Sample records for glacial acetic acid

  1. acetic acid solutions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  2. acetic acid solution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  3. acetic acid operational: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  4. Original article Ethanol and acetic-acid tolerance

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Ethanol and acetic-acid tolerance in Indian geographical populations of Drosophila clines of ethanol toler- ance (1.5-4.2%) and acetic-acid tolerance (2.9-4.9%) were observed in adult individuals of 4 geographical populations of Drosophila immigrans. Thus, both ethanol and acetic

  5. acetal benzoic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  6. acetic acid allyl: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  7. acetic acid cyano: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  8. acetic acid injection: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  9. acetic acid esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  10. acetic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  11. acetic acid exemption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  12. acetic acid bacterium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  13. acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  14. acetic acid ability: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  15. acetic acid trichloro: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  16. acetic acid production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production in Biology and Medicine Websites Summary: The production of acetic acid during wine fermentation is a critical issue for wineries since the sensory quality* Wine...

  17. acetic acid fermentation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production in Biology and Medicine Websites Summary: The production of acetic acid during wine fermentation is a critical issue for wineries since the sensory quality* Wine...

  18. Original article Ethanol and acetic-acid tolerances

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Ethanol and acetic-acid tolerances in Drosophila melanogaster: similar maternal) Summary - Ethanol and acetic-acid tolerances were studied in a cross between 2 geo- graphic races disappeared in the F2. Further investigations demonstrated that for ethanol tolerance, the large difference

  19. acetic acid provide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Centre, University of British Columbia, Vancouver, British Columbia, Canada Abstract of a wine can be affected by the amount of acetic acid it contains. We found that the C2H2-type...

  20. Liquid-liquid equilibria of the ternary systems water + acetic acid + ethyl acetate and water + acetic acid + isophorene (3,5,5-trimethyl-2-cyclohexen-1-one)

    SciTech Connect (OSTI)

    Colombo, A.; Battilana, P.; Ragaini, V.; Bianchi, C.L. [Milan Univ. (Italy). Dept. of Physical Chemistry and Electrochemistry] [Milan Univ. (Italy). Dept. of Physical Chemistry and Electrochemistry; Carvoli, G. [Chemial S.p.A., Cavaglia (Italy)] [Chemial S.p.A., Cavaglia (Italy)

    1999-01-01T23:59:59.000Z

    Liquid-liquid equilibria for the ternary systems water + acetic acid + ethyl acetate and water + acetic acid + isophorone (3,5,5-trimethyl-2-cyclohexen-1-one) were measured over the temperature range (283 to 313) K. The results were used to estimate the interaction parameters between each of the three compounds of the systems studied for the NRTL and UNIQUAC models. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models; experimental data were successfully reproduced. The UNIQUAC model was the most accurate in correlating the overall equilibrium composition of the studied systems. Also the NRTL model satisfactorily predicted the equilibrium composition. Isophorone experimentally resulted in a better extraction capacity for acetic acid and in a lower miscibility with water.

  1. acid acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of asphaltene deposition that occurs during acid treatments of oil reservoirs. Asphaltenes are present to some degree in most hydrocarbons. Due to the molecular weight of the...

  2. Development of Acetic Acid Removal Technology for the UREX+Process

    SciTech Connect (OSTI)

    Robert M. Counce; Jack S. Watson

    2009-06-30T23:59:59.000Z

    It is imperative that acetic acid is removed from a waste stream in the UREX+process so that nitric acid can be recycled and possible interference with downstreatm steps can be avoidec. Acetic acid arises from acetohydrozamic acid (AHA), and is used to suppress plutonium in the first step of the UREX+process. Later, it is hydrolyzed into hydroxyl amine nitrate and acetic acid. Many common separation technologies were examined, and solvent extraction was determined to be the best choice under process conditions. Solvents already used in the UREX+ process were then tested to determine if they would be sufficient for the removal of acetic acid. The tributyl phosphage (TBP)-dodecane diluent, used in both UREX and NPEX, was determined to be a solvent system that gave sufficient distribution coefficients for acetic acid in addition to a high separation factor from nitric acid.

  3. acetic acid survey: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1995-01-01 55 High Purity Ethyl Acetate Production with a Batch Reactive Distillation Column using Dynamic Optimization Strategy CiteSeer Summary: AbstractEthyl acetate with the...

  4. Scaleable production and separation of fermentation-derived acetic acid. Final CRADA report.

    SciTech Connect (OSTI)

    Snyder, S. W.; Energy Systems

    2010-02-08T23:59:59.000Z

    Half of U.S. acetic acid production is used in manufacturing vinyl acetate monomer (VAM) and is economical only in very large production plants. Nearly 80% of the VAM is produced by methanol carbonylation, which requires high temperatures and exotic construction materials and is energy intensive. Fermentation-derived acetic acid production allows for small-scale production at low temperatures, significantly reducing the energy requirement of the process. The goal of the project is to develop a scaleable production and separation process for fermentation-derived acetic acid. Synthesis gas (syngas) will be fermented to acetic acid, and the fermentation broth will be continuously neutralized with ammonia. The acetic acid product will be recovered from the ammonium acid broth using vapor-based membrane separation technology. The process is summarized in Figure 1. The two technical challenges to success are selecting and developing (1) microbial strains that efficiently ferment syngas to acetic acid in high salt environments and (2) membranes that efficiently separate ammonia from the acetic acid/water mixture and are stable at high enough temperature to facilitate high thermal cracking of the ammonium acetate salt. Fermentation - Microbial strains were procured from a variety of public culture collections (Table 1). Strains were incubated and grown in the presence of the ammonium acetate product and the fastest growing cultures were selected and incubated at higher product concentrations. An example of the performance of a selected culture is shown in Figure 2. Separations - Several membranes were considered. Testing was performed on a new product line produced by Sulzer Chemtech (Germany). These are tubular ceramic membranes with weak acid functionality (see Figure 3). The following results were observed: (1) The membranes were relatively fragile in a laboratory setting; (2) Thermally stable {at} 130 C in hot organic acids; (3) Acetic acid rejection > 99%; and (4) Moderate ammonia flux. The advantages of producing acetic acid by fermentation include its appropriateness for small-scale production, lower cost feedstocks, low energy membrane-based purification, and lower temperature and pressure requirements. Potential energy savings of using fermentation are estimated to be approximately 14 trillion Btu by 2020 from a reduction in natural gas use. Decreased transportation needs with regional plants will eliminate approximately 200 million gallons of diesel consumption, for combined savings of 45 trillion Btu. If the fermentation process captures new acetic acid production, savings could include an additional 5 trillion Btu from production and 7 trillion Btu from transportation energy.

  5. Microbial process for the preparation of acetic acid, as well as solvent for its extraction from the fermentation broth

    DOE Patents [OSTI]

    Gaddy, James L.; Clausen, Edgar C.; Ko, Ching-Whan; Wade, Leslie E.; Wikstrom, Carl V.

    2007-03-27T23:59:59.000Z

    A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. Solvent mixtures formed of such a modified solvent with a desired co-solvent, preferably a low boiling hydrocarbon, are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

  6. Microbial process for the preparation of acetic acid, as well as solvent for its extraction from the fermentation broth

    DOE Patents [OSTI]

    Gaddy, James L.; Clausen, Edgar C.; Ko, Ching-Whan; Wade, Leslie E.; Wikstrom, Carl V.

    2004-06-22T23:59:59.000Z

    A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. Solvent mixtures formed of such a modified solvent with a desired co-solvent, preferably a low boiling hydrocarbon, are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

  7. Metabolic regulation of the plant hormone indole-3-acetic acid

    SciTech Connect (OSTI)

    Jerry D. Cohen

    2009-11-01T23:59:59.000Z

    The phytohormone indole-3-acetic acid (IAA, auxin) is important for many aspects of plant growth, development and responses to the environment yet the routes to is biosynthesis and mechanisms for regulation of IAA levels remain important research questions. A critical issue concerning the biosynthesis if IAA in plants is that redundant pathways for IAA biosynthesis exist in plants. We showed that these redundant pathways and their relative contribution to net IAA production are under both developmental and environmental control. We worked on three fundamental problems related to how plants get their IAA: 1) An in vitro biochemical approach was used to define the tryptophan dependent pathway to IAA using maize endosperm, where relatively large amounts of IAA are produced over a short developmental period. Both a stable isotope dilution and a protein MS approach were used to identify intermediates and enzymes in the reactions. 2) We developed an in vitro system for analysis of tryptophan-independent IAA biosynthesis in maize seedlings and we used a metabolite profiling approach to isolate intermediates in this reaction. 3) Arabidopsis contains a small family of genes that encode potential indolepyruvate decarboxylase enzymes. We cloned these genes and studied plants that are mutant in these genes and that over-express each member in the family in terms of the level and route of IAA biosynthesis. Together, these allowed further development of a comprehensive picture of the pathways and regulatory components that are involved in IAA homeostasis in higher plants.

  8. Effect of acetic acid on lipid accumulation by glucose-fed activated sludge cultures

    SciTech Connect (OSTI)

    Mondala, Andro; Hernandez, Rafael; French, Todd; McFarland, Linda; Sparks, Darrell; Holmes, William; Haque, Monica

    2012-01-01T23:59:59.000Z

    The effect of acetic acid, a lignocellulose hydrolysis by-product, on lipid accumulation by activated sludge cultures grown on glucose was investigated. This was done to assess the possible application of lignocellulose as low-cost and renewable fermentation substrates for biofuel feedstock production. Results: Biomass yield was reduced by around 54% at a 2 g L -1 acetic acid dosage but was increased by around 18% at 10 g L -1 acetic acid dosage relative to the control run. The final gravimetric lipid contents at 2 and 10 g L -1 acetic acid levels were 12.5 ???± 0.7% and 8.8 ???± 3.2% w/w, respectively, which were lower than the control (17.8 ???± 2.8% w/w). However, biodiesel yields from activated sludge grown with acetic acid (5.6 ???± 0.6% w/w for 2 g L -1 acetic acid and 4.2 ???± 3.0% w/w for 10 g L -1 acetic acid) were higher than in raw activated sludge (1-2% w/w). The fatty acid profiles of the accumulated lipids were similar with conventional plant oil biodiesel feedstocks. Conclusions: Acetic acid enhanced biomass production by activated sludge at high levels but reduced lipid production. Further studies are needed to enhance acetic acid utilization by activated sludge microorganisms for lipid biosynthesis.

  9. aqueous acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sections. Moreover, purified DNA was found to take up almost its own dry weight of uranyl acetate from 2 per cent aqucous solution. Strongest staining of whole tissue was...

  10. The feeding value of water and acetic acid reconstituted sorghum grain for lactating dairy cows

    E-Print Network [OSTI]

    Bade, David Heinie

    1972-01-01T23:59:59.000Z

    THE FEEDING VALUE OF WATER AND ACETIC ACID RECONSTITUTED SORGHUM GRAIN FOR LACTATING DAIRY COWS A Thesis by DAVID HEINIE BADE Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE May 1972 Major Subject: Animal Nutrition THE FEEDING VALUE OF WATER AND ACETIC ACID RECONSTITUTED SORGHUM GRAIN FOR LACTATING DAIRY COWS A Thesis by DAVID HEINIE BADE Approved as to style and content by: C ' man o Committee...

  11. Spray-chilling and carcass decontamination systems using lactic and acetic acid

    E-Print Network [OSTI]

    Hamby, Patrick Lawrence

    1986-01-01T23:59:59.000Z

    OF SCIENCE December 1986 Najor Subject; Food Science and Technology SPRAY-CHILLING AND CARCASS DECONTAMINATION SYSTEMS USING LACTIC AND ACETIC ACID A Thesis by PATRICK LAWRENCE NAMBY Approved as to style and content by: H. R. Cross (Co...-Chairman of Committee) f W. Sa 11 (Co-Chai n Committee) Fred A. Gardner (Member) C. Vanderz t (Member ary C. Smith (Head of Department) December 1986 ABSTRACT Spray-Chilling and Carcass Decontamination Systems Using Lactic and Acetic Acid (December 1986...

  12. The feeding value of water and acetic acid reconstituted sorghum grain for lactating dairy cows

    E-Print Network [OSTI]

    Bade, David Heinie

    1972-01-01T23:59:59.000Z

    THE FEEDING VALUE OF WATER AND ACETIC ACID RECONSTITUTED SORGHUM GRAIN FOR LACTATING DAIRY COWS A Thesis by DAVID HEINIE BADE Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE May 1972 Major Subject: Animal Nutrition THE FEEDING VALUE OF WATER AND ACETIC ACID RECONSTITUTED SORGHUM GRAIN FOR LACTATING DAIRY COWS A Thesis by DAVID HEINIE BADE Approved as to style and content by: C ' man o Committee...

  13. Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(111)

    SciTech Connect (OSTI)

    Calaza, Florencia [Max Planck Society, Fritz Haber Institute; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Xu, Ye [Louisiana State University; Overbury, Steven {Steve} H [ORNL

    2015-01-01T23:59:59.000Z

    Adsorption and reaction of acetic acid on a CeO2(1 1 1) surface was studied by a combination of ultra-highvacuum based methods including temperature desorption spectroscopy (TPD), soft X-ray photoelectronspectroscopy (sXPS), near edge X-ray absorption spectroscopy (NEXAFS) and reflection absorption IRspectroscopy (RAIRS), together with density functional theory (DFT) calculations. TPD shows that thedesorption products are strongly dependent upon the initial oxidation state of the CeO2surface, includingselectivity between acetone and acetaldehyde products. The combination of sXPS and NEXAFS demon-strate that acetate forms upon adsorption at low temperature and is stable to above 500 K, above whichpoint ketene, acetone and acetic acid desorb. DFT and RAIRS show that below 500 K, bridge bondedacetate coexists with a moiety formed by adsorption of an acetate at an oxygen vacancy, formed bywater desorption.

  14. acetic acid increases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on this diet when compared to the fat... Kelly, Peter B. 2013-10-04 296 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  15. acetals carboxylic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  16. acetals carboxylic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  17. DOI: 10.1002/chem.200700579 Selective Catalytic Oxidation of Ethanol to Acetic Acid on Dispersed

    E-Print Network [OSTI]

    Iglesia, Enrique

    % ethanol conversion) were much higher than in previous re- ports. The presence of TiO2 during syn- thesisDOI: 10.1002/chem.200700579 Selective Catalytic Oxidation of Ethanol to Acetic Acid on Dispersed Mo, easily separated from organic reactants and products, and gas-phase process- es that avoid solid

  18. Microbial process for the preparation of acetic acid as well as solvent for its extraction from the fermentation broth

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR); Ko, Ching-Whan (Fayetteville, AR); Wade, Leslie E. (Corpus Christi, TX); Wikstrom, Carl V. (Fayetteville, AR)

    2002-01-01T23:59:59.000Z

    A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. This solvent is substantially devoid of mono-alkyl amines and alcohols. Solvent mixtures formed of such a modified solvent with a desired cosolvent, preferably a low boiling hydrocarbon which forms an azeotrope with water are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

  19. Microbial process for the preparation of acetic acid as well as solvent for its extraction from the fermentation broth

    DOE Patents [OSTI]

    Gaddy, James L.; Clausen, Edgar C.; Ko, Ching-Whan; Wade, Leslie E.; Wikstrom, Carl V.

    2006-07-11T23:59:59.000Z

    A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. This solvent is substantially devoid of mono-alkyl amines and alcohols. Solvent mixtures formed of such a modified solvent with a desired cosolvent, preferably a low boiling hydrocarbon which forms an azeotrope with water are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

  20. Firmness and cell wall characteristics of pasteurized jalapeno pepper rings affected by acetic acid, calcium chloride and preheating

    E-Print Network [OSTI]

    Burma, Prashanthi V

    1994-01-01T23:59:59.000Z

    pasteurization and storage, especially when high acid brines are used. Development of treatments to retard softening may result in a higher quality product. This study was undertaken to investigate the effects of calcium chloride (CaCI2), acetic acid...

  1. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  2. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  3. Dual Antiplatelet Regime Versus Acetyl-acetic Acid for Carotid Artery Stenting

    SciTech Connect (OSTI)

    Dalainas, Ilias, E-mail: hdlns@freemail.gr; Nano, Giovanni; Bianchi, Paolo; Stegher, Silvia; Malacrida, Giovanni; Tealdi, Domenico G. [University of Milan, Istituto Policlinico San Donato, 1st Unit of Vascular Surgery (Italy)

    2006-08-15T23:59:59.000Z

    Carotid artery stenting has been proposed as an option treatment of carotid artery stenosis. The aim of this single-institution study is to compare the dual-antiplatelet treatment and heparin combined with acetyl-acetic acid, in patients who underwent carotid artery stenting. We compared 2 groups of 50 patents each who underwent carotid artery stenting for primary atherosclerotic disease. Group A received heparin for 24 h combined with 325 mg acetyl-acetic acid and group B received 250 mg ticlopidine twice a day combined with 325 mg acetyl-acetic acid. Outcome measurements included 30-day bleeding and neurological complications and 30-day thrombosis/occlusion rates. The neurological complications were 16% in group A and 2% in group B (p < 0.05). Bleeding complications occurred in 4% in group A and 2% in group B (p > 0.05). The 30-day thrombosis/occlusion rate was 2% in group A and 0% in group B (p > 0.05). Dual antiplatelet treatment is recommended in all patients undergoing carotid artery stenting.

  4. Techno-economic Analysis for the Thermochemical Conversion of Lignocellulosic Biomass to Ethanol via Acetic Acid Synthesis

    SciTech Connect (OSTI)

    Zhu, Yunhua; Jones, Susanne B.

    2009-04-01T23:59:59.000Z

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications. As a widely available biomass form, lignocellulosic biomass can have a major impact on domestic transportation fuel supplies and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). This study performs a techno-economic analysis of the thermo chemical conversion of biomass to ethanol, through methanol and acetic acid, followed by hydrogenation of acetic acid to ethanol. The conversion of syngas to methanol and methanol to acetic acid are well-proven technologies with high conversions and yields. This study was undertaken to determine if this highly selective route to ethanol could provide an already established economically attractive route to ethanol. The feedstock was assumed to be wood chips at 2000 metric ton/day (dry basis). Two types of gasification technologies were evaluated: an indirectly-heated gasifier and a directly-heated oxygen-blown gasifier. Process models were developed and a cost analysis was performed. The carbon monoxide used for acetic acid synthesis from methanol and the hydrogen used for hydrogenation were assumed to be purchased and not derived from the gasifier. Analysis results show that ethanol selling prices are estimated to be $2.79/gallon and $2.81/gallon for the indirectly-heated gasifier and the directly-heated gasifier systems, respectively (1stQ 2008$, 10% ROI). These costs are above the ethanol market price for during the same time period ($1.50 - $2.50/gal). The co-production of acetic acid greatly improves the process economics as shown in the figure below. Here, 20% of the acetic acid is diverted from ethanol production and assumed to be sold as a co-product at the prevailing market prices ($0.40 - $0.60/lb acetic acid), resulting in competitive ethanol production costs.

  5. Liquid-liquid equilibria of the ternary system water + acetic acid + 1-hexanol

    SciTech Connect (OSTI)

    Fahim, M.A. [Kuwait Univ., Safat (Kuwait). Dept. of Chemical Engineering] [Kuwait Univ., Safat (Kuwait). Dept. of Chemical Engineering; Al-Muhtaseb, S.A.; Al-Nashef, I.M. [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

    1997-01-01T23:59:59.000Z

    The recovery of organic acids from dilute solutions resulting from fermentation processes is important and many solvents have been tried to improve such recovery. Liquid-liquid equilibria for the ternary system water + acetic acid + 1-hexanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. The UNIQUAC and UNIFAC models satisfactorily predicted the equilibrium compositions.

  6. Liquid-liquid equilibria of the ternary system water + acetic acid + 2-methyl-2-butanol

    SciTech Connect (OSTI)

    Fahim, M.A.; Al-Muhtaseb, S.A. [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

    1996-11-01T23:59:59.000Z

    Liquid-liquid equilibria for the ternary system water + acetic acid + 2-methyl-2-butanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UJNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. The UNIFAC model satisfactorily predicted the equilibrium compositions.

  7. Vapor phase ketonization of acetic acid on ceria based metal oxides

    SciTech Connect (OSTI)

    Liu, Changjun; Karim, Ayman M.; Lebarbier, Vanessa MC; Mei, Donghai; Wang, Yong

    2013-12-01T23:59:59.000Z

    The activities of CeO2, Mn2O3-CeO2 and ZrO2-CeO2 were measured for acetic acid ketonization under reaction conditions relevant to pyrolysis vapor upgrading. We show that the catalyst ranking changed depending on the reaction conditions. Mn2O3-CeO2 was the most active catalyst at 350 oC, while ZrO2 - CeO2 was the most active catalyst at 450 oC. Under high CO2 and steam concentration in the reactants, Mn2O3-CeO2 was the most active catalyst at 350 and 450 C. The binding energies of steam and CO2 with the active phase were calculated to provide the insight into the tolerance of Mn2O3-CeO2 to steam and CO2.

  8. Phase equilibria of the ternary system water + acetic acid + 1-pentanol

    SciTech Connect (OSTI)

    Fahim, M.A.; Al-Muhtaseb, S.A.; Al-Nashef, I.M. [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

    1996-05-01T23:59:59.000Z

    The recovery of organic acids from dilute solutions resulting from fermentation processes is becoming very important and many solvents have been tried to improve such recovery. Liquid-liquid equilibria for the ternary system water + acetic acid + 1-pentanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL and UNIQUAC models were almost equally good in predicting the overall equilibrium compositions of the studied system. The UNIFAC model satisfactorily predicted the equilibrium compositions. On the basis of this work, the distribution coefficients were also calculated and compared with the experimental values.

  9. The Aerobic Oxidation of Bromide to Dibromine Catalyzed by Homogeneous Oxidation Catalysts and Initiated by Nitrate in Acetic Acid

    SciTech Connect (OSTI)

    Partenheimer, Walt; Fulton, John L.; Sorensen, Christina M.; Pham, Van Thai; Chen, Yongsheng

    2014-06-01T23:59:59.000Z

    A small amount of nitrate, ~0.002 molal, initiates the Co/Mn catalyzed aerobic oxidation of bromide compounds (HBr,NaBr,LiBr) to dibromine in acetic acid at room temperature. At temperatures 40oC or less , the reaction is autocatalytic. Co(II) and Mn(II) themselves and mixed with ionic bromide are known homogeneous oxidation catalysts. The reaction was discovered serendipitously when a Co/Br and Co/Mn/Br catalyst solution was prepared for the aerobic oxidation of methyaromatic compounds and the Co acetate contained a small amount of impurity i.e. nitrate. The reaction was characterized by IR, UV-VIS, MALDI and EXAFS spectroscopies and the coordination chemistry is described. The reaction is inhibited by water and its rate changed by pH. The change in these variables, as well as others, are identical to those observed during homogeneous, aerobic oxidation of akylaromatics. A mechanism is proposed. Accidental addition of a small amount of nitrate compound into a Co/Mn/Br/acetic acid mixture in a large, commercial feedtank is potentially dangerous.

  10. Sulphydryl groups and iodo-(/sup 3/H)acetic acid labeling in proteolipids from Torpedo electroplax

    SciTech Connect (OSTI)

    Criado, M.; Aguilar, J.S.; De Robertis, E.

    1983-05-01T23:59:59.000Z

    Several fractions of proteolipids from Torpedo electroplax were separated by DEAE-cellulose chromatography in organic solvents, and the sulphydryl groups were determined by a spectrophotometric method. On the same fractions the covalent labeling with iodo-(/sup 3/H)acetic acid to sulphydryl groups was studied. In total proteolipids there were 30.3 nmol/mg protein of sulphydryl groups of which 20.6 nmoles were in the form of disulfide bonds and 10.9 nmol as free--SH groups. The highest content of sulphydryl groups (36.7 nmol/mg protein) was found in fraction II; while fraction I, that binds the cholinergic ligands, has a lower content (23.7 nmol/mg protein). The 42 Kdaltons polypeptide, which is the major band in Fraction II, has the strongest labeling with iodo-(/sup 3/H)acetic acid, while the 39 Kdaltons cholinergic polypeptide shows a lower labeling. The importance of proteolipids as channel-forming macromolecules is discussed in connection with the possible significance of the 42 Kdaltons polypeptide.

  11. Preparation of vinyl acetate

    DOE Patents [OSTI]

    Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

    1998-03-24T23:59:59.000Z

    This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

  12. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    1998-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  13. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, J.L.

    1998-09-15T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

  14. Tetraethylene glycol promoted two-step, one-pot rapid synthesis of indole-3-[1-11C]acetic acid

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lee, Sojeong [Brookhaven National Laboratory (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States); Qu, Wenchao [Brookhaven National Laboratory (BNL), Upton, NY (United States); Alexoff, David L. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Shea, Colleen [Brookhaven National Laboratory (BNL), Upton, NY (United States); Kim, Dohyun [Brookhaven National Laboratory (BNL), Upton, NY (United States); Schueller, Michael [Brookhaven National Laboratory (BNL), Upton, NY (United States); Fowler, Joanna S. [Brookhaven National Laboratory (BNL), Upton, NY (United States)

    2015-01-01T23:59:59.000Z

    An operationally friendly, two-step, one-pot process has been developed for the rapid synthesis of carbon-11 labeled indole-3-acetic acid ([11]IAA or [11]auxin). By replacing an aprotic polar solvent with tetraethylene glycol, nucleophilic [11]cyanation and alkaline hydrolysis reactions were performed consecutively in a single pot without a time-consuming intermediate purification step. The entire production time for this updated procedure is 55 min, which dramatically simplifies the entire synthesis and reduces the starting radioactivity required for a whole plant imaging study.

  15. arachidonic acid activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  16. acid inertness studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  17. acid alleviates decreases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  18. acid activated montmorillonite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  19. acid amide hydrolase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been studied....

  20. acid chelation phototherapeutic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  1. acid phosphatase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  2. acid 2-benzothiazolylthiomethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  3. acid phosphatase activities: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  4. acid sphingomyelinase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  5. acids decreases fibrinolysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  6. acid potassium glycyrrhetinate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  7. arachidonic acid activates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  8. acid decarboxylase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  9. acid activates nrf2: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  10. acid processing activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  11. ascorbic acid enhances: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  12. acid incorporating poloxamer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  13. acid cupric chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  14. acids increase cardiovascular: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

  15. Inhibition of Biohydrogen Production by Undissociated Acetic and Butyric

    E-Print Network [OSTI]

    Inhibition of Biohydrogen Production by Undissociated Acetic and Butyric Acids S T E V E N V A N G Sackett Building, Penn State University, University Park, Pennsylvania 16801 Glucose fermentation to hydrogen results in the production of acetic and butyric acids. The inhibitory effect of these acids

  16. acetate sedimentation concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    blend. Inthe present investigation, densities and viscosities have been measured in 4 % solution of polyAcrylic Acid and Poly vinyl Acetate in DMSO using calculated and reduced...

  17. Contrasting wetland CH4 emission responses to simulated glacial atmospheric CO2 in temperate bogs and fens

    E-Print Network [OSTI]

    Gauci, Vincent

    Contrasting wetland CH4 emission responses to simulated glacial atmospheric CO2 in temperate bogs, glacial, Last Glacial Maximum (LGM), methane (CH4), peatland, wetland. Summary · Wetlands were the largest (n = 8 per treatment) and measured gaseous CH4 flux, pore water dissolved CH4 and volatile fatty acid

  18. Catalytic oxidation of propylene to allyl acetate

    SciTech Connect (OSTI)

    Lyons, J.E.; Suld, G.

    1986-07-22T23:59:59.000Z

    A process is described for the preparation of allyl acetate which comprises first activating a supported palladium metal catalyst by contacting it with a C/sub 3/-C/sub 6/ olefin at a temperature of greater than about 50/sup 0/C for a period for time sufficient to provide at least a small but perceptible quantity of the activated catalyst, in the substantial absence of oxygen, and thereafter contacting the activated catalyst with acetic acid and propylene admixed with air or oxygen in a liquid medium, thereby forming allyl acetate.

  19. Vapor-liquid equilibria and excess enthalpies for octane + N-methylacetamide, cyclooctane + N-methylacetamide, and octane + acetic acid anhydride at 125 C

    SciTech Connect (OSTI)

    Haan, A.B. de [DSM-Research, Geleen (Netherlands); Heine, A.; Fischer, K.; Gmehling, J. [Univ. Oldenburg (Germany)

    1995-11-01T23:59:59.000Z

    Isothermal P-x data and excess enthalpies have been measured at approximately 125 C for the binary mixtures of octane + N-methylacetamide, cyclooctane + N-methylacetamide, and octane + acetic anhydride. For each binary system linear temperature dependent interaction parameters were fitted to experimental data using the NRTL model. Activity coefficients at infinite dilution were derived from the P-x data at low concentrations using a flexible Legendre polynomial.

  20. What drives glacial cycles

    SciTech Connect (OSTI)

    Broecker, W.S.; Denton, G.H.

    1990-01-01T23:59:59.000Z

    The Milankovitch theory advocates that the glacial cycles have three components: the tilt of the earth's spin axis; the shape of the earth's orbit; and the interaction between the tilt and the eccentricity effects. These three factors work together to vary the amount of sunshine reaching the high northern latitudes in summer and allow the great ice sheets to grow during intervals of cool summers and mild winters. Evidence is presented which indicates that the circulation pattern of the Atlantic ocean was shifted dramatically about 14,000 years ago, at the same time that glaciers in both hemispheres started to retreat. The authors believe that massive reorganizations of the ocean-atmosphere system are the key events that link cyclic changes in the earth's orbit to the advance and retreat of ice sheet.

  1. Process for the preparation of vinyl acetate

    DOE Patents [OSTI]

    Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

    1998-02-17T23:59:59.000Z

    This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85 and 200 C and removing the reaction products from the contact zone.

  2. Derivation of a human equivalent concentration for n-butanol using a physiologically based pharmacokinetic model for n-butyl acetate and metabolites n-butanol and n-butyric acid

    SciTech Connect (OSTI)

    Teeguarden, Justin G.; Deisinger, P. J.; Poet, Torka S.; English, J C.; Faber, W D.; Barton, H. A.; Corley, Rick A.; Clewell, III, H. J.

    2005-05-01T23:59:59.000Z

    The metabolic series (family) approach for risk assessment uses a dosimetry-based analysis to develop toxicity information for a group of metabolically linked compounds using pharmacokinetic (PK) data for each compound and toxicity data for the parent compound. An initial physiologically-based pharmacokinetic (PBPK) model was developed to support the implementation of the metabolic series approach for n-butyl acetate and its subsequent metabolites, n-butanol, and n-butyric acid (the butyl series) (Barton et al. 2000). In conjunction with pilot pharmacokinetic studies, the model was used to design the definitive intravenous (i.v.) PK studies. Rats were implanted with dual indwelling cannulae and administered test compounds by i.v. bolus dose, i.v. infusion, or by inhalation in a recirculating closed chamber. Hepatic, vascular and extravascular metabolic constants for metabolism were estimated by fitting the model to the blood time course data from these experiments. The respiratory bioavailability of n-butyl acetate and n-butanol was estimated from closed chamber inhalation studies and measured ventilation rates. The resulting butyl series PBPK model successfully reproduces the blood time course of these compounds following i.v. administration, and inhalation exposure to n-butyl acetate and n-butanol. A fully scaled human version of the model successfully reproduces arterial blood n-butanol kinetics following inhalation exposure to n-butanol. These validated i.v (rat) and inhalation route models (rat, butyl acetate, n-butanol; human, butanol only) can be used to support species and dose-route extrapolations required for risk assessment of butyl series family of compounds. Further, this work demonstrates the usefulness of i.v. kinetic data for parameterization of systemic metabolism and the value of collaboration between experimentalists and kineticists in the development of PBPK models. The product of this effort, validated rat and human PBPK models for the butyl series compounds, illustrates the effectiveness of broad multi-institutional public/private collaborations in the pursuit of developing state of the art tools for risk assessment.

  3. A study of carbon-14 of paleoatmospheric methane for the last glacial termination from ancient glacial ice

    E-Print Network [OSTI]

    Petrenko, Vasilii Victorovich

    2008-01-01T23:59:59.000Z

    for the last glacial termination." xii VITA Education Ph.D.the Last Glacial Termination: a horizontal ice core.the Last Glacial Termination: a horizontal ice core.

  4. The Fermentation Stress Response Protein Aaf1p/ Yml081Wp Regulates Acetate Production in

    E-Print Network [OSTI]

    Farrell, Anthony P.

    The production of acetic acid during wine fermentation is a critical issue for wineries since the sensory quality of a wine can be affected by the amount of acetic acid it contains. We found that the C2H2-type zinc as part of the pyruvate dehydrogenase bypass. This regulation was also reflected in the protein levels

  5. 2, 711743, 2006 Glacial CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    CO2 change: a simple "hypsometric effect" on deep-ocean carbon sequestration? L. C. Skinner Godwin carbon sequestration, this mechanism may help to significantly reduce the "deficit" of explained glacialCPD 2, 711743, 2006 Glacial CO2 sequestration L. C. Skinner Title Page Abstract Introduction

  6. Glacial Energy Holdings (Maryland) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacialGlacialGlacial

  7. Mapping bedrock beneath glacial till using CDP seismic reflection methods

    E-Print Network [OSTI]

    Keiswetter, Dean; Black, Ross A.; Steeples, Don W.

    1994-03-01T23:59:59.000Z

    This paper is a case history demonstrating the applicability of the common depth point (CDP) seismic reflection method to image bedrock beneath glacial till in northwestern Iowa. Reflections from the base of the 40-m thick glacial till are clearly...

  8. Glacial Energy Holdings (Delaware) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacial EnergyGlacial

  9. Glacial Energy Holdings (Illinois) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacialGlacial Energy

  10. Glacial Energy Holdings (Maine) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacialGlacial

  11. Glacial Energy Holdings (Ohio) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan)Glacial Energy

  12. Glacial Energy Holdings (Pennsylvania) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan)Glacial

  13. Glacial Lakes Corn Processors | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy HoldingsGlacial Lakes Corn

  14. Concentrating aqueous acetate solutions with tertiary amines

    E-Print Network [OSTI]

    Lee, Champion

    1993-01-01T23:59:59.000Z

    concentrations. ) 73 FIGURE Page 47 Correlation between Kd and water concentration in the organic phase for the calcium acetate/water/amine system. (TEA:DEME mL:1 mL, initial calcium acetate= 1%(w/w)) 48 Correlation between Kd and water concentration... in the organic phase for the calcium acetate/water/amine system. (TEA;DEMAW mL:1 mL, initial calcium acetate= 2%(w/w)) 49 Correlation between Kd and water concentration in the organic phase for the calcium acetate/water/amine system. (TEA:DEMAW mL:1 m...

  15. Investigation of glacial dynamics in lambert glacial basin using satellite remote sensing techniques

    E-Print Network [OSTI]

    Yu, Jaehyung

    2006-04-12T23:59:59.000Z

    The Antarctic ice sheet mass budget is a very important factor for global sea level. An understanding of the glacial dynamics of the Antarctic ice sheet are essential for mass budget estimation. Utilizing a surface velocity field derived from...

  16. Gifts of the Glaciers Glacial Landforms

    E-Print Network [OSTI]

    Cochran-Stafira, D. Liane

    Gifts of the Glaciers Glacial Landforms Gifts of the Glaciers Moving ice of glacier was responsible. Glaciers perform, in many ways, like an excavator. Although they can push weak material, like gravel, like it in place, like a ripper. And, like a bulldozer, glaciers are poor at eroding rock unless it is already

  17. Glacial and Periglacial Processes and Landforms

    E-Print Network [OSTI]

    Pan, Feifei

    associated with mountain locations are ice caps and ice fields. An ice cap is roughly circular and covers is less than that of an ice cap). #12;Vatnajkull Ice Cap #12;Patagonian Ice Field #12;Learning Objective the winter snow and ice accumulation survived the summer melting season. #12;Glacial Movement and Crevasses

  18. Volatile organic acids and microbial processes in the Yegua formation, east-central Texas

    E-Print Network [OSTI]

    Routh, J.; Grossman, E. L.; Ulrich, G. A.; Suflita, J. M.

    2000-01-01T23:59:59.000Z

    reducing bacteria (SRB) in sands. Notably, SRB activity is mostly confined to aquifer sands. Vertical diffusion and advection were modeled to estimate acetic acid transport from aquitard to aquifer. Assuming that SRB completely respire the acetic acid...

  19. Ethylene-Vinyl Acetate Potential Problems for Photovoltaic Packaging: Preprint

    SciTech Connect (OSTI)

    Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K. M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

    2006-05-01T23:59:59.000Z

    Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support, optical coupling, electrical isolation, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate, it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about ?15 C. Temperatures lower than this can be reached for extended periods of time in some climates. Because of increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL 1703.

  20. Ethylene-Vinyl Acetate Potential Problems for Photovoltaic Packaging

    SciTech Connect (OSTI)

    Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K. M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

    2006-01-01T23:59:59.000Z

    Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support, optical coupling, electrical isolation, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate, it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about -15 degC. Temperatures lower than this can be reached for extended periods of time in some climates. Because of increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL1703.

  1. Perchlorate Degradation in Acetate-fed Bioreactors

    E-Print Network [OSTI]

    Perchlorate Degradation in Acetate-fed Bioreactors Yanguang Song Kijung Kim, Bruce Logan Department; Dechlorosoma sp. KJ: isolated from a perchlorate- degrading packed bed bioreactor; Dechlorosoma sp. PDX

  2. Succinic Acid Production with Reduced By-Product Formation in the

    E-Print Network [OSTI]

    Succinic Acid Production with Reduced By-Product Formation in the Fermentation; accepted 13 July 2000 Abstract: Succinic acid was produced by fermentation of Anaerobiospirillum-product acetic acid. The gram ratio of suc- cinic acid to acetic acid was 25.8:1, which is 6.5 times higher than

  3. Hydrogen Fluoride Capture by Imidazolium Acetate Ionic Liquid

    E-Print Network [OSTI]

    Chaban, Vitaly

    2015-01-01T23:59:59.000Z

    Extraction of hydrofluoric acid (HF) from oils is a drastically important problem in petroleum industry, since HF causes quick corrosion of pipe lines and brings severe health problems to humanity. Some ionic liquids (ILs) constitute promising scavenger agents thanks to strong binding to polar compounds and tunability. PM7-MD simulations and hybrid density functional theory are employed here to consider HF capture ability of ILs. Discussing the effects and impacts of the cation and the anion separately and together, I will evaluate performance of imidazolium acetate and outline systematic search guidelines for efficient adsorption and extraction of HF.

  4. Relative timing of last glacial maximum and late-glacial events in the central tropical Andes

    E-Print Network [OSTI]

    Winckler, Gisela

    , and CO2. Moreover, as the energetic powerhouse of the earth, the tropics have huge potential to trigger shifts in tropical temperature and precipitation during the Late Pleistocene (ice-core data: Thompson et al., 1995, 1998; lake-core data: Baker et al., 2001a, b; glacial-geologic data: Smith et al., 2005a

  5. Glacial Lakes Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetec AG Contracting Jump to: navigation,GilaGirasole Srl Jump to:EnergyGlacial

  6. Glacial Energy Holdings (California) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacial Energy Holdings

  7. Glacial Energy Holdings (Connecticut) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacial Energy

  8. Glacial Energy Holdings (Michigan) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan) Jump to:

  9. Glacial Energy Holdings | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings

  10. The volcanic acidification of glacial Lake Caviahue, Province of Neuquen, Argentina Johan C. Varekamp

    E-Print Network [OSTI]

    Royer, Dana

    The volcanic acidification of glacial Lake Caviahue, Province of Neuquen, Argentina Johan C (northern Patagonia, Argentina) is a large glacial lake acidified by volcanic fluids from Copahue volcano

  11. acetate-acetic acid-formalin-fixed stool: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S. stercoralis by agar plate culture of single stool sample, were examined by single PCR. Data analysis was performed using McNemar's ? 2 test, with consideration of a P-value of...

  12. Volatile fatty acid fermentation of lime-treated bagasse by rumen microorganisms

    E-Print Network [OSTI]

    Lee, Chang-Ming

    1993-01-01T23:59:59.000Z

    untreated bagasse . . . . . . . . Iso-Butyric acid concentrations from untreated bagasse . . . Iso-Valeric acid concentrations from untreated bagasse Total acid concentrations from Ca(OH)2-treated bagasse . . Acetic acid concentrations from Ca(OH)2...(OH)q-treated bagasse . . . . . . . Iso-Butyric acid concentrations from Ca(OH/-treated bagasse . . Iso-Valeric acid concentrations from Ca(OH)q-treated bagasse . . Total acid yields from untreated bagasse . 53 54 55 56 57 59 30 31 32 Acetic acid yields...

  13. Glacial Energy Holdings (Rhode Island) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan)GlacialGlacial

  14. Heterogeneous catalyst for the production of ethylidene diacetate from acetic anhydride

    DOE Patents [OSTI]

    Ramprasad, D.; Waller, F.J.

    1998-06-16T23:59:59.000Z

    This invention relates to a process for producing ethylidene diacetate by the reaction of acetic anhydride, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled without loss in activity.

  15. Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    2003-06-24T23:59:59.000Z

    A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

  16. ancient glacial periods: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 MECHANISMS OF ABRUPT CLIMATE CHANGE OF THE LAST GLACIAL PERIOD Geosciences Websites Summary: MECHANISMS OF...

  17. Chilean glacial lake outburst flood impacts on dam construction

    E-Print Network [OSTI]

    Tauro, Flavia

    2009-01-01T23:59:59.000Z

    Four Glacial Lake Outburst Floods (GLOF) occurred in the Colonia Glacier (Northern Patagonia Icefield, Chile) from April 2008 to March 2009. Lago Cachet 2 emptied four times producing a maximum excess discharge in the ...

  18. What happened to the coal forests during Pennsylvanian glacial phases?

    SciTech Connect (OSTI)

    Falcon-Lang, H.J.; Dimichele, W.A. [University of London, Egham (United Kingdom). Dept. of Earth Science

    2010-09-15T23:59:59.000Z

    Sequence stratigraphic analysis of Pennsylvanian coal-bearing strata suggests that glacial-interglacial fluctuations at high latitudes drove cyclic changes in tropical biomes. A literature review of plant assemblages in this paleoclimatic context suggests that coal forests dominated during humid interglacial phases, but were replaced by seasonally dry vegetation during glacial phases. After each glacial event, coal forests reassembled with largely the same species composition. This remarkable stasis implies that coal-forest refugia existed across the equatorial landscape during glacial phases, expanding to repopulate lowlands during and following deglaciation. One possibility is that refugia comprised small pockets of wetland forest strung out along valleys at some sites, but data are currently insufficient to test this hypothesis. The model presented here, if accepted, dramatically alters our understanding of the coal forests and helps explain aspects of their dynamics.

  19. Succinic acid production by Anaerobiospirillum succiniciproducens

    E-Print Network [OSTI]

    , succinic acid has been produced commercially by chemical processes. Recently, however, fermentative of bacteria produce succinic acid as a fermentation end product,4 7 few species can produce it as the major 10 Previous studies showed that A. succiniciproducens produces succinic acid and acetic acid

  20. acetic acid removal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    contamination control 12;10 Transfer of Graphite to Supersack (V) 12;11 Moving graphite pile Complete shipment of graphite to DOE's Nevada Test Site Removal of biological shield...

  1. ammonia acetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to forest health in the region. Sarah Jovan; Bruce Mccune 86 Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems Texas A&M University - TxSpace Summary:...

  2. acetic acid bacterial: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structure of the collapsing cylinder to the spacing of the final aggregates. We show that cylindrical collapse involves a delicate balance in which bacterial attraction and...

  3. acetic acid derivatives: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    affects the values of the derivatives. Our constructions use randomness extractors and expander graphs. We study our derivatives in a more general setting than Arora et al. In...

  4. acetic acid media: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    optics of spatial transformation media CERN Preprints Summary: We show how transformation media J. B. Pendry, D. Schurig, and D. R. Smith, Science 312, 1780 (2006); U. Leonhardt...

  5. Computational and Comparative Investigations of Syntrophic Acetate-

    E-Print Network [OSTI]

    and natural gas, which are depleting rapidly and are major contributors to global warming. Methane is produced with reduced greenhouse gas emissions. In the anaerobic biodegradation process acetate is a major precursor Manzoor, SLU, Department of Animal Breeding and Genetics, P.O. Box 7023, 750 07 Uppsala, Sweden E

  6. Expression of acetate permease-like (apl) genes in subsurface communities of Geobacter species under fluctuating acetate concentrations

    SciTech Connect (OSTI)

    Elifantz, H.; N'Guessan, L.A.; Mouser, P.J.; Williams, K H.; Wilkins, M J.; Risso, C.; Holmes, D.E.; Long, P.E.; Lovley, D.R.

    2010-03-01T23:59:59.000Z

    The addition of acetate to uranium-contaminated aquifers in order to stimulate the growth and activity of Geobacter species that reduce uranium is a promising in situ bioremediation option. Optimizing this bioremediation strategy requires that sufficient acetate be added to promote Geobacter species growth. We hypothesized that under acetate-limiting conditions, subsurface Geobacter species would increase the expression of either putative acetate symporters genes (aplI and aplII). Acetate was added to a uranium-contaminated aquifer (Rifle, CO) in two continuous amendments separated by 5 days of groundwater flush to create changing acetate concentrations. While the expression of aplI in monitoring well D04 (high acetate) weakly correlated with the acetate concentration over time, the transcript levels for this gene were relatively constant in well D08 (low acetate). At the lowest acetate concentrations during the groundwater flush, the transcript levels of aplII were the highest. The expression of aplII decreased 2-10-fold upon acetate reintroduction. However, the overall instability of acetate concentrations throughout the experiment could not support a robust conclusion regarding the role of apl genes in response to acetate limitation under field conditions, in contrast to previous chemostat studies, suggesting that the function of a microbial community cannot be inferred based on lab experiments alone.

  7. Expression of Acetate Permease-like (apl) Genes in Subsurface Communities of Geobacter Species Under Fluctuating Acetate Concentrations

    SciTech Connect (OSTI)

    Elifantz, H.; N'Guessan, A. L.; Mouser, Paula; Williams, Kenneth H.; Wilkins, Michael J.; Risso, Carla; Holmes, Dawn; Long, Philip E.; Lovley, Derek R.

    2010-09-01T23:59:59.000Z

    The addition of acetate to uranium-contaminated aquifers in order to stimulate the growth and activity of Geobacter species that reduce uranium is a promising in situ bioremediation option. Optimizing this bioremediation strategy requires that suf?cient acetate be added to promote Geobacter species growth. We hypothesized that under acetate-limiting conditions, subsurface Geobacter species would increase the expression of either putative acetate symporters genes (aplI and aplII). Acetate was added to a uranium-contaminated aquifer (Ri?e, CO) in two continuous amendments separated by 5 days of groundwater ?ush to create changing acetate concentrations. While the expression of aplI in monitoring well D04 (high acetate) weakly correlated with the acetate concentration over time, the transcript levels for this gene were relatively constant in well D08 (low acetate). At the lowest acetate concentrations during the groundwater ?ush, the transcript levels of aplII were the highest. The expression of aplII decreased 210-fold upon acetate reintroduction. However, the overall instability of acetate concentrations throughout the experiment could not support a robust conclusion regarding the role of apl genes in response to acetate limitation under ?eld conditions, in contrast to previous chemostat studies, suggesting that the function of a microbial community cannot be inferred based on lab experiments alone.

  8. Catalytic, Enantioselective Alkylations of N,O-Acetals

    E-Print Network [OSTI]

    Lectka, Thomas

    , 10998-10999. (2) Hoveyda et al. have developed a Ni-catalyzed alkylation reaction of allylic acetalsCatalytic, Enantioselective Alkylations of N,O-Acetals Dana Ferraris, Travis Dudding, Brandon Young alkylation reactions of acetals have attained a prominent position in organic synthesis.1 Methods employing

  9. Lithium acetate transformation of yeast Maitreya Dunham August 2004

    E-Print Network [OSTI]

    Dunham, Maitreya

    Lithium acetate transformation of yeast Maitreya Dunham August 2004 Original protocol from Katja until the OD600 is around 0.7-0.8 (~7 hours). Spin down the cells. Resuspend in 5 ml lithium acetate mix. Spin. Resuspend in 0.5 ml lithium acetate mix. Transfer to an eppendorf tube. Incubate 60 minutes

  10. QUALIT DES ENSILAGES DE MAS GRAIN HUMIDE PRSERVS PAR L'ACIDE PROPIONIQUE

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    product) and acetic (0,1-0,3 per cent) acids are produced by carbohydrate fermentation. The silage p mas grain humide, la fermentation des glucides entrane une pro- duction notable d'acides lactique (0 degradative change is practically inhi- bited after 3 to 8 months : in our assays, lactic and acetic acids

  11. PRODUCTION D'ACIDES GRAS A COURTE CHAINE AU COURS DE LA DIGESTION CHEZ LE PORC

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    of fermentation) ; this #12;is also the case for acetic acid in the caecum and colon 3 hours after the meal, when jusqu' 9 h aprs la consommation (pH et microflore favorables ce type de fermentation) ; il en va de acids) ; acetic acid, present in great quantities overall in the digestive tract, becomes predominating

  12. SU Material Id Manuf Id SU Material Name QTY SIGM 1-butanol 1

    E-Print Network [OSTI]

    Movileanu, Liviu

    , spectrophotometric grade 1 ALDR 3-hydroxypicolinic acid 1 SIGM acetic acid, glacial 2 SIGM acetic anhydride ACS reagent 1 FISH acetone 1 SIGM acetone, ACS reagent 1 A0300 BIOR agarose (mol. Bio. Grade) 1 FISH allyl acid 1 SIGM tert-butanol ACS reagent 1 ALDR toluene 1 SIGM trichloro acetic acid 1 ALDR Triethylamine

  13. Reduced ventilation and enhanced magnitude of the deep Pacific carbon pool during the last glacial period

    E-Print Network [OSTI]

    Skinner, L.; McCave, I. N.; Carter, L.; Fallon, S.; Scrivner, A. E.; Primeau, F.

    2014-12-15T23:59:59.000Z

    It has been proposed that the ventilation of the deep Pacific carbon pool was not significantly reduced during the last glacial period, posing a problem for canonical theories of glacialinterglacial CO2 change. However, using radiocarbon dates...

  14. Glacial Energy Holdings (New Jersey) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan) JumpGlacial

  15. Post-glacial biogeography of trembling aspen inferred from genetic structure, genetic diversity, and habitat models

    E-Print Network [OSTI]

    Hamann, Andreas

    1 Post-glacial biogeography of trembling aspen inferred from genetic structure, genetic diversity title: Aspen post-glacial migration history Keywords: Populus tremuloides, species distribution models, phylogeography, genetic diversity, glacial refugia, aspen clones, Pando Length: Abstract: 250 words Main text

  16. Topographic control of asynchronous glacial advances: A case study from Annapurna, Nepal

    E-Print Network [OSTI]

    Heimsath, Arjun M.

    Topographic control of asynchronous glacial advances: A case study from Annapurna, Nepal Beth Pratt of asynchronous glacial advances: A case study from Annapurna, Nepal, Geophys. Res. Lett., 38, L24502, doi:10 10 Be dating [Zech et al., 2009]. Further east in Nepal, other glacial dating studies [Finkel et al

  17. GLOBAL GLACIAL ISOSTATIC ADJUSTMENT: TARGET FIELDS FOR SPACE GEODESY

    E-Print Network [OSTI]

    Peltier, W. Richard

    GLOBAL GLACIAL ISOSTATIC ADJUSTMENT: TARGET FIELDS FOR SPACE GEODESY W.R. Peltier Department of Physics, University of Toronto, Toronto, Ontario, Canada M5S-1A7 peltier) and Sabadini and Peltier (1981) whose analysis was based upon the application of a homogeneous viscoelastic

  18. Glacial influence on caldera-forming eruptions Adelina Geyer a,

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    hosted thick glacial ice caps. Additional evidence comes from clustering Kamchatka-derived marine ash by varying: (1) the thickness and asymmetric distribution of the existing ice cap, (2) the depth and size mass build up and hydrothermal alteration. The results obtained indicate that: (1) Any ice cap plays

  19. Potential Problems with Ethylene-Vinyl Acetate for Photovoltaic Packaging (Poster)

    SciTech Connect (OSTI)

    Kempe, M. D.; Jorgensen, G. J.; Terwilliger, K, M.; McMahon, T. J.; Kennedy, C. E.; Borek, T. T.

    2006-05-01T23:59:59.000Z

    Photovoltaic (PV) devices are typically encapsulated using ethylene-vinyl acetate (EVA) to provide mechanical support electrical isolation, optical coupling, and protection against environmental exposure. Under exposure to atmospheric water and/or ultraviolet radiation, EVA will decompose to produce acetic acid, lowering the pH and increasing the surface corrosion rates of embedded devices. Even though acetic acid is produced at a very slow rate it may not take much to catalyze reactions that lead to rapid module deterioration. Another consideration is that the glass transition of EVA, as measured using dynamic mechanical analysis, begins at temperatures of about -15 C. Temperatures lower than this can be reached for extended periods of time in some climates. Due to increased moduli below the glass transition temperature, a module may be more vulnerable to damage if a mechanical load is applied by snow or wind at low temperatures. Modules using EVA should not be rated for use at such low temperatures without additional low-temperature mechanical testing beyond the scope of UL 1703.

  20. alcohol aldehyde acetals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Open Access Theses and Dissertations Summary: ??Liver alcohol dehydrogenase oxidizes ethanol to acetaldehyde, which is further oxidized to acetate by aldehyde dehydrogenase-2...

  1. alcohols aldehydes acetals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Open Access Theses and Dissertations Summary: ??Liver alcohol dehydrogenase oxidizes ethanol to acetaldehyde, which is further oxidized to acetate by aldehyde dehydrogenase-2...

  2. Kinetics and mechanism of the oxidation of propylene to allyl acetate in solutions of palladium clusters

    SciTech Connect (OSTI)

    Stolyarov, I.P.; Vargaftik, M.N.; Moiseev, I.I.

    1988-05-01T23:59:59.000Z

    The kinetics of the oxidative acetoxylation of propylene to allyl acetate in solutions of the clusters Pd/sub 561/Phen/sub 60/(OAc)/sub 180/ and Pd/sub 561/Phen/sub 80/(PF/sub 6/) have been studied by gas-liquid chromatography over the range 40-90/degree/C. It has been established that the rate of reaction is proportional to the concentrations of propylene and the clusters in solution and its dependence on the concentrations of O/sub 2/ and acetic acid is represented by a Michaelis type of equation. For high partial O/sub 2/ pressures inhibition of the reaction by oxygen is observed. A mechanism is proposed for the reaction, according to which the cleavage of the C-H bond in the coordinated olefin molecule to form an allyl complex takes place at the limiting stage.

  3. RPARTITION DES ACIDES GRAS VOLATILS DANS LE TUBE DIGESTIF DU LAPIN DOMESTIQUE

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    that of propionate. Fasting for 48 hours did not cause a total cessation of fermentation. Stercoral fasting did parts (caecum and colon). Key-words : Acetic acid, butyric acid, coprophagy, digestive tract fasting

  4. Investigating the Use of Chelating Agents for Clay Dissolution and Sandstone Acidizing Purposes

    E-Print Network [OSTI]

    Andotra, Gautam

    2014-08-06T23:59:59.000Z

    -Glutamic acid N,N-Di Acetic Acid (Na-GLDA). Experiments were conducted to find out the aluminosilicates dissolution and chelation capabilities of these chelating agents. The first set of experiments were clay dissolution experiments, conducted using different...

  5. Pilot-Scale Fermentation and Laboratory Nutrient Studies on Mixed-Acid Fermentation

    E-Print Network [OSTI]

    Smith, Aaron Douglas

    2011-08-08T23:59:59.000Z

    contacting method (all nutrients fed to F1), the near- optimal feeding strategies improved exit yield, culture yield, process yield, exit acetate- equivalent yield, conversion, and total acid productivity by approximately 31%, 39%, 46%, 31%, 100%, and 19... NOMENCLATURE A mass of carboxylic acid, g [A] total carboxylic acid concentration, g/Lliq. aceq acetic acid equivalents concentration, g/Lliq. ATP adenosine triphosphate Bi Fermentor i bottle plus centrifuge cake, g C conversion, g NAVS consumed/g NAVS...

  6. Alternate fuels and chemicals from synthesis gas: Vinyl acetate monomer. Final report

    SciTech Connect (OSTI)

    Richard D. Colberg; Nick A. Collins; Edwin F. Holcombe; Gerald C. Tustin; Joseph R. Zoeller

    1999-01-01T23:59:59.000Z

    There has been a long-standing desire on the part of industry and the U.S. Department of Energy to replace the existing ethylene-based vinyl acetate monomer (VAM) process with an entirely synthesis gas-based process. Although there are a large number of process options for the conversion of synthesis gas to VAM, Eastman Chemical Company undertook an analytical approach, based on known chemical and economic principles, to reduce the potential candidate processes to a select group of eight processes. The critical technologies that would be required for these routes were: (1) the esterification of acetaldehyde (AcH) with ketene to generate VAM, (2) the hydrogenation of ketene to acetaldehyde, (3) the hydrogenation of acetic acid to acetaldehyde, and (4) the reductive carbonylation of methanol to acetaldehyde. This report describes the selection process for the candidate processes, the successful development of the key technologies, and the economic assessments for the preferred routes. In addition, improvements in the conversion of acetic anhydride and acetaldehyde to VAM are discussed. The conclusion from this study is that, with the technology developed in this study, VAM may be produced from synthesis gas, but the cost of production is about 15% higher than the conventional oxidative acetoxylation of ethylene, primarily due to higher capital associated with the synthesis gas-based processes.

  7. Shapes and surface textures of quartz sand grains from glacial deposits: effects of source and transport

    E-Print Network [OSTI]

    Ritter, Christine

    1987-01-01T23:59:59.000Z

    and to define the shapes and surface texture characteristics which distinguish them from quartz grains of non-glacial origin, 2) to determine the effects of source rock upon the shapes and surface textures of glacial quartz grains, 3) to determine..., and there are no differences in shapes and surface textures of glacial and proglacial quartz grains. The results show that the shapes and surface textures of glacial quartz sand grains largely reflect, and thus are controlled by, the lithology of the source rock from which...

  8. Alignment of micro-crystals of Mn12-acetate and direct observation of single molecules thereof

    E-Print Network [OSTI]

    Seo, Dongmin

    2009-05-15T23:59:59.000Z

    This dissertation focuses on three separate studies. First, magnetization of the Mn12- acetate was studied by low temperature hysteresis loops and DC magnetization data on magnetically aligned Mn12-acetate micro-crystals. Secondly, Mn12-acetate thin...

  9. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, J.L.; Clausen, E.C.

    1992-12-22T23:59:59.000Z

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H[sub 2]O and/or CO[sub 2] and H[sub 2] in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate. 3 figs.

  10. Clostridiumm ljungdahlii, an anaerobic ethanol and acetate producing microorganism

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR)

    1992-01-01T23:59:59.000Z

    A newly discovered microorganism was isolated in a biologically pure culture and designated Clostridium ljungdahlii, having the identifying characteristics of ATCC No. 49587. Cultured in an aqueous nutrient medium under anaerobic conditions, this microorganism is capable of producing ethanol and acetate from CO and H.sub.2 O and/or CO.sub.2 and H.sub.2 in synthesis gas. Under optimal growth conditions, the microorganism produces acetate in preference to ethanol. Conversely, under non-growth conditions, ethanol production is favored over acetate.

  11. Attenuation of acoustic waves in glacial ice and salt domes

    E-Print Network [OSTI]

    P. B. Price

    2005-06-27T23:59:59.000Z

    Two classes of natural solid media (glacial ice and salt domes) are under consideration as media in which to deploy instruments for detection of neutrinos with energy >1e18 eV. Though insensitive to 1e11 to 1e16 eV neutrinos for which observatories (e.g., AMANDA and IceCube) that utilize optical Cherenkov radiation detectors are designed, radio and acoustic methods are suited for searches for the very low fluxes of neutrinos with energies >1017 eV. This is because, due to the very long attenuation lengths of radio and acoustic waves in ice and salt, detection modules can be spaced very far apart. In this paper, I calculate the absorption and scattering coefficients as a function of frequency and grain size for acoustic waves in glacial ice and salt domes and show that experimental measurements on laboratory samples and in glacial ice and salt domes are consistent with theory. For South Pole ice with grain size 0.2 cm at -51 degrees C, scattering lengths are calculated to be 2000 km and 25 km at 10 kHz and 30 kHz, respectively, and the absorption length is calculated to be 9 km at frequencies above 100 Hz. For NaCl (rock salt) with grain size 0.75 cm, scattering lengths are calculated to be 120 km and 1.4 km at 10 kHz and 30 kHz, and absorption lengths are calculated to be 30,000 km and 3300 km at 10 kHz and 30 kHz. Existing measurements are consistent with theory. For ice, absorption is the limiting factor; for salt, scattering is the limiting factor.

  12. Glacial Energy Holdings (District of Columbia) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration < GeothermalGildemeisterGlacial

  13. Glacial Energy Holdings (New Hampshire) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan) Jump

  14. Glacial Energy Holdings (New York) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/Exploration <Glacial Energy Holdings (Michigan)

  15. Acetate-Bridged Platinum(III) Complexes Derived from Cisplatin

    E-Print Network [OSTI]

    Wilson, Justin J.

    Oxidation of the acetate-bridged half-lantern platinum(II) complex cis-[Pt[superscript II](NH[subscript 3])[subscript 2](?-OAc)[subscript 2]Pt[superscript II](NH[subscript 3])[subscript 2

  16. Microorganisms having enhanced resistance to acetate and methods of use

    DOE Patents [OSTI]

    Brown, Steven D; Yang, Shihui

    2014-10-21T23:59:59.000Z

    The present invention provides isolated or genetically modified strains of microorganisms that display enhanced resistance to acetate as a result of increased expression of a sodium proton antiporter. The present invention also provides methods for producing such microbial strains, as well as related promoter sequences and expression vectors. Further, the present invention provides methods of producing alcohol from biomass materials by using microorganisms with enhanced resistance to acetate.

  17. The glacial North Atlantic Oscillation Flavio Justino and W. Richard Peltier

    E-Print Network [OSTI]

    Peltier, W. Richard

    The glacial North Atlantic Oscillation Flavio Justino and W. Richard Peltier Department of Physics: Justino, F., and W. R. Peltier (2005), The glacial North Atlantic Oscillation, Geophys. Res. Lett., 32, L. Climate simulations [e.g., Justino et al., 2005; Peltier and Solheim, 2004; Shin et al., 2003; Hewitt et

  18. A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a,

    E-Print Network [OSTI]

    Sachs, Julian P.

    A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a, , R in paleoceanography. We present evidence from ten equatorial Pacific Ocean sediment cores to show that the deep Pacific Ocean likely stored more carbon during the last glacial period than the Holocene

  19. True to Milankovitch: Glacial Inception in the new Community Climate System Model.

    E-Print Network [OSTI]

    Jochum, Markus

    True to Milankovitch: Glacial Inception in the new Community Climate System Model. 1 2 3 4 Markus42 ability of climate models to anticipate the evolution of climate in the future.43 2 #12 Circulation Models (GCMs) have57 failed to reproduce glacial inception, the cooling and increase in snow

  20. Post-glacial redistribution and shifts in productivity of giant kelp forests

    E-Print Network [OSTI]

    Grosberg, Rick

    Post-glacial redistribution and shifts in productivity of giant kelp forests Michael H. Graham1 kelp (Macrocystis pyrifera) forest distribution as a function of oceanography and geomorphology suggest that kelp forest bio- mass increased up to threefold from the glacial maximum to the mid

  1. Recent glacially influenced sedimentary processes on the East Greenland continental slope and deep Greenland Basin

    E-Print Network [OSTI]

    Jakobsson, Martin

    Recent glacially influenced sedimentary processes on the East Greenland continental slope and deep Greenland Basin Marga Garca a,*, Julian A. Dowdeswell a , Gemma Ercilla b , Martin Jakobsson c a Scott June 2012 Available online xxx Keywords: Greenland Basin Glacially influenced sedimentary processes

  2. Circulation induced by subglacial discharge in glacial fjords: Results from idealized numerical simulations

    E-Print Network [OSTI]

    deYoung, Brad

    and ice caps are among the systems that show the most significant response to warming (Solomon et al, 1980). In some subpolar glacial fjords, however, the glacial ice melting can be masked by the much., 2007). For example, substantial reductions of the sea-ice pack extent may lead to important changes

  3. Abstract A novel succinic acid-producing bacterium was isolated from bovine rumen. The bacterium is a

    E-Print Network [OSTI]

    succinic acid, acetic acid and formic acid at a constant ratio of 2:1:1. When M. succiniciproducens MBEL55E of the tricarboxylic acid (TCA) cycle and also as one of the fermentation products of anaerobic metabo- lism (Gottschalk 1986; Zeikus 1980). Fermentative pro- duction of succinic acid from renewable biomass has re

  4. Post-glacial rebound and asthenosphere viscosity in Iceland

    SciTech Connect (OSTI)

    Sigmundsson, F. (Univ. of Colorado, Boulder (United States))

    1991-06-01T23:59:59.000Z

    During the Weichselian glaciation Iceland was covered with an ice cap which caused downward flexure of the Earth's surface. The post-glacial rebound in Iceland was very rapid, being completed in about 1,000 years. The length of this time interval constrains the maximum value of asthenosphere viscosity in Iceland to be 1 {times} 10{sup 19} Pa s or less. Further clarification of the ice retreat and uplift history may reveal lower viscosity. Current changes in the mass balance of Icelandic glaciers must lead to measurable elevation changes considering this low viscosity. Expected current elevation changes around the Vatnajoekull ice cap are of the order of 1 cm per year, due to mass balance change in this century.

  5. Resonant spin tunneling in randomly oriented nanospheres of Mn?? acetate

    SciTech Connect (OSTI)

    Lendinez, S. [Univ. de Barcelona, Barcelona, Spain (Europe); Billinge, S. J. L. [Columbia Univ., New York, NY (United States); Zarzuela, R. [Univ. de Barcelona, Barcelona, Spain (Europe); Tejada, J. [Univ. de Barcelona, Barcelona, Spain (Europe); Terban, M. W. [Columbia Univ., New York, NY (United States); Espin, J. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Imaz, I. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Maspoch, D. [Univ. Autonoma Barcelona, Barcelona, Spain (Europe); Chudnovsky, E. M. [City Univ. of New York, Bronx, NY (United States)

    2015-01-01T23:59:59.000Z

    We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn?? acetate have been fabricated and characterized by chemical, infrared, TEM, X-ray, and magnetic methods. Magnetic measurements have revealed sharp tunneling peaks in the field derivative of the magnetization that occur at the typical resonant field values for the Mn?? acetate crystal in the field parallel to the easy axis.Theoretical analysis is provided that explains these observations. We argue that resonant spin tunneling in a molecular magnet can be established in a powder sample, without the need for a single crystal and without aligning the easy magnetization axes of the molecules. This is confirmed by re-analyzing the old data on a powdered sample of non-oriented micron-size crystals of Mn?? acetate. Our findings can greatly simplify the selection of candidates for quantum spin tunneling among newly synthesized molecular magnets.

  6. Atlantic Ocean circulation at the last glacial maximum : inferences from data and models

    E-Print Network [OSTI]

    Dail, Holly Janine

    2012-01-01T23:59:59.000Z

    This thesis focuses on ocean circulation and atmospheric forcing in the Atlantic Ocean at the Last Glacial Maximum (LGM, 18-21 thousand years before present). Relative to the pre-industrial climate, LGM atmospheric CO? ...

  7. Tropical climate variability from the last glacial maximum to the present

    E-Print Network [OSTI]

    Dahl, Kristina Ariel

    2005-01-01T23:59:59.000Z

    This thesis evaluates the nature and magnitude of tropical climate variability from the Last Glacial Maximum to the present. The temporal variability of two specific tropical climate phenomena is examined. The first is the ...

  8. Dynamical Reconstruction of Upper-Ocean Conditions in the Last Glacial Maximum Atlantic

    E-Print Network [OSTI]

    Wunsch, Carl

    Proxies indicate that the Last Glacial Maximum (LGM) Atlantic Ocean was marked by increased meridional and zonal near sea surface temperature gradients relative to today. Using a least squares fit of a full general circulation ...

  9. Biogas Production through the Syntrophic Acetate-Oxidising Pathway

    E-Print Network [OSTI]

    Biogas Production through the Syntrophic Acetate-Oxidising Pathway Characterisation and Detection Uppsala 2012 #12;Acta Universitatis agriculturae Sueciae 2012:45 #12;Biogas production through 1.1 Aims of the thesis 12 2 Biogas production 15 2.1 Biogas production in Europe 16 2.2 Substrate

  10. acetate based materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acetate based materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Kinetics and Mechanism of...

  11. Optimization of growth media components for polyhydroxyalkanoate (PHA) production from organic acids by Ralstonia eutropha

    E-Print Network [OSTI]

    Yang, Yung-Hun

    We employed systematic mixture analysis to determine optimal levels of acetate, propionate, and butyrate for cell growth and polyhydroxyalkanoate (PHA) production by Ralstonia eutropha H16. Butyrate was the preferred acid ...

  12. Comparative investigation of volatile fatty acids, soluble glucides and cellulase enzymes activity

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    and Animal Nutrition, 8113, Balotesti, Romania Following a comparative study of the ruminal fermentation in buffaloes for both diets. The molar proportion of acetic acid was significantly higher in buffaloes

  13. Anabolic growth regulator enhancement of amino acid transport in L-6 myoblasts

    E-Print Network [OSTI]

    Love, Eldon Todd

    1997-01-01T23:59:59.000Z

    A series of experiments was conducted to assess the effects of trenbolone acetate, dihydrotestosterone, 170-estradiol, zeranol, zearalanone, zearalanol, dexamethasone and IGF-I on amino acid transport in L-6 myoblasts. Incubation with 10% FBS for 30...

  14. Mn12-acetate thin film patterns and their interaction with superconductors

    E-Print Network [OSTI]

    Kim, Kyongwan

    2009-05-15T23:59:59.000Z

    Mn12-acetate single-molecule magnets (SMMs) are nano-scale magnets showing a strong magnetic anisotropy, slow relaxation and stepwise magnetic hysteresis curves. Possible applications of Mn12-acetate, e.g. for ultra high density magnetic information...

  15. A subtropical fate awaited freshwater discharged from glacial Lake Agassiz

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Condron, Alan; Winsor, Peter

    2011-02-01T23:59:59.000Z

    The 8.2 kyr event is the largest abrupt climatic change recorded in the last 10,000 years, and is widely hypothesized to have been triggered by the release of thousands of kilometers cubed of freshwater into the North Atlantic Ocean. Using a high-resolution (1/6) global, ocean-ice circulation model we present an alternative view that freshwater discharged from glacial Lake Agassiz would have remained on the continental shelf as a narrow, buoyant, coastal current, and would have been transported south into the subtropical North Atlantic. The pathway we describe is in contrast to the conceptual idea that freshwater from this lake outburstmorespread over most of the sub-polar North Atlantic, and covered the deep, open-ocean, convection regions. This coastally confined freshwater pathway is consistent with the present-day routing of freshwater from Hudson Bay, as well as paleoceanographic evidence of this event. Using a coarse-resolution (2.6) version of the same model, we demonstrate that the previously reported spreading of freshwater across the sub-polar North Atlantic results from the inability of numerical models of this resolution to accurately resolve narrow coastal flows, producing instead a diffuse circulation that advects freshwater away from the boundaries. To understand the climatic impact of freshwater released in the past or future (e.g. Greenland and Antarctica), the ocean needs to be modeled at a resolution sufficient to resolve the dynamics of narrow, coastal buoyant flows.less

  16. A subtropical fate awaited freshwater discharged from glacial Lake Agassiz

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Condron, Alan [Univ. of Massachusetts, Amherst, MA (United States). Climate System Research Center, Dept. of Geosciences; Winsor, Peter [Univ. of Alaska, Fairbanks, AK (United States). Inst. of Marine Science, School of Fisheries and Ocean Sciences

    2011-02-01T23:59:59.000Z

    The 8.2 kyr event is the largest abrupt climatic change recorded in the last 10,000 years, and is widely hypothesized to have been triggered by the release of thousands of kilometers cubed of freshwater into the North Atlantic Ocean. Using a high-resolution (1/6) global, ocean-ice circulation model we present an alternative view that freshwater discharged from glacial Lake Agassiz would have remained on the continental shelf as a narrow, buoyant, coastal current, and would have been transported south into the subtropical North Atlantic. The pathway we describe is in contrast to the conceptual idea that freshwater from this lake outburst spread over most of the sub-polar North Atlantic, and covered the deep, open-ocean, convection regions. This coastally confined freshwater pathway is consistent with the present-day routing of freshwater from Hudson Bay, as well as paleoceanographic evidence of this event. Using a coarse-resolution (2.6) version of the same model, we demonstrate that the previously reported spreading of freshwater across the sub-polar North Atlantic results from the inability of numerical models of this resolution to accurately resolve narrow coastal flows, producing instead a diffuse circulation that advects freshwater away from the boundaries. To understand the climatic impact of freshwater released in the past or future (e.g. Greenland and Antarctica), the ocean needs to be modeled at a resolution sufficient to resolve the dynamics of narrow, coastal buoyant flows.

  17. Production of volatile fatty acids as a result of bacterial interactions in the cecum

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    that the C. butyricum strain fermented lactose and D-lactic acid to butyric and acetic acids, whereas L-lactic acid was not fermented. The V. alcalescens strain did not ferment lactose and fermented L better than D of lactose (up to 20 %) to the diet increases bacterial fermentation in the large intestine and cecum

  18. Effect of a lactic acid bacterial inoculant on the fermentation characteristics of cereal and alfalfa forages

    E-Print Network [OSTI]

    Boyer, Edmond

    fermentation (lowering pH, increasing lactic acid to acetic acid ratio, reducing ammonia), especially underEffect of a lactic acid bacterial inoculant on the fermentation characteristics of cereal and corn. Data on the effect of inoculants on the fermentation characteristics of cereal silages

  19. Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation

    E-Print Network [OSTI]

    Zhang, Xumu

    Highly ecient kinetic resolution of 2-cyclohexenyl acetate in Pd-catalyzed allylic alkylation James resolution of 2-cyclohexenyl acetate was observed during alkylation. In addition, the reactivity and enantioselectivity showed a strong dependence on the acetate salt with the BSA/MOAc (M=alkali metal) base system

  20. Effect of Ethanol, Acetate, and Phenol on Toluene Degradation Activity and todlux

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Effect of Ethanol, Acetate, and Phenol on Toluene Degradation Activity and tod­lux Expression with increasing influent concentrations of ethanol, acetate, or phenol. Three inhibitory mechanisms were) by acetate and ethanol, which was quantified by a decrease in specific bioluminescence; (2) competitive

  1. DETERMINATION OF IVERMECTIN IN MILK BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    occurring fermentation products (Miwa et al 19831, exhibits a broad spectrum of activity at a very low; methanol and acetic acid were purchased from Merck (Darmstadt, FRG). Acetonitrile originated from. Operating conditions The mobile phase was 2 % glacial acetic acid in water, methanol, acetonitrile (90 ml/10

  2. EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN

    SciTech Connect (OSTI)

    Adu-Wusu, K.; Pennebaker, F.

    2010-12-22T23:59:59.000Z

    Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A study has been conducted to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. A select few of the top candidate eluants from the screening tests were subjected to actual sorption (loading) and elution tests to confirm their elution ability. The actual sorption (loading) and elution tests mimicked the typical sRF-cesium ion exchange process (i.e., sorption or loading, caustic wash, water rinse, and elution) via batch contact sorption and quasi column caustic wash/water rinse/elution. The eluants tested included ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, and nitric acid. Calcium acetate and magnesium acetate were substitutes for calcium chloride and magnesium chloride respectively due to corrosion concerns. Nitric acid was selected for benchmarking since it is the baseline cesium eluant for sRF resin. The cesium elution performance of ammonium carbonate and ammonium acetate was approximately the same as the benchmark eluant, nitric acid. Ninety-seven (97), 94, and 100% percent of the cesium sorbed or loaded were eluted by ammonium carbonate, ammonium acetate, and nitric acid was respectively. The performance of calcium acetate and magnesium acetate, on the other hand, was mediocre. Percent elution was 16 and 8 respectively.

  3. North Atlantic control on precipitation pattern in the eastern Mediterranean/Black Sea region during the last glacial

    E-Print Network [OSTI]

    Gilli, Adrian

    study of climate change during the last glacial maximum and late-glacial period in the Black Sea region-scale climate variability carried out in the Mediterranean Sea have demonstrated that this region reacted very sensitively to rapid climatic and oceanographic changes in the North Atlantic realm related to the well

  4. Influence of present day and glacial surface conditions on the Antarctic Oscillation/Southern Annular Mode

    E-Print Network [OSTI]

    Peltier, W. Richard

    /Southern Annular Mode Flavio Justino1,2 and W. Richard Peltier1 Received 23 May 2006; revised 5 October 2006., and W. R. Peltier (2006), Influence of present day and glacial surface conditions on the Antarctic around the Antarctic Peninsula [e.g., Peltier and Solheim, 2004], it might be expected that significantly

  5. Clay minerals in late glacial and Holocene sediments of the northern and southern Aegean Sea

    E-Print Network [OSTI]

    Siebel, Wolfgang

    Clay minerals in late glacial and Holocene sediments of the northern and southern Aegean Sea Werner Different source areas, oceanography and climate regimes influenced the clay mineral assemblages and grain and the Holocene. In the North Aegean Sea, clay mineral composition is mainly controlled by sea level evolution

  6. Glacial geology of the West Tensleep Drainage Basin, Bighorn Mountains, Wyoming

    SciTech Connect (OSTI)

    Burggraf, G.B.

    1980-08-01T23:59:59.000Z

    The glacial deposits of the West Tensleep Basin in the Bighorn Mountains of Wyoming are mapped and a relative chromology established. The deposits are correlated with the regional model as defined in the Wind River Mountains. A statistical analysis is performed on the density and weathering characteristics of the surficial boulders to determine their validity as indicators of relative age. (ACR)

  7. Simulation of glacial Cycles with an Earth System Model of intermediate

    E-Print Network [OSTI]

    Calov, Reinhard

    Statistical-Dynamical Atmosphere Model (POTSDAM) Surface Energy and Mass balance Interface (SEMI) annual mass circulation Conclusions and outlook #12;Earth system model of intermediate complexity CLIMBER-2 Petoukhov et of THC are important to fully complete the glacial terminations. #12;Outlook Close the carbon cycle

  8. WHAT CAUSED THE GLACIAL/INTERGLACIAL ATMOSPHERIC pCO2 CYCLES?

    E-Print Network [OSTI]

    Winguth, Arne

    effect on CaCO3 preservation in the sediments, to evaluate the current proposals for explaining with CaCO3 the model is unable to generate glacial pCO2 by increasing ocean NO3 but predicts relatively invariant by equilibrium with CaCO3. A third possibility, which challenges physical oceanogra

  9. Smallmouth Bass Seasonal Dynamics in Northeastern South Dakota Glacial Lakes Thomas D. Bacula

    E-Print Network [OSTI]

    Department of Game, Fish and Parks, and South Dakota State University. #12;iv ABSTRACT Smallmouth BassSmallmouth Bass Seasonal Dynamics in Northeastern South Dakota Glacial Lakes BY Thomas D. Bacula and Fisheries Science (Fisheries Option) South Dakota State University 2009 #12;11 Smallmouth Bass Seasonal

  10. Hillslope glacier coupling: The interplay of topography and glacial dynamics in High Asia

    E-Print Network [OSTI]

    Bookhagen, Bodo

    Hillslope glacier coupling: The interplay of topography and glacial dynamics in High Asia Dirk. Here we provide a regional synthesis of the topography and flow characteristics of 287 glaciers across High Asia using digital elevation analysis and remotely sensed glacier surface velocities. Glaciers

  11. The chronology of the Last Glacial Maximum and deglacial events in central Argentine Patagonia

    E-Print Network [OSTI]

    The chronology of the Last Glacial Maximum and deglacial events in central Argentine Patagonia and deglaciation in the Lago Pueyrredo´n valley of central Patagonia, 47.5 S, Argentina. The valley was a major and the onset of deglaciation occurred broadly synchronously throughout Patagonia. Deglaciation resulted

  12. Evolution of supra-glacial lakes across the Greenland Ice Sheet

    E-Print Network [OSTI]

    Sundal, Aud

    2008-12-05T23:59:59.000Z

    We used 268 cloud-free Moderate-resolution Imaging Spectroradiometer (MODIS) images spanning the melt seasons 2003 and 2005-2007 to study the seasonal evolution of supra-glacial lakes in three different regions of the Greenland ice sheet. Lake area...

  13. Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period

    E-Print Network [OSTI]

    Price, P. Buford

    Globally synchronous ice core volcanic tracers and abrupt cooling during the last glacial period R ash layers determined by remote optical borehole logging and core assays. We find that the Antarctic. These globally coincident volcanics were associated with abrupt cooling, often simultaneous with onsets or sudden

  14. Rapid sea level rise along the Antarctic margins driven by increased glacial1 Supplementary material4

    E-Print Network [OSTI]

    Naveira Garabato, Alberto

    Rapid sea level rise along the Antarctic margins driven by increased glacial1 discharge2 3 of the signal of anomalously rapid sea level rise in the41 Antarctic subpolar seas at the core of this study.42, the Antarctic coastal sea level rise signal is significantly different from47 zero with 95% confidence

  15. Detecting sub-glacial aquifers in the north polar layered deposits with Mars Express/MARSIS

    E-Print Network [OSTI]

    Gurnett, Donald A.

    water ice cap and underlying dusty-ice polar layered deposits or PLD) via melting from ice insulation effects, local geothermal hot spots, or heat-generating glacial sliding. Ice cap basal melting may at the ice/rock interface under the Antarctic ice cap [Oswald and Robin, 1973]. Clifford [1987, 1993] has

  16. Viscous flow lobes in central Taylor Valley, Antarctica: Origin as remnant buried glacial ice

    E-Print Network [OSTI]

    Marchant, David R.

    its terminus, the ESL flows at a rate of 2.4 to 6.7 mm a-1 . The loose drift that caps the buried ice temperatures show that intermittent melting is most likely possible during summer months where buried ice is 35Viscous flow lobes in central Taylor Valley, Antarctica: Origin as remnant buried glacial ice Kate

  17. Influence of Gizzard Shad on Fish Community Ecology in Northeastern South Dakota Glacial Lakes

    E-Print Network [OSTI]

    South Dakota Glacial Lakes By Justin A. VanDeHey and David W. Willis Department of Wildlife Administrator Wildlife Division Director Geno Adams Tony Leif Grants Coordinator Tanna Zabel #12;ii- Chutz, Landon Peirce, Luke Schultz and Breanna VanDeHey. Funding for this project was provided

  18. Process for the preparation of protected 3-amino-1,2-dihydroxypropane acetal and derivatives thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I. (Haslett, MI); Wang, Guijun (East Lansing, MI)

    2000-01-01T23:59:59.000Z

    A process for producing protected 3-amino-1,2-dihydroxypropane acetal, particularly in chiral forms, for use as an intermediate in the preparation of various 3-carbon compounds which are chiral. In particular, the present invention relates to the process for preparation of 3-amino-1,2-dihydroxypropane isopropylidene acetal. The protected 3-amino-1,2-dihydroxypropane acetal is a key intermediate to the preparation of chiral 3-carbon compounds which in turn are intermediates to various pharmaceuticals.

  19. acetic acid-catalyzed hydrothermal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    offer distinct advantages in being able to process a wide variety of biomass feedstocks, the composition of the feedstock will have a large effect on the processing...

  20. Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts

    E-Print Network [OSTI]

    Bao, Xinhe

    on an indirect route via synthesis gas (syngas), i.e., methane is first con- verted to syngas before it is further transformed into other useful products [6]. However, the production of syngas from methane) 130:286290 DOI 10.1007/s10562-009-0017-9 #12;[12], which is produced from syngas feedstock with Cu

  1. E-Print Network 3.0 - acetate-based multi-residue method Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Topic T4 Claudia Hildenbrand 274 EDLC electrodes from cellulose-based carbon aerogels: influence of Summary: organic aerogels. Cellulose-acetate-based organic aerogels...

  2. Modelling of mineral dust for interglacial and glacial climate conditions with a focus on Antarctica

    SciTech Connect (OSTI)

    Sudarchikova, Natalia; Mikolajewicz, Uwe; Timmreck, C.; O'Donnell, D.; Schurgers, G.; Sein, Dmitry; Zhang, Kai

    2015-01-01T23:59:59.000Z

    Mineral dust cycle responds to insolation-induced climate change and plays an important role in the climate system by affecting the radiative balance of the atmosphere. Polar ice cores provide unique information about deposition of aeolian dust particles in the past which indicates climate variability. In the current study the dust cycle in different climate conditions simulated by ECHAM5-HAM is analyzed. The study is focused on the Southern Hemisphere with emphasis on the Antarctic region. The investigated periods include four interglacial time-slices: the pre-industrial control (CTRL), mid-Holocene (6,000 years BP), Eemian (126,000 years BP), last glacial inception (115,000 years BP) and one glacial time interval: Last Glacial Maximum (LGM) (21,000 years BP). This study is a first attempt to simulate past interglacial dust cycles and to understand the quantitative contribution of different processes, such as emission, atmospheric transport and precipitation to the total dust deposition in Antarctica. Results suggest increased deposition of mineral dust globally and in Antarctica in the past interglacial periods relative to the preindustrial CTRL simulation. Maximum dust deposition in Antarctica was simulated for the glacial period. One of the major factors responsible for the increase of dust deposition in the mid-Holocene and Eemian is enhanced Southern Hemisphere dust emissions. The moderate change of dust deposition in Antarctica in the last glacial inception period is caused by the slightly stronger poleward atmospheric transport efficiency compared to the pre-industrial. In the LGM simulation, dust deposition over Antarctica is substantially increased due to 2.6 times higher Southern Hemisphere dust emissions, 2 times stronger atmospheric transport towards Antarctica, and 30% weaker precipitation over the Southern Ocean. The model is able to reproduce the order of magnitude of dust deposition globally and in Antarctica for the pre-industrial and LGM climate. However more records are needed to validate simulated dust deposition for the past interglacial time-slices.

  3. Climatic implications of correlated upper Pleistocene glacial and fluvial deposits on the Cinca and Gallego rivers, NE Spain

    SciTech Connect (OSTI)

    Lewis, Claudia J [Los Alamos National Laboratory; Mcdonald, Eric [NON LANL; Sancho, Carlos [NON LANL; Pena, Jose- Luis [NON LANL

    2008-01-01T23:59:59.000Z

    We correlate Upper Pleistocene glacial and fluvial deposits of the Cinca and Gallego River valleys (south central Pyrenees and Ebro basin, Spain) using geomorphic position, luminescence dates, and time-related trends in soil development. The ages obtained from glacial deposits indicate glacial periods at 85 {+-} 5 ka, 64 {+-} 11 ka, and 36 {+-} 3 ka (from glacial till) and 20 {+-} 3 ka (from loess). The fluvial drainage system, fed by glaciers in the headwaters, developed extensive terrace systems in the Cinca River valley at 178 {+-} 21 ka, 97 {+-} 16 ka, 61 {+-} 4 ka, 47 {+-} 4 ka, and 11 {+-} 1 ka, and in the Gallego River valley at 151 {+-} 11 ka, 68 {+-} 7 ka, and 45 {+-} 3 ka. The times of maximum geomorphic activity related to cold phases coincide with Late Pleistocene marine isotope stages and heinrich events. The maximum extent of glaciers during the last glacial occurred at 64 {+-} 11 ka, and the terraces correlated with this glacial phase are the most extensive in both the Cinca (61 {+-} 4 ka) and Gallego (68 {+-} 7 ka) valleys, indicating a strong increase in fluvial discharge and availability of sediments related to the transition to deglaciation. The global Last Glacial Maximum is scarcely represented in the south central Pyrenees owing to dominantly dry conditions at that time. Precipitation must be controlled by the position of the Iberian Peninsula with respect to the North Atlantic atmospheric circulation system. The glacial systems and the associated fluvial dynamic seem sensitive to (1) global climate changes controlled by insolation, (2) North Atlantic thermohaline circulation influenced by freshwater pulses into the North Atlantic, and (3) anomalies in atmospheric circulation in the North Atlantic controlling precipitation on the Iberian peninsula. The model of glacial and fluvial evolution during the Late Pleistocene in northern Spain could be extrapolated to other glaciated mountainous areas in southern Europe.

  4. Effect of 2-bromoethanesulfonic acid, a methanogen inhibitor, on fermentation

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    -spectrometer. Results and Discussion Addition of BES to rumen incubations shifted the fermentation from acetate (786Effect of 2-bromoethanesulfonic acid, a methanogen inhibitor, on fermentation in the rumen of rumen and hindgut fermenta- tion differs as, in contrast to rumen fermentation hindgut fermentation uses

  5. Effects on milk yield and composition of infusions of volatile fatty acids and caseinate into

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Effects on milk yield and composition of infusions of volatile fatty acids and caseinate isoenergetic infusions of either a low (17 mol/day of 64% acetic, 21% propionic and 15% butyric acids) or high that with infusions, energy and nitrogen needs were met and consisted of 60% maize silage, 10% hay, 21.5% energy

  6. Antimicrobial activity of L. plantarum, isolated from a traditional lactic acid fermentation of table olives

    E-Print Network [OSTI]

    Boyer, Edmond

    of approximately 50 kg.mol1. The presence of another compound of different properties and with a molecular mass) is due to the accumulation of main primary metabolites (lactic and acetic acids, ethanol and carbon dioxide) as well as to the production of other antimicrobial com- pounds, such as formic and benzoic acids

  7. Zymomonas with improved ethanol production in medium containing concentrated sugars and acetate

    DOE Patents [OSTI]

    Caimi, Perry G. (Kennett Square, PA); Chou, Yat-Chen (Lakewood, CO); Franden, Mary Ann (Centennial, CO); Knoke, Kyle (Newark, DE); Tao, Luan (Havertown, PA); Viitanen, Paul V. (West Chester, PA); Zhang, Min (Lakewood, CO); Zhang, Yuying (New Hope, PA)

    2010-09-28T23:59:59.000Z

    Through screening of a Zymomonas mutant library the himA gene was found to be involved in the inhibitory effect of acetate on Zymomonas performance. Xylose-utilizing Zymomonas further engineered to reduce activity of the himA gene were found to have increased ethanol production in comparison to a parental strain, when cultured in medium comprising xylose and acetate.

  8. Temperature-Controlled Regioselectivity in the Reductive Cleavage of p-Methoxybenzylidene Acetals

    E-Print Network [OSTI]

    Wei, Alexander

    Temperature-Controlled Regioselectivity in the Reductive Cleavage of p-Methoxybenzylidene Acetals The regioselective ring opening of pyranosidic 4,6-p-methoxybenzylidene acetals with BH3/Bu2BOTf in THF can be tuned-sensitive functional groups, including allyl and enol ethers. The presence of water does not interfere with reductive

  9. Kinetic and spectroscopic studies of vinyl acetate synthesis over Pd(100)

    E-Print Network [OSTI]

    Goodman, Wayne

    ,b , M.S. Chena , and D.W. Goodmana, * a Department of Chemistry, Texas A&M University, P.O. Box 30012 for the production of polymers such as, polyvinyl acetate and vinyl acetate copolymers [1]. Currently, VA), For XPS analysis, MgKaradiation (300 W, pass energy 58.7 eV) was used, and the spectra referenced

  10. The role of carbon dioxide in the biosynthesis of tyrosine in Lactobacillus arabinosus

    E-Print Network [OSTI]

    Simmons, John Wesley

    1962-01-01T23:59:59.000Z

    obtained from material crystallized from glacial acetic acid (fraction V-4) ----------- 42 LIST OF FIGURES Page Figure 1 Figure 2 Apparatus used for tyrosine synthesis and shikimic acid studies 43 Flow diagram of air-C 0 in apparatus for 14... of combined lacial ac tic acid su ernstant. The com- bined acetic acid supernatant was refrigerated, and the precipitate, after vacuum distillation with water, was combined with the aqueous fraction. The supernatant was saved, and the combined aqueous...

  11. aldehydes acetals carboxylic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  12. aldehyde acetals carboxylic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  13. The last GlacialeInterglacial transition in Patagonia, Argentina: the stable isotope record of bulk sedimentary organic matter from Laguna

    E-Print Network [OSTI]

    The last GlacialeInterglacial transition in Patagonia, Argentina: the stable isotope record of bulk cores recovered from the Patagonian lake Laguna Potrok Aike (Argentina) in the framework of the ICDP

  14. Ultra-low rare earth element content in accreted ice from sub-glacial Lake Vostok, Antarctica

    E-Print Network [OSTI]

    Howat, Ian M.

    Ultra-low rare earth element content in accreted ice from sub-glacial Lake Vostok, Antarctica Paolo. We suggest that such ultra-low concentrations are unlikely to be representative of the real REE

  15. Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate

    E-Print Network [OSTI]

    Tu, TungSheng

    2013-01-01T23:59:59.000Z

    monomer process design. Chemical Engineering Communications,design/control study for the vinyl acetate monomer process. Computers & Chemical Engineering,

  16. Effect of Shear on Gelation of Polyacrylamide-Chromium Acetate Gelant in a Circular Tube

    E-Print Network [OSTI]

    Li, Xianping

    2010-11-26T23:59:59.000Z

    This research studies the gelation and flow properties of a partially hydrolyzed polyacrylamide (HPAM)-chromium acetate gel system under shear conditions. Gelation was observed in steady shear on a rheometer and during injection through a 1,031-ft...

  17. Hole-mediated Photodecomposition of Trimehtyl Acetate on a TiO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acetate on a TiO2(001) Anatase Epitaxial Thin Film Surface. Abstract: Surfaces of titanium dioxide in both rutile and anatase polymorphs have attracted significant attention in...

  18. Selective Monoarylation of Acetate Esters and Aryl Methyl Ketones Using Aryl Chlorides

    E-Print Network [OSTI]

    Biscoe, Mark R.

    Simple, efficient procedures for the monoarylation of acetate esters and aryl methyl ketones using aryl chlorides are presented. Previously, no general method was available to ensure the highly selective monoarylation of ...

  19. Zymomonas with improved ethanol production in medium containing concentrated sugars and acetate

    DOE Patents [OSTI]

    Caimi, Perry G. (Kennett Square, PA); Chou, Yat-Chen (Lakewood, CO); Franden, Mary Ann (Centennial, CO); Knoke, Kyle (Newark, DE); Tao, Luan (Havertown, PA); Viitanen, Paul V. (West Chester, PA); Zhang, Min (Lakewood, CO); Zhang, Yuying (New Hope, PA)

    2011-03-01T23:59:59.000Z

    Through screening of a Zymomonas mutant library the himA gene was found to be involved in the inhibitory effect of acetate on Zymomonas performance. Xylose-utilizing Zymomonas strains further engineered to reduce activity of the himA gene were found to have increased ethanol production in comparison to a parental strain, when cultured in mixed-sugars medium comprising xylose, and, in particular, in the presence of acetate.

  20. Pour-depressant activity of copolymers of ethylene with vinyl acetate in diesel fuel

    SciTech Connect (OSTI)

    Dushechkin, A.P.; Ivanov, V.I.; Elagin, A.L.; Levin, A.A.

    1987-01-01T23:59:59.000Z

    The authors investigate the influence of the degree of branching of the ethylene-vinyl acetate copolymers (EVAC) on the limiting filterability temperature and the solid point of diesel fuels. EVAC samples with identical contents of vinyl acetate and having a molecular weight of 4500-7200 were used. The pour-depressant activity of the copolymers was determined in diesel fuel. It is shown that the degree of branching of EVAC has a substantial influence on the depressant activity in diesel fuel.

  1. Paleoclimatic significance of Middle Pleistocene glacial deposits in the Kotzebue Sound region, northwest coastal Alaska

    SciTech Connect (OSTI)

    Roof, S.R.; Brigham-Grette, J. (Univ. of Massachusetts, Amherst, MA (United States))

    1992-01-01T23:59:59.000Z

    During Middle Pleistocene time, glaciers extended from the western Brooks Range in NW Alaska to the coast at Kotzebue Sound, forming Baldwin Peninsula, a 120 km-long terminal moraine. Marine, glacigenic, and fluvial facies exposed along coastal bluffs surrounding Kotzebue Sound and Hotham Inlet indicate that at least the initial stages of the glacial advance occurred while sea level was high enough to cover the shallow Bering Shelf. Although it is presently uncertain if the ice actually reached tidewater before extensive middle-latitude ice-sheet formation, the marine and glacigenic facies clearly indicate that this advance must have occurred significantly out-of-phase with lower latitude glaciation. The authors believe an ice-free Bering Sea provided the moisture for glacier growth during the waning phases of a global interglacial climate. Although the magnitude of the Baldwin Peninsula advance was large compared to late Pleistocene advances, the timing with respect to sea level is consistent with observations by Miller and de Vernal that late Pleistocene polar glaciations also occurred near the end of interglacial periods, when global sea level was high, high-latitude oceans were relatively warm, and summer insolation was decreasing. An important implication of this out-of-phase glaciation hypothesis is that the critical transition point between climate states may be earlier in the interglacial-glacial cycle than previously thought. Because it appears that climate change is initiated in polar regions while the rest of Earth is experiencing an interglacial climate, many of their climate models must be revised. The glacial record at Baldwin Peninsula provides an opportunity to test, revise, and perhaps extend this out-of-phase glaciation hypothesis to the middle Pleistocene interval.

  2. Constraints on soluble aerosol iron flux to the Southern Ocean at the Last Glacial Maximum

    E-Print Network [OSTI]

    Conway, T. M.; Wolff, E. W.; Rthlisberger, R.; Mulvaney, R.; Elderfield, H. E.

    2015-06-17T23:59:59.000Z

    that an increase in bioavailable atmospheric Fe supply of 5-10x could double export 207 production40, meaning the LGM EDC soluble Fe flux could be large enough to drive big changes in 208 primary productivity, nutrient utilization and carbon sequestration... of iron-limitation in the Southern Ocean during ice ages, with potentially increased carbon storage 3 in the ocean, has been invoked as one driver of glacial-interglacial atmospheric CO2 cycles. Ice and 4 marine sediment records demonstrate...

  3. Quercetin and Chlorogenic Acid Mitigate DSS-Induced Changes in Expression of Select Pro-Inflammatory Cytokines and Short Chain Fatty Acid Transporter Genes

    E-Print Network [OSTI]

    Piefer, Leigh

    2012-10-19T23:59:59.000Z

    oxide synthase LPS lipopolysaccharide LS least squares MCT-1 monocarboxylate transporter-1 MyD88 myeloid differentiation factor-88 NF-?B nuclear transcription factor kappa B PBS phosphate buffered solution PFA paraformaldehyde RT-PCR reverse... animals (acetic acid, pMCT-1 and SLC5A8 mRNA levels show that DSS significantly...

  4. Paleoclimatic inference from glacial fluctuations on Svalbard during the last 20,000 years

    SciTech Connect (OSTI)

    Svendsen, J.I.; Mangerud, J. [Univ. of Bergen (Norway)

    1992-01-01T23:59:59.000Z

    The climate history of western Spitsbergen, Svalbard is deduced from variations of glaciers during the last 20000 years. A major depression of the regional equilibrium line altitude (ELA) occurred during the Late Weichselian glacial maximum (18000-13000 y ago) when low summer temperatures may have caused year-round snow accumulation on the ground. This rapid expansion of the glaciers also indicates nearby moisture sources, suggesting partly open conditions in the Norwegian Sea during the summers. A rapid glacial retreat around 13000-12500 y BP was caused by a sudden warming. During the Younger Dryas the ELA along the extreme western coast of Spitsbergen was not significantly lower than at present. In contrast to Fennoscandia, the British Isles and the Alps, there is no evidence for readvance of local glaciers during Younger Dryas on western Spitsbergen. This difference is attributed to a much dryer climate on Spitsbergen and probably only slight changes in sea surface temperatures. In addition, summer melting in this high arctic area is more sensitive to orbitally increased insolation. Around 10000 y BP another rapid warming occurred and during early and mid Holocene the summer temperatures were significantly higher than at present. A temperature decline during the late Holocene caused regrowth of the glaciers which reached their maximum Holocene position during the last century. 72 refs., 6 figs.

  5. Silicic acid leakage from the Southern Ocean: A possible explanation for glacial atmospheric pCO2

    E-Print Network [OSTI]

    Matsumoto, Katsumi

    in diatoms when iron is added [Hutchins and Bruland, 1998; Takeda, 1998; Franck et al., 2000]. The Southern

  6. Subarctic Pacific evidence for a glacial deepening of the oceanic respired carbon pool S.L. Jaccard a,d,

    E-Print Network [OSTI]

    Gilli, Adrian

    Subarctic Pacific evidence for a glacial deepening of the oceanic respired carbon pool S.L. Jaccard of the overturning circulation. Volumetrically the Pacific Ocean dominates the world ocean (it is three times larger of Atmospheric and Oceanic Sciences, Princeton University, Princeton, USA c Department of Geosciences, Princeton

  7. Sea-salt aerosol response to climate change: Last Glacial Maximum, preindustrial, and doubled carbon dioxide climates

    E-Print Network [OSTI]

    Mahowald, Natalie

    Sea-salt aerosol response to climate change: Last Glacial Maximum, preindustrial, and doubled Received 1 July 2005; revised 31 October 2005; accepted 17 November 2005; published 2 March 2006. [1] Sea-salt their response to changes in climate represents an important potential feedback on climate. Model results for sea-salt

  8. 2 Ocean circulation at the Last Glacial Maximum: 3 A combined modeling and magnetic proxy-based study

    E-Print Network [OSTI]

    40 greater influence and penetration of deep water formed in 41 the Southern Ocean [e.g., Oppo2 Ocean circulation at the Last Glacial Maximum: 3 A combined modeling and magnetic proxy (NADW) is an important component of the ocean thermohaline 7 circulation, but debate exists over

  9. Late Glacial to Preboreal sea-level rise recorded by the previous termRhne deltaic systemnext term

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Late Glacial to Preboreal sea-level rise recorded by the previous termRhne deltaic systemnext term by progradation initiated during the first phase of the Younger Dryas, a period of reduced sea-level rise or stillstand. The delta kept pace with resumed sea-level rise during the Preboreal (which is estimated at about

  10. Temperature profile for glacial ice at the South Pole: Implications for life in a nearby subglacial lake

    E-Print Network [OSTI]

    Price, P. Buford

    by P. Buford Price, April 22, 2002 Airborne radar has detected 100 lakes under the Antarctic ice cap-induced melting temperature of freshwater ice. To produce the strong radar signal, the frozen lake must consistTemperature profile for glacial ice at the South Pole: Implications for life in a nearby subglacial

  11. Anaerobic microbial dissolution of lead and production of organic acids

    DOE Patents [OSTI]

    Francis, A.J.; Dodge, C.; Chendrayan, K.; Quinby, H.L.

    1987-04-16T23:59:59.000Z

    The present invention related to an anaerobic bacterial culture of Clostridium sp. ATCC No. 53464 which solubilizes lead oxide under anaerobic conditions in coal and industrial wastes and therefore presents a method of removing lead from such wastes before they are dumped into the environment. The rat of lead dissolution during logarithmic growth of the bacteria in 40 ml medium containing 3.32 ..mu..moles of lead as lead oxide was 0.042 ..mu..moles m1/sup /-/1/ hr/sup /-/1/. Dissolution of lead oxide by the bacterial isolate is due to the production of metabolites and acidity in the culture medium. The major metabolites are acetic, butyric and lactic acid. The major metabolites are acetic, butyric and lactic acid. Clostridium sp. ATCC No. 53464 can be used in the recovery of the strategic metals from ores and wastes and also for the production of lactic acid for commercial purposes. The process yields large quantities of lactic acid as well as lead complexed in a stable form with said acids. 4 figs., 3 tabs.

  12. Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate + methanol system

    SciTech Connect (OSTI)

    Iliuta, M.C.; Thyrion, F.C. [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.] [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.; Landauer, O.M. [Univ. Politehnica Bucharest (Romania)] [Univ. Politehnica Bucharest (Romania)

    1996-07-01T23:59:59.000Z

    The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.

  13. Role of ocean-atmosphere interactions in tropical cooling during the last glacial maximum

    SciTech Connect (OSTI)

    Bush, A.B.G. [Univ. of Alberta, Edmonton (Canada)] [Univ. of Alberta, Edmonton (Canada); Philander, S.G.H. [Princeton Univ., NJ (United States)] [Princeton Univ., NJ (United States)

    1998-02-27T23:59:59.000Z

    A simulation with a coupled atmosphere-ocean general circulation model configured for the Last Glacial Maximum delivered a tropical climate that is much cooler than that produced by atmosphere-only models. The main reason is a decrease in tropical sea surface temperatures, up to 6{degree}C in the western tropical Pacific, which occurs because of two processes. The trade winds induce equatorial upwelling and zonal advection of cold water that further intensify the trade winds, and an exchange of water occurs between the tropical and extratropical Pacific in which the poleward surface flow is balanced by equatorward flow of cold water in the thermocline. Simulated tropical temperature depressions are of the same magnitude as those that have been proposed from recent proxy data. 25 refs., 4 figs.

  14. Nanoporous layered silicate AMH-3/cellulose acetate nanocomposite membranes for gas separations

    E-Print Network [OSTI]

    Nair, Sankar

    Nanoporous layered silicate AMH-3/cellulose acetate nanocomposite membranes for gas separations Wun 20 March 2013 Available online 9 April 2013 Keywords: Layered silicates AMH-3 Composite membrane Exfoliation Interface CO2 separation a b s t r a c t Nanoporous layered silicate/polymer composite membranes

  15. Methyl Acetate and its singly deuterated isotopomers in the interstellar medium

    E-Print Network [OSTI]

    Das, Ankan; Sahu, Dipen; Gorai, Prasanta; Sivaraman, B; Chakrabarti, Sandip K

    2015-01-01T23:59:59.000Z

    Methyl acetate (CH_3COOCH_3) has been recently observed by IRAM 30 m radio telescope in Orion though the presence of its deuterated isotopomers is yet to be confirmed. We therefore study the properties of various forms of methyl acetate, namely, CH_3COOCH_3, CH_2DCOOCH_3 and CH_3COOCH_2D. Our simulation reveals that these species could be produced efficiently both in gas as well as in ice phases. Production of methyl acetate could follow radical-radical reaction between acetyl (CH_3CO) and methoxy (CH_3O) radicals. To predict abundances of CH_3COOCH_3 along with its two singly deuterated isotopomers and its two isomers (ethyl formate and hydroxyacetone), we prepare a gas-grain chemical network to study chemical evolution of these molecules. Since gas phase rate coefficients for methyl acetate and its related species were unknown, either we consider similar rate coefficients for similar types of reactions (by following existing data bases) or we carry out quantum chemical calculations to estimate the unknown r...

  16. ACET (VREF African FUT CoE for Studies in Public and Non-motorised Transport) Centre for Transport Studies

    E-Print Network [OSTI]

    California at Berkeley, University of

    ACET projects P1: systems and behaviour P2: practices and governance P3: road safety P4: paratransit Advisory Panel (SAP) ACET Secretariat (AS) (UDSM and UONBI) University Leaders (ULs) Partner Working Committee (PWC) Project Leaders (PLs) Project Researchers (PRs) Postgraduate Students (PGs) #12;P6 PL

  17. Acetate availability and its influence on sustainable bioremediation of uranium-contaminated groundwater

    SciTech Connect (OSTI)

    Williams, Kenneth H.; Long, Philip E.; Davis, James A.; Wilkins, Michael J.; N'Guessan, A. Lucie; Steefel, Carl I.; Yang, Li; Newcomer, Darrell R.; Spane, Frank A.; Kerkhof, L.; McGuinness, L.; Dayvault, Richard; Lovley, Derek

    2011-11-01T23:59:59.000Z

    Field biostimulation experiments at the U.S. Department of Energy's Integrated Field Research Challenge (IFRC) site in Rifle, Colorado, have demonstrated that uranium concentrations in groundwater can be decreased to levels below the U.S. Environmental Protection Agency's (EPA) drinking water standard (0.126 {micro}M). During successive summer experiments - referred to as 'Winchester' (2007) and 'Big Rusty' (2008) - acetate was added to the aquifer to stimulate the activity of indigenous dissimilatory metal-reducing bacteria capable of reductively immobilizing uranium. The two experiments differed in the length of injection (31 vs. 110 days), the maximum concentration of acetate (5 vs. 30 mM), and the extent to which iron reduction ('Winchester') or sulfate reduction ('Big Rusty') was the predominant metabolic process. In both cases, rapid removal of U(VI) from groundwater occurred at calcium concentrations (6 mM) and carbonate alkalinities (8 meq/L) where Ca-UO2-CO3 ternary complexes constitute >90% of uranyl species in groundwater. Complete consumption of acetate and increased alkalinity (>30 meq/L) accompanying the onset of sulfate reduction corresponded to temporary increases in U(VI); however, by increasing acetate concentrations in excess of available sulfate (10 mM), low U(VI) concentrations (0.1-0.05 {micro}M) were achieved for extended periods of time (>140 days). Uniform delivery of acetate during 'Big Rusty' was impeded due to decreases in injection well permeability, likely resulting from biomass accumulation and carbonate and sulfide mineral precipitation. Such decreases were not observed during the short-duration 'Winchester' experiment. Terminal restriction fragment length polymorphism (TRFLP) analysis of 16S rRNA genes demonstrated that Geobacter sp. and Geobacter-like strains dominated the groundwater community profile during iron reduction, with 13C stable isotope probing (SIP) results confirming these strains were actively utilizing acetate to replicate their genome during the period of optimal U(VI) removal. Gene transcript levels during 'Big Rusty' were quantified for Geobacter-specific citrate synthase (gltA), with ongoing transcription during sulfate reduction indicating that members of the Geobacteraceae were still active and likely contributing to U(VI) removal. The persistence of reducible Fe(III) in sediments recovered from an area of prolonged (110 day) sulfate reduction is consistent with this conclusion. These results indicate that acetate availability and its ability to sustain the activity of iron- and uranyl-respiring Geobacter strains during sulfate reduction exerts a primary control on optimized U(VI) removal from groundwater at the Rifle IFRC site over extended timescales (>50 days).

  18. Nucleic acids, compositions and uses thereof

    DOE Patents [OSTI]

    Preston, III, James F. (Micanopy, FL); Chow, Virginia (Gainesville, FL); Nong, Guang (Gainesville, FL); Rice, John D. (Gainesville, FL); St. John, Franz J. (Baltimore, MD)

    2012-02-21T23:59:59.000Z

    The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

  19. Nucleic acid compositions and the encoding proteins

    DOE Patents [OSTI]

    Preston, III, James F.; Chow, Virginia; Nong, Guang; Rice, John D.; St. John, Franz J.

    2014-09-02T23:59:59.000Z

    The subject invention provides at least one nucleic acid sequence encoding an aldouronate-utilization regulon isolated from Paenibacillus sp. strain JDR-2, a bacterium which efficiently utilizes xylan and metabolizes aldouronates (methylglucuronoxylosaccharides). The subject invention also provides a means for providing a coordinately regulated process in which xylan depolymerization and product assimilation are coupled in Paenibacillus sp. strain JDR-2 to provide a favorable system for the conversion of lignocellulosic biomass to biobased products. Additionally, the nucleic acid sequences encoding the aldouronate-utilization regulon can be used to transform other bacteria to form organisms capable of producing a desired product (e.g., ethanol, 1-butanol, acetoin, 2,3-butanediol, 1,3-propanediol, succinate, lactate, acetate, malate or alanine) from lignocellulosic biomass.

  20. Modeling of the formation of short-chain acids in propane flames

    E-Print Network [OSTI]

    Battin-Leclerc, Frdrique; Jaffrezo, J L; Legrand, M

    2009-01-01T23:59:59.000Z

    In order to better understand their potential formation in combustion systems, a detailed kinetic mechanism for the formation of short-chain monocarboxylic acids, formic (HCOOH), acetic (CH3COOH), propionic (C2H5COOH) and propenic (C2H3COOH)) acids, has been developed. Simulations of lean (equivalence ratios from 0.9 to 0.48) laminar premixed flames of propane stabilized at atmospheric pressure with nitrogen as diluent have been performed. It was found that amounts up to 25 ppm of acetic acid, 15 ppm of formic acid and 1 ppm of C3 acid can be formed for some positions in the flames. Simulations showed that the more abundant C3 acid formed is propenic acid. A quite acceptable agreement has been obtained with the scarce results from the literature concerning oxygenated compounds, including aldehydes (CH2O, CH3CHO) and acids. A reaction pathways analysis demonstrated that each acid is mainly derived from the aldehyde of similar structure.

  1. Low contaminant formic acid fuel for direct liquid fuel cell

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); Zhu, Yimin (Urbana, IL); Kahn, Zakia (Palatine, IL); Man, Malcolm (Vancouver, CA)

    2009-11-17T23:59:59.000Z

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  2. Phase Preference by Active, Acetate-Utilizing Bacteria at the Rifle, CO Integrated Field Research Challenge Site

    SciTech Connect (OSTI)

    Kerkhof, L.; Williams, K.H.; Long, P.E.; McGuinness, L.

    2011-02-21T23:59:59.000Z

    Previous experiments at the Rifle, Colorado Integrated Field Research Challenge (IFRC) site demonstrated that field-scale addition of acetate to groundwater reduced the ambient soluble uranium concentration. In this report, sediment samples collected before and after acetate field addition were used to assess the active microbes via {sup 13}C acetate stable isotope probing on 3 phases [coarse sand, fines (8-approximately 150 {micro}m), groundwater (0.2-8 {micro}m)] over a 24-day time frame. TRFLP results generally indicated a stronger signal in {sup 13}C-DNA in the 'fines' fraction compared to the sand and groundwater. Before the field-scale acetate addition, a Geobacter-like group primarily synthesized {sup 13}C-DNA in the groundwater phase, an alpha Proteobacterium primarily grew on the fines/sands, and an Acinetobacter sp. and Decholoromonas-like OTU utilized much of the {sup 13}C acetate in both groundwater and particle-associated phases. At the termination of the field-scale acetate addition, the Geobacter-like species was active on the solid phases rather than the groundwater, while the other bacterial groups had very reduced newly synthesized DNA signal. These findings will help to delineate the acetate utilization patterns of bacteria in the field and can lead to improved methods for stimulating distinct microbial populations in situ.

  3. The use of low volatile carriers to increase the effectiveness of (2,4,5-trichlorophenoxy) acetic acid

    E-Print Network [OSTI]

    Hyzak, Daniel Louis

    1969-01-01T23:59:59.000Z

    resulted in cons1derably greater injury to the non-treated distil foliage of velvet mesquite than did the same herbicide applied in d1esel oil. Brender (6) recommended nonphytotoxic oils as herbic1de carriers in the control of kudzu. The latter two...:288-292. 6. Brender, E. U. 1961. Control of honeysuckle and kudzu. U. S. Forest Service, Southeast Forest Exp. Sta. paper 120. 8 pp. 7. Ennis, W. 8, , Jr. 1951. Influence of different carriers upon the inhibiting properties of growth-regulatory spray...

  4. higher proportions of propionic acid for the starchy concentrate (ie 28.8 vs 26.8%), but

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    .8%), but this difference was not significant. The pro- portion of acetic acid was significantly higher for the fibre to the present desires of the dairy industry. In vivo and in vitro fermentation of resis- tant starch Paris;3INRA, 44026 Nantes, France) The hydrogen produced during the intra- colonic fermentation

  5. Abstract Poly(acrylic acid) + zinc diacetate hybrid com-posites have been prepared by precipitation from aqueous

    E-Print Network [OSTI]

    North Texas, University of

    Polymer-based composites Poly(acrylic acid) Zinc acetate Polymer electric conductivity Dynamic for polymer-based materials (PBMs). Thermogravimetric analysis (TGA) shows that thermal de- composition begins under nitrogen. In contrast to typical PBMs, there is evidence of ionic conduction in some

  6. 5790 J. Am. Chem. SOC.1987, 109, 5790-5800 Concerted General Base and Bifunctional General Acid

    E-Print Network [OSTI]

    Cox, Michael M.

    ) no buffer catalysis, ( 2 ) general acid catalysis by diffusion-con- trolled trapping of an unstable anionic of this intermediate, with stabilization of the transition state by hydrogen bonding, and (4) a fully concerted of 4-methylphenyl acetate by me- thylamine and can be trapped by diffusion-controlled proton transfer

  7. Cooligomerization of allyl acetate with norbornadiene and its derivatives catalyzed by nickel complexes

    SciTech Connect (OSTI)

    Dzhemilev, U.M.; Khusnutdinov, R.I.; Galeev, D.K.; Tolstikov, G.A.

    1987-07-20T23:59:59.000Z

    The cyclocooligomerization of allyl acetate with norbornadiene and its derivatives to compounds which are not readily accessible in the series tricyclo(4.2.1.0/sup 2,5/)nonane, tetracyclo(4.3.0.0/sup 2,3/.0/sup 2,4/)nonane and tetracyclo(4.4.1.0/sup 2,5/.7/sup 7,10/)undecane has been achieved with yields of 60-95%, involving the participation of low-valency nickel complexes.

  8. Variations in mid-ocean ridge CO2 emissions driven by glacial cycles

    E-Print Network [OSTI]

    Burley, Jonathan M A

    2015-01-01T23:59:59.000Z

    The geological record shows links between glacial cycles and volcanic productivity, both subaerially and at mid-ocean ridges. Sea-level-driven pressure changes could also affect chemical properties of mid-ocean ridge volcanism. We consider how changing sea-level could alter the \\cotwo{} emissions rate from mid-ocean ridges, on both the segment and global scale. We develop a simplified transport model for a highly incompatible element through a homogenous mantle; variations in the melt concentration the emission rate of the element are created by changes in the depth of first silicate melting. The model predicts an average global mid-ocean ridge \\cotwo{} emissions-rate of $53$~Mt/yr, in line with other estimates. We show that falling sea level would cause an increase in ridge \\cotwo{} emissions with a lag of about $100$~kyrs after the causative sea level change. The lag and amplitude of the response are sensitive to mantle permeability and plate spreading rate. For a reconstructed sea-level time series of the ...

  9. Release of Methane from Bering Sea Sediments During the Last Glacial Period

    SciTech Connect (OSTI)

    Mea Cook; Lloyd Keigwin

    2007-11-30T23:59:59.000Z

    Several lines of evidence suggest that during times of elevated methane flux the sulfate-methane transition zone (SMTZ) was positioned near the sediment-water interface. We studied two cores (from 700 m and 1457 m water depth) from the Umnak Plateau region. Anomalously low d13C and high d18O in benthic and planktonic foraminifera in these cores are the consequence of diagenetic overgrowths of authigenic carbonates. There are multiple layers of authigenic-carbonate-rich sediment in these cores, and the stable isotope compositions of the carbonates are consistent with those formed during anaerobic oxidation of methane (AOM). The carbonate-rich layers are associated with biomarkers produced by methane-oxidizing archaea, archaeol and glyceryl dibiphytanyl glyceryl tetraether (GDGT). The d13C of the archaeol and certain GDGTs are isotopically depleted. These carbonate- and AOM-biomarker-rich layers were emplaced in the SMTZ during episodes when there was a high flux of methane or methane-rich fluids upward in the sediment column. The sediment methane in the Umnak Plateau region appears to have been very dynamic during the glacial period, and interacted with the ocean-atmosphere system at millennial time scales. The upper-most carbonate-rich layers are in radiocarbon-dated sediment deposited during interstitials 2 and 3, 28-20 ka, and may be associated with the climate warming during this time.

  10. Effect of composite microstructure on electrical and mechanical properties of poly(vinyl acetate) composites with carbon black and clay.

    E-Print Network [OSTI]

    Miriyala, Sethu M.

    2009-05-15T23:59:59.000Z

    The electrical and mechanical behavior of carbon black filled poly(vinyl acetate) latex-based and solution-based polymer composites was examined. A set of experiments were performed to distinguish composites with a segregated network (emulsion...

  11. Phase Preference by Active, Acetate-Utilizing Bacteria at the Rifle, CO Integrated Field Research Challenge Site

    SciTech Connect (OSTI)

    Kerkhoff, Lee; Williams, Kenneth H.; Long, Philip E.; McGuinness, L.

    2011-02-15T23:59:59.000Z

    Uranium contaminated groundwaters are a legacy concern for the U.S. Department of Energy. Previous experiments at the Rifle, Colorado Integrated Field Challenge (IFC) site have demonstrated that field-scale addition of acetate to groundwater reduces the ambient soluable uranium concentration, sequestering the radionuclide as uraninite. However, questions remain regarding which microorganism(s) are consuming this acetate and if active groundwater microorganisms are different from active particle-associated bacteria. In this report, 13-C acetate was used to assess the active microbes that synthesize DNA on 3 size fractions [coarse sand, fines (8-approximately 150 micron), groundwater (0.2-8 micron)] over a 24 -day time frame. Results indicated a stronger signal from 13-C acetate associated with the fines fraction compared with smaller amounts of 13-C uptake on the sand fraction and groundwater samples during the SIP incubations. TRFLP analysis of this 13-C-labeled DNA, indicated 31+ 9 OTU's with 6 peaks dominating the active profiles (166, 187, 210, 212, and 277 bp peaks using MnlI). Cloning/sequencing of the amplification products indicated a Geobacter-like group (187, 210, 212 bp) primarily synthesized DNA from acetate in the groundwater phase, an alpha Proteobacterium (166 bp) primarily grew on the fines/sands, and an Acinetobacter sp. (277 bp) utilized much of the 13C acetate in both groundwater and particle-associated phases. These findings will help to delineate the acetate utilization patterns of bacteria during field-scale acetate addition and can lead to improved methods for stimulating distinct microbial populations in situ.

  12. Dissociative Binding of Carboxylic Acid Ligand on Nanoceria Surface in Aqueous Solution: A Joint in Situ Spectroscopic Characterization and First-Principles Study

    SciTech Connect (OSTI)

    Lu, Zhou; Karakoti, Ajay S.; Velarde Ruiz Esparza, Luis A.; Wang, Weina; Yang, Ping; Thevuthasan, Suntharampillai; Wang, Hongfei

    2013-11-21T23:59:59.000Z

    Carboxylic acid is a common ligand anchoring group to functionalize nanoparticle surfaces. Its binding structures and mechanisms as a function of the oxidation states of metal oxide nanoparticle surfaces are not well characterized experimentally. We present an in situ sum frequency generation vibrational spectroscopy (SFG-VS) study on the binding of deuterated acetic acid on ceria nanoparticles in the aqueous solution. In the SFG experiment, ceria nanoparticles were deposited on the flat surface of a CaF2 hemisphere in contact with acetic acid solutions. While the ceria nanoparticle deprotonated the acetic acid, the CaF2 surface could not. Thus, the binding of the deprotonated acetic acid on ceria can be selectively probed. SFG spectra revealed that the binding modes of the carboxylate group depend on the oxidation states of the ceria surfaces. SFG polarization analysis suggested that the bidentate chelating and bridging binding modes co-exist on the reduced ceria surfaces, while the oxidized ceria surfaces are dominated by the bidentate bridging mode. The direct spectroscopic evidence helps to clarify the binding structures and mechanisms on the ceria nanoparticles. Furthermore, the middle-infrared (IR) transparent CaF2 and its chemical inertness make CaF2 and similar substrate materials good candidates for direct SFG-VS measurement of nanoparticle surface reactions and binding chem-istry.

  13. PRELIMINARY REPORT ON EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN

    SciTech Connect (OSTI)

    Adu-Wusu, K.; Pennebaker, F.

    2010-09-01T23:59:59.000Z

    Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. Studies are ongoing to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. The next phase of testing for this work will focus on the following down selected eluants: Ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, nitric acid, and ammonium hydroxide. The next testing phase is a confirmation of the elution ability of the selected eluants. It will mimic a typical sRF cesium ion exchange process i.e., sorption or loading, caustic wash, water rinse, and elution via batch contact sorption and quasi column caustic wash/water rinse/elution. Due to corrosion concerns, calcium acetate and magnesium acetate will be tested instead of calcium chloride and magnesium chloride respectively. Nitric acid is for benchmarking since it is the baseline sRF eluant. The information at hand indicates ammonium hydroxide, while a weak base, may hold promise as an effective eluant. Hence, its inclusion among the eluants to be studied despite the fact that it was not tested as a stand-alone eluant earlier.

  14. V. ANALYTICAL METHODS G. Quantitative Urinary Porphobilinogen

    E-Print Network [OSTI]

    in a 250-ml brown glass bottle: (a) P-dimethylaminobenzaldehyde, 2.0 g Sigma; protect from light (b) HCl at -20 C. at 2-8 C. For longer 3. Reagents. Supplies. and Equipment a. Glass test tubes, disposable: 16 hood): (a) Glacial acetic acid 57 ml (b) Reagent water type I QS to 1 L (2) Transfer to brown glass

  15. 9,10-Anthracenedicarbaldehyde bis[(4,5-dihydro-1H-imidazol-2-yl)hydrazone] acetic acid hydrochloric acid trihydrate salt (Bisantrene)

    E-Print Network [OSTI]

    Siahaan, Teruna J.; Gnanasambandan, T.; Yalkowsky, S. H.

    1986-01-01T23:59:59.000Z

    -438 (4) N(l7a) C(18o) 1-321(4) C(10) C(ll) 1-413 (4) N(19) C(I8) 1-322 (5) C(10) C(14) 1-404 (7) N(19) C(20) 1-451 (8) C(10) C(15) 1-467 (5) N(19a) C(18o) 1-332 (7) C(10fl) C(lla) 1 -409 (7) N(19<7) C(20A) 1-452 (5) C(lOa) C(14A) 1-419 (4) N(22) C.... BASSI, pp. 64-71. Delft Univ. Press. JOHNSON, C. K. (1976). ORTEP. 3rd revision. Report ORNL- 5138. Oak Ridge National Laboratory, Tennessee. MAIN, P., FISKE, S. J., HULL, S. E., LESSINGER, L., GERMAIN, G., DECLERCQ, J.-P. & WOOLFSON, M. M. (1980...

  16. Hormetic effect of ionic liquid 1-ethyl-3-methylimidazolium acetate on bacteria

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nancharaiah, Y. V. [Bhabha Atomic Research Center, Kalpakkam (India). Biofouling and Biofilm Processes Sect.; Francis, A. J. [Brookhaven National Laboratory (BNL), Upton, NY (United States). Environmental Sciences Dept.; POSTECH, Pohang (Korea, Rep. of). Div. of Advanced Nuclear Engineering

    2015-06-01T23:59:59.000Z

    The biological effect of ionic liquids (ILs) is one of the highly debated topics as they are being contemplated for various industrial applications. 1-ethyl-2-methylimidazolium acetate ([EMIM][Ac]) showed remarkable hormesis on anaerobic Clostridium sp. and aerobic Psueudomonas putida. Bacterial growth was stimulated at up to 2.5 g L-1 and inhibited at > 2.5 g L-1 of ([EMIM][Ac]). The growth of Clostridium sp. and P. putida were higher by 0.4 and 4-fold respectively, in the presense of 0.5 g L-1 of ([EMIM][Ac]). Assessment of the effect of [EMIM][Ac] under different growth conditions showed that the hormesis of [EMIM][Ac] was mediated via regulation of medium pH. Hormetic effect of [EMIM][Ac] was evident only in medium with poor buffering capacity and in the presence of a fermentable substrate as the carbon source. The hormetic effect of [EMIM][Ac] on bacterial growth is most likely associated with the buffering capacity of acetate anion. These observations have implications in ILs toxicity studies and ecological risk assessment.

  17. Hormetic effect of ionic liquid 1-ethyl-3-methylimidazolium acetate on bacteria

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nancharaiah, Y. V.; Francis, A. J.

    2015-06-01T23:59:59.000Z

    The biological effect of ionic liquids (ILs) is one of the highly debated topics as they are being contemplated for various industrial applications. 1-ethyl-2-methylimidazolium acetate ([EMIM][Ac]) showed remarkable hormesis on anaerobic Clostridium sp. and aerobic Psueudomonas putida. Bacterial growth was stimulated at up to 2.5 g L-1 and inhibited at > 2.5 g L-1 of ([EMIM][Ac]). The growth of Clostridium sp. and P. putida were higher by 0.4 and 4-fold respectively, in the presense of 0.5 g L-1 of ([EMIM][Ac]). Assessment of the effect of [EMIM][Ac] under different growth conditions showed that the hormesis of [EMIM][Ac] was mediated via regulationmoreof medium pH. Hormetic effect of [EMIM][Ac] was evident only in medium with poor buffering capacity and in the presence of a fermentable substrate as the carbon source. The hormetic effect of [EMIM][Ac] on bacterial growth is most likely associated with the buffering capacity of acetate anion. These observations have implications in ILs toxicity studies and ecological risk assessment.less

  18. New Technique for Speciation of Uranium in Sediments Following Acetate-Stimulated Bioremediation

    SciTech Connect (OSTI)

    Not Available

    2011-06-22T23:59:59.000Z

    Acetate-stimulated bioremediation is a promising new technique for sequestering toxic uranium contamination from groundwater. The speciation of uranium in sediments after such bioremediation attempts remains unknown as a result of low uranium concentration, and is important to analyzing the stability of sequestered uranium. A new technique was developed for investigating the oxidation state and local molecular structure of uranium from field site sediments using X-Ray Absorption Spectroscopy (XAS), and was implemented at the site of a former uranium mill in Rifle, CO. Glass columns filled with bioactive Rifle sediments were deployed in wells in the contaminated Rifle aquifer and amended with a hexavalent uranium (U(VI)) stock solution to increase uranium concentration while maintaining field conditions. This sediment was harvested and XAS was utilized to analyze the oxidation state and local molecular structure of the uranium in sediment samples. Extended X-Ray Absorption Fine Structure (EXAFS) data was collected and compared to known uranium spectra to determine the local molecular structure of the uranium in the sediment. Fitting was used to determine that the field site sediments did not contain uraninite (UO{sub 2}), indicating that models based on bioreduction using pure bacterial cultures are not accurate for bioremediation in the field. Stability tests on the monomeric tetravalent uranium (U(IV)) produced by bioremediation are needed in order to assess the efficacy of acetate-stimulation bioremediation.

  19. Late Glacial and Early Holocene Climatic Changes Based on a Multiproxy Lacustrine Sediment Record from Northeast Siberia

    SciTech Connect (OSTI)

    Kokorowski, H D; Anderson, P M; Sletten, R S; Lozhkin, A V; Brown, T A

    2008-05-20T23:59:59.000Z

    Palynological (species assemblage, pollen accumulation rate), geochemical (carbon to nitrogen ratios, organic carbon and biogenic silica content), and sedimentological (particle size, magnetic susceptibility) data combined with improved chronology and greater sampling resolution from a new core from Elikchan 4 Lake provide a stronger basis for defining paleoenvironmental changes than was previously possible. Persistence of herb-dominated tundra, slow expansion of Betula and Alnus shrubs, and low percentages of organic carbon and biogenic silica suggest that the Late-Glacial transition (ca. 16,000-11,000 cal. yr BP) was a period of gradual rather than abrupt vegetation and climatic change. Consistency of all Late-Glacial data indicates no Younger Dryas climatic oscillation. A dramatic peak in pollen accumulation rates (ca. 11,000-9800 cal. yr BP) suggests a possible summer temperature optimum, but finer grain-sizes, low magnetic susceptibility, and greater organic carbon and biogenic silica, while showing significant warming at ca. 11,000 cal. yr BP, offer no evidence of a Holocene thermal maximum. When compared to trends in other paleo-records, the new Elikchan data underscore the apparent spatial complexity of climatic responses in Northeast Siberia to global forcings between ca. 16,000-9000 cal. yr BP.

  20. A tentative reconstruction of the last interglacial and glacial inception in Greenland based on new gas measurements in the Greenland Ice

    E-Print Network [OSTI]

    Chappellaz, Jrme

    A tentative reconstruction of the last interglacial and glacial inception in Greenland based on new gas measurements in the Greenland Ice Core Project (GRIP) ice core Amaelle Landais,1 Je September 2003. [1] The disturbed stratigraphy of the ice in the lowest 10% of the Greenland GRIP ice core

  1. Online Supplement: Sea salt aerosol response to climate change: last glacial maximum, pre-industrial, and doubled-carbon dioxide climates

    E-Print Network [OSTI]

    Mahowald, Natalie

    Online Supplement: Sea salt aerosol response to climate change: last glacial maximum, pre simulations in the current climate using the CCSM3 sea salt aerosols. We use the sea salt source deposition and wet deposition as loss mechanisms [Rasch et al., 2001]. The source of sea salt aerosols

  2. Sedimentation processes in the Eastern Mediterranean Sea during the Late Glacial and Holocene revealed by end-member modelling of the

    E-Print Network [OSTI]

    Gilli, Adrian

    transition from the African Humid Period to recent arid conditions. This climate change was gradualSedimentation processes in the Eastern Mediterranean Sea during the Late Glacial and Holocene and Holocene were controlled by climatic variations of both the northern high latitudes and the African climate

  3. Enrichment, isolation and characterization of fungi tolerant to 1-ethyl-3-methylimidazolium acetate

    SciTech Connect (OSTI)

    Singer, S.W.; Reddy, A. P.; Gladden, J. M.; Guo, H.; Hazen, T.C.; Simmons, B. A.; VanderGheynst, J. S.

    2010-12-15T23:59:59.000Z

    This work aims to characterize microbial tolerance to 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]), ionic liquid that has emerged as a novel biomass pretreatment for lignocellulosic biomass. Enrichment experiments performed using inocula treated with [C2mim][OAc] under solid and liquid cultivation yielded fungal populationsdominated by Aspergilli. Ionic liquid-tolerant Aspergillus isolates from these enrichments were capable of growing in a radial plate growth assay in the presence of 10% [C2mim][OAc]. When a [C2mim][OAc]-tolerant Aspergillus fumigatus strain was grown in the presence of switchgrass, endoglucanases and xylanases were secreted that retained residual enzymatic activity in the presence of 20% [C2mim][OAc]. The results of the study suggest tolerance to ionic liquids is a general property of Aspergilli. Tolerance to an industrially important ionic liquid was discovered in a fungal genera that is widely used in biotechnology, including biomass deconstruction.

  4. Green polymer electrolytes based on chitosan and 1-butyl-3-methylimidazolium acetate

    SciTech Connect (OSTI)

    Shamsudin, Intan Juliana [Chemistry Department, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur (Malaysia); Ahmad, Azizan; Hassan, Nur Hasyareeda [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan (Malaysia)

    2014-09-03T23:59:59.000Z

    Green polymer electrolytes based on chitosan as the polymer matrix and ionic liquid 1-butyl-3-methylimidazolium acetate [Bmim][OAc] as charge carriers were prepared by solution casting technique. Complexes with various amount of ionic liquid loading were investigated as possible ionic conducting polymers. The ionic conductivity was found to increase with increasing weight percent of ionic liquid. The highest ionic conductivity of the charged chitosan-[Bmim][OAc] was 2.44 10{sup ?3} S cm{sup ?1} at 90 wt.% of [Bmim][OAc] content at ambient temperature. Attenuated Total Reflection Fourier Transform infrared (ATR-FTIR) spectroscopy has proven the interaction between chitosan and [Bmim][OAc]. X-ray Diffraction (XRD) has shown that the amorphosity of the complexes increase as the amount of [Bmim][OAc] increase.

  5. Anaerobic microbial dissolution of lead and production of organic acids

    DOE Patents [OSTI]

    Francis, Arokiasamy J. (Middle Island, NY); Dodge, Cleveland (Wading River, NY); Chendrayan, Krishnachetty (Coimbatore Tamil Nadu, IN); Quinby, Helen L. (Cambridge, MD)

    1988-01-01T23:59:59.000Z

    The present invention relates to an anaerobic bacterial culture of Clostridium sp. ATCC No. 53464 which solubilizes lead oxide under anaerobic conditions in coal and industrial wastes and therefore presents a method of removing lead from such wastes before they are dumped into the environment. The rate of lead dissolution during logarithmic growth of the bacteria in 40 ml medium containing 3.32 .mu.moles of lead as lead oxide was 0.042 .mu.moles ml.sup.-1 hr.sup.-1. Dissolution of lead oxide by the bacterial isolate is due to the production of metabolites and acidity in the culture medium. The major metabolites are acetic, butyric and lactic acid. Clostridium sp. ATCC No. 53464 can be used in the recovery of strategic metals from ores and wastes and also for the production of lactic acid for commercial purposes. The process yields large quantities of lactic acid as well as lead complexed in a stable form with said acids.

  6. Warehouse Catalog -Chemical Catalog Alphabetical

    E-Print Network [OSTI]

    Oliver, Douglas L.

    METHANOL ABSOLUTE, 4 LITER GLASS BOTTLE (9070-03) BT 3184 C01 90050 METHANOL ABSOLUTE, 4L POLY- ETHYLENE 90067 SODIUM CHLORIDE, 2.5KG (3624-05) BT 3184 C01 90077 SOLUENE 350, 500ML GLASS BOTTLE (6003038) BT-33) BT 3184 A01 90003 ACID, ACETIC, GLACIAL, 500ML BOTTLE (9508-01) BT 3184 A01 90009 ACID, HYDROCHLORIC

  7. Histopathological Alterations after Single Epidural Injection of Ropivacaine, Methylprednizolone Acetate, or Contrast Material in Swine

    SciTech Connect (OSTI)

    Kitsou, Maria-Chrysanthi; Kostopanagiotou, Georgia; Kalimeris, Konstantinos [University of Athens, 2nd Department of Anesthesiology-Pain Unit, School of Medicine, Attikon University Hospital (Greece); Vlachodimitropoulos, Demetrios [University of Athens, Department of Forensic Medicine, School of Medicine (Greece); Soultanis, Konstantinos [University of Athens, 1st Department of Orthopaedics, School of Medicine, Attikon University Hospital (Greece); Batistaki, Chrysanthi [University of Athens, 2nd Department of Anesthesiology-Pain Unit, School of Medicine, Attikon University Hospital (Greece); Kelekis, Alexis, E-mail: akelekis@med.uoa.gr [University of Athens, 2nd Radiology Department, Attikon University Hospital (Greece)

    2011-12-15T23:59:59.000Z

    Purpose: The consequences from the injection of different types of drugs in the epidural space remains unknown. Increasing evidence suggests that localized inflammation, fibrosis, and arachnoiditis can complicate sequential epidural blockades, or even epidural contrast injection. We investigate the in vivo effect of epidural injections in the epidural space in an animal model. Materials and Methods: A group of ten male adult pigs, five punctures to each at distinct vertebral interspaces under general anesthesia, were examined, testing different drugs, used regularly in the epidural space (iopamidol, methylprednisolone acetate, ropivacaine). Each site was marked with a percutaneous hook wire marker. Histological analysis of the epidural space, the meninges, and the underlying spinal cord of the punctured sites along with staining for caspase-3 followed 20 days later. Results: The epidural space did not manifest adhesions or any other pathology, and the outer surface of the dura was not impaired in any specimen. The group that had the contrast media injection showed a higher inflammation response compared to the other groups (P = 0.001). Positive staining for caspase-3 was limited to <5% of neurons with all substances used. Conclusion: No proof of arachnoiditis and/or fibrosis was noted in the epidural space with the use of the above-described drugs. A higher inflammation rate was noted with the use of contrast media.

  8. Microstructural characterization of low-density foams. [Silica, resorcinol/formaldehyde, cellulose/acetate

    SciTech Connect (OSTI)

    Price, C.W.

    1988-01-01T23:59:59.000Z

    Low-density foams (of the order 0.1 g/cm/sup 3/) synthesized from silica aerogel, resorcinol/formaldehyde, and cellulose acetate have fine, delicate microstructures that are extremely difficult to characterize. Improved low-voltage resolution of an SEM equipped with a field-emission gun (FESEM) does permit these materials to be examined directly without coating and at sufficient magnification to reveal the microstructures. Light coatings applied by ion-beam deposition can stabilize the specimens to some extent and reduce electron charging without seriously altering the microstructure, but coatings applied by conventional techniques usually obliterate these microstructures. Transmission electron microscopy (TEM) is required to provide unambiguous microstructural interpretations. However, TEM examinations of these materials can be severely restricted by specimen preparation difficulties and electron-beam damage, and considerable care must be taken to ensure that reasonably accurate TEM results have been obtained. This work demonstrates that low-voltage FESEM analyses can be used to characterize microstructures in these foams, but TEM analyses are required to confirm the FESEM analyses and perform quantitative measurements. 19 refs., 11 figs.

  9. Catalytic Upgrading of bio-oil using 1-octene and 1-butanol over sulfonic acid resin catalysts

    SciTech Connect (OSTI)

    Zhang, Zhijun; Wang, Qingwen; Tripathi, Prabhat; Pittman, Charles U.

    2011-02-04T23:59:59.000Z

    Raw bio-oil from fast pyrolysis of biomass must be refined before it can be used as a transporation fuel, a petroleum refinery feed or for many other fuel uses. Raw bio-oil was upgraded with the neat model olefin, 1-octene, and with 1-octene/1-butanol mixtures over sulfonic acid resin catalysts frin 80 to 150 degrees celisus in order to simultaneously lower water content and acidity and to increase hydrophobicity and heating value. Phase separation and coke formation were key factors limiting the reaction rate during upgrading with neat 1-octene although octanols were formed by 1-octene hydration along with small amounts of octyl acetates and ethers. GC-MS analysis confirmed that olefin hydration, carboxylic acid esterification, acetal formation from aldehydes and ketones and O- and C-alkylations of phenolic compounds occurred simultaneously during upgrading with 1-octene/1-butanol mixtures. Addition of 1-butanol increased olefin conversion dramatically be reducing mass transfer restraints and serving as a cosolvent or emulsifying agent. It also reacted with carboxylic acids and aldehydes/ketones to form esters, and acetals, respectively, while also serving to stabilize bio-oil during heating. 1-Butanol addition also protected the catalysts, increasing catalyst lifetime and reducing or eliminationg coking. Upgrading sharply increased ester content and decreased the amounts of levoglucosan, polyhydric alcohols and organic acids. Upgrading lowered acidity (pH value rise from 2.5 to >3.0), removed the uppleasant ordor and increased hydrocarbon solubility. Water content decreased from 37.2% to < 7.5% dramatically and calorific value increased from 12.6 MJ kg to about 30.0 MJ kg.

  10. Response of wether lambs to implantation with trenbolone acetate combined with oestradiol-17? at two levels

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    of rib than controls. Significant reductions due to implantation were recorded for concentra- tions of urea and free fatty acids in blood plasma and for proportions of wool fleece and kidney plus channel significantly greater values for plasma urea, the weight (g/kg EBW) of carcass fat, kidney plus channel fat

  11. Cleavage of nucleic acids

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor L. (Madison, WI); Brow, Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

    2007-12-11T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  12. Nucleic acid detection compositions

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor I. (Madison, WI); Brow, Mary Ann (Madison, WI); Dahlberg, James L. (Madison, WI)

    2008-08-05T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  13. Cleavage of nucleic acids

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Waunakee, WI); Lyamichev, Victor I. (Madison, WI); Brow; Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

    2010-11-09T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  14. Nucleic acid detection assays

    DOE Patents [OSTI]

    Prudent, James R.; Hall, Jeff G.; Lyamichev, Victor I.; Brow, Mary Ann; Dahlberg, James E.

    2005-04-05T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  15. Milk fat composition of a lactating dairy cow as influenced by abomasal infusion of various long chain fatty acids

    E-Print Network [OSTI]

    Switzer, Leonard Anderson

    1971-01-01T23:59:59.000Z

    acids of milk comes from blood acetate, which contributes ma. inly to the fatty acids containing from to 12 carbon atoms. Shaw and co-workers (44) demonstrated that 5- hydroxybutyrate was absorbed in significant amounts by the normal lactating udder... and abbreviations used will be as normal milking (NM), residual milking (SM), and hourly samples as 1 (1PI), 2 (2PI), 3 (3M), (4M), 5 (5PI)~ 6 (6M), 7 (7M)~ 8 (BPI), 9 (9M) and 10 (10M) hr after infusion. Blood samples were collected immediately before...

  16. Process for the preparation of lactic acid and glyceric acid

    DOE Patents [OSTI]

    Jackson, James E [Haslett, MI; Miller, Dennis J [Okemos, MI; Marincean, Simona [Dewitt, MI

    2008-12-02T23:59:59.000Z

    Hexose and pentose monosaccharides are degraded to lactic acid and glyceric acid in an aqueous solution in the presence of an excess of a strongly anionic exchange resin, such as AMBERLITE IRN78 and AMBERLITE IRA400. The glyceric acid and lactic acid can be separated from the aqueous solution. Lactic acid and glyceric acid are staple articles of commerce.

  17. Nucleic acid detection kits

    DOE Patents [OSTI]

    Hall, Jeff G.; Lyamichev, Victor I.; Mast, Andrea L.; Brow, Mary Ann; Kwiatkowski, Robert W.; Vavra, Stephanie H.

    2005-03-29T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof. The present invention further relates to methods and devices for the separation of nucleic acid molecules based on charge. The present invention also provides methods for the detection of non-target cleavage products via the formation of a complete and activated protein binding region. The invention further provides sensitive and specific methods for the detection of nucleic acid from various viruses in a sample.

  18. Microorganisms for producing organic acids

    DOE Patents [OSTI]

    Pfleger, Brian Frederick; Begemann, Matthew Brett

    2014-09-30T23:59:59.000Z

    Organic acid-producing microorganisms and methods of using same. The organic acid-producing microorganisms comprise modifications that reduce or ablate AcsA activity or AcsA homolog activity. The modifications increase tolerance of the microorganisms to such organic acids as 3-hydroxypropionic acid, acrylic acid, propionic acid, lactic acid, and others. Further modifications to the microorganisms increase production of such organic acids as 3-hydroxypropionic acid, lactate, and others. Methods of producing such organic acids as 3-hydroxypropionic acid, lactate, and others with the modified microorganisms are provided. Methods of using acsA or homologs thereof as counter-selectable markers are also provided.

  19. Vapor-liquid equilibrium data at 298. 15 K for binary systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol

    SciTech Connect (OSTI)

    Martin, M.C.; Cocero, M.J.; Mato, F.B. (Univ. de Valladolid (Spain))

    1994-07-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured at 298.15 K for the systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol. Mixtures containing methanol show a behavior close to ideal, while those containing methyl acetate exhibit positive deviations from ideality and satisfy the Redlich-Kister thermodynamic consistency test. The liquid-phase activity coefficients were fitted by using the van Laar, Wilson, NRTL, and NRTL-m (a modified NRTL equation) equations.

  20. EMSL - Nuclei acid structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions showed a temporary pH decrease, with a concomitant increase in formic acid during exponential growth. Fermentation experiments performed outside of the magnet...

  1. Nuclei acid structure | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conditions showed a temporary pH decrease, with a concomitant increase in formic acid during exponential growth. Fermentation experiments performed outside of the magnet...

  2. Recovery of organic acids

    DOE Patents [OSTI]

    Verser, Dan W. (Menlo Park, CA); Eggeman, Timothy J. (Lakewood, CO)

    2011-11-01T23:59:59.000Z

    A method is disclosed for the recovery of an organic acid from a dilute salt solution in which the cation of the salt forms an insoluble carbonate salt. A tertiary amine and CO.sub.2 are introduced to the solution to form the insoluble carbonate salt and a complex between the acid and an amine. A water immiscible solvent, such as an alcohol, is added to extract the acid/amine complex from the dilute salt solution to a reaction phase. The reaction phase is continuously dried and a product between the acid and the solvent, such as an ester, is formed.

  3. Recovery of organic acids

    DOE Patents [OSTI]

    Verser, Dan W. (Golden, CO); Eggeman, Timothy J. (Lakewood, CO)

    2009-10-13T23:59:59.000Z

    A method is disclosed for the recovery of an organic acid from a dilute salt solution in which the cation of the salt forms an insoluble carbonate salt. A tertiary amine and CO.sub.2 are introduced to the solution to form the insoluble carbonate salt and a complex between the acid and an amine. A water immiscible solvent, such as an alcohol, is added to extract the acid/amine complex from the dilute salt solution to a reaction phase. The reaction phase is continuously dried and a product between the acid and the solvent, such as an ester, is formed.

  4. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31T23:59:59.000Z

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  5. The use of acid-treated sorghum grain in the diet of finishing beef cattle

    E-Print Network [OSTI]

    Kowalik, Alvin James

    1972-01-01T23:59:59.000Z

    -dry grain, no heating or mold growth was observed during four weeks of storage under aerobic condit1ons. Sorghum grain, early harvested at 28 to 40K moisture and treated with a commercial m1xture of acetic and propionic acid, heated and molded when... application was less than 2X. Heating in grain treated with 1. 17$ of the mixture was noted almost irsne- di ately after storage. Grain receiving a mixture of 1. 80'4 kept for approximately six months before any mold growth was observed. Grain treated...

  6. Synthesis of iron oxides and the influence of organic acids on the resolubilization of iron minerals

    E-Print Network [OSTI]

    Clarke, Eric Thacher

    1984-01-01T23:59:59.000Z

    to renew Fe in solution (Viets and Lindsay, 1973). Furthermore, a chelate test could be used to simulate the dissolution of oxide phases with high specific surface areas or poor crystallinity. Borggaard (1976) used EDTA buffered at pH 5. 2 and lower... and reducing agents, buffered in 1. 0 N NH4 acetate at pH 3. 5 and 4. 75, Dissolution rate in oxalic acid decreased in the following order: ferrihydrite, lep1docroc1te, and goeth1te. Rate of Fe ox1de dissolution 1n the presence of com- plexing and reducing...

  7. Allylation of acetanilides with allyl acetate under conditions of metal-complex catalysis combined with phase-transfer catalysis

    SciTech Connect (OSTI)

    Lebedev, S.A.; Leonova, Yu.P.; Berestova, S.S.; Petrov, E.S.

    1988-10-20T23:59:59.000Z

    Acetanilides are alkylated at the nitrogen atom under the conditions of phase-transfer catalysis. For the case of the reaction of acetanilides with allyl acetate the authors showed that 2-alkenyl esters can be used for the alkylation of acetanilides under the conditions of phase-transfer catalysis in the presence of the complexes of zero valent palladium. N-Acetylskatole was obtained with a yield of 50% from N-allyl-2-bromoacetanilide by intramolecular cyclization in the presence of Od(OAc)/sub 2/ as catalyst.

  8. The Fatty Acid Content of Ocean Water

    E-Print Network [OSTI]

    Slowey, James Frank

    1960-01-01T23:59:59.000Z

    acetate sea water ethyl acetate 28, 620 226, 750 13, 780 1Z, 500 9, 540 5, 500 89 5-1/ 2 Run 2 sea water ethyl acetate sea water ethyl acetate sea water ethyl acetate 26, 500 20Z, 500 13, 780 12, 250 8, 480 3, 750 11-1/ 2 88-1/ 2...'ters)(CIpCIpCI2C14 14(1=) 16 16(1 =) 18 18(1 =) 18(2 =) Number of Carbon Atoms t. % Wei ht of Esters mg. /I. 10 300 900 1900 0 6Q 20 4 3Q 12 11 7 35 94 0 0 0 7 6 42 15 0 22 16 Bg 14 9 0 0 0 0 0. 5 0. 4 0. 5 0. 3 23 FIGURE 2 SEPARATION...

  9. Controlling acid rain

    E-Print Network [OSTI]

    Fay, James A.

    1983-01-01T23:59:59.000Z

    High concentrations of sulfuric and nitric acid in raTn fn the northeastern USA are caused by the large scale combustion of fossil fuels within this region. Average precipitation acidity is pH 4.2, but spatial and temporal ...

  10. Mutant fatty acid desaturase

    DOE Patents [OSTI]

    Shanklin, John; Cahoon, Edgar B.

    2004-02-03T23:59:59.000Z

    The present invention relates to a method for producing mutants of a fatty acid desaturase having a substantially increased activity towards fatty acid substrates with chains containing fewer than 18 carbons relative to an unmutagenized precursor desaturase having an 18 carbon atom chain length substrate specificity. The method involves inducing one or more mutations in the nucleic acid sequence encoding the precursor desaturase, transforming the mutated sequence into an unsaturated fatty acid auxotroph cell such as MH13 E. coli, culturing the cells in the absence of supplemental unsaturated fatty acids, thereby selecting for recipient cells which have received and which express a mutant fatty acid desaturase with an elevated specificity for fatty acid substrates having chain lengths of less than 18 carbon atoms. A variety of mutants having 16 or fewer carbon atom chain length substrate specificities are produced by this method. Mutant desaturases produced by this method can be introduced via expression vectors into prokaryotic and eukaryotic cells and can also be used in the production of transgenic plants which may be used to produce specific fatty acid products.

  11. MoVO-based catalysts for the oxidation of ethane to ethylene and acetic acid. Influence of niobium and/or palladium on physicochemical

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    of niobium and/or palladium on physicochemical and catalytic properties. Martial Roussel1 , Michel Bouchard1: +33 (0)3 20 43 65 61 Mail: Elisabeth.Bordes@univ-lille1.fr #12;2 ABSTRACT The influence of niobium and spectroscopies. These properties depend on the presence or absence of niobium, and to a lesser extent

  12. High-Density PhyloChip profiling of stimulated aquifer microbial communities reveals a complex response to acetate amendment

    SciTech Connect (OSTI)

    Handley, Kim M.; Wrighton, Kelly C.; Piceno, Y. M.; Andersen, Gary L.; DeSantis, Todd; Williams, Kenneth H.; Wilkins, Michael J.; N'Guessan, A. Lucie; Peacock, Aaron D.; Bargar, John; Long, Philip E.; Banfield, Jillian F.

    2012-04-13T23:59:59.000Z

    There is increasing interest in harnessing the functional capacities of indigenous microbial communities to transform and remediate a wide range of environmental contaminants. Information about which community members respond to stimulation can guide the interpretation and development of remediation approaches. To comprehensively determine community membership and abundance patterns among a suite of samples associated with uranium bioremediation experiments we employed a high?density microarray (PhyloChip). Samples were unstimulated, naturally reducing, or collected during Fe(III) (early) and sulfate reduction (late biostimulation) from an acetate re?amended/amended aquifer in Rifle, Colorado, and from laboratory experiments using field?collected materials. Deep community sampling with PhyloChip identified hundreds?to?thousands of operational taxonomic units (OTUs) present during amendment, and revealed close similarity among highly enriched taxa from drill?core and groundwater well?deployed column sediment. Overall, phylogenetic data suggested stimulated community membership was most affected by a carryover effect between annual stimulation events. Nevertheless, OTUs within the Fe(III)? and sulfate?reducing lineages, Desulfuromonadales and Desulfobacterales, were repeatedly stimulated. Less consistent, co?enriched taxa represented additional lineages associated with Fe(III) and sulfate reduction (for example, Desulfovibrionales; Syntrophobacterales; Peptococcaceae) and autotrophic sulfur oxidation (Sulfurovum; Campylobacterales). These data imply complex membership among highly stimulated taxa, and by inference biogeochemical responses to acetate, a non?fermentable substrate.

  13. UBC Centre for Blood Research: Fermentation Suite Brom A5 (F4) PDF.xls: FermentationProfile Air O2 rpm N2 Base Acid

    E-Print Network [OSTI]

    Strynadka, Natalie

    UBC Centre for Blood Research: Fermentation Suite Brom A5 (F4) PDF.xls: FermentationProfile Air O2 rpm N2 Base Acid NH4OH Acetic Acid 8.6 16.0 Configuration 1 SP 4 - - - SP - 2 SP 3 0.000 Temp (oC) dO2 Fermentation (Hrs) pH rpm Temp Do OD CK (mg/50-L) MeOH (ml) dO2 (%)Temp (C) 40 20 60 80 0 100 6 8 4 2 0 10 28

  14. Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid

    E-Print Network [OSTI]

    Wilcock, William

    Focus Sheet | Hydrofluoric Acid Health hazards of hydrofluoric acid Hydrofluoric acid (HF characterized by weight loss, brittle bones, anemia, and general ill health. Safe use If possible, avoid working to exposures. #12;Focus Sheet | Hydrofluoric Acid Environmental Health and Safety Environmental Programs Office

  15. Fatty acid synthase plays a role in cancer metabolism beyond providing fatty acids for phospholipid synthesis or sustaining elevations in glycolytic activity

    SciTech Connect (OSTI)

    Hopperton, Kathryn E., E-mail: kathryn.hopperton@mail.utoronto.ca [Department of Nutritional Sciences, Faculty of Medicine, University of Toronto, Toronto, ON, Canada M5S 3E2 (Canada); Duncan, Robin E., E-mail: robin.duncan@uwaterloo.ca [Department of Nutritional Sciences, Faculty of Medicine, University of Toronto, Toronto, ON, Canada M5S 3E2 (Canada); Bazinet, Richard P., E-mail: richard.bazinet@utoronto.ca [Department of Nutritional Sciences, Faculty of Medicine, University of Toronto, Toronto, ON, Canada M5S 3E2 (Canada); Archer, Michael C., E-mail: m.archer@utoronto.ca [Department of Nutritional Sciences, Faculty of Medicine, University of Toronto, Toronto, ON, Canada M5S 3E2 (Canada); Department of Medical Biophysics, Faculty of Medicine, University of Toronto, Toronto, ON, Canada M5S 3E2 (Canada)

    2014-01-15T23:59:59.000Z

    Fatty acid synthase is over-expressed in many cancers and its activity is required for cancer cell survival, but the role of endogenously synthesized fatty acids in cancer is unknown. It has been suggested that endogenous fatty acid synthesis is either needed to support the growth of rapidly dividing cells, or to maintain elevated glycolysis (the Warburg effect) that is characteristic of cancer cells. Here, we investigate both hypotheses. First, we compared utilization of fatty acids synthesized endogenously from {sup 14}C-labeled acetate to those supplied exogenously as {sup 14}C-labeled palmitate in the culture medium in human breast cancer (MCF-7 and MDA-MB-231) and untransformed breast epithelial cells (MCF-10A). We found that cancer cells do not produce fatty acids that are different from those derived from exogenous palmitate, that these fatty acids are esterified to the same lipid and phospholipid classes in the same proportions, and that their distribution within neutral lipids is not different from untransformed cells. These results suggest that endogenously synthesized fatty acids do not fulfill a specific function in cancer cells. Furthermore, we observed that cancer cells excrete endogenously synthesized fatty acids, suggesting that they are produced in excess of requirements. We next investigated whether lipogenic activity is involved in the maintenance of high glycolytic activity by culturing both cancer and non-transformed cells under anoxic conditions. Although anoxia increased glycolysis 23 fold, we observed no concomitant increase in lipogenesis. Our results indicate that breast cancer cells do not have a specific qualitative or quantitative requirement for endogenously synthesized fatty acids and that increased de novo lipogenesis is not required to sustain elevations in glycolytic activity induced by anoxia in these cells. - Highlights: Fatty acid synthase (FASN) is over-expressed in cancer but its function is unknown. We compare utilization of fatty acids produced by FASN to those derived exogenously. Cancer cells do not have a specific requirement for fatty acids produced by FASN. Fatty acids produced by FASN are in excess of cell requirements and are excreted. Increased FASN activity is not required to sustain elevations in glycolysis.

  16. FERMENTATION OF PENTOSE SUGARS TO ETHANOL AND OTHER NEUTRAL PRODUCTS BY MICROORGANISMS

    E-Print Network [OSTI]

    Rosenberg, S.L.

    2013-01-01T23:59:59.000Z

    batch fermentation the concentrations of acetic, and butyricthat acetic acid may fate in fermentations conducted by B.acid fermentation are ethanol , CO^, and acetic, succinic,

  17. FERMENTATION OF PENTOSE SUGARS TO ETHANOL AND OTHER NEUTRAL PRODUCTS BY MICROORGANISMS

    E-Print Network [OSTI]

    Rosenberg, S.L.

    2013-01-01T23:59:59.000Z

    that acetic acid may fate in fermentations conducted by B.fermentation the concentrations of acetic, and butyric acidsthe mixed acid fermentation are ethanol , CO^, and acetic,

  18. High-density PhyloChip profiling of stimulated aquifer microbial communities reveals a complex response to acetate amendment

    SciTech Connect (OSTI)

    Handley, Kim M.; Wrighton, Kelly E.; Piceno, Y. M.; Anderson, Gary L.; DeSantis, Todd; Williams, Kenneth H.; Wilkins, Michael J.; N'Guessan, A. L.; Peacock, Aaron; Bargar, John R.; Long, Philip E.; Banfield, Jillian F.

    2012-06-13T23:59:59.000Z

    There is increasing interest in harnessing the functional diversity of indigenous microbial communities to transform and remediate a wide range of environmental contaminants. Understanding the response of communities to stimulation, including flanking taxa, presents important opportunities for optimizing remediation approaches. We used high-density PhyloChip microarray analysis to comprehensively determine community membership and abundance patterns amongst a suite of samples from U(VI) bioremediation experiments. Samples were unstimulated or collected during Fe(III) and sulfate reduction from an acetate-augmented aquifer in Rifle, Colorado, and from laboratory experiments using field-collected materials. Results showed the greatest diversity in abundant SRB lineages was present in naturally-reduced sediment. Desulfuromonadales and Desulfobacterales were consistently identified as the dominant Fe(III)- and sulfate-reducing bacteria (IRB and SRB) throughout acetate amendment experiments. Stimulated communities also exhibited a high degree of functional redundancy amongst enriched flanking members. Not surprisingly, competition for both sulfate and iron was evident amongst abundant taxa, but the distribution and abundance of these ancillary SRB (Peptococcaceae, Desulfovibrionales and Syntrophobacterales), and lineages containing IRB (excluding Desulfobacteraceae) was heterogeneous amongst sample types. Interesting, amongst the most abundant taxa, particularly during sulfate reduction, were Epsilonproteobacteria that perform microaerobic or nitrate-dependant sulfur oxidation, and a number of bacteria other than Geobacteraceae that may enzymatically reduce U(VI). Finally, in depth community probing with PhyloChip determined the efficacy of experimental approaches, notably revealing striking similarity amongst stimulated sediment (from drill cores and in-situ columns) and groundwater communities, and demonstrating that sediment-packed in-situ (down-well) columns served as an ideal method for subsurface biostimulation.

  19. A Direct, Biomass-Based Synthesis of Benzoic Acid: Formic Acid-Mediated Deoxygenation of the Glucose-Derived Materials Quinic Acid and Shikimic Acid

    SciTech Connect (OSTI)

    Arceo, Elena; Ellman, Jonathan; Bergman, Robert

    2010-05-03T23:59:59.000Z

    An alternative biomass-based route to benzoic acid from the renewable starting materials quinic acid and shikimic acid is described. Benzoic acid is obtained selectively using a highly efficient, one-step formic acid-mediated deoxygenation method.

  20. Asphaltene damage in matrix acidizing

    E-Print Network [OSTI]

    Hinojosa, Roberto Antonio

    1996-01-01T23:59:59.000Z

    REVIEW CONSTRUCTION OF APPARATUS . DESCRIPTION OF CORE SAMPLES DESIGN OF EXPERIMENTAL ACID TREATMENT . . . ACIDIZING RESULTS BRINE SATURATED CORE L1D ACIDIZING RESULTS BRINE/CRUDE OIL SATURATED CORE S2A . . . ACIDIZING RESULTS BRINE/KEROSENE OIL... experiment they used HCl saturated kerosene to test the same crude samples. Deposition occurred with the HCl saturated acid. The authors concluded, though deposition at an interface was preferential, sludge formation did not require an interface. Moore et...

  1. Optical high acidity sensor

    DOE Patents [OSTI]

    Jorgensen, B.S.; Nekimken, H.L.; Carey, W.P.; O`Rourke, P.E.

    1997-07-22T23:59:59.000Z

    An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber. 10 figs.

  2. Influence of surface defects and local structure on acid/base properties and oxidation pathways over metal oxide surfaces. Final report, June 1990--January 1997

    SciTech Connect (OSTI)

    Cox, D.F.

    1997-12-31T23:59:59.000Z

    This final report covers work done during project period one and project period two. All the work in project period one was focused on the selective oxidation of oxygenated hydrocarbons over the SnO{sub 2}(110) single crystal surface. In project period two, the emphasis was on the acid/base properties of SnO{sub 2}(110) as well as two different Cu{sub 2}O single crystal surfaces. Prior to the summary of results, a description of these different surfaces is given as background information. Results are described for the dissociation and reaction of Bronsted acids (methanol, formic acid, water, formaldehyde, acetone, propene, acetic acid, and carbon monoxide). Results from project period two include: ammonia adsorption, CO{sub 2} adsorption, propene adsorption and oxidation, with tin oxides; complimentary work with copper oxides; and STM investigations.

  3. acid succinic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulated the laser heating of the succinic acid (this data is still simulation is that infrared heating generates about 10-15 more succinic acid molecules bound to the analyte...

  4. acid docosahexaenoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 38 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  5. acid aspartic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 20 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  6. acid caffeic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 11 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  7. acid propionic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 19 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  8. acid sorbic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 9 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  9. acid benzoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 24 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  10. acid propanoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 9 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  11. acid methoxyacetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  12. acid eicosapentaenoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 18 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  13. acids eicosapentaenoic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 18 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  14. acid acetylsalicylic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 10 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  15. acid dichloroacetic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  16. acid oleic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 31 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  17. Recovery of Carboxylic Acids from Fermentation Broth via Acid Springing

    E-Print Network [OSTI]

    Dong, Jipeng

    2010-01-14T23:59:59.000Z

    RECOVERY OF CARBOXYLIC ACIDS FROM FERMENTATION BROTH VIA ACID SPRINGING A Thesis by JIPENG DONG Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 2008 Major Subject: Chemical Engineering RECOVERY OF CARBOXYLIC ACIDS FROM FERMENTATION BROTH VIA ACID SPRINGING A Thesis by JIPENG DONG Submitted to the Office of Graduate Studies of Texas A...

  18. Acid placement and coverage in the acid jetting process

    E-Print Network [OSTI]

    Mikhailov, Miroslav I.

    2009-05-15T23:59:59.000Z

    Many open-hole acid treatments are being conducted by pumping acid through jetting ports placed at the end of coiled tubing or drill pipe. The filter-cake on the bore-hole is broken by the jet; the acid-soluble material is dissolved, creating...

  19. Lubrication with boric acid additives

    DOE Patents [OSTI]

    Erdemir, Ali (Naperville, IL)

    2000-01-01T23:59:59.000Z

    Self-lubricating resin compositions including a boric acid additive and a synthetic polymer including those thermoset materials.

  20. Pantothenic acid biosynthesis in zymomonas

    DOE Patents [OSTI]

    Tao, Luan; Tomb, Jean-Francois; Viitanen, Paul V.

    2014-07-01T23:59:59.000Z

    Zymomonas is unable to synthesize pantothenic acid and requires this essential vitamin in growth medium. Zymomonas strains transformed with an operon for expression of 2-dehydropantoate reductase and aspartate 1-decarboxylase were able to grow in medium lacking pantothenic acid. These strains may be used for ethanol production without pantothenic acid supplementation in seed culture and fermentation media.

  1. Investigating acid rain

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    A report is given of an address by Kathleen Bennett, Assistant Administrator of Air, Noise and Radiation, Environmental Protection Agency which was presented to the US Senate Committee on the Environment and Public Works. Bennet explained that in view of the many unknowns about acid rain, and the possible substantial cost burden of additional controls, EPA is proceeding with its program to investigate this environmental malady over a 10-year period. The three major areas of the research program are (1) transport, transformation, and deposition processes, (2) effects of acid deposition, and (3) assessments and policy studies. Other issues discussed were global transboundary air pollution and Senate amendments addressing long-range transport. (JMT)

  2. Invasive cleavage of nucleic acids

    DOE Patents [OSTI]

    Prudent, James R. (Madison, WI); Hall, Jeff G. (Madison, WI); Lyamichev, Victor I. (Madison, WI); Brow, Mary Ann D. (Madison, WI); Dahlberg, James E. (Madison, WI)

    2002-01-01T23:59:59.000Z

    The present invention relates to means for the detection and characterization of nucleic acid sequences, as well as variations in nucleic acid sequences. The present invention also relates to methods for forming a nucleic acid cleavage structure on a target sequence and cleaving the nucleic acid cleavage structure in a site-specific manner. The structure-specific nuclease activity of a variety of enzymes is used to cleave the target-dependent cleavage structure, thereby indicating the presence of specific nucleic acid sequences or specific variations thereof.

  3. Fatty Acid Carcass Mapping

    E-Print Network [OSTI]

    Turk, Stacey N.

    2010-01-14T23:59:59.000Z

    calves as yearlings optimizes beef fatty acid composition. M.S. thesis, College Station: Texas A&M University. Chung, K.Y., Lunt, D.K., Choi, C.B., Chae, S.H., Rhoades, R.D., Adams, T.H., Booren, B., & Smith, S.B. (2006). Lipid characteristics... of subcutaneous adipose tissue and M. longissiumus thoracis of Angus and Wagyu steers fed to U.S. and Japanese endpoints. Meat Science, 73(3), 432-441. Chung, K.Y., Lunt, D.K., Kawachi, H., Yano, H., & Smith, S.B. (2005). Stearoyl coenzyme A desaturase...

  4. Chlorine-36 in Water, Snow, and Mid-Latitude Glacial Ice of North America: Meteoric and Weapons-Tests Production in the Vicinity of the Idaho National Engineering and Environmental Laboratory, Idaho

    SciTech Connect (OSTI)

    L. DeWayne; J. R. Green (USGS); S. Vogt, P. Sharma (Purdue University); S. K. Frape (University of Waterloo); S. N. Davis (University of Arizona); G. L. Cottrell (USGS)

    1999-01-01T23:59:59.000Z

    Measurements of chlorine-36 (36Cl) were made for 64 water, snow, and glacial-ice and -runoff samples to determine the meteoric and weapons-tests-produced concentrations and fluxes of this radionuclide at mid-latitudes in North America. The results will facilitate the use of 36Cl as a hydrogeologic tracer at the Idaho National Engineering and Environmental Laboratory (INEEL). This information was used to estimate meteoric and weapons-tests contributions of this nuclide to environmental inventories at and near the INEEL. The data presented in this report suggest a meteoric source 36Cl for environmental samples collected in southeastern Idaho and western Wyoming if the concentration is less than 1 x 10 7 atoms/L. Additionally, concentrations in water, snow, or glacial ice between 1 x 10 7 and 1 x 10 8 atoms/L may be indicative of a weapons-tests component from peak 36Cl production in the late 1950s. Chlorine-36 concentrations between 1 x 10 8 and 1 x 10 9 atoms/L may be representative of re-suspension of weapons-tests fallout airborne disposal of 36Cl from the INTEC, or evapotranspiration. It was concluded from the water, snow, and glacial data presented here that concentrations of 36Cl measured in environmental samples at the INEEL larger than 1 x 10 9 atoms/L can be attributed to waste-disposal practices.

  5. Thermosyntropha lipolytica gen. nov., sp. nov., a lipolytic, anaerobic, alkalitolerant, thermophilic bacterium utilizing short- and long-chain fatty acids in syntrophic coculture with a methanogenic archaeum

    SciTech Connect (OSTI)

    Svetlitshnyi, V.; Wiegel, J. [Univ. of Georgia, Athens, GA (United States); Rainey, F. [German Collection of Microorganisms and Cell Cultures, Braunschweig (Germany)

    1996-10-01T23:59:59.000Z

    Three strains of an anaerobic thermophilic organoheterotrophic lipolytic alkalitolerant bacterium, Thermosyntropha lipolytica gen. nov., sp. nov. (type strain JW/VS-264{sup T}; DSM 11003) were isolated from alkaline hot springs of Lake Bogoria (Kenya). The cells were nonmotile, non-spore forming, straight or slightly curved rods. At 60{degrees}C, the pH range for growth determined at 25{degrees}C [pH{sup 25{degrees}C}] was 7.15 to 9.5, with an optimum between 8.1 and 8.9 (pH{sup 60{degrees}C} of 7.6 and 8.1). At a pH{sup 25{degrees}C} of 8.5 temperature range for growth was from 52 to 70{degrees}C, with an optimum between 60 and 66{degrees}C. The shortest doubling time was around 1 h. In pure culture the bacterium grew in a mineral base medium supplemented with yeast extract, tryptone, Casamino Acids, betaine, and crotonate as carbon sources, producing acetate as a major product and constitutively a lipase. During growth in the presence of olive oil, free long-chain fatty acids were accumulated in the medium but the pure culture syntrophic coculture (Methanobacterium strain JW/VS-M29) the lipolytic bacteria grew on triacylglycerols and linear saturated and unsaturated fatty acids with 4 to 18 carbon atoms, but glycerol was not utilized. Fatty acids with even numbers of carbon atoms were degraded to acetate and methane, while from odd-numbered fatty acids 1 mol of propionate per mol of fatty acid was additionally formed. 16S rDNA sequence analysis identified Syntrophospora and Syntrophomonas spp. as closest phylogenetic neighbors.

  6. SOME EFFECTS OF CYPROTERONE ACETATE ON EPIDIDYMAL FUNCTION IN RATS. T. D. GLOVER, D. J. BLACK, J. C. SHENTON, P. BOYD. Univer-T. D. GLOVER, D. J. BLACK J. C. SHENTON P. BOYD. Univer-

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    SOME EFFECTS OF CYPROTERONE ACETATE ON EPIDIDYMAL FUNCTION IN RATS. T. D. GLOVER, D. J. BLACK, J. C. SHENTON, P. BOYD. Univer-T. D. GLOVER, D. J. BLACK J. C. SHENTON P. BOYD. Univer- site de

  7. Acidic gas capture by diamines

    DOE Patents [OSTI]

    Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

    2011-05-10T23:59:59.000Z

    Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

  8. Organic Phosphoric Acid of the Soil.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1911-01-01T23:59:59.000Z

    . ................................................ introduction 5 .............................. hmmonia-Soluble Phosphoric Acid 5 ................ Solubility of Phosphates in Ammonia 6 I Fixation of Phosphoric Acid from Ammonia .......... 7 Effect of Ratio of Soil to Solvent in Extraction of Phos- I I... .............. phoric Acid by Acid and Ammonia 7 I ........ Other Soil Constituents Dissolved by Ammonia 8 ................... Solution of Fixed Phosphoric Acid 10 ................ ormation of Ammonia-Solubla Phosphoric Acid 11 ....... hosphoric Acid Dissolved...

  9. acidic alpha-amino acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acid indicated that more succinic acid... Gilliland, Patti Lynn 2012-06-07 24 A ACID RAIN Audrey Gibson Geosciences Websites Summary: , oxygen, and oxidants to form...

  10. Chemoenzymatic Synthesis of Unnatural Amino Acids via Modified Claisen

    E-Print Network [OSTI]

    Hudlicky, Tomas

    on the application of Claisen rearrangement to either of the allylic systems in 4, even though this was suggested was described in 1975 by Steglich.8 Since 1982, when the Ireland-Claisen rearrangement of glycine allylic esters acetals were replaced by chelate-bridged metal enolates, claimed to be superior to ketene acetals both

  11. Carbonic Acid Pretreatment of Biomass

    SciTech Connect (OSTI)

    G. Peter van Walsum; Kemantha Jayawardhana; Damon Yourchisin; Robert McWilliams; Vanessa Castleberry

    2003-05-31T23:59:59.000Z

    This project sought to address six objectives, outlined below. The objectives were met through the completion of ten tasks. 1) Solidify the theoretical understanding of the binary CO2/H2O system at reaction temperatures and pressures. The thermodynamics of pH prediction have been improved to include a more rigorous treatment of non-ideal gas phases. However it was found that experimental attempts to confirm theoretical pH predictions were still off by a factor of about 1.8 pH units. Arrhenius experiments were carried out and the activation energy for carbonic acid appears to be substantially similar to sulfuric acid. Titration experiments have not yet confirmed or quantified the buffering or acid suppression effects of carbonic acid on biomass. 2) Modify the carbonic acid pretreatment severity function to include the effect of endogenous acid formation and carbonate buffering, if necessary. It was found that the existing severity functions serve adequately to account for endogenous acid production and carbonate effects. 3) Quantify the production of soluble carbohydrates at different reaction conditions and severity. Results show that carbonic acid has little effect on increasing soluble carbohydrate concentrations for pretreated aspen wood, compared to pretreatment with water alone. This appears to be connected to the release of endogenous acids by the substrate. A less acidic substrate such as corn stover would derive benefit from the use of carbonic acid. 4) Quantify the production of microbial inhibitors at selected reaction conditions and severity. It was found that the release of inhibitors was correlated to reaction severity and that carbonic acid did not appear to increase or decrease inhibition compared to pretreatment with water alone. 5) Assess the reactivity to enzymatic hydrolysis of material pretreated at selected reaction conditions and severity. Enzymatic hydrolysis rates increased with severity, but no advantage was detected for the use of carbonic acid compared to water alone. 6) Determine optimal conditions for carbonic acid pretreatment of aspen wood. Optimal severities appeared to be in the mid range tested. ASPEN-Plus modeling and economic analysis of the process indicate that the process could be cost competitive with sulfuric acid if the concentration of solids in the pretreatment is maintained very high (~50%). Lower solids concentrations result in larger reactors that become expensive to construct for high pressure applications.

  12. A ACID RAIN Audrey Gibson

    E-Print Network [OSTI]

    Toohey, Darin W.

    acid and nitric acid. Sunlight increases the rate of most of these reactions. Electric utility plants;Gas Natural Sources Concentration Carbon dioxide CO2 Decomposition 355 ppm Nitric oxide NO Electric, 2010 #12;Gas Non-Natural Sources Concentration Nitric oxide NO Internal Combustion (cars) 0.2 ppm

  13. Concentrating aqueous volatile fatty acid salt solutions using a tertiary amine mixture

    E-Print Network [OSTI]

    Gaskin, David J

    1997-01-01T23:59:59.000Z

    Lee (1993) has shown that tertiary amines are able to hics. extract water from low-concentration calcium acetate and sodium acetate solutions. This thesis extends the previous work to include calcium propionate and butyrate. Amine extraction may...

  14. The effect of bacterial inoculum on the qualitative characteristics, ruminal degradability and PDI

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    the fermentation characteristics (lower content of acetic and butyric acids, large increase in lactic acid

  15. I Journal of Chemical Ecology. Vol,.29, No. 4,April 2003 (02003) IDENTIFICATION OF ODORS FROM OVERRIPEMANGO

    E-Print Network [OSTI]

    with fermentation, such asI ethanol, acetic acid, ethyl acetate, and acetaldehyde,either as single components ~ 01

  16. Metabolism of Thioctic Acid in Algae

    E-Print Network [OSTI]

    Grisebach, Hans; Fuller, R.C.; Calvin, M.

    1956-01-01T23:59:59.000Z

    METABOLISM OF THlOCTlC ACID IN ALGAE TWO-WEEK LOAN COPY ThisMETABOLISM OF THIOCTIC ACID IN ALGAE Hans Grisebach, R. , C.METABOLISM OF THIOCTIC ACID IN ALGAE Hans Grisebach, R. C.

  17. Time-series analysis for the episodic production and transport of methane from the Glacial Lake Agassiz peatlands, northern Minnesota. Final report

    SciTech Connect (OSTI)

    Siegel, D.I.

    1998-01-01T23:59:59.000Z

    The large peat basins of North America are an important reservoir in the global carbon cycle and a significant source of atmospheric methane. The authors investigated carbon cycling in the Glacial Lake Agassiz peatlands (GLAP) of Minnesota. Initially in 1990, they identified a dramatic change in the concentration of methane in the pore-waters of the raised bogs in the GLAP during an extreme drought. This methane dissipated when the drought broke in 1991 and the occurrence of deep methane is related to changes in the direction of groundwater flow in the peat column. The production of methane and its diffusive loss to the atmosphere was modeled and was about 10 times less than that measured directly in chambers at the land surface. It is clear from the reversals in hydraulic heat, changes in pore-water chemical composition over time, and paleostratigraphic markers, that regional ground water flow systems that are controlled by climate change are unexpectedly a major control over methanogenesis and carbon cycling in GLAP. Seismic profiles made showed that buried bedrock ridges particularly deflect regional groundwater flow upwards towards the land surface and towards raised bog landforms. In addition, high-resolution GPS measurements from data stations funded by this DOE project have shown this year that the peakland land surface elevation changes daily on a scale of cms, and seasonally on a scale of 10s of cm. This most recent observation is exciting because it may reflect episodic degassing of free phase methane from the peat column to the atmosphere, a source for methane previously unaccounted for by methane researchers.

  18. In vivo incorporation of unnatural amino acids

    DOE Patents [OSTI]

    Schultz, Peter G. (La Jolla, CA); Wang, Lei (San Diego, CA); Anderson, John Christopher (San Diego, CA); Chin, Jason W. (Cambridge, GB); Liu, David R. (Lexington, MA); Magliery, Thomas J. (North Haven, CT); Meggers, Eric L. (Philadelphia, PA); Mehl, Ryan Aaron (Lancaster, PA); Pastrnak, Miro (San Diego, CA); Santoro, Stephen William (Cambridge, MA); Zhang, Zhiwen (San Diego, CA)

    2012-05-08T23:59:59.000Z

    The invention provides methods and compositions for in vivo incorporation of unnatural amino acids. Also provided are compositions including proteins with unnatural amino acids.

  19. Carbonic Acid Shows Promise in Geology, Biology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprising Secrets of Carbonic Acid Probing the Surprising Secrets of Carbonic Acid Berkeley Lab Study Holds Implications for Geological and Biological Processes October 23,...

  20. Controlling acid rain : policy issues

    E-Print Network [OSTI]

    Fay, James A.

    1983-01-01T23:59:59.000Z

    The policy and regulatory ramifications of U.S. acid rain control programs are examined; particularly, the alternative of a receptor-oriented strategy as constrasted to emission-oriented proposals (e.g., the Mitchell bill) ...

  1. Nitrate and Prussic Acid Poisoning

    E-Print Network [OSTI]

    Stichler, Charles; Reagor, John C.

    2001-09-05T23:59:59.000Z

    Nitrate and prussic acid poisoning in cattle are noninfectious conditions that can kill livestock. This publication explains the causes and symptoms of these conditions as well as preventive measures and sampling and testing steps....

  2. Seasonalepisodic control of acid deposition

    E-Print Network [OSTI]

    Fay, James A.

    1988-01-01T23:59:59.000Z

    This report contains the climatological, technical and economic factors for episodic and seasonal control of emissions in existing power plants. Analyzing a large data set of acid deposition for the years 1982-85, we find ...

  3. Nitrate and Prussic Acid Poisoning

    E-Print Network [OSTI]

    Stichler, Charles; Reagor, John C.

    2001-09-05T23:59:59.000Z

    Nitrate and prussic acid poisoning in cattle are noninfectious conditions that can kill livestock. This publication explains the causes and symptoms of these conditions as well as preventive measures and sampling and testing steps....

  4. SaltRx HT -Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0

    E-Print Network [OSTI]

    Hill, Chris

    SaltRx HT - Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0 A2. 0.1 M Bis-Tris Propane pH 7.0, 2.8 M Sodium Acetate pH 7.0 A3. 0.1 M Sodium Acetate pH 4.6, 1.5 M Ammonium Chloride A4. 0.1 M Bis-Tris Propane pH 7.0, 1.5 M Ammonium Chloride A5. 0.1 M Tris pH 8.5, 1.5 M Ammonium

  5. Process for the reclamation of battery acid and fluid from expended lead-acid batteries

    SciTech Connect (OSTI)

    Spitz, R.A.

    1990-11-20T23:59:59.000Z

    This patent describes a method for recycling contaminated sulfuric acid from lead acid batteries to reclaimed sulfuric acid fore reuse in the batteries by removing contaminating iron impurities. It comprises: diluting the contaminated sulfuric acid to a concentration between 150 and 230 grams per liter; filtering the sulfuric acid through a first filter means to remove solid impurities.

  6. Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants

    DOE Patents [OSTI]

    Ohlrogge, John B. (Okemos, MI); Cahoon, Edgar B. (Lansing, MI); Shanklin, John (Upton, NY); Somerville, Christopher R. (Okemos, MI)

    1995-01-01T23:59:59.000Z

    The present invention relates to a process for producing lipids containing the fatty acid petroselinic acid in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a .omega.12 desaturase from another species which does normally accumulate petroselinic acid.

  7. Method for production of petroselinic acid and OMEGA12 hexadecanoic acid in transgenic plants

    DOE Patents [OSTI]

    Ohlrogge, J.B.; Cahoon, E.B.; Shanklin, J.; Somerville, C.R.

    1995-07-04T23:59:59.000Z

    The present invention relates to a process for producing lipids containing the fatty acid, petroselinic acid, in plants. The production of petroselinic acid is accomplished by genetically transforming plants which do not normally accumulate petroselinic acid with a gene for a {omega}12 desaturase from another species which does normally accumulate petroselinic acid. 19 figs.

  8. Quantitative implications of the secondary role of carbon dioxide climate forcing in the past glacial-interglacial cycles for the likely future climatic impacts of anthropogenic greenhouse-gas forcings

    E-Print Network [OSTI]

    Soon, Willie

    2007-01-01T23:59:59.000Z

    A review of the recent refereed literature fails to confirm quantitatively that carbon dioxide (CO2) radiative forcing was the prime mover in the changes in temperature, ice-sheet volume, and related climatic variables in the glacial and interglacial periods of the past 650,000 years, even under the "fast response" framework where the convenient if artificial distinction between forcing and feedback is assumed. Atmospheric CO2 variations generally follow changes in temperature and other climatic variables rather than preceding them. Likewise, there is no confirmation of the often-posited significant supporting role of methane (CH4) forcing, which despite its faster atmospheric response time is simply too small, amounting to less than 0.2 W/m2 from a change of 400 ppb. We cannot quantitatively validate the numerous qualitative suggestions that the CO2 and CH4 forcings that occurred in response to the Milankovich orbital cycles accounted for more than half of the amplitude of the changes in the glacial/intergla...

  9. Supporting Information Synthesis of ()-Actinophyllic Acid and Analogs: Applications of

    E-Print Network [OSTI]

    Hergenrother, Paul J.

    two columns of activated neutral alumina prior to use. Dichloromethane (CH2Cl2), acetic anhydride (Ac2O), and allyl chloroformate (Alloc-Cl) were freshly distilled over CaH2. Trimethylsilyl)propan-2-yl acetate. A solution of n-BuLi (6.8 mL of a 2.17 M solution in hexanes, 14.8 mmol) was added

  10. Glacial cycles and astronomical forcing

    SciTech Connect (OSTI)

    Muller, R.A. [Lawrence Berkeley Lab., CA (United States)] [Lawrence Berkeley Lab., CA (United States); MacDonald, G.J. [International Institute for Applied Systems Analysis, Laxenburg (Austria)] [International Institute for Applied Systems Analysis, Laxenburg (Austria)

    1997-07-11T23:59:59.000Z

    Narrow spectral features in ocean sediment records offer strong evidence that the cycles of glaciation were driven by astronomical forces. Two million years ago, the cycles match the 41,000-year period of Earth`s obliquity. This supports the Croll/Milankovitch theory, which attributes the cycles to variations in insolation. But for the past million years, the spectrum is dominated by a single 100,000-year feature and is a poor match to the predictions of insolation models. The spectrum can be accounted for by a theory that derives the cycles of glaciation from variations in the inclination of Earth`s orbital plane.

  11. HYDROFLUORIC ACID FIRST AID INSTRUCTIONS

    E-Print Network [OSTI]

    Jalali. Bahram

    with large amounts of cool running water. Immediately washing off the acid is of primary importance. 2.Remove Immediately flush eyes for at least 15 minutes with copious cool flowing water. 2 If only one eye is affected by a glass of milk or milk of magnesia. 3 Call 911 for immediate medical assistance. REMEMBER, ALL PERSONNEL

  12. A study of the multiplication and rooting in vitro of shoot tips from mature guayule (Parthenium argentatum Gray) plants

    E-Print Network [OSTI]

    Callin, Jeffrey Michael

    1990-01-01T23:59:59.000Z

    10 mL Glacial acetic acid overnight Dehydration Series, Tertiary Butyl Alcohol 1. 50% Dehydration Solution 50 mL distilled water 40 mL 95% Ethyl alcohol 10 mL Tertiary butyl alcohol (t-BuOH) . 2. 70% dehydration solution 30 mL distilled water... alcohol 75 mL -BuOH 2 hours overnight 1 hour 1 hour 1 hour 37 6. Pure t-BuOH 7. Pure t-BuOH 8. Pure t-BuOH 9. Equal volumes t-BuOH and parrifin oil 1 hour overnight 1 hour 24 hours 10. Fill small vials half full with melted parrifin...

  13. European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3.115 NON-LINEAR MECHANICAL PROPERTIES OF ETHYLENE-VINYL ACETATE (EVA) AND ITS

    E-Print Network [OSTI]

    25th European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3,2 1 Institute for Solar Energy Research Hamelin (ISFH), Am Ohrberg 1, D-31860 Emmerthal, Germany 2 ABSTRACT: Polymers such as ethylene-vinyl acetate (EVA) encapsulants are known for their non

  14. CHEMICAL PROCESS RESEARCH AND DEVELOPMENT PROGRAM. Chapter from the Energy and Environment Division Annual Report 1980

    E-Print Network [OSTI]

    Authors, Various

    2014-01-01T23:59:59.000Z

    fermentation can occur with- out the production of acetic acid,fermentation produced by this organism grow- ing with D-xylose are ethanol, acetone, and acetic acid.

  15. ENERGY & ENVIRONMENT DIVISION. ANNUAL REPORT FY 1980

    E-Print Network [OSTI]

    Authors, Various

    2010-01-01T23:59:59.000Z

    fermentation can occur with- out the production of acetic acid.fermentation produced by this organism grow- ing with D-xylose are ethanol, acetone, and acetic acid.

  16. acidization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  17. acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  18. Acid Ions are More Than Spectators

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas-phase studies. The discovery suggests that it is not simply the release of protons - hydrogen ions - that is important for the properties of acids. When a strong acid, such as...

  19. Recovery of mercury from acid waste residues

    DOE Patents [OSTI]

    Greenhalgh, W.O.

    1987-02-27T23:59:59.000Z

    Mercury can be recovered from nitric acid-containing fluids by reacting the fluid with aluminum metal to produce mercury metal, and thence quenching the reactivity of the nitric acid prior to nitration of the mercury metal. 1 fig.

  20. Fuel cell electrolyte membrane with acidic polymer

    DOE Patents [OSTI]

    Hamrock, Steven J. (Stillwater, MN); Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

    2009-04-14T23:59:59.000Z

    An electrolyte membrane is formed by an acidic polymer and a low-volatility acid that is fluorinated, substantially free of basic groups, and is either oligomeric or non-polymeric.

  1. amino acid intake: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    protein intake (PDI) and net portal appearance rate of amino acids by continuous infusion of para-aminohippuric acid via the mesenteric catheter. The amino-acid appearance...

  2. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

  3. Reactions Between Water Soluble Organic Acids and Nitrates in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Between Water Soluble Organic Acids and Nitrates in Atmospheric Aerosols: Recycling of Nitric Acid and Formation of Reactions Between Water Soluble Organic Acids and Nitrates in...

  4. acid anew insights: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the sequence of amino acids produced, and because amino acids average about Texas at San Antonio, University of 290 Combined Acid Catalysis for Asymmetric Synthesis Chemistry...

  5. acid synthase impacts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acid utilization and glucose oxidation. Glucose... Adhikari, Sean 2006-10-30 246 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  6. Chemical Additive Selection in Matrix Acidizing

    E-Print Network [OSTI]

    Weidner, Jason 1981-

    2011-05-09T23:59:59.000Z

    critical detail of weak acid chemistry. One concern when using any acid in oilfield operations is the corrosion of well tubulars. Thus operators often choose to pump corrosion inhibitor, a chemical additive electrostatically attracted... to the negative charge of the well casing or production tubing, to decrease the rate at which the acid accesses well tubular surfaces (Crowe and Minor 1985). A typical working concentration of corrosion inhibitor is 1-2 wt% of injected acid (Smith et al. 1978...

  7. Organic Acid Production by Filamentous Fungi

    E-Print Network [OSTI]

    -being. Indeed, organic acid fermentations are often not even identified as fungal bioprocesses, having been Aspergillus niger in aerated stirred-tank-reactors can convert glucose to citric acid with greater than 80 lipolytica, and related yeast species, may be in use commercially to produce citric acid (Lopez-Garcia, 2002

  8. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander (La Jolla, CA); Cropp, T. Ashton (Bethesda, MD); Chin, Jason W. (Cambridge, GB); Anderson, J. Christopher (San Francisco, CA); Schultz, Peter G. (La Jolla, CA)

    2011-08-09T23:59:59.000Z

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNAsyn-thetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  9. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, Ashton T; Chin, Jason W; Anderson, Christopher J; Schultz, Peter G

    2013-05-21T23:59:59.000Z

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  10. Unnatural reactive amino acid genetic code additions

    DOE Patents [OSTI]

    Deiters, Alexander; Cropp, T. Ashton; Chin, Jason W.; Anderson, J. Christopher; Schultz, Peter G.

    2014-08-26T23:59:59.000Z

    This invention provides compositions and methods for producing translational components that expand the number of genetically encoded amino acids in eukaryotic cells. The components include orthogonal tRNAs, orthogonal aminoacyl-tRNA synthetases, orthogonal pairs of tRNAs/synthetases and unnatural amino acids. Proteins and methods of producing proteins with unnatural amino acids in eukaryotic cells are also provided.

  11. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, Luc (Lakewood, CO)

    1999-01-01T23:59:59.000Z

    A process of preparing an acid addition salt of delta-aminolevulinic acid comprising: dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures thereof to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing said alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  12. Synthesis of an acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters

    DOE Patents [OSTI]

    Moens, L.

    1999-05-25T23:59:59.000Z

    A process is disclosed for preparing an acid addition salt of delta-aminolevulinic acid comprising. The process involves dissolving a lower alkyl 5-bromolevulinate and an alkali metal diformylamide in an organic solvent selected from the group consisting of acetonitrile, methanol, tetrahydrofuran, 2-methyltetrahydrofuran and methylformate or mixtures to form a suspension of an alkyl 5-(N,N-diformylamino) levulinate ester; and hydrolyzing the alkyl 5-(N,N-diformylamino) levulinate with an inorganic acid to form an acid addition salt of delta-amino levulinic acid.

  13. CHAPTER 13. ACID RAIN Acid rain was discovered in the 19th century by Robert Angus

    E-Print Network [OSTI]

    Jacob, Daniel J.

    247 CHAPTER 13. ACID RAIN Acid rain was discovered in the 19th century by Robert Angus Smith, a pharmacist from Manchester (England), who measured high levels of acidity in rain falling over industrial decline of fish populations in the lakes of southern Norway and traced the problem to acid rain. Similar

  14. Fate of Acids in Clouds 1. Combination with bases dissolved in clouds: acids neutralized

    E-Print Network [OSTI]

    Schofield, Jeremy

    problems. E#11;ects of Acid Rain 1. Vegetation: SO 2 is toxic to plants #15; Leaves damaged below pH 3 rain { Athens and Rome cathedrals and statues: pollution leads to acid rain #15; SteelFate of Acids in Clouds 1. Combination with bases dissolved in clouds: acids neutralized NH 3 (g

  15. Evaluation of acid fracturing based on the "acid fracture number" concept

    E-Print Network [OSTI]

    Alghamdi, Abdulwahab

    2006-08-16T23:59:59.000Z

    ................................................................................................. 29 4.2.1 Initial Pad Volume ........................................................................... 29 4.2.2 Acid Strength and Volume...............................................................30 V... stages of pad fluids and acids.11 The reaction of HCl with carbonate formations is fast, especially at high temperatures. This means that the acid will not be able to penetrate deeply down the fracture, which may affect the outcome of acid fracturing...

  16. Organics Characterization Of DWPF Alternative Reductant Simulants, Glycolic Acid, And Antifoam 747

    SciTech Connect (OSTI)

    White, T. L. [Savannah River Site (SRS), Aiken, SC (United States); Wiedenman, B. J. [Savannah River Site (SRS), Aiken, SC (United States); Lambert, D. P. [Savannah River Site (SRS), Aiken, SC (United States); Crump, S. L. [Savannah River Site (SRS), Aiken, SC (United States); Fondeur, F. F. [Savannah River Site (SRS), Aiken, SC (United States); Papathanassiu, A. E. [Catholic University of America Vitreous State Laboratory, Washington, DC (United States); Kot, W. K. [Catholic University of America Vitreous State Laboratory, Washington, DC (United States); Pegg, I. L. [Catholic University of America Vitreous State Laboratory, Washington, DC (United States)

    2013-10-01T23:59:59.000Z

    The present study examines the fate of glycolic acid and other organics added in the Chemical Processing Cell (CPC) of the Defense Waste Processing Facility (DWPF) as part of the glycolic alternate flowsheet. Adoption of this flowsheet is expected to provide certain benefits in terms of a reduction in the processing time, a decrease in hydrogen generation, simplification of chemical storage and handling issues, and an improvement in the processing characteristics of the waste stream including an increase in the amount of nitrate allowed in the CPC process. Understanding the fate of organics in this flowsheet is imperative because tank farm waste processed in the CPC is eventually immobilized by vitrification; thus, the type and amount of organics present in the melter feed may affect optimal melt processing and the quality of the final glass product as well as alter flammability calculations on the DWPF melter off gas. To evaluate the fate of the organic compounds added as the part of the glycolic flowsheet, mainly glycolic acid and antifoam 747, samples of simulated waste that was processed using the DWPF CPC protocol for tank farm sludge feed were generated and analyzed for organic compounds using a variety of analytical techniques at the Savannah River National Laboratory (SRNL). These techniques included Ion Chromatography (IC), Gas Chromatography-Mass Spectrometry (GC-MS), Inductively Coupled Plasma-Atomic Emission Spectroscopy (ICP-AES), and Nuclear Magnetic Resonance (NMR) Spectroscopy. A set of samples were also sent to the Catholic University of America Vitreous State Laboratory (VSL) for analysis by NMR Spectroscopy at the University of Maryland, College Park. Analytical methods developed and executed at SRNL collectively showed that glycolic acid was the most prevalent organic compound in the supernatants of Slurry Mix Evaporator (SME) products examined. Furthermore, the studies suggested that commercially available glycolic acid contained minor amounts of impurities such as formic and diglycolic acid that were then carried over in the SME products. Oxalic acid present in the simulated tank farm waste was also detected. Finally, numerous other compounds, at low concentrations, were observed present in etheric extracts of aqueous supernate solutions of the SME samples and are thought to be breakdown products of antifoam 747. The data collectively suggest that although addition of glycolic acid and antifoam 747 will introduce a number of impurities and breakdown products into the melter feed, the concentrations of these organics is expected to remain low and may not significantly impact REDOX or off-gas flammability predictions. In the SME products examined presently, which contained variant amounts of glycolic acid and antifoam 747, no unexpected organic degradation product was found at concentrations above 500 mg/kg, a reasonable threshold concentration for an organic compound to be taken into account in the REDOX modeling. This statement does not include oxalic or formic acid that were sometimes observed above 500 mg/kg and acetic acid that has an analytical detection limit of 1250 mg/kg due to high glycolate concentration in the SME products tested. Once a finalized REDOX equation has been developed and implemented, REDOX properties of known organic species will be determined and their impact assessed. Although no immediate concerns arose during the study in terms of a negative impact of organics present in SME products of the glycolic flowsheet, evidence of antifoam degradation suggest that an alternative antifoam to antifoam 747 is worth considering. The determination and implementation of an antifoam that is more hydrolysis resistant would have benefits such as increasing its effectiveness over time and reducing the generation of degradation products.

  17. Solid-state actinide acid phosphites from phosphorous acid melts

    SciTech Connect (OSTI)

    Oh, George N. [Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, IN 46556 (United States); Burns, Peter C., E-mail: pburns@nd.edu [Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, 156 Fitzpatrick Hall, Notre Dame, IN 46556 (United States); Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556 (United States)

    2014-07-01T23:59:59.000Z

    The reaction of UO{sub 3} and H{sub 3}PO{sub 3} at 100 C and subsequent reaction with dimethylformamide (DMF) produces crystals of the compound (NH{sub 2}(CH{sub 3}){sub 2})[UO{sub 2}(HPO{sub 2}OH)(HPO{sub 3})]. This compound crystallizes in space group P2{sub 1}/n and consists of layers of uranyl pentagonal bipyramids that share equatorial vertices with phosphite units, separated by dimethylammonium. In contrast, the reaction of phosphorous acid and actinide oxides at 210 C produces a viscous syrup. Subsequent dilution in solvents and use of standard solution-state methods results in the crystallization of two polymorphs of the actinide acid phosphites An(HPO{sub 2}OH){sub 4} (An=U, Th) and of the mixed acid phosphitephosphite U(HPO{sub 3})(HPO{sub 2}OH){sub 2}(H{sub 2}O)2(H{sub 2}O). ?- and ?-An(HPO{sub 2}OH){sub 4} crystallize in space groups C2/c and P2{sub 1}/n, respectively, and comprise a three-dimensional network of An{sup 4+} cations in square antiprismatic coordination corner-sharing with protonated phosphite units, whereas U(HPO{sub 3})(HPO{sub 2}OH){sub 2}(H{sub 2}O){sub 2}(H{sub 2}O) crystallizes in a layered structure in space group Pbca that is composed of An{sup 4+} cations in square antiprismatic coordination corner-sharing with protonated phosphites and water ligands. We discuss our findings in using solid inorganic reagents to produce a solution-workable precursor from which solid-state compounds can be crystallized. - Graphical abstract: Reaction of UO{sub 3} and H{sub 3}PO{sub 3} at 100 C and subsequent reaction with DMF produces crystals of (NH{sub 2}(CH{sub 3}){sub 2})[UO{sub 2}(HPO{sub 2}OH)(HPO{sub 3})] with a layered structure. Reaction of phosphorous acid and actinide oxides at 210 C produces a viscous syrup and further solution-state reactions result in the crystallization of the actinide acid phosphites An(HPO{sub 2}OH){sub 4} (An=U, Th), with a three-dimensional network structure, and the mixed acid phosphitephosphite U(HPO{sub 3})(HPO{sub 2}OH){sub 2}(H{sub 2}O){sub 2}(H{sub 2}O) with a layered structure. - Highlights: U(VI), U(IV) and Th(IV) phosphites were synthesized by solution-state methods. A new uranyl phosphite structure is based upon uranyl phosphite anionic sheets. New U and Th phosphites have framework structures.

  18. Micro-electro-mechanical systems phosphoric acid fuel cell

    DOE Patents [OSTI]

    Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

    2010-12-21T23:59:59.000Z

    A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

  19. Micro-electro-mechanical systems phosphoric acid fuel cell

    DOE Patents [OSTI]

    Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

    2010-08-17T23:59:59.000Z

    A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

  20. acid bacteria isolates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acids are solids not liquids. They sublime under vacuum to compare the strengths of solid acids with liquid acids therefore led us to obtain a measure of acidity in dilute...

  1. acid bacteria isolated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acids are solids not liquids. They sublime under vacuum to compare the strengths of solid acids with liquid acids therefore led us to obtain a measure of acidity in dilute...

  2. The utilization of tricarboxylic acid cycle acids and the uptake of succinic acid by Neurospora crassa

    E-Print Network [OSTI]

    Gilliland, Patti Lynn

    1978-01-01T23:59:59.000Z

    ~50 V E 0 40 V V Z 30 V Ih 'a 20 0 0 V 10 LEGEND ?, pH 4. l --~pH 7A) 0 0 8 12 16 20 TIME, minutes Figure 1. Time Course of Uptake and Accumulation of Succinic Acid at pH 4. 1 and pH 7. 0 (25'C). Each point represents means for data... to 20 140 pH 4. 1 25 C pH 7. 0 g 120 F100 I ~sc E ef 80 Z V lJ ul 40 0 p 40 2 Z 3'C 20 0 0 5 10 15 20 0 5 10 15 20 TIME, minutes Figure 2. Effect of Temperature on Uptake and Accumulation of Succinic Acid. External concentration...

  3. Double stranded nucleic acid biochips

    DOE Patents [OSTI]

    Chernov, Boris; Golova, Julia

    2006-05-23T23:59:59.000Z

    This invention describes a new method of constructing double-stranded DNA (dsDNA) microarrays based on the use of pre-synthesized or natural DNA duplexes without a stem-loop structure. The complementary oligonucleotide chains are bonded together by a novel connector that includes a linker for immobilization on a matrix. A non-enzymatic method for synthesizing double-stranded nucleic acids with this novel connector enables the construction of inexpensive and robust dsDNA/dsRNA microarrays. DNA-DNA and DNA-protein interactions are investigated using the microarrays.

  4. Solvent extraction of inorganic acids

    E-Print Network [OSTI]

    Ysrael, Miguel Curie

    1965-01-01T23:59:59.000Z

    Page 10 27 NOi'!: KCL ITU8l: BIBLIOG. :l PI!Y ct:"P. '. t:OI:t 28 30 32 LIDT DF FIGUP, . " Al'!D T?DL. '. I F igure . olubility curve of wat-r and glycerol etl'er s I-'age 4 3 ~ '=quilibrium diagram for amyl alcohol- water-HC1... Correlation of eq;ilibrium da!. a of amyl alcohol-water-HC1 12 13 ~ ~ selectivity diagram for alcohol- 5 ~, '~electivity diagram for ethers G. Mole fr:ction di=tribution diagrav. . 7 ~ Activity coefficient of acids in water 0 ~ "ctivity coefficient...

  5. ARM - Lesson Plans: Acid Rain

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow, Alaska Outreach Home RoomPlans OutreachAcid

  6. Development Of Ion Chromatography Methods To Support Testing Of The Glycolic Acid Reductant Flowsheet In The Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Wiedenman, B. J.; White, T. L.; Mahannah, R. N.; Best, D. R.; Stone, M. E.; Click, D. R.; Lambert, D. P.; Coleman, C. J.

    2013-10-01T23:59:59.000Z

    Ion Chromatography (IC) is the principal analytical method used to support studies of Sludge Reciept and Adjustment Tank (SRAT) chemistry at DWPF. A series of prior analytical ''Round Robin'' (RR) studies included both supernate and sludge samples from SRAT simulant, previously reported as memos, are tabulated in this report.2,3 From these studies it was determined to standardize IC column size to 4 mm diameter, eliminating the capillary column from use. As a follow on test, the DWPF laboratory, the PSAL laboratory, and the AD laboratory participated in the current analytical RR to determine a suite of anions in SRAT simulant by IC, results also are tabulated in this report. The particular goal was to confirm the laboratories ability to measure and quantitate glycolate ion. The target was + or - 20% inter-lab agreement of the analyte averages for the RR. Each of the three laboratories analyzed a batch of 12 samples. For each laboratory, the percent relative standard deviation (%RSD) of the averages on nitrate, glycolate, and oxalate, was 10% or less. The three laboratories all met the goal of 20% relative agreement for nitrate and glycolate. For oxalate, the PSAL laboratory reported an average value that was 20% higher than the average values reported by the DWPF laboratory and the AD laboratory. Because of this wider window of agreement, it was concluded to continue the practice of an additional acid digestion for total oxalate measurement. It should also be noted that large amounts of glycolate in the SRAT samples will have an impact on detection limits of near eluting peaks, namely Fluoride and Formate. A suite of scoping experiments are presented in the report to identify and isolate other potential interlaboratory disceprancies. Specific ion chromatography inter-laboratory method conditions and differences are tabulated. Most differences were minor but there are some temperature control equipment differences that are significant leading to a recommendation of a heated jacket for analytical columns that are remoted for use in radiohoods. A suggested method improvement would be to implement column temperture control at a temperature slightly above ambient to avoid peak shifting due to temperature fluctuations. Temperature control in this manner would improve short and longer term peak retention time stability. An unknown peak was observed during the analysis of glycolic acid and SRAT simulant. The unknown peak was determined to best match diglycolic acid. The development of a method for acetate is summaraized, and no significant amount of acetate was observed in the SRAT products tested. In addition, an alternative Gas Chromatograph (GC) method for glycolate is summarized.

  7. Self-assembling multimeric nucleic acid constructs

    DOE Patents [OSTI]

    Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

    1999-10-12T23:59:59.000Z

    The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

  8. Self-assembling multimeric nucleic acid constructs

    DOE Patents [OSTI]

    Cantor, Charles R. (Boston, MA); Niemeyer, Christof M. (Bremen, DE); Smith, Cassandra L. (Boston, MA); Sano, Takeshi (Boston, MA); Hnatowich, Donald J. (Brookline, MA); Rusckowski, Mary (Southborough, MA)

    1996-01-01T23:59:59.000Z

    The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products.

  9. Self-assembling multimeric nucleic acid constructs

    DOE Patents [OSTI]

    Cantor, C.R.; Niemeyer, C.M.; Smith, C.L.; Sano, Takeshi; Hnatowich, D.J.; Rusckowski, M.

    1996-10-01T23:59:59.000Z

    The invention is directed to constructs and compositions containing multimeric forms of nucleic acid. Multimeric nucleic acids comprise single-stranded nucleic acids attached via biotin to streptavidin and bound with a functional group. These constructs can be utilized in vivo to treat or identify diseased tissue or cells. Repeated administrations of multimeric nucleic acid compositions produce a rapid and specific amplification of nucleic acid constructs and their attached functional groups. For treatment purposes, functional groups may be toxins, radioisotopes, genes or enzymes. Diagnostically, labeled multimeric constructs may be used to identify specific targets in vivo or in vitro. Multimeric nucleic acids may also be used in nanotechnology and to create self-assembling polymeric aggregates such as membranes of defined porosity, microcircuits and many other products. 5 figs.

  10. Novel Regenerated Solvent Extraction Processes for the Recovery of Carboxylic Acids or Ammonia from Aqueous Solutions Part I. Regeneration of Amine-Carboxylic Acid Extracts

    E-Print Network [OSTI]

    Poole, L.J.

    2008-01-01T23:59:59.000Z

    production of citric acid by fermentation, recovery of theof Citric Acid from Aqueous Fermentation Solutions byof citric acid was 1.1.1 Lactic Acid Currently, fermentation

  11. PREDICTING TEMPERATURE BEHAVIOR IN CARBONATE ACIDIZING TREATMENTS

    E-Print Network [OSTI]

    Tan, Xuehao

    2010-01-16T23:59:59.000Z

    is the temperature of injected acid. A program is developed to solve the energy balance equation numerically and the flow chart is shown below (Fig. 2.4). 17 Fig. 2.4?Flow chart for programming acid injection problem Start Time Step, p.................................................. 8 2.3 Core flow test results. Pore volumes to breakthrough as a function of injection rate. (Buijse and Glasbergen 2005) ........................................... 13 2.4 Flow chart for programming acid injection problem...

  12. Carboxylic acid accelerated formation of diesters

    DOE Patents [OSTI]

    Tustin, G.C.; Dickson, T.J.

    1998-04-28T23:59:59.000Z

    This invention pertains to accelerating the rate of formation of 1,1-dicarboxylic esters from the reaction of an aldehyde with a carboxylic acid anhydride or a ketene in the presence of a non-iodide containing a strong Bronsted acid catalyst by the addition of a carboxylic acid at about one bar pressure and between about 0 and 80 C in the substantial absence of a hydrogenation or carbonylation catalyst.

  13. Acid rain information book. Draft final report

    SciTech Connect (OSTI)

    None

    1980-12-01T23:59:59.000Z

    Acid rain is one of the most widely publicized environmental issues of the day. The potential consequences of increasingly widespread acid rain demand that this phenomenon be carefully evaluated. Reveiw of the literature shows a rapidly growing body of knowledge, but also reveals major gaps in understanding that need to be narrowed. This document discusses major aspects of the acid rain phenomenon, points out areas of uncertainty, and summarizes current and projected research by responsible government agencies and other concerned organizations.

  14. Electrochemical detection of organic acids for anaerobic-digestor control and identification of biocorrosion inception on ferrous substrates. Final report, January 1-December 31, 1990

    SciTech Connect (OSTI)

    Cook, R.L.; Patel, J.; Sammells, A.F.

    1991-01-01T23:59:59.000Z

    The program was directed towards developing in situ techniques for the detection of organic acids present in both anaerobic digestors and as a result of microbial induced corrosion (MIC). The investigation was extneded to include investigating microprobes for pH and chloride ion detection as a strategy for gaining insight into the mechanism of MIC. Experimental work identified a reversible fiber optic chemical sensor for acetate detection in aqueous solution based upon the use of rhodium octaethylporphine immobilized as a molecular host on a fiber optic substrate. Data obtained from systematically performed electrochemical measurements on gas pipeline steel in simulated bacterial metabolite mixtures were analyzed using multivariante statistical analysis; however, no definitive conclusions could be made as to the relative influence of factors aggrevating MIC induced corrosion processes. Fabrication of microelectrodes compatible for monitoring of chloride and pH in MIC corrosion pits was achieved and initial testing performed.

  15. Acid Doped Membranes for High Temperature PEMFC

    Broader source: Energy.gov [DOE]

    Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  16. Lead acetate induces EGFR activation upstream of SFK and PKC{alpha} linkage to the Ras/Raf-1/ERK signaling

    SciTech Connect (OSTI)

    Wang, C.-Y.; Wang, Y.-T.; Tzeng, D.-W. [Molecular Carcinogenesis Laboratory, Institute of Biotechnology and Department of Life Sciences, National Tsing Hua University, Hsinchu 30013, Taiwan (China); Yang, J.-L. [Molecular Carcinogenesis Laboratory, Institute of Biotechnology and Department of Life Sciences, National Tsing Hua University, Hsinchu 30013, Taiwan (China)], E-mail: jlyang@life.nthu.edu.tw

    2009-03-01T23:59:59.000Z

    Lead acetate (Pb), a probable human carcinogen, can activate protein kinase C (PKC) upstream of extracellular signal-regulated kinase 1 and 2 (ERK1/2). Yet, it remains unclear whether Pb activation of PKC {yields} ERK1/2 involves receptor/non-receptor tyrosine kinases and the Ras signaling transducer. Here we demonstrate a novel mechanism elicited by Pb for transmitting ERK1/2 signaling in CL3 human non-small-cell lung adenocarcinoma cells. Pb induction of higher steady-state levels of Ras-GTP was essential for increasing phospho-Raf-1{sup S338} and phospho-ERK1/2. Pre-treatment of the cells with a conventional PKC inhibitor Goe6976 or depleting PKC{alpha} using specific small interfering RNA blocked Pb induction of Ras-GTP. Pb also activated cellular tyrosine kinases. Specific pharmacological inhibitors, PD153035 for epidermal growth factor receptor (EGFR) and SU6656 for Src family tyrosine kinases (SFK), but not AG1296 for platelet-derived growth factor receptor, could suppress the Pb-induced tyrosine kinases, PKC{alpha}, Ras-GTP, phospho-Raf-1{sup S338} and phospho-ERK1/2. Furthermore, phosphorylation of tyrosines on the EGFR multiple autophosphorylation sites and the conserved SFK autophosphorylation site occurred during exposure of cells to Pb for 1-5 min and 5-30 min, respectively. Intriguingly, Pb activation of EGFR required the intrinsic kinase activity but not dimerization of the receptor. Inhibition of SFK or PKC{alpha} activities did not affect EGFR phosphorylation, while knockdown of EGFR blocked SFK phosphorylation and PKC{alpha} activation following Pb. Together, these results indicate that immediate activation of EGFR in response to Pb is obligatory for activation of SFK and PKC{alpha} and subsequent the Ras-Raf-1-MKK1/2-ERK1/2 signaling cascade.

  17. Development of Low Cost Membranes (Ta, Nb & Cellulose Acetate) for H{sub 2}/CO{sub 2} Separation in WGS Reactors

    SciTech Connect (OSTI)

    Naidu Seetala; Upali Siriwardane

    2011-06-30T23:59:59.000Z

    The main aim of this work is to synthesize low temperature bimetallic nanocatalysts for Water Gas Shift reaction (WGS) for hydrogen production from CO and steam mixture; and develop low-cost metal (Nb/Ta)/ceramic membranes for H{sub 2} separation and Cellulose Acetate membranes for CO{sub 2} separation. Cu-Ni-Ce/alumina, Fe-Ni-Ce/alumina granular WGS catalysts incorporating metal oxide nanoparticles into alumina support were prepared using sol-gel/oil-drop methods. The catalysts were characterized by Powder X-ray Diffractometer (PXRD), Scanning Electron Microscope (SEM), Differential Thermal Analyzer (DTA), Thermal Gravitational Analyzer (TGA), and Brunauer, Emmett and Teller (BET) techniques. TGA shows sharp weight loss at approximately 215°C and DTA shows dehydration of metal hydroxides between 200°C and 250°C. The PXRD spectra show an increase in crystallinity as a result of heating to 1000°C, and indicating a fine dispersion of the metal oxide nanoparticles in alumina supports during the sol-gel synthesis and calcination at 450°C. BET analysis indicated a mesoporous structure of the granules with high surface area. A gas-phase dynamic flow reactor is used to optimize the reaction temperatures. A gas-phase batch reactor was used to obtain kinetic data and the parameters for maximum CO conversion. In Cu-Ni-Ce/alumina category, Cu(0%)Ni(10%)Ce(11%) was found to be the best WGS catalyst among six Low Temperature Shift (LTS) catalysts with optimum temperatures between 200-300?°C, while Ni(5%)Cu(5%)Ce(11%) was found to be the best among four High Temperature Shift (HTS) catalysts with optimum temperature between 350-400°C. In the Fe-Ni-Ce/alumina category catalysts, Fe(8%)Ni(0%)Ce(8%)/alumina and Fe(6%)Ni(2%)Ce(8%)/alumina catalysts showed optimum WGS reaction temperature below 150°C. All Ni(8-x%)Fe(x%)Ce(8%) had lower WGS reaction efficiencies compared to Ni(8-x%)Cu(x%)Ce(8%). Metal (Nb or Ta)/ceramic membranes for hydrogen separation from the WGS reaction gas products have been prepared using a) sputtering and b) aluminothermic techniques. A polyvinyl-glass permeability tester was used with a gas chromatograph (GC) for H{sub 2}/CO permeability testing. Nb films showed a higher permeability than Ta at a given disk porosity. The aluminothermically deposited membranes have higher H{sub 2} permeability compared to the sputtered films, and Nb-film coated disks showed lower H{sub 2} permeability than Ta-film. A three-stage prototype stainless steel reactor with integrated housing for 1) WGS reaction catalysts, 2) H{sub 2}/CO{sub 2} separation metal/ceramic or metal/asbestos membranes, and 3) CO/CO{sub 2} separation cellulose acetate /filter-paper membranes has been designed and tested to have capabilities to perform WGS reactions at temperatures up to 400°C and withstand gas pressures up to 15 bars. The cracking of ceramic disks and gas leaks were successfully prevented by replacing ceramic disks with asbestos sheets that can easily withstand 400°C. Kinetic studies of H{sub 2} and CO permeabilities were performed through the single and double layer Nb and Ta membranes. Cellulose acetate (CA) films with 25% triethyl citrate (TEC) as plasticizer were prepared for H{sub 2}/CO/CO{sub 2} gas separation with varying thickness of the films by acetone solutions at different concentrations and by dip-coating onto filter papers. The AFM analysis of the CA membrane showed that the uniform coating had fewer and smaller pores as the film thickness increased, and corroborated by gas permeability studies. The CO{sub 2} permeability has decreased faster than CO permeability with the CA/TEC membrane thickness, and findings support that the CA membrane could be used to entrap CO{sub 2}. Several CA/TEC membranes were also staked to increase the separation efficiency. Positron Lifetime Spectroscopy (PLS) was used to estimate the micro-porosity (pore size and concentration) and fractional free volume changes of CA/TEC films, and used to understand the variations observed in the CO{sub 2}/CO permeabilities.

  18. acid-dependent ribonucleic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 40 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  19. acid n-glycolylneuraminic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by USDA and U of I researchers Illinois at Urbana-Champaign, University of 7 Controlling acid rain MIT - DSpace Summary: High concentrations of sulfuric and nitric acid in raTn fn...

  20. Decomposition Studies of Triphenylboron, Diphenylborinic Acid and Phenylboric Acid in Aqueous Alkaline Solutions Containing Copper

    SciTech Connect (OSTI)

    Crawford, C.L. [Westinghouse Savannah River Company, AIKEN, SC (United States); Peterson, R. A.

    1997-02-11T23:59:59.000Z

    This report documents the copper-catalyzed chemical kinetics of triphenylboron, diphenylborinic acid and phenylboric acid (3PB, 2PB and PBA) in aqueous alkaline solution contained in carbon-steel vessels between 40 and 70 degrees C.

  1. The East Penn process for recycling sulfuric acid from lead-acid batteries

    SciTech Connect (OSTI)

    Leiby, R.; Bricker, M. [East Penn Manufacturing Co., Inc., Lyon Station, PA (United States); Spitz, R. [Spitz (R.), Holbrook, MA (United States)

    1995-12-31T23:59:59.000Z

    Prior to March 1992, the only component of the lead-acid battery that was not recycled by East Penn Manufacturing Company was the sulfuric acid electrolyte. This acid was unusable in new batteries because the iron level was found to exceed new product specifications. The development of a liquid ion exchange process to remove the iron from the acid allows East Penn to currently recover over three million gallons of sulfuric acid annually. The process is based upon the use of an iron selective liquid ion exchange material or solvent to extract iron from the sulfuric acid electrolyte followed by regeneration of the solvent. Equilibrium and kinetic data for the extraction and regeneration steps were collected in order to scale up the process to commercial scale. An electrochemical process for the treatment of the acid used in the regeneration step was also developed which significantly reduces the volume of strip acid required in the process.

  2. Effects of Acid Additives on Spent Acid Flowback through Carbonate Cores

    E-Print Network [OSTI]

    Nasir, Ehsaan Ahmad

    2012-07-16T23:59:59.000Z

    these challenges, different chemicals, or additives, are added to the acid solution such as corrosion inhibitors and iron control agents. These additives may change the relative permeability of the spent acid, and formation wettability, and may either hinder...

  3. A method to attenuate U(VI) mobility in acidic waste plumes using humic acids

    E-Print Network [OSTI]

    Wan, J.

    2011-01-01T23:59:59.000Z

    base properties of a goethite surface model: A theoreticalcomplexation of U(VI) on goethite (alpha-FeOOH). Geochim.acid and humic-acid on goethite, gibbsite and imogolite. J.

  4. BNL Citric Acid Technology: Pilot Scale Demonstration

    SciTech Connect (OSTI)

    FRANCIS, A J; DODGE,; J, C; GILLOW, J B; FORRESTER, K E

    1999-09-24T23:59:59.000Z

    The objective of this project is to remove toxic metals such as lead and cadmium from incinerator ash using the Citric Acid Process developed at Brookhaven National Laboratory. In this process toxic metals in bottom ash from the incineration of municipal solid waste were first extracted with citric acid followed by biodegradation of the citric acid-metal extract by the bacterium Pseudomonas fluorescens for metals recovery. The ash contained the following metals: Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Se, Sr, Ti, and Zn. Optimization of the Citric Acid Process parameters which included citric acid molarity, contact time, the impact of mixing aggressiveness during extraction and pretreatment showed lead and cadmium removal from incinerator ash of >90%. Seeding the treated ash with P. fluorescens resulted in the removal of residual citric acid and biostabilization of any leachable lead, thus allowing it to pass EPA?s Toxicity Characteristic Leaching Procedure. Biodegradation of the citric acid extract removed >99% of the lead from the extract as well as other metals such as Al, Ca, Cu, Fe, Mg, Mn, Ti, and Zn. Speciation of the bioprecipitated lead by Extended X-ray Absorption Fine Structure at the National Synchrotron Light Source showed that the lead is predominantly associated with the phosphate and carboxyl functional groups in a stable form. Citric acid was completely recovered (>99%) from the extract by sulfide precipitation technique and the extraction efficiency of recovered citric acid is similar to that of the fresh citric acid. Recycling of the citric acid should result in considerable savings in the overall treatment cost. We have shown the potential application of this technology to remove and recover the metal contaminants from incinerator ash as well as from other heavy metal bearing wastes (i.e., electric arc furnace dust from steel industry) or soils. Information developed from this project is being applied to demonstrate the remediation of lead paint contaminated soils on Long Island.

  5. Nitrates and Prussic Acid in Forages

    E-Print Network [OSTI]

    Provin, Tony; Pitt, John L.

    2003-01-06T23:59:59.000Z

    When nitrates and prussic acid accumulate in forage, the feed may not be safe for livestock consumption. Learn the symptoms of nitrate and prussic acid poisoning and which plants are most likely to pose a risk to livestock. Also learn sampling...

  6. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, M.M.; Shoup, T.

    1998-10-06T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is [{sup 18}F]-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an {alpha}-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of {alpha}-aminoisobutyric acid.

  7. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, M.M.; Shoup, T.

    1998-09-15T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is [{sup 18}F]-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an {alpha}-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of {alpha}-aminoisobutyric acid.

  8. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, Mark M. (Atlanta, GA); Shoup, Timothy (Decatur, GA)

    1998-09-15T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is .sup.18 F!-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an .alpha.-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of .alpha.-aminoisobutyric acid.

  9. Amino acid analogs for tumor imaging

    DOE Patents [OSTI]

    Goodman, Mark M. (Atlanta, GA); Shoup, Timothy (Decatur, GA)

    1998-10-06T23:59:59.000Z

    The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is .sup.18 F!-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an .alpha.-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of .alpha.-aminoisobutyric acid.

  10. Nanoparticles modified with multiple organic acids

    DOE Patents [OSTI]

    Cook, Ronald Lee (Lakewood, CO); Luebben, Silvia DeVito (Golden, CO); Myers, Andrew William (Arvada, CO); Smith, Bryan Matthew (Boulder, CO); Elliott, Brian John (Superior, CO); Kreutzer, Cory (Brighton, CO); Wilson, Carolina (Arvada, CO); Meiser, Manfred (Aurora, CO)

    2007-07-17T23:59:59.000Z

    Surface-modified nanoparticles of boehmite, and methods for preparing the same. Aluminum oxyhydroxide nanoparticles are surface modified by reaction with selected amounts of organic acids. In particular, the nanoparticle surface is modified by reactions with two or more different carboxylic acids, at least one of which is an organic carboxylic acid. The product is a surface modified boehmite nanoparticle that has an inorganic aluminum oxyhydroxide core, or part aluminum oxyhydroxide core and a surface-bonded organic shell. Organic carboxylic acids of this invention contain at least one carboxylic acid group and one carbon-hydrogen bond. One embodiment of this invention provides boehmite nanoparticles that have been surface modified with two or more acids one of which additional carries at least one reactive functional group. Another embodiment of this invention provides boehmite nanoparticles that have been surface modified with multiple acids one of which has molecular weight or average molecular weight greater than or equal to 500 Daltons. Yet, another embodiment of this invention provides boehmite nanoparticles that are surface modified with two or more acids one of which is hydrophobic in nature and has solubility in water of less than 15 by weight. The products of the methods of this invention have specific useful properties when used in mixture with liquids, as filler in solids, or as stand-alone entities.

  11. Producing dicarboxylic acids using polyketide synthases

    DOE Patents [OSTI]

    Katz, Leonard; Fortman, Jeffrey L; Keasling, Jay D

    2013-10-29T23:59:59.000Z

    The present invention provides for a polyketide synthase (PKS) capable of synthesizing a dicarboxylic acid (diacid). Such diacids include diketide-diacids and triketide-diacids. The invention includes recombinant nucleic acid encoding the PKS, and host cells comprising the PKS. The invention also includes methods for producing the diacids.

  12. Nitrates and Prussic Acid in Forages

    E-Print Network [OSTI]

    Provin, Tony; Pitt, John L.

    2003-01-06T23:59:59.000Z

    When nitrates and prussic acid accumulate in forage, the feed may not be safe for livestock consumption. Learn the symptoms of nitrate and prussic acid poisoning and which plants are most likely to pose a risk to livestock. Also learn sampling...

  13. Ecology of microbe/basaltic glass interactions : mechanisms and diversity

    E-Print Network [OSTI]

    Sudek, Lisa A.

    2011-01-01T23:59:59.000Z

    fermentation and leads to the production of small organic acids like lactic, acetic, formic, citric,

  14. Graduate School of Energy Science: Outlines of Laboratories Department of SOCIO-ENVIRONMENTAL ENERGY SCIENCE

    E-Print Network [OSTI]

    Takada, Shoji

    acetic acid fermentation, non-catalytic conversion of vegetable oil into biodiesel fuel and molecular

  15. Metabolic Design and Control for Production in Prokaryotes

    E-Print Network [OSTI]

    Chhabra, Swapnil R.

    2011-01-01T23:59:59.000Z

    fermentation. To investigate the effect of the central metabolic flux on the acetic acid

  16. R E S E A R C H A R T I C L E Batch and continuous culture-based selection strategiesforacetic

    E-Print Network [OSTI]

    Wagner, Andreas

    . Abstract Acetic acid tolerance of Saccharomyces cerevisiae is crucial for the production of bioethanol

  17. Journal of Power Sources 132 (2004) 256260 Short communication

    E-Print Network [OSTI]

    Rubloff, Gary W.

    glycol, allyl bromide, lithium tri- fluorosulfonamide and acetic acid were purchased from Aldrich. endo

  18. Surfactant Screening to Alter the Wettability and Aid in Acidizing Carbonate Formations

    E-Print Network [OSTI]

    Yadhalli Shivaprasad, Arun Kumar

    2013-02-26T23:59:59.000Z

    , known as high temperature organic acids (HTO acids), have been found to be useful in acidizing subterranean formations at temperatures up to 400oF. Some of these acids are oxalic acid, malonic acid, pimelic acid, succinic acid, glutaric acid, adipic... acid and their mixtures. In addition to creating wormholes in carbonate formations, HTO acids can remove carbonate scale at high temperatures and cause very low corrosion to the tubing and casing. 6 1.2 Role of Surfactants in Acidizing 1...

  19. Experimental Study of Acid Fracture Conductivity of Austin Chalk Formation

    E-Print Network [OSTI]

    Nino Penaloza, Andrea

    2013-05-01T23:59:59.000Z

    to those in actual acid fracture treatments. After acid etching, fracture conductivity is measured at different closure stresses. This research work presents a systematic study to investigate the effect of temperature, rock-acid contact time and initial...

  20. acid-base imbalance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acid generates a material (PE-C02H Deutch, John 59 Acid-Based Synthesis of Monodisperse Rare-Earth-Doped Colloidal SiO2 Spheres Materials Science Websites Summary: Acid-Based...

  1. Experimental Study of Acid Fracture Conductivity of Austin Chalk Formation

    E-Print Network [OSTI]

    Nino Penaloza, Andrea

    2013-05-01T23:59:59.000Z

    Acid fracture conductivity and the effect of key variables in the etching process during acid fracturing can be assessed at the laboratory scale. This is accomplished by using an experimental apparatus that simulates acid injection fluxes comparable...

  2. Investigations of amino acid-based surfactants at liquid interfaces

    E-Print Network [OSTI]

    Yang, Dengliang

    2005-11-01T23:59:59.000Z

    Herein are presented collective studies of amino acid-based surfactants, also known as lipoamino acids, at liquid interfaces. Chapter III describes an investigation of domain morphology of N-Stearoylglutamic acid (N-SGA) ...

  3. aqueous tartaric acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with limited success.2,3 During the last decade, attention to sulfuric acid anodizing and boric-sulfuric acid Paris-Sud XI, Universit de 255 Si isotope systematics of acidic...

  4. Difunctional carboxylic acid anions in oilfield waters

    SciTech Connect (OSTI)

    MacGowan, D.B.; Surdam, R.C.

    1988-01-01T23:59:59.000Z

    Recent models of porosity enhancement during sandstone diagenesis have called upon the metal complexing ability of difunctional carboxylic acid anions in subsurface waters to explain aluminosilicate dissolution. Although carboxylic acid anions have been known to exist in oilfield waters since the turn of the century, until now the existence of significant concentrations of difunctional carboxylic acid anions has not been documented. Data from this study show that difunctional carboxylic acid anions can exist in concentrations up to 2640 ppm, and can account for nearly 100% of the organic acid anions in some oilfield waters. Formation water samples with exceptionally high concentrations of difunctional carboxylic acid anions are found in reservoirs which are at maximum levels of thermal exposure, and which are presently in the 80-100/sup 0/C thermal window. Plagioclase dissolution experiments performed with natural oilfield waters and artificial solutions indicate that waters with high difunctional acid anion concentrations are capable, by organo-metallic complexation, of being apparently oversaturated with respect to total aluminum concentrations compared to the inorganic solubility of kaolinite by several orders of magnitude. Dissolution experiments simulating a specific geologic environment (Stevens Sandstone, southern San Joaquin Basin, California; using natural oilfield waters and Stevens Sandstone core samples), produced plagioclase and calcite dissolution textures similar to those noted in well cores from the Stevens Sandstone, as well as raising total aluminum concentrations in these experimental solutions several orders of magnitude over the solubility of kaolinite.

  5. Production of Succinic Acid for Lignocellulosic Hydrolysates

    SciTech Connect (OSTI)

    Davison, B.H.; Nghiem, J.

    2002-06-01T23:59:59.000Z

    The purpose of this Cooperative Research and Development Agreement (CRADA) is to add and test new metabolic activities to existing microbial catalysts for the production of succinic acid from renewables. In particular, they seek to add to the existing organism the ability to utilize xylose efficiently and simultaneously with glucose in mixtures of sugars or to add succinic acid production to another strain and to test the value of this new capability for production of succinic acid from industrial lignocellulosic hydrolyasates. The Contractors and Participant are hereinafter jointly referred to as the 'Parties'. Research to date in succinic acid fermentation, separation and genetic engineering has resulted in a potentially economical process based on the use of an Escherichia coli strain AFP111 with suitable characteristics for the production of succinic acid from glucose. Economic analysis has shown that higher value commodity chemicals can be economically produced from succinic acid based on repliminary laboratory findings and predicted catalytic parameters. The initial target markets include succinic acid itself, succinate salts, esters and other derivatives for use as deicers, solvents and acidulants. The other commodity products from the succinic acid platform include 1,4-butanediol, {gamma}-butyrolactone, 2-pyrrolidinone and N-methyl pyrrolidinone. Current economic analyses indicate that this platform is competitive with existing petrochemical routes, especially for the succinic acid and derivatives. The report presents the planned CRADA objectives followed by the results. The results section has a combined biocatalysis and fermentation section and a commercialization section. This is a nonproprietary report; additional proprietary information may be made available subject to acceptance of the appropriate proprietary information agreements.

  6. Relative reactivities of solid benzoic acids

    E-Print Network [OSTI]

    Warwas, Edwin James

    1967-01-01T23:59:59.000Z

    REACTIVITIES OF SOLID BENZOIC ACIDS (January 1967) Edwin James Warwas B. S. , Southwest Texas State College Directed by: Dr. C. K. Hancock and Dr. E. A. Meyers The reactions of solid benzoic acid (BZAH) and nine m- or p- substituted benzoic acids (RBZAH...) with solid potassium benzoate (BZAK) and m- or p-substituted potassium benzoates (R'BZAK) have been carried out in sealed thin-walled glass capillary tubes or in 0 sealed weighing bottles at 70 For the reaction, RBZAH + R'BZAK, where R = R', the product...

  7. Chip-based sequencing nucleic acids

    DOE Patents [OSTI]

    Beer, Neil Reginald

    2014-08-26T23:59:59.000Z

    A system for fast DNA sequencing by amplification of genetic material within microreactors, denaturing, demulsifying, and then sequencing the material, while retaining it in a PCR/sequencing zone by a magnetic field. One embodiment includes sequencing nucleic acids on a microchip that includes a microchannel flow channel in the microchip. The nucleic acids are isolated and hybridized to magnetic nanoparticles or to magnetic polystyrene-coated beads. Microreactor droplets are formed in the microchannel flow channel. The microreactor droplets containing the nucleic acids and the magnetic nanoparticles are retained in a magnetic trap in the microchannel flow channel and sequenced.

  8. aspartic acid racemization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rate of racemization for amino acids preserved in planktonic foraminifera climate change. Keywords: amino acid racemization, Quaternary geochronology, Arctic Ocean, planktonic...

  9. Catalytic Consequences of Acid Strength in the Conversion of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Consequences of Acid Strength in the Conversion of Methanol to Dimethyl Ether. Catalytic Consequences of Acid Strength in the Conversion of Methanol to Dimethyl Ether. Abstract:...

  10. acid bacteria revisited: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  11. acid bacteria elicit: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  12. acid bacteria affect: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  13. acid bacteria structure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  14. acid bacteria inducing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  15. acid bacteria purification: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Clark of amino acid in soil using radioactive isotopes, however many experiments...

  16. acid bacteria enhance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de 4 The Fate of Amino Acid in Soil Experiments: Bacteria, Roots and Fungi Melissa Campbell Environmental Sciences and Ecology Websites Summary: The Fate of Amino Acid in...

  17. acid conserved neutralizing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: itself against acidification and is used to monitor the effect of acid rain on watersheds. From 1993MASTERS REPORT ANALYSIS AND MODELING OF ACID...

  18. acid biosynthesis revealed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  19. acid biosynthesis inhibitors: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  20. abscisic acid biosynthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  1. acid neutralization capacity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: itself against acidification and is used to monitor the effect of acid rain on watersheds. From 1993MASTERS REPORT ANALYSIS AND MODELING OF ACID...

  2. acid neutralizing capacity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: itself against acidification and is used to monitor the effect of acid rain on watersheds. From 1993MASTERS REPORT ANALYSIS AND MODELING OF ACID...

  3. acid levels metabolic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  4. acid function biosynthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  5. acid biosynthesis leads: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  6. acid soil tolerance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Websites Summary: 1980; however, soils collected during the earlier phases of acid rain research have led to a growing Indications of Soil Recovery from Acidic...

  7. acid biosynthesis synthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  8. acid biosynthesis genes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: bioavailability of aluminum triggered by in- dustrialization and acid rain 20. The presence of organic acidsThe Metabolism of Aluminum Citrate and...

  9. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with covalently-bound hexafluoroisopropanol groups. Hydrogen-bond acidic functionalized carbon nanotubes (CNTs) with...

  10. Effects of Continuous Triiodothyronine Infusion on Citric Acid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Continuous Triiodothyronine Infusion on Citric Acid Cycle in the Normal Immature Swine Heart under Extracorporeal Effects of Continuous Triiodothyronine Infusion on Citric Acid...

  11. Copper isotope fractionation in acid mine drainage. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in acid mine drainage. Abstract: We surveyed the Cu isotopic composition of primary minerals and stream water affected by acid mine drainage in a mineralized watershed located in...

  12. AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results AVTA: 2010 Honda Civic HEV with Experimental Ultra Lead Acid Battery Testing Results The Vehicle...

  13. acid adenine dinucleotide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theoretical Determination of One-Electron Oxidation Potentials for Nucleic Acid Bases Brian T potentials for N-methyl substituted nucleic acid bases guanine, adenine, cytosine,...

  14. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Acid Initiation of Ammonia-Borane Dehydrogenation for Hydrogen Storage. Abstract: An abstract for this...

  15. Electrodeposition From Acidic Solutions of Nickel Bis(benzenedithiolat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From Acidic Solutions of Nickel Bis(benzenedithiolate) Produces a Hydrogen-Evolving Ni-S Film on Glassy Carbon Electrodeposition From Acidic Solutions of Nickel...

  16. Lewis Acid-Base Interactions between Polysulfides and Metal Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lewis Acid-Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries. Lewis Acid-Base Interactions between Polysulfides and Metal Organic...

  17. amino acid pattern: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  18. acid exhibits selective: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  19. amino acid selective: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  20. amino acid selection: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  1. amino acid mutations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  2. amino acid recognition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acid Sequence Analysis Pradipta Maji and Sankar K. Pal, Fellow, IEEE Abstract--In most pattern recognition algorithms, amino acids feature space. It is designed using an amino...

  3. amino acid insertion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their distribution in known structures with experimental data such as amino acid transfer free energy scales (water to membrane center and water Senes, Alessandro 2 Amino Acid...

  4. Selective Removal of Lanthanides from Natural Waters, Acidic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate. Selective Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate. Abstract: The...

  5. acid increases expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that are especially sensitive to increasing nutrient Gotelli, Nicholas J. 378 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  6. ascorbic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are stable thermodynamically and hydration free energies obtained Yu, Fangqun 78 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  7. acid isopropyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 192 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  8. acid vinyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 280 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  9. ascorbic acid phenolic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 229 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  10. acid inhibits production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Animals excrete three main nitrogen products, ammonia, urea and uric acid (Fig. 1), as well as some and amino acids. The term ammonia...

  11. acid monoethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 180 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  12. antioxidant ascorbic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 218 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  13. acid copolymeric hydrogels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 278 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  14. acid solutions part: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    m Popovych, Roman 71 Z .Comparative Biochemistry and Physiology Part B 128 2001 445 450 Purification and characterization of the fatty acid Chemistry Websites Summary: fatty acid...

  15. acid hydrolysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 213 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  16. acid fume system: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 147 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  17. acid synthase type: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 328 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  18. ascorbic acid induces: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ramsey Theory Continue with Nesetril-Rodl Reminder Prigozhin, Leonid 174 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  19. ascorbic acid fuel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 314 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  20. acid ester prodrugs: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 194 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  1. acid allyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 239 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  2. ascorbic acid determination: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 188 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  3. ascorbic acid influence: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Golnari, Golshan; Banerjee, Arindam; Zhang, Zhi-Li 2014-01-01 176 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  4. ascorbic acid sodium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 338 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  5. acid phenylethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 180 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  6. acrylic acid esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 242 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  7. acid dimethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 227 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  8. acid decarboxylase expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the expressions. Anna Sthl; Petra Sundstrm; Kristina Hk 2005-01-01 180 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  9. acid phosphatase 5a: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 193 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  10. acid based hydrogels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mix of multiple different monomers. These silicone are themselves a complex mix of water, boric acid, hyaluronic acid and other constituents including surfactants suitable surface...

  11. ascorbic acid tablets: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 179 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  12. ascorbic acid biosynthetic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 126 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  13. acid propyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 191 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  14. ascorbic acid biosynthesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 224 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  15. acid catalyzed cyclodimerization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 367 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  16. ascorbic acid acetylsalicylic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are stable thermodynamically and hydration free energies obtained Yu, Fangqun 83 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  17. acetoacetic acid esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 179 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  18. acid phenethyl ester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 178 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  19. acid synthase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    use Rippe, Karsten 53 Z .Comparative Biochemistry and Physiology Part B 128 2001 445 450 Purification and characterization of the fatty acid Chemistry Websites Summary: fatty acid...

  20. acid resin tulsion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 182 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...