National Library of Energy BETA

Sample records for grade sulfur content

  1. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    SciTech Connect (OSTI)

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  2. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  3. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon Excluding...

  4. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District (Cents per Gallon Excluding...

  5. The sulfur content of volcanic gases on Mars Fabrice Gaillard, a

    E-Print Network [OSTI]

    Boyer, Edmond

    The sulfur content of volcanic gases on Mars Fabrice Gaillard, a and Bruno Scaillet1, a a CNRS sulfur contents of the martian regolith and lack of detection of extensive carbonate deposits suggest that the latest geological events that shaped the landscapes of Mars were dominated by acidic waters possibly

  6. Relationship between pyrite formation and organic sulfur content of coal as revealed by electron microscopy

    SciTech Connect (OSTI)

    Raymond, R. Jr.; Hagan, R.C.

    1982-01-01

    There are a large number of questions concerning the mode of occurrence of organic sulfur in peat, and what, if anything, alters its occurrence during and after coalification. The formation of pyrite during periods of peatification and coalification has been hypothesized to have a great effect on the organic sulfur content of organic material surrounding the pyrite. Measurement of organic sulfur contents at different distances from pyrite particles would serve as direct experimental proof for or against this pypothesis. A combination of in situ energy dispersive spectrometer (EDS) line profiles, EDS x-ray maps, and WDS analyses across pyrite/coal interfaces in a variety of coals shows unequivocally that formation of pyrite does not alter the organic sulfur contents of the surrounding coal macerals.

  7. Phosphate Glasses for Vitrification of Waste with High Sulfur Content

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.; Hrma, Pavel R.; Cassingham, Nathan J.

    2002-10-31

    The low solubility of sulfate in silicate-based glasses, approximately 1 mass% as SO3, limits the loading of high-level waste (HLW) and low-activity waste (LAW) containing high concentrations of sulfur. Based on crucible melting studies, we have shown that the phosphate glasses may incorporate more than 5 mass% SO3; hence, the waste loading can be increased until another constraint is met, such as glass durability. A high-sulfate HLW glass has been formulated and tested to demonstrate the advantages of phosphate glasses. The effect of waste loading on the chemical durability of quenched and slow-cooled phosphate glasses was determined using the Product Consistency Test.

  8. Developing Second Grade Teachers' Pedagogical Content Knowledge of Place Value 

    E-Print Network [OSTI]

    Kulhanek, Stefani Michelle

    2013-01-10

    An understanding of whole number place value is a critical component of second-grade mathematics. This understanding of place value provides the foundational concept for operations with whole numbers. The ability to ...

  9. Nutrient Content of Beef Steaks as Influenced by USDA Quality Grade and Degree of Doneness 

    E-Print Network [OSTI]

    Smith, Amanda M.

    2010-07-14

    for the designation as UNDERGRADUATE RESEARCH SCHOLAR A Senior Scholars Thesis by AMANDA MARIAN SMITH Approved by: Co-Research Advisors: Jeffrey W. Savell Kerri B. Harris Associate Dean for Undergraduate Research: Robert C. Webb Major: Animal... QUALITY GRADE AND DEGREE OF DONENESS A Senior Scholars Thesis by AMANDA MARIAN SMITH iii ABSTRACT Nutrient Content of Beef Steaks as Influenced by USDA Quality Grade and Degree of Doneness. (April 2010) Amanda Marian Smith Department...

  10. Synthesis of Bi{sub 2}S{sub 3} with different sulfur content by conventional high temperature solid state solvothermal route

    SciTech Connect (OSTI)

    Solanki, S. I., E-mail: patelishverb@yahoo.com; Patel, I. B., E-mail: patelishverb@yahoo.com [Department of Physics, Veer Narmad South Gujarat University, Surat-395007 (India); Shah, N. M. [Physics Department, A.N. Shah Science College, Kamrej-394185 (India)

    2014-04-24

    Bismuth sulfide (Bi{sub 2}S{sub 3}) is a binary chalcogenide compound material belonging to V-VI group of semiconductors. Because of its direct band gap of 1.3 eV and high figure of merit (ZT) value, it is widely used as a thermo electronic-cooling material based on the Peltier effect. The electrical and optical property of Bi{sub 2}S{sub 3} material is strongly dependent on stoichiometric composition, defect chemistry and structure. In this study, we have synthesized Bi{sub 2}S{sub x} (x = 3.15, 3.30, 3.45) compound material with different sulfur content by conventional high temperature solid state solvothermal reaction of bismuth and sulfur. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDXS) analysis of synthesized compound materials were carried out to observe crystallinity, surface morphology and composition of elements in the compound. The optical analysis revealed that energy band gap decreases with increase of sulfur content.

  11. Establishment of a laboratory mix-design method for open-graded friction courses using sulfur-extended asphalt (SEA) binders 

    E-Print Network [OSTI]

    Ho, Kee-Kwong

    1981-01-01

    indicated that mixtures of sand, asphalt and sulfur exhibited somewhat h1gher Marshall stabil1ties, with a slightly greater water sensitiv1ty, than convent1onal asphalt1c concrete mixtures. 23 Develo ment of SEA-DGFC A review of the literature... temperature of sulfur (i. e. , 240'F (116'C)1. It was also suggested that further study should examine the reasons for the improved permeab1lity in the SEA-OGFC systems. Future work should also include the verificat1on of the proposed mix-des1gn procedure...

  12. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E. (Manassas, VA)

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  13. Using ISC & GIS to predict sulfur deposition from coal-fired power plants 

    E-Print Network [OSTI]

    Lopez, Jose Ignacio

    1993-01-01

    The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

  14. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  15. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H. (LaJolla, CA)

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  16. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  17. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  18. Paper 2008-01-0434 Effects of Sulfur Level and Anisotropy of Sulfide Inclusions on

    E-Print Network [OSTI]

    Fatemi, Ali

    to fatigue strength, the high sulfur material had up to 25% lower fatigue strength than the ultra low sulfur, monotonic tensile and CVN impact behavior of SAE 4140 steel with high (0.077% S), low (0.012% S) and ultra low (0.004% S) sulfur contents at two hardness levels (40 HRC and 50 HRC). The longitudinally oriented

  19. Abatement of Air Pollution: Control of Sulfur Compound Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    set limits on the sulfur content of allowable fuels (1.0% by weight, dry basis) for combustion, as well as for the heat input of any fuel burning equipment (250,000 Btuhour)....

  20. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  1. Low-quality natural gas sulfur removal/recovery

    SciTech Connect (OSTI)

    Damon, D.A. [CNG Research Co., Pittsburgh, PA (United States); Siwajek, L.A. [Acrion Technologies, Inc., Cleveland, OH (United States); Klint, B.W. [BOVAR Inc., AB (Canada). Western Research

    1993-12-31

    Low quality natural gas processing with the integrated CFZ/CNG Claus process is feasible for low quality natural gas containing 10% or more of CO{sub 2}, and any amount of H{sub 2}S. The CNG Claus process requires a minimum CO{sub 2} partial pressure in the feed gas of about 100 psia (15% CO{sub 2} for a 700 psia feed gas) and also can handle any amount of H{sub 2}S. The process is well suited for handling a variety of trace contaminants usually associated with low quality natural gas and Claus sulfur recovery. The integrated process can produce high pressure carbon dioxide at purities required by end use markets, including food grade CO{sub 2}. The ability to economically co-produce high pressure CO{sub 2} as a commodity with significant revenue potential frees process economic viability from total reliance on pipeline gas, and extends the range of process applicability to low quality gases with relatively low methane content. Gases with high acid gas content and high CO{sub 2} to H{sub 2}S ratios can be economically processed by the CFZ/CNG Claus and CNG Claus processes. The large energy requirements for regeneration make chemical solvent processing prohibitive. The cost of Selexol physical solvent processing of the LaBarge gas is significantly greater than the CNG/CNG Claus and CNG Claus processes.

  2. Sulfur removal from diesel fuel-contaminated methanol.

    SciTech Connect (OSTI)

    Lee, S. H. D.; Kumar, R.; Krumpelt, M.; Chemical Engineering

    2002-03-01

    Methanol is considered to be a potential on-board fuel for fuel cell-powered vehicles. In current distribution systems for liquid fuels used in the transportation sector, commodity methanol can occasionally become contaminated with the sulfur in diesel fuel or gasoline. This sulfur would poison the catalytic materials used in fuel reformers for fuel cells. We tested the removal of this sulfur by means of ten activated carbons (AC) that are commercially available. Tests were conducted with methanol doped with 1 vol.% grade D-2 diesel fuel containing 0.29% sulfur, which was present essentially as 33-35 wt.% benzothiophenes (BTs) and 65-67 wt.% dibenzothiophenes (DBT). In general, coconut shell-based carbons activated by high-temperature steam were more effective at sulfur removal than coal-based carbons. Equilibrium sorption data showed linear increase in sulfur capture with the increase of sulfur concentration in methanol. Both types of carbons had similar breakthrough characteristics, with the dynamic sorption capacity of each being about one-third of its equilibrium sorption capacity. Results of this study suggest that a fixed-bed sorber of granular AC can be used, such as in refueling stations, for the removal of sulfur in diesel fuel-contaminated methanol.

  3. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  4. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Hu, Zhicheng (Somerville, MA)

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  5. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  6. Impact of Sulfur Oxides on Mercury Capture by Activated Carbon

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J.

    2007-09-15

    Recent field tests of mercury removal with activated carbon injection (ACI) have revealed that mercury capture is limited in flue gases containing high concentrations of sulfur oxides (SOx). In order to gain a more complete understanding of the impact of SOx on ACI, mercury capture was tested under varying conditions of SO2 and SO3 concentrations using a packed bed reactor and simulated flue gas (SFG). The final mercury content of the activated carbons is independent of the SO2 concentration in the SFG, but the presence of SO3 inhibits mercury capture even at the lowest concentration tested (20 ppm). The mercury removal capacity decreases as the sulfur content of the used activated carbons increases from 1 to 10%. In one extreme case, an activated carbon with 10% sulfur, prepared by H2SO4 impregnation, shows almost no mercury capacity. The results suggest that mercury and sulfur oxides are in competition for the same binding sites on the carbon surface.

  7. An Aerosol Condensation Model for Sulfur Trioxide

    SciTech Connect (OSTI)

    Grant, K E

    2008-02-07

    This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

  8. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P. (Upper St. Clair, PA)

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  9. Stratospheric sulfur oxidation kinetics

    SciTech Connect (OSTI)

    Jayne, J.T.; Worsnop, D.R.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States)] [and others

    1995-12-31

    Oxidation of SO2 to H2SO4 in the atmosphere is believed to involve the reaction of SO3 with water. It is commonly assumed that this is an important step leading to homogeneous nucleation of H2SO4 aerosol particles. Heterogeneous chemistry on sulfuric acid aerosols regulate much of the ozone photochemistry in the lower stratosphere and are also believed to have significant effect on the climate. Understanding aerosol loading requires a detailed knowledge of the stratospheric sulfur budget, including its oxidation kinetics. Here we present results of a laboratory project studying a key step in the oxidation process, the homogeneous reaction between SO3 and H2O vapor. Kinetic measurements are performed in a high-pressure turbulent fast-flow reactor (fabricated at MIT) which minimizes heterogeneous loss of SO3 on reactorwalls. The rate of decay of SO3 and the appearance of H2SO4 is monitored in the presence of excess water vapor. Gas phase reactants and products are detected via an atmospheric pressure chemical ionization mass spectrometer which is coupled to the exit of the flow reactor. Sulfuric acid nucleation studies can also be performed using the turbulent flow reactor. Initial measurements using a particle detector (based on Mie scattering) showed that aerosol formation and particle size distribution are controlled by varying the SO3/H2O gas ratio and the reactor temperature. Results for the reaction SO3J+ H2O show a second order dependence in water vapor density and a strong negative temperature dependence. The results, measured in the range -30C to +95C, imply that an SO3.H2O adduct and/or a water dimer species is likely involved in the reaction mechanism. Results of recent theoretical calculations on the SO3 + H2O system also support the finding that two water molecules are involved. Implications for the gas phase production of sulfuric acid in the atmosphere will be discussed.

  10. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  11. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  12. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  13. Nonflame, source-induced sulfur fluorescence detector for sulfur-containing compounds

    SciTech Connect (OSTI)

    Gage, D.R.; Farwell, S.O.

    1980-12-01

    Results of some preliminary investigations of the fluorescence spectra of S/sub 2/ and the non-flame production of S/sub 2/ from sulfur-containing molecules are reported. Passage of the gas to be analyzed through a catalyst-oven containing a plug of NiO/sub 2//Al/sub 2/O/sub 3/ catalyst containing 10 wt% NiO/sub 2/ and heated to 400/sup 0/C resulted in conversion of H/sub 2/S to S/sub 2/ and elemental sulfur. The S/sub 2/ was detected by measurement of its fluorescence bands at 260 and 310nm, and elemental sulfur condensed on the cool parts of the apparatus. However, determination of sulfur-content of gas mixtures with the apparatus described herein were not as repeatable as desired, and the work is being continued on various facets of the non-flame system with work being directed toward the evaluation of different catalysts, catalyst temperature, design of a smaller detector geometry utilizing a pulsed-light excitation source, a windowless cell, and optical filters instead of monochromators to select the S/sub 2/ excitation and emission wavelengths. (BLM)

  14. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Jozewicz, Wojciech (Chapel Hill, NC)

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  15. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  16. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati (Ann Arbor, MI)

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  17. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  18. Sulfur-Free Selective Pulping 

    E-Print Network [OSTI]

    Dimmel, D. R.; Bozell, J. J.

    1994-01-01

    an increase in pulping rate and yields, which translates to less energy required per ton of product. Less sulfur means a simplified process, lower odor emissions, and a decrease requirement for bleaching chemicals, meaning less organics being discharged...

  19. Effect of Prussian blue on organic sulfur of coal in aqueous medium

    SciTech Connect (OSTI)

    Demirbas, A. [Selcuk University, Konya (Turkey). Dept. of Chemical Engineering

    2007-01-15

    This study is an attempt to desulfurize organic sulfur from coal samples with ferric hexacyanoferrate (II), Fe{sub 4} (Fe(CN){sub 6}), as the desulfurization agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the coal samples has been investigated. The temperature and stirring time are the most important parameters for the level of desulfurization of organic sulfur. Removal of organic sulfur content increased continuously with increasing temperature from 298 to 368 K. The organic sulfur removal rate sharply increases from 10 min to 30 min stirring time. After 30 min, it reaches a value of plateau. Particle size between -100 mesh and -200 mesh slightly affects the amount of organic sulfur removal. Gradual increase in the concentration of ferric hexacyanoferrate (II) raised the magnitude of desulfurization, but at higher concentration, the variation is not significant.

  20. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States)] [and others

    1992-12-31

    The purposes of this Testing and Materials (ASTM) forms of sulfur analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation. Problem that limits commercial application of the PCE process is the high chlorine content in the PCE-treated coals. Hence, to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal is an additional goal of this investigation. MWOPC`s results have been repeated on fresh IBC-104 coal. Oxidation of coals was found to affect subsequent PCE desulfurization. Elemental sulfur is more amenable to removal by PCE. Ohio 5/6 coal appears to produce elemental sulfur more readily than Illinois coal during oxidation. Data from X-Ray Diffraction spectroscopy indicate that sulfate in the oxidized Illinois IBC-104 coal is mainly in gypsum form, whereas, sulfate in oxidized Ohio 5/6 sample is mainly in szomolnokite form. These data suggest that the oxidation reaction for Ohio 5/6 coal might occur under catalytic conditions which readily convert pyrite to produce FeSO{sub 4} and elemental sulfur. The higher elemental sulfur content in that coal results in higher ASTM organic sulfur removal by PCE extraction. From mass balance calculation, 96% of the total sulfur and greater than 95% of total iron were accounted for during our PCE tests with both long-term ambient-oxidized IBC-104 coal and ambient-oxidized Ohio 516 coal.

  1. Grading Instructions Run Grade Roster Status Report

    E-Print Network [OSTI]

    Fletcher, Robin

    list when using Search icon or enter the term code if known. Enter the Grade Roster type ­ Final Grade or Mid-Term. Select the Node: Department ­ Select from list when using search icon or enter if known Tools => Query => Query Viewer Enter the query name or partial name in the search field. Click

  2. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01

    This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than the potential service costs reduction, it is very significant. It represents an important red

  3. Exam 1 Advisory Letter Grades

    E-Print Network [OSTI]

    Kelly T Beranger

    2009-02-12

    MA 16200. Exam 1 Advisory Letter Grades. Spring 09. These advisory letter grades are estimates only and have no official standing. The actual letter grades will ...

  4. Method of preparing graphene-sulfur nanocomposites for rechargeable...

    Office of Scientific and Technical Information (OSTI)

    Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Method of preparing graphene-sulfur...

  5. Grade Uploa Faculty Cen

    E-Print Network [OSTI]

    Angenent, Lars T.

    grading b Grading Basi AUD GRV GRL UV UX . Delete the Taken, Progra e new colum g: stitution­ th s. erm, Grading B A, B, and C, e n all capital same for eve n the heade erms: escription mer 2015 015 er 2016

  6. Adsorbed sulfur-gas methods for both near-surface exploration and downhole logging

    SciTech Connect (OSTI)

    Farwell, S.O.; Barinaga, C.J.; Dolenc, M.R.; Farwell, G.H.

    1986-08-01

    The use of sulfur-containing gases in petroleum exploration is supported by (1) the idea that sulfur may play a role in petroleum genesis, (2) the corresponding existence of sulfur-containing compounds in petroleum and the potential for vertical migration of the low-molecular-weight sulfur species from these reservoirs, (3) the production of H/sub 2/S by anaerobic microorganism populations that develop in the subsurface areas overlying petroleum reservoirs due to the concomitant supply of hydrocarbon nutrients, (4) the recent discovery of near-surface accumulations of pyrite and marcasite as the source of induction potential anomalies over certain fields, and (5) the strong adsorptive affinities of sulfur gases to solid surfaces, which enhance both the concentration and localization of such sulfur-expressed anomalies. During the past 3 years, numerous near-surface soil samples and well cuttings from the Utah-Wyoming Overthrust belt have been analyzed for adsorbed sulfur-gas content by two novel analytical techniques: thermal desorption/metal foil collection/flash desorption/sulfur-selective detection (TD/MFC/FD/SSD) and thermal desorption/cryogenic preconcentration/high-resolution-gas chromatography/optimized-flame photometry (TD/CP/HRGC/OFP).

  7. On the Origin of Sulfur

    E-Print Network [OSTI]

    Nils Ryde; David L. Lambert

    2005-10-05

    We present our work on the halo evolution of sulfur, based on observations of the S I lines around 9220 A for ten stars for which the S abundance was obtained previously from much weaker S I lines at 8694 A. We cannot confirm the rise and the high [S/Fe] abundances for low [Fe/H], as claimed in the literature from analysis of the 8694 A lines. The reasons for claims of an increase in [S/Fe] with decreasing [Fe/H] are probably twofold: uncertainties in the measurements of the weak 8694 A lines, and systematic errors in metallicity determinations from Fe I lines. The near-infrared sulfur triplet at 9212.9, 9228.1, and 9237.5 A are preferred for an abundance analysis of sulfur for metal-poor stars. Our work was presented in full by Ryde & Lambert (2004).

  8. Safety considerations for the use of sulfur in sulfur-modified pavement materials 

    E-Print Network [OSTI]

    Jacobs, Carolyn Yuriko

    1980-01-01

    Liquid Sulfur Page v111 ix 33 33 35 IV Symptoms of Poisoning . First Aid SULFUR IN THE PAVING INDUSTRY General Sand-Asphalt-Sulfur Pavements (SAS) ', , Sulfur-Extended Asphalt Pavements (SEA) Sulfur Concrete EVALUATION OF RISKS AND SAFETY... RECOMMENDATIONS General Stationary Sources Mobile Sources Maintenance 40 41 43 43 44 45 46 Hot-Mix Recycling VI EMISSIONS MONITORING METHODS General Area Monitoring - Continuous Samplina Short Term Sampling (" Grab" Sampling) Personnel Monitoring...

  9. Distributed Road Grade Estimation

    E-Print Network [OSTI]

    Johansson, Karl Henrik

    Distributed Road Grade Estimation for Heavy Duty Vehicles PER SAH LHOLM Doctoral Thesis in Automatic Control Stockholm, Sweden 2011 #12;Distributed Road Grade Estimation for Heavy Duty Vehicles PER state-of-charge control decrease the energy consumption of vehicles and increase the safety

  10. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore »the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  11. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Yang, Xiao-Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Zhang, Xuran [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Li, Chao [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; McKinnon, Meaghan E. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Sadok, Rachel G. [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry; Qu, Deyu [Wuhan Univ. of Technology, Hubei (China); Dept. of Chemistry; Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Laboratory (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Massachusetts, Boston, MA (United States). Dept. of Chemistry

    2014-11-01

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  12. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  13. Emission of biogenic sulfur gases from Chinese paddy soil and rice plant

    SciTech Connect (OSTI)

    Zhen Yang [Nanjing Univ. of Science and Technology (China); Li Kong [Nanjing Agricultural Univ. (China)

    1996-12-31

    Biogenic sulfur gases emitted from terrestrial ecosystem may play in important role in global sulfur cycle and have a profound influence on global climate change. But very little is known concerning emissions from paddy soil and rice plant, which are abundant in many parts of the world. As a big agricultural country, this is about 33 million hectare rice planted in China. With laboratory incubation and closed chamber method in the field, the biogenic sulfur gases emitted from Chinese paddy soil and rice plant were detected in both conditions: hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), methyl mercaptan (MSH), carbon disulfide (CS{sub 2}), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS). Among which, DMS was predominant part of sulfur emission. Emission of sulfur gases from different paddy field exhibit high spatial and temporal variability. The application of fertilizer and organic manure, total sulfur content in wetland, air temperature were positively correlated to the emission of volatile sulfur gases from paddy soil. Diurnal and seasonal variation of total volatile sulfur gases and DMS indicate that their emissions were greatly influenced by the activity of the rice plant. The annual emission of total volatile sulfur gases, from Nanjing paddy field is ranged from 4.0 to 9.5 mg S m{sup -2}yr{sup -1}, that of DMS is ranged from 3.1 to 6.5 mg S m{sup -2}yr{sup -1}. Rice plant could absorb COS gas, that may be one of the sinks of COS.

  14. Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988 1.996Deutsche Bank AG Weekly Download35 35 35Global

  15. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  16. Contribution of isotopologue self-shielding to sulfur mass-independent fractionation during sulfur dioxide photolysis

    E-Print Network [OSTI]

    Lyons, J. R.

    Signatures of sulfur mass-independent fractionation (S-MIF) are observed for sulfur minerals in Archean rocks, and for modern stratospheric sulfate aerosols (SSA) deposited in polar ice. Ultraviolet light photolysis of ...

  17. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  18. How to Obtain Reproducible Results for Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Lu, Dongping; Gu, Meng; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-01-01

    The basic requirements for getting reliable Li-S battery data have been discussed in this work. Unlike Li-ion batteries, electrolyte-rich environment significantly affects the cycling stability of Li-S batteries prepared and tested under the same conditions. The reason has been assigned to the different concentrations of polysulfide-containing electrolytes in the cells, which have profound influences on both sulfur cathode and lithium anode. At optimized S/E ratio of 50 g L-1, a good balance among electrolyte viscosity, wetting ability, diffusion rate dissolved polysulfide and nucleation/growth of short-chain Li2S/Li2S2 has been built along with largely reduced contamination on the lithium anode side. Accordingly, good cyclability, high reversible capacity and Coulombic efficiency are achieved in Li-S cell with controlled S/E ratio without any additive. Other factors such as sulfur content in the composite and sulfur loading on the electrode also need careful concern in Li-S system in order to generate reproducible results and gauge the various methods used to improve Li-S battery technology.

  19. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01

    A test program is being sponsored by the US Department of Energy (DOE), EPRI, FirstEnergy, and TVA to investigate furnace injection of alkaline sorbents as a means of reducing sulfuric acid concentrations in the flue gas from coal-fired boilers. This test program is being conducted at the FirstEnergy Bruce Mansfield Plant (BMP), although later testing will be conducted at a TVA plant. A sorbent injection test was conducted the week of April 18, 2000. The test was the first of several short-term (one- to two-week duration) tests to investigate the effectiveness of various alkaline sorbents for sulfuric acid control and the effects of these sorbents on boiler equipment performance. This first short-term test investigated the effect of injecting dry dolomite powder (CaCO{sub 3} {center_dot} MgCO{sub 3}), a mineral similar to limestone, into the furnace of Unit 2. During the test program, various analytical techniques were used to assess the effects of sorbent injection. These primarily included sampling with the controlled condensation system (CCS) for determining flue gas SO{sub 3} content and an acid dew-point (ADP) meter for determining the sulfuric acid dew point (and, indirectly, the concentration of sulfuric acid) of the flue gas. EPA Reference Method 26a was used for determining hydrochloric acid (HCl) and hydrofluoric acid (HF), as well and chlorine (Cl{sub 2}) and fluorine (F{sub 2}) concentrations in the flue gas. Fly ash resistivity was measured using a Southern Research Institute (SRI) point-to-plane resistivity probe, and unburned carbon in fly ash was determined by loss on ignition (LOI). Coal samples were also collected and analyzed for a variety of parameters. Finally, visual observations were made of boiler furnace and convective pass surfaces prior to and during sorbent injection.

  20. Low-grade coals: a review of some prospective upgrading technologies

    SciTech Connect (OSTI)

    Hassan Katalambula; Rajender Gupta [University of Alberta, Edmonton, AB (Canada). Department of Chemical and Materials Engineering

    2009-07-15

    There is a growing need of using low-grade coals because of higher quest for power generation. In the present carbon-constrained environment, there is a need of upgrading these coals in terms of moisture, ash, and/or other trace elements. The current paper reviews technologies used mainly categorized as drying for reducing moisture and cleaning the coal for reducing mineral content of coal and related harmful constituents, such as sulfur and mercury. The earliest upgrading of high-moisture lignite involved drying and manufacturing of briquettes. Drying technologies consist of both evaporative and non-evaporative (dewatering) types. The conventional coal cleaning used density separation in water medium. However, with water being a very important resource, conservation of water is pushing toward the development of dry cleaning of coal. There are also highly advanced coal-cleaning technologies that produce ultra-clean coals and produce coals with less than 0.1% of ash. The paper discusses some of the promising upgrading technologies aimed at improving these coals in terms of their moisture, ash, and other pollutant components. It also attempts to present the current status of the technologies in terms of development toward commercialization and highlights on problems encountered. It is obvious that still the upgrading goal has not been realized adequately. It can therefore be concluded that, because reserves for low-grade coals are quite plentiful, it is important to intensify efforts that will make these coals usable in an acceptable manner in terms of energy efficiency and environmental protection. 68 refs., 7 figs.

  1. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  2. Microbial Architecture of Environmental Sulfur Processes: A

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    potential impacts on water quality, including acid generation in acid mine drainage (AMD) environments, 2009. Accepted July 9, 2009. Microbial oxidation of sulfur-rich mining waste materials drives acid mine drainage (AMD) and affects the global sulfur biogeochemical cycle. The generation of AMD is a complex

  3. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  4. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  5. Production of low-sulfur binder pitch from high-sulfur Illinois coals. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Knight, R.A. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-12-31

    The objective of this project is to produce electrode binder pitch with sulfur content below 0.6 wt% from high-sulfur Illinois coal mild gasification liquids. In this project, two approaches to sulfur reduction are being explored in conjunction with thermocracking: (1) the use of conventionally cleaned coal with low ({approximately}1%) sulfur as a mild gasification feedstock, and (2) direct biodesulfurization of the liquids prior to thermocracking. In Case 1, the crude pitch is being produced by mild gasification of IBC-109 coal in an existing IGT bench-scale reactor, followed by distillation of the scrubbing solvent and light-to-middle oils to isolate the crude pitch. In Case 2, the crude pitch for biodesulfurization is the same material previously studied, which was obtained from Illinois No. 6 coal tests conducted in the IGT mild gasification PRU in 1990. Biodesulfurization is to be performed by contacting the pitch with Rhodococcus Rhodochrous either as live cultures or in the form of concentrated biocatalyst. Following preparation of the crude pitches, pitch upgrading experiments are to be conducted in a continuous flash thermocracker (FTC) constructed in previous ICCI-sponsored studies. The finished pitch is then characterized for physical and chemical properties (density, softening point, QI, TI, coking value, and elemental composition), and compared to typical specifications for binder pitches. This quarter, 45 kg of IBC-109 coal was obtained and sized to 40 x 80 mesh for mild gasification. Laboratory experiments were conducted to identify means of dispersing or emulsifying pitch in water to render is accessible to biocatalysts, and exploratory desulfurization tests on one-gram pitch samples were begun.

  6. Selective trace determination of sulfur and aluminum using charged particle activation analysis 

    E-Print Network [OSTI]

    Burton, Terrence Dale

    1974-01-01

    for the characterization of ultra-pure materials. In a previous study ( 26) we had analyzed crude oil samples for their sulfur content using the reaction 3 S(p, oc ) P. P is a positron emitter with a half- 29 29 life of 4. . 2 seconds. The 0. 511 MeV gamma... gammas which tended to overload the detector, a lead absorber ( 2" thick) was used. A focused beam of 20 MeV protons was used for irradiating a pure sulfur pellet at very low beam currents (1 nano ampere) and the prompt 2. 23 MeV gamma ray...

  7. Analyzing organic sulfur in coal/char: Integrated mild gasification/XANES methods. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes; Huffman, G.P. [Kentucky Univ., Lexington, KY (United States)

    1994-09-01

    The overall goal of this study is to improve the understanding of sulfur in coals/chars via the use of combined advanced non-destructive and advanced destructive methods of sulfur analysis. This study combines selective oxidation, analytical pyrolysis, and sulfur X-ray Absorption Near Edge Structure Spectroscopy (XANES) analysis. Samples with a wide variety of sulfur contents, (0.63% to 4.40%) have been prepared for use in this study. This includes steam gasification chars, oxidized coals and desulfurized coals as well of the original unaltered coals. Mild pyrolysis and preliminary XANES data shows that the sulfur chemistry of gasification chars is significantly different from that of the original coals. Mild pyrolysis of the samples that were oxidized with peroxyacetic acid showed that the level of simple thiophene structures observed in the pyrolysis products declines with increasing levels of oxidation. Sulfur XANES spectra of treated samples showed various effects depending on the treatment severity. For the less severely treated samples (demineralization and solvent extraction), the XANES spectra were similar, although not identical, to the untreated coal spectra, whereas the more severe treatments (steam at 450 C; peroxyacetic acid at 25 C) showed preferential oxidation of one or more sulfur-bearing phases in the original coal. Additional samples have recently been examined by XANES and W-band EPR and the data is currently being processed and evaluated.

  8. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  9. INFLUENCE OF SUBSTRATE OFF-CUT ON THE DEFECT STRUCTURE IN RELAXED GRADED Si-Ge/Si LAYERS

    E-Print Network [OSTI]

    INFLUENCE OF SUBSTRATE OFF-CUT ON THE DEFECT STRUCTURE IN RELAXED GRADED Si-Ge/Si LAYERS SRIKANTH B and Engineering, University of California, Los Angeles, CA 90095. ABSTRACT Relaxed graded Si-Ge/Si layers can of these applications requires a different final Ge concentration in the graded Si-Ge layer. With increasing Ge content

  10. Grading Instructions in PeopleSoft View Student Grades

    E-Print Network [OSTI]

    Fletcher, Robin

    - QUNIV Enter your Term - Select from the list of valid values that appear after you clicked on the Search => Student Grades Navigation: Records & Enrollment => Student Term Information => Student Grades Enter;View Student Grades - Demo 3/21/2011 13 Navigation: Records & Enrollment => Student Term Information

  11. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  12. Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Sulfur Dioxide Crossover during the Production of Hydrogen and Sulfuric Acid in a PEM Electrolyzer membrane PEM electrolyzer has been investigated as a viable system for the electrolysis step of the electrolyzer and membranes developed to limit SO2 crossover. © 2009 The Electrochemical Society. DOI: 10

  13. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore »cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  14. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zheng, Jianming [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Walter, Eric [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pan, Huilin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Lv, Dongping [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Zuo, Pengjian [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Chen, Honghao [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Deng, Z. D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liaw, Bor Y. [School of Ocean and Earth Science and Technology, Hawaii Natural Energy Institute, (United States); Yu, Xiqian [Brookhaven National Laboratory, Upton, NY (United States); Yang, Xiao-Qing [Brookhaven National Laboratory, Upton, NY (United States); Zhang, Ji-Guang [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Liu, Jun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Xiao, Jie [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  15. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  16. TABLE OF CONTENTS Content Page

    E-Print Network [OSTI]

    Li, Jiuyong "John"

    #12;TABLE OF CONTENTS Content Page Version 5.1 iii September 2012 Contents 1 INTRODUCTION 1-1 1;TABLE OF CONTENTS Content Page Version 5.1 iv September 2012 3 PLANNING AND DESIGN GUIDELINES 3-1 3 Noise 3-25 3.3.15 Optimise Light 3-25 3.3.16 Save Water 3-25 3.3.17 Minimise Waste 3-25 3.4 Green Star

  17. An assessment of middle grades preservice teachers' mathematics knowledge for teaching 

    E-Print Network [OSTI]

    Mohr, Margaret Joan

    2009-06-02

    The overall purpose of this concurrent mixed methods study was to develop an online performance assessment using content questions taken from a reputable seventh and eighth grade standardized assessment that effectively ...

  18. Global Anthropogenic Sulfur Emissions for 1985 and 1990 Carmen M. Benkovitz

    E-Print Network [OSTI]

    i s retained i n bottom and f l y ashes. Various types o f f l u e gas desulfurization (FGD) control States, Canada, Western Europe, Japan and Australia. Crude petroleum i s a1so extremely variable i n the sulfur content, ranging from 0.3 t o 2%, depending on the location o f the petroleum f i e l d . I n

  19. SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-02-04

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NO{sub x} control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two First Energy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

  20. SULFURIC ACID REMOVAL PROCESS EVALUATION: SHORT-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-03-04

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. Sulfuric acid controls are becoming of increasing interest to utilities with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species, a precursor to acid aerosol/condensable emissions, and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of SCR for NOX control on some coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project is testing the effectiveness of furnace injection of four different calcium- and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents have been tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant units. One of the sorbents tested was a magnesium hydroxide slurry produced from a wet flue gas desulfurization system waste stream, from a system that employs a Thiosorbic{reg_sign} Lime scrubbing process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles into the front wall of upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests. The longer-term tests are being conducted to confirm the effectiveness of the sorbents tested over extended operation and to determine balance-of-plant impacts. This reports presents the results of the short-term tests; the long-term test results will be reported in a later document. The short-term test results showed that three of the four reagents tested, dolomite powder, commercial magnesium hydroxide slurry, and byproduct magnesium hydroxide slurry, were able to achieve 90% or greater removal of sulfuric acid compared to baseline levels. The molar ratio of alkali to flue gas sulfuric acid content (under baseline conditions) required to achieve 90% sulfuric acid removal was lowest for the byproduct magnesium hydroxide slurry. However, this result may be confounded because this was the only one of the three slurries tested with injection near the top of the furnace across from the pendant superheater platens. Injection at the higher level was demonstrated to be advantageous for this reagent over injection lower in the furnace, where the other slurries were tested.

  1. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  2. Multiple-sulfur isotope effects during photolysis of carbonyl sulfide

    E-Print Network [OSTI]

    Lin, Ying

    Laboratory experiments were carried out to determine sulfur isotope effects during ultraviolet photolysis of carbonyl sulfide (OCS) to carbon monoxide (CO) and elemental sulfur (S[superscript 0]). The OCS gas at 3.7 to 501 ...

  3. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control – Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  4. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  5. Mass-independent sulfur isotope fractionation during photochemistry of sulfur dioxide

    E-Print Network [OSTI]

    Whitehill, Andrew (Andrew Richard)

    2015-01-01

    Mass-independent sulfur isotope signatures are observed in Archean and early Paleoproterozoic sedimentary sulfate and sulfide minerals, and provide the most robust constraints on early atmospheric oxygen levels. Smaller ...

  6. Policy Analysis Changing Trends in Sulfur Emissions

    E-Print Network [OSTI]

    Jacobson, Mark

    Goddard Institute for Space Studies, New York, New York, and Disaster Prevention Research Institute, Kyoto in Asia where the pressing environ- mental problems of urban pollution, acid deposition, and climate change are intimately linked to sulfur (1). Over the last 25 years the primary energy demand in Asia has

  7. On the galactic chemical evolution of sulfur

    E-Print Network [OSTI]

    N. Ryde; D. L. Lambert

    2003-12-02

    Sulfur abundances have been determined for ten stars to resolve a debate in the literature on the Galactic chemical evolution of sulfur in the halo phase of the Milky Way. Our analysis is based on observations of the S I lines at 9212.9, 9228.1, and 9237.5 A for stars for which the S abundance was obtained previously from much weaker S I lines at 8694.0 and 8694.6 A. In contrast to the previous results showing [S/Fe] to rise steadily with decreasing [Fe/H], our results show that [S/Fe] is approximately constant for metal-poor stars ([Fe/H] < -1) at [S/Fe] = +0.3. Thus, sulfur behaves in a similar way to the other alpha elements, with an approximately constant [S/Fe] for metallicities lower than [Fe/H] = -1. We suggest that the reason for the earlier claims of a rise of [S/Fe] is partly due to the use of the weak S I 8694.0 and 8694.6 A lines and partly uncertainties in the determination of the metallicity when using Fe I lines. The S I 9212.9, 9228.1, and 9237.5 A lines are preferred for an abundance analysis of sulfur for metal-poor stars.

  8. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-01-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  9. Method to prevent sulfur accumulation in membrane electrode assembly

    DOE Patents [OSTI]

    Steimke, John L; Steeper, Timothy J; Herman, David T

    2014-04-29

    A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

  10. CATALYST EVALUATION FOR A SULFUR DIOXIDE-DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D; Hector Colon-Mercado, H

    2007-01-31

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. Testing examined the activity and stability of platinum and palladium as the electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by the concentration of the sulfuric acid electrolyte.

  11. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  12. Costs to reduce sulfur dioxide emissions

    SciTech Connect (OSTI)

    None

    1982-03-01

    Central to the resolution of the acid rain issue are debates about the costs and benefits of controlling man-made emissions of chemicals that may cause acid rain. In this briefing, the position of those who are calling for immediate action and implicating coal-fired powerplants as the cause of the problem is examined. The costs of controlling sulfur dioxide emissions using alternative control methods available today are presented. No attempt is made to calculate the benefits of reducing these emissions since insufficient information is available to provide even a rough estimate. Information is presented in two steps. First, costs are presented as obtained through straightforward calculations based upon simplifying but realistic assumptions. Next, the costs of sulfur dioxide control obtained through several large-scale analyses are presented, and these results are compared with those obtained through the first method.

  13. Evaluation of an enhanced gravity-based fine-coal circuit for high-sulfur coal

    SciTech Connect (OSTI)

    Mohanty, M.K.; Samal, A.R.; Palit, A.

    2008-02-15

    One of the main objectives of this study was to evaluate a fine-coal cleaning circuit using an enhanced gravity separator specifically for a high sulfur coal application. The evaluation not only included testing of individual unit operations used for fine-coal classification, cleaning and dewatering, but also included testing of the complete circuit simultaneously. At a scale of nearly 2 t/h, two alternative circuits were evaluated to clean a minus 0.6-mm coal stream utilizing a 150-mm-diameter classifying cyclone, a linear screen having a projected surface area of 0.5 m{sup 2}, an enhanced gravity separator having a bowl diameter of 250 mm and a screen-bowl centrifuge having a bowl diameter of 500 mm. The cleaning and dewatering components of both circuits were the same; however, one circuit used a classifying cyclone whereas the other used a linear screen as the classification device. An industrial size coal spiral was used to clean the 2- x 0.6-mm coal size fraction for each circuit to estimate the performance of a complete fine-coal circuit cleaning a minus 2-mm particle size coal stream. The 'linear screen + enhanced gravity separator + screen-bowl circuit' provided superior sulfur and ash-cleaning performance to the alternative circuit that used a classifying cyclone in place of the linear screen. Based on these test data, it was estimated that the use of the recommended circuit to treat 50 t/h of minus 2-mm size coal having feed ash and sulfur contents of 33.9% and 3.28%, respectively, may produce nearly 28.3 t/h of clean coal with product ash and sulfur contents of 9.15% and 1.61 %, respectively.

  14. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. [Quarterly] technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Chou, C.L.; Hackley, K.C.; Donnals, G.L.; Cao, J.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Shao, D. [Western Kentucky Univ., Bowling Green, KY (United States)

    1992-10-01

    Four replicate experiments of pyrolysis with quadrupole gas analyzer and ion selective electrode were conducted to monitor the release of chlorine and sulfur from a high-chlorine Illinois coal IBC-109 (0.42% chlorine on dry basis). The chlorine in coal is released solely as HCl, and the HCl release profile shows a broad peak between 250{degree}C and 600{degree}C with a maximum at 445{degree}C. In contrast, the sulfur release profile shows three peaks; the sulfur released around 370{degree}C may be derived from a labile (possibly aliphatic) component of organic sulfur, the main peak at 475{degree}C corresponds to the release of the main component (thiophenic) of organic sulfur, and the third peak at 600{degree} results from the decomposition of pyrite. Sulfur dioxide (SO{sub 2}) is the major sulfur species under an oxidizing condition in the combustion gas; additional gaseous sulfur species (COS and H{sub 2}S) are observed when the atmosphere is changed to a reducing condition. Sodium and chlorine contents in char residues determined by neutron activation analysis showed that 98% of chlorine in coal was volatilized during pyrolysis to 800{degree}C, and all the sodium is retained in the chars. The thermogravimetry-Fourier transform infrared (FTIR) spectroscopy experiments were carried out to characterize gaseous species during pyrolysis of four Illinois coals (IBC-103, -105, -106, and -109). Gas evolution profiles of sulfur (H{sub 2}S, S0{sub 2}, and COS), chlorine (HCl), and nitrogen (NH{sub 3} and HCN) species were determined. Similar release profiles of HCl and NH{sub 3} supported an interpretation that chlorine and nitrogen are closely associated in coal. COS may be formed by reaction of CO with H{sub 2}S in the gas phase.

  15. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,"(202) 586-8800",,,"10272015 9:02:05 AM" "Back to Contents","Data 1: Crude Oil Production" "Sourcekey","MCRFPUS1","MCRFPP11","MCRFPFL1","MCRFPNY1","MCRFPPA1","MCRFPV...

  16. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,"(202) 586-8800",,,"10272015 9:02:06 AM" "Back to Contents","Data 1: Crude Oil Production" "Sourcekey","MCRFPUS1","MCRFPP11","MCRFPFL1","MCRFPNY1","MCRFPPA1","MCRFPV...

  17. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    Administration" ,"For Help, Contact:","infoctr@eia.gov" ,,"(202) 586-8800",,,"2122015 2:09:18 PM" "Back to Contents","Data 1: Distillate Fuel Oil Sales for Residential Use...

  18. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,"(202) 586-8800",,,"6252015 11:11:13 AM" "Back to Contents","Data 1: Crude Oil Production" "Sourcekey","MCRFPUS2","MCRFPP12","MCRFPFL2","MCRFPNY2","MCRFPPA2","MCRFPV...

  19. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"For Help, Contact:","infoctr@eia.gov" ,,"(202) 586-8800",,,"6272015 6:10:39 PM" "Back to Contents","Data 1: Natural Gas Gross Withdrawals from Oil Wells (Summary) "...

  20. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"For Help, Contact:","infoctr@eia.gov" ,,"(202) 586-8800",,,"6272015 6:10:38 PM" "Back to Contents","Data 1: Natural Gas Gross Withdrawals from Gas Wells (Summary) "...

  1. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"For Help, Contact:","infoctr@eia.gov" ,,"(202) 586-8800",,,"6272015 6:11:20 PM" "Back to Contents","Data 1: Natural Gas Vented and Flared (Summary) "...

  2. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria (Winchester, MA); Liu, Wei (Cambridge, MA)

    1995-01-01

    A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(OF.sub.2).sub.1-n (RO.sub.1)n].sub.1-k M.sub.k, [(FO.sub.2).sub.1-n (RO.sub.1.5).sub.n ].sub.1-k M.sub.k, or [Ln.sub.x Zr.sub.1-x O.sub.2-0.5x ].sub.1-k M.sub.k wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

  3. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall to $3.43U.S.longec 188 U.S. Energy1-All Grades, Areas and

  4. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015" ,"Release Date:","12/31/2015"Monthly","10/2015"VolumeNatural GasImports from AllNet ImportsGasoline, All Grades "

  5. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015" ,"Release Date:","12/31/2015"Monthly","10/2015"VolumeNatural GasImports from AllNet ImportsGasoline, All Grades

  6. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  7. Sulfide catalysts for reducing SO2 to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

    2001-01-01

    A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

  8. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    E-Print Network [OSTI]

    Maddalena, Randy

    2012-01-01

    sulfide (H 2 S), carbonyl sulfide (OCS), sulfur dioxide (SOof hydrogen sulfide, carbonyl sulfide, methyl mercaptan,associated with the carbonyl sulfide that typically had very

  9. More Economical Sulfur Removal for Fuel Processing Plants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    crude oil it is present in sulfur-containing organic compounds which are converted into hydrocarbons and H 2 S during the removal process (hydrodesulfurization). In both cases,...

  10. Visbreaker hardware has alternate uses in low-sulfur fuel era

    SciTech Connect (OSTI)

    Toman, J.J.; Beckman, R.F. (Fluor Daniel Inc., Irvine, CA (United States))

    1993-03-22

    Several possible alternate uses for visbreaker equipment are available to refiners who must significantly increase the degree of residue processing to meet future fuel oil sulfur requirements. In both the U.S. and the European Economic Community (EEC), specifications for the sulfur content of residual fuels will likely be difficult to achieve for refiners who process high-sulfur crudes. Those refiners will have to curtail fuel oil production unless they have a significant fuel oil export market. To meet the coming specifications, residue streams will have to be either directly desulfurized or partially or totally destroyed in more-severe conversion processes such as coking, fluid-bed hydrocracking, or gasification. Under this scenario, normal operation of the visbreaker will not serve a useful purpose for the refiner. But revamping the visbreaker furnace and tower-as well as utilizing existing vessels, pumps, heat-exchange equipment, and piping-for alternative uses will require significantly less capital than would building an entirely new facility. The paper describes regulations; the role of visbreaker; integration of the visbreaker to form a new hydrotreating fractionator; and the use of the visbreaker as a preflash system.

  11. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  12. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, N.K.; Ruether, J.A.; Smith, D.N.

    1987-10-07

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

  13. Sulfur removal and comminution of carbonaceous material

    DOE Patents [OSTI]

    Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

    1988-01-01

    Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

  14. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News Publications TraditionalWith PropaneNaturalTestAn Evolutionary Arms Race for Sulfur An

  15. Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Quantifying Individual Potential Contributions of the Hybrid Sulfur Electrolyzer John A. Staser for the hybrid sulfur electrolyzer is controlled mainly by water transport in the cell. Water is required electrolyzer performance and operation. Experimental The experimental setup was the same as that described

  16. Integrated boiler, superheater, and decomposer for sulfuric acid decomposition

    DOE Patents [OSTI]

    Moore, Robert (Edgewood, NM); Pickard, Paul S. (Albuquerque, NM); Parma, Jr., Edward J. (Albuquerque, NM); Vernon, Milton E. (Albuquerque, NM); Gelbard, Fred (Albuquerque, NM); Lenard, Roger X. (Edgewood, NM)

    2010-01-12

    A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.

  17. CLASSIFICATION OF DIVISION -GRADED ALTERNATIVE ALGEBRAS

    E-Print Network [OSTI]

    Yoshii, Yoji

    CLASSIFICATION OF DIVISION Zn -GRADED ALTERNATIVE ALGEBRAS Yoji Yoshii Department of Mathematical division Zn-graded alternative algebras, is classified in this paper. Using the result, we can complete -graded alternative algebras. It turns out that they are strongly prime, and so one can apply Slater

  18. NUSTAR User Guide Print Grade Roster

    E-Print Network [OSTI]

    Fleming, Andrew J.

    . Enter the Term and select Final next to Grade Roster. 3. For a school based report, select the Academic by the Head of School Pawthway: Curriculum Management> Grading>Print Grade Roster 1. Click the Search button for a specific class, click the Specific Class option and enter the desired information into the Class Nbr field

  19. Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3

    SciTech Connect (OSTI)

    Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

    1995-09-01

    The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

  20. Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Sulfur Batteries Guangyuan Zheng, Qianfan Zhang, Judy J. Cha, Yuan Yang, Weiyang Li, Zhi Wei Seh, and Yi lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit

  1. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  2. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  3. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  4. Carbonyl sulfide: potential agent of atmospheric sulfur corrosion

    SciTech Connect (OSTI)

    Graedel, T.E.; Kammlott, G.W.; Franey, J.P.

    1981-05-08

    Laboratory exposure experiments demonstrate that carbonyl sulfide in wet air corrodes copper at 22/sup 0/C at a rate that is approximately linear with total exposure (the product of exposure time and carbonyl sulfide concentration). The corrosion rate is similar to that of hydrogen sulfide, a widely recognized corrodant. The much greater average atmospheric abundance of carbonyl sulfide compared with that of hydrogen sulfide or sulfur dioxide suggests that carbonyl sulfide may be a major agent of atmospheric sulfur corrosion.

  5. Standard test methods for chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of nuclear-grade uranyl nitrate solutions

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    1999-01-01

    1.1 These test methods cover procedures for the chemical, mass spectrometric, spectrochemical, nuclear, and radiochemical analysis of nuclear-grade uranyl nitrate solution to determine compliance with specifications. 1.2 The analytical procedures appear in the following order: Sections Determination of Uranium 7 Specific Gravity by Pycnometry 15-20 Free Acid by Oxalate Complexation 21-27 Determination of Thorium 28 Determination of Chromium 29 Determination of Molybdenum 30 Halogens Separation by Steam Distillation 31-35 Fluoride by Specific Ion Electrode 36-42 Halogen Distillate Analysis: Chloride, Bromide, and Iodide by Amperometric Microtitrimetry 43 Determination of Chloride and Bromide 44 Determination of Sulfur by X-Ray Fluorescence 45 Sulfate Sulfur by (Photometric) Turbidimetry 46 Phosphorus by the Molybdenum Blue (Photometric) Method 54-61 Silicon by the Molybdenum Blue (Photometric) Method 62-69 Carbon by Persulfate Oxidation-Acid Titrimetry 70 Conversion to U3O8 71-74 Boron by ...

  6. EERE Website Content Checklist

    Broader source: Energy.gov [DOE]

    This checklist is a tool to guide EERE content developers and editors in creating and reviewing content for websites.

  7. An electrochemical Claus process for sulfur recovery

    SciTech Connect (OSTI)

    Pujare, N.U.; Tsai, K.J.; Sammuells, A.F. (Eltron Research, Inc., Aurora, IL (US))

    1989-12-01

    Electrochemical oxidation of H{sub 2}S to give sulfur and water was achieved at 900{degrees}C using fuel cells possessing the general configuration where anode electrocatalysts experimentally investigated for promoting the subject oxidation reaction included WS{sub 2} and the thiospinels CuNi{sub 2}S{sub 4}, CuCo{sub 2}S{sub 4}, CuFe{sub 2}S{sub 4}, and NiFe{sub 2}S{sub 4}. The predominant oxidizable electroactive species present in the fuel cell anode compartment was suggested to be hydrogen originating from the initial thermal dissociation of H{sub 2}S (H{sub 2}S {r reversible} H{sub 2} + 1/2 S{sub 2}) at fuel cell operating temperatures. Rapid anode kinetics were found for the anodic reaction with the empirical trend for exchange currents (i{sub o}) per geometric area being found to be NiFe{sub 2}S{sub 4}{gt}WS{sub 2}{gt}CuCo{sub 2}S{sub 4}{gt}CuFe{sub 2}S{sub 4}{approx equal}NiCo{sub 2}S{sub 4}{gt}CuNi{sub 2}S{sub 4}.

  8. COHEN-MACAULAYNESS IN GRADED ALGEBRAS Joseph ...

    E-Print Network [OSTI]

    1910-30-30

    Karen Smith remarked that Sancho de Salas's sequence ((SS) below) could be developed for arbitrary graded rings. More substantially, the observation.

  9. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  10. Influence of frequency, grade, moisture and temperature on Green River oil shale dielectric properties and electromagnetic heating processes

    SciTech Connect (OSTI)

    Hakala, J. Alexandra [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Stanchina, William [Univ. of Pittsburgh, PA (United States); National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Soong, Yee [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Hedges, Sheila [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

    2011-01-01

    Development of in situ electromagnetic (EM) retorting technologies and design of specific EM well logging tools requires an understanding of various process parameters (applied frequency, mineral phases present, water content, organic content and temperature) on oil shale dielectric properties. In this literature review on oil shale dielectric properties, we found that at low temperatures (<200° C) and constant oil shale grade, both the relative dielectric constant (?') and imaginary permittivity (?'') decrease with increased frequency and remain constant at higher frequencies. At low temperature and constant frequency, ?' decreases or remains constant with oil shale grade, while ?'' increases or shows no trend with oil shale grade. At higher temperatures (>200º C) and constant frequency, epsilon' generally increases with temperature regardless of grade while ?'' fluctuates. At these temperatures, maximum values for both ?' and ?'' differ based upon oil shale grade. Formation fluids, mineral-bound water, and oil shale varve geometry also affect measured dielectric properties. This review presents and synthesizes prior work on the influence of applied frequency, oil shale grade, water, and temperature on the dielectric properties of oil shales that can aid in the future development of frequency- and temperature-specific in situ retorting technologies and oil shale grade assay tools.

  11. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and...

    U.S. Energy Information Administration (EIA) Indexed Site

    1996 ... 72.3 79.1 78.8 80.6 76.7 67.3 68.7 75.9 78.4 73.2 63.9 1997 January ... 76.6 82.7 84.1 83.7 81.2 71.0 73.8...

  12. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and...

    U.S. Energy Information Administration (EIA) Indexed Site

    1996 January ... 62.7 68.1 69.9 69.7 67.1 57.5 59.9 66.9 68.8 64.1 55.1 February ... 64.2 70.1 70.7 71.2 68.3 59.3 61.1 67.8 69.6...

  13. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative FuelsMonthly","10/2015" ,"ReleaseVolumeMonthly","10/2015"NaturalMonthly","10/2015"

  14. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13

  15. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13

  16. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13

  17. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13 1996

  18. Table 17. U.S. No. 2 Diesel Fuel Prices by Sulfur Content and Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,137 4,9743Number63 January13

  19. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.6 73.975.6 81.7 84.156.9 63.4

  20. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.6 73.975.6 81.7 84.156.9

  1. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.6 73.975.6 81.7 84.156.976.6

  2. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.6 73.975.6 81.7

  3. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type, and PAD District

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24, 20145,1374.6 73.975.6 81.745.2 48.3 51.7

  4. A FOURTH GRADE EXPERIENCE Donald G. Saari

    E-Print Network [OSTI]

    Stanford, Kyle

    A FOURTH GRADE EXPERIENCE Donald G. Saari Northwestern University, Departments of Mathematics and of Economics August, 1991 "We've been trying to tell you you're wrong!" With this severe reprimand, a fourth. But I fought to disguise my growing panic when informed that I was to talk to a fourth grade class. What

  5. ASTM A-710 GRADE B High Performance

    E-Print Network [OSTI]

    Carbon Equivalent 70 ksi Grade Low Temperature Tough Improved Weldability Improved Weatherability Life) Steel Beams used in the construction of the Lake Villa Bridge Page 10: Semi-automatic welding of NUCu 70-lbs at -80°F. Due to its very low carbon equivalent, NUCu 70W (ASTM A710 Grade B) steel generally does

  6. COHEN-MACAULAYNESS IN GRADED ALGEBRAS Joseph ...

    E-Print Network [OSTI]

    1910-30-30

    For any R-ideal m, and E := X ?R (R/m), there is an exact sequence of graded ... being multiplication by (?1)d (recall that the differentials in ?C[?1] are ..... [MR] J. Matijevic, P. Roberts, A conjecture of Nagata on graded Cohen-Macaulay rings, J

  7. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  8. Weigh options for meeting future gasoline sulfur specifications

    SciTech Connect (OSTI)

    Johnson, T.E.

    1997-03-01

    The most frequently mentioned methods for reducing pool gasoline sulfur to the 50-ppm range are FCC feed hydrotreating and desulfurization of heavy cat naptha (HCN). Of these, cat feed hydrotreating (CFH) is preferred because of the compelling economics of improved FCC gasoline yield. Also, the additional C{sub 3}/C{sub 4} olefin yield opens up the possibility of additional production of sulfur-free alkylate and oxygenate. In addition to the obvious yield benefits, the ability to upgrade lower quality, higher sulfur stocks for inclusion in the FCC charge slate, while lowering flue gas SO{sub x} emissions, is also advantageous to the refiner. However, depending o the level of FCC feed sulfur and the severity of hydrotreating used, it may not be possible to meet 50-ppm sulfur in the gasoline pool. Two possible solutions to this problem are to use: (1) a very severe cat feed hydrotreating operation (i.e., 98%-plus desulfurization), (2) partial conversion hydrocracking.

  9. Gas phase reaction of sulfur trioxide with water vapor

    SciTech Connect (OSTI)

    Kolb, C.E.; Molina, M.J.; Jayne, J.T.; Meads, R.F.; Worsnop, D.R.

    1994-12-31

    Sulfur trioxide (SO3) has long been known to react with water to produce sulfuric acid (H2S04). It has been commonly assumed that the gas phase reaction in the Earth`s atmosphere between SO3 and water vapor to produce sulfuric acid vapor is an important step in the production of sulfuric acid aerosol particles. The kinetics of the gas phase reaction of SO3 with water vapor have previously been studied by Castleman and co-workers, Wang et al and Reiner and Arnold. Each of these studies was carried out in a flow reactor, with the first two studies performed at low pressure (1-10 Torr) and the latter from approx. 30 to 260 Torr. Each of these studies measured SO3 decays over a range of H2O vapor levels, obtaining data consistent with interpreting the reaction of gaseous SO3 and H2O as a bimolecular process. It is not clear why previous experimental studies failed to observe a nonlinear dependence of SO3 consumption on water vapor concentration. It is probable that sufficient water dimer exists in much of the Earth`s atmosphere to allow dimer reactions to participate in sulfuric acid vapor formation.

  10. ADDITIVE TESTING FOR IMPROVED SULFUR RETENTION: PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Amoroso, J.; Fox, K.

    2011-09-07

    The Savannah River National Laboratory is collaborating with Alfred University to evaluate the potential for additives in borosilicate glass to improve sulfur retention. This preliminary report provides further background on the incorporation of sulfur in glass and outlines the experiments that are being performed by the collaborators. A simulated waste glass composition has been selected for the experimental studies. The first phase of experimental work will evaluate the impacts of BaO, PbO, and V{sub 2}O{sub 5} at concentrations of 1.0, 2.0, and 5.0 wt % on sulfate retention in simulated high level waste borosilicate glass. The second phase of experimental work will evaluate the effects of time at the melt temperature on sulfur retention. The resulting samples will be characterized to determine the amount of sulfur remaining as well as to identify the formation of any crystalline phases. The results will be used to guide the future selection of frits and glass forming chemicals in vitrifying Department of Energy wastes containing high sulfur concentrations.

  11. Final Report - Management of High Sulfur HLW, VSL-13R2920-1, Rev. 0, dated 10/31/2013

    SciTech Connect (OSTI)

    Kruger, Albert A.; Gan, H.; Pegg, I. L.; Feng, Z.; Gan, H,; Joseph, I.; Matlack, K. S.

    2013-11-13

    The present report describes results from a series of small-scale crucible tests to determine the extent of corrosion associated with sulfur containing HLW glasses and to develop a glass composition for a sulfur-rich HLW waste stream, which was then subjected to small-scale melter testing to determine the maximum acceptable sulfate loadings. In the present work, a new glass formulation was developed and tested for a projected Hanford HLW composition with sulfate concentrations high enough to limit waste loading. Testing was then performed on the DM10 melter system at successively higher waste loadings to determine the maximum waste loading without the formation of a separate sulfate salt phase. Small scale corrosion testing was also conducted using the glass developed in the present work, the glass developed in the initial phase of this work [26], and a high iron composition, all at maximum sulfur concentrations determined from melter testing, in order to assess the extent of Inconel 690 and MA758 corrosion at elevated sulfate contents.

  12. Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report

    SciTech Connect (OSTI)

    Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S.

    1989-04-28

    This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

  13. SEM CR GRADE Intro to Chem Eng 1

    E-Print Network [OSTI]

    New Hampshire, University of

    Elective Option Elective 2 SEM CR GRADE 4 CHE 705 or CHE 712 Fossil Fuels or Nuclear Engineering SEM CR GRADE 4 CHE 712 or CHE 705 Nuclear Engineering or Fossil Fuels STUDENT NAME ADVISOR NAME #12;Chemical Chemistry SEM CR GRADE 3 CHE 601 Fluid Mechanics SEM CR GRADE 3 CHE 604 ChE Thermodynamics SEM CR GRADE 4

  14. SEM CR GRADE Intro to Chem Eng 1

    E-Print Network [OSTI]

    New Hampshire, University of

    or Nuclear Engineering SEM CR GRADE 4 CHE 712 or CHE 705 Nuclear Engineering or Fossil Fuels Sem: 16 Cum: 132 students see "Advising Notes" on back page SEM CR GRADE 3 CHE 601 Fluid Mechanics SEM CR GRADE 3 CHE 604 Ch of 3 SEM CR GRADE 4 CHE 761 Biochemical Engineering SEM CR GRADE 4 CHE 705 or CHE 712 Fossil Fuels

  15. SEM CR GRADE Intro to Chem Eng 1

    E-Print Network [OSTI]

    New Hampshire, University of

    E Majors Energy Option Page 1 of 3 SEM CR GRADE 4 CHE 705 or CHE 712 Fossil Fuels or Nuclear Engineering Chemistry SEM CR GRADE 3 CHE 601 Fluid Mechanics SEM CR GRADE 3 CHE 604 ChE Thermodynamics SEM CR GRADE 3 Energy Option Elective Option Elective 2 SEM CR GRADE 4 CHE 712 or CHE 705 Nuclear Engineering or Fossil

  16. SEM CR GRADE Intro to Chem Eng 1

    E-Print Network [OSTI]

    Pringle, James "Jamie"

    SEM CR GRADE 3 ENE 612* Unit Operations Lab 1 SEM CR GRADE 4 Tech Elective Tech Elective 1 SEM CR GRADE 4 Tech Elective Tech Elective 2 SEM CR GRADE 4 Tech Elective Tech Elective 3 SEM CR GRADE 4 ENE-IP; Red ­ General Education; Black - Other Environmental Engineering Program University of New Hampshire

  17. Enhancements to passive warning devices for use at railroad-highway grade crossings 

    E-Print Network [OSTI]

    Mynier, Charles Leroy

    1992-01-01

    ENHANCEMENTS TO PASSIVE WARNING DEVICES FOR USE AT RAILROAD-HIGHWAY GRADE CROSSINGS A Thesis by CHARLES LEROY MYNIER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1992 Major Subject: Civil Engineering ENHANCEMENTS TO PASSIVE WARNING DEVICES FOR USE AT RAILROAD-HIGHWAY GRADE CROSSINGS A Thesis by C~S LEROY MYNIER Approved as to style and content by: Neilon wan (Chair of ommittee...

  18. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  19. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01

    S breakthrough time and sulfur capture capacity increased asspace velocity on H 2 S on sulfur capture capacity for H 2 Sbased on the optimal sulfur capture capacity under CE-CERT

  20. Preliminary Investigation of Sulfur Loading in Hanford LAW Glass

    SciTech Connect (OSTI)

    Vienna, John D.; Hrma, Pavel R.; Buchmiller, William C.; Ricklefs, Joel S.

    2004-04-01

    A preliminary estimate was developed for loading limits for high-sulfur low-activity waste (LAW) feeds that will be vitrified into borosilicate glass at the Hanford Site in the waste-cleanup effort. Previous studies reported in the literature were consulted to provide a basis for the estimate. The examination of previous studies led to questions about sulfur loading in Hanford LAW glass, and scoping tests were performed to help answer these questions. These results of these tests indicated that a formulation approach developed by Vienna and colleagues shows promise for maximizing LAW loading in glass. However, there is a clear need for follow-on work. The potential for significantly lowering the amount of LAW glass produced at Hanford (after the initial phase of processing) because of higher sulfur tolerances may outweigh the cost and effort required to perform the necessary testing.

  1. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report

    SciTech Connect (OSTI)

    NONE

    1997-01-01

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

  2. Direct sulfur recovery during sorbent regeneration. Final report

    SciTech Connect (OSTI)

    Nelson, S.G.; Little, R.C. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1993-08-01

    The objective of this research project was to improve the direct elemental sulfur yields that occur during the regeneration of SO{sub 2}-saturated MgO-vermiculite sorbents (MagSorbents) by examining three approaches or strategies. The three approaches were regeneration-gas recycle, high-pressure regeneration, and catalytic reduction of the SO{sub 2} gas using a new catalyst developed by Research Triangle Institute (RTI). Prior to the project, Sorbent Technologies Corporation (Sorbtech) had developed a sorbent-regeneration process that yielded directly a pure elemental sulfur product. In the process, typically about 25 to 35 percent of the liberated S0{sub 2} was converted directly to elemental sulfur. The goal of this project was to achieve a conversion rate of over 90 percent. Good success was attained in the project. About 90 percent or more conversion was achieved with two of the approaches that were examined, regeneration-gas recycle and use of the RTI catalyst. Of these approaches, regeneration-gas recycle gave the best results (essentially 100 percent conversion in some cases). In the regeneration-gas recycle approach, saturated sorbent is simply heated to about 750{degree}C in a reducing gas (methane) atmosphere. During heating, a gas containing elemental sulfur, water vapor, H{sub 2}S, S0{sub 2}, and C0{sub 2} is evolved. The elemental sulfur and water vapor in the gas stream are condensed and removed, and the remaining gas is recycled back through the sorbent bed. After several recycles, the S0{sub 2} and H{sub 2}S completely disappear from the gas stream, and the stream contains only elemental sulfur, water vapor and C0{sub 2}.

  3. Improving fractionation lowers butane sulfur level at Saudi gas plant

    SciTech Connect (OSTI)

    Harruff, L.G.; Martinie, G.D.; Rahman, A. [Saudi Arabian Oil Co., Dhahran (Saudi Arabia)

    1998-10-12

    Increasing the debutanizer reflux/feed ratio to improve fractionation at an eastern Saudi Arabian NGL plant reduced high sulfur in the butane product. The sulfur resulted from dimethyl sulfide (DMS) contamination in the feed stream from an offshore crude-oil reservoir in the northern Arabian Gulf. The contamination is limited to two northeastern offshore gas-oil separation plants operated by Saudi Arabian Oil Co. (Saudi Aramco) and, therefore, cannot be transported to facilities outside the Eastern Province. Two technically acceptable solutions for removing this contaminant were investigated: 13X molecular-sieve adsorption of the DMS and increased fractionation efficiency. The latter would force DMS into the debutanizer bottoms.

  4. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, J.B.L.; Gorski, A.J.; Daniels, E.J.

    1993-05-18

    A process is described for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is [dis]associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  5. Hydrogen and sulfur recovery from hydrogen sulfide wastes

    DOE Patents [OSTI]

    Harkness, John B. L. (Naperville, IL); Gorski, Anthony J. (Woodridge, IL); Daniels, Edward J. (Oak Lawn, IL)

    1993-01-01

    A process for generating hydrogen and elemental sulfur from hydrogen sulfide waste in which the hydrogen sulfide is associated under plasma conditions and a portion of the hydrogen output is used in a catalytic reduction unit to convert sulfur-containing impurities to hydrogen sulfide for recycle, the process also including the addition of an ionizing gas such as argon to initiate the plasma reaction at lower energy, a preheater for the input to the reactor and an internal adjustable choke in the reactor for enhanced coupling with the microwave energy input.

  6. Structural insight into the assembly of iron-sulfur clusters and their function in radical generation

    E-Print Network [OSTI]

    Vey, Jessica L. (Jessica Lynn)

    2008-01-01

    This thesis addresses two emerging areas in the study of iron-sulfur cluster biochemistry: bioassembly of iron-sulfur clusters, and their involvement in initiation of radical chemistry. The structure of a cysteine desulfurase ...

  7. KINETICS AND MECHANISM FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDE ON CARBON IN AQUEOUS SUSPENSIONS

    E-Print Network [OSTI]

    Brodzinsky, R.

    2012-01-01

    AND MECHANISM FOR THE CATALYTIC OXIDATION OF SULFUR DIOXIDEmechanism for the catalytic oxidation of in an aqueous sus1ECHANISf 1 1 FOR TilE CATALYTIC OXIDATION OF SULFUR DIOXIDE

  8. A design strategy applied to sulfur resistant lean NOx̳ automotive catalysts

    E-Print Network [OSTI]

    Tang, Hairong

    2005-01-01

    Catalyst poisoning due to sulfur compounds derived from fuel sulfur presents a major challenge, intractable thus far, to development of many advanced technologies for automotive catalysts such as the lean NOx, trap. Under ...

  9. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  10. Functionally Graded Materials for Manufacturing Tools and Dies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Functionally Graded Materials for Manufacturing Tools and Dies Functionally Graded Materials for Manufacturing Tools and Dies New Material Processes Improve the Performance and...

  11. Making the Grade: Washington School District Invest in Energy...

    Office of Environmental Management (EM)

    Making the Grade: Washington School District Invest in Energy Efficiency Making the Grade: Washington School District Invest in Energy Efficiency September 10, 2015 - 11:55am...

  12. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H. [Voest-Alpine Stahl Linz GmbH (Austria)

    1996-12-31

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  13. Low Quality Natural Gas Sulfur Removal and Recovery CNG Claus Sulfur Recovery Process

    SciTech Connect (OSTI)

    Klint, V.W.; Dale, P.R.; Stephenson, C.

    1997-10-01

    Increased use of natural gas (methane) in the domestic energy market will force the development of large non-producing gas reserves now considered to be low quality. Large reserves of low quality natural gas (LQNG) contaminated with hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}) and nitrogen (N) are available but not suitable for treatment using current conventional gas treating methods due to economic and environmental constraints. A group of three technologies have been integrated to allow for processing of these LQNG reserves; the Controlled Freeze Zone (CFZ) process for hydrocarbon / acid gas separation; the Triple Point Crystallizer (TPC) process for H{sub 2}S / C0{sub 2} separation and the CNG Claus process for recovery of elemental sulfur from H{sub 2}S. The combined CFZ/TPC/CNG Claus group of processes is one program aimed at developing an alternative gas treating technology which is both economically and environmentally suitable for developing these low quality natural gas reserves. The CFZ/TPC/CNG Claus process is capable of treating low quality natural gas containing >10% C0{sub 2} and measurable levels of H{sub 2}S and N{sub 2} to pipeline specifications. The integrated CFZ / CNG Claus Process or the stand-alone CNG Claus Process has a number of attractive features for treating LQNG. The processes are capable of treating raw gas with a variety of trace contaminant components. The processes can also accommodate large changes in raw gas composition and flow rates. The combined processes are capable of achieving virtually undetectable levels of H{sub 2}S and significantly less than 2% CO in the product methane. The separation processes operate at pressure and deliver a high pressure (ca. 100 psia) acid gas (H{sub 2}S) stream for processing in the CNG Claus unit. This allows for substantial reductions in plant vessel size as compared to conventional Claus / Tail gas treating technologies. A close integration of the components of the CNG Claus process also allow for use of the methane/H{sub 2}S separation unit as a Claus tail gas treating unit by recycling the CNG Claus tail gas stream. This allows for virtually 100 percent sulfur recovery efficiency (virtually zero SO{sub 2} emissions) by recycling the sulfur laden tail gas to extinction. The use of the tail gas recycle scheme also deemphasizes the conventional requirement in Claus units to have high unit conversion efficiency and thereby make the operation much less affected by process upsets and feed gas composition changes. The development of these technologies has been ongoing for many years and both the CFZ and the TPC processes have been demonstrated at large pilot plant scales. On the other hand, prior to this project, the CNG Claus process had not been proven at any scale. Therefore, the primary objective of this portion of the program was to design, build and operate a pilot scale CNG Claus unit and demonstrate the required fundamental reaction chemistry and also demonstrate the viability of a reasonably sized working unit.

  14. A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy

    E-Print Network [OSTI]

    Paytan, Adina

    A. Paytan and E.T. Gray Chapter 9 Sulfur Isotope Stratigraphy Abstract: The sulfur isotopic.4. Measurement and Materials for Sulfur Isotope Stratigraphy 171 9.4.1. Isotope Analyses 171 9.4.2. Materials. The features in the record can also be used to correlate between stratigraphic sections and sequences

  15. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India*

    E-Print Network [OSTI]

    The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India* A.L. Ganesan of methane, nitrous oxide and sulfur hexafluoride in Northeast India A. L. Ganesan1, A. Chatterjee2, R. G-frequency atmospheric measurements of methane (CH4), nitrous oxide (N2O) and sulfur hexafluo- ride (SF6) from Darjeeling

  16. Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions

    E-Print Network [OSTI]

    Denver, University of

    sulfur diesel fuel is less expensive due to reduced taxes and as such may be prone to illegal use in on-road November 2005; published online 18 January 2006 A remote sensor for measuring on-road vehicles passing of reducing sulfur in fuel for all mobile sources. This process begins with ultralow sulfur on-road diesel

  17. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    DOE Patents [OSTI]

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  18. Vapor phase elemental sulfur amendment for sequestering mercury in contaminated soil

    DOE Patents [OSTI]

    Looney, Brian B.; Denham, Miles E.; Jackson, Dennis G.

    2014-07-08

    The process of treating elemental mercury within the soil is provided by introducing into the soil a heated vapor phase of elemental sulfur. As the vapor phase of elemental sulfur cools, sulfur is precipitated within the soil and then reacts with any elemental mercury thereby producing a reaction product that is less hazardous than elemental mercury.

  19. [ Table of Contents

    E-Print Network [OSTI]

    Dommel, Hans-Peter

    it can serve companies in day-to- day business. The commercialization of the World Wide Web in the late standards, and avoid problems with freeloading, hacking, spurious presence and low-grade links. These issues

  20. Model Investment Grade Audit and Project Proposal

    Broader source: Energy.gov [DOE]

    Information and documents for conducting an investment grade audit to evaluate potential measures and presenting a project proposal for a set of bundled measures that deliver savings to pay for the project over the finance term.

  1. Grading of lumber using stress waves 

    E-Print Network [OSTI]

    Bethi, Rajeshwar

    1994-01-01

    The goal of this research was to develop stress wave grading technology suitable for small lumber mills. Specific goals include: 1) develop an ultrasonic probe configuration to facilitate real-time grain angle and edge knot measurement, 2) determine...

  2. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2004-11-02

    The disclosure is directed to sorbent compositions for removing reduced sulfur species (e.g., H.sub.2 S, COS and CS.sub.2) a feed stream. The sorbent is formed from a multi-phase composition including a zinc titanate phase and a zinc oxide-aluminate phase. The sorbent composition is substantially free of unreacted alumina.

  3. Catalyst added to Claus furnace reduces sulfur losses

    SciTech Connect (OSTI)

    Luinstra, E.A.; d'Haene, P.E. (Shell Canada Ltd., Toronto, ON (Canada). Oakville Research Centre)

    1989-07-01

    Several substances effectively catalyze the reduction of carbon disulfide in Claus gas streams at Claus reaction furnace conditions (about 1,000{sup 0}C). Some conversion of carbonyl sulfide also occurs. Carbon disulfide and carbonyl sulfide as well-known problem compounds that reduce sulfur recovery efficiency in many sulfur recovery plants. Installation of a suitable catalytic material in the reaction furnace promises significant improvement of Claus plant efficiency, and prolonged life of the catalytic converters. Almost every Claus sulfur recovery plant makes some carbon disulfide (CS/sub 2/) and carbonyl sulfide (COS) in the reaction furnace, and in many of these plants, these compounds constitute a significant problem. CS/sub 2/ and COS often comprise more than 50% of sulfur losses in the tail gas. This article reexamines the issue of CS/sub 2/ and COS in the Claus plant. The relative importance of these two troublesome components is explored with data accumulated from Shell Canada Claus plants. The authors discuss which factors tend to produce these components. Then a method for reducing CS/sub 2/ and COS virtually at the source will be introduced.

  4. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  5. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  6. Auction design and the market for sulfur dioxide emissions

    E-Print Network [OSTI]

    Joskow, Paul L.

    1996-01-01

    Title IV of the Clean Air Act Amendments of 1990 created a market for electric utility emissions of sulfur dioxide (SO2). Recent papers have argued that flaws in the design of the auctions that are part of this market have ...

  7. Hydroprocessing key issue in low-sulfur' era

    SciTech Connect (OSTI)

    Not Available

    1993-07-26

    Refiners gave heavy attention to hydroprocessing operations at the most recent National Petroleum Refiners Association annual question and answer session on refining and petrochemical technology. Among the topics covered were diesel color, blending to meet diesel sulfur specs, and ammonia injection in hydrocracking units. The panelists also related their experiences with increasing vacuum gas oil conversion in hydrocracking operations. These discussions are reproduced here.

  8. Sulfur controls edge closer in acid-rain debate

    SciTech Connect (OSTI)

    Not Available

    1984-10-04

    The role of airborne sulfur emissions from midwestern and southern coal-fired power plants in exacerbating the acid rain problem is discussed. This problem is discussed from the standpoint of legislation, compliance costs, scrubber performance and cost, and chemistry of acid rains.

  9. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  10. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2000-12-01

    This document summarizes progress on the Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2000 through September 30, 2000. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid will also be determined, as will the removal of arsenic, a known poison for NOX selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), First Energy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the second reporting period for the subject Cooperative Agreement. During this period, the first of four short-term sorbent injection tests were conducted at the First Energy Bruce Mansfield Plant. This test determined the effectiveness of dolomite injection through out-of-service burners as a means of controlling sulfuric acid emissions from this unit. The tests showed that dolomite injection could achieve up to 95% sulfuric acid removal. Balance of plant impacts on furnace slagging and fouling, air heater fouling, ash loss-on-ignition, and the flue gas desulfurization system were also determined. These results are presented and discussed in this report.

  11. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M; Lytle, J.M.; Ruch, R.R.; Kruse, C.W.; Chaven, C.; Hackley, K.C.; Hughes, R.E.; Harvey, R.D.; Frost, J.K. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States); Huffman, G.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States)

    1992-09-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal preoxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation.

  12. ENGINEERING EVALUATION OF HOT-GAS DESULFURIZATION WITH SULFUR RECOVERY

    SciTech Connect (OSTI)

    G.W. ROBERTS; J.W. PORTZER; S.C. KOZUP; S.K. GANGWAL

    1998-05-31

    Engineering evaluations and economic comparisons of two hot-gas desulfurization (HGD) processes with elemental sulfur recovery, being developed by Research Triangle Institute, are presented. In the first process, known as the Direct Sulfur Recovery Process (DSRP), the SO{sub 2} tail gas from air regeneration of zinc-based HGD sorbent is catalytically reduced to elemental sulfur with high selectivity using a small slipstream of coal gas. DSRP is a highly efficient first-generation process, promising sulfur recoveries as high as 99% in a single reaction stage. In the second process, known as the Advanced Hot Gas Process (AHGP), the zinc-based HGD sorbent is modified with iron so that the iron portion of the sorbent can be regenerated using SO{sub 2} . This is followed by air regeneration to fully regenerate the sorbent and provide the required SO{sub 2} for iron regeneration. This second-generation process uses less coal gas than DSRP. Commercial embodiments of both processes were developed. Process simulations with mass and energy balances were conducted using ASPEN Plus. Results show that AHGP is a more complex process to operate and may require more labor cost than the DSRP. Also capital costs for the AHGP are higher than those for the DSRP. However, annual operating costs for the AHGP appear to be considerably less than those for the DSRP with a potential break-even point between the two processes after just 2 years of operation for an integrated gasification combined cycle (IGCC) power plant using 3 to 5 wt% sulfur coal. Thus, despite its complexity, the potential savings with the AHGP encourage further development and scaleup of this advanced process.

  13. ContentsContents3399the normal distribution

    E-Print Network [OSTI]

    Vickers, James

    ContentsContents3399the normal distribution 1. The normal distribution 2. The normal approximation to the binomial distribution 3. Sums and differences of random variables Learning outcomes In a previous Workbook of a continuous random variables: the normal distribution. The probabilities of the normal distribution have

  14. ContentsContents4343Regression and correlation

    E-Print Network [OSTI]

    Vickers, James

    ContentsContents4343Regression and correlation 1. Regression 2. Correlation Learning outcomes You. 1 #12;Regression 43.1 Introduction Problems in engineering often involve the exploration of the relationship(s) between two or more variables. The technique of regression analysis is very useful and well

  15. ContentsContents1133integration integration

    E-Print Network [OSTI]

    Vickers, James

    ContentsContents1133integration integration 1. Basic concepts of integration 2. Definite integrals 3. The area bounded by a curve 4. Integration by parts 5. Integration by substitution and using partial fractions 6. Integration of trigonometric functions Learning outcomes In this workbook you

  16. Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996

    SciTech Connect (OSTI)

    NONE

    1996-12-01

    More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

  17. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  18. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C. (Windsor, CT)

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  19. Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    NONE

    1997-12-31

    The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

  20. American-Made SRF Cavity Makes the Grade | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    https:www.jlab.orgnewsreleasesamerican-made-srf-cavity-makes-grade Submitted: Thursday, September 17, 2009 - 12...

  1. CONTENT MODEL HOW-TO

    Energy Science and Technology Software Center (OSTI)

    003241MLTPL00 Content Model Guidelines  https://github.com/usgin/usginspecs/wiki/Content-Model-Guidelines 

  2. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect (OSTI)

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  3. Emission of volatile sulfur compounds during composting of municipal solid waste (MSW)

    SciTech Connect (OSTI)

    Zhang, Hongyu; Schuchardt, Frank; Li, Guoxue; Yang, Jinbing; Yang, Qingyuan

    2013-04-15

    Highlights: ? We compare the volatile sulfur compounds (VSCs) emissions during three types of municipal solid wastes (MSWs) composting. ? The VSCs released from the kitchen waste composting was significantly higher than that from 15–80 mm fraction of MSW. ? Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. ? Addition of 20% cornstalks could significantly reduce the VSCs emissions during kitchen waste composting. - Abstract: Volatile sulfur compounds (VSCs) are the main source for malodor from composting plants. In this study, the VSCs generated from composting of 15–80 mm municipal solid waste (T0), kitchen waste (T1) and kitchen waste mixed dry cornstalks (T2) were measured in 60 L reactors with forced aeration for a period of 30 days. The VSCs detected in all treatments were hydrogen sulfide (H{sub 2}S), methyl mercaptan (MM), dimethyl sulfide (DMS), carbon bisulfide (CS{sub 2}) and dimethyl disulfide (DMDS). Over 90% of the VSCs emissions occurred during the first 15 days, and reached their peak values at days 4–7. The emission profiles of five VSCs species were significantly correlated with internal materials temperature and outlet O{sub 2} concentration (p < 0.05). Total emissions of the VSCs were 216.1, 379.3 and 126.0 mg kg{sup ?1} (dry matter) for T0, T1 and T2, respectively. Among the five VSCs, H{sub 2}S was the most abundant compound with 39.0–43.0% of total VSCs released. Composting of kitchen waste from separate collection posed a negative influence on the VSC and leachate production because of its high moisture content. An addition of dry cornstalks at a mixing ratio of 4:1 (wet weight) could significantly reduce the VSCs emissions and avoid leachate. Compared to pure kitchen waste, VSCs were reduced 66.8%.

  4. Education system Indonesia There is some variation in the grading systems used for individual subjects in Indonesia. These variations include number grade or

    E-Print Network [OSTI]

    New South Wales, University of

    Education system ­ Indonesia There is some variation in the grading systems used for individual subjects in Indonesia. These variations include number grade or point systems, description grades, letter

  5. Method of making sulfur-resistant composite metal membranes

    DOE Patents [OSTI]

    Way, J. Douglas (Boulder, CO) [Boulder, CO; Lusk, Mark (Golden, CO) [Golden, CO; Thoen, Paul (Littleton, CO) [Littleton, CO

    2012-01-24

    The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200.degree. C. and about 1200.degree. C. to form a sulfur-resistant, composite PdAu alloy membrane.

  6. Modeling sulfur dioxide capture in a pulverized coal combustor

    SciTech Connect (OSTI)

    Nair, R.B.; Yavuzkurt, S. [Pennsylvania State Univ., University Park, PA (United States)

    1997-04-01

    The formation and capture of sulfur dioxide in a pulverized coal combustor is investigated. A two-dimensional, steady, axisymmetric code, PCGC-2 (Pulverized Coal Gasification and Combustion-two Dimensional), originally developed at Brigham Young University, has been used to simulate combustion of the pulverized coal. This paper represents part of a project to investigate simultaneously enhancing sulfur capture and particulate agglomeration in combustor effluents. Results from the code have been compared to experimental data obtained from MTCI`s (Manufacturing Technology and Conversion International) test pulse combustor, which generates sound pressure levels of {approximately}180 dB. The overall goal behind the pulse combustor program at MTCI is to develop combustors for stationary gas turbines that use relatively inexpensive coal-based fuels. This study attempts to model the capture of sulfur dioxide when injected into a pulse combustor firing micronized coal. While this work does not presume to model the complex gas flow-field generated by the pulsating flow, the effects of the acoustic field are expressed by increased heat and mass transfer to the particles (coal/sorbent) in question. A comprehensive calcination-sintering-sulfation model for single particles was used to model the capture of sulfur dioxide by limestone sorbent. Processes controlling sulfation are external heat and mass transfer, pore diffusion, diffusion through the product layer of CaSO{sub 4}, sintering, and calcination. The model was incorporated into the PCGC-2 program. Comparisons of exit concentrations of SO{sub 2} showed a fairly good agreement (within {approximately}10 percent) with the experimental results from MTCI.

  7. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  8. Sibley station low-sulfur coal conversion program

    SciTech Connect (OSTI)

    Rupinskas, R.L. [Sargent & Lundy LLC, Chicago, IL (United States); Rembold, D.F. [Missouri Public Service, Kansas City, MO (United States)

    1995-03-01

    After embarking on an upgrade project in 1986 that was designed to allow efficient and reliable operation of its coal-fired Sibley station through 2010, Missouri Public Service (MPS) faced the uncertainty of impending acid-rain legislation. To protect its investment in the Sibley Rebuild Program, the utility evaluated compliance options based on the emerging legislation and concluded that switching to low-sulfur coal offered the least-cost compliance approach. Compared to installing a scrubber, switching to a low-sulfur coal was also more straightforward, although not without challenges and complications. This paper reviews the Sibley low-sulfur coal conversion program. At Sibley, fuel switching was chosen only after numerous internal and external studies; it withstood late challenges from natural gas and allowance trading. Switching demanded additional equipment to blend Power River Basin coals and other coals, and demanded additional and upgraded protective equipment in the areas of fire protection, dust collection, and explosion prevention. In the year since the coal conversion project was completed the facility has operated reliably, the economic benefits of the lower cost Powder River Basin coals have been realized, and the station has also met the requirements of both phases of the acid rain legislation. Fuel switching at Sibley required a team approach and careful analysis. The coal conversion project also required attention and dedication by team members in order to minimize fuel costs while maintaining optimum plant efficiency and availability.

  9. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  10. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  11. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan [ORNL; Liang, Chengdu [ORNL

    2015-01-01

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  12. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  13. Natural sulfur flux from the Gulf of Mexico: dimethyl sulfide, carbonyl sulfide, and sulfur dioxide. Technical report

    SciTech Connect (OSTI)

    Van Valin, C.C.; Luria, M.; Wellman, D.L.; Gunter, R.L.; Pueschel, R.F.

    1987-06-01

    Atmospheric measurements of natural sulfur compounds were performed over the northern Gulf of Mexico during the late summer months of 1984. Air samples were collected with an instrumented aircraft at elevations of 30-3500 m, during both day and night. Most air samples were representative of the clean maritime atmosphere, although some were from continental contaminated air during periods of offshore flow at the coastline. In all samples, carbonyl sulfide concentrations were within the range of 400-500 pptv. Conversely, the dimethyl sulfide concentrations showed significant variability: during clean atmospheric conditions the average of all measurements was 27 pptv, whereas under polluted conditions the average was 7 pptv. Measureable quantities of dimethyl sulfide (>5 pptv) were not observed above the boundary layer. The average sulfur dioxide concentration measured in the marine (clean) atmosphere was 215 pptv, which is consistent with the oxidation of dimethyl sulfide being its major source.

  14. Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report

    SciTech Connect (OSTI)

    NONE

    1996-07-01

    More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

  15. ENERGY EFFICIENCY LIMITS FOR A RECUPERATIVE BAYONET SULFURIC ACID DECOMPOSITION REACTOR FOR SULFUR CYCLE THERMOCHEMICAL HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Gorensek, M.; Edwards, T.

    2009-06-11

    A recuperative bayonet reactor design for the high-temperature sulfuric acid decomposition step in sulfur-based thermochemical hydrogen cycles was evaluated using pinch analysis in conjunction with statistical methods. The objective was to establish the minimum energy requirement. Taking hydrogen production via alkaline electrolysis with nuclear power as the benchmark, the acid decomposition step can consume no more than 450 kJ/mol SO{sub 2} for sulfur cycles to be competitive. The lowest value of the minimum heating target, 320.9 kJ/mol SO{sub 2}, was found at the highest pressure (90 bar) and peak process temperature (900 C) considered, and at a feed concentration of 42.5 mol% H{sub 2}SO{sub 4}. This should be low enough for a practical water-splitting process, even including the additional energy required to concentrate the acid feed. Lower temperatures consistently gave higher minimum heating targets. The lowest peak process temperature that could meet the 450-kJ/mol SO{sub 2} benchmark was 750 C. If the decomposition reactor were to be heated indirectly by an advanced gas-cooled reactor heat source (50 C temperature difference between primary and secondary coolants, 25 C minimum temperature difference between the secondary coolant and the process), then sulfur cycles using this concept could be competitive with alkaline electrolysis provided the primary heat source temperature is at least 825 C. The bayonet design will not be practical if the (primary heat source) reactor outlet temperature is below 825 C.

  16. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2002-04-29

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2001 through March 31, 2002. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub X} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. This is the fifth reporting period for the subject Cooperative Agreement. During the previous (fourth) period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant) and a byproduct magnesium hydroxide slurry (at both Gavin and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub X} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the previous semi-annual technical progress report (April 1, 2001 through September 30, 2001). During the current reporting period, additional balance of plant impact information was determined for one of the two tests. These additional balance-of-plant results are presented and discussed in this report. There was no other technical progress to report, because all planned testing as part of this project has been completed.

  17. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2001-11-06

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2001 through September 30, 2001. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, and the Dravo Lime Company are project co-funders. URS Corporation is the prime contractor. During the current period, American Electric Power (AEP) joined the project as an additional co-funder and as a provider of a host site for testing. This is the fourth reporting period for the subject Cooperative Agreement. During this period, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Station. These tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Station), and a byproduct magnesium hydroxide slurry (both Gavin Station and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70 to 75% sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Station, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. Balance of plant impacts, primarily on the ESP particulate control device, were also determined during both tests. These results are presented and discussed in this report.

  18. Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Lin, Zhan [ORNL] [ORNL; Liu, Zengcai [ORNL] [ORNL; Fu, Wujun [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2013-01-01

    Given the great potential for improving the energy density of state-of-the-art lithium-ion batteries by a factor of 5, a breakthrough in lithium-sulfur (Li-S) batteries will have a dramatic impact in a broad scope of energy related fields. Conventional Li-S batteries that use liquid electrolytes are intrinsically short-lived with low energy efficiency. The challenges stem from the poor electronic and ionic conductivities of elemental sulfur and its discharge products. We report herein lithium polysulfidophosphates (LPSP), a family of sulfur-rich compounds, as the enabler of long-lasting and energy-efficient Li-S batteries. LPSP have ionic conductivities of 3.0 10-5 S cm-1 at 25 oC, which is 8 orders of magnitude higher than that of Li2S (~10-13 S cm-1). The high Li-ion conductivity of LPSP is the salient characteristic of these compounds that impart the excellent cycling performance to Li-S batteries. In addition, the batteries are configured in an all-solid state that promises the safe cycling of high-energy batteries with metallic lithium anodes.

  19. 2000 Solutions Pascal Contest (Grade 9)

    E-Print Network [OSTI]

    Le Roy, Robert J.

    2000 Solutions Pascal Contest (Grade 9) Canadian Mathematics Competition An activity of The Centre for EDUCATION in MATHEMATICS and COMPUTING © 2000 Waterloo Mathematics Foundation #12;2000 Pascal Solutions 2? , , , , (A) (B) (C) (D) (E) #12;2000 Pascal Solutions 3 Solution Since this sequence repeats itself, once

  20. 2000 Solutions Cayley Contest (Grade 10)

    E-Print Network [OSTI]

    Le Roy, Robert J.

    2000 Solutions Cayley Contest (Grade 10) Canadian Mathematics Competition An activity of The Centre for EDUCATION in MATHEMATICS and COMPUTING © 2000 Waterloo Mathematics Foundation #12;2000 Cayley Solutions 2) 13 (B) 18 (C) 22 (D) 21 (E) 19 2 3 6 2 #12;2000 Cayley Solutions 3 Solution The easiest way

  1. Environmental degradation using functionally graded material approach

    E-Print Network [OSTI]

    Sevostianov, Igor

    . It is not yet understood how this unique combination of environmental factors impact on the mechanical propEnvironmental degradation using functionally graded material approach I. Sevostianov a,*, N.K. Sookay b , C.J. von Klemperer b , V.E. Verijenko b a Department of Mechanical Engineering, New Mexico

  2. ART K-12 Minor Credits GRADE

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    ART K-12 Minor Credits GRADE ARTZ 106RA - 2-D 4 ___Fall ARTZ 108RA - 3-D 4 ____Spring ARTZ 105RA 231RA ­ Ceramics I ART 251 ­ Sculpture I ART 261 ­ Metalsmithing I ARTZ 271 ­ Printmaking I Take one ­ Intaglio ARTZ 376 ­ Printmaking ­ Relief ARTZ 379 ­ Alternate Print Media TOTAL Art Credits 28 EDU 397

  3. OIMB GK12 CURRICULUM Grade 45 minutes

    E-Print Network [OSTI]

    OIMB GK12 CURRICULUM 3rd Grade 45 minutes The Incredible Journey: Project WET Water Cycle Game interconnected. Goals: ! To have students understand the physical processes of the water cycle ! To have students get a feel for different lengths of time water spends in different parts of the water cycle ! To play

  4. 1999 Solutions Fermat Contest (Grade 11)

    E-Print Network [OSTI]

    Le Roy, Robert J.

    1999 Solutions Fermat Contest (Grade 11) Canadian Mathematics Competition An activity of The Centre for Education in Mathematics and Computing, University of Waterloo, Waterloo, Ontario for the Awards © 1999 Waterloo Mathematics Foundation #12;1999 Fermat Solutions 2 Part A 1. The value of 25 9 2 ­( ) is (A) 26 (B

  5. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 1, [September--November 1994

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1994-11-30

    This project is being coordinated with an ongoing project at Western Kentucky University that is being supported by the Southeastern Regional Biomass Energy Program through the Tennessee Valley Authority. Fluidized bed combustion tests will be performed on municipal solid waste blended with high-sulfur and high-chlorine coals in a laboratory scale combustor. The purpose of the tests is to evaluate combustion performance, the extent of the inorganic acid gases (HCl and SO{sub x}) and chlorinated organic compound formation, the effect of chlorine species on SO{sub 2} removal with a sorbent, and the effect of sulfur species on the formation of chlorinated organic compounds from MSW for a range of bed temperatures, excess air levels, MSW/coal ratios, and S/Cl ratios. Flue gas samples will be collected and analyzed at three locations: free board, cyclone inlet, and cyclone outlet. Analytical methods used will include ion chromatography, gas chromatography, and mass spectrometry. Waste stream ash samples will be collected from the cyclone catch and analyzed for unburned carbon, chlorine, chlorinated benzenes, polychlorinated biphenyls, chlorinated phenols, dioxins, furans, and metal content. Major, minor, and trace elements in the ash will be determined by x-ray fluorescence and inductively coupled plasma-atomic emission spectroscopy. Accomplishments for the first quarter are presented.

  6. Surface performance grading and grade selection process for surface treatment binders 

    E-Print Network [OSTI]

    Barcena Mendoza, Roberto

    2001-01-01

    ) or performance-graded (PG) asphalt binder specification was developed in the 1990's to measure binder properties directly related to hot mix asphalt concrete (HMAC) performance and included material characterization at low, intermediate, and high temperatures...

  7. Transformations and affinities for sulfur of Chinese Shenmu coal ash in a pulverized coal-fired boiler

    SciTech Connect (OSTI)

    Cheng, J.; Zhou, J.H.; Liu, J.Z.; Cao, X.Y.; Cen, K.F.

    2009-07-01

    The self-desulfurization efficiency of Shenmu coal with a high initial Ca/S molar ratio of 2.02 was measured in a 1,025 t/h pulverized coal-fired boiler. It increases from 29% to 32% when the power capacity decreases from 100% to 70%. About 60% of the mineral matter and calcium element fed into the furnace is retained in the fly ash, while less than 10% is retained in the bottom ash. About 70% of the sulfur element fed into the furnace is emitted as SO{sub 2} in the flue gas, while less than 10% is retained in the fly ash and less than 1% is retained in the bottom ash. The mineralogical compositions of feed coal, fly ash, and bottom ash were obtained by X-ray diffraction analysis. It is found that the initial amorphous phase content is 91.17% and the initial CaCO{sub 3} phase content is 2.07% in Shenmu coal. The vitreous phase and sulfation product CaSO{sub 4} contents are, respectively, 70.47% and 3.36% in the fly ash obtained at full capacity, while the retained CaCO{sub 3} and CaO contents are, respectively, 4.73% and 2.15%. However, the vitreous phase content is only 25.68% and no CaSO{sub 4} is detected in the bottom ash obtained at full capacity. When the power capacity decreases from 100% to 70%, the vitreous phase content in fly ash decreases from 70.47% to 67.41% and that in bottom ash increases from 25.68% to 28.10%.

  8. SCHOOLOFSCIENCE Table of Contents

    E-Print Network [OSTI]

    Varela, Carlos

    SCHOOLOFSCIENCE Table of Contents Degrees Offered and Associated Departments 330 Overview Environmental Science 403 Interdisciplinary Science 407 Multidisciplinary Science 409 The Darrin Fresh Water

  9. InteGrade: Rumo a um Sistema de Computac~ao em Grade para Aproveitamento de

    E-Print Network [OSTI]

    Goldman, Alfredo

    Departamento de Ci^encia da Computa¸c~ao Instituto de Matem´atica e Estat´istica Universidade de S~ao Paulo de recursos. Pro- cessadores que hoje equipam computadores pessoais possuem capacidade de¸c~ao de Grades A id´eia de Grade transcende o uso de redes que fazemos hoje em dia. Em uma rede que se

  10. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  11. Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Gasoline Sulfur naturally occurs in gasoline and diesel fuel, contributing to pollution when the fuel is burned. Beginning in 2004, standards were set on the amount of...

  12. Portable instrument and method for detecting reduced sulfur compounds in a gas

    DOE Patents [OSTI]

    Gaffney, J.S.; Kelly, T.J.; Tanner, R.L.

    1983-06-01

    A portable real time instrument for detecting concentrations in the part per billion range of reduced sulfur compounds in a sample gas. Ozonized air or oxygen and reduced sulfur compounds in a sample gas stream react to produce chemiluminescence in a reaction chamber and the emitted light is filtered and observed by a photomultiplier to detect reduced sulfur compounds. Selective response to individual sulfur compounds is achieved by varying reaction chamber temperature and ozone and sample gas flows, and by the use of either air or oxygen as the ozone source gas.

  13. Sulfur barrier for use with in situ processes for treating formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Christensen, Del Scot (Friendswood, TX)

    2009-12-15

    Methods for forming a barrier around at least a portion of a treatment area in a subsurface formation are described herein. Sulfur may be introduced into one or more wellbores located inside a perimeter of a treatment area in the formation having a permeability of at least 0.1 darcy. At least some of the sulfur is allowed to move towards portions of the formation cooler than the melting point of sulfur to solidify the sulfur in the formation to form the barrier.

  14. A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Life, High-Rate LithiumSulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Min-Kyu Song, , Yuegang Zhang,* ,, and Elton J. Cairns* ,, The...

  15. Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program

    SciTech Connect (OSTI)

    George Sverdrup

    1999-06-07

    DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

  16. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy

    2011-08-20

    Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square meter per hour [{micro}g/m{sup 2}/h]. The dominant sulfur containing compounds in the RSG emission stream were hydrogen sulfide with emission factors between 17-201 {micro}g/m{sup 2}/h, and sulfur dioxide with emission factors between 8-64 {micro}g/m{sup 2}/h. The four highest emitting samples also had a unique signature of VSC emissions including > 40 higher molecular weight sulfur-containing compounds although the emission rate for the VSCs was several orders of magnitude lower than that of the RSGs. All of the high emitting drywall samples were manufactured in China in 2005-2006. Results from Phase 1 provided baseline emission factors for drywall samples manufactured in China and in North America but the results exclude variations in environmental conditions that may exist in homes or other built structures, including various combinations of temperature, RH, ventilation rate and the influence of coatings such as texture and paints. The objective of Phase 2 was to quantify the effect of temperature and RH on the RSG emission factors for uncoated drywall, and to measure the effect of plaster and paint coatings on RSG emission factors from drywall. Additional experiments were also performed to assess the influence of ventilation rate on measured emission factors for drywall.

  17. SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-07-03

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

  18. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-10-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period April 1, 2003 through September, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the eighth reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO{sub 3} removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the report for the time period April 1, 2002 through September 30, 2002. During the current period, process economic estimates were developed, comparing the costs of the furnace magnesium hydroxide slurry injection process tested as part of this project to a number of other candidate SO{sub 3}/sulfuric acid control technologies for coal-fired power plants. The results of this economic evaluation are included in this progress report.

  19. 2015 Market Research Report on Global Medical Grade Dioctyl Industry...

    Open Energy Info (EERE)

    2015 Market Research Report on Global Medical Grade Dioctyl Industry Home There are currently no posts in this category. Syndicate...

  20. SEM CR GRADE Intro to Chem Eng 1

    E-Print Network [OSTI]

    Pringle, James "Jamie"

    Discovery 5 Social Science SEM CR GRADE 3 ENE 612* Unit Operations Lab 1 SEM CR GRADE 4 Tech Elective Tech Elective 1 SEM CR GRADE 4 Tech Elective Tech Elective 2 SEM CR GRADE 4 Tech Elective Tech Elective 3 SEM CR of New Hampshire Advising Worksheet for ENE-IP Majors Page 1 of 3 Green ­ ENE-IP; Red ­ General Education

  1. oZONE Faculty and Staff Exporting and Importing Grades

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Exporting and Importing Grades Exporting/Importing Grades in oZONE The new - Log in to ozone.ou.edu using your OU Net ID (4+4) as you would in any other OU system. Click Importing Grades from a Exported oZONE template If you exported a course template from the oZONE grading

  2. A solvent system to provide selective removal of sulfur compounds

    SciTech Connect (OSTI)

    Pearce, R.L.; Bacon, T.R.

    1986-01-01

    Energy costs and SRU inefficiencies resulting from utilization of low strength MEA technology induced a large refinery to convert to MDEA. One of the seven product streams being treated required extremely low carbonyl sulfide in the treated product. This required careful consideration in making the decision to convert. However, the conclusions were that the advantages outweighed the disadvantages. When the initial converted operations verified a need to improve the carbonyl sulfide removal, GAS/SPEC Tech Service produced an innovative solution which allowed for efficient operation at acceptable COS specification, lower energy utilization, reduced solvent losses, and improved sulfur recovery unit operation.

  3. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  4. Method of preparing graphene-sulfur nanocomposites for rechargeable

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport) |(Patent) | SciTech Connect Patent:lithium-sulfur

  5. The last decade of global anthropogenic sulfur dioxide: 2000-2011 emissions

    SciTech Connect (OSTI)

    Klimont, Z.; Smith, Steven J.; Cofala, Janusz

    2013-01-09

    Evolution of global and regional anthropogenic SO2 emissions in the last decade has been estimated through a bottom-up calculation for recent years. After a strong increase in emissions that peaked about 2006, we estimate a declining trend continuing until 2011. However, there is a strong spatial variability with North America and Europe continuing to reduce emissions with an increasing role of Asia and international shipping. China remains a key contributor but the introduction of stricter emission limits followed by an ambitious program of installing flue gas desulfurization on power plants resulted in significant decline in emissions from energy sector and stabilization of Chinese SO2 emissions. Comparable mitigation strategies are not yet present in several other Asian countries and industrial sectors in general, while emissions from international shipping are expected to start declining soon following agreed reduction of sulfur content of fuel oil. Estimated trends in global SO2 emissions are within the range of RCP projections and uncertainty calculated for the year 2005.

  6. CONTENTS PAGE INTRODUCTION

    E-Print Network [OSTI]

    Aslaksen, Helmer

    THE APPLICATIONS AND VALIDITY OF BODE'S LAW CAN WE EXPLAIN BODE'S LAW USING GRAVITY? 8 Law of Gravitation 8 Centre#12;#12;CONTENTS CONTENTS PAGE INTRODUCTION WHO, HOW AND WHEN IS THE BODE'S LAW DISCOVERED? 1 THE BODE'S LAW HOW THE BODE'S LAW SATISFIED URANUS 3 HOW THE BODE'S LAW LED TO THE DISCOVERY OF CERES

  7. CONSTRUCTION-GRADE CEMENT PRODUCTION FROM CONTAMINATED SEDIMENTS USING

    E-Print Network [OSTI]

    Brookhaven National Laboratory

    1 CONSTRUCTION-GRADE CEMENT PRODUCTION FROM CONTAMINATED SEDIMENTS USING CEMENT-LOCKTM TECHNOLOGY A manufacturing technology for producing construction-grade cements from a wide variety of contaminated waste cementitious properties that allow it to be transformed into construction-grade cement. The Cement

  8. A SENSOR AND DATA FUSION ALGORITHM FOR ROAD GRADE ESTIMATION

    E-Print Network [OSTI]

    Johansson, Karl Henrik

    A SENSOR AND DATA FUSION ALGORITHM FOR ROAD GRADE ESTIMATION Per Sahlholm Henrik Jansson Ermin presents a road grade estimation algorithm for fusion of GPS and vehicle real-time sensor data, with measurements from previous runs over the same road segment. The resulting road grade estimate is thus enhanced

  9. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  10. Standard test methods for chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 These test methods cover procedures for the chemical, mass spectrometric, and spectrochemical analysis of nuclear-grade plutonium dioxide powders and pellets to determine compliance with specifications. 1.2 The analytical procedures appear in the following order: Sections Plutonium Sample Handling 8 to 10 Plutonium by Controlled-Potential Coulometry Plutonium by Ceric Sulfate Titration Plutonium by Amperometric Titration with Iron(II) Plutonium by Diode Array Spectrophotometry Nitrogen by Distillation Spectrophotometry Using Nessler Reagent 11 to 18 Carbon (Total) by Direct Combustion–Thermal Conductivity 19 to 30 Total Chlorine and Fluorine by Pyrohydrolysis 31 to 38 Sulfur by Distillation Spectrophotometry 39 to 47 Plutonium Isotopic Analysis by Mass Spectrometry Rare Earth Elements by Spectroscopy 48 to 55 Trace Elements by Carrier–Distillation Spectroscopy 56 to 63 Impurities by ICP-AES Impurity Elements by Spark-Source Mass Spectrography 64 to 70 Moisture by the Coulomet...

  11. ULTRA-LOW SULFUR REDUCTION EMISSION CONTROL DEVICE/DEVELOPMENT OF AN ON-BOARD FUEL SULFUR TRAP

    SciTech Connect (OSTI)

    Ron Rohrbach; Gary Zulauf; Tim Gavin

    2003-04-01

    Honeywell is actively working on a 3-year program to develop and demonstrate proof-of-concept for an ''on-vehicle'' desulfurization fuel filter for heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NO{sub x} adsorbers. The NO{sub x} adsorber may be required to meet the proposed new EPA Tier II and ''2007-Rule'' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters will also be examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. It is anticipated that the technology developed for heavy-duty applications will be applicable to light-duty as well. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consists of four phases. Phase I will focus on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II we will concentrate on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III will study life cycle and regeneration options for the spent filter. Phase IV will focus on efficacy and life testing and component integration. The project team will include a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Mack Trucks Inc.), a filter recycler (American Wastes Industries), and a low-sulfur fuel supplier (Equilon, a joint venture between Shell and Texaco).

  12. S:\\Registration & Records\\Grades\\Grading-ISIS for Faculty.docx page 1 of 3 JOHNS HOPKINS UNIVERSITY

    E-Print Network [OSTI]

    S:\\Registration & Records\\Grades\\Grading-ISIS for Faculty.docx page 1 of 3 JOHNS HOPKINS UNIVERSITY Registrar, Registration and Records RE: Posting Grades in ISIS As always, the Office of the Registrar SAVED WILL BE POSTED TO THE STUDENTS' RECORDS For a quick demonstration of ISIS for Faculty

  13. Crystal structure studies on sulfur oxygenase reductase from Acidianus tengchongensis

    SciTech Connect (OSTI)

    Li Mei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Chen Zhiwei [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); Zhang Pingfeng; Pan Xiaowei [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China); Jiang Chengying [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); An Xiaomin [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China); Liu Shuangjiang [State Key Laboratory of Microbial Resources, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101 (China); Chang Wenrui [National Laboratory of Biomacromolecules, Institute of Biophysics, Chinese Academy of Sciences, 15 Datun Road, Chaoyang District, Beijing 100101 (China)], E-mail: wrchang@sun5.ibp.ac.cn

    2008-05-09

    Sulfur oxygenase reductase (SOR) simultaneously catalyzes oxidation and reduction of elemental sulfur to produce sulfite, thiosulfate, and sulfide in the presence of molecular oxygen. In this study, crystal structures of wild type and mutants of SOR from Acidianus tengchongensis (SOR-AT) in two different crystal forms were determined and it was observed that 24 identical SOR monomers form a hollow sphere. Within the icosatetramer sphere, the tetramer and trimer channels were proposed as the paths for the substrate and products, respectively. Moreover, a comparison of SOR-AT with SOR-AA (SOR from Acidianus ambivalens) structures showed that significant differences existed at the active site. Firstly, Cys31 is not persulfurated in SOR-AT structures. Secondly, the iron atom is five-coordinated rather than six-coordinated, since one of the water molecules ligated to the iron atom in the SOR-AA structure is lost. Consequently, the binding sites of substrates and a hypothetical catalytic process of SOR were proposed.

  14. Catalysts for the selective oxidation of hydrogen sulfide to sulfur

    DOE Patents [OSTI]

    Srinivas, Girish (Thornton, CO); Bai, Chuansheng (Baton Rouge, LA)

    2000-08-08

    This invention provides catalysts for the oxidation of hydrogen sulfide. In particular, the invention provides catalysts for the partial oxidation of hydrogen sulfide to elemental sulfur and water. The catalytically active component of the catalyst comprises a mixture of metal oxides containing titanium oxide and one or more metal oxides which can be selected from the group of metal oxides or mixtures of metal oxides of transition metals or lanthanide metals. Preferred metal oxides for combination with TiO.sub.2 in the catalysts of this invention include oxides of V, Cr, Mn, Fe, Co, Ni, Cu, Nb, Mo, Tc, Ru, Rh, Hf, Ta, W, Au, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu. Catalysts which comprise a homogeneous mixture of titanium oxide and niobium (Nb) oxide are also provided. A preferred method for preparing the precursor homogenous mixture of metal hydroxides is by coprecipitation of titanium hydroxide with one or more other selected metal hydroxides. Catalysts of this invention have improved activity and/or selectivity for elemental sulfur production. Further improvements of activity and/or selectivity can be obtained by introducing relatively low amounts (up to about 5 mol %)of a promoter metal oxide (preferably of metals other than titanium and that of the selected second metal oxide) into the homogeneous metal/titanium oxide catalysts of this invention.

  15. Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis

    E-Print Network [OSTI]

    Harris, E.

    The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

  16. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID CONTROL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2003-06-01

    This document summarizes progress on Cooperative Agreement DE-FC26-99FT40718, Furnace Injection of Alkaline Sorbents for Sulfuric Acid Control, during the time period October 1, 2002 through March 31, 2003. The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The coincident removal of hydrochloric acid and hydrofluoric acid is also being determined, as is the removal of arsenic, a known poison for NO{sub x} selective catalytic reduction (SCR) catalysts. EPRI, the Tennessee Valley Authority (TVA), FirstEnergy Corporation, American Electric Power (AEP) and the Dravo Lime Company are project co-funders. URS Group is the prime contractor. This is the seventh reporting period for the subject Cooperative Agreement. During previous reporting periods, two long-term sorbent injection tests were conducted, one on Unit 3 at FirstEnergy's Bruce Mansfield Plant (BMP) and one on Unit 1 at AEP's Gavin Plant. Those tests determined the effectiveness of injecting alkaline slurries into the upper furnace of the boiler as a means of controlling sulfuric acid emissions from these units. The alkaline slurries tested included commercially available magnesium hydroxide slurry (Gavin Plant), and a byproduct magnesium hydroxide slurry (both Gavin Plant and BMP). The tests showed that injecting either the commercial or the byproduct magnesium hydroxide slurry could achieve up to 70-75% overall sulfuric acid removal. At BMP, the overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NO{sub x} control than at removing SO{sub 3} formed in the furnace. The SO3 removal results were presented in the semi-annual Technical Progress Report for the time period April 1, 2001 through September 30, 2001. Additional balance of plant impact information for the two tests was reported in the Technical Progress Report for the time period October 1, 2001 through March 30, 2002. Additional information became available about the effects of byproduct magnesium hydroxide injection on SCR catalyst coupons during the long-term test at BMP, and those results were reported in the previous report (April 1, 2002 through September 30, 2002). During the current period, there was no technical progress to report, because all planned testing as part of this project has been completed. The project period of performance was extended to allow the conduct of testing of another SO{sub 3} control technology, the sodium bisulfite injection process. However, these additional tests have not yet been conducted.

  17. FURNACE INJECTION OF ALKALINE SORBENTS FOR SULFURIC ACID REMOVAL

    SciTech Connect (OSTI)

    Gary M. Blythe

    2004-01-01

    The objective of this project has been to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project was co-funded by the U.S. DOE National Energy Technology Laboratory under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corporation, the Tennessee Valley Authority, and Carmeuse North America. Sulfuric acid controls are becoming of increased interest for coal-fired power generating units for a number of reasons. In particular, sulfuric acid can cause plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NOX control, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project tested the effectiveness of furnace injection of four different magnesium-based or dolomitic alkaline sorbents on full-scale utility boilers. These reagents were tested during one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide slurry byproduct from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization process. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercially available magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners. The other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm sorbent effectiveness over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP Unit 3, and the second was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant test provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. A final task in the project was to compare projected costs for furnace injection of magnesium hydroxide slurries to estimated costs for other potential sulfuric acid control technologies. Estimates were developed for reagent and utility costs, and capital costs, for furnace injection of magnesium hydroxide slurries and seven other sulfuric acid control technologies. The estimates were based on retrofit application to a model coal-fired plant.

  18. Developing Kindergarten and Second Grade Teachers' Pedagogical Content Knowledge of Academic Science Vocabulary Instruction 

    E-Print Network [OSTI]

    Venegas, Annette Michè le

    2014-11-14

    hands-on, minds-on scientific investigations to form the heart of science learning for young children, the acquisition of science vocabulary is also an essential part of the process of science learning. Words allow students to communicate their ideas...

  19. A REAL TIME COAL CONTENT ORE GRADE (C2OG) SENSOR

    SciTech Connect (OSTI)

    Rand Swanson

    2004-10-22

    This thirteenth quarterly technical report describes data collection at the Stillwater Mine and an additional improvement to the lighting system. The data collection system was returned to the Stillwater Mine during this reporting period and a large amount of data was collected. The data will be analyzed and correlated with fire assays in the next reporting period. The majority of work done this quarter has been devoted to collecting data from cores scanned in the Stillwater Mining Company core room. This work is somewhat tedious and tiresome, but essential to: (1) obtain enough data to reliably determine the correlation between assay results and spectral imaging results; (2) find bugs and glitches in the system that arise only periodically or after long periods of use; and (3) obtain data on the natural (and man-made) variations in the Stillwater ore that may confuse the machine vision algorithms.

  20. Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3sa Greenhouse Gas

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3sa Greenhouse that a source for this potentially dangerous greenhouse gas might be the recombination of SF5(X2A1) and CF3(X2A1 the strongest greenhouse gas trifluoromethyl sulfur pentafluoride (SF5CF3) with a radiative force of 0.59 W m-2

  1. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S.; Husar, J.D.; Husar, R.B.; Brimblecombe, P.

    1996-07-19

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  2. Understanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur Cathode Performance

    E-Print Network [OSTI]

    Cui, Yi

    structural configurations of conductive polymer-sulfur composites employed in previous studies. In this workUnderstanding the Role of Different Conductive Polymers in Improving the Nanostructured Sulfur for the confinement of lithium polysulfides. However, the roles of different conductive polymers

  3. In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries

    E-Print Network [OSTI]

    Cui, Yi

    In Operando X-ray Diffraction and Transmission X-ray Microscopy of Lithium Sulfur Batteries Johanna Information ABSTRACT: Rechargeable lithium-sulfur (Li-S) batteries hold great potential for high not well understood. In this Article, these changes in Li-S batteries are studied in operando by X

  4. High-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature,

    E-Print Network [OSTI]

    Cui, Yi

    capacity of 849 and 610 mAh/g at 2C and 4C, respectively. lithium sulfur battery | energy storage | long energy storage (1­4). To achieve a quantum leap in the batteries specific energy density, new electrodeHigh-performance hollow sulfur nanostructured battery cathode through a scalable, room temperature

  5. Surface Science 415 (1998) 2936 Structural studies of sulfur-passivated GaAs (100)

    E-Print Network [OSTI]

    Zhang, Yanchao

    1998-01-01

    . Keywords: Atomic force microscopy; Gallium arsenide; Low-energy electron diffraction; Roughness; SulfurSurface Science 415 (1998) 29­36 Structural studies of sulfur-passivated GaAs (100) surfaces Abstract We present the results of Auger electron spectroscopy (AES), low-energy electron diffraction (LEED

  6. Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor

    E-Print Network [OSTI]

    Tobin, Roger G.

    Sulfur surface chemistry on the platinum gate of a silicon carbide based hydrogen sensor Yung Ho September 2007 We have investigated the effects of sulfur contamination on a Pt-gate silicon carbide based monitoring, solid-oxide fuel cells, and coal gasification, require operation at much higher temperatures than

  7. Memory-Assisted Exciton Diffusion in the Chlorosome Light-Harvesting Antenna of Green Sulfur Bacteria

    E-Print Network [OSTI]

    Saikin, Semion

    Memory-Assisted Exciton Diffusion in the Chlorosome Light- Harvesting Antenna of Green Sulfur of bacteriochlorophylls (BChls) enclosed by a lipid monolayer.1-4 They can capture light and transfer it in a form. In green sulfur bacteria, light energy absorbed by the rolls is transferred via a baseplate9 to the Fenna

  8. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-12-31

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  9. Nitrous oxide as a substitute for sulfur hexafluoride in the ANSI/ASHRAE 110 Method of hood performance evaluation

    E-Print Network [OSTI]

    Guffey, Eric J. (Eric Jemison)

    2011-01-01

    The ANSI/ASHRAE 110 Method is the standard test for laboratory hood containment performance. Sulfur hexafluoride is specified as the gas most suitable for this test and is most commonly used. Sulfur hexafluoride use has ...

  10. Fractionation of sulfur isotopes by Desulfovibrio vulgaris mutants lacking hydrogenases or type I tetraheme cytochrome c[subscript 3

    E-Print Network [OSTI]

    Sim, Min Sub

    The sulfur isotope effect produced by sulfate reducing microbes is commonly used to trace biogeochemical cycles of sulfur and carbon in aquatic and sedimentary environments. To test the contribution of intracellular coupling ...

  11. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Chou, M.I.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States)

    1993-09-01

    The purposes of this project are: to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE process developed by the Midwest Ore Processing Co. (MWOPC), to verify the forms-of-sulfur determination using the ASTM method for evaluation of the PCE process, and to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal. The objectives for the second year are: to verify the possible effects of PCE treatment on coal-derived FeS{sub 2}, FeSO{sub 4}, and Fe{sub 2}(SO{sub 4}){sub 3} on ASTM coal analysis, to investigate the behavior of sulfur during oxidation and PCE desulfurization using the isotopically signatured coal sample, to investigate the effects of conditions and/or reagents on the oxidation of the organic-sulfur-model compounds, to evaluate the extended oxidation condition on the organic sulfur removal by PCE desulfurization, and to study other innovative pretreatment processes for the removal of organic sulfur from coal under mild conditions.

  12. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  13. Advanced Article Article Contents

    E-Print Network [OSTI]

    O'Shea, Paul

    -reduction) WILEY ENCYCLOPEDIA OF CHEMICAL BIOLOGY 2008, John Wiley & Sons, Inc. 1 #12;Membrane PotentialsAdvanced Article Article Contents · Biological Background · Physical Chemistry Background of Biological Roles and of Tech- nologies for Measurement Membrane Potentials in Living Systems, Tools

  14. SCHOOLOFSCIENCE Table of Contents

    E-Print Network [OSTI]

    Varela, Carlos

    SCHOOLOFSCIENCE Table of Contents Degrees Offered and Associated Departments 324 Overview The Darrin Fresh Water Institute 401 New York Center for Studies on the Origins of Life 402 New York State

  15. Ductile fracture toughness of modified A 302 grade B plate materials. Volume 2

    SciTech Connect (OSTI)

    McCabe, D.E.; Manneschmidt, E.T.; Swain, R.L.

    1997-02-01

    The objective of this work was to develop ductile fracture toughness data in the form of J-R curves for modified A 302 grade B plate materials typical of those used in fabricating reactor pressure vessels. A previous experimental study at Materials Engineering Associates (MEA) on one particular heat of A 302 grade B plate showed decreasing J-R curves with increased specimen thickness. This characteristic has not been observed in numerous tests made on the more recent production materials of A 533 grade B and A 508 class 2 pressure vessel steels. It was unknown if the departure from norm for the MEA material was a generic characteristic for all heats of A 302 grade B steels or just unique to that one particular plate. Seven heats of modified A 302 grade B steel and one heat of vintage A 533 grade B steel were provided to this project by the General Electric Company of San Jose, California. All plates were tested for chemical content, tensile properties, Charpy transition temperature curves, drop-weight nil-ductility transition (NDT) temperature, and J-R curves. Tensile tests were made in the three principal orientations and at four temperatures, ranging from room temperature to 550{degrees}F (288{degrees}C). Charpy V-notch transition temperature curves were obtained in longitudinal, transverse, and short transverse orientations. J-R curves were made using four specimen sizes (1/2T, IT, 2T, and 4T). None of the seven heats of modified A 302 grade showed size effects of any consequence on the J-R curve behavior. Crack orientation effects were present, but none were severe enough to be reported as atypical. A test temperature increase from 180 to 550{degrees}F (82 to 288{degrees}C) produced the usual loss in J-R curve fracture toughness. Generic J-R curves and mathematical curve fits to the same were generated to represent each heat of material. This volume is a compilation of all data developed.

  16. Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Qiang Wang,*,

    E-Print Network [OSTI]

    Guo, John Zhanhu

    Sulfur Poisoning and Regeneration of NOx Storage-Reduction Cu/K2Ti2O5 Catalyst Qiang Wang,*, Jiahua NOx through the NOx storage-reduction (NSR) process. However, its NSR performance in the presence of sulfur has not been investigated. In this article, the sulfur poisoning of the NOx storage-reduction

  17. Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon and Heather C. Allen*

    E-Print Network [OSTI]

    Methanol Reaction with Sulfuric Acid: A Vibrational Spectroscopic Study Lisa L. Van Loon 43210 ReceiVed: May 27, 2004; In Final Form: August 19, 2004 The reaction between methanol and sulfuric peak in the 800 cm-1 region, not present in either the neat methanol or concentrated sulfuric acid

  18. Population, Economy and Energy Use’s Influence on Sulfur Emissions in the United States Since 1900 

    E-Print Network [OSTI]

    Kissock, J. K.; Husar, R. B.

    1990-01-01

    and the transition from coal to less sulfur intensive fuels have reduced sulfur emissions. The net effect of all drivers has been moderate growth in sulfur emissions from 1900 to present. Since 1973, increased energy efficiency and the shift from an industrial to a...

  19. SuStainability table of contentS

    E-Print Network [OSTI]

    Karonis, Nicholas T.

    SuStainability table of contentS executive Summary-Related Sustainability Options ........................................... 41 Information Technology Infrastucture #12;sustainability 2 Private Giving

  20. As geoscience educators, we focus on helping students understand technical content and learn to think like

    E-Print Network [OSTI]

    ABSTRACT As geoscience educators, we focus on helping students understand technical content grading student writing and still yield more learning benefits from incorporating writing. This approach with a geoscience course suggest gains in student learning. INTRODUCTION As faculty members in geoscience education

  1. Improvement of ASME NH for Grade 91

    SciTech Connect (OSTI)

    Bernard Riou

    2007-10-09

    This report has been prepared in the context of Task 3 of the ASME/DOE Gen IV material project. It has been identified that creep-fatigue evaluation procedures presently available in ASME (1) and RCC-MR (2) have been mainly developed for austenitic stainless steels and may not be suitable for cyclic softening materials such as mod 9 Cr 1 Mo steel (grade 91). The aim of this document is, starting from experimental test results, to perform a review of the procedures and, if necessary, provide recommendations for their improvements.

  2. Cohomological Approach to the Graded Berezinian

    E-Print Network [OSTI]

    Tiffany Covolo

    2013-06-28

    We develop the theory of linear algebra over a (Z_2)^n-commutative algebra (n in N), which includes the well-known super linear algebra as a special case (n=1). Examples of such graded-commutative algebras are the Clifford algebras, in particular the quaternion algebra H. Following a cohomological approach, we introduce analogues of the notions of trace and determinant. Our construction reduces in the classical commutative case to the coordinate-free description of the determinant by means of the action of invertible matrices on the top exterior power, and in the supercommutative case it coincides with the well-known cohomological interpretation of the Berezinian.

  3. Commercial Grade Dedication RM | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartment ofCommercial Grade Dedication (CGD) is to provide guidance

  4. of Your Food Contents Page

    E-Print Network [OSTI]

    B-1400 8/11 of Your Food Content The Sodium #12;Contents Page Introduction.......................................................................................3 Sodium content of foods Beverages and fruit juices activity, and encourages Americans to consume more healthy foods like vegetables, fruits, seafood, whole

  5. Removal of sulfur contaminants in methanol for fuel cell applications

    SciTech Connect (OSTI)

    Lee, S.H.D.; Kumar, R. [Argonne National Lab., IL (United States); Sederquist, R. [International Fuel Cells Corp., South Windsor, CT (United States)

    1996-12-31

    Equilibrium adsorption isotherm and breakthrough data were used to assess feasibility of developing a granular activated carbon (GAC) adsorber for use as a sulfur removal subsystem in transportation fuel cell systems. Results suggest that an on-board GAC adsorber may not be attractive due to size and weight constraints. However, it may be feasible to install this GAC adsorber at methanol distribution stations, where space and weight are not a critical concern. Preliminary economic analysis indicated that the GAC adsorber concept will be attractive if the spent AC can be regenerated for reuse. These preliminary analyses were made on basis of very limited breakthrough data obtained from the bench-scale testing. Optimization on dynamic testing parameters and study on regeneration of spent AC are needed.

  6. Method of forming and starting a sodium sulfur battery

    DOE Patents [OSTI]

    Paquette, David G. (Costa Mesa, CA)

    1981-01-01

    A method of forming a sodium sulfur battery and of starting the reactive capability of that battery when heated to a temperature suitable for battery operation is disclosed. An anodic reaction zone is constructed in a manner that sodium is hermetically sealed therein, part of the hermetic seal including fusible material which closes up openings through the container of the anodic reaction zone. The hermetically sealed anodic reaction zone is assembled under normal atmospheric conditions with a suitable cathodic reaction zone and a cation-permeable barrier. When the entire battery is heated to an operational temperature, the fusible material of the hermetically sealed anodic reaction zone is fused, thereby allowing molten sodium to flow from the anodic reaction zone into reactive engagement with the cation-permeable barrier.

  7. Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap

    SciTech Connect (OSTI)

    Rohrbach, Ron; Barron, Ann

    2008-07-31

    Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Navistar Inc. (formerly International Truck & Engine Corporation) and Mack Trucks Inc.), and filter recycler (American Wastes Industries).

  8. Exporting the Grade Center (Working Offline) Page 1 Exporting the Grade Center

    E-Print Network [OSTI]

    Xu, Shouhuai

    the data has been saved to a file. Click Download . 4. Click Save As. 5. Select a location to save the file. You may change the file name. Click Save. #12;Exporting the Grade Center (Working Offline) Page 2 to the location where you saved your file, select your file and click Import. 4. The Text Import Wizard Appears

  9. Sulfur Partitioning During Vitrification of INEEL Sodium Bearing Waste: Status Report

    SciTech Connect (OSTI)

    Darab, John G.; Graham, Dennis D.; Macisaac, Brett D.; Russell, Renee L.; Smith, Harry D.; Vienna, John D.; Peeler, David K.

    2001-07-31

    The sodium bearing tank waste (SBW) at Idaho National Engineering and Environmental Laboratory (INEEL) contains high concentrations of sulfur (roughly 5 mass% of SO3 on a nonvolatile oxide basis). The amount of sulfur that can be feed to the melter will ultimately determine the loading of SBW in glass produced by the baseline (low-temperature, joule-heated, liquid-fed, ceramic-lined) melter. The amount of sulfur which can be fed to the melter is determined by several major factors including: the tolerance of the melter for an immiscible salt layer accumulation, the solubility of sulfur in the glass melt, the fraction of sulfur removed to the off-gas, and the incorporation of sulfur into the glass up to it?s solubility limit. This report summarizes the current status of testing aimed at determining the impacts of key chemical and physical parameters on the partitioning of sulfur between the glass, a molten salt, and the off-gas.

  10. Nondestructive Evaluation of Nuclear-Grade Graphite

    SciTech Connect (OSTI)

    Dennis C. Kunerth; Timothy R. McJunkin

    2011-07-01

    Nondestructive Evaluation of Nuclear Grade Graphite Dennis C. Kunerth and Timothy R. McJunkin Idaho National Laboratory Idaho Falls, ID, 83415 This paper discusses the nondestructive evaluation of nuclear grade graphite performed at the Idaho National Laboratory. Graphite is a composite material highly dependent on the base material and manufacturing methods. As a result, material variations are expected within individual billets as well billet to billet and lot to lot. Several methods of evaluating the material have been explored. Particular technologies each provide a subset of information about the material. This paper focuses on techniques that are applicable to in-service inspection of nuclear energy plant components. Eddy current examination of the available surfaces provides information on potential near surface structural defects and although limited, ultrasonics can be utilized in conventional volumetric inspection. Material condition (e.g. micro-cracking and porosity induced by radiation and stress) can be derived from backscatter or acousto-ultrasound (AU) methods. Novel approaches utilizing phased array ultrasonics have been attempted to expand the abilities of AU techniques. By combining variable placement of apertures, angle and depth of focus, the techniques provide the potential to obtain parameters at various depths in the material. Initial results of the study and possible procedures for application of the techniques are discussed.

  11. Toward understanding the effect of low-activity waste glass composition on sulfur solubility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; Kim, Dong -Sang; Muller, Isabelle S.; Piepel, Greg F.; Kruger, Albert A.; Jantzen, C.

    2014-07-24

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which inmore »turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. As a result, the order of component effects is similar to previous literature data, in most cases.« less

  12. NONEQUILIBRIUM SULFUR CAPTURE & RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR

    SciTech Connect (OSTI)

    Bert Zauderer

    2003-04-21

    Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. The reacted particles impact and melt in the liquid slag layer on the combustor wall by the centrifugal force of the swirling combustion gases. Due to the low solubility of sulfur in slag, it must be rapidly drained from the combustor to limit sulfur gas re-evolution. Prior analyses and laboratory scale data indicated that for Coal Tech's 20 MMBtu/hour, air-cooled, slagging coal combustor slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to validate this sulfur-in-slag model in a group of combustor tests. A total of 36 days of testing on the combustor were completed during the period of performance of this project. This was more that double the 16 test days that were required in the original work statement. The extra tests were made possible by cost saving innovations that were made in the operation of the combustor test facility and in additional investment of Coal Tech resources in the test effort. The original project plan called for two groups of tests. The first group of tests involved the injection of calcium sulfate particles in the form of gypsum or plaster of Paris with the coal into the 20 MMBtu/hour-combustor. The second group of tests consisted of the entire two-step process, in which lime or limestone is co-injected with coal and reacts with the sulfur gas released during combustion to form calcium sulfate particles that impact and dissolve in the slag layer. Since this sulfur capture process has been validated in numerous prior tests in this combustor, the primary effort in the present project was on achieving the high slag flow rates needed to retain the sulfur in the slag.

  13. Toward Understanding the Effect of Nuclear Waste Glass Composition on Sulfur Solubility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which inmore »turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.« less

  14. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Gregory F.; Kruger, Albert A.

    2014-10-01

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis). If the amount of sulfur exceeds its tolerance level a molten salt will accumulate and upset melter operations and potentially shorten melter useful life. Therefore relatively conservative limits have been placed on sulfur loading in melter feed which in-turn significantly impacts the amount of glass that will be produced, in particular at the Hanford site. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 312 individual glass compositions. This model was shown to well represent the data, accounting for over 80% of the variation in data and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed based on 19 scaled melter tests. The model is appropriate for control of waste glass processing which includes uncertainty quantification. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5 ? TiO2 < CaO < P2O5 ? ZnO. The components that most decrease sulfur solubility are Cl > Cr2O3 > SiO2 ? ZrO2 > Al2O3.

  15. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  16. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

    1987-03-10

    This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

  17. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  18. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  19. Commercial-Grade, Scalable Support and Training Services Platform...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Services Platform Commercial-Grade, Scalable Support and Training Services Platform Lead Performer: Big Ladder Software - Denver, CO DOE Funding: 149,554 Cost Share: NA...

  20. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1998 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and Selected States (Cents per...

  1. Table 32. Conventional Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1998 Table 32. Conventional Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  2. Table 34. Reformulated Motor Gasoline Prices by Grade, Sales...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1999 Table 34. Reformulated Motor Gasoline Prices by Grade, Sales Type, PAD District, and Selected States (Cents per...

  3. Graded-Refractive-Index Glass-based Antireflective Coatings:...

    Office of Scientific and Technical Information (OSTI)

    Graded-Refractive-Index Glass-based Antireflective Coatings: BroadbandOmnidirectional Light Harvesting and Self-Cleaning Characteristics Citation Details In-Document Search Title:...

  4. Queen's University Grading Scale Effective May 1, 2011

    E-Print Network [OSTI]

    Wehlau, David

    .0 Marginal F 0.0 Failure P Pass Credit Unit Conversions Faculty of Engineering and Applied Science Units Conversion* A+ 4.3 90-100 A 4.0 85-89.9 A- 3.7 80-84.9 B+ 3.3 77-79.9 B 3.0 73-76.9 B- 2.7 Min. passing grade) Grading Scale Letter Grade Grade Points Percentage Conversion* A 4.0 80 ­ 100 B 3.0 70 ­ 79 C 2.0 60 ­ 69

  5. Petroleum Products Table 31. Motor Gasoline Prices by Grade...

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 2000 Table 31. Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon Excluding Taxes) -...

  6. Table 32. Conventional Motor Gasoline Prices by Grade, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1998 Table 32. Conventional Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon Excluding Taxes) -...

  7. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    of table. 134 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per...

  8. Content-Aware Image enhancement

    E-Print Network [OSTI]

    Schettini, Raimondo

    1 Content-Aware Image enhancement R. Schettini www.ivl.disco.unimib.it 8 Faculties, 61 Degree Recognition Content-based retrieval Quality Assessment Content-Aware Image Enhancement Presentation Outline Processing Content aware image enhancement We focus here on image based features. And show how to exploit

  9. Content-Aware Image enhancement

    E-Print Network [OSTI]

    Schettini, Raimondo

    Content-Aware Image enhancement R. Schettini www.ivl.disco.unimib.it #12;8 Faculties, 61 Degree Recognition Content-based retrieval Quality Assessment #12;Content-Aware Image Enhancement Presentation Image Processing Content aware image enhancement We focus here on image based features. And show how

  10. ISSUE TABLE OF CONTENTS

    E-Print Network [OSTI]

    SPECTRA HOME CURRENT ISSUE TABLE OF CONTENTS TECHNOLOGY BUSINESS PRESSTIME BULLETIN ARTICLE Thomas Young's classic setup for the demonstration of interference features light from one source incident on two vertical slits because the phenomenon occurs only if the light from the slits has a well

  11. Table of Contents Introduction

    E-Print Network [OSTI]

    Nagy, Eric Sándor

    include nitrogen oxides (NOx = NO + NO2 ), nitric acid (HNO3 ), nitrous oxide (N2 O, a greenhouse gas.TheHaber-BoschprocessalsosuppliesNH3 for industrial processes. Anthropogenic sources of nitrogen are twice as large as natural terDRAFT - 1 #12;2 - DRAFT Table of Contents Introduction What is Reactive Nitrogen and Why

  12. OIMB GK12 CURRICULUM Grade 60 minutes

    E-Print Network [OSTI]

    precipitating out of the vent water; and AMAZINGLY, communities of never-before- seen animals were living. Hydrogen sulfide is poisonous to most animals, but in the vent community, it is the basic source of energy Science Content Standards: 5.2 Interaction and Change: Force, energy, matter, and organisms interact

  13. Method of making a functionally graded material

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Menchhofer, Paul A. (Clinton, TN); Walls, Claudia A. (Oak Ridge, TN); Moorhead, Arthur J. (Knoxville, TN)

    2002-01-01

    A gelcasting method of making an internally graded article alternatively includes the steps of: preparing a slurry including a least two different phases suspended in a gelcasting solution, the phases characterized by having different settling characteristics; casting the slurry into a mold having a selected shape; allowing the slurry to stand for a sufficient period of time to permit desired gravitational fractionation in order to achieve a vertical compositional gradient in the molded slurry; gelling the slurry to form a solid gel while preserving the vertical compositional gradient in the molded slurry; drying the gel to form a dried green body; and sintering the dry green body to form a solid object, at least one property thereof varying along the vertical direction because of the compositional gradient in the molded slurry.

  14. Nitinol engine for low grade heat

    SciTech Connect (OSTI)

    Li, Y.T.

    1981-12-01

    A continuous band of nitinol wrapping in between a cluster of tightly engaged rollers to form a series of s-shaped bends is used as the principle working medium of a thermal engine to convert low grade heat to mechanical power output. The band, together with the rollers, divides the space into an inner and an outer zone. A stream of warmer water and a stream of cooler water are guided to flow separately through one or the other of the two zones to make uniform and intimate contact with the segments of the nitinol band alternatively at appropriate intervals. A well defined four-cycle operation of temperature and stress is thus established and can convert a portion of the energy which is available in the thermal gradient of the two water streams into a mechanical shaft power which may be tapped from one of the rollers.

  15. Method of making a functionally graded material

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); Menchhofer, Paul A. (Clinton, TN); Walls, Claudia A. (Oak Ridge, TN)

    2001-01-01

    A gelcasting method of making an internally graded article includes the steps of: preparing at least two slurries, each of the slurries including a different gelcastable powder suspended in a gelcasting solution, the slurries characterized by having comparable shrinkage upon drying and sintering thereof; casting the slurries into a mold having a selected shape, wherein relative proportions of the slurries is varied in at least one direction within the selected shape; gelling the slurries to form a solid gel while preserving the variation in relative proportions of the slurries; drying the gel to form a dried green body; and sintering the dry green body to form a solid object, at least one property thereof varying because of the variation in relative proportions of the starting slurries. A gelcasting method of making an internally graded article alternatively includes the steps of: preparing a slurry including a least two different phases suspended in a gelcasting solution, the phases characterized by having different settling characteristics; casting the slurry into a mold having a selected shape; allowing the slurry to stand for a sufficient period of time to permit desired gravitational fractionation in order to achieve a vertical compositional gradient in the molded slurry; gelling the slurry to form a solid gel while preserving the vertical compositional gradient in the molded slurry; drying the gel to form a dried green body; and sintering the dry green body to form a solid object, at least one property thereof varying along the vertical direction because of the compositional gradient in the molded slurry.

  16. 1300 Federal Register / Vol. 67, No. 7 / Thursday, January 10, 2002 / Rules and Regulations determining sulfur content in fuel for

    E-Print Network [OSTI]

    emission data to ISO conditions? A2: Yes. DP&L may waive the requirement to convert results to ISO use RATA results obtained during certification of the NOX CEMs to demonstrate initial compliance

  17. Agenda of critical issues: coal price and availability. Final report. [Includes effect of legislation, sulfur content and rail transport costs

    SciTech Connect (OSTI)

    Tennican, M.L.; Wayland, R.E.; Weinstein, D.M.

    1984-10-01

    Temple, Barker, and Sloane, Inc. developed an agenda of critical issues regarding future coal prices and coal availability for EPRI. TBS interviewed nearly 50 utility, coal company, and railroad officials, academic experts, and coal consultants; held a one-day participatory workshop; and conducted a literature review and follow-up interviews with selected utilities. TBS found four causes of uncertainty in the utility industry over future coal prices. First, the acid deposition proposals in Congress vary in terms of the structure of the legislation, the costs of compliance, and the impact on coal prices; in turn these uncertainties impede utility fuel planning and decision making. Second, powerplant-specific factors will have a major impact on whether utilities switch or scrub in response to acid deposition legislation; existing analyses do not capture these factors. The most important powerplant-specific factors are matching unit characteristics with coal specifications, retrofit scrubber costs, and differing state regulatory environments. Third, TBS found that utility fuel managers have great uncertainty over the availability and future cost of compliance coal. TBS estimated that the existing production capacity of eastern compliance coal is at least twice as high as current production. Fourth, TBS concluded that uncertainty over future coal transportation rates was a major reason for utilities' uncertainty over future delivered prices of coal. Critical transportation-related issues are the strategic and tactical response of eastern coal producers to the Staggers Act; the impact on rail rates of the sale of Conrail, of possible transcontinental mergers, and of multi-modal mergers; and the future pricing policies that eastern railroads will adopt in response to imports of Colombian coal. 21 references.

  18. Did the Clean Air Act cause the remarkable decline in sulfur dioxide concentrations?

    E-Print Network [OSTI]

    Greenstone, Michael

    2003-01-01

    Over the last three decades, ambient concentrations of sulfur dioxide (SO2) air pollution have declined by approximately 80%. This paper tests whether the 1970 Clean Air Act and its subsequent amendments caused this decline. ...

  19. Frataxin (FXN) Based Regulation of the Iron-Sulfur Cluster Assembly Complex 

    E-Print Network [OSTI]

    Rabb, Jennifer

    2012-07-16

    Iron-sulfur clusters are protein cofactors that are critical for all life forms. Elaborate multi-component systems have evolved for the biosynthesis of these cofactors to protect organisms from the toxic effects of free ...

  20. Transport Properties and Performance of Polymer Electrolyte Membranes for the Hybrid Sulfur Electrolyzer

    E-Print Network [OSTI]

    Weidner, John W.

    Transport Properties and Performance of Polymer Electrolyte Membranes for the Hybrid Sulfur hydrogen efficiently on a large scale.1 This process has the advantage over traditional i.e., coal gasifica

  1. Sulfur and Oxygen Isotope Analysis of Sulfate at Micromole Levels Using a Pyrolysis Technique in a

    E-Print Network [OSTI]

    Alexander, Becky

    Sulfur and Oxygen Isotope Analysis of Sulfate at Micromole Levels Using a Pyrolysis Technique sample. The technique takes advantage of the easy pyrolysis of Ag2SO4 to SO2, O2, and Ag metal

  2. SO2 impacts on forage and soil sulfur concentrations near coal-fired power plants 

    E-Print Network [OSTI]

    Beene, Jack Stephen

    1995-01-01

    The goal of this research was to determine if S02 emissions from coal-fired power plants could be contributing to the copper deficiency in cattle. Copper deficiency in cattle can result from excessive sulfur intake which is attributed...

  3. Cost-benefit analysis of ultra-low sulfur jet fuel

    E-Print Network [OSTI]

    Kuhn, Stephen (Stephen Richard)

    2010-01-01

    The growth of aviation has spurred increased study of its environmental impacts and the possible mitigation thereof. One emissions reduction option is the introduction of an Ultra Low Sulfur (ULS) jet fuel standard for ...

  4. Explaining low sulfur dioxide allowance prices : the effect of expectation errors and irreversibility

    E-Print Network [OSTI]

    Montero, Juan-Pablo

    1998-01-01

    The low price of allowances has been a frequently noted featured of the implementation of the sulfur dioxide emissions market of the U.S. Acid Rain Program. This paper presents theoretical and numerical analyses that explain ...

  5. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es105liang2011o.pdf More Documents & Publications CarbonSulfur...

  6. Carbon-Sulfur Bond Cleavage of Methyl-Substituted Thiophenes with Iridium(III)

    E-Print Network [OSTI]

    Jones, William D.

    polluting sulfur compounds are removed during the hydroprocessing of crude oil. Unrefined petroleum contains of a hydrogen acceptor, the thiophene was desulfurized (eq 2).4 Also, in the heterogeneous CoMo system it has

  7. Facile synthesis, spectral properties and formation mechanism of sulfur nanorods in PEG-200

    SciTech Connect (OSTI)

    Xie, Xin-yuan; Li, Li-yun; Zheng, Pu-sheng; Zheng, Wen-jie; Bai, Yan; Cheng, Tian-feng; Liu, Jie

    2012-11-15

    Graphical abstract: Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of about 6–8 was obtained. The sulfur nanoparticles could self-assemble from spherical particles to nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift which was due to the production of nanorods. Highlights: ? A novel, facile and greener method to synthesize sulfur nanorods by the solubilizing and templating effect of PEG-200 was reported. ? S{sup 0} nanoparticles could self assemble in PEG-200 and finally form monodisperse and homogeneous rod-like structure with an average diameter of about 80 nm, the length ca. 600 nm. ? The absorption band showed a red shift and the RRS intensity enhanced continuously during the self-assembling process. ? PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. -- Abstract: The synthesis of nano-sulfur sol by dissolving sublimed sulfur in a green solvent-PEG-200 was studied. Homogeneous rod-like structure of sulfur with a typical diameter of about 80 nm and an average aspect ratio of 6–8 was obtained. The structure, morphology, size, and stability of the products were investigated by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering (DLS) measurements. The spectral properties of the products were investigated by ultraviolet-visible (UV–vis) absorption and resonance Rayleigh scattering spectroscopy (RRS). The results showed that the spherical sulfur nanoparticles could self-assemble into nanorods in PEG-200. During the self-assembling process, the absorption band showed a red shift and the RRS intensity enhanced continuously. There was physical cross-linking between PEG and sulfur nanoparticles. PEG-200 induced the oriented attachment of sulfur nanoparticles by the terminal hydroxyl groups. This research provides a greener and more environment-friendly synthetic method for the production of sulfur nanorods.

  8. Fast-regenerable sulfur dioxide adsorbents for diesel engine emission control

    DOE Patents [OSTI]

    Li, Liyu [Richland, WA; King, David L [Richland, WA

    2011-03-15

    Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.

  9. ComputerDerived Nuclear "Grade" and Breast Cancer Prognosis

    E-Print Network [OSTI]

    Street, Nick

    Wolberg 1 Computer­Derived Nuclear "Grade" and Breast Cancer Prognosis William H. Wolberg, M.D., W of nuclear grade are subjective, yet still prognostically important. Now, computer­based analytical techniques can objectively and accurately measure size, shape, and texture features that constitute nuclear

  10. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore »a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  11. Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products

    SciTech Connect (OSTI)

    Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

    2011-11-17

    A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

  12. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  13. Sulfur oxidation to sulfate coupled with electron transfer to electrodes by Desulfuromonas strain TZ1

    SciTech Connect (OSTI)

    Zhang, T; Bain, TS; Barlett, MA; Dar, SA; Snoeyenbos-West, OL; Nevin, KP; Lovley, DR

    2014-01-02

    Microbial oxidation of elemental sulfur with an electrode serving as the electron acceptor is of interest because this may play an important role in the recovery of electrons from sulfidic wastes and for current production in marine benthic microbial fuel cells. Enrichments initiated with a marine sediment inoculum, with elemental sulfur as the electron donor and a positively poised (+300 mV versus Ag/AgCl) anode as the electron acceptor, yielded an anode biofilm with a diversity of micro-organisms, including Thiobacillus, Sulfurimonas, Pseudomonas, Clostridium and Desulfuromonas species. Further enrichment of the anode biofilm inoculum in medium with elemental sulfur as the electron donor and Fe(III) oxide as the electron acceptor, followed by isolation in solidified sulfur/Fe(III) medium yielded a strain of Desulfuromonas, designated strain TZ1. Strain TZ1 effectively oxidized elemental sulfur to sulfate with an anode serving as the sole electron acceptor, at rates faster than Desulfobulbus propionicus, the only other organism in pure culture previously shown to oxidize S with current production. The abundance of Desulfuromonas species enriched on the anodes of marine benthic fuel cells has previously been interpreted as acetate oxidation driving current production, but the results presented here suggest that sulfur-driven current production is a likely alternative.

  14. Sulfur dioxide-induced chronic bronchitis in beagle dogs

    SciTech Connect (OSTI)

    Greene, S.A.; Wolff, R.K.; Hahn, F.F.; Henderson, R.F.; Mauderly, J.L.; Lundgren, D.L.

    1984-01-01

    This study was done to produce a model of chronic bronchitis. Twelve beagle dogs were exposed to 500 ppm sulfur dioxide (SO/sub 2/) for 2 h/d, 5d/wk for 21 wk and 4 dogs were sham-exposed to filtered ambient air for the same period. Exposure effects were evaluated by periodically examining the dogs using chest radiographs, pulmonary function, tracheal mucous clearance, and the cellular and soluble components of bronchopulmonary lavage fluids. Dogs were serially sacrificed after 13 and 21 wk of exposure and after 6 and 14 wk of recovery. Clinical signs produced in the SO/sub 2/-exposed dogs included mucoid nasal discharge, productive cough, moist rales on auscultation, tonsilitis, and conjunctivitis. Chest radiographs revealed mild peribronchiolar thickening. Histopathology, tracheal mucous clearance measurements, and lavage cytology were consistent with a diagnosis of chronic bronchitis. It is concluded that repeated exposure to 500 ppm SO/sub 2/ for 21 wk produced chronic bronchitis in the beagle dog. Complete recovery occurred within 5 wk following cessation of SO/sub 2/ exposure. 43 references, 2 figures, 2 tables.

  15. Longitudinal study of children exposed to sulfur oxides

    SciTech Connect (OSTI)

    Dodge, R.; Solomon, P.; Moyers, J.; Hayes, C.

    1985-05-01

    This study is a longitudinal comparison of the health of children exposed to markedly different concentrations of sulfur dioxide and moderately different concentrations of particulate sulfate. The four groups of subjects lived in two areas of one smelter town and in two other towns, one of which was also a smelter town. In the area of highest pollution, children were intermittently exposed to high SO/sub 2/ levels (peak three-hour average concentration exceeded 2,500 micrograms/m3) and moderate particulate SO/sub 4/= levels (average concentration was 10.1 micrograms/m3). When the children were grouped by the four gradients of pollution observed, the prevalence of cough (measured by questionnaire) correlated significantly with pollution levels (trend chi-square = 5.6, p = 0.02). No significant differences in the incidence of cough or other symptoms occurred among the groups of subjects over three years, and pulmonary function and lung function growth over the study were roughly equal among all the groups. These results suggest that intermittent elevations in SO/sub 2/ concentration, in the presence of moderate particulate SO/sub 4/= concentration, produced evidence of bronchial irritation in the subjects, but no chronic effect on lung function or lung function growth was detected.

  16. Sulfur gas sensor using a calcium fluoride solid electrolyte

    SciTech Connect (OSTI)

    Toniguchi, M.; Wakihara, M.; Uchida, T.; Hirakawa, K.; Nii, J.

    1988-01-01

    The sulfur gas potentials in the H/sub 2/S + H/sub 2/ buffer gases were measured by a galvanic cell Ps/sub 2/(g),Au(Pt)/(MoS/sub 2/ + CaS)/CaF/sub 2//(Cu + Cu/sub 2/S + CaS)/Au(Pt) in the temperature range from 650/sup 0/ to 950/sup 0/C and Ps/sub 2/ region from 10/sup -2/ to 10/sup -10/ atm. A quick response time (within 5 to 10 min) in emf with the change of Ps/sub 2/ at a given temperature was observed by placing a MoS/sub 2/ and CaS mixed pellet auxiliary electrode at the bottom of the cylindrical single-crystal CaF/sub 2/ electrolyte. The observed emf's agreed well with with those calculated from the Nernst equation. Using this sensor, Ps/sub 2/ values in the SO/sub 2/ + H/sub 2/ + H/sub 2/S gas system were also evaluated from the measured emf at 827/sup 0/C and were found to be in close agreement with those calculated from the thermochemical tables.

  17. Low-Cost Illumination-Grade LEDs

    SciTech Connect (OSTI)

    Epler, John

    2013-08-31

    Solid State Lighting is a cost-effective, energy-conserving technology serving a rapidly expand- ing multi-billion dollar market. This program was designed to accelerate this lighting revolution by reducing the manufacturing cost of Illumination-Grade LEDs. The technical strategy was to investigate growth substrate alternatives to standard planar sapphire, select the most effective and compatible option, and demonstrate a significant increase in Lumen/$ with a marketable LED. The most obvious alternate substrate, silicon, was extensively studied in the first two years of the program. The superior thermal and mechanical properties of Si were expected to improve wavelength uniformity and hence color yield in the manufacture of high-power illumination- grade LEDs. However, improvements in efficiency and epitaxy uniformity on standard c-plane sapphire diminished the advantages of switching to Si. Furthermore, the cost of sapphire decreased significantly and the cost of processing Si devices using our thin film process was higher than expected. We concluded that GaN on Si was a viable technology but not a practical option for Philips Lumileds. Therefore in 2012 and 2013, we sought and received amendments which broadened the scope to include other substrates and extended the time of execution. Proprietary engineered substrates, off-axis (non-c-plane) sapphire, and c-plane patterned sapphire substrates (PSS) were all investigated in the final 18 months of this program. Excellent epitaxy quality was achieved on all three candidates; however we eliminated engineered substrates and non-c-plane sapphire because of their higher combined cost of substrate, device fabrication and packaging. Ultimately, by fabricating a flip-chip (FC) LED based upon c-plane PSS we attained a 42% reduction in LED manufacturing cost relative to our LUXEON Rebel product (Q1-2012). Combined with a flux gain from 85 to 102 Lm, the LUXEON Q delivered a 210% increase in Lm/$ over this time period. The technology was commercialized in our LUXEON Q product in Sept., 2013. Also, the retention of the sapphire increased the robustness of the device, enabling sales of low-cost submount-free chips to lighting manufacturers. Thus, blue LED die sales were initiated in the form of a PSS-FC in February, 2013.

  18. Production of battery grade materials via an oxalate method

    DOE Patents [OSTI]

    Belharouak, Ilias; Amine, Khalil

    2014-04-29

    An active electrode material for electrochemical devices such as lithium ion batteries includes a lithium transition metal oxide which is free of sodium and sulfur contaminants. The lithium transition metal oxide is prepared by calcining a mixture of a lithium precursor and a transition metal oxalate. Electrochemical devices use such active electrodes.

  19. A Content Propagation Metric for Efficient Content Distribution

    E-Print Network [OSTI]

    Keinan, Alon

    A Content Propagation Metric for Efficient Content Distribution Ryan S. Peterson Cornell University@cs.cornell.edu ABSTRACT Efficient content distribution in large networks comprising data- centers, end hosts, and distributed in-network caches is a diffi- cult problem. Existing systems rely on mechanisms and metrics

  20. Web Content Filtering 1 User Guidelines Web content filter guidelines

    E-Print Network [OSTI]

    Swain, Peter

    Web Content Filtering 1 User Guidelines Web content filter guidelines Introduction The basic criterion for blocking a Web page Categories of material which will be blocked Requesting the unblocking of Aberdeen applies a Web Content Filtering service to all web pages accessed from the undergraduate network

  1. Observation of neutral sulfuric acid-amine containing clusters in laboratory and ambient measurements

    SciTech Connect (OSTI)

    Kuang C.; Zhao, J.; Smith, J. N.; Eisele, F. L.; Chen, M.; McMurry, P. H.

    2011-11-02

    Recent ab initio calculations showed that amines can enhance atmospheric sulfuric acid-water nucleation more effectively than ammonia, and this prediction has been substantiated in laboratory measurements. Laboratory studies have also shown that amines can effectively displace ammonia in several types of ammonium clusters. However, the roles of amines in cluster formation and growth at a microscopic molecular scale (from molecular sizes up to 2 nm) have not yet been well understood. Processes that must be understood include the incorporation of amines into sulfuric acid clusters and the formation of organic salts in freshly nucleated particles, which contributes significantly to particle growth rates. We report the first laboratory and ambient measurements of neutral sulfuric acid-amine clusters using the Cluster CIMS, a recently-developed mass spectrometer designed for measuring neutral clusters formed in the atmosphere during nucleation. An experimental technique, which we refer to as Semi-Ambient Signal Amplification (SASA), was employed. Sulfuric acid was added to ambient air, and the concentrations and composition of clusters in this mixture were analyzed by the Cluster CIMS. This experimental approach led to significantly higher cluster concentrations than are normally found in ambient air, thereby increasing signal-to-noise levels and allowing us to study reactions between gas phase species in ambient air and sulfuric acid containing clusters. Mass peaks corresponding to clusters containing four H{sub 2}SO{sub 4} molecules and one amine molecule were clearly observed, with the most abundant sulfuric acid-amine clusters being those containing a C2- or C4-amine (i.e. amines with masses of 45 and 73 amu). Evidence for C3- and C5-amines (i.e. amines with masses of 59 and 87 amu) was also found, but their correlation with sulfuric acid tetramer was not as strong as was observed for the C2- and C4-amines. The formation mechanisms for those sulfuric acid-amine clusters were investigated by varying the residence time in the inlet. It was concluded that the amines react directly with neutral clusters and that ion-induced clustering of sulfuric acid cluster ions with amines was not a dominant process. Results from ambient measurements using the Cluster CIMS without addition of sulfuric acid have shown that the sulfuric acid-amine clusters were reasonably well correlated with sulfuric acid tetramer and consistent with the SASA experiments at the same Boulder sampling site. Also, clusters that contain C2- or C4-amines were more abundant and better correlated with sulfuric acid tetramer than other types of amine containing clusters. However, ambient measurements of sulfuric acid-amine clusters remain difficult and highly uncertain because their concentrations are only slightly above background levels, even during nucleation events.

  2. Perceptual Experience and Its Contents 

    E-Print Network [OSTI]

    Toribio, Josefa

    2002-01-01

    The contents of perceptual experience, it has been argued, often include a characteristic “non-conceptual” component (Evans, 1982). Rejecting such views, McDowell (1994) claims that such contents are conceptual in ...

  3. Mitigation of Sulfur Effects on a Lean NOx Trap Catalyst by Sorbate Reapplication

    SciTech Connect (OSTI)

    Parks, II, James E [ORNL

    2007-01-01

    Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by >90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping. Natural gas combusted over partial oxidation catalysts in the exhaust can be used to obtain the rich exhaust conditions necessary for catalyst regeneration. Thus, the lean NOx trap technology is well suited for lean natural gas engine applications. One potential limitation of the lean NOx trap technology is sulfur poisoning. Sulfur compounds directly bond to the NOx trapping sites of the catalyst and render them ineffective; over time, the sulfur poisoning leads to degradation in overall NOx reduction performance. In order to mitigate the effects of sulfur poisoning, a process has been developed to restore catalyst activity after sulfur poisoning has occurred. The process is an aqueous-based wash process that removes the poisoned sorbate component of the catalyst. A new sorbate component is reapplied after removal of the poisoned sorbate. The process is low cost and does not involve reapplication of precious metal components of the catalyst. Experiments were conducted to investigate the feasibility of the washing process on a lean 8.3-liter natural gas engine on a dynamometer platform. The catalyst was rapidly sulfur poisoned with bottled SO2 gas; then, the catalyst sorbate was washed and reapplied and performance was re-evaluated. Results show that the sorbate reapplication process is effective at restoring lost performance due to sulfur poisoning. Specific details relative to the implementation of the process for large stationary natural gas engines will be discussed.

  4. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    SciTech Connect (OSTI)

    Elmore, B.B.

    1993-08-01

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  5. Sulfur containing sediments influenced wear of superheater tubes

    SciTech Connect (OSTI)

    Yoffe, P. [Israel Electric Corp. Ltd., Haifa (Israel)

    1996-10-01

    The failed superheater tube was investigated at the point of failure and at a distance of 25 cm. At both of the cross sections two layers of sediment were detected. The external one contains Na2SO4 and Na3VO3 in concentration relation 6.4:1 approximately. The internal layer that situated on the tube surface consisted of V2O3 mainly (about 70%) and sodium pyrosulfates Na2SO3{center_dot}xSO3. The tube surface was covered with usual passive oxides such as Cr2O3, Fe2CrO4, and magnetite. In the failed section the last layer contained iron and chromium sulfides. Thinning of the wall was detected in both sections, but it was more evident in the failed section. Thermodynamic and kinetic estimations of the results were carried out. The following failure mechanism was proposed: (1) at 460 C the pyrosulfate dissociates with SO3 emanation, during SO3 interaction with steel both passive oxides and iron sulfide are produced simultaneously, sulfides damage the passive (protective) film; (2) in vicinity of partition the temperature increases and the structure of steel is changed, SO3 penetration along grain boundaries is possible, and it leads to embrittlement of the steel through sulfidization; (3) the embrittled layer is stripped off by falling ash deposit and collapsed passive film, thinning of the tube is accelerated at such a region. So, sulfur containing sediment accelerates the wear of the tube. This acceleration is strong especially in the vicinity of the boiler walls.

  6. Personalized professional content recommendation

    DOE Patents [OSTI]

    Xu, Songhua

    2015-10-27

    A personalized content recommendation system includes a client interface configured to automatically monitor a user's information data stream transmitted on the Internet. A hybrid contextual behavioral and collaborative personal interest inference engine resident to a non-transient media generates automatic predictions about the interests of individual users of the system. A database server retains the user's personal interest profile based on a plurality of monitored information. The system also includes a server programmed to filter items in an incoming information stream with the personal interest profile and is further programmed to identify only those items of the incoming information stream that substantially match the personal interest profile.

  7. Personalized professional content recommendation

    DOE Patents [OSTI]

    Xu, Songhua

    2015-11-05

    A personalized content recommendation system includes a client interface configured to automatically monitor a user's information data stream transmitted on the Internet. A hybrid contextual behavioral and collaborative personal interest inference engine resident to a non-transient media generates automatic predictions about the interests of individual users of the system. A database server retains the user's personal interest profile based on a plurality of monitored information. The system also includes a server programmed to filter items in an incoming information stream with the personal interest profile and is further programmed to identify only those items of the incoming information stream that substantially match the personal interest profile.

  8. NESEA Newsletter Content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStressMoveMuncriefB NESEA Newsletter Content

  9. Rough contact mechanics for graded bulk rheology: The role of small-scale wavelengths on rubber friction

    E-Print Network [OSTI]

    Michele Scaraggi; Davide Comingio

    2015-10-13

    We present a numerical model for the prediction of the rough contact mechanics of a viscoelastic block, with graded rheology, in steady sliding contact with a randomly rough rigid surface. In particular, we derive the effective surface response of a stepwise or continuously-graded block in the Fourier domain, which is then embedded in a Fourier-based residuals molecular dynamic formulation of the contact mechanics. Finally we discuss on the role of small-scale wavelengths on rubber friction and contact area, and we demonstrate that the rough contact mechanics exhibits effective interface properties which converge to asymptotes upon increase of the small-scale roughness content, when a realistic rheology of the confinement is taken into account.

  10. ALL GRADE 5 AND GRADE 8 FASTENERS WHICH DO NOT BEAR ANY MANUFACTURERS'

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s s iof1AGGIEAL2007-04.pdfALF HOUSE WesternALL GRADE

  11. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01

    sulfur was strongly dependent on coal type. Gryglewicz [19]coal) [9] and other factors such as heating rate, time, pressure and velocity of the carrying gas, type

  12. Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals

    SciTech Connect (OSTI)

    Nabeel, A.; Khan, T.A.; Sharma, D.K. [Jamia Millia Islamia, New Delhi (India). Dept. of Chemistry

    2009-07-01

    The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

  13. Carbon, sulfur, and phosphorus relations in oceanic Neogene sediments 

    E-Print Network [OSTI]

    Mays, Linda Lowry

    1987-01-01

    of distinguishing paleoenvironments based on C/S ratios was also investigated. C/S ratios were found to have a previously unrecognized positive correlation with organic carbon concentration. They were frequently found to be unreliable indicators of depositional... to especially thank Saulwood Lin, Miguel Huerta-Diaz, and Takeshi Arakaki who assisted me in many ways throughout this project. vhl TABLL' Ol. CONTENTS INTRODUCTION. Page BACKGROUND. BASIS OF ENVIRONMENTAL INTERPRETATION FROM C/S RATIOS. STUDY AREA. 12...

  14. Toward Understanding the Effect of Nuclear Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D. [Pacific Northwest National Laboratory; Kim, Dong-Sang [Pacific Northwest National Laboratory; Muller, I. S. [The Catholic University National Laboratory; Kruger, Albert A. [Department of Energy -- Ofice of River Protection; Piepel, Gregory F. [Pacific Northwest National Laboratory

    2014-10-01

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

  15. Toward Understanding the Effect of Low-Activity Waste Glass Composition on Sulfur Solubility

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Muller, Isabelle S.; Piepel, Greg F.; Kruger, Albert A.

    2014-07-24

    The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

  16. Computational studies of experimentally observed structures of sulfur on metal surfaces

    SciTech Connect (OSTI)

    Alfonso, Dominic

    2011-09-01

    First-principles electronic structure calculations were carried out to examine the experimentally observed structures of sulfur on close packed surfaces of a number of important metals - Ag(111), Cu(111), Ni(111), Pt(111), Rh(111), Re(0001) and Ru(0001). At low coverages ({le} 1/3 ML), the prediction is consistent with the typical pattern of preferred sulfur occupancy of threefold hollow sites, notably the fcc site on the (111) surfaces and the hcp site on the (0001) surfaces. Theoretical confirmation for the existence of pure sulfur overlayer phases on Pt(111), Rh(111), Re(0001) and Ru(0001) at higher coverages (> 1/3 ML) was provided. For the ({radical}7 x {radical}7) phase seen on Ag(111), the most preferred structure identified for adsorbed S trimer consists of an S atom on the top site bonded to two S atoms situated on the nearest neighbor off-bridge site positions. Among the different densely packed mixed sulfur-metal overlayer models suggested for the ({radical}7 x {radical}7) phase on Cu(111), the structure which consists of metal and S atoms in a hexagonal-like arrangement on the top substrate was found to be the most energetically favorable. For the (5{radical}3 x 2) phase on Ni(111), the calculations confirm the existence of clock-reconstructed top layer metal atoms onto which sulfur atoms are adsorbed.

  17. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  18. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  19. Searching For An Electrical-Grade Geothermal Resource In Northern...

    Open Energy Info (EERE)

    Searching For An Electrical-Grade Geothermal Resource In Northern Arizona To Help Geopower The West Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference...

  20. British General Certificate of Education Subjects: Grade CreditsEquivalents

    E-Print Network [OSTI]

    Dennett, Daniel

    Diplomas British General Certificate of Education A-Level Subjects: Grade Credits *See Subject Credit & Equivaliency Chart International Baccalaureat Advanced Credit Subjects: Score Mathematics 7 1 MATH 0012 *No other subjects are awarded credit for subsidiary level French Baccalaureate

  1. Graded Recombination Layers for Multijunction Photovoltaics Ghada I. Koleilat,

    E-Print Network [OSTI]

    Sargent, Edward H. "Ted"

    -matched multijunction devices, the recombination layers must allow the hole current from one cell to recombine functions in the interlayers. KEYWORDS: Multijunction photovoltaics, tandem solar cell, graded recombination layer, thermionic and tunneling transport, transparent conductive oxides Multijunction solar cells raise

  2. ORIGINAL ARTICLE Utilization of diets containing graded levels of ethanol

    E-Print Network [OSTI]

    ORIGINAL ARTICLE Utilization of diets containing graded levels of ethanol production co to manufacture fuel ethanol (Rosentrater and Muthukumarappan, 2006). In 2008, 174 operating ethanol plants.1 billion liters (RFA, 2009). With this exponential growth in ethanol production, significant quantities

  3. Predicting and Utilizing the Vehicle's Past and Futuer Road Grade

    Broader source: Energy.gov [DOE]

    Predicted road grade may be used to estimate the power required to propel the vehicle through the upcoming terrain so that the engine controller can deliver the necessary power.

  4. Green Goals: Carbon Sequestration Grade Levels: 6 12

    E-Print Network [OSTI]

    Hammack, Richard

    Green Goals: Carbon Sequestration Grade Levels: 6 ­ 12 type of carbon sequestration. All plants sequester carbon; however, the larger Objective: To investigate the role of trees in atmospheric carbon dioxide reduction

  5. High-Performance Slab-on-Grade Foundation Insulation Retrofits

    SciTech Connect (OSTI)

    Goldberg, Louise F.; Mosiman, Garrett E.

    2015-09-01

    ?A more accurate assessment of slab-on-grade foundation insulation energy savings than traditionally possible is now feasible. This has been enabled by advances in whole building energy simulation with 3-dimensional foundation modelling integration at each time step together with an experimental measurement of the site energy savings of SOG foundation insulation. Ten SOG insulation strategies were evaluated on a test building to identify an optimum retrofit insulation strategy in a zone 6 climate (Minneapolis, MN). The optimum insulation strategy in terms of energy savings and cost effectiveness consisted of two components: (a) R-20 XPS insulation above grade, and, (b) R-20 insulation at grade (comprising an outer layer of R-10 insulation and an interior layer of R-12 poured polyurethane insulation) tapering to R-10 XPS insulation at half the below-grade wall height (the lower half of the stem wall was uninsulated).

  6. Stochastic multiscale models for fracture analysis of functionally graded materials

    E-Print Network [OSTI]

    Rahman, Sharif

    Stochastic multiscale models for fracture analysis of functionally graded materials Arindam three multiscale models, including sequential, invasive, and concurrent models, for fracture analysis methods for fracture reliability analysis. The par- ticle volume fractions, defined by a generic

  7. Improved Grades and Consumer Demand for In-Shell Pecans. 

    E-Print Network [OSTI]

    Brison, Fred R.; Branson, Robert E.; Clark, Wayne W.; Krezdorn, A. H.; Storey, J. B.

    1959-01-01

    Grade Index for Pecans. ............ Kernel Percentage ........................ Kernel Quality Index. ...................... Kernel Size Index. .......................... Nut Defects. ................................. 8 Comparison of Proposed Grade...-SHELL PECANS FRED R. BRISON, ROBERT E. BRANSON, WAYNE W. CLARK, A. H. KREZDORN and J. B. STOREY* I HE AVERAGE ANNUAL U. S. PECAN CROP for are available from February through Septem- T the 10-year period ending with 1956 was ber. Other nuts often are offered...

  8. Noncommutative Galois Extension and Graded q-Differential Algebra

    E-Print Network [OSTI]

    Abramov, Viktor

    2015-01-01

    We show that a semi-commutative Galois extension of a unital associative algebra can be endowed with the structure of a graded q-differential algebra. We study the first and higher order noncommutative differential calculus of semi-commutative Galois extension induced by the graded q-differential algebra. As an example we consider the quaternions which can be viewed as the semi-commutative Galois extension of complex numbers.

  9. High-Capacity Sulfur Dioxide Absorbents for Diesel Emissions Control

    SciTech Connect (OSTI)

    Li, Liyu; King, David L.

    2005-01-05

    High capacity sulfur dioxide absorbents based on manganese oxide octahedral molecular sieves (OMS) have been identified. These materials are based on MnO6 octahedra sharing faces and edges to form various tunnel structures (2x2, 2x3, 2x4, 3x3) differentiated by the number of octahedra on a side. The SO2 capacities of these materials, measured at 325 C with a feed containing 250 ppmv SO2 in air, are as high as 70wt% (wt/wt), remarkably higher than conventional metal oxide-based SO2 absorbents. Among the OMS materials the 2x2 member, cryptomelane, exhibits the highest capacity and adsorption rate. Its SO2 absorption behavior has been further characterized as a function of temperature, space velocity, and feed composition. The dominant pathway for SO2 absorption is through the oxidation of SO2 to SO3 by Mn4+ followed by SO3 reaction with Mn2+ to form MnSO4. Absorption can occur in the absence of gas phase oxygen, with a moderate loss in overall capacity. The inclusion of reducible gases NO and CO in the feed does not reduce SO2 capacity. The absorption capacity decreases at high space velocity and lower absorption temperature, indicating the important role of diffusion of sulfate from the surface to the bulk of the material in order to reach full capacity. A color change of cryptomelane from black to yellow-brown after SO2 absorption can be used as an indicator of absorption progress. Cryptomelane can be synthesized using MnSO4 as a reagent. Therefore, after full SO2 absorption the product MnSO4 can be re-used as raw material for a subsequent cryptomelane synthesis. Cryptomelane has a similarly high capacity toward SO3, therefore it can be used for removal of all SOx species generated from a variety of combustion sources. Cryptomelane may find application as a replaceable absorbent for the removal of SOx from diesel truck exhaust, protecting downstream emissions control devices such as particulate filters and NOx traps.

  10. Polymorphous low-grade adenocarcinoma in the upper lip: a well-described but infrequently recognized tumor.

    E-Print Network [OSTI]

    Andreu-Barasoain, Marta; Vicente-Martin, Javier; Gomez de la Fuente, Enrique; Salamanca-Santamaria, Javier; Pampin-Franco, Ana; Lopez-Estebaranz, Jose Luiz

    2013-01-01

    Polymorphous low-grade adenocarcinoma of the head and neck.Polymorphous low-grade adenocarcinoma. Arch Otolaryngol Head

  11. U.S. Dept of Energy’s EECBG-SEP Technical Assistance Program Webcast ESPC Investment Grade Audit

    Broader source: Energy.gov [DOE]

    Learn what the investment grade audit is, what to expect from an investment grade audit, how to ensure IGA success.

  12. Effect of sulfur loading on the desulfation chemistry of a commercial lean NOx trap catalyst

    SciTech Connect (OSTI)

    Kim, Do Heui; Yezerets, Aleksey; Li, Junhui; Currier, Neal; Chen, Haiying; Hess, Howard .; Engelhard, Mark H.; Muntean, George G.; Peden, Charles HF

    2012-12-15

    We investigate the effects of initial sulfur loadings on the desulfation chemistry and the subsequent final activity of a commercial LNT catalyst. Identical total amounts of SO2 are applied to the samples, albeit with the frequency of desulfation varied. The results indicate that performance is better with less frequent desulfations. The greater the amount of sulfur deposited before desulfation, the more amount of SO2 evolution before H2S is observed during desulfation, which can be explained by two sequential reactions; initial conversion of sulfate to SO2, followed by the reduction of SO2 to H2S. After completing all sulfation/desulfation steps, the sample with only a single desulfation results in a fairly uniform sulfur distribution along the z-axis inside of the monolith. We expect that the results obtained in this study will provide useful information for optimizing regeneration strategies in vehicles that utilize the LNT technology.

  13. Desulfurization of organic sulfur from lignite by an electron transfer process

    SciTech Connect (OSTI)

    Demirbas, A. [Selcuk University, Konya (Turkey). Dept. for Chemical Engineering

    2006-10-15

    This study is an attempt to desulfurize organic sulfur from lignite samples with ferrocyanide ion as the electron transferring agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the lignite samples has been investigated. The desulfurization process has been found to be continuous and gradually increases with increase of temperature from 298 to 368 K. The particle size has no significant impact on sulfur removal from the lignite samples. Particle size has no profound impact on the amount of sulfur removal. The desulfurization reaction has been found to be dependent on the concentration of potassium ferrocyanide. Gradual increase in the concentration of potassium ferrocyanide raised the magnitude of desulfurization, but at a higher concentration, the variation is not significant.

  14. Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming

    SciTech Connect (OSTI)

    Gunther Dieckmann

    2006-06-30

    In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

  15. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion

    SciTech Connect (OSTI)

    Chou, C.L.

    1991-01-01

    The purpose of this project is to conduct laboratory experiments to clarify the mechanism of boiler corrosion, which may lead to solving the corrosion problem associated with the utilization of Illinois' high-sulfur and high-chlorine coal. The kinetics of the release of sulfur and chlorine species during coal combustion is being determined in the laboratories using temperature-programmed pyrolysis coupled with quadrupole gas analysis (QGA) and thermogravimetric analysis in conjunction with Fourier transform infrared spectroscopy (FTIR). Samples of boiler deposits and ashes from different locations in boilers using Illinois coal will be analyzed for mineralogical and chemical compositions to understand the relations among deposit compositions, coal compositions, and the gaseous species in combustion gases. The relationship between the level of chlorine in Illinois coal and boiler corrosion will be studied by experiments with simulated combustion gases under combustion conditions. Reduction of sulfur and chloride concentrations in the flue gas using additives will also be evaluated.

  16. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J. (Bethel Park, PA)

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  17. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  18. Sonic enhanced ash agglomeration and sulfur capture. Quarterly technical progress report, April--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-01

    A major concern with the utilization of coal in directly fired gas turbines is the control of particulate emissions and reduction of sulfur dioxide, and alkali vapor from combustion of coal, upstream of the gas turbine. Much research and development has been sponsored on methods for particulate emissions control and the direct injection of calcium-based sorbents to reduce SO{sub 2} emission levels. The results of this research and development indicate that both acoustic agglomeration of particulates and direct injection of sorbents have the potential to become a significant emissions control strategy. The Sonic Enhanced Ash Agglomeration and Sulfur Capture program focuses upon the application of an MTCI proprietary invention (Patent No. 5,197,399) for simultaneously enhancing sulfur capture and particulate agglomeration of the combustor effluent. This application can be adapted as either a {open_quotes}hot flue gas cleanup{close_quotes} subsystem for the current concepts for combustor islands or as an alternative primary pulse combustor island in which slagging, sulfur capture, particulate agglomeration and control, and alkali gettering as well as NO{sub x} control processes become an integral part of the pulse combustion process. The goal of the program is to support the DOE mission in developing coal-fired combustion gas turbines. In particular, the MTCI proprietary process for bimodal ash agglomeration and simultaneous sulfur capture will be evaluated and developed. The technology embodiment of the invention provides for the use of standard grind, moderately beneficiated coal and WEM for firing the gas turbine with efficient sulfur capture and particulate emission control upstream of the turbine. The process also accommodates injection of alkali gettering material if necessary. The proposed technology provides for practical, reliable, and capital (and O&M) cost-effective means of protection for the gas turbine from impurities in the coal combustor effluent.

  19. A reanalysis of carbonyl sulfide as a source of stratospheric background sulfur aerosol

    SciTech Connect (OSTI)

    Chin, M.; Davis, D.D. [Georgia Institute of Technology, Atlanta, GA (United States)] [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-05-20

    The authors present an analysis of carbonyl sulfide (OCS) in the earth`s atmosphere, with the objective being to assess its role in the formation of sulfate aerosols in the stratosphere. They review the amount of OCS in the atmosphere, its distribution between the troposphere and stratosphere, the estimated source term for emission to the atmosphere, and from one-dimensional model calculations infer a stratospheric lifetime to photochemical reactions of ten years. Calculations infer a sulfur production rate from OCS oxidation which is a factor of 2 to 5 less than recent sulfur aerosol estimates would infer. They discuss a number of possible explanations for the discrepancy.

  20. NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

    1992-01-01

    This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  1. NOx reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1993-08-31

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  2. NO.sub.x reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, Virendra K. (Durham, NH); Breault, Ronald W. (Kingston, NH); McLarnon, Christopher R. (Exeter, NH); Medros, Frank G. (Waltham, MA)

    1993-01-01

    This invention presents an NO.sub.x environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO.sub.x reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO.sub.x bearing gas stream at a minimum of at least about 75 watts/cubic meter.

  3. NO[sub x] reduction by sulfur tolerant coronal-catalytic apparatus and method

    DOE Patents [OSTI]

    Mathur, V.K.; Breault, R.W.; McLarnon, C.R.; Medros, F.G.

    1992-09-15

    This invention presents an NO[sub x] environment effective reduction apparatus comprising a sulfur tolerant coronal-catalyst such as high dielectric coronal-catalysts like glass wool, ceramic-glass wool or zirconium glass wool and method of use. In one embodiment the invention comprises an NO[sub x] reduction apparatus of sulfur tolerant coronal-catalyst adapted and configured for hypercritical presentation to an NO[sub x] bearing gas stream at a minimum of at least about 75 watts/cubic meter. 7 figs.

  4. Sulfur determination in blood from inhabitants of Brazil using neutron activation analysis

    SciTech Connect (OSTI)

    Oliveira, Laura C.; Zamboni, Cibele B.

    2013-05-06

    In this study the NAA technique was applied to analyze sulfur in blood from inhabitants of Brazil for the proposition of an indicative interval. The measurements were performed considering lifestyle factors (non-smokers, non-drinkers and no history of toxicological exposure) of Brazilian inhabitants. The influence of gender was also investigated considering several age ranges (18-29, 30-39, 40-49, >50 years). These data are useful in clinical investigations, to identify or prevent diseases caused by inadequate sulfur ingestion and for nutritional evaluation of Brazilian population.

  5. Preliminary analysis of patent trends for sodium/sulfur battery technology

    SciTech Connect (OSTI)

    Triplett, M.B.; Winter, C.; Ashton, W.B.

    1985-07-01

    This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

  6. Toxicology Studies on Lewisite and Sulfur Mustard Agents: Modified Dominant Lethal Study of Sulfur Mustard in Rats Final Report

    SciTech Connect (OSTI)

    Sasser, L. B.; Cushing, J. A.; Kalkwarf, D. R.; Buschbom, R. L.

    1989-05-01

    Occupational health standards have not been established for sulfur mustard (HD) [bis{2-chloroethyl)-sulfide) ' a strong alkylating agent with known mutagenic properties. Little, however, is known about the mutagenic activity of HD in mammalian species and data regarding the dominant lethal effects of HD are ambiguous. The purpose of this study was to determine the dominant lethal effect in male and female rats orally exposed to HD. The study was conducted in two phases; a female dominant lethal phase and a male dominant lethal phase. Sprague-Dawley rats of each sex were administered 0.08, 0.20, or 0.50 mg/kg HD in sesame oil 5 days/week for 10 weeks. For the female phase, treated or untreated males were mated with treated females and their fetuses were evaluated at approximately 14 days after copulation. For the male dominant lethal phase, treated males cohabited with untreated femal (during 5 days of each week for 10 weeks) and females were sacrificed for fetal evaluation 14 days after the midweek of cohabitation during each of the 10 weeks. The appearance and behavior of the rats were unremarkable throughout the experiment and there were no treatment-related deaths. Growth rates were reduced in both female and male rats treated with 0.50 mg/kg HD. Indicators of reproductive performance did not demonstrate significant female dominant lethal effects, although significant male dominant lethal effects were observed at 2 and 3 week post-exposure. These effects included increases of early fetal resorptions and preimplantation losses and decreases of total live embryo implants. These effects were most consistently observed at a dose of 0.50 mg/kg, but frequently occurred at the lower doses. Although no treatment-related effects on male reproductive organ weights or sperm motility were found, a significant increase in the percentage of abnormal sperm was detected in males exposed to 0. 50 mg/kg HD. The timing of these effects is consistent with an effect during the postmeiotic stages of spermatogenesis, possibly involving the generally sensitive spermatids.

  7. ATMOSPHERIC CHEMISTRY IN GIANT PLANETS, BROWN DWARFS, AND LOW-MASS DWARF STARS. II. SULFUR AND PHOSPHORUS

    E-Print Network [OSTI]

    ATMOSPHERIC CHEMISTRY IN GIANT PLANETS, BROWN DWARFS, AND LOW-MASS DWARF STARS. II. SULFUR AND PHOSPHORUS Channon Visscher, Katharina Lodders, and Bruce Fegley, Jr. Planetary Chemistry Laboratory to model sulfur and phosphorus chemistry in giant planets, brown dwarfs, and extrasolar giant planets (EGPs

  8. Carbon Flow of Heliobacteria Is Related More to Clostridia than to the Green Sulfur Bacteria*S

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    Carbon Flow of Heliobacteria Is Related More to Clostridia than to the Green Sulfur Bacteria*S, California 94720 The recently discovered heliobacteria are the only Gram-pos- itive photosynthetic bacteria the photosynthetic green sulfur bacteria (containing the type I reaction center) and Clostridia (forming heat

  9. Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost and equipment

    E-Print Network [OSTI]

    Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost gas instead of continuing to burn low-sulfur fuel oil, a report said. Switching to liquefied natural who switch from gasoline-powered vehicles to ones fueled by compressed natural gas could save as much

  10. Insertion of Elemental Sulfur and SO2 into the Metal-Hydride and Metal-Carbon Bonds of Platinum

    E-Print Network [OSTI]

    Jones, William D.

    and other alkyl and aryl compounds, followed by insertion of sulfur-bearing species to syn- thesize sulfur-bearing or main- group metals.2,3 A second resonance is seen in the 31P NMR spectrum at 67.02 (JPtP ) 1811 Hz

  11. Improved Visible Light Harvesting of WO3 by Incorporation of Sulfur or Iodine: A Tale of Two Impurities

    E-Print Network [OSTI]

    Lin, Jung-Fu "Afu"

    Improved Visible Light Harvesting of WO3 by Incorporation of Sulfur or Iodine: A Tale of Two report the incorporation of sulfur or iodine into monoclinic tungsten trioxide (S:WO3 or I:WO3 pyrolysis with either ammonium sulfide or iodide added to the aqueous WO3 precursor solutions. Red shifts

  12. Fun with the Sun- Teacher's Activity Guide for Elementary Grades K-2

    Broader source: Energy.gov [DOE]

    Outdoor solar activities. Grades: K-4 Subject: Energy Basics , Wind Energy , Energy Efficiency and Conservation

  13. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  14. ContentsContents2424Fourier 1. The Fourier transform

    E-Print Network [OSTI]

    Vickers, James

    ContentsContents2424Fourier transforms 1. The Fourier transform 2. Properties of the Fourier Transform 3. Some Special Fourier Transform Pairs Learning outcomes needs doing Time allocation You mathematical topics this time may vary considerably. 1 #12;The Fourier Transform 24.1 Introduction

  15. HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS

    SciTech Connect (OSTI)

    Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

    2009-05-12

    This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

  16. Sulfur Emissions from Volcanic A c t i v i t y i n 1985 and 1990 Carmen M. Benkovitz and M. A l t a f Mubaraki

    E-Print Network [OSTI]

    APPENDIX C Sulfur Emissions from Volcanic A c t i v i t y i n 1985 and 1990 Carmen M. Benkovitz). Global estimates o f anthropogenic emissions o f sulfur f o r 1985 are approximately 65 Tg S y-l (Benkovi Anthropogenic Sulfur Emissions f o r 1985 and 1990 i n t h i s report). Sulfur from biogenic sources i s emitted

  17. Development of a real-time PCR method for the detection of fossil 16S rDNA fragments of phototrophic sulfur bacteria

    E-Print Network [OSTI]

    Gilli, Adrian

    of phototrophic sulfur bacteria in the sediments of Lake Cadagno D. F. RAVASI,1 S. PEDUZZI,1 , 2 V. GUIDI,2 , 3 R sulfur bacteria in the chemocline has been monitored since 1994 with molecular methods such as 16S r sulfur bacteria populations from sediment samples. We detected fossil 16S rDNA of nine populations

  18. New Model to Predict Formation Damage due to Sulfur Deposition in Sour M.A. Mahmoud and A.A. Al-Majed, KFUPM, all SPE

    E-Print Network [OSTI]

    Al-Majed, Abdulaziz Abdullah

    SPE 149535 New Model to Predict Formation Damage due to Sulfur Deposition in Sour Gas Wells M of SPE copyright. Abstract Elemental sulfur (S8) is often present in considerable amounts in sour gas to deposit in the formation. Sulfur deposition can cause severe loss in the pore space available for gas

  19. CONTENTS 2 1 Motivation 4

    E-Print Network [OSTI]

    Gross, Rudolf

    1 #12;CONTENTS 2 Contents 1 Motivation 4 2 Circuit QED and Two-Resonator Circuit-QED 6 2.1 Coupled Fabrication Parameters 94 D E-beam Sample Holder 96 E Danksagungen 103 #12;1 MOTIVATION 4 1 Motivation

  20. Attrition resistant, zinc titanate-containing, reduced sulfur sorbents and methods of use thereof

    DOE Patents [OSTI]

    Vierheilig, Albert A.; Gupta, Raghubir P.; Turk, Brian S.

    2006-06-27

    Reduced sulfur gas species (e.g., H.sub.2S, COS and CS.sub.2) are removed from a gas stream by compositions wherein a zinc titanate ingredient is associated with a metal oxide-aluminate phase material in the same particle species. Nonlimiting examples of metal oxides comprising the compositions include magnesium oxide, zinc oxide, calcium oxide, nickel oxide, etc.

  1. Study on removal of organic sulfur compound by modified activated carbon

    SciTech Connect (OSTI)

    Fan Huiling; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology (China). Research Inst. for Chemical Engineering of Coal

    1997-12-31

    With the price of coal increasing in China, more and more small and medium scale chemical plants are turning to high sulfur coal as the raw material in order to cut cost. However, the major drawback is that the lifetime of the ammonia synthesis catalyst is then reduced greatly because of the high concentration of the sulfur compounds in the synthesis gas, especially organic sulfur, usually CS{sub 2} and COS. The effects of water vapor and experimental temperature on removal of organic sulfur compounds by using a modified activated carbon were studied in this paper. It was found that water vapor had a negative effect on removal of carbon disulfide by activated carbon impregnated with organic amine. The use of activated carbon impregnated with K{sub 2}CO{sub 3} for removal of carbonyl sulfide was also investigated over the temperature range 30--60, the results show a favorable temperature (40) existing for carbonyl sulfide removal. Fixed-bed breakthrough curves for the adsorbent bed were also offered in this paper.

  2. Neon and Sulfur Abundances of Planetary Nebulae in the Magellanic Clouds

    E-Print Network [OSTI]

    J. Bernard-Salas; S. R. Pottasch; S. Gutenkunst; P. W. Morris; J. R. Houck

    2007-09-20

    The chemical abundances of neon and sulfur for 25 planetary nebulae (PNe) in the Magellanic Clouds are presented. These abundances have been derived using mainly infrared data from the Spitzer Space Telescope. The implications for the chemical evolution of these elements are discussed. A comparison with similarly obtained abundances of Galactic PNe and HII regions and Magellanic Clouds HII regions is also given. The average neon abundances are 6.0x10(-5) and 2.7x10(-5) for the PNe in the Large and Small Magellanic Clouds respectively. These are ~1/3 and 1/6 of the average abundances of Galactic planetary nebulae to which we compare. The average sulfur abundances for the LMC and SMC are respectively 2.7x10(-6) and 1.0x10(-6). The Ne/S ratio (23.5) is on average higher than the ratio found in Galactic PNe (16) but the range of values in both data sets is similar for most of the objects. The neon abundances found in PNe and HII regions agree with each other. It is possible that a few (3-4) of the PNe in the sample have experienced some neon enrichment, but for two of these objects the high Ne/S ratio can be explained by their very low sulfur abundances. The neon and sulfur abundances derived in this paper are also compared to previously published abundances using optical data and photo-ionization models.

  3. Understanding Sulfur Poisoning and Regeneration of Nickel Biomass Conditioning Catalysts using X-Ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Yung, M. M.; Cheah, S.; Kuhn, J. N.

    2013-01-01

    The production of biofuels can proceed via a biomass gasification to produce syngas, which can then undergo catalytic conditioning and reforming reactions prior to being sent to a fuel synthesis reactor. Catalysts used for biomass conditioning are plagued by short lifetimes which are a result of, among other things, poisoning. Syngas produced from biomass gasification may contain between 30-300 ppm H2S, depending on the feedstock and gasification conditions, and H2S is a key catalyst poison. In order to overcome catalyst poisoning, either an H2S-tolerant catalyst or an efficient regeneration protocol should be employed. In this study, sulfur K-edge X-ray absorption near edge spectroscopy (XANES) was used to monitor sulfur species on spent catalyst samples and the transformation of these species from sulfides to sulfates during steam and air regeneration on a Ni/Mg/K/Al2O3 catalyst used to condition biomass-derived syngas. Additionally, nickel K-edge EXAFS and XANES are used to examine the state of nickel species on the catalysts. Post-reaction samples showed the presence of sulfides on the H2S-poisoned nickel catalyst and although some gaseous sulfur species were observed to leave the catalyst bed during regeneration, sulfur remained on the catalyst and a transformation from sulfides to sulfates was observed. The subsequent H2 reduction led to a partial reduction of sulfates back to sulfides. A proposed reaction sequence is presented and recommended regeneration strategies are discussed.

  4. Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel is a critical path for the use of jet fuels in powering the commercial growth of fuel cell systems for air the fuel through adsorptive methods is not practical for long term operations. The current work describes

  5. Impact of anthropogenic atmospheric nitrogen and sulfur deposition on ocean acidification

    E-Print Network [OSTI]

    Mahowald, Natalie

    3 and H2SO4) and bases (NH3) alter surface seawater alkalinity, pH, and inorganic carbon storage. We and alkaline in the tropics because of am- monia inputs. However, because most of the excess ammonia Tmol/yr), ammonia (NH3, 4 Tmol/yr), and sulfur dioxide (SO2, 2 Tmol/yr) to the atmosphere (1). Globally

  6. Evidence of Quinone Metabolites of Naphthalene Covalently Bound to Sulfur Nucleophiles of Proteins of

    E-Print Network [OSTI]

    Hammock, Bruce D.

    Evidence of Quinone Metabolites of Naphthalene Covalently Bound to Sulfur Nucleophiles of Proteins in the mouse is associated with the covalent binding of electrophilic metabolites to cellular proteins. Epoxide binding to proteins. To identify the nature of reactive metabolites bound to proteins (cysteine residues

  7. Multilayer sulfur-resistant composite metal membranes and methods of making and repairing the same

    DOE Patents [OSTI]

    Way, J. Douglas; Hatlevik, Oyvind

    2014-07-15

    The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.

  8. Sonic enhanced ash agglomeration and sulfur capture. Quarterly report, January 1996--March 1996

    SciTech Connect (OSTI)

    NONE

    1996-04-01

    A major concern with the utilization of coal in directly fired gas turbines is the control of particulate emissions and reduction of sulfur dioxide, and alkali vapor from combustion of coal, upstream of the gas turbine. Much research and development has been sponsored on methods for particulate emissions control and the direct injection of calcium-based sorbents to reduce SO{sub 2} emission levels. The results of this research and development indicate that both acoustic agglomeration of particulates and direct injection of sorbents have the potential to become a significant emissions control strategy. The Sonic Enhanced Ash Agglomeration and Sulfur Capture program focuses upon the application of an MTCI proprietary invention (Patent No. 5,197,399) for simultaneously enhancing sulfur capture and particulate agglomeration of the combustor effluent. This application can be adapted as either a {open_quotes}hot flue gas cleanup{close_quotes} subsystem for the current concepts for combustor islands or as an alternative primary pulse combustor island in which stagging, sulfur capture, particulate agglomeration and control, and alkali gettering as well as NO{sub x} control processes become an integral part of the pulse combustion process.

  9. Sonic Enhanced Ash Agglomeration and Sulfur Capture. Technical progress report, October 1992--December 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    A major concern with the utilization of coal in directly fired gas turbines is the control of particulate emissions and reduction of sulfur dioxide, and alkali vapor from combustion of coal, upstream of the gas turbine. Much research and development has been sponsored on methods for particulate emissions control and the direct injection of calcium-based sorbents to reduce SO{sub 2} emission levels. The results of this research and development indicate that both acoustic agglomeration of particulates and direct injection of sorbents have the potential to become a significant emissions control strategy. The Sonic Enhanced Ash Agglomeration and Sulfur Capture program focuses upon the application of an MTCI proprietary invention (Invention Disclosure filed) for simultaneously enhancing sulfur capture and particulate agglomeration of the combustor effluent. This application can be adapted as either a ``hot flue gas cleanup`` subsystem for the current concepts for combustor islands or as an alternative primary pulse combustor island in which slagging, sulfur capture, particulate agglomeration and control, and alkali gettering as well as NO{sub x} control processes become an integral part of the pulse combustion process.

  10. Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light

    E-Print Network [OSTI]

    Denver, University of

    Remote Sensing of Ammonia and Sulfur Dioxide from On-Road Light Duty Vehicles D A N I E L A . B U R by dynamometer (16), remote sensing (17), and recently by a chase vehicle (18). Results from these studies vary

  11. Mechanistic Modeling of Sulfur-Deprived Photosynthesis and Hydrogen Production in

    E-Print Network [OSTI]

    Mechanistic Modeling of Sulfur-Deprived Photosynthesis and Hydrogen Production in Suspensions linked to the photosynthetic chain in such a way that hydrogen and oxygen production need to be separated- modate the production of hydrogen gas by partially- deactivating O2 evolution activity, leading

  12. Evidence of recovery of Juniperus virginiana trees from sulfur pollution after the Clean Air Act

    E-Print Network [OSTI]

    Nippert, Jesse

    Evidence of recovery of Juniperus virginiana trees from sulfur pollution after the Clean Air Act decades of acidic pollution. Acid deposition over much of the 20th century reduced stomatal conductance and temporal gradients in natural systems. For over a century, the combustion of fossil fuels resulted

  13. 1794 J. Phys. Chem. 1988, 92, 1794-1803 Photoelectron Spectroscopy of Sulfur Ions

    E-Print Network [OSTI]

    Ellison, Barney

    in combustion p r o c e s ~ e s . ~ ~ ~Early workes focused on the pho- toelectron spectra of 02-,OH-, HOC, CH30 in air pollution and acid rain. Less well studied are the divalent, reduced forms of sulfur important in combustion. Another, CH3SCH2-,is an example of a carbanion with an electron

  14. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the bubble reactor is maintained at 2 for all the reaction experiment runs.

  15. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2004-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia.

  16. Analytic Torsion of Z_2-graded Elliptic Complexes

    E-Print Network [OSTI]

    Varghese Mathai; Siye Wu

    2010-04-10

    We define analytic torsion of Z_2-graded elliptic complexes as an element in the graded determinant line of the cohomology of the complex, generalizing most of the variants of Ray-Singer analytic torsion in the literature. It applies to a myriad of new examples, including flat superconnection complexes, twisted analytic and twisted holomorphic torsions, etc. The definition uses pseudo-differential operators and residue traces. We also study properties of analytic torsion for Z_2-graded elliptic complexes, including the behavior under variation of the metric. For compact odd dimensional manifolds, the analytic torsion is independent of the metric, whereas for even dimensional manifolds, a relative version of the analytic torsion is independent of the metric. Finally, the relation to topological field theories is studied.

  17. Analytic Torsion of Z_2-graded Elliptic Complexes

    E-Print Network [OSTI]

    Mathai, Varghese

    2010-01-01

    We define analytic torsion of Z_2-graded elliptic complexes as an element in the graded determinant line of the cohomology of the complex, generalizing most of the variants of Ray-Singer analytic torsion in the literature. It applies to a myriad of new examples, including flat superconnection complexes, twisted analytic and twisted holomorphic torsions, etc. The definition uses pseudo-differential operators and residue traces. We also study properties of analytic torsion for Z_2-graded elliptic complexes, including the behavior under variation of the metric. For compact odd dimensional manifolds, the analytic torsion is independent of the metric, whereas for even dimensional manifolds, a relative version of the analytic torsion is independent of the metric. Finally, the relation to topological field theories is studied.

  18. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  19. Partial substitution of Mo{sup 6+} by S{sup 6+} in the fast oxide ion conductor La{sub 2}Mo{sub 2}O{sub 9}: Synthesis, structure and sulfur depletion

    SciTech Connect (OSTI)

    Mhadhbi, Noureddine; Corbel, Gwenaeel; Lacorre, Philippe; Bulou, Alain

    2012-06-15

    Powder-solid state reaction route using La{sub 2}(SO{sub 4}){sub 3} as sulfur source was used to prepare compositions of the solid solution La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9}. Single phases were only obtained in the substitution range extending up to y=0.8 (40 mol% S) at the annealing temperature of 850 Degree-Sign C with regard to the limit of stability of the lanthanum sulphate reactant. Within the synthesis conditions, a stabilization of the high temperature {beta}-form is observed from and above y=0.1 (5 mol% S). Temperature-controlled X-ray diffraction and thermogravimetric analyses have shown that La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders undergo thermal decompositions in two steps. Heating above 900 Degree-Sign C, a sulfur depletion to the benefit of molybdenum in La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders leads to the formation of La{sub 2}SO{sub 6}. At higher temperature, the exsolved La{sub 2}SO{sub 6} phase then decomposes into La{sub 2}O{sub 3}, which in turn reacts with the sulfur-depleted La{sub 2}Mo{sub 2}O{sub 9} phase to form La{sub 2}MoO{sub 6}. The present study also reveals that depending on the substitution rate y, the sulfur depletion can be induced by ball-milling of raw powders. Along the La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} series, the isovalent substitution of molybdenum by sulfur tends to restrict in magnitude, or even to suppress above 400 Degree-Sign C, the distortive thermal expansion of the cubic {beta}-type structure, thus strongly decreasing the conductance at high temperature. - Graphical abstract: La{sub 2}O{sub 3}-MoO{sub 3}-'SO{sub 3}' ternary phase diagram showing the exsolution path at low temperature (white arrows) and the total decomposition path at high temperature (black arrows) of {beta}-La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders. Highlights: Black-Right-Pointing-Pointer Isovalent substitution of molybdenum by sulfur in La{sub 2}Mo{sub 2}O{sub 9} up to 40 mol%. Black-Right-Pointing-Pointer Stabilization of the {beta}-form for a sulfur content greater than or equal to 5 mol%. Black-Right-Pointing-Pointer Decomposition by sulfur exsolution induced by thermal treatment or ball-milling. Black-Right-Pointing-Pointer Reduction or even cancellation of the distortive thermal expansion above 400 Degree-Sign C. Black-Right-Pointing-Pointer Decrease of conductance at high T involved by the low thermal expansion above 400 Degree-Sign C.

  20. 2013 strategic petroleum reserve big hill well integrity grading report.

    SciTech Connect (OSTI)

    Lord, David L.; Roberts, Barry L.; Lord, Anna C. Snider; Bettin, Giorgia; Sobolik, Steven Ronald; Park, Byoung Yoon; Rudeen, David Keith; Eldredge, Lisa; Wynn, Karen; Checkai, Dean; Perry, James Thomas

    2014-02-01

    This report summarizes the work performed in developing a framework for the prioritization of cavern access wells for remediation and monitoring at the Big Hill Strategic Petroleum Reserve site. This framework was then applied to all 28 wells at the Big Hill site with each well receiving a grade for remediation and monitoring. Numerous factors affecting well integrity were incorporated into the grading framework including casing survey results, cavern pressure history, results from geomechanical simulations, and site geologic factors. The framework was developed in a way as to be applicable to all four of the Strategic Petroleum Reserve sites.

  1. Strategies for denaturing the weapons-grade plutonium stockpile

    SciTech Connect (OSTI)

    Buckner, M.R.; Parks, P.B.

    1992-10-01

    In the next few years, approximately 50 metric tons of weapons-grade plutonium and 150 metric tons of highly-enriched uranium (HEU) may be removed from nuclear weapons in the US and declared excess. These materials represent a significant energy resource that could substantially contribute to our national energy requirements. HEU can be used as fuel in naval reactors, or diluted with depleted uranium for use as fuel in commercial reactors. This paper proposes to use the weapons-grade plutonium as fuel in light water reactors. The first such reactor would demonstrate the dual objectives of producing electrical power and denaturing the plutonium to prevent use in nuclear weapons.

  2. Low-quality natural gas sulfur removal/recovery

    SciTech Connect (OSTI)

    K. Amo; R.W. Baker; V.D. Helm; T. Hofmann; K.A. Lokhandwala; I. Pinnau; M.B. Ringer; T.T. Su; L. Toy; J.G. Wijmans

    1998-01-29

    A significant fraction of U.S. natural gas reserves are subquality due to the presence of acid gases and nitrogen; 13% of existing reserves (19 trillion cubic feed) may be contaminated with hydrogen sulfide. For natural gas to be useful as fuel and feedstock, this hydrogen sulfide has to be removed to the pipeline specification of 4 ppm. The technology used to achieve these specifications has been amine, or similar chemical or physical solvent, absorption. Although mature and widely used in the gas industry, absorption processes are capital and energy-intensive and require constant supervision for proper operation. This makes these processes unsuitable for treating gas at low throughput, in remote locations, or with a high concentration of acid gases. The U.S. Department of Energy, recognizes that exploitation of smaller, more sub-quality resources will be necessary to meet demand as the large gas fields in the U.S. are depleted. In response to this need, Membrane Technology and Research, Inc. (MTR) has developed membranes and a membrane process for removing hydrogen sulfide from natural gas. During this project, high-performance polymeric thin-film composite membranes were brought from the research stage to field testing. The membranes have hydrogen sulfide/methane selectivities in the range 35 to 60, depending on the feed conditions, and have been scaled up to commercial-scale production. A large number of spiral-wound modules were manufactured, tested and optimized during this project, which culminated in a field test at a Shell facility in East Texas. The short field test showed that membrane module performance on an actual natural gas stream was close to that observed in the laboratory tests with cleaner streams. An extensive technical and economic analysis was performed to determine the best applications for the membrane process. Two areas were identified: the low-flow-rate, high-hydrogen-sulfide-content region and the high-flow-rate, high-hydrogen-sulfide-content region. In both regions the MTR membrane process will be combined with another process to provide the necessary hydrogen sulfide removal from the natural gas. In the first region the membrane process will be combined with the SulfaTreat fixed-bed absorption process, and in the second region the membrane process will be combined with a conventional absorption process. Economic analyses indicate that these hybrid processes provide 20-40% cost savings over stand-alone absorption technologies.

  3. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; et al

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) withmore »highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.« less

  4. Visual Analysis of Weblog Content

    SciTech Connect (OSTI)

    Gregory, Michelle L.; Payne, Deborah A.; McColgin, Dave; Cramer, Nick O.; Love, Douglas V.

    2007-03-26

    In recent years, one of the advances of the World Wide Web is social media and one of the fastest growing aspects of social media is the blogosphere. Blogs make content creation easy and are highly accessible through web pages and syndication. With their growing influence, a need has arisen to be able to monitor the opinions and insight revealed within their content. In this paper we describe a technical approach for analyzing the content of blog data using a visual analytic tool, IN-SPIRE, developed by Pacific Northwest National Laboratory. We highlight the capabilities of this tool that are particularly useful for information gathering from blog data.

  5. A model for determining shelf life, estimating terminal body composition, yield grade and quality grade of feedlot cattle 

    E-Print Network [OSTI]

    Perry, Richard Jay

    1985-01-01

    4. 5 percentage units less fat (21. 64% vs 26, 1% carcass fat) than non-implanted steers of the same carcass weight and rate of gain (350 kg and ADG of 1. 0 kg/d). Fat as a percentage of gain averaged 67. 85, 52. 05 and 39. 59 for non... model which can be used for projecting changes in yield grade and quality grade with performance of cattle in the feedlot over time. The primary objectives of this research were: 1) To determine the "shelf life" of a steer in the feedlot. 2...

  6. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, Mitchell R. (Troy, NY); Gal, Eli (Lititz, PA)

    1993-01-01

    A process and system for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous The government of the United States of America has rights in this invention pursuant to Contract No. DE-AC21-88MC 23174 awarded by the U.S. Department of Energy.

  7. Regenerative process and system for the simultaneous removal of particulates and the oxides of sulfur and nitrogen from a gas stream

    DOE Patents [OSTI]

    Cohen, M.R.; Gal, E.

    1993-04-13

    A process and system are described for simultaneously removing from a gaseous mixture, sulfur oxides by means of a solid sulfur oxide acceptor on a porous carrier, nitrogen oxides by means of ammonia gas and particulate matter by means of filtration and for the regeneration of loaded solid sulfur oxide acceptor. Finely-divided solid sulfur oxide acceptor is entrained in a gaseous mixture to deplete sulfur oxides from the gaseous mixture, the finely-divided solid sulfur oxide acceptor being dispersed on a porous carrier material having a particle size up to about 200 microns. In the process, the gaseous mixture is optionally pre-filtered to remove particulate matter and thereafter finely-divided solid sulfur oxide acceptor is injected into the gaseous mixture.

  8. Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration

    SciTech Connect (OSTI)

    Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

    2008-09-30

    The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

  9. manipulating cytosolic PPi content can

    E-Print Network [OSTI]

    Kronzucker, Herbert J.

    content and starch degradation during storage of tubers harvested from different potato varieties. Potato. et al. (1994) Possible involvement of abscisic acid, ethylene and phenolic acids in potato tuber

  10. Find Teacher & Classroom Resources Health & Physical Education, K Grade 6

    E-Print Network [OSTI]

    Fletcher, Robin

    Find Teacher & Classroom Resources for Health & Physical Education, K ­ Grade 6 Queen's Library weeks Books, Lesson Resources, K-12 books, Multimedia, Ministry of Education documents For use Type of Resource Search Tip Ministry of Education documents Browsing Tip: All M of E documents

  11. OIMB GK12 CURRICULUM Grade Year-long activity

    E-Print Network [OSTI]

    OIMB GK12 CURRICULUM 6th Grade Year-long activity TEACHING "BIG PICTURE" SCIENCE: AN ISLAND selection ! evolution ! dispersal ! recruitment #12;OIMB GK12 CURRICULUM ! colonization Materials: ! Brown CURRICULUM context of a small, recently formed volcanic island. It reinforces the interconnectedness

  12. Effective Thermal Conductivity of Graded Nanocomposites with Interfacial Thermal

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    .M. Yin", G. H. Paulino", W.G. Buttlar", and L.Z. Sun'' '^Department of Civil and Environmental the effective thermal conductivity distribution in functionally graded materials (FGMs) considering the Kapitza is developed to derive the averaged heat flux field of the particle phase. Then the temperature gradient can

  13. Optimization For Grade Transitions In Polyethylene Solution Polymerization

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    , Comonomer, Catalyst, Solvent, Hydrogen 2 1. Che I Kao et al. Non-adiabatic olefin solution polymerizationOptimization For Grade Transitions In Polyethylene Solution Polymerization Jun Shi1, Lorenz T of Advanced Process Decision-making Department of Chemical Engineering Carnegie Mellon University 2The Dow

  14. Optimization For Grade Transitions In Polyethylene Solution Polymerization

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimization For Grade Transitions In Polyethylene Solution Polymerization Jun Shi1, Intan Hamdan2, Sarat Munjal2, Lorenz T. Biegler1 1Center of Advanced Process Decision-making Department of Chemical perfect mixing · Three types of variables · Manipulated variables · Ethylene, comonomer, hydrogen

  15. Mathematics and Optics at Elvira Elementary: 4th grade Acknowledgments

    E-Print Network [OSTI]

    Lega, Joceline

    Mathematics and Optics at Elvira Elementary: 4th grade Acknowledgments - National Science Foundation Grant number 0841234 - Optics outreach laboratory at the University of Arizona College of Optical and multiply. Figure 1. Examples of students work. References http://www.insidemathematics.org/ Optics

  16. ART HISTORY MINOR (NON-TEACHING) Course Credits Grade

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    ART HISTORY MINOR (NON-TEACHING) Course Credits Grade ARTH 200IA ­ World Civilizations I 4 of the following, at least one from each group: Group I ARTH 302 - Survey of Ancient Art 3 _____ ARTH 375 - Roman, Etruscan, Greek 3 _____ ARTH 400 - Art and Architecture of Egypt 3 _____ ARTH 402 - Greek Art

  17. Disposition of weapons-grade plutonium in Westinghouse reactors 

    E-Print Network [OSTI]

    Alsaed, Abdelhalim Ali

    1996-01-01

    We have studied the feasibility of using weapons-grade plutonium in the form of mixed-oxide (MOX) fuel in existing Westinghouse reactors. We have designed three transition cycles from an all LEU core to a partial MOX core. We found that four...

  18. Texas Tech Researchers Discover Low-Grade Nonwoven Cotton

    E-Print Network [OSTI]

    Rock, Chris

    Nonwoven cotton could become the new picker-upper for oil spills. Texas Tech University researchers and his researchers are working with Texas Tech's Office of Technology Commercialization to take this newTexas Tech Researchers Discover Low-Grade Nonwoven Cotton Picks Up 50 Times Own Weight of Oil

  19. The Solar System Presentation for SRS 5th Grade

    E-Print Network [OSTI]

    Cohen, David

    The Solar System Presentation for SRS 5th Grade Prof. David Cohen, Swarthmore College #12;What astronomers try to answer: ·What are the things in the solar system like? Planets, moons, comets, asteroids, the Sun... ·Are there good conditions for life anywhere in the solar system? ·How did the solar system

  20. TA Seminar 2006 Name . Grading Two Example Student Laboratory Reports

    E-Print Network [OSTI]

    Minnesota, University of

    TA Seminar 2006 Name . Page 1 Grading Two Example Student Laboratory Reports Introductory physics laboratory reports, students are provided the opportunity to learn about physics through written assignments the 2 example student laboratory reports. Mark down any and all comments on the example student

  1. Be a Food Detective Grades 9-12: T-1

    E-Print Network [OSTI]

    Miller, Scott

    Be a Food Detective Grades 9-12: T-1 Be a Food Detective Overview Students will explore the exciting area of food and nutrition and answer specific questions about prepared food products, such as, what a food is made from, the source of its ingredients, and how the ingredients were grown. Suggested

  2. Ready to eat breakfast cereals from food-grade sorghums 

    E-Print Network [OSTI]

    Cruz y Celis Ehlinger, Laura Penelope

    1993-01-01

    Two food-grade sorghum hybrids, ATx63 I *Tx436 (non waxy), and B.BON 34, (waxy), were micronized and evaluated for their potential use in ready to eat breakfast cereals (RTE-BC). Whole and decorticated grains were exposed to infra-red burners...

  3. A FUNCTIONALLY GRADED PARTICULATE COMPOSITE: PREPARATION, MEASUREMENTS AND FAILURE

    E-Print Network [OSTI]

    Rousseau, Carl-Ernst

    planes. Such materials have been developed using dierent processes including slip casting [1], centrifugal casting [2], laser alloying and cladding [3], and plasma-spray forming [4]. The FGMs pose new and examined crack growth resistance behavior using the rule of mixtures. Functionally graded metal/cer- a

  4. Short communication Compositional control of continuously graded anode functional layer

    E-Print Network [OSTI]

    Mukhopadhyay, Sharmila M.

    Glenn Hwy., Dayton, OH 45435, USA h i g h l i g h t s SOFC compositionally graded AFL built using kinetics. SOFC performance. a r t i c Compositional gradation SOFC a b s t r a c t In this work, solid oxide fuel cells (SOFC's) are fabricated

  5. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton

    2007-08-15

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  6. Quick Reference Online Grade Pos ng Sign on to the Campus Informa on Services (cis.utah.edu)

    E-Print Network [OSTI]

    Quick Reference Online Grade Pos ng Sign on to the Campus Informa on Services (cis.utah.edu): 1. Will not affect grades that have been saved. Saves the entered grades in the grade roster without pos ng@sa.utah.edu. #12; Quick Reference Online Grade Pos ng For further assistance, contact the Registra on & Records

  7. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2006-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

  8. SO[subscript 2] photolysis as a source for sulfur mass-independent isotope signatures in stratospehric aerosols

    E-Print Network [OSTI]

    Jiang, B.

    Signatures of sulfur isotope mass-independent fractionation (S-MIF) have been observed in stratospheric sulfate aerosols deposited in polar ice. The S-MIF signatures are thought to be associated with stratospheric ...

  9. Lubricant oil consumption effects on diesel exhaust ash emissions using a sulfur dioxide trace technique and thermogravimetry

    E-Print Network [OSTI]

    Plumley, Michael J

    2005-01-01

    A detailed experimental study was conducted targeting lubricant consumption effects on ,diesel exhaust ash levels using a model year 2002 5.9L diesel engine, high and low Sulfur commercial lubricants, and clean diesel ...

  10. Hartree-Fock-Bogoliubov calculations in coordinate space: Neutron-rich sulfur, zirconium, cerium, and samarium isotopes

    E-Print Network [OSTI]

    Teran, Edgar

    Hartree-Fock-Bogoliubov calculations in coordinate space: Neutron-rich sulfur, zirconium, cerium study the properties of neutron-rich zirconium 102,104 Zr , cerium 152 Ce , and samarium 158,160 Sm

  11. The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen

    E-Print Network [OSTI]

    Miu, Kevin (Kevin K.)

    2006-01-01

    The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - the most prevalent method of hydrogen ...

  12. Solar Grade Silicon from Agricultural By-products

    SciTech Connect (OSTI)

    Richard M. Laine

    2012-08-20

    In this project, Mayaterials developed a low cost, low energy and low temperature method of purifying rice hull ash to high purity (5-6Ns) and converting it by carbothermal reduction to solar grade quality silicon (Sipv) using a self-designed and built electric arc furnace (EAF). Outside evaluation of our process by an independent engineering firm confirms that our technology greatly lowers estimated operating expenses (OPEX) to $5/kg and capital expenses (CAPEX) to $24/kg for Sipv production, which is well below best-in-class plants using a Siemens process approach (OPEX of 14/kg and CAPEX of $87/kg, respectively). The primary limiting factor in the widespread use of photovoltaic (PV) cells is the high cost of manufacturing, compared to more traditional sources to reach 6 g Sipv/watt (with averages closer to 8+g/watt). In 2008, the spot price of Sipv rose to $450/kg. While prices have since dropped to a more reasonable $25/kg; this low price level is not sustainable, meaning the longer-term price will likely return to $35/kg. The 6-8 g Si/watt implies that the Sipv used in a module will cost $0.21-0.28/watt for the best producers (45% of the cost of a traditional solar panel), a major improvement from the cost/wafer driven by the $50/kg Si costs of early 2011, but still a major hindrance in fulfilling DOE goal of lowering the cost of solar energy below $1/watt. The solar cell industry has grown by 40% yearly for the past eight years, increasing the demand for Sipv. As such, future solar silicon price spikes are expected in the next few years. Although industry has invested billions of dollars to meet this ever-increasing demand, the technology to produce Sipv remains largely unchanged requiring the energy intensive, and chlorine dependent Siemens process or variations thereof. While huge improvements have been made, current state-of-the-art industrial plant still use 65 kWh/kg of silicon purified. Our technology offers a key distinction to other technologies as it starts one step upstream from all other Sipv production efforts. Our process starts by producing high purity SiO2/C feedstocks from which Sipv can be produced in a single, chlorine free, final EAF step. Specifically, our unique technology, and the resultant SiO2/C product can serve as high purity feedstocks to existing metallurgical silicon (Simet) producers, allowing them to generate Sipv with existing US manufacturing infrastructure, reducing the overall capital and commissioning schedule. Our low energy, low CAPEX and OPEX process purifies the silica and carbon present in rice hull ash (RHA) at low temperatures (< 200C) to produce high purity (5-6 Ns) feedstock for production of Sipv using furnaces similar to those used to produce Simet. During the course of this project we partnered with Wadham Energy LP (Wadham), who burns 220k ton of rice hulls (RH)/yr generating 200 GWh of electricity/yr and >30k ton/yr RHA. The power generation step produces much more energy (42 kWh/kg of final silicon produced) than required to purify the RHA (5 kWh/kg of Sipv, compared to 65 kWh/kg noted above. Biogenic silica offers three very important foundations for producing high purity silicon. First, wastes from silica accumulating plants, such as rice, corn, many grasses, algae and grains, contain very reactive, amorphous silica from which impurities are easily removed. Second, plants take up only a limited set of, and minimal quantities of the heavy metals present in nature, meaning fewer minerals must be removed. Third, biomass combustion generates a product with intrinsic residual carbon, mixed at nanometer length scales with the SiO2. RHA is 80-90 wt% high surface area (20 m2/g), amorphous SiO2 with some simple mineral content mixed intimately with 5-15 wt% carbon. The mineral content is easily removed by low cost, acid washes using Mayaterials IP, leading to purified rice hull ash (RHAclean) at up to 6N purity. This highly reactive silica is partially extracted from RHAclean at 200 C in an environmentally benign process to adjust SiO2:C ratios to those needed in EA

  13. Update on sulfur compound distribution in NGL: Plant test data GPA Section A committee, plant design

    SciTech Connect (OSTI)

    Harryman, J.M. [Shell Oil Co., Houston, TX (United States); Smith, B. [Texaco E and P Inc., Tulsa, OK (United States)

    1996-12-31

    The mystery of why sulfur compounds could never be balanced from analyses of the product streams of NGL fractionation towers was solved by analyzing the data collected during testing completed by GPA Technical Section A in November and December of 1993 at Texaco`s Eunice, New Mexico fractionation plant. Decomposition of dimethyl disulfide (DMDS) to form methyl mercaptan within the towers is the cause of the sulfur balance discrepancies explained in the paper. The results of testing were reported to the 1994 convention, but at the time, a few weeks after completion of testing, the chemistry was not understood, i.e., what is the source of the hydrogen required to complete the formation of methyl mercaptan. This paper is an update of the previous paper and it includes the DMDS decomposition chemistry. It is essentially the body of a report completed in early 1995, excluding the Appendix of data. The 66-page Appendix may be obtained from the GPA, Tulsa.

  14. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  15. Near-frictionless carbon coatings for use in fuel injectors and pump systems operating with low-sulfur diesel fuels

    SciTech Connect (OSTI)

    Erdemir, A.; Ozturk, O.; Alzoubi, M.; Woodford, J.; Ajayi, L.; Fenske, G.

    2000-01-19

    While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO{sub 2} emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. This research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems. The lubricity of various diesel fuels (i.e., high-sulfur, 500 ppm; low sulfur, 140 ppm; ultra-clean, 3 ppm; and synthetic diesel or Fischer-Tropsch, zero sulfur) were tested by using both uncoated and NFC-coated 52100 steel specimens in a ball-on-three-disks and a high-frequency reciprocating wear-test rig. The test program was expanded to include some gasoline fuels as well (i.e., regular gasoline and indolene) to further substantiate the usefulness of the NFC coatings in low-sulfur gasoline environments. The results showed that the NFC coating was extremely effective in reducing wear and providing lubricity in low-sulfur or sulfur-free diesel and gasoline fuels. Specifically, depending on the wear test rig, test pair, and test media, the NFC films were able to reduce wear rates of balls and flats by factors of 8 to 83. These remarkable reductions in wear rates raise the prospect for using the ultra slick carbon coatings to alleviate problems that will be caused by the use of low sulfur diesel and gasoline fuels. Surfaces of the wear scars and tracks were characterized by optical and scanning electron microscopy, and by Raman spectroscopy.

  16. Middle grades in-service teachers pedagogical content knowledge of student internal representation of equivalent fractions and algebraic expressions 

    E-Print Network [OSTI]

    Woodard, Leslie Dorise

    2009-05-15

    trajectories due to noticed aspects of student representation corresponding to the hypothetical learning trajectory model. Using constant comparatives and repertory grid analysis, data was collected in two phases. Phase one, the teacher pre-test, occurred...

  17. Airborne measurements of total sulfur gases during NASA global tropospheric experiment/chemical instrumentation test and evaluation 3

    SciTech Connect (OSTI)

    Farwell, S.O.; MacTaggart, D.L.; Chatham, W.H.

    1995-04-20

    A metal foil collection/flash desorption/flame photometric detection (MFC/FD/FPD) technique was used by investigators from the University of Idaho (UI) to measure ambient total sulfur gas concentrations from an aircraft platform during the NASA Global Tropospheric Experiment/Chemical Instrumentation Test and Evaluation 3 (GTE/CITE 3) program. The MFC/FD/FPD technique allowed rapid quantitation of tropospheric background air masses using sample integration times of 1-3 min with little or no gap between measurements. The rapid and continual sampling nature of this technique yielded data covering approximately 75% of the entire CITE 3 program`s air track. Ambient air measurement data obtained during northern hemisphere (NH) flights often exhibited relatively high total sulfur gas values (up to 19 ppb) and an extremely high degree of sample heterogeneity, especially in coastal locations. Data from southern hemisphere (SH) flights typically exhibited relatively low total sulfur gas concentrations and a low degree of sample heterogeneity. A bimodal interhemispheric total sulfur gas gradient was observed using data obtained during transit flights between the two CITE 3 program ground bases. Comparisons were made of UI total sulfur gas measurements with composite sulfur gas values generated using speciated sulfur gas measurements from other CITE 3 participants. Only a relatively small number of overlap periods for comparison were obtained from all the available CITE 3 data because of large differences in measurement integration times and lack of synchronization of sample start/stop times for the various investigators. These effects were compounded with extreme sample heterogeneity in the NH and the speed at which the aircraft traversed the air masses being sampled. Comparison of NH UI total with composite sulfur gas values showed excellent correlation and linear curve fit, indicating substantial qualitative agreement. 20 refs., 10 figs., 7 tabs.

  18. NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance

    SciTech Connect (OSTI)

    Rangan, M.; Yung, M. M.; Medlin, J. W.

    2012-06-01

    Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

  19. COS-forming reaction between CO and sulfur: A high-temperature intrinsic kinetics study

    SciTech Connect (OSTI)

    Karan, K.; Mehrotra, A.K.; Behie, L.A. [Univ. of Calgary, Alberta (Canada). Dept. of Chemical and Petroleum Engineering] [Univ. of Calgary, Alberta (Canada). Dept. of Chemical and Petroleum Engineering

    1998-12-01

    Carbonyl sulfide is formed in the front end (i.e., the reaction furnace and the waste heat boiler) of Claus plants which are commonly used to recover sulfur from acid gases. Moreover, COS along with CS{sub 2}, are recognized as the problematic sulfur compounds that contribute significantly to plant sulfur emissions. Further, there is limited kinetic information on the important reaction for the formation of these two compounds. Now, it is well-known that one of the important COS-forming reactions is that between CO and sulfur. In this laboratory, the authors conducted an experimental study to measure the intrinsic kinetics of this homogeneous gas-phase reaction in the temperature range of 600--1150 C and over a residence time of 0.5--2.0 s. The overall reaction was found to be second order with a reaction rate constant k{sub f} = (3.18 {+-} 0.36) {times} 10{sup 5} exp[{minus}(6700 {+-} 108 K)/T] m{sup 3}/(kmol{center_dot}s). In addition, a kinetic model was developed to account for both the COS formation and the COS decomposition reactions. And, finally, for the reverse reaction, the COS decomposition reaction rate constant (k{sub r}) was regressed to match the equilibrium data of experiments at high temperatures giving a second-order reaction rate constant as k{sub r} = (2.18 {+-} 1.12) {times} 10{sup 9} exp[{minus}(21630 {+-} 160 K)/T] m{sup 3}/(kmol{center_dot}s).

  20. Photodissociation spectroscopy of the carbonyl sulfide ion with momentum analysis of the sulfur product ion

    SciTech Connect (OSTI)

    Snow, K.B.

    1993-01-01

    A Nuclide 12-90-G mass spectrometer was modified for use as a photofragment momentum spectrometer. The resultant apparatus was capable of obtaining both absolute cross sections for photodissociation with respect to wavelength and relative cross sections for photodissociation with respect to kinetic energy release. The kinetic energy release for the photodissociation reaction of the nitrous oxide cation (leading to the production of the nitric oxide cation and the nitrogen atom), was studied at 3080.4 [angstrom], 3371.3 [angstrom], and 3381.4 [angstrom]. When a nitrogen atom was produced in the [sup 4]S state, the nitric oxide cation was found to be formed predominantly with 5 to 7 quanta of vibrational energy. Nitrogen atoms were formed preferentially in the [sup 2]D state when it was energetically feasible at 3371.3 [angstrom] and 3080.4 [angstrom]. The kinetic energy release for the photodissociation reaction of the carbonyl sulfide cation (leading to the production of carbon monoxide and a sulfur cation), was studied at 2822.2 [angstrom], 2921.8 [angstrom], 2991.0 [angstrom], 2991.9 [angstrom], 3080.4 [angstrom], 3104.3 [angstrom], 3127.9 [angstrom], 3184.9 [angstrom], 3351.8 [angstrom], 3371.3 [angstrom], and 3393.0 [angstrom]. When sulfur cations were produced in the [sup 4]S state, the carbon monoxide products were formed predominantly with 5 to 7 quanta of vibrational energy. Sulfur cations were formed preferentially in the [sup 2]D state from hot bands at 3351.8 [angstrom], 3080.4 [angstrom], and 2991.9 [angstrom]. Sulfur cations were also produced in the [sup 2]D state at 2921.8 [angstrom] and 2822.2 [angstrom], where it was energetically feasible from the ground state of carbonyl sulfide cations.

  1. EVALUATION OF PROTON-CONDUCTING MEMBRANES FOR USE IN A SULFUR-DIOXIDE DEPOLARIZED ELECTROLYZER

    SciTech Connect (OSTI)

    Hobbs, D.; Elvington, M.; Colon-Mercado, H.

    2009-11-11

    The chemical stability, sulfur dioxide transport, ionic conductivity, and electrolyzer performance have been measured for several commercially available and experimental proton exchange membranes (PEMs) for use in a sulfur dioxide depolarized electrolyzer (SDE). The SDE's function is to produce hydrogen by using the Hybrid Sulfur (HyS) Process, a sulfur based electrochemical/thermochemical hybrid cycle. Membrane stability was evaluated using a screening process where each candidate PEM was heated at 80 C in 60 wt. % H{sub 2}SO{sub 4} for 24 hours. Following acid exposure, chemical stability for each membrane was evaluated by FTIR using the ATR sampling technique. Membrane SO{sub 2} transport was evaluated using a two-chamber permeation cell. SO{sub 2} was introduced into one chamber whereupon SO{sub 2} transported across the membrane into the other chamber and oxidized to H{sub 2}SO{sub 4} at an anode positioned immediately adjacent to the membrane. The resulting current was used to determine the SO{sub 2} flux and SO{sub 2} transport. Additionally, membrane electrode assemblies (MEAs) were prepared from candidate membranes to evaluate ionic conductivity and selectivity (ionic conductivity vs. SO{sub 2} transport) which can serve as a tool for selecting membranes. MEAs were also performance tested in a HyS electrolyzer measuring current density versus a constant cell voltage (1V, 80 C in SO{sub 2} saturated 30 wt% H2SO{sub 4}). Finally, candidate membranes were evaluated considering all measured parameters including SO{sub 2} flux, SO{sub 2} transport, ionic conductivity, HyS electrolyzer performance, and membrane stability. Candidate membranes included both PFSA and non-PFSA polymers and polymer blends of which the non-PFSA polymers, BPVE-6F and PBI, showed the best selectivity.

  2. Hybrid sulfur cycle operation for high-temperature gas-cooled reactors

    DOE Patents [OSTI]

    Gorensek, Maximilian B

    2015-02-17

    A hybrid sulfur (HyS) cycle process for the production of hydrogen is provided. The process uses a proton exchange membrane (PEM) SO.sub.2-depolarized electrolyzer (SDE) for the low-temperature, electrochemical reaction step and a bayonet reactor for the high-temperature decomposition step The process can be operated at lower temperature and pressure ranges while still providing an overall energy efficient cycle process.

  3. Sonic enhanced ash agglomeration and sulfur capture. Technical progress report, January 1992--March 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    This program will demonstrate the effectiveness of a unique approach which uses a bimodal distribution composed of large sorbent particles and fine fly ash particles to enhance ash agglomeration and sulfur capture at conditions found in direct coal-fired turbines. Under the impact of high-intensity sound waves, sorbent reactivity and utilization, it is theorized, will increase while agglomerates of fly ash and sorbents are formed which are readily collected in commercial cyclones.

  4. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  5. Home economics 12-16 - the articulation of S1 and S2 with standard grade 

    E-Print Network [OSTI]

    Bryson, Wilma D.

    1991-01-01

    The purpose of this project is to discover whether articulation occurs between S1 and S2 Standard Grade. By "Articulation", one means considering whether the common course structure has fluently and coherently joined into Standard Grade. The issues...

  6. Grade 1 spondylolisthesis and interspinous device placement: removal in six patients and analysis of current data

    E-Print Network [OSTI]

    Bohm, Parker E.; Anderson, Karen K.; Friis, Elizabeth A.; Arnold, Paul M.

    2015-04-02

    In the treatment of patients with Grade 1 spondylolisthesis, the use of interspinous devices has been controversial for nearly a decade. Several authors have suggested that Grade 1 spondylolisthesis be considered a ...

  7. Stochastic multiscale fracture analysis of three-dimensional functionally graded composites

    E-Print Network [OSTI]

    Rahman, Sharif

    Stochastic multiscale fracture analysis of three-dimensional functionally graded composites Sharif: Probabilistic fracture mechanics Polynomial dimensional decomposition Random microstructure Reliability a b for stochastic multiscale fracture analysis of three-dimensional, particle-matrix, functionally graded materials

  8. Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

    SciTech Connect (OSTI)

    Wang, Bin; Alhassan, Saeed M.; Pantelides, Sokrates T

    2014-01-01

    Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

  9. Activated carbon cleanup of the acid gas feed to Claus sulfur plants

    SciTech Connect (OSTI)

    Harruff, L.G.; Bushkuhl, S.J. [Saudi Aramco, Dhahran (Saudi Arabia)

    1996-12-31

    This paper presents the details of a recently developed novel process using activated carbon to remove hydrocarbon contaminants from the acid gas feed to Claus sulfur recovery units. Heavy hydrocarbons, particularly benzene, toluene and xylene (BTX) have been linked to coke formation and catalyst deactivation in Claus converters. This deactivation results in reduced sulfur recovery and increased sulfur emissions from these plants. This effect is especially evident in split flow Claus plants which bypass some of the acid gas feed stream around the initial combustion step because of a low hydrogen sulfide concentration. This new clean-up process was proven to be capable of removing 95% of the BTX and other C{sub 6}{sup +} hydrocarbons from acid gas over a wide range of actual plant conditions. Following the adsorption step, the activated carbon was easily regenerated using low pressure steam. A post regeneration drying step using plant fuel gas also proved beneficial. This technology was extensively pilot tested in Saudi Aramco`s facilities in Saudi Arabia. Full scale commercial units are planned for two plants in the near future with the first coming on-line in 1997. The process described here represents the first application of activated carbon in this service, and a patent has been applied for. The paper will discuss the pilot plant results and the issues involved in scale-up to commercial size.

  10. Sulfur, Chlorine, and Argon Abundances in Planetary Nebulae. III: Observations and Results for a Final Sample

    E-Print Network [OSTI]

    K. B. Kwitter; R. B. C. Henry; J. B. Milingo

    2002-09-25

    This paper is the fourth in a series whose purpose is to study the interstellar abundances of sulfur, chlorine, and argon in the Galaxy using a sample of 86 planetary nebulae. Here we present new high-quality spectrophotometric observations of 20 Galactic planetary nebulae with spectral coverage from 3700-9600 Angstroms. A major feature of our observations throughout the entire study has been the inclusion of the near-infrared lines of [S III] 9069,9532, which allows us to calculate accurate S+2 abundances and to either improve upon or convincingly confirm results of earlier sulfur abundance studies. For each of the 20 objects here we calculate ratios of S/O, Cl/O, and Ar/O and find average values of S/O=1.1E-2+/-1.1E-2, Cl/O=4.2E-4+/-5.3E-4, and Ar/O=5.7E-3+/-4.3E-3. For six objects we are able to compare abundances of S+3 calculated directly from available [S IV] 10.5 micron measurements with those inferred indirectly from the values of the ionization correction factors for sulfur. In the final paper of the series, we will compile results from all 86 objects, search for and evaluate trends, and use chemical evolution models to interpret our results.

  11. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, George (820 Skywood Rd., Lafayette, CA 94549); Orr, Thomas Robert (2285 Vestal, Castro Valley, CA 94546); Greene, Charles Maurice (6450 Regent St., Oakland, CA 94618); Crawford, Douglas Gordon (33 Longridge Rd., Orinda, CA 94563); Berman, Samuel Maurice (2832 Union St., San Francisco, CA 94123)

    1998-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  12. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, George (Lafayette, CA); Orr, Thomas Robert (Castro Valley, CA); Greene, Charles Maurice (Oakland, CA); Crawford, Douglas Gordon (Orinda, CA); Berman, Samuel Maurice (San Francisco, CA)

    1999-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  13. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1998-10-20

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  14. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  15. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  16. Fast-regenerable sulfur dioxide absorbents for lean-burn diesel engine emission control

    SciTech Connect (OSTI)

    Li, Liyu; King, David L.

    2010-01-23

    It is known that sulfur oxides contribute significantly and deleteriously to the overall performance of lean-burn diesel engine aftertreatment systems, especially in the case of NOx traps. A Ag-based, fast regenerable SO2 absorbent has been developed and will be described. Over a temperature range of 300oC to 550oC, it absorbs almost all of the SO2 in the simulated exhaust gases during the lean cycles and can be fully regenerated by the short rich cycles at the same temperature. Its composition has been optimized as 1 wt% Pt-5wt%Ag-SiO2, and the preferred silica source for the supporting material has been identified as inert Cabosil fumed silica. The thermal instability of Ag2O under fuel-lean conditions at 230oC and above makes it possible to fast regenerate the sulfur-loaded absorbent during the following fuel-rich cycles. Pt catalyst helps reducing Ag2SO4 during rich cycles at low temperatures. And the chemically inert fumed SiO2 support gives the absorbent long term stability. This absorbent shows great potential to work under the same lean-rich cycling conditions as those imposed on the NOx traps, and thus, can protect the downstream particulate filter and the NOx trap from sulfur poisoning.

  17. HYBRID SULFUR FLOWSHEETS USING PEM ELECTROLYSIS AND A BAYONET DECOMPOSITION REACTOR

    SciTech Connect (OSTI)

    Gorensek, M; William Summers, W

    2008-05-30

    A conceptual design is presented for a Hybrid Sulfur process for the production of hydrogen using a high-temperature nuclear heat source to split water. The process combines proton exchange membrane-based SO{sub 2}-depolarized electrolyzer technology being developed at Savannah River National Laboratory with silicon carbide bayonet decomposition reactor technology being developed at Sandia National Laboratories. Both are part of the US DOE Nuclear Hydrogen Initiative. The flowsheet otherwise uses only proven chemical process components. Electrolyzer product is concentrated from 50 wt% sulfuric acid to 75 wt% via recuperative vacuum distillation. Pinch analysis is used to predict the high-temperature heat requirement for sulfuric acid decomposition. An Aspen Plus{trademark} model of the flowsheet indicates 340.3 kJ high-temperature heat, 75.5 kJ low-temperature heat, 1.31 kJ low-pressure steam, and 120.9 kJ electric power are consumed per mole of H{sub 2} product, giving an LHV efficiency of 35.3% (41.7% HHV efficiency) if electric power is available at a conversion efficiency of 45%.

  18. Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.; Hawk, Jeffrey A.

    2005-01-01

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

  19. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1999-06-22

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  20. A class of polysulfide catholytes for lithium-sulfur batteries: energy density, cyclability, and voltage enhancement

    SciTech Connect (OSTI)

    Yu, XW; Manthiram, A

    2015-01-01

    Liquid-phase polysulfide catholytes are attracting much attention in lithium-sulfur (Li-S) batteries as they provide a facile dispersion and homogeneous distribution of the sulfur active material in the conductive matrix. However, the organic solvents used in lithium-polysulfide (Li-PS) batteries play an important role and have an impact on the physico-chemical characteristics of polysulfides. For instance, significantly higher voltages (similar to 2.7 V) of the S/S-n(2-) (4 <= n <= 8) redox couple are observed in Li-PS batteries with dimethyl sulfoxide (DMSO) and N-methyl-2-pyrrolidone (NMP) solvents. Accordingly, high power Li-PS batteries are presented here with the catholyte prepared with NMP solvent and operated with the highly reversible sulfur/long-chain polysulfide redox couple. On the other hand, a remarkable cyclability enhancement of the Li-PS battery is observed with the long-chain, ether-based tetraglyme (TEGDME) solvent. The voltage enhancement and the cyclability enhancement of the Li-PS batteries are attributed to the solvation effect, viscosity, and volatility of the solvents. Finally, highly concentrated polysulfide catholytes are successfully synthesized, with which high energy density Li-PS batteries are demonstrated by employing a multi-walled carbon nanotube (MWCNT) fabric electrode.

  1. ELECTRON IRRADIATION OF CARBON DISULFIDE-OXYGEN ICES: TOWARD THE FORMATION OF SULFUR-BEARING MOLECULES IN INTERSTELLAR ICES

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I. [Department of Chemistry, University of Hawai'i at Manoa, Honolulu, HI 96822 (United States)

    2013-08-20

    The formation of sulfur-bearing molecules in interstellar ices was investigated during the irradiation of carbon disulfide (CS{sub 2})-oxygen (O{sub 2}) ices with energetic electrons at 12 K. The irradiation-induced chemical processing of these ices was monitored online and in situ via Fourier transform infrared spectroscopy to probe the newly formed products quantitatively. The sulfur-bearing molecules produced during the irradiation were sulfur dioxide (SO{sub 2}), sulfur trioxide (SO{sub 3}), and carbonyl sulfide (OCS). Formations of carbon dioxide (CO{sub 2}), carbon monoxide (CO), and ozone (O{sub 3}) were observed as well. To fit the temporal evolution of the newly formed products and to elucidate the underlying reaction pathways, kinetic reaction schemes were developed and numerical sets of rate constants were derived. Our studies suggest that carbon disulfide (CS{sub 2}) can be easily transformed to carbonyl sulfide (OCS) via reactions with suprathermal atomic oxygen (O), which can be released from oxygen-containing precursors such as water (H{sub 2}O), carbon dioxide (CO{sub 2}), and/or methanol (CH{sub 3}OH) upon interaction with ionizing radiation. This investigation corroborates that carbonyl sulfide (OCS) and sulfur dioxide (SO{sub 2}) are the dominant sulfur-bearing molecules in interstellar ices.

  2. Functionally-graded fiber-reinforced cement composite: Processing, microstructure, and properties

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Functionally-graded fiber-reinforced cement composite: Processing, microstructure, and properties-graded fiber-reinforced cement composite (FGFRCC). Fiber volume fractions were increased linearly from 0: Fiber-reinforced cement composite (FRCC); Functionally-graded fiber-reinforced cement composite (FGFRCC

  3. ISIS 9.0 | Faculty Center Grade Roster 1 Updated: 05.04.15

    E-Print Network [OSTI]

    Capogna, Luca

    1 ISIS 9.0 | Faculty Center ­ Grade Roster 1 Updated: 05.04.15 Faculty Center ­ Grade Roster ISIS 9 the date the grade entry must be completed. 1. Accessing Faculty Center 1.1. Log in to ISIS. Open your browser and type isis.uark.edu in the URL address field. Type your ISIS User ID and Password

  4. The Economic Feasibility of Assuring U.S. Grade A Quality of

    E-Print Network [OSTI]

    for U.S. Grade A fish, and that sales tended to increase when the U.S. Grade A label appeared on the package and the quality was, in fact, high. This paper, although incorporating the major findings the U.S. Grade A label can be used only on products for which Federal standards exist (Ryan, 1971

  5. Finite Ground Coplanar Lines on CMOS Grade Silicon with a Thick Embedded Silicon Oxide Layer Using

    E-Print Network [OSTI]

    Tentzeris, Manos

    Finite Ground Coplanar Lines on CMOS Grade Silicon with a Thick Embedded Silicon Oxide Layer Using grade silicon wafer (poxide layer have been developed using on a CMOS grade silicon substrate ( ~ 4 . 0 1Cl-cm) with an embedded thick silicon oxide layer using

  6. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Mattson, Earl D. (Albuquerque, NM); Sisson, James B. (Idaho Falls, ID)

    1998-01-01

    A tensiometer to in situ determine below-grade soil moisture, potential of earthen soil includes, a) an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and, comprising; b) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; c) a first fluid conduit extending outwardly of the first fluid chamber; d) a first controllable isolation valve provided within the first fluid conduit, the first controllable isolation valve defining a second fluid chamber in fluid communication with the first fluid chamber through the first fluid conduit and the isolation valve, the first controllable isolation valve being received within the below-grade portion; and e) a pressure transducer in fluid communication with the first fluid chamber, the pressure transducer being received within the below-grade portion. An alternate embodiment includes an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and including: i) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; and ii) a pressure sensing apparatus in fluid communication with the first fluid chamber, the pressure sensing apparatus being entirely received within the below-grade portion. A method is also disclosed using the above and other apparatus.

  7. Tensiometer and method of determining soil moisture potential in below-grade earthen soil

    DOE Patents [OSTI]

    Hubbell, J.M.; Mattson, E.D.; Sisson, J.B.

    1998-06-02

    A tensiometer to in-situ determine below-grade soil moisture, potential of earthen soil includes, (a) an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and, comprising; (b) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; (c) a first fluid conduit extending outwardly of the first fluid chamber; (d) a first controllable isolation valve provided within the first fluid conduit, the first controllable isolation valve defining a second fluid chamber in fluid communication with the first fluid chamber through the first fluid conduit and the isolation valve, the first controllable isolation valve being received within the below-grade portion; and (e) a pressure transducer in fluid communication with the first fluid chamber, the pressure transducer being received within the below-grade portion. An alternate embodiment includes an apparatus adapted for insertion into earthen soil below grade, the apparatus having a below-grade portion, and including: (1) a porous material provided in the below-grade portion, the porous material at least in part defining a below-grade first fluid chamber; and (2) a pressure sensing apparatus in fluid communication with the first fluid chamber, the pressure sensing apparatus being entirely received within the below-grade portion. A method is also disclosed using the above and other apparatus. 6 figs.

  8. School Conditions Will Continue to Earn Failing Grades 

    E-Print Network [OSTI]

    Sonne, J. K.; Vieira, R. K.; Cummings, J. B.

    2006-01-01

    Will Continue to Earn Failing Grades Jeffrey K. Sonne Senior Research Engineer Robin K. Vieira Director, Buildings Research Division Florida Solar Energy Center Cocoa, Florida James B. Cummings Program Manager ABSTRACT This study addresses... (dehumidification) performance. • Cooling system fans can be set to fan “on” on days when the outdoor dew point temperature is say 62 o F or below. • After making changes, monitor indoor relative humidity during hot and humid weather. If reducing air handler...

  9. Low Grade Heat Recovery- A Unique Approach at Polysar Limited 

    E-Print Network [OSTI]

    Shyr, S.

    1988-01-01

    to the river condition. High feed water turbidity, resulting from yearly spring run off and turbulent river conditions from stonns, had led to reduced ion exchange train throughput capacity and increased frequency of sand filter backwash. (2) The operating... exchangers in Canada saves energy for Polysar Limited. This unique retrofit proj~t has not only increased the recovery of low grade heat but also Integrated and optimized the operation of two dif~erent .w~ter treatment facilities. The estimated annual...

  10. FISCAL YEAR 2006 REPORT ON ELECTROLYZER COMPONENT DEVELOPMENT FOR THE HYBRID SULFUR PROJECT

    SciTech Connect (OSTI)

    Colon-Mercado, H; David Hobbs, D; Daryl Coleman, D; Amy Ekechukwu, A

    2006-08-03

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In FY05, testing at the Savannah River National Laboratory (SRNL) explored a low temperature fuel cell design concept for the SDE. The advantages of this design concept include high electrochemical efficiency and small volumetric footprint that is crucial for successful implementation on a commercial scale. A key component of the SDE is the ion conductive membrane through which protons produced at anode migrate to the cathode and react to produce hydrogen. An ideal membrane for the SDE should have both low ionic resistivity and low sulfur dioxide transport. These features allow the electrolyzer to perform at high currents with low potentials, along with preventing contamination of both the hydrogen output and poisoning of the catalysts involved. Another key component is the electrocatalyst material used for the anode and cathode. Good electrocatalysts should be chemically stable and low overpotential for the desired electrochemical reactions. This report summarizes results from activities to evaluate different membrane and electrocatalyst materials for the SDE. Several different types of commercially-available membranes were analyzed for ionic resistance and sulfur dioxide transport including perfluorinated sulfonic acid, sulfonated poly-etherketone-ketone, and poly-benzimidazole membranes. Of these membrane types, the poly-benzimidazole (PBI) membrane, Celtec-L, exhibited the best combination of characteristics for use in an SDE. Testing examined the activity and stability of platinum and palladium as electrocatalyst for the SDE in sulfuric acid solutions. Cyclic and linear sweep voltammetry revealed that platinum provided better catalytic activity with much lower potentials and higher currents than palladium. Testing also showed that the catalyst activity is strongly influenced by concentration of the sulfuric acid. Various cell configurations were examined with respect to the deposition of electrocatalyst and use of conductive carbon materials such as carbon cloth and carbon paper. Findings from these evaluations and the results of the membrane and electrocatalyst testing, we prepared three different membrane electrode assemblies (MEA) for electrolyzer testing. The first MEA consisted of a Nafion{reg_sign} membrane with platinum electrocatalyst deposited on carbon cloths, which were heat pressed onto the membrane, an assembly identical to those used in proton exchange membrane fuel cells. The second MEA also used a Nafion membrane with the electrocatalysts deposited directly onto the membrane. The third MEA proved similar to the second but utilized a PBI membrane in place of the Nafion{reg_sign} membrane. Tailor of the membrane and catalysts properties for the SDE system was concluded as a required step for the technology to move forward. It was also recommended the evaluation of the tested and new developed materials at conditions closer to the SDE operating conditions and for longer period of time.

  11. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  12. Antireflective graded index silica coating, method for making

    DOE Patents [OSTI]

    Yoldas, Bulent E. (Churchill, PA); Partlow, Deborah P. (Wilkinsburg, PA)

    1985-01-01

    Antireflective silica coating for vitreous material is substantially non-reflecting over a wide band of radiations. This is achieved by providing the coating with a graded degree of porosity which grades the index of refraction between that of air and the vitreous material of the substrate. To prepare the coating, there is first prepared a silicon-alkoxide-based coating solution of particular polymer structure produced by a controlled proportion of water to alkoxide and a controlled concentration of alkoxide to solution, along with a small amount of catalyst. The primary solvent is alcohol and the solution is polymerized and hydrolized under controlled conditions prior to use. The prepared solution is applied as a film to the vitreous substrate and rapidly dried. It is thereafter heated under controlled conditions to volatilize the hydroxyl radicals and organics therefrom and then to produce a suitable pore morphology in the residual porous silica layer. The silica layer is then etched in order to enlarge the pores in a graded fashion, with the largest of the pores remaining being sufficiently small that radiations to be passed through the substrate are not significantly scattered. For use with quartz substrates, extremely durable coatings which display only 0.1% reflectivity have been prepared.

  13. Role of Nuclear Grade Graphite in Oxidation in Modular HTGRs

    SciTech Connect (OSTI)

    Willaim Windes; G. Strydom; J. Kane; R. Smith

    2014-11-01

    The passively safe High Temperature Gas-cooled Reactor (HTGR) design is one of the primary concepts considered for Generation IV and Small Modular Reactor (SMR) programs. The helium cooled, nuclear grade graphite moderated core achieves extremely high operating temperatures allowing either industrial process heat or electricity generation at high efficiencies. In addition to their neutron moderating properties, nuclear grade graphite core components provide excellent high temperature stability, thermal conductivity, and chemical compatibility with the high temperature nuclear fuel form. Graphite has been continuously used in nuclear reactors since the 1940’s and has performed remarkably well over a wide range of core environments and operating conditions. Graphite moderated, gas-cooled reactor designs have been safely used for research and power production purposes in multiple countries since the inception of nuclear energy development. However, graphite is a carbonaceous material, and this has generated a persistent concern that the graphite components could actually burn during either normal or accident conditions [ , ]. The common assumption is that graphite, since it is ostensibly similar to charcoal and coal, will burn in a similar manner. While charcoal and coal may have the appearance of graphite, the internal microstructure and impurities within these carbonaceous materials are very different. Volatile species and trapped moisture provide a source of oxygen within coal and charcoal allowing them to burn. The fabrication process used to produce nuclear grade graphite eliminates these oxidation enhancing impurities, creating a dense, highly ordered form of carbon possessing high thermal diffusivity and strongly (covalently) bonded atoms.

  14. High Performance Slab-on-Grade Foundation Insulation Retrofits

    SciTech Connect (OSTI)

    Goldberg, Louise F.; Mosiman, Garrett E.

    2015-09-01

    ?A more accurate assessment of SOG foundation insulation energy savings than traditionally possible is now feasible. This has been enabled by advances in whole building energy simulation with 3-dimensional foundation modelling integration at each time step together with an experimental measurement of the site energy savings of SOG foundation insulation. Ten SOG insulation strategies were evaluated on a test building to identify an optimum retrofit insulation strategy in a zone 6 climate (Minneapolis, MN). The optimum insulation strategy in terms of energy savings and cost effectiveness consisted of two components: (a) R-20 XPS insulation above grade, and, (b) R-20 insulation at grade (comprising an outer layer of R-10 insulation and an interior layer of R-12 poured polyurethane insulation) tapering to R-10 XPS insulation at half the below-grade wall height (the lower half of the stem wall was uninsulated). The optimum insulation strategy was applied to single and multi-family residential buildings in climate zone 4 - 7. The highest site energy savings of 5% was realized for a single family home in Duluth, MN, and the lowest savings of 1.4 % for a 4-unit townhouse in Richmond, VA. SOG foundation insulation retrofit simple paybacks ranged from 18 to 47 years. There are other benefits of SOG foundation insulation resulting from the increase in the slab surface temperatures. These include increased occupant thermal comfort, and a decrease in slab surface condensation particularly around the slab perimeter.

  15. Table of Contents Deschutes Subbasin Plan

    E-Print Network [OSTI]

    Table of Contents Deschutes Subbasin Plan Table of Contents Executive Summary 1. Purpose and Scope.1. Physical, Natural and Human Landscape ................................................2.1 2.2. Water, Table of Contents Page 1 #12;Table of Contents 7. Limiting Factors and Conditions .........

  16. Regulations and Basic Information Table of Contents

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    Regulations and Basic Information Table of Contents Safe and Effective Use.) for Various Quantities of Water

  17. Table Of Contents Section: Page

    E-Print Network [OSTI]

    US Army Corps of Engineers

    EM 385-1-1 XX Sep 13 i Section 2 SANITATION Table Of Contents Section: Page 02.A General Water......................................................... 2-1 02.D Non-Potable Water and openings. 02.C DRINKING WATER #12;EM 385-1-1 XX Sep 13 2-2 02.C.01 An adequate supply of potable water

  18. THINKING THESIS Table of Contents

    E-Print Network [OSTI]

    Massachusetts at Lowell, University of

    THINKING THESIS GUIDEBOOK #12;#12;Table of Contents Part One: Getting Started 1. What the Honors aides 5. Final Turn in of the Thesis Appendix I. Sample Title Page II. Honors Mentor Declaration Form on to better things. Theodore Roosevelt #12;#12;Honors College Thesis Requirements There are several forms

  19. OUTLOOK BYLAWS Table of Contents

    E-Print Network [OSTI]

    OUTLOOK BYLAWS Table of Contents Article I - Legal Authority to Operate Article II - Scope-in-Chief and Responsible Director Article VIII - Funding of Outlook Article IX - Unused Funds Article X - Composition The publication of Outlook is authorized under a license granted to AUB by decision No. 113 issued by the Lebanese

  20. Table of Contents Executive Summary

    E-Print Network [OSTI]

    McDonald, Kirk

    Table of Contents Page Executive Summary I. Introduction 1 Neutrino Oscillation Results from Solar and Atmospheric Neutrino Data 1 Tables 7 References 5 Figures 9 II. Overview of the Long Baseline Experiment 17 Magnetic Moment, Charge Radius, and Extra Z-bosons 261 VII. Cost and Schedule 265 Project schedule 267 Work