Sample records for glass products hydraulic

  1. Glass Production

    E-Print Network [OSTI]

    Shortland, Andrew

    2009-01-01T23:59:59.000Z

    Late Bronze Age glasses. Journal of Archaeological Science781 - 789. Turner, W.E.S. 1954 Studies in ancient glassesand glass making processes. Part I: Crucibles and melting

  2. Production Hydraulic Packer Field Test

    SciTech Connect (OSTI)

    Schneller, Tricia; Salas, Jose

    2000-06-30T23:59:59.000Z

    In October 1999, the Rocky Mountain Oilfield Testing Center and Halliburton Energy Services cooperated on a field test of Halliburton's new Production Hydraulic Packer technology on Well 46-TPX-10 at Naval Petroleum Reserve No. 3 near Casper, WY. Performance of the packer was evaluated in set and unset operations. The packer's ability to seal the annulus between the casing and tubing was hydraulically tested and the results were recorded.

  3. An investigation of productivity increases from hydraulic fracturing treatments

    E-Print Network [OSTI]

    Boriskie, Robert Joe

    1963-01-01T23:59:59.000Z

    AN INVESTIGATION OF PRODUCTIVITY INCREASES FROM HYDRAULIC FRACTURING TREATMENTS A Thesis b7 Robert Joe Boriskie Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... Head of Department) August, 1963 1. ABSTRACT 2. INTRODUCTION. TABLE OF CONTENTS PRgB 3. THEORY AND PROCEDURE. 4. DISCUSSION OF RESULTS. . 5. CONCLUSIONS. 6. ACKNOWLEDGEMENT. 7. APPENDIX. 8. REFERENCES. 18 19 20 32 LIST OF FIGURES...

  4. Low permeability gas reservoir production using large hydraulic fractures

    E-Print Network [OSTI]

    Holditch, Stephen A

    1970-01-01T23:59:59.000Z

    extending up to three thousand feet from the producing well. Also, a model simulating a nuclear cavity was designed. This model simulated a well containing an eighty foot radius cavity with a fractured zone of one hundred times the reservoir permeability... of each system was prepared. The results of this study showed that all fractures of greater than one thousand foot radius had greater productivity and greater cumu- lative gas produced than did the nuclear cavity. It appears that large hydraulic...

  5. Glass and Glass Products (2010 MECS) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdf Flash2006-52.pdf0.pdfDepartmentCounselGlass Coating Makes Solar Panels MoreGlass and

  6. Effects of alteration product precipitation on glass dissolution

    SciTech Connect (OSTI)

    Strachan, Denis M.; Neeway, James J.

    2014-04-02T23:59:59.000Z

    Silicate glasses dissolve in water at a rate dependent on the solution concentration of orthosilicic acid (H4SiO4). In general, higher [H4SiO4] leads to lower dissolution rates. It has often been observed that the precipitation of certain silica-bearing alteration products can cause the dissolution of the glass to increase, even after the rate has decreased significantly. However, it has also been observed that in the concentrations of these silica-bearing solution species do not significantly decrease while other elements continue to be released. In this study, we have used the Geochemist’s Workbench code to investigate the relationship between glass dissolution rates and the precipitation rate of a silica-bearing alteration product, analcime (Na(AlSi2O6)?H2O). In this initial study and to simplify the calculations, we suppressed all alteration products except analcime, gibbsite (Al(OH)3), and amorphous silica. The ‘cross affinity’ code option allowed us to account for the fact that glass is a thermodynamically unstable solid with respect to its alteration products in contact with water. The cross-affinity option in the Geochemist’s Workbench geochemical code allowed us to substitute the amorphous silica equilibrium-constant matrix for the glass equilibrium-constant matrix. In this article, we present the results of our calculations of the glass dissolution rate at different values for the analcime precipitation rate constant and the effects of varying the glass dissolution rate constant at a constant analcime precipitation rate constant. In all cases, our results indicate that the glass dissolution rate controls the rate of analcime precipitation in the long term. Our results, compared in general terms with experiments, show the importance of the gel layer that forms during glass alteration. The meaning of these results pertinent to long-term glass durability is discussed.

  7. GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE GLASS FOR PLUTONIUM DISPOSITION

    SciTech Connect (OSTI)

    Crawford, C; James Marra, J; Ned Bibler, N

    2007-02-12T23:59:59.000Z

    The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) in Aiken, SC, to disposition excess weapons-usable plutonium. A plutonium glass waste form is a leading candidate for immobilization of the plutonium for subsequent disposition in a geologic repository. The objectives of this present task were to fabricate plutonium-loaded lanthanide borosilicate (LaBS) Frit B glass and perform testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the proposed Federal Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit B composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support glass durability testing via the ASTM Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL). The glass was characterized with X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. This characterization revealed some crystalline PuO{sub 2} inclusions with disk-like morphology present in the as fabricated, quench-cooled glass. A series of PCTs was conducted at SRNL with varying exposed surface area and test durations. Filtered leachates from these tests were analyzed to determine the dissolved concentrations of key elements. The leachate solutions were also ultrafiltered to quantify colloid formation. Leached solids from select PCTs were examined in an attempt to evaluate the Pu and neutron absorber release behavior from the glass and to investigate formation of alteration phases on the glass surface. A series of PCTs was conducted at 90 C in ASTM Type 1 water to compare the Pu LaBS Frit B glass durability to current requirements for High Level Waste (HLW) glass in a geologic repository. The PCT (7-day static test with powdered glass) results on the Pu-containing LaBS Frit B glass at SA/V of {approx} 2000 m{sup -1} showed that the glass was very durable with an average normalized elemental release value for boron of 0.013 g/m{sup 2}. This boron release value is {approx} 640X lower than normalized boron release from current Environmental Assessment (EA) glass used for repository acceptance. The PCT-B (7, 14, 28 and 56-day, static test with powdered glass) normalized elemental releases were similar to the normalized elemental release values from PCT-A testing, indicating that the LaBS Frit B glass is very durable as measured by the PCT. Normalized plutonium releases were essentially the same within the analytical uncertainty of the ICP-MS methods used to quantify plutonium in the 0.45 {micro}m-filtered leachates and ultra-filtered leachates, indicating that colloidal plutonium species do not form under the PCT conditions used in this study.

  8. Specialty Cellular Glass Products and Their Applications 

    E-Print Network [OSTI]

    Rostoker, D.

    1979-01-01T23:59:59.000Z

    and boroaluminosilicate fields which exhibit a high degree of resistance to corrosion by aggressive chemicals as well. One product, sold as PENNGUARDTM block by Pennwalt Corporation, is used as a liner for chimneys where acid corrosion had previously caused substantial...

  9. Eco-efficient waste glass recycling: Integrated waste management and green product development through LCA

    SciTech Connect (OSTI)

    Blengini, Gian Andrea, E-mail: blengini@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); CNR-IGAG, Institute of Environmental Geology and Geo-Engineering, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Busto, Mirko, E-mail: mirko.busto@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fantoni, Moris, E-mail: moris.fantoni@polito.it [DITAG - Department of Land, Environment and Geo-Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fino, Debora, E-mail: debora.fino@polito.it [DISMIC - Department of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer A new eco-efficient recycling route for post-consumer waste glass was implemented. Black-Right-Pointing-Pointer Integrated waste management and industrial production are crucial to green products. Black-Right-Pointing-Pointer Most of the waste glass rejects are sent back to the glass industry. Black-Right-Pointing-Pointer Recovered co-products give more environmental gains than does avoided landfill. Black-Right-Pointing-Pointer Energy intensive recycling must be limited to waste that cannot be closed-loop recycled. - Abstract: As part of the EU Life + NOVEDI project, a new eco-efficient recycling route has been implemented to maximise resources and energy recovery from post-consumer waste glass, through integrated waste management and industrial production. Life cycle assessment (LCA) has been used to identify engineering solutions to sustainability during the development of green building products. The new process and the related LCA are framed within a meaningful case of industrial symbiosis, where multiple waste streams are utilised in a multi-output industrial process. The input is a mix of rejected waste glass from conventional container glass recycling and waste special glass such as monitor glass, bulbs and glass fibres. The green building product is a recycled foam glass (RFG) to be used in high efficiency thermally insulating and lightweight concrete. The environmental gains have been contrasted against induced impacts and improvements have been proposed. Recovered co-products, such as glass fragments/powders, plastics and metals, correspond to environmental gains that are higher than those related to landfill avoidance, whereas the latter is cancelled due to increased transportation distances. In accordance to an eco-efficiency principle, it has been highlighted that recourse to highly energy intensive recycling should be limited to waste that cannot be closed-loop recycled.

  10. Summary We investigated hydraulic conductance charac-teristics and associated dry matter production and distribution

    E-Print Network [OSTI]

    DeJong, Theodore

    Summary We investigated hydraulic conductance charac- teristics and associated dry matter') vigor rootstock. `K146-43' and `Hiawatha' rootstocks had 27 and 52% lower mean leaf-specific hydraulic and rootstock, which may be a compensatory response to the differences in leaf specific hydraulic conduc- tance

  11. Glass durability evaluation using product consistency, single-pass flow-through, and vapor hydration tests

    SciTech Connect (OSTI)

    Feng, X.; Hrma, P.; Kim, D. [Pacific Northwest National Lab., Richland, WA (United States)] [and others

    1996-12-31T23:59:59.000Z

    The current approach to assessing chemical durability of waste glasses focuses on a suite of short-term laboratory tests such as dynamic single-pass flow-through (SPFT) tests, static product consistency tests (PCT), and vapor hydration tests. The behavior of the glasses in the three types of tests is quite different, but each test provides insight into the glass corrosion process. The PCT data showed that at constant alumina, silica, and sodium levels the glass durability order for different glass systems is: Boron-series > Boron-Calcium-series > Calcium-series, while the opposite order is observed in SPFT tests. The order for vapor hydration tests is similar to that observed in the PCT tests. The PCT results are consistent with the current understanding of glass structure and are consistent with vapor hydration tests. The SPFT results can be explained using arguments based on solution chemistry.

  12. Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna; Sickafus, Kurt E.

    2010-09-23T23:59:59.000Z

    In this study, glass ceramics were explored as an alternative waste form for glass, the current baseline, to be used for immobilizing alkaline/alkaline earth + lanthanide (CS+LN) or CS+LN+transition metal (TM) fission-product waste streams generated by a uranium extraction (UREX+) aqueous separations type process. Results from past work on a glass waste form for the combined CS+LN waste streams showed that as waste loading increased, large fractions of crystalline phases precipitated upon slow cooling.[1] The crystalline phases had no noticeable impact on the waste form performance by the 7-day product consistency test (PCT). These results point towards the development of a glass ceramic waste form for treating CS+LN or CS+LN+TM combined waste streams. Three main benefits for exploring glass ceramics are: (1) Glass ceramics offer increased solubility of troublesome components in crystalline phases as compared to glass, leading to increased waste loading; (2) The crystalline network formed in the glass ceramic results in higher heat tolerance than glass; and (3) These glass ceramics are designed to be processed by the same melter technology as the current baseline glass waste form. It will only require adding controlled canister cooling for crystallization into a glass ceramic waste form. Highly annealed waste form (essentially crack free) with up to 50X lower surface area than a typical High-Level Waste (HLW) glass canister. Lower surface area translates directly into increased durability. This was the first full year of exploring glass ceramics for the Option 1 and 2 combined waste stream options. This work has shown that dramatic increases in waste loading are achievable by designing a glass ceramic waste form as an alternative to glass. Table S1 shows the upper limits for heat, waste loading (based on solubility), and the decay time needed before treatment can occur for glass and glass ceramic waste forms. The improvements are significant for both combined waste stream options in terms of waste loading and/or decay time required before treatment. For Option 1, glass ceramics show an increase in waste loading of 15 mass % and reduction in decay time of 24 years. Decay times of {approx}50 years or longer are close to the expected age of the fuel that will be reprocessed when the modified open or closed fuel cycle is expected to be put into action. Option 2 shows a 2x to 2.5x increase in waste loading with decay times of only 45 years. Note that for Option 2 glass, the required decay time before treatment is only 35 years because of the waste loading limits related to the solubility of MoO{sub 3} in glass. If glass was evaluated for similar waste loadings as those achieved in Option 2 glass ceramics, the decay time would be significantly longer than 45 years. These glass ceramics are not optimized, but already they show the potential to dramatically reduce the amount of waste generated while still utilizing the proven processing technology used for glass production.

  13. Performance of the Fluidized Bed Steam Reforming Product Under Hydraulically Unsaturated Conditions

    SciTech Connect (OSTI)

    Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Rod, Kenton A.; Bowden, Mark E.; Brown, Christopher F.; Pierce, Eric M.

    2014-05-01T23:59:59.000Z

    Currently, several candidates for secondary waste immobilization at the Hanford site in the State of Washington, USA are being considered. To demonstrate the durability of the product in the unsaturated Integrated Disposal Facility (IDF) at the site, a series of tests have been performed one of the candidate materials using the Pressurized Unsaturated Flow (PUF) system. The material that was tested was the Fluidized Bed Steam Reformer (FBSR) granular product and the granular product encapsulated in a geopolymer matrix. The FBSR product is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals mostly nepheline, sodalite, and nosean. The PUF test method allows for the accelerated weathering of materials, including radioactive waste forms, under hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that most likely will be present at the IDF. The experiments show a trend of decreasing tracer release as a function of time for several of the elements released from the material including Na, Si, Al, and Cs. However, some of the elements, notably I and Re, show a steady release throughout the yearlong test. This result suggests that the release of these minerals from the sodalite cage occurs at a different rate compared with the dissolution of the predominant nepheline phase.

  14. Towards Prestressed Thin-Sheet Glass Concrete Products Gregor Vilkner and Christian Meyer

    E-Print Network [OSTI]

    Meyer, Christian

    Towards Prestressed Thin-Sheet Glass Concrete Products Gregor Vilkner and Christian Meyer SYNOPSIS, and concrete technology. Christian Meyer, FACI, is a Professor of Civil Engineering at Columbia University

  15. Effects of temperature and radiation on the nuclear waste glass product consistency leach test

    SciTech Connect (OSTI)

    Crawford, C.L.; Bibler, N.E.

    1993-01-01T23:59:59.000Z

    Previous leach studies carried out with monolithic glass samples have shown that glass dissolution rates increase with increasing temperature and may or may not increase on exposure to external gamma radiolysis. In this study we have investigated the effects of temperature (70--1200[degrees]C) and radiation on the dissolution of simulated radioactive waste glasses using the Product Consistency Test (PCT). The PCT is a seven day, crushed glass leach test in deionized water that is carried out at 9OO[degrees]C. To date our results indicate no significant effect of external Co--60 gamma radiation when testing various simulated waste glasses at 90[degrees]C in a wellinsulated compartment within a Gammacell 220 irradiation unit. The temperature dependence for glass dissolution clearly exhibits Arrheniustype behavior for two of the three glasses tested. For the third glass the dissolution decreases at the higher temperatures, probably due to saturation effects. Actual radioactive waste glasses will be investigated later as part of this study.

  16. Effects of temperature and radiation on the nuclear waste glass product consistency leach test

    SciTech Connect (OSTI)

    Crawford, C.L.; Bibler, N.E.

    1993-04-01T23:59:59.000Z

    Previous leach studies carried out with monolithic glass samples have shown that glass dissolution rates increase with increasing temperature and may or may not increase on exposure to external gamma radiolysis. In this study we have investigated the effects of temperature (70--1200{degrees}C) and radiation on the dissolution of simulated radioactive waste glasses using the Product Consistency Test (PCT). The PCT is a seven day, crushed glass leach test in deionized water that is carried out at 9OO{degrees}C. To date our results indicate no significant effect of external Co--60 gamma radiation when testing various simulated waste glasses at 90{degrees}C in a wellinsulated compartment within a Gammacell 220 irradiation unit. The temperature dependence for glass dissolution clearly exhibits Arrheniustype behavior for two of the three glasses tested. For the third glass the dissolution decreases at the higher temperatures, probably due to saturation effects. Actual radioactive waste glasses will be investigated later as part of this study.

  17. GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE FRIT B COMPOSITION FOR PLUTONIUM DISPOSITION

    SciTech Connect (OSTI)

    Marra, J

    2006-01-19T23:59:59.000Z

    The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) to disposition excess weapons-usable plutonium. A plutonium glass waste form is a leading candidate for immobilization of the plutonium for subsequent disposition in a geologic repository. A reference glass composition (Lanthanide Borosilicate (LaBS) Frit B) was developed during the Plutonium Immobilization Program (PIP) to immobilize plutonium. A limited amount of performance testing was performed on this baseline composition before efforts to further pursue Pu disposition via a glass waste form ceased. Therefore, the objectives of this present task were to fabricate plutonium loaded LaBS Frit B glass and perform additional testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the Yucca Mountain Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit B composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL) and for additional performance testing at Argonne National Laboratory (ANL) and Pacific Northwest National Laboratory (PNNL). The glass was characterized using x-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. A series of PCTs were conducted at SRNL with varying exposed surface area and test durations. The leachates from these tests were analyzed to determine the dissolved concentrations of key elements. Acid stripping of leach vessels was performed to determine the concentration of the glass constituents that may have sorbed on the vessels during leach testing. Additionally, the leachate solutions were ultrafiltered to quantify colloid formation. The leached solids from select PCTs were examined in an attempt to evaluate the Pu and neutron absorber release behavior from the glass and to identify the formation of alteration phases on the glass surface. Characterization of the glass prior to testing revealed that some undissolved plutonium oxide was present in the glass. The undissolved particles had a disk-like morphology and likely formed via coarsening of particles in areas compositionally enriched in plutonium. Similar disk-like PuO{sub 2} phases were observed in previous LaBS glass testing at PNNL. In that work, researchers concluded that plutonium formed with this morphology as a result of the leaching process. It was more likely that the presence of the plutonium oxide crystals in the PNNL testing was a result of glass fabrication. A series of PCTs were conducted at 90 C in ASTM Type 1 water. The PCT-Method A (PCT-A) was conducted to compare the Pu LaBS Frit B glass durability to current requirements for High Level Waste (HLW) glass in a geologic repository. The PCT-A test has a strict protocol and is designed to specifically be used to evaluate whether the chemical durability and elemental release characteristics of a nuclear waste glass have been consistently controlled during production and, thus, meet the repository acceptance requirements. The PCT-A results on the Pu containing LaBS Frit B glass showed that the glass was very durable with a normalized elemental release value for boron of approximately 0.02 g/L. This boron release value was better than two orders of magnitude better from a boron release standpoint than the current Environmental Assessment (EA) glass used for repository acceptance. The boron release value for EA glass is 16.7 g/L.

  18. Strategies for planning and long-term scheduling for PPG glass production

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Linear Programming (MILP) model for the planning and scheduling of PPG tinted glasses production x,t - P iIM P tT SC PEN3i,t · BCKLi,t Subject to: x Assignment and production constraints x Minimum run

  19. Focused Ion Beam Production Using a Pyroelectric Crystal and a Resistive Glass Tube

    E-Print Network [OSTI]

    Danon, Yaron

    Focused Ion Beam Production Using a Pyroelectric Crystal and a Resistive Glass Tube T. Z. Fullem, A to accelerate electrons into a metal target has led to the production of compact X-Ray generators [4], [5], [6 tungsten tip (marketed for use in a scanning electron microscope) with an apex radius of 70 nm was mounted

  20. Product consistency leach tests of Savannah River Site radioactive waste glasses

    SciTech Connect (OSTI)

    Bibler, N.E. (Westinghouse Savannah River Co., Aiken, SC (United States)); Bates, J.K. (Argonne National Lab., IL (United States))

    1989-01-01T23:59:59.000Z

    The Product Consistency Test (PCT) is a glass leach test that was developed at the Savannah River Site (SRS) to routinely confirm the durability of nuclear waste glasses that will be produced in the Defense Waste Processing Facility. The PCT is a 7 day, crushed glass leach test in deionized water at 90{degree}C. Final leachates are filtered and acidified prior to analysis. To demonstrate the reproducibility of the PCT when performed remotely, SRS and Argonne National Laboratory have performed the PCT on samples of two radioactive glasses. The tests were also performed to compare the releases of the radionuclides with the major nonradioactive glass components and to determine if radiation from the glass was affecting the results of the PCT. The test was performed in triplicate at each laboratory. For the major soluble elements, B, Li, Na, and Si, in the glass, each investigator obtained relative precisions in the range 2--5% in the triplicate tests. This range indicates good precision for the PCT when performed remotely with master slave manipulators in a shielded cell environment.

  1. Performance of the Fluidized Bed Steam Reforming product under hydraulically unsaturated conditions

    SciTech Connect (OSTI)

    Neeway, James J [ORNL] [ORNL; Rod, Kenton A. [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Bowden, Mark E [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Pierce, Eric M [ORNL] [ORNL; Qafoku, Nikolla [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Williams, Benjamin D [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL); Brown, Christopher F [Pacific Northwest National Laboratory (PNNL)] [Pacific Northwest National Laboratory (PNNL)

    2014-01-01T23:59:59.000Z

    Several candidates for supplemental low-activity waste (LAW) immobilization at the Hanford site in Washington State, USA are being considered. One waste sequestering technology considered is Fluidized Bed Steam Reforming (FBSR). The granular product resulting from the FBSR process is composed primarily of an insoluble sodium aluminosilicate matrix with the dominant phases being feldspathoid minerals with a 1:1:1 molar ratio of Na, Al and Si. To demonstrate the durability of the product, which can be disposed of at the unsaturated Integrated Disposal Facility (IDF) at Hanford, a series of tests has been performed using the Pressurized Unsaturated Flow (PUF) system, which allows for the accelerated weathering of the solid materials. The system maintains hydraulically unsaturated conditions, thus mimicking the open-flow and transport properties that will be present at the IDF. Two materials were tested using the system: 1) the FBSR granular product and 2) the FBSR granular product encapsulated in a geopolymer to form a monolith. Results of the experiments show a trend of relatively constant effluent concentration of Na, Si, Al, and Cs as a function of time from both materials. The elements I and Re show a steady release throughout the yearlong test from the granular material but their concentrations seem to be increasing at one year from the monolith material. This result suggests that these two elements may be present in the sodalite cage structure rather than in the predominant nepheline phase because their release occurs at a different rate compared to nepheline phase. Also, these elements to not seem to reprecipitate when released from the starting material. Calculated one-year release rates for Si are on the order of 10 6 g/(m2 d) for the granular material and 10 5 g/(m2 d) for the monolith material while Re release is seen to be two orders of magnitude higher than Si release rates. SEM imaging and XRD analysis show how the alteration of the two materials is dependent on their depth in the column. This phenomenom is a result of depth-dependent solution concentrations giving rise chemical environments that may be supersaturated with respect to a number of mineral phases.

  2. GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSILICATE FRIT X COMPOSITION FOR PLUTONIUM DISPOSITION

    SciTech Connect (OSTI)

    Marra, J

    2006-11-15T23:59:59.000Z

    The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) to disposition excess weapons-usable plutonium. A plutonium glass waste form is the preferred option for immobilization of the plutonium for subsequent disposition in a geologic repository. A reference glass composition (Lanthanide Borosilicate (LaBS) Frit B) was developed during the Plutonium Immobilization Program (PIP) to immobilize plutonium in the late 1990's. A limited amount of performance testing was performed on this baseline composition before efforts to further pursue Pu disposition via a glass waste form ceased. Recent FY05 studies have further investigated the LaBS Frit B formulation as well as development of a newer LaBS formulation denoted as LaBS Frit X. The objectives of this present task were to fabricate plutonium loaded LaBS Frit X glass and perform corrosion testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the Yucca Mountain Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit X composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL). The glass was thoroughly characterized using x-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. A series of PCTs were conducted at SRNL using quenched Pu Frit X glass with varying exposed surface areas. Effects of isothermal and can-in-canister heat treatments on the Pu Frit X glass were also investigated. Another series of PCTs were performed on these different heat-treated Pu Frit X glasses. Leachates from all these PCTs were analyzed to determine the dissolved concentrations of key elements. Acid stripping of leach vessels was performed to determine the concentration of the glass constituents that may have sorbed on the vessels during leach testing. Additionally, the leachate solutions were ultrafiltered to quantify colloid formation.

  3. GLASS FABRICATION AND PRODUCT CONSISTENCY TESTING OF LANTHANIDE BOROSHILICATE FRIT X COMPOSITION FOR PLUTONIUM DISPOSITION

    SciTech Connect (OSTI)

    Marra, J

    2006-11-21T23:59:59.000Z

    The Department of Energy Office of Environmental Management (DOE/EM) plans to conduct the Plutonium Disposition Project at the Savannah River Site (SRS) to disposition excess weapons-usable plutonium. A plutonium glass waste form is the preferred option for immobilization of the plutonium for subsequent disposition in a geologic repository. A reference glass composition (Lanthanide Borosilicate (LaBS) Frit B) was developed during the Plutonium Immobilization Program (PIP) to immobilize plutonium in the late 1990's. A limited amount of performance testing was performed on this baseline composition before efforts to further pursue Pu disposition via a glass waste form ceased. Recent FY05 studies have further investigated the LaBS Frit B formulation as well as development of a newer LaBS formulation denoted as LaBS Frit X. The objectives of this present task were to fabricate plutonium loaded LaBS Frit X glass and perform corrosion testing to provide near-term data that will increase confidence that LaBS glass product is suitable for disposal in the Yucca Mountain Repository. Specifically, testing was conducted in an effort to provide data to Yucca Mountain Project (YMP) personnel for use in performance assessment calculations. Plutonium containing LaBS glass with the Frit X composition with a 9.5 wt% PuO{sub 2} loading was prepared for testing. Glass was prepared to support Product Consistency Testing (PCT) at Savannah River National Laboratory (SRNL). The glass was thoroughly characterized using x-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS) prior to performance testing. A series of PCTs were conducted at SRNL using quenched Pu Frit X glass with varying exposed surface areas. Effects of isothermal and can-in-canister heat treatments on the Pu Frit X glass were also investigated. Another series of PCTs were performed on these different heat-treated Pu Frit X glasses. Leachates from all these PCTs were analyzed to determine the dissolved concentrations of key elements. Acid stripping of leach vessels was performed to determine the concentration of the glass constituents that may have sorbed on the vessels during leach testing. Additionally, the leachate solutions were ultrafiltered to quantify colloid formation. Characterization of the quenched Pu Frit X glass prior to testing revealed that some crystalline plutonium oxide was present in the glass. The crystalline particles had a disklike morphology and likely formed via coarsening of particles in areas compositionally enriched in plutonium. Similar results had also been observed in previous Pu Frit B studies. Isothermal 1250 C heat-treated Pu Frit X glasses showed two different crystalline phases (PuO{sub 2} and Nd{sub 2}Hf{sub 2}O{sub 7}), as well as a peak shift in the XRD spectra that is likely due to a solid solution phase PuO{sub 2}-HfO{sub 2} formation. Micrographs of this glass showed a clustering of some of the crystalline phases. Pu Frit X glass subjected to the can-in-canister heating profile also displayed the two PuO{sub 2} and Nd{sub 2}Hf{sub 2}O{sub 7} phases from XRD analysis. Additional micrographs indicate crystalline phases in this glass were of varying forms (a spherical PuO{sub 2} phase that appeared to range in size from submicron to {approx}5 micron, a dendritic-type phase that was comprised of mixed lanthanides and plutonium, and a minor phase that contained Pu and Hf), and clustering of the phases was also observed.

  4. Summary Report: Glass-Ceramic Waste Forms for Combined Fission Products

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Riley, Brian J.; Turo, Laura A.; Tang, Ming; Kossoy, Anna

    2011-09-23T23:59:59.000Z

    Glass-ceramic waste form development began in FY 2010 examining two combined waste stream options: (1) alkaline earth (CS) + lanthanide (Ln), and (2) + transition metal (TM) fission-product waste streams generated by the uranium extraction (UREX+) separations process. Glass-ceramics were successfully developed for both options however; Option 2 was selected over Option 1, at the conclusion of 2010, because Option 2 immobilized all three waste streams with only a minimal decrease in waste loading. During the first year, a series of three glass (Option 2) were fabricated that varied waste loading-WL (42, 45, and 50 mass%) at fixed molar ratios of CaO/MoO{sub 3} and B{sub 2}O{sub 3}/alkali both at 1.75. These glass-ceramics were slow cooled and characterized in terms of phase assemblage and preliminary irradiation stability. This fiscal year, further characterization was performed on the FY 2010 Option 2 glass-ceramics in terms of: static leach testing, phase analysis by transmission electron microscopy (TEM), and irradiation stability (electron and ion). Also, a new series of glass-ceramics were developed for Option 2 that varied the additives: Al{sub 2}O{sub 3} (0-6 mass%), molar ratio of CaO/MoO{sub 3} and B{sub 2}O{sub 3}/alkali (1.75 to 2.25) and waste loading (50, 55, and 60 mass%). Lastly, phase pure powellite and oxyapatite were synthesized for irradiation studies. Results of this fiscal year studies showed compositional flexibility, chemical stability, and radiation stability in the current glass-ceramic system. First, the phase assemblages and microstructure of all of the FY 2010 and 2011 glass-ceramics are very similar once subjected to the slow cool heat treatment. The phases identified in these glass-ceramics were oxyapatite, powellite, cerianite, and ln-borosilicate. This shows that variations in waste loading or additives can be accommodated without drastically changing the phase assemblage of the waste form, thus making the processing and performance characteristics of the waste form more predictable/flexible. However, in the future, the glass phase still needs to be accurately characterized to determine the effects of waste loading and additives on the glass structure. Initial investigations show a borosilicate glass phase rich in silica. Second, the normalized concentrations of elements leached from the waste form during static leach testing were all below 0.6 g/L after 28d at 90 C, by the Product Consistency Test (PCT), method B. These normalized concentrations are on par with durable waste glasses such as the Low-Activity Reference Material (LRM) glass. The release rates for the crystalline phases (oxyapatite and powellite) appear to be lower (more durable) than the glass phase based on the relatively low release rates of Mo, Ca, and Ln found in the crystalline phases compared to Na and B that are mainly observed in the glass phase. However, further static leach testing on individual crystalline phases is needed to confirm this statement. Third, Ion irradiation and In situ TEM observations suggest that these crystalline phases (such as oxyapatite, ln-borosilicate, and powellite) in silicate based glass ceramic waste forms exhibit stability to 1000 years at anticipated doses (2 x 10{sup 10}-2 x 10{sup 11} Gy). This is adequate for the short lived isotopes in the waste, which lead to a maximum cumulative dose of {approx}7 x 10{sup 9} Gy, reached after {approx}100 yrs, beyond which the dose contributions are negligible. The cumulate dose calculations are based on a glass-ceramic at WL = 50 mass%, where the fuel has a burn-up of 51GWd/MTIHM, immobilized after 5 yr decay from reactor discharge.

  5. Energy Saving Method of Manufacturing Ceramic Products from Fiber Glass Waste

    SciTech Connect (OSTI)

    Michael J. Haun

    2005-07-15T23:59:59.000Z

    The U.S. fiber glass industry disposes of more than 260,000 tons of industrial fiber glass waste in landfills annually. New technology is needed to reprocess this industrial waste into useful products. A low-cost energy-saving method of manufacturing ceramic tile from fiber glass waste was developed. The technology is based on sintering fiber glass waste at 700-900 degrees C to produce products which traditionally require firing temperatures of >1200 degrees C, or glass-melting temperatures >1500 degrees C. The process also eliminates other energy intensive processing steps, including mining and transportation of raw materials, spray-drying to produce granulated powder, drying pressed tile, and glazing. The technology completely transforms fiber glass waste into a dense ceramic product, so that all future environmental problems in the handling and disposal of the fibers is eliminated. The processing steps were developed and optimized to produce glossy and matte surface finishes for wall and floor tile applications. High-quality prototype tile samples were processed for demonstration and tile standards testing. A Market Assessment confirmed the market potential for tile products produced by the technology. Manufacturing equipment trials were successfully conducted for each step of the process. An industrial demonstration plant was designed, including equipment and operating cost analysis. A fiber glass manufacturer was selected as an industrial partner to commercialize the technology. A technology development and licensing agreement was completed with the industrial partner. Haun labs will continue working to transfer the technology and assist the industrial partner with commercialization beyond the DOE project.

  6. Standard test methods for determining chemical durability of nuclear, hazardous, and mixed waste glasses and multiphase glass ceramics: The product consistency test (PCT)

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2002-01-01T23:59:59.000Z

    1.1 These product consistency test methods A and B evaluate the chemical durability of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, and/or multiphase glass ceramic waste forms hereafter collectively referred to as “glass waste forms” by measuring the concentrations of the chemical species released to a test solution. 1.1.1 Test Method A is a seven-day chemical durability test performed at 90 ± 2°C in a leachant of ASTM-Type I water. The test method is static and conducted in stainless steel vessels. Test Method A can specifically be used to evaluate whether the chemical durability and elemental release characteristics of nuclear, hazardous, and mixed glass waste forms have been consistently controlled during production. This test method is applicable to radioactive and simulated glass waste forms as defined above. 1.1.2 Test Method B is a durability test that allows testing at various test durations, test temperatures, mesh size, mass of sample, leachant volume, a...

  7. A new Energy Saving method of manufacturing ceramic products from waste glass

    SciTech Connect (OSTI)

    Haun Labs

    2002-07-05T23:59:59.000Z

    This final report summarizes the activities of the DOE Inventions and Innovations sponsored project, ''A New Energy Saving Method of Manufacturing Ceramic Products from Waste Glass.'' The project involved an innovative method of lowering energy costs of manufacturing ceramic products by substituting traditional raw materials with waste glass. The processing method is based on sintering of glass powder at {approx}750 C to produce products which traditionally require firing temperatures of >1200 C, or glass-melting temperatures >1500 C. The key to the new method is the elimination of previous processing problems, which have greatly limited the use of recycled glass as a ceramic raw material. The technology is aligned with the DOE-OIT Glass Industry Vision and Roadmap, and offers significant energy savings and environmental benefits compared to current technologies. A U.S. patent (No. 6,340,650) covering the technology was issued on January 22, 2002. An international PCT Patent Application is pending with designations made for all PCT regions and countries. The goal of the project was to provide the basis for the design and construction of an energy-efficient manufacturing plant that can convert large volumes of waste glass into high-quality ceramic tile. The main objectives of the project were to complete process development and optimization; construct and test prototype samples; and conduct market analysis and commercialization planning. Two types of ceramic tile products were targeted by the project. The first type was developed during the first year (Phase I) to have a glazed-like finish for applications where slip resistance is not critical, such as wall tile. The processing method optimized in Phase I produces a glossy surface with a translucent appearance, without the extra glazing steps required in traditional tile manufacturing. The second type of product was developed during the second year (Phase II). This product was designed to have an unglazed appearance for applications requiring slip resistance, such as floor tile. The coarser matte finish of this product type was produced by modifying the basic process to include crystalline fillers and partial crystallization of the glass. Additional details of the project results are discussed in Section III.

  8. The production of advanced glass ceramic HLW forms using cold crucible induction melter

    SciTech Connect (OSTI)

    Rutledge, V.J.; Maio, V. [Idaho National Laboratory: P.O. Box 1625, Idaho Falls, ID, 83415-2110 (United States)

    2013-07-01T23:59:59.000Z

    Cold Crucible Induction Melters (CCIM) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in a near future. Unlike the existing Joule-Heated Melters (JHM) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIM offers unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. It is concluded that glass ceramic waste forms that are tailored to immobilize fission products of HLW can be can be made from the HLW processed with the CCIM. The advantageous higher temperatures reached with the CCIM and unachievable with JHM allows the lanthanides, alkali, alkaline earths, and molybdenum to dissolve into a molten glass. Upon controlled cooling they go into targeted crystalline phases to form a glass ceramic waste form with higher waste loadings than achievable with borosilicate glass waste forms. Natural cooling proves to be too fast for the formation of all targeted crystalline phases.

  9. Entanglement entropy and entropy production in the Color Glass Condensate framework

    E-Print Network [OSTI]

    Alex Kovner; Michael Lublinsky

    2015-06-17T23:59:59.000Z

    We compute the entanglement entropy of soft gluons in the wave function of a fast moving hadron and discuss its basic properties. We also derive the expression for entropy production in a high energy hadronic collision within the Color Glass formalism. We show that long range rapidity correlations give negative contribution to the production entropy. We calculate the (naturally defined) temperature of the produced system of particles, and show that it is proportional to the average transverse momentum of the produced particles.

  10. Entanglement entropy and entropy production in the Color Glass Condensate framework

    E-Print Network [OSTI]

    Kovner, Alex

    2015-01-01T23:59:59.000Z

    We compute the entanglement entropy of soft gluons in the wave function of a fast moving hadron and discuss its basic properties. We also derive the expression for entropy production in a high energy hadronic collision within the Color Glass formalism. We show that long range rapidity correlations give negative contribution to the production entropy. We calculate the (naturally defined) temperature of the produced system of particles, and show that it is proportional to the average transverse momentum of the produced particles.

  11. Feasibility study Part I - Thermal hydraulic analysis of LEU target for {sup 99}Mo production in Tajoura reactor

    SciTech Connect (OSTI)

    Bsebsu, F.M.; Abotweirat, F. [Reactor Department, Renewable Energies and Water Desalination Research Cente, P.O. Box 30878 Tajoura, Tripoli (Libyan Arab Jamahiriya)], E-mail: Bsebso@yahoo.com, E-mail: abutweirat@yahoo.com; Elwaer, S. [Radiochemistry Department, Renewable Energies and Water Desalination Research Cente, P.O. Box 30878 Tajoura, Tripoli (Libyan Arab Jamahiriya)], E-mail: samiwer@yahoo.com

    2008-07-15T23:59:59.000Z

    The Renewable Energies and Water Desalination Research Center (REWDRC), Libya, will implement the technology for {sup 99}Mo isotope production using LEU foil target, to obtain new revenue streams for the Tajoura nuclear research reactor and desiring to serve the Libyan hospitals by providing the medical radioisotopes. Design information is presented for LEU target with irradiation device and irradiation Beryllium (Be) unit in the Tajoura reactor core. Calculated results for the reactor core with LEU target at different level of power are presented for steady state and several reactivity induced accident situations. This paper will present the steady state thermal hydraulic design and transient analysis of Tajoura reactor was loaded with LEU foil target for {sup 99}Mo production. The results of these calculations show that the reactor with LEU target during the several cases of transient are in safe and no problems will occur. (author)

  12. Radiation effects in moist-air systems and the influence of radiolytic product formation on nuclear waste glass corrosion

    SciTech Connect (OSTI)

    Wronkiewicz, D.J.; Bates, J.K.; Buck, E.C.; Hoh, J.C.; Emery, J.W. [Argonne National Lab., IL (United States). Chemical Technology Div.; Wang, L.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Geology

    1997-07-01T23:59:59.000Z

    Ionizing radiation may affect the performance of glass in an unsaturated repository site by interacting with air, water vapor, or liquid water to produce a variety of radiolytic products. Tests were conducted to examine the effects of radiolysis under high gas/liquid ratios. Results indicate that nitrate is the predominant radiolytic product produced following both gamma and alpha radiation exposure, with lesser amounts of nitrite and carboxylic acids. The formation of nitrogen acids during exposure to long-lived, alpha-particle-emitting transuranic elements indicates that these acids may play a role in influencing nuclear waste form reactions in a long-term unsaturated disposal scenario. Experiments were also conducted with samples that simulate the composition of Savannah River Plant nuclear waste glasses. Radiolytic product formation in batch tests (340 m{sup {minus}1}, 90 C) resulted in a small increase in the release rates of many glass components, such as alkali and alkaline earth elements, although silicon and uranium release rates were slightly reduced indicating an overall beneficial effect of radiation on waste form stability. The radiolytic acids increased the rate of ion exchange between the glass and the thin film of condensate, resulting in accelerated corrosion rates for the glass. The paragenetic sequence of alteration phases formed on both the irradiated and nonirradiated glass samples reacted in the vapor hydration tests matches closely with those developed during volcanic glass alteration in naturally occurring saline-alkaline lake systems. This correspondence suggests that the high temperatures used in these tests have not changed the underlying glass reaction mechanism relate to that which controls glass reactions under ambient surficial conditions.

  13. Suspensions in hydraulic fracturing

    SciTech Connect (OSTI)

    Shah, S.N. [Univ. of Oklahoma, Norman, OK (United States)

    1996-12-31T23:59:59.000Z

    Suspensions or slurries are widely used in well stimulation and hydraulic fracturing processes to enhance the production of oil and gas from the underground hydrocarbon-bearing formation. The success of these processes depends significantly upon having a thorough understanding of the behavior of suspensions used. Therefore, the characterization of suspensions under realistic conditions, for their rheological and hydraulic properties, is very important. This chapter deals with the state-of-the-art hydraulic fracturing suspension technology. Specifically it deals with various types of suspensions used in well stimulation and fracturing processes, their rheological characterization and hydraulic properties, behavior of suspensions in horizontal wells, review of proppant settling velocity and proppant transport in the fracture, and presently available measurement techniques for suspensions and their merits. Future industry needs for better understanding of the complex behavior of suspensions are also addressed. 74 refs., 21 figs., 1 tab.

  14. Evidence of Reopened Microfractures in Production Data of Hydraulically Fractured Shale Gas Wells

    E-Print Network [OSTI]

    Apiwathanasorn, Sippakorn

    2012-10-19T23:59:59.000Z

    Frequently a discrepancy is found between the stimulated shale volume (SSV) estimated from production data and the SSV expected from injected water and proppant volume. One possible explanation is the presence of a fracture network, often termed...

  15. Hydraulic Fracturing (Vermont)

    Broader source: Energy.gov [DOE]

    Vermont prohibits hydraulic fracturing or the collection, storage, or treatment of wastewater from hydraulic fracturing

  16. The Color Glass Condensate and hadron production in the forward region

    E-Print Network [OSTI]

    Adrian Dumitru; Arata Hayashigaki; Jamal Jalilian-Marian

    2005-09-06T23:59:59.000Z

    We consider one loop corrections to single inclusive particle production in parton-nucleus scattering at high energies, treating the target nucleus as a Color Glass Condensate. We prove by explicit computation that in the leading log Q^2 approximation, these corrections lead to collinear factorization and DGLAP evolution of the projectile parton distribution and hadron fragmentation functions. At leading logarithmic level, and in single-inclusive cross sections, only two-point functions of Wilson lines in the adjoint and fundamental representations (Mueller's dipoles) arise, which can be obtained from the solution of the JIMWLK equations. The application of our results to forward-rapidity production at RHIC energy shows that, in general, recoil effects are large and that the forward rapidity region at RHIC is rather different from the central region at LHC, despite comparable gluon densities in the target. We show that both the quantum x-evolution of the high-density target as well as the DGLAP Q^2-evolution of the parton distribution and fragmentation functions are clearly seen in the BRAHMS data. This provides additional strong evidence for the Color Glass Condensate at RHIC.

  17. CRYSTALLIZATION IN MULTICOMPONENT GLASSES

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR

    2009-10-08T23:59:59.000Z

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

  18. Microseismic Tracer Particles for Hydraulic Fracturing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The trend toward production of hydrocarbons from unconventional reservoirs (tight gas, shale oilgas) has caused a large increase in the use of hydraulic fracture stimulation of...

  19. THERMAL HYDRAULICS KEYWORDS: thermal hydraulics,

    E-Print Network [OSTI]

    Smith, Barton L.

    -fluid modeling of nuclear reactor systems. Thermal-hydraulic analysis codes such as RELAP5-3D ~Ref. 1! and FLICA regions of the system. In fact, the CFD code FLUENT has previously been coupled to RELAP5-3D ~Refs. 3

  20. Multi-phase glass-ceramics as a waste form for combined fission products: alkalis, alkaline earths, lanthanides, and transition metals

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna

    2012-04-01T23:59:59.000Z

    In this study, multi-phase silicate-based glass-ceramics were investigated as an alternate waste form for immobilizing non-fissionable products from used nuclear fuel. Currently, borosilicate glass is the waste form selected for immobilization of this waste stream, however, the low thermal stability and solubility of MoO{sub 3} in borosilicate glass translates into a maximum waste loading in the range of 15-20 mass%. Glass-ceramics provide the opportunity to target durable crystalline phases, e.g., powellite, oxyapatite, celsian, and pollucite, that will incorporate MoO{sub 3} as well as other waste components such as lanthanides, alkalis, and alkaline earths at levels 2X the solubility limits of a single-phase glass. In addition a glass-ceramic could provide higher thermal stability, depending upon the properties of the crystalline and amorphous phases. Glass-ceramics were successfully synthesized at waste loadings of 42, 45, and 50 mass% with the following glass additives: B{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, CaO and SiO{sub 2} by slow cooling form from a glass melt. Glass-ceramics were characterized in terms of phase assemblage, morphology, and thermal stability. The targeted phases: powellite and oxyapatite were observed in all of the compositions along with a lanthanide borosilicate, and cerianite. Results of this initial investigation of glass-ceramics show promise as a potential waste form to replace single-phase borosilicate glass.

  1. Hydraulic fracturing-1

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    This book contains papers on hydraulic fracturing. Topics covered include: An overview of recent advances in hydraulic fracturing technology; Containment of massive hydraulic fracture; and Fracturing with a high-strength proppant.

  2. Determining the dissolution rates of actinide glasses: A time and temperature Product Consistency Test study

    SciTech Connect (OSTI)

    Daniel, W.E.; Best, D.R.

    1995-12-01T23:59:59.000Z

    Vitrification has been identified as one potential option for the e materials such as Americium (Am), Curium (Cm), Neptunium (Np), and Plutonium (Pu). A process is being developed at the Savannah River Site to safely vitrify all of the highly radioactive Am/Cm material and a portion of the fissile (Pu) actinide materials stored on site. Vitrification of the Am/Cm will allow the material to be transported and easily stored at the Oak Ridge National Laboratory. The Am/Cm glass has been specifically designed to be (1) highly durable in aqueous environments and (2) selectively attacked by nitric acid to allow recovery of the valuable Am and Cm isotopes. A similar glass composition will allow for safe storage of surplus plutonium. This paper will address the composition, relative durability, and dissolution rate characteristics of the actinide glass, Loeffler Target, that will be used in the Americium/Curium Vitrification Project at Westinghouse Savannah River Company near Aiken, South Carolina. The first part discusses the tests performed on the Loeffler Target Glass concerning instantaneous dissolution rates. The second part presents information concerning pseudo-activation energy for the one week glass dissolution process.

  3. The Production of Advanced Glass Ceramic HLW Forms using Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    Veronica J Rutledge; Vince Maio

    2013-10-01T23:59:59.000Z

    Cold Crucible Induction Melters (CCIMs) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in the 21st century. Unlike the existing Joule-Heated Melters (JHMs) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIMs offer unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. This paper discusses advantageous features of the CCIM, with emphasis on features that overcome the historical issues with the JHMs presently utilized, as well as the benefits of glass ceramic waste forms over borosilicate glass waste forms. These advantages are then validated based on recent INL testing to demonstrate a first-of-a-kind formulation of a non-radioactive ceramic-based waste form utilizing a CCIM.

  4. West Valley glass product qualification durability studies, FY 1987--1988: Effects of composition, redox state, thermal history, and groundwater

    SciTech Connect (OSTI)

    Reimus, M.A.H.; Piepel, G.F.; Mellinger, G.B.; Bunnell, L.R.

    1988-11-01T23:59:59.000Z

    The product qualification subtask of the West Valley Support Task (WVST) at Pacific Northwest Laboratory (PNL) provides support for the waste form qualification efforts at West Valley Nuclear Services Co. Testing is being conducted to determine waste form chemical durability in support of these efforts. The effects of composition, ferrous/ferric ratio (redox state), thermal history, and groundwater are being investigated. Glasses were tested using modified Materials Characterization Center (MCC) -3 and MCC-1 test methods. Results obtained in fiscal years (FY) 1987 and 1988 are presented here. 13 refs., 27 figs., 36 tabs.

  5. Hydraulic pump

    SciTech Connect (OSTI)

    Polak, P.R.; Jantzen, D.E.

    1984-05-15T23:59:59.000Z

    This invention relates to an improved pump jack characterized by a hollow piston rod which telescopes down over the sucker rod to which it is clamped for reciprocating motion. The cylinder, in turn, is fastened in fixed position directly to the upper exposed end of the well casing. As fluid is introduced into the lower end of the cylinder it raises the piston into engagement with a pushrod housed in the upper cylinder head that lifts switch-actuating means associated therewith into a position operative to actuate a switch located adjacent thereto thereby causing the latter to change state and actuate a multi-function solenoid valve so as to cut off fluid flow to the cylinder. As gravity lowers the sucker rod and piston exhausting the hydraulic fluid therebeneath, an adjustable stop engages the pushrod from above so as to return it together with the switch-actuating means associated therewith to their original positions thereby resetting the switch to complete the operating cycle.

  6. Development of a phenomena identification and ranking table for thermal-hydraulic phenomena during a double-ended guillotine break LOCA in an SRS production reactor

    SciTech Connect (OSTI)

    Hanson, R.G.; Ortiz, M.G.; Bolander, M.A.; Wilson, G.E.

    1989-07-01T23:59:59.000Z

    A rising level of scrutiny is being directed toward the Savannah River Site (SRS) production reactors. Improved calculational capabilities are being developed to provide a best estimate analytical process to determine the safe operating margins of the reactors. The Code Scaling, Applicability, and Uncertainty (CSAU) methodology, developed by the US Nuclear Regulatory Commission to support best estimate simulations, is being applied to the best estimate limits analysis for the SRS production reactors. One of the foundational parts of the method is the identification and ranking of all the processes that occur during the specific limiting scenario. The phenomena ranking is done according to their importance to safety criteria during the transient and is used to focus the uncertainty analysis on a sufficient, yet cost effective scope of work. This report documents the thermal-hydraulic phenomena that occur during a limiting break in an SRS production reactor and their importance to the uncertainty in simulations of the reactor behavior. 9 refs., 14 figs., 10 tabs.

  7. The GLASS CHAIR Edited by Manuel Heitor

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    The GLASS CHAIR Edited by Manuel Heitor IST Press, 2000 #12;Collaborative Design of... The GLASS the glass chair, but also for the numerous discussions on glass production processes. And last · Carmo Valente Chapter 4. GLASS: BEAUTY WITH STRENGTH Sushil Kumar Mendiratta Chapter 5. The IDEA

  8. Thermal-Hydraulic Analyses of Heat Transfer Fluid Requirements and Characteristics for Coupling A Hydrogen Production Plant to a High-Temperature Nuclear Reactor

    SciTech Connect (OSTI)

    C. B. Davis; C. H. Oh; R. B. Barner; D. F. Wilson

    2005-06-01T23:59:59.000Z

    The Department of Energy is investigating the use of high-temperature nuclear reactors to produce hydrogen using either thermochemical cycles or high-temperature electrolysis. Although the hydrogen production processes are in an early stage of development, coupling either of these processes to the hightemperature reactor requires both efficient heat transfer and adequate separation of the facilities to assure that off-normal events in the production facility do not impact the nuclear power plant. An intermediate heat transport loop will be required to separate the operations and safety functions of the nuclear and hydrogen plants. A next generation high-temperature reactor could be envisioned as a single-purpose facility that produces hydrogen or a dual-purpose facility that produces hydrogen and electricity. Early plants, such as the proposed Next Generation Nuclear Plant, may be dual-purpose facilities that demonstrate both hydrogen and efficient electrical generation. Later plants could be single-purpose facilities. At this stage of development, both single- and dual-purpose facilities need to be understood. Seven possible configurations for a system that transfers heat between the nuclear reactor and the hydrogen and/or electrical generation plants were identified. These configurations included both direct and indirect cycles for the production of electricity. Both helium and liquid salts were considered as the working fluid in the intermediate heat transport loop. Methods were developed to perform thermalhydraulic and cycle-efficiency evaluations of the different configurations and coolants. The thermalhydraulic evaluations estimated the sizes of various components in the intermediate heat transport loop for the different configurations. The relative sizes of components provide a relative indication of the capital cost associated with the various configurations. Estimates of the overall cycle efficiency of the various configurations were also determined. The evaluations determined which configurations and coolants are the most promising from thermal-hydraulic and efficiency points of view. These evaluations also determined which configurations and options do not appear to be feasible at the current time.

  9. HIGH LEVEL WASTE (HLW) VITRIFICATION EXPERIENCE IN THE US: APPLICATION OF GLASS PRODUCT/PROCESS CONTROL TO OTHERHLW AND HAZARDOUS WASTES

    SciTech Connect (OSTI)

    Jantzen, C; James Marra, J

    2007-09-17T23:59:59.000Z

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. At the Savannah River Site (SRS) actual HLW tank waste has successfully been processed to stringent product and process constraints without any rework into a stable borosilicate glass waste since 1996. A unique 'feed forward' statistical process control (SPC) has been used rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. In SQC, the glass product is sampled after it is vitrified. Individual glass property models form the basis for the 'feed forward' SPC. The property models transform constraints on the melt and glass properties into constraints on the feed composition. The property models are mechanistic and depend on glass bonding/structure, thermodynamics, quasicrystalline melt species, and/or electron transfers. The mechanistic models have been validated over composition regions well outside of the regions for which they were developed because they are mechanistic. Mechanistic models allow accurate extension to radioactive and hazardous waste melts well outside the composition boundaries for which they were developed.

  10. Stimuli-Responsive/Rheoreversible Hydraulic Fracturing Fluids as a Greener Alternative to Support Geothermal and Fossil Energy Production

    SciTech Connect (OSTI)

    Jung, Hun Bok; Carroll, KC; Kabilan, Senthil; Heldebrant, David J.; Hoyt, David W.; Zhong, Lirong; Varga, Tamas; Stephens, Sean A.; Adams, Lexor; Bonneville, Alain; Kuprat, Andrew P.; Fernandez, Carlos A.

    2015-01-01T23:59:59.000Z

    Cost-effective yet safe creation of high-permeability reservoirs within deep bedrock is the primary challenge for the viability of enhanced geothermal systems (EGS) and unconventional oil/gas recovery. Although fracturing fluids are commonly used for oil/gas, standard fracturing methods are not developed or proven for EGS temperatures and pressures. Furthermore, the environmental impacts of currently used fracturing methods are only recently being determined. Widespread concerns about the environmental contamination have resulted in a number of regulations for fracturing fluids advocating for greener fracturing processes. To enable EGS feasibility and lessen environmental impact of reservoir stimulation, an environmentally benign, CO2-activated, rheoreversible fracturing fluid that enhances permeability through fracturing (at significantly lower effective stress than standard fracturing fluids) due to in situ volume expansion and gel formation is investigated herein. The chemical mechanism, stability, phase-change behavior, and rheology for a novel polyallylamine (PAA)-CO2 fracturing fluid was characterized at EGS temperatures and pressures. Hydrogel is formed upon reaction with CO2 and this process is reversible (via CO2 depressurization or solubilizing with a mild acid) allowing removal from the formation and recycling, decreasing environmental impact. Rock obtained from the Coso geothermal field was fractured in laboratory experiments under various EGS temperatures and pressures with comparison to standard fracturing fluids, and the fractures were characterized with imaging, permeability measurement, and flow modeling. This novel fracturing fluid and process may vastly reduce water usage and the environmental impact of fracturing practices and effectively make EGS production and unconventional oil/gas exploitation cost-effective and cleaner.

  11. Conceptual waste package interim product specifications and data requirements for disposal of borosilicate glass defense high-level waste forms in salt geologic repositories

    SciTech Connect (OSTI)

    Not Available

    1983-06-01T23:59:59.000Z

    The conceptual waste package interim product specifications and data requirements presented are applicable specifically to the normal borosilicate glass product of the Defense Waste Processing Facility (DWPF). They provide preliminary numerical values for the defense high-level waste form parameters and properties identified in the waste form performance specification for geologic isolation in salt repositories. Subject areas treated include containment and isolation, operational period safety, criticality control, waste form/production canister identification, and waste package performance testing requirements. This document was generated for use in the development of conceptual waste package designs in salt. It will be revised as additional data, analyses, and regulatory requirements become available.

  12. Downhole hydraulic seismic generator

    DOE Patents [OSTI]

    Gregory, Danny L. (Corrales, NM); Hardee, Harry C. (Albuquerque, NM); Smallwood, David O. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    A downhole hydraulic seismic generator system for transmitting energy wave vibrations into earth strata surrounding a borehole. The system contains an elongated, unitary housing operably connected to a well head aboveground by support and electrical cabling, and contains clamping apparatus for selectively clamping the housing to the walls of the borehole. The system further comprises a hydraulic oscillator containing a double-actuating piston whose movement is controlled by an electro-servovalve regulating a high pressure hydraulic fluid flow into and out of upper and lower chambers surrounding the piston. The spent hydraulic fluid from the hydraulic oscillator is stored and pumped back into the system to provide high pressure fluid for conducting another run at the same, or a different location within the borehole.

  13. The Effect of Proppant Size and Concentration on Hydraulic Fracture Conductivity in Shale Reservoirs 

    E-Print Network [OSTI]

    Kamenov, Anton

    2013-04-11T23:59:59.000Z

    Hydraulic fracture conductivity in ultra-low permeability shale reservoirs is directly related to well productivity. The main goal of hydraulic fracturing in shale formations is to create a network of conductive pathways in the rock which increase...

  14. Hydraulic Fracture Optimization with a Pseudo-3D Model in Multi-layered Lithology 

    E-Print Network [OSTI]

    Yang, Mei

    2011-10-21T23:59:59.000Z

    Hydraulic Fracturing is a technique to accelerate production and enhance ultimate recovery of oil and gas while fracture geometry is an important aspect in hydraulic fracturing design and optimization. Systematic design ...

  15. Water management in hydraulic fracturing-a planning and decision optimization platform

    E-Print Network [OSTI]

    Mehta, Neha, S.M. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Recent developments in hydraulic fracturing technology have enabled cost-effective production of unconventional resources, particularly shale gas in the U.S. The process of hydraulic fracturing is water intensive, requiring ...

  16. The Effect of Proppant Size and Concentration on Hydraulic Fracture Conductivity in Shale Reservoirs

    E-Print Network [OSTI]

    Kamenov, Anton

    2013-04-11T23:59:59.000Z

    Hydraulic fracture conductivity in ultra-low permeability shale reservoirs is directly related to well productivity. The main goal of hydraulic fracturing in shale formations is to create a network of conductive pathways in the rock which increase...

  17. Glass balls

    E-Print Network [OSTI]

    There is a building with 100 floors in it, and glass balls, and an integer k with the following property. If one drops a glass ball from the floor number k or higher, ...

  18. Crystallization during processing of nuclear waste glass

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2010-12-01T23:59:59.000Z

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glassmaking are reviewed.

  19. Final Report_Production Hydrualic Packer Test.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CENTER Production Hydraulic Packer Field Test i DOERMOTC020120 PRODUCTION HYDRAULIC PACKER FIELD TEST Field Report for the period of October 21, 1999 - November 01, 1999 Date...

  20. Prediction of effects of hydraulic fracturing using reservoir and well flow simulation

    SciTech Connect (OSTI)

    Mineyuki Hanano; Tayuki Kondo

    1992-01-01T23:59:59.000Z

    This paper presents a method to predict and evaluate effects of hydraulic fracturing jobs by using reservoir and well flow numerical simulation. The concept of the method i5 that steam production rate at the operating well head pressure is predicted with different fracture conditions which would be attained by the hydraulic fracturing jobs. Then, the effects of the hydraulic fracturing is evaluated by comparing the predicted steam production rate and that before the hydraulic fracturing. This course of analysis will suggest how large fracture should be created by the fracturing job to attain large enough increase in steam production at the operating condition and the best scheme of the hydraulic fracturing job.

  1. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford site low-level waste

    SciTech Connect (OSTI)

    Shade, J.W.

    1996-05-03T23:59:59.000Z

    Commercially available melter technologies were tested for application to vitrification of Hanford site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW simulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  2. Surrogate-based optimization of hydraulic fracturing in pre-existing fracture networks

    E-Print Network [OSTI]

    Lu, Zhiming

    Surrogate-based optimization of hydraulic fracturing in pre-existing fracture networks Mingjie Chen Keywords: Hydraulic fracturing Fractal dimension Surrogate model Optimization Global sensitivity a b s t r a c t Hydraulic fracturing has been used widely to stimulate production of oil, natural gas

  3. Hydraulic limits on maximum plant transpiration and the emergence of the safetyefficiency trade-off

    E-Print Network [OSTI]

    Jackson, Robert B.

    Hydraulic limits on maximum plant transpiration and the emergence of the safety­efficiency trade.12126 Key words: hydraulic limitation, safety­ efficiency trade-off, soil­plant­atmosphere model, trait hydraulics constrain ecosystem productivity by setting physical limits to water transport and hence carbon

  4. Self-potential observations during hydraulic fracturing

    E-Print Network [OSTI]

    Moore, J R; Glaser, Steven D

    2007-01-01T23:59:59.000Z

    potential measurements during hydraulic fracturing of BunterSP response during hydraulic fracturing. Citation: Moore, J.observations during hydraulic fracturing, J. Geophys. Res. ,

  5. Self-potential observations during hydraulic fracturing

    E-Print Network [OSTI]

    Moore, Jeffrey R.; Glaser, Steven D.

    2008-01-01T23:59:59.000Z

    potential measurements during hydraulic fracturing of BunterMonitoring during hydraulic fracturing using the TG-2 well,fracture processes in hydraulic fracturing, Quarterly Report

  6. Geostatistical inference of hydraulic conductivity and dispersivities from hydraulic heads and tracer data

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    Geostatistical inference of hydraulic conductivity and dispersivities from hydraulic heads; accepted 25 April 2006; published 10 August 2006. [1] In groundwater, hydraulic heads and solute arrival times depend primarily on the hydraulic conductivity field and hydraulic boundary conditions. The spread

  7. Investigation of Created Fracture Geometry through Hydraulic Fracture Treatment Analysis

    E-Print Network [OSTI]

    Ahmed, Ibraheem 1987-

    2012-11-30T23:59:59.000Z

    Successful development of shale gas reservoirs is highly dependent on hydraulic fracture treatments. Many questions remain in regards to the geometry of the created fractures. Production data analysis from some shale gas wells quantifies a much...

  8. Natural analogues of nuclear waste glass corrosion.

    SciTech Connect (OSTI)

    Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

    1999-01-06T23:59:59.000Z

    This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

  9. Water Resources: Hydraulics and Hydrology

    E-Print Network [OSTI]

    US Army Corps of Engineers

    Water Resources: Hydraulics and Hydrology Interview with Margaret S. Petersen #12;This manuscript RESOURCES: HYDRAULICS AND HYDROLOGY #12;Approved for public release distribution IS unlimited. #12;Preface The United States Army Corps of Engineers significantly contributed to hydraulic and hydrologic engineering

  10. Viscous Hydraulic Jumps Submitted by

    E-Print Network [OSTI]

    Bush, John W.M.

    Viscous Hydraulic Jumps Submitted by Jeffrey M. Aristoff, Jeffrey D. Leblanc, Annette E. Hosoi, and John W. M. Bush, Massachusetts Institute of Technology We examine the form of the viscous hydraulic of height 2­10 mm. Elegaard et al.1 first demonstrated that the axial symme- try of the viscous hydraulic

  11. Analytical electron microscopy examination of solid reaction products in long-term test of SRL 200 waste glasses

    SciTech Connect (OSTI)

    Buck, E.C.; Fortner, J.A.; Bates, J.K.; Feng, X.; Dietz, N.L.; Bradley, C.R.; Tani, B.S.

    1993-12-31T23:59:59.000Z

    Alteration phases, found on the leached surfaces and present as colloids in the leachates of 200-based frit (fully active and simulated) nuclear waste glass, reacted under static test conditions, at a surface area to leachate volume ratio of 20,000 m{sup {minus}1} for 15 days to 728 days, have been examined by analytical electron microscopy. The compositions of the secondary phases were determined using x-ray energy dispersive spectroscopy and electron energy loss spectroscopy, and structural analysis was accomplished by electron diffraction. Long-term samples of simulated glass, which had undergone an acceleration of reaction after 182 days, possessed a number of silicate secondary phases, including; smectite (iron silicate and potassium iron alumina-silicate, weeksite (uranium silicate), zeolite (calcium potassium alumino-silicate), tobermorite (calcium silicate), and a pure silica phase. However, uranium silicates and smectite have also been observed in tests, which have not undergone the acceleration of reaction, in both the leachate and leached layer, suggesting that these phases are not responsible for the acceleration of reaction.

  12. Hydraulic waste energy recovery

    SciTech Connect (OSTI)

    Lederer, C.C.; Thomas, A.H.; McGuire, J.L. (Detroit Buildings and Safety Engineering Dept., MI (USA))

    1990-12-01T23:59:59.000Z

    Water distribution systems are typically a municipality's largest consumer of energy and greatest expense. The water distribution network has varying pressure requirements due to the age of the pipeline and topographical differences. Certain circumstances require installation of pressure reducing devices in the pipeline to lower the water pressure in the system. The consequence of this action is that the hydraulic energy supplied by the high lift or booster pumps is wasted in the process of reducing the pressure. A possible solution to capture the waste hydraulic energy is to install an in-line electricity generating turbine. Energy recovery using in-line turbine systems is an emerging technology. Due to the lack of technical and other relevant information on in-line turbine system installations, questions of constructability and legal issues over the power service contract have yet to be answered. This study seeks to resolve these questions and document the findings so that other communities may utilize this information. 10 figs.

  13. Through a glass darkly

    E-Print Network [OSTI]

    Hall, James E

    2012-01-01T23:59:59.000Z

    Closeup Through a glass darklyThrough a glass darkly James E. Hall Keywords: AKAP2; AQP0;Medicine Closeup Through a glass darkly GLUT1 Glucose

  14. Film Formation Mechanism in Glass Lubrication by Polymer Latex Dispersions

    E-Print Network [OSTI]

    Boyer, Edmond

    coatings by tin dioxide resulting in glass bottle lubrication was investigated on flat glass. The anchoring contacts between glass bottles on production lines and transport affect both their mechanical strength and visual aspect. To improve their scratch resistance and prevent surface damage, glass bottles

  15. Glass needs for a growing photovoltaics industry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burrows, Keith; Fthenakis, Vasilis

    2015-01-01T23:59:59.000Z

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantialmore »investments.« less

  16. Glass needs for a growing photovoltaics industry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burrows, Keith [Columbia Univ., New York, NY (United States); Fthenakis, Vasilis [Columbia Univ., New York, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantial investments.

  17. Investigation of the Effect of Non-Darcy Flow and Multi-Phase Flow on the Productivity of Hydraulically Fractured Gas Wells

    E-Print Network [OSTI]

    Alarbi, Nasraldin Abdulslam A.

    2011-10-21T23:59:59.000Z

    an optimum stimulation treatment that leads to the maximum possible productivity. These considerations include, but not limited to, non-Darcy flow and multiphase flow effects inside the fracture. These effects reduce the fracture conductivity significantly...

  18. Relationship between Anisotropy in Soil Hydraulic Conductivity and Saturation

    SciTech Connect (OSTI)

    Zhang, Z. Fred

    2014-01-01T23:59:59.000Z

    Anisotropy in unsaturated hydraulic conductivity is saturation-dependent. Accurate characterization of soil anisotropy is very important in simulating flow and contaminant (e.g., radioactive nuclides in Hanford) transport. A recently developed tensorial connectivity-tortuosity (TCT) concept describes the hydraulic conductivity tensor of the unsaturated anisotropic soils as the product of a scalar variable, the symmetric connectivity tortuosity tensor, and the hydraulic conductivity tensor at saturation. In this study, the TCT model is used to quantify soil anisotropy in unsaturated hydraulic conductivity. The TCT model can describe different types of soil anisotropy; e.g., the anisotropy coefficient, C, can be monotonically increase or decrease with saturation and can vary from greater than unity to less than unity and vice versa. Soil anisotropy is independent of soil water retention properties and can be characterized by the ratio of the saturated hydraulic conductivities and the difference of the tortuosity-connectivity coefficients in two directions. ln(C) is linearly proportional to ln(Se) with Se being the effective saturation. The log-linear relationship between C and Se allows the saturation-dependent anisotropy to be determined using linear regression with the measurements of the directional hydraulic conductivities at a minimum of two water content levels, of which one may be at full saturation. The model was tested using measurements of directional hydraulic conductivities.

  19. POROUS WALL, HOLLOW GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Sexton, W.

    2012-06-30T23:59:59.000Z

    Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of magnitude, which can result in unique properties in areas such as hydrogen storage, gas transport, gas separations and purifications, sensors, global warming applications, new drug delivery systems and so on. One of the most interesting porous glass products that SRNL has developed and patented is Porous Wall, Hollow Glass Microspheres (PW-HGMs) that are being studied for many different applications. The European Patent Office (EPO) just recently notified SRS that the continuation-in-part patent application for the PW-HGMs has been accepted. The original patent, which was granted by the EPO on June 2, 2010, was validated in France, Germany and the United Kingdom. The microspheres produced are generally in the range of 2 to 100 microns, with a 1 to 2 micron wall. What makes the SRNL microspheres unique from all others is that the team in Figure 1 has found a way to induce and control porosity through the thin walls on a scale of 100 to 3000 {angstrom}. This is what makes the SRNL HW-HGMs one-of-a-kind, and is responsible for many of their unique properties and potential for various applications, including those in tritium storage, gas separations, H-storage for vehicles, and even a variety of new medical applications in the areas of drug delivery and MRI contrast agents. SRNL Hollow Glass Microspheres, and subsequent, Porous Wall, Hollow Glass Microspheres are fabricated using a flame former apparatus. Figure 2 is a schematic of the apparatus.

  20. Hydraulic mining method

    DOE Patents [OSTI]

    Huffman, Lester H. (Kent, WA); Knoke, Gerald S. (Kent, WA)

    1985-08-20T23:59:59.000Z

    A method of hydraulically mining an underground pitched mineral vein comprising drilling a vertical borehole through the earth's lithosphere into the vein and drilling a slant borehole along the footwall of the vein to intersect the vertical borehole. Material is removed from the mineral vein by directing a high pressure water jet thereagainst. The resulting slurry of mineral fragments and water flows along the slant borehole into the lower end of the vertical borehole from where it is pumped upwardly through the vertical borehole to the surface.

  1. Case studies of the potential effects of carbon taxation on the stone, clay, and glass industry

    SciTech Connect (OSTI)

    Bock, M.J.; Boyd, G.A. (Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.); Rosenbaum, D.I. (Nebraska Univ., Lincoln, NE (United States). Dept. of Economics); Ross, M.H. (Michigan Univ., Ann Arbor, MI (United States). Dept. of Physics)

    1992-12-01T23:59:59.000Z

    This case study focuses on the potential for a carbon tax ($25 and $100 per metric ton of carbon) to reduce energy use and associated carbon dioxide (CO[sub 2]) emissions in three subsectors of the stone, clay, and glass industry: hydraulic cement, glass and glass products, and other products. A conservation supply curve analysis found that (1) opportunities for reducing fossil fuel use in the subsectors are limited (15% reduction under $100 tax) and (2) the relationship between the tax and reduced CO[sub 2] emissions is nonlinear and diminishing. Because cement manufacturing produces a significant amount of CO[sub 2], this subsector was analyzed. A plant-level analysis found more opportunities to mitigate CO[sub 2] emissions; under a $100 tax, fossil fuel use would decrease 52%. (A conservative estimate lies between 15% and 52%). It also confirmed the nonlinear relationship, suggesting significant benefits could result from small taxes (32% reduction under $25 tax). A fuel share analysis found the cement industry could reduce carbon loading 11% under a $100 tax if gas were substituted for coal. Under a $100 tax, cement demand would decrease 17% and its price would increase 32%, a substantial increase for a material commodity. Overall, CO[sub 2] emissions from cement manufacturing would decrease 24--33% under a $100 tax and 10--18% under a $25 tax. Much of the decrease would result from the reduced demand for cement.

  2. Case studies of the potential effects of carbon taxation on the stone, clay, and glass industry

    SciTech Connect (OSTI)

    Bock, M.J.; Boyd, G.A. [Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.; Rosenbaum, D.I. [Nebraska Univ., Lincoln, NE (United States). Dept. of Economics; Ross, M.H. [Michigan Univ., Ann Arbor, MI (United States). Dept. of Physics

    1992-12-01T23:59:59.000Z

    This case study focuses on the potential for a carbon tax ($25 and $100 per metric ton of carbon) to reduce energy use and associated carbon dioxide (CO{sub 2}) emissions in three subsectors of the stone, clay, and glass industry: hydraulic cement, glass and glass products, and other products. A conservation supply curve analysis found that (1) opportunities for reducing fossil fuel use in the subsectors are limited (15% reduction under $100 tax) and (2) the relationship between the tax and reduced CO{sub 2} emissions is nonlinear and diminishing. Because cement manufacturing produces a significant amount of CO{sub 2}, this subsector was analyzed. A plant-level analysis found more opportunities to mitigate CO{sub 2} emissions; under a $100 tax, fossil fuel use would decrease 52%. (A conservative estimate lies between 15% and 52%). It also confirmed the nonlinear relationship, suggesting significant benefits could result from small taxes (32% reduction under $25 tax). A fuel share analysis found the cement industry could reduce carbon loading 11% under a $100 tax if gas were substituted for coal. Under a $100 tax, cement demand would decrease 17% and its price would increase 32%, a substantial increase for a material commodity. Overall, CO{sub 2} emissions from cement manufacturing would decrease 24--33% under a $100 tax and 10--18% under a $25 tax. Much of the decrease would result from the reduced demand for cement.

  3. A new method for solving radiative heat problems in glass

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    RANA 99­06 A new method for solving radiative heat problems in glass B.J. van der Linden --- R, The Netherlands e­mail: linden@win.tue.nl 15th May 2000 #12; Abstract In the production of glass, temperature Conclusion 25 2 #12; Chapter 1 Introduction The production of glass belongs to the oldest forms of human

  4. A new method for solving radiative heat problems in glass

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    RANA 99-06 A new method for solving radiative heat problems in glass B.J. van der Linden -- R, The Netherlands e-mail: linden@win.tue.nl 15th May 2000 #12;Abstract In the production of glass, temperature plays Conclusion 25 2 #12;Chapter 1 Introduction The production of glass belongs to the oldest forms of human

  5. Hydraulic and Habitat Suitability Analyses Technical Memorandum

    E-Print Network [OSTI]

    Appendix D Hydraulic and Habitat Suitability Analyses Technical Memorandum #12;COPYRIGHT DECEMBER Series 2 and Pond Series 3 Hydraulic and Habitat Suitability Analyses Prepared for Bureau of Reclamation HILL, INC. III Hydraulic and Habitat Suitability Analyses

  6. Parker Hybrid Hydraulic Drivetrain Demonstration

    SciTech Connect (OSTI)

    Collett, Raymond [Parker-Hannifin Corporation, Cleveland, OH (United States); Howland, James [Parker-Hannifin Corporation, Cleveland, OH (United States); Venkiteswaran, Prasad [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

    2014-03-31T23:59:59.000Z

    This report examines the benefits of Parker Hannifin hydraulic hybrid brake energy recovery systems used in commercial applications for vocational purposes. A detailed background on the problem statement being addressed as well as the solution set specific for parcel delivery will be provided. Objectives of the demonstration performed in high start & stop applications included opportunities in fuel usage reduction, emissions reduction, vehicle productivity, and vehicle maintenance. Completed findings during the demonstration period and parallel investigations with NREL, CALSTART, along with a literature review will be provided herein on this research area. Lastly, results identified in the study by third parties validated the savings potential in fuel reduction of on average of 19% to 52% over the baseline in terms of mpg (Lammert, 2014, p11), Parker data for parcel delivery vehicles in the field parallels this at a range of 35% - 50%, emissions reduction of 17.4% lower CO2 per mile and 30.4% lower NOx per mile (Gallo, 2014, p15), with maintenance improvement in the areas of brake and starter replacement, while leaving room for further study in the area of productivity in terms of specific metrics that can be applied and studied.

  7. Hydraulic Hybrid Parcel Delivery Truck Deployment, Testing & Demonstration

    SciTech Connect (OSTI)

    Gallo, Jean-Baptiste

    2014-03-31T23:59:59.000Z

    Although hydraulic hybrid systems have shown promise over the last few years, commercial deployment of these systems has primarily been limited to Class 8 refuse trucks. In 2005, the Hybrid Truck Users Forum initiated the Parcel Delivery Working Group including the largest parcel delivery fleets in North America. The goal of the working group was to evaluate and accelerate commercialization of hydraulic hybrid technology for parcel delivery vehicles. FedEx Ground, Purolator and United Parcel Service (UPS) took delivery of the world’s first commercially available hydraulic hybrid parcel delivery trucks in early 2012. The vehicle chassis includes a Parker Hannifin hydraulic hybrid drive system, integrated and assembled by Freightliner Custom Chassis Corp., with a body installed by Morgan Olson. With funding from the U.S. Department of Energy, CALSTART and its project partners assessed the performance, reliability, maintainability and fleet acceptance of three pre-production Class 6 hydraulic hybrid parcel delivery vehicles using information and data from in-use data collection and on-road testing. This document reports on the deployment of these vehicles operated by FedEx Ground, Purolator and UPS. The results presented provide a comprehensive overview of the performance of commercial hydraulic hybrid vehicles in parcel delivery applications. This project also informs fleets and manufacturers on the overall performance of hydraulic hybrid vehicles, provides insights on how the technology can be both improved and more effectively used. The key findings and recommendations of this project fall into four major categories: ? Performance, ? Fleet deployment, ? Maintenance, ? Business case. Hydraulic hybrid technology is relatively new to the market, as commercial vehicles have been introduced only in the past few years in refuse and parcel delivery applications. Successful demonstration could pave the way for additional purchases of hydraulic hybrid vehicles throughout the trucking industry. By providing unbiased, third-party assessment of this “hybrid without batteries” technology, this report offers relevant, timely and valuable information to the industry.

  8. Spectroscopic investigation of simulated low-level nuclear waste glass

    SciTech Connect (OSTI)

    Rong, Chaoying; Li, Hong; Hrma, P.R.; Cho, H.M. [Pacific Northwest National Lab., Richland, WA (United States)

    1996-12-31T23:59:59.000Z

    Borosilicate glasses with high sodium concentrations, formulated to simulate vitrified Hanford low-level wastes (LLW), were investigated by {sup 31}P magic angle spinning (MAS) nuclear magnetic resonance (NMR). Phase separation, glass homogeneity changes during remelting, and the form of phosphate in glass following product consistency tests (PCT) were also examined by NMR. The results show that a distinct orthophosphate phase not part of the glass network is present in the glass. The effect of glass composition on phosphate chemical environments in the glass is discussed.

  9. Database and Interim Glass Property Models for Hanford HLW Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Piepel, Gregory F.; Vienna, John D.; Cooley, Scott K.; Kim, Dong-Sang; Russell, Renee L.

    2001-07-24T23:59:59.000Z

    The purpose of this report is to provide a methodology for an increase in the efficiency and a decrease in the cost of vitrifying high-level waste (HLW) by optimizing HLW glass formulation. This methodology consists in collecting and generating a database of glass properties that determine HLW glass processability and acceptability and relating these properties to glass composition. The report explains how the property-composition models are developed, fitted to data, used for glass formulation optimization, and continuously updated in response to changes in HLW composition estimates and changes in glass processing technology. Further, the report reviews the glass property-composition literature data and presents their preliminary critical evaluation and screening. Finally the report provides interim property-composition models for melt viscosity, for liquidus temperature (with spinel and zircon primary crystalline phases), and for the product consistency test normalized releases of B, Na, and Li. Models were fitted to a subset of the screened database deemed most relevant for the current HLW composition region.

  10. ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...

    Broader source: Energy.gov (indexed) [DOE]

    industrialbandwidth.pdf More Documents & Publications ITP Glass: Glass Industry of the Future: Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 ITP Glass:...

  11. Combustion Technology Development for an Advanced Glass Melting System

    E-Print Network [OSTI]

    Stickler, D. B.; Westra, L.; Woodroffe, J.; Jeong, K. M.; Donaldson, L. W.

    Concept feasibility of an innovative technology for glass production has recently been demonstrated. It is based on suspension heating of the glass-forming batch minerals while entrained in a combustion flow of preheated air and natural gas...

  12. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2013-01-01T23:59:59.000Z

    Investigations on hydraulic cement from spent oil shale,"April 16-18, 1980 HYDRAULIC CEMENT PREPARATION FROM LURGIpressi ve b strength, MPa this cement in moist environments.

  13. Corrosion of Partially Crystallized Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Riley, Brian J.; Vienna, John D.

    2002-05-21T23:59:59.000Z

    Using existing data on corrosion of partially crystallized, simulated, high-level waste glasses, coefficients were introduced to evaluate the cumulative influence of secondary effects, such as residual stresses or concentration gradients on product consistency test response. As compared to predictions based solely on residual glass composition effects, the results showed that cristobalite, eucryptite, and nepheline had a higher-than-predicted impact on glass corrosion, while the effects of baddeleyite, hematite, calcium-zirconium silicate, and zircon were close to those predicted. The effects of acmite and lithium silicate were opposite to those expected based on their compositions. The analysis revealed important limitations of the databases currently available. Better understanding of corrosion phenomena will require quantitative composition data, microscopic characterization of pristine and corroded surfaces, and long-term tests with glass coupons or monoliths.

  14. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G. [Oak Ridge National Lab., TN (United States); Andres, R.J. [University of Alaska, Fairbanks, AK (United States). Inst. of Northern Engineering

    1995-12-01T23:59:59.000Z

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  15. Electrokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

    2000-01-01T23:59:59.000Z

    A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.

  16. Indirect Adaptive Robust Control of Electro-Hydraulic Systems Driven by Single-Rod Hydraulic Actuator

    E-Print Network [OSTI]

    Yao, Bin

    Indirect Adaptive Robust Control of Electro-Hydraulic Systems Driven by Single-Rod Hydraulic) of electro-hydraulic systems driven by single- rod hydraulic actuators. Unlike the tracking that the proposed IARC achieves good tracking performance and accurate parameter estimation. INTRODUCTION Electro-hydraulic

  17. Development of Property-Transfer Models for Estimating the Hydraulic Properties of Deep

    E-Print Network [OSTI]

    Development of Property-Transfer Models for Estimating the Hydraulic Properties of Deep Sediments. #12;Development of Property-Transfer Models for Estimating the Hydraulic Properties of Deep Sediments-USGS World Wide Web: http://www.usgs.gov/ Any use of trade, product, or firm names in this publication

  18. Recover Power with Hydraulic Motors

    E-Print Network [OSTI]

    Brennan, J. R.

    1982-01-01T23:59:59.000Z

    displacement device, the HPRM torque and speed are almost completely independent - unlike hydraulic power recovery turbines (centrifugal motors). Three screw HPRM's have low moments of inertia, operate at low vibration and noise levels and extract power...

  19. Numerical simulation of hydraulic fracturing

    E-Print Network [OSTI]

    Warner, Joseph Barnes

    1987-01-01T23:59:59.000Z

    ~ared that the results of such treatments were not always adequately described by the two-dimensional models. With recent advances in hydraulic fracturing and computing technology, attempts have been made to formulate more realistic fracture models. These three...NUMERICAL SIMULATION OF HYDRAULIC FRACTURING A Thesis by JOSEPH BARNES WARNER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1987 Maj or Subj ect...

  20. Waste Glass Corrosion: Some Open Questions

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Vienna, John D.; Yeager, John D.

    2003-05-21T23:59:59.000Z

    An equation for time evolution of glass corrosion in a closed system is proposed. Examples of fitting this equation to vapor-hydration test (VHT) and product consistency test data are shown. It is argued that the stage of accelerated corrosion of waste glass is a temporary spike caused by a transition to a different mechanism (not associated solely with high-alumina content in glass) and followed by slower steady corrosion. The effect of temperature and glass composition on the VHT rate of corrosion is evaluated. Results of different corrosion tests are compared. Progress towards a frame-indifferent rate equation is outlined.

  1. ITP Glass: Glass Industry of the Future: Energy and Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    glass2002profile.pdf More Documents & Publications ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: A Clear Vision for a Bright Future ITP Glass:...

  2. Impact of HLW Glass Crystallinity on the PCT Response

    SciTech Connect (OSTI)

    Riley, Brian J.; Rosario, Jose A.; Hrma, Pavel R.

    2002-08-08T23:59:59.000Z

    Optimizing glass formulation for vitrifying waste is based on computing a glass composition that would meet processability and acceptability constraints imposed on glass properties and composition while maximizing system efficiency. The process currently employed allows for estimation of all limiting glass properties except for the normalized element releases (ri, where i = B, Na, or Li) by the product consistency test (PCT) from glasses subjected to canister centerline cooling (CCC). This report documents a suggested approach to include this key glass property in numerical glass optimization. It shows that acceptable predictions of rB and rNa from CCC glasses can be obtained provided that sufficiently accurate compositions and concentrations of the crystalline phases in CCC glass are known.

  3. HYDRAULIC FRACTURE MODEL SENSITIVITY ANALYSES OF MASSIVELY STACKED LENTICULAR RESERVOIRS

    E-Print Network [OSTI]

    and 50% of the total cost may be due to the well stimulation treatment. Therefore, there is a need (MWX) site. A geologic characterization of the Mesaverde group established that the production. In common with most tight gas reservoirs, hydraulic stimulation is required to interconnect the dual

  4. INTERPRETATION OF A HYDRAULIC FRACTURING EXPERIMENT, MONTICELLO, SOUTH CAROLINA

    E-Print Network [OSTI]

    Narasimhan, T.N.

    2014-01-01T23:59:59.000Z

    Letters INTERPRETATION OF A HYDRAULIC FRACTURING EXPERIMENT,12091 INTERPRETATION OF A HYDRAULIC FRACTURING EXPERIMENT,transient data from a hydraulic fracturing experiment have

  5. Mercury-Contaminated Hydraulic Mining Debris in San Francisco Bay

    E-Print Network [OSTI]

    Bouse, Robin M; Fuller, Christopher C; Luoma, Sam; Hornberger, Michelle I; Jaffe, Bruce E; Smith, Richard E

    2010-01-01T23:59:59.000Z

    Contaminated Hydraulic Mining Debris in San Francisco BayAbstract The hydraulic gold-mining process used during thecreated by hydraulic gold mining in the Sierra Nevada,

  6. NEWS & VIEWS Glass dynamics

    E-Print Network [OSTI]

    Weeks, Eric R.

    NEWS & VIEWS Glass dynamics Diverging views on glass transition Gregory B. mc.mckenna@ttu.edu T he glass transition is one of the most intriguing phenomena in the world of soft condensed matter. Despite decades of study, many aspects of the behaviour of glass-forming liquids remain elusive

  7. Glass-silicon column

    DOE Patents [OSTI]

    Yu, Conrad M.

    2003-12-30T23:59:59.000Z

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  8. Energy implications of glass-container recycling

    SciTech Connect (OSTI)

    Gaines, L.L.; Mintz, M.M. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

    1994-03-01T23:59:59.000Z

    This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

  9. Electrokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

    2003-06-03T23:59:59.000Z

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based system. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  10. Method for directional hydraulic fracturing

    DOE Patents [OSTI]

    Swanson, David E. (West St. Paul, MN); Daly, Daniel W. (Crystal, MN)

    1994-01-01T23:59:59.000Z

    A method for directional hydraulic fracturing using borehole seals to confine pressurized fluid in planar permeable regions, comprising: placing a sealant in the hole of a structure selected from geologic or cemented formations to fill the space between a permeable planar component and the geologic or cemented formation in the vicinity of the permeable planar component; making a hydraulic connection between the permeable planar component and a pump; permitting the sealant to cure and thereby provide both mechanical and hydraulic confinement to the permeable planar component; and pumping a fluid from the pump into the permeable planar component to internally pressurize the permeable planar component to initiate a fracture in the formation, the fracture being disposed in the same orientation as the permeable planar component.

  11. Electrokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA); Arnold, Don W. (Livermore, CA); Hencken, Kenneth R. (Pleasanton, CA); Schoeniger, Joseph S. (Oakland, CA); Neyer, David W. (Castro Valley, CA)

    2001-01-01T23:59:59.000Z

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  12. Imaging Hydraulic Fractures: Source Location Uncertainty Analysis At The UPRC Carthage Test Site

    E-Print Network [OSTI]

    Li, Yingping

    1996-01-01T23:59:59.000Z

    Hydraulic fracturing is a useful tool for enhancing gas and oil production. High-resolution seismic imaging of the fracture geometry and fracture growth process is the key in determining optimal spacing and location of ...

  13. Integrated Hydraulic Fracture Placement and Design Optimization in Unconventional Gas Reservoirs 

    E-Print Network [OSTI]

    Ma, Xiaodan

    2013-12-10T23:59:59.000Z

    Unconventional reservoir such as tight and shale gas reservoirs has the potential of becoming the main source of cleaner energy in the 21th century. Production from these reservoirs is mainly accomplished through engineered hydraulic fracturing...

  14. Risk assessment of groundwater contamination from hydraulic fracturing fluid spills in Pennsylvania

    E-Print Network [OSTI]

    Fletcher, Sarah Marie

    2012-01-01T23:59:59.000Z

    Fast-paced growth in natural gas production in the Marcellus Shale has fueled intense debate over the risk of groundwater contamination from hydraulic fracturing and the shale gas extraction process at large. While several ...

  15. Design and analysis of hydraulically driven actuation system For a parabolic solar trough

    E-Print Network [OSTI]

    Popovi?, Katarina, S.B. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    This thesis documents Katarina Popovic's contribution to the design of hydraulic cylinder actuation system for day to day solar trough sun tracking, a semester long project within 2.752 Development of Mechanical Products ...

  16. On the moving boundary conditions for a hydraulic fracture Emmanuel Detournay a,b,

    E-Print Network [OSTI]

    Peirce, Anthony

    are most commonly engineered for the stimulation of hydrocarbon-bearing rock strata to increase production from dikes (Pollard & Hozlhausen, 1979). The design of hydraulic fracturing treatments relies, in part

  17. Integrated Hydraulic Fracture Placement and Design Optimization in Unconventional Gas Reservoirs

    E-Print Network [OSTI]

    Ma, Xiaodan

    2013-12-10T23:59:59.000Z

    Unconventional reservoir such as tight and shale gas reservoirs has the potential of becoming the main source of cleaner energy in the 21th century. Production from these reservoirs is mainly accomplished through engineered hydraulic fracturing...

  18. Powertrain System HANT: Hydraulic Pump/Motor

    SciTech Connect (OSTI)

    Not Available

    1993-06-01T23:59:59.000Z

    The development of the new Hydraulic Pump/Motor is the main part of the Powertrain-System HANT. Several Engineering Models of the same design have been tested to prove that the new concept is effective. The important ranges: Maximum pressure and rpm and low power (low pressure, rpm, swashplate angle) were tested successfully. The efficiencies in all areas have already shown the same or better data then those of the best products on the market. The tests have been conducted in Switzerland (maximum power) in 1987 and at the UWM-Madison, Wisconsin (low power efficiency) in 1988. Based on these data and several new useful design features the Engineering Model has been updated. In addition, the reduction of unnecessary safety factor, new materials and mass-production like manufacturing methods, has lead to an significantly improved Prototype Design. The updated version and its expected improved technical data are presented in this report.

  19. Direction of CRT waste glass processing: Electronics recycling industry communication

    SciTech Connect (OSTI)

    Mueller, Julia R., E-mail: mueller.143@osu.edu [Ohio State University, William G. Lowrie Department of Chemical and Biomolecular Engineering, OH (United States) and University of Queensland, School of Chemical Engineering (Australia) and Ohio State University, Materials Science and Engineering, OH (United States); Boehm, Michael W. [University of Queensland, School of Chemical Engineering (Australia); Drummond, Charles [Ohio State University, Materials Science and Engineering, OH (United States)

    2012-08-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Given a large flow rate of CRT glass {approx}10% of the panel glass stream will be leaded. Black-Right-Pointing-Pointer The supply of CRT waste glass exceeded demand in 2009. Black-Right-Pointing-Pointer Recyclers should use UV-light to detect lead oxide during the separation process. Black-Right-Pointing-Pointer Recycling market analysis techniques and results are given for CRT glass. Black-Right-Pointing-Pointer Academic initiatives and the necessary expansion of novel product markets are discussed. - Abstract: Cathode Ray Tube, CRT, waste glass recycling has plagued glass manufacturers, electronics recyclers and electronics waste policy makers for decades because the total supply of waste glass exceeds demand, and the formulations of CRT glass are ill suited for most reuse options. The solutions are to separate the undesirable components (e.g. lead oxide) in the waste and create demand for new products. Achieving this is no simple feat, however, as there are many obstacles: limited knowledge of waste glass composition; limited automation in the recycling process; transportation of recycled material; and a weak and underdeveloped market. Thus one of the main goals of this paper is to advise electronic glass recyclers on how to best manage a diverse supply of glass waste and successfully market to end users. Further, this paper offers future directions for academic and industry research. To develop the recommendations offered here, a combination of approaches were used: (1) a thorough study of historic trends in CRT glass chemistry; (2) bulk glass collection and analysis of cullet from a large-scale glass recycler; (3) conversations with industry members and a review of potential applications; and (4) evaluation of the economic viability of specific uses for recycled CRT glass. If academia and industry can solve these problems (for example by creating a database of composition organized by manufacturer and glass source) then the reuse of CRT glass can be increased.

  20. Hydraulic jumps on an incline

    E-Print Network [OSTI]

    Jean-Luc Thiffeault; Andrew Belmonte

    2010-09-01T23:59:59.000Z

    When a fluid jet strikes an inclined solid surface at normal incidence, gravity creates a flow pattern with a thick outer rim resembling a parabola and reminiscent of a hydraulic jump. There appears to be little theory or experiments describing simple aspects of this phenomenon, such as the maximum rise height of the fluid above the impact point, and its dependence on jet velocity and inclination angle. We address this with experiments, and present a simple theory based on horizontal hydraulic jumps which accounts for the rise height and its scaling, though without describing the shape of the parabolic envelope.

  1. Electokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

    2000-01-01T23:59:59.000Z

    A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.

  2. The Glass Box offers a unique environment to support research, development and evaluation of software

    E-Print Network [OSTI]

    The Glass Box offers a unique environment to support research, development and evaluation of software products used by workers performing real computer- based tasks. The Glass Box instrumentation and to retrieve, store, and share Glass Box data. · Test Bed environment­Glass Box serves as a test bed

  3. Hydraulic conductivity imaging from 3-D transient hydraulic tomography at several pumping/observation densities

    E-Print Network [OSTI]

    Barrash, Warren

    Hydraulic conductivity imaging from 3-D transient hydraulic tomography at several pumping August 2013; accepted 7 September 2013; published 13 November 2013. [1] 3-D Hydraulic tomography (3-D HT (primarily hydraulic conductivity, K) is estimated by joint inversion of head change data from multiple

  4. Ensemble smoother assimilation of hydraulic head and return flow data to estimate hydraulic conductivity distribution

    E-Print Network [OSTI]

    Bau, Domenico A.

    Ensemble smoother assimilation of hydraulic head and return flow data to estimate hydraulic and data measurements, an ensemble smoother (ES) to provide enhanced estimates of aquifer hydraulic conductivity (K) through assimilation of hydraulic head (H) and groundwater return flow volume (RFV

  5. The Environmental Injector: Beyond Common Rail and Hydraulic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Environmental Injector: Beyond Common Rail and Hydraulic Intensificatiion The Environmental Injector: Beyond Common Rail and Hydraulic Intensificatiion The Environmental...

  6. Nuclear Waste Glasses: Beautiful Simplicity of Complex Systems

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2009-01-01T23:59:59.000Z

    The behavior of glasses with a large number of components, such as waste glasses, is not more complex than the behavior of simple glasses. On the contrary, the presence of many components restricts the composition region of these glasses in a way that allows approximating composition-property relationships by linear functions. This has far-reaching practical consequences for formulating nuclear waste glasses. On the other hand, processing high-level and low-activity waste glasses presents various problems, such as crystallization, foaming, and salt segre-gation in the melter. The need to decrease the settling of solids in the melter to an acceptable level and to maximize the rate of melting presents major challenges to processing technology. However, the most important property of the glass product is its chemical durability, a somewhat vague concept in lieu of the assessment of the glass resistance to aqueous attack while the radioactivity decays over tens of thousands of years.

  7. Hydraulic Fracture: multiscale processes and moving

    E-Print Network [OSTI]

    Peirce, Anthony

    Hydraulic Fracture: multiscale processes and moving interfaces Anthony Peirce Department Mitchell (UBC) · Ed Siebrits (SLB, Houston) #12;2 Outline · What is a hydraulic fracture? · Scaling Fluid Proppant #12;6 An actual hydraulic fracture #12;7 HF experiment (Jeffrey et al CSIRO) #12;8 1D

  8. Hydraulic Fracture: multiscale processes and moving

    E-Print Network [OSTI]

    Peirce, Anthony

    Hydraulic Fracture: multiscale processes and moving interfaces Anthony Peirce Department Siebrits (SLB, Houston) #12;2 Outline · What is a hydraulic fracture? · Mathematical models of hydraulic fracture · Scaling and special solutions for 1-2D models · Numerical modeling for 2-3D problems

  9. LMH Laboratory for Hydraulic Machines Supervisor

    E-Print Network [OSTI]

    Diggavi, Suhas

    rotating (runner-impeller) and stationary (guide vane and stay vane) blades in pump-turbine hydraulicLMH Laboratory for Hydraulic Machines Supervisor: Dr. Mohamed Farhat (LMH) Doctoral Assistants hydraulic lift surface in pump mode and detail the flow behaviour under these conditions. This is a first

  10. Hydraulic Geometry: Empirical Investigations and Theoretical Approaches

    E-Print Network [OSTI]

    Eaton, Brett

    Hydraulic Geometry: Empirical Investigations and Theoretical Approaches B.C. Eatona, a Department of Geography, The University of British Columbia 1984 West Mall, Vancouver, BC, V6T 1Z2 Abstract Hydraulic. One approach to hydraulic geometry considers temporal changes at a single location due to variations

  11. Numerical Study of a Turbulent Hydraulic Jump

    E-Print Network [OSTI]

    Zhao, Qun

    Numerical Study of a Turbulent Hydraulic Jump Qun Zhao, Shubhra Misra, Ib. A. Svendsen and James T of a Turbulent Hydraulic Jump ­ p.1/14 #12;Objective Our ultimate goal is to study the breaking waves. Numerical Study of a Turbulent Hydraulic Jump ­ p.2/14 #12;A moving bore Qiantang Bore China (Courtesy of Dr J

  12. LA-12968-MS The Unsaturated Hydraulic

    E-Print Network [OSTI]

    LA-12968-MS The Unsaturated Hydraulic Characteristics of the BandelierTuff LosN A T I O N A L L A B technical correctness. #12;The Unsaturated Hydraulic Characteristics of the Bandelier Tuff David B. Rogers........................................................................................................4 Hydraulic Data Presentation

  13. 4, 37193769, 2007 A model for hydraulic

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    HESSD 4, 3719­3769, 2007 A model for hydraulic redistribution G. G. Amenu and P. Kumar Title Page are under open-access review for the journal Hydrology and Earth System Sciences A model for hydraulic;HESSD 4, 3719­3769, 2007 A model for hydraulic redistribution G. G. Amenu and P. Kumar Title Page

  14. Regulation of Hydraulic Fracturing in California

    E-Print Network [OSTI]

    Kammen, Daniel M.

    APRIL 2013 Regulation of Hydraulic Fracturing in California: A WAsteWAteR And WAteR QuAlity Pe | Regulation of Hydraulic Fracturing in California Wheeler Institute for Water Law & Policy Center for Law #12;Regulation of Hydraulic Fracturing in California | 3Berkeley law | wheeler InstItute for water law

  15. ENVE 417 HYDRAULIC DESIGN TOPIC SYLLABUS

    E-Print Network [OSTI]

    Clark, Shirley E.

    Applications in Hydraulic Engineering, 5th Edition, Haestad Press. 2002 Shun Dar Lin. Water and WastewaterENVE 417 HYDRAULIC DESIGN TOPIC SYLLABUS Current Catalog Data: Design of water and waste water. John Wiley & Sons, Inc. New York, NY. 2001. Hydraulic Design Handbook, Larry W. Mays, McGraw-Hill, New

  16. Hydraulic Cooling Tower Driver- The Innovation

    E-Print Network [OSTI]

    Dickerson, J. A.

    -drive eliminates these items from the drive train and puts the same electric motor HP at ground level close coupled to a hydraulic pump, filters, and oil reservoir. Hydraulic lines bring oil pressure to the hydraulic motor, which is more than 75% less weight than...

  17. PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS

    SciTech Connect (OSTI)

    Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

    2011-01-04T23:59:59.000Z

    The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

  18. Glass Working, Use and Discard

    E-Print Network [OSTI]

    Nicholson, Paul

    2011-01-01T23:59:59.000Z

    Beck, Horace C. 1934 Glass before 1500 BC. Ancient Egypt7 - 21. Cooney, John 1960 Glass sculpture in ancient Egypt.Journal of Glass Studies 2, pp. 10 - 43. 1976 Glass.

  19. Recent advances in hydraulic fracturing

    SciTech Connect (OSTI)

    Gidley, J.L.

    1989-01-01T23:59:59.000Z

    This book is a reference to the application of significant technological advances in hydraulic fracturing. It features illustrative problems to demonstrate specific applications of advanced technologies. Chapters examine pretreatment formation evaluation, rock mechanics and fracture geometry, 2D and 3D fracture-propagation models, propping agents and fracture conductivity, fracturing fluids and additives, fluid leakoff, flow behavior, proppant transport, treatment design, well completions, field implementation, fracturing-pressure analysis, postfracture formation evaluation, fracture azimuth and geometry determination, and economics of fracturing.

  20. Hydraulic Conductivity Measurements Barrow 2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Katie McKnight; Tim Kneafsey; Craig Ulrich; Jil Geller

    Six individual ice cores were collected from Barrow Environmental Observatory in Barrow, Alaska, in May of 2013 as part of the Next Generation Ecosystem Experiment (NGEE). Each core was drilled from a different location at varying depths. A few days after drilling, the cores were stored in coolers packed with dry ice and flown to Lawrence Berkeley National Laboratory (LBNL) in Berkeley, CA. 3-dimensional images of the cores were constructed using a medical X-ray computed tomography (CT) scanner at 120kV. Hydraulic conductivity samples were extracted from these cores at LBNL Richmond Field Station in Richmond, CA, in February 2014 by cutting 5 to 8 inch segments using a chop saw. Samples were packed individually and stored at freezing temperatures to minimize any changes in structure or loss of ice content prior to analysis. Hydraulic conductivity was determined through falling head tests using a permeameter [ELE International, Model #: K-770B]. After approximately 12 hours of thaw, initial falling head tests were performed. Two to four measurements were collected on each sample and collection stopped when the applied head load exceeded 25% change from the original load. Analyses were performed between 2 to 3 times for each sample. The final hydraulic conductivity calculations were computed using methodology of Das et al., 1985.

  1. Thermal Hydraulic Analysis of HTGR Coupled with Hydrogen Plant

    SciTech Connect (OSTI)

    Chang Oh; Cliff Davis; Robert Barner; Paul Pickard

    2006-06-01T23:59:59.000Z

    The US Department of Energy is investigating the use of high-temperature gas-cooled reactors (HTGR) to produce electricity and hydrogen. Although the hydrogen production processes using the nuclear energy are in an early stage of development, coupling hydrogen plant to HTGR requires both efficient heat transfer and adequate separation of the facilities to assure that off-normal events in the production facility do not impact the nuclear plant. In anticipation of the design, development and procurement of an advanced power conversion system for HTGR, this study was initiated to identify the major design and technology options and their tradeoffs in the evaluation of power conversion system (PCS) coupled to hydrogen plant. In this study, we investigated a number of design configurations and performed thermal hydraulic analyses using various working fluids and various conditions. This paper includes a portion of thermal hydraulic results based on a direct cycle and a parallel intermediate heat exchanger (IHX) configuration option.

  2. System and method for glass processing and temperature sensing

    DOE Patents [OSTI]

    Shepard, Chester L.; Cannon, Bret D.; Khaleel, Mohammad A.

    2004-09-28T23:59:59.000Z

    Techniques for measuring the temperature at various locations through the thickness of glass products and to control the glass processing operation with the sensed temperature information are disclosed. Fluorescence emission of iron or cerium in glass is excited and imaged onto segmented detectors. Spatially resolved temperature data are obtained through correlation of the detected photoluminescence signal with location within the glass. In one form the detected photoluminescence is compared to detected scattered excitation light to determine temperature. Stress information is obtained from the time history of the temperature profile data and used to evaluate the quality of processed glass. A heating or cooling rate of the glass is also controlled to maintain a predetermined desired temperature profile in the glass.

  3. SLUDGE BATCH 7B GLASS VARIABILITY STUDY

    SciTech Connect (OSTI)

    Johnson, F.; Edwards, T.

    2011-10-25T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable using the current Product Composition Control System (PCCS) models for durability, but were acceptable compared to the EA glass when tested. These glasses fell outside of the lower 95% confidence band, which demonstrates conservatism in the model. A few of the glasses fell outside of the upper 95% confidence band; however, these particular glasses have normalized release values that were much lower than the values of EA and should be of no practical concern. Per the requirements of the DWPF Glass Product Control Program, the PCCS durability models have been shown to be applicable to the SB7b sludge system with a range of Na{sub 2}O concentrations blended with Frits 418 or 702. PCT results from the glasses fabricated as part of the variability study were shown to be predictable by the current DWPF PCCS models and/or acceptable with respect to the EA benchmark glass regardless of thermal history or compositional view.

  4. Combined hydraulic and regenerative braking system

    DOE Patents [OSTI]

    Venkataperumal, Rama R. (Troy, MI); Mericle, Gerald E. (Mount Clemens, MI)

    1981-06-02T23:59:59.000Z

    A combined hydraulic and regenerative braking system and method for an electric vehicle, with the braking system being responsive to the applied hydraulic pressure in a brake line to control the braking of the vehicle to be completely hydraulic up to a first level of brake line pressure, to be partially hydraulic at a constant braking force and partially regenerative at a linearly increasing braking force from the first level of applied brake line pressure to a higher second level of brake line pressure, to be partially hydraulic at a linearly increasing braking force and partially regenerative at a linearly decreasing braking force from the second level of applied line pressure to a third and higher level of applied line pressure, and to be completely hydraulic at a linearly increasing braking force from the third level to all higher applied levels of line pressure.

  5. Glass ceramic-to-metal seals

    DOE Patents [OSTI]

    Not Available

    1982-04-19T23:59:59.000Z

    A glass ceramic composition prepared by subjecting a glass composition comprising, by weight, 65 to 80% SiO/sub 2/, 8 to 16% Li/sub 2/O, 2 to 8% Al/sub 2/O/sub 3/, 1 to 8% K/sub 2/O, 1 to 5% P/sub 2/O/sub 5/ and 1.5 to 7% B/sub 2/O/sub 3/, to the following processing steps of heating the glass composition to a temperature sufficient to crystallize lithium metasilicate therein, holding the glass composition at a temperature and for a time period sufficient to dissolve the lithium metasilicate therein thereby creating cristobalite nucleii, cooling the glass composition and maintaining the composition at a temperature and for a time period sufficient to recrystallize lithium metasilicate therein, and thermally treating the glass composition at a temperature and for a time period sufficient to caus growth of cristobalite and further crystallization of lithium metasilicate producing a glass ceramic composition having a specific thermal expansion coefficient and products containing said composition.

  6. Understanding Hydraulic Processes Primary Investigator: Frank H. Quinn

    E-Print Network [OSTI]

    Understanding Hydraulic Processes Primary Investigator: Frank H. Quinn Overview The hydraulic and connecting channel hydraulics models for use in Great Lakes water resource studies. 2000 Plans Niagara River Hydraulic Studies: Detailed analysis of the impact of hydraulic regime changes in the Niagara River

  7. Please cite this article in press as: I. Dejanovic, et al., Hydraulic design, technical challenges and comparison of alternative configurations of a four-product dividing wall column, Chem. Eng. Process. (2014), http://dx.doi.org/10.1016/j.cep.2014.03.009

    E-Print Network [OSTI]

    Skogestad, Sigurd

    2014-01-01T23:59:59.000Z

    Please cite this article in press as: I. Dejanovi´c, et al., Hydraulic design, technical challenges and Processing: Process Intensification journal homepage: www.elsevier.com/locate/cep Hydraulic design, technical, this paper focuses on the hydraulic design and dimensioning of a minimum energy configuration with two

  8. Advanced Reactor Thermal Hydraulic Modeling | Argonne Leadership...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Reactor Thermal Hydraulic Modeling PI Name: Paul Fischer PI Email: fischer@mcs.anl.gov Institution: Argonne National Laboratory Allocation Program: INCITE Allocation Hours...

  9. Advanced Reactor Thermal Hydraulic Modeling | Argonne Leadership...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fischer (ANL), Aleks Obabko (ANL), and Hank Childs (LBNL) Advanced Reactor Thermal Hydraulic Modeling PI Name: Paul Fischer PI Email: fischer@mcs.anl.gov Institution: Argonne...

  10. Database and Interim Glass Property Models for Hanford HLW and LAW Glasses

    SciTech Connect (OSTI)

    Vienna, John D. (BATTELLE (PACIFIC NW LAB)); Kim, Dong-Sang (BATTELLE (PACIFIC NW LAB)); Hrma, Pavel R. (BATTELLE (PACIFIC NW LAB))

    2002-09-27T23:59:59.000Z

    This report discusses a methodology for increasing the efficiency and decreasing the cost of vitrifying nuclear waste by optimizing waste-glass formulation. This methodology involves collecting and generating a property-composition database (for glass properties that determine waste-glass processability and acceptability) and relating these properties to glass composition via property-composition models. The report explains how the property-composition models are developed, fitted to data and evaluated, validated using additional data, used for glass-formulation optimization, and continuously updated in response to changes in waste-composition estimates and processing technologies. Further, the report describes a waste-glass property-composition database compiled from literature sources and presents the results from a critical evaluation and screening of the data for applicability to Hanford waste glasses. Finally, the report provides interim property-composition models for melt viscosity, liquidus temperature (with spinel and zircon primary crystalline phases), and Product Consistency Test normalized releases of B, Na, and Li. Models were fitted to a subset of the database deemed most relevant for the anticipated Hanford waste-glass composition region.

  11. Diamond turning of glass

    SciTech Connect (OSTI)

    Blackley, W.S.; Scattergood, R.O.

    1988-12-01T23:59:59.000Z

    A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

  12. Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2010-01-01T23:59:59.000Z

    300-500°C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

  13. Control rod drive hydraulic system

    DOE Patents [OSTI]

    Ose, Richard A. (San Jose, CA)

    1992-01-01T23:59:59.000Z

    A hydraulic system for a control rod drive (CRD) includes a variable output-pressure CR pump operable in a charging mode for providing pressurized fluid at a charging pressure, and in a normal mode for providing the pressurized fluid at a purge pressure, less than the charging pressure. Charging and purge lines are disposed in parallel flow between the CRD pump and the CRD. A hydraulic control unit is disposed in flow communication in the charging line and includes a scram accumulator. An isolation valve is provided in the charging line between the CRD pump and the scram accumulator. A controller is operatively connected to the CRD pump and the isolation valve and is effective for opening the isolation valve and operating the CRD pump in a charging mode for charging the scram accumulator, and closing the isolation valve and operating the CRD pump in a normal mode for providing to the CRD through the purge line the pressurized fluid at a purge pressure lower than the charging pressure.

  14. Soil Hydraulic Characteristics of a Small Southwest Oregon Watershed Following

    E-Print Network [OSTI]

    Standiford, Richard B.

    --------------------------------------------- Soil Hydraulic Characteristics of a Small Southwest by a high-intensity burn over areas of steep topography. The areal distribution of soil hydraulic of infiltration capacity, saturated hydraulic conductivity, and soil moisture characteristics. Also, measures

  15. Effective hydraulic conductivity of bounded, strongly heterogeneous porous media

    E-Print Network [OSTI]

    Tartakovsky, Daniel M.

    Effective hydraulic conductivity of bounded, strongly heterogeneous porous media Evangelos K of Arizona, Tucson Abstract. We develop analytical expressions for the effective hydraulic conductivity Ke boundaries. The log hydraulic conductivity Y forms a Gaussian, statistically homogeneous and anisotropic

  16. Hydraulic and slurry flows through a channel contraction

    E-Print Network [OSTI]

    Al Hanbali, Ahmad

    Hydraulic and slurry flows through a channel contraction Onno Bokhove o, Twente #12;Hydraulic flow through channel contraction Outline · 1. Introduction · 2. Experiments · 3. Conclusions · References ISSF 2008 University of Twente Page 2 #12;Hydraulic flow through channel contraction

  17. Scaling hydraulic properties of a macroporous soil Binayak P. Mohanty

    E-Print Network [OSTI]

    Mohanty, Binayak P.

    Scaling hydraulic properties of a macroporous soil Binayak P. Mohanty U.S. Salinity Laboratory, Riverside, California Abstract. Macroporous soils exhibit significant differences in their hydraulic properties for different pore domains. Multimodal hydraulic functions may be used to describe

  18. Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors

    SciTech Connect (OSTI)

    De Jonghe, Lutgard C.; Ray, Hannah L.; Wang, Ruigang

    2008-12-03T23:59:59.000Z

    The structure and conductivity of cerium and lanthanum phosphate glasses and glass-ceramics were investigated. The effects of varying the metal to phosphate ratio in the glasses, doping LaP3O9 glasses with Ce, and recrystallization of CeP3O9 glasses, on the glasses' microstructure and total conductivity were investigated using XRD, SEM, and AC impedance techniques. Strong increases in conductivity occurred when the glasses were recrystallized: the conductivity of a cerium metaphosphate glass increased conductivity after recrystallization from 10-7.5 S/cm to 10-6 S/cm at 400oC.

  19. Hydraulic impulse generator and frequency sweep mechanism for borehole applications

    DOE Patents [OSTI]

    Kolle, Jack J.; Marvin, Mark H.; Theimer, Kenneth J.

    2006-11-21T23:59:59.000Z

    This invention discloses a valve that generates a hydraulic negative pressure pulse and a frequency modulator for the creation of a powerful, broadband swept impulse seismic signal at the drill bit during drilling operations. The signal can be received at monitoring points on the surface or underground locations using geophones. The time required for the seismic signal to travel from the source to the receiver directly and via reflections is used to calculate seismic velocity and other formation properties near the source and between the source and receiver. This information can be used for vertical seismic profiling of formations drilled, to check the location of the bit, or to detect the presence of abnormal pore pressure ahead of the bit. The hydraulic negative pressure pulse can also be used to enhance drilling and production of wells.

  20. HGMS: Glasses and Nanocomposites for Hydrogen Storage.

    SciTech Connect (OSTI)

    Lipinska, Kris [PI] [PI; Hemmers, Oliver

    2013-02-17T23:59:59.000Z

    The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not directly address any hydrogen storage technical barriers or targets in terms of numbers. Specifically, hydrogen sorption and desorption tests or kinetics measurements were not part of the project scope. However, the insights gained from these studies could help to answer fundamental questions necessary for considering glass-based materials as hydrogen storage media and could be applied indirectly towards the DOE hydrogen storage technical targets such as system weight and volume, system cost and energy density. Such questions are: Can specific macro-crystals, proven to attract hydrogen when in a macroscopic form (bulk), be nucleated in glass matrices as nanocrystals to create two-phased materials? What are suitable compositions that enable to synthetize glass-based, two-phase materials with nanocrystals that can attract hydrogen via surface or bulk interactions? What are the limits of controlling the microstructure of these materials, especially limits for nanocrystals density and size? Finally, from a technological point of view, the fabrication of glass-derived nanocomposites that we explore is a very simple, fast and inexpensive process that does not require costly or specialized equipment which is an important factor for practical applications.

  1. Grundfos HVAC OEM Efficient water hydraulics

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    complexity ·20 years of experience in hydraulics for the Boiler System industry. ·Key success factor is our Benefits with an integrated solution #12;Heat pump unit with storage tank 1 2 Efficient water hydraulics 3 return Heatin g supply Cold wate r Hot water PRV Drain 3 way valve 1 2 3 air ventPT Grundfos flow sensor

  2. Creation of an Engineered Geothermal System through Hydraulic...

    Office of Environmental Management (EM)

    Creation of an Engineered Geothermal System through Hydraulic and Thermal Stimulation Creation of an Engineered Geothermal System through Hydraulic and Thermal Stimulation Project...

  3. Fracture Evolution Following a Hydraulic Stimulation within an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evolution Following a Hydraulic Stimulation within an EGS Reservoir Fracture Evolution Following a Hydraulic Stimulation within an EGS Reservoir Fracture Evolution Following a...

  4. An automated tool for three types of saturated hydraulic conductivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    automated tool for three types of saturated hydraulic conductivity laboratory measurements. An automated tool for three types of saturated hydraulic conductivity laboratory...

  5. Thermal Predictions of the Cooling of Waste Glass Canisters

    SciTech Connect (OSTI)

    Donna Post Guillen

    2014-11-01T23:59:59.000Z

    Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

  6. Defense HLW Glass Degradation Model

    SciTech Connect (OSTI)

    D. Strachan

    2004-10-20T23:59:59.000Z

    The purpose of this report is to document the development of a model for calculating the release rate for radionuclides and other key elements from high-level radioactive waste (HLW) glasses under exposure conditions relevant to the performance of the repository. Several glass compositions are planned for the repository, some of which have yet to be identified (i.e., glasses from Hanford and Idaho National Engineering and Environmental Laboratory). The mechanism for glass dissolution is the same for these glasses and the glasses yet to be developed for the disposal of DOE wastes. All of these glasses will be of a quality consistent with the glasses used to develop this report.

  7. Glass produced by underground nuclear explosions. [Rainier

    SciTech Connect (OSTI)

    Schwartz, L.; Piwinskii, A.; Ryerson, F.; Tewes, H.; Beiriger, W.

    1983-01-01T23:59:59.000Z

    Detonation of an underground nuclear explosive produces a strong shock wave which propagates spherically outward, vaporizing the explosive and nearby rock and melting, the surrounding rock. The vaporized material expands adiabatically, forming a cavity. As the energy is dissipated during the cavity formation process, the explosive and rock debris condense and mix with the melted rock. The melt flows to the bottom of the cavity where it is quenched by fractured rock fragments falling from above as the cavity collapses. Measurements indicate that about 740 tonnes of rock and/or soil are melted for every kiloton (10/sup 12/ calories) of explosive energy, or about 25% of the explosive energy goes to melting rock. The resulting glass composition reflects the composition of the unaltered rock with explosive debris. The appearance ranges from white pumice to dense, dark lava. The bulk composition and color vary with the amount of explosive iron incorporated into the glass. The refractory explosion products are mixed with the solidified melt, although the degree of mixing is variable. Electron microprobe studies of glasses produced by Rainier in welded tuff have produced the following results: glasses are dehydrated relative to the host media, glasses are extremely heterogeneous on a 20 ..mu..m scale, a ubiquitous feature is the presence of dark marble-cake regions in the glass, which were locally enriched in iron and may be related to the debris, optically amorphous regions provide evidence of shock melting, only limited major element redistribution and homogenization occur within the cavity.

  8. Phosphate Glasses for Vitrification of Waste with High Sulfur Content

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.; Hrma, Pavel R.; Cassingham, Nathan J.

    2002-10-31T23:59:59.000Z

    The low solubility of sulfate in silicate-based glasses, approximately 1 mass% as SO3, limits the loading of high-level waste (HLW) and low-activity waste (LAW) containing high concentrations of sulfur. Based on crucible melting studies, we have shown that the phosphate glasses may incorporate more than 5 mass% SO3; hence, the waste loading can be increased until another constraint is met, such as glass durability. A high-sulfate HLW glass has been formulated and tested to demonstrate the advantages of phosphate glasses. The effect of waste loading on the chemical durability of quenched and slow-cooled phosphate glasses was determined using the Product Consistency Test.

  9. EMPIRICAL MODEL FOR FORMULATION OF CRYSTAL-TOLERANT HLW GLASSES

    SciTech Connect (OSTI)

    KRUGER AA; MATYAS J; HUCKLEBERRY AR; VIENNA JD; RODRIGUEZ CA

    2012-03-07T23:59:59.000Z

    Historically, high-level waste (HLW) glasses have been formulated with a low liquideus temperature (T{sub L}), or temperature at which the equilibrium fraction of spinel crystals in the melt is below 1 vol % (T{sub 0.01}), nominally below 1050 C. These constraints cannot prevent the accumulation of large spinel crystals in considerably cooler regions ({approx} 850 C) of the glass discharge riser during melter idling and significantly limit the waste loading, which is reflected in a high volume of waste glass, and would result in high capital, production, and disposal costs. A developed empirical model predicts crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass, and thereby provides guidance in formulating crystal-tolerant glasses that would allow high waste loadings by keeping the spinel crystals small and therefore suspended in the glass.

  10. Thermal hydraulics development for CASL

    SciTech Connect (OSTI)

    Lowrie, Robert B [Los Alamos National Laboratory

    2010-12-07T23:59:59.000Z

    This talk will describe the technical direction of the Thermal-Hydraulics (T-H) Project within the Consortium for Advanced Simulation of Light Water Reactors (CASL) Department of Energy Innovation Hub. CASL is focused on developing a 'virtual reactor', that will simulate the physical processes that occur within a light-water reactor. These simulations will address several challenge problems, defined by laboratory, university, and industrial partners that make up CASL. CASL's T-H efforts are encompassed in two sub-projects: (1) Computational Fluid Dynamics (CFD), (2) Interface Treatment Methods (ITM). The CFD subproject will develop non-proprietary, scalable, verified and validated macroscale CFD simulation tools. These tools typically require closures for their turbulence and boiling models, which will be provided by the ITM sub-project, via experiments and microscale (such as DNS) simulation results. The near-term milestones and longer term plans of these two sub-projects will be discussed.

  11. Hydraulically amplified PZT mems actuator

    DOE Patents [OSTI]

    Miles, Robin R.

    2004-11-02T23:59:59.000Z

    A hydraulically amplified microelectromechanical systems actuator. A piece of piezoelectric material or stacked piezo bimorph is bonded or deposited as a thin film. The piece is operatively connected to a primary membrane. A reservoir is operatively connected to the primary membrane. The reservoir contains a fluid. A membrane is operatively connected to the reservoir. In operation, energizing the piezoelectric material causing the piezoelectric material to bow. Bowing of the piezoelectric material causes movement of the primary membrane. Movement of the primary membrane results in a force in being transmitted to the liquid in the reservoir. The force in the liquid causes movement of the membrane. Movement of the membrane results in an operating actuator.

  12. Nanocoatings for High-Efficiency Industrial Hydraulic and Tooling Systems

    SciTech Connect (OSTI)

    Clifton B. Higdon III

    2011-01-07T23:59:59.000Z

    Industrial manufacturing in the U.S. accounts for roughly one third of the 98 quadrillion Btu total energy consumption. Motor system losses amount to 1.3 quadrillion Btu, which represents the largest proportional loss of any end-use category, while pumps alone represent over 574 trillion BTU (TBTU) of energy loss each year. The efficiency of machines with moving components is a function of the amount of energy lost to heat because of friction between contacting surfaces. The friction between these interfaces also contributes to downtime and the loss of productivity through component wear and subsequent repair. The production of new replacement parts requires additional energy. Among efforts to reduce energy losses, wear-resistant, low-friction coatings on rotating and sliding components offer a promising approach that is fully compatible with existing equipment and processes. In addition to lubrication, one of the most desirable solutions is to apply a protective coating or surface treatment to rotating or sliding components to reduce their friction coefficients, thereby leading to reduced wear. Historically, a number of materials such as diamond-like carbon (DLC), titanium nitride (TiN), titanium aluminum nitride (TiAlN), and tungsten carbide (WC) have been examined as tribological coatings. The primary objective of this project was the development of a variety of thin film nanocoatings, derived from the AlMgB14 system, with a focus on reducing wear and friction in both industrial hydraulics and cutting tool applications. Proof-of-concept studies leading up to this project had shown that the constituent phases, AlMgB14 and TiB2, were capable of producing low-friction coatings by pulsed laser deposition. These coatings combine high hardness with a low friction coefficient, and were shown to substantially reduce wear in laboratory tribology tests. Selection of the two applications was based largely on the concept of improved mechanical interface efficiencies for energy conservation. In mobile hydraulic systems, efficiency gains through low friction would translate into improved fuel economy and fewer greenhouse gas emissions. Stationary hydraulic systems, accordingly, would consume less electrical power. Reduced tooling wear in machining operations would translate to greater operating yields, while lowering the energy consumed during processing. The AlMgB14 nanocoatings technology progressed beyond baseline laboratory tests into measurable energy savings and enhancements to product durability. Three key hydraulic markets were identified over the course of the project that will benefit from implementation: industrial vane pumps, orbiting valve-in-star hydraulic motors, and variable displacement piston pumps. In the vane pump application, the overall product efficiency was improved by as much as 11%. Similar results were observed with the hydraulic motors tested, where efficiency gains of over 10% were noted. For variable displacement piston pumps, overall efficiency was improved by 5%. For cutting tools, the most significant gains in productivity (and, accordingly, the efficiency of the machining process as a whole) were associated with the roughing and finishing of titanium components for aerospace systems. Use of the AlMgB14 nanocoating in customer field tests has shown that the coated tools were able to withstand machining rates as high as 500sfm (limited only by the substrate material), with relatively low flank wear when compared to other industrial offerings. AlMgB14 coated tools exhibited a 60% improvement over similarly applied TiAlN thin films. Furthermore, AlMgB14-based coatings in these particular tests lasted twice as long than their TiAlN counterparts at the 500sfm feed rates. Full implementation of the technology into the industrial hydraulic and cutting tool markets equates to a worldwide energy savings of 46 trillion BTU/year by 2030. U.S.-based GHG emissions associated with the markets identified would fall accordingly, dropping by as much as 50,000 tonnes annually.

  13. Modelling Glass Parisons R.M.M. Mattheij, K. Wang & H.G. ter Morsche

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    Modelling Glass Parisons R.M.M. Mattheij, K. Wang & H.G. ter Morsche EMail: mattheij@win.tue.nl Abstract In order to design better glass products, numerical modelling is essential. In this paper we focus, more specifically, on pressing forms, so called parison, appearing in the produc­ tion of packing glass

  14. Engineering Glass Passivation Layers -Model Results

    SciTech Connect (OSTI)

    Skorski, Daniel C.; Ryan, Joseph V.; Strachan, Denis M.; Lepry, William C.

    2011-08-08T23:59:59.000Z

    The immobilization of radioactive waste into glass waste forms is a baseline process of nuclear waste management not only in the United States, but worldwide. The rate of radionuclide release from these glasses is a critical measure of the quality of the waste form. Over long-term tests and using extrapolations of ancient analogues, it has been shown that well designed glasses exhibit a dissolution rate that quickly decreases to a slow residual rate for the lifetime of the glass. The mechanistic cause of this decreased corrosion rate is a subject of debate, with one of the major theories suggesting that the decrease is caused by the formation of corrosion products in such a manner as to present a diffusion barrier on the surface of the glass. Although there is much evidence of this type of mechanism, there has been no attempt to engineer the effect to maximize the passivating qualities of the corrosion products. This study represents the first attempt to engineer the creation of passivating phases on the surface of glasses. Our approach utilizes interactions between the dissolving glass and elements from the disposal environment to create impermeable capping layers. By drawing from other corrosion studies in areas where passivation layers have been successfully engineered to protect the bulk material, we present here a report on mineral phases that are likely have a morphological tendency to encrust the surface of the glass. Our modeling has focused on using the AFCI glass system in a carbonate, sulfate, and phosphate rich environment. We evaluate the minerals predicted to form to determine the likelihood of the formation of a protective layer on the surface of the glass. We have also modeled individual ions in solutions vs. pH and the addition of aluminum and silicon. These results allow us to understand the pH and ion concentration dependence of mineral formation. We have determined that iron minerals are likely to form a complete incrustation layer and we plan to look more closely at Vivianite [Fe3(PO4)2-8(H2O)] and Siderite [FeCO3] in the next stage of the project.

  15. Glass, Brian 1 BRIAN DANIEL GLASS, M.A.

    E-Print Network [OSTI]

    Maddox, W. Todd

    Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Texas at Austin Austin, TX 78712 (512) 232-2883 e-mail: glass@mail.utexas.edu EDUCATION 2006 ­ Cognitive include: Designing and constructing experiments, statistical #12;Glass, Brian 2 analysis, manuscript

  16. Glass, Brian 1 BRIAN DANIEL GLASS, M.A.

    E-Print Network [OSTI]

    Maddox, W. Todd

    Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Designing and constructing, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D., Chotibut, T

  17. Glass, Brian 1 BRIAN DANIEL GLASS, M.A.

    E-Print Network [OSTI]

    Maddox, W. Todd

    Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Categorization and Decision Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Programming, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D

  18. Selected factors influencing GCL hydraulic conductivity

    SciTech Connect (OSTI)

    Petrov, R.J. [Trow Consulting Engineers Ltd., Brampton, Ontario (Canada); Rowe, R.K.; Quigley, R.M. [Univ. of Western Ontario, London, Ontario (Canada)

    1997-08-01T23:59:59.000Z

    A series of confined swell and hydraulic conductivity tests were conducted on a needle-punched geosynthetic clay liner (GCL) with water as the hydrating medium and reference permeant. Increases in the static confining stress and the needle-punching both restricted GCL swell and contributed to lower bulk GCL void ratios and hence significantly lower hydraulic conductivity values. A well defined linear-log relationship is found between the bulk void ratio and hydraulic conductivity. The number of pore volumes of permeant flow and consequently the level of chemical equilibrium is shown to have a significant effect on the hydraulic conductivity. It is shown that there is a decrease in hydraulic conductivity for small amounts of permeant flow for all ethanol/water mixtures examined. At or near chemical equilibrium, low concentration mixtures (25 and 50% ethanol) continued to produce relative decreases in GCL hydraulic conductivity due to the increased viscosity of the permeant; however, highly concentrated mixtures (75 and 100% ethanol) produced relative increases in GCL hydraulic conductivity arising from double layer contraction. The implications are discussed.

  19. Overview of Energy Efficiency for Glass Furnace

    E-Print Network [OSTI]

    Banerjee, Rangan

    ,Particulates (Environmental norms) Global competitiveness #12;3 April, 2006 4Source: www.oilnergy.com Crude Oil Price #12, 2006 8 Energy Consumption in Glass Plant Melting 75% Forehearth 7% Anneling 4% Other 10% Printing Energy Consumption Specific Energy Consumption (SEC)­ Energy Consumption per unit of product output Units

  20. Bubble visualization in a simulated hydraulic jump

    E-Print Network [OSTI]

    Witt, Adam; Shen, Lian

    2013-01-01T23:59:59.000Z

    This is a fluid dynamics video of two- and three-dimensional computational fluid dynamics simulations carried out at St. Anthony Falls Laboratory. A transient hydraulic jump is simulated using OpenFOAM, an open source numerical solver. A Volume of Fluid numerical method is employed with a realizable k-epsilon turbulence model. The goal of this research is to model the void fraction and bubble size in a transient hydraulic jump. This fluid dynamics video depicts the air entrainment characteristics and bubble behavior within a hydraulic jump of Froude number 4.82.

  1. 25 kWe solar thermal stirling hydraulic engine system: Final conceptual design report

    SciTech Connect (OSTI)

    Not Available

    1988-01-01T23:59:59.000Z

    This report documents the conceptual design and analysis of a solar thermal free-piston Stirling hydraulic engine system designed to deliver 25 kWe when coupled to the 11-meter Test Bed Concentrator at Sandia National Laboratories. A manufacturing cost assessment for 10,000 units per year was made by Pioneer Engineering and Manufacturing. The design meets all program objectives including a 60,000-hr design life, dynamic balancing, fully automated control, >33.3% overall system efficiency, properly conditioned power, maximum utilization of annualized insolation, and projected production costs of $300/kW. The system incorporates a simple, rugged, reliable pool boiler reflux heat pipe to transfer heat from the solar receiver to the Stirling engine. The free-piston engine produces high-pressure hydraulic flow which powers a commercial hydraulic motor that, in turn, drives a commercial rotary induction generator. The Stirling hydraulic engine uses hermetic bellows seals to separate helium working gas from hydraulic fluid which provides hydrodynamic lubrication to all moving parts. Maximum utilization of highly refined, field proven commercial components for electric power generation minimizes development cost and risk. The engine design is based on a highly refined Stirling hydraulic engine developed over 20 years as a fully implantable artificial heart power source. 4 refs., 19 figs., 3 tabs.

  2. Expanded High-Level Waste Glass Property Data Development: Phase I

    SciTech Connect (OSTI)

    Schweiger, Michael J.; Riley, Brian J.; Crum, Jarrod V.; Hrma, Pavel R.; Rodriguez, Carmen P.; Arrigoni, Benjamin M.; Lang, Jesse B.; Kim, Dong-Sang; Vienna, John D.; Raszewski, F. C.; Peeler, David K.; Edwards, Tommy B.; Best, D. R.; Reamer, Irene A.; Riley, W. T.; Simmons, P. T.; Workman, R. J.

    2011-01-21T23:59:59.000Z

    Two separate test matrices were developed as part if the EM-21 Glass Matrix Crucible Testing. The first matrix, developed using a single component-at-a-time design method and covering glasses of interest primarily to Hanford, is addressed in this data package. This data package includes methods and results from glass fabrication, chemical analysis of glass compositions, viscosity, electrical conductivity, liquidus temperature, canister centerline cooling, product consistency testing, and the toxicity characteristic leach procedure.

  3. Baseline LAW Glass Formulation Testing

    SciTech Connect (OSTI)

    Kruger, Albert A. [USDOE Office of River Protection, Richland, WA (United States); Mooers, Cavin [The Catholic University of America, Washington, DC (United States). Vitreous State Lab.; Bazemore, Gina [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Pegg, Ian L. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Hight, Kenneth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Lai, Shan Tao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Buechele, Andrew [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Rielley, Elizabeth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Gan, Hao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Muller, Isabelle S. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Cecil, Richard [The Catholic University of America, Washington, DC (United States). Vitreous State Lab

    2013-06-13T23:59:59.000Z

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  4. Exploring the physicochemical processes that govern hydraulic fracture through laboratory

    E-Print Network [OSTI]

    Belmonte A; Connelly P

    ) containing model boreholes as an analog to hydraulic fracturing with various fracture-driving fluids. The

  5. Analysis of Small-Scale Hydraulic Systems Jicheng Xia

    E-Print Network [OSTI]

    Durfee, William K.

    power density in a hydraulic system are the design the containing structure and the seals. There has, MN, 55455 Email: wkdurfee@umn.edu We investigated small-scale hydraulic power system using a system- mine whether the high power density advantage of hydraulic power system holds at small sizes. Hydraulic

  6. Fault Detection, Identification and Accommodation for an Electro-hydraulic

    E-Print Network [OSTI]

    Yao, Bin

    Fault Detection, Identification and Accommodation for an Electro-hydraulic System: An Adaptive in electro-hydraulic systems. It is well known fact that any realistic model of a hydraulic system suffers, such a scheme becomes a natural choice for designing robust fault detection algorithms for electro-hydraulic

  7. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Volin, Kenneth J. (Fort Collins, CO)

    1984-01-01T23:59:59.000Z

    An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  8. An experimental and theoretical study of the cooling of a thin glass fiber during the formation process

    E-Print Network [OSTI]

    Xiong, Daxi, 1970-

    2002-01-01T23:59:59.000Z

    The cooling of a thin, moving glass fiber was studied through both experiments and theoretical method in the present thesis. An experimental system was built at a laboratory scale, which included a glass fiber production ...

  9. Acoustic Character Of Hydraulic Fractures In Granite

    E-Print Network [OSTI]

    Paillet, Frederick I.

    1983-01-01T23:59:59.000Z

    Hydraulic fractures in homogeneous granitic rocks were logged with conventional acoustic-transit-time, acoustic-waveform, and acoustic-televiewer logging systems. Fractured intervals ranged in depth from 45 to 570m. and ...

  10. Gas condensate damage in hydraulically fractured wells

    E-Print Network [OSTI]

    Adeyeye, Adedeji Ayoola

    2004-09-30T23:59:59.000Z

    Company. The well was producing a gas condensate reservoir and questions were raised about how much drop in flowing bottomhole pressure below dewpoint would be appropriate. Condensate damage in the hydraulic fracture was expected to be of significant...

  11. Geomechanical review of hydraulic fracturing technology

    E-Print Network [OSTI]

    Arop, Julius Bankong

    2013-01-01T23:59:59.000Z

    Hydraulic fracturing as a method for recovering unconventional shale gas has been around for several decades. Significant research and improvement in field methods have been documented in literature on the subject. The ...

  12. Self-potential observations during hydraulic fracturing

    E-Print Network [OSTI]

    Moore, Jeffrey R.; Glaser, Steven D.

    2008-01-01T23:59:59.000Z

    during hydraulic fracturing Moore and Glaser, in press JGR,press JGR, B – 2006JB004373 where m is the average hydraulichydraulic fracturing with water. Moore and Glaser, in press

  13. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2013-01-01T23:59:59.000Z

    hydraulic cement from spent oil shale," Vol. 10, No. 4, p.J. W. , "Colorado's primary oil shale resource for verticalSimulated effects of oil-shale development on the hydrology

  14. Advanced Technology for Railway Hydraulic Hazard Forecasting

    E-Print Network [OSTI]

    Huff, William Edward 1988-

    2012-12-05T23:59:59.000Z

    Page 1.1 Map of Total Railway Hydraulic Hazard Events from 1982-2011 ............ 2 1.2 90 mi Effective Radar Coverage for Reliable Rainfall Rate Determination ....................................................................... 5 3... Administration (FRA) for the period of 1982-2011. This data was compiled from the FRA Office of Safety Analysis website (FRA, 2011). A map of the railway hydraulic hazard events over the same time period is displayed in Figure 1.1. Table 1.1. U.S. Railway...

  15. Appendix A. Hydraulic Properties Statistics Tables Table A1. Hydraulic properties statistics for the alluvium (Stephens et al.).

    E-Print Network [OSTI]

    A-1 Appendix A. Hydraulic Properties Statistics Tables Table A1. Hydraulic properties statistics Deviation .1708 4.274 28.95 Harmonic Mean Number of Observations 9 8 8 2 2 2 2 2 Table A2. Hydraulic.3×10-5 Number of Observations 10 10 10 34 34 4 4 4 #12;A-2 Table A3. Hydraulic properties statistics

  16. P. Cruiziat et al.Hydraulic architecture of trees Hydraulic architecture of trees: main concepts and results

    E-Print Network [OSTI]

    Boyer, Edmond

    P. Cruiziat et al.Hydraulic architecture of trees Review Hydraulic architecture of trees: main March 2001; accepted 13 February 2002) Abstract ­ Since about twenty years, hydraulic architecture (h. This review encompasses the main concepts and results concerning the hydraulic of architecture of trees. After

  17. Advanced Hydraulic Fracturing Technology for Unconventional Tight Gas Reservoirs

    SciTech Connect (OSTI)

    Stephen Holditch; A. Daniel Hill; D. Zhu

    2007-06-19T23:59:59.000Z

    The objectives of this project are to develop and test new techniques for creating extensive, conductive hydraulic fractures in unconventional tight gas reservoirs by statistically assessing the productivity achieved in hundreds of field treatments with a variety of current fracturing practices ranging from 'water fracs' to conventional gel fracture treatments; by laboratory measurements of the conductivity created with high rate proppant fracturing using an entirely new conductivity test - the 'dynamic fracture conductivity test'; and by developing design models to implement the optimal fracture treatments determined from the field assessment and the laboratory measurements. One of the tasks of this project is to create an 'advisor' or expert system for completion, production and stimulation of tight gas reservoirs. A central part of this study is an extensive survey of the productivity of hundreds of tight gas wells that have been hydraulically fractured. We have been doing an extensive literature search of the SPE eLibrary, DOE, Gas Technology Institute (GTI), Bureau of Economic Geology and IHS Energy, for publicly available technical reports about procedures of drilling, completion and production of the tight gas wells. We have downloaded numerous papers and read and summarized the information to build a database that will contain field treatment data, organized by geographic location, and hydraulic fracture treatment design data, organized by the treatment type. We have conducted experimental study on 'dynamic fracture conductivity' created when proppant slurries are pumped into hydraulic fractures in tight gas sands. Unlike conventional fracture conductivity tests in which proppant is loaded into the fracture artificially; we pump proppant/frac fluid slurries into a fracture cell, dynamically placing the proppant just as it occurs in the field. From such tests, we expect to gain new insights into some of the critical issues in tight gas fracturing, in particular the roles of gel damage, polymer loading (water-frac versus gel frac), and proppant concentration on the created fracture conductivity. To achieve this objective, we have designed the experimental apparatus to conduct the dynamic fracture conductivity tests. The experimental apparatus has been built and some preliminary tests have been conducted to test the apparatus.

  18. Hydraulic multistage turbine of turbodrill

    SciTech Connect (OSTI)

    Brudny-Chelyadinov, S.J.; Budyansky, V.S.; Filimonov, V.A.

    1987-06-30T23:59:59.000Z

    This patent describes a turbodrill provided with a rock destruction tool for drilling wells, a hydraulic turbine for driving the rock destruction tool under the action of a drilling fluid, comprising: identical stages formed by one stator and one rotor; the stator of one stage; a spacing sleeve of the stator; a ring of the stator incorporating: a hub; a blading formed by a multitude of blades equally spaced on the inside of the hub of the stator ring; a rim secured to the blades at the tips away from the hub, and a flow channel for passing the drilling fluid arranged between the hub and the rim, and accommodating the blading; blades of the blading which, at least in a number of the stator rings from the plurality of stages, are made with an angle of curvature of the chamber line being greater than an acute angle formed by the tangent to this line at the exit of the blading and the axis of drilling fluid flow; the rotor of one state arranged coaxially with the stator; a spacing sleeve of the rotor; and a ring of the rotor.

  19. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25T23:59:59.000Z

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  20. DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION

    SciTech Connect (OSTI)

    Adamson, D; Bradley Pickenheim, B

    2008-11-24T23:59:59.000Z

    DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point that the test apparatus had to be disassembled to dislodge the plugs created in the system.

  1. Glass for low-cost photovoltaic solar arrays

    SciTech Connect (OSTI)

    Bouquet, F.L.

    1980-02-01T23:59:59.000Z

    In photovoltaic systems, the encapsulant material that protects the solar cells should be highly transparent and very durable. Glass satisfies these two criteria and is considered a primary candidate for low-cost, photovoltaic encapsulation systems. In this report, various aspects of glass encapsulation are treated that are important for the designer of photovoltaic systems. Candidate glasses and available information defining the state of the art of glass encapsulation materials and processes for automated, high volume production of terrestrial photovoltaic devices and related applications are presented. The criteria for consideration of the glass encapsulation systems were based on the LSA (Low-cost Solar Array) Project goals for arrays: (a) a low degradation rate, (b) high reliability, (c) an efficiency greater than 10 percent, (d) a total array price less than $500/kW, and (e) a production capacity of 5 x 10/sup 5/ kW/yr. The glass design areas treated herein include the types of glass, sources and costs, physical properties and glass modifications, such as antireflection coatings. 78 references.

  2. Coordinated studies in support of hydraulic fracturing of coalbed methane. Annual report, January 1993-April 1994

    SciTech Connect (OSTI)

    Penny, G.S.; Conway, M.W.

    1994-08-01T23:59:59.000Z

    The production of natural gas from coal typically requires stimulation in the form of hydraulic fracturing and, more recently, cavity completions. The results of hydraulic fracturing treatments have ranged from extremely successful to less than satisfactory. The purpose of this work is to characterize common and potential fracturing fluids in terms of coal-fluid interactions to identify reasons for less than satisfactory performance and to ultimately devise alternative fluids and treatment procedures to optimize production following hydraulic fracturing. The laboratory data reported herein has proven helpful in designing improved hydraulic fracturing treatments and remedial treatments in the Black Warrior Basin. Acid inhibitors, scale inhibitors, additives to improve coal relative permeability to gas, and non-damaging polymer systems for hydraulic fracturing have been screened in coal damage tests. The optimum conditions for creating field-like foams in the laboratory have been explored. Tests have been run to identify minimum polymer and surfactant concentrations for applications of foam in coal. The roll of 100 mesh sand in controlling leakoff and impairing conductivity in coal has been investigated. The leakoff and proppant transport of fluids with breaker has been investigated and recommendations have been made for breaker application to minimize damage potential in coal. A data base called COAL`S has been created in Paradox (trademark) for Windows to catalogue coalbed methane activities in the Black Warrior and San Juan Basins.

  3. The Seduction of the Glass Box

    E-Print Network [OSTI]

    Ackerly, Katie

    2013-01-01T23:59:59.000Z

    Visual, and Spatial Effects of Glass, New York: PrincetonBauten, Perspektiven (Glass Architects: Concepts, Buildings,Taking a Second Look: Glass Pavilion at Broadfield House in

  4. Glass blowing on a wafer level

    E-Print Network [OSTI]

    Eklund, E. Jesper; Shkel, Andrei M.

    2007-01-01T23:59:59.000Z

    E. Shelby, Introduction to Glass Science and Technology. :Properties of Corning Glasses [Online]. Available: http://1981. [15] R. H. Doremus, Glass Science. New York: Wiley,

  5. Comparison of glass surfaces as a countertop material to existing surfaces

    SciTech Connect (OSTI)

    Turo, Laura A.; Winschell, Abigail E.

    2011-09-01T23:59:59.000Z

    Gleen Glass, a small production glass company that creates countertops, was selected for the Technology Assistance Program through Pacific Northwest National Laboratory. Gleen Glass was seeking material property analysis comparing glass as a countertop material to current surfaces (i.e. marble, granite and engineered stone). With samples provided from Gleen Glass, testing was done on granite, marble, and 3 different glass surfaces ('Journey,' 'Pebble,' and 'Gleen'). Results showed the glass surfaces have a lower density, lower water absorption, and are stronger in compressive and flexural tests as compared to granite and marble. Thermal shock tests showed the glass failed when objects with a high thermal mass are placed directly on them, whereas marble and granite did not fracture under these conditions.

  6. Glass matrix armor

    DOE Patents [OSTI]

    Calkins, Noel C. (Los Alamos, NM)

    1991-01-01T23:59:59.000Z

    An armor system which utilizes glass. A plurality of constraint cells are mounted on a surface of a substrate, which is metal armor plate or a similar tough material, such that the cells almost completely cover the surface of the substrate. Each constraint cell has a projectile-receiving wall parallel to the substrate surface and has sides which are perpendicular to and surround the perimeter of the receiving wall. The cells are mounted such that, in one embodiment, the substrate surface serves as a sixth side or closure for each cell. Each cell has inside of it a plate, termed the front plate, which is parallel to and in contact with substantially all of the inside surface of the receiving wall. The balance of each cell is completely filled with a projectile-abrading material consisting of glass and a ceramic material and, in certain embodiments, a polymeric material. The glass may be in monolithic form or particles of ceramic may be dispersed in a glass matrix. The ceramic material may be in monolithic form or may be in the form of particles dispersed in glass or dispersed in said polymer.

  7. IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

    2012-03-19T23:59:59.000Z

    Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

  8. Nuclear waste vitrification: electric melting and glass formulation

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2007-07-10T23:59:59.000Z

    The Hanford Site contains 177 underground tanks with radioactive waste that will be vitrified, i.e., immobilized by converting it to glass in electric melters. After pretreatment, the waste slurry will be mixed with glass-forming minerals, and the resulting feed will be charged into the melter. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical properties that guarantee that the glass is easily made and resists environmental degradation. On heating, the feed undergoes complex reactions. The large variability of waste compositions presents numerous technological challenges: undesirable insoluble solids and molten salts may segregate; foam may hinder heat transfer and slows down the process; and on cooling, the glass may precipitate crystalline phases.

  9. Development of a hydraulic borehole seismic source

    SciTech Connect (OSTI)

    Cutler, R.P.

    1998-04-01T23:59:59.000Z

    This report describes a 5 year, $10 million Sandia/Industry project to develop an advanced borehole seismic source for use in oil and gas exploration and production. The development Team included Sandia, Chevron, Amoco, Conoco, Exxon, Raytheon, Pelton, and GRI. The seismic source that was developed is a vertically oriented, axial point force, swept frequency, clamped, reaction-mass vibrator design. It was based on an early Chevron prototype, but the new tool incorporates a number of improvements which make it far superior to the original prototype. The system consists of surface control electronics, a special heavy duty fiber optic wireline and draw works, a cablehead, hydraulic motor/pump module, electronics module, clamp, and axial vibrator module. The tool has a peak output of 7,000 lbs force and a useful frequency range of 5 to 800 Hz. It can operate in fluid filled wells with 5.5-inch or larger casing to depths of 20,000 ft and operating temperatures of 170 C. The tool includes fiber optic telemetry, force and phase control, provisions to add seismic receiver arrays below the source for single well imaging, and provisions for adding other vibrator modules to the tool in the future. The project yielded four important deliverables: a complete advanced borehole seismic source system with all associated field equipment; field demonstration surveys funded by industry showing the utility of the system; industrial sources for all of the hardware; and a new service company set up by their industrial partner to provide commercial surveys.

  10. The Political History of Hydraulic Fracturing’s Expansion Across the West

    E-Print Network [OSTI]

    Forbis, Robert E.

    2014-01-01T23:59:59.000Z

    Political History of Hydraulic Fracturing’s Expansion AcrossPolitical History of Hydraulic Fracturing’s Expansion Acrosss use of the hydraulic fracturing development process.

  11. Acoustic Emission in a Fluid Saturated Hetergeneous Porous Layer with Application to Hydraulic Fracture

    E-Print Network [OSTI]

    Nelson, J.T.

    2009-01-01T23:59:59.000Z

    responses during hydraulic fracturing, and aid developmentFracture Monitoring Hydraulic fracturing is a method forfluids" used for hydraulic fracturing, the above frequencies

  12. HYDRAULIC FRACTURING AND OVERCORING STRESS MEASUREMENTS IN A DEEP BOREHOLE AT THE STRIPA TEST MINE, SWEDEN

    E-Print Network [OSTI]

    Doe, T.

    2010-01-01T23:59:59.000Z

    u l y 2 , 1 9 8 1 HYDRAULIC FRACTURING AND OVERCORING STRESSI nun LBL-12478 HYDRAULIC FRACTURING AND OVERCORING STRESSthe calculated stress. n HYDRAULIC FRACTURING EQUIPMENT AND

  13. Modeling of Glass Making Processes for Improved Efficiency

    SciTech Connect (OSTI)

    Thomas P. Seward III

    2003-03-31T23:59:59.000Z

    The overall goal of this project was to develop a high-temperature melt properties database with sufficient reliability to allow mathematical modeling of glass melting and forming processes for improved product quality, improved efficiency and lessened environmental impact. It was initiated by the United States glass industry through the NSF Industry/University Center for Glass Research (CGR) at Alfred University [1]. Because of their important commercial value, six different types/families of glass were studied: container, float, fiberglass (E- and wool-types), low-expansion borosilicate, and color TV panel glasses. CGR member companies supplied production-quality glass from all six families upon which we measured, as a function of temperature in the molten state, density, surface tension, viscosity, electrical resistivity, infrared transmittance (to determine high temperature radiative conductivity), non-Newtonian flow behavior, and oxygen partial pres sure. With CGR cost sharing, we also studied gas solubility and diffusivity in each of these glasses. Because knowledge of the compositional dependencies of melt viscosity and electrical resistivity are extremely important for glass melting furnace design and operation, these properties were studied more fully. Composition variations were statistically designed for all six types/families of glass. About 140 different glasses were then melted on a laboratory scale and their viscosity and electrical resistivity measured as a function of temperature. The measurements were completed in February 2003 and are reported on here. The next steps will be (1) to statistically analyze the compositional dependencies of viscosity and electrical resistivity and develop composition-property response surfaces, (2) submit all the data to CGR member companies to evaluate the usefulness in their models, and (3) publish the results in technical journals and most likely in book form.

  14. Glass | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdf Flash2006-52.pdf0.pdfDepartmentCounselGlass Coating Makes Solar Panels MoreGlass

  15. Coordinated studies in support of hydraulic fracturing of coalbed methane. Annual report, November 1991-December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-04-01T23:59:59.000Z

    The purpose of the work is to characterize common and potential fracturing fluids in terms of coal-fluid interactions to identify reasons for less than satisfactory performance and to ultimately devise alternative fluids and treatment procedures to optimize production following hydraulic fracturing. The laboratory data reported herein has proven helpful in designing improved hydraulic fracturing treatments and remedial treatments in the Black Warrior Basin. Acid inhibitors, scale inhibitors, additives to improve coal relative permeability to gas, and non-damaging polymer systems for hydraulic fracturing have been screened in coal damage tests. The optimum conditions for creating field-like foams in the laboratory have been explored. Tests have been run to identify minimum polymer and surfactant concentrations for applications of foam in coal. The roll of 100 mesh sand in controlling leakoff and impairing conductivity in coal has been investigated.

  16. Universal asymptotic umbrella for hydraulic fracture modeling

    E-Print Network [OSTI]

    Linkov, Aleksandr M

    2014-01-01T23:59:59.000Z

    The paper presents universal asymptotic solution needed for efficient modeling of hydraulic fractures. We show that when neglecting the lag, there is universal asymptotic equation for the near-front opening. It appears that apart from the mechanical properties of fluid and rock, the asymptotic opening depends merely on the local speed of fracture propagation. This implies that, on one hand, the global problem is ill-posed, when trying to solve it as a boundary value problem under a fixed position of the front. On the other hand, when properly used, the universal asymptotics drastically facilitates solving hydraulic fracture problems (both analytically and numerically). We derive simple universal asymptotics and comment on their employment for efficient numerical simulation of hydraulic fractures, in particular, by well-established Level Set and Fast Marching Methods.

  17. Hydraulic dredging, a sediment removal technique

    SciTech Connect (OSTI)

    Spotts, J.W.

    1980-12-01T23:59:59.000Z

    Sediment was successfully removed from a Peabody Coal Company pond near Macon, Missouri, by a Mud Cat Model SP-810 hydraulic dredge. Previous attempts using land-based equipment had been unsatisfactory. The hydraulic-powered auger and submerged pump easily removed 882 m/sup 3/ (1154 yd/sup 3/) and pumped the slurry a distance of 305 m (1000 ft) to a disposal area. The hydraulic dredge was more effective and cheaper to operate than land-based equipment. The dredge cost was $1.31/m/sup 3/ ($1.00/yd/sup 3/), the dragline cost was $6.54/m/sup 3/ ($5.00/yd/sup 3/) and the front-end loader cost was $15.70/m/sup 3/ ($12.00/yd/sup 3/), under optimum conditions.

  18. The hydraulic jump as a white hole

    E-Print Network [OSTI]

    G. E. Volovik

    2005-10-21T23:59:59.000Z

    In the geometry of the circular hydraulic jump, the velocity of the liquid in the interior region exceeds the speed of capillary-gravity waves (ripplons), whose spectrum is `relativistic' in the shallow water limit. The velocity flow is radial and outward, and thus the relativistic ripplons cannot propagating into the interior region. In terms of the effective 2+1 dimensional Painleve-Gullstrand metric appropriate for the propagating ripplons, the interior region imitates the white hole. The hydraulic jump represents the physical singularity at the white-hole horizon. The instability of the vacuum in the ergoregion inside the circular hydraulic jump and its observation in recent experiments on superfluid 4He by E. Rolley, C. Guthmann, M.S. Pettersen and C. Chevallier in physics/0508200 are discussed.

  19. Composition/Property Relationships for the Phase 2 Am-Cm Glass Variability Study

    SciTech Connect (OSTI)

    Peeler, D.

    2000-06-09T23:59:59.000Z

    The objective of this research was to evaluate the effect of compositional uncertainties on the primary processing and product performance criteria for potential glasses to stabilize the Tank 17.1 Am-Cm solution and to identify the AGCR in which glasses simultaneously meet both process and product performance criteria as defined for Phase 2.

  20. Radionuclide decay effects on waste glass corrosion and weathering

    SciTech Connect (OSTI)

    Wronkiewicz, D.J.

    1993-12-31T23:59:59.000Z

    The release of glass components into solution, including radionuclides, may be influenced by the presence of radiolytically produced nitric acid, carboxylic acid, and transient water dissociation products such as {center_dot}OH and O{sub 2}{sup {minus}}. Under batch test conditions, glass corrosion has been shown to increase up to a maximum of three-to five-fold in irradiated tests relative to nonirradiated tests, while in other studies the presence of radiolytic products has actually decreased glass corrosion rates. Bicarbonate groundwaters will buffer against pH decreases and changes in corrosion rates. Under high surface area-to-solution volume (S/V) conditions, the bicarbonate buffering reservoir may be quickly overwhelmed by radiolytic acids that are concentrated in the thin films of water contacting the samples. Glass reaction rates have been shown to increase up to 10-to-15-fold due to radiation exposure under high S/V conditions. Radiation damage to solid glass materials results in bond damage and atomic displacements. This type of damage has been shown to increase the release rates of glass components up to four-fold during subsequent corrosion tests, although under actual disposal conditions, glass annealing processes may negate the solid radiation damage effects.

  1. Laboratory Waste Disposal HAZARDOUS GLASS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Laboratory Waste Disposal HAZARDOUS GLASS Items that could cut or puncture skin or trash- can without any treatment. Hazardous Glass and Plastic: Items that can puncture, cut or scratch if disposed of in normal trash containers. Pasteur pipettes Other pipettes and tips (glass or plastic) Slides and cover

  2. The Color Glass Condensate

    E-Print Network [OSTI]

    F. Gelis; E. Iancu; J. Jalilian-Marian; R. Venugopalan

    2010-02-01T23:59:59.000Z

    We provide a broad overview of the theoretical status and phenomenological applications of the Color Glass Condensate effective field theory describing universal properties of saturated gluons in hadron wavefunctions that are extracted from deeply inelastic scattering and hadron-hadron collision experiments at high energies.

  3. Hydraulic Interaction between Geosynthetic Drainage Layers and Unsaturated Low Plasticity Clay

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    1 Hydraulic Interaction between Geosynthetic Drainage Layers and Unsaturated Low Plasticity Clay of soil density on the hydraulic interaction between unsaturated, low plasticity clay and geosynthetic drainage layers. The hydraulic interaction was evaluated using the system hydraulic conductivity, moisture

  4. PARTITIONED ANALYSIS FOR DIMENSIONALLY-HETEROGENEOUS HYDRAULIC NETWORKS*

    E-Print Network [OSTI]

    Buscaglia, Gustavo C.

    PARTITIONED ANALYSIS FOR DIMENSIONALLY-HETEROGENEOUS HYDRAULIC NETWORKS* JORGE S. LEIVA , PABLO J for which this procedure is envisaged arises when modeling hydraulic networks in which complex and simple

  5. Simulation of Hydraulic Fractures and their Interactions with Natural Fractures

    E-Print Network [OSTI]

    Sesetty, Varahanaresh

    2012-10-19T23:59:59.000Z

    Modeling the stimulated reservoir volume during hydraulic fracturing is important to geothermal and petroleum reservoir stimulation. The interaction between a hydraulic fracture and pre-existing natural fractures exerts significant control...

  6. Effectiveness of microseismic monitoring for optimizing hydraulic fracturing in California

    E-Print Network [OSTI]

    Alampi, Ann M

    2014-01-01T23:59:59.000Z

    Hydraulic fracturing has fundamentally changed the oil and gas industry in the past 10 years. Bakersfield, California provides a unique case study because steam injection, a type of hydraulic fracturing, has been used there ...

  7. Marcellus Shale Drilling and Hydraulic Fracturing; Technicalities and

    E-Print Network [OSTI]

    Jiang, Huiqiang

    Pipe · Air Rotary Drilling Rig · Hydraulic Rotary Drilling Rig ­ Barite/Bentonite infused drilling muds

  8. Vehicle hydraulic system that provides heat for passenger compartment

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2001-01-01T23:59:59.000Z

    A vehicle includes a vehicle housing which defines a passenger compartment. Attached to the vehicle housing is a hydraulic system, that includes a hydraulic fluid which flows through at least one passageway within the hydraulic system. Also attached to the vehicle housing is a passenger compartment heating system. The passenger compartment heating system includes a heat exchanger, wherein a portion of the heat exchanger is a segment of the at least one passageway of the hydraulic system.

  9. Coupling schemes for modeling hydraulic fracture propagation using the XFEM

    E-Print Network [OSTI]

    Peirce, Anthony

    Coupling schemes for modeling hydraulic fracture propagation using the XFEM Elizaveta Gordeliy of hydraulic fractures in an elastic medium. With appropriate enrichment, the XFEM resolves the Neumann(h) accuracy. For hydraulic fracture problems with a lag separating the uid front from the fracture front, we

  10. Role of seepage forces on hydraulic fracturing and failure patterns

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Role of seepage forces on hydraulic fracturing and failure patterns Alexander Rozhko Thesis September 2007 #12;ii Role of seepage forces on hydraulic fracturing and failure patterns Abstract. The mechanical role of seepage forces on hydraulic fracturing and failure patterns was studied both

  11. Control of a Hydraulically-Powered, Differential Lift Project Proposal

    E-Print Network [OSTI]

    Control of a Hydraulically-Powered, Differential Lift Project Proposal Written by Thomas Johnson ME6401: Linear Control Submitted to Dr. Wayne Book 9/11/06 #12;A hydraulically-powered, differential lift representation of a differential lift can be viewed in Figure 1. Figure 1. Hydraulically-powered, differential

  12. Viscous Undular Hydraulic Jumps of Moderate Reynolds number

    E-Print Network [OSTI]

    Shyamasundar, R.K.

    Viscous Undular Hydraulic Jumps of Moderate Reynolds number Ratul Dasgupta I will present some results on undular hydraulic jumps occurring in a two bores (in rivers), where the interface remains horizontal, the moderate Reynolds hydraulic jump shows a linear increase in height due to viscosity

  13. Reply to Davies: Hydraulic fracturing remains a possible mechanism for

    E-Print Network [OSTI]

    Jackson, Robert B.

    LETTER Reply to Davies: Hydraulic fracturing remains a possible mechanism for observed methane in aquifers overlying the Marcellus formation but asserts that we prematurely ascribed its cause to hydraulic mechanisms were leaky gas well casings and the possibility that hydraulic fracturing might generate new

  14. A COUPLED HYDRAULIC AND ELECTRICAL STRESS DETERMINATION TECHNIQUE

    E-Print Network [OSTI]

    A COUPLED HYDRAULIC AND ELECTRICAL STRESS DETERMINATION TECHNIQUE Mai Linh DOAN Département de Alps. The Hydraulic Tests on Preexisting Fractures (HTPF) method was chosen for it provides means to determine the complete stress tensor. The campaign was performed with a specific probe, coupling hydraulic

  15. System Identification and Modelling of a High Performance Hydraulic Actuator

    E-Print Network [OSTI]

    Hayward, Vincent

    System Identification and Modelling of a High Performance Hydraulic Actuator Benoit Boulet, Laeeque with the experimental identification and modelling of the nonlinear dynamics ofa high performance hydraulic actuator. The actuator properties and performance are also discussed. 1 Introduction Hydraulic actuation used to be

  16. Evaluation of Hydraulic Efficiency of Disinfection Systems Based on

    E-Print Network [OSTI]

    Evaluation of Hydraulic Efficiency of Disinfection Systems Based on Residence Time Distribution. Accepted November 9, 2010. Hydraulic efficiency is a vital component in evaluating the disinfection to overestimate, severely in some instances, the actual hydraulic efficiency as obtained from the system's flow

  17. HYDRAULIC STIMULATION OF NATURAL FRACTURES AS REVEALED BY INDUCED MICROEARTHQUAKES,

    E-Print Network [OSTI]

    -1- HYDRAULIC STIMULATION OF NATURAL FRACTURES AS REVEALED BY INDUCED MICROEARTHQUAKES, CARTHAGE, December, 2001 Manuscript # 01066 LAUR# 01-1204 #12;Hydraulic Stimulation of Natural Fractures -2- ABSTRACT We have produced a high-resolution microseismic image of a hydraulic fracture stimulation

  18. Unsaturated hydraulic conductivity function based on a soil fragmentation process

    E-Print Network [OSTI]

    Tartakovsky, Daniel M.

    Unsaturated hydraulic conductivity function based on a soil fragmentation process Shmuel Assouline-parameter expression for relative hydraulic conductivity (RHC) of partially saturated soils. It is based on the premise. This assumption allows us to derive hydraulic properties of soils (water retention curves and unsaturated

  19. Efficiency Mapping for a Linear Hydraulic-Actuator

    E-Print Network [OSTI]

    Manring, Noah D.

    Efficiency Mapping for a Linear Hydraulic-Actuator Noah D. Manring Mechanical and Aerospace at generating an efficiency map for a linear hydraulic-actuator that is controlled using an open-centered 4- way- ing the efficiency improvements that may be gained for linear hydraulic-actuators that use this type

  20. ORIGINAL PAPER Hydraulic properties and embolism in small-diameter

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ORIGINAL PAPER Hydraulic properties and embolism in small-diameter roots of five temperate broad & Context It has been estimated that about half of a plant's total hydraulic resistance is located belowground, but it is not well known how temperate tree species differ in root hydraulic properties and how

  1. Modeling Turbulent Hydraulic Fracture Near a Free Surface

    E-Print Network [OSTI]

    Modeling Turbulent Hydraulic Fracture Near a Free Surface Victor C. Tsai Seismological Laboratory consider a hydraulic fracture problem in which the crack grows parallel to a free surface, subject to fully components. wall Wall shear stress. ^· Non-dimensionalized ·. 1 Introduction Hydraulic fracture has been

  2. Weakly dispersive hydraulic flows in a contraction --Nonlinear stability analysis

    E-Print Network [OSTI]

    Ee, Bernard Kuowei

    Weakly dispersive hydraulic flows in a contraction -- Nonlinear stability analysis Bernard K. Ee hydraulic solutions of the forced Korteweg de-Vries equation is investigated here. For numerical convenience is destabilized by a hydraulic instability in which superexponential growth occurs prior to satura- tion

  3. Original article Hydraulic conductance of two co-occuring neotropical

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Hydraulic conductance of two co-occuring neotropical understory shrubs December 1999) Abstract ­ Whole plant hydraulic conductance was measured for two co-occuring neotropical hydraulic con- ductance and leaf specific conducance in the drought-avoiding species, P. trigonum, than

  4. Modeling Turbulent Hydraulic Fracture Near a Free Surface

    E-Print Network [OSTI]

    Modeling Turbulent Hydraulic Fracture Near a Free Surface Victor C. Tsai Seismological Laboratory consider a hydraulic fracture problem in which the crack grows parallel to a free surface, subject to fully components. ^· Non-dimensionalized ·. 1 Introduction Hydraulic fracture has been studied for many years

  5. IOWA INSTITUTE OF HYDRAULIC RESEARCH COLLEGE OF ENGINEERING

    E-Print Network [OSTI]

    Stanier, Charlie

    SUMMARY OF ACTIVITIES IOWA INSTITUTE OF HYDRAULIC RESEARCH COLLEGE OF ENGINEERING THE UNIVERSITY December 1999 This report of the activities of the Iowa Institute of Hydraulic Research (IIHR) covers increasing emphasis on field measurements in environmental hydraulics and hydrometeorology and on development

  6. Hydraulic Wind Power Transfer Technology Afshin Izadian

    E-Print Network [OSTI]

    Zhou, Yaoqi

    Hydraulic Wind Power Transfer Technology Afshin Izadian Purdue School of Engineering and Technology of renewable energy tax credits in general and a gap in wind energy breakthroughs in particular have caused high cost of wind energy and technological dependency on countries such as China and Germany. Reducing

  7. March 24, 1999 Hydraulics, CIET 3132

    E-Print Network [OSTI]

    Bowen, James D.

    Test No. 2 March 24, 1999 Hydraulics, CIET 3132 Spring 1999, Bowen Page 1jdb_260.wpd Test Format in Closed Conduits (32 points) Water runs from an upper reservoir, through a turbine, to a lower reservoir, as shown below. Assuming the turbine is 80% efficient in converting the water power to mechanical power

  8. John Day Tailrace MASS2 Hydraulic Modeling

    SciTech Connect (OSTI)

    Rakowski, Cynthia L.; Richmond, Marshall C.

    2003-06-03T23:59:59.000Z

    Recent biological results for the Juvenile Bypass System at John Jay Lock and Dam have raised concerns about the hydraulic conditions that are created in the tailrace under different project operations. This Memorandum for Record discusses the development and application of a truncated MASS2 model in the John Day tailrace.

  9. Constructing Hydraulic Barriers in Deep Geologic Formations

    SciTech Connect (OSTI)

    Carter, E.E.; Carter, P.E. [Technologies Co, Texas (United States); Cooper, D.C. [Ph.D. Idaho National Laboratory, Idaho Falls, ID (United States)

    2008-07-01T23:59:59.000Z

    Many construction methods have been developed to create hydraulic barriers to depths of 30 to 50 meters, but few have been proposed for depths on the order of 500 meters. For these deep hydraulic barriers, most methods are potentially feasible for soil but not for hard rock. In the course of researching methods of isolating large subterranean blocks of oil shale, the authors have developed a wax thermal permeation method for constructing hydraulic barriers in rock to depths of over 500 meters in competent or even fractured rock as well as soil. The technology is similar to freeze wall methods, but produces a permanent barrier; and is potentially applicable in both dry and water saturated formations. Like freeze wall barriers, the wax thermal permeation method utilizes a large number of vertical or horizontal boreholes around the perimeter to be contained. However, instead of cooling the boreholes, they are heated. After heating these boreholes, a specially formulated molten wax based grout is pumped into the boreholes where it seals fractures and also permeates radially outward to form a series of columns of wax-impregnated rock. Rows of overlapping columns can then form a durable hydraulic barrier. These barriers can also be angled above a geologic repository to help prevent influx of water due to atypical rainfall events. Applications of the technique to constructing containment structures around existing shallow waste burial sites and water shutoff for mining are also described. (authors)

  10. Quantitative supersonic flow visualization by hydraulic analogy

    E-Print Network [OSTI]

    Rani, Sarma Laxminarasimha

    1998-01-01T23:59:59.000Z

    The hydraulic analogy, which forms the basis for the phics. current investigation, can be used to study supersonic gas flows with great ease by means of a water table. As a result of the analogy, water heights in free surface water flow correspond...

  11. Hydraulically actuated fuel injector including a pilot operated spool valve assembly and hydraulic system using same

    DOE Patents [OSTI]

    Shafer, Scott F. (Morton, IL)

    2002-01-01T23:59:59.000Z

    The present invention relates to hydraulic systems including hydraulically actuated fuel injectors that have a pilot operated spool valve assembly. One class of hydraulically actuated fuel injectors includes a solenoid driven pilot valve that controls the initiation of the injection event. However, during cold start conditions, hydraulic fluid, typically engine lubricating oil, is particularly viscous and is often difficult to displace through the relatively small drain path that is defined past the pilot valve member. Because the spool valve typically responds slower than expected during cold start due to the difficulty in displacing the relatively viscous oil, accurate start of injection timing can be difficult to achieve. There also exists a greater difficulty in reaching the higher end of the cold operating speed range. Therefore, the present invention utilizes a fluid evacuation valve to aid in displacement of the relatively viscous oil during cold start conditions.

  12. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of...

  13. Interim Models Developed to Predict Key Hanford Waste Glass Properties Using Composition

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Hrma, Pavel R.

    2003-08-08T23:59:59.000Z

    Over the past several years the amount of waste glass property data available in the open literature has increased markedly. We have compiled the data from over 2000 glass compositions, evaluated the data for consistency, and fit glass property models to portions of this database.[1] The properties modeled include normalized releases of boron (rB), sodium (rNa), and lithium (rLi) from glass exposed to the product consistency test (PCT), liquidus temperature (TL) of glasses in the spinel and zircon primary phase field, viscosity (?) at 1150°C (?1150) and as a function of temperature (?T), and molar volume (V). These models were compared to some of the previously available models and were found to predict the properties of glasses not used in model fitting better and covered broader glass composition regions than the previous ones. This paper summarizes the data collected and the models that resulted from this effort.

  14. Coordination of stem and leaf hydraulic conductance in southern California shrubs: a test of the hydraulic segmentation

    E-Print Network [OSTI]

    Sack, Lawren

    Coordination of stem and leaf hydraulic conductance in southern California shrubs: a test of the hydraulic segmentation hypothesis Alexandria L. Pivovaroff1 , Lawren Sack2 and Louis S. Santiago1 1 2014 New Phytologist (2014) 203: 842­850 doi: 10.1111/nph.12850 Key words: chaparral, hydraulic

  15. Abstract--Encouraged by previous performance of a hydraulic bed sensor, this work presents a new hydraulic transducer

    E-Print Network [OSTI]

    He, Zhihai "Henry"

    Abstract--Encouraged by previous performance of a hydraulic bed sensor, this work presents a new hydraulic transducer configuration which improves the system's ability to capture a heartbeat signal from. II.HYDRAULIC BED SENSOR A.Transducer construction The overall procedure and materials

  16. Analytical Plan for Roman Glasses

    SciTech Connect (OSTI)

    Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

    2011-01-01T23:59:59.000Z

    Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent “experiment” that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

  17. Specialty Cellular Glass Products and Their Applications

    E-Print Network [OSTI]

    Rostoker, D.

    1979-01-01T23:59:59.000Z

    . One such field of application, the Alcoa Smelting Process, involves the use of molten salts which tend to impregnate materials which are porous to either salt vapors or to the liquid phase. Such impregnation of ordinary insulating materials causes a...

  18. THE DEVELOPMENT OF RADIOACTIVE GLASS SURROGATES FOR FALLOUT DEBRIS

    SciTech Connect (OSTI)

    Martha R. Finck; Leigh R. Martin; Russel R. Lewis; Kevin P. Carney; Christopher A. McGrath

    2014-01-01T23:59:59.000Z

    The production of glass that emulates fallout is desired for the nuclear forensics community for training and measurement exercises. The composition of nuclear fallout is complex varying isotopic compositions . As the gaseous cloud traverses from hotter to cooler regions of the atmosphere, the processes of condensation and nucleation entrain environmental materials, vaporized nuclear materials and fission products. The elemental and isotopic composition of the fission products is altered due to chemical fractionation (i.e. the fission product composition that would be expected from fission of the original nuclear material is altered by differences in condensation rates of the elements); the fallout may be enriched or depleted in volatile or refractory fission products. This work describes preliminary results to synthesize, irradiate and fractionate the fission product content of irradiated particulate glass using a thermal distillation two hours after irradiation. The glass was synthesized using a solution-based polymerization of tetraethyl orthosilicate. Uranium was incorporated into the glass particulate at trace concentrations during polymerization. The particulate was subjected to a short thermal neutron irradiation then heated to 1273 K approximately 2 hours after the end of irradiation. Fission products of 133, 134, 135I, 132, 134Te, 135Xe, 138Cs and 91, 92Sr were observed to be distilled from the particulate. The results of these preliminary studies are discussed.

  19. Mixed polyanion glass cathodes: Iron phosphate vanadate glasses

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

    2014-01-01T23:59:59.000Z

    Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

  20. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of cultivation systems.

  1. RETENTION OF SULFATE IN HIGH LEVEL RADIOACTIVE WASTE GLASS

    SciTech Connect (OSTI)

    Fox, K.

    2010-09-07T23:59:59.000Z

    High level radioactive wastes are being vitrified at the Savannah River Site for long term disposal. Many of the wastes contain sulfate at concentrations that can be difficult to retain in borosilicate glass. This study involves efforts to optimize the composition of a glass frit for combination with the waste to improve sulfate retention while meeting other process and product performance constraints. The fabrication and characterization of several series of simulated waste glasses are described. The experiments are detailed chronologically, to provide insight into part of the engineering studies used in developing frit compositions for an operating high level waste vitrification facility. The results lead to the recommendation of a specific frit composition and a concentration limit for sulfate in the glass for the next batch of sludge to be processed at Savannah River.

  2. NUCLEAR WASTE GLASSES CONTINUOUS MELTING AND BULK VITRIFICAITON

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR

    2008-03-24T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Nuclear wastes have a variety of components and composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee the glass can be easily made and resist environmental degradation. Glass formulation is facilitated by developing property-composition models, and the strategy of model development and application is reviewed. However, the large variability of waste compositions presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slow down the process; molten salts may accumulate in container refractory walls; the glass on cooling may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  3. Nuclear Waste Glasses: Continuous Melting and Bulk Vitrification

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.

    2008-02-25T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Nuclear wastes have a variety of components and composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee that the glass can be easily made and resist environmental degradation. Glass formulation is facilitated by developing property-composition models, and the strategy of model development and application is reviewed. However, the large variability of waste compositions presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slow down the process; molten salts may accumulate in container refractory walls; on cooling, the glass may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  4. Nuclear Waste Glasses: Continuous Melting and Bulk Vitrification

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.

    2009-01-15T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Composition of nuclear wastes varies in the number of components and their composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee that the glass is easily made and resists environmental degradation. Glass formulation is facilitated by developing property-composition models. The strategy of model development and application is reviewed. However, the large variability of waste composition presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slows down the process; molten salts may accumulate in container refractory walls; on cooling, the glass may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  5. Weihai Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass...

    Open Energy Info (EERE)

    Weihai Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass Group Co Ltd Jump to: navigation, search Name: Weihai Blue Star Glass Holding Co Ltd (aka Shandong Lanxing Glass...

  6. Glass Ceiling or Glass Elevator: Are Voters Biased in Favor of Women Candidates in California Elections?

    E-Print Network [OSTI]

    Abney, Ronni Marie; Peterson, Rolfe Daus

    2011-01-01T23:59:59.000Z

    10.2202/1944-4370.1103 Abney and Peterson: Glass Ceilingor Glass Elevator Table 7A. Positive Gender Bias ModelAbney and Peterson: Glass Ceiling or Glass Elevator Huddy,

  7. Method for heating a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI)

    1998-01-01T23:59:59.000Z

    A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed.

  8. Method for heating a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.

    1998-07-21T23:59:59.000Z

    A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed. 5 figs.

  9. Compositional threshold for Nuclear Waste Glass Durability

    SciTech Connect (OSTI)

    Kruger, Albert A. [Pacific Northwest National Lab., Richland, WA (United States); Farooqi, Rahmatullah [Pohang Univ. of Science and Technology, (Korea, Republic of); Hrma, Pavel R. [Pacific Northwest National Lab., Richland, WA (United States), Pohang Univ. of Science and Technology, (Korea, Republic of)

    2013-04-24T23:59:59.000Z

    Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

  10. Interaction between Injection Points during Hydraulic Fracturing

    E-Print Network [OSTI]

    Hals, Kjetil M D

    2012-01-01T23:59:59.000Z

    We present a model of the hydraulic fracturing of heterogeneous poroelastic media. The formalism is an effective continuum model that captures the coupled dynamics of the fluid pressure and the fractured rock matrix and models both the tensile and shear failure of the rock. As an application of the formalism, we study the geomechanical stress interaction between two injection points during hydraulic fracturing (hydrofracking) and how this interaction influences the fracturing process. For injection points that are separated by less than a critical correlation length, we find that the fracturing process around each point is strongly correlated with the position of the neighboring point. The magnitude of the correlation length depends on the degree of heterogeneity of the rock and is on the order of 30-45 m for rocks with low permeabilities. In the strongly correlated regime, we predict a novel effective fracture-force that attracts the fractures toward the neighboring injection point.

  11. Hydraulic/Shock-Jumps in Protoplanetary Disks

    E-Print Network [OSTI]

    A. C. Boley; R. H. Durisen

    2006-03-10T23:59:59.000Z

    In this paper, we describe the nonlinear outcome of spiral shocks in protoplanetary disks. Spiral shocks, for most protoplanetary disk conditions, create a loss of vertical force balance in the post-shock region and result in rapid expansion of the gas perpendicular to the disk midplane. This expansion has characteristics similar to hydraulic jumps, which occur in incompressible fluids. We present a theory to describe the behavior of these hybrids between shocks and hydraulic jumps (shock bores) and then compare the theory to three-dimensional hydrodynamics simulations. We discuss the fully three-dimensional shock structures that shock bores produce and discuss possible consequences for disk mixing, turbulence, and evolution of solids.

  12. A Model For Polygonal Hydraulic Jumps

    E-Print Network [OSTI]

    Martens, Erik A; Bohr, Tomas

    2011-01-01T23:59:59.000Z

    We propose a phenomenological model for the polygonal hydraulic jumps discovered by Ellegaard et al., based on the known flow structure for the type II hydraulic jumps with a "roller" (separation eddy) near the free surface in the jump region. The model consists of mass conservation and radial force balance between hydrostatic pressure and viscous stresses on the roller surface. In addition, we consider the azimuthal force balance, primarily between pressure and viscosity, but also including non-hydrostatic pressure contributions from surface tension in light of recent observations by Bush et al. The model can be analyzed by linearization around the circular state, resulting in a parameter relationship for nearly circular polygonal states. A truncated, but fully nonlinear version of the model can be solved analytically. This simpler model gives rise to polygonal shapes that are very similar to those observed in experiments, even though surface tension is neglected, and the condition for the existence of a pol...

  13. Hydraulic fracturing slurry transport in horizontal pipes

    SciTech Connect (OSTI)

    Shah, S.N.; Lord, D.L. (Halliburton Services (US))

    1990-09-01T23:59:59.000Z

    Horizontal-well activity has increased throughout the industry in the past few years. To design a successful hydraulic fracturing treatment for horizontal wells, accurate information on the transport properties of slurry in horizontal pipe is required. Limited information exists that can be used to estimate critical deposition and resuspension velocities when proppants are transported in horizontal wells with non-Newtonian fracturing gels. This paper presents a study of transport properties of various hydraulic fracturing slurries in horizontal pipes. Flow data are gathered in three transparent horizontal pipes with different diameters. Linear and crosslinked fracturing gels were studied, and the effects of variables--e.g., pipe size; polymer-gelling-agent concentration; fluid rheological properties; crosslinking effects; proppant size, density, and concentrations; fluid density; and slurry pump rate--on critical deposition and resuspension velocities were investigated. Also, equations to estimate the critical deposition and resuspension velocities of fracturing gels are provided.

  14. Color Glass Condensate and Glasma

    E-Print Network [OSTI]

    Francois Gelis

    2010-09-06T23:59:59.000Z

    In this talk, I review the Color Glass Condensate theory of gluon saturation, and its application to the early stages of heavy ion collisions.

  15. Hydraulic system for a ratio change transmission

    DOE Patents [OSTI]

    Kalns, Ilmars (Northville, MI)

    1981-01-01T23:59:59.000Z

    Disclosed is a drive assembly (10) for an electrically powered vehicle (12). The assembly includes a transaxle (16) having a two-speed transmission (40) and a drive axle differential (46) disposed in a unitary housing assembly (38), an oil-cooled prime mover or electric motor (14) for driving the transmission input shaft (42), an adapter assembly (24) for supporting the prime mover on the transaxle housing assembly, and a hydraulic system (172) providing pressurized oil flow for cooling and lubricating the electric motor and transaxle and for operating a clutch (84) and a brake (86) in the transmission to shift between the two-speed ratios of the transmission. The adapter assembly allows the prime mover to be supported in several positions on the transaxle housing. The brake is spring-applied and locks the transmission in its low-speed ratio should the hydraulic system fail. The hydraulic system pump is driven by an electric motor (212) independent of the prime mover and transaxle.

  16. Development and Testing of ICV Glasses for Hanford LAW

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.; Hrma, Pavel R.; Schweiger, Michael J.; Matyas, Josef; Crum, Jarrod V.; Smith, Donald E.; Sevigny, Gary J.; Buchmiller, William C.; Tixier, John S.; Yeager, John D.; Belew, Kellen B.

    2003-08-01T23:59:59.000Z

    Preliminary glass compositions for immobilizing Hanford low-activity waste (LAW) by the in-container vitrification (ICV) process were fabricated at crucible- and engineering-scale and tested at Pacific Northwest National Laboratory. This testing showed that glasses with LAW loading of 20 mass% can readily be made and meet all product constraints by a far margin. It was found that the response constraint of the vapor hydration test (VHT) of less than 50 g/(m2•d) alteration rate was the most restrictive constraint placed on LAW glasses. Glasses with over 22 mass% Na2O can be made to meet this constraint along with all other product quality and processability constraints imposed by this process. The results of crucible melts with simulants were scaled-up to engineering scale and also tested with actual (radioactive) LAW. All the results suggest that the baseline glass can be successfully processed by the ICV technology and can meet all the constraints related to product quality.

  17. Glass Formulations for Immobilizing Hanford Low-Activity Wastes

    SciTech Connect (OSTI)

    Kim, D.S.; Elliott, M.L.; Smith, H.D.; Bagaasen, L.M.; Hrma, P.R. [Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352 (United States)

    2006-07-01T23:59:59.000Z

    Researchers at Pacific Northwest National Laboratory (PNNL) are developing and testing glasses for immobilizing low-activity wastes (LAW) for the full Hanford mission. PNNL is performing testing for low-activity waste glasses for both the Hanford Waste Treatment Plant (WTP) and the Bulk Vitrification Plant. The objective of this work is to increase the waste content of the glasses and ultimately increase the waste throughput of the LAW vitrification plants. This paper focuses on PNNL's development and testing of glasses for the Bulk Vitrification process. Collaborative studies are also being conducted with the Khlopin Radium Institute in St. Petersburg, Russia, to increase the solubility of sulfur in WTP glasses through the addition of trace chemicals to alter the glass chemistry. That research will be presented in a separate paper at this conference. Bulk Vitrification was selected as a potential supplemental treatment to accelerate the cleanup of LAW at Hanford. Also known as In-Container Vitrification{sup TM} (ICV{sup TM}), the Bulk Vitrification process combines soil, LAW, and chemical amendments; dries the mixture; and then vitrifies the material in a batch process in a refractory lined box. The process was developed by AMEC Earth and Environmental, Inc. (AMEC). Working with AMEC, PNNL developed a glass formulation that could incorporate a broad range of Hanford LAW. The initial glass development involved a 'nominal' waste composition, and a baseline glass was formulated and tested at crucible, engineering, and full scales. The performance of the baseline glass was then verified using a battery of laboratory tests as well as engineering-scale and full-scale ICV{sup TM} tests. Continued testing has focused on developing an acceptable operating envelope for the baseline glass. The current glass constraints are: - 17 {<=} Na{sub 2}O {<=} 22 mass%; - 3 {<=} B{sub 2}O{sub 3} {<=} 5 mass%; - 8 {<=} Al{sub 2}O{sub 3} {<=} 12.5 mass%; - 5.5 {<=} ZrO{sub 2} {<=} 8 mass%; 6.4 {<=} ZrO{sub 2} {<=} 8 mass% if Al{sub 2}O{sub 3} {>=} 9.5 mass%; - 40 {<=} SiO{sub 2} {<=} 48.5 mass%. Multiple samples from engineering-scale and full-scale ICV{sup TM} tests performed with a baseline glass formulation developed from crucible tests were analyzed for chemical composition, Product Consistency Test, Vapor Hydration Test, and the Toxicity Characteristic Leaching Procedure. The results show good agreement between glasses prepared in a crucible in the laboratory and the glasses from the larger scale tests. The results also show that the glass in the ICV{sup TM} box is homogeneous. Future testing is planned for optimizing the glass waste loading and qualifying a broader range of waste streams for treatment in the Bulk Vitrification process. This paper reviews the glass development and qualification process completed to date. This includes several series of crucible studies as well as confirmation testing at engineering-scale and full-scale. This formulation paper complements information presented by AMEC in an ICV{sup TM} processing paper. (authors)

  18. HIGH ALUMINUM HLW (HIGH LEVEL WASTE ) GLASSES FOR HANFORDS WTP (WASTE TREATMENT PROJECT)

    SciTech Connect (OSTI)

    KRUGER AA; BOWAN BW; JOSEPH I; GAN H; KOT WK; MATLACK KS; PEGG IL

    2010-01-04T23:59:59.000Z

    This paper presents the results of glass formulation development and melter testing to identify high waste loading glasses to treat high-Al high level waste (HLW) at Hanford. Previous glass formulations developed for this HLW had high waste loadings but their processing rates were lower that desired. The present work was aimed at improving the glass processing rate while maintaining high waste loadings. Glass formulations were designed, prepared at crucible-scale and characterized to determine their properties relevant to processing and product quality. Glass formulations that met these requirements were screened for melt rates using small-scale tests. The small-scale melt rate screening included vertical gradient furnace (VGF) and direct feed consumption (DFC) melter tests. Based on the results of these tests, modified glass formulations were developed and selected for larger scale melter tests to determine their processing rate. Melter tests were conducted on the DuraMelter 100 (DMIOO) with a melt surface area of 0.11 m{sup 2} and the DuraMelter 1200 (DMI200) HLW Pilot Melter with a melt surface area of 1.2 m{sup 2}. The newly developed glass formulations had waste loadings as high as 50 wt%, with corresponding Al{sub 2}O{sub 3} concentration in the glass of 26.63 wt%. The new glass formulations showed glass production rates as high as 1900 kg/(m{sup 2}.day) under nominal melter operating conditions. The demonstrated glass production rates are much higher than the current requirement of 800 kg/(m{sup 2}.day) and anticipated future enhanced Hanford Tank Waste Treatment and Immobilization Plant (WTP) requirement of 1000 kg/(m{sup 2}.day).

  19. Efficient Breach Theory Through the Looking Glass

    E-Print Network [OSTI]

    Adler, Barry E.

    2007-01-01T23:59:59.000Z

    in Wonderland and Through the Looking Glass (Signet 1960).Theory Through the Looking Glass such an award a put by theTheory Through the Looking Glass Consider also the hoary

  20. Aspects of the mechanics of metallic glasses

    E-Print Network [OSTI]

    Henann, David Lee

    2011-01-01T23:59:59.000Z

    Metallic glasses are amorphous materials that possess unique mechanical properties, such as high tensile strengths and good fracture toughnesses. Also, since they are amorphous, metallic glasses exhibit a glass transition, ...

  1. Investigation of the effect of gel residue on hydraulic fracture conductivity using dynamic fracture conductivity test

    E-Print Network [OSTI]

    Marpaung, Fivman

    2008-10-10T23:59:59.000Z

    conductivity is created when proppant slurry is pumped into a hydraulic fracture in low permeability rock. Unlike conventional fracture conductivity tests in which proppant is loaded into the fracture artificially, we pump proppant/ fracturing fluid slurries... different or special methods for completion, stimulation, and/or production techniques to retrieve the resource. Natural gas from coal or coal bed methane, tight gas sands, shale gas, and gas hydrates are all examples of unconventional gas reservoirs...

  2. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1998-01-01T23:59:59.000Z

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  3. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07T23:59:59.000Z

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  4. Derivation of site-specific relationships between hydraulic parameters and p-wave velocities based on hydraulic and seismic tomography

    SciTech Connect (OSTI)

    Brauchler, R.; Doetsch, J.; Dietrich, P.; Sauter, M.

    2012-01-10T23:59:59.000Z

    In this study, hydraulic and seismic tomographic measurements were used to derive a site-specific relationship between the geophysical parameter p-wave velocity and the hydraulic parameters, diffusivity and specific storage. Our field study includes diffusivity tomograms derived from hydraulic travel time tomography, specific storage tomograms, derived from hydraulic attenuation tomography, and p-wave velocity tomograms, derived from seismic tomography. The tomographic inversion was performed in all three cases with the SIRT (Simultaneous Iterative Reconstruction Technique) algorithm, using a ray tracing technique with curved trajectories. The experimental set-up was designed such that the p-wave velocity tomogram overlaps the hydraulic tomograms by half. The experiments were performed at a wellcharacterized sand and gravel aquifer, located in the Leine River valley near Göttingen, Germany. Access to the shallow subsurface was provided by direct-push technology. The high spatial resolution of hydraulic and seismic tomography was exploited to derive representative site-specific relationships between the hydraulic and geophysical parameters, based on the area where geophysical and hydraulic tests were performed. The transformation of the p-wave velocities into hydraulic properties was undertaken using a k-means cluster analysis. Results demonstrate that the combination of hydraulic and geophysical tomographic data is a promising approach to improve hydrogeophysical site characterization.

  5. Refractory Glass Seals for SOFC

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.

    2011-07-01T23:59:59.000Z

    One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

  6. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08T23:59:59.000Z

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  7. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne (Aiken, SC); Pickett, John Butler (Aiken, SC); Brown, Kevin George (Augusta, GA); Edwards, Thomas Barry (Aiken, SC)

    1998-01-01T23:59:59.000Z

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  8. Transient and Pseudosteady-State Productivity of Hydraulically Fractured Well

    E-Print Network [OSTI]

    Lumban Gaol, Ardhi

    2012-10-19T23:59:59.000Z

    equivalent wellbore radius .......................................................................................................... 16 3.1 Optimum CfD and maximum JD for various proppant number ................... 26 3.2 Model parameters... (Indonesia) that has provided a financial support for my Master study in Texas A&M University. vi NOMENCLATURE CfD = dimensionless fracture conductivity co = oil compressibility, Lt 2/m, 1/psi cte = total effective compressibility, Lt 2/m...

  9. Glass science tutorial: Lecture No. 7, Waste glass technology for Hanford

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-07-01T23:59:59.000Z

    This paper presents the details of the waste glass tutorial session that was held to promote knowledge of waste glass technology and how this can be used at the Hanford Reservation. Topics discussed include: glass properties; statistical approach to glass development; processing properties of nuclear waste glass; glass composition and the effects of composition on durability; model comparisons of free energy of hydration; LLW glass structure; glass crystallization; amorphous phase separation; corrosion of refractories and electrodes in waste glass melters; and glass formulation for maximum waste loading.

  10. Lead phosphate glass compositions for optical components

    DOE Patents [OSTI]

    Sales, Brian C. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN)

    1987-01-01T23:59:59.000Z

    A lead phosphate glass to which has been added indium oxide or scandium oe to improve chemical durability and provide a lead phosphate glass with good optical properties.

  11. Radiation and Thermal Ageing of Nuclear Waste Glass

    SciTech Connect (OSTI)

    Weber, William J [ORNL

    2014-01-01T23:59:59.000Z

    The radioactive decay of fission products and actinides incorporated into nuclear waste glass leads to self-heating and self-radiation effects that may affect the stability, structure and performance of the glass in a closed system. Short-lived fission products cause significant self-heating for the first 600 years. Alpha decay of the actinides leads to self-radiation damage that can be significant after a few hundred years, and over the long time periods of geologic disposal, the accumulation of helium and radiation damage from alpha decay may lead to swelling, microstructural evolution and changes in mechanical properties. Four decades of research on the behavior of nuclear waste glass are reviewed.

  12. Covered Product Category: Refrigerated Beverage Vending Machines...

    Energy Savers [EERE]

    ENERGY STAR product specification applies to new and remanufactured indoor (i.e., glass front) and indooroutdoor (i.e., solid front) refrigerated beverage vending machines....

  13. Glass Ceramic Formulation Data Package

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Rodriguez, Carmen P.; McCloy, John S.; Vienna, John D.; Chung, Chul-Woo

    2012-06-17T23:59:59.000Z

    A glass ceramic waste form is being developed for treatment of secondary waste streams generated by aqueous reprocessing of commercial used nuclear fuel (Crum et al. 2012b). The waste stream contains a mixture of transition metals, alkali, alkaline earths, and lanthanides, several of which exceed the solubility limits of a single phase borosilicate glass (Crum et al. 2009; Caurant et al. 2007). A multi-phase glass ceramic waste form allows incorporation of insoluble components of the waste by designed crystallization into durable heat tolerant phases. The glass ceramic formulation and processing targets the formation of the following three stable crystalline phases: (1) powellite (XMoO4) where X can be (Ca, Sr, Ba, and/or Ln), (2) oxyapatite Yx,Z(10-x)Si6O26 where Y is alkaline earth, Z is Ln, and (3) lanthanide borosilicate (Ln5BSi2O13). These three phases incorporate the waste components that are above the solubility limit of a single-phase borosilicate glass. The glass ceramic is designed to be a single phase melt, just like a borosilicate glass, and then crystallize upon slow cooling to form the targeted phases. The slow cooling schedule is based on the centerline cooling profile of a 2 foot diameter canister such as the Hanford High-Level Waste canister. Up to this point, crucible testing has been used for glass ceramic development, with cold crucible induction melter (CCIM) targeted as the ultimate processing technology for the waste form. Idaho National Laboratory (INL) will conduct a scaled CCIM test in FY2012 with a glass ceramic to demonstrate the processing behavior. This Data Package documents the laboratory studies of the glass ceramic composition to support the CCIM test. Pacific Northwest National Laboratory (PNNL) measured melt viscosity, electrical conductivity, and crystallization behavior upon cooling to identify a processing window (temperature range) for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form.

  14. Downstream hydraulic geometry relations: 2. Calibration and testing

    E-Print Network [OSTI]

    Singh, Vijay P.; Yang, Chih Ted; Deng, Zhi-Qiang

    2003-12-04T23:59:59.000Z

    Downstream hydraulic geometry relations: 2. Calibration and testing Vijay P. Singh Department of Civil and Environmental Engineering, Louisiana State University, Baton Rouge, Louisiana, USA Chih Ted Yang 1 Department of Civil Engineering, Colorado...; KEYWORDS: dynamic equilibrium, hydraulic geometry, maximum entropy, minimum energy dissipation, regime equations, stream power Citation: Singh, V. P., C. T. Yang, and Z.-Q. Deng, Downstream hydraulic geometry relations: 2. Calibration and testing, Water...

  15. IMPACT OF URANIUM AND THORIUM ON HIGH TIO2 CONCENTRATION NUCLEAR WASTE GLASSES

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2012-01-11T23:59:59.000Z

    This study focused on the potential impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. All but one of the study glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which is typically found in DWPF-type glasses and had no practical impact on the durability of the glass. The measured Product Consistency Test (PCT) responses for the study glasses and the viscosities of the glasses were well predicted by the current DWPF models. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components.

  16. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, Carol M. (3922 Wood Valley Dr., Aiken, SC 29801)

    1992-01-01T23:59:59.000Z

    A method for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a "non-bridging oxygen" term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term.

  17. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, C.M.

    1992-04-07T23:59:59.000Z

    A method is described for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a non-bridging oxygen' term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term. 4 figs.

  18. Uncertainty in the maximum principal stress estimated from hydraulic fracturing Measurements due to the presence of the induced fracture

    E-Print Network [OSTI]

    Rutqvist, Jonny; Tsang, Chin-fu; Stephansson, Ove

    2000-01-01T23:59:59.000Z

    reopening during hydraulic fracturing stress determinations.Laboratory study of hydraulic fracturing pressure data?Howevaluation of hydraulic fracturing stress measurement

  19. Memo, "Incorporation of HLW Glass Shell V2.0 into the Flowsheets," to ED Lee, CCN: 184905, October 20, 2009

    SciTech Connect (OSTI)

    Gimpel, Rodney F.; Kruger, Albert A.

    2013-12-18T23:59:59.000Z

    Efforts are being made to increase the efficiency and decrease the cost of vitrifying radioactive waste stored in tanks at the U.S. Department of Energy Hanford Site. The compositions of acceptable and processable high-level waste (HL W) glasses need to be optimized to minimize the waste-form volume and, hence, to reduce cost. A database of glass properties of waste glass and associated simulated waste glasses was collected and documented in PNNL 18501, Glass Property Data and Models for Estimating High-Level Waste Glass Volume and glass property models were curve-fitted to the glass compositions. A routine was developed that estimates HL W glass volumes using the following glass property models: II Nepheline, II One-Percent Crystal Temperature (T1%), II Viscosity (11) II Product Consistency Tests (PCT) for boron, sodium, and lithium, and II Liquidus Temperature (TL). The routine, commonly called the HL W Glass Shell, is presented in this document. In addition to the use of the glass property models, glass composition constraints and rules, as recommend in PNNL 18501 and in other documents (as referenced in this report) were incorporated. This new version of the HL W Glass Shell should generally estimate higher waste loading in the HL W glass than previous versions.

  20. Integrated Thermal and Hydraulic Analysis of Distillation Columns

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    . The paper outlines how bringing together the column thermal and hydraulics analysis provides significant additional insights to help screen the options for distillation column revamps....

  1. Hydraulically refueled battery employing a packed bed metal particle electrode

    DOE Patents [OSTI]

    Siu, S.C.; Evans, J.W.

    1998-12-15T23:59:59.000Z

    A secondary zinc air cell, or another selected metal air cell, employing a spouted/packed metal particle bed and an air electrode is described. More specifically, two embodiments of a cell, one that is capable of being hydraulically recharged, and a second that is capable of being either hydraulically or electrically recharged. Additionally, each cell includes a sloped bottom portion to cause stirring of the electrolyte/metal particulate slurry when the cell is being hydraulically emptied and refilled during hydraulically recharging of the cell. 15 figs.

  2. MICRO-SEISMICITY, FAULT STRUCTURE AND HYDRAULIC COMPARTMENTALIZATION...

    Open Energy Info (EERE)

    GETHERMAL FIELD, CALIFORNIA Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: MICRO-SEISMICITY, FAULT STRUCTURE AND HYDRAULIC...

  3. Hydraulic "Fracking": Are Surface Water Impacts An Ecological Concern?

    E-Print Network [OSTI]

    Hydraulic "Fracking": Are Surface Water Impacts An Ecological Concern? G. Allen Burton Jr; Fracking; Water-quality stressor; Ecological risk assessment Introduction The world's energy marketplace

  4. ROC/RMOTC Hydraulic Pump Test Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    never attained. 6. The pump was hydraulically deployed and retrieved successfully. 7. Corrosion andor erosion of the pump rod were found when the pump was inspected following...

  5. Hydraulic properties of adsorbed water films in unsaturated porous media

    SciTech Connect (OSTI)

    Tokunaga, Tetsu K.

    2009-03-01T23:59:59.000Z

    Adsorbed water films strongly influence residual water saturations and hydraulic conductivities in porous media at low saturations. Hydraulic properties of adsorbed water films in unsaturated porous media were investigated through combining Langmuir's film model with scaling analysis, without use of any adjustable parameters. Diffuse double layer influences are predicted to be important through the strong dependence of adsorbed water film thickness (f) on matric potential ({Psi}) and ion charge (z). Film thickness, film velocity, and unsaturated hydraulic conductivity are predicted to vary with z{sup -1}, z{sup -2}, and z{sup -3}, respectively. In monodisperse granular media, the characteristic grain size ({lambda}) controls film hydraulics through {lambda}{sup -1} scaling of (1) the perimeter length per unit cross sectional area over which films occur, (2) the critical matric potential ({Psi}{sub c}) below which films control flow, and (3) the magnitude of the unsaturated hydraulic conductivity when {Psi} < {Psi}{sub c}. While it is recognized that finer textured sediments have higher unsaturated hydraulic conductivities than coarser sands at intermediate {Psi}, the {lambda}{sup -1} scaling of hydraulic conductivity predicted here extends this understanding to very low saturations where all pores are drained. Extremely low unsaturated hydraulic conductivities are predicted under adsorbed film-controlled conditions (generally < 0.1 mm y{sup -1}). On flat surfaces, the film hydraulic diffusivity is shown to be constant (invariant with respect to {Psi}).

  6. Compact, electro-hydraulic, variable valve actuation system providing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compact, electro-hydraulic, variable valve actuation system providing variable lift, timing and duration to enable high efficiency engine combustion control Compact,...

  7. Thermal Hydraulic Modeling: Cross-Verification, Validation and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aleks Obabko, Paul Fischer, and Tim Tautges, Argonne National Laboratory Thermal Hydraulic Modeling: Cross-Verification, Validation and Co-design PI Name: Paul F. Fischer PI...

  8. 1112323-danimer-abstract-hydraulic-fractures | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil Recovery Deepwater Tech Methane Hydrate Field Demo of Eco-Friendly Propped Hydraulic Fractures 11123-23 Primary Performer DaniMer Scientific, LLC (Bainbridge, GA)...

  9. adopted hydraulic retention: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concern? Geosciences Websites Summary: Hydraulic "Fracking": Are Surface Water Impacts An Ecological Concern? G. Allen Burton Jr shale formations. Millions of liters of...

  10. advanced hydraulic studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concern? Geosciences Websites Summary: Hydraulic "Fracking": Are Surface Water Impacts An Ecological Concern? G. Allen Burton Jr shale formations. Millions of liters of...

  11. asymmetric hydraulic fracture: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the fractured shale 17 RPSEA UNCONVENTIONAL GAS CONFERENCE 2012: Geology, the Environment, Hydraulic Fracturing Engineering Websites Summary: Fracturing Experiment Overview...

  12. advanced hydraulic fracturing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the fractured shale 18 RPSEA UNCONVENTIONAL GAS CONFERENCE 2012: Geology, the Environment, Hydraulic Fracturing Engineering Websites Summary: Fracturing Experiment Overview...

  13. assembly thermo hydraulic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concern? Geosciences Websites Summary: Hydraulic "Fracking": Are Surface Water Impacts An Ecological Concern? G. Allen Burton Jr shale formations. Millions of liters of...

  14. advanced thermal hydraulic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concern? Geosciences Websites Summary: Hydraulic "Fracking": Are Surface Water Impacts An Ecological Concern? G. Allen Burton Jr shale formations. Millions of liters of...

  15. Finite element modeling of hydraulic fracturing in 3D

    E-Print Network [OSTI]

    2013-03-22T23:59:59.000Z

    Mar 22, 2013 ... Gautier. A.. Touzelet. S.: Tracer testing of the geothermal heat ex- ... R.: A field demonstra- tion of hydraulic fracturing for solid waste diposal—.

  16. Hydraulically refueled battery employing a packed bed metal particle electrode

    DOE Patents [OSTI]

    Siu, Stanley C. (Castro Valley, CA); Evans, James W. (Piedmont, CA)

    1998-01-01T23:59:59.000Z

    A secondary zinc air cell, or another selected metal air cell, employing a spouted/packed metal particle bed and an air electrode. More specifically, two embodiments of a cell, one that is capable of being hydraulically recharged, and a second that is capable of being either hydraulically or electrically recharged. Additionally, each cell includes a sloped bottom portion to cause stirring of the electrolyte/metal particulate slurry when the cell is being hydraulically emptied and refilled during hydraulically recharging of the cell.

  17. The US glass industry: An energy perspective

    SciTech Connect (OSTI)

    Babcock, E.; Elaahi, A.; Lowitt, H.E.

    1988-09-01T23:59:59.000Z

    This report investigates the state of the US glass industry in terms of energy consumption and conservation. The specific objectives were: to update and verify energy consumption and production data for the various process steps in 1985; to determine the potential energy savings attainable by replacing current practices with state-of-the-art and advanced (year 2010) production practices and technologies; and to identify areas of research and development opportunity that will enable these potential future savings to be achieved. The results of this study concluded that for the year 2010 production level, there is potential to save between 21 and 44 percent of the projected energy use by replacing current technology practices with state-of-the-art and advanced technologies. RandD needs and opportunities were identified for the industry. Potential RandD candidates for DOE involvement were selected from the identified list, primarily based on their energy savings potential and the opinions of industry experts. 100 refs.

  18. Evaluation Of Glass Density To Support The Estimation Of Fissile Mass Loadings From Iron Concentrations In SB8 Glasses

    SciTech Connect (OSTI)

    Edwards, T. B.; Peeler, D. K.; Kot, W. K.; Gan, H.; Pegg, I. L.

    2013-04-30T23:59:59.000Z

    The Department of Energy – Savannah River (DOE-SR) has provided direction to Savannah River Remediation (SRR) to maintain fissile concentration in glass below 897 g/m{sup 3}. In support of that guidance, the Savannah River National Laboratory (SRNL) provided a technical basis and a supporting Microsoft® Excel® spreadsheet for the evaluation of fissile loading in Sludge Batch 5 (SB5), Sludge Batch 6 (SB6), Sludge Batch 7a (SB7a), and Sludge Batch 7b (SB7b) glass based on the iron (Fe) concentration in glass as determined by the measurements from the Slurry Mix Evaporator (SME) acceptability analysis. SRR has since requested that the necessary density information be provided to allow SRR to update the Excel® spreadsheet so that it may be used to maintain fissile concentration in glass below 897 g/m{sup 3} during the processing of Sludge Batch 8 (SB8). One of the primary inputs into the fissile loading spreadsheet includes an upper bound for the density of SB8-based glasses. Thus, these bounding density values are to be used to assess the fissile concentration in this glass system. It should be noted that no changes are needed to the underlying structure of the Excel-based spreadsheet to support fissile assessments for SB8. However, SRR should update the other key inputs to the spreadsheet that are based on fissile and Fe concentrations reported from the SB8 Waste Acceptance Product Specification (WAPS) sample.

  19. A Topological Glass

    E-Print Network [OSTI]

    Jean-Pierre Eckmann

    2007-04-07T23:59:59.000Z

    We propose and study a model with glassy behavior. The state space of the model is given by all triangulations of a sphere with $n$ nodes, half of which are red and half are blue. Red nodes want to have 5 neighbors while blue ones want 7. Energies of nodes with different numbers of neighbors are supposed to be positive. The dynamics is that of flipping the diagonal of two adjacent triangles, with a temperature dependent probability. We show that this system has an approach to a steady state which is exponentially slow, and show that the stationary state is unordered. We also study the local energy landscape and show that it has the hierarchical structure known from spin glasses. Finally, we show that the evolution can be described as that of a rarefied gas with spontaneous generation of particles and annihilating collisions.

  20. Downstream hydraulic geometry relations: 1. Theoretical development

    E-Print Network [OSTI]

    Singh, Vijay P.; Yang, Chih Ted; Deng, Z. Q.

    2003-12-04T23:59:59.000Z

    . Thus USP, denoted as P w , is expressed as P w ? VS ?3a? where V is the average flow velocity, and S is the energy slope. Stream power (SP) is the rate of energy dissipation due to water: SP ? QgS ?3b? where g is the weight density of water and Q... of flow and B as the width of flow, then the flow cross-sectional area A= Bh, the wetted perimeter P= B + 2h, and the hydraulic radius R = A/P = (Bh)/(B + 2h). If the channel is wide rectangular, then R ? h = depth of flow. The flow discharge in equation...

  1. Hydraulic Hybrid Systems | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtel JumpCounty, Texas: EnergyHy9 CorporationHydra Fuel CellHydraulic

  2. The Hydraulic Institute: Who We Are

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssuesEnergy Solar Decathlon2001 PowerofUseResearchHydraulic Institute:

  3. Thermal Hydraulic Simulations, Error Estimation and Parameter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in theTheoretical Study onThermal Hydraulic Simulations,

  4. Hydraulic Fracturing | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunan Runhua New Energy Development CoHustisfordHydraulic

  5. Data SheetProduct Selection Guide Ultrafiltration Membranes

    E-Print Network [OSTI]

    Lebendiker, Mario

    processing systems. Product Features · Composite PES membrane provides a stable hydraulic environment and an overview of the key criteria and product characteristics to consider when selecting an UF membrane for your

  6. Energy Efficiency Improvement and Cost Saving Opportunities for the Glass Industry. An ENERGY STAR Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    AlChalabi et al. 1995). Praxair has developed a WideFlame™variations in product. Praxair, Inc. also developed an oxy-even reduced product quality. Praxair and Heye Glass have

  7. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    .S. for residential buildings. To meet IECC's U-factor and solar heat gain coefficient (SHGC) requirements insulatingLBNL-5022E Research Needs: Glass Solar Reflectance and Vinyl Siding Authors: R. Hart*, C. Curcija of any information, apparatus, product, or process disclosed, or represents that its use would

  8. Sulfate Fining Chemistry in Oxidized and Reduced Soda-Lime-Silica Glasses

    SciTech Connect (OSTI)

    Matyas, Josef; Hrma, Pavel R.

    2005-05-13T23:59:59.000Z

    Various reducing agents were used and their additions were varied to (1) increase glass quality through eliminating defects from silica scum, (2) decrease SOx emissions through changing the kind and quantity of reducing agents, and (3) improve production efficiency through increased flexibility of glass redox control during continuous processing. The work included measuring silica sand dissolution and sulfate decomposition in melts from glass batches. Glass batches were heated at a temperature-increase rate deemed similar to that experienced in the melting furnace. The sulfate decomposition kinetics was investigated with thermogravimetric analysis-differential thermal analysis and evolved gas analysis. Sulfur concentrations in glasses quenched at different temperatures were determined using X-ray fluorescence spectroscopy. The distribution of residual sand (that which was not dissolved during the initial batch reactions) in the glass was obtained as a function of temperature with optical microscopy in thin-sections of melts. The fraction of undissolved sand was measured with X-ray diffraction. The results of the present study helped Visteon Inc. reduce the energy consumption and establish the batch containing 0.118 mass% of graphite as the best candidate for Visteon glass production. The improved glass batch has a lower potential for silica scum formation and for brown fault occurrence in the final glass product. It was established that bubbles trapped in the melt even at 1450 C have a high probability to be refined when reaching the hot zone in the glass furnace. Furthermore, silica sand does not accumulate at the glass surface and dissolves faster in the batch with graphite than in the batch with carbocite.

  9. Testing of Large-Scale ICV Glasses with Hanford LAW Simulant

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kim, Dong-Sang; Vienna, John D.; Matyas, Josef; Smith, Donald E.; Schweiger, Michael J.; Yeager, John D.

    2005-03-01T23:59:59.000Z

    Preliminary glass compositions for immobilizing Hanford low-activity waste (LAW) by the in-container vitrification (ICV) process were initially fabricated at crucible- and engineering-scale, including simulants and actual (radioactive) LAW. Glasses were characterized for vapor hydration test (VHT) and product consistency test (PCT) responses and crystallinity (both quenched and slow-cooled samples). Selected glasses were tested for toxicity characteristic leach procedure (TCLP) responses, viscosity, and electrical conductivity. This testing showed that glasses with LAW loading of 20 mass% can be made readily and meet all product constraints by a far margin. Glasses with over 22 mass% Na2O can be made to meet all other product quality and process constraints. Large-scale testing was performed at the AMEC, Geomelt Division facility in Richland. Three tests were conducted using simulated LAW with increasing loadings of 12, 17, and 20 mass% Na2O. Glass samples were taken from the test products in a manner to represent the full expected range of product performance. These samples were characterized for composition, density, crystalline and non-crystalline phase assemblage, and durability using the VHT, PCT, and TCLP tests. The results, presented in this report, show that the AMEC ICV product with meets all waste form requirements with a large margin. These results provide strong evidence that the Hanford LAW can be successfully vitrified by the ICV technology and can meet all the constraints related to product quality. The economic feasibility of the ICV technology can be further enhanced by subsequent optimization.

  10. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Allan, Shawn M.; Baranova, Inessa; Poley, Joseph; Reis, Henrique

    2012-02-27T23:59:59.000Z

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 ���°C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination id

  11. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Allan, Shawn M.

    2012-02-27T23:59:59.000Z

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination identifying castable molds for

  12. Formed Core Sampler Hydraulic Conductivity Testing

    SciTech Connect (OSTI)

    Miller, D. H.; Reigel, M. M.

    2012-09-25T23:59:59.000Z

    A full-scale formed core sampler was designed and functionally tested for use in the Saltstone Disposal Facility (SDF). Savannah River National Laboratory (SRNL) was requested to compare properties of the formed core samples and core drilled samples taken from adjacent areas in the full-scale sampler. While several physical properties were evaluated, the primary property of interest was hydraulic conductivity. Differences in hydraulic conductivity between the samples from the formed core sampler and those representing the bulk material were noted with respect to the initial handling and storage of the samples. Due to testing conditions, the site port samples were exposed to uncontrolled temperature and humidity conditions prior to testing whereas the formed core samples were kept in sealed containers with minimal exposure to an uncontrolled environment prior to testing. Based on the results of the testing, no significant differences in porosity or density were found between the formed core samples and those representing the bulk material in the test stand.

  13. HYDRAULIC AND PHYSICAL PROPERTIES OF MCU SALTSTONE

    SciTech Connect (OSTI)

    Dixon, K; Mark Phifer, M

    2008-03-19T23:59:59.000Z

    The Saltstone Disposal Facility (SDF), located in the Z-Area of the Savannah River Site (SRS), is used for the disposal of low-level radioactive salt solution. The SDF currently contains two vaults: Vault 1 (6 cells) and Vault 4 (12 cells). Additional disposal cells are currently in the design phase. The individual cells of the saltstone facility are filled with saltstone., Saltstone is produced by mixing the low-level radioactive salt solution, with blast furnace slag, fly ash, and cement or lime to form a dense, micro-porous, monolithic, low-level radioactive waste form. The saltstone is pumped into the disposal cells where it subsequently solidifies. Significant effort has been undertaken to accurately model the movement of water and contaminants through the facility. Key to this effort is an accurate understanding of the hydraulic and physical properties of the solidified saltstone. To date, limited testing has been conducted to characterize the saltstone. The primary focus of this task was to estimate the hydraulic and physical properties of MCU (Modular Caustic Side Solvent Extraction Unit) saltstone relative to two permeating fluids. These fluids included simulated groundwater equilibrated with vault concrete and simulated saltstone pore fluid. Samples of the MCU saltstone were prepared by the Savannah River National Laboratory (SRNL) and allowed to cure for twenty eight days prior to testing. These samples included two three-inch diameter by six inch long mold samples and three one-inch diameter by twelve inch long mold samples.

  14. Hydraulic conductivity estimation from induced polarisation data at the field scale --the Krauthausen case history

    E-Print Network [OSTI]

    Sailhac, Pascal

    Hydraulic conductivity estimation from induced polarisation data at the field scale Abstract Recently, encouraging results have been obtained to estimate hydraulic conductivity in order to establish semi-empirical relationships between complex electrical conductivity and hydraulic

  15. Passivity Based Adaptive Control of a Two Chamber Single Rod Hydraulic Actuator

    E-Print Network [OSTI]

    Li, Perry Y.

    Passivity Based Adaptive Control of a Two Chamber Single Rod Hydraulic Actuator Meng Wang and Perry based backstepping controller using a physical compressibility energy function for a chamber hydraulic produces an accurate trajectory tracking performance. I. INTRODUCTION Electronically controlled hydraulic

  16. Development of a Hydraulic Manipulator Servoactuator Model: Simulation and Experimental Validation

    E-Print Network [OSTI]

    Papadopoulos, Evangelos

    Development of a Hydraulic Manipulator Servoactuator Model: Simulation and Experimental Validation Abstract In this paper, modelling and identification of a hydraulic servoactuator system is presented, leakage, and load dynamics. System parameters are identified based on a high-performance hydraulic

  17. Hydraulic limitation not declining nitrogen availability causes the age-related photosynthetic decline in loblolly

    E-Print Network [OSTI]

    DeLucia, Evan H.

    Hydraulic limitation not declining nitrogen availability causes the age-related photosynthetic capacity and thus decreases GPP with increasing age; and (2) hydraulic limitations increasingly induce conservative with age. We conclude that hydraulic limitation increasingly limits the photosyn- thetic rates

  18. Reinforced glass beamsReinforced glass beamsg Auteur Dr. Christian LOUTER 1

    E-Print Network [OSTI]

    Reinforced glass beamsReinforced glass beamsg EDCE Auteur Dr. Christian LOUTER 1 ENAC/EDCE 2011In contemporary architecture glass is increasinglyIn contemporary architecture glass is increasingly applied for structural components such as beamsapplied for structural components such as beams. However glass

  19. Hydraulic Fractures: multiscale phenomena, asymptotic and numerical solutions

    E-Print Network [OSTI]

    Peirce, Anthony

    Hydraulic Fractures: multiscale phenomena, asymptotic and numerical solutions SANUM Conference (UMN) Eduard Siebrits (SLB) #12;2 Outline · Examples of hydraulic fractures · Governing equations well stimulation Fracturing Fluid Proppant #12;5 Quarries #12;6 Magma flow Tarkastad #12;7 Model EQ 1

  20. Hydraulic Fractures: multiscale phenomena, asymptotic and numerical solutions

    E-Print Network [OSTI]

    Peirce, Anthony

    Hydraulic Fractures: multiscale phenomena, asymptotic and numerical solutions CSIRO CSS TCP Detournay (UMN) Eduard Siebrits (SLB) #12;2 Outline · Examples of hydraulic fractures · Governing equations well stimulation Fracturing Fluid Proppant #12;5 Quarries #12;6 Magma flow Tarkastad #12;7 Model EQ 1

  1. Creation and Impairment of Hydraulic Fracture Conductivity in Shale Formations 

    E-Print Network [OSTI]

    Zhang, Junjing

    2014-07-10T23:59:59.000Z

    Multi-stage hydraulic fracturing is the key to the success of many shale gas and shale oil reservoirs. The main objectives of hydraulic fracturing in shale are to create artificial fracture networks that are conductive for oil and gas flow...

  2. The Performance and Environmental Effects of a Hydraulic Clam Dredge

    E-Print Network [OSTI]

    The Performance and Environmental Effects of a Hydraulic Clam Dredge THOMAS L MEYER, RICHARD A to Nantucket, Mass. Hydraulic clam dredges with 0.76 m and 1.2 m (30 and 48 inch) wide blades were used during these surveys (Serchuk et aI., 1979). The efficiency of these dredges and the general effect of dredging

  3. Sustained Storage and Transport of Hydraulic Gold Mining Sediment

    E-Print Network [OSTI]

    James, L. Allan

    Sustained Storage and Transport of Hydraulic Gold Mining Sediment in the Bear River, California L primarily in the Yuba Basin. Sus- tained storage and transport of hydraulic min- ing sediment in the Bear- ume is more than double previous estimates of storage in the lower basin, and is greater than any

  4. IOWA INSTITUTE OF HYDRAULIC RESEARCH COLLEGE OF ENGINEERING

    E-Print Network [OSTI]

    Stanier, Charlie

    * Hydraulic Model Study of Circulating Water Pump Structure for Marmara Erglisi Power Plant BVI Ettema Simulations with NEXRAD Data Army/UCONN Krajewski, Kruger Simulation of the Passage of a Blade Through ASCE Holly * ** Hydraulic Model Tests of the St. Louis County Water Company Meramec Plant Intakes No. 1

  5. Optimal Power Management for a Hydraulic Hybrid Delivery Truck

    E-Print Network [OSTI]

    Peng, Huei

    Optimal Power Management for a Hydraulic Hybrid Delivery Truck BIN WU, CHAN-CHIAO LIN, ZORAN FILIPI control strategies. This paper presents a methodology for developing a power management strategy tailored specifically to a parallel Hydraulic Hybrid Vehicle (HHV) configured for a medium-size delivery truck

  6. P and PI controllers for a nonlinear hydraulic network

    E-Print Network [OSTI]

    De Persis, Claudio

    constraints) arising in industrial applications. Current case study: Grundfos district heating system #12;P" district heating system #12;P and PI controllers for a nonlinear hydraulic network Sept. 20, 2007 Page 4 Results #12;P and PI controllers for a nonlinear hydraulic network Sept. 20, 2007 Page 5 District Heating

  7. Systematic Variability of Soil Hydraulic Conductivity Across Three Vertisol Catenas

    E-Print Network [OSTI]

    Rivera, Leonardo Daniel

    2011-10-21T23:59:59.000Z

    .......................................................... 16 Saturated Hydraulic Conductivity Measurements .......................... 19 Soil Sampling and Analysis ............................................................ 22 ROSETTA Modeling... properties. Manure application improved aggregation, decreased bulk density, and increased the hydraulic conductivity of the soil. Conventional tillage treatments had the highest bulk densities and lowest infiltration rates. Effects of Landscape Position...

  8. Creation and Impairment of Hydraulic Fracture Conductivity in Shale Formations

    E-Print Network [OSTI]

    Zhang, Junjing

    2014-07-10T23:59:59.000Z

    Multi-stage hydraulic fracturing is the key to the success of many shale gas and shale oil reservoirs. The main objectives of hydraulic fracturing in shale are to create artificial fracture networks that are conductive for oil and gas flow...

  9. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15T23:59:59.000Z

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  10. Using electrical impedance tomography to map subsurface hydraulic conductivity

    DOE Patents [OSTI]

    Berryman, James G. (Danville, CA); Daily, William D. (Livermore, CA); Ramirez, Abelardo L. (Pleasanton, CA); Roberts, Jeffery J. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    The use of Electrical Impedance Tomography (EIT) to map subsurface hydraulic conductivity. EIT can be used to map hydraulic conductivity in the subsurface where measurements of both amplitude and phase are made. Hydraulic conductivity depends on at least two parameters: porosity and a length scale parameter. Electrical Resistance Tomography (ERT) measures and maps electrical conductivity (which can be related to porosity) in three dimensions. By introducing phase measurements along with amplitude, the desired additional measurement of a pertinent length scale can be achieved. Hydraulic conductivity controls the ability to flush unwanted fluid contaminants from the surface. Thus inexpensive maps of hydraulic conductivity would improve planning strategies for subsequent remediation efforts. Fluid permeability is also of importance for oil field exploitation and thus detailed knowledge of fluid permeability distribution in three-dimension (3-D) would be a great boon to petroleum reservoir analysts.

  11. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27T23:59:59.000Z

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. In addition, all of the blends may require consideration for their handling. A number of engineering considerations and recommendations were prepared based on the experimental findings, experience, and other process considerations. Recommendations for future testing are included. In conjunction with future work, it is recommended that a professional consultant be engaged to guide and assist with testing and design input.

  12. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27T23:59:59.000Z

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. The problems might include arching or ratholing in the silo/hopper. In addition, all of the blends may require consideration for their handling.

  13. Design, modeling, fabrication and testing of a piezoelectric microvalve for high pressure, high frequency hydraulic applications

    E-Print Network [OSTI]

    Roberts, David C. (David Christopher)

    2002-01-01T23:59:59.000Z

    A piezoelectrically-driven hydraulic amplification microvalve for use in high specific power hydraulic pumping applications was designed, fabricated, and experimentally characterized. High frequency, high force actuation ...

  14. Method for valve seating control for an electro-hydraulic engine valve

    DOE Patents [OSTI]

    Sun, Zongxuan (Plymouth, MN)

    2011-01-11T23:59:59.000Z

    Valve lift in an internal combustion engine is controlled by an electro-hydraulic actuation mechanism including a selectively actuable hydraulic feedback circuit.

  15. Thermally efficient melting for glass making

    DOE Patents [OSTI]

    Chen, Michael S. K. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary (Trexlertown, PA); Winchester, David C. (Allentown, PA)

    1991-01-01T23:59:59.000Z

    The present invention is an integrated process for the production of glass utilizing combustion heat to melt glassmaking materials in a glassmaking furnace. The fuel combusted to produce heat sufficient to melt the glassmaking materials is combusted with oxygen-enriched oxidant to reduce heat losses from the offgas of the glassmaking furnace. The process further reduces heat losses by quenching hot offgas from the glassmaking furnace with a process stream to retain the heat recovered from quench in the glassmaking process with subsequent additional heat recovery by heat exchange of the fuel to the glassmaking furnace, as well as the glassmaking materials, such as batch and cullet. The process includes recovery of a commercially pure carbon dioxide product by separatory means from the cooled, residual offgas from the glassmaking furnace.

  16. Preliminary Simulation of the Corrosion Rate of Archaeological Glass

    SciTech Connect (OSTI)

    Steefel, Carl

    2014-01-06T23:59:59.000Z

    In this study, we make use of a micro-continuum modeling approach (the Kinetic-Microscopic-Continuum Model or K{micro}C model) to capture the spatial distribution and identity of reaction products developing over time as a result of the archaeological glass corrosion, while also matching the time scales of alteration where possible. Since the glass blocks sat on the Mediterranean seafloor for 1800 years, the physical and chemical boundary conditions are largely constant. We focus on a fracture within the glass block identified by Verney-Carron et al. (2008) and simulate it as a 1D system, with a fixed concentration (Dirichlet) boundary corresponding to the interior of the fracture.

  17. Analysis of components from drip tests with ATM-10 glass

    SciTech Connect (OSTI)

    Fortner, J.A.; Bates, J.K.; Gerding, T.J.

    1996-09-01T23:59:59.000Z

    Waste package assemblies consisting of actinide-doped West Valley ATM-10 reference glass and sensitized 304L stainless steel have been reacted with simulated repository groundwater using the Unsaturated Test Method. Analyses of surface corrosion and reaction products resulting from tests that were terminated at scheduled intervals between 13 and 52 weeks are reported. Analyses reveal complex interactions between the groundwater, the sensitized stainless steel waste form holder, and the glass. Alteration phases form that consist mainly of smectite clay, brockite, and an amorphous thorium iron titanium silicate, the latter two incorporating thorium, uranium, and possibly transuranics. The results from the terminated tests, combined with data from tests that are still ongoing, will help determine the suitability of glass waste forms in the proposed high-level repository at the Yucca Mountain Site.

  18. Neutron Imaging Reveals Internal Plant Hydraulic Dynamics

    SciTech Connect (OSTI)

    Warren, Jeffrey [ORNL; Bilheux, Hassina Z [ORNL; Kang, Misun [ORNL; Voisin, Sophie [ORNL; Cheng, Chu-Lin [ORNL; Horita, Jusuke [ORNL; Perfect, Edmund [ORNL

    2013-01-01T23:59:59.000Z

    Many terrestrial ecosystem processes are constrained by water availability and transport within the soil. Knowledge of plant water fluxes is thus critical for assessing mechanistic processes linked to biogeochemical cycles, yet resolution of root structure and xylem water transport dynamics has been a particularly daunting task for the ecologist. Through neutron imaging, we demonstrate the ability to non-invasively monitor individual root functionality and water fluxes within Zea mays L. (maize) and Panicum virgatum L. (switchgrass) seedlings growing in a sandy medium. Root structure and growth were readily imaged by neutron radiography and neutron computed tomography. Seedlings were irrigated with water or deuterium oxide and imaged through time as a growth lamp was cycled on to alter leaf demand for water. Sub-millimeter scale resolution reveals timing and magnitudes of root water uptake, redistribution within the roots, and root-shoot hydraulic linkages, relationships not well characterized by other techniques.

  19. Geologic origin of magnetic volcanic glasses in the KBS tuff

    SciTech Connect (OSTI)

    Schlinger, C.M.; Smith, R.M.; Veblen, D.R.

    1986-11-01T23:59:59.000Z

    Volcanic glass shards and banded pumice from the KBS tuff of northern Kenya exhibit marked variations in magnetic susceptibility and color (colorless to dark brown). The darker glass shards exhibit superparamagnetism, which they now know to be carried by a population of tiny microcrystals of Fe-rich cubic oxide, approx. 20 to approx. 100 A in size, thought to be magnetite. A theory for their origin is one of nucleation and growth (precipitation) in quenched homogeneous glass (colorless) at temperatures of approx. 700-1000/sup 0/C during and immediately subsequent to eruption. Results from high-temperature heating experiments on KBS shards support this idea. The precipitate appears in the KBS shards as a consequence of their cooling history and is the origin of their coloring; the origin cannot lie in negligible compositional differences between the colorless and darkest shards. On the other hand, banded pumice from the KBS tuff has both dark and colorless glasses of differing compositions. The pumice appears banded because precipitation occurred preferentially in the Fe-rich glass. Although magma mixing may have played a role in the eruption of these materials, on the basis of their survey of distal eruptive products, it would appear that the volumetric amount of the mafic end member (dark pumice) was insubstantial.

  20. Hydraulic testing around Room Q: Evaluation of the effects of mining on the hydraulic properties of Salado Evaporites

    SciTech Connect (OSTI)

    Domski, P.S.; Upton, D.T. [INTERA, Inc., Albuquerque, NM (United States); Beauheim, R.L. [Sandia National Laboratories, Albuquerque, NM (United States)

    1996-03-01T23:59:59.000Z

    Room Q is a 109-m-long cylindrical excavation in the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site. Fifteen boreholes were drilled and instrumented around Room Q so that tests could be conducted to determine the effects of room excavation on the hydraulic properties of the surrounding evaporate rocks. Pressure-buildup and pressure-pulse tests were conducted in all of the boreholes before Room Q was mined. The data sets from only eight of the boreholes are adequate for parameter estimation, and five of those are of poor quality. Constant-pressure flow tests and pressure-buildup tests were conducted after Room Q was mined, producing eleven interpretable data sets, including two of poor quality. Pre-mining transmissivities interpreted from the three good-quality data sets ranged from 1 x 10{sup -15} to 5 x 10{sup -14} m{sup 2}/s (permeability-thickness products of 2 x 10{sup -22} to 9 x 10{sup -21} m{sup 3}) for test intervals ranging in length from 0.85 to 1.37 m. Pre-mining average permeabilities, which can be considered representative of undisturbed, far-field conditions, were 6 x 10{sup -20} and 8 x 10{sup -20} m{sup 2} for anhydrite, and 3 x 10{sup -22} m{sup 2} for halite. Post-mining transmissivities interpreted from the good-quality data sets ranged from 1 x 10{sup -16} to 3 x 10{sup -13} m{sup 2}/s (permeability-thickness products of 2 x 10{sup -23} to 5 x 10{sup -20} m{sup 3}). Post-mining average permeabilities for anhydrite ranged from 8 x 10{sup -20} to 1 x 10{sup -19} m{sup 2}. The changes in hydraulic properties and pore pressures that were observed can be attributed to one or a combination of three processes: stress reduction, changes in pore connectivity, and flow towards Room Q. The effects of the three processes cannot be individually quantified with the available data.

  1. Gas Test Loop Booster Fuel Hydraulic Testing

    SciTech Connect (OSTI)

    Gas Test Loop Hydraulic Testing Staff

    2006-09-01T23:59:59.000Z

    The Gas Test Loop (GTL) project is for the design of an adaptation to the Advanced Test Reactor (ATR) to create a fast-flux test space where fuels and materials for advanced reactor concepts can undergo irradiation testing. Incident to that design, it was found necessary to make use of special booster fuel to enhance the neutron flux in the reactor lobe in which the Gas Test Loop will be installed. Because the booster fuel is of a different composition and configuration from standard ATR fuel, it is necessary to qualify the booster fuel for use in the ATR. Part of that qualification is the determination that required thermal hydraulic criteria will be met under routine operation and under selected accident scenarios. The Hydraulic Testing task in the GTL project facilitates that determination by measuring flow coefficients (pressure drops) over various regions of the booster fuel over a range of primary coolant flow rates. A high-fidelity model of the NW lobe of the ATR with associated flow baffle, in-pile-tube, and below-core flow channels was designed, constructed and located in the Idaho State University Thermal Fluids Laboratory. A circulation loop was designed and constructed by the university to provide reactor-relevant water flow rates to the test system. Models of the four booster fuel elements required for GTL operation were fabricated from aluminum (no uranium or means of heating) and placed in the flow channel. One of these was instrumented with Pitot tubes to measure flow velocities in the channels between the three booster fuel plates and between the innermost and outermost plates and the side walls of the flow annulus. Flow coefficients in the range of 4 to 6.5 were determined from the measurements made for the upper and middle parts of the booster fuel elements. The flow coefficient for the lower end of the booster fuel and the sub-core flow channel was lower at 2.3.

  2. Improved Alumina Loading in High-Level Waste Glasses

    SciTech Connect (OSTI)

    Kim, D.; Vienna, J.D. [Pacific Northwest National Laboratory, Richland, WA (United States); Peeler, D.K.; Fox, K.M. [Savannah River National Laboratory, Aiken, SC (United States); Aloy, A.; Trofimenko, A.V. [V.G. Khlopin Radium Institute, St. Petersburg (Russian Federation); Gerdes, K.D. [EM-21, Office of Waste Processing, U.S. Department of Energy, Washington, DC (United States)

    2008-07-01T23:59:59.000Z

    Recent tank retrieval, blending, and treatment strategies at both the Savannah River Site (SRS) and Hanford have identified increased amounts of high-Al{sub 2}O{sub 3} waste streams that are scheduled to be processed through their respective high-level waste (HLW) vitrification facilities. It is well known that the addition of small amounts of Al{sub 2}O{sub 3} to borosilicate glasses generally enhances the durability of the waste glasses. However, at higher Al{sub 2}O{sub 3} concentrations nepheline (NaAlSiO{sub 4}) formation can result in a severe deterioration of the chemical durability of the slowly cooled glass near the center of the canister. Additionally, higher concentrations of Al{sub 2}O{sub 3} generally increase the liquidus temperature of the melt and decrease the processing rate. Pacific Northwest National Laboratory (PNNL), Savannah River National Laboratory (SRNL), and Khlopin Radium Institute (KRI) are jointly performing laboratory and scaled-melter tests, through US Department of Energy, EM-21 Office of Waste Processing program, to develop glass formulations with increased Al{sub 2}O{sub 3} concentrations. These glasses are formulated for specific DOE waste compositions at Hanford and Savannah River Site. The objectives are to avoid nepheline formation while maintaining or meeting waste loading and/or waste throughput expectations as well as satisfying critical process and product performance related constraints such as viscosity, liquidus temperature, and glass durability. This paper summarizes the results of recent tests of simulated Hanford HLW glasses containing up to 26 wt% Al{sub 2}O{sub 3} in glass. In summary: Glasses with Al{sub 2}O{sub 3} loading ranging from 25 to 27 wt% were formulated and tested at a crucible scale. Successful glass formulations with up to 26 wt% Al{sub 2}O{sub 3} that do not precipitate nepheline during CCC treatment and had spinel crystals 1 vol% or less after 24 hr heat treatment at 950 deg. C were obtained. The selected glass, HAL-17 with 26 wt% Al{sub 2}O{sub 3}, had viscosity and electrical conductivity within the boundaries for adequate processing in the Joule heated melters operated at 1150 deg. C. This HAL-17 glass was successfully processed using small-scale (SMK) and larger scale (EP-5) melters. There was no indication of spinel settling during processing. The product glass samples from these melter tests contained 1 to 4 vol% spinel crystals that are likely formed during cooling. The PCT tests on the product glasses are underway. The present study demonstrated that it is possible to formulate the glasses with up to 26 wt% Al{sub 2}O{sub 3} that satisfy the property requirements and is processable with Joule-heated melters operated at 1150 deg. C. The 'nepheline discriminator' for HAL-17 glass is 0.45, which supports that claim that the current rule ('nepheline discriminator' < 0.62) is too restrictive. Considering that the cost of HLW treatment is highly dependent on loading of waste in glass, this result provides a potential for significant cost saving for Hanford. The maximum Al{sub 2}O{sub 3} loading that can be achieved will also depend on concentrations of other components in wastes. For example, the loading of waste used in this study was also limited by the spinel crystallization after 950 deg. C 24 hr heat treatment, which suggests that the concentrations of spinel-forming components such as Fe{sub 2}O{sub 3}, Cr{sub 2}O{sub 3}, NiO, ZnO, and MnO would be critical in addition to Al{sub 2}O{sub 3} for the maximum Al{sub 2}O{sub 3} loading achievable. The observed glass production rate per unit melter surface area of 0.75 MT/(d.m{sup 2}) for SMK test is comparable to the design capacity of WTP HLW melters at 0.8 MT/(d.m{sup 2}). However, the test with EP-5 melter achieved 0.38 MT/(d.m{sup 2}), which is roughly a half of the WTP design capacity. This result may imply that the glass with 26 wt% Al{sub 2}O{sub 3} may not achieve the WTP design production rate. However, this hypothesis is not conclusive because of unknown effects of melter size and operation

  3. Nano-structured self-cleaning superhydrophobic glass

    E-Print Network [OSTI]

    Kim, Jin Yeol

    2010-01-01T23:59:59.000Z

    5. Optically transparent glass with vertically alignedcomposition of biosoluble glass fiber” Korean ApplicationS. Jin, “Optically Transparent Glass with Vertically Aligned

  4. Micro-Continuum Modeling of Nuclear Waste Glass Corrosion

    E-Print Network [OSTI]

    Steefel, Carl

    2014-01-01T23:59:59.000Z

    21. Grambow, B. (2006). Nuclear waste glasses – How durable?Continuum Modeling of Nuclear Waste Glass Corrosion AugustContinuum Modeling of Nuclear Waste Glass Corrosion Prepared

  5. Current Understanding and Remaining Challenges in Modeling Long-Term Degradation of Borosilicate Nuclear Waste Glasses

    SciTech Connect (OSTI)

    Vienna, John D. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Ryan, Joseph V. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Gin, Stephane [CEA Marcoule, DTCD SECM, Bagnols-sur-Ceze (France); Inagaki, Yaohiro [Dept. of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoda (Japan)

    2013-12-01T23:59:59.000Z

    Chemical durability is not a single material property that can be uniquely measured. Instead it is the response to a host of coupled material and environmental processes whose rates are estimated by a combination of theory, experiment, and modeling. High-level nuclear waste (HLW) glass is perhaps the most studied of any material yet there remain significant technical gaps regarding their chemical durability. The phenomena affecting the long-term performance of HLW glasses in their disposal environment include surface reactions, transport properties to and from the reacting glass surface, and ion exchange between the solid glass and the surrounding solution and alteration products. The rates of these processes are strongly influenced and are coupled through the solution chemistry, which is in turn influenced by the reacting glass and also by reaction with the near-field materials and precipitation of alteration products. Therefore, those processes must be understood sufficiently well to estimate or bound the performance of HLW glass in its disposal environment over geologic time-scales. This article summarizes the current state of understanding of surface reactions, transport properties, and ion exchange along with the near-field materials and alteration products influences on solution chemistry and glass reaction rates. Also summarized are the remaining technical gaps along with recommended approaches to fill those technical gaps.

  6. Replacement of petroleum based hydraulic fluids with a soybean-based alternative

    SciTech Connect (OSTI)

    Rose, B.; Rivera, P.

    1998-05-01T23:59:59.000Z

    Despite the best preventative measures, ruptured hoses, spills and leaks occur with use of all hydraulic equipment. Although these releases do not usually produce a RCRA regulated waste, they are often a reportable occurrence. Clean-up and subsequent administrative procedure involves additional costs, labor and work delays. Concerns over these releases, especially related to Sandia National Laboratories (SNL) vehicles hauling waste on public roads prompted Fleet Services (FS) to seek an alternative to the standard petroleum based hydraulic fluid. Since 1996 SNL has participated in a pilot program with the University of Iowa (UNI) and selected vehicle manufacturers, notably John Deere, to field test hydraulic fluid produced from soybean oil in twenty of its vehicles. The vehicles included loaders, graders, sweepers, forklifts and garbage trucks. Research was conducted for several years at UNI to modify and market soybean oils for industrial uses. Soybean oil ranks first in worldwide production of vegetable oils (29%), and represents a tremendous renewable resource. Initial tests with soybean oil showed excellent lubrication and wear protection properties. Lack of oxidative stability and polymerization of the oil were concerns. These concerns were being addressed through genetic alteration, chemical modification and use of various additives, and the improved lubricant is in the field testing stage.

  7. HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses

    SciTech Connect (OSTI)

    Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

    2012-04-02T23:59:59.000Z

    In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Matyáš et al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

  8. KJRR-FAI Hydraulic Flow Testing Input Package

    SciTech Connect (OSTI)

    N.E. Woolstenhulme; R.B. Nielson; D.B. Chapman

    2013-12-01T23:59:59.000Z

    The INL, in cooperation with the KAERI via Cooperative Research And Development Agreement (CRADA), undertook an effort in the latter half of calendar year 2013 to produce a conceptual design for the KJRR-FAI campaign. The outcomes of this effort are documented in further detail elsewhere [5]. The KJRR-FAI was designed to be cooled by the ATR’s Primary Coolant System (PCS) with no provision for in-pile measurement or control of the hydraulic conditions in the irradiation assembly. The irradiation assembly was designed to achieve the target hydraulic conditions via engineered hydraulic losses in a throttling orifice at the outlet of the irradiation vehicle.

  9. XRF and leaching characterization of waste glasses derived from wastewater treatment sludges

    SciTech Connect (OSTI)

    Ragsdale, R.G., Jr

    1994-12-01T23:59:59.000Z

    Purpose of this study was to investigate use of XRF (x-ray fluorescence spectrometry) as a near real-time method to determine melter glass compositions. A range of glasses derived from wastewater treatment sludges associated with DOE sites was prepared. They were analyzed by XRF and wet chemistry digestion with atomic absorption/inductively coupled emission spectrometry. Results indicated good correlation between these two methods. A rapid sample preparation and analysis technique was developed and demonstrated by acquiring a sample from a pilot-scale simulated waste glass melter and analyzing it by XRF within one hour. From the results, XRF shows excellent potential as a process control tool for waste glass vitrification. Glasses prepared for this study were further analyzed for durability by toxicity characteristic leaching procedure and product consistency test and results are presented.

  10. GLASS SELECTION STRATEGY: DEVELOPMENT OF US AND KRI TEST MATRICIES

    SciTech Connect (OSTI)

    Fox, K; Tommy Edwards, T; David Peeler, D

    2007-02-06T23:59:59.000Z

    High-level radioactive wastes are stored as liquids in underground storage tanks at the Department of Energy's (DOE) Savannah River Site (SRS) and Hanford Reservation. These wastes are to be prepared for permanent disposition in a geologic repository by vitrification with glass forming additives (e.g., frit), creating a waste form with long-term durability. Wastes at SRS are being vitrified in the Defense Waste Processing Facility (DWPF). Vitrification of the wastes stored at Hanford is planned for the Waste Treatment and Immobilization Plant (WTP) when completed. Some of the wastes at SRS, and particularly those at Hanford, contain high concentrations of aluminum, chromium and sulfate. These elements make it more difficult to produce a waste glass with a high waste loading (WL) without crystallization occurring in the glass (either within the melter or upon cooling of the glass), potentially exceeding the solubility limit of critical components, having negative impacts on durability, and/or resulting in the formation of a sulfate salt layer on the molten glass surface. Although the overall scope of the task is focused on all three critical, chemical components, the current work will primarily address the potential for crystallization (e.g., nepheline and/or spinel) in high level waste (HLW) glasses. Recent work at the Savannah River National Laboratory (SRNL) and by other groups has shown that nepheline (NaAlSiO{sub 4}), which is likely to crystallize in high-alumina glasses, has a detrimental effect on the durability of the glass. The objective of this task is to develop glass formulations for specific SRS and Hanford waste streams to avoid nepheline formation while meeting waste loading and waste throughput expectations, as well as satisfying critical process and product performance related constraints. Secondary objectives of this task are to assess the sulfate solubility limit for the DWPF composition and spinel settling for the WTP composition. SRNL has partnered with Pacific Northwest National Laboratory (PNNL) and the V.G. Khlopin Radium Institute (KRI) to complete this task.

  11. Which Parameters Control Production in Shale Assets? A Pattern Recognition Study

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    characteristics, completion, hydraulic fracturing, and production parameters for a large number of horizontal and hydraulic fracturing. While these practices have led to the economical productions of natural gases statistical analysis does not results in understandable trends and patterns. On the other hand, when advanced

  12. An implicit level set method for modeling hydraulically driven fractures Anthony Peirce a,*, Emmanuel Detournay b

    E-Print Network [OSTI]

    Peirce, Anthony

    An implicit level set method for modeling hydraulically driven fractures Anthony Peirce a the relevant tip asymptotics in hydraulic fracture simulators is critical for the accuracy and stability for a propagating hydraulic fracture. A number of char- acteristics of the governing equations for hydraulic

  13. Hydraulic Effects of Changes in Bottom-Land Vegetation on Three

    E-Print Network [OSTI]

    Hydraulic Effects of Changes in Bottom-Land Vegetation on Three Major Floods, Gila RiverKelvey, Director Library of Congress Cataloging in Publication Data Burkham, D. E. 1927 Hydraulic effects 19.16:655-J 1. Gila River-Floods. 2. Hydraulics. 3. Botany-Ecology-Gila River. 1. Title: Hydraulic

  14. Effects of hydraulic roughness on surface textures of gravel-bed rivers

    E-Print Network [OSTI]

    Effects of hydraulic roughness on surface textures of gravel-bed rivers John M. Buffington1 that bed-surface grain size is responsive to hydraulic roughness caused by bank irregularities, bars condition of low hydraulic roughness. For a given 0bf , channels with progressively greater hydraulic

  15. F. Froux et al.Hydraulic properties of Mediterranean conifers Original article

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    F. Froux et al.Hydraulic properties of Mediterranean conifers Original article Xylem hydraulic (Received 5 November 2001; accepted 11 February 2002) Abstract ­ We studied the xylem hydraulic traits specific hydraulic conductivity was much higher in Cupressus sempervirens and P. nigra than in Cedrus

  16. Analytical Results of DWPF Glass Sample Taken During Pouring of Canister S01913

    SciTech Connect (OSTI)

    Bannochie, C

    2005-10-01T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 2 (SB2) (Macrobatch 3) in December 2001 as part of Sludge Receipt and Adjustment Tank (SRAT) Batch 208. Macrobatch 3 consists of the contents of Tank 40 and Tank 8 in approximately equal proportions. A glass sample was obtained while pouring Canister S01913 and was sent to the Savannah River National Laboratory (SRNL) Shielded Cells for characterization. This report contains observations of the glass sample, results for the density, the chemical composition, the Product Consistency Test (PCT) and the radionuclide results needed for the Production Record for Canister S01913. The following conclusions are drawn from this work: (1) The glass sample taken during the filling of canister S01913 received at SRNL weighed 33.04 grams and was dark and reflective with no obvious inclusions indicating the glass was homogeneous. (2) The results of the composition for glass sample S01913 are in good agreement ({+-} 15%) with the DWPF SME results for Batch Number 254, the SME Batch that was being fed to the melter when the sample was collected. (3) The calculated WDF was 2.58. (4) Acid dissolution of the glass samples may not have completely dissolved the noble metals rhodium and ruthenium. (5) The PCT results for the glass (normalized boron release of 1.18 g/L) indicate that it is greater than seven standard deviations more durable than the EA glass; thus, the glass meets the waste acceptance criterion for durability. (6) The measured density of the glass was 2.56 {+-} 0.03 g/cm{sup 3}.

  17. Glass Transition in Confined Geometry

    E-Print Network [OSTI]

    Simon Lang; Vitalie Botan; Martin Oettel; David Hajnal; Thomas Franosch; Rolf Schilling

    2010-08-23T23:59:59.000Z

    Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting cases and requires as input solely the equilibrium density profile and the structure factors of the fluid in confinement. We evaluate the phase diagram as a function of the distance of the plates for the case of a hard sphere fluid and obtain an oscillatory behavior of the glass transtion line as a result of the structural changes related to layering.

  18. Thermal Hydraulics of the Very High Temperature Gas Cooled Reactor

    SciTech Connect (OSTI)

    Chang Oh; Eung Kim; Richard Schultz; Mike Patterson; Davie Petti

    2009-10-01T23:59:59.000Z

    The U.S Department of Energy (DOE) is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R&D) that will be critical to the success of the NGNP, primarily in the areas of: • High temperature gas reactor fuels behavior • High temperature materials qualification • Design methods development and validation • Hydrogen production technologies • Energy conversion. This paper presents current R&D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs.

  19. Effect of furnace atmosphere on E-glass foaming

    E-Print Network [OSTI]

    Kim, D. S.; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

    2006-01-01T23:59:59.000Z

    oxy-fired furnaces. E-glass foams were generated in a fused-81.05.K 1. Introduction Glass foams generated in glass-that the stability of E-glass foam decreased with increasing

  20. Hydraulic Fracture Monitoring: A Jonah Field Case Study

    E-Print Network [OSTI]

    Seher, T.

    2011-01-01T23:59:59.000Z

    Hydraulic fracturing involves the injection of a fluid to fracture oil and gas reservoirs, and thus increase their permeability. The process creates numerous microseismic events, which can be used to monitor subsurface ...

  1. Numerical Investigation of Interaction Between Hydraulic Fractures and Natural Fractures

    E-Print Network [OSTI]

    Xue, Wenxu

    2011-02-22T23:59:59.000Z

    Hydraulic fracturing of a naturally-fractured reservoir is a challenge for industry, as fractures can have complex growth patterns when propagating in systems of natural fractures in the reservoir. Fracture propagation near a natural fracture (NF...

  2. Studying Hydraulic Fracturing through Time-variant Seismic Anisotropy

    E-Print Network [OSTI]

    Liu, Qifan

    2013-10-01T23:59:59.000Z

    . Studying seismic anisotropy by shear wave splitting can help us better understand the relationship between hydraulic fracturing and fracture systems. Shear wave splitting can be caused by fracturing and also can naturally take place in most sedimentary...

  3. Shale Gas Application in Hydraulic Fracturing Market is likely...

    Open Energy Info (EERE)

    Shale Gas Application in Hydraulic Fracturing Market is likely to grow at a rate of 6.46%, owing to increased natural gas demand Home > Groups > Renewable Energy RFPs Wayne31jan's...

  4. The hydraulic bump: The surface signature of a plunging jet

    E-Print Network [OSTI]

    Labousse, M.

    When a falling jet of fluid strikes a horizontal fluid layer, a hydraulic jump arises downstream of the point of impact, provided a critical flow rate is exceeded. We here examine a phenomenon that arises below this jump ...

  5. On-line hydraulic state prediction for water distribution systems

    E-Print Network [OSTI]

    Whittle, Andrew

    This paper describes and demonstrates a method for on?line hydraulic state prediction in urban water networks. The proposed method uses a Predictor?Corrector (PC) approach in which a statistical data?driven algorithm is ...

  6. Fracture Evolution Following a Hydraulic Stimulation within an EGS Reservoir

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. This project will provide the first ever formal evaluation of fracture and fracture flow evolution in an EGS reservoir following a hydraulic stimulation.

  7. Hydraulically actuated gas exchange valve assembly and engine using same

    DOE Patents [OSTI]

    Carroll, Thomas S. (Peoria, IL); Taylor, Gregory O. (Hinsdale, IL)

    2002-09-03T23:59:59.000Z

    An engine comprises a housing that defines a hollow piston cavity that is separated from a gas passage by a valve seat. The housing further defines a biasing hydraulic cavity and a control hydraulic cavity. A gas valve member is also included in the engine and is movable relative to the valve seat between an open position at which the hollow piston cavity is open to the gas passage and a closed position in which the hollow piston cavity is blocked from the gas passage. The gas valve member includes a ring mounted on a valve piece and a retainer positioned between the ring and the valve piece. A closing hydraulic surface is included on the gas valve member and is exposed to liquid pressure in the biasing hydraulic cavity.

  8. Chile, 2009 HYDRAULIC MANAGEMENT OF FILAMENTOUS ALGAE IN

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    7 th ISE & 8 th HIC Chile, 2009 HYDRAULIC MANAGEMENT OF FILAMENTOUS ALGAE IN OPEN-CHANNEL NETWORKS mechanical interventions to avoid overflows. Moreover, drifting algae cells increase water turbidity

  9. INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2012-01-01T23:59:59.000Z

    ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE P.K. Mehta and P.Cement Manufacture from Oil Shale, U.S. Patent 2,904,445,203 (1974), E. D. York, Amoco Oil Co. , letter to J, P. Fox,

  10. Steady state thermal hydraulic analysis of hydride fueled BWRs

    E-Print Network [OSTI]

    Ferroni, Paolo, Ph. D. Massachusetts Institute of Technology

    2006-01-01T23:59:59.000Z

    (cont.) Since the results obtained in the main body of the analysis account only for thermal-hydraulic constraints, an estimate of the power reduction due to the application of neutronic constraints is also performed. This ...

  11. Water Use for Hydraulic Fracturing: A Texas Sized Problem? 

    E-Print Network [OSTI]

    LeClere, David

    2014-01-01T23:59:59.000Z

    The state of Texas could face a 2.7 trillion gallon shortfall of water by 2060. Hydraulic fracturing (HF) requires large amounts of water for each well. Tax incentives should be offered to companies that substitute brackish ...

  12. Development and Simulation of Mathematical Modelling of Hydraulic Turbine

    E-Print Network [OSTI]

    Gagan Singh; D. S. Chauhan

    Abstract- Power system performance is affected by dynamic characteristics of hydraulic governor-turbines during and following any disturbance, such as occurrence of a fault, loss of a transmission line or a rapid change of load. Accurate modelling of hydraulic System is essential to characterize and diagnose the system response. In this article the mathematical modeling of hydraulic turbine is presented. The model is capable to implement the digital systems for monitoring and control replacing the conventional control systems for power, frequency and voltage. This paper presents the possibilities of modeling and simulation of the hydro power plants and performs an analysis of different control structures and algorithms. Key words: mathematical modeling, simulation, hydraulic turbine. I.

  13. Adaptive control of hydraulic shift actuation in an automatic transmission

    E-Print Network [OSTI]

    Thornton, Sarah Marie

    2013-01-01T23:59:59.000Z

    A low-order dynamic model of a clutch for hydraulic control in an automatic transmission is developed by separating dynamics of the shift into four regions based on clutch piston position. The first three regions of the ...

  14. The Conservation of Seventeenth Century Archaeological Glass

    E-Print Network [OSTI]

    Arcak, Cory

    2010-10-12T23:59:59.000Z

    is the only chance for the objects survival. Though glass is considered one of the most stable archaeological materials, noninvasive, reversible treatments are not always possible given the level of deterioration glass objects undergo within the archaeological...

  15. The Huge, Blue, Jesus Glass Statue

    E-Print Network [OSTI]

    Robbins, Joanna

    2013-01-01T23:59:59.000Z

    Later, I found a huge, blue, glass statue of Jesus stuffedOF CALIFORNIA RIVERSIDE The Huge, Blue, Jesus Glass Statue Aeyes as RED And wrote down BLUE for your hair. I had to fix

  16. Structure glass technology : systems and applications

    E-Print Network [OSTI]

    Leitch, Katherine K. (Katherine Kristen)

    2005-01-01T23:59:59.000Z

    Glass cannot compete with steel in terms of strength or durability, but it is the only structural material that offers the highly sought after qualities of translucency and transparency. The use of glass has evolved from ...

  17. Crystallization in High-Level Waste Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R. (BATTELLE (PACIFIC NW LAB)); Dane R Spearing, Gary L Smith, SK Sundaram

    2002-01-01T23:59:59.000Z

    This review outlines important aspects of crystallization in HLW glasses, such as equilibrium, nucleation, growth, and dissolution. The impact of crystallization on continuous melters and the chemical durability of high-level waste glass are briefly discussed.

  18. Transparent glass honeycomb structures for energy loss control. Final summary report, January 1976-October 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    It has been demonstrated that properly-shaped glass honeycomb placed between a non-selective absorber and the coverglass of a flat plate solar collector gives collection efficiencies significantly higher than those of conventional flat plate units, even those with selective absorbers, collecting solar energy at temperatures required for heating and cooling buildings. Three basic glass honeycomb shapes were analyzed and tested: (1) thin-walled cylindrical glass tube honeycomb in square or hexagonal arrays, (2) corrugated thin glass sheets stacked peak-to-trough to form double-sinsuoid-shaped cells, and (3) flat thin glass sheets stacked to form long parallel slots. A continuous hot-rolling mill was used to corrugate commercial Micro-Sheet glass, thus demonstrating a key step needed for the commercialization of glass honeycomb fabrication. Experimental-scale (61 cm x 61 cm) collectors and collectors scaled-up in area were fabricated and tested outdoors to verify the analytical-numerical performance-prediction algorithms developed during the program. Optimization studies were made with respect to performance and cost to identify optimal shapes of sinusoidal-celled glass honeycombs which have high potential for mass production.

  19. Energy Efficiency Improvement and Cost Saving Opportunities for the Glass Industry. An ENERGY STAR Guide for Energy and Plant Managers

    SciTech Connect (OSTI)

    Galitsky, Christina; Worrell, Ernst; Galitsky, Christina; Masanet, Eric; Graus, Wina

    2008-03-01T23:59:59.000Z

    The U.S. glass industry is comprised of four primary industry segments--flat glass, container glass, specialty glass, and fiberglass--which together consume $1.6 billion in energy annually. On average, energy costs in the U.S. glass industry account for around 14 percent of total glass production costs. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There is a variety of opportunities available at individual plants in the U.S. glass industry to reduce energy consumption in a cost-effective manner. This Energy Guide discusses energy efficiency practices and energy-efficient technologies that can be implemented at the component, process, system, and organizational levels. A discussion of the trends, structure, and energy consumption characteristics of the U.S. glass industry is provided along with a description of the major process steps in glass manufacturing. Expected savings in energy and energy-related costs are given for many energy efficiency measures, based on case study data from real-world applications in glass production facilities and related industries worldwide. Typical measure payback periods and references to further information in the technical literature are also provided, when available. The information in this Energy Guide is intended to help energy and plant managers in the U.S. glass industry reduce energy consumption in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of the measures--as well on as their applicability to different production practices--is needed to assess potential implementation of selected technologies at individual plants.

  20. Integrated hydraulic cooler and return rail in camless cylinder head

    DOE Patents [OSTI]

    Marriott, Craig D. (Clawson, MI); Neal, Timothy L. (Ortonville, MI); Swain, Jeff L. (Flushing, MI); Raimao, Miguel A. (Colorado Springs, CO)

    2011-12-13T23:59:59.000Z

    An engine assembly may include a cylinder head defining an engine coolant reservoir, a pressurized fluid supply, a valve actuation assembly, and a hydraulic fluid reservoir. The valve actuation assembly may be in fluid communication with the pressurized fluid supply and may include a valve member displaceable by a force applied by the pressurized fluid supply. The hydraulic fluid reservoir may be in fluid communication with the valve actuation assembly and in a heat exchange relation to the engine coolant reservoir.

  1. Gravity-free hydraulic jumps and metal femtocups

    E-Print Network [OSTI]

    Rama Govindarajan; Manikandan Mathur; Ratul DasGupta; N. R. Selvi; Neena Susan John; G. U. Kulkarni

    2006-10-03T23:59:59.000Z

    Hydraulic jumps created by gravity are seen every day in the kitchen sink. We show that at small scales a circular hydraulic jump can be created in the absence of gravity, by surface tension. The theory is motivated by our experimental finding of a height discontinuity in spreading submicron molten metal droplets created by pulsed-laser ablation. By careful control of initial conditions, we show that this leads to solid femtolitre cups of gold, silver, copper, niobium and tin.

  2. Long-term hydraulic properties of subsurface flow constructed wetlands

    E-Print Network [OSTI]

    Turner, Glenn Allen

    1994-01-01T23:59:59.000Z

    Vegetation Hydraulic Design Removal Kinetics and Organic Loading Summary lvlATERIALS AND METHODS 5 5 6 . 15 . 16 . 17 RESULTS AND DISCUSSION . Sieve Analysis System Performance Hydraulic Conductivity Porosity Turbulent Flow Comparison of One... analysis of the bull rock. System Performance The operation of this research project generally seemed to be successful. However, there were a few problems with the operation of the appamtus which warrant attention. The major problems were leakage...

  3. Glass Transition and the Coulomb Gap in Electron Glasses M. Muller and L. B. Ioffe

    E-Print Network [OSTI]

    Müller, Markus

    Glass Transition and the Coulomb Gap in Electron Glasses M. Mu¨ller and L. B. Ioffe Department December 2004) We establish the connection between the presence of a glass phase and the appearance correlations in a systematic way, we show that in the case of strong disorder a continuous glass transition

  4. Process management using component thermal-hydraulic function classes

    DOE Patents [OSTI]

    Morman, James A. (Woodridge, IL); Wei, Thomas Y. C. (Downers Grove, IL); Reifman, Jaques (Western Springs, IL)

    1999-01-01T23:59:59.000Z

    A process management expert system where following malfunctioning of a component, such as a pump, for determining system realignment procedures such as for by-passing the malfunctioning component with on-line speeds to maintain operation of the process at full or partial capacity or to provide safe shut down of the system while isolating the malfunctioning component. The expert system uses thermal-hydraulic function classes at the component level for analyzing unanticipated as well as anticipated component malfunctions to provide recommended sequences of operator actions. Each component is classified according to its thermal-hydraulic function, and the generic and component-specific characteristics for that function. Using the diagnosis of the malfunctioning component and its thermal hydraulic class, the expert system analysis is carried out using generic thermal-hydraulic first principles. One aspect of the invention employs a qualitative physics-based forward search directed primarily downstream from the malfunctioning component in combination with a subsequent backward search directed primarily upstream from the serviced component. Generic classes of components are defined in the knowledge base according to the three thermal-hydraulic functions of mass, momentum and energy transfer and are used to determine possible realignment of component configurations in response to thermal-hydraulic function imbalance caused by the malfunctioning component. Each realignment to a new configuration produces the accompanying sequence of recommended operator actions. All possible new configurations are examined and a prioritized list of acceptable solutions is produced.

  5. Process management using component thermal-hydraulic function classes

    DOE Patents [OSTI]

    Morman, J.A.; Wei, T.Y.C.; Reifman, J.

    1999-07-27T23:59:59.000Z

    A process management expert system where following malfunctioning of a component, such as a pump, for determining system realignment procedures such as for by-passing the malfunctioning component with on-line speeds to maintain operation of the process at full or partial capacity or to provide safe shut down of the system while isolating the malfunctioning component. The expert system uses thermal-hydraulic function classes at the component level for analyzing unanticipated as well as anticipated component malfunctions to provide recommended sequences of operator actions. Each component is classified according to its thermal-hydraulic function, and the generic and component-specific characteristics for that function. Using the diagnosis of the malfunctioning component and its thermal hydraulic class, the expert system analysis is carried out using generic thermal-hydraulic first principles. One aspect of the invention employs a qualitative physics-based forward search directed primarily downstream from the malfunctioning component in combination with a subsequent backward search directed primarily upstream from the serviced component. Generic classes of components are defined in the knowledge base according to the three thermal-hydraulic functions of mass, momentum and energy transfer and are used to determine possible realignment of component configurations in response to thermal-hydraulic function imbalance caused by the malfunctioning component. Each realignment to a new configuration produces the accompanying sequence of recommended operator actions. All possible new configurations are examined and a prioritized list of acceptable solutions is produced. 5 figs.

  6. Geochemical comparison of impact glasses from lunar meteorites ALHA81005 and MAC88105 and Apollo 16 regolith 64001

    SciTech Connect (OSTI)

    Delano, J.W. (State Univ. of New York, Albany (United States))

    1991-11-01T23:59:59.000Z

    Most glasses that occur in lunar highland regolith are quenched droplets of impact melt. The chemical compositions of these glasses are equivalent, in the absence of volatile losses, to the original target materials. The compositional range of impact glasses in a regolith reflects the chemical diversity that existed throughout the region up to the time of system closure (e.g., breccia formation). Since these glasses are a product of widespread and random sampling, both in terms of space and time, they can be used for geochemical exploration of the Moon. The major-element compositions of impact glasses occurring in three samples of lunar feldspathic regolith (ALHA81005; MAC88105; Apollo 16 64001) have been determined by electron microprobe. The glass populations among these three unrelated samples are compositionally distinct. While most of the impact glasses within each of these three samples are compositionally similar to the regolith in which they are found, up to 40% of the impact glasses are different. Some of the compositionally exotic glasses were ballistically transported from other areas of the Moon and thereby provide information about the compositional range of regoliths that exist elsewhere. Since the geological setting of the Apollo 16 region is well known compared to the source areas of the lunar meteorites, the Apollo 16 glasses provide a ground truth for interpretations.

  7. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

    SciTech Connect (OSTI)

    Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

    2014-03-21T23:59:59.000Z

    Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

  8. The corrosion behavior of DWPF glasses

    SciTech Connect (OSTI)

    Ebert, W.L.; Bates, J.K. [Argonne National Lab., IL (United States). Chemical Technology Div.

    1995-06-01T23:59:59.000Z

    The authors analyzed the corroded surfaces of reference glasses developed for the Defense Waste Processing Facility (DWPF) to characterize their corrosion behavior. The corrosion mechanism of nuclear waste glasses must be known in order to provide source terms describing radionuclide release for performance assessment calculations. Different DWPF reference glasses were corroded under conditions that highlighted various aspects of the corrosion process and led to different extents of corrosion. The glasses corroded by similar mechanisms, and a phenomenological description of their corrosion behavior is presented here. The initial leaching of soluble glass components results in the formation of an amorphous gel layer on the glass surface. The gel layer is a transient phase that transforms into a layer of clay crystallites, which equilibrates with the solution as corrosion continues. The clay layer does not act as a barrier to either water penetration or glass dissolution, which continues beneath it, and may eventually separate from the glass. Solubility limits for glass components may be established by the eventual precipitation of secondary phases; thus, corrosion of the glass becomes controlled by the chemical equilibrium between the solution and the assemblage of secondary phases. In effect, the solution is an intermediate phase through which the glass transforms to an energetically more favorable assemblage of phases. Implications regarding the prediction of long-term glass corrosion behavior are discussed.

  9. High-Temperature Viscosity of Commercial Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2006-08-31T23:59:59.000Z

    Arrhenius models were developed for glass viscosity within the processing temperature of six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Both local models (for each of the six glass types) and a global model (for the composition region of commercial glasses, i.e., the six glass types taken together) are presented. The models are based on viscosity data previously obtained with rotating spindle viscometers within the temperature range between 900 C and 1550 C; the viscosity varied from 1 Pa?s to 750 Pa?s. First-order models were applied to relate Arrhenius coefficients to the mass fractions of 15 components: SiO2, TiO2, ZrO2, Al2O3, Fe2O3, B2O3, MgO, CaO, SrO, BaO, PbO, ZnO, Li2O, Na2O, K2O. The R2 is 0.98 for the global model and ranges from .097 to 0.99 for the six local models. The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100 C to 1550 C and viscosity range from 5 to 400 Pa?s.

  10. DURABLE GLASS FOR THOUSANDS OF YEARS

    SciTech Connect (OSTI)

    Jantzen, C.

    2009-12-04T23:59:59.000Z

    The durability of natural glasses on geological time scales and ancient glasses for thousands of years is well documented. The necessity to predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to various thermodynamic and kinetic approaches. Advances in the measurement of medium range order (MRO) in glasses has led to the understanding that the molecular structure of a glass, and thus the glass composition, controls the glass durability by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. During the early stages of glass dissolution, a 'gel' layer resembling a membrane forms through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer ages into clay or zeolite minerals by Ostwald ripening. Zeolite mineral assemblages (higher pH and Al{sup 3+} rich glasses) may cause the dissolution rate to increase which is undesirable for long-term performance of glass in the environment. Thermodynamic and structural approaches to the prediction of glass durability are compared versus Ostwald ripening.

  11. Precision diamond grinding of ceramics and glass

    SciTech Connect (OSTI)

    Smith, S.; Paul, H.; Scattergood, R.O.

    1988-12-01T23:59:59.000Z

    A new research initiative will be undertaken to investigate the effect of machine parameters and material properties on precision diamond grinding of ceramics and glass. The critical grinding depth to initiate the plastic flow-to-brittle fracture regime will be directly measured using plunge-grind tests. This information will be correlated with machine parameters such as wheel bonding and diamond grain size. Multiaxis grinding tests will then be made to provide data more closely coupled with production technology. One important aspect of the material property studies involves measuring fracture toughness at the very short crack sizes commensurate with grinding damage. Short crack toughness value`s can be much less than the long-crack toughness values measured in conventional fracture tests.

  12. Technical Note: Updated durability/composition relationships for Hanford high-level waste glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hartley, S.A.; Redgate, P.E.

    1996-03-01T23:59:59.000Z

    This technical note presents empirical models developed in FYI 995 to predict durability as functions of glass composition. Models are presented for normalized releases of B, Li, Na, and Si from the 7-day Product Consistency Test (PCT) applied to quenched and canister centerline cooled (CCC) glasses as well as from the 28-day Materials Characterization Center-1 (MCC-1) test applied to quenched glasses. Models are presented for Composition Variation Study (CVS) data from low temperature melter (LTM) studies (Hrma, Piepel, et al. 1994) and high temperature melter (HTM) studies (Vienna et al. 1995). The data used for modeling in this technical note are listed in Appendix A.

  13. HYDRAULIC CONDUCTIVITY OF SALTSTONE FORMULATED USING 1Q11, 2Q11 AND 3Q11 TANK 50 SLURRY SAMPLES

    SciTech Connect (OSTI)

    Reigel, M.; Nichols, R.

    2012-06-27T23:59:59.000Z

    As part of the Saltstone formulation work requested by Waste Solidification Engineering (WSE), Savannah River National Laboratory (SRNL) was tasked with preparing Saltstone samples for fresh property analysis and hydraulic conductivity measurements using actual Tank 50 salt solution rather than simulated salt solution. Samples of low level waste salt solution collected from Tank 50H during the first, second, and third quarters of 2011 were used to formulate the Saltstone samples. The salt solution was mixed with premix (45 wt % slag, 45 wt % fly ash, and 10 wt % cement), in a ratio consistent with facility operating conditions during the quarter of interest. The fresh properties (gel, set, bleed) of each mix were evaluated and compared to the recommended acceptance criteria for the Saltstone Production Facility. ASTM D5084-03, Method C was used to measure the hydraulic conductivity of the Saltstone samples. The hydraulic conductivity of Saltstone samples prepared from 1Q11 and 2Q11 samples of Tank 50H is 4.2E-9 cm/sec and 2.6E-9 cm/sec, respectively. Two additional 2Q11 and one 3Q11 sample were not successfully tested due to the inability to achieve stable readings during saturation and testing. The hydraulic conductivity of the samples made from Tank 50H salt solution compare well to samples prepared with simulated salt solution and cured under similar conditions (1.4E-9 - 4.9E-8 cm/sec).

  14. Glass-ceramic material and method of making

    DOE Patents [OSTI]

    Meinhardt, Kerry D [Richland, WA; Vienna, John D [West Richland, WA; Armstrong, Timothy R [Pasco, WA; Pederson, Larry R [Kennewick, WA

    2002-08-13T23:59:59.000Z

    The present invention is a glass-ceramic material and method of making useful for joining at least two solid ceramic parts. The seal is a blend of M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 system can be used to join or seal both tubular and planar ceramic solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

  15. Comprehensive data base of high-level nuclear waste glasses: September 1987 status report: Volume 1, Discussion and glass durability data

    SciTech Connect (OSTI)

    Kindle, C.H.; Kreiter, M.R.

    1987-12-01T23:59:59.000Z

    The Materials Characterization Center (MCC) at Pacific Northwest Laboratory is assembling a comprehensive data base (CDB) of experimental data collected for high-level nuclear waste package components. Data collected throughout the world are included in the data base; current emphasis is on waste glasses and their properties. The goal is to provide a data base of properties and compositions and an analysis of dominant property trends as a function of composition. This data base is a resource that nuclear waste producers, disposers, and regulators can use to compare properties of a particular high-level nuclear waste glass product with the properties of other glasses of similar compositions. Researchers may use the data base to guide experimental tests to fill gaps in the available knowledge or to refine empirical models. The data are incorporated into a computerized data base that will allow the data to be extracted based on, for example, glass composition or test duration. 3 figs.

  16. IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT08, KT09, AND KT10-SERIES GLASS COMPOSITIONS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2011-04-26T23:59:59.000Z

    This report is the fourth in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. The KT09-series of glasses was designed to study the effect of increasing Al{sub 2}O{sub 3} and K{sub 2}O concentrations on the propensity for crystallization of titanium containing phases in high TiO{sub 2} concentration glasses. Earlier work on the KT05-series glasses recommended that the impact of these two components be studied further. Increased Al{sub 2}O{sub 3} concentrations have been shown to improve the properties and performance of high waste loading glasses, and K{sub 2}O has been reported to improve the retention of TiO{sub 2} in silicate glasses. The KT10-series of compositions was designed to evaluate any impacts of the SCIX components at concentrations 50% higher than currently projected.a The glasses were fabricated in the laboratory and characterized to identify crystallization, to verify chemical compositions, to measure viscosity, and to measure durability. Liquidus temperature measurements for the KT10-series glasses are underway and will be reported separately. All but one of the KT08-series glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which had no practical impact on the durability of the glass and is typically found in DWPF-type glasses. The measured Product Consistency Test (PCT) responses for the KT08-series glasses are well predicted by the DWPF models. The viscosities of the KT08-series glasses were generally well predicted by the DWPF model. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components. Increased Al{sub 2}O{sub 3} concentrations were not successful in preventing the formation of iron titanate crystals in the KT09-series glasses. Increased K{sub 2}O concentrations were successful in hindering the formation of iron titanates in some of the glasses after the canister centerline cooled (CCC) heat treatment. However, this result did not apply to all of the CCC versions of the glasses, indicating a compositional dependence of this effect. In addition, high concentrations of K{sub 2}O have been shown to hinder the ability of the DWPF durability and viscosity models to predict the performance of these glasses. The usefulness of increased K{sub 2}O concentrations in preventing the formation of iron titanates may therefore be limited. Further characterization was not performed for the KT09-series glasses since the type of crystallization formed was the characteristic of interest for these compositions. All of the KT10-series glasses were XRD amorphous, regardless of heat treatment. Chemical composition measurements showed that the glasses met the targeted concentrations for each oxide. In general, the measured PCT responses of the KT10-series glasses were well predicted by the DWPF models. The measured, normalized release values for silicon for some of the glasses fell above the 95% confidence interval for the predicted values; however, the PCT responses for these glasses remain considerably lower than that of the benchmark Environmental Assessment (EA) glass. The viscosities of the KT10-series glasses were generally well predicted by the DWPF model. The next step in this study will be to compile all of the data developed and further compare the measured properties and performance with those predicted by the current DWPF Product Composition Control System (PCCS) models. Recommendations will then be made as to which models, if any, may need to be modified in order to accommodate the material from SCIX into DWPF

  17. Numerical and physical modeling of hydraulic structures Hydraulic structures are used to control the flow of water in hydropower developments, urban

    E-Print Network [OSTI]

    Barthelat, Francois

    Numerical and physical modeling of hydraulic structures Hydraulic structures are used to control, their solution is found either by physical hydraulic modeling or, more recently, by numerical modeling significantly reduce turbine efficiency and cause premature mechanical failure when they occur at hydropower

  18. METHOD DEVELOPMENT FOR DETERMINING THE HYDRAULIC CONDUCTIVITY OF FRACTURED POROUS MEDIA

    SciTech Connect (OSTI)

    Dixon, K.

    2013-09-30T23:59:59.000Z

    Plausible, but unvalidated, theoretical model constructs for unsaturated hydraulic conductivity of fractured porous media are currently used in Performance Assessment (PA) modeling for cracked saltstone and concrete (Flach 2011). The Nuclear Regulatory Commission (NRC) has expressed concern about the lack of model support for these assumed Moisture Characteristic Curves (MCC) data, as noted in Requests for Additional Information (RAIs) PA-8 and SP-4 (Savannah River Remediation, LLC, 2011). The objective of this task was to advance PA model support by developing an experimental method for determining the hydraulic conductivity of fractured cementitious materials under unsaturated conditions, and to demonstrate the technique on fractured saltstone samples. The task was requested through Task Technical Request (TTR) HLW-SSF-TTR-2012-0016 and conducted in accordance with Task Technical & Quality Assurance Plan (TTQAP) SRNL-TR-2012-00090. Preliminary method development previously conducted by Kohn et al. (2012) identified transient outflow extraction as the most promising method for characterizing the unsaturated properties of fractured porous media. While the research conducted by Kohn et al. (2012) focused on fractured media analogs such as stacked glass slides, the current task focused directly on fractured saltstone. For this task, four sample types with differing fracture geometries were considered: 1) intact saltstone, 2) intact saltstone with a single saw cut, smooth surface fracture, 3) micro-fractured saltstone (induced by oven drying), and 4) micro-fractured saltstone with a single, fully-penetrating, rough-surface fracture. Each sample type was tested initially for saturated hydraulic conductivity following method ASTM D 5084 using a flexible wall permeameter. Samples were subsequently tested using the transient outflow extraction method to determine cumulative outflow as a function of time and applied pressure. Of the four sample types tested, two yielded datasets suitable for analysis (sample types 3 and 4). The intact saltstone sample (sample type 1) did not yield any measureable outflow over the pressure range of the outflow test (0-1000 cm H{sub 2}O). This was expected because the estimated air entry pressure for intact saltstone is on the order of 100,000 cm H{sub 2}O (Dixon et al., 2009). The intact saltstone sample with a single saw cut smooth surface fracture (sample type 2) did not produce useable data because the fracture completely drained at less than 10 cm H{sub 2}O applied pressure. The cumulative outflow data from sample types 3 and 4 were analyzed using an inverse solution of the Richard’s equation for water flow in variably saturated porous media. This technique was implemented using the computer code Hydrus-1D (Šim?nek et al., 2008) and the resulting output included the van Genuchten-Mualem water retention and relative permeability parameters and predicted saturated hydraulic conductivity (Van Genuchten, 1980; Van Genuchten et al., 1991). Estimations of relative permeability and saturated conductivity are possible because the transient response of the sample to pressure changes is recorded during the multi-step outflow extraction test. Characteristic curves were developed for sample types 3 and 4 based on the results of the transient outflow method and compared to that of intact saltstone previously reported by Dixon et al. (2009). The overall results of this study indicate that the outflow extraction method is suitable for measuring the hydraulic properties of micro-fractured porous media. The resulting cumulative outflow data can be analyzed using the computer code Hydrus-1D to generate the van Genuchten curve fitting parameters that adequately describe fracture drainage. The resulting characteristic curves are consistent with blended characteristic curves that combine the behaviors of low pressure drainage associated with fracture flow with high pressure drainage from the bulk saltstone matrix.

  19. Analysis of Sludge Batch 3 (Macrobatch4) DWPF Pour Stream Glass Sample for Canister s02312

    SciTech Connect (OSTI)

    Bannochie, C

    2005-09-01T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 3 (SB3), Macrobatch 4 (MB4) in March 2004 as part of Sludge Receipt and Adjustment Tank (SRAT) Batch 272. Sludge Batch 3 is a blend of the contents Tank 40 remaining from Sludge Batch 2 (SB2), the sludge that was transferred to Tank 40 from Tank 51 and Canyon Np solution additions made directly to Tank 40. The sludge transferred from Tank 51 contained sludges from Tanks 7, 18 and 19 along with precipitated solutions of U, Pu/Gd and Am/Cm from the F and H Canyons. The blend of sludge from Tank 51, Tank 40, and the Canyon additions defines SB3 (or MB4). The sludge slurry is received into the DWPF Chemical Processing Cell (CPC) and is processed through the SRAT and Slurry Mix Evaporator (SME) Tank and fed to the melter. During the processing of each sludge batch, the DWPF is required to take at least one glass sample. This glass sample is taken to meet the objectives of the Glass Product Control Program and complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. Two glass samples were obtained while pouring Canisters S02312 and S02315 which were sent to the Savannah River National Laboratory's (SRNL) Shielded Cells Facility. Sample S02312 was designated for analysis, while sample S02315 was designated for archival storage. This report contains the visual observations of the as-received glass sample, results for the density, chemical composition, the Product Consistency Test (PCT) and the calculated and measured radionuclide results needed for the Production Record for Canister S02312. The following conclusions were drawn from the examination of this DWPF pour stream glass sample: (1) The glass sample taken during the filling of DWPF Canister S02312 weighed 41.69 g and was generally dark and reflective. (2) Minor inclusions, on the order of 1 {micro}m in size, of noble metals were seen in the glass via contained scanning electron microscopy and confirmed from their x-ray fluorescence spectra. (3) The results for the composition of glass sample S02312, except for U, are in reasonable agreement (15% or better) with the DWPF SME Batch 319 results, the SME batch being fed to the melter when the sample was collected. (4) The calculated waste dilution factor (WDF) was 2.19. The measured values of the radionuclides and noble metals in the glass sample generally corresponded well with the calculated values determined using sludge slurry results from Reference 9 and the WDF. (5) The noble metal content of the glass indicates that the noble metals are largely swept from the melter with the glass based upon the noble metals analyzed in the glass and those predicted in the sludge from the WDF. (6) Comparison of the noble metal results for the two digestion methods (mixed acid and alkali fusion) indicates that the alkali fusion method is preferred for the determination of noble metals in glass. (7) The PCT results for the glass (normalized release of B: 1.09 g/L, Na: 1.03 g/L, and Li: 0.94 g/L) indicate that it meets the waste acceptance criterion for durability. (8) The normalized release rates for the measured radionuclides were less than those for the major soluble elements in the waste (B, Na, and Li) with the exception of Tc-99 which was released at a rate similar to that the soluble elements in the leachate. (9) The measured density of the glass was 2.58 {+-} 0.11 g/cm{sup 3}.

  20. Iron phosphate glass for immobilization of 99Tc

    SciTech Connect (OSTI)

    Xu, Kai; Hrma, Pavel R.; Um, Wooyong; Heo, Jong

    2013-06-15T23:59:59.000Z

    Technetium-99 (99Tc) can bring serious environmental threats because of its long half-life (t1/2 = ~2.1 x 105 years), high fission yield (~6%), and high solubility and mobility in the ground water. The high volatility makes it difficult to immobilize 99Tc in continuous melters vitrifying 99Tc-containing nuclear wastes in borosilicate glasses. This work explores a possibility of incorporating a high concentration of 99Tc, surrogated by the non-radioactive Re, in an iron phosphate glass by melting mixtures of iron phosphate glass frits with 1.5-6 mass% KReO4 at ~1000 C. The retention of Re achieved was ~1.1 mass%. The normalized Re release by the 7-day Product Consistency Test was <10*2 g/m2. Surprisingly, the Re escaped from the melt within a short time of heating, especially when the temperature was increased. Therefore, 99Tc volatilization would still be a challenging task for its immobilization in iron phosphate glasses.

  1. CHEMICAL COMPOSITION AND PCT DATA FOR THE INITIAL SET OF HANFORD ENHANCED WASTE LOADING GLASSES

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2014-06-02T23:59:59.000Z

    In this report, the Savannah River National Laboratory provides chemical analyses and Product Consistency Test results for 20 simulated high level waste glasses fabricated by the Pacific Northwest National Laboratory. The results of these analyses will be used as part of efforts to revise or extend the validation ranges of the current Hanford Waste Treatment and Immobilization Plant glass property models to cover a broader span of waste compositions. The measured chemical composition data are reported and compared with the targeted values for each component for each glass. Two components of the study glasses, fluorine and silver, were not measured since each of these species would have required the use of an additional preparation method and their measured values were likely to be near or below analytical detection limits. Some of the glasses were difficult to prepare for chemical analysis. A sodium peroxide fusion dissolution method was successful in completely dissolving the glasses. Components present in the glasses in minor concentrations can be difficult to measure using this dissolution method due to dilution requirements. The use of a lithium metaborate preparation method for the minor components (planned for use since it is typically successful in digesting Defense Waste Processing Facility HLW glasses) resulted in an unacceptable amount of undissolved solids remaining in the sample solutions. An acid dissolution method was used instead, which provided more thorough dissolution of the glasses, although a small amount of undissolved material remained for some of the study glasses. The undissolved material was analyzed to determine those components of the glasses that did not fully dissolve. These components (e.g., calcium and chromium) were present in sufficient quantities to be reported from the measurements resulting from the sodium peroxide fusion preparation method, which did not leave undissolved material. Overall, the analyses resulted in sums of oxides that ranged from about 98 to 101.5 wt % for the study glasses, indicating excellent recovery of all the components in the chemical composition analyses. Comparisons of the targeted and measured chemical compositions indicated that, in general, the measured values for the glasses met the targeted concentrations. Exceptions were Cr{sub 2}O{sub 3}, MgO, and P{sub 2}O{sub 5}. The measured values for Cr{sub 2}O{sub 3} were somewhat low when compared to the targeted values for all of the study glasses targeting Cr{sub 2}O{sub 3} concentrations above 0.5 wt %. Many of the measured MgO and P{sub 2}O{sub 5} values were below the targeted values for those glasses that contained these components. Two of the study glasses exhibited differences from the targeted compositions that may indicate a batching error. Glasses EWG-HAI-Centroid-2 and EWG-OL-1672 had measured values for Al{sub 2}O{sub 3} and SiO{sub 2} that were lower than the targeted values, and measured values for B{sub 2}O{sub 3} that were higher than the targeted values. Glass EWG-HAI-Centroid-2 also had a measured value for Fe{sub 2}O{sub 3} that was lower than the targeted value. A review of the PCT data, including standards and blanks, revealed no issues with the performance of the tests. The PCT results were normalized to both the targeted and measured compositions of the study glasses. Comparisons of the normalized PCT results for both the quenched and Canister Centerline Cooled versions of the study glasses are made with the Environmental Assessment benchmark glass for reference.

  2. Recirculation bubbler for glass melter apparatus

    DOE Patents [OSTI]

    Guerrero, Hector (Evans, GA); Bickford, Dennis (Folly Beach, SC)

    2007-06-05T23:59:59.000Z

    A gas bubbler device provides enhanced recirculation of molten glass within a glass melter apparatus. The bubbler device includes a tube member disposed within a pool of molten glass contained in the melter. The tube member includes a lower opening through which the molten glass enters and upper slots disposed close to (above or below) the upper surface of the pool of molten glass and from which the glass exits. A gas (air) line is disposed within the tube member and extends longitudinally thereof. A gas bubble distribution device, which is located adjacent to the lower end of the tube member and is connected to the lower end of the gas line, releases gas through openings therein so as to produce gas bubbles of a desired size in the molten glass and in a distributed pattern across the tube member.

  3. Fabrication and characterization of MCC (Materials Characterization Center) approved testing material: ATM-10 glass

    SciTech Connect (OSTI)

    Maupin, G.D.; Bowen, W.M.; Daniel, J.L.

    1988-04-01T23:59:59.000Z

    The Materials Characterization Center ATM-10 glass represents a reference commercial high-level waste form similar to that which will be produced by the West Valley Nuclear Service Co. Inc., West Valley, New York. The target composition and acceptable range of composition were defined by the sponsor, West Valley Nuclear Service. The ATM-10 glass was produced in accordance with the Pacific Northwest Laboratory QA Manual for License-Related Programs, MCC technical procedures, and MCC QA Plan that were in effect during the course of the work. The method and procedure to be used in the fabrication and characterization of the ATM-10 glass were specified in two run plans for glass preparation and a characterization plan. All of the ATM-10 glass was produced in the form of bars 1.9 /times/ 1.9 /times/ 10 cm nominal size, and 93 g nominal mass. A total of 15 bars of ATM-10 glass weighing 1394 g was produced. The production bars were characterized to determine the mean composition, oxidation state, and microstructure of the ATM-10 product. Table A summarizes the characterization results. The ATM-10 glass meets all specifications. The elemental composition and oxidation state of the glass are within the specifications of the client. Visually, the ATM-10 glass bars appear uniformly glassy and generally without exterior features. Microscopic examination revealed low (less than 2 wt %) concentractions of 3-..mu..m iron-chrome (suspected spinel) crystals and /approximately/0.5-..mu..m ruthenium inclusions scattered randomly throughout the glassy matrix. Closed porosity, with pores ranging in diameter from 5 to 250 ..mu..m, was observed in all samples. 4 refs., 10 figs., 21 tabs.

  4. Shale gas production: potential versus actual greenhouse gas emissions

    E-Print Network [OSTI]

    O’Sullivan, Francis Martin

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

  5. Shale Gas Production: Potential versus Actual GHG Emissions

    E-Print Network [OSTI]

    O'Sullivan, Francis

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during ...

  6. Enhanced luminescence in Er3+ -doped chalcogenide glass-ceramics based on selenium

    E-Print Network [OSTI]

    Boyer, Edmond

    *laurent.calvez@univ-rennes1.fr Tel: (33) 2 23 23 67 13 Fax: (33) 2 23 23 56 11 b Arizona Materials. These materials are promising candidates for the production of new laser sources in the mid-infrared region of chalcogenide glasses presents two major advantages for the production of laser materials operating

  7. New Strontium-based Bioactive Glasses: Physicochemical Reactivity and Delivering Capability

    E-Print Network [OSTI]

    Boyer, Edmond

    products capable of stimulating cellular responses. In this paper, we report a complete evaluation of Biologically Active Dissolution Products Jonathan Lao , Edouard Jallot , and Jean-Marie Nedelec Laboratoire-doped glasses in treatment of osteoporosis and tissue engineering. hal-00395384,version1-15Jun2009 #12

  8. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, T.D.

    1993-12-14T23:59:59.000Z

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes. 3 figures.

  9. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, Terrance D. (617 Chestnut Ct., Aiken, SC 29803)

    1993-01-01T23:59:59.000Z

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes.

  10. Glass Transition, Cooperativity and Interfaces

    E-Print Network [OSTI]

    Salez, Thomas; Dalnoki-Veress, Kari; Raphaël, Elie; Forrest, James A

    2015-01-01T23:59:59.000Z

    We introduce a minimal theory of glass formation based on the physical ideas of molecular crowding and resultant cooperative motion, and address the effects of free interfaces on dynamics. First, we obtain a simple scaling expression for the diverging number of particles taking part in bulk cooperative relaxation as the system approaches kinetic arrest, and in doing so provide a robust derivation of the Adam and Gibbs description of cooperative dynamics. Then, by including thermal expansivity of the material, the Vogel-Fulcher-Tammann relation is derived. Moreover, we predict a temperature-dependent expression for the cooperative length $\\xi$ of bulk relaxation, and explore the influence of sample boundaries on the glassy dynamics when the system size becomes comparable to $\\xi$. The theory is in full agreement with measurements of the glass transition temperature of thin polystyrene films. This agreement comes with two adjustable parameters, the critical interparticle distance and the Vogel temperature. Alth...

  11. Color Glass Condensate and Glasma

    E-Print Network [OSTI]

    F. Gelis

    2012-11-26T23:59:59.000Z

    We review the Color Glass Condensate effective theory, that describes the gluon content of a high energy hadron or nucleus, in the saturation regime. The emphasis is put on applications to high energy heavy ion collisions. After describing initial state factorization, we discuss the Glasma phase, that precedes the formation of an equilibrated quark-gluon plasma. We end this review with a presentation of recent developments in the study of the isotropization and thermalization of the quark-gluon plasma.

  12. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  13. Method for heating, forming and tempering a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI); Sitzman, Gary W. (Walled Lake, MI)

    1998-01-01T23:59:59.000Z

    A method for heating, forming and tempering a glass sheet including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet.

  14. Method for heating, forming and tempering a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.; Sitzman, G.W.

    1998-10-27T23:59:59.000Z

    A method for heating, forming and tempering a glass sheet is disclosed including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet. 2 figs.

  15. The formation of crystals in glasses containing rare earth oxides

    SciTech Connect (OSTI)

    Fadzil, Syazwani Mohd [Pohang University of Science and Technology (POSTECH), Pohang (Korea, Republic of); Hrma, Pavel [Pohang University of Science and Technology (POSTECH), Pohang, South Korea and Pacific Northwest National Laboratory, Richland, Washington (United States); Crum, Jarrod [Pacific Northwest National Laboratory, Richland, Washington (United States); Siong, Khoo Kok; Ngatiman, Mohammad Fadzlee; Said, Riduan Mt [National University of Malaysia, Bandar Baru Bangi, Selangor (Malaysia)

    2014-02-12T23:59:59.000Z

    Korean spent nuclear fuel will reach the capacity of the available temporary storage by 2016. Pyroprocessing and direct disposal seems to be an alternative way to manage and reuse spent nuclear fuel while avoiding the wet reprocessing technology. Pyroprocessing produces several wastes streams, including metals, salts, and rare earths, which must be converted into stabilized form. A suitable form for rare earth immobilization is borosilicate glass. The borosilicate glass form exhibits excellent durability, allows a high waste loading, and is easy to process. In this work, we combined the rare earths waste of composition (in wt%) 39.2Nd{sub 2}O{sub 3}–22.7CeO{sub 2}–11.7La{sub 2}O{sub 3}–10.9PrO{sub 2}–1.3Eu{sub 2}O{sub 3}–1.3Gd{sub 2}O{sub 3}–8.1Sm{sub 2}O{sub 3}–4.8Y{sub 2}O{sub 3} with a baseline glass of composition 60.2SiO{sub 2}–16.0B{sub 2}O{sub 3}–12.6Na{sub 2}O–3.8Al{sub 2}O{sub 3}–5.7CaO–1.7ZrO{sub 2}. Crystallization in waste glasses occurs as the waste loading increases. It may produce complicate glass processing and affect the product quality. To study crystal formation, we initially made glasses containing 5%, 10% and 15% of La{sub 2}O{sub 3} and then glasses with 5%, 10% and 15% of the complete rare earth mix. Samples were heat-treated for 24 hours at temperatures 800°C to 1150°C in 50°C increments. Quenched samples were analyzed using an optical microscope, scanning electron microscope with energy dispersive spectroscopy, and x-ray diffraction. Stillwellite (LaBSiO{sub 5}) and oxyapatite (Ca{sub 2}La{sub 8}Si{sub 6}O{sub 26}) were found in glasses containing La{sub 2}O{sub 3}, while oxyapatite (Ca{sub 2}La{sub 8}Si{sub 6}O{sub 26} and NaNd{sub 9}Si{sub 6}O{sub 26}) precipitated in glasses with additions of mixed rare earths. The liquidus temperature (T{sub L}) of the glasses containing 5%, 10% and 15% La{sub 2}O{sub 3} were 800°C, 959°C and 986°C, respectively; while T{sub L} was 825°C, 1059°C and 1267°C for glasses with 5%, 10% and 15% addition of mixed rare earth oxides. The component coefficients T{sub B2O3}, T{sub SiO2}, T{sub CaO}, and T{sub RE2O3} were also evaluated using a recently published study.

  16. MAGNOX:BUTEX URANIUM BEARING GLASSES PHYSICAL AND CHEMICAL ANALYSIS DATA PACKAGE

    SciTech Connect (OSTI)

    Peeler, D.; Imrich, K.; Click, D.

    2011-03-08T23:59:59.000Z

    Sellafield Ltd (United Kingdom) has requested technical support from the Savannah River National Laboratory (SRNL) to characterize a series of uranium-bearing, mixed alkali borosilicate glasses [WFO (2010)]. The specific glasses to be characterized are based on different blends of Magnox (WRW17 simulant) and Butex (or HASTs 1 and 2) waste types as well as different incorporation rates (or waste loadings) of each blend. Specific Magnox:Butex blend ratios of interest include: 75:25, 60:40, and 50:50. Each of these waste blend ratios will be mixed with a base glass additive composition targeting waste loadings (WLs) of 25, 28, and 32% which will result in nine different glasses. The nine glasses are to be fabricated and physically characterized to provide Sellafield Ltd with the technical data to evaluate the impacts of various Magnox:Butex blend ratios and WLs on key glass properties of interest. It should be noted that the use of 'acceptable' in the Work for Other (WFO) was linked to the results of a durability test (more specifically the Soxhlet leach test). Other processing (e.g., viscosity ({eta}), liquidus temperature (T{sub L})) or product performance (e.g., Product Consistency Test (PCT) results - in addition to the Soxhlet leach test) property constraints were not identified. For example, a critical hold point in the classification of an 'acceptable glass' prior to processing high-level waste (HLW) through the Defense Waste Processing Facility (DWPF) is an evaluation of specific processing and product performance properties against pre-defined constraints. This process is referred to as Slurry Mix Evaporator (SME) acceptability in which predicted glass properties (based on compositional measurements) are compared to predefined constraints to determine whether the glass is acceptable [Brown and Postles (1995)]. As an example, although the nominal melter temperature at DWPF is 1150 C, there is a T{sub L} constraint (without uncertainties applied) of 1050 C. Any glass which has a T{sub L} predicted value > 1050 C would be classified as unacceptable and the SME product would not be transferred to the melter. As another example, consider durability (as defined by the PCT test) and its related constraints to determine acceptability. If the glass composition yields predicted normalized release values that exceed those associated with the Environmental Assessment (EA) glass (with uncertainties applied) then the glass is deemed unacceptable. The issue of acceptability plays a critical role in high level waste processing but without knowing the pre-defined constraints for the UK HLW system, assessments of acceptability of the glasses to be characterized in this study can not be made. The results of this study will be compared to DWPF constraints to provide a benchmark for determining acceptability. The objective of this task is to provide Sellafield Ltd. with the technical data to evaluate the impacts of various Magnox:Butex blend ratios and WLs on key glass properties of interest. The uranium bearing glasses span a compositional region of interest to Sellafield Ltd. and were physically characterized for key processing and product performance properties as defined in the WFO [WFO (2010)]. One of the specific technical issues (as defined in the WFO) is the potential impact of increasing aluminum concentrations on key properties (in particular viscosity).

  17. Laboratory-Scale Melter for Determination of Melting Rate of Waste Glass Feeds

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, Michael J.; Buchmiller, William C.; Matyas, Josef

    2012-01-09T23:59:59.000Z

    The purpose of this study was to develop the laboratory-scale melter (LSM) as a quick and inexpensive method to determine the processing rate of various waste glass slurry feeds. The LSM uses a 3 or 4 in. diameter-fused quartz crucible with feed and off-gas ports on top. This LSM setup allows cold-cap formation above the molten glass to be directly monitored to obtain a steady-state melting rate of the waste glass feeds. The melting rate data from extensive scaled-melter tests with Hanford Site high-level wastes performed for the Hanford Tank Waste Treatment and Immobilization Plant have been compiled. Preliminary empirical model that expresses the melting rate as a function of bubbling rate and glass yield were developed from the compiled database. The two waste glass feeds with most melter run data were selected for detailed evaluation and model development and for the LSM tests so the melting rates obtained from LSM tests can be compared with those from scaled-melter tests. The present LSM results suggest the LSM setup can be used to determine the glass production rates for the development of new glass compositions or feed makeups that are designed to increase the processing rate of the slurry feeds.

  18. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01T23:59:59.000Z

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0{sub 2},B{sub 2}O{sub 3},A1{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O,Li{sub 2}O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  19. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01T23:59:59.000Z

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0[sub 2],B[sub 2]O[sub 3],A1[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O,Li[sub 2]O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  20. GLASS VISCOSITY AS A FUNCTION OF TEMPERATURE AND COMPOSITION: A MODEL BASED ON ADAM-GIBBS EQUATION

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2008-07-01T23:59:59.000Z

    Within the temperature range and composition region of processing and product forming, the viscosity of commercial and waste glasses spans over 12 orders of magnitude. This paper shows that a generalized Adam-Gibbs relationship reasonably approximates the real behavior of glasses with four temperature-independent parameters of which two are linear functions of the composition vector. The equation is subjected to two constraints, one requiring that the viscosity-temperature relationship approaches the Arrhenius function at high temperatures with a composition-independent pre-exponential factor and the other that the viscosity value is independent of composition at the glass-transition temperature. Several sets of constant coefficients were obtained by fitting the generalized Adam-Gibbs equation to data of two glass families: float glass and Hanford waste glass. Other equations (the Vogel-Fulcher-Tammann equation, original and modified, the Avramov equation, and the Douglass-Doremus equation) were fitted to float glass data series and compared with the Adam-Gibbs equation, showing that Adam-Gibbs glass appears an excellent approximation of real glasses even as compared with other candidate constitutive relations.

  1. The Functional Potential of Microbial Communities in Hydraulic Fracturing Source Water and Produced Water from Natural Gas Extraction Characterized by Metagenomic Sequencing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohan, Arvind Murali; Bibby, Kyle J.; Lipus, Daniel; Hammack, Richard W.; Gregory, Kelvin B.

    2014-10-22T23:59:59.000Z

    Microbial activity in produced water from hydraulic fracturing operations can lead to undesired environmental impacts and increase gas production costs. However, the metabolic profile of these microbial communities is not well understood. Here, for the first time, we present results from a shotgun metagenome of microbial communities in both hydraulic fracturing source water and wastewater produced by hydraulic fracturing. Taxonomic analyses showed an increase in anaerobic/facultative anaerobic classes related to Clostridia, Gammaproteobacteria, Bacteroidia and Epsilonproteobacteria in produced water as compared to predominantly aerobic Alphaproteobacteria in the fracturing source water. The metabolic profile revealed a relative increase in genes responsible formore »carbohydrate metabolism, respiration, sporulation and dormancy, iron acquisition and metabolism, stress response and sulfur metabolism in the produced water samples. These results suggest that microbial communities in produced water have an increased genetic ability to handle stress, which has significant implications for produced water management, such as disinfection.« less

  2. EC Driver - 41" Stroke Hydraulic Cylinder

    SciTech Connect (OSTI)

    Jaques, A.; /Fermilab

    1990-05-24T23:59:59.000Z

    It was decided to use a hydraulic cylinder resting on the floor of the argon spill trough in the EC carriage to drive the EC's motion on the center beam. Space was limited due to the spill bellows and their required support and containment system. The 0.0. of the cylinder had to be limited to 3 to 3-1/2 inches, maximum. The weight of a wet EC and carriage is estimated to be 320 tons. The rolling coefficient of friction of the Tychoway rollers chosen to guide the EC and carriage along the hardened centerbeam ways is claimed to be less than 0.0025. The driver will also need to overcome the forces produced by moving (rotating) the numerous bayonets located at the top of the cryostats in the many piping systems. These forces were conservatively estimated at 1000 lbs. The drive force required to overcome these forces was then calculated to be: 320(2,000) x 0.0025 + 1,000 = 2.600 lbs. (min. required). Due to the uncertainty in the actual roller coefficient of friction and the various unknowns in estimating the resistive forces contained in the piping and cabling systems attached to the cryostat, a conservative design factor of 5 was chosen. This should account for any uncertainty in our estimation of the minimum required drive force and also leaves us with a reserve to fall back on in case any unforeseen problems might arise. Thus the desired capacity of the driver was set at: (2,600) x 5 = 13,000 lbs. (design capacity). Assuming a 3 inch O.D. cylinder with a 1/2 inch wall (2 inch bore), we first analyzed a 1-3/8 inch diameter piston rod. Using Shigley & Mischke's 'Mechanical Engineering Design' (5th Ed.) and it's formulas for long columns with central loading, it was determined that a 1-3/8 inch diameter rod would not suffice, given our safety factor of 2. Increasing the piston rod diameter to 1-1/2 inches proved to be sufficient. The maximum allowable load came out to be approximately 17,000 lbs., which is greater than the 13,000 lbs. design capacity. With a 1-1/2 inch rod, a 2 inch bore and 10,000 psi capacity, the maximum return (retraction) force is: ({pi}/4)(2{sup 2}-1.52) x (10,000) = 13,744 lbs. (return force). This meets the desired design capacity of the cylinder. On the extension of the cylinder, the pressure will be limited such to produce only the 13,000 lb. design capacity. Through the use of a regulator on the cylinder extension inlet, the pressure will be limited to: 13,000/[({pi}/4)(2){sup 2}] {approx_equal} 4,200 psi. (regulator setting) and 4,200 x ({pi}/4)(2){sup 2} = 13,195 lbs. (thrust force). Another reference used by some Fermi engineers in designing hydraulic cylinders is the 'Design Engineers Handbook', Bulletin 0224-B1 published by the Parker-Hannifin Corporation. The piston rod-stroke selection table on page b-5 is used to determine the stroke factor. Our setup most approximates Case II of the table which gives a stroke factor of 0.70. Multiplying this by the actual stroke (41-inch) gives us a basic length of 28.7-inch. Using the piston rodstroke selection graph on page b-6, the 1-1/2 inch rod and 28.7-inch basic length indicate an allowable thrust of approximately 13,000 lbs. According to the Chief Application Engineer at the Parker-Hannifin regional sales office in Des Plaines, IL, a min imum safety factor of 4 can be assumed in the piston rod-stroke selection graph, possibly even higher. This would be at least twice as high as our initial safety factor of 2. Thus we feel our cylinder design falls well within the acceptable region of this reference.

  3. Advanced hydraulic fracturing methods to create in situ reactive barriers

    SciTech Connect (OSTI)

    Murdoch, L. [FRX Inc., Cincinnati, OH (United States)]|[Clemson Univ., SC (United States). Dept. of Geological Sciences; Siegrist, B.; Meiggs, T. [Oak Ridge National Lab., TN (United States)] [and others

    1997-12-31T23:59:59.000Z

    This article describes the use of hydraulic fracturing to increase permeability in geologic formations where in-situ remedial action of contaminant plumes will be performed. Several in-situ treatment strategies are discussed including the use of hydraulic fracturing to create in situ redox zones for treatment of organics and inorganics. Hydraulic fracturing methods offer a mechanism for the in-situ treatment of gently dipping layers of reactive compounds. Specialized methods using real-time monitoring and a high-energy jet during fracturing allow the form of the fracture to be influenced, such as creation of assymmetric fractures beneath potential sources (i.e. tanks, pits, buildings) that should not be penetrated by boring. Some examples of field applications of this technique such as creating fractures filled with zero-valent iron to reductively dechlorinate halogenated hydrocarbons, and the use of granular activated carbon to adsorb compounds are discussed.

  4. On equivalence of thinning fluids used for hydraulic fracturing

    E-Print Network [OSTI]

    Linkov, Alexander

    2012-01-01T23:59:59.000Z

    The paper aims to answer the question: if and how non-Newtonian fluids may be compared in their mechanical action when used for hydraulic fracturing? By employing the modified formulation of the PKN problem we obtain its simple analytical solutions in the cases of perfectly plastic and Newtonian fluids. Since the results for shear thinning fluids are intermediate between those for these cases, the obtained equation for the fracture length suggests a criterion of the equivalence of various shear thinning fluids for the problem of hydraulic fractures. We assume fluids equivalent in their hydrofracturing action, when at a reference time they produce fractures of the same length. The equation for the fracture length translates the equivalence in terms of the hydraulic fracture length and treatment time into the equivalence in terms of the properties of a fracturing fluid (behavior and consistency indices). Analysis shows that the influence of the consistency and behavior indices on the fracture length, particle v...

  5. Evaluation of defense-waste glass produced by full-scale vitrification equipment

    SciTech Connect (OSTI)

    Lukacs, J.M.; Petkus, L.L.; Mellinger, G.B.

    1981-09-01T23:59:59.000Z

    Three full-scale vitrification processes at the Pacific Northwest Laboratory produced over 67,000 kg of simulated nuclear-waste glass from March 1979 to August 1980. Samples were analyzed to monitor process operation and evaluate the resulting glass product. These processes are: Spray Calciner/In-Can Melter (SC/ICM); Spray Calciner/Calcine-Fed Ceramic Melter (SC/CFCM); and Liquid-Fed Ceramic Melter (LFCM). Waste components in the process feed varied less than +- 10%. The SC/ICM and SC/CFCM which use separate waste and frit feed systems showed larger glass compositional variation than the LFCM, which processed only premixed feed during this period. The SC/ICM and SC/CFCM product contained significant amounts of acmite crystals, while the LFCM product was largely amorphous. In addition, the lower portion of all SC/ICM-filled canisters contained a zone rich in waste components. A product chemical durability as determined by pH4 and soxhlet leach tests varied considerably. Aside from increased durability under pH4 conditions with decreasing waste content, glass composition, microstructure and melting process did not correlate with glass durability. For all samples analyzed, the weight loss under pH4 conditions ranged from 17.7 to 85.2 wt %. Soxhlet conditions produced weight losses from 1.78 to 3.56 wt %.

  6. Hydraulic manipulator design, analysis, and control at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Kress, R.L.; Jansen, J.F. [Oak Ridge National Lab., TN (United States). Robotics and Process Systems Div.; Love, L.J. [Oak Ridge Inst. for Science and Education, TN (United States); Basher, A.M.H. [South Carolina State Univ., Orangeburg, SC (United States)

    1996-09-01T23:59:59.000Z

    To meet the increased payload capacities demanded by present-day tasks, manipulator designers have turned to hydraulics as a means of actuation. Hydraulics have always been the actuator of choice when designing heavy-life construction and mining equipment such as bulldozers, backhoes, and tunneling devices. In order to successfully design, build, and deploy a new hydraulic manipulator (or subsystem) sophisticated modeling, analysis, and control experiments are usually needed. To support the development and deployment of new hydraulic manipulators Oak Ridge National Laboratory (ORNL) has outfitted a significant experimental laboratory and has developed the software capability for research into hydraulic manipulators, hydraulic actuators, hydraulic systems, modeling of hydraulic systems, and hydraulic controls. The hydraulics laboratory at ORNL has three different manipulators. First is a 6-Degree-of-Freedom (6-DoF), multi-planer, teleoperated, flexible controls test bed used for the development of waste tank clean-up manipulator controls, thermal studies, system characterization, and manipulator tracking. Finally, is a human amplifier test bed used for the development of an entire new class of teleoperated systems. To compliment the hardware in the hydraulics laboratory, ORNL has developed a hydraulics simulation capability including a custom package to model the hydraulic systems and manipulators for performance studies and control development. This paper outlines the history of hydraulic manipulator developments at ORNL, describes the hydraulics laboratory, discusses the use of the equipment within the laboratory, and presents some of the initial results from experiments and modeling associated with these hydraulic manipulators. Included are some of the results from the development of the human amplifier/de-amplifier concepts, the characterization of the thermal sensitivity of hydraulic systems, and end-point tracking accuracy studies. Experimental and analytical results are included.

  7. Comparison of methods for determining soil hydraulic characteristics

    E-Print Network [OSTI]

    Byrd Humphreys, Kathryn

    1979-01-01T23:59:59.000Z

    to the comprehension of soil water movement. The theory of water movement in soil is based on Darcy's Law which states that flow is proportional to the hydraulic gradient. The equation representing one dimensional flow in a homogeneous iso- tropic media can... of the gravitational head (hg) and the pressure head (h) as follows: H=hg+h In unsaturated flow, the components of the flow equation, K and H, are both dependent on the water content of the soil. These relation- ships between soil water content versus hydraulic...

  8. Incorporating Cold Cap Behavior in a Joule-heated Waste Glass Melter Model

    SciTech Connect (OSTI)

    Varija Agarwal; Donna Post Guillen

    2013-08-01T23:59:59.000Z

    In this paper, an overview of Joule-heated waste glass melters used in the vitrification of high level waste (HLW) is presented, with a focus on the cold cap region. This region, in which feed-to-glass conversion reactions occur, is critical in determining the melting properties of any given glass melter. An existing 1D computer model of the cold cap, implemented in MATLAB, is described in detail. This model is a standalone model that calculates cold cap properties based on boundary conditions at the top and bottom of the cold cap. Efforts to couple this cold cap model with a 3D STAR-CCM+ model of a Joule-heated melter are then described. The coupling is being implemented in ModelCenter, a software integration tool. The ultimate goal of this model is to guide the specification of melter parameters that optimize glass quality and production rate.

  9. ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of BlytheDepartment of Energy IRS Issuesof the U.S. Glass

  10. Method of manufacturing a glass parabolic-cylindrical solar collector

    SciTech Connect (OSTI)

    Deminet, C.

    1980-12-09T23:59:59.000Z

    The method includes the following steps: (1) a microsheet of glass is drawn from a glass melt; (2) a reflective layer, such as silver, is deposited on one surface of the microsheet; (3) a first flexible backing layer, such as fiberglass, is bonded to the reflective layer; (4) the combination of the microsheet with the reflective layer and the first backing layer is formed over a mandrel which is preferably in the form of a parabolic cylinder; and (5) a honeycombed layer, with a second fiberglass backing layer, is then bonded to the first backing layer. The product produced by the steps 1-5 is then cured so that it retains the desired configuration; i.e. parabolic-cylindrical, after it is removed from the mandrel.

  11. Glass Property Data and Models for Estimating High-Level Waste Glass Volume

    SciTech Connect (OSTI)

    Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

    2009-10-05T23:59:59.000Z

    This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

  12. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28T23:59:59.000Z

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  13. Round-robin testing of a reference glass for low-activity waste forms

    SciTech Connect (OSTI)

    Ebert, W. L.; Wolf, S. F.

    1999-12-06T23:59:59.000Z

    A round robin test program was conducted with a glass that was developed for use as a standard test material for acceptance testing of low-activity waste glasses made with Hanford tank wastes. The glass is referred to as the low-activity test reference material (LRM). The program was conducted to measure the interlaboratory reproducibility of composition analysis and durability test results. Participants were allowed to select the methods used to analyze the glass composition. The durability tests closely followed the Product Consistency Test (PCT) Method A, except that tests were conducted at both 40 and 90 C and that parallel tests with a reference glass were not required. Samples of LRM glass that had been crushed, sieved, and washed to remove fines were provided to participants for tests and analyses. The reproducibility of both the composition and PCT results compare favorably with the results of interlaboratory studies conducted with other glasses. From the perspective of reproducibility of analysis results, this glass is acceptable for use as a composition standard for nonradioactive components of low-activity waste forms present at >0.1 elemental mass % and as a test standard for PCTS at 40 and 90 C. For PCT with LRM glass, the expected test results at the 95% confidence level are as follows: (1) at 40 C: pH = 9.86 {+-} 0.96; [B] = 2.30 {+-} 1.25 mg/L; [Na] = 19.7 {+-} 7.3 mg/L; [Si] = 13.7 {+-} 4.2 mg/L; and (2) at 90 C: pH = 10.92 {+-} 0.43; [B] = 26.7 {+-} 7.2 mg/L; [Na] = 160 {+-} 13 mg/L; [Si] = 82.0 {+-} 12.7 mg/L. These ranges can be used to evaluate the accuracy of PCTS conducted at other laboratories.

  14. 68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Glass Technol., 2004, 45, 6870

    E-Print Network [OSTI]

    Sheffield, University of

    68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Glass Technol., 2004, 45, 68­70 The behaviour of a simulant Magnox waste glass

  15. Pediatric Mechanical Circulatory Support Applications for Frequency-Leveraged Piezoelectric Hydraulic Pumps

    E-Print Network [OSTI]

    Valdovinos, John

    2014-01-01T23:59:59.000Z

    B. Olsen, “Axial flow blood pumps,” ASAIO J. Am. Soc. Artif.of a Piezoelectric-hydraulic Pump with Active Valves,” J.Piezoelectric Hydraulic Pump Development,” J. Intell. Mater.

  16. Park City/ANS 1 EVOLVE LITHIUM TRAY THERMAL-HYDRAULIC ANALYSIS

    E-Print Network [OSTI]

    California at Los Angeles, University of

    Park City/ANS 1 EVOLVE LITHIUM TRAY THERMAL-HYDRAULIC ANALYSIS M.H. Anderson, J.G. Murphy, M is viable, thermal-hydraulic analyses were performed on the outboard liquid lithium blanket trays. Various

  17. Quantitative Metrics of Soil Structure and Relationships to Hydraulic Properties in a Vertic Argiudoll

    E-Print Network [OSTI]

    Eck, Dennis V.

    2014-05-31T23:59:59.000Z

    to soil hydraulic parameters, especially saturated hydraulic conductivity (Ks) and water retention curve (WRC) parameters. Soil moisture data collected at the lysimeter, in conjunction with atmospheric data from an adjacent tower, were used as inputs...

  18. THERMAL-HYDRAULIC STUDIES IN SUPPORT OF THE ARIES-CS T-TUBE DIVERTOR DESIGN

    E-Print Network [OSTI]

    THERMAL-HYDRAULIC STUDIES IN SUPPORT OF THE ARIES-CS T-TUBE DIVERTOR DESIGN S. I. ABDEL-KHALIK,*a L and engineering optimization. This paper focuses on the thermal-hydraulic analyses and experiments performed

  19. Analytical methods for estimating saturated hydraulic conductivity in a tile-drained field

    E-Print Network [OSTI]

    Selker, John

    Analytical methods for estimating saturated hydraulic conductivity in a tile-drained field David E; Saturated hydraulic conductivity; Field scale; Tile drains; Water table 1. Introduction The use of spatially

  20. A New Analytical Method to Quantify Residual Fluid Cleanup in Hydraulic Fractures

    E-Print Network [OSTI]

    Zarrin, Tahira

    2014-04-17T23:59:59.000Z

    hydraulic fracturing fluid has always been a major issue, and is believed to drastically undermine the performance of hydraulically fractured wells. Several attempts have been made to quantify the damage associated with residual fluid, with varying level...

  1. Identifying Best Practices in Hydraulic Fracturing Using

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    . Treating Rate Medina Treating Pressure Medina Production Remaining Gas Ultimate Gas Gas Months Prod Gas Medina and Whirlpool sands of southwest New York State are considered to be tight gas sands. Most wells, are fractured upon completion to provide economic amounts of gas. #12;SPE 72385 BACKGROUND A dataset

  2. History of the 185-/189-D thermal hydraulics laboratory and its effects on reactor operations at the Hanford Site

    SciTech Connect (OSTI)

    Gerber, M.S.

    1994-09-01T23:59:59.000Z

    The 185-D deaeration building and the 189-D refrigeration building were constructed at Hanford during 1943 and 1944. Both buildings were constructed as part of the influent water cooling system for D reactor. The CMS studies eliminated the need for 185-D function. Early gains in knowledge ended the original function of the 189-D building mission. In 1951, 185-D and 189-D were converted to a thermal-hydraulic laboratory. The experiments held in the thermal-hydraulic lab lead to historic changes in Hanford reactor operations. In late 1951, the exponential physics experiments were moved to the 189-D building. In 1958, new production reactor experiments were begun in 185/189-D. In 1959, Plutonium Recycle Test Reactor experiments were added to the 185/189-D facility. By 1960, the 185/189-D thermal hydraulics laboratory was one of the few full service facilities of its type in the nation. During the years 1961--1963 tests continued in the facility in support of existing reactors, new production reactors, and the Plutonium Recycle Test Reactor. In 1969, Fast Flux Test Facility developmental testings began in the facility. Simulations in 185/189-D building aided in the N Reactor repairs in the 1980`s. In 1994 the facility was nominated to the National Register of Historic Places, because of its pioneering role over many years in thermal hydraulics, flow studies, heat transfer, and other reactor coolant support work. During 1994 and 1995 it was demolished in the largest decontamination and decommissioning project thus far in Hanford Site history.

  3. Development of Vitrification Process and Glass Formulation for Nuclear Waste Conditioning

    SciTech Connect (OSTI)

    Petitjean, V.; Fillet, C.; Boen, R.; Veyer, C.; Flament, T.

    2002-02-26T23:59:59.000Z

    The vitrification of high-level waste is the internationally recognized standard to minimize the impact to the environment resulting from waste disposal as well as to minimize the volume of conditioned waste to be disposed of. COGEMA has been vitrifying high-level waste industrially for over 20 years and is currently operating three commercial vitrification facilities based on a hot metal crucible technology, with outstanding records of safety, reliability and product quality. To further increase the performance of vitrification facilities, CEA and COGEMA have been developing the cold crucible melter technology since the beginning of the 1980s. This type of melter is characterized by a virtually unlimited equipment service life and a great flexibility in dealing with various types of waste and allowing development of high temperature matrices. In complement of and in parallel with the vitrification process, a glass formulation methodology has been developed by the CEA in order to tailor matrices for the wastes to be conditioned while providing the best adaptation to the processing technology. The development of a glass formulation is a trade-off between material properties and qualities, technical feasibility, and disposal safety criteria. It involves non-radioactive and radioactive laboratories in order to achieve a comprehensive matrix qualification. Several glasses and glass ceramics have thus been studied by the CEA to be compliant with industrial needs and waste characteristics: glasses or other matrices for a large spectrum of fission products, or for high contents of specifics elements such as sodium, phosphate, iron, molybdenum, or actinides. New glasses or glass-ceramics designed to minimize the final wasteform volume for solutions produced during the reprocessing of high burnup fuels or to treat legacy wastes are now under development and take benefit from the latest CEA hot-laboratories and technology development. The paper presents the CEA state-of-the-art in developing matrices or glasses and provides several examples.

  4. Radiation Characteristics of Glass Containing Gas Bubbles

    E-Print Network [OSTI]

    Pilon, Laurent; Viskanta, Raymond

    2003-01-01T23:59:59.000Z

    B. L. Drolen, “Thermal radiation in particulate media withRadiation Characteristics of Glass Containing Gas Bubblesthermophysical properties and radiation characteristics of

  5. Compliant Glass Seals for SOFC Stacks

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Xu, Wei; Stephens, Elizabeth V.; Koeppel, Brian J.; Stevenson, Jeffry W.; Lara-Curzio, Edgar

    2014-04-01T23:59:59.000Z

    This report summarizes results from experimental and modeling studies performed by participants in the Solid-State Energy Conversion Alliance (SECA) Core Technology Program, which indicate that compliant glass-based seals offer a number of potential advantages over conventional seals based on de-vitrifying glasses, including reduced stresses during stack operation and thermal cycling, and the ability to heal micro-damage induced during thermal cycling. The properties and composition of glasses developed and/or investigated in these studies are reported, along with results from long-term (up to 5,800h) evaluations of seals based on a compliant glass containing ceramic particles or ceramic fibers.

  6. High-Temperature Viscosity Of Commercial Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.; See, Clem A.; Lam, Oanh P.; Minister, Kevin B.

    2005-01-01T23:59:59.000Z

    Viscosity was measured for six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Viscosity data were obtained with rotating spindle viscometers within the temperature range between 900°C and 1550°C; the viscosity varied from 1 Pa?s to 750 Pa?s. Arrhenius coefficients were calculated for individual glasses and linear models were applied to relate them to the mass fractions of 11 major components (SiO2, CaO, Na2O, Al2O3, B2O3, BaO, SrO, K2O, MgO, PbO, and ZrO2) and 12 minor components (Fe2O3, ZnO, Li2O, TiO2, CeO2, F, Sb2O3, Cr2O3, As2O3, MnO2, SO3, and Co3O4). The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100°C to 1550°C and viscosity range from 10 to 400 Pa?s.

  7. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The...

  8. Hydraulic constraints on photosynthesis in subtropical evergreen broad leaf forest and pine woodland trees of the Florida Everglades

    E-Print Network [OSTI]

    Jones, Tim J.; Luton, Corene D.; Santiago, Louis S.; Goldstein, Guillermo

    2010-01-01T23:59:59.000Z

    PAPER Hydraulic constraints on photosynthesis in subtropicalwater transport and photosynthesis represents the trade-offwater transport and photosynthesis to evaluate hydraulic

  9. COMPARISON OF PNEUMATIC AND HYDRAULIC FRACTURING FOR EMPLACEMENT OF TREATMENT MATERIALS IN LOW

    E-Print Network [OSTI]

    Mark Strong; Craig Sprinkle; Denis Ewing

    , Georgia to evaluate the performance of pneumatic and hydraulic frac-turing for emplacement of in situ

  10. Engine having hydraulic and fan drive systems using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2000-01-01T23:59:59.000Z

    An engine comprises a hydraulic system attached to an engine housing that includes a high pressure pump and a hydraulic fluid flowing through at least one passageway. A fan drive system is also attached to the engine housing and includes a hydraulic motor and a fan which can move air over the engine. The hydraulic motor includes an inlet fluidly connected to the at least one passageway.

  11. Draining our Glass: An Energy and Heat Characterization of Google Glass

    E-Print Network [OSTI]

    Zhong, Lin

    Draining our Glass: An Energy and Heat Characterization of Google Glass Robert LiKamWa, Zhen Wang, such as hands-free video chat and web search. However, its shape also hampers its potential: (1) battery size characterizing the Glass system. Others have documented technical specifica- tions [22], privacy, security

  12. Introduction and Motivation Structural Model for Laminated Glass Beams Conclusions and Outlook of Laminated Glass Structures

    E-Print Network [OSTI]

    Components of Crystalline Solar Modules back sheet or glass encapsulant electrical conductor crystalline solar cells encapsulant front glass Reference: Schulze, S.-H.; Pander, M.; Naumenko, K.; Altenbach, H and Motivation Components of Thin Film Solar Modules back sheet or glass encapsulant electrical conductor thin

  13. Microseismic mapping of a Cotton Valley hydraulic fracture using decimated downhole arrays J.T. Rutledge

    E-Print Network [OSTI]

    Microseismic mapping of a Cotton Valley hydraulic fracture using decimated downhole arrays J three hydraulic fracture operations in the Cotton Valley gas field of East Texas. Two 48-level, 3 a consortia of operators and service companies conducted an extensive hydraulic fracture imaging demonstration

  14. 2006 GeoX Conference, pages 1 to 6 Characterisation of hydraulic fractures in

    E-Print Network [OSTI]

    2006 GeoX Conference, pages 1 to 6 Characterisation of hydraulic fractures in limestones using X, France Jacques.Desrues@hmg.inpg.fr ABSTRACT: Hydraulic tension fractures were produced in porous, hydraulic fracture, permeability tensor MOTS-CLÃ?S: microtomographie, fracturation hydraulique, tenseur de

  15. Implicit level set schemes for modeling hydraulic fractures using the Elizaveta Gordeliy, Anthony Peirce

    E-Print Network [OSTI]

    Peirce, Anthony

    Implicit level set schemes for modeling hydraulic fractures using the XFEM Elizaveta Gordeliy Copyright Ã? 2013 Published by Elsevier B.V. All rights reserved. 1. Introduction Hydraulic fractures (HF form 13 July 2013 Accepted 27 July 2013 Available online 20 August 2013 Keywords: XFEM Hydraulic

  16. Enrichment strategies and convergence properties of the XFEM for hydraulic fracture problems

    E-Print Network [OSTI]

    Peirce, Anthony

    Enrichment strategies and convergence properties of the XFEM for hydraulic fracture problems Finite Ele- ment Method (XFEM) for modeling hydraulic fractures (HF), two classes of boundary value energy, is not suitable for modeling hydraulic fractures in which the uid and the fracture fronts

  17. A Hybrid, Neuro-Genetic Approach to Hydraulic Fracture Treatment Design and Optimization

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    SPE 36602 A Hybrid, Neuro-Genetic Approach to Hydraulic Fracture Treatment Design and Optimization and novel methodology for optimal design of hydraulic fracture treatments in a gas storage field. What makes very little (almost none) reservoir data availability. Lack of engineering data for hydraulic fracture

  18. A model for turbulent hydraulic fracture and application to crack propagation at glacier beds

    E-Print Network [OSTI]

    Click Here for Full Article A model for turbulent hydraulic fracture and application to crack suggest that fluidinduced hydraulic fracture of an ice sheet from its bed sometimes occurs quickly. Citation: Tsai, V. C., and J. R. Rice (2010), A model for turbulent hydraulic fracture and application

  19. Spatial model coupling -an efficient scheme to combine hydraulic and geomechanic simulations

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    Spatial model coupling - an efficient scheme to combine hydraulic and geomechanic simulations present a spatial coupling approach with two subdomains [1]: Hydro-geomechanical model full model approach-field (geomechanics are neglected) hydro-geomechanical subdomain el2p model hydraulic subdomain 2p model hydraulic

  20. Nonlinear State Space Model of a Hydraulic Wind Power Transfer Masoud Vaezi1

    E-Print Network [OSTI]

    Zhou, Yaoqi

    state space representation of a hydraulic wind energy transfer for a single wind turbine systemNonlinear State Space Model of a Hydraulic Wind Power Transfer Masoud Vaezi1 , Majid Deldar1 1, IUPUI. Gearless hydraulic wind power systems are considered as nonlinear models because of some discrete

  1. Optimal Design of Power-Split Transmissions for Hydraulic Hybrid Passenger Vehicles

    E-Print Network [OSTI]

    Li, Perry Y.

    Optimal Design of Power-Split Transmissions for Hydraulic Hybrid Passenger Vehicles Kai Loon Cheong, Perry Y. Li and Thomas R. Chase Abstract-- Hydraulic hybrid vehicles are inherently power dense. Power and input coupled power-split configurations. Keywords: Hybrid vehicles, hydraulics, power-split, engine

  2. SOFT SWITCHING APPROACH TO REDUCING TRANSITION LOSSES IN AN ON/OFF HYDRAULIC VALVE

    E-Print Network [OSTI]

    Li, Perry Y.

    SOFT SWITCHING APPROACH TO REDUCING TRANSITION LOSSES IN AN ON/OFF HYDRAULIC VALVE Michael B/off controlled hydraulic system is proposed. There has been a growing interest in the use of on/off valves to control hydraulic systems as a means of improving system efficiency. While on/off valves are efficient

  3. Integrated mechatronic design of precision and energy saving electro-hydraulic systems

    E-Print Network [OSTI]

    Yao, Bin

    - 360 - Integrated mechatronic design of precision and energy saving electro-hydraulic systems Bin less energy consumption are the goals for the design of any industrial systems including electro-hydraulics on the precision and energy saving control of electro-hydraulic systems. Specifically, instead of the traditional

  4. HYDRAULIC CONDUCTIVITY ESTIMATION IN PARTIALLY SATURATED SOILS USING THE ADJOINT METHOD

    E-Print Network [OSTI]

    Efendiev, Yalchin

    HYDRAULIC CONDUCTIVITY ESTIMATION IN PARTIALLY SATURATED SOILS USING THE ADJOINT METHOD J. SANTOS for the estimation of the saturated hydraulic conductivity k in a partially saturated soil Q is proposed. Groundwater exam- ple showing the implementation of the algorithm to estimate the saturated hydraulic conductivity

  5. Analysis of hydraulic tomography using temporal moments of drawdown recovery data

    E-Print Network [OSTI]

    Daniels, Jeffrey J.

    Analysis of hydraulic tomography using temporal moments of drawdown recovery data Junfeng Zhu 2006. [1] Transient hydraulic tomography (THT) is a potentially cost-effective and high- resolution technique for mapping spatial distributions of the hydraulic conductivity and specific storage in aquifers

  6. Study on the hydraulic conductivity of Boom clay1 Yong-Feng Deng1, 2

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Study on the hydraulic conductivity of Boom clay1 2 Yong-Feng Deng1, 2 , Anh-Minh Tang2 , Yu Geotechnical Journal 48 (2011) 1461-1470" DOI : 10.1139/T11-048 #12;2 Abstract1 The hydraulic conductivity. Experimental results show that the hydraulic conductivity3 is mainly governed by the soil porosity

  7. APS/123-QED Hydraulic Flow through a Channel Contraction: Multiple Steady States

    E-Print Network [OSTI]

    Al Hanbali, Ahmad

    APS/123-QED Hydraulic Flow through a Channel Contraction: Multiple Steady States Benjamin Akers with a complex hydraulic jump in the contraction occurring in a small section of the bc/b0 and Froude number parameter plane. One- dimensional hydraulic theory provides a comprehensive leading-order approximation

  8. A Hydraulic Capture Application for Optimal Remediation Design K. R. Fowlera

    E-Print Network [OSTI]

    1 A Hydraulic Capture Application for Optimal Remediation Design K. R. Fowlera , C. T. Kelley b , C Carolina Chapel Hill, NC 27599-7400, USA The goal of a hydraulic capture model for remediation purposes is desirable and often influences the choice of solution method. In this paper we present two hydraulic capture

  9. Non-Invasive Measurement of Heartbeat with a Hydraulic Bed Sensor

    E-Print Network [OSTI]

    He, Zhihai "Henry"

    Non-Invasive Measurement of Heartbeat with a Hydraulic Bed Sensor Progress, Challenges}@mail.missouri.edu, SkubicM@missouri.edu Abstract--A hydraulic bed sensor has been developed to non and development of the system. Keywords--hydraulic bed sensor; eldercare monitoring; ballistocardiography I

  10. Equivalent hydraulic conductivity of an experimental stratigraphy: Implications for basin-scale flow

    E-Print Network [OSTI]

    Gable, Carl W.

    Equivalent hydraulic conductivity of an experimental stratigraphy: Implications for basin-scale groundwater flow models are the estimation of representative hydraulic conductivity for the model units. In this study, high-resolution, fully heterogeneous basin-scale hydraulic conductivity map is generated

  11. 1 Estimating aquifer hydraulic properties from the inversion of surface 2 Streaming Potential (SP) anomalies

    E-Print Network [OSTI]

    Sailhac, Pascal

    1 Estimating aquifer hydraulic properties from the inversion of surface 2 Streaming Potential (SP with the geometry of the water table. It follows that 11 SP measurements can be used to estimate aquifer hydraulic and found that we 14 are able to estimate the hydraulic conductivity and the depth 15 and the thickness

  12. Complex hydraulic and substrate variables limit freshwater mussel species richness and abundance

    E-Print Network [OSTI]

    Vaughn, Caryn

    Complex hydraulic and substrate variables limit freshwater mussel species richness and abundance. We examined how substrate and complex hydraulic variables limit the distribution of freshwater mussels. We sampled mussels and measured substrate and hydraulic variables (at low and high flows) at 6

  13. Combining hydraulic knowledge and uncertain gaugings in the estimation of hydrometric rating curves: A Bayesian approach

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Combining hydraulic knowledge and uncertain gaugings in the estimation of hydrometric rating curves HHLY, Hydrology-Hydraulics 5 rue de la Doua CS70077 69626 Villeurbanne cedex, France bCETE Ile analysis of rating curves arises from the quantitative as- sessment of (i) the hydraulic controls

  14. Variation in hydraulic conductivity of mangroves: influence of species, salinity, and nitrogen and phosphorus availability

    E-Print Network [OSTI]

    Ling, Sharon Ewe Mei

    Variation in hydraulic conductivity of mangroves: influence of species, salinity, and nitrogen identity and variation in salinity and nutrient availability influence the hydraulic conductivity of mangroves. Using a fertilization study of two species in Florida, we found that stem hydraulic conductivity

  15. Transient effective hydraulic conductivities under slowly and rapidly varying mean gradients in bounded three-

    E-Print Network [OSTI]

    Tartakovsky, Daniel M.

    Transient effective hydraulic conductivities under slowly and rapidly varying mean gradients it Darcian in real or transformed domains. Each such situation gives rise to an effective hydraulic-time. In this paper we develop first-order analytical expressions for effective hydraulic conductivity under three

  16. Weakly Dispersive Hydraulic Flows in a Contraction -Parametric Solutions and Linear Stability

    E-Print Network [OSTI]

    Ee, Bernard Kuowei

    Weakly Dispersive Hydraulic Flows in a Contraction - Parametric Solutions and Linear Stability typically results is a transition of flow characteristics within the contraction yielding hydraulic flows of the contraction. As considered here, a hydraulic solution is generally one where the fluid response is a function

  17. Variation of hydraulic conductance of some adult conifers under natural conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Variation of hydraulic conductance of some adult conifers under natural conditions A. Granier, N; in the liquid phase, the flow depends upon water potential gradients and hydraulic conductance from the soil present here some evaluations of hydraulic conductance of trees growing under natural conditions. Data

  18. Change in the hydraulic properties of a Brazilian clay Ferralsol on clearing for pasture

    E-Print Network [OSTI]

    Boyer, Edmond

    Change in the hydraulic properties of a Brazilian clay Ferralsol on clearing for pasture L. C 80 to 300 m in size. The aim of this study was to analyze how the hydraulic properties of a clay retention properties were determined by using pressure cell equipment. We determined the saturated hydraulic

  19. Hydraulic adjustment of Scots pine across Europe J. Martnez-Vilalta1,2

    E-Print Network [OSTI]

    Mencuccini, Maurizio

    Research Hydraulic adjustment of Scots pine across Europe J. Martínez-Vilalta1,2 , H. Cochard3), 8903 Birmensdorf, Switzerland Summary · The variability of branch-level hydraulic properties, xylem anatomy, sapwood- and leaf-specific hydraulic conductivity (KS and KL), vulnerability to embolism

  20. The Design of an Adaptive Multiple Agent ConstraintBased Controller for a Complex Hydraulic System

    E-Print Network [OSTI]

    Bahler, Dennis R.

    The Design of an Adaptive Multiple Agent Constraint­Based Controller for a Complex Hydraulic System­order predicate calculus (FOPC) language applied in a complex hydraulic system are presented. The concept an update strategy which makes a real time adaptive hydraulic control for all 20 cities possible. 1