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Sample records for grabens horst blocks

  1. Horst and Graben | Open Energy Information

    Open Energy Info (EERE)

    W 49,500,000,000 mW 0.0495 GW 4.95e-5 TW 470.15 K197 C 386.6 F 846.27 R Brady Hot Springs Geothermal Area Northwest Basin and Range Geothermal Region Extensional...

  2. John Horst | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Horst About Us John Horst - Public Affairs Specialist with the Office of Energy Efficiency and Renewable Energy John Horst is a Public Affairs Specialist with the Office of Energy Efficiency and Renewable Energy. Most Recent Super Bowl City Leads on Energy Efficient Forefront February 2 Ultra Energy Efficient Data Center Saves NREL $200,000 November 14

  3. Growth faulting and syntectonic casting of the Dawson Creek Graben Complex: A North American craton-marginal trough; Carboniferous-Permian Peace River Embayment, western Canada

    SciTech Connect (OSTI)

    Barclay, J.E.; Utting, J. ); Krause, F.F.; Campbell, R.I. )

    1991-06-01

    The Dawson Creek Graben Complex was a 150 {times} 300 km, craton-perpendicular trough near the western North American craton margin. Sedimentary infill spanned 100 million years, and this tectonically controlled basin provides a comparison with other craton-marginal troughs or aulacogens, such as the Big Snowy, Uinta, Delaware, and Southern Oklahoma. The authors suspect that the graben complex was controlled by outboard, Antler-like orogeny and perhaps some strike-slip control. This syntectonic graben infill model provides a basis for developing new structural-stratigraphic plays in this mature basin. This extensional trough rests on a former basement arch and is centered in the broadly downwarped Peace River embayment. Sediment infill records several graben casting stages beginning with westernmost down-dropping, which then extended eastward and was accompanied by an increase in growth-type block faulting. Subsidence and faulting decay was followed by a retreat to western areas and tectonic stabilization. The complex was an arcuate half-graben, steep to the north, that widened asymmetrically and increased in depth to the west through time. The complex contained a principal half-graben with neighboring satellite grabens; throughout the complex are numerous kilometer-scale horst and graben blocks. The horsts subsided slower than neighboring grabens. This differential subsidence along block-bounding syn- and postdepositional growth-type normal faults controlled formation and bed thickness, as did inter- and intraformational unconformities.

  4. Anastomosing grabens, low-angle faults, and Tertiary thrust( ) faults, western Markagunt Plateau, southwestern Utah

    SciTech Connect (OSTI)

    Maldonado, F.; Sable, E.G. )

    1993-04-01

    A structurally complex terrane composed of grabens and horsts, low-angle faults, Tertiary thrust( ) faults, gravity-slide blocks, and debris deposits has been mapped along the western Markagunt Plateau, east of Parowan and Summit, southwestern Utah. This terrane, structurally situated within the transition between the Basin and Range and Colorado Plateau provinces, contains Tertiary volcanic and sedimentary and Cretaceous sedimentary rocks. The structures are mostly Miocene to Oligocene but some are Pleistocene. The oldest structure is the Red Hills low-angle shear zone, interpreted as a shallow structure that decoupled an upper plate composed of a Miocene-Oligocene volcanic ash-flow tuff and volcaniclastic succession from a lower plate of Tertiary sedimentary rocks. The period of deformation on the shear zone is bracketed from field relationships between 22.5 and 20 Ma. The graben-horst system trends northeast and formed after about 20 Ma (and probably much later) based on displacement of dated dikes and a laccolith. The central part of the system contains many grabens that merge toward its southerly end to become a single graben. Within these grabens, (1) older structures are preserved, (2) debris eroded from horst walls forms lobe-shaped deposits, (3) Pleistocene basaltic cinder cones have localized along graben-bounding faults, and (4) rock units are locally folded suggesting some component of lateral translation along graben-bounding faults. Megabreccia deposits and landslide debris are common. Megabreccia deposits are interpreted as gravity-slide blocks of Miocene-Oligocene( ) age resulting from formation of the Red Hills shear zone, although some may be related to volcanism, and still others to later deformation. The debris deposits are landslides of Pleistocene-Pliocene( ) age possibly caused by continued uplift of the Markagunt Plateau.

  5. Microsoft PowerPoint - Horst Simon.BitstoBuidings2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficient Computing: From Bits to Energy Efficient Computing: From Bits to Buildings Horst D. Simon Lawrence Berkeley National Laboratory Lawrence Berkeley National Laboratory and EECS Dept., UC Berkeley hdsimon@lbl.gov The Salishan Conference on High-Speed Computing April 29, 2009 Acknowledgements A l b f i di id l h t ib t d t A large number of individuals have contributed to energy efficiency in computing at Berkeley Lab, UC Berkeley, and to this presentation: David Bailey (CRD), Michael

  6. Property:TopoFeatures | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Area + Horst and Graben + Blue Mountain Geothermal Area + Horst and Graben + Brady Hot Springs Geothermal Area + Horst and Graben + C Coso Geothermal Area + Horst and...

  7. Interpretation of recent seismic data from a frontier hydrocarbon province: western Rough Creek graben, southern Illinois and western Kentucky

    SciTech Connect (OSTI)

    Bertagne, A.J.; Pisasale, E.T.; Leising, T.C.

    1986-05-01

    The northern basement fault of the Rough Creek graben is seismically discernible and has surface expression in the Rough Creek fault zone. The southern basement fault is not clearly defined seismically, but can be inferred from shallow faulting and gravity data. This fault is roughly coincident with the Pennyrile fault zone. Extensional faults that formed the rift boundaries were the sites of late-stage compressional and extensional tectonics. Flower structures observed along the graben boundaries probably indicate post-Pennsylvanian wrench faulting. The basement within the graben plunges north-northwest, with the lowest point occurring south of the Rough Creek fault zone. Pre-Knox sediments thicken to approximately 12,000 in this area. The Knox Megagroup thickens toward the Mississippi Embayment, ranging from 4800 ft (southeastern graben area) to more than 7000 ft (west end of graben). Upper Ordovician to Devonian units also display westward thickening. The top of the Meramecian, New Albany, Maquoketa, and the base of the Knox generate continuous, high-amplitude seismic reflections due to large impedance contrasts between clastic and carbonate units. Shallow oil and gas production (Mississippian and Pennsylvanian) is present in this area. However, deep horizons (Knox, Lower Cambrian) remain relatively untested. Potential hydrocarbon traps in the pre-Knox sequence observed on seismic include fault blocks and updip pinch-outs.

  8. Geometry of Cenozoic extensional faulting: Dixie Valley, Nevada...

    Open Energy Info (EERE)

    was also 15 km instead of the previously reported 40 km. Local microearthquakes cluster around 10-15 km. The geometrical block models indicate that crustal horst-graben...

  9. Shongaloo field: A recent smackover (Jurassic) discovery in the Arkansas-Louisiana state-line graben

    SciTech Connect (OSTI)

    DeMis, W.D.; Milliken, J.V. )

    1993-09-01

    The new North Shongaloo/Red Rock/Haynesville/East Haynesville (herein called Shongaloo) field is a recent discovery (1988) with reserves of 20-30 MMBOE. The field has over 50 wells producing from the Smackover Formation at about 11,000 ft depth, and is the largest field discovered in the very mature Arkansas-Louisiana state-line Smackover play in the past 20 yr. More significantly, the field is locate within the state-line graben, an area considered by industry as barren of Smackover potential because Smackover reservoir rocks were assumed absent. Shongaloo field pay is from the Smackover. The [open quotes]C[close quotes] sand has average porosity of 5-7% and average permeability of less than 1 md (average initial flow rate is 1500 MCFGD with 430 BCPD). The [open quotes]B[close quotes] carbonate reservoirs consist of ooid grainstones with average porosity of 14% and average permeability of 60 md, ranging up to 1800 md (average initial flow rate is 550 BOPD and 950 MCFGD). Shongaloo field is an upthrown fault trap within the overall downthrown central graben. Shongaloo field was found by overcoming two technical hurdles. First, reservoir rock distribution was shown to follow paleoshorelines through the graben. Porous ooid grainstones facies within a mappable cycle of the Smackover [open quotes]B[close quotes] are parallel to, and immediately downdip (<1.5 mi) of paleoshorelines. Paleoshorelines are documented by the updip pinchout of [open quotes]B[close quotes] cycles into time-equivalent Buckner red beds. Second, the critical trapping fault was resolved by shooting and interpreting modern proprietary seismic data. The discovery of Shongaloo field proves that significant reserves can be found in mature domestic plays by applying new technology and stratigraphic concepts.

  10. Laboratory modeling of graben inversion with application to broad fourteens basin, Netherlands offshore

    SciTech Connect (OSTI)

    Nalpas, T.; Brun, J.P. ); Le Douaran, S. ); Richert, J.P. )

    1993-09-01

    The southern North Sea presents spectacular examples of basin inversion, which have been documented by numerous projects of the oil industry. Some basic inversion patterns identified through wells and seismic data were used to prepare a laboratory modeling investigation. Models are built with sand and silicone putty, respectively, which represent the frictional behavior of Mesozoic cover and Paleozoic basement and the viscous behavior of the decollement layer, mainly Permian salt, between them. They are scaled to fit natural configurations observed in the Broad Fourteens basin. All experiments are done in two steps: (1) graben formation with synkinematic sedimentation and (2) compression oblique to the graben. The experiments show that structures generated by or reactivated during inversion are strongly dependent on the strength of the decollement layer at the base of the sedimentary cover, which is itself dependent on the silicone viscosity, the layer thickness, and the displacement velocity applied at model boundaries; and the strength of the sedimentary cover, which is solely dependent on its thickness. This work is in progress. Preliminary results will be compared with examples from the Broad Fourteens basin on the basis of both seismic data and structural maps.

  11. Controlling Structures | Open Energy Information

    Open Energy Info (EERE)

    fault terminations or tip-lines with multiple closely-spaced faults that enhance permeability. Mountainous, Horst and Graben Extensional Tectonics, Rift Zone Stepover or Relay...

  12. Mountainous | Open Energy Information

    Open Energy Info (EERE)

    Horst and Graben Shield Volcano Flat Lava Dome Stratovolcano Cinder Cone Caldera Depression Resurgent Dome Complex The interior of Iceland holds a vast expanse of mountainous...

  13. Lava Dome | Open Energy Information

    Open Energy Info (EERE)

    Horst and Graben Shield Volcano Flat Lava Dome Stratovolcano Cinder Cone Caldera Depression Resurgent Dome Complex "Volcanic or lava domes are formed by relatively small,...

  14. Sedimentation and reservoir distribution related to a tilted block system in the Sardinia Oligocene-Miocene rift (Italy)

    SciTech Connect (OSTI)

    Tremolieres, P.; Cherchi, A.; Eschard, R.; De Graciansky, P.C.; Montadert, L.

    1988-08-01

    In the western Mediterranean basin lies a rift system about 250 km long and 50 km wide and its infilling outcrop (central Sardinia). Seismic reflection surveys show its offshore extension. Block tilting started during the late Oligocene and lasted during Aquitanian-early Burdigalian time. Two main fault trends, with synthetic and antithetic throws, define the more-or-less collapsed blocks. This morphology guided the transit and trapping of sediments. The sedimentation started in a continental environment then, since the Chattian, in marine conditions. In the central part, the series can reach a thickness of 2,000 m. The basement composition and the volcanics products related to the main fault motion controlled the nature of the synrift deposits. According to their location in the rift context, the tilted blocks trap either continental deposits or marine siliciclastic or carbonate deposits. In the deeper part of the graben, sands were redeposited by gravity flows into the basinal marls. The younger prerift deposits are from Eocene to early Oligocene age and locally comprise thick coal layers. Postrift deposits, mainly marls, sealed the blocks and synrift sedimentary bodies. In middle and late Miocene time some faults were reactivated during compressional events. Then, a quaternary extensional phase created the Campidano graben, filled with about 1,000 m of sediments superimposed on the Oligocene-Miocene rift.

  15. Pattern of extensional faulting in pelagic carbonates of the Unbria-Marche Apennines of central Italy

    SciTech Connect (OSTI)

    Alvarez, W. )

    1990-05-01

    The Umbria-Marche Apennines provide a new region in which the nature passive-margin extensional faulting can be studied in outcrop. In these dominantly pelagic carbonate rocks of Jurassic and Cretaceous age, horsts acted as shallow, nonvolcani seamounts, while tilted half grabens formed deeper basins. One well-exposed seamount-basin transition agrees in general with the model of listric normal faulting and tilted half grabens, but shows interesting and significant divergences when studied in detail. A small sedimentary wedge at the faulted margin of a horst-block seamount thickens unexpectedly toward the adjacent basin. This wedge developed because of local convex-upward curvature of the shallowest part of a fault which at depth must have concave-up, listric geometry. The local sedimentary wedge resulted from deposition on the hanging wall as it tilted, followed by differential compaction of younger limestones that lapped onto the gentle slope leading from the horst-block seamount toward the basin. The map pattern of listric normal faulting in the Umbria-Marche Apennines suggests that both principal strain axes were extensional, in contrast to the usual pattern of listric faults crossed by transfer faults.

  16. Thermally actuated wedge block

    DOE Patents [OSTI]

    Queen, Jr., Charles C.

    1980-01-01

    This invention relates to an automatically-operating wedge block for maintaining intimate structural contact over wide temperature ranges, including cryogenic use. The wedging action depends on the relative thermal expansion of two materials having very different coefficients of thermal expansion. The wedge block expands in thickness when cooled to cryogenic temperatures and contracts in thickness when returned to room temperature.

  17. Block copolymer battery separator

    DOE Patents [OSTI]

    Wong, David; Balsara, Nitash Pervez

    2016-04-26

    The invention herein described is the use of a block copolymer/homopolymer blend for creating nanoporous materials for transport applications. Specifically, this is demonstrated by using the block copolymer poly(styrene-block-ethylene-block-styrene) (SES) and blending it with homopolymer polystyrene (PS). After blending the polymers, a film is cast, and the film is submerged in tetrahydrofuran, which removes the PS. This creates a nanoporous polymer film, whereby the holes are lined with PS. Control of morphology of the system is achieved by manipulating the amount of PS added and the relative size of the PS added. The porous nature of these films was demonstrated by measuring the ionic conductivity in a traditional battery electrolyte, 1M LiPF.sub.6 in EC/DEC (1:1 v/v) using AC impedance spectroscopy and comparing these results to commercially available battery separators.

  18. Characterization of Pliocene and Miocene Formations in the Wilmington Graben, Offshore Los Angeles, for Large-Scale Geologic Storage of CO₂

    SciTech Connect (OSTI)

    Bruno, Michael

    2014-12-08

    Geomechanics Technologies has completed a detailed characterization study of the Wilmington Graben offshore Southern California area for large-scale CO₂ storage. This effort has included: an evaluation of existing wells in both State and Federal waters, field acquisition of about 175 km (109 mi) of new seismic data, new well drilling, development of integrated 3D geologic, geomechanics, and fluid flow models for the area. The geologic analysis indicates that more than 796 MMt of storage capacity is available within the Pliocene and Miocene formations in the Graben for midrange geologic estimates (P50). Geomechanical analyses indicate that injection can be conducted without significant risk for surface deformation, induced stresses or fault activation. Numerical analysis of fluid migration indicates that injection into the Pliocene Formation at depths of 1525 m (5000 ft) would lead to undesirable vertical migration of the CO₂ plume. Recent well drilling however, indicates that deeper sand is present at depths exceeding 2135 m (7000 ft), which could be viable for large volume storage. For vertical containment, injection would need to be limited to about 250,000 metric tons per year per well, would need to be placed at depths greater than 7000ft, and would need to be placed in new wells located at least 1 mile from any existing offset wells. As a practical matter, this would likely limit storage operations in the Wilmington Graben to about 1 million tons per year or less. A quantitative risk analysis for the Wilmington Graben indicate that such large scale CO₂ storage in the area would represent higher risk than other similar size projects in the US and overseas.

  19. Tectonic and eustatic controls on facies distribution in the middle of upper Jurassic, Viking Graben, Norwegian North Sea

    SciTech Connect (OSTI)

    Sneider, J.S.; Vail, P.R. ); De Clarens, P. )

    1993-09-01

    The Middle of Upper Jurassic in the Viking Graben area was deposited during an overall transgression. From the lower Toarcian to the base of the cretaceous, there are seven 2nd-order (3-5 m.y.) transgressive-regressive (T/R) facies cycles that are related to regional tectonic events. These cycles dominate facies distribution, appear synchronous, and can be correlated throughout the study area. Local tectonics and sediment supply can modify these cycles. Local tectonics, sediment supply, and position in the T/R facies cycles control development of 3rd-order (0.5-3 m.y.) cycles. Where sediment supply is low, 3rd-order sequences are poorly developed. During a 2nd-order regression, shelfal areas and local highs are often eroded. Third-order sequences have well developed lowstands system-Y tracts (LST) and poorly developed transgressive systems tracts (TST). During 2nd-order transgressions, 3rd-order sequences have enhanced TST, starved HST, and poorly developed LST. Thick, stacked, shoreface sandstones may develop in the TST on terraces or on gently dipping slopes if sediment supply is high. The base of these sequences often shows an abrupt basinward shift in facies followed by backstepping facies. turbidites develop during 3rd-order lowstands when there is a steeply dipping slope and high sediment supply, but their distribution is more limited.

  20. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T.

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  1. Net Requirements Transparency Process for Slice/Block and Block...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 As part of its Net Requirements Transparency process, on July 31, 2013 BPA published the SliceBlock and Block customers' FY2012 and forecast FY2014 Total Retail Load (TRL) and...

  2. Category:Topographic Features | Open Energy Information

    Open Energy Info (EERE)

    Features" The following 9 pages are in this category, out of 9 total. C Caldera Depression Cinder Cone F Flat H Horst and Graben L Lava Dome M Mountainous R Resurgent Dome...

  3. CORE SATURATION BLOCKING OSCILLATOR

    DOE Patents [OSTI]

    Spinrad, R.J.

    1961-10-17

    A blocking oscillator which relies on core saturation regulation to control the output pulse width is described. In this arrangement an external magnetic loop is provided in which a saturable portion forms the core of a feedback transformer used with the thermionic or semi-conductor active element. A first stationary magnetic loop establishes a level of flux through the saturation portion of the loop. A second adjustable magnet moves the flux level to select a saturation point giving the desired output pulse width. (AEC)

  4. Manipulating and Visualizing Proteins Simon, Horst D. 59 BASIC...

    Office of Scientific and Technical Information (OSTI)

    ACIDS; CALIFORNIA; CHAINS; CHEMISTRY; DISEASES; FIBROSIS; FORECASTING; GENETICS; OPTIMIZATION; PROTEIN STRUCTURE; PROTEINS; QUEUES; SHAPE; SIMULATION PROTEIN STRUCTURE...

  5. Eikonalization of conformal blocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.; Wang, Junpu

    2015-09-03

    Classical field configurations such as the Coulomb potential and Schwarzschild solution are built from the t-channel exchange of many light degrees of freedom. We study the CFT analog of this phenomenon, which we term the 'eikonalization' of conformal blocks. We show that when an operator T appears in the OPE Ο(x)Ο(0), then the large spin Fock space states [TT···T]ℓ also appear in this OPE with a computable coefficient. The sum over the exchange of these Fock space states in an correlator build the classical 'T field' in the dual AdS description. In some limits the sum of all Fock spacemore » exchanges can be represented as the exponential of a single T exchange in the 4-pt correlator of O. Our results should be useful for systematizing 1/ℓ perturbation theory in general CFTs and simplifying the computation of large spin OPE coefficients. As examples we obtain the leading log ℓ dependence of Fock space conformal block coefficients, and we directly compute the OPE coefficients of the simplest ‘triple-trace’ operators.« less

  6. Eikonalization of conformal blocks

    SciTech Connect (OSTI)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.; Wang, Junpu

    2015-09-03

    Classical field configurations such as the Coulomb potential and Schwarzschild solution are built from the t-channel exchange of many light degrees of freedom. We study the CFT analog of this phenomenon, which we term the 'eikonalization' of conformal blocks. We show that when an operator T appears in the OPE Ο(x)Ο(0), then the large spin Fock space states [TT···T] also appear in this OPE with a computable coefficient. The sum over the exchange of these Fock space states in an correlator build the classical 'T field' in the dual AdS description. In some limits the sum of all Fock space exchanges can be represented as the exponential of a single T exchange in the 4-pt correlator of O. Our results should be useful for systematizing 1/ℓ perturbation theory in general CFTs and simplifying the computation of large spin OPE coefficients. As examples we obtain the leading log ℓ dependence of Fock space conformal block coefficients, and we directly compute the OPE coefficients of the simplest ‘triple-trace’ operators.

  7. Help:Blocking users | Open Energy Information

    Open Energy Info (EERE)

    3 What it means to be blocked 4 See Also Blocking Blocking users is fairly straightforward, visit Special:BlockIP and follow these steps: IP Address or username: Enter in...

  8. Standard Missile Block IV battery

    SciTech Connect (OSTI)

    Martin, J.

    1996-11-01

    During the 1980`s a trend in automatic primary battery technologies was the replacement of silver-zinc batteries by thermal battery designs. The Standard missile (SM 2) Block IV development is a noteworthy reversal of this trend. The SM2, Block IV battery was originally attempted as a thermal battery with multiple companies attempting to develop a thermal battery design. These attempts resulted in failure to obtain a production thermal battery. A decision to pursue a silver-zinc battery design resulted in the development of a battery to supply the SM 2, Block IV (thermal battery design goal) and also the projected power requirements of the evolving SM 2, Block IVA in a single silver-zinc battery design. Several advancements in silver-zinc battery technology were utilized in this design that improve the producibility and extend the boundaries of silver-zinc batteries.

  9. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport How Antidepressants Block Serotonin Transport Print Tuesday, 12 July 2016 00:00 Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In

  10. Help:Range blocks | Open Energy Information

    Open Energy Info (EERE)

    accounts editing from these IP addresses will also be blocked, unless you check the box to only block anonymous editors. Range blocking is enabled on all Wikimedia wikis; to...

  11. Block LancZos PACKage

    Energy Science and Technology Software Center (OSTI)

    2005-05-01

    BLZPACK (for Block LancZos PACKage) is a standard Fortran 77 implementation of the block Lanczos algorithm intended for the solution of the standard eigenvalue problem Ax=ux or the generalized eigenvalue problem Ax=uBx, where A and B are real, sparse symmetric matrices, u and eigenvalue and x and eigenvector. The development of this eigensolver was motivated by the need to solve large, sparse, generalized problems from free vibration analyses in structural engineering. Several upgrades were performedmore » afterwards aiming at the solution of eigenvalues problems from a wider range of applications.« less

  12. Belos Block Linear Solvers Package

    Energy Science and Technology Software Center (OSTI)

    2004-03-01

    Belos is an extensible and interoperable framework for large-scale, iterative methods for solving systems of linear equations with multiple right-hand sides. The motivation for this framework is to provide a generic interface to a collection of algorithms for solving large-scale linear systems. Belos is interoperable because both the matrix and vectors are considered to be opaque objects--only knowledge of the matrix and vectors via elementary operations is necessary. An implementation of Balos is accomplished viamore » the use of interfaces. One of the goals of Belos is to allow the user flexibility in specifying the data representation for the matrix and vectors and so leverage any existing software investment. The algorithms that will be included in package are Krylov-based linear solvers, like Block GMRES (Generalized Minimal RESidual) and Block CG (Conjugate-Gradient).« less

  13. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system, causing

  14. Liquid-blocking check valve

    DOE Patents [OSTI]

    Merrill, J.T.

    1982-09-27

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  15. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system,

  16. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system,

  17. How Antidepressants Block Serotonin Transport

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Antidepressants Block Serotonin Transport Print Serotonin is a diminutive and deceptively simple-looking neurotransmitter molecule, yet a very complex "machinery" is required for neurotransmitter recognition, transmission, and recycling. The malfunctioning of this protein machinery can cause conditions such as depression, obsessive-compulsive disorder, aggression, anxiety, and Parkinson's disease. In addition, drugs of addiction, such as methamphetamines, act on this system,

  18. Method for making block siloxane copolymers

    DOE Patents [OSTI]

    Butler, Nora; Jessop, Edward S.; Kolb, John R.

    1982-01-01

    A method for synthesizing block polysiloxane copolymers. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

  19. Method for making block siloxane copolymers

    DOE Patents [OSTI]

    Butler, N.L.; Jessop, E.S.; Kolb, J.R.

    1981-02-25

    A method for synthesizing block polysiloxane copolymers is disclosed. Diorganoscyclosiloxanes and an end-blocking compound are interacted in the presence of a ring opening polymerization catalyst, producing a blocked prepolymer. The prepolymer is then interacted with a silanediol, resulting in condensation polymerization of the prepolymers. A second end-blocking compound is subsequently introduced to end-cap the polymers and copolymers formed from the condensation polymerization.

  20. BLOCKING OSCILLATOR DOUBLE PULSE GENERATOR CIRCUIT

    DOE Patents [OSTI]

    Haase, J.A.

    1961-01-24

    A double-pulse generator, particuiarly a double-pulse generator comprising a blocking oscillator utilizing a feedback circuit to provide means for producing a second pulse within the recovery time of the blocking oscillator, is described. The invention utilized a passive network which permits adjustment of the spacing between the original pulses derived from the blocking oscillator and further utilizes the original pulses to trigger a circuit from which other pulses are initiated. These other pulses are delayed and then applied to the input of the blocking oscillator, with the result that the output from the oscillator circuit contains twice the number of pulses originally initiated by the blocking oscillator itself.

  1. LARGE BLOCK TEST STATUS REPORT

    SciTech Connect (OSTI)

    Wilder, D. G.; Blair, S. C.; Buscheck, T.; Carloson, R. C.; Lee, K.; Meike, A.; Ramirez, J. L.; Sevougian, D.

    1997-08-26

    This report is intended to serve as a status report, which essentially transmits the data that have been collected to date on the Large Block Test (LBT). The analyses of data will be performed during FY98, and then a complete report will be prepared. This status report includes introductory material that is not needed merely to transmit data but is available at this time and therefore included. As such, this status report will serve as the template for the future report, and the information is thus preserved. The United States Department of Energy (DOE) is investigatinq the suitability of Yucca Mountain (YM) as a potential site for the nation's first high-level nuclear waste repository. As shown in Fig. 1-1, the site is located about 120 km northwest of Las Vegas, Nevada, in an area of uninhabited desert.

  2. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program ... diode (LED) retrofits, 4) building retrofits to replace a 50 ton HVAC ...

  3. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title ...

  4. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NEP A Determination for the Energy Efficiency and Conservation Block Grant Program Application submitted by the Native Village of Tetlin of AK Energy Efficiency and Conservation ...

  5. Block Island Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    energy Facility Type Commercial Scale Wind Facility Status Proposed Developer Deepwater Wind Location Offshore from Block Island RI Coordinates 41.1, -71.53 Show Map Loading...

  6. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Grant Program Project Title AK-TRIBE-NANWALEK (AKA ENGLISH BAY) Location: Tribe AK-TRIBE- NANWALEK (AKA ENGLISH BAY) AK American Recovery and Reinvestment Act: Proposed ...

  7. Alternating Current Photovoltaic Building Block - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Alternating Current Photovoltaic Building Block Sandia National Laboratories Contact SNL About This...

  8. Precision aligned split V-block

    DOE Patents [OSTI]

    George, Irwin S.

    1984-01-01

    A precision aligned split V-block for holding a workpiece during a milling operation having an expandable frame for allowing various sized workpieces to be accommodated, is easily secured directly to the mill table and having key lugs in one base of the split V-block that assures constant alignment.

  9. Light extraction block with curved surface

    DOE Patents [OSTI]

    Levermore, Peter; Krall, Emory; Silvernail, Jeffrey; Rajan, Kamala; Brown, Julia J.

    2016-03-22

    Light extraction blocks, and OLED lighting panels using light extraction blocks, are described, in which the light extraction blocks include various curved shapes that provide improved light extraction properties compared to parallel emissive surface, and a thinner form factor and better light extraction than a hemisphere. Lighting systems described herein may include a light source with an OLED panel. A light extraction block with a three-dimensional light emitting surface may be optically coupled to the light source. The three-dimensional light emitting surface of the block may includes a substantially curved surface, with further characteristics related to the curvature of the surface at given points. A first radius of curvature corresponding to a maximum principal curvature k.sub.1 at a point p on the substantially curved surface may be greater than a maximum height of the light extraction block. A maximum height of the light extraction block may be less than 50% of a maximum width of the light extraction block. Surfaces with cross sections made up of line segments and inflection points may also be fit to approximated curves for calculating the radius of curvature.

  10. SF30 Continuation Page, Block 14

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Page 9 of 12 Contract DE-AC27-08RV 14800 Modification 083 SF30 Continuation Page, Block 14 7. Update Section J, J-4 Performance Evaluation and Measurement Plan (PEMP), page ...

  11. Building Blocks for the Future of Manufacturing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Blocks for the Future of Manufacturing Scott Smith 2011.05.04 Even though we grew ... Can you send more information on this technology? A photo of Scott Smith. About the Author ...

  12. Picture of the Week: Supercomputer building blocks

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Supercomputer building blocks The first row of cabinets for the new Trinity supercomputer are being prepared for connection to the water cooling infrastructure at Los Alamos National Laboratory. Each set of 12 cabinets is delivered, connected and tested one row at a time, by the Cray installation team, until all five rows arrive. June 21, 2015 Supercomputer building blocks x View extra-large image on Flickr » The first row of cabinets for the new Trinity supercomputer are being prepared for

  13. Molecular origin of photovoltaic performance in donor-block-acceptor all-conjugated block copolymers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Kendall A.; Lin, Yen -Hao; Mok, Jorge W.; Yager, Kevin G.; Strzalka, Joseph; Nie, Wanyi; Mohite, Aditya D.; Verduzco, Rafael

    2015-11-03

    All-conjugated block copolymers may be an effective route to self-assembled photovoltaic devices, but we lack basic information on the relationship between molecular characteristics and photovoltaic performance. Here, we synthesize a library of poly(3-hexylthiophene) (P3HT) block poly((9,9-dialkylfluorene)-2,7-diyl-alt-[4,7-bis(alkylthiophen-5-yl)-2,1,3-benzothiadiazole]-2',2''-diyl) (PFTBT) donor-block-acceptor all-conjugated block copolymers and carry out a comprehensive study of processing conditions, crystallinity, domain sizes, and side-chain structure on photovoltaic device performance. We find that all block copolymers studied exhibit an out-of-plane crystal orientation after deposition, and on thermal annealing at high temperatures the crystal orientation flips to an in-plane orientation. By varying processing conditions on polymer photovoltaic devices, we show thatmore » the crystal orientation has only a modest effect (15-20%) on photovoltaic performance. The addition of side-chains to the PFTBT block is found to decrease photovoltaic power conversion efficiencies by at least an order of magnitude. Through grazing-incidence X-ray measurements we find that the addition of side-chains to the PFTBT acceptor block results in weak segregation and small (< 10 nm) block copolymer self-assembled donor and acceptor domains. This work is the most comprehensive to date on all-conjugated block copolymer systems and suggests that photovoltaic performance of block copolymers depends strongly on the miscibility of donor and acceptor blocks, which impacts donor and acceptor domain sizes and purity. Lastly, strategies for improving the device performance of block copolymer photovoltaics should seek to increase segregation between donor and acceptor polymer domains.« less

  14. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency and Conservation Block Grant Financing Program Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy Efficiency ...

  15. Solvothermal Thin Film Deposition of Electron Blocking Layers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers...

  16. Deformation Processes in Block Copolymer Toughened Epoxies (Journal...

    Office of Scientific and Technical Information (OSTI)

    Deformation Processes in Block Copolymer Toughened Epoxies Citation Details In-Document Search Title: Deformation Processes in Block Copolymer Toughened Epoxies Authors:...

  17. Guidance For Energy Efficiency And Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing ...

  18. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Conservation Block Grant Financing Program Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy ...

  19. Exploration of multi-block polymer morphologies using high performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exploration of multi-block polymer morphologies using high performance computing Modern material design increasingly relies on controlling small scale morphologies. Multi-block...

  20. Indian Community Development Block Grant Program FY 2016 Notice...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Indian Community Development Block Grant Program FY 2016 Notice of Funding Availability Workshop Indian Community Development Block Grant Program FY 2016 Notice of Funding ...

  1. Guidance for Energy Efficiency and Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conservation Block Grant Grantees on Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds Guidance for Energy Efficiency and Conservation Block Grant Program ...

  2. Guidance for Energy Efficiency and Conservation Block Grant Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Grant Program Recipients on Formula Grants U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Energy Efficiency and Conservation Block ...

  3. Energy Efficiency and Conservation Block Grant Financing Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Program Guidance Grantee Letter Energy Efficiency and Conservation Block Grant ... of Energy Efficiency and Conservation Block Grant-funded financing programs, including ...

  4. Energy Efficiency and Conservation Block Grant Program National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Block Grant Program National Evaluation Executive Summary This document presents findings from an evaluation of the Energy Efficiency and Conservation Block Grant ...

  5. Energy Efficiency and Consveration Block Grant Program National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Consveration Block Grant Program National Evaluation Fact Sheet Energy Efficiency and Consveration Block Grant Program National Evaluation Fact Sheet This fact sheet provides ...

  6. Energy Efficiency and Conservation Block Grant Financing Programs...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement ...

  7. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON ...

  8. Guidance For Energy Efficiency And Conservation Block Grant Grantees...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs U.S. ...

  9. A novel power block for CSP systems

    SciTech Connect (OSTI)

    Mittelman, Gur; Epstein, Michael

    2010-10-15

    Concentrating Solar Thermal Power (CSP) and in particular parabolic trough, is a proven large-scale solar power technology. However, CSP cost is not yet competitive with conventional alternatives unless subsidized. Current CSP plants typically include a condensing steam cycle power block which was preferably designed for a continuous operation and higher operating conditions and therefore, limits the overall plant cost effectiveness and deployment. The drawbacks of this power block are as follows: (i) no power generation during low insolation periods (ii) expensive, large condenser (typically water cooled) due to the poor extracted steam properties (high specific volume, sub-atmospheric pressure) and (iii) high installation and operation costs. In the current study, a different power block scheme is proposed to eliminate these obstacles. This power block includes a top Rankine cycle with a back pressure steam turbine and a bottoming Kalina cycle comprising another back pressure turbine and using ammonia-water mixture as a working fluid. The bottoming (moderate temperature) cycle allows power production during low insolation periods. Because of the superior ammonia-water vapor properties, the condensing system requirements are much less demanding and the operation costs are lowered. Accordingly, air cooled condensers can be used with lower economical penalty. Another advantage is that back pressure steam turbines have a less complex design than condensing steam turbines which make their costs lower. All of these improvements could make the combined cycle unit more cost effective. This unit can be applicable in both parabolic trough and central receiver (solar tower) plants. The potential advantage of the new power block is illustrated by a detailed techno-economical analysis of two 50 MW parabolic trough power plants, comparing between the standard and the novel power block. The results indicate that the proposed plant suggests a 4-11% electricity cost saving

  10. ION PRODUCING MECHANISM (ARC EXTERNAL TO BLOCK)

    DOE Patents [OSTI]

    Brobeck, W.H.

    1958-09-01

    This patent pentains to an ion producing mechanism employed in a calutron which has the decided advantage of an increased amount of ionization effectuated by the arc, and a substantially uniform arc in poiat of time, i arc location and along the arc length. The unique features of the disclosed ion source lie in the specific structural arrangement of the source block, gas ionizing passage, filament shield and filament whereby the arc is established both within the ionizing passage and immediately outside the exit of the ionizing passage at the block face.

  11. Chemical relationship between discharging fluids in the Siena-Radicofani Graben and the deep fluids produced by the geothermal fields of Mt Amiata, torre Afina and Latera (Central Italy)

    SciTech Connect (OSTI)

    Duchi, V.; Paolieri, M.; Prati, F ); Minissale, A. Centro di Studio per Mineralogia e la Geochimica dei Sedimenti, Via La Pira 4, 50121 Firenze ); Valori, A )

    1992-06-01

    This paper reports that the thermal springs discharging in the Siena-Radicofani basin and the deep fluids within the geothermal systems of Piancastagnaio (Mt Amiata), Torre Alfina and Latera (Vulsini Mts) have a common origin. The chemical composition and evolution towards the low enthalpy of the springs as compared to the high enthalpy of the geothermal fluids are affected by both the structural setting of the region and the deep hydraulic conditions. Recharge of both the shallow thermal aquifer and the deep geothermal systems takes place in the outcrop areas of Mesozoic carbonate rocks, which constitute the main potential geothermal reservoir in central Italy. The waters of meteoric origin are heated at depth, as a consequence of anomalous heat flow in the region; these waters acquire a CO[sub 2]-rich rising gas phase, equilibrate with the reservoir rocks and, finally, assume their Ca--HCO[sub 3]--SO[sub 4] composition. If these waters discharge rapidly from the border fault systems of the Siena-Radicofani basin they maintain their original composition. If, instead, they emerge from the inner faults of the graben, their temperature and dissolved solids increase so that they become Na--Cl with a high content of NH[sub 4], and H[sub 3]BO[sub 3].

  12. Self-doped microphase separated block copolymer electrolyte

    DOE Patents [OSTI]

    Mayes, Anne M.; Sadoway, Donald R.; Banerjee, Pallab; Soo, Philip; Huang, Biying

    2002-01-01

    A polymer electrolyte includes a self-doped microphase separated block copolymer including at least one ionically conductive block and at least one second block that is immiscible in the ionically conductive block, an anion immobilized on the polymer electrolyte and a cationic species. The ionically conductive block provides a continuous ionically conductive pathway through the electrolyte. The electrolyte may be used as an electrolyte in an electrochemical cell.

  13. Poly(cyclohexylethylene)-block-poly(ethylene oxide) block polymers for metal oxide templating

    SciTech Connect (OSTI)

    Schulze, Morgan W.; Sinturel, Christophe

    2015-09-01

    A series of poly(cyclohexylethylene)-block-poly(ethylene oxide) (CEO) diblock copolymers were synthesized through tandem anionic polymerizations and heterogeneous catalytic hydrogenation. Solvent-annealed CEO diblock films were used to template dense arrays of inorganic oxide nanodots via simple spin coating of an inorganic precursor solution atop the ordered film. The substantial chemical dissimilarity of the two blocks enables (i) selective inclusion of the inorganic precursor within the PEO domain and (ii) the formation of exceptionally small feature sizes due to a relatively large interaction parameter estimated from mean-field analysis of the order–disorder transition temperatures of compositionally symmetric samples. UV/ozone treatment following incorporation produces an ordered arrangement of oxide nanodots and simultaneously removes the block polymer template. However, we report the smallest particles (6 ± 1 nm) templated from a selective precursor insertion method to date using a block polymer scaffold.

  14. Poly(cyclohexylethylene)-block-poly(ethylene oxide) block polymers for metal oxide templating

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schulze, Morgan W.; Sinturel, Christophe; Hillmyer, Marc A.

    2015-09-01

    A series of poly(cyclohexylethylene)-block-poly(ethylene oxide) (CEO) diblock copolymers were synthesized through tandem anionic polymerizations and heterogeneous catalytic hydrogenation. Solvent-annealed CEO diblock films were used to template dense arrays of inorganic oxide nanodots via simple spin coating of an inorganic precursor solution atop the ordered film. The substantial chemical dissimilarity of the two blocks enables (i) selective inclusion of the inorganic precursor within the PEO domain and (ii) the formation of exceptionally small feature sizes due to a relatively large interaction parameter estimated from mean-field analysis of the order–disorder transition temperatures of compositionally symmetric samples. UV/ozone treatment following incorporation produces anmore » ordered arrangement of oxide nanodots and simultaneously removes the block polymer template. However, we report the smallest particles (6 ± 1 nm) templated from a selective precursor insertion method to date using a block polymer scaffold.« less

  15. Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Department of Energy Categorical Exclusion Determination Form Program or Field Office: Energy Efficiency and Conservation Block Grant Program Project Title CA-City-Diamond Bar Location: City Diamond Bar CA American Recovery and Reinvestment Act: Proposed Action or Project Description 1) Install an approximately 50 kW, roof-mounted, solar photovoltaic system on the City Hall Building, 2) public outreach program, 3) signage installation - LED lighting, 4) ITS - signal

  16. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-004A ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-004A REVISION: THIS GUIDANCE HAS BEEN AMENDED ...

  17. Indian Community Development Block Grant Program Workshop - Seattle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Indian Community Development Block Grant Program Workshop - Seattle Indian Community Development Block Grant Program Workshop - Seattle May 18, 2016 9:00AM to 3:00PM PDT Seattle, ...

  18. Measurement of the Magnet Blocks for SSRF Insertion Devices

    SciTech Connect (OSTI)

    He Yongzhou; Zhang Jidong; Zhou Qiaogen; Qian Zhenmei; Li Yang

    2010-06-23

    Two in-vacuum undulators IVU25s and one elliptically polarized undulator EPU100 have been developed for SSRF. Two IVU25s with the same hybrid design contain about 640 Sm{sub 2}Co{sub 17} magnet blocks and the dimension of blocks is 65 Wx25 Hx9 D. The EPU100 of the APPLE-II type contains about 690 NdFeB magnet blocks with the dimension of 35 Wx35 Hx25 D. This paper describes the magnetic measurements of these magnet blocks with the Helmholtz coil measurement system for IVU25 magnet blocks and the Hall probe measurement system for EPU100 magnet blocks. The measured maximum magnetic moment deviation and the maximum angle deviation are less than {+-}1.0% and 1.1 deg. respectively both for Sm{sub 2}Co{sub 17} blocks and NdFeB blocks and satisfy the specifications of undulators.

  19. Solvothermal Thin Film Deposition of Electron Blocking Layers | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Solvothermal Thin Film Deposition of Electron Blocking Layers Home > Research > ANSER Research Highlights > Solvothermal Thin Film Deposition of Electron Blocking Layers

  20. Energy Efficiency and Conservation Block Grant Program | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Energy Efficiency and Conservation Block Grant Program Energy Efficiency and Conservation Block Grant Program With a grant from the Energy Department's Energy Efficiency and Conservation Block Grant Program, the community of Ocean View, Delaware, installed a carport-mounted solar array that is saving taxpayers money on town utility bills. | Photo courtesy of the Town of Ocean View. With a grant from the Energy Department's Energy Efficiency and Conservation Block Grant Program, the

  1. Guidance for Energy Efficiency and Conservation Block Grant Grantees on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Programs | Department of Energy Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs Provides general guidance to the U.S. Department of Energy's Energy Efficiency and Conservation Block Grant grantees on financing programs. Author: U.S. Department of Energy Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs (447.91

  2. Energy Efficiency and Conservation Block Grant Program Success Stories

    Broader source: Energy.gov [DOE]

    Energy Efficiency and Conservation Block Grant (EECBG) Program's success stories including news articles, EERE Successes and EERE Blog entries.

  3. About the Energy Efficiency and Conservation Block Grant Program |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » About the Energy Efficiency and Conservation Block Grant Program About the Energy Efficiency and Conservation Block Grant Program The Energy Efficiency and Conservation Block Grant (EECBG) Program's purpose was to reduce fossil fuel emissions and total energy use and create jobs by working with cities, counties, states, U.S. territories, and Indian tribes to implement and manage energy efficiency and

  4. Energy Efficiency and Conservation Block Grant Program Guidance |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » Energy Efficiency and Conservation Block Grant Program Guidance Energy Efficiency and Conservation Block Grant Program Guidance The Energy Efficiency and Conservation Block Grant (EECBG) Program released guidance documents that explain how the recipients of EECBG funds need to report and manage those funds. These documents are listed below by the year they were released. More program guidance documents are

  5. Energy Efficiency and Conservation Block Grant Program Success Stories |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Energy Efficiency & Conservation Block Grant Program » Energy Efficiency and Conservation Block Grant Program Success Stories Energy Efficiency and Conservation Block Grant Program Success Stories RSS Read Energy Efficiency and Conservation Block Grant Program success stories. August 25, 2014 Pictured here is one of the solar arrays that is providing New Bedford with clean, renewable energy to power its municipally owned buildings. This ground-mounted solar array is

  6. Organic photosensitive optoelectronic device having a phenanthroline exciton blocking layer

    DOE Patents [OSTI]

    Thompson, Mark E.; Li, Jian; Forrest, Stephen; Rand, Barry

    2011-02-22

    An organic photosensitive optoelectronic device, having an anode, a cathode, and an organic blocking layer between the anode and the cathode is described, wherein the blocking layer comprises a phenanthroline derivative, and at least partially blocks at least one of excitons, electrons, and holes.

  7. Building blocks for correlated superconductors and magnets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarrao, J. L.; Ronning, F.; Bauer, E. D.; Batista, C. D.; Zhu, J. -X.; Thompson, J. D.

    2015-04-01

    Recent efforts at Los Alamos to discover strongly correlated superconductors and hard ferromagnets are reviewed. While serendipity remains a principal engine of materials discovery, design principles and structural building blocks are beginning to emerge that hold potential for predictive discovery. Successes over the last decade with the so-called “115” strongly correlated superconductors are summarized, and more recent efforts to translate these insights and principles to novel hard magnets are discussed. While true “materials by design” remains a distant aspiration, progress is being made in coupling empirical design principles to electronic structure simulation to accelerate and guide materials design and synthesis.

  8. Building blocks for correlated superconductors and magnets

    SciTech Connect (OSTI)

    Sarrao, J. L.; Ronning, F.; Bauer, E. D.; Batista, C. D.; Zhu, J. -X.; Thompson, J. D.

    2015-04-01

    Recent efforts at Los Alamos to discover strongly correlated superconductors and hard ferromagnets are reviewed. While serendipity remains a principal engine of materials discovery, design principles and structural building blocks are beginning to emerge that hold potential for predictive discovery. Successes over the last decade with the so-called 115 strongly correlated superconductors are summarized, and more recent efforts to translate these insights and principles to novel hard magnets are discussed. While true materials by design remains a distant aspiration, progress is being made in coupling empirical design principles to electronic structure simulation to accelerate and guide materials design and synthesis.

  9. A reciprocating rotating-block engine

    SciTech Connect (OSTI)

    O`Connor, L.

    1995-06-01

    This article describes the Newbold power plant, a lightweight, clean burning, and efficient engine that is designed to be used in a variety of small-engine applications, from ultralight planes to wheelchairs. A new turbo rotary-power engine brings together different design concepts from engine technology, including the rotary motion of a block, which is applied in a rotary engine, and the reciprocating motion of pistons. The new power plant also uses an air delivery system that operates similar to a turbojet engine. The turbo rotary-power engine, developed by Vernon Newbold, founder of Newbold and Associates, in Lyons, CO, produces power from the heat generated by combustion of most liquid or gaseous fuels. Production engines, expected to be built in August, will be optimized to operate using diesel fuel.

  10. Organic photovoltaic cell incorporating electron conducting exciton blocking layers

    SciTech Connect (OSTI)

    Forrest, Stephen R.; Lassiter, Brian E.

    2014-08-26

    The present disclosure relates to photosensitive optoelectronic devices including a compound blocking layer located between an acceptor material and a cathode, the compound blocking layer including: at least one electron conducting material, and at least one wide-gap electron conducting exciton blocking layer. For example, 3,4,9,10 perylenetetracarboxylic bisbenzimidazole (PTCBI) and 1,4,5,8-napthalene-tetracarboxylic-dianhydride (NTCDA) function as electron conducting and exciton blocking layers when interposed between the acceptor layer and cathode. Both materials serve as efficient electron conductors, leading to a fill factor as high as 0.70. By using an NTCDA/PTCBI compound blocking layer structure increased power conversion efficiency is achieved, compared to an analogous device using a conventional blocking layers shown to conduct electrons via damage-induced midgap states.

  11. Poly(lactide)-block-poly([epsilon]-caprolactone-co-[epsilon]-decalactone)-block-poly(lactide) copolymer elastomers

    SciTech Connect (OSTI)

    Schneiderman, Deborah K.; Hill, Erin M.; Martello, Mark T.; Hillmyer, Marc A.

    2015-08-28

    Batch ring opening transesterification copolymerization of ?-caprolactone and ?-decalactone was used to generate statistical copolymers over a wide range of compositions and molar masses. Reactivity ratios determined for this monomer pair, rCL = 5.9 and rDL = 0.03, reveal ?-caprolactone is added preferentially regardless of the propagating chain end. Relative to poly(?-caprolactone) the crystallinity and melting point of these statistical copolymers were depressed by the addition of ?-decalactone; copolymers containing greater than 31 mol% (46 wt%) ?-decalactone were amorphous. Poly(lactide)-block-poly(?-caprolactone-co-?-decalactone)-block-poly(lactide) triblock polymers were also prepared and used to explore the influence of midblock composition on the temperature dependent Flory-Huggins interaction parameter (?). In addition, uniaxial extension tests were used to determine the effects of midblock composition, poly(lactide) content, and molar mass on the mechanical properties of these new elastomeric triblocks.

  12. Guidance For Energy Efficiency And Conservation Block Grant Grantees On

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Programs | Department of Energy For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs Guidance For Energy Efficiency And Conservation Block Grant Grantees On Financing Programs U.S. Department of Energy (DOE) Weatherization and Intergovernmental Program (WIP) Energy Efficiency and Conservation Block Grant (EECBG) Program Notice 09-002D modified October 17, 2012 that provides guidance about financing programs for state and local governments, overseas U.S.

  13. Guidance for Energy Efficiency and Conservation Block Grant Recipients on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Evaluation Guidelines | Department of Energy for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency and Conservation Block Grant Program grantees on planning and conducting program evaluations on Recovery Act funded EECBG programs and activities eecbg_evaluation_guidelines_10_017.pdf (184.79 KB) More Documents

  14. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. | Department of Energy GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. GUIDANCE FOR ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT RECIPIENTS ON CLOSEOUT PROCEDURES FOR NON-STATE ENERGY OFFICE RECIPIENTS. This document provides guidance for energy efficiency and block grant recipients on closeout procedures for non-state energy office recipients.

  15. State Energy Program and Energy Efficiency and Conservation Block Grant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Guidance 13-001: Guidance for Returning Interest Earned | Department of Energy and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned State Energy Program and Energy Efficiency and Conservation Block Grant Program Guidance 13-001: Guidance for Returning Interest Earned U.S. Department of Energy (DOE) State Energy Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program guidance document for returning

  16. Energy Efficiency and Conservation Block Grant Financing Program Guidance |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Guidance Energy Efficiency and Conservation Block Grant Financing Program Guidance Relevant guidance for Energy Efficiency and Conservation Block Grant financing programs is provided below in the Grantee Letter and supporting appendices listed here. Appendix 1: EECBG Financing Program Annual Report (372.67 KB) Appendix 2: EECBG Program Notice 09-002D Guidance for Energy Efficiency and Conservation Block Grant Grantees on Financing Programs, revised October 17, 2012

  17. Energy Efficiency and Consveration Block Grant Program National Evaluation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet | Department of Energy and Consveration Block Grant Program National Evaluation Fact Sheet Energy Efficiency and Consveration Block Grant Program National Evaluation Fact Sheet This fact sheet provides summarized results of the National Evaluation of the Energy Efficiency and Conservation Block Grant Program, a national program funded one-time under the American Recovery and Reinvestment Act of 2009. Fact Sheet (477.88 KB) More Documents & Publications Energy Efficiency and

  18. Update on Energy Efficiency and Conservation Block Grant Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Allocations | Department of Energy Update on Energy Efficiency and Conservation Block Grant Program Allocations Update on Energy Efficiency and Conservation Block Grant Program Allocations April 10, 2009 - 12:00am Addthis After a review of eligibility criteria for the Department of Energy's Energy Efficiency and Conservation Block Grant Program, $16,429,000 in additional funding will go to 23 counties in Delaware, Kansas, and Louisiana to support energy efficiency projects. Delaware counties

  19. Block copolymer adhesion promoters via ring-opening metathesis polymerization

    DOE Patents [OSTI]

    Kent, Michael S.; Saunders, Randall

    1997-01-01

    Coupling agents based on functionalized block copolymers for bonding thermoset polymers to solid materials. These are polymers which possess at least two types of functional groups, one which is able to attach to and react with solid surfaces, and another which can react with a thermoset resin, which are incorporated as pendant groups in monomers distributed in blocks (typically two) along the backbone of the chain. The block copolymers in this invention are synthesized by living ring-opening metathesis polymerization.

  20. Energy Efficiency and Conservation Block Grant Financing Programs After

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grant Retirement | Department of Energy Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement Energy Efficiency and Conservation Block Grant Financing Programs After Grant Retirement July 15, 2014 - 12:12pm Addthis The information below will help you manage successful Energy Efficiency and Conservation Block Grant (EECBG) financing programs: July 2014 Letter to EECBG Financing Program Managers. This document: Clarifies DOE's ongoing role in monitoring,

  1. Crystal Engineering on Superpolyhedral Building Blocks in Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Superpolyhedral Building Blocks in Metal-Organic Frameworks Applied in Gas Adsorption. Acta Crystallogr., Sect. B: Struct. Sci., Cryst. Eng. Mater., 71, 613-618 (2015). DOI:...

  2. State Energy Program and Energy Efficiency and Conservation Block...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program (SEP) and Energy Efficiency and Conservation Block Grant (EECBG) Program guidance document for returning interest earned; Program year 2013. PDF icon sepeecbg13001...

  3. Microsoft Word - Final Dec 4 Annncmnt of Agg Blocks Adjustmnt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aggregate Blocks and Prepayments BPA will Accept for Prepayment Program, the Adjustment Cap, Market Clearing Purchase Price, and Reservation Price Background Pursuant to Paragraph...

  4. Structural response of a prealigned cylindrical block copolymer...

    Office of Scientific and Technical Information (OSTI)

    melt to extensional flow Citation Details In-Document Search Title: Structural response of a prealigned cylindrical block copolymer melt to extensional flow Authors: McCready, ...

  5. Net Requirements Transparency Process for Slice/Block Customers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 2012 Net Requirements Transparency Process for SliceBlock Customers Description of Changes and a Response to Comments September 24, 2012 Background and Description of Changes:...

  6. NREL: Concentrating Solar Power Research - Power Block R&D

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power block research at NREL focuses on assessing the potential of advanced power cycles to integrate with concentrating solar power (CSP) systems. This research increases the ...

  7. Guidance for Energy Efficiency and Conservation Block Grant Recipients...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency and Conservation Block Grant Recipients on Program Evaluation Guidelines Guidance for Energy Efficiency ...

  8. Energy.gov Content Management System Block Types

    Broader source: Energy.gov [DOE]

    For Office of Energy Efficiency and Renewable Energy (EERE) websites, learn about the variety of block types available in the Energy.gov Drupal content management system (CMS).

  9. Association of a Multifunctional Ionic Block Copolymer in a Selective...

    Office of Scientific and Technical Information (OSTI)

    Results Journal Article: Association of a Multifunctional Ionic Block Copolymer in a Selective Solvent. Citation Details ... Publication Date: 2014-04-01 OSTI Identifier: 1143261 Report ...

  10. Energy Efficiency and Conservation Block Grant Program Success...

    Broader source: Energy.gov (indexed) [DOE]

    RSS Read Energy Efficiency and Conservation Block Grant Program success stories. August ... New Bedford with clean, renewable energy to power its municipally owned buildings. ...

  11. City of Los Angeles  Energy Efficiency and Conservation Block...

    Office of Environmental Management (EM)

    City of Los Angeles - Energy Efficiency and Conservation Block Grant Program Funds Provided by the ... use of faulty data in its compilation of Recovery Act job statistics. ...

  12. County of Los Angeles Energy Efficiency and Conservation Block...

    Broader source: Energy.gov (indexed) [DOE]

    County of Los Angeles - Energy Efficiency and Conservation Block Grant Program Funds Provided by the ... utilized by the Department in its compilation of Recovery Act job statistics. ...

  13. Germanium blocked impurity band infrared detectors

    SciTech Connect (OSTI)

    Rossington, C.S.; Haller, E.E.

    1988-08-01

    Germanium blocked impurity band (BIB) photoconductors have been fabricated and characterized for responsivity, dark current, and noise equivalent power. BIB photoconductors theoretically provide an extension of the spectral response, a reduction in sensitivity to cosmic radiation and a reduction in noise characteristics compared with conventional photoconductors. Silicon BIB detectors have been successfully developed by researchers at Rockwell International, which do indeed meet their theoretical potential. In the proper configuration, these same Si BIB detectors are capable of continuous detection of individual photons in the wavelength range from 0.4 to 28 ..mu..m. Until the BIB concept was developed, detection of individual photons was only possible with photomultiplier tubes which detected visible light. Due to the successes of the Si BIB detectors, it seemed natural to extend this concept to Ge detectors, which would then allow an extension of the spectral response over conventional Ge detectors from /approximately/100 ..mu..m to /approximately/200 ..mu..m. 8 refs., 2 figs.

  14. Molecular origin of photovoltaic performance in donor-block-acceptor all-conjugated block copolymers

    SciTech Connect (OSTI)

    Smith, Kendall A.; Lin, Yen -Hao; Mok, Jorge W.; Yager, Kevin G.; Strzalka, Joseph; Nie, Wanyi; Mohite, Aditya D.; Verduzco, Rafael

    2015-11-03

    All-conjugated block copolymers may be an effective route to self-assembled photovoltaic devices, but we lack basic information on the relationship between molecular characteristics and photovoltaic performance. Here, we synthesize a library of poly(3-hexylthiophene) (P3HT) block poly((9,9-dialkylfluorene)-2,7-diyl-alt-[4,7-bis(alkylthiophen-5-yl)-2,1,3-benzothiadiazole]-2',2''-diyl) (PFTBT) donor-block-acceptor all-conjugated block copolymers and carry out a comprehensive study of processing conditions, crystallinity, domain sizes, and side-chain structure on photovoltaic device performance. We find that all block copolymers studied exhibit an out-of-plane crystal orientation after deposition, and on thermal annealing at high temperatures the crystal orientation flips to an in-plane orientation. By varying processing conditions on polymer photovoltaic devices, we show that the crystal orientation has only a modest effect (15-20%) on photovoltaic performance. The addition of side-chains to the PFTBT block is found to decrease photovoltaic power conversion efficiencies by at least an order of magnitude. Through grazing-incidence X-ray measurements we find that the addition of side-chains to the PFTBT acceptor block results in weak segregation and small (< 10 nm) block copolymer self-assembled donor and acceptor domains. This work is the most comprehensive to date on all-conjugated block copolymer systems and suggests that photovoltaic performance of block copolymers depends strongly on the miscibility of donor and acceptor blocks, which impacts donor and acceptor domain sizes and purity. Lastly, strategies for improving the device performance of block copolymer photovoltaics should seek to increase segregation between donor and acceptor polymer domains.

  15. Modeling Mechanical Behavior of a Prismatic Replaceable Reflector Block

    SciTech Connect (OSTI)

    Robert Bratton

    2009-04-01

    This report outlines the development of finite element models used to determine temperature and stresses in a prismatic core reflector block. This initial analysis determines an appropriate temperature distribution in a prismatic reflector from limiting conditions in the adjacent fuel block based on simplifying assumptions.

  16. Automatic Blocking Of QR and LU Factorizations for Locality

    SciTech Connect (OSTI)

    Yi, Q; Kennedy, K; You, H; Seymour, K; Dongarra, J

    2004-03-26

    QR and LU factorizations for dense matrices are important linear algebra computations that are widely used in scientific applications. To efficiently perform these computations on modern computers, the factorization algorithms need to be blocked when operating on large matrices to effectively exploit the deep cache hierarchy prevalent in today's computer memory systems. Because both QR (based on Householder transformations) and LU factorization algorithms contain complex loop structures, few compilers can fully automate the blocking of these algorithms. Though linear algebra libraries such as LAPACK provides manually blocked implementations of these algorithms, by automatically generating blocked versions of the computations, more benefit can be gained such as automatic adaptation of different blocking strategies. This paper demonstrates how to apply an aggressive loop transformation technique, dependence hoisting, to produce efficient blockings for both QR and LU with partial pivoting. We present different blocking strategies that can be generated by our optimizer and compare the performance of auto-blocked versions with manually tuned versions in LAPACK, both using reference BLAS, ATLAS BLAS and native BLAS specially tuned for the underlying machine architectures.

  17. Light-emitting block copolymers composition, process and use

    DOE Patents [OSTI]

    Ferraris, John P.; Gutierrez, Jose J.

    2006-11-14

    Generally, and in one form, the present invention is a composition of light-emitting block copolymer. In another form, the present invention is a process producing a light-emitting block copolymers that intends polymerizing a first di(halo-methyl) aromatic monomer compound in the presence of an anionic initiator and a base to form a polymer and contacting a second di(halo-methyl) aromatic monomer compound with the polymer to form a homopolymer or block copolymer wherein the block copolymer is a diblock, triblock, or star polymer. In yet another form, the present invention is an electroluminescent device comprising a light-emitting block copolymer, wherein the electroluminescent device is to be used in the manufacturing of optical and electrical devices.

  18. NANOSTRUCTURED METAL OXIDE CATALYSTS VIA BUILDING BLOCK SYNTHESES

    SciTech Connect (OSTI)

    Craig E. Barnes

    2013-03-05

    A broadly applicable methodology has been developed to prepare new single site catalysts on silica supports. This methodology requires of three critical components: a rigid building block that will be the main structural and compositional component of the support matrix; a family of linking reagents that will be used to insert active metals into the matrix as well as cross link building blocks into a three dimensional matrix; and a clean coupling reaction that will connect building blocks and linking agents together in a controlled fashion. The final piece of conceptual strategy at the center of this methodology involves dosing the building block with known amounts of linking agents so that the targeted connectivity of a linking center to surrounding building blocks is obtained. Achieving targeted connectivities around catalytically active metals in these building block matrices is a critical element of the strategy by which single site catalysts are obtained. This methodology has been demonstrated with a model system involving only silicon and then with two metal-containing systems (titanium and vanadium). The effect that connectivity has on the reactivity of atomically dispersed titanium sites in silica building block matrices has been investigated in the selective oxidation of phenols to benezoquinones. 2-connected titanium sites are found to be five times as active (i.e. initial turnover frequencies) than 4-connected titanium sites (i.e. framework titanium sites).

  19. Block copolymer adhesion promoters via ring-opening metathesis polymerization

    DOE Patents [OSTI]

    Kent, M.S.; Saunders, R.

    1997-02-18

    Coupling agents are disclosed based on functionalized block copolymers for bonding thermoset polymers to solid materials. These are polymers which possess at least two types of functional groups, one which is able to attach to and react with solid surfaces, and another which can react with a thermoset resin, which are incorporated as pendant groups in monomers distributed in blocks (typically two) along the backbone of the chain. The block copolymers in this invention are synthesized by living ring-opening metathesis polymerization. 18 figs.

  20. Bulk Vitrification Castable Refractory Block Protection Study

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Beck, Andrew E.; Brouns, Thomas M.; Caldwell, Dustin D.; Elliott, Michael L.; Matyas, Josef; Minister, Kevin BC; Schweiger, Michael J.; Strachan, Denis M.; Tinsley, Bronnie P.; Hollenberg, Glenn W.

    2005-05-01

    Bulk vitrification (BV) was selected for a pilot-scale test and demonstration facility for supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the Hanford U.S. DOE Site. During engineering-scale (ES) tests, a small fraction of radioactive Tc (and Re, its nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the castable refractory block (CRB). Laboratory experiments were undertaken to understand the mechanisms of the transport Tc/Re into the CRB during vitrification and to evaluate various means of CRB protection against the deposition of leachable Tc/Re. The tests used Re as a chemical surrogate for Tc. The tests with the baseline CRB showed that the molten LAW penetrates into CRB pores before it converts to glass, leaving deposits of sulfates and chlorides when the nitrate components decompose. Na2O from the LAW reacts with the CRB to create a durable glass phase that may contain Tc/Re. Limited data from a single CRB sample taken from an ES experiment indicate that, while a fraction of Tc/Re is present in the CRB in a readily leachable form, most of the Tc/Re deposited in the refractory is retained in the form of a durable glass phase. In addition, the molten salts from the LAW, mainly sulfates, chlorides, and nitrates, begin to evaporate from BV feeds at temperatures below 800 C and condense on solid surfaces at temperatures below 530 C. Three approaches aimed at reducing or preventing the deposition of soluble Tc/Re within the CRB were proposed: metal lining, sealing the CRB surface with a glaze, and lining the CRB with ceramic tiles. Metal liners were deemed unsuitable because evaluations showed that they can cause unacceptable distortions of the electric field in the BV system. Sodium silicate and a low-alkali borosilicate glaze were selected for testing. The glazes slowed down molten salt condensate penetration, but did little to reduce the

  1. Square Grains in Asymmetric Rod-Coil Block Copolymers (Journal...

    Office of Scientific and Technical Information (OSTI)

    Unlike the rounded grains that are well known to form in most soft materials, square grains of microphase-separated lamellae are observed in thin films of a rod-coil block ...

  2. Virasoro conformal blocks and thermality from classical background fields

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fitzpatrick, A. Liam; Kaplan, Jared; Walters, Matthew T.

    2015-11-30

    We show that in 2d CFTs at large central charge, the coupling of the stress tensor to heavy operators can be re-absorbed by placing the CFT in a non-trivial background metric. This leads to a more precise computation of the Virasoro conformal blocks between heavy and light operators, which are shown to be equivalent to global conformal blocks evaluated in the new background. We also generalize to the case where the operators carry U(1) charges. The refined Virasoro blocks can be used as the seed for a new Virasoro block recursion relation expanded in the heavy-light limit. Furthermore, we commentmore » on the implications of our results for the universality of black hole thermality in AdS3 , or equivalently, the eigenstate thermalization hypothesis for CFT2 at large central charge.« less

  3. Indian Community Development Block Grant Program Workshop- Seattle

    Broader source: Energy.gov [DOE]

    The U.S. Department of Housing and Urban Development (HUD) Southwest Office of Native American Programs is conducting this training workshop to assist applicants with the Indian Community Development Block Grant Program.

  4. Energy Efficiency and Conservation Block Grant Program Success...

    Broader source: Energy.gov (indexed) [DOE]

    like this will grace Gabe Nesbitt Community Park in McKinney, Texas, thanks to an Energy Efficiency and Conservation Block Grant | Photo courtesy of McKinney, Texas EECBG...

  5. Reordering transitions during annealing of block copolymer cylinder phases

    SciTech Connect (OSTI)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-10-06

    While equilibrium block-copolymer morphologies are dictated by energy-minimization effects, the semi-ordered states observed experimentally often depend on the details of ordering pathways and kinetics. In this study, we explore reordering transitions in thin films of block-copolymer cylinder-forming polystyrene-block-poly(methyl methacrylate). We observe several transient states as films order towards horizontally-aligned cylinders. In particular, there is an early-stage reorganization from randomly-packed cylinders into hexagonally-packed vertically-aligned cylinders; followed by a reorientation transition from vertical to horizontal cylinder states. These transitions are thermally activated. The growth of horizontal grains within an otherwise vertical morphology proceeds anisotropically, resulting in anisotropic grains in the final horizontal state. The size, shape, and anisotropy of grains are influenced by ordering history; for instance, faster heating rates reduce grain anisotropy. These results help elucidate aspects of pathway-dependent ordering in block-copolymer thin films.

  6. Microsoft Word - Posted DSI Amendment of Alcoa Block Power Sales...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No. 1 Contract No. 06PB-11744 DRAFT AMENDMENT executed by the BONNEVILLE POWER ADMINISTRATION and ALCOA INC. This AMENDMENT to the BLOCK POWER SALES AGREEMENT is executed by the...

  7. Energy Efficiency and Conservation Block Grant Financing Program Guidance

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grantee Letter | Department of Energy Guidance Grantee Letter Energy Efficiency and Conservation Block Grant Financing Program Guidance Grantee Letter This document clarifies the U.S. Department of Energy's ongoing role in the monitoring, reporting, and oversight of Energy Efficiency and Conservation Block Grant-funded financing programs, including Revolving Loan Funds, Loan Loss Reserves, and Interest Rate Buydowns. July 2014 Letter to EECGB Financing Program Managers (256.42 KB) More

  8. Big Questions: The Ultimate Building Blocks of Matter

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07

    The Standard Model of particle physics treats quarks and leptons as having no size at all. Quarks are found inside protons and neutrons and the most familiar lepton is the electron. While the best measurements to date support that idea, there is circumstantial evidence that suggests that perhaps the these tiny particles might be composed of even smaller building blocks. This video explains this circumstantial evidence and introduces some very basic ideas of what those building blocks might be.

  9. Lower Cost, Nanoporous Block Copolymer Battery Separator - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Lower Cost, Nanoporous Block Copolymer Battery Separator Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication A.K. Jha, S.L. Tsang, A.E. Ozcam, R.D. Offeman, N.P. Balsara. "Master Curve Captures the Effect of Domain Morphology on Ethanol Pervaporation Through Block Copolymer Membranes," Journal of Membrane Science, published online, 2011. (695 KB) Technology Marketing Summary Although the polyolefin polymer

  10. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Wednesday, 27 January 2010 00:00 Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the

  11. Frequently Asked Questions on Energy Efficiency and Conservation Block

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Grant Financing Program Compliance and Reporting | Department of Energy Frequently Asked Questions on Energy Efficiency and Conservation Block Grant Financing Program Compliance and Reporting Frequently Asked Questions on Energy Efficiency and Conservation Block Grant Financing Program Compliance and Reporting Find answers to frequently asked questions (FAQs) regarding financing program reporting and compliance for programs developed using U.S. Department of Energy (DOE) Energy Efficiency

  12. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print Wednesday, 30 May 2012 00:00 In principle, tri-block copolymers...

  13. Department of Energy Awards $300,000 Block Grant to the Rocky...

    Broader source: Energy.gov (indexed) [DOE]

    Block Grant to the Rocky Flats Community Reuse Organization Department of Energy Awards 300,000 Block Grant to the Rocky Flats Community Reuse Organization More Documents &...

  14. Tobacco mosaic virus: A biological building block for micro/nano...

    Office of Scientific and Technical Information (OSTI)

    Tobacco mosaic virus: A biological building block for micronanobio systems Citation Details In-Document Search Title: Tobacco mosaic virus: A biological building block for micro...

  15. Morphological studies on block copolymer modified PA 6 blends

    SciTech Connect (OSTI)

    Poindl, M. E-mail: christian.bonten@ikt.uni-stuttgart.de; Bonten, C. E-mail: christian.bonten@ikt.uni-stuttgart.de

    2014-05-15

    Recent studies show that compounding polyamide 6 (PA 6) with a PA 6 polyether block copolymers made by reaction injection molding (RIM) or continuous anionic polymerization in a reactive extrusion process (REX) result in blends with high impact strength and high stiffness compared to conventional rubber blends. In this paper, different high impact PA 6 blends were prepared using a twin screw extruder. The different impact modifiers were an ethylene propylene copolymer, a PA PA 6 polyether block copolymer made by reaction injection molding and one made by reactive extrusion. To ensure good particle matrix bonding, the ethylene propylene copolymer was grafted with maleic anhydride (EPR-g-MA). Due to the molecular structure of the two block copolymers, a coupling agent was not necessary. The block copolymers are semi-crystalline and partially cross-linked in contrast to commonly used amorphous rubbers which are usually uncured. The combination of different analysis methods like atomic force microscopy (AFM), transmission electron microscopy (TEM) and scanning electron microscopy (SEM) gave a detailed view in the structure of the blends. Due to the partial cross-linking, the particles of the block copolymers in the blends are not spherical like the ones of ethylene propylene copolymer. The differences in molecular structure, miscibility and grafting of the impact modifiers result in different mechanical properties and different blend morphologies.

  16. Lignin-blocking treatment of biomass and uses thereof

    DOE Patents [OSTI]

    Yang, Bin; Wyman, Charles E.

    2009-10-20

    Disclosed is a method for converting cellulose in a lignocellulosic biomass. The method provides for a lignin-blocking polypeptide and/or protein treatment of high lignin solids. The treatment enhances cellulase availability in cellulose conversion. Cellulase efficiencies are improved by the protein or polypeptide treatment. The treatment may be used in combination with steam explosion and acid prehydrolysis techniques. Hydrolysis yields from lignin containing biomass are enhanced 5-20%, and enzyme utilization is increased from 10% to 50%. Thus, a more efficient and economical method of processing lignin containing biomass materials utilizes a polypeptide/protein treatment step that effectively blocks lignin binding of cellulase.

  17. Electrically conductive doped block copolymer of polyacetylene and polyisoprene

    DOE Patents [OSTI]

    Aldissi, Mahmoud

    1985-01-01

    An electrically conductive block copolymer of polyisoprene and polyacetyl and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I.sub.2 to give it an electrical conductivity in the metallic regime.

  18. Preliminary survey of tuff distribution in Esmeralda, Nye, and Lincoln Counties, Nevada

    SciTech Connect (OSTI)

    Smith, G.V.; Pink, T.S.; Lawrence, J.R.; Woodward, L.A.; Keil, K.; Lappin, A.R.

    1981-02-01

    This report inventories the surface distribution of silicic tuffs in Nye, Esmeralda, and Lincoln Counties, NV, based on a review of available literature. The inventory was taken to provide a data base in evaluating tuff sites for the disposal of high-level nuclear waste. Silicic ash-flow tuffs that are about 11 to 34 million years (my) old are widespread in these counties. These rocks are locally deformed by right-lateral movement along Walker Lane and the Las Vegas Shear Zone, and left-lateral movement along a zone from near the Nevada Test Site (NTS) to the Utah border, and are commonly offset by steeply dipping normal faults. The normal faults that bound horsts, grabens, and tilted-fault blocks of the Basin-and-Range Province began to form 30 my ago; some are still active. Tuff distribution is discussed on a regional basis. Tuff thicknesses and alterations, structural complexity, and proximity to recent faulting, recent volcanism, and mineral resources are discussed for each area. Although the literature on which it is based is often incomplete and sketchy, this report is intended to serve as a basis for future, more detailed work that includes initial field inspection, detailed field and laboratory studies, and extrapolations to the subsurface.

  19. Energy Efficiency and Conservation Block Grant Program Fact Sheet

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s (DOE) Energy Efficiency and Conservation Block Grant (EECBG) program represents a Presidential priority to invest in the cheapest, cleanest and most reliable energy technologies we have – energy efficiency and conservation – which can be deployed immediately.

  20. Reordering transitions during annealing of block copolymer cylinder phases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-10-06

    While equilibrium block-copolymer morphologies are dictated by energy-minimization effects, the semi-ordered states observed experimentally often depend on the details of ordering pathways and kinetics. In this study, we explore reordering transitions in thin films of block-copolymer cylinder-forming polystyrene-block-poly(methyl methacrylate). We observe several transient states as films order towards horizontally-aligned cylinders. In particular, there is an early-stage reorganization from randomly-packed cylinders into hexagonally-packed vertically-aligned cylinders; followed by a reorientation transition from vertical to horizontal cylinder states. These transitions are thermally activated. The growth of horizontal grains within an otherwise vertical morphology proceeds anisotropically, resulting in anisotropic grains in the final horizontalmore » state. The size, shape, and anisotropy of grains are influenced by ordering history; for instance, faster heating rates reduce grain anisotropy. These results help elucidate aspects of pathway-dependent ordering in block-copolymer thin films.« less

  1. Manipulating Interfaces through Surface Confinement of Poly(glycidyl methacrylate)-block-poly(vinyldimethylazlactone), a Dually Reactive Block Copolymer

    SciTech Connect (OSTI)

    Lokitz, Bradley S; Wei, Jifeng; Hinestrosa Salazar, Juan P; Ivanov, Ilia N; Browning, James B; Ankner, John Francis; Kilbey, II, S Michael; Messman, Jamie M

    2012-01-01

    The assembly of dually reactive, well-defined diblock copolymers incorporating the chemoselective/functional monomer, 4,4-dimethyl-2-vinylazlactone (VDMA) and the surface-reactive monomer glycidyl methacrylate (GMA) is examined to understand how competition between surface attachment and microphase segregation influences interfacial structure. Reaction of the PGMA block with surface hydroxyl groups not only anchors the copolymer to the surface, but limits chain mobility, creating brush-like structures comprising PVDMA blocks, which contain reactive azlactone groups. The block copolymers are spin coated at various solution concentrations and annealed at elevated temperature to optimize film deposition to achieve a molecularly uniform layer. The thickness and structure of the polymer thin films are investigated by ellipsometry, infrared spectroscopy, and neutron reflectometry. The results show that deposition of PGMA-b-PVDMA provides a useful route to control film thickness while preserving azlactone groups that can be further modified with biotin-poly(ethylene glycol)amine to generate designer surfaces. The method described herein offers guidance for creating highly functional surfaces, films, or coatings through the use of dually reactive block copolymers and postpolymerization modification.

  2. Method of forming oriented block copolymer line patterns, block copolymer line patterns formed thereby, and their use to form patterned articles

    DOE Patents [OSTI]

    Russell, Thomas P.; Hong, Sung Woo; Lee, Doug Hyun; Park, Soojin; Xu, Ting

    2015-10-13

    A block copolymer film having a line pattern with a high degree of long-range order is formed by a method that includes forming a block copolymer film on a substrate surface with parallel facets, and annealing the block copolymer film to form an annealed block copolymer film having linear microdomains parallel to the substrate surface and orthogonal to the parallel facets of the substrate. The line-patterned block copolymer films are useful for the fabrication of magnetic storage media, polarizing devices, and arrays of nanowires.

  3. Periodic nanostructures from self assembled wedge-type block-copolymers

    DOE Patents [OSTI]

    Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.; Weitekamp, Raymond; Miyake, Garret M.; Piunova, Victoria; Daeffler, Christopher Scot

    2015-06-02

    The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.

  4. Blocked impurity band hybrid infrared focal plane arrays for astronomy

    SciTech Connect (OSTI)

    Reynolds, D.B.; Seib, D.H.; Stetson, S.B.; Herter, T.; Rowlands, N.; Schoenwald, J.

    1989-02-01

    High-performance infrared hybrid focal plane arrays using 10 x 50 element Si:As Blocked-Impurity-Band (BIB) detectors (cut-off wavelength = 28 ..mu..m) and matching switched MOSFET multiplexers have been developed and characterized for space astronomy. Use of impurity band conduction technology provides detectors which are nuclear radiation hard and free of the many anomalies associated with conventional silicon photoconductive detectors. Emphasis in this paper is on recent advances in detector material quality which have led to significantly improved detector and hybrid characteristics. Results demonstrating increase quantum efficiency (particular at short wavelength infrared), obtained by varying the Blocked-Impurity-Band detector properties (infrared active layer thickness and arsenic doping profile), are summarized. Read noise and dark current for different temperatures have been measured and are also described. The hybrid array performance achieved clearly demonstrates that BIB detectors are well suited for use in astronomical instrumentation.

  5. Magnetic alignment of block copolymer microdomains by intrinsic chain anisotropy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rokhlenko, Yekaterina; Yager, Kevin G.; Gopinadhan, Manesh; Osuji, Chinedum O.; Zhang, Kai; O'Hern, Corey S.; Larson, Steven R.; Gopalan, Padma; Majewski, Pawel W.

    2015-12-18

    We examine the role of intrinsic chain susceptibility anisotropy in magnetic field directed self-assembly of a block copolymer using in situ x-ray scattering. Alignment of a lamellar mesophase is observed on cooling across the disorder-order transition with the resulting orientational order inversely proportional to the cooling rate. We discuss the origin of the susceptibility anisotropy, Δχ, that drives alignment and calculate its magnitude using coarse-grained molecular dynamics to sample conformations of surface-tethered chains, finding Δχ ≈ 2×10–8. From field-dependent scattering data, we estimate that grains of ≈ 1.2 μm are present during alignment. Furthermore, these results demonstrate that intrinsic anisotropymore » is sufficient to support strong field-induced mesophase alignment and suggest a versatile strategy for field control of orientational order in block copolymers.« less

  6. Reflectivity studies on adsorbed block copolymers under shear

    SciTech Connect (OSTI)

    Smith, G.S.; Wages, S.; Baker, S.M.; Toprakcioglu, C.; Hadziioannou, G.

    1994-12-01

    The authors report neutron reflectivity data on (poly)styrene-(poly)ethylene oxide (PS-PEO) diblock copolymers adsorbed onto quartz from the selective solvent cyclohexane (a non-solvent for PEO and a poor solvent for PS). The PEO ``anchor block`` adsorbs strongly to form a thin layer on the quartz substrate, while the deuterated PS chains dangle into the solvent. They find that under static conditions the density profile of the PS block in a poor solvent can be well described by a Schultz function which is indicative of a polymer ``mushroom.`` Furthermore, they have studied the same system under shear at shear rates from 0--400s{sup {minus}1}. They find that there is a dramatic increase in the thickness of the PS layer under shear in cyclohexane and that the relaxation time from the shear-on profile back to the static profile is on the order of several days.

  7. Magnetic alignment of block copolymer microdomains by intrinsic chain anisotropy

    SciTech Connect (OSTI)

    Rokhlenko, Yekaterina; Yager, Kevin G.; Gopinadhan, Manesh; Osuji, Chinedum O.; Zhang, Kai; O'Hern, Corey S.; Larson, Steven R.; Gopalan, Padma; Majewski, Pawel W.

    2015-12-18

    We examine the role of intrinsic chain susceptibility anisotropy in magnetic field directed self-assembly of a block copolymer using in situ x-ray scattering. Alignment of a lamellar mesophase is observed on cooling across the disorder-order transition with the resulting orientational order inversely proportional to the cooling rate. We discuss the origin of the susceptibility anisotropy, Δχ, that drives alignment and calculate its magnitude using coarse-grained molecular dynamics to sample conformations of surface-tethered chains, finding Δχ ≈ 2×10–8. From field-dependent scattering data, we estimate that grains of ≈ 1.2 μm are present during alignment. Furthermore, these results demonstrate that intrinsic anisotropy is sufficient to support strong field-induced mesophase alignment and suggest a versatile strategy for field control of orientational order in block copolymers.

  8. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  9. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  10. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  11. EIS-0006: Wind Turbine Generator System, Block Island, Rhode Island

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this EIS to evaluate the environmental impacts of installing and operating a large experimental wind turbine, designated the MOD-OA, which is proposed to be installed on a knoll in Rhode Island's New Meadow Hill Swamp, integrated with the adjacent Block Island Power Company power plant and operated to supply electricity to the existing utility network.

  12. Directed Spontaneous Assembly of Membrane Protein with Amphiphilic Block

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copolymers - Energy Innovation Portal Directed Spontaneous Assembly of Membrane Protein with Amphiphilic Block Copolymers Colorado School of Mines Contact CSM About This Technology Technology Marketing SummaryThis invention describes a method for using membrane proteins (MPs) in synthetic systems for biosensor design, high-throughput drug-screening, catalysis or energy harvesting. DescriptionCurrent efforts in the art face a challenge that practical applications involving liposomes have been

  13. Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrolytes - Joint Center for Energy Storage Research January 13, 2015, Research Highlights Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer Electrolytes (Top) The addition of 2 wt% nanoparticles (SEO-LiTFSI-POSS-2) results in an increase in ionic conductivity. STEM images show the bicontinuous morphology of the electrolyte with 2 wt% of nanoparticles. (Bottom) The value of morphology factor, f, for SEO-LiTFSI-POSS-2 is close to unity, the value expected for an

  14. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  15. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  16. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  17. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  18. Proton Channel Orientation in Block-Copolymer Electrolyte Membranes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proton Channel Orientation in Block-Copolymer Electrolyte Membranes Print Fuel cells have the potential to provide power for a wide variety of applications ranging from electronic devices to transportation vehicles. Cells operating with H2 and air as inputs and electric power and water as the only outputs are of particular interest because of their ability to produce power without degrading the environment. Polymer electrolyte membranes (PEMs), with hydrophilic, proton-conducting channels

  19. Pauli blocking in the nuclear medium π N transition matrix

    SciTech Connect (OSTI)

    Moniz, Ernest J.; Sevgen, A.

    1981-07-01

    We give an analytic expression for the in-medium nonstatic πN transition matrix in nuclear matter. Pauli blocking and spreading effects are included explicitly. Spin-flip terms are retained. We discuss the modifications of the free-space amplitude as a function of energy and density and show that large dynamical isospin effects are expected in pion scattering on heavy nuclei.

  20. ISU offering Financial Building Blocks sessions | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ISU offering Financial Building Blocks sessions Money is often considered the number one stressor. Your relationships, focus, safety and physical health may be impacted. Reduce the stress in your life by getting your finances under control. Build your financial knowledge and your skills. Iowa State University is offering five sessions geared towards informing employees how to build a sound financial future. The sessions will be presented by Brian Hood, a CFP from the Legacy Financial Group. As a

  1. Radical-cured block copolymer-modified thermosets

    SciTech Connect (OSTI)

    Redline, Erica M.; Francis, Lorraine F.; Bates, Frank S.

    2013-01-10

    Poly(ethylene-alt-propylene)-b-poly(ethylene oxide) (PEP-PEO) diblock copolymers were synthesized and added at 4 wt % to 2,2-bis[4-(2-hydroxy-3-methacryloxypropoxy)phenyl]propane (BisGMA), a monomer that cures using free radical chemistry. In separate experiments, poly(ethylene glycol) dimethacrylate (PEGDMA) was combined as a secondary monomer with BisGMA and the monomers were loaded with 4 wt % PEP-PEO. The diblock copolymers self-assembled into well-dispersed spherical micelles with PEP cores and PEO coronas. No appreciable change in the final extent of cure of the thermosets was caused by the addition of diblock copolymer, except in the case of BisGMA, where the addition of the block copolymer increased extent of cure by 12%. Furthermore, the extent of cure was increased by 29% and 37% with the addition of 25 and 50 wt % PEGDMA, respectively. Elastic modulus and fracture resistance were also determined, and the values indicate that the addition of block copolymers does not significantly toughen the thermoset materials. This finding is surprising when compared with the large increase in fracture resistance seen in block copolymer-modified epoxies, and an explanation is proposed.

  2. Gas block mechanism for water removal in fuel cells

    DOE Patents [OSTI]

    Issacci, Farrokh; Rehg, Timothy J.

    2004-02-03

    The present invention is directed to apparatus and method for cathode-side disposal of water in an electrochemical fuel cell. There is a cathode plate. Within a surface of the plate is a flow field comprised of interdigitated channels. During operation of the fuel cell, cathode gas flows by convection through a gas diffusion layer above the flow field. Positioned at points adjacent to the flow field are one or more porous gas block mediums that have pores sized such that water is sipped off to the outside of the flow field by capillary flow and cathode gas is blocked from flowing through the medium. On the other surface of the plate is a channel in fluid communication with each porous gas block mediums. The method for water disposal in a fuel cell comprises installing the cathode plate assemblies at the cathode sides of the stack of fuel cells and manifolding the single water channel of each of the cathode plate assemblies to the coolant flow that feeds coolant plates in the stack.

  3. Nanopatterning of ultrananocrystalline diamond thin films via block copolymer lithography.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B.; Sumant, A. V.; Auciello, O.

    2010-07-01

    Nanopatterning of diamond surfaces is critical for the development of diamond-based microelectromechanical system/nanoelectromechanical system (MEMS/NEMS), such as resonators or switches. Micro-/nanopatterning of diamond materials is typically done using photolithography or electron beam lithography combined with reactive ion etching (RIE). In this work, we demonstrate a simple process, block copolymer (BCP) lithography, for nanopatterning of ultrananocrystalline diamond (UNCD) films to produce nanostructures suitable for the fabrication of NEMS based on UNCD. In BCP lithography, nanoscale self-assembled polymeric domains serve as an etch mask for pattern transfer. The authors used thin films of a cylinder-forming organic-inorganic BCP, poly(styrene-block-ferrocenyldimethylsilane), PS-b-PFS, as an etch mask on the surface of UNCD films. Orientational control of the etch masking cylindrical PFS blocks is achieved by manipulating the polymer film thickness in concert with the annealing treatment. We have observed that the surface roughness of UNCD layers plays an important role in transferring the pattern. Oxygen RIE was used to etch the exposed areas of the UNCD film underneath the BCP. Arrays of both UNCD posts and wirelike structures have been created using the same starting polymeric materials as the etch mask.

  4. Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM NOTICE 10-011 EFFECTIVE DATE: April 21, 2010 SUBJECT: AMERICAN RECOVERY AND REINVESTMENT ACT (ARRA) ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANT PROGRAM - FORMULA GRANT GUIDANCE PURPOSE ........................................................................................................................... 3 SCOPE

  5. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined...

  6. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block ... has succeeded in combining resonant soft x-ray scattering (RSoXS) at ALS Beamline 11.0.1 ...

  7. Plains and Eastern Clean Line Transmission Line: Comment from Block Plains

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Eastern Clean Line: Arkansas and Oklahoma | Department of Energy Block Plains and Eastern Clean Line: Arkansas and Oklahoma Plains and Eastern Clean Line Transmission Line: Comment from Block Plains and Eastern Clean Line: Arkansas and Oklahoma Comment submitted on updated Part 2 application. Comment from Block Plains & Eastern Clean Line Arkansas and Oklahoma 06-08-15.pdf (1.21 MB) More Documents & Publications Plains and Eastern Clean Line Transmission Line: Comment from Block

  8. Application of soil barriers for encapsulation of contaminants using special blocking materials and sealing technologies

    SciTech Connect (OSTI)

    Kretzschmar, H.J.; Lakatos, I.

    1997-12-31

    This paper describes the use of Montanwax and polymersilicate solution for use as blocking materials for the containment of pollutants.

  9. Non-crosslinked, amorphous, block copolymer electrolyte for batteries

    DOE Patents [OSTI]

    Mayes, Anne M.; Ceder, Gerbrand; Chiang, Yet-Ming; Sadoway, Donald R.; Aydinol, Mehmet K.; Soo, Philip P.; Jang, Young-Il; Huang, Biying

    2006-04-11

    Solid battery components are provided. A block copolymeric electrolyte is non-crosslinked and non-glassy through the entire range of typical battery service temperatures, that is, through the entire range of at least from about 0.degree. C. to about 70.degree. C. The chains of which the copolymer is made each include at least one ionically-conductive block and at least one second block immiscible with the ionically-conductive block. The chains form an amorphous association and are arranged in an ordered nanostructure including a continuous matrix of amorphous ionically-conductive domains and amorphous second domains that are immiscible with the ionically-conductive domains. A compound is provided that has a formula of Li.sub.xM.sub.yN.sub.zO.sub.2. M and N are each metal atoms or a main group elements, and x, y and z are each numbers from about 0 to about 1. y and z are chosen such that a formal charge on the M.sub.yN.sub.z portion of the compound is (4-x). In certain embodiments, these compounds are used in the cathodes of rechargeable batteries. The present invention also includes methods of predicting the potential utility of metal dichalgogenide compounds for use in lithium intercalation compounds. It also provides methods for processing lithium intercalation oxides with the structure and compositional homogeneity necessary to realize the increased formation energies of said compounds. An article is made of a dimensionally-stable, interpenetrating microstructure of a first phase including a first component and a second phase, immiscible with the first phase, including a second component. The first and second phases define interphase boundaries between them, and at least one particle is positioned between a first phase and a second phase at an interphase boundary. When the first and second phases are electronically-conductive and ionically-conductive polymers, respectively, and the particles are ion host particles, the arrangement is an electrode of a battery.

  10. Single Helix to Double Gyroid in Chiral Block Copolymers

    SciTech Connect (OSTI)

    C Chen; H Hsueh; Y Chiang; R Ho; S Akasaka; H Hasegawa

    2011-12-31

    An order-order phase transition of chiral block copolymers (BCPs*) from single helix to double gyroid (H* {yields} G) through a nucleation and growth process was demonstrated. The H* and G phases can be obtained by solution casting from fast and slow solvent evaporation, respectively, suggesting that the H* phase is a metastable phase. Consequently, the coexistence of H* and G phases can be found in the solution-cast samples from intermediate solvent evaporation. To truly examine the transition mechanism of the H* {yields} G, electron tomography was carried out to directly visualize the morphological evolution in real space, in particular, the transition zone at interface. Unlike the mechanisms for the transitions of block copolymers (BCPs) by considering the interdomain spacing matching, a significant mismatch in the lattices for the H* {yields} G was found. Consequently, the transition may require an adjustment on the geometric dimensions to justify corresponding lattice mismatch. As a result, the morphological observations from electron tomography offer new insights into BCP phase transitions.

  11. Deuteration Can Impact Micellization Pressure and Cloud Pressure of Polystyrene-block-polybutadiene and Polystyrene-block-polyisoprene in Compressible Propane

    SciTech Connect (OSTI)

    Winoto, Winoto; Shen, Youqin; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    The deuterated homopolymers and their corresponding polystyrene-block-polybutadiene and polystyrene-block-polyisoprene copolymers require lower cloud pressures than their hydrogenous analogues to dissolve in a compressible alkane solvent, such as propane. For symmetric diblocks, deuteration reduces the micellization pressure. By contrast, for asymmetric diblocks with a long diene block relative to the styrene block, deuteration can increase the micellization pressure. All in all, however, the deuteration effects, while measurable, do not qualitatively change the principal diblock properties in compressible propane solutions, such as pressure-induced micelle decomposition, micelle formation and micelle size, and their temperature dependence. Therefore, isotope labeling should be a useful approach to neutron-scattering characterization for styrene-diene block copolymers in compressible alkane systems.

  12. Sealed Battery Block Provided With A Cooling System

    DOE Patents [OSTI]

    Verhoog, Roelof; Barbotin, Jean-Loup

    1999-11-16

    The present invention relates to a sealed battery block operating at a pressure of at least 1 bar relative, the battery including a container made of a plastics material and made up of a lid and of a case subdivided into wells by at least one partition, said battery being provided with a cooling system including two cheek plates made of a plastics material and co-operating with the outside faces of respective ones of two opposite walls of said case, each cheek plate co-operating with the corresponding wall to define a compartment provided with a plurality of ribs forming baffles for fluid flow purposes, and with an inlet orifice and an outlet orifice for the fluid, said battery being characterized in that each of said ribs extends in a direction that forms an angle relative to the plane of said partition lying in the range 60.degree. to 90.degree..

  13. Linked supramolecular building blocks for enhanced cluster formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLellan, Ross; Palacios, Maria A.; Beavers, Christine M.; Teat, Simon J.; Piligkos, Stergios; Brechin, Euan K.; Dalgarno, Scott J.

    2015-01-09

    Methylene-bridged calix[4]arenes have emerged as extremely versatile ligand supports in the formation of new polymetallic clusters possessing fascinating magnetic properties. Metal ion binding rules established for this building block allow one to partially rationalise the complex assembly process. The ability to covalently link calix[4]arenes at the methylene bridge provides significantly improved control over the introduction of different metal centres to resulting cluster motifs. Clusters assembled from bis-calix[4]arenes and transition metal ions or 3d-4f combinations display characteristic features of the analogous calix[4]arene supported clusters, thereby demonstrating an enhanced and rational approach towards the targeted synthesis of complex and challenging structures.

  14. Nanoporous Gold as a Platform for a Building Block Catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporousmore » gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.« less

  15. Nanoporous Gold as a Platform for a Building Block Catalyst

    SciTech Connect (OSTI)

    Wittstock, Arne; Wichmann, Andre; Baeumer, Marcus

    2012-09-25

    The porous bulk materials are of great interest in catalysis because they can be employed in heterogeneous gas and liquid phase catalysis, electrocatalysis, and in electrocatalytic sensing. Nanoporous gold gained considerable attraction in this context because it is the prime example of a corrosion-derived nanoporous bulk metal. Moreover, the material was shown to be a very active and selective Au type catalyst for a variety of oxidation reactions. In leveraging the functionalization of the surface of the material with various additives, its catalytic applications can be extended and tuned. In this review, we will summarize recent developments in using nanoporous gold as the platform for the development of high performance catalytic materials by adding metals, metal oxides, and molecular functionalities as building blocks.

  16. Linked supramolecular building blocks for enhanced cluster formation

    SciTech Connect (OSTI)

    McLellan, Ross; Palacios, Maria A.; Beavers, Christine M.; Teat, Simon J.; Piligkos, Stergios; Brechin, Euan K.; Dalgarno, Scott J.

    2015-01-09

    Methylene-bridged calix[4]arenes have emerged as extremely versatile ligand supports in the formation of new polymetallic clusters possessing fascinating magnetic properties. Metal ion binding rules established for this building block allow one to partially rationalise the complex assembly process. The ability to covalently link calix[4]arenes at the methylene bridge provides significantly improved control over the introduction of different metal centres to resulting cluster motifs. Clusters assembled from bis-calix[4]arenes and transition metal ions or 3d-4f combinations display characteristic features of the analogous calix[4]arene supported clusters, thereby demonstrating an enhanced and rational approach towards the targeted synthesis of complex and challenging structures.

  17. Cooperative storage of shared files in a parallel computing system with dynamic block size

    DOE Patents [OSTI]

    Bent, John M.; Faibish, Sorin; Grider, Gary

    2015-11-10

    Improved techniques are provided for parallel writing of data to a shared object in a parallel computing system. A method is provided for storing data generated by a plurality of parallel processes to a shared object in a parallel computing system. The method is performed by at least one of the processes and comprises: dynamically determining a block size for storing the data; exchanging a determined amount of the data with at least one additional process to achieve a block of the data having the dynamically determined block size; and writing the block of the data having the dynamically determined block size to a file system. The determined block size comprises, e.g., a total amount of the data to be stored divided by the number of parallel processes. The file system comprises, for example, a log structured virtual parallel file system, such as a Parallel Log-Structured File System (PLFS).

  18. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  19. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  20. ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM NOTICE 10-012 DAVIS-BACON ACT WAGE RATES FOR ARRA-FUNDED ENERGY EFFICIENCY AND CONSERVATION BLOCK GRANTS PROGRAM PROJECTS INVOLVING RESIDENTIAL WEATHERIZATION WORK eecbg_guidance_not_using_wap_rates_05062010.pdf (57.2 KB) More Documents & Publications Davis-Bacon Act Wage Rates for ARRA-Funded State Energy Program Projects Involving

  1. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  2. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  3. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  4. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  5. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks interact with surfaces and interfaces is critical to success, previous experiments

  6. Thermal-stress analysis of a Fort St. Vrain core-support block under accident conditions

    SciTech Connect (OSTI)

    Carruthers, L.M.; Butler, T.A.; Anderson, C.A.

    1982-01-01

    A thermoelastic stress analysis of a graphite core support block in the Fort St. Vrain High Temperature Gas Cooled Reactor is described. The support block is subjected to thermal stresses caused by a loss of forced circulation accident of the reactor system. Two- and three-dimensional finite element models of the core support block are analyzed using the ADINAT and ADINA codes, and results are given that verify the integrity of this structural component under the given accident condition.

  7. In Situ SAXS Studies of Structural Relaxation of an Ordered Block...

    Office of Scientific and Technical Information (OSTI)

    Flow Citation Details In-Document Search Title: In Situ SAXS Studies of Structural Relaxation of an Ordered Block Copolymer Melt Following Cessation of Uniaxial Extensional Flow ...

  8. 50 kW Power Block for Distributed Energy Applications - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search 50 kW Power Block for Distributed Energy Applications National Renewable Energy Laboratory Contact NREL About This Technology Actual prototype ...

  9. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resonant Soft X-Ray Scattering of Tri-Block Copolymers Resonant Soft X-Ray Scattering of Tri-Block Copolymers Print Wednesday, 30 May 2012 00:00 In principle, tri-block copolymers (tri-BCPs), consisting of three chemically distinct polymers covalently joined together at the ends of each polymer chain, can serve as scaffolds and templates for fabricating a vast number of nanostructures. While quantitatively understanding the details of the morphology and the manner in which the different blocks

  10. Collapse transitions in thermosensitive multi-block copolymers: A Monte Carlo study

    SciTech Connect (OSTI)

    Rissanou, Anastassia N.; Tzeli, Despoina S.; Anastasiadis, Spiros H.; Bitsanis, Ioannis A.

    2014-05-28

    Monte Carlo simulations are performed on a simple cubic lattice to investigate the behavior of a single linear multiblock copolymer chain of various lengths N. The chain of type (A{sub n}B{sub n}){sub m} consists of alternating A and B blocks, where A are solvophilic and B are solvophobic and N = 2nm. The conformations are classified in five cases of globule formation by the solvophobic blocks of the chain. The dependence of globule characteristics on the molecular weight and on the number of blocks, which participate in their formation, is examined. The focus is on relative high molecular weight blocks (i.e., N in the range of 5005000 units) and very differing energetic conditions for the two blocks (very goodalmost athermal solvent for A and bad solvent for B). A rich phase behavior is observed as a result of the alternating architecture of the multiblock copolymer chain. We trust that thermodynamic equilibrium has been reached for chains of N up to 2000 units; however, for longer chains kinetic entrapments are observed. The comparison among equivalent globules consisting of different number of B-blocks shows that the more the solvophobic blocks constituting the globule the bigger its radius of gyration and the looser its structure. Comparisons between globules formed by the solvophobic blocks of the multiblock copolymer chain and their homopolymer analogs highlight the important role of the solvophilic A-blocks.

  11. Self-assembly of block copolymers on topographically patterned polymeric substrates

    DOE Patents [OSTI]

    Russell, Thomas P.; Park, Soojin; Lee, Dong Hyun; Xu, Ting

    2016-05-10

    Highly-ordered block copolymer films are prepared by a method that includes forming a polymeric replica of a topographically patterned crystalline surface, forming a block copolymer film on the topographically patterned surface of the polymeric replica, and annealing the block copolymer film. The resulting structures can be used in a variety of different applications, including the fabrication of high density data storage media. The ability to use flexible polymers to form the polymeric replica facilitates industrial-scale processes utilizing the highly-ordered block copolymer films.

  12. $300,000 Block Grant Awarded to Tri-City Industrial Development Council

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (TRIDEC) | Department of Energy $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) $300,000 Block Grant Awarded to Tri-City Industrial Development Council (TRIDEC) (37.6 KB) More Documents & Publications Department of Energy Awards $300,000 to Tri-City Industrial Development Council in Washington

  13. Nanostructure of Solid Precipitates Obtained by Expansion of Polystyrene-block-Polybutadiene Solutions in Near Critical Propane: Block Ratio and Micellar Solution Effects

    SciTech Connect (OSTI)

    Green, Jade; Tyrrell, Zachary; Radosz, Maciej; Hong, Kunlun; Mays, Jimmy

    2011-01-01

    In contrast to incompressible liquid solutions, compressible near-critical solutions of block copolymers allow for controlling rapid structure transformations with pressure alone. For example, when dissolved in near-critical propane, polystyrene-block-polybutadiene can form a random molecular solution at high pressures, a micellar solution at moderate pressures, and a solvent-free precipitate at low pressures. In contrast to the unstructured virgin copolymer, such a propane-treated precipitate rapidly self-assembles toward structures characteristic of equilibrated block copolymers, such as lamellae, spheres, or cylinders, which depend on the block ratio rather than on the decompression rate or temperature, at least within the rate and temperature ranges investigated in this work. At lower temperatures, however, say below 40 C, glass transition of the styrene-butadiene diblocks can inhibit independent structure formation, while crystallization of their hydrogenated-butadiene analogues can preserve the micellar-solution structure.

  14. STUDIES IN ASTRONOMICAL TIME SERIES ANALYSIS. VI. BAYESIAN BLOCK REPRESENTATIONS

    SciTech Connect (OSTI)

    Scargle, Jeffrey D.; Norris, Jay P.; Jackson, Brad; Chiang, James

    2013-02-20

    This paper addresses the problem of detecting and characterizing local variability in time series and other forms of sequential data. The goal is to identify and characterize statistically significant variations, at the same time suppressing the inevitable corrupting observational errors. We present a simple nonparametric modeling technique and an algorithm implementing it-an improved and generalized version of Bayesian Blocks-that finds the optimal segmentation of the data in the observation interval. The structure of the algorithm allows it to be used in either a real-time trigger mode, or a retrospective mode. Maximum likelihood or marginal posterior functions to measure model fitness are presented for events, binned counts, and measurements at arbitrary times with known error distributions. Problems addressed include those connected with data gaps, variable exposure, extension to piecewise linear and piecewise exponential representations, multivariate time series data, analysis of variance, data on the circle, other data modes, and dispersed data. Simulations provide evidence that the detection efficiency for weak signals is close to a theoretical asymptotic limit derived by Arias-Castro et al. In the spirit of Reproducible Research all of the code and data necessary to reproduce all of the figures in this paper are included as supplementary material.

  15. The nucleocapsid protein of measles virus blocks host interferon response

    SciTech Connect (OSTI)

    Takayama, Ikuyo; Sato, Hiroki; Watanabe, Akira; Omi-Furutani, Mio; Sugai, Akihiro; Kanki, Keita; Yoneda, Misako; Kai, Chieko

    2012-03-01

    Measles virus (MV) belongs to the genus Morbillivirus of the family Paramyxoviridae. A number of paramyxoviruses inhibit host interferon (IFN) signaling pathways in host immune systems by various mechanisms. Inhibition mechanisms have been described for many paramyxoviruses. Although there are inconsistencies among previous reports concerning MV, it appears that P/V/C proteins interfere with the pathways. In this study, we confirmed the effects of MV P gene products of a wild MV strain on IFN pathways and examined that of other viral proteins on it. Interestingly, we found that N protein acts as an IFN-{alpha}/{beta} and {gamma}-antagonist as strong as P gene products. We further investigated the mechanisms of MV-N inhibition, and revealed that MV-N blocks the nuclear import of activated STAT without preventing STAT and Jak activation or STAT degradation, and that the nuclear translocation of MV-N is important for the inhibition. The inhibitory effect of the N protein was observed as a common feature of other morbilliviruses. The results presented in this report suggest that N protein of MV as well as P/V/C proteins is involved in the inhibition of host IFN signaling pathways.

  16. Parallel Block Structured Adaptive Mesh Refinement on Graphics Processing Units

    SciTech Connect (OSTI)

    Beckingsale, D. A.; Gaudin, W. P.; Hornung, R. D.; Gunney, B. T.; Gamblin, T.; Herdman, J. A.; Jarvis, S. A.

    2014-11-17

    Block-structured adaptive mesh refinement is a technique that can be used when solving partial differential equations to reduce the number of zones necessary to achieve the required accuracy in areas of interest. These areas (shock fronts, material interfaces, etc.) are recursively covered with finer mesh patches that are grouped into a hierarchy of refinement levels. Despite the potential for large savings in computational requirements and memory usage without a corresponding reduction in accuracy, AMR adds overhead in managing the mesh hierarchy, adding complex communication and data movement requirements to a simulation. In this paper, we describe the design and implementation of a native GPU-based AMR library, including: the classes used to manage data on a mesh patch, the routines used for transferring data between GPUs on different nodes, and the data-parallel operators developed to coarsen and refine mesh data. We validate the performance and accuracy of our implementation using three test problems and two architectures: an eight-node cluster, and over four thousand nodes of Oak Ridge National Laboratory’s Titan supercomputer. Our GPU-based AMR hydrodynamics code performs up to 4.87× faster than the CPU-based implementation, and has been scaled to over four thousand GPUs using a combination of MPI and CUDA.

  17. Matrix-free constructions of circulant and block circulant preconditioners

    SciTech Connect (OSTI)

    Yang, Chao; Ng, Esmond G.; Penczek, Pawel A.

    2001-12-01

    A framework for constructing circulant and block circulant preconditioners (C) for a symmetric linear system Ax=b arising from certain signal and image processing applications is presented in this paper. The proposed scheme does not make explicit use of matrix elements of A. It is ideal for applications in which A only exists in the form of a matrix vector multiplication routine, and in which the process of extracting matrix elements of A is costly. The proposed algorithm takes advantage of the fact that for many linear systems arising from signal or image processing applications, eigenvectors of A can be well represented by a small number of Fourier modes. Therefore, the construction of C can be carried out in the frequency domain by carefully choosing its eigenvalues so that the condition number of C{sup T} AC can be reduced significantly. We illustrate how to construct the spectrum of C in a way such that the smallest eigenvalues of C{sup T} AC overlaps with those of A extremely well while the largest eigenvalues of C{sup T} AC are smaller than those of A by several orders of magnitude. Numerical examples are provided to demonstrate the effectiveness of the preconditioner on accelerating the solution of linear systems arising from image reconstruction application.

  18. Tunable Encapsulation Structure of Block Copolymer Coated Single-Walled Carbon Nanotubes in Aqueous Solution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Youngkyu; Ahn, Suk-Kyun; Zhang, Zhe; Smith, Gregory Scott; Do, Changwoo

    2015-01-01

    The nano-sized and shape-tunable molecular building blocks can provide great opportunities for the fabrication of precisely controlled nanostructures. In this work, we have fabricated a molecular building block of single-walled carbon nanotubes (SWNTs) coated by PPO-PEO-PPO block copolymers whose encapsulation structure can be controlled via temperature or addition of small molecules. The structure and optical properties of SWNT-block copolymers have been investigated by small angle neutron scattering (SANS), ultraviolet-visible (UV-vis) spectroscopy, atomic force microscopy (AFM), and molecular dynamics (MD) simulation. The structure of the hydrated block copolymer layer surrounding SWNT can be controlled reversibly by varying temperature as well asmore » by irreversibly adding 5-methylsalicylic acid (5MS). Increasing hydrophobicity of the polymers with temperature and strong tendency of 5MS to interact with both block copolymers and orbitals of the SWNTs are likely to be responsible for the significant structural change of the block copolymer encapsulation layer, from loose corona shell to tightly encapsulating compact shell. These result shows an efficient and simple way to fabricate and manipulate carbon-based nano building blocks in aqueous systems with tunable structure.« less

  19. Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes

    DOE Patents [OSTI]

    Fujimoto, Cy H.; Hibbs, Michael; Ambrosini, Andrea

    2012-02-07

    Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

  20. Monitoring Plan for Weatherization Assistance Program, State Energy Program, Energy Efficiency and Conservation Block Grants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    American Recovery and Reinvestment Act Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants Revised: June 30, 2010 U.S. Department of Energy Office of Weatherization and Intergovernmental Program Monitoring Plan for Weatherization Assistance Program State Energy Program Energy Efficiency and Conservation Block Grants Concurrences:

  1. Ultrasonic examination of the heavy section test blocks for hydroprocessing reactors used by the petroleum industry

    SciTech Connect (OSTI)

    Dodd, F.J.; Zhang, Y.; Imgram, A.

    1995-12-01

    An 18-inch (457 mm) thick Cr-Mo steel test block with an austenitic stainless steel ID cladding was designed and fabricated at the direction of the Material Properties Council in cooperation with the Pressure Vessel Research Committee (PVRC) Committee on Nondestructive Examination of Components. The test block contains several embedded flaws located near both ID and OD surfaces. Chevron Research and Technology Company and WesDyne International conducted the initial UT Examinations on this block at Chevron. In addition, a 10-inch (254 mm) thick block with embedded flaws was also examined. All the flaws m the two blocks were either cracks or lack of fusion. The examination results demonstrate the feasibility of UT to detect and size flaws in hydroprocessing reactor vessels and provide a basis to compare the relative capabilities of UT with the radiographic (RT) inspections currently required by the fabrication code.

  2. Sub-5 nm Domains in Ordered Poly(cyclohexylethylene)-block-poly(methyl methacrylate) Block Polymers for Lithography.

    SciTech Connect (OSTI)

    Kennemur, Justin; Yao, Li; Bates, Frank Stephen; Hillmyer, Marc

    2014-01-01

    A series of poly(cyclohexylethylene)-block-poly- (methyl methacrylate) (PCHE PMMA) diblock copolymers with varying molar mass (4.9 kg/mol Mn 30.6 kg/mol) and narrow molar mass distribution were synthesized through a combination of anionic and atom transfer radical polymerization (ATRP) techniques. Heterogeneous catalytic hydrogenation of -(hydroxy)polystyrene (PS-OH) yielded -(hydroxy)poly(cyclohexylethylene) (PCHEOH) with little loss of hydroxyl functionality. PCHE-OH was reacted with -bromoisobutyryl bromide (BiBB) to produce an ATRP macroinitiator used for the polymerization of methyl methacrylate. PCHE PMMA is a glassy, thermally stable material with a large effective segment segment interaction parameter, eff = (144.4 6.2)/T (0.162 0.013), determined by meanfield analysis of order-to-disorder transition temperatures (TODT) measured by dynamic mechanical analysis and differential scanning calorimetry. Ordered lamellar domain pitches (9 D 33 nm) were identified by small-angle X-ray scattering from neat BCPs containing 43 52 vol % PCHE ( f PCHE). Atomic force microscopy was used to show 7.5 nm lamellar features (D = 14.8 nm) which are some of the smallest observed to date. The lowest molar mass sample (Mn = 4.9 kg/mol, f PCHE = 0.46) is characterized by TODT = 173 3 C and sub-5 nm nanodomains, which together with the sacrificial properties of PMMA and the high overall thermal stability place this material at the forefront of high- systems for advanced nanopatterning applications.

  3. Detecting and Blocking Network Attacks at Ultra High Speeds

    SciTech Connect (OSTI)

    Paxson, Vern

    2010-11-29

    Stateful, in-depth, in-line traffic analysis for intrusion detection and prevention has grown increasingly more difficult as the data rates of modern networks rise. One point in the design space for high-performance network analysis - pursued by a number of commercial products - is the use of sophisticated custom hardware. For very high-speed processing, such systems often cast the entire analysis process in ASICs. This project pursued a different architectural approach, which we term Shunting. Shunting marries a conceptually quite simple hardware device with an Intrusion Prevention System (IPS) running on commodity PC hardware. The overall design goal is was to keep the hardware both cheap and readily scalable to future higher speeds, yet also retain the unparalleled flexibility that running the main IPS analysis in a full general-computing environment provides. The Shunting architecture we developed uses a simple in-line hardware element that maintains several large state tables indexed by packet header fields, including IP/TCP flags, source and destination IP addresses, and connection tuples. The tables yield decision values the element makes on a packet-by-packet basis: forward the packet, drop it, or divert ('shunt') it through the IPS (the default). By manipulating table entries, the IPS can, on a fine-grained basis: (i) specify the traffic it wishes to examine, (ii) directly block malicious traffic, and (iii) 'cut through' traffic streams once it has had an opportunity to 'vet' them, or (iv) skip over large items within a stream before proceeding to further analyze it. For the Shunting architecture to yield benefits, it needs to operate in an environment for which the monitored network traffic has the property that - after proper vetting - much of it can be safely skipped. This property does not universally hold. For example, if a bank needs to examine all Web traffic involving its servers for regulatory compliance, then a monitor in front of one of the bank

  4. High-Pressure Micellar Solutions of Polystyrene-block-Polybutadiene and Polystyrene-block-Polyisoprene Solutions in Propane Exhibit Cloud-Pressure Reduction and Distinct Micellization End Points

    SciTech Connect (OSTI)

    Winoto, Winoto; Radosz, Maciej; Tan, Sugata; Hong, Kunlun; Mays, Jimmy

    2009-01-01

    Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical non-micellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size and ratio, and on the polymer concentration. For a given pressure, the micellization end-point temperature corresponds to the "critical micelle temperature." The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

  5. Organic photosensitive cells having a reciprocal-carrier exciton blocking layer

    DOE Patents [OSTI]

    Rand, Barry P.; Forrest, Stephen R.; Thompson, Mark E.

    2007-06-12

    A photosensitive cell includes an anode and a cathode; a donor-type organic material and an acceptor-type organic material forming a donor-acceptor junction connected between the anode and the cathode; and an exciton blocking layer connected between the acceptor-type organic material of the donor-acceptor junction and the cathode, the blocking layer consisting essentially of a material that has a hole mobility of at least 10.sup.-7 cm.sup.2/V-sec or higher, where a HOMO of the blocking layer is higher than or equal to a HOMO of the acceptor-type material.

  6. Non-immunogenic, hydrophilic/cationic block copolymers and uses thereof

    DOE Patents [OSTI]

    Scales, Charles W.; Huang, Faqing; McCormick, Charles L.

    2010-05-18

    The present invention provides novel non-immunogenic, hydrophilic/cationic block copolymers comprising a neutral-hydrophilic polymer and a cationic polymer, wherein both polymers have well-defined chain-end functionality. A representative example of such a block copolymer comprises poly(N-(2-hydroxypropyl)methacrylamide) (PHPMA) and poly(N-[3-(dimethylamino)propyl]methacrylamide) (PDMAPMA). Also provided is a synthesis method thereof in aqueous media via reversible addition fragmentation chain transfer (RAFT) polymerization. Further provided are uses of these block copolymers as drug delivery vehicles and protection agents.

  7. Three-dimensional thermoelastic analysis of a Fort St. Vrain core support block

    SciTech Connect (OSTI)

    Butler, T.A.; Anderson, C.A.

    1981-09-01

    A thermoelastic stress analysis of a graphite core support block in the Fort St. Vrain High-Temperature Gas-Cooled Reactor is described. The support block is subjected to thermal stresses caused by a loss of forced circulation accident of the reactor system. Two- and three-dimensional finite element models of the core support block are analyzed using the ADINAT and ADINA codes, and results are given that verify the integrity of this structural component under the given accident condition. 10 refs., 39 figs.

  8. Deputy-Director

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Berkeley Lab Deputy Director Horst Simon horst-simon Horst Simon is an internationally recognized expert in computer science and applied mathematics and the Deputy Director of ...

  9. Block entropy and quantum phase transition in the anisotropic Kondo necklace model

    SciTech Connect (OSTI)

    Mendoza-Arenas, J. J.; Franco, R.; Silva-Valencia, J.

    2010-06-15

    We study the von Neumann block entropy in the Kondo necklace model for different anisotropies {eta} in the XY interaction between conduction spins using the density matrix renormalization group method. It was found that the block entropy presents a maximum for each {eta} considered, and, comparing it with the results of the quantum criticality of the model based on the behavior of the energy gap, we observe that the maximum block entropy occurs at the quantum critical point between an antiferromagnetic and a Kondo singlet state, so this measure of entanglement is useful for giving information about where a quantum phase transition occurs in this model. We observe that the block entropy also presents a maximum at the quantum critical points that are obtained when an anisotropy {Delta} is included in the Kondo exchange between localized and conduction spins; when {Delta} diminishes for a fixed value of {eta}, the critical point increases, favoring the antiferromagnetic phase.

  10. Indian Community Development Block Grant Program FY 2016 Notice of Funding Availability Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Housing and Urban Development (HUD) Southwest Office of Native American Programs is conducting this training workshop to assist applicants with the Indian Community Development Block Grant Program.

  11. Method of producing nanopatterned articles using surface-reconstructed block copolymer films

    DOE Patents [OSTI]

    Russell, Thomas P; Park, Soojin; Wang, Jia-Yu; Kim, Bokyung

    2013-08-27

    Nanopatterned surfaces are prepared by a method that includes forming a block copolymer film on a substrate, annealing and surface reconstructing the block copolymer film to create an array of cylindrical voids, depositing a metal on the surface-reconstructed block copolymer film, and heating the metal-coated block copolymer film to redistribute at least some of the metal into the cylindrical voids. When very thin metal layers and low heating temperatures are used, metal nanodots can be formed. When thicker metal layers and higher heating temperatures are used, the resulting metal structure includes nanoring-shaped voids. The nanopatterned surfaces can be transferred to the underlying substrates via etching, or used to prepare nanodot- or nanoring-decorated substrate surfaces.

  12. Well-defined PI-b-PAA/PS-b-PI-b-PAA Block Copolymers: Synthesis...

    Office of Scientific and Technical Information (OSTI)

    Media Citation Details In-Document Search Title: Well-defined PI-b-PAAPS-b-PI-b-PAA Block Copolymers: Synthesis and Their Self-Assembled Hierarchical Structures in Aqueous Media ...

  13. Nanoscale Building Blocks and DNA "Glue" Help Shape 3D Architectures...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Building Blocks and DNA "Glue" Help Shape 3D Architectures Basic Energy Sciences (BES) ... by the U.S. Department of Energy, Office of Science, Office of Basic Energy ...

  14. Testing of TAMU3: a Nb3Sn Block-Coil Dipole with Stress Management...

    Office of Scientific and Technical Information (OSTI)

    The Accelerator Research Lab (ARL) at Texas A&M has recently concluded the construction and testing of a superconducting block-coil dipole TAMU3. TAMU3 reached 85% of the ...

  15. Resonant Soft X-Ray Scattering of Tri-Block Copolymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    enormous parameter space for the creation of new morphologies. Illustration from F.S. Bates and G.H. Fredrickson, "Block copolymers-designer soft materials," Physics Today 52, 32...

  16. Video compression of coronary angiograms based on discrete wavelet transform with block classification

    SciTech Connect (OSTI)

    Ho, B.K.T.; Tsai, M.J.; Wei, J.; Ma, M.; Saipetch, P.

    1996-12-01

    A new method of video compression for angiographic images has been developed to achieve high compression ratio ({approximately}20:1) while eliminating block artifacts which leads to loss of diagnostic accuracy. This method adopts motion picture experts group`s (MPEG`s) motion compensated prediction to take advantage of frame to frame correlation. However, in contrast to MPEG, the error images arising from mismatches in the motion estimation are encoded by discrete wavelet transform (DWT) rather than block discrete cosine transform (DCT). Furthermore, the authors developed a classification scheme which label each block in an image as intra, error, or background type and encode it accordingly. This hybrid coding can significantly improve the compression efficiency in certain cases. This method can be generalized for any dynamic image sequences applications sensitive to block artifacts.

  17. New Shielding Is Designed to Put the Block on Neutrons | Jefferson...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shielding Is Designed to Put the Block on Neutrons New Shielding Is Designed to Put the ... Their patented and patent-pending products are currently being installed in Hall C. New ...

  18. Guidance for Energy Efficiency and Conservation Block Grant Program Recipients on Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE)

    U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Energy Efficiency and Conservation Block Grant (EECBG) Program Guidance 10-011 dealing with formula grants.

  19. Energy Department Announces Energy Efficiency and Conservation Block Grant Program National Evaluation Results

    Broader source: Energy.gov [DOE]

    The Energy Department announced today the results of a major national evaluation of the Energy Efficiency and Conservation Block Grant (EECBG) program funded by the American Recovery and Reinvestment Act (ARRA).

  20. Funding Opportunity Announcement: Recovery Act … Energy Efficiency and Conversation Block Grants … Formula Grants

    Office of Energy Efficiency and Renewable Energy (EERE)

    Funding opportunity announcement for the Energy Efficiency and Conversation Block Grants, an opportunity open from March 26, 2009 to May 26, 2009 for state applicants and June 25, 2009 for local government and tribal applicants.

  1. How to create formatted blocks to hold OpenEI wiki content |...

    Open Energy Info (EERE)

    format, which you can see in use on the OpenEI frontpage. As an example of the migration, please see below. You can see that classes after "block-v1" moved in addition to...

  2. Polysulfide-Blocking Polymer Membrane for Li-S Batteries - Joint Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Research August 3, 2015, Research Highlights Polysulfide-Blocking Polymer Membrane for Li-S Batteries The microporous network allows the passage of smaller moieties such as solvent molecules, LiTFSI, and lithium ions while forbidding the passage of larger polysulfides (Li2Sx). Scientific Achievement Polymers of Intrinsic Microporosity are harnessed as an ion-selective membrane, effectively blocking polysulfide crossover due to its microporous molecular-sieving network.

  3. Road Blocks Yield Key Information about a Catalyst | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Road Blocks Yield Key Information about a Catalyst Researchers systematically blocked key chemical reaction pathways to get unambiguous information about how carbon-nitrogen bonds are formed in a catalytic reaction known as hydroamination. Understanding a multi-step catalytic mechanism is like a solving a puzzle where you can't see the pieces. However, you can add your own "pieces" with known shapes to figure out what other pieces of the puzzle then will (or will not) fit.

  4. US-Guided Femoral and Sciatic Nerve Blocks for Analgesia During Endovenous Laser Ablation

    SciTech Connect (OSTI)

    Yilmaz, Saim Ceken, Kagan; Alimoglu, Emel; Sindel, Timur

    2013-02-15

    Endovenous laser ablation may be associated with significant pain when performed under standard local tumescent anesthesia. The purpose of this study was to investigate the efficacy of femoral and sciatic nerve blocks for analgesia during endovenous ablation in patients with lower extremity venous insufficiency. During a 28-month period, ultrasound-guided femoral or sciatic nerve blocks were performed to provide analgesia during endovenous laser ablation in 506 legs and 307 patients. The femoral block (n = 402) was performed at the level of the inguinal ligament, and the sciatic block at the posterior midthigh (n = 124), by injecting a diluted lidocaine solution under ultrasound guidance. After the blocks, endovenous laser ablations and other treatments (phlebectomy or foam sclerotherapy) were performed in the standard fashion. After the procedures, a visual analogue pain scale (1-10) was used for pain assessment. After the blocks, pain scores were 0 or 1 (no pain) in 240 legs, 2 or 3 (uncomfortable) in 225 legs, and 4 or 5 (annoying) in 41 legs. Patients never experienced any pain higher than score 5. The statistical analysis revealed no significant difference between the pain scores of the right leg versus the left leg (p = 0.321) and between the pain scores after the femoral versus sciatic block (p = 0.7). Ultrasound-guided femoral and sciatic nerve blocks may provide considerable reduction of pain during endovenous laser and other treatments, such as ambulatory phlebectomy and foam sclerotherapy. They may make these procedures more comfortable for the patient and easier for the operator.

  5. Power Block R&D for CSP Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Power Block R&D for CSP Systems Power Block R&D for CSP Systems Power plant components and systems for concentrating solar power (CSP) benefit from a mature and well-understood technology found elsewhere in the power generation industry. The most common cycles employed by conventional CSP plants include subcritical Rankine and Stirling. Gross thermal-to-electric conversion efficiencies are typically 35%-45%. Working fluids include steam, hydrogen, and helium. The primary driver for

  6. Preventive maintenance system for the photomultiplier detector blocks of pet scanners

    DOE Patents [OSTI]

    Levy, Alejandro V.; Warner, Donald

    1995-01-24

    A system including a method and apparatus for preventive maintenance of PET scanner photomultiplier detector blocks is disclosed. The quantitive comparisons used in the method of the present invention to provide an indication in the form of a display or printout advising the user that the photomultiplier block is stable, intermittently unstable, or drifting unstable, and also advising of the expected date of failure of a photomultiplier block in the PET scanner. The system alerts the user to replace the defective photomultiplier block prior to catastrophic failure in a scheduled preventative maintenance program, thus eliminating expensive and unscheduled downtime of the PET scanner due to photomultiplier failure. The apparatus for carrying out the method of the present invention preferably resides in the host computer controlling a PET scanner. It includes a memory adapted for storing a record of a number of iterative adjustments that are necessary to calibrate the gain of a photomultiplier detector block i at a time t.sub.0, a time t.sub.1 and a time T, where T>t.sub.1 >t.sub.0, which is designated as Histo(i,j(t)). The apparatus also includes a processor configured by a software program or a combination of programmed RAM and ROM devices to perform a number of calculations and operations on these values, and also includes a counter for analyzing each photomultiplier detector block i=1 through I of a PET scanner.

  7. Preventive maintenance system for the photomultiplier detector blocks of PET scanners

    DOE Patents [OSTI]

    Levy, A.V.; Warner, D.

    1995-01-24

    A system including a method and apparatus for preventive maintenance of PET scanner photomultiplier detector blocks is disclosed. The qualitative comparisons used in the method of the present invention to provide an indication in the form of a display or printout advising the user that the photomultiplier block is stable, intermittently unstable, or drifting unstable, and also advising of the expected date of failure of a photomultiplier block in the PET scanner. The system alerts the user to replace the defective photomultiplier block prior to catastrophic failure in a scheduled preventative maintenance program, thus eliminating expensive and unscheduled downtime of the PET scanner due to photomultiplier failure. The apparatus for carrying out the method of the present invention preferably resides in the host computer controlling a PET scanner. It includes a memory adapted for storing a record of a number of iterative adjustments that are necessary to calibrate the gain of a photomultiplier detector block i at a time t[sub 0], a time t[sub 1] and a time T, where T>t[sub 1]>t[sub 0], which is designated as Histo(i,j(t)). The apparatus also includes a processor configured by a software program or a combination of programmed RAM and ROM devices to perform a number of calculations and operations on these values, and also includes a counter for analyzing each photomultiplier detector block i=1 through I of a PET scanner. 40 figures.

  8. Synthesis of manganese oxide supported on mesoporous titanium oxide: Influence of the block copolymer

    SciTech Connect (OSTI)

    Schmit, F.; Bois, L.; Chiriac, R.; Toche, F.; Chassagneux, F.; Besson, M.; Descorme, C.; Khrouz, L.

    2015-01-15

    Manganese oxides supported on mesoporous titanium oxides were synthesized via a sol–gel route using block copolymer self-assembly. The oxides were characterized by X-ray diffraction, infrared spectroscopy, thermal analyses, nitrogen adsorption/desorption, electron microscopy and electronic paramagnetic resonance. A mesoporous anatase containing amorphous manganese oxide particles could be obtained with a 0.2 Mn:Ti molar ratio. At higher manganese loading (0.5 Mn:Ti molar ratio), segregation of crystalline manganese oxide occurred. The influence of block copolymer and manganese salt on the oxide structure was discussed. The evolution of the textural and structural characteristics of the materials upon hydrothermal treatment was also investigated. - Graphical abstract: One-pot amorphous MnO{sub 2} supported on mesoporous anataseTiO{sub 2}. - Highlights: • Mesoporous manganese titanium oxides were synthesized using block copolymer. • Block copolymers form complexes with Mn{sup 2+} from MnCl{sub 2}. • With block copolymer, manganese oxide can be dispersed around the titania crystallites. • With Mn(acac){sub 2}, manganese is dispersed inside titania. • MnOOH crystallizes outside mesoporous titania during hydrothermal treatment.

  9. Millisecond ordering of block-copolymer films via photo-thermal gradients

    SciTech Connect (OSTI)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in less than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.

  10. Influence of shape and skin of matrix-rock blocks on pressure transients in fractured reservoirs

    SciTech Connect (OSTI)

    de Swaan, A.

    1986-01-01

    A formulation of pressure transients in terms of the intrinsic, or core, properties of the two media that compose the fractured reservoir, establishes the influence of these properties, and reciprocally, their corroboration from - the pressure-time relationship observed in well tests and interference tests. The following reservoir characteristics are analyzed: the area of fractures transverse to flow; the dimensions, shape and properties of rectangular parallelepiped matrix-rock blocks; and a permeability reduction in the blocks surface. A restatement of the so-called pseudo-steady state inter-media flow gives to parameters alfa and lambda in the theory of a previous study the physical meaning they lacked, and allows a direct determination of the blocks minimum dimension.

  11. Millisecond ordering of block-copolymer films via photo-thermal gradients

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Majewski, Pawel W.; Yager, Kevin G.

    2015-03-12

    For the promise of self-assembly to be realized, processing techniques must be developed that simultaneously enable control of the nanoscale morphology, rapid assembly, and, ideally, the ability to pattern the nanostructure. Here, we demonstrate how photo-thermal gradients can be used to control the ordering of block-copolymer thin films. Highly localized laser heating leads to intense thermal gradients, which induce a thermophoretic force on morphological defects. This increases the ordering kinetics by at least 3 orders-of-magnitude, compared to conventional oven annealing. By simultaneously exploiting the thermal gradients to induce shear fields, we demonstrate uniaxial alignment of a block-copolymer film in lessmore » than a second. Finally, we provide examples of how control of the incident light-field can be used to generate prescribed configurations of block-copolymer nanoscale patterns.« less

  12. Computer simulation of shading and blocking: Discussion of accuracy and recommendations

    SciTech Connect (OSTI)

    Lipps, F W

    1992-04-01

    A field of heliostats suffers losses caused by shading and blocking by neighboring heliostats. The complex geometry of multiple shading and blocking events suggests that a processing code is needed to update the boundary vector for each shading or blocking event. A new version, RSABS, (programmer`s manual included) simulates the split-rectangular heliostat. Researchers concluded that the dominant error for the given heliostat geometry is caused by the departure from planarity of the neighboring heliostats. It is recommended that a version of the heliostat simulation be modified to include losses due to nonreflective structural margins, if they occur. Heliostat neighbors should be given true guidance rather than assumed to be parallel, and the resulting nonidentical quadrilateral images should be processed, as in HELIOS, by ignoring overlapping events, rare in optimized fields.

  13. Ordered porous mesostructured materials from nanoparticle-block copolymer self-assembly

    DOE Patents [OSTI]

    Warren, Scott; Wiesner, Ulrich; DiSalvo, Jr., Francis J

    2013-10-29

    The invention provides mesostructured materials and methods of preparing mesostructured materials including metal-rich mesostructured nanoparticle-block copolymer hybrids, porous metal-nonmetal nanocomposite mesostructures, and ordered metal mesostructures with uniform pores. The nanoparticles can be metal, metal alloy, metal mixture, intermetallic, metal-carbon, metal-ceramic, semiconductor-carbon, semiconductor-ceramic, insulator-carbon or insulator-ceramic nanoparticles, or combinations thereof. A block copolymer/ligand-stabilized nanoparticle solution is cast, resulting in the formation of a metal-rich (or semiconductor-rich or insulator-rich) mesostructured nanoparticle-block copolymer hybrid. The hybrid is heated to an elevated temperature, resulting in the formation of an ordered porous nanocomposite mesostructure. A nonmetal component (e.g., carbon or ceramic) is then removed to produce an ordered mesostructure with ordered and large uniform pores.

  14. Method and apparatus for storing hydrogen isotopes. [stored as uranium hydride in a block of copper

    DOE Patents [OSTI]

    McMullen, J.W.; Wheeler, M.G.; Cullingford, H.S.; Sherman, R.H.

    1982-08-10

    An improved method and apparatus for storing isotopes of hydrogen (especially tritium) are provided. The hydrogen gas is stored as hydrides of material (for example uranium) within boreholes in a block of copper. The mass of the block is critically important to the operation, as is the selection of copper, because no cooling pipes are used. Because no cooling pipes are used, there can be no failure due to cooling pipes. And because copper is used instead of stainless steel, a significantly higher temperature can be reached before the eutectic formation of uranium with copper occurs, (the eutectic of uranium with the iron in stainless steel forms at a significantly lower temperature).

  15. Block Diagram Simulator to Solve a User-Defined Network of Differential Equatios

    Energy Science and Technology Software Center (OSTI)

    1996-12-18

    BDBSIM simulates control and protection systems found in fossil and nuclear power plants. The software is based on the identification of a general equation form that encompasses all control and protection equations encountered in these plants. The user enters his equations in block diagram form as a collection of individual dynamic function, logic, and table blocks. Constructing plant control equations in this manner is analogous to setting up an analog computer for simulation. The capabilitymore » is thus sufficiently general for use in modeling a wide variety of control and protection systems.« less

  16. Electrically conductive doped block copolymer of polyacetylene and polyisoprene. [Soluble in organic solvents

    DOE Patents [OSTI]

    Aldissi, M.

    1984-06-27

    An electrically conductive block copolymer of polyisoprene and polyacetylene and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I/sub 2/ to give it an electrical conductivity in the metallic regime.

  17. Capitol Area East End, Block 225: California Department of Education Headquarters

    High Performance Buildings Database

    Sacramento, CA The California Department of Education Headquarters, Block 225 was the first of the five buildings to make up the Capitol Area East End Complex. The entire project is being developed by the California Department of General Services Real Estate Division. At 336,000 square feet and six stories high, Block 225 was the most ambitious green-building initiative to have been undertaken by the State at that time and the largest office building project ever undertaken by the State. The project was delivered through a bridged design-build process.

  18. Guidance for Energy Efficiency and Conservation Block Grant Grantees on Qualified Energy Conservation Bonds and New Clean Renewable Energy Bonds

    Broader source: Energy.gov [DOE]

    Guidance for Energy Efficiency and Conservation Block Grant Program grantees regarding Qualified Energy Conservation Bonds (QECBs) and New Clean Renewable Energy Bonds (New CREBs)

  19. Compact microwave lamp having a tuning block and a dielectric located in a lamp cavity

    DOE Patents [OSTI]

    Simpson, James E.

    2000-01-01

    A microwave lamp having a compact structure utilizing a coupling slot which has a dielectric member extending therethrough and a tuning block adjoining the coupling slot. A non-conventional waveguide is used which has about the width of a WR-284 waveguide and about the length of a WR-340 waveguide.

  20. Efficient block processing of long duration biotelemetric brain data for health care monitoring

    SciTech Connect (OSTI)

    Soumya, I.; Zia Ur Rahman, M.; Rama Koti Reddy, D. V.; Lay-Ekuakille, A.

    2015-03-15

    In real time clinical environment, the brain signals which doctor need to analyze are usually very long. Such a scenario can be made simple by partitioning the input signal into several blocks and applying signal conditioning. This paper presents various block based adaptive filter structures for obtaining high resolution electroencephalogram (EEG) signals, which estimate the deterministic components of the EEG signal by removing noise. To process these long duration signals, we propose Time domain Block Least Mean Square (TDBLMS) algorithm for brain signal enhancement. In order to improve filtering capability, we introduce normalization in the weight update recursion of TDBLMS, which results TD-B-normalized-least mean square (LMS). To increase accuracy and resolution in the proposed noise cancelers, we implement the time domain cancelers in frequency domain which results frequency domain TDBLMS and FD-B-Normalized-LMS. Finally, we have applied these algorithms on real EEG signals obtained from human using Emotive Epoc EEG recorder and compared their performance with the conventional LMS algorithm. The results show that the performance of the block based algorithms is superior to the LMS counter-parts in terms of signal to noise ratio, convergence rate, excess mean square error, misadjustment, and coherence.

  1. Lattice QCD Thermodynamics : 10k analysis with 1k thermalziation and block size of 500.

    SciTech Connect (OSTI)

    Soltz, R; Vranas, P; Gupta, R

    2007-05-10

    This is a re-analysis of the Lattice QCD Thermodynamics p4rhcm new beta analysis (UCRL-TR-230742) with approximately 10k trajectories per beta point, rerun with thermalization cut at 1000, and a block size of 500. Some diagnostic text has been omitted to reduce the number of pages.

  2. Energy Efficiency and Conservation Block Grant Program National Evaluation Executive Summary

    Office of Energy Efficiency and Renewable Energy (EERE)

    This document presents findings from an evaluation of the Energy Efficiency and Conservation Block Grant Program, a national program operated by the U.S. Department of Energy from 2009 to 2015 that provided grants and technical assistance to local governments, states and territories to support a wide variety of energy efficiency and renewable energy activities.

  3. Task Parallel Incomplete Cholesky Factorization using 2D Partitioned-Block Layout

    SciTech Connect (OSTI)

    Kim, Kyungjoo; Rajamanickam, Sivasankaran; Stelle, George Widgery; Edwards, Harold C.; Olivier, Stephen Lecler

    2016-01-01

    We introduce a task-parallel algorithm for sparse incomplete Cholesky factorization that utilizes a 2D sparse partitioned-block layout of a matrix. Our factorization algorithm follows the idea of algorithms-by-blocks by using the block layout. The algorithm-byblocks approach induces a task graph for the factorization. These tasks are inter-related to each other through their data dependences in the factorization algorithm. To process the tasks on various manycore architectures in a portable manner, we also present a portable tasking API that incorporates different tasking backends and device-specific features using an open-source framework for manycore platforms i.e., Kokkos. A performance evaluation is presented on both Intel Sandybridge and Xeon Phi platforms for matrices from the University of Florida sparse matrix collection to illustrate merits of the proposed task-based factorization. Experimental results demonstrate that our task-parallel implementation delivers about 26.6x speedup (geometric mean) over single-threaded incomplete Choleskyby- blocks and 19.2x speedup over serial Cholesky performance which does not carry tasking overhead using 56 threads on the Intel Xeon Phi processor for sparse matrices arising from various application problems.

  4. A block matching-based registration algorithm for localization of locally advanced lung tumors

    SciTech Connect (OSTI)

    Robertson, Scott P.; Weiss, Elisabeth; Hugo, Geoffrey D.

    2014-04-15

    Purpose: To implement and evaluate a block matching-based registration (BMR) algorithm for locally advanced lung tumor localization during image-guided radiotherapy. Methods: Small (1 cm{sup 3}), nonoverlapping image subvolumes (“blocks”) were automatically identified on the planning image to cover the tumor surface using a measure of the local intensity gradient. Blocks were independently and automatically registered to the on-treatment image using a rigid transform. To improve speed and robustness, registrations were performed iteratively from coarse to fine image resolution. At each resolution, all block displacements having a near-maximum similarity score were stored. From this list, a single displacement vector for each block was iteratively selected which maximized the consistency of displacement vectors across immediately neighboring blocks. These selected displacements were regularized using a median filter before proceeding to registrations at finer image resolutions. After evaluating all image resolutions, the global rigid transform of the on-treatment image was computed using a Procrustes analysis, providing the couch shift for patient setup correction. This algorithm was evaluated for 18 locally advanced lung cancer patients, each with 4–7 weekly on-treatment computed tomography scans having physician-delineated gross tumor volumes. Volume overlap (VO) and border displacement errors (BDE) were calculated relative to the nominal physician-identified targets to establish residual error after registration. Results: Implementation of multiresolution registration improved block matching accuracy by 39% compared to registration using only the full resolution images. By also considering multiple potential displacements per block, initial errors were reduced by 65%. Using the final implementation of the BMR algorithm, VO was significantly improved from 77% ± 21% (range: 0%–100%) in the initial bony alignment to 91% ± 8% (range: 56%–100%;p < 0

  5. Theory for dynamical self arrest and gelation in microemulsions and the block copolymer systems

    SciTech Connect (OSTI)

    Wu, Sangwook

    2005-05-01

    The main purpose of this work is to investigate the glassy behavior of microemulsions and block copolymers. The origin of glassy behavior in microemulsions and block copolymers is frustration due to a competition between short-range interaction and long range interaction. According to the charge frustrated Ising model, the competition between ferromagnetic interaction and antiferromagnetic interaction is the origin of frustration in microemulsions. The competition between entropic effects and stoichiometric constraints responsible for the formation of micelles in microemulsions can lead to the emergence of a self generated glassy behavior in these systems. In the block copolymer, the competition between the repulsive short range interaction between monomers in polymer chains and the long range interaction by chemical bonds can lead to the emergence of a self generated glassy behavior. The criteria for the fluctuation induced first order transition and our microemulsion and block copolymer glasses are essentially the same. Both are a consequence of the large phase space of low energy excitations (14) (62) (all states with momenta q which fulfill |q| = q{sub m}) and are of at the most a moderate supercooling of the liquid state is required. This is strongly supported by the observation in Ref. (14) that the metastable states which are first to appear at a fluctuation induced first order transition are the ones build by a superposition of large amplitude waves of wavenumber q{sub m}, but with random orientations and phases, i.e. just the ones which form the metastable states of our microemulsion and block copolymer glass. (38)

  6. West Delta Block 35 - rediscovery of a 23-year-old field

    SciTech Connect (OSTI)

    Coburn, G.W.; Beeney, K.E. )

    1993-09-01

    The federal leases on the continental shelf, offshore Gulf of Mexico, are mature in terms of development. Many fields are reaching their productive and/or economic limits as defined by their operators and are being released, resulting in excellent opportunities for independents who recognize the importance of modern technology and apply it to their evaluation process. West Delta Block 35 originally was divided into two leases. The northern one-quarter and the southern three-quarters were combined and the entire block was available at the 1992 lease sale. The West Delta Block 35 was evaluated using the following methods: history (leases, companies involved, and changing economic conditions); well records (production, tests, recompletions.previous permits, and related activity); well-log evaluation, including (1) correlation, (2) analysis using PC-based software with user-defined saturation equations and multiple models to determine hydrocarbon-bearing zones, and (3) integration with all other available data; seismic evaluation, including (1) interpretation using workstation technology, (2) modeling various horizons using well data, (3) integration with well-log data; reservoir evaluation (pressure data, sand parameters, volumetrics, etc.). It was determined that significant reserves remained in an updip position on the northern one-quarter of the block in two reservoirs, with an additional reservoir having been penetrated but never produced. Additional potential on the southern part of the block was also recognized. The lease was acquired in the 1992 lease sale and the northern prospect was drilled in late 1992 and early 1993. The well found pay in three sands. Two sands were tested (prior to acidization) for a combined rate of 12.8 MMCFD, with the well still cleaning up. The well proved significant reserves in two previously produced reservoirs and added a new field pay.

  7. Synthesis and Characterization of Stimuli Responsive Block Copolymers, Self-Assembly Behavior and Applications

    SciTech Connect (OSTI)

    Michael Duane Determan

    2005-12-17

    The central theme of this thesis work is to develop new block copolymer materials for biomedical applications. While there are many reports of stimuli-responsive amphiphilic [19-21] and crosslinked hydrogel materials [22], the development of an in situ gel forming, pH responsive pentablock copolymer is a novel contribution to the field, Figure 1.1 is a sketch of an ABCBA pentablock copolymer. The A blocks are cationic tertiary amine methacrylates blocked to a central Pluronic F127 triblock copolymer. In addition to the prerequisite synthetic and macromolecular characterization of these new materials, the self-assembled supramolecular structures formed by the pentablock were experimentally evaluated. This synthesis and characterization process serves to elucidate the important structure property relationships of these novel materials, The pH and temperature responsive behavior of the pentablock copolymer were explored especially with consideration towards injectable drug delivery applications. Future synthesis work will focus on enhancing and tuning the cell specific targeting of DNA/pentablock copolymer polyplexes. The specific goals of this research are: (1) Develop a synthetic route for gel forming pentablock block copolymers with pH and temperature sensitive properties. Synthesis of these novel copolymers is accomplished with ATRP, yielding low polydispersity and control of the block copolymer architecture. Well defined macromolecular characteristics are required to tailor the phase behavior of these materials. (2) Characterize relationship between the size and shape of pentablock copolymer micelles and gel structure and the pH and temperature of the copolymer solutions with SAXS, SANS and CryoTEM. (3) Evaluate the temperature and pH induced phase separation and macroscopic self-assembly phenomenon of the pentablock copolymer. (4) Utilize the knowledge gained from first three goals to design and formulate drug delivery formulations based on the multi

  8. Dilute Group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2012-07-31

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  9. Dilute group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2015-02-24

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  10. Block copolymer with simultaneous electric and ionic conduction for use in lithium ion batteries

    DOE Patents [OSTI]

    2013-10-08

    Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction. A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO.sub.4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.