Powered by Deep Web Technologies
Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

THERMAL ANALYSIS OF WASTE GLASS MELTER FEED Pavel Hrma,  

NLE Websites -- All DOE Office Websites (Extended Search)

THERMAL ANALYSIS OF WASTE GLASS MELTER FEED Pavel Hrma, (a,b) David A. Pierce, (b) Richard Pokorn (b,c) (a) Division of Advanced Nuclear Engineering, Pohang University of Science...

2

THERMAL ANALYSIS OF WASTE GLASS MELTER FEEDS  

SciTech Connect

Melter feeds for high-level nuclear waste (HLW) typically contain a large number of constituents that evolve gas on heating, Multiple gas-evolving reactions are both successive and simultaneous, and include the release of chemically bonded water, reactions of nitrates with organics, and reactions of molten salts with solid silica. Consequently, when a sample of a HLW feed is subjected to thermogravimetric analysis (TGA), the rate of change of the sample mass reveals multiple overlapping peaks. In this study, a melter feed, formulated for a simulated high-alumina HLW to be vitrified in the Waste Treatment and Immobilization Plant, currently under construction at the Hanford Site in Washington State, USA, was subjected to TGA. In addition, a modified melter feed was prepared as an all-nitrate version of the baseline feed to test the effect of sucrose addition on the gas-evolving reactions. Activation energies for major reactions were determined using the Kissinger method. The ultimate aim of TGA studies is to obtain a kinetic model of the gas-evolving reactions for use in mathematical modeling of the cold cap as an element of the overall model of the waste-glass melter. In this study, we focused on computing the kinetic parameters of individual reactions without identifying their actual chemistry, The rough provisional model presented is based on the first-order kinetics.

KRUGER AA; HRMA PR; POKORNY R; PIERCE DA

2011-10-21T23:59:59.000Z

3

EA-0821: Operation of the Glass Melter Thermal Treatment Unit at the U.S.  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1: Operation of the Glass Melter Thermal Treatment Unit at 1: Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio EA-0821: Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio SUMMARY This EA evaluates the environmental impacts of a proposal to use an existing glass melter thermal treatment unit (also known as a Penberthy Pyro-Converter joule-heated glass furnace) for the treatment of hazardous and mixed wastes (waste containing both hazardous and radioactive material at the U.S. Department of Energy's Mound Plant in Miamisburg, Ohio. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD July 26, 1995 EA-0821: Finding of No Significant Impact Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department

4

Determination of temperature-dependent heat conductivity and thermal diffusivity of waste glass melter feed  

SciTech Connect

The cold cap is a layer of reacting glass batch floating on the surface of melt in an all-electric continuous glass melter. The heat needed for the conversion of the melter feed to molten glass must be transferred to and through the cold cap. Since the heat flux into the cold cap determines the rate of melting, the heat conductivity is a key property of the reacting feed. We designed an experimental setup consisting of a large cylindrical crucible with an assembly of thermocouples that monitors the evolution of the temperature field while the crucible is heated at a constant rate. Then we used two methods to calculate the heat conductivity and thermal diffusivity of the reacting feed: the approximation of the temperature field by polynomial functions and the finite-volume method coupled with least-squares analysis. Up to 680C, the heat conductivity of the reacting melter feed was represented by a linear function of temperature.

Pokorny, Richard; Rice, Jarrett A.; Schweiger, Michael J.; Hrma, Pavel R.

2013-06-01T23:59:59.000Z

5

Determination of heat conductivity and thermal diffusivity of waste glass melter feed: Extension to high temperatures  

SciTech Connect

The heat conductivity ({lambda}) and the thermal diffusivity (a) of reacting glass batch, or melter feed, control the heat flux into and within the cold cap, a layer of reacting material floating on the pool of molten glass in an all-electric continuous waste glass melter. After previously estimating {lambda} of melter feed at temperatures up to 680 deg C, we focus in this work on the {lambda}(T) function at T > 680 deg C, at which the feed material becomes foamy. We used a customized experimental setup consisting of a large cylindrical crucible with an assembly of thermocouples, which monitored the evolution of the temperature field while the crucible with feed was heated at a constant rate from room temperature up to 1100C. Approximating measured temperature profiles by polynomial functions, we used the heat transfer equation to estimate the {lambda}(T) approximation function, which we subsequently optimized using the finite-volume method combined with least-squares analysis. The heat conductivity increased as the temperature increased until the feed began to expand into foam, at which point the conductivity dropped. It began to increase again as the foam turned into a bubble-free glass melt. We discuss the implications of this behavior for the mathematical modeling of the cold cap.

Rice, Jarrett A.; Pokorny, Richard; Schweiger, Michael J.; Hrma, Pavel R.

2014-05-12T23:59:59.000Z

6

Lid heater for glass melter  

DOE Patents (OSTI)

A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes.

Phillips, Terrance D. (617 Chestnut Ct., Aiken, SC 29803)

1993-01-01T23:59:59.000Z

7

Cold Crucible Induction Melter Studies for Making Glass Ceramic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms: A Feasibility Assessment. Cold Crucible Induction Melter Studies for Making Glass Ceramic Waste Forms:...

8

DWPF Glass Melter Technology Manual: Volume 3  

SciTech Connect

This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics discussed include: Information collected during testing, equipment, materials, design basis, feed tubes, and an evaluation of the performance of various components. Information is conveyed using many diagrams and photographs.

Iverson, D.C.

1993-12-31T23:59:59.000Z

9

Glass melter off-gas system  

DOE Patents (OSTI)

Apparatus and method for melting glass in a glass melter in such a way as to reduce deposition of particulates in the off-gas duct. Deposit accumulation is reduced by achieving an off-gas velocity above approximately 15 meters/second and an off-gas temperature as close as possible to, but not higher than, the glass softening point. Because the deposits are largely water-soluble, those that do form on the interior surface of the duct can be readily removed by injecting water or steam directly into the off-gas duct from its entrance or exit.

Jantzen, Carol M. (Aiken, SC)

1997-01-01T23:59:59.000Z

10

Crystallization In High Level Waste (HLW) Glass Melters: Operational Experience From The Savannah River Site  

SciTech Connect

processing strategy for the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal tolerant high level waste (HLW) glasses targeting higher waste loadings while still meeting process related limits and melter lifetime expectancies. This report provides a review of the scaled melter testing that was completed in support of the Defense Waste Processing Facility (DWPF) melter. Testing with scaled melters provided the data to define the DWPF operating limits to avoid bulk (volume) crystallization in the un-agitated DWPF melter and provided the data to distinguish between spinels generated by K-3 refractory corrosion versus spinels that precipitated from the HLW glass melt pool. This report includes a review of the crystallization observed with the scaled melters and the full scale DWPF melters (DWPF Melter 1 and DWPF Melter 2). Examples of actual DWPF melter attainment with Melter 2 are given. The intent is to provide an overview of lessons learned, including some example data, that can be used to advance the development and implementation of an empirical model and operating limit for crystal accumulation for WTP. Operation of the first and second (current) DWPF melters has demonstrated that the strategy of using a liquidus temperature predictive model combined with a 100 C offset from the normal melter operating temperature of 1150 C (i.e., the predicted liquidus temperature (TL) of the glass must be 1050 C or less) has been successful in preventing any detrimental accumulation of spinel in the DWPF melt pool, and spinel has not been observed in any of the pour stream glass samples. Spinel was observed at the bottom of DWPF Melter 1 as a result of K-3 refractory corrosion. Issues have occurred with accumulation of spinel in the pour spout during periods of operation at higher waste loadings. Given that both DWPF melters were or have been in operation for greater than 8 years, the service life of the melters has far exceeded design expectations. It is possible that the DWPF liquidus temperature approach is conservative, in that it may be possible to successfully operate the melter with a small degree of allowable crystallization in the glass. This could be a viable approach to increasing waste loading in the glass assuming that the crystals are suspended in the melt and swept out through the riser and pour spout. Additional study is needed, and development work for WTP might be leveraged to support a different operating limit for the DWPF. Several recommendations are made regarding considerations that need to be included as part of the WTP crystal tolerant strategy based on the DWPF development work and operational data reviewed here. These include: Identify and consider the impacts of potential heat sinks in the WTP melter and glass pouring system; Consider the contributions of refractory corrosion products, which may serve to nucleate additional crystals leading to further accumulation; Consider volatilization of components from the melt (e.g., boron, alkali, halides, etc.) and determine their impacts on glass crystallization behavior; Evaluate the impacts of glass REDuction/OXidation (REDOX) conditions and the distribution of temperature within the WTP melt pool and melter pour chamber on crystal accumulation rate; Consider the impact of precipitated crystals on glass viscosity; Consider the impact of an accumulated crystalline layer on thermal convection currents and bubbler effectiveness within the melt pool; Evaluate the impact of spinel accumulation on Joule heating of the WTP melt pool; and Include noble metals in glass melt experiments because of their potential to act as nucleation site

Fox, K. M.

2014-02-27T23:59:59.000Z

11

Energy Efficient Glass Melting - The Next Generation Melter  

SciTech Connect

The objective of this project is to demonstrate a high intensity glass melter, based on the submerged combustion melting technology. This melter will serve as the melting and homogenization section of a segmented, lower-capital cost, energy-efficient Next Generation Glass Melting System (NGMS). After this project, the melter will be ready to move toward commercial trials for some glasses needing little refining (fiberglass, etc.). For other glasses, a second project Phase or glass industry research is anticipated to develop the fining stage of the NGMS process.

David Rue

2008-03-01T23:59:59.000Z

12

Remote Fiber Laser Cutting System for Dismantling Glass Melter - 13071  

SciTech Connect

Since 2008, the equipment for dismantling the used glass melter has been developed in High-level Liquid Waste (HLW) Vitrification Facility in the Japanese Rokkasho Reprocessing Plant (RRP). Due to the high radioactivity of the glass melter, the equipment requires a fully-remote operation in the vitrification cell. The remote fiber laser cutting system was adopted as one of the major pieces of equipment. An output power of fiber laser is typically higher than other types of laser and so can provide high-cutting performance. The fiber laser can cut thick stainless steel and Inconel, which are parts of the glass melter such as casings, electrodes and nozzles. As a result, it can make the whole of the dismantling work efficiently done for a shorter period. Various conditions of the cutting test have been evaluated in the process of developing the remote fiber cutting system. In addition, the expected remote operations of the power manipulator with the laser torch have been fully verified and optimized using 3D simulations. (authors)

Mitsui, Takashi; Miura, Noriaki [IHI Corporation, 1 Shin-Nakahara-cho, Isogo-ku, Yokohama, Kanagawa (Japan)] [IHI Corporation, 1 Shin-Nakahara-cho, Isogo-ku, Yokohama, Kanagawa (Japan); Oowaki, Katsura; Kawaguchi, Isao [IHI Inspection and Instrumentation Co., Ltd, 1 Shin-Nakahara-cho, Isogo-ku, Yokohama, Kanagawa (Japan)] [IHI Inspection and Instrumentation Co., Ltd, 1 Shin-Nakahara-cho, Isogo-ku, Yokohama, Kanagawa (Japan); Miura, Yasuhiko; Ino, Tooru [Japan Nuclear Fuel Limited, 4-108, Aza Okitsuke, Oaza Obuchi, Rokkasho-Mura, Kamikita-gun, Aomori (Japan)] [Japan Nuclear Fuel Limited, 4-108, Aza Okitsuke, Oaza Obuchi, Rokkasho-Mura, Kamikita-gun, Aomori (Japan)

2013-07-01T23:59:59.000Z

13

Cold crucible induction melter studies for making glass ceramic waste forms: A feasibility assessment  

SciTech Connect

Glass ceramics are being developed to immobilize fission products, separated from used nuclear fuel by aqueous reprocessing, into a stable waste form suitable for disposal in a geological repository. This work documents the glass ceramic formulation at bench scale and for a scaled melter test performed in a pilot-scale (approximately 1/4 scale) cold crucible induction melter (CCIM). Melt viscosity, electrical conductivity, and crystallization behavior upon cooling were measured on a small set of compositions to select a formulation for melter testing. Property measurements also identified a temperature range for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form. Bench scale and melter run results successfully demonstrate the processability of the glass ceramic using the CCIM melter technology.

Jarrod Crum [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Vince Maio [Idaho National Laboratory (INL), Idaho Falls, ID (United States); John McCloy [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Clark Scott [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Brian Riley [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Brad Benefiel [Idaho National Laboratory (INL), Idaho Falls, ID (United States); John Vienna [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Kip Archibald [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Carmen Rodriguez [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Veronica Rutledge [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Zihua Zhu [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Joe Ryan [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Matthew Olszta [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

2014-01-01T23:59:59.000Z

14

ENVIRONMENTAL ASSESSMENT DOE/EA-0821 FOR THE OPERATION OF THE GLASS MELTER  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

. - . - ..... . - ... .,. ..... .. :,! ~ ENVIRONMENTAL ASSESSMENT DOE/EA-0821 FOR THE OPERATION OF THE GLASS MELTER THERMAL TREATMENT UNIT AT THE U.S. DEPARTMENT OF ENERGY'S MOUND PLANT, MIAMISBURG, OHIO . JUNE,1995 U.S. DEPARTMENT OF ENERGY L..-_ _ _ _ __ _ _ _ _ __ _ _ _ DIS _TRIBunON OF !HIS DocM~Sbli R DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. , ' .. TABLE OF CONTENTS PREFACE . . . .. ..... . .. . ...... .. . . .. .. . . ... . ....... ..*..... ... 1 1.0 INTRODUCTION ...... .. . .. . . ...... . .. . .. *.. .. . . . ***....... 1·1 1.1 PURPOSE AND NEED FOR ACTION .. . . * . . . . . . . . . . * . . . . . .. 1-1 1.2 BACKGROUND . . . . . . . . . . . . . . . . . * . * . . . . * * . * * . . . . . . .. 1·2

15

Laboratory-Scale Melter for Determination of Melting Rate of Waste Glass Feeds  

SciTech Connect

The purpose of this study was to develop the laboratory-scale melter (LSM) as a quick and inexpensive method to determine the processing rate of various waste glass slurry feeds. The LSM uses a 3 or 4 in. diameter-fused quartz crucible with feed and off-gas ports on top. This LSM setup allows cold-cap formation above the molten glass to be directly monitored to obtain a steady-state melting rate of the waste glass feeds. The melting rate data from extensive scaled-melter tests with Hanford Site high-level wastes performed for the Hanford Tank Waste Treatment and Immobilization Plant have been compiled. Preliminary empirical model that expresses the melting rate as a function of bubbling rate and glass yield were developed from the compiled database. The two waste glass feeds with most melter run data were selected for detailed evaluation and model development and for the LSM tests so the melting rates obtained from LSM tests can be compared with those from scaled-melter tests. The present LSM results suggest the LSM setup can be used to determine the glass production rates for the development of new glass compositions or feed makeups that are designed to increase the processing rate of the slurry feeds.

Kim, Dong-Sang; Schweiger, Michael J.; Buchmiller, William C.; Matyas, Josef

2012-01-09T23:59:59.000Z

16

The production of advanced glass ceramic HLW forms using cold crucible induction melter  

SciTech Connect

Cold Crucible Induction Melters (CCIM) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in a near future. Unlike the existing Joule-Heated Melters (JHM) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIM offers unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. It is concluded that glass ceramic waste forms that are tailored to immobilize fission products of HLW can be can be made from the HLW processed with the CCIM. The advantageous higher temperatures reached with the CCIM and unachievable with JHM allows the lanthanides, alkali, alkaline earths, and molybdenum to dissolve into a molten glass. Upon controlled cooling they go into targeted crystalline phases to form a glass ceramic waste form with higher waste loadings than achievable with borosilicate glass waste forms. Natural cooling proves to be too fast for the formation of all targeted crystalline phases.

Rutledge, V.J.; Maio, V. [Idaho National Laboratory: P.O. Box 1625, Idaho Falls, ID, 83415-2110 (United States)

2013-07-01T23:59:59.000Z

17

The Production of Advanced Glass Ceramic HLW Forms using Cold Crucible Induction Melter  

SciTech Connect

Cold Crucible Induction Melters (CCIMs) will favorably change how High-Level radioactive Waste (from nuclear fuel recovery) is treated in the 21st century. Unlike the existing Joule-Heated Melters (JHMs) currently in operation for the glass-based immobilization of High-Level Waste (HLW), CCIMs offer unique material features that will increase melt temperatures, increase throughput, increase mixing, increase loading in the waste form, lower melter foot prints, eliminate melter corrosion and lower costs. These features not only enhance the technology for producing HLW forms, but also provide advantageous attributes to the waste form by allowing more durable alternatives to glass. This paper discusses advantageous features of the CCIM, with emphasis on features that overcome the historical issues with the JHMs presently utilized, as well as the benefits of glass ceramic waste forms over borosilicate glass waste forms. These advantages are then validated based on recent INL testing to demonstrate a first-of-a-kind formulation of a non-radioactive ceramic-based waste form utilizing a CCIM.

Veronica J Rutledge; Vince Maio

2013-10-01T23:59:59.000Z

18

Final Report - Glass Formulation Development and DM10 Melter Testing with ORP LAW Glasses, VSL-09R1510-2, Rev. 0, dated 6/12/09  

SciTech Connect

The principal objective of the work described in this Final Report is to extend the glass formulation methodology developed in the earlier work by development of acceptable glass compositions for four LAW compositions specified by ORP that cover the range of sulfate to sodium and potassium to sodium ratios expected in Hanford LAW. The glass formulations were designed to exclude titanium and iron as glass former additives, while tin and vanadium as glass former additives were evaluated for beneficial effects in increasing waste loading in the glasses. This was accomplished through a combination of crucible-scale tests and tests on the DM10 melter system. This melter is the most efficient melter platform for screening glass compositions over a wide range of sulfate concentrations and therefore was selected for the present tests. The current tests provide information on melter processing characteristics and off-gas data, including sulfur incorporation and partitioning.

Kruger, Albert A.; Pegg, I. L.; Matlack, K. S.; Joseph, I.; Muller, I. S.; Gong, W.

2013-11-13T23:59:59.000Z

19

Glass melter off-gas system pluggages: Cause, significance, and remediation  

SciTech Connect

Liquid high-level nuclear waste will be immobilized at the Savannah River Site (SRS) by vitrification in borosilicate glass. The glass will be produced in the Defense Waste Processing Facility (DWPF) where the glass will be poured into stainless steel canisters for eventual disposal in a geologic repository. Experimental glass melters used to develop the vitrification process for immobilization of the waste have experienced problems with pluggage of the off-gas line with solid deposits. Off-gas deposits from the DWPF 1/2 Scale Glass Melter (SGM) and the 1/10th scale Integrated DWPF Melter System (IDMS) were determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides with entrained Fe{sub 2}O{sub 3}, spinel, and frit particles. The distribution and location of the alkali deposits throughout the off-gas system indicate that the deposits form by vapor-phase transport and condensation. Condensation of the alkali-rich phases cement the entrained particulates causing off-gas system pluggages. The identification of vapor phase transport as the operational mechanism causing off-gas system pluggage indicates that deposition can be effectively eliminated by increasing the off-gas velocity. Scale glass melter operating experience indicates that a velocity of >50 fps is necessary in order to transport the volatile species to the quencher to prevent having condensation occur in the off-gas line. Hotter off-gas line temperatures would retain the alkali compounds as vapors so that they would remain volatile until they reach the quencher. However, hotter off-gas temperatures can only be achieved by using less air/steam flow at the off-gas entrance, e.g. at the off-gas film cooler (OGFC). This would result in lower off-gas velocities. Maintaining a high velocity is, therefore, considered to be a more important criterion for controlling off-gas pluggage than temperature control. 40 refs., 16 figs., 5 tabs.

Jantzen, C.M.

1991-03-01T23:59:59.000Z

20

Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report  

SciTech Connect

The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

DM100 AND DM1200 MELTER TESTING WITH HIGH WASTE LOADING GLASS FORMULATIONS FOR HANFORD HIGH-ALUMINUM HLW STREAMS  

SciTech Connect

This Test Plan describes work to support the development and testing of high waste loading glass formulations that achieve high glass melting rates for Hanford high aluminum high level waste (HLW). In particular, the present testing is designed to evaluate the effect of using low activity waste (LAW) waste streams as a source of sodium in place ofchemical additives, sugar or cellulose as a reductant, boehmite as an aluminum source, and further enhancements to waste processing rate while meeting all processing and product quality requirements. The work will include preparation and characterization of crucible melts in support of subsequent DuraMelter 100 (DM 100) tests designed to examine the effects of enhanced glass formulations, glass processing temperature, incorporation of the LAW waste stream as a sodium source, type of organic reductant, and feed solids content on waste processing rate and product quality. Also included is a confirmatory test on the HLW Pilot Melter (DM1200) with a composition selected from those tested on the DM100. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy's (DOE's) Office of River Protection (ORP) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same waste composition. This Test Plan is prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the Hanford Tank Waste Treatment and Immobilization Plant (WTP) is about 12,500. This estimate is based upon the inventory ofthe tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat transfer and glass melting rate. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of {approx}1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HLW waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150 C and by increasing the waste loading in the glass product Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage. The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet WTP contract requirements. The WTP's overall mission will require the immobilization oftank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings. Results of this work have demonstrated the feasibility of increases in waste-loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. It is expected that these higher waste loading glasses will reduce the HLW canister production requirement by about 25% or more.

KRUGER AA; MATLACK KS; KOT WK; PEGG IL; JOSEPH I

2009-12-30T23:59:59.000Z

22

Silicate Based Glass Formulations for Immobilization of U.S. Defense Wastes Using Cold Crucible Induction Melters  

SciTech Connect

The cold crucible induction melter (CCIM) is an alternative technology to the currently deployed liquid-fed, ceramic-lined, Joule-heated melter for immobilizing of U.S. tank waste generated from defense related reprocessing. In order to accurately evaluate the potential benefits of deploying a CCIM, glasses must be developed specifically for that melting technology. Related glass formulation efforts have been conducted since the 1990s including a recent study that is first documented in this report. The purpose of this report is to summarize the silicate base glass formulation efforts for CCIM testing of U.S. tank wastes. Summaries of phosphate based glass formulation and phosphate and silicate based CCIM demonstration tests are reported separately (Day and Ray 2013 and Marra 2013, respectively). Combined these three reports summarize the current state of knowledge related to waste form development and process testing of CCIM technology for U.S. tank wastes.

Smith, Gary L.; Kim, Dong-Sang; Schweiger, Michael J.; Marra, James C.; Lang, Jesse B.; Crum, Jarrod V.; Crawford, Charles L.; Vienna, John D.

2014-05-22T23:59:59.000Z

23

Final Report - Glass Formulation Testing to Increase Sulfate Volatilization from Melter, VSL-04R4970-1, Rev. 0, dated 2/24/05  

SciTech Connect

The principal objectives of the DM100 and DM10 tests were to determine the impact of four different organics and one inorganic feed additive on sulfate volatilization and to determine the sulfur partitioning between the glass and the off-gas system. The tests provided information on melter processing characteristics and off-gas data including sulfur incorporation and partitioning. A series of DM10 and DM100 melter tests were conducted using a LAW Envelope A feed. The testing was divided into three parts. The first part involved a series of DM10 melter tests with four different organic feed additives: sugar, polyethylene glycol (PEG), starch, and urea. The second part involved two confirmatory 50-hour melter tests on the DM100 using the best combination of reductants and conditions based on the DM10 results. The third part was performed on the DM100 with feeds containing vanadium oxide (V{sub 2}O{sub 5}) as an inorganic additive to increase sulfur partitioning to the off-gas. Although vanadium oxide is not a reductant, previous testing has shown that vanadium shows promise for partitioning sulfur to the melter exhaust, presumably through its known catalytic effect on the SO{sub 2}/SO{sub 3} reaction. Crucible-scale tests were conducted prior to the melter tests to confirm that the glasses and feeds would be processable in the melter and that the glasses would meet the waste form (ILAW) performance requirements. Thus, the major objectives of these tests were to: ? Perform screening tests on the DM10 followed by tests on the DM100-WV system using a LAW -Envelope A feed with four organic additives to assess their impact on sulfur volatilization. ? Perform tests on the DM100-WV system using a LAW -Envelope A feed containing vanadium oxide to assess its impact on sulfur volatilization. ? Determine feed processability and product quality with the above additives. ? Collect melter emissions data to determine the effect of additives on sulfur partitioning and melter emissions. ? Collect and analyze discharged glass to determine sulfur retention in the glass. ? Prepare and characterize feeds and glasses with the additives to confirm that the feeds and the glass melts are suitable for processing in the DM100 melter. ? Prepare and characterize glasses with the additives to confirm that the glasses meet the waste form (ILAW) performance requirements.

Kruger, Albert A.; Matlack, K. A.; Pegg, I. L.; Gong, W.

2013-11-13T23:59:59.000Z

24

Iron Phosphate Glass for Vitrifying Hanford AZ102 LAW in Joule Heated and Cold Crucible Induction Melters  

SciTech Connect

An iron phosphate composition for vitrifying a high sulfate (~17 wt%) and high alkali (~80 wt%) low activity Hanford waste, known as AZ102 LAW, has been developed for processing in a Joule Heated Melter (JHM) or a Cold Crucible Induction Melter (CCIM). This composition produced a glass waste form, designated as MS26AZ102F-2, with a waste loading of 26 wt% of the AZ102 which corresponded to a total alkali and sulfate (SO3) content of 21 and 4.2 wt%, respectively. A slurry (7M Na) of MS26AZ102F-2 simulant was melted continuously at temperatures between 1030 and 1090C for 10 days in a small JHM at PNNL and for 7 days in a CCIM at INL. The as-cast glasses produced in both melters and in trial laboratory experiments along with their CCC-treated counterparts met the DOE LAW requirements for the Product Consistency Test (PCT) and the Vapor Hydration Test (VHT). These glass waste forms retained up to 77 % of the SO3 (3.3 wt%), 100% of the Cesium, and 33 to 44% of the rhenium, surrogate for Tc-99, all of which either exceeded or were comparable to the retention limit for these species in borosilicate glass nuclear waste form. Analyses of commercial K-3 refractory lining and the Inconel 693 metal electrodes used in JHM indicated only minimum corrosion of these components by the iron phosphate glass. This is the first time that an iron phosphate composition (slurry feed) was melted continuously in the JHM and CCIM, thereby, demonstrating that iron phosphate glasses can be used as alternative hosts for vitrifying nuclear waste.

Day, Delbert E.; Brow, R. K.; Ray, C. S.; Kim, Cheol-Woon; Reis, Signo T.; Vienna, John D.; Peeler, David K.; Johnson, Fabienne; Hansen, E. K.; Sevigny, Gary J.; Soelberg, Nicolas R.; Pegg, Ian L.; Gan, Hao

2012-01-05T23:59:59.000Z

25

DATA SUMMARY REPORT SMALL SCALE MELTER TESTING OF HLW ALGORITHM GLASSES MATRIX1 TESTS VSL-07S1220-1 REV 0 7/25/07  

SciTech Connect

Eight tests using different HLW feeds were conducted on the DM100-BL to determine the effect of variations in glass properties and feed composition on processing rates and melter conditions (off-gas characteristics, glass processing, foaming, cold cap, etc.) at constant bubbling rate. In over seven hundred hours of testing, the property extremes of glass viscosity, electrical conductivity, and T{sub 1%}, as well as minimum and maximum concentrations of several major and minor glass components were evaluated using glass compositions that have been tested previously at the crucible scale. Other parameters evaluated with respect to glass processing properties were +/-15% batching errors in the addition of glass forming chemicals (GFCs) to the feed, and variation in the sources of boron and sodium used in the GFCs. Tests evaluating batching errors and GFC source employed variations on the HLW98-86 formulation (a glass composition formulated for HLW C-106/AY-102 waste and processed in several previous melter tests) in order to best isolate the effect of each test variable. These tests are outlined in a Test Plan that was prepared in response to the Test Specification for this work. The present report provides summary level data for all of the tests in the first test matrix (Matrix 1) in the Test Plan. Summary results from the remaining tests, investigating minimum and maximum concentrations of major and minor glass components employing variations on the HLW98-86 formulation and glasses generated by the HLW glass formulation algorithm, will be reported separately after those tests are completed. The test data summarized herein include glass production rates, the type and amount of feed used, a variety of measured melter parameters including temperatures and electrode power, feed sample analysis, measured glass properties, and gaseous emissions rates. More detailed information and analysis from the melter tests with complete emission chemistry, glass durability, and melter operating details will be provided in the final report. A summary of the tests that were conducted is provided in Table 1. Each of the seven tests was of nominally one hundred hours in duration. Test B was conducted in two equal segments: the first with nominal additives, and the second with the replacement of borax with a mixture of boric acid and soda ash to determine the effect of alternative OPC sources on production rates and processing characteristics. Interestingly, sugar additions were required near mid points of Tests W and Z to reduce excessive foaming that severely limited feed processing rates. The sugar additions were very effective in recovering manageable processing conditions, albeit over the relatively short remainder of the test duration. Tests W and Z employed the highest melt viscosities but not by a particularly wide margin. Other tests, which did not exhibit such foaming Issues, employed higher concentrations of manganese or iron or both. These results highlight the need for the development of protocols for the a priori determination of which HLW feeds will require sugar additions and the appropriate amounts of sugar to be added in order to control foaming (and maintain throughput) without over-reduction of the melt (which could lead to molten metal formation). In total, over 8,800 kg of feed was processed to produce over 3200 kg of glass. Steady-state processing rates were achieved, and no secondary sulfate phases were observed during any of the tests. Analysis was performed on samples of the glass product taken throughout the tests to verify composition and properties. Sampling and analysis was also performed on melter exhaust to determine the effect of the feed and glass changes on melter emissions.

KRUGER AA; MATLACK KS; PEGG IL

2011-12-29T23:59:59.000Z

26

Preliminary melter performance assessment report  

SciTech Connect

The Melter Performance Assessment activity, a component of the Pacific Northwest Laboratory`s (PNL) Vitrification Technology Development (PVTD) effort, was designed to determine the impact of noble metals on the operational life of the reference Hanford Waste Vitrification Plant (HWVP) melter. The melter performance assessment consisted of several activities, including a literature review of all work done with noble metals in glass, gradient furnace testing to study the behavior of noble metals during the melting process, research-scale and engineering-scale melter testing to evaluate effects of noble metals on melter operation, and computer modeling that used the experimental data to predict effects of noble metals on the full-scale melter. Feed used in these tests simulated neutralized current acid waste (NCAW) feed. This report summarizes the results of the melter performance assessment and predicts the lifetime of the HWVP melter. It should be noted that this work was conducted before the recent Tri-Party Agreement changes, so the reference melter referred to here is the Defense Waste Processing Facility (DWPF) melter design.

Elliott, M.L.; Eyler, L.L.; Mahoney, L.A.; Cooper, M.F.; Whitney, L.D.; Shafer, P.J.

1994-08-01T23:59:59.000Z

27

High thermal expansion, sealing glass  

DOE Patents (OSTI)

A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

Brow, R.K.; Kovacic, L.

1993-11-16T23:59:59.000Z

28

Research-scale melter test report  

SciTech Connect

The Melter Performance Assessment (MPA) activity in the Pacific Northwest Laboratory`s (PNL) Hanford Waste Vitrification Plant (HWVP) Technology Development (PHTD) effort is intended to determine the impact of noble metals on the operational life of the reference HWVP melter. As a part of this activity, a parametric melter test was completed using a Research-Scale Melter (RSM). The RSM is a small, approximately 1/100-scale melter, 6-in.-diameter, that allows rapid changing of process conditions and subsequent re-establishment of a steady-state condition. The test matrix contained nine different segments that varied the melter operating parameters (glass and plenum temperatures) and feed properties (oxide concentration, redox potential, and noble metal concentrations) so that the effects of these parameters on noble metal agglomeration on the melter floor could be evaluated. The RSM operated for 48 days and consumed 1,300 L of feed, equating to 153 tank turnovers. The run produced 531 kg of glass. During the latter portion of the run, the resistance between the electrodes decreased. Upon destructive examination of the melter, a layer of noble metals was found on the bottom. This was surprising because the glass residence time in the RSM is only 10% of the HWVP plant melter. The noble metals layer impacted the melter significantly. Approximately 1/3 of one paddle electrode was melted or corroded off. The cause is assumed to be localized heating from short circuiting of the electrode to the noble metal layer. The metal layer also removed approximately 1/2 in. of the refractory on the bottom of the melter. The mechanism for this damage is not presently known.

Cooper, M.F.; Elliott, M.L.; Eyler, L.L.; Freeman, C.J.; Higginson, J.J.; Mahoney, L.A.; Powell, M.R.

1994-05-01T23:59:59.000Z

29

Melter development needs assessment for RWMC buried wastes  

SciTech Connect

This report presents a survey and initial assessment of the existing state-of-the-art melter technology necessary to thermally treat (stabilize) buried TRU waste, by producing a highly leach resistant glass/ceramic waste form suitable for final disposal. Buried mixed transuranic (TRU) waste at the Idaho National Engineering Laboratory (INEL) represents an environmental hazard requiring remediation. The Environmental Protection Agency (EPA) placed the INEL on the National Priorities List in 1989. Remediation of the buried TRU-contaminated waste via the CERCLA decision process is required to remove INEL from the National Priorities List. A Waste Technology Development (WTD) Preliminary Systems Design and Thermal Technologies Screening Study identified joule-heated and plasma-heated melters as the most probable thermal systems technologies capable of melting the INEL soil and waste to produce the desired final waste form (Iron-Enriched Basalt (IEB) glass/ceramic). The work reported herein then surveys the state of existing melter technology and assesses it within the context of processing INEL buried TRU wastes and contaminated soils. Necessary technology development work is recommended.

Donaldson, A.D.; Carpenedo, R.J.; Anderson, G.L.

1992-02-01T23:59:59.000Z

30

Melter development needs assessment for RWMC buried wastes  

SciTech Connect

This report presents a survey and initial assessment of the existing state-of-the-art melter technology necessary to thermally treat (stabilize) buried TRU waste, by producing a highly leach resistant glass/ceramic waste form suitable for final disposal. Buried mixed transuranic (TRU) waste at the Idaho National Engineering Laboratory (INEL) represents an environmental hazard requiring remediation. The Environmental Protection Agency (EPA) placed the INEL on the National Priorities List in 1989. Remediation of the buried TRU-contaminated waste via the CERCLA decision process is required to remove INEL from the National Priorities List. A Waste Technology Development (WTD) Preliminary Systems Design and Thermal Technologies Screening Study identified joule-heated and plasma-heated melters as the most probable thermal systems technologies capable of melting the INEL soil and waste to produce the desired final waste form [Iron-Enriched Basalt (IEB) glass/ceramic]. The work reported herein then surveys the state of existing melter technology and assesses it within the context of processing INEL buried TRU wastes and contaminated soils. Necessary technology development work is recommended.

Donaldson, A.D.; Carpenedo, R.J.; Anderson, G.L.

1992-02-01T23:59:59.000Z

31

Melter performance during surrogate vitrification campaigns at the DOE/Industrial Center for Vitrification Research at Clemson University  

SciTech Connect

This report summarizes the results from seven melter campaigns performed at the DOE/Industrial Center for Vitrification Research at Clemson University. A brief description of the EnVitco EV-16 Joule heated glass melter and the Stir-Melter WV-0.25 stirred melter are included for reference. The report discusses each waste stream examined, glass formulations developed and utilized, specifics relating to melter operation, and a synopsis of the results from the campaigns. A `lessons learned` section is included for each melter to emphasize repeated processing problems and identify parameters which are considered extremely important to successful melter operation

Marra, J.C. [Westinghouse Savannah River Company, AIKEN, SC (United States); Overcamp, T.J.

1995-10-05T23:59:59.000Z

32

Savannah River Site Marks Waste Processing Milestone with Melter's  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Savannah River Site Marks Waste Processing Milestone with Savannah River Site Marks Waste Processing Milestone with Melter's 2,000th Waste Canister Savannah River Site Marks Waste Processing Milestone with Melter's 2,000th Waste Canister February 1, 2012 - 12:00pm Addthis A Savannah River Remediation employee uses a manipulator located inside a shielded enclosure at the Defense Waste Processing Facility, where a melter pours molten glass into a canister. A Savannah River Remediation employee uses a manipulator located inside a shielded enclosure at the Defense Waste Processing Facility, where a melter pours molten glass into a canister. AIKEN, S.C. - The second melter to operate in the 16-year history of the nation's largest radioactive waste glassification plant shows no signs of slowing after recently pouring its 2,000 canister of glass-formed hazardous

33

Savannah River Site Marks Waste Processing Milestone with Melter's  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Marks Waste Processing Milestone with Marks Waste Processing Milestone with Melter's 2,000th Waste Canister Savannah River Site Marks Waste Processing Milestone with Melter's 2,000th Waste Canister February 1, 2012 - 12:00pm Addthis A Savannah River Remediation employee uses a manipulator located inside a shielded enclosure at the Defense Waste Processing Facility, where a melter pours molten glass into a canister. A Savannah River Remediation employee uses a manipulator located inside a shielded enclosure at the Defense Waste Processing Facility, where a melter pours molten glass into a canister. AIKEN, S.C. - The second melter to operate in the 16-year history of the nation's largest radioactive waste glassification plant shows no signs of slowing after recently pouring its 2,000 canister of glass-formed hazardous

34

Induction melter apparatus  

DOE Patents (OSTI)

Apparatus and methods of operation are provided for a cold-crucible-induction melter for vitrifying waste wherein a single induction power supply may be used to effect a selected thermal distribution by independently energizing at least two inductors. Also, a bottom drain assembly may be heated by an inductor and may include an electrically resistive heater. The bottom drain assembly may be cooled to solidify molten material passing therethrough to prevent discharge of molten material therefrom. Configurations are provided wherein the induction flux skin depth substantially corresponds with the central longitudinal axis of the crucible. Further, the drain tube may be positioned within the induction flux skin depth in relation to material within the crucible or may be substantially aligned with a direction of flow of molten material within the crucible. An improved head design including four shells forming thermal radiation shields and at least two gas-cooled plenums is also disclosed.

Roach, Jay A [Idaho Falls, ID; Richardson, John G [Idaho Falls, ID; Raivo, Brian D [Idaho Falls, ID; Soelberg, Nicholas R [Idaho Falls, ID

2008-06-17T23:59:59.000Z

35

Molten Glass for Thermal Storage: Advanced Molten Glass for Heat Transfer and Thermal Energy Storage  

SciTech Connect

HEATS Project: Halotechnics is developing a high-temperature thermal energy storage system using a new thermal-storage and heat-transfer material: earth-abundant and low-melting-point molten glass. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at nightwhen the sun is not outto drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. Halotechnics new thermal storage material targets a price that is potentially cheaper than the molten salt used in most commercial solar thermal storage systems today. It is also extremely stable at temperatures up to 1200Chundreds of degrees hotter than the highest temperature molten salt can handle. Being able to function at high temperatures will significantly increase the efficiency of turning heat into electricity. Halotechnics is developing a scalable system to pump, heat, store, and discharge the molten glass. The company is leveraging technology used in the modern glass industry, which has decades of experience handling molten glass.

None

2012-01-01T23:59:59.000Z

36

Cold-Crucible Induction Melter Design and Development  

SciTech Connect

The international process for immobilization of high-activity waste from aqueous fuel reprocessing is vitrification. In the United States joule-heated melter technology has been implemented at West Valley and the Savannah River Site, but improved melter concepts are sought to bring down the costs of processing. The cold-crucible induction melter (CCIM) design is being evaluated for many applications, including radioactive wastes because it eliminates many materials and operating constraints inherent in the baseline technology. The cold-crucible design is also smaller, less expensive, and generates much less waste for ultimate disposal. In addition, it should allow a much more flexible operating envelope, which will be crucial if the heterogeneous wastes at the U.S. Department of Energy (DOE) reprocessing sites are to be vitrified.A joule-heated melter operates by passing current between water-cooled electrodes through a molten pool in a refractory-lined chamber. This design is inherently limited by susceptibility of materials to corrosion and melting. In addition, redox conditions and free metal content have exacerbated materials problems or lead to electrical short-circuiting causing failures in developmental DOE melters. In contrast, the CCIM design is based on inductive coupling of a water-cooled high-frequency electrical coil with the glass, causing eddy currents that produce heat and mixing.While significant marketing claims have been made by technology suppliers and developers, little data is available for engineering and economic evaluation of the technology, and no facilities are available in the United States to support testing. In addition to verifying the capabilities of the technology, further development can exploit opportunities for optimization through better understanding of the electromagnetic thermal phenomena intrinsic to the cold-crucible melter. Induction frequency, applied power, and coil and crucible configuration are all related but independent variables that can be explored to optimize throughput while designing a system for maximum reliability in a remote environment. This paper is an introduction to the technology as it applies to vitrification of materials not electrically conductive at ambient temperatures, the potential for research improvements, and the new system being built at the Idaho National Engineering and Environmental Laboratory.

Gombert, Dirk; Richardson, John R. [Bechtel BWXT Idaho, LLC (United States)

2003-03-15T23:59:59.000Z

37

Glass fiber composition. [for use as thermal insulation  

DOE Patents (OSTI)

The invention relates to a glass fiber composition useful for thermal insulation having a low melting temperature and high chemical durability.

Wolf, G.A.; Kupfer, M.J.

1980-12-19T23:59:59.000Z

38

Thermal Gradient Holes At Glass Mountain Area (Cumming And Mackie...  

Open Energy Info (EERE)

Area (Cumming And Mackie, 2007) Exploration Activity Details Location Glass Mountain Geothermal Area Exploration Technique Thermal Gradient Holes Activity Date Usefulness not...

39

CRYSTALLIZATION IN MULTICOMPONENT GLASSES  

SciTech Connect

In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

KRUGER AA; HRMA PR

2009-10-08T23:59:59.000Z

40

Molten Oxide Glass Materials for Thermal Energy Storage  

Science Journals Connector (OSTI)

Abstract Halotechnics, Inc. is developing an energy storage system utilizing a low melting point molten glass as the heat transfer and thermal storage material. This work is supported under a grant from the Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E). Advanced oxide glasses promise a potential breakthrough as a low cost, earth abundant, and stable thermal storage material. The system and new glass material will enable grid scale electricity storage at a fraction of the cost of batteries by integrating the thermal storage with a large heat pump device. Halotechnics is combining its proven expertise in combinatorial chemistry with advanced techniques for handling molten glass to design and build a two-tank thermal energy storage system. This system, operating at a high temperature of 1200C and a low temperature of 400C, will demonstrate sensible heat thermal energy storage using a uniquely formulated oxide glass. Our molten glass thermal storage material has the potential to significantly reduce thermal storage costs once developed and deployed at commercial scale. Thermal storage at the target temperature can be integrated with existing high temperature gas turbines that significantly increase efficiencies over today's steam turbine technology. This paper describes the development and selection of Halotechnics molten glass heat transfer fluids with some additional systems considerations.

B. Elkin; L. Finkelstein; T. Dyer; J. Raade

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Formic acid requirement for the Savannah River Site Defense Waste Processing Facility melter feed preparation  

SciTech Connect

The Westinghouse Savannah River Company (WSRC) will vitrify the high-level radioactive waste into a borosilicate glass wasteform using a slurry-fed, joule-heated melter. Formic acid is used to treat the sludge slurry for melter feed preparation. Both a minimum formate requirement and a maximum allowable formate level need to be established to adequately prepare the sludge for melter feed. The data from the Savannah River Laboratory (SRL) Scale Glass Melter (SGM), Integrated DWPF Melter System (IDMS), and research mini-melter runs were used for this purpose. The stoichiometry for major reactions during formic acid treatment was revised to reflect the more predominant chemical reactions and their yields. A minimum formic acid requirement was established according to this revised stoichiometry. Methods for determining the minimum level of formic acid were specified. An operating envelope that includes the maximum total formate level and the minimum nitrate levels, was also proposed. 5 refs., 3 figs., 4 tabs.

Hsu, C.W.

1991-01-01T23:59:59.000Z

42

Final Vitrification Melter Evaluation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste-Incidental-to-Reprocessing Evaluation Waste-Incidental-to-Reprocessing Evaluation for the West Valley Demonstration Project Vitrification Melter February 2012 Prepared by the U.S. Department of Energy West Valley, New York This page is intentionally blank. WASTE-INCIDENTAL-TO-REPROCESSING EVALUATION FOR THE WVDP VITRIFICATION MELTER CONTENTS Revision 0 i NOTATION (Acronyms, Abbreviations, and Units).................................................. v 1.0 INTRODUCTION ...................................................................................................... 1 1.1 Purpose. ................................................................................................................. 2 1.2 Scope and Technical Basis ....................................................................................... 2

43

Effect of Feeding Rate on the Cold Cap Configuration in a Laboratory-Scale Melter - 13362  

SciTech Connect

High-level-waste melter feed is converted into glass in a joule-heated melter, where it forms a floating layer of reacting feed, called the cold cap. After the glass-forming phase becomes connected, evolving gases produce bubbles that form a foam layer under the feed. The bubbles coalesce into cavities, from which most of the gases are released around the edges of the cold cap while gases also escape through small shafts in the reacting feed. The foam layer insulates the cold cap from the heat transferred from the molten glass below. The cold cap behavior was investigated in a laboratory-scale assembly with a fused silica crucible. A high-alumina waste simulant was fed into the crucible and the feed charging rate was varied from 3 to 7 mL min{sup -1}. After a fixed amount of time (35 min), feed charging was stopped and the crucible was removed from the furnace and quenched on a copper block to preserve the structure of the cold cap during cooling. During the rapid quenching, thermal cracking of the glass and cold cap allowed it to be broken up into sections for analysis. The effect of the charging rate on the height, area and volume of the cold cap was determined. The size of the bubbles collected in the foam layer under the feed increased as the cold cap expanded and the relationship between these bubbles and temperature will be determined for input into a mathematical model. (authors)

Dixon, Derek R.; Schweiger, Michael J. [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)] [Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Hrma, Pavel [Pacific Northwest National Laboratory, Richland, WA 99354 (United States) [Pacific Northwest National Laboratory, Richland, WA 99354 (United States); Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, Pohang (Korea, Republic of)

2013-07-01T23:59:59.000Z

44

Milliwave melter monitoring system  

DOE Patents (OSTI)

A milliwave melter monitoring system is presented that has a waveguide with a portion capable of contacting a molten material in a melter for use in measuring one or more properties of the molten material in a furnace under extreme environments. A receiver is configured for use in obtaining signals from the melt/material transmitted to appropriate electronics through the waveguide. The receiver is configured for receiving signals from the waveguide when contacting the molten material for use in determining the viscosity of the molten material. Other embodiments exist in which the temperature, emissivity, viscosity and other properties of the molten material are measured.

Daniel, William E. (North Augusta, SC); Woskov, Paul P. (Bedford, MA); Sundaram, Shanmugavelayutham K. (Richland, WA)

2011-08-16T23:59:59.000Z

45

PHYSICAL CHARACTERIZATION OF VITREOUS STATE LABORATORY AY102/C106 AND AZ102 HIGH LEVEL WASTE MELTER FEED SIMULANTS (U)  

SciTech Connect

The objective of this task is to characterize and report specified physical properties and pH of simulant high level waste (HLW) melter feeds (MF) processed through the scaled melters at Vitreous State Laboratories (VSL). The HLW MF simulants characterized are VSL AZ102 straight hydroxide melter feed, VSL AZ102 straight hydroxide rheology adjusted melter feed, VSL AY102/C106 straight hydroxide melter feed, VSL AY102/C106 straight hydroxide rheology adjusted melter feed, and Savannah River National Laboratory (SRNL) AY102/C106 precipitated hydroxide processed sludge blended with glass former chemicals at VSL to make melter feed. The physical properties and pH were characterized using the methods stated in the Waste Treatment Plant (WTP) characterization procedure (Ref. 7).

Hansen, E

2005-03-31T23:59:59.000Z

46

Glass melter system technologies for vitrification of high-sodium-content low-level, radioactive, liquid wastes: Phase 1, SBS demonstration with simulated low-level waste. Final test report  

SciTech Connect

The attached vendor report was prepared for Westinghouse Hanford Company by Babcock & Wilcox as documentation of the Phase I Final Test Report, Cyclone Combustion Melter Demonstration.

Holmes, M.J.; Scotto, M.V.; Shiao, S.Y. [Babcock & Wilcox, Alliance, OH (United States) Research Center

1995-12-31T23:59:59.000Z

47

Glass transition in Ultrathin Polymer Films : A Thermal Expansion Study  

E-Print Network (OSTI)

Glass transition process gets affected in ultrathin films having thickness comparable to the size of the molecules. We observe systematic broadening of glass transition temperature (Tg) as the thickness of the polymer film reduces below the radius of gyration but the change in the average Tg was found to be very small. Existence of reversible negative and positive thermal expansion below and above Tg increased the sensitivity of our thickness measurements performed using energy dispersive x-ray reflectivity. A simple model of Tg variation as a function of depth expected from sliding motion could explain the results. We observe clear glass transition even for 4 nm polystyrene film that was predicted to be absent from ellipsometry measurements of thicker films.

M. Bhattacharya; M. K. Sanyal; Th. Geue; U. Pietsch

2005-01-19T23:59:59.000Z

48

CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER SAMPLE  

SciTech Connect

The Savannah River National Laboratory (SRNL) recently received a deposit sample from the Melter Primary Off Gas System (POG) of the Defense Waste Processing Facility (DWPF). This sample was composed of material that had been collected while the quencher was in operation January 27, 2011 through March 31, 2011. DWPF requested, through a technical assistance request, characterization of the melter off-gas deposits by x-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical analysis. The purpose of the Melter Off-Gas System is to reduce the amount of radioactive particles and mercury in the gases vented to the atmosphere. Gases emitted from the melter pass through the primary film cooler, quencher, Off-Gas Condensate Tank (OGCT), Steam Atomized Scrubbers (SAS), a condenser, a high efficiency mist eliminator, and a high efficiency particulate air filter, before being vented to the Process Vessel Vent System. The film coolers cool the gases leaving the melter vapor space from {approx}750 C to {approx}375 C, by introducing air and steam to the flow. In the next step, the quencher cools the gas to about 60 C by bringing the condensate from the OGCT in contact with the effluent (Figure 1). Most of the steam in the effluent is then condensed and the melter vapor space pressure is reduced. The purpose of the OGCT is to collect and store the condensate formed during the melter operation. Condensate from the OGCT is circulated to the SAS and atomized with steam. This atomized condensate is mixed with the off-gas to wet and join the particulate which is then removed in the cyclone. The next stage incorporates a chilled water condenser which separates the vapors and elemental mercury from the off-gas steam. Primary off-gas deposit samples from the DWPF melter have previously been analyzed. In 2003, samples from just past the film cooler, from the inlet of the quencher and inside the quencher were analyzed at SRNL. It was determined that the samples were a mixture of sludge and glass frit. The major component was Si along with Fe, Al, and other elements in the radioactive waste being processed. The deposits analyzed also contained U-235 fission products and actinide elements. Prior to that, deposits in the off-gas system in the DWPF nonradioactive half scale melter and the one-tenth scale integrated DWPF melter system were analyzed and determined to be mixtures of alkali rich chlorides, sulfates, borates, and fluorides entrained with iron oxides, spinels and frit particles formed by vapor-phase transport and condensation. Additional work was performed in 2007 in which researchers similarly found the deposits to be a combination of sludge and frit particles.

Newell, J.

2011-11-14T23:59:59.000Z

49

Microsoft Word - Melter 2 Celebrates 10 Years.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Media contact: Dean Campbell 803.208.8270 dean.campbell@srs.gov DWPF Melter 2 Celebrates 10 th Anniversary AIKEN, S.C. (March 26, 2013) - What has been called the "heart" of the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) is celebrating its 10 th anniversary, a full eight years beyond its design life expectancy. Melter 2, the 65-ton, teapot-shaped vessel treats high-level radioactive waste being stored in SRS waste tanks by blending it with a borosilicate frit to form a molten glass mixture. The mixture is poured into stainless steel canisters, which are decontaminated and stored on-site until a permanent storage facility is identified. The melter, only the second in the 17-year history of DWPF, is celebrating 10 years of

50

HLW Melter Control Strategy Without Visual Feedback VSL-12R2500-1 Rev 0  

SciTech Connect

Plans for the treatment of high level waste (HL W) at the Hanford Tank Waste Treatment and Immobilization Plant (WTP) are based upon the inventory of the tank wastes, the anticipated performance of the pretreatment processes, and current understanding of the capability of the borosilicate glass waste form [I]. The WTP HLW melter design, unlike earlier DOE melter designs, incorporates an active glass bubbler system. The bubblers create active glass pool convection and thereby improve heat and mass transfer and increase glass melting rates. The WTP HLW melter has a glass surface area of 3.75 m{sup 2} and depth of ~ 1.1 m. The two melters in the HLW facility together are designed to produce up to 7.5 MT of glass per day at 100% availability. Further increases in HL W waste processing rates can potentially be achieved by increasing the melter operating temperature above 1150?C and by increasing the waste loading in the glass product. Increasing the waste loading also has the added benefit of decreasing the number of canisters for storage.

Kruger, A A. [Department of Energy, Office of River Protection, Richland, Washington (United States); Joseph, Innocent [The Catholic University of America, Washington, DC (United States); Matlack, Keith S. [The Catholic University of America, Washington, DC (United States); Callow, Richard A. [The Catholic University of America, Washington, DC (United States); Abramowitz, Howard [The Catholic University of America, Washington, DC (United States); Pegg, Ian L. [The Catholic University of America, Washington, DC (United States); Brandys, Marek [The Catholic University of America, Washington, DC (United States); Kot, Wing K. [The Catholic University of America, Washington, DC (United States)

2012-11-13T23:59:59.000Z

51

INTEGRATED DM 1200 MELTER TESTING OF HLW C-106/AY-102 COMPOSITION USING BUBBLERS VSL-03R3800-1 REV 0 9/15/03  

SciTech Connect

This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of simulated HLW C-106/AY-102 feed. The principal objectives of the DM1200 melter testing were to determine the achievable glass production rates for simulated HLW C-106/AY-102 feed; determine the effect of bubbling rate on production rate; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and to perform pre- and post test inspections of system components.

KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; KOT WK; PEGG IL

2011-12-29T23:59:59.000Z

52

Development of a simplified thermal analysis procedure for insulating glass units  

E-Print Network (OSTI)

A percentage of insulating glass (IG) units break each year due to thermally induced perimeter stresses. The glass industry has known about this problem for many years and an ASTM standard has recently been developed for the design of monolithic...

Klam, Jeremy Wayne

2009-06-02T23:59:59.000Z

53

Pressurized heat treatment of glass-ceramic to control thermal expansion  

DOE Patents (OSTI)

A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

Kramer, Daniel P. (Dayton, OH)

1985-01-01T23:59:59.000Z

54

Extended Development Work to Validate a HLW Calcine Waste Form via INL's Cold Crucible Induction Melter  

SciTech Connect

To accomplish calcine treatment objectives, the Idaho Clean-up Project contractor, CWI, has chosen to immobilize the calcine in a glass-ceramic via the use of a Hot-Isostatic-Press (HIP); a treatment selection formally documented in a 2010 Record of Decision (ROD). Even though the HIP process may prove suitable for the calcine as specified in the ROD and validated in a number of past value engineering sessions, DOE is evaluating back-up treatment methods for the calcine as a result of the technical, schedule, and cost risk associated with the HIPing process. Consequently DOE HQ has requested DOE ID to make INL's bench-scale cold-crucible induction melter (CCIM) available for investigating its viability as a process alternate to calcine treatment. The waste form is the key component of immobilization of radioactive waste. Providing a solid, stable, and durable material that can be easily be stored is the rationale for immobilization of radioactive waste material in glass, ceramic, or glass-ceramics. Ceramic waste forms offer an alternative to traditional borosilicate glass waste forms. Ceramics can usually accommodate higher waste loadings than borosilicate glass, leading to smaller intermediate and long-term storage facilities. Many ceramic phases are known to possess superior chemical durability as compared to borosilicate glass. However, ceramics are generally multiphase systems containing many minor phase that make characterization and prediction of performance within a repository challenging. Additionally, the technologies employed in ceramic manufacture are typically more complex and expensive. Thus, many have proposed using glass-ceramics as compromise between in the more inexpensive, easier to characterize glass waste forms and the more durable ceramic waste forms. Glass-ceramics have several advantages over traditional borosilicate glasses as a waste form. Borosilicate glasses can inadvertently devitrify, leading to a less durable product that could crack during cooling and crystals may be prone to dissolution. By designing a glass-ceramics, the risks of deleterious effects from devitrification are removed. Furthermore, glass-ceramics have higher mechanical strength and impact strengths and possess greater chemical durability as noted above. Glass-ceramics should provide a waste form with the advantages of glass - ease of manufacture - with improved mechanical properties, thermal stability, and chemical durability. This report will cover aspects relevant for the validation of the CCIM use in the production of glass-ceramic waste forms.

James A. King; Vince Maio

2011-09-01T23:59:59.000Z

55

Vitrification of noble metals containing NCAW simulant with an engineering scale melter (ESM): Campaign report  

SciTech Connect

ESM has been designed as a 10th-scale model of the DWPF-type melter, currently the reference melter for nitrification of Hanford double shell tankwaste. ESM and related equipment have been integrated to the existing mockup vitrification plant VA-WAK at KfK. On June 2-July 10, 1992, a shakedown test using 2.61 m{sup 3} of NCAW (neutralized current acid waste) simulant without noble metals was performed. On July 11-Aug. 30, 1992, 14.23 m{sup 3} of the same simulant with nominal concentrations of Ru, Rh, and Pd were vitrified. Objective was to investigate the behavior of such a melter with respect to discharge of noble metals with routine glass pouring via glass overflow. Results indicate an accumulation of noble metals in the bottom area of the flat-bottomed ESM. About 65 wt% of the noble metals fed to the melter could be drained out, whereas 35 wt% accumulated in the melter, based on analysis of glass samples from glass pouring stream in to the canisters. After the melter was drained at the end of the campaign through a bottom drain valve, glass samples were taken from the residual bottom layer. The samples had significantly increased noble metals content (factor of 20-45 to target loading). They showed also a significant decrease of the specific electric resistance compared to bulk glass (factor of 10). A decrease of 10- 15% of the resistance between he power electrodes could be seen at the run end, but the total amount of noble metals accumulated was not yet sufficient enough to disturb the Joule heating of the glass tank severely.

Grunewald, W.; Roth, G.; Tobie, W.; Weisenburger, S.; Weiss, K.; Elliott, M.; Eyler, L.L.

1996-03-01T23:59:59.000Z

56

Final Vitrification Melter And Vessels Evaluation Documentation  

Energy.gov (U.S. Department of Energy (DOE))

DOE has prepared final evaluations and made waste incidental to reprocessing determinations for the vitrification melter and feed vessels (the concentrator feed makeup tank and the melter feed hold...

57

Final Report - Testing of Optimized Bubbler Configuration for HLW Melter VSL-13R2950-1, Rev. 0, dated 6/12/2013  

SciTech Connect

The principal objective of this work was to determine the glass production rate increase and ancillary effects of adding more bubbler outlets to the current WTP HLW melter baseline. This was accomplished through testing on the HLW Pilot Melter (DM1200) at VSL. The DM1200 unit was selected for these tests since it was used previously with several HLW waste streams including the four tank wastes proposed for initial processing at Hanford. This melter system was also used for the development and optimization of the present baseline WTP HLW bubbler configuration for the WTP HLW melter, as well as for MACT testing for both HLW and LAW. Specific objectives of these tests were to: Conduct DM1200 melter testing with the baseline WTP bubbling configuration and as augmented with additional bubblers. Conduct DM1200 melter testing to differentiate the effects of total bubbler air flow and bubbler distribution on glass production rate and cold cap formation. Collect melter operating data including processing rate, temperatures at a variety of locations within the melter plenum space, melt pool temperature, glass melt density, and melter pressure with the baseline WTP bubbling configuration and as augmented with additional bubblers. Collect melter exhaust samples to compare particulate carryover for different bubbler configurations. Analyze all collected data to determine the effects of adding more bubblers to the WTP HLW melter to inform decisions regarding future lid re-designs. The work used a high aluminum HLW stream composition defined by ORP, for which an appropriate simulant and high waste loading glass formulation were developed and have been previously processed on the DM1200.

Kruger, Albert A.; Pegg, I. L.; Callow, R. A.; Joseph, I.; Matlack, K. S.; Kot, W. K.

2013-11-13T23:59:59.000Z

58

Tunable molten oxide pool assisted plasma-melter vitrification systems  

DOE Patents (OSTI)

The present invention provides tunable waste conversion systems and apparatus which have the advantage of highly robust operation and which provide complete or substantially complete conversion of a wide range of waste streams into useful gas and a stable, nonleachable solid product at a single location with greatly reduced air pollution to meet air quality standards. The systems provide the capability for highly efficient conversion of waste into high quality combustible gas and for high efficiency conversion of the gas into electricity by utilizing a high efficiency gas turbine or an internal combustion engine. The solid product can be suitable for various commercial applications. Alternatively, the solid product stream, which is a safe, stable material, may be disposed of without special considerations as hazardous material. In the preferred embodiment, the arc plasma furnace and joule heated melter are formed as a fully integrated unit with a common melt pool having circuit arrangements for the simultaneous independently controllable operation of both the arc plasma and the joule heated portions of the unit without interference with one another. The preferred configuration of this embodiment of the invention utilizes two arc plasma electrodes with an elongated chamber for the molten pool such that the molten pool is capable of providing conducting paths between electrodes. The apparatus may additionally be employed with reduced use or without further use of the gases generated by the conversion process. The apparatus may be employed as a net energy or net electricity producing unit where use of an auxiliary fuel provides the required level of electricity production. Methods and apparatus for converting metals, non-glass forming waste streams and low-ash producing inorganics into a useful gas are also provided. The methods and apparatus for such conversion include the use of a molten oxide pool having predetermined electrical, thermal and physical characteristics capable of maintaining optimal joule heating and glass forming properties during the conversion process.

Titus, Charles H. (Newtown Square, PA); Cohn, Daniel R. (Chestnut Hill, MA); Surma, Jeffrey E. (Kennewick, WA)

1998-01-01T23:59:59.000Z

59

Method for melting glass by measurement of non-bridging oxygen  

DOE Patents (OSTI)

A method for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a "non-bridging oxygen" term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term.

Jantzen, Carol M. (3922 Wood Valley Dr., Aiken, SC 29801)

1992-01-01T23:59:59.000Z

60

Optical loss reduction in HIC chalcogenide glass waveguides via thermal reflow  

E-Print Network (OSTI)

A rapid thermal reflow technique is applied to high-index-contrast, sub-micron waveguides in As[subscript 2]S[subscript 3] chalcogenide glass to reduce sidewall roughness and associated optical scattering loss. Up to 50% ...

Hu, Juejun

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Thermal Predictions of the Cooling of Waste Glass Canisters  

SciTech Connect

Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

Donna Post Guillen

2014-11-01T23:59:59.000Z

62

Dynamic thermal simulation of a glass-covered semi-outdoor space with roof evaporative cooling  

Science Journals Connector (OSTI)

In the hot season solar radiation impinging on a glass roofing may overheat the underneath space to temperature values which may generate a high stress environment. To moderate the extreme microclimate which may occur in a glass covered semi-outdoor space, evaporative cooling to be applied to the glass roof is suggested. The analysis is performed under both the thermal and the energetic point of view, by accounting for the actual climate of the considered location. The results point out that roof evaporative cooling coupled with glass sheet high solar radiation absorptivity may offer an attractive way for the control of a semi-outdoor environment.

G. Pagliarini; S. Rainieri

2011-01-01T23:59:59.000Z

63

Noble metals-compatible melter features development Phase 1: Establishing functional and design criteria and design concepts  

SciTech Connect

Premature failures have occurred in melters at Japan`s Tokai Mockup Facility and at the Federal Republic of Germany (FRG) PAMELA plant during processing of feeds with high levels of noble metals. Melter failure was due to the accumulation of an electrically conductive, noble metals-containing precipitates in the glass, that then resulted in short circuiting of the electrodes. A comparison was made of the anticipated Hanford Waste Vitrification Plant (HWVP) feed with the feeds processed in the FRG and Japanese melters. The evaluation showed that comparable levels of noble metals and other potential precipitate-forming components (e.g. Cr/Fe/Ni-spinels) exist in the HWVP feed. As a result, the HWVP project made a decision to modify the present reference melter design to include features to prevent the precipitation and accumulation or otherwise accommodate precipitated phases on a routine basis without loss of production capacity.

Elmore, M.R.; Siemens, D.H.; Chapman, C.C.

1996-03-01T23:59:59.000Z

64

Shortwave thermal performance for a glass window with a curved venetian blind  

Science Journals Connector (OSTI)

This paper presents a study of thermal performance for a glass window with a curved venetian blind installed on the indoor side in terms of heat gain in the shortwave part of radiation. The curved venetian blind, whose optical properties are considered nonspecular, is modeled as an effective layer. The mathematical model of the combined glass window and venetian blind is developed by combining the mathematical model of glass window and the mathematical model of a curved venetian blind using the matrix layer calculation method. The experiment is performed in a test room to measure the heat gain due to solar radiation passing through the glass window with a curved venetian blind installed in the shortwave part of radiation. The predicted results from the developed model are compared with the experimental results. The agreement between the predicted results and the experimental results is good. From the study it is found that installing a curved venetian blind to the glass window causes a significant reduction in heat gain compared to the plain glass window. The heat gain through the glass window with blind in the shortwave part of radiation (solar heat gain coefficient in the shortwave part of radiation (ShW SHGC)) is analyzed. It is found that the ShW SHGC is mainly affected by the slat properties, slat angle and solar profile angle. The glass window using blind with a lower value of slat reflectance, will have a smaller value of ShW SHGC. The slat distance also affects the ShW SHGC. The glass window using blind with a lower value of slat distance has a lower value of ShW SHGC. The effect of the slat curvature on the ShW SHGC is small when compared to the effect of other parameters. The effects of the investigated parameters on the ShW SHGC for diffuse radiation are similar to the effects on the ShW SHGC for direct radiation. When installing blind to different kinds of glass window other than clear glass window, it is found that the thermal performance is similar to the case of clear glass window. The magnitude of the ShW SHGC for the glass window with blind is also dependent on the optical properties of the glass window used. The glass window with blind using a lower value of the glass transmittance has a lower value of the ShW SHGC. The absorptance of the glass window has direct effect on the solar heat gain coefficient in the longwave part of radiation (LoW SHGC).

Somsak Chaiyapinunt; Nopparat Khamporn

2013-01-01T23:59:59.000Z

65

A warm heart in a cold body - melter technology for tomorrow  

SciTech Connect

As part of its research and development program on waste conditioning, the CEA has developed a cold crucible induction melting technique suitable for a variety of materials: metals, molten salts or oxides including amorphous glass or vitrocrystalline. The technique can be used, for example, to produce containment glass at high temperatures without contamination of the feed material and without corrosion of the crucible itself. The material is heated to the core, but encased in a solidified shell of the same material that forms in contact with the water-cooled melter walls - a very warm {open_quotes}heart{close_quotes} in a cold {open_quotes}body{close_quotes}. This development opens the way to new and even more sophisticated containment matrices; new applications are already envisaged in the area of incineration: burning contaminated chlorinated plastic waste or even sulfonate ion exchange resins from thermal power stations is feasible without risk of corrosion by chlorine or sulfur. Waste incineration and containment of the residue may be performed simultaneously in a single reactor.

Jouan, A.; Boen, R. [Rhone Valley Research Center, Bagnols-sur-Ceze (France); Merlin, S.; Roux, P. [Societe Generale pour les Techniques Nouvelles (SGN), Bagnols-sur-Ceze (France)

1996-12-31T23:59:59.000Z

66

Thermal Performance Impacts of Center-of-Glass Deflections in Installed  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Performance Impacts of Center-of-Glass Deflections in Installed Thermal Performance Impacts of Center-of-Glass Deflections in Installed Insulating Glazing Units Title Thermal Performance Impacts of Center-of-Glass Deflections in Installed Insulating Glazing Units Publication Type Journal Article LBNL Report Number LBNL-5800E Year of Publication 2012 Authors Hart, Robert, Howdy Goudey, Dariush K. Arasteh, and Dragan C. Curcija Journal Energy and Buildings Volume 54 Issue November 2012 Pagination 453-460 Date Published 11/2012 Keywords concave, convex, deflection, field test, gap, insulating glass unit, thermal performance, thermal transmittance, u-factor Abstract This study examines the thermal performance impact of center-of-glass (COG) deflections in double- and triple-pane insulating glass units (IGUs) installed at several locations throughout the US. Deflection was measured during summer and winter temperatures; the results show that outdoor temperature variations can be represented a linear change in COG gap width in double- and triple-pane IGUs within the temperature ranges measured. However, the summer-winter temperature-induced deflection is similar in magnitude to the observed spread in COG deflection of similar units at the same temperature, which suggests that factors other than temperature are of equal importance in determining the in-situ deflection of windows. The effect of deflection on thermal performance depends on the IGU's designed gap. Units constructed with smaller-than-optimal gaps often exhibit significant U-factor change due to temperature-induced reduction in gap width. This effect is particularly problematic in high-performance triple glazing where small gap dimension changes can have a large impact on performance.

67

Thermally efficient melting and fuel reforming for glass making  

DOE Patents (OSTI)

An integrated process for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling.

Chen, Michael S. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary S. (Trexlertown, PA); Winchester, David C. (Allentown, PA)

1991-01-01T23:59:59.000Z

68

Road Map for Development of Crystal-Tolerant High Level Waste Glasses  

SciTech Connect

This road map guides the research and development for formulation and processing of crystal-tolerant glasses, identifying near- and long-term activities that need to be completed over the period from 2014 to 2019. The primary objective is to maximize waste loading for Hanford waste glasses without jeopardizing melter operation by crystal accumulation in the melter or melter discharge riser. The potential applicability to the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) is also addressed in this road map.

Matyas, Josef; Vienna, John D.; Peeler, David; Fox, Kevin; Herman, Connie; Kruger, Albert A.

2014-05-31T23:59:59.000Z

69

Development of New Generation of Thermally-Enhanced Fiber Glass Insulation  

SciTech Connect

This report presents experimental and numerical results from thermal performance studies. The purpose of this Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and John s Manville was to design a basic concept of a new generation of thermally-enhanced fiber glass insulation. Different types of Phase Change Materials (PCMs) have been tested as dynamic components in buildings during the last 4 decades. Most historical studies have found that PCMs enhance building energy performance. Some PCM-enhanced building materials, like PCM-gypsum boards or PCM-impregnated concretes have already found their limited applications in different countries. Today, continued improvements in building envelope technologies suggest that throughout Southern and Central U.S. climates, residences may soon be routinely constructed with PCM in order to maximize insulation effectiveness and maintain low heating and cooling loads. The proposed thermally-enhanced fiber glass insulation will maximize this integration by utilizing a highly-efficient building envelope with high-R thermal insulation, active thermal mass and superior air-tightness. Improved thermal resistance will come from modifications in infrared internal characteristics of the fiber glass insulation. Thermal mass effect can be provided by proprietary thermally-active microencapsulated phase change material (PCM). Work carried out at the Oak Ridge National Laboratory (ORNL) on the CRADA is described in this report.

Kosny, Jan [ORNL; Yarbrough, David W [ORNL; Childs, Phillip W [ORNL; Miller, William A [ORNL; Atchley, Jerald Allen [ORNL; Shrestha, Som S [ORNL

2010-03-01T23:59:59.000Z

70

Glass-like thermal conductivity in high efficiency thermoelectric materials  

Energy.gov (U.S. Department of Energy (DOE))

Discusses strategies to design thermoelectric materials with extremely low lattice thermal conductivity through modifications of the phonon band structure and phonon relaxation time.

71

Microsoft PowerPoint - 2-05 PEGG-2 - Melter Tests with High Al HLW - Nov 2010 emb.ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

Melter Melter Testing with High Aluminum HLW Streams Ian L. Pegg, Hao Gan, Wing K. Kot, Keith S. Matlack, and Innocent Joseph * Vitreous State Laboratory The Catholic University of America Washington, DC * EnergySolutions, Inc. DOE EM Waste Processing Technical Exchange 2010 Print Close Melter Testing with High Aluminum HLW Streams 2 LAW Vitrification (90+% of waste mass) HLW Vitrification (90+% of waste activity) Pretreatment (solid/liquid separation, Cs-IX, Al, Cr, leaching) SLUDGE SUPERNATE Maximize Mass Maximize Activity Hanford WTP - Key Process Flows LAW glass disposed on site HLW glass disposed of in National Geologic Repository - TBD * Supernate: Solution of Na, Al, P, K, S, Cl, Cs, Tc, nitrates, hydroxides... * Sludge: Solids high in Fe, Al, Zr, Cr, Bi, Sr, TRU, oxides, hydroxides....

72

Analysis and Research on the Thermal Properties of Energy-efficient Building Glass: A Case Study in PVB Laminated Glass  

E-Print Network (OSTI)

A new kind of PVB-laminated glass is introduced as an energy-efficient building glass. Based on tests and calculations of the shading coefficients of flat glass, LOW-E coated glass and PVB-laminated glass with different thickness, their effects...

Chen, Z.; Meng, Q.

2006-01-01T23:59:59.000Z

73

Final Report - Effects of High Spinel and Chromium Oxide Crystal Contents on Simulated HLW Vitrification in DM100 Melter Tests, VSL-09R1520-1, Rev. 0, dated 6/22/09  

SciTech Connect

The principal objective of the work was to evaluate the effects of spinel and chromium oxide particles on WTP HLW melter operations and potential impacts on melter life. This was accomplished through a combination of crucible-scale tests, settling and rheological tests, and tests on the DM100 melter system. Crucible testing was designed to develop and identify HLW glass compositions with high waste loadings that exhibit formation of crystalline spinel and/or chromium oxide phases up to relatively high crystal contents (i.e., > 1 vol%). Characterization of crystal settling and the effects on melt rheology was performed on the HLW glass formulations. Appropriate candidate HLW glass formulations were selected, based on characterization results, to support subsequent melter tests. In the present work, crucible melts were formulated that exhibit up to about 4.4 vol% crystallization.

Kruger, Albert A.; Matlack, K. S.; Kot, W.; Pegg, I. L.; Chaudhuri, M.; Lutze, W.

2013-11-13T23:59:59.000Z

74

FINAL REPORT INTEGRATED DM1200 MELTER TESTING USING AZ 102 AND C 106/AY-102 HLW SIMULANTS: HLW SIMULANT VERIFICATION VSL-05R5800-1 REV 0 6/27/05  

SciTech Connect

The principal objectives of the DM1200 melter tests were to determine the effects of feed rheology, feed solid content, and bubbler configuration on glass production rate and off-gas system performance while processing the HLW AZ-101 and C-106/AY-102 feed compositions; characterize melter off-gas emissions; characterize the performance of the prototypical off-gas system components, as well as their integrated performance; characterize the feed, glass product, and off-gas effluents; and perform pre- and post test inspections of system components. The specific objectives (including test success criteria) of this testing, along with how each objective was met, are outlined in a table. The data provided in this Final Report address the impacts of HLW melter feed rheology on melter throughput and validation of the simulated HLW melter feeds. The primary purpose of this testing is to further validate/verify the HLW melter simulants that have been used for previous melter testing and to support their continued use in developing melter and off-gas related processing information for the Project. The primary simulant property in question is rheology. Simulants and melter feeds used in all previous melter tests were produced by direct addition of chemicals; these feed tend to be less viscous than rheological the upper-bound feeds made from actual wastes. Data provided here compare melter processing for the melter feed used in all previous DM100 and DM1200 tests (nominal melter feed) with feed adjusted by the feed vendor (NOAH Technologies) to be more viscous, thereby simulating more closely the upperbounding feed produced from actual waste. This report provides results of tests that are described in the Test Plan for this work. The Test Plan is responsive to one of several test objectives covered in the WTP Test Specification for this work; consequently, only part of the scope described in the Test Specification was addressed in this particular Test Plan. For the purpose of comparison, the tests reported here were performed with AZ-102 and C-106/AY-102 HLW simulants and glass compositions that are essentially the same as those used for recent DM1200 tests. One exception was the use of an alternate, higher-waste-loading C-106/AY-102 glass composition that was used in previous DM100 tests to further evaluate the performance of the optimized bubbler configuration.

KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; BRANDYS M; KOT WK; PEGG IL

2011-12-29T23:59:59.000Z

75

Glass science tutorial: Lecture No. 7, Waste glass technology for Hanford  

SciTech Connect

This paper presents the details of the waste glass tutorial session that was held to promote knowledge of waste glass technology and how this can be used at the Hanford Reservation. Topics discussed include: glass properties; statistical approach to glass development; processing properties of nuclear waste glass; glass composition and the effects of composition on durability; model comparisons of free energy of hydration; LLW glass structure; glass crystallization; amorphous phase separation; corrosion of refractories and electrodes in waste glass melters; and glass formulation for maximum waste loading.

Kruger, A.A.

1995-07-01T23:59:59.000Z

76

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility  

SciTech Connect

An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

2011-03-01T23:59:59.000Z

77

Evaluation of the Thermal Performance for a Wire Mesh/Hollow Glass Microsphere Composite Structure as a Conduction Barrier  

E-Print Network (OSTI)

An experimental investigation exploring the use of wire mesh/hollow glass microsphere combination for use as thermal insulation was conducted with the aim to conclude whether or not it represents a superior insulation technology to those...

Mckenna, Sean

2010-01-15T23:59:59.000Z

78

The Behavior and Effects of the Noble Metals in the DWPF Melter System  

SciTech Connect

Governments worldwide have committed to stabilization of high-level nuclear waste (HLW) by vitrification to a durable glass form for permanent disposal. All of these nuclear wastes contain the fission-product noble metals: ruthenium, rhodium, and palladium. SRS wastes also contain natural silver from iodine scrubbers. Closely associated with the noble metals are the fission products selenium and tellurium which are chemical analogs of sulfur and which combine with noble metals to influence their behavior and properties. Experience has shown that these melt insoluble metals and their compounds tend to settle to the floor of Joule-heated ceramic melters. In fact, almost all of the major research and production facilities have experienced some operational problem which can be associated with the presence of dense accumulations of these relatively conductive metals and/or their compounds. In most cases, these deposits have led to a loss of production capability, in some cases, to the point that melter operation could not continue. HLW nuclear waste vitrification facilities in the United States are the Department of Energy`s Defense Waste Processing Facility (DWPF) at the Savannah River Site, the planned Hanford Waste Vitrification Plant (HWVP) at the Hanford Site and the operating West Valley Demonstration Project (WVDP) at West Valley, NY. The Integrated DWPF Melter System (IDMS) is a vitrification test facility at the Savannah River Technology Center (SRTC). It was designed and constructed to provide an engineering-scale representation of the DWPF melter and its associated feed preparation and off-gas treatment systems. An extensive noble metals testing program was begun in 1990. The objectives of this task were to explore the effects of the noble metals on the DWPF melter feed preparation and waste vitrification processes. This report focuses on the vitrification portion of the test program.

Smith, M.E. [Westinghouse Savannah River Company, AIKEN, SC (United States); Bickford, D.F.

1997-11-30T23:59:59.000Z

79

Halide, Chromate, and Phosphate Impacts on LAW Glass for Dynamic Flowsheet 24590-WTP-MCR-PET-09-0037, Rev. 1  

SciTech Connect

Revision 1 of this Model Change Request changed Equation 6 in Attachment Al only. Melter studies have shown that halide, chromium, and phosphates can cause precipitation of solids that can interfer the melting process. Pilot melter data now shows what concentrations LAW glass can tolerate. These limits shall be incorporated into the existing LAW glass algorithm per Attachment Al.

Gimpel, Rodney F.; Kruger, Albert A.

2013-12-16T23:59:59.000Z

80

Glass mixing theory and tracer study results from the SF-10 run  

SciTech Connect

A general, partial differential equation governing glass mixing in the Slurry Fed Ceramic Melter (SFCM) was derived and a solution obtained based upon certain simplifying assumptions. Tracer studies were then conducted in the SFCM during the SF-10 run to test the theory and characterize glass mixing in this melter. Analysis of the tracer data shows that glass mixing in the SFCM can be explained by use of a model of two, well-mixed tanks in series.

Bowman, B.W.; Routt, K.R.

1988-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Understanding plastic deformation in thermal glasses from single-soft-spot dynamics  

E-Print Network (OSTI)

By considering the low-frequency vibrational modes of amorphous solids, Manning and Liu [Phys. Rev. Lett. 107, 108302 (2011)] showed that a population of "soft spots" can be identified that are intimately related to plasticity at zero temperature under quasistatic shear. In this work we track individual soft spots with time in a two-dimensional sheared thermal Lennard Jones glass at temperatures ranging from deep in the glassy regime to above the glass transition temperature. We show that the lifetimes of individual soft spots are correlated with the timescale for structural relaxation. We additionally calculate the number of rearrangements required to destroy soft spots, and show that most soft spots can survive many rearrangements. Finally, we show that soft spots are robust predictors of rearrangements at temperatures well into the super-cooled regime. Altogether, these results pave the way for mesoscopic theories of plasticity of amorphous solids based on dynamical behavior of individual soft spots.

Samuel S. Schoenholz; Andrea J. Liu; Robert A. Riggleman; Joerg Rottler

2014-04-04T23:59:59.000Z

82

Performance test report for the 1000 kg melter  

SciTech Connect

A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the 100 kg melter offgas report on testing performed by GTS Duratek Inc., in Columbia, Maryland. GTS Duratek (one of the seven vendors selected) was chosen to demonstrate Joule heated melter technology under WHC subcontract number MMI-SVV- 384215. The document contains the complete offgas report on the 100 kg melter as prepared by Parsons Engineering Science, Inc. A summary of this report is also contained in the ``GTS Duratek, Phase 1 Hanford Low-Level Waste Melter Tests: Final Report`` (WHC-SD-VI-027).

Eaton, W.C.

1995-11-01T23:59:59.000Z

83

Thermal lens study of thermo-optical properties and concentration quenching of Er3+-doped lead pyrophosphate based glasses  

SciTech Connect

In this work, we have used the thermal lens technique combined with conventional spectroscopy to characterize the thermo-optical properties of Er3+-doped lead pyrophosphate-based glasses. More precisely, we have investigated and quantified experimentally the fluorescence quantum efficiencies of the Er3+ levels, and we describe the role of concentration quenching effects. The fluorescence quantum efficiency of the 4I13/2 level is very high when compared to other phosphate glasses, while that of the green-coupled levels is very small. Other important photonic materials parameters, such as the thermal diffusivity and temperature coefficient of the optical path length change, were obtained and compared with those of other glass systems. The cumulative results obtained here for the Er-doped lead pyrophosphate glass show that this material is a good candidate for photonic applications with a characteristic Er3+ infrared emission around 1550 nm.

Santos, C. C. [Universidade Federal do Ceara, Ceara, Brazil; Rocha, U. [Grupo de Fotnica e Fluidos Complexos, Instituto de Fsica, Brazil; Guedes, Ilde [Universidade Federal do Ceara, Ceara, Brazil; Vermelho, M. V. D. [Instituto de Fisica, Universidade Federal de Alagoas, Brazil; Boatner, Lynn A [ORNL; Jacinto, C. [Instituto de Fisica, Universidade Federal de Alagoas, Brazil

2012-01-01T23:59:59.000Z

84

Thermal processing system concepts and considerations for RWMC buried waste  

SciTech Connect

This report presents a preliminary determination of ex situ thermal processing system concepts and related processing considerations for application to remediation of transuranic (TRU)-contaminated buried wastes (TRUW) at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Beginning with top-level thermal treatment concepts and requirements identified in a previous Preliminary Systems Design Study (SDS), a more detailed consideration of the waste materials thermal processing problem is provided. Anticipated waste stream elements and problem characteristics are identified and considered. Final waste form performance criteria, requirements, and options are examined within the context of providing a high-integrity, low-leachability glass/ceramic, final waste form material. Thermal processing conditions required and capability of key systems components (equipment) to provide these material process conditions are considered. Information from closely related companion study reports on melter technology development needs assessment and INEL Iron-Enriched Basalt (IEB) research are considered. Five potentially practicable thermal process system design configuration concepts are defined and compared. A scenario for thermal processing of a mixed waste and soils stream with essentially no complex presorting and using a series process of incineration and high temperature melting is recommended. Recommendations for applied research and development necessary to further detail and demonstrate the final waste form, required thermal processes, and melter process equipment are provided.

Eddy, T.L.; Kong, P.C.; Raivo, B.D.; Anderson, G.L.

1992-02-01T23:59:59.000Z

85

Modeling of the Effective Elastic and Thermal Properties of Glass-Ceramic Solid Oxide Fuel Cell Seal Materials  

SciTech Connect

In this study, the effective elastic properties and coefficients of thermal expansion (CTE) of a glass-ceramic were predicted using homogenization techniques. Using G18, a glass-ceramic solid oxide fuel cell (SOFC) sealant as an initial reference material, the effectiveness of different homogenization models was investigated for a two-phase glass-ceramic. The elastic properties and CTEs of the G18 amorphous phase are currently unknown. Thus, estimated values were used as an input to the models. The predictive model offers accurate macroscopic values on both the elastic modulus and the CTE of glass-ceramic materials, providing the estimated amorphous values are reasonable. This model can be used in designing glass-ceramic SOFC seal materials for its specific operation conditions.

Milhans, Jacqueline; Ahzi, Said; Garmestani, Hamid; Khaleel, Mohammad A.; Sun, Xin; Koeppel, Brian J.

2009-05-01T23:59:59.000Z

86

INSTALLATION OF BUBBLERS IN THE SAVANNAH RIVER SITED DEFENSE WASTE PROCESSING FACILITY MELTER  

SciTech Connect

Savannah River Remediation (SRR) LLC assumed the liquid waste contract at the Savannah River Site (SRS) in the summer of 2009. The main contractual agreement was to close 22 High Level Waste (HLW) tanks in eight years. To achieve this aggressive commitment, faster waste processing throughout the SRS liquid waste facilities will be required. Part of the approach to achieve faster waste processing is to increase the canister production rate of the Defense Waste Processing Facility (DWPF) from approximately 200 canisters filled with radioactive waste glass per year to 400 canisters per year. To reach this rate for melter throughput, four bubblers were installed in the DWPF Melter in the late summer of 2010. This effort required collaboration between SRR, SRR critical subcontractor EnergySolutions, and Savannah River Nuclear Solutions, including the Savannah River National Laboratory (SRNL). The tasks included design and fabrication of the bubblers and related equipment, testing of the bubblers for various technical issues, the actual installation of the bubblers and related equipment, and the initial successful operation of the bubblers in the DWPF Melter.

Smith, M.; Iverson, D.

2010-12-08T23:59:59.000Z

87

Thermal Performance Impacts of Center-of-Glass Deflections in Installed Insulating Glazing Units  

E-Print Network (OSTI)

6] M. Bernier, Effects of Glass Plate Curvature on the U-Selkowitz, Research Needs: Glass Solar Reflectance and VinylAnalysis of Insulating Glass Units, Journal of Structural

Hart, Robert

2014-01-01T23:59:59.000Z

88

LBNL-5800E Thermal Performance Impacts of Center-of- Glass Deflections in Installed Insulating  

NLE Websites -- All DOE Office Websites (Extended Search)

00E 00E Thermal Performance Impacts of Center-of- Glass Deflections in Installed Insulating Glazing Units R.G. Hart Lawrence Berkeley National Laboratory C.W. Goudey Lawrence Berkeley National Laboratory D.K. Arasteh Lawrence Berkeley National Laboratory D.C. Curcija Lawrence Berkeley National Laboratory Windows and Envelope Materials Group Building Technology and Urban Systems Department Environmental Energy Technologies Division June 2012 To be published in Energy and Buildings DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor The Regents of the University of

89

Defining And Characterizing Sample Representativeness For DWPF Melter Feed Samples  

SciTech Connect

Representative sampling is important throughout the Defense Waste Processing Facility (DWPF) process, and the demonstrated success of the DWPF process to achieve glass product quality over the past two decades is a direct result of the quality of information obtained from the process. The objective of this report was to present sampling methods that the Savannah River Site (SRS) used to qualify waste being dispositioned at the DWPF. The goal was to emphasize the methodology, not a list of outcomes from those studies. This methodology includes proven methods for taking representative samples, the use of controlled analytical methods, and data interpretation and reporting that considers the uncertainty of all error sources. Numerous sampling studies were conducted during the development of the DWPF process and still continue to be performed in order to evaluate options for process improvement. Study designs were based on use of statistical tools applicable to the determination of uncertainties associated with the data needs. Successful designs are apt to be repeated, so this report chose only to include prototypic case studies that typify the characteristics of frequently used designs. Case studies have been presented for studying in-tank homogeneity, evaluating the suitability of sampler systems, determining factors that affect mixing and sampling, comparing the final waste glass product chemical composition and durability to that of the glass pour stream sample and other samples from process vessels, and assessing the uniformity of the chemical composition in the waste glass product. Many of these studies efficiently addressed more than one of these areas of concern associated with demonstrating sample representativeness and provide examples of statistical tools in use for DWPF. The time when many of these designs were implemented was in an age when the sampling ideas of Pierre Gy were not as widespread as they are today. Nonetheless, the engineers and statisticians used carefully thought out designs that systematically and economically provided plans for data collection from the DWPF process. Key shared features of the sampling designs used at DWPF and the Gy sampling methodology were the specification of a standard for sample representativeness, an investigation that produced data from the process to study the sampling function, and a decision framework used to assess whether the specification was met based on the data. Without going into detail with regard to the seven errors identified by Pierre Gy, as excellent summaries are readily available such as Pitard [1989] and Smith [2001], SRS engineers understood, for example, that samplers can be biased (Gy?s extraction error), and developed plans to mitigate those biases. Experiments that compared installed samplers with more representative samples obtained directly from the tank may not have resulted in systematically partitioning sampling errors into the now well-known error categories of Gy, but did provide overall information on the suitability of sampling systems. Most of the designs in this report are related to the DWPF vessels, not the large SRS Tank Farm tanks. Samples from the DWPF Slurry Mix Evaporator (SME), which contains the feed to the DWPF melter, are characterized using standardized analytical methods with known uncertainty. The analytical error is combined with the established error from sampling and processing in DWPF to determine the melter feed composition. This composition is used with the known uncertainty of the models in the Product Composition Control System (PCCS) to ensure that the wasteform that is produced is comfortably within the acceptable processing and product performance region. Having the advantage of many years of processing that meets the waste glass product acceptance criteria, the DWPF process has provided a considerable amount of data about itself in addition to the data from many special studies. Demonstrating representative sampling directly from the large Tank Farm tanks is a difficult, if not unsolvable enterprise due to li

Shine, E. P.; Poirier, M. R.

2013-10-29T23:59:59.000Z

90

West Valley Melter Draft Waste Evaluation Released for Public Comment |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Melter Draft Waste Evaluation Released for Public Melter Draft Waste Evaluation Released for Public Comment West Valley Melter Draft Waste Evaluation Released for Public Comment March 11, 2011 - 12:00pm Addthis Media Contact Bill Taylor (513) 246-0539 william.taylor@emcbc.doe.gov West Valley, New York - The U.S. Department of Energy today released a Draft Waste Incidental to Reprocessing (WIR) Evaluation of a vitrification melter at the West Valley Demonstration Project (WVDP) for review and comment by the public, states and Nuclear Regulatory Commission (NRC). This draft evaluation shows that the melter meets the criteria for "waste incidental to reprocessing" and may be managed and disposed of as low-level radioactive waste (LLW). It is an important step in DOE's efforts to clean up the WVDP and meet its obligations under the WVDP Act of

91

Formulation and Characterization of Waste Glasses with Varying Processing Temperature  

SciTech Connect

This report documents the preliminary results of glass formulation and characterization accomplished within the finished scope of the EM-31 technology development tasks for WP-4 and WP-5, including WP-4.1.2: Glass Formulation for Next Generation Melter, WP-5.1.2.3: Systematic Glass Studies, and WP-5.1.2.4: Glass Formulation for Specific Wastes. This report also presents the suggested studies for eventual restart of these tasks. The initial glass formulation efforts for the cold crucible induction melter (CCIM), operating at {approx}1200 C, with selected HLW (AZ-101) and LAW (AN-105) successfully developed glasses with significant increase of waste loading compared to that is likely to be achieved based on expected reference WTP formulations. Three glasses formulated for AZ-101HLW and one glass for AN-105 LAW were selected for the initial CCIM demonstration melter tests. Melter tests were not performed within the finished scope of the WP-4.1.2 task. Glass formulations for CCIM were expanded to cover additional HLWs that have high potential to successfully demonstrate the unique advantages of the CCIM technologies based on projected composition of Hanford wastes. However, only the preliminary scoping tests were completed with selected wastes within the finished scope. Advanced glass formulations for the reference WTP melter, operating at {approx}1200 C, were initiated with selected specific wastes to determine the estimated maximum waste loading. The incomplete results from these initial formulation efforts are summarized. For systematic glass studies, a test matrix of 32 high-aluminum glasses was completed based on a new method developed in this study.

Kim, Dong-Sang; Schweiger, M. J.; Rodriguez, Carmen P.; Lepry, William C.; Lang, Jesse B.; Crum, Jarrod V.; Vienna, John D.; Johnson, Fabienne; Marra, James C.; Peeler, David K.

2011-10-17T23:59:59.000Z

92

In Situ Monitoring of Crystallinily and Temperature during Rapid Thermal Crystallization of Silicon on Glass  

E-Print Network (OSTI)

on Glass V. Subramanian, F. L Degertekin, P. Dankoski, B. 1. Khuri-Yakub, and K. C. Saraswatt Department crystal displays (AMLCDs). There is substantial interest in the development of a glass-com- patible the incorporation of driver circuitry onto glass display sub- strates,' improving performance at a reduced cost. Low

Khuri-Yakub, Butrus T. "Pierre"

93

Responses to Public Comments on Draft Vitrification Melter Evaluation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Comments on Draft WVDP Vitrification Melter WIR Evaluation Comments on Draft WVDP Vitrification Melter WIR Evaluation 1 To provide greater transparency to the Department of Energy's (DOE) cleanup of nuclear legacy waste, DOE made the "West Valley Demonstration Project Draft Waste Incidental to Reprocessing Evaluation for the Vitrification Melter" (Draft WIR Evaluation) available for public and state review and comment and Nuclear Regulatory Commission (NRC) consultation review. The public comments on the Draft WIR Evaluation were submitted to DOE by one individual and two organizations:  Raymond C. Vaughan, PhD.,  The West Valley Citizen Task Force, and  The Coalition on West Valley Nuclear Wastes.

94

PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS  

SciTech Connect

The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

2011-01-04T23:59:59.000Z

95

Structural and thermal characterization of CaO-MgO-SiO2-P2O5-CaF2 glasses  

SciTech Connect

The paper presents the influence of varying CaO/MgO ratio on the structure and thermal properties of CaO-MgO-SiO2-P2O5-CaF2 glasses. A series of eight glass compositions in the glass forming region of diopside (CaMgSi2O6) - fluorapatite [Ca5(PO4)3F] - wollastonite (CaSiO3) ternary system have been designed and synthesized by varying diopside/wollastonite ratio in glasses. The as prepared melt-quenched glasses have been characterized for their structure by infrared spectroscopy (FTIR) and magic angle spinning (MAS)-nuclear magnetic resonance (NMR) spectroscopy. Silicon is predominantly present as Q2 (Si) species, while phosphorus tends to coordinate in orthophosphate environment in all the investigated glasses. The change in CaO/MgO ratio had an insignificant affect on the structure of glasses. The thermal sintering and crystallization parameters for the studied glasses have been obtained from differential thermal analysis (DTA) while crystalline phase fractions in the sintered glass-ceramics have been analyzed by X-ray diffraction adjoined with Rietveld refinement. Diopside, fluorapatite, wollastonite and pseudowollastonite have crystallized as the main crystalline phases in all the glass-ceramics with their content varying with respect to variation in CaO/MgO ratio in glasses. Scanning electron microscopy (SEM) has been used to shed light on the microstructure of glass-ceramics. The possible implications of structure and sintering behaviour of glasses on their bioactivity have been discussed.

Kansal, Ishu; Goel, Ashutosh; Tulyaganov, Dilshat U.; Rajagopal, Raghu R.; Ferreira, Jose M.

2012-08-01T23:59:59.000Z

96

Model of thermally induced wavefront distortion and birefringence in side-pumped Nd-doped YAG and phosphate glass heat capacity rod lasers  

Science Journals Connector (OSTI)

We develop an analytic model to describe the dynamic average thermal distortion and phase difference between the two principal polarizations in side-pumped Nd:YAG and Nd:glass heat...

Liu, Liang; Wang, Xiaobo; Guo, Shaofeng; Xu, Xiaojun; Lu, Qisheng

2010-01-01T23:59:59.000Z

97

NEXT GENERATION MELTER OPTIONEERING STUDY - INTERIM REPORT  

SciTech Connect

The next generation melter (NOM) development program includes a down selection process to aid in determining the recommended vitrification technology to implement into the WTP at the first melter change-out which is scheduled for 2025. This optioneering study presents a structured value engineering process to establish and assess evaluation criteria that will be incorporated into the down selection process. This process establishes an evaluation framework that will be used progressively throughout the NGM program, and as such this interim report will be updated on a regular basis. The workshop objectives were achieved. In particular: (1) Consensus was reached with stakeholders and technology providers represented at the workshop regarding the need for a decision making process and the application of the D{sub 2}0 process to NGM option evaluation. (2) A framework was established for applying the decision making process to technology development and evaluation between 2010 and 2013. (3) The criteria for the initial evaluation in 2011 were refined and agreed with stakeholders and technology providers. (4) The technology providers have the guidance required to produce data/information to support the next phase of the evaluation process. In some cases it may be necessary to reflect the data/information requirements and overall approach to the evaluation of technology options against specific criteria within updated Statements of Work for 2010-2011. Access to the WTP engineering data has been identified as being very important for option development and evaluation due to the interface issues for the NGM and surrounding plant. WRPS efforts are ongoing to establish precisely data that is required and how to resolve this Issue. It is intended to apply a similarly structured decision making process to the development and evaluation of LAW NGM options.

GRAY MF; CALMUS RB; RAMSEY G; LOMAX J; ALLEN H

2010-10-19T23:59:59.000Z

98

EMPIRICAL MODEL FOR FORMULATION OF CRYSTAL-TOLERANT HLW GLASSES  

SciTech Connect

Historically, high-level waste (HLW) glasses have been formulated with a low liquideus temperature (T{sub L}), or temperature at which the equilibrium fraction of spinel crystals in the melt is below 1 vol % (T{sub 0.01}), nominally below 1050 C. These constraints cannot prevent the accumulation of large spinel crystals in considerably cooler regions ({approx} 850 C) of the glass discharge riser during melter idling and significantly limit the waste loading, which is reflected in a high volume of waste glass, and would result in high capital, production, and disposal costs. A developed empirical model predicts crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass, and thereby provides guidance in formulating crystal-tolerant glasses that would allow high waste loadings by keeping the spinel crystals small and therefore suspended in the glass.

KRUGER AA; MATYAS J; HUCKLEBERRY AR; VIENNA JD; RODRIGUEZ CA

2012-03-07T23:59:59.000Z

99

Thermally driven asymmetric responses of grains versus spin-glass related distributions of blocking temperature in exchange biased Co/IrMn bilayers  

SciTech Connect

Controlling ferromagnetic/antiferromagnetic blocking temperatures in exchange biased based devices appears crucial for applications. The blocking temperature is ascribed to the ability of both antiferromagnetic grains and interfacial spin-glass-like phases to withstand ferromagnetic magnetization reversal. To better understand the respective contributions of grains versus spin-glass, blocking temperature distributions were measured after various thermal treatments for cobalt/iridium-manganese bilayers. The high-temperature contribution linked to antiferromagnetic grains shifts towards lower temperatures above a threshold thermal annealing. In contrast, the occurrence and evolution of training effects for the low-temperature contribution only agree with its inferred interfacial spin-glass-like origin.

Baltz, V. [SPINTEC, UMR 8191 CNRS/INAC-CEA/UJF-Grenoble 1/Grenoble-INP, F-38054 Cedex (France)] [SPINTEC, UMR 8191 CNRS/INAC-CEA/UJF-Grenoble 1/Grenoble-INP, F-38054 Cedex (France)

2013-02-11T23:59:59.000Z

100

FINAL REPORT TESTS ON THE DURAMELTER 1200 HLW PILOT MELTER SYSTEM USING AZ-101 HLW SIMULANTS VSL-02R0100-2 REV 1 2/17/03  

SciTech Connect

This document provides the final report on data and results obtained from a series of nine tests performed on the one-third scale DuraMelter{trademark} 1200 (DM1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part B1 [1]. Both melters have similar melt surface areas (1.2 m{sup 2}) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plans. The nine tests reported here were preceded by an initial series of short-duration tests conducted to support the start-up and commissioning of this system. This report is a followup to the previously issued Preliminary Data Summary Reports. The DM1200 system was deployed for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. These tests include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The primary objective of the present series of tests was to determine the effects of a variety of parameters on the glass production rate in comparison to the RPP-WTP HL W design basis of 400 kg/m{sup 2}/d. Previous testing on the DMIOOO system [1] concluded that achievement of that rate with simulants of projected WTP melter feeds (AZ-101 and C-106/AY-102) was unlikely without the use of bubblers. As part of those tests, the same feed that was used during the cold-commissioning of the West Valley Demonstration Project (WVDP) HLW vitrification system was run on the DM1000 system. The DM1000 tests reproduced the rates that were obtained at the larger WVDP facility, lending confidence to the tests results [1]. Since the inclusion or exclusion of a bubbler has significant design implications, the Project commissioned further tests to address this issue. In an effort to identify factors that might increase the glass production rate for projected WTP melter feeds, a subsequent series of tests was performed on the DM100 system. Several tests variables led to glass production rate increases to values significantly above the 400 kg/m2/d requirement. However, while small-scale melter tests are useful for screening relative effects, they tend to overestimate absolute glass production rates, particularly for un-bubbled tests. Consequently, when scale-up effects were taken into account, it was not clear that any of the variables investigated would conclusively meet the 400 kg/m{sup 2}/d requirement without bubbling. The present series of tests was therefore performed on the DM1200 one-third scale HLW pilot melter system to provide the required basis for a final decision on whether bubblers would be included in the HLW melter. The present tests employed the same AZ-101 waste simulant and glass composition that was used for previous testing for consistency and comparability with the results from the earlier tests.

KRUGER AA; MATLACK KS; KOT WK; BARDAKCI T; GONG W; D'ANGELO NA; SCHATZ TR; PEGG IL

2011-12-29T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

HLW Glass Waste Loadings  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HLW HLW Glass Waste Loadings Ian L. Pegg Vitreous State Laboratory The Catholic University of America Washington, DC Overview Overview  Vitrification - general background  Joule heated ceramic melter (JHCM) technology  Factors affecting waste loadings  Waste loading requirements and projections  WTP DWPF  DWPF  Yucca Mountain License Application requirements on waste loading  Summary Vitrification  Immobilization of waste by conversion into a glass  Internationally accepted treatment for HLW  Why glass?  Amorphous material - able to incorporate a wide spectrum of elements over wide ranges of composition; resistant to radiation damage  Long-term durability - natural analogs Relatively simple process - amenable to nuclearization at large  Relatively simple process - amenable to nuclearization at large scale  There

102

Evaluation of Phase II glass formulations for vitrification of Hanford Site low-level waste  

SciTech Connect

A vendor glass formulation study was carried out at Pacific Northwest Laboratory (PNL), supporting the Phase I and Phase II melter vendor testing activities for Westinghouse Hanford Company. This study is built upon the LLW glass optimization effort that will be described in a separate report. For Phase I vendor melter testing, six glass formulations were developed at PNL and additional were developed by Phase I vendors. All the doses were characterized in terms of viscosity and chemical durability by the 7-day Product Consistency Test. Twelve Phase II glass formulations (see Tables 3.5 and 3.6) were developed to accommodate 2.5 wt% P{sub 2}O{sub 5} and 1.0 wt% S0{sub 3} without significant processing problems. These levels of P{sub 2}O{sub 5} and SO{sub 3} are expected to be the highest possible concentrations from Hanford Site LLW streams at 25 wt% waste loading in glass. The Phase H compositions formulated were 6 to 23 times more durable than the environmental assessment (EA) glass. They melt within the temperature range of 1160{degrees} to 1410{degrees}C to suit different melting technologies. The composition types include boron-free for volatilization sensitive melters; boron-containing glasses for coId-cap melters; Zr-containing, glasses for enhanced Iong-term durability; and Fe-containing glasses for reducing melting temperature and melt volatility while maintaining chemical durability.

Feng, X.; Hrma, P.R.; Schweiger, M.J. [and others

1996-03-01T23:59:59.000Z

103

HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses  

SciTech Connect

In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Maty et al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

2012-04-02T23:59:59.000Z

104

The Measurement of Thermal Diffusivity of Simulated Glass Forming Nuclear Waste Melts  

Science Journals Connector (OSTI)

High-level nuclear waste is generated during reprocessing of nuclear reactor fuels. At present, these wastes are stored at various locations in the United States until a final waste form (i.e., glass, SYNROC, ......

James U. Derby; L. David Pye; M. J. Plodinec

1983-01-01T23:59:59.000Z

105

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: Combined stability in isothermal ageing and thermal cycling with YSZ coated ferritic stainless steels  

SciTech Connect

An alkali-containing silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel cell (SOFC) applications. The glass contains about 17 mole% alkalis (K+Na) and has low glass transition and softening temperatures. It remains vitreous and compliant around 750-800oC after sealing without substantial crystallization, as contrary to conventional glass-ceramic sealants, which experience rapid crystallization after the sealing process. The glassy nature and low characteristic temperatures can reduce residual stresses and result in the potential for crack healing. In a previous study, the glass was found to have good thermal cycle stability and was chemically compatible with YSZ coating during short term testing. In the current study, the compliant glass was further evaluated in a more realistic way in that the sealed glass couples were first isothermally aged for 1000h followed by thermal cycling. High temperature leakage was measured. The chemical compatibility was also investigated with powder mixtures at 700 and 800oC to enhance potential interfacial reaction. In addition, interfacial microstructure was examined with scanning electron microscopy and evaluated with regard to the leakage and chemical compatibility results.

Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

2012-01-01T23:59:59.000Z

106

Glass Ceramic Formulation Data Package  

SciTech Connect

A glass ceramic waste form is being developed for treatment of secondary waste streams generated by aqueous reprocessing of commercial used nuclear fuel (Crum et al. 2012b). The waste stream contains a mixture of transition metals, alkali, alkaline earths, and lanthanides, several of which exceed the solubility limits of a single phase borosilicate glass (Crum et al. 2009; Caurant et al. 2007). A multi-phase glass ceramic waste form allows incorporation of insoluble components of the waste by designed crystallization into durable heat tolerant phases. The glass ceramic formulation and processing targets the formation of the following three stable crystalline phases: (1) powellite (XMoO4) where X can be (Ca, Sr, Ba, and/or Ln), (2) oxyapatite Yx,Z(10-x)Si6O26 where Y is alkaline earth, Z is Ln, and (3) lanthanide borosilicate (Ln5BSi2O13). These three phases incorporate the waste components that are above the solubility limit of a single-phase borosilicate glass. The glass ceramic is designed to be a single phase melt, just like a borosilicate glass, and then crystallize upon slow cooling to form the targeted phases. The slow cooling schedule is based on the centerline cooling profile of a 2 foot diameter canister such as the Hanford High-Level Waste canister. Up to this point, crucible testing has been used for glass ceramic development, with cold crucible induction melter (CCIM) targeted as the ultimate processing technology for the waste form. Idaho National Laboratory (INL) will conduct a scaled CCIM test in FY2012 with a glass ceramic to demonstrate the processing behavior. This Data Package documents the laboratory studies of the glass ceramic composition to support the CCIM test. Pacific Northwest National Laboratory (PNNL) measured melt viscosity, electrical conductivity, and crystallization behavior upon cooling to identify a processing window (temperature range) for melter operation and cooling profiles necessary to crystallize the targeted phases in the waste form.

Crum, Jarrod V.; Rodriguez, Carmen P.; McCloy, John S.; Vienna, John D.; Chung, Chul-Woo

2012-06-17T23:59:59.000Z

107

Numerical investigation of electric heating impacts on solid/liquid glass flow patterns.  

SciTech Connect

A typical glass furnace consists of a combustion space and a melter. Intense heat is generated from the combustion of fuel and air/oxygen in the combustion space. This heat is transferred mainly by radiation to the melter in order to melt sand and cullet (scrap glass) eventually creating glass products. Many furnaces use electric boosters to enhance glass melting and increase productivity. The coupled electric/combustion heat transfer patterns are key to the glass making processes. The understanding of the processes can lead to the improvement of glass quality and furnace efficiency. The effects of electrical boosting on the flow patterns and heat transfer in a glass melter are investigated using a multiphase Computational Fluid Dynamics (CFD) code with addition of an electrical boosting model. The results indicate that the locations and spacing of the electrodes have large impacts on the velocity and temperature distributions in the glass melter. With the same total heat input, the batch shape (which is determined by the overall heat transfer and the batch melting rate) is kept almost the same. This indicates that electric boosting can be used to replace part of heat by combustion. Therefore, temperature is lower in the combustion space and the life of the furnace can be prolonged. The electric booster can also be used to increase productivity without increasing the furnace size.

Chang, S. L.; Zhou, C. Q.; Golchert, B.

2002-07-02T23:59:59.000Z

108

Earth melter with rubble walls and method of use  

DOE Patents (OSTI)

The present invention is an improvement to the earth melter described and claimed in U.S. Pat. No. 5,443,618. The improvement is the use of rubble for retaining walls. More specifically, the retaining walls rest on ground level and extend above ground level piling rubble around a melt zone. A portion of the melter may be below grade wherein sidewalls are formed by the relatively undisturbed native soil or rock, and the rubble may be used as a backfill liner for the below grade sidewalls.

Chapman, Chris C. (Richland, WA)

1998-01-01T23:59:59.000Z

109

INVESTIGATION OF WASTE GLASS POURING PROCESS OVER A KNIFE EDGE  

SciTech Connect

Vitrification is the process of capturing radioactive waste in glass. The Savannah River Site's (SRS) Defense Waste Processing Facility (DWPF) is one of the facilities using the vitrification technology to treat and immobilize radioactive waste. The objective of the project is to investigate the pouring behavior of molten glass over a pour spout knife edge. Experiments are run using simulant glass containing the same chemical formulation as the radioactive sludge glass, but without radioactive contaminants. The purpose of these tests is to obtain actual glass data that, when combined with previous cold data from other fluids, will provide an overall understanding of the physics of liquids flowing over a pour spout and knife edge, A specific objective is to verify computational fluid dynamics (CFD) models with a range of liquid data with particular emphasis on glass so as to provide confidence in use of these CFD models for designing a new improved pour spout for the DWPF melter. The work to be performed at FIU-HCET includes assembling the melting and pouring system that mimics the DWPF melter and determining the key parameters that may influence wicking. Information from the FIU-HCET melter tests will lead to better operating guidelines for the DWPF melter so as to avoid wicking. During FY98, a bench-scale melter complete with pour spout and a knife edge was designed and assembled at FIU-HCET. Initially, the system was tested with glycerine. Subsequently, glass provided by SRS was used for experimentation. Flow visualization tests were performed with the melter in FY98 to investigate the pouring behavior of molten glass over a pour spout model simulating a DWPF pour spout of the original design. Simulant glass containing the same chemical formulation as sludge glass but without radioactive contaminants was used in the tests. All the tasks and milestones mentioned in the PTP for the project were accomplished. The project completed its second year, and this document reports the tasks and milestones that were accomplished during the 1998 fiscal year.

M.A. Ebadian, Ph.D.

1999-01-01T23:59:59.000Z

110

Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification  

SciTech Connect

In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform evolved gas analysis (EGA). Apart from identifying the gases evolved, we performed quantitative analysis relating the weighed sum of intensities of individual gases linearly proportional with the differential themogravimetry. The proportionality coefficients were obtained by three methods based on the stoichiometry, least squares, and calibration. The linearity was shown to be a good first-order approximation, in spite of the complicated overlapping reactions.

Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.; Rodriguez, Carmen P.; Schweiger, Michael J.

2014-04-30T23:59:59.000Z

111

Measurement of Thermal Conductivity of PbTe Nanocrystal Coated Glass Fibers by the 3 Method  

E-Print Network (OSTI)

and high aspect ratio result in a significant thermal radiation effect. We simulate the experiment using such as automobile exhaust pipes, power plant steam pipes, manufacturing industry cooling pipes, and so forth. Our the radiation effect and extract the thermal conductivity at the single fiber level. Our simulation method

Ruan, Xiulin

112

DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION  

SciTech Connect

DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point that the test apparatus had to be disassembled to dislodge the plugs created in the system.

Adamson, D; Bradley Pickenheim, B

2008-11-24T23:59:59.000Z

113

MELTING OF GLASS BATCH: MODEL FOR MULTIPLE OVERLAPPING GAS-EVOLVING REACTIONS  

SciTech Connect

In this study, we present a model for the kinetics of multiple overlapping reactions. Mathematical representation of the kinetics of gas-evolving reactions is crucial for the modeling of the feed-to-glass conversion in a waste-glass melter. The model simulates multiple gas-evolving reactions that occur during heating of a high-alumina high-level waste melter feed. To obtain satisfactory kinetic parameters, we employed Kissinger's method combined with least-squares analysis. The power-law kinetics with variable reaction order sufficed for obtaining excellent agreement with measured thermogravimetric analysis data.

Pokorny, Richard; Pierce, David A.; Hrma, Pavel R.

2012-08-10T23:59:59.000Z

114

GTS Duratek, phase I Hanford low-level waste melter tests: Final report  

SciTech Connect

A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense waste stored in underground tanks at the Hanford Site in southeastern Washington State. Phase 1 of the melter demonstration tests using simulated LLW was completed during fiscal year 1995. This document is the final report on testing performed by GTS Duratek Inc. in Columbia, Maryland. GTS Duratek (one of the seven vendors selected) was chosen to demonstrate Joule heated melter technology under WHC subcontract number MMI-SVV-384215. The report contains description of the tests, observations, test data and some analysis of the data as it pertains to application of this technology for LLW vitrification. The document also contains summaries of the melter offgas reports issued as separate documents for the 100 kg melter (WHC-SD-WM-VI-028) and for the 1000 kg melter (WHC-SD-WM-VI-029).

Eaton, W.C.

1995-10-26T23:59:59.000Z

115

Checkout and start-up of the integrated DWPF (Defense Waste Processing Facility) melter system  

SciTech Connect

The Integrated DWPF Melter System (IDMS) is a one-ninth-scale demonstration of the Defense Waste Processing Facility (DWPF) feed preparation, melter, and off-gas systems. The IDMS will be the first engineering-scale melter system at SRL to process mercury and flowsheet levels of halides and sulfates. This report includes a summary of the IDMS program objectives, system and equipment descriptions, and detailed discussions of the system checkout and start-up. 10 refs., 44 figs., 20 tabs.

Smith, M.E.; Hutson, N.D.; Miller, D.H.; Morrison, J.; Shah, H.; Shuford, J.A.; Glascock, J.; Wurzinger, F.H.; Zamecnik, J.R.

1989-11-11T23:59:59.000Z

116

Toward Understanding the Effect of Nuclear Waste Glass Composition of Sulfur Solubility  

SciTech Connect

The concentration of sulfur in nuclear waste glass melter feed must be maintained below the point where salt accumulates on the melt surface. The allowable concentrations may range from 0.37 to over 2.05 weight percent (of SO3 on a calcined oxide basis) depending on the composition of the melter feed and processing conditions. If the amount of sulfur exceeds the melt tolerance level, a molten salt will accumulate, which may upset melter operations and potentially shorten the useful life of the melter. At the Hanford site, relatively conservative limits have been placed on sulfur loading in melter feed, which in turn significantly increases the amount of glass that will be produced. Crucible-scale sulfur solubility data and scaled melter sulfur tolerance data have been collected on simulated Hanford waste glasses over the last 15 years. These data were compiled and analyzed. A model was developed to predict the solubility of SO3 in glass based on 252 simulated Hanford low-activity waste (LAW) glass compositions. This model represents the data well, accounting for over 85% of the variation in data, and was well validated. The model was also found to accurately predict the tolerance for sulfur in melter feed for 13 scaled melter tests of simulated LAW glasses. The model can be used to help estimate glass volumes and make informed decisions on process options. The model also gives quantitative estimates of component concentration effects on sulfur solubility. The components that most increase sulfur solubility are Li2O > V2O5> CaO ? P2O5 > Na2O ? B2O3 > K2O. The components that most decrease sulfur solubility are Cl > Cr2O3 > Al2O3 > ZrO2 ? SnO2 > Others ? SiO2. The order of component effects is similar to previous literature data, in most cases.

Vienna, John D.; Kim, Dong-Sang; Muller, I. S.; Kruger, Albert A.; Piepel, Gregory F.

2014-02-13T23:59:59.000Z

117

RHEOLOGICAL AND ELEMENTAL ANALYSES OF SIMULANT SB5 SLURRY MIX EVAPORATOR-MELTER FEED TANK SLURRIES  

SciTech Connect

The Defense Waste Processing Facility (DWPF) will complete Sludge Batch 5 (SB5) processing in fiscal year 2010. DWPF has experienced multiple feed stoppages for the SB5 Melter Feed Tank (MFT) due to clogs. Melter throughput is decreased not only due to the feed stoppage, but also because dilution of the feed by addition of prime water (about 60 gallons), which is required to restart the MFT pump. SB5 conditions are different from previous batches in one respect: pH of the Slurry Mix Evaporator (SME) product (9 for SB5 vs. 7 for SB4). Since a higher pH could cause gel formation, due in part to greater leaching from the glass frit into the supernate, SRNL studies were undertaken to check this hypothesis. The clogging issue is addressed by this simulant work, requested via a technical task request from DWPF. The experiments were conducted at Aiken County Technology Laboratory (ACTL) wherein a non-radioactive simulant consisting of SB5 Sludge Receipt and Adjustment Tank (SRAT) product simulant and frit was subjected to a 30 hour SME cycle at two different pH levels, 7.5 and 10; the boiling was completed over a period of six days. Rheology and supernate elemental composition measurements were conducted. The caustic run exhibited foaming once, after 30 minutes of boiling. It was expected that caustic boiling would exhibit a greater leaching rate, which could cause formation of sodium aluminosilicate and would allow gel formation to increase the thickness of the simulant. Xray Diffraction (XRD) measurements of the simulant did not detect crystalline sodium aluminosilicate, a possible gel formation species. Instead, it was observed that caustic conditions, but not necessarily boiling time, induced greater thickness, but lowered the leach rate. Leaching consists of the formation of metal hydroxides from the oxides, formation of boric acid from the boron oxide, and dissolution of SiO{sub 2}, the major frit component. It is likely that the observed precipitation of Mg(OH){sub 2} and Mn(OH){sub 2} caused the increase in yield stress. The low pH run exhibited as much as an order of magnitude greater B and Li (frit components) leachate concentrations in the supernate. At high pH a decrease of B leaching was found and this was attributed to adsorption onto Mg(OH){sub 2}. A second leaching experiment was performed without any sludge to deconvolute the leach rate behavior of Frit 418 from those of the SB5 sludge-Frit 418 system. At high pH, the sludgeless system demonstrated very fast leaching of all the frit components, primarily due to fast dissolution of the main component, silica, by hydroxide anion; various semiconductor studies have established this reactivity. Overall, the frit-water system exhibited greater leaching from a factor two to almost three orders of magnitude (varying by conditions and species). The slower leaching of the sludge system is possibly due to a greater ionic strength or smaller driving force. Another possible reason is a physical effect, coating of the frit particles with sludge; this would increase the mass transfer resistance to leaching. Based on this study, the cause of clogs in the melter feed loop is still unknown. A possible explanation is that the SME product, like the simulant, is too thin and could contribute to a loss of two-phase flow which could cause plugging of a restricted and poorly mixed zone like the melter feed loop. This is feasible since a previous study of a slurry showed an increase in resistance to flow at lower flow rates. Testing with a radioactive SME sample is underway and should help understand this potential mechanism.

Fernandez, A.

2010-02-08T23:59:59.000Z

118

Silica and boron-containing ultraphosphate laser glass with low concentration quenching and improved thermal shock resistance  

DOE Patents (OSTI)

Neodymium-doped phosphate glasses having a refractive index, nd>1.520; an Abbe number, Vd, <60; a density <3.0 g/cm.sup.3, a thermal expansion coefficient, .alpha., .ltoreq.110.times.10.sup.-7 .degree.C..sup.-1 ; a Young's Modulus, E, <70.times.10.sup.3 N/mm.sup.2 ; a Poisson's Ratio, .nu., <0.28; a thermal conductivity, K, >0.5 W/m.multidot.K, a thermal FOM=(1-.nu.).multidot.K/.alpha.E>0.7, consisting essentially of, in mol. %: P.sub.2 O.sub.5 : 40-70% SiO.sub.2 : 0-20% B.sub.2 O.sub.3 : 5-20% Sum SiO.sub.2 +B.sub.2 O.sub.3 : 5-35% Sum Li.sub.2 O+Na.sub.2 O+K.sub.2 O: 5-20% Sum La.sub.2 O.sub.3 +Nd.sub.2 O.sub.3 : 3-10% Sum MgO+CaO+SrO+BaO+ZnO: 0-10% and preferably containing an amount of Nd.sub.2 O.sub.3 effective for laser activity having an emission cross-section, .sigma., >3.5.times.10.sup.-20 cm.sup.2 ; a fluorescence linewidth (.DELTA..lambda..sub.f1)<23.5 nm; a first e-folding time of the Nd.sup.3+ fluorescence at 0.5 wt. % Nd.sub.2 O.sub.3 >375 .mu.sec, and a first e-folding time of the Nd.sup.3+ fluorescence at 10 wt. % >175 .mu.sec at 10 wt. %, have very low self-concentration quenching rates.

Cook, Lee M. (Duryea, PA); Stokowski, Stanley E. (Danville, CA)

1987-04-28T23:59:59.000Z

119

17 - Immobilisation of Radioactive Waste in Glass  

Science Journals Connector (OSTI)

Radionuclide immobilisation mechanisms are examined for vitreous wasteforms. Both borosilicate and phosphate glasses are described in detail, including the ability of cations to enter into the glass network structure. The role of various cations is considered, including boron, intermediates, and modifiers and elements difficult to immobilise. Selection rules for designing nuclear wasteform silicate glasses are outlined. Glass composite materials to immobilise glass-immiscible waste components are discussed. Both one- and two-stage vitrification technologies are described. An overview is given of the development of vitrification technology, including current operational data on radioactive waste vitrification facilities. Calcination processes are considered in detail, including typical properties of waste calcination products. Recent developments in vitrification are given, including descriptions of cold crucible induction-heated melters and in situ vitrification. Limitations caused by radionuclide volatility are examined. Acceptance criteria are given for vitreous wasteforms.

M.I. Ojovan; W.E. Lee

2014-01-01T23:59:59.000Z

120

Cold-cap reactions in vitrification of nuclear waste glass: experiments and modeling  

SciTech Connect

Cold-cap reactions are multiple overlapping reactions that occur in the waste-glass melter during the vitrification process when the melter feed is being converted to molten glass. In this study, we used differential scanning calorimetry (DSC) to investigate cold-cap reactions in a high-alumina high-level waste melter feed. To separate the reaction heat from both sensible heat and experimental instability, we employed the run/rerun method, which enabled us to define the degree of conversion based on the reaction heat and to estimate the heat capacity of the reacting feed. Assuming that the reactions are nearly independent and can be approximated by the nth order kinetics, we obtained the kinetic parameters using the Kissinger method combined with least squares analysis. The resulting mathematical simulation of the cold-cap reactions provides a key element for the development of an advanced cold-cap model.

Chun, Jaehun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pierce, David A. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pokorny, Richard [Inst. of Chemical Technology, Prague (Czech Republic); Hrma, Pavel R. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Pohang Univ. of Science and Techology (Korea, Republic of)

2013-05-10T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

ROAD MAP FOR DEVELOPMENT OF CRYSTAL-TOLERANT HIGH LEVEL WASTE GLASSES  

SciTech Connect

The U.S. Department of Energy (DOE) is building a Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford Site in Washington to remediate 55 million gallons of radioactive waste that is being temporarily stored in 177 underground tanks. Efforts are being made to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product quality requirements. This road map guides the research and development for formulation and processing of crystaltolerant glasses, identifying near- and long-term activities that need to be completed over the period from 2014 to 2019. The primary objective is to maximize waste loading for Hanford waste glasses without jeopardizing melter operation by crystal accumulation in the melter or melter discharge riser. The potential applicability to the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) will also be addressed in this road map. The planned research described in this road map is motivated by the potential for substantial economic benefits (significant reductions in glass volumes) that will be realized if the current constraints (T1% for WTP and TL for DWPF) are approached in an appropriate and technically defensible manner for defense waste and current melter designs. The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal-tolerant high-level waste (HLW) glasses targeting high waste loadings while still meeting process related limits and melter lifetime expectancies. The modeling effort will be an iterative process, where model form and a broader range of conditions, e.g., glass composition and temperature, will evolve as additional data on crystal accumulation are gathered. Model validation steps will be included to guide the development process and ensure the value of the effort (i.e., increased waste loading and waste throughput). A summary of the stages of the road map for developing the crystal-tolerant glass approach, their estimated durations, and deliverables is provided.

Fox, K.; Peeler, D.; Herman, C.

2014-05-15T23:59:59.000Z

122

Demonstration of oxygen-enriched air staging at Owens-Brockway glass containers. Quarterly technical progress report for the period August 1, 1996--October 31, 1996  

SciTech Connect

The objective of the program is to demonstrate the use of a previously developed combustion modification technology to reduce NO, emissions from sideport regenerative container glass melters. This technology, known as oxygen-enriched air staging (OEAS), has been demonstrated, and is now being commercialized for endport container glass furnaces. This report focuses on full furnace parametric and long-term testing.

Rue, D.; Abbasi, H.

1997-03-01T23:59:59.000Z

123

FINAL REPORT MELTER TESTS WITH AZ-101 HLW SIMULANT USING A DURAMELTER 100 VITRIFICATION SYSTEM VSL-01R10N0-1 REV 1 2/25/02  

SciTech Connect

This report provides data, analyses, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic of America (VSL) to determine the processing rates that are achievable with AZ-101 HLW simulants and corresponding melter feeds on a DuraMelter 100 (DM100) vitrification system. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. Tests conducted during Part B1 (VSL-00R2590-2) on the DM1000 vitrification system installed at the Vitreous State Laboratory of The Catholic University of America showed that, without the use of bubblers, glass production rates with AZ-101 and C-106/AY-102 simulants were significantly lower than the Project design basis rate of 0.4 MT/m{sup 2}/d. Conversely, three-fold increases over the design basis rate were demonstrated with the use of bubblers. Furthermore, an un-bubbled control test using a replica of the melter feed used in cold commissioning tests at West Valley reproduced the rates that were observed with that feed on the WVDP production melter. More recent tests conducted on the DM1200 system, which more closely represents the present RPP-WTP design, are in general agreement with these earlier results. Screening tests conducted on the DM10 system have provided good indications of the larger-scale processing rates with bubblers (for both HL W and LAW feeds) but significantly overestimated the DM1000 un-bubbled rate observed for C-106/AY-102 melter feeds. This behavior is believed to be a consequence of the role of heat transfer in rate attainment and the much greater role of wall effects in heat transfer when the melt pool is not agitated. The DM100 melter used for the present tests has a surface area of 0.108 m{sup 2}, which is approximately 5 times larger than that of the DM10 (0.021 m{sup 2}) and approximately 11 times smaller than that of the DM1000 (1.2 m{sup 2}) (the DM1000 has since been replaced by a pilot-scale prototypical HLW melter, designated the DM1200, which has the same surface area as the DM1000). Testing on smaller melters is the most economical method for obtaining data over a wide range of operating conditions (particularly at extremes) and for guiding the more expensive tests that are performed at pilot-scale. Thus, one objective of these tests was to determine whether the DM100 melters are sufficiently large to reproduce the un-bubbled melt rates observed at the DM1000 scale, or to determine the extent of any off-set. DM100-scale tests can then be used to screen feed chemistry variations that may serve to increase the un-bubbled production rates prior to confirmation at pilot scale. Finally, extensive characterization data obtained on simulated HLW melter feeds formed from various glass forming additives indicated that there may be advantages in terms of feed rheology and stability to the replacement of some of the hydroxides by carbonates. A further objective of the present tests was therefore to identify any deleterious processing effects of such a change before adopting the carbonate feed as the baseline. Data from the WVDP melter using acidified (nitrated) feeds, and without bubbling, showed productions rates that are higher than those observed with the alkaline RPP feeds at the VSL. Therefore, the effect of feed acidification on production rate also was investigated. This work was performed under Test Specification, 'TSP-W375-00-00019, Rev 0, 'HLW-DM10 and DM100 Melter Tests' dated November 13, 2000 and the corresponding Test Plan. It should be noted, however, that the RPP-WTP Project directed a series of changes to the Test Plan as the result

KRUGER AA; MATLACK KS; KOT WK; PEGG IL

2011-12-29T23:59:59.000Z

124

Iron Phosphate Glass-Containing Hanford Waste Simulant  

SciTech Connect

Resolution of the nation's high-level tank waste legacy requires the design, construction, and operation of large and technically complex one-of-a-kind processing waste treatment and vitrification facilities. While the ultimate limits for waste loading and melter efficiency have yet to be defined or realized, significant reductions in glass volumes for disposal and mission life may be possible with advancements in melter technologies and/or glass formulations. This test report describes the experimental results from a small-scale test using the research-scale melter (RSM) at Pacific Northwest National Laboratory (PNNL) to demonstrate the viability of iron-phosphate-based glass with a selected waste composition that is high in sulfate (4.37 wt% SO3). The primary objective of the test was to develop data to support a cost-benefit analysis related to the implementation of phosphate-based glasses for Hanford low-activity waste (LAW) and/or other high-level waste streams within the U.S. Department of Energy complex. The testing was performed by PNNL and supported by Idaho National Laboratory, Savannah River National Laboratory, Missouri University of Science and Technology, and Mo-Sci Corporation.

Sevigny, Gary J.; Kimura, Marcia L.; Fischer, Christopher M.; Schweiger, M. J.; Rodriguez, Carmen P.; Kim, Dong-Sang; Riley, Brian J.

2012-01-18T23:59:59.000Z

125

MATRIX 1 RESULTS OF THE FY07 ENHANCED DOE HIGH-LEVEL WASTE MELTER THROUGHPUT STUDIES AT SRNL  

SciTech Connect

High-level waste (HLW) throughput (i.e., the amount of waste processed per unit time) is a function of two critical parameters: waste loading (WL) and melt rate. For the Waste Treatment and Immobilization Plant (WTP) at the Hanford Site and the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS), increasing HLW throughput would significantly reduce the overall mission life cycle costs for the Department of Energy (DOE). It has been proposed that a team of glass formulation and processing experts at the Pacific Northwest National Laboratory (PNNL), Savannah River National Laboratory (SRNL), and Vitreous State Laboratory (VSL) at Catholic University of America develop a systematic approach to increase HLW throughput (by increasing WL with minimal or positive impacts on melt rate). Programmatically, this task is aimed at proof-of-principle testing and the development of tools to improve waste loading and melt rate, which will lead to higher waste throughput. The following four specific tasks have been proposed to meet this programmatic objective: (1) Integration and Oversight, (2) Crystal Accumulation Modeling (led by PNNL)/Higher Waste Loading Glasses (led by SRNL), (3) Melt Rate Evaluation and Modeling, and (4) Melter Scale Demonstrations. The details of these tasks can be found in the associated task plan WSRC-STI-2007-00483. The current study is focused on Task 2 (crystal accumulation modeling and higher waste loading glasses) and involves glass formulation and physical property testing by both PNNL and SRNL (as defined in the PNNL and SRNL test plans). The intent of this report is to document the chemical composition and Product Consistency Test (PCT) results and statistical analysis of PNNL's Test Matrix 1 glasses. Note that this document is only a compilation of the data collected by SRNL for PNNL's glasses in support of this task and no conclusions will be drawn.

Raszewski, F; Tommy Edwards, T; David Peeler, D

2008-09-23T23:59:59.000Z

126

Technical information report: Plasma melter operation, reliability, and maintenance analysis  

SciTech Connect

This document provides a technical report of operability, reliability, and maintenance of a plasma melter for low-level waste vitrification, in support of the Hanford Tank Waste Remediation System (TWRS) Low-Level Waste (LLW) Vitrification Program. A process description is provided that minimizes maintenance and downtime and includes material and energy balances, equipment sizes and arrangement, startup/operation/maintence/shutdown cycle descriptions, and basis for scale-up to a 200 metric ton/day production facility. Operational requirements are provided including utilities, feeds, labor, and maintenance. Equipment reliability estimates and maintenance requirements are provided which includes a list of failure modes, responses, and consequences.

Hendrickson, D.W. [ed.

1995-03-14T23:59:59.000Z

127

Property/composition relationships for Hanford high-level waste glasses melting at 115{degrees}C volume 1: Chapters 1-11  

SciTech Connect

A Composition Variation study (CVS) is being performed within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) project in support of a future high-level nuclear waste vitrification plant at the Hanford site in Washington. From 1989 to 1994, over 120 nonradioactive glasses were melted and properties measured in five statistically-designed experimental phases. Glass composition is represented by the 10 components SiO{sub 2}, B{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O, Li{sub 2}O, CaO, MgO, and Others (all remaining components). The properties measured include viscosity ({eta}), electrical conductivity ({epsilon}), glass transition temperature (T{sub g} ), thermal expansion of solid glass ({alpha}{sub s}) and molten glass ({alpha}{sub m}), crystallinity (quenched and canister centerline cooled glasses), liquidus temperature (T{sub L}), durability based on normalized elemental releases from the Materials Characterization Center-1 28-day dissolution test (MCC-1, r{sub mi}) and the 7-day Product Consistency Test (PCT, r{sub pi}), and solution pHs from MCC-1 and PCT. Amorphous phase separation was also evaluated. Empirical first- and second-order mixture models were fit using the CVS data to relate the various properties to glass composition. Equations for calculating the uncertainty associated with property values predicted by the models were also developed. The models were validated using both internal and external data. Other modeling approaches (e.g., non-bridging oxygen, free energy of hydration, phase-equilibria T{sub L}) were investigated for specific properties. A preliminary Qualified Composition Region was developed to identify glass compositions with high confidence of being processable in a melter and meeting waste form acceptance criteria.

Hrma, P.R.; Piepel, G.F.

1994-12-01T23:59:59.000Z

128

Property/composition relationships for Hanford high-level waste glasses melting at 1150{degrees}C volume 2: Chapters 12-16 and appendices A-K  

SciTech Connect

A Composition Variation Study (CVS) is being performed within the Pacific Northwest Laboratory Vitrification Technology Development (PVTD) project in support of a future high-level nuclear waste vitrification plant at the Hanford site in Washington. From 1989 to 1994, over 120 nonradioactive glasses were melted and properties measured in five statistically-designed experimental phases. Glass composition is represented by the 10 components SiO{sub 2}, B{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O, Li{sub 2}O, CaO, MgO, and Others (all remaining components). The properties measured include viscosity ({eta}), electrical conductivity ({epsilon}), glass transition temperature (T{sub g}), thermal expansion of solid glass ({alpha}{sub s}) and molten glass ({alpha}{sub m}), crystallinity (quenched and canister centerline cooled glasses), liquidus temperature (T{sub L}), durability based on normalized elemental releases from the Materials Characterization Center-1 28-day dissolution test (MCC-1, r{sub mi}) and the 7-day Product Consistency Test (PCT, r{sub pi}), and solution pHs from MCC-1 and PCT. Amorphous phase separation was also evaluated. Empirical first- and second-order mixture models were fit using the CVS data to relate the various properties to glass composition. Equations for calculating the uncertainty associated with property values predicted by the models were also developed. The models were validated using both internal and external data. Other modeling approaches (e.g., non-bridging oxygen, free energy of hydration, phase-equilibria T{sub L}) were investigated for specific properties. A preliminary Qualified Composition Region was developed to identify glass compositions with high confidence of being processable in a melter and meeting waste form acceptance criteria.

Hrma, P.R.; Piepel, G.F.

1994-12-01T23:59:59.000Z

129

Final Report - Enhanced LAW Glass Formulation Testing, VSL-07R1130-1, Rev. 0, dated 10/05/07  

SciTech Connect

The principal objective of this work was to extend the glass formulation methodology developed in the earlier work [2, 5, 6] for Envelope A, B and C waste compositions for development of compliant glass compositions targeting five high sodium-sulfur waste loading regions. This was accomplished through a combination of crucible-scale tests, and tests on the DM10 melter system. The DM10 was used for several previous tests on LAW compositions to determine the maximum feed sulfur concentrations that can be processed without forming secondary sulfate phases on the surface of the melt pool. This melter is the most efficient melter platform for screening glass compositions over a wide range of sulfate concentrations and therefore was selected for the present tests. The tests were conducted to provide information on melter processing characteristics and off-gas data, including sulfur incorporation and partitioning. As described above, the main objective was to identify the limits of waste loading in compliant glass formulations spanning the range of expected Na{sub 2}O and SO{sub 3} concentrations in the LAW glasses.

Kruger, Albert A.; Pegg, I. L.; Matlack, K. S.; Joseph, I.; Muller, I. S.; Gong, W.

2013-11-13T23:59:59.000Z

130

Vectra GSI, Inc. low-level waste melter testing Phase 1 test report  

SciTech Connect

A multiphase program was initiated in 1994 to test commercially available melter technologies for the vitrification of the low-level waste (LLW) stream from defense wastes stored in underground tanks at the Hanford Site in southeastern Washington State. Vectra GSI, Inc. was one of seven vendors selected for Phase 1 of the melter demonstration tests using simulated LLW that were completed during fiscal year 1995. The attached report prepared by Vectra GSI, Inc. describes results of melter testing using slurry feed and dried feeds. Results of feed drying and prereaction tests using a fluid bed calciner and rotary dryer also are described.

Stegen, G.E.; Wilson, C.N.

1996-02-21T23:59:59.000Z

131

Test plan for evaluation of plasma melter technology for vitrification of high-sodium content low-level radioactive liquid wastes  

SciTech Connect

This document provides a test plan for the conduct of plasma arc vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System (TWRS) Low-Level Waste (LLW) Vitrification Program. The vendor providing this test plan and conducting the work detailed within it [one of seven selected for glass melter testing under Purchase Order MMI-SVV-384212] is the Westinghouse Science and Technology Center (WSTC) in Pittsburgh, PA. WSTC authors of the test plan are D. F. McLaughlin, E. J. Lahoda, W. R. Gass, and N. D`Amico. The WSTC Program Manager for this test is D. F. McLaughlin. This test plan is for Phase I activities described in the above Purchase Order. Test conduct includes melting of glass frit with Hanford LLW Double-Shell Slurry Feed waste simulant in a plasma arc fired furnace.

McLaughlin, D.F.; Lahoda, E.J.; Gass, W.R.; D`Amico, N. [ed.

1994-10-20T23:59:59.000Z

132

glass jewelry  

Science Journals Connector (OSTI)

various personal adornments decorated with glass or made of glass, beads, finger rings, pendants, necklaces,...

2009-01-01T23:59:59.000Z

133

Theoretical and Experimental Thermal Performance Analysis of Building Shell Components Containing Blown Fiber Glass Insulation Enhanced with Phase Change Material (PCM)  

SciTech Connect

Different types of Phase Change Materials (PCMs) have been tested as dynamic components in buildings during the last 4 decades. Most historical studies have found that PCMs enhance building energy performance. Some PCM-enhanced building materials, like PCM-gypsum boards or PCM-impregnated concretes have already found their limited applications in different countries. Today, continued improvements in building envelope technologies suggest that throughout Southern and Central US climates, residences may soon be routinely constructed with PCM in order to maximize insulation effectiveness and maintain low heating and cooling loads. The proposed paper presents experimental and numerical results from thermal performance studies. These studies focus on blown fiber glass insulation modified with a novel spray-applied microencapsulated PCM. Experimental results are reported for both laboratory-scale and full-size building elements tested in the field. In order to confirm theoretical predictions, PCM enhanced fiber glass insulation was evaluated in a guarded hot box facility to demonstrate heat flow reductions when one side of a test wall is subjected to a temperature increase. The laboratory work showed reductions in heat flow of 30% due to the presence of approximately 20 wt % PCM in the insulation. Field testing of residential attics insulated with blown fiber glass and PCM was completed in Oak Ridge, Tennessee. Experimental work was followed by detailed whole building EnergyPlus simulations in order to generate energy performance data for different US climates. In addition, a series of numerical simulations and field experiments demonstrated a potential for application of a novel PCM fiber glass insulation as enabling technology to be utilized during the attic thermal renovations.

Miller, William A [ORNL] [ORNL; Kosny, Jan [ORNL] [ORNL; Yarbrough, David W [ORNL] [ORNL; Childs, Phillip W [ORNL] [ORNL; Shrestha, Som S [ORNL] [ORNL; Atchley, Jerald Allen [ORNL] [ORNL; Bianchi, Marcus V [ORNL] [ORNL; Smith, John B [ORNL] [ORNL; Fellinger, Thomas [ORNL] [ORNL; Kossecka, Elizabeth [Institute of Fundamental Technological Research, Polish Academy of Sciences] [Institute of Fundamental Technological Research, Polish Academy of Sciences; Lee, Edwin S [ORNL] [ORNL

2010-01-01T23:59:59.000Z

134

Microsoft PowerPoint - 6- 02 final - Next generation melter deploymet at WTP - Nov10.pptx  

NLE Websites -- All DOE Office Websites (Extended Search)

Ron Calmus, WRPS Ron Calmus, WRPS Ron Calmus, WRPS Terry Sams, WRPS Terry Sams, WRPS Deployment Plan Overview for Next Deployment Plan Overview for Next Generation Melter at WTP Generation Melter at WTP November 17, 2010 November 17, 2010 Print Close Tank Operations Contract 2 Presentation Outline  Introduction and Background  Project Goals and Objectives  Key Programmatic Decisions  New Generation Melters (NGM) Development and Deployment Planning (AJHCM & CCIM)  NGM Development and Deployment Activities and Interfaces  Near-Term NGM Development Costs  Summary - Focus Areas Next Generation Melters 2 Print Close Tank Operations Contract 3 Introduction and Background  National Academy of Sciences (NAS) Recommendations - In 2009 the NAS stated in it's report that:

135

Evaluation of defense-waste glass produced by full-scale vitrification equipment  

SciTech Connect

Three full-scale vitrification processes at the Pacific Northwest Laboratory produced over 67,000 kg of simulated nuclear-waste glass from March 1979 to August 1980. Samples were analyzed to monitor process operation and evaluate the resulting glass product. These processes are: Spray Calciner/In-Can Melter (SC/ICM); Spray Calciner/Calcine-Fed Ceramic Melter (SC/CFCM); and Liquid-Fed Ceramic Melter (LFCM). Waste components in the process feed varied less than +- 10%. The SC/ICM and SC/CFCM which use separate waste and frit feed systems showed larger glass compositional variation than the LFCM, which processed only premixed feed during this period. The SC/ICM and SC/CFCM product contained significant amounts of acmite crystals, while the LFCM product was largely amorphous. In addition, the lower portion of all SC/ICM-filled canisters contained a zone rich in waste components. A product chemical durability as determined by pH4 and soxhlet leach tests varied considerably. Aside from increased durability under pH4 conditions with decreasing waste content, glass composition, microstructure and melting process did not correlate with glass durability. For all samples analyzed, the weight loss under pH4 conditions ranged from 17.7 to 85.2 wt %. Soxhlet conditions produced weight losses from 1.78 to 3.56 wt %.

Lukacs, J.M.; Petkus, L.L.; Mellinger, G.B.

1981-09-01T23:59:59.000Z

136

Three-Dimensional Flow and Thermal Structures in Glass Melting Furnaces. Part II: Effect of Batch and Bubbles.  

E-Print Network (OSTI)

) the wall heat losses, and (v) the thickness of glass melt containing gas bubbles under the batch. The study indicates that the partially submerged batch and heat losses through the refractories have a strong impact by adjusting the fuel firing in the combustion space. The heat flux distribution resulting from combustion

Pilon, Laurent

137

FINAL REPORT START-UP AND COMMISSIONING TESTS ON THE DURAMELTER 1200 HLW PILOT MELTER SYSTEM USING AZ-101 HLW SIMULANTS VSL-01R0100-2 REV 0 1/20/03  

SciTech Connect

This document provides the final report on data and results obtained from commissioning tests performed on the one-third scale DuraMelter{trademark} 1200 (DM 1200) HLW Pilot Melter system that has been installed at VSL with an integrated prototypical off-gas treatment system. That system has replaced the DM1000 system that was used for HLW throughput testing during Part BI [1]. Both melters have similar melt surface areas (1.2 m{sup 2}) but the DM1200 is prototypical of the present RPP-WTP HLW melter design whereas the DM1000 was not. These tests were performed under a corresponding RPP-WTP Test Specification and associated Test Plan. This report is a followup to the previously issued Preliminary Data Summary Report. The DM1200 system will be used for testing and confirmation of basic design, operability, flow sheet, and process control assumptions as well as for support of waste form qualification and permitting. This will include data on processing rates, off-gas treatment system performance, recycle stream compositions, as well as process operability and reliability. Consequently, this system is a key component of the overall HLW vitrification development strategy. The results presented in this report are from the initial series of short-duration tests that were conducted to support the start-up and commissioning of this system prior to conducting the main body of development tests that have been planned for this system. These tests were directed primarily at system 'debugging,' operator training, and procedure refinement. The AZ-101 waste simulant and glass composition that was used for previous testing was selected for these tests.

KRUGER AA; MATLACK KS; KOT WK; BRANDYS M; WILSON CN; SCHATZ TR; GONG W; PEGG IL

2011-12-29T23:59:59.000Z

138

DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES  

SciTech Connect

Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

Jantzen, C.

2010-03-18T23:59:59.000Z

139

Nonequilibrium viscosity of glass  

Science Journals Connector (OSTI)

Since glass is a nonequilibrium material, its properties depend on both composition and thermal history. While most prior studies have focused on equilibrium liquid viscosity, an accurate description of nonequilibrium viscosity is essential for understanding the low temperature dynamics of glass. Departure from equilibrium occurs as a glass-forming system is cooled through the glass transition range. The glass transition involves a continuous breakdown of ergodicity as the system gradually becomes trapped in a subset of the available configurational phase space. At very low temperatures a glass is perfectly nonergodic (or isostructural), and the viscosity is described well by an Arrhenius form. However, the behavior of viscosity during the glass transition range itself is not yet understood. In this paper, we address the problem of glass viscosity using the enthalpy landscape model of Mauro and Loucks [Phys. Rev. B 76, 174202 (2007)] for selenium, an elemental glass former. To study a wide range of thermal histories, we compute nonequilibrium viscosity with cooling rates from 10?12 to 1012?K/s. Based on these detailed landscape calculations, we propose a simplified phenomenological model capturing the essential physics of glass viscosity. The phenomenological model incorporates an ergodicity parameter that accounts for the continuous breakdown of ergodicity at the glass transition. We show a direct relationship between the nonequilibrium viscosity parameters and the fragility of the supercooled liquid. The nonequilibrium viscosity model is validated against experimental measurements of Corning EAGLE XG glass. The measurements are performed using a specially designed beam-bending apparatus capable of accurate nonequilibrium viscosity measurements up to 1016?Pa?s. Using a common set of parameters, the phenomenological model provides an accurate description of EAGLE XG viscosity over the full range of measured temperatures and fictive temperatures.

John C. Mauro; Douglas C. Allan; Marcel Potuzak

2009-09-30T23:59:59.000Z

140

Density of simulated americium/curium melter feed solution  

SciTech Connect

Vitrification will be used to stabilize an americium/curium (Am/Cm) solution presently stored in F-Canyon for eventual transport to Oak Ridge National Laboratory and use in heavy isotope production programs. Prior to vitrification, a series of in-tank oxalate precipitation and nitric/oxalic acid washes will be used to separate these elements and lanthanide fission products from the bulk of the uranium and metal impurities present in the solution. Following nitric acid dissolution and oxalate destruction, the solution will be denitrated and evaporated to a dissolved solids concentration of approximately 100 g/l (on an oxide basis). During the Am/Cm vitrification, an airlift will be used to supply the concentrated feed solution to a constant head tank which drains through a filter and an in-line orifice to the melter. Since the delivery system is sensitive to the physical properties of the feed, a simulated solution was prepared and used to measure the density as a function of temperature between 20 to 70{degrees} C. The measured density decreased linearly at a rate of 0.0007 g/cm3/{degree} C from an average value of 1.2326 g/cm{sup 3} at 20{degrees} C to an average value of 1.1973g/cm{sup 3} at 70{degrees} C.

Rudisill, T.S.

1997-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Glass Production  

E-Print Network (OSTI)

Late Bronze Age glasses. Journal of Archaeological Science781 - 789. Turner, W.E.S. 1954 Studies in ancient glassesand glass making processes. Part I: Crucibles and melting

Shortland, Andrew

2009-01-01T23:59:59.000Z

142

silica glass  

Science Journals Connector (OSTI)

...any amorphous, pale yellow to pale green natural silica glass such as moldavite, Libyan Desert glass, contains nearly 98% silica. RI:...

2009-01-01T23:59:59.000Z

143

Thermal insulations using vacuum panels  

DOE Patents (OSTI)

Thermal insulation vacuum panels are formed of an inner core of compressed low thermal conductivity powders enclosed by a ceramic/glass envelope evaluated to a low pressure.

Glicksman, Leon R. (Lynnfield, MA); Burke, Melissa S. (Pittsburgh, PA)

1991-07-16T23:59:59.000Z

144

The Thermal Environment of the Fiber Glass Dome for the New Solar Telescope at Big Bear Solar Observatory  

E-Print Network (OSTI)

The New Solar Telescope (NST) is a 1.6-meter off-axis Gregory-type telescope with an equatorial mount and an open optical support structure. To mitigate the temperature fluctuations along the exposed optical path, the effects of local/dome-related seeing have to be minimized. To accomplish this, NST will be housed in a 5/8-sphere fiberglass dome that is outfitted with 14 active vents evenly spaced around its perimeter. The 14 vents house louvers that open and close independently of one another to regulate and direct the passage of air through the dome. In January 2006, 16 thermal probes were installed throughout the dome and the temperature distribution was measured. The measurements confirmed the existence of a strong thermal gradient on the order of 5 degree Celsius inside the dome. In December 2006, a second set of temperature measurements were made using different louver configurations. In this study, we present the results of these measurements along with their integration into the thermal control system (ThCS) and the overall telescope control system (TCS).

A. P. Verdoni; C. Denker; J. R. Varsik; S. Shumko; J. Nenow; R. Coulter

2007-08-04T23:59:59.000Z

145

SUPERGLASS. Engineering field tests - Phase 3. Production, market planning, and product evaluation for a high-thermal-performance insulating glass design utilizing HEAT MIRROR transparent insulation. Final report  

SciTech Connect

HEAT MIRROR transparent window insulation consists of a clear polyester film two mils (.002'') thick with a thin, clear low-emissivity (.15) coating deposited on one side by state-of-the-art vacuum deposition processes. This neutral-colored invisible coating reflects long-wave infrared energy (heat). When mounted by being stretched with a 1/2'' air-gap on each side of the film, the resulting unit reduces heat loss by 60% compared to dual insulating glass. Southwall Corporation produces HEAT MIRROR transparent insulation and markets it to manufacturers of sealed insulating glass (I.G.) units and window and building manufacturers who make their own I.G. These companies build and sell the SUPERGLASS sealed glazing units. Units made and installed in buildings by six customers were visited. These units were located in many geographic regions, including the Pacific Northwest, Rocky Mountains, New England, Southeast, and West Coast. As much as could be obtained of their history was recorded, as was their current condition and performance. These units had been in place from two weeks to over a year. All of the units were performing thermally very well, as measured by taking temperature profiles through them and through adjacent conventional I.G. units. Some units had minor visual defects (attributed to I.G. assembly techniques) which are discussed in detail. Overall occupant acceptance was enthusiastically positive. In addition to saving energy, without compromise of optical quality or appearance, the product makes rooms with large glazing areas comfortable to be in in cold weather. All defects observed were present when built; there appears to be no in-field degradation of quality at this time.

Tilford, C L

1982-11-01T23:59:59.000Z

146

Melter feed tank operating map from the FA-10.02 test data  

SciTech Connect

The operability of the Melter Feed Tank (MFT) feed loops has been tested during the DWPF-FA-10.02 test. The ability to feed the melter at three distinct melter feed rates (0.20, 0.45, and 0.90 gpm), two distinct agitator speeds (65 and 130 rpm), varying liquid levels, and varying slurry rheologies was tested. This report correlates the operability of the feed loops with the above mentioned variables. The data are presented in the form of operating maps, Figs. 1 through 4, which are plots of the liquid level versus the wt% total solids (and yield stress) for two agitator speeds. The maps are divided into regions of acceptable feed loop operation and unacceptable feed loop operation. This report does not consider how closely the compositions of the MFT, the melter feed lines, and the Hydragard samples agree. The significant observations in this report are as follows: Both feed loops satisfy the operability criteria down to a liquid level below the upper impeller blade at low speed agitation (65 rpm). Under high speed agitation (130 rpm), feed loop No. 2 operates much more poorly than feed loop No. 1. The uncertainty associated with the wt% total solids of a slurry sample is larger than the current design basis range for total solids. The dilution of slurry due to pump priming is shown graphically in the chronological presentation of wt% total solids.

Spatz, T.L.

1994-08-01T23:59:59.000Z

147

Mathematical Model of Lump Coal Falling in the Freeboard Zone of the COREX Melter Gasifier  

Science Journals Connector (OSTI)

Mathematical Model of Lump Coal Falling in the Freeboard Zone of the COREX Melter Gasifier ... Subrata and Ashok(2) studied the combustion of coal char in the raceway of the moving bed by a two-dimensional mathematical model, considering the gas and solid as continuous medium and the interaction between gas and solid. ...

Xunliang Liu; Gang Pan; Gan Wang; Zhi Wen

2011-11-03T23:59:59.000Z

148

Pressurized heat treatment of glass ceramic  

DOE Patents (OSTI)

A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

Kramer, D.P.

1984-04-19T23:59:59.000Z

149

FINAL REPORT INTEGRATED DM1200 MELTER TESTING OF BUBBLER CONFIGURATIONS USING HLW AZ-101 SIMULANTS VSL-04R4800-4 REV 0 10/5/04  

SciTech Connect

This report documents melter and off-gas performance results obtained on the DM1200 HLW Pilot Melter during processing of AZ-101 HLW simulants. The tests reported herein are a subset of six tests from a larger series of tests described in the Test Plan for the work; results from the other tests have been reported separately. The solids contents of the melter feeds were based on the WTP baseline value for the solids content of the feeds from pretreatment which changed during these tests from 20% to 15% undissolved solids resulting in tests conducted at two feed solids contents. Based on the results of earlier tests with single outlet 'J' bubblers, initial tests were performed with a total bubbling rate of 651 pm. The first set of tests (Tests 1A-1E) addressed the effects of skewing this total air flow rate back and forth between the two installed bubblers in comparison to a fixed equal division of flow between them. The second set of tests (2A-2D) addressed the effects of bubbler depth. Subsequently, as the location, type and number of bubbling outlets were varied, the optimum bubbling rate for each was determined. A third (3A-3C) and fourth (8A-8C) set of tests evaluated the effects of alternative bubbler designs with two gas outlets per bubbler instead of one by placing four bubblers in positions simulating multiple-outlet bubblers. Data from the simulated multiple outlet bubblers were used to design bubblers with two outlets for an additional set of tests (9A-9C). Test 9 was also used to determine the effect of small sugar additions to the feed on ruthenium volatility. Another set of tests (10A-10D) evaluated the effects on production rate of spiking the feed with chloride and sulfate. Variables held constant to the extent possible included melt temperature, plenum temperature, cold cap coverage, the waste simulant composition, and the target glass composition. The feed rate was increased to the point that a constant, essentially complete, cold cap was achieved, which was used as an indicator of a maximized feed rate for each test. The first day of each test was used to build the cold cap and decrease the plenum temperature. The remainder of each test was split into two- to six-day segments, each with a different bubbling rate, bubbler orientation, or feed concentration of chloride and sulfur.

KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; LUTZE W; CALLOW RA; BRANDYS M; KOT WK; PEGG IL

2011-12-29T23:59:59.000Z

150

Characterization of New Glass Coated Foam Glass Insulating Tiles by Standard Tests  

Science Journals Connector (OSTI)

A good thermal insulation of buildings is today more and more...1). Among insulating materials, foam glasses are increasing their importance because of...2). Foam glasses are fiber-free inorganic insulation mater...

Andrea Ventrella; Federico Smeacetto

2012-11-01T23:59:59.000Z

151

Kinetic model for quartz and spinel dissolution during melting of high-level-waste glass batch  

SciTech Connect

The dissolution of quartz particles and the growth and dissolution of crystalline phases during the conversion of batch to glass potentially affects both the glass melting process and product quality. Crystals of spinel exiting the cold cap to molten glass below can be troublesome during the vitrification of iron-containing high-level wastes. To estimate the distribution of quartz and spinel fractions within the cold cap, we used kinetic models that relate fractions of these phases to temperature and heating rate. Fitting the model equations to data showed that the heating rate, apart from affecting quartz and spinel behavior directly, also affects them indirectly via concurrent processes, such as the formation and motion of bubbles. Because of these indirect effects, it was necessary to allow one kinetic parameter (the pre-exponential factor) to vary with the heating rate. The resulting kinetic equations are sufficiently simple for the detailed modeling of batch-to-glass conversion as it occurs in glass melters. The estimated fractions and sizes of quartz and spinel particles as they leave the cold cap, determined in this study, will provide the source terms needed for modeling the behavior of these solid particles within the flow of molten glass in the melter.

Pokorny, Richard; Rice, Jarrett A.; Crum, Jarrod V.; Schweiger, Michael J.; Hrma, Pavel R.

2013-07-24T23:59:59.000Z

152

TTP SR1-6-WT-31, Milestone C.3-2 Annual Report on Clemson/INEEL Melter Work  

SciTech Connect

This work is performed in collaboration with RL37WT31-C and ID77WT31-B. During the first two years of radioactive operation of the DWPF process, several areas for improvement in melter design have been identified. The continuing scope of this task is to address performance limitations and deficiencies identified by the user. SRS will design and test several configurations of the melter pour spout and associated equipment to improve consistency of performance and recommend design improvements.

Bickford, D.F.

1999-10-20T23:59:59.000Z

153

Approach to thermal properties and electronic polarizability from average single bond strength in ZnO---Bi{sub 2}O{sub 3}---B{sub 2}O{sub 3} glasses  

SciTech Connect

The glass transition temperature (T{sub g}), density, refractive index, Raman scattering spectra, and X-ray photoelectron spectra (XPS) for xZnO-yBi{sub 2}O{sub 3}-zB{sub 2}O{sub 3} glasses (x=10-65, y=10-50, z=25-60 mol%) are measured to clarify the bonding and structure features of the glasses with large amounts of ZnO. The average electronic polarizability of oxide ions ({alpha}{sub O2-}) and optical basicity ({Lambda}) of the glasses estimated using Lorentz-Lorenz equation increase with increasing ZnO or Bi{sub 2}O{sub 3} content, giving the values of {alpha}{sub O2-}=1.963 A{sup 3} and {Lambda}=0.819 for 60ZnO-10Bi{sub 2}O{sub 3}-30B{sub 2}O{sub 3} glass. The formation of B---O---Bi and B---O---Zn bridging bonds in the glass structure is suggested from Raman and XPS spectra. The average single bond strength (B{sub M---O}) proposed by Dimitrov and Komatsu is applied to the glasses and is calculated using single bond strengths of 150.6 kJ/mol for Zn---O bonds in ZnO{sub 4} groups, 102.5 kJ/mol for Bi---O bonds in BiO{sub 6} groups, 498 kJ/mol for B---O bonds in BO{sub 3} groups, and 373 kJ/mol for B---O bonds in BO{sub 4} groups. Good correlations are observed between T{sub g} and B{sub M---O}, {Lambda} and B{sub M---O}, and T{sub g} and {Lambda}, proposing that the average single bond strength is a good parameter for understanding thermal and optical properties of ZnO---Bi{sub 2}O{sub 3}---B{sub 2}O{sub 3} glasses. -- Graphical abstract: This figure shows the correlation between optical basicity {Lambda} and average single bond strength B{sub M---O} in ZnO---Bi{sub 2}O{sub 3}---B{sub 2}O{sub 3} glasses. A good correlation is observed, proposing that the average single bond strength is a good parameter for understanding optical properties of ZnO---Bi{sub 2}O{sub 3}---B{sub 2}O{sub 3} glasses. Display Omitted

Inoue, Taisuke; Honma, Tsuyoshi [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan); Dimitrov, Vesselin [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.j [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2010-12-15T23:59:59.000Z

154

Melting Hanford LAW into Iron-Phosphate Glass in a CCIM  

SciTech Connect

A vitrification test has been conducted using the cold crucible induction melter (CCIM) test system at the Idaho National Laboratory. The test was conducted to demonstrate the vitrification of a Hanford low activity waste (LAW) that contains relatively large amounts of sulfate and sodium, compared to other radioactive Hanford waste streams. The high sulfate content limits the potential loading of this waste stream in conventional borosilicate glass, so this test demonstrated how this waste stream could be vitrified in an iron-phosphate glass that can tolerate higher levels of sulfate.

Nick Soelberg; Sharna Rossberg

2011-09-01T23:59:59.000Z

155

Letter report: Minor component study for low-level radioactive waste glasses  

SciTech Connect

During the waste vitrification process, troublesome minor components in low-level radioactive waste streams could adversely affect either waste vitrification rate or melter life-time. Knowing the solubility limits for these minor components is important to determine pretreatment options for waste streams and glass formulation to prevent or to minimize these problems during the waste vitrification. A joint study between Pacific Northwest Laboratory and Rensselaer Polytechnic Institute has been conducted to determine minor component impacts in low-level nuclear waste glass.

Li, H.

1996-03-01T23:59:59.000Z

156

Glass balls  

E-Print Network (OSTI)

There is a building with 100 floors in it, and glass balls, and an integer k with the following property. If one drops a glass ball from the floor number k or higher,...

157

Use of Optical and Imaging Techniques for Inspection of Off-Line Joule-Heated Melter at the West Valley Demonstration Project  

SciTech Connect

The West Valley melter has been taken out of service. Its design is the direct ancestor of the current melter design for the Hanford Waste Treatment Plant. Over its eight years of service, the West Valley melter has endured many of the same challenges that the Hanford melter will encounter with feeds that are similar to many of the Hanford double shell tank wastes. Thus, inspection of the West Valley melter prior to its disposal could provide valuable--even crucial--information to the designers of the melters to be used at the Hanford Site, particularly if quantitative information can be obtained. The objective of Mississippi State University's Diagnostic Instrumentation and Analysis Laboratory's (DIAL) efforts is to develop, fabricate, and deploy inspection tools for the West Valley melter that will (i) be remotely operable in the West Valley process cell; (ii) provide quantitative information on melter refractory wear and deposits on the refractory; and (iii) indicate areas of heterogeneity (e.g., deposits) requiring more detailed characterization. A collaborative arrangement has been established with the West Valley Demonstration Project (WVDP) to inspect their melter.

Plodinec, M. J.; Jang, P-R; Long, Z.; Monts, D. L.; Philip, T.; Su, Y.

2003-02-25T23:59:59.000Z

158

Venetian glass  

Science Journals Connector (OSTI)

...a term used for imitation pearl made of hollow, iridescent glass, which is filled with wax to increase...

2009-01-01T23:59:59.000Z

159

Activity Report for Hanford WTP LAW Melter HA Development, July 31 - August 5, 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

HSS Independent Activity Report HSS Independent Activity Report Report Number: HIAR-WTP-2013-07-31 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Operational Awareness of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Dates of Activity : 07/31/13 - 08/05/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS) staff observed a limited portion of the hazards analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) system. The primary purpose of this HSS field activity, conducted from July 31 to August 5, 2013, was to observe and

160

Activity Report for Hanford WTP LAW Melter HA Development, July 31 - August 5, 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HSS Independent Activity Report HSS Independent Activity Report Report Number: HIAR-WTP-2013-07-31 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Operational Awareness of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Dates of Activity : 07/31/13 - 08/05/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS) staff observed a limited portion of the hazards analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) system. The primary purpose of this HSS field activity, conducted from July 31 to August 5, 2013, was to observe and

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Research and development of new ultraphosphate laser glasses  

SciTech Connect

Requirements for Zeus laser glass and HAP laser glass were small {sigma}, low water, low concentration quenching and high mechanical and thermal strength in the former and high {sigma}, low water, low concentration quenching and high mechanical, thermal shock resistance in the later. In order to get a high mechanical and thermal shock resistance, we introduced SiO{sub 2} into phosphate glass, because SiO{sub 2} gives a low expansion coefficient. In this report, we discuss the research and development of the laser glass. Chemical durability, water content, lasing properties, mechanical and thermo-mechanical properties, glass composition and glass structures are discussed.

Izumitani, T.; Toratani, H.; Matsukawa, T.; Kanamori, C.; Miyade, H.

1985-01-30T23:59:59.000Z

162

Properties of crystalline phase in waste glass  

SciTech Connect

Depending on the operating conditions of the vitrification process of high-level liquid waste, some crystalline phases can be present. The crystalline phase exists as molten salt at glass melting temperature. In this study, the chemical and physical properties of the crystalline phase were determined. Two samples rich in Mo and a sample rich in Re were examined. One of the samples rich in Mo was obtained from simulated waste solution and glass beads in a middle scale melter, while two other samples were made from mixed reagents. The chemical forms of the constituents were determined by XRD and SEM-EDX. When Mo is dominant, the crystal is mainly composed of molybdates of Na, Li, Ba and Ca, Na{sub 2}SO{sub 4} and CsReO{sub 4}. When Re is dominant, (Na{sub x}Cs{sub 1-x})ReO{sub 4} and NaLiMoO{sub 4} are added. The characteristic temperature and the heat of transition were determined by differential scanning calorimetry. The density of the molten salt at high temperature was measured from buoyancy. The density of the molten salt is larger than that of molten glass, and increases with Re content. (authors)

Usami, T.; Uruga, K.; Tsukada, T. [Central Research Institute of Electric Power Industry, Komae-shi, Tokyo 201-8511 (Japan); Miura, Y.; Komamine, S.; Ochi, E. [Japan Nuclear Fuel Limited, Rokkasho-mura, Aomori 039-3212 (Japan)

2013-07-01T23:59:59.000Z

163

SUMMARY OF FY11 SULFATE RETENTION STUDIES FOR DEFENSE WASTE PROCESSING FACILITY GLASS  

SciTech Connect

This report describes the results of studies related to the incorporation of sulfate in high level waste (HLW) borosilicate glass produced at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). A group of simulated HLW glasses produced for earlier sulfate retention studies was selected for full chemical composition measurements to determine whether there is any clear link between composition and sulfate retention over the compositional region evaluated. In addition, the viscosity of several glasses was measured to support future efforts in modeling sulfate solubility as a function of predicted viscosity. The intent of these studies was to develop a better understanding of sulfate retention in borosilicate HLW glass to allow for higher loadings of sulfate containing waste. Based on the results of these and other studies, the ability to improve sulfate solubility in DWPF borosilicate glasses lies in reducing the connectivity of the glass network structure. This can be achieved, as an example, by increasing the concentration of alkali species in the glass. However, this must be balanced with other effects of reduced network connectivity, such as reduced viscosity, potentially lower chemical durability, and in the case of higher sodium and aluminum concentrations, the propensity for nepheline crystallization. Future DWPF processing is likely to target higher waste loadings and higher sludge sodium concentrations, meaning that alkali concentrations in the glass will already be relatively high. It is therefore unlikely that there will be the ability to target significantly higher total alkali concentrations in the glass solely to support increased sulfate solubility without the increased alkali concentration causing failure of other Product Composition Control System (PCCS) constraints, such as low viscosity and durability. No individual components were found to provide a significant improvement in sulfate retention (i.e., an increase of the magnitude necessary to have a dramatic impact on blending, washing, or waste loading strategies for DWPF) for the glasses studied here. In general, the concentrations of those species that significantly improve sulfate solubility in a borosilicate glass must be added in relatively large concentrations (e.g., 13 to 38 wt % or more of the frit) in order to have a substantial impact. For DWPF, these concentrations would constitute too large of a portion of the frit to be practical. Therefore, it is unlikely that specific additives may be introduced into the DWPF glass via the frit to significantly improve sulfate solubility. The results presented here continue to show that sulfate solubility or retention is a function of individual glass compositions, rather than a property of a broad glass composition region. It would therefore be inappropriate to set a single sulfate concentration limit for a range of DWPF glass compositions. Sulfate concentration limits should continue to be identified and implemented for each sludge batch. The current PCCS limit is 0.4 wt % SO{sub 4}{sup 2-} in glass, although frit development efforts have led to an increased limit of 0.6 wt % for recent sludge batches. Slightly higher limits (perhaps 0.7-0.8 wt %) may be possible for future sludge batches. An opportunity for allowing a higher sulfate concentration limit at DWPF may lay lie in improving the laboratory experiments used to set this limit. That is, there are several differences between the crucible-scale testing currently used to define a limit for DWPF operation and the actual conditions within the DWPF melter. In particular, no allowance is currently made for sulfur partitioning (volatility versus retention) during melter processing as the sulfate limit is set for a specific sludge batch. A better understanding of the partitioning of sulfur in a bubbled melter operating with a cold cap as well as the impacts of sulfur on the off-gas system may allow a higher sulfate concentration limit to be established for the melter feed. This approach would have to be taken carefully to ensure that a

Fox, K.; Edwards, T.

2012-05-08T23:59:59.000Z

164

Glass optimization for vitrification of Hanford Site low-level tank waste  

SciTech Connect

The radioactive defense wastes stored in 177 underground single-shell tanks (SST) and double-shell tanks (DST) at the Hanford Site will be separated into low-level and high-level fractions. One technology activity underway at PNNL is the development of glass formulations for the immobilization of the low-level tank wastes. A glass formulation strategy has been developed that describes development approaches to optimize glass compositions prior to the projected LLW vitrification facility start-up in 2005. Implementation of this strategy requires testing of glass formulations spanning a number of waste loadings, compositions, and additives over the range of expected waste compositions. The resulting glasses will then be characterized and compared to processing and performance specifications yet to be developed. This report documents the glass formulation work conducted at PNL in fiscal years 1994 and 1995 including glass formulation optimization, minor component impacts evaluation, Phase 1 and Phase 2 melter vendor glass development, liquidus temperature and crystallization kinetics determination. This report also summarizes relevant work at PNNL on high-iron glasses for Hanford tank wastes conducted through the Mixed Waste Integrated Program and work at Savannah River Technology Center to optimize glass formulations using a Plackett-Burnam experimental design.

Feng, X.; Hrma, P.R.; Westsik, J.H. Jr. [and others

1996-03-01T23:59:59.000Z

165

Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Observation of Waste Treatment and Immobilization Plant LAW Melter and Melter Off-gas Process System Hazards Analysis _Oct 21-31  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HSS Independent Activity Report - HSS Independent Activity Report - Rev. 0 Report Number: HIAR-WTP-2013-10-21 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Observation of Waste Treatment and Immobilization Plant Low Activity Waste Melter and Melter Off-gas Process System Hazards Analysis Activities Dates of Activity : 10/21/13 - 10/31/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS), Office of Safety and Emergency Management Evaluations (Independent Oversight) reviewed the Insight software hazard evaluation (HE) tables for hazard analysis (HA) generated to date for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter and Off-gas systems, observed a

166

Development of Vitrification Process and Glass Formulation for Nuclear Waste Conditioning  

SciTech Connect

The vitrification of high-level waste is the internationally recognized standard to minimize the impact to the environment resulting from waste disposal as well as to minimize the volume of conditioned waste to be disposed of. COGEMA has been vitrifying high-level waste industrially for over 20 years and is currently operating three commercial vitrification facilities based on a hot metal crucible technology, with outstanding records of safety, reliability and product quality. To further increase the performance of vitrification facilities, CEA and COGEMA have been developing the cold crucible melter technology since the beginning of the 1980s. This type of melter is characterized by a virtually unlimited equipment service life and a great flexibility in dealing with various types of waste and allowing development of high temperature matrices. In complement of and in parallel with the vitrification process, a glass formulation methodology has been developed by the CEA in order to tailor matrices for the wastes to be conditioned while providing the best adaptation to the processing technology. The development of a glass formulation is a trade-off between material properties and qualities, technical feasibility, and disposal safety criteria. It involves non-radioactive and radioactive laboratories in order to achieve a comprehensive matrix qualification. Several glasses and glass ceramics have thus been studied by the CEA to be compliant with industrial needs and waste characteristics: glasses or other matrices for a large spectrum of fission products, or for high contents of specifics elements such as sodium, phosphate, iron, molybdenum, or actinides. New glasses or glass-ceramics designed to minimize the final wasteform volume for solutions produced during the reprocessing of high burnup fuels or to treat legacy wastes are now under development and take benefit from the latest CEA hot-laboratories and technology development. The paper presents the CEA state-of-the-art in developing matrices or glasses and provides several examples.

Petitjean, V.; Fillet, C.; Boen, R.; Veyer, C.; Flament, T.

2002-02-26T23:59:59.000Z

167

Glass Structure  

Science Journals Connector (OSTI)

... Structure and Crystallization of Glasses. By WernerVogel. Pp. 246. (Pergamon: Oxford and New York, October 1971. ... account of the experimental work on liquid-liquid separation and nucleation and crystal growth in glasses carried out by the author and his colleagues in the laboratories of VEB Jena ...

R. W. DOUGLAS

1972-04-07T23:59:59.000Z

168

Optical Glass  

Science Journals Connector (OSTI)

... space of time. In the forefront of such vital industries is the manufacture of optical glass. However great the other resources in men and material may be, it would be ... be, it would be quite impossible to wage successful warfare without adequate supplies of optical glass ior binocular field- ...

1919-03-27T23:59:59.000Z

169

Glass Technology  

Science Journals Connector (OSTI)

... WE have received from the Department of Glass Technology, University of Sheffield, a copy of vol. ii. of Experimental Researches ... that department. The papers included have already appeared in the Journal of the Society of Glass Technology. They range over a somewhat wide field of the ...

1920-08-23T23:59:59.000Z

170

Tempered Glass  

Science Journals Connector (OSTI)

... year (NATURE, vol. xxxi. p. 7). It consists in the production of glass which appears to be of a very homogeneous character and of considerable strength and hardness ... which we propose to refer shortly, is that of keeping the whole body of the glass at a uniform temperature during the operations of heating and coolingthat is to say ...

1885-03-05T23:59:59.000Z

171

ANALYSIS OF DWPF SLUDGE BATCH 6 (MACROBATCH 7) POUR STREAM GLASS SAMPLES  

SciTech Connect

The Defense Waste Processing Facility (DWPF) began processing Sludge Batch 6 (SB6), also referred to as Macrobatch 7 (MB7), in June 2010. SB6 is a blend of the heel of Tank 40 from Sludge Batch 5 (SB5), H-Canyon Np transfers and SB6 that was transferred to Tank 40 from Tank 51.1 SB6 was processed using Frit 418. Sludge is received into the DWPF Chemical Processing Cell (CPC) and is processed through the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator Tank (SME). The treated sludge slurry is then transferred to the Melter Feed Tank (MFT) and fed to the melter. During processing of each sludge batch, the DWPF is required to take at least one glass sample to meet the objectives of the Glass Product Control Program (GPCP) and to complete the necessary Production Records so that the final glass product may be disposed of at a Federal Repository. The DWPF requested various analyses of radioactive glass samples obtained from the melter pour stream during processing of SB6 as well as reduction/oxidation (REDOX) analysis of MFT samples to determine the impact of Argon bubbling. Sample analysis followed the Task Technical and Quality Assurance Plan (TTQAP) and an Analytical Study Plan (ASP). Four Pour Stream (PS) glass samples and two MFT slurry samples were delivered to the Savannah River National Laboratory (SRNL) from the DWPF. Table 1-1 lists the sample information for each pour stream glass sample. SB6 PS3 (S03472) was selected as the official pour stream sample for SB6 and full analysis was requested. This report details the visual observations of the as-received SB6 PS No.3 glass sample as well as results for the chemical composition, Product Consistency Test (PCT), radionuclide content, noble metals, and glass density. REDOX results will be provided for all four pour stream samples and vitrified samples of MFT-558 and MFT-568A. Where appropriate, data from other pour stream samples will be provided.

Johnson, F.

2012-01-20T23:59:59.000Z

172

Refractory Glass Seals for SOFC  

SciTech Connect

One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

Chou, Y. S.; Stevenson, Jeffry W.

2011-07-01T23:59:59.000Z

173

Studies on Mechanical Properties, Thermal Degradation, and Combustion Behaviors of Poly(1,4-butylene terephthalate)/Glass Fiber/Cerium Hypophosphite Composites  

Science Journals Connector (OSTI)

For the GRPBT composite with 15 wt % of CHP, the storage modulus value at 30 C was 3 times that of GRPBT. ... Yang, W.; Hu, Y.; Tai, Q. L.; Lu, H. D.; Song, L.; Yuen, R. K. K.Fire and mechanical performance of nanoclay reinforced glass-fiber/PBT composites containing aluminum hypophosphite particles Composites, Part A 2011, 42, 794 800 ...

Wei Yang; Ningning Hong; Lei Song; Yuan Hu; Richard K. K. Yuen; Xinglong Gong

2012-06-04T23:59:59.000Z

174

ASSESSMENT OF THE IMPACT OF TOA PARTITIONING ON DWPF MELTER OFF-GAS FLAMMABILITY  

SciTech Connect

An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of increasing the amount of TOA in the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process. The results of this study showed that the concentrations of nonvolatile carbon of the current solvent limit (150 ppm) in the Slurry Mix Evaporator (SME) product would be about 7% higher and the nonvolatile hydrogen would be 2% higher than the actual current solvent (126 ppm) with an addition of up to 3 ppm of TOA when the concentration of Isopar? L in the effluent transfer is controlled below 87 ppm and the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle. Therefore, the DWPF melter off-gas flammability assessment is conservative for up to an additional 3 ppm of TOA in the effluent based on these assumptions. This report documents the calculations performed to reach this conclusion.

Daniel, G.

2013-06-18T23:59:59.000Z

175

Optical glass polishing by controlled laser surface-heat treatment  

Science Journals Connector (OSTI)

It is shown that optical surfaces traditionally ground in conventional glasses with high coefficients of thermal expansion may be polished by irradiation with a space- and...

Laguarta, F; Lupon, N; Armengol, J

1994-01-01T23:59:59.000Z

176

The Development of an Innovative Vertical Floatation Melter and Scrap Dryer for Use in the Aluminum Processing Industry  

SciTech Connect

The project aimed at the development of a Vertical Floatation melter, for application to the aluminum industry. This is intended to improve both the energy efficiency and environmental performance of aluminum melting furnaces. Phase I of this project dealt primarily with the initial research effort. Phase II, dealt with pilot-scale testing.

Robert De Saro

2004-08-24T23:59:59.000Z

177

Physical modeling of flow instabilities during pouring of DWPF radioactive glass  

SciTech Connect

The Defense Waste Processing Facility (DWPF) melter at the Savannah River site is well on its way in making this year`s goal of 150 radioactive glass canisters from high-level waste (HLW). However, the initial operation was marked by extreme difficulty in maintaining a stable pouring process. Flow fluctuations have been accompanied by an unusual flow phenomenon, termed wicking. In this situation, the falling glass stream wavered and departed from a normal vertical trajectory similar to the teapot effect. The pour spout and associated hardware connecting it to the canister have been coated and often plugged with glass. This resulted in extended downtime for frequent cleaning. Wicking occurred at both low and high flows, with a stable mid-flow ran. This paper describes the improvement in the pouring process.

Guerrero, H.N. [Westinghouse Savannah River Co., Aiken, SC (United States)

1997-12-01T23:59:59.000Z

178

Incorporation of Fines and Noble Metals into HLW Borosilicate Glass: Industrial Responses to a Challenging Issue - 13056  

SciTech Connect

During the early stages of spent fuel reprocessing, the fuel rods are cut and dissolved to separate the solid metallic parts of the rods (cladding and end pieces) from the radioactive nitric acid solution containing uranium, plutonium, minor actinides and fission products (FP). This solution contains small, solid particles produced during the shearing process. These small particles, known as 'fines', are then separated from the liquid by centrifugation. At the La Hague plant in France, the fines solution is transferred to the vitrification facilities to be incorporated into borosilicate glass along with the highly radioactive FP solution. These fines are also composed of Zr, Mo and other noble metals (i.e. Ru, Pd, Rh, etc.) that are added before vitrification to the the FP solution that already contained noble metals. As noble metals has the potential to modify the glass properties (including viscosity, electrical conductivity, etc.) and to be affected by sedimentation inside the melter, their behavior in borosilicate glass has been studied in depth over the years by the AREVA and CEA teams which are now working together in the Joint Vitrification Laboratory (LCV). At La Hague, the R7 vitrification facility started operation in 1989 using induction-heated metallic melter technology and was quickly followed by the T7 vitrification facility in 1992. Incorporating the fines into glass has been a challenge since operation began, and has given rise to several R and D studies resulting in a number of technological enhancements to improve the mixing capability of the melters (multiple bubbling technology and mechanical stirring in the mid-90's). Nowadays, the incorporation of fines into R7T7 glass is well understood and process adaptations are deployed in the La Hague facilities to increase the operating flexibility of the melters. The paper will briefly describe the fines production mechanisms, give details of the resulting fines characteristics, explain how the metallic particles can influence the glass properties and challenge vitrification technologies and finally, give a rundown of the R and D efforts which have produced innovative solutions contributing to the operational excellence of AREVA's vitrification facilities in the La Hague reprocessing plant. (authors)

Chauvin, E.; Chouard, N.; Prod'homme, A. [AREVA, AREVA NC, Paris (France)] [AREVA, AREVA NC, Paris (France); Boudot, E. [AREVA, AREVA NC, La Hague (France)] [AREVA, AREVA NC, La Hague (France); Gruber, Ph.; Pinet, O. [CEA Marcoule LCV, France (France)] [CEA Marcoule LCV, France (France); Grosman, R. [AREVA, SGN, Paris (France)] [AREVA, SGN, Paris (France)

2013-07-01T23:59:59.000Z

179

Glass | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

industry sectors. Industrial Glass Bandwidth Analysis (2007) Documents for historical reference Energy and Environmental Profile of the Glass Industry (2002) Glass Industry...

180

Through a glass darkly  

E-Print Network (OSTI)

Closeup Through a glass darklyThrough a glass darkly James E. Hall Keywords: AKAP2; AQP0;Medicine Closeup Through a glass darkly GLUT1 Glucose

Hall, James E

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Iron phosphate glass for immobilization of 99Tc  

SciTech Connect

Technetium-99 (99Tc) can bring serious environmental threats because of its long half-life (t1/2 = ~2.1 x 105 years), high fission yield (~6%), and high solubility and mobility in the ground water. The high volatility makes it difficult to immobilize 99Tc in continuous melters vitrifying 99Tc-containing nuclear wastes in borosilicate glasses. This work explores a possibility of incorporating a high concentration of 99Tc, surrogated by the non-radioactive Re, in an iron phosphate glass by melting mixtures of iron phosphate glass frits with 1.5-6 mass% KReO4 at ~1000 C. The retention of Re achieved was ~1.1 mass%. The normalized Re release by the 7-day Product Consistency Test was <10*2 g/m2. Surprisingly, the Re escaped from the melt within a short time of heating, especially when the temperature was increased. Therefore, 99Tc volatilization would still be a challenging task for its immobilization in iron phosphate glasses.

Xu, Kai; Hrma, Pavel R.; Um, Wooyong; Heo, Jong

2013-06-15T23:59:59.000Z

182

Colored optical glass  

Science Journals Connector (OSTI)

The Lytkarino Optical Glass Factory manufactures various types of colored optical glasses: yellow, orange, and red glasses and glasses that are transparent in the IR region, as well as...

Mogilnaya, L G; Zinoveva, O B; Firsova, Yu A; Gulyukin, M N

2013-01-01T23:59:59.000Z

183

TTP SR1-6-WT-31, Milestone C.3-2 annual report on Clemson/INEEL melter work. Revision 1  

SciTech Connect

This work is performed in collaboration with RL37WT31-C and ID77WT31-B. During the first two years of radioactive operation of the DWPF process, several areas for improvement in melter design have been identified. The continuing scope of this task is to address performance limitations and deficiencies identified by the user. SRS will design and test several configurations of the melter pour spout and associated equipment to improve consistency of performance and recommend design improvements.

Bickford, D.F.

1999-12-17T23:59:59.000Z

184

Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability  

SciTech Connect

An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar{reg_sign} L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar{reg_sign} L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isopar{reg_sign} L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion.

Daniel, W. E.

2013-02-13T23:59:59.000Z

185

Analyses of high-level radioactive glasses and sludges at the Savannah River Site  

SciTech Connect

Reliable analyses of high level radioactive glass and sludge are necessary for successful operation of the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS). This facility will convert the radioactive waste sludges at SRS into durable borosilicate glasses for final disposal in a geologic repository. Analyses that are crucial to DWPF operation and repository acceptance of the glass are measurement of the radioactive and nonradioactive composition of the waste sludges and final glasses and measurement of the Fe(II)/Fe(III) ratio in a vitrified sample of melter feed. These measurements are based on the remote dissolutions of the glass and sludge followed by appropriate chemical analyses. Glasses are dissolved by a peroxide fusion method and a method using HF, HNO{sub 3}, H{sub 3}BO{sub 3}, and HCl acids where the solutions are heated in a microwave oven. The resulting solutions are analyzed by inductively coupled plasma-atomic emission spectroscopy (ICP-AES) and atomic absorption spectroscopy (AAS) for nonradioactive elements and appropriate counting techniques for radioactive elements. Results for two radioactive glasses containing actual radioactive waste are also presented. Sludges are dissolved by the Na{sub 2}O{sub 2} fusion method and an aqua regia method. 8 refs., 4 tabs.

Coleman, C.J.; Bibler, N.E.; Dewberry, R.A.

1990-01-01T23:59:59.000Z

186

Earth melter  

SciTech Connect

An apparatus, and method of operating the apparatus, wherein a feed material is converted into a glassified condition for subsequent use or disposal. The apparatus is particularly useful for disposal of hazardous or noxious waste materials which are otherwise either difficult or expensive to dispose of. The apparatus is preferably constructed either by excavating a melt zone in a quantity of soil or rock, or by constructing a melt zone in an apparatus above grade and lining the melt zone with a back fill material if refractory properties are needed. The feed material is fed into the melt zone and, preferably, combusted to an ash, whereupon the heat of combustion is used to melt the ash to a molten condition. Electrodes may be used to maintain the molten feed material in a molten condition, and to maintain homogeneity of the molten materials.

Chapman, Christopher C. (Richland, WA)

1995-01-01T23:59:59.000Z

187

Coated glass in the automotive industry  

Science Journals Connector (OSTI)

Inorganic coatings on glasses have reached the level where they will certainly be applied in the automotive industry in order to solve such glazing problems as heat load, heat loss, glare, UV adsorption, disturbed reflections, electromagnetic influence and thermal insulation. Their widespread use will depend on optimising the solution to problems of solar control and heatable glasses while the glass is also capable of the other functions required of it, thus justifying the relatively high cost that is predicted. There remain unsolved problems in optical limits and colour matching. When these are solved solar control glasses are likely to give real advantages in terms of air conditioning and comfort, and heatable glasses will be used in association with electrical power for demisting and deicing. Particular attention is being directed to a class of infrared reflecting and heatable glasses, obtained by selectively coating transparent plastic films that are embedded or bonded in laminated or tempered glasses. Fabricating this type of glasses has mainly been useful for two reasons: (I) to develop versatile techniques to make solar control IR reflecting and heatable glasses for all kinds and dimensions of vehicle glazing; and (2) to assess whether these glasses are really feasible alternatives to directly coated glasses. This paper describes results of some solar control experiments in Fiat cars: to ascertain the actual internal temperature differences found when glazing vehicles with the absorbing and reflecting IR glasses currently available; and to obtain results with a similar purpose using heatable glasses. There is also discussion of how the glasses could be used in glazing all or parts of a car's windows / especially addressing problems of glare. Suggestions are made of the directions of this research in the future.

G. Manfre

1991-01-01T23:59:59.000Z

188

Followup of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process Systems Hazards Analysis Activity Review, March 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

HSS Independent Activity Report - HSS Independent Activity Report - Rev. 0 Report Number: HIAR-WTP-2013-03-18 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Follow-up of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Review Dates of Activity : 03/18/13 - 03/21/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS) staff observed a limited portion of the restart of the Hazard Analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) System. The primary purpose of this HSS field activity, on March 18-21, 2013, was to observe and understand the revised approach

189

Followup of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process Systems Hazards Analysis Activity Review, March 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HSS Independent Activity Report - HSS Independent Activity Report - Rev. 0 Report Number: HIAR-WTP-2013-03-18 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Follow-up of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Review Dates of Activity : 03/18/13 - 03/21/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS) staff observed a limited portion of the restart of the Hazard Analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) System. The primary purpose of this HSS field activity, on March 18-21, 2013, was to observe and understand the revised approach

190

Continuing the Validation of CCIM Processability for Glass Ceramic HLLW Forms: Plan for Test AFY14CCIM-GC1  

SciTech Connect

This test plan covers test AFY14CCIM-GC1which is the first of two scheduled FY-2014 test runs involving glass ceramic waste forms in the Idaho National Laboratorys Cold Crucible Induction Melter Pilot Plant. The test plan is based on the successes and challenges of previous tests performed in FY-2012 and FY-2013. The purpose of this test is to continue to collect data for validating the glass ceramic High Level Liquid Waste form processability advantages using Cold Crucible Induction Melter technology. The major objective of AFYCCIM-GC1 is to complete additional proposed crucible pouring and post tapping controlled cooling experiments not completed during previous tests due to crucible drain failure. This is necessary to qualify that no heat treatments in standard waste disposal canisters are necessary for the operational scale production of glass ceramic waste forms. Other objectives include the production and post-test analysis of surrogate waste forms made from separate pours into the same graphite mold canister, testing the robustness of an upgraded crucible bottom drain and drain heater assembly, testing the effectiveness of inductive melt initiation using a resistive starter ring with a square wave configuration, and observing the tapped molten flow behavior in pans with areas identical to standard High Level Waste disposal canisters. Testing conditions, the surrogate waste composition, key testing steps, testing parameters, and sampling and analysis requirements are defined.

Vince Maio

2014-04-01T23:59:59.000Z

191

Crystalline Ceramic Waste Forms: Report Detailing Data Collection In Support Of Potential FY13 Pilot Scale Melter Test  

SciTech Connect

The research conducted in this work package is aimed at taking advantage of the long term thermodynamic stability of crystalline ceramics to create more durable waste forms (as compared to high level waste glass) in order to reduce the reliance on engineered and natural barrier systems. Durable ceramic waste forms that incorporate a wide range of radionuclides have the potential to broaden the available disposal options and to lower the storage and disposal costs associated with advanced fuel cycles. Assemblages of several titanate phases have been successfully demonstrated to incorporate radioactive waste elements, and the multiphase nature of these materials allows them to accommodate variation in the waste composition. Recent work has shown that they can be successfully produced from a melting and crystallization process. The objective of this report is to summarize the data collection in support of future melter demonstration testing for crystalline ceramic waste forms. The waste stream used as the basis for the development and testing is a combination of the projected Cs/Sr separated stream, the Trivalent Actinide - Lanthanide Separation by Phosphorous reagent Extraction from Aqueous Komplexes (TALSPEAK) waste stream consisting of lanthanide fission products, the transition metal fission product waste stream resulting from the transuranic extraction (TRUEX) process, and a high molybdenum concentration with relatively low noble metal concentrations. The principal difficulties encountered during processing of the ?reference ceramic? waste form by a melt and crystallization process were the incomplete incorporation of Cs into the hollandite phase and the presence of secondary Cs-Mo non-durable phases. In the single phase hollandite system, these issues were addressed in this study by refining the compositions to include Cr as a transition metal element and the use of Ti/TiO{sub 2} buffer to maintain reducing conditions. Initial viscosity studies of ceramic waste forms indicated that the pour spout must be maintained above 1400{deg}C to avoid flow blockages due to crystallization. In-situ electron irradiations simulate radiolysis effects indicated hollandite undergoes a crystalline to amorphous transition after a radiation dose of 10{sup 13} Gy which corresponds to approximately 1000 years at anticipated doses (2?10{sup 10}-2?10{sup 11} Gy). Dual-beam ion irradiations employing light ion beam (such as 5 MeV alpha) and heavy ion beam (such as 100 keV Kr) studies indicate that reference ceramic waste forms are radiation tolerant to the ??particles and ?-particles, but are susceptible to a crystalline to amorphous transition under recoil nuclei effects. A path forward for refining the processing steps needed to form the targeted phase assemblages is outlined in this report. Processing modifications including melting in a reducing atmosphere with the use of Ti/TiO2 buffers, and the addition of Cr to the transition metal additives to facilitate Cs-incorporation in the hollandite phase. In addition to melt processing, alternative fabrication routes are being considered including Spark Plasma Sintering (SPS) and Hot Isostatic Pressing (HIP).

Brinkman, K. S.; Amoroso, J.; Marra, J. C.; Fox, K. M.

2012-09-21T23:59:59.000Z

192

Crystallization of niobium germanosilicate glasses  

SciTech Connect

Niobium germanosilicate glasses are potential candidates for the fabrication of transparent glass ceramics with interesting non-linear optical properties. A series of glasses in the (Ge,Si)O{sub 2}-Nb{sub 2}O{sub 5}-K{sub 2}O system were prepared by melting and casting and their characteristic temperatures were determined by differential thermal analysis. Progressive replacement of GeO{sub 2} by SiO{sub 2} improved the thermal stability of the glasses. Depending on the composition and the crystallization heat-treatment, different nanocrystalline phases-KNbSi{sub 2}O{sub 7}, K{sub 3}Nb{sub 3}Si{sub 2}O{sub 13} and K{sub 3.8}Nb{sub 5}Ge{sub 3}O{sub 20.4} could be obtained. The identification and characterization of these phases were performed by X-ray diffraction and Raman spectroscopy. The 40 GeO{sub 2}-10 SiO{sub 2}-25 Nb{sub 2}O{sub 5}-25 K{sub 2}O (mol%) composition presented the higher ability for volume crystallization and its nucleation temperature was determined by the Marotta's method. An activation energy for crystal growth of {approx}529 kJ/mol and a nucleation rate of 9.7x10{sup 18} m{sup -3} s{sup -1} was obtained, for this composition. Transparent glass ceramics with a crystalline volume fraction of {approx}57% were obtained after a 2 h heat-treatment at the nucleation temperature, with crystallite sizes of {approx}20 nm as determined by transmission electron microscopy. - Abstract: TEM image and XRD pattern of the glass ceramic produced (circles indicate nanocrystals).

Santos, Rodrigo [Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Tecnico/TU Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisbon (Portugal); Santos, Luis F., E-mail: luis.santos@ist.utl.p [Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Tecnico/TU Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisbon (Portugal); Almeida, Rui M. [Departamento de Engenharia de Materiais/ICEMS, Instituto Superior Tecnico/TU Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisbon (Portugal); Deubener, Joachim [Institute of Non-Metallic Materials, Clausthal University of Technology, Clausthal-Zellerfeld (Germany); Wondraczek, Lothar [Department of Materials Science, Glass and Ceramics, University of Erlangen-Nuremberg, 91058 Erlangen (Germany)

2010-01-15T23:59:59.000Z

193

A World of Glass  

Science Journals Connector (OSTI)

...This clear molten liquid began to transform agriculture and horticulture. The use of glass houses to promote the precocious growth...enclosed coaches, watch-glasses, lighthouses, and street lighting. The sextant required glass, and the precision chronometer...

Alan Macfarlane; Gerry Martin

2004-09-03T23:59:59.000Z

194

A World of Glass  

Science Journals Connector (OSTI)

...transform agriculture and horticulture. The use of glass houses...appeared. Glass cloches and greenhouses improved the cultivation...lighthouses, and street lighting. The sextant required glass...lanterns, lighthouses, and greenhouses, and finally through cameras...

Alan Macfarlane; Gerry Martin

2004-09-03T23:59:59.000Z

195

Plastic Flow in Glass  

Science Journals Connector (OSTI)

...1964 research-article Plastic Flow in Glass D. M. Marsh The classical brittle fracture...account for the mechanical properties of glasses, but the widespread evidence of plastic flow in all glass fracture phenomena even at room temperature...

1964-01-01T23:59:59.000Z

196

Connecting section and associated systems concept for the spray calciner/in-can melter process  

SciTech Connect

For a number of years, researchers at the Pacific Northwest Laboratory have been developing processes and equipment for converting high-level liquid wastes to solid forms. One of these processes is the Spray Calciner/In-Can Melter system. To immobilize high-level liquid wastes, this system must be operated remotely, and the calcine must be reliably conveyed from the calciner to the melting furnace. A concept for such a remote conveyance system was developed at the Pacific Northwest Laboratory, and equipment was tested under full-scale, nonradioactive conditions. This concept and the design of demonstration equipment are described, and the results of equipment operation during experimental runs of 7 d are presented. The design includes a connecting section and its associated systems - a canister sypport and alignment concept and a weight-monitoring system for the melting furnace. Overall, the runs demonstrated that the concept design is an acceptable method of connecting the two pieces of process equipment together. Although the connecting section has not been optimized in all areas of concern, it provides a first-generation design of a production-oriented system.

Petkus, L.L.; Gorton, P.S.; Blair, H.T.

1981-06-01T23:59:59.000Z

197

Glass and glass-ceramics transparent from the visible range to the mid-infrared for night vision  

Science Journals Connector (OSTI)

Many papers report studies on oxyfluorides glass-ceramics combining the optical advantage of fluoride environment for rare earth with the thermal and chemical advantages of oxide glasses [1??7], or on oxide-based glass-ceramics exhibiting exceptional thermo-mechanical properties such as zero thermal expansion coefficient. The transparency of these glass-ceramics is limited in the infrared region up to 4 µm [8??12]. In this paper, we report the last results on totally new infrared transmitting chalcogenide glass-ceramics which are transparent up to 11 µm for sulphur based glass or up to 16 µm for selenium based glass. By selecting appropriate glass composition in several Ge-(Sb/Ga)-(S/Se)-MX (MX: alkali halide) systems, glass-ceramics with different microcrystals volume fraction can be reproducibly obtained by controlling nucleation and crystallisation annealing time and temperatures. It has been demonstrated that crystals smaller than 200 nm induce some additional losses only in the short wavelength region. The glass ceramics keep the same transmission as the original glass from 1 µm up to 11 µm or 16 µm. Sulphur based glass-ceramics are still transparent in the second for glass and selenium based glass-ceramics keep an excellent transmission in the second and third atmospheric window. The obtained glass-ceramics exhibit much better resistance to cracks propagation than the corresponding pure glass matrix. Observations under electronic microscopy as well as X-ray diffraction have been used to determinate crystals size, density and crystalline phase. The possibility of combining the ceramisation process and the shaping by moulding has also been demonstrated.

L. Calvez; H-L. Ma; J. Lucas; X.H. Zhang

2008-01-01T23:59:59.000Z

198

Sedimentation behavior of noble metal particles in simulated high-level waste borosilicate glasses  

SciTech Connect

Solubility of noble metal elements (NME) in the melted borosilicate glass is much smaller than its normal concentration of the high level liquid waste. Thus most of NME show small particles in the melted glass and tend to sediment in the bottom region of the vitrification melter due to their higher density than that of glass. Experiments of the sedimentation of NME particles in the melted glass were carried out under static condition. Three conditions of initial NME concentration (1.1, 3.0, 6.1 wt % with an equivalent for each oxide) in the simulated glass were set and held at 1100 C. degrees up to 2880 hours. The specimen with 1.1 wt % initial NME concentration indicated zone settling, and the settling rate of the interface is constant: 2.4 mm/h. This sedimentation behavior is the type of rapid settling. Following the rapid settling, the settling rate goes gradually slower; this is the type of compressive settling. The specimens with 3.0 wt % and 6.1 wt % initial NME concentration showed compression settling from the beginning. From the settling curve of the interface, the maximum concentration of NME in sediment was estimated to be around 23- 26 wt %. Growth of NME particles was observed by holding at 1100 C. degrees for up to 2880 hours. The viscosity becomes higher as NME concentration increases and the dependence on shear rate becomes simultaneously stronger. The effect of the particle growth to viscosity appears to be not significant.

Nakajima, M.; Ohyama, K.; Morikawa, Y.; Miyauchi, A.; Yamashita, T. [Japan Atomic Energy Agency, 4-33 Muramatsu, Tokai-mura, Naka-gun, Ibaraki 319-1109 (Japan); Komamine, S.; Ochi, E. [Japan Nuclear Fuel Limited, Bussan-Bldg. Bekkan, 1-1-5 Nishi-Shinbashi Minato-ku, Tokyo 105-0003 (Japan)

2013-07-01T23:59:59.000Z

199

NEWS & VIEWS Glass dynamics  

E-Print Network (OSTI)

NEWS & VIEWS Glass dynamics Diverging views on glass transition Gregory B. mc.mckenna@ttu.edu T he glass transition is one of the most intriguing phenomena in the world of soft condensed matter. Despite decades of study, many aspects of the behaviour of glass-forming liquids remain elusive

Weeks, Eric R.

200

NOBLE METAL CHEMISTRY AND HYDROGEN GENERATION DURING SIMULATED DWPF MELTER FEED PREPARATION  

SciTech Connect

Simulations of the Defense Waste Processing Facility (DWPF) Chemical Processing Cell vessels were performed with the primary purpose of producing melter feeds for the beaded frit program plus obtaining samples of simulated slurries containing high concentrations of noble metals for off-site analytical studies for the hydrogen program. Eight pairs of 22-L simulations were performed of the Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) cycles. These sixteen simulations did not contain mercury. Six pairs were trimmed with a single noble metal (Ag, Pd, Rh, or Ru). One pair had all four noble metals, and one pair had no noble metals. One supporting 4-L simulation was completed with Ru and Hg. Several other 4-L supporting tests with mercury have not yet been performed. This report covers the calculations performed on SRNL analytical and process data related to the noble metals and hydrogen generation. It was originally envisioned as a supporting document for the off-site analytical studies. Significant new findings were made, and many previous hypotheses and findings were given additional support as summarized below. The timing of hydrogen generation events was reproduced very well within each of the eight pairs of runs, e.g. the onset of hydrogen, peak in hydrogen, etc. occurred at nearly identical times. Peak generation rates and total SRAT masses of CO{sub 2} and oxides of nitrogen were reproduced well. Comparable measures for hydrogen were reproduced with more variability, but still reasonably well. The extent of the reproducibility of the results validates the conclusions that were drawn from the data.

Koopman, D

2008-06-25T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Corrosion of MA754 and MA956 in a Commercial Aluminum Melter  

SciTech Connect

The University of North Dakota Energy & Environmental Research Center is working with Oak Ridge National Laboratory to test two oxide dispersion-strengthened alloys that could be used to construct very high-temperature heat recuperators for the aluminum-melting industry. For the initial tests, uncooled rings of MA754 and MA956 piping were exposed for 5 months to gases leaving an aluminum melter furnace at 1200 1290 C. The MA956 suffered spotty areas of severe corrosion and lost 25% of its weight. Scanning electron microscopy showed that there were small spots of alkali-rich corrosion products on the alloy surfaces, indicating the impact of droplets of fluxing agents. The corrosion products in these areas were mixed Fe, Cr, and Al oxides, which were depleted in Cr near the gas surface. However, Al concentrations in the remaining metal were typically between 3.5% and 4.0%, so there was a sufficient reservoir of Al remaining in the alloy to prevent simple breakaway corrosion which could have occurred if the Al were significantly depleted. The MA754 lost approximately 15% of its weight and showed void formation within 2 mm of the gas metal surfaces. Within the porous area, the Cr had largely segregated into oxide precipitates up to 50 9m in diameter, leaving the remaining metal Ni-rich. Below the porous layer, the alloy composition was relatively unchanged. Remains of Na- and Al-rich particles that had impacted the surface sporadically were visible but had not obviously affected the surface scale as they had with the MA956.

Hurley, John P. [University of North Dakota Energy & Environmental Research Center] [University of North Dakota Energy & Environmental Research Center; Kelley, Carl [Natures Fuel, 410 East Cook Road, Fort Wayne, IN 46825, USA] [Natures Fuel, 410 East Cook Road, Fort Wayne, IN 46825, USA; Bornstein, Norman S. [Consultant] [Consultant; Wright, Ian G [ORNL] [ORNL

2008-01-01T23:59:59.000Z

202

Glass Cookware Safety  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Cookware Safety Glass Cookware Safety Under the wrong conditions, glass cookware can crack, break or shatter. Glass cookware is tempered (heat resistant). However, there are many steps to follow to ensure safe use of glass cookware. Glass Cookware Steps: If the steps are not followed, glass cookware can shatter unexpectedly. shatters, (it looks as if it has exploded) If glass bakeware is chipped, cracked, or scratched, it's time for it to be retired from service. It is more likely to shatter! Don't take glass bakeware directly from the freezer to the oven, or vice versa. Allow the oven to fully preheat before putting glassware inside. Don't add liquid to glassware that is already hot. Cover the bottom of glass bakeware with liquid before cooking meat or vegetables.

203

ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 industrialbandwidth.pdf More Documents &...

204

Glass and glass-derivative seals for use in energy-efficient fuel cells and lamps  

SciTech Connect

For solid oxide fuel cells (SOFC), a series of 18 sealing glasses have been prepared and characterized. From the whole design space, several glasses were ''downselected'' and studied in detail to describe their behaviors in simulated fuel cell environments. One of the glasses was found to outperform all others, including the well-known G18 sealant developed at Pacific Northwest National Laboratory. The new glass composition showed lower bulk electrical conductivity, excellent sealing and wetting behavior when sealing under applied load, and qualitatively superior performance when exposed to wet hydrogen for 800 hours. Traditional melting was used to prepare all of the glasses that were studied in detail. The sol-gel approach was used to synthesize several compositions, but it was found that the glasses crystallized very rapidly during heating, precluding sealing. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. The body of fundamental data provides a platform for future developments for high temperature sealants, and the newly-developed glass compositions appear promising for large-scale testing. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria-alumina-silica system at various silica levels. Functional testing of one of the candidate sealants demonstrated that it performs well in current HID lighting applications. Further testing is required to evaluate its performance in next-generation lamps that operate at higher temperatures, but the baseline phase equilibria and crystallization behavior has been established for additional development. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase.

Scott Misture; Arun Varshineya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

2005-07-28T23:59:59.000Z

205

Glass Ceramic Waste Forms for Combined CS+LN+TM Fission Products Waste Streams  

SciTech Connect

In this study, glass ceramics were explored as an alternative waste form for glass, the current baseline, to be used for immobilizing alkaline/alkaline earth + lanthanide (CS+LN) or CS+LN+transition metal (TM) fission-product waste streams generated by a uranium extraction (UREX+) aqueous separations type process. Results from past work on a glass waste form for the combined CS+LN waste streams showed that as waste loading increased, large fractions of crystalline phases precipitated upon slow cooling.[1] The crystalline phases had no noticeable impact on the waste form performance by the 7-day product consistency test (PCT). These results point towards the development of a glass ceramic waste form for treating CS+LN or CS+LN+TM combined waste streams. Three main benefits for exploring glass ceramics are: (1) Glass ceramics offer increased solubility of troublesome components in crystalline phases as compared to glass, leading to increased waste loading; (2) The crystalline network formed in the glass ceramic results in higher heat tolerance than glass; and (3) These glass ceramics are designed to be processed by the same melter technology as the current baseline glass waste form. It will only require adding controlled canister cooling for crystallization into a glass ceramic waste form. Highly annealed waste form (essentially crack free) with up to 50X lower surface area than a typical High-Level Waste (HLW) glass canister. Lower surface area translates directly into increased durability. This was the first full year of exploring glass ceramics for the Option 1 and 2 combined waste stream options. This work has shown that dramatic increases in waste loading are achievable by designing a glass ceramic waste form as an alternative to glass. Table S1 shows the upper limits for heat, waste loading (based on solubility), and the decay time needed before treatment can occur for glass and glass ceramic waste forms. The improvements are significant for both combined waste stream options in terms of waste loading and/or decay time required before treatment. For Option 1, glass ceramics show an increase in waste loading of 15 mass % and reduction in decay time of 24 years. Decay times of {approx}50 years or longer are close to the expected age of the fuel that will be reprocessed when the modified open or closed fuel cycle is expected to be put into action. Option 2 shows a 2x to 2.5x increase in waste loading with decay times of only 45 years. Note that for Option 2 glass, the required decay time before treatment is only 35 years because of the waste loading limits related to the solubility of MoO{sub 3} in glass. If glass was evaluated for similar waste loadings as those achieved in Option 2 glass ceramics, the decay time would be significantly longer than 45 years. These glass ceramics are not optimized, but already they show the potential to dramatically reduce the amount of waste generated while still utilizing the proven processing technology used for glass production.

Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna; Sickafus, Kurt E.

2010-09-23T23:59:59.000Z

206

Modeling of thermal plasma arc technology FY 1994 report  

SciTech Connect

The thermal plasma arc process is under consideration to thermally treat hazardous and radioactive waste. A computer model for the thermal plasma arc technology was designed as a tool to aid in the development and use of the plasma arc-Joule beating process. The value of this computer model is to: (a) aid in understanding the plasma arc-Joule beating process as applied to buried waste or exhumed buried waste, (b) help design melter geometry and electrode configuration, (c) calculate the process capability of vitrifying waste (i.e., tons/hour), (d) develop efficient plasma and melter operating conditions to optimize the process and/or reduce safety hazards, (e) calculate chemical reactions during treatment of waste to track chemical composition of off-gas products, and composition of final vitrified waste form and (f) help compare the designs of different plasma-arc facilities. A steady-state model of a two-dimensional axisymmetric transferred plasma arc has been developed and validated. A parametric analysis was performed that studied the effects of arc length, plasma gas composition, and input power on the temperatures and velocity profiles of the slag and plasma gas. A two-dimensional transient thermo-fluid model of the US Bureau of Mines plasma arc melter has been developed. This model includes the growth of a slag pool. The thermo-fluid model is used to predict the temperature and pressure fields within a plasma arc furnace. An analysis was performed to determine the effects of a molten metal pool on the temperature, velocity, and voltage fields within the slag. A robust and accurate model for the chemical equilibrium calculations has been selected to determine chemical composition of final waste form and off-gas based on the temperatures and pressures within the plasma-arc furnace. A chemical database has been selected. The database is based on the materials to be processed in the plasma arc furnaces.

Hawkes, G.L.; Nguyen, H.D.; Paik, S.; McKellar, M.G.

1995-03-01T23:59:59.000Z

207

NUMERICAL DESIGN TOOLS FOR THERMAL REPLICATION OF  

E-Print Network (OSTI)

by heating Ceramic block Glass workpiece before heating Figure 1: Thermal Replication (after Smith et al. [14NUMERICAL DESIGN TOOLS FOR THERMAL REPLICATION OF OPTICAL­QUALITY SURFACES Y.M. Stokes 1 Department. #12; Thermal replication of optical surfaces 1 1 Introduction Thermal replication is an industrial

Stokes, Yvonne

208

INCONEL 690 CORROSION IN WTP (WASTE TREATMENT PLANT) HLW (HIGH LEVEL WASTE) GLASS MELTS RICH IN ALUMINUM & BISMUTH & CHROMIUM OR ALUMINUM/SODIUM  

SciTech Connect

Metal corrosion tests were conducted with four high waste loading non-Fe-limited HLW glass compositions. The results at 1150 C (the WTP nominal melter operating temperature) show corrosion performance for all four glasses that is comparable to that of other typical borosilicate waste glasses, including HLW glass compositions that have been developed for iron-limited WTP streams. Of the four glasses tested, the Bi-limited composition shows the greatest extent of corrosion, which may be related to its higher phosphorus content. Tests at higher suggest that a moderate elevation of the melter operating temperature (up to 1200 C) should not result in any significant increase in Inconel corrosion. However, corrosion rates did increase significantly at yet higher temperatures (1230 C). Very little difference was observed with and without the presence of an electric current density of 6 A/inch{sup 2}, which is the typical upper design limit for Inconel electrodes. The data show a roughly linear relationship between the thickness of the oxide scale on the coupon and the Cr-depletion depth, which is consistent with the chromium depletion providing the material source for scale growth. Analysis of the time dependence of the Cr depletion profiles measured at 1200 C suggests that diffusion of Cr in the Ni-based Inconel alloy controls the depletion depth of Cr inside the alloy. The diffusion coefficient derived from the experimental data agrees within one order of magnitude with the published diffusion coefficient data for Cr in Ni matrices; the difference is likely due to the contribution from faster grain boundary diffusion in the tested Inconel alloy. A simple diffusion model based on these data predicts that Inconel 690 alloy will suffer Cr depletion damage to a depth of about 1 cm over a five year service life at 1200 C in these glasses.

KRUGER AA; FENG Z; GAN H; PEGG IL

2009-11-05T23:59:59.000Z

209

Glass and Glass Products (2010 MECS)  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Glass Sector (NAICS 3272, 327993) Energy use data source: 2010 EIA MECS (with adjustments) Footprint Last Revised: February 2014

210

Neutron Brillouin scattering in a metallic glass  

SciTech Connect

The dispersion of collective modes in a metallic glass (Mg{sub 70}Zn{sub 30}) measured earlier at the thermal neutron time-of-flight spectrometer IN4 of the HFR of the ILL could be extended towards lower momentum transfers down to the first pseudo-Brillouin zone for the first time. This extension to momentum transfer not accessible up to now was possible using the highly resolving time-of-flight spectrometer HET of the new spallation source ISIS. In the region of overlap the two parts of the dispersion determined with different samples of the same metallic glass on different instruments agree very well. Also the earlier discrepancies with the dispersion determined for this metallic glass from a computer simulation could be nearly completely eliminated due to a more recent and more complete investigations of this glass.

Suck, J.B. (Kernforschungszentrum Karlsruhe GmbH (Germany). Inst. fuer Nukleare Festkoerperphysik); Egelstaff, P.A. (Guelph Univ., ON (Canada). Dept. of Physics); Robinson, R.A.; Sivia, D.S. (Los Alamos National Lab., NM (United States)); Taylor, A.D. (Rutherford Appleton Lab., Chilton (United Kingdom))

1991-01-01T23:59:59.000Z

211

Glass Working, Use and Discard  

E-Print Network (OSTI)

Beck, Horace C. 1934 Glass before 1500 BC. Ancient Egypt7 - 21. Cooney, John 1960 Glass sculpture in ancient Egypt.Journal of Glass Studies 2, pp. 10 - 43. 1976 Glass.

Nicholson, Paul

2011-01-01T23:59:59.000Z

212

Chapter 14 - Glass Recycling  

Science Journals Connector (OSTI)

Abstract Glass has established itself as an essential material in our lives. The composition of glass depends on what it is used for, but the majority of glass in circulation is of the soda-limesilicate type. It is a material that is eminently recyclable, in the sense that it merely needs to be remelted and reformed to produce another glass article. However, glass must be color-sorted and processed to remove contaminants to ensure it is compatible with the product being manufactured. The key benefit of recycling via remelting is the reduced energy demand. However, because differences in color composition can arise between recovered glass and manufacturing output, alternative outlets are also often necessary. This chapter examines both the recycling of glass back into glass manufacture and these alternatives.

Thomas D. Dyer

2014-01-01T23:59:59.000Z

213

Kevin Glass | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass kglass Primary tabs View(active tab) Track Kevin Glass Staff Member Title: Scientist Address: P.O. Box 999 K8-83 City: Richland State: WA Zip Code: 99352 Phone: (509)...

214

DRAFT Glass.indd  

NLE Websites -- All DOE Office Websites (Extended Search)

FAST FACTS FAST FACTS Glass technology provides a versatile method for safely managing a variety of wastes SRNL has studied the behavior in glass of nearly every element in the Periodic Table Overview Converting waste materials into a stable glass form is a highly effective way of treating and disposing of many types of waste, including some hazardous and radioactive wastes. Vitrifi cation - the immobilization of a material in glass - is

215

MECS 2006- Glass  

Energy.gov (U.S. Department of Energy (DOE))

Manufacturing Energy and Carbon Footprint for Glass (NAICS 3272, 327993) Sector with Total Energy Input, October 2012 (MECS 2006)

216

Comparison of glass surfaces as a countertop material to existing surfaces  

SciTech Connect

Gleen Glass, a small production glass company that creates countertops, was selected for the Technology Assistance Program through Pacific Northwest National Laboratory. Gleen Glass was seeking material property analysis comparing glass as a countertop material to current surfaces (i.e. marble, granite and engineered stone). With samples provided from Gleen Glass, testing was done on granite, marble, and 3 different glass surfaces ('Journey,' 'Pebble,' and 'Gleen'). Results showed the glass surfaces have a lower density, lower water absorption, and are stronger in compressive and flexural tests as compared to granite and marble. Thermal shock tests showed the glass failed when objects with a high thermal mass are placed directly on them, whereas marble and granite did not fracture under these conditions.

Turo, Laura A.; Winschell, Abigail E.

2011-09-01T23:59:59.000Z

217

SLUDGE BATCH 7B GLASS VARIABILITY STUDY  

SciTech Connect

The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable using the current Product Composition Control System (PCCS) models for durability, but were acceptable compared to the EA glass when tested. These glasses fell outside of the lower 95% confidence band, which demonstrates conservatism in the model. A few of the glasses fell outside of the upper 95% confidence band; however, these particular glasses have normalized release values that were much lower than the values of EA and should be of no practical concern. Per the requirements of the DWPF Glass Product Control Program, the PCCS durability models have been shown to be applicable to the SB7b sludge system with a range of Na{sub 2}O concentrations blended with Frits 418 or 702. PCT results from the glasses fabricated as part of the variability study were shown to be predictable by the current DWPF PCCS models and/or acceptable with respect to the EA benchmark glass regardless of thermal history or compositional view.

Johnson, F.; Edwards, T.

2011-10-25T23:59:59.000Z

218

Peg supported thermal insulation panel  

DOE Patents (OSTI)

A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprises high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure. 2 figs.

Nowobilski, J.J.; Owens, W.J.

1985-04-30T23:59:59.000Z

219

Peg supported thermal insulation panel  

DOE Patents (OSTI)

A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprising high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure.

Nowobilski, Jeffert J. (Orchard Park, NY); Owens, William J. (Kenmore, NY)

1985-01-01T23:59:59.000Z

220

Sintering and crystallization of akermanite-based glassceramics  

Science Journals Connector (OSTI)

Akermanite-based glassceramics were successfully produced from the SiO2Al2O3B2O3MgOCaONa2OF system via sintering and crystallization of glass-powder compacts at low temperatures between 750 and 800 C. The experimental results indicated that the amount of Al2O3 in the parent glass composition is seemingly a key factor with regard to the potential of this system to crystallize into a mono-mineral akermanite glassceramic. The aesthetics and the mechanical, the chemical and the thermal properties of the produced glassceramics in conjunction with the evaluation of the economic processing route proposed qualify these glassceramics for further investigation as potential materials suitable for applications in restorative dentistry.

J.M.G. Ventura; D.U. Tulyaganov; S. Agathopoulos; J.M.F. Ferreira

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The recycling of the coal fly ash in glass production  

SciTech Connect

The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A. [Istanbul Technical University, Istanbul (Turkey). Dept. of Chemical Engineering

2006-09-15T23:59:59.000Z

222

GlassMelt&Sealing  

NLE Websites -- All DOE Office Websites (Extended Search)

Glass Melting and Sealing Glass Melting and Sealing Manufacturing Technologies The Manufacturing Science & Technology Center performs process development of glass and glass-ceramic-to-metal seals. Small batches of specialty glass can be melted from reagent grade oxide powders. Glass and glass-ceramic-to-metal seals are made in microprocessor controlled inert atmospheres and are checked for her- meticity after sealing. Sandia's extensive properties database of low melting solder glasses is used to aid in material and processing decisions when making glass-to-glass, ceramic-to-ceramic, and glass-to-ceramic seals. These seals are typically done in air at much lower tem- peratures than glass and glass-to-ceramic seals. Capabilities * Interface with designers and vendors to assure that the most appropriate materi-

223

Diamond turning of glass  

SciTech Connect

A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

Blackley, W.S.; Scattergood, R.O.

1988-12-01T23:59:59.000Z

224

Review of the Hanford Site Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity, December 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

the Hanford Site the Hanford Site Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity December 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background.......................................................................................................................................... 1 3.0 Scope and Methodology... ................................................................................................................... 1

225

Review of the Hanford Site Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity, December 2012  

NLE Websites -- All DOE Office Websites (Extended Search)

the Hanford Site the Hanford Site Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity December 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background.......................................................................................................................................... 1 3.0 Scope and Methodology... ................................................................................................................... 1

226

Viscosity Measurements with Glass  

Science Journals Connector (OSTI)

1 May 1925 research-article Viscosity Measurements with Glass Vaughan H. Stott Edith Irvine D. Turner The Royal Society is collaborating with JSTOR to digitize, preserve...

1925-01-01T23:59:59.000Z

227

Richard Serra - Philip Glass.  

E-Print Network (OSTI)

??In dieser Arbeit soll den Gemeinsamkeiten im Werk von Richard Serra und Philip Glass nachgegangen werden. Ausgehend von der Analyse von Serras Arbeiten werden die (more)

Vogl, Christiane

2008-01-01T23:59:59.000Z

228

Glass/ceramic coatings for implants  

DOE Patents (OSTI)

Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

Tomsia, Antoni P. (Pinole, CA); Saiz, Eduardo (Berkeley, CA); Gomez-Vega, Jose M. (Nagoya, JP); Marshall, Sally J. (Larkspur, CA); Marshall, Grayson W. (Larkspur, CA)

2011-09-06T23:59:59.000Z

229

Rare Earth Phosphate Glass and Glass-Ceramic Proton Conductors  

E-Print Network (OSTI)

300-500C. Doping rare earth phosphate glasses with Ce, andRare Earth Phosphate Glass and Glass-Ceramic Protonconductivity of alkaline-earth doped rare earth phosphate

De Jonghe, Lutgard C.

2010-01-01T23:59:59.000Z

230

ITP Glass: Glass Industry Technology Roadmap; April 2002  

Energy.gov (U.S. Department of Energy (DOE))

Glass is a unique material that has been produced for thousands of years. The glass industry's products are an integral part of the American economy and everyday life. Glass products are used in food and beverage packaging, lighting, communications, etc.

231

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

61 - 23770 of 31,917 results. 61 - 23770 of 31,917 results. Page EA-0821: Operation of the Glass Melter Thermal Treatment Unit at the U.S. Department of Energy's Mound Plant, Miamisburg, Ohio This EA evaluates the environmental impacts of a proposal to use an existing glass melter thermal treatment unit (also known as a Penberthy Pyro-Converter joule-heated glass furnace) for the... http://energy.gov/nepa/ea-0821-operation-glass-melter-thermal-treatment-unit-us-department-energys-mound-plant Page EA-0843: Idaho National Engineering Laboratory Low-Level and Mixed Waste Processing, Idaho Falls, Idaho This EA evaluates the environmental impacts of a proposal to (1) reduce the volume of the U.S. Department of Energy's Idaho National Engineering Laboratory's (INEL) generated low-level waste (LLW)...

232

Volume 130, number 1,2 CHEMICAL PHYSICS LETTERS 26 September 1986 OPTICAL DEPHASING OF CHROMOPHORES IN AN ORGANIC GLASS  

E-Print Network (OSTI)

IN AN ORGANIC GLASS: PICOSECOND PHOTON ECHO AND HOLE BURNING EXPERIMENTS C.A. WALSH, M. BERG, L.R. NARASIMHAN The homogeneous optical dephasing time T2for the organic glass system resorufin in ethanol is measured-temperature properties of glasses are dis- tinctly different from those of crystals as has been demonstrated by thermal

Fayer, Michael D.

233

Cultivation of Mycoplasmas on Glass  

Science Journals Connector (OSTI)

...Immunology Cultivation of Mycoplasmas on Glass R. H. Purcell J. R. Valdesuso W. L...human origin were successfully cultivated on glass. Complement-fixing (CF) antigens prepared from glass-adherent mycoplasmas were potent, specific...

R. H. Purcell; J. R. Valdesuso; W. L. Cline; W. D. James; R. M. Chanock

1971-02-01T23:59:59.000Z

234

Microsoft PowerPoint - ESGCold Cap Melting (2) [Read-Only  

NLE Websites -- All DOE Office Websites (Extended Search)

Pre-Treatment Facility HLW Vitrification Facility LAW Vitrification Facility Outline * Glass-melting furnace (melter) and cold cap (batch blanket) * Melter feed conversion to...

235

Environmental assessment of thermal insulation composite material  

Science Journals Connector (OSTI)

Of other thermal insulation materials, the foam glass has most similar mechanical properties (PE...2008) and use (structural details exposed to high compressive loads). Therefore, it is (to a certain extend) comp...

Karel Struhala; Zuzana Strnsk; Jan P?n?k

2014-12-01T23:59:59.000Z

236

Advances in Glass Formulations for Hanford High-Aluminum, High-Iron and Enhanced Sulphate Management in HLW Streams - 13000  

SciTech Connect

The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP's overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or sulphur. Waste processing rate increases for high-iron streams as a combined effect of higher waste loadings and higher melt rates resulting from new formulations have been achieved. (author)

Kruger, Albert A. [WTP Engineering Division, United States Department of Energy, Office of River Protection, Post Office Box 450, Richland, Washington 99352 (United States)] [WTP Engineering Division, United States Department of Energy, Office of River Protection, Post Office Box 450, Richland, Washington 99352 (United States)

2013-07-01T23:59:59.000Z

237

Advances in Glass Formulations for Hanford High-Alumimum, High-Iron and Enhanced Sulphate Management in HLW Streams - 13000  

SciTech Connect

The current estimates and glass formulation efforts have been conservative in terms of achievable waste loadings. These formulations have been specified to ensure that the glasses are homogenous, contain essentially no crystalline phases, are processable in joule-heated, ceramic-lined melters and meet Hanford Tank Waste Treatment and Immobilization Plant (WTP) Contract terms. The WTP?s overall mission will require the immobilization of tank waste compositions that are dominated by mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulphur (S) compounds as waste-limiting components. Glass compositions for these waste mixtures have been developed based upon previous experience and current glass property models. Recently, DOE has initiated a testing program to develop and characterize HLW glasses with higher waste loadings and higher throughput efficiencies. Results of this work have demonstrated the feasibility of increases in waste loading from about 25 wt% to 33-50 wt% (based on oxide loading) in the glass depending on the waste stream. In view of the importance of aluminum limited waste streams at Hanford (and also Savannah River), the ability to achieve high waste loadings without adversely impacting melt rates has the potential for enormous cost savings from reductions in canister count and the potential for schedule acceleration. Consequently, the potential return on the investment made in the development of these enhancements is extremely favorable. Glass composition development for one of the latest Hanford HLW projected compositions with sulphate concentrations high enough to limit waste loading have been successfully tested and show tolerance for previously unreported tolerance for sulphate. Though a significant increase in waste loading for high-iron wastes has been achieved, the magnitude of the increase is not as substantial as those achieved for high-aluminum, high-chromium, high-bismuth or sulphur. Waste processing rate increases for high-iron streams as a combined effect of higher waste loadings and higher melt rates resulting from new formulations have been achieved.

Kruger, Albert A.

2013-01-16T23:59:59.000Z

238

Glass-Making  

Science Journals Connector (OSTI)

... director of Messrs. Pilkington Brothers, Ltd., on The Making of a Sheet of Glass. Major Weeks first gave a brief outline of some fundamental scientific considerations, with ... the raw materials are introduced at one end of a continuous furnace and the molten glass withdrawn at the other. The various processes necessary for the manufacture of sheet and ...

1933-12-16T23:59:59.000Z

239

The Glass Research Association  

Science Journals Connector (OSTI)

... widely known that among the industries which have been profoundly influenced by the war the glass and glassware industry of the United Kingdom occupies a foremost place. Not only have ... certain special sections of this industry, previously non-existent in the country, to supply glass and glassware, ...

EDWARD MEIGH

1919-11-13T23:59:59.000Z

240

Glass for Optical Purposes  

Science Journals Connector (OSTI)

... THE importance of an adequate supply of optical glass of all the principal types cannot be overestimated. The improvement of the microscope has ... improvement of the microscope has been and is still retarded for the want of suitable glasses, the construction of large telescopes is limited by the capacity of the glassmaker to ...

S. D. CHALMERS

1914-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Glass for Reflectors  

Science Journals Connector (OSTI)

... "for the 4-foot disc of glass for the Paris reflector, in place of that which has so recently resulted in ... in place of that which has so recently resulted in failure, the St. Gobain Glass Company require twelve months' time to perfect (although, be it remembered, the quality ...

HENRY BESSEMER

1878-01-24T23:59:59.000Z

242

Decorative Glass Processes  

Science Journals Connector (OSTI)

... of a number of processes employed for the purpose of producing architectural decorative work in glass. Beginning with an account of the various kinds of ... . Beginning with an account of the various kinds of glass available for such work, and indulging in a retrospect of ...

W. R.

1909-01-21T23:59:59.000Z

243

Structure of Glass  

Science Journals Connector (OSTI)

... Introduction of certain cations in soda or potash glass contracts or expands the network proportionally to the concentration, each oxide having its own ... constant over a wide range of compositions. The factors are different for soda and potash glasses, but they remain constant when

I. NRAY-SZAB

1959-03-28T23:59:59.000Z

244

Notes on Glass1  

Science Journals Connector (OSTI)

... A CERTAIN amount of experimental work on glass-ware of various kinds has been carried out recently at the National Physical Laboratory, ... known some of the results. Chemical investigations have for some years been dependent on German glass; the publication of the analyses and of test results may, it is hoped, ...

1915-03-18T23:59:59.000Z

245

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

246

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-07-15T23:59:59.000Z

247

Sol-GelGlasses  

NLE Websites -- All DOE Office Websites (Extended Search)

Sol-Gel Glasses Sol-Gel Glasses Manufacturing Technologies The Manufacturing Science & Technology Center conducts process development and scale-up of ceramic and glass materials prepared by the sol- gel process. Sol-gel processing uses solutions prepared at low temperature rather than high temperature powder processing to make materi- als with controlled properties. A precursor sol-gel solution (sol) is either poured into a mold and allowed to gel or is diluted and applied to a sub- strate by spinning, dipping, spraying, elec- trophoresis, inkjet printing or roll coating. Controlled drying of the wet gel results in either a ceramic or glass bulk part or a thin film on a glass, plastic, ceramic or metal substrate. Sol-gel derived materials have diverse applications in optics, electronics, energy, space, sensors and

248

Glass: Recent Research and Developments  

Science Journals Connector (OSTI)

... THE systematic study of glass and the subject of ... and the subject of glass technology is a field with which the University of Sheffield is particularly associated, Sheffield ...

1956-10-20T23:59:59.000Z

249

Compositional trends of ?-induced optical changes observed in chalcogenide glasses of binary As-S system  

SciTech Connect

Compositional trends of ?-induced optical changes in chalcogenide glasses are studied with the binary As-S system. Effects of ?-irradiation and annealing are compared using the changes measured in the fundamental optical absorption edge region. It is shown that annealing near the glass transition temperature leads to bleaching of As-S glasses, while ?-irradiation leads to darkening; both depend on the glass composition and thermal history of the specimens. These results are explained in terms of competitive destructionpolymerization transformations and physical aging occurring in As-S chalcogenide glasses under the influence of ?-irradiation.

Shpotyuk, M.; Shpotyuk, O.; Golovchak, Roman; McCloy, John S.; Riley, Brian J.

2014-01-23T23:59:59.000Z

250

Ultrafast pulsed laser utilizing broad bandwidth laser glass  

DOE Patents (OSTI)

An ultrafast laser uses a Nd-doped phosphate laser glass characterized by a particularly broad emission bandwidth to generate the shortest possible output pulses. The laser glass is composed primarily of P{sub 2}O{sub 5}, Al{sub 2}O{sub 3} and MgO, and possesses physical and thermal properties that are compatible with standard melting and manufacturing methods. The broad bandwidth laser glass can be used in modelocked oscillators as well as in amplifier modules. 7 figs.

Payne, S.A.; Hayden, J.S.

1997-09-02T23:59:59.000Z

251

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network (OSTI)

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Categorization and Decision Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Programming, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D

Maddox, W. Todd

252

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network (OSTI)

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University Making, The University of Texas at Austin #12;Glass, Brian 2 Duties include: Designing and constructing, constructing, and running experiments, statistical analysis. JOURNAL PUBLICATIONS Glass, B. D., Chotibut, T

Maddox, W. Todd

253

Glass, Brian 1 BRIAN DANIEL GLASS, M.A.  

E-Print Network (OSTI)

Glass, Brian 1 BRIAN DANIEL GLASS, M.A. University Department of Psychology, A8000 The University of Texas at Austin Austin, TX 78712 (512) 232-2883 e-mail: glass@mail.utexas.edu EDUCATION 2006 ­ Cognitive include: Designing and constructing experiments, statistical #12;Glass, Brian 2 analysis, manuscript

Maddox, W. Todd

254

Final Report - DuraMelter 100 Tests to Support LAW Glass Formulation Correlation Development, VSL-06R6480-1, Rev. 0  

SciTech Connect

This report describes the results of work and testing specified by Test Specifications 24590-LAW-TSP-RT-04-004, Rev. 0, Test Plans VSL-05T5480-1, Rev. 0 and Text Exceptions 24590-LAW-TEF-RT-05-00002. The work and any associated testing followed established quality assurance requirements and was conducted as authorized. The descriptions provided in this test report are an accurate account of both the conduct of the work and the data collected. Results required by the Test Plan are reported. Also reported are any unusual or anomalous occurences that are different from the starting hypotheses. The test results and this report have been reviewed and verified.

Kruger, Albert A.; Muller, I. S.; Gong, W.; Pegg, I. L.; Matlack, K. S.

2013-12-03T23:59:59.000Z

255

Cylindrical thermal contact conductance  

E-Print Network (OSTI)

of the Mahr-Federal, Inc. respectively facilitated and provided the necessary surface metrology data of the test pieces. Mr. Claude Davis of Corning, Inc. obtained the thermophysical properties of the Ultra Low Expansion Titanium Silicate glass used... as thermal expansion standard. The engineers at National Instruments provided some much-needed advice and software for programming the data acquisition system. The TAMU Physics Machine Shop provided design advice and a couple of last...

Ayers, George Harold

2004-09-30T23:59:59.000Z

256

Vacuum Glazing; A Thermally Insulating Window Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Vacuum Glazing; A Thermally Insulating Window Technology Vacuum Glazing; A Thermally Insulating Window Technology Speaker(s): Cenk Kocer Date: May 31, 2012 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Sunnie Lim The vacuum glazing consists of two panes of glass separated by a sub-millimetre vacuum gap. Under the action of atmospheric pressure the separation of the panes is maintained by an array of high strength spacers in the gap. The glass panes are hermetically sealed at the edge using a low melting point glass frit (solder glass). Since 1913 many have worked on a practical implementation of such a flat insulating glass structure, with success finally being reported in 1989 by Collins et al. at the University of Sydney. The purpose of this talk is to present a brief history of the vacuum glazing research at the University of Sydney, and outline in detail

257

Changes in the Atomic Structure through Glass Transition Observed by X-Ray Scattering  

SciTech Connect

The glass transition involves a minor change in the internal energy, and yet the physical and mechanical properties of a glass change dramatically. In order to determine the evolution of the atomic structure through the glass transition, we employed in-situ synchrotron X-ray scattering measurements as a function of temperature on a model material: Zr-Cu-Al metallic glass. We found that the thermal expansion at the atomic level is smaller than the macroscopic thermal expansion, and significantly increases above the glass transition temperature. The observed changes in the pair-distribution function (PDF) are explained in terms of the fluctuations in the local atomic volume and their change through the glass transition.

Egami, Takeshi [ORNL

2012-01-01T23:59:59.000Z

258

Super ionic conductive glass  

DOE Patents (OSTI)

An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

Susman, Sherman (Park Forest, IL); Volin, Kenneth J. (Fort Collins, CO)

1984-01-01T23:59:59.000Z

259

SUMMARY OF 2010 DOE EM INTERNATIONAL PROGRAM STUDIES OF WASTE GLASS MELT RATE ENHANCEMENT  

SciTech Connect

A collaborative study has been established under the U.S. Department of Energy (DOE) Office of Environmental Management International Program between the Savannah River National Laboratory (SRNL) and the V. G. Khlopin Radium Institute (KRI) in St. Petersburg, Russia, to investigate potential improvements in melt rate via chemical additions to the glass frit. Researchers at KRI suggested a methodology for selecting frit additives based on empirical coefficients for optimization of glass melting available in the Russian literature. Using these coefficients, KRI identified B{sub 2}O{sub 3}, CuO, and MnO as frit additives that were likely to improve melt rate without having adverse effects on crystallization of the glass or its chemical durability. The results of the melt rate testing in the SMK melter showed that the slurry feed rate (used as a gauge of melt rate) could be significantly increased when MnO or CuO were added to Frit 550 with the SMR-2 sludge. The feed rates increased by about 27% when MnO was added to the frit and by about 26% when CuO was added to the frit, as compared to earlier results for Frit 550 alone. The impact of adding additional B{sub 2}O{sub 3} to the frit was minor when added with CuO. The additional B{sub 2}O{sub 3} showed a more significant, 39% improvement in melt rate when added with MnO. The additional B{sub 2}O{sub 3} also reduced the viscosity of the glasses during pouring. Samples of the glasses from the melt rate testing characterized at SRNL showed that there were no significant impacts on crystallization of the glasses. All of the glasses had very good chemical durability. Chemical composition measurements showed that the frit additives were present in concentrations below the targeted values in some of the glasses. Therefore, it is possible that higher concentrations of these additives may further improve melt rate, although the impacts of higher concentrations of these components on crystallization and durability would need to be determined. Overall, the results show an excellent potential for these additives to significantly improve waste throughput for DOE vitrification facilities. A complete report from KRI is included as an appendix to this document.

Fox, K.; Marra, J.

2011-01-19T23:59:59.000Z

260

Metallic glass composition  

DOE Patents (OSTI)

A metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon carbon and phosphorous to which is added an amount of a ductility enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

Kroeger, Donald M. (Knoxville, TN); Koch, Carl C. (Raleigh, NC)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

DEVELOPMENT OF AN ANTIFOAM TRACKING SYSTEM AS AN OPTION TO SUPPORT THE MELTER OFF-GAS FLAMMABILITY CONTROL STRATEGY AT THE DWPF  

SciTech Connect

The Savannah River National Laboratory (SRNL) has been working with the Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) in the development and implementation of an additional strategy for confidently satisfying the flammability controls for DWPFs melter operation. An initial strategy for implementing the operational constraints associated with flammability control in DWPF was based upon an analytically determined carbon concentration from antifoam. Due to the conservative error structure associated with the analytical approach, its implementation has significantly reduced the operating window for processing and has led to recurrent Slurry Mix Evaporator (SME) and Melter Feed Tank (MFT) remediation. To address the adverse operating impact of the current implementation strategy, SRR issued a Technical Task Request (TTR) to SRNL requesting the development and documentation of an alternate strategy for evaluating the carbon contribution from antifoam. The proposed strategy presented in this report was developed under the guidance of a Task Technical and Quality Assurance Plan (TTQAP) and involves calculating the carbon concentration from antifoam based upon the actual mass of antifoam added to the process assuming 100% retention. The mass of antifoam in the Additive Mix Feed Tank (AMFT), in the Sludge Receipt and Adjustment Tank (SRAT), and in the SME is tracked by mass balance as part of this strategy. As these quantities are monitored, the random and bias uncertainties affecting their values are also maintained and accounted for. This report documents: 1) the development of an alternate implementation strategy and associated equations describing the carbon concentration from antifoam in each SME batch derived from the actual amount of antifoam introduced into the AMFT, SRAT, and SME during the processing of the batch. 2) the equations and error structure for incorporating the proposed strategy into melter off-gas flammability assessments. Sample calculations of the system are also included in this report. Please note that the system developed and documented in this report is intended as an alternative to the current, analytically-driven system being utilized by DWPF; the proposed system is not intended to eliminate the current system. Also note that the system developed in this report to track antifoam mass in the AMFT, SRAT, and SME will be applicable beyond just Sludge Batch 8. While the model used to determine acceptability of the SME product with respect to melter off-gas flammability controls must be reassessed for each change in sludge batch, the antifoam mass tracking methodology is independent of sludge batch composition and as such will be transferable to future sludge batches.

Edwards, T.; Lambert, D.

2014-08-27T23:59:59.000Z

262

Tunable, self-powered integrated arc plasma-melter vitrification system for waste treatment and resource recovery  

DOE Patents (OSTI)

The present invention provides a relatively compact self-powered, tunable waste conversion system and apparatus which has the advantage of highly robust operation which provides complete or substantially complete conversion of a wide range of waste streams into useful gas and a stable, nonleachable solid product at a single location with greatly reduced air pollution to meet air quality standards. The system provides the capability for highly efficient conversion of waste into high quality combustible gas and for high efficiency conversion of the gas into electricity by utilizing a high efficiency gas turbine or by an internal combustion engine. The solid product can be suitable for various commercial applications. Alternatively, the solid product stream, which is a safe, stable material, may be disposed of without special considerations as hazardous material. In the preferred embodiment of the invention, the arc plasma furnace and joule heated melter are formed as a fully integrated unit with a common melt pool having circuit arrangements for the simultaneous independently controllable operation of both the arc plasma and the joule heated portions of the unit without interference with one another. The preferred configuration of this embodiment of the invention utilizes two arc plasma electrodes with an elongated chamber for the molten pool such that the molten pool is capable of providing conducting paths between electrodes. The apparatus may additionally be employed with reduced or without further use of the gases generated by the conversion process. The apparatus may be employed as a self-powered or net electricity producing unit where use of an auxiliary fuel provides the required level of electricity production.

Titus, Charles H. (Newtown Square, PA); Cohn, Daniel R. (Chestnuthill, MA); Surma, Jeffrey E. (Kennewick, WA)

1998-01-01T23:59:59.000Z

263

A Plastic for Thermal Insulation  

Science Journals Connector (OSTI)

... ft. per in. thickness per 1 F. difference of temperature, so that its insulation properties compare very favourably with slab-cork (0-25 B.TH.U.), glass ... tenth that of slab-cork. This makes it of considerable interest in connexion with thermal insulation during transport. Isoflex is non-porous and non-absorbent, with the result that its ...

1941-04-26T23:59:59.000Z

264

Cardinal Glass Industries | Open Energy Information  

Open Energy Info (EERE)

Cardinal Glass Industries Jump to: navigation, search Name: Cardinal Glass Industries Place: Eden Prairie, Minnesota Zip: 55344 Product: Minnesota-based glass products maker. The...

265

Glass blowing on a wafer level  

E-Print Network (OSTI)

E. Shelby, Introduction to Glass Science and Technology. :Properties of Corning Glasses [Online]. Available: http://1981. [15] R. H. Doremus, Glass Science. New York: Wiley,

Eklund, E. Jesper; Shkel, Andrei M.

2007-01-01T23:59:59.000Z

266

IMPACT OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION MELT RATE STUDIES  

SciTech Connect

This study was undertaken to evaluate the potential impacts of the Small Column Ion Exchange (SCIX) streams - particularly the addition of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) - on the melt rate of simulated feed for the Defense Waste Processing Facility (DWPF). Additional MST was added to account for contributions from the Salt Waste Processing Facility (SWPF). The Savannah River National Laboratory (SRNL) Melt Rate Furnace (MRF) was used to evaluate four melter feed compositions: two with simulated SCIX and SWPF material and two without. The Slurry-fed Melt Rate Furnace (SMRF) was then used to compare two different feeds: one with and one without bounding concentrations of simulated SCIX and SWPF material. Analyses of the melter feed materials confirmed that they met their targeted compositions. Four feeds were tested in triplicate in the MRF. The linear melt rates were determined by using X-ray computed tomography to measure the height of the glass formed along the bottom of the beakers. The addition of the SCIX and SWPF material reduced the average measured melt rate by about 10% in MRF testing, although there was significant scatter in the data. Two feeds were tested in the SMRF. It was noted that the ground CST alone (ground CST with liquid in a bucket) was extremely difficult to resuspend during preparation of the feed with material from SCIX and SWPF. This feed was also more difficult to pump than the material without MST and CST due to settling occurring in the melter feed line, although the yield stress of both feeds was high relative to the DWPF design basis. Steady state feeding conditions were maintained for about five hours for each feed. There was a reduction in the feed and pour rates of approximately 15% when CST and MST were added to the feed, although there was significant scatter in the data. Analysis of samples collected from the SMRF pour stream showed that the composition of the glass changed as expected when MST and CST were added to the feed. These reductions in melt rate are consistent with previous studies that showed a negative impact of increased TiO{sub 2} concentrations on the rate of melting. The impact of agitating the melt pool via bubbling was not studied as part of this work, but may be of interest for further testing. It is recommended that additional melt rate testing be performed should a potential reduction in melt rate of 10-15% be considered an issue of concern, or should the anticipated composition of the glass with the addition of material from salt waste processing be modified significantly from the current projections, either due to changes in sludge batch preparation or changes in the composition or volume of SCIX and SWPF material.

Fox, K.; Miller, D.; Koopman, D.

2011-04-26T23:59:59.000Z

267

Smart Glass Based on Micro-Blinds (MEMS)  

NLE Websites -- All DOE Office Websites (Extended Search)

Smart Glass Based on Micro-Blinds (MEMS) Smart Glass Based on Micro-Blinds (MEMS) Speaker(s): Boris Lamontagne Date: June 22, 2012 - 2:00pm Location: 90-3122 Seminar Host/Point of Contact: Stephen Selkowitz At the National Research Council, Canada we are developing a new type of smart glass based on micro-blinds (MEMS). The micro-blinds are tiny stressed metallic foils curling up once released or rolling down once actuated using electrostatic forces. Such smart glass is characterized by fast switching speed, UV-temperature insensitive and neutral appearance. Recent results will be presented as a well as our demo. Transmittance and thermal characteristics will also be addressed. There are various possible applications in building, automotive, aerospace as well as in display sectors. A video briefly describing the technology is

268

Elastic interpretation of the glass transition in aluminosilicate liquids  

Science Journals Connector (OSTI)

One of the remaining puzzles of the glass transition is the origin of a glass-forming liquid's fragility, which quantifies the departure of its relaxation time from Arrhenius-activated kinetics. According to the shoving model proposed by Dyre, fragility is controlled by the instantaneous shear modulus of the liquid, since any flow event requires a local volume increase, and the related activation energy is equal to the work done in shoving aside the surrounding atoms. Here, we present an in situ high-temperature Brillouin spectroscopy test of the shoving model near the glass transition of eight aluminosilicate glass-forming systems. We find that the measured viscosity data agree qualitatively with the measured temperature dependence of shear moduli, as predicted by the shoving model. However, the model systematically underpredicts the values of fragility for our aluminosilicate liquids. This suggests that the dynamics of the glass transition are governed by additional factors beyond the evolution of the shear modulus, such as configurational entropy. We have also compared the glass transition temperature (Tg,vis) obtained from viscosity (temperature at 1012 Pa s) with the onset temperatures of the decrease in elastic moduli (Tg,elas) and increase in the thermal expansion coefficient (Tg,CTE) during heating. While we find an approximate one-to-one correlation between Tg,vis and Tg,CTE, it is clear that the elastic moduli probe a different frequency response of the glass structure, since Tg,elas is systematically lower than Tg,vis.

Morten M. Smedskjaer; Liping Huang; Garth Scannell; John C. Mauro

2012-04-27T23:59:59.000Z

269

Demonstration of oxygen-enriched air staging at Owens-Brockway Glass Containers. Technical progress report, August 1, 1995--July 31, 1996  

SciTech Connect

The objective of the program is to demonstrate the use of a previously developed combustion modification technology to reduce NO, emissions from sideport regenerative container glass melters. This technology, known as oxygen-enriched air staging (OEAS), has been demonstrated, and is now being commercialized, for endport container glass furnaces. A 17-month development program has been established with specific objectives to: (1) acquire baseline operating data on the host sideport furnace in Vernon, California, (2) evaluate secondary oxidant injection strategies based on earlier endport furnace results and through modeling of a single port pair, (3) retrofit and test one port pair (the test furnace has six port pairs) with a flexible OEAS system, and select the optimal system configuration, (4) use the results from tests with one port pair to design, retrofit, and test OEAS on the entire furnace (six port pairs), and (5) analyze test results, prepare report, and finalize the business plan to commercialize OEAS for sideport furnaces. The host furnace for testing in this program is an Owens-Brockway 6-port pair sideport furnace in Vernon, California producing 325-ton/d of amber container glass. The baseline NO{sub x} level of this optimized furnace is about 4.0 lb/ton of glass. An anticipated NO{sub x}, reduction of 50% will lower the NO{sub x} production level to below 2 lb/ton. Secondary oxidant staging techniques being considered include oxygen-enriched ambient air staging (OEAS) and oxygen staging (OS).

Rue, D.; Abbasi, H.

1996-11-01T23:59:59.000Z

270

Demonstration of oxygen-enriched air staging at Owens-Brockway glass containers. Quarterly technical progress report, November 1, 1996--January 31, 1997  

SciTech Connect

The objective of the program is to demonstrate the use of a previously developed combustion modification technology to reduce NO, emissions from sideport regenerative container glass melters. This technology, known as oxygen-enriched air staging (OEAS), has been demonstrated, and is now being commercialized, for endport container glass furnaces. A 17-month development program has been established with specific objectives to: (1) acquire baseline operating data on the host sideport furnace in Vernon, California, (2) evaluate secondary oxidant injection strategies based on earlier endport furnace results and through modeling of a single port pair, (3) retrofit and test one port pair (the test furnace has six port pairs) with a flexible OEAS system, and select the optimal system configuration, (4) use the results from tests with one port pair to design, retrofit, and test OEAS on the entire furnace (six port pairs), and (5) analyze test results, prepare report, and finalize the business plan to commercialize OEAS for sideport furnaces. The host furnace for testing in this program is an Owens-Brockway 6-port pair sideport furnace in Vernon, California producing 325-ton/d of amber container glass. The baseline NO{sub x} level of this optimized furnace is about 4.0 lb/ton of glass. An anticipated NO{sub x}, reduction of 50% will lower the NO{sub x} production level to below 2 lb/ton. Secondary oxidant staging techniques being considered include oxygen-enriched ambient air staging (OEAS) and oxygen staging (OS).

Rue, D.; Abbasi, H.

1997-03-01T23:59:59.000Z

271

Crystalline fragments in glasses  

Science Journals Connector (OSTI)

The nature of tetrahedral molecular fragments is investigated in SiSe2 glasses using the molecular-dynamics method. The glass consists of both edge-sharing (ES) and corner-sharing tetrahedra. The ES tetrahedra are the building blocks of chain-like-molecular fragments. The two-edge-sharing tetrahedra are the nucleus, and corner-sharing configurations provide connecting hinges between fragments. Statistics of rings and fragments reveals that threefold and eightfold rings are most abundant, chainlike fragments that are typically 1015 long occur mostly in eightfold rings, and the longest fragments occur in elevenfold rings.

Giomal A. Antonio; Rajiv K. Kalia; Aiichiro Nakano; Priya Vashishta

1992-04-01T23:59:59.000Z

272

Leaching of Nuclear Waste Glasses  

Science Journals Connector (OSTI)

Resistance to aqueous corrosion is the most important requirement of glasses designed to immobilize high level radioactive wastes. Obtaining a highly durable nuclear waste glass is complicated by the requirement ...

L. L. Hench

1985-01-01T23:59:59.000Z

273

Borosilicate Microporous Glasses for Reverse Osmosis  

Science Journals Connector (OSTI)

The characteristics of microporous borosilicate glasses are described. Glasses with an optimum pore distribution are recommended for production and application.

S. L. Zakharov

2004-05-01T23:59:59.000Z

274

Sources of Weakness in Glass  

Science Journals Connector (OSTI)

...October 1964 research-article Sources of Weakness in Glass C. Gurney The theoretical strength of glass is of the order of 2 to 5 MLb./in.$^2$ At room temperature, common glasses with undamaged surfaces give breaking stresses of about...

1964-01-01T23:59:59.000Z

275

Laboratory Waste Disposal HAZARDOUS GLASS  

E-Print Network (OSTI)

Laboratory Waste Disposal HAZARDOUS GLASS Items that could cut or puncture skin or trash- can without any treatment. Hazardous Glass and Plastic: Items that can puncture, cut or scratch if disposed of in normal trash containers. Pasteur pipettes Other pipettes and tips (glass or plastic) Slides and cover

Sheridan, Jennifer

276

TESTS WITH HIGH-BISMUTH HLW GLASSES FINAL REPORT VSL-10R1780-1 REV 0 12/13/10  

SciTech Connect

This Final Report describes the testing of glass formulations developed for Hanford High Level Waste (HLW) containing high concentrations of bismuth. In previous work on high-bismuth HLW streams specified by the Office of River Protection (ORP), fully compliant, high waste loading compositions were developed and subjected to melter testing on the DM100 vitrification system. However, during heat treatment according to the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW canister centerline cooling (CCC) curves, crucible melts of the high-bismuth glasses were observed to foam. Clearly, such an occurrence during cooling of actual HLW canisters would be highly undesirable. Accordingly, the present work involves larger-scale testing to determine whether this effect occurs under more prototypical conditions, as well as crucible-scale tests to determine the causes and potentially remediate the observed foaming behavior. The work included preparation and characterization of crucible melts designed to determine the underlying causes of the foaming behavior as well as to assess potential mitigation strategies. Testing was also conducted on the DM1200 HLW Pilot melter with a composition previously tested on the DM100 and shown to foam during crucible-scale CCC heat treatment. The DM1200 tests evaluated foaming of glasses over a range of bismuth concentrations poured into temperature-controlled, 55-gallon drums which have a diameter that is close to that of the full-scale WTP HLW canisters. In addition, the DM1200 tests provided the first large-scale melter test data on high-bismuth WTP HLW compositions, including information on processing rates, cold cap behavior and off-gas characteristics, and data from this waste composition on the prototypical DM1200 off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for ORP on the same waste composition. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. The present glass formulation and melter testing work was aimed at one of the four waste streams previously specified by the Office of River Protection (ORP). Such testing supports the ORP basis for projection of the amount of Immobilized High Level Waste (IHLW) to be produced at Hanford and evaluation of the likely potential for future enhancements of the WTP over and above the present well-developed baseline. It should be noted that the compositions of the four ORP-specified waste streams differ significantly from those of the feed tanks (AZ-101, AZ-102, C-16/AY-102, and C-104/AY-101) that have been the focus of the extensive technology development and design work performed for the WTP baseline. In this regard, the work on the ORP-specified compositions is complementary to and necessarily of a more exploratory nature than the work in support of the current WTP baseline.

MATLACK KS; KRUGER AA; JOSEPH I; GAN H; KOT WK; CHAUDHURI M; MOHR RK; MCKEOWN DA; BARDAKEI T; GONG W; BUECCHELE AC; PEGG IL

2011-01-05T23:59:59.000Z

277

Demonstration of oxygen-enriched air staging at Owens-Brockway glass containers. Final technical report for the period April 1, 1995--February 28, 1997  

SciTech Connect

The overall objective of this program was to demonstrate the use of a previously developed combustion modification technology to reduce NO{sub x} emissions from sideport regenerative container glass melters. Specific objectives were to: acquire baseline operating data on the host sideport furnace, evaluate secondary oxidant injection strategies based on earlier endport furnace results and through modeling of a single port pair, retrofit and test one port pair (the test furnace has six port pairs) with a flexible OEAS system, and select the optimal system configuration, use the results from tests with one port pair to design, retrofit, and test OEAS on the entire furnace (six port pairs), and analyze test results, prepare report, and finalize the business plan to commercialize OEAS for sideport furnaces.

Rue, D.; Abbasi, H.

1997-10-01T23:59:59.000Z

278

The Color Glass Condensate  

E-Print Network (OSTI)

We provide a broad overview of the theoretical status and phenomenological applications of the Color Glass Condensate effective field theory describing universal properties of saturated gluons in hadron wavefunctions that are extracted from deeply inelastic scattering and hadron-hadron collision experiments at high energies.

F. Gelis; E. Iancu; J. Jalilian-Marian; R. Venugopalan

2010-02-01T23:59:59.000Z

279

Production of glass or glass-ceramic to metal seals with the application of pressure  

DOE Patents (OSTI)

In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

Kelly, Michael D. (West Alexandria, OH); Kramer, Daniel P. (Dayton, OH)

1987-11-10T23:59:59.000Z

280

Production of glass or glass-ceramic to metal seals with the application of pressure  

DOE Patents (OSTI)

In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

Kelly, M.D.; Kramer, D.P.

1985-01-04T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Microsoft PowerPoint - compliant sealing glass review 7,27,2010 rev1.pptx [Read-Only]  

NLE Websites -- All DOE Office Websites (Extended Search)

Compliant glass seal development Compliant glass seal development Y-S Matt Chou, E. Thomsen, E. Mast, J-P Choi, W. Voldrich, and J. W. Stevenson Introduction and objectives Q1: Effect of differential pressure on thermal cycle stability 1 experimental 1. experimental 2. leak rates versus cycling (700-850 o C/1000h) Q2: thermal stability study in a duel environment 1. leak rates versus time (750-800 o C/1000h) 2. microstructure and interface characterization Q3: assess YSZ coating and other mat'l for spacer rings Q g p g Summary Future work Solid-State Energy Conversion Alliance Core Technology Programs Review, July 27-29, 2010, Pittsburgh, PA Compliant versus refractory sealing glass  = E T Compliant sealing glass 1.20E-02 YSO1 glass Refractory sealing glass Data provided by ORNL

282

Statistics of modifier distributions in mixed network glasses  

Science Journals Connector (OSTI)

The constituents of any network glass can be broadly classified as either network formers or network modifiers. Network formers such as SiO2 Al2O3 B2O3 P2O5 etc. provide the backbone of the glass network and are the primary source of its rigid constraints. Network modifiers play a supporting role such as charge stabilization of the network formers or alteration of the network topology through rupture of bridging bonds and introduction of floppy modes. The specific role of the modifiers depends on which network formers are present in the glass and the relative free energies of modifier interactions with each type of network former site. This variation of free energy with modifier speciation is responsible for the so-called mixed network former effect i.e. the nonlinear scaling of property values in glasses having fixed modifier concentration but a varying ratio of network formers. In this paper a general theoretical framework is presented describing the statistical mechanics of modifier speciation in mixed network glasses. The model provides a natural explanation for the mixed network former effect and also accounts for the impact of thermal history and relaxation on glass network topology.

John C. Mauro

2013-01-01T23:59:59.000Z

283

Analytical Plan for Roman Glasses  

SciTech Connect

Roman glasses that have been in the sea or underground for about 1800 years can serve as the independent experiment that is needed for validation of codes and models that are used in performance assessment. Two sets of Roman-era glasses have been obtained for this purpose. One set comes from the sunken vessel the Iulia Felix; the second from recently excavated glasses from a Roman villa in Aquileia, Italy. The specimens contain glass artifacts and attached sediment or soil. In the case of the Iulia Felix glasses quite a lot of analytical work has been completed at the University of Padova, but from an archaeological perspective. The glasses from Aquileia have not been so carefully analyzed, but they are similar to other Roman glasses. Both glass and sediment or soil need to be analyzed and are the subject of this analytical plan. The glasses need to be analyzed with the goal of validating the model used to describe glass dissolution. The sediment and soil need to be analyzed to determine the profile of elements released from the glass. This latter need represents a significant analytical challenge because of the trace quantities that need to be analyzed. Both pieces of information will yield important information useful in the validation of the glass dissolution model and the chemical transport code(s) used to determine the migration of elements once released from the glass. In this plan, we outline the analytical techniques that should be useful in obtaining the needed information and suggest a useful starting point for this analytical effort.

Strachan, Denis M.; Buck, Edgar C.; Mueller, Karl T.; Schwantes, Jon M.; Olszta, Matthew J.; Thevuthasan, Suntharampillai; Heeren, Ronald M.

2011-01-01T23:59:59.000Z

284

Ising model of a glass transition  

Science Journals Connector (OSTI)

Numerical simulations by Tanaka and co-workers indicate that glass-forming systems of moderately polydisperse hard-core particles, in both two and three dimensions, exhibit diverging correlation lengths. These correlations are described by Ising-like critical exponents, and are associated with diverging, Vogel-Fulcher-Tamann, structural relaxation times. Related simulations of thermalized hard disks indicate that the curves of pressure versus packing fraction for different polydispersities exhibit a sequence of transition points, starting with a liquid-hexatic transition for the monodisperse case, and crossing over with increasing polydispersity to glassy, Ising-like critical points. I propose to explain these observations by assuming that glass-forming fluids contain twofold degenerate, locally ordered clusters of particles, similar to the two-state systems that have been invoked to explain other glassy phenomena. This paper starts with a brief statistical derivation of the thermodynamics of thermalized, hard-core particles. It then discusses how a two-state, Ising-like model can be described within that framework in terms of a small number of statistically relevant, internal state variables. The resulting theory agrees accurately with the simulation data. I also propose a rationale for the observed relation between the Ising-like correlation lengths and the Vogel-Fulcher-Tamann formula.

J. S. Langer

2013-07-17T23:59:59.000Z

285

Mixed polyanion glass cathodes: Iron phosphate vanadate glasses  

SciTech Connect

Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

2014-01-01T23:59:59.000Z

286

ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007  

Energy.gov (U.S. Department of Energy (DOE))

A guide to determining places in the glass-making process where energy can be saved and means by which energy can be saved.

287

Investigation of Performance of SCN-1 Pure Glass as Sealant Used in SOFC  

SciTech Connect

As its name implies, self-healing glass seal has the potential of restoring its mechanical properties upon being reheated to stack operating temperature, even when it has experienced some cooling induced damage/crack at room temperature. Such a self-healing feature is desirable for achieving high seal reliability during thermal cycling. On the other hand, self-healing glass is also characterized by its low mechanical stiffness and high creep rate at the typical operating temperature of SOFCs. Therefore, from a designs perspective, it is important to know the long term geometric stability and thermal mechanical behaviors of the self-healing glass under the stack operating conditions. These predictive capabilities will guide the design and optimization of a reliable sealing system that potentially utilizes self-healing glass as well as other ceramic seal components in achieving the ultimate goal of SOFC. In this report, we focused on predicting the effects of various generic seal design parameters on the stresses in the seal. For this purpose, we take the test cell used in the leakage test for compliant glass seals conducted in PNNL as our initial modeling geometry. The effect of the ceramic stopper on the geometry stability of the self-healing glass sealants is studied first. Then we explored the effect of various interfaces such as stopper and glass, stopper and PEN, as well stopper and IC plate, on the geometry stability and reliability of glass during the operating and cooling processes.

Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2010-03-01T23:59:59.000Z

288

WINDOW 5 Glass Library Update  

NLE Websites -- All DOE Office Websites (Extended Search)

WINDOW 6 or 7 Glass Library Update WINDOW 6 or 7 Glass Library Update Last update:12/09/13 07:26 PM Automatic IGDB Update Feature in WINDOW 6 and 7 The latest versions of WINDOW 6 and 7 have an automatic IGDB database update function in the Glass Library. When you first open the program, it checks to see if there is an IGDB version later than what you already have installed, and will notify you if there is an update. Then you can download and install the IGDB database, and click on the Update IGDB button in the Glass Library in order to start the automatic update. For older versions of WINDOW 6 and 7 without the automatic IGDB update function bullet How to Check the Current WINDOW5 IGDB Version bullet Updating the Glass Library bullet Problem Updating the Glass Library bullet Discontinued Records or Reused NFRC IDs

289

Quasicrystalline Approach to Prediting the Spinel-Nepheline Liquidus: Application to Nuclear Waste Glass Processing  

SciTech Connect

The crystal-melt equilibria in complex fifteen component melts are modeled based on quasicrystalline concepts. A pseudobinary phase diagram between acmite (which melts incongruently to a transition metal ferrite spinel) and nepheline is defined. The pseudobinary lies within the Al{sub 2}O{sub 3}-Fe{sub 2}O{sub 3}-Na{sub 2}O-SiO{sub 2} quaternary system that defines the crystallization of basalt glass melts. The pseudobinary provides the partitioning of species between the melt and the primary liquidus phases. The medium range order of the melt and the melt-crystal exchange equilibria are defined based on a constrained mathematical treatment that considers the crystallochemical coordination of the elemental species in acmite and nepheline. The liquidus phases that form are shown to be governed by the melt polymerization and the octahedral site preference energies. This quasicrystalline liquidus model has been used to prevent unwanted crystallization in the world's largest high level waste (HLW) melter for the past three years while allowing >10 wt% higher waste loadings to be processed.

Jantzen, Carol

2005-10-10T23:59:59.000Z

290

Cold Crucible Induction Melting Technology for Vitrification of High Level Waste: Development and Status in India  

SciTech Connect

Cold crucible induction melting is globally emerging as an alternative technology for the vitrification of high level radioactive waste. The new technology offers several advantages such as high temperature availability with long melter life, high waste loading, high specific capacity etc. Based on the laboratory and bench scale studies, an engineering scale cold crucible induction melter was locally developed in India. The melter was operated continuously to assess its performance. The electrical and thermal efficiencies were found to be in the range of 70-80 % and 10-20 % respectively. Glass melting capacities up to 200 kg m{sup -2} hr{sup -1} were accomplished using the ESCCIM. Industrially adaptable melter operating procedures for start-up, melting and pouring operations were established (author)

Sugilal, G.; Sengar, P.B.S. [Nuclear Recycle Group, Bhabha Atomic Research Centre, Trombay, Mumbai (India)

2008-07-01T23:59:59.000Z

291

Compositional threshold for Nuclear Waste Glass Durability  

SciTech Connect

Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

Kruger, Albert A. [Pacific Northwest National Lab., Richland, WA (United States); Farooqi, Rahmatullah [Pohang Univ. of Science and Technology, (Korea, Republic of); Hrma, Pavel R. [Pacific Northwest National Lab., Richland, WA (United States), Pohang Univ. of Science and Technology, (Korea, Republic of)

2013-04-24T23:59:59.000Z

292

The GLASS CHAIR Edited by Manuel Heitor  

E-Print Network (OSTI)

The GLASS CHAIR Edited by Manuel Heitor IST Press, 2000 #12;Collaborative Design of... The GLASS the glass chair, but also for the numerous discussions on glass production processes. And last · Carmo Valente Chapter 4. GLASS: BEAUTY WITH STRENGTH Sushil Kumar Mendiratta Chapter 5. The IDEA

Instituto de Sistemas e Robotica

293

Method for heating a glass sheet  

DOE Patents (OSTI)

A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed.

Boaz, Premakaran Tucker (Livonia, MI)

1998-01-01T23:59:59.000Z

294

Color Glass Condensate and Glasma  

E-Print Network (OSTI)

In this talk, I review the Color Glass Condensate theory of gluon saturation, and its application to the early stages of heavy ion collisions.

Francois Gelis

2010-09-01T23:59:59.000Z

295

Glass as a structural material.  

E-Print Network (OSTI)

??Glass can be beautiful and strong, so why is it not used more often as a structural material? Most often the reasoning is because people (more)

White, Rachel Lynn

2007-01-01T23:59:59.000Z

296

Insulation products promote thermal efficiency  

SciTech Connect

The judicious use of thermal insulation products in non-residential buildings can provide a number of advantages including increased energy efficiency, lower first costs (by avoiding overside HVAC systems), improved fire safety and better acoustics. Thermal insulation products are those products which retard the flow of heat energy. Materials include glass, plastics, and organic materials such as wood fibers, vermiculite and perlite. Forms range from the familiar batts and blankets of glass fibers to foamed plastic, rigid boards, losse fill and systems combining two or more products, such as polystyrene boards covered with insulating plaster. The R values of selected insulation materials with a cost/sq. ft. of each material at R 10 are given. Costs cover both the material and installation and may vary depending on local conditions.

Chalmers, R.

1985-04-01T23:59:59.000Z

297

Glass rupture disk  

DOE Patents (OSTI)

A frangible rupture disk and mounting apparatus for use in blocking fluid flow, generally in a fluid conducting conduit such as a well casing, a well tubing string or other conduits within subterranean boreholes. The disk can also be utilized in above-surface pipes or tanks where temporary and controllable fluid blockage is required. The frangible rupture disk is made from a pre-stressed glass with controllable rupture properties wherein the strength distribution has a standard deviation less than approximately 5% from the mean strength. The frangible rupture disk has controllable operating pressures and rupture pressures.

Glass, S. Jill (Albuquerque, NM); Nicolaysen, Scott D. (Albuquerque, NM); Beauchamp, Edwin K. (Albuquerque, NM)

2002-01-01T23:59:59.000Z

298

Thermal processing systems for TRU mixed waste  

SciTech Connect

This paper presents preliminary ex situ thermal processing system concepts and related processing considerations for remediation of transuranic (TRU)-contaminated wastes (TRUW) buried at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Anticipated waste stream components and problems are considered. Thermal processing conditions required to obtain a high-integrity, low-leachability glass/ceramic final waste form are considered. Five practical thermal process system designs are compared. Thermal processing of mixed waste and soils with essentially no presorting and using incineration followed by high temperature melting is recommended. Applied research and development necessary for demonstration is also recommended.

Eddy, T.L.; Raivo, B.D.; Anderson, G.L.

1992-01-01T23:59:59.000Z

299

Thermal processing systems for TRU mixed waste  

SciTech Connect

This paper presents preliminary ex situ thermal processing system concepts and related processing considerations for remediation of transuranic (TRU)-contaminated wastes (TRUW) buried at the Radioactive Waste Management Complex (RWMC) of the Idaho National Engineering Laboratory (INEL). Anticipated waste stream components and problems are considered. Thermal processing conditions required to obtain a high-integrity, low-leachability glass/ceramic final waste form are considered. Five practical thermal process system designs are compared. Thermal processing of mixed waste and soils with essentially no presorting and using incineration followed by high temperature melting is recommended. Applied research and development necessary for demonstration is also recommended.

Eddy, T.L.; Raivo, B.D.; Anderson, G.L.

1992-08-01T23:59:59.000Z

300

Efficient Breach Theory Through the Looking Glass  

E-Print Network (OSTI)

in Wonderland and Through the Looking Glass (Signet 1960).Theory Through the Looking Glass such an award a put by theTheory Through the Looking Glass Consider also the hoary

Adler, Barry E.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Immobilization of Chloroperoxidase on Aminopropyl-Glass  

Science Journals Connector (OSTI)

...Immobilization of Chloroperoxidase on Aminopropyl-Glass Tenshuk A. Kadima Michael A. Pickard...89362 was covalently bound to aminopropyl-glass by using a modification of an established method. Acid-washed glass was derivatized by using aminopropyltriethoxysilane...

Tenshuk A. Kadima; Michael A. Pickard

1990-11-01T23:59:59.000Z

302

Glass Fibre Reinforced Cement and Gypsum Products  

Science Journals Connector (OSTI)

6 October 1970 research-article Glass Fibre Reinforced Cement and Gypsum Products A. J. Majumdar Glass fibre reinforced cements and gypsum plaster...discontinuous and irregular. The dispersion of glass fibre in the matrix is not easy. When chopped...

1970-01-01T23:59:59.000Z

303

Rhenium solubility in borosilicate nuclear waste glass  

E-Print Network (OSTI)

Retention in Hanford LAW Glass - Phase 1 Final Report. VSL-rhenium in borosilicate waste glass as determined by X-rayfor NIST SRM 610617 Glasses Following ISO Guidelines," 35[

McCloy, John S.

2014-01-01T23:59:59.000Z

304

Crystal structure of Sr-akermanite glassceramics  

Science Journals Connector (OSTI)

A glassceramic of Sr-akermanite (Sr2MgSi2O7, SG: P 4 2 1 m ) was prepared by crystallization of a glass with composition of 2SrOMgO3SiO2. Parameters of the crystal structure were refined by Rietveld method. The analysis of the experimental results showed the following: the unit cell of Sr-akermanite in the glassceramic is larger than in single crystal. The thermal expansion coefficients of Sr-akermanite, calculated from the lattice constants obtained from X-ray diffractograms at high temperatures, were ?a=3.663נ10?6K?1 and ?c=6.666נ10?6K?1. It is suggested that the atomic displacements from the atomic coordination in single crystal depend on the stress developed during the crystallization process and the thermal contraction stress developed during cooling. Both types of stresses are related to the presence of residual glass and should be responsible for the expansion of the crystal lattice.

Yasuo Ochi

2006-01-01T23:59:59.000Z

305

Crystal structure of Sr-akermanite glass-ceramics  

SciTech Connect

A glass-ceramic of Sr-akermanite (Sr{sub 2}MgSi{sub 2}O{sub 7}, SG: P4-bar 2{sub 1}m) was prepared by crystallization of a glass with composition of 2SrO?MgO?3SiO{sub 2}. Parameters of the crystal structure were refined by Rietveld method. The analysis of the experimental results showed the following: the unit cell of Sr-akermanite in the glass-ceramic is larger than in single crystal. The thermal expansion coefficients of Sr-akermanite, calculated from the lattice constants obtained from X-ray diffractograms at high temperatures, were {alpha}{sub a}=3.663x10{sup -6}K{sup -1} and {alpha}{sub c}=6.666x10{sup -6}K{sup -1}. It is suggested that the atomic displacements from the atomic coordination in single crystal depend on the stress developed during the crystallization process and the thermal contraction stress developed during cooling. Both types of stresses are related to the presence of residual glass and should be responsible for the expansion of the crystal lattice.

Ochi, Yasuo [Research and Development Division, Ohara Incorporated Company, Naka 2-22-28, Kunitachi, Tokyo (Japan)]. E-mail: yasuo_ochi@ybb.ne.jp

2006-10-12T23:59:59.000Z

306

Art and Form in Glass  

Science Journals Connector (OSTI)

... book. The new edition has been brought up to date, the historical section on glass manufacture now concludes with a brief reference to the float process first announced a year ... a year or so ago and the beautiful collection of photographs illustrating the use of glass in buildings has been changed considerably. Many of the photographs are of things which ...

R. W. DOUGLAS

1962-03-24T23:59:59.000Z

307

New Types of Optical Glass  

Science Journals Connector (OSTI)

... IN view of the interest shown in new optical glasses recently produced in Great Britain and in the United States, we wish to summarize ... probable lines of development. Advances in lens design have led to a demand for new glasses with optical properties different from those available hitherto as outlined in a recent paper by ...

W. M. HAMPTON; R. E. BASTICK; W. N. WHEAT

1944-03-04T23:59:59.000Z

308

Structure and Density of Glass  

Science Journals Connector (OSTI)

... SiO2-B2O3 mixed glasses show a linear relation between v and R, which is the number of oxygen ... where the chemical symbols stand for the gram atoms present in a given quantity of glass (for example, 100 gm.) of the respective elements. For SiO2-B2O 3- ...

I. NRAY-SZAB

1958-01-04T23:59:59.000Z

309

Glass-making in England  

Science Journals Connector (OSTI)

... trouble to look through a catalogue of works in English dealing with the subject of glass will be struck with its poverty. For the most part, books on ... will be struck with its poverty. For the most part, books on glass have been written by collectors and admirers of ...

W. E. S. TURNER

1923-10-27T23:59:59.000Z

310

Formation of zirconium metallic glass  

Science Journals Connector (OSTI)

... Bulk metallic glasses are commonly produced by the rapid cooling of liquid alloys. They have emerged over ... a novel class of materials, with attractive properties and technological promise. The bulk metallic glasses so far produced contain three or more component elements. These complex compositions are necessary ...

Jianzhong Zhang; Yusheng Zhao

2004-07-15T23:59:59.000Z

311

Third International Congress on Glass  

Science Journals Connector (OSTI)

... THE Third International Congress on Glass was held in Venice during June 29-July 2, associated with the International Commission ... was held in Venice during June 29-July 2, associated with the International Commission on Glass, the annual meeting of which was held on July 3. 179 delegates attended from ...

1953-08-15T23:59:59.000Z

312

Sintering behavior of lanthanide-containing glass-ceramic sealants for solid oxide fuel cells  

SciTech Connect

This article reports on the influence of different lanthanides (La, Nd, Gd and Yb) on sintering behavior of alkaline-earth aluminosilicate glass-ceramics sealants for their application in solid oxide fuel cells (SOFC). All the glasses have been prepared by melt-quench technique. The in situ follow up of sintering behavior of glass powders has been done by high temperature - environmental scanning electron microscope (HT-ESEM) and hot-stage microscope (HSM) while the crystalline phase evolution and assemblage has been analyzed by x-ray diffraction (XRD) and scanning electron microscopy (SEM). All the glass compositions exhibit a glass-in-glass phase separation followed by two stage sintering resulting in well sintered glass powder compacts after heat treatment at 850 C for 1 h. Diopside (CaMgSi{sub 2}O{sub 6}) based phases constituted the major crystalline part in glass-ceramics followed by some minor phases. The increase in lanthanide content in glasses suppressed their tendency towards devitrification, thus, resulting in glass-ceramics with high amount of residual glassy phase (50-96 wt.%) which is expected to facilitate their self-healing behavior during SOFC operation. The electrical conductivity of the investigated glass-ceramics varied between (1.19 and 7.33) x 10{sup -7} S cm{sup -1} (750-800 C), and depended on the ionic field strength of lanthanide cations. Further experimentation with respect to the long term thermal and chemical stability of residual glassy phase under SOFC operation conditions along with high temperature viscosity measurements will be required in order to elucidate the potential of these glass-ceramics as self-healing sealants.

Goel, Ashutosh; Reddy, Allu Amarnath; Pascual, Maria J.; Gremillard, Laurent; Malchere, Annie; Ferreira, Jose M.

2012-05-01T23:59:59.000Z

313

Rhenium solubility in borosilicate nuclear waste glass  

E-Print Network (OSTI)

Glasses Developed for Nuclear Waste Immobilization," 91[12],solubility in borosilicate nuclear waste glass Ashutoshfor the researchers in nuclear waste community around the

McCloy, John S.

2014-01-01T23:59:59.000Z

314

Nanophase Glass Ceramics for Capacitive Energy Storage.  

E-Print Network (OSTI)

??Glass ceramics are candidate dielectric materials for high energy storage capacitors. Since energy density depends primarily on dielectric permittivity and breakdown strength, glass ceramics with (more)

Rangarajan, Badri

2009-01-01T23:59:59.000Z

315

Aluminoborosilicate Waste Glass Dissolution under Alkaline Conditions...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aluminoborosilicate Waste Glass Dissolution under Alkaline Conditions at 40C: Implications for a Chemical Affinity-Based Aluminoborosilicate Waste Glass Dissolution under...

316

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Bioactive Glass Scaffolds for Bone Regeneration Print Wednesday, 28 September 2011 00:00 Natural materials are renowned for their...

317

Evaluation of the phosphorus concentration and its effect on viscous flow and reflow in phosphosilicate glass  

SciTech Connect

This study describes the use of x-ray fluorescence as an analytical tool for determining phosphorus concentration in phosphosilicate glass. By comparison with other available methods, we shall demonstrate that this direct measurement technique is accurate, simple, fast, reproducible, and nondestructive. With the use of this technique, flow and reflow profiles of phosphosilicate glass will be illustrated at different phosphorous concentrations and representative thermal cycles.

Levy, R.A.; McGahan, T.E.; Vincent, S.M.

1985-06-01T23:59:59.000Z

318

A modeling study on the thermomechanical behavior of glass-ceramic and self-healing glass seals at elevated temperatures  

SciTech Connect

Hermetic gas seals are critical components for planar solid oxide fuel cells. This article focuses on comparative evaluation of a glass-ceramic developed by the Pacific Northwest National Laboratory (PNNL) and a self-healing glass seal developed by the University of Cincinnati. The stress and strain levels in the Positive electrode-Electrolyte-Negative electrode (PEN) seal in one cell stack are evaluated using a multi-physics simulation package developed at PNNL. Simulations were carried out with and without consideration of clamping force and stack body force, respectively. The results indicate that the overall stress and strain levels are dominated by the thermal expansion mismatches between the different cell components. Further, compared with glass-ceramic seal, the self-healing glass seal results in much lower steady state stress due to its much lower stiffness at the operating temperature of SOFC, and also exhibits much shorter relaxation times due to high creep rate. It is also noted that the self-healing glass seal will experience continuing creep deformation under the operating temperature of SOFC therefore resulting in possible overflow of the sealing materials. Further stopper material may need to be added to maintain its geometric stability during operation.

Govindaraju, Nirmal; Liu, Wenning N.; Sun, Xin; Singh, Prabhakar; Singh, R.

2009-05-15T23:59:59.000Z

319

On the mechanism of photoinduced refractive index changes in phosphosilicate glass  

SciTech Connect

The photoinduced growth of the refractive index of phosphosilicate glass during Bragg grating inscription and the thermal decay of the grating have a number of unusual features. The observed index variations are interpreted in terms of a new model for photoinduced glass network rearrangement. The model assumes the formation of photoinduced voids (nanopores) in the glass network near point defects. The nanopores may migrate through the network via bond switching when the network is in a 'soft' state. The photoinduced variations in network density lead to index variations. (fibres)

Larionov, Yu V [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Sokolov, V O; Plotnichenko, V G [Fiber Optics Research Center, Russian Academy of Sciences, Moscow (Russian Federation)

2010-05-26T23:59:59.000Z

320

Relaxation in the glass former acetylsalicylic acid studied by deuteron magnetic resonance and dielectric spectroscopy  

Science Journals Connector (OSTI)

Supercooled liquid and glassy acetylsalicylic acid was studied using dielectric spectroscopy and deuteron relaxometry in a wide temperature range. The supercooled liquid is characterized by major deviations from thermally activated behavior. In the glass the secondary relaxation exhibits the typical features of a Johari-Goldstein process. Via measurements of spin-lattice relaxation times the selectively deuterated methyl group was used as a sensitive probe of its local environments. There is a large difference in the mean activation energy in the glass with respect to that in crystalline acetylsalicylic acid. This can be understood by taking into account the broad energy barrier distribution in the glass.

R. Nath; T. El Goresy; B. Geil; H. Zimmermann; R. Bhmer

2006-08-09T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

A Topological Glass  

E-Print Network (OSTI)

We propose and study a model with glassy behavior. The state space of the model is given by all triangulations of a sphere with $n$ nodes, half of which are red and half are blue. Red nodes want to have 5 neighbors while blue ones want 7. Energies of nodes with different numbers of neighbors are supposed to be positive. The dynamics is that of flipping the diagonal of two adjacent triangles, with a temperature dependent probability. We show that this system has an approach to a steady state which is exponentially slow, and show that the stationary state is unordered. We also study the local energy landscape and show that it has the hierarchical structure known from spin glasses. Finally, we show that the evolution can be described as that of a rarefied gas with spontaneous generation of particles and annihilating collisions.

Jean-Pierre Eckmann

2007-04-07T23:59:59.000Z

322

Fracture mechanics of cellular glass  

SciTech Connect

Cellular glasses are prime candidate materials for the structural substrate of mirrored glass for solar concentrator reflecting panels. These materials are brittle, however, and susceptible to mechanical failure from slow crack growth caused by a stress corrosion mechanism. The results are detailed of one part of a program established to develop improved cellular glasses and to characterize the behavior of these and commercially available materials. Commercial and developmental cellular glasses were tested and analyzed using standard testing techniques and models developed from linear fracture mechanics. Two models describing the fracture behavior of these materials are developed. Slow crack growth behavior in cellular glass was found to be more complex than that encountered in dense glasses or ceramics. The crack velocity was found to be strongly dependent upon water vapor transport to the tip of the moving crack. The existence of a static fatigue limit was not conclusively established, however, it is speculated that slow crack growth behavior in Region I may be slower, by orders of magnitude, than that found in dense glasses.

Zwissler, J.G.; Adams, M.A.

1981-02-01T23:59:59.000Z

323

Quantum computing in a piece of glass  

E-Print Network (OSTI)

Quantum gates and simple quantum algorithms can be designed utilizing the diffraction phenomena of a photon within a multiplexed holographic element. The quantum eigenstates we use are the photon's linear momentum (LM) as measured by the number of waves of tilt across the aperture. Two properties of quantum computing within the circuit model make this approach attractive. First, any conditional measurement can be commuted in time with any unitary quantum gate - the timeless nature of quantum computing. Second, photon entanglement can be encoded as a superposition state of a single photon in a higher-dimensional state space afforded by LM. Our theoretical and numerical results indicate that OptiGrate's photo-thermal refractive (PTR) glass is an enabling technology. We will review our previous design of a quantum projection operator and give credence to this approach on a representative quantum gate grounded on coupled-mode theory and numerical simulations, all with parameters consistent with PTR glass. We discuss the strengths (high efficiencies, robustness to environment) and limitations (scalability, crosstalk) of this technology. While not scalable, the utility and robustness of such optical elements for broader quantum information processing applications can be substantial.

Warner A. Miller; Grigoriy Kreymerman; Christopher Tison; Paul M. Alsing; Jonathan R. McDonald

2011-12-15T23:59:59.000Z

324

ITP Glass: Glass Industry of the Future: Energy and Environmental...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

fuel oil is used in the glass industry (less than 2 percent of total energy). Natural gas is usually the fuel of choice as it is cleaner and in some cases, more cost-effective,...

325

Eco-efficient waste glass recycling: Integrated waste management and green product development through LCA  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer A new eco-efficient recycling route for post-consumer waste glass was implemented. Black-Right-Pointing-Pointer Integrated waste management and industrial production are crucial to green products. Black-Right-Pointing-Pointer Most of the waste glass rejects are sent back to the glass industry. Black-Right-Pointing-Pointer Recovered co-products give more environmental gains than does avoided landfill. Black-Right-Pointing-Pointer Energy intensive recycling must be limited to waste that cannot be closed-loop recycled. - Abstract: As part of the EU Life + NOVEDI project, a new eco-efficient recycling route has been implemented to maximise resources and energy recovery from post-consumer waste glass, through integrated waste management and industrial production. Life cycle assessment (LCA) has been used to identify engineering solutions to sustainability during the development of green building products. The new process and the related LCA are framed within a meaningful case of industrial symbiosis, where multiple waste streams are utilised in a multi-output industrial process. The input is a mix of rejected waste glass from conventional container glass recycling and waste special glass such as monitor glass, bulbs and glass fibres. The green building product is a recycled foam glass (RFG) to be used in high efficiency thermally insulating and lightweight concrete. The environmental gains have been contrasted against induced impacts and improvements have been proposed. Recovered co-products, such as glass fragments/powders, plastics and metals, correspond to environmental gains that are higher than those related to landfill avoidance, whereas the latter is cancelled due to increased transportation distances. In accordance to an eco-efficiency principle, it has been highlighted that recourse to highly energy intensive recycling should be limited to waste that cannot be closed-loop recycled.

Blengini, Gian Andrea, E-mail: blengini@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); CNR-IGAG, Institute of Environmental Geology and Geo-Engineering, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Busto, Mirko, E-mail: mirko.busto@polito.it [DISPEA - Department of Production Systems and Business Economics, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fantoni, Moris, E-mail: moris.fantoni@polito.it [DITAG - Department of Land, Environment and Geo-Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy); Fino, Debora, E-mail: debora.fino@polito.it [DISMIC - Department of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Turin (Italy)

2012-05-15T23:59:59.000Z

326

Reinforced glass beamsReinforced glass beamsg Auteur Dr. Christian LOUTER 1  

E-Print Network (OSTI)

Reinforced glass beamsReinforced glass beamsg EDCE Auteur Dr. Christian LOUTER 1 ENAC/EDCE 2011In contemporary architecture glass is increasinglyIn contemporary architecture glass is increasingly applied for structural components such as beamsapplied for structural components such as beams. However glass

327

Microsoft PowerPoint - ORP Glass Effort TWC HAB  

NLE Websites -- All DOE Office Websites (Extended Search)

10 m 2 EnergySolutions M-Area Mixed Waste DM- 5000 5m 2 LAW Pilot DM-3300 3.3 m 2 Hanford HLW Pilot DM-1200 1.2 m 2 EnergySolutionsVSL Test Melters DM-100 0.11 m 2...

328

Microporous glasses for reverse osmosis  

Science Journals Connector (OSTI)

The preparation, heat-treatment and leaching of phase separable borosilicate glasses which are of interest as possible semipermeable membranes for reverse osmosis applications are described. It is shown that ... ...

P. W. McMillan; C. E. Matthews

1976-01-01T23:59:59.000Z

329

Mobile Window Thermal Test  

NLE Websites -- All DOE Office Websites (Extended Search)

Mobile Window Thermal Test (MoWiTT) Facility Mobile Window Thermal Test (MoWiTT) Facility winter.jpg (469135 bytes) The window has come a long way since the days when it was a single pane of glass in a wood frame. Low-emissivity windows were designed to help buildings retain some of the energy that would have leaked out of less efficient windows. Designing efficient window-and-frame systems is one strategy for reducing the energy use of buildings. But the net energy flowing through a window is a combination of temperature- driven thermal flows and transmission of incident solar energy, both of which vary with time. U-factor and solar heat gain coefficient (SHGC), the window properties that control these flows, depend partly on ambient conditions. Window energy flows can affect how much energy a building uses, depending on when the window flows are available to help meet other energy demands within the building, and when they are adverse, adding to building energy use. This leads to a second strategy for reducing building energy use: using the beneficial solar gain available through a window, either for winter heating or for daylighting, while minimizing adverse flows.

330

Viscosity Measurements in Molten Glass  

Science Journals Connector (OSTI)

The relations existing between viscosity determinations and the various stages of glass manufacture are pointed out and explained with reference to a typical viscosity?temperature curve. The rotation viscometer employed in making such determinations is described. Curves are shown for four representative types of glasses: a lead a lime a lead borosilicate and a hard borosilicate and the use to which such comparison curves may be put is indicated.

Howard R. Lillie

1932-01-01T23:59:59.000Z

331

Fabrication of glass microspheres with conducting surfaces  

DOE Patents (OSTI)

A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

Elsholz, William E. (Acampo, CA)

1984-01-01T23:59:59.000Z

332

Glass nanostructures fabricated by soft thermal nanoimprint C. Peroza,*)  

E-Print Network (OSTI)

reticulated films). Standard TNIL technology is based on the solidification of polymeric materials (resist to applications. Currently, most developments concerning such materials are focused on photo-sensitive resists these materials allow to obtain a completely inorganic highly resistant coating. The few previous papers treating

Paris-Sud XI, Université de

333

Assessing thermal comfort near glass facades with new tools  

E-Print Network (OSTI)

coatings provide very low SHGC values, other options ofnot improve a calculated SHGC coefficient for the systemfor a solar coating with SHGC = 0.33 If an exterior shade is

Hoffmann, Sabine; Jedek, Christoph; Arens, Edward

2012-01-01T23:59:59.000Z

334

The effect of regimes and methods of glass forming on the tin content in float glass  

Science Journals Connector (OSTI)

The dependence of the tin content in glass is derived as a function of the iron oxidecontent in the glass composition, regimes and methods of forming, ... The ways of reducing the tin content in glass in the cour...

V. I. Kondrashov; V. S. Bezlyudnaya; Yu. V. Zverev

335

Natural analogues of nuclear waste glass corrosion.  

SciTech Connect

This report reviews and summarizes studies performed to characterize the products and processes involved in the corrosion of natural glasses. Studies are also reviewed and evaluated on how well the corrosion of natural glasses in natural environments serves as an analogue for the corrosion of high-level radioactive waste glasses in an engineered geologic disposal system. A wide range of natural and experimental corrosion studies has been performed on three major groups of natural glasses: tektite, obsidian, and basalt. Studies of the corrosion of natural glass attempt to characterize both the nature of alteration products and the reaction kinetics. Information available on natural glass was then compared to corresponding information on the corrosion of nuclear waste glasses, specifically to resolve two key questions: (1) whether one or more natural glasses behave similarly to nuclear waste glasses in laboratory tests, and (2) how these similarities can be used to support projections of the long-term corrosion of nuclear waste glasses. The corrosion behavior of basaltic glasses was most similar to that of nuclear waste glasses, but the corrosion of tektite and obsidian glasses involves certain processes that also occur during the corrosion of nuclear waste glasses. The reactions and processes that control basalt glass dissolution are similar to those that are important in nuclear waste glass dissolution. The key reaction of the overall corrosion mechanism is network hydrolysis, which eventually breaks down the glass network structure that remains after the initial ion-exchange and diffusion processes. This review also highlights some unresolved issues related to the application of an analogue approach to predicting long-term behavior of nuclear waste glass corrosion, such as discrepancies between experimental and field-based estimates of kinetic parameters for basaltic glasses.

Abrajano, T.A. Jr.; Ebert, W.L.; Luo, J.S.

1999-01-06T23:59:59.000Z

336

Elaboration And Characterization Of Foam Glass Based On Cullet With Addition Of Soluble Silicates  

SciTech Connect

The politics of the energy saving and of the acoustic comfort buildings is at the heart of the research of new compounds permitting to improve the materials performance actually commercialised. With this aim in view, we'll purpose to elaborate a porous material (foam glass) with addition of soluble silicates (up to 40%) of which the principal material is the waste glass in order to recycle it and improving the present laws about the waste products in closed circuit: (Finished products (leftarrow) waste products (leftarrow) finished products). The investigations have shown that grinding waste glass to particle size less than 0.1 mm and adding 1% of Ca CO{sub 3} content provide production of material with the following properties: particle density 0,5 g/cm{sup 3}, strength 17,50 MPa and water adsorption 95%, the temperature for foaming ranges were determined at 850 deg. C. The microstructures are homogenous, with pore sizes up to 2 mm. The addition of soluble silicates (up to 40%) has resulted in the foam glass of very high porosity. The foam glass is counted among the new glass products meeting certain requirements sought comfort in the building industry in particular (thermal and acoustic insulation). The product obtained present of excellent properties thermal ({lambda} = 0,031 W/m deg. C) and acoustic (R = 15 dB).

Ayadi, A.; Stiti, N.; Benhaoua, F.; Boumchedda, K.; Lerari, Y. [Laboratory of mineral materials and composite, Faculty of Engineering Sciences, University of Boumerdes (Algeria)

2011-01-17T23:59:59.000Z

337

Breaking Through the Glass Ceiling: Recent Experimental Approaches...  

NLE Websites -- All DOE Office Websites (Extended Search)

Through the Glass Ceiling: Recent Experimental Approaches to Probe the Properties of Supercooled Liquids near the Glass Breaking Through the Glass Ceiling: Recent Experimental...

338

A radiochemical study of the mechanism of polishing glass.  

E-Print Network (OSTI)

??In an effort to determine whether glass flows when polished uranium glasses were fused to non uranium glasses and polishings carried out in a direction (more)

Smith, John Graham

2012-01-01T23:59:59.000Z

339

Nano-structured self-cleaning superhydrophobic glass  

E-Print Network (OSTI)

5. Optically transparent glass with vertically alignedcomposition of biosoluble glass fiber Korean ApplicationS. Jin, Optically Transparent Glass with Vertically Aligned

Kim, Jin Yeol

2010-01-01T23:59:59.000Z

340

Preliminary Simulation of the Corrosion Rate of Archaeological Glass  

E-Print Network (OSTI)

to a fractured Roman glass. Geochimica et Cosmochimica Acta,Santarini (2008). SON68 nuclear glass dissolution kinetics:B. (2006). Nuclear waste glasses How durable? Elements, 2,

Steefel, Carl

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Small Glass-Melting Furnaces for Clear, Tinted, and Specialized Glass  

Science Journals Connector (OSTI)

Data on the design and application areas of small-sized glass-melting furnaces for melting various-purpose glasses are supplied.

A. A. Dymov; V. A. Fedorova

2000-07-01T23:59:59.000Z

342

Multiple reentrant glass transitions in confined hard-sphere glasses  

E-Print Network (OSTI)

Glass forming liquids exhibit a rich phenomenology upon confinement. This is often related to the effects arising from wall-fluid interactions. Here we focus on the interesting limit where the separation of the confining walls becomes of the order of a few particle diameters. For a moderately polydisperse, densely packed hard-sphere fluid confined between two smooth hard walls, we show via event-driven molecular dynamics simulations the emergence of a multiple reentrant glass transition scenario upon a variation of the wall separation. Using thermodynamic relations, this reentrant phenomenon is shown to persist also under constant chemical potential. This allows straightforward experimental investigation and opens the way to a variety of applications in micro- and nanotechnology, where channel dimensions are comparable to the size of the contained particles. The results are in-line with theoretical predictions obtained by a combination of density functional theory and the mode-coupling theory of the glass transition.

S. Mandal; S. Lang; M. Gross; M. Oettel; D. Raabe; T. Franosch; F. Varnik

2014-06-20T23:59:59.000Z

343

Glass-ceramic material and method of making  

DOE Patents (OSTI)

The present invention is a glass-ceramic material and method of making useful for joining at least two solid ceramic parts. The seal is a blend of M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 system can be used to join or seal both tubular and planar ceramic solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

Meinhardt, Kerry D [Richland, WA; Vienna, John D [West Richland, WA; Armstrong, Timothy R [Pasco, WA; Pederson, Larry R [Kennewick, WA

2002-08-13T23:59:59.000Z

344

First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses  

SciTech Connect

A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0[sub 2],B[sub 2]O[sub 3],A1[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O,Li[sub 2]O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

1993-01-01T23:59:59.000Z

345

First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses  

SciTech Connect

A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0{sub 2},B{sub 2}O{sub 3},A1{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O,Li{sub 2}O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

1993-01-01T23:59:59.000Z

346

Soft magnetic composites manufactured by warm co-extrusion of bulk metallic glass and steel powders  

SciTech Connect

Soft magnetic composites of Fe-based bulk metallic glass and low-alloy steel have been manufactured by warm co-extrusion of precursor powders at temperatures within the supercooled liquid region of the glass. Composites were manufactured with amorphous volume fractions of 75%, 67%, and 100%. Full consolidation of the constituent powders was observed with the bulk metallic glass remaining substantially amorphous. The composite electrical resistivity was observed to be anisotropic with a resistivity of 79 {mu}{Omega} cm measured transverse to the extrusion axis in a sample with 75% amorphous volume fraction. A 0-3 connectivity pattern with the low-resistivity steel phase embedded in a 3-dimensionally connected high-resistivity bulk metallic glass phase was observed with scanning electron microscopy. This confirms that the flow characteristics of the bulk metallic glass and the steel powders were comparable during extrusion at these temperatures. The saturation magnetization of 1.3 T was consistent with the volume weighted average of the saturation magnetization of the two phases. A relatively high quasistatic coercivity of 8 Oe was measured and is likely due to slight crystallization of the bulk metallic glass as well as domain wall pinning at prior particle boundaries. Careful control of the thermal environment during the extrusion process is required to minimize glass crystallization and achieve the desired balance of magnetic and electrical properties.

Johnson, Francis; Raber, Thomas R.; Zabala, Robert J.; Buresh, Steve J.; Tanico, Brian [GE Global Research, Ceramic and Metallurgy Technologies, One Research Circle, Niskayuna, New York 12309 (United States)

2013-05-07T23:59:59.000Z

347

Multi-phase glass-ceramics as a waste form for combined fission products: alkalis, alkaline earths, lanthanides, and transition metals  

SciTech Connect

In this study, multi-phase silicate-based glass-ceramics were investigated as an alternate waste form for immobilizing non-fissionable products from used nuclear fuel. Currently, borosilicate glass is the waste form selected for immobilization of this waste stream, however, the low thermal stability and solubility of MoO{sub 3} in borosilicate glass translates into a maximum waste loading in the range of 15-20 mass%. Glass-ceramics provide the opportunity to target durable crystalline phases, e.g., powellite, oxyapatite, celsian, and pollucite, that will incorporate MoO{sub 3} as well as other waste components such as lanthanides, alkalis, and alkaline earths at levels 2X the solubility limits of a single-phase glass. In addition a glass-ceramic could provide higher thermal stability, depending upon the properties of the crystalline and amorphous phases. Glass-ceramics were successfully synthesized at waste loadings of 42, 45, and 50 mass% with the following glass additives: B{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, CaO and SiO{sub 2} by slow cooling form from a glass melt. Glass-ceramics were characterized in terms of phase assemblage, morphology, and thermal stability. The targeted phases: powellite and oxyapatite were observed in all of the compositions along with a lanthanide borosilicate, and cerianite. Results of this initial investigation of glass-ceramics show promise as a potential waste form to replace single-phase borosilicate glass.

Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna

2012-04-01T23:59:59.000Z

348

Testing the physics of heat conduction using high pressure: crystals, glasses, and interfaces  

E-Print Network (OSTI)

, simplest case of thermal conductivity where resistive scattering dominates C() v() l() d C() = heatTesting the physics of heat conduction using high pressure: crystals, glasses, and interfaces David supported by CDAC and AFOSR #12;The story... · Use high pressure (gem anvil cells) to modify vibrational

Braun, Paul

349

Polypropylene/Glass Fiber Hierarchical Composites Incorporating Inorganic Fullerene-like Nanoparticles for Advanced Technological Applications  

Science Journals Connector (OSTI)

In particular, the incorporation of nanoclays to GFRPs has been reported to improve significantly the heat distortion temperature, flexural and impact strengths. ... Enhanced mech., thermal and vibration properties were obsd. in nanoclay dispersed composites over vinyl ester-glass fiber composite. ...

Ana M. Dez-Pascual; Mohammed Naffakh

2013-09-09T23:59:59.000Z

350

Glass Transition in Confined Geometry  

E-Print Network (OSTI)

Extending mode-coupling theory, we elaborate a microscopic theory for the glass transition of liquids confined between two parallel flat hard walls. The theory contains the standard MCT equations in bulk and in two dimensions as limiting cases and requires as input solely the equilibrium density profile and the structure factors of the fluid in confinement. We evaluate the phase diagram as a function of the distance of the plates for the case of a hard sphere fluid and obtain an oscillatory behavior of the glass transtion line as a result of the structural changes related to layering.

Simon Lang; Vitalie Botan; Martin Oettel; David Hajnal; Thomas Franosch; Rolf Schilling

2010-08-23T23:59:59.000Z

351

Inelastic Neutron Scattering from Glass Formers  

Science Journals Connector (OSTI)

......research-article Articles Inelastic Neutron Scattering from Glass Formers U. Buchenau...transition. Coherent inelastic neutron scattering data indicate a mixture of...Supplement No. 126, 1997 Inelastic Neutron Scattering from Glass Formers U. BUCHENAU......

U. Buchenau

1997-01-01T23:59:59.000Z

352

Structure glass technology : systems and applications  

E-Print Network (OSTI)

Glass cannot compete with steel in terms of strength or durability, but it is the only structural material that offers the highly sought after qualities of translucency and transparency. The use of glass has evolved from ...

Leitch, Katherine K. (Katherine Kristen)

2005-01-01T23:59:59.000Z

353

The Conservation of Seventeenth Century Archaeological Glass  

E-Print Network (OSTI)

is the only chance for the objects survival. Though glass is considered one of the most stable archaeological materials, noninvasive, reversible treatments are not always possible given the level of deterioration glass objects undergo within the archaeological...

Arcak, Cory

2010-10-12T23:59:59.000Z

354

Glass Transition and the Coulomb Gap in Electron Glasses M. Muller and L. B. Ioffe  

E-Print Network (OSTI)

Glass Transition and the Coulomb Gap in Electron Glasses M. Mu¨ller and L. B. Ioffe Department December 2004) We establish the connection between the presence of a glass phase and the appearance correlations in a systematic way, we show that in the case of strong disorder a continuous glass transition

Müller, Markus

355

Heating-induced glass-glass and glass-liquid transformations in computer simulations of water  

SciTech Connect

Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T phase diagram for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

2014-03-21T23:59:59.000Z

356

Classification of oxide glasses: A polarizability approach  

SciTech Connect

A classification of binary oxide glasses has been proposed taking into account the values obtained on their refractive index-based oxide ion polarizability {alpha}{sub O2-}(n{sub 0}), optical basicity {lambda}(n{sub 0}), metallization criterion M(n{sub 0}), interaction parameter A(n{sub 0}), and ion's effective charges as well as O1s and metal binding energies determined by XPS. Four groups of oxide glasses have been established: glasses formed by two glass-forming acidic oxides; glasses formed by glass-forming acidic oxide and modifier's basic oxide; glasses formed by glass-forming acidic and conditional glass-forming basic oxide; glasses formed by two basic oxides. The role of electronic ion polarizability in chemical bonding of oxide glasses has been also estimated. Good agreement has been found with the previous results concerning classification of simple oxides. The results obtained probably provide good basis for prediction of type of bonding in oxide glasses on the basis of refractive index as well as for prediction of new nonlinear optical materials.

Dimitrov, Vesselin [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki [Department of Chemistry, The Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka-shi, Niigata-ken 940-2188 (Japan)]. E-mail: komatsu@chem.nagaokaut.ac.jp

2005-03-15T23:59:59.000Z

357

Glass Fibres for Cement Reinforcement [and Discussion  

Science Journals Connector (OSTI)

21 January 1980 research-article Glass Fibres for Cement Reinforcement [and Discussion...Ubbelohde G. Manfre The development of glass fibre compositions having sufficient alkali...resistance were used in an initial evaluation of glass compositions, which were then further...

1980-01-01T23:59:59.000Z

358

On the Strength and Structure of Glass  

Science Journals Connector (OSTI)

...research-article On the Strength and Structure of Glass J. E. Gordon D. M. Marsh Margaret E. M. L. Parratt The strength of glass is known to be very variable and also...been revealed on the surface of drawn glasses. These crack systems are correlated...

1959-01-01T23:59:59.000Z

359

Monte Carlo Simulation of Isopentane Glass  

Science Journals Connector (OSTI)

...research-article Monte Carlo Simulation of Isopentane Glass S. Yashonath C. N. R. Rao Monte Carlo...quenching the liquid, we have obtained the glass-transition temperature from the temperature...distribution functions suggest a structure of the glass primarily influenced by geometrical factors...

1985-01-01T23:59:59.000Z

360

Identifying the Bose glass phase  

E-Print Network (OSTI)

Introducing disorder into the Bose-Hubbard model at integer fillings leads to a Bose glass phase, along with the Mott insulator and superfluid phases. We suggest a new order parameter: the determinant of the one body density matrix, which is nonzero only within the Mott-insulator phase. Alongside the superfluid fraction, it is then possible to distinguish the three phases. The Bose glass phase is the only phase which has vanishing determinant and superfluid fraction. The vanishing of the determinant in the Bose glass phase occurs due to the partial fragmentation of the condensate into localized fragments, each with zero superfluid response, which implies the presence of unoccupied sites and hence the presence of lines of zeros in the one body density matrix. In the superfluid phase, the determinant vanish for another reason - due to the macroscopic occupation of a single particle state. Finally, we suggest the enhancement of the three body decay rate in the Bose glass phase, as an experimental indicator for the presence of localized fragments.

R. Pugatch; N. Bar-gill; N. Katz; E. Rowen; N. Davidson

2006-07-28T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Thermal treatment  

Science Journals Connector (OSTI)

Thermal treatment can be regarded as either a pre-treatment of waste prior to final disposal, or as a means of valorising waste by recovering energy. It includes both the burning of mixed MSW in municipal inciner...

Dr. P. White; Dr. M. Franke; P. Hindle

1995-01-01T23:59:59.000Z

362

Thermal Processes  

Energy.gov (U.S. Department of Energy (DOE))

Some thermal processes use the energy in various resources, such as natural gas, coal, or biomass, to release hydrogen, which is part of their molecular structure. In other processes, heat, in...

363

Smart Thermal Skins for Vehicles  

NLE Websites -- All DOE Office Websites (Extended Search)

8 8 Smart Thermal Skins for Vehicles With a modest effort, many of the energy-efficient technologies developed for buildings can be transferred to the transportation sector. The goal of vehicle thermal management research at LBL is to save the energy equivalent of one to two billion gallons of gasoline per year, and improve the marketability of next-generation vehicles using advanced solar control glazings and insulating shell components to reduce accessory loads. Spectrally selective and electrochromic window glass and lightweight insulating materials improve the fuel efficiency of conventional and hybrid vehicles and extend the range of electric vehicles by reducing the need for air conditioning and heating, and by allowing the downsizing of equipment.

364

Fiber optic thermal/fast neutron and gamma ray scintillation detector  

DOE Patents (OSTI)

A system for detecting fissile and fissionable material originating external to the system includes: a .sup.6Li loaded glass fiber scintillator for detecting thermal neutrons, x-rays and gamma rays; a fast scintillator for detecting fast neutrons, x-rays and gamma rays, the fast scintillator conjoined with the glass fiber scintillator such that the fast scintillator moderates fast neutrons prior to their detection as thermal neutrons by the glass fiber scintillator; and a coincidence detection system for processing the time distributions of arriving signals from the scintillators.

Neal, John S. (Knoxville, TN); Mihalczo, John T (Oak Ridge, TN)

2007-10-30T23:59:59.000Z

365

Extraction of Proteins Glass Bead Method For preparation of protein extracts, the glass bead method is preferred. Some researchers  

E-Print Network (OSTI)

Extraction of Proteins ­ Glass Bead Method For preparation of protein extracts, the glass bead. glass beads (106 micron glass bead, Sigma cat. No. G4649) 7. Tabletop centrifuge 8. Vortex 9 µl glass beads (106 micron glass beads, Sigma, cat. G4649). 8. Vortex at top speed for 5 minutes. 9

366

Durability of Silicate Glasses: An Historical Approach  

SciTech Connect

We present a short review of current theories of glass weathering, including glass dissolution, and hydrolysis of nuclear waste glasses, and leaching of historical glasses from an XAFS perspective. The results of various laboratory leaching experiments at different timescales (30 days to 12 years) are compared with results for historical glasses that were weathered by atmospheric gases and soil waters over 500 to 3000 years. Good agreement is found between laboratory experiments and slowly leached historical glasses, with a strong enrichment of metals at the water/gel interface. Depending on the nature of the transition elements originally dissolved in the melt, increasing elemental distributions are expected to increase with time for a given glass durability context.

Farges, Francois; /Museum Natl. Hist. Natur. /Stanford U., Geo. Environ. Sci.; Etcheverry, Marie-Pierre; /Marne la Vallee U.; Haddi, Amine; /Marne la Valle U.; Trocellier,; /Saclay; Curti, Enzo; /PSI, Villigen; Brown, Gordon E., Jr.; /SLAC, SSRL

2007-01-02T23:59:59.000Z

367

Glasses for solar energy conversion systems  

Science Journals Connector (OSTI)

Solar technologies are projected to increase tremendously over the next 10 years. Glasses are playing an important role as transparent materials of photovoltaic (PV) cells and concentrating solar power (CSP) systems. Glasses are materials of short energy payback time and environmental compatibility suitable for sustainable energy concepts. The paper reviews recent solar applications. Surface structuring and coating of glasses are shown to improve energy efficiency for solar conversion systems substantially. Encapsulated glass-to-glass PV modules and solar photocatalytic glass surfaces are identified as elements of a green architecture combining renewable power generating and destruction of air pollutants of urban environments. Emerging solar technologies for power generation, including transparent PV modules, solar chimney and thermoelectric systems may become significant areas of future solar glass applications.

J. Deubener; G. Helsch; A. Moiseev; H. Bornhft

2009-01-01T23:59:59.000Z

368

Calculating center-glass performance indices of windows  

SciTech Connect

Building envelope performance is strongly influenced by solar gain and heat transfer through windows. The majority of this energy gain or loss passes through the center-glass area of the glazing system. Various methods have been devised to calculate the corresponding center-glass performance indices. Solar heat gain coefficient (SHGC) and U-factor are the quantities most frequently sought. Hand calculations have given way to computer-based techniques. Computer simulation offers the opportunity to employ more detailed models plus the ability to model the large number of glazing systems made possible by design options, such as low-emissivity or solar-control coatings, selective glass tints, substitute fill gases, and glazing layers, that partially transmit longwave radiation. A new, more accurate method is presented in this paper for manipulating spectral optical data while calculating the energy related optical properties of glazing layers and glazing systems. The use of the same technique to track visible and ultraviolet radiation is also demonstrated. In addition, more refined methods are documented for calculating SHGC and U-factor while accounting for the thermal resistance of individual glazings.

Wright, J.L. [Univ. of Waterloo, Ontario (Canada). Dept. of Mechanical Engineering

1998-10-01T23:59:59.000Z

369

Probing the glass transition from structural and vibrational properties of zero-temperature glasses  

E-Print Network (OSTI)

We find that the density dependence of the glass transition temperature of Lennard-Jones (LJ) and Weeks-Chandler-Andersen (WCA) systems can be predicted from properties of the zero-temperature ($T=0$) glasses. Below a crossover density $\\rho_s$, LJ and WCA glasses show different structures, leading to different vibrational properties and consequently making LJ glasses more stable with higher glass transition temperatures than WCA ones. Above $\\rho_s$, structural and vibrational quantities of the $T=0$ glasses show scaling collapse. From scaling relations and dimensional analysis, we predict a density scaling of the glass transition temperature, in excellent agreement with simulation results. We also propose an empirical expression of the glass transition temperature using structural and vibrational properties of the $T=0$ glasses, which works well over a wide range of densities.

Lijin Wang; Ning Xu

2014-02-10T23:59:59.000Z

370

Evaluation of plasma melter technology for verification of high-sodium content low-level radioactive liquid wastes: Demonstration test No. 4 preliminary test report  

SciTech Connect

This document provides a preliminary report of plasma arc vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System Low-Level Waste (LLW) Vitrification Program. Phase I test conduct included 26 hours (24 hours steady state) of melting of simulated high-sodium low-level radioactive liquid waste. Average processing rate was 4.9 kg/min (peak rate 6.2 kg/min), producing 7330 kg glass product. Free-flowing glass pour point was 1250 C, and power input averaged 1530 kW(e), for a total energy consumption of 19,800 kJ/kg glass. Restart capability was demonstrated following a 40-min outage involving the scrubber liquor heat exchanger, and glass production was continued for another 2 hours. Some volatility losses were apparent, probably in the form of sodium borates. Roughly 275 samples were collected and forwarded for analysis. Sufficient process data were collected for heat/material balances. Recommendations for future work include lower boron contents and improved tuyere design/operation.

McLaughlin, D.F.; Gass, W.R.; Dighe, S.V.; D`Amico, N.; Swensrud, R.L.; Darr, M.F.

1995-01-10T23:59:59.000Z

371

Method for heating, forming and tempering a glass sheet  

DOE Patents (OSTI)

A method for heating, forming and tempering a glass sheet including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet.

Boaz, Premakaran Tucker (Livonia, MI); Sitzman, Gary W. (Walled Lake, MI)

1998-01-01T23:59:59.000Z

372

Reactive cluster model of metallic glasses  

SciTech Connect

Though discovered more than a half century ago metallic glasses remain a scientific enigma. Unlike crystalline metals, characterized by short, medium, and long-range order, in metallic glasses short and medium-range order persist, though long-range order is absent. This fact has prompted research to develop structural descriptions of metallic glasses. Among these are cluster-based models that attribute amorphous structure to the existence of clusters that are incommensurate with crystalline periodicity. Not addressed, however, are the chemical factors stabilizing these clusters and promoting their interconnections. We have found that glass formers are characterized by a rich cluster chemistry that above the glass transformation temperature promotes exchange as well as static and vibronic sharing of atoms between clusters. The vibronic mechanism induces correlated motions between neighboring clusters and we hypothesize that the distance over which these motions are correlated mediates metallic glass stability and influences critical cooling rates.

Jones, Travis E. [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States) [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States); School of Physics, The University of Sydney, Sydney, New South Wales 2006 (Australia); Miorelli, Jonathan; Eberhart, Mark E. [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States)] [Molecular Theory Group, Colorado School of Mines, Golden, Colorado 80401 (United States)

2014-02-28T23:59:59.000Z

373

Current status of the GLASS code  

SciTech Connect

This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970's. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

Hootman, H.E. (Westinghouse Savannah River Co., Aiken, SC (United States)); Honeck, H.C. (Computer Application Technology, Inc., Aiken, SC (United States))

1991-01-01T23:59:59.000Z

374

Current status of the GLASS code  

SciTech Connect

This paper summarizes the current status of the Generalized Lattice Analysis SubSystem (GLASS) computer code and its supporting cross section libraries. GLASS was developed at the Savannah River Site (SRS) in the early 1970`s. The GLASS code has been instrumental in supporting safe Heavy Water Reactor (HWR) operations and predicting material production at SRS for more than 20 years. The Department of Energy Office of New Production Reactors (ONPR) program has chosen to use the GLASS code for the design of the HWR option of the New Production Reactor (NPR). A substantial body of validation calculations have been performed and additional validation calculations will be performed to qualify the new GLASS multigroup cross section libraries derived from the ENDF/B-5 and 6 nuclear data files. Several improvements to the code are in progress. Many other improvements are planned to bring GLASS up to modern physics and compute technology.

Hootman, H.E. [Westinghouse Savannah River Co., Aiken, SC (United States); Honeck, H.C. [Computer Application Technology, Inc., Aiken, SC (United States)

1991-12-31T23:59:59.000Z

375

Glass Property Data and Models for Estimating High-Level Waste Glass Volume  

SciTech Connect

This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

2009-10-05T23:59:59.000Z

376

Preparation, properties and chemistry of glass- and glass-ceramic-to-metal seals and coatings  

Science Journals Connector (OSTI)

An overview is given outlining the materials and technologies that have been employed in the preparation of glass- and glass-ceramic-to-metal seals and coatings. Metal/non-metal bonding theories are summarized...

I. W. Donald

1993-06-01T23:59:59.000Z

377

68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 69 July 2003 Glass Technol., 2004, 45, 6870  

E-Print Network (OSTI)

68 Glass Technology Vol. 45 No. 2 April 2004 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Proc. VII Symp. on Crystallisation in Glasses and Liquids, Sheffield, 6­9 July 2003 Glass Technol., 2004, 45, 68­70 The behaviour of a simulant Magnox waste glass

Sheffield, University of

378

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network (OSTI)

using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"ings of Aquifer Thermal Energy Storage Workshop, Lawrence

Tsang, C.-F.

2011-01-01T23:59:59.000Z

379

Doping of Glass with Lithium Ion  

Science Journals Connector (OSTI)

Our discovery that the Li+ uptake by the glass walls of the vessels used in the experiments can be used for doping purposes was purely surreptitious. ...

Greg Moakes; Lawrence A. Bottomley; Jiri Janata

2005-01-12T23:59:59.000Z

380

Transparant ductility: Reinforcing a structural glass girder:.  

E-Print Network (OSTI)

??Transparency and light are hot items in building design and massive structural elements often form an unwelcome necessity for architects. The structural use of glass (more)

Rademakers, M.

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

120 Years of Optical Glass Science  

Science Journals Connector (OSTI)

An elegant, century-old mathematical relationship, tying the physical properties of a multicomponent glass to those of its chemical components, still provides a powerful tool...

Dragic, Peter D; Ballato, John

2014-01-01T23:59:59.000Z

382

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure....

383

DEFENSE HIGH LEVEL WASTE GLASS DEGRADATION  

SciTech Connect

The purpose of this Analysis/Model Report (AMR) is to document the analyses that were done to develop models for radionuclide release from high-level waste (HLW) glass dissolution that can be integrated into performance assessment (PA) calculations conducted to support site recommendation and license application for the Yucca Mountain site. This report was developed in accordance with the ''Technical Work Plan for Waste Form Degradation Process Model Report for SR'' (CRWMS M&O 2000a). It specifically addresses the item, ''Defense High Level Waste Glass Degradation'', of the product technical work plan. The AP-3.15Q Attachment 1 screening criteria determines the importance for its intended use of the HLW glass model derived herein to be in the category ''Other Factors for the Postclosure Safety Case-Waste Form Performance'', and thus indicates that this factor does not contribute significantly to the postclosure safety strategy. Because the release of radionuclides from the glass will depend on the prior dissolution of the glass, the dissolution rate of the glass imposes an upper bound on the radionuclide release rate. The approach taken to provide a bound for the radionuclide release is to develop models that can be used to calculate the dissolution rate of waste glass when contacted by water in the disposal site. The release rate of a particular radionuclide can then be calculated by multiplying the glass dissolution rate by the mass fraction of that radionuclide in the glass and by the surface area of glass contacted by water. The scope includes consideration of the three modes by which water may contact waste glass in the disposal system: contact by humid air, dripping water, and immersion. The models for glass dissolution under these contact modes are all based on the rate expression for aqueous dissolution of borosilicate glasses. The mechanism and rate expression for aqueous dissolution are adequately understood; the analyses in this AMR were conducted to provide models and parameter values that can be used to calculate the dissolution rates for the different modes of water contact. The analyses were conducted to identify key aspects of the mechanistic model for glass dissolution to be included in the abstracted models used for PA calculations, evaluate how the models can be used to calculate bounding values of the glass dissolution rates under anticipated water contact modes in the disposal. system, and determine model parameter values for the range of potential waste glass compositions and anticipated environmental conditions. The analysis of a bounding rate also considered the effects of the buildup of glass corrosion products in the solution contacting the glass and potential effects of alteration phase formation. Note that application of the models and model parameter values is constrained to the anticipated range of HLW glass compositions and environmental conditions. The effects of processes inherent to exposure to humid air and dripping water were not modeled explicitly. Instead, the impacts of these processes on the degradation rate were taken into account by using empirically measured parameter values. These include the rates at which water sorbs onto the glass, drips onto the glass, and drips off of the glass. The dissolution rates of glasses that were exposed to humid air and dripping water measured in laboratory tests are used to estimate model parameter values for contact by humid air and dripping water in the disposal system.

W. Ebert

2001-09-20T23:59:59.000Z

384

Copyright the Mathematical Association of America 2003. All rights reserved. Alice through Looking Glass after Looking Glass  

E-Print Network (OSTI)

Glass after Looking Glass: The Mathematics of Mirrors and Kaleidoscopes Roe Goodman 1. ALICE Alice book called Alice Through Looking Glass After Looking Glass. The book opens with Alice in her chamber in front of a peculiar cone­shaped arrangement of three looking glasses. She steps through one

Goodman, Roe

385

Silane Modification of Glass and Silica Surfaces to Obtain Equally...  

NLE Websites -- All DOE Office Websites (Extended Search)

Silane Modification of Glass and Silica Surfaces to Obtain Equally Oil-Wet Surfaces in Glass-Covered Silicon Micromodel Silane Modification of Glass and Silica Surfaces to Obtain...

386

Radiative Heat Transfer in Enhanced Hydrogen Outgassing of Glass  

E-Print Network (OSTI)

transport in a machinable glass-ceramic, Journal of Non-in soda-lime-silicate glasses by reaction with hydrogen,1971. [16] I. Fanderlik, Glass Science and Technology, Vol.

Kitamura, Rei; Pilon, Laurent

2009-01-01T23:59:59.000Z

387

The quantum Biroli-Mzard model: glass transition and superfluidity in a quantum lattice glass model  

E-Print Network (OSTI)

We study the quantum version of a lattice model whose classical counterpart captures the physics of structural glasses. We discuss the role of quantum fluctuations in such systems and in particular their interplay with the amorphous order developed in the glass phase. We show that quantum fluctuations might facilitate the formation of the glass at low enough temperature. We also show that the glass transition becomes a first-order transition between a superfluid and an insulating glass at very low temperature, and is therefore accompanied by phase coexistence between superfluid and glassy regions.

Laura Foini; Guilhem Semerjian; Francesco Zamponi

2010-11-29T23:59:59.000Z

388

Chapter Three - Material Selection for Thermal Insulation  

Science Journals Connector (OSTI)

Abstract This chapter covers the minimum requirements and fundamental concepts relating to the composition, size, dimensions, physical properties, inspection, packaging, and marking of a wide range of thermal insulations for use on pipe and equipment surfaces such as mineral wool insulation, rigid and semi-rigid mineral fiber block and board thermal insulation, mineral blanket and blanket-type pipe insulation, calcium silicate preformed block and pipe section thermal insulation, cellular glass, baked cork, and rigid cellular polyurethane and polyisocyanurate and filler insulation. In addition, vapor barriers, joint sealants, adhesive materials, metallic jacketing, and accessory materials are reviewed. For satisfactory performance, properly installed protective vapor barriers have to be used in low-temperature applications to prevent movement of moisture through or around the insulation towards the colder surface.

Alireza Bahadori

2014-01-01T23:59:59.000Z

389

Radioactive waste material melter apparatus  

DOE Patents (OSTI)

An apparatus for preparing metallic radioactive waste material for storage is disclosed. The radioactive waste material is placed in a radiation shielded enclosure. The waste material is then melted with a plasma torch and cast into a plurality of successive horizontal layers in a mold to form a radioactive ingot in the shape of a spent nuclear fuel rod storage canister. The apparatus comprises a radiation shielded enclosure having an opening adapted for receiving a conventional transfer cask within which radioactive waste material is transferred to the apparatus. A plasma torch is mounted within the enclosure. A mold is also received within the enclosure for receiving the melted waste material and cooling it to form an ingot. The enclosure is preferably constructed in at least two parts to enable easy transport of the apparatus from one nuclear site to another.

Newman, Darrell F. (Richland, WA); Ross, Wayne A. (Richland, WA)

1990-01-01T23:59:59.000Z

390

G-Plus report to Owens Corning-thermal conductivity Measurements of Fiberglass  

SciTech Connect

Fiberglass made by Owens Corning is being used in noise reduction of automobile exhaust system. Specifically, the glass fibers are packed inside the muffler to achieve the desired acoustic effect. A secondary benefit of the fibers is to serve as a thermal insulation. Because of this insulating property, the glass fibers can serve to reduce the temperature of the muffler shell. This in turn reduces the need for heat shields around mufflers and reduces the amount of exterior temperature accelerated corrosion of the muffler shell, especially in the winter ''salt belts'' where large amounts of salt are placed on highways to minimize the safety impact of snow and ice. In addition, for some applications the use of the fiberglass could allow the use of lighter weight carbon based polymer composite materials in place of steel for muffler shells. However, in order to properly design exhaust systems without heat shields or to take advantage of new materials, the thermal conductivity of the fiberglass material at operating temperatures (for some applications above 750 C) must be known. We selected two types of Owens Corning glass fibers, 17 {micro}m and 24 {micro}m in diameter, for this study. There are some room temperature thermal conductivity data for the fiberglass, but high temperature data are not available. Based on the thermal radiation model, thermal conductivity should increase rapidly at high temperature, providing less thermal insulation. In addition, thermal conductivity depends on packing density of the glass fibers. We will study the effect of packing density on thermal conductivity. Another issue is that the glass fiber conducts heat better along the fiber, while the conduction across the fibers is poor, because thermal conduction from one fiber to another has to go through an interface with thermal resistance. In fiberglass, most fibers are not in good contact with the surrounding fibers, thus, most heat transfer is dependent on the thermal radiation effect. Among the many methods of measuring thermal conductivity, only a few can be used for glass fibers. The traditional heat flow meter is used in testing thermal insulations near room temperature. At higher temperatures this method cannot be used due to material and instrument limitations. Our plan is to use a transient plane source (TPS) method to measure thermal conductivity directly. The advantage of the TPS method is that measurements can be taken at over 700 C, and covers the temperature of the automobile exhausts. The following is a report for the G-Plus project conducted at ORNL to apply the TPS method to characterizing the thermal conductivity of two types of fiberglass and also the effect of packing density.

Wang, H

2003-04-15T23:59:59.000Z

391

Method for heating and forming a glass sheet  

DOE Patents (OSTI)

A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration.

Boaz, Premakaran Tucker (Livonia, MI)

1997-01-01T23:59:59.000Z

392

Radiation Induced Nanocrystal Formation in Metallic Glasses  

E-Print Network (OSTI)

The irradiation of metallic glasses to induce nanocrystallization was studied in two metallic glass compositions, Cu50Zr45Ti5 and Zr55Cu30Al10Ni5. Atomic mobility was described using a model based on localized excess free volume due to displace...

Carter, Jesse

2010-01-14T23:59:59.000Z

393

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Glass compositions containing CaO, Al/sub 2/O/sub 3/, B/sub 2/O/sub 3/, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

Brow, R.K.; Watkins, R.D.

1988-01-21T23:59:59.000Z

394

Sealing glasses for titanium and titanium alloys  

DOE Patents (OSTI)

Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

Brow, Richard K. (Albuquerque, NM); Watkins, Randall D. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

395

Hydration Aging of Nuclear Waste Glass  

Science Journals Connector (OSTI)

...of Nuclear Waste Glass 10...STEINDLER Chemical Engineering...60439 The aging of simulated nuclear waste glass by...nuclear waste forms can meet...simulated aging reac-tions...whether a waste formn can...pro-jected Nuclear Regulatory...STEINDLEt Chemical Engineering...Basisfor Waste Form Integrity...

J. K. BATES; L. J. JARDINE; M. J. STEINDLER

1982-10-01T23:59:59.000Z

396

Viscous Glass Sealants for SOFC Applications  

SciTech Connect

Two series of silicate glasses that contain gallium as the primary critical component have been identified and optimized for viscous sealing of solid oxide fuel cells operating from 650 to 850°C. Both series of glass sealants crystallize partially upon heat treatment and yield multiphase microstructures that allow viscous flow at temperatures as low as 650°C. A fully amorphous sealant was also developed by isolating, synthesizing and testing a silicate glass of the same composition as the remnant glassy phase in one of the two glass series. Of ~40 glasses tested for longer than 500 hours, a set of 5 glasses has been further tested for up to 1000h in air, wet hydrogen, and against both yttria-stabilized zirconia and aluminized stainless steel. In some cases the testing times reached 2000h. The reactivity testing has provided new insight into the effects of Y, Zr, and Al on bulk and surface crystallization in boro-gallio-silicate glasses, and demonstrated that at least 5 of the newly-developed glasses are viable viscous sealants.

Scott Misture

2012-09-30T23:59:59.000Z

397

Vibration of Glasses containing Effervescing Liquids  

Science Journals Connector (OSTI)

... of the phenomena, he says:We must consider what passes in the communication of vibrations through the liquid from one side of the glass to the other. The glass ... it is clear, that if any considerable part of a system be unsusceptible of regular vibration, the whole must be so. The phenomenon, then, according to this explanation, ...

ALLEN BEAZELEY

1872-07-18T23:59:59.000Z

398

Materials science: To the heart of glass  

Science Journals Connector (OSTI)

... collaborate with archaeologists. One of the best disposal options is to trap the waste in glass and bury it. So when the civilizations of the Middle East first learnt how ... bury it. So when the civilizations of the Middle East first learnt how to make glass at least 4,500 years ago, they unwittingly launched an experiment on the long- ...

Philip Ball

2003-02-20T23:59:59.000Z

399

Manufacture of Sheet and Plate Glass  

Science Journals Connector (OSTI)

... lantern slides and films, the methods in use for the manufacture of sheet and plate glass. The principal raw materials used in the manu facture of sheet and plate ... . The principal raw materials used in the manu facture of sheet and plate glass are sand, soda ash and limestone. These materials, perhaps with the addition of ...

S. E.

1934-03-10T23:59:59.000Z

400

Origin of Libyan Desert Silica-Glass  

Science Journals Connector (OSTI)

... of germanium, using a modified method of Schneider and Sandell4, in Libyan Desert silica-glass, Libyan Desert sandstone, a Libyan Desert quartzite, two Libyan Desert sands, Aouelloul crater ... Desert sandstone, a Libyan Desert quartzite, two Libyan Desert sands, Aouelloul crater 'impactite' glass, two obsidians, the average for tektites from eleven different localities, including all known ...

ALVIN J. COHEN

1959-05-30T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

New Process of Making Plate Glass  

Science Journals Connector (OSTI)

... , Lancashire, have just announced the successful development of a new process of making plate glass. In the new process the plate ... . In the new process the plate glass is produced with a fire-polished finish, so that the lengthy grinding and polishing ...

1959-01-31T23:59:59.000Z

402

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bioactive Glass Scaffolds for Bone Regeneration Bioactive Glass Scaffolds for Bone Regeneration Print Wednesday, 28 September 2011 00:00 Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

403

Crystallization in heat-treated fluorochlorozirconate glasses  

SciTech Connect

Crystallization phenomena of fluorochlorozirconate glasses were investigated by means of differential scanning calorimetry and inelastic neutron scattering. The precipitation of barium chloride nanoparticles from the glass matrix upon heat treatment was found to be suppressed when re-melting the glass with a reducing agent but not if the agent was present in the initial synthesis. Addition of small amounts of oxide to the predominantly fluoride melt was found to maintain the presence of nanoparticles but not to induce the predicted phase transition of the barium chloride nanoparticles from hexagonal to orthorhombic structure. Inelastic neutron scattering performed on an as-made glass and a heat-treated glass showed an increase in hardness , consistent with a more ordered structure.

Johnson, Jackie A. [University of Tennessee Space Institute; Weber, Rick [Materials Development, Inc., Evanston, IL; Kolesnikov, Alexander I [ORNL; SCHWEIZER, Stefan [Fraunhofer Center for Silicon Photovoltaics, 06120 Halle, Germany

2009-01-01T23:59:59.000Z

404

Gaseous Sulfate Solubility in Glass: Experimental Method  

SciTech Connect

Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

Bliss, Mary

2013-11-30T23:59:59.000Z

405

Titanium sealing glasses and seals formed therefrom  

DOE Patents (OSTI)

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La{sub 2}O{sub 3}, B{sub 2}O{sub 3}, TiO{sub 2} and Al{sub 2}O{sub 3} in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 2 figs.

Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

1997-12-02T23:59:59.000Z

406

Titanium sealing glasses and seals formed therefrom  

DOE Patents (OSTI)

Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

Brow, Richard K. (Albuquerque, NM); McCollister, Howard L. (Albuquerque, NM); Phifer, Carol C. (Albuquerque, NM); Day, Delbert E. (Rolla, MO)

1997-01-01T23:59:59.000Z

407

Glass cullet as a new supplementary cementitious material (SCM).  

E-Print Network (OSTI)

??Finely ground glass has the potential for pozzolanic reactivity and can serve as a supplementary cementitious material (SCM). Glass reaction kinetics depends on both temperature (more)

Mirzahosseini, Mohammadreza

2014-01-01T23:59:59.000Z

408

Static Temperature Survey At Glass Buttes Area (DOE GTP) | Open...  

Open Energy Info (EERE)

Static Temperature Survey At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Static Temperature Survey At Glass...

409

Polyamorphism in a Metallic Glass | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

2000 | 1998 | Subscribe to APS Science Highlights rss feed Polyamorphism in a Metallic Glass MARCH 14, 2007 Bookmark and Share Structural modeling of the metallic glass: (a) A...

410

Waste Loading Enhancements for Hanford Low-Activity Waste Glasses  

NLE Websites -- All DOE Office Websites (Extended Search)

WASTE LOADING ENHANCEMENTS FOR HANFORD LOW-ACTIVITY WASTE GLASSES Albert A. Kruger, Glass Scientist DOE-WTP Project Office Engineering Division US Department of Energy Richland,...

411

Development Wells At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Development Wells At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Glass Buttes Area (DOE GTP)...

412

Pressure Temperature Log At Glass Buttes Area (DOE GTP) | Open...  

Open Energy Info (EERE)

Pressure Temperature Log At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Pressure Temperature Log At Glass Buttes...

413

Cuttings Analysis At Glass Buttes Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Cuttings Analysis At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At Glass Buttes Area (DOE GTP)...

414

Metal and Glass Manufacturers Reduce Costs by Increasing Energy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in Process Heating Systems Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in...

415

Breaking through the Glass Ceiling: The Correlation Between the...  

NLE Websites -- All DOE Office Websites (Extended Search)

through the Glass Ceiling: The Correlation Between the Self-Diffusivity in and Krypton Permeation through Deeply Breaking through the Glass Ceiling: The Correlation Between the...

416

Aligned Crystalline Semiconducting Film On A Glass Substrate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aligned Crystalline Semiconducting Film On A Glass Substrate Aligned Crystalline Semiconducting Film On A Glass Substrate And Method Of Making A semiconducting structure having a...

417

Asahi Glass Co Ltd AGC | Open Energy Information  

Open Energy Info (EERE)

Ltd AGC Jump to: navigation, search Name: Asahi Glass Co Ltd (AGC) Place: Tokyo, Tokyo, Japan Zip: 100-8405 Sector: Efficiency Product: Japanese glass manufacturer; produces cover...

418

Uv-Light Stabilization Additive Package For Solar Cell Module And Laminated Glass Applications  

DOE Patents (OSTI)

An ultraviolet light stabilization additive package is used in an encapsulant material that may be used in solar cell modules, laminated glass and a variety of other applications. The ultraviolet light stabilization additive package comprises a first hindered amine light stabilizer and a second hindered amine light stabilizer. The first hindered amine light stabilizer provides thermal oxidative stabilization, and the second hindered amine light stabilizer providing photo-oxidative stabilization.

Hanoka, Jack I. (Brookline, MA); Klemchuk, Peter P. (Watertown, CT)

2002-03-05T23:59:59.000Z

419

Heat transmission through a glass window with a curved venetian blind installed  

Science Journals Connector (OSTI)

Abstract This article reports a study on the effect of installing a curved venetian blind to a glass window on the solar heat transmission into the space. The mathematical model of the combined glass window and venetian blind is developed. Predicted results from the developed mathematical model are compared with the previous experimental ones to verify their accuracy. The variation of the solar heat gain coefficient (SHGC) with the related blind parameters (optical properties of venetian blind, slat spacing, distance between the blind and glass window, slat angle and solar profile angle) are studied. The variation of the SHGC in the shortwave part (ShW SHGC) and in the longwave part (LoW SHGC) with the related blind parameters are also studied. The understanding of their variation will provide the important information for the study of the thermal comfort for a person who stays near the glass window with blind. The SHGC can be further classified as the SHGC for direct solar radiation (SHGCD) and the SHGC for diffuse solar radiation (SHGCd). From the study it is found that installing a curved venetian blind to the glass window causes a significant reduction in solar heat gain compared to the plain glass window. The SHGCD, ShW SHGCD and LoW SHGCD are all dependent on the slat angle and solar profile angle. The slat reflectance of the venetian blind has direct effect on the ShW SHGCD. The slat absorptance of the venetian blind has direct effect on the LoW SHGCD. The glass window and blind with high slat reflectance gives a lower value of SHGCD compared to the glass window and blind with low slat reflectance. The slat curvature also affects the SHGCD of the fenestration system (glass window with blind installed). The slat with more curvature (lower value of slat radius of curvature) causes more reduction in the value of SHGCD compared to the slat with less curvature. The blind with lower slat spacing yields a lower value of SHGCD compared to the blind with higher slat spacing. The effects of slat emittance and distance between the blind and the glass window on the SHGC D of the fenestration system are only appeared on the LoW SHGCD and such effects are quite small.

Somsak Chaiyapinunt; Nopparat Khamporn

2014-01-01T23:59:59.000Z

420

Appraisal of thermal performance of a glazed office with a solar control coating: Cases in Mexico and Canada  

Science Journals Connector (OSTI)

The use of solar passive strategies such as new solar control coatings on windows for buildings with large glazed areas, have recently become important and helpful tools, mainly because these developments help to reduce heat gains and/or losses through transparent materials, diminishing energy loads, and improving the environment inside buildings. This paper shows an assessment of the thermal performance for an office on top of a building with four different configurations of window glass, and their influence on the indoor conditions. The window glass configurations are: clear glass, glass-film (SnSCuxS solar control coating), double-glass-film, and double clear glass. The simulations were carried out using weather data from Mexico City and Ottawa, which are a good representation of two extreme weather conditions, in order to assess the thermal behaviour inside offices, such as energy loads, costs for air conditioning, and the influence of interior heat transfer coefficient correlations. The results indicate that the glass-film proves to be the less appropriate configuration due to the high temperatures reached on the film surface, which has an impact on the air temperatures inside the office and contributes to increase the energy consumption. In general, the double glass-film configuration results to be adequate for both climates, nevertheless it shows a better performance for Ottawa than Mexico City, where a simple double clear glass would work the same way.

M. Gijn-Rivera; G. lvarez; I. Beausoleil-Morrison; J. Xamn

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "glass melter thermal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Scattering Solar Thermal Concentrators  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

is a rendering of a scattering solar concentrator. Light collected by a cylindrical Fresnel lens is focused within a curved glass "guide" sheet, where it is redirected into...

422

THE SLUDGE BATCH 7A GLASS VARIABILITY STUDY WITH FRIT 418 AND FRIT 702  

SciTech Connect

The Defense Waste Processing Facility (DWPF) is preparing to initiate processing of Sludge Batch 7a (SB7a) in May 2011. To support qualification of SB7a, the Savannah River National Laboratory (SRNL) was requested to execute a variability study (VS) to assess the applicability of the current Product Composition Control System (PCCS) durability models for the Frit 418-SB7a compositional region of interest. The objective of this study was to demonstrate applicability of the current durability models to the SB7a compositional region of interest and acceptability of the SB7a glasses with respect to the Environmental Assessment (EA) glass in terms of durability as defined by the Product Consistency Test (PCT). To support programmatic objectives, twenty-eight SB7a glasses were selected based on the nominal sludge projections used to support the frit recommendation. Twenty-three of the SB7a VS glasses were based on the use of Frit 418, while 5 glasses were based on the use of Frit 702. Frit 702 was also identified as a viable candidate for SB7a, especially if SO{sub 4} concentrations are found to be higher than anticipated. Frit 702 has shown a higher SO{sub 4} retention capability as compared to Frit 418. With respect to acceptability, the PCT results of the SB7a-VS glasses are acceptable relative to the EA glass regardless of thermal history (quenched or canister centerline cooled) or compositional view (target or measured). More specifically, all of the SB7a glasses have normalized boron release values (NL [B]) less than 0.9 g/L as compared to the benchmark NL [B] value for EA of 16.695 g/L. With respect to the applicability of the current durability models to the SB7a VS compositional region of interest, all of the study glasses (based on target compositions) lie within the 95% confidence intervals of the model predictions. When model applicability is based on the measured compositions, all of the SB7a VS glasses are predictable with the exception of SB7aVS-02 and SB7aVS-06. Although the NL [B] values of these two glasses range from 0.66 to 0.73 g/L (considered very acceptable), the PCT responses are not considered predictable by the current durability models. The current durability models are conservative for these glasses since they are more durable than predicted by the models. These two glasses are extreme vertices (EV) based compositions coupled with Frit 418 at 36% WL and target the maximum Na{sub 2}O content (15.01 wt% Na{sub 2}O) of the SB7a VS glasses. Higher alkali glasses for which the model overpredicts the PCT response have been observed previously in the Sludge Batch 3 (SB3) Phase 1 VS and the Sludge Batch 6 (SB6) VS.

Peeler, D.; Edwards, T.

2011-03-24T23:59:59.000Z

423

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective alumina coating on electrical stability in dual environment  

SciTech Connect

An alkali-containing silicate glass was recently proposed as a potential sealant for solid oxide fuel cells (SOFC). The glass contains appreciable amount of alkalis and retains its glassy microstructure at elevated temperatures over time. It is more compliant as compared to conventional glass-ceramics sealants and could potentially heal cracks during thermal cycling. In previous papers the thermal cycle stability, thermal stability and chemical compatibility were reported with yttria-stabilized zirconia (YSZ) electrolyte and YSZ-coated ferritic stainless steel interconnect. In this paper, we report the electrical stability of the compliant glass with aluminized AISI441 interconnect material under DC load in dual environment at 700-800oC. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two aluminized AISI441 metal coupons as well as plain AISI441 substrates. The results showed good electrical stability with the aluminized AISI441 substrate, while unstable behavior was observed for un-coated substrates. In addition, interfacial microstructure was examined with scanning electron microscopy and correlated with the measured resistivity results. Overall, the alumina coating demonstrated good chemical stability with the alkali-containing silicate sealing glass under DC loading.

Chou, Y. S.; Choi, Jung-Pyung; Stevenson, Jeffry W.

2012-12-01T23:59:59.000Z

424

Glass for sealing lithium cells  

DOE Patents (OSTI)

Glass compositions resistant to corrosion by lithium cell electrolyte and having an expansion coefficient of 45 to 85 x 10/sup -70/C/sup -1/ have been made with SiO/sub 2/, 25 to 55% by weight; B/sub 2/O/sub 3/, 5 to 12%; Al/sub 2/O/sub 3/, 12 to 35%; CaO, 5 to 15%; MgO, 5 to 15%; SrO, 0 to 10%; and La/sub 2/O/sub 3/, 0 to 5%. Preferred compositions within that range contain 3 to 8% SrO and 0.5 to 2.5% La/sub 2/O/sub 3/.

Leedecke, C.J.

1981-08-28T23:59:59.000Z

425

Solid oxide fuel cell having a glass composite seal  

DOE Patents (OSTI)

A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

2013-04-16T23:59:59.000Z

426

Critical review of glass performance modeling  

SciTech Connect

Borosilicate glass is to be used for permanent disposal of high-level nuclear waste in a geologic repository. Mechanistic chemical models are used to predict the rate at which radionuclides will be released from the glass under repository conditions. The most successful and useful of these models link reaction path geochemical modeling programs with a glass dissolution rate law that is consistent with transition state theory. These models have been used to simulate several types of short-term laboratory tests of glass dissolution and to predict the long-term performance of the glass in a repository. Although mechanistically based, the current models are limited by a lack of unambiguous experimental support for some of their assumptions. The most severe problem of this type is the lack of an existing validated mechanism that controls long-term glass dissolution rates. Current models can be improved by performing carefully designed experiments and using the experimental results to validate the rate-controlling mechanisms implicit in the models. These models should be supported with long-term experiments to be used for model validation. The mechanistic basis of the models should be explored by using modern molecular simulations such as molecular orbital and molecular dynamics to investigate both the glass structure and its dissolution process.

Bourcier, W.L. [Lawrence Livermore National Lab., CA (United States)

1994-07-01T23:59:59.000Z

427

Energy implications of glass-container recycling  

SciTech Connect

This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

Gaines, L.L.; Mintz, M.M. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States)

1994-03-01T23:59:59.000Z

428

Glass-ceramic joint and method of joining  

DOE Patents (OSTI)

The present invention is a glass-ceramic material and method of making useful for joining a solid ceramic component and at least one other solid component. The material is a blend of M1-M2-M3, wherein M1 is BaO, SrO, CaO, MgO, or combinations thereof, M2 is Al.sub.2 O.sub.3, present in the blend in an amount from 2 to 15 mol %, M3 is SiO.sub.2 with up to 50 mol % B.sub.2 O.sub.3 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M1-Al.sub.2 O.sub.3 -M3 system can be used to join or seal both tubular and planar solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

Meinhardt, Kerry D [Richland, WA; Vienna, John D [West Richland, WA; Armstrong, Timothy R [Clinton, TN; Pederson, Larry R [Kennewick, WA

2003-03-18T23:59:59.000Z

429

Glass Needs for a Growing Photovoltaics Industry Keith Burrows1  

E-Print Network (OSTI)

1 Glass Needs for a Growing Photovoltaics Industry Keith Burrows1 and Vasilis Fthenakis1,2* 1, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass

430

Finding Glass Kenton McHenry, Jean Ponce  

E-Print Network (OSTI)

Finding Glass Kenton McHenry, Jean Ponce Beckman Institute University of Illinois Urbana, IL 61801. This paper addresses the problem of finding glass ob- jects in images. Visual cues obtained by combining with the strong highlights typical of glass surfaces are used to train a hierarchy of classifiers, identify glass

Forsyth, David

431

Non-photorealistic Rendering of Images as Evolutionary Stained Glass  

E-Print Network (OSTI)

Non-photorealistic Rendering of Images as Evolutionary Stained Glass Daniel Ashlock Mathematics glass. A collection of points that are the centers of weighted Voronoi tilings are evolved to minimize. A fractal model of stained glass is then run to create a stained glass texture with a similar average color

Ashlock, Dan

432

Glass/polymer composites and methods of making  

DOE Patents (OSTI)

The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

Samuels, W. D. (Richland, WA); Exarhos, Gregory J. (Richland, WA)

1995-01-01T23:59:59.000Z

433

Dynamics of the Structural Glass Transition and the p-SpinInteraction Spin-Glass Model  

Science Journals Connector (OSTI)

The mathematical structure of the dynamical theory for the soft-spin version of the p-spin-interaction (p>2) spin-glass model is related to that for the dynamical theories of the structural glass transition. The phase transitions predicted by both theories are discussed. The spin-glass transition predicted by the dynamical theory is related to a broken-replica-symmetry equilibrium calculation.

T. R. Kirkpatrick and D. Thirumalai

1987-05-18T23:59:59.000Z

434

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

435

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

436

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

437

Bioactive Glass Scaffolds for Bone Regeneration  

NLE Websites -- All DOE Office Websites (Extended Search)

Bioactive Glass Scaffolds for Bone Regeneration Print Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density ratios. Working at ALS Beamline 8.3.2, researchers from Berkeley Lab and the Imperial College London have created bioactive glass scaffolds that mirror nature's efficient materials. The three-dimensional glass scaffold is as porous as trabecular bone, has a compressive strength comparable to that of cortical bone, and a strength-to-porosity ratio higher than any previously reported scaffolds.

438

Glass Buttes Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Glass Buttes Geothermal Area Glass Buttes Geothermal Area (Redirected from Glass Buttes Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Glass Buttes Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (1) 9 Exploration Activities (14) 10 References Area Overview Geothermal Area Profile Location: Oregon Exploration Region: Cascades GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed. Add a new Operating Power Plant

439

Preparation of fullerene/glass composites  

DOE Patents (OSTI)

Synthesis of fullerene/glass composites is described. A direct method for preparing solid solutions of C{sub 60} in silicon dioxide (SiO{sub 2}) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these ``guests`` in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C{sub 60}. Depending upon the preparative procedure, C{sub 60} dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C{sub 60} in a solid glass matrix, is generated by the present method.

Mattes, B.R.; McBranch, D.W.; Robinson, J.M.; Koskelo, A.C.; Love, S.P.

1995-05-30T23:59:59.000Z

440

Measurement of DWPF glass viscosity - Final Report  

SciTech Connect

This report details the results of a scoping study funded by the Defense Waste Processing Facility (DWPF) for the measurement of melt viscosities for simulated glasses representative of Macrobatch 2 (Tank 42/51 feed).

Harbour, J.R.

2000-02-17T23:59:59.000Z