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  1. City of Grand Marais, Minnesota (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtdEllsworth, IowaGraettinger, Iowa (Utility Company)GrandMarais,

  2. Grand Marais PUC - Commercial & Industrial Energy Efficiency Rebate Program

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping STD-1128-2013 April 2013 DOEOwnedGrand JunctionGrandGrand|

  3. Grande

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    breaks ground on key sediment control project November 5, 2009 Structures will limit flow of sediments toward Rio Grande Los Alamos, New Mexico, November 5, 2009- Crews broke...

  4. Rio Grande

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100Nationalquestionnaires 0serialIndustrialSenior8RickRingleader:Rio Grande

  5. Grand Challenges

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFESOpportunitiesNERSC Getting StartedGraduate, UndergraduateGrand

  6. SOFT COST GRAND CHALLENGE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    energycenter.org California Center for Sustainable Energy Soft Cost Grand Challenge May 22, 2014 Accelerating the transition to a sustainable world powered by clean energy 2...

  7. 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grand Winner and Grand Winner Finalist Team Submissions 2015 Race to Zero Competition Grand Winner and Grand Winner Finalist Team Submissions Read the team submissions for the...

  8. Grande Ronde Subbasin Plan December 31, 2004

    E-Print Network [OSTI]

    Grande Ronde Subbasin Plan Supplement December 31, 2004 Prepared for: Northwest Power Kuchenbecker, Grande Ronde Model Watershed Program #12;Grande Ronde Subbasin Plan Supplement December 2004

  9. GRAND CHALLENGE PROBLEMS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFESOpportunities Nuclear PhysicsGE Global ResearchGNU »GRAND

  10. Mississippi Nuclear Profile - Grand Gulf

    U.S. Energy Information Administration (EIA) Indexed Site

    Grand Gulf" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date"...

  11. CRAD, NNSA- Maintenance (MN)

    Broader source: Energy.gov [DOE]

    CRAD for Maintenance (MN). Criteria Review and Approach Documents (CRADs) that can be used to conduct a well-organized and thorough assessment of elements of safety and health programs.

  12. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Grand Marais PUC- Commercial & Industrial Energy Efficiency Rebate Program Southern Minnesota Municipal Power Agency (SMMPA) is a joint-action agency which generates and sells...

  13. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 8 grandchallengesportfoliopg8.pdf More Documents & Publications Grand...

  14. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 9 grandchallengesportfoliopg9.pdf More Documents & Publications Grand...

  15. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 - pg 6 grandchallengesportfoliopg6.pdf More Documents & Publications Grand...

  16. Grand Challenge Portfolio: Driving Innovations in Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January 2011 Grand Challenge Portfolio: Driving Innovations in Industrial Energy Efficiency, January...

  17. Nuclear Proliferation and Grand Challenges

    ScienceCinema (OSTI)

    McCarthy, Kathy

    2013-05-28

    Nuclear engineer Dr. Kathy McCarthy leads systems analysis. She talks about proliferation and the grand challenges of nuclear R&D. For more information about INL energy research, visit http://www.facebook.com/idahonationallaboratory.

  18. Measured lifetimes of metastable levels of Mn X, Mn XI, Mn XII, and Mn XIII ions 

    E-Print Network [OSTI]

    Moehs, D. P.; Church, David A.

    1999-01-01

    An ion storage technique, based on the capture of metastable multiply charged ions from an external ion source into a Kingdon ion trap, has been used to measure the lifetimes of eight metastable levels of Mn ions with 3s(2)3p(k) configurations, k...

  19. Progress Report "The Grand Challenges

    E-Print Network [OSTI]

    Bou-Zeid, Elie

    : With Grand Challenges project funding to develop sustainable technologies for Africa, faculty member Winston Soboyejo designed a solar-powered refrigeration system for camel transport of vaccines to remote areas fellowships on campus with well over 100 students working on projects annually in 35 countries. It has given

  20. EV Everywhere Grand Challenge - Battery Workshop attendees list...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop EV Everywhere Grand Challenge Overview EV Everywhere Grand...

  1. The Lifetime of Grand Design

    E-Print Network [OSTI]

    M. R. Merrifield; R. J. Rand; S. E. Meidt

    2005-11-02

    The lifetime of the structure in grand design spiral galaxies is observationally ill-determined, but is essentially set by how accurately the pattern's rotation can be characterized by a single angular pattern speed. This paper derives a generalized version of the Tremaine-Weinberg method for observationally determining pattern speeds, in which the pattern speed is allowed to vary arbitrarily with radius. The departures of the derived pattern speed from a constant then provides a simple metric of the lifetime of the spiral structure. Application of this method to CO observations of NGC 1068 reveal that the pattern speed of the spiral structure in this galaxy varies rapidly with radius, and that the lifetime of the spiral structure is correspondingly very short. If this result turns out to be common in grand-design spiral galaxies, then these features will have to be viewed as highly transient phenomena.

  2. Grande

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUsefulJorgeAtlDay Draft TubeSpareFacility

  3. Grand Coulee Transmission Line Replacement Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Reliability Projects Expand Projects Skip navigation links Line Projects Big Eddy-Knight Central Ferry Lower Monumental Grand Coulee Transmission Line Replacement...

  4. Olympia-Grand Coulee No. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Reliability Projects Expand Projects Skip navigation links Line Projects Big Eddy-Knight Central Ferry Lower Monumental Grand Coulee Transmission Line Replacement...

  5. EV Everywhere Grand Challenge - Charging Infrastructure Enabling...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Charging Infrastructure Enabling Flexible EV Design EV Everywhere Grand Challenge - Charging Infrastructure Enabling Flexible EV Design Presentation given at the EV Everywhere...

  6. Synthesis and Electrochemistry of Li3MnO4: Mn in the +5 Oxidation State

    E-Print Network [OSTI]

    Saint, Juliette.A.; Doeff, Marca M.; Reed, John

    2008-01-01

    Synthesis and Electrochemistry of Li 3 MnO 4 : Mn in the +5A study describing the electrochemistry of Li 2 MnO 3 in ainvestigation into the electrochemistry of this system

  7. Proton Hexality in Local Grand Unification

    E-Print Network [OSTI]

    Stefan Forste; Hans Peter Nilles; Saul Ramos-Sanchez; Patrick K. S. Vaudrevange

    2010-09-03

    Proton hexality is a discrete symmetry that avoids the problem of too fast proton decay in the supersymmetric extension of the standard model. Unfortunately it is inconsistent with conventional grand unification. We show that proton hexality can be incorporated in the scheme of "Local Grand Unification" discussed in the framework of model building in (heterotic) string theory.

  8. Cyber Security Grand Challenges and Prognosis

    E-Print Network [OSTI]

    Sandhu, Ravi

    Cyber Security Grand Challenges and Prognosis Prof. Ravi Sandhu Executive Director and Institute for Cyber Security Executive Director and Endowed Chair ravi.sandhu@utsa.edu www.profsandhu.com www.ics.utsa.edu © Ravi Sandhu World-Leading Research with Real Cyber Security Grand Challenges and Prognosis Prof. Ravi

  9. Highly Active Yeast MnSOD has a Novel Mechanism Involving Six-coordinate Mn(3+) Species

    E-Print Network [OSTI]

    Sheng, Yuewei

    2012-01-01

    2009) Functional roles of the tetramer organization of malicGrez, M. (2010) Dimer-tetramer transition controls RUNX1/ETOdimer, Å) Mn•••Mn (A/C, tetramer, Å) Mn•••Mn (A/D, tetramer,

  10. EIS-0485: Interconnection of the Grande Prairie Wind Farm, Holt...

    Office of Environmental Management (EM)

    5: Interconnection of the Grande Prairie Wind Farm, Holt County, Nebraska EIS-0485: Interconnection of the Grande Prairie Wind Farm, Holt County, Nebraska SUMMARY DOE's Western...

  11. EV Everywhere Grand Challenge: Consumer Acceptance and Charging...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agenda EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop Agenda Agenda for the EV Everywhere Grand Challenge: Consumer Acceptance and Charging...

  12. EV Everywhere Grand Challenge - Electric Drive (Power Electronics...

    Broader source: Energy.gov (indexed) [DOE]

    EV Everywhere EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop Agenda EV Everywhere Grand Challenge - Battery Workshop...

  13. Grand Junction Office Founder Honored at the Philip C. Leahy...

    Office of Environmental Management (EM)

    Grand Junction Office Founder Honored at the Philip C. Leahy Memorial Park Dedication and Open House Grand Junction Office Founder Honored at the Philip C. Leahy Memorial Park...

  14. Balance the reaction MnO4 (aq) MnO2(s) + SO4

    E-Print Network [OSTI]

    Peterson, Kirk A.

    Balance the reaction MnO4 Ð (aq) + SO3 2Ð (aq) MnO2(s) + SO4 2Ð (aq) in basic solution Oxidation 2Ð SO4 2Ð (b) 2) These are already balanced in Mn and S 3) Balance O in (a) by adding H2OÕs to the right-hand-side MnO4 Ð MnO2 + 2H2O 4) Balance H by adding H + to the left-hand-side MnO4 Ð + 4H + MnO2

  15. The UCSC Arboretum: A Grand Experiment

    E-Print Network [OSTI]

    Reti, Irene; Regional History Project, UC Santa Cruz Library; Hall, Brett; Harder, Daniel; Norris, Phyllis

    2007-01-01

    had no roots, because Rodger Elliot would grow them in hisA Grand Experiment Jarrell: And Rodger Elliot was—Norris: Rodger Elliot was a nurseryman with his wife, Gwen,

  16. Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes

    SciTech Connect (OSTI)

    Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

    2009-05-28

    Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

  17. Sandia Energy - Upper Rio Grande Simulation Model (URGSiM)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Upper Rio Grande Simulation Model (URGSiM) Home Climate & Earth Systems WaterEnergy Nexus Decision Models for Integrating EnergyWater Systems Modeling Upper Rio Grande Simulation...

  18. Winning the Future: Grand Ronde Solar Projects Reduce Pollution...

    Office of Environmental Management (EM)

    Grand Ronde Solar Projects Reduce Pollution, Cut Costs Winning the Future: Grand Ronde Solar Projects Reduce Pollution, Cut Costs October 20, 2014 - 5:00pm Addthis PV panels...

  19. 2014 SunShot Grand Challenge Summit Opening Session Photos |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opening Session Photos Addthis SunShot Grand Challenge Summit Opening Session 1 of 35 SunShot Grand Challenge Summit Opening Session Anaheim Mayor Tom Tait with SunShot...

  20. Mn/DOT's Project Peer Review

    E-Print Network [OSTI]

    Minnesota, University of

    issue we share with peers) ·Benchmark Mn/DOT's project management practices ·Initial step in a change decision- making ·Able to manage project change #12;Project Management Opportunities and Challenges ·TheMn/DOT's Project Management Peer Review Creating a Project Management Culture 2010 CTS Research

  1. EA-0930: Facility Operations at the U.S. DOE Grand Junction Projects Office, Grand Junction, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to expand and upgrade the U.S. Department of Energy's Grand Junction Projects Office facilities and operations in Grand Junction, Colorado.

  2. Grand Junction Office Founder Honored at the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive CompensationEnergyGet Current:5Logging Systems (December4 Grand

  3. SSL Demonstration: Bridge Lighting, Minneapolis, MN

    SciTech Connect (OSTI)

    2014-10-01

    DOE Solid-State Lighting GATEWAY summary brief for Phase II report on the longer-term performance of LED lighting installed in 2008 on the I-35W Bridge in Minneapolis, MN.

  4. SunShot Grand Challenge Summit

    Broader source: Energy.gov [DOE]

    The SunShot Initiative at the U.S. Department of Energy (DOE) will host the second SunShot Grand Challenge Summit and Peer Review from May 19-22, 2014 at the Hilton Anaheim, California. The 2014 SunShot Summit brings together 800 esteemed members of the solar energy community including SunShot-funded project teams, industry leaders, innovative researchers and scientists, and local, state and federal government policymakers to review the progress made and discuss the challenges ahead to make solar energy more affordable and widespread across America.

  5. Destilaria Rio Grande | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to: navigation,Department of Defense 3Planalto Jump to:Grande

  6. Grand Junction, Colorado, Site Fact Sheet

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M P R E H E N S I551Grand

  7. High Mn austenitic stainless steel

    DOE Patents [OSTI]

    Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Maziasz, Philip J (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Knoxville, TN) [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  8. Citrus Production in the Lower Rio Grande Valley of Texas. 

    E-Print Network [OSTI]

    Traub, Hamilton Paul; Friend, W. H. (William Heartsill)

    1930-01-01

    . TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR COLLEGE STATION, BRAZOS COUNTY, TEXAS - BULLETIN NO. 419 DIVISION OF HORTICULTURE Citrus Production in the Lower Rio Grande Valley of Texas AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS.... . Citrus fruit production in the Lower Rio Grande Valley, especially grapefruit, has increased at a rather rapid rate dur- ing the past few years. More than 5,000,000 citrus trees were set in orchard form in the Lower Rio Grande Valley up to July, 1929...

  9. Summary of Grand Challenge Products Selected for Award Negotiations

    SciTech Connect (OSTI)

    2010-04-26

    DOE provides $13 million in funding to 48 research and development projects across the country that were selected as award winners of the Industrial Energy Efficiency Grand Challenge.

  10. EV Everywhere Grand Challenge: Consumer Acceptance and Charging...

    Broader source: Energy.gov (indexed) [DOE]

    Attnedance list for the EV Everywhere Grand Challenge: Consumer Acceptance and Charging Infrastructure Workshop on July 30, 2012 held at the LAX Marriott, Los Angeles, CA...

  11. Data Acquisition-Manipulation At Rio Grande Rift Region (Morgan...

    Open Energy Info (EERE)

    Data Acquisition-Manipulation At Rio Grande Rift Region (Morgan, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Data...

  12. EV Everywhere Grand Challenge Introduction for Electric Drive...

    Energy Savers [EERE]

    Danielson at the EV Everywhere Grand Challenge - Electric Drive (Power Electronics and Electric Machines) Workshop on July 24, 2012 held at the Doubletree O'Hare, Chicago, IL....

  13. EV Everywhere Grand Challenge - Battery Status and Cost Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Status and Cost Reduction Prospects EV Everywhere Grand Challenge - Battery Status and Cost Reduction Prospects Presentation given by technology manager David Howell at the EV...

  14. Geothermal Resources of Rifts- a Comparison of the Rio Grande...

    Open Energy Info (EERE)

    Rio Grande Rift is less well developed. Recent volcanism consists primarily of mantle-derived basalts, which have not had sufficient residence time within the crust to generate...

  15. Local environment of Mn in Mn delta-doped Si layers

    SciTech Connect (OSTI)

    Xiao, Q.F.; Kahwaji, S.; Monchesky, T.L.; Gordon, R.A.; Crozier, E.D.

    2009-11-09

    Dilute magnetic semiconductors combine both magnetic ordering and semiconducting behaviour, leading to potential spintronic applications. Silicon containing dilute Mn impurities is a potential dilute magnetic semiconductor. We have grown Mn delta-doped films by deposition of 0.7 of a monolayer of Mn on Si(001) by molecular beam epitaxy and capping the film with Si. The magnetic properties are likely sensitive to the distribution of Mn on substitutional or interstitial sites and the formation of metallic precipitates. We have used polarization-dependent XAFS to examine the local structure. We compare to a thicker MnSi film grown on Si(111) and also examine the influence of lead on the manganese environment when used as a surfactant in the growth process.

  16. Properties of (Ga,Mn)As codoped with Li

    SciTech Connect (OSTI)

    Miyakozawa, Shohei; Chen, Lin; Matsukura, Fumihiro; Ohno, Hideo

    2014-06-02

    We grow Li codoped (Ga,Mn)As layers with nominal Mn composition up to 0.15 by molecular beam epitaxy. The layers before and after annealing are characterized by x-ray diffraction, transport, magnetization, and ferromagnetic resonance measurements. The codoping with Li reduces the lattice constant and electrical resistivity of (Ga,Mn)As after annealing. We find that (Ga,Mn)As:Li takes similar Curie temperature to that of (Ga,Mn)As, but with pronounced magnetic moments and in-plane magnetic anisotropy, indicating that the Li codoping has nontrivial effects on the magnetic properties of (Ga,Mn)As.

  17. Magnetic fields of HgMn stars

    E-Print Network [OSTI]

    Hubrig, S; Ilyin, I; Korhonen, H; Schoeller, M; Savanov, I; Arlt, R; Castelli, F; Curto, G Lo; Briquet, M; Dall, T H

    2012-01-01

    The frequent presence of weak magnetic fields on the surface of spotted late-B stars with HgMn peculiarity in binary systems has been controversial during the two last decades. We re-analyse available spectropolarimetric material by applying the moment technique on spectral lines of inhomogeneously distributed elements separately. Furthermore, we present new determinations of the mean longitudinal magnetic field for the HgMn star HD65949 and the hotter analog of HgMn stars, the PGa star HD19400, using FORS2 installed at the VLT. We also give new measurements of the eclipsing system AR Aur with a primary star of HgMn peculiarity which were obtained with the SOFIN spectropolarimeter installed at the Nordic Optical Telescope. We downloaded from the ESO archive the publically available HARPS spectra for eight HgMn stars and one normal and one superficially normal B-type star obtained in 2010. The application of the moment technique to the HARPS and SOFIN spectra allowed us to study the presence of the longitudina...

  18. 39 Geographic Information Science: The Grand Challenges MICHAEL F. GOODCHILD

    E-Print Network [OSTI]

    Wright, Dawn Jeannine

    39 Geographic Information Science: The Grand Challenges MICHAEL F. GOODCHILD Many chapters; and the lack of awareness of such issues as #12;3 Geographic Information Science: The Grand Challenges scale technology; in essence the science behind the systems. Over the past twelve years there have been various

  19. Spin reorientation and Ce-Mn coupling in antiferromagnetic oxypnictide CeMnAsO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Qiang; Tian, Wei; Peterson, Spencer G.; Dennis, Kevin W.; Vaknin, David

    2015-02-18

    Structure and magnetic properties of high-quality polycrystlline CeMnAsO, a parent compound of the “1111”-type oxypnictides, have been investigated using neutron powder diffraction and magnetization measurements. We find that CeMnAsO undergoes a C-type antiferromagnetic order with Mn2+(S = 5/2) moments pointing along the c axis below a relatively high Néel temperature of TN = 347(1) K. Below TSR = 35 K, two simultaneous transitions occur where the Mn moments reorient from the c axis to the ab plane preserving the C-type magnetic order, and Ce moments undergo long-range AFM ordering with antiparallel moments pointing in the ab plane. Another transition tomore »a noncollinear magnetic structure occurs below 7 K. The ordered moments of Mn and Ce at 2 K are 3.32(4) ?B and 0.81(4)?B, respectively. We find that CeMnAsO primarily falls into the category of a local-moment antiferromagnetic insulator in which the nearest-neighbor interaction (J1) is dominant with J2 1/2 in the context of J1 – J2 – Jc model. The spin reorientation transition driven by the coupling between Ce and the transition metal seems to be common to Mn, Fe, and Cr ions, but not to Co and Ni ions in the isostructural oxypnictides. As a result, a schematic illustration of magnetic structures in Mn and Ce sublattices in CeMnAsO is presented.« less

  20. Energy absorption in Ni-Mn-Ga/ polymer composites

    E-Print Network [OSTI]

    Feuchtwanger, Jorge

    2006-01-01

    In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

  1. Seasonally Flooded Grasslands -Grand CaymanSeasonally Flooded Grasslands -Grand Cayman 0 1 2 3 4 50.5

    E-Print Network [OSTI]

    Exeter, University of

    Seasonally Flooded Grasslands - Grand CaymanSeasonally Flooded Grasslands - Grand Cayman 0 1 2 3 4 Protected Areas Seasonally Flooded Grasslands V.A.1.N.g. #12;Seasonally Flooded Grasslands - Little CaymanSeasonally Flooded Grasslands - Little Cayman 0 0.5 1 1.5 2 2.50.25 Kilometers Cayman Islands National Biodiversity

  2. Theory of weak localization in ferromagnetic (Ga,Mn)As 

    E-Print Network [OSTI]

    Garate, Ion; Sinova, Jairo; Jungwirth, T.; MacDonald, A. H.

    2009-01-01

    We study quantum interference corrections to the conductivity in (Ga,Mn)As ferromagnetic semiconductors using a model with disordered valence-band holes coupled to localized Mn moments through a p-d kinetic-exchange interaction. We find that at Mn...

  3. Still the Wild River Runs: Congress, the Sierra Club and the Fight to Save Grand Canyon

    E-Print Network [OSTI]

    Miller, Ryder W.

    2003-01-01

    the Sierra Club and the Fight to Save Grand Canyon By Byronthe Sierra Club and the Fight to Save Grand Canyon. Tucson,during the Grand Canyon dam fight, they are not the most

  4. Formation of MnSb during the growth of MnSi layers in the presence of an Sb flux

    E-Print Network [OSTI]

    Pennycook, Steve

    Epitaxial growth of silicide layers on Si substrates has attracted much attention due to their technologicalFormation of MnSb during the growth of MnSi layers in the presence of an Sb flux K. Matsuda, Y have been performed to elucidate the growth mechanism. The MnSi layer was grown by reactive deposition

  5. Influence of interstitial Mn on magnetism in room-temperature ferromagnet Mn(1+delta)Sb

    SciTech Connect (OSTI)

    Taylor, Alice E [ORNL; Berlijn, Tom [ORNL; Hahn, Steven E [ORNL; May, Andrew F [ORNL; Williams, Travis J [ORNL; Poudel, Lekhanath N [ORNL; Calder, Stuart A [ORNL; Fishman, Randy Scott [ORNL; Stone, Matthew B [ORNL; Aczel, Adam A [ORNL; Cao, Huibo [ORNL; Lumsden, Mark D [ORNL; Christianson, Andrew D [ORNL

    2015-01-01

    We report elastic and inelastic neutron scattering measurements of the high-TC ferromagnet Mn(1+delta)Sb. Measurements were performed on a large, TC = 434 K, single crystal with interstitial Mn content of delta=0.13. The neutron diffraction results reveal that the interstitial Mn has a magnetic moment, and that it is aligned antiparallel to the main Mn moment. We perform density functional theory calculations including the interstitial Mn, and find the interstitial to be magnetic in agreement with the diffraction data. The inelastic neutron scattering measurements reveal two features in the magnetic dynamics: i) a spin-wave-like dispersion emanating from ferromagnetic Bragg positions (H K 2n), and ii) a broad, non-dispersive signal centered at forbidden Bragg positions (H K 2n+1). The inelastic spectrum cannot be modeled by simple linear spin-wave theory calculations, and appears to be significantly altered by the presence of the interstitial Mn ions. The results show that the influence of the int

  6. CaMn2Al10: Itinerant Mn magnetism on the verge of magnetic order

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Steinke, L.; Simonson, J. W.; Yin, W. -G.; Smith, G. J.; Kistner-Morris, J. J.; Zellman, S.; Puri, A.; Aronson, M. C.

    2015-07-24

    We report the discovery of CaMn2Al10, a metal with strong magnetic anisotropy and moderate electronic correlations. Magnetization measurements find a Curie-Weiss moment of 0.83?B/Mn, significantly reduced from the Hund's rule value, and the magnetic entropy obtained from specific heat measurements is correspondingly small, only ? 9% of Rln2. These results imply that the Mn magnetism is highly itinerant, a conclusion supported by density functional theory calculations that find strong Mn-Al hybridization. Consistent with the layered nature of the crystal structure, the magnetic susceptibility ? is anisotropic below 20 K, with a maximum ratio of ?[010]/?[001] ? 3.5. A strong power-lawmore »divergence ?(T) ~ T–1.2 below 20 K implies incipient ferromagnetic order, an Arrott plot analysis of the magnetization suggests a vanishing low Curie temperature TC ~ 0. Our experiments indicate that CaMn2Al10 is a rare example of a system where the weak and itinerant Mn-based magnetism is poised on the verge of order.« less

  7. A Proportional Wire Chamber Array: GRAND's Status

    E-Print Network [OSTI]

    J. Poirier; C. D'Andrea; M. Lopez del Puerto; E. Strahler; J. Vermedahl

    2003-06-18

    Project GRAND is a 100m x 100m air shower array of position sensitive proportional wire chambers (PWCs) located at 41.7 degrees North and 86.2 degrees West at an elevation of 220m above sea level. Its convenient location adjacent to the campus of the University of Notre Dame makes it a good training ground for students. There are 64 stations each with eight 1.29 m^2 PWCs. The geometry of the stations allows for the angles of charged secondaries to be determined to within 0.26 degrees in each of two orthogonal planes; muons are differentiated from electrons and hadrons by means of a steel plate. Two triggers are run simultaneously: a multiple hit coincidence trigger, rich in extensive air showers, and a single track trigger, rich in secondary muon tracks. The former trigger is sensitive to primary energies greater than ~100 TeV, the latter to energies greater than ~10 GeV.

  8. A Cinematic Grand Tour of Sicily: Irony, Memory and Metamorphic Desire from Goethe to Tornatore

    E-Print Network [OSTI]

    Marrone, Gaetana

    2010-01-01

    A Cinematic Grand Tour of Sicily: Irony, Memory, andlike, everywhere. 4 This cinematic grand tour is an album ofvarious social aims. A cinematic example of such a diversion

  9. Habitat Appraisal Guide for Rio Grande Wild Turkey 

    E-Print Network [OSTI]

    Cathey, James; Locke, Shawn; Ransom, Dean; DeMaso, Stephen; Schwertner, T. Wayne; Collier, Bret

    2007-09-04

    The Rio Grande wild turkey habitat appraisal guide gives landowners and managers a standardized, systematic way to evaluate current habitat conditions. It can be used to identify limiting factors. It also contains suggestions for improving...

  10. Estimating Rio Grande wild turkey densities in Texas 

    E-Print Network [OSTI]

    Locke, Shawn Lee

    2009-06-02

    Rio Grande wild turkeys (Meleagris gallopavo intermedia) are a highly mobile, wide ranging, and secretive species located throughout the arid regions of Texas. As a result of declines in turkey abundance within the Edwards Plateau and other areas...

  11. Integrated Reservoir Characterization: Offshore Louisiana, Grand Isle Blocks 32 & 33 

    E-Print Network [OSTI]

    Casey, Michael Chase

    2011-08-08

    This thesis integrated geology, geophysics, and petroleum engineering data to build a detailed reservoir characterization models for three gas pay sands in the Grand Isle 33 & 43 fields, offshore Louisiana. The reservoirs are Late Miocene in age...

  12. City of Grand Rapids- Green Power Purchasing Policy

    Broader source: Energy.gov [DOE]

    In 2005, the City of Grand Rapids established a goal of purchasing 20% of its municipal power demand from renewable energy by 2008. In November 2007, the city signed a three-year agreement with a...

  13. India’s Grand Strategy: Some Preliminary Thoughts

    E-Print Network [OSTI]

    HOYT, Timothy D.

    2012-01-01

    or series of shocks might push India into a similar trajec-of threats that might force India to reconsider its currentPOLICY BRIEF 5, JANUARY 2012 India’s Grand Strategy: Some

  14. Secretary Chu to Deliver Keynote on EV Everywhere Grand Challenge...

    Energy Savers [EERE]

    Launched by President Obama in March 2012, EV-Everywhere is the second in a series of Energy Department "Clean Energy Grand Challenges" aimed at addressing the most pressing...

  15. EV Everywhere EV Everywhere Grand Challenge - Electric Drive...

    Broader source: Energy.gov (indexed) [DOE]

    Agenda for the EV Everywhere Grand Challenge - Electric Drive Workshop on July 24, 2012 at the Doubletree O'Hare, Chicago, IL agendaed.pdf More Documents & Publications EV...

  16. SunShot Grand Challenge Highlights Ambitious Efforts along the...

    Office of Environmental Management (EM)

    Solar Spectrum SunShot Grand Challenge Highlights Ambitious Efforts along the Entire Solar Spectrum June 13, 2012 - 5:30pm Addthis Energy Secretary Steven Chu gives the...

  17. EA-1037: Uranium Lease Management Program, Grand Junction, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the U.S. Department of Energy's Grand Junction Projects Office's proposal to maintain and preserve the nation's immediately accessible supply of...

  18. Grand Opening of Abengoa's Biorefinery: Nation's Third Commercial...

    Office of Environmental Management (EM)

    its grand opening on October 17, 2014, in Hugoton, Kansas. The Abengoa Bioenergy Biomass of Kansas (ABBK) facility is the first of its kind to use a proprietary enzymatic...

  19. EA-1338: Transfer of the Department of Energy Grand Junction Office to Non-DOE Ownership, Grand Junction, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposed transfer of real and personal property at the U.S. Department of Energy's Grand Junction Office to non-DOE ownership.

  20. Experimental and first-principles study of ferromagnetism in Mn-doped zinc stannate nanowires

    SciTech Connect (OSTI)

    Deng Rui; Zhou Hang; Qin Jieming; Wan Yuchun; Jiang Dayong; Liang Qingcheng [School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022 (China); Li Yongfeng [Key Laboratory of Physics and Technology for Advanced Batteries, College of Physics, Jilin University, Changchun 130012 (China); Wu, Tom [Physical Sciences and Engineering Division, Solar and Photovoltaics Engineering Research Center, King Abdullah University of Science and Technology, Thuwal 23955-6900 (Saudi Arabia); Yao Bin [State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012 (China); Liu Lei [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, No.3888 Dongnanhu Road, Changchun 130033 (China)

    2013-07-21

    Room temperature ferromagnetism was observed in Mn-doped zinc stannate (ZTO:Mn) nanowires, which were prepared by chemical vapor transport. Structural and magnetic properties and Mn chemical states of ZTO:Mn nanowires were investigated by X-ray diffraction, superconducting quantum interference device (SQUID) magnetometry and X-ray photoelectron spectroscopy. Manganese predominantly existed as Mn{sup 2+} and substituted for Zn (Mn{sub Zn}) in ZTO:Mn. This conclusion was supported by first-principles calculations. Mn{sub Zn} in ZTO:Mn had a lower formation energy than that of Mn substituted for Sn (Mn{sub Sn}). The nearest neighbor Mn{sub Zn} in ZTO stabilized ferromagnetic coupling. This observation supported the experimental results.

  1. Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof 

    E-Print Network [OSTI]

    Seo, Dongmin

    2009-05-15

    This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

  2. Environmental Audit of the Grand Junction Projects Office

    SciTech Connect (OSTI)

    Not Available

    1991-08-01

    The Grand Junction Projects Office (GJPO) is located in Mesa County, Colorado, immediately south and west of the Grand Junction city limits. The US Atomic Energy Commission (AEC) established the Colorado Raw Materials Office at the present-day Grand Junction Projects Office in 1947, to aid in the development of a viable domestic uranium industry. Activities at the site included sampling uranium concentrate; pilot-plant milling research, including testing and processing of uranium ores; and operation of a uranium mill pilot plant from 1954 to 1958. The last shipment of uranium concentrate was sent from GJPO in January, 1975. Since that time the site has been utilized to support various DOE programs, such as the former National Uranium Resource Evaluation (NURE) Program, the Uranium Mill Tailings Remedial Action Project (UMTRAP), the Surplus Facilities Management Program (SFMP), and the Technical Measurements Center (TMC). All known contamination at GJPO is believed to be the result of the past uranium milling, analyses, and storage activities. Hazards associated with the wastes impounded at GJPO include surface and ground-water contamination and potential radon and gamma-radiation exposure. This report documents the results of the Baseline Environmental Audit conducted at Grand Junction Projects Office (GJPO) located in Grand Junction, Colorado. The Grand Junction Baseline Environmental Audit was conducted from May 28 to June 12, 1991, by the Office of Environmental Audit (EH-24). This Audit evaluated environmental programs and activities at GJPO, as well as GJPO activities at the State-Owned Temporary Repository. 4 figs., 12 tabs.

  3. Electron tunneling studies of Mn12-Acetate 

    E-Print Network [OSTI]

    Ma, Lianxi

    2008-10-10

    laser deposition (PLD) was used to deposit two monolayers of Mn 12 -Acetate on thin Pt wires (diame- ter 0.001 in). The electron tunneling current was measured with typical bias voltages from -1 to 1 V at liquid helium temperature, 4.2 K. I, dI/dV, and d... 2 I/dV 2 signals were directly acquired with the aid of a current amplifier and two lock-in-amplifiers. Results show that the differential conductance is approximately 10 ?6 S for bias volt- ages 0.04 V ?|V |? 1 V and exhibits a strong voltage...

  4. Spin caloritronics in graphene with Mn

    SciTech Connect (OSTI)

    Torres, Alberto Lima, Matheus P. Fazzio, A.; Silva, Antônio J. R. da

    2014-02-17

    We show that graphene with Mn adatoms trapped at single vacancies features spin-dependent Seebeck effect, thus enabling the use of this material for spin caloritronics. A gate potential can be used to tune its thermoelectric properties in a way it presents either a total spin polarized current, flowing in one given direction, or currents for both spins flowing in opposite directions without net charge transport. Moreover, we show that the thermal magnetoresistance can be tuned between ?100% and +100% by varying a gate potential.

  5. Noncommutative geometry, Grand Symmetry and twisted spectral triple

    E-Print Network [OSTI]

    Agostino Devastato

    2015-03-09

    In the noncommutative geometry approach to the standard model we discuss the possibility to derive the extra scalar field sv- initially suggested by particle physicist to stabilize the electroweak vacuum - from a "grand algebra" that contains the usual standard model algebra. We introduce the Connes-Moscovici twisted spectral triples for the Grand Symmetry model, to cure a technical problem, that is the appearance, together with the field sv, of unbounded vectorial terms. The twist makes these terms bounded, and also permits to understand the breaking making the computation of the Higgs mass compatible with the 126 GeV experimental value.

  6. Magnetic Moment Enhancement for Mn7 Cluster on Graphene

    SciTech Connect (OSTI)

    Liu, Xiaojie [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Lin, Hai-Qing [Beijing Computational Science Research Center; Ho, Kai-Ming [Ames Laboratory

    2014-08-21

    Mn7 cluster on graphene with different structural motifs and magnetic orders are investigated systematically by first-principles calculations. The calculations show that Mn7 on graphene prefers a two-layer motif and exhibits a ferrimagnetic coupling. The magnetic moment of the Mn7 cluster increases from 5.0 ?B at its free-standing state to about 6.0 ?B upon adsorption on graphene. Mn7 cluster also induces about 0.3 ?B of magnetic moment in the graphene layer, leading to an overall enhancement of 1.3 ?B magnetic moment for Mn7 on graphene. Detail electron transfer and bonding analysis have been carried out to investigate the origin of the magnetic enhancement.

  7. 2015 INTEL International Science and Engineering Fair Grand Awards

    E-Print Network [OSTI]

    Borchers, Brian

    Fractured Shale Fourth Award of $500 Edward Park, 16, Las Cruces High School, Las Cruces, New Mexico Alamos High School, Los Alamos, New Mexico Modeling Gas Flow in Hydraulically Fractured Shale Coleman J2015 INTEL International Science and Engineering Fair Grand Awards -New Mexico Finalists

  8. 2015 INTEL International Science and Engineering Fair Grand Awards

    E-Print Network [OSTI]

    Borchers, Brian

    , New Mexico Modeling Gas Flow in Hydraulically Fractured Shale Microbiology Third Award of $12015 INTEL International Science and Engineering Fair Grand Awards -New Mexico Finalists- ISEF Second Award of $1,500 Sara Manshad, 16, Arrowhead Park Early College High School, Las Cruces, New Mexico

  9. WATER COMMODIFICATION IN THE LOWER RIO GRANDE VALLEY, TEXAS 

    E-Print Network [OSTI]

    Garcia, Bianca 1989-

    2011-05-06

    The lower Rio Grande Valley of Texas is one of the poorest regions with the largest population lacking suitable water supply in the entire United States. The region is characterized by low-income, rural and peri-urban communities called colonias...

  10. Grand Challenges in Energy, Environmental and Chemical Engineering

    E-Print Network [OSTI]

    Subramanian, Venkat

    Grand Challenges in Energy, Environmental and Chemical Engineering Environmental NanoChemistry Lab Solution chemistry analysis Surface reaction observation in solution http://encl.engineering.wustl.edu/ #12; Engineering Email: ysjun@seas.wustl.edu; Website: http://encl.engineering.wustl.edu/ The ENCL aims

  11. Rio Grande Wild Turkey in Texas: Biology and Management 

    E-Print Network [OSTI]

    Cathey, James; Melton, Kyle; Dreibelbis, Justin; Cavney, Bob; Locke, Shawn; DeMaso, Stephen; Schwertner, T. Wayne; Collier, Bret

    2007-09-11

    Over-hunting greatly reduced populations of the Rio Grande Wild Turkey in Texas. Now, however, restoration efforts and harvest limits are helping the birds make a come-back, and many landowners want to know how to manage their land to encourage them...

  12. RIO GRANDE FLOODWAY SAN ACACIA TO BOSQUE DEL APACHE UNIT

    E-Print Network [OSTI]

    US Army Corps of Engineers

    REEVALUATION REPORT AND SUPPLEMENTAL ENVIRONMENTAL IMPACT STATEMENT II FINAL U.S. Army Corps of Engineers Report and Supplemental Environmental Impact Statement II (GRR/SEIS II) as well as supporting#12;RIO GRANDE FLOODWAY SAN ACACIA TO BOSQUE DEL APACHE UNIT SOCORRO COUNTY, NEW MEXICO GENERAL

  13. Digital Earth as a UCGIS Grand Challenge Karl E. Grossner

    E-Print Network [OSTI]

    Wright, Dawn Jeannine

    Digital Earth as a UCGIS Grand Challenge Karl E. Grossner University of California, Santa Barbara' are mapped to the major components of a digital earth system, and the requisite functionality of next of suggestions put forward--reprised in a sense--by Keith Clarke, was of "a Digital Earth by 2009." That year has

  14. Research Article Rio Grande Wild Turkey Habitat Selection in the

    E-Print Network [OSTI]

    Wallace, Mark C.

    Research Article Rio Grande Wild Turkey Habitat Selection in the Southern Great Plains GALON I, USA ABSTRACT We recorded telemetry locations from 1,129 radiotagged turkeys (Meleagris gallopavo have the highest impact on nesting in riparian zones due to turkey use of grass as nesting cover

  15. Data Mining: Data Analysis on a Grand Scale? Padhraic Smyth

    E-Print Network [OSTI]

    Smyth, Padhraic

    Data Mining: Data Analysis on a Grand Scale? Padhraic Smyth Information and Computer Science informationfrommassiveobservationaldatasets. Because of this historical context, data mining to date has largely focused on computational a brief review of the origins of data mining as well as discussing some of the primary themes in current

  16. Carbonaceous aerosol particles from common vegetation in the Grand Canyon

    SciTech Connect (OSTI)

    Hallock, K.A.; Mazurek, M.A. (Brookhaven National Lab., Upton, NY (United States)); Cass, G.R. (California Inst. of Tech., Pasadena, CA (United States). Dept. of Environmental Engineering Science)

    1992-05-01

    The problem of visibility reduction in the Grand Canyon due to fine organic aerosol particles in the atmosphere has become an area of increased environmental concern. Aerosol particles can be derived from many emission sources. In this report, we focus on identifying organic aerosols derived from common vegetation in the Grand Canyon. These aerosols are expected to be significant contributors to the total atmospheric organic aerosol content. Aerosol samples from living vegetation were collected by resuspension of surface wax and resin components liberated from the leaves of vegetation common to areas of the Grand Canyon. The samples were analyzed using high-resolution gas chromatography/mass spectrometry (GC/MS). Probable identification of compounds was made by comparison of sample spectra with National Institute of Standards and Technology (NIST) mass spectral references and positive identification of compounds was made when possible by comparison with authentic standards as well as NIST references. Using these references, we have been able to positively identify the presence of n-alkane and n-alkanoic acid homolog series in the surface waxes of the vegetation sampled. Several monoterpenes, sesquiterpenes, and diterpenes were identified also as possible biogenic aerosols which may contribute to the total organic aerosol abundance leading to visibility reduction in the Grand Canyon.

  17. Magnetic coupling in neutral and charged Cr{sub 2}, Mn{sub 2}, and CrMn dimers

    SciTech Connect (OSTI)

    Desmarais, N. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Reuse, F. A. [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland)] [Institut de Physique Experimentale, Ecole Polytechnique Federale de Lausanne, PHB-Ecublens, CH-1015 Lausanne, (Switzerland); Khanna, S. N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    2000-04-01

    Theoretical ab initio studies of neutral, cationic and anionic Cr{sub 2}, Mn{sub 2}, and CrMn dimers have been carried out to explore the progression of magnetic coupling with the number of electrons. It is shown that while Cr{sub 2} and Cr{sub 2}{sup -} have antiferromagnetically coupled atomic spins, Cr{sub 2}{sup +} has a ferromagnetic ground state closely followed by an antiferromagnetic state. On the other hand, all Mn{sub 2} dimers are ferromagnetic, irrespective of the charge. The neutral CrMn is ferrimagnetic while the charged CrMn are antiferromagnetic. In all cases, the charged dimers are found to be more stable than the neutral ones. The results are compared with available calculations and experiments and the difficulties associated with theoretical description and the experimental interpretations are discussed. (c) 2000 American Institute of Physics.

  18. Grand Challenges in Global Health Grand Challenges Projects > Control Insect Vectors > Chemical Strategy Site Map | Quick Search

    E-Print Network [OSTI]

    Strategy Site Map | Quick Search: Improve Vaccines - Single-Dose Vaccines - Heat-Stable Vaccines - Needle. Grand Challenge #8: Develop a Chemical Strategy to Control Insects Disruption of Malaria Transmission, and low-cost mosquito repellants that will reduce malaria transmission in endemic areas. Molecular

  19. Research Article Male Rio Grande Turkey Survival and Movements in the

    E-Print Network [OSTI]

    Wallace, Mark C.

    Research Article Male Rio Grande Turkey Survival and Movements in the Texas Panhandle, USA Abstract Wildlife managers depend on accurate information regarding wild turkey (Meleagris gallopavo) survival patterns to properly manage turkey populations. Survival patterns of male Rio Grande

  20. Charging Up For Formula Sun Grand Prix By Jonathan Nutzmann, Project Manager

    E-Print Network [OSTI]

    Janssen, Michel

    Charging Up For Formula Sun Grand Prix By Jonathan Nutzmann, Project Manager The team is currently busy with training for our next race, Formula Sun Grand Prix, which is com- ing up May 2nd-7th

  1. A Geomorphological Assessment of Armored Deposits Along the Southern Flanks of Grand Mesa, CO, USA 

    E-Print Network [OSTI]

    Brunk, Timothy J.

    2011-08-08

    A series of deposits, located along the southern flanks of Grand Mesa, Colorado, and extending to the south, are problematic, and the processes related to emplacement are not understood. The overall area is dominated by two landform systems, Grand...

  2. Top 5 Reasons to Attend the SunShot Grand Challenge Solar Summit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Top 5 Reasons to Attend the SunShot Grand Challenge Solar Summit Top 5 Reasons to Attend the SunShot Grand Challenge Solar Summit May 5, 2014 - 12:16pm Addthis

  3. Estimating commuter rail demand to Kendall Square along the Grand Junction Corridor

    E-Print Network [OSTI]

    Bockelie, Adam

    2012-01-01

    Since acquiring the Grand Junction Railroad in June 2010 from CSX, the Massachusetts Bay Transit Authority (MBTA) has explored the possibility of using the line for commuter rail service. In addition the Grand Junction ...

  4. Solar Community Comes Out in Full Force for SunShot Grand Challenge...

    Energy Savers [EERE]

    Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit Solar Community Comes Out in Full Force for SunShot Grand Challenge Summit May 22, 2014 - 9:58am Addthis...

  5. DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for...

    Energy Savers [EERE]

    DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the Advanced Biofuels Industry DuPont's Cellulosic Ethanol Grand Opening Marks a Milestone for the Advanced Biofuels...

  6. Grand Challenge for Basic and Applied Research in Hydrogen Storage: Statement of Objectives

    Broader source: Energy.gov [DOE]

    Statement of objectives for the Grand Challenge for Basic and Applied Research in Hydrogen Storage issued in 2003.

  7. Grand Traverse Band Renewable Energy Feasibility Study in Wind, Biomass and Solar

    SciTech Connect (OSTI)

    Suzanne McSawby, Project Director Steve Smiley, Principle Investigator Grand Traverse Resort, Cost Sharing Partner

    2008-12-31

    Renewable Energy Feasibility Study for wind, biomass, solar on the Grand Traverse Band tribal lands from 2005 - 2008

  8. The Construction and Maintenance Plan for a Grand Banks Multi-Purpose Pipeline

    E-Print Network [OSTI]

    Bruneau, Steve

    The Construction and Maintenance Plan for a Grand Banks Multi-Purpose Pipeline D.W. (Don) Wilson, Director, North Atlantic Pipeline Partners, L.P. NOIA 2000 Conference June, 2000 #12;Grand Banks Multi-Purpose Pipeline Route January 2000 Grand Banks of Newfoundland Newfoundland Come by Chance St. John's Argentia 50o

  9. A New Species of Parodia (Cactaceae, Notocacteae) from Rio Grande do Sul, Brazil

    E-Print Network [OSTI]

    Zürich, Universität

    A New Species of Parodia (Cactaceae, Notocacteae) from Rio Grande do Sul, Brazil Marlon C. Machado Grande do Sul, Brazil. jlarocca@unisinos.br ABSTRACT . A new species, Parodia gaucha M. Machado & Larocca (Cactaceae, Notocacteae), from Encruzilhada do Sul, Rio Grande do Sul, Brazil, is described and illustrated

  10. Grand Challenges and Opportunities Supply Chain Networks: From Analysis to Design

    E-Print Network [OSTI]

    Nagurney, Anna

    Challenges in Supply Chain Networks #12;Energy Supply Chains Anna Nagurney Grand Challenges in Supply ChainGrand Challenges and Opportunities in Supply Chain Networks: From Analysis to Design Anna Nagurney of Technology Gothenburg, Sweden, March 4, 2013 Anna Nagurney Grand Challenges in Supply Chain Networks #12

  11. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01

    Mn-Si (red squares) and Mn-Ge distances (blue circles) d asof the number of Si or Ge nearest neighbours N c ; (c) localthree Mn atoms with different N c in a-Mn 0.094 Ge 0.906 .

  12. Study of the beta delayed particle emission from 48Mn and its relevance for explosive nucleosynthesis

    E-Print Network [OSTI]

    Martel, I

    2015-01-01

    Study of the beta delayed particle emission from 48Mn and its relevance for explosive nucleosynthesis

  13. Inverse spin Hall effect in Pt/(Ga,Mn)As

    SciTech Connect (OSTI)

    Nakayama, H.; Chen, L.; Chang, H. W.; Ohno, H.; Matsukura, F.

    2015-06-01

    We investigate dc voltages under ferromagnetic resonance in a Pt/(Ga,Mn)As bilayer structure. A part of the observed dc voltage is shown to originate from the inverse spin Hall effect. The sign of the inverse spin Hall voltage is the same as that in Py/Pt bilayer structure, even though the stacking order of ferromagnetic and nonmagnetic layers is opposite to each other. The spin mixing conductance at the Pt/(Ga,Mn)As interface is determined to be of the order of 10{sup 19?}m{sup ?2}, which is about ten times greater than that of (Ga,Mn)As/p-GaAs.

  14. City of Grand Rapids Building Solar Roof Demonstration

    SciTech Connect (OSTI)

    DeClercq, Mark; Martinez, Imelda

    2012-08-31

    Grand Rapids, Michigan is striving to reduce it environmental footprint. The municipal government organization has established environmental sustainability policies with the goal of securing 100% of its energy from renewable sources by 2020. This report describes the process by which the City of Grand Rapids evaluated, selected and installed solar panels on the Water/Environmental Services Building. The solar panels are the first to be placed on a municipal building. Its new power monitoring system provides output data to assess energy efficiency and utilization. It is expected to generate enough clean solar energy to power 25 percent of the building. The benefit to the public includes the economic savings from reduced operational costs for the building; an improved environmentally sustainable area in which to live and work; and increased knowledge about the use of solar energy. It will serve as a model for future energy saving applications.

  15. The Lower Rio Grande Valley Regional Public Transportation Coordination Plan 

    E-Print Network [OSTI]

    Lower Rio Grande Valley Development Council

    2006-11-30

    . Prepared By Lago Elsa Solis Pharr Muniz Donna Bixby Alton Alamo Olmito Lozano Yznaga Lyford Lasana Combes Lasara Encino Havana Bayview Primera Weslaco Nurillo Mission McAllen La Homa Hidalgo Edcouch Penitas Laureles Willamar Ratamosa La Feria Scissors... Isidro Port Isabel South Point Los Fresnos Indian Lake Brownsville Palm Valley Grand Acres Santa Maria Rangerville Arroyo Alto San Perlita Villa Verde South Alamo North Alamo Laguna Seca Citrus City Alton North Villa Pancho Rancho Viejo Laguna Vista...

  16. Grand Blanc Generating Station Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New PagesSustainableGlynn County, Georgia: EnergyGorlitz AGGranby, Connecticut: EnergyGrand

  17. EV Everywhere Grand Challenge Kick-Off | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|DepartmentStatementofApril 25, 2014TEMPLATE|Off EV Everywhere Grand

  18. Grand Coulee-Creston_FONSI_and_MAP_27May2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive CompensationEnergyGet Current:5Logging Systems (December4Grand

  19. Electronic interactions between gold films and mn12-acetate 

    E-Print Network [OSTI]

    Means, Joel Lewis

    2009-05-15

    Interactions between Mn12–acetate molecular magnets and thin gold films have been explored in light of the theory of weak localization. Low-temperature measurements of the magnetoresistance of gold films of varying thicknesses, with and without...

  20. Deciphering Solar Magnetic Activity: On Grand Minima in Solar Activity

    E-Print Network [OSTI]

    McIntosh, Scott W

    2015-01-01

    The Sun provides the energy necessary to sustain our existence. While the Sun provides for us, it is also capable of taking away. The weather and climatic scales of solar evolution and the Sun-Earth connection are not well understood. There has been tremendous progress in the century since the discovery of solar magnetism - magnetism that ultimately drives the electromagnetic, particulate and eruptive forcing of our planetary system. There is contemporary evidence of a decrease in solar magnetism, perhaps even indicators of a significant downward trend, over recent decades. Are we entering a minimum in solar activity that is deeper and longer than a typical solar minimum, a "grand minimum"? How could we tell if we are? What is a grand minimum and how does the Sun recover? These are very pertinent questions for modern civilization. In this paper we present a hypothetical demonstration of entry and exit from grand minimum conditions based on a recent analysis of solar features over the past 20 years and their p...

  1. Environmental assessment of facility operations at the U.S. Department of Energy Grand Junction Projects Office, Grand Junction, Colorado

    SciTech Connect (OSTI)

    1996-06-01

    The US Department of Energy (DOE) has prepared a sitewide environmental assessment (EA) of the proposed action to continue and expand present-day activities on the DOE Grand Junction Projects Office (GJPO) facility in Grand Junction, Colorado. Because DOE-GJPO regularly proposes and conducts many different on-site activities, DOE decided to evaluate these activities in one sitewide EA rather than in multiple, activity-specific documents. On the basis of the information and analyses presented in the EA, DOE has determined that the proposed action does not constitute a major Federal action significantly affecting the quality of the human environment, as defined by the National Environmental Policy Act (NEPA) of 1969. Therefore, preparation of an environmental impact statement is not required for facility operations, and DOE is issuing this Finding of No Significant Impact (FONSI).

  2. Ambi-site substitution of Mn in lanthanum germanate apatites

    SciTech Connect (OSTI)

    Kendrick, E. [Chemical Sciences, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot OX11 0QX (United Kingdom); Slater, P.R., E-mail: p.r.slater@bham.ac.uk [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

    2009-08-05

    A neutron diffraction study at 4 K of the Mn doped lanthanum germanate apatite-type oxide ion conductor of nominal starting composition 'La{sub 9.5}Mn{sub 0.5}(GeO{sub 4}){sub 6}O{sub 2.75}' is reported. The structure was refined in space group P6{sub 3}/m, although high thermal displacement parameters were observed for the oxide ion sites (particularly O3, and O4). Reduced thermal displacement parameters were obtained by splitting the O3 site, and allowing the O4 oxygen to move off site, which may indicate local regions of lower symmetry within the structure. In addition, the data suggested ambi-site substitution of Mn, with it being present on both the Ge site and the La site. Assuming no change in La:Mn:Ge ratio, a composition of La{sub 9.18}Mn{sub 0.28}(GeO{sub 4}){sub 5.8}(MnO{sub 4}){sub 0.2}O{sub 2} was determined. As such there are nominally no interstitial oxide ions, but rather cation vacancies on the La site. Therefore, the high conductivity for this sample is most likely related to the introduction of Frenkel-type defects at higher temperature, as previously proposed for other apatite-type systems containing vacancies on the La site.

  3. Comparison of the EXAFS Spectra of Heteronuclear MnCa/Sr Model Complexes to the Oxygen-Evolving Mn(4)Ca Complex of Photosystem II

    SciTech Connect (OSTI)

    Mishra, A.; Yano, J.; Pushkar, Y.; Abboud, K.A.; Yachandra, V.K.; Christou, G.

    2009-06-03

    Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.

  4. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01

    Magnetization data for a-Mn 0.15 Ge 0.85 ?lms mea- suredSi 1?x and a-Mn x Ge 1?x samples. . . . . . . . . . . . . .both a-Mn x Si 1?x and a-Mn x Ge 1?x as a func- tion of Mn

  5. Segregation of Mn2+ Dopants as Interstitials in SrTiO3 Grain Boundaries

    SciTech Connect (OSTI)

    Yang, Hao; Kotula, Paul G.; Sato, Yukio; Chi, Miaofang; Ikuhara, Yuichi; Browning, Nigel D.

    2013-10-03

    Mn doped SrTiO3 shows promising magnetic and electrical properties, but the doping mechanism remains unclear. In this research Mn4+ is found to substitute Ti in bulk SrTiO3, but Mn2+ segregates inside grain boundaries at both Sr and interstitial sites. Mn interstitial doping has never been reported, but is found possible with the formation of Sr vacancies. This finding is significantly different from the amphoteric doping of Mn2+ substituting Sr and Mn4+ substituting Ti sites, therefore leads to different understanding on the defect mediated electrical and magnetic properties of transition metal doped perovskites.

  6. Functional Mn–Mg{sub k} cation complexes in GaN featured by Raman spectroscopy

    SciTech Connect (OSTI)

    Devillers, T. Bonanni, A.; Leite, D. M. G.; Department of Physics, São Paulo State University, Bauru–SP ; Dias da Silva, J. H.

    2013-11-18

    The evolution of the optical branch in the Raman spectra of (Ga,Mn)N:Mg epitaxial layers as a function of the Mn and Mg concentrations, reveals the interplay between the two dopants. We demonstrate that the various Mn-Mg-induced vibrational modes can be understood in the picture of functional Mn–Mg{sub k} complexes formed when substitutional Mn cations are bound to k substitutional Mg through nitrogen atoms, the number of ligands k being driven by the ratio between the Mg and the Mn concentrations.

  7. Citrus Varieties for the Lower Rio Grande Valley. 

    E-Print Network [OSTI]

    Wood, J. F. (John Fielding); Friend, W. H. (William Heartsill)

    1941-01-01

    TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR, College Station, Texas CITRUS VARIETIES FOR THE LOWER RIO GRANDE VALLEY Mr. H. FRIEND AND J. F. WOOD Division of Horticulture LIBRARY \\gxict~!baa! % khhani~al Callep oof TsM~: Co.... Limes and lemons may be grown by persons who are financially able to equip their orchards with heaters. There are many types of citrus fruits that may be grown as ornamentals or for special purposes, but none of these are of com- mercial importance...

  8. Grande Ronde Endemic Spring Chinook Project - ODFW, 2008 Annual Report.

    SciTech Connect (OSTI)

    Patterson, Scott

    2009-04-10

    Core activities of the Grande Ronde Endemic Spring Chinook Supplementation Program (GRESCSP) are funded through the authority of the Lower Snake River Fish and Wildlife Compensation Plan (LSRCP). The LSRCP program was approved by the Water Resources Development Act of 1976, PL 94-587, Section 102, 94th Congress substantially in accordance with the Special Report, LSRCP, June 1975 on file with the Chief of Engineers. The LSRCP was prepared and submitted in compliance with the Fish and Wildlife Coordination Act of 1958, PL 85-624, 85th Congress, August 12, 1958 to mitigate for the losses of fish and wildlife caused by the construction of dams on lower Snake River. The GRESCSP is an artificial propagation program that was initiated by Bonneville Power Administrations Fish and Wildlife program in the mid 1990's. The intent of this program was to change the mitigation aspect of the LSRCP program (harvest mitigation) to an integrated supplementation program; inasmuch as, hatchery produced fish could be experimentally used as a recovery tool and fish surplus to mitigation would be available for in-place and in-kind harvest. Fish production is still authorized by the LSRCP with the original mitigation return goal of 5,860 adult spring Chinook to the project area. The GRESCSP was developed with two primary components: (1) conventional broodstock (projects 199800702; 199800703; 199800704) and (2) captive brood (projects 199801001; 199801006). The GRESCSP relies on cooperative M&E efforts from the LSRCP including setting aside the Wenaha and Minam tributaries as natural production reserves components used for reference streams. The GRESCSP, coordinated with federal and tribal partners, identifies production levels for both propagation components and weir management strategies for each of the three supplemented tributary areas within the Grande Ronde Sub-basin. The three supplemented areas are Catherine Creek, Lostine River, and upper Grande Ronde River. Lookingglass Creek, an extirpated area, will be stocked (smolts and adults) with Catherine Creek origin salmon to initiate natural production in unseeded habitat, and to initiate future harvest opportunities. The current production levels have been incorporated into the U.S. v. Oregon Interim Management Agreement. The purpose of this contract is to integrate Bonneville Power Administration (BPA) efforts with the Lower Snake River Compensation Plan (LSRCP) program utilizing Lookingglass Hatchery as the primary rearing facility. BPA constructed an adult holding and spawning structure on the hatchery grounds; however, maintenance of this infrastructure was discontinued due to funding limitation and transferred to the LSRCP program in 2007. These integrated efforts focus on holding and spawning adults, rearing juveniles, fish health, and monitoring natural production (Redd counts) for Catherine Creek, Lostine River, and Upper Grande Ronde stocks.

  9. Rio Grande, New Jersey: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, New York:Virginia: EnergyRidgeviewRincon DeJump to:Grande, New

  10. City of Grand Island, Nebraska (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtdEllsworth, IowaGraettinger, Iowa (Utility Company)Grand Island,

  11. City of Grand Junction, Iowa (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtdEllsworth, IowaGraettinger, Iowa (Utility Company)Grand

  12. Arroyo Grande, California: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAandAmminex A SOpen Energy InformationArpin,Arroyo Grande, California:

  13. Casa Grande, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,Cammack Village, Arkansas:FundMichigan:North Carolina:Wisconsin:Grande,

  14. EV Everywhre Grand Challenge - Battery Status and Cost Reduction Prospects

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n cEnergy (AZ, CA,EnergystudentThis the AssistantEV Everywhere Grand

  15. Grand Junction, Colorado, Processing Site and Disposal Sites Fact Sheet

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M P R E H E N S I551Grand Junction,

  16. Grand Challenges | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thIWalter H. Zinn,ChristopherDOE Office ofHistoryGrand

  17. SunShot Grand Challenge | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment ofOffice|inWestMayBuilding K-25KyleEnergyHangoutSunShot Grand

  18. Spectroscopic variability and magnetic fields of HgMn stars

    E-Print Network [OSTI]

    Hubrig, S; Ilyin, I; Korhonen, H; Savanov, I S; Dall, T; Schoeller, M; Cowley, C R; Briquet, M; Arlt, R

    2011-01-01

    The discovery of exotic abundances, chemical inhomogeneities, and weak magnetic fields on the surface of late B-type primaries in spectroscopic binaries has important implications not only for our understanding of the formation mechanisms of stars with Hg and Mn peculiarities themselves, but also for the general understanding of B-type star formation in binary systems. The origin of the abundance anomalies observed in late B-type stars with HgMn peculiarity is still poorly understood. The connection between HgMn peculiarity and membership in binary and multiple systems is supported by our observations during the last decade. The important result achieved in our studies of a large sample of HgMn stars is the finding that most HgMn stars exhibit spectral variability of various chemical elements, proving that the presence of an inhomogeneous distribution on the surface of these stars is a rather common characteristic and not a rare phenomenon. Further, in the studied systems, we found that all components are che...

  19. The blue supergiant MN18 and its bipolar circumstellar nebula

    E-Print Network [OSTI]

    Gvaramadze, V V; Bestenlehner, J M; Bodensteiner, J; Langer, N; Greiner, J; Grebel, E K; Berdnikov, L N; Beletsky, Y

    2015-01-01

    We report the results of spectrophotometric observations of the massive star MN18 revealed via discovery of a bipolar nebula around it with the Spitzer Space Telescope. Using the optical spectrum obtained with the Southern African Large Telescope, we classify this star as B1 Ia. The evolved status of MN18 is supported by the detection of nitrogen overabundance in the nebula, which implies that it is composed of processed material ejected by the star. We analysed the spectrum of MN18 by using the code CMFGEN, obtaining a stellar effective temperature of \\approx 21 kK. The star is highly reddened, E(B-V)\\approx 2 mag. Adopting an absolute visual magnitude of M_V=-6.8\\pm0.5 (typical of B1 supergiants), MN18 has a luminosity of log L/Lsun \\approx 5.42\\pm0.30, a mass-loss rate of \\approx (2.8-4.5)\\times10^{-7} Msun/yr, and resides at a distance of \\approx 5.6^{+1.5} _{-1.2} kpc. We discuss the origin of the nebula around MN18 and compare it with similar nebulae produced by other blue supergiants in the Galaxy (She...

  20. Synthesis, characterization and electrochemical performance of Al-substituted Li?MnO?

    SciTech Connect (OSTI)

    Dhital, Chetan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Huq, Ashfia [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Paranthaman, Mariappan Parans [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Manivannan, Ayyakkannu [National Energy Technology Lab. (NETL), Morgantown, WV (United States); West Virginia Univ., Morgantown, WV (United States); Torres-Castro, Loraine [Univ. of Puerto Rico, San Juan (Puerto Rico); Shojan, Jifi [Univ. of Puerto Rico, San Juan (Puerto Rico); Julien, Christian M. [Univ. Pierre et Marie Curie, Paris (France); Katiyar, Ram S. [Univ. of Puerto Rico, San Juan (Puerto Rico)

    2015-01-01

    Li?MnO? is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li?MnO?, Li1.5Al0.17MnO?, Li1.0Al0.33MnO? and Li0.5Al0.5MnO? were synthesized by a sol-gel Pechini method. All the samples were characterized with XRD, Raman, XPS, SEM, Tap density and BET analyzer. XRD patterns indicated the presence of monoclinic phase for pristine Li?MnO? and mixed monoclinic/spinel phases (Li2-xMn1-yAlx+yO3+z) for Al-substituted Li?MnO? compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. XPS analysis for Mn 2p orbital reveal a significant decrease in binding energy for Li1.0Al0.33MnO? and Li0.5Al0.5MnO? compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g?¹ for Li?MnO?, 68mAh g?¹ for Li1.5Al0.17MnO?, 58 mAh g?¹ for Li1.0Al0.33MnO? and 74 mAh g?¹ for Li0.5Al0.5MnO? were obtained. Aluminum substitutions increased the discharge capacity and the spinel phase.

  1. Synthesis, characterization and electrochemical performance of Al-substituted Li?MnO?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectronmore »spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. Aluminum substitutions increased the formation of spinel phase which is responsible for cycling.« less

  2. Geomorphology of plutonium in the Northern Rio Grande

    SciTech Connect (OSTI)

    Graf, W.L.

    1993-03-01

    Nearly all of the plutonium in the natural environment of the Northern Rio Grande is associated with soils and sediment, and river processes account for most of the mobility of these materials. A composite regional budget for plutonium based on multi-decadal averages for sediment and plutonium movement shows that 90 percent of the plutonium moving into the system is from atmospheric fallout. The remaining 10 percent is from releases at Los Alamos. Annual variation in plutonium flux and storage exceeds 100 percent. The contribution to the plutonium budget from Los Alamos is associated with relatively coarse sediment which often behaves as bedload in the Rio Grande. Infusion of these materials into the main stream were largest in 1951, 1952, 1957, and 1968. Because of the schedule of delivery of plutonium to Los Alamos for experimentation and weapons manufacturing, the latter two years are probably the most important. Although the Los Alamos contribution to the entire plutonium budget was relatively small, in these four critical years it constituted 71--86 percent of the plutonium in bedload immediately downstream from Otowi.

  3. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

    1987-01-01

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  4. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lendinez, S.; Billinge, S. J. L.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

    2015-01-06

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amore »single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.« less

  5. HgMn Stars as apparent X-ray emitters

    E-Print Network [OSTI]

    Hubrig, S; Mathys, G

    1998-01-01

    In the ROSAT all-sky survey 11 HgMn stars were detected as soft X-ray emitters (Berghoefer, Schmitt & Cassinelli 1996). Prior to ROSAT, X-ray observations with the Einstein Observatory had suggested that stars in the spectral range B5-A7 are devoid of X-ray emission. Since there is no X-ray emitting mechanism available for these stars (also not for HgMn stars), the usual argument in the case of an X-ray detected star of this spectral type is the existence of an unseen low-mass companion which is responsible for the X-ray emission. The purpose of the present work is to use all available data for our sample of X-ray detected HgMn stars and conclude on the nature of possible companions.

  6. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    SciTech Connect (OSTI)

    Lendinez, S. [Univ. de Barcelona, Barcelona, Spain (Europe); Billinge, S. J. L. [Columbia Univ., New York, NY (United States); Zarzuela, R. [Univ. de Barcelona, Barcelona, Spain (Europe); Tejada, J. [Univ. de Barcelona, Barcelona, Spain (Europe); Terban, M. W. [Columbia Univ., New York, NY (United States); Espin, J. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Imaz, I. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Maspoch, D. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Chudnovsky, E. M. [City Univ. of New York, Bronx, NY (United States)

    2015-01-01

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for a single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.

  7. 'Grand Challenge' for Basic and Applied Research in Hydrogen Storage Solicitation

    Broader source: Energy.gov [DOE]

    DOE is issuing a Grand Challenge to the scientific community by soliciting Applications for research, development and demonstration of hydrogen storage materials and technologies. In addition to...

  8. Feasibility for Reintroducing Sockeye and Coho Salmon in the Grande Ronde Basin, 1998 Final Report.

    SciTech Connect (OSTI)

    Cramer, Steven P.; Witty, Kenneth L.

    1998-07-01

    A report concerning the feasibility of reintroducing Sockeye Salmon into Wallowa Lake and Coho Salmon into the Grande Ronde River Basin.

  9. EIS-0344: Grand Coulee-Bell 500 kV Transmission Line

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed action for the construction and operation of the proposed Grand Coulee-Bell 500-kV Transmission Line Project.

  10. Assessment of the Diffusive Gradients in Thin-films (DGT) technique to assess the plant availability of Mn in soils.

    E-Print Network [OSTI]

    Mundus, Simon; Husted, Søren; Lombi, Enzo

    2009-01-01

    predicts copper availability to plants. EnvironmentalAttempts to assess Mn availability have been impeded due towill influence the Mn availability. Often flooding of soils

  11. Ferromagnetism in Mn-Implanted Epitaxially Grown Ge on Si(100)

    E-Print Network [OSTI]

    Guchhait, S.

    2011-01-01

    segregation in Mn-doped Ge”, Journal of Applied Physics 101,Room-temperature ferromagnetism in Ge 1-x Mn x nanowires”,BC high-?/metal gate Ge/C alloy pMOSFETs fabricated directly

  12. Single-molecule magnets assembled from oxime stabilized Mn?III triangles

    E-Print Network [OSTI]

    Stephenson, Casey Justin

    2009-01-01

    100, 157203. Chapter Three “Double-Decker” [NX 4 ] 2 [Mn 8 (76 Chapter Three “Double-Decker” [NX 4 ] 2 [Mn 8 (salox) 6 Opacking effects in two “double decker” complexes of the

  13. Electrodeposited Al-Mn Alloys with Microcrystalline, Nanocrystalline, Amorphous and Nano-quasicrystalline Structures

    E-Print Network [OSTI]

    Ruan, Shiyun

    Al–Mn alloys with Mn content ranging from 0 to 15.8 at.% are prepared by electrodeposition from an ionic liquid at room temperature, and exhibit a remarkably broad range of structures. The alloys are characterized through ...

  14. Activation of a MnO2 cathode by water-stimulated Mg2+ insertion...

    Office of Scientific and Technical Information (OSTI)

    Activation of a MnO2 cathode by water-stimulated Mg2+ insertion for a magnesium ion battery Citation Details In-Document Search Title: Activation of a MnO2 cathode by...

  15. X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation...

    Office of Scientific and Technical Information (OSTI)

    X-Ray Spectroscopy of the Mn(4) Ca Cluster in the Water-Oxidation Complex of Photosystem II Citation Details In-Document Search Title: X-Ray Spectroscopy of the Mn(4) Ca Cluster in...

  16. Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal

    E-Print Network [OSTI]

    , and absorption spectroscopy. Fe is speciated as goethite, and Mn as romanechite (psilomelane) and 10 A is separated from the other type by goethite. The binary Mn oxide banding pattern is interpreted by a two

  17. In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function...

    Office of Scientific and Technical Information (OSTI)

    In-situ Electrical Conductivity of LixMnO2 Nanowires as a Function of "x" and Size Citation Details In-Document Search Title: In-situ Electrical Conductivity of LixMnO2 Nanowires...

  18. Mn12-acetate thin film patterns and their interaction with superconductors 

    E-Print Network [OSTI]

    Kim, Kyongwan

    2009-05-15

    Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

  19. Magnetization relaxation in (Ga,Mn)As ferromagnetic semiconductors 

    E-Print Network [OSTI]

    Sinova, Jairo; Jungwirth, T.; Liu, X.; Sasaki, Y.; Furdyna, JK; Atkinson, WA; MacDonald, AH.

    2004-01-01

    stream_source_info PhysRevB.69.085209.pdf.txt stream_content_type text/plain stream_size 32392 Content-Encoding ISO-8859-1 stream_name PhysRevB.69.085209.pdf.txt Content-Type text/plain; charset=ISO-8859-1 n . s re... of the theory of the Mn spin- wave dispersion, and reflect the retarded and nonlocal char- acter of the valence-band-hole mediated interactions between Mn moments.11 The Gilbert damping of magnetization pre- cession discussed here is the aspect of this long...

  20. Mixing antiferromagnets to tune NiFe-[IrMn/FeMn] interfacial spin-glasses, grains thermal stability, and related exchange bias properties

    SciTech Connect (OSTI)

    Akmaldinov, K.; Ducruet, C.; Portemont, C.; Joumard, I.; Prejbeanu, I. L.; Dieny, B.; Baltz, V.

    2014-05-07

    Spintronics devices and in particular thermally assisted magnetic random access memories require a wide range of ferromagnetic/antiferromagnetic (F/AF) exchange bias (EB) properties and subsequently of AF materials to fulfil diverse functionality requirements for the reference and storage. For the reference layer, large EB energies and high blocking temperature (T{sub B}) are required. In contrast, for the storage layer, mostly moderate T{sub B} are needed. One of the present issues is to find a storage layer with properties intermediate between those of IrMn and FeMn and in particular: (i) with a T{sub B} larger than FeMn for better stability at rest-T but lower than IrMn to reduce power consumption at write-T and (ii) with improved magnetic interfacial quality, i.e., with reduced interfacial glassy character for lower properties dispersions. To address this issue, the EB properties of F/AF based stacks were studied for various mixed [IrMn/FeMn] AFs. In addition to EB loop shifts, the F/AF magnetic interfacial qualities and the AF grains thermal stability are probed via measurements of the low- and high-temperature contributions to the T{sub B} distributions, respectively. A tuning of the above three parameters is observed when evolving from IrMn to FeMn via [IrMn/FeMn] repetitions.

  1. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01

    ferromagnetic Mn 5 Ge 3 for spintronic applications. Phys.dopants of interest for spintronic applications, where both

  2. Disentangling the Mn moments on different sublattices in the half-metallic ferrimagnet Mn3?xCoxGa

    SciTech Connect (OSTI)

    Klaer, P.; Jenkins, C.A.; Alijani, V.; Winterlik, J.; Balke, B.; Felser, C.; Elmers, H.J.

    2011-05-03

    Ferrimagnetic Mn{sub 3-x}Co{sub x}Ga compounds have been investigated by magnetic circular dichroism in x-ray absorption (XMCD). Compounds with x > 0.5 crystallize in the CuHg{sub 2}Ti structure. A tetragonal distortion of the cubic structure occurs for x {le} 0.5. For the cubic phase, magnetometry reveals a linearly increasing magnetization of 2x Bohr magnetons per formula unit obeying the generalized Slater-Pauling rule. XMCD confirms the ferrimagnetic character with Mn atoms occupying two different sublattices with antiparallel spin orientation and different degrees of spin localization and identifies the region 0.6 < x {le} 0.8 as most promising for a high spin polarization at the Fermi level. Individual Mn moments on inequivalent sites are compared to theoretical predictions.

  3. Electrochemical Performance of LiMnPO[subscript 4] Synthesized with Off-Stoichiometry

    E-Print Network [OSTI]

    Kang, Byoungwoo

    LiMnPO[subscript 4] was synthesized from an off-stoichiometric mix of starting materials with nominal composition LiMn[subscript 0.9]P[subscript 0.95]O[subscript 4??]. Stoichiometric LiMnPO[subscript 4] with particle size ...

  4. Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}

    SciTech Connect (OSTI)

    López, C.A.; Saleta, M.E.; Pedregosa, J.C.; Sánchez, R.D.; Alonso, J.A.; and others

    2014-02-15

    We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?Mn–O?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. • Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. • Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

  5. Grand Unification of AGN and the Accretion and Spin Paradigms

    E-Print Network [OSTI]

    David L. Meier

    1999-08-26

    While attempts to unify certain classes of AGN using orientation and environmental effects have been successful, it is widely recognized that intrinsic properties of the accreting black hole system also must play a role in determining the appearance of such an object. In addition to mass and accretion rate, the angular momentum (or spin) of the black hole can play a crucial role in determining the power of a relativistic jet that is generated by magnetohydrodynamic acceleration near the hole. In this paper a scenario is presented, based on accretion theory and recent models of MHD jet production, in which the primary (although not only) parameter differentiating between radio loud and quiet objects is the black hole spin, and that determining quasar vs. radio galaxy is the accretion rate. A surprising number of desirable features result from these simple concepts and the accompanying equations. In addition, there are several testable predictions that can determine whether this grand unification scheme has further merit.

  6. Growing the renewable chemicals and advanced biofuels cluster in MN

    E-Print Network [OSTI]

    Levinson, David M.

    Growing the renewable chemicals and advanced biofuels cluster in MN #12;Renewable Chemical Value% Reduction 60% Reduction 0% 10% 20% 30% 40% 50% 60% 70% 80% 90% 100% Gasoline Corn Ethanol Advanced Biofuel Cellulosic Biofuel Corn Ethanol 20% GHG Reduction Compared to gasoline: Advanced Biofuel 50% GHG Reduction e

  7. J. Field Ornithol. 76(1):1220, 2005 Survival of Rio Grande Wild Turkey chicks

    E-Print Network [OSTI]

    Wallace, Mark C.

    12 J. Field Ornithol. 76(1):12­20, 2005 Survival of Rio Grande Wild Turkey chicks Brian L. Spears,1 determined pre-flight daily survival of Rio Grande Wild Turkey (Meleagris gallopavo intermedia) chicks from, survival, telemetry, turkey Increasing population recruitment through reproductive success is often key

  8. Efficient Irrigation for Water Conservation in the Rio Grande Basin: 2010/2011 Progress and Accomplishments 

    E-Print Network [OSTI]

    Kalisek, D.; Harris, B. L.; Runyan, C.; DeMouche, L.

    2011-01-01

    Since 2001, the Efficient Irrigation for Water Conservation in the Rio Grande Basin Federal Initiative-known as the Rio Grande Basin Initiative (RGBI)-has saved more than 5 million acre-feet of water. Researchers, Extension specialists, and county...

  9. A Parallel Java Grande Benchmark Suite L. A. Smith and J. M. Bull

    E-Print Network [OSTI]

    Bull, Mark

    A Parallel Java Grande Benchmark Suite L. A. Smith and J. M. Bull EPCC, The King's Buildings Republic. email: xobdrzal@fi.muni.cz Abstract Increasing interest is being shown in the use of Java for large scale or Grande applications. This new use of Java places specific demands on the Java execution

  10. Tree rings and multiseason drought variability in the lower Rio Grande Basin, USA

    E-Print Network [OSTI]

    Castro, Christopher L.

    ] Summer precipitation can impact water demand and be an important source of water for irrigation in areas to supplement surface water rights to the Rio Grande water and groundwater pumping. The Elephant Butte Irri irrigation from the Rio Grande to over 36,000 ha of crops, including pecans, chilis, and cotton [Bureau

  11. Variational grand-canonical electronic structure method for open systems Shlomit Jacobi and Roi Baera

    E-Print Network [OSTI]

    Baer, Roi

    Variational grand-canonical electronic structure method for open systems Shlomit Jacobi and Roi online 3 August 2005 An ab initio method is developed for variational grand-canonical molecular and a practical method for performing the calculations within standard quantum chemistry codes using Gaussian

  12. An Experimental Study of Mn12-Family Molecular Magnets in Isolation with High Spatial Resolution 

    E-Print Network [OSTI]

    Reaves, Kelley Thomas

    2014-12-17

    atoms. The radius of the Mn atoms has been modified from their ionic radius for clarity. . . . . . . . . . . . . 15 2.4 Magnetization of Mn12-Ph powder sample as a function of applied magnetic field at different temperatures, 1.8K ? T ? 10K. The measured... large circles are Mn3+ ions, the lighter colored large circles are Mn4+ ions, the smaller black circles are O atoms, and the lines indicate a chemical bond (of O to Mn). This double shell has tetragonal symmetry and consists of an inner shell...

  13. Effect of Mn substitution on the transport properties of co-sputtered Fe{sub 3?x}Mn{sub x}Si epilayers

    SciTech Connect (OSTI)

    Tang, M.; Jin, C.; Bai, H. L.

    2014-11-07

    Motivated by the theoretical calculations that Fe{sub 3?x}Mn{sub x}Si can simultaneously exhibit a high spin polarization with a high Curie temperature to be applied in spintronic devices, and in order to further study the effect of Mn contents on the physical properties of Fe{sub 3?x}Mn{sub x}Si, we have investigated the effect of Mn substitution on the transport properties of epitaxial Fe{sub 3?x}Mn{sub x}Si (0?x?1) films systematically. The Fe{sub 3?x}Mn{sub x}Si films were epitaxially grown on MgO(001) plane with 45° rotation. The magnetization for various x shows enhanced irreversibility, implying the antiferromagnetic ordering induced by the substitution of Mn. A metal-semiconductor crossover was observed due to the enhanced disorders of interactions and the local lowering of symmetry induced by the substitution of Mn. The single-domain state in the Fe{sub 3?x}Mn{sub x}Si films leads to twofold symmetric curves of the anisotropic magnetoresistance and planar Hall resistivity.

  14. Role of t{sub 2g} electrons in Mn-Tb coupling of multiferroic TbMnO{sub 3}

    SciTech Connect (OSTI)

    Guo, Y. Y.; Wang, Y. L.; Liu, J.-M.; Wei, T.

    2014-08-14

    We investigate the effect of Cr-doping in polycrystalline TbMn{sub 1?x}Cr{sub x}O{sub 3} (x???6%) ceramics on the magnetism, ferroelectricity, and dielectricity. The Cr substitution gradually suppresses the ferroelectricity induced by the Mn spiral spin ordering, and results in a stronger modulation of polarization by magnetic field with increasing x. However, the transition temperature T{sub Tb} corresponding to onset of Tb magnetic ordering has barely shifted with Cr doping. In other words, although the Cr-doping obviously disrupts the Mn spiral spin ordering, the exchange field J{sub Mn-Tb} acting on the Tb moments from the Mn-spin structure is hardly impacted. Our work demonstrates that the e{sub g} electron of Mn{sup 3+} plays an important role in forming the Mn spiral spin order, but the f-d exchange interaction between the Mn 3d spins and the Tb 4f moments in multiferroic TbMnO{sub 3} almost involves only the t{sub 2g} electrons.

  15. Biological Mn(II) oxidation in freshwater and marine systems : new perspectives on reactants, mechanisms and microbial catalysts of Mn cycling in the environment

    E-Print Network [OSTI]

    Clement, Brian Gregory

    2006-01-01

    a mining-related acid drainage problem. Applied Geochemistrya mining-related acid drainage problem. Applied GeochemistryBioremediation of Acid Mine Drainage: Mn(II) Oxidation at

  16. Controlling Mn depth profiles in GaMnAs during high-temperature molecular beam epitaxial growth

    E-Print Network [OSTI]

    Thibado, Paul M.

    , or spintronics [1]. The reason for this is that, compared to conventional electronic devices, spin-based devices be suitable for spintronics. For example, the discovery of ferromagnetism in Mn-doped GaAs grown by MBE [4] has led to interest in it as an ideal material for spintronics applications [5,6]. The future success

  17. Electronic structure and magnetism of Mn{sub 12}O{sub 12} clusters

    SciTech Connect (OSTI)

    Pederson, M.R. [Complex Systems Theory Branch-6692, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States)] [Complex Systems Theory Branch-6692, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States); Khanna, S.N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    1999-01-01

    To address the ferrimagnetic state of the Mn{sub 12} acetate matrix [Mn{sub 12}O{sub 12}(CH{sub 3}COO){sub 16}(H{sub 2}O){sub 4}] we have performed all-electron gradient-corrected density-functional calculations on (MnO){sub n} with n=1, 2, 4, and 12. In contrast to bulk MnO which is antiferromagnetic, the small (MnO){sub n} (n=1, 2, and 4) clusters are ferromagnetic with Mn moments of 5.0{mu}{sub B} but the ground state of Mn{sub 12}O{sub 12} is ferrimagnetic with a total magnetic moment of 20.0{mu}{sub B} as observed experimentally. The inner Mn sites in Mn{sub 12}O{sub 12} are found to have localized moments of 4.1{mu}{sub B} which are antiferromagnetically coupled to two types of outer Mn with moments of 4.2{mu}{sub B}. The cluster is shown to be marked by ionic as well as covalent bonds between Mn d and O p electrons and a strong intracluster magnetic coupling. {copyright} {ital 1999} {ital The American Physical Society}

  18. Giant Magnetic Moments and Magnetic Bistability of Stoichiomatric MnO Clusters

    SciTech Connect (OSTI)

    Nayak, S.K.; Jena, P. [Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Physics Department, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    1998-10-01

    {ital Abthinspthinspinitio} calculations based on density functional theory and generalized gradient approximation reveal many unusual features of stoichiometric (MnO){sub x} (x{le}9) clusters that contrast with their bulk behavior. The clusters are ferromagnetic and carry atomiclike magnetic moments ranging from 4{mu}{sub B} to 5{mu}{sub B} per MnO unit, and the moments are localized at the Mn sites. The (MnO){sub 8} cluster, in particular, exhibits nearly degenerate ferromagnetic and atypical antiferromagnetic solutions with the ferromagnetic structure carrying a moment of 40{mu}{sub B} . The structures of (MnO){sub x} clusters are also unique with cubic and hexagonal forms competing for stability. (MnO){sub 2} and (MnO){sub 3} are unusually stable and form the foundation for further growth. {copyright} {ital 1998} {ital The American Physical Society}

  19. X-ray absorption study of the electronic structure of Mn-doped amorphous Si

    SciTech Connect (OSTI)

    Arenholz, Elke; Zeng, Li; Huegel, A.; Helgren, E.; Hellman, F.; Piamonteze, C.; Arenholz, E.

    2008-03-08

    The electronic structure of Mn in amorphous Si (a-Mn{sub x}Si{sub 1?x}) is studied by X-ray absorption spectroscopy at the Mn L{sub 3,2} edges for x = 0.005-0.18. Except the x = 0.005 sample, which shows a slight signature of Mn{sup 2+} atomic multiplets associated with a local Mn moment, all samples have broad and featureless L{sub 3,2} absorption peaks, corresponding to an itinerant state for all 3d electrons. The broad X-ray absorption spectra exclude the possibility of a localized 3d moment and explain the unexpectedly quenched Mn moment in this magnetically-doped amorphous semiconductor. Such a fully delocalized d state of Mn dopant in Si has not been previously suggested.

  20. Atomic-resolution study of Mn tetramer clusters using scanning tunneling Rong Yang, Haiqiang Yang, and Arthur R. Smitha

    E-Print Network [OSTI]

    Atomic-resolution study of Mn tetramer clusters using scanning tunneling microscopy Rong Yang clusters is investigated. The clusters are composed of a quadrant array of Mn atoms forming a tetramer of manganese nitride, on which are stabilized peri- odic, self-organized array of MnN-bonded Mn tetramer clus

  1. Plutonium Oxidation and Subsequent Reduction by Mn (IV) Minerals

    SciTech Connect (OSTI)

    KAPLAN, DANIEL

    2005-09-13

    Plutonium sorbed to rock tuff was preferentially associated with manganese oxides. On tuff and synthetic pyrolusite (Mn{sup IV}O{sub 2}), Pu(IV) or Pu(V) was initially oxidized, but over time Pu(IV) became the predominant oxidation state of sorbed Pu. Reduction of Pu(V/VI), even on non-oxidizing surfaces, is proposed to result from a lower Gibbs free energy of the hydrolyzed Pu(IV) surface species versus that of the Pu(V) or Pu(VI) surface species. This work suggests that despite initial oxidation of sorbed Pu by oxidizing surfaces to more soluble forms, the less mobile form of Pu, Pu(IV), will dominate Pu solid phase speciation during long term geologic storage. The safe design of a radioactive waste or spent nuclear fuel geologic repository requires a risk assessment of radionuclides that may potentially be released into the surrounding environment. Geochemical knowledge of the radionuclide and the surrounding environment is required for predicting subsurface fate and transport. Although difficult even in simple systems, this task grows increasingly complicated for constituents, like Pu, that exhibit complex environmental chemistries. The environmental behavior of Pu can be influenced by complexation, precipitation, adsorption, colloid formation, and oxidation/reduction (redox) reactions (1-3). To predict the environmental mobility of Pu, the most important of these factors is Pu oxidation state. This is because Pu(IV) is generally 2 to 3 orders of magnitude less mobile than Pu(V) in most environments (4). Further complicating matters, Pu commonly exists simultaneously in several oxidation states (5, 6). Choppin (7) reported Pu may exist as Pu(IV), Pu(V), or Pu(VI) oxic natural groundwaters. It is generally accepted that plutonium associated with suspended particulate matter is predominantly Pu(IV) (8-10), whereas Pu in the aqueous phase is predominantly Pu(V) (2, 11-13). The influence of the character of Mn-containing minerals expected to be found in subsurface repository environments on Pu oxidation state distributions has been the subject of much recent research. Kenney-Kennicutt and Morse (14), Duff et al. (15), and Morgenstern and Choppin (16) observed oxidation of Pu facilitated by Mn(IV)-bearing minerals. Conversely, Shaughnessy et al. (17) used X-ray Absorption near-edge spectroscopy (XANES) to show reduction of Pu(VI) by hausmannite (Mn{sup II}Mn{sub 2}{sup III}O{sub 4}) and manganite ({gamma}-Mn{sup III}OOH) and Kersting et al., (18) observed reduction of Pu(VI) by pyrolusite (Mn{sup IV}O{sub 2}). In this paper, we attempt to reconcile the apparently conflicting datasets by showing that Mn-bearing minerals can indeed oxidize Pu, however, if the oxidized species remains on the solid phase, the oxidation step competes with the formation of Pu(IV) that becomes the predominant solid phase Pu species with time. The experimental approach we took was to conduct longer term (approximately two years later) oxidation state analyses on the Pu sorbed to Yucca Mountain tuff (initial analysis reported by Duff et al., (15)) and measure the time-dependant changes in the oxidation state distribution of Pu in the presence of the Mn mineral pyrolusite.

  2. Analysis of resonances in grand design spiral galaxies

    E-Print Network [OSTI]

    Nelson Vera-Villamizar; Horacio Dottori; Ivanio Puerari; Reinaldo de Carvalho

    2000-09-13

    We have searched for corotations (CR) in three Southern grand design spiral galaxies: NGC 1365, NGC 1566 and NGC 2997. We have also introduced a method of quantifying errors in the phase diagram used to detect CR. We established the m=2 pattern CR at 12.1 kpc, 9.4 kpc and 7 kpc, for NGC 1365, NGC 1566 and NGC 2997, respectively. By using published rotation curves, we could determine spiral pattern angular speeds of 25.0 km/sec/kpc, 12.2 km/sec/kpc and 17.6 km/sec/kpc, respectively. A three armed component has been detected in NGC 2997, with the CR placed at 8.7 kpc with a pattern angular speed Omega_{CR_3}=12.7 km/sec/kpc. An m=1 component was detected in NGC 1566. We warily locate the CR at 7.1 kpc, with a pattern angular speed Omega_{CR} approx. 16.6 km/sec/kpc. This pattern does not present ILR. Ages have been determined by studying the radial density profile of the m=2 Fourier components in g (newly formed stars) and i (perturbing SDW supported by the disk of old stars), aided by the global aspect of the real spiral pattern in comparison with numerical simulations. The pattern is approx. 1200 Myr old in NGC 1365, approx. 800 Myr old in NGC 1566 and younger than 80 Myr in NGC 2997.

  3. Grand challenge problems in environmental modeling and remediation: Groundwater contaminant transport. Final project report 1998

    SciTech Connect (OSTI)

    1998-04-01

    The over-reaching goal of the Groundwater Grand Challenge component of the Partnership in Computational Science (PICS) was to develop and establish the massively parallel approach for the description of groundwater flow and transport and to address the problem of uncertainties in the data and its interpretation. This necessitated the development of innovative algorithms and the implementation of massively parallel computational tools to provide a suite of simulators for groundwater flow and transport in heterogeneous media. This report summarizes the activities and deliverables of the Groundwater Grand Challenge project funded through the High Performance Computing grand challenge program of the Department of Energy from 1995 through 1997.

  4. Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys 

    E-Print Network [OSTI]

    Karaca, Haluk Ersin

    2009-05-15

    The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single ...

  5. Manganese valence and coordination structure in Mn,Mg-codoped {gamma}-AlON green phosphor

    SciTech Connect (OSTI)

    Takeda, Takashi; Xie, Rong-Jun; Hirosaki, Naoto; Matsushita, Yoshitaka; Honma, Tetuso

    2012-10-15

    The valence and coordination structure of manganese in a Mn,Mg-codoped {gamma}-AlON spinel-type oxynitride green phosphor were studied by synchrotron X-ray diffraction and absorption fine structure measurements. The absorption edge position of the XANES revealed the bivalency of Mn. Two cation sites are available in the spinel structure for cation doping: a tetrahedral site and an octahedral site. The pre-edge of the XANES and the distance to the nearest neighbor atoms obtained from the EXAFS measurement showed that Mn was situated at the tetrahedral site. Rietveld analysis showed that the vacancy occupied the octahedral site. The preferential occupation of the tetrahedral site by Mn and the roles of N and Mg are discussed in relation to the spinel crystal structure. - Graphical Abstract: Fourier transform of EXAFS of Mn K-edge for Mn,Mg-codoped green phosphor and Mn coordination structure. Highlights: Black-Right-Pointing-Pointer Mn, Mg-codoped {gamma}-AlON green phosphor for white LED. Black-Right-Pointing-Pointer The valence of Mn is divalent. Black-Right-Pointing-Pointer Mn occupies the tetrahedral site in the spinel structure.

  6. Ferromagnetic interactions and martensitic transformation in Fe doped Ni-Mn-In shape memory alloys

    SciTech Connect (OSTI)

    Lobo, D. N.; Priolkar, K. R.; Emura, S.; Nigam, A. K.

    2014-11-14

    The structure, magnetic, and martensitic properties of Fe doped Ni-Mn-In magnetic shape memory alloys have been studied by differential scanning calorimetry, magnetization, resistivity, X-ray diffraction (XRD), and EXAFS. While Ni{sub 2}MnIn{sub 1?x}Fe{sub x} (0???x???0.6) alloys are ferromagnetic and non martensitic, the martensitic transformation temperature in Ni{sub 2}Mn{sub 1.5}In{sub 1?y}Fe{sub y} and Ni{sub 2}Mn{sub 1.6}In{sub 1?y}Fe{sub y} increases for lower Fe concentrations (y???0.05) before decreasing sharply for higher Fe concentrations. XRD analysis reveals presence of cubic and tetragonal structural phases in Ni{sub 2}MnIn{sub 1?x}Fe{sub x} at room temperature with tetragonal phase content increasing with Fe doping. Even though the local structure around Mn and Ni in these Fe doped alloys is similar to martensitic Mn rich Ni-Mn-In alloys, presence of ferromagnetic interactions and structural disorder induced by Fe affect Mn-Ni-Mn antiferromagnetic interactions resulting in suppression of martensitic transformation in these Fe doped alloys.

  7. Effect of composition and heat treatment on MnBi magnetic materials

    SciTech Connect (OSTI)

    Cui, Jun [Pacific Northwest National Laboratory; Choi, Jung-Pyung [Pacific Northwest National Laboratory; Polikarpov, Evgueni [Pacific Northwest National Laboratory; Bowden, Mark E [Pacific Northwest National Laboratory; Xie, Wei [Pacific Northwest National Laboratory; Li, Guosheng [Pacific Northwest National Laboratory; Nie, Zimin [Pacific Northwest National Laboratory; Zarkevich, Nikolai [Ames Laboratory; Kramer, Matthew J [Ames Laboratory; Johnson, Duane [Ames Laboratory

    2014-10-01

    The metallic compound MnBi is a promising rare-earth-free permanent magnet material, unique among all candidates for its high intrinsic coercivity (Hci) and its large positive temperature coefficient. The Hci of MnBi in thin-film or powder form can exceed 12 and 26 kOe at 300 and 523 K, respectively. Such a steep rise in Hci with increasing temperature is unique to MnBi. Consequently, MnBi is a highly sought-after hard phase for exchange coupling nanocomposite magnets. However, the reaction between Mn and Bi is peritectic, and hence Mn tends to precipitate out of the MnBi liquid during the solidification process. As result, when the alloy is prepared using conventional induction or arc-melting casting methods, additional Mn is required to compensate the precipitation of Mn. In addition to composition, post-casting annealing plays an important role in obtaining a high content of MnBi low-temperature phase (LTP) because the annealing encourages the Mn precipitates and the unreacted Bi to react, forming the desired LTP phase. Here we report a systematic study of the effect of composition and heat treatments on the phase content and magnetic properties of Mn–Bi alloys. In this study, 14 compositions were prepared using conventional metallurgical methods, and the compositions, crystal structures, phase content and magnetic properties of the resulting alloys were analyzed. The results show that the composition with 55 at.% Mn exhibits both the highest LTP content (93 wt.%) and magnetization (74 emu g?1 with 9 T applied field at 300 K).

  8. On the state of Mn impurity implanted in Si

    SciTech Connect (OSTI)

    Orlov, A. F.; Bublik, V. T.; Vdovin, V. I.; Agafonov, Yu. A.; Balagurov, L. A.; Zinenko, V. I.; Kulemanov, I. V.; Shcherbachev, K. D.

    2009-07-15

    The state of manganese impurity in implanted silicon at implantation doses of up to 5 x 10{sup 16} cm{sup -2} has been investigated by X-ray diffraction and transmission electron microscopy. It is established that, after short-term vacuum annealing at 850{sup o}C, most of the implanted manganese impurities are in microinclusions up to 20 nm in size formed by a tetragonal silicide phase of the Mn{sub 15}Si{sub 26} type.

  9. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect (OSTI)

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Université de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  10. Nesting ecology of Rio Grande wild turkeys in the Edwards Plateau of Texas 

    E-Print Network [OSTI]

    Dreibelbis, Justin Zachary

    2009-05-15

    Rio Grande wild turkey (Meleagris gallopavo intermedia) numbers in the southeastern region of the Edwards Plateau (EP) have shown a significant decline since the 1970s; however, the remainder of the EP had stable populations during this period...

  11. The SO2 Allowance Trading System: The Ironic History of a Grand Policy Experiment

    E-Print Network [OSTI]

    Schmalensee, Richard

    Two decades have passed Two decades have passed since the Clean Air Act Amendments of 1990 launched a grand experiment in market-based environmental policy: the SO2 cap-and-trade system. That system performed well but ...

  12. A simulation model of Rio Grande wild turkey dynamics in the Edwards Plateau of Texas 

    E-Print Network [OSTI]

    Schwertner, Thomas Wayne

    2006-08-16

    I investigated the effect of precipitation and predator abundance on Rio Grande wild turkey (Meleagris gallopavo; RGWT) in Texas. My results suggested that RGWT production was strongly correlated with cumulative winter precipitation over the range...

  13. The systemic and ideological sources of grand strategic doctrine : American foreign policy in the twentieth century

    E-Print Network [OSTI]

    Green, Brendan Rittenhouse

    2011-01-01

    What explains the puzzling variation in America's foreign policy posture? This study proposes and tests a theory of American grand strategy that places an emphasis on two key variables: the ideological content of American ...

  14. EIS-0485: Interconnection of the Grande Prairie Wind Farm, Holt County, Nebraska

    Broader source: Energy.gov [DOE]

    DOE’s Western Area Power Administration prepared an EIS to evaluate the environmental impacts of interconnecting the proposed Grande Prairie Wind Farm, in Holt County, near O’Neill, Nebraska, to Western’s power transmission system.

  15. International cooperation between the United States and Mexico: addressing water quality of the Lower Rio Grande 

    E-Print Network [OSTI]

    Crouch, Kellie Gene

    1997-01-01

    Water quantities of the Lower Rio Grande were apportioned between Mexico and Texas through a treaty in 1944. The treaty defines the mandate of the International Boundary and Water Commission, an international institution ...

  16. A Study of Institutional Factors Affecting Water Resource Development in the Lower Rio Grande Valley, Texas 

    E-Print Network [OSTI]

    Trock, W. L.; Casbeer, T. J.

    1969-01-01

    Despite numerous studies of and plans for the use of land and water resources of the lower Rio Grande Valley for efficient agricultural production, development has lagged and the production potential has not been realized. ...

  17. Vegetation, soils, and surface hydrology of playa landforms in the Rio Grande Plains, Texas 

    E-Print Network [OSTI]

    Farley, Andrea Lee

    2000-01-01

    Playas in the Rio Grande Plains of southern Texas were compared with respect to their: 1) size, shape, soil properties, and microtopography, 2) vegetation composition and structure, 3) surface water accumulation potential, and 4) disturbance history...

  18. Monitoring Fine Sediment; Grande Ronde and John Day Rivers, 1999 Annual Report.

    SciTech Connect (OSTI)

    Rhodes, Jonathan J.; Greene, M. Jonas; Purser, Michael D.

    2000-01-01

    This project was initiated to monitor surface fine sediment levels and overwinter intrusion of fine sediment in spring chinook salmon spawning habitat in the North Folk John Day and Grande Ronde Rivers, for five years.

  19. An applied paleoecology case study: Bahia Grande, Texas prior to construction of the Brownsville Ship Channel 

    E-Print Network [OSTI]

    Lichlyter, Stephen Alvah

    2006-08-16

    . Unfortunately, because very little is known about Bahia Grande prior to isolation, it is difficult to predict whether the results of the restoration will be comparable to the pre-Ship Channel environment. Paleoecological data provide the best opportunity...

  20. Structural fabric of the Palisades Monocline: a study of positive inversion, Grand Canyon, Arizona 

    E-Print Network [OSTI]

    Orofino, James Cory

    2005-08-29

    A field study of positive inversion is conducted to describe associated structural fabrics and to infer kinematic development of the Palisades Monocline, Grand Canyon, Arizona. These features are then compared to sand, clay and solid rock models...

  1. High performance computing and communications grand challenges program

    SciTech Connect (OSTI)

    Solomon, J.E.; Barr, A.; Chandy, K.M.; Goddard, W.A., III; Kesselman, C.

    1994-10-01

    The so-called protein folding problem has numerous aspects, however it is principally concerned with the {ital de novo} prediction of three-dimensional (3D) structure from the protein primary amino acid sequence, and with the kinetics of the protein folding process. Our current project focuses on the 3D structure prediction problem which has proved to be an elusive goal of molecular biology and biochemistry. The number of local energy minima is exponential in the number of amino acids in the protein. All current methods of 3D structure prediction attempt to alleviate this problem by imposing various constraints that effectively limit the volume of conformational space which must be searched. Our Grand Challenge project consists of two elements: (1) a hierarchical methodology for 3D protein structure prediction; and (2) development of a parallel computing environment, the Protein Folding Workbench, for carrying out a variety of protein structure prediction/modeling computations. During the first three years of this project, we are focusing on the use of two proteins selected from the Brookhaven Protein Data Base (PDB) of known structure to provide validation of our prediction algorithms and their software implementation, both serial and parallel. Both proteins, protein L from {ital peptostreptococcus magnus}, and {ital streptococcal} protein G, are known to bind to IgG, and both have an {alpha} {plus} {beta} sandwich conformation. Although both proteins bind to IgG, they do so at different sites on the immunoglobin and it is of considerable biological interest to understand structurally why this is so. 12 refs., 1 fig.

  2. Investigation of structure, magnetic, and transport properties of Mn-doped SiC films

    SciTech Connect (OSTI)

    Sun Xianke [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); Guo Ruisong [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); An Yukai [Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); School of Material Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China); Liu Jiwen [School of Material Science and Engineering, Tianjin University, Tianjin 300172 (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384 (China); School of Material Science and Engineering, Tianjin University of Technology, Tianjin 300384 (China)

    2013-07-15

    Mn-doped SiC films were fabricated by radio frequency magnetron sputtering technique. The structure, composition, and magnetic and transport properties of the films were investigated. The results show the films have the 3C-SiC crystal structure and the doped Mn atoms in the form of Mn{sup 2+} ions substitute for C sites in SiC lattice. All the films are ferromagnetic at 300 K, and the ferromagnetism in films arises from the doped Mn atoms and some extended defects. In addition, the saturation magnetization increases with the Mn-doped concentration increasing. The Mn doping does not change the semiconductor characteristics of the SiC films.

  3. Ge{sub 1-x}Mn{sub x} heteroepitaxial quantum dots: Growth, morphology, and magnetism

    SciTech Connect (OSTI)

    Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

    2013-02-21

    Heteroepitaxial Ge{sub 1-x}Mn{sub x} quantum dots (QDs) were grown on Si (001) by molecular beam epitaxial co-deposition, with x = 0 to 0.10, in order to explore the interaction between Mn content, surface morphological evolution, and magnetism. Morphological evolution typical of the Ge/Si (001) system was observed, where the effect of Mn on surface morphology is surprisingly minimal at low Mn content, with no obvious surface morphological indicators of second phase formation. As the Mn content increases, secondary phase formation becomes evident, appearing to heterogeneously nucleate on or within Ge QDs. Still higher Mn concentrations lead to extensive second phase formation interspersed with an array of Ge QDs. Although ferromagnetism up to 220 K is observed, likely arising from intermetallic precipitates, there is no clear evidence for room-temperature ferromagnetism associated with a dilute magnetic solution phase.

  4. Time resolved magneto-optical studies of ferromagnetic InMnSb films

    SciTech Connect (OSTI)

    Frazier, M.; Kini, R. N.; Nontapot, K.; Khodaparast, G. A. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Wojtowicz, T. [Institute of Physics, Polish Academy of Sciences 02-668 Warsaw (Poland); Liu, X.; Furdyna, J. K. [Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

    2008-02-11

    We report time resolved magneto-optical measurements in InMnSb ferromagnetic films with 2% and 2.8% Mn contents grown by low temperature molecular beam epitaxy. In order to probe a possible interaction between the spins of photoexcited carriers and the Mn ions, we measured spin dynamics before and after aligning the Mn ions by applying an external magnetic field at temperatures above and below the samples' Curie temperatures. We observed no significant temperature or magnetic field dependence in the relaxation times and attribute the observed dynamics entirely to the relaxation of photoexcited electrons in the conduction band where the s-d coupling with the localized Mn ions is significantly weaker compared to the p-d exchange coupling. We observed several differences in the optical response of our InMnSb samples which could have been influenced mainly by the samples' growth conditions.

  5. Estimated Benefits of IBWC Rio Grande Flood-Control Projects in the United States 

    E-Print Network [OSTI]

    Sturdivant, Allen W.; Lacewell, Ronald D.; Michelsen, Ari M.; Rister, M. Edward; Assadian, Naomi; Eriksson, Marian; Freeman, Roger; Jacobs, Jennifer H.; Madison, W. Tom; McGuckin, James T.; Morrison, Wendy; Robinson, John R.C.; Staats, Chris; Sheng, Zhuping; Srinivasan, R.; Villalobos, Joshua I.

    2004-01-01

    on a Residential Area, Along the Rio Grande, Hidalgo County, 2004 ...................................................60 Estimated Benefits of IBWC Rio Grande September, 2004 Flood-Control Projects in the United States page viii of 61 List of Tables... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 B1 Hidalgo County Land Use Categories for Revised FEMA 100-Year Flood Plain Area, 2004 ............................................................47 B2 Cameron County Land Use Categories for Revised FEMA 100-Year Flood Plain Area, 2004...

  6. Watermelon marketing in Texas with emphasis on the Rio Grande Plain 

    E-Print Network [OSTI]

    Brown, Charles William

    1958-01-01

    ?outs cf Water?alone by Truch and. Rail Frc? BobbrcnvQIop Texaco' 1957 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 33 7. Carlct Receipts cf Texas Waters?lens at, Major Barhots, 1953 561 ~ ~ ~ ~ ~ * ~ ~ ~ ~ ~ 4 ~ ~ ~ ~ 4 ~ ~ II ~ ~ 38 8, Prices of Water... xxaternelon producing areas in the h. ie Grande PlaiR4 ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 0 1 ~ ~ ~ ~ ~ ~ I ~ ~ ~ 3, Distribution sf xxaterxalene free the Bio Grande Plain by w e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 6. Distribution ef xxatermlone by rail...

  7. Cr(OH)?(s) Oxidation Induced by Surface Catalyzed Mn(II) Oxidation

    SciTech Connect (OSTI)

    Namgung, Seonyi; Kwon, M.; Qafoku, Nikolla; Lee, Gie Hyeon

    2014-09-16

    This study examined the feasibility of Cr(OH)?(s) oxidation mediated by surface catalyzed Mn(II) oxidation under common groundwater pH conditions as a potential pathway of natural Cr(VI) contaminations. Dissolved Mn(II) (50 ?M) was reacted with or without synthesized Cr(OH)?(s) (1.0 g/L) at pH 7 – 9 under oxic or anoxic conditions. In the absence of Cr(OH)?(s), homogeneous Mn(II) oxidation by dissolved O? was not observed at pH ? 8.0 for 50 d. At pH 9.0, by contrast, dissolved Mn(II) was completely removed within 8 d and precipitated as hausmannite. When Cr(OH)?(s) was present, this solid was oxidized and released substantial amounts of Cr(VI) as dissolved Mn(II) was added into the suspension at pH ? 8.0 under oxic conditions. Our results suggest that Cr(OH)?(s) was readily oxidized by a newly formed Mn oxide as a result of Mn(II) oxidation catalyzed on Cr(OH)?(s) surface. XANES analysis of the residual solids after the reaction between 1.0 g/L Cr(OH)?(s) and 204 ?M Mn(II) at pH 9.0 for 22 d revealed that the product of surface catalyzed Mn(II) oxidation resembled birnessite. The rate and extent of Cr(OH)?(s) oxidation was likely controlled by those of surface catalyzed Mn(II) oxidation as the production of Cr(VI) increased with increasing pH and initial Mn(II) concentrations. This study evokes the potential environmental hazard of sparingly soluble Cr(OH)?(s) that can be a source of Cr(VI) in the presence of dissolved Mn(II).

  8. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore »been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3?B/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  9. Electronic Structure and Oxidation State Changes in the Mn (4) Ca Cluster of Photosystem II

    SciTech Connect (OSTI)

    Yano, J.; Pushkar, Y.; Messinger, J.; Bergmann, U.; Glatzel, P.; Yachandra, V.K.; /SLAC

    2012-08-17

    Oxygen-evolving complex (Mn{sub 4}Ca cluster) of Photosystem II cycles through five intermediate states (S{sub i}-states, i = 0-4) before a molecule of dioxygen is released. During the S-state transitions, electrons are extracted from the OEC, either from Mn or alternatively from a Mn ligand. The oxidation state of Mn is widely accepted as Mn{sub 4}(III{sub 2},IV{sub 2}) and Mn{sub 4}(III,IV{sub 3}) for S{sub 1} and S{sub 2} states, while it is still controversial for the S{sub 0} and S{sub 3} states. We used resonant inelastic X-ray scattering (RIXS) to study the electronic structure of Mn{sub 4}Ca complex in the OEC. The RIXS data yield two-dimensional plots that provide a significant advantage by obtaining both K-edge pre-edge and L-edge-like spectra (metal spin state) simultaneously. We have collected data from PSII samples in the each of the S-states and compared them with data from various inorganic Mn complexes. The spectral changes in the Mn 1s2p{sub 3/2} RIXS spectra between the S-states were compared to those of the oxides of Mn and coordination complexes. The results indicate strong covalency for the electronic configuration in the OEC, and we conclude that the electron is transferred from a strongly delocalized orbital, compared to those in Mn oxides or coordination complexes. The magnitude for the S{sub 0} to S{sub 1}, and S{sub 1} to S{sub 2} transitions is twice as large as that during the S{sub 2} to S{sub 3} transition, indicating that the electron for this transition is extracted from a highly delocalized orbital with little change in charge density at the Mn atoms.

  10. Enhancing SMM properties via axial distortion of Mn-3(III) clusters 

    E-Print Network [OSTI]

    Parsons S.; Brechin, E.K.; Collins A.; Karotsis G.; Jones L.F.; Inglis R.; Wernsdorfer W.; Perlepes S.P.

    2008-01-01

    Replacement of carboxylate and solvent with facially capping tripodal ligands enhances the single-molecule magnet (SMM) properties of [Mn-3(III)] triangles.

  11. Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure

    SciTech Connect (OSTI)

    Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

    2014-09-21

    The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}~55 ?C/cm² obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290 K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ~123 emu/cm³. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

  12. Distinct local electronic structure and magnetism for Mn in amorphous Si and Ge

    E-Print Network [OSTI]

    Zeng, Li

    2010-01-01

    ferromagnetic Mn 5 Ge 3 for spintronic applications. Phys.Wolf, S. A. et al. Spintronics: a spin-based electronicsdopants of interest for spintronic applications, where both

  13. Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors

    SciTech Connect (OSTI)

    Yan, Jun; Wei, Tong; Cheng, Jie; Fan, Zhuangjun; Zhang, Milin

    2010-02-15

    Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

  14. Opti-MN Impact House Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyApril 2014DepartmentCouncilOffice of theOpen DataHeat &Opti-MN

  15. Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based on Synthetic, Isotopic Labeling,

    E-Print Network [OSTI]

    Goddard III, William A.

    the cluster. 1. INTRODUCTION Artificial photosynthesis schemes generally involve water as the terminal source, with the MnIV 3CaO4 OEC model being unreactive. The oxidative oxide incorporation into the partial cubane, Mn

  16. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01

    various transition or rare-earth metals provide a rich ?eldTransition Metal (Mn) and Rare Earth (Gd) Doped AmorphousTransition Metal (Mn) and Rare Earth (Gd) Doped Amorphous

  17. Magnetic and structural properties of Zn doped MnV{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Shahi, Prashant; Shukla, K. K.; Singh, Rahul; Chatterjee, Sandip; Das, A.; Ghosh, A. K.; Nigam, A. K.

    2014-04-24

    The magnetization, Neutron diffraction and X-ray diffraction of Zn doped MnV{sub 2}O{sub 4} as a function of temperature have been measured. It has been observed, with increase of Zn the non-linear orientation of Mn spins with the V spins will decrease which effectively decrease the structural transition temperature more rapidly than Curie Temperature.

  18. Photovoltaic effect in multiphase Bi-Mn-O thin J. P. Chakrabartty,1

    E-Print Network [OSTI]

    Photovoltaic effect in multiphase Bi-Mn-O thin films J. P. Chakrabartty,1 R. Nechache,2,4 C and therefore the photovoltaic conversion efficiency. Specifically, a higher Bi/Mn ratio (towards unity separation. ©2013 Optical Society of America OCIS codes: (040.5350) Photovoltaic; (160.2260) Ferroelectrics

  19. MN 555 MEMS: Fabrication and Materials Spring 2004 Department of Manufacturing Engineering

    E-Print Network [OSTI]

    Lin, Xi

    MN 555 MEMS: Fabrication and Materials Spring 2004 Instructor Xin Zhang Department of Manufacturing meetings by appointment) 2003-2004 Catalog Data: MN 555 MEMS: Fabrication and Materials This course will explore the world of microelectromechanical devices and systems (MEMS). This requires an awareness

  20. Dietary resveratrol administration increases MnSOD expression and activity in mouse brain

    E-Print Network [OSTI]

    Stuart, Jeffrey A.

    Dietary resveratrol administration increases MnSOD expression and activity in mouse brain Ellen L May 2008 Available online xxxx Keywords: MnSOD Superoxide dismutase Resveratrol Antioxidant enzyme Brain Heart Liver Mitochondria Reactive oxygen species a b s t r a c t trans-Resveratrol (3,40 ,5

  1. Magnetic cluster excitations in the antiferromagnetic phase of a-MnMoO4 

    E-Print Network [OSTI]

    Ochsenbein, Stefan T; Chaboussant, Gregory; Sieber, Andreas; Gudel, Hans U; Janssen, Stefan; Furrer, Albert; Attfield, J. Paul

    2003-01-01

    The tetramer-based compound a-MnMoO4 exhibits four prominent peaks in the inelastic neutron scattering (INS) spectrum between 0.5 and 2.0 meV below 10 K. They are assigned to magnetic excitations of the (Mn2+)4 rhombus ...

  2. Electric-Field Modulation of Curie Temperature in (Ga, Mn)As Field-Effect Transistor Structures with Varying Channel Thickness and Mn Compositions

    SciTech Connect (OSTI)

    Nishitani, Y.; Endo, M.; Chiba, D.; Matsukura, F.; Ohno, H.

    2010-01-04

    We have investigated the change of T{sub C} of ferromagnetic semiconductor (Ga, Mn)As by changing hole concentration p. The field effect transistor structure was utilized to change p. The relation T{sub C}propor top{sup 0.2} is obtained for three samples, despite the difference of their Mn composition and thickness, indicating that the relation holds over 2 decades of p.

  3. Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor

    SciTech Connect (OSTI)

    Wijnheijmer, A. P.; Koenraad, P. M.; Marti, X.; Holy, V.; Cukr, M.; Novak, V.; Jungwirth, T.

    2012-03-12

    We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

  4. Core-level satellites and outer core-level multiplet splitting in Mn model compounds

    SciTech Connect (OSTI)

    Nelson, A. J. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States); Reynolds, John G. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States); Roos, Joseph W. [Ethyl Corporation, Richmond, Virginia 23217 (United States)] [Ethyl Corporation, Richmond, Virginia 23217 (United States)

    2000-07-01

    We report a systematic study of the Mn 2p, 3s, and 3p core-level photoemission and satellite structures for Mn model compounds. Charge transfer from the ligand state to the 3d metal state is observed and is distinguished by prominent shake-up satellites. We also observe that the Mn 3s multiplet splitting becomes smaller as the Mn oxidation state increases, and that 3s-3d electron correlation reduces the branching ratio of the {sup 7}S:{sup 5}S states in the Mn 3s spectra. In addition, as the ligand electronegativity decreases, the spin-state purity is lost in the 3s spectra, as evidenced by peak broadening. Our results are best understood in terms of the configuration-interaction model including intrashell electron correlation, charge transfer, and final-state screening. (c) 2000 American Vacuum Society.

  5. Three-Dimensional (3D) Bicontinuous Hierarchically Porous Mn?O? Single Crystals for High Performance Lithium-Ion Batteries

    E-Print Network [OSTI]

    Huang, Shao-Zhuan; Jin, Jun; Cai, Yi; Li, Yu; Deng, Zhao; Zeng, Jun-Yang; Liu, Jing; Wang, Chao; Hasan, Tawfique; Su, Bao-Lian

    2015-10-06

    Bicontinuous hierarchically porous Mn?O? single crystals (BHP-Mn?O?-SCs) with uniform parallelepiped geometry and tunable sizes have been synthesized and used as anode materials for lithium-ion batteries (LIBs). The monodispersed BHP-Mn?O?-SCs...

  6. Start | Author Index 742-3 Rates and Mechanisms of Arsenite Oxidation by Nano-Mn(IV) Oxide Mineral Phases.

    E-Print Network [OSTI]

    Sparks, Donald L.

    Start | Author Index 742-3 Rates and Mechanisms of Arsenite Oxidation by Nano-Mn(IV) Oxide Mineral is thought to generally occur through either biologically or mineral-surface mediated Mn(II) oxidation. These two oxidation pathways result in the formation of nanometer-size Mn(IV) minerals. Compared

  7. Specific heat and bimodality in canonical and grand canonical versions of the thermodynamic model

    E-Print Network [OSTI]

    G. Chaudhuri; S. Das Gupta

    2007-08-26

    We address two issues in the thermodynamic model for nuclear disassembly. Surprisingly large differences in results for specific heat were seen in predictions from the canonical and grand canonical ensembles when the nuclear system passes from liquid-gas co-existence to the pure gas phase. We are able to pinpoint and understand the reasons for such and other discrepancies when they appear. There is a subtle but important difference in the physics addressed in the two models. In particular if we reformulate the parameters in the canonical model to better approximate the physics addressed in the grand canonical model, calculations for observables converge. Next we turn to the issue of bimodality in the probability distribution of the largest fragment in both canonical and grand canonical ensembles. We demonstrate that this distribution is very closely related to average multiplicities. The relationship of the bimodal distribution to phase transition is discussed.

  8. Grande Ronde Endemic Spring Chinook Salmon Supplementation Program : Facility Operation and Maintenance Facilities, Annual Report 2003.

    SciTech Connect (OSTI)

    McLean, Michael L.; Seeger, Ryan; Hewitt, Laurie

    2004-01-01

    Anadromous salmonid stocks have declined in both the Grande Ronde River Basin (Lower Snake River Compensation Plan (LSRCP) Status Review Symposium 1998) and in the entire Snake River Basin (Nehlsen et al. 1991), many to the point of extinction. The Grande Ronde River Basin historically supported large populations of fall and spring chinook (Oncorhynchus tshawytscha), sockeye (O. nerka), and coho (O. kisutch) salmon and steelhead trout (O. mykiss) (Nehlsen et al. 1991). The decline of chinook salmon and steelhead populations and extirpation of coho and sockeye salmon in the Grande Ronde River Basin was, in part, a result of construction and operation of hydroelectric facilities, over fishing, and loss and degradation of critical spawning and rearing habitat in the Columbia and Snake River basins (Nehlsen et al. 1991). Hatcheries were built in Oregon, Washington and Idaho under the Lower Snake River Compensation Plan (LSRCP) to compensate for losses of anadromous salmonids due to the construction and operation of the lower four Snake River dams. Lookingglass Hatchery (LGH) on Lookingglass Creek, a tributary of the Grande Ronde River, was completed under LSRCP in 1982 and has served as the main incubation and rearing site for chinook salmon programs for Grande Ronde and Imnaha rivers in Oregon. Despite these hatchery programs, natural spring chinook populations continued to decline resulting in the National Marine Fisheries Service (NMFS) listing Snake River spring/summer chinook salmon as ''threatened'' under the federal Endangered Species Act (1973) on 22 April 1992. Continuing poor escapement levels and declining population trends indicated that Grande Ronde River basin spring chinook salmon were in imminent danger of extinction. These continuing trends led fisheries co-managers in the basin to initiate the Grande Ronde Endemic Spring Chinook Salmon Supplementation Program (GRESCSSP) in order to prevent extinction and preserve options for use of endemic fish stocks in future artificial propagation programs. The GRESCSSP was implemented in three Grande Ronde River basin tributaries; the Lostine and upper Grande Ronde rivers and Catherine Creek. The GRESCSSP employs two broodstock strategies utilizing captive and conventional brood sources. The captive brood program began in 1995, with the collection of parr from the three tributary areas. The conventional broodstock component of the program began in 1997 with the collection of natural adults returning to these tributary areas. Although LGH was available as the primary production facility for spring chinook programs in the Grande Ronde Basin, there were never any adult or juvenile satellite facilities developed in the tributary areas that were to be supplemented. An essential part of the GRESCSSP was the construction of adult traps and juvenile acclimation facilities in these tributary areas. Weirs were installed in 1997 for the collection of adult broodstock for the conventional component of the program. Juvenile facilities were built in 2000 for acclimation of the smolts produced by the captive and conventional broodstock programs and as release sites within the natural production areas of their natal streams. The Confederated Tribes of the Umatilla Indian Reservation (CTUIR) operate both the juvenile acclimation and adult trapping facilities located on Catherine Creek and the upper Grande Ronde River under this project. The Nez Perce Tribe (NPT) operate the facilities on the Lostine River under a sister project. Hatcheries were also built in Oregon, Washington and Idaho under the LSRCP to compensate for losses of summer steelhead due to the construction and operation of the lowest four Snake River dams. Despite these harvest-driven hatchery programs, natural summer steelhead populations continued to decline as evidenced by declining counts at Lower Granite Dam since 1995 (Columbia River Data Access in Real Time, DART) and low steelhead redd counts on index streams in the Grande Ronde Basin. Because of low escapement the Snake River summer steelhead were listed as threat

  9. Influence of Mn and Ni on the microstructure and toughness of C-Mn-Ni weld metals

    SciTech Connect (OSTI)

    Zhang, Z.; Farrar, R.A. [Univ. of Southampton (United Kingdom). Dept. of Mechanical Engineering

    1997-05-01

    A systematic investigation has been carried out to study the microstructure and toughness of C-Mn-Ni low-alloy shielded metal arc (SMA) weld metals. The manganese and nickel concentrations were progressively changed to determine their influence on weld microstructure and mechanical properties as well as to identify their interactions. The results obtained showed that manganese and nickel have considerable effect on the weld metal microstructure, and both Mn and Ni affect the microstructure in a similar way, i.e., promoting acicular ferrite at the expense of proeutectoid ferrite (grain boundary ferrite and ferrite sideplates). The results in the top bead also showed that there is an optimum composition range that produces an optimum balance of weld metal microstructures. For optimum toughness, a combination of 0.6--1.4% manganese and 1.0--3.7% nickel is suggested. Additions beyond this limit promotes the formation of martensite and other microstructural features, which may be detrimental to weld metal toughness.

  10. Wildlife Mitigation and Restoration for Grand Coulee Dam: Blue Creek Project, Phase 1.

    SciTech Connect (OSTI)

    Merker, Christopher

    1993-04-01

    This report is a recommendation from the Spokane Tribe to the Northwest Power Planning Council (NPPC) for partial mitigation for the extensive wildlife and wildlife habitat losses on the Spokane Indian Reservation caused by the construction of Grand Coulee Dam. NPPC`s interim wildlife goal over the next 7 years for the Columbia hydropower system, is to protect, mitigate and enhance approximately 35% basin wide of the lost habitat units. Grand Coulee Dam had the greatest habitat losses of any Dams of the Wildlife Rule.

  11. Restoring The Azimuthal Symmetry Of Charged Particle Lateral Density In The Range Of KASCADE-Grande

    SciTech Connect (OSTI)

    Sima, O.; Rebel, H.; Apel, W. D.; Bekk, K.; Bozdog, H.; Daumiller, K.; Doll, P.; Engel, R.; Engler, J.; Finger, M.; Gils, H. J.; Haungs, A.; Heck, D.; Huege, T.; Isar, P. G.; Klages, H. O.; Mathes, H. J.; Mayer, H. J.; Milke, J.; Nehls, S.

    2010-11-24

    KASCADE-Grande, an extension of the former KASCADE experiment, is a multi-component Extensive Air Shower (EAS) experiment located in Karlsruhe Institute of Technology (Campus North), Germany. An important observable for analyzing the EAS is the lateral density of charged particles in the intrinsic shower plane. This observable is deduced from the basic information provided by the Grande scintillators - the energy deposit - first in the observation plane, by using a Lateral Energy Correction Function (LECF), then in the intrinsic shower plane, by applying an adequate mapping procedure. In both steps azimuthal.

  12. Grand Challenges in Energy by Secretary Steven Chu | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping STD-1128-2013 April 2013 DOEOwnedGrand JunctionGrand

  13. Investigations of segregation phenomena in highly strained Mn-doped Ge wetting layers and Ge quantum dots embedded in silicon

    SciTech Connect (OSTI)

    Prestat, E., E-mail: eric.prestat@gmail.com; Porret, C.; Favre-Nicolin, V.; Tainoff, D.; Boukhari, M.; Bayle-Guillemaud, P.; Jamet, M.; Barski, A., E-mail: andre.barski@cea.com [INAC, SP2M, CEA and Université Joseph Fourier, 17 rue des Martyrs, 38054 Grenoble (France)

    2014-03-10

    In this Letter, we investigate manganese diffusion and the formation of Mn precipitates in highly strained, few monolayer thick, Mn-doped Ge wetting layers and nanometric size Ge quantum dot heterostructures embedded in silicon. We show that in this Ge(Mn)/Si system manganese always precipitates and that the size and the position of Mn clusters (precipitates) depend on the growth temperature. At high growth temperature, manganese strongly diffuses from germanium to silicon, whereas decreasing the growth temperature reduces the manganese diffusion. In the germanium quantum dots layers, Mn precipitates are detected, not only in partially relaxed quantum dots but also in fully strained germanium wetting layers between the dots.

  14. Ferromagnetic (Ga,Mn)As nanostructures for spintronic applications

    SciTech Connect (OSTI)

    Wosinski, Tadeusz; Andrearczyk, Tomasz; Figielski, Tadeusz; Makosa, Andrzej; Wrobel, Jerzy; Sadowski, Janusz

    2013-12-04

    Magneto-resistive, cross-like nanostructures have been designed and fabricated by electron-beam lithography patterning and chemical etching from thin epitaxial layers of the ferromagnetic semiconductor (Ga,Mn)As. The nanostructures, composed of two perpendicular nanostripes crossing in the middle of their length, represent four-terminal devices, in which an electric current can be driven through any of the two nanostripes. In these devices, a novel magneto-resistive memory effect, related to a rearrangement of magnetic domain walls in the central part of the device, has been demonstrated. It consists in that the zero-field resistance of a nanostripe depends on the direction of previously applied magnetic field. The nanostructures can thus work as two-state devices providing basic elements of nonvolatile memory cells.

  15. Impedance analysis of MnCoCuO NTC ceramic

    SciTech Connect (OSTI)

    Song, S.G. . E-mail: song-ph0@wpmail.paisley.ac.uk; Ling, Z.; Placido, F.

    2005-07-12

    Impedance spectroscopy is often used to analyse the electrical properties of ceramic materials having high-resistive grain boundaries, such as ZnO and SrTiO{sub 3}. Fewer attempts have been made at using this technique for the analysis of inhomogeneous electronic ceramics consisting of grains with differing composition, such as those occurring in negative temperature coefficient (NTC) thermistors. In this study, we have attempted to adopt ac impedance spectroscopy together with other techniques to analyse an NTC thermistor ceramic material. An Mn, Co and Cu multielements transition metal oxide (MnCoCuO) ceramic was prepared by using homogeneous precipitation employing oxalic acid. This material displayed a typical NTC effect, showing an electrical resistance decrease with temperature when dc electrical measurement was performed. The ac impedance spectroscopy analysis showed that there were two peaks in impedance and conductance versus frequency plot. By using an alternative representation of impedance spectra Z'/f versus Z', three distinct relaxation frequency ranges were identified. They are believed to originate, respectively, from the electrode, phase 1 (rich-Cu phase) and phase 2 (poor-Cu phase) grains existing in this ceramic. SEM observation and EDX analysis clearly showed existence of two distinct phase grains. The resistance values were derived from phases 1 and 2 grains based on ac impedance data. The sum of the resistance values was in good agreement with that from dc measurement in the temperature range of 30-95 deg. C. The material constant, B, for the two phases was also calculated, giving 3100 and 3600 K for phases 1 and 2, respectively.

  16. Archeomagnetism of potsherds from Grand Banks, Ontario: a test of low paleointensities in Ontario around A.D. 1000

    E-Print Network [OSTI]

    Dunlop, David J.

    Archeomagnetism of potsherds from Grand Banks, Ontario: a test of low paleointensities in Ontario from Grand Banks, southern Ontario. 14 C dating on maize found in the same pit as the potsherds gives is in agreement with the low virtual axial dipole moment values given by studies on material from Ontario compared

  17. Statistical analysis of lateral migration of the Rio Grande, Gigi A. Richarda,T, Pierre Y. Julienb

    E-Print Network [OSTI]

    Julien, Pierre Y.

    Statistical analysis of lateral migration of the Rio Grande, New Mexico Gigi A. Richarda,T, Pierre migration rates of alluvial rivers are affected by changes in water and sediment regimes. The Rio Grande, and water and sediment regimes. A statistical analysis reveals that migration rates primarily decreased

  18. Quantum Anomalous Hall Effect in Hg_1-yMn_yTe Quantum Wells

    SciTech Connect (OSTI)

    Liu, Chao-Xing; /Tsinghua U., Beijing /Stanford U., Phys. Dept.; Qi, Xiao-Liang; /Stanford U., Phys. Dept.; Dai, Xi; Fang, Zhong; /Beijing, Inst. Phys.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept.

    2010-03-19

    The quantum Hall effect is usually observed when the two-dimensional electron gas is subjected to an external magnetic field, so that their quantum states form Landau levels. In this work we predict that a new phenomenon, the quantum anomalous Hall effect, can be realized in Hg{sub 1-y}Mn{sub y}Te quantum wells, without the external magnetic field and the associated Landau levels. This effect arises purely from the spin polarization of the Mn atoms, and the quantized Hall conductance is predicted for a range of quantum well thickness and the concentration of the Mn atoms. This effect enables dissipationless charge current in spintronics devices.

  19. Recent progress of magnetocaloric effect and magnetic refrigerant materials of Mn compounds (invited)

    SciTech Connect (OSTI)

    Wada, H. Takahara, T.; Katagiri, K.; Ohnishi, T.; Soejima, K.; Yamashita, K.

    2015-05-07

    Magnetocaloric and related properties of Ru and Ni substituted (MnFe){sub 2}(PSi) are presented. It is found that Ru and Ni are effective doping elements to reduce the thermal hysteresis of (MnFe){sub 2}(PSi). The origin of the thermal hysteresis is discussed on the basis of a thermodynamic model. It is shown that the elastic energy is responsible for the thermal hysteresis. We also show recent developments of the production process of Mn compounds in an industrial scale.

  20. Serving the Readers of Scholarly Documents: A Grand Challenge for the Introspective Digital

    E-Print Network [OSTI]

    Kan, Min-Yen

    Serving the Readers of Scholarly Documents: A Grand Challenge for the Introspective Digital Library of attention for scholars, as the wealth of facts, facets and connections in scholarly documents are large. Such machine analysis can derive insights that can inform policy makers, academic and industrial management

  1. Survival and mammalian predation of Rio Grande Turkeys on the Edwards Plateau, Texas. 

    E-Print Network [OSTI]

    Willsey, Beau Judson

    2004-09-30

    Trends in Rio Grande wild turkey (Meleagris gallopavo intermedia) abundance on the Edwards Plateau (EP), Texas, have been either stable or in decline since the 1970s. Four study areas, 2 each within stable (Stable Area A, SAA; Stable Area B, SAB...

  2. Data Mining: Data Analysis on a Grand Scale? \\Lambda Padhraic Smyth

    E-Print Network [OSTI]

    Smyth, Padhraic

    Data Mining: Data Analysis on a Grand Scale? \\Lambda Padhraic Smyth Information and Computer data mining has evolved largely as a result of efforts by computer scientists to address the needs of this historical context, data mining to date has largely focused on computational and algorithmic issues rather

  3. Planning the New Citrus Orchard in the Lower Rio Grande Valley. 

    E-Print Network [OSTI]

    Maxwell, Norman P. (Norman Paul)

    1951-01-01

    horticulturist for the Lower Rio Grande Valley Experiment Station at Weslaco, Texas. The committee included representatives of the Texas Agricultural Experiment Station, the Texas Agricultural Extension Service and the Texas Citrus Commission. CONTENTS... .................................................. 17 Tangors ................................................ 17 Lemons ................................................... 18 Other Citrus .................................................. 18 Planting Considerations...

  4. Geothermal research project sets sights on Grande Prairie By Jenny Oatway May 20, 2015

    E-Print Network [OSTI]

    Wang, Hao "Howard"

    off between the cost of drilling that deep and also much less is known about the reservoirs Geothermal research project sets sights on Grande Prairie By Jenny Oatway May 20, 2015 City Council is excited about an opportunity to explore the potential for harnessing geothermal energy

  5. Select Economic Implications for the Biological Control of Arundo donax along the Rio Grande 

    E-Print Network [OSTI]

    Seawright, Emily Kaye

    2010-10-12

    Arundo donax, or giant reed, is a large, bamboo-like plant native to Spain that has invaded several thousand acres of the Rio Grande riparian in Texas. The plant grows to 18-24 feet, consuming large quantities of water ...

  6. Future Directions in Control, Dynamics, and Systems: Overview, Grand Challenges, and New Courses

    E-Print Network [OSTI]

    Murray, Richard M.

    Future Directions in Control, Dynamics, and Systems: Overview, Grand Challenges, and New Courses and recommendations of a recent panel on Future Di- rections in Control, Dynamics, and Systems, sponsored by the US on Future Directions in Control and Dynamical Systems was formed to prepare a report to provide a renewed

  7. Case Study: Modeling the Lateral Mobility of the Rio Grande below Cochiti Dam, New Mexico

    E-Print Network [OSTI]

    Julien, Pierre Y.

    Case Study: Modeling the Lateral Mobility of the Rio Grande below Cochiti Dam, New Mexico Gigi A, lateral migration, and total lateral movement. By 2001, the width of the Cochiti Reach was close width, 78­90% of variance in migration rates, and 92% of the variance in total lateral movement between

  8. A Grand Challenge for the Future Grid A PSERC White Paper

    E-Print Network [OSTI]

    the white paper, the lead authors consulted with industry and university PSERC members. Feedback on an earlyA Grand Challenge for the Future Grid A PSERC White Paper Power Systems Engineering Research Center A White Paper from the Power Systems Engineering Research Center Lead Authors Chris DeMarco, University

  9. SICE Annual Conference 2010 August 18-21, 2010, The Grand Hotel, Taipei, Taiwan

    E-Print Network [OSTI]

    Lin, Pei-Chun

    SICE Annual Conference 2010 August 18-21, 2010, The Grand Hotel, Taipei, Taiwan ¥400 © 2010 SICE of Mechanical Engineering, National Taiwan University Taipei, Taiwan Corresponding email: peichunlin@ntu.edu.tw Chia-Hung Tsai Department of Mechanical Engineering, National Taiwan University Taipei, Taiwan

  10. Grand challenge problems in environmental modeling and remediation: groundwater contaminant transport

    SciTech Connect (OSTI)

    Todd Arbogast; Steve Bryant; Clint N. Dawson; Mary F. Wheeler

    1998-08-31

    This report describes briefly the work of the Center for Subsurface Modeling (CSM) of the University of Texas at Austin (and Rice University prior to September 1995) on the Partnership in Computational Sciences Consortium (PICS) project entitled Grand Challenge Problems in Environmental Modeling and Remediation: Groundwater Contaminant Transport.

  11. Nutlet Production and Germination of Amsinckla grand/flora I. Measurements From Cultivated Populations

    E-Print Network [OSTI]

    Nutlet Production and Germination of Amsinckla grand/flora I. Measurements From Cultivated Contract No. C-2065 July 1988 #12;1 Paviik, B. M. 1988. Nutlet Production and Germination of Amsinckia arandiflora I. Measurements From Cultivated Populations. State of California, Department of Fish and Game

  12. Recovery sequences for a station blackout accident at the Grand Gulf Nuclear Station

    SciTech Connect (OSTI)

    Carbajo, J.J. [Martin Marietta Energy Systems, Oak Ridge, TN (United States)

    1995-12-31

    Recovery sequences for a low-pressure, short term, station blackout severe accident at the Grand Gulf power plant have been investigated using the computer code MELCOR, version 1.8.3 PN. This paper investigates the effect of reflood timing and mass flow rate on accident recovery.

  13. A Grand Solar Plan for Chile www.clca.columbia.edu

    E-Print Network [OSTI]

    % RE (2025) #12;4 U.S. Annually Installed Capacities and Prices AnnualPVInstallations(MW) Average Capacity Total U.S. Solar Capacity Under the SunShot and Reference Scenarios Achieving SunShot cost1 A Grand Solar Plan for Chile www.clca.columbia.edu Vasilis Fthenakis Center for Life Cycle

  14. Peak discharge of a Pleistocene lava-dam outburst flood in Grand Canyon, Arizona, USA

    E-Print Network [OSTI]

    in channel geometry, dam height, and hydraulic characteristics, ranged from 2.3 to 5.3 × 105 m3 s-1 Canyon; Colorado river; Pleistocene floods; Lava dams; Hydraulic modeling; Paleoflood indicators; DamPeak discharge of a Pleistocene lava-dam outburst flood in Grand Canyon, Arizona, USA Cassandra R

  15. First-principles study of spin-transfer torque in Co{sub 2}MnSi/Al/Co{sub 2}MnSi spin-valve

    SciTech Connect (OSTI)

    Tang, Ling, E-mail: lingtang@zjut.edu.cn; Yang, Zejin, E-mail: zejinyang@zjut.edu.cn [Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023 (China)

    2013-11-21

    The spin-transfer torque (STT) in Co{sub 2}MnSi(CMS)/Al/Co{sub 2}MnSi spin-valve system with and without interfacial disorder is studied by a first-principles noncollinear wave-function-matching method. It is shown that in the case of clean interface the angular dependence of STT for CoCo/Al (the asymmetry parameter ??4.5) is more skewed than that for MnSi/Al (??2.9), which suggests the clean CoCo/Al architecture is much more efficient for the application on radio frequency oscillation. We also find that even with interfacial disorder the spin-valve of half-metallic CMS still has a relatively large parameter ? compared to that of conventional ferromagnet. In addition, for clean interface the in-plane torkance of MnSi/Al is about twice as large as that of CoCo/Al. However, as long as the degree of interfacial disorder is sufficiently large, the CoCo/Al and MnSi/Al will show approximately the same magnitude of in-plane torkance. Furthermore, our results demonstrate that CMS/Al/CMS system has very high efficiency of STT to switch the magnetic layer of spin-valve.

  16. Mn solid solutions in self-assembled Ge/Si (001) quantum dot heterostructures

    SciTech Connect (OSTI)

    Kassim, J.; Nolph, C.; Reinke, P.; Floro, J. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Jamet, M. [Institut Nanosciences et Cryogenie/SP2M, CEA-UJF, F-38054 Grenoble (France)

    2012-12-10

    Heteroepitaxial Ge{sub 0.98}Mn{sub 0.02} quantum dots (QDs) on Si (001) were grown by molecular beam epitaxy. The standard Ge wetting layer-hut-dome-superdome sequence was observed, with no indicators of second phase formation in the surface morphology. We show that Mn forms a dilute solid solution in the Ge quantum dot layer, and a significant fraction of the Mn partitions into a sparse array of buried, Mn-enriched silicide precipitates directly underneath a fraction of the Ge superdomes. The magnetic response from the ultra-thin film indicates the absence of robust room temperature ferromagnetism, perhaps due to anomalous intermixing of Si into the Ge quantum dots.

  17. Prospects for high temperature ferromagnetism in (Ga,Mn)As semiconductors 

    E-Print Network [OSTI]

    Jungwirth, T.; Wang, KY; Masek, J.; Edmonds, KW; Konig, J.; Sinova, Jairo; Polini, M.; Goncharuk, NA; MacDonald, AH; Sawicki, M.; Rushforth, AW; Campion, RP; Zhao, LX; Foxon, CT; Gallagher, BL.

    2005-01-01

    We report on a comprehensive combined experimental and theoretical study of Curie temperature trends in (Ga,Mn)As ferromagnetic semiconductors. Broad agreement between theoretical expectations and measured data allows us to conclude that T-c in high...

  18. Effect of Mn substitution on the transport properties of co-sputtered...

    Office of Scientific and Technical Information (OSTI)

    exhibit a high spin polarization with a high Curie temperature to be applied in spintronic devices, and in order to further study the effect of Mn contents on the physical...

  19. Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals

    E-Print Network [OSTI]

    Techapiesancharoenkij, Ratchatee, 1979-

    2007-01-01

    Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

  20. Formation of nano-crystalline todorokite from biogenic Mn Xiong Han Feng a,1

    E-Print Network [OSTI]

    Sparks, Donald L.

    Formation of nano-crystalline todorokite from biogenic Mn oxides Xiong Han Feng a,1 , Mengqiang Zhu oxides in the environment. Additionally this method may be a viable biosynthesis route for porous, nano-crystalline

  1. Irradiated Esophageal Cells are Protected from Radiation-Induced Recombination by MnSOD Gene Therapy

    E-Print Network [OSTI]

    Niu, Yunyun

    Radiation-induced DNA damage is a precursor to mutagenesis and cytotoxicity. During radiotherapy, exposure of healthy tissues can lead to severe side effects. We explored the potential of mitochondrial SOD (MnSOD) gene ...

  2. Growth of GaMnAs under near-stoichiometric conditions

    SciTech Connect (OSTI)

    Avrutin, V.; Humienik, D.; Frank, S.; Koeder, A.; Schoch, W.; Limmer, W.; Sauer, R.; Waag, A. [Abteilung Halbleiterphysik, Universitaet Ulm, D-89069 Ulm (Germany); Institut fuer Halbleitertechnik, Technische Universitaet (TU) Braunschweig, Hans-Sommer-Strasse 66, D38103 Braunschweig (Germany)

    2005-07-15

    We studied the effect of the V/III flux ratio and substrate temperature on magnetotransport properties and lattice parameters of Ga{sub 0.96}Mn{sub 0.04}As grown by molecular-beam epitaxy. For all the substrate temperatures, the conductivities and Curie temperatures of the layers were found to increase as the V/III flux ratio approaches 1. A Curie temperature as high as 95 K was achieved for the Ga{sub 0.96}Mn{sub 0.04}As samples grown at 240 deg. C and a V/III ratio of about 1.5. The lattice parameter of Ga{sub 0.96}Mn{sub 0.04}As increased with decreasing V/III ratio and/or increasing growth temperature. Possible reasons for the effect of the V/III ratio on the magnetotransport properties and lattice parameter of GaMnAs are discussed.

  3. Dispersive magnetic excitations in the S=1 antiferromagnet Ba3Mn2O8

    SciTech Connect (OSTI)

    Stone, Matthew B [ORNL; Lumsden, Mark D [ORNL; Qiu, Y. [National Institute of Standards and Technology (NIST); Samulon, Eric C [Stanford University; Batista, C. D. [Los Alamos National Laboratory (LANL); Fisher, Ian R [Stanford University

    2008-01-01

    We present powder inelastic neutron scattering measurements of the $S=1$ dimerized antiferromagnet Ba$_3$Mn$_2$O$_8$. The $T=1.4$~K~magnetic spectrum exhibits a spin-gap of $\\Delta = 0.9$~meV and a dispersive spectrum with a bandwidth of approximately $1.74$~meV. Comparison to coupled dimer models describe the dispersion and scattering intensity accurately and determine the exchange constants in Ba$_3$Mn$_2$O$_8$. Interdimer exchange between triangular lattice dimer bilayers in Ba$_3$Mn$_2$O$_8$ is two orders of magnitude weaker than intradimer exchange. Ba$_3$Mn$_2$O$_8$ is thus a quasi-two-dimensional frustrated bilayer triangular lattice of $S=1$ dimers. The wave vector dependent scattering intensity confirms the proposed $S=1$ dimer bond. Temperature dependent measurements of the magnetic excitations indicate the presence of both singlet-triplet and thermally activated triplet-quintet excitations.

  4. Ferromagnetic transition temperature enhancement in (Ga,Mn)As semiconductors by carbon codoping 

    E-Print Network [OSTI]

    Jungwirth, T.; Masek, J.; Sinova, Jairo; MacDonald, AH.

    2003-01-01

    We present a theoretical study of (Ga,Mn)(As,C) diluted magnetic semiconductors with high C acceptor density that combines insights from phenomenological model and microscopic approaches. A tight-binding coherent-potential approximation is used...

  5. Decay of neutron-rich Mn nuclides and deformation of heavy Fe isotopes

    E-Print Network [OSTI]

    M. Hannawald; T. Kautzsch; A. Woehr; W. B. Walters; K. -L. Kratz; V. N. Fedoseyev; V. L. Mishin; W. Boehmer; B. Pfeiffer; V. Sebastian; Y. Jading; U. Koester; J. Lettry; H. L. Ravn; the ISOLDE Collaboration

    1998-12-21

    The use of chemically selective laser ionization combined with beta-delayed neutron counting at CERN/ISOLDE has permitted identification and half-life measurements for 623-ms Mn-61 up through 14-ms Mn-69. The measured half-lives are found to be significantly longer near N=40 than the values calculated with a QRPA shell model using ground-state deformations from the FRDM and ETFSI models. Gamma-ray singles and coincidence spectroscopy has been performed for Mn-64 and Mn-66 decays to levels of Fe-64 and Fe-66, revealing a significant drop in the energy of the first 2+ state in these nuclides that suggests an unanticipated increase in collectivity near N=40.

  6. Quantum Chemical Study of Arsenic (III, V) Adsorption on Mn-Oxides

    E-Print Network [OSTI]

    Sparks, Donald L.

    sites under simulated acidic pH conditions. Therefore, we propose that As(V) adsorption inhibits As(III) oxidation by blocking adsorption sites. Under simulated acidic pH conditions, Mn(IV) sites exhibited

  7. Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past water-column

    E-Print Network [OSTI]

    Gilli, Adrian

    Combining sedimentological, trace metal (Mn, Mo) and molecular evidence for reconstructing past online 22 June 2013 Abstract Here, we present sedimentological, trace metal, and molecular evidence underscores the value of combining sedimentological, geochemical, and microbiological approaches

  8. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

    E-Print Network [OSTI]

    Nelson-Cheeseman, B. B.

    2007-01-01

    2 O 4 –Fe 3 O 4 spinel interfaces B. B. Nelson-Cheeseman,isostructural spinel-spinel interface of NiMn 2 O 4 (NMO)–Feis preserved, both bulk and interface sensitive measurements

  9. Hydrothermal synthesis of Mn vanadate nanosheets and visible-light photocatalytic performance for the degradation of methyl blue

    SciTech Connect (OSTI)

    Pei, L.Z. Xie, Y.K.; Pei, Y.Q.; Jiang, Y.X.; Yu, H.Y.; Cai, Z.Y.

    2013-07-15

    Graphical abstract: - Highlights: • Mn vanadate nanosheets have been synthesized by simple hydrothermal process. • The formation of Mn vanadate nanosheets can be controlled by growth conditions. • Mn vanadate nanosheets exhibit good photocatalytic activities for methyl blue. - Abstract: Mn vanadate nanosheets have been synthesized via a facile hydrothermal route using ammonium metavanadate and Mn acetate as the raw materials, polyvinyl pyrrolidone (PVP) as the surfactant. X-ray diffraction (XRD) shows that the Mn vanadate nanosheets are composed of monoclinic MnV{sub 2}O{sub 6} phase. Scanning electron microscopy (SEM) observation indicates that the nanosheets have the average thickness of about 50 nm, length of 2–10 ?m and width of 800 nm to 2 ?m. The growth process of the Mn vanadate nanosheets has also been discussed based on the analysis of the roles of the growth conditions on the formation of the Mn vanadate nanosheets. The nanosheets show good photocatalytic activities for the degradation of methylene blue (MB) under visible light irradiation. About 72.96% MB can be degraded after visible light irradiation for 1 h over 10 mg Mn vanadate nanosheets in 10 mL MB solution with the concentration of 10 mg L{sup ?1}.

  10. Magnetic Order and Ferroelectricity in RMnO3 Multiferroic Manganites: Coupline Between R- and Mn-spins

    SciTech Connect (OSTI)

    Aliouane, N.; Prokhnenko, O; Feyerherm, R; Mostovoy, M; Strempfer, J; Habicht, K; Rule, K; Dudzik, E; Wolter, A; et. al.

    2008-01-01

    Combining polarized and unpolarized neutron scattering techniques with x-ray resonant magnetic scattering we have studied the coupling between the Mn- and R-spin-ordering in the multiferroic RMnO3, R = Tb and Dy. Polarized neutron diffraction reveals the moment orientation associated with the various modes describing the complex magnetic ordering observed in TbMnO3, while neutron diffraction in high magnetic fields allows the identification of the origin (Mn versus Tb) of the various modes. In this way we identify significant Cx and Fz contributions from Tb arising from the coupling of Tb moments to the Mn cycloidal ordering. The x-ray studies give further insight into this coupling. In the ferroelectric phase, both TbMnO3 and DyMnO3 show an induced ordering of the R-ion with a propagation vector clamped to the Mn ordering. While in TbMnO3 this clamping leads to a ground state in which the two propagation vectors tTb and tMn obey the relation 3tTb-tMn = 1, in DyMnO3 the ferroelectric polarization is effectively enhanced. The theoretical analysis of these effects not only explains the observed behavior for R = Tb and Dy but can also be applied to understand the Mn-R interaction in the related compounds with R = Gd and Ho. Finally we show both experimentally and theoretically how the Mn-R coupling can enhance the ferroelectric polarization in this manganite's multiferroics.

  11. Magnetic properties and loss separation in iron-silicone-MnZn ferrite soft magnetic composites

    SciTech Connect (OSTI)

    Wu, Shen; Sun, Aizhi; Xu, Wenhuan; Zou, Chao; Yang, Jun; Dong, Juan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing (China)

    2013-12-16

    This paper investigates the magnetic and structural properties of iron-based soft magnetic composites coated with silicone-MnZn ferrite hybrid. The organic silicone resin was added to improve the flexibility of the insulated iron powder and causes better adhesion between particles to increase the mechanical properties. Scanning electron microscopy and distribution maps show that the iron particle surface is covered with a thin layer of silicone-MnZn ferrite. Silicone-MnZn ferrite coated samples have higher permeability when compared with the non-magnetic silicone resin coated compacts. The real part of permeability increases by 34.18% when compared with the silicone resin coated samples at 20 kHz. In this work, a formula for calculating the total loss component by loss separation method is presented and finally the different parts of total losses are calculated. The results show that the eddy current loss coefficient is close to each other for the silicone-MnZn ferrite, silicone resin and MnZn ferrite coated samples (0.0078MnZn ferrite coated sample (k{sub 2} =1.4058) in comparison with other samples.

  12. The structure of the Caenorhabditis elegans manganese superoxide dismutase MnSOD-3-azide complex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hunter, Gary J.; Trinh, Chi H.; Bonetta, Rosalin; Stewart, Emma E.; Cabelli, Diane E.; Hunter, Therese

    2015-08-27

    C. elegans MnSOD-3 has been implicated in the longevity pathway and its mechanism of catalysis is relevant to the aging process and carcinogenesis. The structures of MnSOD-3 provide unique crystallographic evidence of a dynamic region of the tetrameric interface (residues 41–54). We have determined the structure of the MnSOD-3-azide complex to 1.77-Å resolution. The analysis of this complex shows that the substrate analog, azide, binds end-on to the manganese center as a sixth ligand and that it ligates directly to a third and new solvent molecule also positioned within interacting distance to the His30 and Tyr34 residues of the substratemore »access funnel. This is the first structure of a eukaryotic MnSOD-azide complex that demonstrates the extended, uninterrupted hydrogen-bonded network that forms a proton relay incorporating three outer sphere solvent molecules, the substrate analog, the gateway residues, Gln142, and the solvent ligand. This configuration supports the formation and release of the hydrogen peroxide product in agreement with the 5-6-5 catalytic mechanism for MnSOD. The high product dissociation constant k? of MnSOD-3 reflects low product inhibition making this enzyme efficient even at high levels of superoxide.« less

  13. Distribution, Natural History, and Parasites of Mammals of Cook County, Minnesota

    E-Print Network [OSTI]

    Timm, Robert M.

    1975-12-30

    labels of some specimens from Cook County provide only a legal de- scription of the locality where the specimen originated. These were converted to a form 10 with mileage from some point of reference as follows: NW X Sec. 8, T. 64 N; R. 1 W ( = 20... mi. N, 6 mi. W Grand Marais) Sec. 33, T. 63 N, R. 1 E ( = 10 mi. N Grand Marais) NE M Sec. 8, T. 64 N, R. 3 E ( = 14 mi. N, 5 mi. W Hovland) NE J£ Sec. 22, T. 64 N, R. 3 E ( = 12 mi. N, 3 mi. W Hovland) NE }i Sec. 32, T. 63 N, R. 4 E ( = 4X mi...

  14. A simple grand canonical approach to compute the vapor pressure of bulk and finite size systems

    SciTech Connect (OSTI)

    Factorovich, Matías H.; Scherlis, Damián A.

    2014-02-14

    In this article we introduce a simple grand canonical screening (GCS) approach to accurately compute vapor pressures from molecular dynamics or Monte Carlo simulations. This procedure entails a screening of chemical potentials using a conventional grand canonical scheme, and therefore it is straightforward to implement for any kind of interface. The scheme is validated against data obtained from Gibbs ensemble simulations for water and argon. Then, it is applied to obtain the vapor pressure of the coarse-grained mW water model, and it is shown that the computed value is in excellent accord with the one formally deduced using statistical thermodynamics arguments. Finally, this methodology is used to calculate the vapor pressure of a water nanodroplet of 94 molecules. Interestingly, the result is in perfect agreement with the one predicted by the Kelvin equation for a homogeneous droplet of that size.

  15. Twisted spectral triple for the Standard Model and spontaneous breaking of the Grand Symmetry

    E-Print Network [OSTI]

    Agostino Devastato; Pierre Martinetti

    2015-01-29

    Grand symmetry models in noncommutative geometry have been introduced to explain how to generate minimally (i.e. without adding new fermions) an extra scalar field beyond the standard model, which both stabilizes the electroweak vacuum and makes the computation of the mass of the Higgs compatible with its experimental value. In this paper, we use Connes-Moscovici twisted spectral triples to cure a technical problem of the grand symmetry, that is the appearance together with the extra scalar field of unbounded vectorial terms. The twist makes these terms bounded and - thanks to a twisted version of the first-order condition that we introduce here - also permits to understand the breaking to the standard model as a dynamical process induced by the spectral action. This is a spontaneous breaking from a pre-geometric Pati-Salam model to the almost-commutative geometry of the standard model, with two Higgs-like fields: scalar and vector.

  16. Lower Rio Grande Valley transboundary air pollution project (TAPP). Project report 1996--1997

    SciTech Connect (OSTI)

    Mukerjee, S.; Shadwick, D.S.; Dean, K.E.; Carmichael, L.Y.; Bowser, J.J.

    1999-04-01

    The Lower Rio Grande Valley Transboundary Air Pollution Project (TAPP) was a US-Mexico Border XXI project to find out if air pollutants were moving across the border from Mexico into the Lower Rio Grande Valley of Texas and to see what levels of air pollutants were present. Ambient measurements and meteorology were collected data for a year (March 1996-March 1997) at three fixed sites in and near Brownsville, Texas very close to the US-Mexico border on a continuous and 24-h internal basis. Overall levels of air pollution were similar to or lower than other areas in Texas and elsewhere. Based on wind sector analyses, transport of air pollution across the border did not appear to adversely impact air quality on the US side of the Valley. Southeasterly winds from the Gulf of Mexico were largely responsible for the clean air conditions.

  17. Une egalite du grand crible pour les entiers sans facteurs carres

    E-Print Network [OSTI]

    Ramaré, Olivier

    Une ´egalit´e du grand crible pour les entiers sans facteurs carr´es O. Ramar´e September 24, 2013 manipuler la suite des entiers sans facteurs carr´es. Un entier est dit sans facteurs carr´es lorsque [p´etique). Signalons ici que l'on a nN µ2 (n) = (6/2 )N + O( N) c'est `a dire qu'il y a beaucoup d'entiers sans

  18. Economies of size in municipal water treatment technologies: Texas lower Rio Grande Valley 

    E-Print Network [OSTI]

    Boyer, Christopher Neil

    2008-10-10

    surface-water contamination. This research specifically focuses on investigating economies of size for conventional surface-water treatment and brackish-groundwater desalination by using results from four water treatment facilities in the Texas Lower Rio... Grande Valley (LRGV). The methodology and results can have direct implications on future water planning. iv Economic and financial life-cycle costs were estimated for a “small”- conventional-surface water facility (2.0 million gallons per day (mgd...

  19. Strobe Light Deterrent Efficacy Test and Fish Behavior Determination at Grand Coulee Dam Third Powerplant Forebay

    SciTech Connect (OSTI)

    Simmons, Mary Ann; Johnson, Robert L.; McKinstry, Craig A.; Simmons, Carver S.; Cook, Chris B.; Brown, Richard S.; Tano, Daniel K.; Thorsten, Susan L.; Faber, Derrek M.; Lecaire, Richard; Francis, Stephen

    2004-01-01

    This report documents the third year of a four-year study to assess the efficacy of a prototype strobe light system to elicit a negative phototactic response in kokanee salmon (Oncorhynchus nerka) and rainbow trout (O. mykiss) in the forebay to the third powerplant at Grand Coulee Dam. This work was conducted for the Bonneville Power Administration, U.S. Department of Energy, by Pacific Northwest National Laboratory (PNNL) in conjunction with the Confederated Tribes of the Colville Reservation (Colville Confederated Tribes).

  20. Evolution of Irrigation Districts and Operating Institutions: Texas, Lower Rio Grande Valley 

    E-Print Network [OSTI]

    Fernandez, Linda; Robinson, John R.C.; Lacewell, Ronald D.; Rister, M. Edward; Ellis, John R.; Sturdivant, Allen W.; Stubbs, Megan J.

    2003-01-01

    sugar plantation, but his venture ultimately failed due to financial problems (Tiefenbacher). Closner’s venture was the first of many irrigation companies created to accommodate the interest in irrigated agriculture. In the 1890s, land developers... Evolution of Irrigation Districts and Operating Institutions: Texas, Lower Rio Grande Valley Megan J. Stubbs M. Edward Rister Ronald D. Lacewell John R. Ellis Allen W. Sturdivant John R. C. Robinson Linda Fernandez...

  1. Industrial Heat Pumps: Appropriate Placement and Sizing Using the Grand Composite 

    E-Print Network [OSTI]

    Ranade, S. M.; Hindmarsh, E.; Boland, D.

    1986-01-01

    . The most sophisticated equipment designs can do very little to improve the cost-effectiveness of inappropriately placed heat pumps. The practice of designing heat pumps to fit particular unit operations without regard to the thermodynamic... characteristics of the total process may result in inefficient designs and is detrimental to the "image" of industrial heat pumps. In this paper the heat pump placement is dis cussed in the context of the total process. The process grand composite curve...

  2. Grand Valley State University Checks Out Energy Savings at New Mary Idema Pew Library

    SciTech Connect (OSTI)

    none,

    2013-03-01

    Grand Valley State University (GVSU) partnered with the Department of Energy (DOE) to develop and implement solutions to build new, low-energy buildings that are at least 50% below Standard 90.1-2007 of the American Society of Heating, Refrigerating, and Air-Conditioning Engineers (ASHRAE), the American National Standards Institute (ANSI), and the Illuminating Engineering Society of North America (IESNA) as part of DOE’s Commercial Building Partnerships (CBP) Program.

  3. Prospects for Photovoltaics in Sunny and Arid Regions: A Solar Grand Plan for Chile

    E-Print Network [OSTI]

    -Chile) #12;Chile: The Atacama Solar Resource Capacity: 4.6 GW Load: 15.4 TWh 50 MW 99 MW Station Horizontal,000-40,000 2,000-14,000 2,000-21,000 302 323 442 Installed capacity of renewable energies 1236 [MW] PotentialProspects for Photovoltaics in Sunny and Arid Regions: A Solar Grand Plan for Chile Part I

  4. Colaboracion de Einstein con los grandes matematicos de la epoca en la teoria de la

    E-Print Network [OSTI]

    Ruiz, Jesús M.

    Colaboraci´on de Einstein con los grandes matem´aticos de la ´epoca en la teor´ia de la relatividad las matem´aticas en la Teor´ia de la Relatividad. Para ello estudiaremos la recepci´on dada a dicha teor´ia por los matem´aticos de la ´epoca y su colaboraci´on con Einstein. 1. Conexiones entre las

  5. Ecosystem level assessment of the Grand Calumet Lagoons, Indiana Dunes National Lakeshore

    SciTech Connect (OSTI)

    Stewart, P.M. [National Biological Service, Porter, IN (United States)

    1995-12-31

    The Grand Calumet Lagoons make up the eastern section of the Grand Calumet River (GCR), Indiana Harbor and Ship Canal and nearshore Lake Michigan Area of Concern (AOC). The GCR AOC is the only one of the 42 Great Lakes Areas of Concern identified by the International Joint Commission with all 14 designated uses classified as impaired. Included within the boundaries of the Indiana Dunes National Lakeshore (INDU), is the central section of the Grand Calumet Lagoons. A number of biotic and abiotic factors were tested to determine the effects of an industrial landfill that borders the lagoons to assess the potential impact on park resources. Analysis included water quality testing, assessments of macroinvertebrate, fish, algae and aquatic plant communities and contaminant concentrations in water, sediment and plant and fish tissue. Surface water testing found very few contaminants, but significantly higher nutrient levels were found in the water column closest to the landfill. Macroinvertebrate, aquatic plant and fish communities all showed significant impairment in relationship to their proximity to the landfill. Aquatic plant growth habit became limited next to the landfill with certain growth habits disappearing entirely. Aquatic plants collected close to the landfill had high concentrations of several heavy metals in their stems and shoots. Using the index of biotic integrity (IBI), fish community assessment indicated impairment in the areas adjacent to the landfill. Sediments tested at one site had over 12% polycyclic aromatic hydrocarbons (PAH) and carp (Cyprinus carpio) collected from this site had whole fish tissue concentrations over 1 mg/kg PAH.

  6. Monitoring Fine Sediment; Grande Ronde and John Day Rivers, 2000 Annual Report.

    SciTech Connect (OSTI)

    Rhodes, Jonathan J.; Greene, M. Jonas; Purser, Michael D.

    2001-01-01

    Fine sediment in spawning substrate has a major effect on salmon survival from egg to smolt. Basin-wide restoration plans have established targets for fine sediment levels in spawning habitat. The project was initiated to monitor surface fine sediment levels and overwinter intrusion of fine sediment in spring chinook salmon spawning habitat in the North Fork John Day (NFJDR) and Grande Ronde Rivers, for five years. The project is also investigating the potential relationship between surface fine levels and overwinter sedimentation. It will provide data to assess trends in substrate conditions in monitored reaches and whether trends are consistent with efforts to improve salmon habitat conditions. The data on the magnitude of overwinter sedimentation will also be used to estimate salmon survival from egg to emergence. In Sept. 1998, 1999, and Aug. 2000, sites for monitoring overwinter sedimentation were established in salmon spawning habitat in the upper Grande Ronde River, Catherine Creek (a Grande Ronde tributary), the North Fork John Day River (NFJDR), and Granite Creek (a NFJDR tributary). Surface fine sediment levels were measured in these reaches via the grid method and visually estimated to test the relative accuracy of these two methods. In 1999 and 2000, surface fine sediment was also estimated via pebble counts at selected reaches to allow comparison of results among the methods. Overwintering substrate samples were collected in April 1999 and April-May 2000 to estimate the amount of overwinter sedimentation in clean gravels in spawning habitat. Monitoring methods and locations are described.

  7. Finite element analysis of the I-40 bridge over the Rio Grande

    SciTech Connect (OSTI)

    Farrar, C.R.; Duffey, T.A.; Goldman, P.A.; Jauregui, D.V.; Vigil, J.S.

    1996-01-01

    In the 1960s and 1970s numerous bridges were built in the US with a design similar to those on Interstate 40 (I-40) over the Rio Grande in Albuquerque, New Mexico. The Federal Highway Administration (FHWA) and the National Science Foundation (NSF) have provided funds to New Mexico State University (NMSU) through the New Mexico State Highway and Transportation Department (NMSH and TD) and The Alliance For Transportation Research (ATR) for evaluation and testing of the existing fracture-critical bridges over the Rio Grande. Because the I-40 Bridges over the Rio Grande were to be razed during the summer of 1993, the investigators were able to introduce damage into the structure in order to test various damage identification methods and to observe the changes in load paths through the structure caused by the cracking. To support this research effort, NMSU contracted Los Alamos National Laboratory (LANL) to perform experimental modal analyses, and to develop experimentally verified numerical models of the bridge. A previous report (LA-12767-MS) summarizes the results of the experimental modal analyses. This report summarizes the numerical analyses of the bridges and compares the results of these analyses to the experimental results.

  8. ROLE OF TRIVALENT Mn IN OXIDATION OF ORGANIC MATTER Christopher J. Matocha and D.L. Sparks

    E-Print Network [OSTI]

    Sparks, Donald L.

    organic matter^ M AT E R I A L S A N D M E T H O D S Reactivity studies of solid Mn(lll,IV) (hydr) oxide of available Mn(lli). R E S U L T S No correlation existed between the initial reductive dissolution ratesROLE OF TRIVALENT Mn IN OXIDATION OF ORGANIC MATTER Christopher J. Matocha and D.L. Sparks Dept

  9. Large scale and fast synthesis of multiferroic TbMn{sub 2}O{sub 5} single-crystalline nanorods

    SciTech Connect (OSTI)

    An, Xiaoxin; Wang, You; Deng, Jinxia; Chen, Jun, E-mail: junchen@ustb.edu.cn; Xing, Xianran, E-mail: xing@ustb.edu.cn

    2014-03-01

    Graphical abstract: - Highlights: • Pure TbMn{sub 2}O{sub 5} phase was synthesized in a wide temperature range for a short time. • Smooth and uniform single-crystalline nanorods were obtained. • The element Mn in TbMn{sub 2}O{sub 5} exhibits a mix Mn{sup 3+/4+} valence state with an average value of 3.5+, and the element Tb exhibits Tb{sup 3+}. - Abstract: Crystalline multiferroic TbMn{sub 2}O{sub 5} nanorods were successfully synthesized by a facile and scalable molten salt synthesis with NaCl–Na{sub 2}SO{sub 4} eutectic salts used in the temperature range of 750–900 °C for only 2 h. The obtained TbMn{sub 2}O{sub 5} could be indexed to an orthorhombic phase by the results of XRD patterns. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), combined with high-resolution TEM (HRTEM), selected area electron diffraction (SAED), and EDS, have been employed to investigate the morphology, size, crystallinity, structure, and composition of the as-synthesized TbMn{sub 2}O{sub 5} nanorods. The TbMn{sub 2}O{sub 5} product exhibits smooth, uniform and crystalline nanorods with diameters of 30–70 nm, and length of varying from 3 to 6 ?m. The results of X-ray photoelectron spectroscopy (XPS) analysis indicate that the elements Mn and Tb in TbMn{sub 2}O{sub 5} exhibit Mn{sup 3+/4+} and Tb{sup 3+}, respectively. The magnetic properties of the as-prepared TbMn{sub 2}O{sub 5} nanorods have been also characterized by physical properties measurement system (PPMS)

  10. Electron scattering mechanisms in Cu-Mn films for interconnect applications

    SciTech Connect (OSTI)

    Misják, F.; Nagy, K. H.; Radnóczi, G.; Lobotka, P.

    2014-08-28

    Electrical properties and corresponding structural features of Cu-Mn alloy films with potential application as barrier and interconnect layers were studied. Cu-Mn films were deposited by DC magnetron sputtering at room temperature on SiO{sub 2} substrates. Electrical resistivity measurements were made as a function of film composition and temperature. The specific resistivity varies linearly with the Mn content showing a maximum of 205???cm at 80 at. % Mn. The temperature coefficient of resistance (TCR) of all alloy films is low, showing non-metallic conductivity for most compositions. Also a minimum TCR has been observed in the 40–80 at. % Mn range which was attributed to a magnetic transformation around 200–300?K. Electrical resistivity measurements are correlated with the film structure revealed by transmission electron microscopy to clarify the phase regions throughout the composition range. In the 20–40 at. % and 70–80 at. % Mn ranges, two-phase structures were identified, where Cu- or Mn-rich solid solution grains were surrounded by a thin amorphous covering layer. Based on the revealed phase regions and morphologies electron scattering mechanisms in the system were evaluated by combining the Matthiessen's rule and the Mayadas-Schatzkes theory. Grain boundary reflectivity coefficients (r?=?0.6–0.8) were calculated from fitting the model to the measurements. The proposed model indicates that, in a binary system, the special arrangement of the two phases results in new scattering mechanisms. The results are of value in optimizing the various parameters needed to produce a suitable barrier layer.

  11. Properties of Ga{sub 1-x}Mn{sub x}As with high x (>0.1)

    SciTech Connect (OSTI)

    Chiba, D.; Yu, K. M.; Walukiewicz, W.; Nishitani, Y.; Matsukura, F.; Ohno, H.

    2008-04-01

    We have investigated the magnetic and the crystalline properties of a set of Ga{sub 1-x}Mn{sub x}As layers with high nominal Mn compositions (x=0.101-0.198). Magnetization measurements and combined channeling Rutherford backscattering (c-RBS) and particle induced x-ray emission (c-PIXE) measurements have been performed to determine the effective Mn composition x{sub eff} and the fraction of Mn atoms at various lattice sites. Here, x{sub eff} determined from magnetization measurements, which increases with increasing x, is consistent with the results determined from c-RBS-PIXE measurements.

  12. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01

    a test bed for simple spintronic devices. (In, Mn)As and (in novel electronic and spintronic materials have drawnpotential applications as spintronic materials. While many

  13. Electronic structure study of the magnetoresistance material CaCu3Mn4O12 by LSDA and LSDAU

    E-Print Network [OSTI]

    Gong, Xingao

    -like orbitals (dxy ,dyz , and dxz are almost full-filled, while the spin-up eg-like orbitals (d3z2 r2 and dx2 y2 of Mn3 (t2g 3 eg 1 ) and Mn4 (t2g 3 eg 0 ). Three spin- polarized d electrons in the t2g orbital of Mn3 and Mn4 cations form an inert spin core S 3/2, and the last one eg electron is itinerant. The eg electron

  14. Ranges, movements, and spatial distribution of radio-tagged Rio Grande wild turkeys in the Edwards Plateau of Texas 

    E-Print Network [OSTI]

    Schaap, Jody Neal

    2006-08-16

    To determine possible causes of declining Rio Grande wild turkey (RGWT; Meleagris gallopavo intermedia) abundance in the southern Edwards Plateau, research was conducted on 4 sites, 2 with stable (S [SA and SB]; Kerr and Real counties) and 2...

  15. EIS-0126: Remedial Actions at the Former Climax Uranium Company Uranium Mill Site, Grand Junction, Mesa County, Colorado

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this EIS to assess the environmental impacts of remediating the residual radioactive materials left from the inactive uranium processing site and associated properties located in Grand Junction, Colorado.

  16. Nonuniversal gaugino masses and muong-<mn>2mn>

    SciTech Connect (OSTI)

    Gogoladze, Ilia [Univ. of Delaware, Newark, DE (United States); Nasir, Fariha [Univ. of Delaware, Newark, DE (United States); Shafi, Qaisar [Univ. of Delaware, Newark, DE (United States); Ün, Cem Salih [Univ. of Delaware, Newark, DE (United States)

    2014-08-01

    We consider two classes of supersymmetric models with nonuniversal gaugino masses at the grand unification scale MGUT in an attempt to resolve the apparent muon g-2 anomaly encountered in the Standard Model. We explore two distinct scenarios, one in which all gaugino masses have the same sign at MGUT, and a second case with opposite sign gaugino masses. The sfermion masses in both cases are assumed to be universal at MGUT. We exploit the nonuniversality among gaugino masses to realize large mass splitting between the colored and noncolored sfermions. Thus, the sleptons can have masses in the few hundred GeV range, whereas the colored sparticles turn out to be an order of magnitude or so heavier. In both models the resolution of the muon g-2 anomaly is compatible, among other things, with a 125–126 GeV Higgs boson mass and the WMAP dark matter bounds.

  17. Enhanced ferromagnetic order in Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} featuring canted [MnO{sub 4}]{sub ?} spin chains of mixed-valent Mn(III)/Mn(IV). Aliovalent substitution of the Sr{sub 4?x}Ln{sub x}Mn{sup III}{sub 2+x}Mn{sup IV}{sub 1?x}O{sub 3}(GeO{sub 4}){sub 3} solid-solution

    SciTech Connect (OSTI)

    West, J. Palmer; Sulejmanovic, Dino; Becht, Gregory; He, Jian; Hitchcock, Dale; Yan, Yonggao; Hwu, Shiou-Jyh

    2013-10-15

    Crystals of Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0; x?0.15 for Ln=La, Pr, Nd, Sm. Eu, Gd, Dy; x?0.3 for Ln=Gd) were isolated upon using high-temperature, solid-state methods in molten-salt media. These compounds are isostructural with the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} (Ln=La, Sm, Gd) series that contains the same [MnO{sub 4}]{sub ?} spin chains. The synthesis of the Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} (x=0) phase was carried out by a double aliovalent substitution with respect to the Sr{sup 2+} and Ge{sup 4+} ions that replace Na{sup +}/Ln{sup 3+} and As{sup 5+} in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, respectively. The title series contains mixed-valent Mn(III)/Mn(IV) and shows a limited range of solid solution, both of which were not observed in the previously reported Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series. To form the Sr{sub 4?x}Ln{sub x}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} solid solution, one of the Sr{sup 2+} sites, i.e., the original Ln-site in Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}, is partially substituted by Ln{sup 3+} in a statistical disorder of Sr{sub 1?x}/Ln{sub x}. Initial magnetic investigations of selected derivatives reveal higher ferromagnetic ordering temperatures than those reported for the Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3} series, presumably attributed to a lesser degree of canting as a result of introducing non-Jahn–Teller Mn{sup 4+} ions. Also intriguing is the observation of multiple anomalies at low temperatures which appear to be of electronic origins. - Graphical abstract: Sr{sub 4?x}Ln{sub x}Mn(III){sub 2+x}Mn(IV){sub 1?x}O{sub 3}(GeO{sub 4}){sub 3}. Display Omitted - Highlights: • Double aliovalent substitution: Sr{sub 4}Mn{sub 3}O{sub 3}(GeO{sub 4}){sub 3} with respect to Na{sub 3}LnMn{sub 3}O{sub 3}(AsO{sub 4}){sub 3}. • Solid solution with respect to statistical disorder of Sr{sub 1?x}Ln{sub x} in one of the two Sr sites. • Mn{sup 3+}/Mn{sup 4+} magnetic ions are spatially arranged in a triangular kagomé fashion. • Enhanced ferromagnetic ordering attributed to doping non-Jahn–Teller Mn{sup 4+}.

  18. An Overview of the Operational Characteristics of Selected Irrigation Districts in the Texas Lower Rio Grande Valley: Brownsville Irrigation District 

    E-Print Network [OSTI]

    Stubbs, Megan J.; Rister, M. Edward; Sturdivant, Allen W.; Lacewell, Ronald D.

    2004-01-01

    – George Burlay purchased 1,000 acres 9 miles east of Brownsville called the Rio Grande Plantation. He began the first large-scale irrigation operation and successfully grew sugarcane. 1879 – Celestina Jagou purchased the former EAA 640 acres... of the Operational Characteristics of Selected Irrigation Districts in the Texas Lower Rio Grande Valley: Brownsville Irrigation District Megan J. Stubbs M. Edward Rister Allen W. Sturdivant Ronald D. Lacewell Texas Water...

  19. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-05-15

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles [1-2], among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials [3] and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique [4], including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  20. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-10-12

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles, among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique, including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  1. Disorder dependent half-metallicity in Mn{sub 2}CoSi inverse Heusler alloy

    SciTech Connect (OSTI)

    Singh, Mukhtiyar; Saini, Hardev S.; Thakur, Jyoti; Reshak, Ali H.; Kashyap, Manish K.

    2013-12-15

    Heusler alloys based thin-films often exhibit a degree of atomic disorder which leads to the lowering of spin polarization in spintronic devices. We present ab-initio calculations of atomic disorder effects on spin polarization and half-metallicity of Mn{sub 2}CoSi inverse Heusler alloy. The five types of disorder in Mn{sub 2}CoSi have been proposed and investigated in detail. The A2{sub a}-type and B2-type disorders destroy the half-metallicity whereas it sustains for all disorders concentrations in DO{sub 3a}- and A2{sub b}-type disorder and for smallest disorder concentration studied in DO{sub 3b}-type disorder. Lower formation energy/atom for A2{sub b}-type disorder than other four disorders in Mn{sub 2}CoSi advocates the stability of this disorder. The total magnetic moment shows a strong dependence on the disorder and the change in chemical environment. The 100% spin polarization even in the presence of disorders explicitly supports that these disorders shall not hinder the use of Mn{sub 2}CoSi inverse Heusler alloy in device applications. - Graphical abstract: Minority-spin gap (E{sub g?}) and HM gap (E{sub sf}) as a function of concentrations of various possible disorder in Mn{sub 2}CoSi inverse Heusler alloy. The squares with solid line (black color)/dotted line (blue color)/dashed line (red color) reperesents E{sub g?} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi and the spheres with solid line (black color)/dottedline (blue color)/dashed line (red color) represents E{sub sf} for DO{sub 3a}-/DO{sub 3b}-/A2{sub b}-type disorder in Mn{sub 2}CoSi. - Highlights: • The DO{sub 3}- and A2-type disorders do not affect the half-metallicity in Mn{sub 2}CoSi. • The B2-type disorder solely destroys half-metallicity in Mn{sub 2}CoSi. • The A2-type disorder most probable to occur out of all three types. • The total spin magnetic moment strongly depends on the disorder concentrations.

  2. High-Resolution Structure of the Photosynthetic Mn4Ca Catalyst from X-ray Spectroscopy

    SciTech Connect (OSTI)

    Yachandra, Vittal; Yano, Junko; Kern, Jan; Pushkar, Yulia; Sauer, Kenneth; Glatzel, Pieter; Bergmann, Uwe; Messinger, Johannes; Zouni, Athina; Yachandra, Vittal K.

    2007-08-01

    The application of high-resolution X-ray spectroscopy methods to study the photosynthetic water oxidizing complex, which contains a unique hetero-nuclear catalytic Mn4Ca cluster, are described. Issues of X-ray damage especially at the metal sites in the Mn4Ca cluster are discussed. The structure of the Mn4Ca catalyst at high-resolution which has so far eluded attempts of determination by X-ray diffraction, EXAFS and other spectroscopic techniques has been addressed using polarized EXAFS techniques applied to oriented PS II membrane preparations and PS II single crystals. A review of how the resolution of traditional EXAFS techniques can be improved, using methods such as range-extended EXAFS is presented, and the changes that occur in the structure of the cluster as it advances through the catalytic cycle are described. X-ray absorption and emission techniques (XANES and K? emission) have been used earlier to determine the oxidation states of the Mn4Ca cluster, and in this report we review the use of X-ray resonant Raman spectroscopy to understand the electronic structure of the Mn4Ca cluster as it cycles through the intermediate S-states.

  3. Electronic structural and magnetic properties of Mn{sub 5}Ge{sub 3} clusters

    SciTech Connect (OSTI)

    Yuan, H. K.; Chen, H. Kuang, A. L.; Tian, C. L.; Wang, J. Z.

    2013-11-28

    Theoretical understanding of the stability, ferromagnetism, and spin polarization of Mn{sub 5}Ge{sub 3} clusters has been performed by using the density functional theory with generalized gradient approximation for exchange and correlation. The magnetic moments and magnetic anisotropy energy (MAE) have been calculated for both bulk and clusters, and the enhanced magnetic moment as well as the enlarged MAE have been identified in clusters. The most attractive achievement is that Mn{sub 5}Ge{sub 3} clusters show a fine half-metallic character with large energy scales. The present results may have important implications for potential applications of small Mn{sub 5}Ge{sub 3} clusters as both emerging spintronics and next-generation data-storage technologies.

  4. Ferromagnetism and the electronic band structure in (Ga,Mn)(Bi,As) epitaxial layers

    SciTech Connect (OSTI)

    Yastrubchak, O., E-mail: yastrub@hektor.umcs.lublin.pl [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Institute of Semiconductor Physics, National Academy of Sciences, 41 pr. Nauki, 03028 Kyiv (Ukraine); Sadowski, J. [MAX-IV Laboratory, Lund University, P.O. Box 118, SE-221 00 Lund (Sweden); Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Gluba, L.; ?uk, J.; Kulik, M. [Institute of Physics, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 1, 20-031 Lublin (Poland); Domagala, J. Z.; Andrearczyk, T.; Wosinski, T. [Institute of Physics, Polish Academy of Sciences, Al. Lotnikow 32/46, 02-668 Warsaw (Poland); Rawski, M. [Analytical Laboratory, Maria Curie-Sklodowska University in Lublin, Pl. M. Curie-Sk?odowskiej 3, 20-031 Lublin (Poland)

    2014-08-18

    Impact of Bi incorporation into (Ga,Mn)As layers on their electronic- and band-structures as well as their magnetic and structural properties has been studied. Homogenous (Ga,Mn)(Bi,As) layers of high structural perfection have been grown by the low-temperature molecular-beam epitaxy technique. Post-growth annealing treatment of the layers results in an improvement of their structural and magnetic properties and an increase in the hole concentration in the layers. The modulation photoreflectance spectroscopy results are consistent with the valence-band model of hole-mediated ferromagnetism in the layers. This material combines the properties of (Ga,Mn)As and Ga(Bi,As) ternary compounds and offers the possibility of tuning its electrical and magnetic properties by controlling the alloy composition.

  5. Shell Model for Atomistic Simulation of Lithium Diffusion in Mixed Mn/Ti Oxides

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Chaka, Anne M.; Droubay, Timothy C.; Ilton, Eugene S.

    2014-10-23

    Mixed Mn/Ti oxides present attractive physicochemical properties such as their ability to accommodate Li for application in Li-ion batteries. In this work, atomic parameters for Mn were developed to extend an existing shell model of the Li-Ti-O system and allow simulations of pure and lithiated Mn and mixed Mn/Ti oxide polymorphs. The shell model yielded good agreement with experimentally-derived structures (i.e. lattice parameters and inter-atomic distances) and represented an improvement over existing potential models. The shell model was employed in molecular dynamics (MD) simulations of Li diffusion in the 1×1 c direction channels of LixMn1 yTiyO2 with the rutile structure, where 0 ? x ? 0.25 and 0 ? y ? 1. In the infinite dilution limit, the arrangement of Mn and Ti ions in the lattice was found to have a significant effect on the activation energy for Li diffusion in the c channels due to the destabilization of half of the interstitial octahedral sites. Anomalous diffusion was demonstrated for Li concentrations as low as x = 0.125, with a single Li ion positioned in every other c channel. Further increase in Li concentration showed not only the substantial effect of Li-Li repulsive interactions on Li mobility but also their influence on the time dependence of Li diffusion. The results of the MD simulations can inform intrinsic structure-property relationships for the rational design of improved electrode materials for Li-ion batteries.

  6. Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells

    E-Print Network [OSTI]

    2002-01-01

    x MnO 3 -Yttria Stabilized Zirconia Electrodes for Thin-FilmMnO 3 -yttria stabilized zirconia) were deposited onto dense1.5 h in acetone, using zirconia milling media. The LSM- YSZ

  7. Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3d transition metal aluminides

    E-Print Network [OSTI]

    Morse, Michael D.

    Spectroscopy of jet-cooled AlMn and trends in the electronic structure of the 3d transition metal, Utah 84112 (Received 9 May 1994; accepted 28 June 1994) Jet-cooled diatomic AlMn has been

  8. MnPASS System Study Phase 2 Prepared for the Minnesota Department of Transportation by Cambridge Systematics, Inc. with SRF

    E-Print Network [OSTI]

    Minnesota, University of

    will be put in place during construction The Next Opportunity See Cayuga Project materials at: http://www.dot.state.mn.us/metro/projects/cayuga/indexPASS onto the Twin City Highway System · Identified a potential MnPASS system ­ Studied cost, operational provide increased trip reliability and user choice in a cost-effective manner (I-394) ­ New lower cost

  9. Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries Hyun diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that Li, lithium ion battery, LiMn2O4 nanowires, high power density, Jahn-Teller distortion T he high energy

  10. Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,

    E-Print Network [OSTI]

    Cui, Yi

    Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery-cost, and environ- mentally friendly anode for lithium ion batteries. Our growth-on- graphene approach should offer

  11. Iron-based soft magnetic composites with MnZn ferrite nanoparticles coating obtained by solgel method

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Iron-based soft magnetic composites with Mn­Zn ferrite nanoparticles coating obtained by sol nanoparticles to coat iron powder. The nanocrystalline iron powders, with an average particle diameter of 20 nm­Zn ferrites. Mn­Zn ferrite uniformly coated the surface of the powder particles, resulting in a reduced

  12. Synthesis of MnO{sub 2}-graphene composites with enhanced supercapacitive performance via pulse electrodeposition under supergravity field

    SciTech Connect (OSTI)

    Liu, Tingting; Shao, Guangjie; Ji, Mingtong; Wang, Guiling

    2014-07-01

    A method of pulse electrodeposition under supergravity field was proposed to synthesize MnO{sub 2}-graphene composites. Supergravity is very efficient for promoting mass transfer and decreasing concentration polarization during the electrodeposition process. The synthesis was conducted on our homemade supergravity equipment. The strength of supergravity field depended on the rotating speed of the ring electrode. 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired when the rotating speed was 3000 rpm. Graphene nanosheets play as a role of conductive substrates for MnO{sub 2} growing. The composites are evaluated as electrode materials for supercapacitors. Electrochemical results show that the maximum specific capacitance of the MnO{sub 2}-graphene composite is 595.7 F g{sup ?1} at a current density of 0.5 A g{sup ?1}. In addition, the composite exhibits excellent cycle stability with no capacitance attenuation after 1000 cycles. The approach provides new ideas for developing supercapacitor electrode materials with high performance. - Graphical abstract: 3D flower like MnO{sub 2} spheres composed of nanoflakes were acquired at 3000 rpm. - Highlights: • MnO{sub 2}-graphene composites were prepared by pulse electrodeposition under supergravity. • 3D flower like MnO{sub 2} spheres are anchored on the graphene nanosheets. • The MnO{sub 2}-graphene electrode exhibits a specific capacitance of 595.7 F g{sup ?1}.

  13. Dynamic characterization and damage detection in the I-40 bridge over the Rio Grande

    SciTech Connect (OSTI)

    Farrar, C.R.; Baker, W.E.; Bell, T.M.; Cone, K.M.; Darling, T.W.; Duffey, T.A.; Eklund, A.; Migliori, A.

    1994-06-01

    In the 1960`s and 1970`s over 2500 bridges were built in the U.S. with a design similar to those on Interstate 40 over the Rio Grande in Albuquerque, New Mexico. These bridges were built without structural redundancy and typically have only two plate girders carrying the entire dead and live loads. Failure of either girder is assumed to produce catastrophic failure of the bridge, hence these bridges are referred to as fracture-critical bridges. The Federal Highway Administration (FHWA) and the National Science Foundation (NSF) have provided funds to New Mexico State University (NMSU) through the New Mexico State Highway and Transportation Department (NMSH&TD) and The Alliance For Transportation Research (ATR) for evaluation and testing of the existing fracture critical bridges over the Rio Grande. Because the 1-40 bridges over the Rio Grande were to be razed during the summer of 1993, the investigators were able to introduce simulated fatigue cracks, similar to those observed in the field, into the structure in order to test various damage identification methods and to observe the changes in load paths through the structure caused by the cracking. To support this research effort, NMSU contracted Los Alamos National Laboratory (LANL) to perform experimental modal analyses, and to develop experimentally verified numerical models of the bridge. Scientists from the LANL`s Condensed Matter and Thermal Physics Group (P-10) applied state-of-the-art sensors and data acquisition software to the modal tests. Engineers from the LANL`s Advanced Engineering Technology Group (MEE-13) conducted ambient and forced vibration tests to verify detailed and simplified finite element models of the bridge. Forced vibration testing was done in conjunction with engineers from Sandia National Laboratory (SNL) who provided and operated a hydraulic shaker.

  14. Grande Ronde Subbasin Gauging Station Operations, 2007-2008 Reporting Period.

    SciTech Connect (OSTI)

    Menton, R. Coby [Grande Ronde Model Watershed

    2008-11-10

    The Grande Ronde Basin (GRB) in Northeast Oregon is a moderately dry climate receiving between 10 and 20 inches of precipitation per year with surrounding mountains accumulating up to 100 inches. Irrigated agriculture is a major part of the economy with water being diverted or pumped from surface and ground sources from April through October. Several ESA listed species exist in the basin including Chinook, steelhead, and bulltrout. Agriculture and ESA (Endangered Species Act) listed aquatic species combined with a dry climate demonstrate the need for a network of stream gauges. The GRB covers over 5,000 square miles and includes several thousand miles of perennial flowing streams. This project is in place to operate 12 existing stream gauges in combination with USGS (4 gauges) and OWRD (one gauge) who, independent of this project, operate five additional gauges (Grande Ronde at Troy, Imnaha R. at Imnaha, Minam R. at Minam, Lookingglass Creek, and Upper Catherine Cr.) to characterizes flow in both the Grande Ronde and Imnaha subbasins. These gauges are intended to assist in irrigation water management, fisheries management, long term flow and trend analysis, TMDL and SB1010 water quality management plan effectiveness, subbasin plan implementation, and provide essential information regarding cumulative effects response to conservation in the GRB. Headwater characteristics, land management influence, and basin outlet data are all selectively collected in this network of 17 flow gauges. Prior to the 2007 water year there were three separate stream gauging programs with similar objectives, protocol, and funding sources in the GRB. Each of these programs for the past ten years has operated under separate administration consuming more time and administrative money than is necessary to accomplish stated objectives. By combining all programs into one project costs have been reduced, each funding source has one contract instead of three, and the same amount of work has been done accomplishing the same objectives. This objective has been continued and realized in the 2008 water year.

  15. MnO spin-wave dispersion curves from neutron powder diffraction

    SciTech Connect (OSTI)

    Goodwin, Andrew L.; Dove, Martin T.; Tucker, Matthew G.; Keen, David A.

    2007-02-15

    We describe a model-independent approach for the extraction of spin-wave dispersion curves from powder neutron total scattering data. Our approach is based on a statistical analysis of real-space spin configurations to calculate spin-dynamical quantities. The RMCPROFILE implementation of the reverse Monte Carlo refinement process is used to generate a large ensemble of supercell spin configurations from MnO powder diffraction data collected at 100 K. Our analysis of these configurations gives spin-wave dispersion curves for MnO that agree well with those determined independently using neutron triple-axis spectroscopic techniques.

  16. Perpendicularly magnetized {tau}-MnAl (001) thin films epitaxied on GaAs

    SciTech Connect (OSTI)

    Nie, S. H.; Zhu, L. J.; Lu, J.; Pan, D.; Wang, H. L.; Yu, X. Z.; Xiao, J. X.; Zhao, J. H.

    2013-04-15

    Perpendicularly magnetized {tau}-MnAl films have been epitaxied on GaAs (001) by molecular-beam epitaxy. Crystalline quality and magnetic properties of the samples were strongly dependent on growth temperature. The highest coercivity of 10.7 kOe, saturation magnetization of 361.4 emu/cm{sup 3}, perpendicular magnetic anisotropy constant of 13.65 Merg/cm{sup 3}, and magnetic energy product of 4.44 MGOe were achieved. These tunable magnetic properties make MnAl films valuable as excellent and cost-effective alternative for not only high density perpendicular magnetic recording storage and spintronics devices but also permanent magnets.

  17. Graphene in proximity to magnetic insulating LaMnO{sub 3}

    SciTech Connect (OSTI)

    Cheng, Guanghui; Wei, Laiming, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn; Cheng, Long; Liang, Haixing; Zhang, Xiaoqiang; Li, Hui [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Yu, Guolin [Shanghai Institute of Technical Physics, Chinese Academy of Science, Shanghai 200083 (China); Zeng, Changgan, E-mail: laiming@ustc.edu.cn, E-mail: cgzeng@ustc.edu.cn [Hefei National Laboratory for Physical Sciences at the Microscale (HFNL) and Department of Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); International Center for Quantum Design of Functional Materials (ICQD), HFNL, University of Science and Technology of China, Hefei, Anhui 230026 (China); Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China)

    2014-09-29

    Proximity to functional substrates may enhance the coupling between the quantum degrees of freedom and thus develop nontrivial quantum effects in graphene. Here, we demonstrate the successful fabrication of graphene in proximity to atomically flat magnetic insulating LaMnO{sub 3} films. The insulating nature of the LaMnO{sub 3} films not only ensures the electronic transport only occur in the graphene layers but also allow them to serve as dielectric layers for gating. Transport measurements reveal anomalous behaviors, including asymmetrical longitudinal magnetoresistivity and nonlinear Hall effect. This work may pave a way toward the realization of intriguing quantum phases in graphene.

  18. Relaxation of photoinduced spins and carriers in ferromagnetic InMnSb films

    SciTech Connect (OSTI)

    Nontapot, K.; Kini, R. N.; Gifford, A.; Merritt, T. R.; Khodaparast, G. A.; Wojtowicz, T.; Liu, X.; Furdyna, J. K. [Department of Physics, Virginia Tech, Blacksburg, Virginia 24061 (United States); Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw (Poland); Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

    2007-04-02

    The authors report time resolved measurements and control of photoinduced spin and carrier relaxations in InMnSb ferromagnetic films with 2% Mn content (grown by low-temperature molecular beam epitaxy) using femtosecond laser pulses, and compare them to analogous measurements on InBeSb and InSb films. In this work, magneto-optical Kerr effect and standard pump-probe techniques provided a direct measure of the photoexcited spin and carrier lifetimes, respectively. They observe decrease in relaxations times in the high laser fluence regime and an absence of temperature dependence of the relaxation times.

  19. Ferromagnetism in Mn Substituted Zirconia: A Density-functional Theory Study

    E-Print Network [OSTI]

    Xingtao Jia; Wei Yang; Minghui Qin; Xinglai Zhang; Mingai Sun; Jianping Li

    2008-09-05

    We study the electronic structure and magnetism of 25% Mn substituted cubic Zirconia (ZrO2) with several homogeneous and heterogeneous doping profiles using density-functional theory calculations. We find that all doping profiles show half-metallic ferromagnetism (HMF), and delta-doping is most energy favorable while homogeneous doping has largest ferromagnetic stabilization energy. Using crystal field theory, we discuss the formation scheme of HMF. Finally, we speculate the potential spintronics applications for Mn doped ZrO2, especially as spin direction controllment.

  20. Communication: Reduced density matrices in molecular systems: Grand-canonical electron states

    SciTech Connect (OSTI)

    Bochicchio, Roberto C.; Miranda-Quintana, Ramón A.; Rial, Diego

    2013-11-21

    Grand-canonical like descriptions of many electron atomic and molecular open systems which are characterized by a non-integer number of electrons are presented. Their associated reduced density matrices (RDMs) are obtained by introducing the contracting mapping for this type of distributions. It is shown that there is loss of information when connecting RDMs of different order by partial contractions. The energy convexity property of these systems simplifies the description. Consequently, this formulation opens the possibility to a new look for chemical descriptors such as chemical potential and reactivity among others. Examples are presented to discuss the theoretical aspects of this work.

  1. Flow, Salts, and Trace Elements in the Rio Grande: A Review 

    E-Print Network [OSTI]

    Miyamoto, S.; Fenn, L. B.; Swietlik, D.

    1995-01-01

    injection, unless ocean or inland lake disposals are feasible. Future research should include the development of cost-effective and ecologically sound saline wa- ter disposal options, including such options as saline solar ponds and salt mining. Another... stream_source_info tr169.pdf.txt stream_content_type text/plain stream_size 135875 Content-Encoding UTF-8 stream_name tr169.pdf.txt Content-Type text/plain; charset=UTF-8 FLOW, SALTS, AND TRACE ELEMENTS IN THE RIO GRANDE...

  2. SO(10) Grand Unification in M theory on a G2 manifold

    E-Print Network [OSTI]

    Bobby S. Acharya; Krzysztof Bozek; Miguel Crispim Romao; Stephen F. King; Chakrit Pongkitivanichkul

    2015-02-05

    We consider Grand Unified Theories based on $SO(10)$ which originate from string/$M$ theory on $G_2$ manifolds or Calabi-Yau spaces with discrete symmetries. In this framework we are naturally led to a novel solution of the doublet-triplet splitting problem previously considered by Dvali which involves an extra vector-like Standard Model family and light, but weakly coupled colour triplets. These additional states are predicted to be accessible at the LHC and also induce R-parity violation. Gauge coupling unification occurs with a larger GUT coupling.

  3. SO(10) Grand Unification in M theory on a G2 manifold

    E-Print Network [OSTI]

    Acharya, Bobby S; Romao, Miguel Crispim; King, Stephen F; Pongkitivanichkul, Chakrit

    2015-01-01

    We consider Grand Unified Theories based on $SO(10)$ which originate from string/$M$ theory on $G_2$ manifolds or Calabi-Yau spaces with discrete symmetries. In this framework we are naturally led to a novel solution of the doublet-triplet splitting problem previously considered by Dvali which involves an extra vector-like Standard Model family and light, but weakly coupled colour triplets. These additional states are predicted to be accessible at the LHC and also induce R-parity violation. Gauge coupling unification occurs with a larger GUT coupling.

  4. Supersymmetric Grand Unified Theories and Global Fits to Low Energy Data

    E-Print Network [OSTI]

    T. Blazek; S. Raby

    1996-11-13

    We present a self-consistent $\\chi^2$ analysis of several supersymmetric (SUSY) grand unified theories recently discussed in the literature. We obtain global fits to low energy data, including gauge couplings, fermion masses and mixing angles, gauge boson masses and $BR(b\\rightarrow s\\gamma)$. One of the models studied provides an excellent fit to the low energy data with $\\chi^2\\sim 1$ for 3 degrees of freedom, in a large region of the experimentally allowed SUSY parameter space. We also discuss the consequences of our work for a general MSSM analysis at the $Z$ scale.

  5. California Red Scale and its Control in the Lower Rio Grande Valley of Texas. 

    E-Print Network [OSTI]

    Clark, S. W. (Sherman Wood); Friend, W. H. (William Heartsill)

    1932-01-01

    appli contl agail insec Th of tl pend; insect The California Red Scale is capable of doing such serious damage to citrus trees in the Lower Rio Grande Valley that its control, is one of the major problems of citrus fruit production... in this region. Environmental conditions are apparently so favorable for the de- velopment and multiplication of this insect that it is probably more active in the Valley than in any of the other citrus-producing areas of the United States. Infested host...

  6. Language assessment instruments: a study of language dominance tests in the Rio Grande Valley 

    E-Print Network [OSTI]

    Hickey, Concepcion Maria

    1976-01-01

    of their children's language use i s a useful and valid cri teri on s i nce they have the opportuni ty of regularly observing thei r children's language behavior in the home-family domain and in various role-relationships. Definition of Terms l. language... in the Rio Grande Valley; 3) to determine the degree and the nature of' correlation between parent, al language census data concerning language dominance of their children in the home-family domain as measured by the Home Bilingual Usage Estimate and test...

  7. Enlarged Mn 3s splitting and room-temperature ferromagnetism in epitaxially grown oxygen doped Mn{sub 2}N{sub 0.86} films

    SciTech Connect (OSTI)

    Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

    2014-11-07

    Single-phase and oxygen doped Mn{sub 2}N{sub 0.86} thin films have been grown on MgO (111) by plasma-assisted molecular beam epitaxy. The films grow under tensile strain and, remarkably, they show ferromagnetic-like interactions at low temperature and ferromagnetic ordering agreed well with the Bloch-law T{sup 3/2} at room-temperature. We further demonstrate the enlarged Mn 3s splitting (6.46?eV) and its possible relation to the observed ferromagnetism. Our study not only provide a strategy for further theoretical work on oxygen doped manganese nitrides, but also shed promising light on utilizing its room-temperature FM property to fabricate spintronic devices.

  8. Microstructures and Mechanical Properties of Compositionally Complex Co-free FeNiMnCr18 FCC Solid Solution Alloy

    SciTech Connect (OSTI)

    Wu, Zhenggang [The University of Tennessee; Bei, Hongbin [ORNL

    2015-01-01

    Recently,a structurally-simplebutcompositionally-complex FeNiCoMnCr highentropyalloywasfoundto haveexcellentmechanicalproperties(e.g.,highstrengthandductility).Tounderstandthepotentialof using highentropyalloysasstructuralmaterialsforadvancednuclearreactorandpowerplants,itis necessary tohaveathoroughunderstandingoftheirstructuralstabilityandmechanicalpropertiesde- gradation underneutronirradiation.ThisrequiresustodevelopasimilarmodelalloywithoutCobe- cause materialwithCowillmakepost-neutron-irradiationtestingdifficult duetotheproductionofthe 60Co radioisotope.Toachievethisgoal,aFCC-structuredsingle-phasealloywithacompositionof FeNiMnCr18 wassuccessfullydeveloped.Thisnear-equiatomicFeNiMnCr18 alloy hasgoodmalleability and itsmicrostructurecanbecontrolledbythermomechanicalprocessing.Byrollingandannealing,the as-cast elongated-grained-microstructureisreplacedbyhomogeneousequiaxedgrains.Themechanical properties (e.g.,strengthandductility)oftheFeNiMnCr18 alloy arecomparabletothoseoftheequiatomic FeNiCoMnCr highentropyalloy.Bothstrengthandductilityincreasewithdecreasingdeformation temperature,withthelargestdifferenceoccurringbetween293and77K.Extensivetwin-bandswhich are bundlesofnumerousindividualtwinsareobservedwhenitistensile-fracturedat77K.Notwin bands aredetectedbyEBSDformaterialsdeformedat293Kandhigher.Theunusualtemperature-de- pendencies ofUTSanduniformelongationcouldbecausedbythedevelopmentofthedensetwin substructure, twin-dislocationinteractionsandtheinteractionsbetweenprimaryandsecondarytwin- ning systemswhichresultinamicrostructurerefinement andhencecauseenhancedstrainhardening and postponednecking.

  9. Observation of Precipitation Evolution in Fe-Ni-Mn-Ti-Al Maraging Steel using Atom Probe Tomography

    SciTech Connect (OSTI)

    Pereloma, E. V.; Stohr, R A; Miller, Michael K; Ringer, S. P.

    2009-01-01

    We describe the full decomposition sequence in an Fe-Ni-Mn-Ti-Al maraging steel during isothermal annealing at 550 C. Following significant pre-precipitation clustering reactions within the supersaturated martensitic solid solution, (Ni,Fe){sub 3}Ti and (Ni,Fe){sub 3}(Al,Mn) precipitates eventually form after isothermal aging for {approx}60 seconds. The morphology of the (Ni,Fe){sub 3}Ti particles changes gradually during aging from predominantly plate-like to rod-like, and, importantly, Mn and Al were observed to segregate to these precipitate/matrix interfaces. The (Ni,Fe){sub 3}(Al,Mn) precipitates occurred at two main locations: uniformly within the matrix and at the periphery of the (Ni,Fe){sub 3}Ti particles. We relate this latter mode of precipitation to the Mn-Al segregation.

  10. Growth of single-crystal {alpha}-MnO{sub 2} nanorods on multi-walled carbon nanotubes

    SciTech Connect (OSTI)

    Chen Yong; Liu Chenguang; Liu Chang; Lu Gaoqing; Cheng Huiming

    2007-11-06

    Single-crystal {alpha}-MnO{sub 2} nanorods were grown on multi-walled carbon nanotubes (MWNTs) in H{sub 2}SO{sub 4} aqueous solution. The morphology and microstructure of the composites were examined by transmission electron microscopy, high-resolution transmission electron microscopy (HRTEM), X-ray diffractometry and energy dispersive spectroscopy (EDS). The results show that {alpha}-MnO{sub 2} single-crystal nanorods with a mean diameter of 15 nm were densely grown on the surface of MWNTs. Those MWNTs/MnO{sub 2} composites were used as an electrode material for supercapacitors, and it was found that the supercapacitor performance using MWNTs/MnO{sub 2} composites was improved largely compared to that using pure MWNTs and {alpha}-MnO{sub 2} nanorod mechanically mixed with MWNTs.

  11. Bulk and surface half-metallicity: The case of D0{sub 3}-type Mn{sub 3}Ge

    SciTech Connect (OSTI)

    Liu, Hao; Gao, G. Y. Hu, Lei; Ni, Yun; Zu, Fengxia; Zhu, Sicong; Wang, Shuling; Yao, K. L.

    2014-01-21

    Motivated by the experimental realization of D0{sub 22}-type Mn{sub 3}Ge (001) films [Kurt et al. Appl. Phys. Lett. 101, 132410 (2012)] and the structural stability of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge [Zhang et al. J. Phys.: Condens. Matter 25, 206006 (2013)], we use the first-principles calculations based on the full potential linearized augmented plane-wave method to investigate the electronic and magnetic properties of D0{sub 3}-type Heusler alloy Mn{sub 3}Ge and its (001) surface. We show that bulk D0{sub 3}-Mn{sub 3}Ge is a half-metallic ferromagnet with the minority-spin energy gap of 0.52?eV and the magnetic moment of 1.00??{sub B} per formula unit. The bulk half-metallicity is preserved at the pure Mn-terminated (001) surface due to the large exchange split, but the MnGe-terminated (001) surface destroys the bulk half-metallicity. We also reveal that the surface stabilities are comparable between the D0{sub 3}-Mn{sub 3}Ge (001) and the experimental D0{sub 22}-Mn{sub 3}Ge (001), which indicates the feasibility to grow the Mn{sub 3}Ge (001) films with D0{sub 3} phase other than D0{sub 22} one. The surface half-metallicity and stability make D0{sub 3}-Mn{sub 3}Ge a promising candidate for spintronic applications.

  12. Comparison of the crystalline structure, morphology, and magnetic properties of -phase Mn/Cu3Au,,100... ultrathin films by varying the growth temperature

    E-Print Network [OSTI]

    Lin, Minn-Tsong

    Comparison of the crystalline structure, morphology, and magnetic properties of -phase Mn/Cu3Au behaviors in the crystalline structure, morphology, and magnetism. RT-Mn films reveal apparent layer the last de- cade, the pure - and -phase Mn films are prepared by epitaxial growth on single-crystalline

  13. Heteronuclear Mn-Ca/Sr Complexes, and Ca/Sr EXAFS SpectralComparisons with the Oxygen-Evolving Complex of Photosystem II

    SciTech Connect (OSTI)

    Mishra, A.; Yano, J.; Pushkar, Y.; Yachandra, V.K.; Abboud, K.A.; Christou, G.

    2007-12-19

    HeterometallicMn Ca and Mn Sr complexes have been preparedand employed as model complexes for Ca and Sr EXAFS spectral comparisonswith the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); thesehave revealed similarities that support the presence of at least one Oatom bridge between the Mn and Ca/Sr in the OEC.

  14. Proton stability in grand unified theories, in strings, and in branes

    E-Print Network [OSTI]

    Pran Nath; Pavel Fileviez Perez

    2007-04-23

    A broad overview of the current status of proton stability in unified models of particle interactions is given which includes non - supersymmetric unification, SUSY and SUGRA unified models, unification based on extra dimensions, and string-M-theory models. The extra dimensional unification includes 5D and 6D and universal extra dimensional (UED) models, and models based on warped geometry. Proton stability in a wide array of string theory and M theory models is reviewed. These include Calabi-Yau models, grand unified models with Kac-Moody levels $k>1$, a new class of heterotic string models, models based on intersecting D branes, and string landscape models. The destabilizing effect of quantum gravity on the proton is discussed. The possibility of testing grand unified models, models based on extra dimensions and string-M-theory models via their distinctive modes is investigated. The proposed next generation proton decay experiments, HyperK, UNO, MEMPHYS, ICARUS, LANNDD (DUSEL), and LENA would shed significant light on the nature of unification complementary to the physics at the LHC. Mathematical tools for the computation of proton lifetime are given in the appendices. Prospects for the future are discussed.

  15. A Coupled Modeling System to Simulate Water Resources in the Rio Grande Basin

    SciTech Connect (OSTI)

    Bossert, J.E.; Breshears, D.D.; Campbell, K.; Costigan, K.R.; Greene, R.K.; Keating, E.H.; Kleifgen, L.M.; Langley, D.L.; Martens, S.N.; Sanderson, J.G.; Springer, E.P.; Stalker, J.R.; Tartakovsky, D.M.; Winter, C.L.; Zyvoloski, G.A.

    1999-01-11

    Limited availability of fresh water in arid and semi-arid regions of the world requires prudent management strategies from accurate, science-based assessments. These assessments demand a thorough understanding of the hydrologic cycle over long time periods within the individual water-sheds that comprise large river basins. Measurement and simulation of the hydrologic cycle is a tremendous challenge, involving a coupling between global to regional-scale atmospheric precipitation processes with regional to local-scale land surface and subsurface water transport. Los Alamos National Laboratory is developing a detailed modeling system of the hydrologic cycle and applying this tool at high resolution to assess the water balance within the upper Rio Grande river basin. The Rio Grande is a prime example of a river system in a semiarid environment, with a high demand from agricultural, industrial, recreational, and municipal interests for its water supply. Within this river basin, groundwater supplies often augment surface water. With increasing growth projected throughout the river basin, however, these multiple water users have the potential to significantly deplete groundwater resources, thereby increasing the dependence on surface water resources.

  16. Electrodeposition of Mn-Co Alloys on Stainless Steels for SOFC Interconnect Application

    SciTech Connect (OSTI)

    Wu, J. (West Virginia University); Jiang, Y. (West Virginia University); Johnson, C.; Gong, M. (West Virginia University); Liu, X. (West Virginia University)

    2007-09-01

    Chromium-containing ferritic stainless steels are the most popular materials for solid oxide fuel cell (SOFC) interconnect applications because of its oxidation resistance and easy fabrication process. However, excessive scale growth and chromium evaporation will degrade the cell performance. Highly conductive coatings that resist oxide scale growth and chromium evaporation may prevent both of these problems. Mn1.5Co1.5O4 spinel is one of the most promising coatings for interconnect application because of its high conducitivy, good chromium retention capability, as well as good CTE match. Electroplating of alloys or thin film multilayers followed by controlled oxidation to the desired spinel phase offers an additional deposition option. In the present study binary Mn/Co alloys was fabricated by electrodeposition, and polarization curves were used to characterize the cathodic reactions on substrate surface. By controlling the current density precisely, coatings with Mn/Co around 1:1 has been successfully deposited in Mn/Co =10 solutions, SEM and EDX was used to characterize the surface morphology and composition.

  17. LABORATORY EXPERIMENT 11 Determination of microelements (Mn and Cu) in tea leaves

    E-Print Network [OSTI]

    Nazarenko, Alexander

    : · Total contents - Mn and Cu in tea leaves by ashing and acid digestion · Extractable contents: hot water to determine the total contents of a component, such as a metal element, being measured. On the other hand used will depend on the purpose of the study. For example, it may be that the total content of a metal

  18. Structural characterization of terrestrial microbial Mn oxides from Pinal Creek, AZ

    E-Print Network [OSTI]

    and oxidatively degrade or trans- form numerous organic and inorganic compounds, includ- ing humic and fulvic acids, aromatic hydrocarbons, Cr(III), Co(II), and hydrogen sulfide (Jenne, 1967; Huang, 1991(II)-oxidizing microorganisms in the envi- ronment (Tebo et al., 2004) and upon the much faster rates of Mn(II) oxidation

  19. Correlated chemostratigraphy of Mn-carbonate microbialites (rkt, Hungary) Mrta Polgri a,b,

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    ) microbialites at the Úrkút black shale-hosted manganese carbonate ore body (central Hungary) is described microbialites mostly behaved as an open system during deposition of black shale under early diagenetic reduction under an oxic water column; more equant types occur at the contact zone of black shale and Mn

  20. In Vitro Study on MgeSneMn Alloy as Biodegradable Metals Zhen Zhen1)

    E-Print Network [OSTI]

    Zheng, Yufeng

    for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China 2) Biomedical Engineering condition) in Hank's solution. Blood compatibility evaluation suggested that Mge3Sne0.5Mn alloy had improve the corrosion resistance, for its high hydrogen overvoltage[22] . In physiology, Sn is a trace

  1. Optical properties of metallic (III, Mn)V ferromagnetic semiconductors in the infrared to visible range 

    E-Print Network [OSTI]

    Hankiewicz, EM; Jungwirth, T.; Dietl, T.; Timm, C.; Sinova, Jairo.

    2004-01-01

    We report on a study of the ac conductivity and magneto-optical properties of metallic ferromagnetic (III, Mn)V semiconductors in the infrared to visible spectrum at zero temperature. Our analysis is based on the successful kinetic exchange model...

  2. Effect of carbon doping on electronic transitions in Mn5Ge3 N. Stojilovic,1,a)

    E-Print Network [OSTI]

    Dordevic, Sasha V.

    these compounds promising candidates for spin injectors for potential spintronics applications. The resistivity mismatch between a metal and a semicon- ductor. Therefore, for spintronics applications, finding a compound is now being considered for use in spintronics applications.4 However, pure Mn5Ge3 has Tc ¼ 293 K,5 which

  3. MN 535 Green Manufacturing Fall'04: M-W noon-2PM

    E-Print Network [OSTI]

    Lin, Xi

    of the Manufacturing Process that aims to efficiently use energy, water and raw materials in order to minimize airMN 535 Green Manufacturing Fall'04: M-W noon-2PM Course Objective Provides a systems view and water pollution and generation of solid waste per unit of the manufactured product Class Discussion

  4. Modified magnetic ground state in NiMn2O4 thin films

    SciTech Connect (OSTI)

    Nelson-Cheeseman, B. B.; Chopdekar, R. V.; Toney, M. F.; Arenholz, E.; Suzuki, Y.; Iwata, J.M.

    2010-08-03

    We demonstrate the stabilization of a magnetic ground state in epitaxial NiMn2O4 (NMO) thin films not observed in their bulk counterpart. Bulk NMO exhibits a magnetic transition from a paramagnetic phase to a collinear ferrimagnetic moment configuration below 110 K and to a canted moment configuration below 70 K. By contrast, as-grown NMO films exhibit a single magnetic transition at 60 K and annealed films exhibit the magnetic behavior found in bulk. Cation inversion and epitaxial strain are ruled out as possible causes for the new magnetic ground state in the as-grown films. However, a decrease in the octahedral Mn{sup 4+}:Mn{sup 3+} concentration is observed and likely disrupts the double exchange that produces the magnetic state at intermediate temperatures. X-ray magnetic circular dichroism and bulk magnetometry indicate a canted ferrimagnetic state in all samples at low temperature. Together these results suggest that the collinear ferrimagnetic state observed in bulk NMO at intermediate temperatures is suppressed in the as grown NMO thin films due to a decrease in octahedral Mn{sup 4+} while the canted moment ferrimagnetic ordering is preserved below 60 K.

  5. FARGO-MOORHEAD METROPOLITAN AREA, ND AND MN FLOOD RISK MANAGEMENT PROJECT

    E-Print Network [OSTI]

    US Army Corps of Engineers

    FARGO-MOORHEAD METROPOLITAN AREA, ND AND MN FLOOD RISK MANAGEMENT PROJECT 23 September 2011, and technically feasible flood risk management for Fargo, North Dakota, Moorhead, Minnesota, and the surrounding area, and a storage area to reduce the existing and future flood risk and damages to public and private

  6. Tracing bottom water oxygenation with sedimentary Mn/Fe ratios in Lake Zurich, Switzerland

    E-Print Network [OSTI]

    Gilli, Adrian

    Tracing bottom water oxygenation with sedimentary Mn/Fe ratios in Lake Zurich, Switzerland and Management, Seestrasse 79, CH-6047 Kastanienbaum, Switzerland b ETH Zurich, Institute for Biogeochemistry and Pollution Dynamics, Universitaetstrasse 16, CH-8092 Zurich, Switzerland c ETH Zurich, Geological Institute

  7. P0805-Hagen Oxidation States of Mn, Cr, and Co in

    E-Print Network [OSTI]

    on metal based interconnects in solid oxide fuel cell (SOFC) stack technology. The nature of the cations of the material, e.g., conductivity, which is of crucial importance in the fuel cell technology. In the present-Mn-Co-O are of great interest as layers of these materials are formed during operation at the metallic interconnects

  8. Spins and magnetic moments of 58;60;62;64Mn ground states and isomers

    E-Print Network [OSTI]

    H. Heylen; C. Babcock; J. Billowes; M. L. Bissell; K. Blaum; P. Campbell; B. Cheal; R. F. Garcia Ruiz; Ch. Geppert; W. Gins; M. Kowalska; K. Kreim; S. M. Lenzi; I. D. Moore; R. Neugart; G. Neyens; W. Nörtershäuser; J. Papuga; D. T. Yordanov

    2015-08-25

    The odd-odd 54;56;58;60;62;64Mn isotopes (Z = 25) were studied using bunched-beam collinear laser spectroscopy at ISOLDE, CERN. From the measured hyperfine spectra the spins and magnetic moments of Mn isotopes up to N = 39 were extracted. The previous tentative ground state spin assignments of 58;60;62;64Mn are now firmly determined to be I = 1 along with an I = 4 assignment for the isomeric states in 58;60;62Mn. The I = 1 magnetic moments show a decreasing trend with increasing neutron number while the I = 4 moments remain quite constant between N = 33 and N = 37. The results are compared to large-scale shell-model calculations using the GXPF1A and LNPS effective interactions. The excellent agreement of the ground state moments with the predictions from the LNPS calculations illustrates the need for an increasing amount of proton excitations across Z = 28 and neutron excitations across N = 40 in the ground state wave functions from N = 37 onwards.

  9. Spins and magnetic moments of 58;60;62;64Mn ground states and isomers

    E-Print Network [OSTI]

    Heylen, H; Billowes, J; Bissell, M L; Blaum, K; Campbell, P; Cheal, B; Ruiz, R F Garcia; Geppert, Ch; Gins, W; Kowalska, M; Kreim, K; Lenzi, S M; Moore, I D; Neugart, R; Neyens, G; Nörtershäuser, W; Papuga, J; Yordanov, D T

    2015-01-01

    The odd-odd 54;56;58;60;62;64Mn isotopes (Z = 25) were studied using bunched-beam collinear laser spectroscopy at ISOLDE, CERN. From the measured hyperfine spectra the spins and magnetic moments of Mn isotopes up to N = 39 were extracted. The previous tentative ground state spin assignments of 58;60;62;64Mn are now firmly determined to be I = 1 along with an I = 4 assignment for the isomeric states in 58;60;62Mn. The I = 1 magnetic moments show a decreasing trend with increasing neutron number while the I = 4 moments remain quite constant between N = 33 and N = 37. The results are compared to large-scale shell-model calculations using the GXPF1A and LNPS effective interactions. The excellent agreement of the ground state moments with the predictions from the LNPS calculations illustrates the need for an increasing amount of proton excitations across Z = 28 and neutron excitations across N = 40 in the ground state wave functions from N = 37 onwards.

  10. Tunable White-Light-Emitting Mn-Doped ZnSe Nanocrystals Vijay Kumar Sharma,

    E-Print Network [OSTI]

    Demir, Hilmi Volkan

    Se-related blue emission (410 and 435 nm), Zn-related defect state green emission (520 nm), and Mn-dopant related for the purpose of generation of photometrically high quality white light while maintaining the energy efficiency is to combine red-, green-, and blue-emitting NCs in an appropriate ratio.1,2 However, when one simply mixes

  11. Materials Research for Environment and Energy Hydrogen Embrittlement in Fe-Mn-C

    E-Print Network [OSTI]

    Cambridge, University of

    Materials Research for Environment and Energy - 1 - Hydrogen Embrittlement in Fe-Mn-C High Strength Seminar, May 23 #12;Materials Research for Environment and Energy - 2 - I had moved from NIMS to Kyushu.kaneaki@nims.go.jp> ********************* #12;Materials Research for Environment and Energy - 3 - #12;Materials Research for Environment

  12. Shannon D. Scott, RN, BN, MN, PhD Faculty of Nursing, University of Alberta

    E-Print Network [OSTI]

    Machel, Hans

    Shannon D. Scott, RN, BN, MN, PhD Faculty of Nursing, University of Alberta Level 3, 11405 Promotion Studies (Mentor Dr. Ron Plotnikoff), University of Alberta. Funded by: Canadian Institutes of Health Research Fellowship, Alberta Heritage Foundation for Medical Research Fellowship, and the Canadian

  13. CaMn2Sb2: Spin waves on a frustrated antiferromagnetic honeycomb lattice

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McNally, D. E.; Simonson, J. W.; Kistner-Morris, J. J.; Smith, G. J.; Hassinger, J. E.; DeBeer-Schmidt, L.; Kolesnikov, A. I.; Zaliznyak, I.; Aronson, M. C.

    2015-05-22

    We present inelastic neutron scattering measurements of the antiferromagnetic insulator CaMn2Sb2:, which consists of corrugated honeycomb layers of Mn. The dispersion of magnetic excitations has been measured along the H and L directions in reciprocal space, with a maximum excitation energy of ? 24 meV. These excitations are well described by spin waves in a Heisenberg model, including first and second neighbor exchange interactions, J1 and J2, in the Mn plane and also an exchange interaction between planes. The determined ratio J2/J1 ? 1/6 suggests that CaMn2Sb2: is the first example of a compound that lies very close to themore »mean field tricritical point, known for the classical Heisenberg model on the honeycomb lattice, where the N´eel phase and two different spiral phases coexist. The magnitude of the determined exchange interactions reveal a mean field ordering temperature ? 4 times larger than the reported N´eel temperature TN = 85 K, suggesting significant frustration arising from proximity to the tricritical point.« less

  14. MN-583 Product Management Fall 2004 SYLLABUS Instructor: William Hauser wmhauser@bu.edu

    E-Print Network [OSTI]

    Lin, Xi

    MN-583 Product Management Fall 2004 SYLLABUS Instructor: William Hauser wmhauser@bu.edu Office: Room 219, 730 Commonwealth Avenue Classroom: 15 St. Mary's Street, Room 105 617-358-0663 http Nature of the Product Management Task Case: The Hewlett Packard Company, The Sally Project 3 Wed, 15-Sep

  15. Solar DEM Model Proposal : A solar image in color band b, mn pixels,

    E-Print Network [OSTI]

    Wolfe, Patrick J.

    Solar DEM Model Proposal : A solar image in color band b, m×n pixels, containing a particular solar 11 )( #12;Solar DEM Model Proposal : the volume (abundance?) of ion ii : the proportion of the total volume at temperature t t T t bitt I i ib MIE 11 )( #12;Solar Dataset · 15 Filters.txt files

  16. Mn-Substituted Inorganic-Organic Hybrid Materials Based on ZnSe

    E-Print Network [OSTI]

    Li, Jing

    Mn-Substituted Inorganic-Organic Hybrid Materials Based on ZnSe: Nanostructures That May Lead research that deals with synthesis, characterization, and modification of organic-inorganic hybrid to integrate functional materials that utilize both electron charge and spin.1 Thus, the introduction

  17. Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications

    SciTech Connect (OSTI)

    Kam, Kinson; Doeff, Marca M.

    2010-12-01

    Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

  18. mn header will be provided by the publisher Linear Passive Stationary Scattering Systems

    E-Print Network [OSTI]

    Rovnyak, James

    mn header will be provided by the publisher Linear Passive Stationary Scattering Systems 26, Odessa 65020, Ukraine 2 Department of Mathematics, University of Virginia, P. O. Box 400137@farlep.net Corresponding author: e-mail: rovnyak@Virginia.edu e-mail: sergey saprikin@ukr.net Copyright line

  19. NEW COURSE NUMBER: ENG ME 579 Extra information on MN/SC579: Microelectronic Device Manufacturing

    E-Print Network [OSTI]

    Lin, Xi

    NEW COURSE NUMBER: ENG ME 579 Extra information on MN/SC579: Microelectronic Device Manufacturing for manufacturing engineering students to take for the following reason. Your future careers in manufacturing are undoubtedly most promising for the manufacturing of what is often referred to as "high technology" areas

  20. Microscopic mechanism of the noncrystalline anisotropic magnetoresistance in (Ga,Mn)As 

    E-Print Network [OSTI]

    Vyborny, Karel; Kucera, Jan; Sinova, Jairo; Rushforth, A. W.; Gallagher, B. L.; Jungwirth, T.

    2009-01-01

    Starting with a microscopic model based on the Kohn-Luttinger Hamiltonian and kinetic p-d exchange combined with Boltzmann formula for conductivity we identify the scattering from magnetic Mn combined with the strong spin-orbit interaction of the GaAs...

  1. NEW COURSE NUMBER: ENG ME 560 MN 560 Precision Machine Design and Instrumentation

    E-Print Network [OSTI]

    Lin, Xi

    : Physics, Designs, and Applications; Jacob Fraden, Springer-Verlag Machinery's Handbook, Industrial PressNEW COURSE NUMBER: ENG ME 560 MN 560 Precision Machine Design and Instrumentation Fall 2006, M,W, 4:00 ­ 6:00 This inter-disciplinary course teaches the student how to design, instrument, and control high

  2. Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4

    E-Print Network [OSTI]

    Cui, Yi

    nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials energy storage devices for portable electronic devices, power tools, and electrical vehicles.1-4 Anodes applied to battery researches. This work represents the first example of single nanostructure device

  3. Precipitation in the Equiatomic High-Entropy Alloy CrMnFeCoNi

    E-Print Network [OSTI]

    Pickering, E. J.; Muñoz-Moreno, R.; Stone, H. J.; Jones, N. G.

    2015-11-02

    CrMnFeCoNi is widely considered to be an exemplar high-entropy alloy, which is stable as a single solid-solution phase at all temperatures below its melting point. Here, for the first time, the formation of two distinct types of Cr-rich precipitate...

  4. Shapes of Knotted Cyclic Polymers Eric J. Rawdon, University of St. Thomas, Saint Paul, MN, USA

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    Shapes of Knotted Cyclic Polymers Eric J. Rawdon, University of St. Thomas, Saint Paul, MN, USA, USA Momentary configurations of long polymers at thermal equilibrium usually deviate from spherical of asphericity (or prolateness) that describe these momentary ellipsoidal shapes of a polymer are determined

  5. Local structure and polarization resistance of Ce doped SrMnO{sub 3} using extended x-ray fine structure analysis

    SciTech Connect (OSTI)

    Ryu, Jiseung; Lee, Heesoo, E-mail: heesoo@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2014-09-15

    Changes to the local structure of Sr and Mn atoms in Sr{sub 1?x}Ce{sub x}MnO{sub 3} (SCM) according to increasing Ce content and the effect of the structural change on the polarization resistance of SCM were investigated. The reduction of manganese was confirmed by the absorption edge shift of the Mn K-edge toward lower energies. The noise of oscillation in extended X-ray absorption fine structure k{sup 3}? data at Mn K-edge reveals the distortion of the local structure of Mn atoms, and the peak that indicates the bonding length of Mn-O, Sr/Ce, and -Mn decreased with the addition of Ce content in Fourier transformations of the Mn K-edge. The distortion of the local structure at Mn atoms was affected by the reduced manganese ions having larger ionic radii than Mn{sup 4+}. Meanwhile, few distortions of local atomic structures of Sr atoms occurred, and the average nearest neighboring distances of Sr-O and Sr-Mn are ?2.13?Å and ?2.95?Å, respectively. The average bonding lengths of the Ce-O and Ce-Mn increased because the ionic radius of substituted Ce ion with 12 coordination number is smaller than that of Sr ion, which leads the reduction of Mn ions and the distortion of local structure at the substituted A-site. Therefore, we reasoned that the distortion of the local atomic structure at Mn atoms in MnO{sub 6} and Ce atoms in A-site is one of the causes for interrupting oxygen ion transfers as a geometric factor, which results in an increase in the polarization resistance of SCM within the Ce composition range from 10?mol.?% to 30?mol.?%.

  6. 3.6.15. Demostrar que el conjunto de puntos de coordenadas visibles desde el origen contiene cuadrados vacios tan grandes como queramos.

    E-Print Network [OSTI]

    Cilleruelo, Javier

    cuadrados vac´ios tan grandes como queramos. Soluci´on: Este problema es equivalente a encontrar, dado k > 0

  7. Preliminary Analysis of Grande Ronde Basalt Formation Flow Top Transmissivity as it Relates to Assessment and Site Selection Applications for Fluid/Energy Storage and Sequestration Projects

    SciTech Connect (OSTI)

    Spane, Frank A.

    2013-04-29

    Preliminary Analysis of Grande Ronde Basalt Formation Flow Top Transmissivity as it Relates to Assessment and Site Selection Applications for Fluid/Energy Storage and Sequestration Projects

  8. Helical antiferromagnetic ordering in Lu1-xScxMnSi

    SciTech Connect (OSTI)

    Goetsch, Ryan J; Anand, V K; Johnston, David C

    2014-08-01

    Polycrystalline samples of Lu1?xScxMnSi (x=0, 0.25, 0.5) are studied using powder x-ray diffraction, heat capacity Cp, magnetization, magnetic susceptibility ?, and electrical resistivity ? measurements versus temperature T and magnetic field H. This system crystallizes in the primitive orthorhombic TiNiSi-type structure (space group Pnma) as previously reported. The ?(T) data indicate metallic behavior. The Cp(T), ?(T), and ?(T) measurements consistently indicate long-range antiferromagnetic (AF) transitions with AF ordering temperatures TN=246, 215, and 188 K for x=0, 0.25, and 0.5, respectively. A second transition is observed at somewhat lower T for each sample from the ?(T) and ?(T) measurements, which we speculate are due to spin reorientation transitions; these second transitions are completely suppressed in H=5.5 T. The Cp data below 10 K for each composition indicate an enhanced Sommerfeld electronic heat capacity coefficient for the series in the range ?=24–29 mJ/mol K2. The ?(T) measurements up to 1000 K were fitted by local-moment Curie-Weiss behaviors which indicate a low Mn spin S?1. The ? data below TN are analyzed using the Weiss molecular field theory for a planar noncollinear cycloidal AF structure with a composition-dependent pitch, following the previous neutron diffraction work of Venturini et al. [J. Alloys Compd. 256, 65 (1997)]. Within this model, the fits indicate a turn angle between Mn ordered moments along the cycloid axis of ?100? or ?145?, either of which indicate dominant AF interactions between the Mn spins in the Lu1?xScxMnSi series of compounds.

  9. Enhanced magnetic and electrical properties in amorphous Ge:Mn thin films by non-magnetic codoping

    SciTech Connect (OSTI)

    Yin Wenjing; Kell, Copeland D.; Duska, Chris; Lu Jiwei; Floro, Jerrold A. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); He Li; Hull, Robert [Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180 (United States); Dolph, Melissa C. [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Wolf, Stuart A. [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States)

    2012-02-01

    Amorphous Ge{sub 1-x}Mn{sub x} thin films have been prepared by co-depositing Ge and Mn on SiO{sub 2}/Si using an ultrahigh vacuum molecular beam epitaxy system. Across a range of growth temperatures and Mn concentrations (2.8 at. %, 10.9 at. %, and 21.3 at. %), we achieved enhanced magnetic and electrical properties with non-magnetic codopants dispersed in the films. Self-assembled Mn-rich amorphous nanostructures were observed in the amorphous Ge matrix, either as isolated nanoclusters or as nanocolumns, depending on Mn concentration. The ferromagnetic saturation moments were found to increase with Mn concentration and reached a maximum of 0.7 {mu}{sub B}/Mn in the as-grown samples. Two magnetic transition temperatures around 15 K and 200 K were observed in these amorphous MBE-grown samples. Coercivity is considered within the context of local magnetic anisotropy. The anomalous Hall effect confirmed a strong correlation between the magnetization and transport properties, indicating that global ferromagnetic coupling was carrier-mediated rather than through direct exchange. In addition, negative magnetoresistance was detected from 5 K to room temperature.

  10. Scientific Grand Challenges: Crosscutting Technologies for Computing at the Exascale - February 2-4, 2010, Washington, D.C.

    SciTech Connect (OSTI)

    Khaleel, Mohammad A.

    2011-02-06

    The goal of the "Scientific Grand Challenges - Crosscutting Technologies for Computing at the Exascale" workshop in February 2010, jointly sponsored by the U.S. Department of Energy’s Office of Advanced Scientific Computing Research and the National Nuclear Security Administration, was to identify the elements of a research and development agenda that will address these challenges and create a comprehensive exascale computing environment. This exascale computing environment will enable the science applications identified in the eight previously held Scientific Grand Challenges Workshop Series.

  11. EIS-0400: Granby Pumping Plant Switchyard-Windy Gap Substation Transmission Line Rebuild Project, Grand County, CO

    Broader source: Energy.gov [DOE]

    Western Area Power Administration prepared an EIS, with the U.S. Forest Service, Bureau of Land Management, and Grand County (Colorado) as cooperating agencies, to evaluate the potential environmental impacts of rebuilding a 12-mile, 69 kV electric transmission line in Grand County. The proposed project would rebuild the single-circuit line as a double-circuit transmission line and add a second power transformer. Western identified potentially significant impacts while preparing an EA for this proposal (DOE/EA-1520) and prepared an EIS instead of completing the EA. Further information about the project is available on the project website.

  12. Impacts of the Cerro Grande fire on Homestead era and Manhattan Project properties at Los Alamos National Laboratory.

    SciTech Connect (OSTI)

    McGehee, E. D. (Ellen D.); Isaacson, J. (John)

    2001-01-01

    In May of 2000, the Cerro Grande Fire burned approximately 8,000 acres of Department of Energy (DOE) managed land at the Los Alamos National Laboratory (LANL). Although the fire was generally of low intensity, it impacted a significant number of LANL's cultural resources. Historic wooden properties were affected more heavily than prehistoric archaeological sites. This paper will provide an overview of the Homestead and Manhattan Project Periods at LANL and will discuss the effects of the Cerro Grande Fire on historic wooden properties. Post-fire cultural resource management issues will also be discussed.

  13. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer, M. E.; Assaf, B. A.; Sterbinsky, G. E.; Arena, D. A.; Heiman, D.

    2014-12-05

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. Results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value.

  14. Atomic moments in Mn2CoAl thin films analyzed by X-ray magnetic circular dichroism

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jamer, M. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Sterbinsky, G. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Assaf, B. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics; Arena, D. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Photon Sciences Directorate; Heiman, D. [Northwestern Univ., Evanston, IL (United States). Dept. of Physics

    2014-12-07

    Spin gapless semiconductors are known to be strongly affected by structural disorder when grown epitaxially as thin films. The magnetic properties of Mn2CoAl thin films grown on GaAs (001) substrates are investigated here as a function of annealing. This study investigates the atomic-specific magnetic moments of Mn and Co atoms measured through X-ray magnetic circular dichroism as a function of annealing and the consequent structural ordering. The results indicate that the structural distortion mainly affects the Mn atoms as seen by the reduction of the magnetic moment from its predicted value. (auth)

  15. $SO(10)$ Grand Unification from $M$ theory on a $G_2$ manifold

    E-Print Network [OSTI]

    Miguel Crispim Romão

    2015-02-20

    We consider Grand Unified Theories based on $SO(10)$ which originate from $M$ theory on $G_2$ manifolds. In this framework we are naturally led to a novel solution of the doublet-triplet splitting problem involving an extra $\\overline{{\\bf 16}}_X+{\\bf 16}_X$ vector-like pair by considering discrete symmetries of the extra dimensions and preserving unification. Since Wilson line breaking preserves the rank of the gauge group, the necessary $U(1)$ gauge breaking is generated from extra multiplets. The main prediction of the approach is the existence of light states with the quantum numbers of a $\\overline{{\\bf 16}}_X+{\\bf 16}_X$ vector-like pair which could show up in future LHC searches.

  16. $SO(10)$ Grand Unification from $M$ theory on a $G_2$ manifold

    E-Print Network [OSTI]

    Romão, Miguel Crispim

    2015-01-01

    We consider Grand Unified Theories based on $SO(10)$ which originate from $M$ theory on $G_2$ manifolds. In this framework we are naturally led to a novel solution of the doublet-triplet splitting problem involving an extra $\\overline{{\\bf 16}}_X+{\\bf 16}_X$ vector-like pair by considering discrete symmetries of the extra dimensions and preserving unification. Since Wilson line breaking preserves the rank of the gauge group, the necessary $U(1)$ gauge breaking is generated from extra multiplets. The main prediction of the approach is the existence of light states with the quantum numbers of a $\\overline{{\\bf 16}}_X+{\\bf 16}_X$ vector-like pair which could show up in future LHC searches.

  17. Statistics and properties of HII regions in a sample of grand design galaxies I. Luminosity functions

    E-Print Network [OSTI]

    M. Rozas; J. E. Beckman; J. H. Knapen

    1995-09-11

    We present new high quality continuum-subtracted H alpha images of the grand-design galaxies NGC 157, NGC 3631, NGC 6764 and NGC 6951. We have determined the positions, angular sizes, and fluxes of their individual HII regions, and describe statistical properties of the HII region samples. We construct luminosity functions for all the HII regions in the disc and separately for arm and interarm zones for each galaxy. The slopes of the luminosity functions for the complete sample agree well with values published for other spiral galaxies of comparable morphological type. For three galaxies we determined the slopes of the luminosity functions for the spiral arm and interarm zones separately. We find that for NGC 157, NGC 3631, and NGC 6951 these slopes are equal within the errors of determination. We compare our results to those found from earlier work, specifically for M51 and NGC 6814, and discuss implications for massive star forming processes.

  18. EIS-0355: Remediation of the Moab Uranium Mill Tailings, Grand and San Juan Counties, Utah

    Broader source: Energy.gov [DOE]

    The Remediation of the Moab Uranium Mill Tailings, Grand and San Juan Counties, Utah, Environmental Impact Statement and associated supplements and amendments provides information on the environmental impacts of the U.S. Department of Energy’s (DOE’s) proposal to (1) remediate approximately 11.9 million tons of contaminated materials located on the Moab site and approximately 39,700 tons located on nearby vicinity properties and (2) develop and implement a ground water compliance strategy for the Moab site using the framework of the Programmatic Environmental Impact Statement for the Uranium Mill Tailings Remedial Action Ground Water Project (DOE/EIS-0198, October 1996). The surface remediation alternatives analyzed in the EIS include on-site disposal of the contaminated materials and off-site disposal at one of three alternative locations in Utah using one or more transportation options: truck, rail, or slurry pipeline.

  19. Use of a dynamic simulation model to understand nitrogen cycling in the middle Rio Grande, NM.

    SciTech Connect (OSTI)

    Meixner, Tom (University of Arizona, Tucson, AZ); Tidwell, Vincent Carroll; Oelsner, Gretchen (University of Arizona, Tucson, AZ); Brooks, Paul (University of Arizona, Tucson, AZ); Roach, Jesse D.

    2008-08-01

    Water quality often limits the potential uses of scarce water resources in semiarid and arid regions. To best manage water quality one must understand the sources and sinks of both solutes and water to the river system. Nutrient concentration patterns can identify source and sink locations, but cannot always determine biotic processes that affect nutrient concentrations. Modeling tools can provide insight into these large-scale processes. To address questions about large-scale nitrogen removal in the Middle Rio Grande, NM, we created a system dynamics nitrate model using an existing integrated surface water--groundwater model of the region to evaluate our conceptual models of uptake and denitrification as potential nitrate removal mechanisms. We modeled denitrification in groundwater as a first-order process dependent only on concentration and used a 5% denitrification rate. Uptake was assumed to be proportional to transpiration and was modeled as a percentage of the evapotranspiration calculated within the model multiplied by the nitrate concentration in the water being transpired. We modeled riparian uptake as 90% and agricultural uptake as 50% of the respective evapotranspiration rates. Using these removal rates, our model results suggest that riparian uptake, agricultural uptake and denitrification in groundwater are all needed to produce the observed nitrate concentrations in the groundwater, conveyance channels, and river as well as the seasonal concentration patterns. The model results indicate that a total of 497 metric tons of nitrate-N are removed from the Middle Rio Grande annually. Where river nitrate concentrations are low and there are no large nitrate sources, nitrate behaves nearly conservatively and riparian and agricultural uptake are the most important removal mechanisms. Downstream of a large wastewater nitrate source, denitrification and agricultural uptake were responsible for approximately 90% of the nitrogen removal.

  20. Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping

    SciTech Connect (OSTI)

    Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H. E-mail: helene.bea@cea.fr; Baltz, V. E-mail: helene.bea@cea.fr

    2014-01-20

    Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

  1. Proc. of the Fourth World Conference on Engineering Education; St. Paul, MN, October 15-20, 1995 Proceedings of the World Conference on Engineering Education, Minneapolis, MN, October 1995 11

    E-Print Network [OSTI]

    Lamancusa, John S.

    components of this integration. Two different Learning Factory paradigms were developed in order to adapt, Minneapolis, MN, October 1995 22 blending of activities as a necessary means of anchoring both the knowledge

  2. Chlorinated Hydrocarbons and Biomarkers of Exposure in Wading Birds and Fish of the Lower Rio Grande Valley, Texas

    E-Print Network [OSTI]

    Mora, Miguel A.

    Chlorinated Hydrocarbons and Biomarkers of Exposure in Wading Birds and Fish of the Lower Rio. During 1997 we evaluated reproductive success in colonial water birds nesting in the Lower Rio Grande Valley (LRGV), Texas, and correlated success with concentrations of contaminants in eggs. We also

  3. Cave and cliff swallows as indicators of exposure and effects of environmental contaminants on birds from the Rio Grande, Texas 

    E-Print Network [OSTI]

    Musquiz, Daniel

    2004-11-15

    in Burleson County, 320 miles north of the nearest site of the Rio Grande. Blood samples were analyzed by flow cytometry, a technique that allows the detection of DNA damage in blood and other tissues. Plasma samples were analyzed for thyroid hormones using...

  4. Appendix A: Documentation of data used in the Ecosystem Diagnosis and Treatment Model (EDT) for the Grande Ronde Basin.

    E-Print Network [OSTI]

    Appendix A: Documentation of data used in the Ecosystem Diagnosis and Treatment Model (EDT) for the Grande Ronde Basin. SUMMARY This report summarizes the values used in the Ecosystem Diagnosis observations, derived information, expert opinion, and hypothetical information. For example, if a stream width

  5. WESTWARD MIGRATING IGNIMBRITE CALDERAS AND A LARGE RADIATING MAFIC DIKE SWARM OF OLIGOCENE AGE, CENTRAL RIO GRANDE RIFT, NEW MEXICO

    E-Print Network [OSTI]

    Borchers, Brian

    WESTWARD MIGRATING IGNIMBRITE CALDERAS AND A LARGE RADIATING MAFIC DIKE SWARM OF OLIGOCENE AGE, CENTRAL RIO GRANDE RIFT, NEW MEXICO: SURFACE EXPRESSION OF AN UPPER MANTLE DIAPIR? CHAMBERLIN, Richard M., CHAPIN, Charles E., and McINTOSH, William C., New Mexico Bureau of Geology and Mineral Resources, New

  6. Submitted to HuffingtonPost.com Obama's Iran Nuclear Deadline: A Grand Bargain is Still Possible if Both Sides

    E-Print Network [OSTI]

    O'Donnell, Tom

    Submitted to HuffingtonPost.com Obama's Iran Nuclear Deadline: A Grand Bargain is Still Possible Obama and Secretary of State Clinton have promised "crippling" new sanctions will be imposed on Iran by year's end if Iran does not seriously engage in negotiations on its nuclear activities. Tehran clearly

  7. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. ???, XXXX, DOI:10.1029/, Possible impacts of a future Grand Solar Minimum1

    E-Print Network [OSTI]

    Maycock, Amanda

    climate system. It follows that changes in solar activity have the potential to27 influence global surface century known as the Maunder min-8 imum. The impact of returning to such a `grand solar minimum' on global Solar Minimum1 on surface climate2 A. C. Maycock 1 , S. Ineson 2 , L. J. Gray 34 , A. A. Scaife 2 and M

  8. ASHRAE 2000 Annual Meeting, June 24-28, 2000, Minneapolis, MN, and published in ASHRAE Transactions, 106(2) 2000.

    E-Print Network [OSTI]

    LBNL-44422 Mo-420 ASHRAE 2000 Annual Meeting, June 24-28, 2000, Minneapolis, MN, and published in ASHRAE Transactions, 106(2) 2000. This work was supported by the Assistant Secretary for Energy

  9. Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material

    E-Print Network [OSTI]

    Kim, Jae Chul

    We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic ...

  10. Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material

    E-Print Network [OSTI]

    Kim, Jae Chul

    We investigated the structural stability and electrochemical properties of LiMnBO[subscript 3] in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on ...

  11. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-01

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for a phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.

  12. Frances Marcus Lewis, RN, MN, PhD, FAAN Professor, Department of Family & Child Nursing, University of Washington

    E-Print Network [OSTI]

    Brent, Roger

    of Washington Frances Marcus Lewis, RN, MN, PhD, FAAN is a Professor in the Department of Family& Child Nursing at the University of Washington, sits as the University of Washington Medical Center Professor of Nursing Leadership

  13. Mn abundances in the stars of the Galactic disc with metallicities -1.0 < [Fe/H] < 0.3

    E-Print Network [OSTI]

    Mishenina, T; Pignatari, M; Thielemann, F -K; Korotin, S A

    2015-01-01

    In this work we present and discuss the observations of the Mn abundances for 247 FGK dwarfs, located in the Galactic disc with metallicity -1supernovae. We confirm the basel...

  14. Thermoelectric properties of nano-meso-micro ?-MnO? powders as a function of electrical resistance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hedden, Morgan; Francis, Nick; Haraldsen, Jason T.; Ahmed, Towfiq; Constantin, Costel

    2015-07-15

    Particle sizes of manganese oxide (?-MnO?) powders were modified by using a mortar and pestle ground method for period of times that varied between 15–60 min. Particle size versus ground time clearly shows the existence of a size-induced regime transition (i.e., regime I and II). Thermoelectric properties of ?-MnO? powders as a function of electrical resistance in the range of RP = 10 - 80? were measured. Based on the data presented, we propose a model for the ?-MnO? system in which nanometer-scale MnO? crystallites bond together through weak van der Waals forces to form larger conglomerates that span inmore »size from nanometer to micrometer scale.« less

  15. Thermoelectric properties of nano-meso-micro ?-MnO? powders as a function of electrical resistance

    SciTech Connect (OSTI)

    Hedden, Morgan; Francis, Nick; Haraldsen, Jason T.; Ahmed, Towfiq; Constantin, Costel

    2015-07-15

    Particle sizes of manganese oxide (?-MnO?) powders were modified by using a mortar and pestle ground method for period of times that varied between 15–60 min. Particle size versus ground time clearly shows the existence of a size-induced regime transition (i.e., regime I and II). Thermoelectric properties of ?-MnO? powders as a function of electrical resistance in the range of RP = 10 - 80? were measured. Based on the data presented, we propose a model for the ?-MnO? system in which nanometer-scale MnO? crystallites bond together through weak van der Waals forces to form larger conglomerates that span in size from nanometer to micrometer scale.

  16. Growth optimization and structural analysis for ferromagnetic Mn-doped ZnO layers deposited by radio frequency magnetron sputtering

    SciTech Connect (OSTI)

    Abouzaid, M.; Ruterana, P.; Liu, C.; Morkoc, H. [SIFCOM UMR 6176 CNRS-ENSICAEN, 6 Boulevard du Marechal Juin, 14050 Caen Cedex (France); Department of Electrical Engineering, Virginia Commonwealth University, Richmond Virginia 23284 (United States)

    2006-06-01

    The effect of the deposition temperature on the crystalline quality of (Zn,Mn)O is investigated in thin films prepared by radio frequency magnetron sputtering on c-plane sapphire and GaN substrates. The layers are made of a 0.5 {mu}m Mn-doped layer towards the surface on top of a 150 nm pure ZnO buffer. Depending on the deposition temperature, the layers can exhibit a columnar structure; the adjacent domains are rotated from one another by 90 deg. , putting [1010] and [1120] directions face to face. At high Mn concentration the columnar structure is blurred by the formation of Mn rich precipitates. Only one variety of domains is observed at an optimal deposition temperature of 500 deg. C: they are slightly rotated around the [0001] axis (mosaic growth) and bounded by threading dislocations.

  17. Disordered electronic and magnetic systems - transition metal (Mn) and rare earth (Gd) doped amorphous group IV semiconductors (C, Si, Ge)

    E-Print Network [OSTI]

    Zeng, Li

    2007-01-01

    for semiconductor spintronics. e Nature Phys. , 3(3):153,and D. M. Treger. Spintronics: a spin-based electronicsa test bed for simple spintronic devices. (In, Mn)As and (

  18. CTUIR Grande Ronde River Watershed Restoration Program McCoy Creek/McIntyre Creek Road Crossing, 1995-1999 Progress Report.

    SciTech Connect (OSTI)

    Childs, Allen B.

    2000-08-01

    The Confederated Tribes of the Umatilla Indian Reservation (CTUIR) and Bonneville Power Administration (BPA) entered into a contract agreement beginning in 1996 to fund watershed restoration and enhancement actions and contribute to recovery of fish and wildlife resources and water quality in the Grande Ronde River Basin. The CTUIR's habitat program is closely coordinated with the Grande Ronde Model Watershed Program and multiple agencies and organizations within the basin. The CTUIR has focused during the past 4 years in the upper portions of the Grande Ronde Subbasin (upstream of LaGrande, Oregon) on several major project areas in the Meadow, McCoy, and McIntyre Creek watersheds and along the mainstem Grande Ronde River. This Annual Report provides an overview of individual projects and accomplishments.

  19. Compressional Behavior of Bulk and Nanorod LiMn[subscript 2]O[subscript 4] under Nonhydrostatic Stress

    SciTech Connect (OSTI)

    Lin, Yu; Yang, Yuan; Ma, Hongwei; Cui, Yi; Mao, Wendy L. (Stanford); (SLAC)

    2011-09-20

    We studied the effect of pressure on LiMn{sub 2}O{sub 4} commercial powders and well-characterized nanorods using angle-dispersive synchrotron X-ray diffraction (XRD) in diamond anvil cells and found that spinel LiMn{sub 2}O{sub 4} is extremely sensitive to deviatoric stress induced by external applied pressure. Under nonhydrostatic conditions, bulk LiMn{sub 2}O{sub 4} underwent an irreversible phase transformation at pressures as low as 0.4 GPa from a cubic Fd-3m to tetragonal I4{sub 1}/amd structure driven by the Jahn-Teller effect. In contrast, bulk LiMn{sub 2}O{sub 4} under hydrostatic conditions experienced a reversible structural transformation beginning at approximately 11 GPa. Well-characterized LiMn{sub 2}O{sub 4} nanorods with an average diameter of 100-150 nm and an average length of 1-2 {micro}m were investigated under the same experimental conditions and showed a similar structural behavior as the bulk material confirming that LiMn{sub 2}O{sub 4} displays an extremely sensitive structural response to deviatoric stress. Scanning electron microscope (SEM) images of the samples especially the nanorods that were recovered from high pressure demonstrated a link between the changing morphology of the materials and the origin of the phase transition. We also found that nanostructured materials can accommodate more stress compared to their bulk counterparts. Our comparative study of bulk and nanorod LiMn{sub 2}O{sub 4} improves our understanding of their fundamental structural and mechanical properties, which can provide guidance for applied battery technology. In addition, LiMn{sub 2}O{sub 4} represents a strongly correlated system, whose structural, electronic, and magnetic properties at high pressure are of broad interest for fundamental chemistry and condensed matter physics.

  20. Non-extended phase space thermodynamics of Lovelock AdS black holes in grand canonical ensemble

    E-Print Network [OSTI]

    Jie-Xiong Mo; Wen-Biao Liu

    2015-03-06

    Recently, extended phase space thermodynamics of Lovelock AdS black holes has been of great interest. To provide insight from a different perspective and gain a unified phase transition picture, non-extended phase space thermodynamics of $(n+1)$-dimensional charged topological Lovelock AdS black holes is investigated detailedly in the grand canonical ensemble. Specifically, the specific heat at constant electric potential is calculated and phase transition in the grand canonical ensemble is discussed. To probe the impact of the various parameters, we utilize the control variate method and solve the phase transition condition equation numerically for the case $k=1,-1$. There are two critical points for the case $n=6,k=1$ while there is only one for other cases. For $k=0$, there exists no phase transition point. To figure out the nature of phase transition in the grand canonical ensemble, we carry out an analytic check of the analog form of Ehrenfest equations proposed by Banerjee et al. It is shown that Lovelock AdS black holes in the grand canonical ensemble undergo a second order phase transition. To examine the phase structure in the grand canonical ensemble, we utilize the thermodynamic geometry method and calculate both the Weinhold metric and Ruppeiner metric. It is shown that for both analytic and graphical results that the divergence structure of the Ruppeiner scalar curvature coincides with that of the specific heat. Our research provides one more example that Ruppeiner metric serves as a wonderful tool to probe the phase structures of black holes.

  1. Abundance analysis of SB2 binary stars with HgMn primaries

    E-Print Network [OSTI]

    T. Ryabchikova

    1998-05-06

    We present a short review of the abundances in the atmospheres of SB2 systems with Mercury-Manganese (HgMn) primaries. Up to now a careful study has been made for both components of 8 out of 17 known SB2 binaries with orbital periods shorter than 100 days and mass ratio ranging from 1.08 to 2.2. For all eight systems we observe a lower Mn abundance in the secondary's atmospheres than in the primary's. Significant difference in the abundances is also found for some peculiar elements such as Ga, Xe, Pt. All secondary stars with effective temperatures less than 10000 K show abundance characteristics typical of the metallic-line stars.

  2. Structural, elastic, electronic, magnetic and vibrational properties of CuCoMnGa under pressure

    SciTech Connect (OSTI)

    ?yigör, Ahmet; U?ur, ?ule

    2014-10-06

    First principles calculations for the structural, electronic, elastic and phonon properties of the cubic quaternary heusler alloy CuCoMnGa on pressure have been reported by density functional theory (DFT) within generalized gradient approximation (GGA). The calculated values of the elastic constants were used for estimations of the Debye temperatures, the bulk modulus, the shear modulus, the young modulus E, the poisson's ratio ? and the B/G ratio. The elastic constants satisfy all of the mechanical stability criteria. The electronic structures of the ferromagnetic configuration for CuCoMnGa have a metallic character. The estimated magnetic moment per formula unit is 3.76 ?{sub B}. The phonon dispersion is studied using the supercell approach, and the stable nature at 0.2 GPa pressure is observed.

  3. Low temperature magnetic properties of magnesium substituted YbMnO{sub 3}

    SciTech Connect (OSTI)

    Sattibabu, Bhumireddi Bhatnagar, Anil K. Mohan, Dasari Das, Dibakar Sundararaman, Mahadevan; Siruguri, Vasudeva; Rayaprol, Sudhindra

    2014-04-24

    Structural and magnetic properties of polycrystalline Yb{sub 1?x}Mg{sub x}MnO{sub 3} (x = 0, 0.05 and 0.10) hexagonal compounds prepared by solid state method, have been studied. The structural analyses of the samples were carried out by Rietveld analysis of neutron diffraction data. With increasing Mg content, we find that the lattice parameter a decreases and c increases whereas the overall Mn-O bond length decreases. Magnetization measured as a function of magnetic field at 2.5 K exhibits hysteresis, which is attributed to ferromagnetic like ordering of Yb{sup 3+} sublattice. Temperature dependence of ac magnetic susceptibility, ?{sub ac}(T), shows no signature of spin-glass behavior. ?”(T) exhibits a sudden increase at low temperatures which is due to ordering of Yb{sup 3+} sublattice.

  4. Extrinsic anomalous Hall effect in epitaxial Mn{sub 4}N films

    SciTech Connect (OSTI)

    Meng, M.; Wu, S. X. Ren, L. Z.; Zhou, W. Q.; Wang, Y. J.; Wang, G. L.; Li, S. W.

    2015-01-19

    Anomalous Hall effect (AHE) in ferrimagnetic Mn{sub 4}N epitaxial films grown by molecular-beam epitaxy is investigated. The longitudinal conductivity ?{sub xx} is within the superclean regime, indicating Mn{sub 4}N is a highly conducting material. We further demonstrate that the AHE signal in 40-nm-thick films is mainly due to the extrinsic contributions based on the analysis fitted by ?{sub AH}=a??{sub xx0}+b?{sub xx}{sup 2} and ?{sub AH}??{sub xx}. Our study not only provide a strategy for further theoretical work on antiperovskite manganese nitrides but also shed promising light on utilizing their extrinsic AHE to fabricate spintronic devices.

  5. Magnetochromic effect in multiferroic R In 1 ? x Mn x O 3 ( R = Tb , Dy)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, P.; Holinsworth, B. S.; O'Neal, K. R.; Brinzari, T. V.; Mazumdar, D.; Topping, C. V.; Luo, X.; Cheong, S.-W.; Singleton, J.; McGill, S.; et al

    2015-05-26

    We combined high field magnetization and magneto-optical spectroscopy to investigate spin-charge coupling in Mn-substituted rare-earth indium oxides of chemical formula RIn??xMnxO? (R=Tb, Dy). The edge states, on-site Mn³?d to d excitations, and rare-earth f-manifold excitations all track the magnetization energy due to dominant Zeeman interactions. The field-induced modifications to the rare-earth excitations are quite large because spin-orbit coupling naturally mixes spin and charge, suggesting that the next logical step in the design strategy should be to bring spin-orbit coupling onto the trigonal bipyramidal chromophore site with a 4 or 5d center.

  6. What is the valence of Mn in Ga1-xMnxN?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Berlijn, Tom; Jarrell, Mark; Nelson, Ryky; Ku, Wei; Moreno, Juana

    2015-11-04

    Motivated by the potential high Curie temperature of Ga1-xMnxN, we investigate the controversial Mn valence in this diluted magnetic semiconductor. From a first-principles Wannier-function analysis of the high energy Hilbert space, we find unambiguously the Mn valence to be close to 2+(d5), but in a mixed spin configuration with average magnetic moments of 4µB. By integrating out high-energy degrees of freedom differently, we further demonstrate the feasibility of both effective d4 and d5 descriptions. These two descriptions offer simple pictures for local and extended properties of the system, and highlight the dual nature of its doped hole. Specifically, in themore »effective d5 description, we demonstrate novel physical effects absent in previous studies. Thus, our derivation highlights the richness of low-energy sectors in interacting many-body systems and the generic need for multiple effective descriptions.« less

  7. Magnetochromic effect in multiferroic R In 1 ? x Mn x O 3 ( R = Tb , Dy)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, P.; Holinsworth, B. S.; O'Neal, K. R.; Brinzari, T. V.; Mazumdar, D.; Topping, C. V.; Luo, X.; Cheong, S.-W.; Singleton, J.; McGill, S.; Musfeldt, J. L.

    2015-05-01

    We combined high field magnetization and magneto-optical spectroscopy to investigate spin-charge coupling in Mn-substituted rare-earth indium oxides of chemical formula RIn??xMnxO? (R=Tb, Dy). The edge states, on-site Mn³?d to d excitations, and rare-earth f-manifold excitations all track the magnetization energy due to dominant Zeeman interactions. The field-induced modifications to the rare-earth excitations are quite large because spin-orbit coupling naturally mixes spin and charge, suggesting that the next logical step in the design strategy should be to bring spin-orbit coupling onto the trigonal bipyramidal chromophore site with a 4 or 5d center.

  8. Three very young HgMn stars in the Orion OB1 Association

    E-Print Network [OSTI]

    Vincent M. Woolf; David L. Lambert

    1999-05-18

    We report the detection of three mercury-manganese stars in the Orion OB1 association. HD 37886 and BD-0 984 are in the approximately 1.7 million year old Orion OB1b. HD 37492 is in the approximately 4.6 million year old Orion OB1c. Orion OB1b is now the youngest cluster with known HgMn star members. This places an observational upper limit on the time scale needed to produce the chemical peculiarities seen in mercury-manganese stars, which should help in the search for the cause or causes of the peculiar abundances in HgMn and other chemically peculiar upper main sequence stars.

  9. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDuke EnergyRenewableMassachusettsCity of San Diego-AnaheimIllinois MunicipalModestoGrand MaraisResidentialGrand

  10. Homogeneity testing and quantitative analysis of manganese (Mn) in vitrified Mn-doped glasses by laser-induced breakdown spectroscopy (LIBS)

    SciTech Connect (OSTI)

    Unnikrishnan, V. K.; Nayak, Rajesh; Kartha, V. B.; Santhosh, C. E-mail: unnikrishnan.vk@manipal.edu; Sonavane, M. S.; Yeotikar, R. G.; Shah, M. L.; Gupta, G. P.; Suri, B. M.

    2014-09-15

    Laser-induced breakdown spectroscopy (LIBS), an atomic emission spectroscopy method, has rapidly grown as one of the best elemental analysis techniques over the past two decades. Homogeneity testing and quantitative analysis of manganese (Mn) in manganese-doped glasses have been carried out using an optimized LIBS system employing a nanosecond ultraviolet Nd:YAG laser as the source of excitation. The glass samples have been prepared using conventional vitrification methods. The laser pulse irradiance on the surface of the glass samples placed in air at atmospheric pressure was about 1.7×10{sup 9} W/cm{sup 2}. The spatially integrated plasma emission was collected and imaged on to the spectrograph slit using an optical-fiber-based collection system. Homogeneity was checked by recording LIBS spectra from different sites on the sample surface and analyzing the elemental emission intensities for concentration determination. Validation of the observed LIBS results was done by comparison with scanning electron microscope- energy dispersive X-ray spectroscopy (SEM-EDX) surface elemental mapping. The analytical performance of the LIBS system has been evaluated through the correlation of the LIBS determined concentrations of Mn with its certified values. The results are found to be in very good agreement with the certified concentrations.

  11. Strain-induced modification in the magnetic properties of Mn{sub 5}Ge{sub 3} thin films

    SciTech Connect (OSTI)

    Dung, Dang Duc [Department of Physics and EHSRC, University of Ulsan, Ulsan 680-749 (Korea, Republic of) [Department of Physics and EHSRC, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Department of General Physics, School of Engineering Physics, Hanoi University of Science and Technology, 1 Dai Co Viet Road, Hanoi (Viet Nam); Odkhuu, Dorj; Cheol Hong, Soon; Cho, Sunglae [Department of Physics and EHSRC, University of Ulsan, Ulsan 680-749 (Korea, Republic of)] [Department of Physics and EHSRC, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Thanh Vinh, Le [Aix Marseille Université, CNRS, CINaM-UMR 7325, 13288 Marseille (France)] [Aix Marseille Université, CNRS, CINaM-UMR 7325, 13288 Marseille (France)

    2013-08-21

    Epitaxial ferromagnetic Mn{sub 5}Ge{sub 3} thin films were stabilized on GaSb(001) and GaAs(001) substrates using molecular beam epitaxy. Compared to bulk Mn{sub 5}Ge{sub 3} materials, an enhancement of the Curie temperature above 350 K and about 320 K was observed for Mn{sub 5}Ge{sub 3}/GaAs(001) and Mn{sub 5}Ge{sub 3}/GaSb(001) heterostructures, respectively. The magnetization was found to decrease from 323 to 245 emu/cm{sup 3} for films grown on GaSb(001) and GaAs(001). Anomalous Hall effect measurements provide evidence of the strain-induced large spin polarization from density-functional study. Furthermore, our calculated results in bulk Mn{sub 5}Ge{sub 3} under strain indicate that the strain is the origin of different physical properties of Mn{sub 5}Ge{sub 3} grown on different substrates.

  12. Epitaxial {tau} phase MnAl thin films on MgO (001) with thickness-dependent magnetic anisotropy

    SciTech Connect (OSTI)

    Cui Yishen; Chen Wei [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Yin Wenjing; Lu Jiwei [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Wolf, Stuart A. [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States)

    2011-11-15

    In this study, ferromagnetic MnAl films were prepared by alternating Al/Mn quasi-monolayer deposition using a novel biased target ion beam deposition (BTIBD) technique. XRD results showed that the magnetic {tau} phase was well formed in MnAl thin films ({approx}10 nm), which grew epitaxially on single crystal MgO (001) substrates. The optimized saturation magnetization was {approx}394 emu/cc. Furthermore, we observed a thickness-dependent uniaxial anisotropy in ferromagnetic MnAl films, which was attributed to the change of the tetragonal lattice distortion as a function of film thickness. The relationship between the film thicknesses and saturation magnetizations suggested the existence of a magnetically dead layer {approx}2.7 nm with an extrapolated saturation moment around 523 emu/cc ({approx}1.90 {mu}{sub B}/Mn). This value has exceeded the experimental value in bulk materials and is close to the theoretically predicted magnetization ({approx}1.975 {mu}{sub B}/Mn).

  13. Mn$_3$O$_4$(001) film growth on Ag(001) - a systematic study using NEXAFS, STM, and LEED

    E-Print Network [OSTI]

    Gillmeister, Konrad; Shantyr, Roman; Trautmann, Martin; Meinel, Klaus; Chassé, Angelika; Schindler, Karl-Michael; Neddermeyer, Henning; Widdra, Wolf

    2015-01-01

    The film growth of Mn$_3$O$_4$(001) films on Ag(001) up to film thicknesses of almost seven unit cells of Mn$_3$O$_4$ has been monitored using a complementary combination of near-edge X-ray absorption fine structure spectroscopy (NEXAFS), scanning tunneling microscopy (STM), and low-energy electron diffraction (LEED). The oxide films have been prepared by molecular beam epitaxy. Using NEXAFS, the identity of the Mn oxide has clearly been determined as Mn$_3$O$_4$. For the initial stages of growth, oxide islands with p(2$\\times$1) and p(2$\\times$2) structures are formed, which are embedded into the substrate. For Mn$_3$O$_4$ coverages up to 1.5 unit cells a p(2$\\times$1) structure of the films is visible in STM and LEED. Further increase of the thickness leads to a phase transition of the oxide films resulting in an additional c(2$\\times$2) structure with a 45$^\\circ$ rotated atomic pattern. The emerging film structures are discussed on the basis of a sublayer model of the Mn$_3$O$_4$ spinel unit cell. While t...

  14. Preparation and characterization of nanostructured NiO/MnO{sub 2} composite electrode for electrochemical supercapacitors

    SciTech Connect (OSTI)

    Liu Enhui Li Wen; Li Jian; Meng Xiangyun; Ding Rui; Tan Songting

    2009-05-06

    Nanostructured nickel-manganese oxides composite was prepared by the sol-gel and the chemistry deposition combination new route. The surface morphology and structure of the composite were characterized by scanning electron microscope and X-ray diffraction. The as-synthesized NiO/MnO{sub 2} samples exhibit higher surface area of 130-190 m{sup 2} g{sup -1}. Cyclic voltammetry and galvanostatic charge/discharge measurements were applied to investigate the electrochemical performance of the composite electrodes with different ratios of NiO/MnO{sub 2}. When the mass ratio of MnO{sub 2} and NiO in composite material is 80:20, the specific capacitance value of NiO/MnO{sub 2} calculated from the cyclic voltammetry curves is 453 F g{sup -1}, for pure NiO and MnO{sub 2} are 209, 330 F g{sup -1} in 6 mol L{sup -1} KOH electrolyte and at scan rate of 10 mV s{sup -1}, respectively. The specific capacitance of NiO/MnO{sub 2} electrode is much larger than that of each pristine component. Moreover, the composite electrodes showed high power density and stable electrochemical properties.

  15. Electrical gating effects on the magnetic properties of (Ga,Mn)As diluted magnetic semiconductors

    E-Print Network [OSTI]

    Owen, Man Hon Samuel

    2010-11-16

    . . . . . . . . . . . . . . . . . . . . . . . . . . 62 3.3.1 Cryogenic systems . . . . . . . . . . . . . . . . . . . . . . . . 62 IV 3.3.2 Electrical measurements . . . . . . . . . . . . . . . . . . . . . 63 Resistance vs. temperature . . . . . . . . . . . . . . . . . . . . 64 Magnetic field sweeps... reduces the tendency toward spin-glass freezing. In fact, for a Background 18 Figure 2.5: Magnetization M as a function of magnetic field H for Ga0.97Mn0.03As thin films, measured at 55 K by SQUID for sample No. 1 at the top panel and sample No. 2...

  16. Magnetism in La?O?(Fe??xMnx)?Se? tuned by Fe/Mn ratio

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lei, Hechang; Bozin, Emil S.; Llobet, A.; Ivanovski, V.; Koteski, V.; Belosevic-Cavor, J.; Cekic, B.; Petrovic, C.

    2012-09-01

    We report the evolution of structural and magnetic properties in La?O?(Fe??xMnx)?Se?. Heat capacity and bulk magnetization indicate an increased ferromagnetic component of the long-range magnetic order and possible increased degree of frustration. Atomic disorder on Fe(Mn) sites suppresses the temperature of the long-range order whereas intermediate alloys show a rich magnetic phase diagram.

  17. MN Lup: X-RAYS FROM A WEAKLY ACCRETING T TAURI STAR

    SciTech Connect (OSTI)

    Guenther, H. M.; Wolk, S. J.; Wolter, U.; Robrade, J.

    2013-07-01

    Young T Tauri stars (TTS) are surrounded by an accretion disk, which over time disperses due to photoevaporation, accretion, and possibly planet formation. The accretion shock on the central star produces an UV/optical veiling continuum, line emission, and X-ray signatures. As the accretion rate decreases, the impact on the central star must change. In this article we study MN Lup, a young star where no indications of a disk are seen in IR observations. We present XMM-Newton and VLT/UVES observations, some of them taken simultaneously. The X-ray data show that MN Lup is an active star with L{sub X} /L{sub bol} close to the saturation limit. However, we find high densities (n{sub e} > 3 Multiplication-Sign 10{sup 10} cm{sup -3}) in the X-ray grating spectrum. This can be well fitted using an accretion shock model with an accretion rate of 2 Multiplication-Sign 10{sup -11} M{sub Sun} yr{sup -1}. Despite the simple H{alpha} line profile which has a broad component, but no absorption signatures as typically seen on accreting TTS, we find rotational modulation in Ca II K and in photospheric absorption lines. These line profile modulations do not clearly indicate the presence of a localized hot accretion spot on the star. In the H{alpha} line we see a prominence in absorption about 2R{sub *} above the stellar surface-the first of its kind on a TTS. MN Lup is also the only TTS where accretion is seen, but no dust disk is detected that could fuel it. We suggest that MN Lup presents a unique and short-lived state in the disk evolution. It may have lost its dust disk only recently and is now accreting the remaining gas at a very low rate.

  18. Solar DEM Models : A solar image in color band b, mn pixels,

    E-Print Network [OSTI]

    Wolfe, Patrick J.

    Solar DEM Models : A solar image in color band b, m×n pixels, containing a particular solar feature, for t = 1, 2, . . . , T. btM sianFieldRandomGaus I M I I bbb T t bbtt bbb bb 2 1 2 )( #12;Solar DEM.bI : the measure error of the ith row and jth column pixel of the certain image in color band b. ijbe #12;Solar DEM

  19. Thermoelectric study of crossroads material MnTe via sulfur doping

    SciTech Connect (OSTI)

    Xie, Wenjie Populoh, Sascha; Sagarna, Leyre; Trottmann, Matthias; Ga??zka, Krzysztof; Xiao, Xingxing; Liu, Yufei; He, Jian; Weidenkaff, Anke

    2014-03-14

    Here, we report thermoelectric study of crossroads material MnTe via iso-electronic doping S on the Te-site. MnTe{sub 1-x}S{sub x} samples with nominal S content of x?=?0.00, 0.05, and 0.10 were prepared using a melt-quench method followed by pulverization and spark plasma sintering. The X-ray powder diffraction, scanning electron microscopy, and ZAF-corrected compositional analysis confirmed that S uniformly substitutes Te up to slightly over 2%. A higher content of S in the starting materials led to the formation of secondary phases. The thermoelectric properties of MnTe{sub 1-x}S{sub x} samples were characterized by means of Seebeck coefficient, electrical conductivity, and thermal conductivity measurements from 300?K to 773?K. Furthermore, Hall coefficient measurements and a single parabolic band model were used to help gain insights on the effects of S-doping on the scattering mechanism and the carrier effective mass. As expected, S doping not only introduced hole charge carriers but also created short-range defects that effectively scatter heat-carrying phonons at elevated temperatures. On the other hand, we found that S doping degraded the effective mass. As a result, the ZT of MnTe{sub 0.9}S{sub 0.1} was substantially enhanced over the pristine sample near 400?K, while the improvement of ZT became marginal at elevated temperatures. A ZT???0.65 at 773?K was obtained in all three samples.

  20. Redox Active Layer-by-Layer Structures containing MnO2 Nanoparticles

    SciTech Connect (OSTI)

    Bazito, Fernanda; O'Brien, Robert; Buttry, Daniel A.

    2005-02-01

    Nanoscale materials provide unique properties that will enable new technologies and enhance older ones. One area of intense activity in which nanoscale materials are being used is in the development of new functional materials for battery applications. This effort promises superior materials with properties that circumvent many of the problems associated with traditional battery materials. Previously we have worked on several approaches for using nanoscale materials for application as cathode materials in rechargeable Li batteries. Our recent work has focused on synthesizing MnO2 nanoparticles and using these in layer-by-layer (LbL) structures to probe the redox properties of the nanoparticles. We show that the aqueous colloidal nanoparticles produced by butanol reduction of tetramethylammonium permanganate can be trapped in thin films using a layer-by-layer deposition approach, and that these films are both redox active and exhibit kinetically facile electrochemical responses. We show cyclic voltammetry of MnO2 colloidal nanoparticles entrapped in a LbL thin film at an ITO electrode surface using poly(diallyldimethylammonium chloride) (PDDA). CV experiments demonstrate that Li+ insertion accompanies Mn(IV) reduction in LiClO4 supporting electrolytes, and that reduction is hindered in supporting electrolytes containing only tetrabutylammonium cations. We also show that electron propagation through multilayer films is facile, suggesting that electrons percolate through the films via electron exchange between nanoparticles.

  1. Magnetization-steps in Y?CoMnO? double perovskite: The role of antisite disorder

    SciTech Connect (OSTI)

    Nair, Harikrishnan S. Xiao, Yinguo; Brückel, Th.; Cherian, Dona; Elizabeth, Suja; Hansen, Thomas; Chatterji, Tapan

    2014-09-28

    Antisite disorder is observed to have significant impact on the magnetic properties of the double perovskite Y²CoMnO? which has been recently identified as a multiferroic. A paramagnetic-ferromagnetic phase transition occurs in this material at Tc ? 75 K. At 2 K, it displays a strong ferromagnetic hysteresis with a significant coercive field of Hc ? 15 kOe. Sharp steps are observed in the hysteresis curves recorded below 8 K. In the temperature range 2 K ? T ? 5 K, the hysteresis loops are anomalous as the virgin curve lies outside the main loop. The field-cooling conditions as well as the rate of field-sweep are found to influence the steps. Quantitative analysis of the neutron diffraction data shows that at room temperature, Y?CoMnO? consists of 62% of monoclinic P2?/n with nearly 70% antisite disorder and 38% Pnma. The bond valence sums indicate the presence of other valence states for Co and Mn which arise from disorder. We explain the origin of steps by using a model for pinning of magnetization at the antiphase boundaries created by antisite disorder. The steps in magnetization closely resemble the martensitic transformations found in intermetallics and display first-order characteristics as revealed in the Arrott's plots.

  2. Correlating Local Structure with Electrochemical Activity in Li2MnO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nanda, Jagjit; Sacci, Robert L.; Veith, Gabriel M.; Dixit, Hemant M.; Cooper, Valentino R.; Pezeshki, Alan M.; Ruther, Rose E.

    2015-07-31

    Li2MnO3 is of interest as one component of the composite lithium-rich oxides, which are under development for high capacity, high voltage cathodes in lithium ion batteries. Despite such practical importance, the mechanism of electrochemical activity in Li2MnO3 is contested in the literature, as are the effects of long-term electrochemical cycling. Here, Raman spectroscopy and mapping are used to follow the chemical and structural changes that occur in Li2MnO3. Both conventional slurry electrodes and thin films are studied as a function of the state of charge (voltage) and cycle number. Thin films have similar electrochemical properties as electrodes prepared from slurries,more »but allow for spectroscopic investigations on uniform samples without carbon additives. Spectral changes correlate well with electrochemical activity and support a mechanism whereby capacity is lost upon extended cycling due to the formation of new manganese oxide phases. Raman mapping of both thin film and slurry electrodes charged to different voltages reveals significant variation in the local structure. Poor conductivity and slow kinetics associated with a two-phase reaction mechanism contribute to the heterogeneity.« less

  3. Magnetic anisotropy barrier for spin tunneling in Mn{sub 12}O{sub 12} molecules

    SciTech Connect (OSTI)

    Pederson, M.R. [Center for Computational Materials Science--6392, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States)] [Center for Computational Materials Science--6392, Naval Research Laboratory, Washington, D.C. 20375-5000 (United States); Khanna, S.N. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284-2000 (United States)

    1999-10-01

    Electronic structure calculations on the nature of electronic states and the magnetic coupling in Mn-acetate [Mn{sub 12}O{sub 12}(RCOO){sub 16}(H{sub 2}O){sub 4}] molecules have been been carried out within the generalized gradient approximation to the density functional formalism. Our studies on this 100-atom molecule illustrate the role of the nonmagnetic carboxyl host in stabilizing the ferrimagnetic Mn{sub 12}O{sub 12} core and provide estimates of the local magnetic moment at the various sites. We provide a first density-functional-based prediction of the second-order magnetic anisotropy energy of this system. Results are in excellent agreement with experiment. To perform these calculations we introduce a simplified exact method for spin-orbit coupling and magnetic anisotropy energies in multicenter systems. This method is free of shape approximations and has other advantages as well. First, it is valid for periodic boundary conditions or finite systems and is independent of basis set choice. Second, the method does not require the calculation of electric field. Third, for applications to systems with a finite energy gap between occupied and unoccupied electronic states, a perturbative expansion allows for a simple determination of the magnetic anisotropy energy. {copyright} {ital 1999} {ital The American Physical Society}

  4. Resonant spin tunneling in randomly oriented nanospheres of Mn12 acetate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lendínez, S.; Zarzuela, R.; Tejada, J.; Terban, M. W.; Billinge, S. J. L.; Espin, J.; Imaz, I.; Maspoch, D.; Chudnovsky, E. M.

    2015-01-06

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for amore »single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. In conclusion, our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.« less

  5. MnO{sub 2}@colloid carbon spheres nanocomposites with tunable interior architecture for supercapacitors

    SciTech Connect (OSTI)

    Zhang, Yuxin; Liu, Chuanpu; Wen, Zhongquan

    2014-01-01

    Graphical abstract: - Highlights: • MnO{sub 2}@CSs nanocomposites have been successfully synthesized in room temperature. • The composites exhibited three structures: core–shell, yolk–shell and hollow structure. • The yolk–shell structure exhibited a high specific capacitance and cycling stability. - Abstract: MnO{sub 2}@colloid carbon spheres nanocomposites with tunable interior architecture have been synthesized by a facile and cost-effective strategy at room temperature. The structure and morphology of as-prepared nanocomposites were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), nitrogen adsorption, focused ion beam scanning electron microscopy (FIB/SEM) and high-resolution transmission electron microscopy (HRTEM). The as-obtained composites exhibited a three-dimensional architecture with core–shell, yolk–shell and hollow interior structure. Furthermore, the electrochemical properties of composites were evaluated by cycle voltammetric (CV) and galvanostatic charge–discharge measurements. The yolk–shell structure exhibited the optimized pseudocapacitance performance, revealing a specific capacitance (273 F g{sup ?1}) with a good rate and cycling stability, owing to its unique structure and the poor crystallinity of MnO{sub 2} nanofilms. Therefore, this facile synthetic strategy could be useful to design and synthesis of tunable nanostructures with enhanced supercapacitor behavior.

  6. Why MnIn{sub 2}O{sub 4} spinel is not a transparent conducting oxide?

    SciTech Connect (OSTI)

    Martinez-Lope, M.J.; Retuerto, M.; Calle, C. de la; Porcher, Florence

    2012-03-15

    The title compound has been synthesized by a citrate technique. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3-bar m, Z=8, with a=9.0008(1) A at 295 K. It exhibits a crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively, with a slight degree of inversion, {lambda}=0.08. MnIn{sub 2}O{sub 4} shows antiferromagnetic interactions below T{sub N} Almost-Equal-To 40 K, due to the statistical distribution of Mn ions over the two available sites. Unlike the related MgIn{sub 2}O{sub 4} and CdIn{sub 2}O{sub 4} spinels, well known as transparent conducting oxides, MnIn{sub 2}O{sub 4} is not transparent and shows a poor conductivity ({sigma}=0.38 S cm{sup -1} at 1123 K): the presence of Mn ions, able to adopt mixed valence states, localizes the charges that, otherwise, would be delocalized in the spinel conduction band. - Graphical Abstract: From NPD data the crystallographic formula (Mn{sub 0.924(2)}In{sub 0.076(2)}){sub 8a}(In{sub 1.804(2)}Mn{sub 0.196(2)}){sub 16d}O{sub 4}, shows a slight degree of inversion, {lambda}=0.08 and a certain In deficiency. The presence of Mn ions, able to adopt mixed oxidation states, localize the charges that, otherwise, would be delocalized in the spinel conduction band; the presence of localized Mn{sup 2+} and Mn{sup 3+} ions provides the characteristic brown color. Highlights: Black-Right-Pointing-Pointer Accurate structural determination from NPD data: inversion degree (8%), and In deficiency. Black-Right-Pointing-Pointer Bond-valence indicates Mn{sup 2+}-Mn{sup 3+} ions; edge-sharing octahedra contain 90% In{sup 3+}+10% Mn{sup 3+} cations. Black-Right-Pointing-Pointer Conductivity several orders of magnitude lower than those of MgIn{sub 2}O{sub 4} or CdIn{sub 2}O{sub 4}. Black-Right-Pointing-Pointer Variability of Mn oxidation states cancels any electron-doping effect, emptying conduction band of mobile charge carriers. Black-Right-Pointing-Pointer Curie-Weiss behavior confirming the determined charge distribution.

  7. Grand Challenges for Biological and Environmental Research: A Long-Term Vision

    SciTech Connect (OSTI)

    Arkin, A.; Baliga, N.; Braam, J.; Church, G.; Collins, J; Cottingham, R.; Ecker, J.; Gerstein, M.; Gilna, P.; Greenberg, J.; Handelsman, J.; Hubbard, S.; Joachimiak, A.; Liao, J.; Looger, L.; Meyerowitz, E.; Mjolness, E.; Petsko, G.; Sayler, G.; Simpson, M.; Stacey, G.; Sussman, M.; Tiedje, J.; Bader, D.; Cessi, P.; Collins, W.; Denning, S.; Dickinson, R.; Easterling, D.; Edmonds, J.; Feddema, J.; Field, C.; Fridlind, A.; Fung, I.; Held, I.; Jackson, R.; Janetos, A.; Large, W.; Leinen, M.; Leung, R.; Long, S.; Mace, G.; Masiello, C.; Meehl, G.; Ort, D.; Otto-Bliesner, B.; Penner, J.; Prather, M.; Randall, D.; Rasch, P.; Schneider, E.; Shugart, H.; Thornton, P.; Washington, W.; Wildung, R.; Wiscombe, W.; Zak, D.; Zhang, M.; Bielicki, J.; Buford, M.; Cleland, E.; Dale, V.; Duke, C.; Ehleringer, J.; Hecht, A.; Kammen, D.; Marland, G.; Pataki, D.; Riley, M. Robertson, P.; Hubbard, S.

    2010-12-01

    The interactions and feedbacks among plants, animals, microbes, humans, and the environment ultimately form the world in which we live. This world is now facing challenges from a growing and increasingly affluent human population whose numbers and lifestyles are driving ever greater energy demand and impacting climate. These and other contributing factors will make energy and climate sustainability extremely difficult to achieve over the 20-year time horizon that is the focus of this report. Despite these severe challenges, there is optimism that deeper understanding of our environment will enable us to mitigate detrimental effects, while also harnessing biological and climate systems to ensure a sustainable energy future. This effort is advanced by scientific inquiries in the fields of atmospheric chemistry and physics, biology, ecology, and subsurface science - all made possible by computing. The Office of Biological and Environmental Research (BER) within the Department of Energy's (DOE) Office of Science has a long history of bringing together researchers from different disciplines to address critical national needs in determining the biological and environmental impacts of energy production and use, characterizing the interplay of climate and energy, and collaborating with other agencies and DOE programs to improve the world's most powerful climate models. BER science focuses on three distinct areas: (1) What are the roles of Earth system components (atmosphere, land, oceans, sea ice, and the biosphere) in determining climate? (2) How is the information stored in a genome translated into microbial, plant, and ecosystem processes that influence biofuel production, climate feedbacks, and the natural cycling of carbon? (3) What are the biological, geochemical, and physical forces that govern the behavior of Earth's subsurface environment? Ultimately, the goal of BER science is to support experimentation and modeling that can reliably predict the outcomes and behaviors of complex biological and environmental systems, leading to robust solutions for DOE missions and strategic goals. In March 2010, the Biological and Environmental Research Advisory Committee held the Grand Challenges for Biological and Environmental Research: A Long-Term Vision workshop to identify scientific opportunities and grand challenges for BER science in the coming decades and to develop an overall strategy for drafting a long-term vision for BER. Key workshop goals included: (1) Identifying the greatest scientific challenges in biology, climate, and the environment that DOE will face over a 20-year time horizon. (2) Describing how BER should be positioned to address those challenges. (3) Determining the new and innovative tools needed to advance BER science. (4) Suggesting how the workforce of the future should be trained in integrative system science. This report lays out grand research challenges for BER - in biological systems, climate, energy sustainability, computing, and education and workforce training - that can put society on a path to achieve the scientific evidence and predictive understanding needed to inform decision making and planning to address future energy needs, climate change, water availability, and land use.

  8. Electrolyte pore/solution partitioning by expanded grand canonical ensemble Monte Carlo simulation

    SciTech Connect (OSTI)

    Moucka, Filip; Bratko, Dusan Luzar, Alenka

    2015-03-28

    Using a newly developed grand canonical Monte Carlo approach based on fractional exchanges of dissolved ions and water molecules, we studied equilibrium partitioning of both components between laterally extended apolar confinements and surrounding electrolyte solution. Accurate calculations of the Hamiltonian and tensorial pressure components at anisotropic conditions in the pore required the development of a novel algorithm for a self-consistent correction of nonelectrostatic cut-off effects. At pore widths above the kinetic threshold to capillary evaporation, the molality of the salt inside the confinement grows in parallel with that of the bulk phase, but presents a nonuniform width-dependence, being depleted at some and elevated at other separations. The presence of the salt enhances the layered structure in the slit and lengthens the range of inter-wall pressure exerted by the metastable liquid. Solvation pressure becomes increasingly repulsive with growing salt molality in the surrounding bath. Depending on the sign of the excess molality in the pore, the wetting free energy of pore walls is either increased or decreased by the presence of the salt. Because of simultaneous rise in the solution surface tension, which increases the free-energy cost of vapor nucleation, the rise in the apparent hydrophobicity of the walls has not been shown to enhance the volatility of the metastable liquid in the pores.

  9. Long-term surveillance plan for the Cheney disposal site near Grand Junction, Colorado

    SciTech Connect (OSTI)

    NONE

    1997-04-01

    This long-term surveillance plan (LTSP) describes the U.S. Department of Energy`s (DOE) long-term care program for the Uranium Mill Tailings Remedial Action (UMTRA) Project Cheney disposal site. The site is in Mesa County near Grand Junction, Colorado. The U.S. Nuclear Regulatory Commission (NRC) has developed regulations for the issuance of a general license for the custody and long-term care of UMTRA Project disposal sites in 10 CFR Part 40. The purpose of this general license is to ensure that the UMTRA Project disposal sites are cared for in a manner that protects public health and safety and the environment. Before each disposal site may be licensed, the NRC requires the DOE to submit a site-specific LTSP. The DOE prepared this LTSP to meet this requirement for the Cheney disposal site. The general license becomes effective when the NRC concurs with the DOE`s determination that remedial action is complete and the NRC formally accepts this plan. This document describes the long-term surveillance program the DOE will implement to ensure that the Cheney disposal site performs as designed. The program is based on site inspections to identify potential threats to disposal cell integrity. The LTSP is based on the UMTRA Project long-term surveillance program guidance and meets the requirements of 10 CFR {section}40.27(b) and 40 CFR {section}192.03.

  10. Measurements of air contaminants during the Cerro Grande fire at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Eberhart, Craig

    2010-08-01

    Ambient air sampling for radioactive air contaminants was continued throughout the Cerro Grande fire that burned part of Los Alamos National Laboratory. During the fire, samples were collected more frequently than normal because buildup of smoke particles on the filters was decreasing the air flow. Overall, actual sampling time was 96% of the total possible sampling time for the May 2000 samples. To evaluate potential human exposure to air contaminants, the samples were analyzed as soon as possible and for additional specific radionuclides. Analyses showed that the smoke from the fire included resuspended radon decay products that had been accumulating for many years on the vegetation and the forest floor that burned. Concentrations of plutonium, americium, and depleted uranium were also measurable, but at locations and concentrations comparable to non-fire periods. A continuous particulate matter sampler measured concentrations that exceeded the National Ambient Air Quality Standard for PM-10 (particles less than 10 micrometers in diameter). These high concentrations were caused by smoke from the fire when it was close to the sampler.

  11. Boric acid flux synthesis, structure and magnetic property of MB??O??(OH)?? (M=Mn, Fe, Zn)

    SciTech Connect (OSTI)

    Yang, Dingfeng; Cong, Rihong [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Gao, Wenliang, E-mail: gaowl@cqu.edu.cn [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China); Yang, Tao, E-mail: taoyang@cqu.edu.cn [College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044 (China)

    2013-05-01

    Three new borates MB??O??(OH)?? (M=Mn, Fe, Zn) have been synthesized by boric acid flux methods, which are isotypic to NiB??O??(OH)??. Single-crystal XRD was performed to determine the crystal structures in detail. They all crystallize in the monoclinic space group P2?/c. The size of MO{sub 6} (M=Mg, Mn, Fe, Co, Ni, Zn) octahedron shows a good agreement with the Shannon effective ionic radii of M²?. Magnetic measurements indicate MnB??O??(OH)?? is antiferromagnetic without a long-range ordering down to 2 K. The values of its magnetic superexchange constants were evaluated by DFT calculations, which explain the observed magnetic behavior. The UV–vis diffuse reflectance spectrum of ZnB??O??(OH)?? suggests a band gap ~4.6 eV. DFT calculations indicate it has a direct band gap 4.9 eV. The optical band gap is contributed by charge transfers from the occupied O 2p to the unoccupied Zn 4s states. - Graphical abstract: Experimental and theoretical studies indicate MnB??O??(OH)?? is antiferromagnetic without a long-range ordering. DFT calculations show ZnB??O??(OH)?? has a direct band gap of 4.9 eV. Highlights: • MB??O??(OH)?? (M=Mn, Fe, Zn) are synthesized by two-step boric acid flux method. • Single-crystal XRD was performed to determine the crystal structures in detail. • Size of MO? (M=Mg, Mn, Fe, Co, Ni, Zn) agrees with the effective ionic radii. • MnB??O??(OH)?? is antiferromagnetic without a long-range ordering down to 2 K. • DFT calculations indicate ZnB??O??(OH)?? has a direct band gap 4.9 eV.

  12. Le mode d'emergence du Reel - L'avenement des manifestations de la base (gzhi snang) selon les conceptions de la Grande Perfection

    E-Print Network [OSTI]

    Achard, Jean-Luc

    2005-01-01

    — LE MODE D’EMERGENCE DU REEL —L’AVENEMENT DES MANIFESTATIONS DE LA BASE (GZHI SNANG)SELON LES CONCEPTIONS DE LA GRANDE PERFECTION* Par Jean-Luc Achard (CNRS) a tradition tibétaine de la Grande Perfection (rDzogs chen)représente un courant important... ’àl’époque dynastique (8e siècle) au Tibet1. L’un des élements essentiels de sapensée consiste dans la notion de Base (gzhi) qui est la pierre angulaire desenseignements de la Grande Perfection2.Définie en tant que la “Base de l’état naturel” (gzhi’i gnas lugs) del...

  13. Mixed metallic Ba(Co,Mn)X{sub 0.2-x}O{sub 3-{delta}} (X=F, Cl) hexagonal perovskites

    SciTech Connect (OSTI)

    Iorgulescu, Mihaela; Roussel, Pascal; Tancret, Nathalie; Renaut, Nicolas; Tiercelin, Nicolas; Mentre, Olivier

    2013-02-15

    We show here that the incorporation of Mn in Ba-Co-oxohalide, BaCoX{sub 0.2-x}O{sub 3-{delta}}, hexagonal perovskite stabilizes the 6H-form (stacking sequence (chhhch Prime ); c, h=[BaO{sub 3}] and h Prime =[BaOX] layers), with tetramers of face-sharing octahedra) rather than the trimeric 10H-form. On the contrary to previous results on the Fe incorporation in similar system leading to more reduced 10H-compounds, the Mn effect is to increase the mean (Co/Mn) valence better suited to the 6H form. We experienced a poor Mn/Co miscibility during our syntheses leading to great difficulties to isolate mixed Co/Mn single phase materials and/or weak reproducibility. Powder neutron diffraction data shows a mixed Mn/Co octahedral occupancy, while the tetrahedra are filled by Co{sup 3+} cations. Anionic vacancies were refined in the h Prime -[BaO{sub 1-z}X{sub 1-x}] layer and the next c-[BaO{sub 3-z}] layers, while the h-[BaO{sub 3}] layers are not oxygen deficient. Magnetic properties suggest that a part of Mn cations remain paramagnetic until low temperature, while isolated spin clusters (probably driven by AFM Co tetrahedral dimers) behave as low-dimensional AFM systems. Transport measurements reveal a transition from high-temperature metallic to low-temperature semi-conducting states that could occur from defect shallow donor upon the Mn for Co substitution. - Graphical abstract: The incorporation of Mn in Ba-Co-oxohalide, BaCoX{sub 0.2-x}O{sub 3-{delta}}, hexagonal perovskite stabilizes the 6H-form with tetrameric (Co,Mn){sub 4}O{sub 15} face sharing linear chains. This results from a oxidizing Mn effect and particular Mn/Co distribution. Highlights: Black-Right-Pointing-Pointer The incorporation of Mn in BaCoX{sub 0.2-x}O{sub 3-{delta}} (X=F,Cl) hexagonal perovskites stabilizes the 6H-form. Black-Right-Pointing-Pointer It contains tetrameric (Co,Mn){sub 4}O{sub 15} face sharing linear chains. Black-Right-Pointing-Pointer The preference for such chains better than trimeric ones is due to the Manganese oxidizing effect. Black-Right-Pointing-Pointer A particular Mn/Co distribution was evidenced. Black-Right-Pointing-Pointer Transport and magnetic properties drastically change during the Mn incorporation.

  14. Magnetic properties of ion implanted Ge{sub 1-x}Mn{sub x} thin films solidified through pulsed laser melting

    SciTech Connect (OSTI)

    Commisso Dolph, Melissa [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Kim, Taeseok; Recht, Daniel; Aziz, Michael J. [Harvard School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States); Yin Wenjing; Fan Wenbin; Yu Jiani; Lu Jiwei [Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Wolf, Stuart A. [Department of Physics, University of Virginia, Charlottesville, Virginia 22904 (United States); Department of Materials Science and Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States)

    2011-05-01

    Ge{sub 1-x}Mn{sub x} thin films with an average Mn concentration of 0.64 at. % were fabricated through Mn ion implantation into crystalline germanium-on-insulator wafers. Implantation damage was removed and crystallinity restored by pulsed laser melting from a single 30-ns 308-nm XeCl{sup +} excimer laser pulse. Resolidified films demonstrated higher Curie temperatures but smaller saturation magnetizations than those of both as-implanted films and implanted films subjected to rapid thermal annealing. These findings are attributed to the redistribution of Mn during solidification.

  15. Observations of micro-structure and void formation in a 8% Mn stainless steel (ICL 016) irradiated with 46 MeV nickel ions

    E-Print Network [OSTI]

    Mazey, D J; Titchmarsh, J M

    1980-01-01

    Observations of micro-structure and void formation in a 8% Mn stainless steel (ICL 016) irradiated with 46 MeV nickel ions

  16. Structure and magnetic properties of Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H-polytype in the Ba-Ce-Mn-O system

    SciTech Connect (OSTI)

    Macias, Mario A.; Mentre, Olivier; Cuello, Gabriel J.; Gauthier, Gilles H.

    2013-02-15

    Based on the peculiar magnetic properties that are observed in pseudo one-dimensional manganites, we decided to synthesize the new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} compound. The preparation was performed by solid state reaction in air at about 1350 Degree-Sign C, for which we found that the compound crystallizes in a hexagonal symmetry with space group P6{sub 3}/mmc (No-194) and cell parameters a=b=5.7861(2) A and c=23.902(1) A. The structural description was correlated with neutron diffraction and bond valence calculations, confirming the presence of Ce{sup 4+} and Mn{sup 4+} segregated in the different crystallographic positions. Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} displays evidence for strong AFM couplings already set at room temperature. The main arrangement of Mn{sup 4+} in magnetically isolated tetramers of face-sharing octahedra is responsible for a metamagnetic-like transition around 50 K. - Graphical abstract: The new Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15} polytype shows strong AFM couplings in magnetically isolated [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers of face-sharing octahedral, resulting in a metamagnetic-like transition around 50 K. Highlights: Black-Right-Pointing-Pointer Ba{sub 5}Ce{sub 1.25}Mn{sub 3.75}O{sub 15}, a new 10H polytype, has been prepared in the Ba-Ce-Mn-O system. Black-Right-Pointing-Pointer The compound crystallizes in the P6{sub 3}/mmc space group with (cchhh){sub 2} stacking sequence. Black-Right-Pointing-Pointer [Ce{sub 0.25}Mn{sub 3.75}O{sub 15}] tetramers are separated by [CeO{sub 6}] octahedra in the structure. Black-Right-Pointing-Pointer Instead of robust AFM ordering, a metamagnetic-like transition is found around 50 K.

  17. The economic simulation of cotton gins in the Lower Rio Grande Valley of Texas and Tamaulipas, Mexico 

    E-Print Network [OSTI]

    White, Duboise

    1994-01-01

    , USA I A D3 Results, USA I B D4 Results, USA2 D5 Results, USA2A D6 Results. USA2B D7 Results, USA3 D8 Results, USA3A D9 Itesults, USA3B D10 Results, MEXI Dl I Results, MEXIA . D12 Results, MEXIB . 106 108 110 112 114 116 118 120 122... the United States and Mexico, 1982-1992 14 Cotton Production m the Lower Rio Grande Valley of Texas, 1983-1992 10 1 5 Study Area for Texas, the Lower Rio Grande Valley 1 6 Study Area in Mexico, Tamaulipas 12 4. 1 Total per Bale Costs for Each Gin...

  18. High H2 Storage of Hexagonal Metal-Organic Frameworks from First-Principles-Based Grand Canonical Monte Carlo Simulations

    E-Print Network [OSTI]

    Goddard III, William A.

    High H2 Storage of Hexagonal Metal-Organic Frameworks from First-Principles-Based Grand Canonical IRMOF-2-60, which we calculate to bind 9.7 wt % H2 storage at 77 K and 70 bar, the highest known value even at ambient temperatures. For example, IRMOF-2-96-Li leads to 6.0 wt % H2 storage at 273 K and 100

  19. EA-1679: Grand Coulee's Third Powerplant 500-kV Transmission Line Replacement Project, Grant and Okanogon Counties, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates potential environmental impacts from the construction and operation of six new 500-kV overhead transmission lines to replace six existing underground lines at Grand Coulee Dam. DOE’s Bonneville Power Administration (BPA), a cooperating agency, was asked by the U. S. Department of the Interior’s Bureau of Reclamation to design and construct the proposed new transmission lines. A Finding of No Significant Impact was issued by BPA in December 2011.

  20. AVTA Federal Fleet PEV Readiness Data Logging and Characterization Study for the National Park Service: Grand Canyon National Park

    SciTech Connect (OSTI)

    Stephen Schey; Jim Francfort; Ian Nienhueser

    2014-08-01

    This report focuses on the Grand Canyon National Park (GCNP) fleet to identify daily operational characteristics of select vehicles and report findings on vehicle and mission characterizations to support the successful introduction of PEVs into the agencies’ fleets. Individual observations of these selected vehicles provide the basis for recommendations related to electric vehicle adoption and whether a battery electric vehicle or plug-in hybrid electric vehicle (collectively PEVs) can fulfill the mission requirements.

  1. Study of the muon content of very high-energy EAS measured with the KASCADE-Grande observatory

    E-Print Network [OSTI]

    Arteaga-Velazquez, J C; Bekk, K; Bertaina, M; Bluemer, J; Bozdog, H; Brancus, I M; Cantoni, E; Chiavassa, A; Cossavella, F; Curcio, C; Daumiller, K; de Souza, V; Di Pierro, F; Doll, P; Engel, R; Engler, J; Fuchs, B; Fuhrmann, D; Gils, H J; Glasstetter, R; Grupen, C; Haungs, A; Heck, D; Hoerandel, J R; Huber, D; Huege, T; Kampert, K -H; Kang, D; Klages, H O; Link, K; Luczak, P; Ludwig, M; Mathes, H J; Mayer, H J; Melissas, M; Milke, J; Mitrica, B; Morello, C; Oehlschlaeger, J; Ostapchenko, S; Palmieri, N; Petcu, M; Pierog, T; Rebel, H; Roth, M; Schieler, H; Schoo, S; Schroeder, F G; Sima, O; Toma, G; Trinchero, G C; Ulrich, H; Weindl, A; Wochele, D; Wochele, J

    2013-01-01

    The KASCADE-Grande detector is an air-shower array devoted to the study of primary cosmic rays with very high-energies (E = 10^{16} - 10^{18} eV). The instrument is composed of different particle detector systems suitable for the detailed study of the properties of Extensive Air Showers (EAS) developed by cosmic rays in the atmosphere. Among the EAS observables studied with the detector, the charged number of particles, the muon content (at different energy thresholds), and the number of electrons are found. By comparing the measurements of these air-shower parameters with the expectations from MC simulations, different hadronic interaction models can be tested at the high-energy regime with the KASCADE-Grande experiment. In this work, the results of a study on the evolution of the muon content of EAS with zenith angle, performed with the KASCADE-Grande instrument, is presented. Measurements are compared with predictions from MC simulations based on the QGSJET II, QGSJET II-04, SIBYLL 2.1 and EPOS 1.99 hadron...

  2. Non-extended phase space thermodynamics of Lovelock AdS black holes in grand canonical ensemble

    E-Print Network [OSTI]

    Mo, Jie-Xiong

    2015-01-01

    Recently, extended phase space thermodynamics of Lovelock AdS black holes has been of great interest. To provide insight from a different perspective and gain a unified phase transition picture, non-extended phase space thermodynamics of $(n+1)$-dimensional charged topological Lovelock AdS black holes is investigated detailedly in the grand canonical ensemble. Specifically, the specific heat at constant electric potential is calculated and phase transition in the grand canonical ensemble is discussed. To probe the impact of the various parameters, we utilize the control variate method and solve the phase transition condition equation numerically for the case $k=1,-1$. There are two critical points for the case $n=6,k=1$ while there is only one for other cases. For $k=0$, there exists no phase transition point. To figure out the nature of phase transition in the grand canonical ensemble, we carry out an analytic check of the analog form of Ehrenfest equations proposed by Banerjee et al. It is shown that Lovelo...

  3. Large ferroelectric polarization in the new double perovskite NaLaMnWO$_{6}$ induced by non-polar instabilities

    E-Print Network [OSTI]

    Fukushima, T; Picozzi, S; Perez-Mato, J M

    2011-01-01

    Based on density functional theory calculations and group theoretical analysis, we have studied NaLaMnWO$_{6}$ compound which has been recently synthesized [Phys. Rev. B 79, 224428 (2009)] and belongs to the $AA'BB'{\\rm O}_{6}$ family of double perovskites. At low temperature, the structure has monoclinic $P2_{1}$ symmetry, with layered ordering of the Na and La ions and rocksalt ordering of Mn and W ions. The Mn atoms show an antiferromagnetic (AFM) collinear spin ordering, and the compound has been reported as a potential multiferroic. By comparing the low symmetry structure with a parent phase of $P4/nmm$ symmetry, two distortion modes are found dominant. They correspond to MnO$_{6}$ and WO$_{6}$ octahedron \\textit{tilt} modes, often found in many simple perovskites. While in the latter these common tilting instabilities yield non-polar phases, in NaLaMnWO$_{6}$ the additional presence of the $A$-$A^{'}$ cation ordering is sufficient to make these rigid unit modes as a source of the ferroelectricity. Throu...

  4. Zero-field signal in the electron paramagnetic resonance spectrum of Mn{sup +2} in silicate glasses

    SciTech Connect (OSTI)

    Rakhimov, Rakhim R. [Center for Materials Research, Norfolk State University, Norfolk, Virginia 23504 (United States)] [Center for Materials Research, Norfolk State University, Norfolk, Virginia 23504 (United States); Jones, David E. [Center for Materials Research, Norfolk State University, Norfolk, Virginia 23504 (United States)] [Center for Materials Research, Norfolk State University, Norfolk, Virginia 23504 (United States)

    2000-07-22

    A 9.4-9.8 GHz electron paramagnetic resonance (EPR) study of Mn{sup +2}-doped Na{sub 2}O-CaO-MgO-SiO{sub 2} glasses has revealed a nonresonant microwave magneto-absorption near zero magnetic field in addition to normal paramagnetic absorption due to Mn{sup +2} ions, electron spin S=5/2. The low-field response has an opposite phase relative to paramagnetic signal and is independent of the mutual orientation of the magnetic field of the microwave H{sub 1} and static magnetic field H. In contrast, the paramagnetic signal is different for perpendicular H{sub 1}(perpendicular sign)H and parallel H{sub 1}(parallel sign)H polarization of the microwave field, which is attributed to enhancement of forbidden magnetic dipolar transitions and suppression of the allowed transitions for parallel polarization. The low-field response is described in terms of microwave dielectric losses that derive from the magneto-induced charge migration in the first coordination sphere of Mn{sup +2}. As opposed to the spin-polarized tunneling that was described in ferromagnets between different valence forms of Mn, the observed effect is due to spin-dependent tunneling that occurs in the vicinity of Mn{sup +2} in a diluted paramagnetic system. (c) 2000 American Institute of Physics.

  5. Resident Fish Stock above Chief Joseph and Grand Coulee Dams; 2003-2004 Annual Report.

    SciTech Connect (OSTI)

    Connor, Jason M.; McLellan, Jason G.; Butler, Chris

    2005-11-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power and Conservation Council (NPCC), formerly the Northwest Power Planning Council. The NPCC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPCC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial and native fish assemblages in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area. The initial year of the project (1997) identified the need for a central data storage and analysis facility, coordination with the StreamNet project, compilation of Blocked Area fisheries information, and a report on the ecological condition of the Spokane River System. These needs were addressed in 1998 by acquiring a central location with a data storage and analysis system, coordinating a pilot project with StreamNet, compiling fisheries distribution data throughout the Blocked Area, identifying data gaps based on compiled information, and researching the ecological condition of the Spokane River. In order to ensure that any additional information collected throughout the life of this project will be easily stored and manipulated by the central storage facility, it was necessary to develop standardized methodologies between the JSAP fisheries managers. Common collection and analytical methodologies were developed in 1999. The project began addressing identified data gaps throughout the Blocked Area in 1999. Data collection of established projects and a variety of newly developed sampling projects are ongoing. Projects developed and undertaken by JSAP fisheries managers include investigations of the Pend Orielle River and its tributaries, the Little Spokane River and its tributaries, and water bodies within and near the Spokane Indian Reservation. Migration patterns of adfluvial and reservoir fish in Box Canyon Reservoir and its tributaries, a baseline assessment of Boundary Reservoir and its tributaries, ecological assessment of mountain lakes in Pend Oreille County, and assessments of streams and lakes on the Spokane Indian Reservation were completed by 2001. Assessments of the Little Spokane River and its tributaries, Spokane River below Spokane Falls, tributaries to the Pend Oreille River, small lakes in Pend Oreille County, WA, and water bodies within and near the Spokane Indian Reservation were conducted in 2002 and 2003. This work was done in accordance with the scope of work approved by Bonneville Power Administration (BPA).

  6. Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams; 2002-2003 Annual Report.

    SciTech Connect (OSTI)

    Connor, Jason M.; McLellan, Jason G.; Butler, Chris

    2006-02-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power and Conservation Council (NPCC), formerly the Northwest Power Planning Council. The NPCC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPCC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial and native fish assemblages in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area. The initial year of the project (1997) identified the need for a central data storage and analysis facility, coordination with the StreamNet project, compilation of Blocked Area fisheries information, and a report on the ecological condition of the Spokane River System. These needs were addressed in 1998 by acquiring a central location with a data storage and analysis system, coordinating a pilot project with StreamNet, compiling fisheries distribution data throughout the Blocked Area, identifying data gaps based on compiled information, and researching the ecological condition of the Spokane River. In order to ensure that any additional information collected throughout the life of this project will be easily stored and manipulated by the central storage facility, it was necessary to develop standardized methodologies between the JSAP fisheries managers. Common collection and analytical methodologies were developed in 1999. The project began addressing identified data gaps throughout the Blocked Area in 1999. Data collection of established projects and a variety of newly developed sampling projects are ongoing. Projects developed and undertaken by JSAP fisheries managers include investigations of the Pend Orielle River and its tributaries, the Little Spokane River and its tributaries, and water bodies within and near the Spokane Indian Reservation. Migration patterns of adfluvial and reservoir fish in Box Canyon Reservoir and its tributaries, a baseline assessment of Boundary Reservoir and its tributaries, ecological assessment of mountain lakes in Pend Oreille County, and assessments of streams and lakes on the Spokane Indian Reservation were completed by 2001. Assessments of the Little Spokane River and its tributaries, Spokane River below Spokane Falls, tributaries to the Pend Oreille River, small lakes in Pend Oreille County, WA, and water bodies within and near the Spokane Indian Reservation were conducted in 2002 and 2003. This work was done in accordance with the scope of work approved by Bonneville Power Administration (BPA).

  7. Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams; 2001 Annual Report.

    SciTech Connect (OSTI)

    Connor, Jason M.; McLellan, Jason G.; O'Connor, Dick

    2003-01-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power Planning Council (NPPC). The NPPC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPPC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial fish assemblages and native fish in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area and the Columbia Basin Blocked Area Management Plan (1998). The initial year of the project (1997) identified the need for a central data storage and analysis facility, coordination with the StreamNet project, compilation of Blocked Area fisheries information, and a report on the ecological condition of the Spokane River System. These needs were addressed in 1998 by acquiring a central location with a data storage and analysis system, coordinating a pilot project with StreamNet, compiling fisheries distribution data throughout the Blocked Area, identifying data gaps based on compiled information, and researching the ecological condition of the Spokane River. In order to ensure that any additional information collected throughout the life of this project will be easily stored and manipulated by the central storage facility, it was necessary to develop standardized methodologies between the JSAP fisheries managers. Common collection and analytical methodologies were developed in 1999. In 1999, 2000, and 2001 the project began addressing some of the identified data gaps throughout the Blocked Area. Data collection of established projects and a variety of newly developed sampling projects are ongoing. Projects developed and undertaken by JSAP fisheries managers include investigations of the Pend Orielle River and its tributaries, the Little Spokane River and its tributaries, and water bodies within and near the Spokane Indian Reservation. Migration patterns of adfluvial and reservoir fish in Box Canyon Reservoir and its tributaries, a baseline assessment of Boundary Reservoir and its tributaries, ecological assessment of mountain lakes in Pend Oreille County, and assessments of seven streams and four lakes on the Spokane Indian Reservation were completed by 2000. Assessments of the Little Spokane River and its tributaries, tributaries to the Pend Oreille River, small lakes in southern Pend Oreille County, and water bodies within and near the Spokane Indian Reservation were conducted in 2001. This work was done in accordance with the scope of work approved by Bonneville Power Administration (BPA).

  8. Resident Fish Stock above Chief Joseph and Grand Coulee Dams; 2002 Annual Report.

    SciTech Connect (OSTI)

    Connor, Jason M.; McLellan, Jason G.; Butler, Chris

    2003-09-01

    In 1980, the United States Congress enacted the Northwest Power Planning and Conservation Act (PL 96-501, 1980), which established the Northwest Power and Conservation Council (NPCC), formerly the Northwest Power Planning Council. The NPCC was directed by Congress to develop a regional Power Plan and also the Columbia River Basin Fish and Wildlife Program (FWP) to restore or replace losses of fish caused by construction and operation of hydroelectric dams in the Columbia River Basin. In developing the FWP, Congress specifically directed NPCC to solicit recommendations for measures to be included in the Program from the region's fish and wildlife agencies and Indian tribes. All measures adopted by the Council were also required to be consistent with the management objectives of the agencies and tribes [Section 4.(h)(6)(A)], the legal rights of Indian tribes in the region [Section 4.(h)(6)(D)] and be based upon and supported by the best available scientific knowledge [Section 4.(h)(6)(B)]. The Resident Fish Stock Status above Chief Joseph and Grand Coulee Dams Project, also known as the Joint Stock Assessment Project (JSAP) specifically addresses NPPC Council measure 10.8B.26 of the 1994 program. The Joint Stock Assessment Project is a management tool using ecosystem principles to manage artificial fish assemblages and native fish in altered environments existing in the Columbia River System above Chief Joseph and Grand Coulee Dams (Blocked Area). A three-phase approach of this project will enhance the fisheries resources of the Blocked Area by identifying data gaps, filling data gaps with research, and implementing management recommendations based on research results. The Blocked Area fisheries information is housed in a central location, allowing managers to view the entire system while making decisions, rather than basing management decisions on isolated portions of the system. The JSAP is designed and guided jointly by fisheries managers in the Blocked Area. The initial year of the project (1997) identified the need for a central data storage and analysis facility, coordination with the StreamNet project, compilation of Blocked Area fisheries information, and a report on the ecological condition of the Spokane River System. These needs were addressed in 1998 by acquiring a central location with a data storage and analysis system, coordinating a pilot project with StreamNet, compiling fisheries distribution data throughout the Blocked Area, identifying data gaps based on compiled information, and researching the ecological condition of the Spokane River. In order to ensure that any additional information collected throughout the life of this project will be easily stored and manipulated by the central storage facility, it was necessary to develop standardized methodologies between the JSAP fisheries managers. Common collection and analytical methodologies were developed in 1999. In 1999, 2000, and 2001 the project began addressing some of the identified data gaps throughout the Blocked Area. Data collection of established projects and a variety of newly developed sampling projects are ongoing. Projects developed and undertaken by JSAP fisheries managers include investigations of the Pend Orielle River and its tributaries, the Little Spokane River and its tributaries, and water bodies within and near the Spokane Indian Reservation. Migration patterns of adfluvial and reservoir fish in Box Canyon Reservoir and its tributaries, a baseline assessment of Boundary Reservoir and its tributaries, ecological assessment of mountain lakes in Pend Oreille County, and assessments of streams and lakes on the Spokane Indian Reservation were completed by 2001. Assessments of the Little Spokane River and its tributaries, tributaries to the Pend Oreille River, small lakes in Pend Oreille County, WA, and water bodies within and near the Spokane Indian Reservation were conducted in 2002. This work was done in accordance with the scope of work approved by Bonneville Power Administration (BPA).

  9. Structural and Chemical Evolution of Li- and Mn-rich Layered Cathode Material

    SciTech Connect (OSTI)

    Zheng, Jianming; Xu, Pinghong; Gu, Meng; Xiao, Jie; Browning, Nigel D.; Yan, Pengfei; Wang, Chong M.; Zhang, Jiguang

    2015-02-24

    Lithium (Li)- and manganese-rich (LMR) layered-structure materials are very promising cathodes for high energy density lithium-ion batteries. However, their voltage fading mechanism and its relationships with fundamental structural changes are far from being sufficiently understood. Here we report the detailed phase transformation pathway in the LMR cathode (Li[Li0.2Ni0.2Mn0.6]O2) during cycling for the samples prepared by hydro-thermal assistant method. It is found the transformation pathway of LMR cathode is closely correlated to its initial structure and preparation conditions. The results reveal that LMR cathode prepared by HA approach experiences a phase transformation from the layered structure to a LT-LiCoO2 type defect spinel-like structure (Fd-3m space group) and then to a disordered rock-salt structure (Fm-3m space group). The voltage fade can be well correlated with the Li ion insertion into octahedral sites, rather than tetrahedral sites, in both defect spinel-like structure and disordered rock-salt structure. The reversible Li insertion/removal into/from the disordered rock-salt structure is ascribed to the Li excess environment that can satisfy the Li percolating in the disordered rock-salt structure despite the increased kinetic barrier. Meanwhile, because of the presence of a great amount of oxygen vacancies, a significant decrease of Mn valence is detected in the cycled particle, which is below that anticipated for a potentially damaging Jahn-Teller distortion (+3.5). Clarification of the phase transformation pathway, cation redistribution, oxygen vacancy and Mn valence change undoubtedly provides insights into a profound understanding on the voltage fade, and capacity degradation of LMR cathode. The results also inspire us to further enhance the reversibility of LMR cathode via improving its surface structural stability.

  10. An Overview of Operational Characteristics of Selected Irrigation Districts in the Texas Lower Rio Grande Valley: Harlingen Irrigation District Cameron County No. 1 

    E-Print Network [OSTI]

    Wolfe, Clint D.; Stubbs, Megan J.; Rister, M. Edward; Sturdivant, Allen W.; Lacewell, Ronald D.; Pennington, Ellen L.; Rogers, Callie S.

    2007-01-01

    Population expansion and water shortfalls have placed the Texas Lower Rio Grande Valley (Valley) center stage in water publicity. The unique characteristics and lack of public knowledge on how irrigation districts divert and convey water from...

  11. A faunal survey and zoogeographic analysis of the Circulionoidea (Coleoptera) (excluding Anthribidae, Platypodinae, and Scolytinae) of the Lower Rio Grande Valley of Texas 

    E-Print Network [OSTI]

    Carlow, Tami Anne

    1997-01-01

    An annotated list of the Curculionoidea (Coleoptera) (excluding Anthribidae, Platypodinae, and Scolytinae) is presented for the Lower Rio Grande Valley (LRGV) of Texas. The list includes species that occur in Cameron, ...

  12. P450 aromatase alterations and DNA damage as avian pollution biomarkers in cliff and cave swallow breeding near the Rio Grande region, Texas 

    E-Print Network [OSTI]

    Sitzlar, Megan Annette

    2006-04-12

    populations lacking proper water and sewage infrastructure. Cliff (Petrochelidon pyrrhonota) and cave (P. fulva) swallows breeding near the Rio Grande were selected to monitor aromatase activity alterations and DNA damage. Swallows were sampled at six sites...

  13. Neutron structural characterization, inversion degree and transport properties of NiMn{sub 2}O{sub 4} spinel prepared by the hydroxide route

    SciTech Connect (OSTI)

    Sagua, A.; Lescano, Gabriela M.; Alonso, J.A.; Martínez-Coronado, R.; Fernández-Díaz, M.T.; Morán, E.

    2012-06-15

    Graphical abstract: A pure specimen has been synthesized by the hydroxide route. This spinel, studied by NPD, shows an important inversion degree, ? = 0.80. A bond-valence study shows that the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected 3+ and 2+ values, respectively. The mixed valence Mn{sup 3+}/Mn{sup 4+} accounts for a hopping mechanism between adjacent octahedral sites, leading to a significant conductivity. Highlights: ? A low-temperature hydroxide route allowed preparing almost pure specimens of NiMn{sub 2}O{sub 4}. ? NPD essential to determine inversion degree; contrasting Ni and Mn for neutrons. ? Bond valence establishes valence state of octahedral and tetrahedral Ni and Mn ions. ? Thermal analysis, transport measurements complement characterization of this oxide. ? A structure–properties relationship is established. -- Abstract: The title compound has been synthesized by the hydroxide route. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3{sup ¯}m, Z = 8, with a = 8.3940(2) ? at 295 K. The crystallographic formula is (Ni{sub 0.202(1)}Mn{sub 0.798(1)}){sub 8a}(Ni{sub 0.790(1)}Mn{sub 1.210(1)}){sub 16d}O{sub 4} where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively. There is a significant inversion degree of the spinel structure, ? = 0.80. In fact, the variable parameter for the oxygen position, u = 0.2636(4), is far from that expected (u = 0.25) for normal spinels. From a bond-valence study, it seems that the valence distribution in NiMn{sub 2}O{sub 4} spinel is not as trivial as expected (Ni{sup 2+} and Mn{sup 3+}), but clearly the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected +3 and +2 values, respectively. The mixed valence observed at the octahedral sites provides the charge carriers that, by a hopping mechanism between Mn{sup 3+}/Mn{sup 4+} adjacent sites, leads to a significant conductivity, up to 0.85 S cm{sup ?1} at 800 °C in air.

  14. Steam Dryer Segmentation and Packaging at Grand Gulf Nuclear Station - 13577

    SciTech Connect (OSTI)

    Kreitman, Paul J.; Sirianni, Steve R.; Pillard, Mark M.

    2013-07-01

    Entergy recently performed an Extended Power Up-rate (EPU) on their Grand Gulf Nuclear Station, near Port Gibson, Mississippi. To support the EPU, a new Steam Dryer Assembly was installed during the last refueling outage. Due to limited access into the containment, the large Replacement Steam Dryer (RSD) had to be brought into the containment in pieces and then final assembly was completed on the refueling floor before installation into the reactor. Likewise, the highly contaminated Original Steam Dryer (OSD) had to be segmented into manageable sections, loaded into specially designed shielded containers, and rigged out of containment where they will be safely stored until final disposal is accomplished at an acceptable waste repository. Westinghouse Nuclear Services was contracted by Entergy to segment, package and remove the OSD from containment. This work was performed on critical path during the most recent refueling outage. The segmentation was performed underwater to minimize radiation exposure to the workers. Special hydraulic saws were developed for the cutting operations based on Westinghouse designs previously used in Sweden to segment ABB Reactor Internals. The mechanical cutting method was selected because of its proven reliability and the minimal cutting debris that is generated by the process. Maintaining stability of the large OSD sections during cutting was accomplished using a custom built support stand that was installed into the Moisture Separator Pool after the Moisture Separator was installed back in the reactor vessel. The OSD was then moved from the Steam Dryer Pool to the Moisture Separator Pool for segmentation. This scenario resolved the logistical challenge of having two steam dryers and a moisture separator in containment simultaneously. A water filtration/vacuum unit was supplied to maintain water clarity during the cutting and handling operations and to collect the cutting chips. (authors)

  15. Annotated bibliography for the humpback chub (Gila cypha) with emphasis on the Grand Canyon population.

    SciTech Connect (OSTI)

    Goulet, C. T.; LaGory, K. E.; Environmental Science Division

    2009-10-05

    Glen Canyon Dam is a hydroelectric facility located on the Colorado River in Arizona that is operated by the U.S. Bureau of Reclamation (Reclamation) for multiple purposes including water storage, flood control, power generation, recreation, and enhancement of fish and wildlife. Glen Canyon Dam operations have been managed for the last several years to improve conditions for the humpback chub (Gila cypha) and other ecosystem components. An extensive amount of literature has been produced on the humpback chub. We developed this annotated bibliography to assist managers and researchers in the Grand Canyon as they perform assessments, refine management strategies, and develop new studies to examine the factors affecting humpback chub. The U.S. Geological Survey recently created a multispecies bibliography (including references on the humpback chub) entitled Bibliography of Native Colorado River Big Fishes (available at www.fort.usgs.gov/Products/data/COFishBib). That bibliography, while quite extensive and broader in scope than ours, is not annotated, and, therefore, does not provide any of the information in the original literature. In developing this annotated bibliography, we have attempted to assemble abstracts from relevant published literature. We present here abstracts taken unmodified from individual reports and articles except where noted. The bibliography spans references from 1976 to 2009 and is organized in five broad topical areas, including: (1) biology, (2) ecology, (3) impacts of dam operations, (4) other impacts, and (5) conservation and management, and includes twenty subcategories. Within each subcategory, we present abstracts alphabetically by author and chronologically by year. We present relevant articles not specific to either the humpback chub or Glen Canyon Dam, but cited in other included reports, under the Supporting Articles subcategory. We provide all citations in alphabetical order in Section 7.

  16. LiMn{sub 2}O{sub 4} nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries

    SciTech Connect (OSTI)

    Lin, Binghui; Yin, Qing; Hu, Hengrun; Lu, Fujia [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Xia, Hui, E-mail: xiahui@njust.edu.cn [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2014-01-15

    Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite has been successfully synthesized by a one-step hydrothermal method without post-heat treatment. In the nanocomposite, LiMn{sub 2}O{sub 4} nanoparticles of 10–30 nm in size are well crystallized and homogeneously anchored on the graphene nanosheets. The graphene nanosheets not only provide a highly conductive matrix for LiMn{sub 2}O{sub 4} nanoparticles but also effectively reduce the agglomeration of LiMn{sub 2}O{sub 4} nanoparticles. The nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite exhibited greatly improved electrochemical performance in terms of specific capacity, cycle performance, and rate capability compared with the bare LiMn{sub 2}O{sub 4} nanoparticles. The superior electrochemical performance of the nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite makes it promising as cathode material for high-performance lithium-ion batteries. - Graphical abstract: Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets (GNS) nanocomposite exhibit superior cathode performance for lithium-ion batteries compared to the bare LiMn{sub 2}O{sub 4} nanoparticles. Display Omitted - Highlights: • LiMn{sub 2}O{sub 4}/graphene nanocomposite is synthesized by a one-step hydrothermal method. • LiMn{sub 2}O{sub 4} nanoparticles are uniformly anchored on the graphene nanosheets. • The nanocomposite exhibits excellent cathode performance for lithium-ion batteries.

  17. Chemical spots and their dynamical evolution on HgMn stars

    E-Print Network [OSTI]

    Korhonen, Heidi; Briquet, Maryline; Gonzalez, Federico; Savanov, Igor

    2010-01-01

    Our recent studies of late B-type stars with HgMn peculiarity revealed for the first time the presence of fast dynamical evolution of chemical spots on their surfaces. These observations suggest a hitherto unknown physical process operating in the stars with radiative outer envelopes. Furthermore, we have also discovered existence of magnetic fields on these stars that have up to now been thought to be non-magnetic. Here we will discuss the dynamical spot evolution on HD 11753 and our new results on magnetic fields on AR Aur.

  18. Reactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)Oxide-Water Interface

    E-Print Network [OSTI]

    Sparks, Donald L.

    A T O C H A , * , E V E R T J . E L Z I N G A , A N D D O N A L D L . S P A R K S DepartmentReactivity of Pb(II) at the Mn(III,IV) (Oxyhydr)Oxide-Water Interface C H R I S T O P H E R J . M and surface functional groups on R-Al2O3 depending on the specific surface site exposed. The uptake of Pb

  19. Conductance with stochastic resonance in Mn{sub 12} redox network without tuning

    SciTech Connect (OSTI)

    Hirano, Yoshiaki [Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043 (Japan); Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507 (Japan); Segawa, Yuji; Kawai, Tomoji [Institute of Scientific and Industrial Research (ISIR), Osaka University, 8-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan); Kuroda-Sowa, Takayoshi [Department of Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502 (Japan); Matsumoto, Takuya, E-mail: matsumoto-t@chem.sci.osaka-u.ac.jp [Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043 (Japan)

    2014-06-09

    Artificial neuron-based information processing is one of the attractive approaches of molecular-scale electronics, which can exploit the ability of molecular system for self-assembling or self-organization. The self-organized Mn{sub 12}/DNA redox network shows nonlinear current-voltage characteristics that can be described by the Coulomb blockade network model. As a demonstration of the nonlinear network system, we have observed stochastic resonance without tuning for weak periodic input signals and thermal noise, which suggests a route to neural network composed of molecular materials.

  20. Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}

    SciTech Connect (OSTI)

    Giot, Maud; Chapon, Laurent C.; Radaelli, Paolo G.; Androulakis, John; Lappas, Alexandros; Green, Mark A.

    2007-12-14

    The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

  1. Magnetic domain wall manipulation in (Ga,Mn)As nanostructures for spintronic applications

    SciTech Connect (OSTI)

    Wosinski, Tadeusz; Andrearczyk, Tomasz; Figielski, Tadeusz; Olender, Karolina; Wrobel, Jerzy

    2014-02-21

    Ring-shaped nanostructures have been designed and fabricated by electron-beam lithography patterning and chemical etching from thin epitaxial layers of the ferromagnetic semiconductor (Ga,Mn)As. The nanostructures, in a form of planar rings with a slit, were supplied with four electrical terminals and subjected to magneto-transport studies under planar weak magnetic field. Magnetoresistive effects caused by manipulation of magnetic domain walls and magnetization reversal in the nanostructures have been investigated and possible applications of the nanostructures as four-terminal spintronic devices are discussed.

  2. Elastic Constants of Ni-Mn-Ga Magnetic Shape Memory Alloys

    SciTech Connect (OSTI)

    Stipcich, M. [Universitat de Barcelona; Manosa, L. [Universitat de Barcelona; Planes, A. [Universitat de Barcelona; Morin, M. [INSA de Lyon; Zarestky, Jerel L [ORNL; Lograsso, Tom [Ames Laboratory; Stassis, C. [Ames Laboratory

    2004-01-01

    We have measured the adiabatic second order elastic constants of two Ni-Mn-Ga magnetic shape memory crystals with different martensitic transition temperatures, using ultrasonic methods. The temperature dependence of the elastic constants has been followed across the ferromagnetic transition and down to the martensitic transition temperature. Within experimental errors no noticeable change in any of the elastic constants has been observed at the Curie point. The temperature dependence of the shear elastic constant C' has been found to be very different for the two alloys. Such a different behavior is in agreement with recent theoretical predictions for systems undergoing multi-stage structural transitions.

  3. Generation and control of spin-polarized photocurrents in GaMnAs heterostructures

    SciTech Connect (OSTI)

    Bezerra, Anibal T. Farinas, Paulo F.; Studart, Nelson; Degani, Marcos H.; Maialle, Marcelo Z.

    2014-01-13

    Photocurrents are calculated for a specially designed GaMnAs semiconductor heterostructure. The results reveal regions in the infrared range of the energy spectrum, in which the proposed structure is remarkably spin-selective. For such photon energies, the generated photocurrents are strongly spin-polarized. Application of a relatively small static bias in the growth direction of the structure is predicted to efficiently reverse the spin-polarization for some photon energies. This behavior suggests the possibility of conveniently simple switching mechanisms. The physics underlying the results is studied and understood in terms of the spin-dependent properties emerging from the particular potential profile of the structure.

  4. Magnetic and transport properties of Mn{sub 2}CoAl oriented films

    SciTech Connect (OSTI)

    Jamer, Michelle E.; Assaf, Badih A.; Devakul, Trithep; Heiman, Don

    2013-09-30

    The structure, magnetic, and transport properties of thin films of the Heusler ferrimagnet Mn{sub 2}CoAl have been investigated for properties related to spin gapless semiconductors. Oriented films were grown by molecular beam epitaxy on GaAs substrates and the structure was found to transform from tetragonal to cubic for increasing annealing temperature. The anomalous Hall resistivity is found to be proportional to the square of the longitudinal resistivity and magnetization expected for a topological Berry curvature origin. A delicate balance of the spin-polarized carrier type when coupled with voltage gate-tuning could significantly impact advanced electronic devices.

  5. Magnetocrystalline Anisotropy in UMn2Ge2 and Related Mn-based Actinide Ferromagnets

    SciTech Connect (OSTI)

    Parker, David S; Mandrus, D.; Ghimire, N J; Baumbach, Ryan; Singleton, John; Thompson, J.D.; Bauer, Eric D.; Li, Ling; Singh, David J

    2015-01-01

    We present magnetization isotherms in pulsed magnetic fields up to 62 Tesla, supported by first principles calculations, demonstrating a huge uniaxial magnetocrystalline anisotropy energy - approximately 20 MJ/m3 - in UMn2Ge2. This large anisotropy results from the extremely strong spin-orbit coupling affecting the uranium 5 f electrons, which in the calculations exhibit a substantial orbital moment exceeding 2 Bohr magnetons. We also find from theoretical calculations that a number of isostructural Mn-actinide compounds are expected to have similarly large anisotropy.

  6. File:USDA-CE-Production-GIFmaps-MN.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View New Pages RecentTempCampApplicationWorksheet 2011.pdf JumpTransmissionKY.pdf JumpMN.pdf Jump

  7. Electrochemical Performances of LiMnPO4 Synthesized from Non-Stoichiometric

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street Lighting Host Site:ERDACarlo-integratedLi/Mn

  8. Calculations of structural, elastic, electronic, magnetic and phonon properties of FeNiMnAl by the first principles

    SciTech Connect (OSTI)

    U?ur, ?ule; ?yigör, Ahmet

    2014-10-06

    The electronic, elastic and dynamical properties of the quaternary alloy FeNiMnAl have been investigated using a pseudopotential plane wave method within the generalized gradient approximation (GGA). We determined the lattice parameters and the bulk modulus B. In addition, the elastic properties such as elastic constans (C{sub 11}, C{sub 12} and C{sub 44}), the shear modulus G, the young modulus E, the poisson's ratio ? and the B/G ratio are also given. The FeNiMnAl Heusler alloy exhibit a ferromagnetic half-metallic behavior with the total magnetic moment of 4.02 ?{sub B}. The phonon dispersion of FeNiMnAl has been performed using the density functional theory and the direct method with 2×2×2 supercell.

  9. Depth-dependent magnetism in epitaxial MnSb thin films: effects of surface passivation and cleaning

    SciTech Connect (OSTI)

    Aldous J. D.; Sanchez-Hanke C.; Burrows, C.W.; Maskery, I.; Brewer, M.S.; Hase, T.P.A.; Duffy, J.A.; Lees, M. Rs; Decoster, T.; Theis, W.; Quesada, A.; Schmid, A.K.; Bell, G.R.

    2012-03-15

    Depth-dependent magnetism in MnSb(0001) epitaxial films has been studied by combining experimental methods with different surface specificities: polarized neutron reflectivity, x-ray magnetic circular dichroism (XMCD), x-ray resonant magnetic scattering and spin-polarized low energy electron microscopy (SPLEEM). A native oxide {approx}4.5 nm thick covers air-exposed samples which increases the film's coercivity. HCl etching efficiently removes this oxide and in situ surface treatment of etched samples enables surface magnetic contrast to be observed in SPLEEM. A thin Sb capping layer prevents oxidation and preserves ferromagnetism throughout the MnSb film. The interpretation of Mn L{sub 3,2} edge XMCD data is discussed.

  10. Structural and Functional Characterization of Redox Mn and Co Sites in AlPO Materials and Their Role in Alkane Oxidation Catalysis

    E-Print Network [OSTI]

    Iglesia, Enrique

    and at similar rates, indicating excellent agreement between these techniques. No H2O or CO2 were detected during could be accurately described by Arrhenius-type behavior, and H2/Me ratios showed that only a fraction of all Me cations undergo reversible redox cycles. This fraction was 0.86 for MnAPO-18 (atomic Mn/P ) 0

  11. Weisman Art Museum | 333 East River Road | Minneapolis, MN 55455 | P: 612.625.9494 | F: 612.625.9630 | WAM.UMN.EDU FOR IMMEDIATE RELEASE

    E-Print Network [OSTI]

    Thomas, David D.

    Weisman Art Museum | 333 East River Road | Minneapolis, MN 55455 | P: 612.625.9494 | F: 612@umn.edu Weisman Art Museum presents stories of hope in The Youth/Dhallinyarada Exhibition dates: July 13, 2013 through February 9, 2014 Minneapolis, MN ­ The Weisman Art Museum at the University of Minnesota, presents

  12. Spin polarization of a Ferromagnetic Narrow Gap p-(In,Mn)As Obtained from Andreev Reflection Spectroscopy

    SciTech Connect (OSTI)

    Akazaki, T. [NTT Basic Research Laboratories, NTT Corporation, 3-1 Morinosato-Wakamiya, Atsugi, Kanagawa, 243-0198 (Japan); Munekata, H. [Imaging Science and Engineering Laboratory, Tokyo Institute of Technology, 425-R2-57 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan); Yokoyama, T. [Dept. Physics, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo, 152-8550 (Japan); Tanaka, Y. [Dept. Applied Physics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, 464-8603 (Japan); Takayanagi, H. [Research Institute for Science and Technology, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo, 162-8601 (Japan); International Center for Materials Nanoarchitectronics, NIMS (Japan)

    2011-12-26

    Spin-polarized carrier transport across Nb/p-(In,Mn)As junctions has been studied. Suppressions of conductance in the superconductor sub-gap region and conductance peaks at the bias voltage around the edge of the sub-gap are observed. These features are well reproduced by a newly modified BTK model including both spin polarization and the inverse proximity effect. The value of spin polarization in p-(In,Mn)As extracted by the calculation is P = 0.725 at 0.5 K with Z = 0.25.

  13. Thermochemical generation of hydrogen and oxygen from water. [NaMnO/sub 2/ and TiO/sub 2/

    DOE Patents [OSTI]

    Robinson, P.R.; Bamberger, C.E.

    1980-02-08

    A thermochemical cyclic process for the production of hydrogen exploits the reaction between sodium manganate (NaMnO/sub 2/) and titanium dioxide (TiO/sub 2/) to form sodium titanate (Na/sub 2/TiO/sub 3/), manganese (II) titanate (MnTiO/sub 3/) and oxygen. The titanate mixture is treated with sodium hydroxide, in the presence of steam, to form sodium titanate, sodium manganate (III), water and hydrogen. The sodium titanate-manganate (III) mixture is treated with water to form sodium manganate (III), titanium dioxide and sodium hydroxide. Sodium manganate (III) and titanium dioxide are recycled following dissolution of sodium hydroxide in water.

  14. Variation of the Mn I 539.4 nm line with the solar cycle

    E-Print Network [OSTI]

    Danilovic, S; Livingston, W; Krivova, N; Vince, I

    2015-01-01

    As a part of the long-term program at Kitt Peak National Observatory (KPNO), the Mn I 539.4 nm line has been observed for nearly three solar cycles using the McMath telescope and the 13.5 m spectrograph in double-pass mode. These full-disk spectrophotometric observations revealed an unusually strong change of this line's parameters over the solar cycle. Optical pumping by the Mg II k line was originally proposed to explain these variations. More recent studies have proposed that this is not required and that the magnetic variability might explain it. Magnetic variability is also the mechanism that drives the changes in total solar irradiance variations (TSI). With this work we investigate this proposition quantitatively by using using the model SATIRE-S. We applied exactly the same model atmospheres and value of the free parameter as were used in previous solar irradiance reconstructions to now model the variation in the Mn I 539.4 nm line profile and in neighboring Fe I lines. We compared the results of the ...

  15. Durability of (Pr0.7sr0.3)Mn03 +/-delta/8ysz

    SciTech Connect (OSTI)

    An, Ke [ORNL; Reifsnider, K L [University of Connecticut, Storrs; Gao, C Y [University of Tennessee, Knoxville (UTK)

    2006-01-01

    Half cell SOFCs with Durability of (Pr{sub 0.7}Sr{sub 0.3})Mn0{sub 3}{+-}{delta}/8YSZ composite cathodes on 8YSZ electrolytes were aged up to 1000 h at 1000 C in air with/without 0.318 A cm{sup -2} cathodic polarization. During the aging, the performance of the half cell SOFCs was measured using electrochemical impedance spectroscopy (EIS). After aging, the surface of the composite cathode and the interface between the composite cathode and the electrolyte was investigated with scanning electron microscopy (SEM). Chemical element analysis was performed with energy dispersive X-ray spectroscopy (EDS). The performance of the half cell SOFCs degraded after aging with/without polarization compared to the initial state. The SOFCs had a larger polarization resistance after 1000 h of aging. The cathodic current was shown to have an impact on the performance by slowing down the rate of decrease of polarization resistance of the SOFCs. After aging, the microstructural properties--mean pore size increased and cumulative pore volume decreased, and growth of grains was found on the Durability of (Pr{sub 0.7}Sr{sub 0.3})Mn0{sub 3}{+-}{delta} phases.

  16. Electronic and magnetic properties of double perovskite Dy{sub 2}MnCoO{sub 6} by first-principles calculation

    SciTech Connect (OSTI)

    Ganeshraj, C.; Santhosh, P. N.

    2014-05-07

    Using first-principles calculation, we investigate electronic and magnetic properties of Dy{sub 2}MnCoO{sub 6}. A detailed structural optimization has been done and found that the orthorhombic structure with Mn (Co) ions aligning along the longest axis type is the most stable structure. Within the generalized gradient approximation, the spin polarized calculations predict Dy{sub 2}MnCoO{sub 6} to be a half-metallic with ferromagnetic interaction between Mn and Co ions and antiferromagnetic interaction between Dy and Mn/Co ions. We also investigate the effect of Hubbard parameter (U) on the ground state magnetic structure. For all values of Hubbard U parameter the Co ions have nonzero magnetic moment; they do not lie in low-spin state, as in DyCoO{sub 3}.

  17. Electrochemically induced deposition method to prepare {gamma}-MnO{sub 2}/multi-walled carbon nanotube composites as electrode material in supercapacitors

    SciTech Connect (OSTI)

    Fan Zhen

    2008-08-04

    The {gamma}-MnO{sub 2}/multi-walled carbon nanotube ({gamma}-MnO{sub 2}/MWNT) composite has been prepared by electrochemically induced deposition method. The morphology and crystal structure of the composite were investigated by X-ray diffraction and scanning electron microscopy, respectively. The capacitive properties of the {gamma}-MnO{sub 2}/MWNT composite have been investigated by cyclic voltammetry (CV). A specific capacitance (based on {gamma}-MnO{sub 2}) as high as 579 F g{sup -1} is obtained at a scan rate of 10 mV s{sup -1} in 0.1 M Na{sub 2}SO{sub 4} aqueous solution. Additionally, the {gamma}-MnO{sub 2}/MWNT composite electrode shows excellent long-term cycle stability (only 2.4% decrease of the specific capacitance is observed after 500 CV cycles)

  18. Radiation-induced instability of MnS precipitates and its possible consequences on irradiation-induced stress corrosion cracking of austenitic stainless steels

    SciTech Connect (OSTI)

    Chung, H.M.; Sanecki, J.E.; Garner, F.A.

    1996-12-01

    Irradiation-assisted stress corrosion cracking (IASCC) is a significant materials issue for the light water reactor (LWR) industry and may also pose a problem for fusion power reactors that will use water as coolant. A new metallurgical process is proposed that involves the radiation-induced release into solution of minor impurity elements not usually thought to participate in IASCC. MnS-type precipitates, which contain most of the sulfur in stainless steels, are thought to be unstable under irradiation. First, Mn transmutes strongly to Fe in thermalized neutron spectra. Second, cascade-induced disordering and the inverse Kirkendall effect operating at the incoherent interfaces of MnS precipitates are thought to act as a pump to export Mn from the precipitate into the alloy matrix. Both of these processes will most likely allow sulfur, which is known to exert a deleterious influence on intergranular cracking, to re-enter the matrix. To test this hypothesis, compositions of MnS-type precipitates contained in several unirradiated and irradiated heats of Type 304, 316, and 348 stainless steels (SSs) were analyzed by Auger electron spectroscopy. Evidence is presented that shows a progressive compositional modification of MnS precipitates as exposure to neutrons increases in boiling water reactors. As the fluence increases, the Mn level in MnS decreases, whereas the Fe level increases. The S level also decreases relative to the combined level of Mn and Fe. MnS precipitates were also found to be a reservoir of other deleterious impurities such as F and O which could be also released due to radiation-induced instability of the precipitates.

  19. Cross-plane electronic and thermal transport properties of p-type La0.67Sr0.33MnO3/LaMnO3 perovskite oxide metal/semiconductor

    E-Print Network [OSTI]

    Xu, Xianfan

    perovskite oxide metal/semiconductor superlattices Pankaj Jha,1,2 Timothy D. Sands,1,2,3,a) Laura Cassels,4)/lanthanum manganate (LaMnO3, i.e., LMO) perovskite oxide metal/semiconductor superlattices were investigated

  20. An Economic Analysis of Cotton Gin Plants -- High Plains, Rolling Plains and Lower Rio Grande Valley of Texas. 

    E-Print Network [OSTI]

    Thompson, Russell G.; Ward, J. M.

    1964-01-01

    volumes of cotton had much lower costs than those ginning relatively small volumes. For com- parable volumes, single-battery gins on the High Plains had lower costs per bale than multiple- battery gins. Costs per bale were considerably greater... in the Lower Rio Grande Valley than at comparable gin plants on the Plains. Costs per bale ranged from $8.41 to $16.49 at single-battery gin plants and from $9.72 to $16.66 at multiple- battery gin plants on the High Plains. Total costs ranged from $13...

  1. Don't let the river run dry: Efficiency and conservation efforts in the Rio Grande Basin 

    E-Print Network [OSTI]

    Supercinski, Danielle

    2010-01-01

    stream_source_info Don't let the river run dry.pdf.txt stream_content_type text/plain stream_size 8105 Content-Encoding ISO-8859-1 stream_name Don't let the river run dry.pdf.txt Content-Type text/plain; charset=ISO-8859...-1 Don?t let the river run dry Effi ciency and conservation efforts in the Rio Grande Basin Story by Danielle Supercinski txH2O | pg. 6 An unknown fact to most is that high water demands by agriculture along with the ever-increasing urban...

  2. Don't let the river run dry: Efficiency and conservation efforts in the Rio Grande Basin 

    E-Print Network [OSTI]

    Supercinski, Danielle

    2011-01-01

    stream_source_info Don't let the river run dry.pdf.txt stream_content_type text/plain stream_size 8105 Content-Encoding ISO-8859-1 stream_name Don't let the river run dry.pdf.txt Content-Type text/plain; charset=ISO-8859...-1 Don?t let the river run dry Effi ciency and conservation efforts in the Rio Grande Basin Story by Danielle Supercinski txH2O | pg. 6 An unknown fact to most is that high water demands by agriculture along with the ever-increasing urban...

  3. Synthesis, crystal structure, and vibrational spectroscopic and UV-visible studies of Cs{sub 2}MnP{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Kaoua, Saida; Krimi, Saida; Pechev, Stanislav; Gravereau, Pierre; Chaminade, Jean-Pierre; Couzi, Michel; El Jazouli, Abdelaziz

    2013-02-15

    A new member of the A{sub 2}MP{sub 2}O{sub 7} diphosphate family, Cs{sub 2}MnP{sub 2}O{sub 7}, has been synthesized and structurally characterized. The crystal structure was determined by single crystal X-Ray diffraction. Cs{sub 2}MnP{sub 2}O{sub 7} crystallizes in the orthorhombic system, space group Pnma ( Music-Sharp-Sign 62), with the unit cell parameters a=16.3398(3), b=5.3872(1), c=9.8872(2) A, Z=4 and V=870.33(3) A{sup 3}. The structure parameters were refined to a final R{sub 1}/wR{sub 2}=0.0194/0.0441 for 1650 observed reflections. The 2D framework of Cs{sub 2}MnP{sub 2}O{sub 7} structure consists of P{sub 2}O{sub 7} and MnO{sub 5} units. The corner-shared MnO{sub 5} and P{sub 2}O{sub 7} units are alternately arranged along the b axis to form [(MnO)P{sub 2}O{sub 7}]{sub {infinity}} chains. These chains are interconnected by an oxygen atom to form sheets parallel to the (b, c) plane. The cesium atoms are located between the sheets in 9- and 10-fold coordinated sites. The infrared and Raman vibrational spectra have been investigated. A factor group analysis leads to the determination of internal modes of (P{sub 2}O{sub 7}) groups. UV-visible spectrum consists of weak bands, between 340 and 700 nm, assigned to the forbidden d-d transitions of Mn{sup 2+} ion, and of a strong band around 250 nm, attributed to the O--Mn charge transfer. - Graphical abstract: Structure of Cs{sub 2}MnP{sub 2}O{sub 7}: The 2D structure of Cs{sub 2}MnP{sub 2}O{sub 7} is built from P{sub 2}O{sub 7} diphosphate groups and MnO{sub 5} square pyramids which share corners and form [(MnO)P{sub 2}O{sub 7}]{sub {infinity}} chains along b axis. These chains are interconnected by an oxygen atom to form wavy (MnP{sub 2}O{sub 7}){sup 2-} sheets parallel to the (b, c) plane. The cesium ions are located between these sheets in the inter-layers space, in zigzag positions. Highlights: Black-Right-Pointing-Pointer A new diphosphate, Cs{sub 2}MnP{sub 2}O{sub 7}, has been synthesized and structurally characterized. Black-Right-Pointing-Pointer The structure consists of a 2D framework built up from (MnP{sub 2}O{sub 7}) sheets. Black-Right-Pointing-Pointer The sheets consist of [(MnO)P{sub 2}O{sub 7}]{sub {infinity}} chains formed by P{sub 2}O{sub 7} units and MnO{sub 5} square pyramids. Black-Right-Pointing-Pointer A factor group analysis leads to the determination of internal modes of (P{sub 2}O{sub 7}) groups. Black-Right-Pointing-Pointer UV-visible spectrum consists bands assigned to d-d transitions of Mn{sup 2+} ion and to O--Mn CT.

  4. Copyright 2010 IEEE. Reprinted from Proceedings of the 2010 IEEE Power & Energy Society General Meeting, Minneapolis, MN, USA.

    E-Print Network [OSTI]

    Kemner, Ken

    General Meeting, Minneapolis, MN, USA. This material is posted here with permission of the IEEE and therefore is exposed to fluctuations in future electricity prices (day-ahead and real-time) and potential from participating in the wholesale electricity market. We propose a methodology to derive optimal day

  5. Magnetic and structural properties of Mn-implanted GaN N. Theodoropoulou and A. F. Hebard

    E-Print Network [OSTI]

    Hebard, Arthur F.

    process- ing, and storage and in photonics. It has been demonstrated in a number of semiconductors, and S. J. Peartona) Department of Materials Science and Engineering, University of Florida, Gainesville hole concentration of 2 1017 cm 3 . Mn ions were implanted at an energy of 250 keV and doses from 1015

  6. Theoretical Study of the Structural Evolution of a Na2FeMn(CN)6 Cathode upon Na Intercalation

    E-Print Network [OSTI]

    Henkelman, Graeme

    Blue analog, NaxFeMn(CN)6, is a potential new cathode material for Na-ion batteries. During Na-sharing tetrahedra. INTRODUCTION Cathode materials for Li and Na batteries have attracted a great deal of interest for renewable energy applications.1-3 They are also of interest scientifically, owing to the rich chemistry

  7. Magnetic properties of MnSb inclusions formed in GaSb matrix directly during molecular beam epitaxial growth

    SciTech Connect (OSTI)

    Lawniczak-Jablonska, Krystyna; Wolska, Anna; Klepka, Marcin T.; Kret, Slawomir; Kurowska, Boguslawa; Kowalski, Bogdan J.; Twardowski, Andrzej; Wasik, Dariusz; Kwiatkowski, Adam; Sadowski, Janusz

    2011-04-01

    Despite of intensive search for the proper semiconductor base materials for spintronic devices working at room temperature no appropriate material based on ferromagnetic semiconductors has been found so far. We demonstrate that the phase segregated system with MnSb hexagonal inclusions inside the GaSb matrix, formed directly during the molecular beam epitaxial growth reveals the ferromagnetic properties at room temperature and is a good candidate for exploitation in spintronics. Furthermore, the MnSb inclusions with only one crystalline structure were identified in this GaMn:MnSb granular material. The SQUID magnetometry confirmed that this material exhibits ferromagnetic like behavior starting from helium up to room temperature. Moreover, the magnetic anisotropy was found which was present also at room temperature, and it was proved that by choosing a proper substrate it is possible to control the direction of easy axis of inclusions' magnetization moment between in-plane and out-of-plane; the latter is important in view of potential applications in spintronic devices.

  8. Incremental Analysis of Power Grids using Backward Random Walks Baktash Boghrati and Sachin S. Sapatnekar, University of Minnesota, Minneapolis, MN

    E-Print Network [OSTI]

    Sapatnekar, Sachin

    intensive task. In this work, we first introduce an accurate modeling methodology for power grids thatA Incremental Analysis of Power Grids using Backward Random Walks Baktash Boghrati and Sachin S. Sapatnekar, University of Minnesota, Minneapolis, MN Power grid design and analysis is a critical part

  9. First-principles study of Mn-induced local magnetic moments in host semiconductors Shi-Hao Wei

    E-Print Network [OSTI]

    Gong, Xingao

    230031, China Gustavo M. Dalpian and Su-Huai Wei National Renewable Energy Laboratory, Golden, Colorado the high energy state, thus lowering the total energy. In the case where no hole is present, such as in Cd lowering the total energy.1,5 However, recent discovery that Mn-doped III-V semiconduc- tors can have

  10. Highly luminescent surface-passivated ZnS:Mn nanoparticles by a simple one-step synthesis

    E-Print Network [OSTI]

    Park, Byungwoo

    to the formation of an effective passivation layer induced by lithium, and consequent suppression enhancement afforded by the formation of the passivation layer induced by lithium addition was stud- ied ml , and Mn NO3 2 0.05 g and LiOH·H2O were prepared in distilled water. Zinc acetate solution

  11. Phase-separated high-temperature-annealed (Ga,Mn)As: A negative charge-transfer-energy material

    E-Print Network [OSTI]

    Moreno, M

    2011-01-01

    The approximate location in the Zaanen-Sawatzky-Allen diagram of the phase-separated (Ga,Mn)As material, consisting of MnAs nanoclusters embedded in GaAs, is determined on the basis of configuration-interaction (CI) cluster-model analysis of their Mn 2p core-level photoemission. The composite material is found to belong to the special class of materials with negative charge-transfer energy (delta). As such, its metallic or insulating/semiconducting behavior depends on the strength of the p-d hybridization (affected by strain) relative to the (size-dependent) p-bandwidth. Whereas internal strain in the embedded clusters counteracts gap opening, a metal-to-semiconductor transition is expected to occur for decreasing cluster size, associated to the opening of a small gap of p-p type (covalent gap). The electronic properties of homogeneous and phase-separated (Ga,Mn)As materials are analyzed, with emphasis on the nature of their metal-insulator transitions.

  12. Magnetization dependence on electron density in epitaxial ZnO thin films codoped with Mn and Sn

    E-Print Network [OSTI]

    Hebard, Arthur F.

    technology. Moreover, this material is useful in delineating the origin of ferromagnetism in a semiconductor. Ivill, S. J. Pearton, and D. P. Nortona Department of Materials Science and Engineering, University online 11 February 2005 The magnetic and transport properties of Mn-doped ZnO thin films codoped with Sn

  13. A non-volatile-memory device on the basis of engineered anisotropies in (Ga,Mn)As

    E-Print Network [OSTI]

    Loss, Daniel

    ­orbit-mediated coupling of magnetic and semiconductor properties in this material gives rise to many novel transport,Mn)As is a prototypical material for investigating potential device applications of ferromagnetic semiconductors. The spin.1038/nphys652 The rich anisotropic transport behaviour shown by ferromagnetic semiconductors arises from

  14. Heat capacity of the site-diluted spin dimer system Ba?(Mn1-xVx)?O?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samulon, E. C.; Shapiro, M. C.; Fisher, I. R.

    2011-08-01

    Heat-capacity and susceptibility measurements have been performed on the diluted spin dimer compound Ba?(Mn1-xVx)?O?. The parent compound Ba?Mn?O? is a spin dimer system based on pairs of antiferromagnetically coupled S=1, 3d² Mn?? ions such that the zero-field ground state is a product of singlets. Substitution of nonmagnetic S=0, 3d? V?? ions leads to an interacting network of unpaired Mn moments, the low-temperature properties of which are explored in the limit of small concentrations 0?x?0.05. The zero-field heat capacity of this diluted system reveals a progressive removal of magnetic entropy over an extended range of temperatures, with no evidence for amore »phase transition. The concentration dependence does not conform to expectations for a spin-glass state. Rather, the data suggest a low-temperature random singlet phase, reflecting the hierarchy of exchange energies found in this system.« less

  15. Mn-doped Ga(As,P) and (Al,Ga)As ferromagnetic semiconductors: Electronic structure calculations 

    E-Print Network [OSTI]

    Masek, J.; Kudrnovsky, J.; Maca, F.; Sinova, Jairo; MacDonald, A. H.; Campion, R. P.; Gallagher, B. L.; Jungwirth, T.

    2007-01-01

    A remarkable progress towards functional ferromagnetic semiconductor materials for spintronics has been achieved in p-type (Ga,Mn)As. Robust hole-mediated ferromagnetism has, however, been observed also in other III-V hosts such as antimonides, Ga...

  16. Unusual magnetic hysteresis and the weakened transition behavior induced by Sn substitution in Mn{sub 3}SbN

    SciTech Connect (OSTI)

    Sun, Ying, E-mail: sunying@buaa.edu.cn [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng; Li, Jun; Wang, Xia [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [Materials Processing Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan); Wang, Cong [Center for Condensed Matter and Materials Physics, Department of Physics, Beihang University, Beijing 100191 (China); Feng, Hai L.; Sathish, Clastin I.; Yamaura, Kazunari, E-mail: yamaura.kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Matsushita, Yoshitaka [Analysis Station, National Institute for Materials Science, Tsukuba, Ibaraki 305-0047 (Japan)

    2014-01-28

    Substitution of Sb with Sn was achieved in ferrimagnetic antiperovskite Mn{sub 3}SbN. The experimental results indicate that with an increase in Sn concentration, the magnetization continuously decreases and the crystal structure of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N changes from tetragonal to cubic phase at around x of 0.8. In the doping series, step-like anomaly in the isothermal magnetization was found and this behavior was highlighted at x?=?0.4. The anomaly could be attributed to the magnetic frustration, resulting from competition between the multiple spin configurations in the antiperovskite lattice. Meantime, H{sub c} of 18 kOe was observed at x?=?0.3, which is probably the highest among those of manganese antiperovskite materials reported so far. With increasing Sn content, the abrupt change of resistivity and the sharp peak of heat capacity in Mn{sub 3}SbN were gradually weakened. The crystal structure refinements indicate the weakened change at the magnetic transition is close related to the change of c/a ratio variation from tetragonal to cubic with Sn content. The results derived from this study indicate that the behavior of Mn{sub 3}Sb{sub 1-x}Sn{sub x}N could potentially enhance its scientific and technical applications, such as spin torque transfer and hard magnets.

  17. Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion

    SciTech Connect (OSTI)

    Mohanty, Debasish [ORNL; Li, Jianlin [ORNL; Abraham, Daniel P [Argonne National Laboratory (ANL); Huq, Ashfia [ORNL; Payzant, E Andrew [ORNL; Wood III, David L [ORNL; Daniel, Claus [ORNL

    2014-01-01

    Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

  18. Synthesis and characterization of R{sub 2}MnTiO{sub 7} (R = Y and Er) pyrochlores oxides

    SciTech Connect (OSTI)

    Martínez-Coronado, R.; Alonso, J.A.; Fernández, M.T.

    2013-09-01

    Graphical abstract: - Abstract: New pyrochlore-like phases of composition R{sub 2}MnTiO{sub 7} (R = Er and Y) have been synthesized by a soft-chemistry procedure involving citrates of the different metal ions followed by thermal treatments at moderate temperatures (850 °C for 12 h in air). A characterization by X-ray diffraction and neutron powder diffraction (NPD) has been carried out in order to determine the crystal structure features: these phyrochlores are cubic, space group Fd-3m, defining an intrinsically frustrated three-dimensional system. The Rietveld-refinement from NPD data at room temperature evidences an antisite cation disorder (distribution of Mn between A and B positions) that is accompanied by an increment of the oxygen-vacancy concentration due to the reduction of Mn{sup 4+} at the B position to Mn{sup 2+} at the A position. Thermogravimetric analysis (TGA) was useful to evaluate the stability of these oxides in reducing conditions up to 500 °C. Magnetic susceptibility measurements indicate a ferromagnetic behavior, due to the random distribution of Mn{sup 4+} ions in the octahedral sublattice. At lower temperatures there is a polarization of the R{sup +3} magnetic moments, which also participate in the magnetic structure. Aiming to evaluate these materials as possible electrodes for solid oxide fuel cells (SOFC) we determined that the thermal expansion coefficients between 100 and 900 °C perfectly match with those of the usual electrolytes; however, these pyrochlore oxides display a semiconductor-like behavior with poor conductivity values, e.g. 6 × 10{sup ?3} cm{sup ?1} at 850 °C for Er, which would prevent its use as MIEC (mixed ionic-electronic conductors) oxides in SOFC devices.

  19. Effect of CoFe insertion in Co{sub 2}MnSi/CoFe/n-GaAs junctions on spin injection properties

    SciTech Connect (OSTI)

    Ebina, Yuya; Akiho, Takafumi; Liu, Hong-xi; Yamamoto, Masafumi; Uemura, Tetsuya, E-mail: uemura@ist.hokudai.ac.jp [Division of Electronics for Informatics, Graduate School of Information Science and Technology, Hokkaido University, Sapporo 060-0814 (Japan)

    2014-04-28

    The CoFe thickness (t{sub CoFe}) dependence of spin injection efficiency was investigated for Co{sub 2}MnSi/CoFe/n-GaAs junctions. The ?V{sub NL}/I value, which is a measure of spin injection efficiency, strongly depended on t{sub CoFe}, where ?V{sub NL} is the amplitude of a nonlocal spin-valve signal, and I is an injection current. Importantly, the maximum value of ?V{sub NL}/I for a Co{sub 2}MnSi/CoFe/n-GaAs junction was one order of magnitude higher than that for a CoFe/n-GaAs junction, indicating that a Co{sub 2}MnSi electrode works as a highly polarized spin source. No clear spin signal, on the other hand, was observed for a Co{sub 2}MnSi/n-GaAs junction due to diffusion of Mn atoms into the GaAs channel. Secondary ion mass spectrometry analysis indicated that the CoFe insertion effectively suppressed the diffusion of Mn into GaAs, resulting in improved spin injection properties compared with those for a Co{sub 2}MnSi/n-GaAs junction.

  20. The role of the (111) texture on the exchange bias and interlayer coupling effects observed in sputtered NiFe/IrMn/Co trilayers

    SciTech Connect (OSTI)

    Castro, I. L.; Nascimento, V. P.; Passamani, E. C.; Takeuchi, A. Y.; Larica, C.; Tafur, M.; Pelegrini, F.

    2013-05-28

    Magnetic properties of sputtered NiFe/IrMn/Co trilayers grown on different seed layers (Cu or Ta) deposited on Si (100) substrates were investigated by magnetometry and ferromagnetic resonance measurements. Exchange bias effect and magnetic spring behavior have been studied by changing the IrMn thickness. As shown by X-ray diffraction, Ta and Cu seed layers provoke different degrees of (111) fcc-texture that directly affect the exchange bias and indirectly modify the exchange spring coupling behavior. Increasing the IrMn thickness, it was observed that the coupling angle between the Co and NiFe ferromagnetic layers increases for the Cu seed system, but it reduces for the Ta case. The results were explained considering (i) different anisotropies of the Co and IrMn layers induced by the different degree of the (111) texture and (ii) the distinct exchange bias set at the NiFe/IrMn and IrMn/Co interfaces in both systems. The NiFe and Co interlayer coupling angle is strongly correlated with both exchange bias and exchange magnetic spring phenomena. It was also shown that the highest exchange bias field occurs when an unstressed L1{sub 2} IrMn structure is stabilized.