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Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Performance of a Permeable Reactive Barrier Using Granular Zero-Valent  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Performance of a Permeable Reactive Barrier Using Granular Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site More Documents & Publications Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing

2

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah  

Energy.gov (U.S. Department of Energy (DOE))

Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah

3

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008  

Energy.gov (U.S. Department of Energy (DOE))

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008

4

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dispersivity Testing of Zero-Valent Iron Treatment Cells: Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 More Documents & Publications Final Report Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Phase II: Performance Evaluation of Permeable Reactive Barriers and Potential for Rejuvenation by Chemical Flushing Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable

5

Degradation of organic and inorganic contaminants by zero valent iron  

E-Print Network (OSTI)

Reduction of trichloroethylene (TCE), chromium (VI), and 2,4 dinitrotoluene (2,4-DNT) by zero valent iron and palladized iron under anaerobic conditions was investigated. Reduction experiments of the contaminants were carried out individually and in combination. All three target contaminants were effectively reduced by both iron (Feo) and palladized iron (Pd/Fe'). However, the rate of reduction by Pd/Fe' was found to be much faster than that by Feo. The reduction of all the contaminants in mixed waste was found to be slower than in the individual experiments, but the difference was most significant in the 2,4-DNT reduction. This observation indicates that there may be a possibility of competition for reactive sites among the contaminants and precipitation resulting from CR(VI) reduction may coat iron surfaces, which may ultimately slow the whole zero valent metals (ZVMS) treatment process in remediating mixed waste sites. The 20 mg/L of CR(VI) was reduced below detection limits in 10 hours by Fe' and in 1.5 hours by the same amount of Pd/Fe' in individual experiment. An initial concentration of 20 mg/L of TCE was reduced below detection limits in 72 hours by Pd/Fe' whereas only 62% of TCE was reduced by the same amount of Fe' in 144 hours in individual experiment. The reaction orders of 1.84 and 2.04 for total TCE loss alone and in mixed waste by Fe' indicates that the reaction mechanisms are complex. The reduction of 72 mg/L of 2,4-DNT proceeded to below detection limits within 3 hours by both Fe' and Pd/Feo. The only product observed in the reduction of 2,4-DNT was 2,4-diaminotoluene (2,4-DAT). The 2,4-DAT produced accounted for 83-100% and only 42-54% of the initial mass of 2@4.DNT under anaerobic and aerobic conditions respectively. Since no degradation of 2,4-DAT alone occurred, these results indicate the possibility of other intermediates or products formation under aerobic conditions. Overall, the results demonstrated the potential application of ZVMs in reducing mixed wastes containing both inorganic and organic contaminant interactions before implementing a ZVMs treatment system, which may help in designing a proper remedial system.

Malla, Deepak Babu

1997-01-01T23:59:59.000Z

6

Zero Valent Iron: Impact of Anions Present during Synthesis on Subsequent Nanoparticle Reactivity  

SciTech Connect

Zero-valent iron particles are an effective remediation technology for groundwater contaminated with halogenated organic compounds. In particular, nano-scale zero-valent iron is a promising material for remediation due to its high specific surface area, which results in faster rate constants and more effective use of the iron. An aspect of iron nanoparticle reactivity that has not been explored is the impact of anions present during iron metal nanoparticle synthesis. Solutions containing chloride, phosphate, sulfate, and nitrate anions and ferric ions were used to generate iron oxide nanoparticles. The resulting materials were dialyzed to remove dissolved byproducts and then dried and reduced by hydrogen gas at high temperature. The reactivity of the resulting zero valent iron nanoparticles was quantified by monitoring the kinetics as well as products of carbon tetrachloride reduction, and significant differences in reactivity and chloroform yield were observed. The reactivity of nanoparticles prepared in the presence of sulfate and phosphate demonstrated the highest reactivity and chloroform yield. Furthermore, substantial variations in the solid-state products of oxidation (magnetite, iron sulfide, and goethite, among others) were also observed.

Moore, Kirsten; Forsberg, Brady; Baer, Donald R.; Arnold, William A.; Penn, R. Lee

2011-10-01T23:59:59.000Z

7

Reduction and Immobilization of Radionuclides and Toxic Metal Ions Using Combined Zero Valent Iron and Anaerobic Bacteria  

Science Conference Proceedings (OSTI)

The use of zero valent iron, permeable reactive barriers (PRBs) for groundwater remediation continues to increase. AN exciting variation of this technology involves introducing anaerobic bacteria into these barriers so that both biological and abiotic pollutant removal processes are functional. This work evaluated the hypothesis that a system combining a mixed culture of sulfate reducing bacteria (SRB) with zero valent iron would have a greater cr(VI) removal efficiency and a greater total Cr(VI) removal capacity than a zero valent iron system without the microorganisms. Hence, the overall goal of this research was to compare the performance of these types of systems with regard to their Cr(VI) removal efficiency and total Cr(VI) removal capacity. Both batch and continuous flow reactor systems were evaluated.

Lenly J. Weathers; Lynn E. Katz

2002-05-29T23:59:59.000Z

8

Injection of Zero Valent Iron into an Unconfined Aquifer Using Shear-Thinning Fluids  

Science Conference Proceedings (OSTI)

Approximately 190 kg of two micron-diameter zero-valent iron (ZVI) particles were injected into a test zone in the top two meters of an unconfined aquifer within a trichloroethene (TCE) source area. A shear-thinning fluid was used to enhance ZVI delivery in the subsurface to a radial distance of up to four meters from a single injection well. The ZVI particles were mixed in-line with the injection water, shear-thinning fluid, and a low concentration of surfactant. ZVI was observed at each of the seven monitoring wells within the targeted radius of influence during injection. Additionally, all wells within the targeted zone showed low TCE concentrations and primarily dechlorination products present 44 days after injection. These results suggest that ZVI can be directly injected into an aquifer with shear-thinning fluids and extends the applicability of ZVI to situations where other emplacement methods may not be viable.

Truex, Michael J.; Vermeul, Vincent R.; Mendoza, Donaldo P.; Fritz, Brad G.; Mackley, Rob D.; Oostrom, Martinus; Wietsma, Thomas W.; Macbeth, Tamzen

2011-02-18T23:59:59.000Z

9

Modelling the remediation of contaminated groundwater using zero-valent iron barrier  

Science Conference Proceedings (OSTI)

This paper presents results of modelling studies on remediation of groundwater contaminated with uranium using a zero-valent iron permeable reactive barrier (ZVI PRB) at the U.S. Oak Ridge Y-12 site that are used to establish modelling techniques that are of value to other sites such as in the UK. A systematic modelling methodology has been developed to study the problem by using a suite of modelling tools. Firstly a conceptual basis of the main chemical processes representing the remediation of uranium by the ZVI PRB is developed. Two main effects involving reduction and corrosion have been identified as being relevant for the remediation processes. These are then formulated and implemented using the reactive chemical model PHREEQC to provide underpinning chemical input parameters for subsequent reactive solute transport modelling using the TRAFFIC and PHAST codes. Initial results shows that modelling can be a very cost-effective means to study the hydrogeological and geochemical processes involved and to aid understanding of the remediation concept. The modelling approaches presented and lessons learnt are thought to be relevant to other cases of contaminated land study and are likely to be of value to site management concepts which consider on-site disposal of contaminated soils and materials. (authors)

Kwong, S.; Small, J.; Tahar, B. [Nexia Solutions Ltd., Hinton House, Risley, Warrington, WA (United Kingdom)

2007-07-01T23:59:59.000Z

10

Pilot-Scale Demonstration of Hybrid Zero-Valent Iron Water Treatment Technology: Removing Trace Metals from Flue Gas Desulfurization (FGD) Wastewater  

Science Conference Proceedings (OSTI)

In previous laboratory- and field bench-scale tests, the hybrid zero-valent iron (hZVI) process had been demonstrated capable of removing selenium, mercury, nitrates, and other pollutants from flue gas desulfurization (FGD) wastewater. By incorporating zero-valent iron (ZVI) with magnetite and certain Fe(II) species, the hZVI technology creates a highly reactive mixture that can transform and immobilize various trace metals, oxyanions, and other impurities from aqueous streams. To further evaluate ...

2013-04-09T23:59:59.000Z

11

Aerosol synthesis of nano and micro-scale zero valent metal particles from oxide precursors  

SciTech Connect

In this work a novel aerosol method, derived form the batch Reduction/Expansion Synthesis (RES) method, for production of nano / micro-scale metal particles from oxides and hydroxides is presented. In the Aerosol-RES (A-RES) method, an aerosol, consisting of a physical mixture of urea and metal oxide or hydroxides, is passed through a heated oven (1000 C) with a residence time of the order of 1 second, producing pure (zero valent) metal particles. It appears that the process is flexible regarding metal or alloy identity, allows control of particle size and can be readily scaled to very large throughput. Current work is focused on creating nanoparticles of metal and metal alloy using this method. Although this is primarily a report on observations, some key elements of the chemistry are clear. In particular, the reducing species produced by urea decomposition are the primary agents responsible for reduction of oxides and hydroxides to metal. It is also likely that the rapid expansion that takes place when solid/liquid urea decomposes to form gas species influences the final morphology of the particles.

Phillips, Jonathan [Los Alamos National Laboratory; Luhrs, Claudia [UNM; Lesman, Zayd [UNM; Soliman, Haytham [UNM; Zea, Hugo [UNM

2010-01-01T23:59:59.000Z

12

THE EFFECT OF SMECTITE ON THE CORROSION OF IRON METAL  

SciTech Connect

The combination of zero-valent iron and a clay-type amendment is often observed to have a synergistic effect on the rate of reduction reactions. In this paper, electrochemical techniques are used to determine the mechanism of interaction between the iron and smectite clay minerals. Iron electrodes coated with an evaporated smectite suspension (clay-modified iron electrodes, CMIEs) were prepared using five different smectites: SAz-1, SWa-1, STx-1, SWy-1, and SHCa-1. All the smectites were exchanged with Na+ and one sample of SWy-1 was also exchanged with Mg2+. Potentiodynamic potential scans and cyclic voltammograms were taken using the CMIEs and uncoated but passivated iron electrodes. These electrochemical experiments, along with measurements of the amount of Fe2+ and Fe3+ sorbed in the smectite coating, suggested that the smectite removed the passive layer of the underlying iron electrode during the evaporation process. Cyclic voltammograms taken after the CMIEs were biased at the active-passive transition potential for varying amounts of time suggested that the smectite limited growth of a passive layer, preventing passivation. These results are attributed to the Broensted acidity of the smectite as well as to its ability to sorb iron cations. Oxides that did form on the surface of the iron in the presence of the smectite when it was biased anodically seemed to be different than those that form on the surface of an uncoated iron electrode under otherwise similar conditions; this difference suggested that the smectite reacted with the Fe2+ formed from the oxidation of the underlying iron. No significant correlation could be found between the ability of the smectite to remove the iron passive film and the smectite type. The results have implications for the mixing of sediments and iron particles in permeable reactive barriers, underground storage of radioactive waste in steel canisters, and the use of smectite supports in preventing aggregation of nano-sized zero-valent iron.

Balko, Barbara A.; Bosse, Stephanie A.; Cade, Anne E.; Jones-Landry, Elise F.; Amonette, James E.; Daschbach, John L.

2012-04-24T23:59:59.000Z

13

Granular filter  

SciTech Connect

The invention described and claimed in this application relates to granular filters and, more particularly, to continuously regenerate granular filters operatable at high temperature and pressure which are particularly suited for cleaning gas used to operate a gas turbine. The filter is of relatively small size and by nature of its operation couples high filtering efficiency with maximum practicable protection to downstream equipment from ash from combustion of the solid fuel and from small particle of the filtering medium entrained in the flowing gas, which would case deposit buildup and erosion to the turbine blades.

Lear, D.E. Jr; Schmid, A.H.; Wigton, H.F.H.

1977-07-12T23:59:59.000Z

14

Microsoft Word - S01394_PRB_ZVI.DOC  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

GJ719-2004 GJ719-2004 ESL-RPT-2004-06 Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site September 2004 Prepared by Environmental Sciences Laboratory U.S. Department of Energy Grand Junction, Colorado This page intentionally blank Signature Page Document Number S0139400 PRB Using Granular ZVI-2004 Annual Report U.S. Department of Energy Page iv September 2004 End of current text Document Number S0139400 Contents U.S. Department of Energy PRB Using Granular ZVI-2004 Annual Report September 2004 Page v Contents Signature Page ...............................................................................................................................

15

Transport in granular systems  

E-Print Network (OSTI)

There are many situations in which a continuum view of granular systems does not fully capture the relevant mechanics. In order for engineers to be able to design systems for transporting granular materials, there needs ...

Wendell, Dawn M. (Dawn Marie), 1983-

2011-01-01T23:59:59.000Z

16

Particle Deposition in Granular Media  

Science Conference Proceedings (OSTI)

Objective is to understand aerosol deposition from gas streams flowing through granular media; this is important to the design of granular filtration systems. The following investigations were carried out: transient behavior of granular filtration of aerosols, and stochastic simulation of aerosol deposition in granular media.

Tien, C.

1992-01-01T23:59:59.000Z

17

Multiscale modeling in granular flow  

E-Print Network (OSTI)

Granular materials are common in everyday experience, but have long-resisted a complete theoretical description. Here, we consider the regime of slow, dense granular flow, for which there is no general model, representing ...

Rycroft, Christopher Harley

2007-01-01T23:59:59.000Z

18

Spreading of a granular droplet.  

Science Conference Proceedings (OSTI)

The influence of controlled vibrations on the granular rheology is investigated in a specifically designed experiment in which a granular film spreads under the action of horizontal vibrations. A nonlinear diffusion equation is derived theoretically that describes the evolution of the deposit shape. A self-similar parabolic shape (the granular droplet) and a spreading dynamics are predicted that both agree quantitatively with the experimental results. The theoretical analysis is used to extract effective friction coefficients between the base and the granular layer under sustained and controlled vibrations. A shear thickening regime characteristic of dense granular flows is evidenced at low vibration energy, both for glass beads and natural sand. Conversely, shear thinning is observed at high agitation.

Sanchez, I.; Raynaud, F.; Lanuza, J.; Andreotti, B.; Clement, E.; Aranson, I. S.; Materials Science Division; Univ. Simon; CNRS-ESPCI-Univ.

2007-01-01T23:59:59.000Z

19

Particle Deposition in Granular Media. Final report  

Science Conference Proceedings (OSTI)

Objective is to understand aerosol deposition from gas streams flowing through granular media; this is important to the design of granular filtration systems. The following investigations were carried out: transient behavior of granular filtration of aerosols, and stochastic simulation of aerosol deposition in granular media.

Tien, C.

1992-12-31T23:59:59.000Z

20

Granular Dynamics during Impact  

E-Print Network (OSTI)

We study the impact of a projectile onto a bed of 3 mm grains immersed in an index-matched fluid. Specifically, we vary the amount of prestrain on the sample, strengthening the force chains within the system. We find this affects only the prefactor of linear depth-dependent term in the stopping force. We therefore attribute this term to pressure within the material, and not the grain-intruder friction as is sometimes suggested. Using a laser sheet scanning technique to visualize internal grain motion, a high-speed camera, and particle tracking, we can measure the trajectory of each grain throughout an impact event. Microscopically, our results indicate that weaker initial force chains result in more irreversible, plastic rearrangements during impact, suggesting static friction between grains does play a substantial role in the energy dissipation within the granular material.

Kerstin Nordstrom; Emily Lim; Matthew Harrington; Wolfgang Losert

2013-04-23T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Lyapunov spectrum of granular gases  

Science Conference Proceedings (OSTI)

We calculate and study the Lyapunov spectrum of a granular gas maintained in a steady state by an isokinetic thermostat. Considering restitution coefficients greater than unity allows us to show that the spectra change smoothly and continuously at equilibrium. The shearing instability of the granular gas, however, provokes an abrupt change in the structure of the spectrum. The relationship between various physically relevant quantities and the energy dissipation rate differs from previously studied nonequilibrium steady states.

McNamara, Sean; Mareschal, Michel

2001-06-01T23:59:59.000Z

22

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Utah A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM...

23

Ground-Water Table and Chemical Changes in an Alluvial Aquifer During  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ground-Water Table and Chemical Changes in an Alluvial Aquifer Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

24

Ground-Water Table and Chemical Changes in an Alluvial Aquifer During  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ground-Water Table and Chemical Changes in an Alluvial Aquifer Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells More Documents & Publications Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

25

Momentum Transport in Granular Flows  

E-Print Network (OSTI)

We investigate the error induced by only considering binary collisions in the momentum transport of hard-sphere granular materials, as is done in kinetic theories. In this process, we first present a general microscopic derivation of the momentum transport equation and compare it to the kinetic theory derivation, which relies on the binary collision assumption. These two derivations yield different microscopic expressions for the stress tensor, which we compare using simulations. This provides a quantitative bound on the regime where binary collisions dominate momentum transport and reveals that most realistic granular flows occur in the region of phase space where the binary collision assumption does not apply.

Gregg Lois; Anael Lemaitre; Jean M. Carlson

2006-02-10T23:59:59.000Z

26

Shock wave propagation in vibrofluidized granular materials  

E-Print Network (OSTI)

Shock wave formation and propagation in two-dimensional granular materials under vertical vibration are studied by digital high speed photography. The steepen density and temperature wave fronts form near the plate as granular layer collides with vibrating plate and propagate upward through the layer. The temperature front is always in the transition region between the upward and downward granular flows. The effects of driving parameters and particle number on the shock are also explored.

Kai Huang; Guoqing Miao; Peng Zhang; Yi Yun; Rongjue Wei

2005-11-29T23:59:59.000Z

27

Segregation of granular particles in suspension flow  

E-Print Network (OSTI)

An experiment was conducted to investigate the development of longitudinal stripes of granular particles due to instabilities in particle suspension flow. Research was conducted to characterize environmental phenomena ...

Tsay, Jessica, 1983-

2004-01-01T23:59:59.000Z

28

Self-Diffusion in Rotating Granular Materials  

Science Conference Proceedings (OSTI)

Rock-cuttings, sand, cement, tablets, grain, coal, biomass etc are examples of granular materials. These materials are transported from one place to another...

29

Status of granular bed filter development program  

SciTech Connect

The objective of this project was to design and develop moving bed granular filters and ceramic candle filters for particulate control from combined cycle systems. Results are described.

Wilson, K.B.; Haas, J.C.; Prudhomme, J.

1995-11-01T23:59:59.000Z

30

Field Projects: Durango, Colorado | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Long-Term Surveillance - Operations and Maintenance Long-Term Surveillance - Operations and Maintenance » Permeable Reactive Barriers » Field Projects: Durango, Colorado Field Projects: Durango, Colorado Personnel from Sandia National Laboratories in New Mexico installed four permeable reactive barriers PRBs at the Durango, Colorado, Uranium Mill Tailings Radiation Control Act Title I site in October 1995. These PRBs are managed by LM. Foamed zero-valent (ZVI) iron bricks produced by Cercona of America, steel wool, and granular iron have been used as reactive media to remove ammonium, arsenic, cadmium, chromium, manganese, molybdenum, nitrate, radium-226, selenium, uranium, vanadium, and zinc contamination from leachate exiting the uranium mill tailings disposal cell. After passing through the ZVI, the leachate contaminant levels meet the

31

Pattern formation and shocks in granular gases  

E-Print Network (OSTI)

Granular media such as sand and sugar are ubiquitous in nature and industry but are less well understood than fluids or solids. We consider the behavior of rapid granular flows where the transfer of momenta by collisions dominates. The physics is quite different for the opposite limit of static or slowly moving grains (e.g., sand piles). To gain understanding of granular flows we consider two problems that have been investigated with experiments, particle simulations and hydrodynamic theory: vertically oscillating granular layers and flow past an obstacle. Oscillating granular layers spontaneously form spatial patterns when the container acceleration amplitude exceeds a critical value, about 2.5 times the gravitational acceleration. Simulations with hard spheres that conserve linear momentum and dissipate energy in collisions are in qualitative accord with some but not all aspects of the observed patterns. It is necessary to include friction and angular momentum conservation in the simulations to achieve quantitative accord with observations. [Abridged

Harry L. Swinney; E. C. Rericha

2004-08-11T23:59:59.000Z

32

Iron (Fe)  

Science Conference Proceedings (OSTI)

Table 19   Linear thermal expansion of iron...Table 19 Linear thermal expansion of iron Temperature Change in length, % (a) Coefficient

33

Chaoticity of the Wet Granular Gas  

E-Print Network (OSTI)

In this work we derive an analytic expression for the Kolmogorov-Sinai entropy of dilute wet granular matter, valid for any spatial dimension. The grains are modelled as hard spheres and the influence of the wetting liquid is described according to the Capillary Model, in which dissipation is due to the hysteretic cohesion force of capillary bridges. The Kolmogorov-Sinai entropy is expanded in a series with respect to density. We find a rapid increase of the leading term when liquid is added. This demonstrates the sensitivity of the granular dynamics to humidity, and shows that the liquid significantly increases the chaoticity of the granular gas.

A. Fingerle; S. Herminghaus; V. Yu. Zaburdaev

2007-05-22T23:59:59.000Z

34

Granular gases under extreme driving  

E-Print Network (OSTI)

We study inelastic gases in two dimensions using event-driven molecular dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady-state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

W. Kang; J. Machta; E. Ben-Naim

2010-02-04T23:59:59.000Z

35

Investigating the potential for long-term permeable reactive barrier (PRB) monitoring from the electrical signatures associated with the reduction in reactive iron performance  

SciTech Connect

The objective of this work was to conduct laboratory and field experiments to determine the sensitivity of low frequency electrical measurements (resistivity and induced polarization) to the processes of corrosion and precipitation that are believed to limit permeable reactive barrier (PRB) performance. The research was divided into four sets of experiments that were each written up and submitted to a peer-reviewed journal: [1] A laboratory experiment to define the controls of aqueous chemistry (electrolyte activity; pH; valence) and total zero valent iron (Fe0) available surface area on the electrical properties of Fe0 columns. [2] A laboratory experiment to determine the impact of corrosion and precipitation on the electrical response of synthetic Fe0 columns as a result of geochemical reactions with NaSO4 and NaCO3 electrolytes. [3] Laboratory experiments on a sequence of cores retrieved from the Kansas City PRB to determine the magnitude of electrical and geochemical changes within a field active PRB after eight years of operation [4] Field-scale cross borehole resistivity and induced polarization monitoring of the Kansas City PRB to evaluate the potential of electrical imaging as a technology for non-invasive, long-term monitoring of indicators of reduced PRB performance This report first summarizes the findings of the four major experiments conducted under this research. The reader is referred to the four papers in Appendices 1-4 for a full description of each experiment, including motivation and significance, technical details, findings and implications. The deliverables of the project, including the publications, conference papers and new collaborative arrangements that have resulted are then described. Appendices 5-6 contain two technical reports written by co-PI Korte describing (1) supporting geochemical measurements, and (2) the coring procedure, conducted at the Kansas City PRB as part of this project.

Slater, Lee D.; Korte, N.; Baker, J.

2005-12-14T23:59:59.000Z

36

Mechanical characterization of jammable granular systems  

E-Print Network (OSTI)

The mode by which a granular material can transition between fluid-like and solid-like states has been often referred to as jamming. The use of this property (via vacuum pressure) for engineering applications has only ...

Hudson, Shaymus William

2012-01-01T23:59:59.000Z

37

Beneficial Reuse at Bodo Canyon Site | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Services » Environmental Justice » Beneficial Reuse at Bodo Services » Environmental Justice » Beneficial Reuse at Bodo Canyon Site Beneficial Reuse at Bodo Canyon Site The George Washington University Environmental Resource Policy Graduate Program Capstone Project Beneficial Reuse at Bodo Canyon Site Feasibility and Community Support for Photovoltaic Array May 2012 The George Washington University Environmental Resource Policy Graduate Program Capstone Project was an analysis of LM's efforts to support the installation of a commercial solar photovoltaic system at the former uranium mill site near Durango, Colorado. Beneficial Reuse at Bodo Canyon Site More Documents & Publications EA-1770: Final Environmental Assessment Performance of a Permeable Reactive Barrier Using Granular Zero-Valent Iron: FY 2004 Annual Report Durango, Colorado, Disposal Site

38

Advanced hydraulic fracturing methods to create in situ reactive barriers  

Science Conference Proceedings (OSTI)

This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

1997-12-31T23:59:59.000Z

39

A constitutive law for dense granular flows  

E-Print Network (OSTI)

A continuum description of granular flows would be of considerable help in predicting natural geophysical hazards or in designing industrial processes. However, the constitutive equations for dry granular flows, which govern how the material moves under shear, are still a matter of debate. One difficulty is that grains can behave like a solid (in a sand pile), a liquid (when poured from a silo) or a gas (when strongly agitated). For the two extreme regimes, constitutive equations have been proposed based on kinetic theory for collisional rapid flows, and soil mechanics for slow plastic flows. However, the intermediate dense regime, where the granular material flows like a liquid, still lacks a unified view and has motivated many studies over the past decade. The main characteristics of granular liquids are: a yield criterion (a critical shear stress below which flow is not possible) and a complex dependence on shear rate when flowing. In this sense, granular matter shares similarities with classical visco-plastic fluids such as Bingham fluids. Here we propose a new constitutive relation for dense granular flows, inspired by this analogy and recent numerical and experimental work. We then test our three-dimensional (3D) model through experiments on granular flows on a pile between rough sidewalls, in which a complex 3D flow pattern develops. We show that, without any fitting parameter, the model gives quantitative predictions for the flow shape and velocity profiles. Our results support the idea that a simple visco-plastic approach can quantitatively capture granular flow properties, and could serve as a basic tool for modelling more complex flows in geophysical or industrial applications.

Pierre Jop; Yol Forterre; Olivier Pouliquen

2006-12-05T23:59:59.000Z

40

Contact micromechanics in granular media with clay  

SciTech Connect

Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

Ita, S.L.

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Dynamic effective mass of granular media  

E-Print Network (OSTI)

We develop the concept of frequency dependent effective mass, M(omega), of jammed granular materials which occupy a rigid cavity to a filling fraction of 48%, the remaining volume being air of normal room condition or controlled humidity. The dominant features of M(omega) provide signatures of the dissipation of acoustic modes, elasticity and aging effects in the granular medium. We perform humidity controlled experiments and interpret the data in terms of a continuum model and a "trap" model of thermally activated capillary bridges at the contact points. The results suggest that attenuation in the granular materials is influenced significantly by the kinetics of capillary condensation between the asperities at the contacts.

Chaur-Jian Hsu; David L. Johnson; Rohit A. Ingale; John J. Valenza; Nicolas Gland; Hernan A. Makse

2006-05-29T23:59:59.000Z

42

Measurement of Elastic Moduli of Nano-Granular Surfaces  

Science Conference Proceedings (OSTI)

Measurement of Elastic Moduli of Nano-Granular Surfaces. Next-generation electronic devices, based on micro- and nanoelectromechanical ...

2013-03-15T23:59:59.000Z

43

Granular Rough Theory: A representation semantics oriented theory of roughness  

Science Conference Proceedings (OSTI)

The present work is an archival paper for a series of contributions proposed in last few years on building a theory of roughness over pure mereological relations among information granules. There are five major efforts taken in the present paper: (1) ... Keywords: Granular Representation Calculus, Granular Rough Theory, Granular-Rough Computational Web Intelligence

Bo Chen; Ming Sun; Mingtian Zhou

2009-03-01T23:59:59.000Z

44

Shock Waves in Weakly Compressed Granular Media  

E-Print Network (OSTI)

We experimentally probe nonlinear wave propagation in weakly compressed granular media, and observe a crossover from quasi-linear sound waves at low impact, to shock waves at high impact. We show that this crossover grows with the confining pressure $P_0$, whereas the shock wave speed is independent of $P_0$ --- two hallmarks of granular shocks predicted recently. The shocks exhibit powerlaw attenuation, which we model with a logarithmic law implying that local dissipation is weak. We show that elastic and potential energy balance in the leading part of the shocks.

Siet van den Wildenberg; Rogier van Loo; Martin van Hecke

2013-04-23T23:59:59.000Z

45

Granular Elasticity and the loss of elastic stability in granular materials  

SciTech Connect

A recently proposed hyperelastic model for granular materials, called "granular elasticity", identifies a yield angle as a result of thermodynamic instability. GE gives yield angles that are smaller than those found in real materials; a generalization of the theory is considered here that includes dependence on the third strain invariant. This generalization proves unsuccessful, as it gives smaller, not larger, yield angles. Fully convex hyperelastic models are identified as a point for future investigation.

P. W. Humrickhouse

2009-07-01T23:59:59.000Z

46

A stochastic flow rule for granular materials  

E-Print Network (OSTI)

There have been many attempts to derive continuum models for dense granular flow, but a general theory is still lacking. Here, we start with Mohr-Coulomb plasticity for quasi-2D granular materials to calculate (average) stresses and slip planes, but we propose a "stochastic flow rule" (SFR) to replace the principle of coaxiality in classical plasticity. The SFR takes into account two crucial features of granular materials - discreteness and randomness - via diffusing "spots" of local fluidization, which act as carriers of plasticity. We postulate that spots perform random walks biased along slip-lines with a drift direction determined by the stress imbalance upon a local switch from static to dynamic friction. In the continuum limit (based on a Fokker-Planck equation for the spot concentration), this simple model is able to predict a variety of granular flow profiles in flat-bottom silos, annular Couette cells, flowing heaps, and plate-dragging experiments -- with essentially no fitting parameters -- although it is only expected to function where material is at incipient failure and slip-lines are inadmissible. For special cases of admissible slip-lines, such as plate dragging under a heavy load or flow down an inclined plane, we postulate a transition to rate-dependent Bagnold rheology, where flow occurs by sliding shear planes. With different yield criteria, the SFR provides a general framework for multiscale modeling of plasticity in amorphous materials, cycling between continuum limit-state stress calculations, meso-scale spot random walks, and microscopic particle relaxation.

Ken Kamrin; Martin Z. Bazant

2006-09-19T23:59:59.000Z

47

Microsoft Word - S04040_tracer.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dispersivity Testing of Zero-Valent Iron Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah November 2005 Through February 2008 April 2008 DOE LM/1587 2008 - - ESL RPT 2008 02 - - - Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AM01 07LM00060 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1587-2007 ESL-RPT-2008-02 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 April 2008 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AM01-07LM00060 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado This page intentionally left blank

48

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

51 - 10060 of 28,905 results. 51 - 10060 of 28,905 results. Download Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 http://energy.gov/lm/downloads/dispersivity-testing-zero-valent-iron-treatment-cells-monticello-utah Download Microsoft Word- AL2000-05Attachment.doc http://energy.gov/management/downloads/microsoft-word-al2000-05attachmentdoc Download October 2012 APM Newsletter http://energy.gov/management/downloads/october-2012-apm-newsletter Page FAQs Topics: http://energy.gov/management/office-management/employee-services/faqs Download EA-1611: Final Environmental Assessment Interconnection Request for the Colorado Highlands Wind Project

49

Microsoft Word - S04040_tracer.doc  

Office of Legacy Management (LM)

Dispersivity Testing of Zero-Valent Iron Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah November 2005 Through February 2008 April 2008 DOE LM/1587 2008 - - ESL RPT 2008 02 - - - Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AM01 07LM00060 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1587-2007 ESL-RPT-2008-02 Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 April 2008 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AM01-07LM00060 for the U.S. Department of Energy Office of Legacy Management, Grand Junction, Colorado This page intentionally left blank

50

Dynamic effective mass of granular media  

E-Print Network (OSTI)

We report an experimental and theoretical investigation of the frequency-dependent effective mass, $\\tilde{M}(\\omega)$, of loose granular particles which occupy a rigid cavity to a given filling fraction, the remaining volume being air of differing humidities. This allow us to study the mechanisms of elastic response and attenuation of acoustic modes in granular media. We demonstrate that this is a sensitive and direct way to measure those properties of the granular medium that are the cause of the changes in acoustic properties of structures containing grain-filled cavities. Specifically, we apply this understanding to the case of the flexural resonances of a rectangular bar with a grain-filled cavity within it. The dominant features of $\\tilde{M}(\\omega)$ are a sharp resonance and a broad background, which we analyze within the context of simple models. We find that: a) These systems may be understood in terms of a height-dependent and diameter-dependent effective sound speed ($\\sim 100-300$ m/s) and an effective viscosity ($\\sim 5\\times 10^4$ Poise). b) There is a dynamic Janssen effect in the sense that, at any frequency, and depending on the method of sample preparation, approximately one-half of the effective mass is borne by the side walls of the cavity and one-half by the bottom. c) By performing experiments under varying humidity conditions we conclude that, on a fundamental level, damping of acoustic modes is dominated by adsorbed films of water at grain-grain contacts in our experiments, not by global viscous dampening. d) There is a monotonically increasing effect of humidity on the dampening of the fundamental resonance within the granular medium which translates to a non-monotonic, but predictable, variation of dampening within the grain-loaded bar.

John Valenza; Chaur-Jian Hsu; Rohit Ingale; Nicolas Gland; Hernn A. Makse; David Linton Johnson

2009-05-08T23:59:59.000Z

51

Hydrodynamic modes in a confined granular fluid  

E-Print Network (OSTI)

Confined granular fluids, placed in a shallow box that is vibrated vertically, can achieve homogeneous stationary states thanks to energy injection mechanisms that take place throughout the system. These states can be stable even at high densities and inelasticities allowing for a detailed analysis of the hydrodynamic modes that govern the dynamics of granular fluids. Analyzing the decay of the time correlation functions it is shown that there is a crossover between a quasielastic regime in which energy evolves as a slow mode, to a inelastic regime, with energy slaved to the other conserved fields. The two regimes have well differentiated transport properties and, in the inelastic regime, the dynamics can be described by a reduced hydrodynamics with modified longitudinal viscosity and sound speed. The crossover between the two regimes takes place at a wavevector that is proportional to the inelasticity. A two dimensional granular model, with collisions that mimic the energy transfers that take place in a confined system is studied by means of microscopic simulations. The results show excellent agreement with the theoretical framework and allows the validation of hydrodynamic-like models.

Ricardo Brito; Dino Risso; Rodrigo Soto

2013-01-17T23:59:59.000Z

52

On universal structural characteristics of granular packs  

E-Print Network (OSTI)

Understanding the dependence of the structure of granular materials on grain parameters is key to predictive modelling of granular matter. Structural characteristics are commonly believed to be sensitive, for a given packing process, to intergranular friction, particle size distribution and initial conditions. We show here that the intergranular friction coefficient and the initial conditions are details, which can be scaled away, and that structures are determined mainly by the packing dynamics and the grain size distribution. This we do using the quadron description to analyse the structures of a number of numerically-generated planar disc packs in mechanical equilibrium, varying all these parameters. Our findings are as follows. 1. The mean coordination number is a universal function of the packing fraction, independent of the initial conditions, intergranular friction and size distribution we used, when "rattlers" are ignored. 2. For a given packing process and disc size distribution, both the total and conditional quadron volume distributions collapse to universal forms, independent of the initial conditions and intergranular friction. 3. The cell order distribution collapses to a universal form for all friction coefficients, initial conditions and for the two disc size distributions we studied. These results suggest that mechanically stable granular structures are determined mainly by the packing dynamics and the grains size / shape distributions - the effects of the intergranular friction and initial state can be scaled away and are therefore predictable.

Takashi Matsushima; Raphael Blumenfeld

2013-05-27T23:59:59.000Z

53

Moving Granular Bed Filter Development Program  

SciTech Connect

The granular bed filter was developed through low pressure, high temperature (1600{degrees}F) testing in the late 1970`s and early 1980`s`. Collection efficiencies over 99% were obtained. In 1988, high pressure, high temperature testing was completed at New York University, Westbury, N.Y., utilizing a coal-fired pressurized, fluidized bed combustor. High particulate removal efficiencies were confirmed as it was shown that both New Source Performance Standards and turbine tolerance limits could be met. The early scale-up work of the granular bed filter indicated potential limitations due to size, cost, and mechanical complexity. These limitations were addressed in the present program by utilizing the information gained from the filter development up through the NYU test program to reassess the commercial approach. Two studies were chosen for developing conceptual designs and cost estimates of the commercial sized filters. One is the economic study of the 250 MWe, second generation pressurized fluidized bed combustion plant defined by Foster Wheeler. This plant originally included cross-flow filters for hot gas cleanup. The other plant under study is a 100 MWe, airblown KRW gasifier. A cross-flow inter was utilized for gas stream cleanup in this study also. Granular bed and ceramic candle filters were substituted for the cross-flow filters in both these plants, and the resulting cost of electricity (COE) is compared.

Wilson, K.B.; Haas, J.C.; Eshelman, M.B.

1992-11-01T23:59:59.000Z

54

Moving Granular Bed Filter Development Program  

SciTech Connect

The granular bed filter was developed through low pressure, high temperature (1600[degrees]F) testing in the late 1970's and early 1980's'. Collection efficiencies over 99% were obtained. In 1988, high pressure, high temperature testing was completed at New York University, Westbury, N.Y., utilizing a coal-fired pressurized, fluidized bed combustor. High particulate removal efficiencies were confirmed as it was shown that both New Source Performance Standards and turbine tolerance limits could be met. The early scale-up work of the granular bed filter indicated potential limitations due to size, cost, and mechanical complexity. These limitations were addressed in the present program by utilizing the information gained from the filter development up through the NYU test program to reassess the commercial approach. Two studies were chosen for developing conceptual designs and cost estimates of the commercial sized filters. One is the economic study of the 250 MWe, second generation pressurized fluidized bed combustion plant defined by Foster Wheeler. This plant originally included cross-flow filters for hot gas cleanup. The other plant under study is a 100 MWe, airblown KRW gasifier. A cross-flow inter was utilized for gas stream cleanup in this study also. Granular bed and ceramic candle filters were substituted for the cross-flow filters in both these plants, and the resulting cost of electricity (COE) is compared.

Wilson, K.B.; Haas, J.C.; Eshelman, M.B.

1992-01-01T23:59:59.000Z

55

NETL: News Release - Clean Coal Technology Report Showcases Advanced Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

April 6, 2000 April 6, 2000 Clean Coal Technology Report Showcases Advanced Iron Making Process, Benefits for the Environment Topical Report Profiles Blast Furnace Granular Coal Injection System; Now Available on DOE's Fossil Energy Web Site An advanced iron making technology demonstrated in the U.S. Department of Energy's Clean Coal Technology Program stands out for its potential to provide major environmental and financial benefits to the United States steel industry. Bethlehem Steel Topical Report The Energy Department has profiled the project in a topical report entitled Blast Furnace Granular Coal Injection System Demonstration Project. The report describes the federal government's partnership demonstration project with Bethlehem Steel Corporation, which tested a new method for reducing

56

Optimization Online - Temporal vs. Stochastic Granularity in Thermal ...  

E-Print Network (OSTI)

Jul 25, 2013 ... Optimization Online. Temporal vs. Stochastic Granularity in Thermal Generation Capacity Planning with Wind Power. Shan Jin(shan.jin.c ***at**...

57

Buoyant Granular Ceramic Insulation for the Liquid Metal Cooled ...  

Science Conference Proceedings (OSTI)

Previous work showed that the buoyant granular insulation (floating baffle) used to insulate the liquid bath from the mold heater strongly influences the curvature...

58

Size separation in vibrated granular matter  

E-Print Network (OSTI)

We review recent developments in size separation in vibrated granular materials. Motivated by a need in industry to efficiently handle granular materials and a desire to make fundamental advances in non-equilibrium physics, experimental and theoretical investigations have shown size separation to be a complex phenomena. Large particles in a vibrated granular system invariably rise to the top. However, they may also sink to the bottom, or show other patterns depending on subtle variations in physical conditions. While size ratio is a dominant factor, particle specific properties such as density, inelasticity and friction can play an important role. The nature of the energy input, boundary conditions and interstitial air have been also shown to be significant factors in determining spatial distributions. The presence of convection can enhance mixing or lead to size separation. Experimental techniques including direct visualization and magnetic resonance imaging are being used to investigate these properties. Molecular dynamics and Monte Carlo simulation techniques have been developed to probe size separation. Analytical methods such as kinetic theory are being used to study the interplay between particle size and density in the vibro-fluidized regime, and geometric models have been proposed to describe size separation for deep beds. Besides discussing these studies, we will also review the impact of inelastic collision and friction on the density and velocity distributions to gain a deeper appreciation of the non-equilibrium nature of the system. While a substantial number of studies have been accomplished, considerable work is still required to achieve a firm description of the phenomena.

A. Kudrolli

2004-02-06T23:59:59.000Z

59

Oscillatory instability in a driven granular gas  

E-Print Network (OSTI)

We discovered an oscillatory instability in a system of inelastically colliding hard spheres, driven by two opposite "thermal" walls at zero gravity. The instability, predicted by a linear stability analysis of the equations of granular hydrodynamics, occurs when the inelasticity of particle collisions exceeds a critical value. Molecular dynamic simulations support the theory and show a stripe-shaped cluster moving back and forth in the middle of the box away from the driving walls. The oscillations are irregular but have a single dominating frequency that is close to the frequency at the instability onset, predicted from hydrodynamics.

Evgeniy Khain; Baruch Meerson

2003-11-13T23:59:59.000Z

60

Granular size segregation in underwater sand ripples  

E-Print Network (OSTI)

We report an experimental study of a binary sand bed under an oscillating water flow. The formation and evolution of ripples is observed. The appearance of a granular segregation is shown to strongly depend on the sand bed preparation. The initial wavelength of the mixture is measured. In the final steady state, a segregation in volume is observed instead of a segregation at the surface as reported before. The correlation between this phenomenon and the fluid flow is emphasised. Finally, different ``exotic'' patterns and their geophysical implications are presented.

G. Rousseaux; H. Caps; J. -E. Wesfreid

2004-03-29T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Numerical simulations of granular dynamics II. Particle dynamics in a shaken granular material  

E-Print Network (OSTI)

Surfaces of planets and small bodies of our Solar System are often covered by a layer of granular material that can range from a fine regolith to a gravel-like structure of varying depths. Therefore, the dynamics of granular materials are involved in many events occurring during planetary and small-body evolution thus contributing to their geological properties. We demonstrate that the new adaptation of the parallel N-body hard-sphere code pkdgrav has the capability to model accurately the key features of the collective motion of bidisperse granular materials in a dense regime as a result of shaking. As a stringent test of the numerical code we investigate the complex collective ordering and motion of granular material by direct comparison with laboratory experiments. We demonstrate that, as experimentally observed, the scale of the collective motion increases with increasing small-particle additive concentration. We then extend our investigations to assess how self-gravity and external gravity affect collective motion. In our reduced-gravity simulations both the gravitational conditions and the frequency of the vibrations roughly match the conditions on asteroids subjected to seismic shaking, though real regolith is likely to be much more heterogeneous and less ordered than in our idealised simulations. We also show that collective motion can occur in a granular material under a wide range of inter-particle gravity conditions and in the absence of an external gravitational field. These investigations demonstrate the great interest of being able to simulate conditions that are to relevant planetary science yet unreachable by Earth-based laboratory experiments.

Naomi Murdoch; Patrick Michel; Derek C. Richardson; Kerstin Nordstrom; Christian R. Berardi; Simon F. Green; Wolfgang Losert

2013-06-07T23:59:59.000Z

62

On-line Task Granularity Adaptation for Dynamic Grid Applications  

E-Print Network (OSTI)

On-line Task Granularity Adaptation for Dynamic Grid Applications Nithiapidary Muthuvelu1, Ian Chai by adjusting the task granularity at the grid scheduler. We propose an on-line scheduling algorithm which@csse.unimelb.edu.au Abstract. Deploying lightweight tasks on grid resources would let the commu- nication overhead dominate

Buyya, Rajkumar

63

An optimization of granular network by evolutionary methods  

Science Conference Proceedings (OSTI)

In this paper, we present an optimization method of GN (Granular Network) based on evolutionary methods such as PSO (Particle Swarm optimization) and GA (Genetic Algorithm). The GN is constructed by linguistic model using CFCM (Context-based Fuzzy C-Means) ... Keywords: context-based fuzzy c-means, genetic algorithm, granular network, information granules, particle swarm optimization

Yun-Hee Han; Keun-Chang Kwak

2010-02-01T23:59:59.000Z

64

Using NMR to Validate First-Principles Granular Flow Equations  

E-Print Network (OSTI)

Nuclear magnetic resonance (NMR) experiments are described for two granular-flow systems, the vibrofluidized bed and the gas-fluidized bed. Using pulsed field gradient, magnetic resonance imaging, and hyperpolarized gas NMR, detailed information is obtained for the density and motions of both grains and interstitial gas. For the vibrofluidized bed, the granular temperature profile is measured and compared with a first-principles formulation of granular hydrodynamics. For the gas-fluidized bed, dynamic correlations in the grain density are used to measure the bubble velocity and hyperpolarized xenon gas NMR is used to measure the bubble-emulsion exchange rate. A goal of these measurements is to verify in earth gravity first-principles theories of granular flows, which then can be used to make concrete predictions for granular flows in reduced gravity.

D. Candela; C. Huan; K. Facto; R. Wang; R. W. Mair; R. L. Walsworth

2005-10-23T23:59:59.000Z

65

Pressure-shear experiments on granular materials.  

SciTech Connect

Pressure-shear experiments were performed on granular tungsten carbide and sand using a newly-refurbished slotted barrel gun. The sample is a thin layer of the granular material sandwiched between driver and anvil plates that remain elastic. Because of the obliquity, impact generates both a longitudinal wave, which compresses the sample, and a shear wave that probes the strength of the sample. Laser velocity interferometry is employed to measure the velocity history of the free surface of the anvil. Since the driver and anvil remain elastic, analysis of the results is, in principal, straightforward. Experiments were performed at pressures up to nearly 2 GPa using titanium plates and at higher pressure using zirconium plates. Those done with the titanium plates produced values of shear stress of 0.1-0.2 GPa, with the value increasing with pressure. On the other hand, those experiments conducted with zirconia anvils display results that may be related to slipping at an interface and shear stresses mostly at 0.1 GPa or less. Recovered samples display much greater particle fracture than is observed in planar loading, suggesting that shearing is a very effective mechanism for comminution of the grains.

Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Thornhill, Tom Finley, III (, Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Alexander, C. Scott (Sandia National Laboratories, Albuquerque, NM)

2011-10-01T23:59:59.000Z

66

Extraterrestrial sink dynamics in granular matter  

E-Print Network (OSTI)

A loosely packed bed of sand sits precariously on the fence between mechanically stable and flowing states. This has especially strong implications for animals or vehicles needing to navigate sandy environments, which can sink and become stuck in a "dry quicksand" if their weight exceeds the yield stress of this fragile matter. While it is known that the contact stresses in these systems are loaded by gravity, very little is known about the sinking dynamics of objects into loose granular systems under gravitational accelerations different from the Earth's (g). A fundamental understanding of how objects sink in different gravitational environments is not only necessary for successful planetary navigation and engineering, but it can also improve our understanding of celestial impact dynamics and crater geomorphology. Here we perform and explain the first systematic experiments of the sink dynamics of objects into granular media in different gravitational accelerations. By using an accelerating experimental apparatus, we explore gravitational conditions ranging from 0.4g to 1.2g. With the aid of discrete element modeling simulations, we reproduce these results and extend this range to include objects as small as asteroids and as large as Jupiter. Surprisingly, we find that the final sink depth is independent of the gravitational acceleration, an observation with immediate relevance to the design of future extraterrestrial structures land-roving spacecraft. Using a phenomenological equation of motion that includes a gravity-loaded frictional term, we are able to quantitatively explain the experimental and simulation results.

E. Altshuler; H. Torres; A. Gonzlez-Pita; G. Snchez-Colina; C. Prez-Penichet; S. Waitukaitis; R. C. Hidalgo

2013-05-29T23:59:59.000Z

67

Dynamics of electrostatically driven granular media: Effects of humidity  

SciTech Connect

We performed experimental studies of the effect of humidity on the dynamics of electrostatically driven granular materials. Both conducting and dielectric particles undergo a phase transition from an immobile state (granular solid) to a fluidized state (granular gas) with increasing applied field. Spontaneous precipitation of solid clusters from the gas phase occurs as the external driving is decreased. The clustering dynamics in conducting particles is primarily controlled by screening of the electric field but is aided by cohesion due to humidity. It is shown that humidity effects dominate the clustering process with dielectric particles.

Howell, D. W.; Aronson, Igor S.; Crabtree, G. W.

2001-05-01T23:59:59.000Z

68

Defining and testing a granular continuum element  

Science Conference Proceedings (OSTI)

Continuum mechanics relies on the fundamental notion of amesoscopic volume "element" in which properties averaged over discreteparticles obey deterministic relationships. Recent work on granularmaterials suggests a continuum law may be inapplicable, revealinginhomogeneities at the particle level, such as force chains and slow cagebreaking. Here, we analyze large-scale Discrete-Element Method (DEM)simulations of different granular flows and show that a "granularelement" can indeed be defined at the scale of dynamical correlations,roughly three to five particle diameters. Its rheology is rather subtle,combining liquid-like dependence on deformation rate and solid-likedependence on strain. Our results confirm some aspects of classicalplasticity theory (e.g., coaxiality of stress and deformation rate),while contradicting others (i.e., incipient yield), and can guide thedevelopment of more realistic continuum models.

Rycroft, Chris H.; Kamrin, Ken; Bazant, Martin Z.

2007-12-03T23:59:59.000Z

69

Dispersion enhanced metal/zeolite catalysts  

DOE Patents (OSTI)

Dispersion stabilized zeolite supported metal catalysts are provided as bimetallic catalyst combinations. The catalyst metal is in a reduced zero valent form while the dispersion stabilizer metal is in an unreduced ionic form. Representative catalysts are prepared from platinum or nickel as the catalyst metal and iron or chromium dispersion stabilizer.

Sachtler, Wolfgang M. H. (Evanston, IL); Tzou, Ming-Shin (Evanston, IL); Jiang, Hui-Jong (Evanston, IL)

1987-01-01T23:59:59.000Z

70

IIT Bombay offers to license intellectual property (IP) created through its research and development efforts and which are available in the form of patents, patent applications, design, trademark, copy-  

E-Print Network (OSTI)

cell covered by an anti-reflective 3506/MUM/2010 coating (ARC) layer EE 26 Solar fluid heater 2502/MUM An improved process for water treatment to remove Arsenic, Iron and Phosphate 2336/MUM/2008 by zero valent EE 14 Refrigeration cum water heating system 151/MUM/2002 EE 15 Switchable heat pipe 152/MUM/2002 EE

Narayanan, H.

71

Bioremediation of Uranium Plumes with Nano-scale  

E-Print Network (OSTI)

Bioremediation of Uranium Plumes with Nano-scale Zero-valent Iron Angela Athey Advisers: Dr. Reyes Undergraduate Student Fellowship Program April 15, 2011 #12;Main Sources of Uranium Natural · Leaching from(IV) (UO2[s], uraninite) Anthropogenic · Release of mill tailings during uranium mining - Mobilization

Cushing, Jim. M.

72

Brownian motion in granular gases of viscoelastic particles  

Science Conference Proceedings (OSTI)

A theory is developed of Brownian motion in granular gases (systems of many macroscopic particles undergoing inelastic collisions), where the energy loss in inelastic collisions is determined by a restitution coefficient {epsilon}. Whereas previous studies used a simplified model with {epsilon} = const, the present analysis takes into account the dependence of the restitution coefficient on relative impact velocity. The granular temperature and the Brownian diffusion coefficient are calculated for a granular gas in the homogeneous cooling state and a gas driven by a thermostat force, and their variation with grain mass and size and the restitution coefficient is analyzed. Both equipartition principle and fluctuation-dissipation relations are found to break down. One manifestation of this behavior is a new phenomenon of 'relative heating' of Brownian particles at the expense of cooling of the ambient granular gas.

Bodrova, A. S., E-mail: bodrova@polly.phys.msu.ru; Brilliantov, N. V.; Loskutov, A. Yu. [Moscow State University (Russian Federation)

2009-12-15T23:59:59.000Z

73

Defect modes in one-dimensional granular crystals  

E-Print Network (OSTI)

We study the vibrational spectra of one-dimensional statically compressed granular crystals (arrays of elastic particles in contact) containing light-mass defects. We focus on the prototypical settings of one or two spherical ...

Boechler, Nicholas Sebastian

74

Iron and Prochlorococcus/  

E-Print Network (OSTI)

Iron availability and primary productivity in the oceans are intricately linked through photosynthesis. At the global scale we understand how iron addition induces phytoplankton blooms through meso-scale iron-addition ...

Thompson, Anne Williford

2009-01-01T23:59:59.000Z

75

Iron Absorption  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Absorption Iron Absorption Name: Mary Location: N/A Country: N/A Date: N/A Question: I wrote before to Steve and got a answer back. I would like more information. The cirmcustances were that I first had anaemia and then I went for a gastroscopy. The results of which were I had insufficient acid been produced in the stomach. I was told that acid was nessary for the absorbion of iron and it was because of this that I became anaemic. I was told to eat plently of red meat not too many vegetables. Is there any other information you can give me? Replies: It is very difficult to say for sure without seeing you chart and I am not your doctor. But it sounds to me like you are deficient in the vitamin B12. In your stomach you have 3 basic types of cells. One is called chief cells which secrete the precursor of the enzyme pepsin which begins the breakdown of protein. Another is called the parietal cells which secrete your stomach acid and a substance called intrinsic factor. Now-switch to your bone marrow which is where your red blood cells are made. In order for your red blood cells to mature in the bone marrow, vitamin B12 is necessary. B12 can only be obtained from animal food sources such as meat, milk and eggs. Unfortunately, B12 cannot be absorbed in the stomach without intrinsic factor. If there is sufficient B12 present in the diet, it can be stored in the liver. If you aren't eating enough animal sources your B12 will be taken from your liver until you run out. You could also be deficient in intrinsic factor. So while the outcome is anemia (not enough red blood cells) the problem could be from a few different things. Follow your doctor's recommendations and eat more sources of B12

76

Steady energy transfer dependence granular temperature on single bouncing granular particle  

E-Print Network (OSTI)

Simulation of a system consisted of free particle bouncing on a vertically vibrated based is performed. Two different states, which are steady and unsteady energy transfer state are found. The vibrating based is hold at constant vibration frequency $f = 0.1$ as the vibration amplitude $A$ varied. Sinusoidal form is used. Granular temperature $T_g$ as function of based velocity and coefficient of restitution is used but shown no role in determining energy transfer state of the system. Peak of free particle trajectory $x_m$ around value 20 seperate region of the two states.

Suparno Satira; Sparisoma Viridi; Freddy P Zen

2011-06-09T23:59:59.000Z

77

Assessing continuum postulates in simulations of granular flow  

Science Conference Proceedings (OSTI)

Continuum mechanics relies on the fundamental notion of a mesoscopic volume"element" in which properties averaged over discrete particles obey deterministic relationships. Recent work on granular materials suggests a continuum law may be inapplicable, revealing inhomogeneities at the particle level, such as force chains and slow cage breaking. Here, we analyze large-scale three-dimensional Discrete-Element Method (DEM) simulations of different granular flows and show that an approximate"granular element" defined at the scale of observed dynamical correlations (roughly three to five particle diameters) has a reasonable continuum interpretation. By viewing all the simulations as an ensemble of granular elements which deform and move with the flow, we can track material evolution at a local level. Our results confirm some of the hypotheses of classical plasticity theory while contradicting others and suggest a subtle physical picture of granular failure, combining liquid-like dependence on deformation rate and solid-like dependence on strain. Our computational methods and results can be used to guide the development of more realistic continuum models, based on observed local relationships betweenaverage variables.

Rycroft, Chris; Kamrin, Ken; Bazant, Martin

2008-08-26T23:59:59.000Z

78

Granular physics in low-gravity environments using DEM  

E-Print Network (OSTI)

Granular materials of different sizes are present on the surface of several atmosphere-less Solar System bodies. The phenomena related to granular materials have been studied in the framework of the discipline called Granular Physics; that has been studied experimentally in the laboratory and, in the last decades, by performing numerical simulations. The Discrete Element Method simulates the mechanical behavior of a media formed by a set of particles which interact through their contact points. The difficulty in reproducing vacuum and low-gravity environments makes numerical simulations the most promising technique in the study of granular media under these conditions. In this work, relevant processes in minor bodies of the Solar System are studied using the Discrete Element Method. Results of simulations of size segregation in low-gravity environments in the cases of the asteroids Eros and Itokawa are presented. The segregation of particles with different densities was analysed, in particular, the case of comet P/Hartley 2. The surface shaking in these different gravity environments could produce the ejection of particles from the surface at very low relative velocities. The shaking causing the above processes is due to: impacts, explosions like the release of energy by the liberation of internal stresses or the re accommodation of material. Simulations of the passage of impact-induced seismic waves through a granular medium were also performed. We present several applications of the Discrete Element Methods for the study of the physical evolution of agglomerates of rocks under low-gravity environments.

G. Tancredi; A. Maciel; L. Heredia; P. Richeri; S. Nesmachnow

2011-11-26T23:59:59.000Z

79

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and understanding into the role of elevated temperature and pressure regimes on physical properties of reconsolidated crushed salt, 2) can supplement an existing database used to develop a reconsolidation constitutive model and 3) provide data for model evaluation. The constitutive model accounts for the effects of moisture through pressure solution and dislocation creep, with both terms dependent

80

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and understanding into the role of elevated temperature and pressure regimes on physical properties of reconsolidated crushed salt, 2) can supplement an existing database used to develop a reconsolidation constitutive model and 3) provide data for model evaluation. The constitutive model accounts for the effects of moisture through pressure solution and dislocation creep, with both terms dependent

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Density-permittivity relationships for powdered and granular materials  

SciTech Connect

Relationships between the permittivities of powdered or granular solid materials and their bulk densities (density of the air-particle mixture) are discussed. Linear relationships between functions of the permittivity and bulk density are identified that are useful in determining permittivity of solids from measurements of the permittivity of pulverized samples. The usefulness of several dielectric mixture equations for calculating solid material permittivity from measured permittivity of pulverized samples is also discussed. Results of testing linear extrapolation techniques and dielectric mixture equations on pulverized coal, limestone, plastics, and granular wheat and flour are presented. Recommendations are provided for reliable estimation of solid material permittivities or changes in permittivities of powdered and granular materials as a result of changes in their bulk densities.

Nelson, S.O. [USDA ARS, Athens, GA (United States). Russell Research Center

2005-10-01T23:59:59.000Z

82

Phase transition or Maxwell's demon in Granular gas?  

E-Print Network (OSTI)

Dynamics of vibro-fluidised granular gas is investigated experimentally using the transfer of grains from a compartment through a horizontal slit at a given height h . It is demonstrated that the transfer rate j varies linearly with the grain number N in the box when N remains small; however j(N) becomes strongly non linear as soon as the number n of layers is larger than 0.3; dj/dN becomes negative for n>0.4.It is found also that the maximum of j(N) increases slightly with the acceleration af_ of the vibration which excites the granular gas. Using dynamical system theory, dynamics equations are written, and a critical bifurcation is found, which explains the existence of a condensation and of a phase transition. This explains how the pseudo " Maxwell's demon" works in granular gases. This experiments contradicts recent modeling . Pacs # : 5.40 ; 45.70 ; 62.20 ; 83.70.Fn

P. Jean; H. Bellenger; P. Burban; L. Ponson; P. Evesque

2005-06-23T23:59:59.000Z

83

Implicit continuum mechanics approach to heat conduction in granular materials  

SciTech Connect

In this paper, we derive a properly frame-invariant implicit constitutive relationship for the heat flux vector for a granular medium (or a density-gradient-type fluid). The heat flux vector is commonly modeled by Fouriers law of heat conduction, and for complex materials such as nonlinear fluids, porous media, or granular materials, the coefficient of thermal conductivity is generalized by assuming that it would depend on a host of material and kinematic parameters such as temperature, shear rate, porosity, concentration, etc. In this paper, we extend the approach of Massoudi [Massoudi, M. Math. Methods Appl. Sci. 2006, 29, 1585; Massoudi, M. Math. Methods Appl. Sci. 2006, 29, 1599], who provided explicit constitutive relations for the heat flux vector for flowing granular materials; in order to do so, we use the implicit scheme suggested by Fox [Fox, N. Int. J. Eng. Sci. 1969, 7, 437], who obtained implicit relations in thermoelasticity.

Massoudi, M.; Mehrabadi, M.

2010-01-01T23:59:59.000Z

84

Hard Sphere Dynamics for Normal and Granular Fluids  

E-Print Network (OSTI)

A fluid of N smooth, hard spheres is considered as a model for normal (elastic collisions) and granular (inelastic collisions) fluids. The potential energy is discontinuous for hard spheres so the pairwise forces are singular and the usual forms of Newtonian and Hamiltonian mechanics do not apply. Nevertheless, particle trajectories in the N particle phase space are well defined and the generators for these trajectories can be identified. The first part of this presentation is a review of the generators for the dynamics of observables and probability densities. The new results presented in the second part refer to applications of these generators to the Liouville dynamics for granular fluids. A set of eigenvalues and eigenfunctions of the generator for this Liouville dynamics is identified in a special "stationary representation". This provides a class of exact solutions to the Liouville equation that are closely related to hydrodynamics for granular fluids.

James W. Dufty; Aparna Baskaran

2005-03-08T23:59:59.000Z

85

A granular neural network: Performance analysis and application to re-granulation  

Science Conference Proceedings (OSTI)

The multi-granularity problem is one of the key open problems in Granular Computing. Multiple descriptions of the same phenomena may use very different information granulations, complicating any comparison or synthesis of those descriptions. One method ... Keywords: Fuzzy logic, Granular computing, Linguistic hedges, Linguistic variables, Neural networks, Neuro-fuzzy systems

Scott Dick, Andrew Tappenden, Curtis Badke, Olufemi Olarewaju

2013-10-01T23:59:59.000Z

86

Conditions for optimum giant magnetoresistance in granular metals  

SciTech Connect

The dependence of the giant magnetoresistance (GMR) of a metallic granular system on the concentration of magnetic particles is studied numerically. The effect of particle coalescence and dipolar interactions between the particles on the value of optimum GMR and the shape of the concentration dependence curve are discussed. The micromagnetic configuration of the system is obtained by a Monte Carlo algorithm that involves short-range effective exchange couplings and long range dipolar interactions. The conductivity is obtained using Kubo{close_quote}s formula for a tight binding Hamiltonian. A comparison of our results to experiments on metallic granular films is made. {copyright} 2001 American Institute of Physics.

Kechrakos, D.; Trohidou, K. N.

2001-06-01T23:59:59.000Z

87

Energy Loss at Propagating Jamming Fronts in Granular Gas Clusters  

E-Print Network (OSTI)

We explore the initial moments of impact between two dense granular clusters in a two-dimensional geometry. The particles are composed of solid CO$_{2}$ and are levitated on a hot surface. Upon collision, the propagation of a dynamic "jamming front" produces a distinct regime for energy dissipation in a granular gas in which the translational kinetic energy decreases by over 90%. Experiments and associated simulations show that the initial loss of kinetic energy obeys a power law in time, $\\Delta E=-Kt^{3/2}$, a form that can be predicted from kinetic arguments.

Justin C. Burton; Peter Y. Lu; Sidney R. Nagel

2013-06-12T23:59:59.000Z

88

Competitive Clustering in a Bi-disperse Granular Gas  

E-Print Network (OSTI)

A bi-disperse granular gas in a compartmentalized system is experimentally found to cluster competitively: Depending on the shaking strength, the clustering can be directed either towards the compartment initially containing mainly small particles, or to the one containing mainly large particles. The experimental observations are quantitatively explained within a flux model.

Ren Mikkelsen; Devaraj van der Meer; Ko van der Weele; Detlef Lohse

2002-10-06T23:59:59.000Z

89

Oracle scheduling: controlling granularity in implicitly parallel languages  

Science Conference Proceedings (OSTI)

A classic problem in parallel computing is determining whether to execute a task in parallel or sequentially. If small tasks are executed in parallel, the task-creation overheads can be overwhelming. If large tasks are executed sequentially, processors ... Keywords: granularity control, scheduling, work stealing

Umut A. Acar; Arthur Charguraud; Mike Rainey

2011-10-01T23:59:59.000Z

90

Patterns in Flowing Sand: Understanding the Physics of Granular Flow  

E-Print Network (OSTI)

Dense granular flows are often unstable and form inhomogeneous structures. Although significant advances have been recently made in understanding simple flows, instabilities of such flows are often not understood. We present experimental and numerical results that show the formation of longitudinal stripes that arise from instability of the uniform flowing state of granular media on a rough inclined plane. The form of the stripes depends critically on the mean density of the flow with a robust form of stripes at high density that consists of fast sliding plug-like regions (stripes) on top of highly agitated boiling material - a configuration reminiscent of the Leidenfrost effect when a droplet of liquid lifted by its vapor is hovering above a hot surface.

Tamas Borzsonyi; Robert E. Ecke; Jim N. McElwaine

2009-10-01T23:59:59.000Z

91

Hydrodynamic granular segregation induced by boundary heating and shear  

E-Print Network (OSTI)

Segregation induced by a thermal gradient of an impurity in a driven low-density granular gas is studied. The system is enclosed between two parallel walls from which we input thermal energy to the gas. We study here steady states occurring when the inelastic cooling is exactly balanced by some external energy input (stochastic force or viscous heating), resulting in a uniform heat flux. A segregation criterion based on Navier-Stokes granular hydrodynamics is written in terms of the tracer diffusion transport coefficients, whose dependence on the parameters of the system (masses, sizes and coefficients of restitution) is explicitly determined from a solution of the inelastic Boltzmann equation. The theoretical predictions are validated by means of Monte Carlo and molecular dynamics simulations, showing that Navier-Stokes hydrodynamics produces accurate segregation criteria even under strong shearing and/or inelasticity.

Francisco Vega Reyes; Vicente Garz; Nagi Khalil

2013-10-02T23:59:59.000Z

92

Mixing and segregation rates in sheared granular materials  

E-Print Network (OSTI)

The size-segregation of granular materials, a process colloquially known as the Brazil Nut Effect, has generally been thought to proceed faster the greater the size difference of the particles. We experimentally investigate sheared bidisperse granular materials as a function of the size ratio of the two species, and find that the mixing rate at low confining pressure behaves as expected from percolation-based arguments. However, we also observe an anomalous effect for the re-segregation rates, wherein particles of both dissimilar and similar sizes segregate more slowly than intermediate particle size ratios. Combined with the fact that increasing the confining pressure significantly suppresses both mixing and segregation rates of particles of dissimilar size, we propose that the anomalous behavior may be attributed to a species-dependent distribution of forces within the system.

Laura A. Golick; Karen E. Daniels

2009-06-17T23:59:59.000Z

93

Fluctuating hydrodynamics and correlation lengths in a driven granular fluid  

E-Print Network (OSTI)

Static and dynamical structure factors for shear and longitudinal modes of the velocity and density fields are computed for a granular system fluidized by a stochastic bath with friction. Analytical expressions are obtained through fluctuating hydrodynamics and are successfully compared with numerical simulations up to a volume fraction $\\sim 50%$. Hydrodynamic noise is the sum of external noise due to the bath and internal one due to collisions. Only the latter is assumed to satisfy the fluctuation-dissipation relation with the average granular temperature. Static velocity structure factors $S_\\perp(k)$ and $S_\\parallel(k)$ display a general non-constant behavior with two plateaux at large and small $k$, representing the granular temperature $T_g$ and the bath temperature $T_b>T_g$ respectively. From this behavior, two different velocity correlation lengths are measured, both increasing as the packing fraction is raised. This growth of spatial order is in agreement with the behaviour of dynamical structure factors, the decay of which becomes slower and slower at increasing density.

Giacomo Gradenigo; Alessandro Sarracino; Dario Villamaina; Andrea Puglisi

2011-07-07T23:59:59.000Z

94

Moving granular-bed filter development program. Topical report  

Science Conference Proceedings (OSTI)

Advanced, coal-based, power plants, such as IGCC and Advanced-PFBC, are currently nearing commercial demonstration. These power plant technologies require hot gas filtration as part of their gas cleaning trains. Ceramic barrier filters are the major filter candidates being developed for these hot gas cleaning applications. While ceramic barrier filters achieve high levels of particle removal, concerns exist for their reliability and operability in these applications. An alternative hot gas filtration technology is the moving granular bed filter. An advanced, moving granular bed filter has been conceived, and early development activities performed by the Westinghouse Electric Corporation, Science and Technology Center. This document reports on the Base Contract tasks performed to resolve the barrier technical issues for this technology. The concept, the Standleg Moving Granular Bed Filter (SMGBF) has a concurrent downward, gas and bed media flow configuration that results in simplified features and improved scaleup feasibility compared to alternative designs. Two modes of bed media operation were assessed in the program: once-through using pelletized power plant waste as bed media, and recycle of bed media via standleg and pneumatic transport techniques. Cold Model testing; high-temperature, high-pressure testing; and pelletization testing using advanced power plant wastes, have been conducted in the program. A commercial, economic assessment of the SMGBF technology was performed for IGCC and Advanced-PFBC applications. The evaluation shows that the barrier technical issues can be resolved, and that the technology is potentially competitive with ceramic barrier filters.

Newby, R.A.; Yang, W.C.; Smeltzer, E.E.; Lippert, T.E.

1994-04-01T23:59:59.000Z

95

Moving granular-bed filter development program topical report  

SciTech Connect

The Westinghouse Science Technology Center has proposed a novel moving granular-bed filter concept, the Standleg Moving Granular-Bed Filter (S-MGBF) system, that overcomes the inherent deficiencies of the current state-of-the-art moving granular-bed filter technology. The S-MGBF system combines two unique features that make it highly effective for use in advanced coal-fueled power plants. First, the S-MGBF system applies pelletization technology to generate filter pellets from the power plant solid waste materials, and uses these pellets as a once-through'' filtering media to eliminate the need for costly, complex, and large filter media recycling equipment. This pelletizing step also generates a more environmentally acceptable solid waste product and provides the potential to incorporate gas-phase contaminant sorbents into the filtering media. Secondly, the S-MGBF system passes these pellets and the flyash laden power plant gas through a highly compact S-MGBF that uses cocurrent gas-pellet contacting in an arrangement that greatly simplifies and enhances the distribution of dirty gas to the moving bed and the disengagement of clean gas from the moving bed.

Newby, R.A.; Dilmore, W.J.; Fellers, A.W.; Gasparovic, A.C.; Kittle, W.F.; Lippert, T.E.; Smeltzer, E.E.; Yang, W.C.

1991-10-17T23:59:59.000Z

96

Applications of moving granular-bed filters to advanced systems  

SciTech Connect

The contract is arranged as a base contract with three options. The objective of the base contract is to develop conceptual design(s) of moving granular bed filter and ceramic candle filter technology for control of particles from integrated gasification combined cycle (IGCC) systems, pressurized fluidized-bed combustors (PFBC), and direct coal fueled turbine (DCFT) environments. The conceptual design(s) of these filter technologies are compared, primarily from an economic perspective. The granular bed filter was developed through low pressure, high temperature (1600{degree}F) testing in the late 1970`s and early 1980`s. Collection efficiencies over 99% were obtained. In 1988, high pressure, high temperature testing was completed at New York University, Westbury, N.Y., utilizing a two advanced power generating plants were chosen for developing conceptual designs and cost estimates of the commercial sized filters. One is the 450 MWe, second generation pressurized fluidized bed combustion plant defined by Foster Wheeler. This plant originally included cross-flow filters for hot gas cleanup. The other plant under study is a 100 MWe, KRW air blown gasifier. A cross-flow filter was utilized for gas stream cleanup in this study also. Granular bed and ceramic candle filters were substituted for the cross-flow filters in both these plants, and the resulting costs were compared.

Wilson, K.W.; Haas, J.C.; Eshelman, M.B.

1993-09-01T23:59:59.000Z

97

Thermal fluctuations of granular gas under HCS using two-point kinetic theory  

E-Print Network (OSTI)

Thermal fluctuations of the granular gas under the homogeneous cooling state (HCS) are estimated using two-point kinetic theory by Tsuge-Sagara. Thermal fluctuations of the elastic gas are modified for the granular gas by nonequilibrium moments, which defines the distribution function under the HCS. The deviations of thermal fluctuations for the granular gas from those for the elastic gas obtained by the fluctuation-dissipation theorem are calculated as a function of the restitution coefficient.

Yano, Ryosuke

2011-01-01T23:59:59.000Z

98

ZIRCONIUM IRON DISPROPORTIONATION DURING ...  

Science Conference Proceedings (OSTI)

... These Zr3Fe and Zr2Fe button samples were made at LANL by arc melting stoichiometric amounts of zirconium and iron in an argon atmosphere. ...

2012-11-26T23:59:59.000Z

99

Method and means for continuous precipitation of easy-dry, granular uranium peroxide  

SciTech Connect

A method and means for continuous precipitation of granular uranium peroxide. The reaction vessel and agitation method practiced in it avoid filter plugging and caking problems.

Cahill, Allen E. (Roland, IA); Burkhart, deceased, Lawrence E. (late of Ames, IA)

1992-02-28T23:59:59.000Z

100

Relaxed Consistency and Coherence Granularity in DSM Systems: A Performance Evaluation  

E-Print Network (OSTI)

granularity works well with 7 of the 12 applications. The combination of a multiple­writer, home­based lazy

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Propagao do momento linear e energia cintica em cadeias granulares afiladas.  

E-Print Network (OSTI)

??Recentemente, cadeias granulares afiladas tem sido objeto de estudo para o desenvolvimento de dispositivos absorvedores de impacto (ondas de choque). A caracter?stica deste sistema em (more)

Luis Paulo Silveira Machado

2011-01-01T23:59:59.000Z

102

Cast Irons - Programmaster.org  

Science Conference Proceedings (OSTI)

Oct 20, 2011 ... Processing, Microstructure and Properties of Cast Irons and Cast and Forged Specialty Steels: Cast Irons Sponsored by: MS&T Organization

103

Forcing and Velocity Correlations in a Vibrated Granular Monolayer  

E-Print Network (OSTI)

The role of forcing on the dynamics of a vertically shaken granular monolayer is investigated. Using a flat plate, surprising negative velocity correlations are measured. A mechanism for this anti-correlation is proposed with support from both experimental results and molecular dynamics simulations. Using a rough plate, velocity correlations are positive, and the velocity distribution evolves from a gaussian at very low densities to a broader distribution at high densities. These results are interpreted as a balance between stochastic forcing, interparticle collisions, and friction with the plate.

Alexis Prevost; David A. Egolf; Jeffrey S. Urbach

2002-03-14T23:59:59.000Z

104

KNOTS AND RANDOM WALKS IN VIBRATED GRANULAR CHAINS  

Science Conference Proceedings (OSTI)

The authors study experimentally statistical properties of the opening times of knots in vertically vibrated granular chains. Our measurements are in good qualitative and quantitative agreement with a theoretical model involving three random walks interacting via hard core exclusion in one spatial dimension. In particular, the knot survival probability follows a universal scaling function which is independent of the chain length, with a corresponding diffusive characteristic time scale. Both the large-exit-time and the small-exit-time tails of the distribution are suppressed exponentially, and the corresponding decay coefficients are in excellent agreement with the theoretical values.

E. BEN-NAIM; ET AL

2000-08-01T23:59:59.000Z

105

Energy trapping and shock disintegration in a composite granular medium  

E-Print Network (OSTI)

Granular materials demonstrate a strongly nonlinear behavior influencing the wave propagation in the medium. We report the first experimental observation of impulse energy confinement and the resultant disintegration of shock and solitary waves. The medium consists of alternating ensambles of high-modulus vs orders of magnitude lower modulus chains of different masses. The trapped energy is contained within the "softer" portions of the composite chain and is slowly released in the form of weak, separated pulses over an extended period of time. This effect is enhanced by using a specific group assembly and superimposed force.

C. Daraio; V. F. Nesterenko; E. B. Herbold; S. Jin

2005-09-24T23:59:59.000Z

106

Granular convection and the Brazil nut effect in reduced gravity  

E-Print Network (OSTI)

We present laboratory experiments of a vertically vibrated granular medium consisting of 1 mm diameter glass beads with embedded 8 mm diameter intruder glass beads. The experiments were performed in the laboratory as well as in a parabolic flight under reduced-gravity conditions (on Martian and Lunar gravity levels). We measured the mean rise velocity of the large glass beads and present its dependence on the fill height of the sample containers, the excitation acceleration, and the ambient gravity level. We find that the rise velocity scales in the same manner for all three gravity regimes and roughly linearly with gravity.

Carsten Gttler; Ingo von Borstel; Rainer Schrpler; Jrgen Blum

2013-04-02T23:59:59.000Z

107

Several applications of a model for dense granular flows  

E-Print Network (OSTI)

aggregates. Furthermore, few children (at least in developed countries) will not, at some point in their lives, have sculpted castles, faces, or animals out of sand or snow. There are countless engineering applications involving granular materials, some... in more than one dimension. We shall discuss some strategies for dealing with sub-yield regions numerically in 2.2. The bounded nature of (I) for large I is also a desirable feature of the rheological law (1.14), because it reflects the notion...

Cawthorn, Christopher John

2011-03-15T23:59:59.000Z

108

Compaction and mobility in randomly agitated granular assemblies  

E-Print Network (OSTI)

We study the compaction and mobility properties of a dense granular material under weak random vibration. By putting in direct contact millimetric glass beads with piezoelectric transducers we manage to inject energy to the system in a disordered manner with accelerations much smaller than gravity, resulting in a slow compaction dynamics and no convection. We characterize the mobility inside the medium by pulling through it an intruder grain at constant velocity. We present an extensive study of the relation between drag force and velocity for different vibration conditions and sizes of the intruder.

G. Caballero; J. Lanuza; E. Clement

2005-04-25T23:59:59.000Z

109

Algorithm for direct numerical simulation of emulsion flow through a granular material  

Science Conference Proceedings (OSTI)

A multipole-accelerated 3D boundary-integral algorithm capable of modelling an emulsion flow through a granular material by direct multiparticle-multidrop simulations in a periodic box is developed and tested. The particles form a random arrangement ... Keywords: Deformable drop, Emulsion, Granular material, Multipole

Alexander Z. Zinchenko; Robert H. Davis

2008-08-01T23:59:59.000Z

110

Stripes ordering in self-stratification experiments of binary and ternary granular mixtures  

E-Print Network (OSTI)

The self-stratification of binary and ternary granular mixtures has been experimentally investigated. Ternary mixtures lead to a particular ordering of the strates which was not accounted for in former explanations. Bouncing grains are found to have an important effect on strate formation. A complementary mechanism for self-stratification of binary and ternary granular mixtures is proposed.

N. Lecocq; N. Vandewalle

2000-04-25T23:59:59.000Z

111

Regeneration Effect of Fluoride-rich Granular Activated Alumina on Desorption Regent NaOH Solution  

Science Conference Proceedings (OSTI)

As an effective adsorbent, granular activated alumina (GAA) has been widely used in defluoridation. In order to reduce cost and operate environment-friendly, the adsorbent should be regenerated. In this paper, column experiment was done to characterize ... Keywords: adsorption, regeneration, defluoridation, granular activated alumina

Baijie Niu; Wenming Ding; Dan Dang

2012-05-01T23:59:59.000Z

112

Energy saving and cost reduction in multi-granularity green optical networks  

Science Conference Proceedings (OSTI)

With the energy consumption increase and the greenhouse effect becomes more and more serious, the energy saving has become the focus in the whole world. At the same time, as the network traffic largely growing, the size and the cost of network equipments ... Keywords: Cost reduction, Energy saving, Green optical networks, Multi-granularity, Multi-granularity grooming

Xingwei Wang; Weigang Hou; Lei Guo; Jiannong Cao; Dingde Jiang

2011-02-01T23:59:59.000Z

113

Construction Summary and As-Built Report for Ground Water Treatment System  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Construction Summary and As-Built Report for Ground Water Treatment Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site Construction Summary and As-Built Report for Ground Water Treatment System Monticello, Utah, Permeable Reactive Barrier Site More Documents & Publications Dispersivity Testing of Zero-Valent Iron Treatment Cells: Monticello, Utah, November 2005 Through February 2008 Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah Performance Assessment and Recommendations for Rejuvenation of a Permeable

114

Microsoft Word - S03840_MNT ZVI Treat Cells_Feb08.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ground-Water Table and Chemical Changes Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells January 2008 DOE LM/1560 2008 - - ESL RPT 2008-01 - - Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AC01 02GJ79491 - - Approved for public release; distribution is unlimited. Environmental Sciences Laboratory Environmental Sciences Laboratory Environmental Sciences Laboratory Environmental Sciences Laboratory Environmental Sciences Laboratory This page intentionally left blank DOE-LM/1560-2007 ESL-RPT-2008-01 Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells

115

Microsoft Word - S02808.doc  

Office of Legacy Management (LM)

Sciences Laboratory Sciences Laboratory Environmental Sciences Laboratory Prepared for U.S. Department of Energy Grand Junction, Colorado Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 DOE-LM/1379-2006 ESL-RPT-2006-03 Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AC01 02GJ79491 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1379-2006 ESL-RPT-2006-03 Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491

116

Microsoft Word - S02808.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sciences Laboratory Sciences Laboratory Environmental Sciences Laboratory Prepared for U.S. Department of Energy Grand Junction, Colorado Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 DOE-LM/1379-2006 ESL-RPT-2006-03 Work Performed nder DOE Contract No. for the U.S. Department of Energy Office of Legacy Management. by the S.M. Stoller Corporation u DE AC01 02GJ79491 - - Approved for public release; distribution is unlimited. This page intentionally left blank DOE-LM/1379-2006 ESL-RPT-2006-03 Third (March 2006) Coring and Analysis of Zero-Valent Iron Permeable Reactive Barrier, Monticello, Utah November 2006 Work Performed by S.M. Stoller Corporation under DOE Contract No. DE-AC01-02GJ79491

117

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

71 - 22380 of 26,764 results. 71 - 22380 of 26,764 results. Download Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells http://energy.gov/lm/downloads/ground-water-table-and-chemical-changes-alluvial-aquifer-during Download DOE-STD-3006-2000 Planning and Conduct of Operational Readiness Reviews Replaced by DOE-STD-3006-2010 | Superseding DOE-STD-3006-95 (November 1995) DOE O 425.1B specifies the conditions and circumstances when an Operational Readiness Review (ORR) or a Readiness Assessment (RA) is required as part of a new start or restart process. This standard provides guidance on the

118

The effect of limb kinematics on the speed of a legged robot on granular media  

E-Print Network (OSTI)

Achieving effective locomotion on diverse terrestrial substrates can require subtle changes of limb kinematics. Biologically inspired legged robots (physical models of organisms) have shown impressive mobility on hard ground but suffer performance loss on unconsolidated granular materials like sand. Because comprehensive limb-ground interaction models are lacking, optimal gaits on complex yielding terrain have been determined empirically. To develop predictive models for legged devices and to provide hypotheses for biological locomotors, we systematically study the performance of SandBot, a small legged robot, on granular media as a function of gait parameters. High performance occurs only in a small region of parameter space. A previously introduced kinematic model of the robot combined with a new anisotropic granular penetration force law predicts the speed. Performance on granular media is maximized when gait parameters minimize body acceleration and limb interference, and utilize solidification features of granular media.

Chen Li; Paul B. Umbanhowar; Haldun Komsuoglu; Daniel I. Goldman

2013-03-29T23:59:59.000Z

119

A cross-layer optimization based integrated routing and grooming algorithm for green multi-granularity transport networks  

Science Conference Proceedings (OSTI)

With the development of IP networks and intelligent optical switch networks, the backbone network tends to be a multi-granularity transport one. In a multi-granularity transport network (MTN), due to the rapid growth of various applications, the scale ... Keywords: Biogeography-based optimization, Green integrated routing and grooming, Multi-granularity transport network, Multi-user QoS satisfaction degree

Xingwei Wang, Hui Cheng, Keqin Li, Jie Li, Jiajia Sun

2013-06-01T23:59:59.000Z

120

Westinghouse standleg moving granular bed filter development program  

SciTech Connect

Advanced, coal-based, power plants, such as IGCC and Advanced-PFBC, are currently nearing commercial demonstration. These power plant technologies require hot gas filtration as part of their gas cleaning trains. Ceramic barrier filters are the major filter candidates being developed for these hot gas cleaning applications. While ceramic barrier filters achieve high levels of particle removal, there are concerns for their reliability and operability. An alternative hot gas filtration technology is the moving granular bed filter. These systems are at a lower state of development than ceramic barrier filters, and their effectiveness as filters is still in question. Their apparent attributes, result from their much less severe mechanical design and materials constraints, and the potential for more reliable, failure-free particle removal operation. The standleg moving granular-bed filter (SMGBF) system, is a compact unit that uses cocurrent gas-pellet contacting in an arrangement that greatly simplifies and enhances the distribution of dirty, process gas to the moving bed and allows effective disengagement of clean gas from the moving bed. This paper describes the equipment and process test results.

Newby, R.A.; Yang, W.C.; Smeltzer, E.E.; Lippert, T.E.

1994-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

iron and steel making  

Science Conference Proceedings (OSTI)

Gas-Solid Reaction Will Help Solid-Solid ReactionNovel Iron Ore Agglomerate Bearing Semi-Coal-Char (Keynote) [pp. 97-104] T. Usui, H. Konishi, and N.

122

Gas-Mediated Impact Dynamics in Fine-Grained Granular Materials  

E-Print Network (OSTI)

Non-cohesive granular media exhibit complex responses to sudden impact that often differ from those of ordinary solids and liquids. We investigate how this response is mediated by the presence of interstitial gas between the grains. Using high-speed x-ray radiography we track the motion of a steel sphere through the interior of a bed of fine, loose granular material. We find a crossover from nearly incompressible, fluid-like behavior at atmospheric pressure to a highly compressible, dissipative response once most of the gas is evacuated. We discuss these results in light of recent proposals for the drag force in granular media.

John R. Royer; Eric I. Corwin; Peter J. Eng; Heinrich M. Jaeger

2007-02-14T23:59:59.000Z

123

Dense Granular Flows Sebastian Chialvo and Sankaran Sundaresan  

NLE Websites -- All DOE Office Websites (Extended Search)

and Refinement and Refinement of a Comprehensive Model for Dense Granular Flows Sebastian Chialvo and Sankaran Sundaresan Princeton University This work is supported by DOE-UCR grant DE-FE0006932. Logo The NETL logotype illustrated on this page is the institutional signature for the U.S. Department of Energy, National Energy Technology Laboratory-NETL. Its function is to be the graphic identi cation for that organization. The relationship among the elements of this logo is essential to preserve this identity. The speci cations included on these pages will assist in the proper display of this logo and should be fol- lowed exactly. Questions concerning this logo and its application may be addressed to the NETL O ce of Public A airs Coordination, Contact.PublicA airs@NETL.DOE.GOV.

124

The interactions between comminution, segregation and remixing in granular flows  

E-Print Network (OSTI)

Granular segregation is an important mechanism for industrial processes aiming at mixing grains. Additionally, it plays a pivotal role in determining the kinematics of geophysical flows. Because of segregation, the grainsize distribution varies in space and time. Additional complications arise from the presence of comminution, where new particles are created, enhancing segregation. This has a feedback on the comminution process, as particles change their local neighbourhood. Simultaneously, particles are generally undergoing remixing, further complicating the segregation and comminution processes. The interaction between these mechanisms is explored using a cellular automaton with three rules: one for each of segregation, comminution and mixing. The interplay between these rules creates complex patterns, as seen in segregating systems, and depth dependent grading curves, which have been observed in avalanche runout. At every depth, log-normal grading curves are produced at steady state, as measured experimentally in avalanche and debris flow deposits.

Benjy Marks; Itai Einav

2013-04-16T23:59:59.000Z

125

Ultrasonic properties of granular media saturated with dnapl/watermixtures  

SciTech Connect

We present the results of four experiments investigating the ultrasonic properties of granular materials partially saturated with trichloroethylene (TCE), a dense non-aqueous contaminant. P-wave velocity measurements were made under in situ effective stress conditions using a pulse transmission cell at ?250 kHz. Two synthetic samples and two natural aquifer cores were fully saturated with water and then subjected to an axial injection of TCE. The resulting measurements show reductions in P-wave velocity of up to 15% due to contaminant saturation. A theoretical model combining Gassmann fluid substitution and Hill's equation was used to estimate the effects of DNAPL saturation; this model underpredicted observed reductions in velocity at high TCE saturations. A linear relationship, expressed in terms of volumetric contaminant fraction, provided an excellent empirical fit to the laboratory measurements.

Ajo-Franklin, J.B.; Geller, J.T.; Harris, J.M.

2007-09-15T23:59:59.000Z

126

Mechanical and acoustic properties of weakly cemented granular rocks  

SciTech Connect

This paper presents the results of laboratory measurements on the mechanical and acoustic properties of weakly cemented granular rock. Artificial rock samples were fabricated by cementing sand and glass beads with sodium silicate binder. During uniaxial compression tests, the rock samples showed stress-strain behavior which was more similar to that of soils than competent rocks, exhibiting large permanent deformations with frictional slip. The mechanical behavior of the samples approached that of competent rocks as the amount of binder was increased. For very weak samples, acoustic waves propagating in these rocks showed very low velocities of less than 1000 m/sec for compressional waves. A borehole made within this weakly cemented rock exhibited a unique mode of failure that is called ''anti-KI mode fracture'' in this paper. The effect of cementation, grain type, and boundary conditions on this mode of failure was also examined experimentally.

Nakagawa, S.; Myer, L.R.

2001-05-09T23:59:59.000Z

127

Electrostatic granular bed filter development program. Final report  

SciTech Connect

The application of the electrostatically enhanced granular bed filter (EGB) in a pressurized fluidized bed (PFB) combined cycle power plant is explored in this study. In a PFB combustor power plant, dust particles entrained in the combustion gases must be removed at high temperature (1700/sup 0/F) and pressure (10 atm) in order to protect a gas turbine from erosion. The EFB filter provides a unique design adapted to avoid filter front face plugging which has been the limiting factor in the successful development of granular bed filters for this application. Under the present study, laboratory experiments and analyses were performed to provide the engineering data necessary to design a test module in the actual PFB environment. An analytical model for predicting the performance of an EGB was also developed. The test data and the model were then utilized to establish preferred geometries and operating parameters of the EGB filter system applied in a 663 MWe PFB power plant. Preliminary conceptual designs were established and an economic evaluations performed. The results of the system analysis and economic studies were analyzed to assess the applicability of the EGB filter to utility scale PFB power plants. New power plants must also meet New Source Performance Standards (.03 lb/10/sup 6/ Btu) which necessitates removal of dust in the respirable size range which would otherwise be harmless to the gas turbine. A key technical issue in the PFB application is whether the hot gas cleanup equipment can satisfy the NSPS. The potential of the EGB for achieving NSPS ahead of the gas turbine is demonstrated, and the conceptual design and economics of this application are presented. (LCL)

1981-11-01T23:59:59.000Z

128

Iron Pots and Kettles  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Pots and Kettles Iron Pots and Kettles Nature Bulletin No. 544-A November 16, 1974 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation IRON POTS AND KETTLES At Possum Trot Hill, on US 150 west of Danville, a huge iron kettle squats as a monument to what was once an important industry in Illinois. It is one of 80 used from 1824 to 1831 for boiling down brine from salt springs in that vicinity. Salt was a luxury then. About a bushel was produced from one kettleful (100 gallons) of brine and that was worth more than 100 bushels of oats. Those 80 monsters came from Kentucky where iron works had been established to make the utensils and implements desperately needed by pioneer families. About half of them had come up through the Cumberland Gap, on horseback, with only a rifle, an ax, a pot for cooking, some bedding and the clothes on their backs. Every family, in addition to a skillet or spider, and a Dutch oven, coveted a big kettle for making salt, soap, candles and maple syrup, butchering hogs, rendering lard, boiling clothes on wash day, and dyeing homespun material for garments.

129

Study of gas flow dynamics in porous and granular media with laser-polarized ?Xe NMR  

E-Print Network (OSTI)

This thesis presents Nuclear Magnetic Resonance (NMR) studies of gas flow dynamics in porous and granular media by using laser-polarized ?Xe . Two different physical processes, the gas transport in porous rock cores and ...

Wang, Ruopeng, 1972-

2005-01-01T23:59:59.000Z

130

Energy Dissipation in Driven Granular Matter in the Absence of Gravity  

E-Print Network (OSTI)

We experimentally investigate the energy dissipation rate in sinusoidally driven boxes which are partly filled by granular material under conditions of weightlessness. We identify two different modes of granular dynamics, depending on the amplitude of driving, $A$. For intense forcing, A>A_0, the material is found in the collect-and-collide regime where the center of mass of the granulate moves synchronously with the driven container while for weak forcing, Agranular material exhibits gas-like behavior. Both regimes correspond to different dissipation mechanisms, leading to different scaling with amplitude and frequency of the excitation and with the mass of the granulate. For the collect-and-collide regime, we explain the dependence on frequency and amplitude of the excitation by means of an effective one-particle model. For both regimes, the results may be collapsed to a single curve characterizing the physics of granular dampers.

Achim Sack; Michael Heckel; Jonathan E. Kollmer; Fabian Zimber; Thorsten Poeschel

2013-05-05T23:59:59.000Z

131

The Granular Sea Ice Model in Spherical Coordinates and Its Application to a Global Climate Model  

Science Conference Proceedings (OSTI)

The granular sea ice model (GRAN) from Tremblay and Mysak is converted from Cartesian to spherical coordinates. In this conversion, the metric terms in the divergence of the deviatoric stress and in the strain rates are included. As an ...

Jan Sedlacek; Jean-Franois Lemieux; Lawrence A. Mysak; L. Bruno Tremblay; David M. Holland

2007-12-01T23:59:59.000Z

132

It's Elemental - The Element Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

Manganese Manganese Previous Element (Manganese) The Periodic Table of Elements Next Element (Cobalt) Cobalt The Element Iron [Click for Isotope Data] 26 Fe Iron 55.845 Atomic Number: 26 Atomic Weight: 55.845 Melting Point: 1811 K (1538°C or 2800°F) Boiling Point: 3134 K (2861°C or 5182°F) Density: 7.874 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 4 Group Number: 8 Group Name: none What's in a name? From the Anglo-Saxon word iron. Iron's chemical symbol comes from the Latin word for iron, ferrum. Say what? Iron is pronounced as EYE-ern. History and Uses: Archaeological evidence suggests that people have been using iron for at least 5000 years. Iron is the cheapest and one of the most abundant of all metals, comprising nearly 5.6% of the earth's crust and nearly all of the

133

Measurement of displacements in granular systems in response to penetration and compaction  

E-Print Network (OSTI)

dynamic penetration experiments, a granular materials behaviour most closely resembles that of a fluid. Hydrodynamic approximations, in which the material is treated as a fluid, have been successfully used to predict a variety of experimental parameters... be included, has also been applied to this area [27, 28]. Again, however, there is the limitation of treating the material as a continuum. Current modelling efforts are directed towards determining the forces experi- enced by individual particles in a granular...

Addiss, John

2010-02-09T23:59:59.000Z

134

EPRI BWR Iron Control Monitoring Final Report  

Science Conference Proceedings (OSTI)

This report summarizes the state of iron control in U.S. BWRs as of July 1999 and documents the implementation and performance status of new iron control technologies. Issues involving the relationship between iron control and radiation dose control, iron control with deep beds, iron control with filters, and iron addition are documented, and areas for future research are noted.

1999-09-16T23:59:59.000Z

135

Mechanisms in the size segregation of a binary granular mixture  

E-Print Network (OSTI)

A granular mixture of particles of two sizes that is shaken vertically will in most cases segregate. If the larger particles accumulate at the top of the sample, this is called the Brazil-nut effect (BNE); if they accumulate at the bottom, the reverse Brazil-nut effect (RBNE). While this process is of great industrial importance in the handling of bulk solids, it is not well understood. In recent years ten different mechanisms have been suggested to explain when each type of segregation is observed. However, the dependence of the mechanisms on driving conditions and material parameters and hence their relative importance is largely unknown. In this paper we present experiments and simulations where both types of particles are made from the same material and shaken under low air pressure, which reduces the number of mechanisms to be considered to seven. We observe both BNE and RBNE by varying systematically the driving frequency and amplitude, diameter ratio, ratio of total volume of small to large particles, and overall sample volume. All our results can be explained by a combination of three mechanisms: a geometrical mechanism called void filling, transport of particles in sidewall-driven convection rolls, and thermal diffusion, a mechanism predicted by kinetic theory.

M. Schrter; S. Ulrich; J. Kreft; J. B. Swift; H. L. Swinney

2006-01-10T23:59:59.000Z

136

Meeting on flows of granular materials in complex geometries  

Science Conference Proceedings (OSTI)

The International Energy Agency Fossil Fuel Multiphase Flow Sciences Agreement has been in effect since 1986. The traditional mechanism for the effort has been information exchange, effected by the inclusion of scientists in annual Executive committee meetings, by exchange of reports and papers, and by visits of scientists to one another`s institutions. In a sequence of informal meetings and at the 1993 Executive committee meeting, held in Pittsburgh, US in March 1994, it was decided that more intensive interactions could be productive. A candidate for such interactions would be specific projects. Each of these would be initiated through a meeting of scientists in which feasibility of the particular project was decided, followed by relatively intense international co-operation in which the work would be done. This is a report of the first of these meetings. Official or unofficial representatives from Canada, italy, japan, mexico, the United Kingdom, and the US met in Albuquerque, New Mexico, US, to consider the subject Flows of Granular Materials in Complex Geometries. Representatives of several other countries expressed interest but were unable to attend this meeting. Sixteen lectures were given on aspects of this topic. It was decided that a co-operative effort was desirable and possible. The most likely candidate for the area of study would be flows in bins and hoppers. Each of the countries wishing to co-operate will pursue funding for its effort. This report contains extended abstracts of the sixteen presentations and a transcription of the final discussion.

Passman, S.L.; Fukushima, E.; Evans, R.E. [eds.

1994-11-01T23:59:59.000Z

137

Removal of taste and odor producing organic substances in water supply in post-filter granular activated carbon adsorber systems.  

E-Print Network (OSTI)

??O objetivo desta pesquisa foi o de estudar o desempenho de ps-filtros adsorvedores de carvo ativado granular de origem mineral e de origem vegetal, com (more)

Carolina Alves de Souza Ferreira

2009-01-01T23:59:59.000Z

138

Iron pages of HTSC  

Science Conference Proceedings (OSTI)

Experimental data are presented on the superconducting and electronic properties of iron-based high-temperature superconductors in the normal and superconducting states. The following topics are discussed: lattice structure; structure of magnetic vortices; magnetic penetration depth; Fermi surface; isotope effect; and critical magnetic fields both in oxide compounds of 1111 type and oxide-free compounds of 122, 111, and 011 types as a function of the doping level, temperature, and external pressure.

Gasparov, V. A., E-mail: vgasparo@issp.ac.r [Russian Academy of Sciences, Institute of Solid State Physics (Russian Federation)

2010-08-15T23:59:59.000Z

139

Differential Characterization of Ikperejere Iron shale and Iron ...  

Science Conference Proceedings (OSTI)

Kaolinite was found in the iron shale. Trace elements were Mn, Mg, Ti, Ca, Na .... High Temperature Exposure of Oil Well Cements In-Situ EBSD Investigation of...

140

Microbial reduction of iron ore  

DOE Patents (OSTI)

A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry.

Hoffmann, Michael R. (Pasadena, CA); Arnold, Robert G. (Pasadena, CA); Stephanopoulos, Gregory (Pasadena, CA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Microbial reduction of iron ore  

DOE Patents (OSTI)

A process is provided for reducing iron ore by treatment with microorganisms which comprises forming an aqueous mixture of iron ore, microorganisms operable for reducing the ferric iron of the iron ore to ferrous iron, and a substrate operable as an energy source for the microbial reduction; and maintaining the aqueous mixture for a period of time and under conditions operable to effect the reduction of the ore. Preferably the microorganism is Pseudomonas sp. 200 and the reduction conducted anaerobically with a domestic wastewater as the substrate. An aqueous solution containing soluble ferrous iron can be separated from the reacted mixture, treated with a base to precipitate ferrous hydroxide which can then be recovered as a concentrated slurry. 11 figs.

Hoffmann, M.R.; Arnold, R.G.; Stephanopoulos, G.

1989-11-14T23:59:59.000Z

142

Enzymes of respiratory iron oxidation  

DOE Green Energy (OSTI)

This report describes experimental progress in characterizing and identifying redox proteins in a number of iron-oxidizing bacteria. Sections of the paper are entitled (1) In Situ electrolysis was explored to achieve enhanced yields of iron-oxidizing bacteria, (2)Structure/function studies were performed on redox-active biomolecules from Thiobacillus ferrooxidans, (3) Novel redox-active biomolecules were demonstrated in other iron autotrophs, and (4) New probes of metalloprotein electron-transfer reactions were synthesized and characterized.

Blake, R. II.

1992-01-01T23:59:59.000Z

143

Characterization of the Drag Force in an Air-Moderated Granular Bed  

E-Print Network (OSTI)

We measure the torque acting on a rod rotated perpendicular to its axis in a granular bed, through which an upflow of gas is utilized to tune the hydrostatic loading between grains. At low rotation rates the torque is independent of speed, but scales quadratically with rod-length and linearly with depth; the proportionality approaches zero linearly as the upflow of gas is increased towards a critical value above which the grains are fluidized. At high rotation rates the torque exhibits quadratic rate- dependence and scales as the rod's length to the 4th power. The torque has no dependence on either depth or airflow at these higher rates. A model used to describe the stopping force experienced by a projectile impacting a granular bed can be shown to predict these behaviors for our system's geometry, indicating that the same mechanics dictate both steady-state and transient drag forces in granular systems, regardless of geometry or material properties of the grains.

Theodore A Brzinski III; Douglas J Durian

2009-12-14T23:59:59.000Z

144

Granular Brownian motor This article has been downloaded from IOPscience. Please scroll down to see the full text article.  

E-Print Network (OSTI)

Granular Brownian motor This article has been downloaded from IOPscience. Please scroll down to see) 50003 www.epljournal.org doi: 10.1209/0295-5075/77/50003 Granular Brownian motor B. Cleuren and C. Van. ­ Brownian motors are spatially asymmetric constructions that, operating under nonequi- librium conditions

Weeks, Eric R.

145

CONTROL OF INTERFACIAL DUST CAKE TO IMPROVE EFFICIENCY OF MOVING BED GRANULAR FILTERS  

Science Conference Proceedings (OSTI)

The goal of this research is to improve the performance of moving bed granular filters for gas cleaning at high temperatures and pressures. A second objective is to better understand dust capture interfacial phenomena and cake formation in moving bed filters. The experimental bed tested in the present study has several unique design features configured as cold flow, axially symmetric, counter-current flow to simulate a filter operating at high temperatures (1088 K) and elevated pressures (10 atmospheres). The granular filter is evaluated in two separate performance studies: (1) optimization of particle collection efficiency and bed pressure drop in a factorial study at near-atmospheric operating pressures through appropriate use of granular bed materials, particle sizes, and feed rates; and (2) high temperature and high pressure model simulation conducted at above-atmospheric pressures and room temperature utilizing dust and granular flow rates, granular size, system pressure, and superficial velocity. The factorial study involves a composite design of 16 near-atmospheric tests, while the model simulation study is comprised of 7 above-atmospheric tests. Similarity rules were validated in tests at four different mass dust ratios and showed nearly constant collection efficiencies ({approx} 99.5 {+-} 0.3%) for operating pressures of 160 kPa gage (23.2 psig) at room temperature (20 C), which simulates the hydrodynamic conditions expected for typical gasification streams (1088 K, 10 atmospheres). An important outcome from the near-atmospheric pressure studies are relationships developed using central composite design between the independent variables, superficial velocity (0.16-0.22 m/s), dust feed rate (0.08-0.74 kg/hr), and granular flow rate (3.32-15.4 kg/hr). These operating equations were optimized in contour plots for bed conditions that simultaneously satisfy low-pressure drop and high particle collection efficiency.

Robert C. Brown; Gerald M. Colver

2002-10-31T23:59:59.000Z

146

Improving Efficiency of a Counter-Current Flow Moving Bed Granular Filter  

DOE Green Energy (OSTI)

The goal of this research is to improve the performance of moving bed granular filters for gas cleaning at high temperatures and pressures. A second goal of the research is to optimize the performances of both solids and gas filtering processes through appropriate use of granular bed materials, particle sizes, feed rates etc. in a factorial study. These goals are directed toward applications of advanced coal-fired power cycles under development by the U.S. Department of Energy including pressurized fluidized bed combustion and integrated gasification/combined cycles based on gas turbines and fuel cells. Only results for particulate gas cleaning are reported here.

Colver, G.M.; Brown, R.C.; Shi, H.; Soo, D.S-C.

2002-09-18T23:59:59.000Z

147

Sphere penetration by impact in a granular medium: A collisional process  

E-Print Network (OSTI)

The penetration by a gravity driven impact of a solid sphere into a granular medium is studied by two-dimensional simulations. The scaling laws observed experimentally for both the final penetration depth and the stopping time with the relevant physical parameters are here recovered numerically without the consideration of any solid friction. Collisional processes are thus found as essential in explaining the physics of the qualitatively observed phenomena whereas frictional processes can only be considered as secondary effects in the granular penetration by impact.

Antoine Seguin; Yann Bertho; Philippe Gondret; Jerome Crassous

2009-07-20T23:59:59.000Z

148

Experimental study of work exchange with a granular gas: the viewpoint of the Fluctuation Theorem  

E-Print Network (OSTI)

This article reports on an experimental study of the fluctuations of energy flux between a granular gas and a small driven harmonic oscillator. The DC-motor driving this system is used simultaneously as actuator and probe. The statistics of work fluctuations at controlled forcing, between the motor and the gas are examined from the viewpoint of the Fluctuation Theorem. A characteristic energy $E_c$ of the granular gas, is obtained from this relation between the probabilities of an event and its reversal.

Antoine Naert

2011-07-26T23:59:59.000Z

149

Track segments in hadronic showers in a highly granular scintillator-steel hadron calorimeter  

E-Print Network (OSTI)

We investigate the three dimensional substructure of hadronic showers in the CALICE scintillator-steel hadronic calorimeter. The high granularity of the detector is used to find track segments of minimum ionising particles within hadronic showers, providing sensitivity to the spatial structure and the details of secondary particle production in hadronic cascades. The multiplicity, length and angular distribution of identified track segments are compared to GEANT4 simulations with several different shower models. Track segments also provide the possibility for in-situ calibration of highly granular calorimeters.

CALICE Collaboration; C. Adloff; J. -J. Blaising; M. Chefdeville; C. Drancourt; R. Gaglione; N. Geffroy; Y. Karyotakis; I. Koletsou; J. Prast; G. Vouters; K. Francis; J. Repond; J. Schlereth; J. Smith; L. Xia; E. Baldolemar; J. Li; S. T. Park; M. Sosebee; A. P. White; J. Yu; G. Eigen; Y. Mikami; N. K. Watson; G. Mavromanolakis; M. A. Thomson; D. R. Ward; W. Yan; D. Benchekroun; A. Hoummada; Y. Khoulaki; J. Apostolakis; D. Dannheim; A. Dotti; G. Folger; V. Ivantchenko; W. Klempt; E. van der Kraaij; A. -I. Lucaci-Timoce; A. Ribon; D. Schlatter; V. Uzhinskiy; C. Carloganu; P. Gay; S. Manen; L. Royer; M. Tytgat; N. Zaganidis; G. C. Blazey; A. Dyshkant; J. G. R. Lima; V. Zutshi; J. -Y. Hostachy; L. Morin; U. Cornett; D. David; G. Falley; K. Gadow; P. Gttlicher; C. Gnter; O. Hartbrich; B. Hermberg; S. Karstensen; F. Krivan; K. Krger; S. Lu; S. Morozov; V. Morgunov; M. Reinecke; F. Sefkow; P. Smirnov; M. Terwort; N. Feege; E. Garutti; S. Laurien; I. Marchesini; M. Matysek; M. Ramilli; K. Briggl; P. Eckert; T. Harion; H. -Ch. Schultz-Coulon; W. Shen; R. Stamen; B. Bilki; E. Norbeck; Y. Onel; G. W. Wilson; K. Kawagoe; Y. Sudo; T. Yoshioka; P. D. Dauncey; A. -M. Magnan; V. Bartsch; M. Wing; F. Salvatore; E. Cortina Gil; S. Mannai; G. Baulieu; P. Calabria; L. Caponetto; C. Combaret; R. Della Negra; G. Grenier; R. Han; J-C. Ianigro; R. Kieffer; I. Laktineh; N. Lumb; H. Mathez; L. Mirabito; A. Petrukhin; A. Steen; W. Tromeur; M. Vander Donckt; Y. Zoccarato; E. Calvo Alamillo; M. -C. Fouz; J. Puerta-Pelayo; F. Corriveau; B. Bobchenko; M. Chadeeva; M. Danilov; A. Epifantsev; O. Markin; R. Mizuk; E. Novikov; V. Popov; V. Rusinov; E. Tarkovsky; N. Kirikova; V. Kozlov; P. Smirnov; Y. Soloviev; P. Buzhan; A. Ilyin; V. Kantserov; V. Kaplin; A. Karakash; E. Popova; V. Tikhomirov; C. Kiesling; K. Seidel; F. Simon; C. Soldner; M. Szalay; M. Tesar; L. Weuste; M. S. Amjad; J. Bonis; S. Callier; S. Conforti di Lorenzo; P. Cornebise; Ph. Doublet; F. Dulucq; J. Fleury; T. Frisson; N. van der Kolk; H. Li; G. Martin-Chassard; F. Richard; Ch. de la Taille; R. Pschl; L. Raux; J. Rouene; N. Seguin-Moreau; M. Anduze; V. Balagura; V. Boudry; J-C. Brient; R. Cornat; M. Frotin; F. Gastaldi; E. Guliyev; Y. Haddad; F. Magniette; G. Musat; M. Ruan; T. H. Tran; H. Videau; B. Bulanek; J. Zacek; J. Cvach; P. Gallus; M. Havranek; M. Janata; J. Kvasnicka; D. Lednicky; M. Marcisovsky; I. Polak; J. Popule; L. Tomasek; M. Tomasek; P. Ruzicka; P. Sicho; J. Smolik; V. Vrba; J. Zalesak; B. Belhorma; H. Ghazlane; K. Kotera; T. Takeshita; S. Uozumi; D. Jeans; M. Gtze; J. Sauer; S. Weber; C. Zeitnitz

2013-05-30T23:59:59.000Z

150

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two...

151

About The Iron and Steel Society  

Science Conference Proceedings (OSTI)

The IRON & STEEL SOCIETY (ISS) is a professional and technical society that provides opportunities for networking among iron and steel industry professionals...

152

Modeling Sea Ice as a Granular Material, Including the Dilatancy Effect  

Science Conference Proceedings (OSTI)

A dynamic sea ice model based on granular material rheology is presented. The sea ice model is coupled to both a mixed layer ocean model and a one-layer thermodynamic atmospheric model, which allows for an ice albedo feedback. Land is represented ...

L-B. Tremblay; L. A. Mysak

1997-11-01T23:59:59.000Z

153

Non-equilibrium fluctuations in frictional granular motor: experiments and kinetic theory  

E-Print Network (OSTI)

We report the study of a new experimental granular Brownian motor, inspired to the one published in [Phys. Rev. Lett. 104, 248001 (2010)], but different in some ingredients. As in that previous work, the motor is constituted by a rotating pawl whose surfaces break the rotation-inversion symmetry through alternated patches of different inelasticity, immersed in a gas of granular particles. The main novelty of our experimental setup is in the orientation of the main axis, which is parallel to the (vertical) direction of shaking of the granular fluid, guaranteeing an isotropic distribution for the velocities of colliding grains, characterized by a variance $v_0^2$. We also keep the granular system diluted, in order to compare with Boltzmann-equation-based kinetic theory. In agreement with theory, we observe for the first time the crucial role of Coulomb friction which induces two main regimes: (i) rare collisions (RC), with an average drift $\\ \\sim v_0^3$, and (ii) frequent collisions (FC), with $\\ \\sim v_0$. We also study the fluctuations of the angle spanned in a large time interval, $\\Delta \\theta$, which in the FC regime is proportional to the work done upon the motor. We observe that the Fluctuation Relation is satisfied with a slope which weakly depends on the relative collision frequency.

Andrea Gnoli; Alessandro Sarracino; Alberto Petri; Andrea Puglisi

2013-04-11T23:59:59.000Z

154

Navier-Stokes hydrodynamics of thermal collapse in a freely cooling granular gas  

E-Print Network (OSTI)

We employ Navier-Stokes granular hydrodynamics to investigate the long-time behavior of clustering instability in a freely cooling dilute granular gas in two dimensions. We find that, in circular containers, the homogeneous cooling state (HCS) of the gas loses its stability via a sub-critical pitchfork bifurcation. There are no time-independent solutions for the gas density in the supercritical region, and we present analytical and numerical evidence that the gas develops thermal collapse unarrested by heat diffusion. To get more insight, we switch to a simpler geometry of a narrow-sector-shaped container. Here the HCS loses its stability via a transcritical bifurcation. For some initial conditions a time-independent inhomogeneous density profile sets in, qualitatively similar to that previously found in a narrow-channel geometry. For other initial conditions, however, the dilute gas develops thermal collapse unarrested by heat diffusion. We determine the dynamic scalings of the flow close to collapse analytically and verify them in hydrodynamic simulations. The results of this work imply that, in dimension higher than one, Navier-Stokes hydrodynamics of a dilute granular gas is prone to finite-time density blowups. This provides a natural explanation to the formation of densely packed clusters of particles in a variety of initially dilute granular flows.

Itamar Kolvin; Eli Livne; Baruch Meerson

2009-12-03T23:59:59.000Z

155

Analysis of granular flow in a pebble-bed nuclear reactor Chris H. Rycroft,1  

E-Print Network (OSTI)

Analysis of granular flow in a pebble-bed nuclear reactor Chris H. Rycroft,1 Gary S. Grest,2 James February 2006; published 24 August 2006 Pebble-bed nuclear reactor technology, which is currently being States, the Modular Pebble Bed Reactor MPBR 4,8 is a candidate for the next generation nuclear plant

Bazant, Martin Z.

156

NANOPRISM: a tool for evaluating granularity vs. reliability trade-offs in nano architectures  

Science Conference Proceedings (OSTI)

It is expected that nano-scale devices and interconnections will introduce unprecedented level of defects, noise and interferences in the substrates. This consideration motivates the search for new architectural paradigms based on redundancy based defect-tolerant ... Keywords: CTMR, PRISM, TMR, defect-tolerant architecture, granularity, nanotechnology

Debayan Bhaduri; Sandeep K. Shukla

2004-04-01T23:59:59.000Z

157

Iron Mountain Electromagnetic Results  

SciTech Connect

Iron Mountain Mine is located seventeen miles northwest of Redding, CA. After the completion of mining in early 1960s, the mine workings have been exposed to environmental elements which have resulted in degradation in water quality in the surrounding water sheds. In 1985, the EPA plugged ore stoops in many of the accessible mine drifts in an attempt to restrict water flow through the mine workings. During this process little data was gathered on the orientation of the stoops and construction of the plugs. During the last 25 years, plugs have begun to deteriorate and allow acidic waters from the upper workings to flow out of the mine. A team from Idaho National Laboratory (INL) performed geophysical surveys on a single mine drift and 3 concrete plugs. The project goal was to evaluate several geophysical methods to determine competence of the concrete plugs and orientation of the stopes.

Gail Heath

2012-07-01T23:59:59.000Z

158

Continuum representation of a continuous size distribution of particles engaged in rapid granular flow  

Science Conference Proceedings (OSTI)

Natural and industrial granular flows often consist of several particle sizes, approximately forming a continuous particle size distribution (PSD). Continuous PSDs are ubiquitous, though existing kinetic-theory-based, hydrodynamic models for rapid granular flows are limited to a discrete number of species. The objective of this work is twofold: (i) to determine the number of discrete species required to accurately approximate a continuous PSD and (ii) to validate these results via a comparison with molecular dynamics (MD) simulations of continuous PSDs. With regard to the former, several analytic (Gaussian and lognormal) and experimental (coal and lunar soil simulants) distributions are investigated. Transport coefficients (pressure, shear viscosity, etc.) of the granular mixture given by the polydisperse theory of Garzo et al. [Enskog theory for polydisperse granular mixtures. I. Navier-Stokes order transport, Phys. Rev. E 76, 031303 (2007);Enskog theory for polydisperse granular mixtures. I. Navier-Stokes order transport, 76, 031304 (2007)] are compared using an increasing number of species s to approximate the given PSD. These discrete approximations are determined by matching the first 2s moments of the approximation and the given continuous distribution. Relatively few species are required to approximate moderately wide distributions (Gaussian, lognormal), whereas even wider distributions (coal and lunar soil simulants) require a larger number of species. Regarding the second objective, a comparison between MD simulations and kinetictheory predictions for a simple shear flow of both Gaussian and lognormal PSDs reveal essentially no loss of accuracy stemming from the polydisperse theory itself (as compared to theories for monodisperse systems) or from the discrete approximations of continuous PSDs used in the polydisperse theory. C #2; 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4744987

Murray, J.A.; Benyahia, S.; Metzger, P.; Hrenya, C.M.

2012-01-01T23:59:59.000Z

159

Mechanisms of Iron and Slag Separation in Carbon Composite Iron ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

160

Iron Edison Battery Company | Open Energy Information  

Open Energy Info (EERE)

Iron Edison Battery Company Iron Edison Battery Company Jump to: navigation, search Logo: Iron Edison Battery Company Name Iron Edison Battery Company Place Lakewood, Colorado Sector Bioenergy, Carbon, Efficiency, Hydro, Renewable Energy, Solar, Wind energy Product Nickel Iron (Ni-Fe) battery systems Year founded 2011 Number of employees 1-10 Phone number 202-681-4766 Website http://ironedison.com Region Rockies Area References Iron Edison Battery Company[1] Nickel Iron Battery Specifications[2] About the company and the owners[3] Nickel Iron Battery Association[4] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Iron Edison Battery Company is a company based in Lakewood, Colorado. Iron Edison is redefining off-grid energy storage using advanced

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Process for the synthesis of iron powder  

DOE Patents (OSTI)

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder. 2 figs.

Welbon, W.W.

1983-11-08T23:59:59.000Z

162

Process for the synthesis of iron powder  

DOE Patents (OSTI)

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Not Available

1982-03-06T23:59:59.000Z

163

Process for the synthesis of iron powder  

DOE Patents (OSTI)

A process for preparing iron powder suitable for use in preparing the iron-potassium perchlorate heat-powder fuel mixture used in thermal batteries, comprises preparing a homogeneous, dense iron oxide hydroxide precipitate by homogeneous precipitation from an aqueous mixture of a ferric salt, formic or sulfuric acid, ammonium hydroxide and urea as precipitating agent; and then reducing the dense iron oxide hydroxide by treatment with hydrogen to prepare the iron powder.

Welbon, William W. (Belleair, FL)

1983-01-01T23:59:59.000Z

164

Energy in Iron and Steel  

Science Conference Proceedings (OSTI)

Energy Technologies and Carbon Dioxide Management: Energy in Iron and Steel ... today imposed by energy, raw materials supply and over supply in the market. ... Through the studies of CCT, TTT and X-ray analysis, it has been successfully...

165

Iron catalyzed coal liquefaction process  

DOE Patents (OSTI)

A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

1983-01-01T23:59:59.000Z

166

Clean Coal III Project: Blast Furnace Granular Coal Injection Project Trial 1 Report - Blast Furnace Granular Coal Injection - Results with Low Volatile Coal  

SciTech Connect

This report describes the first coal trial test conducted with the Blast Furnace Granular Coal Injection System at Bethlehem Steel Corporation's Burns Harbor Plant. This demonstration project is divided into three phases: Phase I - Design Phase II - Construction Phase III - Operation The design phase was conducted in 1991-1993. Construction of the facility began in August 1993 and was completed in late 1994. The coal injection facility began operating in January 1995 and Phase III began in November 1995. The Trial 1 base test orI C furnace was carried out in October 1996 as a comparison period for the analysis of the operation during subsequent coal trials.

1997-11-01T23:59:59.000Z

167

Argonne CNM News: Hollow Iron Oxide Nanoparticles for Lithium...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hollow Iron Oxide Nanoparticles for Lithium-Ion Battery Applications Hollow iron oxide nanoparticles Transmission electron micrograph of hollow iron oxide nanoparticles....

168

Iron/Iron Oxide Core/Shell Nanoparticles for MRI and Magnetic ...  

Science Conference Proceedings (OSTI)

Bulk Nanoceramics and Nanocomposites: Processed by Pulsed Electric Current ... Iron/Iron Oxide Core/Shell Nanoparticles for MRI and Magnetic Hyperthermia.

169

Blast furnace granular coal injection project. Annual report, January--December 1993  

SciTech Connect

This initial annual report describes the Blast Furnace Granular Coal Injection project being implemented at Bethlehem Steel Corporation`s (BSC) Burns Harbor, Indiana, plant. This installation will be the first in the United States to employ British Steel technology that uses granular coal to provide part of the fuel requirement of blast furnaces. The project will demonstrate/assess a broad range of technical/economic issues associated with the use of coal for this purpose. These include: coal grind size, coal injection rate, coal source (type) and blast furnace conversion method. Preliminary Design (Phase 1) began in 1991 with detailed design commencing in 1993. Construction at Burns Harbor (Phase 2) began in August 1993. Construction is expected to complete in the first quarter of 1995 which will be followed by the demonstration test program (Phase 3). Progress is described.

1994-06-01T23:59:59.000Z

170

DETECTION OF SMALL-SCALE GRANULAR STRUCTURES IN THE QUIET SUN WITH THE NEW SOLAR TELESCOPE  

SciTech Connect

Results of a statistical analysis of solar granulation are presented. A data set of 36 images of a quiet-Sun area on the solar disk center was used. The data were obtained with the 1.6 m clear aperture New Solar Telescope at Big Bear Solar Observatory and with a broadband filter centered at the TiO (705.7 nm) spectral line. The very high spatial resolution of the data (diffraction limit of 77 km and pixel scale of 0.''0375) augmented by the very high image contrast (15.5% {+-} 0.6%) allowed us to detect for the first time a distinct subpopulation of mini-granular structures. These structures are dominant on spatial scales below 600 km. Their size is distributed as a power law with an index of -1.8 (which is close to the Kolmogorov's -5/3 law) and no predominant scale. The regular granules display a Gaussian (normal) size distribution with a mean diameter of 1050 km. Mini-granular structures contribute significantly to the total granular area. They are predominantly confined to the wide dark lanes between regular granules and often form chains and clusters, but different from magnetic bright points. A multi-fractality test reveals that the structures smaller than 600 km represent a multi-fractal, whereas on larger scales the granulation pattern shows no multi-fractality and can be considered as a Gaussian random field. The origin, properties, and role of the population of mini-granular structures in the solar magnetoconvection are yet to be explored.

Abramenko, V. I.; Yurchyshyn, V. B.; Goode, P. R. [Big Bear Solar Observatory, 40386 N. Shore Lane, Big Bear City, CA 92314 (United States); Kitiashvili, I. N.; Kosovichev, A. G. [W. W. Hansen Experimental Physics Laboratory, Stanford University, Stanford, CA 94305 (United States)

2012-09-10T23:59:59.000Z

171

Performance of Glass Resistive Plate Chambers for a high granularity semi-digital calorimeter  

E-Print Network (OSTI)

A new design of highly granular hadronic calorimeter using Glass Resistive Plate Chambers (GRPCs) with embedded electronics has been proposed for the future International Linear Collider (ILC) experiments. It features a 2-bit threshold semi-digital read-out. Several GRPC prototypes with their electronics have been successfully built and tested in pion beams. The design of these detectors is presented along with the test results on efficiency, pad multiplicity, stability and reproducibility.

Bedjidian, M; Boudry, V; Combaret, C; Decotigny, D; Gil, E Cortina; de la Taille, C; Dellanegra, R; Gapienko, V A; Grenier, G; Jauffret, C; Kieffer, R; Fouz, M -C; Han, R; Laktineh, I; Lumb, N; Manai, K; Mannai, S; Mathez, H; Mirabito, L; Pelayo, J Puerta; Ruan, M; Schirra, F; Seguin-Moreau, N; Tromeur, W; Tytgat, M; Donckt, M Vander; Zaganidis, N

2010-01-01T23:59:59.000Z

172

Advances in Complex Systems c ? World Scientific Publishing Company DENSE GRANULAR MEDIA AS ATHERMAL GLASSES.  

E-Print Network (OSTI)

I briefly describe how mean-field glass models can be extended to the case where the bath and friction are non-thermal. Solving their dynamics one discovers a temperature with a thermodynamic meaning associated with the slow rearrangements, even though there is no thermodynamic temperature at level of fast dynamics. This temperature can be shown to match the one defined on the basis of a flat measure over blocked (jammed) configurations. Numerical checks on realistic systems suggest that these features may be valid in general. 1. Glasses and Dense Granular Matter An ensemble of many elastic particles of irregular shapes at low temperatures and high densities forms a glass that is, an out of equilibrium system having a relaxation timescale that grows as the system ages. Granular matter would be just an example of this, albeit a rather special one, in that the thermal kinetic energy ? kBT per particle is negligible and that the gravity field plays an unusually important role. What in fact distinguishes granular matter from a glass at zero temperature and very high pressure is the non-thermal manner in which energy is

Jorge Kurchan

2001-01-01T23:59:59.000Z

173

Direct Biohydrometallurgical Extraction of Iron from Ore  

Science Conference Proceedings (OSTI)

A completely novel approach to iron extraction was investigated, based on reductive leaching of iron by anaerobic bacteria. Microorganisms were collected from an anaerobic bog where natural seepage of dissolved iron was observed. This mixed culture was used to reduce insoluble iron in a magnetite ore to the soluble ferrous (Fe{sup +2}) state. While dissolution rates were slow, concentrations of dissolved iron as high as 3487 mg/l could be reached if sufficient time was allowed. A factorial study of the effects of trace nutrients and different forms of organic matter indicated that the best dissolution rates and highest dissolved iron concentrations were achieved using soluble carbohydrate (sucrose) as the bacterial food source, and that nutrients other than nitrogen, phosphorus, potassium, sodium, and acetate were not necessary. A key factor in reaching high levels of dissolved iron was maintaining a high level of carbon dioxide in solution, since the solubility of iron carbonates increases markedly as the quantity of dissolved carbon dioxide increases. Once the iron is dissolved, it has been demonstrated that the ferrous iron can then be electroplated from solution, provided that the concentration of iron is sufficiently high and the hydrogen ion concentration is sufficiently low. However, if the leaching solution is electrolyzed directly, organic matter precipitates at the cathode along with the metallic iron. To prevent this problem, the ferrous iron should be separated from the bulk solution in a more concentrated, purified form. One route to accomplishing this is to take advantage of the change in solubility of ferrous iron as a function of carbon dioxide concentration. By cycling the concentration of carbon dioxide in solution, it is possible to produce an iron-rich concentrate that should be suitable for electrolysis. This represents the first viable hydrometallurgical method for leaching iron directly from ore and producing metallic iron.

T.C. Eisele

2005-10-01T23:59:59.000Z

174

Microsoft Word - IronCore  

NLE Websites -- All DOE Office Websites (Extended Search)

November/December 2013 November/December 2013 Percolation Explains How Earth's Iron Core Formed The formation of Earth's metallic core, which makes up a third of our planet's mass, represents the most significant differentiation event in Earth's history. Earth's present layered structure with a metallic core and an overlying silicate mantle would have required mechanisms to separate iron alloy from a silicate phase. Percolation of liquid iron alloy moving through a solid silicate matrix (much as water percolates through porous rock, or even coffee grinds) has been proposed as a possible model for core formation (Figure 1). Many previous experimental results have ruled out percolation as a major core formation mechanism for Earth at the relatively lower pressure conditions in the upper mantle, but

175

Effects of Iron and Manganese Ions on Potentiostatic Current ...  

Science Conference Proceedings (OSTI)

Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit Direct Precipitation of ... High Temperature Exposure of Oil Well Cements.

176

About The Associate for Iron and Steel Technology - TMS  

Science Conference Proceedings (OSTI)

ABOUT THE ASSOCIATION FOR IRON & STEEL TECHNOLOGY ... that provides opportunities for networking among iron and steel industry professionals and...

177

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Iron Availability in the Southern Ocean Print Friday, 21 June 2013 10:08 The Southern Ocean, circling the Earth between Antarctica and the...

178

Classes and Grades of Ductile Iron  

Science Conference Proceedings (OSTI)

Table 1   Ductile iron properties of various industry and international standards...Table 1 Ductile iron properties of various industry and international standards Grade Tensile strength 0.2% offset yield

179

Magnetism Governs Properties of Iron-Based ...  

Science Conference Proceedings (OSTI)

... a group of materials that conduct electricity without resistance at ... theoretical evidence demonstrating how magnetism controls basic aspects of iron ...

2011-04-06T23:59:59.000Z

180

Lithium Iron Phosphate Composites for Lithium Batteries  

The materials can be added at low cost without changing current scalable cathode ... Lithium Iron Phosphate Composites for Lithium Batteries ...

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Terahertz Properties of Lithium Iron Phosphate Glasses  

Science Conference Proceedings (OSTI)

Presentation Title, Terahertz Properties of Lithium Iron Phosphate Glasses ... Field Assisted Viscous Flow and Crystallization in a Sodium Aluminosilicate Glass.

182

Ligand iron catalysts for selective hydrogenation  

SciTech Connect

Disclosed are iron ligand catalysts for selective hydrogenation of aldehydes, ketones and imines. A catalyst such as dicarbonyl iron hydride hydroxycyclopentadiene) complex uses the OH on the five member ring and hydrogen linked to the iron to facilitate hydrogenation reactions, particularly in the presence of hydrogen gas.

Casey, Charles P. (Madison, WI); Guan, Hairong (Cincinnati, OH)

2010-11-16T23:59:59.000Z

183

Moving granular-bed filter development program, Option III: Development of moving granular-bed filter technology for multi-contaminant control. Task 14: Test plan; Topical report  

Science Conference Proceedings (OSTI)

An experimental test plan has been prepared for DOE/METC review and approval to develop a filter media suitable for multi-contaminant control in granular-bed filter (GBF) applications. The plan includes identification, development, and demonstration of methods for enhanced media morphology, chemical reactivity, and mechanical strength. The test plan includes media preparation methods, physical and chemical characterization methods for fresh and reacted media, media evaluation criteria, details of test and analytical equipment, and test matrix of the proposed media testing. A filter media composed of agglomerated limestone and clay was determined to be the best candidate for multi-contaminate control in GBF operation. The combined limestone/clay agglomerate has the potential to remove sulfur and alkali species, in addition to particulate, and possibly halogens and trace heavy metals from coal process streams.

Haas, J.C.; Olivo, C.A.; Wilson, K.B.

1994-04-01T23:59:59.000Z

184

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydraulic Conductivity of the Monticello Permeable Reactive Barrier Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update Hydraulic Conductivity of the Monticello Permeable Reactive Barrier November 2005 Update More Documents & Publications Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained Pumping at the Monticello, Utah, Zero-Valent Iron Treatment Cells Performance Assessment and Recommendations for Rejuvenation of a Permeable Reactive Barrier: Cotter Corporation's Cañon City, Colorado, Uranium

185

The Jamming point street-lamp in the world of granular media  

E-Print Network (OSTI)

The Jamming of soft spheres at zero temperature, the J-point, has been extensively studied both numerically and theoretically and can now be considered as a safe location in the space of models, where a street lamp has been lit up. However, a recent work by Ikeda et al, 2013 reveals that, in the Temperature/Packing fraction parameter space, experiments on colloids are actually rather far away from the scaling regime illuminated by this lamp. Is it that the J-point has little to say about real system? What about granular media? Such a-thermal, frictional, systems are a-priori even further away from the idealized case of thermal soft spheres. In the past ten years, we have systematically investigated horizontally shaken grains in the vicinity of the Jamming transition. We discuss the above issue in the light of very recent experimental results. First, we demonstrate that the contact network exhibits a remarkable dynamics, with strong heterogeneities, which are maximum at a packing fraction phi star, distinct and smaller than the packing fraction phi dagger, where the average number of contact per particle starts to increase. The two cross-overs converge at point J in the zero mechanical excitation limit. Second, a careful analysis of the dynamics on time scales ranging from a minute fraction of the vibration cycle to several thousands of cycles allows us to map the behaviors of this shaken granular system onto those observed for thermal soft spheres and demonstrate that some light of the J-point street-lamp indeed reaches the granular universe.

Corentin Coulais; Robert P. Behringer; Olivier Dauchot

2013-05-03T23:59:59.000Z

186

Continuous production of granular or powder Ti, Zr and Hf or their alloy products  

DOE Patents (OSTI)

A continuous process for producing a granular metal selected from the group consisting of Ti, Zr or Hf under conditions that provide orderly growth of the metal free of halide inclusions comprising: a) dissolving a reducing metal selected from the group consisting of Na, Mg, Li or K in their respective halide salts to produce a reducing molten salt stream; b) preparing a second molten salt stream containing the halide salt of Ti, Zr or Hf; c) mixing and reacting the two molten streams of steps a) and b) in a continuous stirred tank reactor; d) wherein steps a) through c) are conducted at a temperature range of from about 800.degree. C. to about 1100.degree. C. so that a weight percent of equilibrium solubility of the reducing metal in its respective halide salt varies from about 1.6 weight percent at about 900.degree. C. to about 14.4 weight percent at about 1062.degree. C.; and wherein a range of concentration of the halide salt of Ti, Zn or Hf in molten halides of Na, Mg, Li or K is from about 1 to about 5 times the concentration of Na, Mg, Li or K; e) placing the reacted molten stream from step c) in a solid-liquid separator to recover an impure granular metal product by decantation, centrifugation, or filtration; and f) removing residual halide salt impurity by vacuum evaporator or inert gas sweep at temperatures from about 850.degree. C. to 1000.degree. C. or cooling the impure granular metal product to ambient temperature and water leaching off the residual metal halide salt.

White, Jack C. (Albany, OR); Oden, Laurance L. (Albany, OR)

1993-01-01T23:59:59.000Z

187

Non-local rheological properties of granular flows near a jamming limit.  

Science Conference Proceedings (OSTI)

We study the rheology of sheared granular flows close to a jamming transition. We use the approach of partially fluidized theory (PFT) with a full set of equations extending the thin layer approximation derived previously for the description of the granular avalanches phenomenology. This theory provides a picture compatible with a local rheology at large shear rates [G. D. R. Midi, Eur. Phys. J. E 14, 341 (2004)] and it works in the vicinity of the jamming transition, where a description in terms of a simple local rheology comes short. We investigate two situations displaying important deviations from local rheology. The first one is based on a set of numerical simulations of sheared soft two-dimensional circular grains. The next case describes previous experimental results obtained on avalanches of sandy material flowing down an incline. Both cases display, close to jamming, significant deviations from the now standard Pouliquen's flow rule [O. Pouliquen, Phys. Fluids 11, 542 (1999); 11, 1956 (1999)]. This discrepancy is the hallmark of a strongly nonlocal rheology and in both cases, we relate the empirical results and the outcomes of PFT. The numerical simulations show a characteristic constitutive structure for the fluid part of the stress involving the confining pressure and the material stiffness that appear in the form of an additional dimensionless parameter. This constitutive relation is then used to describe the case of sandy flows. We show a quantitative agreement as far as the effective flow rules are concerned. A fundamental feature is identified in PFT as the existence of a jammed layer developing in the vicinity of the flow arrest that corroborates the experimental findings. Finally, we study the case of solitary erosive granular avalanches and relate the outcome with the PFT analysis.

Aranson, I. S.; Tsimring, L. S.; Malloggi, F.; Clement, E.; Materials Science Division; Univ. of California at San Diego; CNRS-ESPCI Univ.

2008-01-01T23:59:59.000Z

188

Physical test of a particle simulation model in a sheared granular system  

SciTech Connect

We report a detailed comparison of a slow gravity driven sheared granular flow with a computational model performed with the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS). To our knowledge, this is the first thorough test of the LAMMPS model with a laboratory granular flow. In the experiments, grains flow inside a silo with a rectangular cross-section, and are sheared by a rough boundary on one side and smooth boundaries on the other sides. Individual grain position and motion are measured using a particle index matching imaging technique where a fluorescent dye is added to the interstitial liquid which has the same refractive index as the glass beads. The boundary imposes a packing order, and the grains are observed to flow in layers which get progressively more disordered with distance from the walls. The computations use a Cundall--Strack contact model between the grains, using contact parameters that have been used in many other previous studies, and ignore the hydrodynamic effects of the interstitial liquid. Computations are performed to understand the effect of particle coefficient of friction, elasticity, contact model, and polydispersity on mean flow properties. After appropriate scaling, we find that the mean velocity of the grains and the number density as a function of flow cross-section observed in the experiments and the simulations are in excellent agreement. The mean flow profile is observed to be unchanged over a broad range of coefficient of friction, except near the smooth wall. We show that the flow profile is not sensitive to atleast 10\\percent polydispersity in particle size. Because the grain elasticity used is smaller in the computations as compared with glass grains, wave-like features can be noted over short time scales in the mean velocity and the velocity auto-correlations measured in the simulations. These wave features occur over an intermediate timescale larger than the particle interaction but smaller than the timescale of the macroscopic flow features. The wave features become more prominent as grain elasticity is further reduced. We then perform a detailed comparison of the particle fluctuation properties as measured by the displacement probability distribution function and the mean square displacement. Excellent agreement is observed over a time interval over which particles can be tracked effectively in the experiments. Using the longer tracking intervals possible in the simulations, we find that the diffusion inthe layers is greater in the flow direction, than in the perpendicular direction. Further signatures of confinement and hopping between layers is observed. All in all, our study provides strong support for the LAMMPS model of granular flow, and further supports the hypothesis that the interstitial liquid has negligible effects on granular fluctuations provided the flow is slow.

Rycroft, Chris; Orpe, Ashish; Kudrolli, Arshad

2009-01-15T23:59:59.000Z

189

The jamming surface of granular matter determined from soil mechanics results  

E-Print Network (OSTI)

Classical soil mechanics results are used to propose the equation of the jamming transition surface in the (stress, specific volume) space. Taking axis-ymmetric conditions, labelling q the deviatoric stress and p' the mean pressure applied on the granular skeleton, and considering normal range of pressure (10 kPa-10MPa) the equation of the surface of jamming transition is v = vo-m ln(p'/p'o)+ md ln(1+q q/(M' M' p' p')); M' is related to the friction angle, m and md are two constants which depend on soil characteristics; p'o is a "unit" pressure.

P. Evesque

2005-06-17T23:59:59.000Z

190

-Interface effects on the magnetic moment of Co and Cu in CoCu granular alloys  

SciTech Connect

We report on x-ray magnetic circular dichroism experiments performed on Co{sub 5}Cu{sub 95} annealed granular alloys with giant magnetoresistance. Results on the Co-L{sub 2,3} edge evidence a direct correlation between the Co orbital and spin magnetic moment and the Co clusters interfacial roughness. On the other hand, we have found dichroism on the Cu-L{sub 2,3} edge, revealing an induced magnetic polarization of the Cu interfacial atoms. The magnetic moment of the Cu atoms is mainly of spin character and is ferromagnetically coupled with the Co magnetic moment.

Garcia Prieto, A.; Fdez-Gubieda, M.L.; Chaboy, J.; Laguna-Marco, M.A.; Muro, T.; Nakamura, T. [Departamento de Electricidad y Electronica, Universidad del Pais Vasco (UPV/EHU), Apartado 644, 48080 Bilbao (Spain); Instituto de Ciencia de Materiales de Aragon, CSIC-Universidad de Zaragoza, 50009 Zaragoza (Spain); CITIMAC, Universidad de Cantabria, Avenida de los Castros s/n, 39005 Santander (Spain); Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Mikazuki, Sayo, Hyogo 679-5148 (Japan)

2005-12-01T23:59:59.000Z

191

Edwards' measures: a thermodynamic construction for dense granular media and glasses  

E-Print Network (OSTI)

We present numerical support for the hypothesis that macroscopic observables of dense granular media can be evaluated from averages over typical blocked configurations: we construct the corresponding measure for a class of finite-dimensional systems and compare its predictions for various observables with the outcome of the out of equilibrium dynamics at large times. We discuss in detail the connection with the effective temperatures that appear in out of equilibrium glass theories, as well as the relation between our computation and those based on `inherent structure' arguments. A short version of this work has appeared in Phys. Rev. Lett. 85, 5034 (2000) (cond-mat/0006140).

Alain Barrat; Jorge Kurchan; Vittorio Loreto; Mauro Sellitto

2000-11-29T23:59:59.000Z

192

Influence of intergranular exchange coupling on the magnetization dynamics of CoCrPt:SiO{sub 2} granular media  

Science Conference Proceedings (OSTI)

We investigate the effect of Co{sup +} irradiation on the magnetization dynamics of CoCrPt:SiO{sub 2} granular media. Increasing irradiation levels reduce the saturation magnetization and effective anisotropy, which decrease the intrinsic magnetization precession frequency. Furthermore, increasing intergranular exchange coupling results in a qualitative change in the behavior of the magnetic material from a collection of individual grains to a homogeneous thin film, as evidenced in both the switching behavior and dynamics. The frequency change cannot be explained by single crystal macrospin modeling, and can only be reproduced by the inclusion of the dipolar effects and anisotropy distribution inherent in a granular medium.

Brandt, R.; Schmidt, H. [School of Engineering, University of California-Santa Cruz, 1156 High Street, Santa Cruz, California 95064 (United States); Tibus, S. [Department of Physics, University of Konstanz, D-78457 Konstanz (Germany); Institute of Physics, Chemnitz University of Technology, Reichenhainer Str. 70, 09126 Chemnitz (Germany); Springer, F. [Department of Physics, University of Konstanz, D-78457 Konstanz (Germany); Fassbender, J. [Institute of Ion Beam Physics and Materials Research, Forschungszentrum Dresden-Rossendorf, D-01314 Dresden (Germany); Rohrmann, H. [OC Oerlikon Balzers AG, LI-9496 Balzers (Liechtenstein); Albrecht, M. [Institute of Physics, Chemnitz University of Technology, Reichenhainer Str. 70, 09126 Chemnitz (Germany)

2012-08-01T23:59:59.000Z

193

Cratering Experiments on the Self Armoring of Coarse-Grained Granular Targets  

E-Print Network (OSTI)

Recently published crater statistics on the small asteroids 25143 Itokawa and 433 Eros show a significant depletion of craters below approx. 100 m in diameter. Possible mechanisms that were brought up to explain this lack of craters were seismic crater erasure and self armoring of a coarse, boulder covered asteroid surface. While seismic shaking has been studied in this context, the concept of armoring lacks a deeper inspection and an experimental ground truth. We therefore present cratering experiments of glass bead projectiles impacting into granular glass bead targets, where the grain sizes of projectile and target are in a similar range. The impact velocities are in the range of 200 to 300 m/s. We find that craters become fainter and irregular shaped as soon as the target grains are larger than the projectile sizes and that granular craters rarely form when the size ratio between projectile and target grain is around 1:10 or smaller. In that case, we observe a formation of a strength determined crater in ...

Gttler, Carsten; Nakamura, Akiko M

2012-01-01T23:59:59.000Z

194

Local Equation of State and Velocity Distributions of a Driven Granular Gas  

E-Print Network (OSTI)

We present event-driven simulations of a granular gas of inelastic hard disks with incomplete normal restitution in two dimensions between vibrating walls (without gravity). We measure hydrodynamic quantities such as the stress tensor, density and temperature profiles, as well as velocity distributions. Relating the local pressure to the local temperature and local density, we construct a local constitutive equation. For strong inelasticities the local constitutive relation depends on global system parameters, like the volume fraction and the aspect ratio. For moderate inelasticities the constitutive relation is approximately independent of the system parameters and can hence be regarded as a local equation of state, even though the system is highly inhomogeneous with heterogeneous temperature and density profiles arising as a consequence of the energy injection. Concerning the local velocity distributions we find that they do not scale with the square root of the local granular temperature. Moreover the high-velocity tails are different for the distribution of the x- and the y-component of the velocity, and even depend on the position in the sample, the global volume fraction, and the coefficient of restitution.

Olaf Herbst; Peter Mller; Matthias Otto; Annette Zippelius

2004-02-04T23:59:59.000Z

195

Analysis of Granular Flow in a Pebble-Bed Nuclear Reactor  

E-Print Network (OSTI)

Pebble-bed nuclear reactor technology, which is currently being revived around the world, raises fundamental questions about dense granular flow in silos. A typical reactor core is composed of graphite fuel pebbles, which drain very slowly in a continuous refueling process. Pebble flow is poorly understood and not easily accessible to experiments, and yet it has a major impact on reactor physics. To address this problem, we perform full-scale, discrete-element simulations in realistic geometries, with up to 440,000 frictional, viscoelastic 6cm-diameter spheres draining in a cylindrical vessel of diameter 3.5m and height 10m with bottom funnels angled at 30 degrees or 60 degrees. We also simulate a bidisperse core with a dynamic central column of smaller graphite moderator pebbles and show that little mixing occurs down to a 1:2 diameter ratio. We analyze the mean velocity, diffusion and mixing, local ordering and porosity (from Voronoi volumes), the residence-time distribution, and the effects of wall friction and discuss implications for reactor design and the basic physics of granular flow.

Chris H. Rycroft; Gary S. Grest; James W. Landry; Martin Z. Bazant

2006-02-16T23:59:59.000Z

196

Retrieving Biomedical Images through Content-Based Learning from Examples Using Fine Granularity  

SciTech Connect

Traditional content-based image retrieval methods based on learning from examples analyze and attempt to understand high-level semantics of an image as a whole. They typically apply certain case-based reasoning technique to interpret and retrieve images through measuring the semantic similarity or relatedness between example images and search candidate images. The drawback of such a traditional content-based image retrieval paradigm is that the summation of imagery contents in an image tends to lead to tremendous variation from image to image. Hence, semantically related images may only exhibit a small pocket of common elements, if at all. Such variability in image visual composition poses great challenges to content-based image retrieval methods that operate at the granularity of entire images. In this study, we explore a new content-based image retrieval algorithm that mines visual patterns of finer granularities inside a whole image to identify visual instances which can more reliably and generically represent a given search concept. We performed preliminary experiments to validate our new idea for content-based image retrieval and obtained very encouraging results.

Xu, Songhua [ORNL; Jiang, Hao [University of Hong Kong, The; Lau, Francis [University of Hong Kong, The

2012-01-01T23:59:59.000Z

197

Analysis of granular flow in a pebble-bed nuclear reactor  

Science Conference Proceedings (OSTI)

Pebble-bed nuclear reactor technology, which is currently being revived around the world, raises fundamental questions about dense granular flow in silos. A typical reactor core is composed of graphite fuel pebbles, which drain very slowly in a continuous refueling process. Pebble flow is poorly understood and not easily accessible to experiments, and yet it has a ma jor impact on reactor physics. To address this problem, we perform full-scale, discrete-element simulations in realistic geometries, with up to 440,000 frictional, viscoelastic 6cm-diameter spheres draining in a cylindrical vessel of diameter 3.5m and height 10m with bottom funnels angled at 30? or 60? . We also simulate a bidisperse core with a dynamic central column of smaller graphite moderator pebbles and show that little mixing occurs down to a 1:2 diameter ratio. We analyze the mean velocity, diffusion and mixing, local ordering and porosity (from Voronoi volumes), the residence-time distribution, and the effects of wall friction and discuss implications for reactor design and the basic physics of granular flow.

C. H. Rycroft; Gary S. Grest; James W. Landry; Martin Z. Bazant

2006-04-17T23:59:59.000Z

198

Water Quality Criteria Development for Iron  

Science Conference Proceedings (OSTI)

The current national water quality criterion for iron a criterion continuous concentration of 1 mg Fe/L was derived 25 years ago. Such ambient water quality criteria are typically derived from toxicity tests in which the reagent grade chemical is dissolved in clean laboratory water. However, due to the complexity of iron speciation in freshwater, adverse effects of iron precipitates on habitat quality, and access of organisms to food, standard toxicity assays may not adequately assess the...

2004-12-27T23:59:59.000Z

199

Lithium Insertion Chemistry of Some Iron Vanadates  

E-Print Network (OSTI)

in A. Nazri, G.Pistoia (Eds. ), Lithium batteries, Science &structure materials in lithium cells, for a lower limitLithium Insertion Chemistry of Some Iron Vanadates Sbastien

Patoux, Sebastien; Richardson, Thomas J.

2008-01-01T23:59:59.000Z

200

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is...

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Crystal Structure of Iron-dependent Halogenase  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron (brown) is coordinated by two histidines, a-ketoglutarate (grey sticks), water (cyan), and chloride (green). The structural analysis revealed a novel coordination...

202

Iron Control in Zinc Pressure Leach Processes  

Science Conference Proceedings (OSTI)

Consequently, the disposal of iron residues is an integral part of the design and operation of zinc refineries. Zinc has been recovered from sulfide concentrates...

203

Method for producing iron-based catalysts  

DOE Patents (OSTI)

A method for preparing an acid catalyst having a long shelf-life is provided comprising doping crystalline iron oxides with lattice-compatible metals and heating the now-doped oxide with halogen compounds at elevated temperatures. The invention also provides for a catalyst comprising an iron oxide particle having a predetermined lattice structure, one or more metal dopants for said iron oxide, said dopants having an ionic radius compatible with said lattice structure; and a halogen bound with the iron and the metal dopants on the surface of the particle.

Farcasiu, Malvina (Pittsburgh, PA); Kaufman, Phillip B. (Library, PA); Diehl, J. Rodney (Pittsburgh, PA); Kathrein, Hendrik (McMurray, PA)

1999-01-01T23:59:59.000Z

204

Cycling Degradation of Lithium Iron Phosphate Cells  

Science Conference Proceedings (OSTI)

Abstract Scope, Significant improvement of electronic conductivity of lithium iron ... commercialization in many applications especially in plug-in electric vehicles.

205

Carbon Emissions: Iron and Steel Industry  

U.S. Energy Information Administration (EIA)

Energy-Related Carbon Emissions for Selected Iron and Steel Industries, 1994. Besides steel mills and blast furnaces, the primary metals industry also ...

206

Supporting Material for: Capillary-like Fluctuations of a Solid-Liquid Interface in a Non-Cohesive Granular System  

E-Print Network (OSTI)

In this supplementary paper we present some details on the solid-liquid interface detection, the deduction of the non-equilibrium free energy, the analysis of the granular temperature and energy per mode, a validation of the small slope approximation, a description of the Langevin dynamics, and the error analysis.

Li-Hua Luu; Gustavo Castillo; Nicols Mujica; Rodrigo Soto

2013-04-09T23:59:59.000Z

207

Iron mobilization in North African dust.  

SciTech Connect

Iron is an essential nutrient for phytoplankton. Although iron-containing dust mobilized from arid regions supplies the majority of the iron to the oceans, the key flux in terms of the biogeochemical response to atmospheric deposition is the amount of soluble or bioavailable iron. Atmospheric processing of mineral aerosols by anthropogenic pollutants (e.g. sulfuric acid) may transform insoluble iron into soluble forms. Previous studies have suggested higher iron solubility in smaller particles, as they are subject to more thorough atmospheric processing due to a longer residence time than coarse particles. On the other hand, the specific mineralogy of iron in dust may also influence the particulate iron solubility in size. Compared to mineral dust aerosols, iron from combustion sources could be more soluble, and found more frequently in smaller particles. Internal mixing of alkaline dust with iron-containing minerals could significantly reduce iron dissolution in large dust aerosols due to the buffering effect, which may, in contrast, yield higher solubility in smaller particles externally mixed with alkaline dust (Ito and Feng, 2010). Here, we extend the modeling study of Ito and Feng (2010) to investigate atmospheric processing of mineral aerosols from African dust. In contrast to Asian dust, we used a slower dissolution rate for African dust in the fine mode. We compare simulated fractional iron solubility with observations. The inclusion of alkaline compounds in aqueous chemistry substantially limits the iron dissolution during long-range transport to the Atlantic Ocean: only a small fraction of iron (<0.2%) dissolves from illite in coarsemode dust aerosols with 0.45% soluble iron initially. In contrast, a significant fraction (1-1.5%) dissolves in fine-mode dust aerosols due to the acid mobilization of the iron-containing minerals externally mixed with carbonate minerals. Consequently, the model generally reproduces higher iron solubility in smaller particles as suggested by measurements over the Atlantic Ocean. Our results imply that the dissolution of iron in African dust is generally slower than that in Asian dust. Conventionally, dust is assumed as the major supply of bioavailable iron with a constant solubility at 1-2% to the remote ocean. Therefore, the timing and location of the atmospheric iron input to the ocean with detailed modeling of atmospheric processing could be different from those previously assumed. Past and future changes in aerosol supply of bioavailable iron might play a greater role in the nutrient supply for phytoplankton production in the upper ocean, as global warming has been predicted to intensify stratification and reduce vertical mixing from the deep ocean. Thus the feedback of climate change through ocean uptake of carbon dioxide as well as via aerosol-cloud interaction might be modified by the inclusion of iron chemistry in the atmosphere.

Ito, A.; Feng, Y. (Environmental Science Division); (Research Inst. for Global Change)

2011-01-01T23:59:59.000Z

208

Possible Processing of High Phosphorous Libyan Iron Ores  

Science Conference Proceedings (OSTI)

Abstract Scope, Libyan Iron ores reserve > 5.0 billion tons, with 48-55% Fe& 1.0 % P& Libyan Previous ... Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit ... High Temperature Exposure of Oil Well Cements.

209

Shape effects of iron nanowires on hyperthermia treatment  

Science Conference Proceedings (OSTI)

This research discusses the influence ofmorphology of nanomagneticmaterials (one-dimensional iron nanowires and zero-dimensional iron nanoparticles) on heating efficiency of the hyperthermia treatment. One-dimensional iron nanowires, synthesized by reducing ...

Wei-Syuan Lin, Hong-Ming Lin, Hsiang-Hsin Chen, Yeu-Kuang Hwu, Yuh-Jing Chiou

2013-01-01T23:59:59.000Z

210

Fundamental Research on the Characteristics of Sierra Leone Iron ...  

Science Conference Proceedings (OSTI)

Differential Characterization of Ikperejere Iron shale and Iron Sandstone Deposit Direct Precipitation of Sr-doped LaP3O9 Thin Film Electrolytes for...

211

Reconstruction of Gene Networks of Iron Response in Shewanella oneidensis  

Science Conference Proceedings (OSTI)

It is of great interest to study the iron response of the -proteobacterium Shewanella oneidensis since it possesses a high content of iron and is capable of utilizing iron for anaerobic respiration. We report here that the iron response in S. oneidensis is a rapid process. To gain more insights into the bacterial response to iron, temporal gene expression profiles were examined for iron depletion and repletion, resulting in identification of iron-responsive biological pathways in a gene co-expression network. Iron acquisition systems, including genes unique to S. oneidensis, were rapidly and strongly induced by iron depletion, and repressed by iron repletion. Some were required for iron depletion, as exemplified by the mutational analysis of the putative siderophore biosynthesis protein SO3032. Unexpectedly, a number of genes related to anaerobic energy metabolism were repressed by iron depletion and induced by repletion, which might be due to the iron storage potential of their protein products. Other iron-responsive biological pathways include protein degradation, aerobic energy metabolism and protein synthesis. Furthermore, sequence motifs enriched in gene clusters as well as their corresponding DNA-binding proteins (Fur, CRP and RpoH) were identified, resulting in a regulatory network of iron response in S. oneidensis. Together, this work provides an overview of iron response and reveals novel features in S. oneidensis, including Shewanella-specific iron acquisition systems, and suggests the intimate relationship between anaerobic energy metabolism and iron response.

Yang, Yunfeng [ORNL; Harris, Daniel P [ORNL; Luo, Feng [Clemson University; Joachimiak, Marcin [Clemson University; Wu, Liyou [University of Oklahoma; Dehal, Paramvir [Lawrence Berkeley National Laboratory (LBNL); Jacobsen, Janet [Lawrence Berkeley National Laboratory (LBNL); Yang, Zamin Koo [ORNL; Gao, Haichun [University of Oklahoma; Arkin, Adam [Lawrence Berkeley National Laboratory (LBNL); Palumbo, Anthony Vito [ORNL; Zhou, Jizhong [University of Oklahoma

2009-01-01T23:59:59.000Z

212

Processing, Microstructure and Properties of Cast Irons and Cast ...  

Science Conference Proceedings (OSTI)

... Process Design of the Ductile Cast Iron Cylinder Head for Marine Diesel Engine ... Heavy Section Ductile Iron Castings for Use in Wind Turbine Generators.

213

FischerTropsch Synthesis: Characterization Rb Promoted Iron ...  

Science Conference Proceedings (OSTI)

Nov 1, 2007 ... Abstract Rubidium promoted iron FischerTropsch synthesis (FTS) ... Keywords FischerTropsch synthesis Iron catalyst . Rubidium Active...

214

Arsenic Remediation of Bangladesh Drinking Water using Iron-oxide...  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic Remediation of Bangladesh Drinking Water using Iron-oxide Coated Coal Ash Title Arsenic Remediation of Bangladesh Drinking Water using Iron-oxide Coated Coal Ash...

215

Pages that link to "Iron Edison Battery Company" | Open Energy...  

Open Energy Info (EERE)

Share this page on Facebook icon Twitter icon Pages that link to "Iron Edison Battery Company" Iron Edison Battery Company Jump to: navigation, search What links here...

216

Changes related to "Iron Edison Battery Company" | Open Energy...  

Open Energy Info (EERE)

Share this page on Facebook icon Twitter icon Changes related to "Iron Edison Battery Company" Iron Edison Battery Company Jump to: navigation, search This is a list...

217

Iron catalysis in oxidation by ozone - Energy Innovation Portal  

Bookmark Iron catalysis in oxidation by ozone - Energy Innovation Portal on Google; Bookmark Iron catalysis in oxidation by ozone - Energy Innovation ...

218

Climate VISION: Private Sector Initiatives: Iron and Steel: Resources...  

Office of Scientific and Technical Information (OSTI)

Industry Associations American Iron and Steel Institute For over a century, North American steel producers have worked as partners and members of the American Iron and Steel...

219

Preparations of rare earth-iron alloys by thermite reduction  

DOE Patents (OSTI)

An improved method for the preparation of high-purity rare earth-iron alloys by the aluminothermic reduction of a mixture of rare earth and iron fluorides.

Schmidt, Frederick A. (Ames, IA); Peterson, David T. (Ames, IA); Wheelock, John T. (Nevada, IA)

1986-09-16T23:59:59.000Z

220

Diffusivity and Weak Clustering in a Quasi 2D Granular Gas  

E-Print Network (OSTI)

We present results from a detailed simulation of a quasi-2D dissipative granular gas, kept in a non-condensed steady state via vertical shaking over a rough substrate. This gas shows a weak power-law decay in the tails of its Pair Distribution Functions (PDF's), indicating fractality and therefore a tendency to form clusters over several size scales. This clustering depends monotonically on the dissipation coefficient, and disappears when the sphere-sphere collisions are conservative. Clustering is also sensitive to the packing fraction. This gas also displays the standard nonequilibrium characteristics of similar systems, including non-Maxwellian velocity distributions. The diffusion coefficients are calculated over all the conditions of the simulations, and it is found that diluted gases are more diffusive for smaller restitution coefficients.

J. A. Perera-Burgos; G. Perez-Angel; Y. Nahmad-Molinari

2010-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

In situ bioremediation: A network model of diffusion and flow in granular porous media  

SciTech Connect

In situ bioremediation is a potentially expedient, permanent and cost- effective means of waste site decontamination. However, permeability reductions due to the transport and deposition of native fines or due to excessive microorganism populations may severely inhibit the injection of supplemental oxygen in the contamination zone. To help understand this phenomenon, we have developed a micro-mechanical network model of flow, diffusion and particle transport in granular porous materials. The model differs from most similar models in that the network is defined by particle positions in a numerically-generated particle array. The model is thus widely applicable to computing effective transport properties for both ordered and realistic random porous media. A laboratory-scale apparatus to measure permeability reductions has also been designed, built and tested.

Griffiths, S.K.; Nilson, R.H.; Bradshaw, R.W.

1997-04-01T23:59:59.000Z

222

Fluid effects on seismic waves in hard rocks with fractures and in soft granular media  

SciTech Connect

When fractures in otherwise hard rocks are filled with fluids (oil, gas, water, CO{sub 2}), the type and physical state of the fluid (liquid or gas) can make a large difference in the wave speeds and attenuation properties of seismic waves. The present work summarizes methods of deconstructing theses effects of fractures, together with any fluids contained within them, on wave propagation as observed in reflection seismic data. Additional studies of waves in fluid-saturated granular media show that the behavior can be quite different from that for fractured media, since these materials are typically much softer mechanically than are the fractured rocks (i.e., having a very small drained moduli). Important fluid effects in such media are often governed as much by fluid viscosity as by fluid bulk modulus.

Berryman, James G.

2009-03-01T23:59:59.000Z

223

Competition of Brazil nut effect, buoyancy, and inelasticity induced segregation in a granular mixture  

E-Print Network (OSTI)

It has been recently reported that a granular mixture in which grains differ in their restitution coefficients presents segregation: the more inelastic particles sink to the bottom. When other segregation mechanisms as buoyancy and the Brazil nut effect are present, the inelasticity induced segregation can compete with them. First, a detailed analysis, based on numerical simulations of two dimensional systems, of the competition between buoyancy and the inelasticity induced segregation is presented, finding that there is a transition line in the parameter space that determines which mechanism is dominant. In the case of neutrally buoyant particles having different sizes the inelasticity induced segregation can compete with the Brazil nut effect (BNE). Reverse Brazil nut effect (RBNE) could be obtained at large inelasticities of the intruder. At intermediate values, BNE and RBNE coexist and large inelastic particles are found both near the bottom and at the top of the system.

Ricardo Brito; Rodrigo Soto

2010-12-21T23:59:59.000Z

224

Subdiffusive axial transport of granular materials in a long drum mixer  

E-Print Network (OSTI)

Granular mixtures rapidly segregate radially by size when tumbled in a partially filled horizontal drum. The smaller component moves toward the axis of rotation and forms a buried core, which then splits into axial bands. Models have generally assumed that the axial segregation is opposed by diffusion. Using narrow pulses of the smaller component as initial conditions, we have characterized axial transport in the core. We find that the axial advance of the segregated core is well described by a self-similar concentration profile whose width scales as $t^\\alpha$, with $\\alpha \\sim 0.3 < 1/2$. Thus, the process is subdiffusive rather than diffusive as previously assumed. We find that $\\alpha$ is nearly independent of the grain type and drum rotation rate within the smoothly streaming regime. We compare our results to two one-dimensional PDE models which contain self-similarity and subdiffusion; a linear fractional diffusion model and the nonlinear porous medium equation.

Zeina S. Khan; Stephen W. Morris

2004-08-28T23:59:59.000Z

225

Non-Gaussian Resistance Noise near Electrical Breakdown in Granular Materials  

E-Print Network (OSTI)

The distribution of resistance fluctuations of conducting thin films with granular structure near electrical breakdown is studied by numerical simulations. The film is modeled as a resistor network in a steady state determined by the competition between two biased processes, breaking and recovery. Systems of different sizes and with different levels of internal disorder are considered. Sharp deviations from a Gaussian distribution are found near breakdown and the effect increases with the degree of internal disorder. However, we show that in general this non-Gaussianity is related to the finite size of the system and vanishes in the large size limit. Nevertheless, near the critical point of the conductor-insulator transition, deviations from Gaussianity persist when the size is increased and the distribution of resistance fluctuations is well fitted by the universal Bramwell-Holdsworth-Pinton distribution.

C. Pennetta; E. Alfinito; L. Reggiani; S. Ruffo

2004-01-20T23:59:59.000Z

226

Method and apparatus for filtering gas with a moving granular filter bed  

DOE Patents (OSTI)

A method and apparatus for filtering gas (58) with a moving granular filter bed (48) involves moving a mass of particulate filter material (48) downwardly through a filter compartment (35); tangentially introducing gas into the compartment (54) to move in a cyclonic path downwardly around the moving filter material (48); diverting the cyclonic path (58) to a vertical path (62) to cause the gas to directly interface with the particulate filter material (48); thence causing the gas to move upwardly through the filter material (48) through a screened partition (24, 32) into a static upper compartment (22) of a filter compartment for exodus (56) of the gas which has passed through the particulate filter material (48).

Brown, Robert C. (Ames, IA); Wistrom, Corey (Ames, IA); Smeenk, Jerod L. (Ames, IA)

2007-12-18T23:59:59.000Z

227

IRON COATED URANIUM AND ITS PRODUCTION  

DOE Patents (OSTI)

A method of applying a protective coating to a metallic uranium article is given. The method comprises etching the surface of the article with an etchant solution containlng chloride ions, such as a solution of phosphoric acid and hydrochloric acid, cleaning the etched surface, electroplating iron thereon from a ferrous ammonium sulfate electroplating bath, and soldering an aluminum sheath to the resultant iron layer.

Gray, A.G.

1960-03-15T23:59:59.000Z

228

Drinking Water Problems: Iron and Manganese  

E-Print Network (OSTI)

Iron and manganese can give water an unpleasant taste, odor and color. In this publication you'll learn how to know whether your water contains iron or manganese and how to eliminate these contaminants with various treatment methods such as aeration and chemical oxidation.

Dozier, Monty; McFarland, Mark L.

2004-02-20T23:59:59.000Z

229

Production of iron from metallurgical waste  

DOE Patents (OSTI)

A method of recovering metallic iron from iron-bearing metallurgical waste in steelmaking comprising steps of providing an iron-bearing metallurgical waste containing more than 55% by weight FeO and FeO equivalent and a particle size of at least 80% less than 10 mesh, mixing the iron-bearing metallurgical waste with a carbonaceous material to form a reducible mixture where the carbonaceous material is between 80 and 110% of the stoichiometric amount needed to reduce the iron-bearing waste to metallic iron, and as needed additions to provide a silica content between 0.8 and 8% by weight and a ratio of CaO/SiO.sub.2 between 1.4 and 1.8, forming agglomerates of the reducible mixture over a hearth material layer to protect the hearth, heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic iron and slag material from the agglomerates by melting.

Hendrickson, David W; Iwasaki, Iwao

2013-09-17T23:59:59.000Z

230

THE SOLAR FLARE IRON ABUNDANCE  

SciTech Connect

The abundance of iron is measured from emission line complexes at 6.65 keV (Fe line) and 8 keV (Fe/Ni line) in RHESSI X-ray spectra during solar flares. Spectra during long-duration flares with steady declines were selected, with an isothermal assumption and improved data analysis methods over previous work. Two spectral fitting models give comparable results, viz., an iron abundance that is lower than previous coronal values but higher than photospheric values. In the preferred method, the estimated Fe abundance is A(Fe) = 7.91 {+-} 0.10 (on a logarithmic scale, with A(H) = 12) or 2.6 {+-} 0.6 times the photospheric Fe abundance. Our estimate is based on a detailed analysis of 1898 spectra taken during 20 flares. No variation from flare to flare is indicated. This argues for a fractionation mechanism similar to quiet-Sun plasma. The new value of A(Fe) has important implications for radiation loss curves, which are estimated.

Phillips, K. J. H. [Mullard Space Science Laboratory, University College London, Holmbury St. Mary, Dorking RH6 5NT (United Kingdom); Dennis, B. R., E-mail: kjhp@mssl.ucl.ac.uk, E-mail: Brian.R.Dennis@nasa.gov [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

2012-03-20T23:59:59.000Z

231

Iron and Steel Energy Intensities  

U.S. Energy Information Administration (EIA) Indexed Site

If you are having trouble, call 202-586-8800 for help. Home > >Energy Users > Energy Efficiency Page > Iron and Steel Energy Intensities First Use of Energy Blue Bullet First Use/Value of Production Blue Bullet First Use/Ton of steel End Uses of Consumption Blue Bullet Total End Use/Value of Production Blue Bullet Total End Use/Ton of Steel Boiler Fuel as End Use Blue Bullet Boiler Fuel /Value of Production Blue Bullet Boiler Fuel /Ton of Steel Process Heating as End Use Blue Bullet Process Heating Fuel /Ton of Steel Blue Bullet Process Heating /Value of Production Machine Drive as End Use Blue Bullet Machine Drive Fuel/Ton of Steel Blue Bullet Machine Drive Fuel /Value of Production Expenditures Blue Bullet Purchased Fuel /Ton of Steel Blue Bullet Purchased Fuel /Value of Production

232

Dechlorination of TCE with palladized iron  

DOE Patents (OSTI)

The present invention relates to various methods, such as an above-ground method and an in-ground method, of using a palladized iron bimetallic system for the dechlorination of chlorinated organic compounds from effluents containing the same. The use of palladized iron bimetallic system results in the dechlorination of the chlorinated organic compound into environmentally safe reaction products. The present invention also provides kits, devices, and other instruments that use the above-mentioned palladized iron bimetallic system for the dechlorination of chlorinated organic compounds. 10 figs.

Fernando, Q.; Muftikian, R.; Korte, N.

1998-06-02T23:59:59.000Z

233

INVESTIGATION OF THE RATE DEPENDENCE OF LONG-ROD PENETRATION OF GRANULAR MEDIA USING AN IMPROVED DSR ALGORITHM  

SciTech Connect

Digital Speckle Radiography (DSR), a technique allowing measurement of the full field displacement maps in a plane within an opaque material, is used to follow the temporal progression of a long-rod (100 mm long, 10 mm diameter) penetrating a granular sample at a variety of rates. Quasi-static rates of 1.5 mm/min are achieved using an Instron machine, 5 m/s is achieved using a drop-weight and velocities between 10 and 200 m/s are achieved using a light gas gun. These experiments are carried out using a series of time delayed flash x-ray images analysed with an optimised Digital Image Cross Correlation algorithm (DICC). The subsequent data sheds considerable light on the response of granular materials to penetration at a variety of rates. Particularly, a large difference in the response of the material between quasi-static and dynamic rates is observed.

Addiss, John W.; Collins, Adam L.; Proud, William G. [Fracture and Shock Physics, SMF Group, Cavendish Laboratory, J. J. Thomson Ave., Cambridge, CB3 OHE (United Kingdom)

2009-12-28T23:59:59.000Z

234

Laser-Doppler acoustic probing of granular media with in-depth property gradient and varying pore pressures  

Science Conference Proceedings (OSTI)

Non-contacting ultrasonic techniques recently proved to be efficient in the physical modeling of seismic-wave propagation at various application scales, as for instance in the context of geological analogue and seismic modeling. An innovative experimental set-up is proposed here to perform laser-Doppler acoustic probing of unconsolidated granular media with varying pore pressures. The preliminary experiments presented here provide reproducible results and exploitable data, thus validating both the proposed medium preparation and pressure gradient generation procedure.

Bodet, L.; Dhemaied, A.; Mourgues, R.; Tournat, V.; Rejiba, F. [LPG, UMR CNRS 6112, Universite du Maine, Le Mans (France); UMR CNRS 7619 Sisyphe, Universite Pierre et Marie Curie-Paris 6 (France); LPG, UMR CNRS 6112, Universite du Maine, Le Mans (France); LAUM, CNRS, Universite du Maine, Le Mans (France); UMR CNRS 7619 Sisyphe, Universite Pierre et Marie Curie-Paris 6 (France)

2012-05-24T23:59:59.000Z

235

Role of material properties and mesostructure on dynamic deformation and shear instability in Al-W granular composites  

E-Print Network (OSTI)

Dynamic experiments with Al-W granular/porous composites revealed qualitatively different behavior with respect to shear localization depending on bonding between Al particles. Two-dimensional numerical modeling was used to explore the mesomechanics of the large strain dynamic deformation in Al-W granular/porous composites and explain the experimentally observed differences in shear localization between composites with various mesostructures. Specifically, the bonding between the Al particles, the porosity, the roles of the relative particle sizes of Al and W, the arrangements of the W particles, and the material properties of Al were investigated using numerical calculations. It was demonstrated in simulations that the bonding between the "soft" Al particles facilitated shear localization as seen in the experiments. Numerical calculations and experiments revealed that the mechanism of the shear localization in granular composites is mainly due to the local high strain flow of "soft" Al around the "rigid" W particles causing localized damage accumulation and subsequent growth of the meso/macro shear bands/cracks. The "rigid" W particles were the major geometrical factor determining the initiation and propagation of "kinked" shear bands in the matrix of "soft" Al particles, leaving some areas free of extensive plastic deformation as observed in experiments and numerical calculations.

K. L. Olney; P. H. Chiu; C. W. Lee; V. F. Nesterenko; D. J. Benson

2011-05-24T23:59:59.000Z

236

Why Sequence Freshwater Iron-Oxidizing Bacteria?  

NLE Websites -- All DOE Office Websites (Extended Search)

Freshwater Iron-Oxidizing Bacteria? Freshwater Iron-Oxidizing Bacteria? The goal of this project is to obtain complete genome sequences for six different freshwater iron (Fe)-oxidizing bacteria (FeOB). Four of these are oxygen-dependent iron-oxidizing β-proteobacteria, and three of these, Sideroxydans lithotrophicus, Gallionella capsiferriformans, and strain TW-2, are capable of chemolithoautotrophic growth (that is, obtaining energy by the oxidation of inorganic compounds) using Fe(II) as sole energy source under microaerobic (low-oxygen) conditions. The fourth organism, Leptothrix cholodnii, is a sheath-forming heterotrophic (i.e., using complex organic compounds for nutrition) organism that oxidizes both Fe(II) and Mn(II) and deposits a ferromanganic coating on its sheath. In addition,

237

Solubility of carbon in nanocrystalline ?-iron  

Science Conference Proceedings (OSTI)

A thermodynamic model for nanocrystalline interstitial alloys is presented. The equilibrium solid solubility of carbon in ?-iron is calculated for given grain size. Inside the strained nanograins local variation of the carbon content is predicted. ...

Alexander Kirchner; Bernd Kieback

2012-01-01T23:59:59.000Z

238

Iron and the ecology of marine microbes  

E-Print Network (OSTI)

Iron is a cofactor of a number biochemical reactions that are essential for life. In the marine environment, this micronutrient is a scarce resource that limits processes of global importance such as photosynthesis and ...

Ventouras, Laure-Anne

2013-01-01T23:59:59.000Z

239

BNL Blood Drives: Iron-rich foods  

NLE Websites -- All DOE Office Websites (Extended Search)

BNL Blood Drives: Iron-Rich Foods Blood Drive Home Seafood: Fish (cod, sardines, tuna, clams, oysters, shrimp) Poultry: Chicken, eggs, yolk Lean Red Meats: Beef, lamb, veal, pork,...

240

C:\Eco-SSLs\Final Guidance November 2003\Contaminant Specific\Iron\Eco-SSL for Iron.wpd  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Iron Interim Final OSWER Directive 9285.7-69 U. S. Environmental Protection Agency Office of Solid Waste and Emergency Response 1200 Pennsylvania Avenue, N.W. Washington, DC 20460 November 2003 This page intentionally left blank TABLE OF CONTENTS SUMMARY OF ECO-SSLs FOR IRON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ES - 1 1.0 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 - 1 2.0 IRON GEOCHEMISTRY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 1 2.1 Weathering Processes Affect on Iron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 3 2.2 Soil Conditions Affect on Iron . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 4 3.0 EFFECTS OF IRON ON PLANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 - 1 3.1 Essentiality . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 - 1 3.2 General Effects

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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to obtain the most current and comprehensive results.


241

Development of Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Iron and Steel Sector  

E-Print Network (OSTI)

scrap, pig iron or direct reduced iron using an electric arcsteel, pig iron or direct reduced iron using an electric arcbuilding materials). Direct reduced iron (DRI) is produced

Xu, T.T.

2011-01-01T23:59:59.000Z

242

Aluminum stimulates uptake of non-transferrin bound iron and transferrin bound iron in human glial cells  

SciTech Connect

Aluminum and other trivalent metals were shown to stimulate uptake of transferrin bound iron and nontransferrin bound iron in erytholeukemia and hepatoma cells. Because of the association between aluminum and Alzheimer's Disease, and findings of higher levels of iron in Alzheimer's disease brains, the effects of aluminum on iron homeostasis were examined in a human glial cell line. Aluminum stimulated dose- and time-dependent uptake of nontransferrin bound iron and iron bound to transferrin. A transporter was likely involved in the uptake of nontransferrin iron because uptake reached saturation, was temperature-dependent, and attenuated by inhibitors of protein synthesis. Interestingly, the effects of aluminum were not blocked by inhibitors of RNA synthesis. Aluminum also decreased the amount of iron bound to ferritin though it did not affect levels of divalent metal transporter 1. These results suggest that aluminum disrupts iron homeostasis in Brain by several mechanisms including the transferrin receptor, a nontransferrin iron transporter, and ferritin.

Kim, Yongbae [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University (United States); Department of Preventive Medicine, Soonchunhyan University, Chunan City (Korea, Republic of) ; Olivi, Luisa [School of Pharmacy, Sahmyook University, Seoul (Korea, Republic of) ; Cheong, Jae Hoon [School of Pharmacy, Sahmyook University, Seoul (Korea, Republic of) ; Maertens, Alex [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University (United States); Bressler, Joseph P. [Department of Environmental Health Sciences, Bloomberg School of Public Health, Johns Hopkins University (United States) and Kennedy-Krieger Institute, Baltimore, MD 21205 (United States)]. E-mail: Bressler@kennedykrieger.org

2007-05-01T23:59:59.000Z

243

Removal of iron from impure graphites  

DOE Green Energy (OSTI)

Iron-impregnated and ash-rich graphites have been purified by leaching with gaseous I/sub 2/ at 900/sup 0/C. With addition of H/sub 2/, the rate of removal of impurity iron can be markedly increased and becomes comparable to that obtained with Cl/sub 2/. I/sub 2/ has an advantage in that it can also volatilize Ca and perhaps Ba and Sr.

Growcock, F.B.; Heiser, J.

1979-01-01T23:59:59.000Z

244

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Print Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch University, Princeton University, and the Advanced Light Source (ALS) suggests that it is not just a lack of iron, but a lack of iron in an easy-to-use form, that is affecting the ecosystems. The researchers sampled two north-south corridors across the Southern Ocean, traveling an easterly transect between the base of the South African National Antarctic Expeditions (SANAE IV) in Queen Maud Land and Cape Town, and a westerly transect between SANAE IV and South Georgia Island. Along the way they collected particles containing solid iron from a series of ocean systems with different characteristics.

245

Iron Availability in the Southern Ocean  

NLE Websites -- All DOE Office Websites (Extended Search)

Iron Availability in the Southern Ocean Print Iron Availability in the Southern Ocean Print The Southern Ocean, circling the Earth between Antarctica and the southernmost regions of Africa, South America, and Australia, is notorious for its high-nutrient, low-chlorophyll areas, which are rich in nutrients-but poor in essential iron. Sea life is less abundant in these regions because the growth of phytoplankton-the marine plants that form the base of the food chain-is suppressed. A study by scientists from South Africa's Stellenbosch University, Princeton University, and the Advanced Light Source (ALS) suggests that it is not just a lack of iron, but a lack of iron in an easy-to-use form, that is affecting the ecosystems. The researchers sampled two north-south corridors across the Southern Ocean, traveling an easterly transect between the base of the South African National Antarctic Expeditions (SANAE IV) in Queen Maud Land and Cape Town, and a westerly transect between SANAE IV and South Georgia Island. Along the way they collected particles containing solid iron from a series of ocean systems with different characteristics.

246

Shock Wave Structure in a Strongly Nonlinear Granular Lattice with Viscous Dissipation  

E-Print Network (OSTI)

The shock wave structure in a one-dimensional lattice (e.g. granular chain) with a power law dependence of force on displacement between particles with viscous dissipation is considered and compared to the corresponding long wave approximation. A dissipative term depending on the relative velocity between neighboring particles is included in the discrete model to investigate its influence on the shape of steady shock profiles. The critical viscosity coefficient is obtained from the long-wave approximation for arbitrary values of the exponent n and denotes the transition from an oscillatory to a monotonic shock profile in stronly nonlinear systems. The expression for the critical viscosity coefficient converges to the known equation for the critical viscosity in the weakly nonlinear case. Values of viscosity based on this expression are comparable to the values obtained in the numerical analysis of a discrete particle lattice with a Herzian contact interaction corresponding to n = 3/2. An initial disturbance in a discrete system approaches a stationary shock profile after traveling a short distance that is comparable to the width of the leading pulse of a stationary shock front. The shock front width is minimized when the viscosity is equal to its critical value.

E. B. Herbold; V. F. Nesterenko

2006-07-07T23:59:59.000Z

247

Effect of granular porous media on the composting of swine manure  

SciTech Connect

This study investigated the feasibility of a bulking agent of granular porous media (GPM) for the composting of swine manure. Two lab-scale composting reactors were operated to evaluate the general performances and maturity parameters using GPM made of wastes from the Portland cement manufacturing processes as an alternative bulking agent. The overall volatile solid (VS) removal was 38.5% (dry basis). During the experiments, moisture content ranged between 41% and 53%, ensuring feasibility of microbial activity in composting. Cured compost showed proper maturity and low phytotoxicity, despite the slight decreases of CO{sub 2} production and VS removal at the second batch operation. Various physico-chemical parameters of the cured compost met the regulatory standards reported elsewhere. The pH, carbon-to-nitrogen ratio, ammonia nitrogen and soluble organic carbon (SOC) of the cured compost were significantly correlated to the germination index (GI) using the seeds of Chinese cabbage and lettuce, indicating the progressive biodegradation of phytotoxins as well as organic matter. Consequently, the results obtained in this study demonstrate that GPM could contribute to the environmentally friendly and economical composting of problematic swine manure as a recyclable bulking agent.

Kim, Ku-Yong; Kim, Hyun-Woo [Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of); Han, Sun-Kee [Department of Environmental Health, Korea National Open University, 169 Dongsung-dong, Jongno-gu, Seoul 110-791 (Korea, Republic of); Hwang, Eung-Ju [Department of Environmental Engineering, Daegu University, Jinryang, Gyeongsan, Gyeongbuk 712-714 (Korea, Republic of); Lee, Chae-Young [Department of Civil Engineering, The University of Suwon, San 2-2, Wau-ri, Bongdam-eup, Hwaseong-si, Gyeonggi-do 445-743 (Korea, Republic of); Shin, Hang-Sik [Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-dong, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)], E-mail: hangshin@kaist.ac.kr

2008-11-15T23:59:59.000Z

248

Dependence of the giant magnetoresistance on the concentration of magnetic particles in granular composites  

Science Conference Proceedings (OSTI)

We study the dependence of giant magnetoresistance (GMR) on the volume concentration of magnetic particles in a magnetic granular composite via a Monte Carlo method and by modeling the composite as a random resistor network. We assume the nanosized magnetic particles are spherical in shape and are randomly distributed in a square or cubic lattice. The uniaxial anisotropy of the particles and the classical dipolar interaction among the particles are taken into account. By considering the difference in electron scatterings for spin-up and spin-down conduction electrons at the magnetic and nonmagnetic interface, and the scatterings within the magnetic regions and the nonmagnetic host medium in the composite, the value of GMR is found to depend sensitively on the spatial distribution of the particles, the magnetic states of the particles, and the densities of the spin polarized conduction electrons. There is an optimum concentration (about 25% in two-dimensional and 30% in three-dimensional cases) of magnetic particles at which the magnetoresistance shows a maximum. This phenomenon was also observed in experiments. {copyright} 2001 American Institute of Physics.

Xu, C.; Hui, P. M.; Li, Z. Y.

2001-07-01T23:59:59.000Z

249

Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Aerobic granular sludge SBR was used to treat real landfill leachate. Black-Right-Pointing-Pointer COD removal was analyzed kinetically using a modified model. Black-Right-Pointing-Pointer Characteristics of nitrogen removal at different ammonium inputs were explored. Black-Right-Pointing-Pointer DO variations were consistent with the GSBR performances at low ammonium inputs. - Abstract: Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L{sup -1}, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L{sup -1}, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L{sup -1}, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.

Wei Yanjie [School of Environmental Science and Engineering, Tianjin University, Tianjin 300072 (China); Key Laboratory of Environmental Protection in Water Transport Engineering Ministry of Communications, Tianjin Research Institute of Water Transport Engineering, Tianjin 300456 (China); Ji Min, E-mail: jmtju@yahoo.cn [School of Environmental Science and Engineering, Tianjin University, Tianjin 300072 (China); Li Ruying [School of Environmental Science and Engineering, Tianjin University, Tianjin 300072 (China); Qin Feifei [Tianjin Tanggu Sino French Water Supply Co. Ltd., Tianjin 300450 (China)

2012-03-15T23:59:59.000Z

250

Distribution of contact forces in a homogeneous granular material of identical spheres under triaxial compression  

E-Print Network (OSTI)

The distribution P(F) of contact forces F in a homogeneous isotropic disordered granular sample subject to uniform triaxial stress field is studied using a model where forces propagate and collide. Collisions occur at grain and obey given rules which allow satisfying local static equilibrium. Analogy with Boltzmann's equation of density evolution is drawn and used to derive the parameters that control the distribution Ps(F) of contact forces F in the stationary state in case of a packing of mono-disperse spheres. Using symmetry argument and mean field approximation, it is found that stationarity is achieved when the density Ps(F) of force can be written as the product of exponentials of quantities whose sums are preserved during collisions. This introduces 3 parameters in 2d and 6 in 3d which are the mean force components {Fxo, Fyo, Fzo}, and the mean torques of the force on a grain {Mxo, Myo, Mzo} >. Astonishingly, it seems that the theory cannot include distribution of contact orientation implicitly. Extension of the model is possible with some care to case of anisotropic packing. Pacs # : 5.40 ; 45.70 ; 62.20 ; 83.70.Fn

P. Evesque

2005-06-23T23:59:59.000Z

251

Master equation for the probability distribution functions of overlaps between particles in two dimensional granular packings  

E-Print Network (OSTI)

How does the force chain network in a random granular material react to hydrostatic compression? We show that not only contacts, but also their opening and closing as well as interparticle gaps, i.e. virtual contacts, must be included for a comprehensive description of the system response involving the probability distribution functions (PDFs) of the extended force network. Considering overlaps/forces as stochastic variables, their conditional probability distributions (CPDs) are (numerically) determined and allow to formulate a Master equation for the PDFs. The insight one gets from the CPDs is striking: The mean change of contacts reflects non-affinity, while their fluctuations obey uncorrelated Gaussian statistics. In contrast, virtual contacts are mostly affine to isotropic (de)compression in average, but show multi-scale correlations with considerable probability of large "jumps" according to a stable distribution (cf. Levy distribution), that allows for a generalized central limit theorem. Noting that all changes of the network during compression are similarly scaled by the distance from the jamming density, the evolution of the system is fully described by the Master equation.

Kuniyasu Saitoh; Vanessa Magnanimo; Stefan Luding

2013-11-21T23:59:59.000Z

252

COPIES: Iron Range Legislative Delegation  

E-Print Network (OSTI)

Dear Legislators: We are pleased to present the annual report on our research regarding the health status of taconite workers and Iron Range community air quality. This report, as in the past, details the progress made by the University of Minnesota School of Public Health and the Natural Resources Research Institute (NRRI) in all research areas, including occupational exposure, mortality and incidence studies, the respiratory health survey of taconite workers and spouses and the environmental study of airborne particles. In addition, this report contains specific information regarding the assessment of mesothelioma as it pertains to exposure to mineral fibers, referred to as elongate mineral particles (EMP). For this report, the EMP measurement is a standard technique that identifies those fibers (EMP) considered long (over 5 microns). Although the research team felt this was the most important exposure to be assessed with the cases of mesothelioma, in the next several months there will be additional analyses that may provide further insight, including exposure to short EMP, silica and respirable dust. A final report is planned for the end of the year when all components are expected to be completed.

Sen Tony Lourey; Rep Tim Mahoney; Rep Sheldon Johnson; Rep David Dill; Rep Mary Murphy; Sen Tom Bakk; Rep John Persell; Rep Tom Anzelc; Sen Tom Saxhaug; Rep Carly Melin; Rep Jason Metsa

2013-01-01T23:59:59.000Z

253

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

254

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

255

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

256

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

257

Electron Correlation in Iron-Based Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron Correlation in Iron-Based Superconductors Print Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in the new superconductors are as highly correlated as they are in the high-temperature superconductors. A truly international North American/European/Asian collaboration working at the ALS has now reported results from a combination of x-ray absorption spectroscopy, resonant inelastic x-ray scattering, and systematic theoretical simulations of iron-based superconductors. The team was able to settle the correlations debate by showing that electrons in the iron-based families that were studied favor itinerant (delocalized) states with only moderate correlations.

258

Carbon Emissions: Iron and Steel Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Iron and Steel Industry Iron and Steel Industry Carbon Emissions in the Iron and Steel Industry The Industry at a Glance, 1994 (SIC Code: 3312) Total Energy-Related Emissions: 39.9 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 10.7% -- Nonfuel Emissions: 22.2 MMTC Total First Use of Energy: 1,649 trillion Btu -- Pct. of All Manufacturers: 7.6% Nonfuel Use of Energy: 886 trillion Btu (53.7%) -- Coal: 858 trillion Btu (used to make coke) Carbon Intensity: 24.19 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 39.9 Coal 22.7

259

Attrition and carbon formation on iron catalysts  

DOE Green Energy (OSTI)

A serious engineering problem that needs to be addressed in the scale-up of slurry-phase, Fischer-Tropsch reactors is attrition of the precipitated iron catalyst. Attrition, which can break down the catalyst into particles too small to filter, results from both mechanical and chemical forces. This study examines the chemical causes of attrition in iron catalysts. A bench-scale, slurry-phase CSTR is used to simulate operating conditions that lead to attrition of the catalyst. The average particle size and size distribution of the catalyst samples are used to determine the effect of slurry temperature, reducing gas, gas flow rate and time upon attrition of the catalyst. Carbon deposition, a possible contributing factor to attrition, has been examined using gravimetric analysis and TEM. Conditions affecting the rate of carbon deposition have been compared to those leading to attrition of the precipitated iron catalyst.

Kohler, S.D.; Harrington, M.S.; Jackson, N.B. [Sandia National Labs., Albuquerque, NM (United States); Shroff, M.; Kalakkad, D.S.; Datye, A.K. [New Mexico Univ., Albuquerque, NM (United States). Dept. of Chemical and Nuclear Engineering

1994-08-01T23:59:59.000Z

260

Marine Diatoms Survive Iron Droughts in the Ocean by Storing Iron in  

NLE Websites -- All DOE Office Websites (Extended Search)

Marine Diatoms Survive Iron Droughts in Marine Diatoms Survive Iron Droughts in the Ocean by Storing Iron in Ferritin Almost all organisms require iron as a co-factor in numerous metalloproteins and enzymes. In particular, phytoplankton, which are aquatic, free-drifting, single-celled organisms that can harvest energy from the sun, have an elevated demand for iron due to the large role it plays in their photosynthetic machinery. In 30-40% of the world's oceans iron concentrations are low enough to limit the growth of phytoplankton (Martin and Fitzwater 1988; Moore et al. 2002). New sources of iron to these regions are sporadic and typically include atmospheric dust deposition or weak upwelling of deep waters. figure 1 Figure 1: A light micrograph of the marine pennate diatom Pseudo-nitzschia multiseries. Shown are one whole cell and two partial cells connected at the cell tips in a chain. The brown components of the cells are the chloroplasts. Scale bar = 5 mm. (Image courtesy of K. Holtermann)

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Importance of Iron Mineralogy to Aerosol Solubility: Potential Effects of  

NLE Websites -- All DOE Office Websites (Extended Search)

Importance of Iron Mineralogy to Importance of Iron Mineralogy to Aerosol Solubility: Potential Effects of Aerosol Source on Ocean Photosynthesis figure 1 Figure 1. Dust storm blowing glacial dusts from the Copper River Basin of southeast Alaska into the North Pacific Ocean, which depends on this and other external iron sources to support its biological communities. (Image: NASA MODIS satellite image, Nov. 1, 2006. http://earthobservatory.nasa.gov/IOTD/view.php?id=7094) Iron is one of the most important elements to life. Despite its paramount importance and relative abundance, dissolved iron concentrations are often very low, in part due to the formation of very stable iron minerals in most oxidizing environments. Since soluble iron is available to living organisms, iron deficiencies are widespread, and the factors that influence

262

Authority, polity, and tenuous elites in Iron Age Edom (Jordan)  

E-Print Network (OSTI)

the Iron Age in southern Jordan (Shef?eld), 4754. knauf, e.at Tawilan in southern Jordan (Oxford). bienkowski, p.the Iron Age in southern Jordan: A framework. In Bienkowski,

Porter, Benjamin W.

2004-01-01T23:59:59.000Z

263

Candidate anode materials for iron production by molten oxide electrolysis  

E-Print Network (OSTI)

Molten oxide electrolysis (MOE) has been identified by the American Iron and Steel Institute (AISI) as one of four possible breakthrough technologies to alleviate the environmental impact of iron and steel production. This ...

Paramore, James D

2010-01-01T23:59:59.000Z

264

Lab researchers achieve record pressure for solid iron  

NLE Websites -- All DOE Office Websites (Extended Search)

for solid iron. Lab researchers achieve record pressure for solid iron Breanna Bishop, LLNL, (925) 423-9802, bishop33@llnl.gov High Resolution Image Illustration of the...

265

Molecular Dynamics Simulation of Smaller Granular Particles Deposition on a Larger One Due to Velocity Sequence Dependent Electrical Charge Distribution  

E-Print Network (OSTI)

Deposition of smaller granular particles on a larger nucleus particle has been simulated in two-dimension using molecular dynamics method. Variation of sequences of velocity of deposited particles is conducted and reported in this work. The sequences obey a normal distribution function of velocity with the same parameters. It has been observed that for velocity in range of 0 to 0.02 the densest deposited site (15-17 % number of grains) is located at about angle {\\pi}/4 where location of injection point is {\\pi}/4. And the less dense is about {\\pi}/4 + {\\pi}/2. Different sequences give similar result.

Euis Sustini; Siti Nurul Khotimah; Ferry Iskandar; Sparisoma Viridi

2011-07-11T23:59:59.000Z

266

Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal  

Wind Energy; Partners (27) Visual Patent Search; Success Stories; News; Events; Industrial Technologies Iron Catalysis in Oxidations by Ozone Ames ...

267

Lithium Iron Phosphate Composites for Lithium Batteries | Argonne...  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium Iron Phosphate Composites for Lithium Batteries Technology available for licensing: Inexpensive, electrochemically active phosphate compounds with high functionality for...

268

Iron 'Veins' Are Secret of Promising New Hydrogen Storage ...  

Science Conference Proceedings (OSTI)

Iron 'Veins' Are Secret of Promising New Hydrogen Storage Material. ... International Journal of Hydrogen Energy, 36 (2011), pp. ...

2012-10-18T23:59:59.000Z

269

Iron distribution and phytoplankton iron limitation in the southern California Current System  

E-Print Network (OSTI)

chl L -1 ) in the southern offshore region. 1.3. Literaturedissolved iron concentrations at an offshore station (~700 km offshore San Diego, CA, July 2007, 29 51 N, 123

King, Andrew Luke

2008-01-01T23:59:59.000Z

270

Thermodynamic Analyses of Iron Oxides Redox Reactions  

Science Conference Proceedings (OSTI)

To clarify such confusions, the elementary thermodynamic data of various iron ... and water vapor are used to calculate the changes of thermodynamic quantities such as .... Heat Transfer Characteristic in a Slag Heat Recovery Chamber ... Numerical Simulation of Electro-magnetic Flow Control Phenomenon in a Tundish.

271

Removal of RDX and HMX from an artificial groundwater by granular activated carbon  

E-Print Network (OSTI)

Granular activated carbon (GAC) adsorption was efficient at removing high explosive contaminants such as Hexahydro-1,3,5-trinitro-1,3,5-tririne (RDX) and Octahydro-1,3,5,7-tetrritro-1,3,5,7-tetruocine (HMX) from an artificial groundwater (AGW). A completely mixed batch reactor (CMBR) system was selected for all rate and isotherm experiments. A number of rate and isotherm experiments were conducted to measure performance in the removal of RDX and HMX using GAC depending on dissolved oxygen, natural organic matter (NOM) preloading and GAC pretreatment. The investigation of competitive adsorption of RDX and Cr(VI) on GAC was conducted. In addition, IAST model predictions were made for RDX and HMX bisolute isotherms. When oxygen was excluded in the experimental system, there was enhancement in the removal of RDX from AGW using Fe[] pretreated GAC. However, in spite of this enhancement, it was still lower than the level of removal using virgin GAC as discussed below. According to the screening experiment results, dissolved Fe[]alone could not chemically reduce RDX. Despite expectations to the contrary based on the screening results, there was indeed some increase in the removal of RDX by Fe[] pretreated GAC under anaerobic conditions. It was suspected that in regard to the removal of RDX using GAC, there may have been chemical reactions occurring between RDX and the chemically reduced GAC surface under anaerobic conditions. Overall, the sorption capacity of GAC for RDX and HMX decreased as preloaded humid acid concentration increased. GAC procreated with a strong reluctant such as Fe[] or dithionite did not result in the enhancement of RDX removal from AGW compared with isotherms of virgin GAC under both aerobic and anaerobic conditions. Experimental values showed that for RDX, the single-solute isotherm data, bisolute isotherm data in the presence of Cr(VI) exhibited similar results. This suggests that the presence of Cr(VI) had negligible effect on RDX removal by GAC, indicating that competitive effects between RDX and Cr(VI) were minimal. Also, Cr(VI) removal was not significantly affected by the presence of RDX. IAST model predicted that the presence of HMX would reduce the adsorption of RDX compared to the single-solute isotherm of RDX. In the same manner, similar effects were obtained for HMX.

Im, Jeong Ran

1999-01-01T23:59:59.000Z

272

Conditions for making direct reduced iron, transition direct reduced iron and pig iron nuggets in a laboratory furnace - Temperature-time transformations  

Science Conference Proceedings (OSTI)

The pig iron nugget process is gaining in importance as an alternative to the traditional blast furnace. Throughout the process, self-reducing-fluxing dried greenballs composed of iron ore concentrate, reducing-carburizing agent (coal), flux (limestone) and binder (bentonite) are heat-treated. During the heat treatment, dried greenballs are first transformed into direct reduced iron (DRI), then to transition direct reduced iron (TDRI) and finally to pig iron nuggets. The furnace temperature and/or residence time and the corresponding levels of carburization, reduction and metallization dictate these transformations. This study involved the determination of threshold furnace temperatures and residence times for completion of all of the transformation reactions and pig iron nugget production. The experiments involved the heat treatment of self-reducing-fluxing dried greenballs at various furnace temperatures and residence times. The products of these heat treatments were identified by utilizing optical microscopy, apparent density and microhardness measurements.

Anameric, B.; Kawatra, S.K. [Michigan Technological University, Houghton, MI (United States). Dept. of Chemical Engineering

2007-02-15T23:59:59.000Z

273

Modeling of the charging characteristic of linear-type superconducting power supply using granular-based radial basis function neural networks  

Science Conference Proceedings (OSTI)

Since superconducting coils cause the current decay due to connection resistance and intrinsic characteristic in the persistent current mode, various current compensations should be required to maintain stable property in the superconducting magnet system. ... Keywords: Charging characteristic, Fuzzy C-means (FCM) clustering method, Granular-based radial basis function neural network, Information granules, K-means clustering, Linear-type superconducting power supply

H. -S. Park; W. Pedrycz; Y. -D. Chung; S. -K. Oh

2012-01-01T23:59:59.000Z

274

Lithium-aluminum-iron electrode composition  

DOE Patents (OSTI)

A negative electrode composition is presented for use in a secondary electrochemical cell. The cell also includes an electrolyte with lithium ions such as a molten salt of alkali metal halides or alkaline earth metal halides that can be used in high-temperature cells. The cell's positive electrode contains a a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent in an alloy of aluminum-iron. Various binary and ternary intermetallic phases of lithium, aluminum and iron are formed. The lithium within the intermetallic phase of Al.sub.5 Fe.sub.2 exhibits increased activity over that of lithium within a lithium-aluminum alloy to provide an increased cell potential of up to about 0.25 volt.

Kaun, Thomas D. (Mokena, IL)

1979-01-01T23:59:59.000Z

275

Iron-sulfide redox flow batteries  

Science Conference Proceedings (OSTI)

Iron-sulfide redox flow battery (RFB) systems can be advantageous for energy storage, particularly when the electrolytes have pH values greater than 6. Such systems can exhibit excellent energy conversion efficiency and stability and can utilize low-cost materials that are relatively safer and more environmentally friendly. One example of an iron-sulfide RFB is characterized by a positive electrolyte that comprises Fe(III) and/or Fe(II) in a positive electrolyte supporting solution, a negative electrolyte that comprises S.sup.2- and/or S in a negative electrolyte supporting solution, and a membrane, or a separator, that separates the positive electrolyte and electrode from the negative electrolyte and electrode.

Xia, Guan-Guang; Yang, Zhenguo; Li, Liyu; Kim, Soowhan; Liu, Jun; Graff, Gordon L

2013-12-17T23:59:59.000Z

276

Magnetism and Superconductivity in Iron Pnictides  

Science Conference Proceedings (OSTI)

The discovery of high temperature superconductivity in iron pnictides and chalcogenides has resulted in surprising new insights into high temperature superconductivity and its relationship with magnetism. Here we provide an overview of some of what is known about these materials and in particular about the interplay of magnetism and superconductivity in them. Similarities and contrasts with cuprate superconductors are emphasized and the superconducting pairing is discussed within the framework of spin fluctuation induced pairing.

Singh, David J [ORNL

2012-01-01T23:59:59.000Z

277

Thin Wall Cast Iron: Phase II  

DOE Green Energy (OSTI)

The development of thin-wall technology allows the designers of energy consuming equipment to select the most appropriate material based on cost/material properties considerations, and not solely on density. The technology developed in this research project will permit the designers working for the automotive industry to make a better informed choice between competing materials and thin wall cast iron, thus decreasing the overall cost of the automobile.

Doru M. Stefanescu

2005-07-21T23:59:59.000Z

278

Seal welded cast iron nuclear waste container  

SciTech Connect

This invention identifies methods and articles designed to circumvent metallurgical problems associated with hermetically closing an all cast iron nuclear waste package by welding. It involves welding nickel-carbon alloy inserts which are bonded to the mating plug and main body components of the package. The welding inserts might be bonded in place during casting of the package components. When the waste package closure weld is made, the most severe thermal effects of the process are restricted to the nickel-carbon insert material which is far better able to accommodate them than is cast iron. Use of nickel-carbon weld inserts should eliminate any need for pre-weld and post-weld heat treatments which are a problem to apply to nuclear waste packages. Although the waste package closure weld approach described results in a dissimilar metal combination, the relative surface area of nickel-to-iron, their electrochemical relationship, and the presence of graphite in both materials will act to prevent any galvanic corrosion problem.

Filippi, Arthur M. (Pittsburgh, PA); Sprecace, Richard P. (Murrysville, PA)

1987-01-01T23:59:59.000Z

279

Iron phosphate compositions for containment of hazardous metal waste  

DOE Patents (OSTI)

An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P{sub 2}O{sub 5} and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe{sup 3+} provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided. 21 figs.

Day, D.E.

1998-05-12T23:59:59.000Z

280

Iron Corrosion Observations: Pu(VI)-Fe Reduction Studies  

Science Conference Proceedings (OSTI)

Iron and Pu Reduction: (1) Very different appearances in iron reaction products were noted depending on pH, brine and initial iron phase; (2) Plutonium was associated with the Fe phases; (3) Green rust was often noted at the higher pH; (4) XANES established the green rust to be an Fe2/3 phase with a bromide center; and (5) This green rust phase was linked to Pu as Pu(IV).

Reed, Donald T. [Los Alamos National Laboratory; Swanson, Juliet S. [Los Alamos National Laboratory; Richmann, Michael K. [Los Alamos National Laboratory; Lucchini, Jean-Francois [Los Alamos National Laboratory; Borkowski, Marian [Los Alamos National Laboratory

2012-09-11T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Investigation on Modified Humic Substances Based Binders for Iron ...  

Science Conference Proceedings (OSTI)

Presentation Title, Investigation on Modified Humic Substances Based Binders for Iron ... An Electron Microscopy Study of Nanoscale Surface and Sub-Surface...

282

Unusual 'Collapsing' Iron Superconductor Sets Record for Its ...  

Science Conference Proceedings (OSTI)

... superconductor that operates at the highest known temperature for a material in its class.* The discovery inches iron-based superconductors ...

2012-02-07T23:59:59.000Z

283

The Investigation of Sponge Iron Production Parameters by Using ...  

Science Conference Proceedings (OSTI)

May 1, 2007 ... In the present work, the possibilities of coal-based sponge iron production for industrial applications by using domestic lignite coal were...

284

Coal-based Direct Reduction of Iron Concentrate Pellets by ...  

Science Conference Proceedings (OSTI)

Presentation Title, Coal-based Direct Reduction of Iron Concentrate Pellets by Microwave Heating. Author(s), Wang Xia, Huang Zhucheng. On-Site Speaker...

285

Spark Plasma Sintering of Iron and Titanium Powders by ...  

Science Conference Proceedings (OSTI)

Mixtures of titanium and iron powders were activated in kerosene by high-voltage electrical discharges with different electrical discharge numbers.

286

Recent Progress in Molten Oxide Electrolysis for Iron Production  

Science Conference Proceedings (OSTI)

Presentation Title, Recent Progress in Molten Oxide Electrolysis for Iron Production ... Concentrated Solar Power for Producing Liquid Fuels from CO2 and H2O.

287

MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY  

E-Print Network (OSTI)

and J. Newman, Proc. Syrup. Battery Design and Optimization,123, 1364 (1976). Symp, Battery Design and Optimization, S.~ALUMINUM, IRON SULFIDE BATTERY Contents ACKNOWLEDGEMENTS

Pollard, Richard

2012-01-01T23:59:59.000Z

288

Regenerable Mixed Copper-Iron-Inert Support Oxygen ...  

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group

289

Mathematical Modeling for Side-Blow Combustion Region in Iron ...  

Science Conference Proceedings (OSTI)

Presentation Title, Mathematical Modeling for Side-Blow Combustion Region in Iron Bath Reactor with H2-C Mixture Reduction. Author(s), Bo Zhang, Hong Xin.

290

Effect of the Raw Material Characteristic of Iron Concentrates on ...  

Science Conference Proceedings (OSTI)

It has important instructing function for China steel mills to import and use iron ... Numerical Simulation of Electromagnetic Fields in Microwave Gas Heating...

291

Niobium Alloying in Grey Cast Iron for Vehicle Brake Discs  

Science Conference Proceedings (OSTI)

Presentation Title, Niobium Alloying in Grey Cast Iron for Vehicle Brake Discs. Author(s) ... Microtexture Analysis of a Hot Rolled Silicon Electric Steel Niobium

292

Low Resistivity Contact to Iron-Pnicitide Superconductors ...  

Iron-pnictide based superconductors have a number of superior properties as compared to other known high temperature ... Geothermal; Hydrogen and Fuel ...

293

Strengthening Sintering of Refractory Iron Ore with Biomass Fuel  

Science Conference Proceedings (OSTI)

Presentation Title, Strengthening Sintering of Refractory Iron Ore with Biomass Fuel. Author(s), Xiaohui Fan, Zhiyun Ji, Min Gan, Xuling Chen, Wenqi Li. On-Site

294

Iron active electrode and method of making same  

DOE Green Energy (OSTI)

An iron active electrode and method of preparing same in which iron sulfate is calcined in an oxidizing atmosphere at a temperature in the range of from about 600/sup 0/C to about 850/sup 0/C for a time sufficient to produce an iron oxide with a trace amount of sulfate are described. The calcined material is loaded into an electrically conductive support and then heated in a reducing atmosphere at an elevated temperature to produce activated iron having a trace amount of sulfide which is formed into an electrode plate.

Jackovitz, J.F.; Seidel, J.; Pantier, E.A.

1981-04-16T23:59:59.000Z

295

Materials Sustainability: Digital Resource Center - Iron and Steel ...  

Science Conference Proceedings (OSTI)

Jul 3, 2008 ... ABSTRACT: Consumption of iron and steel scrap and the health of the scrap industry depend directly on the health of the steelmaking industry.

296

PRODUCTION OF IRON FROM METALLURGICAL WASTE - Energy Innovation Portal  

Building Energy Efficiency ... Solar Thermal; Startup ... heating the agglomerates to a higher temperature above the melting point of iron to form nodules of metallic ...

297

New Iron-based Superconductors Reinforce Link to ...  

Science Conference Proceedings (OSTI)

New Iron-based and Copper-Oxide High-Temperature Superconductors Share Key Magnetic Properties. For Immediate Release: May 28, 2008. ...

2011-05-04T23:59:59.000Z

298

Vitrification of DOE Problematic Wastes Using Iron Phosphate Glasses  

Science Conference Proceedings (OSTI)

Abstract Scope, This work is to formulate and optimize iron phosphate glass compositions which are suitable for vitrifying several specified Hanford HLW and ...

299

Iron-Air Rechargeable Battery: A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage  

Science Conference Proceedings (OSTI)

GRIDS Project: USC is developing an iron-air rechargeable battery for large-scale energy storage that could help integrate renewable energy sources into the electric grid. Iron-air batteries have the potential to store large amounts of energy at low costiron is inexpensive and abundant, while oxygen is freely obtained from the air we breathe. However, current iron-air battery technologies have suffered from low efficiency and short life spans. USC is working to dramatically increase the efficiency of the battery by placing chemical additives on the batterys iron-based electrode and restructuring the catalysts at the molecular level on the batterys air-based electrode. This can help the battery resist degradation and increase life span. The goal of the project is to develop a prototype iron-air battery at significantly cost lower than todays best commercial batteries.

None

2010-10-01T23:59:59.000Z

300

Arsenic remediation of drinking water using iron-oxide coated coal bottom ash  

E-Print Network (OSTI)

using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwaterusing iron?oxidecoatedcoalbottomash JohannaL. using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

MATHIEU, JOHANNA L.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Iron(II) Oxidation by SO 2 /O 2 in Uranium Leach Solutions  

Science Conference Proceedings (OSTI)

Aug 1, 2003 ... Oxidants are added in uranium leaching in acid media to convert iron(II) in solution to iron(III). Iron(III) has an important role in the leaching of...

302

New trends in industrial energy efficiency in the Mexico iron and steel industry  

E-Print Network (OSTI)

in the iron and steel industry" in 1997 ACEEE Summer Studyin the Mexican Iron and Steel industry are the B O F and theInternational Iron and Steel Industry, Brussels, pp. 47-48

Ozawa, Leticia; Martin, Nathan; Worrell, Ernst; Price, Lynn; Sheinbaum, Claudia

1999-01-01T23:59:59.000Z

303

Electrically insulating phosphate coatings for iron powder based electromagnetic core applications  

E-Print Network (OSTI)

Powdered metals, such as iron, are a common building block for electromagnetic cores. An iron powder was reacted with phosphoric acid to create a layer of iron phosphate on each particle. This electrically insulating ...

Nolan, William Rane

2009-01-01T23:59:59.000Z

304

Void trapping of hydrogen in sintered iron  

DOE Green Energy (OSTI)

The effect of void trapping of hydrogen in iron was studied using the gas-phase permeation technique. Iron membranes of controlled void density, varying from 92% to 98% were prepared by press and sintering of electrolytic iron powder. The presence of internal voids showed no effect on the steady state flux of hydrogen through the membrane. The effective diffusivity, obtained by the time lag method, increased with the increase of input hydrogen partial pressure. This disagreement with the prediction of the theory in literature was explained by the existence of hydrogen in both the diatomic gaseous form and as adsorbed hydrogen. This explanation was further confirmed by examining the dependence of trapped hydrogen concentration with pressure. The linear dependence of trapped hydrogen concentration in voids with external hydrogen partial pressure for samples of 96%, 94% and 92% dense were given respectively by C/sub g/ = (1.5 +- 0.2) x 10/sup 15/ P + (3.2 +- 0.5) x 10/sup 14/ atoms of H/c.c. C/sub g/ = (2.1 +- 0.6) x 10/sup 15/ P + (1.7 +- 0.5) x 10/sup 15/ atoms of H/c.c. C/sub g/ = (4.5 +- 0.3) x 10/sup 15/ P + (6.5 +- 0.2) x 10/sup 15/ atoms of H/c.c. The discrepancy between the reported values and the values predicted by theory was explained by the poisoning of some of the voids by surface oxides.

Wong, K.C.

1976-09-01T23:59:59.000Z

305

Unconventional temperature enhanced magnetism in iron telluride  

SciTech Connect

Discoveries of copper and iron-based high-temperature superconductors (HTSC)1-2 have challenged our views of superconductivity and magnetism. Contrary to the pre-existing view that magnetism, which typically involves localized electrons, and superconductivity, which requires freely-propagating itinerant electrons, are mutually exclusive, antiferromagnetic phases were found in all HTSC parent materials3,4. Moreover, highly energetic magnetic fluctuations, discovered in HTSC by inelastic neutron scattering (INS) 5,6, are now widely believed to be vital for the superconductivity 7-10. In two competing scenarios, they either originate from local atomic spins11, or are a property of cooperative spin-density-wave (SDW) behavior of conduction electrons 12,13. Both assume clear partition into localized electrons, giving rise to local spins, and itinerant ones, occupying well-defined, rigid conduction bands. Here, by performing an INS study of spin dynamics in iron telluride, a parent material of one of the iron-based HTSC families, we have discovered that this very assumption fails, and that conduction and localized electrons are fundamentally entangled. In the temperature range relevant for the superconductivity we observe a remarkable redistribution of magnetism between the two groups of electrons. The effective spin per Fe at T 10 K, in the2 antiferromagnetic phase, corresponds to S 1, consistent with the recent analyses that emphasize importance of Hund s intra-atomic exchange15-16. However, it grows to S 3/2 in the disordered phase, a result that profoundly challenges the picture of rigid bands, broadly accepted for HTSC.

Zalinznyak, I. [Brookhaven National Laboratory (BNL); Xu, Zhijun [ORNL; Tranquada, John M. [Brookhaven National Laboratory (BNL); Gu, G. D. [Brookhaven National Laboratory (BNL); Tsvelik, A. [Brookhaven National Laboratory (BNL); Stone, Matthew B [ORNL

2011-01-01T23:59:59.000Z

306

Charge exchange processes involving iron ions  

DOE Green Energy (OSTI)

A review and evaluation is given of the experimental data which are available for charge exchange processes involving iron ions and neutral H, H/sub 2/ and He. Appropriate scaling laws are presented, and their accuracy estimated for these systems. A bibliography is given of available data sources, as well as of useful data compilations and review articles. A procedure is recommended for providing single approximate formulae to the fusion community to describe total cross sections for electron capture by partially-stripped Fe/sup q+/ ions in collisions with H, H/sub 2/ and He, based on the scaling relationships suggested by Janev and Hvelplund.

Phaneuf, R.A.

1985-01-01T23:59:59.000Z

307

Suspension Hydrogen Reduction of Iron Oxide Concentrates  

DOE Green Energy (OSTI)

The objective of the project is to develop a new ironmaking technology based on hydrogen and fine iron oxide concentrates in a suspension reduction process. The ultimate objective of the new technology is to replace the blast furnace and to drastically reduce CO2 emissions in the steel industry. The goals of this phase of development are; the performance of detailed material and energy balances, thermochemical and equilibrium calculations for sulfur and phosphorus impurities, the determination of the complete kinetics of hydrogen reduction and bench-scale testing of the suspension reduction process using a large laboratory flash reactor.

H.Y. Sohn

2008-03-31T23:59:59.000Z

308

Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. Iron and Steel sector  

E-Print Network (OSTI)

scrap steel, pig iron, or direct reduced iron (DRI) using anfrom scrap and/or direct reduced iron (DRI, also calledAlternatives Direct reduced iron (DRI), hot briquetted

Worrell, Ernst; Martin, N.; Price, L.

1999-01-01T23:59:59.000Z

309

A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.  

E-Print Network (OSTI)

Mt, net imported Direct-Reduced Iron (DRI) in 2006 was 2.61in Figure 3) pig iron, direct-reduced iron (DRI), pellets,of net imported direct reduced iron Energy used for the

Hasanbeigi, Ali

2012-01-01T23:59:59.000Z

310

Study on Nucleation and Growth Mechanism of Iron Crystal Grain in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Study on Nucleation and Growth Mechanism of Iron Crystal Grain in Coal-Based Shaft Furnace Direct Reduction Iron Pellets by Microwave...

311

Trophic status of Chlamydomonas reinhardtii influences the impact of iron deficiency on photosynthesis  

E-Print Network (OSTI)

of iron de?ciency on photosynthesis Aimee M. Terauchi rates by suppress- ing photosynthesis but increasing insteadal. 2007). In oxygenic photosynthesis, iron is a cofactor in

Terauchi, Aimee M.; Peers, Graham; Kobayashi, Marilyn C.; Niyogi, Krishna K.; Merchant, Sabeeha S.

2010-01-01T23:59:59.000Z

312

Mechanism of the hysteretic behavior of the magnetoresistance of granular HTSCs: The universal nature of the width of the magnetoresistance hysteresis loop  

Science Conference Proceedings (OSTI)

The hysteretic behavior of the magnetoresistance R(H) of granular high-temperature superconductors (HTSCs) of the Y-Ba-Cu-O, Bi-Ca-Sr-Cu-O, and La-Sr-Cu-O classical systems is investigated for transport current densities lower and higher than the critical density (at H = 0). All systems exhibit universal behavior of the width of the magnetoresistance hysteresis loop: independence of transport current under identical external conditions. This means that flux trapping in HTSC grains is the main mechanism controlling the hysteretic behavior of the magnetoresistance of granular HTSCs, while pinning of Josephson vortices in the intragranular medium makes no appreciable contribution to the formation of magnetoresistance hysteresis (when transport current flows through the sample). Experimental data on relaxation of residual resistance after the action of a magnetic field also confirm this conclusion.

Balaev, D. A., E-mail: smp@iph.krasn.ru; Dubrovskii, A. A.; Shaikhutdinov, K. A.; Popkov, S. I.; Gokhfeld, D. M.; Gokhfeld, Yu. S.; Petrov, M. I. [Russian Academy of Sciences, Kirenskii Institute of Physics, Siberian Branch (Russian Federation)

2009-02-15T23:59:59.000Z

313

Desulfurization mixture and process for desulfurizing pig iron  

SciTech Connect

Process and composition for desulfurizing pig iron in which the desulfurization agent consists essentially of calcium carbide, a gas-evolving component and fluorspar; the advantage of the process and composition is that it reduces dust pollution and danger of flaming in the handling of the slag after the desulfurization of pig iron.

Freissmuth, A.; Gmohling, W.; Rock, H.

1982-02-16T23:59:59.000Z

314

The release of iron during coal combustion. Milestone report  

Science Conference Proceedings (OSTI)

Iron plays an important role in the formation of both fly ash and deposits in many pulverized-coal-fired boilers. Several authors indicate that iron content is a significant indicator of the slagging propensity of a majority of US bituminous coals, in particular eastern bituminous coals. The pyritic iron content of these coals is shown to be a particularly relevant consideration. A series of investigations of iron release during combustion is reported for a suite of coals ranging in rank from lignite to low-volatile bituminous coal under combustion conditions ranging from oxidizing to inert. Experimental measurements are described in which, under selected conditions, major fractions of the iron in the coal are released within a 25 ms period immediately following coal devolatilization. Mechanistic interpretation of the data suggest that the iron is released as a consequence of oxygen attack on porous pyrrhotite particles. Experimental testing of the proposed mechanism reveals that the release is dependent on the presence of both pyrite in the raw coal and oxygen in the gas phase, that slow preoxidation (weathering) of the pyrite significantly inhibits the iron release, and that iron loss increases as oxygen penetration of the particle increases. Each observation is consistent with the postulated mechanism.

Baxter, L.L. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility

1995-06-01T23:59:59.000Z

315

EnvIRONment and Other Bath Smelting Processes for Treating ...  

Science Conference Proceedings (OSTI)

Although the American Iron and Steel Institute-Department of Energy program is ... definitely superior to the direct-reduced iron and scrap available on the ferrous market. ..... Based on in-house and independent analyses, it should be profitable to run an .... For more information, contact G. Brooks, University of Wollongong,...

316

Iron isotopic fractionation during continental weathering  

SciTech Connect

The biological activity on continents and the oxygen content of the atmosphere determine the chemical pathways through which Fe is processed at the Earth's surface. Experiments have shown that the relevant chemical pathways fractionate Fe isotopes. Measurements of soils, streams, and deep-sea clay indicate that the {sup 56}Fe/{sup 54}Fe ratio ({delta}{sup 56}Fe relative to igneous rocks) varies from +1{per_thousand} for weathering residues like soils and clays, to -3{per_thousand} for dissolved Fe in streams. These measurements confirm that weathering processes produce substantial fractionation of Fe isotopes in the modern oxidizing Earth surface environment. The results imply that biologically-mediated processes, which preferentially mobilize light Fe isotopes, are critical to Fe chemistry in weathering environments, and that the {delta}{sup 56}Fe of marine dissolved Fe should be variable and negative. Diagenetic reduction of Fe in marine sediments may also be a significant component of the global Fe isotope cycle. Iron isotopes provide a tracer for the influence of biological activity and oxygen in weathering processes through Earth history. Iron isotopic fractionation during weathering may have been smaller or absent in an oxygen-poor environment such as that of the early Precambrian Earth.

Fantle, Matthew S.; DePaolo, Donald J.

2003-10-01T23:59:59.000Z

317

Field Projects: Monticello, Utah | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Long-Term Surveillance - Operations and Maintenance Long-Term Surveillance - Operations and Maintenance » Permeable Reactive Barriers » Field Projects: Monticello, Utah Field Projects: Monticello, Utah A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM managed remediation of tailings and tailings-contaminated material at this site. Cleanup of the mill site is regulated under the Comprehensive Environmental Response, Compensation, and Liability Act. Arsenic, molybdenum, nitrate, selenium, uranium, and vanadium are contaminants of concern in groundwater at the site. An Interim Record of Decision designated emplacement of a PRB hydraulically downgradient of the mill site to remove these contaminants. Results of both laboratory and

318

Microsoft Word - Appendix G.doc  

Office of Legacy Management (LM)

1 are included in this appendix. 1 are included in this appendix. Appendix G, Page 1 RFLMA Contact Record 2011-01 1 of 5 ROCKY FLATS SITE REGULATORY CONTACT RECORD Purpose: Replace Mound Site Plume Treatment System (MSPTS) media and maintain/repair discharge gallery. Contact Record Approval Date: 1/14/11 Site Contact(s)/Affiliation(s): Scott Surovchak, U.S. Department of Energy (DOE); John Boylan, S.M. Stoller (Stoller); Rick DiSalvo, Stoller Regulatory Contact(s)/Affiliation(s): Carl Spreng, Colorado Department of Public Health and Environment (CDPHE); Vera Moritz, U.S. Environmental Protection Agency (EPA) Discussion: A routine maintenance activity to remove the MSPTS spent treatment media (zero valent iron [ZVI] filings) and replace it with new ZVI media is scheduled for January-February 2011. The last

319

Pilot testing of in situ chemical reduction to treat carbon tetrachloride  

NLE Websites -- All DOE Office Websites (Extended Search)

Pilot testing of in situ chemical reduction to treat carbon tetrachloride Pilot testing of in situ chemical reduction to treat carbon tetrachloride at a former grain storage facility in Missouri March 26, 2013 At a former grain storage facility in Missouri, EVS has initiated a pilot test of an innovative treatment using amended zero-valent iron to achieve in situ chemical reduction of carbon tetrachloride contamination. Carbon tetrachloride concentrations above regulatory levels in soil and groundwater (at 8-89 ft below ground level [BGL]) are confined to a small area of the former facility, on property that is now a county fairground. At present, the contamination poses no known risks to fairgrounds workers or visitors. The deep bedrock aquifers in the area are at minimal risk of contamination. The areas targeted for treatment in the pilot test are localized

320

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

6 results: 6 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Donald Lucas [Clear All Filters] 2012 Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland. "Increased Cytotoxicity of Oxidized Flame Soot." Atmospheric Pollution Research 3, no. 1 (2012): 25-31. 2009 Keenan, Christina R., Regine Goth-Goldstein, Donald Lucas, and David L. Sedlak. "Oxidative Stress Induced by Zero-Valent Iron Nanoparticles and Fe(II) in Human Bronchial Epithelial Cells." Environmental Science & Technology 43, no. 12 (2009): 4555-4560. Singer, Brett C., Michael G. Apte, Douglas R. Black, Toshifumi Hotchi, Donald Lucas, Melissa M. Lunden, Anna G. Mirer, Michael Spears, and Douglas P. Sullivan. Natural Gas Variability in California: Environmental Impacts

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

3 results: 3 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Regine Goth-Goldstein [Clear All Filters] 2012 Holder, Amara L., Brietta J. Carter, Regine Goth-Goldstein, Donald Lucas, and Catherine P. Koshland. "Increased Cytotoxicity of Oxidized Flame Soot." Atmospheric Pollution Research 3, no. 1 (2012): 25-31. 2010 Goth-Goldstein, Regine, Marion L. Russell, Donghui Li, Ana P. Müller, Maira Caleffi, Joao Eschiletti, Marcia Graudenz, and Michael D. Sohn. Role of CYP1B1 in PAH-DNA Adduct Formation and Breast Cancer Risk. Berkeley: Lawrence Berkeley National Laboratory, 2010. 2009 Keenan, Christina R., Regine Goth-Goldstein, Donald Lucas, and David L. Sedlak. "Oxidative Stress Induced by Zero-Valent Iron Nanoparticles and

322

Treatability study for removal of leachable mercury in crushed fluorescent lamps  

SciTech Connect

Nonserviceable fluorescent lamps removed from radiological control areas at the Oak Ridge Department of Energy facilities have been crushed and are currently managed as mixed waste (hazardous and radiologically contaminated). We present proposed treatment flowsheets and supporting treatability study data for conditioning this solid waste residue so that it can qualify for disposal in a sanitary landfill. Mercury in spent fluorescent lamps occurs primarily as condensate on high-surface-area phosphor material. It can be solubilized with excess oxidants (e.g., hypochlorite solution) and stabilized by complexation with halide ions. Soluble mercury in dechlorinated saline solution is effectively removed by cementation with zero-valent iron in the form of steel wool. In packed column dynamic flow testing, soluble mercury was reduced to mercury metal and insoluble calomel, loading > 1.2 g of mercury per grain of steel wool before an appreciable breakthrough of soluble mercury in the effluent.

Bostick, W.D.; Beck, D.E.; Bowser, K.T. [and others

1996-02-01T23:59:59.000Z

323

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

71 - 21880 of 28,905 results. 71 - 21880 of 28,905 results. Page Field Projects: Monticello, Utah A permeable reactive barrier (PRB) of zero-valent iron is helping to clean up groundwater at a former uranium and vanadium ore processing mill at Monticello, Utah. LM managed remediation of... http://energy.gov/lm/field-projects-monticello-utah Page Carbon Storage Monitoring, Verification and Accounting Research Reliable and cost-effective monitoring, verification and accounting (MVA) techniques are an important part of making geologic sequestration a safe, effective, and acceptable method for greenhouse... http://energy.gov/fe/science-innovation/carbon-capture-and-storage-research/carbon-storage-monitoring-verification-and Article Moab Marks 6-Million-Ton Cleanup Milestone MOAB, Utah - 6,000,000 is a big number, and it marks a significant

324

Electrochemical Deposition of Iron Nanoneedles on Titanium Oxide Nanotubes  

Science Conference Proceedings (OSTI)

Iron as a catalyst has wide applications for hydrogen generation from ammonia, photodecomposition of organics, and carbon nanotube growth. Tuning the size and shape of iron is meaningful for improving the catalysis efficiency. It is the objective of this work to prepare nanostructured iron with high surface area via electrochemical deposition. Iron nanoneedles were successfully electrodeposited on Ti supported TiO2 nanotube arrays in a chlorine-based electrolyte containing 0.15 M FeCl2 {center_dot} 4H2O and 2.0 M HCl. Transmission electron microscopic analysis reveals that the average length of the nanoneedles is about 200 nm and the thickness is about 10 nm. It has been found that a high overpotential at the cathode made of Ti/TiO2 nanotube arrays is necessary for the formation of the nanoneedles. Cyclic voltammetry test indicates that the electrodeposition of iron nanoneedles is a concentration-limited process.

Gan Y. X.; Zhang L.; Gan B.J.

2011-10-01T23:59:59.000Z

325

System and method for producing metallic iron nodules  

SciTech Connect

A method for producing metallic iron nodules by assembling a shielding entry system to introduce coarse carbonaceous material greater than 6 mesh in to the furnace atmosphere at location(s) where the temperature of the furnace atmosphere adjacent at least partially reduced reducible iron bearing material is between about 2200 and 2650.degree. F. (1200 and 1450.degree. C.), the shielding entry system adapted to inhibit emission of infrared radiation from the furnace atmosphere and seal the furnace atmosphere from exterior atmosphere while introducing coarse carbonaceous material greater than 6 mesh into the furnace to be distributed over the at least partially reduced reducible iron bearing material, and heating the covered at least partially reduced reducible iron bearing material in a fusion atmosphere to assist in fusion and inhibit reoxidation of the reduced material during fusion to assist in fusion and inhibit reoxidation of the reduced material in forming metallic iron nodules.

Bleifuss, Rodney L. (Grand Rapids, MN); Englund, David J. (Bovey, MN); Iwasaki, Iwao (Grand Rapids, MN); Lindgren, Andrew J. (Grand Rapids, MN); Kiesel, Richard F. (Hibbing, MN)

2011-09-20T23:59:59.000Z

326

ITP Mining: Energy and Environmental Profile of the U.S. Mining Industry: Chapter 4: Iron  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4 4 Iron The chemical element iron is the fourth most common element in the Earth's crust and the second most abundant metal. About five percent of the Earth's crust is composed of iron. The metal is chemically active and is found in nature combined with other elements in rocks and soils. In its natural state, iron is chemically bonded with oxygen, water, carbon dioxide, or sulfur in a variety of minerals. Forms of Iron Minerals, Ores, and Rocks Iron occurs mainly in iron-oxide ores. Some ores are a mixture of minerals rich in iron. Other iron ores are less rich and have a large number of impurities. The most important iron ore- forming minerals are: * Magnetite - Magnetite (Fe 3 O 4 ) forms magnetic black iron ore. There are large deposits of

327

Theoretical Investigation of Hydrogen Adsorption and dissociation on Iron and Iron Carbide Surfaces Using the ReaxFF Reactive Force Field Method  

SciTech Connect

We have developed a ReaxFF reactive force field to describe hydrogen adsorption and dissociation on iron and iron carbide surfaces relevant for simulation of FischerTropsch (FT) synthesis on iron catalysts. This force field enables large system (>>1000 atoms) simulations of hydrogen related reactions with iron. The ReaxFF force field parameters are trained against a substantial amount of structural and energetic data including the equations of state and heats of formation of iron and iron carbide related materials, as well as hydrogen interaction with iron surfaces and different phases of bulk iron. We have validated the accuracy and applicability of ReaxFF force field by carrying out molecular dynamics simulations of hydrogen adsorption, dissociation and recombination on iron and iron carbide surfaces. The barriers and reaction energies for molecular dissociation on these two types of surfaces have been compared and the effect of subsurface carbon on hydrogen interaction with iron surface is evaluated. We found that existence of carbon atoms at subsurface iron sites tends to increase the hydrogen dissociation energy barrier on the surface, and also makes the corresponding hydrogen dissociative state relatively more stable compared to that on bare iron. These properties of iron carbide will affect the dissociation rate of H{sub 2} and will retain more surface hydride species, thus influencing the dynamics of the FT synthesis process.

Zou, Chenyu; van Duin, Adri C.T.; Sorescu, Dan C.

2012-06-01T23:59:59.000Z

328

Characterization and Correlation of Particle-Level Interactions to the Macroscopic Rheology of Powders, Granular Slurries, and Colloidal Suspensions  

SciTech Connect

Hanford TRU tank sludges are complex mixtures of undissolved minerals and salt solids in an aqueous phase of high ionic strength. They show complex rheological behavior resulting from interactions at the macroscopic level, such as interparticle friction between grains in the coarse fraction, as well as from interactions at the nano-scale level, such as the agglomeration of colloidal particles. An understanding of how phenomena such as interparticle friction and aggregate stability under shear will allow better control of Hanford TRU tank sludges being processed for disposal. The project described in this report had two objectives. The first was to understand the physical properties and behavior of the Hanford transuranic (TRU) tank sludges under conditions that might exist during retrieval, treatment, packaging, and transportation for disposal at the Waste Isolation Pilot Plant (WIPP). The second objective was to develop a fundamental understanding of sludge physical properties by correlating the macroscopic behavior with interactions occurring at the particle/colloidal scale. These objectives were accomplished by: 1) developing continuum models for coarse granular slurries and 2) studying the behavior of colloidal agglomerates under shear and under irradiation.

Poloski, Adam P.; Daniel, Richard C.; Rector, David R.; Bredt, Paul R.; Buck, Edgar C.; Berg, John C.; Saez, Avelino E.

2006-09-29T23:59:59.000Z

329

Multiple hearth furnace for reducing iron oxide  

SciTech Connect

A multiple moving hearth furnace (10) having a furnace housing (11) with at least two moving hearths (20) positioned laterally within the furnace housing, the hearths moving in opposite directions and each moving hearth (20) capable of being charged with at least one layer of iron oxide and carbon bearing material at one end, and being capable of discharging reduced material at the other end. A heat insulating partition (92) is positioned between adjacent moving hearths of at least portions of the conversion zones (13), and is capable of communicating gases between the atmospheres of the conversion zones of adjacent moving hearths. A drying/preheat zone (12), a conversion zone (13), and optionally a cooling zone (15) are sequentially positioned along each moving hearth (30) in the furnace housing (11).

Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

2012-03-13T23:59:59.000Z

330

System and method for producing metallic iron  

SciTech Connect

A hearth furnace 10 for producing metallic iron material has a furnace housing 11 having a drying/preheat zone 12, a conversion zone 13, a fusion zone 14, and optionally a cooling zone 15, the conversion zone 13 is between the drying/preheat zone 12 and the fusion zone 14. A moving hearth 20 is positioned within the furnace housing 11. A hood or separation barrier 30 within at least a portion of the conversion zone 13, fusion zone 14 or both separates the fusion zone 14 into an upper region and a lower region with the lower region adjacent the hearth 20 and the upper region adjacent the lower region and spaced from the hearth 20. An injector introduces a gaseous reductant into the lower region adjacent the hearth 20. A combustion region may be formed above the hood or separation barrier.

Bleifuss, Rodney L. (Grand Rapids, MN); Englund, David J. (Bovey, MN); Iwasaki, Iwao (Grand Rapids, MN); Fosnacht, Donald R. (Hermantown, MN); Brandon, Mark M. (Charlotte, NC); True, Bradford G. (Charlotte, NC)

2012-01-17T23:59:59.000Z

331

Iron aluminide alloy coatings and joints, and methods of forming  

DOE Patents (OSTI)

Disclosed is a method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: (a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; (b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; (c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600 C to less than the melting point of the lower melting point body; (d) applying pressure on the juxtaposed surfaces; and (e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

Wright, R.N.; Wright, J.K.; Moore, G.A.

1994-09-27T23:59:59.000Z

332

Iron aluminide alloy coatings and joints, and methods of forming  

DOE Patents (OSTI)

A method of joining two bodies together, at least one of the bodies being predominantly composed of metal, the two bodies each having a respective joint surface for joining with the joint surface of the other body, the two bodies having a respective melting point, includes the following steps: a) providing aluminum metal and iron metal on at least one of the joint surfaces of the two bodies; b) after providing the aluminum metal and iron metal on the one joint surface, positioning the joint surfaces of the two bodies in juxtaposition against one another with the aluminum and iron positioned therebetween; c) heating the aluminum and iron on the juxtaposed bodies to a temperature from greater than or equal to 600.degree. C. to less than the melting point of the lower melting point body; d) applying pressure on the juxtaposed surfaces; and e) maintaining the pressure and the temperature for a time period effective to form the aluminum and iron into an iron aluminide alloy joint which bonds the juxtaposed surfaces and correspondingly the two bodies together. The method can also effectively be used to coat a body with an iron aluminide coating.

Wright, Richard N. (Idaho Falls, ID); Wright, Julie K. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID)

1994-01-01T23:59:59.000Z

333

TECHNOLOGY DEVELOPMENT FOR IRON AND COBALT FISCHER-TROPSCH CATALYSTS  

DOE Green Energy (OSTI)

The impact of activation procedure on the phase composition of precipitated iron Fischer-Tropsch (FT) catalysts has been studied. Catalyst samples taken during activation and FT synthesis have been characterized by Moessbauer spectroscopy. Formation of iron carbide is necessary for high FT activity. Hydrogen activation of precipitated iron catalysts results in reduction to predominantly metallic iron and Fe{sub 3}O{sub 4}. Metallic iron is not stable under FT 3 4 conditions and is rapidly converted to {epsilon}{prime}-Fe{sub 2.2}C. Activation with carbon monoxide or syngas 2.2 with low hydrogen partial pressure reduces catalysts to {chi}-Fe{sub 5}C{sub 2} and a small amount of 5 2 superparamagnetic carbide. Exposure to FT conditions partially oxidizes iron carbide to Fe{sub 3}O{sub 4}; however, catalysts promoted with potassium or potassium and copper maintain a constant carbide content and activity after the initial oxidation. An unpromoted iron catalyst which was activated with carbon monoxide to produce 94% {chi}-Fe{sub 5}C{sub 2}, deactivated rapidly as the carbide was oxidized to Fe{sub 3}O{sub 4}. No difference in activity, stability or deactivation rate was found for {chi}-Fe{sub 5}C{sub 2} and {epsilon}{prime}-Fe{sub 2.2}C.

Burtron H. Davis

1999-04-30T23:59:59.000Z

334

Erosion of white cast irons and stellite  

SciTech Connect

The erosion behavior of dual-phase alloys containing large, hard carbides has been investigated. A series of high Cr-Mo white cast irons with a systematic variation of carbide volume fraction (CVF) and powder metallurgy specimens of Stellite 6 were eroded with alumina, crushed quartz and rounded quartz particles. These erodents were chosen because quartz has a hardness between that of the matrix and the Cr-rich carbides, whereas the hardness of alumina is comparable to that of the carbides. In addition, comparison of the results with crushed quartz and alumina allows an evaluation of the effect of particle hardness while the differences between the rounded and crushed quartz results can be attributed to the shape difference. For all erodents and alloys, the dependence of erosion on angle of incidence was weak. With alumina and rounded quartz erodents, the erosion rate increased with increasing CVF, while the reverse was true with crushed quartz. The crushed quartz erodent gave an erosion rate only slightly lower than that of alumina, indicating that the carbide erosion resistance is not a strong function of erodent particle hardness in this range of hardness. Scanning electron microscope (SEM) observations of the eroded surfaces showed that erosion of the highest-CVF white cast iron alloy with alumina or rounded quartz resulted in depression of the large primary carbides, while with crushed quartz many of the carbides protruded above the matrix. The SEM and erosion rate observations show that with crushed quartz the carbides are more erosion resistant than the eutectic matrix and that the carbides therfore contribute to erosion resistance, while with the other erodents the reverse is true. 17 refs., 15 figs., 2 tabs.

Aptekar, S.S.; Kosel, T.H.

1985-01-01T23:59:59.000Z

335

The development of precipitated iron catalysts with improved stability  

DOE Green Energy (OSTI)

Precipitated iron catalysts are expected to be used in the next generation of slurry reactors for the large-scale production of transportation fuels from synthesis gas. These reactors may operate at higher temperatures and lower H {sub 2}: CO ratios relative to the Sasol Arge reactor. The feasibility of iron catalysts has been demonstrated under relatively mild Arge-type conditions but not under the more severe slurry conditions. The goal of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors.

Shah, P.P.

1990-01-01T23:59:59.000Z

336

Iron-carbon compacts and process for making them  

DOE Patents (OSTI)

The present invention includes iron-carbon compacts and a process for making them. The process includes preparing a slurry comprising iron powder, furfuryl alcohol, and a polymerization catalyst for initiating the polymerization of the furfuryl alcohol into a resin, and heating the slurry to convert the alcohol into the resin. The resulting mixture is pressed into a green body and heated to form the iron-carbon compact. The compact can be used as, or machined into, a magnetic flux concentrator for an induction heating apparatus.

Sheinberg, Haskell (Santa Fe, NM)

2000-01-01T23:59:59.000Z

337

Cast B2-phase iron-aluminum alloys with improved fluidity  

DOE Patents (OSTI)

Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

2002-01-01T23:59:59.000Z

338

DOE - Office of Legacy Management -- Knoxville Iron Co - TN 07  

Office of Legacy Management (LM)

Knoxville Iron Co - TN 07 Knoxville Iron Co - TN 07 FUSRAP Considered Sites Site: KNOXVILLE IRON CO. (TN.07 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Knoxville , Tennessee TN.07-1 Evaluation Year: 1994 TN.07-2 TN.07-3 Site Operations: Melted uranium contaminated scrap metal in order to test industrial hygiene procedures in the mid-1950s. TN.07-1 Site Disposition: Eliminated - AEC license TN.07-2 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Limited Quantities of Uranium Contained in Slag Material TN.07-4 Radiological Survey(s): Yes - health and safety monitoring during operations only TN.07-4 Site Status: Eliminated from consideration under FUSRAP Also see Documents Related to KNOXVILLE IRON CO.

339

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the The Iron Spin Transition in the Earth's Lower Mantle The Iron Spin Transition in the Earth's Lower Mantle Print Wednesday, 30 April 2008 00:00 It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

340

The industrial ecology of the iron casting industry  

E-Print Network (OSTI)

Metal casting is an energy and materials intensive manufacturing process, which is an important U.S. industry. This study analyzes iron casting, in particular, for possible improvements that will result in greater efficiencies ...

Jones, Alissa J. (Alissa Jean)

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Method and system for producing metallic iron nuggets  

Science Conference Proceedings (OSTI)

A method and system for producing metallic iron nuggets may include providing multiple layers of agglomerates, such as briquettes, balls and extrusions, of a reducible mixture of reducing material (such as carbonaceous material) and of a reducible iron bearing material (such as iron oxide) on a hearth material layer (such as carbonaceous material) and providing a coarse overlayer of carbonaceous material over at least some of the agglomerates. Heating the agglomerates of reducible mixture to 1425.degree. C. or 1400.degree. C. or 1375.degree. C. results in formation of an intermediate product of one or more metallic iron nuggets, which may have a sulfur content of less than 0.03%, and slag, which may have less than 5% mass MgO, which may have a ratio of percent by weight sulfur in the slag over percent by weight sulfur in the metallic nuggets of at least about 12 or at least about 15.

Iwasaki, Iwao; Kiesel, Richard F.; Englund, David J; Hendrickson, Dave

2012-12-18T23:59:59.000Z

342

LANSCE | Lujan Center | Highlights | Local iron displacements and  

NLE Websites -- All DOE Office Websites (Extended Search)

Local iron displacements and magnetoelastic coupling in a spin-ladder Local iron displacements and magnetoelastic coupling in a spin-ladder compound Hypothesis: Is magnetoelastic coupling in [FeX4]-based materials, an important ingredient in the emergence of superconductivity? Lujan Center: Combined Total Scattering and magnetic structure determination (HIPD-NPDF) The study of local, average and magnetic structure shows the existenceof highly correlated local iron (Fe) displacements in the spin-ladder iron chalcogenide BaFe2Se3. Built of ferromagnetic [Fe4] plaquettes, the magnetic ground state correlates with local displacements of the Fe atoms. Knowledge of these local displacements is essential for properly understanding the electronic structure of these systems. As with the copper oxide superconductors two decades ago, these

343

Percolation Explains How Earth's Iron Core Formed | Stanford Synchrotron  

NLE Websites -- All DOE Office Websites (Extended Search)

Percolation Explains How Earth's Iron Core Formed Percolation Explains How Earth's Iron Core Formed Wednesday, November 27, 2013 The formation of Earth's metallic core, which makes up a third of our planet's mass, represents the most significant differentiation event in Earth's history. Earth's present layered structure with a metallic core and an overlying silicate mantle would have required mechanisms to separate iron alloy from a silicate phase. Percolation of liquid iron alloy moving through a solid silicate matrix (much as water percolates through porous rock, or even coffee grinds) has been proposed as a possible model for core formation (Figure 1). Many previous experimental results have ruled out percolation as a major core formation mechanism for Earth at the relatively lower pressure conditions in the upper mantle, but until now experimental

344

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

NLE Websites -- All DOE Office Websites (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

345

Open Ocean Iron Fertilization for Scientific Study and Carbon Sequestration  

NLE Websites -- All DOE Office Websites (Extended Search)

Ocean Iron Fertilization for Scientific Study and Carbon Sequestration Ocean Iron Fertilization for Scientific Study and Carbon Sequestration K. Coale coale@mlml.calstate.edu (831) 632-4400 Moss Landing Marine Laboratories 8272 Moss Landing Road Moss Landing, California 95039 USA Abstract The trace element iron has been recently shown to play a critical role in nutrient utilization, phytoplankton growth and therefore the uptake of carbon dioxide from the surface waters of the global ocean. Carbon fixation in the surface waters, via phytoplankton growth, shifts the ocean/atmosphere exchange equilibrium for carbon dioxide. As a result, levels of atmospheric carbon dioxide (a greenhouse gas) and iron flux to the oceans have been linked to climate change (glacial to interglacial transitions). These recent findings have led some to suggest that large scale

346

Verification of Steelmaking Slags Iron Content Final Technical Progress Report  

Science Conference Proceedings (OSTI)

The steel industry in the United States generates about 30 million tons of by-products each year, including 6 million tons of desulfurization and BOF/BOP slag. The recycling of BF (blast furnace) slag has made significant progress in past years with much of the material being utilized as construction aggregate and in cementitious applications. However, the recycling of desulfurization and BOF/BOP slags still faces many technical, economic, and environmental challenges. Previous efforts have focused on in-plant recycling of the by-products, achieving only limited success. As a result, large amounts of by-products of various qualities have been stockpiled at steel mills or disposed into landfills. After more than 50 years of stockpiling and landfilling, available mill site space has diminished and environmental constraints have increased. The prospect of conventionally landfilling of the material is a high cost option, a waste of true national resources, and an eternal material liability issue. The research effort has demonstrated that major inroads have been made in establishing the viability of recycling and reuse of the steelmaking slags. The research identified key components in the slags, developed technologies to separate the iron units and produce marketable products from the separation processes. Three products are generated from the technology developed in this research, including a high grade iron product containing about 90%Fe, a medium grade iron product containing about 60% Fe, and a low grade iron product containing less than 10% Fe. The high grade iron product contains primarily metallic iron and can be marketed as a replacement of pig iron or DRI (Direct Reduced Iron) for steel mills. The medium grade iron product contains both iron oxide and metallic iron and can be utilized as a substitute for the iron ore in the blast furnace. The low grade iron product is rich in calcium, magnesium and iron oxides and silicates. It has a sufficient lime value and can be utilized for acid mine drainage treatment. Economic analysis from this research demonstrates that the results are favorable. The strong demand and the increase of price of the DRI and pig iron in recent years are particularly beneficial to the economics. The favorable economics has brought commercial interests. ICAN Global has obtained license agreement on the technology from Michigan Tech. This right was later transferred to the Westwood Land, Inc. A demonstration pilot plant is under construction to evaluate the technology. Steel industry will benefit from the new supply of the iron units once the commercial plants are constructed. Environmental benefits to the public and the steel industry will be tremendous. Not only the old piles of the slag will be removed, but also the federal responsible abandoned mines from the old mining activities can be remediated with the favorable product generated from the process. Cost can be reduced and there will be no lime required, which can avoid the release of carbon dioxide from lime production process.

J.Y. Hwang

2006-10-04T23:59:59.000Z

347

Stability and Reactivity of Iron Sulfide Films in Sour Environments  

Science Conference Proceedings (OSTI)

Abstract Scope, Iron sulfide scales form on steels in the presence of H2S, notably in the extreme environments that exist in the oil and gas fields. Our research...

348

A BP neural network predictor model for desulfurizing molten iron  

Science Conference Proceedings (OSTI)

Desulfurization of molten iron is one of the stages of steel production process. A back-propagation (BP) artificial neural network (ANN) model is developed to predict the operation parameters for desulfurization process in this paper. The primary objective ...

Zhijun Rong; Binbin Dan; Jiangang Yi

2005-07-01T23:59:59.000Z

349

Synthesis of Monolithic Iron Incorporated Silica Aerogels by Ambient ...  

Science Conference Proceedings (OSTI)

With the Fe to Si molar ratio not exceeding 0.10, the bulk density of iron incorporated silica aerogels increased to 0.55g/cm3, while the porosity reduced to 76%...

350

Production of Molybdenum Containing Iron Based Alloys via ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

351

Reduction and Separation of High Iron Content Manganese Ore and ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

352

CFD Model Development for Gaseous Reduction of Iron Ore Fines ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

353

NOx Reduction by Sintering Flue Gas Circulation for Iron Ores  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

354

The relationship between iron and nitrogen fixation in Trichodesmium spp.  

E-Print Network (OSTI)

Trichodesmium spp. are considered the dominant nitrogen (N) fixing cyanobacteria in tropical and subtropical oceans, regimes frequently characterized by low iron (Fe). Limited information exists about what levels of Fe ...

Chappell, Phoebe Dreux

2009-01-01T23:59:59.000Z

355

Process for removing technetium from iron and other metals  

DOE Patents (OSTI)

A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

Leitnaker, J.M.; Trowbridge, L.D.

1999-03-23T23:59:59.000Z

356

Process for removing technetium from iron and other metals  

DOE Patents (OSTI)

A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag.

Leitnaker, James M. (Kingston, TN); Trowbridge, Lee D. (Oak Ridge, TN)

1999-01-01T23:59:59.000Z

357

Iron Cycling and Redox Evolution in the Precambrian  

E-Print Network (OSTI)

from neodymium isotopes. Journal of Geology 105, 121-129.iron isotope fractionation in nature. Geology 29, 699-702.from neodymium isotopes. Journal of Geology 105, 121-129.

Planavsky, Noah John

2012-01-01T23:59:59.000Z

358

Automatic control in the iron and steel industry  

Science Conference Proceedings (OSTI)

Basic iron and steel production processes, starting in the blast furnace and followed by steelmaking and rolling procedures, have not been altered greatly, although there have been modifying developments in individual processes, such as a basic oxygen ...

T. Isobe

1970-01-01T23:59:59.000Z

359

Energy intensity in China's iron and steel sector  

E-Print Network (OSTI)

In this study, I examine the spatial and economic factors that influence energy intensity in China's iron and steel sector, namely industrial value added, renovation investment, coke consumption, and local coke supply. ...

Xu, Jingsi, M.C.P. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

360

Polymer-coated iron oxide nanoparticles for medical imaging  

E-Print Network (OSTI)

One of the most versatile and safe materials used in medicine are polymer-coated iron oxide nanoparticles. This dissertation describes several formulations for in vivo imaging applications. The paramagnetic polymer-coated ...

Chen, Suelin, Ph.D. Massachusetts Institute of Technology

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of Charge Dosage Rate Title Arsenic Removal from Groundwater Using Iron Electrocoagulation: Effect of Charge Dosage Rate Publication Type Journal Article Refereed Designation Refereed LBNL Report Number LBNL-6221E Year of Publication 2013 Authors Amrose, Susan, Ashok J. Gadgil, Venkat Srinivasan, Kristin Kowolik, Marc Muller, Jessica Huang, and Robert Kostecki Journal Joournal of Environmental Science and Health, Part A: Toxic/Hazardous Substances and Environmental Engineering Volume 48 Issue 9 Pagination 1019-1030 Date Published 04/2013 Keywords arsenic, bangladesh, Cambodia, dosage rate, electrocoagulation, india, water treatment Abstract We demonstrate that electrocoagulation (EC) using iron electrodes can reduce arsenic below 10 μg/L in synthetic Bangladesh groundwater and in real groundwater from Bangladesh and Cambodia while investigating the effect of operating parameters that are often overlooked, such as charge dosage rate. We measure arsenic removal performance

362

Iron-oxide catalyzed silicon photoanode for water splitting  

E-Print Network (OSTI)

This thesis presents an integrated study of high efficiency photoanodes for water splitting using silicon and iron-oxide. The fundamental limitations of silicon to water splitting applications were overcome by an ultrathin ...

Jun, Kimin

2011-01-01T23:59:59.000Z

363

Spectroscopic Equilibrium of Iron in Metal-Rich Dwarfs  

E-Print Network (OSTI)

We analyze twenty five nearby metal-rich G and late-F dwarfs in order to verify whether the spectroscopic equilibrium (LTE) of iron lines satisfy the observational constraints imposed by the Infrared Flux Method (angular diameters) and Hipparcos parallaxes. The atmospheric parameters derived from iron lines (assuming LTE and employing 1D Kurucz model atmospheres) do not satisfy simultaneously both observational constraints, probably because classical modeling fails to reproduce the detailed line formation of FeI lines.

Jorge Melendez; Ivan Ramirez

2004-09-14T23:59:59.000Z

364

In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation  

E-Print Network (OSTI)

Iron oxide-bearing minerals have long been recognized as an effective reactive media for arsenic-contaminated groundwater remediation. This research aimed to develop a technique that could facilitate in situ oxidative precipitation of Fe3+ in a soil (sand) media for generating a subsurface iron oxide-based reactive barrier that could immobilize arsenic (As) and other dissolved metals in groundwater. A simple in situ arsenic treatment process was successfully developed for treating contaminated rural groundwater using iron oxide-coated sand (IOCS). Using imbibition flow, the system facilitated the dispersive transport of ferrous iron (Fe2+) and oxidant solutions in porous sand to generate an overlaying blanket where the Fe2+ was oxidized and precipitated onto the surface as ferric oxide. The iron oxide (FeOx) emplacement process was significantly affected by (1) the initial surface area and surface-bound iron content of the sand, (2) the pH and solubility of the coating reagents, (3) the stability of the oxidant solution, and (4) the chemical injection schedule. In contrast to conventional excavate-and-fill treatment technologies, this technique could be used to in situ replace a fresh iron oxide blanket on the sand and rejuvenate its treatment capacity for additional arsenic removal. Several bench-scale experiments revealed that the resultant IOCS could treat arsenic-laden groundwater for extended periods of time before approaching its effective life cycle. The adsorption capacity for As(III) and As(V) was influenced by (1) the amount of iron oxide accumulated on the sand surface, (2) the system pH, and (3) competition for adsorption sites from other groundwater constituents such as silicon (Si) and total dissolved solids (TDS). Although the IOCS could be replenished several times before exhaustion, the life cycle of the FeOx reactive barrier may be limited by the gradual loss of hydraulic conductivity induced by the imminent reduction of pore space over time.

Abia, Thomas Sunday

2011-12-01T23:59:59.000Z

365

Super-iron Nanoparticles with Facile Cathodic Charge Transfer  

Science Conference Proceedings (OSTI)

Super-irons contain the + 6 valence state of iron. One advantage of this is that it provides a multiple electron opportunity to store additional battery charge. A decrease of particle size from the micrometer to the nanometer domain provides a higher surface area to volume ratio, and opportunity to facilitate charge transfer, and improve the power, voltage and depth of discharge of cathodes made from such salts. However, super-iron salts are fragile, readily reduced to the ferric state, with both heat and contact with water, and little is known of the resultant passivating and non-passivating ferric oxide products. A pathway to decrease the super-iron particle size to the nano-domain is introduced, which overcomes this fragility, and retains the battery capacity advantage of their Fe(VI) valence state. Time and power controlled mechanosynthesis, through less aggressive, dry ball milling, leads to facile charge transfer of super-iron nanoparticles. Ex-situ X-ray Absorption Spectroscopy is used to explore the oxidation state and structure of these iron oxides during discharge and shows the significant change in stability of the ferrate structure to lower oxidation state when the particle size is in the nano-domain.

M Farmand; D Jiang; B Wang; S Ghosh; D Ramaker; S Licht

2011-12-31T23:59:59.000Z

366

Mesoscale Benchmark Demonstration Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing  

SciTech Connect

A study was conducted to evaluate the capabilities of different numerical methods used to represent microstructure behavior at the mesoscale for irradiated material using an idealized benchmark problem. The purpose of the mesoscale benchmark problem was to provide a common basis to assess several mesoscale methods with the objective of identifying the strengths and areas of improvement in the predictive modeling of microstructure evolution. In this work, mesoscale models (phase-field, Potts, and kinetic Monte Carlo) developed by PNNL, INL, SNL, and ORNL were used to calculate the evolution kinetics of intra-granular fission gas bubbles in UO2 fuel under post-irradiation thermal annealing conditions. The benchmark problem was constructed to include important microstructural evolution mechanisms on the kinetics of intra-granular fission gas bubble behavior such as the atomic diffusion of Xe atoms, U vacancies, and O vacancies, the effect of vacancy capture and emission from defects, and the elastic interaction of non-equilibrium gas bubbles. An idealized set of assumptions was imposed on the benchmark problem to simplify the mechanisms considered. The capability and numerical efficiency of different models are compared against selected experimental and simulation results. These comparisons find that the phase-field methods, by the nature of the free energy formulation, are able to represent a larger subset of the mechanisms influencing the intra-granular bubble growth and coarsening mechanisms in the idealized benchmark problem as compared to the Potts and kinetic Monte Carlo methods. It is recognized that the mesoscale benchmark problem as formulated does not specifically highlight the strengths of the discrete particle modeling used in the Potts and kinetic Monte Carlo methods. Future efforts are recommended to construct increasingly more complex mesoscale benchmark problems to further verify and validate the predictive capabilities of the mesoscale modeling methods used in this study.

Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert; Gao, Fei; Sun, Xin; Tonks, Michael; Biner, Bullent; Millet, Paul; Tikare, Veena; Radhakrishnan, Balasubramaniam; Andersson , David

2012-04-11T23:59:59.000Z

367

A classical approach in simple nuclear fusion reaction {sub 1}H{sup 2}+{sub 1}H{sup 3} using two-dimension granular molecular dynamics model  

Science Conference Proceedings (OSTI)

Molecular dynamics in 2-D accompanied by granular model provides an opportunity to investigate binding between nuclei particles and its properties that arises during collision in a fusion reaction. A fully classical approach is used to observe the influence of initial angle of nucleus orientation to the product yielded by the reaction. As an example, a simplest fusion reaction between {sub 1}H{sup 2} and {sub 1}H{sup 3} is observed. Several products of the fusion reaction have been obtained, even the unreported ones, including temporary {sub 2}He{sup 4} nucleus.

Viridi, S.; Kurniadi, R.; Waris, A.; Perkasa, Y. S. [Nuclear Physics and Biophysics Research Division, Institut Teknologi Bandung, Bandung 40132 (Indonesia); Doctoral Program in Physics, Institut Teknologi Bandung, Bandung 40132 Physics Department, Universitas Islam Negeri Sunan Gunung Djati, Bandung 40614 (Indonesia)

2012-06-06T23:59:59.000Z

368

Morphological development of oxide-sulfide scales on iron and iron-manganese alloys  

Science Conference Proceedings (OSTI)

Pure iron and alloys containing 2, 15, 25, and 50 wt.% manganese have been reacted at 1073 K in controlled gas atmospheres of SO/sub 2/-CO/sub 2/-CO-N/sub 2/. Equilibrium gas compositions were such that (1) FeS was stable but not FeO, or (2) both FeS and FeO were stable, or (3) FeO was stable but not FeS; in all cases, both MnS and MnO were stable. Under all reaction conditions, pure iron corroded to produce both sulfide and oxide. The resultant scale morphologies were consistent with local solid-gas equilibrium for the case in which both oxide and sulfide were stable but in the other cases indicated that equilibrium was not achieved and that direct reaction with SO/sub 2/(g) was responsible for corrosion. Additions of manganese did not greatly alter the scale morphologies. Under reaction conditions that were oxidizing and sulfidizing, very high levels of manganese were required to reduce the corrosion rate. On the other hand, relatively low levels had a beneficial effect both when FeO but not FeS was thermodynamically stable and similarly when FeS but not FeO was stable.

McAdam, G.; Young, D.J.

1987-10-01T23:59:59.000Z

369

Microstructural Characterization of Nodular Ductile Iron  

SciTech Connect

The objective of this study is to quantify the graphite particle phase in nodular ductile iron (NDI). This study provides the basis for initializing microstructure in direct numerical simulations, as part of developing microstructure-fracture response models. The work presented here is a subset of a PhD dissertation on spall fracture in NDI. NDI is an ideal material for studying the influence of microstructure on ductile fracture because it contains a readily identifiable second-phase particle population, embedded in a ductile metallic matrix, which serves as primary void nucleation sites. Nucleated voids grow and coalesce under continued tensile loading, as part of the micromechanisms of ductile fracture, and lead to macroscopic failure. For this study, we used 2D optical microscopy and quantitative metallography relationships to characterize the volume fraction, size distribution, nearest-neighbor distance, and other higher-order metrics of the graphite particle phase. We found that the volume fraction was {Phi} = 0.115, the average particle diameter was d{sub avg} = 25.9 {mu}m, the Weibull shape and scaling parameters were {beta} = 1.8 and {eta} = 29.1 {mu}m, respectively, the (first) nearest neighbor distance was L{sub nn} = 32.4 {mu}m, the exponential coefficients for volume fraction fluctuations was A{sub {Phi}} = 1.89 and B{sub {Phi}} = -0.59, respectively. Based on reaching a coefficient-of-variation (COV) of 0.01, the representative volume element (RVE) size was determined to be 8.9L{sub nn} (288 {mu}m).

Springer, H K

2012-01-03T23:59:59.000Z

370

Insights into the Structure and Metabolic Function of Microbes That Shape Pelagic Iron-Rich Aggregates ( Iron Snow )  

SciTech Connect

Metaproteomics combined with total nucleic acid-based methods aided in deciphering the roles of microorganisms in the formation and transformation of iron-rich macroscopic aggregates (iron snow) formed in the redoxcline of an acidic lignite mine lake. Iron snow had high total bacterial 16S rRNA gene copies, with 2 x 109 copies g (dry wt)-1 in the acidic (pH 3.5) central lake basin and 4 x 1010 copies g (dry wt)-1 in the less acidic (pH 5.5) northern lake basin. Active microbial communities in the central basin were dominated by Alphaproteobacteria (36.6%) and Actinobacteria (21.4%), and by Betaproteobacteria (36.2%) in the northern basin. Microbial Fe-cycling appeared to be the dominant metabolism in the schwertmannite-rich iron snow, because cloning and qPCR assigned up to 61% of active bacteria as Fe-cycling bacteria (FeB). Metaproteomics revealed 70 unique proteins from central basin iron snow and 283 unique proteins from 43 genera from northern basin. Protein identification provided a glimpse into in situ processes, such as primary production, motility, metabolism of acidophilic FeB, and survival strategies of neutrophilic FeB. Expression of carboxysome shell proteins and RubisCO indicated active CO2 fixation by Fe(II) oxidizers. Flagellar proteins from heterotrophs indicated their activity to reach and attach surfaces. Gas vesicle proteins related to CO2-fixing Chlorobium suggested that microbes could influence iron snow sinking. We suggest that iron snow formed by autotrophs in the redoxcline acts as a microbial parachute, since it is colonized by motile heterotrophs during sinking which start to dissolve schwertmannite.

Lu, S [Friedrich Schiller University Jena, Jena Germany; Chourey, Karuna [ORNL; REICHE, M [Friedrich Schiller University Jena, Jena Germany; Nietzsche, S [Friedrich Schiller University Jena, Jena Germany; Shah, Manesh B [ORNL; Hettich, Robert {Bob} L [ORNL; Kusel, K [Friedrich Schiller University Jena, Jena Germany

2013-01-01T23:59:59.000Z

371

A fixed granular-bed sorber for measurement and control of alkali vapors in PFBC (pressurized fluidized-bed combustion)  

SciTech Connect

Alkali vapors (Na and K) in the hot flue gas from the pressurized fluidized-bed combustion (PFBC) of coal could cause corrosion problems with the gas turbine blades. In a laboratory-scale PFBC test with Beulah lignite, a fixed granular bed of activated bauxite sorbent was used to demonstrate its capability for measuring and controlling alkali vapors in the PFBC flue gas. The Beulah lignite was combusted in a bed of Tymochtee dolomite at bed temperatures ranging from 850 to 875{degrees}C and a system pressure of 9.2 atm absolute. The time-averaged concentration of sodium vapor in the PFBC flue gas was determined from the analysis of two identical beds of activated bauxite and found to be 1.42 and 1.50 ppmW. The potassium vapor concentration was determined to be 0.10 ppmW. The sodium material balance showed that only 0.24% of the total sodium in the lignite was released as vapor species in the PFBC flue gas. This results in an average of 1.56 ppmW alkali vapors in the PFBC flue gas. This average is more than 1.5 orders of magnitude greater than the currently suggested alkali specification limit of 0.024 ppm for an industrial gas turbine. The adsorption data obtained with the activated bauxite beds were also analyzed mathematically by use of a LUB (length of unused bed)/equilibrium section concept. Analytical results showed that the length of the bed, L{sub o} in centimeters, relates to the break through time, {theta}{sub b} in hours, for the alkali vapor to break through the bed as follows: L{sub o} = 33.02 + 1.99 {theta}{sub b}. This formula provides useful information for the engineering design of fixed-bed activated bauxite sorbers for the measurement and control of alkali vapors in PFBC flue gas. 26 refs., 4 figs., 4 tabs.

Lee, S.H.D.; Swift, W.M.

1990-01-01T23:59:59.000Z

372

Constraining the initial state granularity with bulk observables in Au+Au collisions at $\\sqrt{s_{\\rm NN}}=200$ GeV  

E-Print Network (OSTI)

In this paper we conduct a systematic study of the granularity of the initial state of hot and dense QCD matter produced in ultra-relativistic heavy-ion collisions and its influence on bulk observables like particle yields, $m_T$ spectra and elliptic flow. For our investigation we use a hybrid transport model, based on (3+1)d hydrodynamics and a microscopic Boltzmann transport approach. The initial conditions are generated by a non-equilibrium hadronic transport approach and the size of their fluctuations can be adjusted by defining a Gaussian smoothing parameter $\\sigma$. The dependence of the hydrodynamic evolution on the choices of $\\sigma$ and $t_{start}$ is explored by means of a Gaussian emulator. To generate particle yields and elliptic flow that are compatible with experimental data the initial state parameters are constrained to be $\\sigma=1$ fm and $t_{\\rm start}=0.5$ fm. In addition, the influence of changes in the equation of state is studied and the results of our event-by-event calculations are compared to a calculation with averaged initial conditions. We conclude that even though the initial state parameters can be constrained by yields and elliptic flow, the granularity needs to be constrained by other correlation and fluctuation observables.

Hannah Petersen; Christopher Coleman-Smith; Steffen A. Bass; Robert Wolpert

2010-12-21T23:59:59.000Z

373

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network (OSTI)

Potentials in the Iron and steel Industry in China. Reportfor the U.S. Iron and Steel Industry. An ENERGY STAR Guidein the U.S. Iron and Steel Industry. Report LBNL-41724.

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

374

Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network (OSTI)

scrap steel, pig iron, or direct reduced iron (DRI) using anthe production of direct reduced iron (DRI). DRI is producedDirect current Direct reduced iron Electric arc furnace

Worrell, Ernst

2011-01-01T23:59:59.000Z

375

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the Earth's Lower Mantle Print The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

376

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the Earth's Lower Mantle Print The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

377

The Iron Spin Transition in the Earth's Lower Mantle  

NLE Websites -- All DOE Office Websites (Extended Search)

The Iron Spin Transition in the Earth's Lower Mantle Print The Iron Spin Transition in the Earth's Lower Mantle Print It is now known that the iron present in minerals of the lower mantle of the Earth undergoes a pressure-induced transition with pairing of the spins of its 3d electrons. A team from the University of California, Berkeley, Tel Aviv University, and Lawrence Livermore National Laboratory has used x-ray diffraction at very high pressure to investigate the effects of this transition on the elastic properties of magnesiowüstite (Mg1-xFex)O, the second most abundant mineral in the Earth's lower mantle. The new results suggest that the effect of the spin-pairing transition on magnesiowüstite can be large enough to require a partial revision of the most accepted model of the lower mantle composition.

378

Mechanical Characterization of Nodular Ductile Iron  

SciTech Connect

The objective of this study is to characterize the strength and fracture response of nodular ductile iron (NDI) and its underlying ferritic matrix phase. Quasistatic and split Hopkinson pressure bar (SHPB) compression tests were performed on NDI and a model material for the NDI matrix phase (Fe-Si alloy). Smooth and notch round bar (NRB) samples were loaded in tension until fracture to determine strain-at-failure with varying stress triaxiality. Multiple tests were performed on each small and large smooth bar samples to obtain fracture statistics with sample size. Fracture statistics are important for initializing simulations of fragmentation events. Johnson-Cook strength models were developed for the NDI and the Fe-Si alloy. NDI strength model parameters are: A = 525 MPa, B = 650 MPa, n = 0.6, and C = 0.0205. The average SHPB experimental strain-rate of 2312/s was used for the reference strain-rate in this model. Fe-Si alloy strength model parameters are: A=560 MPa, B = 625 MPa, n = 0.5, and C = 0.02. The average SHPB experimental strain-rate of 2850/s was used for the reference strain-rate in this model. A Johnson-Cook failure model was developed for NDI with model parameters: D{sub 1} = 0.029, D{sub 2} = 0.44, D{sub 3} = -1.5, and D{sub 4} = D{sub 5} = 0. An exponential relationship was developed for the elongation-at-failure statistics as a function of length-scale with model parameters: S{sub f1} = 0.108, S{sub f2} = -0.00169, and L{sub m} = 32.4 {mu}m. NDI strength and failure models, including failure statistics, will be used in continuum-scale simulations of explosively-driven ring fragmentation. The Fe-Si alloy strength model will be used in mesoscale simulations of spall fracture in NDI, where the NDI matrix phase is captured explicitly.

Springer, H K

2012-01-03T23:59:59.000Z

379

Gas Diffusion in Metals: Fundamental Study of Helium-Point Defect Interactions in Iron and Kinetics of Hydrogen Desorption from Zirconium Hydride  

E-Print Network (OSTI)

Steel irradiated in HFIR, as reproduced from Ref. [irons placed in HFIR. .. 97 Table 6-iron in HFIR. .. 102

Hu, Xunxiang

2013-01-01T23:59:59.000Z

380

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network (OSTI)

electricity and fuel prices differ between industries andelectricity and fuel efficiency improvements in the iron and steel industryprice of electricity paid by the iron and steel industry in

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Characterization of temperature profile in furnace and solubility of iron in silicon  

E-Print Network (OSTI)

A better understanding of the behavior of impurities, such as iron, in silicon can lead to increases in solar cell efficiency. The purpose of this thesis was to study the behavior of iron in silicon via three sub-tasks: ...

Modi, Vrajesh Y

2011-01-01T23:59:59.000Z

382

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Cisco IronPort Web Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web Email Security Appliance Sophos Anti-Virus Multiple...

383

Interactions of Fe(II) with the iron oxidizing bacterium Rhodopseudomonas palustris TIE-1  

E-Print Network (OSTI)

Microbial anaerobic iron oxidation has long been of interest to biologists and geologists, both as a possible mechanism for the creation of banded iron formations before the rise of oxygen, and as a model system for organisms ...

Bird, Lina J. (Lina Joana)

2013-01-01T23:59:59.000Z

384

New trends in industrial energy efficiency in the Mexico iron and steel industry  

E-Print Network (OSTI)

de Ingeniera, U N A M . , Mexico Energy Analysis Program atIndustrial Energy Efficiency in the Mexico: Iron and Steelenergy consumption of the iron and steel industry is the feedstock. In Mexico,

Ozawa, Leticia; Martin, Nathan; Worrell, Ernst; Price, Lynn; Sheinbaum, Claudia

1999-01-01T23:59:59.000Z

385

Recovery of iron oxide from coal fly ash  

DOE Patents (OSTI)

A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

Dobbins, Michael S. (Ames, IA); Murtha, Marlyn J. (Ames, IA)

1983-05-31T23:59:59.000Z

386

Electrolytic photodissociation of chemical compounds by iron oxide photochemical diodes  

DOE Patents (OSTI)

Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor photochemical diode having visible light as its sole source of energy. The photochemical diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

Somorjai, Gabor A. (Berkeley, CA); Leygraf, Christofer H. (Berkeley, CA)

1985-01-01T23:59:59.000Z

387

Electrolytic photodissociation of chemical compounds by iron oxide electrodes  

DOE Patents (OSTI)

Chemical compounds can be dissociated by contacting the same with a p/n type semi-conductor diode having visible light as its sole source of energy. The diode consists of low cost, readily available materials, specifically polycrystalline iron oxide doped with silicon in the case of the n-type semi-conductor electrode, and polycrystalline iron oxide doped with magnesium in the case of the p-type electrode. So long as the light source has an energy greater than 2.2 electron volts, no added energy source is needed to achieve dissociation.

Somorjai, Gabor A. (Berkeley, CA); Leygraf, Christofer H. (Berkeley, CA)

1984-01-01T23:59:59.000Z

388

Influence of Iron Redox Transformations on Plutonium Sorption to Sediments  

SciTech Connect

Plutonium subsurface mobility is primarily controlled by its oxidation state, which in turn is loosely coupled to the oxidation state of iron in the system. Experiments were conducted to examine the effect of sediment iron mineral composition and oxidation state on plutonium sorption and oxidation state. A pH 6.3 vadose zone sediment containing iron oxides and iron-containing phyllosilicates was treated with various complexants (ammonium oxalate) and reductants (dithionite-citrate-bicarbonate) to selectively leach and/or reduce iron oxide and phyllosilicate phases. Mssbauer spectroscopy was used to identify initial iron mineral composition of the sediment and monitor dissolution and reduction of iron oxides. Sorption of Pu(V) was monitored over one week for each of six treated sediment fractions. Plutonium oxidation state speciation in the aqueous and solid phases was monitored using solvent extraction, coprecipitation, and XANES. Mssbauer spectroscopy showed that the sediment contained 25-30% hematite, 60-65% Al-goethite, and <10%Fe(III) in phyllosilicate; there was no detectable Fe(II). Upon reduction with a strong chemical reductant (dithionite-citrate buffer, DCB), much of the hematite and goethite disappeared and the Fe in the phyllosilicate reduced to Fe(II). The rate of sorption was found to correlate with the 1 fraction of Fe(II) remaining within each treated sediment phase. Pu(V) was the only oxidation state measured in the aqueous phase, irrespective of treatment, whereas Pu(IV) and much smaller amounts of Pu(V) and Pu(VI) were measured in the solid phase. Surface-mediated reduction of Pu(V) to Pu(IV) occurred in treated and untreated sediment samples; Pu(V) remained on untreated sediment surface for two days before reducing to Pu(IV). Similar to the sorption kinetics, the reduction rate was correlated with sediment Fe(II) concentration. The correlation between Fe(II) concentrations and Pu(V) reduction demonstrates the potential impact of changing iron mineralogy on plutonium subsurface transport through redox transition areas. These findings should influence the conceptual models of long-term stewardship of Pu contaminated sites that have fluctuating redox conditions, such as vadose zones or riparian zones.

Hixon, Amy E.; Hu, Yung-Jin; Kaplan, Daniel I.; Kukkadapu, Ravi K.; Nitsche, Heino; Qafoku, Odeta; Powell, Brian A.

2010-10-01T23:59:59.000Z

389

Granularity Jerry R. Hobbs  

E-Print Network (OSTI)

thereby sacri#12;ce the tight connection between our local theory and the overarching global theory, but sand is sand only down to the size of a grain of sand, the grain size associated with succotash

Hobbs, Jerry R.

390

A modeling approach for iron concentration in sand filtration effluent using adaptive neuro-fuzzy model  

Science Conference Proceedings (OSTI)

Effluent iron concentration is an important water quality criterion used for the assessment of the performance of rapid sand filters, in addition to other criteria. This study deals with the prediction of effluent iron concentrations by adaptive neuro-fuzzy ... Keywords: ANFIS, Effluent iron concentration, Modeling, Sand filtration

Mehmet akmakci; Cumali Kinaci; Mahmut Bayramo?lu; Y?lmaz Yildirim

2010-03-01T23:59:59.000Z

391

Porous iron and ferric oxide pellets for hydrogen storage: texture and transport characteristics  

Science Conference Proceedings (OSTI)

Materials for hydrogen storage based on the recovery reduction of Fe3O4 to iron and back iron oxidation to Fe3O4 by water vapor were studied. The preparation conditions for cylindrical pellets from ferric oxide/aluminium ... Keywords: hydrogen storage, inverse gas chromatography, steam iron process, transport parameters

Karel Soukup; Jan Rogut; Jacek Grabowski; Marian Wiatowski; Magdalena Ludwik-Parda?a; Petr Schneider; Olga olcov

2010-11-01T23:59:59.000Z

392

Abundance Analysis of Planetary Host Stars I. Differential Iron Abundances  

E-Print Network (OSTI)

We present atmospheric parameters and iron abundances derived from high-resolution spectra for three samples of dwarf stars: stars which are known to host close-in giant planets (CGP), stars for which radial velocity data exclude the presence of a close-in giant planetary companion (no-CGP), as well as a random sample of dwarfs with a spectral type and magnitude distribution similar to that of the planetary host stars (control). All stars have been observed with the same instrument and have been analyzed using the same model atmospheres, atomic data and equivalent width modeling program. Abundances have been derived differentially to the Sun, using a solar spectrum obtained with Callisto as the reflector with the same instrumentation. We find that the iron abundances of CGP dwarfs are on average by 0.22 dex greater than that of no-CGP dwarfs. The iron abundance distributions of both the CGP and no-CGP dwarfs are different than that of the control dwarfs, while the combined iron abundances have a distribution which is very similar to that of the control dwarfs. All four samples (CGP, no-CGP, combined, control) have different effective temperature distributions. We show that metal enrichment occurs only for CGP dwarfs with temperatures just below solar and approximately 300 K higher than solar, whereas the abundance difference is insignificant at Teff around 6000 K.

U. Heiter; R. E. Luck

2003-07-16T23:59:59.000Z

393

Survey of Iron and Nickel Concentrations in PWR Primary Coolant  

Science Conference Proceedings (OSTI)

The concentrations of iron and nickel corrosion products in primary coolant water were measured at eleven different pressurized water reactors. Two reactors experienced anomalies in the axial power distribution during the cycles that were sampled. The axial power distribution anomalies appeared to be associated with high-coolant nickel concentrations early in the fuel cycle.

2001-07-27T23:59:59.000Z

394

Iron Recovery from Copper Slag through Oxidation-magnetic ...  

Science Conference Proceedings (OSTI)

Recovery of iron from the copper slag is very essential not only for recycling the valuable ... Characterization of High-arsenic Sludge in Copper Metallurgy Plant ... Characterization of Waste from Ornamental Stones for Use in Mortar ... Effect of Friction Stir Welding Speed and Post Weld Heat Treatment on the Microstructure

395

Oxide Dispersion Strengthened Iron Aluminide by CVD Coated Powders  

SciTech Connect

This I &I Category2 program developed chemical vapor deposition (CVD) of iron, aluminum and aluminum oxide coated iron powders and the availability of high temperature oxidation, corrosion and erosion resistant coating for future power generation equipment and can be used for retrofitting existing fossil-fired power plant equipment. This coating will provide enhanced life and performance of Coal-Fired Boilers components such as fire side corrosion on the outer diameter (OD) of the water wall and superheater tubing as well as on the inner diameter (ID) and OD of larger diameter headers. The program also developed a manufacturing route for readily available thermal spray powders for iron aluminide coating and fabrication of net shape component by powder metallurgy route using this CVD coated powders. This coating can also be applid on jet engine compressor blade and housing, industrial heat treating furnace fixtures, magnetic electronic parts, heating element, piping and tubing for fossil energy application and automotive application, chemical processing equipment , heat exchanger, and structural member of aircraft. The program also resulted in developing a new fabrication route of thermal spray coating and oxide dispersion strengthened (ODS) iron aluminide composites enabling more precise control over material microstructures.

Asit Biswas Andrew J. Sherman

2006-09-25T23:59:59.000Z

396

Radiofrequency characterization of polydimethylsiloxane - iron oxide based nanocomposites  

Science Conference Proceedings (OSTI)

Colloidal iron oxide nanoparticles with diameters ranging from 15+/-1nm up to 29+/-3nm are used as pure dielectric fillers for nanoparticles-doped nanocomposites. We show that their superparamagnetic behavior allows them to increase the real dielectric ... Keywords: Magnetic nanoparticles, Nanocomposite, Polydimethylsiloxane, Radiofrequency

Ferruccio Pisanello, Rosa De Paolis, Daniela Lorenzo, Simone Nitti, Giuseppina Monti, Despina Fragouli, Athanassia Athanassiou, Liberato Manna, Luciano Tarricone, Massimo De Vittorio, Luigi Martiradonna

2013-11-01T23:59:59.000Z

397

Iron Biomineralization: Implications on the Fate of Arsenic in Landfills  

E-Print Network (OSTI)

these arsenic-bearing solid residuals (ABSR) pass the Toxicity Characteristic Leaching Procedure (TCLP in our laboratory as well as other labs, has shown that the TCLP greatly underestimates the ABSR leaching concentrations of As. Iron reduction led to arsenic release into solution, where arsenic was reduced. #12;Figure

Cushing, Jim. M.

398

An elastoplastic framework for granular materials becoming cohesive through mechanical densification. Part II - the formulation of elastoplastic coupling at large strain  

E-Print Network (OSTI)

The two key phenomena occurring in the process of ceramic powder compaction are the progressive gain in cohesion and the increase of elastic stiffness, both related to the development of plastic deformation. The latter effect is an example of `elastoplastic coupling', in which the plastic flow affects the elastic properties of the material, and has been so far considered only within the framework of small strain assumption (mainly to describe elastic degradation in rock-like materials), so that it remains completely unexplored for large strain. Therefore, a new finite strain generalization of elastoplastic coupling theory is given to describe the mechanical behaviour of materials evolving from a granular to a dense state. The correct account of elastoplastic coupling and of the specific characteristics of materials evolving from a loose to a dense state (for instance, nonlinear --or linear-- dependence of the elastic part of the deformation on the forming pressure in the granular --or dense-- state) makes the use of existing large strain formulations awkward, if even possible. Therfore, first, we have resorted to a very general setting allowing general transformations between work-conjugate stress and strain measures; second, we have introduced the multiplicative decomposition of the deformation gradient and, third, employing isotropy and hyperelasticity of elastic response, we have obtained a relation between the Biot stress and its `total' and `plastic' work-conjugate strain measure. This is a key result, since it allows an immediate achievement of the rate elastoplastic constitutive equations. Knowing the general form of these equations, all the specific laws governing the behaviour of ceramic powders are finally introduced as generalizations of the small strain counterparts given in Part I of this paper.

Andrea Piccolroaz; Davide Bigoni; Alessandro Gajo

2010-10-09T23:59:59.000Z

399

Iron Aerogel and Xerogel Catalysts for Fischer-Tropsch Synthesis of Diesel Fuel  

SciTech Connect

Iron aerogels, potassium-doped iron aerogels, and potassium-doped iron xerogels have been synthesized and characterized and their catalytic activity in the Fischer-Tropsch (F-T) reaction has been studied. Iron aerogels and xerogels were synthesized by polycondensation of an ethanolic solution of iron(III) chloride hexahydrate with propylene oxide which acts as a proton scavenger for the initiation of hydrolysis and polycondensation. Potassium was incorporated in the iron aerogel and iron xerogel by adding aqueous K{sub 2}CO{sub 3} to the ethanolic solutions of the Fe(III) precursor prior to addition of propylene oxide. Fischer-Tropsch activities of the catalysts were tested in a fixed bed reactor at a pressure of 100 psi with a H{sub 2}:CO ratio of 2:1. Iron aerogels were found to be active for F-T synthesis, and their F-T activities increased on addition of a K containing promoter. Moessbauer spectroscopic data are consistent with an open, nonrigid iron(III) aerogel structure progressing to an iron carbide/metallic iron catalyst via agglomeration as the F-T synthesis proceeds in the course of a 35 h fixed bed reaction test.

Bali, S.; Huggins, F; Huffman, G; Ernst, R; Pugmire, R; Eyring, E

2009-01-01T23:59:59.000Z

400

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21: Cisco IronPort Web / Email Security Appliance Sophos 21: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities November 12, 2012 - 6:00am Addthis PROBLEM: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities PLATFORM: Cisco IronPort Email Security Appliances (C-Series and X-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. Cisco IronPort Web Security Appliances (S-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. ABSTRACT: Cisco Ironport Appliances Sophos Anti-Virus Vulnerabilities. REFERENCE LINKS: Cisco Security Advisory ID: cisco-sa-20121108-sophos Secunia Advisory SA51197 IMPACT ASSESSMENT: High DISCUSSION: Cisco has acknowledged some vulnerabilities in Cisco IronPort Web Security

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Cisco IronPort Web / Email Security Appliance Sophos 1: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities V-021: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities November 12, 2012 - 6:00am Addthis PROBLEM: Cisco IronPort Web / Email Security Appliance Sophos Anti-Virus Multiple Vulnerabilities PLATFORM: Cisco IronPort Email Security Appliances (C-Series and X-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. Cisco IronPort Web Security Appliances (S-Series) running Sophos Engine versions 3.2.07.352_4.80 and prior. ABSTRACT: Cisco Ironport Appliances Sophos Anti-Virus Vulnerabilities. REFERENCE LINKS: Cisco Security Advisory ID: cisco-sa-20121108-sophos Secunia Advisory SA51197 IMPACT ASSESSMENT: High DISCUSSION: Cisco has acknowledged some vulnerabilities in Cisco IronPort Web Security

402

Use of bimodal carbon distribution in compacts for producing metallic iron nodules  

SciTech Connect

A method for use in production of metallic iron nodules comprising providing a reducible mixture into a hearth furnace for the production of metallic iron nodules, where the reducible mixture comprises a quantity of reducible iron bearing material, a quantity of first carbonaceous reducing material of a size less than about 28 mesh of an amount between about 65 percent and about 95 percent of a stoichiometric amount necessary for complete iron reduction of the reducible iron bearing material, and a quantity of second carbonaceous reducing material with an average particle size greater than average particle size of the first carbonaceous reducing material and a size between about 3 mesh and about 48 mesh of an amount between about 20 percent and about 60 percent of a stoichiometric amount of necessary for complete iron reduction of the reducible iron bearing material.

Iwasaki, Iwao

2012-10-16T23:59:59.000Z

403

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

404

Parkers-Iron Springs, Arkansas: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

Parkers-Iron Springs, Arkansas: Energy Resources Parkers-Iron Springs, Arkansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 34.6081427°, -92.3320235° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":34.6081427,"lon":-92.3320235,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

405

What's in the Cage Matters in Iron Antimonide Thermoelectric Materials |  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Experiments on Cement Yield Concrete Results Novel Experiments on Cement Yield Concrete Results Watching a Glycine Riboswitch "Switch" Polyamorphism in a Metallic Glass Under Pressure, Vanadium Won't Turn Down the Volume New Nanoscale Engineering Breakthrough Points to Hydrogen-Powered Vehicles Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed What's in the Cage Matters in Iron Antimonide Thermoelectric Materials MARCH 29, 2007 Bookmark and Share Crystal structure of EuFe4Sb12 showing the cage confined Eu atoms (red) and Fe atoms (brown) surrounded by Sb tilted octahedral (Sb atoms are not shown). Thermoelectric materials such as iron antimonide have drawn intense interest because they offer a pollution-free source of electricity and a

406

Arsenic Removal by Photochemical Methods: Nanoparticulate Zerovalent Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

Arsenic Removal by Photochemical Methods: Nanoparticulate Zerovalent Iron Arsenic Removal by Photochemical Methods: Nanoparticulate Zerovalent Iron and Heterogeneous Photocatalysis with TiO2 Speaker(s): Marta Litter Date: November 19, 2010 - 11:00am Location: 90-3122 Seminar Host/Point of Contact: Hugo Destaillats Arsenic in groundwater is a dramatic global problem due to the high incidence of arsenicosis or HACRE (Chronic Endemic Regional Hydro-arsenicism, Hidroarsenicismo Crónico Regional Endémico in Spanish), a severe illness causing skin lesions and cancer in extended regions of the world. For this reason, research on low-cost technologies for As removal to be applied in isolated, poor, rural locations is mandatory. This seminar will present a brief overview of arsenic pollution issues and mitigation needs in Latin America. It will also present results on As(V) removal using

407

The Viscosity of a Liquid Plutonium-Iron Eutectic Alloy  

SciTech Connect

The viscosity of a liquid plutonium-iron eutectic alloy, which contains 9.5 atom per cent iron and melts at 411 degrees C, was determined up to 808 degrees C at Mound Laboratory by an oscillating cup viscosimeter. This type of apparatus employed a right-circular cylindrical cup containing the liquid under investigation attached to a torsion fiber. The dampening effect of the liquid upon the normal oscillations of the pendululm was a function of the viscosity of the liquid. The amplitudes of the oscillations of the pendulum were measured by a photographic technique. The periods of the oscillations were determined by an automatic timing mechanism. The reliability of the viscosimeter was demonstrated by following the expected function of the viscosity of liquid lead and bismuth over a larger temperature range than was previously reported.

Wittenberg, L. J., Jones, L. V., Ofte, D.

1960-04-01T23:59:59.000Z

408

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents (OSTI)

An improved iron aluminide alloy of the DO[sub 3] type is described that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy conversion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26--30 at. % aluminum, 0.5--10 at. % chromium, 0.02--0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron. 3 figs.

McKamey, C.G.; Liu, C.T.

1990-10-09T23:59:59.000Z

409

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSTS  

DOE Green Energy (OSTI)

The goal of the proposed work described in this Final Report was the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The work described here has optimized the catalyst composition and pretreatment operation for a low-alpha catalyst. In parallel, work has been conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies have been conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors have been studied at the laboratory scale. Catalyst performance has been determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1998-07-22T23:59:59.000Z

410

IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

Science Conference Proceedings (OSTI)

Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

2012-03-19T23:59:59.000Z

411

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents (OSTI)

An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.

McKamey, Claudette G. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

1990-01-01T23:59:59.000Z

412

Iron aluminide alloy container for solid oxide fuel cells  

DOE Patents (OSTI)

A container for fuel cells is made from an iron aluminide alloy. The container alloy preferably includes from about 13 to about 22 weight percent Al, from about 2 to about 8 weight percent Cr, from about 0.1 to about 4 weight percent M selected from Zr and Hf, from about 0.005 to about 0.5 weight percent B or from about 0.001 to about 1 weight percent C, and the balance Fe and incidental impurities. The iron aluminide container alloy is extremely resistant to corrosion and metal loss when exposed to dual reducing and oxidizing atmospheres at elevated temperatures. The alloy is particularly useful for containment vessels for solid oxide fuel cells, as a replacement for stainless steel alloys which are currently used.

Judkins, Roddie Reagan (Knoxville, TN); Singh, Prabhakar (Export, PA); Sikka, Vinod Kumar (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

413

Method for heat treating iron-nickel-chromium alloy  

DOE Patents (OSTI)

A method for heat treating an age-hardenable iron-nickel-chromium alloy to obtain a bimodal distribution of gamma prime phase within a network of dislocations, the alloy consisting essentially of about 25% to 45% nickel, 10% to 16% chromium, 1.5% to 3% of an element selected from the group consisting of molybdenum and niobium, about 2% titanium, about 3% aluminum, and the remainder substantially all iron. To obtain optimum results, the alloy is heated to a temperature of 1025.degree. C. to 1075.degree. C. for 2-5 minutes, cold-worked about 20% to 60%, aged at a temperature of about 775.degree. C. for 8 hours followed by an air-cool, and then heated to a temperature in the range of 650.degree. C. to 700.degree. C. for 2 hours followed by an air-cool.

Merrick, Howard F. (Suffern, NY); Korenko, Michael K. (Rockville, MD)

1982-01-01T23:59:59.000Z

414

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

1997-01-01T23:59:59.000Z

415

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, {<=}1% Cr and either {>=}0.05% Zr or ZrO{sub 2} stringers extending perpendicular to an exposed surface of the heating element or {>=}0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, {<=}2% Ti, {<=}2% Mo, {<=}1% Zr, {<=}1% C, {<=}0.1% B, {<=}30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, {<=}1% rare earth metal, {<=}1% oxygen, {<=}3% Cu, balance Fe. 64 figs.

Sikka, V.K.; Deevi, S.C.; Fleischhauer, G.S.; Hajaligol, M.R.; Lilly, A.C. Jr.

1997-04-15T23:59:59.000Z

416

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

1999-01-01T23:59:59.000Z

417

Iron aluminide useful as electrical resistance heating elements  

DOE Patents (OSTI)

The invention relates generally to aluminum containing iron-base alloys useful as electrical resistance heating elements. The aluminum containing iron-base alloys have improved room temperature ductility, electrical resistivity, cyclic fatigue resistance, high temperature oxidation resistance, low and high temperature strength, and/or resistance to high temperature sagging. The alloy has an entirely ferritic microstructure which is free of austenite and includes, in weight %, over 4% Al, .ltoreq.1% Cr and either .gtoreq.0.05% Zr or ZrO.sub.2 stringers extending perpendicular to an exposed surface of the heating element or .gtoreq.0.1% oxide dispersoid particles. The alloy can contain 14-32% Al, .ltoreq.2% Ti, .ltoreq.2% Mo, .ltoreq.1% Zr, .ltoreq.1% C, .ltoreq.0.1% B, .ltoreq.30% oxide dispersoid and/or electrically insulating or electrically conductive covalent ceramic particles, .ltoreq.1% rare earth metal, .ltoreq.1% oxygen, .ltoreq.3% Cu, balance Fe.

Sikka, Vinod K. (Oak Ridge, TN); Deevi, Seetharama C. (Oak Ridge, TN); Fleischhauer, Grier S. (Midlothian, VA); Hajaligol, Mohammad R. (Richmond, VA); Lilly, Jr., A. Clifton (Chesterfield, VA)

2001-01-01T23:59:59.000Z

418

Technology development for iron F-T catalysts. Final report  

DOE Green Energy (OSTI)

The objectives of this work were twofold. The first objective was to design and construct a pilot plant for preparing precipitated iron oxide F-T precursors and demonstrate that the rate of production from this plant is equivalent to 100 lbs/day of dried metal oxide. Secondly, these precipitates were to be used to prepare catalysts capable of achieving 88% CO + H{sub 2} conversion with {le} 5 mole percent selectivity to methane + ethane.

Frame, R.R.; Gala, H.B.

1994-08-01T23:59:59.000Z

419

Multimuon production in 280 GeV ?+ iron interactions  

Science Conference Proceedings (OSTI)

Results are presented on dimuon and trimuon final states in 280 GeV ?+ iron interactions. Both dimuon and trimuon data show clear evidence for open charm production and suggest strongly that the dominant production process is photon?gluon fusion. Similar amounts of elastic and inelastic (shower energy ?5 GeV) J/? production are measured in the trimuon sample. Elastic J/? production is consistent with photon?gluon fusion plus naive assumptions. Inelastic J/? production is inconsistent with this simple model

The European Muon Collaboration

1980-01-01T23:59:59.000Z

420

Pressure Effects on Two Superconducting Iron-based Families  

SciTech Connect

Insight into the mechanism of high-temperature superconductivity can be gained by pressure-dependent studies of structural, thermodynamics and transport data. The role of pressure may be complicated by the level of hydrostaticity. High-pressure studies on two iron-based families of RFeAsO (R = rare-earth metals) and AFe{sub 2}As{sub 2} (A = alkaline-earth metals) are reviewed here.

Safa-Sefat, Athena [ORNL

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Low resistivity contact to iron-pnictide superconductors  

DOE Patents (OSTI)

Method of making a low resistivity electrical connection between an electrical conductor and an iron pnictide superconductor involves connecting the electrical conductor and superconductor using a tin or tin-based material therebetween, such as using a tin or tin-based solder. The superconductor can be based on doped AFe.sub.2As.sub.2, where A can be Ca, Sr, Ba, Eu or combinations thereof for purposes of illustration only.

Tanatar, Makariy; Prozorov, Ruslan; Ni, Ni; Bud& #x27; ko, Sergey; Canfield, Paul

2013-05-28T23:59:59.000Z

422

Performance and cycling of the iron-ion/hydrogen redox flow cell with  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and cycling of the iron-ion/hydrogen redox flow cell with Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Title Performance and cycling of the iron-ion/hydrogen redox flow cell with various catholyte salts Publication Type Journal Article Year of Publication 2013 Authors Tucker, Michael C., Venkat Srinivasan, Philip N. Ross, and Adam Z. Weber Journal Journal of Applied Electrochemistry Volume 43 Issue 7 Pagination 637 - 644 Date Published 7/2013 ISSN 0021-891X Keywords battery, Flow battery, iron hydrogen cell, progress, redox flow cell Abstract A redox flow cell utilizing the Fe2+/Fe3+ and H-2/H+ couples is investigated as an energy storage device. A conventional polymer electrolyte fuel cell anode and membrane design is employed, with a cathode chamber containing a carbon felt flooded with aqueous acidic solution of iron salt. The maximum power densities achieved for iron sulfate, iron chloride, and iron nitrate are 148, 207, and 234 mW cm(-2), respectively. It is found that the capacity of the iron nitrate solution decreases rapidly during cycling. Stable cycling is observed for more than 100 h with iron chloride and iron sulfate solutions. Both iron sulfate and iron chloride solutions display moderate discharge polarization and poor charge polarization; therefore, voltage efficiency decreases dramatically with increasing current density. A small self-discharge current occurs when catholyte is circulating through the cathode chamber. As a result, a current density above 100 mA cm(-2) is required to achieve high Coulombic efficiency (> 0.9).

423

Snapshot of iron response in Shewanella oneidensis by gene network reconstruction  

Science Conference Proceedings (OSTI)

Background: Iron homeostasis of Shewanella oneidensis, a gamma-proteobacterium possessing high iron content, is regulated by a global transcription factor Fur. However, knowledge is incomplete about other biological pathways that respond to changes in iron concentration, as well as details of the responses. In this work, we integrate physiological, transcriptomics and genetic approaches to delineate the iron response of S. oneidensis. Results: We show that the iron response in S. oneidensis is a rapid process. Temporal gene expression profiles were examined for iron depletion and repletion, and a gene co-expression network was reconstructed. Modules of iron acquisition systems, anaerobic energy metabolism and protein degradation were the most noteworthy in the gene network. Bioinformatics analyses suggested that genes in each of the modules might be regulated by DNA-binding proteins Fur, CRP and RpoH, respectively. Closer inspection of these modules revealed a transcriptional regulator (SO2426) involved in iron acquisition and ten transcriptional factors involved in anaerobic energy metabolism. Selected genes in the network were analyzed by genetic studies. Disruption of genes encoding a putative alcaligin biosynthesis protein (SO3032) and a gene previously implicated in protein degradation (SO2017) led to severe growth deficiency under iron depletion conditions. Disruption of a novel transcriptional factor (SO1415) caused deficiency in both anaerobic iron reduction and growth with thiosulfate or TMAO as an electronic acceptor, suggesting that SO1415 is required for specific branches of anaerobic energy metabolism pathways. Conclusions: Using a reconstructed gene network, we identified major biological pathways that were differentially expressed during iron depletion and repletion. Genetic studies not only demonstrated the importance of iron acquisition and protein degradation for iron depletion, but also characterized a novel transcriptional factor (SO1415) with a role in anaerobic energy metabolism.

Yang, Yunfeng; Harris, Daniel P.; Luo, Feng; Xiong, Wenlu; Joachimiak, Marcin; Wu, Liyou; Dehal, Paramvir; Jacobsen, Janet; Yang, Zamin; Palumbo, Anthony V.; Arkin, Adam P.; Zhou, Jizhong

2008-10-09T23:59:59.000Z

424

Blood and hair lead in children with different extents of iron deficiency in Karachi  

SciTech Connect

Childhood iron deficiency has a high incidence in Pakistan. Some but not all studies have shown that dietary iron deficiency may cause increased absorption of lead as both compete for the same transporters in the small intestine. Therefore, children in Pakistan, residing in heavily polluted cities like Karachi may be prone to lead poisoning. This hypothesis was tested by investigating blood and hair lead concentrations in children from Karachi who were divided into four groups of iron status; normal, borderline iron deficiency, iron deficiency and iron deficiency anaemia. A prospective observational study was conducted where 269 children were categorized into four groups of iron status using the World Health Organization criteria and one based on soluble transferrin receptor measurements. Blood iron status was determined using a full blood count, serum iron, ferritin, transferrin saturation and soluble transferrin receptor measurements. Blood lead was determined by graphite atomic absorption spectroscopy, whereas hair lead was assessed using an inductively coupled plasma atomic emission spectroscopy technique. Blood lead concentrations were significantly higher in children with iron deficiency anaemia (mean [95% confidence intervals] were 24.9 [22.6-27.2] {mu}g/dL) compared to those with normal iron status (19.1 [16.8-21.4] {mu}g/dL) using WHO criteria. In contrast, hair lead content was not significantly different in children of different iron status. Our findings reinforce the importance of not only reducing environmental lead pollution but also the development of national health strategies to reduce childhood iron deficiency in Pakistan.

Ataur Rahman, Muhammad; Rahman, Bushra [Karachi Institute of Biotechnology and Genetic Engineering, University of Karachi, Karachi-75270 (Pakistan)] [Karachi Institute of Biotechnology and Genetic Engineering, University of Karachi, Karachi-75270 (Pakistan); Saeed Ahmad, Muhammad [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom)] [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom); Blann, Andrew [Department of Medicine, City Hospital, Birmingham B18 7QH, United Kingdom. (United Kingdom)] [Department of Medicine, City Hospital, Birmingham B18 7QH, United Kingdom. (United Kingdom); Ahmed, Nessar, E-mail: N.Ahmed@mmu.ac.uk [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom)] [School of Healthcare Science, Manchester Metropolitan University, Manchester M1 5GD (United Kingdom)

2012-10-15T23:59:59.000Z

425

Length-scale Effects in Cascade Damage Production in Iron  

SciTech Connect

Molecular dynamics simulations provide an atomistic description of the processes that control primary radiation damage formation in atomic displacement cascades. An extensive database of simulations describing cascade damage production in single crystal iron has been compiled using a modified version of the interatomic potential developed by Finnis and Sinclair. This same potential has been used to investigate primary damage formation in nanocrystalline iron in order to have a direct comparison with the single crystal results. A statistically significant number of simulations were carried out at cascade energies of 10 keV and 20 keV and temperatures of 100 and 600K to make this comparison. The results demonstrate a significant influence of nearby grain boundaries as a sink for mobile defects during the cascade cooling phase. This alters the residual primary damage that survives the cascade event. Compared to single crystal, substantially fewer interstitials survive in the nanograined iron, while the number of surviving vacancies is similar or slightly greater than the single crystal result. The fraction of the surviving interstitials contained in clusters is also reduced. The asymmetry in the survival of the two types of point defects is likely to alter damage accumulation at longer times.

Stoller, Roger E [ORNL; Osetskiy, Yury N [ORNL; Kamenski, Paul J [ORNL

2009-01-01T23:59:59.000Z

426

The development of precipitated iron catalysts with improved stability  

DOE Green Energy (OSTI)

The goal of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. This report covers testing an iron catalyst. During the last quarter, a new precipitated iron catalyst was prepared and tested in the slurry autoclave reactor at various conditions. This catalyst did not noticeably deactivate during 1250 hours of testing. This quarter, the test was extended to include performance evaluations at different conversion levels ranging from 35 to 88% at 265 and 275{degree}C. The conversion levels were varied by changing the feed rate. The catalytic performance at different conversion intervals was then integrated to approximately predict performance in a bubble column reactor. The run was shut down at the end of 1996 hours because of a 24-hour-power outage. When the power was back on, the run was restarted from room temperature. Catalytic performance during the first 300 hours after the restart-up was monitored. Overall product distributions are being tabulated as analytical laboratory data are obtained. 34 figs., 3 tabs.

Not Available

1990-01-01T23:59:59.000Z

427

Mineral ecophysiological evidence for microbial activity in banded iron formation  

Science Conference Proceedings (OSTI)

The phosphorus composition of banded-iron formations (BIFs) has been used as a proxy for Precambrian seawater composition and the paleoeredox state of Earth's surface environment. However, it is unclear whether the phosphorus in BIFs originally entered the sediment as a sorbed component of the iron oxyhydroxide particles, or whether it was incorporated into the biomass of marine phytoplankton. We conducted high-resolution mineral analyses and report here the first detection of an Fe(III) acetate salt, as well as nanocrystals of apatite in association with magnetite, in the 2.48 Ga Dales Gorge Member of the Brockman Iron Formation (a BIF), Hamersley, Western Australia. The clusters of apatite are similar in size and morphology to biogenic apatite crystals resulting from biomass decay in Phanerozoic marine sediments, while the formation of an Fe(III) acetate salt and magnetite not only implies the original presence of biomass in the BIF sediments, but also that organic carbon likely served as an electron donor during bacterial Fe(III) reduction. This study is important because it suggests that phytoplankton may have played a key role in the transfer of phosphorus (and other trace elements) from the photic zone to the seafloor.

Li, Dr. Yi-Liang [University of Tennessee, Knoxville (UTK); Konhauser, Dr, Kurt [University of Alberta; Cole, David R [ORNL; Phelps, Tommy Joe [ORNL

2011-01-01T23:59:59.000Z

428

Versatile and Biomass Synthesis of Iron-based Nanoparticles Supported on Carbon Matrix with High Iron Content and Tunable Reactivity  

SciTech Connect

Iron-based nanoparticles supported on carbon (FeNPs{at}C) have enormous potential for environmental applications. Reported is a biomass-based method for FeNP{at}C synthesis that involves pyrolysis of bleached wood fiber pre-mixed with Fe{sub 3}O{sub 4} nanoparticles. This method allows synthesis of iron-based nanoparticles with tunable chemical reactivity by changing the pyrolysis temperature. The FeNP{at}C synthesized at a pyrolysis temperature of 500 C (FeNP{at}C-500) reacts violently (pyrophoric) when exposed to air, while FeNP{at}C prepared at 800 C (FeNP{at}C-800) remains stable in ambient condition for at least 3 months. The FeNPs in FeNP{at}C-800 are mostly below 50 nm in diameter and are surrounded by carbon. The immediate carbon layer (within 5-15 nm radius) on the FeNPs is graphitized. Proof-of-concept environmental applications of FeNPs{at}C-800 were demonstrated by Rhodamine 6G and arsenate (V) removal from water. This biomass-based method provides an effective way for iron-based nanoparticle fabrication and biomass utilization.

Zhang, Dongmao [ORNL; Shi, Sheldon Q [ORNL; Jiang, Dongping [Mississippi State University (MSU); Che, Wen [Mississippi State University (MSU); Gai, Zheng [ORNL; Howe, Jane Y [ORNL; More, Karren Leslie [ORNL; Arockiasamy, Antonyraj [Mississippi State University (MSU)

2012-01-01T23:59:59.000Z

429

Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins  

NLE Websites -- All DOE Office Websites (Extended Search)

Solvent Tuning of Properties of Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in nature and catalyze one-electron transfer processes. These proteins have evolved into two classes that have large differences in their electrochemical potentials: high potential iron-sulfur proteins (HiPIPs) and bacterial ferredoxins (Fds). The role of the surrounding protein environment in tuning the redox potential of these iron sulfur clusters has been a persistent puzzle in biological electron transfer [1]. Although HiPIPs and Fds have the same iron sulfur structural motif - a cubane-type structure - (Figure 1), there are large differences in their electrochemical

430

Laboratory study related to the production and properties of pig iron nuggets  

SciTech Connect

Pig iron nuggets were produced in a laboratory-scale furnace at Michigan Technological University. The process was intended to replicate Kobe Steel's ITmk3 direct ironmaking process. These nuggets were produced from pellets that were made from a mixture of iron oxide, coal, flux and a binder and heated in a furnace with a chamber temperature of 1450{sup o}C. The pellets then self-reduced to produce a solid, high-density, highly metallized (96.5% Fe) pig iron. During the nugget production process, a separate liquid slag phase formed that cleanly separated from the molten metal. The physical and chemical properties of the pig iron nuggets were similar to pig iron produced by blast furnaces, which is distinct from direct reduced iron (DRI).

Anameric, B.; Kawatra, S.K. [Michigan Technological University, Houghton, MI (United States). Dept. for Chemical Engineering

2006-02-15T23:59:59.000Z

431

Enzymes of respiratory iron oxidation. Progress report, March 1990--June 1992  

DOE Green Energy (OSTI)

This report describes experimental progress in characterizing and identifying redox proteins in a number of iron-oxidizing bacteria. Sections of the paper are entitled (1) In Situ electrolysis was explored to achieve enhanced yields of iron-oxidizing bacteria, (2)Structure/function studies were performed on redox-active biomolecules from Thiobacillus ferrooxidans, (3) Novel redox-active biomolecules were demonstrated in other iron autotrophs, and (4) New probes of metalloprotein electron-transfer reactions were synthesized and characterized.

Blake, R. II

1992-12-31T23:59:59.000Z

432

Preservation of iron(II) by carbon-rich matrices in a hydrothermal plume  

SciTech Connect

Hydrothermal venting associated with mid-ocean ridge volcanism is globally widespread. This venting is responsible for a dissolved iron flux to the ocean that is approximately equal to that associated with continental riverine runoff. For hydrothermal fluxes, it has long been assumed that most of the iron entering the oceans is precipitated in inorganic forms. However, the possibility of globally significant fluxes of iron escaping these mass precipitation events and entering open-ocean cycles is now being debated, and two recent studies suggest that dissolved organic ligands might influence the fate of hydrothermally vented metals. Here we present spectromicroscopic measurements of iron and carbon in hydrothermal plume particles at the East Pacific Rise mid-ocean ridge. We show that organic carbon-rich matrices, containing evenly dispersed iron(II)-rich materials, are pervasive in hydrothermal plume particles. The absence of discrete iron(II) particles suggests that the carbon and iron associate through sorption or complexation. We suggest that these carbon matrices stabilize iron(II) released from hydrothermal vents in the region, preventing its oxidation and/or precipitation as insoluble minerals. Our findings have implications for deep-sea biogeochemical cycling of iron, a widely recognized limiting nutrient in the oceans.

Toner, Brandy M.; Fakra, Sirine C.; Manganini, Steven J.; Santelli, Cara M.; Marcus, Matthew A.; Moffett, James W.; Rouxel, Olivier; German, Christopher R.; Edwards, Katrina J.

2008-09-20T23:59:59.000Z

433

Iron-Carbon Phase Diagram: A Century at Variance with Chemical ...  

Science Conference Proceedings (OSTI)

Abstract Scope, For about a century thermodynamically absurd facts have been propagated in conjunction with the iron-carbon phase diagram. These facts...

434

Reduction of soot emissions by iron pentacarbonyl in isooctane diffusion flames  

Science Conference Proceedings (OSTI)

Light-scattering measurements, in situ laser-induced fluorescence, and thermophoretic sampling with transmission electron microscopy (TEM) analysis, were performed in laboratory isooctane diffusion flames seeded with 4000 ppm iron pentacarbonyl. These measurements allowed the determination of the evolution of the size, number density, and volume fraction of soot particles through the flame. Comparison to unseeded flame data provided a detailed assessment of the effects of iron addition on soot particle inception, growth, and oxidation processes. Iron was found to produce a minor soot-enhancing effect at early residence times, while subsequent soot particle growth was largely unaffected. It is concluded that primarily elemental iron is incorporated within the soot particles during particle inception and growth. However, iron addition was found to enhance the rate of soot oxidation during the soot burnout regime, yielding a two-thirds reduction in overall soot emissions. In situ spectroscopic measurements probed the transient nature of elemental iron throughout the flame, revealing significant loss of elemental iron, presumably to iron oxides, with increasing flame residence, suggesting catalysis of soot oxidation via iron oxide species. (author)

Kim, K.B.; Masiello, K.A.; Hahn, D.W. [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, FL 32611 (United States)

2008-07-15T23:59:59.000Z

435

Corrosion Products of Iron Wire Arterial Implants from In Vivo and In ...  

Science Conference Proceedings (OSTI)

In the present study, iron wire was implanted into either the abdominal rat aortic wall or ... Fabrication of a Cellulosic Nanocomposite Scaffold with Improved...

436

Sticking of Iron Ore Pellets in Direct Reduction with Coal Gas  

Science Conference Proceedings (OSTI)

Abstract Scope, A series of reduction experiments of iron ore pellets with coal gasification gas were carried out in a laboratory scale shaft furnace. The sticking

437

Mathematical Modeling for Developing Iron Bath Reactor with H2-C ...  

Science Conference Proceedings (OSTI)

After dispersion treatment with Control-Volume-Method, the whole model was ... Iron Removal from Titanium Ore Through Selective Chlorination and Its...

438

Impacts of increasing anthropogenic soluble iron and nitrogen deposition on ocean biogeochemistry  

E-Print Network (OSTI)

and sulfur deposition on ocean acidification and thethe tropical North Atlantic Ocean, J. Geophys. Res. , 105,and iron inputs to the ocean, Global Biogeochem. Cycles, 19,

2009-01-01T23:59:59.000Z

439

Effect of PCI blending on combustion characteristics for iron-making.  

E-Print Network (OSTI)

??The PCI technology is well established for reducing the consumption of economic and environmentally expensive coke in blast furnace iron-making. Often, coal blends show unexpected (more)

Gill, Trilochan Singh

2009-01-01T23:59:59.000Z

440

Moving towards Sustainability: Improving Material Flows in the Iron Casting Industry.  

E-Print Network (OSTI)

??ustainable engineering solutions were developed to improve the sustainability of the iron casting process. These engineering solutions aimed to modify the material and energy flow (more)

Huang, He

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Clean iron production and machining technology. Year 1 summary report, January 1--December 31, 1995  

SciTech Connect

The first phase of this project was conducted to develop a technique for evaluating the machinability of gray and ductile iron. That technique was then used to measure the machinability of a variety of irons and determine the processing factors that influenced and controlled machinability. The procedure developed to evaluate machinability involved drilling holes with a feed rate of 0.009 in/rev at various surface speeds. High speed steel drills were used so wear was observed more quickly. Microcarbides present in the irons were found to dominate the machinability. Pearlitic irons considered to have ``acceptable`` machinability (indicated either by tool life measured in the laboratory using high speed steel (HSS) drills or reports from commercial machine shops using other cutters) were found to contain from 8.9 to 10.5% by weight microscopic carbides. The tool wear rate increased when machining at higher surface speeds or machining irons containing higher weight percentage of microcarbides. All irons containing above 11.5% microcarbides consistently exhibited poor machinability. Tool wear results obtained using cubic boron nitride (CBN) cutters paralleled those obtained with HSS. Higher iron microcarbide concentrations produced faster tool wear. Experiments are now being formulated to explore methods of improving iron machinability. Future work will extend the study to ductile irons.

1996-03-05T23:59:59.000Z

442

Iron Works Advance 1750-1910 in Central Canada, Contrasted With ...  

Science Conference Proceedings (OSTI)

... center for Central Canada, based on local pig iron and on WI imports (later, .... of Special-shape Tundish with Gas Curtain, Retaining Wall and Retaining Dam.

443

NERSC User Group 2013 Big Bang, Big Data, Big Iron Planck Satellite...  

NLE Websites -- All DOE Office Websites (Extended Search)

User Group 2013 Big Bang, Big Data, Big Iron Planck Satellite Data Analysis At NERSC Julian Borrill Computational Cosmology Center, Berkeley Lab & Space Sciences Laboratory, UC...

444

Anisotropy of the Fracture Behaviour of Severly Deformed Iron and a ...  

Science Conference Proceedings (OSTI)

Anisotropy of the Fracture Behaviour of Severly Deformed Iron and a Pearlitic Rail Steel Atom Probe Tomography: A New Insight into the Partition and...

445

Visualization at Supercomputing Centers: The Tale of Little Big Iron and the Three Skinny Guys  

SciTech Connect

Supercomputing centers are unique resources that aim to enable scientific knowledge discovery by employing large computational resources - the 'Big Iron.' Design, acquisition, installation, and management of the Big Iron are carefully planned and monitored. Because these Big Iron systems produce a tsunami of data, it's natural to colocate the visualization and analysis infrastructure. This infrastructure consists of hardware (Little Iron) and staff (Skinny Guys). Our collective experience suggests that design, acquisition, installation, and management of the Little Iron and Skinny Guys doesn't receive the same level of treatment as that of the Big Iron. This article explores the following questions about the Little Iron: How should we size the Little Iron to adequately support visualization and analysis of data coming off the Big Iron? What sort of capabilities must it have? Related questions concern the size of visualization support staff: How big should a visualization program be - that is, how many Skinny Guys should it have? What should the staff do? How much of the visualization should be provided as a support service, and how much should applications scientists be expected to do on their own?

Bethel, E Wes [Lawrence Berkeley National Laboratory (LBNL); Brugger, Eric [Lawrence Livermore National Laboratory (LLNL)

2011-01-01T23:59:59.000Z

446

Method for the Production of Mineral Wool andIron from ...  

Method for the Production of Mineral Wool and Iron from Serpentine Ore Overview This invention discloses a method to fabricate a product that has the potential

447

ESS 2012 Peer Review - Iron-Air Rechargeable Battery for Grid...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A Robust and Inexpensive Iron-Air Rechargeable Battery for Grid-Scale Energy Storage Lead: University of Southern California, Loker Hydrocarbon Research Institute Sub-Awardee: Jet...

448

Theory of spin-fluctuation induced superconductivity in iron-based superconductors.  

E-Print Network (OSTI)

??In this dissertation we focus on the investigation of the pairing mechanism in the recently discovered high-temperature superconductor, iron pnictides. Due to the proximity to (more)

Zhang, Junhua

2011-01-01T23:59:59.000Z

449

Constraining the initial state granularity with bulk observables in Au+Au collisions at $\\sqrt{s_{\\rm NN}}=200$ GeV  

E-Print Network (OSTI)

In this paper we conduct a systematic study of the granularity of the initial state of hot and dense QCD matter produced in ultra-relativistic heavy-ion collisions and its influence on bulk observables like particle yields, $m_T$ spectra and elliptic flow. For our investigation we use a hybrid transport model, based on (3+1)d hydrodynamics and a microscopic Boltzmann transport approach. The initial conditions are generated by a non-equilibrium hadronic transport approach and the size of their fluctuations can be adjusted by defining a Gaussian smoothing parameter $\\sigma$. The dependence of the hydrodynamic evolution on the choices of $\\sigma$ and $t_{start}$ is explored by means of a Gaussian emulator. To generate particle yields and elliptic flow that are compatible with experimental data the initial state parameters are constrained to be $\\sigma=1$ fm and $t_{\\rm start}=0.5$ fm. In addition, the influence of changes in the equation of state is studied and the results of our event-by-event calculations are ...

Petersen, Hannah; Bass, Steffen A; Wolpert, Robert

2010-01-01T23:59:59.000Z

450

Performance evaluation of granular activated carbon system at Pantex: Rapid small-scale column tests to simulate removal of high explosives from contaminated groundwater  

Science Conference Proceedings (OSTI)

A granular activated carbon (GAC) system is now in operation at Pantex to treat groundwater from the perched aquifer that is contaminated with high explosives. The main chemicals of concern are RDX and HMX. The system consists of two GAC columns in series. Each column is charged with 10,000 pounds of Northwestern LB-830 GAC. At the design flow rate of 325 gpm, the hydraulic loading is 6.47 gpm/ft{sup 2}, and the empty bed contact time is 8.2 minutes per column. Currently, the system is operating at less than 10% of its design flow rate, although flow rate increases are expected in the relatively near future. This study had several objectives: Estimate the service life of the GAC now in use at Pantex; Screen several GACs to provide a recommendation on the best GAC for use at Pantex when the current GAC is exhausted and is replaced; Determine the extent to which natural organic matter in the Pantex groundwater fouls GAC adsorption sites, thereby decreasing the adsorption capacity for high explosives; and Determine if computer simulation models could match the experimental results, thereby providing another tool to follow system performance.

Henke, J.L.; Speitel, G.E. [Univ. of Texas, Austin, TX (United States). Dept. of Civil Engineering] [Univ. of Texas, Austin, TX (United States). Dept. of Civil Engineering

1998-08-01T23:59:59.000Z

451

Effect of temperature and iron-oxide nano-particle inclusions on the ultrasound vaporization pressure of perfluorocarbon droplets for disease detection and therapy  

E-Print Network (OSTI)

Temperature and Iron-Oxide Nano-particle inclusions on the22 1.9.1 Why Iron-Oxide NanoTemperature and Iron-Oxide Nano-particle inclusions on the

Amirriazi, Seyed Saleh

2009-01-01T23:59:59.000Z

452

Phosphate influences cycling of iron and carbon in the environment |  

NLE Websites -- All DOE Office Websites (Extended Search)

Science Science Computing, Environment & Life Sciences Energy Engineering & Systems Analysis Photon Sciences Physical Sciences & Engineering Energy Frontier Research Centers Science Highlights Postdoctoral Researchers Phosphate influences cycling of iron and carbon in the environment August 30, 2013 Tweet EmailPrint Aquatic and terrestrial environments are dynamic systems where coupled microbiological, geochemical, and hydrological processes define the complex interactions that drive the biogeochemical cycling of water and the major and minor elements. Therefore, a thorough understanding of these complex interactions is critical for predicting the biogeochemical cycling of carbon, nutrients, heavy metals, radionuclides, and other contaminants; managing water quality; and understanding the interactions between

453

Chemistry and Electronic Structure of Iron-Based Superconductors  

Science Conference Proceedings (OSTI)

The solid state provides a richly varied fabric for intertwining chemical bonding, electronic structure, and magnetism. The discovery of superconductivity in iron pnictides and chalcogenides has revealed new aspects of this interplay, especially involving magnetism and superconductivity. Moreover, it has challenged prior thinking about high-temperature superconductivity by providing a set of materials that differ in many crucial aspects from the previously known cuprate superconductors. Here we review some of what is known about the superconductivity and its interplay with magnetism, chemistry, and electronic structure in Fe-based superconductors.

Safa-Sefat, Athena [ORNL; Singh, David J [ORNL

2011-01-01T23:59:59.000Z

454

New iron catalyst for preparation of polymethylene from synthesis gas  

DOE Patents (OSTI)

This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

Sapienza, R.S.; Slegeir, W.A.

1988-03-31T23:59:59.000Z

455

NONEQUILIBRIUM FLUCTUATIONS IN SHOCK COMPRESSION OF POLYCRYSTALLINE ALPHA-IRON  

Science Conference Proceedings (OSTI)

We report a numerical study of heterogeneous and nonequilibrium fluctuations in shock compression of {alpha}-iron at the grain level. A quasi-molecular code called DM2 is used to model the interactions of a plane shock wave with grain boundaries and crystal anisotropy over the pressure range of 5-45 GPa. Highly transient eddies that were reported earlier are again observed. We show new features through an elementary statistical analysis. They are (1) a characteristic decay constant for the non-equilibrium fluctuation on the order of 20ns, (2) a resonance phenomenon at an intermediate shock pressure, and (3) a more uniform shock structure for very high pressures.

Y. HORIE; K. YANO

2001-06-01T23:59:59.000Z

456

Feedwater Iron Optimization: Quad Cities Generating Station Unit 1  

Science Conference Proceedings (OSTI)

EPRI's BWR Water Chemistry Guidelines 2004 Revisions (report 1008192) recommends feedwater iron control in the range of 0.1 ppb 1.0 ppb for plants operating with reducing chemistry conditions for intergranular stress corrosion cracking (IGSCC) mitigation. Since all U.S. plants now operate under moderate hydrogen water chemistry (HWC-M) or noble metals chemical addition and hydrogen water chemistry (NMCA+HWC), it is appropriate to target the lower end of the range (0.1 0.5 ppb) to minimize zinc requiremen...

2008-08-18T23:59:59.000Z

457

GLASSES CONTAINING IRON (II III) OXIDES FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

SciTech Connect

Technetium-99 (Tc-99) has posed serious environmental threats as US Department of Energy's high-level waste. This work reports the vitrification of Re, as surrogate for Tc-99, by iron-borosilicate and iron-phosphate glasses, respectively. Iron-phosphate glasses can dissolve Re as high as {approx} 1.2 wt. %, which can become candidate waste forms for Tc-99 disposal, while borosilicate glasses can retain less than 0.1 wt. % of Re due to high melting temperature and long melting duration. Vitrification of Re as Tc-99's mimic was investigated using iron-borosilicate and iron-phosphate glasses. The retention of Re in borosilicate glasses was less than 0.1 wt. % and more than 99 wt. % of Re were volatilized due to high melting temperature and long melting duration. Because the retention of Re in iron-phosphate glasses is as high as 1.2 wt. % and the volatilization is reduced down to {approx}50 wt. %, iron-phosphate glasses can be one of the glass waste form candidates for Tc (or Re) disposal. The investigations of chemical durability and leaching test of iron-phosphate glasses containing Re are now underway to test the performance of the waste form.

KRUGER AA; HEO J; XU K; CHOI JK; HRMA PR; UM W

2011-11-07T23:59:59.000Z

458

Kiel Policy Brief Ocean Iron Fertilization: An Option for Mitigating Climate Change?  

E-Print Network (OSTI)

The world is very likely to experience a range of adverse climate change impacts in the coming decades and ocean iron fertilization is discussed as one measure to contribute to the mitigation of these impacts. Ocean iron fertilization aims at stimulating phytoplankton growth in certain parts of the ocean, thus enhancing oceanic CO2 uptake and reducing atmospheric CO2 concentrations.

Christine Bertram

2009-01-01T23:59:59.000Z

459

Attrition resistant bulk iron catalysts and processes for preparing and using same  

DOE Patents (OSTI)

An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.

Jothimurugesan, Kandaswamy (Ponca City, OK); Goodwin, Jr., James G. (Clemson, SC); Gangwal, Santosh K. (Cary, NC)

2007-08-21T23:59:59.000Z

460

Visualization at Supercomputing Centers: The Tale of Little Big Iron and the Three Skinny Guys  

SciTech Connect

Supercomputing Centers (SC's) are unique resources that aim to enable scientific knowledge discovery through the use of large computational resources, the Big Iron. Design, acquisition, installation, and management of the Big Iron are activities that are carefully planned and monitored. Since these Big Iron systems produce a tsunami of data, it is natural to co-locate visualization and analysis infrastructure as part of the same facility. This infrastructure consists of hardware (Little Iron) and staff (Skinny Guys). Our collective experience suggests that design, acquisition, installation, and management of the Little Iron and Skinny Guys does not receive the same level of treatment as that of the Big Iron. The main focus of this article is to explore different aspects of planning, designing, fielding, and maintaining the visualization and analysis infrastructure at supercomputing centers. Some of the questions we explore in this article include:"How should the Little Iron be sized to adequately support visualization and analysis of data coming off the Big Iron?" What sort of capabilities does it need to have?" Related questions concern the size of visualization support staff:"How big should a visualization program be (number of persons) and what should the staff do?" and"How much of the visualization should be provided as a support service, and how much should applications scientists be expected to do on their own?"

Bethel, E. Wes; van Rosendale, John; Southard, Dale; Gaither, Kelly; Childs, Hank; Brugger, Eric; Ahern, Sean

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "granular zero-valent iron" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Spectral induced polarization and electrodic potential monitoring of microbially mediated iron sulfide transformations  

Science Conference Proceedings (OSTI)

Stimulated sulfate-reduction is a bioremediation technique utilized for the sequestration of heavy metals in the subsurface.We performed laboratory column experiments to investigate the geoelectrical response of iron sulfide transformations by Desulfo vibriovulgaris. Two geoelectrical methods, (1) spectral induced polarization (SIP), and (2) electrodic potential measurements, were investigated. Aqueous geochemistry (sulfate, lactate, sulfide, and acetate), observations of precipitates (identified from electron microscopy as iron sulfide), and electrodic potentials on bisulfide ion (HS) sensitive silver-silver chloride (Ag-AgCl) electrodes (630 mV) were diagnostic of induced transitions between an aerobic iron sulfide forming conditions and aerobic conditions promoting iron sulfide dissolution. The SIP data showed 10m rad anomalies during iron sulfide mineralization accompanying microbial activity under an anaerobic transition. These anomalies disappeared during iron sulfide dissolution under the subsequent aerobic transition. SIP model parameters based on a Cole-Cole relaxation model of the polarization at the mineral-fluid interface were converted to (1) estimated biomineral surface area to pore volume (Sp), and (2) an equivalent polarizable sphere diameter (d) controlling the relaxation time. The temporal variation in these model parameters is consistent with filling and emptying of pores by iron sulfide biofilms, as the system transitions between anaerobic (pore filling) and aerobic (pore emptying) conditions. The results suggest that combined SIP and electrodic potential measurements might be used to monitor spatiotemporal variability in microbial iron sulfide transformations in the field.

Hubbard, Susan; Personna, Y.R.; Ntarlagiannis, D.; Slater, L.; Yee, N.; O'Brien, M.; Hubbard, S.

2008-02-15T23:59:59.000Z

462

Metallo-carbohedrenes. Chromium, iron, and molybdenum analogues  

Science Conference Proceedings (OSTI)

The formation of especially stable metal-carbon clusters, which have been designated metallo-carbohedrenes by Castleman and co-workers, has previously been reported for the early transition metals (Ti, Zr, Hf, V). Clusters having the formula M[sub 8]C[sub 12] were recognized as especially stable species which were formed in plasmas containing the metal and a carbon-containing precursor. A similar laser induced plasma technique is employed to synthesize chromium, molybdenum, and iron analogues of these so-called [open quotes]met-cars[close quotes] clusters and to study their photodissociation behavior. These observations suggest that met-cars cluster formation is a more general phenomenon than previously recognized. While chromium and molybdenum form the [open quotes]super-magic[close quotes] 8/12 stochiometry efficiently, met-cars formation competes with other special stoichiometries in the iron clusters. Implications for the bonding properties in met-cars systems are discussed. 22 refs., 5 figs.

Pilgrim, J.S.; Duncan, M.A. (Univ. of Georgia, Athens (United States))

1993-07-28T23:59:59.000Z

463

Deactivation by carbon of iron catalysts for indirect liquefaction  

DOE Green Energy (OSTI)

This report describes recent progress in a fundamental, three-year investigation of carbon formation and its effects on the activity and selectivity of promoted iron catalysts for Fischer-Tropsch (FT) synthesis, the objectives of which are: determine rates and mechanisms of carbon deactivation of unsupported Fe and Fe/K catalysts during CO hydrogenation over a range of CO concentrations, CO:H{sub 2} ratios, and temperatures; model the rates of deactivation of the same catalysts in fixed-bed reactors. During the thirteenth quarter design of software for a computer-automated reactor system to be used in the kinetic and deactivation studies was continued. Further progress was made toward the completion of the control language, control routines, and software for operating this system. Progress was also made on the testing of the system hardware and software. H{sub 2} chemisorption capacities and activity selectivity data were also measured for three iron catalysts promoted with 1% alumina. 47 refs., 8 figs., 1 tab.

Bartholomew, C.H.

1990-10-11T23:59:59.000Z

464

Technology development for iron Fischer-Tropsch catalysts  

DOE Green Energy (OSTI)

Objectives are to develop active, stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. For a H[sub 2]-CO in molar ratio of 0.5 to 1.0, catalyst performance target is 88% CO+H[sub 2] conversion at a minimum space velocity of 2.4 NL/hr/gFe, with no more than 4% methane/ethane selectivity and 1% conversion loss per week. During this period, it was found that the performance of the slurry-phase iron and copper oxide-based catalyst depends on the amount of K. Five catalysts with differing K contents were studied. The catalysts with the lowest K were more active than the ones with higher K levels. The one with the middle K level was judged best.

Frame, R.R.

1991-01-01T23:59:59.000Z

465

TECHNOLOGY DEVELOPMENT FOR IRON FISCHER-TROPSCH CATALYSIS  

DOE Green Energy (OSTI)

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the ''standard-catalyst'' developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics.

Burtron H. Davis

1998-04-01T23:59:59.000Z

466

Technology development for iron fischer-tropsch catalysis  

SciTech Connect

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. The catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the `standard-catalyst` developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low- alpha catalyst. In parallel, work will be conducted to design a high- alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for 5 catalysts synthesized in this program for activity, selectivity and aging characteristics.

Davis, B.H.

1997-05-14T23:59:59.000Z

467

Technology development for iron fisher-tropsch catalysis  

SciTech Connect

The goal of the proposed work is the development of iron-based Fischer-Tropsch catalysts that combined high activity, selectivity and life with physical robustness for slurry phase reactors that will produce either low-alpha or high-alpha products. the catalyst that is developed will be suitable for testing at the Advanced Fuels Development Facility at LaPorte, Texas or similar sized plant. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the standard-catalyst developed by German workers for slurry phase synthesis, The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. the oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studies at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity, and aging characteristics.

Davis, B.H.

1997-07-15T23:59:59.000Z

468

Discharge model for the lithium iron-phosphate electrode  

DOE Green Energy (OSTI)

This paper develops a mathematical model for lithium intercalation and phase change in an iron phosphate-based lithium-ion cell in order to understand the cause for the low power capability of the material. The juxtaposition of the two phases is assumed to be in the form of a shrinking core, where a shell of one phase covers a core of the second phase. Diffusion of lithium through the shell and the movement of the phase interface are described and incorporated into a porous electrode model consisting of two different particle sizes. Open-circuit measurements are used to estimate the composition ranges of the single-phase region. Model-experimental comparisons under constant current show that ohmic drops in the matrix phase, contact resistances between the current collector and the porous matrix, and transport limitations in the iron phosphate particle limit the power capability of the cells. Various design options, consisting of decreasing the ohmic drops, using smaller particles, and substituting the liquid electrolyte by a gel are explored, and their relative importance discussed. The model developed in this paper can be used as a means of optimizing the cell design to suit a particular application.

Srinivasan, Venkat; Newman, John

2004-02-28T23:59:59.000Z

469

Calculated power output from a thin iron-seeded plasma  

DOE Green Energy (OSTI)

Ionization equilibrium calculations are carried out for iron ions at a density of 10/sup 12/ cm/sup -3/ in a (hydrogen) plasma with electron density 10/sup 14/ cm/sup -3/, at temperatures from 0.8 to 10 keV. The computed radiated power loss from this plasma due to the iron ions ranges from about 4 W/cm/sup 3/ at the lowest temperature to about 0.4 W/cm/sup 3/ at the highest temperature; loss rates for other electron and ion densities will scale approximately as N/sub e/N/sub Fe/10/sup 26/. The losses are due principally to collisionally excited line radiation (especially ..delta..n = 0 transitions) at low temperatures, and to collisionally excited ..delta..n not equal to 0 transitions and to continuum radiative recombination at high temperatures. Spectra are also computed for diagnostic x-ray K/sub ..cap alpha../ (1s - 2p) transitions; the change in spectral distribution as a function of temperature agrees well with observations in the ST Tokamak. Bound-bound radiative transitions and dielectronic recombination are discussed at length in appendices; the latter process is of great importance in the establishment of ionization equilibrium, and in the excitation of K/sub ..cap alpha../ radiation at the lower temperatures.

Merts, A.L.; Cowan, R.D.; Magee, N.H. Jr.

1976-02-01T23:59:59.000Z

470

Interplay of superconductivity, magnetism, and density waves in rare-earth tritellurides and iron-based superconducting materials  

E-Print Network (OSTI)

B. Superconductivity . . . . . . . . . . . . . . . . .IV Superconductivity and Magnetism in Iron-PnictideSearch for Pressure Induced Superconductivity in Undoped Ce-

Zocco, Diego Andrs

2011-01-01T23:59:59.000Z