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Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
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1

Injection of Zero Valent Iron into an Unconfined Aquifer Using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Injection of Zero Valent Iron into an Unconfined Aquifer Using Shear-Thinning Fluids. Injection of Zero Valent Iron into an Unconfined Aquifer Using Shear-Thinning Fluids....

2

Demonstration of Combined Zero-Valent Iron and Electrical Resistance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Demonstration of Combined Zero-Valent Iron and Electrical Resistance Heating for In Situ Trichloroethene Remediation. Demonstration of Combined Zero-Valent Iron and Electrical...

3

Zero-valent iron nanoparticles preparation  

SciTech Connect (OSTI)

Graphical abstract: Zero-valent iron nanoparticles were synthesized by hydrogenating [Fe[N(Si(CH{sub 3}){sub 3}){sub 2}]{sub 2}] at room temperature and a pressure of 3 atm. The synthesized nanoparticles were spherical and had diameters less than 5 nm. Highlights: ? Zero-valent iron nanoparticles were synthesized by hydrogenating [Fe[N(Si(CH{sub 3}){sub 3}){sub 2}]{sub 2}]. ? The conditions of reaction were at room temperature and a pressure of 3 atm. ? The synthesized nanoparticles were spherical and had diameters less than 5 nm. -- Abstract: Zero-valent iron nanoparticles were synthesized by hydrogenating [Fe[N(Si(CH{sub 3}){sub 3}){sub 2}]{sub 2}] at room temperature and a pressure of 3 atm. To monitor the reaction, a stainless steel pressure reactor lined with PTFE and mechanically stirred was designed. This design allowed the extraction of samples at different times, minimizing the perturbation in the system. In this way, the shape and the diameter of the nanoparticles produced during the reaction were also monitored. The results showed the production of zero-valent iron nanoparticles that were approximately 5 nm in diameter arranged in agglomerates. The agglomerates grew to 900 nm when the reaction time increased up to 12 h; however, the diameter of the individual nanoparticles remained almost the same. During the reaction, some byproducts constituted by amino species acted as surfactants; therefore, no other surfactants were necessary.

Oropeza, S. [Instituto Politécnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer Piso, C.P. 07738, Col. San Pedro Zacatenco, México D.F. (Mexico)] [Instituto Politécnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer Piso, C.P. 07738, Col. San Pedro Zacatenco, México D.F. (Mexico); Corea, M., E-mail: mcoreat@yahoo.com.mx [Instituto Politécnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer Piso, C.P. 07738, Col. San Pedro Zacatenco, México D.F. (Mexico); Gómez-Yáñez, C. [Instituto Politécnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer Piso, C.P. 07738, Col. San Pedro Zacatenco, México D.F. (Mexico)] [Instituto Politécnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer Piso, C.P. 07738, Col. San Pedro Zacatenco, México D.F. (Mexico); Cruz-Rivera, J.J. [Universidad Autónoma de San Luis Potosí, Instituto de Metalurgia, Sierra Leona 550, San Luis Potosí, C.P. 78210 (Mexico)] [Universidad Autónoma de San Luis Potosí, Instituto de Metalurgia, Sierra Leona 550, San Luis Potosí, C.P. 78210 (Mexico); Navarro-Clemente, M.E., E-mail: mnavarroc@ipn.mx [Instituto Politécnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer Piso, C.P. 07738, Col. San Pedro Zacatenco, México D.F. (Mexico)

2012-06-15T23:59:59.000Z

4

Chromate transport through columns packed with surfactant-modified zeolite/zero valent iron pellets  

E-Print Network [OSTI]

Chromate transport through columns packed with surfactant-modified zeolite/zero valent iron pellets Chromate transport through columns packed with zeolite/zero valent iron (Z/ZVI) pellets, either untreated originated from chromate sorption onto the HDTMA modified Z/ZVI pellets. Due to dual porosity, the presence

Li, Zhaohui

5

Degradation of Polymers Coating Nano-scale Zero Valent Iron Particles used in Groundwater Remediation  

E-Print Network [OSTI]

Degradation of Polymers Coating Nano-scale Zero Valent Iron Particles used in Groundwater chemicals (Zhang, 2003). Nano-scale zero valent iron (NZVI) can be injected into the soil to degrade centrifugation. UV spectrophotometer: The polymers could be quantified when dissolved in pure water or in mineral

Barthelat, Francois

6

Sulfur-Modified Zero-Valent Iron for Remediation Applications at DOE Sites - 13600  

SciTech Connect (OSTI)

Many DOE remediation sites have chemicals of concern that are compounds in higher oxidation states, which make them both more mobile and more toxic. The chemical reduction of these compounds both prevents the migration of these chemicals and in some cases reduces the toxicity. It has also been shown that zero-valent iron is a very effective substance to use in reducing oxygenated compounds in various treatment processes. These have included the treatment of halogenated hydrocarbons in the form volatile organic compounds used as solvents and pesticides. Zero-valent iron has also been used to reduce various oxidized metals such as chromium, arsenic, and mercury in order to immobilize them, decrease their toxicity, and prevent further transport. In addition, it has been used to immobilize or break down other non-metallic species such as selenium compounds and nitrates. Of particular interest at several DOE remediation sites is the fact that zero-valent iron is very effective in immobilizing several radioactive metals which are mobile in their oxidized states. These include both technetium and uranium. The main difficulty in using zero-valent iron has been its tendency to become inactive after relatively short periods of time. While it is advantageous to have the zero-valent iron particles as porous as possible in order to provide maximum surface area for reactions to take place, these pores can become clogged when the iron is oxidized. This is due to the fact that ferric oxide has a greater volume for a given mass than metallic iron. When the surfaces of the iron particles oxidize to ferric oxide, the pores become narrower and will eventually shut. In order to minimize the degradation of the chemical activity of the iron due to this process, a modification of zero-valent iron has been developed which prevents or slows this process, which decreases its effectiveness. It is called sulfur-modified iron, and it has been produced in high purity for applications in municipal water treatment applications. Sulfur-modified iron has been found to not only be an extremely economical treatment technology for municipal water supplies, where very large quantities of water must be treated economically, but it has also been demonstrated to immobilize technetium. It has the added benefit of eliminating several other harmful chemicals in water supplies. These include arsenic and selenium. In one large-scale evaluation study an integrated system implemented chemical reduction of nitrate with sulfur-modified iron followed by filtration for arsenic removal. The sulfur-modified iron that was used was an iron-based granular medium that has been commercially developed for the removal of nitrate, co-contaminants including uranium, vanadium and chromium, and other compounds from water. The independent study concluded that 'It is foreseen that the greatest benefit of this technology (sulfur-modified iron) is that it does not produce a costly brine stream as do the currently accepted nitrate removal technologies of ion exchange and reverse osmosis. This investigation confirmed that nitrate reduction via sulfur-modified iron is independent of the hydraulic loading rate. Future sulfur-modified iron treatment systems can be designed without restriction of the reactor vessel dimensions. Future vessels can be adapted to existing site constraints without being limited to height-to-width ratios that would exist if nitrate reduction were to depend on hydraulic loading rate'. Sulfur-modified iron was studied by the Pacific Northwest National Laboratory (PNNL) for its effectiveness in the reduction and permanent sequestration of technetium. The testing was done using Hanford Site groundwater together with sediment. The report stated, 'Under reducing conditions, TcO{sub 4} is readily reduced to TcIV, which forms highly insoluble oxides such at TcO{sub 2}.nH{sub 2}O. However, (re)oxidation of TcIV oxides can lead to remobilization. Under sulfidogenic conditions, most TcIV will be reduced and immobilized as Tc{sub 2}S{sub 7}, which is less readily re-mobilized, ev

Fogwell, Thomas W. [Fogwell Consulting, P.O. Box 20221, Piedmont, CA 94620 (United States)] [Fogwell Consulting, P.O. Box 20221, Piedmont, CA 94620 (United States); Santina, Pete [SMI-PS, Inc., 2073 Prado Vista, Lincoln, CA 95648 (United States)] [SMI-PS, Inc., 2073 Prado Vista, Lincoln, CA 95648 (United States)

2013-07-01T23:59:59.000Z

7

Chemical Reduction of PCE by Zero Valent Iron Colloids Batch and Column Experiments  

E-Print Network [OSTI]

Chemical Reduction of PCE by Zero Valent Iron Colloids ­ Batch and Column Experiments Motivation nm NAPASAN Particle - nZVI / PCE-Solution 0 20 40 60 80 100 120 140 0 2 4 6 8 10 12 14 16 18 20 22 24H[-] PCE - Inflow PCE - Outflow TCE - Inflow TCE - Outflow Chloride - Outflow Blank Value Chloride pH Value

Cirpka, Olaf Arie

8

Zero Valent Iron: Impact of Anions Present during Synthesis on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

iron nanoparticles was quantified by monitoring the kinetics as well as products of carbon tetrachloride reduction, and significant differences in reactivity and chloroform...

9

Calcite precipitation dominates the electrical signatures of zero valent iron columns under simulated field conditions  

SciTech Connect (OSTI)

Calcium carbonate is a secondary mineral precipitate influencing zero valent iron (ZVI) barrier reactivity and hydraulic performance. We conducted column experiments to investigate electrical signatures resulting from concurrent CaCO{sub 3} and iron oxides precipitation under simulated field geochemical conditions. We identified CaCO{sub 3} as a major mineral phase throughout the columns, with magnetite present primarily close to the influent based on XRD analysis. Electrical measurements revealed decreases in conductivity and polarization of both columns, suggesting that electrically insulating CaCO{sub 3} dominates the electrical response despite the presence of electrically conductive iron oxides. SEM/EDX imaging suggests that the electrical signal reflects the geometrical arrangement of the mineral phases. CaCO{sub 3} forms insulating films on ZVI/magnetite surfaces, restricting charge transfer between the pore electrolyte and ZVI particles, as well as across interconnected ZVI particles. As surface reactivity also depends on the ability of the surface to engage in redox reactions via charge transfer, electrical measurements may provide a minimally invasive technology for monitoring reactivity loss due to CaCO{sub 3} precipitation. Comparison between laboratory and field data shows consistent changes in electrical signatures due to iron corrosion and secondary mineral precipitation.

Wu, Yuxin; Versteeg, R.; Slater, L.; LaBrecque, D.

2009-06-01T23:59:59.000Z

10

Degradation of carbon tetrachloride in the presence of zero-valent iron.  

SciTech Connect (OSTI)

Efforts to achieve the decomposition of carbon tetrachloride through anaerobic and aerobic bioremediation and chemical transformation have met with limited success because of the conditions required and the formation of hazardous intermediates. Recently, particles of zero-valent iron (ZVI) have been used with limited success for in situ remediation of carbon tetrachloride. We studied a modified microparticulate product that combines controlled-release carbon with ZVI for stimulation of in situ chemical reduction of persistent organic compounds in groundwater. With this product, a number of physical, chemical, and microbiological processes were combined to create very strongly reducing conditions that stimulate rapid, complete dechlorination of organic solvents. In principle, the organic component of ZVI microparticles is nutrient rich and hydrophilic and has high surface area capable of supporting the growth of bacteria in the groundwater environment. In our experiments, we found that as the bacteria grew, oxygen was consumed, and the redox potential decreased to values reaching -600 mV. The small modified ZVI particles provide substantial reactive surface area that, in these conditions, directly stimulates chemical dechlorination and cleanup of the contaminated area without accumulation of undesirable breakdown products. The objective of this work was to evaluate the effectiveness of ZVI microparticles in reducing carbon tetrachloride under laboratory and field conditions. Changes in concentrations and in chemical and physical parameters were monitored to determine the role of the organic products in the reductive dechlorination reaction. Laboratory and field studies are presented.

Alvarado, J. S.; Rose, C.; LaFreniere, L.; Environmental Science Division

2010-01-01T23:59:59.000Z

11

Deployment of an innovative thermally enhanced soil mixing process augmented with zero-valent iron.  

SciTech Connect (OSTI)

An innovative in-situ soil treatment process, referred to as soil mixing/thermally enhanced soil vapor extraction (SM/TESVE), was used to remediate the 317 Area of Argonne National Laboratory-East (i.e., Argonne), which is contaminated with volatile organic compounds (VOCs). Following the initial soil treatment, polishing was required to reduce residual concentrations of contaminants. A study of polishing methods was conducted. It determined that injecting metallic iron particles into the soil, in conjunction with soil mixing, would reduce residual VOC concentrations more effectively than the original conventional soil ventilation approach. After the effectiveness of iron injection was verified, it replaced the soil ventilation step. The modified process involved mixing the soil while hot air and steam were injected into it. Off-gases were captured in a hood over the treatment area. During this process, an iron slurry, consisting of up to 50% iron particles in water with guar gum added as a thickening agent, was injected and mixed into the soil by the mixing equipment. Approximately 6,246 m{sup 3} (8, 170 yd{sup 3}) of soil was treated during this project. Confirmatory samples were then collected. In these samples, VOC concentrations were usually reduced by more than 80%.

Lynch, P. L.

1999-01-15T23:59:59.000Z

12

An Experimental Study of Micron-Size Zero-Valent Iron Emplacement in Permeable Porous Media Using Polymer-Enhanced Fluids  

SciTech Connect (OSTI)

At the Hanford Site, an extensive In Situ Redox Manipulation (ISRM) permeable reactive barrier was installed to prevent chromate from reaching the Columbia River. However, chromium has been detected in several wells, indicating a premature loss of the reductive capacity in the aquifer. One possible cause for premature chromate breakthrough is associated with the presence of high-permeability zones in the aquifer. In these zones, groundwater moves relatively fast and is able to oxidize iron more rapidly. There is also a possibility that the high-permeability flow paths are deficient in reducing equivalents (e.g. reactive iron), required for barrier performance. One way enhancement of the current barrier reductive capacity can be achieved is by the addition of micron-scale zero-valent iron to the high-permeability zones within the aquifer. The potential emplacement of zero-valent iron (Fe0) into high-permeability Hanford sediments (Ringold Unit E gravels) using shear-thinning fluids containing polymers was investigated in three-dimensional wedge-shaped aquifer models. Polymers were used to create a suspension viscous enough to keep the Fe0 in solution for extended time periods to improve colloid movement into the porous media without causing a permanent detrimental decrease in hydraulic conductivity. Porous media were packed in the wedge-shaped flow cell to create either a heterogeneous layered system with a high-permeability zone in between two low-permeability zones or a high-permeability channel surrounded by low-permeability materials. The injection flow rate, polymer type, polymer concentration, and injected pore volumes were determined based on preliminary short- and long-column experiments.

Oostrom, Mart; Wietsma, Thomas W.; Covert, Matthew A.; Vermeul, Vince R.

2005-12-22T23:59:59.000Z

13

Fundamental Studies of The Removal of Contaminants from Ground and Waste Waters Via Reduction By Zero-Valent metals  

SciTech Connect (OSTI)

Oxyanions of uranium, selenium, chromium, arsenic, technetium, and chlorine (as perchlorate) are frequently found as contaminants on many DOE sites, and in other areas of the U.S.. A potential remediation method is to react the contaminated water with zero-valent iron (ZVI). We are performing fundamental investigations of the interactions of the relevant compounds with Fe filings and single- and poly-crystalline surfaces. The aim of this work is to develop the physical and chemical understanding that is necessary for the development of cleanup techniques and procedures.

Jory A. Yarmoff; Christopher Amrhein

2002-04-23T23:59:59.000Z

14

Degradation of organic and inorganic contaminants by zero valent iron  

E-Print Network [OSTI]

/Feo. The only product observed in the reduction of 2,4-DNT was 2,4-diaminotoluene (2,4-DAT). The 2,4-DAT produced accounted for 83-100% and only 42-54% of the initial mass of 2@4.DNT under anaerobic and aerobic conditions respectively. Since no degradation of 2...

Malla, Deepak Babu

1997-01-01T23:59:59.000Z

15

Electrochemical deposition of green rust on zero-valent iron  

E-Print Network [OSTI]

.............................................. 22 3 Analysis of green rust for content of Fe(II) and Fe(III) after extraction by 0.12 N HCl or Endox ................................................................................................................ 25 4... immersed in seawater and on the hulls of large ships (3). Green rusts are compounds with double-layers of mixed Fe(II)-Fe(III) hydroxides surrounding a layer of anions (A -n ). This structure can be represented by the general formula (Fe II ) 6-x (Fe...

Kulkarni, Dhananjay Vijay

2006-08-16T23:59:59.000Z

16

Demonstration of Combined Zero-Valent Iron and Electrical Resistance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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17

Injection of Zero Valent Iron into an Unconfined Aquifer Using  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared Land Surface Emissivity in the VicinitySrTiO3(100).Initiatives

18

Perchlorate reduction using electrochemically induced pitting corrosion of zero-valent titanium  

E-Print Network [OSTI]

effective technologies, especially chemical treatments, to completely destroy trace levels of perchlorate present in drinking and groundwater. The research on perchlorate reduction by zero-valent titanium (Ti(0)) showed that perchlorate was effectively...

Lee, Chun Woo

2009-05-15T23:59:59.000Z

19

Fundamental Studies of the Removal of Contaminants from Ground and Waste Waters via Reduction by Zero-Valent Metals  

SciTech Connect (OSTI)

Contaminated groundwater and surface waters are a problem throughout the United States and the world. In many instances, the types of contamination can be directly attributed to man's actions. For instance, the burial of chemical wastes, casual disposal of solvents in unlined pits, and the development of irrigated agriculture have all contributed to groundwater and surface water contamination. The kinds of contaminants include chlorinated solvents and toxic trace elements (including radioisotopes) that are soluble and mobile in soils and aquifers. Oxyanions of uranium, selenium, chromium, arsenic, technetium, and chlorine (as perchlorate) are frequently found as contaminants on many DOE sites. Uranium is a particularly widespread contaminant at most DOE sites including Oak Ridge, Rocky Flats, Hanford, Idaho (INEEL), and Fernald. The uranium contamination is associated with mining and milling of uranium ore (UMTRA sites), isotope separation and enrichment, and mixed waste and TRU waste burial. In addition, the careless disposal of halogenated solvents, such as carbon tetrachloride and trichloroethylene, has further contaminated many groundwaters at these sites. A potential remediation method for many of these oxyanions and chlorinated-solvents is to react the contaminated water with zero-valent iron. In this reaction, the iron serves as both an electron source and as a catalyst. Elemental iron is already being used on an experimental basis at many DOE sites. Both in situ reactive barriers and above-ground reactors are being developed for this purpose. However, the design and operation of these treatment systems requires a detailed process-level understanding of the interactions between the contaminants and the iron surfaces. We are performing fundamental investigations of the interactions of the relevant chlorinated solvents and trace element-containing compounds with single- and poly-crystalline Fe surfaces. The aim of this work is to develop th e fundamental physical and chemical understanding that is necessary for the development of cleanup techniques and procedures.

Yarmoff, Jory A.; Amrhein, Christopher

1999-06-01T23:59:59.000Z

20

Performance of a Permeable Reactive Barrier Using Granular Zero-Valent  

Broader source: Energy.gov (indexed) [DOE]

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Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Calcite precipitation dominates the electrical signatures of zero valent iron columns under simulated field conditions  

E-Print Network [OSTI]

of the electrical signatures from magnetite/fougerite vs.electrical properties of the different mineralogies: i.e. conductive and polarizable magnetite/fougerite vs.

Wu, Yuxin

2009-01-01T23:59:59.000Z

22

Aminoclay-templated nanoscale zero-valent iron (nZVI) synthesis for efficient harvesting of  

E-Print Network [OSTI]

of oleaginous microalga, Chlorella sp. KR-1 Young-Chul Lee,ae Kyubock Lee,b Yuhoon Hwang,c Henrik Rasmus ). On the basis of these characteristics, oleaginous Chlorella sp. KR-1 was harvested within 3 min at a > 20 g LÃ?1

Mosegaard, Klaus

23

Dechlorination of PCE by mixtures of green rust and zero-valent iron  

E-Print Network [OSTI]

such as pH (8, 9, and 10), ZVI pretreatment, and preparation method of the mixtures (GR[S]?? synthesized in the presence of ZVI; GR[S]?? and ZVI mixed after preparation). For all the experimental conditions evaluated, the activities of these reductants...

Marchal, Fabienne

2002-01-01T23:59:59.000Z

24

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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25

Mineral Precipitation Upgradient from a Zero-Valent Iron Permeable Reactive  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 Alabama - NaturalHanford Tank

26

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah,  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office of Audit Services AuditTransatlanticDirect-Cooled PowerDishwasher: 1; Human:

27

Zero Valent Iron: Impact of Anions Present during Synthesis on Subsequent  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste andAnniversary, part 2Zenoss, Version 2.1.3

28

Conversion of Steel Mill's Surface Waste into Zero Valent Iron (ZVI) Nanoparticles for Hydrogen Generation for PEMFCs  

E-Print Network [OSTI]

. The currently pursued modes of hydrogen generation include autothermal and/ or steam reforming of fossil fuels

Azad, Abdul-Majeed

29

Iron optimization for Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC) was accomplished through the addition of iron (Fe) and hydrogen peroxide (H{sub 2}O{sub 2}) (15.9 g/L; pH 3). The GAC used was URV, a bituminous-coal based carbon. The Fe concentration in GAC was incrementally varied (1020-25 660 mg/kg) by the addition of increasing concentrations of Fe solution (FeSO4{center_dot}7H{sub 2}O). MTBE degradation in Fe-amended GAC increased by an order of magnitude over Fe-unamended GAC and H{sub 2}O{sub 2} reaction was predominantly (99%) attributed to GAC-bound Fe within the porous structure of the GAC. Imaging and microanalysis of GAC particles indicated limited penetration of Fe into GAC. The optimal Fe concentration was 6710 mg/kg (1020 mg/kg background; 5690 mg/kg amended Fe) and resulted in the greatest MTBE removal and maximum Fe loading oxidation efficiency (MTBE oxidized (g)/Fe loaded to GAC(mg/Kg)). At lower Fe concentrations, the H{sub 2}O{sub 2} reaction was Fe limited. At higher Fe concentrations, the H{sub 2}O{sub 2} reaction was not entirely Fe limited, and reductions in GAC surface area, GAC pore volume, MTBE adsorption, and Fe loading oxidation efficiency were measured. Results are consistent with nonuniform distribution of Fe, pore blockage in H{sub 2}O{sub 2} transport, unavailable Fe, and limitations in H{sub 2}O{sub 2} diffusive transport, and emphasize the importance of optimal Fe loading. 22 refs., 6 figs., 2 tabs.

Scott G. Huling; Patrick K. Jones; Tony R. Lee [U.S. Environmental Protection Agency, Ada, OK (United States). Office of Research and Development, National Risk Management Research Laboratory

2007-06-01T23:59:59.000Z

30

Factors Affecting the Reactvity of Granular Iron in contact with Chlorinated Solvents  

E-Print Network [OSTI]

in column experiments: Connelly Iron (GI)(~3% C) and Electrolytic Iron (EI) (¡Ü 0.01% C). Kinetic data suggested a shift in rate constant (k) and sorption parameters for both iron types with time. This work demonstrated the implication of carbon during...

Firdous, Rubina

2013-12-31T23:59:59.000Z

31

Optimization of soil mixing technology through metallic iron addition.  

SciTech Connect (OSTI)

Enhanced soil mixing is a process used to remove volatile organic compounds (VOCs) from soil. In this process, also known as soil mixing with thermally enhanced soil vapor extraction, or SM/TESVE, a soil mixing apparatus breaks up and mixes a column of soil up to 9 m (30 ft) deep; simultaneously, hot air is blown through the soil. The hot air carries the VOCs to the surface where they are collected and safely disposed of. This technology is cost effective at high VOC concentrations, but it becomes cost prohibitive at low concentrations. Argonne National Laboratory-East conducted a project to evaluate ways of improving the effectiveness of this system. The project investigated the feasibility of integrating the SM/TESVE process with three soil treatment processes--soil vapor extraction, augmented indigenous biodegradation, and zero-valent iron addition. Each of these technologies was considered a polishing treatment designed to remove the contaminants left behind by enhanced soil mixing. The experiment was designed to determine if the overall VOC removal effectiveness and cost-effectiveness of the SM/TESVE process could be improved by integrating this approach with one of the polishing treatment systems.

Moos, L. P.

1999-01-15T23:59:59.000Z

32

Multiscale modeling in granular flow  

E-Print Network [OSTI]

Granular materials are common in everyday experience, but have long-resisted a complete theoretical description. Here, we consider the regime of slow, dense granular flow, for which there is no general model, representing ...

Rycroft, Christopher Harley

2007-01-01T23:59:59.000Z

33

Models of granular ratchets  

E-Print Network [OSTI]

We study a general model of granular Brownian ratchet consisting of an asymmetric object moving on a line and surrounded by a two-dimensional granular gas, which in turn is coupled to an external random driving force. We discuss the two resulting Boltzmann equations describing the gas and the object in the dilute limit and obtain a closed system for the first few moments of the system velocity distributions. Predictions for the net ratchet drift, the variance of its velocity fluctuations and the transition rates in the Markovian limit, are compared to numerical simulations and a fair agreement is observed.

G. Costantini; A. Puglisi; U. Marini Bettolo Marconi

2009-05-26T23:59:59.000Z

34

Field Projects: Monticello, Utah  

Broader source: Energy.gov [DOE]

A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM managed remediation of...

35

Field Projects: Cañon City, Colorado  

Broader source: Energy.gov [DOE]

In June 2000, Cotter Corporation installed a PRB at its uranium ore processing millsite in Cañon City, Colorado. The PRB contains zero-valent iron (ZVI) that treated molybdenum and uranium...

36

Capillary Fracturing in Granular Media  

E-Print Network [OSTI]

We study the displacement of immiscible fluids in deformable, noncohesive granular media. Experimentally, we inject air into a thin bed of water-saturated glass beads and observe the invasion morphology. The control ...

Holtzman, Ran

37

3D Imaging Of Wet Granular Matter  

E-Print Network [OSTI]

3D Imaging Of Wet Granular Matter Leonard Goff Advisor: Dr. Wolfgang Losert With Application to Penetrometer Insertion #12;3D Imaging Of Wet Granular Matter Leonard Goff, Advisor: Dr. Wolfgang Losert CoffeeSand Gravel Oops! #12;3D Imaging Of Wet Granular Matter Leonard Goff, Advisor: Dr. Wolfgang Losert

Anlage, Steven

38

HYPERELASTIC MODELS FOR GRANULAR MATERIALS  

SciTech Connect (OSTI)

A continuum framework for modeling of dust mobilization and transport, and the behavior of granular systems in general, has been reviewed, developed and evaluated for reactor design applications. The large quantities of micron-sized particles expected in the international fusion reactor design, ITER, will accumulate into piles and layers on surfaces, which are large relative to the individual particle size; thus, particle-particle, rather than particle-surface, interactions will determine the behavior of the material in bulk, and a continuum approach is necessary and justified in treating the phenomena of interest; e.g., particle resuspension and transport. The various constitutive relations that characterize these solid particle interactions in dense granular flows have been discussed previously, but prior to mobilization their behavior is not even fluid. Even in the absence of adhesive forces between particles, dust or sand piles can exist in static equilibrium under gravity and other forces, e.g., fluid shear. Their behavior is understood to be elastic, though not linear. The recent “granular elasticity” theory proposes a non-linear elastic model based on “Hertz contacts” between particles; the theory identifies the Coulomb yield condition as a requirement for thermodynamic stability, and has successfully reproduced experimental results for stress distributions in sand piles. The granular elasticity theory is developed and implemented in a stand- alone model and then implemented as part of a finite element model, ABAQUS, to determine the stress distributions in dust piles subjected to shear by a fluid flow. We identify yield with the onset of mobilization, and establish, for a given dust pile and flow geometry, the threshold pressure (force) conditions on the surface due to flow required to initiate it. While the granular elasticity theory applies strictly to cohesionless granular materials, attractive forces are clearly important in the interaction of micron-sized particles; extension of the theory to account for these effects is also considered. A set of continuum models are proposed for use in the future dust transport modeling.

Humrickhouse, Paul W; Corradini, Michael L

2009-01-29T23:59:59.000Z

39

Microscopic origin of granular ratcheting  

E-Print Network [OSTI]

Numerical simulations of assemblies of grains under cyclic loading exhibit ``granular ratcheting'': a small net deformation occurs with each cycle, leading to a linear accumulation of deformation with cycle number. We show that this is due to a curious property of the most frequently used models of the particle-particle interaction: namely, that the potential energy stored in contacts is path-dependent. There exist closed paths that change the stored energy, even if the particles remain in contact and do not slide. An alternative method for calculating the tangential force removes granular ratcheting.

S. McNamara; R. García-Rojo; H. J. Herrmann

2007-08-10T23:59:59.000Z

40

Hysteretic clustering in granular gas  

E-Print Network [OSTI]

Granular material is vibro-fluidized in N=2 and N=3 connected compartments, respectively. For sufficiently strong shaking the granular gas is equi-partitioned, but if the shaking intensity is lowered, the gas clusters in one compartment. The phase transition towards the clustered state is of 2nd order for N=2 and of 1st order for N=3. In particular, the latter is hysteretic. The experimental findings are accounted for within a dynamical model that exactly has the above properties.

Ko van der Weele; Devaraj van der Meer; Michel Versluis; Detlef Lohse

2001-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Shock wave propagation in vibrofluidized granular materials  

E-Print Network [OSTI]

Shock wave formation and propagation in two-dimensional granular materials under vertical vibration are studied by digital high speed photography. The steepen density and temperature wave fronts form near the plate as granular layer collides with vibrating plate and propagate upward through the layer. The temperature front is always in the transition region between the upward and downward granular flows. The effects of driving parameters and particle number on the shock are also explored.

Kai Huang; Guoqing Miao; Peng Zhang; Yi Yun; Rongjue Wei

2005-11-29T23:59:59.000Z

42

Why Granular Media Are, After All, Thermal  

E-Print Network [OSTI]

Granular media are considered "athermal", because the grains are too large to display Brownian type thermal fluctuations. Yet being macroscopic, every grain undergoes thermal expansion, possesses a temperature that may be measured with a thermometer, and consists of many, many internal degrees of freedom that in their sum do affect granular dynamics. Therefore, including them in a comprehensive approach to account for granular behavior entails crucial advantages. The pros and cons of thermal versus athermal descriptions are considered.

Yimin Jiang; Mario Liu

2014-07-27T23:59:59.000Z

43

Advanced hydraulic fracturing methods to create in situ reactive barriers  

SciTech Connect (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

44

Rheology of confined granular flows Patrick RICHARD  

E-Print Network [OSTI]

in the momentum balance if the second term on the right in this equation dominates over the first. This equation://www.aip..org/pacs/index.html> INTRODUCTION Surface flows of granular materials are frequently observed in industrial processes and in nature configurations. The first one is a rotating drum [3, 5, 4, 6], a cylinder, partly filled with granular material

Boyer, Edmond

45

A RESISTIVE FORCE MODEL FOR LEGGED LOCOMOTION ON GRANULAR MEDIA*  

E-Print Network [OSTI]

on granular surfaces like sand and gravel. Understanding the mechanics of legged locomotion on granular media and kinematics, e.g., a bio-inspired robot L-leg rotated through uniform granular media (loosely packed ~ 1 mm including insects, lizards, and mammals encounter granular surfaces like sand and gravel in their natural

Goodisman, Michael

46

Nonlinear Sound during Granular Impact  

E-Print Network [OSTI]

How do dynamic stresses propagate in granular material after a high-speed impact? This occurs often in natural and industrial processes. Stress propagation in a granular material is controlled by the inter-particle force law, $f$, in terms of particle deformation, $\\delta$, often given by $f\\propto\\delta^{\\alpha}$, with $\\alpha>1$. This means that a linear wave description is invalid when dynamic stresses are large compared to the original confining pressure. With high-speed video and photoelastic grains with varying stiffness, we experimentally study how forces propagate following an impact and explain the results in terms of the nonlinear force law (we measure $\\alpha\\approx 1.4$). The spatial structure of the forces and the propagation speed, $v_f$, depend on a dimensionless parameter, $M'=t_cv_0/d$, where $v_0$ is the intruder speed at impact, $d$ is the grain diameter, and $t_c$ is a binary collision time between grains with relative speed $v_0$. For $M'\\ll 1$, propagati ng forces are chain-like, and the measured $v_f \\propto d/t_c\\propto v_b(v_0/v_b)^\\frac{\\alpha-1}{\\alpha+1}$, where $v_b$ is the bulk sound speed. For larger $M'$, the force response has a 2D character, and forces propagate faster than predicted by $d/t_c$ due to collective stiffening of a packing.

Abram H. Clark; Alec J. Petersen; Lou Kondic; R. P. Behringer

2014-08-08T23:59:59.000Z

47

Chaoticity of the Wet Granular Gas  

E-Print Network [OSTI]

In this work we derive an analytic expression for the Kolmogorov-Sinai entropy of dilute wet granular matter, valid for any spatial dimension. The grains are modelled as hard spheres and the influence of the wetting liquid is described according to the Capillary Model, in which dissipation is due to the hysteretic cohesion force of capillary bridges. The Kolmogorov-Sinai entropy is expanded in a series with respect to density. We find a rapid increase of the leading term when liquid is added. This demonstrates the sensitivity of the granular dynamics to humidity, and shows that the liquid significantly increases the chaoticity of the granular gas.

A. Fingerle; S. Herminghaus; V. Yu. Zaburdaev

2007-05-22T23:59:59.000Z

48

A constitutive law for dense granular flows  

E-Print Network [OSTI]

A continuum description of granular flows would be of considerable help in predicting natural geophysical hazards or in designing industrial processes. However, the constitutive equations for dry granular flows, which govern how the material moves under shear, are still a matter of debate. One difficulty is that grains can behave like a solid (in a sand pile), a liquid (when poured from a silo) or a gas (when strongly agitated). For the two extreme regimes, constitutive equations have been proposed based on kinetic theory for collisional rapid flows, and soil mechanics for slow plastic flows. However, the intermediate dense regime, where the granular material flows like a liquid, still lacks a unified view and has motivated many studies over the past decade. The main characteristics of granular liquids are: a yield criterion (a critical shear stress below which flow is not possible) and a complex dependence on shear rate when flowing. In this sense, granular matter shares similarities with classical visco-plastic fluids such as Bingham fluids. Here we propose a new constitutive relation for dense granular flows, inspired by this analogy and recent numerical and experimental work. We then test our three-dimensional (3D) model through experiments on granular flows on a pile between rough sidewalls, in which a complex 3D flow pattern develops. We show that, without any fitting parameter, the model gives quantitative predictions for the flow shape and velocity profiles. Our results support the idea that a simple visco-plastic approach can quantitatively capture granular flow properties, and could serve as a basic tool for modelling more complex flows in geophysical or industrial applications.

Pierre Jop; Yoël Forterre; Olivier Pouliquen

2006-12-05T23:59:59.000Z

49

A taxonomy of granular partitions Thomas Bittner and Barry Smith  

E-Print Network [OSTI]

A taxonomy of granular partitions Thomas Bittner and Barry Smith Qualitative Reasoning Group. In Smith and Brogaard (2000) the notion of granular partition was introduced as a generalization of David

Forbus, Kenneth D.

50

Achieving progressive fine granularity scalable coding in H.26L  

E-Print Network [OSTI]

Fine granularity scalable (FGS) coding and progressive fine granularity scalable (PFGS) coding are novel scalable video schemes which are ideally suited for streaming multimedia over networks with varying bandwidth, network conditions and receiver...

Shanmugampillai, Muthukumar

2001-01-01T23:59:59.000Z

51

Stochastic and deterministic models for dense granular flow  

E-Print Network [OSTI]

Granular materials such as sand or gravel surround us everyday and yet remain poorly understood. In this thesis, two models are developed for dense granular flow, each capable of predicting flows with accuracy in multiple ...

Kamrin, Kenneth Norman

2008-01-01T23:59:59.000Z

52

Friction and dilatancy in immersed granular matter  

E-Print Network [OSTI]

The friction of a sliding plate on a thin immersed granular layer obeys Amonton-Coulomb law. We bring to the fore a large set of experimental results which indicate that, over a few decades of values, the effective dynamical friction-coefficient depends neither on the viscosity of the interstitial fluid nor on the size of beads in the sheared layer, which bears out the analogy with the solid-solid friction in a wide range of experimental parameters. We accurately determine the granular-layer dilatancy, which dependance on the grain size and slider velocity can be qualitatively accounted by considering the rheological behaviour of the whole slurry. However, additional results, obtained after modification of the grain surface by a chemical treatment, demonstrate that the theoretical description of the flow properties of granular matter, even immersed, requires the detailed properties of the grain surface to be taken into account.

Thibaut Divoux; Jean-Christophe Géminard

2008-06-10T23:59:59.000Z

53

Comparison of Hyperelastic Models for Granular Materials  

SciTech Connect (OSTI)

Three recently proposed hyperelastic models for granular materials are compared with experiment data. Though all three are formulated to give elastic moduli that are power law functions of the mean stress, they have rather different dependencies on individual stresses, and generally differ from well established experimental forms. Predicted static stress distributions are in qualitative agreement with experiments, but do not differ greatly from isotropic linear elasticity, and similarly fail to account for variability in experiment data that presumably occurs due to a preparation dependence of granular materials.

Paul W. Humrickhouse; J. Phil Sharpe; Michael L. Corradini

2010-01-01T23:59:59.000Z

54

Trajectory entanglement in dense granular materials  

E-Print Network [OSTI]

The particle-scale dynamics of granular materials have commonly been characterized by the self-diffusion coefficient $D$. However, this measure discards the collective and topological information known to be an important characteristic of particle trajectories in dense systems. Direct measurement of the entanglement of particle space-time trajectories can be obtained via the topological braid entropy $\\Sbraid$, which has previously been used to quantify mixing efficiency in fluid systems. Here, we investigate the utility of $\\Sbraid$ in characterizing the dynamics of a dense, driven granular material at packing densities near the static jamming point $\\phi_J$. From particle trajectories measured within a two-dimensional granular material, we typically observe that $\\Sbraid$ is well-defined and extensive. However, for systems where $\\phi \\gtrsim 0.79$, we find that $\\Sbraid$ (like $D$) is not well-defined, signifying that these systems are not ergodic on the experimental timescale. Both $\\Sbraid$ and $D$ decrease with either increasing packing density or confining pressure, independent of the applied boundary condition. The related braiding factor provides a means to identify multi-particle phenomena such as collective rearrangements. We discuss possible uses for this measure in characterizing granular systems.

James G. Puckett; Frédéric Lechenault; Karen E. Daniels; Jean-Luc Thiffeault

2012-02-23T23:59:59.000Z

55

Iron and Prochlorococcus/  

E-Print Network [OSTI]

Iron availability and primary productivity in the oceans are intricately linked through photosynthesis. At the global scale we understand how iron addition induces phytoplankton blooms through meso-scale iron-addition ...

Thompson, Anne Williford

2009-01-01T23:59:59.000Z

56

Investigating Iron Ions | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigating Iron Ions Investigating Iron Ions Computer code provides detailed predictions of highly charged ions in water Using resources at EMSL, scientists obtained...

57

Erosion dynamics of a wet granular medium  

E-Print Network [OSTI]

Liquid may give strong cohesion properties to a granular medium, and confer a solid-like behavior. We study the erosion of a fixed circular aggregate of wet granular matter subjected to a flow of dry grains inside a half-filled rotating drum. During the rotation, the dry grains flow around the fixed obstacle. We show that its diameter decreases linearly with time for low liquid content, as wet grains are pulled-out of the aggregate. This erosion phenomenon is governed by the properties of the liquids. The erosion rate decreases exponentially with the surface tension while it depends on the viscosity to the power -1. We propose a model based on the force fluctuations arising inside the flow, explaining both dependencies: the capillary force acts as a threshold and the viscosity controls the erosion time scale. We also provide experiments using different flowing grains confirming our model.

Gautier Lefebvre; Pierre Jop

2014-12-08T23:59:59.000Z

58

New boundary conditions for granular fluids  

E-Print Network [OSTI]

We present experimental evidence, which contradicts the the standard boundary conditions used in continuum theories of non-cohesive granular flows for the velocity normal to a boundary u.n=0, where n points into the fluid. We propose and experimentally verify a new boundary condition for u.n, based on the observation that the boundary cannot exert a tension force Fb on the fluid. The new boundary condition is u.n=0 if Fb.n>=0 else n.P.n=0, where P is the pressure tensor. This is the analog of cavitation in ordinary fluids, but due the lack of attractive forces and dissipation it occurs frequently in granular flows.

Mark D. Shattuck

2007-03-22T23:59:59.000Z

59

Brownian motor in a granular medium  

E-Print Network [OSTI]

In this work we experimentally study the behavior of a freely-rotating asymmetric probe immersed in a vibrated granular medium. For a wide variety of vibration conditions the probe exhibits a steady rotation whose direction is constant with respect to the asymmetry. By changing the vibration amplitude and by filtering the noise in different frequency bands we show that the velocity of rotation does not depend only on the RMS acceleration $\\Gamma$, but also on the amount of energy provided to two separate frequency bands which are revealed to be important for the dynamics of the granular medium: the first band governs the transfer of energy from the grains to the probe, and the second affects the dynamics by altering the viscosity of the vibro-fluidized material.

Riccardo Balzan; Fergal Dalton; Vittorio Loreto; Alberto Petri; Giorgio Pontuale

2009-09-21T23:59:59.000Z

60

Sudden Collapse of a Granular Cluster  

E-Print Network [OSTI]

Single clusters in a vibro-fluidized granular gas in N connected compartments become unstable at strong shaking. They are experimentally shown to collapse very abruptly. The observed cluster lifetime (as a function of the driving intensity) is analytically calculated within a flux model, making use of the self-similarity of the process. After collapse, the cluster diffuses out into the uniform distribution in a self-similar way, with an anomalous diffusion exponent 1/3.

Devaraj van der Meer; Ko van der Weele; Detlef Lohse

2002-04-12T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Refraction of shear zones in granular materials  

E-Print Network [OSTI]

We study strain localization in slow shear flow focusing on layered granular materials. A heretofore unknown effect is presented here. We show that shear zones are refracted at material interfaces in analogy with refraction of light beams in optics. This phenomenon can be obtained as a consequence of a recent variational model of shear zones. The predictions of the model are tested and confirmed by 3D discrete element simulations. We found that shear zones follow Snell's law of light refraction.

Tamas Unger

2007-01-08T23:59:59.000Z

62

Nonlinear elasto-plastic model for dense granular flow  

E-Print Network [OSTI]

This work proposes a model for granular deformation that predicts the stress and velocity profiles in well-developed dense granular flows. Recent models for granular elasticity (Jiang and Liu 2003) and rate-sensitive plastic flow (Jop et al. 2006) are reformulated and combined into one universal granular continuum law, capable of predicting flowing regions and stagnant zones simultaneously in any arbitrary 3D flow geometry. The unification is performed by justifying and implementing a Kroner-Lee elasto-plastic decomposition, with care taken to ensure certain continuum physical principles are necessarily upheld. The model is then numerically implemented in multiple geometries and results are compared to experiments and discrete simulations.

Ken Kamrin

2009-05-07T23:59:59.000Z

63

Formation of aerobic granular sludge biofilms for sustainable wastewater treatment  

E-Print Network [OSTI]

ENAC/ Formation of aerobic granular sludge biofilms for sustainable wastewater treatment David G Research, Microbiology of Interfaces, Magdeburg (Germany) EDCE 2011 / From activated sludge flocs

64

Environmental Aspects of Two Volatile Organic Compound Groundwater Treatment Designs at the Rocky Flats Site - 13135  

SciTech Connect (OSTI)

DOE's Rocky Flats Site in Colorado is a former nuclear weapons production facility that began operations in the early 1950's. Because of releases of hazardous substances to the environment, the federally owned property and adjacent offsite areas were placed on the CERCLA National Priorities List in 1989. The final remedy was selected in 2006. Engineered components of the remedy include four groundwater treatment systems that were installed before closure as CERCLA-accelerated actions. Two of the systems, the Mound Site Plume Treatment System and the East Trenches Plume Treatment System, remove low levels of volatile organic compounds using zero-valent iron media, thereby reducing the loading of volatile organic compounds in surface water resulting from the groundwater pathway. However, the zero-valent iron treatment does not reliably reduce all volatile organic compounds to consistently meet water quality goals. While adding additional zero-valent iron media capacity could improve volatile organic compound removal capability, installation of a solar powered air-stripper has proven an effective treatment optimization in further reducing volatile organic compound concentrations. A comparison of the air stripper to the alternative of adding additional zero-valent iron capacity to improve Mound Site Plume Treatment System and East Trenches Plume Treatment System treatment based on several key sustainable remediation aspects indicates the air stripper is also more 'environmentally friendly'. These key aspects include air pollutant emissions, water quality, waste management, transportation, and costs. (authors)

Michalski, Casey C.; DiSalvo, Rick; Boylan, John [Stoller LMS Team, 11025 Dover Street, Suite 1000, Westminster, CO 80021 (United States)] [Stoller LMS Team, 11025 Dover Street, Suite 1000, Westminster, CO 80021 (United States)

2013-07-01T23:59:59.000Z

65

Acetylene Inhibition of Trichloroethene and Vinyl Chloride  

E-Print Network [OSTI]

and enhanced anaerobic remediation of chloroethenes at contaminated sites. The results also suggest that acetylene produced abiotically by reactions of chlorinated ethenes with zero-valent iron could inhibit water standard (2 µg/L) (3). A variety of biochemical tools have been used to probe the complexity

Semprini, Lewis

66

Bioremediation of Uranium Plumes with Nano-scale  

E-Print Network [OSTI]

(IV) (UO2[s], uraninite) Anthropogenic · Release of mill tailings during uranium mining - MobilizationBioremediation of Uranium Plumes with Nano-scale Zero-valent Iron Angela Athey Advisers: Dr. Reyes Undergraduate Student Fellowship Program April 15, 2011 #12;Main Sources of Uranium Natural · Leaching from

Fay, Noah

67

Technical Assistance to Ohio Closure Sites Technologies to Address Excavated VOC Contaminated Soil  

E-Print Network [OSTI]

and available solar heat. This report focuses on design features and recommendations for implementing disposal, passive soil venting, enhanced soil venting, zero-valent iron, anaerobic bioremediation, aerobic and functional design requirements (equipment, flow rates, options, issues, cautions, etc.).The design

Hazen, Terry

68

Dispersion enhanced metal/zeolite catalysts  

DOE Patents [OSTI]

Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

Sachtler, W.M.H.; Tzou, M.S.; Jiang, H.J.

1987-03-31T23:59:59.000Z

69

A MODEL FOR GRANULAR STATICS WITH IMPENETRABILITY CONSTRAINTS  

E-Print Network [OSTI]

of frictionless granular packings. The packing is deformed by imposing boundary conditions, modeling those in shear and compression experiments. In our two-dimensional model, the packing is represented by a spring of granular materials. Examples of such ma- terials are common, including sand, gravel, medicinal pills, coins

Panchenko, Alexander

70

INTRODUCTION The granular mechanics of plastics within a single-  

E-Print Network [OSTI]

INTRODUCTION The granular mechanics of plastics within a single- screw extruder has, for the past are transported forward by the action of the extruder screw, assisted by the differ- ence in frictional forces and feed hopper of a single-screw extruder. The method considers each particle in a granular assem- bly

Thompson, Michael

71

High-Frequency Resistivity of Soft Magnetic Granular Films  

E-Print Network [OSTI]

permeability was measured and used to predict the power loss expected when granular films are used as high-frequency core materials for film inductors. The power loss is predicted to be lower than that of commercial Ni permeability, power loss, soft magnetic film. I. INTRODUCTION SOFT magnetic granular films are considered ideal

72

Size separation in vibrated granular matter  

E-Print Network [OSTI]

We review recent developments in size separation in vibrated granular materials. Motivated by a need in industry to efficiently handle granular materials and a desire to make fundamental advances in non-equilibrium physics, experimental and theoretical investigations have shown size separation to be a complex phenomena. Large particles in a vibrated granular system invariably rise to the top. However, they may also sink to the bottom, or show other patterns depending on subtle variations in physical conditions. While size ratio is a dominant factor, particle specific properties such as density, inelasticity and friction can play an important role. The nature of the energy input, boundary conditions and interstitial air have been also shown to be significant factors in determining spatial distributions. The presence of convection can enhance mixing or lead to size separation. Experimental techniques including direct visualization and magnetic resonance imaging are being used to investigate these properties. Molecular dynamics and Monte Carlo simulation techniques have been developed to probe size separation. Analytical methods such as kinetic theory are being used to study the interplay between particle size and density in the vibro-fluidized regime, and geometric models have been proposed to describe size separation for deep beds. Besides discussing these studies, we will also review the impact of inelastic collision and friction on the density and velocity distributions to gain a deeper appreciation of the non-equilibrium nature of the system. While a substantial number of studies have been accomplished, considerable work is still required to achieve a firm description of the phenomena.

A. Kudrolli

2004-02-06T23:59:59.000Z

73

Using NMR to Validate First-Principles Granular Flow Equations  

E-Print Network [OSTI]

Nuclear magnetic resonance (NMR) experiments are described for two granular-flow systems, the vibrofluidized bed and the gas-fluidized bed. Using pulsed field gradient, magnetic resonance imaging, and hyperpolarized gas NMR, detailed information is obtained for the density and motions of both grains and interstitial gas. For the vibrofluidized bed, the granular temperature profile is measured and compared with a first-principles formulation of granular hydrodynamics. For the gas-fluidized bed, dynamic correlations in the grain density are used to measure the bubble velocity and hyperpolarized xenon gas NMR is used to measure the bubble-emulsion exchange rate. A goal of these measurements is to verify in earth gravity first-principles theories of granular flows, which then can be used to make concrete predictions for granular flows in reduced gravity.

D. Candela; C. Huan; K. Facto; R. Wang; R. W. Mair; R. L. Walsworth

2005-10-23T23:59:59.000Z

74

DEM simulation of experimental dense granular packing  

SciTech Connect (OSTI)

In this study we present numerical analysis performed on the experimental results of sphere packings of mono-sized hard sphere whose packing fraction spans across a wide range of 0.59<{Phi}<0.72. Using X-ray Computed Tomography (XCT), we have full access to the 3D structure of the granular packings. Numerical analysis performed on thr data provides the first experimental proofs of how densification affects local order parameters. Furthermore by combining Discrete Element Method (DEM) and the experimental results from XCT, we investigate how the intergranular forces change with the onset of crystallization.

Hanifpour, Maryam; Allaei, Mehdi Vaez [Department of Physics, University of Tehran, Tehran (Iran, Islamic Republic of); Francois, Nicolas; Saadatfar, Mohammad [Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra (Australia)

2013-06-18T23:59:59.000Z

75

Granular Matter 4(3) (2002) How good is the equipartition assumption for the transport  

E-Print Network [OSTI]

Granular Matter 4(3) (2002) How good is the equipartition assumption for the transport properties of a granular mixture? Meheboob Alam (1) , Stefan Luding (1;2) ? Abstract Kinetic-theory, with the assumption of equipar- tition of granular energy, suggests that the pressure and viscosity of a granular mixture vary

Luding, Stefan

76

Pressure-shear experiments on granular materials.  

SciTech Connect (OSTI)

Pressure-shear experiments were performed on granular tungsten carbide and sand using a newly-refurbished slotted barrel gun. The sample is a thin layer of the granular material sandwiched between driver and anvil plates that remain elastic. Because of the obliquity, impact generates both a longitudinal wave, which compresses the sample, and a shear wave that probes the strength of the sample. Laser velocity interferometry is employed to measure the velocity history of the free surface of the anvil. Since the driver and anvil remain elastic, analysis of the results is, in principal, straightforward. Experiments were performed at pressures up to nearly 2 GPa using titanium plates and at higher pressure using zirconium plates. Those done with the titanium plates produced values of shear stress of 0.1-0.2 GPa, with the value increasing with pressure. On the other hand, those experiments conducted with zirconia anvils display results that may be related to slipping at an interface and shear stresses mostly at 0.1 GPa or less. Recovered samples display much greater particle fracture than is observed in planar loading, suggesting that shearing is a very effective mechanism for comminution of the grains.

Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Thornhill, Tom Finley, III (, Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Alexander, C. Scott (Sandia National Laboratories, Albuquerque, NM)

2011-10-01T23:59:59.000Z

77

Imaging of granular sources in high energy heavy ion collisions  

E-Print Network [OSTI]

We investigate the source imaging for a granular pion-emitting source model in high energy heavy ion collisions. The two-pion source functions of the granular sources exhibit a two-tiered structure. Using a parametrized formula of granular two-pion source function, we examine the two-tiered structure of the source functions for the imaging data of Au+Au collisions at Alternating Gradient Synchrotron (AGS) and Relativistic Heavy Ion Collider (RHIC). We find that the imaging technique introduced by Brown and Danielewicz is suitable for probing the granular structure of the sources. Our data-fitting results indicate that there is not visible granularity for the sources at AGS energies. However, the data for the RHIC collisions with the selections of $40 < {\\rm centrality} < 90%$ and $0.20granular emission than that of one Gaussian. The model with granular source has more parameters than the simple Gaussian, hence can describe more complicated shapes.

Zhi-Tao Yang; Wei-Ning Zhang; Lei Huo; Jing-Bo Zhang

2008-08-18T23:59:59.000Z

78

Software digitizer for high granular gaseous detector  

E-Print Network [OSTI]

A sampling calorimeter using gaseous sensor layers with digital readout [1] is near perfect for ``Particle Flow Algorithm'' [2,3] approach, since it is homogeneous over large surfaces, robust, cost efficient, easily segmentable to any readout pad dimension and size and almost insensitive to neutrons. Monte-Carlo (MC) programs such as GEANT4 [4] simulate with high precision the energy deposited by particles. The sensor and electronic response associated to a pad are calculated in a separate ``digitization'' process. We develop a general method for simulating the pad response using the spatial information from a simulation done at high granularity. The digitization method proposed here has been applied to gaseous detectors including Glass Resistive Plate Chambers (GRPC) and MicroMegas, and validated on test beam data. Experimental observable such as pad multiplicity and mean number of hits at different thresholds have been reproduced with high precision.

Haddad, Y; Boudry, V

2015-01-01T23:59:59.000Z

79

Frictional granular mechanics: A variational approach  

SciTech Connect (OSTI)

The mechanical properties of a cohesionless granular material are evaluated from grain-scale simulations. Intergranular interactions, including friction and sliding, are modeled by a set of contact rules based on the theories of Hertz, Mindlin, and Deresiewicz. A computer generated, three-dimensional, irregular pack of spherical grains is loaded by incremental displacement of its boundaries. Deformation is described by a sequence of static equilibrium configurations of the pack. A variational approach is employed to find the equilibrium configurations by minimizing the total work against the intergranular loads. Effective elastic moduli are evaluated from the intergranular forces and the deformation of the pack. Good agreement between the computed and measured moduli, achieved with no adjustment of material parameters, establishes the physical soundness of the proposed model.

Holtzman, R.; Silin, D.B.; Patzek, T.W.

2009-10-16T23:59:59.000Z

80

Bifurcation Diagram for Compartmentalized Granular Gases  

E-Print Network [OSTI]

The bifurcation diagram for a vibro-fluidized granular gas in N connected compartments is constructed and discussed. At vigorous driving, the uniform distribution (in which the gas is equi-partitioned over the compartments) is stable. But when the driving intensity is decreased this uniform distribution becomes unstable and gives way to a clustered state. For the simplest case, N=2, this transition takes place via a pitchfork bifurcation but for all N>2 the transition involves saddle-node bifurcations. The associated hysteresis becomes more and more pronounced for growing N. In the bifurcation diagram, apart from the uniform and the one-peaked distributions, also a number of multi-peaked solutions occur. These are transient states. Their physical relevance is discussed in the context of a stability analysis.

Devaraj van der Meer; Ko van der Weele; Detlef Lohse

2001-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Dynamics of Gas-Fluidized Granular Rods  

E-Print Network [OSTI]

We study a quasi-two-dimensional monolayer of granular rods fluidized by a spatially and temporally homogeneous upflow of air. By tracking the position and orientation of the particles, we characterize the dynamics of the system with sufficient resolution to observe ballistic motion at the shortest time scales. Particle anisotropy gives rise to dynamical anisotropy and superdiffusive dynamics parallel to the rod's long axis, causing the parallel and perpendicular mean squared displacements to become diffusive on different timescales. The distributions of free times and free paths between collisions deviate from exponential behavior, underscoring the non-thermal character of the particle motion. The dynamics show evidence of rotational-translational coupling similar to that of an anisotropic Brownian particle. We model rotational-translation coupling in the single-particle dynamics with a modified Langevin model using non-thermal noise sources. This suggests a phenomenological approach to thinking about collections of self-propelling particles in terms of enhanced memory effects.

L. J. Daniels; Y. Park; T. C. Lubensky; D. J. Durian

2008-11-17T23:59:59.000Z

82

Moving Granular Bed Filter Development Program  

SciTech Connect (OSTI)

For coal-fired power plants utilizing a gas turbine, the removal of ash particles is necessary to protect the turbine and to meet emission standards. Advantages are also evident for a filter system that can remove other coal-derived contaminants such as alkali, halogens, and ammonia. With most particulates and other contaminants removed, erosion and corrosion of turbine materials, as well as deposition of particles within the turbine, are reduced to acceptable levels. The granular bed filter is suitable for this task in a pressurized gasification or combustion environment. The objective of the base contract was to develop conceptual designs of moving granular bed filter (GBF) and ceramic candle filter technologies for control of particles from integrated gasification combined cycle (IGCC), pressurized fluidized-bed combustion (PFBC), and direct coal-fueled turbine (DCFT) systems. The results of this study showed that the GBF design compared favorably with the candle filter. Three program options followed the base contract. The objective of Option I, Component Testing, was to identify and resolve technical issues regarding GBF development for IGCC and PFBC environments. This program was recently completed. The objective of Option II, Filter Proof Tests, is to test and evaluate the moving GBF system at a government-furnished hot-gas cleanup test facility. This facility is located at Southern Company Services (SCS), Inc., Wilsonville, Alabama. The objective of Option III, Multicontaminant Control Using a GBF, is to develop a chemically reactive filter material that will remove particulates plus one or more of the following coal-derived contaminants: alkali, halogens, and ammonia.

Wilson, K.B.; Haas, J.C. [Combustion Power Co., San Mateo, CA (United States); Gupta, R.P.; Turk, B.S. [Research Triangle Inst., Research Triangle Park, NC (United States)

1996-12-31T23:59:59.000Z

83

Inert plug formation in the DDT of granular energetic materials  

SciTech Connect (OSTI)

A mechanism is proposed to explain the {open_quotes}plugs{close_quotes} that have been observed in deflagration-to-detonation transition (DDT) of granular explosives. Numerical simulations are performed that demonstrate the proposed mechanism. Observed trends are reproduced.

Son, S.F.; Asay, B.W.; Bdzil, J.B.

1995-09-01T23:59:59.000Z

84

Resilient modulus and permanent deformation testing of unbound granular materials  

E-Print Network [OSTI]

Numerous research efforts have been devoted to characterizing the behavior of granular materials, which is one of the main concerns of pavement engineers. For better understanding of this behavior, laboratory tests where in-situ stress conditions...

Kancherla, Anuroopa

2005-11-01T23:59:59.000Z

85

A Theory of Granular Partitions Thomas Bittner and Barry Smith  

E-Print Network [OSTI]

CHAPTER 7 A Theory of Granular Partitions Thomas Bittner and Barry Smith Institute for Formal of part and whole relations (Smith, 1998) as a framework for ontological theorizing. Mereology is better

Bittner, Thomas

86

SHEAR DEFORMATION IN GRANULAR MATERIAL S. G. Bardenhagen  

E-Print Network [OSTI]

of New Mexico Albuquerque, NM 87131 An investigation into the properties of granular materials of the binder as a lubricant in force chains. INTRODUCTION We report the results of an investigation

Sulsky, Deborah L.

87

Particle Scale Dynamics in Granular Impact Abram H. Clark,1  

E-Print Network [OSTI]

experiments, v ( C, where C ' 300 m=s is the granular sound speed, measured from photoelastic space-time plots are cut from PS-1 material (Vishay Precision Group; bulk density of 1:28 g=cm3, elastic modulus of 2.5 GPa of granular impact, where intruders strike 2D beds of photoelastic disks from above. High-speed video captures

Kondic, Lou

88

A lattice gas model of avalanches in a granular pile  

E-Print Network [OSTI]

A granular media lattice gas (GMLG) model is used to study avalanches in a two-dimensional granular pile. We demonstrate the efficiency of the algorithm by showing that several features of the non-critical behaviour of real sandpile surfaces, such as the bounded outflow statistics or the finite-size effect of the time evolution of the pile mass, can be reproduced by this simulation approach.

Antal Karolyi; Janos Kertesz

1997-10-31T23:59:59.000Z

89

Deflagration to detonation experiments in granular HMX  

SciTech Connect (OSTI)

In this paper the authors report on continuing work involving a series of deflagration-to-detonation transition (DDT) experiments in which they study the piston-initiated DDT of heavily confined granular cyclotetramethylenetetranitramine (HMX). These experiments were designed to he useful in model development and evaluation. A main focus of these experiments is the effect of density on the DDT event. Particle size distribution and morphology are carefully characterized. In this paper they present recent surface area analysis. Earlier studies demonstrated extensive fracturing and agglomeration in samples at densities as low as 75% TMD as evidenced by dramatic decreases in particle size distribution due to mild stimulus. This is qualitatively confirmed with SEM images and quantitatively studied with gas absorption surface area analysis. Also, in this paper they present initial results using a microwave interferometer technique. Dynamic calibration of the technique was performed, a 35 GHz signal is used to increase resolution, and the system has been designed to be inexpensive for repeated experiments. The distance to where deformation of the inner wall begins for various densities is reported. This result is compared with the microwave interferometer measurements.

Burnside, N.J.; Son, S.F.; Asay, B.W.; Dickson, P.M.

1998-03-01T23:59:59.000Z

90

Software digitizer for high granular gaseous detector  

E-Print Network [OSTI]

A sampling calorimeter equipped with gaseous sensor layers with digital readout is near perfect for "Particle Flow Algorithm" approach, since it is homogeneous over large surfaces, robust, cost efficient, easily segmentable to any readout pad dimension and size and almost insensitive to neutrons. The response of a finely segmented digital calorimeter is characterized by track efficiency and multiplicity. Monte Carlo (MC) programs such as GEANT4 simulate with high precision the energy deposited by particles. The sensor and electronic response associated to a pad are calculated in a separate "digitization" process. We developed a general method for simulating the pad response, a digitization, reproducing efficiency and multiplicity, using the spatial information from a simulation done at higher granularity. The digitization method proposed here has been applied to gaseous detectors including Glass Resistive Plate Chambers (GRPC) and MicroMegas. Validating the method on test beam data, experimental observables such as efficiency, multiplicity and mean number of hits at different thresholds have been reproduced with high precision.

Y. Haddad; M. Ruan; V. Boudry

2014-05-06T23:59:59.000Z

91

Accelerated drop detachment in granular suspensions  

E-Print Network [OSTI]

We experimentally study the detachment of drops of granular suspensions using a density matched model suspension with varying volume fraction ({\\phi} = 15% to 55%) and grain diameter (d = 20 {\\mu}m to 140 {\\mu}m). We show that at the beginning of the detachment process, the suspensions behave as an effective fluid. The detachment dynamics in this regime can be entirely described by the shear viscosity of the suspension. At later stages of the detachment the dynamics become independent of the volume fraction and are found to be identical to the dynamics of the interstitial fluid. Surprisingly, visual observation reveals that at this stage particles are still present in the neck. We suspect rearrangements of particles to locally free the neck of grains, causing the observed dynamics. Close to the final pinch off, the detachment of the suspensions is further accelerated, compared to the dynamics of pure interstitial fluid. This acceleration might be due to the fact that the neck diameter gets of the order of magnitude of the size of the grains and a continuous thinning of the liquid thread is not possible any more. The crossover between the different detachment regimes is function of the grain size and the initial volume fraction. We characterize the overall acceleration as a function of the grain size and volume fraction.

Claire Bonnoit; Thibault Bertrand; Éric Clément; Anke Lindner

2010-09-09T23:59:59.000Z

92

Softening of Granular Packings with Dynamic Forcing  

E-Print Network [OSTI]

We perform numerical simulations of a two-dimensional bidisperse granular packing subjected to both a static confining pressure and a sinusoidal dynamic forcing applied by a wall on one edge of the packing. We measure the response experienced by a wall on the opposite edge of the packing and obtain the resonant frequency of the packing as the static or dynamic pressures are varied. Under increasing static pressure, the resonant frequency increases, indicating a velocity increase of elastic waves propagating through the packing. In contrast, when the dynamic amplitude is increased for fixed static pressure, the resonant frequency decreases, indicating a decrease in the wave velocity. This occurs both for compressional and for shear dynamic forcing, and is in agreement with experimental results. We find that the average contact number $Z_c$ at the resonant frequency decreases with increasing dynamic amplitude, indicating that the elastic softening of the packing is associated with a reduced number of grain-grain contacts through which the elastic waves can travel. We image the excitations created in the packing and show that there are localized disturbances or soft spots that become more prevalent with increasing dynamic amplitude. Our results are in agreement with experiments on glass bead packings and earth materials such as sandstone and granite, and may be relevant to the decrease in elastic wave velocities that has been observed to occur near fault zones after strong earthquakes, in surficial sediments during strong ground motion, and in structures during earthquake excitation.

C. J. Olson Reichhardt; L. M. Lopatina; X. Jia; P. A. Johnson

2014-06-17T23:59:59.000Z

93

Quasi-static mechanics of granular materials  

E-Print Network [OSTI]

This textbook in French describes the rheology of granular materials in the quasi static regime at a macroscopic scale. It starts defining cohesion, friction and the Coulomb approach, from the large-strain range. Then it focuses on the range of small and intermediate deformation when the medium can dilate if it is dense; different specific typical tests (oedometric, constant pressure, constant volume) are defined, the behaviours they lead are carefully described and their dependences upon initial density recalled. Roles of friction and dilatancy are exemplified and their link with the deviatoric stress too. "Natural" "phase space" is defined, which is (specific volume, mean pressure, axial or deviatoric stress). Then the "critical" state, the "characteristic" state and the Rowe's law of dilatancy are defined, and the previous behaviours analysed in term of plastic deformation, showing that these behaviours obey a specific rule of dissipation. An isotropic incremental modelling is then proposed and studied, with a pseudo Poisson coefficient that evolves with the stress ratio. It shows a good agreement with experimental trends, while the theory keeps simple, which describes in particular the isochoric compression and the oedometric compression correctly. Cyclic behaviours are then described, and their link with soil liquefaction, with a peculiar attention to the role of stress ratio. Basic concepts on micro-macro passage are given, starting with a theoretical approach leading to an exponential distribution of forces ; then it proposes a theory for the compaction of the medium with pressure, that predicts the v-log(p) law for the critical state.

P. Evesque

2005-07-13T23:59:59.000Z

94

Standleg Moving Granular Bed Filter development program  

SciTech Connect (OSTI)

The design, fabrication, and installation of the cold flow test facility has been completed. The SMGBF test facility shown in Figure 2 consists of a solids feed hopper, a transparent test vessel, a screw conveyor, a 55-gal drum for solids storage, a dust feeder, a baghouse filter, and the associated instrumentation for flow and pressure control and measurement. The standleg is 11-in ID by 3-ft long, and also transparent to facilitate observation. The crushed acrylic particles of characteristics shown in Table 1 are used as the bed media. The bed particles were selected, by maintaining the particle size while reducing the particle density, to simulate the minimum fluidization velocity expected under high-temperature, high-pressure conditions. By maintaining the particle size, the bed effectively simulates the bed packing and voidage in the moving bed which is directly related to the efficiency of particulate removal and pressure drop characteristics. The test facility performed as designed and no particular difficulties were encountered. The baseline data on pressure profiles across the stationary and the moving granular beds were obtained for gas face velocities up to 6 ft/s, higher than the minimum fluidization velocity of the bed material (5 ft/s), and no visible fluidization was observed at the base of the standleg. This confirms the operational feasibility of the compact SMGBF design.

Newby, R.A.; Yang, W.C.; Smeltzer, E.E.

1992-11-01T23:59:59.000Z

95

Standleg Moving Granular Bed Filter development program  

SciTech Connect (OSTI)

The design, fabrication, and installation of the cold flow test facility has been completed. The SMGBF test facility shown in Figure 2 consists of a solids feed hopper, a transparent test vessel, a screw conveyor, a 55-gal drum for solids storage, a dust feeder, a baghouse filter, and the associated instrumentation for flow and pressure control and measurement. The standleg is 11-in ID by 3-ft long, and also transparent to facilitate observation. The crushed acrylic particles of characteristics shown in Table 1 are used as the bed media. The bed particles were selected, by maintaining the particle size while reducing the particle density, to simulate the minimum fluidization velocity expected under high-temperature, high-pressure conditions. By maintaining the particle size, the bed effectively simulates the bed packing and voidage in the moving bed which is directly related to the efficiency of particulate removal and pressure drop characteristics. The test facility performed as designed and no particular difficulties were encountered. The baseline data on pressure profiles across the stationary and the moving granular beds were obtained for gas face velocities up to 6 ft/s, higher than the minimum fluidization velocity of the bed material (5 ft/s), and no visible fluidization was observed at the base of the standleg. This confirms the operational feasibility of the compact SMGBF design.

Newby, R.A.; Yang, W.C.; Smeltzer, E.E.

1992-01-01T23:59:59.000Z

96

Grow Iron, Slow Pollution | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Grow Iron, Slow Pollution Grow Iron, Slow Pollution Scientists connect previous studies on electron transport in hematite Making a Deposit: Scanning electron micrographs of...

97

Continuous shearing of dense and wet granular materials in a torsional rheometer  

E-Print Network [OSTI]

. The experimental research mainly focuses on the rapid deformation of granular material in a confined area. Experiments were carried out on a torsional rheometer to study how the addition of different types of lubricating oils affect the characteristics of granular...

Kannan, Raguraman

2002-01-01T23:59:59.000Z

98

Location and chemical composition of microbially induced phosphorus precipitates in anaerobic and aerobic granular sludge  

E-Print Network [OSTI]

and aerobic granular sludge A. Mañasa,b,c,e , M. Spérandioa,b,c , F. Deckerd and B. Biscanse aINSA, UPS, INP X-ray analysis (SEM-EDX) applied to granular sludge used for biological treatment of high sludge blanket (UASB) reactors and two aerobic granular sequenced batch reactors (GSBR) were evaluated

Boyer, Edmond

99

Acoustic Probing of the Jamming Transition in an Unconsolidated Granular X. Jacob, V. Aleshin, V. Tournat  

E-Print Network [OSTI]

1 Acoustic Probing of the Jamming Transition in an Unconsolidated Granular Medium X. Jacob, V the mechanically free surface of an unconsolidated granular packed structure provide information on the elasticity in unconsolidated granular media is supported by its macroscopic manifestation in nature in the form of avalanches

Paris-Sud XI, Université de

100

Hard Sphere Dynamics for Normal and Granular Fluids  

E-Print Network [OSTI]

A fluid of N smooth, hard spheres is considered as a model for normal (elastic collisions) and granular (inelastic collisions) fluids. The potential energy is discontinuous for hard spheres so the pairwise forces are singular and the usual forms of Newtonian and Hamiltonian mechanics do not apply. Nevertheless, particle trajectories in the N particle phase space are well defined and the generators for these trajectories can be identified. The first part of this presentation is a review of the generators for the dynamics of observables and probability densities. The new results presented in the second part refer to applications of these generators to the Liouville dynamics for granular fluids. A set of eigenvalues and eigenfunctions of the generator for this Liouville dynamics is identified in a special "stationary representation". This provides a class of exact solutions to the Liouville equation that are closely related to hydrodynamics for granular fluids.

James W. Dufty; Aparna Baskaran

2005-03-08T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Friction vs Texture at the Approach of a Granular Avalanche  

E-Print Network [OSTI]

We perform a novel analysis of the granular texture of a granular bed close to stability limit. Our analysis is based on a unique criterion of friction mobilisation in a simulated two-dimensional packing. In this way, we recover the bimodal character of granular texture, and the coexistence of weak and strong phases in the sense of distinct contacts populations. Moreover, we show the existence of a well-defined subset of contacts within the weak contact network. These contacts are characterized by their important friction, and form a highly coherent population in terms of fabric. They play an antagonistic role with respect to force chains. We are thus able to discriminate between incoherent contacts and coherent contacts in the weak phase, and to specify the role that the latter plays in the destabilisation process.

Lydie Staron; Farhang Radjai

2005-05-04T23:59:59.000Z

102

Inhomogeneous Cooling of the Rough Granular Gas in Two Dimensions  

E-Print Network [OSTI]

We study the inhomogeneous clustered regime of a freely cooling granular gas of rough particles in two dimensions using large-scale event driven simulations and scaling arguments. During collisions, rough particles dissipate energy in both the normal and tangential directions of collision. In the inhomogeneous regime, translational kinetic energy and the rotational energy decay with time $t$ as power-laws $t^{-\\theta_T}$ and $t^{-\\theta_R}$. We numerically determine $\\theta_T \\approx 1$ and $\\theta_R \\approx 1.6$, independent of the coefficients of restitution. The inhomogeneous regime of the granular gas has been argued to be describable by the ballistic aggregation problem, where particles coalesce on contact. Using scaling arguments, we predict $\\theta_T=1$ and $\\theta_R=1$ for ballistic aggregation, $\\theta_R$ being different from that obtained for the rough granular gas. Simulations of ballistic aggregation with rotational degrees of freedom are consistent with these exponents.

Sudhir N. Pathak; Dibyendu Das; R. Rajesh

2014-07-03T23:59:59.000Z

103

NMR Experiments on a Three-Dimensional Vibrofluidized Granular Medium  

E-Print Network [OSTI]

A three-dimensional granular system fluidized by vertical container vibrations was studied using pulsed field gradient (PFG) NMR coupled with one-dimensional magnetic resonance imaging (MRI). The system consisted of mustard seeds vibrated vertically at 50 Hz, and the number of layers N_ell <= 4 was sufficiently low to achieve a nearly time-independent granular fluid. Using NMR, the vertical profiles of density and granular temperature were directly measured, along with the distributions of vertical and horizontal grain velocities. The velocity distributions showed modest deviations from Maxwell-Boltzmann statistics, except for the vertical velocity distribution near the sample bottom which was highly skewed and non-Gaussian. Data taken for three values of N_ell and two dimensionless accelerations Gamma=15,18 were fit to a hydrodynamic theory, which successfully models the density and temperature profiles including a temperature inversion near the free upper surface.

Chao Huan; Xiaoyu Yang; D. Candela; R. W. Mair; R. L. Walsworth

2003-05-12T23:59:59.000Z

104

Runaway electrification of friable self-replicating granular matter  

E-Print Network [OSTI]

We establish that the nonlinear dynamics of collisions between particles favors the charging of a insulating, friable, self-replicating granular material that undergoes nucleation, growth, and fission processes; we demonstrate with a minimal dynamical model that secondary nucleation produces a positive feedback in an electrification mechanism that leads to runaway charging. We discuss ice as an example of such a self-replicating granular material: We confirm with laboratory experiments in which we grow ice from the vapor phase in situ within an environmental scanning electron microscope that charging causes fast-growing and easily breakable palm-like structures to form, which when broken off may form secondary nuclei. We propose that thunderstorms, both terrestrial and on other planets, and lightning in the solar nebula are instances of such runaway charging arising from this nonlinear dynamics in self-replicating granular matter.

Julyan H. E. Cartwright; Bruno Escribano; Hinrich Grothe; Oreste Piro; C. Ignacio Sainz Díaz; Idan Tuval

2014-11-19T23:59:59.000Z

105

Power-law friction in closely-packed granular materials  

E-Print Network [OSTI]

In order to understand the nature of friction in closely-packed granular materials, a discrete element simulation on granular layers subjected to isobaric plain shear is performed. It is found that the friction coefficient increases as the power of the shear rate, the exponent of which does not depend on the material constants. Using a nondimensional parameter that is known as the inertial number, the power-law can be cast in a generalized form so that the friction coefficients at different confining pressures collapse on the same curve. We show that the volume fraction also obeys a power-law.

Takahiro Hatano

2007-05-08T23:59:59.000Z

106

Time-resolved dynamics of granular matter by random laser emission  

E-Print Network [OSTI]

Because of the huge commercial importance of granular systems, the second-most used material in industry after water, intersecting the industry in multiple trades, like pharmacy and agriculture, fundamental research on grain-like materials has received an increasing amount of attention in the last decades. In photonics, the applications of granular materials have been only marginally investigated. We report the first phase-diagram of a granular as obtained by laser emission. The dynamics of vertically-oscillated granular in a liquid solution in a three-dimensional container is investigated by employing its random laser emission. The granular motion is function of the frequency and amplitude of the mechanical solicitation, we show how the laser emission allows to distinguish two phases in the granular and analyze its spectral distribution. This constitutes a fundamental step in the field of granulars and gives a clear evidence of the possible control on light-matter interaction achievable in grain-like system.

Folli, Viola; Puglisi, Andrea; Leuzzi, Luca; Conti, Claudio

2013-01-01T23:59:59.000Z

107

Time-resolved dynamics of granular matter by random laser emission  

E-Print Network [OSTI]

Because of the huge commercial importance of granular systems, the second-most used material in industry after water, intersecting the industry in multiple trades, like pharmacy and agriculture, fundamental research on grain-like materials has received an increasing amount of attention in the last decades. In photonics, the applications of granular materials have been only marginally investigated. We report the first phase-diagram of a granular as obtained by laser emission. The dynamics of vertically-oscillated granular in a liquid solution in a three-dimensional container is investigated by employing its random laser emission. The granular motion is function of the frequency and amplitude of the mechanical solicitation, we show how the laser emission allows to distinguish two phases in the granular and analyze its spectral distribution. This constitutes a fundamental step in the field of granulars and gives a clear evidence of the possible control on light-matter interaction achievable in grain-like system.

Viola Folli; Neda Ghofraniha; Andrea Puglisi; Luca Leuzzi; Claudio Conti

2013-10-22T23:59:59.000Z

108

Inert plug formation in the DDT of granular energetic materials  

SciTech Connect (OSTI)

A mechanism is proposed to explain the {open_quotes}plugs{close_quotes} that have been observed in deflagration-to-detonation transition (DDT) of granular explosives. Numerical simulations are performed that demonstrate the proposed mechanism. Observed trends are reproduced. {copyright} {ital 1996 American Institute of Physics.}

Son, S.F.; Asay, B.W.; Bdzil, J.B. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States of America)

1996-05-01T23:59:59.000Z

109

30-MHz Power Inductor Using Nano-Granular Magnetic Material  

E-Print Network [OSTI]

-granular metal-nonmetal soft magnetic materials con- sist of nano-grains of a magnetic metal in a ceramic matrix [1]­[8]. The ceramic leads to high overall resistivity, while the metal grains are too small of their characteristics are similar to nanocrystalline materials, but the ceramic leads to much higher resistivity

110

Sound wave propagation in weakly polydisperse granular materials  

E-Print Network [OSTI]

Sound wave propagation in weakly polydisperse granular materials O. Mouraille, S. Luding NSM/DCT/TUDelft, Julianalaan 136, 2628 BL Delft, Netherlands Abstract Dynamic simulations of wave propagation are performed. A small perturbation is created on one side of a static packing and its propagation, for both P- and S-waves

Luding, Stefan

111

Foams and granular media known state of mat-  

E-Print Network [OSTI]

Foams and granular media 2 known state of mat- design glasses with de- perties on an industrial n disordered ail in this review, mod- proaches to the glass ledge of advanced liq- renormalization group, FIG a broad range of lengthscales, such as atomic (top left), colloidal (top right) systems, but also in foams

Cox, Simon

112

Modeling compaction-induced energy dissipation of granular HMX  

SciTech Connect (OSTI)

A thermodynamically consistent model is developed for the compaction of granular solids. The model is an extension of the single phase limit of two-phase continuum models used to describe Deflagration-to-Detonation Transition (DDT) experiments. The focus is on the energetics and dissipation of the compaction process. Changes in volume fraction are partitioned into reversible and irreversible components. Unlike conventional DDT models, the model is applicable from the quasi-static to dynamic compaction regimes for elastic, plastic, or brittle materials. When applied to the compaction of granular HMX (a brittle material), the model predicts results commensurate with experiments including stress relaxation, hysteresis, and energy dissipation. The model provides a suitable starting point for the development of thermal energy localization sub-scale models based on compaction-induced dissipation.

Gonthier, K.A. [Lamar Univ., Beaumont, TX (US). Dept. of Mechanical Engineering; Menikoff, R.; Son, S.F.; Asay, B.W. [Los Alamos National Lab., NM (US)

1998-12-31T23:59:59.000Z

113

Fluctuations relation and external thermostats: an application to granular materials  

E-Print Network [OSTI]

In this note we discuss a paradigmatic example of interacting particles subject to non conservative external forces and to the action of thermostats consisting of external (finite) reservoirs of particles. We then consider a model of granular materials of interest for experimental tests that had recently attracted lot of attentions. This model can be reduced to the previously discussed example under a number of assumptions, in particular that inelasticity due to internal collisions can be neglected for the purpose of measuring the large deviation functional for entropy production rate. We show that if the restitution coefficient in the granular material model is close to one, then the required assuptions are verified on a specific time scale and we predict a fluctuation relation for the entropy production rate measured on the same time scale.

F. Bonetto; G. Gallavotti; A. Giuliani; F. Zamponi

2006-05-08T23:59:59.000Z

114

Friction and the oscillatory motion of granular flows  

E-Print Network [OSTI]

This contribution reports on numerical simulations of 2D granular flows on erodible beds. The broad aim is to investigate whether simple flows of model granular matter exhibits spontaneous oscillatory motion in generic flow conditions, and in this case, whether the frictional properties of the contacts between grains may affect the existence or the characteristics of this oscillatory motion. The analysis of different series of simulations show that the flow develops an oscillatory motion with a well-defined frequency which increases like the inverse of the velocity's square root. We show that the oscillation is essentially a surface phenomena. The amplitude of the oscillation is higher for lower volume fractions, and can thus be related to the flow velocity and grains friction properties. The study of the influence of the periodic geometry of the simulation cell shows no significant effect. These results are discussed in relation to sonic sands.

Lydie Staron

2012-11-26T23:59:59.000Z

115

Mixing and segregation rates in sheared granular materials  

E-Print Network [OSTI]

The size-segregation of granular materials, a process colloquially known as the Brazil Nut Effect, has generally been thought to proceed faster the greater the size difference of the particles. We experimentally investigate sheared bidisperse granular materials as a function of the size ratio of the two species, and find that the mixing rate at low confining pressure behaves as expected from percolation-based arguments. However, we also observe an anomalous effect for the re-segregation rates, wherein particles of both dissimilar and similar sizes segregate more slowly than intermediate particle size ratios. Combined with the fact that increasing the confining pressure significantly suppresses both mixing and segregation rates of particles of dissimilar size, we propose that the anomalous behavior may be attributed to a species-dependent distribution of forces within the system.

Laura A. Golick; Karen E. Daniels

2009-06-17T23:59:59.000Z

116

Hydrodynamic granular segregation induced by boundary heating and shear  

E-Print Network [OSTI]

Segregation induced by a thermal gradient of an impurity in a driven low-density granular gas is studied. The system is enclosed between two parallel walls from which we input thermal energy to the gas. We study here steady states occurring when the inelastic cooling is exactly balanced by some external energy input (stochastic force or viscous heating), resulting in a uniform heat flux. A segregation criterion based on Navier-Stokes granular hydrodynamics is written in terms of the tracer diffusion transport coefficients, whose dependence on the parameters of the system (masses, sizes and coefficients of restitution) is explicitly determined from a solution of the inelastic Boltzmann equation. The theoretical predictions are validated by means of Monte Carlo and molecular dynamics simulations, showing that Navier-Stokes hydrodynamics produces accurate segregation criteria even under strong shearing and/or inelasticity.

Francisco Vega Reyes; Vicente Garzó; Nagi Khalil

2014-04-28T23:59:59.000Z

117

Revisiting Johnson and Jackson boundary conditions for granular flows  

SciTech Connect (OSTI)

In this article, we revisit Johnson and Jackson boundary conditions for granular flows. The oblique collision between a particle and a flat wall is analyzed by adopting the classic rigid-body theory and a more realistic semianalytical model. Based on the kinetic granular theory, the input parameter for the partial-slip boundary conditions, specularity coefficient, which is not measurable in experiments, is then interpreted as a function of the particle-wall restitution coefficient, the frictional coefficient, and the normalized slip velocity at the wall. An analytical expression for the specularity coefficient is suggested for a flat, frictional surface with a low frictional coefficient. The procedure for determining the specularity coefficient for a more general problem is outlined, and a working approximation is provided.

Li, Tingwen; Benyahia, Sofiane

2012-07-01T23:59:59.000Z

118

A deductive statistical mechanics approach for granular matter  

E-Print Network [OSTI]

We introduce a deductive statistical mechanics approach for granular materials which is formally built from few realistic physical assumptions. The main finding is an universal behavior for the distribution of the density fluctuations. Such a distribution is the equivalent of the Maxwell-Boltzmann's distribution in the kinetic theory of gasses. The comparison with a very extensive set of experimental and simulation data for packings of monosized spherical grains, reveals a remarkably good quantitative agreement with the theoretical predictions for the density fluctuations both at the grain level and at the global system level. Such agreement is robust over a broad range of packing fractions and it is observed in several distinct systems prepared by using different methods. The equilibrium distributions are characterized by only one parameter ($k$) which is a quantity very sensitive to changes in the structural organization. The thermodynamical equivalent of $k$ and its relation with the `granular temperature' are also discussed.

T. Aste; T. Di Matteo

2007-11-21T23:59:59.000Z

119

On the capillary stress tensor in wet granular materials  

E-Print Network [OSTI]

This paper presents a micromechanical study of unsaturated granular media in the pendular regime, based upon numerical experiments using the discrete element method, compared to a microstructural elastoplastic model. Water effects are taken into account by adding capillary menisci at contacts and their consequences in terms of force and water volume are studied. Simulations of triaxial compression tests are used to investigate both macro and micro-effects of a partial saturation. The results provided by the two methods appear to be in good agreement, reproducing the major trends of a partially saturated granular assembly, such as the increase in the shear strength and the hardening with suction. Moreover, a capillary stress tensor is exhibited from capillary forces by using homogenisation techniques. Both macroscopic and microscopic considerations emphasize an induced anisotropy of the capillary stress tensor in relation with the pore fluid distribution inside the material. In so far as the tensorial nature of this fluid fabric implies shear effects on the solid phase associated with suction, a comparison has been made with the standard equivalent pore pressure assumption. It is shown that water effects induce microstrural phenomena that cannot be considered at the macro level, particularly when dealing with material history. Thus, the study points out that unsaturated soil stress definitions should include, besides the macroscopic stresses such as the total stress, the microscopic interparticle stresses such as the ones resulting from capillary forces, in order to interpret more precisely the implications of the pore fluid on the mechanical behaviour of granular materials.

Luc Scholtès; Pierre-Yves Hicher; François Nicot; Bruno Chareyre; Félix Darve

2011-05-05T23:59:59.000Z

120

Moving granular-bed filter development program. Topical report  

SciTech Connect (OSTI)

Advanced, coal-based, power plants, such as IGCC and Advanced-PFBC, are currently nearing commercial demonstration. These power plant technologies require hot gas filtration as part of their gas cleaning trains. Ceramic barrier filters are the major filter candidates being developed for these hot gas cleaning applications. While ceramic barrier filters achieve high levels of particle removal, concerns exist for their reliability and operability in these applications. An alternative hot gas filtration technology is the moving granular bed filter. An advanced, moving granular bed filter has been conceived, and early development activities performed by the Westinghouse Electric Corporation, Science and Technology Center. This document reports on the Base Contract tasks performed to resolve the barrier technical issues for this technology. The concept, the Standleg Moving Granular Bed Filter (SMGBF) has a concurrent downward, gas and bed media flow configuration that results in simplified features and improved scaleup feasibility compared to alternative designs. Two modes of bed media operation were assessed in the program: once-through using pelletized power plant waste as bed media, and recycle of bed media via standleg and pneumatic transport techniques. Cold Model testing; high-temperature, high-pressure testing; and pelletization testing using advanced power plant wastes, have been conducted in the program. A commercial, economic assessment of the SMGBF technology was performed for IGCC and Advanced-PFBC applications. The evaluation shows that the barrier technical issues can be resolved, and that the technology is potentially competitive with ceramic barrier filters.

Newby, R.A.; Yang, W.C.; Smeltzer, E.E.; Lippert, T.E.

1994-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Moving granular-bed filter development program topical report  

SciTech Connect (OSTI)

The Westinghouse Science Technology Center has proposed a novel moving granular-bed filter concept, the Standleg Moving Granular-Bed Filter (S-MGBF) system, that overcomes the inherent deficiencies of the current state-of-the-art moving granular-bed filter technology. The S-MGBF system combines two unique features that make it highly effective for use in advanced coal-fueled power plants. First, the S-MGBF system applies pelletization technology to generate filter pellets from the power plant solid waste materials, and uses these pellets as a once-through'' filtering media to eliminate the need for costly, complex, and large filter media recycling equipment. This pelletizing step also generates a more environmentally acceptable solid waste product and provides the potential to incorporate gas-phase contaminant sorbents into the filtering media. Secondly, the S-MGBF system passes these pellets and the flyash laden power plant gas through a highly compact S-MGBF that uses cocurrent gas-pellet contacting in an arrangement that greatly simplifies and enhances the distribution of dirty gas to the moving bed and the disengagement of clean gas from the moving bed.

Newby, R.A.; Dilmore, W.J.; Fellers, A.W.; Gasparovic, A.C.; Kittle, W.F.; Lippert, T.E.; Smeltzer, E.E.; Yang, W.C.

1991-10-17T23:59:59.000Z

122

Method and means for continuous precipitation of easy-dry, granular uranium peroxide  

DOE Patents [OSTI]

A method and means for continuous precipitation of granular uranium peroxide. The reaction vessel and agitation method practiced in it avoid filter plugging and caking problems.

Cahill, Allen E. (Roland, IA); Burkhart, deceased, Lawrence E. (late of Ames, IA)

1992-02-28T23:59:59.000Z

123

E-Print Network 3.0 - au-zro2 granular films Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

15 FEBRUARY 1999 Morphology of Quench Condensed Pb Films near the Insulator to Metal Transition Summary: substrates TS 4 K -- the so-called granular quench condensed (QC)...

124

Iron pages of HTSC  

SciTech Connect (OSTI)

Experimental data are presented on the superconducting and electronic properties of iron-based high-temperature superconductors in the normal and superconducting states. The following topics are discussed: lattice structure; structure of magnetic vortices; magnetic penetration depth; Fermi surface; isotope effect; and critical magnetic fields both in oxide compounds of 1111 type and oxide-free compounds of 122, 111, and 011 types as a function of the doping level, temperature, and external pressure.

Gasparov, V. A., E-mail: vgasparo@issp.ac.r [Russian Academy of Sciences, Institute of Solid State Physics (Russian Federation)

2010-08-15T23:59:59.000Z

125

A rheometer for measuring the material moduli for granular solids. Quarterly progress report, March 1, 1993--May 31, 1993  

SciTech Connect (OSTI)

This report describes the design of an orthogonal rheometer for the measuring of properties of granular materials such as coal. A section is presented on constitutive modeling of granular materials based on continuum theory.

Rajagopal, K.R.

1996-02-01T23:59:59.000Z

126

Validation of hadronic models using CALICE highly granular calorimeters, 15th International Conference on Calorimetry in High Energy Physics  

E-Print Network [OSTI]

Validation of hadronic models using CALICE highly granular calorimeters, 15th International Conference on Calorimetry in High Energy Physics

The CALICE Collaboration

2015-01-01T23:59:59.000Z

127

Microbial reduction of iron ore  

DOE Patents [OSTI]

A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry.

Hoffmann, Michael R. (Pasadena, CA); Arnold, Robert G. (Pasadena, CA); Stephanopoulos, Gregory (Pasadena, CA)

1989-01-01T23:59:59.000Z

128

Microbial reduction of iron ore  

DOE Patents [OSTI]

A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry. 11 figs.

Hoffmann, M.R.; Arnold, R.G.; Stephanopoulos, G.

1989-11-14T23:59:59.000Z

129

Granular flow in pebble-bed nuclear reactors: Scaling, Dust Generation, and Stress  

E-Print Network [OSTI]

Granular flow in pebble-bed nuclear reactors: Scaling, Dust Generation, and Stress Chris H. Keywords: granular flow, dust generation, numerical methods 1. Introduction Pebble-bed nuclear reactors prototypes of pebble-bed reactors, significant quantities of graphite dust have been observed due to rubbing

Rycroft, Chris H.

130

Towards the zero-surface-tension limit in granular fingering instability  

E-Print Network [OSTI]

LETTERS Towards the zero-surface-tension limit in granular fingering instability XIANG CHENG*, LEI Hele­Shaw system to explore the zero-surface-tension property of granular `fluids'16 . We demonstrate-unrealizable singular hydrodynamics predicted in the zero-surface-tension limit of normal fluid fingering2,17­23 . Above

Loss, Daniel

131

Identification of Avalanche Precursors by Acoustic Probing in the Bulk of Tilted Granular Layers  

E-Print Network [OSTI]

Identification of Avalanche Precursors by Acoustic Probing in the Bulk of Tilted Granular Layers M simultaneously caracterize precursors on the free surface with an optical method and in the bulk with acoustic to probe rearrangements in the bulk of the granular material. A linear method can also be used provided

Paris-Sud XI, Université de

132

Class-dependent rough-fuzzy granular space, dispersion index and classification  

E-Print Network [OSTI]

granular computing Soft computing Pattern recognition Remote sensing a b s t r a c t A new rough-fuzzy model for pattern classification based on granular computing is described in the present article. In this model, we propose the formulation of class-dependent granules in fuzzy environment. Fuzzy membership

Pal, Sankar Kumar

133

4/3 law of Granular Particles Flowing through a Vertical Pipe  

E-Print Network [OSTI]

4/3 law of Granular Particles Flowing through a Vertical Pipe Osamu Moriyama, Naoya Kuroiwa­01, Japan (Received June 16, 1997) Density waves of granular material (sand) flowing through a vertical pipe have been investigated. Clear density waves emerge when the cock attached to bottom end of the pipe

Hayakawa, Hisao

134

The Mechanical Coupling of Fluid-Filled Granular Material Under Shear  

E-Print Network [OSTI]

The Mechanical Coupling of Fluid-Filled Granular Material Under Shear L. Goren*, E. Aharonov and University of Strasbourg (EOST), Strasbourg, France. Abstract. The coupled mechanics of fluid-filled granular the mechanical strength of the grains skeleton? To answer these questions, a formulation for the pore fluid

Paris-Sud XI, Université de

135

Granular impact cratering by liquid drops: Understanding raindrop imprints through an analogy to asteroid strikes  

E-Print Network [OSTI]

When a granular material is impacted by a sphere, its surface deforms like a liquid yet it preserves a circular crater like a solid. Although the mechanism of granular impact cratering by solid spheres is well explored, our knowledge on granular impact cratering by liquid drops is still very limited. Here, by combining high-speed photography with high-precision laser profilometry, we investigate liquid-drop impact dynamics on granular surface and monitor the morphology of resulting impact craters. Surprisingly, we find that, despite the enormous energy and length difference, granular impact cratering by liquid drops follows the same energy scaling and reproduces the same crater morphology as that of asteroid impact craters. Inspired by this similarity, we integrate the physical insight from planetary sciences, the liquid marble model from fluid mechanics and the concept of jamming transition from granular physics into a simple theoretical framework that quantitatively describes all the main features of liquid-drop imprints in granular media. Our study sheds light on the mechanisms governing raindrop impacts on granular surfaces and reveals a remarkable analogy between familiar phenomena of raining and catastrophic asteroid strikes.

Runchen Zhao; Qianyun Zhang; Hendro Tjugito; Xiang Cheng

2014-12-23T23:59:59.000Z

136

A General Criterion for Liquefaction in Granular Layers with Heterogeneous Pore Pressure  

E-Print Network [OSTI]

A General Criterion for Liquefaction in Granular Layers with Heterogeneous Pore Pressure Liran-saturated granular and porous layers can undergo liquefaction and lose their shear resistance when subjected to shear forcing. In geosystems, such a process can lead to severe natural hazards of soil liquefaction

Einat, Aharonov

137

A General Criterion for Liquefaction in Granular Layers with Heterogeneous Pore Pressure  

E-Print Network [OSTI]

numerical simulations a general criterion for liquefaction that applies also for the cases in which the poreA General Criterion for Liquefaction in Granular Layers with Heterogeneous Pore Pressure December.g.flekkoy@fys.uio.no ABSTRACT Fluid-saturated granular and porous layers can undergo liquefaction and lose their shear

Paris-Sud XI, Université de

138

Friction of a slider on a granular layer: Nonmonotonic thickness dependence and effect of boundary conditions  

E-Print Network [OSTI]

Friction of a slider on a granular layer: Nonmonotonic thickness dependence and effect of boundary the effective friction encountered by a mass sliding on a granular layer as a function of bed thickness and boundary roughness conditions. The observed friction has minima for a small number of layers before

Kudrolli, Arshad

139

Granularity as an Optimal Approach to Uncertainty A General Mathematical Idea With Applications to  

E-Print Network [OSTI]

of Mathematical Sciences New Mexico State University Las Cruces, NM 88003, USA email hunguyen@nmsu.edu Abstract viewpoint, granularity is a crude approximation. From the viewpoint of traditional prob- abilistic or fuzzy approach, this granular description is a crude approximate description of the continuous un- certainty. One

Kreinovich, Vladik

140

Granularity as an Optimal Approach to Uncertainty --A General Mathematical Idea With Applications to  

E-Print Network [OSTI]

of Mathematical Sciences New Mexico State University Las Cruces, NM 88003, USA email hunguyen@nmsu.edu Abstract the traditional viewpoint, granularity is a crude approximation. From the viewpoint of traditional prob­ abilistic or fuzzy approach, this granular description is a crude approximate description of the continuous un

Kreinovich, Vladik

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Surface wave acoustics of granular packing under gravity  

SciTech Connect (OSTI)

Due to the non-linearity of Hertzian contacts, the speed of sound in granular matter increases with pressure. For a packing under gravity and in the presence of a free surface, bulk acoustic waves cannot propagate due to the inherent refraction toward the surface (the mirage effect). Thus, only modes corresponding to surface waves (Raleigh-Hertz modes) are able to propagate the acoustic signal. First, based on a non-linear elasticity model, we describe the main features associated to these surface waves. We show that under gravity, a granular packing is from the acoustic propagation point of view an index gradient waveguide that selects modes of two distinct families i.e. the sagittal and transverse waves localized in the vicinity of the free surface. A striking feature of these surface waves is the multi-modal propagation: for both transverse and sagittal waves, we show the existence of a infinite but discrete series of propagating modes. In each case, we determine the mode shape and and the corresponding dispersion relation. In the case of a finite size system, a geometric waveguide is superimposed to the index gradient wave guide. In this later case, the dispersion relations are modified by the appearance of a cut-off frequency that scales with depth. The second part is devoted to an experimental study of surface waves propagating in a granular packing confined in a long channel. This set-up allows to tune a monomodal emission by taking advantage of the geometric waveguide features combined with properly designed emitters. For both sagittal and transverses waves, we were able to isolate a single mode (the fundamental one) and to plot the dispersion relation. This measurements agree well with the Hertzian scaling law as predicted by meanfield models. Furthermore, it allows us to determine quantitatively relations on the elastic moduli. However, we observe that our data yield a shear modulus abnormally weak when compared to several meanfield predictions.

Clement, Eric; Andreotti, Bruno [PMMH, ESPCI, CNRS (UMR 7636) and Univ. Paris 6 and Paris 7, 10 rue Vauquelin, 75005 Paris (France); Bonneau, Lenaic [PMMH, ESPCI, CNRS (UMR 7636) and Univ. Paris 6 and Paris 7, 10 rue Vauquelin, 75005 Paris (France)

2009-06-18T23:59:59.000Z

142

Magnetoresistance oscillations in superconducting granular niobium nitride nanowires.  

SciTech Connect (OSTI)

We report on magnetoresistance oscillations in superconducting NbN{sub x} nanowires synthesized through ammonia gas annealing of NbSe{sub 3} precursor nanostructures. Even though the transverse dimensions of the nanowires are much larger than the superconducting coherence length, the voltage-current characteristics of these nanowires at low temperatures are reminiscent of one-dimensional superconductors where quantum phase slips are associated with the origin of dissipation. We show that both the magnetoresistance oscillations and voltage-current characteristics observed in this work result from the granular structure of our nanowires.

Patel, U.; Xiao, Z. L.; Gurevich, A.; Avci, S.; Hua, J.; Divan, R.; Welp, U.; Kwok, W. K.; Northern Illinois Univ.; National High Magnetic Field Lab.

2009-01-01T23:59:59.000Z

143

The nature of quasistatic deformation in granular materials  

E-Print Network [OSTI]

Strain in granular materials in quasistatic conditions under varying stress originate in (I) contact deformation and (II) rearrangements of the contact network. Depending on sample history and applied load, either mechanism might dominate. One may thus define rheological regimes I and II accordingly. Their properties are presented and illustrated here with discrete numerical simulation results on sphere packings. Understanding the microscopic physical origin of strain enables one to clarify such issues as the existence of macroscopic elasticity, the approach to stress-strain relations in the large system limit and the sensitivity to noise.

Jean-Noël Roux

2009-01-15T23:59:59.000Z

144

Shear zone refraction and deflection in layered granular materials  

E-Print Network [OSTI]

Refraction and deflection of shear zones in layered granular materials was studied experimentally and numerically. We show, that (i) according to a recent theoretical prediction [T. Unger, Phys. Rev. Lett. 98, 018301 (2007)] shear zones refract in layered systems in analogy with light refraction, (ii) zone refraction obeys Snell's law known from geometric optics and (iii) under natural pressure conditions (i.e. in the presence of gravity) the zone can also be deflected by the interface so that the deformation of the high friction material is avoided.

Tamas Borzsonyi; Tamas Unger; Balazs Szabo

2009-12-09T23:59:59.000Z

145

A Maxwell Construction for Phase Separation in Vibrated Granular Matter?  

E-Print Network [OSTI]

Experiments and computer simulations are carried out to investigate ordering principles in a granular gas which phase separates under vibration. The densities of the dilute and the dense phase are found to follow a lever rule. A Maxwell construction is found to predict both the coexisting pressure and binodal densities remarkably well, despite the fact that the pressure-volume characteristic $P(v)$ is not an isotherm. Although the system is far from equilibrium and energy conservation is strongly violated, we derive the construction from the minimization of mechanical work and fluctuating particle currents.

James P. D. Clewett; Jack Wade; R. M. Bowley; Stephan Herminghaus; Michael R. Swift; Marco G. Mazza

2015-02-28T23:59:59.000Z

146

Lack of energy equipartition in homogeneous heated binary granular mixtures  

E-Print Network [OSTI]

We consider the problem of determining the granular temperatures of the components of a homogeneous binary heated mixture of inelastic hard spheres, in the framework of Enskog kinetic theory. Equations are derived for the temperatures of each species and their ratio, which is different from unity, as may be expected since the system is out of equilibrium. We focus on the particular heating mechanism where the inelastic energy loss is compensated by an injection through a random external force (``stochastic thermostat''). The influence of various parameters and their possible experimental relevance is discussed.

A. Barrat; E. Trizac

2002-05-21T23:59:59.000Z

147

Energy trapping and shock disintegration in a composite granular medium  

E-Print Network [OSTI]

Granular materials demonstrate a strongly nonlinear behavior influencing the wave propagation in the medium. We report the first experimental observation of impulse energy confinement and the resultant disintegration of shock and solitary waves. The medium consists of alternating ensambles of high-modulus vs orders of magnitude lower modulus chains of different masses. The trapped energy is contained within the "softer" portions of the composite chain and is slowly released in the form of weak, separated pulses over an extended period of time. This effect is enhanced by using a specific group assembly and superimposed force.

C. Daraio; V. F. Nesterenko; E. B. Herbold; S. Jin

2005-09-24T23:59:59.000Z

148

The building blocks of dynamical heterogeneities in dense granular media  

E-Print Network [OSTI]

We investigate experimentally the connection between short time dynamics and long time dynamical heterogeneities within a dense granular media under cyclic shear. We show that dynamical heterogeneities result from a two timescales process. Short time but already collective events consisting in clustered cage jumps concentrate most of the non affine displacements. On larger timescales such clusters appear aggregated both temporally and spatially in avalanches which eventually build the large scales dynamical heterogeneities. Our results indicate that facilitation plays an important role in the relaxation process although it does not appear to be conserved as proposed in many models studied in the literature.

R. Candelier; O. Dauchot; G. Biroli

2009-01-22T23:59:59.000Z

149

Iron efficiency in sorghum  

E-Print Network [OSTI]

) James Craig Esty, B, S. , Panhandle State College Co-Chairmen of Advisory Committee: Dr. Arthur B. Onken Dr. Lloyd R. Hossner R tt *ht ' d f * ' g * gh L~Sh bicolor (L. ) Moenchj parental lines and Fl hybrids indicate varying degrees of iron (Fe...) utilization. Visual ratings after seven days of Fe stress indicated only one hybrid, ATx 378 x RTx 2536, to be green or Fe efficient. Hybrids or parental lines rated partially chlorotic were: ATx 378 x RTx 415 and RTx 2536. Those sorghums rated chlorotic...

Esty, James Craig

1979-01-01T23:59:59.000Z

150

Dynamical mechanism for non-locality in dense granular flows  

E-Print Network [OSTI]

The dynamical mechanism at the origin of the non-local rheology of dense granular flows is investigated trough discrete element simulations. We show that the influence of a shear band on the mechanical behavior of a distant zone is contained in the spatial variations observed in the network of granular contacts. Using a micro-rheology technique, we establish that the exponential responses hence obtained, do not proof the validity of a mechanical activation process as previously suggested, but stem from the spatial relaxation of the shear rate as a direct consequence of a macroscopic non-local constitutive relation. Finally, by direct visualization of the local relaxation processes, we dismiss the kinetic elasto-plastic picture, where a flow is conceived as a quasi-static sequence of localized plastic events interacting through the stress field. We therefore conclude in favor of the jamming scenario, where geometrical constrains lead to coherent non-affine displacements along floppy modes, inherently non-local.

M. Bouzid; M. Trulsson; P. Claudin; E. Clement; B. Andreotti

2014-05-09T23:59:59.000Z

151

Electron Correlation in Iron-Based Superconductors  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two...

152

Eosinophilic fasciitis secondary to intravenous iron infusions  

E-Print Network [OSTI]

secondary to intravenous iron infusions Bahar F Firoz MD MPHfour weeks after receiving intravenous iron infusions atmultiple infusion sites along the right proximal forearm.

Firoz, Bahar F; Goldberg, Leonard H; Landau, Jennifer; Kaye, Valda; Berman, Louis

2010-01-01T23:59:59.000Z

153

Transcriptional and translational regulatory responses to iron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Candidatus Pelagibacter ubique cultures to iron limitation in natural seawater media supplemented with a siderophore to chelate iron. MethodologyPrincipal Findings:...

154

Gas-Mediated Impact Dynamics in Fine-Grained Granular Materials  

E-Print Network [OSTI]

Non-cohesive granular media exhibit complex responses to sudden impact that often differ from those of ordinary solids and liquids. We investigate how this response is mediated by the presence of interstitial gas between the grains. Using high-speed x-ray radiography we track the motion of a steel sphere through the interior of a bed of fine, loose granular material. We find a crossover from nearly incompressible, fluid-like behavior at atmospheric pressure to a highly compressible, dissipative response once most of the gas is evacuated. We discuss these results in light of recent proposals for the drag force in granular media.

John R. Royer; Eric I. Corwin; Peter J. Eng; Heinrich M. Jaeger

2007-07-17T23:59:59.000Z

155

Penetration depth scaling for impact into wet granular packings  

E-Print Network [OSTI]

We present experimental measurements of penetration depths for the impact of spheres into wetted granular media. We observe that the penetration depth in the liquid saturated case scales with projectile density, size, and drop height in a fashion consistent with the scaling observed in the dry case, but that penetration depths into saturated packings tend to be smaller. This result suggests that, for the range of impact energies observed, the stopping force is set by static contact forces between grains within the bed, and that the presence of liquid serves, primarily, to enhance these contact forces. The enhancement to the stopping force has a complicated dependence on liquid fraction, accompanied by a change in the drop-height dependence, that must be the consequence of accompanying changes in the conformation of the liquid phase in the interstices.

Theodore A. Brzinski III; Jorin Schug; Kelly Mao; Douglas J. Durian

2015-01-25T23:59:59.000Z

156

Heating mechanism affects equipartition in a binary granular system  

E-Print Network [OSTI]

Two species of particles in a binary granular system typically do not have the same mean kinetic energy, in contrast to the equipartition of energy required in equilibrium. We investigate the role of the heating mechanism in determining the extent of this non-equipartition of kinetic energy. In most experiments, different species of particle are unequally heated at the boundaries. We show by event-driven simulations that this differential heating at the boundary influences the level of non-equipartition even in the bulk of the system. This conclusion is fortified by studying a numerical model and a solvable stochastic model without spatial degrees of freedom. In both cases, even in the limit where heating events are rare compared to collisions, the effect of the heating mechanism persists.

Hong-Qiang Wang; Narayanan Menon

2007-10-19T23:59:59.000Z

157

Reflection and Exclusion of Shear Zones in Inhomogeneous Granular Materials  

E-Print Network [OSTI]

Shear localization in granular materials is studied experimentally and numerically. The system consists of two material layers with different effective frictions. The presence of the material interface leads to a special type of "total internal reflection" of the shear zone. In a wide range of configurations the reflection is characterized by a fixed angle which is analogous to the critical angle of refraction in optics. The zone leaves and reenters the high friction region at this critical angle and in between it stays near the interface in the low friction region. The formalism describing the geometry of the shear zones and that of refracted and reflected light beams is very similar. For the internal visualization of shear localization two independent experimental techniques were used (i) excavation and (ii) Magnetic Resonance Imaging.

Tamas Borzsonyi; Tamas Unger; Balazs Szabo; Sandra Wegner; Frank Angenstein; Ralf Stannarius

2011-08-17T23:59:59.000Z

158

Method for reducing iron losses in an iron smelting process  

DOE Patents [OSTI]

A process of smelting iron that comprises the steps of: a) introducing a source of iron oxide, oxygen, nitrogen, and a source of carbonaceous fuel to a smelting reactor, at least some of said oxygen being continuously introduced through an overhead lance; b) maintaining conditions in said reactor to cause (i) at least some of the iron oxide to be chemically reduced, (ii) a bath of molten iron to be created and stirred in the bottom of the reactor, surmounted by a layer of slag, and (iii) carbon monoxide gas to rise through the slag; c) causing at least some of said carbon monoxide to react in the reactor with the incoming oxygen, thereby generating heat for reactions taking place in the reactor; and d) releasing from the reactor an offgas effluent, is run in a way that keeps iron losses in the offgas relatively low. After start-up of the process is complete, steps (a) and (b) are controlled so as to: e) keep the temperature of the molten iron at or below about 1550.degree. C. and f) keep the slag weight at or above about 0.8 tonne per square meter.

Sarma, Balu (Airmont, NY); Downing, Kenneth B. (Greenville, SC)

1999-01-01T23:59:59.000Z

159

Method for reducing iron losses in an iron smelting process  

DOE Patents [OSTI]

A process of smelting iron that comprises the steps of: (a) introducing a source of iron oxide, oxygen, nitrogen, and a source of carbonaceous fuel to a smelting reactor, at least some of said oxygen being continuously introduced through an overhead lance; (b) maintaining conditions in said reactor to cause (1) at least some of the iron oxide to be chemically reduced, (2) a bath of molten iron to be created and stirred in the bottom of the reactor, surmounted by a layer of slag, and (3) carbon monoxide gas to rise through the slag; (c) causing at least some of said carbon monoxide to react in the reactor with the incoming oxygen, thereby generating heat for reactions taking place in the reactor; and (d) releasing from the reactor an offgas effluent, is run in a way that keeps iron losses in the offgas relatively low. After start-up of the process is complete, steps (a) and (b) are controlled so as to: (1) keep the temperature of the molten iron at or below about 1550 C and (2) keep the slag weight at or above about 0.8 ton per square meter. 13 figs.

Sarma, B.; Downing, K.B.

1999-03-23T23:59:59.000Z

160

Nonlinear Rate-Dependent Material Model with Damage and Plasticity from Granular Micromechanics Approach  

E-Print Network [OSTI]

based and ignores the effect of microstructural changes on the overall mechanical behavior. Therefore, to overcome the limitation of phenomenological based models, we utilize granular micromechanics approach in conjunction with thermo...

Singh, Viraj

2014-05-31T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Acoustic Probing of the Jamming Transition in an Unconsolidated Granular Medium  

E-Print Network [OSTI]

Experiments with acoustic waves guided along the mechanically free surface of an unconsolidated granular packed structure provide information on the elasticity of granular media at very low pressures that are naturally controlled by the gravitational acceleration and the depth beneath the surface. Comparison of the determined dispersion relations for guided surface acoustic modes with a theoretical model reveals the dependencies of the elastic moduli of the granular medium on pressure. The experiments confirm recent theoretical predictions that relaxation of the disordered granular packing through non-affine motion leads to a peculiar scaling of shear rigidity with pressure near the jamming transition corresponding to zero pressure. Unexpectedly, and in disagreement with the most of the available theories, the bulk modulus depends on pressure in a very similar way to the shear modulus.

Jacob, Xavier; Tournat, Vincent; Leclaire, Philippe; Lauriks, Walter; Gusev, Vitalyi

2007-01-01T23:59:59.000Z

162

Theory of acoustic attenuation, dispersion, and pulse propagation in unconsolidated granular materials including  

E-Print Network [OSTI]

Theory of acoustic attenuation, dispersion, and pulse propagation in unconsolidated granular of particles in contact with a new, rough-surface, random-packing model of mineral grains in unconsolidated

Buckingham, Michael

163

Acoustic Probing of the Jamming Transition in an Unconsolidated Granular Medium  

E-Print Network [OSTI]

Experiments with acoustic waves guided along the mechanically free surface of an unconsolidated granular packed structure provide information on the elasticity of granular media at very low pressures that are naturally controlled by the gravitational acceleration and the depth beneath the surface. Comparison of the determined dispersion relations for guided surface acoustic modes with a theoretical model reveals the dependencies of the elastic moduli of the granular medium on pressure. The experiments confirm recent theoretical predictions that relaxation of the disordered granular packing through non-affine motion leads to a peculiar scaling of shear rigidity with pressure near the jamming transition corresponding to zero pressure. Unexpectedly, and in disagreement with the most of the available theories, the bulk modulus depends on pressure in a very similar way to the shear modulus.

Xavier Jacob; Vladislav Aleshin; Vincent Tournat; Philippe Leclaire; Walter Lauriks; Vitalyi Gusev

2007-10-11T23:59:59.000Z

164

Study of gas flow dynamics in porous and granular media with laser-polarized ¹²?Xe NMR  

E-Print Network [OSTI]

This thesis presents Nuclear Magnetic Resonance (NMR) studies of gas flow dynamics in porous and granular media by using laser-polarized ¹²?Xe . Two different physical processes, the gas transport in porous rock cores and ...

Wang, Ruopeng, 1972-

2005-01-01T23:59:59.000Z

165

Diffusing-wave spectroscopy study of microscopic dynamics of three-dimensional granular systems  

E-Print Network [OSTI]

fluidized-granular systems, such as; channel flow, gas-fluidized beds, avalanche flow, and vibro-fluidized, such as magnetic resonance imaging (MRI),21,22 X-ray microtomography,23,24 electrical capacitance tomography (ECT

Pak, Hyuk Kyu

166

Evolution of a non-cohesive granular bed subject to a succession of erosive turbidity currents  

E-Print Network [OSTI]

An experiment was performed to study the evolution of a non-cohesive granular bed subject to a succession of erosive turbidity currents to evaluate the applicability of a proposed interface model that prescribes a relationship ...

Rangel, Roberto Carlos

2006-01-01T23:59:59.000Z

167

Failure in shear bands for granular materials: thermo-hydro-chemo-mechanical effects  

E-Print Network [OSTI]

Failure in shear bands for granular materials: thermo-hydro-chemo- mechanical effects M. VEVEAKIS depends on the chemical reaction characteristics and that micro-inertia due to grain translations

Paris-Sud XI, Université de

168

Jamming during the discharge of granular matter from a silo Iker Zuriguel,1,  

E-Print Network [OSTI]

the idea of "jamming transition," character- ized by the sudden arrest of the particle dynamics. Glass transitions, colloidal gels, foams, as well as granular flows, traffic, and stampedes are included among

Weeks, Eric R.

169

Process for the synthesis of iron powder  

DOE Patents [OSTI]

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder. 2 figs.

Welbon, W.W.

1983-11-08T23:59:59.000Z

170

Process for the synthesis of iron powder  

DOE Patents [OSTI]

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Not Available

1982-03-06T23:59:59.000Z

171

Iron and Steel Energy Intensities  

U.S. Energy Information Administration (EIA) Indexed Site

If you are having trouble, call 202-586-8800 for help. Home > >Energy Users > Energy Efficiency Page > Iron and Steel Energy Intensities First Use of Energy Blue Bullet First Use...

172

Numerical simulation of comminution in granular materials with an application to fault gouge evolution  

E-Print Network [OSTI]

NUMERICAL SIMULATION OF COMMINUTION IN GRANULAR MATERIALS WITH AN APPLICATION TO FAULT GOUGE EVOLUTION A Thesis by RICHARD ANTHONY LANG Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 2002 Major Subject: Geophysics NUMERICAL SIMULATION OF COMMINUTION IN GRANULAR MATERIALS WITH AN APPLICATION TO FAULT GOUGE EVOLUTION A Thesis by RICHARD ANTHONY LANG Submitted...

Lang, Richard Anthony

2004-09-30T23:59:59.000Z

173

Explorations of iron-iron hydrogenase active site models by experiment and theory  

E-Print Network [OSTI]

This dissertation describes computational and experimental studies of synthetic complexes that model the active site of the iron-iron hydrogenase [FeFe]H2ase enzyme. Simple dinuclear iron dithiolate complexes act as functional models of the ironiron...

Tye, Jesse Wayne

2009-05-15T23:59:59.000Z

174

Absorption of Iron from Ferritin Is Independent of Heme Iron and Ferrous Salts in Women and Rat Intestinal Segments .  

E-Print Network [OSTI]

??Ferritin iron from food is readily bioavailable to humans and has the potential for treating iron deficiency. Whether ferritin iron absorption is mechanistically different from… (more)

Theil, Elizabeth C.

2012-01-01T23:59:59.000Z

175

Shear Jamming in Granular Experiments without Basal Friction  

E-Print Network [OSTI]

Jammed states of frictional granular systems can be induced by shear strain at densities below the isostatic jamming density ($\\phi_c$). It remains unclear, however, how much friction affects this so-called shear-jamming. Friction appears in two ways in this type of experiment: friction between particles, and friction between particles and the base on which they rest. Here, we study how particle-bottom friction, or basal friction, affects shear jamming in quasi-two dimensional experiments. In order to study this issue experimentally, we apply simple shear to a disordered packing of photoelastic disks. We can tune the basal friction of the particles by immersing the particles in a density matched liquid, thus removing the normal force, hence the friction, between the particles and base. We record the overall shear stress, and particle motion, and the photoelastic response of the particles. We compare the shear response of dry and immersed samples, which enables us to determine how basal friction affects shear jamming. Our findings indicate that changing the basal friction shifts the point of shear jamming, but it does not change the basic phenomenon of shear jamming.

Hu Zheng; Joshua A. Dijksman; Robert P. Behringer

2014-04-29T23:59:59.000Z

176

Granular-bed-filter development program, Phase II. Final report  

SciTech Connect (OSTI)

The high-temperature moving bed granular filter (GBF) program at Combustion Power Company (CPC) commenced in 1977. Its purpose was to investigate, for the Department of Energy, the filtration performance of the GBF for application to coal-fired PFBC turbine systems. The GBF test system was successfully operated on 1500/sup 0/F to 1600/sup 0/F gases produced from an atmospheric pressure coal-fired fluidized bed combustor. Overall collection efficiencies above 99% and submicron collection efficiencies above 96% were consistently demonstrated in over 1500 hours of high-temperature testing. Alkali content of the hot gases was also measured to evaluate aluminosilicate additives for controlling alkali emissions. Operational and performance stability under upset conditions (ten times normal inlet loading and 125% of design gas flowrate) was also demonstrated experimentally. A computer-based GBF performance model was developed. It predicts overall particle capture within +- 5%. Gas flow streamlines and isobars are computer generated from theoretical principles and particle capture is based on the most recent empirical models. The effects of elevated pressure on efficiency and filter pressure drop are included in the model. A modular approach was adopted for GBF scale-up to commercial size systems using elements of the same size tested in this program. Elements can be readily packaged into 30,000 acfm modules at a projected equipment cost of approximately $27 per acfm.

Guillory, J.; Cooper, J.; Ferguson, J.; Goldbach, G.; Placer, F.

1983-05-01T23:59:59.000Z

177

Correcting Iron Deficiencies in Grain Sorghum  

E-Print Network [OSTI]

Until grain sorghum develops an extensive root system, young plants may be unable to obtain enough ferrous iron to maintain normal growth. This publication offers strategies for avoiding, identifying and correcting iron deficiencies....

Livingston, Stephen; Coffman, Cloyce G.; Unruh, L. G.

1996-02-20T23:59:59.000Z

178

Ligand iron catalysts for selective hydrogenation  

DOE Patents [OSTI]

Disclosed are iron ligand catalysts for selective hydrogenation of aldehydes, ketones and imines. A catalyst such as dicarbonyl iron hydride hydroxycyclopentadiene) complex uses the OH on the five member ring and hydrogen linked to the iron to facilitate hydrogenation reactions, particularly in the presence of hydrogen gas.

Casey, Charles P. (Madison, WI); Guan, Hairong (Cincinnati, OH)

2010-11-16T23:59:59.000Z

179

NMR experiments on a three-dimensional vibrofluidized granular medium Chao Huan, Xiaoyu Yang,* and D. Candela  

E-Print Network [OSTI]

coupled with one-dimensional magnetic resonance imaging. The system consisted of mustard seeds vibrated-dimensional granular system fluidized by vertical container vibrations was studied using pulsed field gradient NMR.05.Rm I. INTRODUCTION One of the basic granular flow phenomena is the creation of a fluidized state

Walsworth, Ronald L.

180

hal-00283263,version1-29May2008 Submitted Nonlinear effects for coda-type elastic waves in stressed granular media  

E-Print Network [OSTI]

are presented on the nonlinear acoustic effects of multiple scattered elastic waves in unconsolidated granular modifications in the elastic response of an unconsolidated granular structure. PACS numbers: Valid PACS appear here I. INTRODUCTION Unconsolidated granular materials are known to ex- hibit a high complexity

Boyer, Edmond

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Collective behavior in a granular jet: Emergence of a liquid with zero surface-tension  

E-Print Network [OSTI]

We perform the analog to the "water bell" experiment using non-cohesive granular material. When a jet of granular material, many particles wide, rebounds from a fixed cylindrical target, it deforms into a sharply-defined sheet or cone with a shape that mimics a liquid with zero surface tension. The particulate nature of granular material becomes apparent when the number of particles in the cross-section of the jet is decreased and the emerging sheets and cones broaden and gradually disintegrate into a broad spray. This experiment has its counterpart in the behavior of the quark-gluon plasma generated by collisions of gold ions at the Relativistic Heavy Ion Collider. There a high density of inter-particle collisions gives rise to collective behavior that has also been described as a liquid.

Xiang Cheng; German Varas; Daniel Citron; Heinrich M. Jaeger; Sidney R. Nagel

2007-06-14T23:59:59.000Z

182

Crucial role of side walls for granular surface flows: consequences for the rheology  

E-Print Network [OSTI]

In this paper we study the steady uniform flows that develop when granular material is released from a hopper on top of a static pile in a channel. We more specifically focus on the role of side walls by carrying out experiments in setup of different widths, from narrow channels 20 particle diameters wide to channels 600 particle diameters wide. Results show that steady flows on pile are entirely controlled by side wall effects. A theoretical model, taking into account the wall friction and based on a simple local constitutive law recently proposed for other granular flow configurations (GDR MiDi 2004), gives predictions in quantitative agreement with the measurements. This result gives new insights in our understanding of free surface granular flows and strongly supports the relevance of the constitutive law proposed.

Pierre Jop; Yoël Forterre; Olivier Pouliquen

2014-10-16T23:59:59.000Z

183

Critical Phenomena in Driven Granular Matter: Jamming and Glassy Behavior - Final Report  

SciTech Connect (OSTI)

Granular materials, such as powders, seeds, grains, sand, rocks, etc., are ubiquitous both in nature and in industrial processes. At the scale of individual grains, granular systems are particularly simple: particles interact only when they touch. But when viewed in the aggregate, granular systems can display complex behavior. In particular, as the volume packing fraction of the grains increases, the system undergoes a jamming transition from a flowing liquid to a disordered but rigid solid. We study the critical behavior of such systems near the jamming transition using numerical simulations of a simple model of soft-core, bidisperse, frictionless disks in two dimensions. We seek to understand the structural and transport properties of such systems under a variety of physical perturbations such as steady state shear driven flow, and finite thermal fluctuations.

Teitel, Stephen

2013-02-20T23:59:59.000Z

184

A biaxial apparatus for the study of heterogeneous and intermittent strains in granular materials  

E-Print Network [OSTI]

We present an experimental apparatus specifically designed to investigate the precursors of failure in granular materials. A sample of granular material is placed between a latex membrane and a glass plate. A confining effective pressure is applied by applying vacuum to the sample. Displacement-controlled compression is applied in the vertical direction, while the specimen deforms in plane strain. A Diffusing Wave Spectroscopy visualization setup gives access to the measurement of deformations near the glass plate. After describing the different parts of this experimental setup, we present a demonstration experiment where extremely small (of order $10^{-5}$) heterogeneous strains are measured during the loading process.

Antoine Le Bouil; Axelle Amon; Jean-Christophe Sangleboeuf; Hervé Orain; Pierre Bésuelle; Gioacchino Viggiani; Patrick Chasle; Jérôme Crassous

2013-12-17T23:59:59.000Z

185

Sphere penetration by impact in a granular medium: A collisional process  

E-Print Network [OSTI]

The penetration by a gravity driven impact of a solid sphere into a granular medium is studied by two-dimensional simulations. The scaling laws observed experimentally for both the final penetration depth and the stopping time with the relevant physical parameters are here recovered numerically without the consideration of any solid friction. Collisional processes are thus found as essential in explaining the physics of the qualitatively observed phenomena whereas frictional processes can only be considered as secondary effects in the granular penetration by impact.

Antoine Seguin; Yann Bertho; Philippe Gondret; Jerome Crassous

2009-11-26T23:59:59.000Z

186

Iron production maintenance effectiveness system  

SciTech Connect (OSTI)

In 1989, an internal study in the Coke and Iron Maintenance Department identified the opportunities available to increase production, by decreasing unscheduled maintenance delays from 4.6%. A five year front loaded plan was developed, and presented to the company president. The plan required an initial investment of $1.4 million and a conservative break-even point was calculated to be 2.5 years. Due to budget restraints, it would have to be self-funded, i.e., generate additional production or savings, to pay for the program. The program began in 1991 at number 2 coke plant and the blast furnaces. This paper will describe the Iron Production Maintenance Effectiveness System (ME), which began with the mechanical and pipefitting trades.

Augstman, J.J. [Dofasco Inc., Hamilton, Ontario (Canada)

1996-12-31T23:59:59.000Z

187

Analysis of granular flow in a pebble-bed nuclear reactor Chris H. Rycroft,1  

E-Print Network [OSTI]

Analysis of granular flow in a pebble-bed nuclear reactor Chris H. Rycroft,1 Gary S. Grest,2 James February 2006; published 24 August 2006 Pebble-bed nuclear reactor technology, which is currently being States, the Modular Pebble Bed Reactor MPBR 4,8 is a candidate for the next generation nuclear plant

Bazant, Martin Z.

188

Stochastic flow rule for granular materials Ken Kamrin and Martin Z. Bazant  

E-Print Network [OSTI]

of Mathematics, Massachusetts Institute of Technology, Cambridge, Massachusetts 01239, USA Received 15 September , this simple model is able to predict a variety of granular flow profiles in flat-bottom silos, annular Couette. For special cases of admissible slip lines, such as plate dragging under a heavy load or flow down an inclined

Bazant, Martin Z.

189

Finite Element Modeling of Rate-Dependent Ratcheting in Granular Materials  

E-Print Network [OSTI]

Finite Element Modeling of Rate-Dependent Ratcheting in Granular Materials A. Karrech a,, A. Seibi thrust is the introduc- tion of the "Chicago" law in a continuum approach to account for the ratcheting or jointly with the ratcheting effect. Non-associated plasticity is adopted since the paper mainly targets

Paris-Sud XI, Université de

190

Granular flow in the marginal ice zone BY DANIEL L. FELTHAM  

E-Print Network [OSTI]

and the balance equation of fluctuation kinetic energy. The steady solution of these equations is found to leading in determining the dynamics of the MIZ. Here, sea ice is treated as a granular material with a composite rheology. A simplified model of the MIZ is introduced consisting of the along and across momentum balance of the sea ice

Feltham, Daniel

191

A HighGranularity Scintillator Calorimeter Read Out with Silicon Photomultipliers  

E-Print Network [OSTI]

energy of photons and measured hadronic energy of neutral hadrons. Thus, high granu­ larity is necessary Abstract We report upon the design, construction and performance of a prototype for a high­granularity tile. Detector calibration, noise, linearity and stability are discussed, and the energy response in a 1­6 Ge

192

Ultrasonic wave transport in weakly confined granular media in the intermediate frequency regime  

E-Print Network [OSTI]

Understanding how sound propagates through random non-cohesive granular media [1,2,3,4], such as the sand, has in between nonlinear elastic interactions between grains at the scale of the contacts [5,6], the existence some restrictions, for instance by considering ideal random close packing of monodisperse of elastic

Boyer, Edmond

193

An accurate elasto-plastic frictional tangential forcedisplacement model for granular-flow  

E-Print Network [OSTI]

An accurate elasto-plastic frictional tangential force­displacement model for granular for both elastic and plastic deformations together with interfacial friction occurring in collisions of spherical particles. This elasto-plastic frictional TFD model, with its force-driven version presented in [L

Vu-Quoc, Loc

194

The Impact of Test Suite Granularity on the CostEffectiveness of Regression Testing  

E-Print Network [OSTI]

The Impact of Test Suite Granularity on the Cost­Effectiveness of Regression Testing Gregg,pkallakug@cse.unl.edu ABSTRACT Regression testing is an expensive testing process used to validate software following modi#12;cations. The cost-e#11;ective- ness of regression testing techniques varies with characteris- tics of test

Rothermel, Gregg

195

The Impact of Test Suite Granularity on the Cost-Effectiveness of Regression Testing  

E-Print Network [OSTI]

The Impact of Test Suite Granularity on the Cost-Effectiveness of Regression Testing Gregg,pkallakug@cse.unl.edu ABSTRACT Regression testing is an expensive testing process used to validate software following modi cations. The cost-e ective- ness of regression testing techniques varies with characteris- tics of test

Rothermel, Gregg

196

The Impact of Test Suite Granularity on the CostEffectiveness of Regression Testing  

E-Print Network [OSTI]

The Impact of Test Suite Granularity on the Cost­Effectiveness of Regression Testing Gregg,pkallakug@cse.unl.edu ABSTRACT Regression testing is an expensive testing process used to validate software following modifications. The cost­effective­ ness of regression testing techniques varies with characteris­ tics of test

Rothermel, Gregg

197

Friction dependence of shallow granular flows from discrete par-ticle simulations  

E-Print Network [OSTI]

Friction dependence of shallow granular flows from discrete par- ticle simulations Anthony Thornton relation for the macroscopic bed friction or basal roughness obtained from micro-scale discrete particle simulations of steady flows. We systematically vary the bed friction by changing the contact friction

Al Hanbali, Ahmad

198

Spreading of a granular mass on a horizontal plane E. Lajeunesse  

E-Print Network [OSTI]

a of the granular cylinder pile, the properties of the underlying substrate smooth or rough, rigid or erodible properties or the bead size. Moreover the rescaled deposit radius, the rescaled spreading velocity surrounded by a less dense intergranular fluid such as water or gas.1,2 The volumetric concentration

Lajeunesse, Eric

199

Dynamic fracture of granular material under quasi-static loading Amir Sagy,1,2  

E-Print Network [OSTI]

Dynamic fracture of granular material under quasi-static loading Amir Sagy,1,2 Gil Cohen,3 Ze; published 13 April 2006. [1] The dynamics of rapid fracturing of heterogeneous grainy media are studied in laboratory experiments in which artificial rock slabs are fractured under uniaxial tension. By performing

Ze'ev, Reches

200

Reflection of Nonlinear Acoustic Waves from the Mechanically Free Surface of an Unconsolidated Granular Medium  

E-Print Network [OSTI]

1 Reflection of Nonlinear Acoustic Waves from the Mechanically Free Surface of an Unconsolidated a mechanically free surface of an unconsolidated granular layer under gravity is solved analytically using of the acoustic experiments directed to the investigation of fundamental mechanical properties of unconsolidated

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Study of Gas Flow Dynamics in Porous and Granular Media with Laser-Polarized 129  

E-Print Network [OSTI]

Abstract This thesis presents Nuclear Magnetic Resonance (NMR) studies of gas flow dynamics in porous in porous rock cores and the mass exchanges between different phases in fluidized granular systems, were-emulsion exchange and emulsion-adsorption exchange in a fluidized bed are two processes crucial to the efficiency

Walsworth, Ronald L.

202

Granular Matter (2007) 9:331335 DOI 10.1007/s10035-007-0045-3  

E-Print Network [OSTI]

magnetic resonance (NMR) experim- ents are described for gas-fluidized granular beds, which are important · Fluidized bed · NMR · Hyperpolarized gas 1 Introduction Nuclear magnetic resonance (NMR) enables noninvasive systems for many materials-processing operations. Using pulsed field gradient, magnetic resonance imaging

Walsworth, Ronald L.

2007-01-01T23:59:59.000Z

203

Granular temperature as an energy dissipation mechanism in bodies of the Solar System  

E-Print Network [OSTI]

Granular temperature as an energy dissipation mechanism in bodies of the Solar System BY JON KADISH Mary College, University of London, Mile End Road, London E1 4NS, UK There is theoretical grains to boulders. It is well known that energy added to such systems is dissipated by friction

Daly, Samantha

204

GSTP: A Temporal Reasoning System Supporting Multi-Granularity Temporal Constraints  

E-Print Network [OSTI]

and algorithms proposed in the literature for Temporal Constraint Satisfaction Problems (TCSP) have essentially granularity, so that some of the standard algorithms for CSP, like consistency checking through arc- or path adopting these conversions as the only tool to reduce the problem to a standard CSP is in- evitably

Mascetti, Sergio

205

ccsd00003870, Importance of convection in the compaction mechanisms of anisotropic granular media  

E-Print Network [OSTI]

the importance of compression waves propagation on granular compaction. PACS numbers: 45.70.Cc, 45.70.Mg, 83 consists of a glass cylinder of diameter D #25; 10 cm #12;lled with 600 g of grains (corre- sponding frequency f = 30 Hz. The resulting motion of the whole system, monitored by an accelerometer at the bottom

206

Experimental study of work exchange with a granular gas: the viewpoint of the Fluctuation Theorem.  

E-Print Network [OSTI]

and irreversible thermodynamics PACS 05.40.-a ­ Fluctuation phenomena, random processes, noise, and Brownian motion of the fluctuations of energy flux between a granular gas and a small driven harmonic oscillator. The DC-motor driving forcing, between the motor and the gas are examined from the viewpoint of the Fluctuation Theorem

Boyer, Edmond

207

A simplified model of thin layer static/flowing dynamics for granular materials with yield  

E-Print Network [OSTI]

/deposition processes when a layer of particles is flowing over a static layer or near the destabilization and arrestA simplified model of thin layer static/flowing dynamics for granular materials with yield, 75005 Paris, France, 4 ANGE team, INRIA, CETMEF, Lab. J.-L. Lions, Paris, France Abstract We introduce

Paris-Sud XI, Université de

208

Iron speciation and its biological availability in seawater: A workshop  

SciTech Connect (OSTI)

This workshop brought together marine chemists with expertise in iron chemistry and biologists with expertise in the role of iron in phytoplankton production to discuss controversies regarding the role of iron in oceanic primary productivity and global climatic change. A new paradigm for marine iron biogeochemistry was generated. The five major new items within this paradigm included (1) the nature of iron inputs to the sea, (2) chemical speciation of iron in seawater, (3) relationships between iron chemistry and marine microbial community dynamics, (4) adaptations of marine microbes to iron input, and (5) ecological and biogeochemical implications of changes in iron supply to the sea.

Wells, M.L.; Bruland, K.W.

1995-09-08T23:59:59.000Z

209

Pion Transverse Momentum Spectrum, Elliptic Flow and Interferometry in the Granular Source Model in Ultra-Relativistic Heavy Ion Collisions  

E-Print Network [OSTI]

We systematically investigate the pion transverse momentum spectrum, elliptic flow, and Hanbury-Brown-Twiss (HBT) interferometry in the granular source model of quark-gluon plasma droplets in ultra-relativistic heavy ion collisions. The granular source model can well reproduce the experimental results of the Au-Au collisions at $\\sqrt{s_{NN}}=$ 200 GeV and the Pb-Pb collisions at $\\sqrt{s_{NN}} =$ 2.76 TeV with different centralities. We examine the parameters of the granular source models with an uniform and Woods-Saxon initial energy distributions in a droplet. The parameters exhibit certain regularities for collision centrality and energy.

Yang, Jing; Zhang, Wei-Ning

2015-01-01T23:59:59.000Z

210

Dynamical properties of high-temperature-superconductor granular bridge junctions: Inhomogeneous Josephson-junction-array model  

SciTech Connect (OSTI)

As an attempt to understand the dynamical behavior of the high-temperature-superconductor (HTSC) granular bridge junction, we model the granular HTSC bridge junction consisting of many small grains inside by an inhomogeneous Josephson junction array, i.e., randomly arranged Josephson junction arrays (JJA). To describe randomly distributed critical currents between the grains inside the HTSC granular bridge junction, we chose various possible configurations in {l_brace}{ital I}{sub {ital ij}}{sup {ital c}}{r_brace} and {l_brace}{ital R}{sub {ital ij}}{r_brace} for the one-dimensional (1D) and 2D inhomogeneous Josephson junctions, and calculated the current-voltage ({ital IV}) characteristics and self-radiation spectral densities of the 1D and 2D inhomogeneous Josephson junctions. As a result, depending upon the distribution of critical currents and shunted resistances, it is found that there are large variations of {ital IV} characteristics. In contrast to the appearance of giant Shapiro steps in the regular ordered array, such Shapiro steps disappear in the case of the disordered JJA due to the increased randomness in the distribution of critical currents. On the contrary, however, when there exists a correlation between critical currents and resistances, i.e., a constant Josephson voltage, {ital I}{sub {ital ij}}{sup {ital c}}{ital R}{sub {ital ij}}={ital V}{sub {ital J}} (constant), the fundamental Shapiro step emerges despite the disordered distribution of {ital I}{sub {ital ij}}{sup {ital c}}. The relevance of this model to the HTSC granular bridge junctions is discussed. In particular, experimentally observed dynamical behaviors of the HTSC granular bridge junctions are shown to be closely related to the case of the correlated distribution with constant Josephson voltage. {copyright} {ital 1996 The American Physical Society.}

Lee, J.; Lee, S.; Yu, J.; Park, G. [Department of Physics, Sogang University, Seoul 121-742 (Korea)] [Department of Physics, Sogang University, Seoul 121-742 (Korea)

1996-02-01T23:59:59.000Z

211

Lithium Insertion Chemistry of Some Iron Vanadates  

E-Print Network [OSTI]

in A. Nazri, G.Pistoia (Eds. ), Lithium batteries, Science &structure materials in lithium cells, for a lower limitLithium Insertion Chemistry of Some Iron Vanadates Sébastien

Patoux, Sebastien; Richardson, Thomas J.

2008-01-01T23:59:59.000Z

212

Lithium Insertion Chemistry of Some Iron Vanadates  

E-Print Network [OSTI]

G.Pistoia (Eds. ), Lithium batteries, Science & Technology,Keywords: Lithium batteries, iron vanadates, insertionelectrode materials for lithium batteries, (mostly layered

Patoux, Sebastien; Richardson, Thomas J.

2008-01-01T23:59:59.000Z

213

Method for producing iron-based catalysts  

DOE Patents [OSTI]

A method for preparing an acid catalyst having a long shelf-life is provided comprising doping crystalline iron oxides with lattice-compatible metals and heating the now-doped oxide with halogen compounds at elevated temperatures. The invention also provides for a catalyst comprising an iron oxide particle having a predetermined lattice structure, one or more metal dopants for said iron oxide, said dopants having an ionic radius compatible with said lattice structure; and a halogen bound with the iron and the metal dopants on the surface of the particle.

Farcasiu, Malvina (Pittsburgh, PA); Kaufman, Phillip B. (Library, PA); Diehl, J. Rodney (Pittsburgh, PA); Kathrein, Hendrik (McMurray, PA)

1999-01-01T23:59:59.000Z

214

Nanostructure, Chemistry and Crystallography of Iron Nitride...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nanostructure, Chemistry and Crystallography of Iron Nitride Magnetic Materials by Ultra-High-Resolution Electron Microscopy and Related Methods Nanostructure, Chemistry and...

215

Characterization and Reactivity of Iron Nanoparticles Prepared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

as solute within the iron core of the HRCO particles. Kinetic batch experiments of carbon tetrachloride (CT) degradation were performed to quantitatively compare the redox...

216

Iron oxyhydroxide mineralization on microbial extracellular polysaccharides  

SciTech Connect (OSTI)

Iron biominerals can form in neutral pH microaerophilic environments where microbes both catalyze iron oxidation and create polymers that localize mineral precipitation. In order to classify the microbial polymers that influence FeOOH mineralogy, we studied the organic and mineral components of biominerals using scanning transmission X-ray microscopy (STXM), micro X-ray fluorescence ({mu}XRF) microscopy, and high-resolution transmission electron microscopy (HRTEM). We focused on iron microbial mat samples from a creek and abandoned mine; these samples are dominated by iron oxyhydroxide-coated structures with sheath, stalk, and filament morphologies. In addition, we characterized the mineralized products of an iron-oxidizing, stalk-forming bacterial culture isolated from the mine. In both natural and cultured samples, microbial polymers were found to be acidic polysaccharides with carboxyl functional groups, strongly spatially correlated with iron oxyhydroxide distribution patterns. Organic fibrils collect FeOOH and control its recrystallization, in some cases resulting in oriented crystals with high aspect ratios. The impact of polymers is particularly pronounced as the materials age. Synthesis experiments designed to mimic the biomineralization processes show that the polysaccharide carboxyl groups bind dissolved iron strongly but release it as mineralization proceeds. Our results suggest that carboxyl groups of acidic polysaccharides are produced by different microorganisms to create a wide range of iron oxyhydroxide biomineral structures. The intimate and potentially long-term association controls the crystal growth, phase, and reactivity of iron oxyhydroxide nanoparticles in natural systems.

Chan, Clara S.; Fakra, Sirine C.; Edwards, David C.; Emerson, David; Banfield, Jillian F.

2010-06-22T23:59:59.000Z

217

Electrodynamics in Iron and Steel  

E-Print Network [OSTI]

In order to calculate the reflected EM fields at low amplitudes in iron and steel, more must be understood about the nature of long wavelength excitations in these metals. A bulk piece of iron is a very complex material with microstructure, a split band structure, magnetic domains and crystallographic textures that affect domain orientation. Probing iron and other bulk ferromagnetic materials with weak reflected and transmitted inductive low frequency fields is an easy operation to perform but the responses are difficult to interpret because of the complexity and variety of the structures affected by the fields. First starting with a simple single coil induction measurement and classical EM calculation to show the error is grossly under estimating the measured response. Extending this experiment to measuring the transmission of the induced fields allows the extraction of three dispersion curves which define these internal fields. One dispersion curve yielded an exceedingly small effective mass of 1.8 10^{-39}kg (1.3 10^{-9} m_e) for those spin waves. There is a second distinct dispersion curve more representative of the density function of a zero momentum bound state rather than a propagating wave. The third dispersion curve describes a magneto-elastic coupling to a very long wave length propagating mode. These experiments taken together display the characteristics of a high temperature Bose-Einstein like condensation that can be initiated by pumping two different states. A weak time dependent field drives the formation of coupled J=0 spin wave pairs with the reduced effective mass reflecting the increased size of the coherent state. These field can dominate induction measurements well past the Curie temperature.

John Paul Wallace

2009-06-03T23:59:59.000Z

218

Oceanographic and ecological consequences of iron localization in phytoplankton photosystems  

E-Print Network [OSTI]

Y. Zhang, and K.W. Bruland. 1998. An iron limitation mosaicRue, J. Conn, and K.W. Bruland. 2002. Phytoplankton ironY. Zhang, and K.W. Bruland. 1998. An iron limitation mosaic

Hopkinson, Brian Matthew

2007-01-01T23:59:59.000Z

219

The production of iron carbide  

SciTech Connect (OSTI)

From start-up in 1994 to present, Nucor`s Iron Carbide plant has overcome many obstacles in achieving design production. Many of these impediments were due to flaws in equipment design. With the integration existing within the plant, limitations in any one system reduced the operating capacity of others. For this reason, as modifications were made and system capacities were increased, the need for additional modifications became apparent. Subsequently, operating practices, maintenance scheduling, employee incentives, and production objectives were continually adapted. This paper discusses equipment and design corrections and the quality issues that contributed to achieving the plant`s production capacity.

Anderson, K.M.; Scheel, J. [Nucor Iron Carbide, Inc., Point Lisas (Trinidad and Tobago)

1997-12-31T23:59:59.000Z

220

Subcritical compaction and yielding of granular quartz sand Stephen L. Karner*, Frederick M. Chester, Andreas K. Kronenberg, Judith S. Chester  

E-Print Network [OSTI]

Subcritical compaction and yielding of granular quartz sand Stephen L. Karner*, Frederick M October 2003 Abstract Cylindrical samples of water-saturated, initially loose, St. Peter quartz sand were

Chester, Frederick M.

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

A study of the effects of rate and frequency of loading on the stress-strain characteristics of granular soils  

E-Print Network [OSTI]

A STUDY OF THE EFFECTS OF RATE AND FREQUENCY OF LOADING ON THE STRESS-STRAIN CHARACTERISTICS OF GRANULAR SOILS A Thesis By James Clyde Armstrong Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1962 Major Subject: Civil Engineering A STUDY OF THE EFFECTS OF RATE AND FREQUENCY OF LOADING ON THE STRESS-STRAIN CHARACTERISTICS OF GRANULAR SOILS A Thesis By James Clyde...

Armstrong, James Clyde

1962-01-01T23:59:59.000Z

222

Electrochemical Studies of Packed Iron Powder Electrodes: Effects...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Packed Iron Powder Electrodes: Effects of Common Constituents of Natural Waters on Corrosion Electrochemical Studies of Packed Iron Powder Electrodes: Effects of Common...

223

Preparations of rare earth-iron alloys by thermite reduction  

DOE Patents [OSTI]

An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA)

1986-09-16T23:59:59.000Z

224

Watermelon-like iron nanoparticles: Cr doping effect on magnetism...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Watermelon-like iron nanoparticles: Cr doping effect on magnetism and magnetization interaction reversal. Watermelon-like iron nanoparticles: Cr doping effect on magnetism and...

225

Influence of Iron Redox Transformations on Plutonium Sorption...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation...

226

Atomistic Simulations of Uranium Incorporation into Iron (Hydr...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Uranium Incorporation into Iron (Hydr)Oxides. Atomistic Simulations of Uranium Incorporation into Iron (Hydr)Oxides. Abstract: Atomistic simulations were carried out to...

227

Microbial Reduction of Uranium under Iron- and Sulfate-reducing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uranium under Iron- and Sulfate-reducing Conditions: Effect of Amended Goethite on Microbial Community Microbial Reduction of Uranium under Iron- and Sulfate-reducing Conditions:...

228

Formation of iron complexs from trifluoroacetic acid based liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of iron complexs from trifluoroacetic acid based liquid chromatography mobile phases as interference ions in liquid Formation of iron complexs from trifluoroacetic acid based...

229

Bioreduction of hematite nanoparticles by the dissimilatory iron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanoparticles by the dissimilatory iron reducing bacterium Shewanella oneidensis MR-1. Bioreduction of hematite nanoparticles by the dissimilatory iron reducing bacterium...

230

Manufacturing Energy and Carbon Footprint - Sector: Iron and...  

Broader source: Energy.gov (indexed) [DOE]

Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006) Manufacturing Energy and Carbon Footprint - Sector: Iron and Steel (NAICS 3311, 3312), October 2012 (MECS 2006)...

231

Morphology and Oxide Shell Structure of Iron Nanoparticles Grown...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxide Shell Structure of Iron Nanoparticles Grown by Sputter-Gas-Aggregation. Morphology and Oxide Shell Structure of Iron Nanoparticles Grown by Sputter-Gas-Aggregation. Abstract:...

232

Dechlorination of TCE with palladized iron  

DOE Patents [OSTI]

The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from various effluents or contaminated soil containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products.

Fernando, Quintus (Tucson, AZ); Muftikian, Rosy (Tucson, AZ); Korte, Nic (Grand Junction, CO)

1997-01-01T23:59:59.000Z

233

Production of iron from metallurgical waste  

DOE Patents [OSTI]

A method of recovering metallic iron from iron-bearing metallurgical waste in steelmaking comprising steps of providing an iron-bearing metallurgical waste containing more than 55% by weight FeO and FeO equivalent and a particle size of at least 80% less than 10 mesh, mixing the iron-bearing metallurgical waste with a carbonaceous material to form a reducible mixture where the carbonaceous material is between 80 and 110% of the stoichiometric amount needed to reduce the iron-bearing waste to metallic iron, and as needed additions to provide a silica content between 0.8 and 8% by weight and a ratio of CaO/SiO.sub.2 between 1.4 and 1.8, forming agglomerates of the reducible mixture over a hearth material layer to protect the hearth, heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic iron and slag material from the agglomerates by melting.

Hendrickson, David W; Iwasaki, Iwao

2013-09-17T23:59:59.000Z

234

Introduction Southern Ocean natural iron fertilization  

E-Print Network [OSTI]

led to immediate localized phytoplankton blooms. They also have stimulated con- siderable speculation processes motivated three field programs in 2004­ 2006. The United Kingdom led the "CROZet natural iron into surface waters, recycling of nutrients, reactivity of iron, and phytoplankton physiology. This special

235

Stratification, segregation and mixing of granular materials in quasi-2D bounded heaps  

E-Print Network [OSTI]

Segregation and mixing of granular mixtures during heap formation have important consequences in industry and agriculture. This research investigates three different final particle configurations of bi-disperse granular mixtures -- stratified, segregated and mixed -- during filling of quasi-two dimensional silos. We consider a larger number and relatively wider range of control parameters than previous studies, including particle size ratio, flow rate, system size and heap rise velocity. The boundary between stratified and unstratified states is primarily controlled by the two-dimensional flow rate, with the critical flow rate for the transition depending weakly on particle size ratio and flowing layer length. In contrast, the transition from segregated to mixed states is controlled by the rise velocity of the heap, a control parameter not previously considered. The critical rise velocity for the transition depends strongly on the particle size ratio.

Yi Fan; Youcef Boukerkour; Thibault Blanc; Paul B. Umbanhowar; Julio M. Ottino; Richard M. Lueptow

2012-09-25T23:59:59.000Z

236

Modeling energy dissipation induced by quasi-static compaction of granular HMX  

SciTech Connect (OSTI)

A simple extension of a conventional two-phase continuum model of Deflagration-to-Detonation Transition (DDT) in energetic granular material is given to account for energy dissipation induced by quasi-static compaction. To this end, the conventional model equations are supplemented by a relaxation equation that accounts for irreversible changes in solid volume fraction due to intergranular friction, plastic deformation of granules, and granule fracture. The proposed model, which is consistent with the Second Law of Thermodynamics for a two-phase mixture, is demonstrated by applying it to the quasi-static compaction of granular HMX. The model predicts results commensurate with experimental data including stress relaxation and substantial dissipation; such phenomena have not been previously accounted for by two-phase DDT models. {copyright} {ital 1998 American Institute of Physics.}

Gonthier, K.A.; Menikoff, R.; Son, S.F.; Asay, B.W. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

1998-07-01T23:59:59.000Z

237

Mechanical properties of granular materials: A variational approach to grain-scale simulations  

SciTech Connect (OSTI)

The mechanical properties of cohesionless granular materials are evaluated from grain-scale simulations. A three-dimensional pack of spherical grains is loaded by incremental displacements of its boundaries. The deformation is described as a sequence of equilibrium configurations. Each configuration is characterized by a minimum of the total potential energy. This minimum is computed using a modification of the conjugate gradient algorithm. Our simulations capture the nonlinear, path-dependent behavior of granular materials observed in experiments. Micromechanical analysis provides valuable insight into phenomena such as hysteresis, strain hardening and stress-induced anisotropy. Estimates of the effective bulk modulus, obtained with no adjustment of material parameters, are in agreement with published experimental data. The model is applied to evaluate the effects of hydrate dissociation in marine sediments. Weakening of the sediment is quantified as a reduction in the effective elastic moduli.

Holtzman, R.; Silin, D.B.; Patzek, T.W.

2009-01-15T23:59:59.000Z

238

The path to fracture in granular flows: dynamics of contact networks  

E-Print Network [OSTI]

Capturing the dynamics of granular flows at intermediate length scales can often be difficult. We propose studying the dynamics of contact networks as a new tool to study fracture at intermediate scales. Using experimental three-dimensional flow fields with particle-scale resolution, we calculate the time evolving broken-links network and find that a giant component of this network is formed as shear is applied to this system. We implement a model of link breakages where the probability of a link breaking is proportional to the average rate of longitudinal strain (elongation) in the direction of the edge and find that the model demonstrates qualitative agreement with the data when studying the onset of the giant component. We note, however, that the broken-links network formed in the model is less clustered than our experimental observations, indicating that the model reflects less localized breakage events and does not fully capture the dynamics of the granular flow.

Mark Herrera; Shane McCarthy; Steven Slotterback; Emmanuel Cephas; Wolfgang Losert; Michelle Girvan

2011-06-27T23:59:59.000Z

239

Simulation Study of Internal and Surface waves of Vertically Vibrated Granular Materials  

E-Print Network [OSTI]

Molecular dynamical (MD) simulations are performed to simulate two dimensional vibrofluidized granular materials in this work. Statistics on simulation results indicate that there exist shocks propagating upward in each vibrating cycle. Under certain driving parameters surface waves similar to Faraday instability in normal fluid coexist with internal waves. Relationship between the two kinds of waves is explored. Moreover simulation results indicate that periodically structured bottom can change the dispersion relationship and amplitude of surface waves.

Kai Huang; Guoqing Miao; Peng Zhang; Yifei Zhu; Rongjue Wei

2005-11-29T23:59:59.000Z

240

Depth-Independent Drag Force Induced by Stirring in Granular Media Francois Guillard,* Yoel Forterre,  

E-Print Network [OSTI]

may be used to drill deeply in a granular medium without developing high torques. DOI: 10.1103/PhysRevLett.110.138303 PACS numbers: 47.57.Gc, 45.20.da, 45.70.Ã?n In fluid mechanics, the problem of the forces experi- enced by an object moving in a fluid has been extensively studied. Whereas most investigations

Boyer, Edmond

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Deformation-Driven Diffusion and Plastic Flow in Two-Dimensional Amorphous Granular Pillars  

E-Print Network [OSTI]

We report a combined experimental and simulation study of deformation-induced diffusion in compacted two-dimensional amorphous granular pillars, in which thermal fluctuations play negligible role. The pillars, consisting of bidisperse cylindrical acetal plastic particles standing upright on a substrate, are deformed uniaxially and quasistatically by a rigid bar moving at a constant speed. The plastic flow and particle rearrangements in the pillars are characterized by computing the best-fit affine transformation strain and non-affine displacement associated with each particle between two stages of deformation. The non-affine displacement exhibits exponential crossover from ballistic to diffusive behavior with respect to the cumulative deviatoric strain, indicating that in athermal granular packings, the cumulative deviatoric strain plays the role of time in thermal systems and drives effective particle diffusion. We further study the size-dependent deformation of the granular pillars by simulation, and find that different-sized pillars follow self-similar shape evolution during deformation. In addition, the yield stress of the pillars increases linearly with pillar size. Formation of transient shear lines in the pillars during deformation becomes more evident as pillar size increases. The width of these elementary shear bands is about twice the diameter of a particle, and does not vary with pillar size.

Wenbin Li; Jennifer M. Rieser; Andrea J. Liu; Douglas J. Durian; Ju Li

2015-02-04T23:59:59.000Z

242

Rheology of weakly wetted granular materials - a comparison of experimental and numerical data  

E-Print Network [OSTI]

Shear cell simulations and experiments of weakly wetted particles (a few volume percent liquid binders) are compared, with the goal to understand their flow rheology. Application examples are cores for metal casting by core shooting made of sand and liquid binding materials. The experiments are carried out with a Couette-like rotating viscometer. The weakly wetted granular materials are made of quartz sand and small amounts of Newtonian liquids. For comparison, experiments on dry sand are also performed with a modified configuration of the viscometer. The numerical model involves spherical, monodisperse particles with contact forces and a simple liquid bridge model for individual capillary bridges between two particles. Different liquid content and properties lead to different flow rheology when measuring the shear stress-strain relations. In the experiments of the weakly wetted granular material, the apparent shear viscosity $\\eta_g$ scales inversely proportional to the inertial number $I$, for all shear rates. On the contrary, in the dry case, an intermediate scaling regime inversely quadratic in $I$ is observed for moderate shear rates. In the simulations, both scaling regimes are found for dry and wet granular material as well.

Ruediger Schwarze; Anton Gladkyy; Fabian Uhlig; Stefan Luding

2014-09-12T23:59:59.000Z

243

Moving granular-bed filter development program topical report. Base contract test plan  

SciTech Connect (OSTI)

The Westinghouse Science & Technology Center has proposed a novel moving granular-bed filter concept, the Standleg Moving Granular-Bed Filter (S-MGBF) system, that overcomes the inherent deficiencies of the current state-of-the-art moving granular-bed filter technology. The S-MGBF system combines two unique features that make it highly effective for use in advanced coal-fueled power plants. First, the S-MGBF system applies pelletization technology to generate filter pellets from the power plant solid waste materials, and uses these pellets as a ``once-through`` filtering media to eliminate the need for costly, complex, and large filter media recycling equipment. This pelletizing step also generates a more environmentally acceptable solid waste product and provides the potential to incorporate gas-phase contaminant sorbents into the filtering media. Secondly, the S-MGBF system passes these pellets and the flyash laden power plant gas through a highly compact S-MGBF that uses cocurrent gas-pellet contacting in an arrangement that greatly simplifies and enhances the distribution of dirty gas to the moving bed and the disengagement of clean gas from the moving bed.

Newby, R.A.; Dilmore, W.J.; Fellers, A.W.; Gasparovic, A.C.; Kittle, W.F.; Lippert, T.E.; Smeltzer, E.E.; Yang, W.C.

1991-10-17T23:59:59.000Z

244

Evidence for Localization of Reaction Upon Reduction of Carbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Localization of Reaction Upon Reduction of Carbon Tetrachloride by Granular Iron. Evidence for Localization of Reaction Upon Reduction of Carbon Tetrachloride by Granular Iron....

245

2iron-based superconductors  

SciTech Connect (OSTI)

We measured the static uniform spin susceptibility of Ba(Fe1?xRhx)2As2 iron-based superconductors, over a broad range of doping (0.041x0.094) and magnetic fields. At small fields (H1kOe) we observed, above the transition temperature Tc, the occurrence of precursor diamagnetism, which is not ascribable to the Ginzburg–Landau theory. On the contrary, our data agree with a phase fluctuation model, which has been used to interpret a similar phenomenology occurring in the high- Tc cuprate superconductors. Additionally, in the presence of strong fields, the unconventional fluctuating diamagnetism is suppressed, whereas Ginzburg–Landau fluctuations are found, in agreement with literature.

Bossoni, L [University of Pavia-CNISM; Romano, L [University of Parma, Parco Area dell Scienze; Canfield, Paul C [Ames Laboratory; Lascialfari, A [Universita degli Studi di Milano

2014-10-08T23:59:59.000Z

246

Realization and Tests of the Highly Granular CALICE Engineering Calorimeter Prototypes, 15th International Conference on Calorimetry in High Energy Physics  

E-Print Network [OSTI]

Realization and Tests of the Highly Granular CALICE Engineering Calorimeter Prototypes, 15th International Conference on Calorimetry in High Energy Physics

The CALICE Collaboration

2015-01-01T23:59:59.000Z

247

Iron-air battery development program  

SciTech Connect (OSTI)

The progress and status of the research and development program on the iron-air advanced technology battery system at the Westinghouse Electric Corporation during the period June 1978-December 1979 are described. This advanced battery system is being developed for electric vehicle propulsion applications. Testing and evaluation of 100 cm/sup 2/ size cells was undertaken while individual iron and air electrode programs continued. Progress is reported in a number of these study areas. Results of the improvements made in the utilization of the iron electrode active material coupled with manufacturing and processing studies related to improved air electrodes continue to indicate that a fully developed iron-air battery system will be capable of fulfilling the performance requirements for commuter electric vehicles.

Buzzelli, E.S.; Liu, C.T.; Bryant, W.A.

1980-05-01T23:59:59.000Z

248

System and method for producing metallic iron  

DOE Patents [OSTI]

A method of production of metallic iron nodules comprises assembling a hearth furnace having a moveable hearth comprising refractory material and having a conversion zone and a fusion zone, providing a hearth material layer comprising carbonaceous material on the refractory material, providing a layer of reducible material comprising and iron bearing material arranged in discrete portions over at least a portion of the hearth material layer, delivering oxygen gas into the hearth furnace to a ratio of at least 0.8:1 ponds of oxygen to pounds of iron in the reducible material to heat the conversion zone to a temperature sufficient to at least partially reduce the reducible material and to heat the fusion zone to a temperature sufficient to at least partially reduce the reducible material, and heating the reducible material to form one or more metallic iron nodules and slag.

Englund, David J.; Schlichting, Mark; Meehan, John; Crouch, Jeremiah; Wilson, Logan

2014-07-29T23:59:59.000Z

249

Thermal transport properties of grey cast irons  

SciTech Connect (OSTI)

Thermal diffusivity and thermal conductivity of grey cast iron have been measured as a function of graphite flake morphology, chemical composition, and position in a finished brake rotor. Cast iron samples used for this investigation were cut from ``step block`` castings designed to produce iron with different graphite flake morphologies resulting from different cooling rates. Samples were also machined from prototype alloys and from production brake rotors representing a variation in foundry practice. Thermal diffusivity was measured at room and elevated temperatures via the flash technique. Heat capacity of selected samples was measured with differential scanning calorimetry, and these results were used to calculate the thermal conductivity. Microstructure of the various cast iron samples was quantified by standard metallography and image analysis, and the chemical compositions were determined by optical emission spectroscopy.

Hecht, R.L. [Ford Motor Co., Dearborn, MI (United States). Ford Research Lab.; Dinwiddie, R.B.; Porter, W.D.; Wang, Hsin [Oak Ridge National Lab., TN (United States)

1996-10-01T23:59:59.000Z

250

Iron and the ecology of marine microbes  

E-Print Network [OSTI]

Iron is a cofactor of a number biochemical reactions that are essential for life. In the marine environment, this micronutrient is a scarce resource that limits processes of global importance such as photosynthesis and ...

Ventouras, Laure-Anne

2013-01-01T23:59:59.000Z

251

Dechlorination of TCE with palladized iron  

DOE Patents [OSTI]

The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from various effluents or contaminated soil containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. 10 figs.

Fernando, Q.; Muftikian, R.; Korte, N.

1997-04-01T23:59:59.000Z

252

Elastic moduli of nickel and iron aluminides  

E-Print Network [OSTI]

ELASTIC MODULI OF NICKEL AND IRON ALUMINIDES A Thesis by SREEDHAR MAN JIGANI Submitted to the Oifice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1993... Major Subject: Mechanical Engineering ELASTIC MODULI OF NICKEL AND IRON ALUMINIDES A Thesis by SREEDHAR MAN JIGANI Submitted to Texas AkM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved...

Manjigani, Sreedhar

2012-06-07T23:59:59.000Z

253

IEA Energy conservation in the iron and steel industry. [US and Western Europe  

SciTech Connect (OSTI)

The NATO Committee on the Challenges of Modern Society research program, under the auspices of the IEA, had the objectives of collecting data on material requirements and energy-consumption patterns in selected energy-intensive industries in the US and Western Europe, of identifying technologies and operating practices with the potential for energy conservation in those industries, and of recommending research projects that could lead to improved energy efficiency. The steel industry was selected for analysis and ideas for an international cooperative program were developed. Representatives from various countries conducted meetings and the form of an implementing agreement for a research and development program was finalized in December, 1980. The program includes three technical areas: hot-surface inspection, heat recovery, and coal gasification. Hot-surface inspection methods to be demonstrated are: optical, induction, electromagnetic ultrasonic, electromagnetic ultrasonic surface testing methods, and eddy current method for hot surface inspection and an infrared system (possibly). Three heat-recovery projects are: ceramic heat wheel development; demonstration of granular bed/heat pipe system for heat recovery; and demonstration of tubular ceramic recuperators. Processes in coal gasification are: converter process, gas treatment, and iron treatment. Each project is described in detail. (MCW)

Tunnah, B.G.

1981-01-01T23:59:59.000Z

254

Moving granular-bed filter development program, Option III: Development of moving granular-bed filter technology for multi-contaminant control. Task 14: Test plan; Topical report  

SciTech Connect (OSTI)

An experimental test plan has been prepared for DOE/METC review and approval to develop a filter media suitable for multi-contaminant control in granular-bed filter (GBF) applications. The plan includes identification, development, and demonstration of methods for enhanced media morphology, chemical reactivity, and mechanical strength. The test plan includes media preparation methods, physical and chemical characterization methods for fresh and reacted media, media evaluation criteria, details of test and analytical equipment, and test matrix of the proposed media testing. A filter media composed of agglomerated limestone and clay was determined to be the best candidate for multi-contaminate control in GBF operation. The combined limestone/clay agglomerate has the potential to remove sulfur and alkali species, in addition to particulate, and possibly halogens and trace heavy metals from coal process streams.

Haas, J.C.; Olivo, C.A.; Wilson, K.B.

1994-04-01T23:59:59.000Z

255

A theoretical model for the x-ray luminescence of granular phosphor G. E. Giakoumakis, M. C. Katsarioti, and I. E. Lagaris  

E-Print Network [OSTI]

A theoretical model for the x-ray luminescence of granular phosphor screens G. E. Giakoumakis, M. C-ray luminescence of a phosphor screen is presented. The model takes into account the granular structure of the screen and the random deposition of the phosphor grains on the screen substrate. Results based

Lagaris, Isaac

256

A Comparison of Iron and Steel Production Energy Intensity in China and the U.S  

E-Print Network [OSTI]

of Iron and Steel Production Energy Use and Energy Intensityof Iron and Steel Production Energy Intensity in China andof Iron and Steel Production Energy Intensity in China and

Price, Lynn

2014-01-01T23:59:59.000Z

257

E-Print Network 3.0 - assembly cellular iron Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , iron storage function and cellular regulation. Biochim. Biophys. Acta Bioenerg. 1275: 161-203. HOFMANN... Availability of iron from iron-storage proteins to marine...

258

Effect of different intravenous iron preparations on lymphocyte intracellular reactive oxygen species generation and subpopulation survival.  

E-Print Network [OSTI]

IV iron compounds induced greater intracellular ROS generation,IV iron preparations on intracellular reactive oxygen species generationIV iron preparations on intracellular immune cell ROS generation

Gupta, Ajay; Zhuo, Jiaying; Zha, Junli; Reddy, Srinivasa; Olp, Jonathan; Pai, Amy

2010-01-01T23:59:59.000Z

259

Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas  

SciTech Connect (OSTI)

Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

Lee, S.H.D.; Swift, W.M.; Johnson, I.

1980-01-01T23:59:59.000Z

260

Testing Hadronic Interaction Models using a Highly Granular Silicon-Tungsten Calorimeter  

E-Print Network [OSTI]

A detailed study of hadronic interactions is presented using data recorded with the highly granular CALICE silicon-tungsten electromagnetic calorimeter. Approximately 600,000 selected negatively changed pion events at energies between 2 and 10 GeV have been studied. The predictions of several physics models available within the GEANT4 simulation tool kit are compared to this data. Although a reasonable overall description of the data is observed, there are significant quantitative discrepancies in the longitudinal and transverse distributions of reconstructed energy.

Bilki, B; Schlereth, J; Xia, L; Deng, Z; Li, Y; Wang, Y; Yue, Q; Yang, Z; Eigen, G; Mikami, Y; Price, T; Watson, N K; Thomson, M A; Ward, D R; Benchekroun, D; Hoummada, A; Khoulaki, Y; Cârloganu, C; Chang, S; Khan, A; Kim, D H; Kong, D J; Oh, Y D; Blazey, G C; Dyshkant, A; Francis, K; Lima, J G R; Salcido, P; Zutshi, V; Boisvert, V; Green, B; Misiejuk, A; Salvatore, F; Kawagoe, K; Miyazaki, Y; Sudo, Y; Suehara, T; Tomita, T; Ueno, H; Yoshioka, T; Apostolakis, J; Folger, G; Ivantchenko, V; Ribon, A; Uzhinskiy, V; Cauwenbergh, S; Tytgat, M; Zaganidis, N; Hostachy, J -Y; Morin, L; Gadow, K; Göttlicher, P; Günter, C; Krüger, K; Lutz, B; Reinecke, M; Sefkow, F; Feege, N; Garutti, E; Laurien, S; Lu, S; Marchesini, I; Matysek, M; Ramilli, M; Kaplan, A; Norbeck, E; Northacker, D; Onel, Y; Kim, E J; van Doren, B; Wilson, G W; Wing, M; Bobchenko, B; Chadeeva, M; Chistov, R; Danilov, M; Drutskoy, A; Epifantsev, A; Markin, O; Mizuk, R; Novikov, E; Popov, V; Rusinov, V; Tarkovsky, E; Besson, D; Popova, E; Gabriel, M; Kiesling, C; Simon, F; Soldner, C; Szalay, M; Tesar, M; Weuste, L; Amjad, M S; Bonis, J; Callier, S; di Lorenzo, S Conforti; Cornebise, P; Doublet, Ph; Dulucq, F; Faucci-Giannelli, M; Fleury, J; Frisson, T; Kégl, B; van der Kolk, N; Li, H; Martin-Chassard, G; Richard, F; de la Taille, Ch; Pöschl, R; Raux, L; Rouëné, J; Seguin-Moreau, N; Anduze, M; Balagura, V; Becheva, E; Boudry, V; Brient, J-C; Cornat, R; Frotin, M; Gastaldi, F; Magniette, F; Matthieu, A; de Freitas, P Mora; Videau, H; Augustin, J-E; David, J; Ghislain, P; Lacour, D; Lavergne, L; Zacek, J; Cvach, J; Gallus, P; Havranek, M; Janata, M; Kvasnicka, J; Lednicky, D; Marcisovsky, M; Polak, I; Popule, J; Tomasek, L; Tomasek, M; Ruzicka, P; Sicho, P; Smolik, J; Vrba, V; Zalesak, J; Jeans, D; Götze, M

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Testing Hadronic Interaction Models using a Highly Granular Silicon-Tungsten Calorimeter  

E-Print Network [OSTI]

A detailed study of hadronic interactions is presented using data recorded with the highly granular CALICE silicon-tungsten electromagnetic calorimeter. Approximately 600,000 selected negatively changed pion events at energies between 2 and 10 GeV have been studied. The predictions of several physics models available within the GEANT4 simulation tool kit are compared to this data. Although a reasonable overall description of the data is observed, there are significant quantitative discrepancies in the longitudinal and transverse distributions of reconstructed energy.

The CALICE Collaboration; B. Bilki; J. Repond; J. Schlereth; L. Xia; Z. Deng; Y. Li; Y. Wang; Q. Yue; Z. Yang; G. Eigen; Y. Mikami; T. Price; N. K. Watson; M. A. Thomson; D. R. Ward; D. Benchekroun; A. Hoummada; Y. Khoulaki; C. Cârloganu; S. Chang; A. Khan; D. H. Kim; D. J. Kong; Y. D. Oh; G. C. Blazey; A. Dyshkant; K. Francis; J. G. R. Lima; P. Salcido; V. Zutshi; V. Boisvert; B. Green; A. Misiejuk; F. Salvatore; K. Kawagoe; Y. Miyazaki; Y. Sudo; T. Suehara; T. Tomita; H. Ueno; T. Yoshioka; J. Apostolakis; G. Folger; G. Folger; V. Ivantchenko; A. Ribon; V. Uzhinskiy; S. Cauwenbergh; M. Tytgat; N. Zaganidis; J. -Y. Hostachy; L. Morin; K. Gadow; P. Göttlicher; C. Günter; K. Krüger; B. Lutz; M. Reinecke; F. Sefkow; N. Feege; E. Garutti; S. Laurien; S. Lu; I. Marchesini; M. Matysek; M. Ramilli; A. Kaplan; E. Norbeck; D. Northacker; Y. Onel; E. J. Kim; B. van Doren; G. W. Wilson; M. Wing; B. Bobchenko; M. Chadeeva; R. Chistov; M. Danilov; A. Drutskoy; A. Epifantsev; O. Markin; R. Mizuk; E. Novikov; V. Popov; V. Rusinov; E. Tarkovsky; D. Besson; E. Popova; M. Gabriel; C. Kiesling; F. Simon; C. Soldner; M. Szalay; M. Tesar; L. Weuste; M. S. Amjad; J. Bonis; S. Callier; S. Conforti di Lorenzo; P. Cornebise; Ph. Doublet; F. Dulucq; M. Faucci-Giannelli; J. Fleury; T. Frisson; B. Kégl; N. van der Kolk; H. Li; G. Martin-Chassard; F. Richard; Ch. de la Taille; R. Pöschl; L. Raux; J. Rouëné; N. Seguin-Moreau; M. Anduze; V. Balagura; E. Becheva; V. Boudry; J-C. Brient; R. Cornat; M. Frotin; F. Gastaldi; F. Magniette; A. Matthieu; P. Mora de Freitas; H. Videau; J-E. Augustin; J. David; P. Ghislain; D. Lacour; L. Lavergne; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; J. Kvasnicka; D. Lednicky; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; D. Jeans; M. Götze

2014-11-26T23:59:59.000Z

262

Critical behavior of two freely evolving granular gases separated by an adiabatic piston  

E-Print Network [OSTI]

Two granular gases separated by an adiabatic piston and initially in the same macroscopic state are considered. It is found that a phase transition with an spontaneous symmetry breaking occurs. When the mass of the piston is increased beyond a critical value, the piston moves to a stationary position different from the middle of the system. The transition is accurately described by a simple kinetic model that takes into account the velocity fluctuations of the piston. Interestingly, the final state is not characterized by the equality of the temperatures of the subsystems but by the cooling rates being the same. Some relevant consequences of this feature are discussed.

J. Javier Brey; Nagi Khalil

2010-09-23T23:59:59.000Z

263

The jamming surface of granular matter determined from soil mechanics results  

E-Print Network [OSTI]

Classical soil mechanics results are used to propose the equation of the jamming transition surface in the (stress, specific volume) space. Taking axis-ymmetric conditions, labelling q the deviatoric stress and p' the mean pressure applied on the granular skeleton, and considering normal range of pressure (10 kPa-10MPa) the equation of the surface of jamming transition is v = vo-m ln(p'/p'o)+ md ln(1+q q/(M' M' p' p')); M' is related to the friction angle, m and md are two constants which depend on soil characteristics; p'o is a "unit" pressure.

P. Evesque

2005-06-17T23:59:59.000Z

264

Strain versus stress in a model granular material: a Devil's staircase  

E-Print Network [OSTI]

The series of equilibrium states reached by disordered packings of rigid, frictionless discs in two dimensions, under gradually varying stress, are studied by numerical simulations. Statistical properties of trajectories in configuration space are found to be independent of specific assumptions ruling granular dynamics, and determined by geometry only. A monotonic increase in some macroscopic loading parameter causes a discrete sequence of rearrangements. For a biaxial compression, we show that, due to the statistical importance of such events of large magnitudes, the dependence of the resulting strain on stress direction is a Levy flight in the thermodynamic limit.

Gael Combe; Jean-Noel Roux

2000-04-05T23:59:59.000Z

265

Iron speciation in urban dust  

SciTech Connect (OSTI)

An improved understanding of anthropogenic impacts on ocean fertility requires knowledge of anthropogenic dust mineralogy and associated Fe speciation as a critical step toward developing Fe solubility models constrained by mineralogical composition. This study explored the utility of micro-focused X-ray absorption spectroscopy ({mu}-XAS) in characterizing the speciation of Fe in urban dust samples. A micro-focused beam of 10 x 7 {mu}m made possible the measurement of the Fe K edge XAS spectra of individual dust particles in the PM5.6 size fraction collected in Newark, New Jersey, USA. Spectral analysis indicated the presence of mixtures of Fe-containing minerals within individual dust particles; we observed significant magnetite content along with other Fe(III)-(hydr)oxide minerals which could not be conclusively identified. Our data indicate that detailed quantitative determination of Fe speciation requires extended energy scans to constrain the types and relative abundance of Fe species present. We observe heterogeneity in Fe speciation at the dust particle level, which underscores the importance of analyzing a statistically adequate number of particles within each dust sample. Where possible, {mu}-XAS measurements should be complemented with additional characterization techniques such as {mu}-XRD and bulk XAS to obtain a comprehensive picture of the Fe speciation in dust materials. X-ray microprobes should be used to complement bulk methods used to determine particle composition, methods that fail to record particle heterogeneity. Keywords - Urban dust; Iron; Speciation; Micro-focused X-ray absorption spectroscopy.

Elzinga, E.J.; Fitts, J.; Gao, Y.; Tappero, R.

2011-08-01T23:59:59.000Z

266

Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion  

SciTech Connect (OSTI)

Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

Shen, M.; Yang, R.T.

1980-09-30T23:59:59.000Z

267

Analysis of Granular Flow in a Pebble-Bed Nuclear Reactor  

E-Print Network [OSTI]

Pebble-bed nuclear reactor technology, which is currently being revived around the world, raises fundamental questions about dense granular flow in silos. A typical reactor core is composed of graphite fuel pebbles, which drain very slowly in a continuous refueling process. Pebble flow is poorly understood and not easily accessible to experiments, and yet it has a major impact on reactor physics. To address this problem, we perform full-scale, discrete-element simulations in realistic geometries, with up to 440,000 frictional, viscoelastic 6cm-diameter spheres draining in a cylindrical vessel of diameter 3.5m and height 10m with bottom funnels angled at 30 degrees or 60 degrees. We also simulate a bidisperse core with a dynamic central column of smaller graphite moderator pebbles and show that little mixing occurs down to a 1:2 diameter ratio. We analyze the mean velocity, diffusion and mixing, local ordering and porosity (from Voronoi volumes), the residence-time distribution, and the effects of wall friction and discuss implications for reactor design and the basic physics of granular flow.

Chris H. Rycroft; Gary S. Grest; James W. Landry; Martin Z. Bazant

2006-02-16T23:59:59.000Z

268

Moving Bed, Granular Bed Filter Development Program: Option 1, Component Test Facility. Task 3, Test plan  

SciTech Connect (OSTI)

In the base contract, Combustion Power Co. developed commercial designs for a moving granular-bed filter (GBF). The proposed filter is similar to previous designs in terms of its shape and method of filtration. The commercial designs have scaled the filter from a 5 ft diameter to as large as a 20 ft diameter filter. In Task 2 of the Moving Bed-Granular Filter Development Program, all technical concerns related to the further development of the filter are identified. These issues are discussed in a Topical Report which has been issued as part of Task 2. Nineteen issues are identified in this report. Along with a discussion of these issues are the planned approaches for resolving each of these issues. These issues will be resolved in either a cold flow component test facility or in pilot scale testing at DOE`s Power System Development Facility (PSDF) located at Southem Company Services` Wilsonville facility. Task 3 presents a test plan for resolving those issues which can be addressed in component test facilities. The issues identified in Task 2 which will be addressed in the component test facilities are: GBF scale-up; effect of filter cone angle and sidewall materials on medium flow and ash segregation; maximum gas filtration rate; lift pipe wear; GBF media issues; mechanical design of the gas inlet duct; and filter pressure drop. This document describes a test program to address these issues, with testing to be performed at Combustion Power Company`s facility in Belmont, California.

Haas, J.C.; Purdhomme, J.W.; Wilson, K.B.

1994-04-01T23:59:59.000Z

269

Effective thermal conductivity for anisotropic granular porous media using fractal concepts  

SciTech Connect (OSTI)

The use of granular porous media in chemical processes, thermal insulation, heat exchangers, and nuclear reactor fuel rods has led to the development of correlations for thermophysical properties, such as thermal conductivity. These correlations are essential in the prediction of heat and mass transfer involving porous media. Analytical correlations are derived for the effective thermal conductivity of anisotropic, Granular Porous Media (GPM). The correlations proposed, which can be apply in general to any porous media material, are used to determine the effective thermal conductivity of GPM that are formed by semi-cylindrical ice particles. Pictures of the cross-section of GPM provide digital data for measuring local fractal dimensions. Local fractal dimensions are used to determine an equivalent three-dimensional Representative Unit Cell (RUC) for the GPM considered. A simplified analysis of heat conduction at the RUC level provide an analytical expression for the effective heat transfer coefficient. Estimates for the effective thermal conductivity by the use of the models are discussed and compared with various models known in literature. Finally, results for anisotropic thermal conductivities, which are obtained by the use of fractal correlations, are discussed.

Sabau, A.S.; Tao, Y.X.; Liu, G.; Vidhuvalavan, G.

1997-07-01T23:59:59.000Z

270

Role of gravity or confining pressure and contact stiffness in granular rheology  

E-Print Network [OSTI]

The steady shear rheology of granular materials is investigated in slow quasi-static states and inertial flows. The effect of the gravity field and contact stiffness, which are conventionally trivialized is the focus of this study. Series of Discrete Element Method simulations are performed on a weakly frictional granular assembly in a split-bottom geometry considering various gravity fields and contact stiffnesses. While traditionally the inertial number, i.e., the ratio of stress to strain-rate timescales describes the flow rheology, we find that a second dimensionless number, the ratio of softness and stress timescales, must also be included to characterize the bulk flow behavior. For slow, quasi-static flows, the density increases while the macroscopic friction decreases with respective increase in particle softness and gravity. This trend is added to the $\\mu(I)$ rheology and can be traced back to the anisotropy in the contact network, displaying a linear correlation between macroscopic friction and deviatoric fabric in the steady state. Interestingly, the linear relation holds when the external rotation rate is increased for a given gravity field and contact stiffness.

Abhinendra Singh; Vanessa Magnanimo; Kuniyasu Saitoh; Stefan Luding

2014-12-02T23:59:59.000Z

271

Extraction of Force-Chain Network Architecture in Granular Materials Using Community Detection  

E-Print Network [OSTI]

Force chains form heterogeneous physical structures that can constrain the mechanical stability and acoustic transmission of granular media. However, despite their relevance for predicting bulk properties of materials, there is no agreement on a quantitative description of force chains. Consequently, it is difficult to compare the force-chain structures in different materials or experimental conditions. To address this challenge, we treat granular materials as spatially-embedded networks in which the nodes (particles) are connected by weighted edges that represent contact forces. We use techniques from community detection, which is a type of clustering, to find groups of closely connected particles. By using a geographical null model that is constrained by the particles' contact network, we extract chain-like structures that are reminiscent of force chains. We propose three diagnostics to measure these chain-like structures, and we demonstrate the utility of these diagnostics for identifying and characterizing classes of force-chain network architectures in various materials. To illustrate our methods, we describe how force-chain architecture depends on pressure for both laboratory experiments and numerically-generated frictionless packings. By resolving individual force chains, we quantify statistical properties of force-chain shape and strength, which are potentially crucial diagnostics of bulk properties (including material stability). These methods facilitate quantitative comparisons between different particulate systems, regardless of whether they are measured experimentally or numerically.

Danielle S. Bassett; Eli T. Owens; Mason A. Porter; M. Lisa Manning; Karen E. Daniels

2014-08-17T23:59:59.000Z

272

MRI Investigations of Particle Motion within a Three-Dimensional Vibro-Fluidized Granular Bed  

E-Print Network [OSTI]

The unique ability of magnetic resonance imaging (MRI) to provide spatial and temporal information from optically opaque systems, in three dimensions, make it an ideal tool to study the internal motion of rapid granular flows. This paper will focus on the use of ultra-fast velocity compensated MRI measurements to study particle velocity and density distributions in a granular gas, produced by vibrating vertically a bed of mustard seeds at 40 Hz. Specifically, a velocity compensated, double spin-echo, triggered, one-dimensional MRI profiling pulse sequence was developed. This gives an MRI temporal resolution of approximately 2 ms and also minimises MRI velocity artefacts. 12 phase measurements per vibration cycle were used. The data can be used to extract values of the mustard seed average velocity and velocity propagators (probability distributions functions) as a function of the phase of the vibration cycle and vertical height within the cell. The data show strong transient effects during the impact phase of the vibration. A detailed discussion of the temporal passage of the individual phase resolved, height resolved velocity distributions, along with seed velocity propagators at a fix height from the vibrating base is presented.

Mick D. Mantle; Andrew J. Sederman; Lynn F. Gladden; Jonathan M. Huntley; Tom W. Martin Ricky D. Wildman; Mark D. Shattuck

2007-02-08T23:59:59.000Z

273

Iron-based Superconductor Simulations Spin Out New Possibilities...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in 15 iron-based materials, including iron compounds that are high-temperature superconductors (images d-h). The x axis shows the momentum of the spin excitation in selected...

274

Candidate anode materials for iron production by molten oxide electrolysis  

E-Print Network [OSTI]

Molten oxide electrolysis (MOE) has been identified by the American Iron and Steel Institute (AISI) as one of four possible breakthrough technologies to alleviate the environmental impact of iron and steel production. This ...

Paramore, James D

2010-01-01T23:59:59.000Z

275

Iron oxide nanoparticles as a contrast agent for thermoacoustic tomography  

E-Print Network [OSTI]

radiation. The addition of an exogenous contrast agent improves image quality by more effectively converting microwave energy to heat. The use of iron oxide nanoparticles in MRI applications has been explored but super paramagnetic iron oxide nanoparticles...

Keho, Aaron Lopez

2009-06-02T23:59:59.000Z

276

Preparations of rare earth-iron alloys by thermite reduction  

DOE Patents [OSTI]

Disclosed is an improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.

1985-10-28T23:59:59.000Z

277

The marine biogeochemistry of dissolved and colloidal iron  

E-Print Network [OSTI]

Iron is a redox active trace metal micronutrient essential for primary production and nitrogen acquisition in the open ocean. Dissolved iron (dFe) has extremely low concentrations in marine waters that can drive phytoplankton ...

Fitzsimmons, Jessica Nicole

2013-01-01T23:59:59.000Z

278

arabian iron age: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

iron deficiency should be the goal of nutritional intervention programs. In the United States, approximately 5 % of children from 1-5 years of age suffer from iron deficiency...

279

Iron and Manganese in Potable Water  

E-Print Network [OSTI]

none 22. Hays 469.0 1.0 none 23. Hays .55 24. Peabody 830.0 .5 trace 25. Caldwell 458.0 2.0 trace 26. Lyons 456.0 .1 trace 27. Osborne 377.0 .3 none 28. Herington 608,0 .1 trace 29. Sterling - - _ .1 .036 30. Waverly 546,0 .2 none 31. Clifton 350.... The occurence of a black peaty layer overlying white sand containing iron, the white sand in turn overlying red sand containing 10. oxidize^ iron, is a familiar sight to all engineers who have made excavations. Here the carbon dioxide produced...

Young, Clifford Caudy

1911-06-01T23:59:59.000Z

280

Steam reforming utilizing iron oxide catalyst  

SciTech Connect (OSTI)

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Iron Availability in the Southern Ocean  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines | ornl.govIronIron

282

Iron Availability in the Southern Ocean  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctober 5,Octoberdeep |IronIron

283

Iron Availability in the Southern Ocean  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctober 5,OctoberdeepIronIron

284

Minnesota Jobs to Come with Efficient Iron Plant  

Broader source: Energy.gov [DOE]

New energy-efficient iron plant offers a ray of hope for workers after local mining company shuts down.

285

IEEE TRANSACTIONS ON FUZZY SYSTEMS, VOL. 12, NO. 5, OCTOBER 2004 697 Granular Prototyping in Fuzzy Clustering  

E-Print Network [OSTI]

modeling and pattern recognition, cf. [12], [24], and [25]. Clusters are information granulesIEEE TRANSACTIONS ON FUZZY SYSTEMS, VOL. 12, NO. 5, OCTOBER 2004 697 Granular Prototyping in Fuzzy of clustering techniques [1], [3], [16], [24] and a diversity of ways in which clustering is used in fuzzy

Bargiela, Andrzej

286

MetalBosonic InsulatorSuperconductor Transition in Boron-Doped Granular Diamond Gufei Zhang,1,* Monika Zeleznik,2  

E-Print Network [OSTI]

. Second, the giant RðTÞ peak is observed in heavily boron-doped polycrystalline diamond thick filmsMetal­Bosonic Insulator­Superconductor Transition in Boron-Doped Granular Diamond Gufei Zhang,1 the onset of superconductivity in heavily boron-doped diamond. This anomalous RðTÞ peak in a 3D system

Bristol, University of

287

Washboard Road: The Dynamics of Granular Ripples Formed by Rolling Wheels Nicolas Taberlet,1,2,* Stephen W. Morris,3  

E-Print Network [OSTI]

experiments on rippled granular surfaces formed under rolling wheels. Ripples appear above a critical speed surface under tangential stress is reminiscent of other sorts of wind- and water-driven ripples [2 rolled freely on the sand bed as the table rotated at a constant speed. No torque was applied

McElwaine, Jim

288

Role of friction in pattern formation in oscillated granular layers Sung Joon Moon, # J. B. Swift, and Harry L. Swinney  

E-Print Network [OSTI]

Role of friction in pattern formation in oscillated granular layers Sung Joon Moon, # J. B. Swift grains. Our molecular dynamics simu­ lations reveal that friction is essential for realistic modeling at a container acceleration about 30% smaller than that observed in experiments and simulations with friction

Texas at Austin. University of

289

Role of friction in pattern formation in oscillated granular layers Sung Joon Moon,* J. B. Swift, and Harry L. Swinney  

E-Print Network [OSTI]

Role of friction in pattern formation in oscillated granular layers Sung Joon Moon,* J. B. Swift as there are no elastic grains. Our molecular dynamics simulations reveal that friction is essential for realistic with friction. More importantly, even though square and hexagonal patterns form for a wide range

Texas at Austin. University of

290

Dynamic fracture of granular material under quasi-static loading , The Institute of Earth Sciences, The Hebrew University of Jerusalem  

E-Print Network [OSTI]

Dynamic fracture of granular material under quasi-static loading Amir Sagy1 , The Institute;Abstract The dynamics of rapid fracture in heterogeneous grainy media are studied in a series of laboratory experiments in which artificial rock slab is fractured under conditions of uniaxial tension. By performing

Fineberg, Jay

291

PHYSICAL REVIEW E 85, 051302 (2012) Probing the shear-band formation in granular media with sound waves  

E-Print Network [OSTI]

, the application of these experimental methods to real 3D opaque granular materials appears difficult. Sound waves [13­17]. Speed measurements of long-wavelength sound waves allow one to determine the nonlinear scattered sound waves enable one to detect tiny changes of the contact network configuration at the grain

Paris 7 - Denis Diderot, Université

292

ccsd-00003870,version1-11Jan2005 Importance of convection in the compaction mechanisms of anisotropic granular media  

E-Print Network [OSTI]

of the vortices and relate them to granular convection. Our results demonstrate the importance of compression of a glass cylinder of diameter D 10 cm filled with 600 g of grains (corre- sponding to a height of roughly) by vertical taps. Each tap is created by one entire period of sine wave at a fixed frequency f = 30 Hz

Paris-Sud XI, Université de

293

Wastewater treatment by aerobic granular biofilmWastewater treatment by aerobic granular biofilmaste ate t eat e t by ae ob c g a u a b o Aeration pulses to improve N eliminationAeration pulses to improve N-eliminationAeration pulses to improve N eliminat  

E-Print Network [OSTI]

Wastewater treatment by aerobic granular biofilmWastewater treatment by aerobic granular wastewater treatment p p denitrification Nitrification is the oxidation from ammonium (NH +) first activated sludge for biological N-elimination is a two step process: aerobic nitrification and anoxicp g g g

294

Iron distribution and phytoplankton iron limitation in the southern California Current System  

E-Print Network [OSTI]

layer density (sigma-theta) are shown for six CalCOFI surveysolution (Sigma-Aldrich) in 0.016 M ultrapure HCl every sixsigma-theta. Macronutrients, dissolved iron, and chl were elevated during all six

King, Andrew Luke

2008-01-01T23:59:59.000Z

295

Moving granular-bed filter development program option I -- Component test facilities technical tradeoffs and issues. Topical report  

SciTech Connect (OSTI)

Advanced, coal-based, power plants, such as IGCC and Advanced-PFBC, are currently nearing commercial demonstration. These power plant technologies require hot gas filtration as part of their gas cleaning trains. Ceramic barrier filters are the major filter candidates being developed for these hot gas cleaning applications. While ceramic barrier filters achieve high levels of particle removal, there are concerns for their reliability and operability in these applications. An alternative hot gas filtration technology is the moving granular bed filter. These systems are at a lower state of development than ceramic barrier filters, and the current, moving granular-bed filter technologies are relatively large, complex, and costly systems in terms of their capital investment, their operating and maintenance cost, and their impact on the power plant efficiency. In addition, their effectiveness as filters is still in question. Their apparent attributes, relative to ceramic barrier filter systems, result from their much less severe mechanical design and materials constraints, and the potential for more reliable, failure-free particle removal operation. The Westinghouse Science & Technology Center has proposed a novel moving granular-bed filter concept, the Standleg Moving Granular-Bed Filter (SMGBF) system, that may overcome the inherent deficiencies of the current state-of-the-art moving granular-bed filter technology. The SMGBF is a compact unit that uses cocurrent gas-pellet contacting in an arrangement that greatly simplifies and enhances the distribution of dirty, process gas to the moving bed and allows effective disengagement of clean gas from the moving bed.

Newby, R.A.; Yang, W.C.; Smeltzer, E.E.; Lippert, T.E.; Gasparovic, A.C.; Kittle, W.F.; Schneider, G.N.; Fellers, A.W.

1994-06-01T23:59:59.000Z

296

Iron Air collision with high density QCD  

E-Print Network [OSTI]

The color glass condensate approach describes successfully heavy ion collisions at RHIC. We investigate Iron-air collisions within this approach and compare results to event generators commonly used in air shower simulations. We estimate uncertainties in the extrapolation to GZK energies and discuss implications for air shower simulations.

Hans-Joachim Drescher

2006-12-08T23:59:59.000Z

297

Drinking Water Problems: Iron and Manganese  

E-Print Network [OSTI]

. The chemical must be in the water for at least 20 minutes for oxi- dation to take place, longer if the water contains colloidal iron/manganese. After solid particles have formed they are filtered, often with a sand filter. Adding aluminum sulfate (alum...

Dozier, Monty; McFarland, Mark L.

2004-02-20T23:59:59.000Z

298

Superconductivity in iron compounds G. R. Stewart  

E-Print Network [OSTI]

of the superconductivity in this new class of compounds. These iron pnictide and chalcogenide (FePn/Ch) superconductors-phonon coupled ``conventional'' superconductors. Clearly, superconductivity and magnetism or magnetic of magnetism and superconductivity in FePn/Ch superconductors 1606 D. Tc and TS=TSDW versus pressure 1607 1

Wu, Zhigang

299

Ligand effects on bioinspired iron complexes  

E-Print Network [OSTI]

- phosphaadamantane, PTA, coordinates to the Fe centers forming the disubstituted complex (m-pdt)[Fe(CO)2PTA]2, which presents one PTA in each iron in a transoid arrangement. Substitution of one CO ligand in the (m-pdt)[Fe(CO)3]2 parent complex forms the asymmetric (m-pdt)[Fe...

Mejia Rodriguez, Ma. del Rosario

2005-11-01T23:59:59.000Z

300

Visualizing Iron Deposition in Multiple Sclerosis Cadaver Brains  

SciTech Connect (OSTI)

Aim: To visualize and validate iron deposition in two cases of multiple sclerosis using rapid scanning X-Ray Fluorescence (RS-XRF) and Susceptibility Weighted Imaging (SWI). Material and Methods: Two (2) coronal cadaver brain slices from patients clinically diagnosed with multiple sclerosis underwent magnetic resonance imaging (MRI), specifically SWI to image iron content. To confirm the presence of iron deposits and the absence of zinc-rich myelin in lesions, iron and zinc were mapped using RS-XRF. Results: MS lesions were visualized using FLAIR and correlated with the absence of zinc by XRF. XRF and SWI showed that in the first MS case, there were large iron deposits proximal to the draining vein of the caudate nucleus as well as iron deposits associated with blood vessels throughout the globus pallidus. Less iron was seen in association with lesions than in the basal ganglia. The presence of larger amounts of iron correlated reasonably well between RS-XRF and SWI. In the second case, the basal ganglia appeared normal and acute perivascular iron deposition was absent. Conclusion: Perivascular iron deposition is seen in some but not all MS cases, giving credence to the use of SWI to assess iron involvement in MS pathology in vivo.

Habib, Charbel A.; Zheng Weili; Mark Haacke, E. [Department Of Biomedical Engineering, Wayne State University, Detroit, MI 48202 (United States); Webb, Sam [Stanford Synchrotron Radiation Lightsource, Stanford Linear Accelerator Complex National Accelerator Laboratory, Menlo Park, California (United States); Nichol, Helen [Department of Anatomy and Cell Biology, University of Saskatchewan, 107 Wiggins Rd. Rm A302, Saskatoon, SK S7N5E5 (Canada)

2010-07-23T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Method for preparing hydrous iron oxide gels and spherules  

DOE Patents [OSTI]

The present invention is directed to methods for preparing hydrous iron oxide spherules, hydrous iron oxide gels such as gel slabs, films, capillary and electrophoresis gels, iron monohydrogen phosphate spherules, hydrous iron oxide spherules having suspendable particles homogeneously embedded within to form composite sorbents and catalysts, iron monohydrogen phosphate spherules having suspendable particles of at least one different sorbent homogeneously embedded within to form a composite sorbent, iron oxide spherules having suspendable particles homogeneously embedded within to form a composite of hydrous iron oxide fiber materials, iron oxide fiber materials, hydrous iron oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, iron oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, dielectric spherules of barium, strontium, and lead ferrites and mixtures thereof, and composite catalytic spherules of barium or strontium ferrite embedded with oxides of Mg, Zn, Pb, Ce and mixtures thereof. These variations of hydrous iron oxide spherules and gel forms prepared by the gel-sphere, internal gelation process offer more useful forms of inorganic ion exchangers, catalysts, getters, dielectrics, and ceramics.

Collins, Jack L.; Lauf, Robert J.; Anderson, Kimberly K.

2003-07-29T23:59:59.000Z

302

R&D for a highly granular silicon tungsten electromagnetic calorimeter  

E-Print Network [OSTI]

This article reports on first experience with the technological prototype of a highly- granular silicon-tungsten electromagnetic calorimeter as envisaged for the detectors at a future lepton collider. In the focus of the analysis is the performance of a highly integrated Application Specific Integrated Circuit designed to meet the requirements in terms of dynamic range, compactness and power consumption. The beam test results show that the circuit will allow a future detector with a signal over noise ratio of at least 10:1. To minimise the power dissipation the ASIC will be operated in a power pulsed mode. So far no conceptual problem was revealed but the studies show the way for further work. The prototype is read out by a DAQ system conceived to meet the needs of a trigger less system with a huge number of readout cells.

Pöschl, R

2015-01-01T23:59:59.000Z

303

X-ray tomography system to investigate granular materials during mechanical loading  

E-Print Network [OSTI]

We integrate a small and portable medical x-ray device with mechanical testing equipment to enable in-situ, non-invasive measurements of a granular material's response to mechanical loading. We employ an orthopedic C-arm as the x-ray source and detector to image samples mounted in the materials tester. We discuss the design of a custom rotation stage, which allows for sample rotation and tomographic reconstruction under applied compressive stress. We then discuss the calibration of the system for 3d computed tomography, as well as the subsequent image reconstruction process. Using this system to reconstruct packings of 3d-printed particles, we resolve packing features with 0.52 mm resolution in a (60 mm)$^3$ field of view. By analyzing the performance bounds of the system, we demonstrate that the reconstructions exhibit only moderate noise.

Athanassiadis, Athanasios G; Sidky, Emil; Pelizzari, Charles; Pan, Xiaochuan; Jaeger, Heinrich M

2014-01-01T23:59:59.000Z

304

X-ray tomography system to investigate granular materials during mechanical loading  

E-Print Network [OSTI]

We integrate a small and portable medical x-ray device with mechanical testing equipment to enable in-situ, non-invasive measurements of a granular material's response to mechanical loading. We employ an orthopedic C-arm as the x-ray source and detector to image samples mounted in the materials tester. We discuss the design of a custom rotation stage, which allows for sample rotation and tomographic reconstruction under applied compressive stress. We then discuss the calibration of the system for 3d computed tomography, as well as the subsequent image reconstruction process. Using this system to reconstruct packings of 3d-printed particles, we resolve packing features with 0.52 mm resolution in a (60 mm)$^3$ field of view. By analyzing the performance bounds of the system, we demonstrate that the reconstructions exhibit only moderate noise.

Athanasios G Athanassiadis; Patrick J. La Rivière; Emil Sidky; Charles Pelizzari; Xiaochuan Pan; Heinrich M. Jaeger

2014-07-28T23:59:59.000Z

305

Validation of GEANT4 Monte Carlo Models with a Highly Granular Scintillator-Steel Hadron Calorimeter  

E-Print Network [OSTI]

Calorimeters with a high granularity are a fundamental requirement of the Particle Flow paradigm. This paper focuses on the prototype of a hadron calorimeter with analog readout, consisting of thirty-eight scintillator layers alternating with steel absorber planes. The scintillator plates are finely segmented into tiles individually read out via Silicon Photomultipliers. The presented results are based on data collected with pion beams in the energy range from 8GeV to 100GeV. The fine segmentation of the sensitive layers and the high sampling frequency allow for an excellent reconstruction of the spatial development of hadronic showers. A comparison between data and Monte Carlo simulations is presented, concerning both the longitudinal and lateral development of hadronic showers and the global response of the calorimeter. The performance of several GEANT4 physics lists with respect to these observables is evaluated.

C. Adloff; J. Blaha; J. -J. Blaising; C. Drancourt; A. Espargilière; R. Gaglione; N. Geffroy; Y. Karyotakis; J. Prast; G. Vouters; K. Francis; J. Repond; J. Schlereth; J. Smith; L. Xia; E. Baldolemar; J. Li; S. T. Park; M. Sosebee; A. P. White; J. Yu; T. Buanes; G. Eigen; Y. Mikami; N. K. Watson; G. Mavromanolakis; M. A. Thomson; D. R. Ward; W. Yan; D. Benchekroun; A. Hoummada; Y. Khoulaki; J. Apostolakis; A. Dotti; G. Folger; V. Ivantchenko; V. Uzhinskiy; M. Benyamna; C. Cârloganu; F. Fehr; P. Gay; S. Manen; L. Royer; G. C. Blazey; A. Dyshkant; J. G. R. Lima; V. Zutshi; J. -Y. Hostachy; L. Morin; U. Cornett; D. David; G. Falley; K. Gadow; P. Göttlicher; C. Günter; B. Hermberg; S. Karstensen; F. Krivan; A. -I. Lucaci-Timoce; S. Lu; B. Lutz; S. Morozov; V. Morgunov; M. Reinecke; F. Sefkow; P. Smirnov; M. Terwort; A. Vargas-Trevino; N. Feege; E. Garutti; I. Marchesinik; M. Ramilli; P. Eckert; T. Harion; A. Kaplan; H. -Ch. Schultz-Coulon; W. Shen; R. Stamen; B. Bilki; E. Norbeck; Y. Onel; G. W. Wilson; K. Kawagoe; P. D. Dauncey; A. -M. Magnan; V. Bartsch; M. Wing; F. Salvatore; E. Calvo Alamillo; M. -C. Fouz; J. Puerta-Pelayo; B. Bobchenko; M. Chadeeva; M. Danilov; A. Epifantsev; O. Markin; R. Mizuk; E. Novikov; V. Popov; V. Rusinov; E. Tarkovsky; N. Kirikova; V. Kozlov; P. Smirnov; Y. Soloviev; P. Buzhan; A. Ilyin; V. Kantserov; V. Kaplin; A. Karakash; E. Popova; V. Tikhomirov; C. Kiesling; K. Seidel; F. Simon; C. Soldner; M. Szalay; M. Tesar; L. Weuste; M. S. Amjad; J. Bonis; S. Callier; S. Conforti di Lorenzo; P. Cornebise; Ph. Doublet; F. Dulucq; J. Fleury; T. Frisson; N. van der Kolk; H. Li; G. Martin-Chassard; F. Richard; Ch. de la Taille; R. Pöschl; L. Raux; J. Rouëné; N. Seguin-Moreau; M. Anduze; V. Boudry; J-C. Brient; D. Jeans; P. Mora de Freitas; G. Musat; M. Reinhard; M. Ruan; H. Videau; B. Bulanek; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; J. Kvasnicka; D. Lednicky; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; B. Belhorma; H. Ghazlane; T. Takeshita; S. Uozumi; M. Götze; O. Hartbrich; J. Sauer; S. Weber; C. Zeitnitz

2014-06-15T23:59:59.000Z

306

Method and apparatus for filtering gas with a moving granular filter bed  

DOE Patents [OSTI]

A method and apparatus for filtering gas (58) with a moving granular filter bed (48) involves moving a mass of particulate filter material (48) downwardly through a filter compartment (35); tangentially introducing gas into the compartment (54) to move in a cyclonic path downwardly around the moving filter material (48); diverting the cyclonic path (58) to a vertical path (62) to cause the gas to directly interface with the particulate filter material (48); thence causing the gas to move upwardly through the filter material (48) through a screened partition (24, 32) into a static upper compartment (22) of a filter compartment for exodus (56) of the gas which has passed through the particulate filter material (48).

Brown, Robert C. (Ames, IA); Wistrom, Corey (Ames, IA); Smeenk, Jerod L. (Ames, IA)

2007-12-18T23:59:59.000Z

307

Hadronic energy resolution of a highly granular scintillator-steel hadron calorimeter using software compensation techniques  

E-Print Network [OSTI]

The energy resolution of a highly granular 1 m3 analogue scintillator-steel hadronic calorimeter is studied using charged pions with energies from 10 GeV to 80 GeV at the CERN SPS. The energy resolution for single hadrons is determined to be approximately 58%/sqrt(E/GeV}. This resolution is improved to approximately 45%/sqrt(E/GeV) with software compensation techniques. These techniques take advantage of the event-by-event information about the substructure of hadronic showers which is provided by the imaging capabilities of the calorimeter. The energy reconstruction is improved either with corrections based on the local energy density or by applying a single correction factor to the event energy sum derived from a global measure of the shower energy density. The application of the compensation algorithms to Geant4 simulations yield resolution improvements comparable to those observed for real data.

CALICE Collaboration; C. Adloff; J. Blaha; J. -J. Blaising; C. Drancourt; A. Espargilière; R. Gaglione; N. Geffroy; Y. Karyotakis; J. Prast; G. Vouters; K. Francis; J. Repond; J. Smith; L. Xia; E. Baldolemar; J. Li; S. T. Park; M. Sosebee; A. P. White; J. Yu; T. Buanes; G. Eigen; Y. Mikami; N. K. Watson; T. Goto; G. Mavromanolakis; M. A. Thomson; D. R. Ward; W. Yan; D. Benchekroun; A. Hoummada; Y. Khoulaki; M. Benyamna; C. Cârloganu; F. Fehr; P. Gay; S. Manen; L. Royer; G. C. Blazey; A. Dyshkant; J. G. R. Lima; V. Zutshi; J. -Y. Hostachy; L. Morin; U. Cornett; D. David; G. Falley; K. Gadow; P. Göttlicher; C. Günter; B. Hermberg; S. Karstensen; F. Krivan; A. -I. Lucaci-Timoce; S. Lu; B. Lutz; S. Morozov; V. Morgunov; M. Reinecke; F. Sefkow; P. Smirnov; M. Terwort; A. Vargas-Trevino; N. Feege; E. Garutti; I. Marchesini; M. Ramilli; P. Eckert; T. Harion; A. Kaplan; H. -Ch. Schultz-Coulon; W. Shen; R. Stamen; A. Tadday; B. Bilki; E. Norbeck; Y. Onel; G. W. Wilson; K. Kawagoe; P. D. Dauncey; A. -M. Magnan; M. Wing; F. Salvatore; E. Calvo Alamillo; M. -C. Fouz; J. Puerta-Pelayo; V. Balagura; B. Bobchenko; M. Chadeeva; M. Danilov; A. Epifantsev; O. Markin; R. Mizuk; E. Novikov; V. Rusinov; E. Tarkovsky; N. Kirikova; V. Kozlov; P. Smirnov; Y. Soloviev; P. Buzhan; B. Dolgoshein; A. Ilyin; V. Kantserov; V. Kaplin; A. Karakash; E. Popova; S. Smirnov; C. Kiesling; S. Pfau; K. Seidel; F. Simon; C. Soldner; M. Szalay; M. Tesar; L. Weuste; J. Bonis; B. Bouquet; S. Callier; P. Cornebise; Ph. Doublet; F. Dulucq; M. Faucci Giannelli; J. Fleury; H. Li; G. Martin-Chassard; F. Richard; Ch. de la Taille; R. Pöschl; L. Raux; N. Seguin-Moreau; F. Wicek; M. Anduze; V. Boudry; J-C. Brient; D. Jeans; P. Mora de Freitas; G. Musat; M. Reinhard; M. Ruan; H. Videau; B. Bulanek; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; J. Kvasnicka; D. Lednicky; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; B. Belhorma; H. Ghazlane; T. Takeshita; S. Uozumi; J. Sauer; S. Weber; C. Zeitnitz

2012-09-27T23:59:59.000Z

308

X-ray tomography system to investigate granular materials during mechanical loading  

SciTech Connect (OSTI)

We integrate a small and portable medical x-ray device with mechanical testing equipment to enable in situ, non-invasive measurements of a granular material's response to mechanical loading. We employ an orthopedic C-arm as the x-ray source and detector to image samples mounted in the materials tester. We discuss the design of a custom rotation stage, which allows for sample rotation and tomographic reconstruction under applied compressive stress. We then discuss the calibration of the system for 3D computed tomography, as well as the subsequent image reconstruction process. Using this system to reconstruct packings of 3D-printed particles, we resolve packing features with 0.52?mm resolution in a (60 mm){sup 3} field of view. By analyzing the performance bounds of the system, we demonstrate that the reconstructions exhibit only moderate noise.

Athanassiadis, Athanasios G. [James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States); Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); La Rivière, Patrick J.; Sidky, Emil; Pan, Xiaochuan [Department of Radiology, The University of Chicago, Chicago, Illinois 60637 (United States); Pelizzari, Charles [Department of Radiation and Cellular Oncology, The University of Chicago, Chicago, Illinois 60637 (United States); Jaeger, Heinrich M., E-mail: h-jaeger@uchicago.edu [James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)

2014-08-15T23:59:59.000Z

309

Modeling Granular Materials as Compressible Non-Linear Fluids: Heat Transfer Boundary Value Problems  

SciTech Connect (OSTI)

We discuss three boundary value problems in the flow and heat transfer analysis in flowing granular materials: (i) the flow down an inclined plane with radiation effects at the free surface; (ii) the natural convection flow between two heated vertical walls; (iii) the shearing motion between two horizontal flat plates with heat conduction. It is assumed that the material behaves like a continuum, similar to a compressible nonlinear fluid where the effects of density gradients are incorporated in the stress tensor. For a fully developed flow the equations are simplified to a system of three nonlinear ordinary differential equations. The equations are made dimensionless and a parametric study is performed where the effects of various dimensionless numbers representing the effects of heat conduction, viscous dissipation, radiation, and so forth are presented.

Massoudi, M.C.; Tran, P.X.

2006-01-01T23:59:59.000Z

310

Dynamic synchrotron X-ray imaging study of effective temperature in a vibrated granular medium  

E-Print Network [OSTI]

We present a dynamic synchrotron X-ray imaging study of the effective temperature $T_{eff}$ in a vibrated granular medium. By tracking the directed motion and the fluctuation dynamics of the tracers inside, we obtained $T_{eff}$ of the system using Einstein relation. We found that as the system unjams with increasing vibration intensities $\\Gamma$, the structural relaxation time $\\tau$ increases substantially which can be fitted by an Arrhenius law using $T_{eff}$. And the characteristic energy scale of structural relaxation yielded by the Arrhenius fitting is $E = 0.21 \\pm 0.02$ $pd^3$, where $p$ is the pressure and $d$ is the background particle diameter, which is consistent with those from hard sphere simulations in which the structural relaxation happens via the opening up of free volume against pressure.

Yixin Cao; Xiaodan Zhang; Binquan Kou; Xiangting Li; Xianghui Xiao; Kamel Fezzaa; Yujie Wang

2014-03-21T23:59:59.000Z

311

Power-law rheology and the dynamical heterogeneity in a sheared granular material  

E-Print Network [OSTI]

Rheology of a granular material at the jamming density is investigated using molecular dynamics simulation. It is found that shear stress exhibits power-law dependence on shear rate with a nontrivial exponent. Due to the criticality of the jamming transition point, finite-size effect is observed in smaller systems at lower shear rates. Finite-size scaling indicates the correlation length algebraically diverges in the zero shear rate limit. It is also found that the dynamical susceptibility monotonically decreases with time so that the dynamical heterogeneity is detected by a two-point correlation function. Several exponents that describe rheology, the correlation length, and the amplitude of the dynamical susceptibility are estimated.

Takahiro Hatano

2008-11-09T23:59:59.000Z

312

An Investigation on Granular-Nanocomposite-Based Giant Magnetoresistance (GMR) Sensor Fabrication  

E-Print Network [OSTI]

composites reinforced with iron nanoparticles which has been heat treated was reported. The flexible to conductive composites. The coercive forces reflect strong particle loading and matrix dependent magnetic of adjacent ferromagnetic layers in a GMR material are antiparallel due to a weak anti-ferromagnetic coupling

Guo, John Zhanhu

313

JOURNAL DE PHYSIQUE Colloque C6, supplment au no 12, Tome 35, Dcembre 1974,page C6-393 SUPERCONDUCTIVITY AND LATTICE DYNAMICS OF GRANULAR TIN (*)  

E-Print Network [OSTI]

-393 SUPERCONDUCTIVITY AND LATTICE DYNAMICS OF GRANULAR TIN (*) S. AKSELROD, M. PASTERNAK Physics Department, Tel was measured in samples of 4 5 8 Sn grains embedded in a tin-oxide matrix. The Debye temperature of the same

Paris-Sud XI, Université de

314

Iron-sulfide redox flow batteries  

DOE Patents [OSTI]

Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

2013-12-17T23:59:59.000Z

315

Role of microbial iron reduction in the dissolution of iron hydroxysulfate minerals - article no. G01012  

SciTech Connect (OSTI)

Reduction of structural sulfate in the iron-hydroxysulfate mineral jarosite by sulfate-reducing bacteria has previously been demonstrated. The primary objective of this work was to evaluate the potential for anaerobic dissolution of the iron-hydroxysulfate minerals jarosite and schwertmannite at neutral pH by iron-reducing bacteria. Mineral dissolution was tested using a long-term cultivar, Geobacter metallireducens strain GS-15, and a fresh isolate Geobacter sp. strain ENN1, previously undescribed. ENN1 was isolated from the discharge site of Shadle Mine, in the southern anthracite coalfield of Pennsylvania, where schwertmannite was the predominant iron-hydroxysulfate mineral. When jarosite from Elizabeth Mine (Vermont) was provided as the sole terminal electron acceptor, resting cells of both G. metallireducens and ENN1 were able to reduce structural Fe(III), releasing Fe{sup +2}, SO{sub 4}{sup -2}, and K{sup +} ions. A lithified jarosite sample from Utah was more resistant to microbial attack, but slow release of Fe{sup +2} was observed. Neither bacterium released Fe{sup +2} from poorly crystalline synthetic schwertmannite. Our results indicate that exposure of jarosite to iron-reducing conditions at neutral pH is likely to promote the mobility of hazardous constituents and should therefore be considered in evaluating waste disposal and/or reclamation options involving jarosite-bearing materials.

Jones, E.J.P.; Nadeau, T.L.; Voytek, M.A.; Landa, E.R. [US Geological Survey, Reston, VA (United States)

2006-03-28T23:59:59.000Z

316

Thin Wall Cast Iron: Phase II  

SciTech Connect (OSTI)

The development of thin-wall technology allows the designers of energy consuming equipment to select the most appropriate material based on cost/material properties considerations, and not solely on density. The technology developed in this research project will permit the designers working for the automotive industry to make a better informed choice between competing materials and thin wall cast iron, thus decreasing the overall cost of the automobile.

Doru M. Stefanescu

2005-07-21T23:59:59.000Z

317

Seal welded cast iron nuclear waste container  

DOE Patents [OSTI]

This invention identifies methods and articles designed to circumvent metallurgical problems associated with hermetically closing an all cast iron nuclear waste package by welding. It involves welding nickel-carbon alloy inserts which are bonded to the mating plug and main body components of the package. The welding inserts might be bonded in place during casting of the package components. When the waste package closure weld is made, the most severe thermal effects of the process are restricted to the nickel-carbon insert material which is far better able to accommodate them than is cast iron. Use of nickel-carbon weld inserts should eliminate any need for pre-weld and post-weld heat treatments which are a problem to apply to nuclear waste packages. Although the waste package closure weld approach described results in a dissimilar metal combination, the relative surface area of nickel-to-iron, their electrochemical relationship, and the presence of graphite in both materials will act to prevent any galvanic corrosion problem.

Filippi, Arthur M. (Pittsburgh, PA); Sprecace, Richard P. (Murrysville, PA)

1987-01-01T23:59:59.000Z

318

Correlation effects in the iron pnictides  

SciTech Connect (OSTI)

One of the central questions about the iron pnictides concerns the extent to which their electrons are strongly correlated. Here we address this issue through the phenomenology of the charge transport and dynamics, single-electron excitation spectrum, and magnetic ordering and dynamics. We outline the evidence that the parent compounds, while metallic, have electron interactions that are sufficiently strong to produce incipient Mott physics. In other words, in terms of the strength of electron correlations compared to the kinetic energy, the iron pnictides are closer to intermediately-coupled systems lying at the boundary between itinerancy and localization, such as V{sub 2}O{sub 3} a or Se-doped NiS{sub 2} , rather than to simple antiferromagnetic metals like Cr. This level of electronic correlations produces a new small parameter for controlled theoretical analyses, namely the fraction of the single-electron spectral weight that lies in the coherent part. Using this expansion parameter, we construct the effective low-energy Hamiltonian and discuss its implications for the magnetic order and magnetic quantum criticality. Finally, this approach sharpens the notion of magnetic frustration for such a metallic system, and brings about a multi band matrix t-J{sub 1}-J{sub 2} model for the carrier-doped iron pnictides.

Zhu, Jian-xin [Los Alamos National Laboratory; Si, Qimiao [RICE UNIV; Abrahams, Elihu [RUTGERS UNIV; Dai, Jianhui [ZHEJIANG UNIV

2009-01-01T23:59:59.000Z

319

INVESTIGATION OF THE RATE DEPENDENCE OF LONG-ROD PENETRATION OF GRANULAR MEDIA USING AN IMPROVED DSR ALGORITHM  

SciTech Connect (OSTI)

Digital Speckle Radiography (DSR), a technique allowing measurement of the full field displacement maps in a plane within an opaque material, is used to follow the temporal progression of a long-rod (100 mm long, 10 mm diameter) penetrating a granular sample at a variety of rates. Quasi-static rates of 1.5 mm/min are achieved using an Instron machine, 5 m/s is achieved using a drop-weight and velocities between 10 and 200 m/s are achieved using a light gas gun. These experiments are carried out using a series of time delayed flash x-ray images analysed with an optimised Digital Image Cross Correlation algorithm (DICC). The subsequent data sheds considerable light on the response of granular materials to penetration at a variety of rates. Particularly, a large difference in the response of the material between quasi-static and dynamic rates is observed.

Addiss, John W.; Collins, Adam L.; Proud, William G. [Fracture and Shock Physics, SMF Group, Cavendish Laboratory, J. J. Thomson Ave., Cambridge, CB3 OHE (United Kingdom)

2009-12-28T23:59:59.000Z

320

Magnetic phase composition of strontium titanate implanted with iron ions  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer The origin of RT-ferromagnetism in iron implanted strontium titanate. Black-Right-Pointing-Pointer Metallic iron nanoclusters form during implantation and define magnetic behaviour. Black-Right-Pointing-Pointer Paramagnetic at room temperature iron-substituted strontium titanate identified. -- Abstract: Thin magnetic films were synthesized by means of implantation of iron ions into single-crystalline (1 0 0) substrates of strontium titanate. Depth-selective conversion electron Moessbauer spectroscopy (DCEMS) indicates that origin of the samples magnetism is {alpha}-Fe nanoparticles. Iron-substituted strontium titanate was also identified but with paramagnetic behaviour at room temperature. Surface magneto-optical Kerr effect (SMOKE) confirms that the films reveal superparamagnetism (the low-fluence sample) or ferromagnetism (the high-fluence sample), and demonstrate absence of magnetic in-plane anisotropy. These findings highlight iron implanted strontium titanate as a promising candidate for composite multiferroic material and also for gas sensing applications.

Dulov, E.N., E-mail: evgeny.dulov@ksu.ru [Kazan Federal University, 420008 Kazan (Russian Federation); Ivoilov, N.G.; Strebkov, O.A. [Kazan Federal University, 420008 Kazan (Russian Federation)] [Kazan Federal University, 420008 Kazan (Russian Federation); Tagirov, L.R. [Kazan Federal University, 420008 Kazan (Russian Federation) [Kazan Federal University, 420008 Kazan (Russian Federation); Zavoisky Physico-Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, 420029 Kazan (Russian Federation); Nuzhdin, V.I. [Zavoisky Physico-Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, 420029 Kazan (Russian Federation)] [Zavoisky Physico-Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, 420029 Kazan (Russian Federation); Khaibullin, R.I. [Kazan Federal University, 420008 Kazan (Russian Federation) [Kazan Federal University, 420008 Kazan (Russian Federation); Zavoisky Physico-Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, 420029 Kazan (Russian Federation); Kazan, S. [Department of Physics, Gebze Institute of Technology, Gebze, 41400 Kocaeli (Turkey)] [Department of Physics, Gebze Institute of Technology, Gebze, 41400 Kocaeli (Turkey); Mikailzade, F.A. [Department of Physics, Gebze Institute of Technology, Gebze, 41400 Kocaeli (Turkey) [Department of Physics, Gebze Institute of Technology, Gebze, 41400 Kocaeli (Turkey); Institute of Physics, Azerbaijan National Academy of Sciences, H. Javid Av. 33, AZ 1143, Baku (Azerbaijan)

2011-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Iron phosphate compositions for containment of hazardous metal waste  

DOE Patents [OSTI]

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P{sub 2}O{sub 5} and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe{sup 3+} provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided. 21 figs.

Day, D.E.

1998-05-12T23:59:59.000Z

322

Iron phosphate compositions for containment of hazardous metal waste  

DOE Patents [OSTI]

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P.sub.2 O.sub.5 and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe.sup.3+ provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided.

Day, Delbert E. (Rolla, MO)

1998-01-01T23:59:59.000Z

323

Tap Density Equations of Granular Powders Based on the Rate Process Theory and the Free Volume Concept  

E-Print Network [OSTI]

Tap density of a granular powder is often linked to the flowability via Carr Index that measures how tight a powder can be packed, under an assumption that more easily packed powders usually flow poorly. Understanding how particles are packed is important for revealing why a powder flows better than others. There are two types of empirical equations that were proposed to fit the experimental data of packing fractions vs. numbers of taps in literature: The inverse logarithmic and the stretched exponential. Using the rate process theory and the free volume concept, we obtain the tap density equations and they can be reducible to the two empirical equations currently widely used in literature. Our equations could potentially fit experimental data better with an additional adjustable parameter. The tapping amplitude and frequency, the weight of the granular materials, and the environment temperature are grouped into one parameter that weighs the pace of packing process. The current results, in conjunction with our previous findings, may imply that both dry(granular)and wet(colloidal and polymeric) particle systems are governed by the same physical mechanisms in term of the role of the free volume and how particles behave (a rate controlled process).

Tian Hao

2014-09-05T23:59:59.000Z

324

Role of material properties and mesostructure on dynamic deformation and shear instability in Al-W granular composites  

E-Print Network [OSTI]

Dynamic experiments with Al-W granular/porous composites revealed qualitatively different behavior with respect to shear localization depending on bonding between Al particles. Two-dimensional numerical modeling was used to explore the mesomechanics of the large strain dynamic deformation in Al-W granular/porous composites and explain the experimentally observed differences in shear localization between composites with various mesostructures. Specifically, the bonding between the Al particles, the porosity, the roles of the relative particle sizes of Al and W, the arrangements of the W particles, and the material properties of Al were investigated using numerical calculations. It was demonstrated in simulations that the bonding between the "soft" Al particles facilitated shear localization as seen in the experiments. Numerical calculations and experiments revealed that the mechanism of the shear localization in granular composites is mainly due to the local high strain flow of "soft" Al around the "rigid" W particles causing localized damage accumulation and subsequent growth of the meso/macro shear bands/cracks. The "rigid" W particles were the major geometrical factor determining the initiation and propagation of "kinked" shear bands in the matrix of "soft" Al particles, leaving some areas free of extensive plastic deformation as observed in experiments and numerical calculations.

K. L. Olney; P. H. Chiu; C. W. Lee; V. F. Nesterenko; D. J. Benson

2011-05-24T23:59:59.000Z

325

Reduction and carburization reactions in the iron bath smelter  

SciTech Connect (OSTI)

Slag-metal-coal reactions in the iron-bath smelter were analyzed based on a reaction model. It was concluded that the productivity and carbon content of the hot metal produced in a smelter can be controlled by adjusting the slag volume and iron oxide content in slag. Furthermore, iron oxide content is determined by the slag volume and the stirring intensity of the slag.

Uemura, Kenichiro

1993-01-01T23:59:59.000Z

326

approved iron nanoparticles: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

thickness on magnetic interactions in self-assembled single domain iron nanoparticles Materials Science Websites Summary: of Mechanical and Chemical Engineering, North Carolina...

327

Argonne scientists discover new magnetic phase in iron-based...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

neutron diffraction image giving evidence for the new magnetic phase in iron-based superconductors discovered by Argonne scientists. It shows the scattering results from a sample...

328

Metal regeneration of iron chelates in nitric oxide scrubbing  

DOE Patents [OSTI]

The present invention relates to a process of using metal particles to reduce NO to NH.sub.3. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20.degree. and 90.degree. C. to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution.

Chang, Shih-Ger (El Cerrito, CA); Littlejohn, David (Oakland, CA); Shi, Yao (Berkeley, CA)

1997-08-19T23:59:59.000Z

329

Metal regeneration of iron chelates in nitric oxide scrubbing  

DOE Patents [OSTI]

The present invention relates to a process of using metal particles to reduce NO to NH{sub 3}. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: (a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20 and 90 C to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution. 34 figs.

Chang, S.G.; Littlejohn, D.; Shi, Y.

1997-08-19T23:59:59.000Z

330

Iron Speciation and Mixing in Single Aerosol Particles from the...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

iron from atmospheric aerosol is an essential nutrient that can control oceanic productivity, thereby impacting the global carbon budget and climate. Particles collected on...

331

Iron Cycling and Redox Evolution in the Precambrian  

E-Print Network [OSTI]

I use compilations of phosphorous and iron data in ironused upwelling dissolved phosphorous and ammonium as well asand adsorption of dissolved phosphorous onto microbial Fe

Planavsky, Noah John

2012-01-01T23:59:59.000Z

332

Iron(III)-doped, silica : biodegradable, self-targeting nanoparticles  

E-Print Network [OSTI]

of calcium and phosphorous, which can be attributed toamount of calcium and phosphorous increase. The iron(III)-composed of calcium and phosphorous were in the recovered

Mitchell, Kristina Kalani Pohaku

2011-01-01T23:59:59.000Z

333

The effects of copper and iron deficiencies in the chick  

E-Print Network [OSTI]

was assimilated by the chick. Cunningham (1931) and Josephs (1932) found that rats fed a milk diet plus iron showed no significant difference from rats fed milk plus sources of copper and iron. Elvehjem and Sherman (1932) reported that when rats de- ficient.../or iron as follows: Group Group Group Group Group Group 1 ? no added copper or iron 2 - cupric sulfate added (5 ppm) 3 - cupric oxide added (5 ppm) 4 ? ferrous sulfate added (40 ppm) 5 - cupric sulfate (5 ppm) plus ferrous sulfate added (40 ppm...

McGhee, Flin Cameron

1964-01-01T23:59:59.000Z

334

Iron acquisition and utilization by Rhodococcus equi: potential virulence factors  

E-Print Network [OSTI]

. . . . . . . . . . . . . . . . Growth of R. equi in minimal media (MM) and MM without iron 66 (MM-Fe) . . 67 12 13 Growth of R. equi in 100 ItM DIP + varying iron concentrations. . . . . . . . . 68 Effects of iron source (FeSO& or FeCls) onin vitro growth of R. equi. . . 69.... , virulence factors) against oxidative stress Three types of bacterial SODs have been described: those that contain either iron (Fe SOD), manganese (MnSOD), or copper-zinc (Cu-ZnSOD)(85). If the appropriate minerals are not available for production of SODs...

Carnes, Misty Lee

2002-01-01T23:59:59.000Z

335

Percolation Explains How Earth's Iron Core Formed | Stanford...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

history. Earth's present layered structure with a metallic core and an overlying silicate mantle would have required mechanisms to separate iron alloy from a silicate phase....

336

Public good dynamics drive evolution of iron acquisition strategies in natural bacterioplankton populations  

E-Print Network [OSTI]

A common strategy among microbes living in iron-limited environments is the secretion of siderophores, which can bind poorly soluble iron and make it available to cells via active transport mechanisms. Such siderophore–iron ...

Cordero, Otto X.

337

Tricking Iron into Acting like a Rare-earth Element | The Ames...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tricking Iron into Acting like a Rare-earth Element By slipping iron between two nitrogen atoms in a lithium matrix, researchers are able to trick iron into having magnetic...

338

A Comparison of Iron and Steel Production Energy Intensity in China and the U.S  

E-Print Network [OSTI]

pdf Association for Iron and Steel Technology (AIST). 2010a.American BOF Roundup. Iron & Steel Technology. November.for Iron and Steel Technology (AIST). 2010b. 2010 EAF

Price, Lynn

2014-01-01T23:59:59.000Z

339

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network [OSTI]

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

340

Crystal Structure of Iron-dependent Halogenase  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: Crude Oil Period-Unit:Iron-dependent Halogenase Over 4000

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Rare Iron Oxide in Ancient Chinese Pottery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising Science for1PrincipalRare Iron Oxide in Ancient Chinese

342

Suspension Hydrogen Reduction of Iron Oxide Concentrates  

SciTech Connect (OSTI)

The objective of the project is to develop a new ironmaking technology based on hydrogen and fine iron oxide concentrates in a suspension reduction process. The ultimate objective of the new technology is to replace the blast furnace and to drastically reduce CO2 emissions in the steel industry. The goals of this phase of development are; the performance of detailed material and energy balances, thermochemical and equilibrium calculations for sulfur and phosphorus impurities, the determination of the complete kinetics of hydrogen reduction and bench-scale testing of the suspension reduction process using a large laboratory flash reactor.

H.Y. Sohn

2008-03-31T23:59:59.000Z

343

Iron Availability in the Southern Ocean  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines | ornl.govIron

344

Iron Availability in the Southern Ocean  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctober 5,Octoberdeep |Iron

345

Iron Availability in the Southern Ocean  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctober 5,OctoberdeepIron

346

(Ir)reversibility in dense granular systems driven by oscillating forces  

E-Print Network [OSTI]

We use computer simulations to study highly dense systems of granular particles that are driven by oscillating forces. We implement different dissipation mechanisms that are used to extract the injected energy. In particular, the action of a simple local Stokes' drag is compared with non-linear and history-dependent frictional forces that act either between particle pairs or between particles and an external container wall. The Stokes' drag leads to particle motion that is periodic with the driving force, even at high densities around close packing where particles undergo frequent collisions. With the introduction of inter-particle frictional forces this "interacting absorbing state" is destroyed and particles start to diffuse around. By reducing the density of the material we go through another transition to a "non-interacting" absorbing state, where particles independently follow the force-induced oscillations without collisions. In the system with particle-wall frictional interactions this transition has signs of a discontinuous phase transition. It is accompanied by a diverging relaxation time, but not by a vanishing order parameter, which rather jumps to zero at the transition.

Ronny Moebius; Claus Heussinger

2014-04-07T23:59:59.000Z

347

Liquid-phase adsorption of organic compounds by granular activated carbon and activated carbon fibers  

SciTech Connect (OSTI)

Liquid-phase adsorption of organic compounds by granular activated carbon (GAC) and activated carbon fibers (ACFs) is investigated. Acetone, isopropyl alcohol (IPA), phenol, and tetrahydrofuran (THF) were employed as the model compounds for the present study. It is observed from the experimental results that adsorption of organic compounds by GAC and ACF is influenced by the BET (Brunauer-Emmett-Teller) surface area of adsorbent and the molecular weight, polarity, and solubility of the adsorbate. The adsorption characteristics of GAC and ACFs were found to differ rather significantly. In terms of the adsorption capacity of organic compounds, the time to reach equilibrium adsorption, and the time for complete desorption, ACFs have been observed to be considerably better than GAC. For the organic compounds tested here, the GAC adsorptions were shown to be represented well by the Langmuir isotherm while the ACF adsorption could be adequately described by the Langmuir or the Freundlich isotherm. Column adsorption tests indicated that the exhausted ACFs can be effectively regenerated by static in situ thermal desorption at 150 C, but the same regeneration conditions do not do as well for the exhausted GAC.

Lin, S.H.; Hsu, F.M. [Yuan Ze Inst. of Tech., Taoyuan (Taiwan, Province of China). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

348

Poroelastic measurement schemes resulting in complete data sets for granular and other anisotropic porous media  

SciTech Connect (OSTI)

Poroelastic analysis usually progresses from assumed knowledge of dry or drained porous media to the predicted behavior of fluid-saturated and undrained porous media. Unfortunately, the experimental situation is often incompatible with these assumptions, especially when field data (from hydrological or oil/gas reservoirs) are involved. The present work considers several different experimental scenarios typified by one in which a set of undrained poroelastic (stiffness) constants has been measured using either ultrasound or seismic wave analysis, while some or all of the dry or drained constants are normally unknown. Drained constants for such a poroelastic system can be deduced for isotropic systems from available data if a complete set of undrained compliance data for the principal stresses are available - together with a few other commonly measured quantities such as porosity, fluid bulk modulus, and grain bulk modulus. Similar results are also developed here for anisotropic systems having up to orthotropic symmetry if the system is granular (i.e., composed of solid grains assembled into a solid matrix, either by a cementation process or by applied stress) and the grains are known to be elastically homogeneous. Finally, the analysis is also fully developed for anisotropic systems with nonhomogeneous (more than one mineral type), but still isotropic, grains - as well as for uniform collections of anisotropic grains as long as their axes of symmetry are either perfectly aligned or perfectly random.

Berryman, J.G.

2009-11-20T23:59:59.000Z

349

Average balance equations, scale dependence, and energy cascade for granular materials  

E-Print Network [OSTI]

A new averaging method linking discrete to continuum variables of granular materials is developed and used to derive average balance equations. Its novelty lies in the choice of the decomposition between mean values and fluctuations of properties which takes into account the effect of gradients. Thanks to a local homogeneity hypothesis, whose validity is discussed, simplified balance equations are obtained. This original approach solves the problem of dependence of some variables on the size of the averaging domain obtained in previous approaches which can lead to huge relative errors (several hundred percentages). It also clearly separates affine and nonaffine fields in the balance equations. The resulting energy cascade picture is discussed, with a particular focus on unidirectional steady and fully developed flows for which it appears that the contact terms are dissipated locally unlike the kinetic terms which contribute to a nonlocal balance. Application of the method is demonstrated in the determination of the macroscopic properties such as volume fraction, velocity, stress, and energy of a simple shear flow, where the discrete results are generated by means of discrete particle simulation.

Riccardo Artoni; Patrick Richard

2015-03-09T23:59:59.000Z

350

Biodegradation of methyl tertiary butyl ether (MTBE) using a granular activated carbon trickling filter  

SciTech Connect (OSTI)

A pilot scale trickling filter was constructed using granular activated carbon (GAC) as the packing medium and inoculated with a microbial culture known to degrade MTBE. The packing dimensions were 0.076 m in diameter and 0.22 m deep. The unit operated with recycling flow for two months before a biofilm was observed on the GAC. After two additional months the biofilm had visibly spread throughout the packing. A few pieces of GAC were placed in a sealed bottle with MTBE-contaminated water and nutrients. Headspace analysis performed over 14 days confirmed that MTBE degradation was occurring. The trickling filter was converted to continuous flow and operated for one month at a nominal flow rate of 0.1 L/min and a hydraulic loading rate of 32 m{sup 3}/m{sup 2}-d. Samples were collected for analysis at the spray nozzle and at the bottom of the trickling filter. Fractional removal varied with influent MTBE concentration, temperature and liquid flow rate. Percent MTBE removal was as high as 85%. A mechanical failure resulted in the trickling filter bed drying and percent removal dropping to less than 1 percent. However, the system recovered within five days.

Converse, B.M.; Schroeder, E.D.; Chang, D.P.Y.

1999-07-01T23:59:59.000Z

351

Local heat flux and energy loss in a 2D vibrated granular gas  

E-Print Network [OSTI]

We performed event-driven simulations of a two-dimensional granular gas between two vibrating walls and directly measured the local heat flux and energy dissipation rate in the stationary state. Describing the local heat flux as a function of the coordinate x in the direction perpendicular to the driving walls, we use a generalization of Fourier's law, q_x(x) = kappa d_x T(x) + mu d_x rho(x), to relate the local heat flux to the local gradients of the temperature and density. This ansatz accounts for the fact that density gradients also generate heat flux, not only temperature gradients. The transport coefficients kappa and mu are assumed to be independent of x, and we check the validity of this assumption in the simulations. Both kappa and mu are determined for different system parameters, in particular, for a wide range of coefficients of restitution. We also compare our numerical results to existing hydrodynamic theories. Agreement is found for kappa for very small inelasticities only. Beyond this region, kappa and mu exhibit a striking non-monotonic behavior.

Olaf Herbst; Peter Müller; Annette Zippelius

2004-12-13T23:59:59.000Z

352

Using Disorder to Study How Electrons Pair in Iron-Based Superconducto...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Using Disorder to Study How Electrons Pair in Iron-Based Superconductors Researchers introduced disorder to test electron pairing in iron-based superconductors and produced...

353

Trophic status of Chlamydomonas reinhardtii influences the impact of iron deficiency on photosynthesis  

E-Print Network [OSTI]

of iron de?ciency on photosynthesis Aimee M. Terauchi •rates by suppress- ing photosynthesis but increasing insteadal. 2007). In oxygenic photosynthesis, iron is a cofactor in

Terauchi, Aimee M.; Peers, Graham; Kobayashi, Marilyn C.; Niyogi, Krishna K.; Merchant, Sabeeha S.

2010-01-01T23:59:59.000Z

354

E-Print Network 3.0 - ancient iron plate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oceans Noah... Keywords: iron-bacteria iron-formations Fe-isotopes rare earth elements Paleoproterozoic stromatolites We... conducted a geochemical and petrographic...

355

E-Print Network 3.0 - alpha elements iron Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gordon*a Keywords... : Asymmetric iron(II) amidinate Bridging ligands Metathesis Sublimation kinetics Thermochemistry... A highly volatile asymmetric iron(II) amidinate,...

356

Neutron Scattering Studies of Cuprates and Iron Pnictides.  

E-Print Network [OSTI]

??Presented within are neutron scattering studies of several different high temperature superconducting materials: BaFe1.9Ni0.1As2 [Barium Iron Nickel Arsenic], BaFe1.85Ni0.15As2 [Barium Iron Nickel Arsenic], Ba0.67K0.33Fe2As2 [Barium… (more)

Liu, Mengshu

2014-01-01T23:59:59.000Z

357

Enhanced Superconducting Properties of Iron Chalcogenide Thin Films  

E-Print Network [OSTI]

Among the newly discovered iron-based superconductor, FeSe with the simplest structure and a transition temperature (T_c) around 8 K arouses much research interest. Although its Tc is much lower than that of the cuprates, iron chalcogenide has low...

Chen, Li

2013-07-26T23:59:59.000Z

358

Next Generation Metallic Iron Nodule Technology in Electric Furnace Steelmaking  

Broader source: Energy.gov [DOE]

This factsheet describes a research project whose objective is to investigate reducing processing temperature, controlling the gas temperature and gas atmosphere over metalized iron nodules, and effectively using sub-bituminous coal as a reductant for producing high quality metalized iron nodules at low cost.

359

Investigation of Iron Aluminide Weld Overlays  

SciTech Connect (OSTI)

Conventional fossil fired boilers have been retrofitted with low NO(sub)x burners in order for the power plants to comply with new clean air regulations. Due to the operating characteristics of these burners, boiler tube sulfidation corrosion typically has been enhanced resulting in premature tube failure. To protect the existing panels from accelerated attack, weld overlay coatings are typically being applied. By depositing an alloy that offers better corrosion resistance than the underlying tube material, the wastage rates can be reduced. While Ni-based and stainless steel compositions are presently providing protection, they are expensive and susceptible to failure via corrosion-fatigue due to microsegregation upon solidification. Another material system presently under consideration for use as a coating in the oxidation/sulfidation environments is iron-aluminum. These alloys are relatively inexpensive, exhibit little microsegregation, and show excellent corrosion resistance. However, their use is limited due to weldability issues and their lack of corrosion characterization in simulated low NO(sub)x gas compositions. Therefore a program was initiated in 1996 to evaluate the use of iron-aluminum weld overlay coatings for erosion/corrosion protection of boiler tubes in fossil fired boilers with low NO(sub)x burners. Investigated properties included weldability, corrosion behavior, erosion resistance, and erosion-corrosion performance.

Banovic, S.W.; DuPont, J.B.; Levin, B.F.; Marder, A.R.

1999-08-02T23:59:59.000Z

360

Fabrication and processing of iron aluminides  

SciTech Connect (OSTI)

The Fe{sub 3}Al-based alloys have been shown to exhibit room-temperature ductility values of 15 to 19% by the control of composition and thermomechanical processing steps. The scale-up of one of the compositions to 2270-kg (5000-lb) electroslag-remelted (ESR) round ingot and 3272-kg (7200-lb) vacuum-induction-melted (VIM) slab ingot is described. Microstructural and mechanical property data are presented on small pieces sectioned from these ingots. The effects of final rolling temperature and the final annealing treatment on room-temperature ductility were investigated for the ESR ingot. A study of iron-aluminide binary alloys revealed that the environmental effects on room-temperature ductility values were absent for {le}8.5 wt % Al. The increasing aluminum content and the development of ordered structure resulted in increased environmental effects. Applications and a brief description of their status are described. Based on the combined property and cost advantage, continued development of iron aluminide is recommended.

Sikka, V.K.; Viswanathan, S.

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Fabrication and processing of iron aluminides  

SciTech Connect (OSTI)

The Fe{sub 3}Al-based alloys have been shown to exhibit room-temperature ductility values of 15 to 19% by the control of composition and thermomechanical processing steps. The scale-up of one of the compositions to 2270-kg (5000-lb) electroslag-remelted (ESR) round ingot and 3272-kg (7200-lb) vacuum-induction-melted (VIM) slab ingot is described. Microstructural and mechanical property data are presented on small pieces sectioned from these ingots. The effects of final rolling temperature and the final annealing treatment on room-temperature ductility were investigated for the ESR ingot. A study of iron-aluminide binary alloys revealed that the environmental effects on room-temperature ductility values were absent for {le}8.5 wt % Al. The increasing aluminum content and the development of ordered structure resulted in increased environmental effects. Applications and a brief description of their status are described. Based on the combined property and cost advantage, continued development of iron aluminide is recommended.

Sikka, V.K.; Viswanathan, S.

1992-07-01T23:59:59.000Z

362

System and method for producing metallic iron nodules  

DOE Patents [OSTI]

A method for producing metallic iron nodules by assembling a shielding entry system to introduce coarse carbonaceous material greater than 6 mesh in to the furnace atmosphere at location(s) where the temperature of the furnace atmosphere adjacent at least partially reduced reducible iron bearing material is between about 2200 and 2650.degree. F. (1200 and 1450.degree. C.), the shielding entry system adapted to inhibit emission of infrared radiation from the furnace atmosphere and seal the furnace atmosphere from exterior atmosphere while introducing coarse carbonaceous material greater than 6 mesh into the furnace to be distributed over the at least partially reduced reducible iron bearing material, and heating the covered at least partially reduced reducible iron bearing material in a fusion atmosphere to assist in fusion and inhibit reoxidation of the reduced material during fusion to assist in fusion and inhibit reoxidation of the reduced material in forming metallic iron nodules.

Bleifuss, Rodney L. (Grand Rapids, MN); Englund, David J. (Bovey, MN); Iwasaki, Iwao (Grand Rapids, MN); Lindgren, Andrew J. (Grand Rapids, MN); Kiesel, Richard F. (Hibbing, MN)

2011-09-20T23:59:59.000Z

363

The iron powder test for naphthenic acid corrosion studies  

SciTech Connect (OSTI)

In the course of an ongoing investigation into the phenomenon of naphthenic acid corrosion, a new test method has evolved and is currently being further developed to substitute the total acid number (TAN or neutralization number) as an indicator for naphthenic acid corrosion potential. It can also be used to complement conventional autoclave corrosion tests in high temperature environments, which are based on weight loss of steel coupons. In this new method an oil sample reacts with pure iron powder within an autoclave heated to the testing temperature. The result is based on the amount of dissolved iron found in the oil sample. The oil sample can dissolve an amount of iron for a given time at a given temperature, depending on the naphthenic acid corrosion, since these acids react with iron to produce oil soluble iron naphthenates. This paper describes the method, compares it with conventional crude corrosiveness testing, and proposes it as a new way of measuring naphthenic acid corrosion potential.

Hau, J.L.; Yepez, O.; Specht, M.I.; Lorenzo, R. [PDVSA-Intevep, Caracas (Venezuela)

1999-11-01T23:59:59.000Z

364

MOSSBAUER STUDIES ON THE STATE OF TIN ATOMS SEGREGATED AT THE GRAIN BOUNDARY OF IRON AND IRON ALLOYS  

E-Print Network [OSTI]

MOSSBAUER STUDIES ON THE STATE OF TIN ATOMS SEGREGATED AT THE GRAIN BOUNDARY OF IRON AND IRON, Tokyo, Japan Abstract.- The binding state of tin atoms segregated at the grain boundary of fine grained state differs considerably from that of solid solution tin even though the average binding force itself

Paris-Sud XI, Université de

365

Insulating state of granular superconductors in a strong-coupling regime I. S. Beloborodov,1 Ya. V. Fominov,1,2 A. V. Lopatin,1 and V. M. Vinokur1  

E-Print Network [OSTI]

Insulating state of granular superconductors in a strong-coupling regime I. S. Beloborodov,1 Ya. V-field-induced insulating state in a two-dimensional granular superconductor with relatively strong intergranular coupling the superconductor-insulator transi- tion, and a reentrant drop upon further increase of magnetic field. The magnetic

Fominov, Yakov

366

Time series of high resolution photospheric spectra in a quiet region of the Sun. II. Analysis of the variation of physical quantities of granular structures  

E-Print Network [OSTI]

From the inversion of a time series of high resolution slit spectrograms obtained from the quiet sun, the spatial and temporal distribution of the thermodynamical quantities and the vertical flow velocity is derived as a function of logarithmic optical depth and geometrical height. Spatial coherence and phase shift analyzes between temperature and vertical velocity depict the height variation of these physical quantities for structures of different size. An average granular cell model is presented, showing the granule-intergranular lane stratification of temperature, vertical velocity, gas pressure and density as a function of logarithmic optical depth and geometrical height. Studies of a specific small and a specific large granular cell complement these results. A strong decay of the temperature fluctuations with increasing height together with a less efficient penetration of smaller cells is revealed. The T -T coherence at all granular scales is broken already at log tau =-1 or z~170 km. At the layers beyon...

Puschmann, K G; Vazquez, M; Bonet, J A; Hanslmeier, A; 10.1051/0004-6361:20047193

2012-01-01T23:59:59.000Z

367

Use of Separator with Regular Granular Filling in Extraction Processes - 12209  

SciTech Connect (OSTI)

The separator with a regular granular filling has been developed to be used for the operations of the removal of carbon-black impurities from the aqueous flow; the intra-cycle regeneration of back-extractants; and the concentrating back-extraction of plutonium in the extraction SNF reprocessing technology. The process conditions for those operations have been experimentally tested using this separator. Thus, the separator for operations of concentrating reextraction of plutonium and regeneration recycling extractant allows to: - derive plutonium from the organic stream into an extremely concentrated form, reducing the amount of liquid radioactive waste (raffinate, decantate) plutonium branches to a minimum; - controlling the processes of concentration of uranium and plutonium, get uranium-plutonium product with required concentration and the amount of metal with required ratio; - eliminate contamination of the emulsion flows; - simplify the purification of uranium from the extract plutonium; - test results showed that when working on a solution 'hydrazine-DTPA' in the separator it is achieved the extraction of plutonium re-extract - 82% TC - at 56-65%. With the transition to the reextraction by solution 'U (IV)-hydrazine', of plutonium into re-extract increases to 95%, technetium - up to 83%; - regenerate the extractant recycling minimizing the amount of liquid radioactive waste generated as a technology used as well as alternative 'salt-free' systems; - it is found that the regeneration of the extractant solution of soda and EDA in the separator at a load of 3.2 m{sup 3} / (m{sup 2}.h) it can be achieved almost complete phase separation. Residual carryover of 0,005-0,006% emulsion is on the verge of analytical detection. - It is shown that in the depth of separation phase a separation of the extractant regeneration of quality superior is more than 5-7 times to the extraction. (authors)

Volk, Vladimir; Veselov, Sergey; Zherebtsov, Alexander [Joint Stock Company 'A.A. Bochvar High-Technology Scientific Research Institute of Inorganic Materials' (VNIINM), Rogova st., 5A (Russian Federation)

2012-07-01T23:59:59.000Z

368

THE ROLE OF FERRIC IRON UPTAKE REGULATOR (FUR) PROTEIN ON IRON REGULATION IN COXIELLA BURNETII  

E-Print Network [OSTI]

at 37?C for overnight. These cultures were then subcultured in 5mL media with either 50uM ferrous chloride or 200uM deferoxamine, an iron chelator until an OD600 of 0.45-0.55 was reached and the assay performed. Plasmids/Strain#7;Description#7;Source#7... Solution, 98mM KH2PO4, 270mM KCl, 26.8mM NaCl, 40mM MgCl, 0.2mM glucose, 2x spermine, 2x erythritol, 2x para-aminobenzoic acid, 2x NADH, 2x adenine, 2x hypoxanthine, 2x uracil) (Beare, personal communication) with 0uM, 10uM or 50uM iron sulfate. After...

Wilson, Mary J

2006-08-16T23:59:59.000Z

369

Kinetics of dissolution and bio-availability of iron in amorphous siliceous iron oxides  

E-Print Network [OSTI]

A&M University Chair of Advisory Committee: Dr. Richard H. Loeppert Amorphous iron (Fe) oxides are of interest because of their high reactivity, surface area, and influence on Fe availability in the soil environment. These materials may have... potential utilization as slow-release Fe amendments for calcareous soils. The objective of this study was to evaluate the impact of various concentrations of silicon (Si), present during precipitation, on the dissolution kinetics of amorphous Fe oxides...

Seaman, John C.

1990-01-01T23:59:59.000Z

370

Theoretical Investigation of Hydrogen Adsorption and Dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method  

SciTech Connect (OSTI)

We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of Fischer–Tropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

2012-06-01T23:59:59.000Z

371

System and method for producing metallic iron  

DOE Patents [OSTI]

A hearth furnace for producing metallic iron material has a furnace housing having a drying/preheat zone, a conversion zone, a fusion zone, and optionally a cooling zone, the conversion zone is between the drying/preheat zone and the fusion zone. A moving hearth is positioned within the furnace housing. A hood or separation barrier within at least a portion of the conversion zone, fusion zone or both separates the fusion zone into an upper region and a lower region with the lower region adjacent the hearth and the upper region adjacent the lower region and spaced from the hearth. An injector introduces a gaseous reductant into the lower region adjacent the hearth. A combustion region may be formed above the hood or separation barrier.

Bleifuss, Rodney L; Englund, David J; Iwasaki, Iwao; Fosnacht, Donald R; Brandon, Mark M; True, Bradford G

2013-09-17T23:59:59.000Z

372

Iron and steel industry process model  

SciTech Connect (OSTI)

The iron and steel industry process model depicts expected energy-consumption characteristics of the iron and steel industry and ancillary industries for the next 25 years by means of a process model of the major steps in steelmaking, from ore mining and scrap recycling to the final finishing of carbon, alloy, and stainless steel into steel products such as structural steel, slabs, plates, tubes, and bars. Two plant types are modeled: fully integrated mills and mini-mills. User-determined inputs into the model are as follows: projected energy and materials prices; projected costs of capacity expansion and replacement; energy-conserving options, both operating modes and investments; the internal rate of return required on investment; and projected demand for finished steel. Nominal input choices in the model for the inputs listed above are as follows: National Academy of Sciences Committee on Nuclear and Alternative Energy Systems Demand Panel nominal energy-price projections for oil, gas, distillates, residuals, and electricity and 1975 actual prices for materials; actual 1975 costs; new technologies added; 15% after taxes; and 1975 actual demand with 1.5%/y growth. The model reproduces the base-year (1975) actual performance of the industry; then, given the above nominal input choices, it projects modes of operation and capacity expansion that minimize the cost of meeting the given final demands for each of 5 years, each year being the midpoint of a 5-year interval. The output of the model includes the following: total energy use and intensity (Btu/ton) by type, by process, and by time period; energy conservation options chosen; utilization rates for existing capacity; capital-investment decisions for capacity expansion.

Sparrow, F.T.; Pilati, D.; Dougherty, T.; McBreen, E.; Juang, L.L.

1980-01-01T23:59:59.000Z

373

Discrete element modelling of iron ore pellets to include the effects of moisture and fines   

E-Print Network [OSTI]

Across industry the majority of raw materials handled are particulate in nature, ranging in size and properties from aggregates to powders. The stress regimes experienced by the granular solids vary and the exhibited ...

Morrissey, John Paul

2013-11-28T23:59:59.000Z

374

RUSTY OLD STARS: A SOURCE OF THE MISSING INTERSTELLAR IRON?  

SciTech Connect (OSTI)

Iron, the universe's most abundant refractory element, is highly depleted in both circumstellar and interstellar environments, meaning it exists in solid form. The nature of this solid is unknown. In this Letter, we provide evidence that metallic iron grains are present around oxygen-rich asymptotic giant branch stars, where it is observationally manifest as a featureless mid-infrared excess. This identification is made using Spitzer Space Telescope observations of evolved globular cluster stars, where iron dust production appears ubiquitous and in some cases can be modeled as the only observed dust product. In this context, FeO is examined as the likely carrier for the 20 {mu}m feature observed in some of these stars. Metallic iron appears to be an important part of the dust condensation sequence at low metallicity, and subsequently plays an influential role in the interstellar medium. We explore the stellar metallicities and luminosities at which iron formation is observed, and how the presence of iron affects the outflow and its chemistry. The conditions under which iron can provide sufficient opacity to drive a wind remain unclear.

McDonald, I.; Zijlstra, A. A.; Markwick, A. J. [Jodrell Bank Centre for Astrophysics, Alan Turing Building, Manchester, M13 9PL (United Kingdom); Sloan, G. C.; Bernard-Salas, J. [Cornell University, Astronomy Department, Ithaca, NY 14853-6801 (United States); Matsunaga, N. [Institute of Astronomy, University of Tokyo, 2-21-1 Osawa, Mitaka, Tokyo 181-0015 (Japan); Matsuura, M. [UCL-Institute of Origins, Astrophysics Group, Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Kraemer, K. E., E-mail: iain.mcdonald-2@jb.man.ac.u, E-mail: albert.zijlstra@manchester.ac.u, E-mail: andrew.markwick@manchester.ac.u, E-mail: sloan@isc.astro.cornell.ed, E-mail: matsunaga@ioa.s.u-tokyo.ac.j, E-mail: mikako@star.ucl.ac.u [Air Force Research Laboratory, Space Vehicles Directorate, Hanscom AFB, MA 01731 (United States)

2010-07-10T23:59:59.000Z

375

Iron aluminide alloy coatings and joints, and methods of forming  

DOE Patents [OSTI]

Disclosed is a method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: (a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; (b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; (c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600 C to less than the melting point of the lower melting point body; (d) applying pressure on the juxtaposed surfaces; and (e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

Wright, R.N.; Wright, J.K.; Moore, G.A.

1994-09-27T23:59:59.000Z

376

Iron aluminide alloy coatings and joints, and methods of forming  

DOE Patents [OSTI]

A method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600.degree. C. to less than the melting point of the lower melting point body; d) applying pressure on the juxtaposed surfaces; and e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

Wright, Richard N. (Idaho Falls, ID); Wright, Julie K. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID)

1994-01-01T23:59:59.000Z

377

Iron/soot interaction in a laminar ethylene nonpremixed flame  

SciTech Connect (OSTI)

A laminar, coannular, ethylene/air nonpremixed flame doped with ferrocene additive is employed to address the fundamental question of how iron becomes incorporated into the carbonaceous soot phase, thus interfering with the soot formation processes. The structure and chemical composition of individual aggregates are characterized with respect to flame coordinates via a combination of thermophoretic sampling, transmission electron microscopy, and energy dispersive spectrometry. Soot aggregate microstructure clearly reveals iron occlusion, as well as stratification of soot layers over the occluded phase. The study provides physical evidence that the soot and iron compounds combine in the flame to form a hybrid (inhomogeneous) particulate phase. The reported observations are consistent with the hypothesis that ferrocene decomposes early in the combustion process and before the onset of soot particle inception, thus forming a fine aerosol for the subsequent deposition of carbonaceous substances. Examination of a series of inhomogeneous soot aggregates shows that the flame aerosol composition varies with flame coordinates. In particular, aggregates transported in the soot annulus near the luminous flame front are primarily composed of carbon and oxygen, with traces of iron finely dispersed through the aggregate matrix. On the other hand, carbonaceous soot transported at low heights and near the flame axis contains iron in its elemental form. Finally, soot aggregates in all other areas of the flame contain both iron and oxygen, thus implying the possible presence of iron oxides within the carbonaceous matrix.

Zhang, J.; Megaridis, C.M. [Univ. of Illinois, Chicago, IL (United States). Dept. of Mechanical Engineering

1994-12-31T23:59:59.000Z

378

Spall behavior of cast iron with varying microstructures  

SciTech Connect (OSTI)

The spall strength of cast iron with varying microstructures has been investigated using plate impact at moderate speed. Stress history measurements were made with manganin stress gauges embedded between the back face of the specimen and a low impedance polycarbonate backing. Five separate cast irons were tested. Four of these consisted of gray cast iron with graphite in flake form, with three classified as Type VII A2 and the fourth containing a bimodal distribution of Types VII A4 and VII D8. The fifth casting consisted of ductile cast iron with graphite in nodular form, classified as Type I, size class 5. The spall strength for the Type VII A2 gray cast irons varied between 40 and 370?MPa, and that of the additional gray cast iron, between 410 and 490?MPa. The spall strength of the ductile cast iron fell within the range of 0.94–1.2?GPa. It is shown that the spall strength is linked to the damage level at the spall plane, where an increased level of tensile stress is required to generate higher levels of damage. Post mortem analysis was performed on the recovered samples, revealing the graphite phase to be the primary factor governing the spall fracture of cast irons, where crack nucleation is directly correlated to the debonding of graphite from the metal matrix. The average length of graphite found within a casting is linked to the material's strength, where strength increases as a function of decreasing length. The morphology and mean free path of graphite precipitates further govern the subsequent coalescence of initiated cracks to form a complete fracture plane. In cases where graphite spacing is large, increased energy level is required to complete the fracture process. A secondary factor governing the spall fracture of cast irons has also been linked to the microstructure of the metal matrix, with pearlite yielding higher spall strengths than free ferrite.

Plume, Gifford; Rousseau, Carl-Ernst, E-mail: rousseau@uri.edu [Mechanical Engineering, University of Rhode Island, 92 Upper College Rd., Kingston, Rhode Island 02881 (United States)

2014-07-21T23:59:59.000Z

379

Iron-carbon compacts and process for making them  

DOE Patents [OSTI]

The present invention includes iron-carbon compacts and a process for making them. The process includes preparing a slurry comprising iron powder, furfuryl alcohol, and a polymerization catalyst for initiating the polymerization of the furfuryl alcohol into a resin, and heating the slurry to convert the alcohol into the resin. The resulting mixture is pressed into a green body and heated to form the iron-carbon compact. The compact can be used as, or machined into, a magnetic flux concentrator for an induction heating apparatus.

Sheinberg, Haskell (Santa Fe, NM)

2000-01-01T23:59:59.000Z

380

Iron is the Key to Preserving Dinosaur Soft Tissue  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines | ornl.govIronIronIron

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Iron is the Key to Preserving Dinosaur Soft Tissue  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctoberOxide WasteIronIronIron

382

Snapshot of iron response in Shewanella oneidensis by gene network reconstruction  

E-Print Network [OSTI]

dissection of the Helicobacter pylori Fur regulatory circuitregulation of the Helicobacter pylori iron-cofactored

Harris, Daniel P.

2010-01-01T23:59:59.000Z

383

Cast B2-phase iron-aluminum alloys with improved fluidity  

DOE Patents [OSTI]

Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

2002-01-01T23:59:59.000Z

384

BLAST FURNACE GRANULAR COAL INJECTION SYSTEM. Final Report Volume 2: Project Performance and Economics  

SciTech Connect (OSTI)

Bethlehem Steel Corporation (BSC) requested financial assistance from the Department of Energy (DOE), for the design, construction and operation of a 2,800-ton-per-day blast furnace granulated coal injection (BFGCI) system for two existing iron-making blast furnaces. The blast furnaces are located at BSC's facilities in Burns Harbor, Indiana. The demonstration project proposal was selected by the DOE and awarded to Bethlehem in November 1990. The design of the project was completed in December 1993 and construction was completed in January 1995. The equipment startup period continued to November 1995 at which time the operating and testing program began. The blast furnace test program with different injected coals was completed in December 1998.

Unknown

1999-10-01T23:59:59.000Z

385

anthropogenic iron cycles: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tion in the average odds of each feature occurring within Sandercock, Brett K. 42 Solar Cycle Variations in the Elemental Abundance of Helium and Fractionation of Iron in the...

386

Mechanism of iron catalysis of carbon monoxide decomposition in refractories  

SciTech Connect (OSTI)

The authors discuss the catalytic effects of selected iron phases (metals, oxides, sulfides, and carbides) on the Boudouard reaction studied in an effort to more fully understand the disintegration of refractories when exposed to CO for long periods of time. It was found that active Fe atoms generated from the reduction of the iron oxides, especially {alpha}-Fe/sub 2/O/sub 3/, are the actual catalysts for the Boudouard reaction. The catalytic process confirmed by thermodynamic calculations, kinetic data, and X-ray diffraction data, consists of adsorption and decomposition of CO simultaneously forming carbides of iron. The chemisorption and subsequent decomposition of the iron carbides, rather than diffusion, constitute the rate-controlling process for carbon deposition.

Xu, M.W.P.; Brown, J.J. Jr. (Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (USA). Dept. of Materials Engineering)

1989-01-01T23:59:59.000Z

387

Simulation of iron impurity gettering in crystalline silicon solar cells  

E-Print Network [OSTI]

This work discusses the Impurity-to-Efficiency (12E) simulation tool and applet. The 12E simulator models the physics of iron impurity gettering in silicon solar cells during high temperature processing. The tool also ...

Powell, Douglas M. (Douglas Michael)

2012-01-01T23:59:59.000Z

388

Magnetism and Superconductivity Compete in Iron-based Superconductors...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Magnetism and Superconductivity Compete in Iron-based Superconductors Wednesday, April 30, 2014 HTSC Figure 1 Fig. 1. Measured electronic structure of underdoped Ba1-xKxFe2As2 in...

389

Evidence for a Weak Iron Core at Earth's Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iron Core at Earth's Center Print Seismic waves that pass through the center of the Earth travel faster going from pole to pole than along the equatorial plane-why? One theory...

390

The Iron Spin Transition in the Earth's Lower Mantle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons....

391

The Iron Spin Transition in the Earth's Lower Mantle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2008 00:00 It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons....

392

Modernization of the iron making plant at SOLLAC FOS  

SciTech Connect (OSTI)

When the blast furnaces at SOLLAC/FOS were relined, the objective being to ensure a worklife of 15 years, it was decided that the iron making plant would be modernized at the same time: the coking plant has been overhauled and renovated and its coking time increased to ensure a worklife of at least 34 years. The surface area of the sinter strand was increased from 400 to 520 m{sup 2}, the burden preparation circuit were simplified, and pig iron production capacity increased from 4.2 to 4.5 million metric tons per year. Coal injection was developed so as to obtain 170 kg/t of pig iron, an expert system was added to ensure more efficient blast furnace operation, and new measures have been carried out for environmental protection. Since these heavy investments have been completed, SOLLAC/FOS is a high-performance iron making plant, allowing it to face new challenges in the future.

Crayelynghe, M. van; Dufour, A.; Soland, J.; Feret, J.; Lebonvallet, J.

1995-12-01T23:59:59.000Z

393

LIQUID PHASE SINTERING OF IRON WITH COPPER BASE ALLOY POWDERS  

E-Print Network [OSTI]

Symposium on Powder Metallurgy - The Iron and Steel Inst.a Liquid Phase", Powder Metallurgy, 17 (33), 227 (1974). H.Other made by powder metallurgy techniques. ses to produce

Chen, M.-H.

2010-01-01T23:59:59.000Z

394

Metal Reduction and Iron Biomineralization by a Psychrotolerant...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sp. strain PV-4, from the microbial mat at a hydrothermal vent of Loihi Seamount in the Pacific Ocean has been further characterized, with emphases on metal reduction and iron...

395

Method and system for producing metallic iron nuggets  

DOE Patents [OSTI]

A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

Iwasaki, Iwao; Kiesel, Richard F.; Englund, David J; Hendrickson, Dave

2012-12-18T23:59:59.000Z

396

Iron-oxide catalyzed silicon photoanode for water splitting  

E-Print Network [OSTI]

This thesis presents an integrated study of high efficiency photoanodes for water splitting using silicon and iron-oxide. The fundamental limitations of silicon to water splitting applications were overcome by an ultrathin ...

Jun, Kimin

2011-01-01T23:59:59.000Z

397

Process for removing technetium from iron and other metals  

DOE Patents [OSTI]

A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

Leitnaker, J.M.; Trowbridge, L.D.

1999-03-23T23:59:59.000Z

398

Process for removing technetium from iron and other metals  

DOE Patents [OSTI]

A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag.

Leitnaker, James M. (Kingston, TN); Trowbridge, Lee D. (Oak Ridge, TN)

1999-01-01T23:59:59.000Z

399

Energy intensity in China's iron and steel sector  

E-Print Network [OSTI]

In this study, I examine the spatial and economic factors that influence energy intensity in China's iron and steel sector, namely industrial value added, renovation investment, coke consumption, and local coke supply. ...

Xu, Jingsi, M.C.P. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

400

Polymer-coated iron oxide nanoparticles for medical imaging  

E-Print Network [OSTI]

One of the most versatile and safe materials used in medicine are polymer-coated iron oxide nanoparticles. This dissertation describes several formulations for in vivo imaging applications. The paramagnetic polymer-coated ...

Chen, Suelin, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Microstructure of thin-wall ductile iron castings  

SciTech Connect (OSTI)

The automotive industry is seeking to replace current car parts made of aluminum and iron castings with thin wall (down to 2 mm) iron castings to reduce the cost and weight of automobiles. The mechanical properties of thin wall ductile iron castings are affected strongly by the thickness of the castings. The thinner castings cool at a faster rate, and microstructural features that form during solidification, and subsequently, transform in the solid state, are strongly dependent on a geometrical parameter related to the ratio of surface area-to-volume of the casting. As this ratio becomes larger, castings cool faster. As a result, the nodule count on the observation plane of the specimens increases dramatically (>2000 nodules/mm2 in most specimens), i.e. as the thickness of castings decreases. Also, the matrix of the thin walled ductile iron castings becomes more ferritic as the ratio of surface area-to-volume decreases.

Dogan, Omer N.; Schrems, Karol K.; Hawk, Jeffrey A.; Druschitz, A.P. (Intermet Corp., Lynchburg, VA)

2001-10-01T23:59:59.000Z

402

The relationship between iron and nitrogen fixation in Trichodesmium spp.  

E-Print Network [OSTI]

Trichodesmium spp. are considered the dominant nitrogen (N) fixing cyanobacteria in tropical and subtropical oceans, regimes frequently characterized by low iron (Fe). Limited information exists about what levels of Fe ...

Chappell, Phoebe Dreux

2009-01-01T23:59:59.000Z

403

Verification of Steelmaking Slags Iron Content Final Technical Progress Report  

SciTech Connect (OSTI)

The steel industry in the United States generates about 30 million tons of by-products each year, including 6 million tons of desulfurization and BOF/BOP slag. The recycling of BF (blast furnace) slag has made significant progress in past years with much of the material being utilized as construction aggregate and in cementitious applications. However, the recycling of desulfurization and BOF/BOP slags still faces many technical, economic, and environmental challenges. Previous efforts have focused on in-plant recycling of the by-products, achieving only limited success. As a result, large amounts of by-products of various qualities have been stockpiled at steel mills or disposed into landfills. After more than 50 years of stockpiling and landfilling, available mill site space has diminished and environmental constraints have increased. The prospect of conventionally landfilling of the material is a high cost option, a waste of true national resources, and an eternal material liability issue. The research effort has demonstrated that major inroads have been made in establishing the viability of recycling and reuse of the steelmaking slags. The research identified key components in the slags, developed technologies to separate the iron units and produce marketable products from the separation processes. Three products are generated from the technology developed in this research, including a high grade iron product containing about 90%Fe, a medium grade iron product containing about 60% Fe, and a low grade iron product containing less than 10% Fe. The high grade iron product contains primarily metallic iron and can be marketed as a replacement of pig iron or DRI (Direct Reduced Iron) for steel mills. The medium grade iron product contains both iron oxide and metallic iron and can be utilized as a substitute for the iron ore in the blast furnace. The low grade iron product is rich in calcium, magnesium and iron oxides and silicates. It has a sufficient lime value and can be utilized for acid mine drainage treatment. Economic analysis from this research demonstrates that the results are favorable. The strong demand and the increase of price of the DRI and pig iron in recent years are particularly beneficial to the economics. The favorable economics has brought commercial interests. ICAN Global has obtained license agreement on the technology from Michigan Tech. This right was later transferred to the Westwood Land, Inc. A demonstration pilot plant is under construction to evaluate the technology. Steel industry will benefit from the new supply of the iron units once the commercial plants are constructed. Environmental benefits to the public and the steel industry will be tremendous. Not only the old piles of the slag will be removed, but also the federal responsible abandoned mines from the old mining activities can be remediated with the favorable product generated from the process. Cost can be reduced and there will be no lime required, which can avoid the release of carbon dioxide from lime production process.

J.Y. Hwang

2006-10-04T23:59:59.000Z

404

The industrial ecology of the iron casting industry  

E-Print Network [OSTI]

Metal casting is an energy and materials intensive manufacturing process, which is an important U.S. industry. This study analyzes iron casting, in particular, for possible improvements that will result in greater efficiencies ...

Jones, Alissa J. (Alissa Jean)

2007-01-01T23:59:59.000Z

405

Surface modifications of iron oxide nanoparticles for biological applications  

E-Print Network [OSTI]

Iron oxides magnetic nanoparticles (MPs) of high crystallinity, high magnetization, and size-monodispersity were synthesized with oleic acid as their native ligands. These hydrophobic and non-functionalized MPs have magnetic ...

Insin, Numpon

2011-01-01T23:59:59.000Z

406

Iron limitation and the role of Siderophores in marine Synechococcus  

E-Print Network [OSTI]

Marine cyanobacteria in the genus Synechococcus are widely distributed and contribute significantly to global primary productivity. In many parts of the ocean their growth is limited by a lack of iron, an essential nutrient ...

Rivers, Adam R. (Adam Reid)

2009-01-01T23:59:59.000Z

407

Neutron scattering study of the iron based superconductors.  

E-Print Network [OSTI]

??In most iron-based and copper-oxide superconductors, the Tc [superconducting critical temperature] gradually increases upon charge carrier doping or isovalent doping. In the under-doped regime of… (more)

Wang, Miaoyin

2013-01-01T23:59:59.000Z

408

SLURRY PHASE IRON CATALYSTS FOR INDIRECT COAL LIQUEFACTION  

SciTech Connect (OSTI)

This report describes research conducted to support the DOE program in indirect coal liquefaction. Specifically, they have studied the attrition behavior of iron Fischer-Tropsch catalysts, their interaction with the silica binder and the evolution of iron phases in a synthesis gas conversion process. The results provide significant insight into factors that should be considered in the design of catalysts for converting coal based syngas into liquid fuels.

Abhaya K. Datye

1998-11-19T23:59:59.000Z

409

Slurry Phase Iron Catalysts for Indirect Coal Liquefaction  

SciTech Connect (OSTI)

This report describes research conducted to support the DOE program in indirect coal liquefaction. Specifically, we have studied the attrition behavior of Iron Fischer-Tropsch catalysts, their interaction with the silica binder and the evolution of iron phases in a synthesis gas conversion process. The results provide significant insight into factors that should be considered in the design of catalysts for the conversion of coal-derived synthesis gas into liquid fuels.

Abhaya K. Datye

1998-09-10T23:59:59.000Z

410

Methyl arsenic adsorption and desorption behavior on iron oxides  

E-Print Network [OSTI]

METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 2004 Major Subject: Soil Science METHYL ARSENIC ADSORPTION AND DESORPTION BEHAVIOR ON IRON OXIDES A Thesis by BRANDON JAMES LAFFERTY Submitted to Texas A&M University...

Lafferty, Brandon James

2005-08-29T23:59:59.000Z

411

Near-field Second Harmonic Imaging of Granular Membrane Structures in Natural Killer Richard D. Schaller, Claude Roth, David H. Raulet, and Richard J. Saykally*,  

E-Print Network [OSTI]

Near-field Second Harmonic Imaging of Granular Membrane Structures in Natural Killer Cells Richard) cells were recorded at four different wavelengths using a tunable near-infrared femtosecond laser membrane. Introduction Natural killer cells are a class of white blood cells that attack pathogen

Cohen, Ronald C.

412

Fastest Path Determination at Lane Granularity using a Vehicle-to-Vehicle-to-Infrastructure (V2V2I) Intelligent Transportation System Architecture  

E-Print Network [OSTI]

-to- vehicle-to-infrastructure (V2V2I) architecture, which is a hybrid of the vehicle-to-vehicle (V2VFastest Path Determination at Lane Granularity using a Vehicle-to-Vehicle-to- Infrastructure (V2V2I University of Alaska, Anchorage jmiller@uaa.alaska.edu Abstract ­ In this paper, I describe the vehicle

Miller, Jeffrey A.

413

Reorganization of a dense granular assembly: The unjamming response function Evelyne Kolb,* Jean Cviklinski,* Jose Lanuza,* Philippe Claudin,* and Eric Clement*  

E-Print Network [OSTI]

like foams, emulsions, or granular systems share in common many rheological properties 1 . All of the dynamics which led Liu and Nagel 1 to propose an analogy between the process of jamming and the glass transition for glass-forming liquids. Although the na- ture of this jamming transition is still unclear

414

Electrodeposition of binary iron-group alloys  

SciTech Connect (OSTI)

Thin films of NiCo and CoFe have been galvanostatically electroplated onto a platinum rotating disk electrode from simple sulfate baths containing 0.5M of the more noble metal sulfate and 0.1M of the less noble metal sulfate. The experimental results are compared to those of previous studies of NiFe codeposition in order to study the anomalous codeposition behavior of the binary iron-group alloys. Comparison of the electrodeposition results indicates that codeposition of these binary alloys is not totally analogous. It was found that codeposition of NiCo and NiFe show more mass-transfer effects than does CoFe deposition within the range of current densities studied. A model of anomalous codeposition put forth previously for NiFe was applied to the electrodeposition of NiCo and CoFe to determine the extensibility of the model, which assumes metal mono hydroxides, MOH{sup +}, are the important charge-transfer species. This model was unable to characterize fully either NiCo or CoFe electrodeposition. However, with minor changes to the hydrolysis constants used in the model, the model predictions were found to agree with the data for CoFe codeposition and greatly, improve the fit for the NiCo results.

Sasaki, K.Y.; Talbot, J.B. [Univ. of California, San Diego, La Jolla, CA (United States)

1995-03-01T23:59:59.000Z

415

Treatability study for removal of leachable mercury in crushed fluorescent lamps  

SciTech Connect (OSTI)

Nonserviceable fluorescent lamps removed from radiological control areas at the Oak Ridge Department of Energy facilities have been crushed and are currently managed as mixed waste (hazardous and radiologically contaminated). We present proposed treatment flowsheets and supporting treatability study data for conditioning this solid waste residue so that it can qualify for disposal in a sanitary landfill. Mercury in spent fluorescent lamps occurs primarily as condensate on high-surface-area phosphor material. It can be solubilized with excess oxidants (e.g., hypochlorite solution) and stabilized by complexation with halide ions. Soluble mercury in dechlorinated saline solution is effectively removed by cementation with zero-valent iron in the form of steel wool. In packed column dynamic flow testing, soluble mercury was reduced to mercury metal and insoluble calomel, loading > 1.2 g of mercury per grain of steel wool before an appreciable breakthrough of soluble mercury in the effluent.

Bostick, W.D.; Beck, D.E.; Bowser, K.T. [and others

1996-02-01T23:59:59.000Z

416

Interplay between interband coupling and ferromagnetism in iron pnictide superconductor/ferromagnet/iron pnictide superconductor junctions  

SciTech Connect (OSTI)

An extended eight-component Bogoliubov-de Gennes equation is applied to study the Josephson effect between iron-based superconductors (SCs) with s{sub ±}-wave pairing symmetry, separated by an ferromagnet (FM). The feature of damped oscillations of critical Josephson current as a function of FM thickness, the split of the peaks induced by the interband coupling is much different from that for the junction with the s{sub ±}-wave SCs replaced by s{sub ++}-wave ones. In particular, a 0?? transition as a function of interband coupling strength ? is found to always exhibit with the corresponding dip shifting toward the larger ? due to enhancing the spin polarization in the FM, while there exits no 0?? transition for the SC with s{sub ++}-wave pairing symmetry. The two features can be used to identify the pairing symmetry in the iron pnictide SC different from the s{sub ++}-wave one in MgB{sub 2}. Experimentally, by adjusting the doping level in the s{sub ±}-wave SCs, one can vary ?.

Liu, S. Y.; Tao, Y. C., E-mail: yctao88@163.com [Department of Physics and Institute of Theoretical Physics, Nanjing Normal University, Nanjing 210023 (China); Hu, J. G. [Department of Physics, Yangzhou University, Yangzhou 225002 (China)

2014-08-28T23:59:59.000Z

417

Exchange bias in Core-Shell Iron-Iron Oxide Nanoclusters  

SciTech Connect (OSTI)

An exchange bias study has been performed on core-shell iron-iron oxide (Fe-Fe3O4) nanoclusters (NCs) of size 11 nm and 14 nm carrying a different core to shell ratio. NCs show complicated behaviors due to competition between interfacial exchange and Zeeman energy in the presence of magnetic field during cooling. These behaviors are accompanied by the evolution of size- dependent cluster structures in the ferromagnetic-core/ferri- or antiferro-magnetic-shell. Smaller clusters have larger coercive field, exchange bias field, and vertical magnetization shift due to the greater contribution from frozen spins of shell/interfaces. These smaller clusters thus also show more dramatic changes with the training effect. Both sizes of clusters display an additional anomaly of the upper part of the hysteresis loop at 10 K under low cooling field (0.1 kOe). This anomaly decreases with number of loop cycles with same field, and disappear with large cooling field (> 0.1 kOe). It may be caused by the competition between the magnetization reversal and the magnetostatic interactions.

Kaur, Maninder; McCloy, John S.; Qiang, You

2013-04-03T23:59:59.000Z

418

The effect of iron dilution on strength of nickel/steel and Monel/steel welds  

SciTech Connect (OSTI)

The weld strength, as a function of iron content, for nickel/steel and Monel/steel welds was determined. Samples were prepared using a Gas Metal Arc (GMAW) automatic process to weld steel plate together with nickel or Monel to produce a range of iron contents typical of weld compositions. Tensile specimens of each iron content were tested to obtain strength and ductility measurements for that weld composition. Data indicate that at iron contents of less than 20% iron in a nickel/steel weld, the weld fails at the weld interface, due to a lack of fusion. Between 20% and 35% iron, the highest iron dilution that could be achieved in a nickel weld, the welds were stronger than the steel base metal. This indicates that a minimum amount of iron dilution (20%) is necessary for good fusion and optimum strength. On the other hand for Monel/steel welds, test results showed that the welds had good strength and integrity between 10% and 27% iron in the weld. Above 35% iron, the welds have less strength and are more brittle. The 35% iron content also corresponds to the iron dilution in Monel welds that has been shown to produce an increase in corrosion rate. This indicates that the iron dilution in Monel welds should be kept below 35% iron to maximize both the strength and corrosion resistance. 2 refs., 6 figs., 3 tabs.

Fout, S.L.; Wamsley, S.D.

1983-03-28T23:59:59.000Z

419

Use of high-granularity position sensing to correct response non-uniformities of CdZnTe detectors  

SciTech Connect (OSTI)

CdZnTe (CZT) is a promising medium for room-temperature gamma-ray detectors. However, the low production yield of acceptable quality crystals hampers the use of CZT detectors for gamma-ray spectroscopy. Significant efforts have been directed towards improving quality of CZT crystals to make them generally available for radiation detectors. Another way to address this problem is to implement detector designs that would allow for more accurate and predictable correction of the charge loss associated with crystal defects. In this work, we demonstrate that high-granularity position-sensitive detectors can significantly improve the performance of CZT detectors fabricated from CZT crystals with wider acceptance boundaries, leading to an increase of their availability and expected decrease in cost.

Bolotnikov, A. E., E-mail: bolotnik@bnl.gov; Camarda, G. S.; Cui, Y.; De Geronimo, G.; Fried, J.; Hossain, A.; Mahler, G.; Maritato, M.; Marshall, M.; Roy, U.; Vernon, E.; Yang, G.; James, R. B. [Department of Non-proliferation and National Security, Brookhaven National Laboratory, Upton, New York 11793-5000 (United States); Lee, K. [Korea University, 161 Jeongneung-ro, Seongbuk-gu, Seoul, 136-855 (Korea, Republic of); Petryk, M. [State University of New York at Binghamton, Binghamton, New York 13902 (United States)

2014-06-30T23:59:59.000Z

420

Friction of a slider on a granular layer: Non-monotonic thickness dependence and effect of boundary conditions  

E-Print Network [OSTI]

We investigate the effective friction encountered by a mass sliding on a granular layer as a function of bed thickness and boundary roughness conditions. The observed friction has minima for a small number of layers before it increases and saturates to a value which depends on the roughness of the sliding surface. We use an index-matched interstitial liquid to probe the internal motion of the grains with fluorescence imaging in a regime where the liquid has no significant effect on the measured friction. The shear profiles obtained as a function of depth show decrease in slip near the sliding surface as the layer thickness is increased. We propose that the friction depends on the degree of grain confinement relative to the sliding surfaces.

Saloome Siavoshi; Ashish V. Orpe; Arshad Kudrolli

2005-12-22T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

OPTIMISATION AND USE OF A DIGITAL SPECKLE RADIOGRAPHY ALGORITHM FOR INVESTIGATION OF LONG ROD PENETRATION OF GRANULAR MEDIA  

SciTech Connect (OSTI)

Digital Speckle Radiography (DSR) is a technique allowing full field displacement maps in a plan within an opaque material to be determined. The displacements are determined by tracking the motions of small sub-sections of a deforming speckle pattern, produced by seeding an internal layer of lead and taking flash x-ray images. An improved DSR algorithm is discussed which can improve the often poor contrast in DSR images, such that the mean and variance of the speckle pattern is uniform. This considerably improves the correlation success relative to other similar algorithms for DSR experiments. A series of experiments involving the penetration of granular media by long-rod projectiles, and the improved correlation achieved using this new algorithm, are discussed.

Addiss, John W.; Collins, Adam; Proud, William G. [Fracture and Shock Physics, SMF Group, Cavendish Laboratory, J. J. Thomson Ave., Cambridge, CB3 0HE (United Kingdom)

2009-12-28T23:59:59.000Z

422

Dynamics of iron-acceptor-pair formation in co-doped silicon  

SciTech Connect (OSTI)

The pairing dynamics of interstitial iron and dopants in silicon co-doped with phosphorous and several acceptor types are presented. The classical picture of iron-acceptor pairing dynamics is expanded to include the thermalization of iron between different dopants. The thermalization is quantitatively described using Boltzmann statistics and different iron-acceptor binding energies. The proper understanding of the pairing dynamics of iron in co-doped silicon will provide additional information on the electronic properties of iron-acceptor pairs and may become an analytical method to quantify and differentiate acceptors in co-doped silicon.

Bartel, T.; Gibaja, F.; Graf, O.; Gross, D.; Kaes, M.; Heuer, M.; Kirscht, F. [Calisolar GmbH, Magnusstrasse 11, 12489 Berlin (Germany)] [Calisolar GmbH, Magnusstrasse 11, 12489 Berlin (Germany); Möller, C. [CiS Forschungsinstitut für Mikrosensorik und Photovoltaik GmbH, Konrad-Zuse-Str. 14, 99099 Erfurt (Germany) [CiS Forschungsinstitut für Mikrosensorik und Photovoltaik GmbH, Konrad-Zuse-Str. 14, 99099 Erfurt (Germany); TU Ilmenau, Institut für Physik, Weimarer Str. 32, 98693 Ilmenau (Germany); Lauer, K. [CiS Forschungsinstitut für Mikrosensorik und Photovoltaik GmbH, Konrad-Zuse-Str. 14, 99099 Erfurt (Germany)] [CiS Forschungsinstitut für Mikrosensorik und Photovoltaik GmbH, Konrad-Zuse-Str. 14, 99099 Erfurt (Germany)

2013-11-11T23:59:59.000Z

423

Granular Bed Filter Development Program, Phase II. Monthly technical progress report for April 1-30, 1980  

SciTech Connect (OSTI)

The Department of Energy is sponsoring a multiphase program to investigate the filtration potential of the moving bed granular filter (GBF) for application in pressurized high temperature energy conversion systems. Phase I included the development of a mathematical model, a cold flow parametric test series in a 0.746 Nm/sup 3//s GBF, and investigations of potential dust plugging problems at the inlet screen. During the experimental program, collection efficiencies of 99% and filter outlet loadings less that 0.0074 g/m/sup 3/ were demonstrated. The objectives of Phase II are to investigate the effects of elevated temperature and coal combustion particulate on GBF filtration performance, to update the analytical model developed in Phase I to reflect high-temperature effects, to optimize filter internal configuration, to demonstrate long duration GBF performance relative to corrosion, deposition, erosion, filtration efficiency, reliability, controllability, and to design and construct a 0.879 Nm/sup 3//s, 660 kPa filter for delivery to DOE. Hot flow testing to date has confirmed that the GBF configured with inlet and outlet screens has exhibited a tendency for extensive and irreversible ash plugging. As an alternative, the potential advantages produced by a screenless configuration, having higher filtration efficiency, has been achieved during both cold flow and hot flow tests as previously reported. Feed and solid compositions from test P704, the 400-hour GBF test, are presented. A status report on the design of the high pressure GBF along with operation details for purging the GBF of corrosive gases upon shutdown and granular reserve sensing during its operation are detailed.

Moresco, L.L.; Cooper, J.; Ferguson, J.

1980-01-01T23:59:59.000Z

424

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network [OSTI]

Potentials in the Iron and steel Industry in China. Reportfor the U.S. Iron and Steel Industry. An ENERGY STAR Guidebusiness/industry/Iron_Steel_Guide.pdf Worrell, E. Ramesohl,

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

425

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network [OSTI]

23 5. Comparison of Energy Intensity of Iron and Steelthe U.S. . 27 5.1. Energy Intensity of Iron and27 5.2. Energy Intensity of Iron and Steel Production in

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

426

Response of zinc, iron and copper status parameters to supplementation with zinc or zinc and iron in women  

SciTech Connect (OSTI)

Supplementation with zinc at levels available over-the-counter may compromise iron or copper status. This study examined the effects of zinc(50mg/day) or zinc and iron(50 mg each/day) on 18 women aged 25-40. Subjects were matched on initial levels of serum ferritin(SF) and erythrocyte superoxide dismutase(ESOD) and randomly assigned to Group Z (zinc) or F-Z (iron and zinc). The following were measured pretreatment and after 6 and 10 weeks treatment: serum zinc (BZ), salivary sediment zinc (SSZ), hemoglobin (Hgb), hematocrit (Hct), SF, serum ceruloplasmin (Cp) and ESOD. Effects of treatment and weeks of treatment on changes from initial blood and saliva levels were analyzed using AOV. BZ increased (P=0.0144) and ESOD decreased (P=0.0001) with weeks of treatment. Differences due to treatment are presented. No effects were noted on Hgb, Hct or Cp. Intakes of zinc supplements at about 4X RDA appear to decrease copper(ESOD) and iron(SF) status. Use of iron w/zinc may be protective for FE but not Cu, and may compromise zinc (SSZ) status.

Yadrick, K.; Kenney, M.A.; Winterfeldt, E.

1986-03-05T23:59:59.000Z

427

Method and system for producing metallic iron nuggets  

DOE Patents [OSTI]

Method and system for producing metallic nuggets includes providing reducible mixture of reducing material (such as carbonaceous material) and reducible iron bearing material (such as iron oxide) that may be arranged in discrete portions, such as mounds or briquettes, on at least a portion of a hearth material layer (such as carbonaceous material). A coarse overlayer of carbonaceous material may be provided over at least some of the discrete portions. Heating the reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

Iwasaki, Iwao; Lindgren, Andrew J.; Kiesel, Richard F.

2013-06-25T23:59:59.000Z

428

Fissile sample worths in the Uranium/Iron Benchmark  

SciTech Connect (OSTI)

One of the long-standing problems from LMFBR critical experiments is the central worth discrepancy, the consistent overprediction of the reactivity associated with introducing a small material sample near the center of an assembly. Reactivity (sample worth) experiments in ZPR-9, assembly 34, the Uranium/Iron Benchmark (U/Fe), were aimed at investigating this discrepancy. U/Fe had a large, single-region core whose neutronics was governed almost entirely by /sup 235/U and iron. The essentially one-dimensional plate unit cell had one 1.6 mm-wide column of 93% enriched uranium (U(93)) near the center, imbedded in about 50 mm of iron and stainless steel. The neutron spectrum was roughly comparable to that of an LMFBR, but the adjoint spectrum was much flatter than an LMFBR's. The worths of four different fissile materials were measured and the worth of U(93) was measured using several different experimental techniques.

Schaefer, R.W.; Bucher, R.G.

1983-01-01T23:59:59.000Z

429

XMM-Newton Observations of AGN Iron Line Profiles  

E-Print Network [OSTI]

XMM-Newton observations of type I AGN are presented. The properties of the iron K emission line are reviewed, the majority of AGN observed by XMM-Newton show narrow, unresolved (by XMM) iron lines at 6.4 keV from cold matter that must originate far from the inner accretion disc, perhaps in the putative torus or outer broad line region. The strength of this narrow line appears to decrease with luminosity, implying a reduction in the covering fraction of this material in the more luminous quasars. Few examples of the broad, relativistic iron line profile have been found by XMM-Newton, although in MCG -6-30-15, the extreme breadth of the broad line component may imply a Kerr metric for the central black hole. Generally, relativistic Fe K line profiles are not required in a number of other Seyfert 1 X-ray spectra.

James Reeves

2002-11-18T23:59:59.000Z

430

Activation of Hydrogen Peroxide by Iron-Containing Minerals and Catalysts in Circumneutral pH Solutions: Implications for ex situ and in situ Treatment of Contaminated Water and Soil  

E-Print Network [OSTI]

iron and oxygen. Environmental Science & Technology 2008,iron and oxygen. Environmental Science & Technology 2008,

Pham, Anh

2012-01-01T23:59:59.000Z

431

How Godzilla Ate Pittsburgh: The Long Rise of the Japanese Iron and Steel Industry, 1900–1973  

E-Print Network [OSTI]

poorly endowed as Japan in coking coal and iron ore (WarrenYawata of iron ore for coking coal and the progressive in-

Bernard Elbaum

2007-01-01T23:59:59.000Z

432

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network [OSTI]

of Iron and Steel Production Energy Use and Energy Intensityof Iron and Steel Production Energy Use and Energy Intensitycomparisons of steel production energy efficiency and CO 2

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

433

E-Print Network 3.0 - as-cast iron-aluminide alloys Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe3Al alloys. Proceedings of the International Symposium on Nickel and Iron... . A., and Liu, C. T. 1989. Effect of chromium on properties of iron ... Source: DuPont, John N. -...

434

Sedimentary and mineral dust sources of dissolved iron to the world ocean  

E-Print Network [OSTI]

of the tropi- cal Pacific Ocean II. Iron biogeochemistry,in the Northeast Pacific Ocean Gyre: Aerosols, iron, and theF. M. M. : The equatorial Pacific Ocean: Grazer-controlled

Moore, J. K; Braucher, O.

2008-01-01T23:59:59.000Z

435

Interactions of Fe(II) with the iron oxidizing bacterium Rhodopseudomonas palustris TIE-1  

E-Print Network [OSTI]

Microbial anaerobic iron oxidation has long been of interest to biologists and geologists, both as a possible mechanism for the creation of banded iron formations before the rise of oxygen, and as a model system for organisms ...

Bird, Lina J. (Lina Joana)

2013-01-01T23:59:59.000Z

436

Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project...  

Office of Environmental Management (EM)

Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping and Feasibility Vessel Cold-Ironing Using a Barge Mounted PEM Fuel Cell: Project Scoping and Feasibility...

437

Characterization of temperature profile in furnace and solubility of iron in silicon  

E-Print Network [OSTI]

A better understanding of the behavior of impurities, such as iron, in silicon can lead to increases in solar cell efficiency. The purpose of this thesis was to study the behavior of iron in silicon via three sub-tasks: ...

Modi, Vrajesh Y

2011-01-01T23:59:59.000Z

438

Mineralogical and Microbial Controls on Iron Reduction in a Contaminated Aquifer-Wetland System  

E-Print Network [OSTI]

and lepidocrocite); moderately reducible iron (such as goethite, akageneite, and hematite); organically bound iron; magnetite; and pyrite. The second phase of this research involved creating in situ microcosm experiments that exposed native microbial communities...

Howson, Andrea Melissa

2011-02-22T23:59:59.000Z

439

A Radar-like Iron based Nanohybrid as an Efficient and Stable...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Radar-like Iron based Nanohybrid as an Efficient and Stable Electrocatalyst for Oxygen Reduction. A Radar-like Iron based Nanohybrid as an Efficient and Stable Electrocatalyst for...

440

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti...  

Broader source: Energy.gov (indexed) [DOE]

1: Cisco IronPort Web Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web Email Security Appliance Sophos Anti-Virus Multiple...

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

The shielding effect of wild type iron reducing bacterial flora on the corrosion of linepipe steel  

E-Print Network [OSTI]

The shielding effect of wild type iron reducing bacterial flora on the corrosion of linepipe steel (iron reducing bacteria (IRB)) on API 5L Ã?52 carbon steel coupons was investigated. A wild type of IRB

442

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect (OSTI)

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mössbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mössbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

443

Geologic evolution of Iron Mountain, central Mojave Desert, California  

E-Print Network [OSTI]

' quadrangle, mapped Iron Mountain [Dibblee, 1967] at a scale of 1:62,500, and presented the first description of many of the rock types at Iron Mountain. Detailed geologic mapping at 1:12,000 of the entire range, undertaken by S.S. Boettcher in the Fall... by coarsely crystalline dolomitic marble that is massive to finely laminated. A distinct, micaceous quartzite unit, up to 50 m thick, forms aprominent marker. It contains abundant, closely spaced, dark laminations ofbiotite, magnetite and other heavy...

Boettcher, Stefan S.; Walker, J. Douglas

1993-04-01T23:59:59.000Z

444

Iron-phosphorus relationships in Fe chlorisis of sorghum  

E-Print Network [OSTI]

IRON-PHOSPHORUS RELATIONSHIPS IN FE CHLOROSIS OF SORGHUM A Thesis by DENNIS A. MORALES-VARGAS Submitted to the Graduate College of Texas A8M University in partial fulfillment of the requirement for the degree of MASl'ER OF SCIENCE December... 1979 Major Subject: Soil Science IRON-PHOSPHORUS RELATIONSHIPS IN FE CHLOROSI OF SORGHUM A Thesis by DENNIS A. MORALES-VARGAS Approved as to style and content by: \\ J(c'w"H~. v& 4 Cc ~. r&'4 wc' c "&"~ / ~Chairman of Committee ! ~Co-' hai...

Morales-Vargas, Dennis A

1979-01-01T23:59:59.000Z

445

Iron is the Key to Preserving Dinosaur Soft Tissue  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines |Iron is the Key toIron is

446

The Iron Spin Transition in the Earth's Lower Mantle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 and NbSe2DifferentTheInforum LIFTThe Iron SpinThe Iron

447

Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctober 5,OctoberdeepIronIron

448

Iron is the Key to Preserving Dinosaur Soft Tissue  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctoberOxide WasteIron andIron

449

Iron is the Key to Preserving Dinosaur Soft Tissue  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctoberOxide WasteIronIron is

450

Iron is the Key to Preserving Dinosaur Soft Tissue  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/Surface Reactions andOctoberOxide WasteIronIron

451

Chromium modified nickel-iron aluminide useful in sulfur bearing environments  

DOE Patents [OSTI]

An improved nickel-iron aluminide containing chromium and molybdenum additions to improve resistance to sulfur attack.

Cathcart, John V. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

1989-06-13T23:59:59.000Z

452

Consequence of total lepton number violation in strongly magnetized iron white dwarfs  

SciTech Connect (OSTI)

The influence of a neutrinoless electron to positron conversion on a cooling of strongly magnetized iron white dwarfs is studied.

Belyaev, V. B. [Bogolyubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, Dubna 141980 (Russian Federation); Ricci, P. [Istituto Nazionale di Fisica Nucleare, Sezione di Firenze, I-50019 Sesto Fiorentino (Firenze) (Italy); Šimkovic, F. [Department of Nuclear Physics and Biophysics, Comenius University, Mlynská dolina F1, SK-842 15, Bratislava, Slovakia and Bogolyubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, Dubna 141980 (Russian Federation); Adam, J. Jr.; Tater, M.; Truhlík, E. [Institute of Nuclear Physics ASCR, CZ-250 68 ?ež (Czech Republic)

2013-12-30T23:59:59.000Z

453

Iron Based Superconductors Jeffrey W. Lynn, NIST Center for Neutron Research  

E-Print Network [OSTI]

Iron Based Superconductors Jeffrey W. Lynn, NIST Center for Neutron Research The phenomenon energy without dissipation. Superconductors have other unique properties such as the ability to expel of superconductors based on iron. These iron-based superconductors have initiated a flurry of activity as researchers

Lynn, Jeffrey W.

454

The Continental Margin is a Key Source of Iron to the HNLC North Pacific Ocean  

E-Print Network [OSTI]

The Continental Margin is a Key Source of Iron to the HNLC North Pacific Ocean Phoebe J. Lam1 concentrations in the upper 500m of the Western Subarctic Pacific, an iron-limited High Nutrient Low Chlorophyll a key source of bioavailable Fe to the HNLC North Pacific. Keywords: iron, continental margin, HNLC 1

455

Phase diagram of iron, revised-core temperatures Thomas J. Ahrens, Kathleen G. Holland,1  

E-Print Network [OSTI]

. In agreement with Brown [2001] the discrepancy between the diamond cell melting data and the iron shock and Ahrens [1998b]. [6] We used polycrystalline iron (99%) targets in the shape of two cylinders that for the VISAR shots, the iron sample is covered with a 0.5 mm thick shim of polycrystalline Mo. [10] For g

Stewart, Sarah T.

456

Highpressure behavior of iron carbide (Fe7C3) at inner core conditions  

E-Print Network [OSTI]

Highpressure behavior of iron carbide (Fe7C3) at inner core conditions Mainak Mookherjee,1 Yoichi at high pressures have demonstrated that Fe7C3 iron carbide is a likely candidate for the Earth's inner behavior of iron carbide (Fe7C3) at inner core conditions, J. Geophys. Res., 116, B04201, doi:10

Steinle-Neumann, Gerd

457

Author's personal copy Hematite and iron carbonate precipitation-coexistence at the  

E-Print Network [OSTI]

Carbon dioxide The hydrothermal reactivity of swelling clays has relevant implications on the geological that the carbon dioxide increased the hydrothermal reactivity of montmorillonite because the hematite and ironAuthor's personal copy Hematite and iron carbonate precipitation-coexistence at the iron

Montes-Hernandez, German

458

Numerical analysis of a model for Nickel-Iron alloy electrodeposition on rotating disk  

E-Print Network [OSTI]

Numerical analysis of a model for Nickel-Iron alloy electrodeposition on rotating disk electrode N the nickel-iron electrodeposition process, we have developed one-dimensional numerical model. This model ad can predict characteristic features of the nickel-iron sys- tem. this work was supported

Paris-Sud XI, Université de

459

Role of Surface Precipitation in Copper Sorption by the Hydrous Oxides of Iron and Aluminum  

E-Print Network [OSTI]

Role of Surface Precipitation in Copper Sorption by the Hydrous Oxides of Iron and Aluminum K. G precipitation; sorption; isotherms; X-ray diffraction; hydrous iron oxide; hydrous aluminum oxide; copper. INTRODUCTION Hydrous oxides of iron (HFO) and aluminum (HAO) are important mineral components of natural

Chorover, Jon

460

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS  

E-Print Network [OSTI]

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS S.W. Banovic, J.N. Du (Received January 5, 1998) (Accepted March 23, 1998) Introduction Iron-aluminum weld overlay coatings, the application of iron-aluminum alloys is currently limited due to hydrogen cracking susceptibility subsequent

DuPont, John N.

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Variable-temperature solid-state NMR studies of iron(II) and iron(III) complexes  

E-Print Network [OSTI]

the first communication reporting the use of C CP/MAS NMR to observe paramagnetic solids directly. Zust as shift reagents had been used in solution-state NMR, selected paramagnetic lanthanide acetates exhibited paramagnetic shifts in the solid state... of the Fe(III) chloride salt yields the w-oxo-bis[porphine- iron(III)] dimer where the two iron centers are bridged via an oxygen. The synthesis, characterization and crystal structure of the metallo-porphyrin dimer w-oxo-bis[tetra- phenylporphineiron...

Shepard, Patricia Arlene

1989-01-01T23:59:59.000Z

462

Comparison of gleptoferron iron compound to two commonly used iron supplements for the prevention of baby pig anemia  

E-Print Network [OSTI]

wk of age. Wahlstrom and Juhl (1960) demonstrated that injecting baby pi gs dur- ing the first d of life with iron dextran (100 mg) resulted in higher hemoglobin values at 10, 21, and 28 d and heavier pigs at 28 d than when an oral pill (292 mg... and treatment of baby pig anemia. J. Anim. Sci. 16:1038. Wahlstrom, R. C. and E. W. Juhl. 1960. A comparison of different methods of iron administration on rate of gain and hemoglobin level of the baby pig . J . Anim. Sci . 1 9: 1 83. Zimmerman, D. R. , V. C...

Homann, Ervin R.

2012-06-07T23:59:59.000Z

463

Studies of anisotropy of iron based superconductors  

SciTech Connect (OSTI)

To study the electronic anisotropy in iron based superconductors, the temperature dependent London penetration depth, {Delta}{lambda}#1;#21;(T), have been measured in several compounds, along with the angular dependent upper critical field, H{sub c2}(T). Study was undertaken on single crystals of Ba(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} with x=0.108 and x=0.127, in the overdoped range of the doping phase diagram, characterized by notable modulation of the superconducting gap. Heavy ion irradiation with matching field doses of 6 T and 6.5 T respectively, were used to create columnar defects and to study their effect on the temperature {Delta}{lambda}#1;#21;(T). The variation of the low-temperature penetration depth in both pristine and irradiated samples was #12;tted with a power-law function {Delta}{lambda}#1;#21;(T) = AT{sup n}. Irradiation increases the magnitude of the pre-factor A and decreases the exponent n, similar to the effect on the optimally doped samples. This finding supports the universal s{sub {+-}}#6; scenario for the whole doping range. Knowing that the s{sub {+-}}#6; gap symmetry exists across the superconducting dome for the electron doped systems, we next looked at {lambda}#21;(T), in optimally - doped, SrFe{sub 2}(As{sub 1-x}P{sub x}){sub 2}, x =0.35. Both, as-grown (T{sub c} ~ #25;25 K) and annealed (T{sub c} ~ #25;35 K) single crystals of SrFe{sub 2}(As{sub 1-x}P{sub x}){sub 2} were measured. Annealing decreases the absolute value of the London penetration depth from #21;{lambda}(0) = 300 {+-}#6; 10 nm in as-grown samples to {lambda}#21;(0) = 275{+-}#6;10 nm. At low temperatures, {lambda}#21;(T) #24;~ T indicates a superconducting gap with line nodes. Analysis of the full-temperature range superfluid density is consistent with the line nodes, but differs from the simple single-gap d-wave. The observed behavior is very similar to that of BaFe{sub 2}(As{sub 1-x}P{sub x}){sub 2}, showing that isovalently substituted pnictides are inherently different from the charge-doped materials. In-plane resistivity measurements as a function of temperature, magnetic field, and its orientation with respect to the crystallographic ab-plane were used to study the upper critical field, H{sub c2}, of two overdoped compositions of Ba(Fe{sub 1-x}Ni{sub x}){sub 2}As{sub 2}, x=0.054 and x=0.072. Measurements were performed using precise alignment (with accuracy less than 0.1{degree}) of the magnetic field with respect to the Fe-As plane. The dependence of the H{sub c2} on angle {theta}#18; between the field and the ab- plane was measured in isothermal conditions in a broad temperature range. We found that the shape of the H{sub c2} vs. {theta}#18; curve clearly deviates from the Ginzburg-Landau theory.

Murphy, Jason [Ames Laboratory

2013-05-15T23:59:59.000Z

464

Fischer-Tropsch synthesis over iron-rhodium alloy catalysts  

SciTech Connect (OSTI)

To investigate the nature of iron-rhodium alloy catalysts during the Fischer-Tropsch synthesis, a combination of experimental techniques were applied. Infrared spectroscopy was mainly used to extract direct information on the surface of catalysts under the reaction conditions. In addition, Mossbauer spectroscopy was employed to study the iron alloy catalysts. Further characterization of the catalysts was performed by chemisorption measurements. Hydrocarbon products of the CO + H/sub 2/ synthesis reaction were analyzed by gas chromatography. The working surface of a silica-supported rhodium catalyst was found to be saturated with molecular carbon monoxide. The intensity of the linear carbonyl absorption band remained constant compared to that for room temperature CO adsorption, while that of the bridge-bonded carbonyl absorption band was drastically reduced during the Fischer-Tropsch synthesis. The bridge-bonded adsorption sites are assumed to be the active sites for dissociating carbon monoxide. The hydrogenation rate of the linearly adsorbed carbon monoxide was much slower than the steady state reaction rate. The alloy catalyst did not form a bulk carbide, but the presence of surface carbon was suggested by the large shift of the linear carbonyl absorption band. On the other hand, infrared spectra on an iron catalyst showed only weak bands, indicating a high degree of CO dissociation. On a silica-supported iron-rhodium alloy catalyst, surface analysis by infrared spectroscopy presents evidence of well-mixed alloy formation. Three models of carbon monoxide adsorption were identified.

Choi, S.

1983-01-01T23:59:59.000Z

465

The unexpected properties of alkali metal iron selenide superconductors  

SciTech Connect (OSTI)

The iron-based superconductors that contain FeAs layers as the fundamental building block in the crystal structures have been rationalized in the past using ideas based on the Fermi surface nesting of hole and electron pockets when in the presence of weak Hubbard U interactions. This approach seemed appropriate considering the small values of the magnetic moments in the parent compounds and the clear evidence based on photoemission experiments of the required electron and hole pockets. However, recent results in the context of alkali metal iron selenides, with generic chemical composition AxFe2ySe2 (A alkali metal element), have challenged those previous ideas since at particular compositions y the low-temperature ground states are insulating and display antiferromagnetic order with large iron magnetic moments. Moreover, angle-resolved photoemission studies have revealed the absence of hole pockets at the Fermi level in these materials. The present status of this exciting area of research, with the potential to alter conceptually our understanding of the ironbased superconductors, is here reviewed, covering both experimental and theoretical investigations. Other recent related developments are also briefly reviewed, such as the study of selenide two-leg ladders and the discovery of superconductivity in a single layer of FeSe. The conceptual issues considered established for the alkali metal iron selenides, as well as several issues that still require further work, are discussed.

Dagotto, Elbio R [ORNL

2013-01-01T23:59:59.000Z

466

Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders  

SciTech Connect (OSTI)

This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

Asit Biswas Andrew J. Sherman

2006-09-25T23:59:59.000Z

467

Reduction of Vinyl Chloride in Metallic Iron-Water Systems  

E-Print Network [OSTI]

Reduction of Vinyl Chloride in Metallic Iron-Water Systems B A O L I N D E N G * Department to groundwater and soil contamination. In particular, VC can be produced as an intermediate in the reductive). Remediation of groundwater contaminated with chlori- nated ethylenes, including vinyl chloride, has been chal

Deng, Baolin

468

Extracellular iron-sulfur precipitates from growth of Desulfovibrio desulfuricans  

SciTech Connect (OSTI)

The authors have examined extracellular iron-bearing precipitates resulting from the growth of Desulfovibrio desulfuricans in a basal medium with lactate as the carbon source and ferrous sulfate. Black precipitates were obtained when D. desulfuricans was grown with an excess of FeSO{sub 4}. When D. desulfuricans was grown under conditions with low amounts of FeSO{sub 4}, brown precipitates were obtained. The precipitates were characterized by iron K-edge XAFS (X-ray absorption fine structure), {sup 57}Fe Moessbauer-effect spectroscopy, and powder X-ray diffraction. Both were noncrystalline and nonmagnetic (at room temperature) solids containing high-spin Fe(III). The spectroscopic data for the black precipitates indicate the formation of an iron-sulfur phase with 6 nearest S neighbors about Fe at an average distance of 2.24(1) {angstrom}, whereas the brown precipitates are an iron-oxygen-sulfur phase with 6 nearest O neighbors about Fe at an average distance of 1.95(1) {angstrom}.

Antonio, M. R.; Tischler, M. L.; Witzcak, D.

1999-12-20T23:59:59.000Z

469

Versatile ferrofluids based on polyethylene glycol coated iron oxide nanoparticles  

E-Print Network [OSTI]

Versatile ferrofluids based on polyethylene glycol coated iron oxide nanoparticles W. Brullot a in revised form 20 December 2011 Available online 3 February 2012 Keywords: Ferrofluid Polyethylene glycol Magneto-optics Magnetite Rheology a b s t r a c t Versatile ferrofluids based on polyethylene glycol

470

ORIGINAL PAPER Electrochemical reduction of oxygen with iron phthalocyanine  

E-Print Network [OSTI]

bio- fuel cells) has been increasing [1­6]. The common point for all the biological systems is need Recent interest in electricity production using microbial fuel cells makes it important to better applications in neutral media. Keywords Microbial fuel cells Á Oxygen reduction Á Iron phthalocyanine Á Redox

471

Octadecylphosphonate (ODP) for corrosion inhibition of iron using  

E-Print Network [OSTI]

of corrosion include pipelines, mining facilities, oil and gas production sites, marine ships, hazmat storageOctadecylphosphonate (ODP) for corrosion inhibition of iron using the T-BAG technique Tiffany V · Cost of corrosion in the U.S. is $276 billion/year, (CC Technologies Laboratories, 2001) ­ Cost

Petta, Jason

472

High Temperature Corrosion Behavior of Iron Aluminide Alloys and Coatings  

SciTech Connect (OSTI)

A multi-year effort has been focused on optimizing the long-term oxidation performance of ingot-processed (IP) and oxide-dispersion strengthened (ODS) Fe{sub 3}Al and iron aluminide-based coatings. Based on results from several composition iterations, a Hf-doped alloy (Fe-28Al-2Cr-0.05at.%Hf) has been developed with significantly better high temperature oxidation resistance than other iron aluminides. The scale adhesion is not significantly better; however, the {alpha}-Al{sub 2}O{sub 3} scale grows at a slower rate, approximately a factor of 10 less than undoped iron aluminide. The benefit of Hf is greatest at 1100-1200 C. Long-term oxidation resistance of commercially fabricated ODS Fe{sub 3}Al has been determined and compared to commercially available ODS FeCrAl. Scale spallation rates for ODS Fe{sub 3}Al are higher than for ODS FeCrAl. To complement studies of iron-aluminide weld-overlay coatings, carbon steel was coated with Fe-Al-Cr by thermal spraying. These specimens were then exposed in air at 900 and 1000 C and in air-1%SO{sub 2} at 800 C. Most likely due to an inadequate aluminum concentration in the coatings, continuous protective Al{sub 2}O{sub 3} could not be maintained and, consequently, the corrosion performance was significantly worse than what is normally observed for Fe{sub 3}Al.

Pint, B.A.

2001-10-22T23:59:59.000Z

473

Sulfur Versus Iron Oxidation in an Iron-Thiolate Model Complex  

SciTech Connect (OSTI)

In the absence of base, the reaction of [Fe{sup II}(TMCS)]PF{sub 6} (1, TMCS = 1-(2-mercaptoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane) with peracid in methanol at -20 C did not yield the oxoiron(IV) complex (2, [Fe{sup IV}(O)(TMCS)]PF{sub 6}), as previously observed in the presence of strong base (KO{sup t}Bu). Instead, the addition of 1 equiv of peracid resulted in 50% consumption of 1. The addition of a second equivalent of peracid resulted in the complete consumption of 1 and the formation of a new species 3, as monitored by UV-vis, ESI-MS, and Moessbauer spectroscopies. ESI-MS showed 3 to be formulated as [Fe{sup II}(TMCS) + 2O]{sup +}, while EXAFS analysis suggested that 3 was an O-bound iron(II)-sulfinate complex (Fe-O = 1.95 {angstrom}, Fe-S = 3.26 {angstrom}). The addition of a third equivalent of peracid resulted in the formation of yet another compound, 4, which showed electronic absorption properties typical of an oxoiron(IV) species. Moessbauer spectroscopy confirmed 4 to be a novel iron(IV) compound, different from 2, and EXAFS (Fe{double_bond}O = 1.64 {angstrom}) and resonance Raman ({nu}{sub Fe{double_bond}O} = 831 cm{sup -1}) showed that indeed an oxoiron(IV) unit had been generated in 4. Furthermore, both infrared and Raman spectroscopy gave indications that 4 contains a metal-bound sulfinate moiety ({nu}{sub s}(SO{sub 2}) {approx} 1000 cm{sup -1}, {nu}{sub as}(SO{sub 2}) {approx} 1150 cm{sup -1}). Investigations into the reactivity of 1 and 2 toward H{sup +} and oxygen atom transfer reagents have led to a mechanism for sulfur oxidation in which 2 could form even in the absence of base but is rapidly protonated to yield an oxoiron(IV) species with an uncoordinated thiol moiety that acts as both oxidant and substrate in the conversion of 2 to 3.

A McDonald; M Bukowski; E Farquhar; T Jackson; K Koehntop; M Seo; R De Hont; A Stubna; J Halfen; E Munck

2011-12-31T23:59:59.000Z

474

Iron Aerogel and Xerogel Catalysts for Fischer-Tropsch Synthesis of Diesel Fuel  

SciTech Connect (OSTI)

Iron aerogels, potassium-doped iron aerogels, and potassium-doped iron xerogels have been synthesized and characterized and their catalytic activity in the Fischer-Tropsch (F-T) reaction has been studied. Iron aerogels and xerogels were synthesized by polycondensation of an ethanolic solution of iron(III) chloride hexahydrate with propylene oxide which acts as a proton scavenger for the initiation of hydrolysis and polycondensation. Potassium was incorporated in the iron aerogel and iron xerogel by adding aqueous K{sub 2}CO{sub 3} to the ethanolic solutions of the Fe(III) precursor prior to addition of propylene oxide. Fischer-Tropsch activities of the catalysts were tested in a fixed bed reactor at a pressure of 100 psi with a H{sub 2}:CO ratio of 2:1. Iron aerogels were found to be active for F-T synthesis, and their F-T activities increased on addition of a K containing promoter. Moessbauer spectroscopic data are consistent with an open, nonrigid iron(III) aerogel structure progressing to an iron carbide/metallic iron catalyst via agglomeration as the F-T synthesis proceeds in the course of a 35 h fixed bed reaction test.

Bali, S.; Huggins, F; Huffman, G; Ernst, R; Pugmire, R; Eyring, E

2009-01-01T23:59:59.000Z

475

Use of bimodal carbon distribution in compacts for producing metallic iron nodules  

DOE Patents [OSTI]

A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.

Iwasaki, Iwao

2014-04-08T23:59:59.000Z

476

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect (OSTI)

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

477

A Highly Granular Silicon-Tungsten Electromagnetic Calorimeter and Top Quark Production at the International Linear Collider  

E-Print Network [OSTI]

This thesis deals with two aspects of the International Linear Collider (ILC) which is a project of a linear electron-positron collider of up to at least 500 GeV center of mass energy. The first aspect is the development of a silicon-tungsten electromagnetic calorimeter (SiW-ECAL) for one of the detectors of the ILC. The concept of this detector is driven by the ILC beam specifications and by the Particle Flow Algorithm (PFA). This requires highly granular calorimeter and very compact one with integrated electronics. To prove the capability of the SiW- ECAL a technological prototype has been built and tested in test beam at DESY. The results are presented here, and show, after the calibration procedure a signal over noise ratio of 10, even in the power pulsing mode. The second aspect is the study of one of the important physics channels of the ILC, the top anti-top quark pairs production. The main goal of this study is to determine the precision that we can expect at the ILC on the top coupling with the W bos...

Rouëné, J

2014-01-01T23:59:59.000Z

478

Spacer-less, decoupled granular L1{sub 0} FePt magnetic media using Ar-He sputtering gas  

SciTech Connect (OSTI)

Spacer materials are often used to fabricate granular L1{sub 0} FePt media and reduce the grain size, however, at the expense of reduced out-of-plane coercivity. Here, we demonstrate a spacer-less method in which adding 1% helium to argon sputtering gas leads to a substantial improvement in the chemical ordering, as well as the magnetic and microstructural properties of FePt. This change is attributed to the modification in the ion current density of the plasma caused by the excited metastable helium species. Helium plays a pivotal role in providing the Fe and Pt atoms optimal adatom mobility, thereby, producing well-ordered L1{sub 0} FePt media. This leads to an enhancement of the out-of-plane coercivity from 15 to 22 kOe. Furthermore, exchange decoupled grains with a twofold reduction in their diameter to {approx}24 nm are also achieved. These properties are crucial for magnetic media of the future for data storage recording densities beyond 1 Tb/in{sup 2}.

Kundu, Shreya [Department of Electrical and Computer Engineering, National University of Singapore, 21 Lower Kent Ridge Road, Singapore 117576 (Singapore); Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore); Gaur, Nikita; Yang, Hyunsoo; Bhatia, Charanjit S. [Department of Electrical and Computer Engineering, National University of Singapore, 21 Lower Kent Ridge Road, Singapore 117576 (Singapore); Saifullah, M. S. M. [Institute of Materials Research and Engineering, A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)

2012-12-01T23:59:59.000Z

479

The effect of water temperature on the adsorption equilibrium of dissolved organic matter and atrazine on granular activated carbon  

SciTech Connect (OSTI)

The influence of water temperature on the adsorption of natural dissolved organic matter (DOM) on activated carbon has not been investigated intensively yet. In this study, batch experiments with granular activated carbon (GAC) F300, from bituminous coal, have been carried out at three temperatures (5, 20, 35{sup o} C) using a humic acid model water and different types of surface water (lake, river, canal). Furthermore, the adsorption of an anthropogenic contaminant, atrazine, was quantified in the absence and presence of DOM. The results indicate a significant influence of water temperature on the adsorption equilibrium of DOM and atrazine. Contrary to expectations, DOM and atrazine adsorption in surface water tends to be increased with increasing water temperature, whereas the extent of this effect is dependent on the type and concentration of DOM. Furthermore, the temperature effect on atrazine adsorption is controlled by competition of DOM and atrazine on adsorption sites. Some assumptions are proposed and discussed for explaining the temperature effects observed in the batch studies. 39 refs., 4 figs., 2 tabs.

Bernd Schreiber; Viktor Schmalz; Thomas Brinkmann; Eckhard Worch [Dresden University of Technology, Dresden (Germany). Institute of Water Chemistry

2007-09-15T23:59:59.000Z

480

Effects of temperature and acidic pre-treatment on Fenton-driven oxidation of MTBE-spent granular activated carbon  

SciTech Connect (OSTI)

The effects of temperature and acidic pretreatment on Fenton-driven chemical oxidation of methyl tert-butyl ether (MTBE)-spent granular activated carbon (GAC, derived from bituminous coal) were investigated. Limiting factors in MTBE removal in GAC include the heterogeneous distribution of amended Fe, and slow intraparticle diffusive transport of MTBE and hydrogen peroxide (H{sub 2}O{sub 2}) into the 'reactive zone'. Acid pretreatment of GAC before Fe amendment altered the surface chemistry of the GAC, lowered the pH point of zero charge, and resulted in greater penetration and more uniform distribution of Fe in GAC. This led to a condition where Fe, MTBE, and H{sub 2}O{sub 2} coexisted over a larger volume of the GAC contributing to greater MTBE oxidation and removal. H{sub 2}O{sub 2} reaction and MTBE removal in GAC increased with temperature. Modeling H{sub 2}O{sub 2} transport and reaction in GAC indicated that H{sub 2}O{sub 2} penetration was inversely proportional with temperature and tortuosity, and occurred over a larger fraction of the total volume of small GAC particles (0.3 mm diameter) relative to large particles (1.2 mm diameter). Acidic pretreatment of GAC, Fe-amendment, elevated reaction temperature, and use of small GAC particles are operational parameters that improve Fenton-driven oxidation of MTBE in GAC. 29 refs., 6 figs., 1 tab.

Kan, E.; Huling, S.G. [Robert S. Kerr Environmental Research Center, Ada, OK (United States)

2009-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Characterization and Correlation of Particle-Level Interactions to the Macroscopic Rheology of Powders, Granular Slurries, and Colloidal Suspensions  

SciTech Connect (OSTI)

Hanford TRU tank sludges are complex mixtures of undissolved minerals and salt solids in an aqueous phase of high ionic strength. They show complex rheological behavior resulting from interactions at the macroscopic level, such as interparticle friction between grains in the coarse fraction, as well as from interactions at the nano-scale level, such as the agglomeration of colloidal particles. An understanding of how phenomena such as interparticle friction and aggregate stability under shear will allow better control of Hanford TRU tank sludges being processed for disposal. The project described in this report had two objectives. The first was to understand the physical properties and behavior of the Hanford transuranic (TRU) tank sludges under conditions that might exist during retrieval, treatment, packaging, and transportation for disposal at the Waste Isolation Pilot Plant (WIPP). The second objective was to develop a fundamental understanding of sludge physical properties by correlating the macroscopic behavior with interactions occurring at the particle/colloidal scale. These objectives were accomplished by: 1) developing continuum models for coarse granular slurries and 2) studying the behavior of colloidal agglomerates under shear and under irradiation.

Poloski, Adam P.; Daniel, Richard C.; Rector, David R.; Bredt, Paul R.; Buck, Edgar C.; Berg, John C.; Saez, Avelino E.

2006-09-29T23:59:59.000Z

482

Iron beam acceleration using direct plasma injection scheme  

SciTech Connect (OSTI)

A new set of vanes of radio frequency quadrupole (RFQ) accelerator was commissioned using highly charged iron beam. To supply high intensity heavy ion beams to the RFQ, direct plasma injection scheme (DPIS) with a confinement solenoid was adopted. One of the difficulties to utilize the combination of DPIS and a solenoid field is a complexity of electro magnetic field at the beam extraction region, since biasing high static electric field for ion extraction, RFQ focusing field, and the solenoid magnetic field fill the same space simultaneously. To mitigate the complexity, a newly designed magnetic field clamps were used. The intense iron beam was observed with bunched structure and the total accelerated current reached 2.5 nC.

Okamura, M., E-mail: okamura@bnl.gov [Brookhaven National Laboratory, Upton, New York 11973 (United States); RIKEN-BNL Research Center, Upton, New York 11973 (United States); Kanesue, T. [Brookhaven National Laboratory, Upton, New York 11973 (United States)] [Brookhaven National Laboratory, Upton, New York 11973 (United States); Yamamoto, T. [Waseda University, Shinjuku, Tokyo 169-8555 (Japan)] [Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Fuwa, Y. [Kyoto University, Uji, Kyoto 611-0011 (Japan) [Kyoto University, Uji, Kyoto 611-0011 (Japan); RIKEN, Wako, Saitama 351-0198 (Japan)

2014-02-15T23:59:59.000Z

483

Unified Picture for Magnetic Correlations in Iron-Based Superconductors  

SciTech Connect (OSTI)

The varying metallic antiferromagnetic correlations observed in iron-based superconductors are unified in a model consisting of both itinerant electrons and localized spins. The decisive factor is found to be the sensitive competition between the superexchange antiferromagnetism and the orbital-degenerate double-exchange ferromagnetism. Our results reveal the crucial role of Hund's rule coupling for the strongly correlated nature of the system and suggest that the iron-based superconductors are closer kin to manganites than cuprates in terms of their diverse magnetism and incoherent normal-state electron transport. This unified picture would be instrumental for exploring other exotic properties and the mechanism of superconductivity in this new class of superconductors.

Yin, W.G.; Lee, E.-C.; Ku, W.

2010-09-02T23:59:59.000Z

484

The world`s first commercial iron carbide plant  

SciTech Connect (OSTI)

The paper traces the development of Nucor`s investigation of clean iron unit processes, namely, direct reduction, and the decision to build and operate the world`s first commercial iron carbide plant. They first investigated coal based processes since the US has abundant coal reserves, but found a variety of reasons for dropping the coal-based processes from further consideration. A natural gas based process was selected, but the failure to find economically priced gas supplies stopped the development of a US based venture. It was later found that Trinidad had economically priced and abundant supplies of natural gas, and the system of government, the use of English language, and geographic location were also ideal. The cost estimates required modification of the design, but the plant was begun in April, 1993. Start-up problems with the plant are also discussed. Production should commence shortly.

Prichard, L.C.; Schad, D.

1995-12-01T23:59:59.000Z

485

Iron aluminide alloy container for solid oxide fuel cells  

DOE Patents [OSTI]

A container for fuel cells is made from an iron aluminide alloy. The container alloy preferably includes from about 13 to about 22 weight percent Al, from about 2 to about 8 weight percent Cr, from about 0.1 to about 4 weight percent M selected from Zr and Hf, from about 0.005 to about 0.5 weight percent B or from about 0.001 to about 1 weight percent C, and the balance Fe and incidental impurities. The iron aluminide container alloy is extremely resistant to corrosion and metal loss when exposed to dual reducing and oxidizing atmospheres at elevated temperatures. The alloy is particularly useful for containment vessels for solid oxide fuel cells, as a replacement for stainless steel alloys which are currently used.

Judkins, Roddie Reagan (Knoxville, TN); Singh, Prabhakar (Export, PA); Sikka, Vinod Kumar (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

486

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents [OSTI]

An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.

McKamey, Claudette G. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

1990-01-01T23:59:59.000Z

487

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents [OSTI]

An improved iron aluminide alloy of the DO[sub 3] type is described that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy conversion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26--30 at. % aluminum, 0.5--10 at. % chromium, 0.02--0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron. 3 figs.

McKamey, C.G.; Liu, C.T.

1990-10-09T23:59:59.000Z

488

IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

SciTech Connect (OSTI)

Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

2012-03-19T23:59:59.000Z

489

Microstructure of thin-wall ductile iron castings  

SciTech Connect (OSTI)

Step plate castings with section thicknesses of 1.5 mm to 6 mm and individual (single) castings with section thicknesses of 2 mm to 6 mm were produced using a ductile iron chemistry. Microstructures of these thin wall ductal iron castings were characterized quantitatively using an image analyzer. Matrix structure (amount of pearlite, ferrite, and massive carbides) and graphite structure (volume fraction, nodule size, nodule content, and nodularity) were investigated as a function of section thickness. Pearlite content, nodule count, and nodularity increased with decreasing section thickness, whereas the nodule size decreased. Nodule content exceeded 2000 nodules per mm{sup 2} at the thinnest sections. Statistical analysis was performed to investigate the effect of casting parameters on the microstructure.

Dogan, Omer N.; Schrems, Karol K.; Hawk, Jeffrey A.

2003-01-01T23:59:59.000Z

490

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS  

SciTech Connect (OSTI)

The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1998-07-22T23:59:59.000Z

491

Iron aluminide useful as electrical resistance heating elements  

DOE Patents [OSTI]

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

2001-01-01T23:59:59.000Z

492

Iron aluminide useful as electrical resistance heating elements  

DOE Patents [OSTI]

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

1999-01-01T23:59:59.000Z

493

Iron aluminide useful as electrical resistance heating elements  

DOE Patents [OSTI]

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, {<=}1% Cr and either {>=}0.05% Zr or ZrO{sub 2} stringers extending perpendicular to an exposed surface of the heating element or {>=}0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, {<=}2% Ti, {<=}2% Mo, {<=}1% Zr, {<=}1% C, {<=}0.1% B, {<=}30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, {<=}1% rare earth metal, {<=}1% oxygen, {<=}3% Cu, balance Fe. 64 figs.

Sikka, V.K.; Deevi, S.C.; Fleischhauer, G.S.; Hajaligol, M.R.; Lilly, A.C. Jr.

1997-04-15T23:59:59.000Z

494

Iron aluminide useful as electrical resistance heating elements  

DOE Patents [OSTI]

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

1997-01-01T23:59:59.000Z

495

Broad Iron Emission from Gravitationally Lensed Quasars Observed by Chandra  

E-Print Network [OSTI]

Recent work has demonstrated the potential of gravitationally lensed quasars to extend measurements of black hole spin out to high-redshift with the current generation of X-ray observatories. Here we present an analysis of a large sample of 27 lensed quasars in the redshift range 1.0permit the detection of iron emission from the inner accretion disk in individual cases in our sample, we find significant structure in the stacked residuals. In addition to the narrow core, seen almost ubiquitously in local AGN, we find evidence for an additional underlying broad component from the inner accretion disk, with a clear red wing to the emission profile. Based on simulations, we find the detection of this broader component to be significant at greater than the 3-sigma level. This implies that iron emission...

Walton, D J; Miller, J M; Reis, R C; Stern, D; Harrison, F A

2015-01-01T23:59:59.000Z

496

Coal Fly Ash as a Source of Iron in Atmospheric Dust  

SciTech Connect (OSTI)

Anthropogenic coal fly ash aerosols may represent a significant source of bioavailable iron in the open ocean. Few measurements have been made to compare the solubility of atmospheric iron from anthropogenic aerosols and other sources. We report an investigation of the iron dissolution of three fly ash samples in acidic aqueous solutions and compare the solubilities with that of Arizona test dust, a reference material of mineral dust. The effects of pH, cloud processing, and solar irradiation on Fe solubility were explored. Similar to previously reported results on mineral dust, iron in aluminosilicate phases provide predominant dissolved iron compared with iron in oxides. Iron solubility of fly ash is higher than Arizona test dust, especially at the higher pH conditions investigated. Simulated atmospheric processing elevates iron solubility due to significant changes in the morphology aluminosilicate glass, a dominantly material in fly ash particle. Iron continuously releases into the aqueous solution as fly ash particles break up into smaller fragments. The assessment of dissolved atmospheric iron deposition fluxes, and their effect on the biogeochemistry at ocean surface should be constrained by taking into account the source, environment pH, Fe speciation, and solar radiation.

Chen, Haihan; Laskin, Alexander; Baltrusaitis, Jonas; Gorski, Christopher A.; Scherer, Michelle; Grassian, Vicki H.

2012-01-18T23:59:59.000Z

497

Zinc sorption by iron oxides and soil samples  

E-Print Network [OSTI]

(Head of Department) May 1989 ABSTRACT Zinc Sorption by Iron Oxides and Soil Samples. (May 1989) Markku Juhani Yli-Halla, M. S. University of Helsinki, Finland Chair of Advisory Committee: Dr. Richard H. Loeppert Zn sorption by synthetic Fe oxide... and soil samples was studied. The purpose was to examine the effect of crystallinity and adsorbed silica on Zn adsorption by synthetic Fe oxide using goethite and ferrihydrite as test materials. Zn sorption by acid soil samples from Finland and a...

Yli-Halla, Markku Juhani

1989-01-01T23:59:59.000Z

498

Low resistivity contact to iron-pnictide superconductors  

DOE Patents [OSTI]

Method of making a low resistivity electrical connection between an electrical conductor and an iron pnictide superconductor involves connecting the electrical conductor and superconductor using a tin or tin-based material therebetween, such as using a tin or tin-based solder. The superconductor can be based on doped AFe.sub.2As.sub.2, where A can be Ca, Sr, Ba, Eu or combinations thereof for purposes of illustration only.

Tanatar, Makariy; Prozorov, Ruslan; Ni, Ni; Bud'ko, Sergey; Canfield, Paul

2013-05-28T23:59:59.000Z

499

Methods for making a supported iron-copper catalyst  

DOE Patents [OSTI]

A catalyst is described for the synthesis of hydrocarbons from CO+H.sub.2 utilizing a porous Al.sub.2 O.sub.3 support impregnated with iron and copper and optionally promoted with an alkali metal. The use of an Al.sub.2 O.sub.3 support results in the suppression of heavy waxes (C.sub.26 + hydrocarbons), particularly in slurry phase operation, when compared to unsupported or co-precipitated catalysts.

Dyer, Paul N. (Allentown, PA); Pierantozzi, Ronald (Macungie, PA)

1986-01-01T23:59:59.000Z

500

Parkers-Iron Springs, Arkansas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy ResourcesLoading map...(UtilityCounty,Orleans County,PPPSolarParagonThis articlePandaParkers-Iron