras, Dionisis A.; Delis, Harry B.; Panayiotakis, George S.

    2006-12-15

    The intrinsic phosphor properties are of significant importance for the performance of phosphor screens used in medical imaging systems. In previous analytical-theoretical and Monte Carlo studies on granular phosphor materials, values of optical properties, and light interaction cross sections were found by fitting to experimental data. These values were then employed for the assessment of phosphor screen imaging performance. However, it was found that, depending on the experimental technique and fitting methodology, the optical parameters of a specific phosphor material varied within a wide range of values, i.e., variations of light scattering with respect to light absorption coefficients were often observed for the same phosphor material. In this study, x-ray and light transport within granular phosphor materials was studied by developing a computational model using Monte Carlo methods. The model was based on the intrinsic physical characteristics of the phosphor. Input values required to feed the model can be easily obtained from tabulated data. The complex refractive index was introduced and microscopic probabilities for light interactions were produced, using Mie scattering theory. Model validation was carried out by comparing model results on x-ray and light parameters (x-ray absorption, statistical fluctuations in the x-ray to light conversion process, number of emitted light photons, output light spatial distribution) with previous published experimental data on Gd{sub 2}O{sub 2}S:Tb phosphor material (Kodak Min-R screen). Results showed the dependence of the modulation transfer function (MTF) on phosphor grain size and material packing density. It was predicted that granular Gd{sub 2}O{sub 2}S:Tb screens of high packing density and small grain size may exhibit considerably better resolution and light emission properties than the conventional Gd{sub 2}O{sub 2}S:Tb screens, under similar conditions (x-ray incident energy, screen thickness)

  16. Granular Lithium Injector --- Inventor(s) Lane Roquemore and Dennis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mansfield | Princeton Plasma Physics Lab Granular Lithium Injector --- Inventor(s) Lane Roquemore and Dennis Mansfield This invention utilizes a rotating impeller operating at up to 15000 rpm to inject spherical particles into the pedastal of a tokamak plasma. It was designed specifically to inject Li granules with diameters up to 1mm. The particles are fed to the injector via a piezo-based dropper disclosed in a previous Invention Disclosure. The design goal is to use the injector to induce

  17. Thin Wall Iron Castings

    SciTech Connect (OSTI)

    J.F. Cuttino; D.M. Stefanescu; T.S. Piwonka

    2001-10-31

    Results of an investigation made to develop methods of making iron castings having wall thicknesses as small as 2.5 mm in green sand molds are presented. It was found that thin wall ductile and compacted graphite iron castings can be made and have properties consistent with heavier castings. Green sand molding variables that affect casting dimensions were also identified.

  18. Pulsed Gradient Spin Echo Nuclear Magnetic Resonance Imaging of Diffusion in Granular Flow

    SciTech Connect (OSTI)

    Seymour, Joseph D.; Caprihan, Arvind; Altobelli, Stephen A.; Fukushima, Eiichi

    2000-01-10

    We derive the formalism to obtain spatial distributions of collisional correlation times for macroscopic particles undergoing granular flow from pulsed gradient spin echo nuclear magnetic resonance diffusion data. This is demonstrated with an example of axial motion in the shear flow regime of a 3D granular flow in a horizontal rotating cylinder at one rotation rate. (c) 2000 The American Physical Society.

  19. Superdiffusive transport and energy localization in disordered granular crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martinez, Alejandro J.; Kevrekidis, Panagiotis G.; Porter, Mason A.

    2016-02-12

    We study the spreading of initially localized excitations in one-dimensional disordered granular crystals. We thereby investigate localization phenomena in strongly nonlinear systems, which we demonstrate to be fundamentally different from localization in linear and weakly nonlinear systems. We conduct a thorough comparison of wave dynamics in chains with three different types of disorder: an uncorrelated (Anderson-like) disorder and two types of correlated disorders (which are produced by random dimer arrangements), and for two families of initial conditions: displacement perturbations and velocity perturbations. We find for strongly precompressed (i.e., weakly nonlinear) chains that the dynamics strongly depends on the initial condition.more » Furthermore, for displacement perturbations, the long-time asymptotic behavior of the second moment m~2 has oscillations that depend on the type of disorder, with a complex trend that is markedly different from a power law and which is particularly evident for an Anderson-like disorder.« less

  20. Magnetic properties of granular CoCrPt:SiO{sub 2} films as tailored by

    Office of Scientific and Technical Information (OSTI)

    Co{sup +} irradiation (Journal Article) | SciTech Connect Magnetic properties of granular CoCrPt:SiO{sub 2} films as tailored by Co{sup +} irradiation Citation Details In-Document Search Title: Magnetic properties of granular CoCrPt:SiO{sub 2} films as tailored by Co{sup +} irradiation We report on an approach to tailor the magnetic exchange in a conventional granular CoCrPt:SiO{sub 2} recording medium by irradiation with Co{sup +} ions. Irradiation at low fluences enhances the intergranular

  1. Analysis of MSE Cores Tuba City, Arizona, Site | Department of Energy

    Energy Savers [EERE]

    MSE Cores Tuba City, Arizona, Site Analysis of MSE Cores Tuba City, Arizona, Site Analysis of MSE Cores Tuba City, Arizona, Site PDF icon Analysis of MSE Cores Tuba City, Arizona, Site More Documents & Publications Analysis of Contaminant Rebound in Ground Water in Extraction Wells at the Tuba City, Arizona, Site Diffusion Multilayer Sampling of Ground Water in Five Wells at the Tuba City, Arizona, Site Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier,

  2. Alumni | Savannah River Ecology Laboratory REU in Radioecology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Class of 2015 2015 ALUMNI Abstract | Shaina Carrington - Presence of ranavirus and chytrid fungus in Lithobates sphenocephalus in long and short hydroperiod wetlands Abstract | Jarad Cochran - Influence of coal ash contamination on metabolic rates of eastern mud turtles Abstract | Emily Dorward - Zero valent iron as a filter for water contaminated with uranium and nitrate Abstract | Naya Eady - Influence of coal ash exposure on eastern mud turtle immune response Abstract | Nathaniel Fox -

  3. Traveling waves and their tails in locally resonant granular systems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, H.; Kevrekidis, P. G.; Stefanov, A.

    2015-04-22

    In the present study, we revisit the theme of wave propagation in locally resonant granular crystal systems, also referred to as mass-in-mass systems. We use three distinct approaches to identify relevant traveling waves. In addition, the first consists of a direct solution of the traveling wave problem. The second one consists of the solution of the Fourier tranformed variant of the problem, or, more precisely, of its convolution reformulation (upon an inverse Fourier transform) in real space. Finally, our third approach will restrict considerations to a finite domain, utilizing the notion of Fourier series for important technical reasons, namely themore » avoidance of resonances, which will be discussed in detail. All three approaches can be utilized in either the displacement or the strain formulation. Typical resulting computations in finite domains result in the solitary waves bearing symmetric non-vanishing tails at both ends of the computational domain. Importantly, however, a countably infinite set of anti-resonance conditions is identified for which solutions with genuinely rapidly decaying tails arise.« less

  4. GRANULAR-SCALE MAGNETIC FLUX CANCELLATIONS IN THE PHOTOSPHERE

    SciTech Connect (OSTI)

    Kubo, M.; Low, B. C.; Lites, B. W.

    2010-04-01

    We investigate the evolution of five granular-scale magnetic flux cancellations just outside the moat region of a sunspot by using accurate spectropolarimetric measurements and G-band images with the Solar Optical Telescope (SOT) aboard Hinode. The opposite-polarity magnetic elements approach a junction of the intergranular lanes and then collide with each other there. The intergranular junction has strong redshifts, darker intensities than the regular intergranular lanes, and surface converging flows. This clearly confirms that the converging and downward convective motions are essential for the approaching process of the opposite-polarity magnetic elements. However, the motion of the approaching magnetic elements does not always match with their surrounding surface flow patterns in our observations. This suggests that, in addition to the surface flows, subsurface downward convective motions and subsurface magnetic connectivities are important for understanding the approach and collision of the opposite-polarity elements observed in the photosphere. We find that the horizontal magnetic field appears between the canceling opposite-polarity elements in only one event. The horizontal fields are observed along the intergranular lanes with Doppler redshifts. This cancellation is most probably a result of the submergence (retraction) of low-lying photospheric magnetic flux. In the other four events, the horizontal field is not observed between the opposite-polarity elements at any time when they approach and cancel each other. These approaching magnetic elements are more concentrated rather than gradually diffused, and they have nearly vertical fields even while they are in contact each other. We thus infer that the actual flux cancellations are highly time-dependent events at scales less than a pixel of Hinode SOT (about 200 km) near the solar surface.

  5. Critical Phenomena in Driven Granular Matter: Jamming and Glassy Behavior - Final Report

    SciTech Connect (OSTI)

    Teitel, Stephen

    2013-02-20

    Granular materials, such as powders, seeds, grains, sand, rocks, etc., are ubiquitous both in nature and in industrial processes. At the scale of individual grains, granular systems are particularly simple: particles interact only when they touch. But when viewed in the aggregate, granular systems can display complex behavior. In particular, as the volume packing fraction of the grains increases, the system undergoes a jamming transition from a flowing liquid to a disordered but rigid solid. We study the critical behavior of such systems near the jamming transition using numerical simulations of a simple model of soft-core, bidisperse, frictionless disks in two dimensions. We seek to understand the structural and transport properties of such systems under a variety of physical perturbations such as steady state shear driven flow, and finite thermal fluctuations.

  6. Microbial reduction of iron ore

    DOE Patents [OSTI]

    Hoffmann, M.R.; Arnold, R.G.; Stephanopoulos, G.

    1989-11-14

    A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry. 11 figs.

  7. Microbial reduction of iron ore

    DOE Patents [OSTI]

    Hoffmann, Michael R.; Arnold, Robert G.; Stephanopoulos, Gregory

    1989-01-01

    A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry.

  8. Low-field diamagnetic response of granular superconductors at finite temperatures

    SciTech Connect (OSTI)

    Auletta, C.; Raiconi, G. ); De Luca, R.; Pace, S. )

    1994-05-01

    We study the low-field diamagnetic response of granular superconductors at finite temperatures by means of a simple two-dimensional Josephson-junction array. The temperature effects are taken into account by inserting white-noise current sources in parallel to the resistively shunted junction circuit models of the Josephson junctions of the network. By this analysis we argue that a simplified one-dimensional description of the equivalent circuit, proposed by the authors for cylindrical granular superconductors, is still valid even in the presence of thermally activated flux jumps. A flux-creep picture for intergranular flux motion follows.

  9. Active hopper for promoting flow of bulk granular or powdered solids

    Office of Scientific and Technical Information (OSTI)

    (Patent) | DOEPatents Data Explorer Search Results Active hopper for promoting flow of bulk granular or powdered solids Title: Active hopper for promoting flow of bulk granular or powdered solids An apparatus that promotes the flow of materials has a body having an inner shape for holding the materials, a wall having a shape that approximates a portion of the inner shape of the body, and a vibrator attached to the wall. The wall may be disposed vertically within the body close to the body's

  10. Iron and Steel (2010 MECS)

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

  11. Method for reducing iron losses in an iron smelting process

    DOE Patents [OSTI]

    Sarma, Balu; Downing, Kenneth B.

    1999-01-01

    A process of smelting iron that comprises the steps of: a) introducing a source of iron oxide, oxygen, nitrogen, and a source of carbonaceous fuel to a smelting reactor, at least some of said oxygen being continuously introduced through an overhead lance; b) maintaining conditions in said reactor to cause (i) at least some of the iron oxide to be chemically reduced, (ii) a bath of molten iron to be created and stirred in the bottom of the reactor, surmounted by a layer of slag, and (iii) carbon monoxide gas to rise through the slag; c) causing at least some of said carbon monoxide to react in the reactor with the incoming oxygen, thereby generating heat for reactions taking place in the reactor; and d) releasing from the reactor an offgas effluent, is run in a way that keeps iron losses in the offgas relatively low. After start-up of the process is complete, steps (a) and (b) are controlled so as to: e) keep the temperature of the molten iron at or below about 1550.degree. C. and f) keep the slag weight at or above about 0.8 tonne per square meter.

  12. Method for reducing iron losses in an iron smelting process

    DOE Patents [OSTI]

    Sarma, B.; Downing, K.B.

    1999-03-23

    A process of smelting iron that comprises the steps of: (a) introducing a source of iron oxide, oxygen, nitrogen, and a source of carbonaceous fuel to a smelting reactor, at least some of said oxygen being continuously introduced through an overhead lance; (b) maintaining conditions in said reactor to cause (1) at least some of the iron oxide to be chemically reduced, (2) a bath of molten iron to be created and stirred in the bottom of the reactor, surmounted by a layer of slag, and (3) carbon monoxide gas to rise through the slag; (c) causing at least some of said carbon monoxide to react in the reactor with the incoming oxygen, thereby generating heat for reactions taking place in the reactor; and (d) releasing from the reactor an offgas effluent, is run in a way that keeps iron losses in the offgas relatively low. After start-up of the process is complete, steps (a) and (b) are controlled so as to: (1) keep the temperature of the molten iron at or below about 1550 C and (2) keep the slag weight at or above about 0.8 ton per square meter. 13 figs.

  13. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar; Givens, Edwin N.

    1983-01-01

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  14. Process for the synthesis of iron powder

    DOE Patents [OSTI]

    Welbon, W.W.

    1983-11-08

    A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder. 2 figs.

  15. Process for the synthesis of iron powder

    DOE Patents [OSTI]

    Welbon, William W.

    1983-01-01

    A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

  16. Process for the synthesis of iron powder

    DOE Patents [OSTI]

    Not Available

    1982-03-06

    A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

  17. Mechanical properties of granular materials: A variational approach to grain-scale simulations

    SciTech Connect (OSTI)

    Holtzman, R.; Silin, D.B.; Patzek, T.W.

    2009-01-15

    The mechanical properties of cohesionless granular materials are evaluated from grain-scale simulations. A three-dimensional pack of spherical grains is loaded by incremental displacements of its boundaries. The deformation is described as a sequence of equilibrium configurations. Each configuration is characterized by a minimum of the total potential energy. This minimum is computed using a modification of the conjugate gradient algorithm. Our simulations capture the nonlinear, path-dependent behavior of granular materials observed in experiments. Micromechanical analysis provides valuable insight into phenomena such as hysteresis, strain hardening and stress-induced anisotropy. Estimates of the effective bulk modulus, obtained with no adjustment of material parameters, are in agreement with published experimental data. The model is applied to evaluate the effects of hydrate dissociation in marine sediments. Weakening of the sediment is quantified as a reduction in the effective elastic moduli.

  18. DETECTION OF SMALL-SCALE GRANULAR STRUCTURES IN THE QUIET SUN WITH THE NEW SOLAR TELESCOPE

    SciTech Connect (OSTI)

    Abramenko, V. I.; Yurchyshyn, V. B.; Goode, P. R.; Kitiashvili, I. N.; Kosovichev, A. G.

    2012-09-10

    Results of a statistical analysis of solar granulation are presented. A data set of 36 images of a quiet-Sun area on the solar disk center was used. The data were obtained with the 1.6 m clear aperture New Solar Telescope at Big Bear Solar Observatory and with a broadband filter centered at the TiO (705.7 nm) spectral line. The very high spatial resolution of the data (diffraction limit of 77 km and pixel scale of 0.''0375) augmented by the very high image contrast (15.5% {+-} 0.6%) allowed us to detect for the first time a distinct subpopulation of mini-granular structures. These structures are dominant on spatial scales below 600 km. Their size is distributed as a power law with an index of -1.8 (which is close to the Kolmogorov's -5/3 law) and no predominant scale. The regular granules display a Gaussian (normal) size distribution with a mean diameter of 1050 km. Mini-granular structures contribute significantly to the total granular area. They are predominantly confined to the wide dark lanes between regular granules and often form chains and clusters, but different from magnetic bright points. A multi-fractality test reveals that the structures smaller than 600 km represent a multi-fractal, whereas on larger scales the granulation pattern shows no multi-fractality and can be considered as a Gaussian random field. The origin, properties, and role of the population of mini-granular structures in the solar magnetoconvection are yet to be explored.

  19. Steelmaking with iron carbide

    SciTech Connect (OSTI)

    Geiger, G.H.; Stephens, F.A. )

    1993-01-01

    The concept of using iron carbide in steelmaking is not new. Tests were run several decades ago, using carbide made from ore, in steelmaking furnaces. The problem was that at that time, the need for the product was not clear and the economics of production were not favorable. In the early 1970's Frank M. Stephens, Jr., conceived the basis for the present process, and considerable development work has been done during the past decade to bring the carbide production process to its present state, with the first commercial unit now under construction. The process utilizes the following overall reaction to produce Fe[sub 3]C from ore: 3Fe[sub 2]O[sub 3] + 5H[sub 2] + 2 CH[sub 4][equals]2 Fe[sub 3]C + 9 H[sub 2]O. Hydrogen gas from a natural gas reformer is blended with natural gas to form the process gas that is recirculated through the fluid bed reactor, the cooling tower, to remove reaction product water, and back through the reactor again, after reheating. The closed loop nature of the process means that virtually 100% of the process reagents are utilized by the process. The only exception is that a small stream of the process gas is burned as fuel in the reheating step, in order to maintain the level of inerts in the process gas at an acceptable level. The quantity of the bleed stream is entirely dependent on the concentration of inert gases in the fuel supply.

  20. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant...

  1. Kumba Iron Ore | Open Energy Information

    Open Energy Info (EERE)

    can help OpenEI by expanding it. Kumba Iron Ore is a company located in Pretoria, South Africa . References "Kumba Iron Ore" Retrieved from "http:en.openei.orgw...

  2. Iron Edison Battery Company | Open Energy Information

    Open Energy Info (EERE)

    is a company based in Lakewood, Colorado. Iron Edison is redefining off-grid energy storage using advanced Nickel-iron (Ni-Fe) battery technology. Vastly out-lasting the 7...

  3. Moving granular-bed filter development program, Option III: Development of moving granular-bed filter technology for multi-contaminant control. Task 14: Test plan; Topical report

    SciTech Connect (OSTI)

    Haas, J.C.; Olivo, C.A.; Wilson, K.B.

    1994-04-01

    An experimental test plan has been prepared for DOE/METC review and approval to develop a filter media suitable for multi-contaminant control in granular-bed filter (GBF) applications. The plan includes identification, development, and demonstration of methods for enhanced media morphology, chemical reactivity, and mechanical strength. The test plan includes media preparation methods, physical and chemical characterization methods for fresh and reacted media, media evaluation criteria, details of test and analytical equipment, and test matrix of the proposed media testing. A filter media composed of agglomerated limestone and clay was determined to be the best candidate for multi-contaminate control in GBF operation. The combined limestone/clay agglomerate has the potential to remove sulfur and alkali species, in addition to particulate, and possibly halogens and trace heavy metals from coal process streams.

  4. Ligand iron catalysts for selective hydrogenation

    DOE Patents [OSTI]

    Casey, Charles P.; Guan, Hairong

    2010-11-16

    Disclosed are iron ligand catalysts for selective hydrogenation of aldehydes, ketones and imines. A catalyst such as dicarbonyl iron hydride hydroxycyclopentadiene) complex uses the OH on the five member ring and hydrogen linked to the iron to facilitate hydrogenation reactions, particularly in the presence of hydrogen gas.

  5. Implementation and Re nement of a Comprehensive Model for Dense Granular Flows

    SciTech Connect (OSTI)

    Sundaresan, Sankaran

    2015-09-30

    Dense granular ows are ubiquitous in both natural and industrial processes. They manifest three di erent ow regimes, each exhibiting its own dependence on solids volume fraction, shear rate, and particle-level properties. This research project sought to develop continuum rheological models for dense granular ows that bridges multiple regimes of ow, implement them in open-source platforms for gas-particle ows and perform test simulations. The rst phase of the research covered in this project involved implementation of a steady- shear rheological model that bridges quasi-static, intermediate and inertial regimes of ow into MFIX (Multiphase Flow with Interphase eXchanges - a general purpose computer code developed at the National Energy Technology Laboratory). MFIX simulations of dense granular ows in hourglass-shaped hopper were then performed as test examples. The second phase focused on formulation of a modi ed kinetic theory for frictional particles that can be used over a wider range of particle volume fractions and also apply for dynamic, multi- dimensional ow conditions. To guide this work, simulations of simple shear ows of identical mono-disperse spheres were also performed using the discrete element method. The third phase of this project sought to develop and implement a more rigorous treatment of boundary e ects. Towards this end, simulations of simple shear ows of identical mono-disperse spheres con ned between parallel plates were performed and analyzed to formulate compact wall boundary conditions that can be used for dense frictional ows at at frictional boundaries. The fourth phase explored the role of modest levels of cohesive interactions between particles on the dense phase rheology. The nal phase of this project focused on implementation and testing of the modi ed kinetic theory in MFIX and running bin-discharge simulations as test examples.

  6. Continuous production of granular or powder Ti, Zr and Hf or their alloy products

    DOE Patents [OSTI]

    White, Jack C.; Oden, Laurance L.

    1993-01-01

    A continuous process for producing a granular metal selected from the group consisting of Ti, Zr or Hf under conditions that provide orderly growth of the metal free of halide inclusions comprising: a) dissolving a reducing metal selected from the group consisting of Na, Mg, Li or K in their respective halide salts to produce a reducing molten salt stream; b) preparing a second molten salt stream containing the halide salt of Ti, Zr or Hf; c) mixing and reacting the two molten streams of steps a) and b) in a continuous stirred tank reactor; d) wherein steps a) through c) are conducted at a temperature range of from about 800.degree. C. to about 1100.degree. C. so that a weight percent of equilibrium solubility of the reducing metal in its respective halide salt varies from about 1.6 weight percent at about 900.degree. C. to about 14.4 weight percent at about 1062.degree. C.; and wherein a range of concentration of the halide salt of Ti, Zn or Hf in molten halides of Na, Mg, Li or K is from about 1 to about 5 times the concentration of Na, Mg, Li or K; e) placing the reacted molten stream from step c) in a solid-liquid separator to recover an impure granular metal product by decantation, centrifugation, or filtration; and f) removing residual halide salt impurity by vacuum evaporator or inert gas sweep at temperatures from about 850.degree. C. to 1000.degree. C. or cooling the impure granular metal product to ambient temperature and water leaching off the residual metal halide salt.

  7. Effects of Granular Control on Customers’ Perspective and Behavior with Automated Demand Response Systems

    SciTech Connect (OSTI)

    Schetrit, Oren; Kim, Joyce; Yin, Rongxin; Kiliccote, Sila

    2014-08-01

    Automated demand response (Auto-DR) is expected to close the loop between buildings and the grid by providing machine-to-machine communications to curtail loads without the need for human intervention. Hence, it can offer more reliable and repeatable demand response results to the grid than the manual approach and make demand response participation a hassle-free experience for customers. However, many building operators misunderstand Auto-DR and are afraid of losing control over their building operation. To ease the transition from manual to Auto-DR, we designed and implemented granular control of Auto-DR systems so that building operators could modify or opt out of individual load-shed strategies whenever they wanted. This paper reports the research findings from this effort demonstrated through a field study in large commercial buildings located in New York City. We focused on (1) understanding how providing granular control affects building operators’ perspective on Auto-DR, and (2) evaluating the usefulness of granular control by examining their interaction with the Auto-DR user interface during test events. Through trend log analysis, interviews, and surveys, we found that: (1) the opt-out capability during Auto-DR events can remove the feeling of being forced into load curtailments and increase their willingness to adopt Auto-DR; (2) being able to modify individual load-shed strategies allows flexible Auto-DR participation that meets the building’s changing operational requirements; (3) a clear display of automation strategies helps building operators easily identify how Auto-DR is functioning and can build trust in Auto-DR systems.

  8. An Elastic Plastic Contact Model with Strain Hardening for the LAMMPS Granular Package

    SciTech Connect (OSTI)

    Kuhr, Bryan; Brake, Matthew Robert; Lechman, Jeremy B.

    2015-03-01

    The following details the implementation of an analytical elastic plastic contact model with strain hardening for normal im pacts into the LAMMPS granular package. The model assumes that, upon impact, the co llision has a period of elastic loading followed by a period of mixed elastic plas tic loading, with contributions to each mechanism estimated by a hyperbolic seca nt weight function. This function is implemented in the LAMMPS source code as the pair style gran/ep/history. Preliminary tests, simulating the pouring of pure nickel spheres, showed the elastic/plastic model took 1.66x as long as similar runs using gran/hertz/history.

  9. Torsional rheometer for granular materials slurries and gas-solid mixtures and related methods

    DOE Patents [OSTI]

    Rajagopal, C.; Rajagopal, K.R.; Yalamanchili, R.C.

    1997-03-11

    A torsional rheometer apparatus for determining rheological properties of a specimen is provided. A stationary plate and a rotatable plate are in generally coaxial position and structured to receive a specimen there between. In one embodiment, at least one of the plates and preferably both have roughened specimen engaging surfaces to serve to reduce undesired slippage between the plate and the specimen. A motor is provided to rotate the rotatable plate and a transducer for monitoring forces applied to the stationary plate and generating output signals to a computer which determines the desired rheological properties are provided. In one embodiment, the roughened surfaces consist of projections extending toward the specimen. Where granular material is being evaluated, it is preferred that the roughness of the plate is generally equal to the average size of the granular material being processed. In another embodiment, an air-solid mixture is processed and the roughened portions are pore openings in the plates. Air flows through the region between the two pore containing plates to maintain the solid materials in suspension. In yet another embodiment, the base of the stationary plate is provided with a deformable capacitance sensor and associated electronic means. 17 figs.

  10. Torsional rheometer for granular materials slurries and gas-solid mixtures and related methods

    DOE Patents [OSTI]

    Rajagopal, Chandrika (Allison Park, PA); Rajagopal, Kumbakonam R. (Allison Park, PA); Yalamanchili, Rattaya C. (Allison Park, PA)

    1997-01-01

    A torsional rheometer apparatus for determining rheological properties of a specimen is provided. A stationary plate and a rotatable plate are in generally coaxial position and structured to receive a specimen therebetween. In one embodiment, at least one of the plates and preferably both have roughened specimen engaging surfaces to serve to reduce undesired slippage between the plate and the specimen. A motor is provided to rotate the rotatable plate and a transducer for monitoring forces applied to the stationary plate and generating output signals to a computer which determines the desired rheological properties are provided. In one embodiment, the roughened surfaces consist of projections extending toward the specimen. Where granular material is being evaluated, it is preferred that the roughness of the plate is generally equal to the average size of the granular material being processed. In another embodiment, an air-solid mixture is processed and the roughened portions are pore openings in the plates. Air flows through the region between the two pore containing plates to maintain the solid materials in suspension. In yet another embodiment, the base of the stationary plate is provided with a deformable capacitance sensor and associated electronic means.

  11. Iron production maintenance effectiveness system

    SciTech Connect (OSTI)

    Augstman, J.J.

    1996-12-31

    In 1989, an internal study in the Coke and Iron Maintenance Department identified the opportunities available to increase production, by decreasing unscheduled maintenance delays from 4.6%. A five year front loaded plan was developed, and presented to the company president. The plan required an initial investment of $1.4 million and a conservative break-even point was calculated to be 2.5 years. Due to budget restraints, it would have to be self-funded, i.e., generate additional production or savings, to pay for the program. The program began in 1991 at number 2 coke plant and the blast furnaces. This paper will describe the Iron Production Maintenance Effectiveness System (ME), which began with the mechanical and pipefitting trades.

  12. Microsoft Word - DUR 2006 CR.doc

    Office of Legacy Management (LM)

    Durango, Colorado Page 4-1 4.0 Durango, Colorado, Disposal Site 4.1 Compliance Summary The Durango, Colorado, Disposal Site, inspected on June 7, 2006, was in good condition. The retention pond northeast of the disposal cell was designed to retain transient drainage water from the cell that has been collected and treated with zero-valent iron. Because the pore water level in the disposal cell has dropped and remained below the required elevation, water has not been treated since 2004. In June

  13. Microsoft Word - Exec Summ CR.doc

    Office of Legacy Management (LM)

    Durango, Colorado Page 4-1 4.0 Durango, Colorado, Disposal Site 4.1 Compliance Summary The Durango, Colorado, Disposal Site, inspected on June 7, 2005, was in good condition. The holding pond northeast of the disposal cell retains transient drainage water from the cell that has been collected and treated with zero-valent iron. Because the water level in the disposal cell has dropped, water currently is not being treated. Breaks in the holding pond drainpipes are not scheduled for repair because

  14. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Electron Correlation in Iron-Based Superconductors Print Wednesday, 24 February 2010 00:00 In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of

  15. Weldability and hot ductility of iron aluminides

    SciTech Connect (OSTI)

    Ash, D.I.; Edwards, G.R. . Center for Welding and Joining Research); David, S.A. )

    1991-05-01

    The weldability of iron aluminide alloys is discussed. Although readily welded with electron beam (EB) and gas-tungsten arc (GTA) techniques, iron aluminides are sometimes susceptible to cracking during cooling when welded with the GTA welding process. Taken into account are the effects of microstructural instability (grain growth), weld heat input (cooling rate) and environment on the hot ductility of an iron aluminide alloy designated FA-129. 64 refs., 59 figs., 3 tabs.

  16. Surface modification of high temperature iron alloys

    DOE Patents [OSTI]

    Park, J.H.

    1995-06-06

    A method and article of manufacture of a coated iron based alloy are disclosed. The method includes providing an iron based alloy substrate, depositing a silicon containing layer on the alloy surface while maintaining the alloy at a temperature of about 700--1200 C to diffuse silicon into the alloy surface and exposing the alloy surface to an ammonia atmosphere to form a silicon/oxygen/nitrogen containing protective layer on the iron based alloy. 13 figs.

  17. High pressure effects on the iron iron oxide and nickel nickel oxide oxygen

    Office of Scientific and Technical Information (OSTI)

    fugacity buffers (Journal Article) | SciTech Connect High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers Citation Details In-Document Search Title: High pressure effects on the iron iron oxide and nickel nickel oxide oxygen fugacity buffers The chemical potential of oxygen in natural and experimental samples is commonly reported relative to a specific oxygen fugacity (fO{sub 2}) buffer. These buffers are precisely known at 1 bar, but under high

  18. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is...

  19. Oregon Iron Works Inc | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Oregon Iron Works Inc Region: United States Sector: Marine and Hydrokinetic Website: http: This company is listed in the Marine and Hydrokinetic...

  20. Method for producing iron-based catalysts

    DOE Patents [OSTI]

    Farcasiu, Malvina (Pittsburgh, PA); Kaufman, Phillip B. (Library, PA); Diehl, J. Rodney (Pittsburgh, PA); Kathrein, Hendrik (McMurray, PA)

    1999-01-01

    A method for preparing an acid catalyst having a long shelf-life is provided comprising doping crystalline iron oxides with lattice-compatible metals and heating the now-doped oxide with halogen compounds at elevated temperatures. The invention also provides for a catalyst comprising an iron oxide particle having a predetermined lattice structure, one or more metal dopants for said iron oxide, said dopants having an ionic radius compatible with said lattice structure; and a halogen bound with the iron and the metal dopants on the surface of the particle.

  1. Nanostructure, Chemistry and Crystallography of Iron Nitride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy and Related Methods Nanostructure, Chemistry and Crystallography of Iron Nitride Magnetic Materials by Ultra-High-Resolution Electron Microscopy and Related ...

  2. Iron oxyhydroxide mineralization on microbial extracellular polysaccharides

    SciTech Connect (OSTI)

    Chan, Clara S.; Fakra, Sirine C.; Edwards, David C.; Emerson, David; Banfield, Jillian F.

    2010-06-22

    Iron biominerals can form in neutral pH microaerophilic environments where microbes both catalyze iron oxidation and create polymers that localize mineral precipitation. In order to classify the microbial polymers that influence FeOOH mineralogy, we studied the organic and mineral components of biominerals using scanning transmission X-ray microscopy (STXM), micro X-ray fluorescence ({mu}XRF) microscopy, and high-resolution transmission electron microscopy (HRTEM). We focused on iron microbial mat samples from a creek and abandoned mine; these samples are dominated by iron oxyhydroxide-coated structures with sheath, stalk, and filament morphologies. In addition, we characterized the mineralized products of an iron-oxidizing, stalk-forming bacterial culture isolated from the mine. In both natural and cultured samples, microbial polymers were found to be acidic polysaccharides with carboxyl functional groups, strongly spatially correlated with iron oxyhydroxide distribution patterns. Organic fibrils collect FeOOH and control its recrystallization, in some cases resulting in oriented crystals with high aspect ratios. The impact of polymers is particularly pronounced as the materials age. Synthesis experiments designed to mimic the biomineralization processes show that the polysaccharide carboxyl groups bind dissolved iron strongly but release it as mineralization proceeds. Our results suggest that carboxyl groups of acidic polysaccharides are produced by different microorganisms to create a wide range of iron oxyhydroxide biomineral structures. The intimate and potentially long-term association controls the crystal growth, phase, and reactivity of iron oxyhydroxide nanoparticles in natural systems.

  3. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    between different theoretical models and experimental data indicated that, instead of localized states due to strong electron interactions, electrons in iron pnictides prefer...

  4. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    At bottom left, the kinds of iron species found in two transects of the Southern Ocean are ... (ACC stands for Antarctic Circumpolar Current.) The map shows chlorophyll ...

  5. Iron oxyhydroxide mineralization on microbial extracellular polysaccha...

    Office of Scientific and Technical Information (OSTI)

    a creek and abandoned mine; these samples are dominated by iron oxyhydroxide-coated structures with sheath, stalk, and filament morphologies. In addition, we characterized the...

  6. The structural origin of the hard-sphere glass transition in granular packing

    SciTech Connect (OSTI)

    Xia, Chengjie; Li, Jindong; Cao, Yixin; Kou, Binquan; Xiao, Xianghui; Fezzaa, Kamel; Xiao, Tiqiao; Wang, Yujie

    2015-09-28

    Glass transition is accompanied by a rapid growth of the structural relaxation time and a concomitant decrease of configurational entropy. It remains unclear whether the transition has a thermodynamic origin, and whether the dynamic arrest is associated with the growth of a certain static order. Using granular packing as a model hard-sphere glass, we show the glass transition as a thermodynamic phase transition with a ‘hidden’ polytetrahedral order. This polytetrahedral order is spatially correlated with the slow dynamics. It is geometrically frustrated and has a peculiar fractal dimension. Additionally, as the packing fraction increases, its growth follows an entropy-driven nucleation process, similar to that of the random first-order transition theory. In conclusion, our study essentially identifies a long-sought-after structural glass order in hard-sphere glasses.

  7. Method and apparatus for filtering gas with a moving granular filter bed

    DOE Patents [OSTI]

    Brown, Robert C.; Wistrom, Corey; Smeenk, Jerod L.

    2007-12-18

    A method and apparatus for filtering gas (58) with a moving granular filter bed (48) involves moving a mass of particulate filter material (48) downwardly through a filter compartment (35); tangentially introducing gas into the compartment (54) to move in a cyclonic path downwardly around the moving filter material (48); diverting the cyclonic path (58) to a vertical path (62) to cause the gas to directly interface with the particulate filter material (48); thence causing the gas to move upwardly through the filter material (48) through a screened partition (24, 32) into a static upper compartment (22) of a filter compartment for exodus (56) of the gas which has passed through the particulate filter material (48).

  8. The structural origin of the hard-sphere glass transition in granular packing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xia, Chengjie; Li, Jindong; Cao, Yixin; Kou, Binquan; Xiao, Xianghui; Fezzaa, Kamel; Xiao, Tiqiao; Wang, Yujie

    2015-09-28

    Glass transition is accompanied by a rapid growth of the structural relaxation time and a concomitant decrease of configurational entropy. It remains unclear whether the transition has a thermodynamic origin, and whether the dynamic arrest is associated with the growth of a certain static order. Using granular packing as a model hard-sphere glass, we show the glass transition as a thermodynamic phase transition with a ‘hidden’ polytetrahedral order. This polytetrahedral order is spatially correlated with the slow dynamics. It is geometrically frustrated and has a peculiar fractal dimension. Additionally, as the packing fraction increases, its growth follows an entropy-driven nucleationmore » process, similar to that of the random first-order transition theory. In conclusion, our study essentially identifies a long-sought-after structural glass order in hard-sphere glasses.« less

  9. The production of iron carbide

    SciTech Connect (OSTI)

    Anderson, K.M.; Scheel, J.

    1997-12-31

    From start-up in 1994 to present, Nucor`s Iron Carbide plant has overcome many obstacles in achieving design production. Many of these impediments were due to flaws in equipment design. With the integration existing within the plant, limitations in any one system reduced the operating capacity of others. For this reason, as modifications were made and system capacities were increased, the need for additional modifications became apparent. Subsequently, operating practices, maintenance scheduling, employee incentives, and production objectives were continually adapted. This paper discusses equipment and design corrections and the quality issues that contributed to achieving the plant`s production capacity.

  10. EFFECT OF ENDOSPERM HARDNESS ON AN ETHANOL PROCESS USING A GRANULAR STARCH HYDROLYZING ENZYME

    SciTech Connect (OSTI)

    P. Wang; W. Liu, D. B; Johnston, K. D; Rausch, S. J; Schmidt, M. E; Tumbleson, V. Singh

    2010-01-01

    Granular starch hydrolyzing enzymes (GSHE) can hydrolyze starch at low temperature (32C). The dry grind process using GSHE (GSH process) has fewer unit operations and no changes in process conditions (pH 4.0 and 32C) compared to the conventional process because it dispenses with the cooking and liquefaction step. In this study, the effects of endosperm hardness, protease, urea, and GSHE levels on GSH process were evaluated. Ground corn, soft endosperm, and hard endosperm were processed using two GSHE levels (0.1 and 0.4 mL per 100 g ground material) and four treatments of protease and urea addition. Soft and hard endosperm materials were obtained by grinding and sifting flaking grits from a dry milling pilot plant; classifications were confirmed using scanning electron microscopy. During 72 h of simultaneous granular starch hydrolysis and fermentation (GSHF), ethanol and glucose profiles were determined using HPLC. Soft endosperm resulted in higher final ethanol concentrations compared to ground corn or hard endosperm. Addition of urea increased final ethanol concentrations for soft and hard endosperm. Protease addition increased ethanol concentrations and fermentation rates for soft endosperm, hard endosperm, and ground corn. The effect of protease addition on ethanol concentrations and fermentation rates was most predominant for soft endosperm, less for hard endosperm, and least for ground corn. Samples (soft endosperm, hard endosperm, or corn) with protease resulted in higher (1.0% to 10.5% v/v) ethanol concentration compared to samples with urea. The GSH process with protease requires little or no urea addition. For fermentation of soft endosperm, GSHE dose can be reduced. Due to nutrients (lipids, minerals, and soluble proteins) present in corn that enhance yeast growth, ground corn fermented faster at the beginning than hard and soft endosperm.

  11. Microbial reduction of iron ore (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a...

  12. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle The Iron Spin Transition in the Earth's Lower Mantle Print Wednesday, 30 April 2008 00:00 It is now known that the iron present...

  13. Marine Diatoms Survive Iron Droughts in the Ocean by Storing Iron in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ferritin Marine Diatoms Survive Iron Droughts in the Ocean by Storing Iron in Ferritin Almost all organisms require iron as a co-factor in numerous metalloproteins and enzymes. In particular, phytoplankton, which are aquatic, free-drifting, single-celled organisms that can harvest energy from the sun, have an elevated demand for iron due to the large role it plays in their photosynthetic machinery. In 30-40% of the world's oceans iron concentrations are low enough to limit the growth of

  14. Evaluation of Characterization Techniques for Iron Pipe Corrosion Products

    Office of Scientific and Technical Information (OSTI)

    and Iron Oxide Thin Films (Journal Article) | SciTech Connect Journal Article: Evaluation of Characterization Techniques for Iron Pipe Corrosion Products and Iron Oxide Thin Films Citation Details In-Document Search Title: Evaluation of Characterization Techniques for Iron Pipe Corrosion Products and Iron Oxide Thin Films A common problem faced by drinking water studies is that of properly characterizing the corrosion products (CP) in iron pipescor synthetic Fe (hydr)oxides used to simulate

  15. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron and Steel (2010 MECS) Iron and Steel (2010 MECS) Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014 View footprints for other sectors here. Manufacturing Energy and Carbon Footprint PDF icon Iron and Steel More Documents & Publications MECS 2006 - Iron and Steel Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), October

  16. Dechlorination of TCE with palladized iron

    DOE Patents [OSTI]

    Fernando, Quintus; Muftikian, Rosy; Korte, Nic

    1997-01-01

    The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from various effluents or contaminated soil containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products.

  17. IRON COATED URANIUM AND ITS PRODUCTION

    DOE Patents [OSTI]

    Gray, A.G.

    1960-03-15

    A method of applying a protective coating to a metallic uranium article is given. The method comprises etching the surface of the article with an etchant solution containlng chloride ions, such as a solution of phosphoric acid and hydrochloric acid, cleaning the etched surface, electroplating iron thereon from a ferrous ammonium sulfate electroplating bath, and soldering an aluminum sheath to the resultant iron layer.

  18. Production of iron from metallurgical waste

    DOE Patents [OSTI]

    Hendrickson, David W; Iwasaki, Iwao

    2013-09-17

    A method of recovering metallic iron from iron-bearing metallurgical waste in steelmaking comprising steps of providing an iron-bearing metallurgical waste containing more than 55% by weight FeO and FeO equivalent and a particle size of at least 80% less than 10 mesh, mixing the iron-bearing metallurgical waste with a carbonaceous material to form a reducible mixture where the carbonaceous material is between 80 and 110% of the stoichiometric amount needed to reduce the iron-bearing waste to metallic iron, and as needed additions to provide a silica content between 0.8 and 8% by weight and a ratio of CaO/SiO.sub.2 between 1.4 and 1.8, forming agglomerates of the reducible mixture over a hearth material layer to protect the hearth, heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic iron and slag material from the agglomerates by melting.

  19. Manufacturing Energy and Carbon Footprint - Sector: Iron and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006) Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS ...

  20. Neutron scattering of iron-based superconductors (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Neutron scattering of iron-based superconductors Citation Details In-Document Search Title: Neutron scattering of iron-based superconductors Low-energy spin excitations have been...

  1. Influence of Iron Redox Transformations on Plutonium Sorption...

    Office of Scientific and Technical Information (OSTI)

    Influence of Iron Redox Transformations on Plutonium Sorption to Sediments Citation Details In-Document Search Title: Influence of Iron Redox Transformations on Plutonium Sorption ...

  2. Pressure-Driven Quantum Criticality in Iron-Selenide Superconductors...

    Office of Scientific and Technical Information (OSTI)

    Pressure-Driven Quantum Criticality in Iron-Selenide Superconductors Title: Pressure-Driven Quantum Criticality in Iron-Selenide Superconductors Authors: Guo, Jing ; Chen, Xiao-Jia ...

  3. Preparations of rare earth-iron alloys by thermite reduction

    DOE Patents [OSTI]

    Schmidt, Frederick A.; Peterson, David T.; Wheelock, John T.

    1986-09-16

    An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

  4. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at the ALS. Researchers hypothesized that the iron had come from dinosaurs' blood and muscle cells during decay, and were able to identify iron-facilitated reactions that...

  5. Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at...

    Office of Scientific and Technical Information (OSTI)

    Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at 40 - 50 GPa and their ... Title: Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at 40 - 50 GPa and ...

  6. Phase Discrimination through Oxidant Selection for Iron Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron...

  7. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come...

  8. Laser-Doppler acoustic probing of granular media with in-depth property gradient and varying pore pressures

    SciTech Connect (OSTI)

    Bodet, L.; Dhemaied, A.; Mourgues, R.; Tournat, V.; Rejiba, F.

    2012-05-24

    Non-contacting ultrasonic techniques recently proved to be efficient in the physical modeling of seismic-wave propagation at various application scales, as for instance in the context of geological analogue and seismic modeling. An innovative experimental set-up is proposed here to perform laser-Doppler acoustic probing of unconsolidated granular media with varying pore pressures. The preliminary experiments presented here provide reproducible results and exploitable data, thus validating both the proposed medium preparation and pressure gradient generation procedure.

  9. Dechlorination of TCE with palladized iron

    DOE Patents [OSTI]

    Fernando, Q.; Muftikian, R.; Korte, N.

    1998-06-02

    The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds. 10 figs.

  10. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Iron Availability in the Southern Ocean Print Friday, 21 June 2013 10:08 The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is

  11. Dechlorination of TCE with palladized iron

    DOE Patents [OSTI]

    Fernando, Quintus; Muftikian, Rosy; Korte, Nic

    1998-01-01

    The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds.

  12. Dechlorination of TCE with palladized iron

    DOE Patents [OSTI]

    Fernando, Quintus; Muftikian, Rosy; Korte, Nic

    1997-01-01

    The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds.

  13. Dechlorination of TCE with palladized iron

    DOE Patents [OSTI]

    Fernando, Q.; Muftikian, R.; Korte, N.

    1997-03-18

    The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds. 10 figs.

  14. Synthesis of iron based hydrocracking catalysts

    DOE Patents [OSTI]

    Farcasiu, Malvina (Pittsburgh, PA); Eldredge, Patricia A. (Barboursville, VA); Ladner, Edward P. (Pittsburgh, PA)

    1993-01-01

    A method of preparing a fine particle iron based hydrocracking catalyst and the catalyst prepared thereby. An iron (III) oxide powder and elemental sulfur are reacted with a liquid hydrogen donor having a hydroaromatic structure present in the range of from about 5 to about 50 times the weight of iron (III) oxide at a temperature in the range of from about 180.degree. C. to about 240.degree. C. for a time in the range of from about 0 to about 8 hours. Various specific hydrogen donors are disclosed. The catalysts are active at low temperature (<350.degree. C.) and low pressure.

  15. IEA Energy conservation in the iron and steel industry. [US and Western Europe

    SciTech Connect (OSTI)

    Tunnah, B.G.

    1981-01-01

    The NATO Committee on the Challenges of Modern Society research program, under the auspices of the IEA, had the objectives of collecting data on material requirements and energy-consumption patterns in selected energy-intensive industries in the US and Western Europe, of identifying technologies and operating practices with the potential for energy conservation in those industries, and of recommending research projects that could lead to improved energy efficiency. The steel industry was selected for analysis and ideas for an international cooperative program were developed. Representatives from various countries conducted meetings and the form of an implementing agreement for a research and development program was finalized in December, 1980. The program includes three technical areas: hot-surface inspection, heat recovery, and coal gasification. Hot-surface inspection methods to be demonstrated are: optical, induction, electromagnetic ultrasonic, electromagnetic ultrasonic surface testing methods, and eddy current method for hot surface inspection and an infrared system (possibly). Three heat-recovery projects are: ceramic heat wheel development; demonstration of granular bed/heat pipe system for heat recovery; and demonstration of tubular ceramic recuperators. Processes in coal gasification are: converter process, gas treatment, and iron treatment. Each project is described in detail. (MCW)

  16. Shock Loading of Granular Ni/Al Composites. Part 1. Mechanics of Loading

    SciTech Connect (OSTI)

    Cherukara, Mathew J.; Germann, Timothy C.; Kober, Edward M.; Strachan, Alejandro

    2014-10-16

    We present molecular dynamics simulations of the thermomechanical response under shock loading of a granular material consisting of laminated Ni/Al grains. We observe two regimes: At low piston velocities (up ? 1km/s), the shock wave is diffuse, and the width of the shock front decreases with increasing piston velocity. Beyond a critical shock strength, however, the width remains relatively constant at approximately the mean grain radius. This change in behavior follows from an evolution of the mechanism of compaction with increasing insult strength. Furthermore, the mechanism evolves from plastic deformation-mediated pore collapse for relatively weak shocks, to solid extrusion and fluid ejecta filling pores ahead of the shock front at intermediate strengths, and finally to atomic jetting into the pore for very strong shocks (up ? 2 km/s). High-energy fluid ejecta into pores leads to the formation of flow vorticity and can result in a large fraction of the input energy localizing into translational kinetic energy components including the formation of hot spots. This has implications for the mechanical mixing of Ni and Al in these reactive composites.

  17. Time-Periodic Solutions of Driven-Damped Trimer Granular Crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Charalampidis, E. G.; Li, F.; Chong, C.; Yang, J.; Kevrekidis, P. G.

    2015-01-01

    We consider time-periodic structures of granular crystals consisting of alternate chrome steel (S) and tungsten carbide (W) spherical particles where each unit cell follows the pattern of a 2 : 1 trimer: S-W-S. The configuration at the left boundary is driven by a harmonic in-time actuation with given amplitude and frequency while the right one is a fixed wall. Similar to the case of a dimer chain, the combination of dissipation, driving of the boundary, and intrinsic nonlinearity leads to complex dynamics. For fixed driving frequencies in each of the spectral gaps, we find that the nonlinear surface modes and the statesmore » dictated by the linear drive collide in a saddle-node bifurcation as the driving amplitude is increased, beyond which the dynamics of the system becomes chaotic. While the bifurcation structure is similar for solutions within the first and second gap, those in the first gap appear to be less robust. We also conduct a continuation in driving frequency, where it is apparent that the nonlinearity of the system results in a complex bifurcation diagram, involving an intricate set of loops of branches, especially within the spectral gap. The theoretical findings are qualitatively corroborated by the experimental full-field visualization of the time-periodic structures.« less

  18. IS MAGNETIC RECONNECTION THE CAUSE OF SUPERSONIC UPFLOWS IN GRANULAR CELLS?

    SciTech Connect (OSTI)

    Borrero, J. M.; Schmidt, W.; Martinez Pillet, V.; Quintero Noda, C.; Bonet, J. A.

    2013-05-01

    In a previous work, we reported on the discovery of supersonic magnetic upflows on granular cells in data from the SUNRISE/IMaX instrument. In the present work, we investigate the physical origin of these events employing data from the same instrument but with higher spectral sampling. By means of the inversion of Stokes profiles we are able to recover the physical parameters (temperature, magnetic field, line-of-sight velocity, etc.) present in the solar photosphere at the time of these events. The inversion is performed in a Monte-Carlo-like fashion, that is, repeating it many times with different initializations and retaining only the best result. We find that many of the events are characterized by a reversal in the polarity of the magnetic field along the vertical direction in the photosphere, accompanied by an enhancement in the temperature and by supersonic line-of-sight velocities. In about half of the studied events, large blueshifted and redshifted line-of-sight velocities coexist above/below each other. These features can be explained in terms of magnetic reconnection, where the energy stored in the magnetic field is released in the form of kinetic and thermal energy when magnetic field lines of opposite polarities coalesce. However, the agreement with magnetic reconnection is not perfect and, therefore, other possible physical mechanisms might also play a role.

  19. What can granular media teach us about deformation in geothermal systems

    SciTech Connect (OSTI)

    Stephen L. Karner

    2004-06-01

    Experiments on granular media have significantly improved our understanding of deformation processes in porous rocks. Laboratory results have lead to fundamental theoretical developments (such as poroelasticity, or rate and state-variable friction) that have found widespread application. This paper presents results from laboratory experiments that help constrain these theories. Data from triaxial deformation experiments on quartz sand aggregates are used to illustrate stress-dependent behavior of poroelastic parameters (e.g. the Biot-Willis and Skempton coefficients). Calculations for these coefficients show systematic variations as effective stress increases, in a manner consistent with measured compressibilities of the aggregate. Data from shear experiments show that frictional strength varies systematically with time and temperature. At temperatures below 450 oC, shear zones exhibit greater cohesive strengths as the time of stationary contact increases (hence, positive healing rates). For conditions exceeding 450 oC, shear zone strength is seen to decrease with contact time (negative healing rates). The results from both volumetric compaction and frictional shear experiments are well described by poroelasticity as well as rate and state-variable friction. The combination of these constitutive relations may provide a powerful tool that can be used in numerical models that couple thermal, mechanical, hydraulic, and temporal processes as occur in geothermal systems.

  20. PHOTOSPHERIC SIGNATURES OF GRANULAR-SCALE FLUX EMERGENCE AND CANCELLATION AT THE PENUMBRAL BOUNDARY

    SciTech Connect (OSTI)

    Lim, Eun-Kyung; Yurchyshyn, Vasyl; Abramenko, Valentyna; Ahn, Kwangsu; Cao Wenda; Goode, Philip

    2011-10-20

    We studied flux emergence events of sub-granular scale in a solar active region. The New Solar Telescope (NST) of the Big Bear Solar Observatory made it possible to clearly observe the photospheric signature of flux emergence with very high spatial (0.''11 at 7057 A) and temporal (15 s) resolution. From TiO observations with the pixel scale of 0.''0375, we found several elongated granule-like features (GLFs) stretching from the penumbral filaments of a sunspot at a relatively high speed of over 4 km s{sup -1}. After a slender arched darkening appeared at the tip of a penumbral filament, a bright point (BP) developed and quickly moved away from the filament, forming and stretching a GLF. The size of a GLF was approximately 0.''5 wide and 3'' long. The moving BP encountered nearby structures after several minutes of stretching, and the well-defined elongated shape of the GLF faded away. Magnetograms from the Solar Dynamics Observatory/Helioseismic and Magnetic Imager and NST/InfraRed Imaging Magnetograph revealed that those GLFs are photospheric indicators of small-scale flux emergence, and their disappearance is related to magnetic cancellation. From two well-observed events, we describe detailed development of the sub-structures of GLFs and different cancellation processes that each of the two GLFs underwent.

  1. Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors

    SciTech Connect (OSTI)

    Wei Yanjie; Ji Min; Li Ruying; Qin Feifei

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Aerobic granular sludge SBR was used to treat real landfill leachate. Black-Right-Pointing-Pointer COD removal was analyzed kinetically using a modified model. Black-Right-Pointing-Pointer Characteristics of nitrogen removal at different ammonium inputs were explored. Black-Right-Pointing-Pointer DO variations were consistent with the GSBR performances at low ammonium inputs. - Abstract: Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L{sup -1}, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L{sup -1}, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L{sup -1}, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.

  2. Shock Loading of Granular Ni/Al Composites. Part 1. Mechanics of Loading

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cherukara, Mathew J.; Germann, Timothy C.; Kober, Edward M.; Strachan, Alejandro

    2014-10-16

    We present molecular dynamics simulations of the thermomechanical response under shock loading of a granular material consisting of laminated Ni/Al grains. We observe two regimes: At low piston velocities (up ≲ 1km/s), the shock wave is diffuse, and the width of the shock front decreases with increasing piston velocity. Beyond a critical shock strength, however, the width remains relatively constant at approximately the mean grain radius. This change in behavior follows from an evolution of the mechanism of compaction with increasing insult strength. Furthermore, the mechanism evolves from plastic deformation-mediated pore collapse for relatively weak shocks, to solid extrusion andmore » fluid ejecta filling pores ahead of the shock front at intermediate strengths, and finally to atomic jetting into the pore for very strong shocks (up ≳ 2 km/s). High-energy fluid ejecta into pores leads to the formation of flow vorticity and can result in a large fraction of the input energy localizing into translational kinetic energy components including the formation of hot spots. This has implications for the mechanical mixing of Ni and Al in these reactive composites.« less

  3. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Animal, Vegetable or Mineral? Iron is a limiting nutrient in many parts of the oceans, nowhere more so than in the Southern Ocean's photic zone, which receives enough sunlight for...

  4. System and method for producing metallic iron

    DOE Patents [OSTI]

    Englund, David J.; Schlichting, Mark; Meehan, John; Crouch, Jeremiah; Wilson, Logan

    2014-07-29

    A method of production of metallic iron nodules comprises assembling a hearth furnace having a moveable hearth comprising refractory material and having a conversion zone and a fusion zone, providing a hearth material layer comprising carbonaceous material on the refractory material, providing a layer of reducible material comprising and iron bearing material arranged in discrete portions over at least a portion of the hearth material layer, delivering oxygen gas into the hearth furnace to a ratio of at least 0.8:1 ponds of oxygen to pounds of iron in the reducible material to heat the conversion zone to a temperature sufficient to at least partially reduce the reducible material and to heat the fusion zone to a temperature sufficient to at least partially reduce the reducible material, and heating the reducible material to form one or more metallic iron nodules and slag.

  5. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which prevents two electrons from occupying the same site, resulting in a so-called Mott insulator. The lack of information on the strength of electron correlation in the iron...

  6. MECS 2006 - Iron and Steel | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iron and Steel MECS 2006 - Iron and Steel Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) with Total Energy Input, October 2012 (MECS 2006) All available footprints and supporting documents Manufacturing Energy and Carbon Footprint PDF icon Iron and Steel More Documents & Publications Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006

  7. Center for Inverse Design Highlight: Iron Chalcogenide PV Absorbers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Chalcogenide Photovoltaic Absorbers The Center for Inverse Design has identified the iron-based ternary chalcogenide materials Fe 2 SiS 4 and Fe 2 GeS 4 as promising new photovoltaic materials, which circumvent the problems historically encountered with iron sulfide FeS 2 (iron pyrite). There is intense interest in earth-abundant materials, including iron-bearing systems, for the widespread development of photovoltaic (PV) technologies to sustainably meet growing energy needs. The inverse

  8. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch

  9. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch

  10. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch

  11. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  12. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  13. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  14. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  15. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  16. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  17. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  18. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch

  19. Iron Availability in the Southern Ocean

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch

  20. Dechlorination of TCE with palladized iron

    DOE Patents [OSTI]

    Fernando, Q.; Muftikian, R.; Korte, N.

    1997-04-01

    The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from various effluents or contaminated soil containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. 10 figs.

  1. Development of an integrated, in-situ remediation technology. Topical report for task No. 9. Part I. TCE degradation using nonbiological methods, September 26, 1994--May 25, 1996

    SciTech Connect (OSTI)

    Shapiro, A.P.; Sivavec, T.M.; Baghel, S.S.

    1997-04-01

    Contamination in low-permeability soils poses a significant technical challenge for in situ remediation efforts. Poor accessibility to the contaminants and difficulty in delivery of treatment reagents have rendered existing in situ treatments such as bioremediation, vapor extraction, pump and treat rather ineffective when applied to low-permeability soils present at many contaminated sites. The technology is an integrated in situ treatment in which established geotechnical methods are used to install degradation zones directly in the contaminated soil and electro-osmosis is used to move the contaminants back and forth through those zones until the treatment is completed. The present Draft Topical Report for Task No. 9 summarizes laboratory investigations into TCE degradation using nonbiological methods. These studies were conducted by the General Electric Company. The report concentrates on zero valent iron as the reducing agent and presents data on TCE and daughter product degradation rates in batch experiments, column studies, and electroosmotic cells. It is shown that zero valent iron effectively degrades TCE in electroosmotic experiments. Daughter product degradation and gas generation are shown to be important factors in designing field scale treatment zones for the Lasagna{trademark} process.

  2. Understanding the Factors Affecting the Formation of Carbonyl Iron Electrodes in Rechargeable Alkaline Iron Batteries

    SciTech Connect (OSTI)

    Manohar, AK; Yang, CG; Malkhandi, S; Yang, B; Prakash, GKS; Narayanan, SR

    2012-01-01

    Rechargeable iron-based alkaline batteries such as iron - air and nickel - iron batteries are attractive for large-scale electrical energy storage because iron is inexpensive, globally-abundant and environmentally-friendly. Further, the iron electrode is known for its robustness to repeated charge/discharge cycling. During manufacturing these batteries are charged and discharged 20 to 50 times during which the discharge capacity of the iron electrode increases gradually and attains a stable value. This process of achieving stable capacity is called formation. In this study we have focused our efforts on understanding the effect of electrode design on formation. We have investigated the role of wetting agent, pore-former additive, and sulfide additive on the formation of carbonyl iron electrodes. The wetting agent increased the rate of formation while the pore-former additive increased the final capacity. Sodium sulfide added to the electrolyte worked as a de-passivation agent and increased the final discharge capacity. We have proposed a phenomenological model for the formation process that predicts the rate of formation and final discharge capacity given the design parameters for the electrode. The understanding gained here will be useful in reducing the time lost in formation and in maximizing the utilization of the iron electrode. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.021301jes] All rights reserved.

  3. Transport of fluorescently labeled hydroxyapatite nanoparticles in saturated granular media at environmentally relevant concentrations of surfactants

    SciTech Connect (OSTI)

    Wang, Dengjun; Su, Chuming; Liu, Chongxuan; Zhou, Dongmei

    2014-05-01

    Hydroxyapatite nanoparticle (nHAP) is being used to remediate soils and aquifers contaminated with metals and radionuclides; however, the mobility of nHAP is still poorly understood in subsurface granular environments. In this study, transport and retention kinetics of alizarin red S (ARS)-labeled nHAP were investigated in water-saturated quartz sand at low concentrations of surfactants: sodium dodecyl benzene sulfonate (SDBS, an anionic surfactant, 050 mg L1) and cetyltrimethylammonium bromide (CTAB, a cationic surfactant, 05 mg L1). Both surfactants were found to have a marked effect on the electrokinetic properties of ARS-nHAP and, consequently, on their transport and retention behaviors. Transport of nanoparticles (NPs) increased significantly with increasing SDBS concentration, largely because of enhanced colloidal stability and reduced aggregate size arising from enhanced electrostatic, osmotic, and elastic-steric repulsions between ARS-nHAP and sand grains. Conversely, transport decreased significantly in the presence of increasing CTAB concentrations due to reduced surface charge and consequential enhanced aggregation of the NPs. Osmotic and elastic-steric repulsions played only a minor role in enhancing the colloidal stability of ARS-nHAP in the presence of CTAB. Retention profiles of ARS-nHAP exhibited hyperexponential-shapes (decreasing rates of retention with increasing distance) for all conditions tested, and became more pronounced as CTAB concentration increased. The phenomenon was attributed to the aggregation and ripening of ARS-nHAP in the presence of surfactants, particularly CTAB. Overall, the present study suggests that surfactants at environmentally relevant concentrations may be an important consideration in employing nHAP for engineered in-situ remediation of certain metals and radionuclides in contaminated soils and aquifers.

  4. Alternative granular media for the metal casting industry. Final report, September 30, 1994

    SciTech Connect (OSTI)

    Guichelaar, P.J.; Ramrattan, S.N.; Tieder, R.E.

    1995-09-01

    Silica sand for foundry use is inexpensive to purchase, readily transported and widely available. As a result, it is universally used. However, three factors are becoming increasingly significant as more environmental regulations are promulgated. First, the disposal of waste foundry sand has become an excessively burdensome cost. Second, the phase changes which occur in the silica structure on heating and cooling cause thermal breakdown of the sand into smaller unusable fractions. Third, silica is a relatively weak mineral. Alternatives to silica sand which can withstand the rigors of repetitive reuse must be seriously evaluated as a way to control production costs of the domestic metal casting industry. Chromite sands, olivine sands and carbon sands have each been successfully used to solve operating problems and thus have developed their specific niches in the foundry materials inventory. However, there are several other materials that are candidates for replacing silica sand, such as fused alumina, sintered bauxite and sintered oil well proppants. These media, and others that are generically similar, are manufactured for specific purposes. Compositions and shapes could be readily tailored for used in a metal casting environment of total recycling and materials conservation. This study examines materials that are readily available as alternatives to silica sand from a functionality perspective and a cost perspective. Some of the alternative materials are natural and others are synthetic and thus referring to them as ``sands`` has the potential to cause confusion; the generic term ``granular medium`` is used in this study to mean any material that could functionally substitute for silica sand in the foundry process.

  5. Iron-based amorphous alloys and methods of synthesizing iron-based amorphous alloys

    DOE Patents [OSTI]

    Saw, Cheng Kiong; Bauer, William A.; Choi, Jor-Shan; Day, Dan; Farmer, Joseph C.

    2016-05-03

    A method according to one embodiment includes combining an amorphous iron-based alloy and at least one metal selected from a group consisting of molybdenum, chromium, tungsten, boron, gadolinium, nickel phosphorous, yttrium, and alloys thereof to form a mixture, wherein the at least one metal is present in the mixture from about 5 atomic percent (at %) to about 55 at %; and ball milling the mixture at least until an amorphous alloy of the iron-based alloy and the at least one metal is formed. Several amorphous iron-based metal alloys are also presented, including corrosion-resistant amorphous iron-based metal alloys and radiation-shielding amorphous iron-based metal alloys.

  6. Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

    DOE Patents [OSTI]

    Shen, Ming-Shing (Rocky Point, NY); Yang, Ralph T. (Middle Island, NY)

    1980-01-01

    Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

  7. Tropical forest soil microbial communities couple iron and carbon biogeochemistry

    SciTech Connect (OSTI)

    Dubinsky, E.A.; Silver, W.L.; Firestone, M.K.

    2009-10-15

    We report that iron-reducing bacteria are primary mediators of anaerobic carbon oxidation in upland tropical soils spanning a rainfall gradient (3500 - 5000 mm yr-1) in northeast Puerto Rico. The abundant rainfall and high net primary productivity of these tropical forests provide optimal soil habitat for iron-reducing and iron-oxidizing bacteria. Spatially and temporally dynamic redox conditions make iron-transforming microbial communities central to the belowground carbon cycle in these wet tropical forests. The exceedingly high abundance of iron-reducing bacteria (up to 1.2 x 10{sup 9} cells per gram soil) indicated that they possess extensive metabolic capacity to catalyze the reduction of iron minerals. In soils from the higher rainfall sites, measured rates of ferric iron reduction could account for up to 44 % of organic carbon oxidation. Iron reducers appeared to compete with methanogens when labile carbon availability was limited. We found large numbers of bacteria that oxidize reduced iron at sites with high rates of iron reduction and large numbers of iron-reducers. the coexistence of large populations of ironreducing and iron-oxidizing bacteria is evidence for rapid iron cycling between its reduced and oxidized states, and suggests that mutualistic interactions among these bacteria ultimately fuel organic carbon oxidation and inhibit CH4 production in these upland tropical forests.

  8. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced...

  9. Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Films | ANSER Center | Argonne-Northwestern National Laboratory Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films

  10. Preparations of rare earth-iron alloys by thermite reduction

    DOE Patents [OSTI]

    Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.

    1985-10-28

    Disclosed is an improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

  11. Baotou Iron and Steel Group Baotou Steel | Open Energy Information

    Open Energy Info (EERE)

    search Name: Baotou Iron and Steel Group (Baotou Steel) Place: Baotou, Inner Mongolia Autonomous Region, China Product: Baotou-based iron and steel maker as well as a rare...

  12. Iron County, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    is classified as ASHRAE 169-2006 Climate Zone Number 5 Climate Zone Subtype B. Registered Energy Companies in Iron County, Utah Solar Unlimited USA Places in Iron County, Utah...

  13. City of Mountain Iron, Minnesota (Utility Company) | Open Energy...

    Open Energy Info (EERE)

    City of Mountain Iron, Minnesota (Utility Company) Jump to: navigation, search Name: City of Mountain Iron Place: Minnesota Phone Number: (218)748-7570 Website: www.mtniron.com...

  14. Emergence of granular-sized magnetic bubbles through the solar atmosphere. I. Spectropolarimetric observations and simulations

    SciTech Connect (OSTI)

    Ortiz, Ada; Hansteen, Viggo H.; Van der Voort, Luc Rouppe [Institute of Theoretical Astrophysics, University of Oslo, P.O. Box 1029 Blindern, N-0315 Oslo (Norway); Bellot Rubio, Luis R. [Instituto de Astrofsica de Andaluca (CSIC), Apdo. 3040, E-18080 Granada (Spain); De la Cruz Rodrguez, Jaime, E-mail: ada@astro.uio.no [Department of Physics and Astronomy, Uppsala University, Box 516, SE-75120 Uppsala (Sweden)

    2014-02-01

    We study a granular-sized magnetic flux emergence event that occurred in NOAA 11024 in 2009 July. The observations were made with the CRISP spectropolarimeter at the Swedish 1 m Solar Telescope achieving a spatial resolution of 0.''14. Simultaneous full Stokes observations of the two photospheric Fe I lines at 630.2 nm and the chromospheric Ca II 854.2 nm line allow us to describe in detail the emergence process across the solar atmosphere. We report here on three-dimensional (3D) semi-spherical bubble events, where instead of simple magnetic footpoints, we observe complex semi-circular feet straddling a few granules. Several phenomena occur simultaneously, namely, abnormal granulation, separation of opposite-polarity legs, and brightenings at chromospheric heights. However, the most characteristic signature in these events is the observation of a dark bubble in filtergrams taken in the wings of the Ca II 854.2 nm line. There is a clear coincidence between the emergence of horizontal magnetic field patches and the formation of the dark bubble. We can infer how the bubble rises through the solar atmosphere as we see it progressing from the wings to the core of Ca II 854.2 nm. In the photosphere, the magnetic bubble shows mean upward Doppler velocities of 2 km s{sup 1} and expands at a horizontal speed of 4 km s{sup 1}. In about 3.5 minutes it travels some 1100 km to reach the mid chromosphere, implying an average ascent speed of 5.2 km s{sup 1}. The maximum separation attained by the magnetic legs is 6.''6. From an inversion of the observed Stokes spectra with the SIR code, we find maximum photospheric field strengths of 480 G and inclinations of nearly 90 in the magnetic bubble interior, along with temperature deficits of up to 250 K at log ? = 2 and above. To aid the interpretation of the observations, we carry out 3D numerical simulations of the evolution of a horizontal, untwisted magnetic flux sheet injected in the convection zone, using the Bifrost code. The computational domain spans from the upper convection zone to the lower corona. In the modeled chromosphere, the rising flux sheet produces a large, cool, magnetized bubble. We compare this bubble with the observed ones and find excellent agreement, including similar field strengths and velocity signals in the photosphere and chromosphere, temperature deficits, ascent speeds, expansion velocities, and lifetimes.

  15. Minnesota Jobs to Come with Efficient Iron Plant

    Broader source: Energy.gov [DOE]

    New energy-efficient iron plant offers a ray of hope for workers after local mining company shuts down.

  16. Influence of Iron Redox Transformations on Plutonium Sorption to Sediments

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Influence of Iron Redox Transformations on Plutonium Sorption to Sediments Citation Details In-Document Search Title: Influence of Iron Redox Transformations on Plutonium Sorption to Sediments Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on

  17. Modification of the structural and magnetic properties of granular FePt films by seed layer conditioning

    SciTech Connect (OSTI)

    Wicht, S.; Neu, V.; Schultz, L.; Rellinghaus, B.; Mehta, V.; Jain, S.; Reiner, J.; Mosendz, O.; Hellwig, O.; Weller, D.

    2015-01-07

    The steadily increasing amount of digital information necessitates the availability of reliable high capacity magnetic data storage. Here, future hard disk drives with extended areal storage densities beyond 1.0 Tb/in{sup 2} are envisioned by using high anisotropy granular and chemically L1{sub 0}-ordered FePt (002) perpendicular media within a heat-assisted magnetic recording scheme. Perpendicular texturing of the [001] easy axes of the individual grains can be achieved by using MgO seed layers. It is therefore investigated, if and how an Ar{sup +} ion irradiation of the MgO seed layer prior to the deposition of the magnetic material influences the MgO surface properties and hereby the FePt [001] texture. Structural investigations reveal a flattening of the seed layer surface accompanied by a change in the morphology of the FePt grains. Moreover, the fraction of small second layer particles and the degree of coalescence of the primarily deposited FePt grains strongly increases. As for the magnetic performance, this results in a reduced coercivity along the magnetic easy axis (out of plane) and in enhanced hard axis (in-plane) remanence values. The irradiation induced changes in the magnetic properties of the granular FePt-C films are traced back to the accordingly modified atomic structure of the FePt-MgO interface region.

  18. Method for preparing hydrous iron oxide gels and spherules

    DOE Patents [OSTI]

    Collins, Jack L.; Lauf, Robert J.; Anderson, Kimberly K.

    2003-07-29

    The present invention is directed to methods for preparing hydrous iron oxide spherules, hydrous iron oxide gels such as gel slabs, films, capillary and electrophoresis gels, iron monohydrogen phosphate spherules, hydrous iron oxide spherules having suspendable particles homogeneously embedded within to form composite sorbents and catalysts, iron monohydrogen phosphate spherules having suspendable particles of at least one different sorbent homogeneously embedded within to form a composite sorbent, iron oxide spherules having suspendable particles homogeneously embedded within to form a composite of hydrous iron oxide fiber materials, iron oxide fiber materials, hydrous iron oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, iron oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, dielectric spherules of barium, strontium, and lead ferrites and mixtures thereof, and composite catalytic spherules of barium or strontium ferrite embedded with oxides of Mg, Zn, Pb, Ce and mixtures thereof. These variations of hydrous iron oxide spherules and gel forms prepared by the gel-sphere, internal gelation process offer more useful forms of inorganic ion exchangers, catalysts, getters, dielectrics, and ceramics.

  19. Use of high-granularity position sensing to correct response non-uniformities of CdZnTe detectors

    SciTech Connect (OSTI)

    Bolotnikov, A. E. Camarda, G. S.; Cui, Y.; De Geronimo, G.; Fried, J.; Hossain, A.; Mahler, G.; Maritato, M.; Marshall, M.; Roy, U.; Vernon, E.; Yang, G.; James, R. B.; Lee, K.; Petryk, M.

    2014-06-30

    CdZnTe (CZT) is a promising medium for room-temperature gamma-ray detectors. However, the low production yield of acceptable quality crystals hampers the use of CZT detectors for gamma-ray spectroscopy. Significant efforts have been directed towards improving quality of CZT crystals to make them generally available for radiation detectors. Another way to address this problem is to implement detector designs that would allow for more accurate and predictable correction of the charge loss associated with crystal defects. In this work, we demonstrate that high-granularity position-sensitive detectors can significantly improve the performance of CZT detectors fabricated from CZT crystals with wider acceptance boundaries, leading to an increase of their availability and expected decrease in cost.

  20. Water Clustering on Nanostructured Iron Oxide Films

    SciTech Connect (OSTI)

    Merte, L. R.; Bechstein, Ralf; Peng, Guowen; Rieboldt, Felix; Farberow, Carrie A.; Zeuthen, Helene; Knudsen, Jan; Laegsgaard, E.; Wendt, Stefen; Mavrikakis, Manos; Besenbacher, Fleming

    2014-06-30

    The adhesion of water to solid surfaces is characterized by the tendency to balance competing moleculemolecule and moleculesurface interactions. Hydroxyl groups form strong hydrogen bonds to water molecules and are known to substantially influence the wetting behaviour of oxide surfaces, but it is not well-understood how these hydroxyl groups and their distribution on a surface affect the molecular-scale structure at the interface. Here we report a study of water clustering on a moire-structured iron oxide thin film with a controlled density of hydroxyl groups. While large amorphous monolayer islands form on the are film, the hydroxylated iron oxide film acts as a hydrophilic nanotemplate, causing the formation of a regular array of ice-like hexameric nanoclusters. The formation of this ordered phase is localized at the nanometre scale; with increasing water coverage, ordered and amorphous water are found to coexist at adjacent hydroxylated and hydroxyl-free domains of the moire structure.

  1. Iron-sulfide redox flow batteries

    DOE Patents [OSTI]

    Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

    2013-12-17

    Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

  2. Lithium-aluminum-iron electrode composition

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1979-01-01

    A negative electrode composition is presented for use in a secondary electrochemical cell. The cell also includes an electrolyte with lithium ions such as a molten salt of alkali metal halides or alkaline earth metal halides that can be used in high-temperature cells. The cell's positive electrode contains a a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent in an alloy of aluminum-iron. Various binary and ternary intermetallic phases of lithium, aluminum and iron are formed. The lithium within the intermetallic phase of Al.sub.5 Fe.sub.2 exhibits increased activity over that of lithium within a lithium-aluminum alloy to provide an increased cell potential of up to about 0.25 volt.

  3. Thin Wall Cast Iron: Phase II

    SciTech Connect (OSTI)

    Doru M. Stefanescu

    2005-07-21

    The development of thin-wall technology allows the designers of energy consuming equipment to select the most appropriate material based on cost/material properties considerations, and not solely on density. The technology developed in this research project will permit the designers working for the automotive industry to make a better informed choice between competing materials and thin wall cast iron, thus decreasing the overall cost of the automobile.

  4. Spectroscopic absorption measurements of an iron plasma

    SciTech Connect (OSTI)

    Springer, P.T.; Fields, D.J.; Wilson, B.G.; Nash, J.K.; Goldstein, W.H.; Iglesias, C.A.; Rogers, F.J.; Swenson, J.K.; Chen, M.H.; Bar-Shalom, A.; Stewart, R.E. Nuclear Research Center Negev, P.O. Box 9001, Beer-Sheva 84190 )

    1992-12-28

    The first quantitative measurement of photoabsorption in the region determining the Rosseland and Planck mean opacities is obtained for a well-characterized, radiatively heated iron plasma using new techniques and instrumentation. The plasma density and temperature are simultaneously constrained with high accuracy, allowing unambiguous comparisons with opacity models used in modeling radiative transfer in equilibrium astrophysical and laboratory plasmas. The experimental Rosseland and Planck group means are constrained to an accuracy of 15%.

  5. Crystal Structure of Iron-dependent Halogenase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron-dependent Halogenase Over 4000 natural products contain halide atoms such as chlorine, bromine, or iodine.1 Halogenated natural products are medically valuable and include antibiotics (chlorotetracycline and vancomycin), antitumor agents (rebeccamycin and calichemycin), and human thyroid hormone (thyroxine).2 Halogenation is essential to the biological activity and chemical reactivity of such compounds, and often generates versatile molecular building blocks for synthetic organic chemists.

  6. Superconductivity at Dawn of the Iron Age

    ScienceCinema (OSTI)

    Tesanovic, Zlatko [Johns Hopkins University, Baltimore, Maryland, United States

    2010-09-01

    Superconductivity is a stunning quantum phenomenon and among the deepest paradigms in all of physics. From fundamental theories of the universe to strange goings-on in exotic materials to medical imaging and cell phones, its conceptual and practical dimensions span a reach as wide as anything in science. Twenty-odd years ago, the discovery of copper oxides ushered in a new era of high-temperature superconductivity, and the joyous exuberance that followed - with physicists throwing everything from fancy gauge theories to synchrotron radiation into its kitchen sink - only recently began to show any signs of waning. In the spring of 2008, as if on cue, a new family of iron pnictide high-temperature superconductors burst on the scene, hinting at an alternative route to room-temperature superconductivity and all of its momentous consequences. Fueled by genuine excitement - and a bit of hype - the iron-based superconductivity turned into a science blockbuster of 2009. I will present a pedagogical review of this new field, contrast the physics of iron- and copper-based systems, and speculate on the microscopic origins of the two types of high-temperature superconductivity.

  7. Seal welded cast iron nuclear waste container

    DOE Patents [OSTI]

    Filippi, Arthur M.; Sprecace, Richard P.

    1987-01-01

    This invention identifies methods and articles designed to circumvent metallurgical problems associated with hermetically closing an all cast iron nuclear waste package by welding. It involves welding nickel-carbon alloy inserts which are bonded to the mating plug and main body components of the package. The welding inserts might be bonded in place during casting of the package components. When the waste package closure weld is made, the most severe thermal effects of the process are restricted to the nickel-carbon insert material which is far better able to accommodate them than is cast iron. Use of nickel-carbon weld inserts should eliminate any need for pre-weld and post-weld heat treatments which are a problem to apply to nuclear waste packages. Although the waste package closure weld approach described results in a dissimilar metal combination, the relative surface area of nickel-to-iron, their electrochemical relationship, and the presence of graphite in both materials will act to prevent any galvanic corrosion problem.

  8. Iron phosphate compositions for containment of hazardous metal waste

    DOE Patents [OSTI]

    Day, D.E.

    1998-05-12

    An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P{sub 2}O{sub 5} and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe{sup 3+} provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided. 21 figs.

  9. Iron phosphate compositions for containment of hazardous metal waste

    DOE Patents [OSTI]

    Day, Delbert E.

    1998-01-01

    An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P.sub.2 O.sub.5 and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe.sup.3+ provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided.

  10. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  11. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  12. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  13. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Iron is the Key to Preserving Dinosaur Soft Tissue Print Thursday, 21 August 2014 10:43 Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were

  14. Importance of Iron Mineralogy to Aerosol Solubility: Potential Effects of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Source on Ocean Photosynthesis Importance of Iron Mineralogy to Aerosol Solubility: Potential Effects of Aerosol Source on Ocean Photosynthesis figure 1 Figure 1. Dust storm blowing glacial dusts from the Copper River Basin of southeast Alaska into the North Pacific Ocean, which depends on this and other external iron sources to support its biological communities. (Image: NASA MODIS satellite image, Nov. 1, 2006. http://earthobservatory.nasa.gov/IOTD/view.php?id=7094) Iron is one of

  15. Iron-titanium-mischmetal alloys for hydrogen storage

    DOE Patents [OSTI]

    Sandrock, Gary Dale

    1978-01-01

    A method for the preparation of an iron-titanium-mischmetal alloy which is used for the storage of hydrogen. The alloy is prepared by air-melting an iron charge in a clay-graphite crucible, adding titanium and deoxidizing with mischmetal. The resultant alloy contains less than about 0.1% oxygen and exhibits a capability for hydrogen sorption in less than half the time required by vacuum-melted, iron-titanium alloys.

  16. Reduction and carburization reactions in the iron bath smelter

    SciTech Connect (OSTI)

    Uemura, Kenichiro

    1993-01-01

    Slag-metal-coal reactions in the iron-bath smelter were analyzed based on a reaction model. It was concluded that the productivity and carbon content of the hot metal produced in a smelter can be controlled by adjusting the slag volume and iron oxide content in slag. Furthermore, iron oxide content is determined by the slag volume and the stirring intensity of the slag.

  17. Determination of ferrous and total iron in refractory spinels (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Determination of ferrous and total iron in refractory spinels Citation Details In-Document Search Title: Determination of ferrous and total iron in refractory spinels Accurate and precise determination of the redox state of iron (Fe) in spinels presents a significant challenge due to their refractory nature. The resultant extreme conditions needed to obtain complete dissolution generally oxidize some of the Fe(II) initially present and thus prevent the use of

  18. COLLOQUIUM: How Trenton Iron and Steel Innovations Reshaped America |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab April 9, 2014, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: How Trenton Iron and Steel Innovations Reshaped America Mr. Clifford Zink Independent Historian Iron and steel innovations in Trenton helped transform modern life with new methods of transportation, construction, and communications. Peter Cooper established his Trenton Iron Company on the Delaware River in 1847, and rolled America's first I-beams in the early 1850s. Cooper then established the

  19. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  20. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  1. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  2. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the Key to Preserving Dinosaur Soft Tissue Print Researchers studying organic material from dinosaur bones have been able to show that the organic material in the samples contained original soft tissue material from Mesozoic dinosaurs. The x-ray techniques at the ALS were key to showing a possible mechanism for this unexpected preservation-iron nanoparticles associated with dinosaur blood vessels were identified at the ALS. Researchers hypothesized that the iron had come from dinosaurs'

  3. Bandwidth Study U.S. Iron and Steel Manufacturing | Department...

    Broader source: Energy.gov (indexed) [DOE]

    This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. iron and steel manufacturing. The study relies on multiple sources to estimate ...

  4. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Evidence for a Weak Iron Core at Earth's Center Print Wednesday, 30 April 2014 00:00 Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron

  5. Big Iron for Big Data: An Unnatural Alliance?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Big Iron for Big Data: An Unnatural Alliance? Steve Plimpton Sandia National Labs Salishan Conference on High-Speed Computing April 2012 Big data analytics (BD) versus scientific...

  6. Low Resistivity Contact to Iron-Pnicitide Superconductors - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Advanced Materials Find More Like This Return to Search Low Resistivity Contact to Iron-Pnicitide Superconductors Ames Laboratory Contact AMES About This Technology...

  7. Low Resistivity Contact to Iron-Pnicitide Superconductors - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Resistivity Contact to Iron-Pnicitide Superconductors Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Superconductors are materials which carry...

  8. Iron active electrode and method of making same

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Seidel, Joseph (Pittsburgh, PA); Pantier, Earl A. (Verona, PA)

    1982-10-26

    An iron active electrode and method of preparing same in which iron sulfate is calcined in an oxidizing atmosphere at a temperature in the range of from about 600.degree. C. to about 850.degree. C. for a time sufficient to produce an iron oxide with a trace amount of sulfate. The calcined material is loaded into an electrically conductive support and then heated in a reducing atmosphere at an elevated temperature to produce activated iron having a trace amount of sulfide which is formed into an electrode plate.

  9. Iron County, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Climate Zone Number 7 Climate Zone Subtype A. Places in Iron County, Wisconsin Anderson, Wisconsin Carey, Wisconsin Gurney, Wisconsin Hurley, Wisconsin Kimball, Wisconsin...

  10. Metal regeneration of iron chelates in nitric oxide scrubbing

    DOE Patents [OSTI]

    Chang, S.G.; Littlejohn, D.; Shi, Y.

    1997-08-19

    The present invention relates to a process of using metal particles to reduce NO to NH{sub 3}. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: (a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20 and 90 C to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution. 34 figs.

  11. Pressure-Induced Hydrogen Bond Symmetrization in Iron Oxyhydroxide...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Pressure-Induced Hydrogen Bond Symmetrization in Iron Oxyhydroxide ... Publication Date: 2014-07-21 OSTI Identifier: 1123936 Resource Type: Journal Article ...

  12. Metal regeneration of iron chelates in nitric oxide scrubbing

    DOE Patents [OSTI]

    Chang, Shih-Ger; Littlejohn, David; Shi, Yao

    1997-08-19

    The present invention relates to a process of using metal particles to reduce NO to NH.sub.3. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20.degree. and 90.degree. C. to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution.

  13. Iron is the Key to Preserving Dinosaur Soft Tissue

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    occurring mechanism for stabilization of soft tissues has implications beyond paleontology. If iron-mediated reactions are part of a continuum from those that facilitate life...

  14. Recoil-free fractions of iron in aluminous bridgmanite fromtemperatur...

    Office of Scientific and Technical Information (OSTI)

    from temperature-dependent Mssbauer spectra Citation Details In-Document Search Title: Recoil-free fractions of iron in aluminous bridgmanite from temperature-dependent ...

  15. Microstructural Modification of a Cast Iron by Magnetic Field Processing

    SciTech Connect (OSTI)

    Kenik, Edward A [ORNL; Ludtka, Gail Mackiewicz- [ORNL; Ludtka, Gerard Michael [ORNL; Wilgen, John B [ORNL; Kisner, Roger A [ORNL

    2010-01-01

    The current study deals with the microstructural modification of a nodular cast iron during solidification under the influence of high magnetic fields (up to 18 tesla).

  16. Correlation effects in the iron pnictides (Journal Article) ...

    Office of Scientific and Technical Information (OSTI)

    One of the central questions about the iron pnictides concerns the extent to which their electrons are strongly correlated. Here we address this issue through the phenomenology of ...

  17. Melting of clinopyroxene + magnesite in iron-bearing planetary...

    Office of Scientific and Technical Information (OSTI)

    Melting of clinopyroxene + magnesite in iron-bearing planetary mantles and implications for the Earth and Mars Citation Details In-Document Search Title: Melting of clinopyroxene + ...

  18. Mountain Iron, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Mountain Iron, Minnesota: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 47.5324267, -92.623515 Show Map Loading map... "minzoom":false,"mappi...

  19. Iron-Air Rechargeable Battery: A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage

    SciTech Connect (OSTI)

    2010-10-01

    GRIDS Project: USC is developing an iron-air rechargeable battery for large-scale energy storage that could help integrate renewable energy sources into the electric grid. Iron-air batteries have the potential to store large amounts of energy at low costiron is inexpensive and abundant, while oxygen is freely obtained from the air we breathe. However, current iron-air battery technologies have suffered from low efficiency and short life spans. USC is working to dramatically increase the efficiency of the battery by placing chemical additives on the batterys iron-based electrode and restructuring the catalysts at the molecular level on the batterys air-based electrode. This can help the battery resist degradation and increase life span. The goal of the project is to develop a prototype iron-air battery at significantly cost lower than todays best commercial batteries.

  20. Suspension Hydrogen Reduction of Iron Oxide Concentrates

    SciTech Connect (OSTI)

    H.Y. Sohn

    2008-03-31

    The objective of the project is to develop a new ironmaking technology based on hydrogen and fine iron oxide concentrates in a suspension reduction process. The ultimate objective of the new technology is to replace the blast furnace and to drastically reduce CO2 emissions in the steel industry. The goals of this phase of development are; the performance of detailed material and energy balances, thermochemical and equilibrium calculations for sulfur and phosphorus impurities, the determination of the complete kinetics of hydrogen reduction and bench-scale testing of the suspension reduction process using a large laboratory flash reactor.

  1. Enhancing the Performance of the Rechargeable Iron Electrode in Alkaline Batteries with Bismuth Oxide and Iron Sulfide Additives

    SciTech Connect (OSTI)

    Manohar, AK; Yang, CG; Malkhandi, S; Prakash, GKS; Narayanan, SR

    2013-09-07

    Iron-based alkaline rechargeable batteries have the potential of meeting the needs of large-scale electrical energy storage because of their low-cost, robustness and eco-friendliness. However, the widespread commercial deployment of iron-based batteries has been limited by the low charging efficiency and the poor discharge rate capability of the iron electrode. In this study, we have demonstrated iron electrodes containing bismuth oxide and iron sulfide with a charging efficiency of 92% and capable of being discharged at the 3C rate. Such a high value of charging efficiency combined with the ability to discharge at high rates is being reported for the first time. The bismuth oxide additive led to the in situ formation of elemental bismuth and a consequent increase in the overpotential for the hydrogen evolution reaction leading to an increase in the charging efficiency. We observed that the sulfide ions added to the electrolyte and iron sulfide added to the electrode mitigated-electrode passivation and allowed for continuous discharge at high rates. At the 3C discharge rate, a utilization of 0.2 Ah/g was achieved. The performance level of the rechargeable iron electrode demonstrated here is attractive for designing economically-viable large-scale energy storage systems based on alkaline nickel-iron and iron-air batteries. (C) 2013 The Electrochemical Society. All rights reserved.

  2. A study in three-dimensional chaotic dynamics: Granular flow and transport in a bi-axial spherical tumbler

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Christov, Ivan C.; Lueptow, Richard M.; Ottino, Julio M.; Sturman, Rob

    2014-05-22

    We study three-dimensional (3D) chaotic dynamics through an analysis of transport in a granular flow in a half-full spherical tumbler rotated sequentially about two orthogonal axes (a bi-axial “blinking” tumbler). The flow is essentially quasi-two-dimensional in any vertical slice of the sphere during rotation about a single axis, and we provide an explicit exact solution to the model in this case. Hence, the cross-sectional flow can be represented by a twist map, allowing us to express the 3D flow as a linked twist map (LTM). We prove that if the rates of rotation about each axis are equal, then (inmore » the absence of stochasticity) particle trajectories are restricted to two-dimensional (2D) surfaces consisting of a portion of a hemispherical shell closed by a “cap''; if the rotation rates are unequal, then particles can leave the surface they start on and traverse a volume of the tumbler. The period-one structures of the governing LTM are examined in detail: analytical expressions are provided for the location of period-one curves, their extent into the bulk of the granular material, and their dependence on the protocol parameters (rates and durations of rotations). Exploiting the restriction of trajectories to 2D surfaces in the case of equal rotation rates about the axes, a method is proposed for identifying and constructing 3D Kolmogorov--Arnold--Moser (KAM) tubes around the normally elliptic period-one curves. The invariant manifold structure arising from the normally hyperbolic period-one curves is also examined. When the motion is restricted to 2D surfaces, the structure of manifolds of the hyperbolic points in the bulk differs from that corresponding to hyperbolic points in the flowing layer. Each is reminiscent of a template provided by a non-integrable perturbation to a Hamiltonian system, though the governing LTM is not. This highlights the novel 3D chaotic behaviors observed in this model dynamical system.« less

  3. A study in three-dimensional chaotic dynamics: Granular flow and transport in a bi-axial spherical tumbler

    SciTech Connect (OSTI)

    Christov, Ivan C.; Lueptow, Richard M.; Ottino, Julio M.; Sturman, Rob

    2014-05-22

    We study three-dimensional (3D) chaotic dynamics through an analysis of transport in a granular flow in a half-full spherical tumbler rotated sequentially about two orthogonal axes (a bi-axial blinking tumbler). The flow is essentially quasi-two-dimensional in any vertical slice of the sphere during rotation about a single axis, and we provide an explicit exact solution to the model in this case. Hence, the cross-sectional flow can be represented by a twist map, allowing us to express the 3D flow as a linked twist map (LTM). We prove that if the rates of rotation about each axis are equal, then (in the absence of stochasticity) particle trajectories are restricted to two-dimensional (2D) surfaces consisting of a portion of a hemispherical shell closed by a cap''; if the rotation rates are unequal, then particles can leave the surface they start on and traverse a volume of the tumbler. The period-one structures of the governing LTM are examined in detail: analytical expressions are provided for the location of period-one curves, their extent into the bulk of the granular material, and their dependence on the protocol parameters (rates and durations of rotations). Exploiting the restriction of trajectories to 2D surfaces in the case of equal rotation rates about the axes, a method is proposed for identifying and constructing 3D Kolmogorov--Arnold--Moser (KAM) tubes around the normally elliptic period-one curves. The invariant manifold structure arising from the normally hyperbolic period-one curves is also examined. When the motion is restricted to 2D surfaces, the structure of manifolds of the hyperbolic points in the bulk differs from that corresponding to hyperbolic points in the flowing layer. Each is reminiscent of a template provided by a non-integrable perturbation to a Hamiltonian system, though the governing LTM is not. This highlights the novel 3D chaotic behaviors observed in this model dynamical system.

  4. Positive field-cooled dc susceptibility in granular superconductors interpreted through numerical simulations on a simple Josephson-junction-array model

    SciTech Connect (OSTI)

    Auletta, C.; Raiconi, G.; De Luca, R.; Pace, S.

    1995-05-01

    We have performed numerical simulations of a field-cooled dc susceptibility experiment carried out for granular superconductors by modeling these systems with a simple Josephson-junction array proposed by the authors. By this analysis the temperature dependence of the positive field-cooled susceptibility at very low values of the applied magnetic field, observed by Braunisch {ital et} {ital al}. [Phys. Rev. Lett. 68, 1908 (1992)] for some ceramic superonductors, has been reproduced and interpreted.

  5. Investigation of Iron Aluminide Weld Overlays

    SciTech Connect (OSTI)

    Banovic, S.W.; DuPont, J.B.; Levin, B.F.; Marder, A.R.

    1999-08-02

    Conventional fossil fired boilers have been retrofitted with low NO(sub)x burners in order for the power plants to comply with new clean air regulations. Due to the operating characteristics of these burners, boiler tube sulfidation corrosion typically has been enhanced resulting in premature tube failure. To protect the existing panels from accelerated attack, weld overlay coatings are typically being applied. By depositing an alloy that offers better corrosion resistance than the underlying tube material, the wastage rates can be reduced. While Ni-based and stainless steel compositions are presently providing protection, they are expensive and susceptible to failure via corrosion-fatigue due to microsegregation upon solidification. Another material system presently under consideration for use as a coating in the oxidation/sulfidation environments is iron-aluminum. These alloys are relatively inexpensive, exhibit little microsegregation, and show excellent corrosion resistance. However, their use is limited due to weldability issues and their lack of corrosion characterization in simulated low NO(sub)x gas compositions. Therefore a program was initiated in 1996 to evaluate the use of iron-aluminum weld overlay coatings for erosion/corrosion protection of boiler tubes in fossil fired boilers with low NO(sub)x burners. Investigated properties included weldability, corrosion behavior, erosion resistance, and erosion-corrosion performance.

  6. Next Generation Metallic Iron Nodule Technology in Electric Furnace Steelmaking

    SciTech Connect (OSTI)

    2007-09-01

    This factsheet describes a research project whose objective is to investigate reducing processing temperature, controlling the gas temperature and gas atmosphere over metallized iron nodules, and effectively using sub-bituminous coal as a reductant for producing high quality metallized iron nodules at low cost.

  7. Next Generation Metallic Iron Nodule Technology in Electric Furnace Steelmaking

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose objective is to investigate reducing processing temperature, controlling the gas temperature and gas atmosphere over metalized iron nodules, and effectively using sub-bituminous coal as a reductant for producing high quality metalized iron nodules at low cost.

  8. Electrochemical Deposition of Iron Nanoneedles on Titanium Oxide Nanotubes

    SciTech Connect (OSTI)

    Gan Y. X.; Zhang L.; Gan B.J.

    2011-10-01

    Iron as a catalyst has wide applications for hydrogen generation from ammonia, photodecomposition of organics, and carbon nanotube growth. Tuning the size and shape of iron is meaningful for improving the catalysis efficiency. It is the objective of this work to prepare nanostructured iron with high surface area via electrochemical deposition. Iron nanoneedles were successfully electrodeposited on Ti supported TiO2 nanotube arrays in a chlorine-based electrolyte containing 0.15 M FeCl2 {center_dot} 4H2O and 2.0 M HCl. Transmission electron microscopic analysis reveals that the average length of the nanoneedles is about 200 nm and the thickness is about 10 nm. It has been found that a high overpotential at the cathode made of Ti/TiO2 nanotube arrays is necessary for the formation of the nanoneedles. Cyclic voltammetry test indicates that the electrodeposition of iron nanoneedles is a concentration-limited process.

  9. System and method for producing metallic iron nodules

    DOE Patents [OSTI]

    Bleifuss, Rodney L.; Englund, David J.; Iwasaki, Iwao; Lindgren, Andrew J.; Kiesel, Richard F.

    2011-09-20

    A method for producing metallic iron nodules by assembling a shielding entry system to introduce coarse carbonaceous material greater than 6 mesh in to the furnace atmosphere at location(s) where the temperature of the furnace atmosphere adjacent at least partially reduced reducible iron bearing material is between about 2200 and 2650.degree. F. (1200 and 1450.degree. C.), the shielding entry system adapted to inhibit emission of infrared radiation from the furnace atmosphere and seal the furnace atmosphere from exterior atmosphere while introducing coarse carbonaceous material greater than 6 mesh into the furnace to be distributed over the at least partially reduced reducible iron bearing material, and heating the covered at least partially reduced reducible iron bearing material in a fusion atmosphere to assist in fusion and inhibit reoxidation of the reduced material during fusion to assist in fusion and inhibit reoxidation of the reduced material in forming metallic iron nodules.

  10. Characterization and Correlation of Particle-Level Interactions to the Macroscopic Rheology of Powders, Granular Slurries, and Colloidal Suspensions

    SciTech Connect (OSTI)

    Poloski, Adam P.; Daniel, Richard C.; Rector, David R.; Bredt, Paul R.; Buck, Edgar C.; Berg, John C.; Saez, Avelino E.

    2006-09-29

    Hanford TRU tank sludges are complex mixtures of undissolved minerals and salt solids in an aqueous phase of high ionic strength. They show complex rheological behavior resulting from interactions at the macroscopic level, such as interparticle friction between grains in the coarse fraction, as well as from interactions at the nano-scale level, such as the agglomeration of colloidal particles. An understanding of how phenomena such as interparticle friction and aggregate stability under shear will allow better control of Hanford TRU tank sludges being processed for disposal. The project described in this report had two objectives. The first was to understand the physical properties and behavior of the Hanford transuranic (TRU) tank sludges under conditions that might exist during retrieval, treatment, packaging, and transportation for disposal at the Waste Isolation Pilot Plant (WIPP). The second objective was to develop a fundamental understanding of sludge physical properties by correlating the macroscopic behavior with interactions occurring at the particle/colloidal scale. These objectives were accomplished by: 1) developing continuum models for coarse granular slurries and 2) studying the behavior of colloidal agglomerates under shear and under irradiation.

  11. Effects of temperature and acidic pre-treatment on Fenton-driven oxidation of MTBE-spent granular activated carbon

    SciTech Connect (OSTI)

    Kan, E.; Huling, S.G.

    2009-03-01

    The effects of temperature and acidic pretreatment on Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC, derived from bituminous coal) were investigated. Limiting factors in MTBE removal in GAC include the heterogeneous distribution of amended Fe, and slow intraparticle diffusive transport of MTBE and hydrogen peroxide (H{sub 2}O{sub 2}) into the 'reactive zone'. Acid pretreatment of GAC before Fe amendment altered the surface chemistry of the GAC, lowered the pH point of zero charge, and resulted in greater penetration and more uniform distribution of Fe in GAC. This led to a condition where Fe, MTBE, and H{sub 2}O{sub 2} coexisted over a larger volume of the GAC contributing to greater MTBE oxidation and removal. H{sub 2}O{sub 2} reaction and MTBE removal in GAC increased with temperature. Modeling H{sub 2}O{sub 2} transport and reaction in GAC indicated that H{sub 2}O{sub 2} penetration was inversely proportional with temperature and tortuosity, and occurred over a larger fraction of the total volume of small GAC particles (0.3 mm diameter) relative to large particles (1.2 mm diameter). Acidic pretreatment of GAC, Fe-amendment, elevated reaction temperature, and use of small GAC particles are operational parameters that improve Fenton-driven oxidation of MTBE in GAC. 29 refs., 6 figs., 1 tab.

  12. System and method for producing metallic iron

    DOE Patents [OSTI]

    Bleifuss, Rodney L.; Englund, David J.; Iwasaki, Iwao; Fosnacht, Donald R.; Brandon, Mark M.; True, Bradford G.

    2012-01-17

    A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

  13. System and method for producing metallic iron

    DOE Patents [OSTI]

    Bleifuss, Rodney L; Englund, David J; Iwasaki, Iwao; Fosnacht, Donald R; Brandon, Mark M; True, Bradford G

    2013-09-17

    A hearth furnace for producing metallic iron material has a furnace housing having a drying/preheat zone, a conversion zone, a fusion zone, and optionally a cooling zone, the conversion zone is between the drying/preheat zone and the fusion zone. A moving hearth is positioned within the furnace housing. A hood or separation barrier within at least a portion of the conversion zone, fusion zone or both separates the fusion zone into an upper region and a lower region with the lower region adjacent the hearth and the upper region adjacent the lower region and spaced from the hearth. An injector introduces a gaseous reductant into the lower region adjacent the hearth. A combustion region may be formed above the hood or separation barrier.

  14. Multiple hearth furnace for reducing iron oxide

    DOE Patents [OSTI]

    Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

    2012-03-13

    A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).

  15. Predict carbonation rate on iron catalyst

    SciTech Connect (OSTI)

    Dry, M.E.

    1980-02-01

    On solely thermodynamic grounds, the main hydrocarbon product of the Fischer-Tropsch reaction should be methane; in practice, however, carbon is frequently produced as well and deposited on the iron catalyst, fouling the active surface sites. South African Coal, Oil and Gas Corp., Ltd.'s experiments with a fluidized Fischer-Tropsch catalyst bed demonstrate that the rate of carbon deposition is strongly dependent on the hydrogen partial pressure in the reactor, much less dependent on the CO pressure, and not affected at all by the pressure of CO/sub 2/. A suggested reaction scheme for the Fischer-Tropsch synthesis explains these observations and provides a basis for a correlation useful in predicting carbon-deposition rates.

  16. Rhombohedral magnetostriction in dilute iron (Co) alloys

    SciTech Connect (OSTI)

    Jones, Nicholas J. Wun-Fogle, Marilyn; Restorff, J. B.; Petculescu, Gabriela; Clark, Arthur E.; Hathaway, Kristl B.; Schlagel, Deborah; Lograsso, Thomas A.

    2015-05-07

    Iron is a well-utilized material in structural and magnetic applications. This does not mean, however, that it is well understood, especially in the field of magnetostriction. In particular, the rhombohedral magnetostriction of iron, λ{sub 111}, is anomalous in two respects: it is negative in sign, in disagreement with the prediction of first principles theory, and its magnitude decreases with increasing temperature much too rapidly to be explained by a power law dependence on magnetization. These behaviors could arise from the location of the Fermi level, which leaves a small region of the majority 3d t{sub 2g} states unfilled, possibly favoring small internal displacements that split these states. If this view is correct, adding small amounts of Co to Fe fills some of these states, and the value of λ{sub 111} should increase toward a positive value, as predicted for perfect bcc Fe. We have measured the magnetostriction coefficients (λ{sub 111} and λ{sub 100}) of pure Fe, Fe{sub 97}Co{sub 3}, and Fe{sub 94}Co{sub 6} single crystals from 77 K to 450 K. Resonant ultrasound spectroscopy has been used to check for anomalies in the associated elastic constants, c{sub 44} and c′. The additional electrons provided by the cobalt atoms indeed produced positive contributions to both magnetostriction constants, λ{sub 111} and λ{sub 100}, exhibiting an increase of 2.8 × 10{sup −6} per at. % Co for λ{sub 111} and 3.8 × 10{sup −6} per at. % Co for λ{sub 100}.

  17. Theoretical Investigation of Hydrogen Adsorption and Dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method

    SciTech Connect (OSTI)

    Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

    2012-06-01

    We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of FischerTropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

  18. Iron aluminide alloy coatings and joints, and methods of forming

    DOE Patents [OSTI]

    Wright, Richard N. (Idaho Falls, ID); Wright, Julie K. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID)

    1994-01-01

    A method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600.degree. C. to less than the melting point of the lower melting point body; d) applying pressure on the juxtaposed surfaces; and e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

  19. TECHNOLOGY DEVELOPMENT FOR IRON AND COBALT FISCHER-TROPSCH CATALYSTS

    SciTech Connect (OSTI)

    Burtron H. Davis

    1999-04-30

    The impact of activation procedure on the phase composition of precipitated iron Fischer-Tropsch (FT) catalysts has been studied. Catalyst samples taken during activation and FT synthesis have been characterized by Moessbauer spectroscopy. Formation of iron carbide is necessary for high FT activity. Hydrogen activation of precipitated iron catalysts results in reduction to predominantly metallic iron and Fe{sub 3}O{sub 4}. Metallic iron is not stable under FT 3 4 conditions and is rapidly converted to {epsilon}{prime}-Fe{sub 2.2}C. Activation with carbon monoxide or syngas 2.2 with low hydrogen partial pressure reduces catalysts to {chi}-Fe{sub 5}C{sub 2} and a small amount of 5 2 superparamagnetic carbide. Exposure to FT conditions partially oxidizes iron carbide to Fe{sub 3}O{sub 4}; however, catalysts promoted with potassium or potassium and copper maintain a constant carbide content and activity after the initial oxidation. An unpromoted iron catalyst which was activated with carbon monoxide to produce 94% {chi}-Fe{sub 5}C{sub 2}, deactivated rapidly as the carbide was oxidized to Fe{sub 3}O{sub 4}. No difference in activity, stability or deactivation rate was found for {chi}-Fe{sub 5}C{sub 2} and {epsilon}{prime}-Fe{sub 2.2}C.

  20. Iron aluminide alloy coatings and joints, and methods of forming

    DOE Patents [OSTI]

    Wright, R.N.; Wright, J.K.; Moore, G.A.

    1994-09-27

    Disclosed is a method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: (a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; (b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; (c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600 C to less than the melting point of the lower melting point body; (d) applying pressure on the juxtaposed surfaces; and (e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

  1. Spall behavior of cast iron with varying microstructures

    SciTech Connect (OSTI)

    Plume, Gifford; Rousseau, Carl-Ernst, E-mail: rousseau@uri.edu [Mechanical Engineering, University of Rhode Island, 92 Upper College Rd., Kingston, Rhode Island 02881 (United States)

    2014-07-21

    The spall strength of cast iron with varying microstructures has been investigated using plate impact at moderate speed. Stress history measurements were made with manganin stress gauges embedded between the back face of the specimen and a low impedance polycarbonate backing. Five separate cast irons were tested. Four of these consisted of gray cast iron with graphite in flake form, with three classified as Type VII A2 and the fourth containing a bimodal distribution of Types VII A4 and VII D8. The fifth casting consisted of ductile cast iron with graphite in nodular form, classified as Type I, size class 5. The spall strength for the Type VII A2 gray cast irons varied between 40 and 370?MPa, and that of the additional gray cast iron, between 410 and 490?MPa. The spall strength of the ductile cast iron fell within the range of 0.941.2?GPa. It is shown that the spall strength is linked to the damage level at the spall plane, where an increased level of tensile stress is required to generate higher levels of damage. Post mortem analysis was performed on the recovered samples, revealing the graphite phase to be the primary factor governing the spall fracture of cast irons, where crack nucleation is directly correlated to the debonding of graphite from the metal matrix. The average length of graphite found within a casting is linked to the material's strength, where strength increases as a function of decreasing length. The morphology and mean free path of graphite precipitates further govern the subsequent coalescence of initiated cracks to form a complete fracture plane. In cases where graphite spacing is large, increased energy level is required to complete the fracture process. A secondary factor governing the spall fracture of cast irons has also been linked to the microstructure of the metal matrix, with pearlite yielding higher spall strengths than free ferrite.

  2. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron grains in the Earth's inner core comes from x-ray spectroscopy and diffraction

  3. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron grains in the Earth's inner core comes from x-ray spectroscopy and diffraction

  4. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron grains in the Earth's inner core comes from x-ray spectroscopy and diffraction

  5. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron grains in the Earth's inner core comes from x-ray spectroscopy and diffraction

  6. How Trenton Iron and Steel Innovations Reshaped America Clifford Zink

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trenton Iron and Steel Innovations Reshaped America Clifford Zink Independent Historian Wednesday, April 9, 2014 - 4:15PM MBG AUDITORIUM Refreshments at 4:00PM The PrinceTon Plasma Physics laboraTory is a U.s. DeParTmenT of energy faciliTy Iron and steel innovations in Trenton helped transform modern life with new methods of transportation, construction, and communications. Peter Cooper established his Trenton Iron Company on the Delaware River in 1847, and rolled America's first I-beams in the

  7. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle The Iron Spin Transition in the Earth's Lower Mantle Print Wednesday, 30 April 2008 00:00 It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the

  8. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron grains in the Earth's inner core comes from x-ray spectroscopy and diffraction

  9. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that transmits waves more efficiently in one direction than the other. Recent evidence for this "texturing" of iron grains in the Earth's inner core comes from x-ray spectroscopy and diffraction

  10. Probing iron at Super-Earth core conditions

    SciTech Connect (OSTI)

    Amadou, N.; Brambrink, E.; Vinci, T.; Benuzzi-Mounaix, A.; Huser, G.; Brygoo, S.; Morard, G.; Guyot, F.; Resseguier, T. de; Mazevet, S.; Miyanishi, K.; Ozaki, N.; Kodama, R.; Henry, O.; Raffestin, D.; Boehly, T.; and others

    2015-02-15

    In this paper, we report on the quasi-isentropic compression of an iron sample using ramp shaped laser irradiation. This technique allows us to quasi-isentropically compress iron up to 700 GPa and 8500 K. To our knowledge, these data are the highest pressures reached on iron in off-Hugoniot conditions and the closest to the thermodynamic states thought to exist in Earth-like planetary cores. The experiment was performed on the Ligne d'Intégration laser facility at CESTA, Bordeaux, France.

  11. Synchrotron infrared reflectivity measurements of iron at high pressures

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Synchrotron infrared reflectivity measurements of iron at high pressures Citation Details In-Document Search Title: Synchrotron infrared reflectivity measurements of iron at high pressures The infrared reflectance of iron was studied using high-pressure synchrotron radiation methods up to 50 GPa at room temperature in a diamond anvil cell of 1000-8000 cm{sup -1} (1.25-10 {mu}m). The magnitude of the reflectivity shows a weak pressure

  12. Iron-carbon compacts and process for making them

    DOE Patents [OSTI]

    Sheinberg, Haskell

    2000-01-01

    The present invention includes iron-carbon compacts and a process for making them. The process includes preparing a slurry comprising iron powder, furfuryl alcohol, and a polymerization catalyst for initiating the polymerization of the furfuryl alcohol into a resin, and heating the slurry to convert the alcohol into the resin. The resulting mixture is pressed into a green body and heated to form the iron-carbon compact. The compact can be used as, or machined into, a magnetic flux concentrator for an induction heating apparatus.

  13. Cast B2-phase iron-aluminum alloys with improved fluidity

    DOE Patents [OSTI]

    Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

    2002-01-01

    Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

  14. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    going from pole to pole than along the equatorial plane-why? One theory is that the grains of iron that make up most of the solid inner core could be aligned in a way that...

  15. DOE - Office of Legacy Management -- Rogers Iron Works Co - MO...

    Office of Legacy Management (LM)

    of Ohio Analytical Data Sheet 9908; August 2, 1956 MO.10-2 - MemorandumChecklist, Williams to File; Subject: Rogers Iron; June 1, 1990 MO.10-3 - DOE Memorandum; Williams to the...

  16. DOE - Office of Legacy Management -- Armco-Rustless Iron and...

    Office of Legacy Management (LM)

    from Further Consideration Under FUSRAP; November 17, 1987 MD.03-2 - AEC Memorandum; Harris to Wolf; Subject: Rolling of Billets at Armco-Rustless Iron & Steel, Baltimore, MD;...

  17. Modernization of the iron making plant at SOLLAC FOS

    SciTech Connect (OSTI)

    Crayelynghe, M. van; Dufour, A.; Soland, J.; Feret, J.; Lebonvallet, J.

    1995-12-01

    When the blast furnaces at SOLLAC/FOS were relined, the objective being to ensure a worklife of 15 years, it was decided that the iron making plant would be modernized at the same time: the coking plant has been overhauled and renovated and its coking time increased to ensure a worklife of at least 34 years. The surface area of the sinter strand was increased from 400 to 520 m{sup 2}, the burden preparation circuit were simplified, and pig iron production capacity increased from 4.2 to 4.5 million metric tons per year. Coal injection was developed so as to obtain 170 kg/t of pig iron, an expert system was added to ensure more efficient blast furnace operation, and new measures have been carried out for environmental protection. Since these heavy investments have been completed, SOLLAC/FOS is a high-performance iron making plant, allowing it to face new challenges in the future.

  18. Verification of Steelmaking Slags Iron Content Final Technical Progress Report

    SciTech Connect (OSTI)

    J.Y. Hwang

    2006-10-04

    The steel industry in the United States generates about 30 million tons of by-products each year, including 6 million tons of desulfurization and BOF/BOP slag. The recycling of BF (blast furnace) slag has made significant progress in past years with much of the material being utilized as construction aggregate and in cementitious applications. However, the recycling of desulfurization and BOF/BOP slags still faces many technical, economic, and environmental challenges. Previous efforts have focused on in-plant recycling of the by-products, achieving only limited success. As a result, large amounts of by-products of various qualities have been stockpiled at steel mills or disposed into landfills. After more than 50 years of stockpiling and landfilling, available mill site space has diminished and environmental constraints have increased. The prospect of conventionally landfilling of the material is a high cost option, a waste of true national resources, and an eternal material liability issue. The research effort has demonstrated that major inroads have been made in establishing the viability of recycling and reuse of the steelmaking slags. The research identified key components in the slags, developed technologies to separate the iron units and produce marketable products from the separation processes. Three products are generated from the technology developed in this research, including a high grade iron product containing about 90%Fe, a medium grade iron product containing about 60% Fe, and a low grade iron product containing less than 10% Fe. The high grade iron product contains primarily metallic iron and can be marketed as a replacement of pig iron or DRI (Direct Reduced Iron) for steel mills. The medium grade iron product contains both iron oxide and metallic iron and can be utilized as a substitute for the iron ore in the blast furnace. The low grade iron product is rich in calcium, magnesium and iron oxides and silicates. It has a sufficient lime value and can be utilized for acid mine drainage treatment. Economic analysis from this research demonstrates that the results are favorable. The strong demand and the increase of price of the DRI and pig iron in recent years are particularly beneficial to the economics. The favorable economics has brought commercial interests. ICAN Global has obtained license agreement on the technology from Michigan Tech. This right was later transferred to the Westwood Land, Inc. A demonstration pilot plant is under construction to evaluate the technology. Steel industry will benefit from the new supply of the iron units once the commercial plants are constructed. Environmental benefits to the public and the steel industry will be tremendous. Not only the old piles of the slag will be removed, but also the federal responsible abandoned mines from the old mining activities can be remediated with the favorable product generated from the process. Cost can be reduced and there will be no lime required, which can avoid the release of carbon dioxide from lime production process.

  19. Iron speciation in minerals and glasses probed by M [subscript...

    Office of Scientific and Technical Information (OSTI)

    X-ray Raman scattering spectroscopy Citation Details In-Document Search Title: Iron speciation in minerals and glasses probed by M subscript 23 -edge X-ray Raman scattering ...

  20. Shewanella loihica sp. nov., isolated from iron-rich microbial...

    Office of Scientific and Technical Information (OSTI)

    loihica sp. nov., isolated from iron-rich microbial mats in the Pacific Ocean A novel marine bacterial strain, PV-4T, isolated from a microbial mat located at a hydrothermal vent...

  1. Origin of banded iron formations : oceanic crust leaching & self...

    Office of Scientific and Technical Information (OSTI)

    Subject: 58 GEOSCIENCES; IRON; LEACHING; OCEANIC CRUST; ORIGIN Word Cloud More Like This Full Text Journal Articles Find in Google Scholar Find in Google Scholar Search WorldCat ...

  2. Percolation Explains How Earth's Iron Core Formed | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... at high pressure (64 GPa) and temperature (3,300 K). a,b, The channel in a has been confirmed to be iron-rich material by element-sensitive nanoscale tomographic imaging; the ...

  3. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evidence for a Weak Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial...

  4. Evidence for a Weak Iron Core at Earth's Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory...

  5. Dopant Site Determination in Iron Oxide Nanoparticles Utilizing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dopant Site Determination in Iron Oxide Nanoparticles Utilizing X-ray Absorption Techniques Monday, September 9, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Dr....

  6. Probing high-energy spin fluctuations in iron pnictide superconductors...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spin fluctuations in iron pnictide superconductors and the metal-insulator transition in rare-earth nickelates by soft X-ray RIXS Wednesday, November 18, 2015 - 3:00pm...

  7. Sorption of Ferric Iron from Siderophore Complexes by Layer Type...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon sequestration as the global carbon dioxide concentration rises. In the marine environment, iron is typically found in subnanomolar total concentrations (0.02-1 nM), which...

  8. Korea Iron Steel Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Steel Co Ltd Jump to: navigation, search Name: Korea Iron & Steel Co Ltd Place: Changwon, South Gyeongsang, Korea (Republic) Zip: 641 370 Product: Korea-based manufacturer of steel...

  9. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, J.M.; Trowbridge, L.D.

    1999-03-23

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

  10. Method and system for producing metallic iron nuggets

    DOE Patents [OSTI]

    Iwasaki, Iwao; Kiesel, Richard F.; Englund, David J; Hendrickson, Dave

    2012-12-18

    A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

  11. Lithium Iron Phosphate Composites for Lithium Batteries (IN-11...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Iron Phosphate Composites for Lithium Batteries (IN-11-024) Low-Cost Phosphate ... that are highly functional when used in high-power and high-energy lithium batteries. ...

  12. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, James M. (Kingston, TN); Trowbridge, Lee D. (Oak Ridge, TN)

    1999-01-01

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag.

  13. Mesoscale Benchmark Demonstration Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert; Gao, Fei; Sun, Xin; Tonks, Michael; Biner, Bullent; Millet, Paul; Tikare, Veena; Radhakrishnan, Balasubramaniam; Andersson , David

    2012-04-11

    A study was conducted to evaluate the capabilities of different numerical methods used to represent microstructure behavior at the mesoscale for irradiated material using an idealized benchmark problem. The purpose of the mesoscale benchmark problem was to provide a common basis to assess several mesoscale methods with the objective of identifying the strengths and areas of improvement in the predictive modeling of microstructure evolution. In this work, mesoscale models (phase-field, Potts, and kinetic Monte Carlo) developed by PNNL, INL, SNL, and ORNL were used to calculate the evolution kinetics of intra-granular fission gas bubbles in UO2 fuel under post-irradiation thermal annealing conditions. The benchmark problem was constructed to include important microstructural evolution mechanisms on the kinetics of intra-granular fission gas bubble behavior such as the atomic diffusion of Xe atoms, U vacancies, and O vacancies, the effect of vacancy capture and emission from defects, and the elastic interaction of non-equilibrium gas bubbles. An idealized set of assumptions was imposed on the benchmark problem to simplify the mechanisms considered. The capability and numerical efficiency of different models are compared against selected experimental and simulation results. These comparisons find that the phase-field methods, by the nature of the free energy formulation, are able to represent a larger subset of the mechanisms influencing the intra-granular bubble growth and coarsening mechanisms in the idealized benchmark problem as compared to the Potts and kinetic Monte Carlo methods. It is recognized that the mesoscale benchmark problem as formulated does not specifically highlight the strengths of the discrete particle modeling used in the Potts and kinetic Monte Carlo methods. Future efforts are recommended to construct increasingly more complex mesoscale benchmark problems to further verify and validate the predictive capabilities of the mesoscale modeling methods used in this study.

  14. Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), January 2014 (MECS 2010)

    Energy Savers [EERE]

    3311, 3312), October 2012 (MECS 2006) | Department of Energy - Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006) Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006) PDF icon steel_footprint_2012.pdf More Documents & Publications MECS 2006 - Iron and Steel Iron and Steel (2010 MECS) MECS 2006 - Cement

    Iron and Steel (NAICS 3311, 3312) Process Energy Electricity and Steam Generation Losses Process Losses 49

  15. Nitrogen Atom Transfer From High Valent Iron Nitrides

    SciTech Connect (OSTI)

    Johnson, Michael D.; Smith, Jeremy M.

    2015-10-14

    This report describes the synthesis and reactions of high valent iron nitrides. Organonitrogen compounds such as aziridines are useful species for organic synthesis, but there are few efficient methods for their synthesis. Using iron nitrides to catalytically access these species may allow for their synthesis in an energy-and atom-efficient manner. We have developed a new ligand framework to achieve these goals as well as providing a method for inducing previously unknown reactivity.

  16. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Iron Catalysis in Oxidations by Ozone Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Ozone is used commercially for treatment of potable and non-potable water, and as an industrial oxidant. ISU and Ames Laboratory researchers have developed a method for using iron in ozone oxidation that significantly improves the speed of oxidation reactions. Description Ozone is recognized as potent and effective oxidizing agent, and has a

  17. Iron-based composition for magnetocaloric effect (MCE) applications and

    Office of Scientific and Technical Information (OSTI)

    method of making a single crystal (Patent) | SciTech Connect Patent: Iron-based composition for magnetocaloric effect (MCE) applications and method of making a single crystal Citation Details In-Document Search Title: Iron-based composition for magnetocaloric effect (MCE) applications and method of making a single crystal A method of making a single crystal comprises heating a material comprising magnetic anisotropy to a temperature T sufficient to form a melt of the material. A magnetic

  18. Progress in Understanding Iron Peak Elements in Young Supernova Remnants

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Progress in Understanding Iron Peak Elements in Young Supernova Remnants Citation Details In-Document Search Title: Progress in Understanding Iron Peak Elements in Young Supernova Remnants Authors: Eriksen, Kristoffer A. [1] ; Hughes, Jack [2] ; Fontes, Christopher J. [1] ; Colgan, James P. [1] ; Hungerford, Aimee L. [1] ; Fryer, Christopher L. [1] ; Zhang, Honglin [1] ; Badenes, Carles [3] ; Slane, Patrick [4] + Show Author Affiliations Los Alamos National

  19. Pressure-Induced Hydrogen Bond Symmetrization in Iron Oxyhydroxide (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Journal Article: Pressure-Induced Hydrogen Bond Symmetrization in Iron Oxyhydroxide Citation Details In-Document Search Title: Pressure-Induced Hydrogen Bond Symmetrization in Iron Oxyhydroxide Authors: Xu, Weiming ; Greenberg, Eran ; Rozenberg, Gregory Kh. ; Pasternak, Moshe P. ; Bykova, Elena ; Boffa-Ballaran, Tiziana ; Dubrovinsky, Leonid ; Prakapenka, Vitali ; Hanfland, Michael ; Vekilova, Olga Yu. ; Simak, Sergei I. ; Abrikosov, Igor A. [1] ; Link) [2] ;

  20. Controlled Phase and Tunable Magnetism in Ordered Iron Oxide Nanotube

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arrays Prepared by Atomic Layer Deposition | Argonne National Laboratory Controlled Phase and Tunable Magnetism in Ordered Iron Oxide Nanotube Arrays Prepared by Atomic Layer Deposition Title Controlled Phase and Tunable Magnetism in Ordered Iron Oxide Nanotube Arrays Prepared by Atomic Layer Deposition Publication Type Journal Article Year of Publication 2016 Authors Zhang, Y, Liu, M, Peng, B, Zhou, Z, Chen, X, Yang, S-M, Jiang, Z-D, Zhang, J, Ren, W, Ye, Z-G Journal Scientific Reports

  1. High-temperature fabricable nickel-iron aluminides

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN)

    1988-02-02

    Nickel-iron aluminides are described that are based on Ni.sub.3 Al, and have significant iron content, to which additions of hafnium, boron, carbon and cerium are made resulting in Ni.sub.3 Al base alloys that can be fabricated at higher temperatures than similar alloys previously developed. Further addition of molybdenum improves oxidation and cracking resistance. These alloys possess the advantages of ductility, hot fabricability, strength, and oxidation resistance.

  2. Interplay between interband coupling and ferromagnetism in iron pnictide superconductor/ferromagnet/iron pnictide superconductor junctions

    SciTech Connect (OSTI)

    Liu, S. Y.; Tao, Y. C.; Hu, J. G.

    2014-08-28

    An extended eight-component Bogoliubov-de Gennes equation is applied to study the Josephson effect between iron-based superconductors (SCs) with s{sub }-wave pairing symmetry, separated by an ferromagnet (FM). The feature of damped oscillations of critical Josephson current as a function of FM thickness, the split of the peaks induced by the interband coupling is much different from that for the junction with the s{sub }-wave SCs replaced by s{sub ++}-wave ones. In particular, a 0?? transition as a function of interband coupling strength ? is found to always exhibit with the corresponding dip shifting toward the larger ? due to enhancing the spin polarization in the FM, while there exits no 0?? transition for the SC with s{sub ++}-wave pairing symmetry. The two features can be used to identify the pairing symmetry in the iron pnictide SC different from the s{sub ++}-wave one in MgB{sub 2}. Experimentally, by adjusting the doping level in the s{sub }-wave SCs, one can vary ?.

  3. Microstructural Characterization of Nodular Ductile Iron

    SciTech Connect (OSTI)

    Springer, H K

    2012-01-03

    The objective of this study is to quantify the graphite particle phase in nodular ductile iron (NDI). This study provides the basis for initializing microstructure in direct numerical simulations, as part of developing microstructure-fracture response models. The work presented here is a subset of a PhD dissertation on spall fracture in NDI. NDI is an ideal material for studying the influence of microstructure on ductile fracture because it contains a readily identifiable second-phase particle population, embedded in a ductile metallic matrix, which serves as primary void nucleation sites. Nucleated voids grow and coalesce under continued tensile loading, as part of the micromechanisms of ductile fracture, and lead to macroscopic failure. For this study, we used 2D optical microscopy and quantitative metallography relationships to characterize the volume fraction, size distribution, nearest-neighbor distance, and other higher-order metrics of the graphite particle phase. We found that the volume fraction was {Phi} = 0.115, the average particle diameter was d{sub avg} = 25.9 {mu}m, the Weibull shape and scaling parameters were {beta} = 1.8 and {eta} = 29.1 {mu}m, respectively, the (first) nearest neighbor distance was L{sub nn} = 32.4 {mu}m, the exponential coefficients for volume fraction fluctuations was A{sub {Phi}} = 1.89 and B{sub {Phi}} = -0.59, respectively. Based on reaching a coefficient-of-variation (COV) of 0.01, the representative volume element (RVE) size was determined to be 8.9L{sub nn} (288 {mu}m).

  4. The effect of iron dilution on strength of nickel/steel and Monel/steel welds

    SciTech Connect (OSTI)

    Fout, S.L.; Wamsley, S.D.

    1983-03-28

    The weld strength, as a function of iron content, for nickel/steel and Monel/steel welds was determined. Samples were prepared using a Gas Metal Arc (GMAW) automatic process to weld steel plate together with nickel or Monel to produce a range of iron contents typical of weld compositions. Tensile specimens of each iron content were tested to obtain strength and ductility measurements for that weld composition. Data indicate that at iron contents of less than 20% iron in a nickel/steel weld, the weld fails at the weld interface, due to a lack of fusion. Between 20% and 35% iron, the highest iron dilution that could be achieved in a nickel weld, the welds were stronger than the steel base metal. This indicates that a minimum amount of iron dilution (20%) is necessary for good fusion and optimum strength. On the other hand for Monel/steel welds, test results showed that the welds had good strength and integrity between 10% and 27% iron in the weld. Above 35% iron, the welds have less strength and are more brittle. The 35% iron content also corresponds to the iron dilution in Monel welds that has been shown to produce an increase in corrosion rate. This indicates that the iron dilution in Monel welds should be kept below 35% iron to maximize both the strength and corrosion resistance. 2 refs., 6 figs., 3 tabs.

  5. Insights into the Structure and Metabolic Function of Microbes That Shape Pelagic Iron-Rich Aggregates ( Iron Snow )

    SciTech Connect (OSTI)

    Lu, S; Chourey, Karuna; REICHE, M; Nietzsche, S; Shah, Manesh B; Hettich, Robert {Bob} L; Kusel, K

    2013-01-01

    Metaproteomics combined with total nucleic acid-based methods aided in deciphering the roles of microorganisms in the formation and transformation of iron-rich macroscopic aggregates (iron snow) formed in the redoxcline of an acidic lignite mine lake. Iron snow had high total bacterial 16S rRNA gene copies, with 2 x 109 copies g (dry wt)-1 in the acidic (pH 3.5) central lake basin and 4 x 1010 copies g (dry wt)-1 in the less acidic (pH 5.5) northern lake basin. Active microbial communities in the central basin were dominated by Alphaproteobacteria (36.6%) and Actinobacteria (21.4%), and by Betaproteobacteria (36.2%) in the northern basin. Microbial Fe-cycling appeared to be the dominant metabolism in the schwertmannite-rich iron snow, because cloning and qPCR assigned up to 61% of active bacteria as Fe-cycling bacteria (FeB). Metaproteomics revealed 70 unique proteins from central basin iron snow and 283 unique proteins from 43 genera from northern basin. Protein identification provided a glimpse into in situ processes, such as primary production, motility, metabolism of acidophilic FeB, and survival strategies of neutrophilic FeB. Expression of carboxysome shell proteins and RubisCO indicated active CO2 fixation by Fe(II) oxidizers. Flagellar proteins from heterotrophs indicated their activity to reach and attach surfaces. Gas vesicle proteins related to CO2-fixing Chlorobium suggested that microbes could influence iron snow sinking. We suggest that iron snow formed by autotrophs in the redoxcline acts as a microbial parachute, since it is colonized by motile heterotrophs during sinking which start to dissolve schwertmannite.

  6. Reaction of iron and steel slags with refractories

    SciTech Connect (OSTI)

    Banerjee, S.; Anderson, M.W.

    1993-04-01

    Slag corrosion and erosion has been a major wear factor for refractories wear in contact with molten iron and steel. In blast furnace ironmaking, the slag/iron interface plays a more important role than does the slag/refractory interface. On the other hand in steelmaking, the slag in the ladles and tundish predominantly affect refractory wear. This paper presents the results of a detailed microstructural evaluation of (a) slag and slag/iron interactions with A1{sub 2}O{sub 3}-SiC-C refractories for ironmaking in blast furnaces, (b) basic oxygen furnace and ladle slag interactions with alumina spinel refractories for steelmaking, and (c) slag interactions with working refractory lining for continuous casting tundishes. Results will also be presented on refractory wear/failure due to simultaneous corrosion and penetration by the slag.

  7. Method and system for producing metallic iron nuggets

    DOE Patents [OSTI]

    Iwasaki, Iwao; Lindgren, Andrew J.; Kiesel, Richard F.

    2013-06-25

    Method and system for producing metallic nuggets includes providing reducible mixture of reducing material (such as carbonaceous material) and reducible iron bearing material (such as iron oxide) that may be arranged in discrete portions, such as mounds or briquettes, on at least a portion of a hearth material layer (such as carbonaceous material). A coarse overlayer of carbonaceous material may be provided over at least some of the discrete portions. Heating the reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

  8. Welding studies of nickel aluminide and nickel-iron aluminides

    SciTech Connect (OSTI)

    Santella, M.L.; David, S.A.; Horton, J.A.; White, C.L.; Liu, C.T.

    1985-08-01

    Because welding is often used during the fabrication of structural components, one of the key issues in the development of nickel aluminides and nickel-iron aluminides for engineering applications is their weldability. The goals of this study were to characterize weldment microstructures and to identify some of the factors controlling weldability of ductile Ni/sub 3/Al alloys. The alloys used in this initial study were Ni/sub 3/Al containing 500 wppm boron and Ni/sub 3/Al containing 10 at. % iron and either 500 wppm or 20 wppm boron. Full-penetration autogenous welds were made in sheet shock by the electron beam (EB) and gas tungsten arc (GTA) processes. The main process variables were travel speed and preheat. The as-welded coupons were examined visually and in detail by the usual optical and electron metallographic methods. Weldments of boron-doped Ni/sub 3/Al were composed of nearly 100% ordered ..gamma..' phase. Weldments of the nickel-iron aluminides were ..gamma..' + ..beta..' phase mixtures, with martensitic ..beta..' distributed interdendritically in the fusion zone and decorating grain boundaries in the heat-affected zone. All welds made in this particular boron-doped Ni/sub 3/Al alloy contained cracks. Weldability improved with the addition of iron, and defect-free welds were made in the nickel-iron aluminides by both EB and GTA welding. Nevertheless, the iron-containing alloys were susceptible to cracking, and their weldability was affected by boron concentration, welding speed, and (for GTA) gas shielding. Defect-free welds were found to have good tensile properties relative to those of the base metal. 34 refs., 17 figs., 2 tabs.

  9. Friedel-Like Oscillations from Interstitial Iron in Superconducting

    Office of Scientific and Technical Information (OSTI)

    Fe1+yTe0.62Se0.38 (Journal Article) | SciTech Connect Journal Article: Friedel-Like Oscillations from Interstitial Iron in Superconducting Fe1+yTe0.62Se0.38 Citation Details In-Document Search Title: Friedel-Like Oscillations from Interstitial Iron in Superconducting Fe1+yTe0.62Se0.38 Using polarized and unpolarized neutron scattering we show that interstitial Fe in superconducting Fe$$_{1+y}$$Te$$_{1-x}$$Se$_x$ induces a magnetic Friedel-like oscillation that diffracts at $${\bf

  10. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O,

  11. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O,

  12. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O,

  13. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O,

  14. Electrolytic photodissociation of chemical compounds by iron oxide photochemical diodes

    DOE Patents [OSTI]

    Somorjai, Gabor A.; Leygraf, Christofer H.

    1985-01-01

    Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor photochemical diode having visible light as its sole source of energy. The photochemical diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

  15. Electronic spin state of iron in lower mantle perovskite

    SciTech Connect (OSTI)

    Li, J.; Struzhkin, V.; Mao, H.-k.; Shu, J.; Hemley, R.; Fei, Y.; Mysen, B.; Dera, P.; Parapenka, V.; Shen, G.

    2010-11-16

    The electronic spin state of iron in lower mantle perovskite is one of the fundamental parameters that governs the physics and chemistry of the most voluminous and massive shell in the Earth. We present experimental evidence for spin-pairing transition in aluminum-bearing silicate perovskite (Mg,Fe)(Si,Al)O{sub 3} under the lower mantle pressures. Our results demonstrate that as pressure increases, iron in perovskite transforms gradually from the initial high-spin state toward the final low-spin state. At 100 GPa, both aluminum-free and aluminum-bearing samples exhibit a mixed spin state. The residual magnetic moment in the aluminum-bearing perovskite is significantly higher than that in its aluminum-free counterpart. The observed spin evolution with pressure can be explained by the presence of multiple iron species and the occurrence of partial spin-paring transitions in the perovskite. Pressure-induced spin-pairing transitions in the perovskite would have important bearing on the magnetic, thermoelastic, and transport properties of the lower mantle, and on the distribution of iron in the Earth's interior. The lower mantle constitutes more than half of the Earth's interior by volume (1), and it is believed to consist predominantly (80-100%) of (Mg,Fe)(Si,Al)O{sub 3} perovskite (hereafter called perovskite), with up to 20% (Mg,Fe)O ferropericlase (2). The electronic spin state of iron has direct influence on the physical properties and chemical behavior of its host phase. Hence, knowledge on the spin state of iron is important for the interpretation of seismic observations, geochemical modeling, and geodynamic simulation of the Earth's deep interior (3, 4). Crystal field theory (4, 5) and band theory (6) predicted that a high-spin to low-spin transition would occur as a result of compression. To date, no experimental data exist on the spin sate of iron in Al-bearing perovskite. To detect possible spinpairing transition of iron in perovskite under the lower mantle conditions, we measured the x-ray emission spectra of an Al-bearing perovskite sample to 100 GPa. For comparison, a parallel measurement was also carried out on an Al-free perovskite sample.

  16. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iran Deal is Working The Iran Deal is Working Addthis Topic Nuclear Security & Safety Since the Iran Deal came into effect in October 2015, the International Atomic Energy Agency (IAEA) verified that Iran undertook critical steps to ensure its four pathways to a nuclear bomb are blocked. Watch to see how the Iran Deal is working

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a

  17. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O,

  18. The Iron Spin Transition in the Earth's Lower Mantle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O,

  19. Recovery of iron oxide from coal fly ash

    DOE Patents [OSTI]

    Dobbins, Michael S.; Murtha, Marlyn J.

    1983-05-31

    A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

  20. Magnetic states of the two-leg-ladder alkali metal iron selenides...

    Office of Scientific and Technical Information (OSTI)

    states of the two-leg-ladder alkali metal iron selenides AFe2Se3 Prev Next Title: Magnetic states of the two-leg-ladder alkali metal iron selenides AFe2Se3 Authors: Luo, ...

  1. ITP Steel: Energy and Environmental Profile fo the U.S. Iron...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Environmental Profile fo the U.S. Iron and Steel Industry ITP Steel: Energy and Environmental Profile fo the U.S. Iron and Steel Industry PDF icon steelprofile.pdf More ...

  2. Observation of magnon-mediated current drag in Pt/yttrium iron...

    Office of Scientific and Technical Information (OSTI)

    Observation of magnon-mediated current drag in Ptyttrium iron garnetPt(Ta) trilayers Title: Observation of magnon-mediated current drag in Ptyttrium iron garnetPt(Ta) trilayers ...

  3. Iron Pyrite Thin Films Synthesized from an Fe(acac)[subscript...

    Office of Scientific and Technical Information (OSTI)

    Iron Pyrite Thin Films Synthesized from an Fe(acac)subscript 3 Ink Citation Details In-Document Search Title: Iron Pyrite Thin Films Synthesized from an Fe(acac)subscript 3 Ink...

  4. Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in...

  5. Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project...

    Energy Savers [EERE]

    Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping and Feasibility Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping and Feasibility ...

  6. Bandwidth Study U.S. Iron and Steel Manufacturing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Iron and Steel Manufacturing Bandwidth Study U.S. Iron and Steel Manufacturing Bandwidth Study U.S. Iron and Steel Manufacturing Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. iron and steel manufacturing. The study relies on multiple sources to estimate the energy used in

  7. Chromium modified nickel-iron aluminide useful in sulfur bearing environments

    DOE Patents [OSTI]

    Cathcart, John V.; Liu, Chain T.

    1989-06-13

    An improved nickel-iron aluminide containing chromium and molybdenum additions to improve resistance to sulfur attack.

  8. Manufacturing Energy and Carbon Footprint- Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006)

    Broader source: Energy.gov [DOE]

    Manufacturing Energy and Carbon Footprint for Iron and Steel Sector (NAICS 3311, 3312) with Total Energy Input

  9. Studies of anisotropy of iron based superconductors

    SciTech Connect (OSTI)

    Murphy, Jason

    2013-05-15

    To study the electronic anisotropy in iron based superconductors, the temperature dependent London penetration depth, {Delta}{lambda}#1;#21;(T), have been measured in several compounds, along with the angular dependent upper critical field, H{sub c2}(T). Study was undertaken on single crystals of Ba(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} with x=0.108 and x=0.127, in the overdoped range of the doping phase diagram, characterized by notable modulation of the superconducting gap. Heavy ion irradiation with matching field doses of 6 T and 6.5 T respectively, were used to create columnar defects and to study their effect on the temperature {Delta}{lambda}#1;#21;(T). The variation of the low-temperature penetration depth in both pristine and irradiated samples was #12;tted with a power-law function {Delta}{lambda}#1;#21;(T) = AT{sup n}. Irradiation increases the magnitude of the pre-factor A and decreases the exponent n, similar to the effect on the optimally doped samples. This finding supports the universal s{sub {+-}}#6; scenario for the whole doping range. Knowing that the s{sub {+-}}#6; gap symmetry exists across the superconducting dome for the electron doped systems, we next looked at {lambda}#21;(T), in optimally - doped, SrFe{sub 2}(As{sub 1-x}P{sub x}){sub 2}, x =0.35. Both, as-grown (T{sub c} ~ #25;25 K) and annealed (T{sub c} ~ #25;35 K) single crystals of SrFe{sub 2}(As{sub 1-x}P{sub x}){sub 2} were measured. Annealing decreases the absolute value of the London penetration depth from #21;{lambda}(0) = 300 {+-}#6; 10 nm in as-grown samples to {lambda}#21;(0) = 275{+-}#6;10 nm. At low temperatures, {lambda}#21;(T) #24;~ T indicates a superconducting gap with line nodes. Analysis of the full-temperature range superfluid density is consistent with the line nodes, but differs from the simple single-gap d-wave. The observed behavior is very similar to that of BaFe{sub 2}(As{sub 1-x}P{sub x}){sub 2}, showing that isovalently substituted pnictides are inherently different from the charge-doped materials. In-plane resistivity measurements as a function of temperature, magnetic field, and its orientation with respect to the crystallographic ab-plane were used to study the upper critical field, H{sub c2}, of two overdoped compositions of Ba(Fe{sub 1-x}Ni{sub x}){sub 2}As{sub 2}, x=0.054 and x=0.072. Measurements were performed using precise alignment (with accuracy less than 0.1{degree}) of the magnetic field with respect to the Fe-As plane. The dependence of the H{sub c2} on angle {theta}#18; between the field and the ab- plane was measured in isothermal conditions in a broad temperature range. We found that the shape of the H{sub c2} vs. {theta}#18; curve clearly deviates from the Ginzburg-Landau theory.

  10. Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders

    SciTech Connect (OSTI)

    Asit Biswas Andrew J. Sherman

    2006-09-25

    This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

  11. Deactivation by carbon of iron catalysts for indirect liquefaction

    SciTech Connect (OSTI)

    Bartholomew, C H

    1991-02-14

    Progress is reported for a four-year fundamental investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for FT synthesis, the objectives of which were to (1) determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation and (2) model the global rates of deactivation at the surface of the catalyst for the same catalysts. A computer-automated reactor system to be used in the kinetic and deactivation studies was designed, constructed and tested. Kinetic data for CO hydrogenation on unsupported, unpromoted iron, 99% Fe/1% Al{sub 2}O{sub 3}, and K-promoted 99% Fe/1% Al{sub 2}O{sub 3} catalysts were obtained as functions of temperature, reactant particle pressures and time. The activity/selectivity and kinetic data are consistent with those previously reported for supported, unpromoted and promoted iron. Two kinds of deactivation were observed during FT synthesis on these samples: (1) loss of surface area after reduction of unsupported, unpromoted iron at 400{degree}C and (2) loss of activity with time due to carbon deposition, especially in the case of K-promoted 99% Fe/1% A1{sub 2}O{sub 3}. Deactivation rate data were obtained for CO hydrogenation on promoted Fe as a function of time, temperature, and H{sub 2}/CO ratio. 50 refs., 24 figs., 5 tabs.

  12. Alteration of Iron-Rich Lacustrine Sediments by Dissimilatory Iron-Reducing Bacteria

    SciTech Connect (OSTI)

    Crowe,S.; Roberts, J.; Weisener, C.; Fowle, D.

    2007-01-01

    The reduction of Fe during bacterial anaerobic respiration in sediments and soils not only causes the degradation of organic matter but also results in changes in mineralogy and the redistribution of many nutrients and trace metals. Understanding trace metal patterns in sedimentary rocks and predicting the fate of contaminants in the environment requires a detailed understanding of the mechanisms through which they are redistributed during Fe reduction. In this work, lacustrine sediments from Lake Matano in Indonesia were incubated in a minimal media with the dissimilatory iron reducing (DIR) bacterium Shewanella putrefaciens 200R. These sediments were reductively dissolved at rates slower than pure synthetic goethite despite the presence of an 'easily reducible' component, as defined by selective extractions. DIR of the lacustrine sediments resulted in the substrate-dependent production of abundant quantities of extracellular polymeric substances. Trace elements, including Ni, Co, P, Si, and As, were released from the sediments with progressive Fe reduction while Cr was sequestered. Much of the initial trace metal mobility can be attributed to the rapid reduction of a Mn-rich oxyhydroxide phase. The production of organo-Fe(III) reveals that DIR bacteria can generate significant metal complexation capacity. This work demonstrates that DIR induces the release of many elements associated with Fe-Mn oxyhydroxides, despite secondary mineralization.

  13. Iron Aerogel and Xerogel Catalysts for Fischer-Tropsch Synthesis of Diesel Fuel

    SciTech Connect (OSTI)

    Bali, S.; Huggins, F; Huffman, G; Ernst, R; Pugmire, R; Eyring, E

    2009-01-01

    Iron aerogels, potassium-doped iron aerogels, and potassium-doped iron xerogels have been synthesized and characterized and their catalytic activity in the Fischer-Tropsch (F-T) reaction has been studied. Iron aerogels and xerogels were synthesized by polycondensation of an ethanolic solution of iron(III) chloride hexahydrate with propylene oxide which acts as a proton scavenger for the initiation of hydrolysis and polycondensation. Potassium was incorporated in the iron aerogel and iron xerogel by adding aqueous K{sub 2}CO{sub 3} to the ethanolic solutions of the Fe(III) precursor prior to addition of propylene oxide. Fischer-Tropsch activities of the catalysts were tested in a fixed bed reactor at a pressure of 100 psi with a H{sub 2}:CO ratio of 2:1. Iron aerogels were found to be active for F-T synthesis, and their F-T activities increased on addition of a K containing promoter. Moessbauer spectroscopic data are consistent with an open, nonrigid iron(III) aerogel structure progressing to an iron carbide/metallic iron catalyst via agglomeration as the F-T synthesis proceeds in the course of a 35 h fixed bed reaction test.

  14. Use of bimodal carbon distribution in compacts for producing metallic iron nodules

    DOE Patents [OSTI]

    Iwasaki, Iwao

    2014-04-08

    A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.

  15. Use of bimodal carbon distribution in compacts for producing metallic iron nodules

    DOE Patents [OSTI]

    Iwasaki, Iwao

    2012-10-16

    A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.

  16. Arsenic Sequestration By Sorption Processes in High-Iron Sediments

    SciTech Connect (OSTI)

    Root, R.A.; Dixit, S.; Campbell, K.M.; Jew, A.D.; Hering, J.G.; O'Day, P.A.

    2009-06-04

    High-iron sediments in North Haiwee Reservoir (Olancha, CA), resulting from water treatment for removal of elevated dissolved arsenic in the Los Angeles Aqueduct system, were studied to examine arsenic partitioning between solid phases and porewaters undergoing shallow burial. To reduce arsenic in drinking water supplies, ferric chloride and a cationic polymer coagulant are added to the aqueduct upstream of Haiwee Reservoir, forming an iron-rich floc that scavenges arsenic from the water. Analysis by synchrotron X-ray absorption spectroscopy (XAS) showed that the aqueduct precipitate is an amorphous hydrous ferric oxide (HFO) similar to ferrihydrite, and that arsenic is associated with the floc as adsorbed and/or coprecipitated As(V). Arsenic-rich floc and sediments are deposited along the inlet channel as aqueduct waters enter the reservoir. Sediment core samples were collected in two consecutive years from the edge of the reservoir along the inlet channel using 30- or 90-cm push cores. Cores were analyzed for total and extractable arsenic and iron concentrations. Arsenic and iron speciation and mineralogy in sediments were examined at selected depths by synchrotron XAS and X-ray diffraction (XRD). Sediment-porewater measurements were made adjacent to the core sample sites using polyacrylamide gel probe samplers. Results showed that sediment As(V) is reduced to As(III) in all cores at or near the sediment-water interface (0--4 cm), and only As(III) was observed in deeper sediments. Analyses of EXAFS spectra indicated that arsenic is present in the sediments mostly as a bidentate-binuclear, inner-sphere sorption complex with local atomic geometries similar to those found in laboratory studies. Below about 10 cm depth, XAS indicated that the HFO floc had been reduced to a mixed Fe(II, III) solid with a local structure similar to that of synthetic green rust (GR) but with a slightly contracted average interatomic Fe-Fe distance in the hydroxide layer. There was no evidence from XRD for the formation of a crystalline GR phase. The release of dissolved iron (presumably Fe{sup 2+}) and arsenic to solution, as monitored by in situ gel probes, was variable but, in general, occurred at greater depths than arsenic reduction in the sediments by spectroscopic observations and appears to be near or below the depth at which sediment GR was identified. These data point to reductive dissolution of the sorbent iron phase as the primary mechanism of release of sorbed arsenic to solution.

  17. Method for heat treating iron-nickel-chromium alloy

    DOE Patents [OSTI]

    Merrick, Howard F.; Korenko, Michael K.

    1982-01-01

    A method for heat treating an age-hardenable iron-nickel-chromium alloy to obtain a bimodal distribution of gamma prime phase within a network of dislocations, the alloy consisting essentially of about 25% to 45% nickel, 10% to 16% chromium, 1.5% to 3% of an element selected from the group consisting of molybdenum and niobium, about 2% titanium, about 3% aluminum, and the remainder substantially all iron. To obtain optimum results, the alloy is heated to a temperature of 1025.degree. C. to 1075.degree. C. for 2-5 minutes, cold-worked about 20% to 60%, aged at a temperature of about 775.degree. C. for 8 hours followed by an air-cool, and then heated to a temperature in the range of 650.degree. C. to 700.degree. C. for 2 hours followed by an air-cool.

  18. The world`s first commercial iron carbide plant

    SciTech Connect (OSTI)

    Prichard, L.C.; Schad, D.

    1995-12-01

    The paper traces the development of Nucor`s investigation of clean iron unit processes, namely, direct reduction, and the decision to build and operate the world`s first commercial iron carbide plant. They first investigated coal based processes since the US has abundant coal reserves, but found a variety of reasons for dropping the coal-based processes from further consideration. A natural gas based process was selected, but the failure to find economically priced gas supplies stopped the development of a US based venture. It was later found that Trinidad had economically priced and abundant supplies of natural gas, and the system of government, the use of English language, and geographic location were also ideal. The cost estimates required modification of the design, but the plant was begun in April, 1993. Start-up problems with the plant are also discussed. Production should commence shortly.

  19. Synthesis of carbon-coated iron nanoparticles by detonation technique

    SciTech Connect (OSTI)

    Sun, Guilei, E-mail: sunguilei@126.com [Department of Safety Engineering, China Institute of Industrial Relations, Beijing 100037 (China)] [Department of Safety Engineering, China Institute of Industrial Relations, Beijing 100037 (China); Li, Xiaojie, E-mail: dalian03@vip.sina.com [State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023 (China)] [State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023 (China); Wang, Qiquan [Department of Safety Engineering, China Institute of Industrial Relations, Beijing 100037 (China)] [Department of Safety Engineering, China Institute of Industrial Relations, Beijing 100037 (China); Yan, Honghao [State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023 (China)] [State Key Laboratory of Structural Analysis for Industrial Equipment, Department of Engineering Mechanics, Dalian University of Technology, Dalian 116023 (China)

    2010-05-15

    Carbon-coated iron nanoparticles were synthesized by detonating a mixture of ferrocene, naphthalene and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in an explosion vessel under low vacuum conditions (8.1 kPa). The RDX functioned as an energy source for the decomposition of ferrocene and naphthalene. The carbon-coated iron nanoparticles were formed as soot-like deposits on the inner surface of the reactor, which were characterized by XRD, TEM, HRTEM, Raman spectroscopy and vibrating sample magnetometer. And a portion of the detonation soot was treated with hydrochloric acid. The product was carbon-coated nanoparticles in perfect core-shell structures with graphitic shells and bcc-Fe cores. The detonation technique offers an energy-saving route to the synthesis of carbon-coated nanomaterials.

  20. Method for heat treating iron-nickel-chromium alloy

    DOE Patents [OSTI]

    Not Available

    1980-04-03

    A method is described for heat treating an age-hardenable iron-nickel-chromium alloy to obtain a morphology of the gamma-double prime phase enveloping the gamma-prime, the alloy consisting essentially of about 25 to 45% nickel, 10 to 16% chromium, 1.5 to 3% of an element selected from the group consisting of molybdenum and niobium, about 2% titanium, about 3% aluminum, and the remainder substantially all iron. To obtain optimum results, the alloy is heated to a temperature of 1025 to 1075/sup 0/C for 2 to 5 minutes, cold-worked about 20 to 60%, aged at a temperature of about 775/sup 0/C for 8 hours followed by an air-cool, and then heated to a temperature in the range of 650 to 700/sup 0/C for 2 hours followed by an air-cool.

  1. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

    2001-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  2. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, V.K.; Deevi, S.C.; Fleischhauer, G.S.; Hajaligol, M.R.; Lilly, A.C. Jr.

    1997-04-15

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, {<=}1% Cr and either {>=}0.05% Zr or ZrO{sub 2} stringers extending perpendicular to an exposed surface of the heating element or {>=}0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, {<=}2% Ti, {<=}2% Mo, {<=}1% Zr, {<=}1% C, {<=}0.1% B, {<=}30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, {<=}1% rare earth metal, {<=}1% oxygen, {<=}3% Cu, balance Fe. 64 figs.

  3. Oxidation, carburization and/or sulfidation resistant iron aluminide alloy

    DOE Patents [OSTI]

    Sikka, Vinod K.; Deevi, Seetharama C.; Fleischhauer, Grier S.; Hajaligol, Mohammad R.; Lilly, Jr., A. Clifton

    2003-08-19

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or Zro.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B. .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  4. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

    1999-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  5. Iron aluminide alloy container for solid oxide fuel cells

    DOE Patents [OSTI]

    Judkins, Roddie Reagan; Singh, Prabhakar; Sikka, Vinod Kumar

    2000-01-01

    A container for fuel cells is made from an iron aluminide alloy. The container alloy preferably includes from about 13 to about 22 weight percent Al, from about 2 to about 8 weight percent Cr, from about 0.1 to about 4 weight percent M selected from Zr and Hf, from about 0.005 to about 0.5 weight percent B or from about 0.001 to about 1 weight percent C, and the balance Fe and incidental impurities. The iron aluminide container alloy is extremely resistant to corrosion and metal loss when exposed to dual reducing and oxidizing atmospheres at elevated temperatures. The alloy is particularly useful for containment vessels for solid oxide fuel cells, as a replacement for stainless steel alloys which are currently used.

  6. Iron aluminide alloys with improved properties for high temperature applications

    DOE Patents [OSTI]

    McKamey, Claudette G. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

    1990-01-01

    An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.

  7. Method for heat treating iron-nickel-chromium alloy

    DOE Patents [OSTI]

    Korenko, Michael K.

    1980-01-01

    A method for heat treating an age-hardenable iron-nickel-chromium alloy to obtain a morphology of the gamma-double prime phase enveloping the gamma-prime phase, the alloy consisting essentially of about 40 to 50% nickel, 7.5 to 14% chromium, 1.5 to 4% niobium, 0.3 to 0.75% silicon, 1 to 3% titanium, 0.1 to 0.5% aluminum, 0.02 to 1% carbon, 0.002 to 0.0015% boron and the remain substantially all iron. To obtain optimal results, the alloy is cold-worked 20 to 60% followed by heating at 1050.degree. C. for 1/2 hour with an air-cool plus heating at 800.degree. C. for 2 hours with a furnace cool to 625.degree. C. The alloy is then held at 625.degree. C. for 12 hours, followed by an air-cool.

  8. TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS

    SciTech Connect (OSTI)

    Davis, B.H.

    1998-07-22

    The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

  9. Iron aluminide useful as electrical resistance heating elements

    DOE Patents [OSTI]

    Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

    1997-01-01

    The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

  10. Iron beam acceleration using direct plasma injection scheme

    SciTech Connect (OSTI)

    Okamura, M.; Kanesue, T.; Yamamoto, T.; Fuwa, Y.; RIKEN, Wako, Saitama 351-0198

    2014-02-15

    A new set of vanes of radio frequency quadrupole (RFQ) accelerator was commissioned using highly charged iron beam. To supply high intensity heavy ion beams to the RFQ, direct plasma injection scheme (DPIS) with a confinement solenoid was adopted. One of the difficulties to utilize the combination of DPIS and a solenoid field is a complexity of electro magnetic field at the beam extraction region, since biasing high static electric field for ion extraction, RFQ focusing field, and the solenoid magnetic field fill the same space simultaneously. To mitigate the complexity, a newly designed magnetic field clamps were used. The intense iron beam was observed with bunched structure and the total accelerated current reached 2.5 nC.

  11. Cation-exchange fiber reduces iron oxide leakage

    SciTech Connect (OSTI)

    MacClure, S.L.

    1993-10-01

    This article describes how addition of new fiber in powdered-resin precoat improves demineralizer crud-retention capability and reduces disposal cost for radioactive spent resin. Various attempts have been made to reduce the concentrations of iron oxide at the outlet of filter/demineralizer (FTD) vessels. Each vessel is fitted with an array of tubular septa that are precoated with powdered ion-exchange resin. The coatings perform filtering and ion-exchange actions on incoming feedwater, removing both suspended and dissolved solids. Experience at Duane Arnold Energy Center (CAED) indicates that use of a powdered-resin precoat containing cation-exchange fibers rather than cellulose fibers can reduce iron oxide levels in FTD effluent significantly.

  12. Iron aluminide alloys with improved properties for high temperature applications

    DOE Patents [OSTI]

    McKamey, C.G.; Liu, C.T.

    1990-10-09

    An improved iron aluminide alloy of the DO[sub 3] type is described that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy conversion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26--30 at. % aluminum, 0.5--10 at. % chromium, 0.02--0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron. 3 figs.

  13. Low resistivity contact to iron-pnictide superconductors

    DOE Patents [OSTI]

    Tanatar, Makariy; Prozorov, Ruslan; Ni, Ni; Bud'ko, Sergey; Canfield, Paul

    2013-05-28

    Method of making a low resistivity electrical connection between an electrical conductor and an iron pnictide superconductor involves connecting the electrical conductor and superconductor using a tin or tin-based material therebetween, such as using a tin or tin-based solder. The superconductor can be based on doped AFe.sub.2As.sub.2, where A can be Ca, Sr, Ba, Eu or combinations thereof for purposes of illustration only.

  14. Bifunctional air electrodes containing elemental iron powder charging additive

    DOE Patents [OSTI]

    Liu, Chia-tsun; Demczyk, Brian G.; Gongaware, Paul R.

    1982-01-01

    A bifunctional air electrode for use in electrochemical energy cells is made, comprising a hydrophilic layer and a hydrophobic layer, where the hydrophilic layer essentially comprises a hydrophilic composite which includes: (i) carbon; (ii) elemental iron particles having a particle size of between about 25 microns and about 700 microns diameter; (iii) an oxygen evolution material; (iv) a nonwetting agent; and (v) a catalyst, where at least one current collector is formed into said composite.

  15. Technology development for iron F-T catalysts. Final report

    SciTech Connect (OSTI)

    Frame, R.R.; Gala, H.B.

    1994-08-01

    The objectives of this work were twofold. The first objective was to design and construct a pilot plant for preparing precipitated iron oxide F-T precursors and demonstrate that the rate of production from this plant is equivalent to 100 lbs/day of dried metal oxide. Secondly, these precipitates were to be used to prepare catalysts capable of achieving 88% CO + H{sub 2} conversion with {le} 5 mole percent selectivity to methane + ethane.

  16. Magnetism and Superconductivity Compete in Iron-based Superconductors |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource Magnetism and Superconductivity Compete in Iron-based Superconductors Wednesday, April 30, 2014 HTSC Figure 1 Fig. 1. Measured electronic structure of underdoped Ba1-xKxFe2As2 in the orthorhombic spin-density-wave (SDW) ordered state. The antiferromagnetic and ferromagnetic directions are indicated by arrows. High-temperature superconductivity (HTSC), one of the long-standing unsolved mysteries of condensed matter physics, is a beautiful example of

  17. Methods for making a supported iron-copper catalyst

    DOE Patents [OSTI]

    Dyer, Paul N.; Pierantozzi, Ronald

    1986-01-01

    A catalyst is described for the synthesis of hydrocarbons from CO+H.sub.2 utilizing a porous Al.sub.2 O.sub.3 support impregnated with iron and copper and optionally promoted with an alkali metal. The use of an Al.sub.2 O.sub.3 support results in the suppression of heavy waxes (C.sub.26 + hydrocarbons), particularly in slurry phase operation, when compared to unsupported or co-precipitated catalysts.

  18. The development of precipitated iron catalysts with improved stability

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The goal of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. This report covers testing an iron catalyst. During the last quarter, a new precipitated iron catalyst was prepared and tested in the slurry autoclave reactor at various conditions. This catalyst did not noticeably deactivate during 1250 hours of testing. This quarter, the test was extended to include performance evaluations at different conversion levels ranging from 35 to 88% at 265 and 275{degree}C. The conversion levels were varied by changing the feed rate. The catalytic performance at different conversion intervals was then integrated to approximately predict performance in a bubble column reactor. The run was shut down at the end of 1996 hours because of a 24-hour-power outage. When the power was back on, the run was restarted from room temperature. Catalytic performance during the first 300 hours after the restart-up was monitored. Overall product distributions are being tabulated as analytical laboratory data are obtained. 34 figs., 3 tabs.

  19. Deactivation by carbon of iron catalysts for indirect liquefaction

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1991-01-10

    Although promoted cobalt and iron catalysts for Fischer-Tropsch (FT) synthesis of gasoline feedstock were first developed more than three decades ago, a major technical problem still limiting the commercial use of these catalysts today is carbon deactivation. This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for FT synthesis, the objectives of which are to: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; and model the rates of deactivation of the same catalysts in fixed-bed reactors. To accomplish the above objectives, the project is divided into the following tasks: (1) determine the kinetics of reaction and of carbon deactivation during CO hydrogenation on Fe and Fe/K catalysts coated on monolith bodies. (2) Determine the reactivities and types of carbon deposited during reaction on the same catalysts from temperature-programmed-surface-reaction spectroscopy (TPSR) and transmission electron microscopy (TEM). Determine the types of iron carbides formed at various temperatures and H{sub 2}/CO ratios using x-ray diffraction and Moessbauer spectroscopy. (3) Develop mathematical deactivation models which include heat and mass transport contributions for FT synthesis is packed-bed reactors. Progress to date is described. 48 refs., 3 figs., 1 tab.

  20. Method of fabricating a prestressed cast iron vessel

    DOE Patents [OSTI]

    Lampe, Robert F. (Bethel Park, PA)

    1982-01-01

    A method of fabricating a prestressed cast iron vessel wherein double wall cast iron body segments each have an arcuate inner wall and a spaced apart substantially parallel outer wall with a plurality of radially extending webs interconnecting the inner wall and the outer wall, the bottom surface and the two exposed radial side surfaces of each body segment are machined and eight body segments are formed into a ring. The top surfaces and outer surfaces of the outer walls are machined and keyways are provided across the juncture of adjacent end walls of the body segments. A liner segment complementary in shape to a selected inner wall of one of the body segments is mounted to each of the body segments and again formed into a ring. The liner segments of each ring are welded to form unitary liner rings and thereafter the cast iron body segments are prestressed to complete the ring assembly. Ring assemblies are stacked to form the vessel and adjacent unitary liner rings are welded. A top head covers the top ring assembly to close the vessel and axially extending tendons retain the top and bottom heads in place under pressure.

  1. Interface driven magnetic interactions in nanostructured thin films of iron nanocrystallites embedded in a copper matrix

    SciTech Connect (OSTI)

    Desautels, R. D. Lierop, J. van; Shueh, C.; Lin, K.-W.; Freeland, J. W.

    2015-05-07

    We have fabricated thin films of iron nanocrystallites embedded in a copper matrix using a dual ion beam assisted deposition technique. A secondary End-Hall ion beam bombarded the iron atoms during deposition altering significantly the morphology of the films and allowing for control of the intermixing between iron and copper components. Cross-sectional transmission electron microscopy and x-ray reflectometry experiments indicated that the morphology of the films was that of iron nanocrystallites embedded in a copper matrix. Rietveld refinements of the diffraction pattern identified fcc-copper and amorphous iron. An increased amount of disorder was observed with a reduction in the amount of deposited iron from a 1:1 Fe:Cu ratio to 0.25:0.75 Fe:Cu ratio. Interfacial copper-iron alloys were identified by DC susceptibility experiments through their reduced T{sub C,Alloy} (370, 310, and 280 K) compared with that of bulk iron (∼1000 K). Element specific x-ray absorption and x-ray magnetic circular dichroism experiments were performed to identify the contributions to the magnetism from the iron and the copper-iron alloy.

  2. Coal Fly Ash as a Source of Iron in Atmospheric Dust

    SciTech Connect (OSTI)

    Chen, Haihan; Laskin, Alexander; Baltrusaitis, Jonas; Gorski, Christopher A.; Scherer, Michelle; Grassian, Vicki H.

    2012-01-18

    Anthropogenic coal fly ash aerosols may represent a significant source of bioavailable iron in the open ocean. Few measurements have been made to compare the solubility of atmospheric iron from anthropogenic aerosols and other sources. We report an investigation of the iron dissolution of three fly ash samples in acidic aqueous solutions and compare the solubilities with that of Arizona test dust, a reference material of mineral dust. The effects of pH, cloud processing, and solar irradiation on Fe solubility were explored. Similar to previously reported results on mineral dust, iron in aluminosilicate phases provide predominant dissolved iron compared with iron in oxides. Iron solubility of fly ash is higher than Arizona test dust, especially at the higher pH conditions investigated. Simulated atmospheric processing elevates iron solubility due to significant changes in the morphology aluminosilicate glass, a dominantly material in fly ash particle. Iron continuously releases into the aqueous solution as fly ash particles break up into smaller fragments. The assessment of dissolved atmospheric iron deposition fluxes, and their effect on the biogeochemistry at ocean surface should be constrained by taking into account the source, environment pH, Fe speciation, and solar radiation.

  3. Snapshot of iron response in Shewanella oneidensis by gene network reconstruction

    SciTech Connect (OSTI)

    Yang, Yunfeng; Harris, Daniel P.; Luo, Feng; Xiong, Wenlu; Joachimiak, Marcin; Wu, Liyou; Dehal, Paramvir; Jacobsen, Janet; Yang, Zamin; Palumbo, Anthony V.; Arkin, Adam P.; Zhou, Jizhong

    2008-10-09

    Background: Iron homeostasis of Shewanella oneidensis, a gamma-proteobacterium possessing high iron content, is regulated by a global transcription factor Fur. However, knowledge is incomplete about other biological pathways that respond to changes in iron concentration, as well as details of the responses. In this work, we integrate physiological, transcriptomics and genetic approaches to delineate the iron response of S. oneidensis. Results: We show that the iron response in S. oneidensis is a rapid process. Temporal gene expression profiles were examined for iron depletion and repletion, and a gene co-expression network was reconstructed. Modules of iron acquisition systems, anaerobic energy metabolism and protein degradation were the most noteworthy in the gene network. Bioinformatics analyses suggested that genes in each of the modules might be regulated by DNA-binding proteins Fur, CRP and RpoH, respectively. Closer inspection of these modules revealed a transcriptional regulator (SO2426) involved in iron acquisition and ten transcriptional factors involved in anaerobic energy metabolism. Selected genes in the network were analyzed by genetic studies. Disruption of genes encoding a putative alcaligin biosynthesis protein (SO3032) and a gene previously implicated in protein degradation (SO2017) led to severe growth deficiency under iron depletion conditions. Disruption of a novel transcriptional factor (SO1415) caused deficiency in both anaerobic iron reduction and growth with thiosulfate or TMAO as an electronic acceptor, suggesting that SO1415 is required for specific branches of anaerobic energy metabolism pathways. Conclusions: Using a reconstructed gene network, we identified major biological pathways that were differentially expressed during iron depletion and repletion. Genetic studies not only demonstrated the importance of iron acquisition and protein degradation for iron depletion, but also characterized a novel transcriptional factor (SO1415) with a role in anaerobic energy metabolism.

  4. Mssbauer study of metallic iron and iron oxide nanoparticles having environmental purifying ability

    SciTech Connect (OSTI)

    Kubuki, Shiro Watanabe, Yuka Akiyama, Kazuhiko; Risti?, Mira; Krehula, Stjepko; Homonnay, Zoltn; Kuzmann, Ern?; Nishida, Tetsuaki

    2014-10-27

    A relationship between local structure and methylene blue (MB) decomposing ability of nanoparticles (NPs) of metallic iron (Fe{sup 0}) and maghemite (??Fe{sub 2}O{sub 3}) was investigated by {sup 57}Fe Mssbauer spectroscopy, X-ray diffractometry and UV-visible light absorption spectroscopy. ??Fe{sub 2}O{sub 3} NPs were successfully prepared by mixing (NH{sub 4}){sub 2}Fe(SO{sub 4}){sub 2}?6H{sub 2}O (Mohr's salt) and (NH{sub 4}){sub 3}Fe(C{sub 2}O{sub 4}){sub 3}?3H{sub 2}O aqueous solution at 30 C for 1 h, while those of Fe{sup 0} were obtained by the reduction of Mohr's salt with NaBH{sub 4}. From the Scherrer's equation, the smallest crystallite sizes of ??Fe{sub 2}O{sub 3} NPs and Fe{sup 0} NPs were determined to be 9.7 and 1.5 nm, respectively. {sup 57}Fe Mssbauer spectrum of ??Fe{sub 2}O{sub 3} NPs consists of a relaxed sextet with isomer shift (?) of 0.33{sub 0.01} mm s{sup ?1}, internal magnetic field (H{sub int}) of 25.8{sub 0.5} T, and linewidth (?) of 0.62{sub 0.04} mm s{sup ?1}. {sup 57}Fe Mssbauer spectrum of Fe{sup 0} NP is mainly composed of a sextet having ?, ?, and H{sub int} of 0.00{sub 0.01} mm s{sup ?1} 0.45{sub 0.01} mm s{sup ?1}, and 22.8{sub 0.1} T, respectively. A bleaching test of the mixture of Fe{sup 0} and ??Fe{sub 2}O{sub 3} NPs (3:7 ratio, 100 mg) in MB aqueous solution (20 mL) for 6 h showed a remarkable decrease of MB concentration with the first-order rate constant (k{sub MB}) of 6.7 10{sup ?1} h{sup ?1}. This value is larger than that obtained for the bleaching test using bulk Fe{sup 0}+??Fe{sub 2}O{sub 3} (3:7) mixture (k{sub MB}?=?6.510{sup ?3}h{sup ?1}). These results prove that MB decomposing ability is enhanced by the NPs mixture of Fe{sub 0} and ??Fe{sub 2}O{sub 3}.

  5. Studies on the reduction kinetics of hematite iron ore pellets with noncoking coals for sponge iron plants

    SciTech Connect (OSTI)

    Kumar, M.; Mohapatra, P.; Patel, S.K.

    2009-07-01

    In the present investigation, fired pellets were made by mixing hematite iron ore fines of -100, -16+18, and -8+10 mesh size in different ratios and studies on their reduction kinetics in Lakhanpur, Orient OC-2 and Belpahar coals were carried out at temperatures ranging from 850{sup o}C to 1000{sup o}C with a view toward promoting the massive utilization of fines in ironmaking. The rate of reduction in all the fired iron ore pellets increased markedly with an increase in temperature up to 1000{sup o}C, and it was more intense in the first 30min. The values of activation energy, calculated from integral and differential approaches, for the reduction of fired pellets (prepared from iron ore fines of -100 mesh size) in coals were found to be in the range 131-148 and 130-181 kJ mol{sup -1} (for =0.2 to 0.8), indicating the process is controlled by a carbon gasification reaction. The addition of selected larger size particles in the matrix of -100 mesh size fines up to the extent studied decreased the activation energy and slightly increased the reduction rates of resultant fired pellets. In comparison to coal, the reduction of fired pellets in char was characterized by significantly lower reduction rates and higher activation energy.

  6. Laboratory study related to the production and properties of pig iron nuggets

    SciTech Connect (OSTI)

    Anameric, B.; Kawatra, S.K.

    2006-02-15

    Pig iron nuggets were produced in a laboratory-scale furnace at Michigan Technological University. The process was intended to replicate Kobe Steel's ITmk3 direct ironmaking process. These nuggets were produced from pellets that were made from a mixture of iron oxide, coal, flux and a binder and heated in a furnace with a chamber temperature of 1450{sup o}C. The pellets then self-reduced to produce a solid, high-density, highly metallized (96.5% Fe) pig iron. During the nugget production process, a separate liquid slag phase formed that cleanly separated from the molten metal. The physical and chemical properties of the pig iron nuggets were similar to pig iron produced by blast furnaces, which is distinct from direct reduced iron (DRI).

  7. Nitrided iron catalysts for the Fischer-Tropsch synthesis in the eighties

    SciTech Connect (OSTI)

    Anderson, R.B.

    1980-01-01

    Nitrided iron catalysts are active and durable and have an unusal selectivity. They do not produce significant amounts of wax, which should be advantageous in situations where gasoline is the desired product. The low yield of wax permits operation of nitrided iron in fluidized fixed-bed or entrained reactors at 230 to 255/sup 0/C. Conventional reduced iron catalysts in these reactors must be operated at about 325/sup 0/C to prevent formation of higher hydrocarbon that leads to agglomeration of the fluidized particles. At 325/sup 0/C carbon deposition and other processes leading to catalyst deterioration proceed rapidly. The yields of methane and ethane from nitrided iron are larger than desired for most purposes. Possibly promoters may be found to improve the selectivity of nitrided iron catalysts. The Bureau of Mines did not conduct a systematic catalyst development program on iron nitrides. (DP) 5 fgures, 6 tables.

  8. Effects of Iron Oxides on the Rheological Properties of Cementitious Slurry

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Effects of Iron Oxides on the Rheological Properties of Cementitious Slurry Citation Details In-Document Search Title: Effects of Iron Oxides on the Rheological Properties of Cementitious Slurry Iron oxide has been considered a promising host for immobilizing and encapsulating radioactive 99Tc (t1/2=2.1x105 year), which significantly enhances the stability of 99Tc within a cementitious waste form. However, the flow behavior of cementitious slurry

  9. Iron supplementation at high altitudes induces inflammation and oxidative injury to lung tissues in rats

    SciTech Connect (OSTI)

    Salama, Samir A.; Omar, Hany A.; Maghrabi, Ibrahim A.; AlSaeed, Mohammed S.; EL-Tarras, Adel E.

    2014-01-01

    Exposure to high altitudes is associated with hypoxia and increased vulnerability to oxidative stress. Polycythemia (increased number of circulating erythrocytes) develops to compensate the high altitude associated hypoxia. Iron supplementation is, thus, recommended to meet the demand for the physiological polycythemia. Iron is a major player in redox reactions and may exacerbate the high altitudes-associated oxidative stress. The aim of this study was to explore the potential iron-induced oxidative lung tissue injury in rats at high altitudes (6000 ft above the sea level). Iron supplementation (2 mg elemental iron/kg, once daily for 15 days) induced histopathological changes to lung tissues that include severe congestion, dilatation of the blood vessels, emphysema in the air alveoli, and peribronchial inflammatory cell infiltration. The levels of pro-inflammatory cytokines (IL-1?, IL-6, and TNF-?), lipid peroxidation product and protein carbonyl content in lung tissues were significantly elevated. Moreover, the levels of reduced glutathione and total antioxidant capacity were significantly reduced. Co-administration of trolox, a water soluble vitamin E analog (25 mg/kg, once daily for the last 7 days of iron supplementation), alleviated the lung histological impairments, significantly decreased the pro-inflammatory cytokines, and restored the oxidative stress markers. Together, our findings indicate that iron supplementation at high altitudes induces lung tissue injury in rats. This injury could be mediated through excessive production of reactive oxygen species and induction of inflammatory responses. The study highlights the tissue injury induced by iron supplementation at high altitudes and suggests the co-administration of antioxidants such as trolox as protective measures. - Highlights: Iron supplementation at high altitudes induced lung histological changes in rats. Iron induced oxidative stress in lung tissues of rats at high altitudes. Iron increased the levels of IL-1?, IL-6 and TNF-? in lung tissues at high altitudes. Trolox alleviated the iron-induced histological and biochemical changes to the lungs.

  10. ITmk3: High-Quality Iron Nuggets Using a Rotary Hearth Furnace | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy ITmk3: High-Quality Iron Nuggets Using a Rotary Hearth Furnace ITmk3: High-Quality Iron Nuggets Using a Rotary Hearth Furnace Steelmaking Process with a One-step Furnace Operation Uses Less Energy The industrial sector consumes 30% of all U.S. energy consumption, of which about half (1.5 quad) is consumed by iron and steel production. Despite steadily increasing demand the iron and steel industry has reduced CO2 emissions and lowered energy consumption by 30% since the early

  11. Iron and Steel Sector (NAICS 3311 and 3312) Energy and GHG Combustion Emissions Profile, November 2012

    Energy Savers [EERE]

    99 2.6 IRON AND STEEL SECTOR (NAICS 3311, 3312) 2.6.1. Overview of the Iron and Steel Manufacturing Sector The iron and steel sector is an essential part of the U.S. manufacturing sector, providing the necessary raw material for the extensive industrial supply chain. U.S. infrastructure is heavily reliant on the U.S. iron and steel sector, as it provides the foundation for construction (bridges, buildings), transportation systems (railroads, cars, trucks), utility systems (municipal water

  12. NERSC User Group 2013 Big Bang, Big Data, Big Iron Planck Satellite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2013 Big Bang, Big Data, Big Iron Planck Satellite Data Analysis At NERSC Julian Borrill Computational Cosmology Center, Berkeley Lab & Space Sciences Laboratory, UC Berkeley NERSC ...

  13. Visualization at Supercomputing Centers: The Tale of Little Big Iron and the Three Skinny Guys

    SciTech Connect (OSTI)

    Bethel, E Wes; Brugger, Eric

    2011-01-01

    Supercomputing centers are unique resources that aim to enable scientific knowledge discovery by employing large computational resources - the 'Big Iron.' Design, acquisition, installation, and management of the Big Iron are carefully planned and monitored. Because these Big Iron systems produce a tsunami of data, it's natural to colocate the visualization and analysis infrastructure. This infrastructure consists of hardware (Little Iron) and staff (Skinny Guys). Our collective experience suggests that design, acquisition, installation, and management of the Little Iron and Skinny Guys doesn't receive the same level of treatment as that of the Big Iron. This article explores the following questions about the Little Iron: How should we size the Little Iron to adequately support visualization and analysis of data coming off the Big Iron? What sort of capabilities must it have? Related questions concern the size of visualization support staff: How big should a visualization program be - that is, how many Skinny Guys should it have? What should the staff do? How much of the visualization should be provided as a support service, and how much should applications scientists be expected to do on their own?

  14. Synthesis of phase-pure and monodisperse iron oxide nanoparticles by thermal decomposition

    SciTech Connect (OSTI)

    Hufschmid, Ryan D.; Arami, Hamed; Ferguson, R. Matthew; Gonzales, Marcela; Teeman, Eric M.; Brush, Lucien N.; Browning, Nigel D.; Krishnan, Kannan M.

    2015-06-03

    We present a comprehensive template for the design and synthesis of iron oxide nanoparticles with control over size, size distribution, phase, and resulting properties. Monodisperse superparamagnetic iron oxide nanoparticles were synthesized by thermal decomposition of three different iron containing precursors (iron oleate, iron pentacarbonyl, and iron oxyhydroxide) in organic solvents under a variety of synthetic conditions. We compare the suitability of these three kinetically controlled synthesis protocols, which have in common the use of iron oleate as a starting precursor or reaction intermediate, for producing nanoparticles with specific size and magnetic properties. Monodisperse particles were produced over a tunable range of sizes from approximately 2-30 nm. Reaction parameters such as precursor concentration, addition of surfactant, temperature, ramp rate, and time were adjusted to kinetically control size and size-distribution. In particular, large quantities of excess surfactant (up to 25:1 molar ratio) alter reaction kinetics and result in larger particles with uniform size; however, there is often a trade-off between large particles and a narrow size distribution. Iron oxide phase is also critical for establishing magnetic properties. As an example, we show the importance of obtaining the required iron oxide phase for application to Magnetic Particle Imaging (MPI), and describe how phase purity can be controlled.

  15. Erosion-Corrosion of Iron and Nickel Alloys at Elevated Temperature...

    Office of Scientific and Technical Information (OSTI)

    at Elevated Temperature in a Combustion Gas Environment Citation Details In-Document Search Title: Erosion-Corrosion of Iron and Nickel Alloys at Elevated Temperature in a ...

  16. Iron repletion relocalizes hephaestin to a proximal basolateral compartment in polarized MDCK and Caco2 cells

    SciTech Connect (OSTI)

    Lee, Seung-Min [Department of Biological Sciences, University of Columbia, NY (United States) [Department of Biological Sciences, University of Columbia, NY (United States); Department of Nutritional Science and Toxicology, University of California, Berkeley, CA (United States); Attieh, Zouhair K. [Department of Laboratory Science and Technology, American University of Science and Technology, Ashrafieh (Lebanon) [Department of Laboratory Science and Technology, American University of Science and Technology, Ashrafieh (Lebanon); Department of Nutritional Science and Toxicology, University of California, Berkeley, CA (United States); Son, Hee Sook [Department of Food Science and Human Nutrition, College of Human Ecology, Chonbuk National University (Korea, Republic of) [Department of Food Science and Human Nutrition, College of Human Ecology, Chonbuk National University (Korea, Republic of); Department of Nutritional Science and Toxicology, University of California, Berkeley, CA (United States); Chen, Huijun [Medical School, Nanjing University, Nanjing 210008, Jiangsu Province (China) [Medical School, Nanjing University, Nanjing 210008, Jiangsu Province (China); Department of Nutritional Science and Toxicology, University of California, Berkeley, CA (United States); Bacouri-Haidar, Mhenia [Department of Biology, Faculty of Sciences (I), Lebanese University, Hadath (Lebanon) [Department of Biology, Faculty of Sciences (I), Lebanese University, Hadath (Lebanon); Department of Nutritional Science and Toxicology, University of California, Berkeley, CA (United States); Vulpe, Chris D., E-mail: vulpe@berkeley.edu [Department of Nutritional Science and Toxicology, University of California, Berkeley, CA (United States)

    2012-05-11

    Highlights: Black-Right-Pointing-Pointer Hephaestin localizes in the perinuclear space in non-polarized cells. Black-Right-Pointing-Pointer Hephaestin localizes in the perinuclear space in iron deficient and polarized cells. Black-Right-Pointing-Pointer Hephaestin with apical iron moves near to basolateral membrane of polarized cells. Black-Right-Pointing-Pointer Peri-basolateral location of hephaestin is accessible to the extracellular space. Black-Right-Pointing-Pointer Hephaestin is involved in iron mobilization from the intestine to circulation. -- Abstract: While intestinal cellular iron entry in vertebrates employs multiple routes including heme and non-heme routes, iron egress from these cells is exclusively channeled through the only known transporter, ferroportin. Reduced intestinal iron export in sex-linked anemia mice implicates hephaestin, a ferroxidase, in this process. Polarized cells are exposed to two distinct environments. Enterocytes contact the gut lumen via the apical surface of the cell, and through the basolateral surface, to the body. Previous studies indicate both local and systemic control of iron uptake. We hypothesized that differences in iron availability at the apical and/or basolateral surface may modulate iron uptake via cellular localization of hephaestin. We therefore characterized the localization of hephaestin in two models of polarized epithelial cell lines, MDCK and Caco2, with varying iron availability at the apical and basolateral surfaces. Our results indicate that hephaestin is expressed in a supra-nuclear compartment in non-polarized cells regardless of the iron status of the cells and in iron deficient and polarized cells. In polarized cells, we found that both apical (as FeSO{sub 4}) and basolateral iron (as the ratio of apo-transferrin to holo-transferrin) affect mobilization of hephaestin from the supra-nuclear compartment. We find that the presence of apical iron is essential for relocalization of hephaestin to a cellular compartment in close proximity but not overlapping with the basolateral surface. Surface biotinylation studies indicate that hephaestin in the peri-basolateral location is accessible to the extra-cellular environment. These results support the hypothesis that hephaestin is involved in iron mobilization of iron from the intestine to circulation.

  17. Assessing the Role of Iron Sulfides in the Long Term Sequestration...

    Office of Scientific and Technical Information (OSTI)

    Research at ASU, focused on the biogenesis aspects, examined the biogeochemical bases for iron-sulfide production by Desulfovibrio vulgaris, a Gram-negative bacterium that is one ...

  18. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.; Franco, S.C.S.

    1994-03-29

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications. 6 figures.

  19. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, Lynn A.; Sales, Brian C.; Franco, Sofia C. S.

    1994-01-01

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications.

  20. Iron catalyst for preparation of polymethylene from synthesis gas

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY)

    1990-01-01

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a cabon monoxide containing gas to a product which could substitute for high density polyethylene.

  1. New iron catalyst for preparation of polymethylene from synthesis gas

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.

    1988-03-31

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  2. An Octahedral Coordination Complex of Iron(VI)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iron is the most abundant transition element on earth, and is typically found in formal oxidation states of either II or III. However, high valent Fe(IV) and Fe(V) complexes are invoked in the mechanisms of both heme and non-heme enzymes; and Fe(VI) is known to exist in the mineral ferrate.[1] Ferrate is a powerful oxidant, which has been used in soil and wastewater treatment, batteries, and disinfectants; however, it is unstable and often indiscriminately reactive. This has driven chemists to

  3. Thermo-Mechanical Processing and Properties of a Ductile Iron

    SciTech Connect (OSTI)

    Syn, C.K.; Lesuer, R.R.; Sherby, O.D.

    1997-07-14

    Thermo-mechanical processing of ductile irons is a potential method for enhancing their mechanical properties. A ductile cast iron containing 3.6% C, 2.6% Si and 0.045% Mg was continuously hot-and-warm rolled or one-step press-forged from a temperature in the austenite range (900{degrees}C-1100{degrees}C) to a temperature below the A, temperature. Various amounts of reduction were used (from 60% to more than 90%) followed by a short heat ent at 600`C. The heat ent lead to a structure of fine graphite in a matrix of ferrite and carbides. The hot-and- warm worked materials developed a pearlitic microstructure while the press-forged material developed a spheroidite-like carbide microstructure in the matrix. Cementite-denuded ferrite zones were developed around graphite stringers in the hot-and-warm worked materials, but such zones were absent in the press-forged material. Tensile properties including tensile strength and total elongation were measured along the direction parallel and transverse to the rolling direction and along the direction transverse to the press-forging direction. The tensile ductility and strength both increased with a decrease in the amount of hot-and-warm working. The press- forged materials showed higher strength (645 MPa) than the hot-and-warrn worked materials (575 MPa) when compared at the same ductility level (22% elongation).

  4. Discharge model for the lithium iron-phosphate electrode

    SciTech Connect (OSTI)

    Srinivasan, Venkat; Newman, John

    2004-02-28

    This paper develops a mathematical model for lithium intercalation and phase change in an iron phosphate-based lithium-ion cell in order to understand the cause for the low power capability of the material. The juxtaposition of the two phases is assumed to be in the form of a shrinking core, where a shell of one phase covers a core of the second phase. Diffusion of lithium through the shell and the movement of the phase interface are described and incorporated into a porous electrode model consisting of two different particle sizes. Open-circuit measurements are used to estimate the composition ranges of the single-phase region. Model-experimental comparisons under constant current show that ohmic drops in the matrix phase, contact resistances between the current collector and the porous matrix, and transport limitations in the iron phosphate particle limit the power capability of the cells. Various design options, consisting of decreasing the ohmic drops, using smaller particles, and substituting the liquid electrolyte by a gel are explored, and their relative importance discussed. The model developed in this paper can be used as a means of optimizing the cell design to suit a particular application.

  5. Electron uptake by iron-oxidizing phototrophic bacteria

    SciTech Connect (OSTI)

    Bose, A; Gardel, EJ; Vidoudez, C; Parra, EA; Girguis, PR

    2014-02-26

    Oxidation-reduction reactions underlie energy generation in nearly all life forms. Although most organisms use soluble oxidants and reductants, some microbes can access solid-phase materials as electron-acceptors or -donors via extracellular electron transfer. Many studies have focused on the reduction of solid-phase oxidants. Far less is known about electron uptake via microbial extracellular electron transfer, and almost nothing is known about the associated mechanisms. Here we show that the iron-oxidizing photoautotroph Rhodopseudomonas palustris TIE-1 accepts electrons from a poised electrode, with carbon dioxide as the sole carbon source/electron acceptor. Both electron uptake and ruBisCo form I expression are stimulated by light. Electron uptake also occurs in the dark, uncoupled from photosynthesis. Notably, the pioABC operon, which encodes a protein system essential for photoautotrophic growth by ferrous iron oxidation, influences electron uptake. These data reveal a previously unknown metabolic versatility of photoferrotrophs to use extracellular electron transfer for electron uptake.

  6. Deactivation by carbon of iron catalysts for indirect liquefaction

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1990-10-11

    This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for Fischer-Tropsch (FT) synthesis, the objectives of which are: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; model the rates of deactivation of the same catalysts in fixed-bed reactors. During the thirteenth quarter design of software for a computer-automated reactor system to be used in the kinetic and deactivation studies was continued. Further progress was made toward the completion of the control language, control routines, and software for operating this system. Progress was also made on the testing of the system hardware and software. H{sub 2} chemisorption capacities and activity selectivity data were also measured for three iron catalysts promoted with 1% alumina. 47 refs., 8 figs., 1 tab.

  7. Technology development for iron fisher-tropsch catalysis

    SciTech Connect (OSTI)

    Davis, B.H.

    1997-07-15

    The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. the catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the standard-catalyst developed by German workers for slurry phase synthesis, The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. the oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studies at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity, and aging characteristics.

  8. Sublattice Magnetic Relaxation in Rare Earth Iron Garnets

    SciTech Connect (OSTI)

    McCloy, John S.; Walsh, Brian

    2013-07-08

    The magnetic properties of rare earth garnets make them attractive materials for applications ranging from optical communications to magnetic refrigeration. The purpose of this research was to determine the AC magnetic properties of several rare earth garnets, in order to ascertain the contributions of various sublattices. Gd3Fe5O¬12, Gd3Ga5O12, Tb3Fe5O12, Tb3Ga5O12, and Y3Fe5O12 were synthesized by a solid state reaction of their oxides and verified by x-ray diffraction. Frequency-dependent AC susceptibility and DC magnetization were measured versus temperature (10 – 340 K). Field cooling had little effect on AC susceptibility, but large effect on DC magnetization, increasing magnetization at the lowest temperature and shifting the compensation point to lower temperatures. Data suggest that interaction of the two iron lattices results in the two frequency dependent magnetic relaxations in the iron garnets, which were fit using the Vogel-Fulcher and Arrhenius laws.

  9. Fischer–Tropsch Synthesis: Characterization Rb Promoted Iron Catalyst

    SciTech Connect (OSTI)

    Sarkar,A.; Jacobs, G.; Ji, Y.; Hamdeh, H.; Davis, B.

    2008-01-01

    Rubidium promoted iron Fischer-Tropsch synthesis (FTS) catalysts were prepared with two Rb/Fe atomic ratios (1.44/100 and 5/100) using rubidium nitrate and rubidium carbonate as rubidium precursors. Results of catalytic activity and deactivation studies in a CSTR revealed that rubidium promoted catalysts result in a steady conversion with a lower deactivation rate than that of the corresponding unpromoted catalyst although the initial activity of the promoted catalyst was almost half that of the unpromoted catalyst. Rubidium promotion results in lower methane production, and higher CO2, alkene and 1-alkene fraction in FTS products. M{umlt o}ssbauer spectroscopic measurements of CO activated and working catalyst samples indicated that the composition of the iron carbide phase formed after carbidization was -Fe5 C2 for both promoted and unpromoted catalysts. However, in the case of the rubidium promoted catalyst, '-Fe2.2C became the predominant carbidic phase as FTS continued and the overall catalyst composition remained carbidic in nature. In contrast, the carbide content of the unpromoted catalyst was found to decline very quickly as a function of synthesis time. Results of XANES and EXAFS measurements suggested that rubidium was present in the oxidized state and that the compound most prevalent in the active catalyst samples closely resembled that of rubidium carbonate.

  10. Technology Development for Iron Fischer-Tropsch Catalysis.

    SciTech Connect (OSTI)

    Davis, B.H.

    1997-12-16

    The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the `standard-catalyst` developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

  11. Spectral induced polarization and electrodic potential monitoring of microbially mediated iron sulfide transformations

    SciTech Connect (OSTI)

    Hubbard, Susan; Personna, Y.R.; Ntarlagiannis, D.; Slater, L.; Yee, N.; O'Brien, M.; Hubbard, S.

    2008-02-15

    Stimulated sulfate-reduction is a bioremediation technique utilized for the sequestration of heavy metals in the subsurface.We performed laboratory column experiments to investigate the geoelectrical response of iron sulfide transformations by Desulfo vibriovulgaris. Two geoelectrical methods, (1) spectral induced polarization (SIP), and (2) electrodic potential measurements, were investigated. Aqueous geochemistry (sulfate, lactate, sulfide, and acetate), observations of precipitates (identified from electron microscopy as iron sulfide), and electrodic potentials on bisulfide ion (HS) sensitive silver-silver chloride (Ag-AgCl) electrodes (630 mV) were diagnostic of induced transitions between an aerobic iron sulfide forming conditions and aerobic conditions promoting iron sulfide dissolution. The SIP data showed 10m rad anomalies during iron sulfide mineralization accompanying microbial activity under an anaerobic transition. These anomalies disappeared during iron sulfide dissolution under the subsequent aerobic transition. SIP model parameters based on a Cole-Cole relaxation model of the polarization at the mineral-fluid interface were converted to (1) estimated biomineral surface area to pore volume (Sp), and (2) an equivalent polarizable sphere diameter (d) controlling the relaxation time. The temporal variation in these model parameters is consistent with filling and emptying of pores by iron sulfide biofilms, as the system transitions between anaerobic (pore filling) and aerobic (pore emptying) conditions. The results suggest that combined SIP and electrodic potential measurements might be used to monitor spatiotemporal variability in microbial iron sulfide transformations in the field.

  12. GLASSES CONTAINING IRON (II III) OXIDES FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM

    SciTech Connect (OSTI)

    KRUGER AA; HEO J; XU K; CHOI JK; HRMA PR; UM W

    2011-11-07

    Technetium-99 (Tc-99) has posed serious environmental threats as US Department of Energy's high-level waste. This work reports the vitrification of Re, as surrogate for Tc-99, by iron-borosilicate and iron-phosphate glasses, respectively. Iron-phosphate glasses can dissolve Re as high as {approx} 1.2 wt. %, which can become candidate waste forms for Tc-99 disposal, while borosilicate glasses can retain less than 0.1 wt. % of Re due to high melting temperature and long melting duration. Vitrification of Re as Tc-99's mimic was investigated using iron-borosilicate and iron-phosphate glasses. The retention of Re in borosilicate glasses was less than 0.1 wt. % and more than 99 wt. % of Re were volatilized due to high melting temperature and long melting duration. Because the retention of Re in iron-phosphate glasses is as high as 1.2 wt. % and the volatilization is reduced down to {approx}50 wt. %, iron-phosphate glasses can be one of the glass waste form candidates for Tc (or Re) disposal. The investigations of chemical durability and leaching test of iron-phosphate glasses containing Re are now underway to test the performance of the waste form.

  13. Visualization at Supercomputing Centers: The Tale of Little Big Iron and the Three Skinny Guys

    SciTech Connect (OSTI)

    Bethel, E. Wes; van Rosendale, John; Southard, Dale; Gaither, Kelly; Childs, Hank; Brugger, Eric; Ahern, Sean

    2010-12-01

    Supercomputing Centers (SC's) are unique resources that aim to enable scientific knowledge discovery through the use of large computational resources, the Big Iron. Design, acquisition, installation, and management of the Big Iron are activities that are carefully planned and monitored. Since these Big Iron systems produce a tsunami of data, it is natural to co-locate visualization and analysis infrastructure as part of the same facility. This infrastructure consists of hardware (Little Iron) and staff (Skinny Guys). Our collective experience suggests that design, acquisition, installation, and management of the Little Iron and Skinny Guys does not receive the same level of treatment as that of the Big Iron. The main focus of this article is to explore different aspects of planning, designing, fielding, and maintaining the visualization and analysis infrastructure at supercomputing centers. Some of the questions we explore in this article include:"How should the Little Iron be sized to adequately support visualization and analysis of data coming off the Big Iron?" What sort of capabilities does it need to have?" Related questions concern the size of visualization support staff:"How big should a visualization program be (number of persons) and what should the staff do?" and"How much of the visualization should be provided as a support service, and how much should applications scientists be expected to do on their own?"

  14. Chemically bonded phosphate ceramics of trivalent oxides of iron and manganese

    DOE Patents [OSTI]

    Wagh, Arun S.; Jeong, Seung-Young

    2002-01-01

    A new method for combining elemental iron and other metals to form an inexpensive ceramic to stabilize arsenic, alkaline red mud wastes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast.

  15. Evolution of iron-containing defects during processing of Si solar cells

    SciTech Connect (OSTI)

    Mchedlidze, Teimuraz Weber, Jrg; Mller, Christian; Lauer, Kevin

    2014-12-28

    The formation of iron-containing defects was studied during the fabrication process of a Si solar cell. Three Cz-Si crystals with different iron content in the feedstock were grown for the study. Iron-containing defects in and near-to the n{sup +}p-junction volume (NJV) of the cells are formed directly after phosphorus diffusion due to an inflow of iron atoms from the dissolving iron-silicide precipitates. These NJV-defects strongly affect the dark saturation current of the junctions. Partial dissolution or gettering of the NJV-defects during formation of the antireflection coating is accompanied by an increase in defect concentrations in the bulk of the cell. Further deterioration of bulk carrier lifetime during the formation of electrical contacts is related to the partial dissolution of remaining iron-silicide precipitates during the firing process. A general description of the defect evolution in iron-contaminated wafers during solar cell processing is presented and possible strategies for reducing the influence of iron-containing defects are proposed.

  16. Attrition resistant bulk iron catalysts and processes for preparing and using same

    DOE Patents [OSTI]

    Jothimurugesan, Kandaswamy; Goodwin, Jr., James G.; Gangwal, Santosh K.

    2007-08-21

    An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.

  17. Pore-scale investigation on stress-dependent characteristics of granular packs and the impact of pore deformation on fluid distribution

    SciTech Connect (OSTI)

    Yoon, Hongkyu; Klise, Katherine A.; Torrealba, Victor A.; Karpyn, Zuleima T.; Crandall, D.

    2015-05-25

    Understanding the effect of changing stress conditions on multiphase flow in porous media is of fundamental importance for many subsurface activities including enhanced oil recovery, water drawdown from aquifers, soil confinement, and geologic carbon storage. Geomechanical properties of complex porous systems are dynamically linked to flow conditions, but their feedback relationship is often oversimplified due to the difficulty of representing pore-scale stress deformation and multiphase flow characteristics in high fidelity. In this work, we performed pore-scale experiments of single- and multiphase flow through bead packs at different confining pressure conditions to elucidate compaction-dependent characteristics of granular packs and their impact on fluid flow. A series of drainage and imbibition cycles were conducted on a water-wet, soda-lime glass bead pack under varying confining stress conditions. Simultaneously, X-ray micro-CT was used to visualize and quantify the degree of deformation and fluid distribution corresponding with each stress condition and injection cycle. Micro-CT images were segmented using a gradient-based method to identify fluids (e.g., oil and water), and solid phase redistribution throughout the different experimental stages. Changes in porosity, tortuosity, and specific surface area were quantified as a function of applied confining pressure. Results demonstrate varying degrees of sensitivity of these properties to confining pressure, which suggests that caution must be taken when considering scalability of these properties for practical modeling purposes. Changes in capillary number with confining pressure are attributed to the increase in pore velocity as a result of pore contraction. Furthermore, this increase in pore velocity was found to have a marginal impact on average phase trapping at different confining pressures.

  18. Pore-scale investigation on stress-dependent characteristics of granular packs and the impact of pore deformation on fluid distribution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yoon, Hongkyu; Klise, Katherine A.; Torrealba, Victor A.; Karpyn, Zuleima T.; Crandall, D.

    2015-05-25

    Understanding the effect of changing stress conditions on multiphase flow in porous media is of fundamental importance for many subsurface activities including enhanced oil recovery, water drawdown from aquifers, soil confinement, and geologic carbon storage. Geomechanical properties of complex porous systems are dynamically linked to flow conditions, but their feedback relationship is often oversimplified due to the difficulty of representing pore-scale stress deformation and multiphase flow characteristics in high fidelity. In this work, we performed pore-scale experiments of single- and multiphase flow through bead packs at different confining pressure conditions to elucidate compaction-dependent characteristics of granular packs and their impactmore » on fluid flow. A series of drainage and imbibition cycles were conducted on a water-wet, soda-lime glass bead pack under varying confining stress conditions. Simultaneously, X-ray micro-CT was used to visualize and quantify the degree of deformation and fluid distribution corresponding with each stress condition and injection cycle. Micro-CT images were segmented using a gradient-based method to identify fluids (e.g., oil and water), and solid phase redistribution throughout the different experimental stages. Changes in porosity, tortuosity, and specific surface area were quantified as a function of applied confining pressure. Results demonstrate varying degrees of sensitivity of these properties to confining pressure, which suggests that caution must be taken when considering scalability of these properties for practical modeling purposes. Changes in capillary number with confining pressure are attributed to the increase in pore velocity as a result of pore contraction. Furthermore, this increase in pore velocity was found to have a marginal impact on average phase trapping at different confining pressures.« less

  19. A study of kinetics and mechanisms of iron ore reduction in ore/coal composites

    SciTech Connect (OSTI)

    Sun, S.; Lu, W.K.

    1996-12-31

    Blast furnace ironmaking technology, by far the most important ironmaking process, is based on coke and iron ore pellets (or sinter) to produce liquid iron. However, there has been a worldwide effort searching for a more economical and environmental friendly alternative process for the production of liquid iron. The essential requirement is that it should be minimized in the usage of metallurgical coke and agglomerate of iron ore concentrates. With iron ore concentrate and coal as raw materials, there are two approaches: (a) Smelting reduction; melting the ore before reduction; (b) Reduction of the ore in solid state followed by melting. The present work is on the fundamentals of the latter. It consists of a better designed experimental study including pressure gradient measurement, and a more rigorous non-isothermal and non-isobaric mathematical model. Results of this work may be applied to carbothermic processes, such as FASTMET and LB processes, as well as recycling of fines in steel plants.

  20. X-ray absorption spectroscopic studies of mononuclear non-heme iron enzymes

    SciTech Connect (OSTI)

    Westre, T.E.

    1996-01-01

    Fe-K-edge X-ray absorption spectroscopy (XAS) has been used to investigate the electronic and geometric structure of the iron active site in non-heme iron enzymes. A new theoretical extended X-ray absorption fine structure (EXAFS) analysis approach, called GNXAS, has been tested on data for iron model complexes to evaluate the utility and reliability of this new technique, especially with respect to the effects of multiple-scattering. In addition, a detailed analysis of the 1s{yields}3d pre-edge feature has been developed as a tool for investigating the oxidation state, spin state, and geometry of iron sites. Edge and EXAFS analyses have then been applied to the study of non-heme iron enzyme active sites.

  1. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2004-04-27

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  2. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2004-07-28

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  3. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon; Reina Calderon

    2004-01-27

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  4. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2005-01-25

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  5. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2005-01-26

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  6. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2006-01-30

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets, briquettes, sinter and coke.

  7. Phase II Calderon Process to Produce Direct Reduced Iron Research and Development Project

    SciTech Connect (OSTI)

    Albert Calderon

    2007-03-31

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase 1 was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets, briquettes, sinter and coke.

  8. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2005-07-29

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  9. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2006-04-19

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets, briquettes, sinter and coke.

  10. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2004-10-28

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. In 2000, U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy by using iron ore concentrate and coal as raw materials, both materials being appreciably lower in cost than using iron pellets and coke.

  11. Blockage of mitochondrial calcium uniporter prevents iron accumulation in a model of experimental subarachnoid hemorrhage

    SciTech Connect (OSTI)

    Yan, Huiying; Hao, Shuangying; Sun, Xiaoyan; Zhang, Dingding; Gao, Xin; Yu, Zhuang; Li, Kuanyu; Hang, Chun-Hua

    2015-01-24

    Highlights: • Iron accumulation was involved in the acute phase following SAH. • Blockage of MCU could attenuate cellular iron accumulation following SAH. • Blockage of MCU could decrease ROS generation and improve cell energy supply following SAH. • Blockage of MCU could alleviate apoptosis and brain injury following SAH. - Abstract: Previous studies have shown that iron accumulation is involved in the pathogenesis of brain injury following subarachnoid hemorrhage (SAH) and chelation of iron reduced mortality and oxidative DNA damage. We previously reported that blockage of mitochondrial calcium uniporter (MCU) provided benefit in the early brain injury after experimental SAH. This study was undertaken to identify whether blockage of MCU could ameliorate iron accumulation-associated brain injury following SAH. Therefore, we used two reagents ruthenium red (RR) and spermine (Sper) to inhibit MCU. Sprague–Dawley (SD) rats were randomly divided into four groups including sham, SAH, SAH + RR, and SAH + Sper. Biochemical analysis and histological assays were performed. The results confirmed the iron accumulation in temporal lobe after SAH. Interestingly, blockage of MCU dramatically reduced the iron accumulation in this area. The mechanism was revealed that inhibition of MCU reversed the down-regulation of iron regulatory protein (IRP) 1/2 and increase of ferritin. Iron–sulfur cluster dependent-aconitase activity was partially conserved when MCU was blocked. In consistence with this and previous report, ROS levels were notably reduced and ATP supply was rescued; levels of cleaved caspase-3 dropped; and integrity of neurons in temporal lobe was protected. Taken together, our results indicated that blockage of MCU could alleviate iron accumulation and the associated injury following SAH. These findings suggest that the alteration of calcium and iron homeostasis be coupled and MCU be considered to be a therapeutic target for patients suffering from SAH.

  12. The nature of iron deposits differs between symptomatic and asymptomatic carotid atherosclerotic plaques

    SciTech Connect (OSTI)

    Kopriva, David; Kisheev, Anastasye; Meena, Deiter; Pelle, Shaneen; Karnitsky, Max; Lavoie, Andrea; Buttigieg, Josef; Hagemeyer, Christoph E.

    2015-11-25

    Iron within atherosclerotic plaque has been implicated as a catalyst of oxidative stress that causes progression of plaque, and plaque rupture. Iron is believed to accumulate within plaque by incorporation of erythrocytes following plaque rupture and hemorrhage. There is only indirect evidence to support this hypothesis. Plaque specimens were obtained from ten symptomatic and fifteen asymptomatic patients undergoing carotid endarterectomy at a single institution. Plaques were sectioned for study using synchrotron radiation induced X-ray fluorescence the study the distribution of zinc, calcium and iron. Histologic staining was carried out with Prussian Blue, and immunohistochemical staining was done to localize macrophages with CD68. Data were compared against patient clinical variables. Ten symptomatic (15 ± 10 days between index symptoms and surgery) and fifteen asymptomatic carotid plaques were studied. Zinc and calcium co-localized in mineralized areas of symptomatic and asymptomatic plaque. Iron was identified away from zinc and calcium in both symptomatic and asymptomatic plaques. Within the symptomatic plaques, iron was found within the thrombus associated with plaque rupture and hemorrhage. It did not stain with Prussian Blue, but was found in association with CD68 positive macrophages. In symptomatic plaques, the abundance of iron showed an association with the source patient’s LDL cholesterol (R2 = 0.39, Significance F = 0.05). Iron in asymptomatic plaque was present as hemosiderin/ferritin that stained positive with Prussian Blue, and was observed in association with CD68 positive macrophages. Iron in acutely symptomatic plaques is found within thrombus, in the presence of macrophages. Moreover, the abundance of iron in symptomatic plaques is associated with the source patient’s LDL cholesterol. Within asymptomatic plaques, iron is found in association with macrophages, as hemosiderin/ferritin.

  13. The nature of iron deposits differs between symptomatic and asymptomatic carotid atherosclerotic plaques

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kopriva, David; Kisheev, Anastasye; Meena, Deiter; Pelle, Shaneen; Karnitsky, Max; Lavoie, Andrea; Buttigieg, Josef; Hagemeyer, Christoph E.

    2015-11-25

    Iron within atherosclerotic plaque has been implicated as a catalyst of oxidative stress that causes progression of plaque, and plaque rupture. Iron is believed to accumulate within plaque by incorporation of erythrocytes following plaque rupture and hemorrhage. There is only indirect evidence to support this hypothesis. Plaque specimens were obtained from ten symptomatic and fifteen asymptomatic patients undergoing carotid endarterectomy at a single institution. Plaques were sectioned for study using synchrotron radiation induced X-ray fluorescence the study the distribution of zinc, calcium and iron. Histologic staining was carried out with Prussian Blue, and immunohistochemical staining was done to localize macrophagesmore » with CD68. Data were compared against patient clinical variables. Ten symptomatic (15 ± 10 days between index symptoms and surgery) and fifteen asymptomatic carotid plaques were studied. Zinc and calcium co-localized in mineralized areas of symptomatic and asymptomatic plaque. Iron was identified away from zinc and calcium in both symptomatic and asymptomatic plaques. Within the symptomatic plaques, iron was found within the thrombus associated with plaque rupture and hemorrhage. It did not stain with Prussian Blue, but was found in association with CD68 positive macrophages. In symptomatic plaques, the abundance of iron showed an association with the source patient’s LDL cholesterol (R2 = 0.39, Significance F = 0.05). Iron in asymptomatic plaque was present as hemosiderin/ferritin that stained positive with Prussian Blue, and was observed in association with CD68 positive macrophages. Iron in acutely symptomatic plaques is found within thrombus, in the presence of macrophages. Moreover, the abundance of iron in symptomatic plaques is associated with the source patient’s LDL cholesterol. Within asymptomatic plaques, iron is found in association with macrophages, as hemosiderin/ferritin.« less

  14. Iron/potassium perchlorate pellet burn rate measurements

    SciTech Connect (OSTI)

    Reed, J.W.; Walters, R.R.

    1995-01-25

    A burn rate test having several advantages for low gas-producing pyrotechnic compacts has been developed. The technique involves use of a high speed video motion analysis system that allows immediate turnaround and produces all required data for rate computation on magnetic tape and becomes immediately available on the display screen. The test technique provides a quick method for material qualification along with data for improved reliability and function. Burn rate data has been obtained for both UPI and Eagle Pitcher Iron/Potassium Perchlorate blends. The data obtained for the UPI blends cover a range of composition, pellet density, and ambient (before ignition) pellet temperature. Burn rate data for the E-P blends were extended to include surface conditions or particle size as a variable parameter.

  15. Exploring the structure of high temperature, iron-bearing liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wilding, Martin; Benmore, Chris; Weber, Rick; Parise, John; Lazareva, Lena; Skinner, Lawrie; Alderman, Oliver; Tamalonis, Antony

    2015-06-25

    This paper describes the direct measurements of the structure of iron-bearing liquids using a combination of containerless techniques and in–situ high energy x-ray diffraction. These capabilities provide data that is important to help model and optimize processes such as smelting, steel making, and controlling slag chemistry. A successful programme of liquid studies has been undertaken and the Advanced Photon Source using these combined techniques which include the provision of gas mixing and the control of pO₂ and the changing influence of mixed valance elements. It is possible to combine rapid image acquisition with quenching of liquids to obtain the fullmore » diffraction patterns of deeply supercooled liquids and the metastable supercooled liquid regime, where the liquid structures and viscosity change most dramatically, can also be explored.« less

  16. Organic binders for iron ore pelletization and steelmaking

    SciTech Connect (OSTI)

    Karkoska, D.; Sankey, E.; Anderson, R.

    1995-12-01

    Historically, bentonite has been used in the agglomeration process in North American iron ore plants. In 1986, Eveleth Mines replaced bentonite with Peridur, a carboxy methyl cellulose organic binder used in conjunction with 1% limestone. Since May of 1993, Allied Colloids` Alcotac FE8 has been used by Eveleth as the replacement for bentonite. This paper discusses the performance benefits obtained when bentonite was replaced with an organic binder. These totally synthetic binders are used in conjunction with limestone. The benefits of organic binders are: improved metallurgical parameters of the fired pellet, especially the reducibility, which results in more efficient use of gases in the blast furnace; reduced silica in the pellet, in the case of Eveleth Mines this was a reduction of 0.5%, a lower silica pellet reduces slag in the blast furnace; increased production in both the agglomeration/induration and steelmaking processes; and a decrease in coke consumption.

  17. Innovative environmental investigation techniques for iron and steel facilities

    SciTech Connect (OSTI)

    Hullinger, J.P.; Skubak, J.; Hawthorne, D.S.; Swales, A.C.

    1997-02-01

    Closed or curtailed iron and steelmaking facilities represent a substantial resource to US industry as the US steel industry rationalizes and retools to meet the demands of the world marketplace. Recently, many states have begun to enact legislation aimed at encouraging reuse of such facilities. Therefore, interest in evaluating them as to environmental status is increasing. A number of relatively new investigative techniques are available that can allow an environmental site assessment or other environmental investigation to proceed more quickly and/or at less cost. This article discussed the following methods: Direct-use technology for sampling groundwater, subsurface soil and soil gas; immunoassay field screening for organic contaminants; and close-support (field mobilized) analytical laboratory. Different approaches for sequencing investigative and remediation efforts are also discussed, building upon the observational method for site investigation and clean up.

  18. Development of Improved Iron-Aluminide Filter Tubes and Elements

    SciTech Connect (OSTI)

    Judkins, R.R.; Sutton, T.G.; Miller, C.J.; Tortorelli, P.F.

    2008-01-14

    The purpose of this Cooperative Research and Development Agreement (CRADA) was to explore and develop advanced manufacturing techniques to fabricate sintered iron-aluminide intermetallic porous bodies used for gas filtration so as to reduce production costs while maintaining or improving performance in advanced coal gasification and combustion systems. The use of a power turbine fired with coal-derived synthesis gas requires some form of gas cleaning in order to protect turbine and downstream components from degradation by erosion, corrosion, and/or deposition. Hot-gas filtration is one form of cleaning that offers the ability to remove particles from the gases produced by gasification processes without having to substantially cool and, possibly, reheat them before their introduction into the turbine. This technology depends critically on materials durability and reliability, which have been the subject of study for a number of years.

  19. Exploring the structure of high temperature, iron-bearing liquids

    SciTech Connect (OSTI)

    Wilding, Martin; Benmore, Chris; Weber, Rick; Parise, John; Lazareva, Lena; Skinner, Lawrie; Alderman, Oliver; Tamalonis, Antony

    2015-06-25

    This paper describes the direct measurements of the structure of iron-bearing liquids using a combination of containerless techniques and insitu high energy x-ray diffraction. These capabilities provide data that is important to help model and optimize processes such as smelting, steel making, and controlling slag chemistry. A successful programme of liquid studies has been undertaken and the Advanced Photon Source using these combined techniques which include the provision of gas mixing and the control of pO? and the changing influence of mixed valance elements. It is possible to combine rapid image acquisition with quenching of liquids to obtain the full diffraction patterns of deeply supercooled liquids and the metastable supercooled liquid regime, where the liquid structures and viscosity change most dramatically, can also be explored.

  20. Deactivation by carbon of iron catalysts for indirect liquefaction

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1990-10-29

    This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for synthesis, the objectives of which are: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; model the rates of deactivation of the same catalysts in fixed-bed reactors. During the fourteenth quarter design of software for a computer-automated reactor system to be used in the kinetic and deactivation studies was continued. Further progress was made toward the completion of the control language, control routines, and software for operating this system. Progress was also made towards testing of the system hardware and software. 47 refs.

  1. High strength nickel-chromium-iron austenitic alloy

    DOE Patents [OSTI]

    Gibson, Robert C.; Korenko, Michael K.

    1980-01-01

    A solid solution strengthened Ni-Cr-Fe alloy capable of retaining its strength at high temperatures and consisting essentially of 42 to 48% nickel, 11 to 13% chromium, 2.6 to 3.4% niobium, 0.2 to 1.2% silicon, 0.5 to 1.5% vanadium, 2.6 to 3.4% molybdenum, 0.1 to 0.3% aluminum, 0.1 to 0.3% titanium, 0.02 to 0.05% carbon, 0.002 to 0.015% boron, up to 0.06 zirconium, and the balance iron. After solution annealing at 1038.degree. C. for one hour, the alloy, when heated to a temperature of 650.degree. C., has a 2% yield strength of 307 MPa, an ultimate tensile strength of 513 MPa and a rupture strength of as high as 400 MPa after 100 hours.

  2. A High-Performance Rechargeable Iron Electrode for Large-Scale Battery-Based Energy Storage

    SciTech Connect (OSTI)

    Manohar, AK; Malkhandi, S; Yang, B; Yang, C; Prakash, GKS; Narayanan, SR

    2012-01-01

    Inexpensive, robust and efficient large-scale electrical energy storage systems are vital to the utilization of electricity generated from solar and wind resources. In this regard, the low cost, robustness, and eco-friendliness of aqueous iron-based rechargeable batteries are particularly attractive and compelling. However, wasteful evolution of hydrogen during charging and the inability to discharge at high rates have limited the deployment of iron-based aqueous batteries. We report here new chemical formulations of the rechargeable iron battery electrode to achieve a ten-fold reduction in the hydrogen evolution rate, an unprecedented charging efficiency of 96%, a high specific capacity of 0.3 Ah/g, and a twenty-fold increase in discharge rate capability. We show that modifying high-purity carbonyl iron by in situ electro-deposition of bismuth leads to substantial inhibition of the kinetics of the hydrogen evolution reaction. The in situ formation of conductive iron sulfides mitigates the passivation by iron hydroxide thereby allowing high discharge rates and high specific capacity to be simultaneously achieved. These major performance improvements are crucial to advancing the prospect of a sustainable large-scale energy storage solution based on aqueous iron-based rechargeable batteries. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.034208jes] All rights reserved.

  3. Energy Saving Melting and Revert Reduction Technology: Aging of Graphitic Cast Irons and Machinability

    SciTech Connect (OSTI)

    Von L. Richards

    2012-09-19

    The objective of this task was to determine whether ductile iron and compacted graphite iron exhibit age strengthening to a statistically significant extent. Further, this effort identified the mechanism by which gray iron age strengthens and the mechanism by which age-strengthening improves the machinability of gray cast iron. These results were then used to determine whether age strengthening improves the machinability of ductile iron and compacted graphite iron alloys in order to develop a predictive model of alloy factor effects on age strengthening. The results of this work will lead to reduced section sizes, and corresponding weight and energy savings. Improved machinability will reduce scrap and enhance casting marketability. Technical Conclusions: ???¢???????¢ Age strengthening was demonstrated to occur in gray iron ductile iron and compacted graphite iron. ???¢???????¢ Machinability was demonstrated to be improved by age strengthening when free ferrite was present in the microstructure, but not in a fully pearlitic microstructure. ???¢???????¢ Age strengthening only occurs when there is residual nitrogen in solid solution in the Ferrite, whether the ferrite is free ferrite or the ferrite lamellae within pearlite. ???¢???????¢ Age strengthening can be accelerated by Mn at about 0.5% in excess of the Mn/S balance Estimated energy savings over ten years is 13.05 trillion BTU, based primarily on yield improvement and size reduction of castings for equivalent service. Also it is estimated that the heavy truck end use of lighter castings for equivalent service requirement will result in a diesel fuel energy savings of 131 trillion BTU over ten years.

  4. Assessing the Role of Iron Sulfides in the Long Term Sequestration of

    Office of Scientific and Technical Information (OSTI)

    Uranium by Sulfate-Reducing Bacteria (Technical Report) | SciTech Connect Assessing the Role of Iron Sulfides in the Long Term Sequestration of Uranium by Sulfate-Reducing Bacteria Citation Details In-Document Search Title: Assessing the Role of Iron Sulfides in the Long Term Sequestration of Uranium by Sulfate-Reducing Bacteria This overarching aim of this project was to identify the role of biogenic and synthetic iron-sulfide minerals in the long-term sequestration of reduced U(IV) formed

  5. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Khan, M. Rashid

    1989-01-01

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

  6. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Rashid Khan, M.

    1988-05-05

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

  7. Assessing the Role of Iron Sulfides in the Long Term Sequestration of

    Office of Scientific and Technical Information (OSTI)

    Uranium by Sulfate-Reducing Bacteria (Technical Report) | SciTech Connect Technical Report: Assessing the Role of Iron Sulfides in the Long Term Sequestration of Uranium by Sulfate-Reducing Bacteria Citation Details In-Document Search Title: Assessing the Role of Iron Sulfides in the Long Term Sequestration of Uranium by Sulfate-Reducing Bacteria This overarching aim of this project was to identify the role of biogenic and synthetic iron-sulfide minerals in the long-term sequestration of

  8. Assessing the Role of Iron Sulfides in the Long Term Sequestration of U by

    Office of Scientific and Technical Information (OSTI)

    Sulfate Reducing Bacteria (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Assessing the Role of Iron Sulfides in the Long Term Sequestration of U by Sulfate Reducing Bacteria Citation Details In-Document Search Title: Assessing the Role of Iron Sulfides in the Long Term Sequestration of U by Sulfate Reducing Bacteria This four-year project's overarching aim was to identify the role of biogenic and synthetic iron-sulfide minerals in the long-term

  9. Phase II Calderon Process to Produce Direct Reduced Iron Research and Development Project

    SciTech Connect (OSTI)

    Albert Calderon

    2003-06-30

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. U.S. Steel teamed up with Calderon for a joint effort which will last 42 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy.

  10. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2003-01-28

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. U.S. Steel teamed up with Calderon for a joint effort which will last 30 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy.

  11. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2003-04-28

    This project was initially targeted to the making of coke for blast furnaces by using proprietary technology of Calderon in a phased approach, and Phase I was successfully completed. The project was then re-directed to the making of iron units. U.S. Steel teamed up with Calderon for a joint effort which will last 30 months to produce directly reduced iron with the potential of converting it into molten iron or steel consistent with the Roadmap recommendations of 1998 prepared by the Steel Industry in cooperation with the Department of Energy.

  12. Watermelon-like iron nanoparticles: Cr doping effect on magnetism and magnetization interaction reversal

    SciTech Connect (OSTI)

    Kaur, Maninder; Dai, Qilin; Bowden, Mark E.; Engelhard, Mark H.; Wu, Yaqiao; Tang, Jinke; Qiang, You

    2013-06-26

    Chromium (Cr) forms a solid solution with iron (Fe) lattice when doped in core-shell iron -iron oxide nanocluster (NC) and shows a mixed phase of sigma (?) FeCr and bcc Fe. The Cr dopant affects heavily the magnetization and magnetic reversal process, and causes the hysteresis loop to shrink near the zero field axis. Dramatic transformation happens from dipolar interaction (0 at. % Cr) to strong exchange interaction (8 at. % of Cr) is confirmed from the Henkel plot and delta M plot, and is explained by a water-melon model of core-shell NC system.

  13. DISCHARGE VALVE FOR GRANULAR MATERIAL

    DOE Patents [OSTI]

    Stoughton, L.D.; Robinson, S.T.

    1962-05-15

    A gravity-red dispenser or valve is designed for discharging the fueled spherical elements used in a pebble bed reactor. The dispenser consists of an axially movable tube terminating under a hood having side walls with openings. When the tube is moved so that its top edge is above the tops of the side openings the elements will not flow. As the tube is moved downwardly, the elements flow into the hood through the side openings and over the top edge into the tube at an increasing rate as the tube is lowered further. The tube is spaced at all times from the hood and side walls a distance greater than the diameter of the largest element to prevent damaging of the elements when the dispenser is closed to flow. (AEC)

  14. Earth-abundant Solar Cells: Can Iron Complexes Serve as Photosensitize...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth-abundant Solar Cells: Can Iron Complexes Serve as Photosensitizers in DSSCs November 10, 2015 11:00AM to 12:00PM Presenter Elena Jakubikova, North Carolina State University...

  15. ITP Steel: Energy and Environmental Profile fo the U.S. Iron and Steel Industry

    Broader source: Energy.gov [DOE]

    DOE's Office of Industrial Technologes has formed a partnership with the U.S. iron and steel industry to accelerate development of technologies and processes that will improve the industry's production and energy efficiency and environmental performance.

  16. Can an Iron Man Suit Be Made?: Science Behind Superheroes | GE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can an Iron Man Suit Be Made?: Science Behind Superheroes Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new...

  17. Nitrided iron catalysts for the Fischer-Tropsch synthesis in the eighties

    SciTech Connect (OSTI)

    Anderson, R.B.

    1980-01-01

    A survey covers the preparation and structure of nitrided iron catalysts and their activity, selectivity, and stability for the reaction of synthesis gas in comparison with iron catalysts pretreated by various other methods, as measured in laboratory reactors; a comparison of product distributions obtained in fluidized-bed, slurry, and oil-circulation fixed bed pilot plants with nitrided catalysts and by the Kellogg entrained catalyst process SASOL, which uses a reduced iron catalyst; and possible methods for refining the Fischer-Tropsch products from nitrided iron catalysts for producing gasoline, including bauxite treatment, the Mobil process for converting oxygenates to high-octane gasoline and C/sub 3/-C/sub 4/ olefins, and an alkylation-polymerization process for converting the C/sub 3/-C/sub 4/ fraction to high-octane blending stocks.

  18. Thermal plasma processed ferro-magnetically ordered face-centered cubic iron at room temperature

    SciTech Connect (OSTI)

    Raut, Suyog A.; Kanhe, Nilesh S.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

    2014-10-28

    Here, we report tailor made phase of iron nanoparticles using homogeneous gas phase condensation process via thermal plasma route. It was observed that crystal lattice of nano-crystalline iron changes as a function of operating parameters of the plasma reactor. In the present investigation iron nanoparticles have been synthesized in presence of argon at operating pressures of 1251000?Torr and fixed plasma input DC power of 6?kW. It was possible to obtain pure fcc, pure bcc as well as the mixed phases for iron nanoparticles in powder form as a function of operating pressure. The as synthesized product was characterized for understanding the structural and magnetic properties by using X-ray diffraction, vibrating sample magnetometer, and Mssbauer spectroscopy. The data reveal that fcc phase is ferromagnetically ordered with high spin state, which is unusual whereas bcc phase is found to be ferromagnetic as usual. Finally, the structural and magnetic properties are co-related.

  19. The f-spin physics of rare-earth iron pnictides: influence of...

    Office of Scientific and Technical Information (OSTI)

    influence of d-electron antiferromagnetic order on heavy fermion phase diagram Citation Details In-Document Search Title: The f-spin physics of rare-earth iron pnictides: influence ...

  20. Role of copper promotion in precipitated iron Fischer-Tropsch catalysts

    SciTech Connect (OSTI)

    O`Brien, R.J.; Xu, L.; Davis, B.H.

    1996-10-01

    Slurry phase Fischer-Tropsch synthesis was conducted on precipitated iron-silicon catalysts. The affect of copper promotion on the activity and selectivity of carbon monoxide, hydrogen and syngas activated catalysts is presented. High activity and stability have been obtained for potassium promoted catalysts when operating at 270{degrees}C; however, it has been found that promotion with potassium and copper is essential to obtaining good activity in a wax producing mode at 230{degrees}C. Promotion with copper is critical to achieving good activity when pretreating catalysts with hydrogen or with syngas at high pressure. XRD and Mossbauer data indicate that copper facilitates the reduction of iron oxide to metallic iron and iron carbides during hydrogen and syngas pretreatments.

  1. Iron-niobium-aluminum alloy having high-temperature corrosion resistance

    DOE Patents [OSTI]

    Hsu, Huey S.

    1988-04-14

    An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

  2. Hydrogen storage and carbon dioxide capture in an iron-based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods Previous Next List Kenji Sumida,...

  3. Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at ~ 40 - 50

    Office of Scientific and Technical Information (OSTI)

    GPa and their Relevance to the Martian Reolith Component Present in Shergotties (Conference) | SciTech Connect Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at ~ 40 - 50 GPa and their Relevance to the Martian Reolith Component Present in Shergotties Citation Details In-Document Search Title: Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at ~ 40 - 50 GPa and their Relevance to the Martian Reolith Component Present in Shergotties Basaltic shergottites such as

  4. Melting Hanford LAW into Iron-Phosphate Glass in a CCIM (Technical Report)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Melting Hanford LAW into Iron-Phosphate Glass in a CCIM Citation Details In-Document Search Title: Melting Hanford LAW into Iron-Phosphate Glass in a CCIM A vitrification test has been conducted using the cold crucible induction melter (CCIM) test system at the Idaho National Laboratory. The test was conducted to demonstrate the vitrification of a Hanford low activity waste (LAW) that contains relatively large amounts of sulfate and sodium, compared to other radioactive

  5. Data on production and use of DRI: World and U. S. [Direct Reduced Iron

    SciTech Connect (OSTI)

    Jensen, H.B.

    1993-01-01

    This paper will present data on the production and use direct-reduced iron (DRI) worldwide, focusing primarily on its use in the United States. The author is indebted to the Midrex Corporation for the data on world production of DRI. The U.S. data is his own and he will explain later how it was collected. He uses the term DRI to include all forms of direct-reduced iron, whether briquettes, pellets or lump.

  6. Effects of dissimilatory sulfate reduction on iron (hydr)oxide reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and microbial community development | Argonne National Laboratory Effects of dissimilatory sulfate reduction on iron (hydr)oxide reduction and microbial community development May 14, 2014 Tweet EmailPrint Aquatic and terrestrial environments are dynamic systems where coupled microbiological, geochemical, and hydrological processes define the complex interactions that drive the biogeochemical cycling of the major and minor elements. For example, microbial iron and sulfate reduction profoundly

  7. Melting of clinopyroxene + magnesite in iron-bearing planetary mantles and

    Office of Scientific and Technical Information (OSTI)

    implications for the Earth and Mars (Journal Article) | SciTech Connect Melting of clinopyroxene + magnesite in iron-bearing planetary mantles and implications for the Earth and Mars Citation Details In-Document Search Title: Melting of clinopyroxene + magnesite in iron-bearing planetary mantles and implications for the Earth and Mars Authors: Martin, Audrey M. ; Righter, Kevin [1] + Show Author Affiliations (NASA-JSC) [NASA-JSC Publication Date: 2013-12-05 OSTI Identifier: 1107421 Resource

  8. Memo Is Homologous to Nonheme Iron Dioxygenases and Binds an ErbB2-derived

    Office of Scientific and Technical Information (OSTI)

    Phosphopeptide in Its Vestigial Active Site (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Memo Is Homologous to Nonheme Iron Dioxygenases and Binds an ErbB2-derived Phosphopeptide in Its Vestigial Active Site Citation Details In-Document Search Title: Memo Is Homologous to Nonheme Iron Dioxygenases and Binds an ErbB2-derived Phosphopeptide in Its Vestigial Active Site Authors: Qiu, Chen ; Lienhard, Susanne ; Hynes, Nancy E. ; Badache, Ali ; Leahy, Daniel

  9. Behavior of tritium permeation induced by water corrosion of alpha iron

    Office of Scientific and Technical Information (OSTI)

    around room temperature (Journal Article) | SciTech Connect Behavior of tritium permeation induced by water corrosion of alpha iron around room temperature Citation Details In-Document Search Title: Behavior of tritium permeation induced by water corrosion of alpha iron around room temperature Tritium (T) permeation leakage to surroundings is a great safety concern in fission and fusion reactor systems. T permeation potentially occurs from T contaminated water through cooling tubes or

  10. FEASIBILITY OF MEASURING IRON IN VIVO USING FAST 14 MEV NEUTRONS.

    SciTech Connect (OSTI)

    WIELOPOLSKI, L.

    2005-05-01

    In this short report, I reassess the feasibility of measuring iron in vivo in the liver and heart of thalassemia patients undergoing chelation therapy. Despite the multiplicity of analytical methods for analyzing iron, only two, magnetic resonance imaging, and magnetic susceptibility, are suitable for in vivo applications, and these are limited to the liver because of the heart's beat. Previously, a nuclear method, gamma-resonance scattering, offered a quantitative measure of iron in these organs; however, it was abandoned because it necessitated a nuclear reactor to produce the radioactive source. I reviewed and reassessed the status of two alternative nuclear methods, based on iron spectroscopy of gamma rays induced by fast neutron inelastic scattering and delayed activation in iron. Both are quantitative methods with high specificity for iron and adequate penetrating power to measure it in organs sited deep within the human body. My experiments demonstrated that both modalities met the stated qualitative objectives to measure iron. However, neutron dosimetry revealed that the intensity of the neutron radiation field was too weak to reliably assess the minimum detection limits, and to allow quantitative extrapolations to measurements in people. A review of the literature, included in this report, showed that these findings agree qualitatively with the published results, although the doses reported were about three orders-of-magnitude higher than those I used. Reviewing the limitations of the present work, steps were outlined for overcoming some of the shortcomings. Due to a dearth of valid quantitative alternatives for determining iron in vivo, I conclude that nuclear methods remain the only viable option. However, from the lessons learned, further systematic work is required before embarking on clinical studies.

  11. Superfluid Density in the s ± -Wave State of Clean Iron-Based

    Office of Scientific and Technical Information (OSTI)

    Superconductors (Journal Article) | SciTech Connect Superfluid Density in the s ± -Wave State of Clean Iron-Based Superconductors Citation Details In-Document Search Title: Superfluid Density in the s ± -Wave State of Clean Iron-Based Superconductors Authors: Huang, Huaixiang ; Gao, Yi ; Zhu, Jian-Xin ; Ting, C. S. Publication Date: 2012-11-02 OSTI Identifier: 1101717 Type: Publisher's Accepted Manuscript Journal Name: Physical Review Letters Additional Journal Information: Journal Volume:

  12. Theory of mixed-state effect on NMR relaxation measurements in iron

    Office of Scientific and Technical Information (OSTI)

    pnictide superconductors (Journal Article) | SciTech Connect Theory of mixed-state effect on NMR relaxation measurements in iron pnictide superconductors Citation Details In-Document Search Title: Theory of mixed-state effect on NMR relaxation measurements in iron pnictide superconductors Authors: Gao, Yi ; Zhu, Jian-Xin ; Ting, C. S. ; Su, Wu-Pei Publication Date: 2011-12-19 OSTI Identifier: 1098437 Type: Publisher's Accepted Manuscript Journal Name: Physical Review B Additional Journal

  13. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  14. Structural and valence state of iron ions in sodium-aluminum-phosphate glass

    SciTech Connect (OSTI)

    Vashman, A.A.; Pronin, I.S.; Samsonov, V.E.; Filin, V.M.

    1994-12-01

    The purpose of this paper is to study the structural and valence state of iron ions in sodium-aluminum-phosphate glass for the application of liquid radioactive waste solidification. Electron paramagnetic resonance, Moessbauer spectroscopy, and nuclear magnetic resonances were used to conduct the study. Results were used to determine the characteristics of the occupancy and distribution of iron ions over tetra- and octahedral positions as a function of the ratio of the concentration of iron and aluminum oxides, to determine the concentration of Fe{sup 3}{sup +} and Fe{sup 2}{sup +} ions and the number of phosphorus and aluminum atoms in the nearest neighbor environment of the impurity iron ions, and estimate the effect of the concentration of aluminum oxide on the average distance between the phosphorus atoms in the glass. Results indicate that it must be assumed that tetrahedral glass-forming positions of ions are more stable than octahedral positions. Therefore, the long-term fixation of iron ions in sodium-aluminum-phosphate glasses will be more reliable with lower iron-aluminum ratios. These results will apparently extend to radioactive ions due to similar valence properties. 8 refs., 4 figs., 3 tabs.

  15. Lead iron phosphate glass as a containment medium for disposal of high-level nuclear waste

    DOE Patents [OSTI]

    Boatner, Lynn A.; Sales, Brian C.

    1989-01-01

    Lead-iron phosphate glasses containing a high level of Fe.sub.2 O.sub.3 for use as a storage medium for high-level radioactive nuclear waste. By combining lead-iron phosphate glass with various types of simulated high-level nuclear waste, a highly corrosion resistant, homogeneous, easily processed glass can be formed. For corroding solutions at 90.degree. C., with solution pH values in the range between 5 and 9, the corrosion rate of the lead-iron phosphate nuclear waste glass is at least 10.sup.2 to 10.sup.3 times lower than the corrosion rate of a comparable borosilicate nuclear waste glass. The presence of Fe.sub.2 O.sub.3 in forming the lead-iron phosphate glass is critical. Lead-iron phosphate nuclear waste glass can be prepared at temperatures as low as 800.degree. C., since they exhibit very low melt viscosities in the 800.degree. to 1050.degree. C. temperature range. These waste-loaded glasses do not readily devitrify at temperatures as high as 550.degree. C. and are not adversely affected by large doses of gamma radiation in H.sub.2 O at 135.degree. C. The lead-iron phosphate waste glasses can be prepared with minimal modification of the technology developed for processing borosilicate glass nuclear wasteforms.

  16. Magnetic Nanocrystalline Films Softened by Obliquely Accelerating Iron Nanoclusters

    SciTech Connect (OSTI)

    Meyer, Daniel R.; Faheem, Mohammad; Campanell, Michael; Antony, Jiji; Sharma, Amit M.; Qiang, You

    2007-06-01

    We have generated magnetically ultrasoft thin films composed of iron nanoclusters with diameters of about 20 nm by energetic cluster impact (ECI). The clusters were created in a sputtering-gas-aggregation cluster source with approximately 40% of the particles negatively charged. The charged particles were accelerated onto substrates held at potentials of 0, 5, and 15 kV. The substrates were tilted at an angle of 30 with respect to the incident beam to generate elliptically shaped clusters and thereby induce shape anisotropy. Visible changes of the film structures were observed for increasing potential with the zero potential samples being black due to the porous nature of soft landed clusters. For the 5 and 15 kV samples, the films take on a metallic sheen due to the increased density. The magnetic properties of the films were measured by SQUID at room temperature. Dramatic softening of the films was observed for samples with applied potentials, in good agreement with the random anisotropy model. The coercivity at zero potential was measured to be 78 Oe. Along the easy axis, the coercivities of the 5 and 15 kV samples were 0.50 and 0.65 Oe and 2.06 and 2.46 Oe for the hard axis, respectively. The coercivities for the axis perpendicular to the substrates were 9.86 and 6.70 Oe. In this experiment, we have demonstrated a novel technique for directly controlling film morphology and thereby ability to custom tailor magnetic characteristics.

  17. Iron Phosphate Glass-Containing Hanford Waste Simulant

    SciTech Connect (OSTI)

    Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, M. J.; Rodriguez, Carmen P.; Kim, Dong-Sang; Riley, Brian J.

    2012-01-18

    Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

  18. Melter Throughput Enhancements for High-Iron HLW

    SciTech Connect (OSTI)

    Kruger, A. A.; Gan, Hoa; Joseph, Innocent; Pegg, Ian L.; Matlack, Keith S.; Chaudhuri, Malabika; Kot, Wing

    2012-12-26

    This report describes work performed to develop and test new glass and feed formulations in order to increase glass melting rates in high waste loading glass formulations for HLW with high concentrations of iron. Testing was designed to identify glass and melter feed formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts to assess melt rate using a vertical gradient furnace system and to develop new formulations with enhanced melt rate. Testing evaluated the effects of waste loading on glass properties and the maximum waste loading that can be achieved. The results from crucible-scale testing supported subsequent DuraMelter 100 (DM100) tests designed to examine the effects of enhanced glass and feed formulations on waste processing rate and product quality. The DM100 was selected as the platform for these tests due to its extensive previous use in processing rate determination for various HLW streams and glass compositions.

  19. Iron Phosphate Glass-Containing Hanford Waste Simulant

    SciTech Connect (OSTI)

    Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, Michael J.; Kim, Dong-Sang

    2011-08-01

    Resolution of the nation’s high level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron phosphate-based glass with a selected waste composition that is high in sulfates (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis as related to the implementation of phosphate-based glasses for Hanford low activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, and Mo-Sci Corporation.

  20. Spin transition in a four-coordinate iron oxide

    SciTech Connect (OSTI)

    Kawakami, T. [Nihon University, Tokyo; Sutou, S. [Nihon University, Tokyo; Hirama, H. [Nihon University, Tokyo; Sekiya, Y. [Nihon University, Tokyo; Makino, T. [Nihon University, Tokyo; Tsujimoto, Y. [Kyoto University, Japan; Kitada, A. [Kyoto University, Japan; Tassel, C. [Kyoto University, Japan; Kageyama, H. [Kyoto University, Japan; Yoshimura, K. [Kyoto University, Japan; Chen, Xingqiu [ORNL; Fu, Chong Long [ORNL; Okada, T. [University of Tokyo, Tokyo, Japan; Yagi, T. [University of Tokyo, Tokyo, Japan; Hayashi, N. [Kyoto University, Japan; Nasu, S. [Osaka University; Podloucky, R. [Institut fur Physikalische Chemie der RWTH; Takano, M. [Kyoto University, Japan

    2009-01-01

    The spin transition, or spin crossover, is a manifestation of electronic instability induced by external constraints such as pressure1. Among known examples that exhibit spin transition, 3d ions with d6 electron configurations represent the vast majority, but the spin transition observed thus far has been almost exclusively limited to that between high-spin (S = 2) and low-spin (S = 0) states2-9. Here we report a novel high-spin to intermediate-spin (S = 1) state transition at 33 GPa induced by pressurization of an antiferromagnetic insulator SrFeO2 with a square planar coordination10. The change in spin multiplicity brings to ferromagnetism as well as metallicity, yet keeping the ordering temperature far above ambient. First-principles calculations attribute the origin of the transition to the strong inlayer hybridization between Fe dx 2 -y 2 O p , leading to a pressure-induced electronic instability toward the depopulation of Fe dx 2 -y 2 O p antibonding states. Furthermore, the ferromagnetic S = 1 state is half-metallic due to the inception of half-occupied spin-down (dxz, dyz) degenerate states upon spin transition. These results highlight the square-planar coordinated iron oxides as a new class of magnetic and electric materials and provide new avenues toward realizing multi-functional sensors and data-storage devices.

  1. Identification of Iron-reducing Thermus strains as Thermus scotoductus

    SciTech Connect (OSTI)

    Balkwill, David L.; Kieft, T L.; Tsukuda, Toyoko; Kostandarithes, Heather M.; Onstott, T C.; Macnaughton, S.; Bownas, J.; Fredrickson, Jim K.

    2004-02-01

    Thermus strain SA-01, previously isolated from a deep (3.2) South African gold mine, is closely related to Thermus strains NMX2 A.1 and VI-7 (previously isolated from thermal springs in New Mexico USA and Portugal, respectively). Thermus strains SA-01 and NMX2 A.1 have also been shown previously to grow using nitrate, Fe(III), , Mn(IV) or So as terminal electron acceptors and to be capable of reducing Cr(VI), U(VI), Co(III), and the quinine-containing compound anthraquinone-2,6-disulfonate. The objectives of this study were to determine the phylogenetic positions of the three known metal-reducing Thermus strains and to determine the phylogenetic significance of metal reduction within the genus Thermus. Phylogenetic analyses of 16S rDNA sequences, BOX PCR genomic fingerprinting, and DNA-DNA reassociation analyses indicated that these strains belong to the previously described genospecies T. scotoductus. The morphologies and lipid fatty acid profiles of these metal-reducing strains are consistent with their identification as T. scotoductus; however, the T. scotoductus strains tested in this study evinced a wide intraspecies variability in some other phenotypic traits, e.g., carbon substrate utilization and pigmentation. Iron reduction occurred in all strains of T. scotoductus tested except the mixotrophic, sulfur-oxidizing strain IT-7254. Thermus strains belonging to other species did not reduce Fe(III) to Fe(II) or reduced it only poorly.

  2. Permeation characteristics of some iron and nickel based alloys

    SciTech Connect (OSTI)

    Mitchell, D.J.; Edge, E.M.

    1985-06-15

    The permeation characteristics of deuterium in several iron and nickel based alloys were measured by the gas phase breakthrough technique in the temperature range 100 to 500 /sup 0/C with applied pressures ranging from 10 Pa to 100 kPa. The restriction of the gas flux imposed by surface oxides was modeled in order to evaluate the effects of surface oxide retardation of the gas flux on the effective values of the deuterium permeabilities and diffusivities in the alloys. The most permeable alloys were 430 and 431 stainless steels. The next most permeable alloy was Monel K-500, which exceeded the permeability of pure Ni by more than a factor of five at room temperature. The alloys with permeabilities less than pure Ni were, in order of decreasing permeability: the Inconels 625, 718, and 750, the Fe-Ni-Co glass-sealing alloys Kovar and Ceramvar, and the 300-series stainless steels. Deuterium trapping within the alloys appeared to influence the values of bulk diffusivities, which were not correlated with either the permeabilities or the chemical compositions of the alloys.

  3. Co-Production of Electricity and Hydrogen Using a Novel Iron-based Catalyst

    SciTech Connect (OSTI)

    Hilaly, Ahmad; Georgas, Adam; Leboreiro, Jose; Arora, Salil; Head, Megann; Trembly, Jason; Turk, Brian; Gupta, Raghubir

    2011-09-30

    The primary objective of this project was to develop a hydrogen production technology for gasification applications based on a circulating fluid-bed reactor and an attrition resistant iron catalyst. The work towards achieving this objective consisted of three key activities: • Development of an iron-based catalyst suitable for a circulating fluid-bed reactor • Design, construction, and operation of a bench-scale circulating fluid-bed reactor system for hydrogen production • Techno-economic analysis of the steam-iron and the pressure swing adsorption hydrogen production processes. This report describes the work completed in each of these activities during this project. The catalyst development and testing program prepared and iron-based catalysts using different support and promoters to identify catalysts that had sufficient activity for cyclic reduction with syngas and steam oxidation and attrition resistance to enable use in a circulating fluid-bed reactor system. The best performing catalyst from this catalyst development program was produced by a commercial catalyst toll manufacturer to support the bench-scale testing activities. The reactor testing systems used during material development evaluated catalysts in a single fluid-bed reactor by cycling between reduction with syngas and oxidation with steam. The prototype SIP reactor system (PSRS) consisted of two circulating fluid-bed reactors with the iron catalyst being transferred between the two reactors. This design enabled demonstration of the technical feasibility of the combination of the circulating fluid-bed reactor system and the iron-based catalyst for commercial hydrogen production. The specific activities associated with this bench-scale circulating fluid-bed reactor systems that were completed in this project included design, construction, commissioning, and operation. The experimental portion of this project focused on technical demonstration of the performance of an iron-based catalyst and a circulating fluid-bed reactor system for hydrogen production. Although a technology can be technically feasible, successful commercial deployment also requires that a technology offer an economic advantage over existing commercial technologies. To effective estimate the economics of this steam-iron process, a techno-economic analysis of this steam iron process and a commercial pressure swing adsorption process were completed. The results from this analysis described in this report show the economic potential of the steam iron process for integration with a gasification plant for coproduction of hydrogen and electricity.

  4. Dissolution of thin iron oxide films used as models for iron passive films studied by in situ X-ray absorption near-edge spectroscopy

    SciTech Connect (OSTI)

    Virtanen, S; Schmuki, P.; Davenport, A.J.; Vitus, C.M.

    1997-01-01

    This paper reports results from X-ray absorption near-edge spectroscopy (XANES) studies during polarization of thin sputter-deposited iron oxide films in acidic solutions. The dissolution rate of iron oxides in acidic solutions was found to be strongly increased by the presence of Fe{sup 2+} in the oxide. During anodic polarization in acidic solutions, it is found that dissolution is accelerated by chloride anions in comparison with sulfates. In HCl solutions of increasing concentration, not only does the pH decrease, but also the increasing chloride concentration accelerates dissolution. On the other hand, the dissolution rate in sulfuric acid does not depend on the sulfate (bisulfate) concentration. During anodic polarization, the dissolution rate is fairly independent of the potential, except at very high anodic potentials, and the XANES spectra reveal no changes in the average oxide valence during anodic polarization. Thus the dissolution that takes place is mostly chemical rather than electrochemical. During cathodic polarization, the dissolution rate is independent of the anion in the electrolyte. The findings are interpreted in terms of the negative surface charge of n-type oxides at potentials lower than the flatband potential, retarding anion adsorption on the surface. Hence it is suggested that the detrimental role of chloride anions on the stability of iron oxide films is due to a surface complexation effect. The findings and their relevance to the stability of natural passive films on iron surfaces are discussed.

  5. Reaction of Inconel 690 and 693 in Iron Phosphate Melts: Alternative Glasses for Waste Vitrification

    SciTech Connect (OSTI)

    Day, Delbert E.

    2005-09-13

    The corrosion resistance of candidate materials used for the electrodes (Inconel 690 & 693) and the melt contact refractory (Monofrax K-3) in a Joule Heated Melter (JHM) has been investigated at the University of Missouri-Rolla (UMR) during the period from June 1, 2004 to August 31, 2005. This work was supported by the U.S. Department of Energy (DOE) Office of Biological and Environmental Research (DE-FG02-04ER63831). The unusual properties and characteristics of iron phosphate glasses, as viewed from the standpoint of alternative glasses for vitrifying nuclear and hazardous wastes which contain components that make them poorly suited for vitrification in borosilicate glass, were recently discovered at UMR. The expanding national and international interest in iron phosphate glasses for waste vitrification stems from their rapid melting and chemical homogenization which results in higher furnace output, their high waste loading that varies from 32 wt% up to 75 wt% for the Hanford LAW and HLW, respectively, and the outstanding chemical durability of the iron phosphate wasteforms which meets all present DOE requirements (PCT and VHT). The higher waste loading in iron phosphate glasses, compared to the baseline borosilicate glass, can reduce the time and cost of vitrification considerably since a much smaller mass of glass will be produced, for example, about 43% less glass when the LAW at Hanford is vitrified in an iron phosphate glass according to PNNL estimates. In view of the promising performance of iron phosphate glasses, information is needed for how to best melt these glasses on the scale needed for practical use. Melting iron phosphate glasses in a JHM is considered the preferred method at this time because its design could be nearly identical to the JHM now used to melt borosilicate glasses at the Defense Waste Processing Facility (DWPF), Westinghouse Savannah River Co. Therefore, it is important to have information for the corrosion of candidate electrode and refractory materials in iron phosphate melts in a JHM. During the period from June 1, 2004 to August 31, 2005, the corrosion resistance of coupons of Inconel 690 & 693 metals and Monofrax K-3 refractory, partially submerged in several iron phosphate melts at 950-1200?C, has been investigated to determine whether iron phosphate glasses could be melted in a JHM equipped with such electrodes and refractory in the same manner as now being used to melt borosilicate glass. These representative iron phosphate melts, which contained 30 wt% Hanford LAW and 40 wt% Idaho SBW simulants, did not corrode the Inconel 690 to any greater extent than what has been reported for Inconel 690 in the borosilicate melt in the JHM at DWPF. Inconel 693 appeared to be an even better candidate for use in iron phosphate melts since its corrosion rate (1.8 to 25.4 ?m/day) was only about one half that (5.4 to 45.4 ?m/day) of Inconel 690. The dynamic corrosion measured for the candidate refractory, Monofrax K-3, by iron phosphate melts is quite encouraging since the measured corrosion (0.011 to 0.132 mm/day at 9.2 rpm) is less than the corrosion (0.137 mm/day) that has been reported in the JHM used to melt borosilicate glass at DWPF. During the period covered by this final report, the results of the research on iron phosphate glasses have been described in seven technical papers and have been presented at one national meeting. In addition to the principal investigator, one research professor and one undergraduate research aide were supported by this project.

  6. ATTRITION RESISTANT IRON-BASED FISCHER-TROPSCH CATALYSTS

    SciTech Connect (OSTI)

    James G. Goodwin, Jr.; James J. Spivey; K. Jothimurugesan; Santosh K. Gangwal

    1999-03-29

    The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO+H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T when using low CO/H2 ratio synthesis gases derived from modern coal gasifiers. This is because in addition to reasonable F-T activity, the F-T catalysts also possess high water gas shift (WGS) activity. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, making the separation of catalyst from the oil/wax product very difficult if not impossible, and results in a steady loss of catalyst from the reactor. The objectives of this research are to develop a better understanding of the parameters affecting attrition resistance of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance. Catalyst preparations will be based on the use of spray drying and will be scalable using commercially available equipment. The research will employ among other measurements, attrition testing and F-T synthesis, including long duration slurry reactor runs in order to ascertain the degree of success of the various preparations. The goal is to develop an Fe catalyst which can be used in a SBCR having only an internal filter for separation of the catalyst from the liquid product, without sacrificing F-T activity and selectivity. The effect of silica addition via coprecipitation and as a binder to a doubly promoted Fischer-Tropsch synthesis iron catalyst (100 Fe/5 Cu/4.2 K) was studied. The catalysts were prepared by coprecipitation, followed by binder addition and drying in a 1 m diameter, 2 m tall spray dryer. The binder silica content was varied from 0 to 20 wt %. A catalyst with 12 wt % binder silica was found to have the highest attrition resistance. F-T reaction studies over 100 hours in a fixed-bed reactor showed that this catalyst maintained around 95 % CO conversion with a methane selectivity of less than 7 wt % and a C5 + selectivity of greater than 73 wt %. The effect of adding precipitated silica from 0 to 20 parts by weight to this catalyst (containing 12 wt % binder silica) was also studied. Addition of precipitated silica was found to be detrimental to attrition resistance and resulted in increased methane and reduced wax formation. An HPR series of proprietary catalysts was prepared to further improve the attrition resistance. Based on the experience gained, a proprietary HPR-43 catalyst has been successfully spray dried in 500 g quantity. This catalyst showed 95 % CO conversion over 125 h and had less than 4 % methane selectivity. Its attrition resistance was one of the highest among the catalyst tested.

  7. H{sub 2} from biosyngas via iron reduction and oxidation

    SciTech Connect (OSTI)

    Straus, J.; Terry, P.

    1995-09-01

    The production of hydrogen from the steam-oxidation of iron is a long-known phenomenon. The rise in interest in the production and storage of hydrogen justifies the examination of this process (and of the reverse process, the reduction of iron oxide) for commercial use. Under NREL subcontract ZAR-4-13294-02, a process simulation program was developed and used as a design tool to analyze various configurations of the iron-hydrogen purification/storage scheme. Specifically, analyses were performed to determine the effectiveness of this scheme in conjunction with biomass-derived gasified fuel streams (biosyngas). The results of the computer simulations led to a selection of a two-stage iron oxide reduction process incorporating interstage water and CO{sub 2} removal. Thermal analysis shows that the iron-hydrogen process would yield essentially the same quantity of clean hydrogen per unit of biomass as the conventional route. The iron-hydrogen process benefits from the excellent match potentially achievable between the otherwise-unusable energy fraction in the off-gas of the reduction reactor and the parasitic thermal, mechanical and electrical energy needs of some typical gasifier systems. The program simulations and economic analysis suggest that clean hydrogen from biomass feedstock could cost about 20% less via the iron-hydrogen method than by conventional methods of purification (using the same feedstock). Cost analyses show that lower capital costs would be incurred in generating clean hydrogen by utilizing this approach, especially in response to the fluctuating demand profile of a utility.

  8. Attrition Resistant Iron-Based Fischer-Tropsch Catalysts.

    SciTech Connect (OSTI)

    Jothimurugesan, K.; Goodwin, J.S.; Spivey, J.J.; Gangwal, S.K.

    1997-09-22

    The Fischer-Tropsch (F-T) reaction provides a way of converting coal-derived synthesis gas (CO and H{sub 2}) to liquid fuels. Since the reaction is highly exothermic, one of the major problems in control of the reaction is heat removal. Recent work has shown that the use of slurry bubble column reactors (SBCRs) can largely solve this problem. Iron-based (Fe) catalysts are preferred catalysts for F-T when using low CO/H{sub 2} ratio synthesis gases derived from modern coal gasifiers. This is because in addition to reasonable F-T activity, the F-T catalysts also possess high water gas shift (WGS) activity. However, a serious problem with the use of Fe catalysts in a SBCR is their tendency to undergo attrition. This can cause fouling/plugging of downstream filters and equipment, making the separation of catalyst from the oil/wax product very difficult if not impossible, and results in a steady loss of catalyst from the reactor. The objectives of this research are to develop a better understanding of the parameters affecting attrition resistance of Fe F-T catalysts suitable for use in SBCRs and to incorporate this understanding into the design of novel Fe catalysts having superior attrition resistance. Catalyst preparations will be based on the use of spray drying and will be scalable using commercially available equipment. The research will employ among other measurements, attrition testing and F-T synthesis, including long duration slurry reactor runs in order to ascertain the degree of success of the various preparations. The goal is to develop an Fe catalyst which can be used in a SBCR having only an internal filter for separation of the catalyst from the liquid product, without sacrificing F-T activity and selectivity.

  9. The origin of the most iron-poor star

    SciTech Connect (OSTI)

    Marassi, S.; Schneider, R.; Limongi, M. [INAF/Osservatorio Astronomico di Roma, Via di Frascati 33, I-00040 Monteporzio (Italy); Chiaki, G.; Yoshida, N. [Department of Physics, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-0033 (Japan); Omukai, K. [Astronomical Institute, Tohoku University, Sendai 980-8578 (Japan); Nozawa, T. [National Astronomical Observatory of Japan, Mitaka, Tokyo 181-8588 (Japan); Chieffi, A., E-mail: stefania.marassi@oa-roma.inaf.it [INAF/IASF, Via Fosso del Cavaliere 100, I-00133 Roma (Italy)

    2014-10-20

    We investigate the origin of carbon-enhanced metal-poor (CEMP) stars starting from the recently discovered [Fe/H] < -7.1 star SMSS J031300. We show that the elemental abundances observed on the surface of SMSS J031300 can be well fit by the yields of faint, metal-free, supernovae (SNe). Using properly calibrated faint SN explosion models, we study, for the first time, the formation of dust grains in such carbon-rich, iron-poor SN ejecta. Calculations are performed assuming both unmixed and uniformly mixed ejecta and taking into account the partial destruction by the SN reverse shock. We find that, due to the paucity of refractory elements beside carbon, amorphous carbon is the only grain species to form, with carbon condensation efficiencies that range between (0.15 and 0.84), resulting in dust yields in the range (0.025-2.25) M {sub ?}. We follow the collapse and fragmentation of a star-forming cloud enriched by the products of these faint SN explosions and we explore the role played by fine structure line cooling and dust cooling. We show that even if grain growth during the collapse has a minor effect of the dust-to-gas ratio, due to C depletion into CO molecules at an early stage of the collapse, the formation of CEMP low-mass stars, such as SMSS J031300, could be triggered by dust cooling and fragmentation. A comparison between model predictions and observations of a sample of C-normal and C-rich metal-poor stars supports the idea that a single common pathway may be responsible for the formation of the first low-mass stars.

  10. The Mesabi Nugget Research Project New Ironmaking Technology of the Future: High Quality Iron Nuggets Using a Rotary Hearth Furnace

    SciTech Connect (OSTI)

    2004-07-01

    The manufacture of steel involves many energy intensive processes that consume raw or recycled materials, such as iron ore and scrap metal, from around the world.

  11. Method of manufacturing iron aluminide by thermomechanical processing of elemental powders

    DOE Patents [OSTI]

    Deevi, Seetharama C.; Lilly, Jr., A. Clifton; Sikka, Vinod K.; Hajaligol, Mohammed R.

    2000-01-01

    A powder metallurgical process of preparing iron aluminide useful as electrical resistance heating elements having improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The iron aluminide has an entirely ferritic microstructure which is free of austenite and can include, in weight %, 20 to 32% Al, and optional additions such as .ltoreq.1% Cr, .gtoreq.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1 % rare earth metal, .ltoreq.1% oxygen, and/or .ltoreq.3% Cu. The process includes forming a mixture of aluminum powder and iron powder, shaping the mixture into an article such as by cold rolling the mixture into a sheet, and sintering the article at a temperature sufficient to react the iron and aluminum powders and form iron aluminide. The sintering can be followed by hot or cold rolling to reduce porosity created during the sintering step and optional annealing steps in a vacuum or inert atmosphere.

  12. Observation of universal strong orbital-dependent correlation effects in iron chalcogenides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yi, M.; Liu, Z. -K.; Zhang, Y.; Yu, R.; Zhu, J. -X.; Lee, J. J.; Moore, R. G.; Schmitt, F. T.; Li, W.; Riggs, S. C.; et al

    2015-07-23

    Establishing the appropriate theoretical framework for unconventional superconductivity in the iron-based materials requires correct understanding of both the electron correlation strength and the role of Fermi surfaces. This fundamental issue becomes especially relevant with the discovery of the iron chalcogenide superconductors. Here, we use angle-resolved photoemission spectroscopy to measure three representative iron chalcogenides, FeTe0.56Se0.44, monolayer FeSe grown on SrTiO3 and K0.76Fe1.72Se2. We show that these superconductors are all strongly correlated, with an orbital-selective strong renormalization in the dxy bands despite having drastically different Fermi surface topologies. Furthermore, raising temperature brings all three compounds from a metallic state to a phasemore » where the dxy orbital loses all spectral weight while other orbitals remain itinerant. As a result, these observations establish that iron chalcogenides display universal orbital-selective strong correlations that are insensitive to the Fermi surface topology, and are close to an orbital-selective Mott phase, hence placing strong constraints for theoretical understanding of iron-based superconductors.« less

  13. Evaluation of the fabricability of advanced iron aluminide-clad austenitic stainless steel tubing

    SciTech Connect (OSTI)

    Mohn, W.R.; Topolski, M.J.

    1993-07-01

    Researchers at Babcock & Wilcox Alliance Research Center have investigated methods to produce bimetallic tubing consisting of iron aluminide-clad austenitic stainless steel for practical use in fossil fueled energy equipment. In the course of this work, the compatibility of iron aluminide with four candidate austenitic stainless steel substrates was first evaluated using diffusion couples. Based on these results, a combination of iron aluminide and 304 stainless steel was selected for further development. Two composite billets of this combination were then prepared and extruded in separate trails at 2200F and 2000F. Both extrusions yielded 2-inch OD clad tubes, each approximately 18 feet long. Results of the evaluation show that the tube extruded at 2000F had a sound, integrally bonded clad layer throughout its entire length. However, the tube extruded at 2200F exhibited regions of disbonding between the clad layer and the substrate. In supplement to this work, an assessment of the technical and economic merits of iron aluminide-clad austenitic stainless steel components in power generation systems was conducted by B&W Fossil Power Division. Future activities should include an investigation of lower extrusion processing temperatures to optimize the fabrication of high quality iron-aluminide clad tubing.

  14. Diagnosis of energy transport in iron buried layer targets using an extreme ultraviolet laser

    SciTech Connect (OSTI)

    Shahzad, M.; Culfa, O.; Rossall, A. K.; Tallents, G. J.; Wilson, L. A.; Guilbaud, O.; Kazamias, S.; Delmas, O.; Demailly, J.; Maitrallain, A.; Pittman, M.; Baynard, E.; Farjardo, M.

    2015-02-15

    We demonstrate the use of extreme ultra-violet (EUV) laboratory lasers in probing energy transport in laser irradiated solid targets. EUV transmission through targets containing a thin layer of iron (50 nm) encased in plastic (CH) after irradiation by a short pulse (35 fs) laser focussed to irradiances 3 × 10{sup 16} Wcm{sup −2} is measured. Heating of the iron layer gives rise to a rapid decrease in EUV opacity and an increase in the transmission of the 13.9 nm laser radiation as the iron ionizes to Fe{sup 5+} and above where the ion ionisation energy is greater than the EUV probe photon energy (89 eV). A one dimensional hydrodynamic fluid code HYADES has been used to simulate the temporal variation in EUV transmission (wavelength 13.9 nm) using IMP opacity values for the iron layer and the simulated transmissions are compared to measured transmission values. When a deliberate pre-pulse is used to preform an expanding plastic plasma, it is found that radiation is important in the heating of the iron layer while for pre-pulse free irradiation, radiation transport is not significant.

  15. Observation of universal strong orbital-dependent correlation effects in iron chalcogenides

    SciTech Connect (OSTI)

    Yi, M.; Liu, Z. -K.; Zhang, Y.; Yu, R.; Zhu, J. -X.; Lee, J. J.; Moore, R. G.; Schmitt, F. T.; Li, W.; Riggs, S. C.; Chu, J. -H.; Lv, B.; Hu, J.; Hashimoto, M.; Mo, S. -K.; Hussain, Z.; Mao, Z. Q.; Chu, C. W.; Fisher, I. R.; Si, Q.; Shen, Z. -X.; Lu, D. H.

    2015-07-23

    Establishing the appropriate theoretical framework for unconventional superconductivity in the iron-based materials requires correct understanding of both the electron correlation strength and the role of Fermi surfaces. This fundamental issue becomes especially relevant with the discovery of the iron chalcogenide superconductors. Here, we use angle-resolved photoemission spectroscopy to measure three representative iron chalcogenides, FeTe0.56Se0.44, monolayer FeSe grown on SrTiO3 and K0.76Fe1.72Se2. We show that these superconductors are all strongly correlated, with an orbital-selective strong renormalization in the dxy bands despite having drastically different Fermi surface topologies. Furthermore, raising temperature brings all three compounds from a metallic state to a phase where the dxy orbital loses all spectral weight while other orbitals remain itinerant. As a result, these observations establish that iron chalcogenides display universal orbital-selective strong correlations that are insensitive to the Fermi surface topology, and are close to an orbital-selective Mott phase, hence placing strong constraints for theoretical understanding of iron-based superconductors.

  16. MOSSBAUER SPECTROSCOPY STUDIES OF IRON CATALYSTS USED IN SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

    SciTech Connect (OSTI)

    G.P. Huffman; K. R. P. M. Rao; F.E. Huggins

    1998-02-01

    Iron and cobalt are the two principal choices as catalysts for Fischer-Tropsch (F-T) synthesis. As discussed in a recent review by Wender each metal has certain advantages and disadvantages. Davis and co-workers have recently discussed the advantages of iron-based F-T catalysts in some detail. In order to understand the catalytic reaction mechanisms of iron during F-T synthesis, it is critical to identify the active catalytic phases. Moreover, from a practical point of view, it is equally important to identify the reactions and transformations that deactivate the catalysts. {sup 57}Fe Moessbauer spectroscopy is perhaps the best technique available for quantitative characterization of the iron phases in complex samples. For the past several years, our group has been using Moessbauer spectroscopy to characterize the iron-based catalysts prepared and tested for F-T synthesis in a number of DOE-sponsored programs. The results of this investigation have been summarized in detail in DOE reports and in a number of publications released over the past few years. A list of the principal publications resulting from this work is given. A brief summary of the highlights of the results presented in these papers is presented in the current report.

  17. Interplay between superconductivity and magnetism in iron-based superconductors

    SciTech Connect (OSTI)

    Chubukov, Andrey V

    2015-06-10

    This proposal is for theoretical work on strongly correlated electron systems, which are at the center of experimental and theoretical activities in condensed-matter physics. The interest to this field is driven fascinating variety of observed effects, universality of underlying theoretical ideas, and practical applications. I propose to do research on Iron-based superconductors (FeSCs), which currently attract high attention in the physics community. My goal is to understand superconductivity and magnetism in these materials at various dopings, the interplay between the two, and the physics in the phase in which magnetism and superconductivity co-exist. A related goal is to understand the origin of the observed pseudogap-like behavior in the normal state. My research explores the idea that superconductivity is of electronic origin and is caused by the exchange of spin-fluctuations, enhanced due to close proximity to antiferromagnetism. The multi-orbital/multi-band nature of FeSCs opens routes for qualitatively new superconducting states, particularly the ones which break time-reversal symmetry. By all accounts, the coupling in pnictdes is below the threshold for Mott physics and I intend to analyze these systems within the itinerant approach. My plan is to do research in two stages. I first plan to address several problems within weak-coupling approach. Among them: (i) what sets stripe magnetic order at small doping, (ii) is there a preemptive instability into a spin-nematic state, and how stripe order affects fermions; (iii) is there a co-existence between magnetism and superconductivity and what are the system properties in the co-existence state; (iv) how superconductivity emerges despite strong Coulomb repulsion and can the gap be s-wave but with nodes along electron FSs, (v) are there complex superconducting states, like s+id, which break time reversal symmetry. My second goal is to go beyond weak coupling and derive spin-mediated, dynamic interaction between fermions, understand what sets the upper scale for attractive interaction, compute T_c, and then obtain and solve matrix non-linear gap equation for spin-mediated pairing and study various feedbacks from the pairing on fermions on ARPES spectra, optical and thermal conductivity, and other observables, The problems I have chosen are quite generic, and the understanding of magnetically-mediated superconductivity in the strong-coupling regime will not only advance the theory of superconductivity in FeSCs, but will contribute to a generic understanding of the pairing of fermions near quantum-critical points -- the problems ranging from s-wave pairing by soft optical phonons to to color superconductivity of quarks mediated by a gluon exchange.

  18. DEVELOPMENT OF PRECIPITATED IRON FISCHER-TROPSCH CATALYSTS

    SciTech Connect (OSTI)

    Dr. Dragomir B. Bukur; Dr. X. Lang; Dr. S. Chokkaram; Dr. L. Nowicki; G. Wei; Dr. Y. Ding; Dr. B. Reddy; Dr. S. Xiao

    1999-07-22

    Despite the current worldwide oil glut, the US will ultimately require large-scale production of liquid (transportation) fuels from coal. Slurry phase Fischer-Tropsch (F-T) technology, with its versatile product slate, may be expected to play a major role in production of transportation fuels via indirect coal liquefaction. Some of the F-T catalysts synthesized and tested at Texas A and M University under DOE Contract No. DE-AC22-89PC89868 were more active than any other known catalysts developed for maximizing production of high molecular weight hydrocarbons (waxes). The objectives of the present contract were to demonstrate repeatability of catalyst performance and reproducibility of preparation procedures of two of these catalysts on a laboratory scale. Improvements in the catalyst performance were attempted through the use of: (a) higher reaction pressure and gas space velocity to maximize the reactor productivity; (b) modifications in catalyst preparation steps; and (c) different pretreatment procedures. Repeatability of catalyst performance and reproducibility of catalyst synthesis procedure have been successfully demonstrated in stirred tank slurry reactor tests. Reactor space-time-yield was increased up to 48% by increasing reaction pressure from 1.48 MPa to 2.17 MPa, while maintaining the gas contact time and synthesis gas conversion at a constant value. Use of calcination temperatures above 300 C, additional CaO promoter, and/or potassium silicate as the source of potassium promoter, instead of potassium bicarbonate, did not result in improved catalyst performance. By using different catalyst activation procedures they were able to increase substantially the catalyst activity, while maintaining low methane and gaseous hydrocarbon selectivities. Catalyst productivity in runs SA-0946 and SA-2186 was 0.71 and 0.86 gHC/g-Fe/h, respectively, and this represents 45-75% improvement in productivity relative to that achieved in Rheinpreussen's demonstration plant unit (the most successful bubble column slurry reactor performance to date), and sets new standards of performance for ''high alpha'' iron catalysts.

  19. From iron(III) precursor to magnetite and vice versa

    SciTech Connect (OSTI)

    Gotic, M.; Jurkin, T.; Music, S.

    2009-10-15

    The syntheses of nanosize magnetite particles by wet-chemical oxidation of Fe{sup 2+} have been extensively investigated. In the present investigation the nanosize magnetite particles were synthesised without using the Fe(II) precursor. This was achieved by {gamma}-irradiation of water-in-oil microemulsion containing only the Fe(III) precursor. The corresponding phase transformations were monitored. Microemulsions (pH {approx} 12.5) were {gamma}-irradiated at a relatively high dose rate of {approx}22 kGy/h. Upon 1 h of {gamma}-irradiation the XRD pattern of the precipitate showed goethite and unidentified low-intensity peaks. Upon 6 h of {gamma}-irradiation, reductive conditions were achieved and substoichiometric magnetite ({approx}Fe{sub 2.71}O{sub 4}) particles with insignificant amount of goethite particles found in the precipitate. Hydrated electrons (e{sub aq}{sup -}), organic radicals and hydrogen gas as radiolytic products were responsible for the reductive dissolution of iron oxide in the microemulsion and the reduction Fe{sup 3+} {yields} Fe{sup 2+}. Upon 18 h of {gamma}-irradiation the precipitate exhibited dual behaviour, it was a more oxidised product than the precipitate obtained after 6 h of {gamma}-irradiation, but it contained magnetite particles in a more reduced form ({approx}Fe{sub 2.93}O{sub 4}). It was presumed that the reduction and oxidation processes existed as concurrent competitive processes in the microemulsion. After 18 h of {gamma}-irradiation the pH of the medium shifted from the alkaline to the acidic range. The high dose rate of {approx}22 kGy/h was directly responsible for this shift to the acidic range. At a slightly acidic pH a further reduction of Fe{sup 3+} {yields} Fe{sup 2+} resulted in the formation of more stoichiometric magnetite particles, whereas the oxidation conditions in the acidic medium permitted the oxidation Fe{sup 2+} {yields} Fe{sup 3+}. The Fe{sup 3+} was much less soluble in the acidic medium and it hydrolysed and recrystallised as goethite. The {gamma}-irradiation of the microemulsion for 25 h at a lower dose rate of 16 kGy/h produced pure substoichiometric nanosize magnetite particles of about 25 nm in size and with the stoichiometry of Fe{sub 2.83}O{sub 4}.

  20. Nitrogen-doped carbon-supported cobalt-iron oxygen reduction catalyst

    DOE Patents [OSTI]

    Zelenay, Piotr; Wu, Gang

    2014-04-29

    A Fe--Co hybrid catalyst for oxygen reaction reduction was prepared by a two part process. The first part involves reacting an ethyleneamine with a cobalt-containing precursor to form a cobalt-containing complex, combining the cobalt-containing complex with an electroconductive carbon supporting material, heating the cobalt-containing complex and carbon supporting material under conditions suitable to convert the cobalt-containing complex and carbon supporting material into a cobalt-containing catalyst support. The second part of the process involves polymerizing an aniline in the presence of said cobalt-containing catalyst support and an iron-containing compound under conditions suitable to form a supported, cobalt-containing, iron-bound polyaniline species, and subjecting said supported, cobalt-containing, iron bound polyaniline species to conditions suitable for producing a Fe--Co hybrid catalyst.

  1. Following iron speciation in the early stages of magnetite magnetosome biomineralization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Firlar, Emre; Perez-Gonzalez, Teresa; Olszewska, Agata; Faivre, Damien; Prozorov, Tanya

    2016-02-26

    Understanding magnetosome magnetite biomineralization is of fundamental interest to devising the strategies for bioinspired synthesis of magnetic materials at the nanoscale. Thus, we investigated the early stages of magnetosome formation in this work and correlated the size and emergent crystallinity of magnetosome nanoparticles with the changes in chemical environment of iron and oxygen by utilizing advanced analytical electron microscopy techniques. We observed that magnetosomes in the early stages of biomineralization with the sizes of 5–10 nm were amorphous, with a majority of iron present as Fe3+, indicative of ferric hydroxide. The magnetosomes with intermediate sizes showed partially crystalline structure withmore » a majority of iron present as Fe3+ and trace amounts of Fe2+. The fully maturated magnetosomes were indexed to magnetite. Furthermore, our approach provides spatially resolved structural and chemical information of individual magnetosomes with different particle sizes, attributed to magnetosomes at different stages of biomineralization.« less

  2. Quantitative analysis of iron dissolution during repassivation of freshly generated metallic surfaces

    SciTech Connect (OSTI)

    Itagaki, M.; Oltra, R.; Vuillemin, B.; Keddam, M.; Takenouti, H.

    1997-01-01

    A channel flow double electrode was coupled with the pulsed laser depassivation technique to investigate the repassivation kinetics on iron in sulfuric acid (pH 1 to 3). The amount of ferrous ion dissolved from the activated iron electrode during repassivation was measured. The total charge for repassivation is separated into partial charges for dissolution of ions, Q{sub d}, and formation of adsorbed species, Q{sub f}. The charge Q{sub d} decreases with the electrode potential. The charge Q{sub f} does not depend on the electrode potential. Its value corresponds to the formation of a monolayer of trivalent oxide film. A reaction model for repassivation of iron involving two adsorbed species was simulated numerically in good agreement with the experimental results. The actual rate of repassivation was characterized by the fractional coverage of passivating species.

  3. Method of forming magnetostrictive rods from rare earth-iron alloys

    DOE Patents [OSTI]

    McMasters, O.D.

    1986-09-02

    Rods of magnetostrictive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube. 5 figs.

  4. System and method for making metallic iron with reduced CO.sub.2 emissions

    DOE Patents [OSTI]

    Kiesel, Richard F; Englund, David J; Schlichting, Mark; Meehan, John; Crouch, Jeremiah; Wilson, Logan

    2014-10-14

    A method and system for making metallic iron nodules with reduced CO.sub.2 emissions is disclosed. The method includes: assembling a linear hearth furnace having entry and exit portions, at least a conversion zone and a fusion zone, and a moving hearth adapted to move reducible iron bearing material through the furnace on contiguous hearth sections; assembling a shrouded return substantially free of air ingress extending adjacent at least the conversion and fusion zones of the furnace through which hearth sections can move from adjacent the exit portion to adjacent the entry portion of the furnace; transferring the hearth sections from the furnace to the shrouded return adjacent the exit portion; reducing reducible material in the linear hearth furnace to metallic iron nodules; and transporting gases from at least the fusion zone to the shrouded return to heat the hearth sections while in the shrouded return.

  5. Size-Dependent Specific Surface Area of Nanoporous Film Assembled by Core-Shell Iron Nanoclusters

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Antony, Jiji; Nutting, Joseph; Baer, Donald R.; Meyer, Daniel; Sharma, Amit; Qiang, You

    2006-01-01

    Nmore » anoporous films of core-shell iron nanoclusters have improved possibilities for remediation, chemical reactivity rate, and environmentally favorable reaction pathways. Conventional methods often have difficulties to yield stable monodispersed core-shell nanoparticles. We produced core-shell nanoclusters by a cluster source that utilizes combination of Fe target sputtering along with gas aggregations in an inert atmosphere at 7 ∘ C . Sizes of core-shell iron-iron oxide nanoclusters are observed with transmission electron microscopy (TEM). The specific surface areas of the porous films obtained from Brunauer-Emmett-Teller (BET) process are size-dependent and compared with the calculated data.« less

  6. Competing magnetic fluctuations in iron pnictide superconductors: Role of ferromagnetic spin correlations revealed by NMR

    SciTech Connect (OSTI)

    Wiecki, P.; Roy, B.; Johnston, D. C.; Budko, S. L.; Canfield, P. C.; Furukawa, Y.

    2015-09-22

    In the iron pnictide superconductors, theoretical calculations have consistently shown enhancements of the static magnetic susceptibility at both the stripe-type antiferromagnetic and in-plane ferromagnetic (FM) wave vectors. However, the possible existence of FM fluctuations has not yet been examined from a microscopic point of view. Here, using 75As NMR data, we provide clear evidence for the existence of FM spin correlations in both the hole- and electron-doped BaFe2As2 families of iron-pnictide superconductors. Furthermore, these FM fluctuations appear to compete with superconductivity and are thus a crucial ingredient to understanding the variability of Tc and the shape of the superconducting dome in these and other iron-pnictide families.

  7. Photoelectrochemical study of pitting on iron in borate buffer solution containing inhibitor

    SciTech Connect (OSTI)

    Yang, M.; Chen, L.; Cai, S.

    1997-01-01

    The photoelectrochemical behavior and the susceptibility of iron to pitting in borate buffer containing chloride ions (Cl{sup {minus}}) were investigated in the presence and absence of inhibitor PC-604, which is a mixture of polyhydric alcohol phosphoric easter and polyphosphoric ester of various molecular weights. Measurements of the band gap (E{sub g}) of the passive film on iron showed inhibitor concentration and passivation time did not interfere with E{sub g}. Photocurrent and photocurrent transients increased with increasing inhibitor quantities and passivation times at constant potential. The decay time-constant of the photocurrent transient was investigated as a specific parameter of the film. Data showed this parameter was related to pitting susceptibility of the passive film on iron.

  8. Production and Machining of Thin Wall Gray and Ductile Cast Iron

    SciTech Connect (OSTI)

    Fleischman, E.H.; Li, H.; Griffin, R.; Bates, C.E.; Eleftheriou, E.

    2000-11-03

    The University of Alabama at Birmingham, in cooperation with the American Foundry Society, companies across North America, with support from the U.S. Department of Energy, is conducting a project to develop an understanding of the factors that control the machinability of cast gray and ductile iron. Differences of as much as 500% have been found in machinability have been observed at the same strength. The most machinable irons were those with a high cell counts and few carbonitride inclusions. Additions of tin and copper can be added to both gray and ductile iron to stabilize the pearlite, but excessive additions (above those required to produce the desired pearlite content) degrade the machinability.

  9. Competing magnetic fluctuations in iron pnictide superconductors: Role of ferromagnetic spin correlations revealed by NMR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wiecki, P.; Roy, B.; Johnston, D. C.; Bud’ko, S. L.; Canfield, P. C.; Furukawa, Y.

    2015-09-22

    In the iron pnictide superconductors, theoretical calculations have consistently shown enhancements of the static magnetic susceptibility at both the stripe-type antiferromagnetic and in-plane ferromagnetic (FM) wave vectors. However, the possible existence of FM fluctuations has not yet been examined from a microscopic point of view. Here, using 75As NMR data, we provide clear evidence for the existence of FM spin correlations in both the hole- and electron-doped BaFe2As2 families of iron-pnictide superconductors. Furthermore, these FM fluctuations appear to compete with superconductivity and are thus a crucial ingredient to understanding the variability of Tc and the shape of the superconducting domemore » in these and other iron-pnictide families.« less

  10. Semiconductor sensor for optically measuring polarization rotation of optical wavefronts using rare earth iron garnets

    DOE Patents [OSTI]

    Duncan, Paul G.

    2002-01-01

    Described are the design of a rare earth iron garnet sensor element, optical methods of interrogating the sensor element, methods of coupling the optical sensor element to a waveguide, and an optical and electrical processing system for monitoring the polarization rotation of a linearly polarized wavefront undergoing external modulation due to magnetic field or electrical current fluctuation. The sensor element uses the Faraday effect, an intrinsic property of certain rare-earth iron garnet materials, to rotate the polarization state of light in the presence of a magnetic field. The sensor element may be coated with a thin-film mirror to effectively double the optical path length, providing twice the sensitivity for a given field strength or temperature change. A semiconductor sensor system using a rare earth iron garnet sensor element is described.

  11. Method of forming magnetostrictive rods from rare earth-iron alloys

    DOE Patents [OSTI]

    McMasters, O. Dale

    1986-09-02

    Rods of magnetrostructive alloys of iron with rare earth elements are formed by flowing a body of rare earth-iron alloy in a crucible enclosed in a chamber maintained under an inert gas atmosphere, forcing such molten rare-earth-iron alloy into a hollow mold tube of refractory material positioned with its lower end portion within the molten body by means of a pressure differential between the chamber and mold tube and maintaining a portion of the molten alloy in the crucible extending to a level above the lower end of the mold tube so that solid particles of higher melting impurities present in the alloy collect at the surface of the molten body and remain within the crucible as the rod is formed in the mold tube.

  12. Metal matrix composite of an iron aluminide and ceramic particles and method thereof

    DOE Patents [OSTI]

    Schneibel, Joachim H.

    1997-01-01

    A metal matrix composite comprising an iron aluminide binder phase and a ceramic particulate phase such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide is made by heating a mixture of iron aluminide powder and particulates of one of the ceramics such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide in a alumina crucible at about 1450.degree. C. for about 15 minutes in an evacuated furnace and cooling the mixture to room temperature. The ceramic particulates comprise greater than 40 volume percent to about 99 volume percent of the metal matrix composite.

  13. Iron speciation in minerals and glasses probed by M [subscript 2/3] -edge

    Office of Scientific and Technical Information (OSTI)

    X-ray Raman scattering spectroscopy (Journal Article) | SciTech Connect Iron speciation in minerals and glasses probed by M [subscript 2/3] -edge X-ray Raman scattering spectroscopy Citation Details In-Document Search Title: Iron speciation in minerals and glasses probed by M [subscript 2/3] -edge X-ray Raman scattering spectroscopy Authors: Nyrow, A. ; Sternemann, C. ; Wilke, M. ; Gordon, R. A. ; Mende, K. ; Yava, ; #351 ; H. ; Simonelli, L. ; Hiraoka, N. ; Sahle, Ch. J. ; Huotari, S. ;

  14. Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping

    Energy Savers [EERE]

    and Feasibility | Department of Energy Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping and Feasibility Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping and Feasibility This Sandia National Laboratories study examines the feasibility of a hydrogen-fueled PEM fuel cell barge to provide electrical power to vessels at anchorage or at berth. The study includes both a determination of the technical feasibility of the idea as well as an analysis of

  15. Temperature and melting of laser-shocked iron releasing into an LiF window

    SciTech Connect (OSTI)

    Huser, G.; Koenig, M.; Benuzzi-Mounaix, A.; Henry, E.; Vinci, T.; Faral, B.; Tomasini, M.; Telaro, B.; Batani, D.

    2005-06-15

    Absolute reflectivity and self-emission diagnostics are used to determine the gray-body equivalent temperature of laser-shocked iron partially releasing into a lithium fluoride window. Pressure and reflectivity are measured simultaneously by means of velocity interferometer system for any reflector interferometers. In the temperature-pressure plane, a temperature plateau in the release is observed which is attributed to iron's melting line. Extrapolation of data leads to a melting temperature at Earth's inner-outer core boundary of 7800{+-}1200 K, in good agreement with previous works based on dynamic compression. Shock temperatures were calculated and found to be in the liquid phase.

  16. Mechanisms of stress corrosion cracking for iron-based alloys in high-temperature water

    SciTech Connect (OSTI)

    Zhou, X.Y.; Congleton, J.; Bahraloloom, A.

    1998-11-01

    Stress corrosion cracking (SCC) susceptibilities of a series of iron-based alloys (IBA), including some high-purity irons, were evaluated in lithiated water at temperatures up to 300 C. Inclusion distributions in each material were established using quantitative metallography and energy dispersive x-ray analysis (EDX). Electrochemical measurements were performed to investigate film formation kinetics. Results showed the minimum potential for SCC was a function of the inclusion content. Reducing the inclusion content in IBA moved the minimum potential for SCC in the anodic direction and/or increased the temperature for the onset of cracking but did not eliminate SCC.

  17. Metal matrix composite of an iron aluminide and ceramic particles and method thereof

    DOE Patents [OSTI]

    Schneibel, J.H.

    1997-06-10

    A metal matrix composite comprising an iron aluminide binder phase and a ceramic particulate phase such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide is made by heating a mixture of iron aluminide powder and particulates of one of the ceramics such as titanium diboride, zirconium diboride, titanium carbide and tungsten carbide in a alumina crucible at about 1,450 C for about 15 minutes in an evacuated furnace and cooling the mixture to room temperature. The ceramic particulates comprise greater than 40 volume percent to about 99 volume percent of the metal matrix composite.

  18. Phase diagram of the isovalent phosphorous-substituted 122-type iron

    Office of Scientific and Technical Information (OSTI)

    pnictides (Journal Article) | SciTech Connect Phase diagram of the isovalent phosphorous-substituted 122-type iron pnictides Citation Details In-Document Search Title: Phase diagram of the isovalent phosphorous-substituted 122-type iron pnictides Recent experiments demonstrated that the isovalent doping system gives a similar phase diagram as the heterovalent doped cases. For example, with the phosphorous (P) doping, the magnetic order in BaFe2(As1-xPx)2 compound is first suppressed, then

  19. Crystal structures and compressibility of novel iron borides Fe{sub 2}B{sub

    Office of Scientific and Technical Information (OSTI)

    7} and Fe{sub x}B{sub 50} synthesized at high pressure and high temperature (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Crystal structures and compressibility of novel iron borides Fe{sub 2}B{sub 7} and Fe{sub x}B{sub 50} synthesized at high pressure and high temperature Citation Details In-Document Search Title: Crystal structures and compressibility of novel iron borides Fe{sub 2}B{sub 7} and Fe{sub x}B{sub 50} synthesized at high pressure and high

  20. Melting in the Iron-Oxygen-Silicon System up to 85 GPa. (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Journal Article: Melting in the Iron-Oxygen-Silicon System up to 85 GPa. Citation Details In-Document Search Title: Melting in the Iron-Oxygen-Silicon System up to 85 GPa. Authors: Seagle, Christopher T ; Cottrell, Elizabeth ; Fei, Yingwei ; Dera, Przemyslaw. Publication Date: 2012-03-01 OSTI Identifier: 1074068 Report Number(s): SAND2012-1892J DOE Contract Number: AC04-94AL85000 Resource Type: Journal Article Resource Relation: Journal Name:

  1. Melting in the Iron-Oxygen-Silicon System up to 85 GPa. (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Journal Article: Melting in the Iron-Oxygen-Silicon System up to 85 GPa. Citation Details In-Document Search Title: Melting in the Iron-Oxygen-Silicon System up to 85 GPa. Abstract not provided. Authors: Seagle, Christopher T ; Cottrell, Elizabeth ; Fei, Yingwei ; Dera, Przemyslaw Publication Date: 2012-03-01 OSTI Identifier: 1078694 Report Number(s): SAND2012-1892J 447870 DOE Contract Number: AC04-94AL85000 Resource Type: Journal Article Resource Relation: Journal Name: J.

  2. Observation of magnon-mediated current drag in Pt/yttrium iron

    Office of Scientific and Technical Information (OSTI)

    garnet/Pt(Ta) trilayers (Journal Article) | DOE PAGES Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers Title: Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers Pure spin current, a flow of spin angular momentum without flow of any accompanying net charge, is generated in two common ways. One makes use of the spin Hall effect in normal metals (NM) with strong spin-orbit coupling, such as Pt or Ta. The other utilizes

  3. Observation of magnon-mediated current drag in Pt/yttrium iron

    Office of Scientific and Technical Information (OSTI)

    garnet/Pt(Ta) trilayers (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers Citation Details In-Document Search Title: Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers Pure spin current, a flow of spin angular momentum without flow of any accompanying net charge, is generated in two common ways. One makes use of the spin Hall effect in

  4. Observation of magnon-mediated current drag in Pt/yttrium iron

    Office of Scientific and Technical Information (OSTI)

    garnet/Pt(Ta) trilayers (Journal Article) | SciTech Connect Journal Article: Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers Citation Details In-Document Search Title: Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public

  5. Ordered iron aluminide alloys having an improved room-temperature ductility and method thereof

    DOE Patents [OSTI]

    Sikka, Vinod K.

    1992-01-01

    A process is disclosed for improving the room temperature ductility and strength of iron aluminide intermetallic alloys. The process involves thermomechanically working an iron aluminide alloy by means which produce an elongated grain structure. The worked alloy is then heated at a temperature in the range of about 650.degree. C. to about 800.degree. C. to produce a B2-type crystal structure. The alloy is rapidly cooled in a moisture free atmosphere to retain the B2-type crystal structure at room temperature, thus providing an alloy having improved room temperature ductility and strength.

  6. Iron-nickel-chromium alloy having improved swelling resistance and low neutron absorbence

    DOE Patents [OSTI]

    Korenko, Michael K.

    1986-01-01

    An iron-nickel-chromium age-hardenable alloy suitable for use in fast breeder reactor ducts and cladding which utilizes the gamma-double prime strengthening phase and characterized in having a delta or eta phase distributed at or near grain boundaries. The alloy consists essentially of about 33-39.5% nickel, 7.5-16% chromium, 1.5-4% niobium, 0.1-0.7% silicon, 0.01-0.2% zirconium, 1-3% titanium, 0.2-0.6% aluminum, and the remainder essentially all iron. Up to 0.4% manganese and up to 0.010% magnesium can be added to inhibit trace element effects.

  7. Lead-iron phosphate glass as a containment medium for the disposal of high-level nuclear wastes

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.

    1984-04-11

    Disclosed are lead-iron phosphate glasses containing a high level of Fe/sub 2/O/sub 3/ for use as a storage medium for high-level radioactive nuclear waste. By combining lead-iron phosphate glass with various types of simulated high-level nuclear waste

  8. Phase 1 report on the Bear Creek Valley treatability study, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1997-04-01

    Bear Creek Valley (BCV) is located within the US Department of Energy (DOE) Oak Ridge Reservation and encompasses multiple waste units containing hazardous and radioactive wastes associated with past operations at the adjacent Oak Ridge Y-12 Plant. The BCV Remedial Investigation determined that disposal of wastes at the S-3 Site, Boneyard/Burnyard (BYBY), and Bear Creek Burial Grounds (BCBG) has caused contamination of both deep and shallow groundwater. The primary contaminants include uranium, nitrate, and VOCs, although other metals such as aluminum, magnesium, and cadmium persist. The BCV feasibility study will describe several remedial options for this area, including both in situ and ex situ treatment of groundwater. This Treatability Study Phase 1 Report describes the results of preliminary screening of treatment technologies that may be applied within BCV. Four activities were undertaken in Phase 1: field characterization, laboratory screening of potential sorbents, laboratory testing of zero valent iron products, and field screening of three biological treatment systems. Each of these activities is described fully in technical memos attached in Appendices A through G.

  9. Hydrogen passivation of interstitial iron in boron-doped multicrystalline silicon during annealing

    SciTech Connect (OSTI)

    Liu, AnYao; Sun, Chang; Macdonald, Daniel

    2014-11-21

    Effective hydrogenation of interstitial iron in boron-doped multicrystalline silicon wafers is reported. The multicrystalline silicon wafers were annealed with plasma-enhanced chemical vapour deposited silicon nitride films, at temperatures of 400?C??900?C and for times from minutes to hours. At low temperatures where a combined effect of hydrogenation and precipitation of dissolved Fe is expected, results show that the hydrogenation process dominates the effect of precipitation. The concentrations of dissolved interstitial iron reduce by more than 90% after a 30-min anneal at temperatures between 600 and 900?C. The most effective reduction occurs at 700?C, where 99% of the initial dissolved iron is hydrogenated after 30?min. The results show that the observed reductions in interstitial Fe concentrations are not caused by the internal gettering of Fe at structural defects or by an enhanced diffusivity of Fe due to the presence of hydrogen. The hydrogenation process is conjectured to be the pairing of positively charged iron with negatively charged hydrogen, forming less recombination active Fe-H complexes in silicon.

  10. Iron-phosphate ceramics for solidification of mixed low-level waste

    DOE Patents [OSTI]

    Aloy, Albert S.; Kovarskaya, Elena N.; Koltsova, Tatiana I.; Macheret, Yevgeny; Medvedev, Pavel G.; Todd, Terry

    2000-01-01

    A method of immobilizing mixed low-level waste is provided which uses low cost materials and has a relatively long hardening period. The method includes: forming a mixture of iron oxide powders having ratios, in mass %, of FeO:Fe.sub.2 O.sub.3 :Fe.sub.3 O.sub.4 equal to 25-40:40-10:35-50, or weighing a definite amount of magnetite powder. Metallurgical cinder can also be used as the source of iron oxides. A solution of the orthophosphoric acid, or a solution of the orthophosphoric acid and ferric oxide, is formed and a powder phase of low-level waste and the mixture of iron oxide powders or cinder (or magnetite powder) is also formed. The acid solution is mixed with the powder phase to form a slurry with the ratio of components (mass %) of waste:iron oxide powders or magnetite:acid solution=30-60:15-10:55-30. The slurry is blended to form a homogeneous mixture which is cured at room temperature to form the final product.

  11. Temperature evolution of electromotive force from Pt on yttrium-iron-garnet under ferromagnetic resonance

    SciTech Connect (OSTI)

    Ohshima, Ryo; Emoto, Hiroyuki; Shinjo, Teruya; Ando, Yuichiro; Shiraishi, Masashi

    2015-05-07

    Temperature evolution of electromotive force from Pt due to the inverse spin Hall effect is studied. Pure spin current is injected from yttrium-iron-garnet by using spin pumping technique. The electromotive force from the Pt monotonically decreases with decreasing temperature, and it is showed that there is a deviation between the measured and the calculated electromotive forces.

  12. Iron aluminides and nickel aluminides as materials for chemical air separation

    DOE Patents [OSTI]

    Kang, Doohee (Macungie, PA)

    1991-01-01

    The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

  13. Reduction of iron-oxide-carbon composites: part I. Estimation of the rate constants

    SciTech Connect (OSTI)

    Halder, S.; Fruehan, R.J.

    2008-12-15

    A new ironmaking concept using iron-oxide-carbon composite pellets has been proposed, which involves the combination of a rotary hearth furnace (RHF) and an iron bath smelter. This part of the research focuses on studying the two primary chemical kinetic steps. Efforts have been made to experimentally measure the kinetics of the carbon gasification by CO{sub 2} and wustite reduction by CO by isolating them from the influence of heat- and mass-transport steps. A combined reaction model was used to interpret the experimental data and determine the rate constants. Results showed that the reduction is likely to be influenced by the chemical kinetics of both carbon oxidation and wustite reduction at the temperatures of interest. Devolatilized wood-charcoal was observed to be a far more reactive form of carbon in comparison to coal-char. Sintering of the iron-oxide at the high temperatures of interest was found to exert a considerable influence on the reactivity of wustite by virtue of altering the internal pore surface area available for the reaction. Sintering was found to be predominant for highly porous oxides and less of an influence on the denser ores. It was found using an indirect measurement technique that the rate constants for wustite reduction were higher for the porous iron-oxide than dense hematite ore at higher temperatures (> 1423 K). Such an indirect mode of measurement was used to minimize the influence of sintering of the porous oxide at these temperatures.

  14. The Romelt Process -- Prospects for pig iron production in North America

    SciTech Connect (OSTI)

    Thompson, M.W.; Weston, T.R.

    1997-12-31

    The iron and steel industry in North America is undergoing dramatic changes and is being driven by three factors. First, the introduction of new technologies and pace of innovation has placed North America at the forefront of commercializing new technologies. Second, new technologies have changed the market for steelmaking raw materials and stimulated an industry-wide discussion of the ``value in use`` of scrap and scrap substitutes. Finally, an increase in environmental costs has fundamentally changed management`s view toward the environmental impact of iron and steelmaking, particularly in the integrated steel industry. This paper discusses the Romelt Process, an emerging ironmaking technology developed by the Moscow Institute for Steels and Alloys, in the context of these industry trends. ICF Kaiser, a worldwide licensee to the Romelt technology, believes that the current North American climate is probably the most conducive of all steelmaking regions to the commercialization of new technologies. Liquid or cast pig iron, the product of the Romelt Process, is the highest value feed for both the EAF and BOF steelmaking processes. In terms of environmental benefits, Romelt uses non-coking coals for its fuel and reductant, and has a proven large scale pilot plant track record in smelting both low grade fine ores and iron bearing wastes from the integrated works.

  15. Electrochemical polishing of thread fastener test specimens of nickel-chromium iron alloys

    DOE Patents [OSTI]

    Kephart, Alan R.

    1991-01-01

    An electrochemical polishing device and method for selective anodic dissolution of the surface of test specimens comprised, for example, of nickel-chromium-iron alloys, which provides for uniform dissolution at the localized sites to remove metal through the use of a coiled wire electrode (cathode) placed in the immediate proximity of the working, surface resulting in a polished and uniform grain boundary.

  16. Iron aluminides and nickel aluminides as materials for chemical air separation

    DOE Patents [OSTI]

    Kang, D.

    1991-01-29

    The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

  17. A Review of Iron Phosphate Glasses and Recommendations for Vitrifying Hanford Waste

    SciTech Connect (OSTI)

    Delbert E. Ray; Chandra S. Ray

    2013-11-01

    This report contains a comprehensive review of the research conducted, world-wide, on iron phosphate glass over the past ~30 years. Special attention is devoted to those iron phosphate glass compositions which have been formulated for the purpose of vitrifying numerous types of nuclear waste, with special emphasis on the wastes stored in the underground tanks at Hanford WA. Data for the structural, chemical, and physical properties of iron phosphate waste forms are reviewed for the purpose of understanding their (a) outstanding chemical durability which meets all current DOE requirements, (b) high waste loadings which can exceed 40 wt% (up to 75 wt%) for several Hanford wastes, (c) low melting temperatures, can be as low as 900°C for certain wastes, and (d) high tolerance for “problem” waste components such as sulfates, halides, and heavy metals (chromium, actinides, noble metals, etc.). Several recommendations are given for actions that are necessary to smoothly integrate iron phosphate glass technology into the present waste treatment plans and vitrification facilities at Hanford.

  18. Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust

    DOE Patents [OSTI]

    Zaromb, S.; Lawson, D.B.

    1994-02-15

    A process for recovering zinc-rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered by distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10 C, separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream. 1 figure.

  19. Hydrometallurgical process for recovering iron sulfate and zinc sulfate from baghouse dust

    DOE Patents [OSTI]

    Zaromb, Solomon; Lawson, Daniel B.

    1994-01-01

    A process for recovering zinc/rich and iron-rich fractions from the baghouse dust that is generated in various metallurgical operations, especially in steel-making and other iron-making plants, comprises the steps of leaching the dust by hot concentrated sulfuric acid so as to generate dissolved zinc sulfate and a precipitate of iron sulfate, separating the precipitate from the acid by filtration and washing with a volatile liquid, such as methanol or acetone, and collecting the filtered acid and the washings into a filtrate fraction. The volatile liquid may be recovered distillation, and the zinc may be removed from the filtrate by alternative methods, one of which involves addition of a sufficient amount of water to precipitate hydrated zinc sulfate at 10.degree. C., separation of the precipitate from sulfuric acid by filtration, and evaporation of water to regenerate concentrated sulfuric acid. The recovery of iron may also be effected in alternative ways, one of which involves roasting the ferric sulfate to yield ferric oxide and sulfur trioxide, which can be reconverted to concentrated sulfuric acid by hydration. The overall process should not generate any significant waste stream.

  20. Thermal treatment for increasing magnetostrictive response of rare earth-iron alloy rods

    DOE Patents [OSTI]

    Verhoeven, John D.; McMasters, O. D.

    1989-07-18

    Magnetostrictive rods formed from rare earth-iron alloys are subjected to a short time heat treatment to increase their Magnetostrictive response under compression. The heat treatment is preferably carried out at a temperature of from 900.degree. to 1000.degree. C. for 20 minutes to six hours.

  1. Thermal treatment for increasing magnetostrictive response of rare earth-iron alloy rods

    DOE Patents [OSTI]

    Verhoeven, J.D.; McMasters, O.D.

    1989-07-18

    Magnetostrictive rods formed from rare earth-iron alloys are subjected to a short time heat treatment to increase their magnetostrictive response under compression. The heat treatment is preferably carried out at a temperature of from 900 to 1,000 C for 20 minutes to six hours.

  2. The Siderocalin/Enterobactin Interaction: A Link between Mammalian Immunity and Bacterial Iron Transport

    SciTech Connect (OSTI)

    Meux, Susan C.

    2008-05-12

    The siderophore enterobactin (Ent) is produced by enteric bacteria to mediate iron uptake. Ent scavenges iron and is taken up by the bacteria as the highly stable ferric complex [Fe{sup III}(Ent)]{sup 3-}. This complex is also a specific target of the mammalian innate immune system protein, Siderocalin (Scn), which acts as an anti-bacterial agent by specifically sequestering siderophores and their ferric complexes during infection. Recent literature suggesting that Scn may also be involved in cellular iron transport has increased the importance of understanding the mechanism of siderophore interception and clearance by Scn; Scn is observed to release iron in acidic endosomes and [Fe{sup III}(Ent)]{sup 3-} is known to undergo a change from catecholate to salicylate coordination in acidic conditions, which is predicted to be sterically incompatible with the Scn binding pocket (also referred to as the calyx). To investigate the interactions between the ferric Ent complex and Scn at different pH values, two recombinant forms of Scn with mutations in three residues lining the calyx were prepared: Scn-W79A/R81A and Scn-Y106F. Binding studies and crystal structures of the Scn-W79A/R81A:[Fe{sup III}(Ent)]{sup 3-} and Scn-Y106F:[Fe{sup III}(Ent)]{sup 3-} complexes confirm that such mutations do not affect the overall conformation of the protein but do weaken significantly its affinity for [Fe{sup III}(Ent)]{sup 3-}. Fluorescence, UV-Vis and EXAFS spectroscopies were used to determine Scn/siderophore dissociation constants and to characterize the coordination mode of iron over a wide pH range, in the presence of both mutant proteins and synthetic salicylate analogs of Ent. While Scn binding hinders salicylate coordination transformation, strong acidification results in the release of iron and degraded siderophore. Iron release may therefore result from a combination of Ent degradation and coordination change.

  3. In situ treatment of arsenic contaminated groundwater by aquifer iron coating: Experimental Study

    SciTech Connect (OSTI)

    Xie, Xianjun; Wang, Yanxin; Pi, Kunfu; Liu, Chongxuan; Li, Junxia; Liu, Yaqing; Wang, Zhiqiang; Duan, Mengyu

    2015-09-15

    In situ arsenic removal from groundwater by an iron coating method has great potential to be a cost effective and simple groundwater remediation technique, especially in rural and remote areas where groundwater is used as the main source of drinking water. The in situ arsenic removal technique was first optimized by simulating arsenic removal in various quartz sand columns under anoxic conditions., Its effectiveness was then evaluated in an actual high-arsenic groundwater environment. The mechanism of arsenic removal by the iron coating was investigated under different conditions using scanning electron microscopy (SEM)/X-ray absorption spectroscopy, an electron microprobe, and Fourier transformation infrared spectroscopy. A 4-step alternative cycle aquifer iron coating method was developed. A continuous injection of 5 mmol/L FeSO4 and 2.5 mmol/L NaClO for 96 hours can create a uniform coating of crystalline goethite on the surface of quartz sand in the columns without causing clogging. At a flow rate of 0.45 cm/min of the injection reagents (vi), the time for arsenic (as Na2HAsO4) to pass through the iron-coated quartz sand column was approximately 35 hours, which was much longer than that for tracer fluorescein sodium (approximately 2 hours). The retardation factor of arsenic was 23, and its adsorption capacity was 0.11 mol As per mol Fe, leading to an excellent arsenic removal. In situ arsenic removal from groundwater in an aquifer was achieved by simultaneous injections of As (V) and Fe (II) reagents. When the arsenic content in the groundwater was 233 ?g/L, the aqueous phase arsenic was completely removed with an arsenic adsorption of 0.05 mol As per mol Fe. Arsenic fixation resulted from a process of adsorption/co-precipitation, in which arsenic and iron likely formed the arsenic-bearing iron mineral phases with poor crystallinity by way of bidentate binuclear complexes. Thus, the high arsenic removal efficiency of the technique likely resulted from the expanded specific iron oxide/hydroxide surface area with poor crystallinity and from coprecipitation.

  4. Iron-oxide Aerogel and Xerogel Catalyst Formulations: Characterization by 57Fe Mssbauer and XAFS Spectroscopies

    SciTech Connect (OSTI)

    Huggins, F.; Bali, S; Huffman, G; Eyring, E

    2010-01-01

    Iron in various iron-oxide aerogel and xerogel catalyst formulations ({ge}85% Fe{sub 2}O{sub 3}; {le}10% K, Co, Cu, or Pd) developed for possible use in Fischer-Tropsch synthesis (FTS) or the water-gas-shift (WGS) reaction has been examined by {sup 57}Fe Moessbauer spectroscopy. The seventeen samples consisted of both as-prepared and calcined aerogels and xerogels and their products after use as catalysts for FTS or the WGS reaction. Complementary XAFS spectra were obtained on the occurrence of the secondary elements in some of the same materials. A broad, slightly asymmetric, two-peak Moessbauer spectrum was obtained from the different as-prepared and calcined catalyst formulations in the majority of cases. Such spectra could only be satisfactorily fit with three quadrupole doublet components, but no systematic trends in the isomer shift and quadrupole splitting parameters and area ratios of the individual components could be discerned that reflected variations in the composition or preparation of the aerogel or xerogel materials. However, significant reductions were noted in the Moessbauer effective thickness (recoilless absorption effect per unit mass of iron) parameter, {chi}{sub eff}/g, determined at room temperature, for aerogels and xerogels compared to bulk iron oxides, reflecting the openness and lack of rigidity of the aerogel and xerogel structures. Moessbauer measurements for two aerogels over the range from 15 to 292 K confirmed the greatly diminished nature of this parameter at room temperature. Major increases in the effective thickness parameter were observed when the open structure of the aerogel or xerogel collapsed during calcination resulting in the formation of iron oxides (hematite, spinel ferrite). Similar structural changes were indicated by increases in this parameter after use of iron-oxide aerogels as catalysts for FTS or the WGS reaction, during which the iron-oxide aerogel was converted to a mixture of nonstoichiometric magnetite and the Haegg carbide, {chi}-Fe{sub 5}C{sub 2}, or nonstoichiometric magnetite, respectively.

  5. Next Generation Metallic Iron Nodule Technology in Electric Arc Steelmaking - Phase II

    SciTech Connect (OSTI)

    Donald R. Fosnacht; Iwao Iwasaki; Richard F. Kiesel; David J. Englund; David W. Hendrickson; Rodney L. Bleifuss

    2010-12-22

    The current trend in the steel industry is a gradual decline in conventional steelmaking from taconite pellets in blast furnaces, and an increasing number of alternative processes using metallic scrap iron, pig iron and metallized iron ore products. Currently, iron ores from Minnesota and Michigan are pelletized and shipped to the lower Great Lakes ports as blast furnace feed. The existing transportation system and infrastructure is geared to handling these bulk materials. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the needs of the emerging steel industry while utilizing the existing infrastructure and materials handling. A recent commercial installation employing Kobe Steel’s ITmk3 process, was installed in Northeastern Minnesota. The basic process uses a moving hearth furnace to directly reduce iron oxides to metallic iron from a mixture of iron ore, coals and additives. The resulting products can be shipped using the existing infrastructure for use in various steelmaking processes. The technology reportedly saves energy by 30% over the current integrated steelmaking process and reduces emissions by more than 40%. A similar large-scale pilot plant campaign is also currently in progress using JFE Steel’s Hi-QIP process in Japan. The objective of this proposal is to build upon and improve the technology demonstrated by Kobe Steel and JFE, by further reducing cost, improving quality and creating added incentive for commercial development. This project expands previous research conducted at the University of Minnesota Duluth’s Natural Resources Research Institute and that reported by Kobe and JFE Steel. Three major issues have been identified and are addressed in this project for producing high-quality nodular reduced iron (NRI) at low cost: (1) reduce the processing temperature, (2) control the furnace gas atmosphere over the NRI, and (3) effectively use sub-bituminous coal as a reductant. From over 4000 laboratory tube and box furnace tests, it was established that the correct combination of additives, fluxes, and reductant while controlling the concentration of CO and CO2 in the furnace atmosphere (a) lowers the operating temperature, (b) decreases the use of reductant coal (c) generates less micro nodules of iron, and (d) promotes desulphurization. The laboratory scale work was subsequently verified on 12.2 m (40 ft) long pilot scale furnace. High quality NRI could be produced on a routine basis using the pilot furnace facility with energy provided from oxy-gas or oxy-coal burner technologies. Specific strategies were developed to allow the use of sub-bituminous coals both as a hearth material and as part of the reaction mixture. Computational Fluid Dynamics (CFD) modeling was used to study the overall carbothermic reduction and smelting process. The movement of the furnace gas on a pilot hearth furnace and larger simulated furnaces and various means of controlling the gas atmosphere were evaluated. Various atmosphere control methods were identified and tested during the course of the investigation. Based on the results, the appropriate modifications to the furnace were made and tested at the pilot scale. A series of reduction and smelting tests were conducted to verify the utility of the processing conditions. During this phase, the overall energy use characteristics, raw materials, alternative fuels, and the overall economics predicted for full scale implementation were analyzed. The results indicate that it should be possible to lower reaction temperatures while simultaneously producing low sulfur, high carbon NRI if the right mix chemistry and atmosphere are employed. Recommendations for moving the technology to the next stage of commercialization are presented.

  6. Iron-Doped Carbon Aerogels: Novel Porous Substrates for Direct Growth of Carbon Nanotubes

    SciTech Connect (OSTI)

    Steiner, S A; Baumann, T F; Kong, J; Satcher, J H; Dresselhaus, M S

    2007-02-15

    We present the synthesis and characterization of Fe-doped carbon aerogels (CAs) and demonstrate the ability to grow carbon nanotubes directly on monoliths of these materials to afford novel carbon aerogel-carbon nanotube composites. Preparation of the Fe-doped CAs begins with the sol-gel polymerization of the potassium salt of 2,4-dihydroxybenzoic acid with formaldehyde, affording K{sup +}-doped gels that can then be converted to Fe{sup 2+}- or Fe{sup 3+}-doped gels through an ion exchange process, dried with supercritical CO{sub 2} and subsequently carbonized under an inert atmosphere. Analysis of the Fe-doped CAs by TEM, XRD and XPS revealed that the doped iron species are reduced during carbonization to form metallic iron and iron carbide nanoparticles. The sizes and chemical composition of the reduced Fe species were related to pyrolysis temperature as well as the type of iron salt used in the ion exchange process. Raman spectroscopy and XRD analysis further reveal that, despite the presence of the Fe species, the CA framework is not significantly graphitized during pyrolysis. The Fe-doped CAs were subsequently placed in a thermal CVD reactor and exposed to a mixture of CH{sub 4} (1000 sccm), H{sub 2} (500 sccm), and C{sub 2}H{sub 4} (20 sccm) at temperatures ranging from 600 to 800 C for 10 minutes, resulting in direct growth of carbon nanotubes on the aerogel monoliths. Carbon nanotubes grown by this method appear to be multiwalled ({approx}25 nm in diameter and up to 4 mm long) and grow through a tip-growth mechanism that pushes catalytic iron particles out of the aerogel framework. The highest yield of CNTs were grown on Fe-doped CAs pyrolyzed at 800 C treated at CVD temperatures of 700 C.

  7. Efficient laser-induced 6-8 keV x-ray production from iron oxide aerogel

    Office of Scientific and Technical Information (OSTI)

    and foil-lined cavity targets (Journal Article) | SciTech Connect Efficient laser-induced 6-8 keV x-ray production from iron oxide aerogel and foil-lined cavity targets Citation Details In-Document Search Title: Efficient laser-induced 6-8 keV x-ray production from iron oxide aerogel and foil-lined cavity targets The performance of new iron-based laser-driven x-ray sources has been tested at the OMEGA laser facility for production of x rays in the 6.5-8.5 keV range. Two types of targets were

  8. PHASE II CALDERON PROCESS TO PRODUCE DIRECT REDUCED IRON RESEARCH AND DEVELOPMENT PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2005-10-14

    The commercialization path of the Calderon technology for making a feedstock for steelmaking with assistance from DOE initially focused on making coke and work was done which proved that the Calderon technology is capable of making good coke for hard driving blast furnaces. U.S. Steel which participated in such demonstration felt that the Calderon technology would be more meaningful in lowering the costs of making steel by adapting it to the making of iron--thus obviating the need for coke. U.S. Steel and Calderon teamed up to jointly work together to demonstrate that the Calderon technology will produce in a closed system iron units from iron concentrate (ore) and coal competitively by eliminating pelletizing, sintering, coking and blast furnace operation. If such process steps could be eliminated, a huge reduction in polluting emissions and greenhouse gases (including CO{sub 2}) relating to steelmaking would ensue. Such reduction will restructure the steel industry away from the very energy-intensive steelmaking steps currently practiced and drastically reduce costs of making steel. The development of a technology to lower U.S. steelmaking costs and become globally competitive is a priority of major importance. Therefore, the development work which Calderon is conducting presently under this Agreement with the U.S. Department of Energy becomes more crucial than ever. During the 3rd quarter of 2005 which the present report covers, virtually all the effort to advance the Calderon technology to make iron units was concentrated towards forming a team with a steelmaker who needs both iron units in the form of hot metal and a substitute for natural gas (SNG), both being major contributors to higher costs in steelmaking. Calderon felt that a very good candidate would be Steel Dynamics (SDI) by virtue that it operates a rotary hearth facility in Butler, Indiana that uses large amounts of natural gas to reduce briquettes made from ore and coal that they subsequently melt in a submerged arc furnace that is a large consumer of electric power. This facility is operated as a division of SDI under the name of Iron Dynamics (IDI). It is no secret that IDI has had and still has a great number of operational problems, including high cost for natural gas.

  9. Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

    SciTech Connect (OSTI)

    Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

    2011-12-22

    The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting iron ore to metallic iron nodules. Various types of coals including a bio-coal produced though torrefaction can result in production of NRI at reduced GHG levels. The process results coupled with earlier already reported developments indicate that this process technique should be evaluated at the next level in order to develop parameter information for full scale process design. Implementation of the process to full commercialization will require a full cost production analysis and comparison to other reduction technologies and iron production alternatives. The technical results verify that high quality NRI can be produced under various operating conditions at the pilot level.

  10. Controllable 0 − π transition in iron pnictide superconductor junctions with a spacer of strong ferromagnet

    SciTech Connect (OSTI)

    Liu, S. Y.; Tao, Y. C. Ji, T. T.; Di, Y. S.; Hu, J. G.

    2014-03-17

    We investigate the control of 0−π transition in Josephson junctions consisting of a highly spin-polarized ferromagnet coupled to two iron pnictide superconductors (SCs). It is shown that, a 0−π transition as a function of interband coupling strength is always exhibited, which can be experimentally used to discriminate the s{sub ±}-wave pairing symmetry in the iron pnictide SCs from the s{sub ++}-wave one in MgB{sub 2}. By tuning the doping level in the s{sub ±}-wave SCs, one can vary the interband coupling strength so as to obtain the controllable 0−π transition. This device may be realized with current technologies and has practical use in Cooper pair spintronics and quantum information.

  11. High-temperature corrosion-resistant iron-aluminide (FeAl) alloys exhibiting improved weldability

    DOE Patents [OSTI]

    Maziasz, Philip J. (Oak Ridge, TN); Goodwin, Gene M. (Lenoir City, TN); Liu, Chain T. (Oak Ridge, TN)

    1996-01-01

    This invention relates to improved corrosion-resistant iron-aluminide intermetallic alloys. The alloys of this invention comprise, in atomic percent, from about 30% to about 40% aluminum alloyed with from about 0.1% to about 0.5% carbon, no more than about 0.04% boron such that the atomic weight ratio of boron to carbon in the alloy is in the range of from about 0.01:1 to about 0.08:1, from about 0.01 to about 3.5% of one or more transition metals selected from Group IVB, VB, and VIB elements and the balance iron wherein the alloy exhibits improved resistance to hot cracking during welding.

  12. Iron hydroxyl phosphate microspheres: Microwave-solvothermal ionic liquid synthesis, morphology control, and photoluminescent properties

    SciTech Connect (OSTI)

    Cao Shaowen; Zhu Yingjie; Cui Jingbiao

    2010-07-15

    A variety of iron hydroxyl phosphate (NH{sub 4}Fe{sub 2}(PO{sub 4}){sub 2}OH.2H{sub 2}O) nanostructures such as solid microspheres, microspheres with the core in the hollow shell, and double-shelled hollow microspheres were synthesized by a simple one-step microwave-solvothermal ionic liquid method. The effects of the experimental parameters on the morphology and crystal phase of the resultant materials were investigated. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres and the underlying mechanisms were discussed. - Graphical abstract: A variety of iron hydroxyl phosphate (NH{sub 4}Fe{sub 2}(PO{sub 4}){sub 2}OH.2H{sub 2}O) nanostructures were synthesized by a simple one-step microwave-solvothermal ionic liquid method. Structural dependent photoluminescence was observed from the double-shelled hollow microspheres.

  13. Method for preparing high cure temperature rare earth iron compound magnetic material

    DOE Patents [OSTI]

    Huang, Yuhong; Wei, Qiang; Zheng, Haixing

    2002-01-01

    Insertion of light elements such as H,C, or N in the R.sub.2 Fe.sub.17 (R=rare earth metal) series has been found to modify the magnetic properties of these compounds, which thus become prospective candidates for high performance permanent magnets. The most spectacular changes are increases of the Curie temperature, T.sub.c, of the magnetization, M.sub.s, and of coercivity, H.sub.c, upon interstitial insertion. A preliminary product having a component R--Fe--C,N phase is produced by a chemical route. Rare earth metal and iron amides are synthesized followed by pyrolysis and sintering in an inert or reduced atmosphere, as a result of which, the R--Fe--C,N phases are formed. Fabrication of sintered rare earth iron nitride and carbonitride bulk magnet is impossible via conventional process due to the limitation of nitridation method.

  14. Anodic oxygen-transfer electrocatalysis at iron-doped lead dioxide electrodes

    SciTech Connect (OSTI)

    Feng, Jianren

    1994-10-01

    The research illustrated in this thesis was performed under the guidance of Professor Dennis C. Johnson beginning in March 1987. Chapter 2 concentrates on the development and electrocatalytic properties of iron-doped {beta}-PbO{sub 2} films on noble-metal substrates. Chapter 3 focuses attention on the preparation and characterization of iron-doped {beta}-PbO{sub 2} films on titanium substrates (Fe-PbO{sub 2}/Ti). Chapter 4 discusses anodic evolution of ozone at Fe-PbO{sub 2}/Ti electrodes. Chapter 5 describes electrochemical incineration of p-benzoquinone (BQ) at Fe-PbO{sub 2}/Ti electrodes. In addition, the Appendix includes another published paper which is a detailed study of {alpha}-PbO{sub 2} films deposited on various types of stainless steel substrates.

  15. Effect of FeO-content and potentials for quality improvements of iron ore pellets

    SciTech Connect (OSTI)

    Kortmann, H.A.; Mertins, E.; Ritz, V.J.

    1995-12-01

    The FeO-content strongly influences the physical and metallurgical properties of iron ore pellets. A wide range of FeO-contents within the pellet deliveries to the Germany market is evaluated. Investigations include the effect of pellet size. The paper concludes potentials for quality improvement of iron ore pellets. Most of the German blast furnaces are operated with high injection rates either of oil or of coal resulting in a decrease of coke consumption down to a level of about 300 kg/t hot metal. As the retention time of the burden increases, blast furnace operators demand higher quality burden material, basically with respect to strength before and during reduction.

  16. A study on the flow of molten iron in the hearth of blast furnace

    SciTech Connect (OSTI)

    Suh, Y.K.; Lee, Y.J.; Baik, C.Y.

    1996-12-31

    The flow of molten iron in the hearth of blast furnace was investigated by using a water model test and a numerical simulation. The water model apparatus was set up in order to evaluate the effects of coke size, coke bed structure, drain rate, and coke free space on the fluidity of molten iron through measurement of residence time and visualization of flow pattern. In addition, the flow was calculated by solving momentum equation in porous media using finite element method. The residence time increased with the coke size decrease, but decreased with the drain rate increase. If small coke was placed in the center of deadman, peripheral flow was enhanced. The flow path was changed due to the coke free space.

  17. Hydrogen-deuterium reactions on palladium-iron bilayers: A permeation investigation

    SciTech Connect (OSTI)

    Kuhn, D.K.; Johnson, H.H.

    1988-10-01

    The permeation of hydrogen, deuterium, and hydrogen-deuterium through iron coated with thin surface films of palladium has been measured. The experimental steady-state fluxes show the expected isotope diffusivity dependence in iron. A new observation is that hydrogen and deuterium react on the palladium surface to form HD, and this affects the permeation fluxes. The results are in good agreement with a model incorporating second-order surface kinetics which allow for competition between hydrogen and deuterium for surface sites. The theory predicts that the hydrogen/deuterium surface coverage ratio on palladium is approx.4 at room temperature for equal H/sub 2/ and D/sub 2/ pressures.

  18. Kinetic temperatures of iron ions in the solar wind observed with STEREO/PLASTIC

    SciTech Connect (OSTI)

    Bochsler, Peter; Lee, Martin A.; Popecki, Mark A.; Galvin, Antoinette B.; Kistler, Lynn M.; Moebius, Eberhard; Farrugia, Charles J.; Kucharek, Harald; Simunac, Kristin D. C.; Karrer, Reto; Blush, Lisa M.; Daoudi, Hagar; Wurz, Peter; Klecker, Berndt; Wimmer-Schweingruber, Robert F.; Thompson, Barbara; Luhmann, Janet G.; Jian, Lan K.; Russell, Christopher T.; Opitz, Andrea

    2010-03-25

    STEREO/PLASTIC provides detailed information on the three-dimensional velocity distributions of solar wind iron ions with a time resolution of 5 minutes. In general the distributions at 1 AU contain complicated structures showing persistence over several records, i.e., over intervals of up to 30 minutes, but no clear correlation of the properties of these distributions with the direction of the ambient magnetic field is evident. We have performed a statistical analysis using nearly 9000 observations. Iron ions follow the same trends as protons, alpha particles, and electrons: The ratio T{sub perpendicular}/T{sub ||} seems to be limited by the ion cyclotron instability, whereas T{sub ||} /T{sub perpendicular} is bounded by the firehose instability.

  19. Lithium insertion mechanism in iron-based oxyfluorides with anionic vacancies probed by PDF analysis

    SciTech Connect (OSTI)

    Dambournet, Damien; Chapman, Karena W.; Duttine, Mathieu; Borkiewicz, Olaf; Chupas, Peter J.; Groult, Henri

    2015-06-25

    The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties.

  20. Lithium insertion mechanism in iron-based oxyfluorides with anionic vacancies probed by PDF analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dambournet, Damien; Chapman, Karena W.; Duttine, Mathieu; Borkiewicz, Olaf; Chupas, Peter J.; Groult, Henri

    2015-06-25

    The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing thatmore » the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties.« less