National Library of Energy BETA

Sample records for global ozone depletion

  1. Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2,

    E-Print Network [OSTI]

    Jackman, Charles H.

    Revised UV absorption spectra, ozone depletion potentials, and global warming potentials for the ozone-depleting substances CF2Br2, CF2ClBr, and CF2BrCF2Br Dimitrios K. Papanastasiou,1,2,5 Nabilah. [1] The contribution of Halons, bromine-containing haloalkanes, to stratospheric ozone depletion

  2. Nuclear conflict and ozone depletion Quick summary

    E-Print Network [OSTI]

    Toohey, Darin W.

    Nuclear conflict and ozone depletion Quick summary o Regional nuclear war could cause global which traps pollutants o Nuclear weapons cause explosions, which then causes things around the vicinity to start burning, which in turn releases black carbon; it is not the nuclear material or fallout causing

  3. Ozone Depletion 2. O 3 generation and depletion

    E-Print Network [OSTI]

    Schofield, Jeremy

    Ozone Depletion Outline: 1. O 3 , O 2 evolution 2. O 3 generation and depletion 3. Antarctic ozone 2 converted to ozone via: O 2 h#23; ! 2O #3; O #3; +O 2 ! O 3 + heat #15; O 3 absorbs near #21;#1;l #15; Decreasing l increases transmittance Imagine all ozone in atmosphere forming a thin layer

  4. Is the Ozone Depletion Regime a Model for an Emerging Regime on Global Warming?

    E-Print Network [OSTI]

    Lang, Winfried

    1991-01-01

    the for- mation of a global warming regime produces a highlydepletion and the global warming regimes was recognized byan Emerging Regime on Global Warming? by Winfried Lang I.

  5. Fundamental differences between Arctic and Antarctic ozone depletion

    E-Print Network [OSTI]

    Solomon, Susan

    Antarctic ozone depletion is associated with enhanced chlorine from anthropogenic chlorofluorocarbons and heterogeneous chemistry under cold conditions. The deep Antarctic “hole” contrasts with the generally weaker depletions ...

  6. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  7. Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer

    E-Print Network [OSTI]

    Oppenheimer, Michael

    Learning about ozone depletion Paul J. Crutzen & Michael Oppenheimer Received: 12 January 2007 ozone depletion has been much studied as a case history in the interaction between environmental science the photochemistry of ozone in order to illustrate how scientific learning has the potential to mislead policy makers

  8. 2, 921942, 2002 Global ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 921­942, 2002 Global ozone forecasting H. J. Eskes et al. Title Page Abstract Introduction Geophysical Society 2002 Atmospheric Chemistry and Physics Discussions Global ozone forecasting based on ERS-2 July 2002 Correspondence to: H. J. Eskes (eskes@knmi.nl) 921 #12;ACPD 2, 921­942, 2002 Global ozone

  9. Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment: Algorithm description and validation

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone profile and tropospheric ozone retrievals from the Global Ozone Monitoring Experiment October 2005. [1] Ozone profiles are derived from back scattered radiance spectra in the ultraviolet (289­339 nm) measured by the Global Ozone Monitoring Experiment (GOME) using the optimal estimation technique

  10. Impact of Antarctic Ozone Depletion and Recovery on Southern Hemisphere Precipitation, Evaporation, and Extreme Changes

    E-Print Network [OSTI]

    Son, Seok-Woo

    Impact of Antarctic Ozone Depletion and Recovery on Southern Hemisphere Precipitation, Evaporation) ABSTRACT The possible impact of Antarctic ozone depletion and recovery on Southern Hemisphere (SH) mean- tercomparison Project 3 (CMIP3). By grouping models into four sets, those with and without ozone depletion

  11. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  12. Terrestrial Ozone Depletion Due to a Milky Way Gamma-Ray Burst

    E-Print Network [OSTI]

    Brian C. Thomas; Charles H. Jackman; Adrian L. Melott; Claude M. Laird; Richard S. Stolarski; Neil Gehrels; John K. Cannizzo; Daniel P. Hogan

    2005-02-10

    Based on cosmological rates, it is probable that at least once in the last Gy the Earth has been irradiated by a gamma-ray burst in our Galaxy from within 2 kpc. Using a two-dimensional atmospheric model we have performed the first computation of the effects upon the Earth's atmosphere of one such impulsive event. A ten second burst delivering 100 kJ/m^2 to the Earth penetrates to the stratosphere and results in globally averaged ozone depletion of 35%, with depletion reaching 55% at some latitudes. Significant global depletion persists for over 5 years after the burst. This depletion would have dramatic implications for life since a 50% decrease in ozone column density results in approximately three times the normal UVB flux. Widespread extinctions are likely, based on extrapolation from UVB sensitivity of modern organisms. Additional effects include a shot of nitrate fertilizer and NO2 opacity in the visible providing a cooling perturbation to the climate over a similar timescale. These results lend support to the hypothesis that a GRB may have initiated the late Ordovician mass extinction (Melott et al. 2004).

  13. Ozone-depleting-substance control and phase-out plan

    SciTech Connect (OSTI)

    Nickels, J.M.; Brown, M.J.

    1994-07-01

    Title VI of the Federal Clean Air Act Amendments of 1990 requires regulation of the use and disposal of ozone-depleting substances (ODSs) (e.g., Halon, Freon). Several important federal regulations have been promulgated that affect the use of such substances at the Hanford Site. On April 23, 1993, Executive Order (EO) 12843, Procurement Requirements and Policies for Federal Agencies for Ozone-Depleting Substances (EPA 1993) was issued for Federal facilities to conform to the new US Environmental Protection Agency (EPA) regulations implementing the Clean Air Act of 1963 (CAA), Section 613, as amended. To implement the requirements of Title VI the US Department of Energy, Richland Operations Office (RL), issued a directive to the Hanford Site contractors on May 25, 1994 (Wisness 1994). The directive assigns Westinghouse Hanford Company (WHC) the lead in coordinating the development of a sitewide comprehensive implementation plan to be drafted by July 29, 1994 and completed by September 30, 1994. The implementation plan will address several areas where immediate compliance action is required. It will identify all current uses of ODSs and inventories, document the remaining useful life of equipment that contains ODS chemicals, provide a phase-out schedule, and provide a strategy that will be implemented consistently by all the Hanford Site contractors. This plan also addresses the critical and required elements of Federal regulations, the EO, and US Department of Energy (DOE) guidance. This plan is intended to establish a sitewide management system to address the clean air requirements.

  14. Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY

    E-Print Network [OSTI]

    Jackman, Charles H.

    Ozone depletion during the solar proton events of October//November 2003 as seen by SCIAMACHY G; revised 4 May 2005; accepted 13 May 2005; published 20 August 2005. [1] We use atmospheric ozone density profiles between 35 and 65 km altitude derived from SCIAMACHY limb measurements to quantify the ozone

  15. Ozone depletion, developing countries, and human rights: Seeking better ground on which to fight for protection of the ozone layer

    SciTech Connect (OSTI)

    Williams, V.

    1995-12-31

    I urge you not to take a complacent view of the situation. The state of depletion of the ozone layer continues to be alarming... In February, 1993, the ozone levels over North America and most of Europe were 20 percent below normal... Even now, millions of tons of CFC [chlorofluorocarbon] products are en route to their fatal stratospheric rendezvous... This exponential increase calls for increased reflection on the state of the ozone layer and calls for bold decisions.

  16. Ozone Depletion: Part 2 Antarctic Ozone Hole: Each spring, the ozone layer thins over the poles.

    E-Print Network [OSTI]

    Schofield, Jeremy

    via catalytic cycle: Under cold conditions, dimers ClO OCl form which are unstable in light. #3; Once concentration of ozone drops, reservoir reactions dominate and HCl and ClONO 2 reformed. #3; In antarctic spring

  17. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01

    2008. Learning about ozone depletion. Climatic Change 89(1–and Physics of Stratospheric Ozone. San Diego, CA: AcademicPhotochemical behavior of the ozone layer. Report Number

  18. http://www.yfes.tn.edu.tw/environment/main1.htm Global warming

    E-Print Network [OSTI]

    Chen, Yang-Yuan

    ; : #12; Global warming Stratospheric ozone depletion Acid deposition Deforestation Desertification Ocean

  19. A global picture of the seasonal persistence of stratospheric ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    A global picture of the seasonal persistence of stratospheric ozone anomalies Article Published persistence of stratospheric ozone anomalies. Journal of Geophysical Research, 115. D18119. ISSN 0148-0227 doi global picture of the seasonal persistence of stratospheric ozone anomalies S. Tegtmeier,1,2 V. E

  20. Assessing Global Terrestrial Sources of Methyl Halides - Ozone Regulating Gases 

    E-Print Network [OSTI]

    Gancarczyk, Maciej

    2010-11-24

    Methyl bromide (CH3Br) and methyl chloride (CH3Cl) play significant roles in the depletion of the stratospheric ozone layer. The vast portion of methyl halide sources and sinks sources and sinks are natural in origin. The ...

  1. D) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases

    E-Print Network [OSTI]

    Jackman, Charles H.

    O(1 D) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases Munkhbayar Baasandorj) and greenhouse gases (GHGs) is reaction with the O(1 D) atom. In this study, rate coefficients, k, for the O(1 D) and greenhouse gases (GHGs). Quantifying the atmospheric loss processes of ODSs and GHGs is essential

  2. A global inventory of ecosystem sources of methyl bromide, an ozone destroying gas 

    E-Print Network [OSTI]

    Fenney, Gareth

    2008-12-11

    Stratospheric ozone depletion is affected by halogen radicals, such as bromine, which is 40 times more effective at depleting ozone than chlorine. Methyl bromide, the largest contributor of bromine to the stratosphere is ...

  3. Distinguishing the impacts of ozone-depleting substances and well-mixed greenhouse gases on Arctic stratospheric ozone and temperature trends

    E-Print Network [OSTI]

    Rieder, Harald E.

    Whether stratospheric cooling due to increases in well-mixed greenhouse gases (WMGHG) could increase the depletion of Arctic stratospheric ozone has been the subject of scientific and public attention for decades. Here we ...

  4. Increasing global agricultural production by reducing ozone damages via methane emission controls and ozone-

    E-Print Network [OSTI]

    Mauzerall, Denise

    Increasing global agricultural production by reducing ozone damages via methane emission controls demonstrate the significant potential to sustainably improve global agricultural production by decreasing O3 degradation poses a major challenge for agricultural production. Because surface ozone (O3) has a significant

  5. An assessment of alternatives and technologies for replacing ozone- depleting substances at DOE facilities

    SciTech Connect (OSTI)

    Purcell, C.W.; Miller, K.B.; Friedman, J.R.; Rapoport, R.D.; Conover, D.R.; Hendrickson, P.L.; Koss, T.C.

    1992-10-01

    Title VI of the Clean Air Act, as amended, mandates a production phase-out for ozone-depleting substances (ODSs). These requirements will have a significant impact on US Department of Energy (DOE) facilities. Currently, DOE uses ODSs in three major activities: fire suppression (halon), refrigeration and cooling (chlorofluorocarbons [CFCs]), and cleaning that requires solvents (CFCs, methyl chloroform, and carbon tetrachloride). This report provides basic information on methods and strategies to phase out use of ODSs at DOE facilities.

  6. Effects of 20002050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone

    E-Print Network [OSTI]

    Wu, Shiliang

    Effects of 2000­2050 changes in climate and emissions on global tropospheric ozone and the policy-relevant background surface ozone in the United States Shiliang Wu,1 Loretta J. Mickley,1 Daniel J. Jacob,1 David Rind) on the global tropospheric ozone budget and on the policy-relevant background (PRB) ozone in the United States

  7. I. PROBLEM ADDRESSED In recent years, global warming, depleting conventional

    E-Print Network [OSTI]

    Ramakrishnan, Naren

    such as solar panels, wind turbines or diesel generators. Typically, and more so recently dueI. PROBLEM ADDRESSED In recent years, global warming, depleting conventional sources of energy physical and operational state, including environmental sensor data (e.g. temperature), operational state

  8. The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination

    E-Print Network [OSTI]

    Thompson, Anne

    iii ABSTRACT The NASA Aura satellite houses four instruments to study atmospheric ozone. The Ozone Monitoring Instrument (OMI) onboard the satellite provides global total column ozone (TCO) and in combination with other instruments tropospheric ozone residual (TOR) can be derived. In this study, the trajectory

  9. Ozone production efficiency and NOx depletion in an urban plume: Interpretation of field observations and implications for evaluating

    E-Print Network [OSTI]

    3 to a wide span of NOx and VOC emission changes. Properly constrained and well-evaluated modelsOzone production efficiency and NOx depletion in an urban plume: Interpretation of field observations and implications for evaluating O3-NOx-VOC sensitivity Rahul A. Zaveri,1 Carl M. Berkowitz,1

  10. Massive global ozone loss predicted following regional nuclear conflict

    E-Print Network [OSTI]

    Robock, Alan

    that nuclear war could be winnable, and preceded the first significant reductions in nuclear weapons stockpiles, the proliferation of nuclear weapons has produced greater risks of a regional nuclear conflict. At the same timeMassive global ozone loss predicted following regional nuclear conflict Michael J. Mills* , Owen B

  11. Why are there large differences between models in global budgets of tropospheric ozone?

    E-Print Network [OSTI]

    Wu, Shiliang

    Why are there large differences between models in global budgets of tropospheric ozone? Shiliang Wu for tropospheric ozone. The ozone production rate in the troposphere, P(Ox), varies from 2300 to 5300 Tg yrÀ1 compounds (NMVOCs, mostly biogenic isoprene), and ozone influx from stratosphere-troposphere exchange (STE

  12. The signature of ozone depletion on tropical temperature trends, as revealed by their seasonal cycle in model integrations with single forcings

    E-Print Network [OSTI]

    Polvani, Lorenzo M.

    [1] The effect of ozone depletion on temperature trends in the tropical lower stratosphere is explored with an atmospheric general circulation model, and directly contrasted to the effect of increased greenhouse gases and ...

  13. Global tropospheric ozone modeling: Quantifying errors due to grid resolution

    E-Print Network [OSTI]

    Wild, Oliver; Prather, Michael J

    2006-01-01

    by and influencing ozone in unpolluted tropospheric air,R. C. , et al. (2004), Ozone production in transpacificplumes and implications for ozone air quality in California,

  14. Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde column measurements

    E-Print Network [OSTI]

    Palmer, Paul

    Constraining global isoprene emissions with Global Ozone Monitoring Experiment (GOME) formaldehyde emission estimates are highly uncertain because of a lack of direct observations. Formaldehyde (HCHO the observation of this trace gas to help constrain isoprene emissions. We use HCHO column observations from

  15. Quantifying the contributions to stratospheric ozone changes from ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Quantifying the contributions to stratospheric ozone changes from ozone depleting substances., Reader, M. C. and Jonsson, A. I. (2010) Quantifying the contributions to stratospheric ozone changes from ozone depleting substances and greenhouse gases. Atmospheric Chemistry and Physics, 10. pp. 8803

  16. Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2

    E-Print Network [OSTI]

    Wu, Shiliang

    1 Sensitivity of China's ozone air quality to 2000-2050 global changes of1 climate and emissions2 3 the effect on China's ozone air quality from 2000-2050 global15 changes in climate and anthropogenic emissions of ozone precursors. The climate and16 emission effect in combination will increase afternoon mean

  17. A Large Ozone-Circulation Feedback & Its Implications for Global Warming Assessments

    E-Print Network [OSTI]

    Jackson, Sophie

    Peer A Large Ozone-Circulation Feedback & Its Implications for Global Warming Assessments PeerCO2, b T by 4xCO2, c T by O3 and d water vapour by O3. 4. GLOBAL WARMING RESPONSE 0 50 100 150 200 250) Figure 1 | Temporal evolution of the annual and global mean surface tem- perature anomalies. Interactive

  18. Global Health and Economic Impacts of Future Ozone Pollution

    E-Print Network [OSTI]

    Webster, Mort D.

    We assess the human health and economic impacts of projected 2000-2050 changes in ozone pollution using the MIT Emissions Prediction and Policy Analysis-Health Effects (EPPA-HE) model, in combination with results from the ...

  19. A large ozone-circulation feedback and its implications for global warming assessments

    E-Print Network [OSTI]

    Nowack, Peer J.; Abraham, N. Luke; Maycock, Amanda C.; Braesicke, Peter; Gregory, Jonathan M.; Joshi, Manoj M.; Osprey, Annette; Pyle, John A.

    2014-12-01

    -climate model, we find an increase in global mean surface warming of around 1°C (~20%) after 75 years when ozone is prescribed at pre-industrial levels compared with when it is allowed to evolve self-consistently in response to an abrupt 4xCO2 forcing...

  20. Global environmental change: Its nature and impact

    SciTech Connect (OSTI)

    Hidore, J.J.

    1996-12-31

    This book is intended as an entry-level textbook on environmental science for nonscience majors. Twenty chapters address topics from historical geology and climatic change to population dynamics, land-use, water pollution, ozone depletion and biodiversity, global warming.

  1. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01

    Global and zonal total ozone variations estimated fromon multidecadal total ozone simulations, J. Geophys. Res. ,and J. A. Logan (2007), Ozone climatolo- gical profiles for

  2. Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

    E-Print Network [OSTI]

    2011-01-01

    Part I: NO x , PAN and Ozone Relationships, J. Atmos.Bromine measurements in ozone depleted air over the Arcticto springtime tropospheric ozone maxima using TOPSE measure-

  3. 2, 339356, 2002 Surface ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 2, 339­356, 2002 Surface ozone depletion episodes D. W. Tarasick and J. W. Bottenheim Title ozone depletion episodes in the Arctic and Antarctic from historical ozonesonde records D. W. Tarasick.tarasick@ec.gc.ca) 339 #12;ACPD 2, 339­356, 2002 Surface ozone depletion episodes D. W. Tarasick and J. W. Bottenheim

  4. 5, 38113845, 2005 Antarctic ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al. Title Page Discussions Indicators of Antarctic ozone depletion G. E. Bodeker 1 , H. Shiona 1 , and H. Eskes 2 1 National Commons License. 3811 #12;ACPD 5, 3811­3845, 2005 Antarctic ozone depletion indicators G. E. Bodeker et al

  5. Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

  6. FTT:Power : A global model of the power sector with induced technological change and natural resource depletion

    E-Print Network [OSTI]

    Mercure, J -F

    2012-01-01

    This work introduces a model of Future Technology Transformations for the power sector (FTT:Power), a representation of global power systems based on market competition, induced technological change (ITC) and natural resource use and depletion. It is the first component of a family of sectoral bottom-up models of technology, designed for integration into the global macroeconometric model E3MG. ITC occurs as a result of technological learning produced by cumulative investment and leads to highly nonlinear, irreversible and path dependent technological transitions. The model uses a dynamic coupled set of logistic differential equations. As opposed to traditional bottom-up energy models based on systems optimisation, such differential equations offer an appropriate treatment of the times and structure of change involved in sectoral technology transformations, as well as a much reduced computational load. Resource use and depletion are represented by local cost-supply curves, which give rise to different regional...

  7. Running Out of and Into Oil: Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, D.L.

    2003-11-14

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value. Probability distributions are produced for the year in which conventional oil production peaks for the world as a whole and the year of peak production from regions outside the Middle East. Recent estimates of world oil resources by the United States Geological Survey (USGS), the International Institute of Applied Systems Analysis (IIASA), the World Energy Council (WEC) and Dr. C. Campbell provide alternative views of the extent of ultimate world oil resources. A model of oil resource depletion and expansion for twelve world regions is combined with a market equilibrium model of conventional and unconventional oil supply and demand to create a World Energy Scenarios Model (WESM). The model does not make use of Hubbert curves but instead relies on target reserve-to-production ratios to determine when regional output will begin to decline. The authors believe that their analysis has a bias toward optimism about oil resource availability because it does not attempt to incorporate political or environmental constraints on production, nor does it explicitly include geologic constraints on production rates. Global energy scenarios created by IIASA and WEC provide the context for the risk analysis. Key variables such as the quantity of undiscovered oil and rates of technological progress are treated as probability distributions, rather than constants. Analyses based on the USGS and IIASA resource assessments indicate that conventional oil production outside the Middle East is likely to peak sometime between 2010 and 2030. The most important determinants of the date are the quantity of undiscovered oil, the rate at which unconventional oil production can be expanded, and the rate of growth of reserves and enhanced recovery. Analysis based on data produced by Campbell indicates that the peak of non-Middle East production will occur before 2010. For total world conventional oil production, the results indicate a peak somewhere between 2020 and 2050. Key determinants of the peak in world oil production are the rate at which the Middle East region expands its output and the minimum reserves-to-production ratios producers will tolerate. Once world conventional oil production peaks, first oil sands and heavy oil from Canada, Venezuela and Russia, and later some other source such as shale oil from the United States must expand if total world oil consumption is to continue to increase. Alternative sources of liquid hydrocarbon fuels, such as coal or natural gas are also possible resources but not considered in this analysis nor is the possibility of transition to a hydrogen economy. These limitations were adopted to simplify the transition analysis. Inspection of the paths of conventional oil production indicates that even if world oil production does not peak before 2020, output of conventional oil is likely to increase at a substantially slower rate after that date. The implication is that there will have to be increased production of unconventional oil after that date if world petroleum consumption is to grow.

  8. Global warming and the challenge of international cooperation: An interdisciplinary assessment

    SciTech Connect (OSTI)

    Bryner, G.C.

    1995-07-01

    This book focuses on ozone depletion first, global warming second. It is a collection of perspectives from a variety of disciplines and includes a limited amount of technical assessment information.

  9. Running Out Of and Into Oil. Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, David L.; Hopson, Janet L.; Li, Jia

    2003-10-01

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value.

  10. Use of North American and European air quality networks to evaluate global chemistry-climate modeling of surface ozone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schnell, J. L.; Prather, M. J.; Josse, B.; Naik, V.; Horowitz, L. W.; Cameron-Smith, P.; Bergmann, D.; Zeng, G.; Plummer, D. A.; Sudo, K.; et al

    2015-04-16

    We test the current generation of global chemistry-climate models in their ability to simulate observed, present-day surface ozone. Models are evaluated against hourly surface ozone from 4217 stations in North America and Europe that are averaged over 1° × 1° grid cells, allowing commensurate model-measurement comparison. Models are generally biased high during all hours of the day and in all regions. Most models simulate the shape of regional summertime diurnal and annual cycles well, correctly matching the timing of hourly (~ 15:00) and monthly (mid-June) peak surface ozone abundance. The amplitude of these cycles is less successfully matched. The observedmore »summertime diurnal range (~ 25 ppb) is underestimated in all regions by about 7 ppb, and the observed seasonal range (~ 21 ppb) is underestimated by about 5 ppb except in the most polluted regions where it is overestimated by about 5 ppb. The models generally match the pattern of the observed summertime ozone enhancement, but they overestimate its magnitude in most regions. Most models capture the observed distribution of extreme episode sizes, correctly showing that about 80% of individual extreme events occur in large-scale, multi-day episodes of more than 100 grid cells. The observed linear relationship showing increases in ozone by up to 6 ppb for larger-sized episodes is also matched.« less

  11. Use of North American and European air quality networks to evaluate global chemistry–climate modeling of surface ozone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schnell, J. L.; Prather, M. J.; Josse, B.; Naik, V.; Horowitz, L. W.; Cameron-Smith, P.; Bergmann, D.; Zeng, G.; Plummer, D. A.; Sudo, K.; et al

    2015-09-25

    We test the current generation of global chemistry–climate models in their ability to simulate observed, present-day surface ozone. Models are evaluated against hourly surface ozone from 4217 stations in North America and Europe that are averaged over 1° × 1° grid cells, allowing commensurate model–measurement comparison. Models are generally biased high during all hours of the day and in all regions. Most models simulate the shape of regional summertime diurnal and annual cycles well, correctly matching the timing of hourly (~ 15:00 local time (LT)) and monthly (mid-June) peak surface ozone abundance. The amplitude of these cycles is less successfullymore »matched. The observed summertime diurnal range (~ 25 ppb) is underestimated in all regions by about 7 ppb, and the observed seasonal range (~ 21 ppb) is underestimated by about 5 ppb except in the most polluted regions, where it is overestimated by about 5 ppb. The models generally match the pattern of the observed summertime ozone enhancement, but they overestimate its magnitude in most regions. Most models capture the observed distribution of extreme episode sizes, correctly showing that about 80 % of individual extreme events occur in large-scale, multi-day episodes of more than 100 grid cells. The models also match the observed linear relationship between episode size and a measure of episode intensity, which shows increases in ozone abundance by up to 6 ppb for larger-sized episodes. We conclude that the skill of the models evaluated here provides confidence in their projections of future surface ozone.« less

  12. Green house gases Ozone depletion

    E-Print Network [OSTI]

    Zevenhoven, Ron

    · Advantages ­ CO2 at high partial pressures ­ Solvent scrubbing is proven technology ­ Benefits from improved ­ Gasification is quite different from combustion ­ Not widely demonstrated, reliability is an issue Coal Coal preparation gasification O2 gas cooling and clean-up H2O gas shift H2S, CO2 removal synthesis separation

  13. Oceanic alkyl nitrates as a natural source of tropospheric ozone

    E-Print Network [OSTI]

    Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

    2008-01-01

    Chemical transport model ozone simulations for spring 2001ozonesondes, and Total Ozone Mapping Spectrometer columns,behaviour of tropospheric ozone precursors in a global 3-D

  14. Zevenhoven & Kilpinen Greenhouse Gases, Ozone-Depleting Gases 19.6.2001 9-1 Figure 9.1 Increasing world population

    E-Print Network [OSTI]

    Zevenhoven, Ron

    ), methane (CH4) and nitrous oxide (N2O) trap the outgoing solar radiation that is reflected by the earth by blocking "hard" ultraviolet solar radiation. #12;Zevenhoven & Kilpinen Greenhouse Gases, Ozone by using experimental data from e.g. air trapped in polar ice. CO2 concentrations started to rise in ~1800

  15. Narrowband filter radiometer for ground-based measurements of global ultraviolet solar irradiance and total ozone

    SciTech Connect (OSTI)

    Petkov, Boyan; Vitale, Vito; Tomasi, Claudio; Bonafe, Ubaldo; Scaglione, Salvatore; Flori, Daniele; Santaguida, Riccardo; Gausa, Michael; Hansen, Georg; Colombo, Tiziano

    2006-06-20

    The ultraviolet narrowband filter radiometer (UV-RAD) designed by the authors to take ground-based measurements of UV solar irradiance, total ozone, and biological dose rate is described, together with the main characteristics of the seven blocked filters mounted on it, all of which have full widths at half maxima that range 0.67 to 0.98 nm. We have analyzed the causes of cosine response and calibration errors carefully to define the corresponding correction terms, paying particular attention to those that are due to the spectral displacements of the filter transmittance peaks from the integer wavelength values. The influence of the ozone profile on the retrieved ozone at large solar zenith angles has also been examined by means of field measurements. The opportunity of carrying out nearly monochromatic irradiance measurements offered by the UV-RAD allowed us to improve the procedure usually followed to reconstruct the solar spectrum at the surface by fitting the computed results, using radiative transfer models with field measurements of irradiance. Two long-term comparison campaigns took place, showing that a mean discrepancy of+0.3% exists between the UV-RAD total ozone values and those given by the Brewer no. 63 spectroradiometer and that mean differences of+0.3% and-0.9% exist between the erythemal dose rates determined with the UV-RAD and those obtained with the Brewer no. 63 and the Brewer no. 104 spectroradiometers, respectively.

  16. Atmospheric ozone and colors of the Antarctic twilight sky

    E-Print Network [OSTI]

    Lee Jr., Raymond L.

    Atmospheric ozone and colors of the Antarctic twilight sky Raymond L. Lee, Jr.,1, * Wolfgang Meyer absorption at longer wavelengths by ozone's Chappuis bands. Because stratospheric ozone is greatly depleted correlations between ozone concentration and twilight colors. We also used a spectroradiometer at a midlatitude

  17. Ozone Climatologies Figure 1: Ozone climatology for control run in kg/m(a), percentage change in

    E-Print Network [OSTI]

    Feigon, Brooke

    Ozone Climatologies (a) (b) (c) Figure 1: Ozone climatology for control run in kg/m³(a), percentage change in ozone for the perturbed runs; tropopause region (b), whole stratosphere (c). Determining the impact of lower stratospheric ozone depletion on Southern Hemisphere climate Sarah P.E. Keeley and Nathan

  18. Assimilation of Aura ozone data

    E-Print Network [OSTI]

    Assimilation of Aura ozone data I. Stajner, H. Hayashi, K. Wargan, L.-P. Chang, and S. Pawson Global Modeling and Assimilation Office (GMAO) NASA/Goddard AGU Fall meeting December 2004 #12;2 Ozone assimilation at GMAO · Total ozone columns and stratospheric profiles from SBUV/2 instrument are assimilated

  19. Projected changes in global tropospheric ozone to 2030 David Stevenson, Institute for Meteorology, University of Edinburgh

    E-Print Network [OSTI]

    Stevenson, David

    ,000 Lagrangian air parcels, and simulates 70 species with 160 reactions. It has an output resolution of 5° x 5° x much of the troposphere, often reinforcing the existing spring maximum. Tateno Japan36°N Hilo Hawaii20 globally. Emissions controls have been used successfully to reduce peak O3 values seen during pollution

  20. Replacement of chlorofluorocarbons at the DOE gaseous diffusion plants: An assessment of global impacts

    SciTech Connect (OSTI)

    Socolof, M.L.; McCold, L.N.; Saylor, R.E.

    1997-01-01

    Three gaseous diffusion plants (GDPs) for enriching uranium maintain a large inventory of chlorofluorocarbon-114 (CFC-114) as a coolant. To address the continued use of CFC-114, an ozone-depleting substance, the US Department of Energy (DOE) considered introducing perfluorocarbons (PFCs) by the end of 1995. These PFCs would not contribute to stratospheric ozone depletion but would be larger contributors to global warming than would CFC-114. The paper reports the results of an assessment of the global impacts of four alternatives for modifying GDP coolant system operations over a three-year period beginning in 1996. The overall contribution of GDP coolant releases to impacts on ozone depletion and global warming were quantified by parameters referred to as ozone-depletion impact and global-warming impact. The analysis showed that these parameters could be used as surrogates for predicting global impacts to all resources and could provide a framework for assessing environmental impacts of a permanent coolant replacement, eliminating the need for subsequent resource-specific analyses.

  1. Global warming impacts of ozone-safe refrigerants and refrigeration, heating, and air-conditioning technologies

    SciTech Connect (OSTI)

    Fischer, S.; Sand, J.; Baxter, V.

    1997-12-01

    International agreements mandate the phase-out of many chlorine containing compounds that are used as the working fluid in refrigeration, air-conditioning, and heating equipment. Many of the chemical compounds that have been proposed, and are being used in place of the class of refrigerants eliminated by the Montreal Protocol are now being questioned because of their possible contributions to global warming. Natural refrigerants are put forth as inherently superior to manufactured refrigerants because they have very low or zero global warming potentials (GWPs). Questions are being raised about whether or not these manufactured refrigerants, primarily hydrofluorocarbons (HFCs), should be regulated and perhaps phased out in much the same manner as CFCs and HCFCs. Several of the major applications of refrigerants are examined in this paper and the results of an analysis of their contributions to greenhouse warming are presented. Supermarket refrigeration is shown to be an application where alternative technologies have the potential to reduce emissions of greenhouse gases (GHG) significantly with no clear advantage to either natural or HFC refrigerants. Mixed results are presented for automobile air conditioners with opportunities to reduce GHG emissions dependent on climate and comfort criteria. GHG emissions for hermetic and factory built systems (i.e. household refrigerators/freezers, unitary equipment, chillers) are shown to be dominated by energy use with much greater potential for reduction through efficiency improvements than by selection of refrigerant. The results for refrigerators also illustrate that hydrocarbon and carbon dioxide blown foam insulation have lower overall effects on GHG emissions than HFC blown foams at the cost of increased energy use.

  2. Past and Future Effects of Ozone on Net Primary Production and Carbon Sequestration Using a Global Biogeochemical Model

    E-Print Network [OSTI]

    Felzer, Benjamin Seth.

    Exposure of plants to ozone inhibits photosynthesis and therefore reduces vegetation production and carbon sequestration. Simulations with the Terrestrial Ecosystem Model (TEM) for the historical period (1860-1995) show ...

  3. Process Modeling of Global Soil Nitrous Oxide Emissions

    E-Print Network [OSTI]

    Saikawa, E.

    2011-09-01

    Nitrous oxide is an important greenhouse gas and is a major ozone-depleting substance. To understand and

  4. Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion

    Office of Scientific and Technical Information (OSTI)

    sprays went into effect first in the United States in 1978, and later in Canada, Norway, and Sweden. ... Over the years evidence mounted in support of Molina's theories,...

  5. Mario Molina, Chlorofluorocarbons (CFCs), and Ozone Depletion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousandReport)PriceHistoricEnergyApril 25,4Mario Molina,

  6. Could the Earth's surface Ultraviolet irradiance be blamed for the global warming? (II) ----Ozone layer depth reconstruction via HEWV effect

    E-Print Network [OSTI]

    Chen, Jilong; Zheng, Yujun

    2014-01-01

    It is suggested by Chen {\\it et al.} that the Earth's surface Ultraviolet irradiance ($280-400$ nm) could influence the Earth's surface temperature variation by "Highly Excited Water Vapor" (HEWV) effect. In this manuscript, we reconstruct the developing history of the ozone layer depth variation from 1860 to 2011 based on the HEWV effect. It is shown that the reconstructed ozone layer depth variation correlates with the observational variation from 1958 to 2005 very well ($R=0.8422$, $P>99.9\\%$). From this reconstruction, we may limit the spectra band of the surface Ultraviolet irradiance referred in HEWV effect to Ultraviolet B ($280-320$ nm).

  7. Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1

    E-Print Network [OSTI]

    Son, Seok-Woo

    Ozone hole and Southern Hemisphere climate change Seok-Woo Son,1 Neil F. Tandon,2 Lorenzo M cooling resulting from ozone depletion has only recently been examined and a comprehensive picture on the stratospheric ozone forcing used, we here show that stratospheric ozone affects the entire atmospheric

  8. Past changes in the vertical distribution of ozone – Part 3: Analysis and interpretation of trends

    E-Print Network [OSTI]

    Harris, N. R. P.; Hassler, B.; Tummon, F.; Bodeker, G. E.; Hubert, D.; Petropavlovskikh, I.; Steinbrecht, W.; Anderson, J.; Bhartia, P. K.; Boone, C. D.; Bourassa, A.; Davis, S. M.; Degenstein, D.; Delcloo, A.; Frith, S. M.; Froidevaux, L.; Godin-Beekmann, S.; Jones, N.; Kurylo, M. J.; Kyrölä, E.; Laine, M.; Leblanc, S. T.; Lambert, J.-C.; Liley, B.; Mahieu, E.; Maycock, A.; de Mazière, M.; Parrish, A.; Querel, R.; Rosenlof, K. H.; Roth, C.; Sioris, C.; Staehelin, J.; Stolarski, R. S.; Stübi, R.; Tamminen, J.; Vigouroux, C.; Walker, K.; Wang, H. J.; Wild, J.; Zawodny, J. M.

    2015-03-23

    Trends in the vertical distribution of ozone are reported and compared for a number of new and recently revised datasets. The amount of ozone-depleting compounds in the stratosphere (as measured by Equivalent Effective Stratospheric Chlorine – EESC...

  9. 6, 43254340, 2006 Scaling in ozone and

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title Chemistry and Physics Discussions Long-memory processes in global ozone and temperature variations C #12;ACPD 6, 4325­4340, 2006 Scaling in ozone and temperature C. Varotsos and D. Kirk-Davidoff Title

  10. Speeding up Ozone Profile Retrieval using Machine Learning Techniques

    E-Print Network [OSTI]

    Emmerich, Michael

    Speeding up Ozone Profile Retrieval using Machine Learning Techniques L.M. Strijbosch April 25 to the process of ozone profile retrieval, a method for retrieving a global ozone distribution from satellite Machines are selected to replace the forward model, which is the slowest part of ozone profile retrieval

  11. Global Economic Effects of Changes in Crops, Pasture, and Forests due to Changing Climate, Carbon Dioxide, and Ozone

    E-Print Network [OSTI]

    Reilly, John M.

    Multiple environmental changes will have consequences for global vegetation. To the extent that crop yields and pasture and forest productivity are affected there can be important economic consequences. We examine the ...

  12. Separating the Influence of Halogen and Climate Changes on Ozone Recovery in the Upper Stratosphere

    E-Print Network [OSTI]

    causes ozone destruction by enhancing production of water vapor via methane oxidation. Additionally. Including potential climate-induced stratospheric water vapor increases, the ozone change relative to 1980 depletion chemistry, and therefore indirectly leading to more ozone. Increases in methane directly affect

  13. 17 October 2014 Antarctic Ozone Bulletin

    E-Print Network [OSTI]

    Toohey, Darin W.

    17 October 2014 Antarctic Ozone Bulletin No 4/2014 Global Atmosphere Watch 0 5 10 0 5 10 15 20 25 30 -80 -60 -40 -20 0 Ushuaia 2014-10-10 Total ozone = 180 DU 14-21 km column = 39 DU 12-20 km column = 53 DU Ozone Temperature ECMWF analysis of PV at 475 K on 2014-10-10 at 12h -65.0 -59.5 -54.0 -48

  14. Depleted Uranium Technical Brief

    E-Print Network [OSTI]

    Depleted Uranium Technical Brief United States Environmental Protection Agency Office of Air and Radiation Washington, DC 20460 EPA-402-R-06-011 December 2006 #12;#12;Depleted Uranium Technical Brief EPA of Radiation and Indoor Air Radiation Protection Division ii #12;iii #12;FOREWARD The Depleted Uranium

  15. Ranking* Category Aspect Normal Abnormal Emergency Impact Description Impact Comment High Water & energy Water consumption 7 (Neg) 7 (Neg) 7 (Neg) Water resource depletion. Use of chlorine / ozone in treatment and potential risk of damage to human health

    E-Print Network [OSTI]

    Sussex, University of

    2 saving vis-à-vis national grid supplied electricity (20% electricity generation from CHP and global warming resulting in sea level rise, changing weather patterns, increased incidence of pest electrical & electronic equipment (WEEE) 7 (Neg) 7 (Neg) 7 (Neg) Breaches of environmental legislation. Human

  16. One: Microphysics of frost metamorphism: Applications to Triton and Mars. Two: A global analysis of the ozone deficit in the upper stratosphere and lower mesosphere. Three: The diabatic circulation in the stratosphere as diagnosed from Microwave Limb Sounder data

    SciTech Connect (OSTI)

    Eluszkiewicz, J.B.

    1993-01-01

    The present thesis is devoted to two broad subjects, planetary frost metamorphism and the terrestrial middle atmosphere, and consists of three papers. Paper 1 considers frost metamorphism on the surfaces of Triton and Mars. Based on an analysis of the microphysical processes involved in the pressureless sintering, it is concluded that fine-grained nitrogen and carbon dioxide frosts can undergo seasonal metamorphism into semitransparent layers on the surface of Triton and in the Martian seasonal polar caps, respectively. The presence of such layers explains a host of facts about Triton's surface and about the Martian seasonal caps. Paper 2 is devoted to elucidating a long-standing issue in the terrestrial middle atmosphere chemistry, the so-called 'ozone deficit problem.' Based on an analysis of data acquired by the Limb Infrared Monitor of the Stratosphere (LIMS) instrument between October 1978 and May 1979, it is concluded that current photochemical models systematically underestimate observed ozone abundances in the upper stratosphere and lower mesosphere. Three modifications to the accepted photochemical scheme, capable of providing a global solution to this problem, are proposed and discussed. Paper 3 differs from the other two in that it reports on results from an ongoing research effort. It considers the diabatic circulation in the stratosphere and lower mesosphere, using ozone and temperature measurements acquired by the Microwave Limb Sounder (MLS) instrument onboard the Upper Atmosphere Research Satellite (UARS). The present study extends past analyses of the diabatic circulation by considering a full annual cycle, November 1991-November 1992, and by taking advantage of the high vertical resolution of MLS data. In the tropical upper stratosphere and lower mesosphere, a semiannual oscillation (SAO) is observed in the computed circulation, with the region of downwelling reaching maximum spatial extent approximately 1 month before the equinox.

  17. EARTH OBSERVATION 400M Indians Endangered By Ozone

    E-Print Network [OSTI]

    Singh, Ramesh P.

    has been linked to increases in skin cancer rates. All rights reserved. © 2004 United Press using satellite and limited ground observations, the Press Trust of India reported Tuesday. The rate the reasons for the depletion, th e report states. Ozone is an important atmospheric trace gas that blocks

  18. Global

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUseful LinksGlass Stronger thanGlenn T.4Global

  19. Managing the global environmental risks in Russia: The missing links and external influences

    SciTech Connect (OSTI)

    Sokolov, V.

    1996-12-31

    Based on analysis of management history of three global environmental issues in Russia--climate change, ozone depletion and acid rains--the author suggests a few explanations of failure to build-up the nationwide strategy to manage global risks. Among them are specific factors related to the science-policy relationship on global changes processes and impacts. Particular attention is given to such internal factors as: the monopolization of these issues by the single state agency Hydromet until the late 1980s; the interest of the Soviet military in global atmospheric issues; the absence of any major input from the public or the media; and the manner in which the discussion of these issues was nested within the Soviet government`s broader foreign policy agenda.

  20. The Ozone Hole Some perspective

    E-Print Network [OSTI]

    Toohey, Darin W.

    The Ozone Hole · Some perspective · The British Antarctic Survey · The "Ozone Hole" · International of the predicted ozone losses! This was quite a controversy. Ultimately, ozone losses started appearing in the late 1980s (see Figure below), but by then, there was already a credibility issue for ozone scientists. #12

  1. Midlatitude Ozone: Loss and Trends

    E-Print Network [OSTI]

    Toohey, Darin W.

    1 Lecture 17 Midlatitude Ozone: Loss and Trends ATOC/CHEM 5151 #12;2 Importance of midlatitude ozone · Covers most of the world's populated areas · Provides protection from UV #12;3 Ozone loss picture, c. 1988 #12;4 Lower vs. Upper stratosphere #12;5 Ozone loss, post 1988 · Discovery of ozone hole

  2. 6, 74277469, 2006 Linear ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 7427­7469, 2006 Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Chemistry and Physics Discussions Evaluation of linear ozone photochemistry parametrizations Linear ozone photochemistry parametrizations A. J. Geer et al. Title Page Abstract Introduction

  3. The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations on an accurate potential energy surface

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The vibrational energies of ozone up to the dissociation threshold: Dynamics calculations present an ab initio potential energy surface for the ground electronic state of ozone. It is global, i. All bound states of nonrotating ozone up to more than 99% of the dissociation energy are calculated

  4. Seasonal ozone variations in the upper mesosphere

    SciTech Connect (OSTI)

    Thomas, R.J. (Univ. of Colorado, Boulder (United States))

    1990-05-20

    The global daytime ozone was measured by the Solar Mesosphere Explorer satellite (SME) for 5 years. The measurements extend through the mesosphere, covering from 50 km to over 90 km. The ozone in the upper mesosphere varies annually by up to a factor of 3. The observed seasonal variations may be summarized in several different ways. From year to year there is a great deal of repeatability of these variations. This repeatability occurs in most of the upper mesosphere outside the tropics. Near 0.01 mbar (80 km) the mid- and high-latitude mixing ratio peaks each year in mid-April. A secondary maximum in the altitude profile of ozone density usually occurs near 85 km. Changes in this structure are directly related to the April maximum and other seasonal changes seen at 0.01 mbar. The changing seasonal structure produces a bump at the ozone mixing ratio minimum that is largest just after spring equinox. This perturbation to the mixing ratio profile seems to move upward during the first half of the year. The seasonal changes of ozone were analyzed in terms of annual and semiannual structure. The variations generally have both an annual and semiannual component depending on altitude and latitude. The phases of the variations change quickly with both altitude and latitude. The semiannual component peaks in April, over most of the upper mesosphere.

  5. Validation of operational ozone profiles from the Ozone Monitoring Instrument

    E-Print Network [OSTI]

    Validation of operational ozone profiles from the Ozone Monitoring Instrument M. Kroon,1 J. F. de we present the validation results of the operational vertical ozone profiles retrieved from the nadir observations by the Ozone Monitoring Instrument (OMI) aboard the NASA Earth Observing System (EOS) Aura

  6. Modeling international cooperation for the global environmental problematique

    SciTech Connect (OSTI)

    Sadeh, E.

    1997-12-31

    The focus of this study is on international cooperative decision-making related to global change issues concerning stratospheric ozone depletion and global climate warming. Such anthropogenic alteration of the Earth`s biosphere has given rise to a global environmental problematique that is demarcated by two dimensions. The first dimension is that global environmental Issues are demarcated by international environmental commons. Commons are defined as physical or biological systems that lie outside the jurisdiction of any individual state and are valued environmental resources globally. A second dimension pertains to tile collective action problem which results from a {open_quotes}tragedy of the commons.{close_quotes} According to traditional realist conception of international relations, that states behave in their rational self-interest, a {open_quotes}tragedy of the commons{close_quotes} ensues. The tragedy is a function of damage to the global environment, such as the production of economic resources that release greenhouse gases into the Earth`s biosphere, that is nonappropriable. Commons resources relative to the Earth`s biosphere are not limitless. At issue, is the realization of sustainable economic development promoted by cooperative political patterns that mitigate the negative consequences of this tragedy.

  7. Projections of Future Summertime Ozone over the U.S.

    SciTech Connect (OSTI)

    Pfister, G. G.; Walters, Stacy; Lamarque, J. F.; Fast, Jerome D.; Barth, Mary; Wong, John; Done, James; Holland, Greg; Bruyere, Cindy

    2014-05-05

    This study uses a regional fully coupled chemistry-transport model to assess changes in surface ozone over the summertime U.S. between present and a 2050 future time period at high spatial resolution (12 km grid spacing) under the SRES A2 climate and RCP8.5 anthropogenic pre-cursor emission scenario. The impact of predicted changes in climate and global background ozone is estimated to increase surface ozone over most of the U.S; the 5th - 95th percentile range for daily 8-hour maximum surface ozone increases from 31-79 ppbV to 30-87 ppbV between the present and future time periods. The analysis of a set of meteorological drivers suggests that these mostly will add to increasing ozone, but the set of simulations conducted does not allow to separate this effect from that through enhanced global background ozone. Statistically the most robust positive feedbacks are through increased temperature, biogenic emissions and solar radiation. Stringent emission controls can counteract these feedbacks and if considered, we estimate large reductions in surface ozone with the 5th-95th percentile reduced to 27-55 ppbV. A comparison of the high-resolution projections to global model projections shows that even though the global model is biased high in surface ozone compared to the regional model and compared to observations, both the global and the regional model predict similar changes in ozone between the present and future time periods. However, on smaller spatial scales, the regional predictions show more pronounced changes between urban and rural regimes that cannot be resolved at the coarse resolution of global model. In addition, the sign of the changes in overall ozone mixing ratios can be different between the global and the regional predictions in certain regions, such as the Western U.S. This study confirms the key role of emission control strategies in future air quality predictions and demonstrates the need for considering degradation of air quality with future climate change in emission policy making. It also illustrates the need for high resolution modeling when the objective is to address regional and local air quality or establish links to human health and society.

  8. NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY

    E-Print Network [OSTI]

    vi NARSTO OZONE ASSESSMENT EXECUTIVE SUMMARY Prepared as a NARSTO initiative, this tropospheric O3 in the accompanying Textbox, the NARSTO Ozone Assessment contains two product components. The first of these is a set aspects of tropospheric ozone pollution. The second component, the NARSTO Ozone Assessment Document

  9. Artificial ozone holes

    E-Print Network [OSTI]

    S. N. Dolya

    2014-10-18

    This article considers an opportunity of disinfecting a part of the Earth surface, occupying a large area of ten thousand square kilometers. The sunlight will cause dissociation of molecular bromine into atoms; each bromine atom kills thirty thousand molecules of ozone. Each bromine plate has a mass of forty milligrams grams and destroys ozone in the area of hundred square meters. Thus, to form the ozone hole over the area of ten thousand square kilometers, it is required to have the total mass of bromine equal to the following four tons.

  10. Groundwater depletion in the Middle East from GRACE with implications for transboundary water management in the Tigris-Euphrates-Western Iran region

    E-Print Network [OSTI]

    Voss, Katalyn A; Famiglietti, James S; Lo, MinHui; de Linage, Caroline; Rodell, Matthew; Swenson, Sean C

    2013-01-01

    Wilson (2007), Estimating groundwater storage changes in theGlobal depletion of groundwater resources, Geophys. Res.table decline on the groundwater quality in Marand Plain,

  11. Stratospheric variability and tropospheric ozone

    E-Print Network [OSTI]

    Hsu, Juno; Prather, Michael J

    2009-01-01

    models include a nearly complete set of chemical species and reactions that affect ozone, but are costly to Earth System

  12. 5, 59575985, 2005 European ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract Introduction explain the trends in European ozone levels? J. E. Jonson 1 , D. Simpson 1 , H. Fagerli 1 , and S. Solberg License. 5957 #12;ACPD 5, 5957­5985, 2005 European ozone trends J. E. Jonson et al. Title Page Abstract

  13. 6, 56715709, 2006 Hemispheric ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page Chemistry and Physics Discussions Hemispheric ozone variability indices derived from satellite observations.erbertseder@dlr.de) 5671 #12;ACPD 6, 5671­5709, 2006 Hemispheric ozone variability indices T. Erbertseder et al. Title Page

  14. 4, 32853332, 2004 Tropospheric ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 3285­3332, 2004 Tropospheric ozone over Equatorial Africa B. Sauvage et al. Title Page and Physics Discussions Tropospheric ozone over Equatorial Africa: regional aspects from the MOZAIC data B Correspondence to: B. Sauvage (saub@aero.obs-mip.fr) 3285 #12;ACPD 4, 3285­3332, 2004 Tropospheric ozone over

  15. 6, 51375162, 2006 Oceanic ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W. Fairall et al. Title Page Abstract Discussions Water-side turbulence enhancement of ozone deposition to the ocean C. W. Fairall1 , D. Helmig2 , L. Fairall (chris.fairall@noaa.gov) 5137 #12;ACPD 6, 5137­5162, 2006 Oceanic ozone deposition velocity C. W

  16. Ozone decomposition in water solutions 

    E-Print Network [OSTI]

    Hewes, Cecil Grayson

    1969-01-01

    OF LITERATUR 1V Vi ~ V111 III ~ EXPERIMENTAL SYSTEM AND ITS OPERATION 14 IV. DISCUSS10N OF RESULTS AND COiJCLUSION. . . 24 i~JOMENCLATUHE. BIBLIOGRAPIFY APPENDIX I. WASTE WATER REGENERATION BY OZONATION. II. AMINE REMOVAL BY OZONATION...ATER SOLUTIONS OF pH 8. XIII. REACTION RATE CONSTANTS FOR THE D'COMPOSITION OF OZONE IN INTER SOLUTIONS OF pH 8. XIV COD REMOVAL BY OZONE XV. OZONIZATION OF MATER CONTAINIiNG RESIDUAL AMINE. 57 60 LIST OF FIGURES FIGURE 1. FIOW DIAGRAM OF THZ...

  17. Ozone decomposing filter

    DOE Patents [OSTI]

    Simandl, Ronald F. (Farragut, TN); Brown, John D. (Harriman, TN); Whinnery, Jr., LeRoy L. (Dublin, CA)

    1999-01-01

    In an improved ozone decomposing air filter carbon fibers are held together with a carbonized binder in a perforated structure. The structure is made by combining rayon fibers with gelatin, forming the mixture in a mold, freeze-drying, and vacuum baking.

  18. Multi-model assessment of stratospheric ozone return dates and ozone recovery in

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models. (2010) Multi-model assessment of stratospheric ozone return dates and ozone recovery in CCMVal-2 models Chemistry and Physics Multi-model assessment of stratospheric ozone return dates and ozone recovery

  19. Solving the Tulsa ozone problem

    SciTech Connect (OSTI)

    Wagner, K.K. [Atmospheric Information Systems, Norman, OK (United States); Wilson, J.D. [Wilson Consulting Group, Tulsa, OK (United States); Gibeau, E. [Aeromet Inc., Tulsa, OK (United States)

    1998-12-31

    Local governments and interested parties in Tulsa, Oklahoma are planning actions to keep Tulsa in compliance with the ozone ambient air quality standard. Based on recent data Tulsa exceeds the new eight hour average national ambient air quality standard for ozone and occasionally exceeds the previous one hour standard. Currently, Tulsa is in attainment of the former one-hour ozone standard. The first planning step is to integrate the existing information about Tulsa`s ozone problem. Prior studies of Tulsa ozone are reviewed. Tulsa`s recent air quality and meteorological monitoring are evaluated. Emission inventory estimates are assessed. Factors identified with Tulsa`s ozone problem are the transport of ozone and precursor gases, a possible role for biogenic emissions, and a simplistic ozone forecasting method. The integration of information found that current air quality and meteorological monitoring is meager. Observations of volatile organic compounds and NO{sub y} are absent. Prior intensive studies in 1977 and 1985 are more than ten years old and lack relevance to today`s problem. Emission inventory estimates are scarce and uncertain. The current knowledge base was judged inadequate to properly characterize the present ozone problem. Actions are recommended to enlarge the information base to address Tulsa`s ozone problem.

  20. 6, 66276694, 2006 linearized ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al. Title Chemistry and Physics Discussions CHEM2D-OPP: A new linearized gas-phase ozone photochemistry.mccormack@nrl.navy.mil) 6627 #12;ACPD 6, 6627­6694, 2006 CHEM2D-OPP linearized ozone photochemistry J. P. McCormack et al

  1. Depleted uranium disposal options evaluation

    SciTech Connect (OSTI)

    Hertzler, T.J.; Nishimoto, D.D.; Otis, M.D. [Science Applications International Corp., Idaho Falls, ID (United States). Waste Management Technology Div.

    1994-05-01

    The Department of Energy (DOE), Office of Environmental Restoration and Waste Management, has chartered a study to evaluate alternative management strategies for depleted uranium (DU) currently stored throughout the DOE complex. Historically, DU has been maintained as a strategic resource because of uses for DU metal and potential uses for further enrichment or for uranium oxide as breeder reactor blanket fuel. This study has focused on evaluating the disposal options for DU if it were considered a waste. This report is in no way declaring these DU reserves a ``waste,`` but is intended to provide baseline data for comparison with other management options for use of DU. To PICS considered in this report include: Retrievable disposal; permanent disposal; health hazards; radiation toxicity and chemical toxicity.

  2. Contribution of global groundwater depletion since 1900 to sealevel rise

    E-Print Network [OSTI]

    of water from terrestrial subsurface storage is a natural consequence of groundwater withdrawals] The extracted groundwater can subsequently follow any number of pathways through the hydrologic cycle, and most pathways that don't involve a return to the groundwater system have relatively short travel times

  3. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  4. Depleted argon from underground sources

    SciTech Connect (OSTI)

    Back, H.O.; /Princeton U.; Alton, A.; /Augustana U. Coll.; Calaprice, F.; Galbiati, C.; Goretti, A.; /Princeton U.; Kendziora, C.; /Fermilab; Loer, B.; /Princeton U.; Montanari, D.; /Fermilab; Mosteiro, P.; /Princeton U.; Pordes, S.; /Fermilab

    2011-09-01

    Argon is a powerful scintillator and an excellent medium for detection of ionization. Its high discrimination power against minimum ionization tracks, in favor of selection of nuclear recoils, makes it an attractive medium for direct detection of WIMP dark matter. However, cosmogenic {sup 39}Ar contamination in atmospheric argon limits the size of liquid argon dark matter detectors due to pile-up. The cosmic ray shielding by the earth means that Argon from deep underground is depleted in {sup 39}Ar. In Cortez Colorado a CO{sub 2} well has been discovered to contain approximately 500ppm of argon as a contamination in the CO{sub 2}. In order to produce argon for dark matter detectors we first concentrate the argon locally to 3-5% in an Ar, N{sub 2}, and He mixture, from the CO{sub 2} through chromatographic gas separation. The N{sub 2} and He will be removed by continuous cryogenic distillation in the Cryogenic Distillation Column recently built at Fermilab. In this talk we will discuss the entire extraction and purification process; with emphasis on the recent commissioning and initial performance of the cryogenic distillation column purification.

  5. Beneficial Uses of Depleted Uranium

    SciTech Connect (OSTI)

    Brown, C. [U.S. Department of Energy, Germantown, MD (United States); Croff, A.G.; Haire, M. J. [Oak Ridge National Lab., TN (United States)

    1997-08-01

    Naturally occurring uranium contains 0.71 wt% {sup 235}U. In order for the uranium to be useful in most fission reactors, it must be enriched the concentration of the fissile isotope {sup 235}U must be increased. Depleted uranium (DU) is a co-product of the processing of natural uranium to produce enriched uranium, and DU has a {sup 235}U concentration of less than 0.71 wt%. In the United States, essentially all of the DU inventory is in the chemical form of uranium hexafluoride (UF{sub 6}) and is stored in large cylinders above ground. If this co-product material were to be declared surplus, converted to a stable oxide form, and disposed, the costs are estimated to be several billion dollars. Only small amounts of DU have at this time been beneficially reused. The U.S. Department of Energy (DOE) has begun the Beneficial Uses of DU Project to identify large-scale uses of DU and encourage its reuse for the primary purpose of potentially reducing the cost and expediting the disposition of the DU inventory. This paper discusses the inventory of DU and its rate of increase; DU disposition options; beneficial use options; a preliminary cost analysis; and major technical, institutional, and regulatory issues to be resolved.

  6. Ozone Conference II: Abstract Proceedings

    SciTech Connect (OSTI)

    None

    1999-11-01

    Ozone Conference II: Pre- and Post-Harvest Applications Two Years After Gras, was held September 27-28, 1999 in Tulare, California. This conference, sponsored by EPRI's Agricultural Technology Alliance and Southern California Edison's AgTAC facility, was coordinated and organized by the on-site ATA-AgTAC Regional Center. Approximately 175 people attended the day-and-a-half conference at AgTAC. During the Conference twenty-two presentations were given on ozone food processing and agricultural applications. Included in the presentations were topics on: (1) Ozone fumigation; (2) Ozone generation techniques; (3) System and design applications; (4) Prewater treatment requirements; (5) Poultry water reuse; (6) Soil treatments with ozone gas; and (7) Post-harvest aqueous and gaseous ozone research results. A live videoconference between Tulare and Washington, D.C. was held to discuss the regulators' view from inside the beltway. Attendees participated in two Roundtable Question and Answer sessions and visited fifteen exhibits and demonstrations. The attendees included university and governmental researchers, regulators, consultants and industry experts, technology developers and providers, and corporate and individual end-users. This report is comprised of the Abstracts of each presentation, biographical sketches for each speaker and a registration/attendees list.

  7. Depleted uranium: A DOE management guide

    SciTech Connect (OSTI)

    1995-10-01

    The U.S. Department of Energy (DOE) has a management challenge and financial liability in the form of 50,000 cylinders containing 555,000 metric tons of depleted uranium hexafluoride (UF{sub 6}) that are stored at the gaseous diffusion plants. The annual storage and maintenance cost is approximately $10 million. This report summarizes several studies undertaken by the DOE Office of Technology Development (OTD) to evaluate options for long-term depleted uranium management. Based on studies conducted to date, the most likely use of the depleted uranium is for shielding of spent nuclear fuel (SNF) or vitrified high-level waste (HLW) containers. The alternative to finding a use for the depleted uranium is disposal as a radioactive waste. Estimated disposal costs, utilizing existing technologies, range between $3.8 and $11.3 billion, depending on factors such as applicability of the Resource Conservation and Recovery Act (RCRA) and the location of the disposal site. The cost of recycling the depleted uranium in a concrete based shielding in SNF/HLW containers, although substantial, is comparable to or less than the cost of disposal. Consequently, the case can be made that if DOE invests in developing depleted uranium shielded containers instead of disposal, a long-term solution to the UF{sub 6} problem is attained at comparable or lower cost than disposal as a waste. Two concepts for depleted uranium storage casks were considered in these studies. The first is based on standard fabrication concepts previously developed for depleted uranium metal. The second converts the UF{sub 6} to an oxide aggregate that is used in concrete to make dry storage casks.

  8. EIA - Natural Gas Pipeline Network - Depleted Reservoir Storage...

    Gasoline and Diesel Fuel Update (EIA)

    Depleted Reservoir Storage Configuration About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Depleted Production...

  9. DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6...

    Energy Savers [EERE]

    DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6) Operations at Ohio and Kentucky Facilities DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6) Operations at...

  10. Improved Potential Energy Surface of Ozone Constructed Using the Fitting by Permutationally Invariant Polynomial Function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ayouz, Mehdi; Babikov, Dmitri

    2012-01-01

    New global potential energy surface for the ground electronic state of ozone is constructed at the complete basis set level of the multireference configuration interaction theory. A method of fitting the data points by analytical permutationally invariant polynomial function is adopted. A small set of 500 points is preoptimized using the old surface of ozone. In this procedure the positions of points in the configuration space are chosen such that the RMS deviation of the fit is minimized. Newab initiocalculations are carried out at these points and are used to build new surface. Additional points are added to the vicinitymore »of the minimum energy path in order to improve accuracy of the fit, particularly in the region where the surface of ozone exhibits a shallow van der Waals well. New surface can be used to study formation of ozone at thermal energies and its spectroscopy near the dissociation threshold.« less

  11. Population Issues & Policies Population Issues

    E-Print Network [OSTI]

    Huang, Youqin

    Desertification Food Production & Environment Cost of extensification Deforestation Soil erosion Desertification Loss of biodiversity Local and global weather change (global warming) Ozone depletion Can we

  12. The influence of cosmic rays on the size of the Antarctic Ozone Hole

    E-Print Network [OSTI]

    M. Alvarez Madrigal; J. Perez Peraza; V. M. Velasco

    2010-01-15

    The Antarctic region in which severe ozone depletion has taken place is known as the ozone hole. This region has two basic indicators: the area, where the ozone abundance is low (size), and the quantity of ozone mass deficit (depth). The energetic particles that penetrate deeply into the atmosphere and galactic cosmic rays (GCR) modify the ozone abundance in the stratosphere. With this research project, we are looking for evidence of a connection between variations in the cosmic ray flux and variations in the size of the ozone hole. In addition, we are looking for signs of the kind of processes that physically connect GCR fluxes with variations in the stratospheric ozone hole size (OHS) in the Antarctic region. With this goal in mind, we also analyze here the atmospheric temperature (AT) anomalies, which have often been linked with such variations. Using Morlet's wavelet spectral analysis to compute the coherence between two time series, we found that during the analyzed period (1982-2005), there existed a common signal of around 3 and 5 years between the OHS and GCR time series, during September and November, respectively. In both cases, the relationship showed a time-dependent anti-correlation between the two series. On the other hand, for October the analysis showed a time-dependent correlation that occurs around 1.7 years. These results seem to indicate that there exist at least two kinds of modulation processes of GCR fluxes on the OHS that work simultaneously but that change their relative relevance along the timeline.

  13. ATOC 3500/CHEM 3151 Spring 2014 Stratospheric Ozone Destruction in the "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC 3500/CHEM 3151 Spring 2014 Problem 15 Stratospheric Ozone Destruction in the "Ozone Hole" The figure below shows typical observations of the total amount of ozone in a layer of air 8 km thick between 12 and 20 km over the South Pole (recall that we like to express the `thickness of ozone

  14. N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone"

    E-Print Network [OSTI]

    Heller, Barbara

    N:\\redesign\\guides\\Ozone.doc 1 Materials found in the IIT Archives concerning "Ozone" Search done of Ozone by G. C. Carnahan and O. A. DeCelle; Chemical Engineering program, 1914 Call No. Thesis 543.2 C22 Press releases issued by Illinois Institute of Technology, 1940-1968 that include the word "ozone

  15. Climatology of UTLS ozone and the ratio of ozone and potential vorticity over northern Europe

    E-Print Network [OSTI]

    Kirkwood, Sheila

    Climatology of UTLS ozone and the ratio of ozone and potential vorticity over northern Europe T variations of ozone in the upper troposphere and lower stratosphere (UTLS) region have been studied using of ozone exhibits a prominent annual cycle in the UTLS region. The observed change in the phase

  16. Theoretical and experimental studies of heterogeneous chemical processes leading to stratospheric ozone depletion

    E-Print Network [OSTI]

    Mantz, Yves André, 1974-

    2002-01-01

    The microscopic chemical mechanisms of heterogeneous reactions involving HC on crystalline ice and nitric acid trihydrate (NAT) are of fundamental interest to physical chemists, because such reactions yield "active" chlorine ...

  17. Modeling the climate impact of Southern Hemisphere ozone depletion: The importance

    E-Print Network [OSTI]

    MacDonald, Mark

    Processes and their Role in Climate (SPARC)) used by many Intergovernmental Panel on Climate Change Fifth/summer polar cap cooling, geopotential height decreases, and zonal wind increases in the BDBP simulations

  18. Biomass burning influence on high-latitude tropospheric ozone and reactive nitrogen in summer 2008: a multi-model analysis based on POLMIP simulations

    E-Print Network [OSTI]

    Arnold, S. R.

    We have evaluated tropospheric ozone enhancement in air dominated by biomass burning emissions at high latitudes (> 50° N) in July 2008, using 10 global chemical transport model simulations from the POLMIP multi-model ...

  19. 7, 1009710129, 2007 Chemical ozone loss

    E-Print Network [OSTI]

    ACPD 7, 10097­10129, 2007 Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Chemistry and Physics Discussions Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes 1 , R. M Chemical ozone loss in the Arctic winter 1991­1992 S. Tilmes et al. Title Page Abstract Introduction

  20. 5, 243286, 2005 Retrieval of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 243­286, 2005 Retrieval of ozone column content during SOLVE II J. M. Livingston et al and Physics Discussions Retrieval of ozone column content from airborne Sun photometer measurements during Aerospace Center), Oberpfaffenhofen, Wessling, Germany 243 #12;ACPD 5, 243­286, 2005 Retrieval of ozone

  1. 4, 20552088, 2004 Aerosol-ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni et al and Physics Discussions Aerosol-ozone correlations during dust transport episodes P. Bonasoni1 , P.bonasoni@isac.cnr.it) 2055 #12;ACPD 4, 2055­2088, 2004 Aerosol-ozone correlations during dust transport episodes P. Bonasoni

  2. 7, 22492274, 2007 Vertical ozone over

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean and Central Europe P. D a Creative Commons License. Atmospheric Chemistry and Physics Discussions Vertical ozone measurements (kalabokas pavlos@yahoo.gr) 2249 #12;ACPD 7, 2249­2274, 2007 Vertical ozone over Eastern Mediterranean

  3. 8, 31433162, 2008 Total ozone over

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 3143­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Chemistry and Physics Discussions Total column ozone variations over oceanic region around Indian sub­3162, 2008 Total ozone over oceanic regions M. C. R. Kalapureddy et al. Title Page Abstract Introduction

  4. 8, 50075060, 2008 Evaluation of ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 5007­5060, 2008 Evaluation of ozone trends from g-b FTIR observations C. Vigouroux et al.0 License. Atmospheric Chemistry and Physics Discussions Evaluation of tropospheric and stratospheric ozone Publications on behalf of the European Geosciences Union. 5007 #12;ACPD 8, 5007­5060, 2008 Evaluation of ozone

  5. 8, 49114947, 2008 NOx-induced ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 8, 4911­4947, 2008 NOx-induced ozone loss processes B. Vogel et al. Title Page Abstract Chemistry and Physics Discussions Model simulations of stratospheric ozone loss caused by enhanced on behalf of the European Geosciences Union. 4911 #12;ACPD 8, 4911­4947, 2008 NOx-induced ozone loss

  6. 5, 1133111375, 2005 NH total ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract Introduction On the possible causes of recent increases in NH total ozone from a statistical analysis of satellite data from License. 11331 #12;ACPD 5, 11331­11375, 2005 NH total ozone increase S. Dhomse et al. Title Page Abstract

  7. 6, 84578483, 2006 Low ozone over the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 6, 8457­8483, 2006 Low ozone over the UK M. Keil et al. Title Page Abstract Introduction Discussions The January 2006 low ozone event over the UK M. Keil, D. R. Jackson, and M. C. Hort Met Office 2006 Correspondence to: M. Keil (mike.keil@metoffice.gov.uk) 8457 #12;ACPD 6, 8457­8483, 2006 Low ozone

  8. 5, 96419668, 2005 The origin of ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 5, 9641­9668, 2005 The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions-5-9641 European Geosciences Union Atmospheric Chemistry and Physics Discussions The origin of ozone V. Grewe The origin of ozone V. Grewe Title Page Abstract Introduction Conclusions References Tables Figures Back

  9. 6, 39133943, 2006 Svalbard total ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 6, 3913­3943, 2006 Svalbard total ozone C. Vogler et al. Title Page Abstract Introduction Discussions Re-evaluation of the 1950­1962 total ozone record from Longyearbyen, Svalbard C. Vogler 1 , S. Br total ozone C. Vogler et al. Title Page Abstract Introduction Conclusions References Tables Figures Back

  10. 3, 187223, 2003 TOMS cloudy ozone

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 3, 187­223, 2003 TOMS cloudy ozone anomaly X. Liu et al. Title Page Abstract Introduction Geosciences Union 2003 Atmospheric Chemistry and Physics Discussions Occurrence of ozone anomalies over cloudy 2003 Correspondence to: X. Liu (xliu@nsstc.uah.edu) 187 #12;ACPD 3, 187­223, 2003 TOMS cloudy ozone

  11. 3, 10811107, 2003 Mid-latitude ozone

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 3, 1081­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page-dimensional model study of long-term mid-high latitude lower stratosphere ozone changes M. P. Chipperfield School­1107, 2003 Mid-latitude ozone changes in a 3D CTM M. P. Chipperfield Title Page Abstract Introduction

  12. 4, 21672238, 2004 Ozone loss and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 4, 2167­2238, 2004 Ozone loss and chlorine activation in the Arctic winters 1991­2003 S Union 2004 Atmospheric Chemistry and Physics Discussions Ozone loss and chlorine activation Correspondence to: S. Tilmes (simone.tilmes@t-online.de) 2167 #12;ACPD 4, 2167­2238, 2004 Ozone loss and chlorine

  13. Ozone: Integrating Structured and Semistructured Data ?

    E-Print Network [OSTI]

    Abiteboul, Serge

    Ozone: Integrating Structured and Semistructured Data ? Tirthankar Lahiri 1 , Serge Abiteboul 2 language, and we implement our extensions in a system called Ozone. In our approach, structured data may full knowledge of structure. Ozone also enhances both ODMG/OQL and OEM/Lorel by virtue

  14. Seasonal persistence of midlatitude total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of midlatitude total ozone anomalies Article Published Version Fioletov, V. E. and Shepherd, T. G. (2003) Seasonal persistence of midlatitude total ozone anomalies. Geophysical Research persistence of midlatitude total ozone anomalies Vitali E. Fioletov Meteorological Service of Canada, Toronto

  15. The New MCNP6 Depletion Capability

    SciTech Connect (OSTI)

    Fensin, Michael Lorne [Los Alamos National Laboratory; James, Michael R. [Los Alamos National Laboratory; Hendricks, John S. [Los Alamos National Laboratory; Goorley, John T. [Los Alamos National Laboratory

    2012-06-19

    The first MCNP based inline Monte Carlo depletion capability was officially released from the Radiation Safety Information and Computational Center as MCNPX 2.6.0. Both the MCNP5 and MCNPX codes have historically provided a successful combinatorial geometry based, continuous energy, Monte Carlo radiation transport solution for advanced reactor modeling and simulation. However, due to separate development pathways, useful simulation capabilities were dispersed between both codes and not unified in a single technology. MCNP6, the next evolution in the MCNP suite of codes, now combines the capability of both simulation tools, as well as providing new advanced technology, in a single radiation transport code. We describe here the new capabilities of the MCNP6 depletion code dating from the official RSICC release MCNPX 2.6.0, reported previously, to the now current state of MCNP6. NEA/OECD benchmark results are also reported. The MCNP6 depletion capability enhancements beyond MCNPX 2.6.0 reported here include: (1) new performance enhancing parallel architecture that implements both shared and distributed memory constructs; (2) enhanced memory management that maximizes calculation fidelity; and (3) improved burnup physics for better nuclide prediction. MCNP6 depletion enables complete, relatively easy-to-use depletion calculations in a single Monte Carlo code. The enhancements described here help provide a powerful capability as well as dictate a path forward for future development to improve the usefulness of the technology.

  16. Molten-Salt Depleted-Uranium Reactor

    E-Print Network [OSTI]

    Dong, Bao-Guo; Gu, Ji-Yuan

    2015-01-01

    The supercritical, reactor core melting and nuclear fuel leaking accidents have troubled fission reactors for decades, and greatly limit their extensive applications. Now these troubles are still open. Here we first show a possible perfect reactor, Molten-Salt Depleted-Uranium Reactor which is no above accident trouble. We found this reactor could be realized in practical applications in terms of all of the scientific principle, principle of operation, technology, and engineering. Our results demonstrate how these reactors can possess and realize extraordinary excellent characteristics, no prompt critical, long-term safe and stable operation with negative feedback, closed uranium-plutonium cycle chain within the vessel, normal operation only with depleted-uranium, and depleted-uranium high burnup in reality, to realize with fission nuclear energy sufficiently satisfying humanity long-term energy resource needs, as well as thoroughly solve the challenges of nuclear criticality safety, uranium resource insuffic...

  17. Neutral depletion and the helicon density limit

    SciTech Connect (OSTI)

    Magee, R. M.; Galante, M. E.; Carr, J. Jr.; Lusk, G.; McCarren, D. W.; Scime, E. E.

    2013-12-15

    It is straightforward to create fully ionized plasmas with modest rf power in a helicon. It is difficult, however, to create plasmas with density >10{sup 20} m{sup ?3}, because neutral depletion leads to a lack of fuel. In order to address this density limit, we present fast (1 MHz), time-resolved measurements of the neutral density at and downstream from the rf antenna in krypton helicon plasmas. At the start of the discharge, the neutral density underneath the antenna is reduced to 1% of its initial value in 15 ?s. The ionization rate inferred from these data implies that the electron temperature near the antenna is much higher than the electron temperature measured downstream. Neutral density measurements made downstream from the antenna show much slower depletion, requiring 14 ms to decrease by a factor of 1/e. Furthermore, the downstream depletion appears to be due to neutral pumping rather than ionization.

  18. Ozone Reductions Using Residential Building Envelopes

    SciTech Connect (OSTI)

    Walker, Iain S.; Sherman, Max; Nazaroff, William W.

    2009-02-01

    Ozone is an air pollutant with that can have significant health effects and a significant source of ozone in some regions of California is outdoor air. Because people spend the vast majority of their time indoors, reduction in indoor levels of ozone could lead to improved health for many California residents. Ozone is removed from indoor air by surface reactions and can also be filtered by building envelopes. The magnitude of the envelope impact depends on the specific building materials that the air flows over and the geometry of the air flow paths through the envelope that can be changes by mechanical ventilation operation. The 2008 Residential Building Standards in California include minimum requirements for mechanical ventilation by referencing ASHRAE Standard 62.2. This study examines the changes in indoor ozone depending on the mechanical ventilation system selected to meet these requirements. This study used detailed simulations of ventilation in a house to examine the impacts of different ventilation systems on indoor ozone concentrations. The simulation results showed that staying indoors reduces exposure to ozone by 80percent to 90percent, that exhaust ventilation systems lead to lower indoor ozone concentrations, that opening of windows should be avoided at times of high outdoor ozone, and that changing the time at which mechanical ventilation occurs has the ability to halve exposure to ozone. Future work should focus on the products of ozone reactions in the building envelope and the fate of these products with respect to indoor exposures.

  19. THE RIMINI PROTOCOL Oil Depletion Protocol

    E-Print Network [OSTI]

    Keeling, Stephen L.

    1 THE RIMINI PROTOCOL an Oil Depletion Protocol ~ Heading Off Economic Chaos and Political Conflict During the Second Half of the Age of Oil As proposed at the 2003 Pio Manzu Conference Soaring oil prices have drawn attention to the issue of the relative supply and demand for crude oil

  20. Ground-level ozone following astrophysical ionizing radiation events: an additional biological hazard?

    E-Print Network [OSTI]

    Thomas, Brian C

    2015-01-01

    Astrophysical ionizing radiation events such as supernovae, gamma-ray bursts, and solar proton events have been recognized as a potential threat to life on Earth, primarily through depletion of stratospheric ozone and subsequent increase in solar UV radiation at Earth's surface and in the upper levels of the ocean. Other work has also considered the potential impact of nitric acid rainout, concluding that no significant threat is likely. Not yet studied to-date is the potential impact of ozone produced in the lower atmosphere following an ionizing radiation event. Ozone is a known irritant to organisms on land and in water and therefore may be a significant additional hazard. Using previously completed atmospheric chemistry modeling we have examined the amount of ozone produced in the lower atmosphere for the case of a gamma-ray burst and find that the values are too small to pose a significant additional threat to the biosphere. These results may be extended to other ionizing radiation events, including supe...

  1. A study of the effect of ozone and antioxidants on ozone-sensitive loblolly pine 

    E-Print Network [OSTI]

    Posey, Karen Lashea

    1995-01-01

    Ozone, a phytotoxic air pollutant, is formed from photochemical reactions of hydrocarbons and nitrogen oxides in the troposphere. Ozone is taken into the plant through the stomata, and quickly broken down into hydroxyl radicals. These hydroxyl...

  2. Improving ozone profile retrieval from spaceborne UV backscatter

    E-Print Network [OSTI]

    Haak, Hein

    Chapter 2 Improving ozone profile retrieval from spaceborne UV backscatter spectrometers using convergence behaviour diagnostics Abstract The Ozone Profile Algorithm (OPERA), developed at KNMI, retrieves the vertical ozone distribution from nadir spectral satellite measurements of back scattered sunlight

  3. oZONE Faculty and Staff Enrolling Students

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Enrolling Students Log in to ozone.ou.edu. Click the Advising tab. Please lecture schedule CRN ­ Course Reference Number In oZONE the Registration Add Errors will display one

  4. Controls over ozone deposition to a high elevation subalpine forest

    E-Print Network [OSTI]

    Turnipseed, AA; Burns, SP; Moore, DJP; Hu, J; Guenther, AB; Monson, RK

    2009-01-01

    D.L. , Fehsenfeld, F.C. , 1986b. Background ozone andanthropogenic ozone enhancement at Niwot Ridge, Colorado.Day-time variations of ozone eddy ?uxes to maize. Boundary-

  5. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01

    carbon filters for the control of ozone, sulfur dioxide, andMendell (2008). "Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  6. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01

    particles produced by ozone/limonene reactions in indoor airgas-phase reactions of ozone with organic compounds underNazaroff, W.W. , 2008. Ozone levels in passenger cabins of

  7. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    Jan de Leeuw; Shuojun Wang

    2011-01-01

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  8. Ozone Standard Exceedance Days in the South San Joaquin Valley

    E-Print Network [OSTI]

    de Leeuw, Jan; Wang, Shuojun

    2007-01-01

    about the health e?ects of ozone. CES is looking at many8h national std. days OZONE STANDARDS F????? 2. Bakers?eld8h national std. days OZONE STANDARDS Time F????? 4. Shafter

  9. Assessment of Preferred Depleted Uranium Disposal Forms

    SciTech Connect (OSTI)

    Croff, A.G.; Hightower, J.R.; Lee, D.W.; Michaels, G.E.; Ranek, N.L.; Trabalka, J.R.

    2000-06-01

    The Department of Energy (DOE) is in the process of converting about 700,000 metric tons (MT) of depleted uranium hexafluoride (DUF6) containing 475,000 MT of depleted uranium (DU) to a stable form more suitable for long-term storage or disposal. Potential conversion forms include the tetrafluoride (DUF4), oxide (DUO2 or DU3O8), or metal. If worthwhile beneficial uses cannot be found for the DU product form, it will be sent to an appropriate site for disposal. The DU products are considered to be low-level waste (LLW) under both DOE orders and Nuclear Regulatory Commission (NRC) regulations. The objective of this study was to assess the acceptability of the potential DU conversion products at potential LLW disposal sites to provide a basis for DOE decisions on the preferred DU product form and a path forward that will ensure reliable and efficient disposal.

  10. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  11. 5, 58415874, 2005 Ozone/tracer

    E-Print Network [OSTI]

    Boyer, Edmond

    ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et al. Title Page Discussions Impact of mixing and chemical change on ozone-tracer relations in the polar vortex R. M¨uller 1 Commons License. 5841 #12;ACPD 5, 5841­5874, 2005 Ozone/tracer relations in the polar vortex R. M¨uller et

  12. A fast stratospheric ozone chemistry schemeA fast stratospheric ozone chemistry scheme Michel Bourqui1

    E-Print Network [OSTI]

    Bourqui, Michel

    A fast stratospheric ozone chemistry schemeA fast stratospheric ozone chemistry scheme Michel a computationally efficient chemical scheme, the FAst STratospheric Ozone Chemistry (FASTOC) scheme, which has advantages over many existing fast methods, as it does not rely on relaxation to assumed conditions, does

  13. The ultimate disposition of depleted uranium

    SciTech Connect (OSTI)

    Lemons, T.R. [Uranium Enrichment Organization, Oak Ridge, TN (United States)

    1991-12-31

    Depleted uranium (DU) is produced as a by-product of the uranium enrichment process. Over 340,000 MTU of DU in the form of UF{sub 6} have been accumulated at the US government gaseous diffusion plants and the stockpile continues to grow. An overview of issues and objectives associated with the inventory management and the ultimate disposition of this material is presented.

  14. Carbon sequestration in depleted oil shale deposits

    SciTech Connect (OSTI)

    Burnham, Alan K; Carroll, Susan A

    2014-12-02

    A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

  15. ENV/ERS 467/667 Regional and Global Issues in Environmental and Natural Resource Sciences

    E-Print Network [OSTI]

    Nowak, Robert S.

    of clarity? 9. Radioactive waste in Nevada: Is the risk substantial? 10. Other topic also open, with consent · Values and politics Nowak 12 Persistent organic pollutants: Long range transport 14 Stratospheric Ozone Depletion (CFCs) 19 Metals: Long range transport Miller 21 International pollution, socioeconomic

  16. Tropospheric Ozone Pollution and Personal Exposure

    E-Print Network [OSTI]

    Toohey, Darin W.

    ://www.nctcog.org/trans/air/ozone/formation.gif #12;Health Effects · Chest pain, coughing, throat irritation, and congestion · Wheezing and difficulty

  17. DOE's Studies of Weekday/Weekend Ozone Pollution in Southern...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies of WeekdayWeekend Ozone Pollution in Southern California DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California 2002 DEER Conference Presentation:...

  18. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    E-Print Network [OSTI]

    Coleman, Beverly Kaye

    2009-01-01

    to determine deposition velocity, reaction probability, orOzone level, deposition velocity, reaction probability wereOzone level, deposition velocity, reaction probability were

  19. The Weekend Ozone Effect - The Weekly Ambient Emissions Control...

    Energy Savers [EERE]

    More Documents & Publications WeekendWeekday Ozone Study in the South Coast Air Basin DOE's Studies of WeekdayWeekend Ozone Pollution in Southern California...

  20. The Impact of Emission and Climate Change on Ozone in the United States under Representative Concentration Pathways (RCPs)

    SciTech Connect (OSTI)

    Gao, Yang; Fu, Joshua S.; Drake, John B.; Lamarque, J.-F.; Liu, Yang

    2013-09-27

    Dynamical downscaling was applied in this study to link the global climate-chemistry model Community Atmosphere Model (CAM-Chem) with the regional models: Weather Research and Forecasting (WRF) Model and Community Multi-scale Air Quality (CMAQ). Two Representative Concentration Pathway (RCP) scenarios (RCP 4.5 and RCP 8.5) were used to evaluate the climate impact on ozone concentrations in 2050s. Ozone concentrations in the lower-mid troposphere (surface to ~300 hPa), from mid- to high latitudes in the Northern Hemisphere (NH), show decreasing trends in RCP 4.5 between 2000s and 2050s, with the largest decrease of 4-10 ppbv occurring in the summer and the fall; and increasing trends (2-12 ppbv) in RCP 8.5 resulting from the increased methane emissions. In RCP 8.5, methane emissions increase by ~60% by the end of 2050s, accounting for more than 90% of ozone increases in summer and fall, and 60-80% in spring and winter. Under the RCP 4.5 scenario, in the summer when photochemical reactions are the most active, the large ozone precursor emissions reduction leads to the greatest decrease of downscaled surface ozone concentrations, ranging from 6 to 10 ppbv. However, a few major cities show ozone increases of 3 to 7 ppbv due to weakened NO titration. Under the RCP 8.5 scenario, in winter, downscaled ozone concentrations increase across nearly the entire continental US in winter, ranging from 3 to 10 ppbv due to increased methane emissions and enhanced stratosphere-troposphere exchange (STE). More intense heat waves are projected to occur by the end of 2050s in RCP 8.5, leading to more than 8 ppbv of the maximum daily 8-hour daily average (MDA8) ozone during the heat wave days than other days; this indicates the dramatic impact heat waves exert on high frequency ozone events.

  1. Energy and global warming impacts of HFC refrigerants and emerging technologies: TEWI-III

    SciTech Connect (OSTI)

    Sand, J.R.; Fischer, S.K.; Baxter, V.D.

    1997-06-01

    The use of hydrofluorocarbons (BFCs) which were developed as alternative refrigerants and insulating foam blowing agents to replace chlorofluorocarbons (CFCs) is now being affected by scientific investigations of greenhouse warming and questions about the effects of refrigerants and blowing agents on global warming. A Total Equivalent Warming Impact (TEWI) assessment analyzes the environmental affects of these halogenated working fluids in energy consuming applications by combining a direct effect resulting from the inadvertent release of HFCs to the atmosphere with an indirect effect resulting from the combustion of fossil fuels needed to provide the energy to operate equipment using these compounds as working fluids. TEWI is a more balanced measure of environmental impact because it is not based solely on the global warming potential (GWP) of the working fluid. It also shows the environmental benefit of efficient technologies that result in less CO{sub 2} generation and eventual emission to the earth`s atmosphere. The goal of TEWI is to assess total global warming impact of all the gases released to the atmosphere, including CO{sub 2} emissions from energy conversion. Alternative chemicals and technologies have been proposed as substitutes for HFCs in the vapor-compression cycle for refrigeration and air conditioning and for polymer foams in appliance and building insulations which claim substantial environmental benefits. Among these alternatives are: (1) Hydrocarbon (HC) refrigerants and blowing agents which have zero ozone depleting potential and a negligible global warming potential, (2) CO{sub 2} as a refrigerant and blowing agent, (3) Ammonia (NH{sub 3}) vapor compression systems, (4) Absorption chiller and heat pumping cycles using ammonia/water or lithium bromide/water, and (5) Evacuated panel insulations. This paper summarizes major results and conclusions of the detailed final report on the TEWI-111 study.

  2. Using Depletion to Tune Colloid Shape for Assembly

    E-Print Network [OSTI]

    Andrew S. Karas; Jens Glaser; Sharon C. Glotzer

    2015-10-14

    Depletion interactions arise from entropic forces and their ability to induce aggregation and even ordering of colloidal particles through self-assembly is well established, especially for spherical colloids. We vary the size and concentration of penetrable hard sphere depletants in a system of nonspherical colloids, and show how depletion effectively changes the shape of the colloids and thereby selects different crystal structures. We provide a simple explanation of this effective shape change using cuboctahedra, and explain the stability of the distinct crystals formed via depletion using free energy calculations that consider separately the contribution of the cuboctahedra and depletant entropy. We show that, counterintuitively, the colloid contribution to the free energy stabilizes the simple cubic phase. We corroborate our results by analyzing how the depletant concentration and size affect the emergent directional entropic forces and hence effective particle shape. We propose the use of depletants as a means of easily changing the effective shape of self-assembling anisotropic colloids.

  3. Global Statistics

    E-Print Network [OSTI]

    Crow, Ben D

    2006-01-01

    of Globalization: Statistics Weiss, L. (1997). "of Globalization: Statistics Milanovic, B. (1999). Truethe focus of global statistics, particularly in relation to

  4. PowerPoint Presentation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    consumption, peak electric demand, and avoid using refrigerants with high potentials for global warming and ozone depletion. * Further study is ongoing for the economical...

  5. Global tropospheric ozone modeling: Quantifying errors due to grid resolution

    E-Print Network [OSTI]

    Wild, Oliver; Prather, Michael J

    2006-01-01

    G4), and 576 Â 354 Â 184 (G8). For each successive doubling,The computational cost of the G8 run is 4096 times that ofare not better resolved at G8 than at G1. Surface abundances

  6. Effects of stratospheretroposphere chemistry coupling on tropospheric ozone

    E-Print Network [OSTI]

    Effects of stratospheretroposphere chemistry coupling on tropospheric ozone Wenshou Tian,1,2 Martyn in both the troposphere and stratosphere. The modeled total column ozone agrees well with Total Ozone Mapping Spectrometer observations. Modeled ozone profiles in the upper troposphere and lower stratosphere

  7. Part III Research Project Stratosphere-Troposphere Exchange of Ozone

    E-Print Network [OSTI]

    Withers, Paul

    Part III Research Project Stratosphere-Troposphere Exchange of Ozone Observed by Data Assimilation Stratosphere-Troposphere exchange of ozone at tropopause folds is an important process in the atmosphere. Reconstruction of the evolution of ozone at a tropopause fold by conventional means requires synoptic ozone

  8. Tropospheric Ozone Satellite Retrievals in the Pacific Northwest

    E-Print Network [OSTI]

    Collins, Gary S.

    Tropospheric Ozone Satellite Retrievals in the Pacific Northwest Jacqueline Costello1, Farren: Tropospheric ozone is difficult to retrieve from satellites because of the abundance of ozone in the stratosphere. Tropospheric ozone has become a significant environmental issue and can be exacerbated by UT

  9. Microarray-based analysis of survival of soil microbial community during ozonation

    E-Print Network [OSTI]

    Wang, Jian

    2010-01-01

    3 ] in Ozonation time (h) Ozone BTC TSEM content was used to1. Ozone breakthrough curve (BTC) and TSEM removal during

  10. Exposure to Particulate Matter and Ozone of Outdoor Origin in Singapore

    E-Print Network [OSTI]

    Gall, Elliott T; Chen, Ailu; Chang, Victor; Nazaroff, William W

    2015-01-01

    ulate matter (PM) or ozone, at concentration increments of ~SL, Samet JM, Dominici F. Ozone and short-term mortality inthe penetration of ambient ozone into residential buildings.

  11. LARGE MULTICONFIGURATION SELF-CONSISTENT-FIELD WAVEFUNCTIONS FOR THE OZONE MOLECULE

    E-Print Network [OSTI]

    Schaefer III., Henry F.

    2013-01-01

    theory comparable to that employed here for ozone. HoweverB (cyclopentadiyl) > B (ozone) > B (methylene), based onfor the its state of ozone near geometry. Coefficients of

  12. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01

    of healthy young volunteers to ozone causes cardiovasculareffects of five common ozone-initiated terpene reactiondecay rates, and removal of ozone and their relation to

  13. Ozone photochemical production in urban Shanghai, China: Analysis based on ground level observations

    E-Print Network [OSTI]

    2009-01-01

    of aerosols on surface ozone concentration in Tianjin,W. P. L. (1994), Development of ozone reactivity scales forand M. M. Fox (1953), Ozone formation in photochemical

  14. oZONE Faculty and Staff Exporting and Importing Grades

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Exporting and Importing Grades Exporting/Importing Grades in oZONE The new - Log in to ozone.ou.edu using your OU Net ID (4+4) as you would in any other OU system. Click Importing Grades from a Exported oZONE template If you exported a course template from the oZONE grading

  15. Directional depletion interactions in shaped particles

    E-Print Network [OSTI]

    A. Scala; P. G. De Sanctis Lucentini

    2014-10-16

    Entropic forces in colloidal suspensions and in polymer-colloid systems are of long-standing and continuing interest. Experiments show how entropic forces can be used to control the self-assembly of colloidal particles. Significant advances in colloidal synthesis made in the past two decades have enabled the preparation of high quality nano-particles with well-controlled sizes, shapes, and compositions, indicating that such particles can be utilized as "artificial atoms" to build new materials. To elucidate the effects of the shape of particles upon the magnitude of entropic interaction, we analyse the entropic interactions of two cut-spheres. We show that the solvent induces a strong directional depletion attraction among flat faces of the cut-spheres. Such an effect highlights the possibility of using the shape of particles to control directionality and strength of interaction.

  16. Lithium Depletion of Nearby Young Stellar Associations

    E-Print Network [OSTI]

    Erin Mentuch; Alexis Brandeker; Marten H. van Kerkwijk; Ray Jayawardhana; Peter H. Hauschildt

    2008-08-26

    We estimate cluster ages from lithium depletion in five pre-main-sequence groups found within 100 pc of the Sun: TW Hydrae Association, Eta Chamaeleontis Cluster, Beta Pictoris Moving Group, Tucanae-Horologium Association and AB Doradus Moving Group. We determine surface gravities, effective temperatures and lithium abundances for over 900 spectra through least squares fitting to model-atmosphere spectra. For each group, we compare the dependence of lithium abundance on temperature with isochrones from pre-main-sequence evolutionary tracks to obtain model dependent ages. We find that the Eta Chamaelontis Cluster and the TW Hydrae Association are the youngest, with ages of 12+/-6 Myr and 12+/-8 Myr, respectively, followed by the Beta Pictoris Moving Group at 21+/-9 Myr, the Tucanae-Horologium Association at 27+/-11 Myr, and the AB Doradus Moving Group at an age of at least 45 Myr (where we can only set a lower limit since the models -- unlike real stars -- do not show much lithium depletion beyond this age). Here, the ordering is robust, but the precise ages depend on our choice of both atmospheric and evolutionary models. As a result, while our ages are consistent with estimates based on Hertzsprung-Russell isochrone fitting and dynamical expansion, they are not yet more precise. Our observations do show that with improved models, much stronger constraints should be feasible: the intrinsic uncertainties, as measured from the scatter between measurements from different spectra of the same star, are very low: around 10 K in effective temperature, 0.05 dex in surface gravity, and 0.03 dex in lithium abundance.

  17. Carbonyl sulfide: No remedy for global warming

    SciTech Connect (OSTI)

    Taubman, S.J.; Kasting, J.F. [Pennsylvania State Univ., University Park, PA (United States)] [Pennsylvania State Univ., University Park, PA (United States)

    1995-04-01

    The authors look at the possibility of counteracting global warming forces by the injection of carbonyl sulfide (OCS) into the stratosphere at levels high enough to balance the impact say of a doubling of carbon dioxide concentrations, which are projected to result in a global 3{degrees} C warming. OCS injections at densities to provide such cooling will result a 30 percent impact of global ozone, whereas the carbon dioxide only made a 5% impact. In addition levels which would be found on the earths surface would be in the range 10 ppmv which is questionable as a safe exposure limit for humans, in addition to its impact on the ph of rainwater.

  18. EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth...

    Broader source: Energy.gov (indexed) [DOE]

    and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three alternative locations within the Portsmouth site;...

  19. Enterprise Assessments Targeted Review of the Paducah Depleted...

    Broader source: Energy.gov (indexed) [DOE]

    Targeted Review of the Fire Protection Program at the Paducah Depleted Uranium Hexafluoride Conversion Facility The U.S. Department of Energy (DOE) Office of Enterprise Assessments...

  20. Gas generation matrix depletion quality assurance project plan

    SciTech Connect (OSTI)

    NONE

    1998-05-01

    The Los Alamos National Laboratory (LANL) is to provide the necessary expertise, experience, equipment and instrumentation, and management structure to: Conduct the matrix depletion experiments using simulated waste for quantifying matrix depletion effects; and Conduct experiments on 60 cylinders containing simulated TRU waste to determine the effects of matrix depletion on gas generation for transportation. All work for the Gas Generation Matrix Depletion (GGMD) experiment is performed according to the quality objectives established in the test plan and under this Quality Assurance Project Plan (QAPjP).

  1. 5, 90039038, 2005 Ozone in Europe

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    that extensive forest fires on the Iberian Peninsula, resulting from the drought and heat, contributed to the peak ozone values observed in15 North Europe in August. Additionally, forest fires in Siberia probably

  2. Ozone determination in different copying centers 

    E-Print Network [OSTI]

    Lai, Chen-Fu

    1993-01-01

    Photocopying machines have been in existence for forty years: however, few people recognize their potential to create a human health hazard by ozone emission. This study was designed to determine the photocopier's emission rate and evaluate tile...

  3. Globalization Nationalized

    E-Print Network [OSTI]

    Mazlish, Bruce

    Globalism and globalization have been seen as competitors to other allegiances, namely regionalism and nationalism. A look at recent efforts at reconceptualizing global history in China, Korea and the U.S., however, suggests ...

  4. Recovery of Depleted Uranium Fragments from Soil

    SciTech Connect (OSTI)

    Farr, C.P.; Alecksen, T.J.; Heronimus, R.S.; Simonds, M.H.; Farrar, D.R.; Baker, K.R. [Environmental Restoration Group, Inc., Washington St. NE, Albuquerque, NM (United States); Miller, M.L. [Sandia National Laboratories, Albuquerque, NM (United States)

    2008-07-01

    A cost-effective method was demonstrated for recovering depleted uranium (DU) fragments from soil. A compacted clean soil pad was prepared adjacent to a pile of soil containing DU fragments. Soil from the contaminated pile was placed on the pad in three-inch lifts using conventional construction equipment. Each lift was scanned with an automatic scanning system consisting of an array of radiation detectors coupled to a detector positioning system. The data were downloaded into ArcGIS for data presentation. Areas of the pad exhibiting scaler counts above the decision level were identified as likely locations of DU fragments. The coordinates of these locations were downloaded into a PDA that was wirelessly connected to the positioning system. The PDA guided technicians to the locations where hand-held trowels and shovels were used to remove the fragments. After DU removal, the affected areas were re-scanned and the new data patched into the data base to replace the original data. This new data set along with soil sample results served as final status survey data. (authors)

  5. Concentration of ozone in surface air over greater Boston

    E-Print Network [OSTI]

    Widen, Donald Allen

    1966-01-01

    Surface ozone concentrations were measured in the Greater Boston area from November, 1964 to December, 1965. Ozone was monitored continuosly using a Mast microcoulombmetric sensor. A chromium trioxide filter was fitted to ...

  6. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. 2005 Diesel Engine Emissions...

  7. What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found in the strato-

    E-Print Network [OSTI]

    What is Ozone? Ozone (O3) is a molecule made up of three atoms of oxygen (O), and is mostly found it represents only a tiny fraction of the atmosphere, ozone is crucial for life on Earth. Ozone--acts as a shield to protect Earth's surface from the sun's harmful ultraviolet radiation. With- out ozone, the Sun

  8. Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong-Hoo Park a

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone uptake by citrus trees exposed to a range of ozone concentrations Silvano Fares a,b,*, Jeong Received in revised form 26 May 2010 Accepted 2 June 2010 Keywords: Ozone fluxes Citrus Tropospheric ozone climates. In the summer, orchards in California experience high levels of tropospheric ozone, formed

  9. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2000 tropical ozone climatology 2; published 31 January 2003. [1] The first view of stratospheric and tropospheric ozone variability in the Southern Hemisphere tropics is provided by a 3-year record of ozone soundings from the Southern Hemisphere

  10. Ozone climatology using interactive chemistry: results from the Canadian

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone climatology using interactive chemistry: results from the Canadian Middle Atmosphere Model., Medvedev, A. S. and Shepherd, T. G. (2000) Ozone climatology using interactive chemistry: results from RESEARCH, VOL. 105,NO. D21, PAGES 26,475-26,491,NOVEMBER 16, 2000 Ozone climatology using interactive

  11. Chemistry climate model simulations of1 spring Antarctic ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Chemistry climate model simulations of1 spring Antarctic ozone Article Published Version Austin, J. (2010) Chemistry climate model simulations of spring Antarctic1 ozone. Journal of Geophysical Research ozone John Austin,1,2 H. Struthers,3 J. Scinocca,4 D. A. Plummer,5 H. Akiyoshi,6 A. J. G. Baumgaertner,7

  12. Assigning vibrational polyads using relative equilibria. Application to ozone

    E-Print Network [OSTI]

    Sadovskií, Dmitrií

    Assigning vibrational polyads using relative equilibria. Application to ozone I. N. Kozin a,1 , D equilibria. We use the ozone molecule as a concrete example where n­polyads or ``hyperpolyads'' should structure of the vibrational levels of ozone. We consider the classical mechanical analogue

  13. Using transport diagnostics to understand chemistry climate model ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Using transport diagnostics to understand chemistry climate model ozone simulations Article chemistry climate model ozone simulations. Journal of Geophysical Research - Atmospheres, 116 (D17). D17302 transport diagnostics to understand chemistry climate model ozone simulations S. E. Strahan,1 A. R. Douglass

  14. A comparison study of data assimilation algorithms for ozone forecasts

    E-Print Network [OSTI]

    Mallet, Vivien

    A comparison study of data assimilation algorithms for ozone forecasts Lin Wu,1,2 V. Mallet,1,2 M assimilation schemes with the aim of designing suitable assimilation algorithms for short- range ozone but stable systems with high uncertainties (e.g., over 20% for ozone daily peaks (Hanna et al., 1998; Mallet

  15. On the statistical modeling of persistence in total ozone anomalies

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    On the statistical modeling of persistence in total ozone anomalies Article Published Version in total ozone anomalies. Journal of Geophysical Research, 115. D16306. ISSN 0148-0227 doi: 10.1029/2009JD the statistical modeling of persistence in total ozone anomalies D. I. Vyushin,1 T. G. Shepherd,1 and V. E

  16. Ozone Chemistry in the High-Latitude Boundary Layer

    E-Print Network [OSTI]

    Toohey, Darin W.

    Ozone Chemistry in the High-Latitude Boundary Layer Linnea Avallone Department of Atmospheric layer ozone loss phenomenon · In situ observations of BrO at Arctic sites · Preliminary results from Antarctic experiments in 2002 and 2004 #12;Brief History · Springtime ozone loss observed at many sites

  17. Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Effectiveness of Houseplants in Reducing the Indoor Air Pollutant Ozone Heather L. Papinchak1 , E for their species effectiveness in reducing ozone concentrations in a simulated indoor environment. Continuously supply system were used to simulate an indoor environment in which ozone concentrations could be measured

  18. Ozone Treatments of Fresh Atlantic Cod, Gadus morhua

    E-Print Network [OSTI]

    Ozone Treatments of Fresh Atlantic Cod, Gadus morhua ELINOR M. RAVESI, JOSEPH J. L1CCIARDELLO and LINDA D. RACICOT Introduction The strong oxidizing nature of ozone, known since its discovery in 1840 (1977) cited in a review article numerous reports of the successful use of ozone to I) control microbial

  19. Relative importance of radical families The "Ozone Hole"

    E-Print Network [OSTI]

    Toohey, Darin W.

    · Relative importance of radical families · The "Ozone Hole" · Introduction to heterogeneous chemistry Tuesday, March 8, 2011 #12;Review of important points so far Stratospheric ozone is only produced with these parameters Sir Sydney Chapman nearly got it right. He could account for the formation of the ozone layer

  20. oZONE Faculty and Staff Course Overrides

    E-Print Network [OSTI]

    Oklahoma, University of

    oZONE Faculty and Staff Course Overrides and the Registration Add Errors They Resolve Departments of the overrides within the registration component of oZONE. We have, however, retained a few instances where some. There is also a link to this document on the Student Training and Instructions page in the oZONE info site

  1. Quantum origin of an anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Quantum origin of an anomalous isotope effect in ozone formation D. Babikov *, B.K. Kendrick, R mechanical calculations of the ðJ ¼ 0Þ energies and lifetimes of the metastable states of ozone on a new effect in the reaction that forms ozone because of their role in the energy transfer mechanism, in which

  2. The Ozone Layer in the 21st Lead Authors

    E-Print Network [OSTI]

    Robock, Alan

    CHAPTER 6 The Ozone Layer in the 21st Century Lead Authors: G.E. Bodeker D.W. Waugh Coauthors: H;#12;CHAPTER 6 THE OZONE LAYER IN THE 21ST CENTURY Contents SCIENTIFIC SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.5 6.2 A FRAMEWORK FOR EVALUATING CHANGES IN OZONE ABUNDANCES

  3. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982004 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2004 tropical ozone climatology: 3 more than 3000 ozone profiles from 14 tropical and subtropical sites using balloon- borne technique might cause small station-to-station biases in the total ozone measurement. We present further

  4. Summertime total ozone variations over middle and polar latitudes

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Summertime total ozone variations over middle and polar latitudes Article Published Version Fioletov, V. E. and Shepherd, T. G. (2005) Summertime total ozone variations over middle and polar's research outputs online #12;Summertime total ozone variations over middle and polar latitudes Vitali E

  5. Arctic ozone loss and climate sensitivity: Updated threedimensional model study

    E-Print Network [OSTI]

    Feng, Wuhu

    Arctic ozone loss and climate sensitivity: Updated three­dimensional model study Chipperfield winter­spring chemical ozone loss from 1991 2003, its observed correlation with low temperatures. CTM throughout studied. The model reproduces large column winters also captures shape of ozone loss profile

  6. Southern Hemisphere Additional Ozonesondes (SHADOZ) 19982000 tropical ozone climatology

    E-Print Network [OSTI]

    Thompson, Anne

    Southern Hemisphere Additional Ozonesondes (SHADOZ) 1998­2000 tropical ozone climatology 1. Comparison with Total Ozone Mapping Spectrometer (TOMS) and ground-based measurements Anne M. Thompson,1 Additional Ozonesondes (SHADOZ) project and established from operational sites, provided over 1000 ozone

  7. GLOBAL CHANGE ECOLOGY N. J. Karberg K. S. Pregitzer J. S. King

    E-Print Network [OSTI]

    carbon dioxide partial pressure and dissolved inorganic carbonate chemistry under elevated carbon dioxide Carbon-13 Æ Carbon sequestration Æ FACE Æ Free air carbon dioxide and ozone enrichment Æ Global carbonate-Verlag 2004 Abstract Global emissions of atmospheric CO2 and tropospheric O3 are rising and expected to impact

  8. The economics of fuel depletion in fast breeder reactor blankets

    E-Print Network [OSTI]

    Brewer, Shelby Templeton

    1972-01-01

    A fast breeder reactor fuel depletion-economics model was developed and applied to a number of 1000 MWe UMBR case studies, involving radial blanket-radial reflector design, radial blanket fuel management, and sensitivity ...

  9. Hyperspectral stimulated emission depletion microscopy and methods of use thereof

    DOE Patents [OSTI]

    Timlin, Jerilyn A; Aaron, Jesse S

    2014-04-01

    A hyperspectral stimulated emission depletion ("STED") microscope system for high-resolution imaging of samples labeled with multiple fluorophores (e.g., two to ten fluorophores). The hyperspectral STED microscope includes a light source, optical systems configured for generating an excitation light beam and a depletion light beam, optical systems configured for focusing the excitation and depletion light beams on a sample, and systems for collecting and processing data generated by interaction of the excitation and depletion light beams with the sample. Hyperspectral STED data may be analyzed using multivariate curve resolution analysis techniques to deconvolute emission from the multiple fluorophores. The hyperspectral STED microscope described herein can be used for multi-color, subdiffraction imaging of samples (e.g., materials and biological materials) and for analyzing a tissue by Forster Resonance Energy Transfer ("FRET").

  10. ProteoSpinTM Abundant Serum Protein Depletion Kit

    E-Print Network [OSTI]

    Lebendiker, Mario

    abundance proteins. Depleted serum profile on 2D is clean and smearless with enrich- ment of some minor CORPORATION 3 General Introduction 2The use of body fluids, including serum and plasma, has become widespread

  11. Depleted Uranium Hexafluoride (DUF6) Fully Operational at the...

    Broader source: Energy.gov (indexed) [DOE]

    Jack Zimmerman, DUF6 at the PortsmouthPaducah Project Office. DUF6 is depleted uranium hexafluoride, a byproduct of uranium enrichment that has taken place at U.S. gaseous...

  12. Lymphocyte depletion in peripheral blood of gamma irradiated rats 

    E-Print Network [OSTI]

    Goldin, Eric Michael

    1972-01-01

    LYMPHOCYTE DEPLETION IN PERIPHERAL BLOOD OF GAMMA IRRADIATED RATS A Thesis by ERIC MICHAEL GOLDIN Submitted to the Graduate College of Texas ABM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... December 1972 Major Subject: Nuclear Engineering (Health Physics) LYMPHOCYTE DEPLETION IN PERIPHERAL BLOOD OF GAMMA IRRADIATED RATS A Thesis by ERIC MICHAEL GOLDIN Approved as to sty1e and con ent by: ( hairman of Co it ee) (H of Depar ment...

  13. Retrieval of buried depleted uranium from the T-1 trench

    SciTech Connect (OSTI)

    Burmeister, M.; Castaneda, N.; Greengard, T. |; Hull, C.; Barbour, D.; Quapp, W.J.

    1998-07-01

    The Trench 1 remediation project will be conducted this year to retrieve depleted uranium and other associated materials from a trench at Rocky Flats Environmental Technology Site. The excavated materials will be segregated and stabilized for shipment. The depleted uranium will be treated at an offsite facility which utilizes a novel approach for waste minimization and disposal through utilization of a combination of uranium recycling and volume efficient uranium stabilization.

  14. DOE Announces Transfer of Depleted Uranium to Advance the U.S...

    Energy Savers [EERE]

    Transfer of Depleted Uranium to Advance the U.S. National Security Interests, Extend Operations at Paducah Gaseous Diffusion Plant DOE Announces Transfer of Depleted Uranium to...

  15. Engineering analysis report for the long-term management of depleted uranium hexafluoride : storage of depleted uranium metal.

    SciTech Connect (OSTI)

    Folga, S.M.; Kier, P.H.; Thimmapuram, P.R.

    2001-01-24

    This report contains an engineering analysis of long-term storage of uranium metal in boxes as an option for long-term management of depleted uranium hexafluoride (UF{sub 6}). Three storage facilities are considered: buildings, vaults, and mined cavities. Three cases are considered: either all, half, or a quarter of the depleted uranium metal that would be produced from the conversion of depleted UF{sub 6} is stored at the facility. The analysis of these alternatives is based on a box design used in the Final Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride, report DOE/EIS-0269, published in 1999 by the US Department of Energy. This box design does not appear to effectively use space within the box. Hence, an alternative box design that allows for a reduced storage area is addressed in the appendices for long-term storage in buildings.

  16. The Effects of Gaseous Ozone and Nitric Acid Deposition on two Crustose Lichen Species From Joshua Tree National Park

    E-Print Network [OSTI]

    Hessom, Elizabeth Curie

    2012-01-01

    photosynthetic rate responses to ozone in some foliose andof gaseous nitric acid and ozone on lichens. Dissertations &with nitric acid and ozone. Environmental Pollution, In

  17. Tropospheric column ozone: matching individual profiles from Aura OMI and TES with a chemistry-transport model

    E-Print Network [OSTI]

    Tang, Q.; Prather, M. J

    2012-01-01

    Science Objectives of the Ozone Monitoring In- strument,G. J. , and Logan, J. A. : Ozone climatolog- ical profilestroposphere ex- change ozone flux related to deep

  18. Megacity impacts on regional ozone formation: observations and WRF-Chem modeling for the MIRAGE-Shanghai field campaign

    E-Print Network [OSTI]

    2013-01-01

    Tie, X. : Analysis of ozone and VOCs measured in Shanghai: AMegacity impacts on regional ozone formation terminations inand Tie, X. : Study of ozone “weekend effect” in Shanghai,

  19. Ozone, water vapor, and temperature in the upper tropical troposphere: Variations over a decade of MOZAIC measurements

    E-Print Network [OSTI]

    Bortz, Sarah E; Prather, Michael J; Cammas, Jean-Pierre; Thouret, Valérie; Smit, Herman

    2006-01-01

    An extension of the measurement of ozone and water vapour byin-service Aircraft (MOZAIC) ozone climatologies usingcomparison with SHADOZ ozone and MODIS aerosol, J. Geophys.

  20. Ozone Reductions using Residential Building Envelopes

    E-Print Network [OSTI]

    for Energy Efficiency and Renewable Energy, Building Technologies Program, of the U.S. Department of Energy Residential Building Envelopes Prepared For: California Energy Commission Public Interest Energy ResearchOzone Reductions using Residential Building Envelopes I.S. Walker, M.H. Sherman and W.W. Nazaroff

  1. Effect of Shim Arm Depletion in the NBSR

    SciTech Connect (OSTI)

    Hanson A. H.; Brown N.; Diamond, D.J.

    2013-02-22

    The cadmium shim arms in the NBSR undergo burnup during reactor operation and hence, require periodic replacement. Presently, the shim arms are replaced after every 25 cycles to guarantee they can maintain sufficient shutdown margin. Two prior reports document the expected change in the 113Cd distribution because of the shim arm depletion. One set of calculations was for the present high-enriched uranium fuel and the other for the low-enriched uranium fuel when it was in the COMP7 configuration (7 inch fuel length vs. the present 11 inch length). The depleted 113Cd distributions calculated for these cores were applied to the current design for an equilibrium low-enriched uranium core. This report details the predicted effects, if any, of shim arm depletion on the shim arm worth, the shutdown margin, power distributions and kinetics parameters.

  2. Tuning of depletion interaction in nanoparticle-surfactant systems

    SciTech Connect (OSTI)

    Ray, D., E-mail: debes@barc.gov.in; Aswal, V. K., E-mail: debes@barc.gov.in [Solid State Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India)

    2014-04-24

    The interaction of anionic silica nanoparticles (Ludox LS30) and non-ionic surfactants decaethylene glycol monododecylether (C12E10) without and with anionic sodium dodecyl sulfate (SDS) in aqueous electrolyte solution has been studied by small-angle neutron scattering (SANS). The measurements have been carried out for fixed concentrations of nanoparticle (1 wt%), surfactants (1 wt%) and electrolyte (0.1 M NaCl). Each of these nanoparticlesurfactant systems has been examined for different contrast conditions where individual components (nanoparticle or surfactant) are made visible. It is observed that the nanoparticle-C12E10 system leads to the depletion-induced aggregation of nanoparticles. The system however behaves very differently on addition of SDS where depletion interaction gets suppressed and aggregation of nanoparticles can be prevented. We show that C12E10 and SDS form mixed micelles and the charge on these micelles plays important role in tuning the depletion interaction.

  3. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, C.W.

    1998-11-03

    A method is described for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package. 6 figs.

  4. Depleted uranium as a backfill for nuclear fuel waste package

    DOE Patents [OSTI]

    Forsberg, Charles W. (Oak Ridge, TN)

    1998-01-01

    A method for packaging spent nuclear fuel for long-term disposal in a geological repository. At least one spent nuclear fuel assembly is first placed in an unsealed waste package and a depleted uranium fill material is added to the waste package. The depleted uranium fill material comprises flowable particles having a size sufficient to substantially fill any voids in and around the assembly and contains isotopically-depleted uranium in the +4 valence state in an amount sufficient to inhibit dissolution of the spent nuclear fuel from the assembly into a surrounding medium and to lessen the potential for nuclear criticality inside the repository in the event of failure of the waste package. Last, the waste package is sealed, thereby substantially reducing the release of radionuclides into the surrounding medium, while simultaneously providing radiation shielding and increased structural integrity of the waste package.

  5. Relations between isoprene and nitric oxide in exhaled breath and the potential influence of outdoor ozone: a pilot study

    E-Print Network [OSTI]

    Khan, Alya; Staimer, Norbert; Tjoa, Thomas; Galassetti, Pietro; Blake, Donald R.; Delfino, Ralph J.

    2013-01-01

    2-day 3-day 5-day a 12.7 ppb ozone b Adjusted for splines ofoutput after exposure to ozone. J Appl Physiol. 1996; 80:apparatus against ozone damage, quenches ozone products, and

  6. Characterization of Thermal Properties of Depleted Uranium Metal Microspheres 

    E-Print Network [OSTI]

    Humrickhouse, Carissa Joy

    2012-07-16

    llment of the requirements for the degree of MASTER OF SCIENCE Approved by: Chair of Committee, Sean M. McDeavitt Committee Members, Kenneth L. Peddicord Lin Shao Head of Department, Yassin A. Hassan May 2012 Major Subject: Nuclear Engineering iii.../m-K) Density (units: g/cm3) CHTA Crucible Heater Test Assembly DU Depleted uranium EU Enriched uranium LFA Laser (or light) ash analysis LFA 447 Light ash analyzer, model 447, by Netzsch Instruments LWR Light water reactor ODU Oxidized depleted uranium...

  7. Role of nucleonic Fermi surface depletion in neutron star cooling

    E-Print Network [OSTI]

    Dong, J M; Zhang, H F; Zuo, W

    2015-01-01

    The Fermi surface depletion of beta-stable nuclear matter is calculated to study its effects on several physical properties which determine the neutron star thermal evolution. The neutron and proton Z factors measuring the corresponding Fermi surface depletions, are calculated within the Brueckner-Hartree-Fock approach employing the AV18 two-body force supplemented by a microscopic three body force. Neutrino emissivity, heat capacity and, in particular, neutron 3PF2 superfluidity turn out to be reduced, especially at high baryonic density, to such an extent that the cooling rates of young neutron stars are significantly slowed

  8. Role of nucleonic Fermi surface depletion in neutron star cooling

    E-Print Network [OSTI]

    J. M. Dong; U. Lombardo; H. F. Zhang; W. Zuo

    2015-12-09

    The Fermi surface depletion of beta-stable nuclear matter is calculated to study its effects on several physical properties which determine the neutron star thermal evolution. The neutron and proton Z factors measuring the corresponding Fermi surface depletions, are calculated within the Brueckner-Hartree-Fock approach employing the AV18 two-body force supplemented by a microscopic three body force. Neutrino emissivity, heat capacity and, in particular, neutron 3PF2 superfluidity turn out to be reduced, especially at high baryonic density, to such an extent that the cooling rates of young neutron stars are significantly slowed

  9. Global Predictions 

    E-Print Network [OSTI]

    Swyden, Courtney

    2006-01-01

    stream_source_info Global Predictions.pdf.txt stream_content_type text/plain stream_size 7503 Content-Encoding ISO-8859-1 stream_name Global Predictions.pdf.txt Content-Type text/plain; charset=ISO-8859-1 Every morning... drought index is based on a daily water balance, where a drought factor is calculated with precipitation and soil moisture,? Srinivasan said. Global Predictions Story by Courtney Swyden Global Predictions Lab uses advanced technologies to forecast...

  10. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean 

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31

    Despite the known reactivity of ozone (O_(3)) in water and ozone’s environmental importance in the atmosphere, there are relatively few studies published examining the chemistry of O_(3) in seawater. This study focused on ...

  11. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    E-Print Network [OSTI]

    Jin, Ling

    2010-01-01

    Vertical distribution of ozone at four sites in the UnitedAltshuler, S. ; Franco, G. Ozone formation in California'sSeinfeld, J. H. Analysis of ozone in the San Joaquin Valley

  12. Reactivity of Ozone with Solid Potassium Iodide Investigated by Atomic Force Microscopy

    E-Print Network [OSTI]

    Brown, Matthew A.

    2008-01-01

    J. C. , Reactivity of ozone on solid potassium iodide.and mechanisms of aqueous ozone reactions with bromide,for Dry Deposition of Ozone to Seawater Surfaces. Journal of

  13. Ground-level ozone influenced by circadian control of isoprene emissions

    E-Print Network [OSTI]

    2011-01-01

    S. The relation between ozone, NO x and hydrocarbons inAmerican emissions on surface ozone in the US. Atmos. Chem.10.1038/NGEO1271 Ground-level ozone influenced by circadian

  14. OZONE INDUCED CONDUCTANCE INCREASES ASSAYED WITH LIPID IMPREGNATED FILTER MEMBRANES-EFFECT OF VITAMIN E

    E-Print Network [OSTI]

    Sheih, P.K

    2011-01-01

    29-44. R. L. Heath (1975) Ozone, in Response of Plants toSince it is possible that ozone absorption "is incompleteof the filter. After the ozone treatment was stopped the

  15. Secondary Pollutants from Ozone Reaction with Ventilation Filters and Degradation of Filter Media Additives

    E-Print Network [OSTI]

    Destaillats, Hugo

    2012-01-01

    used in LBNL, exposed to 150 ppb ozone at two different flowMendell, 2008. Outdoor ozone and building-related symptomsAir filter materials, outdoor ozone and building-related

  16. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D7, PAGES 9873-9887, JULY 20, 1989 The Sensitivity of Total Ozone and Ozone Perturbation Scenarios

    E-Print Network [OSTI]

    Jackman, Charles H.

    of Total Ozone and Ozone Perturbation Scenarios in a Two-Dimensional Model Due to Dynamical Inputs CHARLESTland The sensitivity of the total ozone distribution in our two-dimensional photochemical model to dynamical inputs has average total ozone varies by up to 10%. dependingon the various dynamical inputs, and the seasonaland

  17. Ozone treatment in a closed culture system for Macrobrachium rosenbergii 

    E-Print Network [OSTI]

    Yamaguchi, Ryoji

    1978-01-01

    periodically and analyzed for total ammonia nitrogen and nitrate nitrogen concentrations using the Direct Nessleriza- tion Method and the Cadmium Reduction Method, respectively (APHA, 1976) . 2. Chemical oxygen demand (COD) and ozonation: The solutions... level. 29 7. Tests of the homogeneity of variance and oneway analysis of variance for the effects of ozonation on two levels of nitrite nitrogen concentration with 95X confidence limit. . . . 31 8. Effects of ozone on ammonia, nitrite, nitrate, COD...

  18. Tropospheric Ozone ATOC/CHEM 5151

    E-Print Network [OSTI]

    Toohey, Darin W.

    ) ( production! #12;18 Ozone production CO + OH CO2 + H loss · Photolysis (1.4 x 1011 cm-2 s-1) · Oxidation of CO (3.5 x 1011 cm-2 s-1) 4. Chemical production #12;23 Formaldehyde chemistry CH2O + h H + HCO H + O2 + M HO2 + M HCO + O2 CO + HO2 2x [HO2

  19. Estimating changes in urban ozone concentrations due to life cycle emissions from hydrogen transportation systems

    E-Print Network [OSTI]

    Wang, Guihua; Ogden, Joan M; Chang, Daniel P.Y.

    2007-01-01

    of natural gas to hydrogen pathways on urban air quality.Natural gas (NG); Hydrogen pathways; Ozone formation; Ozone air quality

  20. EIS-0269: Long-Term Management of Depleted Uranium Hexaflouride

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) prepared this programmatic environmental impact statement to assess the potential impacts of alternative management strategies for depleted uranium hexafluoride currently stored at three DOE sites: Paducah site near Paducah, Kentucky; Portsmouth site near Portsmouth, Ohio; and K-25 site on the Oak Ridge Reservation in Oak Ridge, Tennessee.

  1. Population and Climate Change: How Depletion of Nature and

    E-Print Network [OSTI]

    Maryland at College Park, University of

    , Deforestation, Desertification, etc Inputs: 1. Energy Oil, Coal, Gas, Nuclear, Biomass, Renewables, etc 2Population and Climate Change: How Depletion of Nature and Human Inequality Impact Sustainability best farmland This is not sustainable: "We are drawing down the stock of natural capital

  2. Lithium depletion and the rotational history of exoplanet host stars

    E-Print Network [OSTI]

    Jerome Bouvier

    2008-09-03

    Israelian et al. (2004) reported that exoplanet host stars are lithium depleted compared to solar-type stars without detected massive planets, a result recently confirmed by Gonzalez (2008). We investigate whether enhanced lithium depletion in exoplanet host stars may result from their rotational history. We have developed rotational evolution models for slow and fast solar-type rotators from the pre-main sequence (PMS) to the age of the Sun and compare them to the distribution of rotational periods observed for solar-type stars between 1 Myr and 5 Gyr. We show that slow rotators develop a high degree of differential rotation between the radiative core and the convective envelope, while fast rotators evolve with little core-envelope decoupling. We suggest that strong differential rotation at the base of the convective envelope is responsible for enhanced lithium depletion in slow rotators. We conclude that lithium-depleted exoplanet host stars were slow rotators on the zero-age main sequence (ZAMS) and argue that slow rotation results from a long lasting star-disk interaction during the PMS. Altogether, this suggests that long-lived disks (> 5 Myr) may be a necessary condition for massive planet formation/migration.

  3. Depleted-Heterojunction Colloidal Quantum Dot Solar Cells

    E-Print Network [OSTI]

    Sargent, Edward H. "Ted"

    -processed single-junction cells and also multijunction architectures. Size-effect tuning also en- ables the useDepleted-Heterojunction Colloidal Quantum Dot Solar Cells Andras G. Pattantyus-Abraham,, Illan J requires thick, high-purity solar cells with correspondingly long carrier transport lengths;3 organic

  4. Widespread foliage d15 N depletion under elevated CO2

    E-Print Network [OSTI]

    Thomas, David D.

    Widespread foliage d15 N depletion under elevated CO2: inferences for the nitrogen cycle H O R M O an integrated assessment of the nitrogen (N) cycle and whether it is influenced by rising atmospheric CO2 concentration. We tested the hypothesis that elevated CO2 significantly changes foliage d15 N in a wide range

  5. Running into an out of oil: Scenarios of global oil use and resource depletion to 2050

    SciTech Connect (OSTI)

    Greene, David L.; Hopson, Janet L.; Li, Jia

    2002-07-23

    Is a transition from conventional oil imminent? Is it likely to lock the world into a high-carbon energy future? This report attempts to shed some light on these questions.

  6. Global energy and global precipitation

    E-Print Network [OSTI]

    1 Global energy and global precipitation or Why doesn't precipitation increase as Clausias expect precipitation to increase at the same rate. · Rest of this brief talk is to show you why Heat Flux (S) 20 W/m2 Atmospheric heating from precipitation LP Atmosphere has small heat capacity. So

  7. CRDIAC: Coupled Reactor Depletion Instrument with Automated Control

    SciTech Connect (OSTI)

    Steven K. Logan

    2012-08-01

    When modeling the behavior of a nuclear reactor over time, it is important to understand how the isotopes in the reactor will change, or transmute, over that time. This is especially important in the reactor fuel itself. Many nuclear physics modeling codes model how particles interact in the system, but do not model this over time. Thus, another code is used in conjunction with the nuclear physics code to accomplish this. In our code, Monte Carlo N-Particle (MCNP) codes and the Multi Reactor Transmutation Analysis Utility (MRTAU) were chosen as the codes to use. In this way, MCNP would produce the reaction rates in the different isotopes present and MRTAU would use cross sections generated from these reaction rates to determine how the mass of each isotope is lost or gained. Between these two codes, the information must be altered and edited for use. For this, a Python 2.7 script was developed to aid the user in getting the information in the correct forms. This newly developed methodology was called the Coupled Reactor Depletion Instrument with Automated Controls (CRDIAC). As is the case in any newly developed methodology for modeling of physical phenomena, CRDIAC needed to be verified against similar methodology and validated against data taken from an experiment, in our case AFIP-3. AFIP-3 was a reduced enrichment plate type fuel tested in the ATR. We verified our methodology against the MCNP Coupled with ORIGEN2 (MCWO) method and validated our work against the Post Irradiation Examination (PIE) data. When compared to MCWO, the difference in concentration of U-235 throughout Cycle 144A was about 1%. When compared to the PIE data, the average bias for end of life U-235 concentration was about 2%. These results from CRDIAC therefore agree with the MCWO and PIE data, validating and verifying CRDIAC. CRDIAC provides an alternative to using ORIGEN-based methodology, which is useful because CRDIAC's depletion code, MRTAU, uses every available isotope in its depletion, unlike ORIGEN, which only depletes the isotopes specified by the user. This means that depletions done by MRTAU more accurately reflect reality. MRTAU also allows the user to build new isotope data sets, which means any isotope with nuclear data could be depleted, something that would help predict the outcomes of nuclear reaction testing in materials other than fuel, like beryllium or gold.

  8. Reactive uptake of ozone at simulated leaf surfaces: implications for "non-stomatal" ozone flux 

    E-Print Network [OSTI]

    Cape, J Neil; Hamilton, Richard P; Heal, Mathew R

    2009-01-01

    The reaction of ozone (O3) with ?-pinene has been studied as a function of temperature and relative humidity and in the presence of wax surfaces that simulate a leaf surface. The objective was to determine whether the presence of a wax surface...

  9. Observed relationships of ozone air pollution with temperature and emissions

    E-Print Network [OSTI]

    Stehr, Jeffrey

    Observed relationships of ozone air pollution with temperature and emissions Bryan J. Bloomer,1, and R. R. Dickerson (2009), Observed relationships of ozone air pollution with temperature and emissions decreased by 43% for the time period 1995 to 2002 compared with 2003 to 2006 as a result of air pollution

  10. URBAN OZONE CONCENTRATION FORECASTING WITH ARTIFICIAL NEURAL NETWORK IN CORSICA

    E-Print Network [OSTI]

    Boyer, Edmond

    Perceptron; Ozone concentration. 1. Introduction Tropospheric ozone is a major air pollution problem, both, Ajaccio, France, e-mail: balu@univ-corse.fr Abstract: Atmospheric pollutants concentration forecasting is an important issue in air quality monitoring. Qualitair Corse, the organization responsible for monitoring air

  11. ORIGINAL CONTRIBUTION Ozone and Short-term Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    . With the National Morbidity, Mortality, and Air Pollution Study (NMMAPS), we have developed na- tional approaches Ambient Air Qual- ity Standard (NAAQS) for ozone, adding a daily maximum 8-hour stan- dard of 80 ppb.19 Because of the relevance of epidemiologic evi- dence to the NAAQS for ozone and other pollutants

  12. Accounting for Depletion of Oil and Gas Resources in Malaysia

    SciTech Connect (OSTI)

    Othman, Jamal Jafari, Yaghoob

    2012-12-15

    Since oil and gas are non-renewable resources, it is important to identify the extent to which they have been depleted. Such information will contribute to the formulation and evaluation of appropriate sustainable development policies. This paper provides an assessment of the changes in the availability of oil and gas resources in Malaysia by first compiling the physical balance sheet for the period 2000-2007, and then assessing the monetary balance sheets for the said resource by using the Net Present Value method. Our findings show serious reduction in the value of oil reserves from 2001 to 2005, due to changes in crude oil prices, and thereafter the depletion rates decreased. In the context of sustainable development planning, albeit in the weak sustainability sense, it will be important to ascertain if sufficient reinvestments of the estimated resource rents in related or alternative capitals are being attempted by Malaysia. For the study period, the cumulative resource rents were to the tune of RM61 billion. Through a depletion or resource rents policy, the estimated quantum may guide the identification of a reinvestment threshold (after considering needed capital investment for future development of the industry) in light of ensuring the future productive capacity of the economy at the time when the resource is exhausted.

  13. Modeling Transport E ects on Ground-Level Ozone Using a

    E-Print Network [OSTI]

    Huang, Su-Yun

    Modeling Transport E ects on Ground-Level Ozone Using a Non-Stationary Space-Time Model Hsin on Ground-Level Ozone 1 #12;Summary This article presents a novel autoregressive space-time model for ground-level ozone data, which models not only spatio-temporal dynamics of hourly ozone con- centrations, but also

  14. Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Aakash C. Rai1

    E-Print Network [OSTI]

    Chen, Qingyan "Yan"

    Simulations of Ozone Distributions in an Aircraft Cabin Using Computational Fluid1 Dynamics2 3 10 Ozone is a major pollutant of indoor air. Many studies have demonstrated the adverse health effect of11 ozone and the byproducts generated as a result of ozone-initiated reactive chemistry

  15. Improving total column ozone retrievals by using cloud pressures derived from Raman scattering in the UV

    E-Print Network [OSTI]

    Joiner, Joanna

    Improving total column ozone retrievals by using cloud pressures derived from Raman scattering resolution, coverage, and sampling of the Aura satellite ozone monitoring instrument (OMI), as compared with the total ozone mapping spectrometer (TOMS) should allow for improved ozone retrievals. By default, the TOMS

  16. Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Passive Ozone Control Through Use of Reactive Indoor Wall and Ceiling Materials Paper # 715 Donna A) Austin, TX 78758, USA ABSTRACT Most ozone exposure occurs indoors even though some surfaces consume ozone and reduce its concentration relative to outdoors. Ozone consumption often results in emissions of secondary

  17. An intramolecular theory of the mass-independent isotope effect for ozone. I.

    E-Print Network [OSTI]

    Hathorn, Bryan C.

    An intramolecular theory of the mass-independent isotope effect for ozone. I. B. C. Hathorn and R-independent isotope effect for ozone formation and dissociation is described. The experiments include the enrichment and asymmetric ozone isotopomers, the enrichment of ozone formed from heavily enriched oxygen isotopes

  18. A cohesive total ozone data set from the SBUV(/2) satellite system A. J. Miller,1

    E-Print Network [OSTI]

    Jackman, Charles H.

    A cohesive total ozone data set from the SBUV(/2) satellite system A. J. Miller,1 R. M. Nagatani,1 of total ozone estimates from the Solar Backscatter Ultraviolet Ozone Sensors (SBUVand SBUV/2) began of individual instruments are good, they give total ozone accuracies of approximately 2%. However, without

  19. PPPL-3281, Preprint: January 1998, UC-426 Synthesis of Ozone at Atmospheric Pressure

    E-Print Network [OSTI]

    in industrial processes is increasing. Applications for ozone include treatment of waste water, water

  20. Accelerated Depletion: Assessing Its Impacts on Domestic Oil and Natural Gas Prices and Production

    Reports and Publications (EIA)

    2000-01-01

    Analysis of the potential impacts of accelerated depletion on domestic oil and natural gas prices and production.

  1. Global warming, global research, and global governing

    SciTech Connect (OSTI)

    Preining, O.

    1997-12-31

    The anticipated dangers of Global Warming can be mitigated by reducing atmospheric greenhouse gas concentrations, especially CO{sub 2}. To reach acceptable, constant levels within the next couple of centuries it might be necessary to accept stabilization levels higher than present ones, The annual CO{sub 2} emissions must be reduced far below today`s values. This is a very important result of the models discussed in the 1995 IPCC report. However, any even very modest scenario for the future must take into account a substantial increase in the world population which might double during the 21st century, There is a considerable emission reduction potential of the industrialized world due to efficiency increase, However, the demand for energy services by the growing world population will, inspite of the availability of alternative energy resources, possibly lead to a net increase in fossil fuel consumption. If the climate models are right, and the science community believes they are, we will experience a global warming of the order of a couple of degrees over the next century; we have to live with it. To be prepared for the future it is essential for us to use new research techniques embracing not only the familiar fields of hard sciences but also social, educational, ethical and economic aspects, We must find a way to build up the essential intellectual capacities needed to deal with these kinds of general problems within all nations and all societies. But this is not Although, we also have to find the necessary dynamical and highly flexible structures for a global governing using tools such as the environmental regime. The first step was the Framework Convention On Climate Change, UN 1992; for resolution of questions regarding implementations the Conference of the Parties was established.

  2. Global Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you not findGeoscience/EnvironmentGlobal Security Global Security

  3. Global Warming

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Low LETUseful LinksGlass StrongerGlobalOn1 Global

  4. Essays on the Impact of Climate Change and Building Codes on Energy Consumption and the Impact of Ozone on Crop Yield

    E-Print Network [OSTI]

    Aroonruengsawat, Anin

    2010-01-01

    14 Impact of ozone on crop yield15 Data 15.1 OzoneEstimated effect of mean ozone on crop yields. . . . . . .

  5. Evaluation of microporous carbon filters as catalysts for ozone decomposition

    SciTech Connect (OSTI)

    Whinnery, L.; Coutts, D.; Shen, C.; Adams, R. [Sandia National Labs., Livermore, CA (United States); Quintana, C.; Showalter, S. [Sandia National Labs., Albuquerque, NM (United States)

    1994-12-31

    Ozone is produced in small quantities in photocopiers and laser printers in the workplace and large quantities in industrial waste water treatment facilities. Carbon filters are commonly used to decompose this unwanted ozone. The three most important factors in producing a filter for this purpose are flow properties, efficiency, and cost. Most ozone decomposition applications require very low back-pressure at modest flow rates. The tradeoff between the number of pores and the size of the pores will be discussed. Typical unfiltered emissions in the workplace are approximately 1 ppm. The maximum permissible exposure limit, PEL, for worker exposure to ozone is 0.1 ppm over 8 hours. Several methods have been examined to increase the efficiency of ozone decomposition. Carbon surfaces were modified with catalysts, the surface activated, and the surface area was increased, in attempts to decompose ozone more effectively. Methods to reduce both the processing and raw material costs were investigated. Several sources of microporous carbon were investigated as ozone decomposition catalysts. Cheaper processing routes including macropore templating, faster drying and extracting methods were also studied.

  6. Exposure-Relevant Ozone Chemistry in Occupied Spaces

    SciTech Connect (OSTI)

    Coleman, Beverly Kaye

    2009-04-01

    Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft cabins, to form phosgene is investigated. A derivatization technique was developed to detect phosgene at low levels, and chamber experiments were conducted with permethrin-coated cabin materials. It was determined that phosgene formation, if it occurs in the aircraft cabin, is not likely to exceed the relevant, health-based phosgene exposure guidelines.

  7. Inhibition of lytic infection of pseudorabies virus by arginine depletion

    SciTech Connect (OSTI)

    Wang, H.-C. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China); Kao, Y.-C. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China); Chang, T-J. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China); Wong, M.-L. [Department of Veterinary Medicine, College of Veterinary Medicine, National Chung-Hsing University, Taichung 402, Taiwan (China)]. E-mail: mlwong@dragon.nchu.edu.tw

    2005-08-26

    Pseudorabies virus (PRV) is a member of Alphahepesviruses; it is an enveloped virus with a double-stranded DNA genome. Polyamines (such as spermine and spermidine) are ubiquitous in animal cells and participate in cellular proliferation and differentiation. Previous results of our laboratory showed that the PRV can accomplish lytic infection either in the presence of exogenous spermine (or spermidine) or depletion of cellular polyamines. The amino acid arginine is a precursor of polyamine biosynthesis. In this work, we investigated the role of arginine in PRV infection. It was found that the plaque formation of PRV was inhibited by arginase (enzyme catalyzing the conversion of arginine into ornithine and urea) treatment whereas this inhibition can be reversed by exogenous arginine, suggesting that arginine is essential for PRV proliferation. Western blotting was conducted to study the effect of arginine depletion on the levels of structural proteins of PRV in virus-infected cells. Four PRV structural proteins (gB, gE, UL47, and UL48) were chosen for examination, and results revealed that the levels of viral proteins were obviously reduced in long time arginase treatment. However, the overall protein synthesis machinery was apparently not influenced by arginase treatment either in mock or PRV-infected cells. Analyzing with native gel, we found that arginase treatment affected the mobility of PRV structural proteins, suggesting the conformational change of viral proteins by arginine depletion. Heat shock proteins, acting as molecular chaperons, participate in protein folding and translocation. Our results demonstrated that long time arginase treatment could reduce the expression of cellular heat shock proteins 70 (hsc70 and hsp70), and transcriptional suppression of heat shock protein 70 gene promoter was one of the mechanisms involved in this reduced expression.

  8. Implementation of global energy sustainability

    SciTech Connect (OSTI)

    Grob, G.R.

    1998-02-01

    The term energy sustainability emerged from the UN Conference on Environment and Development in Rio 1992, when Agenda 21 was formulated and the Global Energy Charter proclaimed. Emission reductions, total energy costing, improved energy efficiency, and sustainable energy systems are the four fundamental principles of the charter. These principles can be implemented in the proposed financial, legal, technical, and education framework. Much has been done in many countries toward the implementation of the Global Energy Charter, but progress has not been fast enough to ease the disastrous effects of the too many ill-conceived energy systems on the environment, climate, and health. Global warming is accelerating, and pollution is worsening, especially in developing countries with their hunger for energy to meet the needs of economic development. Asian cities are now beating all pollution records, and greenhouse gases are visibly changing the climate with rising sea levels, retracting glaciers, and record weather disasters. This article presents why and how energy investments and research money have to be rechanneled into sustainable energy, rather than into the business-as-usual of depleting, unsustainable energy concepts exceeding one trillion dollars per year. This largest of all investment sectors needs much more attention.

  9. Climatological simulations of ozone and atmospheric aerosols in the Greater Cairo region

    SciTech Connect (OSTI)

    Steiner, A. L.; Tawfik, A. B.; Shalaby, A.; Zakey, A. S.; Abdel Wahab, M. M.; Salah, Z.; Solmon, F.; Sillman, S.; Zaveri, Rahul A.

    2014-04-16

    An integrated chemistry-climate model (RegCM4-CHEM) simulates present-day climate, ozone and tropospheric aerosols over Egypt with a focus on Greater Cairo (GC) region. The densley populated GC region is known for its severe air quality issues driven by high levels of anthropogenic pollution in conjuction with natural sources such as dust and agricultural burning events. We find that current global emission inventories underestimate key pollutants such as nitrogen oxides and anthropogenic aerosol species. In the GC region, average-ground-based NO2 observations of 40-60 ppb are substantially higher than modeled estimates (5-10 ppb), likely due to model grid resolution, improper boundary layer representation, and poor emissions inventories. Observed ozone concentrations range from 35 ppb (winter) to 80 ppb (summer). The model reproduces the seasonal cycle fairly well, but modeled summer ozone is understimated by approximately 15 ppb and exhibits little interannual variability. For aerosols, springtime dust events dominate the seasonal aerosol cycle. The chemistry-climate model captures the springtime peak aerosol optical depth (AOD) of 0.7-1 but is slightly greater than satellite-derived AOD. Observed AOD decreases in the summer and increases again in the fall due to agricultural burning events in the Nile Delta, yet the model underestimates this fall observed AOD peak, as standard emissions inventories underestimate this burning and the resulting aerosol emissions. Our comparison of modeled gas and particulate phase atmospheric chemistry in the GC region indicates that improved emissions inventories of mobile sources and other anthropogenic activities are needed to improve air quality simulations in this region.

  10. Depleted uranium storage and disposal trade study: Summary report

    SciTech Connect (OSTI)

    Hightower, J.R.; Trabalka, J.R.

    2000-02-01

    The objectives of this study were to: identify the most desirable forms for conversion of depleted uranium hexafluoride (DUF6) for extended storage, identify the most desirable forms for conversion of DUF6 for disposal, evaluate the comparative costs for extended storage or disposal of the various forms, review benefits of the proposed plasma conversion process, estimate simplified life-cycle costs (LCCs) for five scenarios that entail either disposal or beneficial reuse, and determine whether an overall optimal form for conversion of DUF6 can be selected given current uncertainty about the endpoints (specific disposal site/technology or reuse options).

  11. Utilizing weak pump depletion to stabilize squeezed vacuum states

    E-Print Network [OSTI]

    Timo Denker; Dirk Schütte; Maximilian H. Wimmer; Trevor A. Wheatley; Elanor H. Huntington; Michèle Heurs

    2015-03-10

    We propose and demonstrate a pump-phase locking technique that makes use of weak pump depletion (WPD) - an unavoidable effect that is usually neglected - in a sub-threshold optical parametric oscillator (OPO). We show that the phase difference between seed and pump beam is imprinted on both light fields by the non-linear interaction in the crystal and can be read out without disturbing the squeezed output. Our new locking technique allows for the first experimental realization of a pump-phase lock by reading out the pre-existing phase information in the pump field. There is no degradation of the detected squeezed states required to implement this scheme.

  12. Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects

    E-Print Network [OSTI]

    Simulating the growth response of aspen to elevated ozone: a mechanistic approach to scaling a leaf-level model of ozone effects on photosynthesis to a complex canopy architecture§ M.J. Martina, *, G.E. Hosta; accepted 17 July 2001 ``Capsule'': A process model is described that predicts the relative effects of ozone

  13. Depletion GPT-free sensitivity analysis for reactor eigenvalue problems

    SciTech Connect (OSTI)

    Kennedy, C.; Abdel-Khalik, H. [North Carolina State University, Raleigh, NC (United States)

    2013-07-01

    This manuscript introduces a novel approach to solving depletion perturbation theory problems without the need to set up or solve the generalized perturbation theory (GPT) equations. The approach, hereinafter denoted generalized perturbation theory free (GPT-Free), constructs a reduced order model (ROM) using methods based in perturbation theory and computes response sensitivity profiles in a manner that is independent of the number or type of responses, allowing for an efficient computation of sensitivities when many responses are required. Moreover, the reduction error from using the ROM is quantified in the GPT-Free approach by means of a Wilks' order statistics error metric denoted the K-metric. Traditional GPT has been recognized as the most computationally efficient approach for performing sensitivity analyses of models with many input parameters, e.g. when forward sensitivity analyses are computationally intractable. However, most neutronics codes that can solve the fundamental (homogenous) adjoint eigenvalue problem do not have GPT capabilities unless envisioned during code development. The GPT-Free approach addresses this limitation by requiring only the ability to compute the fundamental adjoint. This manuscript demonstrates the GPT-Free approach for depletion reactor calculations performed in SCALE6 using the 7x7 UAM assembly model. A ROM is developed for the assembly over a time horizon of 990 days. The approach both calculates the reduction error over the lifetime of the simulation using the K-metric and benchmarks the obtained sensitivities using sample calculations. (authors)

  14. Including environmental concerns in management strategies for depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Goldberg, M. [Argonne National Laboratory, Washington, DC (United States); Avci, H.I. [Argonne National Lab., IL (United States); Bradley, C.E. [USDOE, Washington, DC (United States)

    1995-12-31

    One of the major programs within the Office of Nuclear Energy, Science, and Technology of the US Department of Energy (DOE) is the depleted uranium hexafluoride (DUF{sub 6}) management program. The program is intended to find a long-term management strategy for the DUF{sub 6} that is currently stored in approximately 46,400 cylinders at Paducah, KY; Portsmouth, OH; and Oak Ridge, TN, USA. The program has four major components: technology assessment, engineering analysis, cost analysis, and the environmental impact statement (EIS). From the beginning of the program, the DOE has incorporated the environmental considerations into the process of strategy selection. Currently, the DOE has no preferred alternative. The results of the environmental impacts assessment from the EIS, as well as the results from the other components of the program, will be factored into the strategy selection process. In addition to the DOE`s current management plan, other alternatives continued storage, reuse, or disposal of depleted uranium, will be considered in the EIS. The EIS is expected to be completed and issued in its final form in the fall of 1997.

  15. Sampling Plan for Assaying Plates Containing Depleted or Normal Uranium

    SciTech Connect (OSTI)

    Ivan R. Thomas

    2011-11-01

    This paper describes the rationale behind the proposed method for selecting a 'representative' sample of uranium metal plates, portions of which will be destructively assayed at the Y-12 Security Complex. The total inventory of plates is segregated into two populations, one for Material Type 10 (depleted uranium (DU)) and one for Material Type 81 (normal [or natural] uranium (NU)). The plates within each population are further stratified by common dimensions. A spreadsheet gives the collective mass of uranium element (and isotope for DU) and the piece count of all plates within each stratum. These data are summarized in Table 1. All plates are 100% uranium metal, and all but approximately 60% of the NU plates have Kel-F{reg_sign} coating. The book inventory gives an overall U-235 isotopic percentage of 0.22% for the DU plates, ranging from 0.19% to 0.22%. The U-235 ratio of the NU plates is assumed to be 0.71%. As shown in Table 1, the vast majority of the plates are comprised of depleted uranium, so most of the plates will be sampled from the DU population.

  16. Review: Global Climate Change

    E-Print Network [OSTI]

    Smith, Jennifer

    2013-01-01

    introduction to global climate change, the greenhouseReview: Global Climate Change: A Primer By Orrin H PilkeyPilkey, Keith C. Global Climate Change: a primer. Durham,

  17. Foliar ozone injury and gas exchange among black cherry genotypes

    SciTech Connect (OSTI)

    Kouterick, K.B.; Skelly, J.M.; Fredericksen, T.S.; Kolb, T.E.; Savage, J.E.; Snyder, K.R. (Penn State Univ., University Park, PA (United States))

    1994-06-01

    The effect of differing ozone exposures on seedlings of black cherry genotypes was investigated in northcentral Pennsylvania. Ozone exclusion treatments were administrated to half-sib families R12 and MO-7, and wild-type (WT) grown in open-top chambers. Over the 1993 growing season, left gas exchange and stem volume were related to percentage of foliar ozone injury observed as adaxial stipple. Ozone symptoms decreased significantly with increasing ozone filtration. R12 exhibited the most severe foliar injury, while WT seedlings showed slightly less symptoms. MO-7 had the least amount of foliar injury. No clear trends in stomatal conductance or net photosynthesis were observed until August. During August, foliar injury was positively related to stomatal conductance. Stomatal conductance values were greatest in R12, followed by WT and MO-7. Photosynthesis followed the same pattern at stomatal conductance. Dark respiration rates were variable across treatments for the entire growing season. Differing ozone exposures did not affect stem volume, but stem volume of seedlings of all families in the open plot were significantly lower than seedlings within chambers. Overall, R12 had higher stem volume than MO-7 and WT seedlings.

  18. Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause-Based Climatology and Optimal Estimation Approach

    E-Print Network [OSTI]

    Pan, Laura

    Ozone Profile Retrieval from an Advanced Infrared Sounder: Experiments with Tropopause for retrieving atmospheric ozone profile information from advanced satellite infrared sounders, this study investigates various methods to optimize ozone retrievals. A set of retrieval experiments has been performed

  19. Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest

    E-Print Network [OSTI]

    2015-01-01

    VOC reactivity and its effect on ozone production during theand HONO chemistry on ozone A. , Molina, L. T. , Nenes, A. ,15/4357/2015/ emissions on ozone concentration during summer

  20. ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE

    SciTech Connect (OSTI)

    Ketusky, E.; Subramanian, K.

    2012-02-29

    At the Savannah River Site (SRS), oxalic acid is currently considered the preferred agent for chemically cleaning the large underground Liquid Radioactive Waste Tanks. It is applied only in the final stages of emptying a tank when generally less than 5,000 kg of waste solids remain, and slurrying based removal methods are no-longer effective. The use of oxalic acid is preferred because of its combined dissolution and chelating properties, as well as the fact that corrosion to the carbon steel tank walls can be controlled. Although oxalic acid is the preferred agent, there are significant potential downstream impacts. Impacts include: (1) Degraded evaporator operation; (2) Resultant oxalate precipitates taking away critically needed operating volume; and (3) Eventual creation of significant volumes of additional feed to salt processing. As an alternative to dealing with the downstream impacts, oxalate decomposition using variations of ozone based Advanced Oxidation Process (AOP) were investigated. In general AOPs use ozone or peroxide and a catalyst to create hydroxyl radicals. Hydroxyl radicals have among the highest oxidation potentials, and are commonly used to decompose organics. Although oxalate is considered among the most difficult organic to decompose, the ability of hydroxyl radicals to decompose oxalate is considered to be well demonstrated. In addition, as AOPs are considered to be 'green' their use enables any net chemical additions to the waste to be minimized. In order to test the ability to decompose the oxalate and determine the decomposition rates, a test rig was designed, where 10 vol% ozone would be educted into a spent oxalic acid decomposition loop, with the loop maintained at 70 C and recirculated at 40L/min. Each of the spent oxalic acid streams would be created from three oxalic acid strikes of an F-area simulant (i.e., Purex = high Fe/Al concentration) and H-area simulant (i.e., H area modified Purex = high Al/Fe concentration) after nearing dissolution equilibrium, and then decomposed to {le} 100 Parts per Million (ppm) oxalate. Since AOP technology largely originated on using ultraviolet (UV) light as a primary catalyst, decomposition of the spent oxalic acid, well exposed to a medium pressure mercury vapor light was considered the benchmark. However, with multi-valent metals already contained in the feed, and maintenance of the UV light a concern; testing was conducted to evaluate the impact from removing the UV light. Using current AOP terminology, the test without the UV light would likely be considered an ozone based, dark, ferrioxalate type, decomposition process. Specifically, as part of the testing, the impacts from the following were investigated: (1) Importance of the UV light on the decomposition rates when decomposing 1 wt% spent oxalic acid; (2) Impact of increasing the oxalic acid strength from 1 to 2.5 wt% on the decomposition rates; and (3) For F-area testing, the advantage of increasing the spent oxalic acid flowrate from 40 L/min (liters/minute) to 50 L/min during decomposition of the 2.5 wt% spent oxalic acid. The results showed that removal of the UV light (from 1 wt% testing) slowed the decomposition rates in both the F & H testing. Specifically, for F-Area Strike 1, the time increased from about 6 hours to 8 hours. In H-Area, the impact was not as significant, with the time required for Strike 1 to be decomposed to less than 100 ppm increasing slightly, from 5.4 to 6.4 hours. For the spent 2.5 wt% oxalic acid decomposition tests (all) without the UV light, the F-area decompositions required approx. 10 to 13 hours, while the corresponding required H-Area decompositions times ranged from 10 to 21 hours. For the 2.5 wt% F-Area sludge, the increased availability of iron likely caused the increased decomposition rates compared to the 1 wt% oxalic acid based tests. In addition, for the F-testing, increasing the recirculation flow rates from 40 liter/minute to 50 liter/minute resulted in an increased decomposition rate, suggesting a better use of ozone.

  1. Cumulative theoretical uncertainties in lithium depletion boundary age

    E-Print Network [OSTI]

    Tognelli, Emanuele; Degl'Innocenti, Scilla

    2015-01-01

    We performed a detailed analysis of the main theoretical uncertainties affecting the age at the lithium depletion boundary (LDB). To do that we computed almost 12000 pre-main sequence models with mass in the range [0.06, 0.4] M_sun by varying input physics (nuclear reaction cross-sections, plasma electron screening, outer boundary conditions, equation of state, and radiative opacity), initial chemical elements abundances (total metallicity, helium and deuterium abundances, and heavy elements mixture), and convection efficiency (mixing length parameter, alpha_ML). As a first step, we studied the effect of varying these quantities individually within their extreme values. Then, we analysed the impact of simultaneously perturbing the main input/parameters without an a priori assumption of independence. Such an approach allowed us to build for the first time the cumulative error stripe, which defines the edges of the maximum uncertainty region in the theoretical LDB age. We found that the cumulative error stripe ...

  2. Morphological basis of tolerance to ozone

    SciTech Connect (OSTI)

    Evans, M.J.; Dekker, N.P.; Cabral-Anderson, L.J.; Shami, S.G.

    1985-06-01

    The purpose of this research was to study Type 1 epithelial cells in the ozone (O/sub 3/)-tolerant lung epithelium. Rats were made tolerant by exposure to 0.5 ppm O/sub 3/ for 2 days and allowed to recover in air. Reexposure to a lethal concentration of O/sub 3/ (6 ppm) at 3, 7, and 15 days of recovery revealed that tolerance was present at 3 days but almost absent at 7 and 15 days of recovery. Using Type 2 cell proliferation as a means of quantitating Type 1 cell injury, it was observed that when the preexposed rats were reexposed to 0.5 ppm at 3, 7, and 15 days, very little Type 1 cell injury occurred at 3 days. However, at 7 and 15 days the amount of Type 1 cell injury was the same as that associated with the original exposure. To determine whether there was any change in the alveolar epithelial cell populations between the periods of tolerance (3 days) and its decline (7 and 15 days), the percentage of tritiated thymidine (( /sup 3/H)TdR-labeled Type 1 and 2 cells at these times were determined. There was a significant decrease in (/sup 3/H)TdR-labeled Type 1 and 2 cells between the third and fifteenth days of recovery as excess cells were sloughed off and the tissue returned to normal. Using electron microscopic morphometry, Type 1 and 2 cells were then studied during the decline of tolerance. No change was found in the morphology of Type 2 cells; however, the morphology of Type 1 cells revealed a 58% decrease in surface area and a 25% increase in the arithmetic mean thickness when tolerance was present at 3 days. As tolerance declined (7 and 15 days), Type 1 cell morphology returned to normal. It was concluded that tolerance exists when the surface area of a cell exposed to a particular concentration of ozone is small enough so that the existing antioxidant mechanism contained within that cell volume can protect it from damage.

  3. EIS-0329: Proposed Construction, Operation, Decontamination/Decommissioning of Depleted Uranium Hexafluoride Conversion Facilities

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposal to construct, operate, maintain, and decontaminate and decommission two depleted uranium hexafluoride (DUF 6) conversion facilities, at Portsmouth, Ohio, and Paducah, Kentucky.

  4. A A~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 0~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    -ton C hier,this effHiiency difference can provide centrifug a lchiller in a ' inqgsof over -$24000per of ozone depletion, global warming this: If every centrifugal chiller in the world and energy efficiency

  5. The Cost of Crop Damage Caused by Ozone Air Pollution From Motor Vehicles

    E-Print Network [OSTI]

    Murphy, James; Delucchi, Mark; McCubbin, Donald; Kim, H.J.

    1999-01-01

    Effects of Motor-Vehicle Air Pollution. UCD-ITS-RR-96-3 (by Ozone Air Pollution from Motor-Vehicles. UCD- ITS-RR-96-by ozone air pollution from motor vehicles J. J. Murphy†?,

  6. Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films...

    Office of Scientific and Technical Information (OSTI)

    Ozone-Based Atomic Layer Deposition of Crystalline V2O5Films for High Performance Electrochemical Energy Storage Citation Details In-Document Search Title: Ozone-Based Atomic Layer...

  7. Modeling Ozone Removal to Indoor Materials, Including the Effects of Porosity, Pore Diameter, and Thickness

    E-Print Network [OSTI]

    Gall, Elliott T; Siegel, Jeffrey A; Corsi, Richard L

    2015-01-01

    C. Ozone deposition velocities, reaction probabilities andreaction phenomena described by a single parameter, the ozone deposition velocity,velocity, v t (m h ?1 ), a characteristic of the ?uid mechanics of a space, and the reaction

  8. Weekend/Weekday Ozone Study in the South Coast Air Basin | Department...

    Energy Savers [EERE]

    Ozone Effect - The Weekly Ambient Emissions Control Experiment Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

  9. Effect of ozonation on the composition of crude coal-tar benzene

    SciTech Connect (OSTI)

    Semenova, S.A.; Patrakov, Y.F.

    2007-05-15

    The effect of ozonation on the composition of crude benzene produced by the coal-tar chemical industry was studied.

  10. Effects of ozone cooling in the tropical lower stratosphere and upper troposphere

    E-Print Network [OSTI]

    Effects of ozone cooling in the tropical lower stratosphere and upper troposphere Piers M. Forster lower stratosphere and upper troposphere and elucidate the key role of ozone changes in driving of tropical ozone decreases at 70 hPa and lower pressures can lead to significant cooling not only

  11. THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING BAYESIAN MODELS

    E-Print Network [OSTI]

    West, Mike

    THE FILTERING OF OZONE CONCENTRATION MEASUREMENTS COLLECTED IN A TURBULENT AIR STREAM USING University. The authors thank Alex Guenther for supplying the high frequency ozone concentration measurements a multiscale Bayesian model for separating ozone (O 3 ) concentration turbulent fluctuations from such inherent

  12. EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH

    E-Print Network [OSTI]

    McKendry, Ian

    EVIDENCE OF ELEVATED OZONE CONCENTRATIONS ON FORESTED SLOPES OF THE LOWER FRASER VALLEY, BRITISH, hourly average ozone concentrations were mea- sured at three sites of differing elevation (188, 588. Sites experienced ozone concentrations ranging from 0 to 88 ppb in 2001, and 0 to 96 ppb in 2002. Daily

  13. Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend

    E-Print Network [OSTI]

    Effect of stratosphere-troposphere exchange on the future tropospheric ozone trend W. J. Collins, R of circulation changes in a changed climate on the exchange of ozone between the stratosphere and the troposphere. We have identified an increase in the net transport of ozone into the troposphere in the future

  14. The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation

    E-Print Network [OSTI]

    Waugh, Darryn W.

    The ozone response to ENSO in Aura satellite measurements and a chemistry-climate simulation Luke D impact on tropospheric circulation causes significant changes to the distribution of ozone. Here we derive the lower tropospheric to lower stratospheric ozone response to ENSO from observations

  15. How Bromate and Ozone Concentrations can be Modelled at Full Scale

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 How Bromate and Ozone Concentrations can be Modelled at Full Scale based on Lab-Scale Experiments ­ A Case Study Running head title How to model bromate & ozone at full scale based on lab tests Pierre-scale modelling study of an industrial ozonation unit for practical application. The modelling framework combines

  16. Technical note Barriers and opportunities for passive removal of indoor ozone

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Technical note Barriers and opportunities for passive removal of indoor ozone Elliott T. Gall presents a Monte Carlo simulation to assess passive removal materials (PRMs) that remove ozone of homes in Houston, Texas, were taken from the literature and combined with back- ground ozone removal

  17. Ground-level ozone in the 21st century: future trends,

    E-Print Network [OSTI]

    Ground-level ozone in the 21st century: future trends, impacts and policy implications October 2008. Courtesy of Dr Mhairi Coyle, CEH Edinburgh. #12;Ground-level ozone in the 21st century: future trends Limited #12;Ground-level ozone in the 21st century I October 2008 I iiiThe Royal Society Ground

  18. Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone

    E-Print Network [OSTI]

    Barthelat, Francois

    Pilot Scale Study of Excess Sludge Production Reduction in Wastewater Treatment by Ozone Yuan Ma-scale reactors were operated at the LaPrairie Wastewater Treatment plant (one control and one ozonated) to investigate the sludge reduction potential of partially ozonating sludge return activated sludge (RAS

  19. 1 Ozone pollution forecasting 3 Herve Cardot, Christophe Crambes and Pascal Sarda.

    E-Print Network [OSTI]

    Crambes, Christophe

    Contents 1 Ozone pollution forecasting 3 Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1;1 Ozone pollution forecasting using conditional mean and conditional quantiles with functional covariates Herv´e Cardot, Christophe Crambes and Pascal Sarda. 1.1 Introduction Prediction of Ozone pollution

  20. Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a)

    E-Print Network [OSTI]

    Reid, Scott A.

    Formation of ozone: Metastable states and anomalous isotope effect Dmitri Babikov,a) Brian K for an anomalous isotope effect in ozone formation is given in terms of the energy transfer mechanism, where the metastable states of ozone are formed first, and then stabilized by collisions with other atoms. Unusual

  1. A review of statistical methods for the meteorological adjustment of tropospheric ozone

    E-Print Network [OSTI]

    Washington at Seattle, University of

    A review of statistical methods for the meteorological adjustment of tropospheric ozone Mary Lou adjustment of tropospheric ozone Mary Lou Thompson1 Joel Reynolds1 Lawrence H. Cox2 Peter Guttorp1 Paul D.larry@epamail.epa.gov ABSTRACT: A variety of statistical methods for meteorological adjustment of ozone have been proposed

  2. Ozone deposition to an orange orchard: Partitioning between stomatal and non-stomatal sinks

    E-Print Network [OSTI]

    Goldstein, Allen

    Ozone deposition to an orange orchard: Partitioning between stomatal and non-stomatal sinks Silvano January 2012 Keywords: Orange plants Ozone flux Stomatal deposition Non-stomatal deposition BVOC a b s t r a c t Orange trees are widely cultivated in regions with high concentrations of tropospheric ozone

  3. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. , NO. , PAGES 1?? , Analysis of 19701995 Trends in Tropospheric Ozone at

    E-Print Network [OSTI]

    Jacob, Daniel J.

    in Tropospheric Ozone at Northern Hemisphere Midlatitudes with the GEOS­CHEM Model Andrew C. Fusco Department. The causes of trends in tropospheric ozone at Northern Hemisphere mid­ latitudes from 1970 to 1995 to investigate the sensitivity of tropospheric ozone with respect to (1) changes in the anthropogenic emission

  4. Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery Article Published.G. and Ravishankara, A.R. (2009) Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery's research outputs online #12;Impact of sudden Arctic sea-ice loss on stratospheric polar ozone recovery J. F

  5. A Comparison of Bayesian and Conditional Density Models in Probabilistic Ozone Forecasting

    E-Print Network [OSTI]

    Hsieh, William

    A Comparison of Bayesian and Conditional Density Models in Probabilistic Ozone Forecasting Song Cai to provide predictive distributions of daily maximum surface level ozone concentrations. Five forecast models forecasts for extreme events, namely poor air quality events defined as having ozone concentration 82 ppb

  6. Projections of UV radiation changes in the 21st century: impact of ozone recovery

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Projections of UV radiation changes in the 21st century: impact of ozone recovery and cloud effects radiation changes in the 21st century: impact of ozone recovery and cloud effects. Atmospheric Chemistry Chemistry and Physics Projections of UV radiation changes in the 21st century: impact of ozone recovery

  7. Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux measurements

    E-Print Network [OSTI]

    Goldstein, Allen

    Tropospheric ozone reduces carbon assimilation in trees: estimates from analysis of continuous flux Abstract High ground-level ozone concentrations are typical of Mediterranean climates. Plant exposure to this oxidant is known to reduce carbon assimilation. Ozone damage has been traditionally measured through

  8. ATOC/CHEM 5151 Problem 10 Energetics of the Photolysis of Ozone

    E-Print Network [OSTI]

    Toohey, Darin W.

    ATOC/CHEM 5151 ­ Problem 10 Energetics of the Photolysis of Ozone Answers will be posted Thursday, October 9, 2014 Photolysis of ozone is important in the formation of the OH radical throughout much standard enthalpy tables to determine the bond strength of ozone (i.e., heat of reaction O + O2 O3) 105 k

  9. Quantifying stratospheric ozone response to changes in methane and nitrous oxide

    E-Print Network [OSTI]

    Bourqui, Michel

    Quantifying stratospheric ozone response to changes in methane and nitrous oxide concentrations of Ozone destruction and creation at different altitudes and concentrations of CH4 and N2O #12;Contents levels have varying conditions and are governed by different chemical regimes We will simulate ozone

  10. Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002

    E-Print Network [OSTI]

    Thompson, Anne

    Tropospheric ozone climatology over Irene, South Africa, from 1990 to 1994 and 1998 to 2002 R. D the characteristic Southern Hemisphere springtime tropospheric ozone maximum, but its seasonal features are modulated anticyclonic gyre over southern Africa permit the buildup of relatively high springtime midtropospheric ozone

  11. Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun

    E-Print Network [OSTI]

    Folkins, Ian

    Tropical ozone as an indicator of deep convection Ian Folkins and Christopher Braun Department] The climatological ozone profile in the tropics is shaped like an ``S,'' with a minimum at the surface, a maximum. These features can be reproduced by a very simple model whose only free parameter is the mean ozone mixing ratio

  12. PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone on

    E-Print Network [OSTI]

    PublishedbyManeyPublishing(c)IOMCommunicationsLtd Influence of UV irradiation and ozone. Kelly*1 The corrosion of Ag in an atmosphere of ozone and humidity with or without irradiation corrosion product to chloride in the reduction solution. The presence of both ozone and UV radiation

  13. Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone treatment

    E-Print Network [OSTI]

    Parikh, Atul N.

    Photochemical template removal and spatial patterning of zeolite MFI thin films using UV/ozone (structure code: MFI) following a previously published procedure. The films were illuminated using an ozone. Results presented here indicate that the UV/ozone treatment under nominally room temperature conditions

  14. Evaluating Ozone Air Pollution Effects on Pines in the Western United States

    E-Print Network [OSTI]

    Evaluating Ozone Air Pollution Effects on Pines in the Western United States United States. Evaluating ozone air pollution effects on pines in the western United States. Gen. Tech. Rep. PSW­GTR­155. Historical and technical background is provided about ozone air pollution effects on ponderosa (Pinus

  15. Ensemble-based air quality forecasts: A multimodel approach applied to ozone

    E-Print Network [OSTI]

    Mallet, Vivien

    Ensemble-based air quality forecasts: A multimodel approach applied to ozone Vivien Mallet1 21 September 2006. [1] The potential of ensemble techniques to improve ozone forecasts ozone-monitoring networks. We found that several linear combinations of models have the potential

  16. The potential to narrow uncertainty in projections of stratospheric ozone over the

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    The potential to narrow uncertainty in projections of stratospheric ozone over the 21st century of stratospheric ozone over the 21st century. Atmospheric Chemistry and Physics, 10 (19). pp. 9473-9486. ISSN 1680 of stratospheric ozone over the 21st century A. J. Charlton-Perez1, E. Hawkins1, V. Eyring2, I. Cionni2, G. E

  17. Ozone database in support of CMIP5 simulations: results and corresponding

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing Article., Bodeker, G.E., Shepherd, T.G., Shindell, D.T. and Waugh, D.W. (2011) Ozone database in support of CMIP5 and Physics Ozone database in support of CMIP5 simulations: results and corresponding radiative forcing I

  18. Smoothing Parameter Selection When Errors are Correlated and Application to Ozone Data

    E-Print Network [OSTI]

    Heckman, Nancy E.

    Smoothing Parameter Selection When Errors are Correlated and Application to Ozone Data by Robert Jr trend of daily and monthly ground ozone levels in southern Ontario. iii #12; Contents Abstract ii.2 Air Pollution Data . . . . . . . . . . . . . . . . . . . . . . . . 79 5.2.1 Daily Ozone Data . . . . . . . . . . . . . . . . . . .

  19. Nighttime secondary ozone layer during major stratospheric sudden warmings in specified-dynamics WACCM

    E-Print Network [OSTI]

    Limpasuvan, Varavut

    Nighttime secondary ozone layer during major stratospheric sudden warmings in specified to the thermosphere. Currently, the role of atmospheric dynamics on polar ozone in the mesosphere-lower thermosphere "secondary" (90­105 km) ozone maximum by examining the dynamics and distribution of key species (like H and O

  20. Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations

    E-Print Network [OSTI]

    Liu, Hongyu

    Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations ozone over the Asian Pacific Rim in different seasons are quantified by analysis of Hong Kong at midlatitudes from fall at low latitudes due to monsoonal influence. The UT ozone minimum and high variability

  1. Analytica Chimica Acta 573574 (2006) 913 Metal oxide thin films as sensing layers for ozone detection

    E-Print Network [OSTI]

    2006-01-01

    Analytica Chimica Acta 573­574 (2006) 9­13 Metal oxide thin films as sensing layers for ozone. Their structural, electrical and ozone sensing properties were analyzed. Structural investigations carried out with ultraviolet light and subsequent oxidation in ozone atmosphere at room temperature. © 2006 Elsevier B.V. All

  2. Low ozone concentrations over Macquarie Island during 1997. Part I: trajectory analysis

    E-Print Network [OSTI]

    Cordero, Eugene

    Low ozone concentrations over Macquarie Island during 1997. Part I: trajectory analysis by Eugene C instruments show record low ozone column densities between 20°S and 60°S throughout 1997. The monthly averaged record from the Total Ozone Mapping Spectrometer (TOMS) indicates that measurements from 1997 are lower

  3. Ozone ensemble forecast with machine learning Vivien Mallet,1,2

    E-Print Network [OSTI]

    Mallet, Vivien

    Ozone ensemble forecast with machine learning algorithms Vivien Mallet,1,2 Gilles Stoltz,3; published 13 March 2009. [1] We apply machine learning algorithms to perform sequential aggregation of ozone forecasts. The latter rely on a multimodel ensemble built for ozone forecasting with the modeling system

  4. Efficient quantum-classical method for computing thermal rate constant of recombination: Application to ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    : Application to ozone formation Mikhail V. Ivanov and Dmitri Babikov Citation: J. Chem. Phys. 136, 184304 (2012 for computing thermal rate constant of recombination: Application to ozone formation Mikhail V. Ivanov of ozone. Comparison of the predicted rate vs. experimental result is presented. © 2012 American Institute

  5. Conditional quantiles when the covariates are curves : an application to Ozone pollution

    E-Print Network [OSTI]

    Bercu, Bernard

    Conditional quantiles when the covariates are curves : an application to Ozone pollution forecasting Summary This work deals with the study of pollution data with the aim of forecas- ting the Ozone of the maximum of Ozone one day kno- wing one or several of these functional variables the day before. To do this

  6. Semiclassical wave packet study of anomalous isotope effect in ozone formation

    E-Print Network [OSTI]

    Reid, Scott A.

    Semiclassical wave packet study of anomalous isotope effect in ozone formation Evgeny Vetoshkin represent the metastable O3 * species and play a central role in the process of ozone formation.1063/1.2778432 I. INTRODUCTION Ozone O3 is formed in the stratosphere as a product of the following recombination

  7. Seedling insensitivity to ozone for three conifer species native to Great Smoky Mountains National Park$

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seedling insensitivity to ozone for three conifer species native to Great Smoky Mountains National concentrations of ozone had little eect on seedlings of three species of conifers commonly found in Great Smoky Mountains National Park. Abstract Field symptoms typical of ozone injury have been observed on several

  8. Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air Purifiers

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    Quantification of Ozone Levels in Indoor Environments Generated by Ionization and Ozonolysis Air ozone (O3) during operation, either in- tentionally or as a byproduct of air ionization standards. Sev- eral types of air purifiers were tested for their ability to produce ozone in various indoor

  9. The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest

    E-Print Network [OSTI]

    Collins, Gary S.

    The Effect of Ozone Stomatal Conductance on Isoprene Emissions above a Northern Hardwood Forest also acts as an antioxidant within a plant, reacting and neutralizing ozone and peroxides, though , and reacts photochemically in the presence of NOx to produce tropospheric ozone. The Model of Emissions

  10. Seasonal persistence of northern low-and middle-latitude anomalies of ozone and

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases) Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other trace gases outputs online #12;Seasonal persistence of northern low- and middle-latitude anomalies of ozone and other

  11. Impact of long-range correlations on trend detection in total ozone

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Impact of long-range correlations on trend detection in total ozone Article Published Version detection in total ozone. Journal of Geophysical Research, 112. D14307. ISSN 0148-0227 doi: 10.1029/2006JD of long-range correlations on trend detection in total ozone Dmitry I. Vyushin,1 Vitali E. Fioletov,2

  12. Semiclassical molecular dynamics simulations of ultrafast photodissociation dynamics associated with the Chappuis band of ozone

    E-Print Network [OSTI]

    Miller, William H.

    with the Chappuis band of ozone Victor S. Batista and William H. Millera) Department of Chemistry, University A ) of ozone following photoexcitation of the molecule in the gas phase with visible light. Our algorithm and recurrence events, as well as an interpretation of experimental studies of the Chappuis band of ozone

  13. A ground state depleted laser in neodymium doped yttrium orthosilicate

    SciTech Connect (OSTI)

    Beach, R.; Albrecht, G.; Solarz, R.; Krupke, W.; Comaskey, B.; Mitchell, S.; Brandle, C.; Berkstresser, G.

    1990-01-16

    A ground state depleted (GSD){sup 1,2} laser has been demonstrated in the form of a Q-switched oscillator operating at 912 nm. Using Nd{sup 3+} as the active ion and Y{sub 2}SiO{sub 5} as the host material, the laser transition is from the lowest lying stark level of the Nd{sup 3t}F{sub 3/2} level to a stark level 355 cm{sup {minus}1} above the lowest lying one in the {sup 4}I{sub 9/2} manifold. The necessity of depleting the ground {sup 4}I{sub 9/2} manifold is evident for this level scheme as transparency requires a 10% inversion. To achieve the high excitation levels required for the efficient operation of this laser, bleach wave pumping using an alexandrite laser at 745 nm has been employed. The existence of a large absorption feature at 810 nm also allows for the possibility of AlGaAs laser diode pumping. Using KNbO{sub 3}, noncritical phase matching is possible at 140{degree}C using d{sub 32} and has been demonstrated. The results of Q-switched laser performance and harmonic generation in KNbO{sub 3} will be presented. Orthosilicate can be grown in large boules of excellent optical quality using a Czochralski technique. Because of the relatively small 912 nm emission cross section of 2-3 {times} 10{sup {minus}20} cm{sup 2} (orientation dependent) fluences of 10-20 J/cm{sup 2} must be circulated in the laser cavity for the efficient extraction of stored energy. This necessitates very aggressive laser damage thresholds. Results from the Reptile laser damage facility at Lawrence Livermore National Laboratory (LLNL) will be presented showing Y{sub 2}SiO{sub 5} bulk and AR sol-gel coated surface damage thresholds of greater than 40 J/cm{sup 2} for 10 nsec, 10 Hz, 1.06 {mu} pulses. 16 refs., 18 figs., 6 tabs.

  14. LOT-G3: Plasma Lamp, Ozonator and CW transmitter

    E-Print Network [OSTI]

    Gobato, Ricardo; Gobato, Alekssander

    2015-01-01

    The LOT-G3 is designed to be a versatile equipment that perform several simple experiments for use in helping the physics classes for high school. Easy construction, low cost, using easily accessible materials. Its construction involves simple practices and knowledge of electromagnetism. It has the function of a plasma globe to demonstrate the ionization of a low pressure gas, as well as the formation of magnetic field. Can be used as sanitizer closed environments such as automotive vehicles in ozonator function, demonstrating the ionization of oxygen in the atmosphere, producing ozone, essential to life on earth. And as a sparks transmitter, low power, low frequency modulated continuous wave in (CW), for signals in Morse code. Therefore the equipment here called LOT-G3, has three functions: a plasma lamp, ozonator and CW transmitter.

  15. Sustainable Use and Depletion of Natural Resources: The Quest for Energy

    E-Print Network [OSTI]

    Hill, Jeffrey E.

    Sustainable Use and Depletion of Natural Resources: The Quest for Energy Stephen R. Humphrey of sustainable resource use A model of resource depletion The resource substitution puzzle Peak and decline of oil Quest for energy substitution What about other natural resources? #12;How Do We Add 2 billion

  16. Depletion-induced surface alignment of asymmetric diblock copolymer in selective solvents

    E-Print Network [OSTI]

    Depletion-induced surface alignment of asymmetric diblock copolymer in selective solvents Rong Wang online 31 July 2008 Phase separation of asymmetric diblock copolymer near surfaces in selective solvents. The walls strongly affect the phase separation of block copolymer in selective solvent, and the depletion

  17. Reservoir depletion at The Geysers geothermal area, California, shown by four-dimensional seismic tomography

    E-Print Network [OSTI]

    Foulger, G. R.

    Reservoir depletion at The Geysers geothermal area, California, shown by four-dimensional seismic geothermal exploitation at The Geysers geothermal area, California, induces myriads of small of Vp, Vs, and Vp/Vs is an effective geothermal reservoir depletion monitoring tool and can potentially

  18. Groundwater depletion and sustainability of irrigation in the US High Plains and Central Valley

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Groundwater depletion and sustainability of irrigation in the US High Plains and Central Valley impact crop produc- tion in the United States because 60% of irrigation relies on groundwater. Groundwater depletion in the irrigated High Plains and California Central Valley accounts for 50

  19. Investigation of breached depleted UF{sub 6} cylinders

    SciTech Connect (OSTI)

    DeVan, J.H. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

    1991-12-31

    In June 1990, during a three-site inspection of cylinders being used for long-term storage of solid depleted UF{sub 6}, two 14-ton cylinders at Portsmouth, Ohio, were discovered with holes in the barrel section of the cylinders. An investigation team was immediately formed to determine the cause of the failures and their impact on future storage procedures and to recommend corrective actions. Subsequent investigation showed that the failures most probably resulted from mechanical damage that occurred at the time that the cylinders had been placed in the storage yard. In both cylinders evidence pointed to the impact of a lifting lug of an adjacent cylinder near the front stiffening ring, where deflection of the cylinder could occur only by tearing the cylinder. The impacts appear to have punctured the cylinders and thereby set up corrosion processes that greatly extended the openings in the wall and obliterated the original crack. Fortunately, the reaction products formed by this process were relatively protective and prevented any large-scale loss of uranium. The main factors that precipitated the failures were inadequate spacing between cylinders and deviations in the orientations of lifting lugs from their intended horizontal position. After reviewing the causes and effects of the failures, the team`s principal recommendation for remedial action concerned improved cylinder handling and inspection procedures. Design modifications and supplementary mechanical tests were also recommended to improve the cylinder containment integrity during the stacking operation.

  20. Kr Ion Irradiation Study of the Depleted-Uranium Alloys

    SciTech Connect (OSTI)

    J. Gan; D. Keiser; B. Miller; M. Kirk; J. Rest; T. Allen; D. Wachs

    2010-12-01

    Fuel development for the Reduced Enrichment Research and Test Reactor program is tasked with the development of new low-enriched uranium nuclear fuels that can be employed to replace existing highly enriched uranium fuels currently used in some research reactors throughout the world. For dispersion-type fuels, radiation stability of the fuel/cladding interaction product has a strong impact on fuel performance. Three depleted uranium alloys are cast for the radiation stability studies of the fuel/cladding interaction product using Kr ion irradiation to investigate radiation damage from fission products. SEM analysis indicates the presence of the phases of interest: U(Si, Al)3, (U, Mo)(Si, Al)3, UMo2Al20, U6Mo4Al43, and UAl4. Irradiations of TEM disc samples were conducted with 500 keV Kr ions at 200ºC to ion doses up to 2.5 × 1015 ions/cm2 (~ 10 dpa) with an Kr ion flux of 1012 ions/cm2-sec (~ 4.0 × 10-3 dpa/sec). Microstructural evolution of the phases relevant to fuel-cladding interaction products was investigated using transmission electron microscopy.

  1. Global hydrological cycle response to rapid and slow global warming

    E-Print Network [OSTI]

    Kuang, Zhiming

    Global hydrological cycle response to rapid and slow global warming and Jiaxu Zhang #12;· Anthropogenic global warming causes "robust" changes in the global in the global hydrological cycle due to anthropogenic global warming Atmospheric radiative

  2. Ozone induces glucose intolerance and systemic metabolic effects in young and aged brown Norway rats

    SciTech Connect (OSTI)

    Bass, V.; Gordon, C.J.; Jarema, K.A.; MacPhail, R.C.; Cascio, W.E.; Phillips, P.M.; Ledbetter, A.D.; Schladweiler, M.C.; Andrews, D.; Miller, D.; Doerfler, D.L.; Kodavanti, U.P.

    2013-12-15

    Air pollutants have been associated with increased diabetes in humans. We hypothesized that ozone would impair glucose homeostasis by altering insulin signaling and/or endoplasmic reticular (ER) stress in young and aged rats. One, 4, 12, and 24 month old Brown Norway (BN) rats were exposed to air or ozone, 0.25 or 1.0 ppm, 6 h/day for 2 days (acute) or 2 d/week for 13 weeks (subchronic). Additionally, 4 month old rats were exposed to air or 1.0 ppm ozone, 6 h/day for 1 or 2 days (time-course). Glucose tolerance tests (GTT) were performed immediately after exposure. Serum and tissue biomarkers were analyzed 18 h after final ozone for acute and subchronic studies, and immediately after each day of exposure in the time-course study. Age-related glucose intolerance and increases in metabolic biomarkers were apparent at baseline. Acute ozone caused hyperglycemia and glucose intolerance in rats of all ages. Ozone-induced glucose intolerance was reduced in rats exposed for 13 weeks. Acute, but not subchronic ozone increased ?{sub 2}-macroglobulin, adiponectin and osteopontin. Time-course analysis indicated glucose intolerance at days 1 and 2 (2 > 1), and a recovery 18 h post ozone. Leptin increased day 1 and epinephrine at all times after ozone. Ozone tended to decrease phosphorylated insulin receptor substrate-1 in liver and adipose tissues. ER stress appeared to be the consequence of ozone induced acute metabolic impairment since transcriptional markers of ER stress increased only after 2 days of ozone. In conclusion, acute ozone exposure induces marked systemic metabolic impairments in BN rats of all ages, likely through sympathetic stimulation. - Highlights: • Air pollutants have been associated with increased diabetes in humans. • Acute ozone exposure produces profound metabolic alterations in rats. • Age influences metabolic risk factors in aging BN rats. • Acute metabolic effects are reversible and repeated exposure reduces these effects. • Ozone metabolic effects are only slightly exacerbated in geriatric rats.

  3. Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a,*, Daniel J. Jacob a,b

    E-Print Network [OSTI]

    Chance, Kelly

    Ozone air quality measurement requirements for a geostationary satellite mission Peter Zoogman a Accepted 23 May 2011 Keywords: Air quality Ozone Kalman filter Assimilation Remote sensing a b s t r a c satellite measurements of ozone in different spectral regions to constrain surface ozone concentrations

  4. Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great Smoky Mountains National Park

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Seasonal development of ozone-induced foliar injury on tall milkweed (Asclepias exaltata) in Great by symptoms of foliar ozone injury. Abstract The goals of this study were to document the development of ozone-induced foliar injury, on a leaf-by-leaf basis, and to develop ozone exposure relationships for leaf cohorts

  5. Synthesis of Ozone at Atmospheric Pressure by a Quenched Induction-Coupled Plasma Torch

    SciTech Connect (OSTI)

    A. Blutke; B.C. Stratton; D.R. Mikkelsen; J. Vavruska; R. Knight

    1998-01-01

    The technical feasibility of using an induction-coupled plasma (ICP) torch to synthesize ozone at atmospheric pressure is explored. Ozone concentrations up to ~250 ppm were produced using a thermal plasma reactor system based on an ICP torch operating at 2.5 MHz and ~11 kVA with an argon/oxygen mixture as the plasma-forming gas. A gaseous oxygen quench formed ozone by rapid mixing of molecular oxygen with atomic oxygen produced by the torch. The ozone concentration in the reaction chamber was measured by Fourier Transform infrared (FTIR) spectroscopy over a wide range of experimental configurations. The geometry of the quench gas flow, the quench flow velocity, and the quench flow rate played important roles in determining the ozone concentration. The ozone concentration was sensitive to the torch RF power, but was insensitive to the torch gas flow rates. These observations are interpreted within the framework of a simple model of ozone synthesis.

  6. Development of DU-AGG (Depleted Uranium Aggregate)

    SciTech Connect (OSTI)

    Lessing, P.A.

    1995-09-01

    Depleted uranium oxide (UO{sub 2} or U0{sub 3}) powder was mixed with fine mineral additives, pressed, and heated to about 1,250{degree}C. The additives were chemically constituted to result in an iron-enriched basalt (IEB). Melting and wetting of the IEB phase caused the urania powder compact to densify (sinter) via a liquid phase sintering mechanism. An inorganic lubricant was found to aid in green-forming of the body. Sintering was successful in oxidizing (air), inert (argon), or reducing (dry hydrogen containing) atmospheres. The use of ground U0{sub 3} powders (93 vol %) followed by sintering in a dry hydrogen-containing atmosphere significantly increased the density of samples (bulk density of 8.40 g/cm{sup 3} and apparent density of 9.48 g/cm{sup 3}, open porosity of 11.43%). An improvement in the microstructure (reduction in open porosity) was achieved when the vol % of U0{sub 3} was decreased to 80%. The bulk density increased to 8.59 g/cm{sup 3}, the apparent density decreased slightly to 8.82 g/cm{sup 3} (due to increase of low density IEB content), while the open porosity decreased to an excellent number of 2.78%. A representative sample derived from 80 vol % U0{sub 3} showed that most pores were closed pores and that, overall, the sample achieved the excellent relative density value of 94.1% of the estimated theoretical density (composite of U0{sub 2} and IEB). It is expected that ground powders of U0{sub 3} could be successfully used to mass produce lowcost aggregate using the green-forming technique of briquetting.

  7. Design and Usage of an Ozone Mapping App Ilyas Uyanik

    E-Print Network [OSTI]

    design, pollution visualiza- tion, air quality monitoring, ozone, user studies Permission to make digital-time, quantitative, and localized pollutant information has become available for a few big cities. Several mobile to conventional weather report- ing systems that provide a qualitative and static description of pollutant levels

  8. Tropospheric ozone over the North Pacific from ozonesonde observations

    E-Print Network [OSTI]

    Liu, Hongyu

    of urban air pollution. At sites in the mid and eastern Pacific the signature of transport of polluted air, Tsukuba, and Sapporo, Japan), a site in the central Pacific (Hilo, Hawaii), and a site on the west coast very high mixing ratios of ozone were observed that result from pollution transport from China

  9. Validation of satellite ozone profile retrievals using Beijing ozonesonde data

    E-Print Network [OSTI]

    Pan, Laura

    , the Atmospheric Infrared Sounder (AIRS) on the NASA Aqua satellite and the Microwave Limb Sounder (MLS in the stratosphere and troposphere. Stratospheric ozone forms a protective layer that absorbs enough solar) on the NASA Aqua satellite [Aumann et al., 2003] and the Microwave Limb Sounder (MLS) on the NASA Aura

  10. Dupoly process for treatment of depleted uranium and production of beneficial end products

    DOE Patents [OSTI]

    Kalb, Paul D. (Wading River, NY); Adams, Jay W. (Stony Brook, NY); Lageraaen, Paul R. (Seaford, NY); Cooley, Carl R. (Gaithersburg, MD)

    2000-02-29

    The present invention provides a process of encapsulating depleted uranium by forming a homogenous mixture of depleted uranium and molten virgin or recycled thermoplastic polymer into desired shapes. Separate streams of depleted uranium and virgin or recycled thermoplastic polymer are simultaneously subjected to heating and mixing conditions. The heating and mixing conditions are provided by a thermokinetic mixer, continuous mixer or an extruder and preferably by a thermokinetic mixer or continuous mixer followed by an extruder. The resulting DUPoly shapes can be molded into radiation shielding material or can be used as counter weights for use in airplanes, helicopters, ships, missiles, armor or projectiles.

  11. Earth'sFuture Multidecadal global cooling and unprecedented ozone loss

    E-Print Network [OSTI]

    Robock, Alan

    of the impacts of 100 small nuclear weapons should motivate the elimination of more than 17,000 nuclear weapons that odd nitrogen produced by the largest nuclear weapons could loft to the stratosphere, resulting; Mills et al., 2008; Stenke et al., 2013]. Even the smallest of nuclear weapons, such as the 15 kt weapon

  12. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]

    2013-01-01

    Journal of the Air & Waste Management Association 63 (2013)Journal of the Air & Waste Management Association 63 (2013)of the Air & Waste Management Association Publication

  13. The Exposure-Response Curve for Ozone and Risk of Mortality and the Adequacy of Current Ozone

    E-Print Network [OSTI]

    Dominici, Francesca

    and applied several statistical models to data on air pollution, weather, and mortality for 98 U.S. urban mortality. Interventions to further reduce ozone pollution would benefit public health, even in regions pollutant linked to numerous harmful health effects, including reduced lung function, increased frequency

  14. Depleted uranium human health risk assessment, Jefferson Proving Ground, Indiana

    SciTech Connect (OSTI)

    Ebinger, M.H.; Hansen, W.R.

    1994-04-29

    The risk to human health from fragments of depleted uranium (DU) at Jefferson Proving Ground (JPG) was estimated using two types of ecosystem pathway models. A steady-state, model of the JPG area was developed to examine the effects of DU in soils, water, and vegetation on deer that were hunted and consumed by humans. The RESRAD code was also used to estimate the effects of farming the impact area and consuming the products derived from the farm. The steady-state model showed that minimal doses to humans are expected from consumption of deer that inhabit the impact area. Median values for doses to humans range from about 1 mrem ({plus_minus}2.4) to 0.04 mrem ({plus_minus}0.13) and translate to less than 1 {times} 10{sup {minus}6} detriments (excess cancers) in the population. Monte Carlo simulation of the steady-state model was used to derive the probability distributions from which the median values were drawn. Sensitivity analyses of the steady-state model showed that the amount of DU in airborne dust and, therefore, the amount of DU on the vegetation surface, controlled the amount of DU ingested by deer and by humans. Human doses from the RESRAD estimates ranged from less than 1 mrem/y to about 6.5 mrem/y in a hunting scenario and subsistence fanning scenario, respectively. The human doses exceeded the 100 mrem/y dose limit when drinking water for the farming scenario was obtained from the on-site aquifer that was presumably contaminated with DU. The two farming scenarios were unrealistic land uses because the additional risk to humans due to unexploded ordnance in the impact area was not figured into the risk estimate. The doses estimated with RESRAD translated to less than 1 {times} 10{sup {minus}6} detriments to about 1 {times} 10{sup {minus}3} detriments. The higher risks were associated only with the farming scenario in which drinking water was obtained on-site.

  15. Global Warming Observations

    E-Print Network [OSTI]

    Schofield, Jeremy

    Global Warming Observations: 1. Global temperature has been gradually rising in recent years #15 in range 8000 12000 nm { CFC's, methane and N 2 O important for global warming even though concentra- tions in concentration of \\greenhouse gases" like CO 2 What determines global temperature? Energy budget of earth: 1

  16. Global Health Seminar Series

    E-Print Network [OSTI]

    Klein, Ophir

    Bay Area Global Health Seminar Series Moving beyond millennium targets in global health: The challenges of investing in health and universal health coverage Although targets can help to focus global health efforts, they can also detract attention from deeper underlying challenges in global health

  17. Experimental and simulation studies of sequestration of supercritical carbon dioxide in depleted gas reservoirs 

    E-Print Network [OSTI]

    Seo, Jeong Gyu

    2004-09-30

    he feasibility of sequestering supercritical CO2 in depleted gas reservoirs. The experimental runs involved the following steps. First, the 1 ft long by 1 in. diameter carbonate core is inserted into a viton Hassler sleeve and placed inside...

  18. Adjoint-Based Uncertainty Quantification and Sensitivity Analysis for Reactor Depletion Calculations 

    E-Print Network [OSTI]

    Stripling, Hayes Franklin

    2013-08-02

    Depletion calculations for nuclear reactors model the dynamic coupling between the material composition and neutron flux and help predict reactor performance and safety characteristics. In order to be trusted as reliable predictive tools and inputs...

  19. Delayed neutron measurements for Th-232, Np-237, Pu-239, Pu-241 and depleted uranium 

    E-Print Network [OSTI]

    Stone, Joseph C.

    2001-01-01

    The neutron emission rates from five very pure actinide samples (Th-232, Np-237, Pu-239, Pu-241 and depleted uranium) were measured following equilibrium irradiation in fast and thermal neutron fluxes. The relative abundances (alphas) for the first...

  20. Accelerated cellular senescence phenotype of GAPDH-depleted human lung carcinoma cells

    SciTech Connect (OSTI)

    Phadke, Manali; Krynetskaia, Natalia; Mishra, Anurag; Krynetskiy, Evgeny; Jayne Haines Center for Pharmacogenomics, Temple University School of Pharmacy, Philadelphia, PA 19140

    2011-07-29

    Highlights: {yields} We examined the effect of glyceraldehyde 3-phosphate (GAPDH) depletion on proliferation of human carcinoma A549 cells. {yields} GAPDH depletion induces accelerated senescence in tumor cells via AMPK network, in the absence of DNA damage. {yields} Metabolic and genetic rescue experiments indicate that GAPDH has regulatory functions linking energy metabolism and cell cycle. {yields} Induction of senescence in LKB1-deficient lung cancer cells via GAPDH depletion suggests a novel strategy to control tumor cell proliferation. -- Abstract: Glyceraldehyde 3-phosphate dehydrogenase (GAPDH) is a pivotal glycolytic enzyme, and a signaling molecule which acts at the interface between stress factors and the cellular apoptotic machinery. Earlier, we found that knockdown of GAPDH in human carcinoma cell lines resulted in cell proliferation arrest and chemoresistance to S phase-specific cytotoxic agents. To elucidate the mechanism by which GAPDH depletion arrests cell proliferation, we examined the effect of GAPDH knockdown on human carcinoma cells A549. Our results show that GAPDH-depleted cells establish senescence phenotype, as revealed by proliferation arrest, changes in morphology, SA-{beta}-galactosidase staining, and more than 2-fold up-regulation of senescence-associated genes DEC1 and GLB1. Accelerated senescence following GAPDH depletion results from compromised glycolysis and energy crisis leading to the sustained AMPK activation via phosphorylation of {alpha} subunit at Thr172. Our findings demonstrate that GAPDH depletion switches human tumor cells to senescent phenotype via AMPK network, in the absence of DNA damage. Rescue experiments using metabolic and genetic models confirmed that GAPDH has important regulatory functions linking the energy metabolism and the cell cycle networks. Induction of senescence in LKB1-deficient non-small cell lung cancer cells via GAPDH depletion suggests a novel strategy to control tumor cell proliferation.

  1. Optimization of Depletion Modeling and Simulation for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Betzler, Benjamin R; Ade, Brian J; Chandler, David; Ilas, Germina; Sunny, Eva E

    2015-01-01

    Monte Carlo based depletion tools used for the high-fidelity modeling and simulation of the High Flux Isotope Reactor (HFIR) come at a great computational cost; finding sufficient approximations is necessary to make the use of these tools feasible. The optimization of the neutronics and depletion model for the HFIR is based on two factors: (i) the explicit representation of the involute fuel plates with sets of polyhedra and (ii) the treatment of depletion mixtures and control element position during depletion calculations. A very fine representation (i.e., more polyhedra in the involute plate approximation) does not significantly improve simulation accuracy. The recommended representation closely represents the physical plates and ensures sufficient fidelity in regions with high flux gradients. Including the fissile targets in the central flux trap of the reactor as depletion mixtures has the greatest effect on the calculated cycle length, while localized effects (e.g., the burnup of specific isotopes or the power distribution evolution over the cycle) are more noticeable consequences of including a critical control element search or depleting burnable absorbers outside the fuel region.

  2. FTT:Power : A global model of the power sector with induced technological change and natural resource depletion

    E-Print Network [OSTI]

    Mercure, Jean-Francois

    2011-08-25

    to reproduce the sigmoid (S -shaped) character of techno- logical transitions that stem from their dynamic nature. Most models use instead procedures of energy systems optimisation based on cost minimisation, which produces optimal equilib- rium solutions... at every second, and therefore some flexibility must exist to make both meet. This is done with power plants which have the ability to vary their output rapidly, such as combined cycle gas turbines (CCGT) or hydroelectric dams. However, a large fraction...

  3. Sum frequency generation and catalytic reaction studies of the removal of the organic capping agents from Pt nanoparticles by UV-ozone treatment

    E-Print Network [OSTI]

    Aliaga, Cesar

    2010-01-01

    and (b) after 2 hours of UV/ozone treatment. (a) 50nm (b)a) before and (b) after UV/ozone treatment for 270 minutes.from Pt nanoparticles by UV-ozone treatment Cesar Aliaga, †

  4. JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 91, NO. D1, PAGES 1103-1116, JANUARY 20, 1986 Two-Dimensional Monthly Average Ozone BalanceFrom

    E-Print Network [OSTI]

    Jackman, Charles H.

    -Dimensional Monthly Average Ozone BalanceFrom Limb Infrared Monitor of the Stratosphereand Stratosphericand consistency.We computethe diurnal averagephotochemicalproductionand lossterms of ozone usingmonthly ozone,whichisthelossrate by thechlorinefamily,iscalculatedfroma two

  5. Depletion of cellular poly (A) binding protein prevents protein synthesis and leads to apoptosis in HeLa cells

    SciTech Connect (OSTI)

    Thangima Zannat, Mst.; Bhattacharjee, Rumpa B.; Bag, Jnanankur

    2011-05-13

    Highlights: {yields} Depletion of cellular PABP level arrests mRNA translation in HeLa cells. {yields} PABP knock down leads to apoptotic cell death. {yields} PABP depletion does not affect transcription. {yields} PABP depletion does not lead to nuclear accumulation of mRNA. -- Abstract: The cytoplasmic poly (A) binding protein (PABP) is important in mRNA translation and stability. In yeast, depletion of PABP leads to translation arrest. Similarly, the PABP gene in Drosophila is important for proper development. It is however uncertain, whether mammalian PABP is essential for mRNA translation. Here we showed the effect of PABP depletion on mRNA metabolism in HeLa cells by using a small interfering RNA. Our results suggest that depletion of PABP prevents protein synthesis and consequently leads to cell death through apoptosis. Interestingly, no detectable effect of PABP depletion on transcription, transport and stability of mRNA was observed.

  6. Global Focus Microscope The Global Health Challenge

    E-Print Network [OSTI]

    . To address this need, we developed the Global Focus Microscope (GFM): a portable, battery- powered, inverted digi- tal images, the Global Focus Microscope comes with shelf for an iPhone 4. Figure 1. From left to right: Malaria parasites imaged at 1000x in bright field mode, tuberculosis imaged at 400x in bright

  7. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  8. The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters 

    E-Print Network [OSTI]

    Buys, Ronald Earl

    1980-01-01

    time of 30 days. 34 10 Correlation between measured and calculated nonadsorbable COD values for bio-oxidized samples. 37 Correlation between measured and calculated nonadsorbable COD values for bio-oxidized plus ozonated samples. 12 Effect... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

  9. Meeting the New Ozone Standard: Challenges and Opportunities

    Broader source: Energy.gov [DOE]

    This presentation by Anna Garcia, executive director of the Ozone Transport Commission, was part of the July 2008 Webcast sponsored by the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Weatherization and Intergovernmental Program Clean Energy and Air Quality Integration Initiative that was titled Role of Energy Efficiency and Renewable Energy in Improving Air Quality and Addressing Greenhouse Gas Reduction Goals on High Electric Demand Days.

  10. The Global Brain is Neither Global nor a Brain

    E-Print Network [OSTI]

    Rocha, Luis

    The Global Brain is Neither Global nor a Brain Adaptive Webs for Heterarchies Luis Mateus Rocha-organism or a global brain? The Global Brain Is Neither Global nor a Brain #12;!Disembodied Brain Disembodied brains on symbol-matter requirements for open-ended evolution) The Global Brain Is Neither Global Nor a Brain #12

  11. The Cost of Crop Damage Caused by Ozone Air Pollution From Motor Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark A.; Murphy, James; Kim, Jin; McCubbin, Donald R.

    1996-01-01

    without motor-vehicle related pollution. This diagram is forBY OZONE AIR POLLUTION FROM MOTOR VEHICLES Report #12 in thePOLLUTION FROM MOTOR VEHICLES

  12. Before House Subcommittee on Africa, Global Health, Global Human...

    Office of Environmental Management (EM)

    House Subcommittee on Africa, Global Health, Global Human Rights, and International Organizations, Committee on Foreign Affairs Before House Subcommittee on Africa, Global Health,...

  13. Cows Causing Global Warming

    E-Print Network [OSTI]

    Hacker, Randi

    2008-08-06

    Broadcast Transcript: Remember when President Reagan blamed trees for air pollution? Well now the Japanese are blaming cows for global warming. Apparently, the methane emissions from burping cows account for 5% of all global greenhouse gases. Simple...

  14. Review: Globalization of Water

    E-Print Network [OSTI]

    Tennant, Matthew Aaron

    2009-01-01

    Review: Globalization of Water: Sharing the Planet’sAshok K. Globalization of Water: Sharing the Planet’s140) liters of virtual water (p. 15). This is one of the

  15. Globalization of biopharmaceutical manufacturing

    E-Print Network [OSTI]

    Pande, Rachna

    2011-01-01

    The biomanufacturing industry is changing due to increasing globalization. However, it is changing differently from other high tech industries like software/ semiconductor/ automobiles. In this study we use global ...

  16. CHILLING CONSIDERATIONS GLOBAL WARMING

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    CHILLING CONSIDERATIONS REGARDING GLOBAL WARMING Stephen E. Schwartz http IS INCREASING Global carbon dioxide concentration over the last thousand years Polar ice cores #12;Mann et al 1000-1850) 1998 THE TEMPERATURE'S RISING #12;GLOBAL ANNUAL TEMPERATURE ANOMALY, 1880-2008 0.8 0.6 0.4 0

  17. SCIENTIFIC EVIDENCE GLOBAL WARMING

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    SCIENTIFIC EVIDENCE FOR GLOBAL WARMING Stephen E. Schwartz Jefferson's Ferry Public Affairs century. The warmest year of the millennium was 1998. #12;EVIDENCE OF GLOBAL WARMING OTHER THAN SURFACE TEMPERATURE ANOMALY The global ocean has warmed significantly since the late 1940s: more than half

  18. Carbon Dioxide & Global Warming

    E-Print Network [OSTI]

    Miami, University of

    Carbon Dioxide & Global Warming University of MiaMi rosenstiel sChool of Marine anD atMospheriC s , organic carbon, and other chemicals that contribute to global warming in a variety of studies. DownCienCe 4600 rickenbacker Causeway Miami, florida 33149 http://www.rsmas.miami.edu the Chemistry of Global

  19. Global Information Technologies

    E-Print Network [OSTI]

    Keromytis, Angelos D.

    Global Information Technologies: Concepts, Methodologies, Tools, and Applications Felix B. Tan in the United States of America by Information Science Reference (an imprint of IGI Global) 701 E. Chocolate (an imprint of IGI Global) 3 Henrietta Street Covent Garden London WC2E 8LU Tel: 44 20 7240 0856 Fax

  20. Meteorology as Infrastructural Globalism

    E-Print Network [OSTI]

    Edwards, Paul N.

    the history of a global governance institution, the World Me- teorological Organization (WMO), from its (from the 1967 inauguration of the Intelsat system) and global environmental monitoring (from the UN Confer- ence on the Human Environment, 1972). Throughout, Hewson sees global governance institutions

  1. GLOBAL TAXONOMY INITIATIVE

    E-Print Network [OSTI]

    Grant, Taran

    #12;THE GLOBAL TAXONOMY INITIATIVE: Using Systematic Inventories to Meet Country and Regional Needs (COP) to the Convention on Biological Diversity (CBD) has endorsed a GlobalTaxonomy Initiative (GTI workshop, The Global Taxonomy Initiative: Shortening the Distance between Discovery and Delivery, made

  2. Stochastic interactions of two Brownian hard spheres in the presence of depletants

    SciTech Connect (OSTI)

    Karzar-Jeddi, Mehdi; Fan, Tai-Hsi; Tuinier, Remco; Taniguchi, Takashi

    2014-06-07

    A quantitative analysis is presented for the stochastic interactions of a pair of Brownian hard spheres in non-adsorbing polymer solutions. The hard spheres are hypothetically trapped by optical tweezers and allowed for random motion near the trapped positions. The investigation focuses on the long-time correlated Brownian motion. The mobility tensor altered by the polymer depletion effect is computed by the boundary integral method, and the corresponding random displacement is determined by the fluctuation-dissipation theorem. From our computations it follows that the presence of depletion layers around the hard spheres has a significant effect on the hydrodynamic interactions and particle dynamics as compared to pure solvent and uniform polymer solution cases. The probability distribution functions of random walks of the two interacting hard spheres that are trapped clearly shift due to the polymer depletion effect. The results show that the reduction of the viscosity in the depletion layers around the spheres and the entropic force due to the overlapping of depletion zones have a significant influence on the correlated Brownian interactions.

  3. Seasonal and Diurnal Variations of Ozone near the Mesopause from Observations of the 11.072-GHz Line

    E-Print Network [OSTI]

    Pratap, P.

    Ground-based observations of the 11.072-GHz line of ozone were made from January 2008 through January 2009. These observations provide an estimate of the diurnal and seasonal variations of ozone in the mesopause region. ...

  4. Depleted Uranium Hexafluoride Management Program. The technology assessment report for the long-term management of depleted uranium hexafluoride. Volume 1

    SciTech Connect (OSTI)

    Zoller, J.N.; Rosen, R.S.; Holliday, M.A. [and others] [and others

    1995-06-30

    With the publication of a Request for Recommendations and Advance Notice of Intent in the November 10, 1994 Federal Register, the Department of Energy initiated a program to assess alternative strategies for the long-term management or use of depleted uranium hexafluoride. This Request was made to help ensure that, by seeking as many recommendations as possible, Department management considers reasonable options in the long-range management strategy. The Depleted Uranium Hexafluoride Management Program consists of three major program elements: Engineering Analysis, Cost Analysis, and an Environmental Impact Statement. This Technology Assessment Report is the first part of the Engineering Analysis Project, and assesses recommendations from interested persons, industry, and Government agencies for potential uses for the depleted uranium hexafluoride stored at the gaseous diffusion plants in Paducah, Kentucky, and Portsmouth, Ohio, and at the Oak Ridge Reservation in Tennessee. Technologies that could facilitate the long-term management of this material are also assessed. The purpose of the Technology Assessment Report is to present the results of the evaluation of these recommendations. Department management will decide which recommendations will receive further study and evaluation. These Appendices contain the Federal Register Notice, comments on evaluation factors, independent technical reviewers resumes, independent technical reviewers manual, and technology information packages.

  5. Depleted Uranium Hexafluoride Management Program. The technology assessment report for the long-term management of depleted uranium hexafluoride. Volume 2

    SciTech Connect (OSTI)

    Zoller, J.N.; Rosen, R.S.; Holliday, M.A. [and others] [and others

    1995-06-30

    With the publication of a Request for Recommendations and Advance Notice of Intent in the November 10, 1994 Federal Register, the Department of Energy initiated a program to assess alternative strategies for the long-term management or use of depleted uranium hexafluoride. This Request was made to help ensure that, by seeking as many recommendations as possible, Department management considers reasonable options in the long-range management strategy. The Depleted Uranium Hexafluoride Management Program consists of three major program elements: Engineering Analysis, Cost Analysis, and an Environmental Impact Statement. This Technology Assessment Report is the first part of the Engineering Analysis Project, and assesses recommendations from interested persons, industry, and Government agencies for potential uses for the depleted uranium hexafluoride stored at the gaseous diffusion plants in Paducah, Kentucky, and Portsmouth, Ohio, and at the Oak Ridge Reservation in Tennessee. Technologies that could facilitate the long-term management of this material are also assessed. The purpose of the Technology Assessment Report is to present the results of the evaluation of these recommendations. Department management will decide which recommendations will receive further study and evaluation.

  6. San Onofre PWR Data for Code Validation of MOX Fuel Depletion Analyses

    SciTech Connect (OSTI)

    Hermann, O.W.

    1999-09-01

    The isotopic composition of mixed-oxide fuel (fabricated with both uranium and plutonium isotope) discharged from reactors is of interest to the Fissile Material Disposition Program. The validation of depletion codes used to predict isotopic compositions of MOX fuel, similar to studies concerning uranium-only fueled reactors, thus, is very important. The EEI-Westinghouse Plutonium Recycle Demonstration Program was conducted to examine the use of MOX fuel in the San Onofre PWR, Unit I, during cycles 2 and 3. The data usually required as input to depletion codes, either one-dimensional or lattice codes, were taken from various sources and compiled into this report. Where data were either lacking or determined inadequate, the appropriate data were supplied from other references. The scope of the reactor operations and design data, in addition to the isotopic analyses, were considered to be of sufficient quality for depletion code validation.

  7. Summary of the engineering analysis report for the long-term management of depleted uranium hexafluoride

    SciTech Connect (OSTI)

    Dubrin, J.W., Rahm-Crites, L.

    1997-09-01

    The Department of Energy (DOE) is reviewing ideas for the long-term management and use of its depleted uranium hexafluoride. DOE owns about 560,000 metric tons (over a billion pounds) of depleted uranium hexafluoride. This material is contained in steel cylinders located in storage yards near Paducah, Kentucky; Portsmouth, Ohio; and at the East Tennessee Technology Park (formerly the K-25 Site) in Oak Ridge, Tennessee. On November 10, 1994, DOE announced its new Depleted Uranium Hexafluoride Management Program by issuing a Request for Recommendations and an Advance Notice of Intent in the Federal Register (59 FR 56324 and 56325). The first part of this program consists of engineering, costs and environmental impact studies. Part one will conclude with the selection of a long-term management plan or strategy. Part two will carry out the selected strategy.

  8. Transient effects and pump depletion in stimulated Raman scattering. [Para-hydrogen

    SciTech Connect (OSTI)

    Carlsten, J.L.; Wenzel, R.G.; Druehl, K.

    1983-01-01

    Stimulated rotational Raman scattering in a 300-K multipass cell filled with para-H/sub 2/ with a single-mode CO/sub 2/-pumped laser is studied using a frequency-narrowed optical parametric oscillator (OPO) as a probe laser at the Stokes frequency for the S/sub 0/(O) transition. Amplification and pump depletion are examined as a function of incident pump energy. The pump depletion shows clear evidence of transient behavior. A theoretical treatment of transient stimulated Raman scattering, including effects of both pump depletion and medium saturation is presented. In a first approximation, diffraction effects are neglected, and only plane-wave interactions are considered. The theoretical results are compared to the experimental pulse shapes.

  9. Depleted uranium hexafluoride management program : data compilation for the Portsmouth site.

    SciTech Connect (OSTI)

    Hartmann, H. M.

    2001-06-05

    This report is a compilation of data and analyses for the Portsmouth site, near Portsmouth, Ohio. The data were collected and the analyses were done in support of the U.S. Department of Energy (DOE) 1999 Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride (DOE/EIS-0269). The report describes the affected environment at the Portsmouth site and summarizes potential environmental impacts that could result from conducting the following depleted uranium hexafluoride (UF{sub 6}) management activities at the site: continued cylinder storage, preparation of cylinders for shipment, conversion, and long-term storage. DOE's preferred alternative is to begin converting the depleted UF{sub 6} inventory as soon as possible to either uranium oxide, uranium metal, or a combination of both, while allowing for use of as much of this inventory as possible.

  10. Depleted uranium hexafluoride management program : data compilation for the Paducah site.

    SciTech Connect (OSTI)

    Hartmann, H.

    2001-06-07

    This report is a compilation of data and analyses for the Paducah site, near Paducah, Kentucky. The data were collected and the analyses were done in support of the U.S. Department of Energy (DOE) 1999 Programmatic Environmental Impact Statement for Alternative Strategies for the Long-Term Management and Use of Depleted Uranium Hexafluoride (DOE/EIS-0269). The report describes the affected environment at the Paducah site and summarizes potential environmental impacts that could result from conducting the following depleted uranium hexafluoride (UF{sub 6}) activities at the site: continued cylinder storage, preparation of cylinders for shipment, conversion, and long-term storage. DOE's preferred alternative is to begin converting the depleted UF{sub 6} inventory as soon as possible to either uranium oxide, uranium metal, or a combination of both, while allowing for use of as much of this inventory as possible.

  11. Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region, induced by dynamic processes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Very low zonally asymmetric ozone values in March 1997 above the North Atlantic-European region September 1998 / Revised: 25 January 1999 / Accepted: 26 January 1999 Abstract. The total ozone distribution before. A spatial pattern correlation between the zonally asymmetric part of total ozone

  12. LA RPARTITION DE L'OZONE ATMOSPHRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER.

    E-Print Network [OSTI]

    Boyer, Edmond

    LA RÉPARTITION DE L'OZONE ATMOSPHÉRIQUE EN FONCTION DE L'ALTITUDE Par M. D. BARBIER. Observatoire observations en déter- minant la distribution de l'ozone par une série de Charlier du type A. En général on ne peut déterminer que la quantité totale d'ozone et la hauteur moyenne de la distribution, ces quantités

  13. Photodissociation of Ozone from 321 to 329 nm: The Relative Yields P2) with O2(X 3

    E-Print Network [OSTI]

    Houston, Paul L.

    Photodissociation of Ozone from 321 to 329 nm: The Relative Yields of O(3 P2) with O2(X 3 g - ), O2 Supporting Information ABSTRACT: Product imaging of O(3 P2) following dissociation of ozone has been used to determine the relative yields of the product channels O(3 P2) + O2(X 3 g - ) of ozone. All three channels

  14. Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH*. Nicolas MOSER**, Caroline CHARPENTIER*, Alexis MOQUET*,

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Measurement of ozone in ambient air with microsensors : on-site campaign Isabelle ZDANEVITCH, Switzerland E-mail : Isabelle.Zdanevitch(a),iner is.fr (corresponding author) ABSTRACT Ozone is actually one by continuous monitors but a better information on ozone levels would be given by a denser monitoring network

  15. Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace

    E-Print Network [OSTI]

    Collins, Gary S.

    Vertical Ozone Profiling at UMBS K. O'Donnell, T. Jobson, M. Erickson, T. Vanreken, W. Wallace been done to determine vertical ozone profiles, especially in environments such as the northern mixed forest where this field campaign is being run. What past research that has been done has shown that ozone

  16. Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis) in Great Smoky Mountains

    E-Print Network [OSTI]

    Neufeld, Howard S.

    Ozone injury on cutleaf coneflower (Rudbeckia laciniata) and crown-beard (Verbesina occidentalis ``Capsule'': Ground-level ozone causes deleterious effects to cutleaf coneflower and crown-beard in Great Smoky Mountains National Park. Abstract Incidence and severity of visible foliar ozone injury on cutleaf

  17. The Huggins band of ozone: Unambiguous electronic and vibrational Zheng-Wang Qu, Hui Zhu, Motomichi Tashiro, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: Unambiguous electronic and vibrational assignment Zheng-Wang Qu, Hui Zhu 12 February 2004; accepted 2 March 2004 The Huggins band of ozone is investigated by means of exact.1063/1.1711589 Because of the importance of ozone for the shielding of harmful UV light, its photophysics has been

  18. Rapid formation of molecular bromine from deliquesced NaBr aerosol in the presence of ozone and UV light

    E-Print Network [OSTI]

    Dabdub, Donald

    Rapid formation of molecular bromine from deliquesced NaBr aerosol in the presence of ozone and UV deliquesced NaBr aerosols in the presence of OH radicals produced by ozone irradiated by UV light, depending on the availability of ozone and bromide in the system. Interface reactions, an important source

  19. The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov, and Reinhard Schinkea)

    E-Print Network [OSTI]

    Farantos, Stavros C.

    The Huggins band of ozone: A theoretical analysis Zheng-Wang Qu, Hui Zhu, Sergy Yu. Grebenshchikov; accepted 16 September 2004 The Huggins band of ozone is investigated by means of dynamics calculations American Institute of Physics. DOI: 10.1063/1.1814098 I. INTRODUCTION Because of the importance of ozone

  20. Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA

    E-Print Network [OSTI]

    Pan, Laura

    Validation of AIRS v4 ozone profiles in the UTLS using ozonesondes from Lauder, NZ and Boulder, USA) are used to examine the quality of the Atmospheric Infrared Sounder (AIRS) v4 vertical ozone profile range), AIRS ozone mixing ratios are larger than ozonesonde measurements, and at higher altitudes ($100

  1. Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core-Shell Morphologies

    E-Print Network [OSTI]

    Products and Mechanisms of Ozone Reactions with Oleic Acid for Aerosol Particles Having Core of oleic acid aerosol particles with ozone are studied below 1% relative humidity. The particles have inert of the organic layer is monitored with increasing ozone exposure by using an aerosol mass spectrometer

  2. 3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1

    E-Print Network [OSTI]

    3USDA Forest Service Gen.Tech.Rep. PSW-GTR-166. 1998. Biochemical Reactions of Ozone in Plants1 Abstract Plants react biochemically to ozone in three phases: with constitutive chemicals in the apoplastic, plant reactions with ozone result in constitutive molecules such as the ozonolysis of ethylene

  3. A New Application of UV-Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin

    E-Print Network [OSTI]

    Parikh, Atul N.

    A New Application of UV-Ozone Treatment in the Preparation of Substrate-Supported, Mesoporous Thin room temperature photochemical method, simply employing ultraviolet light- (187-254 nm) generated ozone. The structures and compositions of the thin film mesophases before and after exposure to UV/ozone were determined

  4. A neural emission-receptor model for ozone reduction S.Barazzetta, G. Corani

    E-Print Network [OSTI]

    Corani, Giorgio

    A neural emission-receptor model for ozone reduction planning S.Barazzetta, G. Corani , G- ulated areas. Ozone is produced by a series of photochemical reactions, activated by the emissions concen- trations are equally complex and cannot be directly used to optimize emission reduction policies

  5. Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution

    E-Print Network [OSTI]

    Thompson, Anne

    Lusaka, Zambia, during SAFARI-2000: Convergence of local and imported ozone pollution Anne M of the southern African burning region were taken at Lusaka, Zambia (15.5S, 28E) in early September 2000. Maximum from trans- boundary recirculation. Starting out over Zambia, Angola, and Namibia, ozone-rich air

  6. White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure

    E-Print Network [OSTI]

    Collins, Gary S.

    White Pine Emission Trends of Monoterpenes and Sesquiterpenes After Acute Ozone Exposure Daniel M on a large scale in forests. Monoterpene and sesquiterpene emissions from trees significantly contribute investigates the effect of an abiotic stress, specifically acute ozone exposure, on the terpene emissions

  7. Intercontinental source attribution of ozone pollution at western U.S. sites using an adjoint method

    E-Print Network [OSTI]

    Jacob, Daniel J.

    the history of air parcels reaching the site. MBO experiences distinct Asian ozone pollution episodes; most stringent air quality standards [Task Force on Hemispheric Transport of Air Pollution, 2007]. Ozone previously to pollutant transport to Hawaii [Vukic´evic´ and Hess, 2000; Hess and Vukic´evic´, 2003

  8. Thesis proposal CSF Brazil 2014 treatment of open pit mines wastewater by a coupled ozone technique

    E-Print Network [OSTI]

    Bordenave, Charles

    /or hydroxides such as MnO2 or Fe(OH)3. The disinfection power of ozone is also well known. Thus the efficiency of University of São Paulo (USP). It has more than 2000 installations in Brazil, Argentina and Peru, treating of new application of ozone permitting to support his growth. Powered by TCPDF (www.tcpdf.org) #12;

  9. Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations

    E-Print Network [OSTI]

    Jacob, Daniel J.

    1 Sources of tropospheric ozone along the Asian Pacific Rim: An analysis of ozonesonde observations contributing to tropospheric ozone over the Asian Pacific Rim in different seasons are quantified by analysis influence along the Pacific Rim occurs in summer, reflecting rapid convective transport of surface pollution

  10. Formaldehyde columns from the Ozone Monitoring Instrument: Urban versus background levels and evaluation using aircraft

    E-Print Network [OSTI]

    Mlllet, Dylan B.

    Formaldehyde columns from the Ozone Monitoring Instrument: Urban versus background levels formaldehyde column (WHCHO) retrievals from the Ozone Monitoring Instrument (OMI) and assess the information (20­200 km) near many urban areas. Citation: Boeke, N. L., et al. (2011), Formaldehyde columns from

  11. Air Pollution Physics and Chemistry EAS 6790 Home Work Assignment Ozone Chemistry 2

    E-Print Network [OSTI]

    Weber, Rodney

    1 Air Pollution Physics and Chemistry EAS 6790 Fall 2010 Home Work Assignment Ozone Chemistry 2 and Chemistry EAS 6790 Fall 2006 Home Work Assignment No. 4, Ozone Chemistry Problems 11.8 and 11.9 (sub-part 1 and 2 only). Daniel Jacob, Atmospheric Chemistry #12;2 Problem 2: 2 2. Consider an air parcel ventilated

  12. The impact of large scale biomass production on ozone air pollution in Joost B. Beltman a

    E-Print Network [OSTI]

    Utrecht, Universiteit

    The impact of large scale biomass production on ozone air pollution in Europe Joost B. Beltman by up to 25% and 40%. Air pollution mitigation strategies should consider land use management. a r t i Poplar a b s t r a c t Tropospheric ozone contributes to the removal of air pollutants from

  13. Response of different-aged black cherry trees to ambient ozone exposure

    SciTech Connect (OSTI)

    Fredericksen, T.S.; Joyce, B.J.; Kouterick, K.B.; Kolb, T.E.; Skelly, J.M.; Steiner, K.C.; Savage, J.E.; Snyder, K.R. (Pennyslvania State Univ., Univ. Park, PA (United States))

    1994-06-01

    Black cherry (Prunus serotina Ehrh.) is a valuable commercial timber species which is also highly sensitive to ozone relative to other eastern deciduous tree species. Studies of ozone effects on forest trees have been restricted mostly to experiments using small seedlings under controlled conditions. Yet, mature trees may differ from seedlings in physiology, morphology, and exposure to air pollutants. An experiment was conducted in 1993 to determine differences in ozone uptake and foliar injury symptoms between open-ground seedlings, forest saplings, and mature forest trees of black cherry in northcentral Pennsylvania. Seedlings grew under the highest ozone concentrations and also had greater seasonal ozone uptake due to higher rates of stomatal conductance. However, because of their indeterminate growth habit, seedlings had lower cumulative ozone uptake per leaf lifespan than saplings or mature trees, both of which had determinate shoot growth. Although greater initially for seedlings, foliar injury was nearly identical between size classes by the end of the growing season. Leaves in the lower crown of larger trees had lower ozone uptake than leaves in the upper crown, but exhibited more foliar injury symptoms. Lower crown leaves received more effective exposure to ozone because of their thinner leaves and had less available photosynthate for repair or replacement of damaged tissue.

  14. Structure and Depletion at Fluoro- and Hydro-carbon/Water Liquid/Liquid Interfaces

    E-Print Network [OSTI]

    Kaoru Kashimoto; Jaesung Yoon; Binyang Hou; Chiu-hao Chen; Binhua Lin; Makoto Aratono; Takanori Takiue; Mark L. Schlossman

    2008-07-18

    The results of x-ray reflectivity studies of two oil/water (liquid/liquid) interfaces are inconsistent with recent predictions of the presence of a vapor-like depletion region at hydrophobic/aqueous interfaces. One of the oils, perfluorohexane, is a fluorocarbon whose super-hydrophobic interface with water provides a stringent test for the presence of a depletion layer. The other oil, heptane, is a hydrocarbon and, therefore, is more relevant to the study of biomolecular hydrophobicity. These results are consistent with the sub-angstrom proximity of water to soft hydrophobic materials.

  15. Electron depletion via cathode spot dispersion of dielectric powder into an overhead plasma

    SciTech Connect (OSTI)

    Gillman, Eric D. [Naval Research Laboratory, 4555 Overlook Ave SW, Washington, District of Columbia 20375 (United States)] [Naval Research Laboratory, 4555 Overlook Ave SW, Washington, District of Columbia 20375 (United States); Foster, John E. [Department of Nuclear Engineering and Radiological Sciences (NERS), University of Michigan, 2355 Bonisteel Blvd., Ann Arbor, Michigan 48109 (United States)] [Department of Nuclear Engineering and Radiological Sciences (NERS), University of Michigan, 2355 Bonisteel Blvd., Ann Arbor, Michigan 48109 (United States)

    2013-11-15

    The effectiveness of cathode spot delivered dielectric particles for the purpose of plasma depletion is investigated. Here, cathode spot flows kinetically entrain and accelerate dielectric particles originally at rest into a background plasma. The time variation of the background plasma density is tracked using a cylindrical Langmuir probe biased approximately at electron saturation. As inferred from changes in the electron saturation current, depletion fractions of up to 95% are observed. This method could be exploited as a means of communications blackout mitigation for manned and unmanned reentering spacecraft as well as any high speed vehicle enveloped by a dense plasma layer.

  16. Development of a Reliable Fuel Depletion Methodology for the HTR-10 Spent Fuel Analysis

    SciTech Connect (OSTI)

    Chung, Kiwhan [Los Alamos National Laboratory; Beddingfield, David H. [Los Alamos National Laboratory; Geist, William H. [Los Alamos National Laboratory; Lee, Sang-Yoon [unaffiliated

    2012-07-03

    A technical working group formed in 2007 between NNSA and CAEA to develop a reliable fuel depletion method for HTR-10 based on MCNPX and to analyze the isotopic inventory and radiation source terms of the HTR-10 spent fuel. Conclusions of this presentation are: (1) Established a fuel depletion methodology and demonstrated its safeguards application; (2) Proliferation resistant at high discharge burnup ({approx}80 GWD/MtHM) - Unfavorable isotopics, high number of pebbles needed, harder to reprocess pebbles; (3) SF should remain under safeguards comparable to that of LWR; and (4) Diversion scenarios not considered, but can be performed.

  17. Engineering the global ecosystem

    E-Print Network [OSTI]

    Stringfellow, William T.; Jain, Ravi

    2010-01-01

    of humans deliberately engineering agricultural landscapes.010-0302-8 EDITORIAL Engineering the global ecosystemtale about human explorers engineering the ecosystem of Mars

  18. Peak production in an oil depletion model with triangular field profiles

    E-Print Network [OSTI]

    Stark, Dudley

    Peak production in an oil depletion model with triangular field profiles Dudley Stark School.S.A. would occur between 1965 and 1970. Oil production in the U.S.A. actually peaked in 1970 and has been declining since then. Hubbert used a logistic curve to approximate the rate of oil production. Deffeyes [2

  19. Sustainable Use and Depletion of Natural Resources: The Quest for Energy

    E-Print Network [OSTI]

    Pilyugin, Sergei S.

    Sustainable Use and Depletion of Natural Resources: The Quest for Energy Stephen R. Humphrey of oil Quest for energy substitution What about other natural resources? #12;How Do We Add 2 billion people by 2050? · Using 70% more of earth's resources · Must provide more energy, food, fiber · Avoid

  20. Excitation energy trapping in photosystem I complexes depleted in Lhca1 and Lhca4

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Excitation energy trapping in photosystem I complexes depleted in Lhca1 and Lhca4 Janne A equally effective energy transfer routes to the PSI core complex, and that Lhca5 provides a less effective energy transfer route. We suggest that the specific location of each Lhca protein within the PSI

  1. Quantum dots and etch-induced depletion of a silicon two-dimensional electron gas

    E-Print Network [OSTI]

    Coppersmith, Susan N.

    Quantum dots and etch-induced depletion of a silicon two-dimensional electron gas L. J. Klein, K. L coupled quantum dots containing individual electrons whose spins act as qubits.4 We have made recent in a silicon quantum dot can be held constant for up to 11 hours. This fulfills an important milestone towards

  2. Depletion interactions in colloid-polymer mixtures X. Ye, T. Narayanan, and P. Tong*

    E-Print Network [OSTI]

    Tong, Penger

    to the depletion effect or London­ van der Waals force and the colloidal suspension is stabilized 5,6 . In addition colloidal particles in polymer solutions control the phase stability of many colloid-polymer mixtures, which in which phase stability is desired. The interaction between the colloidal particles can be ex- pressed

  3. The Fight and Flight Responses of Crickets Depleted of Biogenic Amines

    E-Print Network [OSTI]

    Hofmann, Hans A.

    The Fight and Flight Responses of Crickets Depleted of Biogenic Amines Paul A. Stevenson, Hans A or submissive behaviors. AMT-treated crickets could normally only be brought to fight by coaxing. Though capable metabolic body functions for the prospective fight, whereas the central nervous noradrenergic sys- tem

  4. DOE Issues Request for Quotations for Depleted Uranium Hexafluoride Conversion Technical Services

    Broader source: Energy.gov [DOE]

    Cincinnati – The U.S. Department of Energy (DOE) today issued a Request for Quotation (RFQ) for engineering and operations technical services to support the Portsmouth Paducah Project Office and the oversight of operations of the Depleted Uranium Hexafluoride (DUF6) Conversion Project located in Paducah KY, and Portsmouth OH.

  5. Depleted-heterojunction colloidal quantum dot photovoltaics employing low-cost electrical contacts

    E-Print Network [OSTI]

    Sargent, Edward H. "Ted"

    solution-processed single-junction cells and also multijunction architectures.1 Size-effect tuning also of depleted-heterojunction colloidal quantum dot solar cells, we describe herein a strategy that replaces energy conver- sion. Recently, colloidal quantum dot CQD solar cells were reported that reached above 5

  6. Brightening of 630.0 nm equatorial spread-F airglow depletions Carlos Martinis,1

    E-Print Network [OSTI]

    Mendillo, Michael

    , above the bright feature recorded by the all-sky imager, indicating a possible connection between both occurs. One possible interpretation of this change in the brightness of the depleted structure involves electric fields and winds are medium-scale traveling ionospheric disturbances (MSTIDs) [Hunsucker, 1982

  7. SPALLING FAILURE OF A THERMAL BARRIER COATING ASSOCIATED WITH ALUMINUM DEPLETION

    E-Print Network [OSTI]

    Clarke, David R.

    SPALLING FAILURE OF A THERMAL BARRIER COATING ASSOCIATED WITH ALUMINUM DEPLETION IN THE BOND-COAT EÐA plasma-sprayed thermal barrier coating is observed to spall after oxidation at 11218C from a CoNiCrAlY bond-coated superalloy at the interface between the thermally grown oxide (TGO) and the zir- conia

  8. A method for determining the drift velocity of plasma depletions in the equatorial ionosphere using

    E-Print Network [OSTI]

    Mende, Stephen B.

    . The brightness of these emissions at night corresponds to the line-of-sight integrated product of the O+ and e the objective identification and tracking of depletions. The automation of this process has also allowed of the ionosphere from space. Furthermore, this automation allows the drift velocities of each bubble

  9. FORIG: a modification of the ORIGEN2 isotope-generation and depletion code for fusion problems

    SciTech Connect (OSTI)

    Blink, J.A.

    1982-03-03

    This report describes how to use the FORIG computer code to solve isotope-generation and depletion problems in fusion and fission reactors. FORIG is an adaptation of ORIGEN2 to run on a Cray-1 computer, and to accept more extensive activation cross sections.

  10. Global Change Sustainability

    E-Print Network [OSTI]

    Tipple, Brett

    Global Change and Sustainability Center The GCSC is an inclusionary and interdisciplinary hub that promotes, coordinates, and conducts local to global environmental- and sustainability-related research to complex environmental and sustainability issues and challenges. 2012 Annual Report #12;1GCSC 2012 ANNUAL

  11. Sensitivity analysis of ozone formation and transport for a Central California air pollution episode

    SciTech Connect (OSTI)

    Jin, Ling; Tonse, Shaheen; Cohan, Daniel S.; Mao, Xiaoling; Harley, Robert A.; Brown, Nancy J.

    2009-05-15

    CMAQ-HDDM is used to determine spatial and temporal variations in ozone limiting reagents and local vs upwind source contributions for an air pollution episode in Central California. We developed a first- and second- order sensitivity analysis approach with the Decoupled Direct Method to examine spatial and temporal variations of ozone-limiting reagents and the importance of local vs upwind emission sources in the San Joaquin Valley of central California for a five-day ozone episode (29th July-3rd Aug, 2000). Despite considerable spatial variations, nitrogen oxides (NO{sub x}) emission reductions are overall more effective than volatile organic compound (VOC) control for attaining the 8-hr ozone standard in this region for this episode, in contrast to the VOC control that works better for attaining the prior 1-hr ozone standard. Inter-basin source contributions of NO{sub x} emissions are limited to the northern part of the SJV, while anthropogenic VOC (AVOC) emissions, especially those emitted at night, influence ozone formation in the SJV further downwind. Among model input parameters studied here, uncertainties in emissions of NO{sub x} and AVOC, and the rate coefficient of the OH + NO{sub 2} termination reaction, have the greatest effect on first-order ozone responses to changes in NO{sub x} emissions. Uncertainties in biogenic VOC emissions only have a modest effect because they are generally not collocated with anthropogenic sources in this region.

  12. THE IMPACT OF OZONE ON THE LOWER FLAMMABLE LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

    SciTech Connect (OSTI)

    Sherburne, Carol [Savannah River Site (SRS), Aiken, SC (United States). Savannah River Remediation, LLC; Osterberg, Paul [Fauske and Associates, LLC, Burr Ridge, IL (United States); Johnson, Tom [Fauske and Associates, LLC, Burr Ridge, IL (United States); Frawely, Thomas [Fauske and Associates, LLC, Burr Ridge, IL (United States)

    2013-01-23

    The Savannah River Site, in conjunction with AREVA Federal services, has designed a process to treat dissolved radioactive waste solids with ozone. It is known that in this radioactive waste process, radionuclides radiolytically break down water into gaseous hydrogen and oxygen, which presents a well defined flammability hazard. Flammability limits have been established for both ozone and hydrogen separately; however, there is little information on mixtures of hydrogen and ozone. Therefore, testing was designed to provide critical flammability information necessary to support safety related considerations for the development of ozone treatment and potential scale-up to the commercial level. Since information was lacking on flammability issues at low levels of hydrogen and ozone, a testing program was developed to focus on filling this portion of the information gap. A 2-L vessel was used to conduct flammability tests at atmospheric pressure and temperature using a fuse wire ignition source at 1 percent ozone intervals spanning from no ozone to the Lower Flammable Limit (LFL) of ozone in the vessel, determined as 8.4%(v/v) ozone. An ozone generator and ozone detector were used to generate and measure the ozone concentration within the vessel in situ, since ozone decomposes rapidly on standing. The lower flammability limit of hydrogen in an ozone-oxygen mixture was found to decrease from the LFL of hydrogen in air, determined as 4.2 % (v/v) in this vessel. From the results of this testing, Savannah River was able to develop safety procedures and operating parameters to effectively minimize the formation of a flammable atmosphere.

  13. Surface modification of nitrogen-doped carbon nanotubes by ozone via atomic layer deposition

    SciTech Connect (OSTI)

    Lushington, Andrew; Liu, Jian; Tang, Yongji; Li, Ruying; Sun, Xueliang, E-mail: xsun@eng.uwo.ca [Department of Mechanical and Materials Engineering, University of Western Ontario, London, Ontario N6A 5B9 (Canada)

    2014-01-15

    The use of ozone as an oxidizing agent for atomic layer deposition (ALD) processes is rapidly growing due to its strong oxidizing capabilities. However, the effect of ozone on nanostructured substrates such as nitrogen-doped multiwalled carbon nanotubes (NCNTs) and pristine multiwalled carbon nanotubes (PCNTs) are not very well understood and may provide an avenue toward functionalizing the carbon nanotube surface prior to deposition. The effects of ALD ozone treatment on NCNTs and PCNTs using 10?wt. % ozone at temperatures of 150, 250, and 300?°C are studied. The effect of ozone pulse time and ALD cycle number on NCNTs and PCNTs was also investigated. Morphological changes to the substrate were observed by scanning electron microscopy and high resolution transmission electron microscopy. Brunauer-Emmett-Teller measurements were also conducted to determine surface area, pore size, and pore size distribution following ozone treatment. The graphitic nature of both NCNTs and PCNTs was determined using Raman analysis while x-ray photoelectron spectroscopy (XPS) was employed to probe the chemical nature of NCNTs. It was found that O{sub 3} attack occurs preferentially to the outermost geometric surface of NCNTs. Our research also revealed that the deleterious effects of ozone are found only on NCNTs while little or no damage occurs on PCNTs. Furthermore, XPS analysis indicated that ALD ozone treatment on NCNTs, at elevated temperatures, results in loss of nitrogen content. Our studies demonstrate that ALD ozone treatment is an effective avenue toward creating low nitrogen content, defect rich substrates for use in electrochemical applications and ALD of various metal/metal oxides.

  14. Oceanic alkyl nitrates as a natural source of tropospheric ozone

    E-Print Network [OSTI]

    Neu, Jessica L; Lawler, Michael J; Prather, Michael J; Saltzman, Eric S

    2008-01-01

    1997), The ASAD atmospheric chemistry integration package2007), Global atmospheric chemistry: Integrating overEhhalt (2001), Atmospheric chemistry and greenhouse gases,

  15. Energy Department Selects Global Laser Enrichment for Future...

    Broader source: Energy.gov (indexed) [DOE]

    Operations at Paducah Site DOE Seeks Contractor for Depleted Uranium Hexafluoride (DUF6) Operations at Ohio and Kentucky Facilities DOE Selects Contractor for Depleted...

  16. Energy Department Selects Global Laser Enrichment for Future...

    Energy Savers [EERE]

    Site November 27, 2013 - 12:00pm Addthis Workers inspect cylinders containing depleted uranium hexafluoride. Workers inspect cylinders containing depleted uranium hexafluoride....

  17. A global warning for global warming

    SciTech Connect (OSTI)

    Paepe, R.

    1996-12-31

    The problem of global warming is a complex one not only because it is affecting desert areas such as the Sahel leading to famine disasters of poor rural societies, but because it is an even greater threat to modern well established industrial societies. Global warming is a complex problem of geographical, economical and societal factors together which definitely are biased by local environmental parameters. There is an absolute need to increase the knowledge of such parameters, especially to understand their limits of variance. The greenhouse effect is a global mechanism which means that in changing conditions at one point of the Earth, it will affect all other regions of the globe. Industrial pollution and devastation of the forest are quoted as similar polluting anthropogenic activities in far apart regions of the world with totally different societies and industrial compounds. The other important factor is climatic cyclicity which means that droughts are bound to natural cycles. These natural cycles are numerous as is reflected in the study of geo-proxydata from several sequential geological series on land, ice and deepsea. Each of these cycles reveals a drought cycle which occasionally interfere at the same time. It is believed that the present drought might well be a point of interference between the natural cycles of 2,500 and 1,000 years and the man induced cycle of the last century`s warming up. If the latter is the only cycle involved, man will be able to remediate. If not, global warming will become even more disastrous beyond the 21st century.

  18. Multimodel projections of stratospheric ozone in the 21st century

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    predict continued, global mean cooling of the stratosphere over the next 5 decades, increasing from around 0.25 K/decade at 50 hPa to around 1 K/ decade at 1 hPa under the Intergovernmental Panel on Climate evolution is mainly determined by decreases in halogen concentrations and continued cooling of the global

  19. EIS-0360: Depleted Uranium Oxide Conversion Product at the Portsmouth, Ohio Site

    Broader source: Energy.gov [DOE]

    This site-specific EIS analyzes the construction, operation, maintenance, and decontamination and decommissioning of the proposed depleted uranium hexafluoride (DUF6) conversion facility at three alternative locations within the Paducah site; transportation of all cylinders (DUF6, enriched, and empty) currently stored at the East Tennessee Technology Park (ETTP) near Oak Ridge, Tennessee, to Portsmouth; construction of a new cylinder storage yard at Portsmouth (if required) for ETTP cylinders; transportation of depleted uranium conversion products and waste materials to a disposal facility; transportation and sale of the hydrogen fluoride (HF) produced as a conversion coproduct; and neutralization of HF to calcium fluoride and its sale or disposal in the event that the HF product is not sold.

  20. Ca depletion and the presence of dust in large scale nebulosities in radiogalaxies (I)

    E-Print Network [OSTI]

    M. Villar-Martin; L. Binette

    1995-11-24

    We show that the study of the Calcium depletion is a valid an highly sensitive method for investigating the chemical and physical history of the very extended ionized nebulae seen around radio galaxies (EELR), massive ellipticals and `cooling flow' galaxies. By observing the near IR spectrum of nebular regions characterized by low excitation emission lines (LINER-like), we can use the intensity of the [CaII]$\\lambda\\lambda 7291,7324$\\AA\\ doublet --relative to other lines, like H$\\alpha$-- to infer the amount of Calcium depletion onto dust grains. The presence of dust in these objects --which does not necessarily result in a measurable level of extinction-- would favour a `galactic debris' rather than a `cooling flow' origin for the emitting gas. Before aplying such test to our data, we study four possible alternative mechanisms to dust depletion and which could have explained the absence of the [CaII] lines: a) ionization of Ca$^+$ from its metastable level, b) thermal ionization of Ca$^+$, c) a high ionization parameter and/or a harder ionizing contiuum than usually asummed and d) matter bounded models associated to a hard ionizing continuum. We show that none of these alternative mechanisms explain the absence of the [CaII] lines, except possibly for the highly ionized EELR where a high ionization parameter is required combined with a soft power law. We thus conclude that for the other low excitation emission regions (cooling flows, liners, low excitation EELR), the abscence of the CaII lines {\\it must} be due to the depletion of Calcium onto dust grains.

  1. Evaluation of a novel ozone generation technique for disinfection of poultry hatchers and processed broiler carcasses 

    E-Print Network [OSTI]

    Ramirez, Gerardo Arturo

    1994-01-01

    When comparing electrochemically generated ozone(03)(2.94.2 wt % inside the (hatcher) and formaldehyde (16 n-A formalin + 7.5 g potassium pertnanganate) for disinfection of Salmonella enteiltidis (SE) contaminated agar plates and typical hatchery...

  2. Isolation and characterization of five ozone-inductible cDNA clones from Atriplax canescens (saltbush) 

    E-Print Network [OSTI]

    No, Eun-Gyu

    1994-01-01

    Prolonged exposure of plants to ozone inhibits growth and development and produces visible signs of damage. Within a few hours of exposure, certain biochemical alterations have been observed with the induction of several stress-related proteins...

  3. An ozone climatology of the Dallas-Fort Worth area and its relationship to meteorology 

    E-Print Network [OSTI]

    Nobis, Timothy Edward

    1998-01-01

    The Environmental protection agency has established a hics. National Ambient Air Quality Standard for surface ozone through the Clean Air Act and its amendments. The Dallas / Fort Worth area is in violation of these standards, and to date...

  4. Controlling superconductivity in La2-xSrxCuO4+? by ozone and vacuum annealing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leng, Xiang; Bozovic, Ivan

    2014-11-21

    In this study we performed a series of ozone and vacuum annealing experiments on epitaxial La2-xSrxCuO4+? thin films. The transition temperature after each annealing step has been measured by the mutual inductance technique. The relationship between the effective doping and the vacuum annealing time has been studied. Short-time ozone annealing at 470 °C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 °C to 380 °C slowly brings the sample across the optimal doping point back to the undoped, non-superconducting state. Several ozone and vacuum annealing cycles have been done on themore »same sample and the effects were found to be repeatable and reversible Vacuum annealing of ozone-loaded LSCO films is a very controllable process, allowing one to tune the doping level of LSCO in small steps across the superconducting dome, which can be used for fundamental physics studies.« less

  5. Climatology and Trends in the Forcing of the Stratospheric Ozone Transport

    E-Print Network [OSTI]

    Monier, Erwan

    A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer transport equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re- Analysis (ERA-40). In ...

  6. Controlling superconductivity in La2-xSrxCuO4+? by ozone and...

    Office of Scientific and Technical Information (OSTI)

    time has been studied. Short-time ozone annealing at 470 C oxidizes an underdoped film all the way to the overdoped regime. The subsequent vacuum annealing at 350 C to 380...

  7. Why does surface ozone peak in summertime at Waliguan? Hajime Akimoto,1

    E-Print Network [OSTI]

    in the East Asian Pacific rim region. Model results suggest that there is band of a high ozone between 35°N$45 Hemisphere. In the East Asian Pacific Rim region, most monitoring sites are located downwind of the large

  8. Enhancing Low-Cost Ozone Spectrometers to Measure Mesospheric Winds and Tides

    E-Print Network [OSTI]

    Alam, O B

    2015-01-01

    Ground-based spectrometers have been developed to measure the concentration, velocity, and temperature of ozone in the mesosphere and lower thermosphere (MLT) using low-cost satellite television electronics to observe the 11.072 GHz spectral line of ozone. A two-channel spectrometer has been engineered to yield various performance improvements, including a doubling of the signal-to-noise ratio, improved data processing efficiency, and lower power consumption at 15 W. Following 2009 and 2012 observations of the seasonal and diurnal variations in ozone concentration near the mesopause, the ozone line was observed at an altitude near 95 km and latitude of 38 degrees north using three single-channel spectrometers located at the MIT Haystack Observatory (Westford, MA), Chelmsford High School (Chelmsford, MA), and Union College (Schenectady, NY) pointed south at 8 degrees. Observations from 2009 through 2014 are used to derive the nightly-averaged seasonal variation in meridional velocity, as well as the seasonally...

  9. Environmental Externalities in Electric Power Markets: Acid Rain, Urban Ozone, and Climate Change

    Reports and Publications (EIA)

    1995-01-01

    This article discusses the emissions resulting from the generation of electricity by utilities and their role in contributing to the environmental problems of acid rain, urban ozone, and climate change.

  10. Climatology and trends in the forcing of the stratospheric ozone transport

    E-Print Network [OSTI]

    Monier, Erwan

    A thorough analysis of the ozone transport was carried out using the Transformed-Mean Eulerian (TEM) tracer continuity equation and the European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40). In ...

  11. Ozone predictabilities due to meteorological uncertainties in the Mexico City basin using ensemble forecasts

    E-Print Network [OSTI]

    Bei, Naifang

    The purpose of the present study is to investigate the sensitivity of ozone (O3)[(O subscript 3)] predictions in the Mexico City Metropolitan Area (MCMA) to meteorological initial uncertainties and planetary boundary layer ...

  12. Reductions in ozone concentrations due to controls on variability in industrial flare emissions in Houston, Texas

    E-Print Network [OSTI]

    Nam, Junsang

    2007-01-01

    High concentrations of ozone in the Houston/Galveston area are associated with industrial plumes of highly reactive hydrocarbons, mixed with NOx. The emissions leading to these plumes can have significant temporal variability, ...

  13. Ozone response to emission changes: a modeling study during the MCMA-2006/MILAGRO Campaign

    E-Print Network [OSTI]

    Song, Jihee

    The sensitivity of ozone production to precursor emissions was investigated under five different meteorological conditions in the Mexico City Metropolitan Area (MCMA) during the MCMA-2006/MILAGRO field campaign using the ...

  14. Structural carbohydrate availability with electrochemical ozonation and ammonia pressurization / depressurization pre-treatment technologies 

    E-Print Network [OSTI]

    Williams, James Jason

    1999-01-01

    Experiments were conducted to determine the quantity and conditions of electrochemical ozonation (O?) that maximize the dissolution of the lignin-cellulose complex. Combination treatments of anhydrous ammonia (NH?) and O? were also assessed...

  15. The effect of variability in industrial emissions on ozone formation in Houston, Texas

    E-Print Network [OSTI]

    Webster, Mort David

    2007-01-01

    Ambient observations have indicated that high concentrations of ozone observed in the Houston/Galveston area are associated with plumes of highly reactive hydrocarbons, mixed with NOx, from industrial facilities. Ambient ...

  16. Real-World Studies of Ambient Ozone Formation as a Function of...

    Energy Savers [EERE]

    -- Washington D.C. ace29lawson.pdf More Documents & Publications Weekday and Weekend Air Pollutant Levels in Ozone Problem Areas in the U.S. DOE's Studies of WeekdayWeekend...

  17. Ozone (o3) efficacy on reduction of phytophthora capsici in recirculated horticultural irrigation water 

    E-Print Network [OSTI]

    McDonald, Garry Vernon

    2009-05-15

    Microorganisms that cause plant disease have been isolated in recirculated irrigation water and increase the risks of disease incidence in horticultural operations. Ozone is an effective oxidizer used to disinfect drinking ...

  18. Ground-level ozone in eastern North America : its formation and transport

    E-Print Network [OSTI]

    Zemba, Stephen G.

    1990-01-01

    Ozone (Os), a natural component of the troposphere, is augmented by photochemical processes involving manmade emissions of nitrogen oxides (NOx) and volatile organic compounds (VOCs). Sufficiently high concentrations of ...

  19. Verification of the WRF model during a high ozone event over Houston, TX 

    E-Print Network [OSTI]

    Ames, Douglas Seeley

    2003-01-01

    High ozone values were observed in Houston, TX during August 25 - September 1, 2000. A comparison of WRF data with observations and MM5 data was conducted to determine the WRF model's performance in simulating the meteorological conditions...

  20. Global Cool Cities Alliance

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) is currently supporting the Global Cool Cities Alliance (GCCA), a non-profit organization that works with cities, regions, and national governments to speed the...

  1. Global Energy Management System 

    E-Print Network [OSTI]

    Eidt, B. D.

    2005-01-01

    commitment to Stanford University's Global Climate and Energy Project (GCEP). The overarching goal of this program is the accelerated development of commercially viable energy technologies that can substantially reduce greenhouse gas emissions on a...

  2. The Global Grid

    E-Print Network [OSTI]

    Chatzivasileiadis, Spyros; Andersson, Göran

    2012-01-01

    This paper puts forward the vision that a natural future stage of the electricity network could be a grid spanning the whole planet and connecting most of the large power plants in the world: this is the "Global Grid". The main driving force behind the Global Grid will be the harvesting of remote renewable sources, and its key infrastructure element will be the high capacity long transmission lines. Wind farms and solar power plants will supply load centers with green power over long distances. This paper focusses on the introduction of the concept, showing that a globally interconnected network can be technologically feasible and economically competitive. We further highlight the multiple opportunities emerging from a global electricity network such as smoothing the renewable energy supply and electricity demand, reducing the need for bulk storage, and reducing the volatility of the energy prices. We also discuss possible investment mechanisms and operating schemes. Among others, we envision in such a system...

  3. KRFTWRK – Global Human Electricity

    E-Print Network [OSTI]

    Prohaska, Rainer

    2009-01-01

    Power Network 2.1.1 Virtual Power Plants The Global Powernetwork, based on "Virtual Power Plants", called "VPP". A "participant runs a virtual human power plant. Per every "

  4. Global Research Collaborations

    E-Print Network [OSTI]

    i Global Research Collaborations Merrill Series on The Research Mission..........................................................................................................9 Director, North America Office, German Research Foundation (Deutsch Forschungsgemeinschaft, DFG) International Research Collaboration: Just Nice to Have or Necessary? Panel 1: Research Administrators Prem

  5. Micelle-induced depletion interaction and resultant structure in charged colloidal nanoparticle system

    SciTech Connect (OSTI)

    Ray, D.; Aswal, V. K.; Kohlbrecher, J.

    2015-04-28

    The evolution of the interaction and the resultant structure in the mixed system of anionic silica nanoparticles (Ludox LS30) and non-ionic surfactant decaethylene glycol monododecylether (C12E10), undergoing phase separation, have been studied using small-angle neutron scattering and dynamic light scattering. The measurements have been carried out for a fixed concentration of nanoparticle (1?wt.?%) with varying concentration of surfactant (0 to 1?wt.?%), in the absence and presence of an electrolyte. It is found that the micelles of non-ionic surfactant adsorb on the nanoparticle in the absence of electrolyte (form stable system), whereas these micelles become non-adsorbing in the presence of electrolyte (show phase separation). The phase separation arises because of C12E10 micelles, causing depletion interaction between nanoparticles and leading to their aggregation. The interaction is modeled by double Yukawa potential accounting for attractive depletion as well as repulsive electrostatic forces. Both the interactions (attraction and repulsion) are found to be of long-range. The nanoparticle aggregation (phase separation) is governed by the increase in the magnitude and the range of the depletion attraction with the increase in the surfactant concentration. The nanoparticle aggregates formed are quite large in size (order of micron) and are characterized by the surface fractal having simple cubic packing of nanoparticles within the aggregates.

  6. Power distributions in fresh and depleted LEU and HEU cores of the MITR reactor.

    SciTech Connect (OSTI)

    Wilson, E.H.; Horelik, N.E.; Dunn, F.E.; Newton, T.H., Jr.; Hu, L.; Stevens, J.G. (Nuclear Engineering Division); (2MIT Nuclear Reactor Laboratory and Nuclear Science and Engineering Department)

    2012-04-04

    The Massachusetts Institute of Technology Reactor (MITR-II) is a research reactor in Cambridge, Massachusetts designed primarily for experiments using neutron beam and in-core irradiation facilities. It delivers a neutron flux comparable to current LWR power reactors in a compact 6 MW core using Highly Enriched Uranium (HEU) fuel. In the framework of its non-proliferation policies, the international community presently aims to minimize the amount of nuclear material available that could be used for nuclear weapons. In this geopolitical context, most research and test reactors both domestic and international have started a program of conversion to the use of Low Enriched Uranium (LEU) fuel. A new type of LEU fuel based on an alloy of uranium and molybdenum (UMo) is expected to allow the conversion of U.S. domestic high performance reactors like the MITR-II reactor. Toward this goal, core geometry and power distributions are presented. Distributions of power are calculated for LEU cores depleted with MCODE using an MCNP5 Monte Carlo model. The MCNP5 HEU and LEU MITR models were previously compared to experimental benchmark data for the MITR-II. This same model was used with a finer spatial depletion in order to generate power distributions for the LEU cores. The objective of this work is to generate and characterize a series of fresh and depleted core peak power distributions, and provide a thermal hydraulic evaluation of the geometry which should be considered for subsequent thermal hydraulic safety analyses.

  7. Potential hazards of compressed air energy storage in depleted natural gas reservoirs.

    SciTech Connect (OSTI)

    Cooper, Paul W.; Grubelich, Mark Charles; Bauer, Stephen J.

    2011-09-01

    This report is a preliminary assessment of the ignition and explosion potential in a depleted hydrocarbon reservoir from air cycling associated with compressed air energy storage (CAES) in geologic media. The study identifies issues associated with this phenomenon as well as possible mitigating measures that should be considered. Compressed air energy storage (CAES) in geologic media has been proposed to help supplement renewable energy sources (e.g., wind and solar) by providing a means to store energy when excess energy is available, and to provide an energy source during non-productive or low productivity renewable energy time periods. Presently, salt caverns represent the only proven underground storage used for CAES. Depleted natural gas reservoirs represent another potential underground storage vessel for CAES because they have demonstrated their container function and may have the requisite porosity and permeability; however reservoirs have yet to be demonstrated as a functional/operational storage media for compressed air. Specifically, air introduced into a depleted natural gas reservoir presents a situation where an ignition and explosion potential may exist. This report presents the results of an initial study identifying issues associated with this phenomena as well as possible mitigating measures that should be considered.

  8. Performance upgrades to the MCNP6 burnup capability for large scale depletion calculations

    SciTech Connect (OSTI)

    Fensin, M. L.; Galloway, J. D.; James, M. R.

    2015-04-11

    The first MCNP based inline Monte Carlo depletion capability was officially released from the Radiation Safety Information and Computational Center as MCNPX 2.6.0. With the merger of MCNPX and MCNP5, MCNP6 combined the capability of both simulation tools, as well as providing new advanced technology, in a single radiation transport code. The new MCNP6 depletion capability was first showcased at the International Congress for Advancements in Nuclear Power Plants (ICAPP) meeting in 2012. At that conference the new capabilities addressed included the combined distributive and shared memory parallel architecture for the burnup capability, improved memory management, physics enhancements, and new predictability as compared to the H.B Robinson Benchmark. At Los Alamos National Laboratory, a special purpose cluster named “tebow,” was constructed such to maximize available RAM per CPU, as well as leveraging swap space with solid state hard drives, to allow larger scale depletion calculations (allowing for significantly more burnable regions than previously examined). As the MCNP6 burnup capability was scaled to larger numbers of burnable regions, a noticeable slowdown was realized.This paper details two specific computational performance strategies for improving calculation speedup: (1) retrieving cross sections during transport; and (2) tallying mechanisms specific to burnup in MCNP. To combat this slowdown new performance upgrades were developed and integrated into MCNP6 1.2.

  9. Performance upgrades to the MCNP6 burnup capability for large scale depletion calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fensin, M. L.; Galloway, J. D.; James, M. R.

    2015-04-11

    The first MCNP based inline Monte Carlo depletion capability was officially released from the Radiation Safety Information and Computational Center as MCNPX 2.6.0. With the merger of MCNPX and MCNP5, MCNP6 combined the capability of both simulation tools, as well as providing new advanced technology, in a single radiation transport code. The new MCNP6 depletion capability was first showcased at the International Congress for Advancements in Nuclear Power Plants (ICAPP) meeting in 2012. At that conference the new capabilities addressed included the combined distributive and shared memory parallel architecture for the burnup capability, improved memory management, physics enhancements, and newmore »predictability as compared to the H.B Robinson Benchmark. At Los Alamos National Laboratory, a special purpose cluster named “tebow,” was constructed such to maximize available RAM per CPU, as well as leveraging swap space with solid state hard drives, to allow larger scale depletion calculations (allowing for significantly more burnable regions than previously examined). As the MCNP6 burnup capability was scaled to larger numbers of burnable regions, a noticeable slowdown was realized.This paper details two specific computational performance strategies for improving calculation speedup: (1) retrieving cross sections during transport; and (2) tallying mechanisms specific to burnup in MCNP. To combat this slowdown new performance upgrades were developed and integrated into MCNP6 1.2.« less

  10. Systems integration for global sustainability

    E-Print Network [OSTI]

    2015-01-01

    footprinting of global biofuel production. Appl. Energy 112,tion research because biofuel production and consumption as90% of the global biofuel production of 105 billion liters

  11. Aerosolized neutral endopeptidase reverses ozone-induced airway hyperreactivity to substance P

    SciTech Connect (OSTI)

    Murlas, C.G.; Lang, Z.; Williams, G.J.; Chodimella, V. (Department of Medicine, Rush University, Chicago, IL (United States))

    1992-03-01

    The authors investigated the effects of ozone exposure (3.0 ppm, 2 h) on airway neutral endopeptidase (NEP) activity and bronchial reactivity to substance P in guinea pigs. Reactivity after ozone or air exposure was determined by measuring specific airway resistance in intact unanesthetized spontaneously breathing animals in response to increasing doses of intravenous substance P boluses. The effective dose of substance P (in micrograms) that produced a doubling of baseline specific airway resistance (ED200SP) was determined by interpolation of cumulative substance P dose-response curves. NEP activity was measured in tracheal homogenates made from each animal of other groups exposed to either ozone or room air. By reverse-phase high-pressure liquid chromatography, this activity was characterized by the phosphoramidon-inhibitable cleavage of alanine-p-nitroaniline from succinyl-(Ala)3-p-nitroaniline in the presence of 100 microM amastatin. Mean values of the changes in log ED200SP were 0.27 +/- 0.07 (SE) for the ozone-exposed group and 0.08 +/- 0.04 for the air-exposed group. We found that phosphoramidon significantly increased substance P reactivity in the air-exposed animals (P less than 0.01), but it had no effect in the ozone-exposed group. This finding was associated with a significant reduction in tracheal homogenate NEP activity of ozone-exposed animals compared with controls: mean values were 18.1 +/- 1.9 nmol.min-1.mg protein-1 for the ozone-exposed group and 25.1 +/- 2.4 nmol.min-1.mg protein-1 for air-exposed animals (P less than 0.05). Inhalation of an aerosolized NEP preparation, partially purified from guinea pig kidney, reversed the substance P hyperreactivity produced by ozone exposure.(ABSTRACT TRUNCATED AT 250 WORDS)

  12. Ozone impacts on the productivity of selected crops. [Corn, wheat, soybean and peanut crops

    SciTech Connect (OSTI)

    Heck, W.W.; Cure, W.W.; Shriner, D.S.; Olson, R.J.; Heagle, A.S.

    1982-01-01

    The regional impacts of ozone on corn, wheat, soybean, and peanut crops are estimated by using dose-response functions to relate ambient maximum 7 h/d seasonal ozone concentrations to crop productivity data. Linear dose-response functions were developed from open-top field chamber studies. It was assumed that the limited number of cultivars and growing conditions available for the analysis were representative of major agricultural regions. Hourly ozone data were selected to represent rural concentrations and used to calculate maximum 7-h/d average values. Seasonal ozone averages for counties were extrapolated from approximately 300 monitoring sites. Results must be interpreted with knowledge of these assumptions and sources of uncertainty. Impacts are calculated for county units for the conterminous United States with maps showing patterns and tables summarizing the potential magnitude of ozone effects on selected crop yields. The assessment estimates that approximately three billion dollars of productivity could be gained if current maximum 7 hour per day ozone levels were reduced from present levels to below 25 parts per billion. Dollar values are based on 1978 crop prices, without accounting for price effects, to provide an overall estimate of the impact. Of the estimated economic impact, soybean represents 64%, corn 17%, wheat 12%, and peanuts 7%.

  13. A MODELING APPROACH TO ESTIMATING SNOW COVER DEPLETION AND SOIL MOISTURE RECHARGE IN A SEMI-ARID CLIMATE AT TWO NASA CLPX

    E-Print Network [OSTI]

    Anderson, Charles W.

    THESIS A MODELING APPROACH TO ESTIMATING SNOW COVER DEPLETION AND SOIL MOISTURE RECHARGE IN A SEMI A MODELING APPROACH TO ESTIMATING SNOW COVER DEPLETION AND SOIL MOISTURE RECHARGE IN A SEMI-ARID CLIMATE ________________________________________ Department Head #12;iii ABSTRACT A MODELING APPROACH TO ESTIMATING SNOW COVER DEPLETION AND SOIL MOISTURE

  14. Quantum-trajectory description of laser noise with pump depletion J. Visser, G. Nienhuis, S. M. Dutra, M. P. van Exter, and J. P. Woerdman

    E-Print Network [OSTI]

    Exter, Martin van

    Quantum-trajectory description of laser noise with pump depletion J. Visser, G. Nienhuis, S. M, the value of , and thereby the ground-state depletion, can be appreciable even for modest pumping properties change when the pumping is strong enough to cause depletion of the number of atoms participat- ing

  15. Comment on "Global Genetic Change Tracks Global Climate Warming in

    E-Print Network [OSTI]

    Rodríguez, Miguel Ángel

    Comment on "Global Genetic Change Tracks Global Climate Warming in Drosophila subobscura" Francisco in response to global warming. However, that conclusion is not adequately buttressed by their data, because that chromosomal inversion polymorphisms of Drosophila subobscura are evolving in response to global warming. (2

  16. Eos, Vol. 88, No. 21, 22 May 2007 Humans have come to the realization that

    E-Print Network [OSTI]

    Robock, Alan

    activities, the defense policies of many nations, and nuclear proliferation.Thus, we must seek ways, ozone depletion, global warming, and nuclear smoke all are human- driven problems that have actual and global warming are already happening, while drastic cooling from smoke from nuclear-generated fires has

  17. Siberian gas venting and the end-Permian environmental crisis Henrik Svensen a,

    E-Print Network [OSTI]

    Svensen, Henrik

    and 2006. Heating of organic-rich shale and petroleum bearing evaporites around sill intrusions led with the end-Permian global warming and mass extinction. Heating experiments to 275 °C on petroleum-bearing of the erupted gases. The results indicate that global warming and ozone depletion were the two main drivers

  18. Abstracts EuroDendro 2004 [P] Poster [L] Lecture

    E-Print Network [OSTI]

    to limitation factors. At natural conditions the level of potential stability is essentially higher for investigation of modern global change effects: global warming, total ozone depletion etc. Very important-year Solar activity cycles ­ increment maximums coincided with favourable for growth warm periods

  19. 224 IEEE ELECTRON DEVICE LETTERS, VOL. 23, NO. 4, APRIL 2002 Gate Length Dependent Polysilicon Depletion Effects

    E-Print Network [OSTI]

    Dutton, Robert W.

    - tribution effect, MOSFET, polydepletion, polysilicon depletion ef- fect. I. INTRODUCTION IN THE dual n -p impurity penetration through the gate oxide, while maintaining the required source/drain junction depths [2

  20. GLOBAL WARMING THE GREENHOUSE EFFECT

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    GLOBAL WARMING THE GREENHOUSE EFFECT AND YOUR FAMILY'S CONTRIBUTION TO IT Stephen E. Schwartz://www.grida.no/climate/ipcc_tar/wg1/ #12;EVIDENCE OF GLOBAL WARMING OTHER THAN SURFACE TEMPERATURE ANOMALY The global ocean has warmed latitudes of the Northern Hemisphere. #12;MORE EVIDENCE OF GLOBAL WARMING OTHER THAN SURFACE TEMPERATURE

  1. Sensitivity and uncertainty analysis of atmospheric ozone photochemistry models. Final report, September 30, 1993--December 31, 1998

    SciTech Connect (OSTI)

    Smith, G.P.

    1999-03-01

    The author has examined the kinetic reliability of ozone model predictions by computing direct first-order sensitivities of model species concentrations to input parameters: S{sub ij} = [dC{sub i}/C{sub i}]/[dk{sub j}/k{sub j}], where C{sub i} is the abundance of species i (e.g., ozone) and k{sub j} is the rate constant of step j (reaction, photolysis, or transport), for localized boxes from the LLNL 2-D diurnally averaged atmospheric model. An ozone sensitivity survey of boxes at altitudes of 10--55 km, 2--62N latitude, for spring, equinox, and winter is presented. Ozone sensitivities are used to evaluate the response of model predictions of ozone to input rate coefficient changes, to propagate laboratory rate uncertainties through the model, and to select processes and regions suited to more precise measurements. By including the local chemical feedbacks, the sensitivities quantify the important roles of oxygen and ozone photolysis, transport from the tropics, and the relation of key catalytic steps and cycles in regulating stratospheric ozone as a function of altitude, latitude, and season. A sensitivity-uncertainty analysis uses the sensitivity coefficients to propagate laboratory error bars in input photochemical parameters and estimate the net model uncertainties of predicted ozone in isolated boxes; it was applied to potential problems in the upper stratospheric ozone budget, and also highlights superior regions for model validation.

  2. Tethered balloon-based soundings of ozone, aerosols, and solar radiation near Mexico City during MIRAGE-MEX

    E-Print Network [OSTI]

    Greenberg, JP; Guenther, AB; Turnipseed, A

    2009-01-01

    ozone, aerosols, and solar radiation near Mexico City duringand solar radiation in the atmospheric boundary layer on the northern edge of Mexico

  3. Tethered balloon-based soundings of ozone, aerosols, and solar radiation near Mexico City during MIRAGE-MEX

    E-Print Network [OSTI]

    Greenberg, JP; Guenther, AB; Turnipseed, A

    2009-01-01

    ozone, aerosols, and solar radiation near Mexico City duringsolar radiation in the atmospheric boundary layer on the northern edge of Mexico

  4. Reconstruction and Prediction of Variations of Total Ozone and Associated Variations of UV-B Solar Radiation for Subarctic Regions Based of Dendrochronologic Data

    SciTech Connect (OSTI)

    Zuev, V.V.; Bondarenko, S.L.

    2005-03-18

    Variations of dendrochronologic parameters, especially annual ring density, significantly reflect the physiological tree response to systematic variations of solar UV-B radiation, taking place on monthly and longer timescales during growing season. Such variations of UV-B radiation are totally governed by variations of total ozone (TO). Thus, in any dendrochronologic signal, especially for coniferous trees, there is also a recorded response to TO variations, characterizing variations of UV-B radiation. Because a monitoring of global TO distribution is regularly performed since 1979 using TOMS satellite instrumentation, there appears a possibility to reconstruct TO behavior in the past practically at any point of dendrochronologic monitoring network. The reconstruction is performed by the method of linear regression, based on significant correlation of annual ring density of coniferous trees and TO for coordinates of denrochronologic signal. The present report considers the Subarctic latitudes, which are characterized by considerable TO variations in the second half of twentieth century.

  5. Distributed Gaussian Process Regression for Mobile Sensor Networks Under Localization Uncertainty

    E-Print Network [OSTI]

    changes, due to increasing green- house gas concentrations, stratospheric ozone depletion, and tropical

  6. The State and the Global Ecological Crisis

    E-Print Network [OSTI]

    Carchidi, Victoria

    2006-01-01

    acknowledges that global environmental governance oftenforms of global environmental governance” sitting between

  7. The Private Regulation of Global Corporate Conduct

    E-Print Network [OSTI]

    Vogel, David

    2006-01-01

    issue annual reports Can Forest Certification Fill Gaps in the Global Forest Regime” Global Environmental Politics

  8. Interdisciplinary Investigation of CO2 Sequestration in Depleted Shale Gas Formations

    SciTech Connect (OSTI)

    Zoback, Mark; Kovscek, Anthony; Wilcox, Jennifer

    2013-09-30

    This project investigates the feasibility of geologic sequestration of CO2 in depleted shale gas reservoirs from an interdisciplinary viewpoint. It is anticipated that over the next two decades, tens of thousands of wells will be drilled in the 23 states in which organic-rich shale gas deposits are found. This research investigates the feasibility of using these formations for sequestration. If feasible, the number of sites where CO2 can be sequestered increases dramatically. The research embraces a broad array of length scales ranging from the ~10 nanometer scale of the pores in the shale formations to reservoir scale through a series of integrated laboratory and theoretical studies.

  9. U.S. Natural Gas Underground Storage Depleted Fields Capacity (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of theCubic Feet) Depleted Fields Capacity (Million Cubic

  10. Global Health Center (GHC) Website Architecture

    E-Print Network [OSTI]

    Chapman, Michael S.

    Global Health Center (GHC) Website Architecture About Global Health Student Interest Group Contact) Leadership Electives (overview) PTGH Conversations in Global Health OHSU Global Health Grants Concentration in Global Health Studies Scholarship · Information · Awards · Reports News & Events Donate to the Center

  11. Global decarbonization strategies

    SciTech Connect (OSTI)

    Messner, S.

    1996-12-31

    The presentation covers a brief summary of the research activities of the Environmentally Compatible Energy Strategies Project (ECS) at IIASA. The overall research focuses on long-term global energy development and emissions of greenhouse gases (GHG). The ultimate goal is to analyze strategies that achieve decarbonization of global energy systems during the next century. The specific activities range from mitigation of GHG emissions to an integrated assessment of climate change. One focal point is the GHG mitigation technology inventory CO{sub 2}DB, which presently covers approximately 1,400 technologies related to energy and the greenhouse effect. Another integral part is the development of global energy and emissions scenarios, an effort involving a number of formal models to assess the implications. A large number of global scenarios for the next century has been developed, that could be grouped into three families. All of them include energy efficiency improvements and some degree of decarbonization in the world. They are based on different economic and technological development trajectories, and their emissions range from very high to a stabilization of atmospheric carbon dioxide emissions. The presentation will outline the salient characteristics of the three scenario families and provide some regional implications of these alternative futures.

  12. WORKPLACE GUIDES GLOBAL WORKING

    E-Print Network [OSTI]

    Roelleke, Thomas

    of Stonewall good practice publications ­ profiles some of the employers paving the way for gay staff to work do arise. This guide provides clear, practical tips on how gay employees can access internationalWORKPLACE GUIDES GLOBAL WORKING Supporting lesbian, gay and bisexual staff on overseas assignments

  13. Global Change at Edinburgh

    E-Print Network [OSTI]

    Greenaway, Alan

    at Edinburgh | 2 The Global Change Group Human impacts on our planet are changing the atmosphere, climate, ice and to the CarboEurope programme. Cryosphere: field & remote observations & experiments on glacial erosion Biodiversity and the carbon cycle in Peru 10 Radiation penetration in forest stands 12 Genetics and Past

  14. GLOBALIZATION HAS EXISTED

    E-Print Network [OSTI]

    Huang, Wei

    -tech and social spheres. Leading in our highly connected, dynamic and fast-changing world takes special skills that you will consider joining us in expanding and strengthening Darden's global community and impact. MARC countries with active alumni chapters around the globe. EXAMPLES India Mexico Brazil PARTNER SCHOOLS Darden

  15. On the temperature dependence of organic reactivity, nitrogen oxides, ozone production, and the impact of emission controls in San Joaquin Valley, California

    E-Print Network [OSTI]

    Pusede, S. E.

    The San Joaquin Valley (SJV) experiences some of the worst ozone air quality in the US, frequently exceeding the California 8 h standard of 70.4 ppb. To improve our understanding of trends in the number of ozone violations ...

  16. Overview of ozone human exposure and health risk analyses used in the U.S. EPA's review of the ozone air quality standard.

    SciTech Connect (OSTI)

    Whitfield, R. G.

    1999-03-04

    This paper presents an overview of the ozone human exposure and health risk analyses developed under sponsorship of the U.S. Environmental Protection Agency (EPA). These analyses are being used in the current review of the national ambient air quality standards (NAAQS) for ozone. The analyses consist of three principal steps: (1) estimating short-term ozone exposure for particular populations (exposure model); (2) estimating population response to exposures or concentrations (exposure-response or concentration-response models); and (3) integrating concentrations or exposure with concentration-response or exposure-response models to produce overall risk estimates (risk model). The exposure model, called the probabilistic NAAQS exposure model for ozone (pNEM/03), incorporates the following factors: hourly ambient ozone concentrations; spatial distribution of concentrations; ventilation state of individuals at time of exposure; and movement of people through various microenvironments (e.g., outdoors, indoors, inside a vehicle) of varying air quality. Exposure estimates are represented by probability distributions. Exposure-response relationships have been developed for several respiratory symptom and lung function health effects, based on the results of controlled human exposure studies. These relationships also are probabilistic and reflect uncertainties associated with sample size and variability of response among subjects. The analyses also provide estimates of excess hospital admissions in the New York City area based on results from an epidemiology study. Overall risk results for selected health endpoints and recently analyzed air quality scenarios associated with alternative 8-hour NAAQS and the current 1-hour standard for outdoor children are used to illustrate application of the methodology.

  17. The oceanic cycle and global atmospheric budget of carbonyl sulfide

    SciTech Connect (OSTI)

    Weiss, P.S.

    1994-12-31

    A significant portion of stratospheric air chemistry is influenced by the existence of carbonyl sulfide (COS). This ubiquitous sulfur gas represents a major source of sulfur to the stratosphere where it is converted to sulfuric acid aerosol particles. Stratospheric aerosols are climatically important because they scatter incoming solar radiation back to space and are able to increase the catalytic destruction of ozone through gas phase reactions on particle surfaces. COS is primarily formed at the surface of the earth, in both marine and terrestrial environments, and is strongly linked to natural biological processes. However, many gaps in the understanding of the global COS cycle still exist, which has led to a global atmospheric budget that is out of balance by a factor of two or more, and a lack of understanding of how human activity has affected the cycling of this gas. The goal of this study was to focus on COS in the marine environment by investigating production/destruction mechanisms and recalculating the ocean-atmosphere flux.

  18. Post-treatment of fly ash by ozone in a fixed bed reactor

    SciTech Connect (OSTI)

    Kim Hougaard Pedersen; Merc Casanovas Meli; Anker Degn Jensen; Kim Dam-Johansen

    2009-01-15

    The residual carbon in fly ash produced from pulverized coal combustion can adsorb the air-entraining admixtures (AEAs) added to enhance air entrainment in concrete. This behavior of the ash can be suppressed by exposing the fly ash to oxidizing species, which oxidizes the carbon surface and thus prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O{sub 3}/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data. 28 refs., 7 figs., 3 tabs.

  19. Visible ozone injury on mature black cherry in two Class I wilderness areas

    SciTech Connect (OSTI)

    Chappelka, A. [Auburn Univ., AL (United States). School of Forestry; Skelly, J.; Hildebrand, E. [Pennsylvania Univ., University Park, PA (United States). Dept. of Plant Pathology; Renfro, J. [USDI-NPS, Gatlinburg, TN (United States)

    1995-12-31

    During the summer of 1991--1993, the incidence and severity of foliar symptoms due to ambient ozone exposures were documented on mature black cherry (Prunus serotina) in two Class 1 areas in the Appalachian mountains of the eastern US: Great Smoky Mountains National Park (GRSM) and Shenandoah National Park (SHEN). Three plots in each park containing 30 trees each (Big Meadows in SHEN had 60 trees evaluated each year) with 90 and 120 trees evaluated per GRSM and SHEN, respectively. Plots were established adjacent to ozone monitoring stations at different elevations. Samples of foliage from trees were collected by tree climbers and three exposed branches from the upper crown and three branches form the mid-to-lower crown were evaluated for symptoms of foliar injury due to ozone. Incidence was the greatest in 1991 at both locations; 45% and 60% for SHEN and GRSM, respectively. In 1992 and 1993, incidence was very similar in both parks, with approximately 33% of the trees affected. Black cherry at the highest elevations exhibited the greatest amount of symptoms in both parks all three years of investigation. These sites also exhibited the highest levels of ozone. The results indicate that visible injury due to ambient ozone is prevalent in Class 1 areas in the eastern US, indicative of the nature of this regional phytotoxicant.

  20. Occurrence and severity of foliar ozone symptoms on sensitive hardwood species in Shenandoah National Park, VA

    SciTech Connect (OSTI)

    Hildebrand, E.; Skelly, J.M. (Pennsylvania State Univ., University Park (United States))

    1993-02-01

    To assess the extent of foliar symptoms due to ozone on sensitive hardwoods in the Shenandoah National Park in Virginia, three species were sampled and evaluated at sites of differing elevations adjacent to 3 ozone monitors in 1991 and 1992: black cherry, yellow poplar, and white ash. All foliar samples were evaluated to precent of symptomatic leaves on each branch and average precent leaf area affected. The Horsfall-Barratt rating scale was used to estimate the precent leaf area symptomatic. Ozone symptoms were manifested as stipple on the adazial leaf surface. In the preliminary 1991 sampling, 40, 87, and 7% of black cherry trees sampled were found to be symptomatic at the 3 sites; 63 and 67% of yellow poplar trees sampled were found to be symptomatic at sites 1 and 3, as were 43 and 63% of the white ash at sites 1 and 2 (3 complete sets were not found in 1991). In 1992, the sampling and rating of injury were repeated. Symptoms of ozone injury appeared on 23, 88, and 10% of black cherry, on 17, 7, and 80% of yellow poplar, and 27, 40, and 40% of white ash. Elevation and ozone exposure will be discussed.