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Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Glass Structure  

Science Journals Connector (OSTI)

... Structure and Crystallization of Glasses. By WernerVogel. Pp. 246. (Pergamon: Oxford and New York, October 1971. ... account of the experimental work on liquid-liquid separation and nucleation and crystal growth in glasses carried out by the author and his colleagues in the laboratories of VEB Jena ...

R. W. DOUGLAS

1972-04-07T23:59:59.000Z

2

Structure of Glass  

Science Journals Connector (OSTI)

... Introduction of certain cations in soda or potash glass contracts or expands the network proportionally to the concentration, each oxide having its own ... constant over a wide range of compositions. The factors are different for soda and potash glasses, but they remain constant when

I. NÁRAY-SZABÓ

1959-03-28T23:59:59.000Z

3

Glass as a structural material.  

E-Print Network (OSTI)

??Glass can be beautiful and strong, so why is it not used more often as a structural material? Most often the reasoning is because people… (more)

White, Rachel Lynn

2007-01-01T23:59:59.000Z

4

Structure glass technology : systems and applications  

E-Print Network (OSTI)

Glass cannot compete with steel in terms of strength or durability, but it is the only structural material that offers the highly sought after qualities of translucency and transparency. The use of glass has evolved from ...

Leitch, Katherine K. (Katherine Kristen)

2005-01-01T23:59:59.000Z

5

On the Strength and Structure of Glass  

Science Journals Connector (OSTI)

...research-article On the Strength and Structure of Glass J. E. Gordon D. M. Marsh Margaret E. M. L. Parratt The strength of glass is known to be very variable and also...been revealed on the surface of drawn glasses. These crack systems are correlated...

1959-01-01T23:59:59.000Z

6

Transparant ductility: Reinforcing a structural glass girder:.  

E-Print Network (OSTI)

??Transparency and light are hot items in building design and massive structural elements often form an unwelcome necessity for architects. The structural use of glass… (more)

Rademakers, M.

2009-01-01T23:59:59.000Z

7

Structure and Density of Glass  

Science Journals Connector (OSTI)

... SiO2-B2O3 mixed glasses show a linear relation between v and R, which is the number of oxygen ... where the chemical symbols stand for the gram atoms present in a given quantity of glass (for example, 100 gm.) of the respective elements. For SiO2-B2O 3- ...

I. NÁRAY-SZABÓ

1958-01-04T23:59:59.000Z

8

Probing the glass transition from structural and vibrational properties of zero-temperature glasses  

E-Print Network (OSTI)

We find that the density dependence of the glass transition temperature of Lennard-Jones (LJ) and Weeks-Chandler-Andersen (WCA) systems can be predicted from properties of the zero-temperature ($T=0$) glasses. Below a crossover density $\\rho_s$, LJ and WCA glasses show different structures, leading to different vibrational properties and consequently making LJ glasses more stable with higher glass transition temperatures than WCA ones. Above $\\rho_s$, structural and vibrational quantities of the $T=0$ glasses show scaling collapse. From scaling relations and dimensional analysis, we predict a density scaling of the glass transition temperature, in excellent agreement with simulation results. We also propose an empirical expression of the glass transition temperature using structural and vibrational properties of the $T=0$ glasses, which works well over a wide range of densities.

Lijin Wang; Ning Xu

2014-02-10T23:59:59.000Z

9

glass jewelry  

Science Journals Connector (OSTI)

various personal adornments decorated with glass or made of glass, beads, finger rings, pendants, necklaces,...

2009-01-01T23:59:59.000Z

10

Dynamics of the Structural Glass Transition and the p-Spin—Interaction Spin-Glass Model  

Science Journals Connector (OSTI)

The mathematical structure of the dynamical theory for the soft-spin version of the p-spin-interaction (p>2) spin-glass model is related to that for the dynamical theories of the structural glass transition. The phase transitions predicted by both theories are discussed. The spin-glass transition predicted by the dynamical theory is related to a broken-replica-symmetry equilibrium calculation.

T. R. Kirkpatrick and D. Thirumalai

1987-05-18T23:59:59.000Z

11

Structure of rhenium-containing sodium borosilicate glass  

SciTech Connect

A series of sodium borosilicate glasses were synthesized with increasing fractions of KReO4 or Re2O7, to 10000 ppm (1 mass%) target Re in glass, to assess the effects of large concentrations of rhenium on glass structure and to estimate the solubility of technetium, a radioactive component in typical low active waste nuclear waste glasses. Magic angle spinning nuclear magnetic resonance (MAS-NMR), Fourier transform infrared (FTIR) spectroscopy, and Raman spectroscopy were performed to characterize the glasses as a function of Re source additions. In general, silicon was found coordinated in a mixture of Q2 and Q3 structural units, while Al was 4-coordinated and B was largely 3-coordinate and partially 4-coordinated. The rhenium source did not appear to have significant effects on the glass structure. Thus, at the up to the concentrations that remain in dissolved in glass, ~3000 ppm Re by mass maximum. , the Re appeared to be neither a glass-former nor a strong glass modifier., Rhenium likely exists in isolated ReO4- anions in the interstices of the glass network, as evidenced by the polarized Raman spectrum of the Re glass in the absence of sulfate. Analogous to SO42-¬ in similar glasses, ReO4- is likely a network modifier and forms alkali salt phases on the surface and in the bulk glass above solubility.

Goel, Ashutosh; McCloy, John S.; Windisch, Charles F.; Riley, Brian J.; Schweiger, Michael J.; Rodriguez, Carmen P.; Ferreira, Jose M.

2013-03-01T23:59:59.000Z

12

Glass Production  

E-Print Network (OSTI)

Late Bronze Age glasses. Journal of Archaeological Science781 - 789. Turner, W.E.S. 1954 Studies in ancient glassesand glass making processes. Part I: Crucibles and melting

Shortland, Andrew

2009-01-01T23:59:59.000Z

13

silica glass  

Science Journals Connector (OSTI)

...any amorphous, pale yellow to pale green natural silica glass such as moldavite, Libyan Desert glass, contains nearly 98% silica. RI:...

2009-01-01T23:59:59.000Z

14

Nano-structured self-cleaning superhydrophobic glass  

E-Print Network (OSTI)

5. Optically transparent glass with vertically alignedcomposition of biosoluble glass fiber” Korean ApplicationS. Jin, “Optically Transparent Glass with Vertically Aligned

Kim, Jin Yeol

2010-01-01T23:59:59.000Z

15

Glass balls  

E-Print Network (OSTI)

There is a building with 100 floors in it, and glass balls, and an integer k with the following property. If one drops a glass ball from the floor number k or higher, ...

16

Venetian glass  

Science Journals Connector (OSTI)

...a term used for imitation pearl made of hollow, iridescent glass, which is filled with wax to increase...

2009-01-01T23:59:59.000Z

17

The effect of reinforcement on loadbearing capacity of structural glass  

E-Print Network (OSTI)

The transparent property of glass makes it a favored choice of material in the design of structures because it maximizes light and creates an illusion of larger spaces. However, it is a very brittle, making it difficult ...

Navarro, Bridget I. (Bridget Isabela)

2011-01-01T23:59:59.000Z

18

Renaissance of paper models and folded plate structures in glass  

Science Journals Connector (OSTI)

This paper presents the development of glass folded plate structures. Glass will not only be used as a transparent covering but as a load-bearing element for the whole structure. A complete outline ranging from the architectural approach including simple paper models to structural analysis will be presented. The structural concept and its functional characteristics will be confirmed by finite element analysis. Moreover, this paper will also put into focus the geometrical diversity and individuality and will present mathematical algorithms as definitions of the geometrical freeform.

Stefan Trometer; Mathias Krupna

2010-01-01T23:59:59.000Z

19

Structure and Chemistry in Halide Lead-Tellurite Glasses  

SciTech Connect

A series of TeO2-PbO glasses were fabricated with increasing fractions of mixed alkali, alkaline earth, and lanthanide chlorides. The glass and crystal structure was studied with Raman spectroscopy, nuclear magnetic resonance (NMR), X-ray diffraction, and electron microscopy. As the chloride fraction increased, the medium-range order in the glass decreased up to a critical point (~14 mass% of mixed chlorides), above which the glasses became phase-separated. Resulting phases are a TeO2/PbO-rich phase and a crystalline phase rich in alkali chlorides. The 125Te NMR indicates, contrary to previous studies, that Te site distribution did not change with increased concentrations of M+, M2+, and M3+ cations, but rather is controlled by the Te/Pb molar ratio. The 207Pb NMR shows that two Pb species exist and their relative concentration changes nearly linearly with addition of the mixed chlorides, indicating that the additives to the TeO2-PbO glass are accommodated by changing the Pb species. The 23Na and 35Cl NMR indicate that Na and Cl are distributed in the single-phase glass phase up to the critical point, and at higher concentrations partition to crystalline phases. Transmission electron microscopy shows that the sample at the critical point contains ~10 nm seed nuclei that increase in size and concentration with exposure to the electron beam.

McCloy, John S.; Riley, Brian J.; Lipton, Andrew S.; Windisch, Charles F.; Washton, Nancy M.; Olszta, Matthew J.; Rodriguez, Carmen P.

2013-02-11T23:59:59.000Z

20

Optical Glass  

Science Journals Connector (OSTI)

... space of time. In the forefront of such vital industries is the manufacture of optical glass. However great the other resources in men and material may be, it would be ... be, it would be quite impossible to wage successful warfare without adequate supplies of optical glass ior binocular field- ...

1919-03-27T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Glass Technology  

Science Journals Connector (OSTI)

... WE have received from the Department of Glass Technology, University of Sheffield, a copy of vol. ii. of “Experimental Researches ... that department. The papers included have already appeared in the Journal of the Society of Glass Technology. They range over a somewhat wide field of the ...

1920-08-23T23:59:59.000Z

22

Tempered Glass  

Science Journals Connector (OSTI)

... year (NATURE, vol. xxxi. p. 7). It consists in the production of glass which appears to be of a very homogeneous character and of considerable strength and hardness ... which we propose to refer shortly, is that of keeping the whole body of the glass at a uniform temperature during the operations of heating and cooling—that is to say ...

1885-03-05T23:59:59.000Z

23

Structural models of bioactive glasses from molecular dynamics simulations  

Science Journals Connector (OSTI)

...to adsorb and dissociate a water molecule (Tilocca Cormack 2008...the available computational power steadily grows, it will become...surface of bioactive glasses: water adsorption and reactivity...soda-lime silicate glasses by Car-Parrinello molecular dynamics...

2009-01-01T23:59:59.000Z

24

Surface treatment of glass-reinforced plastics: Structural study of silane finish layers on the surface of glass fillers. Modification of finishes by transition metal salts  

Science Journals Connector (OSTI)

The structure and chemical composition of glass fiber surface treatment substances and their influence on composite materials...

O. E. Fedorova; T. L. Ragulina

2010-10-01T23:59:59.000Z

25

Stability of Bulk Metallic Glass Structure. Final Report  

SciTech Connect

The fundamental origins of the stability of the (Pd-Ni){sub 80}P{sub 20} bulk metallic glasses (BMGs), a prototype for a whole class of BMG formers, were explored. While much of the properties of their BMGs have been characterized, their glass-stability have not been explained in terms of the atomic and electronic structure. The local structure around all three constituent atoms was obtained, in a complementary way, using extended X-ray absorption fine structure (EXAFS), to probe the nearest neighbor environment of the metals, and extended energy loss fine structure (EXELFS), to investigate the environment around P. The occupied electronic structure was investigated using X-ray photoelectron spectroscopy (XPS). The (Pd-Ni){sub 80}P{sub 20} BMGs receive their stability from cumulative, and interrelated, effects of both atomic and electronic origin. The stability of the (Pd-Ni){sub 80}P{sub 20} BMGs can be explained in terms of the stability of Pd{sub 60}Ni{sub 20}P{sub 20} and Pd{sub 30}Ni{sub 50}P{sub 20}, glasses at the end of BMG formation. The atomic structure in these alloys is very similar to those of the binary phosphide crystals near x=0 and x=80, which are trigonal prisms of Pd or Ni atoms surrounding P atoms. Such structures are known to exist in dense, randomly-packed systems. The structure of the best glass former in this series, Pd{sub 40}Ni{sub 40}P{sub 20} is further described by a weighted average of those of Pd{sub 30}Ni{sub 50}P{sub 20} and Pd{sub 60}Ni{sub 20}P{sub 20}. Bonding states present only in the ternary alloys were found and point to a further stabilization of the system through a negative heat of mixing between Pd and Ni atoms. The Nagel and Tauc criterion, correlating a decrease in the density of states at the Fermi level with an increase in the glass stability, was consistent with greater stability of the Pd{sub x}Ni{sub 80-x}P{sub 20} glasses with respect to the binary alloys of P. A valence electron concentration of 1.8 e/a, which ensures the superpositioning of the first peak in the structure factor with twice the Fermi momentum, was used to calculate the interatomic potential of these alloys. The importance of Pd to the stability of the alloys is evidenced by the fact that replacing Ni and Pd places the nearest neighbor distances at more attractive positions in this potential.

Jain, H.; Williams, D. B.

2003-06-01T23:59:59.000Z

26

Glass | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

industry sectors. Industrial Glass Bandwidth Analysis (2007) Documents for historical reference Energy and Environmental Profile of the Glass Industry (2002) Glass Industry...

27

Through a glass darkly  

E-Print Network (OSTI)

Closeup Through a glass darklyThrough a glass darkly James E. Hall Keywords: AKAP2; AQP0;Medicine Closeup Through a glass darkly GLUT1 Glucose

Hall, James E

2012-01-01T23:59:59.000Z

28

Crystal structure of Sr-akermanite glass–ceramics  

Science Journals Connector (OSTI)

A glass–ceramic of Sr-akermanite (Sr2MgSi2O7, SG: P 4 ¯ 2 1 m ) was prepared by crystallization of a glass with composition of 2SrOMgO3SiO2. Parameters of the crystal structure were refined by Rietveld method. The analysis of the experimental results showed the following: the unit cell of Sr-akermanite in the glass–ceramic is larger than in single crystal. The thermal expansion coefficients of Sr-akermanite, calculated from the lattice constants obtained from X-ray diffractograms at high temperatures, were ?a = 3.663 × 10?6 K?1 and ?c = 6.666 × 10?6 K?1. It is suggested that the atomic displacements from the atomic coordination in single crystal depend on the stress developed during the crystallization process and the thermal contraction stress developed during cooling. Both types of stresses are related to the presence of residual glass and should be responsible for the expansion of the crystal lattice.

Yasuo Ochi

2006-01-01T23:59:59.000Z

29

Crystal structure of Sr-akermanite glass-ceramics  

SciTech Connect

A glass-ceramic of Sr-akermanite (Sr{sub 2}MgSi{sub 2}O{sub 7}, SG: P4-bar 2{sub 1}m) was prepared by crystallization of a glass with composition of 2SrO?MgO?3SiO{sub 2}. Parameters of the crystal structure were refined by Rietveld method. The analysis of the experimental results showed the following: the unit cell of Sr-akermanite in the glass-ceramic is larger than in single crystal. The thermal expansion coefficients of Sr-akermanite, calculated from the lattice constants obtained from X-ray diffractograms at high temperatures, were {alpha}{sub a}=3.663x10{sup -6}K{sup -1} and {alpha}{sub c}=6.666x10{sup -6}K{sup -1}. It is suggested that the atomic displacements from the atomic coordination in single crystal depend on the stress developed during the crystallization process and the thermal contraction stress developed during cooling. Both types of stresses are related to the presence of residual glass and should be responsible for the expansion of the crystal lattice.

Ochi, Yasuo [Research and Development Division, Ohara Incorporated Company, Naka 2-22-28, Kunitachi, Tokyo (Japan)]. E-mail: yasuo_ochi@ybb.ne.jp

2006-10-12T23:59:59.000Z

30

Colored optical glass  

Science Journals Connector (OSTI)

The Lytkarino Optical Glass Factory manufactures various types of colored optical glasses: yellow, orange, and red glasses and glasses that are transparent in the IR region, as well as...

Mogil’naya, L G; Zinov’eva, O B; Firsova, Yu A; Gulyukin, M N

2013-01-01T23:59:59.000Z

31

THE GLASS CEILING: STRUCTURAL, CULTURAL AND ORGANIZATIONAL CAREER BARRIERS FOR FRENCH AND  

E-Print Network (OSTI)

THE GLASS CEILING: STRUCTURAL, CULTURAL AND ORGANIZATIONAL CAREER BARRIERS FOR FRENCH AND TURKISH is particularly focused on the glass ceiling issues and the main career obstacles for female executives based to the concept of the `glass ceiling'. A comparative descriptive analysis was conducted to show differences

Paris-Sud XI, Université de

32

Structural models of bioactive glasses from molecular dynamics simulations  

Science Journals Connector (OSTI)

...an excellent reference to support new fundamental investigations, whose conclusions will...bone-bonding ability of bioactive materials, fundamental investigations only need to focus on...bioactive glass-ceramic prostheses. In Handbook of bioactive ceramics: 1. Bioactive...

2009-01-01T23:59:59.000Z

33

A World of Glass  

Science Journals Connector (OSTI)

...This clear molten liquid began to transform agriculture and horticulture. The use of glass houses to promote the precocious growth...enclosed coaches, watch-glasses, lighthouses, and street lighting. The sextant required glass, and the precision chronometer...

Alan Macfarlane; Gerry Martin

2004-09-03T23:59:59.000Z

34

A World of Glass  

Science Journals Connector (OSTI)

...transform agriculture and horticulture. The use of glass houses...appeared. Glass cloches and greenhouses improved the cultivation...lighthouses, and street lighting. The sextant required glass...lanterns, lighthouses, and greenhouses, and finally through cameras...

Alan Macfarlane; Gerry Martin

2004-09-03T23:59:59.000Z

35

Plastic Flow in Glass  

Science Journals Connector (OSTI)

...1964 research-article Plastic Flow in Glass D. M. Marsh The classical brittle fracture...account for the mechanical properties of glasses, but the widespread evidence of plastic flow in all glass fracture phenomena even at room temperature...

1964-01-01T23:59:59.000Z

36

Compositional threshold for Nuclear Waste Glass Durability  

SciTech Connect

Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

Kruger, Albert A. [Pacific Northwest National Lab., Richland, WA (United States); Farooqi, Rahmatullah [Pohang Univ. of Science and Technology, (Korea, Republic of); Hrma, Pavel R. [Pacific Northwest National Lab., Richland, WA (United States), Pohang Univ. of Science and Technology, (Korea, Republic of)

2013-04-24T23:59:59.000Z

37

CRYSTALLIZATION IN MULTICOMPONENT GLASSES  

SciTech Connect

In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

KRUGER AA; HRMA PR

2009-10-08T23:59:59.000Z

38

Glass science tutorial: Lecture No. 7, Waste glass technology for Hanford  

SciTech Connect

This paper presents the details of the waste glass tutorial session that was held to promote knowledge of waste glass technology and how this can be used at the Hanford Reservation. Topics discussed include: glass properties; statistical approach to glass development; processing properties of nuclear waste glass; glass composition and the effects of composition on durability; model comparisons of free energy of hydration; LLW glass structure; glass crystallization; amorphous phase separation; corrosion of refractories and electrodes in waste glass melters; and glass formulation for maximum waste loading.

Kruger, A.A.

1995-07-01T23:59:59.000Z

39

Changes in the Atomic Structure through Glass Transition Observed by X-Ray Scattering  

SciTech Connect

The glass transition involves a minor change in the internal energy, and yet the physical and mechanical properties of a glass change dramatically. In order to determine the evolution of the atomic structure through the glass transition, we employed in-situ synchrotron X-ray scattering measurements as a function of temperature on a model material: Zr-Cu-Al metallic glass. We found that the thermal expansion at the atomic level is smaller than the macroscopic thermal expansion, and significantly increases above the glass transition temperature. The observed changes in the pair-distribution function (PDF) are explained in terms of the fluctuations in the local atomic volume and their change through the glass transition.

Egami, Takeshi [ORNL

2012-01-01T23:59:59.000Z

40

Absence of Red Structural Color in Photonic Glasses, Bird Feathers and Certain Beetles  

E-Print Network (OSTI)

Colloidal glasses, bird feathers, and beetle scales can all show structural colors arising from short-ranged spatial correlations between scattering centers. Unlike the structural colors arising from Bragg diffraction in ordered materials like opals, the colors of these photonic glasses are independent of orientation, owing to their disordered, isotropic microstructures. However, there are few examples of photonic glasses with angle-independent red colors in nature, and colloidal glasses with particle sizes chosen to yield structural colors in the red show weak color saturation. Using scattering theory, we show that the absence of angle-independent red color can be explained by the tendency of individual particles to backscatter light more strongly in the blue. We discuss how the backscattering resonances of individual particles arise from cavity-like modes, and how they interact with the structural resonances to prevent red. Finally, we use the model to develop design rules for colloidal glasses with red, angle-independent structural colors.

Sofia Magkiriadou; Jin-Gyu Park; Young-Seok Kim; Vinothan N. Manoharan

2014-11-14T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Reinforced glass beamsReinforced glass beamsg Auteur Dr. Christian LOUTER 1  

E-Print Network (OSTI)

Reinforced glass beamsReinforced glass beamsg EDCE Auteur Dr. Christian LOUTER 1 ENAC/EDCE 2011In contemporary architecture glass is increasinglyIn contemporary architecture glass is increasingly applied for structural components such as beamsapplied for structural components such as beams. However glass

42

NEWS & VIEWS Glass dynamics  

E-Print Network (OSTI)

NEWS & VIEWS Glass dynamics Diverging views on glass transition Gregory B. mc.mckenna@ttu.edu T he glass transition is one of the most intriguing phenomena in the world of soft condensed matter. Despite decades of study, many aspects of the behaviour of glass-forming liquids remain elusive

Weeks, Eric R.

43

Glass Cookware Safety  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Cookware Safety Glass Cookware Safety Under the wrong conditions, glass cookware can crack, break or shatter. Glass cookware is tempered (heat resistant). However, there are many steps to follow to ensure safe use of glass cookware. Glass Cookware Steps: If the steps are not followed, glass cookware can shatter unexpectedly. shatters, (it looks as if it has exploded) If glass bakeware is chipped, cracked, or scratched, it's time for it to be retired from service. It is more likely to shatter! Don't take glass bakeware directly from the freezer to the oven, or vice versa. Allow the oven to fully preheat before putting glassware inside. Don't add liquid to glassware that is already hot. Cover the bottom of glass bakeware with liquid before cooking meat or vegetables.

44

Origin of the first sharp diffraction peak in the structure factor of covalent glasses  

Science Journals Connector (OSTI)

A model is proposed for the ‘‘first sharp diffraction peak’’ (FSDP) in glasses. The FSDP is a chemical-order prepeak due to interstitial volume around cation-centered structural units. Calculated FSDP positions of some covalent glasses agree well with experiment, and the anomalous temperature and pressure dependences of the FSDP can be understood in terms of density effects.

S. R. Elliott

1991-08-05T23:59:59.000Z

45

ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 industrialbandwidth.pdf More Documents &...

46

Glass and Glass Products (2010 MECS)  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Glass Sector (NAICS 3272, 327993) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

47

Europium oxidation state and local structure in silicate glasses  

Science Journals Connector (OSTI)

...0.44 1650 10 0.68 0.15 NS2 Mu832 69.98 - - - - - 30...and Di Cicco 1995). As GNXAS code performs a fit on the total signal...sodium disilicate composition (NS2) was synthesized to have a sample...Glasses Mu809 HPG8Na Mu824 DiAn NS2* Zu907 HPG8An Zu908 HPG8Na...

M. Rita Cicconi; Gabriele Giuli; Eleonora Paris; Werner Ertel-Ingrisch; Peter Ulmer; Donald B. Dingwell

48

Effect of Li{sub 2}SO{sub 4} addition on structure and ionic conductivity of lithium borosilicotitanate glasses  

SciTech Connect

Lithium borosilicotitanate glasses containing Li{sub 2}SO{sub 4} were prepared by melt quenching technique. Electrical conductivity, density, molar volume and glass transition temperature T{sub g} for all the glass samples were measured. IR spectroscopy was used for structural studies of these glasses in the range from 400 to 2000 cm{sub ?1}. The conductivity of the Li{sub 2}SO{sub 4} containing glasses was found to be half an order higher than the base glass. The electrical conductivity was interpreted from the point of view of glass structure which suggests that an enhancement in conductivity is due to the incorporation of Li{sub 2}SO{sub 4} in the macromolecular network. The molar volume and glass transition temperature T{sub g} results are found to be in good correlation with conductivity results.

Satpute, N. S., E-mail: nspaighanp@gmail.com [Department of Applied Physics, Visvesvaraya National Institute of Technology, Nagpur-440010 (India); Deshpande, A. V. [Department of Applied Physics, Dr. Babasaheb Ambedkar College of Engineering and Research, Nagpur- 441110 (India)

2014-04-24T23:59:59.000Z

49

Metallic glass electronic structure peculiarities revealed by UHV STM/STS  

Science Journals Connector (OSTI)

We present the results of ultrahigh vacuum scanning tunneling microscopy/spectroscopy investigation of metallic glass surface. The topography and electronic structure of Ni63.5Nb36.5 have been studied. A great nu...

A. I. Oreshkin; N. S. Maslova; V. N. Mantsevich; S. I. Oreshkin…

2011-09-01T23:59:59.000Z

50

Glass Working, Use and Discard  

E-Print Network (OSTI)

Beck, Horace C. 1934 Glass before 1500 BC. Ancient Egypt7 - 21. Cooney, John 1960 Glass sculpture in ancient Egypt.Journal of Glass Studies 2, pp. 10 - 43. 1976 Glass.

Nicholson, Paul

2011-01-01T23:59:59.000Z

51

Chapter 14 - Glass Recycling  

Science Journals Connector (OSTI)

Abstract Glass has established itself as an essential material in our lives. The composition of glass depends on what it is used for, but the majority of glass in circulation is of the soda-lime–silicate type. It is a material that is eminently recyclable, in the sense that it merely needs to be remelted and reformed to produce another glass article. However, glass must be color-sorted and processed to remove contaminants to ensure it is compatible with the product being manufactured. The key benefit of recycling via remelting is the reduced energy demand. However, because differences in color composition can arise between recovered glass and manufacturing output, alternative outlets are also often necessary. This chapter examines both the recycling of glass back into glass manufacture and these alternatives.

Thomas D. Dyer

2014-01-01T23:59:59.000Z

52

Kevin Glass | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass kglass Primary tabs View(active tab) Track Kevin Glass Staff Member Title: Scientist Address: P.O. Box 999 K8-83 City: Richland State: WA Zip Code: 99352 Phone: (509)...

53

DRAFT Glass.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

FAST FACTS FAST FACTS Glass technology provides a versatile method for safely managing a variety of wastes SRNL has studied the behavior in glass of nearly every element in the Periodic Table Overview Converting waste materials into a stable glass form is a highly effective way of treating and disposing of many types of waste, including some hazardous and radioactive wastes. Vitrifi cation - the immobilization of a material in glass - is

54

MECS 2006- Glass  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Glass (NAICS 3272, 327993) Sector with Total Energy Input, October 2012 (MECS 2006)

55

Mixed polyanion glass cathodes: Iron phosphate vanadate glasses  

SciTech Connect

Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

2014-01-01T23:59:59.000Z

56

Structural origin of the nonlinear optical properties of lead niobium germanate film glasses  

SciTech Connect

The structural origin of the nonlinear optical susceptibility (/{chi}{sup (3)}/) of lead-niobium-germanate film glasses with large Nb{sub 2}O{sub 5} contents has been investigated. /{chi}{sup (3)}/ shows a strong enhancement with the Nb content in the films with /{chi}{sup (3)}/ values close to 2 x 10{sup -11} esu at 800 nm for a Nb content as high as 0.71. Boling-Glass-Owyoung and Lines' semiempirical models predict accurately the values of /{chi}{sup (3)}/ for transparent bulk glasses but not for film glasses. This discrepancy is related to the remarkable structural differences between them. Raman spectroscopy suggests the formation of a three-dimensional (3D) structure of [NbO{sub 6}] octahedra in the case of film glasses having large Nb contents, while X-ray photoelectron spectroscopy shows that a significant fraction of these units contain Nb{sup 4+} ions. The combination of a 3D structure of [NbO{sub 6}] with the presence of Nb{sup 4+} polarons and their migration through electron intervalence transfer is proposed as the origin of the observed enhancement of /{chi}{sup (3)}/ in the film glasses.

Munoz-Martin, D.; Ruiz de La Cruz, A.; Fernandez-Navarro, J. M.; Solis, J.; Gonzalo, J. [Laser Processing Group, Instituto de Optica (CSIC), Serrano 121, 28006 Madrid (Spain); Domingo, C. [Instituto de Estructura de la Materia (CSIC), Serrano 121, 28006 Madrid (Spain)

2011-07-15T23:59:59.000Z

57

Structural and optical properties of Sb{sub 2}S{sub 3} nanocrystals in glass  

SciTech Connect

In this work conventional solid state precipitation method is adopted to fabricate Sb{sub 2}S{sub 3} nanocrystals in glass. The glass composition is optimized for proper host glass matrix to grow antimony trisulphide semiconductor quantum dots. The dot size is modified by heat treatment of glass samples in the temperature range from 550°C to 700°C for various time durations. Structural studies are carried out by X-ray diffraction and transmission electron microscopy and nanoparticles with size ranges from 8 nm to 70 nm are obtained. Quantum dots so grown were further characterized by optical absorption spectroscopy and a blue shift is observed for absorption edge energy that conform the quantum confinement effect.

Mishra, Rakesh K., E-mail: mishrarake@gmail.com; Kashyap, Raman, E-mail: mishrarake@gmail.com; Vedeshwar, A. G., E-mail: mishrarake@gmail.com; Tandon, R. P., E-mail: mishrarake@gmail.com [Department of Physics and Astrophysics, University of Delhi, Delhi 1-10007 (India)

2014-04-24T23:59:59.000Z

58

Gamma Radiation Effects on Physical, Optical, and Structural Properties of Binary As-S glasses  

SciTech Connect

Gamma radiation induces changes in physical, optical, and structural properties in chalcogenide glasses., Previous research has focused on As{sub 2}S{sub 3} and families of glasses containing Ge. For the first time, we present composition and dose dependent data on the As-S binary glass series. Binary As{sub x}S{sub 100-x} (x = 30, 33, 36, 40, and 42) glasses were irradiated with gamma radiation using a {sup 60}Co source at 2.8 Gy/s to accumulated doses of 1, 2, 3, and 4 MGy. The irradiated samples were characterized at each dose level for density, refractive index, x-ray diffraction, and Raman spectrum. These results are compared to those of as-made and 1 year aged samples. We report an initial increase in density followed by a decrease as a function of dose that contradicts the expected compositional dependence of molar volume of these glasses. This unusual behavior is explained based on microvoid formation and nanoscale phase-separation induced by the irradiation in these glasses. XRD, Raman, and EPR data provide supporting evidence, underscoring the importance of optimally- or overly-constrained structures for stability under aging or irradiation.

Sundaram, S. K.; McCloy, John S.; Riley, Brian J.; Murphy, Mark K.; Qiao, Hong (Amy) [Amy; Windisch, Charles F.; Walter, Eric D.; Crum, Jarrod V.; Golovchak, Roman; Shpotyuk, O.

2012-03-01T23:59:59.000Z

59

Thermo-physical and structural studies of sodium zinc borovanadate glasses in the region of high concentration of modifier oxides  

SciTech Connect

Highlights: ? Highly modified sodium zinc borovanadate glasses. ? Structural model for borovanadate glasses. ? Network forming tendency of ZnO in borovanadate glasses. ? Fragility can be limited to NBO concentration in borovanadate glasses. -- Abstract: This paper reports investigation of Na{sub 2}O and ZnO modified borovanadate glasses in the highly modified regime of compositions. These glasses have been prepared by microwave route. Ultraviolet (UV) and visible, infrared (IR), Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR) and Electron Paramagnetic Resonance (EPR) spectroscopies have been used to characterize the speciation in the glasses. Together with the variation of properties such as molar volume and glass transition temperatures, spectroscopic data indicate that at high levels of modification, ZnO tends to behave like network former. It is proposed that the observed variation of all the properties can be reasonably well understood with a structural model. The model considers that the modification and speciation in glasses are strongly determined by the hierarchy of group electronegativities. Further, it is proposed that the width of the transitions of glasses obtained under same condition reflects the fragility of the glasses. An empirical expression has been suggested to quantify fragility on the basis of width of the transition regions.

Chethana, B.K. [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012 (India)] [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012 (India); Reddy, C. Narayana [Maharani's Science College for Women, Bangalore 560 001 (India)] [Maharani's Science College for Women, Bangalore 560 001 (India); Rao, K.J., E-mail: kalyajrao@yahoo.co.in [Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012 (India)

2012-07-15T23:59:59.000Z

60

Fabrication of microfluidics structures on different glasses by simplified imprinting technique  

Science Journals Connector (OSTI)

Imprinting technique is an efficient method for fabricating microstructures for microfluidics and lab-on-chip applications. However such technique is not commonly used for glass based microstructures fabrication. In this study, microstructures were transferred completely and successfully from a nickel alloy stamp to different glasses such as sodalime glass, Pyrex glass, SGBN glass and magneto optical glasses, using imprinting technique. Furthermore, the traditional vacuum hot press for imprinting was replaced with the conventional electric furnace which increases the cost efficiency and simplicity greatly. Using specific mold in the conventional furnace, the mass production of microstructured glass chips can be realized.

Qiuping Chen; Qiuling Chen; Gabriele Maccioni

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The perturbative structure of spin glass field theory  

E-Print Network (OSTI)

Cubic replicated field theory is used to study the glassy phase of the short-range Ising spin glass just below the transition temperature, and for systems above, at, and slightly below the upper critical dimension six. The order parameter function is computed up to two-loop order. There are two, well-separated bands in the mass spectrum, just as in mean field theory. The small mass band acts as an infrared cutoff, whereas contributions from the large mass region can be computed perturbatively (d>6), or interpreted by the epsilon-expansion around the critical fixed point (d=6-epsilon). The one-loop calculation of the (momentum-dependent) longitudinal mass, and the whole replicon sector is also presented. The innocuous behavior of the replicon masses while crossing the upper critical dimension shows that the ultrametric replica symmetry broken phase remains stable below six dimensions.

Tamás Temesvári

2013-12-27T23:59:59.000Z

62

Structural Signature of Plastic Deformation in Metallic Glasses H. L. Peng,1,2  

E-Print Network (OSTI)

Structural Signature of Plastic Deformation in Metallic Glasses H. L. Peng,1,2 M. Z. Li,2,* and W the degree of local fivefold symmetry (LFFS) as the structural indicator to predict plastic deformation of local structures and find that the plastic events prefer to be initiated in regions with a lower degree

Wang, Wei Hua

63

GlassMelt&Sealing  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Melting and Sealing Glass Melting and Sealing Manufacturing Technologies The Manufacturing Science & Technology Center performs process development of glass and glass-ceramic-to-metal seals. Small batches of specialty glass can be melted from reagent grade oxide powders. Glass and glass-ceramic-to-metal seals are made in microprocessor controlled inert atmospheres and are checked for her- meticity after sealing. Sandia's extensive properties database of low melting solder glasses is used to aid in material and processing decisions when making glass-to-glass, ceramic-to-ceramic, and glass-to-ceramic seals. These seals are typically done in air at much lower tem- peratures than glass and glass-to-ceramic seals. Capabilities * Interface with designers and vendors to assure that the most appropriate materi-

64

Natural analogues of nuclear waste glass corrosion.  

SciTech Connect

This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

1999-01-06T23:59:59.000Z

65

Nonequilibrium viscosity of glass  

Science Journals Connector (OSTI)

Since glass is a nonequilibrium material, its properties depend on both composition and thermal history. While most prior studies have focused on equilibrium liquid viscosity, an accurate description of nonequilibrium viscosity is essential for understanding the low temperature dynamics of glass. Departure from equilibrium occurs as a glass-forming system is cooled through the glass transition range. The glass transition involves a continuous breakdown of ergodicity as the system gradually becomes trapped in a subset of the available configurational phase space. At very low temperatures a glass is perfectly nonergodic (or “isostructural”), and the viscosity is described well by an Arrhenius form. However, the behavior of viscosity during the glass transition range itself is not yet understood. In this paper, we address the problem of glass viscosity using the enthalpy landscape model of Mauro and Loucks [Phys. Rev. B 76, 174202 (2007)] for selenium, an elemental glass former. To study a wide range of thermal histories, we compute nonequilibrium viscosity with cooling rates from 10?12 to 1012?K/s. Based on these detailed landscape calculations, we propose a simplified phenomenological model capturing the essential physics of glass viscosity. The phenomenological model incorporates an ergodicity parameter that accounts for the continuous breakdown of ergodicity at the glass transition. We show a direct relationship between the nonequilibrium viscosity parameters and the fragility of the supercooled liquid. The nonequilibrium viscosity model is validated against experimental measurements of Corning EAGLE XG™ glass. The measurements are performed using a specially designed beam-bending apparatus capable of accurate nonequilibrium viscosity measurements up to 1016?Pa?s. Using a common set of parameters, the phenomenological model provides an accurate description of EAGLE XG™ viscosity over the full range of measured temperatures and fictive temperatures.

John C. Mauro; Douglas C. Allan; Marcel Potuzak

2009-09-30T23:59:59.000Z

66

Diamond turning of glass  

SciTech Connect

A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

Blackley, W.S.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

67

Viscosity Measurements with Glass  

Science Journals Connector (OSTI)

1 May 1925 research-article Viscosity Measurements with Glass Vaughan H. Stott Edith Irvine D. Turner The Royal Society is collaborating with JSTOR to digitize, preserve...

1925-01-01T23:59:59.000Z

68

Richard Serra - Philip Glass.  

E-Print Network (OSTI)

??In dieser Arbeit soll den Gemeinsamkeiten im Werk von Richard Serra und Philip Glass nachgegangen werden. Ausgehend von der Analyse von Serras Arbeiten werden die… (more)

Vogl, Christiane

2008-01-01T23:59:59.000Z

69

Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors  

E-Print Network (OSTI)

300-500°C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

De Jonghe, Lutgard C.

2010-01-01T23:59:59.000Z

70

ITP Glass: Glass Industry Technology Roadmap; April 2002  

Energy.gov (U.S. Department of Energy (DOE))

Glass is a unique material that has been produced for thousands of years. The glass industry's products are an integral part of the American economy and everyday life. Glass products are used in food and beverage packaging, lighting, communications, etc.

71

Cultivation of Mycoplasmas on Glass  

Science Journals Connector (OSTI)

...Immunology Cultivation of Mycoplasmas on Glass R. H. Purcell J. R. Valdesuso W. L...human origin were successfully cultivated on glass. Complement-fixing (CF) antigens prepared from glass-adherent mycoplasmas were potent, specific...

R. H. Purcell; J. R. Valdesuso; W. L. Cline; W. D. James; R. M. Chanock

1971-02-01T23:59:59.000Z

72

Glass-Making  

Science Journals Connector (OSTI)

... director of Messrs. Pilkington Brothers, Ltd., on “The Making of a Sheet of Glass”. Major Weeks first gave a brief outline of some fundamental scientific considerations, with ... the raw materials are introduced at one end of a continuous furnace and the molten glass withdrawn at the other. The various processes necessary for the manufacture of sheet and ...

1933-12-16T23:59:59.000Z

73

The Glass Research Association  

Science Journals Connector (OSTI)

... widely known that among the industries which have been profoundly influenced by the war the glass and glassware industry of the United Kingdom occupies a foremost place. Not only have ... certain special sections of this industry, previously non-existent in the country, to supply glass and glassware, ...

EDWARD MEIGH

1919-11-13T23:59:59.000Z

74

Glass for Optical Purposes  

Science Journals Connector (OSTI)

... THE importance of an adequate supply of optical glass of all the principal types cannot be overestimated. The improvement of the microscope has ... improvement of the microscope has been and is still retarded for the want of suitable glasses, the construction of large telescopes is limited by the capacity of the glassmaker to ...

S. D. CHALMERS

1914-10-01T23:59:59.000Z

75

Glass for Reflectors  

Science Journals Connector (OSTI)

... "for the 4-foot disc of glass for the Paris reflector, in place of that which has so recently resulted in ... in place of that which has so recently resulted in failure, the St. Gobain Glass Company require twelve months' time to perfect (although, be it remembered, the quality ...

HENRY BESSEMER

1878-01-24T23:59:59.000Z

76

Decorative Glass Processes  

Science Journals Connector (OSTI)

... of a number of processes employed for the purpose of producing architectural decorative work in glass. Beginning with an account of the various kinds of ... . Beginning with an account of the various kinds of glass available for such work, and indulging in a retrospect of ...

W. R.

1909-01-21T23:59:59.000Z

77

Notes on Glass1  

Science Journals Connector (OSTI)

... A CERTAIN amount of experimental work on glass-ware of various kinds has been carried out recently at the National Physical Laboratory, ... known some of the results. Chemical investigations have for some years been dependent on German glass; the publication of the analyses and of test results may, it is hoped, ...

1915-03-18T23:59:59.000Z

78

Monte Carlo Simulation of Isopentane Glass  

Science Journals Connector (OSTI)

...research-article Monte Carlo Simulation of Isopentane Glass S. Yashonath C. N. R. Rao Monte Carlo...quenching the liquid, we have obtained the glass-transition temperature from the temperature...distribution functions suggest a structure of the glass primarily influenced by geometrical factors...

1985-01-01T23:59:59.000Z

79

Sol-GelGlasses  

NLE Websites -- All DOE Office Websites (Extended Search)

Sol-Gel Glasses Sol-Gel Glasses Manufacturing Technologies The Manufacturing Science & Technology Center conducts process development and scale-up of ceramic and glass materials prepared by the sol- gel process. Sol-gel processing uses solutions prepared at low temperature rather than high temperature powder processing to make materi- als with controlled properties. A precursor sol-gel solution (sol) is either poured into a mold and allowed to gel or is diluted and applied to a sub- strate by spinning, dipping, spraying, elec- trophoresis, inkjet printing or roll coating. Controlled drying of the wet gel results in either a ceramic or glass bulk part or a thin film on a glass, plastic, ceramic or metal substrate. Sol-gel derived materials have diverse applications in optics, electronics, energy, space, sensors and

80

Glass: Recent Research and Developments  

Science Journals Connector (OSTI)

... THE systematic study of glass and the subject of ... and the subject of glass technology is a field with which the University of Sheffield is particularly associated, Sheffield ...

1956-10-20T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Polyamorphism in a Metallic Glass | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

2000 | 1998 | Subscribe to APS Science Highlights rss feed Polyamorphism in a Metallic Glass MARCH 14, 2007 Bookmark and Share Structural modeling of the metallic glass: (a) A...

82

Aligned Crystalline Semiconducting Film On A Glass Substrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aligned Crystalline Semiconducting Film On A Glass Substrate Aligned Crystalline Semiconducting Film On A Glass Substrate And Method Of Making A semiconducting structure having a...

83

Fracture mechanics of cellular glass  

SciTech Connect

Cellular glasses are prime candidate materials for the structural substrate of mirrored glass for solar concentrator reflecting panels. These materials are brittle, however, and susceptible to mechanical failure from slow crack growth caused by a stress corrosion mechanism. The results are detailed of one part of a program established to develop improved cellular glasses and to characterize the behavior of these and commercially available materials. Commercial and developmental cellular glasses were tested and analyzed using standard testing techniques and models developed from linear fracture mechanics. Two models describing the fracture behavior of these materials are developed. Slow crack growth behavior in cellular glass was found to be more complex than that encountered in dense glasses or ceramics. The crack velocity was found to be strongly dependent upon water vapor transport to the tip of the moving crack. The existence of a static fatigue limit was not conclusively established, however, it is speculated that slow crack growth behavior in Region I may be slower, by orders of magnitude, than that found in dense glasses.

Zwissler, J.G.; Adams, M.A.

1981-02-01T23:59:59.000Z

84

Structure and formation mechanism of six-fold coordinated silicon in phosphosilicate glasses  

SciTech Connect

The local structure of sixfold oxygen coordinated silicon ({sup [6]}Si) in sodium phosphosilicate glasses has been investigated using MAS NMR spectroscopy and ab initio quantum-chemical techniques. It has been demonstrated that {sup [6]}Si is interconnected by six PO{sub 4} tetrahedral units by sharing only their corners, forming a nearly regular [SiO{sub 6/2}]{sup 2-} octahedral site. Alkali cations behave as charge compensators of the doubly charged {sup [6]}Si species and hence play an indispensable role in stabilizing the peculiar octahedral coordination in the glasses.

Miyabe, D.; Yoko, T. [Amorphous Materials Laboratory, Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Takahashi, M.; Tokuda, Y. [Amorphous Materials Laboratory, Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); PRESTO, Japan Science and Technology Agency, Kawaguchi, Saitama 332-0012 (Japan); Uchino, T. [Department of Chemistry, Faculty of Science, Kobe University, Nada, Kobe 657-8501 (Japan)

2005-05-01T23:59:59.000Z

85

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network (OSTI)

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Categorization and Decision Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Programming, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D

Maddox, W. Todd

86

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network (OSTI)

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Designing and constructing, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D., Chotibut, T

Maddox, W. Todd

87

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network (OSTI)

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Texas at Austin Austin, TX 78712 (512) 232-2883 e-mail: glass@mail.utexas.edu EDUCATION 2006 ­ Cognitive include: Designing and constructing experiments, statistical #12;Glass, Brian 2 analysis, manuscript

Maddox, W. Todd

88

Super ionic conductive glass  

DOE Patents (OSTI)

An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

Susman, Sherman (Park Forest, IL); Volin, Kenneth J. (Fort Collins, CO)

1984-01-01T23:59:59.000Z

89

Metallic glass composition  

DOE Patents (OSTI)

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

90

Structure of Cu64.5Zr35.5 Metallic glass by reverse Monte Carlo simulations  

SciTech Connect

Reverse Monte Carlo simulations (RMC) have been widely used to generate three dimensional (3D) atomistic models for glass systems. To examine the reliability of the method for metallic glass, we use RMC to predict the atomic configurations of a “known” structure from molecular dynamics (MD) simulations, and then compare the structure obtained from the RMC with the target structure from MD. We show that when the structure factors and partial pair correlation functions from the MD simulations are used as inputs for RMC simulations, the 3D atomistic structure of the glass obtained from the RMC gives the short- and medium-range order in good agreement with those from the target structure by the MD simulation. These results suggest that 3D atomistic structure model of the metallic glass alloys can be reasonably well reproduced by RMC method with a proper choice of input constraints.

Fang, Xikui W. [Ames Laboratory; Huang, Li [Ames Laboratory; Wang, Cai-Zhuang [Ames Laboratory; Ho, Kai-Ming [Ames Laboratory; Ding, Z. J. [University of Science and Technology of China

2014-02-07T23:59:59.000Z

91

DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION  

SciTech Connect

DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point that the test apparatus had to be disassembled to dislodge the plugs created in the system.

Adamson, D; Bradley Pickenheim, B

2008-11-24T23:59:59.000Z

92

Molecular dynamics of shock-wave induced structural changes in silica glasses  

Science Journals Connector (OSTI)

We seek to model the shock wave induced structural changes in silicate glass at the atomic scale. We use both direct shock propagation with nonequilibrium molecular dynamics (NEMD) and bulk simulations in the Hugoniot ensemble to characterize the structure and topology of the shocked glass. Despite the lack of long-range interactions in our model, the close agreement between our structures and those obtained by experimental and simulation studies alike underlines the importance of the role played by first neighbor interactions on the structure of silicate glass. The results obtained from this study show that, in agreement with experimental work, the structure and topology of the shock-induced densified phase is unique in its structure as can be revealed by medium-range order measurements. The modifications include a reduction of the average tetrahedra size and an increase in the proportion of 3–4 and 8–10 membered Si-rings. Application of a Hugoniostat method based on constraint dynamics shows near-perfect agreement with the NEMD results. Besides validating the former method, this opens the prospect of studying shock-induced effects at a fraction of the cost required to run large scale shock simulations while using much more complicated potentials and setups.

F. Barmes; L. Soulard; M. Mareschal

2006-06-16T23:59:59.000Z

93

Glasses for solar energy conversion systems  

Science Journals Connector (OSTI)

Solar technologies are projected to increase tremendously over the next 10 years. Glasses are playing an important role as transparent materials of photovoltaic (PV) cells and concentrating solar power (CSP) systems. Glasses are materials of short energy payback time and environmental compatibility suitable for sustainable energy concepts. The paper reviews recent solar applications. Surface structuring and coating of glasses are shown to improve energy efficiency for solar conversion systems substantially. Encapsulated glass-to-glass PV modules and solar photocatalytic glass surfaces are identified as elements of a green architecture combining renewable power generating and destruction of air pollutants of urban environments. Emerging solar technologies for power generation, including transparent PV modules, solar chimney and thermoelectric systems may become significant areas of future solar glass applications.

J. Deubener; G. Helsch; A. Moiseev; H. Bornhöft

2009-01-01T23:59:59.000Z

94

Synthesis and structural studies of multi-component strontium zinc silicate glass-ceramics  

SciTech Connect

Glass having composition 40SrO-10ZnO-40SiO{sub 2}-2B{sub 2}O{sub 3}-2Al{sub 2}O{sub 3}-2TiO{sub 2}-2Cr{sub 2}O{sub 3}-2Y{sub 2}O{sub 3}, (mol %) was prepared by melt-quench technique and converted into glass-ceramics by subjecting it to varying heat treatments. Thermal properties were measured by thermo-mechanical analyzer and differential thermal analyzer. The XRD revealed that initially Sr{sub 2}ZnSi{sub 2}O{sub 7} phase at lower temperature and later SrSiO{sub 3}/Sr{sub 3}Si{sub 3}O{sub 9} phase crystallized. The structural elucidation by Raman spectroscopy shows the presence of mainly Q{sup 1} structural units along with Q{sup 2} and Q{sup 0} units in the base glass. Raman spectra revealed that during crystallization initially crystalline phase having Q{sup 1} structural units (corresponding to Sr{sub 2}ZnSi{sub 2}O{sub 7} phase) are formed and later crystalline phase having Q{sup 2} structural units with 3 member ring type structure crystallizes. Thus, Raman spectroscopy and XRD together confirm that in early stage of crystallization, Sr{sub 2}ZnSi{sub 2}O{sub 7} phase and later Sr{sub 3}Si{sub 3}O{sub 9} phase formed in the glass-ceramics.

Tiwari, Babita [Technical Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Pandey, M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Kothiyal, G. P. [Glass and Advanced Ceramics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India); Gadkari, S. C.

2013-02-05T23:59:59.000Z

95

Cardinal Glass Industries | Open Energy Information  

Open Energy Info (EERE)

Cardinal Glass Industries Jump to: navigation, search Name: Cardinal Glass Industries Place: Eden Prairie, Minnesota Zip: 55344 Product: Minnesota-based glass products maker. The...

96

Glass blowing on a wafer level  

E-Print Network (OSTI)

E. Shelby, Introduction to Glass Science and Technology. :Properties of Corning Glasses [Online]. Available: http://1981. [15] R. H. Doremus, Glass Science. New York: Wiley,

Eklund, E. Jesper; Shkel, Andrei M.

2007-01-01T23:59:59.000Z

97

Glass Transition in Confined Geometry  

E-Print Network (OSTI)

Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting cases and requires as input solely the equilibrium density profile and the structure factors of the fluid in confinement. We evaluate the phase diagram as a function of the distance of the plates for the case of a hard sphere fluid and obtain an oscillatory behavior of the glass transtion line as a result of the structural changes related to layering.

Simon Lang; Vitalie Botan; Martin Oettel; David Hajnal; Thomas Franosch; Rolf Schilling

2010-08-23T23:59:59.000Z

98

The Quasi-Static Structure of Oxide Glasses  

Science Journals Connector (OSTI)

The explanation of the physical and chemical properties of amorphous materials requires knowledge of their composition, thermodynamic history, and structure. Whereas, for example, only structural units in the ...

Christian Schultz-Münzenberg…

1999-01-01T23:59:59.000Z

99

Investigation of a chalcohalide glass optical waveguide structure fabricated by dual-energy carbon-ion implantation  

Science Journals Connector (OSTI)

A planar waveguide structure in a chalcohalide glass was fabricated by dual-energy C ion implantation with energies of 5.5 and 6.0 MeV at fluences of 7.0×1014 and...

Yu, Xiao-Fei; Liu, Tao; Zhang, Lian; Zhou, Yu-Fan; Wang, Tie-Jun; Wang, Xue-Lin

2014-01-01T23:59:59.000Z

100

A Topological Glass  

E-Print Network (OSTI)

We propose and study a model with glassy behavior. The state space of the model is given by all triangulations of a sphere with $n$ nodes, half of which are red and half are blue. Red nodes want to have 5 neighbors while blue ones want 7. Energies of nodes with different numbers of neighbors are supposed to be positive. The dynamics is that of flipping the diagonal of two adjacent triangles, with a temperature dependent probability. We show that this system has an approach to a steady state which is exponentially slow, and show that the stationary state is unordered. We also study the local energy landscape and show that it has the hierarchical structure known from spin glasses. Finally, we show that the evolution can be described as that of a rarefied gas with spontaneous generation of particles and annihilating collisions.

Jean-Pierre Eckmann

2007-04-07T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

HLW Glass Waste Loadings  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HLW HLW Glass Waste Loadings Ian L. Pegg Vitreous State Laboratory The Catholic University of America Washington, DC Overview Overview  Vitrification - general background  Joule heated ceramic melter (JHCM) technology  Factors affecting waste loadings  Waste loading requirements and projections  WTP DWPF  DWPF  Yucca Mountain License Application requirements on waste loading  Summary Vitrification  Immobilization of waste by conversion into a glass  Internationally accepted treatment for HLW  Why glass?  Amorphous material - able to incorporate a wide spectrum of elements over wide ranges of composition; resistant to radiation damage  Long-term durability - natural analogs Relatively simple process - amenable to nuclearization at large  Relatively simple process - amenable to nuclearization at large scale  There

102

Reactive cluster model of metallic glasses  

SciTech Connect

Though discovered more than a half century ago metallic glasses remain a scientific enigma. Unlike crystalline metals, characterized by short, medium, and long-range order, in metallic glasses short and medium-range order persist, though long-range order is absent. This fact has prompted research to develop structural descriptions of metallic glasses. Among these are cluster-based models that attribute amorphous structure to the existence of clusters that are incommensurate with crystalline periodicity. Not addressed, however, are the chemical factors stabilizing these clusters and promoting their interconnections. We have found that glass formers are characterized by a rich cluster chemistry that above the glass transformation temperature promotes exchange as well as static and vibronic sharing of atoms between clusters. The vibronic mechanism induces correlated motions between neighboring clusters and we hypothesize that the distance over which these motions are correlated mediates metallic glass stability and influences critical cooling rates.

Jones, Travis E. [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States) [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States); School of Physics, The University of Sydney, Sydney, New South Wales 2006 (Australia); Miorelli, Jonathan; Eberhart, Mark E. [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States)] [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States)

2014-02-28T23:59:59.000Z

103

Development of an energy-saving glass using two-dimensional periodic nano-structures  

Science Journals Connector (OSTI)

Abstract A new type of energy-saving glass, Ag inlaid with SiO2 nano-structures (Inlay SiO2), is numerically developed here to offer modern buildings a passive but promising way of saving power under sunlight. The profile of glass is identified after optimizing optical responses using the genetic algorithm and a fitness function. Wavelength-selective reflectance (R) and transmittance (T) are demonstrated with validated programs based on the rigorous coupled-wave analysis algorithm. The high T and low R in the visible range not only saves energy for lighting but diminishes reflected and stray light. The low T and high R in the near-infrared reduce the cost for air-conditioning. Besides the cost can be further reduced, the superiority of this glass over current commercially available products includes the material commonness, light weight, and freedom from adhesion as well as oxidation. The fabrication tolerance of each dimension is further investigated to determine the key one. Other structure configurations are also approached to explore possibilities of alternates.

Chih-Ling Huang; Chi-Chun Ho; Yu-Bin Chen

2014-01-01T23:59:59.000Z

104

Crystalline fragments in glasses  

Science Journals Connector (OSTI)

The nature of tetrahedral molecular fragments is investigated in SiSe2 glasses using the molecular-dynamics method. The glass consists of both edge-sharing (ES) and corner-sharing tetrahedra. The ES tetrahedra are the building blocks of chain-like-molecular fragments. The two-edge-sharing tetrahedra are the nucleus, and corner-sharing configurations provide connecting hinges between fragments. Statistics of rings and fragments reveals that threefold and eightfold rings are most abundant, chainlike fragments that are typically 10–15 Å long occur mostly in eightfold rings, and the longest fragments occur in elevenfold rings.

Giomal A. Antonio; Rajiv K. Kalia; Aiichiro Nakano; Priya Vashishta

1992-04-01T23:59:59.000Z

105

Leaching of Nuclear Waste Glasses  

Science Journals Connector (OSTI)

Resistance to aqueous corrosion is the most important requirement of glasses designed to immobilize high level radioactive wastes. Obtaining a highly durable nuclear waste glass is complicated by the requirement ...

L. L. Hench

1985-01-01T23:59:59.000Z

106

Borosilicate Microporous Glasses for Reverse Osmosis  

Science Journals Connector (OSTI)

The characteristics of microporous borosilicate glasses are described. Glasses with an optimum pore distribution are recommended for production and application.

S. L. Zakharov

2004-05-01T23:59:59.000Z

107

The quantum Biroli-Mézard model: glass transition and superfluidity in a quantum lattice glass model  

E-Print Network (OSTI)

We study the quantum version of a lattice model whose classical counterpart captures the physics of structural glasses. We discuss the role of quantum fluctuations in such systems and in particular their interplay with the amorphous order developed in the glass phase. We show that quantum fluctuations might facilitate the formation of the glass at low enough temperature. We also show that the glass transition becomes a first-order transition between a superfluid and an insulating glass at very low temperature, and is therefore accompanied by phase coexistence between superfluid and glassy regions.

Laura Foini; Guilhem Semerjian; Francesco Zamponi

2010-11-29T23:59:59.000Z

108

Sources of Weakness in Glass  

Science Journals Connector (OSTI)

...October 1964 research-article Sources of Weakness in Glass C. Gurney The theoretical strength of glass is of the order of 2 to 5 MLb./in.$^2$ At room temperature, common glasses with undamaged surfaces give breaking stresses of about...

1964-01-01T23:59:59.000Z

109

Laboratory Waste Disposal HAZARDOUS GLASS  

E-Print Network (OSTI)

Laboratory Waste Disposal HAZARDOUS GLASS Items that could cut or puncture skin or trash- can without any treatment. Hazardous Glass and Plastic: Items that can puncture, cut or scratch if disposed of in normal trash containers. Pasteur pipettes Other pipettes and tips (glass or plastic) Slides and cover

Sheridan, Jennifer

110

The Color Glass Condensate  

E-Print Network (OSTI)

We provide a broad overview of the theoretical status and phenomenological applications of the Color Glass Condensate effective field theory describing universal properties of saturated gluons in hadron wavefunctions that are extracted from deeply inelastic scattering and hadron-hadron collision experiments at high energies.

F. Gelis; E. Iancu; J. Jalilian-Marian; R. Venugopalan

2010-02-01T23:59:59.000Z

111

Structure of GeO2 glass at pressures up to 8.6 GPa  

Science Journals Connector (OSTI)

The structure of GeO2 glass at pressures extending from ambient to 8.6(5) GPa was measured at ?25?°C by using in situ neutron diffraction. The results show a gradual change in the intermediate range order with increasing density as manifested by an increase in position and reduction in height of the first sharp diffraction peak in the total structure factor. By contrast, the local ordering, as characterized by the Ge-O bond length and coordination number, remains constant for the pressure range from ambient to ?5?GPa. As the pressure is increased further to 8.6(5) GPa, however, a steady increase from 4.0(1) to 4.9(1) is observed in the Ge-O coordination number as the corresponding distance increases from 1.73(2) to 1.77(2)?Å. The results are therefore consistent with the operation of two densification mechanisms, the low-pressure one associated with squeezing the open network of corner-linked tetrahedral motifs and the high-pressure one associated with a transformation of those motifs. There is no evidence in support of an abrupt transformation of the network structure over the investigated pressure range. The structure of permanently densified GeO2 glass was also investigated by high-energy x-ray diffraction. The results show that there is a threshold pressure at ?5?GPa below which the structure of a recovered glass is similar to that of the high-pressure material. Above the threshold pressure there is, however, a reorganization of both the local and intermediate range ordering once the pressure is released and the Ge-O coordination number returns to 4.

James W. E. Drewitt; Philip S. Salmon; Adrian C. Barnes; Stefan Klotz; Henry E. Fischer; Wilson A. Crichton

2010-01-11T23:59:59.000Z

112

Cooling rate and size effects on the medium-range structure of multicomponent oxide glasses simulated by molecular dynamics  

SciTech Connect

A set of molecular dynamics simulations were performed to investigate the effect of cooling rate and system size on the medium-range structure of melt-derived multicomponent silicate glasses, represented by the quaternary 45S5 Bioglass composition. Given the significant impact of the glass degradation on applications of these materials in biomedicine and nuclear waste disposal, bulk structural features which directly affect the glass dissolution process are of particular interest. Connectivity of the silicate matrix, ion clustering and nanosegregation, distribution of ring and chain structural patterns represent critical features in this context, which can be directly extracted from the models. A key issue is represented by the effect of the computational approach on the corresponding glass models, especially in light of recent indications questioning the suitability of conventional MD approaches (that is, involving melt-and-quench of systems containing ?10{sup 3} atoms at cooling rates of 5-10 K/ps) when applied to model these glasses. The analysis presented here compares MD models obtained with conventional and nonconventional cooling rates and system sizes, highlighting the trend and range of convergence of specific structural features in the medium range. The present results show that time-consuming computational approaches involving much lower cooling rates and/or significantly larger system sizes are in most cases not necessary in order to obtain a reliable description of the medium-range structure of multicomponent glasses. We identify the convergence range for specific properties and use them to discuss models of several glass compositions for which a possible influence of cooling-rate or size effects had been previously hypothesized. The trends highlighted here represent an important reference to obtain reliable models of multicomponent glasses and extract converged medium-range structural features which affect the glass degradation and thus their application in different fields. In addition, as a first application of the present findings, the fully converged structure of the 45S5 glass was further analyzed to shed new light on several dissolution-related features whose interpretation has been rather controversial in the past.

Tilocca, Antonio [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom)] [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom)

2013-09-21T23:59:59.000Z

113

Production of glass or glass-ceramic to metal seals with the application of pressure  

DOE Patents (OSTI)

In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

Kelly, Michael D. (West Alexandria, OH); Kramer, Daniel P. (Dayton, OH)

1987-11-10T23:59:59.000Z

114

Production of glass or glass-ceramic to metal seals with the application of pressure  

DOE Patents (OSTI)

In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

Kelly, M.D.; Kramer, D.P.

1985-01-04T23:59:59.000Z

115

Crystallization in heat-treated fluorochlorozirconate glasses  

SciTech Connect

Crystallization phenomena of fluorochlorozirconate glasses were investigated by means of differential scanning calorimetry and inelastic neutron scattering. The precipitation of barium chloride nanoparticles from the glass matrix upon heat treatment was found to be suppressed when re-melting the glass with a reducing agent but not if the agent was present in the initial synthesis. Addition of small amounts of oxide to the predominantly fluoride melt was found to maintain the presence of nanoparticles but not to induce the predicted phase transition of the barium chloride nanoparticles from hexagonal to orthorhombic structure. Inelastic neutron scattering performed on an as-made glass and a heat-treated glass showed an increase in hardness , consistent with a more ordered structure.

Johnson, Jackie A. [University of Tennessee Space Institute; Weber, Rick [Materials Development, Inc., Evanston, IL; Kolesnikov, Alexander I [ORNL; SCHWEIZER, Stefan [Fraunhofer Center for Silicon Photovoltaics, 06120 Halle, Germany

2009-01-01T23:59:59.000Z

116

Analytical Plan for Roman Glasses  

SciTech Connect

Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent “experiment” that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

2011-01-01T23:59:59.000Z

117

Structural and thermal characterization of CaO-MgO-SiO2-P2O5-CaF2 glasses  

SciTech Connect

The paper presents the influence of varying CaO/MgO ratio on the structure and thermal properties of CaO-MgO-SiO2-P2O5-CaF2 glasses. A series of eight glass compositions in the glass forming region of diopside (CaMgSi2O6) - fluorapatite [Ca5(PO4)3F] - wollastonite (CaSiO3) ternary system have been designed and synthesized by varying diopside/wollastonite ratio in glasses. The as prepared melt-quenched glasses have been characterized for their structure by infrared spectroscopy (FTIR) and magic angle spinning (MAS)-nuclear magnetic resonance (NMR) spectroscopy. Silicon is predominantly present as Q2 (Si) species, while phosphorus tends to coordinate in orthophosphate environment in all the investigated glasses. The change in CaO/MgO ratio had an insignificant affect on the structure of glasses. The thermal sintering and crystallization parameters for the studied glasses have been obtained from differential thermal analysis (DTA) while crystalline phase fractions in the sintered glass-ceramics have been analyzed by X-ray diffraction adjoined with Rietveld refinement. Diopside, fluorapatite, wollastonite and pseudowollastonite have crystallized as the main crystalline phases in all the glass-ceramics with their content varying with respect to variation in CaO/MgO ratio in glasses. Scanning electron microscopy (SEM) has been used to shed light on the microstructure of glass-ceramics. The possible implications of structure and sintering behaviour of glasses on their bioactivity have been discussed.

Kansal, Ishu; Goel, Ashutosh; Tulyaganov, Dilshat U.; Rajagopal, Raghu R.; Ferreira, Jose M.

2012-08-01T23:59:59.000Z

118

ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007  

Energy.gov (U.S. Department of Energy (DOE))

A guide to determining places in the glass-making process where energy can be saved and means by which energy can be saved.

119

WINDOW 5 Glass Library Update  

NLE Websites -- All DOE Office Websites (Extended Search)

WINDOW 6 or 7 Glass Library Update WINDOW 6 or 7 Glass Library Update Last update:12/09/13 07:26 PM Automatic IGDB Update Feature in WINDOW 6 and 7 The latest versions of WINDOW 6 and 7 have an automatic IGDB database update function in the Glass Library. When you first open the program, it checks to see if there is an IGDB version later than what you already have installed, and will notify you if there is an update. Then you can download and install the IGDB database, and click on the Update IGDB button in the Glass Library in order to start the automatic update. For older versions of WINDOW 6 and 7 without the automatic IGDB update function bullet How to Check the Current WINDOW5 IGDB Version bullet Updating the Glass Library bullet Problem Updating the Glass Library bullet Discontinued Records or Reused NFRC IDs

120

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bioactive Glass Scaffolds for Bone Regeneration Bioactive Glass Scaffolds for Bone Regeneration Print Wednesday, 28 September 2011 00:00 Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

17 - Immobilisation of Radioactive Waste in Glass  

Science Journals Connector (OSTI)

Radionuclide immobilisation mechanisms are examined for vitreous wasteforms. Both borosilicate and phosphate glasses are described in detail, including the ability of cations to enter into the glass network structure. The role of various cations is considered, including boron, intermediates, and modifiers and elements difficult to immobilise. Selection rules for designing nuclear wasteform silicate glasses are outlined. Glass composite materials to immobilise glass-immiscible waste components are discussed. Both one- and two-stage vitrification technologies are described. An overview is given of the development of vitrification technology, including current operational data on radioactive waste vitrification facilities. Calcination processes are considered in detail, including typical properties of waste calcination products. Recent developments in vitrification are given, including descriptions of cold crucible induction-heated melters and in situ vitrification. Limitations caused by radionuclide volatility are examined. Acceptance criteria are given for vitreous wasteforms.

M.I. Ojovan; W.E. Lee

2014-01-01T23:59:59.000Z

122

The GLASS CHAIR Edited by Manuel Heitor  

E-Print Network (OSTI)

The GLASS CHAIR Edited by Manuel Heitor IST Press, 2000 #12;Collaborative Design of... The GLASS the glass chair, but also for the numerous discussions on glass production processes. And last · Carmo Valente Chapter 4. GLASS: BEAUTY WITH STRENGTH Sushil Kumar Mendiratta Chapter 5. The IDEA

Instituto de Sistemas e Robotica

123

Method for heating a glass sheet  

DOE Patents (OSTI)

A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed.

Boaz, Premakaran Tucker (Livonia, MI)

1998-01-01T23:59:59.000Z

124

Color Glass Condensate and Glasma  

E-Print Network (OSTI)

In this talk, I review the Color Glass Condensate theory of gluon saturation, and its application to the early stages of heavy ion collisions.

Francois Gelis

2010-09-01T23:59:59.000Z

125

Research and development of new ultraphosphate laser glasses  

SciTech Connect

Requirements for Zeus laser glass and HAP laser glass were small {sigma}, low water, low concentration quenching and high mechanical and thermal strength in the former and high {sigma}, low water, low concentration quenching and high mechanical, thermal shock resistance in the later. In order to get a high mechanical and thermal shock resistance, we introduced SiO{sub 2} into phosphate glass, because SiO{sub 2} gives a low expansion coefficient. In this report, we discuss the research and development of the laser glass. Chemical durability, water content, lasing properties, mechanical and thermo-mechanical properties, glass composition and glass structures are discussed.

Izumitani, T.; Toratani, H.; Matsukawa, T.; Kanamori, C.; Miyade, H.

1985-01-30T23:59:59.000Z

126

Glass rupture disk  

DOE Patents (OSTI)

A frangible rupture disk and mounting apparatus for use in blocking fluid flow, generally in a fluid conducting conduit such as a well casing, a well tubing string or other conduits within subterranean boreholes. The disk can also be utilized in above-surface pipes or tanks where temporary and controllable fluid blockage is required. The frangible rupture disk is made from a pre-stressed glass with controllable rupture properties wherein the strength distribution has a standard deviation less than approximately 5% from the mean strength. The frangible rupture disk has controllable operating pressures and rupture pressures.

Glass, S. Jill (Albuquerque, NM); Nicolaysen, Scott D. (Albuquerque, NM); Beauchamp, Edwin K. (Albuquerque, NM)

2002-01-01T23:59:59.000Z

127

Efficient Breach Theory Through the Looking Glass  

E-Print Network (OSTI)

in Wonderland and Through the Looking Glass (Signet 1960).Theory Through the Looking Glass such an award a put by theTheory Through the Looking Glass Consider also the hoary

Adler, Barry E.

2007-01-01T23:59:59.000Z

128

Immobilization of Chloroperoxidase on Aminopropyl-Glass  

Science Journals Connector (OSTI)

...Immobilization of Chloroperoxidase on Aminopropyl-Glass Tenshuk A. Kadima Michael A. Pickard...89362 was covalently bound to aminopropyl-glass by using a modification of an established method. Acid-washed glass was derivatized by using aminopropyltriethoxysilane...

Tenshuk A. Kadima; Michael A. Pickard

1990-11-01T23:59:59.000Z

129

Glass Fibre Reinforced Cement and Gypsum Products  

Science Journals Connector (OSTI)

6 October 1970 research-article Glass Fibre Reinforced Cement and Gypsum Products A. J. Majumdar Glass fibre reinforced cements and gypsum plaster...discontinuous and irregular. The dispersion of glass fibre in the matrix is not easy. When chopped...

1970-01-01T23:59:59.000Z

130

Rhenium solubility in borosilicate nuclear waste glass  

E-Print Network (OSTI)

Retention in Hanford LAW Glass - Phase 1 Final Report. VSL-rhenium in borosilicate waste glass as determined by X-rayfor NIST SRM 610–617 Glasses Following ISO Guidelines," 35[

McCloy, John S.

2014-01-01T23:59:59.000Z

131

Structural transformation in densified silica glass: A molecular-dynamics study  

Science Journals Connector (OSTI)

Pressure-induced structural transformation and the concomitant loss of intermediate-range order (IRO) in high-density SiO2 glass are investigated with the molecular-dynamics (MD) approach. The MD simulations cover a wide range of mass densities—from normal density (2.20 g/cm3) to the density corresponding to stishovite (4.28 g/cm3). This twofold increase in the density produces significant changes in the short-range order and intermediate-range order. As the density increases from 2.20 to 4.28 g/cm3, the Si-O bond length increases from 1.61 to 1.67 Å, the Si-O and O-O coordinations change from 4 to 5.8 and from 6 to 12, respectively, and the O-Si-O bond angle changes from 109° to 90°. These results provide firm evidence of structural transition from a corner-sharing Si(O1/2)4 tetrahedral network to a network of Si(O1/3)6 octahedra jointed at corners and edges. At normal density, the first sharp diffraction peak (FSDP) in the static structure factor S(q) is at 1.6 A?-1 whereas under pressure the height of the FSDP is considerably diminished and its position shifts to larger q values. At a density of 2.64 g/cm3, a peak in S(q) appears at 2.85 A?-1. The height of this peak grows as the density increases. All of these results are in agreement with the recent high-pressure x-ray measurements on SiO2 glass.

Wei Jin; Rajiv K. Kalia; Priya Vashishta; José P. Rino

1994-07-01T23:59:59.000Z

132

Refractory Glass Seals for SOFC  

SciTech Connect

One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

Chou, Y. S.; Stevenson, Jeffry W.

2011-07-01T23:59:59.000Z

133

Art and Form in Glass  

Science Journals Connector (OSTI)

... book. The new edition has been brought up to date, the historical section on glass manufacture now concludes with a brief reference to the float process first announced a year ... a year or so ago and the beautiful collection of photographs illustrating the use of glass in buildings has been changed considerably. Many of the photographs are of things which ...

R. W. DOUGLAS

1962-03-24T23:59:59.000Z

134

New Types of Optical Glass  

Science Journals Connector (OSTI)

... IN view of the interest shown in new optical glasses recently produced in Great Britain and in the United States, we wish to summarize ... probable lines of development. Advances in lens design have led to a demand for new glasses with optical properties different from those available hitherto as outlined in a recent paper by ...

W. M. HAMPTON; R. E. BASTICK; W. N. WHEAT

1944-03-04T23:59:59.000Z

135

Glass-making in England  

Science Journals Connector (OSTI)

... trouble to look through a catalogue of works in English dealing with the subject of glass will be struck with its poverty. For the most part, books on ... will be struck with its poverty. For the most part, books on glass have been written by collectors and admirers of ...

W. E. S. TURNER

1923-10-27T23:59:59.000Z

136

Formation of zirconium metallic glass  

Science Journals Connector (OSTI)

... Bulk metallic glasses are commonly produced by the rapid cooling of liquid alloys. They have emerged over ... a novel class of materials, with attractive properties and technological promise. The bulk metallic glasses so far produced contain three or more component elements. These complex compositions are necessary ...

Jianzhong Zhang; Yusheng Zhao

2004-07-15T23:59:59.000Z

137

Third International Congress on Glass  

Science Journals Connector (OSTI)

... THE Third International Congress on Glass was held in Venice during June 29-July 2, associated with the International Commission ... was held in Venice during June 29-July 2, associated with the International Commission on Glass, the annual meeting of which was held on July 3. 179 delegates attended from ...

1953-08-15T23:59:59.000Z

138

The Shock Wave Response of a Filled Glass  

Science Journals Connector (OSTI)

...research-article The Shock Wave Response of a Filled Glass N. K. Bourne J. C. F. Millett Z...relatively open structure, low density glasses such as borosilicate (pyrex) and soda-lime...addressed the response of highly filled lead glasses. This work presents the results of a...

1996-01-01T23:59:59.000Z

139

Rhenium solubility in borosilicate nuclear waste glass  

E-Print Network (OSTI)

Glasses Developed for Nuclear Waste Immobilization," 91[12],solubility in borosilicate nuclear waste glass Ashutoshfor the researchers in nuclear waste community around the

McCloy, John S.

2014-01-01T23:59:59.000Z

140

Nanophase Glass Ceramics for Capacitive Energy Storage.  

E-Print Network (OSTI)

??Glass ceramics are candidate dielectric materials for high energy storage capacitors. Since energy density depends primarily on dielectric permittivity and breakdown strength, glass ceramics with… (more)

Rangarajan, Badri

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Aluminoborosilicate Waste Glass Dissolution under Alkaline Conditions...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aluminoborosilicate Waste Glass Dissolution under Alkaline Conditions at 40°C: Implications for a Chemical Affinity-Based Aluminoborosilicate Waste Glass Dissolution under...

142

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Bioactive Glass Scaffolds for Bone Regeneration Print Wednesday, 28 September 2011 00:00 Natural materials are renowned for their...

143

Exploration and Modeling of Structural changes in Waste Glass Under Corrosion  

SciTech Connect

Vitrification is currently the world-wide treatment of choice for the disposition of high-level nuclear wastes. In glasses, radionuclides are atomistically bonded into the solid, resulting in a highly durable product, with borosilicate glasses exhibiting particularly excellent durability in water. Considering that waste glass is designed to retain the radionuclides within the waste form for long periods, it is important to understand the long-term stability of these materials when they react in the environment, especially in the presence of water. Based on a number of previous studies, there is general consensus regarding the mechanisms controlling the initial rate of nuclear waste glass dissolution. Agreement regarding the cause of the observed decrease in dissolution rate at extended times, however, has been elusive. Two general models have been proposed to explain this behavior, and it has been concluded that both concepts are valid and must be taken into account when considering the decrease in dissolution rate. Furthermore, other processes such as water diffusion, ion exchange, and precipitation of mineral phases onto the glass surface may occur in parallel with dissolution of the glass and can influence long-term performance. Our proposed research will address these issues through a combination of aqueous-phase dissolution/reaction experiments and probing of the resulting surface layers with state-of-the-art analytical methods. These methods include solid-state nuclear magnetic resonance (SSNMR) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). The resulting datasets will then be coupled with computational chemistry and reaction-rate modeling to address the most persistent uncertainties in the understanding of glass corrosion, which indeed have limited the performance of the best corrosion models to date. With an improved understanding of corrosion mechanisms, models can be developed and improved that, while still conservative, take advantage of the inherent durability of the waste form to enable secure repositories to be engineered with a much higher density of waste disposition. We propose the synthesis, corrosion, and characterization of two sets of glass samples— containing approximately 8 single-component oxides each—as models for corrosion studies of more complicated glass systems (which can contain in excess of 25 single-component ingredients). Powdered samples and millimeter- sized coupons of these simpler glasses will be corroded in solutions that begin at circumneutral pH, but are known to increase in alkalinity as corrosion proceeds and saturation in silica species is approached. Through carefully selected isotopic substitutions with nuclides that are readily detected with SSNMR and TOF-SIMS methods, we will be able to follow the diffusion of atoms into and out of the reacted surface layers of these glasses and provide new data for testing with existing reaction models. The models can then be further extended or updated to take our new data into account, allowing the existing long-term glass corrosion models to more accurately reflect the extraordinary durability of these systems. With improved models, a significant opportunity exists to better utilize the storage volume of any geologic repository.

Pantano, Carlos; Ryan, Joseph; Strachan, Denis

2013-11-10T23:59:59.000Z

144

Thermal Performance Impacts of Center-of-Glass Deflections in Installed Insulating Glazing Units  

E-Print Network (OSTI)

6] M. Bernier, Effects of Glass Plate Curvature on the U-Selkowitz, Research Needs: Glass Solar Reflectance and VinylAnalysis of Insulating Glass Units, Journal of Structural

Hart, Robert

2014-01-01T23:59:59.000Z

145

E-Print Network 3.0 - absorbent glass mat Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: Francisco, J. Magn. and Magn. Mat., 54-57, 6 (1986). 58. Long Range Ising Spin Glasses: Critical Behavior... Structure in Ising Spin Glasses" (with Matteo...

146

Critical review of glass performance modeling  

SciTech Connect

Borosilicate glass is to be used for permanent disposal of high-level nuclear waste in a geologic repository. Mechanistic chemical models are used to predict the rate at which radionuclides will be released from the glass under repository conditions. The most successful and useful of these models link reaction path geochemical modeling programs with a glass dissolution rate law that is consistent with transition state theory. These models have been used to simulate several types of short-term laboratory tests of glass dissolution and to predict the long-term performance of the glass in a repository. Although mechanistically based, the current models are limited by a lack of unambiguous experimental support for some of their assumptions. The most severe problem of this type is the lack of an existing validated mechanism that controls long-term glass dissolution rates. Current models can be improved by performing carefully designed experiments and using the experimental results to validate the rate-controlling mechanisms implicit in the models. These models should be supported with long-term experiments to be used for model validation. The mechanistic basis of the models should be explored by using modern molecular simulations such as molecular orbital and molecular dynamics to investigate both the glass structure and its dissolution process.

Bourcier, W.L. [Lawrence Livermore National Lab., CA (United States)

1994-07-01T23:59:59.000Z

147

Glass Ceramic Formulation Data Package  

SciTech Connect

A glass ceramic waste form is being developed for treatment of secondary waste streams generated by aqueous reprocessing of commercial used nuclear fuel (Crum et al. 2012b). The waste stream contains a mixture of transition metals, alkali, alkaline earths, and lanthanides, several of which exceed the solubility limits of a single phase borosilicate glass (Crum et al. 2009; Caurant et al. 2007). A multi-phase glass ceramic waste form allows incorporation of insoluble components of the waste by designed crystallization into durable heat tolerant phases. The glass ceramic formulation and processing targets the formation of the following three stable crystalline phases: (1) powellite (XMoO4) where X can be (Ca, Sr, Ba, and/or Ln), (2) oxyapatite Yx,Z(10-x)Si6O26 where Y is alkaline earth, Z is Ln, and (3) lanthanide borosilicate (Ln5BSi2O13). These three phases incorporate the waste components that are above the solubility limit of a single-phase borosilicate glass. The glass ceramic is designed to be a single phase melt, just like a borosilicate glass, and then crystallize upon slow cooling to form the targeted phases. The slow cooling schedule is based on the centerline cooling profile of a 2 foot diameter canister such as the Hanford High-Level Waste canister. Up to this point, crucible testing has been used for glass ceramic development, with cold crucible induction melter (CCIM) targeted as the ultimate processing technology for the waste form. Idaho National Laboratory (INL) will conduct a scaled CCIM test in FY2012 with a glass ceramic to demonstrate the processing behavior. This Data Package documents the laboratory studies of the glass ceramic composition to support the CCIM test. Pacific Northwest National Laboratory (PNNL) measured melt viscosity, electrical conductivity, and crystallization behavior upon cooling to identify a processing window (temperature range) for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form.

Crum, Jarrod V.; Rodriguez, Carmen P.; McCloy, John S.; Vienna, John D.; Chung, Chul-Woo

2012-06-17T23:59:59.000Z

148

THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED BY MO K-EDGE X-RAY ABSORPTION  

E-Print Network (OSTI)

THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED of molybdenum in model UK high level nuclear waste glasses was investigated by X-ray Absorption Spectroscopy (XAS). Molybdenum K-edge XAS data were acquired from several inactive simulant high level nuclear waste

Sheffield, University of

149

The effect of structural relaxation on SANS and its anisotropy in a metallic glass (*)  

E-Print Network (OSTI)

small-angle-neutron scattering (SANS) intensity from ribbons ofmetallic glasses [I]which we attributed baisse de l'intensité diffusée. Abstract. 2014 We report a large decrease in small-angle-neutron scattering (SANS) after relaxation- annealing below Tg in glassy Pd80Si12Ge8 ribbons. We had previously

Boyer, Edmond

150

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

151

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

152

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

153

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

154

ITP Glass: Glass Industry of the Future: Energy and Environmental...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

fuel oil is used in the glass industry (less than 2 percent of total energy). Natural gas is usually the fuel of choice as it is cleaner and in some cases, more cost-effective,...

155

Local structure around rare-earth ions in B{sub 2}O{sub 3} glass at high pressure  

SciTech Connect

Melt quenching of B{sub 2}O{sub 3} with less than 25 mol. % rare-earth oxide (RE{sub 2}O{sub 3}) at ambient pressure results in a milky white glass because of liquid-liquid phase separation into B{sub 2}O{sub 3} and RE{sub 2}O{sub 3}{center_dot}3B{sub 2}O phases. In contrast, we have found that melt quenching under GPa-order pressure realizes a transparent RE-doped B{sub 2}O{sub 3} glass. This study investigates the local structure around the RE ions in the B{sub 2}O{sub 3} glass prepared at 3 GPa using optical measurements and electron-spin-echo envelope modulation spectroscopy. It is shown that the RE-rich microparticles disappear and the RE ions are isolated from each other in a highly symmetric crystal field formed by triangular and tetrahedral boron units. This result is consistent with that extrapolated from the data for RE-doped sodium borate glasses.

Funabiki, Fuji [Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan)] [Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan); Matsuishi, Satoru [Research Center for Strategic Materials, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan)] [Research Center for Strategic Materials, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan); Hosono, Hideo [Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan) [Frontier Research Center, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan); Research Center for Strategic Materials, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan); Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503 (Japan)

2013-06-14T23:59:59.000Z

156

DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES  

SciTech Connect

Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

Jantzen, C.

2010-03-18T23:59:59.000Z

157

Microporous glasses for reverse osmosis  

Science Journals Connector (OSTI)

The preparation, heat-treatment and leaching of phase separable borosilicate glasses which are of interest as possible semipermeable membranes for reverse osmosis applications are described. It is shown that ... ...

P. W. McMillan; C. E. Matthews

1976-01-01T23:59:59.000Z

158

Viscosity Measurements in Molten Glass  

Science Journals Connector (OSTI)

The relations existing between viscosity determinations and the various stages of glass manufacture are pointed out and explained with reference to a typical viscosity?temperature curve. The rotation viscometer employed in making such determinations is described. Curves are shown for four representative types of glasses: a lead a lime a lead borosilicate and a hard borosilicate and the use to which such comparison curves may be put is indicated.

Howard R. Lillie

1932-01-01T23:59:59.000Z

159

Fabrication of glass microspheres with conducting surfaces  

DOE Patents (OSTI)

A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

Elsholz, William E. (Acampo, CA)

1984-01-01T23:59:59.000Z

160

Glass and glass-derivative seals for use in energy-efficient fuel cells and lamps  

SciTech Connect

For solid oxide fuel cells (SOFC), a series of 18 sealing glasses have been prepared and characterized. From the whole design space, several glasses were ''downselected'' and studied in detail to describe their behaviors in simulated fuel cell environments. One of the glasses was found to outperform all others, including the well-known G18 sealant developed at Pacific Northwest National Laboratory. The new glass composition showed lower bulk electrical conductivity, excellent sealing and wetting behavior when sealing under applied load, and qualitatively superior performance when exposed to wet hydrogen for 800 hours. Traditional melting was used to prepare all of the glasses that were studied in detail. The sol-gel approach was used to synthesize several compositions, but it was found that the glasses crystallized very rapidly during heating, precluding sealing. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. The body of fundamental data provides a platform for future developments for high temperature sealants, and the newly-developed glass compositions appear promising for large-scale testing. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria-alumina-silica system at various silica levels. Functional testing of one of the candidate sealants demonstrated that it performs well in current HID lighting applications. Further testing is required to evaluate its performance in next-generation lamps that operate at higher temperatures, but the baseline phase equilibria and crystallization behavior has been established for additional development. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase.

Scott Misture; Arun Varshineya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

2005-07-28T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Structure determination of Ag-Ge-S glasses using neutron diffraction  

Science Journals Connector (OSTI)

The structure of the superionic glass system (Ag2S)x(GeS2)1-x, for three compositions x=0.3, 0.4, 0.5, has been studied using neutron diffraction, and isotopic-substitution neutron-diffraction experiments have been performed on three silver isotope-substituted (107Ag,natAg,109Ag) samples of the composition (Ag2S)0.5(GeS2)0.5. The average short-range orderings of Ge-S, Ag-S, and Ge-Ag correlations were identified in the radial distribution functions for the isotopically substituted system of (Ag2S)0.5(GeS2)0.5. From the first and second differences in the three sets of isotopic-substitution neutron-diffraction data, the other three partial correlations (Ag-Ag, Ge-Ge, and S-S), were also identified. By examining unusually broad peaks in the Ag-Ag correlation function, it was concluded that the Ag-Ag distribution was rather homogeneous. We were also able to obtain further information by combining the first and second difference analyses, resulting in a structural model of a slightly elongated GeS4 tetrahedron with the local environment of Ag+ ions being threefold coordination by nonbridging sulphur ions. The medium-range order of the host framework was found to be a chainlike structure of linked corner-sharing GeS4 tetrahedra. Substantial changes in the first and second peaks in the distinct scattering functions i(Q) were found with composition and also with isotopic substitution. It was possible to explain the trends in the changes of the heights of these peaks in the structure factor by applying the void model for the first sharp diffraction peak. © 1996 The American Physical Society.

J. H. Lee; A. P. Owens; A. Pradel; A. C. Hannon; M. Ribes; S. R. Elliott

1996-08-01T23:59:59.000Z

162

The effect of regimes and methods of glass forming on the tin content in float glass  

Science Journals Connector (OSTI)

The dependence of the tin content in glass is derived as a function of the iron oxidecontent in the glass composition, regimes and methods of forming, ... The ways of reducing the tin content in glass in the cour...

V. I. Kondrashov; V. S. Bezlyudnaya; Yu. V. Zverev

163

Cooperative heterogeneous facilitation: Multiple glassy states and glass-glass transition  

Science Journals Connector (OSTI)

The formal structure of glass singularities in the mode-coupling theory (MCT) of supercooled liquids dynamics is closely related to that appearing in the analysis of heterogeneous bootstrap percolation on Bethe lattices, random graphs, and complex networks. Starting from this observation one can build up microscopic on-lattice realizations of schematic MCT based on cooperative facilitated spin mixtures. I discuss a microscopic implementation of the F13 schematic model including multiple glassy states and the glass-glass transition. Results suggest that our approach is flexible enough to bridge alternative theoretical descriptions of glassy matter based on the notions of quenched disorder and dynamic facilitation.

Mauro Sellitto

2012-09-14T23:59:59.000Z

164

Breaking Through the Glass Ceiling: Recent Experimental Approaches...  

NLE Websites -- All DOE Office Websites (Extended Search)

Through the Glass Ceiling: Recent Experimental Approaches to Probe the Properties of Supercooled Liquids near the Glass Breaking Through the Glass Ceiling: Recent Experimental...

165

A radiochemical study of the mechanism of polishing glass.  

E-Print Network (OSTI)

??In an effort to determine whether glass flows when polished uranium glasses were fused to non uranium glasses and polishings carried out in a direction… (more)

Smith, John Graham

2012-01-01T23:59:59.000Z

166

Preliminary Simulation of the Corrosion Rate of Archaeological Glass  

E-Print Network (OSTI)

to a fractured Roman glass. Geochimica et Cosmochimica Acta,Santarini (2008). SON68 nuclear glass dissolution kinetics:B. (2006). Nuclear waste glasses – How durable? Elements, 2,

Steefel, Carl

2014-01-01T23:59:59.000Z

167

Small Glass-Melting Furnaces for Clear, Tinted, and Specialized Glass  

Science Journals Connector (OSTI)

Data on the design and application areas of small-sized glass-melting furnaces for melting various-purpose glasses are supplied.

A. A. Dymov; V. A. Fedorova

2000-07-01T23:59:59.000Z

168

Multiple reentrant glass transitions in confined hard-sphere glasses  

E-Print Network (OSTI)

Glass forming liquids exhibit a rich phenomenology upon confinement. This is often related to the effects arising from wall-fluid interactions. Here we focus on the interesting limit where the separation of the confining walls becomes of the order of a few particle diameters. For a moderately polydisperse, densely packed hard-sphere fluid confined between two smooth hard walls, we show via event-driven molecular dynamics simulations the emergence of a multiple reentrant glass transition scenario upon a variation of the wall separation. Using thermodynamic relations, this reentrant phenomenon is shown to persist also under constant chemical potential. This allows straightforward experimental investigation and opens the way to a variety of applications in micro- and nanotechnology, where channel dimensions are comparable to the size of the contained particles. The results are in-line with theoretical predictions obtained by a combination of density functional theory and the mode-coupling theory of the glass transition.

S. Mandal; S. Lang; M. Gross; M. Oettel; D. Raabe; T. Franosch; F. Varnik

2014-06-20T23:59:59.000Z

169

HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses  

SciTech Connect

In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Matyᚠet al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

2012-04-02T23:59:59.000Z

170

"Double swallow-tail" singularity and glass-glass transition in a quasibinary system  

E-Print Network (OSTI)

The system with the square shoulder (SS) potential is considered in the frame of Mode Coupling Theory (MCT) approach. An approximation for the structure factor is used that emphasizes the quasibinary character of the system. The qualitative phase diagram is constructed that includes continuous and discontinuous glass-glass transitions. The phase diagram is governed by two swallow tails connected with two $A_4$ singularities.

V. N. Ryzhov; E. E. Tareyeva

2013-12-05T23:59:59.000Z

171

Dynamics of window glass fracture in explosions  

SciTech Connect

An exploratory study was conducted under the Architectural Surety Program to examine the possibility of modifying fracture of glass in the shock-wave environment associated with terrorist bombings. The intent was to explore strategies to reduce the number and severity of injuries resulting from those attacks. The study consisted of a series of three experiments at the Energetic Materials Research and Testing Center (EMRTC) of the New Mexico Institute of Mining and Technology at Socorro, NM, in which annealed and tempered glass sheets were exposed to blast waves at several different levels of overpressure and specific impulse. A preliminary assessment of the response of tempered glass to the blast environment suggested that inducing early failure would result in lowering fragment velocity as well as reducing the loading from the window to the structure. To test that possibility, two different and novel procedures (indentation flaws and spot annealing) were used to reduce the failure strength of the tempered glass while maintaining its ability to fracture into small cube-shaped fragments. Each experiment involved a comparison of the performance of four sheets of glass with different treatments.

Beauchamp, E.K.; Matalucci, R.V.

1998-05-01T23:59:59.000Z

172

Crystallization of niobium germanosilicate glasses  

SciTech Connect

Niobium germanosilicate glasses are potential candidates for the fabrication of transparent glass ceramics with interesting non-linear optical properties. A series of glasses in the (Ge,Si)O{sub 2}-Nb{sub 2}O{sub 5}-K{sub 2}O system were prepared by melting and casting and their characteristic temperatures were determined by differential thermal analysis. Progressive replacement of GeO{sub 2} by SiO{sub 2} improved the thermal stability of the glasses. Depending on the composition and the crystallization heat-treatment, different nanocrystalline phases-KNbSi{sub 2}O{sub 7}, K{sub 3}Nb{sub 3}Si{sub 2}O{sub 13} and K{sub 3.8}Nb{sub 5}Ge{sub 3}O{sub 20.4} could be obtained. The identification and characterization of these phases were performed by X-ray diffraction and Raman spectroscopy. The 40 GeO{sub 2}-10 SiO{sub 2}-25 Nb{sub 2}O{sub 5}-25 K{sub 2}O (mol%) composition presented the higher ability for volume crystallization and its nucleation temperature was determined by the Marotta's method. An activation energy for crystal growth of {approx}529 kJ/mol and a nucleation rate of 9.7x10{sup 18} m{sup -3} s{sup -1} was obtained, for this composition. Transparent glass ceramics with a crystalline volume fraction of {approx}57% were obtained after a 2 h heat-treatment at the nucleation temperature, with crystallite sizes of {approx}20 nm as determined by transmission electron microscopy. - Abstract: TEM image and XRD pattern of the glass ceramic produced (circles indicate nanocrystals).

Santos, Rodrigo [Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Tecnico/TU Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisbon (Portugal); Santos, Luis F., E-mail: luis.santos@ist.utl.p [Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Tecnico/TU Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisbon (Portugal); Almeida, Rui M. [Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Tecnico/TU Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisbon (Portugal); Deubener, Joachim [Institute of Non-Metallic Materials, Clausthal University of Technology, Clausthal-Zellerfeld (Germany); Wondraczek, Lothar [Department of Materials Science, Glass and Ceramics, University of Erlangen-Nuremberg, 91058 Erlangen (Germany)

2010-01-15T23:59:59.000Z

173

Ionic Ckonductivity and Glass Transition of Phosphoric Acids  

SciTech Connect

Here we report the low-temperature dielectric and viscoelastic properties of phosphoric acids in the range of H2O:P2O5 1.5 5. Both dielectric and viscosity measurements allow us to determine the glass-transition temperatures of phosphoric acids. The obtained glass-transition temperatures are in good agreement with previous differential scanning calorimetric measurements. Moreover, our analysis reveals moderate decoupling of ionic conductivity from structural relaxation in the vicinity of the glass transition.

Wang, Yangyang [ORNL; Lane, Nathan A [ORNL; Sun, Che-Nan [Oak Ridge National Laboratory (ORNL); Fan, Fei [ORNL; Zawodzinski, Thomas [University of Tennessee, Knoxville (UTK); Sokolov, Alexei P [ORNL

2013-01-01T23:59:59.000Z

174

Ionic conductivity and glass transition of phosphoric acids  

SciTech Connect

Here we report the low-temperature dielectric and viscoelastic properties of phosphoric acids in the range of H2O:P2O5 1.5 5. Both dielectric and viscosity measurements allow us to determine the glass-transition temperatures of phosphoric acids. The obtained glass-transition temperatures are in good agreement with previous differential scanning calorimetric measurements. Moreover, our analysis reveals moderate decoupling of ionic conductivity from structural relaxation in the vicinity of the glass transition.

Wang, Yangyang [Oak Ridge National Laboratory (ORNL)] [Oak Ridge National Laboratory (ORNL); Lane, Nathan A [ORNL] [ORNL; Sun, Che-Nan [Oak Ridge National Laboratory (ORNL)] [Oak Ridge National Laboratory (ORNL); Fan, Fei [ORNL] [ORNL; Zawodzinski, Thomas [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Sokolov, Alexei P [ORNL] [ORNL

2013-01-01T23:59:59.000Z

175

Inelastic Neutron Scattering from Glass Formers  

Science Journals Connector (OSTI)

......research-article Articles Inelastic Neutron Scattering from Glass Formers U. Buchenau...transition. Coherent inelastic neutron scattering data indicate a mixture of...Supplement No. 126, 1997 Inelastic Neutron Scattering from Glass Formers U. BUCHENAU......

U. Buchenau

1997-01-01T23:59:59.000Z

176

The Conservation of Seventeenth Century Archaeological Glass  

E-Print Network (OSTI)

is the only chance for the objects survival. Though glass is considered one of the most stable archaeological materials, noninvasive, reversible treatments are not always possible given the level of deterioration glass objects undergo within the archaeological...

Arcak, Cory

2010-10-12T23:59:59.000Z

177

Glass Transition and the Coulomb Gap in Electron Glasses M. Muller and L. B. Ioffe  

E-Print Network (OSTI)

Glass Transition and the Coulomb Gap in Electron Glasses M. Mu¨ller and L. B. Ioffe Department December 2004) We establish the connection between the presence of a glass phase and the appearance correlations in a systematic way, we show that in the case of strong disorder a continuous glass transition

Müller, Markus

178

Heating-induced glass-glass and glass-liquid transformations in computer simulations of water  

SciTech Connect

Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

2014-03-21T23:59:59.000Z

179

Classification of oxide glasses: A polarizability approach  

SciTech Connect

A classification of binary oxide glasses has been proposed taking into account the values obtained on their refractive index-based oxide ion polarizability {alpha}{sub O2-}(n{sub 0}), optical basicity {lambda}(n{sub 0}), metallization criterion M(n{sub 0}), interaction parameter A(n{sub 0}), and ion's effective charges as well as O1s and metal binding energies determined by XPS. Four groups of oxide glasses have been established: glasses formed by two glass-forming acidic oxides; glasses formed by glass-forming acidic oxide and modifier's basic oxide; glasses formed by glass-forming acidic and conditional glass-forming basic oxide; glasses formed by two basic oxides. The role of electronic ion polarizability in chemical bonding of oxide glasses has been also estimated. Good agreement has been found with the previous results concerning classification of simple oxides. The results obtained probably provide good basis for prediction of type of bonding in oxide glasses on the basis of refractive index as well as for prediction of new nonlinear optical materials.

Dimitrov, Vesselin [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki [Department of Chemistry, The Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka-shi, Niigata-ken 940-2188 (Japan)]. E-mail: komatsu@chem.nagaokaut.ac.jp

2005-03-15T23:59:59.000Z

180

Glass Fibres for Cement Reinforcement [and Discussion  

Science Journals Connector (OSTI)

21 January 1980 research-article Glass Fibres for Cement Reinforcement [and Discussion...Ubbelohde G. Manfre The development of glass fibre compositions having sufficient alkali...resistance were used in an initial evaluation of glass compositions, which were then further...

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Identifying the Bose glass phase  

E-Print Network (OSTI)

Introducing disorder into the Bose-Hubbard model at integer fillings leads to a Bose glass phase, along with the Mott insulator and superfluid phases. We suggest a new order parameter: the determinant of the one body density matrix, which is nonzero only within the Mott-insulator phase. Alongside the superfluid fraction, it is then possible to distinguish the three phases. The Bose glass phase is the only phase which has vanishing determinant and superfluid fraction. The vanishing of the determinant in the Bose glass phase occurs due to the partial fragmentation of the condensate into localized fragments, each with zero superfluid response, which implies the presence of unoccupied sites and hence the presence of lines of zeros in the one body density matrix. In the superfluid phase, the determinant vanish for another reason - due to the macroscopic occupation of a single particle state. Finally, we suggest the enhancement of the three body decay rate in the Bose glass phase, as an experimental indicator for the presence of localized fragments.

R. Pugatch; N. Bar-gill; N. Katz; E. Rowen; N. Davidson

2006-07-28T23:59:59.000Z

182

Extraction of Proteins Glass Bead Method For preparation of protein extracts, the glass bead method is preferred. Some researchers  

E-Print Network (OSTI)

Extraction of Proteins ­ Glass Bead Method For preparation of protein extracts, the glass bead. glass beads (106 micron glass bead, Sigma cat. No. G4649) 7. Tabletop centrifuge 8. Vortex 9 µl glass beads (106 micron glass beads, Sigma, cat. G4649). 8. Vortex at top speed for 5 minutes. 9

183

Structure of finite-RSB asymptotic Gibbs measures in the diluted spin glass models  

E-Print Network (OSTI)

We suggest a possible approach to proving the M\\'ezard-Parisi formula for the free energy in the diluted spin glass models, such as diluted K-spin or random K-sat model at any positive temperature. In the main contribution of the paper, we show that a certain small modification of the Hamiltonian in any of these models forces all finite-RSB asymptotic Gibbs measures in the sense of the overlaps to satisfy the M\\'ezard-Parisi ansatz for the distribution of spins. Unfortunately, what is still missing is a description of the general full-RSB asymptotic Gibbs measures. If one could show that the general case can be approximated by finite-RSB case in the right sense then one could a posteriori remove the small modification of the Hamiltonian to recover the M\\'ezard-Parisi formula for the original model.

Dmitry Panchenko

2014-06-18T23:59:59.000Z

184

Durability of Silicate Glasses: An Historical Approach  

SciTech Connect

We present a short review of current theories of glass weathering, including glass dissolution, and hydrolysis of nuclear waste glasses, and leaching of historical glasses from an XAFS perspective. The results of various laboratory leaching experiments at different timescales (30 days to 12 years) are compared with results for historical glasses that were weathered by atmospheric gases and soil waters over 500 to 3000 years. Good agreement is found between laboratory experiments and slowly leached historical glasses, with a strong enrichment of metals at the water/gel interface. Depending on the nature of the transition elements originally dissolved in the melt, increasing elemental distributions are expected to increase with time for a given glass durability context.

Farges, Francois; /Museum Natl. Hist. Natur. /Stanford U., Geo. Environ. Sci.; Etcheverry, Marie-Pierre; /Marne la Vallee U.; Haddi, Amine; /Marne la Valle U.; Trocellier,; /Saclay; Curti, Enzo; /PSI, Villigen; Brown, Gordon E., Jr.; /SLAC, SSRL

2007-01-02T23:59:59.000Z

185

Pressurized heat treatment of glass ceramic  

DOE Patents (OSTI)

A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

Kramer, D.P.

1984-04-19T23:59:59.000Z

186

Glass-Ceramics in U.S.S.R.  

Science Journals Connector (OSTI)

... CATALYZED Crystallization of Glass differs from ^ Volumes 1 and 2 in this series which were reports of meetings ... meetings where very varied topics were brought together under the heading of the "Structure of Glass". The concentration on the one topic has resulted in a volume which leaves a ...

R. W. DOUGLAS

1965-08-14T23:59:59.000Z

187

Coated glass in the automotive industry  

Science Journals Connector (OSTI)

Inorganic coatings on glasses have reached the level where they will certainly be applied in the automotive industry in order to solve such glazing problems as heat load, heat loss, glare, UV adsorption, disturbed reflections, electromagnetic influence and thermal insulation. Their widespread use will depend on optimising the solution to problems of solar control and heatable glasses while the glass is also capable of the other functions required of it, thus justifying the relatively high cost that is predicted. There remain unsolved problems in optical limits and colour matching. When these are solved solar control glasses are likely to give real advantages in terms of air conditioning and comfort, and heatable glasses will be used in association with electrical power for demisting and deicing. Particular attention is being directed to a class of infrared reflecting and heatable glasses, obtained by selectively coating transparent plastic films that are embedded or bonded in laminated or tempered glasses. Fabricating this type of glasses has mainly been useful for two reasons: (I) to develop versatile techniques to make solar control IR reflecting and heatable glasses for all kinds and dimensions of vehicle glazing; and (2) to assess whether these glasses are really feasible alternatives to directly coated glasses. This paper describes results of some solar control experiments in Fiat cars: to ascertain the actual internal temperature differences found when glazing vehicles with the absorbing and reflecting IR glasses currently available; and to obtain results with a similar purpose using heatable glasses. There is also discussion of how the glasses could be used in glazing all or parts of a car's windows / especially addressing problems of glare. Suggestions are made of the directions of this research in the future.

G. Manfre

1991-01-01T23:59:59.000Z

188

Equilibrium ultrastable glasses produced by random pinning  

E-Print Network (OSTI)

Ultrastable glasses have risen to prominence due to their potentially useful material properties and the tantalizing possibility of a general method of preparation via vapor deposition. Despite the importance of this novel class of amorphous materials, numerical studies have been scarce because achieving ultrastability in atomistic simulations is an enormous challenge. Here we bypass this difficulty and establish that randomly pinning the position of a small fraction of particles inside an equilibrated supercooled liquid generates ultrastable configurations at essentially no numerical cost, while avoiding undesired structural changes due to the preparation protocol. Building on the analogy with vapor-deposited ultrastable glasses, we study the melting kinetics of these configurations following a sudden temperature jump into the liquid phase. In homogeneous geometries, we find that enhanced kinetic stability is accompanied by large scale dynamic heterogeneity, while a competition between homogeneous and heterogeneous melting is observed when a liquid boundary invades the glass at constant velocity. Our work demonstrates the feasibility of large-scale, atomistically resolved, and experimentally relevant simulations of the kinetics of ultrastable glasses.

Glen M Hocky; Ludovic Berthier; David R. Reichman

2014-09-23T23:59:59.000Z

189

Evaluation of the Thermal Performance for a Wire Mesh/Hollow Glass Microsphere Composite Structure as a Conduction Barrier  

E-Print Network (OSTI)

An experimental investigation exploring the use of wire mesh/hollow glass microsphere combination for use as thermal insulation was conducted with the aim to conclude whether or not it represents a superior insulation technology to those...

Mckenna, Sean

2010-01-15T23:59:59.000Z

190

Lid heater for glass melter  

DOE Patents (OSTI)

A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes.

Phillips, Terrance D. (617 Chestnut Ct., Aiken, SC 29803)

1993-01-01T23:59:59.000Z

191

New windows into the brain: using glass to see deeper  

Science Journals Connector (OSTI)

We present the use of simple glass structures, such as plugs, prisms, and prism-plug combinations, for chronic in vivo multiphoton microscopy of cortical and sub-cortical structures...

Levene, Michael J; Velasco, Mary Grace; Wolfel, Markus

192

PbO-free glasses for low temperature packaging  

SciTech Connect

Zinc polyphosphate glasses were examined as potential candidates for low temperature sealing applications. Glass-formation and properties were determined for the ZnO-P{sub 2}O{sub 5}, ZnO-B{sub 2}O{sub 3}-P{sub 2}O{sub 5} and ZnO-SnO-P{sub 2}O{sub 5} systems, and information about the short-range structures of these glasses was obtained by Raman and solid state nuclear magnetic resonance spectroscopies. In general, the most durable polyphosphate glasses have structures based on relatively short pyrophosphate chain lengths (i.e., 2 P-tetrahedra). Modified phosphate compositions are given, including compositions used to seal float glass substrates at temperatures as low as 500{degrees}C.

Brow, R.K.; Bencoe, D.N.; Tallant, D.R. [and others

1997-10-01T23:59:59.000Z

193

Method for heating, forming and tempering a glass sheet  

DOE Patents (OSTI)

A method for heating, forming and tempering a glass sheet including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet.

Boaz, Premakaran Tucker (Livonia, MI); Sitzman, Gary W. (Walled Lake, MI)

1998-01-01T23:59:59.000Z

194

Chalcogenide glass nanostructures  

DOE Patents (OSTI)

Chalcogenide nanowires and other micro-and nano scale structures are grown on a preselected portion of on a substrate. They are amorphous and of uniform composition and can be grown by a sublimation-condensation process onto the surface of an amorphous substrate. Among other uses, these structures can be used as coatings on optical fibers, as coatings on implants, as wispering galleries, in electrochemical devices, and in nanolasers.

Johnson, Bradley R. (Richland, WA); Schweiger, Michael J. (Richland, WA); MacIsaac, Brett D. (Kennewick, WA); Sundaram, S. Kamakshi (Richland, WA)

2007-05-01T23:59:59.000Z

195

Far-infrared attenuation in glasses  

Science Journals Connector (OSTI)

The influence of quasilocal vibrations on the far-infrared spectra of glasses is investigated under the supposition that the quasilocal vibrations are directly inactive in the attenuation. It is shown that taking into account phonon-quasilocal-vibration coupling and both medium- and short-range structure of the inhomogeneities of a photon-phonon coupling parameter can give rise to an attenuation curve similar to one observed for a-SiO2 and related materials.

Lev I. Deich

1994-01-01T23:59:59.000Z

196

Current status of the GLASS code  

SciTech Connect

This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970's. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

Hootman, H.E. (Westinghouse Savannah River Co., Aiken, SC (United States)); Honeck, H.C. (Computer Application Technology, Inc., Aiken, SC (United States))

1991-01-01T23:59:59.000Z

197

Current status of the GLASS code  

SciTech Connect

This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970`s. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

Hootman, H.E. [Westinghouse Savannah River Co., Aiken, SC (United States); Honeck, H.C. [Computer Application Technology, Inc., Aiken, SC (United States)

1991-12-31T23:59:59.000Z

198

Glass Property Data and Models for Estimating High-Level Waste Glass Volume  

SciTech Connect

This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

2009-10-05T23:59:59.000Z

199

Preparation, properties and chemistry of glass- and glass-ceramic-to-metal seals and coatings  

Science Journals Connector (OSTI)

An overview is given outlining the materials and technologies that have been employed in the preparation of glass- and glass-ceramic-to-metal seals and coatings. Metal/non-metal bonding theories are summarized...

I. W. Donald

1993-06-01T23:59:59.000Z

200

Characterization of New Glass Coated Foam Glass Insulating Tiles by Standard Tests  

Science Journals Connector (OSTI)

A good thermal insulation of buildings is today more and more...1). Among insulating materials, foam glasses are increasing their importance because of...2). Foam glasses are fiber-free inorganic insulation mater...

Andrea Ventrella; Federico Smeacetto…

2012-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Glass Technol., 2004, 45, 6870  

E-Print Network (OSTI)

68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Glass Technol., 2004, 45, 68­70 The behaviour of a simulant Magnox waste glass

Sheffield, University of

202

Doping of Glass with Lithium Ion  

Science Journals Connector (OSTI)

Our discovery that the Li+ uptake by the glass walls of the vessels used in the experiments can be used for doping purposes was purely surreptitious. ...

Greg Moakes; Lawrence A. Bottomley; Jiri Janata

2005-01-12T23:59:59.000Z

203

120 Years of Optical Glass Science  

Science Journals Connector (OSTI)

An elegant, century-old mathematical relationship, tying the physical properties of a multicomponent glass to those of its chemical components, still provides a powerful tool...

Dragic, Peter D; Ballato, John

2014-01-01T23:59:59.000Z

204

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure....

205

DEFENSE HIGH LEVEL WASTE GLASS DEGRADATION  

SciTech Connect

The purpose of this Analysis/Model Report (AMR) is to document the analyses that were done to develop models for radionuclide release from high-level waste (HLW) glass dissolution that can be integrated into performance assessment (PA) calculations conducted to support site recommendation and license application for the Yucca Mountain site. This report was developed in accordance with the ''Technical Work Plan for Waste Form Degradation Process Model Report for SR'' (CRWMS M&O 2000a). It specifically addresses the item, ''Defense High Level Waste Glass Degradation'', of the product technical work plan. The AP-3.15Q Attachment 1 screening criteria determines the importance for its intended use of the HLW glass model derived herein to be in the category ''Other Factors for the Postclosure Safety Case-Waste Form Performance'', and thus indicates that this factor does not contribute significantly to the postclosure safety strategy. Because the release of radionuclides from the glass will depend on the prior dissolution of the glass, the dissolution rate of the glass imposes an upper bound on the radionuclide release rate. The approach taken to provide a bound for the radionuclide release is to develop models that can be used to calculate the dissolution rate of waste glass when contacted by water in the disposal site. The release rate of a particular radionuclide can then be calculated by multiplying the glass dissolution rate by the mass fraction of that radionuclide in the glass and by the surface area of glass contacted by water. The scope includes consideration of the three modes by which water may contact waste glass in the disposal system: contact by humid air, dripping water, and immersion. The models for glass dissolution under these contact modes are all based on the rate expression for aqueous dissolution of borosilicate glasses. The mechanism and rate expression for aqueous dissolution are adequately understood; the analyses in this AMR were conducted to provide models and parameter values that can be used to calculate the dissolution rates for the different modes of water contact. The analyses were conducted to identify key aspects of the mechanistic model for glass dissolution to be included in the abstracted models used for PA calculations, evaluate how the models can be used to calculate bounding values of the glass dissolution rates under anticipated water contact modes in the disposal. system, and determine model parameter values for the range of potential waste glass compositions and anticipated environmental conditions. The analysis of a bounding rate also considered the effects of the buildup of glass corrosion products in the solution contacting the glass and potential effects of alteration phase formation. Note that application of the models and model parameter values is constrained to the anticipated range of HLW glass compositions and environmental conditions. The effects of processes inherent to exposure to humid air and dripping water were not modeled explicitly. Instead, the impacts of these processes on the degradation rate were taken into account by using empirically measured parameter values. These include the rates at which water sorbs onto the glass, drips onto the glass, and drips off of the glass. The dissolution rates of glasses that were exposed to humid air and dripping water measured in laboratory tests are used to estimate model parameter values for contact by humid air and dripping water in the disposal system.

W. Ebert

2001-09-20T23:59:59.000Z

206

Analysis and Research on the Thermal Properties of Energy-efficient Building Glass: A Case Study in PVB Laminated Glass  

E-Print Network (OSTI)

A new kind of PVB-laminated glass is introduced as an energy-efficient building glass. Based on tests and calculations of the shading coefficients of flat glass, LOW-E coated glass and PVB-laminated glass with different thickness, their effects...

Chen, Z.; Meng, Q.

2006-01-01T23:59:59.000Z

207

Copyright the Mathematical Association of America 2003. All rights reserved. Alice through Looking Glass after Looking Glass  

E-Print Network (OSTI)

Glass after Looking Glass: The Mathematics of Mirrors and Kaleidoscopes Roe Goodman 1. ALICE Alice book called Alice Through Looking Glass After Looking Glass. The book opens with Alice in her chamber in front of a peculiar cone­shaped arrangement of three looking glasses. She steps through one

Goodman, Roe

208

Nanomechanical studies of metallic glasses at ambient and elevated temperatures  

E-Print Network (OSTI)

Bulk metallic glasses, though attractive for use in structural applications for their high strength and elastic limit, display several unacceptable features upon deformation, including quasi-brittle failure along shear ...

Packard, Corinne E

2009-01-01T23:59:59.000Z

209

Silane Modification of Glass and Silica Surfaces to Obtain Equally...  

NLE Websites -- All DOE Office Websites (Extended Search)

Silane Modification of Glass and Silica Surfaces to Obtain Equally Oil-Wet Surfaces in Glass-Covered Silicon Micromodel Silane Modification of Glass and Silica Surfaces to Obtain...

210

Radiative Heat Transfer in Enhanced Hydrogen Outgassing of Glass  

E-Print Network (OSTI)

transport in a machinable glass-ceramic”, Journal of Non-in soda-lime-silicate glasses by reaction with hydrogen”,1971. [16] I. Fanderlik, Glass Science and Technology, Vol.

Kitamura, Rei; Pilon, Laurent

2009-01-01T23:59:59.000Z

211

Electrostatic transfer of epitaxial graphene to glass.  

SciTech Connect

We report on a scalable electrostatic process to transfer epitaxial graphene to arbitrary glass substrates, including Pyrex and Zerodur. This transfer process could enable wafer-level integration of graphene with structured and electronically-active substrates such as MEMS and CMOS. We will describe the electrostatic transfer method and will compare the properties of the transferred graphene with nominally-equivalent 'as-grown' epitaxial graphene on SiC. The electronic properties of the graphene will be measured using magnetoresistive, four-probe, and graphene field effect transistor geometries [1]. To begin, high-quality epitaxial graphene (mobility 14,000 cm2/Vs and domains >100 {micro}m2) is grown on SiC in an argon-mediated environment [2,3]. The electrostatic transfer then takes place through the application of a large electric field between the donor graphene sample (anode) and the heated acceptor glass substrate (cathode). Using this electrostatic technique, both patterned few-layer graphene from SiC(000-1) and chip-scale monolayer graphene from SiC(0001) are transferred to Pyrex and Zerodur substrates. Subsequent examination of the transferred graphene by Raman spectroscopy confirms that the graphene can be transferred without inducing defects. Furthermore, the strain inherent in epitaxial graphene on SiC(0001) is found to be partially relaxed after the transfer to the glass substrates.

Ohta, Taisuke; Pan, Wei; Howell, Stephen Wayne; Biedermann, Laura Butler; Beechem Iii, Thomas Edwin; Ross, Anthony Joseph, III

2010-12-01T23:59:59.000Z

212

STRUCTURAL ENVIRONMENT OF Nb5+ IN DRY AND FLUID-RICH (H2O, F) SILICATE GLASSES: A COMBINED XANES AND EXAFS STUDY  

Science Journals Connector (OSTI)

...anhydrous sodium silicate glasses (NS2: Na2Si2O5, NS3: Na2Si3O7...from the EXAFS baseline (VIPER code, Klementiev 1989), which creates...from centrosymmetry. In the NS2 and NS3 glasses (Fig. 5...significant interest. In the NS2 and NS3 glasses, the doublet...

Paula C. Piilonen; François Farges; Robert L. Linnen; Gordon E. Brown; Jr.; Marcin Pawlak; Allen Pratt

213

Method for heating and forming a glass sheet  

DOE Patents (OSTI)

A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration.

Boaz, Premakaran Tucker (Livonia, MI)

1997-01-01T23:59:59.000Z

214

Radiation Induced Nanocrystal Formation in Metallic Glasses  

E-Print Network (OSTI)

The irradiation of metallic glasses to induce nanocrystallization was studied in two metallic glass compositions, Cu50Zr45Ti5 and Zr55Cu30Al10Ni5. Atomic mobility was described using a model based on localized excess free volume due to displace...

Carter, Jesse

2010-01-14T23:59:59.000Z

215

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Glass compositions containing CaO, Al/sub 2/O/sub 3/, B/sub 2/O/sub 3/, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

Brow, R.K.; Watkins, R.D.

1988-01-21T23:59:59.000Z

216

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

217

Hydration Aging of Nuclear Waste Glass  

Science Journals Connector (OSTI)

...of Nuclear Waste Glass 10...STEINDLER Chemical Engineering...60439 The aging of simulated nuclear waste glass by...nuclear waste forms can meet...simulated aging reac-tions...whether a waste formn can...pro-jected Nuclear Regulatory...STEINDLEt Chemical Engineering...Basisfor Waste Form Integrity...

J. K. BATES; L. J. JARDINE; M. J. STEINDLER

1982-10-01T23:59:59.000Z

218

Viscous Glass Sealants for SOFC Applications  

SciTech Connect

Two series of silicate glasses that contain gallium as the primary critical component have been identified and optimized for viscous sealing of solid oxide fuel cells operating from 650 to 850°C. Both series of glass sealants crystallize partially upon heat treatment and yield multiphase microstructures that allow viscous flow at temperatures as low as 650°C. A fully amorphous sealant was also developed by isolating, synthesizing and testing a silicate glass of the same composition as the remnant glassy phase in one of the two glass series. Of ~40 glasses tested for longer than 500 hours, a set of 5 glasses has been further tested for up to 1000h in air, wet hydrogen, and against both yttria-stabilized zirconia and aluminized stainless steel. In some cases the testing times reached 2000h. The reactivity testing has provided new insight into the effects of Y, Zr, and Al on bulk and surface crystallization in boro-gallio-silicate glasses, and demonstrated that at least 5 of the newly-developed glasses are viable viscous sealants.

Scott Misture

2012-09-30T23:59:59.000Z

219

Vibration of Glasses containing Effervescing Liquids  

Science Journals Connector (OSTI)

... of the phenomena, he says:—“We must consider what passes in the communication of vibrations through the liquid from one side of the glass to the other. The glass ... it is clear, that if any considerable part of a system be unsusceptible of regular vibration, the whole must be so.” The phenomenon, then, according to this explanation, ...

ALLEN BEAZELEY

1872-07-18T23:59:59.000Z

220

Materials science: To the heart of glass  

Science Journals Connector (OSTI)

... collaborate with archaeologists. One of the best disposal options is to trap the waste in glass and bury it. So when the civilizations of the Middle East first learnt how ... bury it. So when the civilizations of the Middle East first learnt how to make glass at least 4,500 years ago, they unwittingly launched an experiment on the long- ...

Philip Ball

2003-02-20T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Manufacture of Sheet and Plate Glass  

Science Journals Connector (OSTI)

... lantern slides and films, the methods in use for the manufacture of sheet and plate glass. The principal raw materials used in the manu facture of sheet and plate ... . The principal raw materials used in the manu facture of sheet and plate glass are sand, soda ash and limestone. These materials, perhaps with the addition of ...

S. E.

1934-03-10T23:59:59.000Z

222

Origin of Libyan Desert Silica-Glass  

Science Journals Connector (OSTI)

... of germanium, using a modified method of Schneider and Sandell4, in Libyan Desert silica-glass, Libyan Desert sandstone, a Libyan Desert quartzite, two Libyan Desert sands, Aouelloul crater ... Desert sandstone, a Libyan Desert quartzite, two Libyan Desert sands, Aouelloul crater 'impactite' glass, two obsidians, the average for tektites from eleven different localities, including all known ...

ALVIN J. COHEN

1959-05-30T23:59:59.000Z

223

New Process of Making Plate Glass  

Science Journals Connector (OSTI)

... , Lancashire, have just announced the successful development of a new process of making plate glass. In the new process the plate ... . In the new process the plate glass is produced with a fire-polished finish, so that the lengthy grinding and polishing ...

1959-01-31T23:59:59.000Z

224

Numerical investigation of low-velocity impacts on monolithic and laminated safety glass  

E-Print Network (OSTI)

Numerical investigation of low-velocity impacts on monolithic and laminated safety glass Researcher objects are one of the most common incidents to impact on glass floors or stairs during day to day experienced during hard body impacts on monolithic and laminated safety glass, mainly of structural use

Birmingham, University of

225

Elastic Properties and Structural Studies on Boro-Vanadate Glasses Containing Sulphate (SO{sub 4}{sup 2-}) Ions  

SciTech Connect

Elastic properties of xLi{sub 2}SO{sub 4}-16 Li{sub 2}O-(84-x) [0.7 B{sub 2}O{sub 3}-0.3 V{sub 2}O{sub 5}] where (5{<=}x{>=}30) glasses have been prepared by melt quenching method and structural investigations were carried out using ultrasonic pulse echo overlap technique at a frequency of 10 MHz and at 300 K. The molar volume increases and the density decreases with the increase of Li{sub 2}SO{sub 4} concentration due to the incorporation of SO{sub 4}{sup 2-} ions into the modified macromolecular network. The addition of Li{sub 2}SO{sub 4} content leads to loose packing structure which is attributed to volume increasing effect and the reduction in the vibrations of borate and vanadate lattices. Increase in Li{sub 2}{sup SO}{sub 4} results in decreasing cross link density which in turn decreases elastic moduli. The results are discussed in view of its network structure. The structural groups [VOO{sub 3/2}]{sup 0} and [BO{sub 3/2}]{sup 0} modify preferentially. This preference in modification is decided by the electronegativity ({chi}) of the structural groups.

Reddy, M. Sudhakar [Department of Physics, Sri Bhagavan Mahaveer Jain College, Jain University, Bangalore-560027 (India); Gowda, V. C. Veeranna [Department of Physics, Government College for Women's, Chintamani-563125 (India); Reddy, C. Narayana [Department of Physics, Maharani's Science College for Woman, Palace Road, Bangalore-560001 (India)

2011-12-12T23:59:59.000Z

226

Gaseous Sulfate Solubility in Glass: Experimental Method  

SciTech Connect

Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

Bliss, Mary

2013-11-30T23:59:59.000Z

227

Titanium sealing glasses and seals formed therefrom  

DOE Patents (OSTI)

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La{sub 2}O{sub 3}, B{sub 2}O{sub 3}, TiO{sub 2} and Al{sub 2}O{sub 3} in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 2 figs.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-12-02T23:59:59.000Z

228

Titanium sealing glasses and seals formed therefrom  

DOE Patents (OSTI)

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

229

An infrared invisibility cloak composed of glass  

Science Journals Connector (OSTI)

We propose to implement a nonmetallic low-loss cloak for the infrared range from identical chalcogenide glassresonators. Based on transformation optics for cylindrical objects our approach does not require metamaterial response to be homogeneous and accounts for the discrete nature of elementary responses governed by resonator shape illumination angle and inter-resonator coupling. Air fractions are employed to obtain the desired distribution of the cloak effective parameters. The effect of cloaking is verified by full-wave simulations of the true multiresonator structure. The feasibility of cloak fabrication is demonstrated by prototyping glass grating structures with the dimensions characteristic for the cloak resonators.

Elena Semouchkina; Douglas H. Werner; George B. Semouchkin; Carlo Pantano

2010-01-01T23:59:59.000Z

230

Glass cullet as a new supplementary cementitious material (SCM).  

E-Print Network (OSTI)

??Finely ground glass has the potential for pozzolanic reactivity and can serve as a supplementary cementitious material (SCM). Glass reaction kinetics depends on both temperature… (more)

Mirzahosseini, Mohammadreza

2014-01-01T23:59:59.000Z

231

Static Temperature Survey At Glass Buttes Area (DOE GTP) | Open...  

Open Energy Info (EERE)

Static Temperature Survey At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Static Temperature Survey At Glass...

232

Waste Loading Enhancements for Hanford Low-Activity Waste Glasses  

NLE Websites -- All DOE Office Websites (Extended Search)

WASTE LOADING ENHANCEMENTS FOR HANFORD LOW-ACTIVITY WASTE GLASSES Albert A. Kruger, Glass Scientist DOE-WTP Project Office Engineering Division US Department of Energy Richland,...

233

Development Wells At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Development Wells At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Glass Buttes Area (DOE GTP)...

234

Pressure Temperature Log At Glass Buttes Area (DOE GTP) | Open...  

Open Energy Info (EERE)

Pressure Temperature Log At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Pressure Temperature Log At Glass Buttes...

235

Cuttings Analysis At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Cuttings Analysis At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At Glass Buttes Area (DOE GTP)...

236

Metal and Glass Manufacturers Reduce Costs by Increasing Energy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in Process Heating Systems Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in...

237

Breaking through the Glass Ceiling: The Correlation Between the...  

NLE Websites -- All DOE Office Websites (Extended Search)

through the Glass Ceiling: The Correlation Between the Self-Diffusivity in and Krypton Permeation through Deeply Breaking through the Glass Ceiling: The Correlation Between the...

238

Cold Crucible Induction Melter Studies for Making Glass Ceramic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms: A Feasibility Assessment. Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms:...

239

Asahi Glass Co Ltd AGC | Open Energy Information  

Open Energy Info (EERE)

Ltd AGC Jump to: navigation, search Name: Asahi Glass Co Ltd (AGC) Place: Tokyo, Tokyo, Japan Zip: 100-8405 Sector: Efficiency Product: Japanese glass manufacturer; produces cover...

240

Elastic interpretation of the glass transition in aluminosilicate liquids  

Science Journals Connector (OSTI)

One of the remaining puzzles of the glass transition is the origin of a glass-forming liquid's “fragility,” which quantifies the departure of its relaxation time from Arrhenius-activated kinetics. According to the shoving model proposed by Dyre, fragility is controlled by the instantaneous shear modulus of the liquid, since any flow event requires a local volume increase, and the related activation energy is equal to the work done in shoving aside the surrounding atoms. Here, we present an in situ high-temperature Brillouin spectroscopy test of the shoving model near the glass transition of eight aluminosilicate glass-forming systems. We find that the measured viscosity data agree qualitatively with the measured temperature dependence of shear moduli, as predicted by the shoving model. However, the model systematically underpredicts the values of fragility for our aluminosilicate liquids. This suggests that the dynamics of the glass transition are governed by additional factors beyond the evolution of the shear modulus, such as configurational entropy. We have also compared the glass transition temperature (Tg,vis) obtained from viscosity (temperature at 1012 Pa s) with the onset temperatures of the decrease in elastic moduli (Tg,elas) and increase in the thermal expansion coefficient (Tg,CTE) during heating. While we find an approximate one-to-one correlation between Tg,vis and Tg,CTE, it is clear that the elastic moduli probe a different frequency response of the glass structure, since Tg,elas is systematically lower than Tg,vis.

Morten M. Smedskjaer; Liping Huang; Garth Scannell; John C. Mauro

2012-04-27T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Hollow porous-wall glass microspheres for hydrogen storage  

DOE Patents (OSTI)

A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

Heung, Leung K. (Aiken, SC); Schumacher, Ray F. (Aiken, SC); Wicks, George G. (Aiken, SC)

2010-02-23T23:59:59.000Z

242

Three-Dimensional Flow and Thermal Structures in Glass Melting Furnaces. Part II: Effect of Batch and Bubbles.  

E-Print Network (OSTI)

) the wall heat losses, and (v) the thickness of glass melt containing gas bubbles under the batch. The study indicates that the partially submerged batch and heat losses through the refractories have a strong impact by adjusting the fuel firing in the combustion space. The heat flux distribution resulting from combustion

Pilon, Laurent

243

Glass for sealing lithium cells  

DOE Patents (OSTI)

Glass compositions resistant to corrosion by lithium cell electrolyte and having an expansion coefficient of 45 to 85 x 10/sup -70/C/sup -1/ have been made with SiO/sub 2/, 25 to 55% by weight; B/sub 2/O/sub 3/, 5 to 12%; Al/sub 2/O/sub 3/, 12 to 35%; CaO, 5 to 15%; MgO, 5 to 15%; SrO, 0 to 10%; and La/sub 2/O/sub 3/, 0 to 5%. Preferred compositions within that range contain 3 to 8% SrO and 0.5 to 2.5% La/sub 2/O/sub 3/.

Leedecke, C.J.

1981-08-28T23:59:59.000Z

244

Solid oxide fuel cell having a glass composite seal  

DOE Patents (OSTI)

A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

2013-04-16T23:59:59.000Z

245

Energy implications of glass-container recycling  

SciTech Connect

This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

Gaines, L.L.; Mintz, M.M. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

1994-03-01T23:59:59.000Z

246

Aligned Crystalline Semiconducting Film On A Glass Substrate And Method Of  

NLE Websites -- All DOE Office Websites (Extended Search)

Aligned Crystalline Semiconducting Film On A Glass Substrate Aligned Crystalline Semiconducting Film On A Glass Substrate Aligned Crystalline Semiconducting Film On A Glass Substrate And Method Of Making A semiconducting structure having a glass substrate. Available for thumbnail of Feynman Center (505) 665-9090 Email Aligned Crystalline Semiconducting Film On A Glass Substrate And Method Of Making A semiconducting structure having a glass substrate. In one embodiment, the glass substrate has a softening temperature of at least about 750.degree. C. The structure includes a nucleation layer formed on a surface of the substrate, a template layer deposited on the nucleation layer by one of ion assisted beam deposition and reactive ion beam deposition, at least on biaxially oriented buffer layer epitaxially deposited on the template

247

Glass melter off-gas system  

DOE Patents (OSTI)

Apparatus and method for melting glass in a glass melter in such a way as to reduce deposition of particulates in the off-gas duct. Deposit accumulation is reduced by achieving an off-gas velocity above approximately 15 meters/second and an off-gas temperature as close as possible to, but not higher than, the glass softening point. Because the deposits are largely water-soluble, those that do form on the interior surface of the duct can be readily removed by injecting water or steam directly into the off-gas duct from its entrance or exit.

Jantzen, Carol M. (Aiken, SC)

1997-01-01T23:59:59.000Z

248

SLUDGE BATCH 7B GLASS VARIABILITY STUDY  

SciTech Connect

The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable using the current Product Composition Control System (PCCS) models for durability, but were acceptable compared to the EA glass when tested. These glasses fell outside of the lower 95% confidence band, which demonstrates conservatism in the model. A few of the glasses fell outside of the upper 95% confidence band; however, these particular glasses have normalized release values that were much lower than the values of EA and should be of no practical concern. Per the requirements of the DWPF Glass Product Control Program, the PCCS durability models have been shown to be applicable to the SB7b sludge system with a range of Na{sub 2}O concentrations blended with Frits 418 or 702. PCT results from the glasses fabricated as part of the variability study were shown to be predictable by the current DWPF PCCS models and/or acceptable with respect to the EA benchmark glass regardless of thermal history or compositional view.

Johnson, F.; Edwards, T.

2011-10-25T23:59:59.000Z

249

Glass Needs for a Growing Photovoltaics Industry Keith Burrows1  

E-Print Network (OSTI)

1 Glass Needs for a Growing Photovoltaics Industry Keith Burrows1 and Vasilis Fthenakis1,2* 1, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass

250

Finding Glass Kenton McHenry, Jean Ponce  

E-Print Network (OSTI)

Finding Glass Kenton McHenry, Jean Ponce Beckman Institute University of Illinois Urbana, IL 61801. This paper addresses the problem of finding glass ob- jects in images. Visual cues obtained by combining with the strong highlights typical of glass surfaces are used to train a hierarchy of classifiers, identify glass

Forsyth, David

251

Non-photorealistic Rendering of Images as Evolutionary Stained Glass  

E-Print Network (OSTI)

Non-photorealistic Rendering of Images as Evolutionary Stained Glass Daniel Ashlock Mathematics glass. A collection of points that are the centers of weighted Voronoi tilings are evolved to minimize. A fractal model of stained glass is then run to create a stained glass texture with a similar average color

Ashlock, Dan

252

Glass/polymer composites and methods of making  

DOE Patents (OSTI)

The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

Samuels, W. D. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

1995-01-01T23:59:59.000Z

253

Glass Buttes Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Glass Buttes Geothermal Area Glass Buttes Geothermal Area (Redirected from Glass Buttes Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Buttes Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (1) 9 Exploration Activities (14) 10 References Area Overview Geothermal Area Profile Location: Oregon Exploration Region: Cascades GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed. Add a new Operating Power Plant

254

Preparation of fullerene/glass composites  

DOE Patents (OSTI)

Synthesis of fullerene/glass composites is described. A direct method for preparing solid solutions of C{sub 60} in silicon dioxide (SiO{sub 2}) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these ``guests`` in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C{sub 60}. Depending upon the preparative procedure, C{sub 60} dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C{sub 60} in a solid glass matrix, is generated by the present method.

Mattes, B.R.; McBranch, D.W.; Robinson, J.M.; Koskelo, A.C.; Love, S.P.

1995-05-30T23:59:59.000Z

255

Neutron Brillouin scattering in a metallic glass  

SciTech Connect

The dispersion of collective modes in a metallic glass (Mg{sub 70}Zn{sub 30}) measured earlier at the thermal neutron time-of-flight spectrometer IN4 of the HFR of the ILL could be extended towards lower momentum transfers down to the first pseudo-Brillouin zone for the first time. This extension to momentum transfer not accessible up to now was possible using the highly resolving time-of-flight spectrometer HET of the new spallation source ISIS. In the region of overlap the two parts of the dispersion determined with different samples of the same metallic glass on different instruments agree very well. Also the earlier discrepancies with the dispersion determined for this metallic glass from a computer simulation could be nearly completely eliminated due to a more recent and more complete investigations of this glass.

Suck, J.B. (Kernforschungszentrum Karlsruhe GmbH (Germany). Inst. fuer Nukleare Festkoerperphysik); Egelstaff, P.A. (Guelph Univ., ON (Canada). Dept. of Physics); Robinson, R.A.; Sivia, D.S. (Los Alamos National Lab., NM (United States)); Taylor, A.D. (Rutherford Appleton Lab., Chilton (United Kingdom))

1991-01-01T23:59:59.000Z

256

Measurement of DWPF glass viscosity - Final Report  

SciTech Connect

This report details the results of a scoping study funded by the Defense Waste Processing Facility (DWPF) for the measurement of melt viscosities for simulated glasses representative of Macrobatch 2 (Tank 42/51 feed).

Harbour, J.R.

2000-02-17T23:59:59.000Z

257

A photo-stable chalcogenide glass  

Science Journals Connector (OSTI)

Photo-darkening and photo-bleaching are well known phenomena in As-Se and Ge-Se chalcogenide glasses, respectively. Consequently, a systematic dependence of photo-induced optical...

Yang, Guang; Jain, Himanshu; Ganjoo, Ashtosh; Zhao, Donghui; Xu, Yinsheng; Zeng, Huidan; Chen, Guorong

2008-01-01T23:59:59.000Z

258

Energy Assessment Protocol for Glass Furnaces  

E-Print Network (OSTI)

The Department of Energy funded development of a methodology that could be used by glass producers to increase furnace efficiency, and that could serve as a model for other energy-intensive industries. Accordingly, a team comprising PPG Industries...

Plodinec, M. J.; Kauffman, B. M.; Norton, O. P.; Richards, C.; Connors, J.; Wishnick, D.

2005-01-01T23:59:59.000Z

259

Glass bead micromodel study of solute transport  

E-Print Network (OSTI)

This study presents the quantification of glass bead micromodel experiments through a combination of computational modeling and experimental analysis. The computational model simulates two-dimensional solute flow through porous media using a finite...

Fedirchuk, Paula Diane

1995-01-01T23:59:59.000Z

260

Preparation of fullerene/glass composites  

DOE Patents (OSTI)

Synthesis of fullerene/glass composites. A direct method for preparing solid solutions of C.sub.60 in silicon dioxide (SiO.sub.2) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these "guests" in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C.sub.60. Depending upon the preparative procedure, C.sub.60 dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C.sub.60 in a solid glass matrix, is generated by the present method.

Mattes, Benjamin R. (Santa Fe, NM); McBranch, Duncan W. (Santa Fe, NM); Robinson, Jeanne M. (Los Alamos, NM); Koskelo, Aaron C. (Los Alamos, NM); Love, Steven P. (Los Alamos, NM)

1995-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Quarks in the looking glass | Jefferson Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Quarks in the looking glass Jefferson Lab's Experimental Hall A The electron-quark scattering experiment was carried out in Jefferson Lab's Experimental Hall A. In this view from...

262

Frequency-dependent conductivity of electron glasses  

Science Journals Connector (OSTI)

Results of dc and frequency-dependent conductivity in the quantum limit—i.e., ??>kBT—for a broad range of dopant concentrations in nominally uncompensated, crystalline phosphorous-doped silicon and amorphous niobium-silicon alloys are reported. These materials fall under the general category of disordered insulating systems, which are referred to as electron glasses. Using microwave resonant cavities and quasioptical millimeter-wave spectroscopy we are able to study the frequency-dependent response on the insulating side of the metal-insulator transition. We identify a quantum critical regime, a Fermi glass regime, and a Coulomb glass regime. Our phenomenological results lead to a phase diagram description, or taxonomy, of the electrodynamic response of electron glass systems.

E. Helgren; N. P. Armitage; G. Grüner

2004-01-13T23:59:59.000Z

263

Rotational dynamics in the plastic-crystal phase of ethanol: Relevance for understanding the dynamics during the structural glass transition  

Science Journals Connector (OSTI)

The reorientational dynamics within the rotationally disordered cubic plastic phase of solid ethanol is investigated by means of the concurrent use of computer molecular dynamics and quasielastic neutron scattering. Motions involving widely different time scales are shown to take place above the calorimetric “glass transition” which is centered at Tg?97?K. These correspond to well-defined reorientations belonging to the cubic point group. The dynamics of this solid exhibits features remarkably close to those of the supercooled liquid that can exist at the same temperature. Such similitude of dynamic behavior serves to provide some clues for the understanding of the nature of molecular motions at temperatures close to the canonical liquid?glass transition.

A. Criado; M. Jiménez-Ruiz; C. Cabrillo; F. J. Bermejo; R. Fernández-Perea; H. E. Fischer; F. R. Trouw

2000-05-01T23:59:59.000Z

264

Glass-formers and structure-seekers: From interatomic forces and potential-surface topographies to crystallization and protein folding  

SciTech Connect

The salient information for characterizing topographies of many-dimensional potential surfaces is the nature and distribution of the sequences of stationary points connecting the basin bottoms with the high reaches of the landscape. Roughly, the longer the range of the interatomic forces, the smoother is the topography. Landscapes studied thus far seem to fall into two classes: sawtooth-like, in which the changes in energy from one minimum to the next along a sequence of local minima monotonic in energy are small relative to the heights of the saddles separating successive minima, and staircase-like, in which some large changes in potential energy occur along monotonic sequences of minima, large compared with the heights of saddles linking those minima or others close to them. Sawtooth potentials appear to be associated with growth of nuclei by few-particle steps, and with glass formation. Staircase potentials seem to be associated with growth of nuclei by highly cooperative processes, and with {open_quotes}structure-seeking{close_quotes}--either crystallization or folding, in the case of a polymer model. The dynamics on the surface can be modeled reliably by a master equation based on thermal equilibration of the vibrational motion after entry into each new well, even for staircase potentials.

Berry, R.S.; Astakhova, T.; Ball, K.D. [Univ. of Chicago, IL (United States)] [and others

1996-12-31T23:59:59.000Z

265

Femtosecond laser-induced modification of potassium-magnesium silicate glasses: An analysis of structural changes by near edge x-ray absorption spectroscopy  

SciTech Connect

The effects of femtosecond laser pulse irradiation on the glass structure of alkaline silicate glasses were investigated by x-ray absorption near edge structure spectroscopy using the beamline of the Physikalisch-Technische Bundesanstalt at the electron synchrotron BESSY II in Berlin (Germany) by analyzing the magnesium K-edge absorption peak for different laser fluences. The application of fluences above the material modification threshold (2.1 J/cm{sup 2}) leads to a characteristic shift of {approx}1.0 eV in the K-edge revealing a reduced ({approx}3%) mean magnesium bond length to the ligated oxygen ions (Mg-O) along with a reduced average coordination number of the Mg ions.

Seuthe, T.; Eberstein, M. [Fraunhofer-Institut fuer Keramische Technologien und Systeme (IKTS), Winterbergstrasse 28, 01277 Dresden (Germany); Hoefner, M.; Eichler, H. J.; Grehn, M. [Technische Universitaet Berlin, Institut fuer Optik und Atomare Physik, Strasse des 17. Juni 135, 10623 Berlin (Germany); Reinhardt, F. [Physikalisch-Technische Bundesanstalt (PTB), Abbestr. 2-12, 10587 Berlin (Germany); Tsai, W. J. [ITRI South, Industrial Technology Research Institute, 8 Gongyan Rd., Liu-jia District, Tainan City 73445, Taiwan (China); Bonse, J. [BAM Bundesanstalt fuer Materialforschung und - pruefung, Unter den Eichen 87, 12205 Berlin (Germany)

2012-05-28T23:59:59.000Z

266

Equivalence of Glass Transition and Colloidal Glass Transition in the Hard-Sphere Limit Thomas K. Haxton,2  

E-Print Network (OSTI)

Equivalence of Glass Transition and Colloidal Glass Transition in the Hard-Sphere Limit Ning Xu,1 that the slowing of the dynamics in simulations of several model glass-forming liquids is equivalent to the hard-sphere glass transition in the low-pressure limit. In this limit, we find universal behavior of the relaxation

Weeks, Eric R.

267

High expansion, lithium corrosion resistant sealing glasses  

DOE Patents (OSTI)

Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

268

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents (OSTI)

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

1995-01-01T23:59:59.000Z

269

High thermal expansion, sealing glass  

DOE Patents (OSTI)

A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

Brow, R.K.; Kovacic, L.

1993-11-16T23:59:59.000Z

270

Hysteretic Optimization For Spin Glasses  

E-Print Network (OSTI)

The recently proposed Hysteretic Optimization (HO) procedure is applied to the 1D Ising spin chain with long range interactions. To study its effectiveness, the quality of ground state energies found as a function of the distance dependence exponent, $\\sigma$, is assessed. It is found that the transition from an infinite-range to a long-range interaction at $\\sigma=0.5$ is accompanied by a sharp decrease in the performance . The transition is signaled by a change in the scaling behavior of the average avalanche size observed during the hysteresis process. This indicates that HO requires the system to be infinite-range, with a high degree of interconnectivity between variables leading to large avalanches, in order to function properly. An analysis of the way auto-correlations evolve during the optimization procedure confirm that the search of phase space is less efficient, with the system becoming effectively stuck in suboptimal configurations much earlier. These observations explain the poor performance that HO obtained for the Edwards-Anderson spin glass on finite-dimensional lattices, and suggest that its usefulness might be limited in many combinatorial optimization problems.

B. Goncalves; S. Boettcher

2007-12-10T23:59:59.000Z

271

Evaluation Of Glass Density To Support The Estimation Of Fissile Mass Loadings From Iron Concentrations In SB8 Glasses  

SciTech Connect

The Department of Energy – Savannah River (DOE-SR) has provided direction to Savannah River Remediation (SRR) to maintain fissile concentration in glass below 897 g/m{sup 3}. In support of that guidance, the Savannah River National Laboratory (SRNL) provided a technical basis and a supporting Microsoft® Excel® spreadsheet for the evaluation of fissile loading in Sludge Batch 5 (SB5), Sludge Batch 6 (SB6), Sludge Batch 7a (SB7a), and Sludge Batch 7b (SB7b) glass based on the iron (Fe) concentration in glass as determined by the measurements from the Slurry Mix Evaporator (SME) acceptability analysis. SRR has since requested that the necessary density information be provided to allow SRR to update the Excel® spreadsheet so that it may be used to maintain fissile concentration in glass below 897 g/m{sup 3} during the processing of Sludge Batch 8 (SB8). One of the primary inputs into the fissile loading spreadsheet includes an upper bound for the density of SB8-based glasses. Thus, these bounding density values are to be used to assess the fissile concentration in this glass system. It should be noted that no changes are needed to the underlying structure of the Excel-based spreadsheet to support fissile assessments for SB8. However, SRR should update the other key inputs to the spreadsheet that are based on fissile and Fe concentrations reported from the SB8 Waste Acceptance Product Specification (WAPS) sample.

Edwards, T. B.; Peeler, D. K.; Kot, W. K.; Gan, H.; Pegg, I. L.

2013-04-30T23:59:59.000Z

272

Natural glass analogues to alteration of nuclear waste glass: A review and recommendations for further study  

SciTech Connect

The purpose of this report is to review previous work on the weathering of natural glasses; and to make recommendations for further work with respect to studying the alteration of natural glasses as it relates quantifying rates of dissolution. the first task was greatly simplified by the published papers of Jercinovic and Ewing (1987) and Byers, Jercinovic, and Ewing (1987). The second task is obviously the more difficult of the two and the author makes no claim of completeness in this regard. Glasses weather in the natural environment by reacting with aqueous solutions producing a rind of secondary solid phases. It had been proposed by some workers that the thickness of this rind is a function of the age of the glass and thus could be used to estimate glass dissolution rates. However, Jercinovic and Ewing (1987) point out that in general the rind thickness does not correlate with the age of the glass owing to the differences in time of contact with the solution compared to the actual age of the sample. It should be noted that the rate of glass dissolution is also a function of the composition of both the glass and the solution, and the temperature. Quantification of the effects of these parameters (as well as time of contact with the aqueous phase and flow rates) would thus permit a prediction of the consequences of glass-fluid interactions under varying environmental conditions. Defense high- level nuclear waste (DHLW), consisting primarily of liquid and sludge, will be encapsulated by and dispersed in a borosilicate glass before permanent storage in a HLW repository. This glass containing the DHLW serves to dilute the radionuclides and to retard their dispersion into the environment. 318 refs.

McKenzie, W.F.

1990-01-01T23:59:59.000Z

273

Ising model of a glass transition  

Science Journals Connector (OSTI)

Numerical simulations by Tanaka and co-workers indicate that glass-forming systems of moderately polydisperse hard-core particles, in both two and three dimensions, exhibit diverging correlation lengths. These correlations are described by Ising-like critical exponents, and are associated with diverging, Vogel-Fulcher-Tamann, structural relaxation times. Related simulations of thermalized hard disks indicate that the curves of pressure versus packing fraction for different polydispersities exhibit a sequence of transition points, starting with a liquid-hexatic transition for the monodisperse case, and crossing over with increasing polydispersity to glassy, Ising-like critical points. I propose to explain these observations by assuming that glass-forming fluids contain twofold degenerate, locally ordered clusters of particles, similar to the two-state systems that have been invoked to explain other glassy phenomena. This paper starts with a brief statistical derivation of the thermodynamics of thermalized, hard-core particles. It then discusses how a two-state, Ising-like model can be described within that framework in terms of a small number of statistically relevant, internal state variables. The resulting theory agrees accurately with the simulation data. I also propose a rationale for the observed relation between the Ising-like correlation lengths and the Vogel-Fulcher-Tamann formula.

J. S. Langer

2013-07-17T23:59:59.000Z

274

Bose glass and Mott glass of quasiparticles in a doped quantum magnet  

Science Journals Connector (OSTI)

... has been predicted that for strongly interacting bosons, Anderson localization manifests itself in the Bose glass: in this phase, the collective modes of the system—and not the individual particles ... interacting Anderson insulator to an interacting superfluid condensate, or from a superfluid to a Bose glass. Such a transition is relevant for a large variety of physical systems, including superfluid ...

Rong Yu; Liang Yin; Neil S. Sullivan; J. S. Xia; Chao Huan; Armando Paduan-Filho; Nei F. Oliveira Jr; Stephan Haas; Alexander Steppke; Corneliu F. Miclea; Franziska Weickert; Roman Movshovich; Eun-Deok Mun; Brian L. Scott; Vivien S. Zapf; Tommaso Roscilde

2012-09-19T23:59:59.000Z

275

Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics  

SciTech Connect

Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400°C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

Sathish, M., E-mail: sathishphy79@gmail.com [Department of Physics, GOVT first grade College, Doddaballapur-561203 (India); Eraiah, B., E-mail: eraiah@rediffmail.com [Department of Physics, Bangalore University, Bangalore-560056, India (India)

2014-04-24T23:59:59.000Z

276

8 - Bioactive glass and glass–ceramic foam scaffolds for bone tissue restoration  

Science Journals Connector (OSTI)

Abstract: One of the major goals of bone tissue engineering is the development of appropriate porous biomaterials (scaffolds) that can stimulate the body’s own regenerative mechanism, to induce tissue healing and self-repair. Bioactive glasses are excellent candidates for producing 3-D scaffolds, as their properties can be finely tailored depending on the glass composition, and they can bond to bone, inducing osteogenesis at the defect site. This chapter is focused on glass/glass–ceramic scaffolds characterized by foam-like architecture closely mimicking that of natural cancellous bone. After giving an overview of the features and limitations of the biomedical glass foams investigated in the literature, future directions of research will be described, emphasizing the challenge to develop multifunctional foams able to combine bone regeneration with special therapeutic functionalities.

F. Baino; C. Vitale-Brovarone

2014-01-01T23:59:59.000Z

277

Nano-Continuum Modeling of a Nuclear Glass Specimen Altered for 25 Years  

E-Print Network (OSTI)

Insight into silicate-glass corrosion mechanisms. NatureSantarini (2008). SON68 nuclear glass dissolution kinetics:B. (2006). Nuclear waste glasses – How durable? Elements, 2,

Steefel, Carl

2014-01-01T23:59:59.000Z

278

Tapping on the glass : the intersection of leadership and gender in independent school administration  

E-Print Network (OSTI)

Psychology, 82(6), 920-934. Glass, T. & Franceschini, L. (Schumacher, L. (2005). Has the ‘glass ceiling’ cracked? Anadministrators: A crack in the glass ceiling. Journal of

Ostos, Barbara Escobio

2012-01-01T23:59:59.000Z

279

Glass-like structure of a lead-based relaxor ferroelectric  

Science Journals Connector (OSTI)

On the basis of diffuse scattering analysis, the structure of lead-based relaxors is shown to correspond to the specific dipole glassy state, as opposed to the concept of polar nanoregions.

Bosak, A.

2012-10-10T23:59:59.000Z

280

Metallic Glass Yields Secrets under Pressure | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Structure of the "Swine Flu" Virus Structure of the "Swine Flu" Virus The Package Matters Disarming Deadly South American Hemorrhagic Fever Viruses Pull-Chain "Polymer" Solves Puzzle of Complex Molecular Packing Discovering New Talents for Diamond Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Metallic Glass Yields Secrets under Pressure MARCH 29, 2010 Bookmark and Share Diamond anvil cell used for high-pressure experiments Metallic glasses are emerging as potentially useful materials at the frontier of materials science research. They combine the advantages-and avoid many of the problems of-normal metals and glasses, two classes of materials with a very wide range of applications. For example, metallic

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Magnesium phosphate glass cements with ceramic-type properties  

DOE Patents (OSTI)

Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

1984-03-13T23:59:59.000Z

282

Magnesium-phosphate-glass cements with ceramic-type properties  

DOE Patents (OSTI)

Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

Sugama, T.; Kukacka, L.E.

1982-09-23T23:59:59.000Z

283

Vacuum fusion bonding of glass plates  

DOE Patents (OSTI)

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2001-01-01T23:59:59.000Z

284

Vacuum fusion bonding of glass plates  

DOE Patents (OSTI)

An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

2000-01-01T23:59:59.000Z

285

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

286

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-07-15T23:59:59.000Z

287

Effect of glass composition on waste form durability: A critical review  

SciTech Connect

This report reviews literature concerning the relationship between the composition and durability of silicate glasses, particularly glasses proposed for immobilization of radioactive waste. Standard procedures used to perform durability tests are reviewed. It is shown that tests in which a low-surface area sample is brought into contact with a very large volume of solution provide the most accurate measure of the intrinsic durability of a glass composition, whereas high-surface area/low-solution volume tests are a better measure of the response of a glass to changes in solution chemistry induced by a buildup of glass corrosion products. The structural chemistry of silicate and borosilicate glasses is reviewed to identify those components with the strongest cation-anion bonds. A number of examples are discussed in which two or more cations engage in mutual bonding interactions that result in minima or maxima in the rheologic and thermodynamic properties of the glasses at or near particular optimal compositions. It is shown that in simple glass-forming systems such interactions generally enhance the durability of glasses. Moreover, it is shown that experimental results obtained for simple systems can be used to account for durability rankings of much more complex waste glass compositions. Models that purport to predict the rate of corrosion of glasses in short-term durability tests are evaluated using a database of short-term durability test results for a large set of glass compositions. The predictions of these models correlate with the measured durabilities of the glasses when considered in large groupings, but no model evaluated in this review provides accurate estimates of durability for individual glass compositions. Use of these models in long-term durability models is discussed. 230 refs.

Ellison, A.J.G.; Mazer, J.J.; Ebert, W.L. [Argonne National Lab., IL (United States). Chemical Technology Div.

1994-11-01T23:59:59.000Z

288

Static structure factor of a suspension of charge-stabilized colloids: Application to liquid-glass transition phase diagram and to micellar solution  

E-Print Network (OSTI)

-glass transition phase diagram and to micellar solution S. K. Lai, J. L. Wang, and G. F. Wang Department of Physics approximately. We contrast the liquid-glass transition phase boundary determined from the latter model approximation MSA . For point-like small ions counterions and electrolyte , this so-called primitive model PM

289

The Glass-like Structure of Globular Proteins and the Boson Peak  

E-Print Network (OSTI)

Vibrational spectra of proteins and topologically disordered solids display a common anomaly at low frequencies, known as Boson peak. We show that such feature in globular proteins can be deciphered in terms of an energy landscape picture, as it is for glassy systems. Exploiting the tools of Euclidean random matrix theory, we clarify the physical origin of such anomaly in terms of a mechanical instability of the system. As a natural explanation, we argue that such instability is relevant for proteins in order for their molecular functions to be optimally rooted in their structures.

Stefano Ciliberti; Paolo De Los Rios; Francesco Piazza

2005-11-23T23:59:59.000Z

290

Glass Buttes Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Glass Buttes Geothermal Area Glass Buttes Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Buttes Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (1) 9 Exploration Activities (14) 10 References Area Overview Geothermal Area Profile Location: Oregon Exploration Region: Cascades GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed. Add a new Operating Power Plant Developing Power Projects: 0

291

Pu Glass Fabrication and Product Consistency Testing  

SciTech Connect

The DOE/EM plans to conduct the Plutonium Vitrification Project at the Savannah River Site (SRS). An important part of this project is to reduce the attractiveness of the plutonium by fabricating a plutonium glass form and immobilizing the Pu form within the high level waste (HLW) glass prepared in the Defense Waste Processing Facility (DWPF). This requires that a project schedule that is consistent with EM plans for DWPF and cleanup of the SRS be developed. Critical inputs to key decisions in the vitrification project schedule are near-term data that will increase confidence that lanthanide borosilicate (LaBS) glass product is suitable for disposal in the Yucca Mountain Repository. A workshop was held on April 28, 2005 at Bechtel SAIC Company facility in Las Vegas, NV to define the near term data needs. Dissolution rate data and the fate of plutonium oxide and the neutron absorbers during the dissolution process were defined as key data needs. A suite of short-term tests were defined at the workshop to obtain the needed data. The objectives of these short-term tests are to obtain data that can be used to show that the dissolution rate of a LaBS glass is acceptable and to show that the extent of Pu separation from neutron absorbers, as the glass degrades and dissolves, is not likely to lead to criticality concerns. An additional data need was identified regarding the degree of macroscopic cracking that occurs during processing of the Pu glass waste form and subsequent pouring of HLW glass in the DWPF. A final need to evaluate new frit formulations that may increase the durability of the plutonium glass and/or decrease the degree to which neutron absorbers separate from the plutonium during dissolution was identified. This task plan covers testing to support a near term data need regarding glass dissolution performance. Separate task plans will be developed for testing to address the degree of macroscopic cracking and the development of alternative frit formulations. The Product Consistency Test (PCT) was identified as a means to provide some of the near term performance data. The PCT is a static test method in which known masses of crushed glass and demineralized water are reacted for a desired duration [1]. There are two reasons to perform the PCT. The first is that the results are used as a measure of acceptance in the Waste Acceptance Product Specifications Document (WAPS) [2]. The second is the need for long-term static test results that can be used to verify the applicability of the degradation model. Thus, the primary focus will be on the use of the PCT Method B (PCT-B) to study the formation and stability of colloids and to study alteration phases formed on the glass surface. The standard 7-day PCT in demineralized water (PCT-A) will be included to demonstrate compliance with the waste acceptance criterion and determine the value of the k{sub E} rate parameter for comparison with the Defense HLW Glass Degradation Model [3].

Marra, James

2005-06-29T23:59:59.000Z

292

Glass/ceramic coatings for implants  

DOE Patents (OSTI)

Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

2011-09-06T23:59:59.000Z

293

Glass Frit Clumping And Dusting  

SciTech Connect

DWPF mixes a slurry of glass frit (Frit 418) and dilute (1.5 wt%) formic acid solution with high level waste in the Slurry Mix Evaporator (SME). There would be advantages to introducing the frit in a non-slurry form to minimize water addition to the SME, however, adding completely dry frit has the potential to generate dust which could clog filters or condensers. Prior testing with another type of frit, Frit 320, and using a minimal amount of water reduced dust generation, however, the formation of hard clumps was observed. To examine options and behavior, a TTQAP [McCabe and Stone, 2013] was written to initiate tests that would address these concerns. Tests were conducted with four types of glass frit; Frit 320, DWPF Frit 418, Bekeson Frit 418 and Multi-Aspirator Frit 418. The last two frits are chemically identical to DWPF Frit 418 but smaller particles were removed by the respective vendors. Test results on Frit Clumping and Dusting are provided in this report. This report addresses the following seven questions. Short answers are provided below with more detailed answers to follow. 1. Will the addition of a small amount of water, 1.5 wt%, to dry DWPF Frit 418 greatly reduce the dust generation during handling at DWPF? a. Yes, a small scale test showed that adding a little water to the frit greatly reduced dust generation during handling. 2. Will the addition of small amounts of water to the frit cause clumping that will impair frit handling at DWPF? a. No, not with Frit 418. Although clumps were observed to form when 1.5 wt% water was mixed with DWPF Frit 418, then compressed and air-dried overnight, the clumps were easily crushed and did not form the hardened material noted when Frit 320 was tested. 3. What is the measured size distribution of dust generated when dry frit is handled? (This affects the feasibility and choice of processing equipment for removing the dust generating fraction of the frit before it is added to the SME.) a. The size distribution for the dust removed from fresh DWPF Frit 418 while it was being shaken in a small scale LabRAM test was measured. The median size on a volume basis was 7.6 ?m and 90% of the frit particles were between 1.6 and 28 ?m. The mass of dust collected using this test protocol was much less than 1% of the original frit. 4. Can the dust be removed in a small number of processing steps and without the larger frit particles continuing to spall additional dust sized particles? a. Test results using a LabRAM were inconclusive. The LaRAM performs less efficient particle size separation than the equipment used by Bekeson and Multi-Aspirator. 5. What particle size of frit is expected to create a dust problem? a. The original criterion for creating a dusting problem was those particle sizes that were readily suspended when being shaken. For that criterion calculations and Microtrac size analyses indicated that particles smaller than 37 ?m are likely dust generators. Subsequently a more sophisticated criterion for dust problem was considered, particle sizes that would become suspended in the air flow patterns inside the SME and possibly plug the condenser. That size may be larger than 37 ?m but has not yet been determined. 6. If particles smaller than 37 ?m are removed will bulk dust generation be eliminated? a. Video-taped tests were performed using three gallons each of three types of frit 418, DWPF frit, Bekeson frit and Multi-Aspirator frit. Frit was poured through air from a height of approximately eight feet into a container half filled with water. Pouring Bekeson frit or Multi-Aspirator frit generated markedly less visible dust, but there was still a significant amount, which still has the potential of causing a dust problem. 7. Can completely dry frit be poured into the SME without having dust plug the condenser at the top of the vessel? a. Because of the complexity of air currents inside the SME and the difficulty of defensible size scaling a more prototypical test will be required to answer this question. We recommend construction of a full scale

Steimke, J. L.

2013-09-26T23:59:59.000Z

294

Direction of CRT waste glass processing: Electronics recycling industry communication  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Given a large flow rate of CRT glass {approx}10% of the panel glass stream will be leaded. Black-Right-Pointing-Pointer The supply of CRT waste glass exceeded demand in 2009. Black-Right-Pointing-Pointer Recyclers should use UV-light to detect lead oxide during the separation process. Black-Right-Pointing-Pointer Recycling market analysis techniques and results are given for CRT glass. Black-Right-Pointing-Pointer Academic initiatives and the necessary expansion of novel product markets are discussed. - Abstract: Cathode Ray Tube, CRT, waste glass recycling has plagued glass manufacturers, electronics recyclers and electronics waste policy makers for decades because the total supply of waste glass exceeds demand, and the formulations of CRT glass are ill suited for most reuse options. The solutions are to separate the undesirable components (e.g. lead oxide) in the waste and create demand for new products. Achieving this is no simple feat, however, as there are many obstacles: limited knowledge of waste glass composition; limited automation in the recycling process; transportation of recycled material; and a weak and underdeveloped market. Thus one of the main goals of this paper is to advise electronic glass recyclers on how to best manage a diverse supply of glass waste and successfully market to end users. Further, this paper offers future directions for academic and industry research. To develop the recommendations offered here, a combination of approaches were used: (1) a thorough study of historic trends in CRT glass chemistry; (2) bulk glass collection and analysis of cullet from a large-scale glass recycler; (3) conversations with industry members and a review of potential applications; and (4) evaluation of the economic viability of specific uses for recycled CRT glass. If academia and industry can solve these problems (for example by creating a database of composition organized by manufacturer and glass source) then the reuse of CRT glass can be increased.

Mueller, Julia R., E-mail: mueller.143@osu.edu [Ohio State University, William G. Lowrie Department of Chemical and Biomolecular Engineering, OH (United States) and University of Queensland, School of Chemical Engineering (Australia) and Ohio State University, Materials Science and Engineering, OH (United States); Boehm, Michael W. [University of Queensland, School of Chemical Engineering (Australia); Drummond, Charles [Ohio State University, Materials Science and Engineering, OH (United States)

2012-08-15T23:59:59.000Z

295

GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE GLASS FOR PLUTONIUM DISPOSITION  

SciTech Connect

The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) in Aiken, SC, to disposition excess weapons-usable plutonium. A plutonium glass waste form is a leading candidate for immobilization of the plutonium for subsequent disposition in a geologic repository. The objectives of this present task were to fabricate plutonium-loaded lanthanide borosilicate (LaBS) Frit B glass and perform testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the proposed Federal Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit B composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support glass durability testing via the ASTM Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL). The glass was characterized with X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. This characterization revealed some crystalline PuO{sub 2} inclusions with disk-like morphology present in the as fabricated, quench-cooled glass. A series of PCTs was conducted at SRNL with varying exposed surface area and test durations. Filtered leachates from these tests were analyzed to determine the dissolved concentrations of key elements. The leachate solutions were also ultrafiltered to quantify colloid formation. Leached solids from select PCTs were examined in an attempt to evaluate the Pu and neutron absorber release behavior from the glass and to investigate formation of alteration phases on the glass surface. A series of PCTs was conducted at 90 C in ASTM Type 1 water to compare the Pu LaBS Frit B glass durability to current requirements for High Level Waste (HLW) glass in a geologic repository. The PCT (7-day static test with powdered glass) results on the Pu-containing LaBS Frit B glass at SA/V of {approx} 2000 m{sup -1} showed that the glass was very durable with an average normalized elemental release value for boron of 0.013 g/m{sup 2}. This boron release value is {approx} 640X lower than normalized boron release from current Environmental Assessment (EA) glass used for repository acceptance. The PCT-B (7, 14, 28 and 56-day, static test with powdered glass) normalized elemental releases were similar to the normalized elemental release values from PCT-A testing, indicating that the LaBS Frit B glass is very durable as measured by the PCT. Normalized plutonium releases were essentially the same within the analytical uncertainty of the ICP-MS methods used to quantify plutonium in the 0.45 {micro}m-filtered leachates and ultra-filtered leachates, indicating that colloidal plutonium species do not form under the PCT conditions used in this study.

Crawford, C; James Marra, J; Ned Bibler, N

2007-02-12T23:59:59.000Z

296

PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS  

SciTech Connect

The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

2011-01-04T23:59:59.000Z

297

Scaling of fluctuations in a colloidal glass  

E-Print Network (OSTI)

We report experimental measurements of particle dynamics in a colloidal glass in order to understand the dynamical heterogeneities associated with the cooperative motion of the particles in the glassy regime. We study the local and global fluctuation of correlation and response functions in an aging colloidal glass. The observables display universal scaling behavior following a modified power-law, with a plateau dominating the less heterogeneous short-time regime and a power-law tail dominating the highly heterogeneous long-time regime.

P. Wang; C. Song; H. A. Makse

2006-11-01T23:59:59.000Z

298

Role of Quantum Effects in the GlassTransition.  

SciTech Connect

It is shown that quantum effects lead to a significant decrease of the glass transition temperature Tg with respect to the melting temperature Tm, so that the ratio Tg=Tm can be much smaller than the typical value of 2=3 in materials where Tg is near or below 60 K. Furthermore, it is demonstrated that the viscosity or structural relaxation time in such low temperature glass formers should exhibit highly unusual temperature dependence, namely a decrease of the apparent activation energy upon approaching Tg (instead of traditional increase).

Novikov, Vladimir [ORNL; Sokolov, Alexei P [ORNL

2013-01-01T23:59:59.000Z

299

Spin-glass model of QCD near saturation  

E-Print Network (OSTI)

We establish a connection between the cascading of gluon momenta modeled with the diffusive approximation of the Balitsky-Fadin-Kuraev-Lipatov kernel and the thermodynamics of directed polymers on a tree with disorder. Using known results on the low-temperature spin-glass phase of this statistical-mechanic problem we describe the dynamical phase space of gluon transverse momenta near saturation including its fluctuation pattern. It exhibits a nontrivial clustering structure, analoguous to ``hot spots'', whose distributions are derived and possess universal features in common with other spin-glass systems.

Robi Peschanski

2006-02-10T23:59:59.000Z

300

Self-powdering and nonlinear optical domain structures in ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals formed in glass  

SciTech Connect

Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3}, (GMO), crystals are formed through the crystallization of 21.25Gd{sub 2}O{sub 3}-63.75MoO{sub 3}-15B{sub 2}O{sub 3} glass (mol%), and two scientific curious phenomena are observed. (1) GMO crystals formed in the crystallization break into small pieces with a triangular prism or pyramid shape having a length of 50-500 {mu}m spontaneously during the crystallizations in the inside of an electric furnace, not during the cooling in air after the crystallization. This phenomenon is called 'self-powdering phenomenon during crystallization' in this paper. (2) Each self-powdered GMO crystal grain shows a periodic domain structure with different refractive indices, and a spatially periodic second harmonic generation (SHG) depending on the domain structure is observed. It is proposed from polarized micro-Raman scattering spectra and the azimuthal dependence of second harmonic intensities that GMO crystals are oriented in each crystal grain and the orientation of (MoO{sub 4}){sup 2-} tetrahedra in GMO crystals changes periodically due to spontaneous strains in ferroelastic GMO crystals. - Graphical abstract: This figure shows the polarized optical photograph at room temperature for a particle (piece) obtained by a heat treatment of the glass at 590 deg. C for 2 h in an electric furnace in air. This particle was obtained through the self-powdering behavior in the crystallization of glass. The periodic domain structure is observed. Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals are formed in the particle, and second harmonic generations are detected, depending on the domain structure.

Tsukada, Y.; Honma, T. [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Komatsu, T., E-mail: komatsu@mst.nagaokaut.ac.j [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2009-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Development of a Procedure to Evaluate the Shear Modulus of Laminated Glass Interlayers  

E-Print Network (OSTI)

Laminated glass is comprised of multiple glass plates coupled together in a sandwich construction through the use of a polymorphous interlayer that acts as a bonding agent between the glass plates. Laminated glass offers several advantages over...

Brackin, Michael S.

2010-07-14T23:59:59.000Z

302

BUILD YOUR OWN 3D GLASSES! Oaktag (sturdy poster board)  

E-Print Network (OSTI)

BUILD YOUR OWN 3D GLASSES! Materials · Oaktag (sturdy poster board) · Scissors · Clear tape · Basic or sturdy poster board. Cut the glasses out making sure to also cut out the eyeholes. Step 3 Tape the red

Christian, Eric

303

Heavy Metals in Glass Beads Used in Pavement Markings  

E-Print Network (OSTI)

Pavement markings are vital for safely navigating roadways. The nighttime visibility of pavement markings is enhanced by addition of retroreflective glass beads, most of which are made from recycled glass. Concern has been raised over the presence...

Mangalgiri, Kiranmayi

2012-07-16T23:59:59.000Z

304

Bioresistance of Foam-Glass Crystal Materials to Filamentous Fungi  

Science Journals Connector (OSTI)

Foam-glass crystal (FGC) materials used for heat insulation obtained by the technology described in [7...] were chosen for the present study. It is known that foam glass is environmentally harmless and safe for ....

O. V. Kaz’mina; M. A. Dushkina; M. V. Chubik

2014-01-01T23:59:59.000Z

305

Combustion Technology Development for an Advanced Glass Melting System  

E-Print Network (OSTI)

Concept feasibility of an innovative technology for glass production has recently been demonstrated. It is based on suspension heating of the glass-forming batch minerals while entrained in a combustion flow of preheated air and natural gas...

Stickler, D. B.; Westra, L.; Woodroffe, J.; Jeong, K. M.; Donaldson, L. W.

306

EFFECT OF GLASS COMPOSITION ON ACTIVATION ENERGY OF VISCOSITY...  

NLE Websites -- All DOE Office Websites (Extended Search)

EFFECT OF GLASS COMPOSITION ON ACTIVATION ENERGY OF VISCOSITY IN GLASS-MELTING-TEMPERATURE RANGE Sang-Soo Han (1) , Pavel Hrma (1,2) (1) Division of Advanced Nuclear Engineering,...

307

Iodine Solubility in Low-Activity Waste Borosilicate Glass at...  

NLE Websites -- All DOE Office Websites (Extended Search)

Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 °C. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 °C. Abstract: The purpose of this...

308

Numerical studies of a one-dimensional three-spin spin-glass model with long-range interactions  

E-Print Network (OSTI)

We study a p-spin spin-glass model to understand if the finite-temperature glass transition found in the mean-field regime of p-spin models, and used to model the behavior of structural glasses, persists in the nonmean-field regime. By using a three...

Larson, Derek; Katzgraber, Helmut G.; Moore, M. A.; Young, A. P.

2010-01-01T23:59:59.000Z

309

IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION KT07-SERIES GLASS COMPOSITIONS  

SciTech Connect

This report is the third in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility is also considered in the study. The KT07-series glasses were selected to evaluate any potential impacts of noble metals on their properties and performance. The glasses characterized thus far for the SCIX study have not included noble metals since they are not typically tracked in sludge batch composition projections. However, noble metals can act as nucleation sites in glass melts, leading to enhanced crystallization. This crystallization can potentially influence the properties and performance of the glass, such as chemical durability, viscosity, and liquidus temperature. The noble metals Ag, Pd, Rh, and Ru were added to the KT07-series glasses in concentrations based on recent measurements of Sludge Batch 6, which was considered to contain a high concentration of noble metals. The KT04-series glasses were used as the baseline compositions. After fabrication, the glasses were characterized to determine their homogeneity, chemical composition, durability, and viscosity. Liquidus temperature measurements are also underway but were not complete at the time of this report. The liquidus temperature results for the KT07-series glasses, along with several of the earlier glasses in the SCIX study, will be documented separately. All of the KT07-series glasses, both quenched and slowly cooled, were found to be amorphous by X-ray diffraction. Chemical composition measurements showed that all of the glasses met their targeted compositions. The Product Consistency Test (PCT) results showed that all of the glasses had chemical durabilities that were far better than that of the Environmental Assessment benchmark glass. The measured PCT responses were well predicted by the current DWPF Product Composition Control System (PCCS) durability models. The measured viscosity values for each KT07-series glass were acceptable for DWPF processing and were well predicted by the current PCCS model. Overall, the results show that the inclusion of relatively high concentrations of noble metals (in terms of expected values for a DWPF sludge batch) had no significant impact on the properties and performance of these glass compositions. There were no significant differences in the measured properties when compared to those of the KT04-series glasses, which did not contain noble metals. Liquidus temperature measurements are still underway and there may be an impact of the noble metals on those measurements. However, no adverse effects were noted in terms of crystallization after slow cooling. At the completion of these studies, all of the data generated will be reviewed with regard to the applicability of the DWPF PCCS models and recommendations will be made as to whether the validation ranges of the current models can be extended, or whether some or all of the models need to be refit to allow for the incorporation of the SCIX streams. As changes are made to the projected sludge compositions and the volume of the SCIX material, additional evaluations should be performed.

Fox, K.; Edwards, T.

2011-01-12T23:59:59.000Z

310

Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon  

Energy.gov (U.S. Department of Energy (DOE))

Innovative Exploration Technologies Maui Hawii & Glass Buttes, Oregon presentation at the April 2013 peer review meeting held in Denver, Colorado.

311

Magnetotellurics At Glass Mountain Area (Cumming And Mackie,...  

Open Energy Info (EERE)

Area (Cumming And Mackie, 2007) Exploration Activity Details Location Glass Mountain Geothermal Area Exploration Technique Magnetotellurics Activity Date Usefulness useful...

312

condmat/9801215 Crossovers in the Two Dimensional Ising Spin Glass  

E-Print Network (OSTI)

cond­mat/9801215 v2 26 Jan 1998 Crossovers in the Two Dimensional Ising Spin Glass of extensive computer simulations we analyze in detail the two dimen­ sional \\SigmaJ Ising spin glass Introduction At present it is clear that the lower critical dimension of Edwards­Anderson Ising spin glasses

Roma "La Sapienza", Università di

313

A new method for solving radiative heat problems in glass  

E-Print Network (OSTI)

RANA 99-06 A new method for solving radiative heat problems in glass B.J. van der Linden -- R, The Netherlands e-mail: linden@win.tue.nl 15th May 2000 #12;Abstract In the production of glass, temperature plays Conclusion 25 2 #12;Chapter 1 Introduction The production of glass belongs to the oldest forms of human

Eindhoven, Technische Universiteit

314

The Polishing, Surface Flow and Wear of Diamond and Glass  

Science Journals Connector (OSTI)

...Polishing, Surface Flow and Wear of Diamond and Glass F. P. Bowden H. G. Scott It has been shown that a diamond sliding on glass can under suitable conditions induce surface flow of the glass. The speed (v) and load (W) necessary to cause...

1958-01-01T23:59:59.000Z

315

GLASS TRANSITION SEEN THROUGH ASYMPTOTIC JULIEN OLIVIER AND MICHAEL RENARDY  

E-Print Network (OSTI)

GLASS TRANSITION SEEN THROUGH ASYMPTOTIC EXPANSIONS JULIEN OLIVIER AND MICHAEL RENARDY Abstract of the model at low shear rate changes when a certain parameter (which we call the glass parameter) crosses´ebraud-Lequeux model, a Fokker-Planck-like description of soft glassy material, exhibits such a glass transition

316

A new method for solving radiative heat problems in glass  

E-Print Network (OSTI)

RANA 99­06 A new method for solving radiative heat problems in glass B.J. van der Linden --- R, The Netherlands e­mail: linden@win.tue.nl 15th May 2000 #12; Abstract In the production of glass, temperature Conclusion 25 2 #12; Chapter 1 Introduction The production of glass belongs to the oldest forms of human

Eindhoven, Technische Universiteit

317

Calorimetric glass transition explained by hierarchical dynamic facilitation  

E-Print Network (OSTI)

Calorimetric glass transition explained by hierarchical dynamic facilitation Aaron S. Keysa Contributed by David Chandler, February 11, 2013 (sent for review November 15, 2012) The glass transition different on cooling than on heating, and the response to melting a glass depends markedly on the cooling

Garrahan, Juan P.

318

Rectilinear Glass-Cut Dissections of Rectangles to Squares  

E-Print Network (OSTI)

Rectilinear Glass-Cut Dissections of Rectangles to Squares Jurek Czyzowicz§ czyzowic is made using only rectilinear glass-cuts, i.e., vertical or horizontal straight-line cuts separating pieces into two. 1 Introduction A glass-cut of a rectangle is a cut by a straight-line segment

Urrutia, Jorge

319

Saga of Glass Damage in Urban Environments Continues  

E-Print Network (OSTI)

Saga of Glass Damage in Urban Environments Continues: Consequences of Aerodynamics and Debris Laboratory University of Notre Dame The Saga of Glass Damage in Urban Environments Continues: Consequences east of the city of Houston. Initial reconnaissance suggested that the observed glass/cladding damage

Kareem, Ahsan

320

5D Data Storage by Ultrafast Laser Nanostructuring in Glass  

E-Print Network (OSTI)

5D Data Storage by Ultrafast Laser Nanostructuring in Glass Jingyu Zhang* , Mindaugas Gecevicius-assembled form birefringence and retrieved in glass opening the era of unlimited lifetime data storage. © 2013 laser writing in glass were proposed for the polarization multiplexed optical memory, where

Anderson, Jim

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Detection of Strength-Impairing Surface Flaws in Glass  

Science Journals Connector (OSTI)

...of Strength-Impairing Surface Flaws in Glass F. M. Ernsberger Experiments have shown...sodium vapour treatment on the surface of glass (Andrade Tsien 1937) are fractures due...can also be developed, in soda-lime glass, by treatment with a molten lithium salt...

1960-01-01T23:59:59.000Z

322

The Adhesion of Evaporated Metal Films on Glass  

Science Journals Connector (OSTI)

...The Adhesion of Evaporated Metal Films on Glass P. Benjamin C. Weaver The adhesion of...deposited by vacuum techniques on to a glass surface have been examined. It has been...intermediate oxide layer at the metal/glass interface is necessary for good adhesion...

1961-01-01T23:59:59.000Z

323

Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics  

E-Print Network (OSTI)

Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics Gregor Vilkner Submitted Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics Gregor Vilkner Thin sheet concrete crushed glass as aggregate, a multitude of different esthetic effects can be produced, which again open up

Meyer, Christian

324

A Phase-Field Model for Phase Transformations in Glass-Forming Alloys  

SciTech Connect

A phase-field model is proposed for phase transformations in glass-forming alloys. The glass transition is introduced as a structural relaxation, and the competition between the glass and crystalline phases is investigated. The simulations are performed for Cu-Zr alloys, employing thermodynamic and kinetic parameters derived from reported thermodynamic modeling and molecular dynamics simulation results,[1–3] respectively. Four distinct phase fields are treated with a multi-phase-field approach, representing the liquid/glass, Cu10Zr7, CuZr, and CuZr2 phases. In addition, a continuum-field method is applied to the liquid to accommodate the liquid–glass transformation. The combined phase-field approach is used to investigate the glass formation tendency, and critical cooling rates are estimated and compared with the reported experimental values.

Wang, Tao; Napolitano, Ralph E.

2012-03-24T23:59:59.000Z

325

Glass Forming Ability and Relaxation Behavior of Zr Based Metallic Glasses  

E-Print Network (OSTI)

Metallic glasses can be considered for many commercial applications because of the higher mechanical strength, corrosion and wear resistance when compared to crystalline materials. To consider them for novel applications, the challenge of preparing...

Kamath, Aravind Miyar

2012-07-16T23:59:59.000Z

326

Nanodiamond in tellurite glass Part I: origin of loss in nanodiamond-doped glass  

E-Print Network (OSTI)

Tellurite glass fibers with embedded nanodiamond are attractive materials for quantum photonic applications. Reducing the loss of these fibers in the 600-800 nm wavelength range of nanodiamond fluorescence is essential to exploit the unique properties of nanodiamond in the new hybrid material. In the first part of this study, we report the effect of interaction of the tellurite glass melt with the embedded nanodiamond on the loss of the glasses. The glass fabrication conditions such as melting temperature and concentration of NDs added to the melt were found to have critical influence on the interaction. Based on this understanding, we identified promising fabrication conditions for decreasing the loss to levels required for practical applications.

Ebendorff-Heidepriem, Heike; Ji, Hong; Greentree, Andrew D; Gibson, Brant C; Monro, Tanya M

2014-01-01T23:59:59.000Z

327

Optical glass and glass ceramic historical aspects and recent developments: a Schott view  

Science Journals Connector (OSTI)

Since the time of Galilei 400 years ago the progress of optical systems was restricted due to the lack of optical glass types with different dispersion properties and due to poor...

Hartmann, Peter; Jedamzik, Ralf; Reichel, Steffen; Schreder, Bianca

2010-01-01T23:59:59.000Z

328

Heisenberg-Ising crossover in spin glasses  

Science Journals Connector (OSTI)

The small anisotropy always present in real spin glasses induces a finite-temperature phase transition of Ising character. We argue that the width of the Ising-like critical regime should be comparable with teh transition temperature itself. Furthermore, for realistic values of the anisotropy there is no well-defined Heisenberg-like critical regime at all.

A. J. Bray and M. A. Moore

1986-11-01T23:59:59.000Z

329

Glass fiber channels laser light to robot  

Science Journals Connector (OSTI)

Glass fiber channels laser light to robot ... In a demonstration of the technique, a fiberoptic cable carried a laser beam of more than 10,000 W of peak power—400 W average—from a neodymiumyttrium- aluminum-garnet laser to an industrial robot more than 25 yards away. ...

1983-11-28T23:59:59.000Z

330

Condensed matter: Through a glass, lightly  

Science Journals Connector (OSTI)

... allow detection of atomic jump rates. The authors use an unusual spin alignment echo (SAE) technique to detect Be hopping in the bulk metallic glass. They consider with care ... of the echo decay from the 9Be atoms; its pure exponential form confirms that the SAE technique detects unconstrained hopping that contributes fully to long-range atomic transport and is not ...

A. Lindsay Greer

1999-11-11T23:59:59.000Z

331

DWPF Glass Melter Technology Manual: Volume 3  

SciTech Connect

This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics discussed include: Information collected during testing, equipment, materials, design basis, feed tubes, and an evaluation of the performance of various components. Information is conveyed using many diagrams and photographs.

Iverson, D.C.

1993-12-31T23:59:59.000Z

332

Thermodynamics of the Lévy spin glass  

Science Journals Connector (OSTI)

We investigate the Lévy glass, a mean-field spin-glass model with power-law distributed couplings characterized by a divergent second moment. By combining extensively many small couplings with a spare random backbone of strong bonds the model is intermediate between the Sherrington-Kirkpatrick and the Viana-Bray models. A truncated version where couplings smaller than some threshold ? are neglected can be studied within the cavity method developed for spin glasses on locally treelike random graphs. By performing the limit ??0 in a well-defined way we calculate the thermodynamic functions within replica symmetry and determine the de Almeida-Thouless line in the presence of an external magnetic field. Contrary to previous findings we show that there is no replica-symmetric spin-glass phase. Moreover we determine the leading corrections to the ground-state energy within one-step replica symmetry breaking. The effects due to the breaking of replica symmetry appear to be small in accordance with the intuitive picture that a few strong bonds per spin reduce the degree of frustration in the system.

K. Janzen; A. Engel; M. Mézard

2010-08-30T23:59:59.000Z

333

The Color Glass Condensate and some applications  

E-Print Network (OSTI)

We give an elementary discussion of parton saturation and its description by the effective theory of the Color Glass Condensate. We report on progress in calculating multi-gluon correlators. The latter are necessary for many phenomenological applications, upon some of which we briefly touch.

D. N. Triantafyllopoulos

2012-09-14T23:59:59.000Z

334

How a liquid becomes a glass both on cooling and on heating  

E-Print Network (OSTI)

The onset of structural arrest and glass formation in a concentrated suspension of silica nanoparticles in a water-lutidine binary mixture near its consolute point is studied by exploiting the near-critical fluid degrees of freedom to control the strength of an attraction between particles and multispeckle x-ray photon correlation spectroscopy to determine the particles' collective dynamics. This model system undergoes a glass transition both on cooling and on heating, and the intermediate liquid realizes unusual logarithmic relaxations. How vitrification occurs for the two different glass transitions is characterized in detail and comparisons are drawn to recent theoretical predictions for glass formation in systems with attractive interactions.

Xinhui Lu; S. G. J. Mochrie; S. Narayanan; A. R. Sandy; M. Sprung

2007-08-27T23:59:59.000Z

335

Blocking effect of crystal–glass interface in lanthanum doped barium strontium titanate glass–ceramics  

SciTech Connect

Graphical abstract: The blocking effect of the crystal–glass interface on the carrier transport behavior in the lanthanum doped barium strontium titanate glass–ceramics: preparation and characterization. - Highlights: • La{sub 2}O{sub 3} addition promotes the crystallization of the major crystalline phase. • The Z? and M? peaks exist a significant mismatch for 0.5 mol% La{sub 2}O{sub 3} addition. • The Z? and M? peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. • Crystallite impedance decreases while crystal–glass interface impedance increases. • La{sub 2}O{sub 3} addition increases blocking factor of the crystal–glass interface. - Abstract: The microstructures and dielectric properties in La{sub 2}O{sub 3}-doped barium strontium titanate glass–ceramics have been investigated by scanning electron microscopy (SEM) and impedance spectroscopy. SEM analysis indicated that La{sub 2}O{sub 3} additive decreases the average crystallite size. Impedance spectroscopy revealed that the positions of Z? and M? peaks are close for undoped samples. When La{sub 2}O{sub 3} concentration is 0.5 mol%, the Z? and M? peaks show a significant mismatch. Furthermore, these peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. With increasing La{sub 2}O{sub 3} concentration, the contribution of the crystallite impedance becomes smaller, while the contribution of the crystal–glass interface impedance becomes larger. More interestingly, it was found that La{sub 2}O{sub 3} additive increases blocking factor of the crystal–glass interface in the temperature range of 250–450 °C. This may be attributed to a decrease of activation energy of the crystallite and an increase of the crystal–glass interface area.

Wang, Xiangrong [Beijing Fine Ceramics Laboratory, State Key Laboratory of New Ceramics and Fine Processing, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Zhang, Yong, E-mail: yzhang@tsinghua.edu.cn [Beijing Fine Ceramics Laboratory, State Key Laboratory of New Ceramics and Fine Processing, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Baturin, Ivan [Ferroelectric Laboratory, Institute of Natural Science, Ural Federal University, Ekaterinburg 620000 (Russian Federation); Liang, Tongxiang [Beijing Fine Ceramics Laboratory, State Key Laboratory of New Ceramics and Fine Processing, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

2013-10-15T23:59:59.000Z

336

The development of design factors for heat-strengthened and tempered glass based on the glass failure prediction model  

E-Print Network (OSTI)

THE DEVELOPMENT OF DESIGN FACTORS FOR HEAT-STRENGTHENED AND TEMPERED GLASS BASED ON THE GLASS FAILURE PREDICTION MODEL A Thesis by Timothy Andrew Oakes Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE Decypber 199$ Major Subject: Civil Engineering THE DEVELOPMENT OF DESIGN FACTORS FOR HEAT-STRENGTHENED AND TEMPERED GLASS BASED ON THE GLASS FAILURE PREDICTION MODEL A Thesis...

Oakes, Timothy Andrew

1991-01-01T23:59:59.000Z

337

Glass and glass-ceramics transparent from the visible range to the mid-infrared for night vision  

Science Journals Connector (OSTI)

Many papers report studies on oxyfluorides glass-ceramics combining the optical advantage of fluoride environment for rare earth with the thermal and chemical advantages of oxide glasses [1â??7], or on oxide-based glass-ceramics exhibiting exceptional thermo-mechanical properties such as zero thermal expansion coefficient. The transparency of these glass-ceramics is limited in the infrared region up to 4 µm [8â??12]. In this paper, we report the last results on totally new infrared transmitting chalcogenide glass-ceramics which are transparent up to 11 µm for sulphur based glass or up to 16 µm for selenium based glass. By selecting appropriate glass composition in several Ge-(Sb/Ga)-(S/Se)-MX (MX: alkali halide) systems, glass-ceramics with different microcrystals volume fraction can be reproducibly obtained by controlling nucleation and crystallisation annealing time and temperatures. It has been demonstrated that crystals smaller than 200 nm induce some additional losses only in the short wavelength region. The glass ceramics keep the same transmission as the original glass from 1 µm up to 11 µm or 16 µm. Sulphur based glass-ceramics are still transparent in the second for glass and selenium based glass-ceramics keep an excellent transmission in the second and third atmospheric window. The obtained glass-ceramics exhibit much better resistance to cracks propagation than the corresponding pure glass matrix. Observations under electronic microscopy as well as X-ray diffraction have been used to determinate crystals size, density and crystalline phase. The possibility of combining the ceramisation process and the shaping by moulding has also been demonstrated.

L. Calvez; H-L. Ma; J. Lucas; X.H. Zhang

2008-01-01T23:59:59.000Z

338

Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses  

E-Print Network (OSTI)

Influence of glass polymerisation and oxidation on micro-Raman water analysis in alumino-silicate glasses Maxime Merciera, Andrea Di Muroab , Daniele Giordanoc , Nicole Métricha , Priscille Lesned of an accurate analytical procedure for determination of dissolved water in complex alumino-silicate glasses via

Paris-Sud XI, Université de

339

Glasstech. Ber. Glass Sci. Technol. 75 C2 (2002) 298 Photoinduced Chemical Etching of Silicate and Borosilicate Glasses  

E-Print Network (OSTI)

Glasstech. Ber. Glass Sci. Technol. 75 C2 (2002) 298 Photoinduced Chemical Etching of Silicate and Borosilicate Glasses Leonid B. Glebov, Larissa Glebova and Olena Lopatiuk School of Optics/CREOL, University modification of glasses for electronic applications [1]. Main disadvantage of using this method for optical

Glebov, Leon

340

Photograph from Ruth Glass Obituary in The Times 9th March 1990. Ruth Adele Glass [ne Lazarus] (1912 1990), sociologist, was born on 30 June 1912 in Berlin,  

E-Print Network (OSTI)

RUTH GLASS Photograph from Ruth Glass Obituary in The Times 9th March 1990. Ruth Adele Glass [née, published in 1939, established her reputation as a social scientist. From 1940 until 1942 Ruth Glass College London, which remained her academic base for the rest of her life. In 1951 Ruth Glass became

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Rapid process for producing transparent, monolithic porous glass  

DOE Patents (OSTI)

A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

Coronado, Paul R. (Livermore, CA)

2006-02-14T23:59:59.000Z

342

Energy Efficient Glass Melting - The Next Generation Melter  

SciTech Connect

The objective of this project is to demonstrate a high intensity glass melter, based on the submerged combustion melting technology. This melter will serve as the melting and homogenization section of a segmented, lower-capital cost, energy-efficient Next Generation Glass Melting System (NGMS). After this project, the melter will be ready to move toward commercial trials for some glasses needing little refining (fiberglass, etc.). For other glasses, a second project Phase or glass industry research is anticipated to develop the fining stage of the NGMS process.

David Rue

2008-03-01T23:59:59.000Z

343

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents (OSTI)

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

1995-05-02T23:59:59.000Z

344

Glass transitions in two-dimensional suspensions of colloidal ellipsoids  

E-Print Network (OSTI)

We observed a two-step glass transition in monolayers of colloidal ellipsoids by video microscopy. The glass transition in the rotational degree of freedom was at a lower density than that in the translational degree of freedom. Between the two transitions, ellipsoids formed an orientational glass. Approaching the respective glass transitions, the rotational and translational fastest-moving particles in the supercooled liquid moved cooperatively and formed clusters with power-law size distributions. The mean cluster sizes diverge in power law as approaching the glass transitions. The clusters of translational and rotational fastest-moving ellipsoids formed mainly within pseudo-nematic domains, and around the domain boundaries, respectively.

Zhongyu Zheng; Feng Wang; Yilong Han

2011-05-29T23:59:59.000Z

345

GlassPoint Solar Inc | Open Energy Information  

Open Energy Info (EERE)

GlassPoint Solar Inc GlassPoint Solar Inc Jump to: navigation, search Name GlassPoint Solar Inc. Place San Francisco, California Zip 94105 Sector Solar Product San Francisco-based developer and marketer of solar industrial process heat generating equipment for a wide range of industries including enhanced oil recovery, municipal waste water treatment and electrical power generation. References GlassPoint Solar Inc.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. GlassPoint Solar Inc. is a company located in San Francisco, California . References ↑ "GlassPoint Solar Inc." Retrieved from "http://en.openei.org/w/index.php?title=GlassPoint_Solar_Inc&oldid=345889

346

Fabrication of microstructures on glass by imprinting in conventional furnace for lab-on-chip application  

Science Journals Connector (OSTI)

Imprinting micro structures on glass in conventional furnace instead of vacuum chamber was carried out using a nickel alloy mold which was fabricated by diode-pumped solid state laser writing. The layout is designed to serve for DNA analysis. In the ... Keywords: Conventional furnace, Glass imprinting, Laser direct writing, Ni alloy mold

Qiuling Chen; Qiuping Chen; Gabriele Maccioni; Adriano Sacco; Sergio Ferrero; Luciano Scaltrito

2012-07-01T23:59:59.000Z

347

Loss and modal properties of Ag/AgI hollow glass waveguides  

E-Print Network (OSTI)

-mode transmission is obtained when the thickness of the glass wall is large. These smaller bores, thick wall hollow and industrial applications involving the delivery of CO2 laser radiation, but they have also proven use- ful popular structures is the hollow glass waveguide (HGW) comprised of a silica tube with an inner coating

348

EXAFS studies of sodium silicate glasses containing dissolved actinides  

SciTech Connect

Sodium silicate glasses containing dissolved Th, U, Np, and Pu have been studied using the EXAFS technique. Th/sup 4 +/, U/sup 4 +/, Np/sup 4 +/, and Pu/sup 4 +/ ions in the silicate glasses are 8-fold coordinated to oxygen neighbors. The higher valent U/sup 6 +/ and Np/sup 5 +/ ions have complex local symmetries. The U/sup 6 +/ ions appear in a uranyl configuration with 2 oxygen atoms at 1.85A and 4 at 2.25A from the U ion. The Np/sup 5 +/ local symmetry is more complex and difficult to determine uniquely. The U/sup 6 +/ glasses show substantial clustering of the uranium atoms. A structural model, with nearly planar uranyl sheets sandwiched between alkali and silica layers, is used to explain the U/sup 6 +/ EXAFS data. This model allows us to understand why U/sup 6 +/ ions are much more soluble in the glasses than the actinide 4/sup +/ ions. 4 references, 2 figures.

Knapp, G.S.; Veal, B.W.; Paulikas, A.P.; Mitchell, A.W.; Lam, D.J.; Klippert, T.E.

1984-07-01T23:59:59.000Z

349

Physical origin of chemical trends in glass formation in alkali tellurites: Reconciliation of constraint theory with experiments  

Science Journals Connector (OSTI)

A chemical trend in glass formation with alkali atom (Li, Na, K) in tellurite glasses is recognized, whose physical origin is revealed by a recently formulated approach to the constraint theory of glasses [Phys. Rev. B 60, 11 859 (1999)]. In this work, the parameters appearing in the constraint theory are directly related to quantities derived from atomic structure studies, which facilitates the understanding of glass formation in ionic glasses. As a corollary, the issue of coordination number that has to be considered in the theory, and which has been debated in the literature, is clarified.

R. Aravinda Narayanan

2001-09-11T23:59:59.000Z

350

Correlated excitations and Raman scattering in glasses  

Science Journals Connector (OSTI)

The dominant Raman line in AX2 tetrahedral glasses is demonstrated to be caused by correlated symmetric stretch motions of the bridging X atoms. Using a bond-polarizability model and the central-force model of Sen and Thorpe, we derive simple analytic forms for Raman spectra. We show that correlations may cause qualitative changes in the polarized spectrum leading to a peak at the edge of a band of vibrational states, whereas the depolarized spectrum is less affected and mimics the density of states. Both features are clearly observed in GeO2 and explain features in many other glasses. The same reasoning leads to a prediction of unusual spectral features in electronic spectra of disordered solids which may be observable in angular-dependent photoemission.

Richard M. Martin and Frank L. Galeener

1981-03-15T23:59:59.000Z

351

Nanoscale -structural domains in the phonon-glass thermoelectric material -Zn4Sb3 H. J. Kim,1 E. S. Bozin,1 S. M. Haile,2 G. J. Snyder,2 and S. J. L. Billinge1,  

E-Print Network (OSTI)

Nanoscale -structural domains in the phonon-glass thermoelectric material -Zn4Sb3 H. J. Kim,1 E. S April 2007 A study of the local atomic structure of the promising thermoelectric material -Zn4Sb3, using Thermoelectric materials allow for direct conversion of heat into electrical energy and vice versa. They hold

352

Kinetic Ising Model of the Glass Transition  

Science Journals Connector (OSTI)

A graph theory of single-spin-flip kinetic Ising models is developed and applied to a class of spin models with strongly cooperative dynamics. Self-consistent approximations for the spin time correlation function are presented. One of the dynamical models exhibits a glass transition with no underlying thermodynamic singularity. The approximation for the time correlation function predicts a critical temperature, below which small fluctuations from equilibrium in the thermodynamic limit cannot relax in a finite amount of time.

Glenn H. Fredrickson and Hans C. Andersen

1984-09-24T23:59:59.000Z

353

Overview of Energy Efficiency for Glass Furnace  

E-Print Network (OSTI)

,Particulates (Environmental norms) Global competitiveness #12;3 April, 2006 4Source: www.oilnergy.com Crude Oil Price #12;3 April, 2006 5 Natural Gas Price Source: www.oilnergy.com #12;3 April, 2006 6 Carbon Dioxide Endothermic heat of reaction Glass enthalpy at outlet of tank 1886 From temperature of 20 oC to 1500 oC Batch

Banerjee, Rangan

354

Free Energy Fluctuations in Ising Spin Glasses  

Science Journals Connector (OSTI)

The sample-to-sample fluctuations of the free energy in finite-dimensional Ising spin glasses are calculated, using the replica method, from higher order terms in the replica number n. It is shown that the Parisi symmetry breaking scheme does not give the correct answers for these higher order terms. A modified symmetry breaking scheme with the same stability is shown to resolve the problem.

T. Aspelmeier and M. A. Moore

2003-04-30T23:59:59.000Z

355

Geek-Up[6.17.2011]: Metallic Glass and 3D Plasmon Rulers | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7.2011]: Metallic Glass and 3D Plasmon Rulers 7.2011]: Metallic Glass and 3D Plasmon Rulers Geek-Up[6.17.2011]: Metallic Glass and 3D Plasmon Rulers June 17, 2011 - 5:41pm Addthis Check out a short animation of a 3D plasmon ruler as it delivers optical information about the structural dynamics of an attached protein and read more below. Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs What does this mean for me? The discovery of a new property of glass offers new insight into the atomic structure and behavior of metallic glasses, which are in products such as anti-theft tags and power transformers. A new ruler could help provide scientists with unprecedented details into a variety of biological events, including the interaction between DNA and enzymes, protein folding and cell membrane vibrations.

356

Properties of crystalline phase in waste glass  

SciTech Connect

Depending on the operating conditions of the vitrification process of high-level liquid waste, some crystalline phases can be present. The crystalline phase exists as molten salt at glass melting temperature. In this study, the chemical and physical properties of the crystalline phase were determined. Two samples rich in Mo and a sample rich in Re were examined. One of the samples rich in Mo was obtained from simulated waste solution and glass beads in a middle scale melter, while two other samples were made from mixed reagents. The chemical forms of the constituents were determined by XRD and SEM-EDX. When Mo is dominant, the crystal is mainly composed of molybdates of Na, Li, Ba and Ca, Na{sub 2}SO{sub 4} and CsReO{sub 4}. When Re is dominant, (Na{sub x}Cs{sub 1-x})ReO{sub 4} and NaLiMoO{sub 4} are added. The characteristic temperature and the heat of transition were determined by differential scanning calorimetry. The density of the molten salt at high temperature was measured from buoyancy. The density of the molten salt is larger than that of molten glass, and increases with Re content. (authors)

Usami, T.; Uruga, K.; Tsukada, T. [Central Research Institute of Electric Power Industry, Komae-shi, Tokyo 201-8511 (Japan); Miura, Y.; Komamine, S.; Ochi, E. [Japan Nuclear Fuel Limited, Rokkasho-mura, Aomori 039-3212 (Japan)

2013-07-01T23:59:59.000Z

357

Tm{sup 3+}-sensitized up- and down-conversions in nano-structured oxyfluoride glass ceramics  

SciTech Connect

Graphical abstract: Display Omitted Highlights: ? UC and DC are achieved in a single-ion sensitized phosphor for PV applications. ? The most intense fractions of AM 1.5G spectrum below/above c-Si bandgap are absorbed. ? The converted photons match the optimal spectral response of c-Si. -- Abstract: Tm{sup 3+}-sensitized up-conversion and down-conversion are studied in transparent glass ceramics embedded with ?-YF{sub 3} nanocrystals. Upon excitation at 1220 nm, where crystalline silicon (c-Si) solar cells no longer absorb, the sub-bandgap photons could be converted to the higher-energy ones via up-conversion. In addition, under excitation at 468 nm (a wavelength close to the peak in the air-mass 1.5 global solar spectrum), one blue photon might be split in up to two near-infrared ones via down-conversion. In both cases, the frequency-converted photons match the spectral response of c-Si solar cell well. Hopefully, the investigated luminescent materials may act as the spectral conversion layers to reduce the sub-bandgap transmission and charge carrier thermalization losses of c-Si solar cells, and in turn, enhance the energy efficiency.

Lin, Hang [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)] [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Marqués-Hueso, José [School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom)] [School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom); Chen, Daqin [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)] [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Wang, Yuansheng, E-mail: yswang@fjirsm.ac.cn [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China)] [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Richards, Bryce S., E-mail: b.s.richards@hw.ac.uk [School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS (United Kingdom)

2012-12-15T23:59:59.000Z

358

Investigation of ruthenium dioxide formation mechanisms in containment glass synthesized by liquid feed  

SciTech Connect

The presenting paper focuses on the structural configuration of ruthenium in vitreous matrices with the objective of obtaining more insight into ruthenium incorporation and solubilization mechanisms in borosilicate glasses. To determine the structural effect of an increasing RuO{sub 2} in a borosilicate glass, a series of glass samples were selected from a benchmark composition. {sup 11}B NMR shows that the borate network is influenced by the presence of RuO{sub 2} in the glass: the addition of 2% RuO{sub 2} in a borosilicate glass led to a significant rise of BO{sub 4}. RuO{sub 2} precipitated in the glass does not seem to be the cause of this modification because when RuO{sub 2} increase there is no further change of BO{sub 4} fraction. This effect can be therefore attributed to RuO{sub 2} dissolved in the glass. RuO{sub 2} is known to have a very low solubility in borosilicate glasses (50 to 2000 ppm depending on the temperature, sodium concentration and conditions of synthesis). The link between the ruthenium and the borated network is not yet clearly identified, however, assumptions can be made such as the formation of Ru-O-B when a sufficient quantity of Ru is add (> 400 ppm). Ruthenium could play the role of silicon in increasing the possibility of bridging bond formation with boron coordination number IV.

Sawada, K.; Shimada, T.; Sako, N.; Enokida, Y. [Graduate School of Engineering, Nagoya University (Japan); Schuller, S.; Angeli, F. [CEA-DEN-DTCD-LCV-SECM, 30207 Bagnols-sur-Ceze (France); Charpentier, T. [CEA-Saclay, DSM-IRAMIS-SIS2M, 91191 Gif-sur-Yvette (France)

2013-07-01T23:59:59.000Z

359

Short-, intermediate-, and extended-range order in rubidium germanate glasses  

Science Journals Connector (OSTI)

The origin of diffraction peaks observed at low wave vector in many complex glasses remains a central issue in the understanding of amorphous structures. In this work a combination of neutron and x-ray diffraction is used to correlate the contributions from the different atom pair correlations to such peaks in rubidium germanate glasses. The information obtained is compared with structural data on glasses of similar compositions from other techniques, structures of corresponding crystalline compounds, and results from computer simulation of analogous systems.

D. L. Price; A. J. G. Ellison; Marie-Louise Saboungi; R.-Z. Hu; T. Egami; W. S. Howells

1997-05-01T23:59:59.000Z

360

Tiny Glass Bubbles With Big Potential | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tiny Glass Bubbles With Big Potential Tiny Glass Bubbles With Big Potential Tiny Glass Bubbles With Big Potential August 19, 2011 - 12:32pm Addthis SRNL's Porous Walled Hollow Glass Microspheres (which are about half the width of a human hair in diameter) have a network of interconnected pores that enable them to be filled with, hold and release gases and other materials. | Image courtesy of SRNL SRNL's Porous Walled Hollow Glass Microspheres (which are about half the width of a human hair in diameter) have a network of interconnected pores that enable them to be filled with, hold and release gases and other materials. | Image courtesy of SRNL Liisa O'Neill Liisa O'Neill Former New Media Specialist, Office of Public Affairs What are the key facts? SRNL's porous walled glass microspheres allow the potential for

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

EMPIRICAL MODEL FOR FORMULATION OF CRYSTAL-TOLERANT HLW GLASSES  

SciTech Connect

Historically, high-level waste (HLW) glasses have been formulated with a low liquideus temperature (T{sub L}), or temperature at which the equilibrium fraction of spinel crystals in the melt is below 1 vol % (T{sub 0.01}), nominally below 1050 C. These constraints cannot prevent the accumulation of large spinel crystals in considerably cooler regions ({approx} 850 C) of the glass discharge riser during melter idling and significantly limit the waste loading, which is reflected in a high volume of waste glass, and would result in high capital, production, and disposal costs. A developed empirical model predicts crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass, and thereby provides guidance in formulating crystal-tolerant glasses that would allow high waste loadings by keeping the spinel crystals small and therefore suspended in the glass.

KRUGER AA; MATYAS J; HUCKLEBERRY AR; VIENNA JD; RODRIGUEZ CA

2012-03-07T23:59:59.000Z

362

Sintering and crystallization of akermanite-based glass–ceramics  

Science Journals Connector (OSTI)

Akermanite-based glass–ceramics were successfully produced from the SiO2–Al2O3–B2O3–MgO–CaO–Na2O–F system via sintering and crystallization of glass-powder compacts at low temperatures between 750 and 800 °C. The experimental results indicated that the amount of Al2O3 in the parent glass composition is seemingly a key factor with regard to the potential of this system to crystallize into a mono-mineral akermanite glass–ceramic. The aesthetics and the mechanical, the chemical and the thermal properties of the produced glass–ceramics in conjunction with the evaluation of the economic processing route proposed qualify these glass–ceramics for further investigation as potential materials suitable for applications in restorative dentistry.

J.M.G. Ventura; D.U. Tulyaganov; S. Agathopoulos; J.M.F. Ferreira

2006-01-01T23:59:59.000Z

363

Stress measurements in glass using shaped-charge jets  

Science Journals Connector (OSTI)

Stresses were measured in glass targets in the vicinity of a penetrating shaped-charge jet. Stress levels of approximately 0.3 \\{GPa\\} were measured 12–20mm away from a jet formed by a 35mm copper liner. High speed framing camera photographs showed that the penetration velocity in the glass was 2.57 km/s and the glass fracture velocity was 2.10 km/s.

William Lawrence; Robert E. Franz

1987-01-01T23:59:59.000Z

364

Formulation and Characterization of Waste Glasses with Varying Processing Temperature  

SciTech Connect

This report documents the preliminary results of glass formulation and characterization accomplished within the finished scope of the EM-31 technology development tasks for WP-4 and WP-5, including WP-4.1.2: Glass Formulation for Next Generation Melter, WP-5.1.2.3: Systematic Glass Studies, and WP-5.1.2.4: Glass Formulation for Specific Wastes. This report also presents the suggested studies for eventual restart of these tasks. The initial glass formulation efforts for the cold crucible induction melter (CCIM), operating at {approx}1200 C, with selected HLW (AZ-101) and LAW (AN-105) successfully developed glasses with significant increase of waste loading compared to that is likely to be achieved based on expected reference WTP formulations. Three glasses formulated for AZ-101HLW and one glass for AN-105 LAW were selected for the initial CCIM demonstration melter tests. Melter tests were not performed within the finished scope of the WP-4.1.2 task. Glass formulations for CCIM were expanded to cover additional HLWs that have high potential to successfully demonstrate the unique advantages of the CCIM technologies based on projected composition of Hanford wastes. However, only the preliminary scoping tests were completed with selected wastes within the finished scope. Advanced glass formulations for the reference WTP melter, operating at {approx}1200 C, were initiated with selected specific wastes to determine the estimated maximum waste loading. The incomplete results from these initial formulation efforts are summarized. For systematic glass studies, a test matrix of 32 high-aluminum glasses was completed based on a new method developed in this study.

Kim, Dong-Sang; Schweiger, M. J.; Rodriguez, Carmen P.; Lepry, William C.; Lang, Jesse B.; Crum, Jarrod V.; Vienna, John D.; Johnson, Fabienne; Marra, James C.; Peeler, David K.

2011-10-17T23:59:59.000Z

365

Method for forming glass-to-metal seals  

DOE Patents (OSTI)

A method for forming a glass-to-metal seal in which the glass has a higher melting point than the metal. The molten glass is vacuum injection molded onto the metal, thus melting a very thin layer of the surface of the metal long enough to form a seal, but not long enough to cause a distortion in the shape of the metal component.

Kramer, Daniel P. (Dayton, OH); Massey, Richard T. (Hamilton, OH)

1986-01-01T23:59:59.000Z

366

Using sputter coated glass to stabilize microstrip gas chambers  

DOE Patents (OSTI)

By sputter coating a thin-layer of low-resistive, electronically-conductive glass on various substrates (including quartz and ceramics, thin-film Pestov glass), microstrip gas chambers (MSGC) of high gain stability, low leakage current, and a high rate capability can be fabricated. This design can make the choice of substrate less important, save the cost of ion-implantation, and use less glass material.

Gong, Wen G. (Albany, CA)

1997-01-01T23:59:59.000Z

367

Window Spacers and Edge Seals in Insulating Glass Units: A State-of-the-Art Review and Future Perspectives  

E-Print Network (OSTI)

2012) [53] Bystronic Glass, Sashlite, http://www.bystronic-products_architectural_ glass/window_manufacturing/sashline/Production and Quality, Glass Processing Days (2005) 228-

Bergh, Sofie Van Den

2014-01-01T23:59:59.000Z

368

Cellular glass insulation keeps liquefied gas from vaporizing  

SciTech Connect

The North West Shelf Project, located on the Burrup Peninsula in Western Australia, supplies much of that vast state with natural gas for domestic and industrial applications. Some of the gas is also exported to Japan as liquefied natural gas (LNG). While awaiting shipment to Japan, the LNG is stored at {minus}322 F in four storage tanks, each with a capacity of 2.5 million ft{sup 3}. When Woodside Offshore Petroleum Pty Ltd., operator of the LNG facility, selected insulation material for the storage tanks, it went in search of a material with more than just insulating value. Since the insulation is installed inside the tanks, it must be able to resist wicking or absorbing the LNG. Also, it had to have sufficient strength to withstand the weight of the 2.5 million ft{sup 3} of LNG without being crushed or losing its insulting properties. And, as a safety precaution, the selected materials should neither burn nor support combustion. Ultimately, Woodside selected a cellular glass insulation called Foamglas, from Pittsburgh Corning Corp., that met all the performance criteria and was cost competitive with the lesser-performing alternatives. Foamglas is produced from strong, inert borosilicate glass. Its insulating capability is provided by the tiny, closed cells of air encapsulated within the foam-like structure of the glass. Since the cells are closed,neither liquid nor vapor can enter the structure of the insulation. The inert glass itself will not absorb or react with LNG, nor will it burn or support a fire. The cellular structure provides effective insulation in both not and cold applications, and offers a fire barrier.

NONE

1995-11-01T23:59:59.000Z

369

Thermal Predictions of the Cooling of Waste Glass Canisters  

SciTech Connect

Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

Donna Post Guillen

2014-11-01T23:59:59.000Z

370

Poisson's Ratio and the Densification of Glass under High Pressure  

SciTech Connect

Because of a relatively low atomic packing density, (C{sub g}) glasses experience significant densification under high hydrostatic pressure. Poisson's ratio ({nu}) is correlated to C{sub g} and typically varies from 0.15 for glasses with low C{sub g} such as amorphous silica to 0.38 for close-packed atomic networks such as in bulk metallic glasses. Pressure experiments were conducted up to 25 GPa at 293 K on silica, soda-lime-silica, chalcogenide, and bulk metallic glasses. We show from these high-pressure data that there is a direct correlation between {nu} and the maximum post-decompression density change.

Rouxel, T.; Ji, H. [Applied Mechanics Laboratory of the University of Rennes 1, LARMAUR, Universite de Rennes 1, Campus de Beaulieu, 35042 Rennes cedex (France); Hammouda, T. [Laboratoire Magmas et Volcans, CNRS-OPG , Universite Blaise Pascal, 5 rue Kessler, 63038 Clermont-Ferrand cedex (France); Moreac, A. [IPR, CNRS-Universite de Rennes 1, Campus de Beaulieu, 35042 Rennes cedex (France)

2008-06-06T23:59:59.000Z

371

Optical glass polishing by controlled laser surface-heat treatment  

Science Journals Connector (OSTI)

It is shown that optical surfaces traditionally ground in conventional glasses with high coefficients of thermal expansion may be polished by irradiation with a space- and...

Laguarta, F; Lupon, N; Armengol, J

1994-01-01T23:59:59.000Z

372

China Glass Solar aka CG Solar formerly Weihai Bluestar Terra...  

Open Energy Info (EERE)

Solar aka CG Solar formerly Weihai Bluestar Terra Photovoltaic Co Ltd Jump to: navigation, search Name: China Glass Solar (aka CG Solar, formerly Weihai Bluestar Terra Photovoltaic...

373

Controlled permeation of hydrogen through glass. Final report  

SciTech Connect

Storing hydrogen inside of hollow glass spheres requires that the gas permeate through the glass walls. Hydrogen permeation through glass is relatively slow and the time to charge a sphere or bed of spheres is dependent on many factors. Permeation processes are strongly temperature dependent with behavior that follows an Arrhenius function., Rate is also dependent on the pressure drop driving force across a membrane wall and inversely proportional to thickness. Once filled, glass spheres will immediately begin to leak once the pressure driving force is reversed. Practical systems would take advantage of the fact that keeping the glass at ambient temperatures can minimize outboard leakage even with significant internal pressures. If hydrogen could be loaded and unloaded from glass microspheres with significantly less energy and particularly at near ambient temperature, some of the key barriers to commercializing this storage concept would be broken and further system engineering efforts may make this approach cost-effective. There were two key objectives for this effort. The first was to evaluate the application of hollow glass microspheres for merchant hydrogen storage and distribution and then determine the hydrogen permeation performance required for practical commercial use. The second objective was to identify, through a series of fundamental experiments, a low energy, low temperature field effect that could significantly enhance hydrogen permeation through glass without application of heat. If such an effect could be found, hollow glass microspheres could be much more attractive for hydrogen storage or possibly gas separation applications.

Halvorson, T. [Praxair, Inc., Tonawanda, NY (United States); Shelby, J.E. Jr. [Alfred Univ., NY (United States). Glass Science Lab.

1998-03-01T23:59:59.000Z

374

Glass fiber composition. [for use as thermal insulation  

DOE Patents (OSTI)

The invention relates to a glass fiber composition useful for thermal insulation having a low melting temperature and high chemical durability.

Wolf, G.A.; Kupfer, M.J.

1980-12-19T23:59:59.000Z

375

Method of calculation of heat generation rates for DWPF glass  

SciTech Connect

The Waste Acceptance Preliminary Specifications (WAPS) require estimates of the heat generation rate of DWPF waste glasses. Estimates of the heat generation rates of projected glass compositions are to be reported in the Waste Form Qualification Report. Similar estimates for actual production glasses are to be reported in the Production Records. In this report, a method of calculating the heat generation rate from the radionuclide inventory is provided. Application of the method to the DWPF Design-Basis glass indicates that the heat generation rate can be accurately estimated from the Sr-90, Y-90, Cs-137, Ba-137m, and Pu-238 contents alone.

Plodinec, M.J.

1992-03-17T23:59:59.000Z

376

Method of calculation of heat generation rates for DWPF glass  

SciTech Connect

The Waste Acceptance Preliminary Specifications (WAPS) require estimates of the heat generation rate of DWPF waste glasses. Estimates of the heat generation rates of projected glass compositions are to be reported in the Waste Form Qualification Report. Similar estimates for actual production glasses are to be reported in the Production Records. In this report, a method of calculating the heat generation rate from the radionuclide inventory is provided. Application of the method to the DWPF Design-Basis glass indicates that the heat generation rate can be accurately estimated from the Sr-90, Y-90, Cs-137, Ba-137m, and Pu-238 contents alone.

Plodinec, M.J.

1993-02-04T23:59:59.000Z

377

Thermal Gradient Holes At Glass Mountain Area (Cumming And Mackie...  

Open Energy Info (EERE)

Area (Cumming And Mackie, 2007) Exploration Activity Details Location Glass Mountain Geothermal Area Exploration Technique Thermal Gradient Holes Activity Date Usefulness not...

378

Time-Domain Electromagnetics At Glass Mountain Area (Cumming...  

Open Energy Info (EERE)

Time-Domain Electromagnetics At Glass Mountain Area (Cumming And Mackie, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Time-Domain...

379

Bose Glass of Quasiparticles in Doped Quantum Magnet Gregory...  

NLE Websites -- All DOE Office Websites (Extended Search)

Bose Glass of Quasiparticles in Doped Quantum Magnet Gregory S. Boebinger, National High Magnetic Field Laboratory DMR-Award 0654118 High BT Facility & Pulsed Field Facility When...

380

Multispectral Imaging At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Retrieved from "http:en.openei.orgwindex.php?titleMultispectralImagingAtGlassButtesArea(DOEGTP)&oldid511008" Categories: Geothermal Exploration Activities DOE...

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Compound and Elemental Analysis At Glass Buttes Area (DOE GTP...  

Open Energy Info (EERE)

Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding...

382

Dynamical heterogeneities in an attraction driven colloidal glass  

E-Print Network (OSTI)

The dynamical heterogeneities (DH) in non-ergodic states of an attractive colloidal glass are studied, as a function of the waiting time. Whereas the fluid states close to vitrify showed strong DH, the distribution of squared displacements of the glassy states studied here only present a tail of particles with increased mobility for the lower attraction strength at short waiting times. These particles are in the surface of the percolating cluster that comprises all of the particles, reminiscent of the fastest particles in the fluid. The quench deeper into the attractive glass is dynamically more homogeneous, in agreement with repulsive glasses (i.e. Lennard-Jones glass).

Antonio M. Puertas; Matthias Fuchs; Michael E. Cates

2005-10-17T23:59:59.000Z

383

Welding/sealing glass-enclosed space in a vacuum  

DOE Patents (OSTI)

A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbant material, such as FeO, VO.sub.2, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbant material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbant material melts glass in the portions of both glass sheets that are adjacent the absorbant material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbant material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbant material to source energy power and welding heat needed, the process can be made self-stopping.

Tracy, C. Edwin (Golden, CO); Benson, David K. (Golden, CO)

1996-01-01T23:59:59.000Z

384

Aeromagnetic Survey At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

(1 January 2011) GTP ARRA Spreadsheet Additional References Retrieved from "http:en.openei.orgwindex.php?titleAeromagneticSurveyAtGlassButtesArea(DOEGTP)&oldid402411...

385

Potential for energy conservation in the glass industry  

SciTech Connect

While the glass industry (flat glass, container glass, pressed and blown glass, and insulation fiber glass) has reduced its specific energy use (Btu/ton) by almost 30% since 1972, significant potential for further reduction still remains. State-of-the-art technologies are available which could lead to incremental improvements in glass industry energy productivity; however, these technologies must compete for capital with projects undertaken for other reasons (e.g., capacity expansion, equipment rebuild, labor cost reduction, product quality improvement, or compliance with environmental, health or safety regulations). Narrowing profit margins in the large tonnage segments of the glass industry in recent years and the fact that energy costs represent less than 25% of the value added in glass manufacture have combined to impede the widespread adoption of many state-of-the-art conservation technologies. Savings in energy costs alone have not provided the incentive to justify the capital expenditures required to realize the energy savings. Beyond implementation of state-of-the-art technologies, significant potential energy savings could accrue from advanced technologies which represent a radical departure from current glass making technology. Long-term research and development (R and D) programs, which address the technical and economic barriers associated with advanced, energy-conserving technologies, offer the opportunity to realize this energy-saving potential.

Garrett-Price, B.A.; Fassbender, A.G.; Bruno, G.A.

1986-06-01T23:59:59.000Z

386

Strengthening of glass beams with steel reinforced polymer (SRP)  

Science Journals Connector (OSTI)

Abstract The work describes an experimental analysis for studying the flexural strengthening of beams made from glass and composite material consisting of steel cords impregnated with polymeric resins (SRP). Beams were prepared consisting of glass sheets set vertically and reinforced on the intrados with SRP and subjected to four-point bending tests. The use of SRP produced beneficial effects in the elastic phase with an increase of the first cracking load and provided residual strength in the post-failure phase allowing new equilibrium configurations after the first cracking. The results obtained were satisfying as regards both the increase in strength and stiffness in the elastic phase and in residual strength in the post-failure phase. An analytical modeling based on the load–deformation characteristics was performed to obtain more in-depth knowledge on the behavior of the structural elements tested.

E. Speranzini; S. Agnetti

2014-01-01T23:59:59.000Z

387

Molten Glass for Thermal Storage: Advanced Molten Glass for Heat Transfer and Thermal Energy Storage  

SciTech Connect

HEATS Project: Halotechnics is developing a high-temperature thermal energy storage system using a new thermal-storage and heat-transfer material: earth-abundant and low-melting-point molten glass. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. Halotechnics new thermal storage material targets a price that is potentially cheaper than the molten salt used in most commercial solar thermal storage systems today. It is also extremely stable at temperatures up to 1200°C—hundreds of degrees hotter than the highest temperature molten salt can handle. Being able to function at high temperatures will significantly increase the efficiency of turning heat into electricity. Halotechnics is developing a scalable system to pump, heat, store, and discharge the molten glass. The company is leveraging technology used in the modern glass industry, which has decades of experience handling molten glass.

None

2012-01-01T23:59:59.000Z

388

Celloidosomes® via glass-based microfluidics  

Science Journals Connector (OSTI)

We report a glass-based microfluidic route for the generation of a particular class of celloidosomes consisting of an assembly of yeast cells at the outskirts of liquid drops inside an also liquid continuous phase. This is the first demonstration of the encapsulation of cells into shells of alginate surrounding a liquid core. The microfluidic method based on double emulsion technology allows precise control on the size of the celloidosomes, thickness of the outer shell, and the cell density. In addition, this surface encapsulation technique can potentially overcome cell viability issues usually associated with bulk cell encapsulation techniques.

V R Gundabala; S Martinez-Escobar; S M Marquez; M Marquez; A Fernandez-Nieves

2013-01-01T23:59:59.000Z

389

Tests of concrete beams with externally-bonded glass-fiber fabric web reinforcement  

E-Print Network (OSTI)

of strengthening techniques used for rehabilitation of concrete structures is the method of using thin glass and carbon fiber fabrics, which are bonded externally to the surface of concrete. The study is focused on investigating the feasibility of using fabrics...

Dabholkar, Niranjan Shamsunder

2012-06-07T23:59:59.000Z

390

Portland cement mortar modified with latex and fiber glass for thin shell construction  

E-Print Network (OSTI)

with latex and fiber glass as a covering material for thin shell structures. Tests were conducted on various formulations to determine certain physical properties of the modified portland cement. Application techniques were investigated to determine...

Raymond, Jewell Duane

1963-01-01T23:59:59.000Z

391

Synthesis of nanocrystals in KNb(Ge,Si)O{sub 5} glasses and chemical etching of nanocrystallized glass fibers  

SciTech Connect

The nanocrystallization behavior of 25K{sub 2}O-25Nb{sub 2}O{sub 5}-(50-x)GeO{sub 2}-xSiO{sub 2} glasses with x=0,25,and50 (i.e., KNb(Ge,Si)O{sub 5} glasses) and the chemical etching behavior of transparent nanocrystallized glass fibers have been examined. All glasses show nanocrystallization, and the degree of transparency of the glasses studied depends on the heat treatment temperature. Transparent nanocrystallized glasses can be obtained if the glasses are heat treated at the first crystallization peak temperature. Transparent nanocrystallized glass fibers with a diameter of about 100{mu}m in 25K{sub 2}O-25Nb{sub 2}O{sub 5}-50GeO{sub 2} are fabricated, and fibers with sharpened tips (e.g., the taper length is about 450{mu}m and the tip angle is about 12{sup o}) are obtained using a meniscus chemical etching method, in which etching solutions of 10wt%-HF/hexane and 10M-NaOH/hexane are used. Although the tip (aperture size) has not a nanoscaled size, the present study suggests that KNb(Ge,Si)O{sub 5} nanocrystallized glass fibers have a potential for new near-field optical fiber probes with high refractive indices of around n=1.8 and high dielectric constants of around {epsilon}=58 (1kHz, room temperature)

Enomoto, Itaru [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Benino, Yasuhiko [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Fujiwara, Takumi [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Komatsu, Takayuki [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)]. E-mail: komatsu@chem.nagaokaut.ac.jp

2006-06-15T23:59:59.000Z

392

Reduction of Glass Surface Reflectance by Ion Beam Surface Modification  

SciTech Connect

This is the final report for DOE contract DE-EE0000590. The purpose of this work was to determine the feasibility of the reduction of the reflection from the front of solar photovoltaic modules. Reflection accounts for a power loss of approximately 4%. A solar module having an area of one square meter with an energy conversion efficiency of 18% generates approximately 180 watts. If reflection loss can be eliminated, the power output can be increased to 187 watts. Since conventional thin-film anti-reflection coatings do not have sufficient environmental stability, we investigated the feasibility of ion beam modification of the glass surface to obtain reduction of reflectance. Our findings are generally applicable to all solar modules that use glass encapsulation, as well as commercial float glass used in windows and other applications. Ion implantation of argon, fluorine, and xenon into commercial low-iron soda lime float glass, standard float glass, and borosilicate glass was studied by implantation, annealing, and measurement of reflectance. The three ions all affected reflectance. The most significant change was obtained by argon implantation into both low-iron and standard soda-lime glass. In this way samples were formed with reflectance lower than can be obtained with a single-layer coatings of magnesium fluoride. Integrated reflectance was reduced from 4% to 1% in low-iron soda lime glass typical of the glass used in solar modules. The reduction of reflectance of borosilicate glass was not as large; however borosilicate glass is not typically used in flat plate solar modules. Unlike conventional semiconductor ion implantation doping, glass reflectance reduction was found to be tolerant to large variations in implant dose, meaning that the process does not require high dopant uniformity. Additionally, glass implantation does not require mass analysis. Simple, high current ion implantation equipment can be developed for this process; however, before the process can be employed on full scale solar modules, equipment must be developed for ion implanting large sheets of glass. A cost analysis shows that the process can be economical. Our finding is that the reduction of reflectance by ion beam surface modification is technically and economically feasible. The public will benefit directly from this work by the improvement of photovoltaic module efficiency, and indirectly by the greater understanding of the modification of glass surfaces by ion beams.

Mark Spitzer

2011-03-11T23:59:59.000Z

393

The mechanics of glass and functionalised glass surfaces E. Barthel, M. Beauvais, R. Briard, N. Chemin, D. Dalmas, C. Heitz, M. Klotz, P. Nael, A.  

E-Print Network (OSTI)

The mechanics of glass and functionalised glass surfaces E. Barthel, M. Beauvais, R. Briard, N Aubervilliers Cedex France etienne.barthel@saint-gobain.com Abstract Glass is highly sensitive to surface flaws in glass functionalisation by grafting or coating lend an even more prominent role to the surface

Paris-Sud XI, Université de

394

Evolution of glass properties during a substitution of S by Se in Ge28Sb12S60-xSex glass Guillaume Guery1,2  

E-Print Network (OSTI)

Evolution of glass properties during a substitution of S by Se in Ge28Sb12S60-xSex glass network, Université de Bordeaux I, Avenue du Dr Schweitzer, 33608 Pessac Cedex, France. Keywords: Chalcogenide glass; Raman spectroscopy; X-ray photoelectron spectroscopy; Glass properties Author whom correspondence should

Paris-Sud XI, Université de

395

Coexistence of spin-glass and ferromagnetic order in the J Heisenberg spin-glass model A. D. Beath and D. H. Ryan  

E-Print Network (OSTI)

Coexistence of spin-glass and ferromagnetic order in the ±J Heisenberg spin-glass model A. D. Beath temperature spin-glass transition at TSG=0.220 5 . Remarkably, this transition temperature is composition dependent, rising to TSG=0.25 1 by the ferromagnet­spin-glass boundary. Coexistence of ferromagnetic

Ryan, Dominic

396

Graded index antireflective coatings for glass : final report, September 1978 - February 1982  

E-Print Network (OSTI)

Glass compositions and process conditions by which broad band gradedindex antreflective films can be produced on glass surfaces have been developed. The end use for the treated glass sheet is as cover plates for flat plate ...

Haggerty, John Scarseth

1983-01-01T23:59:59.000Z

397

The effect of temperature on the bending of laminated glass beams  

E-Print Network (OSTI)

Laminated glass is comprised of multiple plates of glass bonded together with polymorphous interlayers. The interest in the use of architectural laminated glass in the construction industry has increased due to its possible advantages over...

Edel, Matthew Thomas

1997-01-01T23:59:59.000Z

398

Glass fiber contamination of cigarette filters: an additional health risk to the smoker?  

Science Journals Connector (OSTI)

Articles Glass fiber contamination of cigarette filters...cigarette-appearing smoking article labeled Eclipse with glass fibers, fragments, and particles. Eclipse...insulated and bound with two wrapping mats of glass fibers. Recently, Eclipse has been modified...

J L Pauly; H J Lee; E L Hurley; K M Cummings; J D Lesses; R J Streck

1998-11-01T23:59:59.000Z

399

Glass particles produced by laser ablation for ICP-MS measurements  

E-Print Network (OSTI)

Glass particles produced by laser ablation for ICP-MS266nm) was used to generate glass particles from two sets ofWhen the current data on glass were compared with the metal

Gonzalez, J.; Liu, C.; Wen, S.; Mao, X.; Russo, R.E.

2008-01-01T23:59:59.000Z

400

Solid-State NMR Examination of Alteration Layers on a Nuclear Waste Glasses  

SciTech Connect

Solid-state NMR is a powerful tool for probing the role and significance of alteration layers in determining the kinetics for the corrosion of nuclear waste glass. NMR methods are used to probe the chemical structure of the alteration layers to elucidate information about their chemical complexity, leading to increased insight into the mechanism of altered layer formation. Two glass compositions were examined in this study: a glass preliminarily designed for nuclear waste immobilization (called AFCI) and a simplified version of this AFCI glass (which we call SA1R). Powdered glasses with controlled and known particles sizes were corroded at 90 °C for periods of one and five months with a surface-area to solution-volume ratio of 100,000 m-1. 1H-29Si CP-CPMG MAS NMR, 1H-27Al CP-MAS NMR, 1H-11B CP-MAS NMR, and 1H-23Na CP-MAS NMR experiments provide isolated structural information about the alteration layers, which differ in structure from that of the pristine glass. Both glasses studied here develop alteration layers composed primarily of [IV]Si species. Aluminum is also retained in the alteration layers, perhaps facilitated by the observed increase in coordination from [IV]Al to [VI]Al, which correlates with a loss of charge balancing cations. 1H-11B CP-MAS NMR observations indicated a retention of boron in hydrated glass layers, which has not been characterized by previous work. For the AFCI glass, secondary phase formation begins during the corrosion times considered here, and these neophases are detected within the alteration layers. We identify precursor phases as crystalline sodium metasilicates. An important finding is that layer thickness depends on the length of the initial alteration stages and varies only with respect to silicon species during the residual rate regime.

Murphy, Kelly A. [Penn State Univ., State College, PA (United States). Dept. of Chemistry; Washton, Nancy M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Science Lab.; Ryan, Joseph V. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pantano, Carlo G. [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Mueller, Karl T. [Penn State Univ., State College, PA (United States). Dept. of Chemistry; Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Science Lab.

2013-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Quantum computing in a piece of glass  

E-Print Network (OSTI)

Quantum gates and simple quantum algorithms can be designed utilizing the diffraction phenomena of a photon within a multiplexed holographic element. The quantum eigenstates we use are the photon's linear momentum (LM) as measured by the number of waves of tilt across the aperture. Two properties of quantum computing within the circuit model make this approach attractive. First, any conditional measurement can be commuted in time with any unitary quantum gate - the timeless nature of quantum computing. Second, photon entanglement can be encoded as a superposition state of a single photon in a higher-dimensional state space afforded by LM. Our theoretical and numerical results indicate that OptiGrate's photo-thermal refractive (PTR) glass is an enabling technology. We will review our previous design of a quantum projection operator and give credence to this approach on a representative quantum gate grounded on coupled-mode theory and numerical simulations, all with parameters consistent with PTR glass. We discuss the strengths (high efficiencies, robustness to environment) and limitations (scalability, crosstalk) of this technology. While not scalable, the utility and robustness of such optical elements for broader quantum information processing applications can be substantial.

Warner A. Miller; Grigoriy Kreymerman; Christopher Tison; Paul M. Alsing; Jonathan R. McDonald

2011-12-15T23:59:59.000Z

402

Glass Mountain Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Glass Mountain Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Mountain Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (2) 9 Exploration Activities (3) 10 References Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN","zoom":6,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"300px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.7,"lon":-121.45,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

403

Energy Saving Glass Lamination via Selective Radio Frequency Heating  

SciTech Connect

Ceralink Inc. developed FastFuse™, a rapid, new, energy saving process for lamination of glass and composites using radio frequency (RF) heating technology. The Inventions and Innovations program supported the technical and commercial research and development needed to elevate the innovation from bench scale to a self-supporting technology with significant potential for growth. The attached report provides an overview of the technical and commerical progress achieved for FastFuse™ during the course of the project. FastFuse™ has the potential to revolutionize the laminate manufacturing industries by replacing energy intensive, multi-step processes with an energy efficient, single-step process that allows higher throughput. FastFuse™ transmits RF energy directly into the interlayer to generate heat, eliminating the need to directly heat glass layers and the surrounding enclosures, such as autoclaves or vacuum systems. FastFuse™ offers lower start-up and energy costs (up to 90% or more reduction in energy costs), and faster cycles times (less than 5 minutes). FastFuse™ is compatible with EVA, TPU, and PVB interlayers, and has been demonstrated for glass, plastics, and multi-material structures such as photovoltaics and transparent armor.

Shawn M. Allan; Patricia M. Strickland; Holly S. Shulman

2009-11-11T23:59:59.000Z

404

Regular ring dynamics in AX2 tetrahedral glasses  

Science Journals Connector (OSTI)

We review the experimental evidence and qualitative arguments for the existence of small highly regular rings of bonds in amorphous (a-)SiO2 and selected other AX2 tetrahedral glasses. The structure and vibrations of planar 3-rings and regular puckered 4-rings in a-SiO2 are then modeled using Born central and noncentral forces. The vibrational coupling of these rings to the more disordered glass network is modeled by attaching a Bethe lattice at each connection. The calculated vibrational properties of the breathing modes of the rings are found to be quite consistent with the observed frequencies, linewidths, and isotope shifts of the sharp lines D1 and D2 seen in the Raman spectra of a-SiO2. The results support the previous assignment of D2 (606 cm-1) to a planar 3-ring and D1 (495 cm-1) to a regular ring. Similar calculations for a-GeO2 are consistent with the suggestion that this material contains a substantial concentration of nearly planar 3-rings. Our methods can be generalized to treat similar forms of intermediate range order in glasses having other network connectivities.

R. A. Barrio; F. L. Galeener; E. Martínez; R. J. Elliott

1993-12-01T23:59:59.000Z

405

Glass Rheology: From mode-coupling theory to a dynamical yield criterion  

E-Print Network (OSTI)

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as colloidal glasses. However, the constitutive equations derivable from MCT are somewhat intractable, hindering their practical use and also their interpretation. Here, we present a schematic (single-mode) MCT model which incorporates the tensorial structure of the full theory. Using it, we calculate the dynamic yield surface for a large class of flows.

J. M. Brader; Th. Voigtmann; M. Fuchs; R. G. Larson; M. E. Cates

2009-09-28T23:59:59.000Z

406

The Glass Transition in Fluids with Magnetic Interactions  

E-Print Network (OSTI)

We study the glass transition in fluids where particles are endowed with spins, such that magnetic and positional degrees of freedom are coupled. Novel results for slowing down in the spin time-correlation functions are described, and the effects of magnetic fields on the glass transition are studied. Aging effects in such systems and the corresponding data collapse are presented and discussed.

Ricardo Gutierrez; Bhaskar Sen Gupta; Itamar Procaccia

2014-06-15T23:59:59.000Z

407

Americium/curium extraction from a lanthanide borosilicate glass  

SciTech Connect

A solution containing kilogram quantities of highly radioactive isotopes of americium and curium (Am/Cm) and lanthanide fission products is currently stored in a process tank at the Department of Energy`s Savannah River Site (SRS). This tank and its vital support systems are old, subject to deterioration, and prone to possible leakage. For this reason, a program has been initiated to stabilize this material as a lanthanide borosilicate (LBS) glass. The Am/Cm has commercial value and is desired for use by the heavy isotope programs at the Oak Ridge National Laboratory (ORNL). A recovery flowsheet was demonstrated using a curium containing glass to extract the Am/Cm from the glass matrix. The procedure involved grinding the glass to less than 200 mesh and dissolving in concentrated nitric acid at 110 {degrees}C. Under these conditions, the dissolution was essentially 100% after 2 hours except for the insoluble silicon. Using a nonradioactive surrogate, the expected glass dissolution rate during Am/Cm recovery was bracketed by using both static and agitated conditions. The measured rates, 0.0082 and 0.040 g/hr.sq cm, were used to develop a predictive model for the time required to dissolve a spherical glass particle in terms of the glass density, particle size, and measured rate. The calculated dissolution time was in agreement with the experimental observation that the curium glass dissolution was complete in less than 2 hrs.

Rudisill, T.S.; Pareizs, J.M.; Ramsey, W.G.

1996-12-01T23:59:59.000Z

408

The recycling of the coal fly ash in glass production  

SciTech Connect

The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-09-15T23:59:59.000Z

409

Thermodynamics and Universality for Mean Field Quantum Spin Glasses  

E-Print Network (OSTI)

We study aspects of the thermodynamics of quantum versions of spin glasses. By means of the Lie-Trotter formula for exponential sums of operators, we adapt methods used to analyze classical spin glass models to answer analogous questions about quantum models.

Nick Crawford

2006-10-13T23:59:59.000Z

410

Irradiation study of PNNL synthesized glass-ceramics  

SciTech Connect

Two types of glass-ceramic were investigated: (1) for immobilization of Ln, alkali, and alkaline earths (GC4); and (2) same as above + high (7%) molybdenum content (Mo7) multiphase specimens. The purpose was to study the radiation stability of PNNL synthesized glass-ceramics and changes in microstructure/phase composition.

Kossoy-simakov, Anna-eden [Los Alamos National Laboratory; Tang, Ming [Los Alamos National Laboratory; Valdez, James A [Los Alamos National Laboratory; Usov, Igor O [Los Alamos National Laboratory; Sickafus, Kurt E [Los Alamos National Laboratory

2011-01-18T23:59:59.000Z

411

production under ionizing radiation in aluminoborosilicate glasses by EPR spectroscopy.  

E-Print Network (OSTI)

1 Ti3+ production under ionizing radiation in aluminoborosilicate glasses by EPR spectroscopy. P irradiation of Ti4+ ions in aluminoborosilicate glasses have been studied by EPR spectroscopy at 20 K of the Ti3+ ion EPR spectra has shown three different Ti3+ environment attributed to one [VI] Ti3+ and two

Paris-Sud XI, Université de

412

Glass Development for Treatment of LANL Evaporator Bottoms Waste  

SciTech Connect

Vitrification is an attractive treatment option for meeting the stabilization and final disposal requirements of many plutonium (Pu) bearing materials and wastes at the Los Alamos National Laboratory (LANL) TA-55 facility, Rocky Flats Environmental Technology Site (RFETS), Hanford, and other Department of Energy (DOE) sites. The Environmental Protection Agency (EPA) has declared that vitrification is the "best demonstrated available technology" for high- level radioactive wastes (HLW) (Federal Register 1990) and has produced a handbook of vitriilcation technologies for treatment of hazardous and radioactive waste (US EPA, 1992). This technology has been demonstrated to convert Pu-containing materials (Kormanos, 1997) into durable (Lutze, 1988) and accountable (Forsberg, 1995) waste. forms with reduced need for safeguarding (McCulhun, 1996). The composition of the Evaporator Bottoms Waste (EVB) at LANL, like that of many other I%-bearing materials, varies widely and is generally unpredictable. The goal of this study is to optimize the composition of glass for EVB waste at LANL, and present the basic techniques and tools for developing optimized glass compositions for other Pu-bearing materials in the complex. This report outlines an approach for glass formulation with fixed property restrictions, using glass property-composition databases. This approach is applicable to waste glass formulation for many variable waste streams and vitrification technologies.. Also reported are the preliminary property data for simulated evaporator bottom glasses, including glass viscosity and glass leach resistance using the Toxicity Characteristic Leaching Procedure (TCLP).

DE Smith; GF Piepel; GW Veazey; JD Vienna; ML Elliott; RK Nakaoka; RP Thimpke

1998-11-20T23:59:59.000Z

413

On the Sealing of Electrical Conductors through Glass  

Science Journals Connector (OSTI)

... AT the present time there is great difficulty in obtaining soft glass with a comparatively high coefficient of expansion, suitable for sealing wires into ... with a comparatively high coefficient of expansion, suitable for sealing wires into glass tubes, bulbs, etc. The pre-war imported stocks of ...

F. F. S. BRYSON

1915-06-03T23:59:59.000Z

414

Time Factors in the Breaking of Toughened Glass  

Science Journals Connector (OSTI)

... has been much interest in the relationship between rates of stressing and strength properties of glass, and several hypotheses and relations have been put forward in connexion with the quantitative ... of the broaking stress with increase in duration of loading should be slower with toughened glass than with sheet. However, the same conclusion follows from the quantitative formulation6 of the ...

R. N. HAWARD

1946-01-05T23:59:59.000Z

415

Central Glass and Ceramic Research Institute of India  

Science Journals Connector (OSTI)

... THE official opening of the Central Glass and Ceramic Research Institute of India at Calcutta by the Honourable Dr. B. C ... contributions on the availability and improvement in the quality of Indian raw materials for the glass and ceramic industries have already been made ; a detailed account of these investigations was ...

1950-11-18T23:59:59.000Z

416

The Late Rev. W. V. Harcourt's Researches on Glass*  

Science Journals Connector (OSTI)

... THE subject of the preparation and optical properties of glasses of a great variety of chemical positions, formed, for nearly forty years, a ... inquiry, was published in the reports, but the results of the actual experiments on glass have never yet been published. My own connection with these experiments commenced at the ...

1871-08-31T23:59:59.000Z

417

Glass Based on the oxides of Molybdenum, Tungsten and Uranium  

Science Journals Connector (OSTI)

... IN previous publications from this Laboratory, attention has been directed to glasses of unusual composition based on the oxides of tellurium and vanadium1-4. This article ... the oxides of tellurium and vanadium1-4. This article describes the development of further unusual glasses based on the oxides of molybdenum, tungsten and uranium.

P. L. BAYNTON; H. RAWSON; J. E. STANWORTH

1956-10-27T23:59:59.000Z

418

Photocatalytic activity of glass ceramics containing Nasicon-type crystals  

SciTech Connect

Graphical abstract: Display Omitted Highlights: ? Glass ceramics containing Nasicon-type crystals were prepared. ? The glass ceramics showed photocatalytic activity under UV irradiation. ? Higher activity was observed in the MgTi{sub 4}(PO{sub 4}){sub 6}- and CaTi{sub 4}(PO{sub 4}){sub 6}-containing glass ceramics. -- Abstract: Glass ceramics were prepared by heat-treating MO–TiO{sub 2}–P{sub 2}O{sub 5} (M = Mg, Ca, Sr and Ba) and R{sub 2}O–TiO{sub 2}–P{sub 2}O{sub 5}–SiO{sub 2} (R = Li, Na and K) glasses, and their photocatalytic activity was investigated. The crystalline phases precipitated in the glasses were only Nasicon-type crystals, MTi{sub 4}(PO{sub 4}){sub 6} or RTi{sub 2}(PO{sub 4}){sub 3}. Decomposition experiments of both methylene blue (MB) and acetaldehyde showed that the glass ceramics exhibited effective photocatalytic activity. The activity did not depend on the radius of the M{sup 2+} or R{sup +} ion, and higher activity was observed in the MgTi{sub 4}(PO{sub 4}){sub 6} and CaTi{sub 4}(PO{sub 4}){sub 6} precipitated glass ceramics.

Fu, Jie, E-mail: fu@ohara-inc.co.jp [R and D Department, Ohara Inc., Sagamihara-shi, Kanagawa 252-5286 (Japan)] [R and D Department, Ohara Inc., Sagamihara-shi, Kanagawa 252-5286 (Japan)

2013-01-15T23:59:59.000Z

419

Jena Glass and its Applications to Science and Art  

Science Journals Connector (OSTI)

... pages, in which Dr. Hovestadt has collected a mass of information about the Jena glass. In a report on the scientific apparatus of the London Exhibition of 1876, Abbe ... Exhibition of 1876, Abbe called attention to the need for progress in the art of glass making if the microscope were to advance, and to the necessity, for obtaining ...

R. T. G.

1900-12-20T23:59:59.000Z

420

Production and Decay of Mediæval Stained Glass1  

Science Journals Connector (OSTI)

... THE earliest direct evidence as to the methods of mediaeval glass-painting is contained in the treatise of Theophilusv (“Diversarum Artium Schedula”), which ... half of the twelfth century; here one finds detailed instructions for the making of the glass as well as for its formation into the flat sheets or “tables” in which ...

1907-05-02T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Department of Electrical Engineering Spring 2011 Glass Block Solar Collector  

E-Print Network (OSTI)

to the sponsor. The collector incorporated a solar panel that charged a battery unit. The battery poweredPENNSTATE Department of Electrical Engineering Spring 2011 Glass Block Solar Collector Overview Pittsburgh Corning, a leading manufacturer of architectural glass blocks, wanted to incorporate a solar

Demirel, Melik C.

422

Effects of alteration product precipitation on glass dissolution  

Science Journals Connector (OSTI)

Abstract Understanding the mechanisms that control the durability of nuclear waste glass is paramount if reliable models are to be constructed so that the glass dissolution rate in a given geological repository can be calculated. Presently, it is agreed that (boro)silicate glasses dissolve in water at a rate dependent on the solution concentration of orthosilicic acid (H4SiO4) with higher [H4SiO4] leading to lower dissolution rates. Once the reaction has slowed as a result of the buildup of H4SiO4, another increase in the rate has been observed that corresponds to the precipitation of certain silica-bearing alteration products. However, it has also been observed that the concentration of silica-bearing solution species does not significantly decrease, indicating saturation, while other glass tracer elements concentrations continue to increase, indicating that the glass is still dissolving. In this study, we have used the Geochemist’s Workbench code to investigate the relationship between glass dissolution rates and the precipitation rate of a representative zeolitic silica-bearing alteration product, analcime [Na(AlSi2O6)?H2O]. To simplify the calculations, we suppressed all alteration products except analcime, gibbsite (Al(OH)3), and amorphous silica. The pseudo-equilibrium-constant matrix for amorphous silica was substituted for the glass pseudo-equilibrium-constant matrix because it has been shown that silicate glasses act as a silica-only solid with respect to kinetic considerations. In this article, we present the results of our calculations of the glass dissolution rate at different values for the analcime precipitation rate constant and the effects of varying the glass dissolution rate constant at a constant analcime precipitation rate constant. From the simulations we conclude, firstly, that the rate of glass dissolution is dependent on the kinetics of formation of the zeolitic phase. Therefore, the kinetics of secondary phase formation is an important parameter that should be taken into account in future glass dissolution modeling efforts. Secondly, the results indicate that, in the absence of a gel layer, the glass dissolution rate controls the rate of analcime precipitation in the long term. The meaning of these results pertinent to long-term glass durability is discussed.

Denis M. Strachan; James J. Neeway

2014-01-01T23:59:59.000Z

423

Crystallisation Within Simulated High Level Waste Borosilicate Glass Peter B. Rose, Michael I. Ojovan, Neil C. Hyatt and William E. Lee  

E-Print Network (OSTI)

molybdate with a powellite-type structure formed on the surface of both glasses after heat treatment in air heat treatment the glass developed a zektzerite-type phase, CeO2, a strontium molybdate (containing Nd-rich phase. Heat treatment of this glass resulted in the growth of the CeO2 crystals, the development

Sheffield, University of

424

Glass capable of ionic conduction and method of preparation  

DOE Patents (OSTI)

Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS[sub 2], B[sub 2]S[sub 3] and SiS[sub 2] in mixture with a glass modifier such as Na[sub 2]S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na[sub 2]O:XB[sub 2]S[sub 3] is disclosed. 4 figs.

Susman, S.; Delbecq, C.J.; Volin, K.J.; Boehm, L.

1984-02-21T23:59:59.000Z

425

Property Data for Simulated Americium/Curium Glasses  

SciTech Connect

The authors studied the properties of mixed lanthanide-alumino-borosilicate glasses. Fifty-five glasses were designed to augment a previous, Phase I, study by systematically varying the composition of Ln{sub 2}O{sub 3} and the concentrations of Ln{sub 2}O{sub 3}, SiO{sub 2}, B{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, and SrO in glass. These glasses were designed and fabricated at the Savannah River Technology Center and tested at the Pacific Northwest National Laboratory. The properties measured include the high-temperature viscosity ({eta}) as a function of temperature (T) and the liquidus temperature (T{sub L}) of Phase II test glasses.

Riley, B.J.; Smith, D.E.; Peeler, D.K.; Reamer, I.A.; Vienna, J.D.; Schweiger, M.J.

1999-10-20T23:59:59.000Z

426

IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM  

SciTech Connect

Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

2012-03-19T23:59:59.000Z

427

Iron Phosphate Glasses: An Alternative for Vitrifying Certain Nuclear Wastes  

SciTech Connect

Vitrification of nuclear waste in a glass is currently the preferred process for waste disposal. DOE currently approves only borosilicate (BS) type glasses for such purposes. However, many nuclear wastes, presently awaiting disposal, have complex and diverse chemical compositions, and often contain components that are poorly soluble or chemically incompatible in BS glasses. Such problematic wastes can be pre-processed and/or diluted to compensate for their incompatibility with a BS glass matrix, but both of these solutions increases the wasteform volume and the overall cost for vitrification. Direct vitrification using alternative glasses that utilize the major components already present in the waste is preferable, since it avoids pre-treating or diluting the waste, and, thus, minimizes the wasteform volume and overall cost.

Delbert E. Day; Chandra S. Ray; Cheol-Woon Kim

2004-12-28T23:59:59.000Z

428

Fabrication of TiO{sub 2} nanocrystallized glass  

SciTech Connect

Nanocrystallization of rutile and anatase was observed in a CaO-B{sub 2}O{sub 3}-Bi{sub 2}O{sub 3}-Al{sub 2}O{sub 3}-TiO{sub 2} crystallized glass. The color of the present crystallized glass was changed by the heat-treatment temperature, and x-ray diffraction (XRD) patterns of the crystallized glass show that the apparent color change is correlated with the formation of titania nanocrystallites. The particle size of crystallites observed in the transmission electron microscope image is comparable to that measured by XRD pattern. In addition, a large change of refractive index between the rutile particles and glass matrix, 0.8 or larger, was obtained. The present titania crystallized glass will be not only a photocatalytic material but also a promising candidate for random lasing devices.

Masai, Hirokazu; Fujiwara, Takumi; Mori, Hiroshi; Komatsu, Takayuki [Department of Applied Physics, Tohoku University, 6-6-05 Aoba, Sendai 980-8579 (Japan); Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka 940-2188 (Japan)

2007-02-19T23:59:59.000Z

429

Removal Rate Model for Magnetorheological Finishing of Glass  

SciTech Connect

Magnetorheological finishing (MRF) is a deterministic subaperture polishing process. The process uses a magntorheological (MR) fluid that consists of micrometer-sized, spherical, magnetic carbonyl iron (CI) particles, nonmagnetic polishing abrasives, water, and stabilizers. Material removal occurs when the CI and nonmagnetic polishing abrasives shear material off the surface being polished. We introduce a new MRF material removal rate model for glass. This model contains terms for the near surface mechanical properties of glass, drag force, polishing abrasive size and concentration, chemical durability of the glass, MR fluid pH, and the glass composition. We introduce quantitative chemical predictors for the first time, to the best of our knowledge, into an MRF removal rate model. We validate individual terms in our model separately and then combine all of the terms to show the whole MRF material removal model compared with experimental data. All of our experimental data were obtained using nanodiamond MR fluids and a set of six optical glasses.

DeGroote, J.E.; Marino, A.E.; WIlson, J.P.; Bishop, A.L.; Lambropoulos, J.C.; Jacobs, S.D.

2007-11-14T23:59:59.000Z

430

One-way glass for microwaves using nonreciprocal metamaterials  

Science Journals Connector (OSTI)

We introduce a class of nonreciprocal metamaterials based on composite assemblies of metallic and biased ferrimagnetic elements. We show that such structures act as ultrathin one-way glasses due to the competition between two modes at the surface of the ferrimagnetic elements—a low-loss surface wave that transmits the signal on the other side of the structure and a surface spin-wave resonance that produces strong isolation levels. These findings can be adapted to existing metamaterial geometries, offering a blueprint to achieve unidirectional propagation in a variety of artificial media at radio, microwave, and millimeter wave frequencies.

A. Degiron and D. R. Smith

2014-05-27T23:59:59.000Z

431

Lichens and their Action on the Glass and Leadings of Church Windows  

Science Journals Connector (OSTI)

... found only on unaltered glass; they do not persist, and on disappearing leave a roughened surface conformable to their own shape. On deeply corroded glass, lichen debris, not ...

E. MELLOR

1923-10-06T23:59:59.000Z

432

Flow Test At Glass Buttes Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

Flow Test At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Glass Buttes Area (DOE GTP) Exploration...

433

Ground Gravity Survey At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Ground Gravity Survey At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Glass Buttes Area...

434

Field Mapping At Glass Buttes Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

Field Mapping At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Glass Buttes Area (DOE GTP)...

435

Silicon-on-glass pore network micromodels with oxygen-sensing...  

NLE Websites -- All DOE Office Websites (Extended Search)

Silicon-on-glass pore network micromodels with oxygen-sensing fluorophore films for chemical imaging and defined spatial Silicon-on-glass pore network micromodels with...

436

Slim Holes At Glass Buttes Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area...

437

Atomic trigger shatters mystery of how glass deforms | ornl.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Atomic trigger shatters mystery of how glass deforms Bond switching underpins warping of strong metallic glasses Joint Institute for Neutron Sciences Director Takeshi Egami, left,...

438

Solid-state NMR examination of alteration layers on nuclear waste glasses  

Science Journals Connector (OSTI)

Abstract Solid-state nuclear magnetic resonance (NMR) is a powerful tool for probing the role and significance of alteration layers in determining the kinetics for the corrosion of nuclear waste glass. NMR methods are used to probe the chemical structure of the alteration layers to elucidate information about their chemical complexity, leading to increased insight into the mechanism of altered layer formation. Two glass compositions were examined in this study: a glass preliminarily designed for nuclear waste immobilization (called AFCI) and a simplified version of this AFCI glass (which we call SA1R). Powdered glasses with controlled and known particle sizes were corroded in ASTM type I water at 90 °C for periods of one and five months with a glass surface-area to solution-volume ratio of 100,000 m? 1. 1H–29Si cross-polarization Carr-Purcell-Meiboom-Gill (CP-CPMG) magic angle spinning (MAS) NMR, 1H–27Al CP-MAS NMR, 1H–11B CP-MAS NMR, and 1H–23Na CP-MAS NMR experiments provided isolated structural information about the alteration layers, which differ in structure from that of the pristine glass. Both glasses studied here develop alteration layers composed primarily of [IV]Si species. Aluminum is also retained in the alteration layers, perhaps facilitated by the observed increase in coordination from [IV]Al to [VI]Al, which correlates with a loss of charge balancing cations. The mechanism of increasing coordination appears to occur through an unstable [V]Al intermediate. 1H–11B CP-MAS NMR observations indicated a retention of boron in the hydrated glass layers, which has not been characterized by previous work. For the AFCI glass, secondary phase formation begins during the corrosion times considered here, and these new phases are detected within the alteration layers. We identify new phases (termed as precursor phases) as crystalline sodium metasilicates. An important finding is that simple glass compositions, while providing general trends about the formation of alteration layers, do not account for all of the various reaction products that occur in the corrosion of more complex nuclear waste glass compositions.

Kelly A. Murphy; Nancy M. Washton; Joseph V. Ryan; Carlo G. Pantano; Karl T. Mueller

2013-01-01T23:59:59.000Z

439

Glass transition line in C60: a mode-coupling/molecular-dynamics study  

E-Print Network (OSTI)

We report a study of the mode-coupling theory (MCT) glass transition line for the Girifalco model of C60 fullerene. The equilibrium static structure factor of the model, the only required input for the MCT calculations, is provided by molecular dynamics simulations. The glass transition line develops inside the metastable liquid-solid coexistence region and extends down in temperature, terminating on the liquid sideof the metastable portion of the liquid-vapor binodal. The vitrification locus does not show re-entrant behavior. A comparison with previous computer simulation estimates of the location of the glass line suggests that the theory accurately reproduces the shape of the arrest line in the density-temperature plane. The theoretical HNC and MHNC structure factors (and consequently the corresponding MCT glass line) compare well with the numerical counterpart. These evidences confirm the conclusion drawn in previous works about the existence of a glassy phase for the fullerene model at issue.

D. Costa; R. Ruberto; F. Sciortino; M. C. Abramo; C. Caccamo

2007-03-22T23:59:59.000Z

440

Effect of glass composition on activation energy of viscosity in glass-melting-temperature range  

SciTech Connect

In the high-temperature range, where the viscosity (Eta) of molten glass is <10{sup 3} Pa s, the activation energy (B) is virtually ln(Eta) = A + B/T, is nearly independent of melt composition. Hence, the viscosity-composition relationship for Eta < 10{sup 3} Pa s is defined by B as a function of composition. Using a database encompassing over 1300 compositions of high-level waste glasses with nearly 7000 viscosity data, we developed mathematical models for B(x), where x is the composition vector in terms of mass fractions of components. In this paper, we present 13 versions of B(x) as first- and second-order polynomials with coefficients for 15 to 39 components, including Others, a component that sums constituents having little effect on viscosity.

Hrma, Pavel R.; Han, Sang Soo

2012-08-01T23:59:59.000Z

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441

Direct measurement of the kinetics of volume and enthalpy relaxation of an Au-based bulk metallic glass  

SciTech Connect

Structural relaxation of glasses below their glass transition is a well-studied phenomenon that still poses several open issues. With the advent of bulk metallic glasses with exceptionally low glass transition temperatures, new options are available that are based on the experimental assessment of the time dependence of several different thermodynamic quantities by direct measurements with high accuracy. In this contribution the first direct measurement of the isothermal relaxation of the volume and the enthalpy of an Au-based bulk metallic glassformer are reported and discussed with respect of the characteristics describing the underlying processes.

Bünz, J.; Wilde, G. [Institute of Materials Physics, University of Münster, 48149 Münster (Germany)] [Institute of Materials Physics, University of Münster, 48149 Münster (Germany)

2013-12-14T23:59:59.000Z

442

Carrying Out and Developing the Glass Industry Vision and Roadmap  

SciTech Connect

In support of its obligations under the above-mentioned project, the GMIC performed the following tasks: (1) Provided two-way communications liaison services between the U.S. glass industry and the D.O.E. to ensure the needs and concerns of each party are effectively communicated to the other. (2) Updated and modified on a continuing basis and in response to evolving conditions within the glass industry, the goals and priorities outlined in the Glass Industry Vision and the Glass Technology Roadmap. (3) Established relationships with a wide variety of government and non-governmental organizations with interests in further improving the levels of technology, productivity and environmental responsibility of the glass industry. (4) Canvassed the glass industry on an ongoing basis to determine overall and specific sector needs for technological development. (5) Fostered direct contacts between member companies and national laboratories to facilitate the development of individual company technology development. (6) Advised the DOE on the key elements of the solicitation process in support of the Glass Industry Vision and Technology Roadmap. In the course of this contract, the membership of the GMIC has grown to include over 70% of the glass industry. This gives it the ability to communicate persuasively with the vast majority of this energy intensive industry. One of the principal benefits of the existence of the GMIC is that, for the first time in this country, representative companies of all major sectors of the glass industry are now in regular communication with each other. Prior to the existence and activity of the GMIC, companies and individuals in the flat glass, container glass, fiber glass and specialty glass sectors rarely had contact with each other, in spite of the fact that they all face similar challenges and can benefit from pre-competitive research conducted to the benefit of the broad industry. The development of innovations in the industry under cost-shared DOE/industry research projects such as new melting technologies, sensors and controls, modeling programs, energy efficiency tools, etc. has led to substantial increases in energy efficiency in the industry. Increased energy efficiency results in increased job opportunities in the industry that has been negatively impacted by increases in energy costs, globalization and increased environmental controls.

Michael Greenman

2007-06-14T23:59:59.000Z

443

Cogeneration from glass furnace waste heat recovery  

SciTech Connect

In glass manufacturing 70% of the total energy utilized is consumed in the melting process. Three basic furnaces are in use: regenerative, recuperative, and direct fired design. The present paper focuses on secondary heat recovery from regenerative furnaces. A diagram of a typical regenerative furnace is given. Three recovery bottoming cycles were evaluated as part of a comparative systems analysis: steam Rankine Cycle (SRC), Organic Rankine Cycle (ORC), and pressurized Brayton cycle. Each cycle is defined and schematicized. The net power capabilities of the three different systems are summarized. Cost comparisons and payback period comparisons are made. Organic Rankine cycle provides the best opportunity for cogeneration for all the flue gas mass flow rates considered. With high temperatures, the Brayton cycle has the shortest payback period potential, but site-specific economics need to be considered.

Hnat, J.G.; Cutting, J.C.; Patten, J.S.

1982-06-01T23:59:59.000Z

444

Precision diamond grinding of ceramics and glass  

SciTech Connect

A new research initiative will be undertaken to investigate the effect of machine parameters and material properties on precision diamond grinding of ceramics and glass. The critical grinding depth to initiate the plastic flow-to-brittle fracture regime will be directly measured using plunge-grind tests. This information will be correlated with machine parameters such as wheel bonding and diamond grain size. Multiaxis grinding tests will then be made to provide data more closely coupled with production technology. One important aspect of the material property studies involves measuring fracture toughness at the very short crack sizes commensurate with grinding damage. Short crack toughness value`s can be much less than the long-crack toughness values measured in conventional fracture tests.

Smith, S.; Paul, H.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

445

Summary Report: Glass-Ceramic Waste Forms for Combined Fission Products  

SciTech Connect

Glass-ceramic waste form development began in FY 2010 examining two combined waste stream options: (1) alkaline earth (CS) + lanthanide (Ln), and (2) + transition metal (TM) fission-product waste streams generated by the uranium extraction (UREX+) separations process. Glass-ceramics were successfully developed for both options however; Option 2 was selected over Option 1, at the conclusion of 2010, because Option 2 immobilized all three waste streams with only a minimal decrease in waste loading. During the first year, a series of three glass (Option 2) were fabricated that varied waste loading-WL (42, 45, and 50 mass%) at fixed molar ratios of CaO/MoO{sub 3} and B{sub 2}O{sub 3}/alkali both at 1.75. These glass-ceramics were slow cooled and characterized in terms of phase assemblage and preliminary irradiation stability. This fiscal year, further characterization was performed on the FY 2010 Option 2 glass-ceramics in terms of: static leach testing, phase analysis by transmission electron microscopy (TEM), and irradiation stability (electron and ion). Also, a new series of glass-ceramics were developed for Option 2 that varied the additives: Al{sub 2}O{sub 3} (0-6 mass%), molar ratio of CaO/MoO{sub 3} and B{sub 2}O{sub 3}/alkali (1.75 to 2.25) and waste loading (50, 55, and 60 mass%). Lastly, phase pure powellite and oxyapatite were synthesized for irradiation studies. Results of this fiscal year studies showed compositional flexibility, chemical stability, and radiation stability in the current glass-ceramic system. First, the phase assemblages and microstructure of all of the FY 2010 and 2011 glass-ceramics are very similar once subjected to the slow cool heat treatment. The phases identified in these glass-ceramics were oxyapatite, powellite, cerianite, and ln-borosilicate. This shows that variations in waste loading or additives can be accommodated without drastically changing the phase assemblage of the waste form, thus making the processing and performance characteristics of the waste form more predictable/flexible. However, in the future, the glass phase still needs to be accurately characterized to determine the effects of waste loading and additives on the glass structure. Initial investigations show a borosilicate glass phase rich in silica. Second, the normalized concentrations of elements leached from the waste form during static leach testing were all below 0.6 g/L after 28d at 90 C, by the Product Consistency Test (PCT), method B. These normalized concentrations are on par with durable waste glasses such as the Low-Activity Reference Material (LRM) glass. The release rates for the crystalline phases (oxyapatite and powellite) appear to be lower (more durable) than the glass phase based on the relatively low release rates of Mo, Ca, and Ln found in the crystalline phases compared to Na and B that are mainly observed in the glass phase. However, further static leach testing on individual crystalline phases is needed to confirm this statement. Third, Ion irradiation and In situ TEM observations suggest that these crystalline phases (such as oxyapatite, ln-borosilicate, and powellite) in silicate based glass ceramic waste forms exhibit stability to 1000 years at anticipated doses (2 x 10{sup 10}-2 x 10{sup 11} Gy). This is adequate for the short lived isotopes in the waste, which lead to a maximum cumulative dose of {approx}7 x 10{sup 9} Gy, reached after {approx}100 yrs, beyond which the dose contributions are negligible. The cumulate dose calculations are based on a glass-ceramic at WL = 50 mass%, where the fuel has a burn-up of 51GWd/MTIHM, immobilized after 5 yr decay from reactor discharge.

Crum, Jarrod V.; Riley, Brian J.; Turo, Laura A.; Tang, Ming; Kossoy, Anna

2011-09-23T23:59:59.000Z

446

Enabling Tool for Innovative Glass Applications - Final Report  

SciTech Connect

The use of abrasive waterjet (AWJ) cutting systems in the industrial sector has been limited to applications that are difficult to machine using conventional methods. A major factor for this limited use is the high cost of the garnet abrasive currently used. Initial studies indicated that glass can be processed to produce particles with the desired characteristics at a fraction of the existing price of garnet. Inexpensive abrasive waterjet cutting systems would allow a wider array of glass products to be produced while eliminating many existing design limitations. Availability of low-cost abrasive waterjet cutting media would open new markets for glass applications by making glass a more versatile material. A fundamental goal of this project was to scale up and refine the circuit that was established in the initial phase of this project, which using waste glass as a feed stream, could economically produce glass particles displaying high angularity, sharp edges and a low aspect ratio which would prove suitable for use in abrasive waterjet (AWJ) cutting systems. Using commercial scale equipment, demonstration runs were conducted at various manufacturers facilities to further establish that waste glass is a viable source for the production of an inexpensive AWJ media for use in cutting glass and a variety of other materials. The glass abrasive produced was used to demonstrate that processed waste glass could serve as a less costly alternative to garnet in many AWJ cutting applications. Studies indicated that glass can be processed to produce particles with the desired characteristics at less than 1% of the existing price of garnet. The waste stream resulting from the use of the glass abrasive in an AWJ system was in turn used as a source for inexpensive fillers in various polymers. The reduced energy requirements needed to produce glass abrasives and lower cost associated with the use of waste glass over garnet, as well as the environmental benefits associated with the recycling of glass waste streams were the primary objectives of this project. The use of the glass abrasive produced in this study did not result in feed rates as high as was expected when used as the media in the cutting of plate glass products. Furthermore, the process and equipment refinements that have been implemented at the PPG and Donnelly facilities since this project was initiated have also served to reduce their energy requirements and in turn the cost associated with the production of sidelites and foiled prisms using conventional means. In addition, further improvements would have to be realized in the cutting of these harder materials before the use of an AWJ system could be viewed as an economically viable means of establishing the perimeter of either product. The possibility of tempering to increase the hardness of the glass media may be one means of achieving this goal.

James M. Gillis

2005-11-16T23:59:59.000Z

447

Molten Oxide Glass Materials for Thermal Energy Storage  

Science Journals Connector (OSTI)

Abstract Halotechnics, Inc. is developing an energy storage system utilizing a low melting point molten glass as the heat transfer and thermal storage material. This work is supported under a grant from the Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E). Advanced oxide glasses promise a potential breakthrough as a low cost, earth abundant, and stable thermal storage material. The system and new glass material will enable grid scale electricity storage at a fraction of the cost of batteries by integrating the thermal storage with a large heat pump device. Halotechnics is combining its proven expertise in combinatorial chemistry with advanced techniques for handling molten glass to design and build a two-tank thermal energy storage system. This system, operating at a high temperature of 1200 °C and a low temperature of 400 °C, will demonstrate sensible heat thermal energy storage using a uniquely formulated oxide glass. Our molten glass thermal storage material has the potential to significantly reduce thermal storage costs once developed and deployed at commercial scale. Thermal storage at the target temperature can be integrated with existing high temperature gas turbines that significantly increase efficiencies over today's steam turbine technology. This paper describes the development and selection of Halotechnics’ molten glass heat transfer fluids with some additional systems considerations.

B. Elkin; L. Finkelstein; T. Dyer; J. Raade

2014-01-01T23:59:59.000Z

448

Waste glass corrosion modeling: Comparison with experimental results  

SciTech Connect

A chemical model of glass corrosion will be used to predict the rates of release of radionuclides from borosilicate glass waste forms in high-level waste repositories. The model will be used both to calculate the rate of degradation of the glass, and also to predict the effects of chemical interactions between the glass and repository materials such as spent fuel, canister and container materials, backfill, cements, grouts, and others. Coupling between the degradation processes affecting all these materials is expected. Models for borosilicate glass dissolution must account for the processes of (1) kinetically-controlled network dissolution, (2) precipitation of secondary phases, (3) ion exchange, (4) rate-limiting diffusive transport of silica through a hydrous surface reaction layer, and (5) specific glass surface interactions with dissolved cations and anions. Current long-term corrosion models for borosilicate glass employ a rate equation consistent with transition state theory embodied in a geochemical reaction-path modeling program that calculates aqueous phase speciation and mineral precipitation/dissolution. These models are currently under development. Future experimental and modeling work to better quantify the rate-controlling processes and validate these models are necessary before the models can be used in repository performance assessment calculations.

Bourcier, W.L.

1993-11-01T23:59:59.000Z

449

Low melting high lithia glass compositions and methods  

DOE Patents (OSTI)

The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

Jantzen, Carol M. (Aiken, SC); Pickett, John B. (Aiken, SC); Cicero-Herman, Connie A. (Aiken, SC); Marra, James C. (Aiken, SC)

2000-01-01T23:59:59.000Z

450

Glass Fragility and Atomic Ordering on the Intermediate and Extended Range  

Science Journals Connector (OSTI)

The relation between the fragility of glass-forming systems, a parameter which describes many of their key physical characteristics, and atomic scale structure is investigated by using neutron diffraction to measure the topological and chemical ordering for germania, or GeO2, which is an archetypal strong glass former. We find that the ordering for this and other tetrahedral network-forming glasses at distances greater than the nearest neighbor can be rationalized in terms of an interplay between the relative importance of two length scales. One of these is associated with an intermediate range, the other with an extended range and, with increasing glass fragility, it is the extended range ordering which dominates.

Philip S. Salmon; Adrian C. Barnes; Richard A. Martin; Gabriel J. Cuello

2006-06-13T23:59:59.000Z

451

Chalcogenide Glass Radiation Sensor; Materials Development, Design and Device Testing  

SciTech Connect

For many decades, various radiation detecting material have been extensively researched, to find a better material or mechanism for radiation sensing. Recently, there is a growing need for a smaller and effective material or device that can perform similar functions of bulkier Geiger counters and other measurement options, which fail the requirement for easy, cheap and accurate radiation dose measurement. Here arises the use of thin film chalcogenide glass, which has unique properties of high thermal stability along with high sensitivity towards short wavelength radiation. The unique properties of chalcogenide glasses are attributed to the lone pair p-shell electrons, which provide some distinctive optical properties when compared to crystalline material. These qualities are derived from the energy band diagram and the presence of localized states in the band gap. Chalcogenide glasses have band tail states and localized states, along with the two band states. These extra states are primarily due to the lone pair electrons as well as the amorphous structure of the glasses. The localized states between the conductance band (CB) and valence band (VB) are primarily due to the presence of the lone pair electrons, while the band tail states are attributed to the Van der Waalâ??s forces between layers of atoms [1]. Localized states are trap locations within the band gap where electrons from the valence band can hop into, in their path towards the conduction band. Tail states on the other hand are locations near the band gap edges and are known as Urbach tail states (Eu). These states are occupied with many electrons that can participate in the various transformations due to interaction with photons. According to Y. Utsugi et. al.[2], the electron-phonon interactions are responsible for the generation of the Urbach tails. These states are responsible for setting the absorption edge for these glasses and photons with energy near the band gap affect these states. We have studied the effect of x-rays and γ-rays, on thin film chalcogenide glasses and applied them in conjunction with film incorporating a silver source in a new type of radiation sensor for which we have an US patent application [3]. In this report, we give data about our studies regarding our designed radiation sensor along with the testing and performance at various radiation doses. These studies have been preceded by materials characterization research related to the compositional and structural characteristics of the active materials used in the radiation sensor design. During the work on the project, we collected a large volume of material since every experiment was repeated many times to verify the results. We conducted a comprehensive material research, analysis and discussion with the aim to understand the nature of the occurring effects, design different structures to harness these effects, generated models to aid in the understanding the effects, built different device structures and collected data to quantify device performance. These various aspects of our investigation have been detailed in previous quarterly reports. In this report, we present our main results and emphasize on the results pertaining to the core project goals â?? materials development, sensor design and testing and with an emphasis on classifying the appropriate material and design for the optimal application. The report has three main parts: (i) Presentation of the main data; (ii) Bulleted summary of the most important results; (iii) List of the patent, journal publications, conference proceedings and conferences participation, occurring as a result of working on the project.

Mitkova, Maria; Butt, Darryl; Kozicki, Michael; Barnaby, Hugo

2013-04-30T23:59:59.000Z

452

Inverse Freezing in Mean-Field Models of Fragile Glasses  

E-Print Network (OSTI)

A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the ``random-first order'' scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favoured an inverse static glass transition and a double inverse dynamic freezing appear.

Mauro Sellitto

2006-03-14T23:59:59.000Z

453

Inverse freezing in mean-field models of fragile glasses  

Science Journals Connector (OSTI)

A disordered spin model suitable for studying inverse freezing in fragile glass-forming systems is introduced. The model is a microscopic realization of the “random first-order” scenario in which the glass transition can be either continuous or discontinuous in thermodynamic sense. The phase diagram exhibits a first-order transition line between two fluid phases terminating at a critical point. When the interacting degrees of freedom are entropically favored, an inverse static glass transition and a double inverse dynamic freezing appear.

Mauro Sellitto

2006-05-30T23:59:59.000Z

454

Photon Interaction Studies with Some Glasses and Building Materials  

SciTech Connect

Mass attenuation coefficients of some shielding materials, namely, Bakelite, black cement, white cement, plaster of paris, and concrete were determined at 356-, 511-, 662-, 1173-, and 1332-keV energies, and those of glasses containing oxides of B, Cd, Pb, and Bi were determined only at 662 keV using a narrow beam transmission method. These coefficients of glasses were then used to determine their interaction cross sections, effective atomic numbers, and electron densities. Good agreement was observed between the experimental and theoretical values. It has been proven that glasses have a potential application as a transparent radiation shielding.

Singh, Harvinder [Guru Nanak Dev University (India); Singh, Kulwant [Guru Nanak Dev University (India); Sharma, Gopi [Guru Nanak Dev University (India); Nathuram, R. [Bhabha Atomic Research Centre (India); Sahota, H.S. [Punjabi University (India)

2002-11-15T23:59:59.000Z

455

Ultrafast pulsed laser utilizing broad bandwidth laser glass  

DOE Patents (OSTI)

An ultrafast laser uses a Nd-doped phosphate laser glass characterized by a particularly broad emission bandwidth to generate the shortest possible output pulses. The laser glass is composed primarily of P{sub 2}O{sub 5}, Al{sub 2}O{sub 3} and MgO, and possesses physical and thermal properties that are compatible with standard melting and manufacturing methods. The broad bandwidth laser glass can be used in modelocked oscillators as well as in amplifier modules. 7 figs.

Payne, S.A.; Hayden, J.S.

1997-09-02T23:59:59.000Z

456

Tamper-indicating device having a glass body  

DOE Patents (OSTI)

A tamper-indicating device is described. The device has a first glass body member and a second glass body member that are attached to each other through a hasp. The glass body members of the device can be tempered. The body members can be configured with hollow volumes into which powders, microparticles, liquids, gels, or combinations thereof are sealed. The choice, the amount, and the location of these materials can produce a visible, band pattern to provide each body member with a unique fingerprint identifier, which makes it extremely difficult to repair or replace once it is damaged in order to avoid tamper detection.

Johnston, Roger G. (Los Alamos, NM); Garcia, Anthony R. E. (Espanola, NM)

2003-04-29T23:59:59.000Z

457

Contribution of atom-probe tomography to a better understanding of glass alteration mechanisms: application to a nuclear glass specimen altered 25 years in a granitic environment  

SciTech Connect

We report and discuss results of atom probe tomography (APT) and energy-filtered transmission electron microscopy (EFTEM) applied to a borosilicate glass sample of nuclear interest altered for nearly 26 years at 90°C in a confined granitic medium in order to better understand the rate-limiting mechanisms under conditions representative of a deep geological repository for vitrified radioactive waste. The APT technique allows the 3D reconstruction of the elemental distribution at the reactive interphase with sub-nanometer precision. Profiles of the B distribution at pristine glass/hydrated glass interface obtained by different techniques are compared to show the challenge of accurate measurements of diffusion profiles at this buried interface on the nanometer length scale. Our results show that 1) Alkali from the glass and hydrogen from the solution exhibit anti-correlated 15 ± 3 nm wide gradients located between the pristine glass and the hydrated glass layer, 2) boron exhibits an unexpectedly sharp profile located just at the outside of the alkali/H interdiffusion layer; this sharp profile is more consistent with a dissolution front than a diffusion-controlled release of boron. The resulting apparent diffusion coefficients derived from the Li and H profiles are DLi = 1.5 × 10-22 m2.s-1 and DH = 6.8 × 10-23 m2.s-1. These values are around two orders of magnitude lower than those observed at the very beginning of the alteration process, which suggests that interdiffusion is slowed at high reaction progress by local conditions that could be related to the porous structure of the interphase. As a result, the accessibility of water to the pristine glass could be the rate-limiting step in these conditions. More generally, these findings strongly support the importance of interdiffusion coupled with hydrolysis reactions of the silicate network on the long-term dissolution rate, contrary to what has been suggested by recent interfacial dissolution-precipitation models for silicate minerals.

Gin, Stephane [CEA Marcoule DTCD SECM LCLT, Bagnols-sur-Ceze (France); Ryan, Joseph V. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Schreiber, Daniel K. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Neeway, James J. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Cabie, M. [Aix-Marseille Universite, CP2M, Marseille (France)

2013-06-26T23:59:59.000Z

458

Effects of the iron content and redox state on the structure of sodium borosilicate glasses: A Raman, Moessbauer and boron K-edge XANES spectroscopy study  

SciTech Connect

The structure of iron-bearing sodium borosilicate glasses with up to 10 mol% FeO has been investigated in the range 0.15 ? Fe{sup 3+}/SFe ? 0.95. According to Moessbauer spectroscopy, Fe{sup 3+} and Fe{sup 2+} are mainly in tetrahedral and octahedral coordination, respectively, although other coordination states exist for both cations. From XANES experiments, we conclude that increasing Fe content and varying redox states have only a minor effect on the relative proportions of BO{sub 3} and BO{sub 4} units. In Raman spectra, a decrease of the proportion of BO{sub 4} species present in danburite-like units (Na{sub 2}O.B{sub 2}O{sub 3}.2SiO{sub 2}) is found upon increasing iron content and oxidizing state. Whereas the insensitivity of the overall boron speciation to iron content and redox state points to weak interactions between boron and iron, the changes affecting BO{sub 4} species do indicate a more subtle interplay between Fe{sup 3+} and the other tetrahedrally coordinated cations (Si,B) because of the competition between tetrahedral Fe{sup 3+} and B{sup 3+} for charge compensation by Na{sup +}. (authors)

Cochain, B. [CEA, DEN, SECM, LDMC, Bagnols Sur Ceze, (France); IPGP-CNRS, Universite Paris 7, Sorbonne Paris Cite Paris, (France); Geology Department, University of Toronto, Toronto, (Canada); Neuville, D.R.; Richet, P. [Univ Paris 07, IPGP CNRS, Paris, (France); Henderson, G.S. [Univ Toronto, Dept Geol, Toronto, ON, (Canada); McCammon, C.A. [Univ Bayreuth, Bayer Geoinst, Bayreuth, (Germany)

2012-03-15T23:59:59.000Z

459

Seeing through Obscure Glass Qi Shan, Brian Curless, and Tadayoshi Kohno  

E-Print Network (OSTI)

condition for successful deconvolution) and minimize: Digital approach requires: sparse-kernel glass, access

Zhang, Li

460

Glass Buttes Exploration and Drilling: 2010 Geothermal Technologies Program Peer Review Presentation, Walsh, et al, Ormat  

SciTech Connect

Glass Buttes Exploration and Drilling: 2010 Geothermal Technologies Program Peer Review Presentation, Walsh, et al, Ormat

Ezra Zemach

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The Glass Box offers a unique environment to support research, development and evaluation of software  

E-Print Network (OSTI)

The Glass Box offers a unique environment to support research, development and evaluation of software products used by workers performing real computer- based tasks. The Glass Box instrumentation and to retrieve, store, and share Glass Box data. · Test Bed environment­Glass Box serves as a test bed

462

Orientational ordering of short LC rods in an anisotropic liquid crystalline polymer glass  

E-Print Network (OSTI)

Orientational ordering of short LC rods in an anisotropic liquid crystalline polymer glass Lorin the glass transition is determined by field theory. Microscopic anisotropic interactions can align the LC the glass transition. Host anisotropic glass formers made of mesogens with side chains were studied recently

Cao, Jianshu

463

Alkaline resistant phosphate glasses and method of preparation and use thereof  

DOE Patents (OSTI)

A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.

Brow, Richard K. (Rolla, MO); Reis, Signo T. (Rolla, MO); Velez, Mariano (Rolla, MO); Day, Delbert E. (Rolla, MO)

2010-01-26T23:59:59.000Z

464

Preparation of Bi-Sr-Ca-Cu-O superconductors from oxide-glass precursors  

DOE Patents (OSTI)

A superconductor and precursor therefor from oxide mixtures of Ca, Sr, Bi and Cu. Glass precursors quenched to elevated temperatures result in glass free of crystalline precipitates having enhanced mechanical properties. Superconductors are formed from the glass precursors by heating in the presence of oxygen to a temperature below the melting point of the glass.

Hinks, David G. (Lemont, IL); Capone, II, Donald W. (Northbridge, MA)

1992-01-01T23:59:59.000Z

465

Dating the Glass Lake Dugout by Dendrochronology (NY State Museum #CN-37516)  

E-Print Network (OSTI)

Dating the Glass Lake Dugout by Dendrochronology (NY State Museum #CN-37516) Carol Griggs, Dendrochronology Lab, Cornell University, cbg4@cornell.edu The Glass Lake Dugout was found at the bottom of Glass for the Glass Lake Dugout (Figure 2B). The series was compared with other site and regional white pine

Manning, Sturt

466

Breaking Through the Glass Ceiling: Recent Experimental Approaches to Probe the Properties of Supercooled Liquids near the Glass Transition.  

SciTech Connect

Experimental measurements of the properties supercooled liquids at temperatures near their respective glass transition temperatures, Tg, are requisite for understanding the behavior of glasses and amorphous solids. Unfortunately, many supercooled molecular liquids rapidly crystallize at temperatures far above their Tg making such measurements difficult to nearly impossible. In this perspective we discuss some recent alternative approaches to obtain experimental data in the temperature regime near Tg. These new approaches may yield the additional experimental data necessary to test current theoretical models of the dynamical slowdown that occurs in supercooled liquids approaching the glass transition.

Smith, R. Scott; Kay, Bruce D.

2012-03-15T23:59:59.000Z

467

Smart Glass Based on Micro-Blinds (MEMS)  

NLE Websites -- All DOE Office Websites (Extended Search)

Smart Glass Based on Micro-Blinds (MEMS) Smart Glass Based on Micro-Blinds (MEMS) Speaker(s): Boris Lamontagne Date: June 22, 2012 - 2:00pm Location: 90-3122 Seminar Host/Point of Contact: Stephen Selkowitz At the National Research Council, Canada we are developing a new type of smart glass based on micro-blinds (MEMS). The micro-blinds are tiny stressed metallic foils curling up once released or rolling down once actuated using electrostatic forces. Such smart glass is characterized by fast switching speed, UV-temperature insensitive and neutral appearance. Recent results will be presented as a well as our demo. Transmittance and thermal characteristics will also be addressed. There are various possible applications in building, automotive, aerospace as well as in display sectors. A video briefly describing the technology is

468

The effect of moisture on a glass/epoxy composite  

E-Print Network (OSTI)

Research was done to determine the effect of moisture on the transverse tensile strength and the interfacial shear strength of a glass/epoxy composite. Specimens with two different fiber sizings, one epoxy compatible and one vinyl-ester compatible...

Chatawanich, Candy Suda

2012-06-07T23:59:59.000Z

469

Spectral broadening in femtosecond laser written waveguides in chalcogenide glass  

Science Journals Connector (OSTI)

Nonlinear spectral broadening to 200 nm, from an initial width of 50 nm, has been demonstrated in gallium lanthanum sulphide glass waveguides from 1540 nm, 200 fs pulses at 30...

Hughes, Mark A; Yang, Weijia; Hewak, Daniel W

2009-01-01T23:59:59.000Z

470

Conical-Indenter Penetration Viscometry on Thin Glass Plates  

Science Journals Connector (OSTI)

A method is proposed for calculating the viscosity of glasses from the rate of penetration of a conical indenter into thin samples ... mm under conditions of continuous heating at a rate ranging from 1 to 10 K/mi...

V. P. Klyuev

2001-09-01T23:59:59.000Z

471

Sydney opera house glass walls: Colour measurement and control  

Science Journals Connector (OSTI)

One of the architectural requirements of the tinted laminated glass used in the construction of the Sydney Opera House glass walls was that it should be uniform in colour relative to an initially accepted colour standard. As the glass was manufactured in small batches over a two year period, stringent controls were needed to maintain the necessary colour quality of the laminate. The procedures adopted to check uniformity of colour are described and results are given of colorimetric analyses carried out on the colour standards and the production control specimens. The chromaticity data are interpreted in terms of subjective colour discrimination and are shown to be compatible with visual observations of the glass in situ.

J.A. Hooper; M.P. Wassall

1975-01-01T23:59:59.000Z

472

Initial Results of Advanced Glass Slumping for Commercial CSP Systems  

Science Journals Connector (OSTI)

We present the initial results of advanced glass slumping for commercial CSP systems. It is shown that the fast-slumping process is repeatable and accurate using a furnace and curved...

Stalcup, Thomas; Hammer, Kimberly; Lesser, David; Olbert, Blain; Warner, Steve; Wheelwright, Brian; Angel, Roger P; Villanueva, Jordi

473

Composite polymer: Glass edge cladding for laser disks  

DOE Patents (OSTI)

Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation. 18 figs.

Powell, H.T.; Wolfe, C.A.; Campbell, J.H.; Murray, J.E.; Riley, M.O.; Lyon, R.E.; Jessop, E.S.

1987-11-02T23:59:59.000Z

474

Composite polymer-glass edge cladding for laser disks  

DOE Patents (OSTI)

Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation.

Powell, Howard T. (Livermore, CA); Riley, Michael O. (San Ramon, CA); Wolfe, Charles R. (Palo Alto, CA); Lyon, Richard E. (Livermore, CA); Campbell, John H. (Livermore, CA); Jessop, Edward S. (Tracy, CA); Murray, James E. (Livermore, CA)

1989-01-01T23:59:59.000Z

475

Electron-beam-induced absorption in quartz glasses  

Science Journals Connector (OSTI)

Electron-beam-induced absorption in quartz glasses of types KS-4V, KU-1, and Corning 7940 has been experimentally investigated in the 150-1000-nm region. Samples of optical materials...

Sergeev, P B; Zvorykin, V D; Sergeev, A P; Ermolenko, T A; Popov, S A; Pronina, M S; Turoverov, P K; Cheremisin, I I; Evlampiev, I K

2004-01-01T23:59:59.000Z

476

ITP Glass: A Clear Vision for a Bright Future  

Energy.gov (U.S. Department of Energy (DOE))

This document presents perspectives on the glass industry's past, present and future, with special attention to competitive challenges now facing the industry and technological responses that will reinforce its continuing contribution...

477

Color-center dynamics in a lead glass fiber  

Science Journals Connector (OSTI)

We report on the formation of color centers in a lead glass fiber through two-photon absorption of a laser at 532 nm. The color centers can subsequently be photobleached by a weaker...

DeLong, K W; Saifi, M A; Andrejco, M J; Mizrahi, Victor; Stegeman, G I

1990-01-01T23:59:59.000Z

478

RETENTION OF SULFATE IN HIGH LEVEL RADIOACTIVE WASTE GLASS  

SciTech Connect

High level radioactive wastes are being vitrified at the Savannah River Site for long term disposal. Many of the wastes contain sulfate at concentrations that can be difficult to retain in borosilicate glass. This study involves efforts to optimize the composition of a glass frit for combination with the waste to improve sulfate retention while meeting other process and product performance constraints. The fabrication and characterization of several series of simulated waste glasses are described. The experiments are detailed chronologically, to provide insight into part of the engineering studies used in developing frit compositions for an operating high level waste vitrification facility. The results lead to the recommendation of a specific frit composition and a concentration limit for sulfate in the glass for the next batch of sludge to be processed at Savannah River.

Fox, K.

2010-09-07T23:59:59.000Z

479

THERMAL ANALYSIS OF WASTE GLASS MELTER FEED Pavel Hrma,  

NLE Websites -- All DOE Office Websites (Extended Search)

THERMAL ANALYSIS OF WASTE GLASS MELTER FEED Pavel Hrma, (a,b) David A. Pierce, (b) Richard Pokorn (b,c) (a) Division of Advanced Nuclear Engineering, Pohang University of Science...

480

Glass Does a Double-Take | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

| 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Glass Does a Double-Take APRIL 4, 2008 Bookmark and Share Predicted phase diagram as a...

Note: This page contains sample records for the topic "glass structural glass" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Atomistic mechanisms of cyclic hardening in metallic glass  

E-Print Network (OSTI)

Molecular dynamics with an embedded-atom method potential is used to simulate the nanoindentation of Cu[subscript 63.5]Zr[subscript 36.5] metallic glasses. In particular, the effects of cyclic loading within the nominal ...

Deng, Chuang

482

Quenched-vacancy induced spin-glass order  

E-Print Network (OSTI)

The ferromagnetic phase of an Ising model in d=3, with any amount of quenched antiferromagnetic bond randomness, is shown to undergo a transition to a spin-glass phase under sufficient quenched bond dilution. This result, ...

Gulpinar, Gul

483

Research Needs: Glass Solar Reflectance and Vinyl Siding  

SciTech Connect

The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

2011-07-07T23:59:59.000Z

484

Americium/curium extraction from a lanthanide borosilciate glass  

SciTech Connect

A solution containing kilogram quantities of highly radioactive isotopes of americium and curium (Am/Cm) and lanthanide fission products is currently stored in a process tank at the Department of Energy`s Savannah River Site (SRS). This tank and its vital support systems are old, subject to deterioration, and prone to possible leakage. For this reason, a program has been initiated to immobilize this material as a lanthanide borosilicate glass for safe long-term storage. The Am/Cm has commercial value and is desired for use by the heavy isotope programs at the Oak Ridge National Laboratory (ORNL). Therefore, a flowsheet was demonstrated using a curium-containing glass to extract these elements from the glass matrix. The method involved grinding the glass to less than 200 mesh and dissolving in concentrated nitric acid at 110{degrees}C. Under these conditions, the dissolution was essentially 100% after 2 hours except for silicon which remained mostly insoluble. Since the actual process conditions at ORNL could not be exactly simulated, the dissolution rate of a surrogate glass was measured using static and agitated conditions to bracket the expected rate. The measured rates, 0.040 to 0.0082 grams/hour-centimeter, were constant which allowed development of a predictive model for the time required to dissolve a glass particle of spherical geometry in terms of the glass density, particle size, and experimentally measured rate. The calculated time required to dissolve an idealized curium glass particle was in agreement with the experimental observation that dissolution was complete in less than 2 hours.

Rudisill, T.S.; Pareizs, J.M.; Ramsey, W.G.

1996-12-31T23:59:59.000Z

485

Metallic glass composition. [That does not embrittle upon annealing  

DOE Patents (OSTI)

This patent pertains to a metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon, carbon and phosphorous to which is added an amount of a ductility-enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, D.M.; Koch, C.C.

1984-09-14T23:59:59.000Z

486

SUMMARY OF FY11 SULFATE RETENTION STUDIES FOR DEFENSE WASTE PROCESSING FACILITY GLASS  

SciTech Connect

This report describes the results of studies related to the incorporation of sulfate in high level waste (HLW) borosilicate glass produced at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). A group of simulated HLW glasses produced for earlier sulfate retention studies was selected for full chemical composition measurements to determine whether there is any clear link between composition and sulfate retention over the compositional region evaluated. In addition, the viscosity of several glasses was measured to support future efforts in modeling sulfate solubility as a function of predicted viscosity. The intent of these studies was to develop a better understanding of sulfate retention in borosilicate HLW glass to allow for higher loadings of sulfate containing waste. Based on the results of these and other studies, the ability to improve sulfate solubility in DWPF borosilicate glasses lies in reducing the connectivity of the glass network structure. This can be achieved, as an example, by increasing the concentration of alkali species in the glass. However, this must be balanced with other effects of reduced network connectivity, such as reduced viscosity, potentially lower chemical durability, and in the case of higher sodium and aluminum concentrations, the propensity for nepheline crystallization. Future DWPF processing is likely to target higher waste loadings and higher sludge sodium concentrations, meaning that alkali concentrations in the glass will already be relatively high. It is therefore unlikely that there will be the ability to target significantly higher total alkali concentrations in the glass solely to support increased sulfate solubility without the increased alkali concentration causing failure of other Product Composition Control System (PCCS) constraints, such as low viscosity and durability. No individual components were found to provide a significant improvement in sulfate retention (i.e., an increase of the magnitude necessary to have a dramatic impact on blending, washing, or waste loading strategies for DWPF) for the glasses studied here. In general, the concentrations of those species that significantly improve sulfate solubility in a borosilicate glass must be added in relatively large concentrations (e.g., 13 to 38 wt % or more of the frit) in order to have a substantial impact. For DWPF, these concentrations would constitute too large of a portion of the frit to be practical. Therefore, it is unlikely that specific additives may be introduced into the DWPF glass via the frit to significantly improve sulfate solubility. The results presented here continue to show that sulfate solubility or retention is a function of individual glass compositions, rather than a property of a broad glass composition region. It would therefore be inappropriate to set a single sulfate concentration limit for a range of DWPF glass compositions. Sulfate concentration limits should continue to be identified and implemented for each sludge batch. The current PCCS limit is 0.4 wt % SO{sub 4}{sup 2-} in glass, although frit development efforts have led to an increased limit of 0.6 wt % for recent sludge batches. Slightly higher limits (perhaps 0.7-0.8 wt %) may be possible for future sludge batches. An opportunity for allowing a higher sulfate concentration limit at DWPF may lay lie in improving the laboratory experiments used to set this limit. That is, there are several differences between the crucible-scale testing currently used to define a limit for DWPF operation and the actual conditions within the DWPF melter. In particular, no allowance is currently made for sulfur partitioning (volatility versus retention) during melter processing as the sulfate limit is set for a specific sludge batch. A better understanding of the partitioning of sulfur in a bubbled melter operating with a cold cap as well as the impacts of sulfur on the off-gas system may allow a higher sulfate concentration limit to be established for the melter feed. This approach would have to be taken carefully to ensure that a

Fox, K.; Edwards, T.

2012-05-08T23:59:59.000Z

487

THERMAL ANALYSIS OF WASTE GLASS MELTER FEEDS  

SciTech Connect

Melter feeds for high-level nuclear waste (HLW) typically contain a large number of constituents that evolve gas on heating, Multiple gas-evolving reactions are both successive and simultaneous, and include the release of chemically bonded water, reactions of nitrates with organics, and reactions of molten salts with solid silica. Consequently, when a sample of a HLW feed is subjected to thermogravimetric analysis (TGA), the rate of change of the sample mass reveals multiple overlapping peaks. In this study, a melter feed, formulated for a simulated high-alumina HLW to be vitrified in the Waste Treatment and Immobilization Plant, currently under construction at the Hanford Site in Washington State, USA, was subjected to TGA. In addition, a modified melter feed was prepared as an all-nitrate version of the baseline feed to test the effect of sucrose addition on the gas-evolving reactions. Activation energies for major reactions were determined using the Kissinger method. The ultimate aim of TGA studies is to obtain a kinetic model of the gas-evolving reactions for use in mathematical modeling of the cold cap as an element of the overall model of the waste-glass melter. In this study, we focused on computing the kinetic parameters of individual reactions without identifying their actual chemistry, The rough provisional model presented is based on the first-order kinetics.

KRUGER AA; HRMA PR; POKORNY R; PIERCE DA

2011-10-21T23:59:59.000Z

488

Open-cell glass crystalline porous material  

DOE Patents (OSTI)

An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

Anshits, Alexander G. (Krasnoyarsk, RU); Sharonova, Olga M. (Krasnoyarsk, RU); Vereshchagina, Tatiana A. (Krasnoyarsk, RU); Zykova, Irina D. (Krasnoyarsk, RU); Revenko, Yurii A. (Zheleznogorsk, RU); Tretyakov, Alexander A. (Zheleznogorsk, RU); Aloy, Albert S. (Saint-Petersburg, RU); Lubtsev, Rem I. (Saint-Petersburg, RU); Knecht, Dieter A. (Idaho Falls, ID); Tranter, Troy J. (Idaho Falls, ID); Macheret, Yevgeny (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

489

The glass pipeline: increasing supply chain  

Science Journals Connector (OSTI)

Based upon a year-long project carried out at a UK luxury carmaker, this paper argues for a supply chain where upstream synchronisation is improved by the use of primary demand to calculate second and third-tier component requirements. The paper formulates a case for further developments to the established automotive ''sequenced'' supply model, where synchronised and lean first tiers are frequently supplied by lower tiers that carry higher stock levels, and whose production patterns bear little relationship to primary demand. The proposed development aims to enhance synchronisation of the lower portion of the chain that is outside the reach of full ''sequenced'' supply, but, within the time horizon of the vehicle manufacturers firm build schedule. This ''synchronised'' portion of the chain is achieved through increased information transparency, and hence the term ''glass pipeline'' has been used as a label for the proposed model. A case study illustration of the concept is presented, and a prototype is tested with a series of trials across a four-tier supply chain. A method for measuring synchronisation is developed, and associated business benefits are calculated in order to evaluate the model.

Julian Coleman; Andrew Lyons; Dennis Kehoe

2004-01-01T23:59:59.000Z

490

Statistics of modifier distributions in mixed network glasses  

Science Journals Connector (OSTI)

The constituents of any network glass can be broadly classified as either network formers or network modifiers. Network formers such as SiO2 Al2O3 B2O3 P2O5 etc. provide the backbone of the glass network and are the primary source of its rigid constraints. Network modifiers play a supporting role such as charge stabilization of the network formers or alteration of the network topology through rupture of bridging bonds and introduction of floppy modes. The specific role of the modifiers depends on which network formers are present in the glass and the relative free energies of modifier interactions with each type of network former site. This variation of free energy with modifier speciation is responsible for the so-called mixed network former effect i.e. the nonlinear scaling of property values in glasses having fixed modifier concentration but a varying ratio of network formers. In this paper a general theoretical framework is presented describing the statistical mechanics of modifier speciation in mixed network glasses. The model provides a natural explanation for the mixed network former effect and also accounts for the impact of thermal history and relaxation on glass network topology.

John C. Mauro

2013-01-01T23:59:59.000Z

491

Development of a process control sensor for the glass industry  

SciTech Connect

This project was initiated to fill a need in the glass industry for a non-contact temperature sensor for glass melts. At present, the glass forming industry (e.g., bottle manufacture) consumes significant amounts of energy. Careful control of temperature at the point the bottle is molded is necessary to prevent the bottle from being rejected as out-of-specification. In general, the entire glass melting and conditioning process is designed to minimize this rejection rate, maximize throughput and thus control energy and production costs. This program focuses on the design, development and testing of an advanced optically based pyrometer for glass melts. The pyrometer operates simultaneously at four wavelengths; through analytical treatment of the signals, internal temperature profiles within the glass melt can be resolved. A novel multiplexer alloys optical signals from a large number of fiber-optic sensors to be collected and resolved by a single detector at a location remote from the process. This results in a significant cost savings on a per measurement point basis. The development program is divided into two phases. Phase 1 involves the construction of a breadboard version on the instrument and its testing on a pilot-scale furnace. In Phase 2, a prototype analyzer will be constructed and tested on a commercial forehearth. This report covers the Phase 1 activities.

Gardner, M.; Candee, A.; Kramlich, J.; Koppang, R.

1991-05-01T23:59:59.000Z

492

Phosphate glasses for radioactive, hazardous and mixed waste immobilization  

DOE Patents (OSTI)

Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1