Sample records for glass products cement

  1. Magnesium phosphate glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

    1984-03-13T23:59:59.000Z

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  2. Magnesium-phosphate-glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-09-23T23:59:59.000Z

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  3. CONSTRUCTION-GRADE CEMENT PRODUCTION FROM CONTAMINATED SEDIMENTS USING

    E-Print Network [OSTI]

    Brookhaven National Laboratory

    1 CONSTRUCTION-GRADE CEMENT PRODUCTION FROM CONTAMINATED SEDIMENTS USING CEMENT-LOCKTM TECHNOLOGY A manufacturing technology for producing construction-grade cements from a wide variety of contaminated waste cementitious properties that allow it to be transformed into construction-grade cement. The Cement

  4. Long-term modeling of glass waste in portland cement- and clay-based matrices

    SciTech Connect (OSTI)

    Stockman, H.W.; Nagy, K.L. [Sandia National Labs., Albuquerque, NM (United States); Morris, C.E. [Wollongong Univ., NSW (Australia). Dept. of Civil and Mining Engineering

    1995-12-01T23:59:59.000Z

    A set of ``templates`` was developed for modeling waste glass interactions with cement-based and clay-based matrices. The templates consist of a modified thermodynamic database, and input files for the EQ3/6 reaction path code, containing embedded rate models and compositions for waste glass, cement, and several pozzolanic materials. Significant modifications were made in the thermodynamic data for Th, Pb, Ra, Ba, cement phases, and aqueous silica species. It was found that the cement-containing matrices could increase glass corrosion rates by several orders of magnitude (over matrixless or clay matrix systems), but they also offered the lowest overall solubility for Pb, Ra, Th and U. Addition of pozzolans to cement decreased calculated glass corrosion rates by up to a factor of 30. It is shown that with current modeling capabilities, the ``affinity effect`` cannot be trusted to passivate glass if nuclei are available for precipitation of secondary phases that reduce silica activity.

  5. Characterization and modeling of the cemented sediment surrounding the Iulia Felix glass

    SciTech Connect (OSTI)

    Strachan, Denis M.; Crum, Jarrod V.; Ryan, Joseph V.; Silvestri, Alberta

    2014-02-28T23:59:59.000Z

    About 1800 years ago a Roman Corbita sunk off the coast of Italy carrying a barrel of glass cullet to the floor of the Adriatic Sea. Samples of glass cullet and the cemented surrounding sediment have been characterized and the reaction between the glass and the sea water saturated with respect to calcite and dolomite has been modeled. Results from characterization and modeling show that the cement phase surrounding the sediment grains is a high-Mg calcite. The origin of the cement phase is likely the reaction between the glass and the sea water to from a Mg-silicate, here modeled as sepiolite.

  6. Energy, environmental and greenhouse gas effects of using alternative fuels in cement production

    E-Print Network [OSTI]

    Columbia University

    1 Energy, environmental and greenhouse gas effects of using alternative fuels in cement to an increase of AF use from 8.7% to 20.9% of the total energy consumption. 2. One of the alternative fuels used cement industry produces about 3.3 billion tonnes of cement annually. Cement production is energy

  7. India's cement industry: Productivity, energy efficiency and carbon emissions

    SciTech Connect (OSTI)

    Schumacher, Katja; Sathaye, Jayant

    1999-07-01T23:59:59.000Z

    Historical estimates of productivity growth in India's cement sector vary from indicating an improvement to a decline in the sector's productivity. The variance may be traced to the time period of study, source of data for analysis, and type of indices and econometric specifications used for reporting productivity growth. Analysis shows that in the twenty year period, 1973 to 1993, productivity in the aluminum sector increased by 0.8% per annum. An econometric analysis reveals that technical progress in India's cement sector has been biased towards the use of energy and capital, while it has been material and labor saving. The increase in productivity was mainly driven by a period of progress between 1983 and 1991 following partial decontrol of the cement sector in 1982. The authors examine the current changes in structure and energy efficiency in the sector. Their analysis shows that the Indian cement sector is moving towards world-best technology, which will result in fewer carbon emissions and more efficient energy use. However, substantial further energy savings and carbon reduction potentials still exist.

  8. Estimation of CO2 Emissions from China's Cement Production: Methodologies and Uncertainties

    E-Print Network [OSTI]

    Ke, Jing

    2014-01-01T23:59:59.000Z

    L. , 2006. Discussion of CO2 emission reduction in ChineseFurther discussion of CO2 emission reduction in Chinesecalculation method of CO2 emissions of cement production.

  9. Glass and Glass Products (2010 MECS) | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky LearningGet Assistance GetGiant ProteaseGlass and Glass Products

  10. Recycling of the product of thermal inertization of cement-asbestos for various industrial applications

    SciTech Connect (OSTI)

    Gualtieri, Alessandro F., E-mail: alessandro.gualtieri@unimore.it [Dipartimento di Scienze della Terra, Universita di Modena e R.E., Via S. Eufemia 19, I-41100 Modena (Italy); Giacobbe, Carlotta; Sardisco, Lorenza; Saraceno, Michele [Dipartimento di Scienze della Terra, Universita di Modena e R.E., Via S. Eufemia 19, I-41100 Modena (Italy); Lassinantti Gualtieri, Magdalena [Dipartimento Ingegneria dei Materiali e dell'Ambiente, Universita di Modena e Reggio Emilia, Via Vignolese 905/a, I-41100 Modena (Italy); Lusvardi, Gigliola [Dipartimento di Chimica, Universita degli Studi di Modena e Reggio Emilia, Via G. Campi 183, I-41100 Modena (Italy); Cavenati, Cinzia; Zanatto, Ivano [ZETADI S.r.l., Via dell'Artigianato 10, Ferno (Italy)

    2011-01-15T23:59:59.000Z

    Recycling of secondary raw materials is a priority of waste handling in the countries of the European community. A potentially important secondary raw material is the product of the thermal transformation of cement-asbestos, produced by prolonged annealing at 1200-1300 {sup o}C. The product is chemically comparable to a Mg-rich clinker. Previous work has assured the reliability of the transformation process. The current challenge is to find potential applications as secondary raw material. Recycling of thermally treated asbestos-containing material (named KRY.AS) in traditional ceramics has already been studied with successful results. The results presented here are the outcome of a long termed project started in 2005 and devoted to the recycling of this secondary raw materials in various industrial applications. KRY.AS can be added in medium-high percentages (10-40 wt%) to commercial mixtures for the production of clay bricks, rock-wool glasses for insulation as well as Ca-based frits and glass-ceramics for the production of ceramic tiles. The secondary raw material was also used for the synthesis of two ceramic pigments; a green uvarovite-based pigment [Ca{sub 3}Cr{sub 2}(SiO{sub 4}){sub 3}] and a pink malayaite-based pigment [Ca(Sn,Cr)SiO{sub 5}]. The latter is especially interesting as a substitute for cadmium-based pigments. This work also shows that KRY.AS can replace standard fillers in polypropylene plastics without altering the properties of the final product. For each application, a description and relevant results are presented and discussed.

  11. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    Hilger, J. 2003. Combined Utilization of Oil Shale Energyand Oil Shale Minerals within the Production of Cement andOther Hydraulic Minerals. Oil Shale, Vol. 20, No. 3, pp.

  12. Process for Converting Waste Glass Fiber into Value Added Products, Final Report

    SciTech Connect (OSTI)

    Hemmings, Raymond T.

    2005-12-31T23:59:59.000Z

    Nature of the Event: Technology demonstration. The project successfully met all of its technical objectives. Albacem has signed an exclusive licensing agreement with Vitro Minerals Inc., a specialty minerals company, to commercialize the Albacem technology (website: www.vitrominerals.com). Location: The basic research for the project was conducted in Peoria, Illinois, and Atlanta, Georgia, with third-party laboratory verification carried out in Ontario, Canada. Pilot-scale trials (multi-ton) were conducted at a facility in South Carolina. Full-scale manufacturing facilities have been designed and are scheduled for construction by Vitro Minerals during 2006 at a location in the Georgia, North Carolina, and South Carolina tri-state area. The Technology: This technology consists of a process to eliminate solid wastes generated at glass fiber manufacturing facilities by converting them to value-added materials (VCAS Pozzolans) suitable for use in cement and concrete applications. This technology will help divert up to 250,000 tpy of discarded glass fiber manufacturing wastes into beneficial use applications in the concrete construction industry. This technology can also be used for processing glass fiber waste materials reclaimed from monofills at manufacturing facilities. The addition of take-back materials and reclamation from landfills can help supply over 500,000 tpy of glass fiber waste for processing into value added products. In the Albacem process, waste glass fiber is ground to a fine powder that effectively functions as a reactive pozzolanic admixture for use in portland ce¬ment-based building materials and products, such as concrete, mortars, terrazzo, tile, and grouts. Because the waste fiber from the glass manufacturing industry is vitreous, clean, and low in iron and alkalis, the resulting pozzolan is white in color and highly consistent in chemical composition. This white pozzolan, termed VCAS Pozzolan (for Vitreous Calcium-Alumino-Silicate). is especially suited for white concrete applications where it imparts desirable benefits such as increased long-term strength and improved long-term durability of concrete products. Two U.S. patents entitled have been issued to Albacem covering the technology. Third-party validation testing has confirmed that the pozzolanic product is an excellent, high performance material that conforms to a ASTM standards and improves the strength and durability of concrete. Currently, there are no known significant competing technologies to process glass fiber manufacturing by-products and con¬vert them into value-added products. Most glass fiber-forming and fabrication wastes continue to be disposed in landfills at significant costs and with associated negative environmental impact. It is estimated that in a typical glass fiber manufactur¬ing facility, 10-20% by weight of the processed glass material is sent for dis¬posal to a landfill. Today, supplementary ce¬menting materials or mineral admixtures are key to achieving strong and durable concrete. Recovered materials such as coal fly ash, ground granulated blast furnace slag and silica fume are widely accepted and used in concrete all over the world, espe¬cially in the construction of “high performance” structures such as massive dams, bridges, subway tunnels, etc. These min¬eral admixtures are not suitable for white concrete and light-colored architectural concrete applications. Converting waste glass fibers into a high performance white pozzolan would allow white concrete producers to gain from the same durability benefits currently realized by gray concrete producers. Description of the Benefit: Albacem’s technology will enable the glass fiber industry to eliminate nearly 100% of its glass fiber produc¬tion waste streams by converting them into viable value-added products. With this technology, the glass industry can prevent the landfilling of about 250,000 tons of waste glass fiber annually. Glass manufacturers will realize improved production efficiency by reducing process costs through the elimination of solid was

  13. Portland cement mortar modified with latex and fiber glass for thin shell construction

    E-Print Network [OSTI]

    Raymond, Jewell Duane

    1963-01-01T23:59:59.000Z

    and materials required for the elaborate formwork. Building codes are also in need of revision to include provisions for thin shell construction. The objective of this study was to investigate the possible potential use of portland cement mortar modified...

  14. The use of Devonian oil shales in the production of portland cement

    SciTech Connect (OSTI)

    Schultz, C.W.; Lamont, W.E. [Alabama Univ., University, AL (United States); Daniel, J. [Lafarge Corp., Alpena, MI (United States)

    1991-12-31T23:59:59.000Z

    The Lafarge Corporation operates a cement plant at Alpena, Michigan in which Antrim shale, a Devonian oil shale, is used as part of the raw material mix. Using this precedent the authors examine the conditions and extent to which spent shale might be utilized in cement production. They conclude that the potential is limited in size and location but could provide substantial benefit to an oil shale operation meeting these criteria.

  15. Energy Efficient Microwave Hybrid Processing of Lime for Cement, Steel, and Glass Industries

    SciTech Connect (OSTI)

    Fall, Morgana L; Yakovlev, Vadim; Sahi, Catherine; Baranova, Inessa; Bowers, Johnney G; Esquenazi\t, Gibran L

    2012-02-10T23:59:59.000Z

    In this study, the microwave materials interactions were studied through dielectric property measurements, process modeling, and lab scale microwave hybrid calcination tests. Characterization and analysis were performed to evaluate material reactions and energy usage. Processing parameters for laboratory scale and larger scale calcining experiments were developed for MAT limestone calcination. Early stage equipment design concepts were developed, with a focus on microwave post heating treatment. The retrofitting of existing rotary calcine equipment in the lime industry was assessed and found to be feasible. Ceralink sought to address some of the major barriers to the uptake of MAT identified as the need for (1) team approach with end users, technology partners, and equipment manufacturers, (2) modeling that incorporates kiln materials and variations to the design of industrial microwave equipment. This project has furthered the commercialization effort of MAT by working closely with an industrial lime manufacturer to educate them regarding MAT, identifying equipment manufacturer to supply microwave equipment, and developing a sophisticated MAT modeling with WPI, the university partner. MAT was shown to enhance calcining through lower energy consumption and faster reaction rates compared to conventional processing. Laboratory testing concluded that a 23% reduction in energy was possible for calcining small batches (5kg). Scale-up testing indicated that the energy savings increased as a function of load size and 36% energy savings was demonstrated (22 kg). A sophisticated model was developed which combines simultaneous microwave and conventional heating. Continued development of this modeling software could be used for larger scale calcining simulations, which would be a beneficial low-cost tool for exploring equipment design prior to actual building. Based on these findings, estimates for production scale MAT calcining benefits were calculated, assuming uptake of MAT in the US lime industry. This estimate showed that 7.3 TBTU/year could be saved, with reduction of 270 MMlbs of CO2 emissions, and $29 MM/year in economic savings. Taking into account estimates for MAT implementation in the US cement industry, an additional 39 TBTU/year, 3 Blbs of CO2 and $155 MM/year could be saved. One of the main remaining barriers to commercialization of MAT for the lime and cement industries is the sheer size of production. Through this project, it was realized that a production size MAT rotary calciner was not feasible, and a different approach was adapted. The concept of a microwave post heat section located in the upper portion of the cooler was devised and appears to be a more realistic approach for MAT implementation. Commercialization of this technology will require (1) continued pilot scale calcining demonstrations, (2) involvement of lime kiln companies, and (3) involvement of an industrial microwave equipment provider. An initial design concept for a MAT post-heat treatment section was conceived as a retrofit into the cooler sections of existing lime rotary calciners with a 1.4 year payback. Retrofitting will help spur implementation of this technology, as the capital investment will be minimal for enhancing the efficiency of current rotary lime kilns. Retrofits would likely be attractive to lime manufacturers, as the purchase of a new lime kiln is on the order of a $30 million dollar investment, where as a MAT retrofit is estimated on the order of $1 million. The path for commercialization lies in partnering with existing lime kiln companies, who will be able to implement the microwave post heat sections in existing and new build kilns. A microwave equipment provider has been identified, who would make up part of the continued development and commercialization team.

  16. Production of cements from Illinois coal ash. Technical report, September 1, 1995--November 30, 1995

    SciTech Connect (OSTI)

    Wagner, J.C. [Institute of Gas Technology, Chicago, IL (United States); Bhatty, J.I.; Mishulovich, A. [Construction Technology Labs., Inc., Washington, DC (United States)

    1995-12-31T23:59:59.000Z

    The objective of this program is to convert Illinois coal combustion residues, such as fly ash, bottom ash, and boiler slag, into novel cementitious materials for use in the construction industry. Currently only about 30% of the 5 million tons of these coal combustion residues generated in Illinois each year are utilized, mainly as aggregate. These residues are composed largely Of SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, MgO, and CaO, which are also the major components of cement. The process being developed in this program will use the residues directly in the manufacture of cement products. Therefore, a much larger amount of residues can be utilized. To achieve the above objective, in the first phase (current year) samples of coal combustion residues will be blended and mixed, as needed, with a lime or cement kiln dust (CKD) to adjust the CaO composition. Six mixtures will be melted in a laboratory-scale furnace at CTL. The resulting products will then be tested for cementitious properties. Two preliminary blends have been tested. One blend used fly ash with limestone, while the other used fly ash with CKD. Each blend was melted and then quenched, and the resulting product samples were ground to a specific surface area similar to portland cement. Cementitious properties of these product samples were evaluated by compression testing of 1-inch cube specimens. The specimens were formed out of cement paste where a certain percentage of the cement paste is displaced by one of the sample products. The specimens were cured for 24 hours at 55{degrees}C and 100% relative humidity. The specimens made with the product samples obtained 84 and 89% of the strength of a pure portland cement control cube. For comparison, similar (pozzolanic) materials in standard concrete practice are required to have a compressive strength of at least 75% of that of the control.

  17. Evaluation of cement production using a pressurized fluidized-bed combustor

    SciTech Connect (OSTI)

    DeLallo, M.; Eshbach, R.

    1994-01-01T23:59:59.000Z

    There are several primary conclusions which can be reached and used to define research required in establishing the feasibility of using PFBC-derived materials as cement feedstock. 1. With appropriate blending almost any material containing the required cement-making materials can be utilized to manufacture cement. However, extensive blending with multiple materials or the use of ash in relatively small quantities would compromise the worth of this concept. 2. The composition of a potential feedstock must be considered not only with respect to the presence of required materials, but just as significantly, with respect to the presence and concentration of known deleterious materials. 3. The processing costs for rendering the feedstock into an acceptable composition and the energy costs associated with both processing and burning must be considered. It should be noted that the cost of energy to produce cement, expressed as a percentage of the price of the product is higher than for any other major industrial product. Energy consumption is, therefore, a major issue. 4. The need for conformance to environmental regulations has a profound effect on the cement industry since waste materials can neither be discharged to the atmosphere or be shipped to a landfill. 5. Fifth, the need for achieving uniformity in the composition of the cement is critical to controlling its quality. Unfortunately, certain materials in very small concentrations have the capability to affect the rate and extent to which the cementitious compound in portland cement are able to form. Particularly critical are variations in the ash, the sulfur content of the coal or the amount and composition of the stack dust returned to the kiln.

  18. production under ionizing radiation in aluminoborosilicate glasses by EPR spectroscopy.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Ti3+ production under ionizing radiation in aluminoborosilicate glasses by EPR spectroscopy. P irradiation of Ti4+ ions in aluminoborosilicate glasses have been studied by EPR spectroscopy at 20 K of the Ti3+ ion EPR spectra has shown three different Ti3+ environment attributed to one [VI] Ti3+ and two

  19. Effects of alteration product precipitation on glass dissolution

    SciTech Connect (OSTI)

    Strachan, Denis M.; Neeway, James J.

    2014-04-02T23:59:59.000Z

    Silicate glasses dissolve in water at a rate dependent on the solution concentration of orthosilicic acid (H4SiO4). In general, higher [H4SiO4] leads to lower dissolution rates. It has often been observed that the precipitation of certain silica-bearing alteration products can cause the dissolution of the glass to increase, even after the rate has decreased significantly. However, it has also been observed that in the concentrations of these silica-bearing solution species do not significantly decrease while other elements continue to be released. In this study, we have used the Geochemist’s Workbench code to investigate the relationship between glass dissolution rates and the precipitation rate of a silica-bearing alteration product, analcime (Na(AlSi2O6)?H2O). In this initial study and to simplify the calculations, we suppressed all alteration products except analcime, gibbsite (Al(OH)3), and amorphous silica. The ‘cross affinity’ code option allowed us to account for the fact that glass is a thermodynamically unstable solid with respect to its alteration products in contact with water. The cross-affinity option in the Geochemist’s Workbench geochemical code allowed us to substitute the amorphous silica equilibrium-constant matrix for the glass equilibrium-constant matrix. In this article, we present the results of our calculations of the glass dissolution rate at different values for the analcime precipitation rate constant and the effects of varying the glass dissolution rate constant at a constant analcime precipitation rate constant. In all cases, our results indicate that the glass dissolution rate controls the rate of analcime precipitation in the long term. Our results, compared in general terms with experiments, show the importance of the gel layer that forms during glass alteration. The meaning of these results pertinent to long-term glass durability is discussed.

  20. Research on drilling fluids and cement slurries at Standard Oil Production Company: an internship report

    E-Print Network [OSTI]

    Flipse, Eugene Charles, 1956-

    2013-03-13T23:59:59.000Z

    1986 Major Subject: Chemical Engineering Research on Drilling Fluids and Cement Slurries at Standard Oil Production Company An Internship Report by EUGENE CHARLES FLIPSE Dr. K. R. Hall Chairman, Advisory Committee Dr. A Juazis Internship... was assigned to the SOPC Drilling Fluids Laboratory during his internship. Dr. W. C. McMordie, Jr. was his direct supervisor. The technical and administrative duties of this internship fell into six categories: orientation, laboratory build-out, office...

  1. Production of cements from Illinois coal ash. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect (OSTI)

    Wagner, J.C.; Bhatty, J.L.; Mishulovich, A.

    1997-05-01T23:59:59.000Z

    The objective of this program is to convert Illinois coal combustion residues, such as fly ash, bottom ash, and boiler slag, into novel cementitious materials for use in the construction industry. These residues are composed largely of SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, MgO, and CaO, which are also the major components of cement. Since the residues are used as an integral component of the cement and not just as additives to concrete, larger amounts of the residues can be utilized. The process uses submerged combustion to melt blends of coal combustion residues with lime, clay, and/or sand. The submerged combustion melter utilizes natural gas-oxidant firing directly into a molten bath to provide efficient melting of mineral-like materials. Use of this melter for cement production has many advantages over rotary kilns including very little, if any, grinding of the feed material, very low emissions, and compact size. During the first year of the program, samples of coal combustion residues were blended and mixed, as needed; with lime, clay, and/or sand to adjust the composition. Six mixtures, three with fly ash and three with bottom ash, were melted in a laboratory-scale furnace. The resultant products were used in mortar cubes and bars which were subjected to ASTM standard tests of cementitious properties. In the hydraulic activity test, mortar cubes were found to have a strength comparable to standard mortar cements. In the compressive strength test, mortar cubes were found to have strengths that exceeded ASTM blended cement performance specifications. In the ASR expansion test, mortar bars were subjected to alkali-silica reaction-induced expansion, which is a problem for siliceous aggregate-based concretes that are exposed to moisture. The mortar bars made with the products inhibited 85 to 97% of this expansion. These results show that residue-based products have an excellent potential as ASR-preventing additions in concretes.

  2. Emerging Energy-efficiency and CO{sub 2} Emission-reduction Technologies for Cement and Concrete Production

    SciTech Connect (OSTI)

    Hasanbeigi, Ali; Price, Lynn; Lin, Elina

    2012-04-06T23:59:59.000Z

    Globally, the cement industry accounts for approximately 5 percent of current anthropogenic carbon dioxide (CO{sub 2}) emissions. World cement demand and production are increasing significantly, leading to an increase in this industry's absolute energy use and CO{sub 2} emissions. Development of new energy-efficiency and CO{sub 2} emission-reduction technologies and their deployment in the market will be key for the cement industry's mid- and long-term climate change mitigation strategies. This report is an initial effort to compile available information on process description, energy savings, environmental and other benefits, costs, commercialization status, and references for emerging technologies to reduce the cement industry's energy use and CO{sub 2} emissions. Although studies from around the world identify a variety of sector-specific and cross-cutting energy-efficiency technologies for the cement industry that have already been commercialized, information is scarce and/or scattered regarding emerging or advanced energy-efficiency and low-carbon technologies that are not yet commercialized. This report consolidates available information on nineteen emerging technologies for the cement industry, with the goal of providing engineers, researchers, investors, cement companies, policy makers, and other interested parties with easy access to a well-structured database of information on these technologies.

  3. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, Michael D. (West Alexandria, OH); Kramer, Daniel P. (Dayton, OH)

    1987-11-10T23:59:59.000Z

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  4. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, M.D.; Kramer, D.P.

    1985-01-04T23:59:59.000Z

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  5. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    of granulated blast furnace slag and its effect on theblast furnace slag in cement results from the combined effects

  6. Baseline Glass Development for Combined Fission Products Waste Streams

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Billings, Amanda Y.; Lang, Jesse B.; Marra, James C.; Rodriguez, Carmen P.; Ryan, Joseph V.; Vienna, John D.

    2009-06-29T23:59:59.000Z

    Borosilicate glass was selected as the baseline technology for immobilization of the Cs/Sr/Ba/Rb (Cs), lanthanide (Ln) and transition metal fission product (TM) waste steams as part of a cost benefit analysis study.[1] Vitrification of the combined waste streams have several advantages, minimization of the number of waste forms, a proven technology, and similarity to waste forms currently accepted for repository disposal. A joint study was undertaken by Pacific Northwest National Laboratory (PNNL) and Savannah River National Laboratory (SRNL) to develop acceptable glasses for the combined Cs + Ln + TM waste streams (Option 1) and Cs + Ln combined waste streams (Option 2) generated by the AFCI UREX+ set of processes. This study is aimed to develop baseline glasses for both combined waste stream options and identify key waste components and their impact on waste loading. The elemental compositions of the four-corners study were used along with the available separations data to determine the effect of burnup, decay, and separations variability on estimated waste stream compositions.[2-5] Two different components/scenarios were identified that could limit waste loading of the combined Cs + LN + TM waste streams, where as the combined Cs + LN waste stream has no single component that is perceived to limit waste loading. Combined Cs + LN waste stream in a glass waste form will most likely be limited by heat due to the high activity of Cs and Sr isotopes.

  7. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    2010. Cement and concrete nanoscience and nanotechnology.of 100 Percent Fly Ash Concrete. 2005 World of Coal Ash (carbon dioxide in precast concrete. TECHNOLOGY REVIEW – A

  8. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    cement industry Oxygen enrichment technology Post-combustionOther Benefits: ? Oxygen enrichment technology reduces fuelprocess. Oxy-fuel technology uses oxygen instead of air in

  9. Alex Benson Cement Plants

    E-Print Network [OSTI]

    Toohey, Darin W.

    with steel balls which grind mix into a fine powder -> Final Cement Product Associated Air Pollution: o From health effects Relative News; o "EPA Clamps down on Cement Plant Pollution" http.4 million dollars for violating the Clean Air Act and 2 million dollars for pollution controls #12

  10. Evaluation of Life-Cycle Assessment Studies of Chinese Cement Production: Challenges and Opportunities

    SciTech Connect (OSTI)

    Lu, Hongyou; Masanet, Eric; Price, Lynn

    2009-05-29T23:59:59.000Z

    The use of life-cycle assessment (LCA) to understand the embodied energy, environmental impacts, and potential energy-savings of manufactured products has become more widespread among researchers in recent years. This paper reviews recent LCA studies in the cement industry in China and in other countries and provides an assessment of the methodology used by the researchers compared to ISO LCA standards (ISO 14040:2006, ISO 14044:2006, and ISO/TR 14048:2002). We evaluate whether the authors provide information on the intended application, targeted audience, functional unit, system boundary, data sources, data quality assessment, data disaggregation and other elements, and draw conclusions regarding the level of adherence to ISO standards for the papers reviewed. We found that China researchers have gained much experience during last decade, but still have room for improvement in establishing boundaries, assessing data quality, identifying data sources, and explaining limitations. The paper concludes with a discussion of directions for future LCA research in China.

  11. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    2 abatement using the calcium looping cycle. Energy Environ.the CO 2 captured by the calcium looping system, use of the16. Flow diagram of calcium-looping CO 2 capture and cement

  12. A Review of Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01T23:59:59.000Z

    and Resource Saving Technologies in Cement Industry.1:87–94. Blue World Crete. 2012. Technology. Available atOakey. 2009. CO 2 Capture Technologies for Cement Industry.

  13. The use of electrical impedance spectroscopy for monitoring the hydration products of Portland cement mortars with high percentage of pozzolans

    SciTech Connect (OSTI)

    Cruz, J.M. [Departamento de Física Aplicada, Universitat Politècnica de València, Camino de Vera, 46022, Valencia (Spain)] [Departamento de Física Aplicada, Universitat Politècnica de València, Camino de Vera, 46022, Valencia (Spain); Fita, I.C., E-mail: infifer@fis.upv.es [Departamento de Física Aplicada, Universitat Politècnica de València, Camino de Vera, 46022, Valencia (Spain); Soriano, L.; Payá, J.; Borrachero, M.V. [ICITECH, Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València (Spain)] [ICITECH, Instituto de Ciencia y Tecnología del Hormigón, Universitat Politècnica de València (Spain)

    2013-08-15T23:59:59.000Z

    In this paper, mortars and pastes containing large replacement of pozzolan were studied by mechanical strength, thermogravimetric analysis (TGA), scanning electronic microscopy (SEM), mercury intrusion porosimetry (MIP) and electrical impedance spectroscopy (EIS). The effect of metakaolin (35%) and fly ash (60%) was evaluated and compared with an inert mineral addition (andalusite). The portlandite content was measured, finding that the pozzolanic reaction produced cementing systems with all portlandite fixed. The EIS measurements were analyzed by the equivalent electrical circuit (EEC) method. An EEC with three branches in parallel was applied. The dc resistance was related to the degree of hydration and allowed us to characterize plain and blended mortars. A constant phase element (CPE) quantified the electrical properties of the hydration products located in the solid–solution interface and was useful to distinguish the role of inert and pozzolanic admixtures present in the cement matrix.

  14. Eco-efficient waste glass recycling: Integrated waste management and green product development through LCA

    SciTech Connect (OSTI)

    Blengini, Gian Andrea, E-mail: blengini@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); CNR-IGAG, Institute of Environmental Geology and Geo-Engineering, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Busto, Mirko, E-mail: mirko.busto@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fantoni, Moris, E-mail: moris.fantoni@polito.it [DITAG - Department of Land, Environment and Geo-Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fino, Debora, E-mail: debora.fino@polito.it [DISMIC - Department of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer A new eco-efficient recycling route for post-consumer waste glass was implemented. Black-Right-Pointing-Pointer Integrated waste management and industrial production are crucial to green products. Black-Right-Pointing-Pointer Most of the waste glass rejects are sent back to the glass industry. Black-Right-Pointing-Pointer Recovered co-products give more environmental gains than does avoided landfill. Black-Right-Pointing-Pointer Energy intensive recycling must be limited to waste that cannot be closed-loop recycled. - Abstract: As part of the EU Life + NOVEDI project, a new eco-efficient recycling route has been implemented to maximise resources and energy recovery from post-consumer waste glass, through integrated waste management and industrial production. Life cycle assessment (LCA) has been used to identify engineering solutions to sustainability during the development of green building products. The new process and the related LCA are framed within a meaningful case of industrial symbiosis, where multiple waste streams are utilised in a multi-output industrial process. The input is a mix of rejected waste glass from conventional container glass recycling and waste special glass such as monitor glass, bulbs and glass fibres. The green building product is a recycled foam glass (RFG) to be used in high efficiency thermally insulating and lightweight concrete. The environmental gains have been contrasted against induced impacts and improvements have been proposed. Recovered co-products, such as glass fragments/powders, plastics and metals, correspond to environmental gains that are higher than those related to landfill avoidance, whereas the latter is cancelled due to increased transportation distances. In accordance to an eco-efficiency principle, it has been highlighted that recourse to highly energy intensive recycling should be limited to waste that cannot be closed-loop recycled.

  15. Recovery Act Production of Algal BioCrude Oil from Cement Plant Carbon Dioxide

    SciTech Connect (OSTI)

    Robert Weber; Norman Whitton

    2010-09-30T23:59:59.000Z

    The consortium, led by Sunrise Ridge Algae Inc, completed financial, legal, siting, engineering and environmental permitting preparations for a proposed demonstration project that would capture stack gas from an operating cement plant and convert the carbon dioxide to beneficial use as a liquid crude petroleum substitute and a coal substitute, using algae grown in a closed system, then harvested and converted using catalyzed pyrolysis.

  16. Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna; Sickafus, Kurt E.

    2010-09-23T23:59:59.000Z

    In this study, glass ceramics were explored as an alternative waste form for glass, the current baseline, to be used for immobilizing alkaline/alkaline earth + lanthanide (CS+LN) or CS+LN+transition metal (TM) fission-product waste streams generated by a uranium extraction (UREX+) aqueous separations type process. Results from past work on a glass waste form for the combined CS+LN waste streams showed that as waste loading increased, large fractions of crystalline phases precipitated upon slow cooling.[1] The crystalline phases had no noticeable impact on the waste form performance by the 7-day product consistency test (PCT). These results point towards the development of a glass ceramic waste form for treating CS+LN or CS+LN+TM combined waste streams. Three main benefits for exploring glass ceramics are: (1) Glass ceramics offer increased solubility of troublesome components in crystalline phases as compared to glass, leading to increased waste loading; (2) The crystalline network formed in the glass ceramic results in higher heat tolerance than glass; and (3) These glass ceramics are designed to be processed by the same melter technology as the current baseline glass waste form. It will only require adding controlled canister cooling for crystallization into a glass ceramic waste form. Highly annealed waste form (essentially crack free) with up to 50X lower surface area than a typical High-Level Waste (HLW) glass canister. Lower surface area translates directly into increased durability. This was the first full year of exploring glass ceramics for the Option 1 and 2 combined waste stream options. This work has shown that dramatic increases in waste loading are achievable by designing a glass ceramic waste form as an alternative to glass. Table S1 shows the upper limits for heat, waste loading (based on solubility), and the decay time needed before treatment can occur for glass and glass ceramic waste forms. The improvements are significant for both combined waste stream options in terms of waste loading and/or decay time required before treatment. For Option 1, glass ceramics show an increase in waste loading of 15 mass % and reduction in decay time of 24 years. Decay times of {approx}50 years or longer are close to the expected age of the fuel that will be reprocessed when the modified open or closed fuel cycle is expected to be put into action. Option 2 shows a 2x to 2.5x increase in waste loading with decay times of only 45 years. Note that for Option 2 glass, the required decay time before treatment is only 35 years because of the waste loading limits related to the solubility of MoO{sub 3} in glass. If glass was evaluated for similar waste loadings as those achieved in Option 2 glass ceramics, the decay time would be significantly longer than 45 years. These glass ceramics are not optimized, but already they show the potential to dramatically reduce the amount of waste generated while still utilizing the proven processing technology used for glass production.

  17. ULTRA-LIGHTWEIGHT CEMENT

    SciTech Connect (OSTI)

    Fred Sabins

    2001-10-23T23:59:59.000Z

    The objective of this project is to develop an improved ultra-lightweight cement using ultra-lightweight hollow glass spheres (ULHS). Work reported herein addresses tasks performed in the fourth quarter as well as the other three quarters of the past year. The subjects that were covered in previous reports and that are also discussed in this report include: Analysis of field laboratory data of active cement applications from three oil-well service companies; Preliminary findings from a literature review focusing on problems associated with ultra-lightweight cements; Summary of pertinent information from Russian ultra-lightweight cement literature review; and Comparison of compressive strengths of ULHS systems using ultrasonic and crush methods Results reported from the fourth quarter include laboratory testing of ULHS systems along with other lightweight cement systems--foamed and sodium silicate slurries. These comparison studies were completed for two different densities (10.0 and 11.5 lb/gal) and three different field application scenarios. Additional testing included the mechanical properties of ULHS systems and other lightweight systems. Studies were also performed to examine the effect that circulation by centrifugal pump during mixing has on breakage of ULHS.

  18. Thermodynamics and cement science

    SciTech Connect (OSTI)

    Damidot, D., E-mail: damidot@ensm-douai.fr [Universite Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France); Lothenbach, B. [Empa, Lab. Concrete and Construction Chemistry, Duebendorf (Switzerland); Herfort, D. [Cementir Holding (Denmark); Glasser, F.P. [Chemistry Department, University of Aberdeen, Aberdeen (United Kingdom)

    2011-07-15T23:59:59.000Z

    Thermodynamics applied to cement science has proved to be very valuable. One of the most striking findings has been the extent to which the hydrate phases, with one conspicuous exception, achieve equilibrium. The important exception is the persistence of amorphous C-S-H which is metastable with respect to crystalline calcium silicate hydrates. Nevertheless C-S-H can be included in the scope of calculations. As a consequence, from comparison of calculation and experiment, it appears that kinetics is not necessarily an insuperable barrier to engineering the phase composition of a hydrated Portland cement. Also the sensitivity of the mineralogy of the AFm and AFt phase compositions to the presence of calcite and to temperature has been reported. This knowledge gives a powerful incentive to develop links between the mineralogy and engineering properties of hydrated cement paste and, of course, anticipates improvements in its performance leading to decreasing the environmental impacts of cement production.

  19. Production of a High-Level Waste Glass from Hanford Waste Samples

    SciTech Connect (OSTI)

    Crawford, C.L. [Westinghouse Savannah River Company, AIKEN, SC (United States); Farrara, D.M.; Ha, B.C.; Bibler, N.E.

    1998-09-01T23:59:59.000Z

    The HLW glass was produced from a HLW sludge slurry (Envelope D Waste), eluate waste streams containing high levels of Cs-137 and Tc-99, solids containing both Sr-90 and transuranics (TRU), and glass-forming chemicals. The eluates and Sr-90/TRU solids were obtained from ion-exchange and precipitation pretreatments, respectively, of other Hanford supernate samples (Envelopes A, B and C Waste). The glass was vitrified by mixing the different waste streams with glass-forming chemicals in platinum/gold crucibles and heating the mixture to 1150 degree C. Resulting glass analyses indicated that the HLW glass waste form composition was close to the target composition. The targeted waste loading of Envelope D sludge solids in the HLW glass was 30.7 wt percent, exclusive of Na and Si oxides. Condensate samples from the off-gas condenser and off-gas dry-ice trap indicated that very little of the radionuclides were volatilized during vitrification. Microstructure analysis of the HLW glass using Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Analysis (EDAX) showed what appeared to be iron spinel in the HLW glass. Further X-Ray Diffraction (XRD) analysis confirmed the presence of nickel spinel trevorite (NiFe2O4). These crystals did not degrade the leaching characteristics of the glass. The HLW glass waste form passed leach tests that included a standard 90 degree C Product Consistency Test (PCT) and a modified version of the United States Environmental Protection Agency Toxicity Characteristic Leaching Procedure (TCLP).

  20. Thermal Shock-resistant Cement

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.; Gill, S.

    2012-02-01T23:59:59.000Z

    We studied the effectiveness of sodium silicate-activated Class F fly ash in improving the thermal shock resistance and in extending the onset of hydration of Secar #80 refractory cement. When the dry mix cement, consisting of Secar #80, Class F fly ash, and sodium silicate, came in contact with water, NaOH derived from the dissolution of sodium silicate preferentially reacted with Class F fly ash, rather than the #80, to dissociate silicate anions from Class F fly ash. Then, these dissociated silicate ions delayed significantly the hydration of #80 possessing a rapid setting behavior. We undertook a multiple heating -water cooling quenching-cycle test to evaluate the cement’s resistance to thermal shock. In one cycle, we heated the 200 and #61616;C-autoclaved cement at 500 and #61616;C for 24 hours, and then the heated cement was rapidly immersed in water at 25 and #61616;C. This cycle was repeated five times. The phase composition of the autoclaved #80/Class F fly ash blend cements comprised four crystalline hydration products, boehmite, katoite, hydrogrossular, and hydroxysodalite, responsible for strengthening cement. After a test of 5-cycle heat-water quenching, we observed three crystalline phase-transformations in this autoclaved cement: boehmite and #61614; and #61543;-Al2O3, katoite and #61614; calcite, and hydroxysodalite and #61614; carbonated sodalite. Among those, the hydroxysodalite and #61614; carbonated sodalite transformation not only played a pivotal role in densifying the cementitious structure and in sustaining the original compressive strength developed after autoclaving, but also offered an improved resistance of the #80 cement to thermal shock. In contrast, autoclaved Class G well cement with and without Class F fly ash and quartz flour failed this cycle test, generating multiple cracks in the cement. The major reason for such impairment was the hydration of lime derived from the dehydroxylation of portlandite formed in the autoclaved cement, causing its volume to expand.

  1. Focused Ion Beam Production Using a Pyroelectric Crystal and a Resistive Glass Tube

    E-Print Network [OSTI]

    Danon, Yaron

    Focused Ion Beam Production Using a Pyroelectric Crystal and a Resistive Glass Tube T. Z. Fullem, A to accelerate electrons into a metal target has led to the production of compact X-Ray generators [4], [5], [6 tungsten tip (marketed for use in a scanning electron microscope) with an apex radius of 70 nm was mounted

  2. Summary Report: Glass-Ceramic Waste Forms for Combined Fission Products

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Riley, Brian J.; Turo, Laura A.; Tang, Ming; Kossoy, Anna

    2011-09-23T23:59:59.000Z

    Glass-ceramic waste form development began in FY 2010 examining two combined waste stream options: (1) alkaline earth (CS) + lanthanide (Ln), and (2) + transition metal (TM) fission-product waste streams generated by the uranium extraction (UREX+) separations process. Glass-ceramics were successfully developed for both options however; Option 2 was selected over Option 1, at the conclusion of 2010, because Option 2 immobilized all three waste streams with only a minimal decrease in waste loading. During the first year, a series of three glass (Option 2) were fabricated that varied waste loading-WL (42, 45, and 50 mass%) at fixed molar ratios of CaO/MoO{sub 3} and B{sub 2}O{sub 3}/alkali both at 1.75. These glass-ceramics were slow cooled and characterized in terms of phase assemblage and preliminary irradiation stability. This fiscal year, further characterization was performed on the FY 2010 Option 2 glass-ceramics in terms of: static leach testing, phase analysis by transmission electron microscopy (TEM), and irradiation stability (electron and ion). Also, a new series of glass-ceramics were developed for Option 2 that varied the additives: Al{sub 2}O{sub 3} (0-6 mass%), molar ratio of CaO/MoO{sub 3} and B{sub 2}O{sub 3}/alkali (1.75 to 2.25) and waste loading (50, 55, and 60 mass%). Lastly, phase pure powellite and oxyapatite were synthesized for irradiation studies. Results of this fiscal year studies showed compositional flexibility, chemical stability, and radiation stability in the current glass-ceramic system. First, the phase assemblages and microstructure of all of the FY 2010 and 2011 glass-ceramics are very similar once subjected to the slow cool heat treatment. The phases identified in these glass-ceramics were oxyapatite, powellite, cerianite, and ln-borosilicate. This shows that variations in waste loading or additives can be accommodated without drastically changing the phase assemblage of the waste form, thus making the processing and performance characteristics of the waste form more predictable/flexible. However, in the future, the glass phase still needs to be accurately characterized to determine the effects of waste loading and additives on the glass structure. Initial investigations show a borosilicate glass phase rich in silica. Second, the normalized concentrations of elements leached from the waste form during static leach testing were all below 0.6 g/L after 28d at 90 C, by the Product Consistency Test (PCT), method B. These normalized concentrations are on par with durable waste glasses such as the Low-Activity Reference Material (LRM) glass. The release rates for the crystalline phases (oxyapatite and powellite) appear to be lower (more durable) than the glass phase based on the relatively low release rates of Mo, Ca, and Ln found in the crystalline phases compared to Na and B that are mainly observed in the glass phase. However, further static leach testing on individual crystalline phases is needed to confirm this statement. Third, Ion irradiation and In situ TEM observations suggest that these crystalline phases (such as oxyapatite, ln-borosilicate, and powellite) in silicate based glass ceramic waste forms exhibit stability to 1000 years at anticipated doses (2 x 10{sup 10}-2 x 10{sup 11} Gy). This is adequate for the short lived isotopes in the waste, which lead to a maximum cumulative dose of {approx}7 x 10{sup 9} Gy, reached after {approx}100 yrs, beyond which the dose contributions are negligible. The cumulate dose calculations are based on a glass-ceramic at WL = 50 mass%, where the fuel has a burn-up of 51GWd/MTIHM, immobilized after 5 yr decay from reactor discharge.

  3. Energy Saving Method of Manufacturing Ceramic Products from Fiber Glass Waste

    SciTech Connect (OSTI)

    Michael J. Haun

    2005-07-15T23:59:59.000Z

    The U.S. fiber glass industry disposes of more than 260,000 tons of industrial fiber glass waste in landfills annually. New technology is needed to reprocess this industrial waste into useful products. A low-cost energy-saving method of manufacturing ceramic tile from fiber glass waste was developed. The technology is based on sintering fiber glass waste at 700-900 degrees C to produce products which traditionally require firing temperatures of >1200 degrees C, or glass-melting temperatures >1500 degrees C. The process also eliminates other energy intensive processing steps, including mining and transportation of raw materials, spray-drying to produce granulated powder, drying pressed tile, and glazing. The technology completely transforms fiber glass waste into a dense ceramic product, so that all future environmental problems in the handling and disposal of the fibers is eliminated. The processing steps were developed and optimized to produce glossy and matte surface finishes for wall and floor tile applications. High-quality prototype tile samples were processed for demonstration and tile standards testing. A Market Assessment confirmed the market potential for tile products produced by the technology. Manufacturing equipment trials were successfully conducted for each step of the process. An industrial demonstration plant was designed, including equipment and operating cost analysis. A fiber glass manufacturer was selected as an industrial partner to commercialize the technology. A technology development and licensing agreement was completed with the industrial partner. Haun labs will continue working to transfer the technology and assist the industrial partner with commercialization beyond the DOE project.

  4. Standard test methods for determining chemical durability of nuclear, hazardous, and mixed waste glasses and multiphase glass ceramics: The product consistency test (PCT)

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2002-01-01T23:59:59.000Z

    1.1 These product consistency test methods A and B evaluate the chemical durability of homogeneous glasses, phase separated glasses, devitrified glasses, glass ceramics, and/or multiphase glass ceramic waste forms hereafter collectively referred to as “glass waste forms” by measuring the concentrations of the chemical species released to a test solution. 1.1.1 Test Method A is a seven-day chemical durability test performed at 90 ± 2°C in a leachant of ASTM-Type I water. The test method is static and conducted in stainless steel vessels. Test Method A can specifically be used to evaluate whether the chemical durability and elemental release characteristics of nuclear, hazardous, and mixed glass waste forms have been consistently controlled during production. This test method is applicable to radioactive and simulated glass waste forms as defined above. 1.1.2 Test Method B is a durability test that allows testing at various test durations, test temperatures, mesh size, mass of sample, leachant volume, a...

  5. Case studies of the potential effects of carbon taxation on the stone, clay, and glass industry

    SciTech Connect (OSTI)

    Bock, M.J.; Boyd, G.A. (Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.); Rosenbaum, D.I. (Nebraska Univ., Lincoln, NE (United States). Dept. of Economics); Ross, M.H. (Michigan Univ., Ann Arbor, MI (United States). Dept. of Physics)

    1992-12-01T23:59:59.000Z

    This case study focuses on the potential for a carbon tax ($25 and $100 per metric ton of carbon) to reduce energy use and associated carbon dioxide (CO[sub 2]) emissions in three subsectors of the stone, clay, and glass industry: hydraulic cement, glass and glass products, and other products. A conservation supply curve analysis found that (1) opportunities for reducing fossil fuel use in the subsectors are limited (15% reduction under $100 tax) and (2) the relationship between the tax and reduced CO[sub 2] emissions is nonlinear and diminishing. Because cement manufacturing produces a significant amount of CO[sub 2], this subsector was analyzed. A plant-level analysis found more opportunities to mitigate CO[sub 2] emissions; under a $100 tax, fossil fuel use would decrease 52%. (A conservative estimate lies between 15% and 52%). It also confirmed the nonlinear relationship, suggesting significant benefits could result from small taxes (32% reduction under $25 tax). A fuel share analysis found the cement industry could reduce carbon loading 11% under a $100 tax if gas were substituted for coal. Under a $100 tax, cement demand would decrease 17% and its price would increase 32%, a substantial increase for a material commodity. Overall, CO[sub 2] emissions from cement manufacturing would decrease 24--33% under a $100 tax and 10--18% under a $25 tax. Much of the decrease would result from the reduced demand for cement.

  6. Case studies of the potential effects of carbon taxation on the stone, clay, and glass industry

    SciTech Connect (OSTI)

    Bock, M.J.; Boyd, G.A. [Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.; Rosenbaum, D.I. [Nebraska Univ., Lincoln, NE (United States). Dept. of Economics; Ross, M.H. [Michigan Univ., Ann Arbor, MI (United States). Dept. of Physics

    1992-12-01T23:59:59.000Z

    This case study focuses on the potential for a carbon tax ($25 and $100 per metric ton of carbon) to reduce energy use and associated carbon dioxide (CO{sub 2}) emissions in three subsectors of the stone, clay, and glass industry: hydraulic cement, glass and glass products, and other products. A conservation supply curve analysis found that (1) opportunities for reducing fossil fuel use in the subsectors are limited (15% reduction under $100 tax) and (2) the relationship between the tax and reduced CO{sub 2} emissions is nonlinear and diminishing. Because cement manufacturing produces a significant amount of CO{sub 2}, this subsector was analyzed. A plant-level analysis found more opportunities to mitigate CO{sub 2} emissions; under a $100 tax, fossil fuel use would decrease 52%. (A conservative estimate lies between 15% and 52%). It also confirmed the nonlinear relationship, suggesting significant benefits could result from small taxes (32% reduction under $25 tax). A fuel share analysis found the cement industry could reduce carbon loading 11% under a $100 tax if gas were substituted for coal. Under a $100 tax, cement demand would decrease 17% and its price would increase 32%, a substantial increase for a material commodity. Overall, CO{sub 2} emissions from cement manufacturing would decrease 24--33% under a $100 tax and 10--18% under a $25 tax. Much of the decrease would result from the reduced demand for cement.

  7. A new Energy Saving method of manufacturing ceramic products from waste glass

    SciTech Connect (OSTI)

    Haun Labs

    2002-07-05T23:59:59.000Z

    This final report summarizes the activities of the DOE Inventions and Innovations sponsored project, ''A New Energy Saving Method of Manufacturing Ceramic Products from Waste Glass.'' The project involved an innovative method of lowering energy costs of manufacturing ceramic products by substituting traditional raw materials with waste glass. The processing method is based on sintering of glass powder at {approx}750 C to produce products which traditionally require firing temperatures of >1200 C, or glass-melting temperatures >1500 C. The key to the new method is the elimination of previous processing problems, which have greatly limited the use of recycled glass as a ceramic raw material. The technology is aligned with the DOE-OIT Glass Industry Vision and Roadmap, and offers significant energy savings and environmental benefits compared to current technologies. A U.S. patent (No. 6,340,650) covering the technology was issued on January 22, 2002. An international PCT Patent Application is pending with designations made for all PCT regions and countries. The goal of the project was to provide the basis for the design and construction of an energy-efficient manufacturing plant that can convert large volumes of waste glass into high-quality ceramic tile. The main objectives of the project were to complete process development and optimization; construct and test prototype samples; and conduct market analysis and commercialization planning. Two types of ceramic tile products were targeted by the project. The first type was developed during the first year (Phase I) to have a glazed-like finish for applications where slip resistance is not critical, such as wall tile. The processing method optimized in Phase I produces a glossy surface with a translucent appearance, without the extra glazing steps required in traditional tile manufacturing. The second type of product was developed during the second year (Phase II). This product was designed to have an unglazed appearance for applications requiring slip resistance, such as floor tile. The coarser matte finish of this product type was produced by modifying the basic process to include crystalline fillers and partial crystallization of the glass. Additional details of the project results are discussed in Section III.

  8. The proposed fixation of sludge in cement at the Feed Materials Production Center

    SciTech Connect (OSTI)

    Gimpel, R.F.

    1990-12-01T23:59:59.000Z

    The Feed Materials Production Center (FMPC), located near Cincinnati, Ohio, is a government-owned facility. Westinghouse Materials Company of Ohio (WMCO) is the prime contractor to the United States Department of Energy (DOE) at the FMPC. DOE has entered into a Consent Agreement with the United States Environmental Protection Agency (US EPA) to remediate the FMPC site. A project known as the Environmental Remedial Action (ERA) Project was created to accomplish the task of remediating the site. The majority of the estimated $2-billion ERA Project was broken into five smaller manageable subtasks called operable units.'' Each operable unit is handled as a project with its own project manager/engineer. Due to the project's complexity and stringent completion dates, DOE and WMCO have devised a project management philosophy to ensure the successful completion of the ERA Project. This paper will discuss the ERA project and the development needs to accomplish this project. In particular, development of processes for the treatment of waste sludges for Operable Units 1 and 4 will be discussed. Operable Units 2 sludges will be treated in a similar fashion to Operable Unit 1 if it is determined these sludges need treatment. 4 refs., 5 figs., 9 tabs.

  9. Characterization and modeling of the cemented sediment surrounding...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cement phase is likely the reaction between the glass and the sea water to from a Mg-silicate, here modeled as sepiolite. Citation: Strachan DM, JV Crum, JV Ryan, and A...

  10. Radiation effects in moist-air systems and the influence of radiolytic product formation on nuclear waste glass corrosion

    SciTech Connect (OSTI)

    Wronkiewicz, D.J.; Bates, J.K.; Buck, E.C.; Hoh, J.C.; Emery, J.W. [Argonne National Lab., IL (United States). Chemical Technology Div.; Wang, L.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Geology

    1997-07-01T23:59:59.000Z

    Ionizing radiation may affect the performance of glass in an unsaturated repository site by interacting with air, water vapor, or liquid water to produce a variety of radiolytic products. Tests were conducted to examine the effects of radiolysis under high gas/liquid ratios. Results indicate that nitrate is the predominant radiolytic product produced following both gamma and alpha radiation exposure, with lesser amounts of nitrite and carboxylic acids. The formation of nitrogen acids during exposure to long-lived, alpha-particle-emitting transuranic elements indicates that these acids may play a role in influencing nuclear waste form reactions in a long-term unsaturated disposal scenario. Experiments were also conducted with samples that simulate the composition of Savannah River Plant nuclear waste glasses. Radiolytic product formation in batch tests (340 m{sup {minus}1}, 90 C) resulted in a small increase in the release rates of many glass components, such as alkali and alkaline earth elements, although silicon and uranium release rates were slightly reduced indicating an overall beneficial effect of radiation on waste form stability. The radiolytic acids increased the rate of ion exchange between the glass and the thin film of condensate, resulting in accelerated corrosion rates for the glass. The paragenetic sequence of alteration phases formed on both the irradiated and nonirradiated glass samples reacted in the vapor hydration tests matches closely with those developed during volcanic glass alteration in naturally occurring saline-alkaline lake systems. This correspondence suggests that the high temperatures used in these tests have not changed the underlying glass reaction mechanism relate to that which controls glass reactions under ambient surficial conditions.

  11. A Review of Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, A.; Price, L.; Lin, E.

    2012-01-01T23:59:59.000Z

    - Environmental Advantages. Available at http://www.ceratechinc.com/environmental- advantages.asp Cross, D., J. Stephens, J. Vollmer. 2005. Structural Applications of 100 Percent Fly Ash Concrete. 2005 World of Coal Ash (WOCA), Lexington, Kentucky, USAApril...://recocement.com/ Roskos, C., D. Cross, M. Berry, J. Stephens. 2011. Identification and Verification of Self-Cementing Fly Ash Binders for ?Green? Concrete. 2011 World of Coal Ash (WOCA) Conference ? May 9-12, 2011 in Denver CO, USA. Available at www.flyash.info/2011...

  12. Improved microstructure of cement-based composites through the addition of rock wool particles

    SciTech Connect (OSTI)

    Lin, Wei-Ting [Dept. of Civil Engineering, National Ilan University, Ilan 26047, Taiwan (China); Institute of Nuclear Energy Research, Atomic Energy Council, Taoyuan 32546, Taiwan (China); Cheng, An, E-mail: ancheng@niu.edu.tw [Dept. of Civil Engineering, National Ilan University, Ilan 26047, Taiwan (China); Huang, Ran; Zou, Si-Yu [Dept. of Harbor and River Engineering, National Taiwan Ocean University, Keelung 20224, Taiwan (China)

    2013-10-15T23:59:59.000Z

    Rock wool is an inorganic fibrous substance produced by steam blasting and cooling molten glass. As with other industrial by-products, rock wool particles can be used as cementitious materials or ultra fine fillers in cement-based composites. This study investigated the microstructure of mortar specimens produced with cement-based composites that include various forms of rock wool particles. It conducted compressive strength testing, rapid chloride penetration tests, X-ray diffraction analysis, thermo-gravimetric analysis, and scanning electronic microscopy to evaluate the macro- and micro-properties of the cement-based composites. Test results indicate that inclusion of rock wool particles in composites improved compressive strength and reduced chloride ion penetration at the age of 91 days due to the reduction of calcium hydroxide content. Microscopic analysis confirms that the use of rock wool particles contributed to the formation of a denser, more compact microstructure within the hardened paste. In addition, X-ray diffraction analysis shows few changes in formation of pozzolanic reaction products and no new hydrations are formed with incorporating rock wool particles. - Highlights: • We report the microstructural characterization of cement-based composites. • Different mixes produced with various rock wool particles have been tested. • The influence of different mixes on macro and micro properties has been discussed. • The macro properties are included compressive strength and permeability. • XRD and SEM observations confirm the pozzolanic reaction in the resulting pastes.

  13. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G. [Oak Ridge National Lab., TN (United States); Andres, R.J. [University of Alaska, Fairbanks, AK (United States). Inst. of Northern Engineering

    1995-12-01T23:59:59.000Z

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  14. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    production instantly reaches the current world best practice energyworld best practice and implement aggressive energy efficiency and carbon reduction measures in all cement productionenergy intensity of China’s cement production would reach current world

  15. Capture of green-house carbon dioxide in Portland cement

    SciTech Connect (OSTI)

    Wagh, A.S.; Singh, D.; Pullockaran, J.; Knox, L.

    1993-12-31T23:59:59.000Z

    A novel process has been developed to sequester green-house carbon dioxide produced by the cement industry in precast cement products. Typically, 10--24 wt % of CO{sub 2} produced by calcination of calcium carbonate during clinkering of the cement may be captured. The carbonation process also cures the cement paste within minutes into hard bodies. The process maintains high pH conditions during curing, to allow conventional steel reinforcement of concrete. The process will save time and money to the cement industry, and at the same time, help them to comply with the Clean Air Act by sequestering the green-house carbon dioxide.

  16. Problems in squeeze cementing

    SciTech Connect (OSTI)

    Toor, I.A.

    1983-03-01T23:59:59.000Z

    For the past half century, work has been carried out to improve squeeze cementing. During the course of time, new techniques, equipment, cement and cement additives were introduced. Work is still underway to improve squeeze cementing. Basic concept of squeeze cementing, understanding the problems, planning for a squeeze job and then later testing of the job help in achieving the goal. Solutions were offered to some common problems, whereas many regional problems need time to time study and effort. Squeezing long perforations in highly permeable sand has always been a problem, for which some techniques were presented.

  17. CRYSTALLIZATION IN MULTICOMPONENT GLASSES

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR

    2009-10-08T23:59:59.000Z

    In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

  18. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, T.

    1993-09-21T23:59:59.000Z

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

  19. Quantifying the Co-benefits of Energy-Efficiency Programs: A Case Study of the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2014-01-01T23:59:59.000Z

    ingredient in cement: vertical shaft kilns and rotary kilns.cement was produced by plants using outdated vertical shaft kilns (Vertical shaft kilns (Mt) Rotary (NSP + other) kilns (Mt) Clinker production (Mt) Clinker-cement

  20. Nano-ChemoMechanical assessment of Rice Husk Ash cement by wavelength dispersive spectroscopy and nanoindentation

    E-Print Network [OSTI]

    Abuhaikal, Muhannad (Muhannad A. R.)

    2011-01-01T23:59:59.000Z

    Cement global production stands at 3 Giga tons making concrete the most consumed structural mateial worldwide. This massively produced material comes with a heavy environmental footprint rendering the cement industry ...

  1. Alternative Fuel for Portland Cement Processing

    SciTech Connect (OSTI)

    Anton K. Schindler; Steve R. Duke; Thomas E. Burch; Edward W. Davis; Ralph H. Zee; David I. Bransby; Carla Hopkins; Rutherford L. Thompson; Jingran Duan; Vignesh Venkatasubramanian; Stephen Giles.

    2012-06-30T23:59:59.000Z

    The production of cement involves a combination of numerous raw materials, strictly monitored system processes, and temperatures on the order of 1500 °C. Immense quantities of fuel are required for the production of cement. Traditionally, energy from fossil fuels was solely relied upon for the production of cement. The overarching project objective is to evaluate the use of alternative fuels to lessen the dependence on non-renewable resources to produce portland cement. The key objective of using alternative fuels is to continue to produce high-quality cement while decreasing the use of non-renewable fuels and minimizing the impact on the environment. Burn characteristics and thermodynamic parameters were evaluated with a laboratory burn simulator under conditions that mimic those in the preheater where the fuels are brought into a cement plant. A drop-tube furnace and visualization method were developed that show potential for evaluating time- and space-resolved temperature distributions for fuel solid particles and liquid droplets undergoing combustion in various combustion atmospheres. Downdraft gasification has been explored as a means to extract chemical energy from poultry litter while limiting the throughput of potentially deleterious components with regards to use in firing a cement kiln. Results have shown that the clinkering is temperature independent, at least within the controllable temperature range. Limestone also had only a slight effect on the fusion when used to coat the pellets. However, limestone addition did display some promise in regards to chlorine capture, as ash analyses showed chlorine concentrations of more than four times greater in the limestone infused ash as compared to raw poultry litter. A reliable and convenient sampling procedure was developed to estimate the combustion quality of broiler litter that is the best compromise between convenience and reliability by means of statistical analysis. Multi-day trial burns were conducted at a full-scale cement plant with alternative fuels to examine their compatibility with the cement production process. Construction and demolition waste, woodchips, and soybean seeds were used as alternative fuels at a full-scale cement production facility. These fuels were co-fired with coal and waste plastics. The alternative fuels used in this trial accounted for 5 to 16 % of the total energy consumed during these burns. The overall performance of the portland cement produced during the various trial burns performed for practical purposes very similar to the cement produced during the control burn. The cement plant was successful in implementing alternative fuels to produce a consistent, high-quality product that increased cement performance while reducing the environmental footprint of the plant. The utilization of construction and demolition waste, woodchips and soybean seeds proved to be viable replacements for traditional fuels. The future use of these fuels depends on local availability, associated costs, and compatibility with a facilityâ??s production process.

  2. Multi-phase glass-ceramics as a waste form for combined fission products: alkalis, alkaline earths, lanthanides, and transition metals

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna

    2012-04-01T23:59:59.000Z

    In this study, multi-phase silicate-based glass-ceramics were investigated as an alternate waste form for immobilizing non-fissionable products from used nuclear fuel. Currently, borosilicate glass is the waste form selected for immobilization of this waste stream, however, the low thermal stability and solubility of MoO{sub 3} in borosilicate glass translates into a maximum waste loading in the range of 15-20 mass%. Glass-ceramics provide the opportunity to target durable crystalline phases, e.g., powellite, oxyapatite, celsian, and pollucite, that will incorporate MoO{sub 3} as well as other waste components such as lanthanides, alkalis, and alkaline earths at levels 2X the solubility limits of a single-phase glass. In addition a glass-ceramic could provide higher thermal stability, depending upon the properties of the crystalline and amorphous phases. Glass-ceramics were successfully synthesized at waste loadings of 42, 45, and 50 mass% with the following glass additives: B{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, CaO and SiO{sub 2} by slow cooling form from a glass melt. Glass-ceramics were characterized in terms of phase assemblage, morphology, and thermal stability. The targeted phases: powellite and oxyapatite were observed in all of the compositions along with a lanthanide borosilicate, and cerianite. Results of this initial investigation of glass-ceramics show promise as a potential waste form to replace single-phase borosilicate glass.

  3. Determining the dissolution rates of actinide glasses: A time and temperature Product Consistency Test study

    SciTech Connect (OSTI)

    Daniel, W.E.; Best, D.R.

    1995-12-01T23:59:59.000Z

    Vitrification has been identified as one potential option for the e materials such as Americium (Am), Curium (Cm), Neptunium (Np), and Plutonium (Pu). A process is being developed at the Savannah River Site to safely vitrify all of the highly radioactive Am/Cm material and a portion of the fissile (Pu) actinide materials stored on site. Vitrification of the Am/Cm will allow the material to be transported and easily stored at the Oak Ridge National Laboratory. The Am/Cm glass has been specifically designed to be (1) highly durable in aqueous environments and (2) selectively attacked by nitric acid to allow recovery of the valuable Am and Cm isotopes. A similar glass composition will allow for safe storage of surplus plutonium. This paper will address the composition, relative durability, and dissolution rate characteristics of the actinide glass, Loeffler Target, that will be used in the Americium/Curium Vitrification Project at Westinghouse Savannah River Company near Aiken, South Carolina. The first part discusses the tests performed on the Loeffler Target Glass concerning instantaneous dissolution rates. The second part presents information concerning pseudo-activation energy for the one week glass dissolution process.

  4. Comparison of modified sulfur cement and hydraulic cement for encapsulation of radioactive and mixed wastes

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1990-01-01T23:59:59.000Z

    The majority of solidification/stabilization systems for low-level radioactive waste (LLW) and mixed waste, both in the commercial sector and at Department of Energy (DOE) facilities, utilize hydraulic cement (such as portland cement) to encapsulate waste materials and yield a monolithic solid waste form for disposal. A new and innovative process utilizing modified sulfur cement developed by the US Bureau of Mines has been applied at Brookhaven National Laboratory (BNL) for the encapsulation of many of these problem'' wastes. Modified sulfur cement is a thermoplastic material, and as such, it can be heated above it's melting point (120{degree}C), combined with dry waste products to form a homogeneous mixture, and cooled to form a monolithic solid product. Under sponsorship of the DOE, research and development efforts at BNL have successfully applied the modified sulfur cement process for treatment of a range of LLWs including sodium sulfate salts, boric acid salts, and incinerator bottom ash and for mixed waste contaminated incinerator fly ash. Process development studies were conducted to determine optimal waste loadings for each waste type. Property evaluation studies were conducted to test waste form behavior under disposal conditions by applying relevant performance testing criteria established by the Nuclear Regulatory Commission (for LLW) and the Environmental Protection Agency (for hazardous wastes). Based on both processing and performance considerations, significantly greater waste loadings were achieved using modified sulfur cement when compared with hydraulic cement. Technology demonstration of the modified sulfur cement encapsulation system using production-scale equipment is scheduled for FY 1991. 12 refs., 8 figs., 3 tabs.

  5. The Production of Advanced Glass Ceramic HLW Forms using Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    Veronica J Rutledge; Vince Maio

    2013-10-01T23:59:59.000Z

    Cold Crucible Induction Melters (CCIMs) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in the 21st century. Unlike the existing Joule-Heated Melters (JHMs) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIMs offer unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. This paper discusses advantageous features of the CCIM, with emphasis on features that overcome the historical issues with the JHMs presently utilized, as well as the benefits of glass ceramic waste forms over borosilicate glass waste forms. These advantages are then validated based on recent INL testing to demonstrate a first-of-a-kind formulation of a non-radioactive ceramic-based waste form utilizing a CCIM.

  6. Alkaline resistant phosphate glasses and method of preparation and use thereof

    DOE Patents [OSTI]

    Brow, Richard K. (Rolla, MO); Reis, Signo T. (Rolla, MO); Velez, Mariano (Rolla, MO); Day, Delbert E. (Rolla, MO)

    2010-01-26T23:59:59.000Z

    A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.

  7. Passamaquoddy Technology Recovery Scrubber{trademark} at the Dragon Products, Inc. Cement Plant located in Thomaston, Maine. 1990 Annual technical report

    SciTech Connect (OSTI)

    Not Available

    1990-12-31T23:59:59.000Z

    The background and process of the Passamaquoddy Technology Recovery Scrubber{trademark} are described. The Scrubber was developed for Dragon Cement Plant in Thomaston, Maine and facilitates a number of process improvements. The exhaust gas is scrubbed of SO{sub 2} with better than 90% efficiency. The kiln dust is cleaned of alkalines and so can be returned to kiln feed instead of dumped to landfill. Potassium sulfate in commercial quantity and purity can be recovered. Distilled water is recovered which also has commercial potential. Thus, various benefits are accrued and no waste streams remain for disposal. The process is applicable to both wet and dry process cement kilns and appears to have potential in any industry which generates acidic gaseous exhausts and/or basic solid or liquid wastes.

  8. Energy Efficiency Improvement Opportunities for the Cement Industry

    SciTech Connect (OSTI)

    Price, Lynn; Worrell, Ernst; Galitsky, Christina; Price, Lynn

    2008-01-31T23:59:59.000Z

    This report provides information on the energy savings, costs, and carbon dioxide emissions reductions associated with implementation of a number of technologies and measures applicable to the cement industry. The technologies and measures include both state-of-the-art measures that are currently in use in cement enterprises worldwide as well as advanced measures that are either only in limited use or are near commercialization. This report focuses mainly on retrofit measures using commercially available technologies, but many of these technologies are applicable for new plants as well. Where possible, for each technology or measure, costs and energy savings per tonne of cement produced are estimated and then carbon dioxide emissions reductions are calculated based on the fuels used at the process step to which the technology or measure is applied. The analysis of cement kiln energy-efficiency opportunities is divided into technologies and measures that are applicable to the different stages of production and various kiln types used in China: raw materials (and fuel) preparation; clinker making (applicable to all kilns, rotary kilns only, vertical shaft kilns only); and finish grinding; as well as plant wide measures and product and feedstock changes that will reduce energy consumption for clinker making. Table 1 lists all measures in this report by process to which they apply, including plant wide measures and product or feedstock changes. Tables 2 through 8 provide the following information for each technology: fuel and electricity savings per tonne of cement; annual operating and capital costs per tonne of cement or estimated payback period; and, carbon dioxide emissions reductions for each measure applied to the production of cement. This information was originally collected for a report on the U.S. cement industry (Worrell and Galitsky, 2004) and a report on opportunities for China's cement kilns (Price and Galitsky, in press). The information provided in this report is based on publicly-available reports, journal articles, and case studies from applications of technologies around the world.

  9. 'The Overriding Demand for Energy Conservation in the Cement Industry' An Update

    E-Print Network [OSTI]

    Spellman, L. U.

    1981-01-01T23:59:59.000Z

    addi tives. While cement makes up only about 7 to 15 percent of the weight of concrete, it is 1:5y far the greatest contributor of energy content in the mixture. Cement, usually portland cement, is a product derived from pyro-processing calcareous... and argillaceous materials such as limestone and clay or shale into an intermediate fused material called clinker, which is subse quently ground together with a small amount of gypsum. Portland cement is the principal material produced by the U. S. cement...

  10. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi.

    1989-10-03T23:59:59.000Z

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

  11. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1989-01-01T23:59:59.000Z

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed.

  12. HIGH LEVEL WASTE (HLW) VITRIFICATION EXPERIENCE IN THE US: APPLICATION OF GLASS PRODUCT/PROCESS CONTROL TO OTHERHLW AND HAZARDOUS WASTES

    SciTech Connect (OSTI)

    Jantzen, C; James Marra, J

    2007-09-17T23:59:59.000Z

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. At the Savannah River Site (SRS) actual HLW tank waste has successfully been processed to stringent product and process constraints without any rework into a stable borosilicate glass waste since 1996. A unique 'feed forward' statistical process control (SPC) has been used rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. In SQC, the glass product is sampled after it is vitrified. Individual glass property models form the basis for the 'feed forward' SPC. The property models transform constraints on the melt and glass properties into constraints on the feed composition. The property models are mechanistic and depend on glass bonding/structure, thermodynamics, quasicrystalline melt species, and/or electron transfers. The mechanistic models have been validated over composition regions well outside of the regions for which they were developed because they are mechanistic. Mechanistic models allow accurate extension to radioactive and hazardous waste melts well outside the composition boundaries for which they were developed.

  13. Burning hazardous waste in cement kilns

    SciTech Connect (OSTI)

    Chadbourne, J.F.; Helmsteller, A.J.

    1983-06-01T23:59:59.000Z

    The cement manufacturing process is one of the oldest in the world, having been in practice for over 2000 years. It is also one of the most energy intensive, with up to 65 percent of the cost of the product attributable to energy consumption. In addition to high energy demand, the process conditions include extremely high temperatures. Cement clinker forms when the correct mixture of raw materials is heated to 2650/sup 0/ F. This requires combustion temperatures exceeding 3000/sup 0/ F. under oxidizing conditions. To accomplish this, gas temperatures above 2000/sup 0/ F. occur for several seconds (typically five seconds), which is much longer than residence times in permitted hazardous waste incinerators. These conditions are extremely favorable to the destruction of organic compounds and have led to extensive investigation into the potential for burning hazardous waste in cement kilns. Cement kilns consuming hazardous wastes have been tested for air emissions under various operating conditions. The substantial body of information on the emissions and handling of hazardous wastes from these studies has demonstrated that effective destruction of wastes can be accomplished with the added benefits of energy conservation and no significant change in air emissions.

  14. Photon Interaction Studies with Some Glasses and Building Materials

    SciTech Connect (OSTI)

    Singh, Harvinder [Guru Nanak Dev University (India); Singh, Kulwant [Guru Nanak Dev University (India); Sharma, Gopi [Guru Nanak Dev University (India); Nathuram, R. [Bhabha Atomic Research Centre (India); Sahota, H.S. [Punjabi University (India)

    2002-11-15T23:59:59.000Z

    Mass attenuation coefficients of some shielding materials, namely, Bakelite, black cement, white cement, plaster of paris, and concrete were determined at 356-, 511-, 662-, 1173-, and 1332-keV energies, and those of glasses containing oxides of B, Cd, Pb, and Bi were determined only at 662 keV using a narrow beam transmission method. These coefficients of glasses were then used to determine their interaction cross sections, effective atomic numbers, and electron densities. Good agreement was observed between the experimental and theoretical values. It has been proven that glasses have a potential application as a transparent radiation shielding.

  15. History and some potentials of oil shale cement

    SciTech Connect (OSTI)

    Knutson, C.F.; Smith, R.P.; Russell, B.F. (Idaho National Engineering Lab., Idaho Falls, ID (USA))

    1989-01-01T23:59:59.000Z

    The utilization of oil shale as a cement component is discussed. It was investigated in America and Europe during World War I. Additional development occurred in Western Europe, Russia, and China during the 1920s and 1930s. World War II provided further development incentives and a relatively mature technology was in place in Germany, Russia, and China prior to 1980. The utilization of oil shale in cement has taken a number of different paths. One approach has been to utilize the energy in the oil shale as the principal source for the cement plant and to use the combusted shale as a minor constituent of the plant's cement product. A second approach has been to use the combusted shale as a class C or cementitious fly-ash component in portland cement concrete. Other approaches utilizing eastern oil shale have been to use the combusted oil shale with additives as a specialty cement, or to cocombust the oil shale with coal and utilize the sulfur-rich combustion product.

  16. SUPERGLASS. Engineering field tests - Phase 3. Production, market planning, and product evaluation for a high-thermal-performance insulating glass design utilizing HEAT MIRROR transparent insulation. Final report

    SciTech Connect (OSTI)

    Tilford, C L

    1982-11-01T23:59:59.000Z

    HEAT MIRROR transparent window insulation consists of a clear polyester film two mils (.002'') thick with a thin, clear low-emissivity (.15) coating deposited on one side by state-of-the-art vacuum deposition processes. This neutral-colored invisible coating reflects long-wave infrared energy (heat). When mounted by being stretched with a 1/2'' air-gap on each side of the film, the resulting unit reduces heat loss by 60% compared to dual insulating glass. Southwall Corporation produces HEAT MIRROR transparent insulation and markets it to manufacturers of sealed insulating glass (I.G.) units and window and building manufacturers who make their own I.G. These companies build and sell the SUPERGLASS sealed glazing units. Units made and installed in buildings by six customers were visited. These units were located in many geographic regions, including the Pacific Northwest, Rocky Mountains, New England, Southeast, and West Coast. As much as could be obtained of their history was recorded, as was their current condition and performance. These units had been in place from two weeks to over a year. All of the units were performing thermally very well, as measured by taking temperature profiles through them and through adjacent conventional I.G. units. Some units had minor visual defects (attributed to I.G. assembly techniques) which are discussed in detail. Overall occupant acceptance was enthusiastically positive. In addition to saving energy, without compromise of optical quality or appearance, the product makes rooms with large glazing areas comfortable to be in in cold weather. All defects observed were present when built; there appears to be no in-field degradation of quality at this time.

  17. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    SciTech Connect (OSTI)

    Price, Lynn; Hasanbeigi, Ali; Lu, Hongyou; Wang, Lan

    2009-10-01T23:59:59.000Z

    China's cement industry, which produced 1,388 million metric tons (Mt) of cement in 2008, accounts for almost half of the world's total cement production. Nearly 40% of China's cement production is from relatively obsolete vertical shaft kiln (VSK) cement plants, with the remainder from more modern rotary kiln cement plants, including plants equipped with new suspension pre-heater and pre-calciner (NSP) kilns. Shandong Province is the largest cement-producing Province in China, producing 10% of China's total cement output in 2008. This report documents an analysis of the potential to improve the energy efficiency of NSP kiln cement plants in Shandong Province. Sixteen NSP kiln cement plants were surveyed regarding their cement production, energy consumption, and current adoption of 34 energy-efficient technologies and measures. Plant energy use was compared to both domestic (Chinese) and international best practice using the Benchmarking and Energy Saving Tool for Cement (BEST-Cement). This benchmarking exercise indicated an average technical potential primary energy savings of 12% would be possible if the surveyed plants operated at domestic best practice levels in terms of energy use per ton of cement produced. Average technical potential primary energy savings of 23% would be realized if the plants operated at international best practice levels. Energy conservation supply curves for both fuel and electricity savings were then constructed for the 16 surveyed plants. Using the bottom-up electricity conservation supply curve model, the cost-effective electricity efficiency potential for the studied cement plants in 2008 is estimated to be 373 gigawatt hours (GWh), which accounts for 16% of total electricity use in the 16 surveyed cement plants in 2008. Total technical electricity-saving potential is 915 GWh, which accounts for 40% of total electricity use in the studied plants in 2008. The fuel conservation supply curve model shows the total technical fuel efficiency potential equal to 7,949 terajoules (TJ), accounting for 8% of total fuel used in the studied cement plants in 2008. All the fuel efficiency potential is shown to be cost effective. Carbon dioxide (CO{sub 2}) emission reduction potential associated with cost-effective electricity saving is 383 kiloton (kt) CO{sub 2}, while total technical potential for CO{sub 2} emission reduction from electricity-saving is 940 ktCO{sub 2}. The CO{sub 2} emission reduction potentials associated with fuel-saving potentials is 950 ktCO{sub 2}.

  18. Opportunities for Energy Efficiency and Demand Response in the California Cement Industry

    SciTech Connect (OSTI)

    Olsen, Daniel; Goli, Sasank; Faulkner, David; McKane, Aimee

    2010-12-22T23:59:59.000Z

    This study examines the characteristics of cement plants and their ability to shed or shift load to participate in demand response (DR). Relevant factors investigated include the various equipment and processes used to make cement, the operational limitations cement plants are subject to, and the quantities and sources of energy used in the cement-making process. Opportunities for energy efficiency improvements are also reviewed. The results suggest that cement plants are good candidates for DR participation. The cement industry consumes over 400 trillion Btu of energy annually in the United States, and consumes over 150 MW of electricity in California alone. The chemical reactions required to make cement occur only in the cement kiln, and intermediate products are routinely stored between processing stages without negative effects. Cement plants also operate continuously for months at a time between shutdowns, allowing flexibility in operational scheduling. In addition, several examples of cement plants altering their electricity consumption based on utility incentives are discussed. Further study is needed to determine the practical potential for automated demand response (Auto-DR) and to investigate the magnitude and shape of achievable sheds and shifts.

  19. Conceptual waste package interim product specifications and data requirements for disposal of borosilicate glass defense high-level waste forms in salt geologic repositories

    SciTech Connect (OSTI)

    Not Available

    1983-06-01T23:59:59.000Z

    The conceptual waste package interim product specifications and data requirements presented are applicable specifically to the normal borosilicate glass product of the Defense Waste Processing Facility (DWPF). They provide preliminary numerical values for the defense high-level waste form parameters and properties identified in the waste form performance specification for geologic isolation in salt repositories. Subject areas treated include containment and isolation, operational period safety, criticality control, waste form/production canister identification, and waste package performance testing requirements. This document was generated for use in the development of conceptual waste package designs in salt. It will be revised as additional data, analyses, and regulatory requirements become available.

  20. Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry

    SciTech Connect (OSTI)

    Galitsky, Christina; Price, Lynn; Zhou, Nan; Fuqiu , Zhou; Huawen, Xiong; Xuemin, Zeng; Lan, Wang

    2008-07-30T23:59:59.000Z

    The Benchmarking and Energy Savings Tool (BEST) Cement is a process-based tool based on commercially available efficiency technologies used anywhere in the world applicable to the cement industry. This version has been designed for use in China. No actual cement facility with every single efficiency measure included in the benchmark will likely exist; however, the benchmark sets a reasonable standard by which to compare for plants striving to be the best. The energy consumption of the benchmark facility differs due to differences in processing at a given cement facility. The tool accounts for most of these variables and allows the user to adapt the model to operational variables specific for his/her cement facility. Figure 1 shows the boundaries included in a plant modeled by BEST Cement. In order to model the benchmark, i.e., the most energy efficient cement facility, so that it represents a facility similar to the user's cement facility, the user is first required to input production variables in the input sheet (see Section 6 for more information on how to input variables). These variables allow the tool to estimate a benchmark facility that is similar to the user's cement plant, giving a better picture of the potential for that particular facility, rather than benchmarking against a generic one. The input variables required include the following: (1) the amount of raw materials used in tonnes per year (limestone, gypsum, clay minerals, iron ore, blast furnace slag, fly ash, slag from other industries, natural pozzolans, limestone powder (used post-clinker stage), municipal wastes and others); the amount of raw materials that are preblended (prehomogenized and proportioned) and crushed (in tonnes per year); (2) the amount of additives that are dried and ground (in tonnes per year); (3) the production of clinker (in tonnes per year) from each kiln by kiln type; (4) the amount of raw materials, coal and clinker that is ground by mill type (in tonnes per year); (5) the amount of production of cement by type and grade (in tonnes per year); (6) the electricity generated onsite; and, (7) the energy used by fuel type; and, the amount (in RMB per year) spent on energy. The tool offers the user the opportunity to do a quick assessment or a more detailed assessment--this choice will determine the level of detail of the energy input. The detailed assessment will require energy data for each stage of production while the quick assessment will require only total energy used at the entire facility (see Section 6 for more details on quick versus detailed assessments). The benchmarking tool provides two benchmarks--one for Chinese best practices and one for international best practices. Section 2 describes the differences between these two and how each benchmark was calculated. The tool also asks for a target input by the user for the user to set goals for the facility.

  1. Cement Kiln Flue Gas Recovery Scrubber Project

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-11-30T23:59:59.000Z

    The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

  2. Corrosion of aluminium metal in OPC- and CAC-based cement matrices

    SciTech Connect (OSTI)

    Kinoshita, Hajime, E-mail: h.kinoshita@sheffield.ac.uk [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom)] [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom); Swift, Paul; Utton, Claire [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom)] [Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield, S1 3JD (United Kingdom); Carro-Mateo, Beatriz [The Public University of Navarra, C/Esquíroz, 30 trasera, Pamplona 31007 (Spain)] [The Public University of Navarra, C/Esquíroz, 30 trasera, Pamplona 31007 (Spain); Marchand, Geraldine [The National Institute of Applied Sciences (INSA) Lyon, 20 Avenue Albert Einstein 69621 Villeurbanne Cedex (France)] [The National Institute of Applied Sciences (INSA) Lyon, 20 Avenue Albert Einstein 69621 Villeurbanne Cedex (France); Collier, Nick [National Nuclear Laboratory, Chadwick House, Birchwood Park, Warrington, WA3 6AE (United Kingdom)] [National Nuclear Laboratory, Chadwick House, Birchwood Park, Warrington, WA3 6AE (United Kingdom); Milestone, Neil [Industrial Research Ltd., 69 Gracefield Road, Lower Hutt, 5040 (New Zealand)] [Industrial Research Ltd., 69 Gracefield Road, Lower Hutt, 5040 (New Zealand)

    2013-08-15T23:59:59.000Z

    Corrosion of aluminium metal in ordinary Portland cement (OPC) based pastes produces hydrogen gas and expansive reaction products causing problems for the encapsulation of aluminium containing nuclear wastes. Although corrosion of aluminium in cements has been long known, the extent of aluminium corrosion in the cement matrices and effects of such reaction on the cement phases are not well established. The present study investigates the corrosion reaction of aluminium in OPC, OPC-blast furnace slag (BFS) and calcium aluminate cement (CAC) based systems. The total amount of aluminium able to corrode in an OPC and 4:1 BFS:OPC system was determined, and the correlation between the amount of calcium hydroxide in the system and the reaction of aluminium obtained. It was also shown that a CAC-based system could offer a potential matrix to incorporate aluminium metal with a further reduction of pH by introduction of phosphate, producing a calcium phosphate cement.

  3. Potential for energy conservation in the cement industry

    SciTech Connect (OSTI)

    Garrett-Price, B.A.

    1985-02-01T23:59:59.000Z

    This report assesses the potential for energy conservation in the cement industry. Energy consumption per ton of cement decreased 20% between 1972 and 1982. During this same period, the cement industry became heavily dependent on coal and coke as its primary fuel source. Although the energy consumed per ton of cement has declined markedly in the past ten years, the industry still uses more than three and a half times the fuel that is theoretically required to produce a ton of clinker. Improving kiln thermal efficiency offers the greatest opportunity for saving fuel. Improving the efficiency of finish grinding offers the greatest potential for reducing electricity use. Technologies are currently available to the cement industry to reduce its average fuel consumption per ton by product by as much as 40% and its electricity consumption per ton by about 10%. The major impediment to adopting these technologies is the cement industry's lack of capital as a result of low or no profits in recent years.

  4. Portland cement for SO/sub 2/ control in coal-fired power plants

    DOE Patents [OSTI]

    Steinberg, M.

    1984-10-17T23:59:59.000Z

    A method is described for removing oxides of sulfur from the emissions of fossil fuel combustion by injecting portland cement into the boiler with the fuel, the combustion air, or downstream with the combustion gases. The cement products that result from this method is also described. 1 tab.

  5. Portland cement for SO.sub.2 control in coal-fired power plants

    DOE Patents [OSTI]

    Steinberg, Meyer (Melville, NY)

    1985-01-01T23:59:59.000Z

    There is described a method of removing oxides of sulfur from the emissions of fossil fuel combustion by injecting portland cement into the boiler with the fuel, the combustion air, or downstream with the combustion gases. There is also described the cement products that result from this method.

  6. Product consistency test of fully radioactive high-sodium content borosilicate glass K-26 N.V. Ojovan1

    E-Print Network [OSTI]

    Sheffield, University of

    of radioactive waste in a glass matrix. The program was initiated in the mid-70s. Since then pilot and industrial of this glass were produced in the 1980s during a pilot vitrification campaign of radioactive waste fromO - 16.1Na2O - 1.7Fe2O3 - 1.2NaCl - 1.1Na2SO4 - 6.2Misc. The main radioactive contaminant of waste

  7. Review of PennDOT Publication 408 for the use of recycled co-product materials: Summary recommendations. Final report

    SciTech Connect (OSTI)

    Van Tassel, E.L.; Tikalsky, P.J.; Christensen, D.W.

    1999-04-30T23:59:59.000Z

    The purpose of this project is to decrease the institutional or perceived institutional barriers for the use of recycled and co-product materials including glass, steel slag, foundry sand, fly ash, shingle tabs, reclaimed Portland cement concrete, and scrap tires in the Pennsylvania Department of Transportation`s (PennDOT) Publications 408, Commonwealth of Pennsylvania Department of Transportation Specifications. This report reviews potential uses of each material, identifies the project that used these materials, and provides direction for future specification development.

  8. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01T23:59:59.000Z

    and a vertical shaft kiln at another cement manufacturingrotary kiln or vertical shaft kiln in a cement plant. Baseda vertical shaft kiln (VSK) at another cement manufacturing

  9. Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry

    E-Print Network [OSTI]

    Galitsky, Christina

    2009-01-01T23:59:59.000Z

    the small cement plants, earthen vertical kiln (and hollowcement plant in North China utilizing vertical shaft kilnsCement Industry Technical Conference: 75- Replacing Vertical Shaft Kilns

  10. Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics

    E-Print Network [OSTI]

    Meyer, Christian

    Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics Gregor Vilkner Submitted Glass Concrete Thin Sheets Reinforced with Prestressed Aramid Fabrics Gregor Vilkner Thin sheet concrete presented in this work explored the possibilities of prestressing thin sheet glass concrete products

  11. Assessment of gas-side fouling in cement plants

    SciTech Connect (OSTI)

    Marner, W.J.

    1982-09-01T23:59:59.000Z

    The purpose of this study is to provide an assessment of gas-side fouling in cement plants with special emphasis on heat recovery applications. Exhaust gases in the cement industry which are suitable for heat recovery range in temperature from about 400 to 1300 K, are generally dusty, may be highly abrasive, and are often heavily laden with alkalies, sulfates, and chlorides. Particulates in the exhaust streams range in size from molecular to about 100 ..mu..m in diameter and come from both the raw feed as well as the ash in the coal which is the primary fuel used in the cement industry. The major types of heat-transfer equipment used in the cement industry include preheaters, gas-to-air heat exchangers, waste heat boilers, and clinker coolers. The most important gas-side fouling mechanisms in the cement industry are those due to particulate, chemical reaction, and corrosion fouling. Particulate transport mechanisms which appear to be of greatest importance include laminar and turbulent mass transfer, thermophoresis, electrophoresis, and inertial impaction. Chemical reaction mechanisms of particular importance include the deposition of alkali sulfates, alkali chlorides, spurrite, calcium carbonate, and calcium sulfate. At sufficiently low temperatures, sulfuric acid and water can condense on heat exchanger surfaces which can cause corrosion and also attract particulates in the flow. The deleterious effects of gas-side fouling in cement plants are due to: (1) increased capital costs; (2) increased maintenance costs; (3) loss of production; and (4) energy losses. A conservative order-of-magnitude analysis shows that the cost of gas-side fouling in US cement plants is $0.24 billion annually.

  12. Study of composite cement containing burned oil shale

    E-Print Network [OSTI]

    Dalang, Robert C.

    Study of composite cement containing burned oil shale Julien Ston Supervisors : Prof. Karen properties. SCMs can be by-products from various industries or of natural origin, such as shale. Oil shale correctly, give a material with some cementitious properties known as burned oil shale (BOS). This study

  13. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford site low-level waste

    SciTech Connect (OSTI)

    Shade, J.W.

    1996-05-03T23:59:59.000Z

    Commercially available melter technologies were tested for application to vitrification of Hanford site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW simulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  14. E-Print Network 3.0 - ash cements stabilized Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science 6 By-Products Utilization Summary: OF WISCONSIN - MILWAUKEE 12;2 Use of Clean Coal Ash as Setting Time Regulator in Portland Cement by Zichao Wu... as setting time...

  15. Cement advanced furnace and process

    SciTech Connect (OSTI)

    Litka, A.F.; Cohen, S.M.

    1992-06-02T23:59:59.000Z

    This patent describes a suspension shaft furnace for producing discrete cement clinkers from discrete pellets of cement-forming batch materials which are gravity-migrated therethrough. It comprises a vertical furnace housing enclosing a top pellet-feeding and preheating zone comprising an elongate vertical shaft section opening into an intermediate fluidized bed section comprising fuel inlet conduits, an air-permeable clinker-impermeable support; a lower clinker-cooling section beneath the fluidized bed section; clinker-discharge means communicating between the fluidized bed section and the cooling section and air inlet means.

  16. ADVANCED CEMENTS FOR GEOTHERMAL WELLS

    SciTech Connect (OSTI)

    SUGAMA,T.

    2007-01-01T23:59:59.000Z

    Using the conventional well cements consisting of the calcium silicate hydrates (CaO-SiO{sub 2}-H{sub 2}O system) and calcium aluminum silicate hydrates (CaO-Al{sub 2}O{sub 3}-SiO{sub 2}-H{sub 2}O system) for the integrity of geothermal wells, the serious concern confronting the cementing industries was their poor performance in mechanically supporting the metallic well casing pipes and in mitigating the pipe's corrosion in very harsh geothermal reservoirs. These difficulties are particularly acute in two geological regions: One is the deep hot downhole area ({approx} 1700 m depth at temperatures of {approx} 320 C) that contains hyper saline water with high concentrations of CO{sub 2} (> 40,000 ppm) in conjunction with {approx} 100 ppm H{sub 2}S at a mild acid of pH {approx} 5.0; the other is the upper well region between the well's surface and {approx} 1000 m depth at temperatures up to 200 C. The specific environment of the latter region is characterized by highly concentrated H{sub 2}SO{sub 4} (pH < 1.5) brine containing at least 5000 ppm CO{sub 2}. When these conventional cements are emplaced in these harsh environments, their major shortcoming is their susceptibility to reactions with hot CO{sub 2} and H{sub 2}SO4, thereby causing their deterioration brought about by CO{sub 2}-catalyzed carbonation and acid-initiated erosion. Such degradation not only reduced rapidly the strength of cements, lowering the mechanical support of casing pipes, but also increased the extent of permeability of the brine through the cement layer, promoting the rate of the pipe's corrosion. Severely carbonated and acid eroded cements often impaired the integrity of a well in less than one year; in the worst cases, casings have collapsed within three months, leading to the need for costly and time-consuming repairs or redrilling operations. These were the reasons why the geothermal well drilling and cementing industries were concerned about using conventional well cements, and further their deterioration was a major impediment in expediting the development of geothermal energy resources.

  17. Cement design key to subsalt success

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    Failures in casing set across salt formations have cost the petroleum industry billions of dollars. One of the most effective weapons for halting casing damage in salt formations is a competent cement sheath across the whole salt zone formation. Good cement jobs are at least as important as casing design. Choice of cementing recipe and practice can ensure a lasting cementation and is a function of the formation, its inclusions and its boundaries. The paper discusses the gauge hole, salt creep, and well casing and cementing.

  18. High temperature synthetic cement retarder

    SciTech Connect (OSTI)

    Eoff, L.S.; Buster, D.

    1995-11-01T23:59:59.000Z

    A synthetic cement retarder which provides excellent retardation and compressive strength development has been synthesized. The response properties and temperature ranges of the synthetic retarder far exceed those of commonly used retarders such as lignosulfonates. The chemical nature of the new retarder is discussed and compared to another synthetic retarder.

  19. Process for cementing geothermal wells

    DOE Patents [OSTI]

    Eilers, Louis H. (Inola, OK)

    1985-01-01T23:59:59.000Z

    A pumpable slurry of coal-filled furfuryl alcohol, furfural, and/or a low molecular weight mono- or copolymer thereof containing, preferably, a catalytic amount of a soluble acid catalyst is used to cement a casing in a geothermal well.

  20. Hydration and leaching characteristics of cement pastes made from electroplating sludge

    SciTech Connect (OSTI)

    Chen, Ying-Liang [Department of Environmental Engineering, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China); Sustainable Environment Research Center, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China); Ko, Ming-Sheng [Institute of Mineral Resources Engineering, National Taipei University of Technology, No. 1, Sec. 3, Chunghsiao E. Rd., Taipei City 10608, Taiwan (China); Lai, Yi-Chieh [Department of Bioenvironmental Engineering, Chung Yuan Christian University, No. 200, Chung-Pei Rd., Chung-Li 32023, Taiwan (China); Chang, Juu-En, E-mail: juuen@mail.ncku.edu.tw [Department of Environmental Engineering, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China); Sustainable Environment Research Center, National Cheng Kung University, No. 1, University Rd., Tainan City 70101, Taiwan (China)

    2011-06-15T23:59:59.000Z

    The purpose of this study was to investigate the hydration and leaching characteristics of the pastes of belite-rich cements made from electroplating sludge. The compressive strength of the pastes cured for 1, 3, 7, 28, and 90 days was determined, and the condensation of silicate anions in hydrates was examined with the {sup 29}Si nuclear magnetic resonance (NMR) technology. The leachabilities of the electroplating sludge and the hardened pastes were studied with the multiple toxicity characteristic leaching procedure (MTCLP) and the tank leaching test (NEN 7345), respectively. The results showed that the electroplating sludge continued to leach heavy metals, including nickel, copper, and zinc, and posed a serious threat to the environment. The belite-rich cement made from the electroplating sludge was abundant in hydraulic {beta}-dicalcium silicate, and it performed well with regard to compressive-strength development when properly blended with ordinary Portland cements. The blended cement containing up to 40% the belite-rich cement can still satisfy the compressive-strength requirements of ASTM standards, and the pastes cured for 90 days had comparable compressive strength to an ordinary Portland cement paste. It was also found that the later hydration reaction of the blended cements was relatively more active, and high fractions of belite-rich cement increased the chain length of silicate hydrates. In addition, by converting the sludge into belite-rich cements, the heavy metals became stable in the hardened cement pastes. This study thus indicates a viable alternative approach to dealing with heavy metal bearing wastes, and the resulting products show good compressive strength and heavy-metal stability.

  1. Analytical electron microscopy examination of solid reaction products in long-term test of SRL 200 waste glasses

    SciTech Connect (OSTI)

    Buck, E.C.; Fortner, J.A.; Bates, J.K.; Feng, X.; Dietz, N.L.; Bradley, C.R.; Tani, B.S.

    1993-12-31T23:59:59.000Z

    Alteration phases, found on the leached surfaces and present as colloids in the leachates of 200-based frit (fully active and simulated) nuclear waste glass, reacted under static test conditions, at a surface area to leachate volume ratio of 20,000 m{sup {minus}1} for 15 days to 728 days, have been examined by analytical electron microscopy. The compositions of the secondary phases were determined using x-ray energy dispersive spectroscopy and electron energy loss spectroscopy, and structural analysis was accomplished by electron diffraction. Long-term samples of simulated glass, which had undergone an acceleration of reaction after 182 days, possessed a number of silicate secondary phases, including; smectite (iron silicate and potassium iron alumina-silicate, weeksite (uranium silicate), zeolite (calcium potassium alumino-silicate), tobermorite (calcium silicate), and a pure silica phase. However, uranium silicates and smectite have also been observed in tests, which have not undergone the acceleration of reaction, in both the leachate and leached layer, suggesting that these phases are not responsible for the acceleration of reaction.

  2. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization USE OF CLEAN COAL ASH AS SETTING TIME REGULATOR IN PORTLAND OF WISCONSIN ­ MILWAUKEE #12;2 Use of Clean Coal Ash as Setting Time Regulator in Portland Cement by Zichao Wu as setting time regulator for portland cement production. In this paper a source of clean coal ash (CCA

  3. Effect of Sodium Carboxymethyl Celluloses on Water-catalyzed Self-degradation of 200-degree C-heated Alkali-Activated Cement

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.

    2012-05-01T23:59:59.000Z

    We investigated the usefulness of sodium carboxymethyl celluloses (CMC) in promoting self-degradation of 200°C-heated sodium silicate-activated slag/Class C fly ash cementitious material after contact with water. CMC emitted two major volatile compounds, CO2 and acetic acid, creating a porous structure in cement. CMC also reacted with NaOH from sodium silicate to form three water-insensitive solid reaction products, disodium glycolate salt, sodium glucosidic salt, and sodium bicarbonate. Other water-sensitive solid reaction products, such as sodium polysilicate and sodium carbonate, were derived from hydrolysates of sodium silicate. Dissolution of these products upon contact with water generated heat that promoted cement’s self-degradation. Thus, CMC of high molecular weight rendered two important features to the water-catalyzed self-degradation of heated cement: One was the high heat energy generated in exothermic reactions in cement; the other was the introduction of extensive porosity into cement.

  4. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    SciTech Connect (OSTI)

    Mehta, P.K.; Persoff, P.; Fox, J.P.

    1980-06-01T23:59:59.000Z

    Low cost material is needed for grouting abandoned retorts. Experimental work has shown that a hydraulic cement can be produced from Lurgi spent shale by mixing it in a 1:1 weight ratio with limestone and heating one hour at 1000°C. With 5% added gypsum, strengths up to 25.8 MPa are obtained. This cement could make an economical addition up to about 10% to spent shale grout mixes, or be used in ordinary cement applications.

  5. INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2012-01-01T23:59:59.000Z

    CEMENTS FROM SPENT OIL SHALE P.K. Mehta and P. Persoff AprilCement Manufacture from Oil Shale, U.S. Patent 2,904,445,CEMENTS FROM SPENT OIL SHALE P, K, Mehta Civil Engineering

  6. Relationship Between Engineering Properties, Mineralogy, and Microstructure in Cement-Based Hydroceramic Materials Cured at

    E-Print Network [OSTI]

    Bentz, Dale P.

    . I. Introduction CEMENT is universally used in the construction of oil and geothermal wells. Cement

  7. asbestos cement workers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    early stage hydration of different classes of oilwell cement Bentz, Dale P. 152 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

  8. ash cement concrete: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    early stage hydration of different classes of oilwell cement Bentz, Dale P. 410 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

  9. ash substituted cements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    early stage hydration of different classes of oilwell cement Bentz, Dale P. 199 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

  10. asbestos cement dust: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    early stage hydration of different classes of oilwell cement Bentz, Dale P. 278 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

  11. african portland cement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    present in hardened cement blends in the long term Sheffield, University of 337 NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration Engineering Websites Summary: NISTIR...

  12. Multifunctional Corrosion-resistant Foamed Well Cement Composites...

    Broader source: Energy.gov (indexed) [DOE]

    Multifunctional Corrosion-resistant Foamed Well Cement Composites Multifunctional Corrosion-resistant Foamed Well Cement Composites Multifunctional Corrosion-resistant Foamed Well...

  13. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    flash distillation waste heat power generation demonstrationAdvanced Concepts of Waste Heat Recovery in Cement PlantsCement Ltd. also installed waste heat recovery equipment on

  14. POROUS WALL, HOLLOW GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Sexton, W.

    2012-06-30T23:59:59.000Z

    Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of magnitude, which can result in unique properties in areas such as hydrogen storage, gas transport, gas separations and purifications, sensors, global warming applications, new drug delivery systems and so on. One of the most interesting porous glass products that SRNL has developed and patented is Porous Wall, Hollow Glass Microspheres (PW-HGMs) that are being studied for many different applications. The European Patent Office (EPO) just recently notified SRS that the continuation-in-part patent application for the PW-HGMs has been accepted. The original patent, which was granted by the EPO on June 2, 2010, was validated in France, Germany and the United Kingdom. The microspheres produced are generally in the range of 2 to 100 microns, with a 1 to 2 micron wall. What makes the SRNL microspheres unique from all others is that the team in Figure 1 has found a way to induce and control porosity through the thin walls on a scale of 100 to 3000 {angstrom}. This is what makes the SRNL HW-HGMs one-of-a-kind, and is responsible for many of their unique properties and potential for various applications, including those in tritium storage, gas separations, H-storage for vehicles, and even a variety of new medical applications in the areas of drug delivery and MRI contrast agents. SRNL Hollow Glass Microspheres, and subsequent, Porous Wall, Hollow Glass Microspheres are fabricated using a flame former apparatus. Figure 2 is a schematic of the apparatus.

  15. Current status of the GLASS code

    SciTech Connect (OSTI)

    Hootman, H.E. (Westinghouse Savannah River Co., Aiken, SC (United States)); Honeck, H.C. (Computer Application Technology, Inc., Aiken, SC (United States))

    1991-01-01T23:59:59.000Z

    This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970's. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

  16. Current status of the GLASS code

    SciTech Connect (OSTI)

    Hootman, H.E. [Westinghouse Savannah River Co., Aiken, SC (United States); Honeck, H.C. [Computer Application Technology, Inc., Aiken, SC (United States)

    1991-12-31T23:59:59.000Z

    This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970`s. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

  17. Fracture model for cemented aggregates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zubelewicz, Aleksander; Thompson, Darla G.; Ostoja-Starzewski, Martin; Ionita, Axinte; Shunk, Devin; Lewis, Matthew W.; Lawson, Joe C.; Kale, Sohan; Koric, Seid

    2013-01-01T23:59:59.000Z

    A mechanisms-based fracture model applicable to a broad class of cemented aggregates and, among them, plastic-bonded explosive (PBX) composites, is presented. The model is calibrated for PBX 9502 using the available experimental data under uniaxial compression and tension gathered at various strain rates and temperatures. We show that the model correctly captures inelastic stress-strain responses prior to the load peak and it predicts the post-critical macro-fracture processes, which result from the growth and coalescence of micro-cracks. In our approach, the fracture zone is embedded into elastic matrix and effectively weakens the material's strength along the plane of the dominant fracture.

  18. Combustion Technology Development for an Advanced Glass Melting System

    E-Print Network [OSTI]

    Stickler, D. B.; Westra, L.; Woodroffe, J.; Jeong, K. M.; Donaldson, L. W.

    Concept feasibility of an innovative technology for glass production has recently been demonstrated. It is based on suspension heating of the glass-forming batch minerals while entrained in a combustion flow of preheated air and natural gas...

  19. Corrosion of Partially Crystallized Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Riley, Brian J.; Vienna, John D.

    2002-05-21T23:59:59.000Z

    Using existing data on corrosion of partially crystallized, simulated, high-level waste glasses, coefficients were introduced to evaluate the cumulative influence of secondary effects, such as residual stresses or concentration gradients on product consistency test response. As compared to predictions based solely on residual glass composition effects, the results showed that cristobalite, eucryptite, and nepheline had a higher-than-predicted impact on glass corrosion, while the effects of baddeleyite, hematite, calcium-zirconium silicate, and zircon were close to those predicted. The effects of acmite and lithium silicate were opposite to those expected based on their compositions. The analysis revealed important limitations of the databases currently available. Better understanding of corrosion phenomena will require quantitative composition data, microscopic characterization of pristine and corroded surfaces, and long-term tests with glass coupons or monoliths.

  20. Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. cement industry

    SciTech Connect (OSTI)

    Martin, Nathan; Worrell, Ernst; Price, Lynn

    1999-08-01T23:59:59.000Z

    This paper reports on an in-depth analysis of the U.S. cement industry, identifying cost-effective energy efficiency measures and potentials. The authors assess this industry at the aggregate level (Standard Industrial Classification 324), which includes establishments engaged in manufacturing hydraulic cements, including Portland, natural, masonry, and pozzolana when reviewing industry trends and when making international comparisons. Coal and coke are currently the primary fuels for the sector, supplanting the dominance of natural gas in the 1970s. Between 1970 and 1997, primary physical energy intensity for cement production (SIC 324) dropped 30%,from 7.9 GJ/t to 5.6 GJ/t, while carbon dioxide intensity due to fuel consumption (carbon dioxide emissions expressed in tons of carbon per ton cement) dropped 25%, from 0.16 tC/ton to 0.12 tC/ton. Carbon dioxide intensity due to fuel consumption and clinker calcination dropped 17%, from 0.29 tC/ton to 0.24 tC/ton. They examined 30 energy efficient technologies and measures and estimated energy savings, carbon dioxide savings, investment costs, and operation and maintenance costs for each of the measures. They constructed an energy conservation supply curve for U.S. cement industry which found a total cost-effective reduction of 0.6 GJ/ton of cement consisting of measures having a simple payback period of 3 years or less. This is equivalent to potential energy savings of 11% of 1994 energy use for cement making and a savings of 5% of total 1994 carbon dioxide emissions by the U.S. cement industry. Assuming the increased production of blended cement in the U.S., as is common in many parts of the world, the technical potential for energy efficiency improvement would not change considerably. However, the cost-effective potential, would increase to 1.1 GJ/ton cement or 18% of total energy use, and carbon dioxide emissions would be reduced by 16%.

  1. Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry

    E-Print Network [OSTI]

    Galitsky, Christina

    2009-01-01T23:59:59.000Z

    Advanced Concepts of Waste Heat Recovery in Cement Plantsquantities of low grade waste heat from the kilns or clinkerthere is significant effect of waste heat recovery on dioxin

  2. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    obsolete vertical shaft kiln (VSK) cement plants, with theobsolete vertical shaft kiln (VSK) cement plants, with theobsolete vertical shaft kiln (VSK) cement plants, with the

  3. Supply chain management in the cement industry

    E-Print Network [OSTI]

    Agudelo, Isabel

    2009-01-01T23:59:59.000Z

    Traditionally supply chain management has played an operational role within cement and mineral extraction commodity companies. Recently, cost reduction projects have brought supply chain management into the limelight. In ...

  4. A nanochemomechanical investigation of carbonated cement paste

    E-Print Network [OSTI]

    Vanzo, James (James F.)

    2009-01-01T23:59:59.000Z

    Concrete, and in particular its principal component, cement paste, has an interesting relation with carbon dioxide. Concrete is a carbon dioxide generator-- it is estimated that 5-10% of atmospheric CO? comes from this ...

  5. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2013-01-01T23:59:59.000Z

    cement from spent oil shale," Vol. 10, No. 4, p. 54S,Colorado's primary oil shale resource for vertical modifiedSimulated effects of oil-shale development on the hydrology

  6. HYDRAULIC CEMENT PREPARATION FROM LURGI SPENT SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2013-01-01T23:59:59.000Z

    hydraulic cement from spent oil shale," Vol. 10, No. 4, p.J. W. , "Colorado's primary oil shale resource for verticalSimulated effects of oil-shale development on the hydrology

  7. Wearability of Portland Cement Concrete Pavement Finishes

    E-Print Network [OSTI]

    McKeen, William Rew

    1971-01-01T23:59:59.000Z

    Major Subject: Civil Engineering NEARABILITY OF PORTLAND CENENT CONCRETE PAPFNENT FIVISNFS A Thesis by Nilliam Rem NcKeen Approved as to style and content by: (Chairman of Committ e) (Nember) August 1971 ABSTRACT Hearabil'tv of Portland Cement... portland cement, and an air entrainment admixture. Standard laboratory tests were performed on all aggregates to determine their properties. iv The test specimens were molded in a controlled environmental room and the anpropriate surface finish (burlap...

  8. SENSITIVITY OF THE BOND STRENGTH TO THE STRUCTURE OF THE INTERFACE BETWEEN REINFORCEMENT AND CEMENT, AND THE

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    Ashland Petroleum Co. (Ashland, KY). Cement paste made from Portland cement (Type I) from Lafarge Corp

  9. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M. (Aiken, SC); Pickett, John B. (Aiken, SC); Cicero-Herman, Connie A. (Aiken, SC); Marra, James C. (Aiken, SC)

    2000-01-01T23:59:59.000Z

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  10. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2004-11-02T23:59:59.000Z

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  11. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2003-10-07T23:59:59.000Z

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  12. Glass-silicon column

    DOE Patents [OSTI]

    Yu, Conrad M.

    2003-12-30T23:59:59.000Z

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  13. Metal and Glass Manufacturers Reduce Costs by Increasing Energy...

    Broader source: Energy.gov (indexed) [DOE]

    in Process Heating Systems Process heating plays a key role in producing steel, aluminum, and glass and in manufacturing products made from these materials. Faced with...

  14. Energy implications of glass-container recycling

    SciTech Connect (OSTI)

    Gaines, L.L.; Mintz, M.M. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

    1994-03-01T23:59:59.000Z

    This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

  15. Fe-containing phases in hydrated cements

    SciTech Connect (OSTI)

    Dilnesa, B.Z., E-mail: belay.dilnesa@gmail.com [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Wieland, E. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Lothenbach, B. [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Dähn, R. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Scrivener, K.L. [Ecole Polytechnique Federal de Lausanne (EPFL), Laboratory for Construction Materials, 1015 Lausanne (Switzerland)

    2014-04-01T23:59:59.000Z

    In this study synchrotron X-ray absorption spectroscopy (XAS) has been applied, an element specific technique which allows Fe-containing phases to be identified in the complex mineral mixture of hydrated cements. Several Fe species contributed to the overall Fe K-edge spectra recorded on the cement samples. In the early stage of cement hydration ferrite was the dominant Fe-containing mineral. Ferrihydrite was detected during the first hours of the hydration process. After 1 day the formation of Al- and Fe-siliceous hydrogarnet was observed, while the amount of ferrihydrite decreased. The latter finding agrees with thermodynamic modeling, which predicts the formation of Fe-siliceous hydrogarnet in Portland cement systems. The presence of Al- and Fe-containing siliceous hydrogarnet was further substantiated in the residue of hydrated cement by performing a selective dissolution procedure. - Highlights: • Fe bound to ferrihydrite at early age hydration • Fe found to be stable in siliceous hydrogarnet at longer term age hydration • Fe-containing AFt and AFm phases are less stable than siliceous hydrogarnet. • The study demonstrates EXAFS used to identify amorphous or poorly crystalline phases.

  16. INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2012-01-01T23:59:59.000Z

    20 to 40% of the oil shale, and explosively rubblizing andCEMENTS FROM SPENT OIL SHALE P.K. Mehta and P. Persoff AprilCement Manufacture from Oil Shale, U.S. Patent 2,904,445,

  17. Identification of Concrete Incompatibilities Using Cement Paste Rheology

    E-Print Network [OSTI]

    Jang, Se Hoon

    2010-07-14T23:59:59.000Z

    as well as heat evolution abnormalities. The objectives of the present study were to examine the applicability of the dynamic shear rheometer (DSR) to measure cement paste rheology, and to identify cement and mineral/chemical admixture incompatibilities...

  18. Development of an Improved Cement for Geothermal Wells

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Develop a novel, zeolite-containing lightweight, high temperature, high pressure geothermal cement, which will provide operators with an easy to use, flexible cementing system that saves time and simplifies logistics.

  19. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    and energy savings per tonne of cement produced are estimated and then carbon dioxide emissionsand energy savings per tonne of cement produced are estimated and then carbon dioxide emissions

  20. Master Thesis: Simulation of plastic deformation in cemented carbide inserts

    E-Print Network [OSTI]

    Haviland, David

    Master Thesis: Simulation of plastic deformation in cemented carbide inserts Background Sandvik in cemented carbide, high-speed steel and other hard materials such as diamond, cubic boron nitride in cemented carbide inserts will be performed using the FEM software Ansys and AdvantEdge. The work

  1. Successful Alternatives to Conventional Cement Designs in the Williston Basin

    SciTech Connect (OSTI)

    Bryant, G.A.

    1984-05-01T23:59:59.000Z

    Since mid-1981, 36 wells have been cemented in the Williston Basin with a cementing system diametrically opposed to conventional cementing designs used for bonding across massive salt members. Since implementation, along with the use of relaxed invert emulsion oil mud, not one casing problem has arisen in the wells where these systems were used.

  2. NIST Special Publication 1173 Virtual Cement and Concrete

    E-Print Network [OSTI]

    #12;NIST Special Publication 1173 Virtual Cement and Concrete Testing Laboratory Version 9.5 User;Virtual Cement and Concrete Testing Laboratory Version 9.5 User Guide Jeffrey W. Bullard1 Materials-8615 This document serves as the user's guide for the Virtual Cement and Con- crete Testing Laboratory (VCCTL

  3. A literature review of mixed waste components: Sensitivities and effects upon solidification/stabilization in cement-based matrices

    SciTech Connect (OSTI)

    Mattus, C.H.; Gilliam, T.M.

    1994-03-01T23:59:59.000Z

    The US DOE Oak Ridge Field Office has signed a Federal Facility Compliance Agreement (FFCA) regarding Oak Ridge Reservation (ORR) mixed wastes subject to the land disposal restriction (LDR) provisions of the Resource conservation and Recovery Act. The LDR FFCA establishes an aggressive schedule for conducting treatability studies and developing treatment methods for those ORR mixed (radioactive and hazardous) wastes listed in Appendix B to the Agreement. A development, demonstration, testing, and evaluation program has been initiated to provide those efforts necessary to identify treatment methods for all of the wastes that meet Appendix B criteria. The program has assembled project teams to address treatment development needs in a variety of areas, including that of final waste forms (i.e., stabilization/solidification processes). A literature research has been performed, with the objective of determining waste characterization needs to support cement-based waste-form development. The goal was to determine which waste species are problematic in terms of consistent production of an acceptable cement-based waste form and at what concentrations these species become intolerable. The report discusses the following: hydration mechanisms of Portland cement; mechanisms of retardation and acceleration of cement set-factors affecting the durability of waste forms; regulatory limits as they apply to mixed wastes; review of inorganic species that interfere with the development of cement-based waste forms; review of radioactive species that can be immobilized in cement-based waste forms; and review of organic species that may interfere with various waste-form properties.

  4. ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 ITP Glass: Glass Industry Technology Roadmap; April 2002 ITP Glass: A Clear Vision for a Bright Future...

  5. ITP Glass: Glass Industry of the Future: Energy and Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glass Industry of the Future: Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 ITP Glass: Glass Industry of the Future: Energy and Environmental Profile of...

  6. PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS

    SciTech Connect (OSTI)

    Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

    2011-01-04T23:59:59.000Z

    The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

  7. Use of waste gypsum to replace natural gypsum as set retarders in portland cement

    SciTech Connect (OSTI)

    Chandara, Chea; Azizli, Khairun Azizi Mohd [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia); Ahmad, Zainal Arifin [School of Materials and Mineral Resources Engineering, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang (Malaysia)], E-mail: zainal@eng.usm.my; Sakai, Etsuo [Tokyo Institute of Technology, Graduate School of Science and Engineering, Department of Metallurgy and Ceramic Science, 2-12-1 Meguro-ku, Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2009-05-15T23:59:59.000Z

    The present study is focused on clarifying the influence of waste gypsum (WG) in replacing natural gypsum (NG) in the production of ordinary Portland cement (OPC). WG taken from slip casting moulds in a ceramic factory was formed from the hydration of plaster of paris. Clinker and 3-5 wt% of WG was ground in a laboratory ball mill to produce cement waste gypsum (CMWG). The same procedure was repeated with NG to substitute WG to prepare cement natural gypsum (CMNG). The properties of NG and WG were investigated via X-ray Diffraction (XRD), X-ray fluorescence (XRF) and differential scanning calorimetry (DSC)/thermogravimetric (TG) to evaluate the properties of CMNG and CMWG. The mechanical properties of cement were tested in terms of setting time, flexural and compressive strength. The XRD result of NG revealed the presence of dihydrate while WG contained dihydrate and hemihydrate. The content of dihydrate and hemihydrates were obtained via DSC/TG, and the results showed that WG and NG contained 12.45% and 1.61% of hemihydrate, respectively. Furthermore, CMWG was found to set faster than CMNG, an average of 15.29% and 13.67% faster for the initial and final setting times, respectively. This was due to the presence of hemihydrate in WG. However, the values obtained for flexural and compressive strength were relatively the same for CMNG and CMWG. Therefore, this result provides evidence that WG can be used as an alternative material to NG in the production of OPC.

  8. Development of a performance-based industrial energy efficiency indicator for cement manufacturing plants.

    SciTech Connect (OSTI)

    Boyd, G.; Decision and Information Sciences

    2006-07-21T23:59:59.000Z

    Organizations that implement strategic energy management programs have the potential to achieve sustained energy savings if the programs are carried out properly. A key opportunity for achieving energy savings that plant managers can take is to determine an appropriate level of energy performance by comparing the plant performance with that of similar plants in the same industry. Manufacturing plants can set energy efficiency targets by using performance-based indicators. The U.S. Environmental Protection Agency (EPA), through its ENERGY STAR{reg_sign} program, has been developing plant energy performance indicators (EPIs) to encourage a variety of U.S. industries to use energy more efficiently. This report describes work with the cement manufacturing industry to provide a plant-level indicator of energy efficiency for assembly plants that produce a variety of products, including Portland cement and other specialty cement products, in the United States. Consideration is given to the role that performance-based indicators play in motivating change; the steps needed to develop indicators, including interacting with an industry to secure adequate data for an indicator; and the actual application and use of an indicator when complete. How indicators are employed in the EPA's efforts to encourage industries to voluntarily improve their use of energy is discussed as well. The report describes the data and statistical methods used to construct the EPI for cement manufacturing plants. Individual equations are presented, as are the instructions for using them in an associated Excel spreadsheet.

  9. INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE

    SciTech Connect (OSTI)

    Mehta, P.K.; Persoff, P.

    1980-04-01T23:59:59.000Z

    A process for making hydraulic cements from spent oil shale is described in this paper. Inexpensive cement is needed to grout abandoned in-situ retorts of spent shale for subsidence control, mitigation of leaching, and strengthening the retorted mass in order to recover oil from adjacent pillars of raw shale. A hydraulic cement was produced by heating a 1:1 mixture of Lurgi spent shale and CaCO{sub 3} at 1000 C for one hour. This cement would be less expensive than ordinary portland cement and is expected to fulfill the above requirements.

  10. How to run and cement liners

    SciTech Connect (OSTI)

    Bowman, G.R.; Sherer, B.

    1988-09-01T23:59:59.000Z

    Testing the top of a liner after it has been cemented is necessary to ensure a well's integrity. However, whether done with or without packers there are potential problems attendant with either method that can occur if the tests are not properly engineered. A discussion of these problems and ways to avoid them is presented.

  11. Corrosion-resistant Foamed Cements for Carbon Steels

    SciTech Connect (OSTI)

    Sugama T.; Gill, S.; Pyatina, T., Muraca, A.; Keese, R.; Khan, A.; Bour, D.

    2012-12-01T23:59:59.000Z

    The cementitious material consisting of Secar #80, Class F fly ash, and sodium silicate designed as an alternative thermal-shock resistant cement for the Enhanced Geothermal System (EGS) wells was treated with cocamidopropyl dimethylamine oxide-based compound as foaming agent (FA) to prepare numerous air bubble-dispersed low density cement slurries of and #61603;1.3 g/cm3. Then, the foamed slurry was modified with acrylic emulsion (AE) as corrosion inhibitor. We detailed the positive effects of the acrylic polymer (AP) in this emulsion on the five different properties of the foamed cement: 1) The hydrothermal stability of the AP in 200 and #61616;C-autoclaved cements; 2) the hydrolysis-hydration reactions of the slurry at 85 and #61616;C; 3) the composition of crystalline phases assembled and the microstructure developed in autoclaved cements; 4) the mechanical behaviors of the autoclaved cements; and, 5) the corrosion mitigation of carbon steel (CS) by the polymer. For the first property, the hydrothermal-catalyzed acid-base interactions between the AP and cement resulted in Ca-or Na-complexed carboxylate derivatives, which led to the improvement of thermal stability of the AP. This interaction also stimulated the cement hydration reactions, enhancing the total heat evolved during cement’s curing. Addition of AP did not alter any of the crystalline phase compositions responsible for the strength of the cement. Furthermore, the AP-modified cement developed the porous microstructure with numerous defect-free cavities of disconnected voids. These effects together contributed to the improvement of compressive-strength and –toughness of the cured cement. AP modification of the cement also offered an improved protection of CS against brine-caused corrosion. There were three major factors governing the corrosion protection: 1) Reducing the extents of infiltration and transportation of corrosive electrolytes through the cement layer deposited on the underlying CS surfaces; 2) inhibiting the cathodic reactions at the corrosion site of CS; 3) extending the coverage of cement over CS surfaces; and, 4) improving the adherence of the cement to CS surfaces. Thus, the CS’s corrosion rate of 176 milli inch/per year (mpy) for 1 wt% FA-foamed cement without AP was considerably reduced to 69 mpy by adding only 2 wt% AP. Addition of AP at 10 wt% further reduced this rate to less than 10 mpy.

  12. Carbon dioxide capture from a cement manufacturing process

    DOE Patents [OSTI]

    Blount, Gerald C. (North Augusta, SC); Falta, Ronald W. (Seneca, SC); Siddall, Alvin A. (Aiken, SC)

    2011-07-12T23:59:59.000Z

    A process of manufacturing cement clinker is provided in which a clean supply of CO.sub.2 gas may be captured. The process also involves using an open loop conversion of CaO/MgO from a calciner to capture CO.sub.2 from combustion flue gases thereby forming CaCO.sub.3/CaMg(CO.sub.3).sub.2. The CaCO.sub.3/CaMg(CO.sub.3).sub.2 is then returned to the calciner where CO.sub.2 gas is evolved. The evolved CO.sub.2 gas, along with other evolved CO.sub.2 gases from the calciner are removed from the calciner. The reactants (CaO/MgO) are feed to a high temperature calciner for control of the clinker production composition.

  13. System and method for glass processing and temperature sensing

    DOE Patents [OSTI]

    Shepard, Chester L.; Cannon, Bret D.; Khaleel, Mohammad A.

    2004-09-28T23:59:59.000Z

    Techniques for measuring the temperature at various locations through the thickness of glass products and to control the glass processing operation with the sensed temperature information are disclosed. Fluorescence emission of iron or cerium in glass is excited and imaged onto segmented detectors. Spatially resolved temperature data are obtained through correlation of the detected photoluminescence signal with location within the glass. In one form the detected photoluminescence is compared to detected scattered excitation light to determine temperature. Stress information is obtained from the time history of the temperature profile data and used to evaluate the quality of processed glass. A heating or cooling rate of the glass is also controlled to maintain a predetermined desired temperature profile in the glass.

  14. SLUDGE BATCH 7B GLASS VARIABILITY STUDY

    SciTech Connect (OSTI)

    Johnson, F.; Edwards, T.

    2011-10-25T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable using the current Product Composition Control System (PCCS) models for durability, but were acceptable compared to the EA glass when tested. These glasses fell outside of the lower 95% confidence band, which demonstrates conservatism in the model. A few of the glasses fell outside of the upper 95% confidence band; however, these particular glasses have normalized release values that were much lower than the values of EA and should be of no practical concern. Per the requirements of the DWPF Glass Product Control Program, the PCCS durability models have been shown to be applicable to the SB7b sludge system with a range of Na{sub 2}O concentrations blended with Frits 418 or 702. PCT results from the glasses fabricated as part of the variability study were shown to be predictable by the current DWPF PCCS models and/or acceptable with respect to the EA benchmark glass regardless of thermal history or compositional view.

  15. New techniques for monitoring cement hydration under simulated well conditions

    SciTech Connect (OSTI)

    Luke, K.; Hall, C.; Jones, T. [Schlumberger Cambridge Research (United Kingdom); Barnes, P.; Turillas, X.; Lewis, A. [Univ. of London (United Kingdom). Birkbeck College

    1995-11-01T23:59:59.000Z

    Fourier transform infrared spectroscopy and synchrotron X-ray powder diffraction methods are described for studying cement hydration chemistry at temperatures up to 200 C, covering the normal temperature range of wellbore cementing. The methods provide complementary information on the transformation of silicate, ferrite and sulfate minerals. The thermal decomposition of the cement mineral ettringite is shown to occur at 114 C in a sealed system in contact with water. The FTIR spectrum of a well cement slurry hydrating at 150 C and 2,000 psi is analyzed. The anomalous thickening time behavior of certain cements around 75--100 C is discussed in the light of new data on the hydration of a Class G cement at 65 and 95 C, with and without retarder.

  16. Effective Permeability Change in Wellbore Cement with Carbon Dioxide Reaction

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Martin, Paul F.; McGrail, B. Peter

    2011-11-01T23:59:59.000Z

    Portland cement, a common sealing material for wellbores for geological carbon sequestration was reacted with CO{sub 2} in supercritical, gaseous, and aqueous phases at various pressure and temperature conditions to simulate cement-CO{sub 2} reaction along the wellbore from carbon injection depth to the near-surface. Hydrated Portland cement columns (14 mm diameter x 90 mm length; water-to-cement ratio = 0.33) including additives such as steel coupons and Wallula basalt fragments were reacted with CO{sub 2} in the wet supercritical (the top half) and dissolved (the bottom half) phases under carbon sequestration condition with high pressure (10 MPa) and temperature (50 C) for 5 months, while small-sized hydrated Portland cement columns (7 mm diameter x 20 mm length; water-to-cement ratio = 0.38) were reacted with CO{sub 2} in dissolved phase at high pressure (10 MPa) and temperature (50 C) for 1 month or with wet CO{sub 2} in gaseous phase at low pressure (0.2 MPa) and temperature (20 C) for 3 months. XMT images reveal that the cement reacted with CO{sub 2} saturated groundwater had degradation depth of {approx}1 mm for 1 month and {approx}3.5 mm for 5 month, whereas the degradation was minor with cement exposure to supercritical CO{sub 2}. SEM-EDS analysis showed that the carbonated cement was comprised of three distinct zones; the innermost less degraded zone with Ca atom % > C atom %, the inner degraded zone with Ca atom % {approx} C atom % due to precipitation of calcite, the outer degraded zone with C atom % > Ca atom % due to dissolution of calcite and C-S-H, as well as adsorption of carbon to cement matrix. The outer degraded zone of carbonated cement was porous and fractured because of dissolution-dominated reaction by carbonic acid exposure, which resulted in the increase in BJH pore volume and BET surface area. In contrast, cement-wet CO{sub 2}(g) reaction at low P (0.2 MPa)-T (20 C) conditions for 1 to 3 months was dominated by precipitation of micron-sized calcite on the outside surface of cement, which resulted in the decrease in BJH pore volume and BET surface area. Cement carbonation and pore structure change are significantly dependent on pressure and temperature conditions as well as the phase of CO{sub 2}, which controls the balance between precipitation and dissolution in cement matrix. Geochemical modeling result suggests that ratio of solid (cement)-to-solution (carbonated water) has a significant effect on cement carbonation, thus the cement-CO{sub 2} reaction experiment needs to be conducted under realistic conditions representing the in-situ wellbore environment of carbon sequestration field site. Total porosity and air permeability for a duplicate cement column with water-to-cement ratio of 0.38 measured after oven-drying by Core Laboratories using Boyle's Law technique and steady-state method were 31% and 0.576 mD. A novel method to measure the effective liquid permeability of a cement column using X-ray micro-tomography images after injection of pressurized KI (potassium iodide) is under development by PNNL. Preliminary results indicate the permeability of a cement column with water-to-cement ratio of 0.38 is 4-8 mD. PNNL will apply the method to understand the effective permeability change of Portland cement by CO{sub 2}(g) reaction under a variety of pressure and temperature conditions to develop a more reliable well-bore leakage risk model.

  17. Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers

    SciTech Connect (OSTI)

    Galitsky, Christina; Worrell, Ernst; Galitsky, Christina

    2008-01-01T23:59:59.000Z

    The cost of energy as part of the total production costs in the cement industry is significant, warranting attention for energy efficiency to improve the bottom line. Historically, energy intensity has declined, although more recently energy intensity seems to have stabilized with the gains. Coal and coke are currently the primary fuels for the sector, supplanting the dominance of natural gas in the 1970s. Most recently, there is a slight increase in the use of waste fuels, including tires. Between 1970 and 1999, primary physical energy intensity for cement production dropped 1 percent/year from 7.3 MBtu/short ton to 5.3 MBtu/short ton. Carbon dioxide intensity due to fuel consumption and raw material calcination dropped 16 percent, from 609 lb. C/ton of cement (0.31 tC/tonne) to 510 lb. C/ton cement (0.26 tC/tonne). Despite the historic progress, there is ample room for energy efficiency improvement. The relatively high share of wet-process plants (25 percent of clinker production in 1999 in the U.S.) suggests the existence of a considerable potential, when compared to other industrialized countries. We examined over 40 energy efficient technologies and measures and estimated energy savings, carbon dioxide savings, investment costs, and operation and maintenance costs for each of the measures. The report describes the measures and experiences of cement plants around the wold with these practices and technologies. Substantial potential for energy efficiency improvement exists in the cement industry and in individual plants. A portion of this potential will be achieved as part of (natural) modernization and expansion of existing facilities, as well as construction of new plants in particular regions. Still, a relatively large potential for improved energy management practices exists.

  18. An investigation of cement mortar thermal storage characteristics

    E-Print Network [OSTI]

    Davis, Glenn Baker

    2012-06-07T23:59:59.000Z

    energy storage characteristics of solid cement mortar cylinders. Two var1a- tions 1nvolving mechanically induced porosity were also investigated. Rocks, a commonly used sensible heat storage material, were tested to prov1de a reference for the cement... mortar. A numer1cal model, analogous to program available for rock bed storage systems, simulating the cement mortar cylinder storage section was developed. Heat transfer coefficients were calculated from the experimental data for use in the model...

  19. Diamond turning of glass

    SciTech Connect (OSTI)

    Blackley, W.S.; Scattergood, R.O.

    1988-12-01T23:59:59.000Z

    A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

  20. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    the small cement plants, earthen vertical kiln (and hollowcement plant in North China utilizing vertical shaft kilnscement has ordered a vertical roller mill for the new kiln

  1. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    Lime Institute. 2001. Energy Efficiency Opportunity Guide inIndustry, Office of Energy Efficiency, Natural Resourcesof a Cement Kiln, Energy Efficiency Demonstration Scheme,

  2. Multifunctional Corrosion-resistant Foamed Well Cement Composites

    Broader source: Energy.gov (indexed) [DOE]

    Multifunctional Corrosion-resistant Foamed Well Cement Composites Project Officer: Dan KingGreg Stillman Total budget: 300 K April 24 , 2013 Principal Investigator: Dr. Toshifumi...

  3. Optimization Online - The carbon leakage effect on the cement ...

    E-Print Network [OSTI]

    Elisabetta Allevi

    2015-02-08T23:59:59.000Z

    Feb 8, 2015 ... This paper investigates the impact of these two policies on the cement sector ... Environmental policies, Generalized Nash Equilibrium Problem.

  4. Development of an Improved Cement for Geothermal Wells

    Broader source: Energy.gov (indexed) [DOE]

    availability. * Schedule slippage resulting from delays in the fabrication of Chandler Engineering specialized high pressurehigh temperature cement testing equipment. 6 | US...

  5. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    on Power Generation by Waste Heat of the Kiln in NingguoPure Low Temperature & Waste Heat in Beijing Cement Ltd. ;flash distillation waste heat power generation demonstration

  6. Stabilizing coal-water mixtures with Portland cement

    DOE Patents [OSTI]

    Steinberg, M.; Krishna, C.R.

    1984-10-17T23:59:59.000Z

    Coal-water mixes stabilized by the addition of Portland cement which may additionally contain retarding carbohydrates, or borax are described. 1 tab.

  7. Identification of active agents for tetrachloroethylene degradation in Portland cement slurry containing ferrous iron

    E-Print Network [OSTI]

    Ko, Sae Bom

    2006-08-16T23:59:59.000Z

    -EDS) were used to identify minerals in chemical mixtures that have high activities. Results indicate that active agents for PCE degradation in Portland cement slurries and in cement extracts might be one of several AFm phases. However, systems without cement...

  8. Instantaneous In-Situ Determination of Water-Cement Ratio of Fresh Concrete

    E-Print Network [OSTI]

    Mancio, Mauricio; Moore, Jeffrey R.; Brooks, Zenzile; Monteiro, Paulo J. M.; Glaser, Steve D.

    2010-01-01T23:59:59.000Z

    method for cement content determination of fresh concrete.Cement and Concrete Research, 1980. 10(1): p. 23-34. Hime,the cement content of plastic concrete. ASTM Bulletin, 1955.

  9. Calcite cemented layers, their characterization and use in improving reservoir recovery from Murchison field, northern North Sea

    SciTech Connect (OSTI)

    Warrender, J.M. (Conoco Ltd., Aberdeen (United Kingdom)); Spears, D.A. (Univ. of Sheffield (United Kingdom))

    1991-08-01T23:59:59.000Z

    Murchison field is a mature development forming part of the Brent oil province in the East Shetland basin, northern North Sea. The productive reservoir consists of coastal deltaic sands of the Middle Jurassic Brent Group and is produced by a line-drive waterflood mechanism. The Rannoch Formation in Murchison, one of the field's most prolific producing zones, is characterized by the presence of calcite-cemented zones, known locally as doggers, which occlude all porosity and behave as vertical barriers to fluid flow. Geochemical-mineralogical analysis of the carbonate cements allied to sedimentological studies of host sandstone indicate that they occur as continuously cemented layers with relatively homogeneous compositions. Dogger occurrence is generally confined to the upper parts of individual coarsening-upward confined to the upper parts of individual coarsening-upward profile and sand bodies, characterized by low detrital clay and mica contents, low bioturbation, and high pre-cementation porosites and permeabilities. The carbonate bands are thus thought to represent zones of maximum pore water flow through high permeability conduits during burial diagenesis. Wireline correlation supported by core description indicates that at least three significant, laterally continuous calcite-cemented zones occur, the most extensive of which has a lateral extent of at least 5 km. All significant doggers have been mapped geologically and incorporated into the full-field reservoir simulation model. Based on this new understanding, a revised infill drilling and perforation strategy has been devised for the Rannoch Formation, aimed at improving recovery from this complex reservoir zone.

  10. Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2010-01-01T23:59:59.000Z

    300-500°C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

  11. Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    Modern Vertical Shaft Kiln Technology” World Cement 1 26cement has ordered a vertical roller mill for the new kiln

  12. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R #12;1 HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R. Naik, Shiw S. Singh, and Bruce for manufacture of cement-based products using ashes generated from combustion of high-sulfur coals. A clean coal

  13. E-Print Network 3.0 - affect cement penetration Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a coating Summary: as an admixture in cement and as a coating on cement for electromagnetic interference shielding'' J. Cao, D... parameters that affect the shielding...

  14. E-Print Network 3.0 - aluminate cement blended Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    predicting the setting times of Type I cement concrete and blended... -29, 1980. 20. Tay, J. .H., Properties of Pulverized Sludge Ash Blended Cement. ACI Materials Journals... OF...

  15. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    Wang, L. , 2008. Alternative fuel using and waste materialPolicy Research on Alternative Fuels for Cement Industry incement and using alternative fuels in the cement kiln. There

  16. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    UNFCCC), 2007 b. Energy efficiency measures at cementUNFCCC), 2007 c. Energy efficiency measures at cementBanerjee, R. , 2005. Energy Efficiency and Demand Side

  17. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    and MAIN, 1993. Energy Technology in the Cement Industrialof Demonstrated Energy Technologies (CADDET), Internationaland MAIN. 1993. Energy Technology in the Cement Industrial

  18. HGMS: Glasses and Nanocomposites for Hydrogen Storage.

    SciTech Connect (OSTI)

    Lipinska, Kris [PI] [PI; Hemmers, Oliver

    2013-02-17T23:59:59.000Z

    The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not directly address any hydrogen storage technical barriers or targets in terms of numbers. Specifically, hydrogen sorption and desorption tests or kinetics measurements were not part of the project scope. However, the insights gained from these studies could help to answer fundamental questions necessary for considering glass-based materials as hydrogen storage media and could be applied indirectly towards the DOE hydrogen storage technical targets such as system weight and volume, system cost and energy density. Such questions are: Can specific macro-crystals, proven to attract hydrogen when in a macroscopic form (bulk), be nucleated in glass matrices as nanocrystals to create two-phased materials? What are suitable compositions that enable to synthetize glass-based, two-phase materials with nanocrystals that can attract hydrogen via surface or bulk interactions? What are the limits of controlling the microstructure of these materials, especially limits for nanocrystals density and size? Finally, from a technological point of view, the fabrication of glass-derived nanocomposites that we explore is a very simple, fast and inexpensive process that does not require costly or specialized equipment which is an important factor for practical applications.

  19. Thermal Predictions of the Cooling of Waste Glass Canisters

    SciTech Connect (OSTI)

    Donna Post Guillen

    2014-11-01T23:59:59.000Z

    Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

  20. Defense HLW Glass Degradation Model

    SciTech Connect (OSTI)

    D. Strachan

    2004-10-20T23:59:59.000Z

    The purpose of this report is to document the development of a model for calculating the release rate for radionuclides and other key elements from high-level radioactive waste (HLW) glasses under exposure conditions relevant to the performance of the repository. Several glass compositions are planned for the repository, some of which have yet to be identified (i.e., glasses from Hanford and Idaho National Engineering and Environmental Laboratory). The mechanism for glass dissolution is the same for these glasses and the glasses yet to be developed for the disposal of DOE wastes. All of these glasses will be of a quality consistent with the glasses used to develop this report.

  1. Plant-Wide Energy Efficiency Assessment at the Arizona Portland Cement Plant in Rillito, Arizona

    SciTech Connect (OSTI)

    Stephen J. Coppinger, P.E.; Bruce Colburn, Ph.D., P.E., CEM

    2007-05-17T23:59:59.000Z

    A Department of Energy Plant-wide Assessment was undertaken by Arizona Portland Cement (APC) beginning in May 2005. The assessment was performed at APC’s cement production facility in Rillito, Arizona. The assessment included a compressed air evaluation along with a detailed process audit of plant operations and equipment. The purpose of this Energy Survey was to identify a series of energy cost savings opportunities at the Plant, and provide preliminary cost and savings estimates for the work. The assessment was successful in identifying projects that could provide annual savings of over $2.7 million at an estimated capital cost of $4.3 million. If implemented, these projects could amount to a savings of over 4.9 million kWh/yr and 384,420 MMBtu/year.

  2. Cement (2010 MECS) | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational HealthcatalystsMaking Same -Cement (2010

  3. High Temperature Cements | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio:GreerHi Gtel Jump to: navigation,Solar Power Plant JumpDrillingCements

  4. Cement Bond Log | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV EconomicsOregon: Energy ResourcesCeilingCement Bond

  5. Communication Electric polarization in carbon fiber-reinforced cement

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    Communication Electric polarization in carbon fiber-reinforced cement Sihai Wen, D.D.L. Chung Abstract Electric polarization induced an increase of the measured electrical resistivity of carbon fiber of the cement paste through the use of carbon fibers that were more crystalline, the increase of the fiber

  6. Portland Cement Concrete Pavement Shannon Golden, Alabama DOT

    E-Print Network [OSTI]

    Portland Cement Concrete Pavement Shannon Golden, Alabama DOT PORTLAND CEMENT CONCRETE PAVEMENT PROJECT · First in Alabama in more than 25 years! · IM-I059 (342) Etowah County ­ I-59 Concrete Pavement Rehabilitation with Unbonded Concrete Overlay ­ Length: 10.9 miles ­ Thickness: 11.0 to 13.5 inches ­ Volume: 300

  7. Glass produced by underground nuclear explosions. [Rainier

    SciTech Connect (OSTI)

    Schwartz, L.; Piwinskii, A.; Ryerson, F.; Tewes, H.; Beiriger, W.

    1983-01-01T23:59:59.000Z

    Detonation of an underground nuclear explosive produces a strong shock wave which propagates spherically outward, vaporizing the explosive and nearby rock and melting, the surrounding rock. The vaporized material expands adiabatically, forming a cavity. As the energy is dissipated during the cavity formation process, the explosive and rock debris condense and mix with the melted rock. The melt flows to the bottom of the cavity where it is quenched by fractured rock fragments falling from above as the cavity collapses. Measurements indicate that about 740 tonnes of rock and/or soil are melted for every kiloton (10/sup 12/ calories) of explosive energy, or about 25% of the explosive energy goes to melting rock. The resulting glass composition reflects the composition of the unaltered rock with explosive debris. The appearance ranges from white pumice to dense, dark lava. The bulk composition and color vary with the amount of explosive iron incorporated into the glass. The refractory explosion products are mixed with the solidified melt, although the degree of mixing is variable. Electron microprobe studies of glasses produced by Rainier in welded tuff have produced the following results: glasses are dehydrated relative to the host media, glasses are extremely heterogeneous on a 20 ..mu..m scale, a ubiquitous feature is the presence of dark marble-cake regions in the glass, which were locally enriched in iron and may be related to the debris, optically amorphous regions provide evidence of shock melting, only limited major element redistribution and homogenization occur within the cavity.

  8. Potential for energy conservation in the glass industry

    SciTech Connect (OSTI)

    Garrett-Price, B.A.; Fassbender, A.G.; Bruno, G.A.

    1986-06-01T23:59:59.000Z

    While the glass industry (flat glass, container glass, pressed and blown glass, and insulation fiber glass) has reduced its specific energy use (Btu/ton) by almost 30% since 1972, significant potential for further reduction still remains. State-of-the-art technologies are available which could lead to incremental improvements in glass industry energy productivity; however, these technologies must compete for capital with projects undertaken for other reasons (e.g., capacity expansion, equipment rebuild, labor cost reduction, product quality improvement, or compliance with environmental, health or safety regulations). Narrowing profit margins in the large tonnage segments of the glass industry in recent years and the fact that energy costs represent less than 25% of the value added in glass manufacture have combined to impede the widespread adoption of many state-of-the-art conservation technologies. Savings in energy costs alone have not provided the incentive to justify the capital expenditures required to realize the energy savings. Beyond implementation of state-of-the-art technologies, significant potential energy savings could accrue from advanced technologies which represent a radical departure from current glass making technology. Long-term research and development (R and D) programs, which address the technical and economic barriers associated with advanced, energy-conserving technologies, offer the opportunity to realize this energy-saving potential.

  9. EMPIRICAL MODEL FOR FORMULATION OF CRYSTAL-TOLERANT HLW GLASSES

    SciTech Connect (OSTI)

    KRUGER AA; MATYAS J; HUCKLEBERRY AR; VIENNA JD; RODRIGUEZ CA

    2012-03-07T23:59:59.000Z

    Historically, high-level waste (HLW) glasses have been formulated with a low liquideus temperature (T{sub L}), or temperature at which the equilibrium fraction of spinel crystals in the melt is below 1 vol % (T{sub 0.01}), nominally below 1050 C. These constraints cannot prevent the accumulation of large spinel crystals in considerably cooler regions ({approx} 850 C) of the glass discharge riser during melter idling and significantly limit the waste loading, which is reflected in a high volume of waste glass, and would result in high capital, production, and disposal costs. A developed empirical model predicts crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass, and thereby provides guidance in formulating crystal-tolerant glasses that would allow high waste loadings by keeping the spinel crystals small and therefore suspended in the glass.

  10. Engineering Glass Passivation Layers -Model Results

    SciTech Connect (OSTI)

    Skorski, Daniel C.; Ryan, Joseph V.; Strachan, Denis M.; Lepry, William C.

    2011-08-08T23:59:59.000Z

    The immobilization of radioactive waste into glass waste forms is a baseline process of nuclear waste management not only in the United States, but worldwide. The rate of radionuclide release from these glasses is a critical measure of the quality of the waste form. Over long-term tests and using extrapolations of ancient analogues, it has been shown that well designed glasses exhibit a dissolution rate that quickly decreases to a slow residual rate for the lifetime of the glass. The mechanistic cause of this decreased corrosion rate is a subject of debate, with one of the major theories suggesting that the decrease is caused by the formation of corrosion products in such a manner as to present a diffusion barrier on the surface of the glass. Although there is much evidence of this type of mechanism, there has been no attempt to engineer the effect to maximize the passivating qualities of the corrosion products. This study represents the first attempt to engineer the creation of passivating phases on the surface of glasses. Our approach utilizes interactions between the dissolving glass and elements from the disposal environment to create impermeable capping layers. By drawing from other corrosion studies in areas where passivation layers have been successfully engineered to protect the bulk material, we present here a report on mineral phases that are likely have a morphological tendency to encrust the surface of the glass. Our modeling has focused on using the AFCI glass system in a carbonate, sulfate, and phosphate rich environment. We evaluate the minerals predicted to form to determine the likelihood of the formation of a protective layer on the surface of the glass. We have also modeled individual ions in solutions vs. pH and the addition of aluminum and silicon. These results allow us to understand the pH and ion concentration dependence of mineral formation. We have determined that iron minerals are likely to form a complete incrustation layer and we plan to look more closely at Vivianite [Fe3(PO4)2-8(H2O)] and Siderite [FeCO3] in the next stage of the project.

  11. Effect of Elevated Curing Temperature on Early Hydration and Microstructure of Composite Cements

    E-Print Network [OSTI]

    Sheffield, University of

    Effect of Elevated Curing Temperature on Early Hydration and Microstructure of Composite Cements J, Seascale, Cumbria, CA20 1PG, UK Abstract The heat of hydration of a number of composite cement systems has of composite cements based on the partial replacement of Portland cement by waste materials has become

  12. Abstract The concurrent goals of cement hydration are to percolate (bridge) the original

    E-Print Network [OSTI]

    Bentz, Dale P.

    Cement hydration Ã? Low temperature calorimetry Ã? Microstructure Ã? Percolation Ã? Porosity Ã? Rheology Ã?, however, cement-based materials exhibit a highly dynamic (micro)structure that is extremely sen- sitive. Because many of the cement hydration prod- ucts form around the initial cement clinker par- ticles

  13. Time-dependent behaviour of hardened cement paste under isotropic loading

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of hardened cement paste under isotropic loading, Cement and Concrete Research, doi: 10.1016/j.cemconres.2012.03.002 hal-00689716,version1-19Apr2012 Author manuscript, published in "Cement and Concrete Research (2012 the framework of the classical theory of porous media. The effects of water-to-cement ratio and chemical

  14. Z .Chemical Geology 152 1998 257271 The thermal and cementation histories of a sandstone petroleum

    E-Print Network [OSTI]

    Z .Chemical Geology 152 1998 257­271 The thermal and cementation histories of a sandstone petroleum of the cement formed, the maturation of petroleum in the interbedded shales likely postdates cementation. q 1998 of partially cemented petroleum reservoirs may help in constraining the physical character of a reservoir

  15. Expanded High-Level Waste Glass Property Data Development: Phase I

    SciTech Connect (OSTI)

    Schweiger, Michael J.; Riley, Brian J.; Crum, Jarrod V.; Hrma, Pavel R.; Rodriguez, Carmen P.; Arrigoni, Benjamin M.; Lang, Jesse B.; Kim, Dong-Sang; Vienna, John D.; Raszewski, F. C.; Peeler, David K.; Edwards, Tommy B.; Best, D. R.; Reamer, Irene A.; Riley, W. T.; Simmons, P. T.; Workman, R. J.

    2011-01-21T23:59:59.000Z

    Two separate test matrices were developed as part if the EM-21 Glass Matrix Crucible Testing. The first matrix, developed using a single component-at-a-time design method and covering glasses of interest primarily to Hanford, is addressed in this data package. This data package includes methods and results from glass fabrication, chemical analysis of glass compositions, viscosity, electrical conductivity, liquidus temperature, canister centerline cooling, product consistency testing, and the toxicity characteristic leach procedure.

  16. Baseline LAW Glass Formulation Testing

    SciTech Connect (OSTI)

    Kruger, Albert A. [USDOE Office of River Protection, Richland, WA (United States); Mooers, Cavin [The Catholic University of America, Washington, DC (United States). Vitreous State Lab.; Bazemore, Gina [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Pegg, Ian L. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Hight, Kenneth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Lai, Shan Tao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Buechele, Andrew [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Rielley, Elizabeth [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Gan, Hao [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Muller, Isabelle S. [The Catholic University of America, Washington, DC (United States). Vitreous State Lab; Cecil, Richard [The Catholic University of America, Washington, DC (United States). Vitreous State Lab

    2013-06-13T23:59:59.000Z

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  17. Methods of vitrifying waste with low melting high lithia glass compositions

    DOE Patents [OSTI]

    Jantzen, Carol M. (Aiken, SC); Pickett, John B. (Aiken, SC); Cicero-Herman, Connie A. (Aiken, SC); Marra, James C. (Aiken, SC)

    2001-01-01T23:59:59.000Z

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  18. Solid-phase synthesis of high-alumina cements by high-temperature treatment on the surface of molten cast iron

    SciTech Connect (OSTI)

    Fedorov, N.F.; Gavrilov, A.P.; Ivanov, N.I.; Khalina, O.M.

    1986-09-10T23:59:59.000Z

    The use of block and monolithic concreting technology in the construction of thermal power plants together with the technical and economic advantages arising from the use of high-alumina cements in the production of refractory concretes have made the development of new methods for the production of high-alumina cement clinkers mandatory. To this end the authors of this paper study the kinetics of synthesis of such clinkers obtained by their firing on the surface of molten cast iron as the heat transfer agent. Among the results presented are a structural and quantitative analysis of the clinker along with phase and activation energy studies.

  19. Metallic glass composition

    DOE Patents [OSTI]

    Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

    1986-01-01T23:59:59.000Z

    A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

  20. DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION

    SciTech Connect (OSTI)

    Adamson, D; Bradley Pickenheim, B

    2008-11-24T23:59:59.000Z

    DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point that the test apparatus had to be disassembled to dislodge the plugs created in the system.

  1. Use of Finite-element Analysis to Improve Well Cementing in HTHP Conditions

    E-Print Network [OSTI]

    Arias, Henry

    2013-07-30T23:59:59.000Z

    stresses of San Antonio cement (left) and PEEQ of cement San Antonio and Barco formation (right) after hydraulic fracturing ........ 103 Figure 5.1 UCS (top left), Young?s modulus (top right), and Poisson?s ratio (bottom) for Halliburton Portland... cements ............................................... 110 Figure 5.2 Tensile strength for Halliburton Portland cements ................................... 111 Figure 5.3 Stress strain-curve and photo of uniaxial test for Halliburton Portland cement...

  2. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25T23:59:59.000Z

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  3. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Center for By-Products Utilization CHARACTERIZATION AND APPLICATION OF CLASSF FLY ASHCOAL AND CLEAN-COAL #12;-1- CHARACTERIZATION AND APPLICATION OF CLASSF FLYASHCOAL AND CLEAN-COAL ASHFOR CEMENT -Milwaukee (UWM) Daniel D.Banerjee, Project Manager,Illinois Clean Coal Institute RudolphN.Kraus, Research

  4. Glass matrix armor

    DOE Patents [OSTI]

    Calkins, Noel C. (Los Alamos, NM)

    1991-01-01T23:59:59.000Z

    An armor system which utilizes glass. A plurality of constraint cells are mounted on a surface of a substrate, which is metal armor plate or a similar tough material, such that the cells almost completely cover the surface of the substrate. Each constraint cell has a projectile-receiving wall parallel to the substrate surface and has sides which are perpendicular to and surround the perimeter of the receiving wall. The cells are mounted such that, in one embodiment, the substrate surface serves as a sixth side or closure for each cell. Each cell has inside of it a plate, termed the front plate, which is parallel to and in contact with substantially all of the inside surface of the receiving wall. The balance of each cell is completely filled with a projectile-abrading material consisting of glass and a ceramic material and, in certain embodiments, a polymeric material. The glass may be in monolithic form or particles of ceramic may be dispersed in a glass matrix. The ceramic material may be in monolithic form or may be in the form of particles dispersed in glass or dispersed in said polymer.

  5. Comparison of glass surfaces as a countertop material to existing surfaces

    SciTech Connect (OSTI)

    Turo, Laura A.; Winschell, Abigail E.

    2011-09-01T23:59:59.000Z

    Gleen Glass, a small production glass company that creates countertops, was selected for the Technology Assistance Program through Pacific Northwest National Laboratory. Gleen Glass was seeking material property analysis comparing glass as a countertop material to current surfaces (i.e. marble, granite and engineered stone). With samples provided from Gleen Glass, testing was done on granite, marble, and 3 different glass surfaces ('Journey,' 'Pebble,' and 'Gleen'). Results showed the glass surfaces have a lower density, lower water absorption, and are stronger in compressive and flexural tests as compared to granite and marble. Thermal shock tests showed the glass failed when objects with a high thermal mass are placed directly on them, whereas marble and granite did not fracture under these conditions.

  6. IRON-PHOSPHATE GLASS FOR IMMOBILIZATION OF RADIOACTIVE TECHNETIUM

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; XU K; CHOI J; UM W; HEO J

    2012-03-19T23:59:59.000Z

    Technetium-99 (Tc-99) can bring a serious environmental threat because of its high fission yield, long half-life, and high solubility and mobility in the ground water. The present work investigated the immobilization of Tc-99 (surrogated by Re) by heat-treating mixtures of an iron-phosphate glass with 1.5 to 6 wt.% KReO{sub 4} at {approx}1000 C. The Re retention in the glass was as high as {approx}1.2 wt. % while the loss of Re by evaporation during melting was {approx}50%. Re was uniformly distributed within the glass. The normalized Re release by the 7-day Product Consistency Test was {approx}0.39 g/m{sup 2}, comparable with that in phosphate-bonded ceramics and borosilicate glasses. These results suggest that iron-phosphate glass can provide a good matrix for immobilizing Tc-99.

  7. Carbonation Behavior of Pure Cement Hydrates under Supercritical Carbon Dioxide Conditions - 12199

    SciTech Connect (OSTI)

    Hirabayashi, Daisuke; Enokida, Youichi [Graduate School of Engineering, Nagoya University, 1 Furo-cho, Chikusa-ku, Nagoya-shi, Aichi-ken, 464-8603 (Japan); Sawada, Kayo [EcoTopia Science Institute, Nagoya University, 1 Furo-cho, Chikusa-ku, Nagoya-shi, Aichi-ken, 464-8603 (Japan); Hertz, Audrey; Charton, Frederic [CEA, DEN, Marcoule, DTCD/SPDE/L2ED, BP 17171, F-30207 Bagnols-sur-Ceze (France); Frizon, Fabien [CEA, DEN, Marcoule, DTCD/SPDE/LFSM, BP 17171, F-30207 Bagnols-sur-Ceze (France); Brouno, Fournel [CEA, DEN, Marcoule, DTCD, BP 17171, F-30207 Bagnols-sur-Ceze (France)

    2012-07-01T23:59:59.000Z

    Carbonation of cement-based waste forms using a supercritical carbon dioxide (SCCO{sub 2}) is a developing technology for the waste immobilization of radioactive and non-radioactive wastes. However, the detail carbonation behaviors of cement matrices under the SCCO{sub 2} condition are unknown, since cement matrices forms very complex phases. In this study, in order to clarify the crystal phases, we synthesized pure cement hydrate phases as each single phases; portlandite (Ca(OH){sub 2}), ettringite (Ca{sub 6}Al{sub 2}(SO{sub 4}){sub 3}(OH){sub 12}.26H{sub 2}O), and calcium silicate hydrate (n CaO---m SiO{sub 2} ---x H{sub 2}O), using suspensions containing a stoichiometric mixture of chemical regents, and performed carbonation experiments using an autoclave under supercritical condition for carbon dioxide. The XRD results revealed both the carbonate phases and co-product phases depending on the initial hydrate phases; gypsum for Ettringite, amorphous or crystalline silica for calcium silicate hydroxide. Thermogravimetric analysis was also performed to understand carbonation behaviors quantitatively. According to the experimental results, it was found that the major reaction was formation of calcium carbonate (CaCO{sub 3}) in all cases. However, the behaviors of H{sub 2}O and CO{sub 2} content were quietly different: Portlandite was most reactive for carbonation under SCCO{sub 2} conditions, and the CO{sub 2} content per one molar CaO was ranged from 0.96 ? 0.98. In the case of Ettringite, the experiment indicates partial decomposition of ettringite phase during carbonation. Ettringite was comparatively stable even under the SCCO{sub 2} conditions. Therefore, a part of ettringite remained and formed similar phases after the ettringite carbonation. The CO{sub 2} content for ettringite showed almost constant values around 0.86 ? 0.87. In the case of calcium silicate hydrate, the carbonation behavior was significantly influenced by the condition of SCCO{sub 2}. The CO{sub 2} content for the calcium silicate hydrate had values that ranged from 0.51 ? 1.01. The co-products of the carbonation were gypsum (CaSO{sub 4}) for ettringite, silica gel (SiO{sub x}) and silica (SiO{sub 2}) for calcium silicate hydrate, which also contributed to the densification of the particles. The production of co-products enhanced the change to their morphology after the carbonation. (authors)

  8. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of...

  9. Investigation of the formation of a Portland Cement plant detached plume

    SciTech Connect (OSTI)

    Cheney, J.L.; Knapp, K.T.

    1986-05-01T23:59:59.000Z

    A gaseous and particulate-source emissions sampling program was conducted at a Portland Cement production plant in Rapid City, South Dakota. The study was conducted to determine the cause of the formation of an opaque detached plume from the plants' dry process kiln. The instack opacity of the emissions was less than 10% while the opacity of the plume five to ten stack diameters from the mouth of the stack was in excess of 40%, thus giving an appearance of a detached plume. The sampling and analysis program included particulate emissions measurements, particle sizing and composition, and measurements of gaseous and particle ammonia, chloride, fluoride, and sulfur dioxide. Extensive process materials sampling and analysis were also conducted. Based on the resulting data, one conclusion is that the opaque detached plume is the result of ammonium chloride particles formed by the reaction of gaseous ammonia and hydrochloric acid. It was also found that the ammonia in the cement plant was generated from the shale portion of the raw products when the raw product was passed through the heat exchanger.

  10. Americium/curium extraction from a lanthanide borosilicate glass

    SciTech Connect (OSTI)

    Rudisill, T.S.; Pareizs, J.M.; Ramsey, W.G.

    1996-12-01T23:59:59.000Z

    A solution containing kilogram quantities of highly radioactive isotopes of americium and curium (Am/Cm) and lanthanide fission products is currently stored in a process tank at the Department of Energy`s Savannah River Site (SRS). This tank and its vital support systems are old, subject to deterioration, and prone to possible leakage. For this reason, a program has been initiated to stabilize this material as a lanthanide borosilicate (LBS) glass. The Am/Cm has commercial value and is desired for use by the heavy isotope programs at the Oak Ridge National Laboratory (ORNL). A recovery flowsheet was demonstrated using a curium containing glass to extract the Am/Cm from the glass matrix. The procedure involved grinding the glass to less than 200 mesh and dissolving in concentrated nitric acid at 110 {degrees}C. Under these conditions, the dissolution was essentially 100% after 2 hours except for the insoluble silicon. Using a nonradioactive surrogate, the expected glass dissolution rate during Am/Cm recovery was bracketed by using both static and agitated conditions. The measured rates, 0.0082 and 0.040 g/hr.sq cm, were used to develop a predictive model for the time required to dissolve a spherical glass particle in terms of the glass density, particle size, and measured rate. The calculated dissolution time was in agreement with the experimental observation that the curium glass dissolution was complete in less than 2 hrs.

  11. The Color Glass Condensate

    E-Print Network [OSTI]

    F. Gelis; E. Iancu; J. Jalilian-Marian; R. Venugopalan

    2010-02-01T23:59:59.000Z

    We provide a broad overview of the theoretical status and phenomenological applications of the Color Glass Condensate effective field theory describing universal properties of saturated gluons in hadron wavefunctions that are extracted from deeply inelastic scattering and hadron-hadron collision experiments at high energies.

  12. Probing Water Phases in Cement Blends using 1 Magnetic Resonance Relaxometry

    E-Print Network [OSTI]

    Sheffield, University of

    the corrosion. In the long term, the volume increase due to the formation of corrosion products creates ratio (w:s). Pastes were poured into 1 cm OD diameter glass test tubes, vibrated to remove entrapped air their relative content. Relative content of chemically bound water was estimated by subtracting the CPMG

  13. Production

    Broader source: Energy.gov [DOE]

    Algae production R&D focuses on exploring resource use and availability, algal biomass development and improvements, characterizing algal biomass components, and the ecology and engineering of cultivation systems.

  14. The use of scrap tires in rotary cement kilns

    SciTech Connect (OSTI)

    Blumenthal, M. [Scrap Tire Management Council, Washington, DC (United States)

    1996-12-31T23:59:59.000Z

    The use of scrap tires as a supplemental fuel in the United States Portland cement industry has increased significantly in the past six years. In 1990, there were two kilns using tire-derived fuel (TDF), today 30 kilns use TDF. The outlook for continued and expanded use of TDF in the U.S. cement industry should be considered favorable, with 15 kilns conducting tests to determine TDF`s applicability or in the permitting process. The Council`s estimates are that by the end of 1996, the cement industry could be consuming some 75-100 million of the 253 million annually generated scrap tires in the United States. This level of TDF usage will make the cement industry the largest market segments for scrap tires in the United States. While the long-term outlook is at present positive, there are a series of factors that have, and will likely continue to adversely impact the near-term usage of TDF. These issues, as well as the factors that are likely to positively impact the cement kiln TDF market are the subject of this presentation.

  15. NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration

    E-Print Network [OSTI]

    Bentz, Dale P.

    NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration and Microstructure Development Modeling Package. Version 3.0 Dale P. Bentz #12;NISTIR 7232 CEMHYD3D: A Three-Dimensional Cement Hydration

  16. Energy conservation potential of Portland cement particle size distribution control, Phase 2

    SciTech Connect (OSTI)

    Helmuth, R.A; Whiting, D.A.

    1983-01-01T23:59:59.000Z

    The main objectives of Phase 2 are to determine the feasibility of using cements with controlled particle size distributions (CPSD cements) in practical concrete applications, and to refine our estimates of the potential energy savings that may ensue from such use. The work in Phase 2 is divided into two main tasks, some parts of which will be carried out simultaneously: Task 1 will continue cement paste studies to optimize cement performance similar to those of Phase 1, but with particular emphasis on gypsum requirements, blended cements, and water-reducing admixtures. This task will also include preparation of sufficient CPSD cements for use in all Phase 2 work. Task 2 will be a comprehensive examination of the properties of concretes made with CPSD cements. This will include optimization of concrete mix designs to obtain the best possible performance for practical applications of both portland and blended cements. The effects of chemical admixtures and curing temperature variations will also be determined.

  17. Unprocessed rice husk ash as a partial replacement of cement for low-cost concrete

    E-Print Network [OSTI]

    Brown, Dorothy Kamilah

    2012-01-01T23:59:59.000Z

    Cement is a very valuable commodity as it can be used to construct structurally sound buildings and infrastructure. However, in many developing countries cement is expensive due to the unavailability of local resources to ...

  18. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    2050 China Energy and CO2 Emissions Report. Science Press,Energy Savings and CO2 Emissions Reduction of China’s CementEnergy Savings and CO2 Emissions Reduction of China’s Cement

  19. Specialty Cellular Glass Products and Their Applications

    E-Print Network [OSTI]

    Rostoker, D.

    1979-01-01T23:59:59.000Z

    . One such field of application, the Alcoa Smelting Process, involves the use of molten salts which tend to impregnate materials which are porous to either salt vapors or to the liquid phase. Such impregnation of ordinary insulating materials causes a...

  20. Evaluation of final waste forms and recommendations for baseline alternatives to group and glass

    SciTech Connect (OSTI)

    Bleier, A.

    1997-09-01T23:59:59.000Z

    An assessment of final waste forms was made as part of the Federal Facilities Compliance Agreement/Development, Demonstration, Testing, and Evaluation (FFCA/DDT&E) Program because supplemental waste-form technologies are needed for the hazardous, radioactive, and mixed wastes of concern to the Department of Energy and the problematic wastes on the Oak Ridge Reservation. The principal objective was to identify a primary waste-form candidate as an alternative to grout (cement) and glass. The effort principally comprised a literature search, the goal of which was to establish a knowledge base regarding four areas: (1) the waste-form technologies based on grout and glass, (2) candidate alternatives, (3) the wastes that need to be immobilized, and (4) the technical and regulatory constraints on the waste-from technologies. This report serves, in part, to meet this goal. Six families of materials emerged as relevant; inorganic, organic, vitrified, devitrified, ceramic, and metallic matrices. Multiple members of each family were assessed, emphasizing the materials-oriented factors and accounting for the fact that the two most prevalent types of wastes for the FFCA/DDT&E Program are aqueous liquids and inorganic sludges and solids. Presently, no individual matrix is sufficiently developed to permit its immediate implementation as a baseline alternative. Three thermoplastic materials, sulfur-polymer cement (inorganic), bitumen (organic), and polyethylene (organic), are the most technologically developed candidates. Each warrants further study, emphasizing the engineering and economic factors, but each also has limitations that regulate it to a status of short-term alternative. The crystallinity and flexible processing of sulfur provide sulfur-polymer cement with the highest potential for short-term success via encapsulation. Long-term immobilization demands chemical stabilization, which the thermoplastic matrices do not offer. Among the properties of the remaining candidates, those of glass-ceramics (devitrified matrices) represent the best compromise for meeting the probable stricter disposal requirements in the future.

  1. E-Print Network 3.0 - aluminate cements hydration Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    INTRODUCTION Many entities currently use fly ash in portland cement concrete (PCC) pavements... Transportation & Development and Louisiana State University incorporating...

  2. Improved cement quality and grinding efficiency by means of closed mill circuit modeling

    E-Print Network [OSTI]

    Mejeoumov, Gleb Gennadievich

    2009-05-15T23:59:59.000Z

    ..............................................................................................................................185 Page x LIST OF FIGURES Figure 1.1. Portland Cement (after Bhatty et al., 2004). ....................................................1 Figure 1.2. A Simplified Schematic of a Dry Cement Manufacturing Process. ................3 Figure 1....................................13 Figure 2.2. Typical Particle Size Distribution of a Type I Portland Cement Sample. .....16 Figure 2.3. Rosin-Rammler Representation of Cement PSD...........................................21 Figure 2.4. Blaine Calculation within the Particle...

  3. Downhole cement test in a very hot hole

    SciTech Connect (OSTI)

    Pettitt, R.A.; Cocks, G.G.; Dreesen, D.N.; Sims, J.R.; Nicholson, R.W.; Boevers, B.

    1982-01-01T23:59:59.000Z

    Completion of the commercial-sized Hot Dry Rock Geothermal Energy Project requires that hydraulic fractures be created between two inclined wellbores at a depth of about 4 km (15,000 ft). Isolation of a section of the open wellbore is necessary for pressurization to achieve the fracture connections. A cemented-in liner/PBR assembly is one of the methods used for zone isolation near the botton of the injection well. A downhole, pumped cement test was first conducted at a wellbore temperature of 275/sup 0/C (525/sup 0/F) to determine if a suitable slurry could be designed, pumped, and later recovered to assure the success of the cemented-in liner operation.

  4. Rapid setting of portland cement by greenhouse carbon dioxide capture

    SciTech Connect (OSTI)

    Wagh, A.S.; Singh, D.; Knox, L.J.

    1994-04-01T23:59:59.000Z

    Following the work by Berger et al. on rapid setting of calcium silicates by carbonation, a method of high-volume capture of CO{sub 2} in portland cement has been developed. Typically, 10--24 wt. % of CO{sub 2} produced by the calcination of calcium carbonate during clinkering, may be captured, and the set cement acquires most of its full strength in less than a day. The approach will have economic advantages in fabrication of precast structures, in emergency development of infrastructure during natural disasters, and in defense applications. Moreover, it will help the cement industry comply with the Clean Air Act of 1990 by sequestering the greenhouse carbon dioxide.

  5. Effect of MgO Additive on Volumetric Expansion of Self-Degradable Cements

    SciTech Connect (OSTI)

    Sugama T.; Warren, J.; Butcher, T.

    2011-09-30T23:59:59.000Z

    We identified hard-burned magnesium oxide (MgO) as a suitable expansive additive for improving the plugging performance of self-degradable, temporary sodium silicate-activated slag/Class C fly ash (SSASC) blend cement sealers into rock fractures in Enhanced Geothermal Systems (EGSs). MgO extended the volumetric expansion of sealers during their exposure to a hydrothermal environment at 200 C under pressures, ranging from 300 to 1500 psi. A great expansion ratc of 19.3% was observed by adding 3.0 wt% MgO under 300 psi pressure, thus promising to plug thoroughly inner fracture. When the pressure was increased from 300 psi to 1500 psi, the expansion rate of cement markedly reduced, corresponding to the formaLion of crack-free specimens and the improvement of compressive strength. However, with 3.0 wt% MgO, the specimens still engendered the generation of numerous visual cracks, although they were prepared under a high pressure of 1500 psi. The effective content of MgO in minimizing and eliminating the generation of cracks was 2.0 wt%, which provided a moderate expansion of {ge} 0.5%. The compressive strength of 2.0 wt% MgO specimens made under a pressure of 300 psi rose {approx} 1.7-fold to 4816 psi with an increasing pressure to 1500 psi. The in-situ growth of brucite crystal formed by the hydrothermal hydration of MgO was responsive for such an expansion of the SSASC cement; meanwhile. two crystalline hydrothermal reaction products, 1.1 nm tobermorite and calcium silicate hydrated, contributed to the development of the sealer's compressive strength. Thus, the increasing pressure seems to suppress and control a growth rate of brucite crystal in response to a lower extension of expansion. Furthermore, all MgO-conlaining SSASC sealers possessed the water-catalyzed self-degradable properties.

  6. The Effect of Simulated Barium Carbonate Waste Stream on the Hydration of Composite Cement Systems

    E-Print Network [OSTI]

    Sheffield, University of

    The Effect of Simulated Barium Carbonate Waste Stream on the Hydration of Composite Cement Systems cements, comprised of ordinary Portland cement (OPC) and blast furnace slag (BFS), are used to encapsulate it is not uncommon for up to 90% of the OPC to be replaced by BFS, which will have significant effects

  7. The effect of BaCO3 on the hydration of OPC and composite cements

    E-Print Network [OSTI]

    Sheffield, University of

    The effect of BaCO3 on the hydration of OPC and composite cements Claire A. Utton* and Neil B of ordinary Portland cement (OPC) and up to 90% blast furnace slag (BFS), are used to encapsulate Intermediate. The effect of BaCO3 on the hydration properties of composite cements is being studied. This paper reports

  8. Virtual Cement and Concrete Testing Laboratory Educational Version 2.0 User Guide

    E-Print Network [OSTI]

    Magee, Joseph W.

    1 Virtual Cement and Concrete Testing Laboratory Educational Version 2.0 User Guide Jeffrey W of the Virtual Cement and Concrete Testing Laboratory (VCCTL) software, version 2.0. Using the VCCTL software, cement hydration, computer modeling, concrete testing, microstructure, simulation, virtual laboratory

  9. Analytical Plan for Roman Glasses

    SciTech Connect (OSTI)

    Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

    2011-01-01T23:59:59.000Z

    Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent “experiment” that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

  10. Sulfur dioxide oxidation and plume formation at cement kilns

    SciTech Connect (OSTI)

    Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

    1980-10-01T23:59:59.000Z

    Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

  11. Mixed polyanion glass cathodes: Iron phosphate vanadate glasses

    SciTech Connect (OSTI)

    Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

    2014-01-01T23:59:59.000Z

    Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

  12. Computational studies of two-phase cement-CO2-brine interaction in wellbore environments

    SciTech Connect (OSTI)

    Carey, James William [Los Alamos National Laboratory; Lichtner, Peter C [Los Alamos National Laboratory

    2009-01-01T23:59:59.000Z

    Wellbore integrity is essential to ensuring long-term isolation of buoyant supercritical CO{sub 2} during geologic sequestration of CO{sub 2}. In this report, we summarize recent progress in numerical simulations of cement-brine-CO{sub 2} interactions with respect to migration of CO{sub 2} outside of casing. Using typical values for the hydrologic properties of cement, caprock (shale) and reservoir materials, we show that the capillary properties of good quality cement will prevent flow of CO{sub 2} into and through cement. Rather, CO{sub 2}, if present, is likely to be confined to the casing-cement or cement-formation interfaces. CO{sub 2} does react with the cement by diffusion from the interface into the cement, in which case it produces distinct carbonation fronts within the cement. This is consistent with observations of cement performance at the CO{sub 2}-enhanced oil recovery SACROC Unit in West Texas (Carey et al. 2007). For poor quality cement, flow through cement may occur and would produce a pattern of uniform carbonation without reaction fronts. We also consider an alternative explanation for cement carbonation reactions as due to CO{sub 2} derived from caprock. We show that carbonation reactions in cement are limited to surficial reactions when CO{sub 2} pressure is low (< 10 bars) as might be expected in many caprock environments. For the case of caprock overlying natural CO{sub 2} reservoirs for millions of years, we consider Scherer and Huet's (2009) hypothesis of diffusive steady-state between CO{sub 2} in the reservoir and in the caprock. We find that in this case, the aqueous CO{sub 2} concentration would differ little from the reservoir and would be expected to produce carbonation reaction fronts in cements that are relatively uniform as a function of depth.

  13. NUCLEAR WASTE GLASSES CONTINUOUS MELTING AND BULK VITRIFICAITON

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR

    2008-03-24T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Nuclear wastes have a variety of components and composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee the glass can be easily made and resist environmental degradation. Glass formulation is facilitated by developing property-composition models, and the strategy of model development and application is reviewed. However, the large variability of waste compositions presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slow down the process; molten salts may accumulate in container refractory walls; the glass on cooling may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  14. Compositional threshold for Nuclear Waste Glass Durability

    SciTech Connect (OSTI)

    Kruger, Albert A. [Pacific Northwest National Lab., Richland, WA (United States); Farooqi, Rahmatullah [Pohang Univ. of Science and Technology, (Korea, Republic of); Hrma, Pavel R. [Pacific Northwest National Lab., Richland, WA (United States), Pohang Univ. of Science and Technology, (Korea, Republic of)

    2013-04-24T23:59:59.000Z

    Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

  15. Cement fatigue and HPHT well integrity with application to life of well prediction

    E-Print Network [OSTI]

    Ugwu, Ignatius Obinna

    2009-05-15T23:59:59.000Z

    to the cyclic loading and few data sets may not be sufficient to give an adequate description of cement behavior under fatigue loading. Studies were conducted by Kim and Kim 2 on the fatigue behavior of high strength concrete using a type I Portland cement....3: Comparison of Max Stress Levels to Number of Cycles for Different Cement Strengths [2] Antrim 3 conducted fatigue studies on hardened ordinary Portland (type I) cement paste using 2 specimens; one with a high-water cement ratio of 0.7 and another...

  16. Evaluation of water resources for enhanced oil recovery operations, Cement Field, Caddo and Grady Counties, Oklahoma

    SciTech Connect (OSTI)

    Preston, D.A.; Harrison, W.E.; Luza, K.V.; Prater, L.; Reddy, R.J.

    1982-02-01T23:59:59.000Z

    This report is based on the results of an investigation of the water resources local to the Cement Oil Field in Caddo and Grady Counties, southwestern, Oklahoma. The intent of the report is to present at least a semi-quantitative estimate of the volume, deliverability, and chemistry of the water potentially available for enhanced oil recovery in one or more Oklahoma oil fields. Subsequent to a review of several oil fields, the Cement Field was chosen for study because of its large size (25,000 acres), its extensive subsurface control (over 1850 wells), and its long history of production (since 1952) from several producing formations, some of which are already undergoing extensive waterflood operations. A preliminary review of the available data for this study suggested a threefold categorization of water resources, since the data for each category are distinctly different in nature, and, to some extent, different in source. The three categories are: surface water, ground water, and subsurface water. Flow, volume, and chemical analyses of each source are estimated.

  17. Westinghouse Cementation Facility of Solid Waste Treatment System - 13503

    SciTech Connect (OSTI)

    Jacobs, Torsten; Aign, Joerg [Westinghouse Electric Germany GmbH, Global Waste Management, Tarpenring 6, D- 22419 Hamburg (Germany)] [Westinghouse Electric Germany GmbH, Global Waste Management, Tarpenring 6, D- 22419 Hamburg (Germany)

    2013-07-01T23:59:59.000Z

    During NPP operation, several waste streams are generated, caused by different technical and physical processes. Besides others, liquid waste represents one of the major types of waste. Depending on national regulation for storage and disposal of radioactive waste, solidification can be one specific requirement. To accommodate the global request for waste treatment systems Westinghouse developed several specific treatment processes for the different types of waste. In the period of 2006 to 2008 Westinghouse awarded several contracts for the design and delivery of waste treatment systems related to the latest CPR-1000 nuclear power plants. One of these contracts contains the delivery of four Cementation Facilities for waste treatment, s.c. 'Follow on Cementations' dedicated to three locations, HongYanHe, NingDe and YangJiang, of new CPR-1000 nuclear power stations in the People's Republic of China. Previously, Westinghouse delivered a similar cementation facility to the CPR-1000 plant LingAo II, in Daya Bay, PR China. This plant already passed the hot functioning tests successfully in June 2012 and is now ready and released for regular operation. The 'Follow on plants' are designed to package three 'typical' kind of radioactive waste: evaporator concentrates, spent resins and filter cartridges. The purpose of this paper is to provide an overview on the Westinghouse experience to design and execution of cementation facilities. (authors)

  18. Development of Bulk Nanocrystalline Cemented Tungsten Carbide for Industrial Applicaitons

    SciTech Connect (OSTI)

    Z. Zak Fang, H. Y. Sohn

    2009-03-10T23:59:59.000Z

    This report contains detailed information of the research program entitled "Development of Bulk Nanocrystalline Cemented Tungsten Carbide Materials for Industrial Applications". The report include the processes that were developed for producing nanosized WC/Co composite powders, and an ultrahigh pressure rapid hot consolidation process for sintering of nanosized powders. The mechanical properties of consolidated materials using the nanosized powders are also reported.

  19. Automated Assessment of Polyethylene Wear in Cemented Acetabular Components using

    E-Print Network [OSTI]

    St Andrews, University of

    Automated Assessment of Polyethylene Wear in Cemented Acetabular Components using Anteroposterior, Ninewells Hospital, Dundee, DD1 9SY, UK Abstract Polyethylene wear in the acetabular components of hip to the polyethylene acetabular component of a prosthesis so that both it and the metal femoral head component can

  20. COMPOSITE PORTLAND CEMENT CONCRETE PAVEMENTS (Tollway) Effective: January 30, 2012

    E-Print Network [OSTI]

    COMPOSITE PORTLAND CEMENT CONCRETE PAVEMENTS (Tollway) Effective: January 30, 2012 Revised: May 8 for special applications to composite pavements as shown and described on the Drawings and in this Special as required; 5. Constructing the composite pavement on a prepared subgrade, or subbase, without forms. 6

  1. Leaching induced concentration profiles in the solid phase of cement

    SciTech Connect (OSTI)

    Fuhrmann, M.; Colombo, P.

    1987-04-01T23:59:59.000Z

    Analysis of the solid phase of portland cement specimens by energy dispersive x-ray spectrometry before and after leaching provided elemental profiles within the cement. Releases of potassium were calculated from the solid phase profiles and were compared to releases determined from leachate analyses of potassium and cesium-137. The fraction of potassium released in the leachate was found to correlate closely to that of cesium-137 under varying time and temperature conditions, despite the different manner in which each was originally contained in the cement. Agreement was obtained among potassium releases as determined from the solid, potassium in the leachate and cesium-137 in the leachate. These correlations allowed the use of potassium as an analog for cesium-137 in cement. Profiles of potassium in the solid showed varying degrees of depletion. A specimen, sectioned immediately after leaching for 471 days, showed complete removal of potassium to 9 mm depth from the specimens surface. From 9 mm to the center of the specimen, an apparently linear increase in concentration was observed. Specimens that had been air dried prior to sectioning had profiles that were produced by evaporative transport of dissolved species toward the surface. Carbonation of the surface appears to have retarded migration of the dissolved material. This prevented it from reaching the outer edge and resulted in increased potassium concentrations several mm inside the surface. 9 refs., 10 figs., 2 tabs.

  2. Surface effects of cement-based solidified waste forms

    E-Print Network [OSTI]

    Pavlonnis, George

    1998-01-01T23:59:59.000Z

    This study was performed in order to determine-nine if the surface characteristics of cement-based waste forms were different than those of the bulk material. This was done as a prelude to the potential development of an accelerated leach test...

  3. Regional distribution of diagenetic carbonate cement in Palaeocene deepwater

    E-Print Network [OSTI]

    Haszeldine, Stuart

    0QF, UK (Received 9 June 1998; revised 15 March 1999) ABSTRACT: Sandstones of the Palaeocene al., 1993), and by inorganic thermal breakdown of organic material at depths >1.5 km (Irwin et al., 1977). Within the Rannoch Formation of the Brent Group, sandstones contain >5% carbonate cement

  4. Contact Mechanics Based Mechanical Characterization of Portland Cement Paste

    E-Print Network [OSTI]

    Jones, Christopher

    2012-02-14T23:59:59.000Z

    that the calcium silicate hydrate (C-S-H) phase of hydrated portland cement has different properties on the nanometric scale than on the micron scale. Packing density of C-S-H particles is proposed as an explanation for the disparity in the measured results...

  5. More durable roof coverings such as steel and fiber cement

    E-Print Network [OSTI]

    - heating equipment saves money. Tankless water heaters provide hot water on demand at a preset temperature- cement siding is termite- and water-resistant and warrantied to last 50 years. Increasing the amount natural daylighting. Xeriscaping, or using native plants, significantly reduces the need for watering

  6. Glass rupture disk

    DOE Patents [OSTI]

    Glass, S. Jill (Albuquerque, NM); Nicolaysen, Scott D. (Albuquerque, NM); Beauchamp, Edwin K. (Albuquerque, NM)

    2002-01-01T23:59:59.000Z

    A frangible rupture disk and mounting apparatus for use in blocking fluid flow, generally in a fluid conducting conduit such as a well casing, a well tubing string or other conduits within subterranean boreholes. The disk can also be utilized in above-surface pipes or tanks where temporary and controllable fluid blockage is required. The frangible rupture disk is made from a pre-stressed glass with controllable rupture properties wherein the strength distribution has a standard deviation less than approximately 5% from the mean strength. The frangible rupture disk has controllable operating pressures and rupture pressures.

  7. Glass | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdf Flash2006-53.pdf0.pdfCostAnalysis GeothermalEnergy GeothermalGetGlass and

  8. SYNCHROTRON X-RAY MICROTOMOGRAPHY, ELECTRON PROBE MICROANALYSIS, AND NMR OF TOLUENE WASTE IN CEMENT.

    SciTech Connect (OSTI)

    BUTLER,L.G.

    1999-07-22T23:59:59.000Z

    Synchrotron X-ray microtomography shows vesicular structures for toluene/cement mixtures, prepared with 1.22 to 3.58 wt% toluene. Three-dimensional imaging of the cured samples shows spherical vesicles, with diameters ranging from 20 to 250 {micro}m; a search with EPMA for vesicles in the range of 1-20 {micro}m proved negative. However, the total vesicle volume, as computed from the microtomography images, accounts for less than 10% of initial toluene. Since the cements were cured in sealed bottles, the larger portion of toluene must be dispersed within the cement matrix. Evidence for toluene in the cement matrix comes from {sup 29}Si MAS NMR spectroscopy, which shows a reduction in chain silicates with added toluene. Also, {sup 2}H NMR of d{sub 8}-toluene/cement samples shows high mobility for all, toluene and thus no toluene/cement binding. A model that accounts for all observations follows: For loadings below about 3 wt%, most toluene is dispersed in the cement matrix, with a small fraction of the initial toluene phase separating from the cement paste and forming vesicular structures that are preserved in the cured cement. Furthermore, at loadings above 3 wt%, the abundance of vesicles formed during toluene/cement paste mixing leads to macroscopic phase separation (most toluene floats to the surface of the cement paste).

  9. Aspects of the mechanics of metallic glasses

    E-Print Network [OSTI]

    Henann, David Lee

    2011-01-01T23:59:59.000Z

    Metallic glasses are amorphous materials that possess unique mechanical properties, such as high tensile strengths and good fracture toughnesses. Also, since they are amorphous, metallic glasses exhibit a glass transition, ...

  10. Ghabezloo et al.: Poromechanical behaviour of hardened cement paste under isotropic loading Poromechanical behaviour of hardened cement paste

    E-Print Network [OSTI]

    Boyer, Edmond

    of the material is described in the framework of the mechanics of porous media. The poroelastic parameters the framework of the theory of porous media. Keywords: hardened cement paste, poromechanics, effective stress and Concrete Research, DOI 10.1016/j.cemconres.2008.06.007 * Corresponding Author : CERMES, Ecole Nationale des

  11. HIGH ALUMINUM HLW (HIGH LEVEL WASTE ) GLASSES FOR HANFORDS WTP (WASTE TREATMENT PROJECT)

    SciTech Connect (OSTI)

    KRUGER AA; BOWAN BW; JOSEPH I; GAN H; KOT WK; MATLACK KS; PEGG IL

    2010-01-04T23:59:59.000Z

    This paper presents the results of glass formulation development and melter testing to identify high waste loading glasses to treat high-Al high level waste (HLW) at Hanford. Previous glass formulations developed for this HLW had high waste loadings but their processing rates were lower that desired. The present work was aimed at improving the glass processing rate while maintaining high waste loadings. Glass formulations were designed, prepared at crucible-scale and characterized to determine their properties relevant to processing and product quality. Glass formulations that met these requirements were screened for melt rates using small-scale tests. The small-scale melt rate screening included vertical gradient furnace (VGF) and direct feed consumption (DFC) melter tests. Based on the results of these tests, modified glass formulations were developed and selected for larger scale melter tests to determine their processing rate. Melter tests were conducted on the DuraMelter 100 (DMIOO) with a melt surface area of 0.11 m{sup 2} and the DuraMelter 1200 (DMI200) HLW Pilot Melter with a melt surface area of 1.2 m{sup 2}. The newly developed glass formulations had waste loadings as high as 50 wt%, with corresponding Al{sub 2}O{sub 3} concentration in the glass of 26.63 wt%. The new glass formulations showed glass production rates as high as 1900 kg/(m{sup 2}.day) under nominal melter operating conditions. The demonstrated glass production rates are much higher than the current requirement of 800 kg/(m{sup 2}.day) and anticipated future enhanced Hanford Tank Waste Treatment and Immobilization Plant (WTP) requirement of 1000 kg/(m{sup 2}.day).

  12. Effect of glass composition on waste form durability: A critical review

    SciTech Connect (OSTI)

    Ellison, A.J.G.; Mazer, J.J.; Ebert, W.L. [Argonne National Lab., IL (United States). Chemical Technology Div.

    1994-11-01T23:59:59.000Z

    This report reviews literature concerning the relationship between the composition and durability of silicate glasses, particularly glasses proposed for immobilization of radioactive waste. Standard procedures used to perform durability tests are reviewed. It is shown that tests in which a low-surface area sample is brought into contact with a very large volume of solution provide the most accurate measure of the intrinsic durability of a glass composition, whereas high-surface area/low-solution volume tests are a better measure of the response of a glass to changes in solution chemistry induced by a buildup of glass corrosion products. The structural chemistry of silicate and borosilicate glasses is reviewed to identify those components with the strongest cation-anion bonds. A number of examples are discussed in which two or more cations engage in mutual bonding interactions that result in minima or maxima in the rheologic and thermodynamic properties of the glasses at or near particular optimal compositions. It is shown that in simple glass-forming systems such interactions generally enhance the durability of glasses. Moreover, it is shown that experimental results obtained for simple systems can be used to account for durability rankings of much more complex waste glass compositions. Models that purport to predict the rate of corrosion of glasses in short-term durability tests are evaluated using a database of short-term durability test results for a large set of glass compositions. The predictions of these models correlate with the measured durabilities of the glasses when considered in large groupings, but no model evaluated in this review provides accurate estimates of durability for individual glass compositions. Use of these models in long-term durability models is discussed. 230 refs.

  13. Covered Product Category: Commercial Refrigerators and Freezers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Beer-dispensing and direct draw units Glass frosters Deep well and bunker freezers. Open-air units, deli cases, prep tables, drawer cabinets, laboratory-grade products,...

  14. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne (Aiken, SC); Pickett, John Butler (Aiken, SC); Brown, Kevin George (Augusta, GA); Edwards, Thomas Barry (Aiken, SC)

    1998-01-01T23:59:59.000Z

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  15. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08T23:59:59.000Z

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  16. Laboratory Waste Disposal HAZARDOUS GLASS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    of in normal trash containers. Pasteur pipettes Other pipettes and tips (glass or plastic) Slides and cover bodies (without needles) Container: Sturdy and leakproof with Hazardous Glass label. Either: Plastic resistant, leakproof plastic carboy with green sharps label. Do not fill these containers completely. Leave

  17. Refractory Glass Seals for SOFC

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.

    2011-07-01T23:59:59.000Z

    One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

  18. Glass science tutorial: Lecture No. 7, Waste glass technology for Hanford

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-07-01T23:59:59.000Z

    This paper presents the details of the waste glass tutorial session that was held to promote knowledge of waste glass technology and how this can be used at the Hanford Reservation. Topics discussed include: glass properties; statistical approach to glass development; processing properties of nuclear waste glass; glass composition and the effects of composition on durability; model comparisons of free energy of hydration; LLW glass structure; glass crystallization; amorphous phase separation; corrosion of refractories and electrodes in waste glass melters; and glass formulation for maximum waste loading.

  19. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    glass, adding ions to impart specific properties, enables them to manage the degradation rate of the glass, creating attractive and compliant scaffold materials. A variety...

  20. Development of a process control sensor for the glass industry

    SciTech Connect (OSTI)

    Gardner, M.; Candee, A.; Kramlich, J.; Koppang, R.

    1991-05-01T23:59:59.000Z

    This project was initiated to fill a need in the glass industry for a non-contact temperature sensor for glass melts. At present, the glass forming industry (e.g., bottle manufacture) consumes significant amounts of energy. Careful control of temperature at the point the bottle is molded is necessary to prevent the bottle from being rejected as out-of-specification. In general, the entire glass melting and conditioning process is designed to minimize this rejection rate, maximize throughput and thus control energy and production costs. This program focuses on the design, development and testing of an advanced optically based pyrometer for glass melts. The pyrometer operates simultaneously at four wavelengths; through analytical treatment of the signals, internal temperature profiles within the glass melt can be resolved. A novel multiplexer alloys optical signals from a large number of fiber-optic sensors to be collected and resolved by a single detector at a location remote from the process. This results in a significant cost savings on a per measurement point basis. The development program is divided into two phases. Phase 1 involves the construction of a breadboard version on the instrument and its testing on a pilot-scale furnace. In Phase 2, a prototype analyzer will be constructed and tested on a commercial forehearth. This report covers the Phase 1 activities.

  1. IMPACT OF URANIUM AND THORIUM ON HIGH TIO2 CONCENTRATION NUCLEAR WASTE GLASSES

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2012-01-11T23:59:59.000Z

    This study focused on the potential impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. All but one of the study glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which is typically found in DWPF-type glasses and had no practical impact on the durability of the glass. The measured Product Consistency Test (PCT) responses for the study glasses and the viscosities of the glasses were well predicted by the current DWPF models. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components.

  2. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, C.M.

    1992-04-07T23:59:59.000Z

    A method is described for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a non-bridging oxygen' term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term. 4 figs.

  3. Americium/curium extraction from a lanthanide borosilciate glass

    SciTech Connect (OSTI)

    Rudisill, T.S.; Pareizs, J.M.; Ramsey, W.G.

    1996-12-31T23:59:59.000Z

    A solution containing kilogram quantities of highly radioactive isotopes of americium and curium (Am/Cm) and lanthanide fission products is currently stored in a process tank at the Department of Energy`s Savannah River Site (SRS). This tank and its vital support systems are old, subject to deterioration, and prone to possible leakage. For this reason, a program has been initiated to immobilize this material as a lanthanide borosilicate glass for safe long-term storage. The Am/Cm has commercial value and is desired for use by the heavy isotope programs at the Oak Ridge National Laboratory (ORNL). Therefore, a flowsheet was demonstrated using a curium-containing glass to extract these elements from the glass matrix. The method involved grinding the glass to less than 200 mesh and dissolving in concentrated nitric acid at 110{degrees}C. Under these conditions, the dissolution was essentially 100% after 2 hours except for silicon which remained mostly insoluble. Since the actual process conditions at ORNL could not be exactly simulated, the dissolution rate of a surrogate glass was measured using static and agitated conditions to bracket the expected rate. The measured rates, 0.040 to 0.0082 grams/hour-centimeter, were constant which allowed development of a predictive model for the time required to dissolve a glass particle of spherical geometry in terms of the glass density, particle size, and experimentally measured rate. The calculated time required to dissolve an idealized curium glass particle was in agreement with the experimental observation that dissolution was complete in less than 2 hours.

  4. A Coupled Nanoindentation/SEM-EDS Study on Low Water/Cement Ratio Portland Cement Paste: Evidence for C-S-H/Ca(OH)[subscript 2] Nanocomposites

    E-Print Network [OSTI]

    Chen, Jeffrey J.

    A low water/cement ratio (w/c=0.20) hydrated Portland cement paste was analyzed by grid-indentation coupled with ex situ scanning electron microscope-energy-dispersive X-ray spectra (SEM-EDS) analysis at each indentation ...

  5. Memo, "Incorporation of HLW Glass Shell V2.0 into the Flowsheets," to ED Lee, CCN: 184905, October 20, 2009

    SciTech Connect (OSTI)

    Gimpel, Rodney F.; Kruger, Albert A.

    2013-12-18T23:59:59.000Z

    Efforts are being made to increase the efficiency and decrease the cost of vitrifying radioactive waste stored in tanks at the U.S. Department of Energy Hanford Site. The compositions of acceptable and processable high-level waste (HL W) glasses need to be optimized to minimize the waste-form volume and, hence, to reduce cost. A database of glass properties of waste glass and associated simulated waste glasses was collected and documented in PNNL 18501, Glass Property Data and Models for Estimating High-Level Waste Glass Volume and glass property models were curve-fitted to the glass compositions. A routine was developed that estimates HL W glass volumes using the following glass property models: II Nepheline, II One-Percent Crystal Temperature (T1%), II Viscosity (11) II Product Consistency Tests (PCT) for boron, sodium, and lithium, and II Liquidus Temperature (TL). The routine, commonly called the HL W Glass Shell, is presented in this document. In addition to the use of the glass property models, glass composition constraints and rules, as recommend in PNNL 18501 and in other documents (as referenced in this report) were incorporated. This new version of the HL W Glass Shell should generally estimate higher waste loading in the HL W glass than previous versions.

  6. Evaluation Of Glass Density To Support The Estimation Of Fissile Mass Loadings From Iron Concentrations In SB8 Glasses

    SciTech Connect (OSTI)

    Edwards, T. B.; Peeler, D. K.; Kot, W. K.; Gan, H.; Pegg, I. L.

    2013-04-30T23:59:59.000Z

    The Department of Energy – Savannah River (DOE-SR) has provided direction to Savannah River Remediation (SRR) to maintain fissile concentration in glass below 897 g/m{sup 3}. In support of that guidance, the Savannah River National Laboratory (SRNL) provided a technical basis and a supporting Microsoft® Excel® spreadsheet for the evaluation of fissile loading in Sludge Batch 5 (SB5), Sludge Batch 6 (SB6), Sludge Batch 7a (SB7a), and Sludge Batch 7b (SB7b) glass based on the iron (Fe) concentration in glass as determined by the measurements from the Slurry Mix Evaporator (SME) acceptability analysis. SRR has since requested that the necessary density information be provided to allow SRR to update the Excel® spreadsheet so that it may be used to maintain fissile concentration in glass below 897 g/m{sup 3} during the processing of Sludge Batch 8 (SB8). One of the primary inputs into the fissile loading spreadsheet includes an upper bound for the density of SB8-based glasses. Thus, these bounding density values are to be used to assess the fissile concentration in this glass system. It should be noted that no changes are needed to the underlying structure of the Excel-based spreadsheet to support fissile assessments for SB8. However, SRR should update the other key inputs to the spreadsheet that are based on fissile and Fe concentrations reported from the SB8 Waste Acceptance Product Specification (WAPS) sample.

  7. Fracture mechanics of cellular glass

    SciTech Connect (OSTI)

    Zwissler, J.G.; Adams, M.A.

    1981-02-01T23:59:59.000Z

    Cellular glasses are prime candidate materials for the structural substrate of mirrored glass for solar concentrator reflecting panels. These materials are brittle, however, and susceptible to mechanical failure from slow crack growth caused by a stress corrosion mechanism. The results are detailed of one part of a program established to develop improved cellular glasses and to characterize the behavior of these and commercially available materials. Commercial and developmental cellular glasses were tested and analyzed using standard testing techniques and models developed from linear fracture mechanics. Two models describing the fracture behavior of these materials are developed. Slow crack growth behavior in cellular glass was found to be more complex than that encountered in dense glasses or ceramics. The crack velocity was found to be strongly dependent upon water vapor transport to the tip of the moving crack. The existence of a static fatigue limit was not conclusively established, however, it is speculated that slow crack growth behavior in Region I may be slower, by orders of magnitude, than that found in dense glasses.

  8. Research Needs: Glass Solar Reflectance and Vinyl Siding

    E-Print Network [OSTI]

    .S. for residential buildings. To meet IECC's U-factor and solar heat gain coefficient (SHGC) requirements insulatingLBNL-5022E Research Needs: Glass Solar Reflectance and Vinyl Siding Authors: R. Hart*, C. Curcija of any information, apparatus, product, or process disclosed, or represents that its use would

  9. Energy Efficiency Improvement and Cost Saving Opportunities for the Glass Industry. An ENERGY STAR Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    AlChalabi et al. 1995). Praxair has developed a WideFlame™variations in product. Praxair, Inc. also developed an oxy-even reduced product quality. Praxair and Heye Glass have

  10. Numerical investigation of electric heating impacts on solid/liquid glass flow patterns.

    SciTech Connect (OSTI)

    Chang, S. L.; Zhou, C. Q.; Golchert, B.

    2002-07-02T23:59:59.000Z

    A typical glass furnace consists of a combustion space and a melter. Intense heat is generated from the combustion of fuel and air/oxygen in the combustion space. This heat is transferred mainly by radiation to the melter in order to melt sand and cullet (scrap glass) eventually creating glass products. Many furnaces use electric boosters to enhance glass melting and increase productivity. The coupled electric/combustion heat transfer patterns are key to the glass making processes. The understanding of the processes can lead to the improvement of glass quality and furnace efficiency. The effects of electrical boosting on the flow patterns and heat transfer in a glass melter are investigated using a multiphase Computational Fluid Dynamics (CFD) code with addition of an electrical boosting model. The results indicate that the locations and spacing of the electrodes have large impacts on the velocity and temperature distributions in the glass melter. With the same total heat input, the batch shape (which is determined by the overall heat transfer and the batch melting rate) is kept almost the same. This indicates that electric boosting can be used to replace part of heat by combustion. Therefore, temperature is lower in the combustion space and the life of the furnace can be prolonged. The electric booster can also be used to increase productivity without increasing the furnace size.

  11. Scanning probe microscopy: Sulfate minerals in scales and cements

    SciTech Connect (OSTI)

    Hall, C. [Schlumberger Cambridge Research (United Kingdom)

    1995-11-01T23:59:59.000Z

    The principles of scanning probe microscopy (SPM) are illustrated with examples from oilfield mineralogy, particularly emphasizing sulfate minerals involved in scale formation and cement hydration chemistry. The topography of the (010) cleavage surface of gypsum observed by atomic force microscopy shows atomically flat terraces separated by shallow steps often only one unit cell high. SPM allows direct observation of processes on mineral surfaces while they are in contact with solutions. The dissolution etching and crystal growth of gypsum and barite are discussed and rates of step migration estimated. The orientation of steps is related to the crystallographic axes. The action of phosphonate crystal growth inhibitor on gypsum and of a chelating scale solvent on barite are also shown. The multiphase microstructure of an oilwell cement clinker is described in relation to its hydration chemistry in contact with water and its reaction with sulfate ions.

  12. Sulfate Fining Chemistry in Oxidized and Reduced Soda-Lime-Silica Glasses

    SciTech Connect (OSTI)

    Matyas, Josef; Hrma, Pavel R.

    2005-05-13T23:59:59.000Z

    Various reducing agents were used and their additions were varied to (1) increase glass quality through eliminating defects from silica scum, (2) decrease SOx emissions through changing the kind and quantity of reducing agents, and (3) improve production efficiency through increased flexibility of glass redox control during continuous processing. The work included measuring silica sand dissolution and sulfate decomposition in melts from glass batches. Glass batches were heated at a temperature-increase rate deemed similar to that experienced in the melting furnace. The sulfate decomposition kinetics was investigated with thermogravimetric analysis-differential thermal analysis and evolved gas analysis. Sulfur concentrations in glasses quenched at different temperatures were determined using X-ray fluorescence spectroscopy. The distribution of residual sand (that which was not dissolved during the initial batch reactions) in the glass was obtained as a function of temperature with optical microscopy in thin-sections of melts. The fraction of undissolved sand was measured with X-ray diffraction. The results of the present study helped Visteon Inc. reduce the energy consumption and establish the batch containing 0.118 mass% of graphite as the best candidate for Visteon glass production. The improved glass batch has a lower potential for silica scum formation and for brown fault occurrence in the final glass product. It was established that bubbles trapped in the melt even at 1450 C have a high probability to be refined when reaching the hot zone in the glass furnace. Furthermore, silica sand does not accumulate at the glass surface and dissolves faster in the batch with graphite than in the batch with carbocite.

  13. Extension and replacement of aspalt cement with sulphur

    E-Print Network [OSTI]

    Pickett, Daniel Ernest

    1977-01-01T23:59:59.000Z

    material containing bitumen, sulphur, and mineral matter such as sand, rock, road metal and clinker (41). He recommended preparing the mixture in hot mix plants, and completely filling the voids between aggregate particles with sulphur-asphalt binder... Selection . Aggregate Selection Selection of Asphalt Cement and Sulphur Content 10 13 20 23 23 26 27 28 28 28 33 44 PAGE Selection of Moisture Condition and Compaction Effort . 45 Processing of Sulphur-Asphalt Emulsion (SAE) Binders...

  14. Polymer-cement geothermal-well-completion materials. Final report

    SciTech Connect (OSTI)

    Zeldin, A.N.; Kukacka, L.E.

    1980-07-01T23:59:59.000Z

    A program to develop high-temperature polymer cements was performed. Several formulations based on organic and semi-inorganic binders were evaluated on the basis of mechanical and thermal stability, and thickening time. Two optimized systems exhibited properties exceeding those required for use in geothermal wells. Both systems were selected for continued evaluation at the National Bureau of Standards and contingent upon the results, for field testing in geothermal wells.

  15. Testing of Large-Scale ICV Glasses with Hanford LAW Simulant

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kim, Dong-Sang; Vienna, John D.; Matyas, Josef; Smith, Donald E.; Schweiger, Michael J.; Yeager, John D.

    2005-03-01T23:59:59.000Z

    Preliminary glass compositions for immobilizing Hanford low-activity waste (LAW) by the in-container vitrification (ICV) process were initially fabricated at crucible- and engineering-scale, including simulants and actual (radioactive) LAW. Glasses were characterized for vapor hydration test (VHT) and product consistency test (PCT) responses and crystallinity (both quenched and slow-cooled samples). Selected glasses were tested for toxicity characteristic leach procedure (TCLP) responses, viscosity, and electrical conductivity. This testing showed that glasses with LAW loading of 20 mass% can be made readily and meet all product constraints by a far margin. Glasses with over 22 mass% Na2O can be made to meet all other product quality and process constraints. Large-scale testing was performed at the AMEC, Geomelt Division facility in Richland. Three tests were conducted using simulated LAW with increasing loadings of 12, 17, and 20 mass% Na2O. Glass samples were taken from the test products in a manner to represent the full expected range of product performance. These samples were characterized for composition, density, crystalline and non-crystalline phase assemblage, and durability using the VHT, PCT, and TCLP tests. The results, presented in this report, show that the AMEC ICV product with meets all waste form requirements with a large margin. These results provide strong evidence that the Hanford LAW can be successfully vitrified by the ICV technology and can meet all the constraints related to product quality. The economic feasibility of the ICV technology can be further enhanced by subsequent optimization.

  16. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Allan, Shawn M.

    2012-02-27T23:59:59.000Z

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination identifying castable molds for

  17. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Allan, Shawn M.; Baranova, Inessa; Poley, Joseph; Reis, Henrique

    2012-02-27T23:59:59.000Z

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 ���°C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination id

  18. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    dioxide (CO2) emissions from fossil fuel combustion, as wellCO2 emissions (including cement process and fossil fuel combustion

  19. Microsoft Word - NETL-TRS-2-2013_Foamed Cement_20140124.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ultimately, this research will provide industry the knowledge to ensure long-term well integrity and safe operation of wells in which foamed cements are used. Computed...

  20. E-Print Network 3.0 - ash blended cement Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CLSM mixture utilized... . CHARACTERIZATION AND APPLICATION OF CLASS F FLY ASH AND CLEAN-COAL ASH FOR CEMENT-BASED MATERIALS 2 The major... investigation. Two additional ash ......

  1. Policy Options for Encouraging Energy Efficiency Best Practices in Shandong Province's Cement Industry

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01T23:59:59.000Z

    Azure. Alternative Fuel Use in the Cement Sector in ShandongAlternative fuels ..6 Resource potential for alternative fuel use in Shandong

  2. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    Sustainable Development waste heat recovery World Wide FundTaishan Cement Works Waste Heat Recovery and Utilisation forPlant’s Low Temperature Waste Heat Power Generation Project.

  3. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    report of cement industry waste heat power generation. ChinaWorrell et al. , 2001). Waste heat recovery (WHR) poweradoption and utilization of waste heat recovery (WHR) power

  4. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    Banerjee, R. , 2005. Energy Efficiency and Demand SideKiln Systems,” Energy Efficiency in the Cement Industry (Ed.for Improving Energy Efficiency, Reducing Pollution and

  5. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    of Demonstrated Energy Technologies (CADDET), Internationaland MAIN. 1993. Energy Technology in the Cement IndustrialAugust 19, 2009. Energy Technology Support Unit (ETSU).

  6. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15T23:59:59.000Z

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  7. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27T23:59:59.000Z

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. In addition, all of the blends may require consideration for their handling. A number of engineering considerations and recommendations were prepared based on the experimental findings, experience, and other process considerations. Recommendations for future testing are included. In conjunction with future work, it is recommended that a professional consultant be engaged to guide and assist with testing and design input.

  8. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27T23:59:59.000Z

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. The problems might include arching or ratholing in the silo/hopper. In addition, all of the blends may require consideration for their handling.

  9. Thermally efficient melting for glass making

    DOE Patents [OSTI]

    Chen, Michael S. K. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary (Trexlertown, PA); Winchester, David C. (Allentown, PA)

    1991-01-01T23:59:59.000Z

    The present invention is an integrated process for the production of glass utilizing combustion heat to melt glassmaking materials in a glassmaking furnace. The fuel combusted to produce heat sufficient to melt the glassmaking materials is combusted with oxygen-enriched oxidant to reduce heat losses from the offgas of the glassmaking furnace. The process further reduces heat losses by quenching hot offgas from the glassmaking furnace with a process stream to retain the heat recovered from quench in the glassmaking process with subsequent additional heat recovery by heat exchange of the fuel to the glassmaking furnace, as well as the glassmaking materials, such as batch and cullet. The process includes recovery of a commercially pure carbon dioxide product by separatory means from the cooled, residual offgas from the glassmaking furnace.

  10. Preliminary Simulation of the Corrosion Rate of Archaeological Glass

    SciTech Connect (OSTI)

    Steefel, Carl

    2014-01-06T23:59:59.000Z

    In this study, we make use of a micro-continuum modeling approach (the Kinetic-Microscopic-Continuum Model or K{micro}C model) to capture the spatial distribution and identity of reaction products developing over time as a result of the archaeological glass corrosion, while also matching the time scales of alteration where possible. Since the glass blocks sat on the Mediterranean seafloor for 1800 years, the physical and chemical boundary conditions are largely constant. We focus on a fracture within the glass block identified by Verney-Carron et al. (2008) and simulate it as a 1D system, with a fixed concentration (Dirichlet) boundary corresponding to the interior of the fracture.

  11. Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic Sequestration Conditions Using X?ray Computed Microtomography

    SciTech Connect (OSTI)

    Jung, Hun Bok; Jansik, Danielle P.; Um, Wooyong

    2013-01-01T23:59:59.000Z

    ABSTRACT: X-ray microtomography (XMT), a nondestructive three-dimensional imaging technique, was applied to demonstrate its capability to visualize the mineralogical alteration and microstructure changes in hydrated Portland cement exposed to carbon dioxide under geologic sequestration conditions. Steel coupons and basalt fragments were added to the cement paste in order to simulate cement-steel and cement-rock interfaces. XMT image analysis showed the changes of material density and porosity in the degradation front (density: 1.98 g/cm3, porosity: 40%) and the carbonated zone (density: 2.27 g/cm3, porosity: 23%) after reaction with CO2- saturated water for 5 months compared to unaltered cement (density: 2.15 g/cm3, porosity: 30%). Three-dimensional XMT imaging was capable of displaying spatially heterogeneous alteration in cement pores, calcium carbonate precipitation in cement cracks, and preferential cement alteration along the cement-steel and cement-rock interfaces. This result also indicates that the interface between cement and host rock or steel casing is likely more vulnerable to a CO2 attack than the cement matrix in a wellbore environment. It is shown here that XMT imaging can potentially provide a new insight into the physical and chemical degradation of wellbore cement by CO2 leakage.

  12. Geologic origin of magnetic volcanic glasses in the KBS tuff

    SciTech Connect (OSTI)

    Schlinger, C.M.; Smith, R.M.; Veblen, D.R.

    1986-11-01T23:59:59.000Z

    Volcanic glass shards and banded pumice from the KBS tuff of northern Kenya exhibit marked variations in magnetic susceptibility and color (colorless to dark brown). The darker glass shards exhibit superparamagnetism, which they now know to be carried by a population of tiny microcrystals of Fe-rich cubic oxide, approx. 20 to approx. 100 A in size, thought to be magnetite. A theory for their origin is one of nucleation and growth (precipitation) in quenched homogeneous glass (colorless) at temperatures of approx. 700-1000/sup 0/C during and immediately subsequent to eruption. Results from high-temperature heating experiments on KBS shards support this idea. The precipitate appears in the KBS shards as a consequence of their cooling history and is the origin of their coloring; the origin cannot lie in negligible compositional differences between the colorless and darkest shards. On the other hand, banded pumice from the KBS tuff has both dark and colorless glasses of differing compositions. The pumice appears banded because precipitation occurred preferentially in the Fe-rich glass. Although magma mixing may have played a role in the eruption of these materials, on the basis of their survey of distal eruptive products, it would appear that the volumetric amount of the mafic end member (dark pumice) was insubstantial.

  13. Multi-criteria analysis of the mechanism of degradation of Portland cement based mortars exposed to external sulphate attack

    SciTech Connect (OSTI)

    El-Hachem, R.; Roziere, E.; Grondin, F.; Loukili, A., E-mail: ahmed.loukili@ec-nantes.fr

    2012-10-15T23:59:59.000Z

    This work aims to contribute to the design of durable concrete structures exposed to external sulphate attacks (ESA). Following a preliminary study aimed at designing a representative test, the present paper suggests a study on the effect of the water-to-cement (w/c) ratio and the cement composition in order to understand the degradation mechanisms. Length and mass measurements were registered continuously, leached calcium and hydroxide ions were also quantified. In parallel, scanning electron microscopy observations as well as X-ray microtomography were realised at different times to identify the formed products and the crack morphology. Test results provide information on the basic aspects of the degradation mechanism, such as the main role of leaching and diffusion in the sulphate attack process. The mortar composition with a low w/c ratio leads to a better resistance to sulphate attack because the microstructure is less permeable. Reducing the C{sub 3}A content results in a macro-cracking decrease but it does not prevent expansion, which suggests the contribution of other expansive products, such as gypsum, in damage due to ESA. The observation of the cracks network in the microstructure helps to understand the micro-mechanisms of the degradation process.

  14. Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01T23:59:59.000Z

    B. , 1990. “Utilisation of Waste Heat from the Cement RotaryAdvanced Concepts of Waste Heat Recovery in Cement Plants”a roller mill. Utilizing waste heat from the kiln exhaust,

  15. HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses

    SciTech Connect (OSTI)

    Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

    2012-04-02T23:59:59.000Z

    In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Matyáš et al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

  16. Sulfur polymer cement for macroencapsulation of mixed waste debris

    SciTech Connect (OSTI)

    Mattus, C.H.

    1998-06-01T23:59:59.000Z

    In FY 1997, the US DOE Mixed Waste Focus Area (MWFA) sponsored a demonstration of the macroencapsulation of mixed waste debris using sulfur polymer cement (SPC). Two mixed wastes were tested--a D006 waste comprised of sheets of cadmium and a D008/D009 waste comprised of lead pipes and joints contaminated with mercury. The demonstration was successful in rendering these wastes compliant with Land Disposal Restrictions (LDR), thereby eliminating one Mixed Waste Inventory Report (MWIR) waste stream from the national inventory.

  17. Corrosion of Metals in Composite Cements Anthony Setiadi*, J. Hill and N. B. Milestone

    E-Print Network [OSTI]

    Sheffield, University of

    Corrosion of Metals in Composite Cements Anthony Setiadi*, J. Hill and N. B. Milestone. However, there may be issues regarding the corrosion of some of the metal components which arise from reprocessing and decommissioning due to the alkaline environment in the cement grouts. The corrosion

  18. Speciation of heavy metals in cement-stabilized waste forms: A micro-spectroscopic study

    E-Print Network [OSTI]

    -ray fluorescence (XRF)) were used to investigate Co and Ni uptake by Hardened Cement Paste (HCP) with the aim. For Ni and Co, XRF mapping revealed a highly heterogeneous element distribution as far Elsevier B.V. All rights reserved. Keywords: Cement; Micro-XAS; Micro-XRF mapping; Ni; Co 1. Introduction

  19. Carbon 39 (2001) 19952001 Silane-treated carbon fiber for reinforcing cement

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    Carbon 39 (2001) 1995­2001 Silane-treated carbon fiber for reinforcing cement *Yunsheng Xu, D-treated carbon fibers and silane-treated silica fume, relative to the values for cement paste with as-received carbon fibers and as-received silica fume. Silane treatment of fibers and silica fume contributed about

  20. The Effect of Cement Mechanical Properties and Reservoir Compaction on HPHT Well Integrity

    E-Print Network [OSTI]

    Yuan, Zhaoguang

    2012-11-15T23:59:59.000Z

    Cement high- cycle fatigue failure constant B Cement high -cycle fatigue failure constant C Rock internal strength, psi Cr Volumetric solid...-grain compressibility, psi-1 Cbc Volumetric bulk-volume compressibility, psi-1 E Young?s modulus, psi F Critical force, lbf G...

  1. Using artificial neural networks to predict the quality and performance of oilfield cements

    SciTech Connect (OSTI)

    Coveney, P.V.; Hughes, T.L. [Schlumberger Cambridge Research Ltd., Cambridge (United Kingdom); Fletcher, P. [Schlumberger Dowell, Skene, Aberdeen (United Kingdom)

    1996-12-31T23:59:59.000Z

    Inherent batch to batch variability, ageing and contamination are major factors contributing to variability in oilfield cement slurry performance. Of particular concern are problems encountered when a slurry is formulated with one cement sample and used with a batch having different properties. Such variability imposes a heavy burden on performance testing and is often a major factor in operational failure. We describe methods which allow the identification, characterization and prediction of the variability of oilfield cements. Our approach involves predicting cement compositions, particle size distributions and thickening time curves from the diffuse reflectance infrared Fourier transform spectrum of neat cement powders. Predictions make use of artificial neural networks. Slurry formulation thickening times can be predicted with uncertainties of less than {+-}10%. Composition and particle size distributions can be predicted with uncertainties a little greater than measurement error but general trends and differences between cements can be determined reliably. Our research shows that many key cement properties are captured within the Fourier transform infrared spectra of cement powders and can be predicted from these spectra using suitable neural network techniques. Several case studies are given to emphasize the use of these techniques which provide the basis for a valuable quality control tool now finding commercial use in the oilfield.

  2. Thermal Energy Storage/Waste Heat Recovery Applications in the Cement Industry

    E-Print Network [OSTI]

    Beshore, D. G.; Jaeger, F. A.; Gartner, E. M.

    1979-01-01T23:59:59.000Z

    , and the Portland Cement Association have studied the potential benefits of using waste heat recovery methods and thermal energy storage systems in the cement manufacturing process. This work was performed under DOE Contract No. EC-77-C-01-50S4. The study has been...

  3. Z .Chemical Geology 152 1998 227256 The thermal and cementation histories of a sandstone petroleum

    E-Print Network [OSTI]

    Z .Chemical Geology 152 1998 227­256 The thermal and cementation histories of a sandstone petroleum-feldspars recovered at various depths from a deep well drilled through a carbonate-cemented sandstone petroleum of a sandstone petroleum xreservoir, Elk Hills, California. Part 2: In situ oxygen and carbon isotopic results

  4. Impact of Hydrated Cement Paste Quality and Entrained Air-Void

    E-Print Network [OSTI]

    Impact of Hydrated Cement Paste Quality and Entrained Air-Void System on the Durability of Concrete the characteristics of the entrained air-void system #12;Objectives · Review the current accepted relationship between is affected by the quality of the hydrated cement paste (HCP) and the presence of a properly entrained air

  5. XRF and leaching characterization of waste glasses derived from wastewater treatment sludges

    SciTech Connect (OSTI)

    Ragsdale, R.G., Jr

    1994-12-01T23:59:59.000Z

    Purpose of this study was to investigate use of XRF (x-ray fluorescence spectrometry) as a near real-time method to determine melter glass compositions. A range of glasses derived from wastewater treatment sludges associated with DOE sites was prepared. They were analyzed by XRF and wet chemistry digestion with atomic absorption/inductively coupled emission spectrometry. Results indicated good correlation between these two methods. A rapid sample preparation and analysis technique was developed and demonstrated by acquiring a sample from a pilot-scale simulated waste glass melter and analyzing it by XRF within one hour. From the results, XRF shows excellent potential as a process control tool for waste glass vitrification. Glasses prepared for this study were further analyzed for durability by toxicity characteristic leaching procedure and product consistency test and results are presented.

  6. Control technology assessment of hazardous-waste-disposal operations in chemicals manufacturing: in-depth survey report of San Juan Cement Company, Dorado, Puerto Rico, November 1981

    SciTech Connect (OSTI)

    Crandall, M.S.

    1982-07-01T23:59:59.000Z

    A visit was made to the San Juan Cement Company, Dorado, Puerto Rico to evaluate control methods for a storage and delivery system for hazardous wastes used in a demonstration project as a supplemental fuel for cofiring a cement kiln. Analysis of the material during the visit revealed the presence of methylene chloride, carbon-tetrachloride, chloroform, acetone, hexane, ethanol, and ethyl acetate. Steel storage tanks were placed on an impermeable concrete slab surrounded by a sealed retaining wall. Steel piping with all welded joints carried the waste fuels from storage tanks to the kiln, where fuels were injected through a specially fabricated burner. Vapor emissions were suppressed by venting the displaced vapor through a recycle line. Exhaust gases from the kiln passed through a bag house type dust collector, and were vented to the atmosphere through a single stack. Half-mask air-purifying respirators were used when in the hazardous-waste storage/delivery area. Neoprene gloves were used when performing tasks with potential skin contact. Hard hats, safety glasses, and safety boots were all worn. The author concludes that the control methods used seemed effective in suppressing vapor emissions.

  7. Early containment of high-alkaline solution simulating low-level radioactive waste stream in clay-bearing blended cement

    SciTech Connect (OSTI)

    Kruger, A.A. [Westinghouse Hanford Co., Richland, WA (United States); Olson, R.A.; Tennis, P.D. [Northwestern Univ., Evanston, IL (United States). Center for Advanced Cement-Based Materials] [and others

    1995-04-01T23:59:59.000Z

    Portland cement blended with fly ash and attapulgite clay was mixed with high-alkaline solution simulating low-level radioactive waste stream at a one-to-one weight ratio. Mixtures were adiabatically and isothermally cured at various temperatures and analyzed for phase composition, total alkalinity, pore solution chemistry, and transport properties as measured by impedance spectroscopy. Total alkalinity is characterized by two main drops. The early one corresponds to a rapid removal of phosphorous, aluminum, sodium, and to a lesser extent potassium solution. The second drop from about 10 h to 3 days is mainly associated with the removal of aluminum, silicon, and sodium. Thereafter, the total alkalinity continues descending, but at a lower rate. All pastes display a rapid flow loss that is attributed to an early precipitation of hydrated products. Hemicarbonate appears as early as one hour after mixing and is probably followed by apatite precipitation. However, the former is unstable and decomposes at a rate that is inversely related to the curing temperature. At high temperatures, zeolite appears at about 10 h after mixing. At 30 days, the stabilized crystalline composition Includes zeolite, apatite and other minor amounts of CaCO{sub 3}, quartz, and monosulfate Impedance spectra conform with the chemical and mineralogical data. The normalized conductivity of the pastes shows an early drop, which is followed by a main decrease from about 12 h to three days. At three days, the permeability of the cement-based waste as calculated by Katz-Thompson equation is over three orders of magnitude lower than that of ordinary portland cement paste. However, a further decrease in the calculated permeability is questionable. Chemical stabilization is favorable through incorporation of waste species into apatite and zeolite.

  8. Comparative analysis of the life cycle impact assessment of available cement inventories in the EU

    SciTech Connect (OSTI)

    Josa, Alejandro [Technical University of Catalonia (UPC), School of Civil Engineering (ETSECCPB), C/Jordi Girona 1-3 Modul D2/C1, Barcelona 08034 (Spain)]. E-mail: alejandro.josa@upc.edu; Aguado, Antonio [Technical University of Catalonia (UPC), School of Civil Engineering (ETSECCPB), C/Jordi Girona 1-3 Modul D2/C1, Barcelona 08034 (Spain); Cardim, Arnaldo [Civil Engineering Department, Polytechnic School of Penambuco University, Rua Benfica, 455-Madalena, CEP 50.750-410 (Brazil); Byars, Ewan [Centre for Cement and Concrete, Department of Civil and Structural Engineering, University of Sheffield, Sir Frederick Mappin Building, Mappin Street, Sheffield S1 3JD (United Kingdom)

    2007-05-15T23:59:59.000Z

    Life cycle impact assessment (LCIA) is one of basic steps in life cycle assessment methodology (LCA). This paper presents a comparative study of the LCIA of different life cycle inventories (LCI) for EU cements. The analysis unit used is the manufacture of 1 kg of cement, from 'cradle to gate'. The impact categories considered are those resulting from the manufacture of cement and include greenhouse effects, acidification, eutrophication and summer and winter smog, amongst others. The results of the study highlighted some inconsistencies in existing inventories. As for the LCIA, the main environmental interventions related to cement manufacture were classified and characterised and their effect on different impact categories analysed. Differences observed in evaluation of the impact of cement type were essentially related to their clinker content.

  9. Dynamic Evolution of Cement Composition and Transport Properties under Conditions Relevant to Geological Carbon Sequestration

    SciTech Connect (OSTI)

    Brunet, Jean-Patrick Leopold; Li, Li; Karpyn, Zuleima T.; Strazisar, Brian; Bromhal Grant

    2013-08-01T23:59:59.000Z

    Assessing the possibility of CO{sub 2} leakage is one of the major challenges for geological carbon sequestration. Injected CO{sub 2} can react with wellbore cement, which can potentially change cement composition and transport properties. In this work, we develop a reactive transport model based on experimental observations to understand and predict the property evolution of cement in direct contact with CO{sub 2}-saturated brine under diffusion-controlled conditions. The model reproduced the observed zones of portlandite depletion and calcite formation. Cement alteration is initially fast and slows down at later times. This work also quantified the role of initial cement properties, in particular the ratio of the initial portlandite content to porosity (defined here as ?), in determining the evolution of cement properties. Portlandite-rich cement with large ? values results in a localized “sharp” reactive diffusive front characterized by calcite precipitation, leading to significant porosity reduction, which eventually clogs the pore space and prevents further acid penetration. Severe degradation occurs at the cement–brine interface with large ? values. This alteration increases effective permeability by orders of magnitude for fluids that preferentially flow through the degraded zone. The significant porosity decrease in the calcite zone also leads to orders of magnitude decrease in effective permeability, where fluids flow through the low-permeability calcite zone. The developed reactive transport model provides a valuable tool to link cement–CO{sub 2} reactions with the evolution of porosity and permeability. It can be used to quantify and predict long-term wellbore cement behavior and can facilitate the risk assessment associated with geological CO{sub 2} sequestration.

  10. Effect of furnace atmosphere on E-glass foaming

    E-Print Network [OSTI]

    Kim, D. S.; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

    2006-01-01T23:59:59.000Z

    oxy-fired furnaces. E-glass foams were generated in a fused-81.05.K 1. Introduction Glass foams generated in glass-that the stability of E-glass foam decreased with increasing

  11. Structure glass technology : systems and applications

    E-Print Network [OSTI]

    Leitch, Katherine K. (Katherine Kristen)

    2005-01-01T23:59:59.000Z

    Glass cannot compete with steel in terms of strength or durability, but it is the only structural material that offers the highly sought after qualities of translucency and transparency. The use of glass has evolved from ...

  12. The Huge, Blue, Jesus Glass Statue

    E-Print Network [OSTI]

    Robbins, Joanna

    2013-01-01T23:59:59.000Z

    Later, I found a huge, blue, glass statue of Jesus stuffedOF CALIFORNIA RIVERSIDE The Huge, Blue, Jesus Glass Statue Aeyes as RED And wrote down BLUE for your hair. I had to fix

  13. Hydration studies of calcium sulfoaluminate cements blended with fly ash

    SciTech Connect (OSTI)

    García-Maté, M.; De la Torre, A.G. [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain)] [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain); León-Reina, L. [Servicios Centrales de Apoyo a la Investigación, Universidad de Málaga, 29071 Málaga (Spain)] [Servicios Centrales de Apoyo a la Investigación, Universidad de Málaga, 29071 Málaga (Spain); Aranda, M.A.G. [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain) [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain); CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); Santacruz, I., E-mail: isantacruz@uma.es [Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071 Málaga (Spain)

    2013-12-15T23:59:59.000Z

    The main objective of this work is to study the hydration and properties of calcium sulfoaluminate cement pastes blended with fly ash (FA) and the corresponding mortars at different hydration ages. Laboratory X-ray powder diffraction, rheological studies, thermal analysis, porosimetry and compressive strength measurements were performed. The analysis of the diffraction data by Rietveld method allowed quantifying crystalline phases and overall amorphous contents. The studied parameters were: i) FA content, 0, 15 and 30 wt.%; and ii) water addition, water-to-CSA mass ratio (w/CSA = 0.50 and 0.65), and water-to-binder mass ratio (w/b = 0.50). Finally, compressive strengths after 6 months of 0 and 15 wt.% FA [w/CSA = 0.50] mortars were similar: 73 ± 2 and 72 ± 3 MPa, respectively. This is justified by the filler effect of the FA as no strong evidences of reactivity of FA with CSA were observed. These results support the partial substitution of CSA cements with FA with the economic and environmental benefits.

  14. Acceptable approaches for beneficial use of cement kiln dust

    SciTech Connect (OSTI)

    Schreiber, R.J.; Smeenk, S.D. [Schreiber, Yonley and Associates, St. Louis, MO (United States)

    1998-12-31T23:59:59.000Z

    One beneficial use of cement kiln dust (CKD) is application of CKD to cropland as agricultural lime or fertilizer. However, the EPA has expressed a concern over land application of CKD when the metals constituents in the CKD are above the industry-wide median levels presented in EPA`s Report to Congress on Cement Kiln Dust. Under the Clean Water Act, EPA has established limits for metals concentrations in sewage sludge that is applied to the land for beneficial use of the nitrogen in the sludge. The limits for land application of sewage sludge were established based on the results of exposure risk assessments. A comparison of the median industry-wide metals concentrations in CKD to the metals concentration limits for land application of sewage sludge indicates that all trace metal concentrations IN CKD are below the corresponding sewage sludge land application limit, with the exception of the median level of arsenic from one data set. EPA has determined that land application of CKD with metals concentration limits at or below the industry-wide median concentrations does not pose a significant human cancer or non-cancer health risk. Therefore, with appropriate limits, CKD can be beneficially reused for land application on agricultural land in a manner that is protective of human health and the environment.

  15. Synthesis of belite cement clinker of high hydraulic reactivity

    SciTech Connect (OSTI)

    Kacimi, Larbi [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)], E-mail: kacimi20002000@yahoo.fr; Simon-Masseron, Angelique [Laboratoire des Materiaux a Porosite Controlee, CNRS UMR 7016, Universite de Haute-Alsace, 3, rue Alfred-Werner, F-68093 Mulhouse cedex (France)], E-mail: A.Simon@univ-mulhouse.fr; Salem, Souria [Departement d'Architecture, Faculte de Genie Civile, USTO-Oran (Algeria)], E-mail: zinaisalem@yahoo.fr; Ghomari, Abdelhamid [Departement de Chimie, U.A.I.B., Route de Belahcel, Mostaganem (Algeria)], E-mail: belkey@hotmail.com; Derriche, Zoubir [Laboratoire de Genie des Procedes, Departement de Chimie, Universite des Sciences et de la Technologie d'Oran, B.P. 1505, El-M'nouar, U.S.T. Oran (Algeria)

    2009-07-15T23:59:59.000Z

    This study is concerned with the increase of the cooling rate of belite clinker, by using the water quenching for the chemical stabilization of reactive belite, which improves the hydraulic properties of this clinker. The addition of adequate mineralizers, as NaF and Fe{sub 2}O{sub 3}, contributes to the improvement of the clinker properties obtained at low burning temperature. X-ray fluorescence spectroscopy, X-ray diffraction analysis and optical microscopy were used to determine the chemical and mineralogical compositions of this clinker. The samples were analyzed by means of a scanning electronic microscope connected with an energy-dispersive X-ray spectrometer to detect the composition of the belite phase and its morphology. Physical and mechanical properties of this clinker cement were determined. The results show that the belite clinker obtained at 1150 {sup o}C, with lime saturation factor 0.67, is characterized by a great hydraulic reactivity, similar to that of the ordinary alite clinker. The addition of 2% of NaF and the water quenching improved the chemical, mineralogical and structural properties, while improving the cement hydraulic properties.

  16. Demonstration of Mixed Waste Debris Macroencapsulation Using Sulfur Polymer Cement

    SciTech Connect (OSTI)

    Mattus, C.H.

    1998-07-01T23:59:59.000Z

    This report covers work performed during FY 1997 as part of the Evaluation of Sulfur Polymer Cement Fast-Track System Project. The project is in support of the ``Mercury Working Group/Mercury Treatment Demonstrations - Oak Ridge`` and is described in technical task plan (TTP) OR-16MW-61. Macroencapsulation is the treatment technology required for debris by the U.S. Environmental Protection Agency Land Disposal Restrictions (LDR) under the Resource Conservation and Recovery Act. Based upon the results of previous work performed at Oak Ridge, the concept of using sulfur polymer cement (SPC) for this purpose was submitted to the Mixed Waste Focus Area (MWFA). Because of the promising properties of the material, the MWFA accepted this Quick Win project, which was to demonstrate the feasibility of macroencapsulation of actual mixed waste debris stored on the Oak Ridge Reservation. The waste acceptance criteria from Envirocare, Utah, were chosen as a standard for the determination of the final waste form produced. During this demonstration, it was shown that SPC was a good candidate for macroencapsulation of mixed waste debris, especially when the debris pieces were dry. The matrix was found to be quite easy to use and, once the optimum operating conditions were identified, very straightforward to replicate for batch treatment. The demonstration was able to render LDR compliant more than 400 kg of mixed wastes stored at the Oak Ridge National Laboratory.

  17. Transparent glass honeycomb structures for energy loss control. Final summary report, January 1976-October 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    It has been demonstrated that properly-shaped glass honeycomb placed between a non-selective absorber and the coverglass of a flat plate solar collector gives collection efficiencies significantly higher than those of conventional flat plate units, even those with selective absorbers, collecting solar energy at temperatures required for heating and cooling buildings. Three basic glass honeycomb shapes were analyzed and tested: (1) thin-walled cylindrical glass tube honeycomb in square or hexagonal arrays, (2) corrugated thin glass sheets stacked peak-to-trough to form double-sinsuoid-shaped cells, and (3) flat thin glass sheets stacked to form long parallel slots. A continuous hot-rolling mill was used to corrugate commercial Micro-Sheet glass, thus demonstrating a key step needed for the commercialization of glass honeycomb fabrication. Experimental-scale (61 cm x 61 cm) collectors and collectors scaled-up in area were fabricated and tested outdoors to verify the analytical-numerical performance-prediction algorithms developed during the program. Optimization studies were made with respect to performance and cost to identify optimal shapes of sinusoidal-celled glass honeycombs which have high potential for mass production.

  18. Energy Efficiency Improvement and Cost Saving Opportunities for the Glass Industry. An ENERGY STAR Guide for Energy and Plant Managers

    SciTech Connect (OSTI)

    Galitsky, Christina; Worrell, Ernst; Galitsky, Christina; Masanet, Eric; Graus, Wina

    2008-03-01T23:59:59.000Z

    The U.S. glass industry is comprised of four primary industry segments--flat glass, container glass, specialty glass, and fiberglass--which together consume $1.6 billion in energy annually. On average, energy costs in the U.S. glass industry account for around 14 percent of total glass production costs. Energy efficiency improvement is an important way to reduce these costs and to increase predictable earnings, especially in times of high energy price volatility. There is a variety of opportunities available at individual plants in the U.S. glass industry to reduce energy consumption in a cost-effective manner. This Energy Guide discusses energy efficiency practices and energy-efficient technologies that can be implemented at the component, process, system, and organizational levels. A discussion of the trends, structure, and energy consumption characteristics of the U.S. glass industry is provided along with a description of the major process steps in glass manufacturing. Expected savings in energy and energy-related costs are given for many energy efficiency measures, based on case study data from real-world applications in glass production facilities and related industries worldwide. Typical measure payback periods and references to further information in the technical literature are also provided, when available. The information in this Energy Guide is intended to help energy and plant managers in the U.S. glass industry reduce energy consumption in a cost-effective manner while maintaining the quality of products manufactured. Further research on the economics of the measures--as well on as their applicability to different production practices--is needed to assess potential implementation of selected technologies at individual plants.

  19. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

    SciTech Connect (OSTI)

    Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

    2014-03-21T23:59:59.000Z

    Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

  20. Classification of oxide glasses: A polarizability approach

    SciTech Connect (OSTI)

    Dimitrov, Vesselin [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki [Department of Chemistry, The Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka-shi, Niigata-ken 940-2188 (Japan)]. E-mail: komatsu@chem.nagaokaut.ac.jp

    2005-03-15T23:59:59.000Z

    A classification of binary oxide glasses has been proposed taking into account the values obtained on their refractive index-based oxide ion polarizability {alpha}{sub O2-}(n{sub 0}), optical basicity {lambda}(n{sub 0}), metallization criterion M(n{sub 0}), interaction parameter A(n{sub 0}), and ion's effective charges as well as O1s and metal binding energies determined by XPS. Four groups of oxide glasses have been established: glasses formed by two glass-forming acidic oxides; glasses formed by glass-forming acidic oxide and modifier's basic oxide; glasses formed by glass-forming acidic and conditional glass-forming basic oxide; glasses formed by two basic oxides. The role of electronic ion polarizability in chemical bonding of oxide glasses has been also estimated. Good agreement has been found with the previous results concerning classification of simple oxides. The results obtained probably provide good basis for prediction of type of bonding in oxide glasses on the basis of refractive index as well as for prediction of new nonlinear optical materials.

  1. The corrosion behavior of DWPF glasses

    SciTech Connect (OSTI)

    Ebert, W.L.; Bates, J.K. [Argonne National Lab., IL (United States). Chemical Technology Div.

    1995-06-01T23:59:59.000Z

    The authors analyzed the corroded surfaces of reference glasses developed for the Defense Waste Processing Facility (DWPF) to characterize their corrosion behavior. The corrosion mechanism of nuclear waste glasses must be known in order to provide source terms describing radionuclide release for performance assessment calculations. Different DWPF reference glasses were corroded under conditions that highlighted various aspects of the corrosion process and led to different extents of corrosion. The glasses corroded by similar mechanisms, and a phenomenological description of their corrosion behavior is presented here. The initial leaching of soluble glass components results in the formation of an amorphous gel layer on the glass surface. The gel layer is a transient phase that transforms into a layer of clay crystallites, which equilibrates with the solution as corrosion continues. The clay layer does not act as a barrier to either water penetration or glass dissolution, which continues beneath it, and may eventually separate from the glass. Solubility limits for glass components may be established by the eventual precipitation of secondary phases; thus, corrosion of the glass becomes controlled by the chemical equilibrium between the solution and the assemblage of secondary phases. In effect, the solution is an intermediate phase through which the glass transforms to an energetically more favorable assemblage of phases. Implications regarding the prediction of long-term glass corrosion behavior are discussed.

  2. DURABLE GLASS FOR THOUSANDS OF YEARS

    SciTech Connect (OSTI)

    Jantzen, C.

    2009-12-04T23:59:59.000Z

    The durability of natural glasses on geological time scales and ancient glasses for thousands of years is well documented. The necessity to predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to various thermodynamic and kinetic approaches. Advances in the measurement of medium range order (MRO) in glasses has led to the understanding that the molecular structure of a glass, and thus the glass composition, controls the glass durability by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. During the early stages of glass dissolution, a 'gel' layer resembling a membrane forms through which ions exchange between the glass and the leachant. The hydrated gel layer exhibits acid/base properties which are manifested as the pH dependence of the thickness and nature of the gel layer. The gel layer ages into clay or zeolite minerals by Ostwald ripening. Zeolite mineral assemblages (higher pH and Al{sup 3+} rich glasses) may cause the dissolution rate to increase which is undesirable for long-term performance of glass in the environment. Thermodynamic and structural approaches to the prediction of glass durability are compared versus Ostwald ripening.

  3. Precision diamond grinding of ceramics and glass

    SciTech Connect (OSTI)

    Smith, S.; Paul, H.; Scattergood, R.O.

    1988-12-01T23:59:59.000Z

    A new research initiative will be undertaken to investigate the effect of machine parameters and material properties on precision diamond grinding of ceramics and glass. The critical grinding depth to initiate the plastic flow-to-brittle fracture regime will be directly measured using plunge-grind tests. This information will be correlated with machine parameters such as wheel bonding and diamond grain size. Multiaxis grinding tests will then be made to provide data more closely coupled with production technology. One important aspect of the material property studies involves measuring fracture toughness at the very short crack sizes commensurate with grinding damage. Short crack toughness value`s can be much less than the long-crack toughness values measured in conventional fracture tests.

  4. Identifying the Bose glass phase

    E-Print Network [OSTI]

    R. Pugatch; N. Bar-gill; N. Katz; E. Rowen; N. Davidson

    2006-07-28T23:59:59.000Z

    Introducing disorder into the Bose-Hubbard model at integer fillings leads to a Bose glass phase, along with the Mott insulator and superfluid phases. We suggest a new order parameter: the determinant of the one body density matrix, which is nonzero only within the Mott-insulator phase. Alongside the superfluid fraction, it is then possible to distinguish the three phases. The Bose glass phase is the only phase which has vanishing determinant and superfluid fraction. The vanishing of the determinant in the Bose glass phase occurs due to the partial fragmentation of the condensate into localized fragments, each with zero superfluid response, which implies the presence of unoccupied sites and hence the presence of lines of zeros in the one body density matrix. In the superfluid phase, the determinant vanish for another reason - due to the macroscopic occupation of a single particle state. Finally, we suggest the enhancement of the three body decay rate in the Bose glass phase, as an experimental indicator for the presence of localized fragments.

  5. Glass-ceramic material and method of making

    DOE Patents [OSTI]

    Meinhardt, Kerry D [Richland, WA; Vienna, John D [West Richland, WA; Armstrong, Timothy R [Pasco, WA; Pederson, Larry R [Kennewick, WA

    2002-08-13T23:59:59.000Z

    The present invention is a glass-ceramic material and method of making useful for joining at least two solid ceramic parts. The seal is a blend of M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 system can be used to join or seal both tubular and planar ceramic solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

  6. Comprehensive data base of high-level nuclear waste glasses: September 1987 status report: Volume 1, Discussion and glass durability data

    SciTech Connect (OSTI)

    Kindle, C.H.; Kreiter, M.R.

    1987-12-01T23:59:59.000Z

    The Materials Characterization Center (MCC) at Pacific Northwest Laboratory is assembling a comprehensive data base (CDB) of experimental data collected for high-level nuclear waste package components. Data collected throughout the world are included in the data base; current emphasis is on waste glasses and their properties. The goal is to provide a data base of properties and compositions and an analysis of dominant property trends as a function of composition. This data base is a resource that nuclear waste producers, disposers, and regulators can use to compare properties of a particular high-level nuclear waste glass product with the properties of other glasses of similar compositions. Researchers may use the data base to guide experimental tests to fill gaps in the available knowledge or to refine empirical models. The data are incorporated into a computerized data base that will allow the data to be extracted based on, for example, glass composition or test duration. 3 figs.

  7. Characterization of modified calcium-silicate cements exposed to acidic environment

    SciTech Connect (OSTI)

    Camilleri, Josette, E-mail: josette.camilleri@um.edu.mt

    2011-01-15T23:59:59.000Z

    Portland cement which is used as a binder in concrete in the construction industry has been developed into a biomaterial. It is marketed as mineral trioxide aggregate and is used in dentistry. This material has been reported to be very biocompatible and thus its use has diversified. The extended use of this material has led to developments of newer versions with improved physical properties. The aim of this study was to evaluate the effect of acidic environments found in the oral cavity on fast setting calcium silicate cements with improved physical properties using a combination of techniques. Two fast setting calcium silicate cements (CSA and CFA) and two cement composites (CSAG and CFAG) were assessed by subjecting the materials to lactic acid/sodium lactate buffer gel for a period of 28 days. At weekly intervals the materials were viewed under the tandem scanning confocal microscope (TSM), and scanning electron microscope (SEM). The two prototype cements exhibited changes in their internal chemistry with no changes in surface characteristics. Since the changes observed were mostly sub-surface evaluation of surface characteristics of cement may not be sufficient in the determination of chemical changes occurring. - Research Highlights: {yields} An acidic environment affects modified fast setting calcium silicate-based cements. {yields} No surface changes are observed in acidic environment. {yields} An acidic environment causes sub-surface changes in the material chemistry which are only visible in fractured specimens. {yields} A combination of techniques is necessary in order to evaluate the chemical changes occurring.

  8. IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT08, KT09, AND KT10-SERIES GLASS COMPOSITIONS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2011-04-26T23:59:59.000Z

    This report is the fourth in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. The KT09-series of glasses was designed to study the effect of increasing Al{sub 2}O{sub 3} and K{sub 2}O concentrations on the propensity for crystallization of titanium containing phases in high TiO{sub 2} concentration glasses. Earlier work on the KT05-series glasses recommended that the impact of these two components be studied further. Increased Al{sub 2}O{sub 3} concentrations have been shown to improve the properties and performance of high waste loading glasses, and K{sub 2}O has been reported to improve the retention of TiO{sub 2} in silicate glasses. The KT10-series of compositions was designed to evaluate any impacts of the SCIX components at concentrations 50% higher than currently projected.a The glasses were fabricated in the laboratory and characterized to identify crystallization, to verify chemical compositions, to measure viscosity, and to measure durability. Liquidus temperature measurements for the KT10-series glasses are underway and will be reported separately. All but one of the KT08-series glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which had no practical impact on the durability of the glass and is typically found in DWPF-type glasses. The measured Product Consistency Test (PCT) responses for the KT08-series glasses are well predicted by the DWPF models. The viscosities of the KT08-series glasses were generally well predicted by the DWPF model. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components. Increased Al{sub 2}O{sub 3} concentrations were not successful in preventing the formation of iron titanate crystals in the KT09-series glasses. Increased K{sub 2}O concentrations were successful in hindering the formation of iron titanates in some of the glasses after the canister centerline cooled (CCC) heat treatment. However, this result did not apply to all of the CCC versions of the glasses, indicating a compositional dependence of this effect. In addition, high concentrations of K{sub 2}O have been shown to hinder the ability of the DWPF durability and viscosity models to predict the performance of these glasses. The usefulness of increased K{sub 2}O concentrations in preventing the formation of iron titanates may therefore be limited. Further characterization was not performed for the KT09-series glasses since the type of crystallization formed was the characteristic of interest for these compositions. All of the KT10-series glasses were XRD amorphous, regardless of heat treatment. Chemical composition measurements showed that the glasses met the targeted concentrations for each oxide. In general, the measured PCT responses of the KT10-series glasses were well predicted by the DWPF models. The measured, normalized release values for silicon for some of the glasses fell above the 95% confidence interval for the predicted values; however, the PCT responses for these glasses remain considerably lower than that of the benchmark Environmental Assessment (EA) glass. The viscosities of the KT10-series glasses were generally well predicted by the DWPF model. The next step in this study will be to compile all of the data developed and further compare the measured properties and performance with those predicted by the current DWPF Product Composition Control System (PCCS) models. Recommendations will then be made as to which models, if any, may need to be modified in order to accommodate the material from SCIX into DWPF

  9. Improved method and composition for immobilization of waste in cement-based material

    DOE Patents [OSTI]

    Tallent, O.K.; Dodson, K.E.; McDaniel, E.W.

    1987-10-01T23:59:59.000Z

    A composition and method for fixation or immobilization of aqueous hazardous waste material in cement-based materials (grout) is disclosed. The amount of drainable water in the cured grout is reduced by the addition of an ionic aluminum compound to either the waste material or the mixture of waste material and dry-solid cement- based material. This reduction in drainable water in the cured grout obviates the need for large, expensive amounts of gelling clays in grout materials and also results in improved consistency and properties of these cement-based waste disposal materials.

  10. Pressurized heat treatment of glass ceramic

    DOE Patents [OSTI]

    Kramer, D.P.

    1984-04-19T23:59:59.000Z

    A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

  11. Durability of Silicate Glasses: An Historical Approach

    SciTech Connect (OSTI)

    Farges, Francois; /Museum Natl. Hist. Natur. /Stanford U., Geo. Environ. Sci.; Etcheverry, Marie-Pierre; /Marne la Vallee U.; Haddi, Amine; /Marne la Valle U.; Trocellier,; /Saclay; Curti, Enzo; /PSI, Villigen; Brown, Gordon E., Jr.; /SLAC, SSRL

    2007-01-02T23:59:59.000Z

    We present a short review of current theories of glass weathering, including glass dissolution, and hydrolysis of nuclear waste glasses, and leaching of historical glasses from an XAFS perspective. The results of various laboratory leaching experiments at different timescales (30 days to 12 years) are compared with results for historical glasses that were weathered by atmospheric gases and soil waters over 500 to 3000 years. Good agreement is found between laboratory experiments and slowly leached historical glasses, with a strong enrichment of metals at the water/gel interface. Depending on the nature of the transition elements originally dissolved in the melt, increasing elemental distributions are expected to increase with time for a given glass durability context.

  12. CHEMICAL COMPOSITION AND PCT DATA FOR THE INITIAL SET OF HANFORD ENHANCED WASTE LOADING GLASSES

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2014-06-02T23:59:59.000Z

    In this report, the Savannah River National Laboratory provides chemical analyses and Product Consistency Test results for 20 simulated high level waste glasses fabricated by the Pacific Northwest National Laboratory. The results of these analyses will be used as part of efforts to revise or extend the validation ranges of the current Hanford Waste Treatment and Immobilization Plant glass property models to cover a broader span of waste compositions. The measured chemical composition data are reported and compared with the targeted values for each component for each glass. Two components of the study glasses, fluorine and silver, were not measured since each of these species would have required the use of an additional preparation method and their measured values were likely to be near or below analytical detection limits. Some of the glasses were difficult to prepare for chemical analysis. A sodium peroxide fusion dissolution method was successful in completely dissolving the glasses. Components present in the glasses in minor concentrations can be difficult to measure using this dissolution method due to dilution requirements. The use of a lithium metaborate preparation method for the minor components (planned for use since it is typically successful in digesting Defense Waste Processing Facility HLW glasses) resulted in an unacceptable amount of undissolved solids remaining in the sample solutions. An acid dissolution method was used instead, which provided more thorough dissolution of the glasses, although a small amount of undissolved material remained for some of the study glasses. The undissolved material was analyzed to determine those components of the glasses that did not fully dissolve. These components (e.g., calcium and chromium) were present in sufficient quantities to be reported from the measurements resulting from the sodium peroxide fusion preparation method, which did not leave undissolved material. Overall, the analyses resulted in sums of oxides that ranged from about 98 to 101.5 wt % for the study glasses, indicating excellent recovery of all the components in the chemical composition analyses. Comparisons of the targeted and measured chemical compositions indicated that, in general, the measured values for the glasses met the targeted concentrations. Exceptions were Cr{sub 2}O{sub 3}, MgO, and P{sub 2}O{sub 5}. The measured values for Cr{sub 2}O{sub 3} were somewhat low when compared to the targeted values for all of the study glasses targeting Cr{sub 2}O{sub 3} concentrations above 0.5 wt %. Many of the measured MgO and P{sub 2}O{sub 5} values were below the targeted values for those glasses that contained these components. Two of the study glasses exhibited differences from the targeted compositions that may indicate a batching error. Glasses EWG-HAI-Centroid-2 and EWG-OL-1672 had measured values for Al{sub 2}O{sub 3} and SiO{sub 2} that were lower than the targeted values, and measured values for B{sub 2}O{sub 3} that were higher than the targeted values. Glass EWG-HAI-Centroid-2 also had a measured value for Fe{sub 2}O{sub 3} that was lower than the targeted value. A review of the PCT data, including standards and blanks, revealed no issues with the performance of the tests. The PCT results were normalized to both the targeted and measured compositions of the study glasses. Comparisons of the normalized PCT results for both the quenched and Canister Centerline Cooled versions of the study glasses are made with the Environmental Assessment benchmark glass for reference.

  13. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01T23:59:59.000Z

    of O2 in combustion products Excess air used Recommended airtemperature of the air or combustion products and nodules tocombustion products of coal, additional air from various

  14. Cement substitution by a combination of metakaolin and limestone

    SciTech Connect (OSTI)

    Antoni, M., E-mail: mathieu.antoni@epfl.ch [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland); Rossen, J. [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)] [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland); Martirena, F. [CIDEM-UCLV, Universidad Las Villas, Santa Clara (Cuba)] [CIDEM-UCLV, Universidad Las Villas, Santa Clara (Cuba); Scrivener, K. [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)] [EPFL-STI-IMX-Laboratoires des Materiaux de Construction, Station12, CH-1015 Lausanne (Switzerland)

    2012-12-15T23:59:59.000Z

    This study investigates the coupled substitution of metakaolin and limestone in Portland cement (PC). The mechanical properties were studied in mortars and the microstructural development in pastes by X-ray diffraction, thermogravimetry analysis, mercury intrusion porosimetry and isothermal calorimetry. We show that 45% of substitution by 30% of metakaolin and 15% of limestone gives better mechanical properties at 7 and 28 days than the 100% PC reference. Our results show that calcium carbonate reacts with alumina from the metakaolin, forming supplementary AFm phases and stabilizing ettringite. Using simple mass balance calculations derived from thermogravimetry results, we also present the thermodynamic simulation for the system, which agrees fairly well with the experimental observations. It is shown that gypsum addition should be carefully balanced when using calcined clays because it considerably influences the early age strength by controlling the very rapid reaction of aluminates.

  15. In What Form is Lime Present in Portland Cement

    E-Print Network [OSTI]

    Wright, Claude W.

    1910-01-01T23:59:59.000Z

    to obtain Si02.33a0, In his conclusions Hebuffat does not consider it of importance whether alit consists of pure Si02.3CaO or a crystalline compound of Si02.2CaO with 3a0 and an aluminate. He says the aluminate in Portland dement can­ not be Al 203.30a..., Erd- meyer, Nev/berry's, Zulkowski, Rebuff at, Meyers, Richardson, Michaelis and Meade• d. Work of the Carbegie Institute of Washington on CaO #Si0 2 series and binary compounds of Al 2°3> Si0 2, MgO, CaO. On the presence of free lime in cement...

  16. The utilization of flue gas desulfurization waste by-products in construction brick

    E-Print Network [OSTI]

    Berryman, Charles Wayne

    1992-01-01T23:59:59.000Z

    APPENDIX D. TEST PROCEDURES APPENDIX E. CONVERSION TABLES VITA 85 90 93 96 99 LIST OF FIGURES Figure Page Model for FGD Waste By-Product Research Unconfined Compressive Strength for Fly Ash Mixed with Various Inductions of Portland Cement 15... properties such as weight, durability, strength, density, etc. Varying mixes of bottom ash, fly ash, portland cement, and sand will be tested for possible enhancement of the hemihydrate. Also, a mix design that best utilizes all the waste by...

  17. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, Terrance D. (617 Chestnut Ct., Aiken, SC 29803)

    1993-01-01T23:59:59.000Z

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes.

  18. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, T.D.

    1993-12-14T23:59:59.000Z

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes. 3 figures.

  19. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  20. Experimental study of potential wellbore cement carbonation by various phases of carbon dioxide during geologic carbon sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong

    2013-08-16T23:59:59.000Z

    Hydrated Portland cement was reacted with carbon dioxide (CO2) in supercritical, gaseous, and aqueous phases to understand the potential cement alteration processes along the length of a wellbore, extending from deep CO2 storage reservoir to the shallow subsurface during geologic carbon sequestration. The 3-D X-ray microtomography (XMT) images displayed that the cement alteration was significantly more extensive by CO2-saturated synthetic groundwater than dry or wet supercritical CO2 at high P (10 MPa)-T (50°C) conditions. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis also exhibited a systematic Ca depletion and C enrichment in cement matrix exposed to CO2-saturated groundwater. Integrated XMT, XRD, and SEM-EDS analyses identified the formation of extensive carbonated zone filled with CaCO3(s), as well as the porous degradation front and the outermost silica-rich zone in cement after exposure to CO2-saturated groundwater. The cement alteration by CO2-saturated groundwater for 2-8 months overall decreased the porosity from 31% to 22% and the permeability by an order of magnitude. Cement alteration by dry or wet supercritical CO2 was slow and minor compared to CO2-saturated groundwater. A thin single carbonation zone was formed in cement after exposure to wet supercritical CO2 for 8 months or dry supercritical CO2 for 15 months. Extensive calcite coating was formed on the outside surface of a cement sample after exposure to wet gaseous CO2 for 1-3 months. The chemical-physical characterization of hydrated Portland cement after exposure to various phases of carbon dioxide indicates that the extent of cement carbonation can be significantly heterogeneous depending on CO2 phase present in the wellbore environment. Both experimental and geochemical modeling results suggest that wellbore cement exposure to supercritical, gaseous, and aqueous phases of CO2 during geologic carbon sequestration is unlikely to damage the wellbore integrity because cement alteration by all phases of CO2 is dominated by carbonation reaction. This is consistent with previous field studies of wellbore cement with extensive carbonation after exposure to CO2 for 3 decades. However, XMT imaging indicates that preferential cement alteration by supercritical CO2 or CO2-saturated groundwater can occur along the cement-steel or cement-rock interfaces. This highlights the importance of further investigation of cement degradation along the interfaces of wellbore materials to ensure permanent geologic carbon storage.

  1. MAGNOX:BUTEX URANIUM BEARING GLASSES PHYSICAL AND CHEMICAL ANALYSIS DATA PACKAGE

    SciTech Connect (OSTI)

    Peeler, D.; Imrich, K.; Click, D.

    2011-03-08T23:59:59.000Z

    Sellafield Ltd (United Kingdom) has requested technical support from the Savannah River National Laboratory (SRNL) to characterize a series of uranium-bearing, mixed alkali borosilicate glasses [WFO (2010)]. The specific glasses to be characterized are based on different blends of Magnox (WRW17 simulant) and Butex (or HASTs 1 and 2) waste types as well as different incorporation rates (or waste loadings) of each blend. Specific Magnox:Butex blend ratios of interest include: 75:25, 60:40, and 50:50. Each of these waste blend ratios will be mixed with a base glass additive composition targeting waste loadings (WLs) of 25, 28, and 32% which will result in nine different glasses. The nine glasses are to be fabricated and physically characterized to provide Sellafield Ltd with the technical data to evaluate the impacts of various Magnox:Butex blend ratios and WLs on key glass properties of interest. It should be noted that the use of 'acceptable' in the Work for Other (WFO) was linked to the results of a durability test (more specifically the Soxhlet leach test). Other processing (e.g., viscosity ({eta}), liquidus temperature (T{sub L})) or product performance (e.g., Product Consistency Test (PCT) results - in addition to the Soxhlet leach test) property constraints were not identified. For example, a critical hold point in the classification of an 'acceptable glass' prior to processing high-level waste (HLW) through the Defense Waste Processing Facility (DWPF) is an evaluation of specific processing and product performance properties against pre-defined constraints. This process is referred to as Slurry Mix Evaporator (SME) acceptability in which predicted glass properties (based on compositional measurements) are compared to predefined constraints to determine whether the glass is acceptable [Brown and Postles (1995)]. As an example, although the nominal melter temperature at DWPF is 1150 C, there is a T{sub L} constraint (without uncertainties applied) of 1050 C. Any glass which has a T{sub L} predicted value > 1050 C would be classified as unacceptable and the SME product would not be transferred to the melter. As another example, consider durability (as defined by the PCT test) and its related constraints to determine acceptability. If the glass composition yields predicted normalized release values that exceed those associated with the Environmental Assessment (EA) glass (with uncertainties applied) then the glass is deemed unacceptable. The issue of acceptability plays a critical role in high level waste processing but without knowing the pre-defined constraints for the UK HLW system, assessments of acceptability of the glasses to be characterized in this study can not be made. The results of this study will be compared to DWPF constraints to provide a benchmark for determining acceptability. The objective of this task is to provide Sellafield Ltd. with the technical data to evaluate the impacts of various Magnox:Butex blend ratios and WLs on key glass properties of interest. The uranium bearing glasses span a compositional region of interest to Sellafield Ltd. and were physically characterized for key processing and product performance properties as defined in the WFO [WFO (2010)]. One of the specific technical issues (as defined in the WFO) is the potential impact of increasing aluminum concentrations on key properties (in particular viscosity).

  2. E-modulus evolution and its relation to solids formation of pastes from commercial cements

    SciTech Connect (OSTI)

    Maia, Lino, E-mail: lino.maia@fe.up.pt [LABEST - Laboratory for the Concrete Technology and Structural Behaviour, Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal); Centro de Ciencias Exatas e da Engenharia, Universidade da Madeira, Campus Universitario da Penteada, 9020-105 Funchal (Portugal); Azenha, Miguel, E-mail: miguel.azenha@civil.uminho.pt [ISISE - Institute for Sustainability and Innovation in Structural Engineering, Universidade do Minho, Escola de Engenharia, Campus de Azurem, 4800-058 Guimaraes (Portugal); Geiker, Mette, E-mail: mge@byg.dtu.dk [DTU - Department of Civil Engineering, Technical University of Denmark, Brovej, Building 118, DK-2800 Kgs. Lyngby (Denmark); NTNU - Department of Structural Engineering, Norwegian University of Science and Technology, Rich. Birkelandsvei 1A, 7491 Trondheim (Norway); Figueiras, Joaquim, E-mail: jafig@fe.up.pt [LABEST - Laboratory for the Concrete Technology and Structural Behaviour, Faculdade de Engenharia, Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto (Portugal)

    2012-07-15T23:59:59.000Z

    Models for early age E-modulus evolution of cement pastes are available in the literature, but their validation is limited. This paper provides correlated measurements of early age evolution of E-modulus and hydration of pastes from five commercial cements differing in limestone content. A recently developed methodology allowed continuous monitoring of E-modulus from the time of casting. The methodology is a variant of classic resonant frequency methods, which are based on determination of the first resonant frequency of a composite beam containing the material. The hydration kinetics - and thus the rate of formation of solids - was determined using chemical shrinkage measurements. For the cements studied similar relationships between E-modulus and chemical shrinkage were observed for comparable water-to-binder ratio. For commercial cements it is suggested to model the E-modulus evolution based on the amount of binder reacted, instead of the degree of hydration.

  3. Microsoft Word - NETL-TRS-003-2012_Cementing Research Needs_20121207...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Research Needs Related to Improving Primary Cement Isolation of Formations in Deep Offshore Wells 7 December 2012 Office of Fossil Energy NETL-TRS-3-2012 Disclaimer This report...

  4. Effect of spatial variability on the bearing capacity of cement-treated ground

    E-Print Network [OSTI]

    Kasama, Kiyonobu

    This paper presents a reliability assessment for the undrained bearing capacity of a surface strip foundation based on the results of a probabilistic study in which the shear strength and unit weight of cement-treated ...

  5. Sources of high temperature degradation of cement-based materials : nanoindentation and microporoelastic analysis

    E-Print Network [OSTI]

    DeJong, Matthew J. (Matthew Justin)

    2005-01-01T23:59:59.000Z

    The effects of high temperature exposure on cement-based materials have been under investigation for quite some time, but a fundamental understanding of the sources of high temperature degradation has been limited by ...

  6. Synthesis and Characterization of High Temperature Cement-Based Hydroceramic Materials 

    E-Print Network [OSTI]

    Kyritsis, Konstantinos

    2009-01-01T23:59:59.000Z

    Cement-based materials are of importance in the construction of geothermal wells and high-temperature oil and gas wells. These materials fill the annulus between the well casing and the rock forming a protective layer, ...

  7. Effects of microorganisms growth on the long-term stability of cement and bitumen

    SciTech Connect (OSTI)

    Libert, M.F.; Sellier, R.; Jouquet, G.; Trescinski, M.; Spor, H. [Nuclear Research Center of Cadarache, St.Paul-Lez-Durance (France)

    1993-12-31T23:59:59.000Z

    Cement is used as a coating matrix for nuclear waste or as an engineered barrier of waste repositories situated in geological formations. The effect of mineral acids excreted by bacteria (Thiobacillus) or organic acids produced by fungi, on the biodegradation of cement is discussed. Organic acids are quantitatively and qualitatively determined during growth of fungi over a two-year period. Even with high pH conditions, pH of the cement {approx} 11, growth of microorganisms occurs. Biodeterioration of cement is expressed in terms of bioleaching velocity of calcium and is observed by electron microscopy. Bitumen is commonly used as a matrix for the long-term storage of radioactive wastes. Long-term biodegrability of bitumen is discussed as a function of its chemical composition and various studied microorganisms.

  8. Lattice Boltzmann simulations of the permeability and capillary adsorption of cement model microstructures

    SciTech Connect (OSTI)

    Zalzale, M. [Laboratory of Construction Materials, Ecole Polytechnique Federale de Lausanne, CH-1015 Lausanne (Switzerland)] [Laboratory of Construction Materials, Ecole Polytechnique Federale de Lausanne, CH-1015 Lausanne (Switzerland); McDonald, P.J., E-mail: p.mcdonald@surrey.ac.uk [Department of Physics, University of Surrey, Guildford, Surrey GU2 7XH (United Kingdom)

    2012-12-15T23:59:59.000Z

    The lattice Boltzmann method is used to investigate the permeability of microstructures of cement pastes generated using the numerical models CEMHYD3D (Bentz, 1997) and {mu}IC (Bishnoi and Scrivener, 2009). Results are reported as a function of paste water-to-cement ratio and degree of hydration. The permeability decreases with increasing hydration and decreasing water-to-cement ratio in agreement with experiment. However the permeability is larger than the experimental data recorded using beam bending methods (Vichit-Vadakan and Scherer, 2002). Notwithstanding, the lattice Boltzmann results compare favourably with alternate numerical methods of permeability calculation for cement model microstructures. In addition, we show early results for the liquid/vapour capillary adsorption and desorption isotherms in the same model {mu}IC structures. The broad features of the experimental capillary porosity isotherm are reproduced, although further work is required to adequately parameterise the model.

  9. E-Print Network 3.0 - antibiotic-loaded cement spacers Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in this study. Sealed Reference Sample Sample Cement Paste 10 mm 10 mm 11.5mm 8mm Plastic Spacers 5 mm... based on Stokes equation actually suggests that some of the...

  10. Assessment of durability performance of "Early-Opening-to-Traffic" Portland Cement Concrete pavement and patches

    E-Print Network [OSTI]

    Shrestha, Pradhumna Babu

    1999-01-01T23:59:59.000Z

    This study relates the assessment of durability to ''early-opening-to-traffic'' (EOT) portland cement concrete (PCC). Several factors were identified relative to the performance of EOT PCC. Each of these factors was considered in terms of freeze...

  11. Detecting and modeling cement failure in high pressure/ high temperature wells using finite-element method

    E-Print Network [OSTI]

    Shahri, Mehdi Abbaszadeh

    2006-04-12T23:59:59.000Z

    conditions and are investigated simultaneously to more accurately predict cement failure. The results of this study show the relevant dependency of stress principles with temperature and pressure. These results clarify the deformation caused by any...

  12. Grinding of cement clinkers : linking multi-scale fracture properties to system chemistry, mineralogy and microstructure

    E-Print Network [OSTI]

    Wilson, William, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    Growing environmental concerns encourage the cement industry to improve its environmental performance, which in turn renews the interest in clinker grinding efficiency. Current knowledge on clinker grinding was built over ...

  13. Non-Linear Drying Diffusion and Viscoelastic Drying Shrinkage Modeling in Hardened Cement Pastes

    E-Print Network [OSTI]

    Leung, Chin K.

    2010-07-14T23:59:59.000Z

    modeling with an average diffusion coefficient and with determined viscoelastic parameters from creep tests agreed well compared to the shrinkage data from experiments, indicating that drying shrinkage of cement paste may be considered as a poroviscoelastic...

  14. Microsoft Word - NETL-TRS-2-2014_Addendum 1 to Foamed Cement...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Addendum 1 to Computed Tomography and Statistical Analysis of Bubble Size Distributions in Atmospheric-Generated Foamed Cement 6 March 2014 Office of Fossil Energy NETL-TRS-2-2014...

  15. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01T23:59:59.000Z

    Potential (GWh) CO2 Emission Reduction Potential (kt CO 2 )Fuel Savings (TJ) CO2 Emission Reduction Potential (kt COPotentials and CO2 Emission Reductions in 16 Studied Cement

  16. Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry

    E-Print Network [OSTI]

    Ke, Jing

    2013-01-01T23:59:59.000Z

    Energy Savings and CO2 Emissions Reduction of China’s CementEnergy Savings and CO2 Emissions Reduction of China’s Cementenergy savings and CO2 emission reduction potentials are

  17. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01T23:59:59.000Z

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0[sub 2],B[sub 2]O[sub 3],A1[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O,Li[sub 2]O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  18. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01T23:59:59.000Z

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0{sub 2},B{sub 2}O{sub 3},A1{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O,Li{sub 2}O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  19. Laboratory-Scale Melter for Determination of Melting Rate of Waste Glass Feeds

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, Michael J.; Buchmiller, William C.; Matyas, Josef

    2012-01-09T23:59:59.000Z

    The purpose of this study was to develop the laboratory-scale melter (LSM) as a quick and inexpensive method to determine the processing rate of various waste glass slurry feeds. The LSM uses a 3 or 4 in. diameter-fused quartz crucible with feed and off-gas ports on top. This LSM setup allows cold-cap formation above the molten glass to be directly monitored to obtain a steady-state melting rate of the waste glass feeds. The melting rate data from extensive scaled-melter tests with Hanford Site high-level wastes performed for the Hanford Tank Waste Treatment and Immobilization Plant have been compiled. Preliminary empirical model that expresses the melting rate as a function of bubbling rate and glass yield were developed from the compiled database. The two waste glass feeds with most melter run data were selected for detailed evaluation and model development and for the LSM tests so the melting rates obtained from LSM tests can be compared with those from scaled-melter tests. The present LSM results suggest the LSM setup can be used to determine the glass production rates for the development of new glass compositions or feed makeups that are designed to increase the processing rate of the slurry feeds.

  20. Effects of composition and exposure on the solar reflectance of Portland cement concrete

    SciTech Connect (OSTI)

    Levinson, Ronnen; Akbari, Hashem

    2001-12-21T23:59:59.000Z

    Increasing the solar reflectance (albedo) of a paved surface keeps it cooler in the sun, reducing convection of heat from pavement to air and thereby decreasing the ambient air temperature. Simulations of the influence of pavement albedo on air temperature in Los Angeles predict that increasing the albedo of 1,250 km2 of pavement by 0.25 would save cooling energy worth $15M yr-1, and reduce smog-related medical and lost-work expenses by $76M yr-1. Most sidewalks and a small fraction of roads and parking areas are paved with portland cement concrete, which can be made quite reflective through suitable choice of cement and aggregate. Variations with composition and environmental exposure of the albedos of portland cement concrete pavements were investigated through laboratory fabrication and exposure of 32 mixes of concrete. Twenty-four mixes yielded substandard, ''rough'' concretes due to high, unmet aggregate water demand. The albedos of the remaining eight ''smooth'' concrete mixes ranged from 0.41 to 0.77 (mean 0.59). Simulated weathering, soiling, and abrasion each reduced average concrete albedo (mean decreases 0.06, 0.05, and 0.19, respectively), though some samples became slightly more reflective through weathering or soiling. Simulated rain (wetting) strongly depressed the albedos of concretes (mean decrease 0.23) until their surfaces were dried. Concrete albedo grew as the cement hydration reaction progressed (mean increase 0.08), but stabilized within six weeks of casting. White-cement concretes were on average significantly more reflective than gray-cement concretes. The albedo of the most-reflective white-cement concrete was 0.18 to 0.39 higher than that of the most-reflective gray-cement concrete, depending on state of exposure. Concrete albedo generally correlated with cement albedo and sand albedo, and, after abrasion, with rock albedo. Cement albedo had a disproportionately strong influence on the reflectance of concrete. Efflorescence and surface carbonation whitened some gray-cement mixes.

  1. COMPANY CONFIDENTIAL CEMENT-BASED MATRIX-GRID

    E-Print Network [OSTI]

    Mobasher, Barzin

    °C (ASTM C1560). Specimen Dimensions:50x300x9mm 5 replicate samples tested per age, and fabric orientation. Glass plate Machined Aluminum bar Double sided tape Specimen Spacer bar End plate #12;COMPANY in saturated Ca(OH)2 solution at 80°C (ASTM C1560). Sample Dimensions: 75x300x9mm 5 replicate samples tested

  2. Submicron carbon filament cement-matrix composites for electromagnetic interference shielding

    SciTech Connect (OSTI)

    Fu, X.; Chung, D.D.L. [State Univ. of New York, Buffalo, NY (United States). Composite Materials Research Lab.] [State Univ. of New York, Buffalo, NY (United States). Composite Materials Research Lab.

    1996-10-01T23:59:59.000Z

    Carbon filaments of diameter 0.1 mm were found to be a much more effective additive than conventional carbon fibers of diameter 10 mm in providing cement pastes capable of electromagnetic interference shielding. With 0.54 vol. % filaments and a shield thickness of 4 mm, a shielding effectiveness of 30 dB was attained at 1--2 GHz. However, the filaments were less effective than the fibers for reinforcing and for providing strain sensing cement-matrix composites.

  3. The physical and chemical aspects of the leaching behavior of metals from portland cement

    E-Print Network [OSTI]

    Davis, Ricardo Corye

    1990-01-01T23:59:59.000Z

    THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemistry THE PHYSICAL AND CHEMICAL ASPECTS OF THE LEACHING BEHAVIOR OF METALS FROM PORTLAND CEMENT A Thesis by RICARDO CORYE DAVIS Approved as to style and content by: David L. Cocke (Co...

  4. Determining the effective diffusivity of ions in hazardous wastes solidified by portland cement

    E-Print Network [OSTI]

    Taffinder, Glen Gregory

    1991-01-01T23:59:59.000Z

    DETERMINING THE EFFECTIVE DIFFUSIVITY OF TONS IN HAZARDOUS WASTES SOLIDIFIED BY PORTLAND CEMENT A Thesis by GLEN GREGORY TAFFINDER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Civil Engineering DETERMINING THE EFFECTIVE DIFFUSIVITY OF TONS IN HAZARDOUS WASTES SOLIDIFIED BY PORTLAND CEMENT A Thesis by GLEN GREGORY TAFFINDER Approved as to scyle and content by: Bill...

  5. Preliminary non-destructive assessment of moisture content, hydration and dielectric properties of Portland cement concrete

    E-Print Network [OSTI]

    Avelar Lezama, Ivan

    2007-04-25T23:59:59.000Z

    PRELIMINARY NON-DESTRUCTIVE ASSESSMENT OF MOISTURE CONTENT, HYDRATION AND DIELECTRIC PROPERTIES OF PORTLAND CEMENT CONCRETE A Thesis by IVAN AVELAR LEZAMA Submitted to the Office of Graduate Studies of Texas A... AND DIELECTRIC PROPERTIES OF PORTLAND CEMENT CONCRETE A Thesis by IVAN AVELAR LEZAMA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

  6. Evaluation of defense-waste glass produced by full-scale vitrification equipment

    SciTech Connect (OSTI)

    Lukacs, J.M.; Petkus, L.L.; Mellinger, G.B.

    1981-09-01T23:59:59.000Z

    Three full-scale vitrification processes at the Pacific Northwest Laboratory produced over 67,000 kg of simulated nuclear-waste glass from March 1979 to August 1980. Samples were analyzed to monitor process operation and evaluate the resulting glass product. These processes are: Spray Calciner/In-Can Melter (SC/ICM); Spray Calciner/Calcine-Fed Ceramic Melter (SC/CFCM); and Liquid-Fed Ceramic Melter (LFCM). Waste components in the process feed varied less than +- 10%. The SC/ICM and SC/CFCM which use separate waste and frit feed systems showed larger glass compositional variation than the LFCM, which processed only premixed feed during this period. The SC/ICM and SC/CFCM product contained significant amounts of acmite crystals, while the LFCM product was largely amorphous. In addition, the lower portion of all SC/ICM-filled canisters contained a zone rich in waste components. A product chemical durability as determined by pH4 and soxhlet leach tests varied considerably. Aside from increased durability under pH4 conditions with decreasing waste content, glass composition, microstructure and melting process did not correlate with glass durability. For all samples analyzed, the weight loss under pH4 conditions ranged from 17.7 to 85.2 wt %. Soxhlet conditions produced weight losses from 1.78 to 3.56 wt %.

  7. Percutaneous Extraction of Cement Leakage After Vertebroplasty Under CT and Fluoroscopy Guidance: A New Technique

    SciTech Connect (OSTI)

    Amoretti, Nicolas, E-mail: amorettinicolas@yahoo.fr; Huwart, Laurent, E-mail: huwart.laurent@wanadoo.fr [Centre Hospitalo-Universitaire de Nice, Department of Radiology (France)

    2012-12-15T23:59:59.000Z

    Purpose: We report a new minimally invasive technique of extraction of cement leakage following percutaneous vertebroplasty in adults. Methods: Seven adult patients (five women, two men; mean age: 81 years) treated for vertebral compression fractures by percutaneous vertebroplasty had cement leakage into perivertebral soft tissues along the needle route. Immediately after vertebroplasty, the procedure of extraction was performed under computed tomography (CT) and fluoroscopy guidance: a Chiba needle was first inserted using the same route as the vertebroplasty until contact was obtained with the cement fragment. This needle was then used as a guide for an 11-gauge Trocar t'am (Thiebaud, France). After needle withdrawal, a 13-gauge endoscopy clamp was inserted through the cannula to extract the cement fragments. The whole procedure was performed under local anesthesia. Results: In each patient, all cement fragments were withdrawn within 10 min, without complication. Conclusions: This report suggests that this CT- and fluoroscopy-guided percutaneous technique of extraction could reduce the rate of cement leakage-related complications.

  8. Reactive cluster model of metallic glasses

    SciTech Connect (OSTI)

    Jones, Travis E. [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States) [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States); School of Physics, The University of Sydney, Sydney, New South Wales 2006 (Australia); Miorelli, Jonathan; Eberhart, Mark E. [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States)] [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States)

    2014-02-28T23:59:59.000Z

    Though discovered more than a half century ago metallic glasses remain a scientific enigma. Unlike crystalline metals, characterized by short, medium, and long-range order, in metallic glasses short and medium-range order persist, though long-range order is absent. This fact has prompted research to develop structural descriptions of metallic glasses. Among these are cluster-based models that attribute amorphous structure to the existence of clusters that are incommensurate with crystalline periodicity. Not addressed, however, are the chemical factors stabilizing these clusters and promoting their interconnections. We have found that glass formers are characterized by a rich cluster chemistry that above the glass transformation temperature promotes exchange as well as static and vibronic sharing of atoms between clusters. The vibronic mechanism induces correlated motions between neighboring clusters and we hypothesize that the distance over which these motions are correlated mediates metallic glass stability and influences critical cooling rates.

  9. Incorporating Cold Cap Behavior in a Joule-heated Waste Glass Melter Model

    SciTech Connect (OSTI)

    Varija Agarwal; Donna Post Guillen

    2013-08-01T23:59:59.000Z

    In this paper, an overview of Joule-heated waste glass melters used in the vitrification of high level waste (HLW) is presented, with a focus on the cold cap region. This region, in which feed-to-glass conversion reactions occur, is critical in determining the melting properties of any given glass melter. An existing 1D computer model of the cold cap, implemented in MATLAB, is described in detail. This model is a standalone model that calculates cold cap properties based on boundary conditions at the top and bottom of the cold cap. Efforts to couple this cold cap model with a 3D STAR-CCM+ model of a Joule-heated melter are then described. The coupling is being implemented in ModelCenter, a software integration tool. The ultimate goal of this model is to guide the specification of melter parameters that optimize glass quality and production rate.

  10. Method of manufacturing a glass parabolic-cylindrical solar collector

    SciTech Connect (OSTI)

    Deminet, C.

    1980-12-09T23:59:59.000Z

    The method includes the following steps: (1) a microsheet of glass is drawn from a glass melt; (2) a reflective layer, such as silver, is deposited on one surface of the microsheet; (3) a first flexible backing layer, such as fiberglass, is bonded to the reflective layer; (4) the combination of the microsheet with the reflective layer and the first backing layer is formed over a mandrel which is preferably in the form of a parabolic cylinder; and (5) a honeycombed layer, with a second fiberglass backing layer, is then bonded to the first backing layer. The product produced by the steps 1-5 is then cured so that it retains the desired configuration; i.e. parabolic-cylindrical, after it is removed from the mandrel.

  11. Glass Property Data and Models for Estimating High-Level Waste Glass Volume

    SciTech Connect (OSTI)

    Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

    2009-10-05T23:59:59.000Z

    This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

  12. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28T23:59:59.000Z

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  13. Denaturing Urea PAGE -Large Gel Preparation of Glass Plates

    E-Print Network [OSTI]

    Aris, John P.

    for short glass plate. Wear gloves. 3. Place long glass plate on 2 foam rectangles. Set up spacers and short32 Denaturing Urea PAGE - Large Gel Preparation of Glass Plates 1. Clean glass plates and comb pipette, add 5 drops of dichlorodimethylsilane (Aldrich D6,082-6) to 5 mls of acetone in diposable glass

  14. Compliant Glass Seals for SOFC Stacks

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Xu, Wei; Stephens, Elizabeth V.; Koeppel, Brian J.; Stevenson, Jeffry W.; Lara-Curzio, Edgar

    2014-04-01T23:59:59.000Z

    This report summarizes results from experimental and modeling studies performed by participants in the Solid-State Energy Conversion Alliance (SECA) Core Technology Program, which indicate that compliant glass-based seals offer a number of potential advantages over conventional seals based on de-vitrifying glasses, including reduced stresses during stack operation and thermal cycling, and the ability to heal micro-damage induced during thermal cycling. The properties and composition of glasses developed and/or investigated in these studies are reported, along with results from long-term (up to 5,800h) evaluations of seals based on a compliant glass containing ceramic particles or ceramic fibers.

  15. Development of Vitrification Process and Glass Formulation for Nuclear Waste Conditioning

    SciTech Connect (OSTI)

    Petitjean, V.; Fillet, C.; Boen, R.; Veyer, C.; Flament, T.

    2002-02-26T23:59:59.000Z

    The vitrification of high-level waste is the internationally recognized standard to minimize the impact to the environment resulting from waste disposal as well as to minimize the volume of conditioned waste to be disposed of. COGEMA has been vitrifying high-level waste industrially for over 20 years and is currently operating three commercial vitrification facilities based on a hot metal crucible technology, with outstanding records of safety, reliability and product quality. To further increase the performance of vitrification facilities, CEA and COGEMA have been developing the cold crucible melter technology since the beginning of the 1980s. This type of melter is characterized by a virtually unlimited equipment service life and a great flexibility in dealing with various types of waste and allowing development of high temperature matrices. In complement of and in parallel with the vitrification process, a glass formulation methodology has been developed by the CEA in order to tailor matrices for the wastes to be conditioned while providing the best adaptation to the processing technology. The development of a glass formulation is a trade-off between material properties and qualities, technical feasibility, and disposal safety criteria. It involves non-radioactive and radioactive laboratories in order to achieve a comprehensive matrix qualification. Several glasses and glass ceramics have thus been studied by the CEA to be compliant with industrial needs and waste characteristics: glasses or other matrices for a large spectrum of fission products, or for high contents of specifics elements such as sodium, phosphate, iron, molybdenum, or actinides. New glasses or glass-ceramics designed to minimize the final wasteform volume for solutions produced during the reprocessing of high burnup fuels or to treat legacy wastes are now under development and take benefit from the latest CEA hot-laboratories and technology development. The paper presents the CEA state-of-the-art in developing matrices or glasses and provides several examples.

  16. Introduction and Motivation Structural Model for Laminated Glass Beams Conclusions and Outlook of Laminated Glass Structures

    E-Print Network [OSTI]

    Components of Crystalline Solar Modules back sheet or glass encapsulant electrical conductor crystalline solar cells encapsulant front glass Reference: Schulze, S.-H.; Pander, M.; Naumenko, K.; Altenbach, H and Motivation Components of Thin Film Solar Modules back sheet or glass encapsulant electrical conductor thin

  17. Alteration of basaltic glasses from north-central British Columbia, Canada

    SciTech Connect (OSTI)

    Jercinovic, M.J. (Univ. of New Mexico, Albuquerque (USA)); Keil, K. (Univ. of Hawaii at Manoa, Honolulu (USA)); Smith, M.R.; Schmitt, R.A. (Oregon State Univ., Corvallis (USA))

    1990-10-01T23:59:59.000Z

    Evidence of palagonitization is seen on all glasses studied from three Pleistocene subglacial volcanoes in north-central British Columbia, Canada. Samples from foreset breccias of Tuya Butte are more highly palagonitized than those from the tephra cones of Ash Mountain and Southern Tuya. Extensive palagonitization is generally associated with authigenic mineralization (clays, zeolites). Palagonite composition varies widely relative to glass composition, and palagonite can be broadly categorized as either high-Al or low-Al, depending on whether Al was retained or lost to aqueous solutions during palagonitization. Loss of Al during palagonitization is related to closed-system alteration, including precipitation of aluminosilicate authigenic cements. Microenvironment appears to be more influential than macroenvironment in determining the composition of palagonite. Palagonite rinds are compositionally zoned, generally becoming progressively higher in Al and Ca, and lower in Fe and Mg, towards the innermost (later-formed) portions of the rinds. Phillipsite is the first zeolite formed, followed by chabazite. Analcime and calcite occur in the most highly palagonitized samples. Mass balance considerations indicate higher mass loss where palagonitization has not proceeded to the point where zeolite solubility limits were attained in the local solution. Zeolites occur in closed-system conditions (low flow rates), where little net system mass loss or gain has occurred. The colloidal nature of palagonite allows the effective adsorption of Rb, Cs, Sr, Ba, and REEs.

  18. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Cement Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    Wang, L. , 2008. Alternative fuel using and waste materialPolicy Research on Alternative Fuels for Cement Industry inis very little use of alternative fuels (defined as waste

  19. Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Cement Sector

    E-Print Network [OSTI]

    Sathaye, J.

    2011-01-01T23:59:59.000Z

    Advanced Concepts of Waste Heat Recovery in Cement Plants”building controls, waste heat recovery or adjustable speedquantities of low grade waste heat from the kilns or clinker

  20. Permeability of consolidated incinerator facility wastes stabilized with portland cement

    SciTech Connect (OSTI)

    Walker, B.W.

    2000-04-19T23:59:59.000Z

    The Consolidated Incinerator Facility (CIF) at the Savannah River Site (SRS) burns low-level radioactive wastes and mixed wastes as a method of treatment and volume reduction. The CIF generates secondary waste, which consists of ash and offgas scrubber solution. Currently the ash is stabilized/solidified in the Ashcrete process. The scrubber solution (blowdown) is sent to the SRS Effluent Treatment Facility (ETF) for treatment as wastewater. In the past, the scrubber solution was also stabilized/solidified in the Ashcrete process as blowcrete, and will continue to be treated this way for listed waste burns and scrubber solutions that do not meet the ETF Waste Acceptance Criteria (WAC). The disposal plan for Ashcrete and special case blowcrete is to bury these containerized waste forms in shallow unlined trenches in E-Area. The WAC for intimately mixed, cement-based wasteforms intended for direct disposal specifies limits on compressive strength and permeability. Simulated waste and actual CIF ash and scrubber solution were mixed in the laboratory and cast into wasteforms for testing. Test results and related waste disposal consequences are given in this report.

  1. Analysis Of The Sludge Batch 7b (Macrobatch 9) DWPF Pour Stream Glass Sample

    SciTech Connect (OSTI)

    Johnson, F. C.; Crawford, C. L.; Pareizs, J. M.

    2013-11-18T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 7b (SB7b), also referred to as Macrobatch 9 (MB9), in January 2012. SB7b is a blend of the heel of Tank 40 from Sludge Batch 7a (SB7a) and the SB7b material that was transferred to Tank 40 from Tank 51. SB7b was processed using Frit 418. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP), which is governed by the DWPF Waste Form Compliance Plan, and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. Two pour stream glass samples were collected while processing SB7b. The samples were transferred to the Savannah River National Laboratory (SRNL) where one was analyzed and the other was archived. The following conclusions were drawn from the analytical results provided in this report: The sum of oxides for the official SB7b pour stream glass is within the Product Composition Control System (PCCS) limits (95-105 wt%); The average calculated Waste Dilution Factor (WDF) for SB7b is 2.3. In general, the measured radionuclide content of the official SB7b pour stream glass is in good agreement with the calculated values from the Tank 40 dried sludge results from the SB7b Waste Acceptance Program Specification (WAPS) sample; As in previous pour stream samples, ruthenium and rhodium inclusions were detected by Scanning Electron Microscopy-Electron Dispersive Spectroscopy (SEM-EDS) in the SB7b pour stream sample; The Product Consistency Test (PCT) results indicate that the official SB7b pour stream glass meets the waste acceptance criteria for durability with a normalized boron release of 0.8 g/L, which is an order of magnitude less than the Environmental Assessment (EA) glass; The measured density of the SB7b pour stream glass was 2.70 g/cm{sup 3}; The Fe{sup 2+}/?Fe ratio of the SB7b pour stream samples was 0.07.

  2. Energy efficiency for greenhouse gas emission reduction in China: The case of the cement industry

    SciTech Connect (OSTI)

    Sinton, J. [Lawrence Berkeley National Lab., Berkeley, CA (United States)

    1996-12-31T23:59:59.000Z

    A project at LBNL has combined two different approaches to investigate changes in efficiency in China`s cement industry, which currently accounts for over 6% of China`s total commercial energy use and over 1% of global carbon emissions. Cement output has doubled over the past five years, and will double again within 15 years. Addressing cement industry carbon emissions will be a key element of any program to control China`s carbon emissions. Macro-level analysis was used to investigate industry-wide trends, and detailed case studies of individual plants illuminated key issues in technology choice that fundamentally affect efficiency. In general, enterprises adopted technologies that increased output and improved quality, and had little regard for energy efficiency, though most new technologies and practices did improve efficiency. Changes in energy prices were a surprisingly weak factor in adoption of efficient technologies. Unexpectedly, many enterprises developed a strong preference for the least fuel-efficient technology, which allows power generation with kiln waste heat. This preference was motivated in a large part by the desire to achieve security in electricity supply, and by some reforms. This alternative has become increasingly popular, and threatens to reverse some progress made in reducing the carbon-intensiveness of China`s cement industry. Foreign technical assistance and more importantly, greater participation in China`s cement industry of foreign cement companies would speed the adoption of large scale very efficient precalciner plants. Paradoxically, improving energy efficiency in China`s cement industry is also a supply-side issue, improved reliability in China`s power network will make the more fuel-efficient alternative more attractive.

  3. SRNL POROUS WALL GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Wicks, G; Leung Heung, L; Ray Schumacher, R

    2008-04-15T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) has developed a new medium for storage of hydrogen and other gases. This involves fabrication of thin, Porous Walled, Hollow Glass Microspheres (PW-HGMs), with diameters generally in the range of 1 to several hundred microns. What is unique about the glass microballons is that porosity has been induced and controlled within the thin, one micron thick walls, on the scale of 10 to several thousand Angstroms. This porosity results in interesting properties including the ability to use these channels to fill the microballons with special absorbents and other materials, thus providing a contained environment even for reactive species. Gases can now enter the microspheres and be retained on the absorbents, resulting in solid-state and contained storage of even reactive species. Also, the porosity can be altered and controlled in various ways, and even used to filter mixed gas streams within a system. SRNL is involved in about a half dozen different programs involving these PW-HGMs and an overview of some of these activities and results emerging are presented.

  4. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, R.K.; Watkins, R.D.

    1988-01-21T23:59:59.000Z

    Glass compositions containing CaO, Al/sub 2/O/sub 3/, B/sub 2/O/sub 3/, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

  5. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

  6. Monitoring and analyzing waste glass compositions

    DOE Patents [OSTI]

    Schumacher, R.F.

    1994-03-01T23:59:59.000Z

    A device and method are described for determining the viscosity of a fluid, preferably molten glass. The apparatus and method use the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality. 2 figures.

  7. Radiation Induced Nanocrystal Formation in Metallic Glasses

    E-Print Network [OSTI]

    Carter, Jesse

    2010-01-14T23:59:59.000Z

    The irradiation of metallic glasses to induce nanocrystallization was studied in two metallic glass compositions, Cu50Zr45Ti5 and Zr55Cu30Al10Ni5. Atomic mobility was described using a model based on localized excess free volume due to displace...

  8. Eyeglass lens made of glass (radiopaque)

    E-Print Network [OSTI]

    Fig. 9-1 Eyeglass lens made of glass (radiopaque) and frame made of metal (radiopaque). #12;Fig. 9-2 Eyeglass lens made of glass (radiopaque) and frame made of plastic (radiolucent). #12;Fig. 9-3 Metal frame of eyeglasses (radiopaque). The eyeglass lens is made of plastic (radiolucent). #12;Fig. 9-4 Cotton roll

  9. Viscous Glass Sealants for SOFC Applications

    SciTech Connect (OSTI)

    Scott Misture

    2012-09-30T23:59:59.000Z

    Two series of silicate glasses that contain gallium as the primary critical component have been identified and optimized for viscous sealing of solid oxide fuel cells operating from 650 to 850°C. Both series of glass sealants crystallize partially upon heat treatment and yield multiphase microstructures that allow viscous flow at temperatures as low as 650°C. A fully amorphous sealant was also developed by isolating, synthesizing and testing a silicate glass of the same composition as the remnant glassy phase in one of the two glass series. Of ~40 glasses tested for longer than 500 hours, a set of 5 glasses has been further tested for up to 1000h in air, wet hydrogen, and against both yttria-stabilized zirconia and aluminized stainless steel. In some cases the testing times reached 2000h. The reactivity testing has provided new insight into the effects of Y, Zr, and Al on bulk and surface crystallization in boro-gallio-silicate glasses, and demonstrated that at least 5 of the newly-developed glasses are viable viscous sealants.

  10. Comparative assessment of TRU waste forms and processes. Volume I. Waste form and process evaluations

    SciTech Connect (OSTI)

    Ross, W.A.; Lokken, R.O.; May, R.P.; Roberts, F.P.; Timmerman, C.L.; Treat, R.L.; Westsik, J.H. Jr.

    1982-09-01T23:59:59.000Z

    This study provides an assesses seven waste forms and eight processes for immobilizing transuranic (TRU) wastes. The waste forms considered are cast cement, cold-pressed cement, FUETAP (formed under elevated temperature and pressure) cement, borosilicate glass, aluminosilicate glass, basalt glass-ceramic, and cold-pressed and sintered silicate ceramic. The waste-immobilization processes considered are in-can glass melting, joule-heated glass melting, glass marble forming, cement casting, cement cold-pressing, FUETAP cement processing, ceramic cold-pressing and sintering, basalt glass-ceramic processing. Properties considered included gas generation, chemical durability, mechanical strength, thermal stability, and radiation stability. The ceramic products demonstrated the best properties, except for plutonium release during leaching. The glass and ceramic products had similar properties. The cement products generally had poorer properties than the other forms, except for plutonium release during leaching. Calculations of the Pu release indicated that the waste forms met the proposed NRC release rate limit of 1 part in 10/sup 5/ per year in most test conditions. The cast-cement process had the lowest processing cost, followed closely by the cold-pressed and FUETAP cement processes. Joule-heated glass melting had the lower cost of the glass processes. In-can melting in a high-quality canister had the highest cost, and cold-pressed and sintered ceramic the second highest. Labor and canister costs for in-can melting were identified. The major contributor to costs of disposing of TRU wastes in a defense waste repository is waste processing costs. Repository costs could become the dominant cost for disposing of TRU wastes in a commercial repository. It is recommended that cast and FUETAP cement and borosilicate glass waste-form systems be considered. 13 figures, 16 tables.

  11. Glass heat pipe evacuated tube solar collector

    DOE Patents [OSTI]

    McConnell, Robert D. (Lakewood, CO); Vansant, James H. (Tracy, CA)

    1984-01-01T23:59:59.000Z

    A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

  12. Gaseous Sulfate Solubility in Glass: Experimental Method

    SciTech Connect (OSTI)

    Bliss, Mary

    2013-11-30T23:59:59.000Z

    Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

  13. Heat capacity at the glass transition

    E-Print Network [OSTI]

    Kostya Trachenko; Vadim Brazhkin

    2010-07-13T23:59:59.000Z

    A fundamental problem of glass transition is to explain the jump of heat capacity at the glass transition temperature $T_g$ without asserting the existence of a distinct solid glass phase. This problem is also common to other disordered systems, including spin glasses. We propose that if $T_g$ is defined as the temperature at which the liquid stops relaxing at the experimental time scale, the jump of heat capacity at $T_g$ follows as a necessary consequence due to the change of system's elastic, vibrational and thermal properties. In this picture, we discuss time-dependent effects of glass transition, and identify three distinct regimes of relaxation. Our approach explains widely observed logarithmic increase of $T_g$ with the quench rate and the correlation of heat capacity jump with liquid fragility.

  14. A consortium approach to glass furnace modeling.

    SciTech Connect (OSTI)

    Chang, S.-L.; Golchert, B.; Petrick, M.

    1999-04-20T23:59:59.000Z

    Using computational fluid dynamics to model a glass furnace is a difficult task for any one glass company, laboratory, or university to accomplish. The task of building a computational model of the furnace requires knowledge and experience in modeling two dissimilar regimes (the combustion space and the liquid glass bath), along with the skill necessary to couple these two regimes. Also, a detailed set of experimental data is needed in order to evaluate the output of the code to ensure that the code is providing proper results. Since all these diverse skills are not present in any one research institution, a consortium was formed between Argonne National Laboratory, Purdue University, Mississippi State University, and five glass companies in order to marshal these skills into one three-year program. The objective of this program is to develop a fully coupled, validated simulation of a glass melting furnace that may be used by industry to optimize the performance of existing furnaces.

  15. Titanium sealing glasses and seals formed therefrom

    DOE Patents [OSTI]

    Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

    1997-12-02T23:59:59.000Z

    Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La{sub 2}O{sub 3}, B{sub 2}O{sub 3}, TiO{sub 2} and Al{sub 2}O{sub 3} in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 2 figs.

  16. Titanium sealing glasses and seals formed therefrom

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

    1997-01-01T23:59:59.000Z

    Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

  17. Bioactive glass coatings for orthopedic metallic implants

    SciTech Connect (OSTI)

    Lopez-Esteban, Sonia; Saiz, Eduardo; Fujino, Sigheru; Oku, Takeo; Suganuma, Katsuaki; Tomsia, Antoni P.

    2003-06-30T23:59:59.000Z

    The objective of this work is to develop bioactive glass coatings for metallic orthopedic implants. A new family of glasses in the SiO2-Na2O-K2O-CaO-MgO-P2O5 system has been synthesized and characterized. The glass properties (thermal expansion, softening and transformation temperatures, density and hardness) are in line with the predictions of established empirical models. The optimized firing conditions to fabricate coatings on Ti-based and Co-Cr alloys have been determined and related to the glass properties and the interfacial reactions. Excellent adhesion to alloys has been achieved through the formation of 100-200 nm thick interfacial layers (Ti5Si3 on Ti-based alloys and CrOx on Co-Cr). Finally, glass coatings, approximately 100 mu m thick, have been fabricated onto commercial Ti alloy-based dental implants.

  18. andesitic glass comparison: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    applications. - Int. J. Solids & Struct. 49 and Motivation Components of Thin Film Solar Modules back sheet or glass encapsulant electrical conductor thin 59 Glass Forming...

  19. ajakirja stained glass: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    applications. - Int. J. Solids & Struct. 49 and Motivation Components of Thin Film Solar Modules back sheet or glass encapsulant electrical conductor thin 122 Glass Forming...

  20. Glass-like thermal conductivity in high efficiency thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glass-like thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to...

  1. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1997-01-01T23:59:59.000Z

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

  2. Conversion of batch to molten glass, I: Volume expansion

    SciTech Connect (OSTI)

    Henager, Samuel H.; Hrma, Pavel R.; Swearingen, Kevin J.; Schweiger, Michael J.; Marcial, Jose; Tegrotenhuis, Nathan E.

    2011-02-01T23:59:59.000Z

    Batches designed to simulate nuclear high-level waste glass were compressed into pellets that were heated at a rate of 5°C/min and photographed to obtain the profile area as a function of temperature. Three types of batches were prepared with different nitrate-carbonate ratios. To determine the impact of the heat supply by an exothermic reaction and the batch expansion, the nitrated batches were prepared with varying addition of sucrose. To obtain the impact of the grain size of the quartz component, the mixed nitrate-carbonate batches were prepared with silica particles ranging in size from 5 µm to 195 µm. One batch containing only carbonates was also tested. Sucrose addition had little effect on the batch expansion, while the size of silica was very influential. The 5-?m grains had a strongest effect, causing the generation of both primary and secondary foam, whereas only secondary foam was produced in batches with grains of 45 µm and larger. The retention of gases evolved as the batch melts creates primary foam. Gases evolved from oxidation-reduction reactions once the batch has melted produce secondary foam. We suggest that the viscosity of the melt and the amount of gas evolved are the main influences on foam production. As more gas is produced in the melt and as the glass becomes less viscous, the bubbles of gas coalesce into larger and larger cavities, until the glass can no longer contain the bubbles and they burst, causing the foam to collapse.

  3. In-situ early-age hydration study of sulfobelite cements by synchrotron powder diffraction

    SciTech Connect (OSTI)

    Álvarez-Pinazo, G.; Cuesta, A.; García-Maté, M.; Santacruz, I.; Losilla, E.R. [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain)] [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain); Sanfélix, S.G. [Unidad Técnica de Investigación de Materiales, AIDICO, Avda. Benjamín Franklin, 17 Paterna, Valencia (Spain)] [Unidad Técnica de Investigación de Materiales, AIDICO, Avda. Benjamín Franklin, 17 Paterna, Valencia (Spain); Fauth, F. [CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain)] [CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); Aranda, M.A.G. [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain) [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain); CELLS-Alba synchrotron, Carretera BP 1413, Km. 3.3, E-08290 Cerdanyola, Barcelona (Spain); De la Torre, A.G., E-mail: mgd@uma.es [Departamento de Química Inorgánica, Universidad de Málaga, Campus Teatinos S/N., 29071 Málaga (Spain)

    2014-02-15T23:59:59.000Z

    Eco-friendly belite calcium sulfoaluminate (BCSA) cement hydration behavior is not yet well understood. Here, we report an in-situ synchrotron X-ray powder diffraction study for the first hours of hydration of BCSA cements. Rietveld quantitative phase analysis has been used to establish the degree of reaction (?). The hydration of a mixture of ye'elimite and gypsum revealed that ettringite formation (? ? 70% at 50 h) is limited by ye'elimite dissolution. Two laboratory-prepared BCSA cements were also studied: non-active-BCSA and active-BCSA cements, with ?- and ??{sub H}-belite as main phases, respectively. Ye'elimite, in the non-active-BCSA system, dissolves at higher pace (? ? 25% at 1 h) than in the active-BCSA one (? ? 10% at 1 h), with differences in the crystallization of ettringite (? ? 30% and ? ? 5%, respectively). This behavior has strongly affected subsequent belite and ferrite reactivities, yielding stratlingite and other layered phases in non-active-BCSA. The dissolution and crystallization processes are reported and discussed in detail. -- Highlights: •Belite calcium sulfoaluminate cements early hydration mechanism has been determined. •Belite hydration strongly depends on availability of aluminum hydroxide. •Orthorhombic ye’elimite dissolved at a higher pace than cubic one. •Ye’elimite larger reaction degree yields stratlingite formation by belite reaction. •Rietveld method quantified gypsum, anhydrite and bassanite dissolution rates.

  4. Determining the slag fraction, water/binder ratio and degree of hydration in hardened cement pastes

    SciTech Connect (OSTI)

    Yio, M.H.N., E-mail: marcus.yio11@imperial.ac.uk; Phelan, J.C.; Wong, H.S.; Buenfeld, N.R.

    2014-02-15T23:59:59.000Z

    A method for determining the original mix composition of hardened slag-blended cement-based materials based on analysis of backscattered electron images combined with loss on ignition measurements is presented. The method does not require comparison to reference standards or prior knowledge of the composition of the binders used. Therefore, it is well-suited for application to real structures. The method is also able to calculate the degrees of reaction of slag and cement. Results obtained from an experimental study involving sixty samples with a wide range of water/binder (w/b) ratios (0.30 to 0.50), slag/binder ratios (0 to 0.6) and curing ages (3 days to 1 year) show that the method is very promising. The mean absolute errors for the estimated slag, water and cement contents (kg/m{sup 3}), w/b and s/b ratios were 9.1%, 1.5%, 2.5%, 4.7% and 8.7%, respectively. 91% of the estimated w/b ratios were within 0.036 of the actual values. -- Highlights: •A new method for estimating w/b ratio and slag content in cement pastes is proposed. •The method is also able to calculate the degrees of reaction of slag and cement. •Reference standards or prior knowledge of the binder composition are not required. •The method was tested on samples with varying w/b ratios and slag content.

  5. Evaluation of in-situ cemented backfill performance. Rept. of Investigations/1991

    SciTech Connect (OSTI)

    Tesarik, D.R.; Vickery, J.D.; Seymour, J.B.

    1991-01-01T23:59:59.000Z

    As part of its research program to investigate ways of improving resource recovery and reducing subsidence, researchers from the U.S. Bureau of Mines placed instruments in the B-North ore body of the Cannon Mine, Wenatchee, WA, to monitor cemented backfill and rock deformation during mining. The vibrating-wire guages proved to be reliable and versatile, and approximately half of the instruments are providing data after 2 years of use. A two-dimensional, finite-element model was used to analyze the Cannon Mine's multilevel bench cut-and-fill mining method and predict rock and backfill displacements. The model accurately predicted rock displacements, but the predicted and measured displacements in cemented backfill had a correlation coefficient near zero, indicating that the model should only be used to predict rock displacements and not backfill displacements. A finite-difference model was also used to evaluate the stability of a cemented backfill pillar. Results can be used to conservatively predict backfill stresses, but on-site observations of pillar failures coupled with in situ measurements are needed to make more accurate predictions. An ongoing evaluation of the mining system has indicated that filling the primary stopes tight to the back with cemented backfill allowed these pillars to carry overburden loads soon after the cemented backfill was placed.

  6. COMBINED RETENTION OF MOLYBDENUM AND SULFUR IN SIMULATED HIGH LEVEL WASTE GLASS

    SciTech Connect (OSTI)

    Fox, K.

    2009-10-16T23:59:59.000Z

    This study was undertaken to investigate the effect of elevated sulfate and molybdenum concentrations in nuclear waste glasses. A matrix of 24 glasses was developed and the glasses were tested for acceptability based on visual observations, canister centerline-cooled heat treatments, and chemical composition analysis. Results from the chemical analysis of the rinse water from each sample were used to confirm the presence of SO{sup 2-}{sub 4} and MoO{sub 3} on the surface of glasses as well as other components which might form water soluble compounds with the excess sulfur and molybdenum. A simple, linear model was developed to show acceptable concentrations of SO{sub 4}{sup 2-} and MoO{sub 3} in an example waste glass composition. This model was constructed for scoping studies only and is not ready for implementation in support of actual waste vitrification. Several other factors must be considered in determining the limits of sulfate and molybdenum concentrations in the waste vitrification process, including but not limited to, impacts on refractory and melter component corrosion, effects on the melter off-gas system, and impacts on the chemical durability and crystallization of the glass product.

  7. VOCs and formaldehyde emissions from cleaning products and air Ccilia Solal1,*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    VOCs and formaldehyde emissions from cleaning products and air fresheners Cécilia Solal1: air fresheners, glass cleaners, furniture polishes, toilet products, carpet and floor cleaning Formaldehyde, Volatile organic compounds, Household products, Exposure INTRODUCTION Most indoor air pollutants

  8. INTERNATIONAL STUDY OF ALUMINUM IMPACTS ON CRYSTALLIZATION IN U.S. HIGH LEVEL WASTE GLASS

    SciTech Connect (OSTI)

    Fox, K; David Peeler, D; Tommy Edwards, T; David Best, D; Irene Reamer, I; Phyllis Workman, P; James Marra, J

    2008-09-23T23:59:59.000Z

    The objective of this task was to develop glass formulations for (Department of Energy) DOE waste streams with high aluminum concentrations to avoid nepheline formation while maintaining or meeting waste loading and/or waste throughput expectations as well as satisfying critical process and product performance related constraints. Liquidus temperatures and crystallization behavior were carefully characterized to support model development for higher waste loading glasses. The experimental work, characterization, and data interpretation necessary to meet these objectives were performed among three partnering laboratories: the V.G. Khlopin Radium Institute (KRI), Pacific Northwest National Laboratory (PNNL) and Savannah River National Laboratory (SRNL). Projected glass compositional regions that bound anticipated Defense Waste Processing Facility (DWPF) and Hanford high level waste (HLW) glass regions of interest were developed and used to generate glass compositions of interest for meeting the objectives of this study. A thorough statistical analysis was employed to allow for a wide range of waste glass compositions to be examined while minimizing the number of glasses that had to be fabricated and characterized in the laboratory. The glass compositions were divided into two sets, with 45 in the test matrix investigated by the U.S. laboratories and 30 in the test matrix investigated by KRI. Fabrication and characterization of the US and KRI-series glasses were generally handled separately. This report focuses mainly on the US-series glasses. Glasses were fabricated and characterized by SRNL and PNNL. Crystalline phases were identified by X-ray diffraction (XRD) in the quenched and canister centerline cooled (CCC) glasses and were generally iron oxides and spinels, which are not expected to impact durability of the glass. Nepheline was detected in five of the glasses after the CCC heat treatment. Chemical composition measurements for each of the glasses were conducted following an analytical plan. A review of the individual oxides for each glass revealed that there were no errors in batching significant enough to impact the outcome of the study. A comparison of the measured compositions of the replicates indicated an acceptable degree of repeatability as the percent differences for most of the oxides were less than 5% and percent differences for all of the oxides were less than 10 wt%. Chemical durability was measured using the Product Consistency Test (PCT). All but two of the study glasses had normalized leachate for boron (NL [B]) values that were well below that of the Environmental Assessment (EA) reference glass. The two highest NL [B] values were for the CCC versions of glasses US-18 and US-27 (10.498 g/L and 15.962 g/L, respectively). Nepheline crystallization was identified by qualitative XRD in five of the US-series glasses. Each of these five glasses (US-18, US-26, US-27, US-37 and US-43) showed a significant increase in NL [B] values after the CCC heat treatment. This reduction in durability can be attributed to the formation of nepheline during the slow cooling cycle and the removal of glass formers from the residual glass network. The liquidus temperature (T{sub L}) of each glass in the study was determined by both optical microscopy and XRD methods. The correlation coefficient of the measured XRD TL data versus the measured optical TL data was very good (R{sup 2} = 0.9469). Aside from a few outliers, the two datasets aligned very well across the entire temperature range (829 C to 1312 C for optical data and 813 C to 1310 C for XRD crystal fraction data). The data also correlated well with the predictions of a PNNL T{sub L} model. The correlation between the measured and calculated data had a higher degree of merit for the XRD crystal fraction data than for the optical data (higher R{sup 2} value of 0.9089 versus 0.8970 for the optical data). The SEM-EDS analysis of select samples revealed the presence of undissolved RuO{sub 2} in all glasses due to the low solubility of RuO{sub 2} in borosilicate glass. These

  9. International Best Practices for Pre-Processing and Co-Processing Municipal Solid Waste and Sewage Sludge in the Cement Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    least two seconds. ” The waste heat from the co-processingis drawn from the waste heat of the associated cementSewage sludge drying using waste heat from cement plant flue

  10. Glass for sealing lithium cells

    DOE Patents [OSTI]

    Leedecke, C.J.

    1981-08-28T23:59:59.000Z

    Glass compositions resistant to corrosion by lithium cell electrolyte and having an expansion coefficient of 45 to 85 x 10/sup -70/C/sup -1/ have been made with SiO/sub 2/, 25 to 55% by weight; B/sub 2/O/sub 3/, 5 to 12%; Al/sub 2/O/sub 3/, 12 to 35%; CaO, 5 to 15%; MgO, 5 to 15%; SrO, 0 to 10%; and La/sub 2/O/sub 3/, 0 to 5%. Preferred compositions within that range contain 3 to 8% SrO and 0.5 to 2.5% La/sub 2/O/sub 3/.

  11. Solid oxide fuel cell having a glass composite seal

    DOE Patents [OSTI]

    De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

    2013-04-16T23:59:59.000Z

    A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

  12. Influence of curing temperature on cement hydration and mechanical strength development of fly ash mortars

    SciTech Connect (OSTI)

    Maltais, Y.; Marchand, J. [Univ. Laval, Quebec (Canada). Centre de Recherche Interuniversitaire sur le Beton] [Univ. Laval, Quebec (Canada). Centre de Recherche Interuniversitaire sur le Beton

    1997-07-01T23:59:59.000Z

    The influence of fly ash and curing temperature on cement hydration and compressive strength development of mortars was investigated. Test parameters included type of fly ash (two different Class F fly ashes were tested), the level of cement replacement (10, 20 and 30% by mass), and curing temperature (20 C and 40 C). The mortar physical and microstructural properties were determined by means of thermal analyses, compressive strength measurements and SEM observations. Test results confirm that fly ash tends to increase significantly the rate of cement hydration at early age. Data also demonstrate that an elevation of the curing temperature reduces the long-term compressive strength of the reference mortar mixture. In contrast, an increase of the curing temperature seems to have no detrimental effect on the long-term compressive strength of the fly ash mixtures.

  13. Carbon black: A low cost colloidal additive for controlling gas-migration in cement slurries

    SciTech Connect (OSTI)

    Calloni, G.; Moroni, N.; Miano, F.

    1995-11-01T23:59:59.000Z

    The effect of different additives on the permeability of cement slurries to formation gas has been studied with the aid of a gas flow apparatus. The performance of two commercial additives (polymer latex and silica fume) has been compared to that of a novel additive (carbon black) that has been developed in the authors laboratories with the aim of simplifying the cement slurry composition and reducing field operational costs. Data on the thickening time, fluid loss, rheology and compressive strength are also presented to provide a clear picture of the potential of carbon black as a substitute for silica fume and polymer latex in some field applications. Finally, the paper describes the results of a field application using carbon black as a gas-block additive in the cement slurry.

  14. Effect of composition and temperature on the properties of High-Level Waste (HLW) glasses melting above 1200{degrees}C (Draft)

    SciTech Connect (OSTI)

    Vienna, J.D.; Hrma, P.R.; Schweiger, M.J. [and others

    1996-02-01T23:59:59.000Z

    Increasing the melting temperature of HLW glass allows an increase of waste loading (thus reducing product volume) and the production of more durable glasses at a faster melting rate. However, HLW glasses that melt at high temperatures differ in composition from glasses formulated for low temperature ({approximately}1150{degree}C). Consequently, the composition of high-temperature glasses falls in a region previously not well tested or understood. This report represents a preliminary study of property/composition relationships of high-temperature Hanford HLW glasses using a one-component-at-a-time change approach. A test matrix has been designed to explore a composition region expected for high-temperature high-waste loading HLW glasses to be produced at Hanford. This matrix was designed by varying several key components (SiO{sub 2}, B{sub 2}O{sub 3}, Na{sub 2}O, Li{sub 2}O, Fe{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, ZrO{sub 2}, Bi{sub 2}O{sub 3}, P{sub 2}O{sub 5}, UO{sub 2}, TiO{sub 2}, Cr{sub 2}O{sub 3}, and others) starting from a glass based on a Hanford HLW all-blend waste. Glasses were fabricated and tested for viscosity, glass transition temperature, electrical conductivity, crystallinity, liquidus temperature, and PCT release. The effect of individual components on glass properties was assessed using first- and second- order empirical models. The first-order component effects were compared with those from low-temperature HLW glasses.

  15. Effects of aluminosilicate minerals in clay soil fractions on pore water hydroxide ion concentrations in soil/cement matrices

    E-Print Network [OSTI]

    Cook, Evan Russell

    1998-01-01T23:59:59.000Z

    form of montmorillonite, with 0. 5, 10, 20, and 40 percent bentonite by total, air-dry weight were mixed with Type I Portland cement at 10, 20, and 30 percent cement by weight of air-dry soil. Pore water was expressed and analyzed for hydroxide, calcium...

  16. INTRODUCTION Portland cement concrete (PCC) is the world's most versatile and utilized construction material. Modern concrete consists of six

    E-Print Network [OSTI]

    Harms, Kyle E.

    INTRODUCTION Portland cement concrete (PCC) is the world's most versatile and utilized construction material. Modern concrete consists of six main ingredients: coarse aggregate, sand, portland cement agreement that the use of SCMs has the following effects in concrete: 1. Improved workability and finish

  17. DM100 AND DM1200 MELTER TESTING WITH HIGH WASTE LOADING GLASS FORMULATIONS FOR HANFORD HIGH-ALUMINUM HLW STREAMS

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL; JOSEPH I

    2009-12-30T23:59:59.000Z

    This Test Plan describes work to support the development and testing of high waste loading glass formulations that achieve high glass melting rates for Hanford high aluminum high level waste (HLW). In particular, the present testing is designed to evaluate the effect of using low activity waste (LAW) waste streams as a source of sodium in place ofchemical additives, sugar or cellulose as a reductant, boehmite as an aluminum source, and further enhancements to waste processing rate while meeting all processing and product quality requirements. The work will include preparation and characterization of crucible melts in support of subsequent DuraMelter 100 (DM 100) tests designed to examine the effects of enhanced glass formulations, glass processing temperature, incorporation of the LAW waste stream as a sodium source, type of organic reductant, and feed solids content on waste processing rate and product quality. Also included is a confirmatory test on the HLW Pilot Melter (DM1200) with a composition selected from those tested on the DM100. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy's (DOE's) Office of River Protection (ORP) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same waste composition. This Test Plan is prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is about 12,500. This estimate is based upon the inventory ofthe tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP contract requirements. The WTP's overall mission will require the immobilization oftank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in waste-loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

  18. Temperature Measurement During Polymerization of Bone Cement in Percutaneous Vertebroplasty: An In Vivo Study in Humans

    SciTech Connect (OSTI)

    Anselmetti, Giovanni Carlo, E-mail: giovanni.anselmetti@ircc.it; Manca, Antonio [Institute for Cancer Research and Treatment (IRCC), Interventional Radiology Unit (Italy); Kanika, Khanna; Murphy, Kieran [Johns Hopkins Hospital, Radiology and Radiological Science (United States); Eminefendic, Haris [Institute for Cancer Research and Treatment (IRCC), Radiology Unit (Italy); Masala, Salvatore ['Tor Vergata' University General Hospital, Department of Diagnostic Imaging, Molecular Imaging, Interventional Radiology and Radiotherapy (Italy); Regge, Daniele [Institute for Cancer Research and Treatment (IRCC), Radiology Unit (Italy)

    2009-05-15T23:59:59.000Z

    Aim of the study was to 'in vivo' measure temperature, during percutaneous vertebroplasty (PV), within a vertebral body injected with different bone cements. According to the declaration of Helsinki, 22 women (60-80 years; mean, 75 years) with painful osteoporotic vertebral collapse underwent bilateral transpedicular PV on 22 lumbar vertebrae. Two 10-G vertebroplasty needles were introduced into the vertebra under digital fluoroscopy; a 16-G radiofrequency thermoablation needle (Starburst XL; RITA Medical System Inc., USA), carrying five thermocouples, was than coaxially inserted. Eleven different bone cements were injected and temperatures were measured every 30 s until temperatures dropped under 45{sup o}C. After the thermocouple needle was withdrawn, bilateral PV was completed with cement injection through the vertebroplasty needle. Unpaired Student's t-tests, Kruskal-Wallis test, and Wilcoxon signed rank test were used to evaluate significant differences (p < 0.05) in peak temperatures, variations between cements, and clinical outcome. All procedures were completed without complications, achieving good clinical outcomes (p < 0.0001). Regarding average peak temperature, cements were divided into three groups: A (over 60{sup o}C), B (from 50{sup o} to 60{sup o}C), and C (below 50{sup o}C). Peak temperature in Group A (86.7 {+-} 10.7{sup o}C) was significantly higher (p = 0.0172) than that in Groups B (60.5 {+-} 3.7{sup o}C) and C (44.8 {+-} 2.6{sup o}C). The average of all thermocouples showed an extremely significant difference (p = 0.0002) between groups. None of the tested cements maintained a temperature {>=}45{sup o}C for more than 30 min. These data suggest that back-pain improvement is obtained not by thermal necrosis but by mechanical consolidation only. The relative necrotic thermal effect in vertebral metastases seems to confirm that analgesia must be considered the main intent of PV.

  19. Carbon dioxide emissions from fossil fuel consumption and cement manufacture, 1751-1991; and an estimate of their isotopic composition and latitudinal distribution

    SciTech Connect (OSTI)

    Andres, R.J.; Marland, G.; Boden, T.; Bischof, S.

    1994-10-01T23:59:59.000Z

    This work briefly discusses four of the current research emphases at Oak Ridge National Laboratory regarding the emission of carbon dioxide (CO{sub 2}) from fossil fuel consumption, natural gas flaring and cement manufacture. These emphases include: (1) updating the 1950 to present time series of CO{sub 2} emissions from fossil fuel consumption and cement manufacture, (2) extending this time series back to 1751, (3) gridding the data at 1{sup 0} by 1{sup 0} resolution, and (4) estimating the isotopic signature of these emissions. In 1991, global emissions of CO{sub 2} from fossil fuel and cement increased 1.5% over 1990 levels to 6188 {times} 10{sup 6} metric tonnes C. The Kuwaiti oil fires can account for all of the increase. Recently published energy data (Etemad et al., 1991) allow extension of the CO emissions time series back to 1751. Preliminary examination shows good agreement with two other, but shorter, energy time series. A latitudinal distribution of carbon emissions is being completed. A southward shift in the major mass of CO{sub 2} emissions is occurring from European-North American latitudes towards central-southeast Asian latitudes, reflecting the growth of population and industrialization at these lower latitudes. The carbon isotopic signature of these emissions has been re-examined. The emissions of the last two decades are approximately 1{per_thousand} lighter than previously reported (Tans, 1981). This lightening of the emissions signature is due to fossil fuel gases and liquids, including a revision of their {delta}{sup 13}C isotopic signature and an increased production rate.

  20. THE SLUDGE BATCH 7A GLASS VARIABILITY STUDY WITH FRIT 418 AND FRIT 702

    SciTech Connect (OSTI)

    Peeler, D.; Edwards, T.

    2011-03-24T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) is preparing to initiate processing of Sludge Batch 7a (SB7a) in May 2011. To support qualification of SB7a, the Savannah River National Laboratory (SRNL) was requested to execute a variability study (VS) to assess the applicability of the current Product Composition Control System (PCCS) durability models for the Frit 418-SB7a compositional region of interest. The objective of this study was to demonstrate applicability of the current durability models to the SB7a compositional region of interest and acceptability of the SB7a glasses with respect to the Environmental Assessment (EA) glass in terms of durability as defined by the Product Consistency Test (PCT). To support programmatic objectives, twenty-eight SB7a glasses were selected based on the nominal sludge projections used to support the frit recommendation. Twenty-three of the SB7a VS glasses were based on the use of Frit 418, while 5 glasses were based on the use of Frit 702. Frit 702 was also identified as a viable candidate for SB7a, especially if SO{sub 4} concentrations are found to be higher than anticipated. Frit 702 has shown a higher SO{sub 4} retention capability as compared to Frit 418. With respect to acceptability, the PCT results of the SB7a-VS glasses are acceptable relative to the EA glass regardless of thermal history (quenched or canister centerline cooled) or compositional view (target or measured). More specifically, all of the SB7a glasses have normalized boron release values (NL [B]) less than 0.9 g/L as compared to the benchmark NL [B] value for EA of 16.695 g/L. With respect to the applicability of the current durability models to the SB7a VS compositional region of interest, all of the study glasses (based on target compositions) lie within the 95% confidence intervals of the model predictions. When model applicability is based on the measured compositions, all of the SB7a VS glasses are predictable with the exception of SB7aVS-02 and SB7aVS-06. Although the NL [B] values of these two glasses range from 0.66 to 0.73 g/L (considered very acceptable), the PCT responses are not considered predictable by the current durability models. The current durability models are conservative for these glasses since they are more durable than predicted by the models. These two glasses are extreme vertices (EV) based compositions coupled with Frit 418 at 36% WL and target the maximum Na{sub 2}O content (15.01 wt% Na{sub 2}O) of the SB7a VS glasses. Higher alkali glasses for which the model overpredicts the PCT response have been observed previously in the Sludge Batch 3 (SB3) Phase 1 VS and the Sludge Batch 6 (SB6) VS.

  1. Ghabezloo: Micromechanics analysis of thermal expansion and thermal pressurization of a hardened cement paste Micromechanics analysis of thermal expansion and thermal

    E-Print Network [OSTI]

    Boyer, Edmond

    pore fluid is anomalously higher than the one of pure bulk water. The micromechanics model water-to-cement ratios. It permits also to calculate the pore volume thermal expansion coefficient expansion and thermal pressurization of a hardened cement paste, Cement and Concrete Research, DOI 10.1016/j

  2. Dynamics and rheology of active glasses

    E-Print Network [OSTI]

    T. F. F. Farage; J. M. Brader

    2014-03-07T23:59:59.000Z

    Within the framework of mode-coupling theory, we present a simple model for describing dense assemblies of active (self-propelled) spherical colloidal particles. For isotropic suspensions, we demonstrate that the glass transition is shifted to higher volume fraction by the addition of activity, in agreement with recent Brownian dynamics simulations. Activity-induced changes in the static structure factor of the fluid are predicted. The mechanical response of an active glass to applied strain is shown to be softer than the corresponding passive glass; both the nonergodicity parameter and the yield stress reduce with increasing activity.

  3. A cement kiln flue-dust evaluated as a soil liming material

    E-Print Network [OSTI]

    Stacha, Raimund

    1973-01-01T23:59:59.000Z

    A CEMENT KILN FLUE-DUST EVALUATED AS A SOIl LIMING MATERIAL A Thesis by RAIMUND STACHA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE 1973 NJSbj t...:~StlCh tt A CEMENT KILN FLUE-DUST EVALUATED AS A SOIL I IMING MATERIAL A Thesis by RAIMUND STACHA Approved as to style and content by: (Chairman of Committee) (Head of Department) (Me er) (Member) (Member) (Member) (Member) 1973 ABSTRACT A...

  4. CSER 00-001 Criticality Safety Evaluation Report for Cementation Operations at the PFP

    SciTech Connect (OSTI)

    DOBBIN, K.D.

    2000-04-18T23:59:59.000Z

    Glovebox HA-20MB is located in Room 235B of the 234-5Z Building at the Plutonium Finishing Plant. This enclosure contains mixers, mixer bowls, a crusher unit, an isolated inoperable conveyor unit, plutonium residue feed cans, cemented cans, and a feedwater container. Plutonium residue, not conducive to other forms of stabilization, is prepared for storage and ultimate disposal by cementation. The feed residue material cans can have plutonium contents of only a few grams or up to 200 grams. This evaluation accommodates this wide range of container fissile concentrations.

  5. Soil stabilization and pavement recycling with self-cementing coal fly ash

    SciTech Connect (OSTI)

    NONE

    2008-01-15T23:59:59.000Z

    This manual provides design information for self-cementing coal fly ash as the sole stabilizing agent for a wide range of engineering applications. As in any process, the application of sound engineering practices, appropriate testing, and evaluation of fly ash quality and characteristics will lend themselves to successful projects using the guidelines in this manual. Topics discussed include: self-cementing coal fly ash characteristics; laboratory mix design; stabilization of clay soils; stabilisation of granular materials; construction considerations; high sulfate ash; environmental considerations for fly ash stabilization; design considerations; state specification/guidelines/standards; and a sample of a typical stabilization specification.

  6. Tensile creep of soil-cement and its relationship to fatigue

    E-Print Network [OSTI]

    Kim, Youngsoo

    1985-01-01T23:59:59.000Z

    Creep curves at different temperatures. 19 Log (D(t)-Dz) vs. log t at different temperatures. 68 69 INTRODUCTION Portland cement is an extremely important stabilizing agent for a wide range of soil types. Because of its strength-enhancing property... Mechanics (LEFM) is applicable to the investigation and determination of realistic failure criteria of fine-grained soils stabilized with Portland cement [27]. This is due to the fact that the radius of curvature at the tip of a microcrack is small...

  7. SUMMARY OF FY11 SULFATE RETENTION STUDIES FOR DEFENSE WASTE PROCESSING FACILITY GLASS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2012-05-08T23:59:59.000Z

    This report describes the results of studies related to the incorporation of sulfate in high level waste (HLW) borosilicate glass produced at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). A group of simulated HLW glasses produced for earlier sulfate retention studies was selected for full chemical composition measurements to determine whether there is any clear link between composition and sulfate retention over the compositional region evaluated. In addition, the viscosity of several glasses was measured to support future efforts in modeling sulfate solubility as a function of predicted viscosity. The intent of these studies was to develop a better understanding of sulfate retention in borosilicate HLW glass to allow for higher loadings of sulfate containing waste. Based on the results of these and other studies, the ability to improve sulfate solubility in DWPF borosilicate glasses lies in reducing the connectivity of the glass network structure. This can be achieved, as an example, by increasing the concentration of alkali species in the glass. However, this must be balanced with other effects of reduced network connectivity, such as reduced viscosity, potentially lower chemical durability, and in the case of higher sodium and aluminum concentrations, the propensity for nepheline crystallization. Future DWPF processing is likely to target higher waste loadings and higher sludge sodium concentrations, meaning that alkali concentrations in the glass will already be relatively high. It is therefore unlikely that there will be the ability to target significantly higher total alkali concentrations in the glass solely to support increased sulfate solubility without the increased alkali concentration causing failure of other Product Composition Control System (PCCS) constraints, such as low viscosity and durability. No individual components were found to provide a significant improvement in sulfate retention (i.e., an increase of the magnitude necessary to have a dramatic impact on blending, washing, or waste loading strategies for DWPF) for the glasses studied here. In general, the concentrations of those species that significantly improve sulfate solubility in a borosilicate glass must be added in relatively large concentrations (e.g., 13 to 38 wt % or more of the frit) in order to have a substantial impact. For DWPF, these concentrations would constitute too large of a portion of the frit to be practical. Therefore, it is unlikely that specific additives may be introduced into the DWPF glass via the frit to significantly improve sulfate solubility. The results presented here continue to show that sulfate solubility or retention is a function of individual glass compositions, rather than a property of a broad glass composition region. It would therefore be inappropriate to set a single sulfate concentration limit for a range of DWPF glass compositions. Sulfate concentration limits should continue to be identified and implemented for each sludge batch. The current PCCS limit is 0.4 wt % SO{sub 4}{sup 2-} in glass, although frit development efforts have led to an increased limit of 0.6 wt % for recent sludge batches. Slightly higher limits (perhaps 0.7-0.8 wt %) may be possible for future sludge batches. An opportunity for allowing a higher sulfate concentration limit at DWPF may lay lie in improving the laboratory experiments used to set this limit. That is, there are several differences between the crucible-scale testing currently used to define a limit for DWPF operation and the actual conditions within the DWPF melter. In particular, no allowance is currently made for sulfur partitioning (volatility versus retention) during melter processing as the sulfate limit is set for a specific sludge batch. A better understanding of the partitioning of sulfur in a bubbled melter operating with a cold cap as well as the impacts of sulfur on the off-gas system may allow a higher sulfate concentration limit to be established for the melter feed. This approach would have to be taken carefully to ensure that a

  8. A Signal-Inducing Bone Cement for Magnetic Resonance Imaging-Guided Spinal Surgery Based on Hydroxyapatite and Polymethylmethacrylate

    SciTech Connect (OSTI)

    Wichlas, Florian, E-mail: florian.wichlas@charite.de; Seebauer, Christian J.; Schilling, Rene [University Charite, Center for Musculoskeletal Surgery (Germany); Rump, Jens [University Charite, Department of Radiology (Germany); Chopra, Sascha S. [University Charite, Center for Musculoskeletal Surgery (Germany); Walter, Thula; Teichgraeber, Ulf K. M. [University Charite, Department of Radiology (Germany); Bail, Hermann J. [University Charite, Center for Musculoskeletal Surgery (Germany)

    2012-06-15T23:59:59.000Z

    The aim of this study was to develop a signal-inducing bone cement for magnetic resonance imaging (MRI)-guided cementoplasty of the spine. This MRI cement would allow precise and controlled injection of cement into pathologic lesions of the bone. We mixed conventional polymethylmethacrylate bone cement (PMMA; 5 ml methylmethacrylate and 12 g polymethylmethacrylate) with hydroxyapatite (HA) bone substitute (2-4 ml) and a gadolinium-based contrast agent (CA; 0-60 {mu}l). The contrast-to-noise ratio (CNR) of different CA doses was measured in an open 1.0-Tesla scanner for fast T1W Turbo-Spin-Echo (TSE) and T1W TSE pulse sequences to determine the highest signal. We simulated MRI-guided cementoplasty in cadaveric spines. Compressive strength of the cements was tested. The highest CNR was (1) 87.3 (SD 2.9) in fast T1W TSE for cements with 4 {mu}l CA/ml HA (4 ml) and (2) 60.8 (SD 2.4) in T1W TSE for cements with 1 {mu}l CA/ml HA (4 ml). MRI-guided cementoplasty in cadaveric spine was feasible. Compressive strength decreased with increasing amounts of HA from 46.7 MPa (2 ml HA) to 28.0 MPa (4 ml HA). An MRI-compatible cement based on PMMA, HA, and CA is feasible and clearly visible on MRI images. MRI-guided spinal cementoplasty using this cement would permit direct visualization of the cement, the pathologic process, and the anatomical surroundings.

  9. The effect of chemical composition on the PCT durability of mixed waste glasses from wastewater treatment sludges

    SciTech Connect (OSTI)

    Resce, J.L.; Ragsdale, R.G.; Overcamp, T.J. [Clemson Univ., SC (United States); Bickford, D.F.; Cicero, C.A. [Savannah River Technology Center, Aiken, SC (United States)

    1995-01-25T23:59:59.000Z

    An experimental program has been designed to examine the chemical durability of glass compositions derived from the vitrification of simulated wastewater treatment sludges. These sludges represent the majority of low-level mixed wastes currently in need of treatment by the US DOE. The major oxides in these model glasses included SiO{sub 2}, Al{sub 2}O{sub 3}, B{sub 2}O{sub 3}, Na{sub 2}O, CaO and Fe{sub 2}O{sub 3}. In addition, three minor oxides, BaO, NiO, and PbO, were added as hazardous metals. The major oxides were each varied at two levels resulting in 32 experimental glasses. The chemical durability was measured by the 7-Day Product Consistency Test (PCT). The normalized sodium release rates (NRR{sub Na}) of these glasses ranged from 0.01 to 4.99 g/m{sup 2}. The molar ratio of the glass-former to glass-modifier (F/M) was found to have the greatest effect on PCT durability. Glass-formers included SiO{sub 2}, Al{sub 2}O{sub 3}, and B{sub 2}O{sub 3}, while Na{sub 2}O, CaO, BaO, NiO, and PbO were glass-modifiers. As this ratio increased from 0.75 to 2.0, NRR{sub Na} was found to decrease between one and two orders of magnitude. Another important effect on NRR{sub Na} was the Na{sub 2}O/CaO ratio. As this ratio increased from 0.5 to 2.0, NRR{sub Na} increased up to two orders of magnitude for the glasses with the low F/M ratio but almost no effect was observed for the glasses with the high F/M ratio. Increasing the iron oxide content from 2 to 18 mole% was found to decrease NRR{sub Na} one order of magnitude for the glasses with low F/M but iron had little effect on the glasses with the high F/M ratio. The durability also increased when 10 mole percent Al{sub 2}O{sub 3} was included in low iron oxide glasses but no effect was observed with the high iron glasses. The addition of B{sub 2}O{sub 3} had little effect on durability. The effects of other composition parameters on durability are discussed as well.

  10. Glass/polymer composites and methods of making

    DOE Patents [OSTI]

    Samuels, W. D. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

    1995-01-01T23:59:59.000Z

    The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

  11. FLUIDIZED BED STEAM REFORMER (FBSR) PRODUCT: MONOLITH FORMATION AND CHARACTERIZATION

    SciTech Connect (OSTI)

    Jantzen, C

    2006-09-13T23:59:59.000Z

    The most important requirement for Hanford's low activity waste (LAW) form for shallow land disposal is the chemical durability of the product. A secondary, but still essential specification, is the compressive strength of the material with regards to the strength of the material under shallow land disposal conditions, e.g. the weight of soil overburden and potential intrusion by future generations, because the term ''near-surface disposal'' indicates disposal in the uppermost portion, or approximately the top 30 meters, of the earth's surface. The THOR{reg_sign} Treatment Technologies (TTT) mineral waste form for LAW is granular in nature because it is formed by Fluidized Bed Steam Reforming (FBSR). As a granular product it has been shown to be as durable as Hanford's LAW glass during testing with ASTM C-1285-02 known as the Product Consistency Test (PCT) and with the Single Pass Flow Through Test (SPFT). Hanford Envelope A and Envelope C simulants both performed well during PCT and SPFT testing and during subsequent performance assessment modeling. This is partially due to the high aluminosilicate content of the mineral product which provides a natural aluminosilicate buffering mechanism that inhibits leaching and is known to occur in naturally occurring aluminosilicate mineral analogs. In order for the TTT Na-Al-Si (NAS) granular mineral product to meet the compressive strength requirements (ASTM C39) for a Hanford waste form, the granular product needs to be made into a monolith or disposed of in High Integrity Containers (HIC's). Additionally, the Hanford intruder scenario for disposal in the Immobilized Low Activity Waste (ILAW) trench is mitigated as there is reduced intruder exposure when a waste form is in a monolithic form. During the preliminary testing of a monolith binder for TTT's FBSR mineral product, four parameters were monitored: (1) waste loading (not optimized for each waste form tested); (2) density; (3) compressive strength; and (4) durability must not be compromised--binding agent should not react with the NAS product and binding agent should not create an unfavorable pH environment that may cause accelerated leaching. It is the goal of the present study to survey cementitious waste forms based on Ordinary Portland Cement (OPC), Ceramicrete, and hydroceramic binders by correlating waste loading, density and compressive strength and then determine if these binders affect the product performance in terms of the PCT response. This will be done by making a one-to-one comparison of the PCT response measured on granular NAS mineral product (mixed bed and fines products) with the PCT response of the monolithed NAS product in the different binders. Future studies may include, refining the above binders, and examining other binders. It is likely that binders formed from kaolin would be most compatible with the chemistry of the THOR{reg_sign} mineral waste form which is made by steam reforming of kaolin and sodium rich wastes. The economics of production on a large scale have yet to be investigated for any of the binders tested.

  12. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    Utilization of Oil Shale Energy and Oil Shale Mineralsand Other Hydraulic Minerals. Oil Shale, Vol. 20, No. 3, pp.15 3.3.4. Calcareous Oil Shale as an Alternative Raw

  13. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    Looping Technology Description: Amine scrubbing carboncarbon capture using absorption technologies Calera process CO 2 sequestration in concrete curing technology Carbonate looping

  14. Evaluation of Life-Cycle Assessment Studies of Chinese Cement Production: Challenges and Opportunities

    E-Print Network [OSTI]

    Lu, Hongyou

    2010-01-01T23:59:59.000Z

    system boundary, data sources, data quality assessment, data disaggregation and other elements. The Development of Life Cycle

  15. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    processes to reduce the carbon footprint of concrete. Thelargest share of energy and carbon footprint of the concreteproduct have a negative carbon footprint because they are

  16. Evaluation of Life-Cycle Assessment Studies of Chinese Cement Production: Challenges and Opportunities

    E-Print Network [OSTI]

    Lu, Hongyou

    2010-01-01T23:59:59.000Z

    The use of life-cycle assessment (LCA) to understand theIntroduction Life-cycle assessment (LCA) is an important

  17. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    and/or used in enhanced oil recovery. This technology can beCO 2 for underground storage, enhanced oil recovery or other

  18. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01T23:59:59.000Z

    technology would be more economical in new plants because retrofits would involve removal of existing

  19. Glass bead micromodel study of solute transport

    E-Print Network [OSTI]

    Fedirchuk, Paula Diane

    1995-01-01T23:59:59.000Z

    This study presents the quantification of glass bead micromodel experiments through a combination of computational modeling and experimental analysis. The computational model simulates two-dimensional solute flow through porous media using a finite...

  20. Neutron Brillouin scattering in a metallic glass

    SciTech Connect (OSTI)

    Suck, J.B. (Kernforschungszentrum Karlsruhe GmbH (Germany). Inst. fuer Nukleare Festkoerperphysik); Egelstaff, P.A. (Guelph Univ., ON (Canada). Dept. of Physics); Robinson, R.A.; Sivia, D.S. (Los Alamos National Lab., NM (United States)); Taylor, A.D. (Rutherford Appleton Lab., Chilton (United Kingdom))

    1991-01-01T23:59:59.000Z

    The dispersion of collective modes in a metallic glass (Mg{sub 70}Zn{sub 30}) measured earlier at the thermal neutron time-of-flight spectrometer IN4 of the HFR of the ILL could be extended towards lower momentum transfers down to the first pseudo-Brillouin zone for the first time. This extension to momentum transfer not accessible up to now was possible using the highly resolving time-of-flight spectrometer HET of the new spallation source ISIS. In the region of overlap the two parts of the dispersion determined with different samples of the same metallic glass on different instruments agree very well. Also the earlier discrepancies with the dispersion determined for this metallic glass from a computer simulation could be nearly completely eliminated due to a more recent and more complete investigations of this glass.

  1. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, B.R.; McBranch, D.W.; Robinson, J.M.; Koskelo, A.C.; Love, S.P.

    1995-05-30T23:59:59.000Z

    Synthesis of fullerene/glass composites is described. A direct method for preparing solid solutions of C{sub 60} in silicon dioxide (SiO{sub 2}) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these ``guests`` in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C{sub 60}. Depending upon the preparative procedure, C{sub 60} dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C{sub 60} in a solid glass matrix, is generated by the present method.

  2. Measurement of DWPF glass viscosity - Final Report

    SciTech Connect (OSTI)

    Harbour, J.R.

    2000-02-17T23:59:59.000Z

    This report details the results of a scoping study funded by the Defense Waste Processing Facility (DWPF) for the measurement of melt viscosities for simulated glasses representative of Macrobatch 2 (Tank 42/51 feed).

  3. Energy Assessment Protocol for Glass Furnaces

    E-Print Network [OSTI]

    Plodinec, M. J.; Kauffman, B. M.; Norton, O. P.; Richards, C.; Connors, J.; Wishnick, D.

    2005-01-01T23:59:59.000Z

    The Department of Energy funded development of a methodology that could be used by glass producers to increase furnace efficiency, and that could serve as a model for other energy-intensive industries. Accordingly, a team comprising PPG Industries...

  4. Tiny Glass Bubbles With Big Potential

    Broader source: Energy.gov [DOE]

    If these glass microspheres' walls could talk…They would explain how their tiny pores allow the potential for handling, storing and transporting a variety of materials, including drugs that have...

  5. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, Benjamin R. (Santa Fe, NM); McBranch, Duncan W. (Santa Fe, NM); Robinson, Jeanne M. (Los Alamos, NM); Koskelo, Aaron C. (Los Alamos, NM); Love, Steven P. (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    Synthesis of fullerene/glass composites. A direct method for preparing solid solutions of C.sub.60 in silicon dioxide (SiO.sub.2) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these "guests" in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C.sub.60. Depending upon the preparative procedure, C.sub.60 dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C.sub.60 in a solid glass matrix, is generated by the present method.

  6. MELT RATE ENHANCEMENT FOR HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASS FORMULATION FINAL REPORT 08R1360-1

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT W; PEGG IL; JOSEPH I; BARDAKCI T; GAN H; GONG W; CHAUDHURI M

    2010-01-04T23:59:59.000Z

    This report describes the development and testing of new glass formulations for high aluminum waste streams that achieve high waste loadings while maintaining high processing rates. The testing was based on the compositions of Hanford High Level Waste (HLW) with limiting concentrations of aluminum specified by the Office of River Protection (ORP). The testing identified glass formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts and small scale melt rate screening tests. The results were used to select compositions for subsequent testing in a DuraMelter 100 (DM100) system. These tests were used to determine processing rates for the selected formulations as well as to examine the effects of increased glass processing temperature, and the form of aluminum in the waste simulant. Finally, one of the formulations was selected for large-scale confirmatory testing on the HLW Pilot Melter (DM1200), which is a one third scale prototype of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW melter and off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy (DOE) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same high-aluminum waste composition used in the present work and other Hanford HLW compositions. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the WTP is about 13,500 (equivalent to 40,500 MT glass). This estimate is based upon the inventory of the tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in wasteloading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

  7. ANALYSIS OF DWPF SLUDGE BATCH 6 (MACROBATCH 7) POUR STREAM GLASS SAMPLES

    SciTech Connect (OSTI)

    Johnson, F.

    2012-01-20T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 6 (SB6), also referred to as Macrobatch 7 (MB7), in June 2010. SB6 is a blend of the heel of Tank 40 from Sludge Batch 5 (SB5), H-Canyon Np transfers and SB6 that was transferred to Tank 40 from Tank 51.1 SB6 was processed using Frit 418. Sludge is received into the DWPF Chemical Processing Cell (CPC) and is processed through the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator Tank (SME). The treated sludge slurry is then transferred to the Melter Feed Tank (MFT) and fed to the melter. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP) and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. The DWPF requested various analyses of radioactive glass samples obtained from the melter pour stream during processing of SB6 as well as reduction/oxidation (REDOX) analysis of MFT samples to determine the impact of Argon bubbling. Sample analysis followed the Task Technical and Quality Assurance Plan (TTQAP) and an Analytical Study Plan (ASP). Four Pour Stream (PS) glass samples and two MFT slurry samples were delivered to the Savannah River National Laboratory (SRNL) from the DWPF. Table 1-1 lists the sample information for each pour stream glass sample. SB6 PS3 (S03472) was selected as the official pour stream sample for SB6 and full analysis was requested. This report details the visual observations of the as-received SB6 PS No.3 glass sample as well as results for the chemical composition, Product Consistency Test (PCT), radionuclide content, noble metals, and glass density. REDOX results will be provided for all four pour stream samples and vitrified samples of MFT-558 and MFT-568A. Where appropriate, data from other pour stream samples will be provided.

  8. High expansion, lithium corrosion resistant sealing glasses

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

    1991-01-01T23:59:59.000Z

    Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

  9. High expansion, lithium corrosion resistant sealing glasses

    DOE Patents [OSTI]

    Brow, R.K.; Watkins, R.D.

    1991-06-04T23:59:59.000Z

    Glass compositions containing CaO, Al[sub 2]O[sub 3], B[sub 2]O[sub 3], SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

  10. MECS 2006 - Glass | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-Temperature CombustionGlass MECS 2006 - Glass Manufacturing

  11. ICG 2000 Amsterdam Glass in the new Millennium Absorption Spectra of Iron and Water in Silicate Glasses

    E-Print Network [OSTI]

    Glebov, Leon

    ICG 2000 Amsterdam ­ Glass in the new Millennium Absorption Spectra of Iron and Water in Silicate of the absorption spectrum of silicate glasses and determination of absolute concentrations of ferric, ferrous of silicate glass. 2. Experimental The same glass samples were used in this work as were described in [3, 4

  12. Glass-ceramic joint and method of joining

    DOE Patents [OSTI]

    Meinhardt, Kerry D [Richland, WA; Vienna, John D [West Richland, WA; Armstrong, Timothy R [Clinton, TN; Pederson, Larry R [Kennewick, WA

    2003-03-18T23:59:59.000Z

    The present invention is a glass-ceramic material and method of making useful for joining a solid ceramic component and at least one other solid component. The material is a blend of M1-M2-M3, wherein M1 is BaO, SrO, CaO, MgO, or combinations thereof, M2 is Al.sub.2 O.sub.3, present in the blend in an amount from 2 to 15 mol %, M3 is SiO.sub.2 with up to 50 mol % B.sub.2 O.sub.3 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M1-Al.sub.2 O.sub.3 -M3 system can be used to join or seal both tubular and planar solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

  13. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

    1995-01-01T23:59:59.000Z

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  14. Hysteretic Optimization For Spin Glasses

    E-Print Network [OSTI]

    B. Goncalves; S. Boettcher

    2007-12-10T23:59:59.000Z

    The recently proposed Hysteretic Optimization (HO) procedure is applied to the 1D Ising spin chain with long range interactions. To study its effectiveness, the quality of ground state energies found as a function of the distance dependence exponent, $\\sigma$, is assessed. It is found that the transition from an infinite-range to a long-range interaction at $\\sigma=0.5$ is accompanied by a sharp decrease in the performance . The transition is signaled by a change in the scaling behavior of the average avalanche size observed during the hysteresis process. This indicates that HO requires the system to be infinite-range, with a high degree of interconnectivity between variables leading to large avalanches, in order to function properly. An analysis of the way auto-correlations evolve during the optimization procedure confirm that the search of phase space is less efficient, with the system becoming effectively stuck in suboptimal configurations much earlier. These observations explain the poor performance that HO obtained for the Edwards-Anderson spin glass on finite-dimensional lattices, and suggest that its usefulness might be limited in many combinatorial optimization problems.

  15. Natural glass analogues to alteration of nuclear waste glass: A review and recommendations for further study

    SciTech Connect (OSTI)

    McKenzie, W.F.

    1990-01-01T23:59:59.000Z

    The purpose of this report is to review previous work on the weathering of natural glasses; and to make recommendations for further work with respect to studying the alteration of natural glasses as it relates quantifying rates of dissolution. the first task was greatly simplified by the published papers of Jercinovic and Ewing (1987) and Byers, Jercinovic, and Ewing (1987). The second task is obviously the more difficult of the two and the author makes no claim of completeness in this regard. Glasses weather in the natural environment by reacting with aqueous solutions producing a rind of secondary solid phases. It had been proposed by some workers that the thickness of this rind is a function of the age of the glass and thus could be used to estimate glass dissolution rates. However, Jercinovic and Ewing (1987) point out that in general the rind thickness does not correlate with the age of the glass owing to the differences in time of contact with the solution compared to the actual age of the sample. It should be noted that the rate of glass dissolution is also a function of the composition of both the glass and the solution, and the temperature. Quantification of the effects of these parameters (as well as time of contact with the aqueous phase and flow rates) would thus permit a prediction of the consequences of glass-fluid interactions under varying environmental conditions. Defense high- level nuclear waste (DHLW), consisting primarily of liquid and sludge, will be encapsulated by and dispersed in a borosilicate glass before permanent storage in a HLW repository. This glass containing the DHLW serves to dilute the radionuclides and to retard their dispersion into the environment. 318 refs.

  16. THE PRODUCT CONSISTENCY TEST HOW AND WHY IT WAS DEVELOPED

    SciTech Connect (OSTI)

    Jantzen, C; Ned Bibler, N

    2008-12-15T23:59:59.000Z

    The Product Consistency Test (PCT), American Society for Testing Materials (ASTM) Standard C1285, is currently used world wide for testing glass and glass-ceramic waste forms for high level waste (HLW), low level waste (LLW), and hazardous wastes. Development of the PCT was initiated in 1986 because HLW glass waste forms required extensive characterization before actual production began and required continued characterization during production ({ge}25 years). Non-radioactive startup was in 1994 and radioactive startup was in 1996. The PCT underwent extensive development from 1986-1994 and became an ASTM consensus standard in 1994. During the extensive laboratory testing and inter- and intra-laboratory round robins using non-radioactive and radioactive glasses, the PCT was shown to be very reproducible, to yield reliable results rapidly, to distinguish between glasses of different durability and homogeneity, and to easily be performed in shielded cell facilities with radioactive samples. In 1997, the scope was broadened to include hazardous and mixed (radioactive and hazardous) waste glasses. In 2002, the scope was broadened to include glass-ceramic waste forms which are currently being recommended for second generation nuclear wastes yet to be generated in the nuclear renaissance. Since the PCT has proven useful for glass-ceramics with up to 75% ceramic component and has been used to evaluate Pu ceramic waste forms, the use of this test for other ceramic/mineral waste forms such as geopolymers, hydroceramics, and fluidized bed steam reformer mineralized product is under investigation.

  17. A THERMODYNAMICS STUDY ON THE UTILIZATION OF JORDANIAN OIL SHALE IN CEMENT INDUSTRY

    E-Print Network [OSTI]

    Awni Y. Al-otoom

    Oil shale can be utilized in manufacturing the Portland cement. In addition to the utilization of the spent oil shale after combustion, it can also reduce the required temperature for the clinkering reactions. A study on the Jordanian oil shale was performed to maximize the use of oil shale in the

  18. Corrosion of Aluminium in Composite Cements Anthony Setiadi* and Neil B. Milestone

    E-Print Network [OSTI]

    Sheffield, University of

    Corrosion of Aluminium in Composite Cements Anthony Setiadi* and Neil B. Milestone Immobilisation they are economic, durable and have long-term stability. However, there may be issues regarding the corrosion it is exposed to air, an oxide layer is formed. This layer generally provides protection to further corrosion

  19. Cement-based biocide coatings for controlling algal growth in water distribution canals

    E-Print Network [OSTI]

    Mobasher, Barzin

    to potable or waste water. There is however a lack of understanding in the correlation between the natureCement-based biocide coatings for controlling algal growth in water distribution canals A. Alum Foundation, Water Quality Center, Arizona State University, Tempe, AZ, United States a r t i c l e i n f o

  20. CSER 96-027: storage of cemented plutonium residue containers in 55 gallon drums

    SciTech Connect (OSTI)

    Watson, W.T.

    1997-01-20T23:59:59.000Z

    A nuclear criticality safety analysis has been performed for the storage of residual plutonium cementation containers, produced at the Plutonium Finishing Plant, in 55 gallon drums. This CSER increases the limit of total plutonium stored in each 55 gallon drum from 100 to 200 grams.

  1. Pore water evolution in oilfield sandstones: constraints from oxygen isotope microanalyses of quartz cement

    E-Print Network [OSTI]

    Haszeldine, Stuart

    of quartz cement Ann M.E. Marchanda,*, Calum I. Macaulayb , R. Stuart Haszeldinea , Anthony E. Fallickc--direct measurements were not possible) precipitated in the sandstones at temperatures jC; (2) the second zone B in the sandstones most likely between 70 and 90 jC; (3) the third zone C (homogeneous CL pattern and directly

  2. Electromagnetic interference shielding reaching 70 dB in steel fiber cement

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    Electromagnetic interference shielding reaching 70 dB in steel fiber cement Sihai Wen, D.D.L. Chung; Silica fume; Shielding 1. Introduction Electromagnetic interference (EMI) shielding [1­4] is in critical, NY 14260-4400, USA Received 9 January 2002; accepted 14 August 2003 Abstract An electromagnetic

  3. Effects of oil charge on illite dates and stopping quartz cement: calibration of basin models

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Abstract Effects of oil charge on illite dates and stopping quartz cement: calibration of basin Oil can fill pores in reservoir sandstones at any burial depth by long or short distance migration. There has been a debate since 1920 concerning the effect of oil charge. We have made detailed local

  4. CAPACITY INVESTMENT UNDER DEMAND UNCERTAINTY: THE ROLE OF IMPORTS IN THE U.S. CEMENT INDUSTRY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    varies across markets. In the presence of uncertain demand, capacity choices are shown theoreticallyCAPACITY INVESTMENT UNDER DEMAND UNCERTAINTY: THE ROLE OF IMPORTS IN THE U.S. CEMENT INDUSTRY Guy://www.economie.polytechnique.edu/ mailto:chantal.poujouly@polytechnique.edu #12;Capacity Investment under Demand Uncertainty: The Role

  5. Proceedings of the 12 International Congress on the Chemistry of Cement

    E-Print Network [OSTI]

    Bentz, Dale P.

    in water or as a granular water-filled porous media. In the former case, significant settling, and Evaporative Water Loss during Early Age Curing/Drying Immediately after placement, gravitational forces and the local drying environment begin to influence the (micro)structure of a cement paste, mortar, or concrete

  6. The interfacial chemistry of solidification/stabilization of metals in cement and pozzolanic material systems

    SciTech Connect (OSTI)

    Yousuf, M.; Mollah, A.; Vempati, R.K.; Lin, T.C.; Cocke, D.L. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States)

    1995-11-01T23:59:59.000Z

    The chemistry of cement, its hydration and mechanisms of solidification/stabilization (s/s) of toxic metals by cement-based systems and pozzolanic materials are significantly controlled by surface, near-surface and interfacial phenomena. The adsorption conditions and the selectivity strong affinity of hazardous metals towards clay minerals, certain hydrated metal oxides and oxyhydroxides, and cementitous substances also play an important role in the s/s process for the immobilization of contaminants. Recent works from the authors` laboratory involving metal ions and superplasticizers have elucidated the mechanisms of reactions leading to the retardation of cement hydration and subsequent setting and their interactions with silicate-based systems. This article delineates the current status of interfacial chemistry at the solid-liquid boundary and places it in perspective with present and future s/s processes based on Portland cement and pozzolanic materials. The importance of surface charge, the role of interfacial phenomena on adsorption, and the importance of calcium and other types of anions and cations in s/s are also discussed. A surface charge control reaction model that accounts for the importance of calcium and other cations and anions is outlined and used to discuss the chemical nature and microstructure of the interfacial transition zone.

  7. Mechanical properties of WC10Co cemented carbides sintered from nanocrystalline spray conversion processed powders

    E-Print Network [OSTI]

    Hong, Soon Hyung

    Mechanical properties of WC±10Co cemented carbides sintered from nanocrystalline spray conversion as the spray conversion process [2]. The WC particle sizes in powders fabricated by the spray conversion: microstructural parameters such as WC grain size, Co mean free path and WC/WC contiguity; chemical factors

  8. Characterizations of WC-10Co nanocomposite powders and subsequently sinterhip sintered cemented carbide

    SciTech Connect (OSTI)

    Shi, X.L. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China)]. E-mail: sxl071932@126.com; Shao, G.Q. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China); Duan, X.L. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China); Xiong, Z. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China); Yang, H. [State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122Luoshi Road, Wuhan 430070 (China)

    2006-12-15T23:59:59.000Z

    Ultrafine WC-Co cemented carbides, combining high hardness and high toughness, are expected to find broad applications. In this study, WC-10Co-0.4VC-0.4Cr{sub 3}C{sub 2} (wt.%) nanocomposite powders, whose average grain size was about 30 nm, were fabricated by spray pyrolysis-continuous reduction and carbonization technology. The as-prepared nanocomposite powders were characterized and analyzed by chemical methods, scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET analysis and atomic force microscopy (AFM). Furthermore, 'sinterhip' was used in the sintering process, by which ultrafine WC-10Co cemented carbides with an average grain size of 240 nm were prepared. The material exhibited high Rockwell A hardness of HRA 92.8, Vickers hardness HV{sub 1} 1918, and transverse rapture strength (TRS) of 3780 MPa. The homogeneously dispersed grain growth inhibitors such as VC, Cr{sub 3}C{sub 2} in nanocomposite powder and the special nonmetal-metal nanocomposite structure of WC-10Co nanocomposite powder played very important roles in obtaining ultrafine WC-10Co cemented carbide with the desired properties and microstructure. There was an abundance of triple junctions in the ultrafine WC-10Co cemented carbide; these triple junctions endowed the sintered specimen with high mechanical properties.

  9. Recycle of Wastes of Clay Brick Industry for Producing Eco-cement

    E-Print Network [OSTI]

    Amin, A. M

    2010-01-01T23:59:59.000Z

    mixes were designed from the WCB and ordinary Portland cement (OPC). After adding the required amount of water for each mix, the pastes were moulded in 5x5x5cm3 mould. The initial and final setting time were measured. The moulded specimens were cured...

  10. Identification and characterization of agent for reductive dechlorination in mixtures of ferrous iron and Portland cement

    E-Print Network [OSTI]

    Ko, Sae Bom

    2001-01-01T23:59:59.000Z

    were conducted to identify a potential active agent in a mixture of Fe(II) and Portland cement extract (PCX). Results of XRD analysis indicated that a potential active agent is likely to be green rust chloride, which is a layered Fe...

  11. Encapsulation of mixed radioactive and hazardous waste contaminated incinerator ash in modified sulfur cement

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1990-01-01T23:59:59.000Z

    Some of the process waste streams incinerated at various Department of Energy (DOE) facilities contain traces of both low-level radioactive (LLW) and hazardous constituents, thus yielding ash residues that are classified as mixed waste. Work is currently being performed at Brookhaven National Laboratory (BNL) to develop new and innovative materials for encapsulation of DOE mixed wastes including incinerator ash. One such material under investigation is modified sulfur cement, a thermoplastic developed by the US Bureau of Mines. Monolithic waste forms containing as much as 55 wt % incinerator fly ash from Idaho national Engineering Laboratory (INEL) have been formulated with modified sulfur cement, whereas maximum waste loading for this waste in hydraulic cement is 16 wt %. Compressive strength of these waste forms exceeded 27.6 MPa. Wet chemical and solid phase waste characterization analyses performed on this fly ash revealed high concentrations of soluble metal salts including Pb and Cd, identified by the Environmental Protection Agency (EPA) as toxic metals. Leach testing of the ash according to the EPA Toxicity Characteristic Leaching Procedure (TCLP) resulted in concentrations of Pb and Cd above allowable limits. Encapsulation of INEL fly ash in modified sulfur cement with a small quantity of sodium sulfide added to enhance retention of soluble metal salts reduced TCLP leachate concentrations of Pb and Cd well below EPA concentration criteria for delisting as a toxic hazardous waste. 12 refs., 4 figs., 2 tabs.

  12. Influence of hydroxypropylguars on rheological behaviour of cement-based mortars

    E-Print Network [OSTI]

    Boyer, Edmond

    behavior of cementitious materials [7]. Concrete, mortar and cement grout with high fluidity (e.g. self-compacting concrete or self- leveling underlayment) have been developed in order to facilitate placement. However and Concrete Research 58 (2014) 161-168" DOI : 10.1016/j.cemconres.2014.01.020 #12;2 ABSTRACT

  13. [ ]May 2014 Portland cement concrete (PCC) overlays have been used with great success in many locations

    E-Print Network [OSTI]

    Harms, Kyle E.

    accelerated pavement testing on bonded concrete overlay pavements to be constructed at the Pavement Research testing; evaluate the structural bearing capacity of the concrete overlay pavement structures[ ]May 2014 PROBLEM Portland cement concrete (PCC) overlays have been used with great success

  14. Concrete international /january 2010 35 Portland limestone cement (PLC) is produced by

    E-Print Network [OSTI]

    Concrete international /january 2010 35 Portland limestone cement (PLC) is produced by blending demonstration of PLC concrete in the late-fall construction of a parking lot at a ready mixed concrete plant near Gatineau, QC, Canada. The performance of the plastic and hardened concretes produced with PLC

  15. Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms: A Feasibility Assessment

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Maio, Vincent; McCloy, John S.; Scott, Clark; Riley, Brian J.; Benefiel, Bradley; Vienna, John D.; Archibald, Kip; Rodriguez, Carmen P.; Rutledge, Veronica; Zhu, Zihua; Ryan, Joseph V.; Olszta, Matthew J.

    2014-01-01T23:59:59.000Z

    Glass ceramics are being developed to immobilize fission products, separated from used nuclear fuel by aqueous reprocessing, into a stable waste form suitable for disposal in a geological repository. This work documents the glass ceramic formulation at bench scale and for a scaled melter test performed in a pilot-scale (~1/4 scale) cold crucible induction meter (CCIM). Melt viscosity, electrical conductivity, and crystallization behavior upon cooling were measured on a small set of compositions to select a formulation for melter testing. Property measurements also identified a temperature range for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form. Bench scale and melter run results successfully demonstrate the processability of the glass ceramic using the CCIM melter technology.

  16. Hierarchical modeling of structure and mechanics of cement hydrate

    E-Print Network [OSTI]

    Shahsavari, Rouzbeh

    2011-01-01T23:59:59.000Z

    With an annual production of more than 20 billion tons a year, concrete continues to be the world's dominating manufacturing material for a foreseeable future. However, this ubiquity comes with a large ecological price as ...

  17. Mechanical property evaluation of porous 13-93 Bioactive Glass and GL1550 Borate Glass 3D scaffolds D. Li, A. Scully, and T. M. G. Chu

    E-Print Network [OSTI]

    Zhou, Yaoqi

    Mechanical property evaluation of porous 13-93 Bioactive Glass and GL1550 Borate Glass 3D scaffolds-glass (A) and GL1550 borate bioactive-glass (B) powders, at different sintering temperatures, and with (failure, Pb) of scaffolds made from 13-93 bioactive- glass and GL1550 bioactive-glass powders are compared

  18. Brownfield reuse of dredged New York Harbor sediment by cement-based solidification/stabilization

    SciTech Connect (OSTI)

    Loest, K. [ECDC Environmental L.C., Pembroke, MA (United States). Eastern Operations; Wilk, C.M. [Portland Cement Association, Skokie, IL (United States)

    1998-12-31T23:59:59.000Z

    Newly effective federal regulations restrict the ocean disposal of sediments dredged from the harbors of New York and Newark. The New York Port Authority is faced with a critical situation: find land-based disposal/uses for 10`s of millions cubic yards of sediments or lose standing as a commercial port for ocean-going ships. One of the technologies now being employed to manage the sediments is portland cement-based solidification/stabilization (S/S) treatment. At least 4 million cubic yards of the sediments will undergo cement-based S/S treatment. This treatment will immobilize heavy metals, dioxin, PCBs and other organic contaminants in the sediment. The treatment changes the sediment from a environmental liability into a valuable structural fill. This structural fill is being used at two properties. The first property is an old municipal landfill in Port Newark, New Jersey. The treated sediments are being used as structural fill to cover about 20 acres of the landfill. This will allow planned redevelopment of the landfill property into a shopping mall. The second property called the Seaboard site, was the location of a coal gasification facility and later a wood preservation facility. This 160-acre property has been designated for brownfield redevelopment. Over 4 million cubic yards of treated sediments will eventually cover this site. Portland cement is the selected S/S binding reagent. Nearly 500,000 tons of cement will eventually be used to treat the sediments. Cement was selected for its ability to (a) change the peanut butter-like consistency of the sediments into a structural material and (b) to physically and chemically immobilize hazardous constituents in the sediment.

  19. An Insulating Glass Knowledge Base

    SciTech Connect (OSTI)

    Michael L. Doll; Gerald Hendrickson; Gerard Lagos; Russell Pylkki; Chris Christensen; Charlie Cureija

    2005-08-01T23:59:59.000Z

    This report will discuss issues relevant to Insulating Glass (IG) durability performance by presenting the observations and developed conclusions in a logical sequential format. This concluding effort discusses Phase II activities and focuses on beginning to quantifying IG durability issues while continuing the approach presented in the Phase I activities (Appendix 1) which discuss a qualitative assessment of durability issues. Phase II developed a focus around two specific IG design classes previously presented in Phase I of this project. The typical box spacer and thermoplastic spacer design including their Failure Modes and Effect Analysis (FMEA) and Fault Tree diagrams were chosen to address two currently used IG design options with varying components and failure modes. The system failures occur due to failures of components or their interfaces. Efforts to begin quantifying the durability issues focused on the development and delivery of an included computer based IG durability simulation program. The focus/effort to deliver the foundation for a comprehensive IG durability simulation tool is necessary to address advancements needed to meet current and future building envelope energy performance goals. This need is based upon the current lack of IG field failure data and the lengthy field observation time necessary for this data collection. Ultimately, the simulation program is intended to be used by designers throughout the current and future industry supply chain. Its use is intended to advance IG durability as expectations grow around energy conservation and with the growth of embedded technologies as required to meet energy needs. In addition the tool has the immediate benefit of providing insight for research and improvement prioritization. Included in the simulation model presentation are elements and/or methods to address IG materials, design, process, quality, induced stress (environmental and other factors), validation, etc. In addition, acquired data is presented in support of project and model assumptions. Finally, current and suggested testing protocol and procedure for future model validation and IG physical testing are discussed.

  20. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-01-01T23:59:59.000Z

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  1. Magnetic behavior of erbium-zinc-borate glasses and glass ceramics

    SciTech Connect (OSTI)

    Borodi, G. [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath, 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath, 400293 Cluj-Napoca (Romania); Pascuta, P.; Bosca, M.; Pop, V. [Technical University, 28 Memorandumului, 400114 Cluj-Napoca (Romania)] [Technical University, 28 Memorandumului, 400114 Cluj-Napoca (Romania); Stefan, R. [Agricultural Science and Veterinary Medicine University, 3-5 Calea Manastur, 400372 Cluj-Napoca (Romania)] [Agricultural Science and Veterinary Medicine University, 3-5 Calea Manastur, 400372 Cluj-Napoca (Romania); Tetean, R. [Babes-Bolyai University, 1 Mihail Kogalniceanu, Faculty of Physics, 400084 Cluj Napoca (Romania)] [Babes-Bolyai University, 1 Mihail Kogalniceanu, Faculty of Physics, 400084 Cluj Napoca (Romania); Radulescu, D. [University of Medicine and Pharmacy Iuliu Hatieganu, 8 Victor Babes, 400012 Cluj-Napoca (Romania)] [University of Medicine and Pharmacy Iuliu Hatieganu, 8 Victor Babes, 400012 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    Glasses of the system (Er{sub 2}O{sub 3}){sub x}?(B{sub 2}O{sub 3}){sub (60?x)}?(ZnO){sub 40} (3 ? x ? 15 mol%) were prepared by conventional melt quenching and subsequently converted to glass ceramics by heat treatment of glass samples at 860 °C for 2 h. The magnetic behaviour of the studied glasses and glass ceramics were investigated using a vibrating sample magnetometer (VSM) and a Faraday-type magnetic balance. Magnetic data show that erbium ions are involved in negative superexchange interactions in all the investigated samples, being antiferromagnetically coupled. For all studied samples the experimental values obtained for the effective magnetic moments are lower than the value corresponding to free Er{sup 3+} ions and decrease with the increasing of Er{sub 2}O{sub 3} content. The decrease is more pronounced in heat treated samples than untreated ones.

  2. Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics

    SciTech Connect (OSTI)

    Sathish, M., E-mail: sathishphy79@gmail.com [Department of Physics, GOVT first grade College, Doddaballapur-561203 (India); Eraiah, B., E-mail: eraiah@rediffmail.com [Department of Physics, Bangalore University, Bangalore-560056, India (India)

    2014-04-24T23:59:59.000Z

    Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400°C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

  3. Assessment of China's Energy-Saving and Emission-Reduction Accomplishments and Opportunities During the 11th Five Year Plan

    E-Print Network [OSTI]

    Levine, Mark D.

    2010-01-01T23:59:59.000Z

    calcium carbide, coking, cement, coal, plate glass, pulp andcarbide 2 Mt Coking 80 Mt Cement 250 Mt Coal mining (

  4. Insulation products promote thermal efficiency

    SciTech Connect (OSTI)

    Chalmers, R.

    1985-04-01T23:59:59.000Z

    The judicious use of thermal insulation products in non-residential buildings can provide a number of advantages including increased energy efficiency, lower first costs (by avoiding overside HVAC systems), improved fire safety and better acoustics. Thermal insulation products are those products which retard the flow of heat energy. Materials include glass, plastics, and organic materials such as wood fibers, vermiculite and perlite. Forms range from the familiar batts and blankets of glass fibers to foamed plastic, rigid boards, losse fill and systems combining two or more products, such as polystyrene boards covered with insulating plaster. The R values of selected insulation materials with a cost/sq. ft. of each material at R 10 are given. Costs cover both the material and installation and may vary depending on local conditions.

  5. Dynamics of window glass fracture in explosions

    SciTech Connect (OSTI)

    Beauchamp, E.K.; Matalucci, R.V.

    1998-05-01T23:59:59.000Z

    An exploratory study was conducted under the Architectural Surety Program to examine the possibility of modifying fracture of glass in the shock-wave environment associated with terrorist bombings. The intent was to explore strategies to reduce the number and severity of injuries resulting from those attacks. The study consisted of a series of three experiments at the Energetic Materials Research and Testing Center (EMRTC) of the New Mexico Institute of Mining and Technology at Socorro, NM, in which annealed and tempered glass sheets were exposed to blast waves at several different levels of overpressure and specific impulse. A preliminary assessment of the response of tempered glass to the blast environment suggested that inducing early failure would result in lowering fragment velocity as well as reducing the loading from the window to the structure. To test that possibility, two different and novel procedures (indentation flaws and spot annealing) were used to reduce the failure strength of the tempered glass while maintaining its ability to fracture into small cube-shaped fragments. Each experiment involved a comparison of the performance of four sheets of glass with different treatments.

  6. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  7. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  8. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

    1997-01-01T23:59:59.000Z

    Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

  9. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

    1997-07-15T23:59:59.000Z

    Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

  10. Retention of Halogens in Waste Glass

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2010-05-01T23:59:59.000Z

    In spite of their potential roles as melting rate accelerators and foam breakers, halogens are generally viewed as troublesome components for glass processing. Of five halogens, F, Cl, Br, I, and At, all but At may occur in nuclear waste. A nuclear waste feed may contain up to 10 g of F, 4 g of Cl, and ?100 mg of Br and I per kg of glass. The main concern is halogen volatility, producing hazardous fumes and particulates, and the radioactive iodine 129 isotope of 1.7x10^7-year half life. Because F and Cl are soluble in oxide glasses and tend to precipitate on cooling, they can be retained in the waste glass in the form of dissolved constituents or as dispersed crystalline inclusions. This report compiles known halogen-retention data in both high-level waste (HLW) and low-activity waste (LAW) glasses. Because of its radioactivity, the main focus is on I. Available data on F and Cl were compiled for comparison. Though Br is present in nuclear wastes, it is usually ignored; no data on Br retention were found.

  11. Wetting of metals and glasses on Mo

    SciTech Connect (OSTI)

    Saiz, Eduardo; Tomsia, Antoni P.; Saiz, Eduardo; Lopez-Esteban, Sonia; Benhassine, Mehdi; de Coninck, Joel; Rauch, Nicole; Ruehle, Manfred

    2008-01-08T23:59:59.000Z

    The wetting of low melting point metals and Si-Ca-Al-Ti-O glasses on molybdenum has been investigated. The selected metals (Au, Cu, Ag) form a simple eutectic with Mo. Metal spreading occurs under nonreactive conditions without interdiffusion or ridge formation. The metals exhibit low (non-zero) contact angles on Mo but this requires temperatures higher than 1100 C in reducing atmospheres in order to eliminate a layer of adsorbed impurities on the molybdenum surface. By controlling the oxygen activity in the furnace, glass spreading can take place under reactive or nonreactive conditions. We have found that in the glass/Mo system the contact angle does not decrease under reactive conditions. In all cases, adsorption from the liquid seems to accelerate the diffusivity on the free molybdenum surface.

  12. Irradiation effects on borosilicate waste glasses

    SciTech Connect (OSTI)

    Roberts, F.P.

    1980-06-01T23:59:59.000Z

    The effects of alpha decay on five borosilicate glasses containing simulated nuclear high-level waste oxides were studied. Irradiations carried out at room temperature were achieved by incorporating 1 to 8 wt % /sup 244/Cm/sub 2/O/sub 3/ in the glasses. Density changes and stored-energy build-up saturated at doses less than 2 x 10/sup 21/ alpha decays/kg. Damage manifested by stored energy was completely annealed at 633/sup 0/K. Positive and negative density changes were observed which never exceeded 1%. Irradiation had very little effect on mechanical strength or on chemical durability as measured by aqueous leach rates. Also, no effects were observed on the microstructure for vitreous waste glasses, although radiation-induced microcracking could be achieved on specimens that had been devitrified prior to irradiation.

  13. Glass/ceramic coatings for implants

    SciTech Connect (OSTI)

    Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

    2011-09-06T23:59:59.000Z

    Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

  14. ROAD MAP FOR DEVELOPMENT OF CRYSTAL-TOLERANT HIGH LEVEL WASTE GLASSES

    SciTech Connect (OSTI)

    Fox, K.; Peeler, D.; Herman, C.

    2014-05-15T23:59:59.000Z

    The U.S. Department of Energy (DOE) is building a Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford Site in Washington to remediate 55 million gallons of radioactive waste that is being temporarily stored in 177 underground tanks. Efforts are being made to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product quality requirements. This road map guides the research and development for formulation and processing of crystaltolerant glasses, identifying near- and long-term activities that need to be completed over the period from 2014 to 2019. The primary objective is to maximize waste loading for Hanford waste glasses without jeopardizing melter operation by crystal accumulation in the melter or melter discharge riser. The potential applicability to the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) will also be addressed in this road map. The planned research described in this road map is motivated by the potential for substantial economic benefits (significant reductions in glass volumes) that will be realized if the current constraints (T1% for WTP and TL for DWPF) are approached in an appropriate and technically defensible manner for defense waste and current melter designs. The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal-tolerant high-level waste (HLW) glasses targeting high waste loadings while still meeting process related limits and melter lifetime expectancies. The modeling effort will be an iterative process, where model form and a broader range of conditions, e.g., glass composition and temperature, will evolve as additional data on crystal accumulation are gathered. Model validation steps will be included to guide the development process and ensure the value of the effort (i.e., increased waste loading and waste throughput). A summary of the stages of the road map for developing the crystal-tolerant glass approach, their estimated durations, and deliverables is provided.

  15. Glass Frit Clumping And Dusting

    SciTech Connect (OSTI)

    Steimke, J. L.

    2013-09-26T23:59:59.000Z

    DWPF mixes a slurry of glass frit (Frit 418) and dilute (1.5 wt%) formic acid solution with high level waste in the Slurry Mix Evaporator (SME). There would be advantages to introducing the frit in a non-slurry form to minimize water addition to the SME, however, adding completely dry frit has the potential to generate dust which could clog filters or condensers. Prior testing with another type of frit, Frit 320, and using a minimal amount of water reduced dust generation, however, the formation of hard clumps was observed. To examine options and behavior, a TTQAP [McCabe and Stone, 2013] was written to initiate tests that would address these concerns. Tests were conducted with four types of glass frit; Frit 320, DWPF Frit 418, Bekeson Frit 418 and Multi-Aspirator Frit 418. The last two frits are chemically identical to DWPF Frit 418 but smaller particles were removed by the respective vendors. Test results on Frit Clumping and Dusting are provided in this report. This report addresses the following seven questions. Short answers are provided below with more detailed answers to follow. 1. Will the addition of a small amount of water, 1.5 wt%, to dry DWPF Frit 418 greatly reduce the dust generation during handling at DWPF? a. Yes, a small scale test showed that adding a little water to the frit greatly reduced dust generation during handling. 2. Will the addition of small amounts of water to the frit cause clumping that will impair frit handling at DWPF? a. No, not with Frit 418. Although clumps were observed to form when 1.5 wt% water was mixed with DWPF Frit 418, then compressed and air-dried overnight, the clumps were easily crushed and did not form the hardened material noted when Frit 320 was tested. 3. What is the measured size distribution of dust generated when dry frit is handled? (This affects the feasibility and choice of processing equipment for removing the dust generating fraction of the frit before it is added to the SME.) a. The size distribution for the dust removed from fresh DWPF Frit 418 while it was being shaken in a small scale LabRAM test was measured. The median size on a volume basis was 7.6 ?m and 90% of the frit particles were between 1.6 and 28 ?m. The mass of dust collected using this test protocol was much less than 1% of the original frit. 4. Can the dust be removed in a small number of processing steps and without the larger frit particles continuing to spall additional dust sized particles? a. Test results using a LabRAM were inconclusive. The LaRAM performs less efficient particle size separation than the equipment used by Bekeson and Multi-Aspirator. 5. What particle size of frit is expected to create a dust problem? a. The original criterion for creating a dusting problem was those particle sizes that were readily suspended when being shaken. For that criterion calculations and Microtrac size analyses indicated that particles smaller than 37 ?m are likely dust generators. Subsequently a more sophisticated criterion for dust problem was considered, particle sizes that would become suspended in the air flow patterns inside the SME and possibly plug the condenser. That size may be larger than 37 ?m but has not yet been determined. 6. If particles smaller than 37 ?m are removed will bulk dust generation be eliminated? a. Video-taped tests were performed using three gallons each of three types of frit 418, DWPF frit, Bekeson frit and Multi-Aspirator frit. Frit was poured through air from a height of approximately eight feet into a container half filled with water. Pouring Bekeson frit or Multi-Aspirator frit generated markedly less visible dust, but there was still a significant amount, which still has the potential of causing a dust problem. 7. Can completely dry frit be poured into the SME without having dust plug the condenser at the top of the vessel? a. Because of the complexity of air currents inside the SME and the difficulty of defensible size scaling a more prototypical test will be required to answer this question. We recommend construction of a full scale

  16. Identifying Opportunities for Industrial Energy Conservation

    E-Print Network [OSTI]

    Hoffman, A. R.

    1981-01-01T23:59:59.000Z

    . Cement Making 5. Vacuum Distillation 4. Cooking 6. Hydrocracking 5. Glass Melting 7. Hydrogen Production 6. Copper Smelting 8. Hydrorefining/Hydrotreating 7. Miscellaneous 9. Visbreaking 10. Petroleum Coking 11. Desulfurization C. Iron and Steel I...

  17. Carbon nanotube and nanofiber reinforcement for improving the flexural strength and fracture toughness of portland cement paste

    E-Print Network [OSTI]

    Tyson, Bryan Michael

    2012-07-16T23:59:59.000Z

    The focus of the proposed research will be on exploring the use of nanotechnology-based nano-filaments, such as carbon nanotubes (CNTs) and nanofibers (CNFs), as reinforcement in improving the mechanical properties of portland cement paste as a...

  18. By-Products Utilization

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    ", Portland Cement Association Skokie, IL, pp. 1-10. 11. Burnham, J. C., Bennet, G. F., and Logan, T. J., 1990

  19. Towards modeling gadolinium-lead-borate glasses

    SciTech Connect (OSTI)

    Rada, S., E-mail: Simona.Rada@phys.utcluj.ro [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Ristoiu, T. [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Rada, M. [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Coroiu, I. [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Maties, V. [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Mechatronic, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania); Culea, E. [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)] [Department of Physics, Technical University of Cluj-Napoca, 400641 Cluj-Napoca (Romania)

    2010-01-15T23:59:59.000Z

    Infrared spectra of gadolinium-lead-borate glasses of the xGd{sub 2}O{sub 3}.(100 - x)[3B{sub 2}O{sub 3}.PbO] system, where x = 0, 5, 10, 15, 25, 35 and 50 mol.%, have been recorded to explore the role of content of gadolinium ions behaving as glass modifier. The FTIR spectroscopy data for the xGd{sub 2}O{sub 3}.(1 - x)[3B{sub 2}O{sub 3}.PbO] glasses show the structural role of lead ions as a network-formers and of the gadolinium ions network modifiers. Adding of the rare earth ion up to 35 mol.% into the glass matrix, the IR bands characteristic to the studied glasses become sharper and more pronounced. Structural changes, as recognized by analyzing band shapes of IR spectra, revealed that Gd{sub 2}O{sub 3} causes a change from the continuous borate network to the continuous lead-borate network interconnected through Pb-O-B and B-O-B bridges and the transformation of some tetrahedral [BO{sub 4}] units into trigonal [BO{sub 3}] units. Then, gadolinium ions have affinity towards [BO{sub 3}] structural units which contain non-bridging oxygens necessary for the charge compensation because the more electronegative [BO{sub 3}] structural units were implied in the formation of B-O-Gd bonds and the transformation of glass network into a glass ceramic. We propose a possible structural model of building blocks for the formation of continuous random 3B{sub 2}O{sub 3}.PbO network glass used by density functional theory (DFT) calculations. DFT calculations show that lead atoms occupy three different sites in the proposed model. The first is coordinated with six oxygen atoms forming distorted octahedral geometries. The second lead atom has an octahedral oxygen environment and the five longer Pb-O bonds are considered as participating in the metal coordination scheme. The third lead atom has ionic character. In agreement with the results offered by the experimental FTIR data, the theoretical IR data confirm that our proposed structure is highly possible.

  20. Assessing the effect of cement-steel interface on well casing corrosion in aqueous CO2 environments

    SciTech Connect (OSTI)

    Han, Jiabin [Los Alamos National Laboratory; Carey, James W [Los Alamos National Laboratory; Zhang, Jinsuo [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    CO{sub 2} leakage is a critical safety concern for geologic storage. In wellbore environments, important leakage paths include the rock-cement and cement-casing interfaces. If the cement-casing interface is filled with escaping CO{sub 2}, the well casing directly contacts the CO{sub 2}. This can cause severe corrosion in the presence of water. This paper studies the effect of steel-cement interface gaps, ranging from 1 mm to 0 um, on casing corrosion. Corrosion kinetics were measured employing electrochemical techniques including linear polarization resistance, open circuit potential and electrochemical impedance spectroscopy. The experimental results showed that the corrosion of steel is not significant where the gap between steel and cement is small ({le} 100 {micro}m). Corrosion rates are controlled by the diffusion of corrosive species (H{sub 2}CO{sub 3} and H{sup +}) along the interface. In contrast, steel corrosion is severe in a broad gap where the corrosion process is limited only by the reaction kinetics of steel and corrosive species. The threshold leading to severe corrosion in terms of the cement-steel interface size (100 {micro}m) was determined. Our research clarifies a corrosion scenario at the cement-steel interface. Casing steel corrosion is initiated when attacked by corrosive species at the cement-steel interface. For relatively tight interfaces, this results in a slow thinning of the casing and expansion of the interface width. If the gap increases beyond the critical threshold size, the corrosion rate increases significantly, and a potentially damaging cycle of corrosion and interface expansion is developed.