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1

Giner Electrochemicals Inc | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation,GigaCrete Inc Jump to: navigation,Gillard HotGiner

2

Webinar: Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis—Spotlight on Giner and Proton  

Broader source: Energy.gov [DOE]

Video recording of the webinar, Hydrogen Production by Polymer Electrolyte Membrane (PEM) Electrolysis—Spotlight on Giner and Proton, originally presented on May 23, 2011.

3

Premio Nacional de Sociologa y Presidente del Institut d'Estudis Catalans, Salvador Giner aborda el futuro del capitalismo  

E-Print Network [OSTI]

Premio Nacional de Sociología y Presidente del Institut d'Estudis Catalans, Salvador Giner aborda de Chicago (EEUU) y catedrático de la Universidad de Barcelona, Salvador Giner será el encargado de, Manuel Atienza y abordará El futur del capitalisme: teories i realitats. Salvador Giner ha sido profesor

Escolano, Francisco

4

Electrochemical hydrogen Storage Systems  

SciTech Connect (OSTI)

As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

Dr. Digby Macdonald

2010-08-09T23:59:59.000Z

5

System and method for networking electrochemical devices  

DOE Patents [OSTI]

An improved electrochemically active system and method including a plurality of electrochemical devices, such as fuel cells and fluid separation devices, in which the anode and cathode process-fluid flow chambers are connected in fluid-flow arrangements so that the operating parameters of each of said plurality of electrochemical devices which are dependent upon process-fluid parameters may be individually controlled to provide improved operating efficiency. The improvements in operation include improved power efficiency and improved fuel utilization in fuel cell power generating systems and reduced power consumption in fluid separation devices and the like through interstage process fluid parameter control for series networked electrochemical devices. The improved networking method includes recycling of various process flows to enhance the overall control scheme.

Williams, Mark C. (Morgantown, WV); Wimer, John G. (Morgantown, WV); Archer, David H. (Pittsburgh, PA)

1995-01-01T23:59:59.000Z

6

Sheet electrode for electrochemical systems  

DOE Patents [OSTI]

An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

Tsien, Hsue C. (Chatham Township, Morris County, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Grimes, Patrick G. (Westfield, NJ); Bellows, Richard J. (Westfield, NJ)

1983-04-12T23:59:59.000Z

7

Lithium based electrochemical cell systems having a degassing agent  

DOE Patents [OSTI]

A lithium based electrochemical cell system includes a positive electrode; a negative electrode; an electrolyte; and a degassing agent.

Hyung, Yoo-Eup (Naperville, IL); Vissers, Donald R. (Naperville, IL); Amine, Khalil (Downers Grove, IL)

2012-05-01T23:59:59.000Z

8

Gas permeable electrode for electrochemical system  

DOE Patents [OSTI]

An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

Ludwig, Frank A. (Rancho Palos Verdes, CA); Townsend, Carl W. (Los Angeles, CA)

1989-01-01T23:59:59.000Z

9

Gas permeable electrode for electrochemical system  

DOE Patents [OSTI]

An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

Ludwig, F.A.; Townsend, C.W.

1989-09-12T23:59:59.000Z

10

Electrochemical  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sub-10 nm features. However, the relationship between the ESM contrast and local electrochemical activity remains largely unexplored. Here, we analyze the image for-...

11

Measuring Physical Properties of Polymer Electrolyte Membranes  

Broader source: Energy.gov [DOE]

Presented by Cortney Mittelsteadt of Giner Electrochemical Systems, LLC, at the DOE High Temperature Membrane Working Group held September 14, 2006.

12

Diffuse-Charge Dynamics in Electrochemical Systems  

E-Print Network [OSTI]

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem consists of a symmetric binary electrolyte between parallel-plate, blocking electrodes which suddenly apply a voltage. Compact Stern layers on the electrodes are also taken into account. The Nernst-Planck-Poisson equations are first linearized and solved by Laplace transforms for small voltages, and numerical solutions are obtained for large voltages. The ``weakly nonlinear'' limit of thin double layers is then analyzed by matched asymptotic expansions in the small parameter $\\epsilon = \\lambda_D/L$, where $\\lambda_D$ is the screening length and $L$ the electrode separation. At leading order, the system initially behaves like an RC circuit with a response time of $\\lambda_D L / D$ (not $\\lambda_D^2/D$), where $D$ is the ionic diffusivity, but nonlinearity violates this common picture and introduce multiple time scales. The charging process slows down, and neutral-salt adsorption by the diffuse part of the double layer couples to bulk diffusion at the time scale, $L^2/D$. In the ``strongly nonlinear'' regime (controlled by a dimensionless parameter resembling the Dukhin number), this effect produces bulk concentration gradients, and, at very large voltages, transient space charge. The article concludes with an overview of more general situations involving surface conduction, multi-component electrolytes, and Faradaic processes.

Martin Z. Bazant; Katsuyo Thornton; Armand Ajdari

2004-01-08T23:59:59.000Z

13

Electrochemical Double Layered Capacitor Development and Implementation System  

E-Print Network [OSTI]

Electrochemical Double Layered Capacitors (EDLC's) are becoming a more popular topic of research for hybrid power systems, especially vehicles. They are known for their high power density, high cycle life, low internal resistance, and wider...

Strunk, Gavin

2014-08-31T23:59:59.000Z

14

Separator-spacer for electrochemical systems  

DOE Patents [OSTI]

An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Bellows, Richard J. (Westfield, NJ)

1983-08-02T23:59:59.000Z

15

Systems, methods and computer-readable media for modeling cell performance fade of rechargeable electrochemical devices  

DOE Patents [OSTI]

A system includes an electrochemical cell, monitoring hardware, and a computing system. The monitoring hardware periodically samples performance characteristics of the electrochemical cell. The computing system determines cell information from the performance characteristics of the electrochemical cell. The computing system also develops a mechanistic level model of the electrochemical cell to determine performance fade characteristics of the electrochemical cell and analyzing the mechanistic level model to estimate performance fade characteristics over aging of a similar electrochemical cell. The mechanistic level model uses first constant-current pulses applied to the electrochemical cell at a first aging period and at three or more current values bracketing a first exchange current density. The mechanistic level model also is based on second constant-current pulses applied to the electrochemical cell at a second aging period and at three or more current values bracketing the second exchange current density.

Gering, Kevin L

2013-08-27T23:59:59.000Z

16

A biofilm microreactor system for simultaneous electrochemical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on polarized gold electrodes. For an example application of this system, we grew Geobacter sulfurreducens biofilms. NMR was used to investigate growth media flow velocities,...

17

Electrochemical system including lamella settler crystallizer  

DOE Patents [OSTI]

A crystallizer which incorporates a lamella settler and which is particularly applicable for use in batteries and power cells for electric vehicles or stationary applications. The lamella settler can be utilized for coarse particle separation or for agglomeration, and is particularly applicable to aluminum-air batteries or power cells for solving the hydrargillite (aluminum-hydroxide) removal problems from such batteries. This invention provides the advantages of very low energy consumption, turbulence, shear, cost and maintenance. Thus, due to the low shear and low turbulence of this invention, it is particularly effective in the control of aluminum hydroxide particle size distribution in the various sections of an aluminum-air system, as will as in other elecrochemical systems requiring separation for phases of different densities.

Maimoni, Arturo (Orinda, CA)

1988-01-01T23:59:59.000Z

18

Current-potential characteristics of electrochemical systems  

SciTech Connect (OSTI)

This dissertation contains investigations in three distinct areas. Chapters 1 and 2 provide an analysis of the effects of electromagnetic phenomena during the initial stages of cell discharge. Chapter 1 includes the solution to Maxwell`s equations for the penetration of the axial component of an electric field into an infinitely long cylindrical conductor. Chapter 2 contains the analysis of the conductor included in a radial circuit. Chapter 3 provides a complete description of the equations that describe the growth of an oxide film. A finite difference program was written to solve the equations. The system investigated is the iron/iron oxide in a basic, aqueous solution. Chapters 4 and 5 include the experimental attempts for replacing formaldehyde with an innocuous reducing agent for electroless deposition. In chapter 4, current-versus-voltage curves are provided for a sodium thiosulfate bath in the presence of a copper disk electrode. Also provided are the cathodic polarization curves of a copper/EDTA bath in the presence of a copper electrode. Chapter 5 contains the experimental results of work done with sodium hypophosphite as a reducing agent. Mixed-potential-versus-time curves for solutions containing various combinations of copper sulfate, nickel chloride, and hypophosphite in the presence of a palladium disk electrode provide an indication of the reducing power of the solutions.

Battaglia, V.S.

1993-07-01T23:59:59.000Z

19

Systems, methods and computer readable media for estimating capacity loss in rechargeable electrochemical cells  

DOE Patents [OSTI]

A system includes an electrochemical cell, monitoring hardware, and a computing system. The monitoring hardware periodically samples charge characteristics of the electrochemical cell. The computing system periodically determines cell information from the charge characteristics of the electrochemical cell. The computing system also periodically adds a first degradation characteristic from the cell information to a first sigmoid expression, periodically adds a second degradation characteristic from the cell information to a second sigmoid expression and combines the first sigmoid expression and the second sigmoid expression to develop or augment a multiple sigmoid model (MSM) of the electrochemical cell. The MSM may be used to estimate a capacity loss of the electrochemical cell at a desired point in time and analyze other characteristics of the electrochemical cell. The first and second degradation characteristics may be loss of active host sites and loss of free lithium for Li-ion cells.

Gering, Kevin L.

2013-06-18T23:59:59.000Z

20

Electrochemical and optical studies of model photosynthetic systems  

SciTech Connect (OSTI)

The objective of this research is to obtain a better understanding of the relationship between the structural organization of photosynthetic pigments and their spectroscopic and electrochemical properties. Defined model systems were studied first. These included the least ordered (solutions) through the most highly ordered (Langmuir-Blodgett (LB) monolayers and self-assembled monolayers) systems containing BChl, BPheo, and UQ. Molecules other than the photosynthetic pigments and quinones were also examined, including chromophores (i.e. surface active cyanine dyes and phtahlocyanines) an redox active compounds (methyl viologen (MV) and surfactant ferrocenes), in order to develop the techniques needed to study the photosynthetic components. Because the chlorophylls are photosensitive and labile, it was easier first to develop procedures using stable species. Three different techniques were used to characterize these model systems. These included electrochemical techniques for determining the standard oxidation and reduction potentials of the photosynthetic components as well as methods for determining the heterogeneous electron transfer rate constants for BChl and BPheo at metal electrodes (Pt and Au). Resonance Raman (RR) and surface enhanced resonance Raman (SERR) spectroscopy were used to determine the spectra of the photosynthetic pigments and model compounds. SERRS was also used to study several types of photosynthetic preparations.

Not Available

1992-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Systems, methods and computer-readable media to model kinetic performance of rechargeable electrochemical devices  

DOE Patents [OSTI]

A system includes an electrochemical cell, monitoring hardware, and a computing system. The monitoring hardware samples performance characteristics of the electrochemical cell. The computing system determines cell information from the performance characteristics. The computing system also analyzes the cell information of the electrochemical cell with a Butler-Volmer (BV) expression modified to determine exchange current density of the electrochemical cell by including kinetic performance information related to pulse-time dependence, electrode surface availability, or a combination thereof. A set of sigmoid-based expressions may be included with the modified-BV expression to determine kinetic performance as a function of pulse time. The determined exchange current density may be used with the modified-BV expression, with or without the sigmoid expressions, to analyze other characteristics of the electrochemical cell. Model parameters can be defined in terms of cell aging, making the overall kinetics model amenable to predictive estimates of cell kinetic performance along the aging timeline.

Gering, Kevin L.

2013-01-01T23:59:59.000Z

22

MSE 498 Special Topics -Materials in Electrochemical Systems Instructor Shen Dillon  

E-Print Network [OSTI]

Energy storage systems(batteries, super capacitors, fuel cells) Electrodeposition: Energy storage (traditional batteries, super capacitors, Li-ion) Apr 15: Impedance storage and conversion in batteries, electrochemical capacitors, fuel cells, photocatalysts, and related

Weaver, John H.

23

Monolithic three-dimensional electrochemical energy storage system on aerogel or nanotube scaffold  

DOE Patents [OSTI]

A monolithic three-dimensional electrochemical energy storage system is provided on an aerogel or nanotube scaffold. An anode, separator, cathode, and cathodic current collector are deposited on the aerogel or nanotube scaffold.

Farmer, Joseph C; Stadermann, Michael

2013-11-12T23:59:59.000Z

24

Monolithic three-dimensional electrochemical energy storage system on aerogel or nanotube scaffold  

DOE Patents [OSTI]

A monolithic three-dimensional electrochemical energy storage system is provided on an aerogel or nanotube scaffold. An anode, separator, cathode, and cathodic current collector are deposited on the aerogel or nanotube scaffold.

Farmer, Joseph Collin; Stadermann, Michael

2014-07-15T23:59:59.000Z

25

Integrated Microfluidics/Electrochemical Sensor System for Field-Monitoring of Toxic Metals  

SciTech Connect (OSTI)

Discusses a miniaturized analytical system based on a microfluidics/electrochemical detection scheme. Individual modules, such as microfabricated piezoelectrically actuated pumps, a micro-membrane separator and a microelectrochemical cell will be integrated onto a portable platform.

Lin, Yuehe; Matson, Dean W.; Bennett, Wendy D.; Thrall, K D.; Timchalk, Chuck; W. Ehrfeld

2000-01-01T23:59:59.000Z

26

Panel 3, Giner Overview  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CFB. * Equipment & Labor @ Cost Share (in-kind) * () & Ideal Location site * Wind Solar Farm Utility Co. Electrolysis Manufacturer + Engineering Construction Firm Auto...

27

Giner, Inc./GES  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject: Guidance forGeospatialSession) |GettingLEARNING

28

Panel 3, Giner Overview  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F SSalesOE0000652 Srivastava,Pacific1of PageHYDROGEN H 25 th , 2014

29

Electrochemical Techniques  

SciTech Connect (OSTI)

Sensitive and selective detection techniques are of crucial importance for capillary electrophoresis (CE), microfluidic chips, and other microfluidic systems. Electrochemical detectors have attracted considerable interest for microfluidic systems with features that include high sensitivity, inherent miniaturization of both the detection and control instrumentation, low cost and power demands, and high compatibility with microfabrication technology. The commonly used electrochemical detectors can be classified into three general modes: conductimetry, potentiometry, and amperometry.

Chen, Gang; Lin, Yuehe

2008-07-20T23:59:59.000Z

30

Journal of The Electrochemical Society, 161 (8) E3149-E3157 (2014) E3149 JES FOCUS ISSUE ON MATHEMATICAL MODELING OF ELECTROCHEMICAL SYSTEMS AT MULTIPLE SCALES  

E-Print Network [OSTI]

, Massachusetts 02139, USA Improving the efficiency and utilization of battery systems can increase the viability on fossil fuels. Lithium-ion batteries are a popular choice as an energy storage medium for high demand ON MATHEMATICAL MODELING OF ELECTROCHEMICAL SYSTEMS AT MULTIPLE SCALES Efficient Simulation and Reformulation

Subramanian, Venkat

31

A biofilm microreactor system for simultaneous electrochemical and nuclear magnetic resonance techniques  

SciTech Connect (OSTI)

In order to fully understand electrochemically active biofilms and the limitations to their scale-up in industrial biofilm reactors, a complete picture of the microenvironments inside the biofilm is needed. Nuclear magnetic resonance (NMR) techniques are ideally suited for the study of biofilms and for probing their microenvironments because these techniques allow for non-invasive interrogation and in situ monitoring with high resolution. By combining NMR with simultaneous electrochemical techniques, it is possible to sustain and study live electrochemically active biofilms. Here, we introduce a novel biofilm microreactor system that allows for simultaneous electrochemical and NMR techniques (EC-NMR) at the microscale. Microreactors were designed with custom radiofrequency resonator coils, which allowed for NMR measurements of biofilms growing on polarized gold electrodes. For an example application of this system, we grew Geobacter sulfurreducens biofilms. NMR was used to investigate growth media flow velocities, which were compared to simulated laminar flow, and electron donor concentrations inside the biofilms. We use Monte Carlo error analysis to estimate standard deviations of the electron donor concentration measurements within the biofilm. The EC-NMR biofilm microreactor system can ultimately be used to correlate extracellular electron transfer rates with metabolic reactions and explore extracellular electron transfer mechanisms.

Renslow, Ryan S.; Babauta, Jerome T.; Majors, Paul D.; Mehta, Hardeep S.; Ewing, R. James; Ewing, Thomas; Mueller, Karl T.; Beyenal, Haluk

2014-01-30T23:59:59.000Z

32

Novel electrochemical system intended for 1.5 V nonmetallic hermetically sealed secondary cell  

SciTech Connect (OSTI)

A novel reversible system based on graphite and anthraquinone electrodes and intended for the development of a nonmetallic ecologically clean secondary cell is proposed. The principal problem associated with combining the two electrodes in a unified electrochemical system involves the search for an electrolyte which would be suitable for both electrodes. Optimum and limiting pH intervals as well as the influence exerted by the anion type on the electrode efficiency are considered. The use of combined electrolytes on the basis of HBF{sub 4} with tetrafluoroborate additives is recommended.

Barsukov, V.Z. [Institute of General and Inorganic Chemistry, Kiev (Ukraine); Barsukov, I.V.; Motronyuk, T.I. [Kiev Polytechnical Institute (Ukraine); Beck, F. [Univ. of Duisburg, Lotharstrabe (Germany)

1995-04-01T23:59:59.000Z

33

A Novel System for Carbon Dioxide Capture Utilizing Electrochemical Membrane Technology  

SciTech Connect (OSTI)

FuelCell Energy, Inc. (FCE), in collaboration with Pacific Northwest National Laboratory (PNNL) and URS Corporation, is developing a novel Combined Electric Power and Carbon-Dioxide Separation (CEPACS) system, under a contract from the U.S. Department of Energy (DE-FE0007634), to efficiently and cost effectively separate carbon dioxide from the emissions of existing coal fired power plants. The CEPACS system is based on FCE’s electrochemical membrane (ECM) technology utilizing the Company’s internal reforming carbonate fuel cell products carrying the trade name of Direct FuelCell® (DFC®). The unique chemistry of carbonate fuel cells offers an innovative approach for separation of CO2 from existing fossil-fuel power plant exhaust streams (flue gases). The ECM-based CEPACS system has the potential to become a transformational CO2-separation technology by working as two devices in one: it separates the CO2 from the exhaust of other plants such as an existing coal-fired plant and simultaneously produces clean and environmentally benign (green) electric power at high efficiency using a supplementary fuel. The overall objective of this project is to successfully demonstrate the ability of FCE’s electrochemical membrane-based CEPACS system technology to separate ? 90% of the CO2 from a simulated Pulverized Coal (PC) power plant flue-gas stream and to compress the captured CO2 to a state that can be easily transported for sequestration or beneficial use. Also, a key project objective is to show, through a Technical and Economic Feasibility Study and bench scale testing (11.7 m2 area ECM), that the electrochemical membrane-based CEPACS system is an economical alternative for CO2 capture in PC power plants, and that it meets DOE objectives for the incremental cost of electricity (COE) for post-combustion CO2 capture.

Ghezel-Ayagh, Hossein; Jolly, Stephen; Patel, Dilip; Hunt, Jennifer; Steen, William A.; Richardson, Carl F.; Marina, Olga A.

2013-06-03T23:59:59.000Z

34

Compact electrochemical sensor system and method for field testing for metals in saliva or other fluids  

DOE Patents [OSTI]

Microanalytical systems based on a microfluidics/electrochemical detection scheme are described. Individual modules, such as microfabricated piezoelectrically actuated pumps and a microelectrochemical cell were integrated onto portable platforms. This allowed rapid change-out and repair of individual components by incorporating "plug and play" concepts now standard in PC's. Different integration schemes were used for construction of the microanalytical systems based on microfluidics/electrochemical detection. In one scheme, all individual modules were integrated in the surface of the standard microfluidic platform based on a plug-and-play design. Microelectrochemical flow cell which integrated three electrodes based on a wall-jet design was fabricated on polymer substrate. The microelectrochemical flow cell was then plugged directly into the microfluidic platform. Another integration scheme was based on a multilayer lamination method utilizing stacking modules with different functionality to achieve a compact microanalytical device. Application of the microanalytical system for detection of lead in, for example, river water and saliva samples using stripping voltammetry is described.

Lin, Yuehe; Bennett, Wendy D.; Timchalk, Charles; Thrall, Karla D.

2004-03-02T23:59:59.000Z

35

Investigation of Synergy Between Electrochemical Capacitors, Flywheels, and Batteries in Hybrid Energy Storage for PV Systems  

SciTech Connect (OSTI)

This report describes the results of a study that investigated the synergy between electrochemical capacitors (ECs) and flywheels, in combination with each other and with batteries, as energy storage subsystems in photovoltaic (PV) systems. EC and flywheel technologies are described and the potential advantages and disadvantages of each in PV energy storage subsystems are discussed. Seven applications for PV energy storage subsystems are described along with the potential market for each of these applications. A spreadsheet model, which used the net present value method, was used to analyze and compare the costs over time of various system configurations based on flywheel models. It appears that a synergistic relationship exists between ECS and flywheels. Further investigation is recommended to quantify the performance and economic tradeoffs of this synergy and its effect on overall system costs.

Miller, John; Sibley, Lewis, B.; Wohlgemuth, John

1999-06-01T23:59:59.000Z

36

Portable system and method combining chromatography and array of electrochemical sensors  

DOE Patents [OSTI]

A portable system for analyzing a fluid sample includes a small, portable, low-pressure and low-power chromatographic analyzer and a chemical parameter spectrometry monitor including an array of sensors for detecting, identifying and measuring the concentrations of a variety of components in the eluent from the chromatographic analyzer. The monitor includes one or more operating condition controllers which may be used to change one or more of the operating conditions during exposure of the sensors to the eluent from the chromatography analyzer to form a response pattern which is then compared with a library of previously established patterns. Gas and liquid chromatographic embodiments are disclosed. In the gas embodiment, the operating condition controllers include heated filaments which may convert electrochemically inactive components to electrochemically active products. In the liquid chromatography embodiment, low-power, liquid-phase equivalents of heated filaments are used with appropriate sensors. The library response patterns may be divided into subsets and the formed pattern may be assigned for comparison only with the patterns of a particular subset.

Zaromb, Solomon (Hinsdale, IL); Stetter, Joseph R. (Naperville, IL)

1989-01-01T23:59:59.000Z

37

Performance Optimization of Battery-Super Capacitor Hybrid System Electrochemical capacitors (ultracapacitors) offer high power density when compared to battery  

E-Print Network [OSTI]

Performance Optimization of Battery-Super Capacitor Hybrid System Electrochemical capacitors of super capacitors with batteries and fuel cells under specific loads. Despite the fact that Lithium density compared to conventional capacitors. In the late nineties they have gained considerable attention

Popov, Branko N.

38

Creating systems that effectively convert energy, such as efficient solar cells and electrochemical batteries, has been a  

E-Print Network [OSTI]

SEMTE abstract Creating systems that effectively convert energy, such as efficient solar cells stimuli, the solar energy from sunlight, and the mechanical motion is commonplace, indeed fundamental and electrochemical batteries, has been a longstanding scientific pursuit, especially given the global energy

Reisslein, Martin

39

Combined process for 2,4-Dichlorophenoxyacetic acid treatment Coupling of an electrochemical system with a biological treatment.  

E-Print Network [OSTI]

system with a biological treatment. Jean-Marie Fontmorina,b *, Florence Fourcadea,b Florence Genestec-made electrochemical flow cell was used for the pre-treatment and a biological treatment was then carried out using activated sludge supplied by a local wastewater treatment plant. 2,4-D was used as a target compound

Paris-Sud XI, Université de

40

Microstructural manipulation and architecture design of carbon-based electrochemical systems  

E-Print Network [OSTI]

Carbon materials are important in electrochemistry. The often cited advantages of carbonaceous materials for electrochemical applications include wide potential working windows, tunable electrocatalytic activity for a ...

Mao, Xianwen

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Theoretical approach for optical response in electrochemical systems: Application to electrode potential dependence of surface-enhanced Raman scattering  

SciTech Connect (OSTI)

We propose a theoretical approach for optical response in electrochemical systems. The fundamental equation to be solved is based on a time-dependent density functional theory in real-time and real-space in combination with its finite temperature formula treating an electrode potential. Solvation effects are evaluated by a dielectric continuum theory. The approach allows us to treat optical response in electrochemical systems at the atomistic level of theory. We have applied the method to surface-enhanced Raman scattering (SERS) of 4-mercaptopyridine on an Ag electrode surface. It is shown that the SERS intensity has a peak as a function of the electrode potential. Furthermore, the real-space computational approach facilitates visualization of variation of the SERS intensity depending on an electrode potential.

Iida, Kenji; Noda, Masashi; Nobusada, Katsuyuki, E-mail: nobusada@ims.ac.jp [Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki 444-8585 (Japan)

2014-09-28T23:59:59.000Z

42

A mathematical model of the current-potential characteristics for the bromine/bromide ion electrochemical system  

E-Print Network [OSTI]

toward the study of the Hr /Br electrochemical system. First, the Z model was shown to be a good tool for electrode kinetic analysis. The detailed expressions for current density, developed for two electrode kinetic mechanisms commonly proposed... Kinetic Analysis Using Model. 89 108 116 Application of Model to Kinetic Mechanism Discrimination. 118 Reproduction of Experimental Current Density- Overpotential Curves with Model. Theoretical Study of Current Dens(ty-Overpotential Behavior Disk...

Lorimer, Susan Elaine

1982-01-01T23:59:59.000Z

43

Alternating-polarity operation for complete regeneration of electrochemical deionization system  

DOE Patents [OSTI]

An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. By polarizing the cells, ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes. As the electrodes of each cell of the battery are saturated with the removed ions, the battery is regenerated electrically at a reversed polarity from that during the deionization step of the cycle, thus significantly minimizing secondary wastes.

Tran, Tri D. (Livermore, CA); Lenz, David J. (Livermore, CA)

2002-01-01T23:59:59.000Z

44

In operando observation system for electrochemical reaction by soft X-ray absorption spectroscopy with potential modulation method  

SciTech Connect (OSTI)

In order to investigate local structures of electrolytes in electrochemical reactions under the same scan rate as a typical value 100 mV/s in cyclic voltammetry (CV), we have developed an in operando observation system for electrochemical reactions by soft X-ray absorption spectroscopy (XAS) with a potential modulation method. XAS spectra of electrolytes are measured by using a transmission-type liquid flow cell with built-in electrodes. The electrode potential is swept with a scan rate of 100 mV/s at a fixed photon energy, and soft X-ray absorption coefficients at different potentials are measured at the same time. By repeating the potential modulation at each fixed photon energy, it is possible to measure XAS of electrochemical reaction at the same scan rate as in CV. We have demonstrated successful measurement of the Fe L-edge XAS spectra of aqueous iron sulfate solutions and of the change in valence of Fe ions at different potentials in the Fe redox reaction. The mechanism of these Fe redox processes is discussed by correlating the XAS results with those at different scan rates.

Nagasaka, Masanari, E-mail: nagasaka@ims.ac.jp; Kosugi, Nobuhiro [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan); The Graduate University for Advanced Studies, Myodaiji, Okazaki 444-8585 (Japan); Yuzawa, Hayato; Horigome, Toshio [Institute for Molecular Science, Myodaiji, Okazaki 444-8585 (Japan)

2014-10-15T23:59:59.000Z

45

Porous electrodes and prototypes of secondary cells based on a novel electrochemical system graphite-HBF{sub 4}-anthraquinone  

SciTech Connect (OSTI)

Porous electrodes and experimental prototypes of rechargeable batteries based on a novel electrochemical system graphite-HBF{sub 4} + tetrafluoroborate additives-anthraquinone are developed. Intercalation of anions in the graphite electrode is studied in detail and the intercalation potential is determined (E{sub i} {approximately} 1.55 V vs. Ag-AgCl). Side reactions proceeding concurrently with primary current-generating processes at the electrodes are described. Feasibility of hermetically sealing a battery based on the new system due to anthrahydroquinone`s ability to reduce oxygen that evolves during charging is demonstrated.

Barsukov, V.Z. [Institute of General and Inorganic Chemistry, Kiev (Ukraine); Barsukov, I.V.; Motronyuk, T.I. [Kiev Polytechnical Institute (Ukraine); Beck, F. [Univ. of Duisburg (Germany)

1995-04-01T23:59:59.000Z

46

Electrochemical and optical studies of model photosynthetic systems. Final progress report, July 1, 1984--August 31, 1989  

SciTech Connect (OSTI)

The objective of this research is to obtain a better understanding of the relationship between the structural organization of photosynthetic pigments and their spectroscopic and electrochemical properties. Defined model systems were studied first. These included the least ordered (solutions) through the most highly ordered (Langmuir-Blodgett (LB) monolayers and self-assembled monolayers) systems containing BChl, BPheo, and UQ. Molecules other than the photosynthetic pigments and quinones were also examined, including chromophores (i.e. surface active cyanine dyes and phtahlocyanines) an redox active compounds (methyl viologen (MV) and surfactant ferrocenes), in order to develop the techniques needed to study the photosynthetic components. Because the chlorophylls are photosensitive and labile, it was easier first to develop procedures using stable species. Three different techniques were used to characterize these model systems. These included electrochemical techniques for determining the standard oxidation and reduction potentials of the photosynthetic components as well as methods for determining the heterogeneous electron transfer rate constants for BChl and BPheo at metal electrodes (Pt and Au). Resonance Raman (RR) and surface enhanced resonance Raman (SERR) spectroscopy were used to determine the spectra of the photosynthetic pigments and model compounds. SERRS was also used to study several types of photosynthetic preparations.

Not Available

1992-01-15T23:59:59.000Z

47

Electrochemical Characterization Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Electrochemical Characterization Laboratory at the Energy Systems Integration Facility. The research focus at the Electrochemical Characterization Laboratory at NREL's Energy Systems Integration Facility (ESIF) is evaluating the electrochemical properties of novel materials synthesized by various techniques and understanding and delineating the reaction mechanisms to provide practical solutions to PEMFCs commercialization issues of cost, performance and durability. It is also involved in the development of new tools and techniques for electrochemical characterization. The laboratory concentrates on the development and characterization of new materials for PEMFCs such as electrocatalysts, catalyst supports in terms of electrochemical activity, electrochemical surface area and corrosion/durability. The impact of impurities and/or contaminants on the catalyst activity is also under study. Experiments that can be performed include: (1) Determination and benchmarking of novel electrocatalyst activity; (2) Determination of electrochemical surface area; (3) Determination of electrocatalyst and support corrosion resistance and durability; (4) Synthesis and characterization of novel electrocatalyst; (5) Determination of fundamental electrochemical parameters; and (6) Estimation of electrocatalyst utilization.

Not Available

2011-10-01T23:59:59.000Z

48

Electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm[sup 3]; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6[times]10[sup 4] cm[sup 2]/g of Ni. 8 figures.

Redey, L.I.; Vissers, D.R.; Prakash, J.

1994-02-01T23:59:59.000Z

49

Supported liquid membrane electrochemical separators  

DOE Patents [OSTI]

Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

1986-01-01T23:59:59.000Z

50

Alternating-polarity operation for complete regeneration of electrochemical deionization system  

DOE Patents [OSTI]

An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. In other words, after each regeneration step operated at a given polarity in a deionization-regeneration cycle, the polarity of the deionization step in the next cycle is maintained. In one embodiment, two end electrodes are arranged one at each end of the battery, adjacent to end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity, preferably a sheet formed of carbon aerogel composite. The batter further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes. As the electrolyte enters the battery of ells, t flows through a continuous open serpentine channel defined by the electrodes, substantially parallel to the surfaces of the electrodes. By polarizing the cells, ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes. As the electrodes of each cell of the battery are saturated with the removed ions, the battery is regenerated electrically at a reversed polarity from that during the deionization step of the cycle, thus significantly minimizing secondary wastes.

Tran, Tri D. (Livermore, CA); Lenz, David J. (Livermore, CA)

2006-11-21T23:59:59.000Z

51

Electrochemical construction  

DOE Patents [OSTI]

An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

Einstein, Harry (Springfield, NJ); Grimes, Patrick G. (Westfield, NJ)

1983-08-23T23:59:59.000Z

52

Electrochemical device  

DOE Patents [OSTI]

A tunnel protected electrochemical device features channels fluidically communicating between manifold, tunnels and cells. The channels are designed to provide the most efficient use of auxiliary power. The channels have a greater hydraulic pressure drop and electrical resistance than the manifold. This will provide a design with the optimum auxiliary energy requirements.

Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ); Bellows, Richard J. (Westfield, NJ)

1988-01-12T23:59:59.000Z

53

160 IEEE TRANSACTIONS ON BIOMEDICAL CIRCUITS AND SYSTEMS, VOL. 3, NO. 3, JUNE 2009 Amperometric Electrochemical Microsystem  

E-Print Network [OSTI]

Electrochemical Microsystem for a Miniaturized Protein Biosensor Array Chao Yang, Yue Huang, Student Member, IEEE, Brian L. Hassler, R. Mark Worden, and Andrew J. Mason, Senior Member, IEEE AbstractA. A prototype electrochemical sensor platform, including an onchip potentiostat and miniaturized biosensor array

Mason, Andrew

54

A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)  

SciTech Connect (OSTI)

This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

Anil Virkar

2008-03-31T23:59:59.000Z

55

Electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell is described having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a [beta] alumina electrolyte and NaAlCl[sub 4] or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose. 6 figs.

Redey, L.I.; Vissers, D.R.; Prakash, J.

1994-08-23T23:59:59.000Z

56

Electrochemical cell  

DOE Patents [OSTI]

An improved secondary electrochemical cell is disclosed having a negative electrode of lithium aluminum, a positive electrode of iron sulfide, a molten electrolyte of lithium chloride and potassium chloride, and the combination that the fully charged theoretical capacity of the negative electrode is in the range of 0.5-1.0 that of the positive electrode. The cell thus is negative electrode limiting during discharge cycling. Preferably, the negative electrode contains therein, in the approximate range of 1-10 volume % of the electrode, an additive from the materials of graphitized carbon, aluminum-iron alloy, and/or magnesium oxide.

Kaun, Thomas D. (New Lenox, IL)

1984-01-01T23:59:59.000Z

57

PEM fuel cell stack performance using dilute hydrogen mixture. Implications on electrochemical engine system performance and design  

SciTech Connect (OSTI)

Onboard fuel processing to generate a hydrogen-rich fuel for PEM fuel cells is being considered as an alternative to stored hydrogen fuel for transportation applications. If successful, this approach, contrasted to operating with onboard hydrogen, utilizes the existing fuels infrastructure and provides required vehicle range. One attractive, commercial liquid fuels option is steam reforming of methanol. However, expanding the liquid methanol infrastructure will take both time and capital. Consequently technology is also being developed to utilize existing transportation fuels, such as gasoline or diesel, to power PEM fuel cell systems. Steam reforming of methanol generates a mixture with a dry gas composition of 75% hydrogen and 25% carbon dioxide. Steam reforming, autothermal reforming, and partial oxidation reforming of C{sub 2} and larger hydrocarbons produces a mixture with a more dilute hydrogen concentration (65%-40%) along with carbon dioxide ({approx}20%) and nitrogen ({approx}10%-40%). Performance of PEM fuel cell stacks on these dilute hydrogen mixtures will affect the overall electrochemical engine system design as well as the overall efficiency. The Los Alamos Fuel Cell Stack Test facility was used to access the performance of a PEM Fuel cell stack over the range of gas compositions chosen to replicate anode feeds from various fuel processing options for hydrocarbon and alcohol fuels. The focus of the experiments was on the anode performance with dilute hydrogen mixtures with carbon dioxide and nitrogen diluents. Performance with other anode feed contaminants, such as carbon monoxide, are not reported here.

Inbody, M.A.; Vanderborgh, N.E.; Hedstrom, J.C.; Tafoya, J.I. [Los Alamos National Lab., NM (United States)

1996-12-31T23:59:59.000Z

58

A Mathematical Model for a Lithium-Ion Battery/Electrochemical Capacitor Hybrid System  

E-Print Network [OSTI]

they are frequently encountered in portable power systems such as machine guns, implantable cardioverter

Popov, Branko N.

59

Electrochemical supercapacitors  

DOE Patents [OSTI]

A new class of electrochemical capacitors provides in its charged state a positive electrode including an active material of a p-doped material and a negative electrode including an active material of an n-doped conducting polymer, where the p-doped and n-doped materials are separated by an electrolyte. In a preferred embodiment, the positive and negative electrode active materials are selected from conducting polymers consisting of polythiophene, polymers having an aryl group attached in the 3-position, polymers having aryl and alkyl groups independently attached in the 3- and 4-positions, and polymers synthesized from bridged dimers having polythiophene as the backbone. A preferred electrolyte is a tetraalykyl ammonium salt, such as tetramethylammonium trifluoromethane sulphonate (TMATFMS), that provides small ions that are mobile through the active material, is soluble in acetonitrile, and can be used in a variety of capacitor configurations.

Rudge, Andrew J. (Los Alamos, NM); Ferraris, John P. (Dallas, TX); Gottesfeld, Shimshon (Los Alamos, NM)

1996-01-01T23:59:59.000Z

60

Anode-cathode power distribution systems and methods of using the same for electrochemical reduction  

DOE Patents [OSTI]

Power distribution systems are useable in electrolytic reduction systems and include several cathode and anode assembly electrical contacts that permit flexible modular assembly numbers and placement in standardized connection configurations. Electrical contacts may be arranged at any position where assembly contact is desired. Electrical power may be provided via power cables attached to seating assemblies of the electrical contacts. Cathode and anode assembly electrical contacts may provide electrical power at any desired levels. Pairs of anode and cathode assembly electrical contacts may provide equal and opposite electrical power; different cathode assembly electrical contacts may provide different levels of electrical power to a same or different modular cathode assembly. Electrical systems may be used with an electrolyte container into which the modular cathode and anode assemblies extend and are supported above, with the modular cathode and anode assemblies mechanically and electrically connecting to the respective contacts in power distribution systems.

Koehl, Eugene R; Barnes, Laurel A; Wiedmeyer, Stanley G; Williamson, Mark A; Willit, James L

2014-01-28T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

An electrochemical system for efficiently harvesting low-grade heat energy  

E-Print Network [OSTI]

Efficient and low-cost thermal energy-harvesting systems are needed to utilize the tremendous low-grade heat sources. Although thermoelectric devices are attractive, its efficiency is limited by the relatively low ...

Lee, Seok Woo

62

ORIGINAL RESEARCH PAPER Enhanced nitrogen removal in bio-electrochemical systems  

E-Print Network [OSTI]

.V. 2009 Abstract Microbial fuel cells can be designed to remove nitrogenous compounds out of wastewater systems. Keywords Bio-catalyzed cathode Á Energy recovery Á Microbial electrolysis cell Á Microbial fuel, the term microbial fuel cell (MFC) is used, whereas the term microbial electrolysis cell (MEC) is used when

Nerenberg, Robert

63

Microfluidic electrochemical reactors  

DOE Patents [OSTI]

A microfluidic electrochemical reactor includes an electrode and one or more microfluidic channels on the electrode, where the microfluidic channels are covered with a membrane containing a gas permeable polymer. The distance between the electrode and the membrane is less than 500 micrometers. The microfluidic electrochemical reactor can provide for increased reaction rates in electrochemical reactions using a gaseous reactant, as compared to conventional electrochemical cells. Microfluidic electrochemical reactors can be incorporated into devices for applications such as fuel cells, electrochemical analysis, microfluidic actuation, pH gradient formation.

Nuzzo, Ralph G. (Champaign, IL); Mitrovski, Svetlana M. (Urbana, IL)

2011-03-22T23:59:59.000Z

64

Electrochemical Behavior of Lithium in LiOH-H/sub 2/O-System Solutions  

SciTech Connect (OSTI)

A study of the anodic behavior and corrosion of lithium in LiOH-H/sub 2/O-system solutions at 298 /SUP o/ K is made. Anodic potentiodynamic and galvanostatic polarization plots were taken with a P-5827M potentiostat and displayed on a PDP-4 flatbed X-Y recorder. The potentiodynamic polarization curves were taken at a scanning rate of 80 mV/sec where the data were almost reproducible. Ptentiodynamic polarization plots taken for solutions of various LiOH concentrations are shown. Corrosion of the lithium in the aqueous electrolyte was studied volumetrically. Data obtained on lithium corrosion in solutions of the LiOH-H/sub 2/O system confirm the postualte that a lithium hydroxide concentration of more than 4 m densifies passive film on the lithium electrode.

Demidov, A.I.; Gerasimenko, L.N.; Konstantinova, M.V.; Morachevskii, A.G.

1985-04-10T23:59:59.000Z

65

654 IEEE TRANSACTIONS ON CONTROL SYSTEMS TECHNOLOGY, VOL. 18, NO. 3, MAY 2010 Model-Based Electrochemical Estimation and  

E-Print Network [OSTI]

in the literature. Accurate estimation of the battery's internal electrochemical state enables an expanded range governor, state-of-charge (SOC) estimation. I. INTRODUCTION MODEL-BASED battery monitoring algorithms theories, captures relevant solid-state and electrolyte diffusion dynamics and accurately predicts current

66

Breakthrough Flow Battery Cell Stack: Transformative Electrochemical Flow Storage System (TEFSS)  

SciTech Connect (OSTI)

GRIDS Project: UTRC is developing a flow battery with a unique design that provides significantly more power than today's flow battery systems. A flow battery is a cross between a traditional battery and a fuel cell. Flow batteries store their energy in external tanks instead of inside the cell itself. Flow batteries have traditionally been expensive because the battery cell stack, where the chemical reaction takes place, is costly. In this project, UTRC is developing a new stack design that achieves 10 times higher power than today’s flow batteries. This high power output means the size of the cell stack can be smaller, reducing the amount of expensive materials that are needed. UTRC’s flow battery will reduce the cost of storing electricity for the electric grid, making widespread use feasible.

None

2010-09-09T23:59:59.000Z

67

In-situ short-circuit protection system and method for high-energy electrochemical cells  

DOE Patents [OSTI]

An in-situ thermal management system for an energy storage device. The energy storage device includes a plurality of energy storage cells each being coupled in parallel to common positive and negative connections. Each of the energy storage cells, in accordance with the cell's technology, dimensions, and thermal/electrical properties, is configured to have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell is conducted to a cell adjacent the particular cell so as to prevent the temperature of the particular cell from exceeding a breakdown temperature. In one embodiment, a fuse is coupled in series with each of a number of energy storage cells. The fuses are activated by a current spike capacitively produced by a cell upon occurrence of a short-circuit in the cell, thereby electrically isolating the short-circuited cell from the common positive and negative connections.

Gauthier, Michel (La Prairie, CA); Domroese, Michael K. (South St. Paul, MN); Hoffman, Joseph A. (Minneapolis, MN); Lindeman, David D. (Hudson, WI); Noel, Joseph-Robert-Gaetan (St-Hubert, CA); Radewald, Vern E. (Austin, TX); Rouillard, Jean (Saint-Luc, CA); Rouillard, Roger (Beloeil, CA); Shiota, Toshimi (St. Bruno, CA); Trice, Jennifer L. (Eagan, MN)

2003-04-15T23:59:59.000Z

68

In-situ short circuit protection system and method for high-energy electrochemical cells  

DOE Patents [OSTI]

An in-situ thermal management system for an energy storage device. The energy storage device includes a plurality of energy storage cells each being coupled in parallel to common positive and negative connections. Each of the energy storage cells, in accordance with the cell's technology, dimensions, and thermal/electrical properties, is configured to have a ratio of energy content-to-contact surface area such that thermal energy produced by a short-circuit in a particular cell is conducted to a cell adjacent the particular cell so as to prevent the temperature of the particular cell from exceeding a breakdown temperature. In one embodiment, a fuse is coupled in series with each of a number of energy storage cells. The fuses are activated by a current spike capacitively produced by a cell upon occurrence of a short-circuit in the cell, thereby electrically isolating the short-circuited cell from the common positive and negative connections.

Gauthier, Michel (La Prairie, CA); Domroese, Michael K. (South St. Paul, MN); Hoffman, Joseph A. (Minneapolis, MN); Lindeman, David D. (Hudson, WI); Noel, Joseph-Robert-Gaetan (St-Hubert, CA); Radewald, Vern E. (Austin, TX); Rouillard, Jean (Saint-Luc, CA); Rouillard, Roger (Beloeil, CA); Shiota, Toshimi (St. Bruno, CA); Trice, Jennifer L. (Eagan, MN)

2000-01-01T23:59:59.000Z

69

Recognized Leader in Electrochemical Purification  

ScienceCinema (OSTI)

PNNL scientists developed an electrochemical method for purifying copper, a key material that makes possible radiation detection systems of unprecedented sensitivity. The method begins with the purest copper materials available, and results in the lowest-background copper in the world. Chemist Eric Hoppe explains the process.

Hoppe, Eric

2014-07-24T23:59:59.000Z

70

Separator material for electrochemical cells  

DOE Patents [OSTI]

An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

Cieslak, W.R.; Storz, L.J.

1991-03-26T23:59:59.000Z

71

Separator material for electrochemical cells  

DOE Patents [OSTI]

An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

Cieslak, Wendy R. (1166 Laurel Loop NE., Albuquerque, NM 87122); Storz, Leonard J. (2215 Ambassador NE., Albuquerque, NM 87112)

1991-01-01T23:59:59.000Z

72

Electrochemical implications of defects in carbon nanotubes  

E-Print Network [OSTI]

ESR is the equivalent series resistance and is calculatedESR is the equivalent series resistance and is calculatedequivalent circuit of the electrochemical system under inves- tigation. R s is the solution resistance,

Hoefer, Mark

2012-01-01T23:59:59.000Z

73

Electrochemical and optical studies on model photosynthetic systems: Progress report for the period 7/1/84 to 12/1/86  

SciTech Connect (OSTI)

Objective of this research is to study the relation between the structure of photosynthetic pigments and their spectroscopic and electrochemical properties. Model systems under study progress from the least ordered (solutions) through the most highly ordered (Langmuir-Blodgett (LB) monolayers) systems containing BChl, BPheo, and UQ. Vesicles, intermediate between solutions and LB monolayers, are also under investigation. Molecules other than the photosynthetic pigments and quinones have been examined, including chromophores (i.e., surface active cyanine dyes and phthalocyanines) and redox active compounds (methyl viologen (MV) and surfactant ferrocenes), in order to develop the techniques needed to study the photosynthetic components. The chlorophylls are photosensitive and labile. Thus, it is easier first to develop procedures using stable species. During this period, we have focused on the application of electrochemical methods for determining the heterogeneous electron transfer rate constants of BChl and BPheo at metal electrodes (Pt and Au). We have also determined the effect of adsorption on the redox properties of quinones. Resonance Raman (RR) and surface enhanced resonance Raman (SERR) spectroscopy were used to study solution and surface species.

Cotton, T.M.

1986-12-01T23:59:59.000Z

74

Reactive MD Simulations of Electrochemical Oxide Interfaces at...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

protection, ranging from electrochemical energy conversionstorage systems to corrosion surfaces. The goal of this project is to understand the growth mechanisms and...

75

MATERIALS, INTERFACES, AND ELECTROCHEMICAL PHENOMENA Hydrophilic Zeolite Coatings for Improved  

E-Print Network [OSTI]

MATERIALS, INTERFACES, AND ELECTROCHEMICAL PHENOMENA Hydrophilic Zeolite Coatings for Improved Heat the system, decreases the oper- ation noise and the pumping cost. Another major consideration for a heat

Aguilar, Guillermo

76

Mediated electrochemical oxidation of organic wastes using a Co (III) mediator in a nitric acid based system  

DOE Patents [OSTI]

An electrochemical cell with a Co(III) mediator and nitric acid electrolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the mediator oxidizes the organics and insoluble transuranic compounds and is regenerated at the anode until the organics are converted to CO[sub 2]. The nitric acid is an excellent oxidant that facilitates the destruction of the organic components. The anode is not readily attacked by the nitric acid solution, thus the cell can be used for extended continual operation without electrode replacement. 2 figs.

Balazs, G.B.; Chiba, Z.; Lewis, P.R.; Nelson, N.; Steward, G.A.

1999-06-15T23:59:59.000Z

77

Mediated electrochemical oxidation of organic wastes using a Co (III) mediator in a nitric acid based system  

DOE Patents [OSTI]

An electrochemical cell with a Co(III) mediator and nitric acid electrolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the mediator oxidizes the organics and insoluble transuranic compounds and is regenerated at the anode until the organics are converted to CO.sub.2. The nitric acid is an excellent oxidant that facilitates the destruction of the organic components. The anode is not readily attacked by the nitric acid solution, thus the cell can be used for extended continual operation without electrode replacement.

Balazs, G. Bryan (Livermore, CA); Chiba, Zoher (Moraga, CA); Lewis, Patricia R. (Livermore, CA); Nelson, Norvell (Palo Alto, CA); Steward, G. Anthony (Los Altos Hills, CA)

1999-01-01T23:59:59.000Z

78

Electrochemical methane sensor  

DOE Patents [OSTI]

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, S.; Otagawa, T.; Stetter, J.R.

1984-08-27T23:59:59.000Z

79

Nanoelectrode array for electrochemical analysis  

DOE Patents [OSTI]

A nanoelectrode array comprises a plurality of nanoelectrodes wherein the geometric dimensions of the electrode controls the electrochemical response, and the current density is independent of time. By combining a massive array of nanoelectrodes in parallel, the current signal can be amplified while still retaining the beneficial geometric advantages of nanoelectrodes. Such nanoelectrode arrays can be used in a sensor system for rapid, non-contaminating field analysis. For example, an array of suitably functionalized nanoelectrodes can be incorporated into a small, integrated sensor system that can identify many species rapidly and simultaneously under field conditions in high-resistivity water, without the need for chemical addition to increase conductivity.

Yelton, William G. (Sandia Park, NM); Siegal, Michael P. (Albuquerque, NM)

2009-12-01T23:59:59.000Z

80

"Studying the electrochemical and chemical conditions of corrosion in  

E-Print Network [OSTI]

"Studying the electrochemical and chemical conditions of corrosion in mission critical systems of Virginia Charlottesville, VA 434.982.5783 Center for Electrochemical Science & Engineering Corrosion, the degradation of materials, has a massive economic impact. The estimated annual cost of corrosion to the U

Acton, Scott

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

HIGH TEMPERATURE REMOVAL OF H{sub 2}S FROM COAL GASIFICATION PROCESS STREAMS USING AN ELECTROCHEMICAL MEMBRANE SYSTEM  

SciTech Connect (OSTI)

A bench scale set-up was constructed to test the cell performance at 600-700 C and 1 atm. The typical fuel stream inlet proportions were 34% CO, 22% CO{sub 2}, 35% H{sub 2}, 8% H{sub 2}O, and 450-2000 ppm H{sub 2}S. The fundamental transport restrictions for sulfur species in an electrochemical cell were examined. Temperature and membrane thickness were varied to examine how these parameters affect the maximum flux of H{sub 2}S removal. It was found that higher temperature allows more sulfide species to enter the electrolyte, thus increasing the sulfide flux across the membrane and raising the maximum flux of H{sub 2}S removal. The results identify sulfide diffusion across the membrane as the rate-limiting step in H{sub 2}S removal. The maximum H{sub 2}S removal flux of 1.1 x 10-6 gmol H{sub 2}S min{sup -1} cm{sup -2} (or 3.5 mA cm{sup -2}) was obtained at 650 C, with a membrane that was 0.9 mm thick, 36% porous, and had an estimated tortuosity of 3.6. Another focus of this thesis was to examine the stability of cathode materials in full cell trials. A major hurdle that remains in process scale-up is cathode selection, as the lifetime of the cell will depend heavily on the lifetime of the cathode material, which is exposed to very sour gas. Materials that showed success in the past (i.e. cobalt sulfides and Y{sub 0.9}Ca{sub 0.1}FeO{sub 3}) were examined but were seen to have limitations in operating environment and temperature. Therefore, other novel metal oxide compounds were studied to find possible candidates for full cell trials. Gd{sub 2}TiMoO{sub 7} and La{sub 0.7}Sr{sub 0.3}VO{sub 3} were the compounds that retained their structure best even when exposed to high H{sub 2}S, CO{sub 2}, and H{sub 2}O concentrations.

Jack Winnick; Meilin Liu

2003-06-01T23:59:59.000Z

82

Nanotechnology-Based Electrochemical Sensors for Biomonitoring...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanotechnology-Based Electrochemical Sensors for Biomonitoring Chemical Exposures . Nanotechnology-Based Electrochemical Sensors for Biomonitoring Chemical Exposures . Abstract:...

83

1352 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 19, NO. 6, DECEMBER 2010 Parylene-Based Electrochemical-MEMS Transducers  

E-Print Network [OSTI]

on a microelectromechanical systems scanning mirror Wibool Piyawattanametha,1,2 Eric D. Cocker,1 Laurie D. Burns,1 Robert P. J on a microelectromechanical systems (MEMS) laser-scanning mirror. The microscope has a focusing motor and a micro

Meng, Ellis

84

Separators for electrochemical cells  

DOE Patents [OSTI]

Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

Carlson, Steven Allen; Anakor, Ifenna Kingsley

2014-11-11T23:59:59.000Z

85

Electrochemical fabrication of capacitors  

SciTech Connect (OSTI)

A film of nickel oxide is anodically deposited on a graphite sheet held in position on an electrochemical cell during application of a positive electrode voltage to the graphite sheet while exposed to an electrolytic nickel oxide solution within a volumetrically variable chamber of the cell. An angularly orientated x-ray beam is admitted into the cell for transmission through the deposited nickel oxide film in order to obtain structural information while the film is subject to electrochemical and in-situ x-ray spectroscopy from which optimum film thickness, may be determined by comparative analysis for capacitor fabrication purposes.

Mansour, A.N.; Melendres, C.A.

1999-12-14T23:59:59.000Z

86

Electrochemical membrane incinerator  

DOE Patents [OSTI]

Electrochemical incineration of p-benzoquinone was evaluated as a model for the mineralization of carbon in toxic aromatic compounds. A Ti or Pt anode was coated with a film of the oxides of Ti, Ru, Sn and Sb. This quaternary metal oxide film was stable; elemental analysis of the electrolyzed solution indicated the concentration of these metal ions to be 3 .mu.g/L or less. The anode showed good reactivity for the electrochemical incineration of benzoquinone. The use of a dissolved salt matrix as the so-called "supporting electrolyte" was eliminated in favor of a solid-state electrolyte sandwiched between the anode and cathode.

Johnson, Dennis C. (Ames, IA); Houk, Linda L. (Ames, IA); Feng, Jianren (Ames, IA)

2001-03-20T23:59:59.000Z

87

Electrochemical micro sensor  

DOE Patents [OSTI]

A micro-amperometric electrochemical sensor for detecting the presence of a pre-determined species in a fluid material is disclosed. The sensor includes a smooth substrate having a thin coating of solid electrolytic material deposited thereon. The working and counter electrodes are deposited on the surface of the solid electrolytic material and adhere thereto. Electrical leads connect the working and counter electrodes to a potential source and an apparatus for measuring the change in an electrical signal caused by the electrochemical oxidation or reduction of the species. Alternatively, the sensor may be fabricated in a sandwich structure and also may be cylindrical, spherical or other shapes.

Setter, Joseph R. (Naperville, IL); Maclay, G. Jordan (Maywood, IL)

1989-09-12T23:59:59.000Z

88

NAME ORGANIZATION E-MAIL PHONE Aly Shaaban AFRL/MLQ aly.shaaban@tyndall.af.mil (850) 283-3702  

E-Print Network [OSTI]

@futuristicdesighnintl.com (248) 396-2399 Mark Richards Gas Technology Institute mark.richards@gastechnology.org (847) 768) 986-5149 Lawrence Gestaut Giner Electrochemical lgestaut@ginerinc.com (781) 529-0533 Lou Lautman GTI

89

A flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface  

E-Print Network [OSTI]

low-noise measurements in ambient, in situ, and electrochemical environments. II. DESIGNA flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface, specifically in electrolyte environments. Quantification of system noise limits

Gimzewski, James

90

Hydrogen Production by PEM Electrolysis: Spotlight on Giner and Proton  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:GroundtoProduction Technical Team Roadmap June

91

Remote electrochemical sensor  

DOE Patents [OSTI]

An electrochemical sensor for remote detection, particularly useful for metal contaminants and organic or other compounds. The sensor circumvents technical difficulties that previously prevented in-situ remote operations. The microelectrode, connected to a long communications cable, allows convenient measurements of the element or compound at timed and frequent intervals and instrument/sample distances of ten feet to more than 100 feet. The sensor is useful for both downhole groundwater monitoring and in-situ water (e.g., shipboard seawater) analysis.

Wang, Joseph (Las Cruces, NM); Olsen, Khris (Richland, WA); Larson, David (Las Cruces, NM)

1997-01-01T23:59:59.000Z

92

Electrochemical, Structural and Surface Characterization of Nickel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrochemical, Structural and Surface Characterization of NickelZirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Electrochemical, Structural and Surface...

93

Advanced Hybrid Water Heater using Electrochemical Compressor...  

Energy Savers [EERE]

Advanced Hybrid Water Heater using Electrochemical Compressor Advanced Hybrid Water Heater using Electrochemical Compressor Xergy is using its Electro Chemical Compression (ECC)...

94

Facile and controllable electrochemical reduction of graphene...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and controllable electrochemical reduction of graphene oxide and its applications. Facile and controllable electrochemical reduction of graphene oxide and its applications....

95

Electrochemical thinning of silicon  

DOE Patents [OSTI]

Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR).

Medernach, John W. (Albuquerque, NM)

1994-01-01T23:59:59.000Z

96

Electrochemical thinning of silicon  

DOE Patents [OSTI]

Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR). 14 figures.

Medernach, J.W.

1994-01-11T23:59:59.000Z

97

Remote electrochemical sensor  

DOE Patents [OSTI]

An electrochemical sensor is described for remote detection, particularly useful for metal contaminants and organic or other compounds. The sensor circumvents technical difficulties that previously prevented in-situ remote operations. The microelectrode, connected to a long communications cable, allows convenient measurements of the element or compound at timed and frequent intervals and instrument/sample distances of ten feet to more than 100 feet. The sensor is useful for both downhole groundwater monitoring and in-situ water (e.g., shipboard seawater) analysis. 21 figs.

Wang, J.; Olsen, K.; Larson, D.

1997-10-14T23:59:59.000Z

98

Electrochemical cell method  

DOE Patents [OSTI]

A secondary electrochemical cell is prepared by providing positive and negative electrodes having outer enclosures of rigid perforated electrically conductive material defining an internal compartment containing the electrode material in porous solid form. The electrodes are each immersed in molten electrolyte salt prior to cell assembly to incorporate the cell electrolyte. Following solidification of the electrolyte substantially throughout the porous volume of the electrode material, the electrodes are arranged in an alternating positive-negative array with interelectrode separators of porous frangible electrically insulative material. The completed array is assembled into the cell housing and sealed such that on heating the solidified electrolyte flows into the interelectrode separator.

Kaun, T.D.; Eshman, P.F.

1980-05-09T23:59:59.000Z

99

Electrochemical photovoltaic cells and electrodes  

DOE Patents [OSTI]

Improved electrochemical photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

Skotheim, Terje A. (East Patchogue, NY)

1984-01-01T23:59:59.000Z

100

Electrochemical sensor for monitoring electrochemical potentials of fuel cell components  

DOE Patents [OSTI]

An electrochemical sensor comprised of wires, a sheath, and a conduit can be utilized to monitor fuel cell component electric potentials during fuel cell shut down or steady state. The electrochemical sensor contacts an electrolyte reservoir plate such that the conduit wicks electrolyte through capillary action to the wires to provide water necessary for the electrolysis reaction which occurs thereon. A voltage is applied across the wires of the electrochemical sensor until hydrogen evolution occurs at the surface of one of the wires, thereby forming a hydrogen reference electrode. The voltage of the fuel cell component is then determined with relation to the hydrogen reference electrode.

Kunz, Harold R. (Vernon, CT); Breault, Richard D. (Coventry, CT)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Process for electrochemically gasifying coal  

DOE Patents [OSTI]

A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

Botts, T.E.; Powell, J.R.

1985-10-25T23:59:59.000Z

102

Renewable-reagent electrochemical sensor  

DOE Patents [OSTI]

A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery is described. The probe comprises an integrated membrane sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s). 19 figs.

Wang, J.; Olsen, K.B.

1999-08-24T23:59:59.000Z

103

Renewable-reagent electrochemical sensor  

DOE Patents [OSTI]

A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery. The probe comprises an integrated membrane-sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s).

Wang, Joseph (Las Cruces, NM); Olsen, Khris B. (Richland, WA)

1999-01-01T23:59:59.000Z

104

An electrochemical route for making porous nickel oxide electrochemical capacitors  

SciTech Connect (OSTI)

Porous nickel oxide films were prepared by electrochemically precipitating nickel hydroxide and heating the hydroxide in air at 300 C. The resulting nickel oxide films behave as an electrochemical capacitor with a specific capacitance of 59 F/g electrode material. These nickel oxide films maintain high utilization at high rates of discharge (i.e., high power density) and have excellent cycle life. Porous cobalt oxide films were also synthesized. Although the specific capacitances of these films are approximately one-fifth that of the nickel oxide films, the results demonstrate the versatility of fabricating a wide range of porous metal oxide films using this electrochemical route for use in capacitor applications. Electrochemical capacitors have generated wide interest in recent years for use in high power applications (e.g., in a hybrid electric vehicle, where they are expected to work in conjunction with a conventional battery).

Srinivasan, V.; Weidner, J.W. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering

1997-08-01T23:59:59.000Z

105

Electrochemical catalyst recovery method  

DOE Patents [OSTI]

A method of recovering catalyst material from latent catalyst material solids includes: (a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; (b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; (c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and (d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications. 3 figs.

Silva, L.J.; Bray, L.A.

1995-05-30T23:59:59.000Z

106

Development of Electrochemical Micro Machining  

E-Print Network [OSTI]

. Micro electrochemical machining (µECM) removes material while holding micron tolerances and µECM can machine hard metals and alloys. This study aims at developing a novel µECM utilizing high frequency voltage pulses and closed loop control... DEVELOPMENT OF ELECTROCHEMICAL MICRO MACHINING A Thesis by SRIHARSHA SRINIVAS SUNDARRAM Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

Srinivas Sundarram, Sriharsha

2008-10-10T23:59:59.000Z

107

Electrochemical Hydrogen Compressor  

SciTech Connect (OSTI)

The Electrochemical Hydrogen Compressor EHC was evaluated against DOE applications for compressing hydrogen at automobile filling stations, in future hydrogen pipelines and as a commercial replacement for conventional diaphragm hydrogen compressors. It was also evaluated as a modular replacement for the compressors used in petrochemical refineries. If the EHC can be made inexpensive, reliable and long lived then it can satisfy all these applications save pipelines where the requirements for platinum catalyst exceeds the annual world production. The research performed did not completely investigate Molybdenum as a hydrogen anode or cathode, it did show that photoetched 316 stainless steel is inadequate for an EHC. It also showed that: molybdenum bipolar plates, photochemical etching processes, and Gortex Teflon seals are too costly for a commercial EHC. The use of carbon paper in combination with a perforated thin metal electrode demonstrated adequate anode support strength, but is suspect in promoting galvanic corrosion. The nature of the corrosion mechanisms are not well understood, but locally high potentials within the unit cell package are probably involved. The program produced a design with an extraordinary high cell pitch, and a very low part count. This is one of the promising aspects of the redesigned EHC. The development and successful demonstration of the hydraulic cathode is also important. The problem of corrosion resistant metal bipolar plates is vital to the development of an inexpensive, commercial PEM fuel cell. Our research suggests that there is more to the corrosion process in fuel cells and electrochemical compressors than simple, steady state, galvanic stability. It is an important area for scientific investigation. The experiments and analysis conducted lead to several recommended future research directions. First, we need a better understanding of the corrosion mechanisms involved. The diagnosis of experimental cells with titration to determine the loss of membrane active sites is recommended. We suspect that the corrosion includes more than simple galvanic mechanisms. The mechanisms involved in this phenomenon are poorly understood. Shunt currents at hydraulic cathode ports were problematic, but are not difficult to cure. In addition to corrosion there is evidence of high component resistivity. This may be due to the deposition of organic compounds, which may be produced electrochemically on the surface of the metal support screens that contact carbon gas diffusion layers (GDLs) or catalyst supports. An investigation of possible electro-organic sythesis mechanisms with emphasis on oxalates formation is warranted. The contaminated cell parts can be placed in an oxidizing atmosphere at high temperature and the weight loss can be observed. This would reveal the existence of organic compounds. Investigation into the effects of conductivity enhancers such as carbon microlayers on supporting carbon paper is also needed. Corrosion solutions should be investigated such as surface passivation of 316 SS parts using nitric acid. Ultra thin silane/siloxane polymer coatings should be tried. These may be especially useful in conjunction with metal felt replacement of carbon paper. A simple cure for the very high, localized corrosion of the anode might be to diffusion bond the metal electrode support screen to bipolar plate. This will insure uniform resistance perpendicular to the plane of the cell and eliminate some of the dependence of the resistance on high stack compression. Alternative materials should be explored. Alternatives to carbon in the cell may be helpful in any context. In particular, alternatives to carbon paper GDLs such as metal felts and alternatives to carbon supports for Pt such as TiC and TiB2 might also be worthwhile and would be helpful to fuel cells as well. Some alternative to the metals we used in the cell, Mo and 316 SS, are potentially useful. These include Al/Mg/Si alloys. Corrosion resistant materials such as Nb and Mo might prove useful as cladding materials that can be hot stamp

David P. Bloomfield; Brian S. MacKenzie

2006-05-01T23:59:59.000Z

108

Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1  

E-Print Network [OSTI]

Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1 , Wen Chao Lee1 This study demonstrates the feasibility of using water and the contents of waste Li-ion batteries for the electrodes in a Li-liquid battery system. Li metal was collected electrochemically from a waste Li

Zhou, Yaoqi

109

High-resolution friction force microscopy under electrochemical control Aleksander Labuda,1  

E-Print Network [OSTI]

High-resolution friction force microscopy under electrochemical control Aleksander Labuda,1 William and development of a friction force microscope for high-resolution studies in electrochemical environments in liquids. The noise of the system is analyzed based on a methodology for the quantification of all

Grütter, Peter

110

Time Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2.5 Brownmillerite Structure: Comparison with the Homologous SrCoO2.5 System  

E-Print Network [OSTI]

temperature oxygen ionic conductors are key materials for the development of the next generation solid oxideTime Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2 to reversibly intercalate oxygen in an electrochemical reaction at room temperature to reach SrMO3 stoichiometry

Frenkel, Anatoly

111

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

Broader source: Energy.gov (indexed) [DOE]

of Work * Barriers * Approach * Performance Measures and Accomplishments * Technology Transfer * Plans for Next Fiscal Year * Summary * PublicationsPatents Electrochemical...

112

Electrochemically Stable Cathode Current Collectors for Rechargeable...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stable Cathode Current Collectors for Rechargeable Magnesium Batteries . Electrochemically Stable Cathode Current Collectors for Rechargeable Magnesium Batteries . Abstract:...

113

ELECTROCHEMICAL POWER FOR TRANSPORTATION  

E-Print Network [OSTI]

Battery Type Overall Electric Drive System Demonstration ofof batteries and electric drive components and to obtain ain Section 5. Overall Electric Drive System The electric

Cairns, Elton J.

2012-01-01T23:59:59.000Z

114

Development of an electrochemical hydrogen separator  

SciTech Connect (OSTI)

The EHS is an electrochemical hydrogen separator based on the uniquely reversible nature of hydrogen oxidation-reduction reactions in electrochemical systems. The principle and the hardware concept are shown in Figure 1. Hydrogen from the mixed gas stream is oxidized to H{sup +} ions, transported through a cation transport electrolyte membrane (matrix) under an applied electric field and discharged in a pure hydrogen state on the cathode. The cation transfer electrolyte membrane provides a barrier between the feed and product gases. The EHS design is an offshoot of phosphoric acid fuel cell development. Although any proton transfer electrolyte can be used, the phosphoric acid based system offers a unique advantage because its operating temperature of {approximately}200{degree}C makes it tolerant to trace CO and also closely matches the water-shift reactor exit gas temperature ({approximately}250{degree}C). Hydrogen-containing streams in coal gasification systems have large carbon monoxide contents. For efficient hydrogen recovery, most of the CO must be converted to hydrogen by the low temperature water-shift reaction (Figure 2). Advanced coal gasification and gas separation technologies offer an important pathway to the clean utilization of coal resources.

Abens, S.; Fruchtman, J.; Kush, A.

1993-09-01T23:59:59.000Z

115

Electrochemical behavior of lead telluride  

SciTech Connect (OSTI)

The electrochemical behavior of lead telluride was studied in acidic, neutral, and alkaline solutions. It was shown that in the case of anodic polarization in 1 M NaOH the PbTe surface composition is nearly stoichiometric. During cathodic polarization in 1 M NaOH and during anodic polarization in 1 M HCl the surface layer is lead-rich. In the case of anodic polarization in 1 M HCl the surface is tellurium-rich. Cathodic polarization in 1 M NaCl leads to tellurium depletion of the surface layer. Reaction equations describing the electrochemical processes at the PbTe electrode are reported.

Danilova, M.G.; Sveshnikova, L.L.; Repinskii, S.M.

1987-07-01T23:59:59.000Z

116

Electrochemical characterization and time-variant structural reliability assessment of post-tensioned, segmental concrete bridges  

E-Print Network [OSTI]

results obtained from a comprehensive experimental and analytical program on the performance of PT bridges. 1) Electrochemical characteristics of PT systems 2) Probabilistic models for tension capacity of PT strands and wires exposed to various void...

Pillai Gopalakrishnan, Radhakris

2010-07-14T23:59:59.000Z

117

Decoupling Electrochemical Reaction  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

storage devices, ranging from Liion 1 and Liair batteries, 2 to solid oxide fuel cells (SOFC) 3 to electrore- sistive 4 and memristive 5 systems. These...

118

Electrochemical synthesis of multisegmented nanowires  

SciTech Connect (OSTI)

Electrochemical deposition has emerged as a promising route for nanostructure fabrication in recent years due to the many inherent advantages it possesses. This study focuses on the synthesis of high-aspect-ratio multisegmented Au/Ni nanowires using template-directed sequential electrochemical deposition techniques. By selectively removing the Ni segments in the nanowires, high-yield of pure gold nanorods of predetermined lengths was obtained. Alternatively, the sacrificial Ni segments in the nanowires can be galvanically displaced with Bi and Te to form barbells structures with Bi{sub x}Te{sub y} nanotubes attached to neighbouring gold segments. Detailed studies on the nanostructures obtained were carried out using various microscopy, diffraction and probebased techniques for structural, morphological and chemical characterizations.

Kok, Kuan-Ying; Ng, Inn-Khuan; Saidin, Nur Ubaidah [Malaysian Nuclear Agency, Bangi, 43000 Kajang (Malaysia)

2012-11-27T23:59:59.000Z

119

Graphene-based Electrochemical Energy Conversion and Storage: Fuel cells, Supercapacitors and Lithium Ion Batteries  

SciTech Connect (OSTI)

Graphene has attracted extensive research interest due to its strictly 2-dimensional (2D) structure, which results in its unique electronic, thermal, mechanical, and chemical properties and potential technical applications. These remarkable characteristics of graphene, along with the inherent benefits of a carbon material, make it a promising candidate for application in electrochemical energy devices. This article reviews the methods of graphene preparation, introduces the unique electrochemical behavior of graphene, and summarizes the recent research and development on graphene-based fuel cells, supercapacitors and lithium ion batteries. In addition, promising areas are identified for the future development of graphene-based materials in electrochemical energy conversion and storage systems.

Hou, Junbo; Shao, Yuyan; Ellis, Michael A.; Moore, Robert; Yi, Baolian

2011-09-14T23:59:59.000Z

120

Argonne Electrochemical Technology ProgramArgonne Electrochemical Technology Program Effects of Fuel Composition on  

E-Print Network [OSTI]

Argonne Electrochemical Technology ProgramArgonne Electrochemical Technology Program Effects. Applegate, L. Miller, Cecille Rossignol Argonne National Laboratory Annual Review The Hydrogen, Fuel Cells Argonne National Laboratory Annual Review The Hydrogen, Fuel Cells & Infrastructure Technologies Program

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Compacted carbon for electrochemical cells  

DOE Patents [OSTI]

This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

Greinke, R.A.; Lewis, I.C.

1997-10-14T23:59:59.000Z

122

Shock-activated electrochemical power supplies  

DOE Patents [OSTI]

A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolyte rendering the electrolyte electrochemically active. 2 figs.

Benedick, W.B.; Graham, R.A.; Morosin, B.

1987-04-20T23:59:59.000Z

123

Shock-activated electrochemical power supplies  

DOE Patents [OSTI]

A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolytes rendering the electrolyte electrochemically active. 2 figs.

Benedick, W.B.; Graham, R.A.; Morosin, B.

1988-11-08T23:59:59.000Z

124

Electrochemical components employing polysiloxane-derived binders  

DOE Patents [OSTI]

A processed polysiloxane resin binder for use in electrochemical components and the method for fabricating components with the binder. The binder comprises processed polysiloxane resin that is partially oxidized and retains some of its methyl groups following partial oxidation. The binder is suitable for use in electrodes of various types, separators in electrochemical devices, primary lithium batteries, electrolytic capacitors, electrochemical capacitors, fuel cells and sensors.

Delnick, Frank M.

2013-06-11T23:59:59.000Z

125

Reliability of electrochemical noise measurements: results of round-robin testing on electrochemical noise  

E-Print Network [OSTI]

1 Reliability of electrochemical noise measurements: results of round-robin testing on electrochemical noise Rik-Wouter BOSCHa , Robert A. COTTISb,* , Kinga CSECSc , Thomas DORSCHc , Lucia DUNBARd), Switzerland; p) University of Cadiz, Spain. Abstract Sixteen laboratories have performed electrochemical noise

126

Electrochemical detection of leukemia oncogenes using enzyme...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and early disease diagnostic applications. Citation: Lee AC, D Du, B Chen, CK Heng, TM Lim, and Y Lin.2014."Electrochemical detection of leukemia oncogenes using...

127

Vehicle Technologies Office Merit Review 2014: Electrochemical...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Electrochemical Modeling of LMR-NMC Materials and Electrodes Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle...

128

Apparatus for combinatorial screening of electrochemical materials  

DOE Patents [OSTI]

A high throughput combinatorial screening method and apparatus for the evaluation of electrochemical materials using a single voltage source (2) is disclosed wherein temperature changes arising from the application of an electrical load to a cell array (1) are used to evaluate the relative electrochemical efficiency of the materials comprising the array. The apparatus may include an array of electrochemical cells (1) that are connected to each other in parallel or in series, an electronic load (2) for applying a voltage or current to the electrochemical cells (1), and a device (3), external to the cells, for monitoring the relative temperature of each cell when the load is applied.

A high throughput combinatorial screening method and apparatus for the evaluation of electrochemical materials using a single voltage source (2) is disclosed wherein temperature changes arising from the application of an electrical load to a cell array (1) are used to evaluate the relative electrochemical efficiency of the materials comprising the array. The apparatus may include an array of electrochemical cells (1) that are connected to each other in parallel or in series, an electronic load (2) for applying a voltage or current to the electrochemical cells (1), and a device (3), external to the cells, for monitoring the relative temperature of each cell when the load is applied.

2009-12-15T23:59:59.000Z

129

Nanostructured Electrochemical Sensors Based on Functionalized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sensors Based on Functionalized Nanoporous Silica for Voltammetric Analysis of Lead, Mercury and Nanostructured Electrochemical Sensors Based on Functionalized Nanoporous Silica...

130

Thermal regeneration of an electrochemical concentration cell  

DOE Patents [OSTI]

A system and method for thermally regenerating an electrochemical concentration cell having first and second aluminum electrodes respectively positioned in contact with first and second electrolytes separated by an ion exchange member, the first and second electrolytes being composed of different concentrations of an ionic solvent and a salt, preferably an aluminum halide. The ionic solvent may be either organic or inorganic with a relatively low melting point, the ionic solvent and the salt form a complex wherein the free energy of formation of said complex is less than about -5 Kcal/mole. A distillation column using solar heat or low grade industrial waste heat receives the first and second electrolytes and thermally decomposes the salt-solvent complex to provide feed material for the two half cells.

Krumpelt, Michael (Naperville, IL); Bates, John K. (Plainfield, IL)

1981-01-01T23:59:59.000Z

131

Thermal regeneration of an electrochemical concentration cell  

DOE Patents [OSTI]

A system and method are described for thermally regenerating an electrochemical concentration cell having first and second aluminum electrodes respectively positioned in contact with first and second electrolytes separated by an ion exchange member, the first and second electrolytes being composed of different concentrations of an ionic solvent and a salt, preferably an aluminum halide. The ionic solvent may be either organic or inorganic with a relatively low melting point, the ionic solvent and the salt form a complex wherein the free energy of formation of said complex is less than about -5 kcal/mole. A distillation column using solar heat or low grade industrial waste heat receives the first and second electrolytes and thermally decomposes the salt-solvent complex to provide feed material for the two half cells.

Krumpelt, M.; Bates, J.K.

1980-05-09T23:59:59.000Z

132

Effects of Tungsten Oxide Addition on the Electrochemical Performance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Effects of Tungsten Oxide Addition on the Electrochemical...

133

Integrated Lateral Flow Test Strip with Electrochemical Sensor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lateral Flow Test Strip with Electrochemical Sensor for Quantification of Phosphorylated Cholinesterase: Biomarker of Integrated Lateral Flow Test Strip with Electrochemical Sensor...

134

Carbon Nanotubes (CNTs) for the Development of Electrochemical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(CNTs) for the Development of Electrochemical Biosensors . Carbon Nanotubes (CNTs) for the Development of Electrochemical Biosensors . Abstract: Carbon nanotube (CNT) is a very...

135

A graphene-based electrochemical sensor for sensitive detection...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A graphene-based electrochemical sensor for sensitive detection of paracetamol . A graphene-based electrochemical sensor for sensitive detection of paracetamol . Abstract: An...

136

A Renewable Electrochemical Magnetic Immunosensor Based on Gold...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Renewable Electrochemical Magnetic Immunosensor Based on Gold Nanoparticle Labels. A Renewable Electrochemical Magnetic Immunosensor Based on Gold Nanoparticle Labels. Abstract: A...

137

US DRIVE Electrochemical Energy Storage Technical Team Roadmap...  

Broader source: Energy.gov (indexed) [DOE]

This U.S. DRIVE electrochemical energy storage roadmap describes ongoing and planned efforts to develop electrochemical energy storage technologies for plug-in electric vehicles...

138

Papers Based Electrochemical Biosensors: From Test Strips to...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Papers Based Electrochemical Biosensors: From Test Strips to Paper-Based Microfluidics. Papers Based Electrochemical Biosensors: From Test Strips to Paper-Based Microfluidics....

139

Nitrogen-doped Graphene and Its Electrochemical Applications...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

doped Graphene and Its Electrochemical Applications. Nitrogen-doped Graphene and Its Electrochemical Applications. Abstract: Nitrogen-doped graphene (N-graphene) is obtained by...

140

A graphene-based electrochemical sensor for sensitive detection...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

graphene-based electrochemical sensor for sensitive detection of paracetamol . A graphene-based electrochemical sensor for sensitive detection of paracetamol . Abstract: An...

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Nitrogen-Doped Graphene and its Application in Electrochemical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Doped Graphene and its Application in Electrochemical Biosensing. Nitrogen-Doped Graphene and its Application in Electrochemical Biosensing. Abstract: Chemical doping with foreign...

142

Carbon Nanotube-Based Electrochemical Sensor for Assay of Salivary...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nanotube-Based Electrochemical Sensor for Assay of Salivary Cholinesterase Enzyme Activity: An Exposure Biomarker of Carbon Nanotube-Based Electrochemical Sensor for Assay of...

143

ESM of Ionic and Electrochemical Phenomena on the Nanoscale  

SciTech Connect (OSTI)

Operation of energy storage and conversion devices is ultimately controlled by series of intertwined ionic and electronic transport processes and electrochemical reactions at surfaces and interfaces, strongly mediated by strain and mechanical processes [1-4]. In a typical fuel cell, these include chemical species transport in porous cathode and anode materials, gas-solid electrochemical reactions at grains and triple-phase boundaries (TPBs), ionic and electronic flows in multicomponent electrodes, and chemical and electronic potential drops at internal interfaces in electrodes and electrolytes. All these phenomena are sensitively affected by the microstructure of materials from device level to the atomic scales as illustrated in Fig. 1. Similar spectrum of length scales and phenomena underpin operation of other energy systems including primary and secondary batteries, as well as hybrid systems such flow and metal-air/water batteries.

Kalinin, Sergei V [ORNL; Kumar, Amit [Pennsylvania State University; Balke, Nina [ORNL; McCorkle, Morgan L [ORNL; Guo, Senli [ORNL; Arruda, Thomas M [ORNL; Jesse, Stephen [ORNL

2011-01-01T23:59:59.000Z

144

Rapid electrochemical screening of engine coolants. Correlation of electrochemical potentiometric measurements with ASTM D 1384 glassware corrosion test  

SciTech Connect (OSTI)

Engine coolants are typically subjected to comprehensive performance evaluations that involve multiple laboratory and field tests. These tests can take several weeks to conduct and can be expensive. The tests can involve everything from preliminary chemical screening to long term fleet tests. An important test conducted at the beginning of coolant formula development to screen the corrosion performance of engine coolants is described in ASTM D 1384. If the coolant formula passes the test, it is then subjected to more rigorous testing. Conducting the test described in ASTM D 1384 takes two weeks, and determining the coolant corrosion performance under several test parameters can takes resources and time that users seldom have. Therefore, it is very desirable to have tests that can be used for rapid screening and quality assurance of coolants. The purpose of this study was to conduct electrochemical tests that can ultimately be used for quick initial screening of engine coolants. The specific intent of the electrochemical tests is to use ASTM D 1384 as a model and to attempt to duplicate its results. Implementation of the electrochemical tests could accelerate the process of selecting promising coolant formulas and reduce coolant evaluation time and cost. Various electrochemical tests were conducted to determine the corrosion performance of several engine coolant formulas. The test results were compared to those obtained from the ASTM D 1384 test. These tests were conducted on the same metal specimens and under similar conditions as those used in the ASTM D 1384 test. The electrochemical tests included the determination of open circuit potential (OCP) for the various metal specimens, anodic and cathodic polarization curves for the various metal specimens, corrosion rate for metal specimens involved in a galvanic triad, and critical pitting potential (CPP) for aluminum (pitting of aluminum engine components and cooling systems is a cause for concern). The details for the methods and the correlation of the results to ASTM D 1384 tests results will be presented.

Doucet, G.P. [Shell Chemical Co., Houston, TX (United States); Jackson, J.M.; Kriegel, O.A.; Passwater, D.K. [Shell Oil Products Co., Houston, TX (United States); Prieto, N.E. [Petroferm Inc., Fernandina Beach, FL (United States)

1999-08-01T23:59:59.000Z

145

Electrochemical studies of quinone oxygen  

SciTech Connect (OSTI)

Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

1990-02-01T23:59:59.000Z

146

Electrochemical formation of field emitters  

DOE Patents [OSTI]

Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area.

Bernhardt, Anthony F. (Berkeley, CA)

1999-01-01T23:59:59.000Z

147

Materials for electrochemical capacitors: Theoretical and experimental constraints  

SciTech Connect (OSTI)

Electrochemical capacitors, also called supercapacitors, are unique devices exhibiting 20 to 200 times greater capacitance than conventional capacitors. The large capacitance exhibited by these systems has been demonstrated to arise from a combination of the double-layer capacitance and pseudocapacitance associated with surface redox-type reactions. The purpose of this review is to survey the published data of available electrode materials possessing high specific double-layer or pseudocapacitance and examine their reported performance data in relation to their theoretical expectations.

Sarangapani, S. [ICET, Inc., Norwood, MA (United States); Tilak, B.V.; Chen, C.P. [Occidental Chemical Corp., Grand Island, NY (United States)

1996-11-01T23:59:59.000Z

148

Electrochemically Stable Cathode Current Collectors for Rechargeable Magnesium Batteries  

SciTech Connect (OSTI)

Rechargeable Mg batteries are attractive energy storage systems and could bring cost-effective energy solutions. Currently, however, no practical cathode current collectors that can withstand high voltages in Mg2+ electrolytes has been identified and therefore cathode research is greatly hindered. Here we identified that two metals, Mo and W, are electrochemically stable through formation of surface passive layers. The presented results could have significant impacts on the developments of high voltage Mg batteries.

Cheng, Yingwen; Liu, Tianbiao L.; Shao, Yuyan; Engelhard, Mark H.; Liu, Jun; Li, Guosheng

2014-01-01T23:59:59.000Z

149

Bussing Structure In An Electrochemical Cell  

DOE Patents [OSTI]

A bussing structure for bussing current within an electrochemical cell. The bussing structure includes a first plate and a second plate, each having a central aperture therein. Current collection tabs, extending from an electrode stack in the electrochemical cell, extend through the central aperture in the first plate, and are then sandwiched between the first plate and second plate. The second plate is then connected to a terminal on the outside of the case of the electrochemical cell. Each of the first and second plates includes a second aperture which is positioned beneath a safety vent in the case of the electrochemical cell to promote turbulent flow of gasses through the vent upon its opening. The second plate also includes protrusions for spacing the bussing structure from the case, as well as plateaus for connecting the bussing structure to the terminal on the case of the electrochemical cell.

Romero, Antonio L. (Parkton, MD)

2001-06-12T23:59:59.000Z

150

Buffered Electrochemical Polishing of Niobium  

SciTech Connect (OSTI)

The standard preparation of superconducting radio-frequency (SRF) cavities made of pure niobium include the removal of a 'damaged' surface layer, by buffered chemical polishing (BCP) or electropolishing (EP), after the cavities are formed. The performance of the cavities is characterized by a sharp degradation of the quality factor when the surface magnetic field exceeds about 90 mT, a phenomenon referred to as 'Q-drop'. In cavities made of polycrystalline fine grain (ASTM 5) niobium, the Q-drop can be significantly reduced by a low-temperature ({approx} 120 C) 'in-situ' baking of the cavity if the chemical treatment was EP rather than BCP. As part of the effort to understand this phenomenon, we investigated the effect of introducing a polarization potential during buffered chemical polishing, creating a process which is between the standard BCP and EP. While preliminary results on the application of this process to Nb cavities have been previously reported, in this contribution we focus on the characterization of this novel electrochemical process by measuring polarization curves, etching rates, surface finish, electrochemical impedance and the effects of temperature and electrolyte composition. In particular, it is shown that the anodic potential of Nb during BCP reduces the etching rate and improves the surface finish.

Gianluigi Ciovati, Hui Tian, Sean Corcoran

2011-03-01T23:59:59.000Z

151

Solid oxide electrochemical reactor science.  

SciTech Connect (OSTI)

Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

2010-09-01T23:59:59.000Z

152

Regenerative Fuel Cells for Energy Storage  

Broader source: Energy.gov (indexed) [DOE]

1 1 Regenerative Fuel Cells for Energy Storage April 2011 Corky Mittelsteadt April 2011 2 Outline 1. Regenerative Fuel Cells at Giner 2. Regenerative Systems for Energy Storage 1....

153

Molecular-scale measurements of electric fields at electrochemical interfaces.  

SciTech Connect (OSTI)

Spatially resolved measurements of electric fields at electrochemical interfaces would be a critical step toward further understanding and modeling the detailed structure of electric double layers. The goal of this project was to perform proof-of-principle experiments to demonstrate the use of field-sensitive dyes for optical measurements of fields in electrochemical systems. A confocal microscope was developed that provides sensitive detection of the lifetime and high resolution spectra of excited fluorescence for dyes tethered to electrically conductive surfaces. Excited state lifetimes for the dyes were measured and found to be relatively unquenched when linked to indium tin oxide, but strongly quenched on gold surfaces. However, our fluorescence detection is sufficiently sensitive to measure spectra of submonolayer dye coatings even when the fluorescence was strongly quenched. Further work to create dye labeled interfaces on flat, uniform and durable substrates is necessary to make electric field measurements at interfaces using field sensitive dyes.

Hayden, Carl C.; Farrow, Roger L.

2011-01-01T23:59:59.000Z

154

Modeling and simulations of electrical energy storage in electrochemical capacitors  

E-Print Network [OSTI]

spectroscopy (EIS) in microbial fuel cell studies,” Energy &de- velopment of microbial fuel cells: an electrochemical

Wang, Hainan

2013-01-01T23:59:59.000Z

155

Electrochemical oxygen pumps. Final CRADA report.  

SciTech Connect (OSTI)

All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

Carter, J. D.

2009-10-01T23:59:59.000Z

156

Mapping Ionic Currents and Reactivity on the Nanoscale: Electrochemical Strain Microscopy  

SciTech Connect (OSTI)

Solid-state electrochemical processes in oxides underpin a broad spectrum of energy and information storage devices, ranging from Li-ion and Li-air batteries, to solid oxide fuel cells (SOFC) to electroresistive and memristive systems. These functionalities are controlled by the bias-driven diffusive and electromigration transport of mobile ionic species, as well as intricate a set of electrochemical and defect-controlled reactions at interfaces and in bulk. Despite the wealth of device-level and atomistic studies, little is known on the mesoscopic mechanisms of ion diffusion and electronic transport on the level of grain clusters, individual grains, and extended defects. The development of the capability for probing ion transport on the nanometer scale is a key to deciphering complex interplay between structure, functionality, and performance in these systems. Here we introduce Electrochemical Strain Microscopy, a scanning probe microscopy technique based on strong strain-bias coupling in the systems in which local ion concentrations are changed by electrical fields. The imaging capability, as well as time- and voltage spectroscopies analogous to traditional current based electrochemical characterization methods are developed. The reversible intercalation of Li and mapping electrochemical activity in LiCoO2 is demonstrated, illustrating higher Li diffusivity at non-basal planes and grain boundaries. In Si-anode device structure, the direct mapping of Li diffusion at extended defects and evolution of Li-activity with charge state is explored. The electrical field-dependence of Li mobility is studied to determine the critical bias required for the onset of electrochemical transformation, allowing reaction and diffusion processes in the battery system to be separated at each location. Finally, the applicability of ESM for probing oxygen vacancy diffusion and oxygen reduction/evolution reactions is illustrated, and the high resolution ESM maps are correlated with aberration corrected scanning transmission electron microscopy imaging. The future potential for deciphering mechanisms of electrochemical transformations on an atomically-defined single-defect level is discussed.

Kalinin, S.V. (Center for Nanophase Materials Sciences, ORNL) [Center for Nanophase Materials Sciences, ORNL

2010-10-19T23:59:59.000Z

157

Process for electrochemically gasifying coal using electromagnetism  

DOE Patents [OSTI]

A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

Botts, Thomas E. (Markham, VA); Powell, James R. (Shoreham, NY)

1987-01-01T23:59:59.000Z

158

Electrolyte for an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte amorphous lithium phosphorus oxynitride which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN)

1997-01-01T23:59:59.000Z

159

Electrolyte for an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making the same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte amorphous lithium phosphorus oxynitride which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C. 9 figs.

Bates, J.B.; Dudney, N.J.

1997-01-28T23:59:59.000Z

160

Cathode for an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Electrochemical formation of field emitters  

DOE Patents [OSTI]

Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays is disclosed. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area. 12 figs.

Bernhardt, A.F.

1999-03-16T23:59:59.000Z

162

Minimizing Wind Power Producer's Balancing Costs Using Electrochemical Energy Storage: Preprint  

SciTech Connect (OSTI)

This paper examines how electrochemical energy storage can be used to decrease the balancing costs of a wind power producer in the Nordic market. Because electrochemical energy storage is developing in both technological and financial terms, a sensitivity analysis was carried out for the most important variables in the wind-storage hybrid system. The system was studied from a wind power producer's point of view. The main result is that there are no technical limitations to using storage for reducing the balancing costs. However, in terms of economic feasibility, installing hybrid wind-storage systems such as the one studied in this paper faces challenges in both the short and long terms.

Miettinen, J.; Tikka, V.; Lassila, J.; Partanen, J.; Hodge, B. M.

2014-08-01T23:59:59.000Z

163

Bismuth-based electrochemical stripping analysis  

DOE Patents [OSTI]

Method and apparatus for trace metal detection and analysis using bismuth-coated electrodes and electrochemical stripping analysis. Both anodic stripping voltammetry and adsorptive stripping analysis may be employed.

Wang, Joseph

2004-01-27T23:59:59.000Z

164

Sensitive electrochemical detection of horseradish peroxidase...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

devices and point-of-care (POC) diagnosis applications. Citation: Lee AC, G Liu, CK Heng, SN Tan, TM Lim, and Y Lin.2008."Sensitive electrochemical detection of horseradish...

165

High Frequency Electrochemical Nanopolishing of Alpha Titanium  

E-Print Network [OSTI]

manufacturing techniques have been employed traditionally to manufacture microcomponents; however, these techniques would be expensive, cause surface damage, or produce a very rough surface. Electrochemical polishing is capable of machining/polishing any...

Kanchwala, Abbas M

2013-08-07T23:59:59.000Z

166

From corrosion to batteries: Electrochemical interface studies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

From corrosion to batteries: Electrochemical interface studies Thursday, October 18, 2012 - 11:00am SSRL, Bldg. 137, Rm 226 Dr. Frank Uwe Renner Max-Planck-Institut fr...

167

Rechargeable thin-film electrochemical generator  

DOE Patents [OSTI]

An improved electrochemical generator is disclosed. The electrochemical generator includes a thin-film electrochemical cell which is maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of the cell, conducts current into and out of the cell and also conducts thermal energy between the cell and thermally conductive, electrically resistive material disposed on a vessel wall adjacent the conductor. The thermally conductive, electrically resistive material may include an anodized coating or a thin sheet of a plastic, mineral-based material or conductive polymer material. The thermal conductor is fabricated to include a resilient portion which expands and contracts to maintain mechanical contact between the cell and the thermally conductive material in the presence of relative movement between the cell and the wall structure. The electrochemical generator may be disposed in a hermetically sealed housing.

Rouillard, Roger (Beloeil, CA); Domroese, Michael K. (South St. Paul, MN); Hoffman, Joseph A. (Minneapolis, MN); Lindeman, David D. (Hudson, WI); Noel, Joseph-Robert-Gaetan (St-Hubert, CA); Radewald, Vern E. (Austin, TX); Ranger, Michel (Lachine, CA); Sudano, Anthony (Laval, CA); Trice, Jennifer L. (Eagan, MN); Turgeon, Thomas A. (Fridley, MN)

2000-09-15T23:59:59.000Z

168

Microfluidic Actuation Using Electrochemically Generated Bubbles  

E-Print Network [OSTI]

Microfluidic Actuation Using Electrochemically Generated Bubbles Susan Z. Hua,*, Frederick Sachs, Buffalo, New York 14260 Bubble-based actuation in microfluidic applications is attractive owing closing) rate increases with applied voltage, small microfluidic dimensions accelerate bubble deflation

Sachs, Frederick

169

Analysis and Simulation of Electrochemical Energy Systems  

Broader source: Energy.gov (indexed) [DOE]

Power * Informal collaborations with Vince Battaglia, John Kerr, and Venkat Srinivasan (LBNL-BATT) Partners 3 Objectives I. Understand interactions between redox shuttles and solid...

170

Exploratory technology research program for electrochemical energy storage. Annual report for 1995  

SciTech Connect (OSTI)

The US DOE Office of Transportation Technologies provides support for an Electrochemical Energy Storage Program, that includes research and development (R&D) on advanced rechargeable batteries and fuel cells. A major goal of this program is to develop electrochemical power sources suitable for application in electric vehicles (EV`s)and hybrid systems. The program centers on advanced electrochemical systems that offer the potential for high performance and low life- cycle costs, both of which are necessary to permit significant penetration into commercial markets. The DOE Electric Vehicle Technology Program is divided into two project areas: the US Advanced Battery Consortium (USABC) and Advanced battery R&D which includes the Exploratory Technology Research (ETR) program managed by the Lawrence Berkeley National Laboratory. The role of the ETR program is to perform supporting research on the advanced battery systems under development by the USABC and the Sandia Laboratories (SNL) Electric Vehicle Advanced Battery Systems (EVABS) program, and to evaluate new systems with potentially superior performance, durability and/of cost characteristics. The specific goal of the ETR program is to identify the most promising electrochemical technologies and development and scale-up. This report summarizes the research, financial and management activities relevant to the ETR program in CY 1995. This is a continuing program, and reports for prior years have been published; they are listed in this report.The general R&D areas addressed by the program include identification of new electrochemical couples for advanced batteries, determination of technical feasibility of the new couples, improvements in battery components and materials, establishment of engineering principles applicable to electrochemical energy storage and conversion, and the development of fuel cell technology for transportation applications.

Kinoshita, Kim [ed.

1996-06-01T23:59:59.000Z

171

Refractory lining for electrochemical cell  

DOE Patents [OSTI]

Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contcat with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

Blander, Milton (Palos Park, IL); Cook, Glenn M. (Naperville, IL)

1987-01-01T23:59:59.000Z

172

alloy electrochemical behavior: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Journal of the Electrochemical Society Corrosion Behavior of a Novel SiCAl2O3Al Composite Materials Science Websites Summary: The electrochemical behavior of a new class of...

173

Novel electrochemical method for monitoring and predicting localized corrosion.  

E-Print Network [OSTI]

??This PhD research project was conducted to develop new electrochemical methods for studying localized corrosion processes in various environment. An electrochemically integrated multi-electrode array, namely… (more)

Naing Naing Aung.

2008-01-01T23:59:59.000Z

174

SEPARATION OF OVERLAPPED ELECTROCHEMICAL PEAKS USING THE KALMAN FILTER  

E-Print Network [OSTI]

the structure of the electrochemical noise than do the othernoise assumptions can be met in terms of that variable, For electrochemicalnoise ratios often encountered in trace analysis and by the use of electrochemical

Brown, T.F.

2013-01-01T23:59:59.000Z

175

PEM Electrolyzer Incorporating an Advanced  

E-Print Network [OSTI]

PEM Electrolyzer Incorporating an Advanced Low Cost Membrane Monjid Hamdan Giner Electrochemical (Academic)­ Membrane Development Collaborations 3M Fuel Cell Components Program­ NSTF Catalyst & Membrane Entegris ­ Carbon Cell Separators Tokuyama ­ Low-Cost Membrane Prof. R. Zalosh (WPI) ­ Hydrogen Safety

176

ENHANCED ELECTROCHEMICAL PROCESSES IN SUBCRITICAL WATER  

SciTech Connect (OSTI)

This project involved designing and performing preliminary electrochemical experiments in subcritical water. An electrochemical cell with substantially better performance characteristics than presently available was designed, built, and tested successfully. The electrochemical conductivity of subcritical water increased substantially with temperature, e.g., conductivities increased by a factor of 120 when the temperature was increased from 25 to 250 C. Cyclic voltammograms obtained with platinum and nickel demonstrated that the voltage required to produce hydrogen and oxygen from water can be dropped by a factor of three in subcritical water compared to the voltages required at ambient temperatures. However, no enhancement in the degradation of 1,2-dichlorobenzene and the polychlorinated biphenyl 3,3',4,4'-tetrachlorobiphenyl was observed with applied potential in subcritical water.

Steven B. Hawthorne

2000-07-01T23:59:59.000Z

177

Modeling and simulations of electrical energy storage in electrochemical capacitors  

E-Print Network [OSTI]

and carbon nanotubes,” Advanced Energy Materials, vol. 1,carbon nanotubes supercapacitors: Improving both energy andcarbon nanotubes for enhanced electrochemical energy

Wang, Hainan

2013-01-01T23:59:59.000Z

178

Stochastic resonance of electrochemical aperiodic spike trains P. Parmananda,1  

E-Print Network [OSTI]

-output correlation as a function of the noise amplitude. Numerical simulations with an electrochemical model of the electrochemical cell can be found in our previously published work 26 . The imposed external noise was producedStochastic resonance of electrochemical aperiodic spike trains P. Parmananda,1 Gerardo J. Escalera

Showalter, Kenneth

179

Application of the inverse wavelet transform on electrochemical current signals  

E-Print Network [OSTI]

, Frequency distribution charts, Frequencies Paper type Research paper 1. Introduction Electrochemical noise, 1968). Two main methods can be used to analyze electrochemical noise, namely sequence of electrochemical noise signals due to their dynamic nature. The wavelet transform was first applied to noise

Volinsky, Alex A.

180

Electrochemical apparatus comprising modified disposable rectangular cuvette  

DOE Patents [OSTI]

Electrochemical apparatus includes a disposable rectangular cuvette modified with at least one hole through a side and/or the bottom. Apparatus may include more than one cuvette, which in practice is a disposable rectangular glass or plastic cuvette modified by drilling the hole(s) through. The apparatus include two plates and some means of fastening one plate to the other. The apparatus may be interfaced with a fiber optic or microscope objective, and a spectrometer for spectroscopic studies. The apparatus are suitable for a variety of electrochemical experiments, including surface electrochemistry, bulk electrolysis, and flow cell experiments.

Dattelbaum, Andrew M; Gupta, Gautam; Morris, David E

2013-09-10T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Tunable Electrochemical Properties of Fluorinated Graphene  

SciTech Connect (OSTI)

The structural and electrochemical properties of fluorinated graphene have been investigated by using a series of graphene fluorides (CFx, x=0.47, 0.66, 0.89). Fluorinated graphene exhibited high capacity retentions of 75-81% of theoretical capacity at moderate rates as cathode materials for primary lithium batteries. Specifically, CF0.47 maintained a capacity of 356 mAhg-1 at a 5C rate, superior to that of traditional fluorinated graphite. The discharged graphene fluorides also provide an electrochemical tool to probe the chemical bonding on the parent graphene substrate.

Meduri, Praveen; Chen, Honghao; Xiao, Jie; Martinez, Jayson J.; Carlson, Thomas J.; Zhang, Jiguang; Deng, Zhiqun

2013-06-18T23:59:59.000Z

182

Control oriented 1D electrochemical model of lithium ion battery Kandler A. Smith a  

E-Print Network [OSTI]

dynamics (i.e. state of charge). � 2007 Elsevier Ltd. All rights reserved. Keywords: Lithium ion battery electrochemical system dynamics [3,4]. Empirical battery models are often favored for their low order (2­5 states and Wang show that a hybrid electric vehicle (HEV) cell may become solid state diffusion limited in sec

183

Int. J. Electrochem. Sci., 8 (2013) 859 -871 International Journal of  

E-Print Network [OSTI]

V between the biotic medium with reference to abiotic medium (control). These positive polarization shifts and associated structures that synergistically altered the electrochemical environment of the system changes in the aqueous environment (such as - alter the concentration of the electrolyte, components, p

184

Safeguards and security modeling for electrochemical plants  

SciTech Connect (OSTI)

Safeguards and security design for reprocessing plants can lead to excessive costs if not incorporated early in the design process. The design for electrochemical plants is somewhat uncertain since these plants have not been built at a commercial scale in the past. The Separation and Safeguards Performance Model (SSPM), developed at Sandia National Laboratories, has been used for safeguards design and evaluation for multiple reprocessing plant types. The SSPM includes the following capabilities: -) spent fuel source term library, -) mass tracking of elements 1-99 and bulk solid/liquids, -) tracking of heat load and activity, -) customisable measurement points, -) automated calculation of ID and error propagation, -) alarm conditions and statistical tests, and -) user-defined diversion scenarios. Materials accountancy and process monitoring data can provide more timely detection of material loss specifically to protect against the insider threat. While the SSPM is capable of determining detection probabilities and examining detection times for material loss scenarios, it does not model the operations or spatial effects for a plant design. The STAGE software was chosen to model the physical protection system. STAGE provides a framework to create end-to-end scalable force-on-force combat simulations. It allows for a complete 3D model of a facility to be designed along with the design of physical protection elements. This software, then, can be used to model operations and response for various material loss scenarios. The future integration of the SSPM model data with the STAGE software will provide a more complete analysis of diversion scenarios to assist plant designers.

Cipiti, B.B.; Duran, F.A.; Mendoza, L.A.; Parks, M.J.; Dominguez, D.; Le, T.D. [Sandia National Laboratories, PO Box 5800 MS 0747, Albuquerque, NM 87185 (United States)

2013-07-01T23:59:59.000Z

185

Exploratory technology research program for electrochemical energy storage, annual report for 1997  

SciTech Connect (OSTI)

The US Department of Energy`s (DOE) Office of Transportation Technologies provides support for an Electrochemical Energy Storage Program, that includes research and development on advanced rechargeable batteries. A major goal of this program is to develop electrochemical power sources suitable for application in electric vehicles (EVs) and hybrid systems. The program centers on advanced electrochemical systems that offer the potential for high performance and low life-cycle costs, both of which are necessary to permit significant penetration into commercial markets. The DOE Electric Vehicle Technology Program is divided into two project areas: the US Advanced Battery Consortium (USABC) and Advanced Battery R and D which includes the Exploratory Technology Research (ETR) Program managed by the Lawrence Berkeley National Laboratory (LBNL). The specific goal of the ETR Program is to identify the most promising electrochemical technologies and transfer them to the USABC, the battery industry and/or other Government agencies for further development and scale-up. This report summarizes the research, financial and management activities relevant to the ETR Program in CY 1997. This is a continuing program, and reports for prior years have been published; they are listed at the end of this Executive Summary. The general R and D areas addressed by the program include identification of new electrochemical couples for advanced batteries, determination of technical feasibility of the new couples, improvements in battery components and materials, and establishment of engineering principles applicable to electrochemical energy storage. Major emphasis is given to applied research which will lead to superior performance and lower life-cycle costs.

Kinoshita, K. [ed.

1998-06-01T23:59:59.000Z

186

Exploratory Technology Research Program for electrochemical energy storage: Annual report for 1993  

SciTech Connect (OSTI)

The U.S. Department of Energy`s Office of Propulsion Systems provides support for an Electrochemical Energy Storage Program, that includes research and development (R&D) on advanced rechargeable batteries and fuel cells. A major goal of this program is to develop electrochemical power sources suitable for application in electric vehicles (EVs). The program centers on advanced systems that offer the potential for high performance and low life-cycle costs, both of which are necessary to permit significant penetration into commercial markets. The DOE Electrochemical Energy Storage Program is divided into two projects: the Electric Vehicle Advanced Battery Systems (EVABS) Development Program and the Exploratory Technology Research (ETR) Program. The EVABS Program management responsibility has been assigned to Sandia National Laboratories (SNL); Lawrence Berkeley Laboratory (LBL) is responsible for management of the ETR Program. The EVABS and ETR Programs include an integrated matrix of R&D efforts designed to advance progress on selected candidate electrochemical systems. The United States Advanced Battery Consortium (USABC), a tripartite undertaking between DOE, the U.S. automobile manufacturers and the Electric Power Research Institute (EPRI), was formed in 1991 to accelerate the development of advanced batteries for consumer EVs. The role of the FIR Program is to perform supporting research on the advanced battery systems under development by the USABC and EVABS Program, and to evaluate new systems with potentially superior performance, durability and/or cost characteristics. The specific goal of the ETR Program is to identify the most promising electrochemical technologies and transfer them to the USABC, the battery industry and/or the EVABS Program for further development and scale-up. This report summarizes the research, financial and management activities relevant to the ETR Program in CY 1993.

Kinoshita, K. [ed.

1994-09-01T23:59:59.000Z

187

ORIGINAL PAPER Improvement of the electrochemical properties  

E-Print Network [OSTI]

-doped polycrystalline diamond electrodes deposited on tungsten wires using ethanol Reinaldo F. Teófilo & Helder J # Springer-Verlag 2007 Abstract The electrochemical properties of boron-doped diamond (BDD) polycrystalline applications. Keywords Boron-doped diamond electrodes . Ethanol . Cathodic pretreatment . EIS Introduction

Ferreira, Márcia M. C.

188

Titanium Carbide Bipolar Plate for Electrochemical Devices  

SciTech Connect (OSTI)

Titanium carbide comprises a corrosion resistant, electrically conductive, non-porous bipolar plate for use in an electrochemical device. The process involves blending titanium carbide powder with a suitable binder material, and molding the mixture, at an elevated temperature and pressure.

LaConti, Anthony B.; Griffith, Arthur E.; Cropley, Cecelia C.; Kosek, John A.

1998-05-08T23:59:59.000Z

189

Method of constructing an improved electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ)

1984-10-09T23:59:59.000Z

190

Development of Microfluidic Devices Incorporating Electrochemical Detection  

E-Print Network [OSTI]

Development of Microfluidic Devices Incorporating Electrochemical Detection Anne Regel Submitted to the Department of Chemistry and the Graduate School of the University of Kansas in partial fulfillment of the requirements for the degree... _______________________________ Karen Nordheden Dissertation Defense: August 21, 2013 ii The Dissertation Committee for Anne Regel certifies that this is the approved version of the following dissertation: Development of Microfluidic Devices Incorporating...

Regel, Anne

2014-05-31T23:59:59.000Z

191

Minimizing electrode contamination in an electrochemical cell  

SciTech Connect (OSTI)

An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

2014-12-09T23:59:59.000Z

192

Exploratory Technology Research Program for Electrochemical Energy Storage. Annual report, 1992  

SciTech Connect (OSTI)

This report summarizes the progress made by the Exploratory Technology Research (ETR) Program for Electrochemical Energy Storage during calendar year 1992. The primary objective of the ETR Program, which is sponsored by the US Department of Energy (DOE) and managed by Lawrence Berkeley Laboratory (LBL), is to identify electrochemical technologies that can satisfy stringent performance, durability and economic requirements for electric vehicles (EVs). The ultimate goal is to transfer the most-promising electrochemical technologies to the private sector or to another DOE program (e.g., SNL`s Electric Vehicle Advanced Battery Systems Development Program, EVABS) for further development and scale-up. Besides LBL, which has overall responsibility for the ETR Program, LANL and BNL have participated in the ETR Program by providing key research support in several of the program elements. The ETR Program consists of three major elements: Exploratory Research; Applied Science Research; and Air Systems Research. The objectives and the specific battery and electrochemical systems addressed by each program element are discussed in the following sections, which also include technical summaries that relate to the individual programs. Financial information that relates to the various programs and a description of the management activities for the ETR Program are described in the Executive Summary.

Kinoshita, K. [ed.

1993-10-01T23:59:59.000Z

193

SEPARATION OF OVERLAPPED ELECTROCHEMICAL PEAKS USING THE KALMAN FILTER  

SciTech Connect (OSTI)

A major limitation in the use of electrochemical techniques for the quantitative analysis of mixtures is the difficulty of resolving overlapped peaks. This problem is further complicated by the low signal-to-noise ratios often encountered in trace analysis and by the use of electrochemical techniques that produce broad, asymmetric waveforms. This paper demonstrates the use of the Kalman Filter for multi-component analysis of linear sweep voltammograms. Even with the broad, asymmetric LSV waveform, synthetic data runs show that a peak separation of as little as 2.5 mV is sufficient for peak deconvolution in the presence of random noise. Besides separating overlapped peaks, the methods also filters the noise from the signal and can be used to separate the capacitive current component from the faradaic current component. The method is validated further using the Cd(II)/In(III) and Cd(II)/In(III)/Pb(II) systems which show peak separations of 40 to 200 mV. The use of the techniques with two other voltammetric waveforms is also demonstrated.

Brown, T.F.; Brown, S.D.

1981-01-01T23:59:59.000Z

194

Evaluation of oilfield corrosion inhibitors by electrochemical impedance spectroscopy (EIS)  

SciTech Connect (OSTI)

The performance of commercially available oilfield corrosion inhibitors has been evaluated by electrochemical impedance spectroscopy (EIS) in CO{sub 2} saturated 5% sodium chloride solution. The results demonstrate that EIS is a feasible method for ranking oilfield corrosion inhibitor performance, and the inhibitors exhibit inhibition through different mechanisms. EIS can provide information on the inhibited film growth, and generate the parameters which are specific to a particular corrosion inhibition system. It is found that the high breakpoint frequency at 45{degree} phase angle has excellent correlation with the corrosion rate in the inhibited system. The identification of this correlation is significant because there are advantages associated with measuring this parameter. A patent application has been filed for this discovery.

Chen, H.J. [Chevron Petroleum Technology Co., La Habra, CA (United States)

1994-12-31T23:59:59.000Z

195

Electrochemically controlled charging circuit for storage batteries  

DOE Patents [OSTI]

An electrochemically controlled charging circuit for charging storage batteries is disclosed. The embodiments disclosed utilize dc amplification of battery control current to minimize total energy expended for charging storage batteries to a preset voltage level. The circuits allow for selection of Zener diodes having a wide range of reference voltage levels. Also, the preset voltage level to which the storage batteries are charged can be varied over a wide range.

Onstott, E.I.

1980-06-24T23:59:59.000Z

196

Sealed joint structure for electrochemical device  

DOE Patents [OSTI]

Several members make up a joint in a high-temperature electrochemical device, wherein the various members perform different functions. The joint is useful for joining multiple cells (generally tubular modules) of an electrochemical device to produce a multi-cell segment-in-series stack for a solid oxide fuel cell, for instance. The joint includes sections that bond the joining members to each other; one or more seal sections that provide gas-tightness, and sections providing electrical connection and/or electrical insulation between the various joining members. A suitable joint configuration for an electrochemical device has a metal joint housing, a first porous electrode, a second porous electrode, separated from the first porous electrode by a solid electrolyte, and an insulating member disposed between the metal joint housing and the electrolyte and second electrode. One or more brazes structurally and electrically connects the first electrode to the metal joint housing and forms a gas tight seal between the first electrode and the second electrode.

Tucker, Michael C; Jacobson, Craig P; De Jonghe, Lutgard C; Visco, Steven J

2013-05-21T23:59:59.000Z

197

High temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Corrosion occurs in the high temperature sections of energy production plants due to a number of factors: ash deposition, coal composition, thermal gradients, and low NOx conditions, among others. Electrochemical corrosion rate (ECR) probes have been shown to operate in high temperature gaseous environments that are similar to those found in fossil fuel combustors. ECR probes are rarely used in energy production plants at the present time, but if they were more fully understood, corrosion could become a process variable at the control of plant operators. Research is being conducted to understand the nature of these probes. Factors being considered are values selected for the Stern-Geary constant, the effect of internal corrosion, and the presence of conductive corrosion scales and ash deposits. The nature of ECR probes will be explored in a number of different atmospheres and with different electrolytes (ash and corrosion product). Corrosion rates measured using an electrochemical multi-technique capabilities instrument will be compared to those measured using the linear polarization resistance (LPR) technique. In future experiments, electrochemical corrosion rates will be compared to penetration corrosion rates determined using optical profilometry measurements.

Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Ziomek-Moroz, M.

2005-09-01T23:59:59.000Z

198

Electrochemical Polishing Applications and EIS of a Vitamin B{sub 4}-Based Ionic Liquid  

SciTech Connect (OSTI)

Modern particle accelerators require minimal interior surface roughness for Niobium superconducting radio frequency (SRF) cavities. Polishing of the Nb is currently achieved via electrochemical polishing with concentrated mixtures of sulfuric and hydrofluoric acids. This acid-based approach is effective at reducing the surface roughness to acceptable levels for SRF use, but due to acid-related hazards and extra costs (including safe disposal of used polishing solutions), an acid-free method would be preferable. This study focuses on an alternative electrochemical polishing method for Nb, using a novel ionic liquid solution containing choline chloride, also known as Vitamin B{sub 4} (VB{sub 4}). Potentiostatic electrochemical impedance spectroscopy (EIS) was also performed on the VB4-based system. Nb polished using the VB4-based method was found to have a final surface roughness comparable to that achieved via the acid-based method, as assessed by atomic force microscopy (AFM). These findings indicate that acid-free VB{sub 4}-based electrochemical polishing of Nb represents a promising replacement for acid-based methods of SRF cavity preparation.

Wixtrom, Alex I. [Christopher Newport University, Newport News, VA (United States); Buhler, Jessica E. [Christopher Newport University, Newport News, VA (United States); Reece, Charles E. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Abdel-Fattah, Tarek M. [Christopher Newport University, Newport News, VA (United States)

2013-01-01T23:59:59.000Z

199

High temperature electrochemical corrosion rate probes for combustion environments  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in an air plus water vapor and a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 200? to 700?C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature and process environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Eden, David A. (Intercorr International Inc.); Kane, Russell D. (Intercorr International Inc.); Eden, Dawn C. (Intercorr International Inc.)

2004-01-01T23:59:59.000Z

200

Method of determining methane and electrochemical sensor therefor  

DOE Patents [OSTI]

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about about 1.4 volts versus R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, Solomon (Hinsdale, IL); Otagawa, Takaaki (Westmont, IL); Stetter, Joseph R. (Naperville, IL)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for in Situ Characterization of Mixed Wastes  

SciTech Connect (OSTI)

This research effort aims at developing a portable analytical system for fast, sensitive, and inexpensive, on-site monitoring of toxic transition metals and radionuclides in contaminated DOE Sites. The portable devices will be based on Microscale Total Analytical systems ( -TAS) or ''Lab-on-a-chip'' in combination with electrochemical (stripping-voltammetric) sensors. The resulting microfluidics/electrochemical sensor system would allow testing for toxic metals to be performed more rapidly, inexpensively, and reliably in a field setting. Progress Summary/Accomplishments: This report summarizes the ASU activity over the second year of the project. In accordance to our original objectives our studies have focused on various fundamental and practical aspects of sensing and microchip devices for monitoring metal contaminants. As described in this section, we have made a substantial progress, and introduced effective routes for improving the on-site detection of toxic metals and for interfacing microchips with the real world.

Wang, Joseph

2006-06-01T23:59:59.000Z

202

accompanying electrochemical intercalation: Topics by E-print...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Double Layer Formation and Cation Pseudo-Intercalation Supercapacitor Carbon Nanotube Composite Electrodes With Enhanced Electrochemical Performances. Open Access Theses and...

203

Electrochemical Studies of Packed Iron Powder Electrodes: Effects...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Packed Iron Powder Electrodes: Effects of Common Constituents of Natural Waters on Corrosion Electrochemical Studies of Packed Iron Powder Electrodes: Effects of Common...

204

Electrochemical Branched-DNA Assay for Polymerase Chain Reaction...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Branched-DNA Assay for Polymerase Chain Reaction-Free Detection and Quantification of Oncogenes in Messenger RNA Electrochemical Branched-DNA Assay for Polymerase Chain...

205

advanced electrochemical oxidation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

??Three dimensional, conductive, macroporous nickel foams and mesoporous carbon aerogels have been utilized as skeletal supports for an electrochemically assisted deposition...

206

Vehicle Technologies Office Merit Review 2014: Electrochemical Performance Testing  

Broader source: Energy.gov [DOE]

Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrochemical...

207

Modeling and simulations of electrical energy storage in electrochemical capacitors  

E-Print Network [OSTI]

3D nanoarchitec- tures for energy storage and conversion,”functionality in energy storage materials and devices byto electrochemical energy storage in TiO 2 (anatase)

Wang, Hainan

2013-01-01T23:59:59.000Z

208

Electrochemical Characterization of Voltage Fade in LMR-NMC cells...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Electrochemical Characterization of Voltage Fade in LMR-NMC cells 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

209

Electrochemical Sensors for the Detection of Lead and Other Toxic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sensors for the Detection of Lead and Other Toxic Heavy Metals: The Next Generation of Personal Exposure Electrochemical Sensors for the Detection of Lead and Other Toxic Heavy...

210

Cell structure for electrochemical devices and method of making same  

DOE Patents [OSTI]

An electrochemical device comprising alternating layers of positive and negative electrodes separated from each other by separator layers. The electrode layers extend beyond the periphery of the separator layers providing superior contact between the electrodes and battery terminals, eliminating the need for welding the electrode to the terminal. Electrical resistance within the battery is decreased and thermal conductivity of the cell is increased allowing for superior heat removal from the battery and increased efficiency. Increased internal pressure within the battery can be alleviated without damaging or removing the battery from service while keeping the contents of the battery sealed off from the atmosphere by a pressure release system. Nonoperative cells within a battery assembly can also be removed from service by shorting the nonoperative cell thus decreasing battery life.

Kaun, Thomas D.

2007-03-27T23:59:59.000Z

211

Electrochemical Corrosion Testing of Borated Stainless Steel Alloys  

SciTech Connect (OSTI)

The Department of Energy Office of Civilian Radioactive Waste Management has specified borated stainless steel manufactured to the requirements of ASTM A 887-89, Grade A, UNS S30464, to be the material used for the fabrication of the fuel basket internals of the preliminary transportation, aging, and disposal canister system preliminary design. The long-term corrosion resistance performance of this class of borated materials must be verified when exposed to expected YMP repository conditions after a waste package breach. Electrochemical corrosion tests were performed on crevice corrosion coupons of Type 304 B4 and Type 304 B5 borated stainless steels exposed to single postulated in-package chemistry at 60°C. The results show low corrosion rates for the test period

lister, tedd e; Mizia, Ronald E

2007-09-01T23:59:59.000Z

212

Electrochemical Corrosion Testing of Borated Stainless Steel Alloys  

SciTech Connect (OSTI)

The Department of Energy Office of Civilian Radioactive Waste Management has specified borated stainless steel manufactured to the requirements of ASTM A 887-89, Grade A, UNS S30464, to be the material used for the fabrication of the fuel basket internals of the preliminary transportation, aging, and disposal canister system preliminary design. The long-term corrosion resistance performance of this class of borated materials must be verified when exposed to expected YMP repository conditions after a waste package breach. Electrochemical corrosion tests were performed on crevice corrosion coupons of Type 304 B4 and Type 304 B5 borated stainless steels exposed to single postulated in-package chemistry at 60°C. The results show low corrosion rates for the test period

lister, tedd e; Mizia, Ronald E

2007-05-01T23:59:59.000Z

213

MEMS Materials and Temperature Sensors for Down Hole Geothermal System Monitoring  

E-Print Network [OSTI]

Journal of Microelectromechanical Systems, 5(4), 1996. [25]bon for microelectromechanical systems and electrochemicalJournal of Microelectromechanical Systems, 22(1), 2013. [98

Wodin-Schwartz, Sarah

2013-01-01T23:59:59.000Z

214

High-Power Electrochemical Storage Devices and Plug-in Hybrid...  

Broader source: Energy.gov (indexed) [DOE]

High-Power Electrochemical Storage Devices and Plug-in Hybrid Electric Vehicle Battery Development High-Power Electrochemical Storage Devices and Plug-in Hybrid Electric Vehicle...

215

Schemes for the use of conducting polymers as active materials in electrochemical supercapacitors  

SciTech Connect (OSTI)

The development of a novel conducting polymer based system for use in electrochemical capacitors is described. This system utilizes a new conducting polymer, poly-3-(4-fluorophenyl)-thiophene (PFPT), that can be reversibly n- and p-doped to high charge density. The electrochemical n-dopability of this material can be further improved by cycling in acetonitrile solution that contains a new electrolyte, tetramethylammonium trifluoromethanesulfonate (Me{sub 4}NCF{sub 3}SO{sub 3}). We discuss these improvements in n-dopability in terms of potential electronic and steric influences. We believe that the substituent fluorophenyl group does not communicate with the polythiophene backbone through resonance, and conclude that the ability to n-dope PFPT to high charge density may occur as a result of electron transfer reactions from the conducting polymer backbone into the substituent. This new system for electrochemical capacitors provides the best achievable performance from conducting polymers and generates high energy and power densities that are comparable with noble metal oxide systems, potentially at a fraction of the cost.

Rudge, A.; Davey, J.; Gottesfeld, S. [Los Alamos National Lab., NM (United States); Ferraris, J.P. [Texas Univ., Richardson, TX (United States). Dept. of Chemistry

1993-05-01T23:59:59.000Z

216

Electrochemical mercerization, souring, and bleaching of textiles  

DOE Patents [OSTI]

Economical, pollution-free treatment of textiles occurs in a low voltage electrochemical cell that mercerizes (or scours), sours, and optionally bleaches without effluents and without the purchase of bulk caustic, neutralizing acids, or bleaches. The cell produces base in the cathodic chamber for mercerization and an equivalent amount of acid in the anodic chamber for neutralizing the fabric. Gas diffusion electrodes are used for one or both electrodes and may simultaneously generate hydrogen peroxide for bleaching. The preferred configuration is a stack of bipolar electrodes, in which one or both of the anode and cathode are gas diffusion electrodes, and where no hydrogen gas is evolved at the cathode.

Cooper, John F. (Oakland, CA)

1995-01-01T23:59:59.000Z

217

Electrochemical Biosensors: Recommended Definitions and Classification  

E-Print Network [OSTI]

of the general signi®cance of the word, a transducer provides bidirectional signal transfer (non-electrical to electrical and vice versa); the transducer part of a sensor is also called a detector, sensor or electrode, but the term transducer is preferred... with an electrochemical transducer (Table 2). It is considered to be a chemically modi®ed electrode (CME) [4,5] as electronic conducting, semiconducting or ionic conducting material is coated with a biochemical ®lm. A biosensor is an integrated receptor±transducer device...

Wilson, George S.; Thé venot, Daniel R.; Toth, Klara; Durst, Richard A.

1999-01-01T23:59:59.000Z

218

Solid oxide electrochemical cell fabrication process  

DOE Patents [OSTI]

A method to form an electrochemical cell (12) is characterized by the steps of thermal spraying stabilized zirconia over a doped lanthanum manganite air electrode tube (14) to provide an electrolyte layer (15), coating conductive particles over the electrolyte, pressurizing the outside of the electrolyte layer, feeding halide vapors of yttrium and zirconium to the outside of the electrolyte layer and feeding a source of oxygen to the inside of the electrolyte layer, heating to cause oxygen reaction with the halide vapors to close electrolyte pores if there are any and to form a metal oxide coating on and between the particles and provide a fuel electrode (16).

Dollard, Walter J. (Churchill Borough, PA); Folser, George R. (Lower Burrell, PA); Pal, Uday B. (Cambridge, MA); Singhal, Subhash C. (Murrysville, PA)

1992-01-01T23:59:59.000Z

219

Electrochemical Energy Storage | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series toESnet4: Networking for the‹ See allElectrochemical Energy Storage Apr

220

Electrochemical aspects of stress-corrosion cracking in. cap alpha. -brass  

SciTech Connect (OSTI)

This paper considers a number of aspects of the stress-corrosion cracking of brass from the point of view of the localized electrochemical processes occurring at the tip of a propagating crack. The principal system examined is the intergranular SCC of 70-30 brass in near-neutral ammoniacal solutions, for which a detailed mechanism is developed. In addition, the effects of nitrite ions in promoting SCC of both brass and copper are considered.

Burstein, G T; Newman, R C

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Exploratory technology research program for electrochemical energy storage. Annual report for 1996  

SciTech Connect (OSTI)

The U.S. Department of Energy`s Office of Transportation Technologies provides support for an Electrochemical Energy Storage Program, that includes research and development on advanced rechargeable batteries and fuel cells. A major goal of this program is to develop electrochemical power sources suitable for application in electric vehicles (EVs) and hybrid systems. The program centers on advanced electrochemical systems that offer the potential for high performance and low life-cycle costs, both of which are necessary to permit significant penetration into commercial markets. The DOE Electric Vehicle Technology Program is divided into two project areas: the United States Advanced Battery Consortium (USABC) and Advanced Battery R&D which includes the Exploratory Technology Research (ETR) Program managed by the Lawrence Berkeley National Laboratory (LBNL). The USABC, a tripartite undertaking between DOE, the U.S. automobile manufacturers and the Electric Power Research Institute (EPRI), was formed in 1991 to accelerate the development of advanced batteries for EVs. In addition, DOE is actively involved in the Partnership for a New Generation of Vehicles (PNGV) Program which seeks to develop passenger vehicles with a range equivalent to 80 mpg of gasoline. The role of the ETR Program is to perform supporting research on the advanced battery systems under development by the USABC and the PNGV Program, and to evaluate new systems with potentially superior performance, durability and/or cost characteristics. The specific goal of the ETR Program is to identify the most promising electrochemical technologies and transfer them to the USABC, the battery industry and/or other Government agencies for further development and scale-up. This report summarizes the research, financial and management activities relevant to the ETR Program in CY 1996. This is a continuing program, and reports for prior years have been published; they are listed at the end of this Executive Summary.

Kinoshita, K. [ed.

1997-06-01T23:59:59.000Z

222

Electrochemical NOx Sensor for Monitoring Diesel Emissions  

SciTech Connect (OSTI)

Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

Woo, L Y; Glass, R S

2008-11-14T23:59:59.000Z

223

Argonne Electrochemical Technology Program Sulfur removal from reformate  

E-Print Network [OSTI]

Argonne Electrochemical Technology Program Sulfur removal from reformate Xiaoping Wang, Theodore Krause, and Romesh Kumar Chemical Engineering Division Argonne National Laboratory Hydrogen, Fuel Cells, and Infrastructure Technologies 2003 Merit Review Berkeley, CA May 19-22, 2003 #12;Argonne Electrochemical Technology

224

The Electrochemical Society Interface Fall 2006 MARK ORAZEM  

E-Print Network [OSTI]

The Electrochemical Society Interface · Fall 2006 MARK ORAZEM For his contributions distinguished service to the educa- tional and research dissemination missions of The Electrochemical Society. Mark Orazem obtained his BS and MS degrees from Kansas State University and his doctorate in 1983 from

Fang, Yuguang "Michael"

225

DOI: 10.1002/cphc.200900924 Structural, Compositional and Electrochemical  

E-Print Network [OSTI]

DOI: 10.1002/cphc.200900924 Structural, Compositional and Electrochemical Characterization of Pt. It is this context that we have carried out studies on the interfacial and electrochemical properties of Pt­Co alloy phase diagram of the alloy film marked by a sub- stantial divergence between the composition

Goodman, Wayne

226

A Low Noise Readout Circuit for Integrated Electrochemical Biosensor Arrays  

E-Print Network [OSTI]

A Low Noise Readout Circuit for Integrated Electrochemical Biosensor Arrays Jichun Zhang, Nicholas 48823, USA {zhangjic, tromblyn, mason}@egr.msu.edu Abstract This paper presents a low noise electrochemical interface circuit that is tuned to the needs of protein-based biosensor arrays and compatible

Mason, Andrew

227

J.M. Tarascon, et al. , Electrochemical energy storage  

E-Print Network [OSTI]

opportunities for Electrochemical Energy Storage (EES) Mass storage (MW): Which technology? Compressed air #12J.M. Tarascon, et al. , Electrochemical energy storage for renewable energies CNRS, Jeudi 3 Octobre 28 TW Renewable EnergiesRenewable EnergiesRenewable Energies WHY ENERGY STORAGE ? Billionsdebarils

Canet, Léonie

228

JV Task-121 Electrochemical Synthesis of Nitrogen Fertilizers  

SciTech Connect (OSTI)

An electrolytic renewable nitrogen fertilizer process that utilizes wind-generated electricity, N{sub 2} extracted from air, and syngas produced via the gasification of biomass to produce nitrogen fertilizer ammonia was developed at the University of North Dakota Energy & Environmental Research Center. This novel process provides an important way to directly utilize biosyngas generated mainly via the biomass gasification in place of the high-purity hydrogen which is required for Haber Bosch-based production of the fertilizer for the production of the widely used nitrogen fertilizers. Our preliminary economic projection shows that the economic competitiveness of the electrochemical nitrogen fertilizer process strongly depends upon the cost of hydrogen gas and the cost of electricity. It is therefore expected the cost of nitrogen fertilizer production could be considerably decreased owing to the direct use of cost-effective 'hydrogen-equivalent' biosyngas compared to the high-purity hydrogen. The technical feasibility of the electrolytic process has been proven via studying ammonia production using humidified carbon monoxide as the hydrogen-equivalent vs. the high-purity hydrogen. Process optimization efforts have been focused on the development of catalysts for ammonia formation, electrolytic membrane systems, and membrane-electrode assemblies. The status of the electrochemical ammonia process is characterized by a current efficiency of 43% using humidified carbon monoxide as a feedstock to the anode chamber and a current efficiency of 56% using high-purity hydrogen as the anode gas feedstock. Further optimization of the electrolytic process for higher current efficiency and decreased energy consumption is ongoing at the EERC.

Junhua Jiang; Ted Aulich

2008-11-30T23:59:59.000Z

229

Transition from supercapacitor to battery behavior in electrochemical energy storage  

SciTech Connect (OSTI)

In this paper the storage of electrochemical energy in battery, supercapacitor, and double-layer capacitor devices is considered. A comparison of the mechanisms and performance of such systems enables their essential features to be recognized and distinguished, and the conditions for transition between supercapacitor and battery behavior to be characterized. Supercapacitor systems based on two-dimensional underpotential deposition reactions are highly reversible and their behavior arises from the pseudocapaccitance associated with potential-dependence of two-dimensional coverage of electroactive adatoms on an electrode substrate surface. Such capacitance can be 10-100 times the double-layer capacitance of the same electrode area. An essential fundamental difference from battery behavior arises because, in such systems, the chemical and associated electrode potentials are a continuous function of degree of charge, unlike the thermodynamic behavior of single-phase battery reactants. Quai-two-dimensional systems, such as hyperextended hydrous RuP{sub 2}, also exhibit large pseudocapacitance which, in this case, is associated with a sequence of redox redox processes that are highly reversible.

Conway, B.E. (Ottawa Univ., ON (Canada). Dept. of Chemistry)

1991-06-01T23:59:59.000Z

230

Do not forget the electrochemical characteristics of the Membrane-Electrode-Assembly when designing a PEMFC stack  

E-Print Network [OSTI]

, France I Introduction: Principle of Fuel Cells I.1 Fuel Cell system I.2 Proton Exchange Membrane Fuel Cell (PEMFC) I.3 Components of a PEM Elementary Cell (Membrane, Catalysts, GDL) I.4 Electrical Characterization of the MEA by Electrochemical Spectroscopy (EIS) II.4 Optimization of the Membrane

Paris-Sud XI, Université de

231

A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries  

E-Print Network [OSTI]

1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

232

Cr-Ga-N materials for negative electrodes in Li rechargeable batteries : structure, synthesis and electrochemical performance  

E-Print Network [OSTI]

Electrochemical performances of two ternary compounds (Cr2GaN and Cr3GaN) in the Cr-Ga-N system as possible future anode materials for lithium rechargeable batteries were studied. Motivation for this study was dealt in ...

Kim, Miso

2007-01-01T23:59:59.000Z

233

Sensor apparatus using an electrochemical cell  

DOE Patents [OSTI]

A novel technology for sensing mechanical quantities such as force, stress, strain, pressure and acceleration has been invented. This technology is based on a change in the electrochemically generated voltage (electromotive force) with application of force, stress, strain, pressure or acceleration. The change in the voltage is due to a change in the internal resistance of the electrochemical cell with a change in the relative position or orientation of the electrodes (anode and cathode) in the cell. The signal to be detected (e.g. force, stress, strain, pressure or acceleration) is applied to one of the electrodes to cause a change in the relative position or orientation between the electrodes. Various materials, solid, semisolid, gel, paste or liquid can be utilized as the electrolyte. The electrolyte must be an ion conductor. The examples of solid electrolytes include specific polymer conductors, polymer composites, ion conducting glasses and ceramics. The electrodes are made of conductors such as metals with dissimilar electronegativities. Significantly enhanced sensitivities, up to three orders of magnitude higher than that of comparable commercial sensors, are obtained. The materials are substantially less expensive than commercially used materials for mechanical sensors.

Thakur, Mrinal (1309 Gatewood Dr., Apt. 1703, Auburn, AL 36830)

2002-01-01T23:59:59.000Z

234

SURFACE SEGREGATION STUDIES OF SOFC CATHODES: COMBINING SOFT X-RAYS AND ELECTROCHEMICAL IMPEDENCE SPECTROSCOPY  

SciTech Connect (OSTI)

A system to grow heteroepitaxial thin-films of solid oxide fuel cell (SOFC) cathodes on single crystal substrates was developed. The cathode composition investigated was 20% strontium-doped lanthanum manganite (LSM) grown by pulsed laser deposition (PLD) on single crystal (111) yttria-stabilized zirconia (YSZ) substrates. By combining electrochemical impedance spectroscopy (EIS) with x-ray photoemission spectroscopy (XPS) and x-ray absorption spectroscopy XAS measurements, we conclude that electrically driven cation migration away from the two-phase gas-cathode interface results in improved electrochemical performance. Our results provide support to the premise that the removal of surface passivating phases containing Sr2+ and Mn2+, which readily form at elevated temperatures even in O2 atmospheric pressures, is responsible for the improved cathodic performance upon application of a bias.

Miara, Lincoln J.; Piper, L.F.J.; Davis, Jacob N.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Basu, Soumendra; Smith, K. E.; Pal, Uday B.; Gopalan, Srikanth

2010-12-01T23:59:59.000Z

235

Real space mapping of ionic diffusion and electrochemical activity in energy storage and conversion materials  

DOE Patents [OSTI]

A method and system for probing mobile ion diffusivity and electrochemical reactivity on a nanometer length scale of a free electrochemically active surface includes a control module that biases the surface of the material. An electrical excitation signal is applied to the material and induces the movement of mobile ions. An SPM probe in contact with the surface of the material detects the displacement of mobile ions at the surface of the material. A detector measures an electromechanical strain response at the surface of the material based on the movement and reactions of the mobile ions. The use of an SPM tip to detect local deformations allows highly reproducible measurements in an ambient environment without visible changes in surface structure. The measurements illustrate effective spatial resolution comparable with defect spacing and well below characteristic grain sizes of the material.

Kalinin, Sergei V; Balke, Nina; Kumar, Amit; Dudney, Nancy J; Jesse, Stephen

2014-05-06T23:59:59.000Z

236

Investigation of the suppression effect of polyethylene glycol on copper electroplating by electrochemical impedance spectroscopy  

SciTech Connect (OSTI)

Polyethylene glycol (PEG) is an additive that is commonly used as a suppressor in the semiconductor copper (Cu)-electroplating process. In this study, electrochemical impedance spectroscopy (EIS) was used to analyze the electrochemical behavior of PEG in the Cu-electroplating process. Polarization analysis, cyclic-voltammetry stripping, and cell voltage versus plating time were examined to clarify the suppression behavior of PEG. The equivalent circuit simulated from the EIS data shows that PEG inhibited the Cu-electroplating rate by increasing the charge-transfer resistance as well as the resistance of the adsorption layer. The presence of a large inductance demonstrated the strong adsorption of cuprous-PEG-chloride complexes on the Cu surface during the Cu-electroplating process. Increasing the PEG concentration appears to increase the resistances of charge transfer, the adsorption layer, and the inductance of the electroplating system.

Hung, C.-C.; Lee, W.-H.; Wang, Y.-L.; Chan, D.-Y.; Hwang, G.-J. [Department of Electrical Engineering, National Cheng Kung University, Tainan 701, Taiwan (China); Department of Electrical Engineering, National Chiayi University, Chiayi, Taiwan (China); College of Science and Engineering, National University of Tainan, Tainan 700, Taiwan (China)

2008-09-15T23:59:59.000Z

237

Influence of engine coolant composition on the electrochemical degradation behavior of EPDM radiator hoses  

SciTech Connect (OSTI)

EPDM (ethylene-propylene rubber) has been used for more than 25 years as the main elastomer in radiator hoses because it offers a well-balanced price/performance ratio in this field of application. Some years ago the automotive and rubber industry became aware of a problem called electrochemical degradation and cracking. Cooling systems broke down due to a typical cracking failure of some radiator hoses. Different test methods were developed to simulate and solve the problem on laboratory scale. The influence of different variables with respect to the electrochemical degradation and cracking. Cooling systems broke down due to a typical cracking failure of some radiator hoses. Different test methods were developed to simulate and solve the problem on laboratory scale. The influence of different variables with respect to the electrochemical degradation process has been investigated, but until recently the influence of the engine coolant was ignored. Using a test method developed by DSM elastomers, the influence of the composition of the engine coolant as well as of the EPDM composition has now been evaluated. This paper gives an overview of test results with different coolant technologies and offers a plausible explanation of the degradation mechanisms as a function of the elastomer composition.

Vroomen, G.L.M. [DSM Elastomers Europe, Geleen (Netherlands). Application Center of Expertise; Lievens, S.S.; Maes, J.P. [Texaco Technology Ghent (Belgium)

1999-08-01T23:59:59.000Z

238

ASSESSING THE TRIBOCORROSION BEHAVIOUR OF Cu AND Al13 BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY14  

E-Print Network [OSTI]

monitoring under15 open circuit conditions, i.e. electrochemical noise measurements [7]. Electrochemical16 BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY14 15 16 17 18 Jean Geringera , Bernard Normandb , Catherine Alemany is focused on the interests and limits of Electrochemical Impedance Spectroscopy,4 to establish

Paris-Sud XI, Université de

239

Electrolyte for an electrochemical cell, and an electrochemical cell including the electrolyte  

SciTech Connect (OSTI)

An electrolyte for use in an electrochemical cell is disclosed of the alkali metal-aluminium-halide type. The electrolyte has a melting point below 140/sup 0/ C. At atmospheric pressure and conforms with the stoichiometric product MAlx4 wherein M represents lithium cations, a mixture of lithium and potassium cations or a mixture of sodium and potassium cations; and X represents a mixture of chloride and fluoride anions. A method of reducing the melting point of a sodium-aluminiumchloride or lithium-aluminium-chloride electrolyte by doping it with a potassium fluoride, sodium fluoride, or lithium fluoride, to obtain said electrolyte with a melting point below 140/sup 0/ C. Is disclosed, as are various electrochemical cells employing the product electrolyte.

Coetzer, J.; Nolte, M.J.; Steynberg, A.D.

1981-09-01T23:59:59.000Z

240

Synthesis of graphene platelets by chemical and electrochemical route  

SciTech Connect (OSTI)

Graphical abstract: A schematic showing the overall reduction process of graphite to reduced graphene platelets by chemical and electrochemical route. - Highlights: • Graphene was prepared by diverse routes viz. chemical and electrochemical methods. • NaBH{sub 4} was effective for removing oxygen functional groups from graphene oxide. • Sodium borohydride reduced graphene oxide (SRGO) showed high specific capacitance. • Electrochemical rendered a cheap route for production of graphene in powder form. - Abstract: Graphene platelets were synthesized from graphene oxide by chemical and electrochemical route. Under the chemical method, sodium borohydride and hydrazine chloride were used as reductants to produce graphene. In this paper, a novel and cost effective electrochemical method, which can simplify the process of reduction on a larger scale, is demonstrated. The electrochemical method proposed in this paper produces graphene in powder form with good yield. The atomic force microscopic images confirmed that the graphene samples prepared by all the routes have multilayers of graphene. The electrochemical process provided a new route to make relatively larger area graphene sheets, which will have interest for further patterning applications. Attempt was made to quantify the quantum of reduction using cyclic voltammetry and choronopotentiometry techniques on reduced graphene samples. As a measure in reading the specific capacitance values, a maximum specific capacitance value of 265.3 F/g was obtained in sodium borohydride reduced graphene oxide.

Ramachandran, Rajendran; Felix, Sathiyanathan [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Joshi, Girish M. [Materials Physics Division, School of Advanced Sciences, VIT University, Vellore 632014, Tamil Nadu (India); Raghupathy, Bala P.C., E-mail: balapraveen2000@yahoo.com [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Research and Advanced Engineering Division (Materials), Renault Nissan Technology and Business Center India (P) Ltd., Chennai, Tamil Nadu (India); Jeong, Soon Kwan, E-mail: jeongsk@kier.re.kr [Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Grace, Andrews Nirmala, E-mail: anirmalagrace@vit.ac.in [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

2013-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Gas venting system  

DOE Patents [OSTI]

A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

2010-06-29T23:59:59.000Z

242

Alternative Electrochemical Salt Waste Forms, Summary of FY2010 Results  

SciTech Connect (OSTI)

In FY2009, PNNL performed scoping studies to qualify two waste form candidates, tellurite (TeO2-based) glasses and halide minerals, for the electrochemical waste stream for further investigation. Both candidates showed promise with acceptable PCT release rates and effective incorporation of the 10% fission product waste stream. Both candidates received reprisal for FY2010 and were further investigated. At the beginning of FY2010, an in-depth literature review kicked off the tellurite glasses study. The review was aimed at ascertaining the state-of-the-art for chemical durability testing and mixed chloride incorporation for tellurite glasses. The literature review led the authors to 4 unique binary and 1 unique ternary systems for further investigation which include TeO2 plus the following: PbO, Al2O3-B2O3, WO3, P2O5, and ZnO. Each system was studied with and without a mixed chloride simulated electrochemical waste stream and the literature review provided the starting points for the baseline compositions as well as starting points for melting temperature, compatible crucible types, etc. The most promising glasses in each system were scaled up in production and were analyzed with the Product Consistency Test, a chemical durability test. Baseline and PCT glasses were analyzed to determine their state, i.e., amorphous, crystalline, phase separated, had undissolved material within the bulk, etc. Conclusions were made as well as the proposed direction for FY2011 plans. Sodalite was successfully synthesized by the sol-gel method. The vast majority of the dried sol-gel consisted of sodalite with small amounts of alumino-silicates and unreacted salt. Upon firing the powders made by sol-gel, the primary phase observed was sodalite with the addition of varying amounts of nepheline, carnegieite, lithium silicate, and lanthanide oxide. The amount of sodalite, nepheline, and carnegieite as well as the bulk density of the fired pellets varied with firing temperature, sol-gel process chemistry, and the amount of glass sintering aid added to the batch. As the firing temperature was increased from 850 C to 950 C, chloride volatility increased, the fraction of sodalite decreased, and the fractions nepheline and carnegieite increased. This indicates that the sodalite structure is not stable and begins to convert to nepheline and carnegieite under these conditions at 950 C. Density has opposite relationship with relation to firing temperature. The addition of a NBS-1, a glass sintering aid, had a positive effect on bulk density and increased the stability of the sodalite structure in a minimal way.

Riley, Brian J.; Rieck, Bennett T.; Crum, Jarrod V.; Matyas, Josef; McCloy, John S.; Sundaram, S. K.; Vienna, John D.

2010-08-01T23:59:59.000Z

243

Method for making an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN)

1996-01-01T23:59:59.000Z

244

Electrochemical Approaches to PV Busbar Application  

SciTech Connect (OSTI)

Busbars are an integral component of any thin-film photovoltaic module and must be easy and quick to apply by PV manufacturers, as well as provide long-term reliability in deployed modules. Potential reliability issues include loss of adhesion and delamination, chemical instability under current collection conditions (electromigration or corrosion), compatibility of material and application method with subsequent encapsulation steps. Several new and novel busbar materials and application methods have been explored, including adhering metal busbars with various one- and two-part conductive epoxies or conductive adhesive films, ultrasonic bonding of metal busbar strips, and bonding of busbar strips using low-temperature solders. The most promising approach to date has been the direct application of metal busbars via various electrochemical techniques, which offers a variety of distinct advantages.

Pankow, J. W.

2005-01-01T23:59:59.000Z

245

Method for making an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making the same, having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C. 9 figs.

Bates, J.B.; Dudney, N.J.

1996-10-22T23:59:59.000Z

246

Electrochemical cell having cylindrical electrode elements  

DOE Patents [OSTI]

A secondary, high temperature electrochemical cell especially adapted for lithium alloy negative electrodes, transition metal chalcogenide positive electrodes and alkali metal halide or alkaline earth metal halide electrolyte is disclosed. The cell is held within an elongated cylindrical container in which one of the active materials is filled around the outside surfaces of a plurality of perforate tubular current collectors along the length of the container. Each of the current collector tubes contain a concentric tubular layer of electrically insulative ceramic as an interelectrode separator. The active material of opposite polarity in elongated pin shape is positioned longitudinally within the separator layer. A second electrically conductive tube with perforate walls can be swagged or otherwise bonded to the outer surface of the pin as a current collector and the electrically insulative ceramic layer can be coated or otherwise layered onto the outer surface of this second current collector. Alternatively, the central pin electrode can include an axial core as a current collector.

Nelson, Paul A. (Wheaton, IL); Shimotake, Hiroshi (Hinsdale, IL)

1982-01-01T23:59:59.000Z

247

Development of an Electrochemical Separator and Compressor  

SciTech Connect (OSTI)

Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

Trent Molter

2011-04-28T23:59:59.000Z

248

Thermoelectrochemical system and method  

DOE Patents [OSTI]

A thermal electrochemical system is described in which an electrical current is generated between a cathode immersed in a concentrated aqueous solution of phosphoric acid and an anode immersed in a molten salt solution of ammonium phosphate and monohydric ammonium phosphate. Reactants consumed at the electrodes during the electrochemical reaction are thermochemically regenerated and recycled to the electrodes to provide continuous operation of the system. 5 figs.

Ludwig, F.A.; Townsend, C.W.; Eliash, B.M.

1995-11-28T23:59:59.000Z

249

Electrochemically-mediated amine regeneration for carbon dioxide separations  

E-Print Network [OSTI]

This thesis describes a new strategy for carbon dioxide (CO?) separations based on amine sorbents, which are electrochemically-mediated to facilitate the desorption and regeneration steps of the separation cycle. The ...

Stern, Michael C. (Michael Craig)

2014-01-01T23:59:59.000Z

250

In situ electrochemical dilatometry of carbide-derived carbons  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electrochemical dilatometry of carbide-derived carbons M.M. Hantel a , V. Presser b , R. Ktz a, , Y. Gogotsi b a Electrochemistry Laboratory, Paul Scherrer Institut, CH-5232...

251

Development of a morphing helicopter blade with electrochemical actuators  

E-Print Network [OSTI]

The use of the expansion of electrochemical cells, upon ion intercalation, for the development of a morphing helicopter blade is explored. Using commercially available lithium-ion batteries as demostrators of the technology, ...

Tubilla Kuri, Fernando

2007-01-01T23:59:59.000Z

252

Electrochemical Corrosion Rate Sensors for Waste Incineration Applications  

SciTech Connect (OSTI)

Electrochemical corrosion rate sensors work in high temperature waste incineration applications where ash is deposited. The ash serves as the electrolyte for electrochemical measurements, such as liner polarization resistance, electrochemical noise, and harmonic distortion analyses. Results to date have shown that these types of sensors respond qualitatively to changes in temperature, gas composition, alloy composition, and type of ash. Several years of research have shown that high temperature corrosion rate probes need to be better understood before corrosion rate can be used as a process variable by power plant operators. More recent research has shown that electrochemical corrosion probes typically measure lower corrosion rates than those measured by standard mass loss techniques. While still useful for monitoring changes in corrosion rates, absolute probe corrosion rates will need a calibration factor to be useful. Ideas for research that may help resolve these issues are presented.

Covino, B.S., Jr.; Bullard, S.J.; Matthes, S.A.; Holcomb, G.R.; Ziomek-Moroz, M.; Eden, D.A. (Honeywell Intercorr)

2007-03-01T23:59:59.000Z

253

Design considerations and characterization of Origami [TM] electrochemical capacitors  

E-Print Network [OSTI]

Electrochemical capacitors, also known as supercapacitors, ultracapacitors, and electric double-layer capacitors, have recently received attention as electrical energy storage devices. The devices are both high power and ...

Blanton, Gabriel G. (Gabriel Garrison), 1982-

2004-01-01T23:59:59.000Z

254

Conducting polymers as potential active materials in electrochemical supercapacitors  

SciTech Connect (OSTI)

Electronically,conducting polymers represent an interesting class of materials for use in electrochemical capacitors because of the combination of high capacitive energy density and low materials cost. Three generalized types of electrochemical capacitors can be constructed using conducting polymers as active material, and in the third of these, which utilizes conducting polymers that can be both n- and p-doped, energy densities of up to 40 watt-hours per kilogram of active material on both electrodes have been demonstrated.

Rudge, A.; Davey, J.; Raistrick, I.; Gottesfeld, S. [Los Alamos National Lab., NM (United States); Ferraris, J.P. [Texas Univ., Richardson, TX (United States). Dept. of Chemistry

1992-12-01T23:59:59.000Z

255

Conducting polymers as potential active materials in electrochemical supercapacitors  

SciTech Connect (OSTI)

Electronically,conducting polymers represent an interesting class of materials for use in electrochemical capacitors because of the combination of high capacitive energy density and low materials cost. Three generalized types of electrochemical capacitors can be constructed using conducting polymers as active material, and in the third of these, which utilizes conducting polymers that can be both n- and p-doped, energy densities of up to 40 watt-hours per kilogram of active material on both electrodes have been demonstrated.

Rudge, A.; Davey, J.; Raistrick, I.; Gottesfeld, S. (Los Alamos National Lab., NM (United States)); Ferraris, J.P. (Texas Univ., Richardson, TX (United States). Dept. of Chemistry)

1992-01-01T23:59:59.000Z

256

Thermal conductor for high-energy electrochemical cells  

DOE Patents [OSTI]

A thermal conductor for use with an electrochemical energy storage device is disclosed. The thermal conductor is attached to one or both of the anode and cathode contacts of an electrochemical cell. A resilient portion of the conductor varies in height or position to maintain contact between the conductor and an adjacent wall structure of a containment vessel in response to relative movement between the conductor and the wall structure. The thermal conductor conducts current into and out of the electrochemical cell and conducts thermal energy between the electrochemical cell and thermally conductive and electrically resistive material disposed between the conductor and the wall structure. The thermal conductor may be fabricated to include a resilient portion having one of a substantially C-shaped, double C-shaped, Z-shaped, V-shaped, O-shaped, S-shaped, or finger-shaped cross-section. An elastomeric spring element may be configured so as to be captured by the resilient conductor for purposes of enhancing the functionality of the thermal conductor. The spring element may include a protrusion that provides electrical insulation between the spring conductor and a spring conductor of an adjacently disposed electrochemical cell in the presence of relative movement between the cells and the wall structure. The thermal conductor may also be fabricated from a sheet of electrically conductive material and affixed to the contacts of a number of electrochemical cells.

Hoffman, Joseph A. (Minneapolis, MN); Domroese, Michael K. (South St. Paul, MN); Lindeman, David D. (Hudson, WI); Radewald, Vern E. (Austin, TX); Rouillard, Roger (Beloeil, CA); Trice, Jennifer L. (Eagan, MN)

2000-01-01T23:59:59.000Z

257

3516 J. Electrochem. Soc., Vol. 141, No. 12, December 1994 9 The Electrochemical Society, Inc. i. S.P. Murarka, J. Steigerwald, and R. J. Gutmann, MRS  

E-Print Network [OSTI]

3516 J. Electrochem. Soc., Vol. 141, No. 12, December 1994 9 The Electrochemical Society, Inc, Pittsburgh, PA (1994). 9. M. Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solutions, p. 384, NACESilicon,Carbon, and Oxygen Implantation Damage on Diffusionof Phosphorusin Silicon Samir Chaudhry* and Mark E. Law

Florida, University of

258

The Use of Electrochemical Techniques to Characterize Wet Steam Environments  

SciTech Connect (OSTI)

The composition of a steam phase in equilibrium with a water phase at high temperature is remarkably affected by the varying capabilities of the water phase constituents to partition into the steam. Ionic impurities (sodium, chloride, sulfate, etc.) tend to remain in the water phase, while weakly ionic or gaseous species (oxygen) partition into the steam. Analysis of the water phase can provide misleading results concerning the steam phase composition or environment. This paper describes efforts that were made to use novel electrochemical probes and sampling techniques to directly characterize a wet steam phase environment in equilibrium with high temperature water. Probes were designed to make electrochemical measurements in the thin film of water existing on exposed surfaces in steam over a water phase. Some of these probes were referenced against a conventional high temperature electrode located in the water phase. Others used two different materials (typically tungsten and platinum) to make measurements without a true reference electrode. The novel probes were also deployed in a steam space removed from the water phase. It was necessary to construct a reservoir and an external, air-cooled condenser to automatically keep the reservoir full of condensed steam. Conventional reference and working electrodes were placed in the water phase of the reservoir and the novel probes protruded into the vapor space above it. Finally, water phase probes (both reference and working electrodes) were added to the hot condensed steam in the external condenser. Since the condensing action collapsed the volatiles back into the water phase, these electrodes proved to be extremely sensitive at detecting oxygen, which is one of the species of highest concern in high temperature power systems. Although the novel steam phase probes provided encouraging initial results, the tendency for tungsten to completely corrode away in the steam phase limited their usefulness. However, the conventional water phase electrodes, installed both in the reservoir and in the external condensing coil, provided useful data showing the adverse impact of oxygen and carbon dioxide on the REDOX potential and high temperature pH, respectively.

Bruce W. Bussert; John A. Crowley; Kenneth J. Kimball; Brian J. Lashway

2003-04-30T23:59:59.000Z

259

Portable Analyzer Based on Microfluidics, Nanoengineered Electrochemical Sensors  

SciTech Connect (OSTI)

This report summarizes the NMSU activity over the first year of the project (i.e., the 11/03-8/04 period). This research effort aims at developing a portable analytical system for fast, sensitive, and inexpensive, on-site monitoring of toxic transition metals and radionuclides in contaminated DOE Sites. In accordance to our original objectives our studies have focused on various fundamental and practical aspects of microchip devices for monitoring metal contaminants. As described in this section, we have made a substantial progress, and introduced effective routes for improving the reliability of devices for field screening of toxic metals. This 11-mos activity has already resulted in 2 research papers (published or in press in major journals), and several invited presentations in major meetings. (Several more publications are expected in the late part of 2004.) The electrochemical sensors being investigated rely on the highly sensitive adsorptive stripping voltammetry (AdSV) technique to detect metal ions of interest to the DOE, particularly uranium and chromium.

Wang, Joseph

2003-06-01T23:59:59.000Z

260

SISGR: Improved Electrical Energy Storage with Electrochemical Double Layer Capacitance Based on Novel Carbon Electrodes, New Electrolytes, and Thorough Development of a Strong Science Base  

SciTech Connect (OSTI)

The broad objective of the SISGR program is to advance the fundamental scientific understanding of electrochemical double layer capacitance (EDLC) and thus of ultracapacitor systems composed of a new type of electrode based on chemically modified graphene (CMG) and (primarily) with ionic liquids (ILs) as the electrolyte. Our team has studied the interplay between graphene-based and graphene-derived carbons as the electrode materials in electrochemical double layer capacitors (EDLC) systems on the one hand, and electrolytes including novel ionic liquids (ILs), on the other, based on prior work on the subject.

Ruoff, Rodney S. [PI; Alam, Todd M. [co-PI; Bielawski, Christopher W. [co-PI; Chabal, Yves [co-PI; Hwang, Gyeong [co-PI; Ishii, Yoshitaka [co-PI; Rogers, Robin [co-PI

2014-07-23T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Steel refining with an electrochemical cell  

DOE Patents [OSTI]

Disclosed is an apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

Blander, M.; Cook, G.M.

1985-05-21T23:59:59.000Z

262

Steel refining with an electrochemical cell  

DOE Patents [OSTI]

Apparatus is described for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom. 2 figs.

Blander, M.; Cook, G.M.

1988-05-17T23:59:59.000Z

263

Steel refining with an electrochemical cell  

DOE Patents [OSTI]

Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

Blander, Milton (Palos Park, IL); Cook, Glenn M. (Naperville, IL)

1988-01-01T23:59:59.000Z

264

Electrochemical cell having improved pressure vent  

DOE Patents [OSTI]

The electrochemical cell of the instant invention includes a case having a gas outlet, one or more positive electrodes positioned within the case, one or more negative electrodes positioned within the case electrode separators positioned between the positive and negative electrodes, electrolyte positioned within the case, and a pressure vent for releasing internal pressure occurring in the case to the surrounding atmosphere. The pressure vent is affixed to the case covering the gas outlet, the pressure vent includes a vent housing having a hollow interior area in gaseous communication with the surrounding atmosphere and the interior of the case via the gas outlet, a pressure release piston positioned within the hollow interior area, the pressure release piston sized to surround the gas outlet and having a seal groove configured to encapsulate all but one surface of a seal mounted within the seal groove, leaving the non-encapsulated surface of the seal exposed, and a compression spring positioned to urge the pressure release piston to compress the seal in the seal groove and block the gas outlet in the case.

Dean, Kevin (Pontiac, MI); Holland, Arthur (Troy, MI); Fillmore, Donn (Waterford, MI)

1993-01-01T23:59:59.000Z

265

Joint with application in electrochemical devices  

DOE Patents [OSTI]

A joint for use in electrochemical devices, such as solid oxide fuel cells (SOFCs), oxygen separators, and hydrogen separators, that will maintain a hermetic seal at operating temperatures of greater than 600.degree. C., despite repeated thermal cycling excess of 600.degree. C. in a hostile operating environment where one side of the joint is continuously exposed to an oxidizing atmosphere and the other side is continuously exposed to a wet reducing gas. The joint is formed of a metal part, a ceramic part, and a flexible gasket. The flexible gasket is metal, but is thinner and more flexible than the metal part. As the joint is heated and cooled, the flexible gasket is configured to flex in response to changes in the relative size of the metal part and the ceramic part brought about by differences in the coefficient of thermal expansion of the metal part and the ceramic part, such that substantially all of the tension created by the differences in the expansion and contraction of the ceramic and metal parts is absorbed and dissipated by flexing the flexible gasket.

Weil, K Scott [Richland, WA; Hardy, John S [Richland, WA

2010-09-14T23:59:59.000Z

266

Electrochemical-thermal modeling and microscale phase change for passive internal thermal management of lithium ion batteries.  

SciTech Connect (OSTI)

A fully coupled electrochemical and thermal model for lithium-ion batteries is developed to investigate the impact of different thermal management strategies on battery performance. In contrast to previous modeling efforts focused either exclusively on particle electrochemistry on the one hand or overall vehicle simulations on the other, the present work predicts local electrochemical reaction rates using temperature-dependent data on commercially available batteries designed for high rates (C/LiFePO{sub 4}) in a computationally efficient manner. Simulation results show that conventional external cooling systems for these batteries, which have a low composite thermal conductivity ({approx}1 W/m-K), cause either large temperature rises or internal temperature gradients. Thus, a novel, passive internal cooling system that uses heat removal through liquid-vapor phase change is developed. Although there have been prior investigations of phase change at the microscales, fluid flow at the conditions expected here is not well understood. A first-principles based cooling system performance model is developed and validated experimentally, and is integrated into the coupled electrochemical-thermal model for assessment of performance improvement relative to conventional thermal management strategies. The proposed cooling system passively removes heat almost isothermally with negligible thermal resistances between the heat source and cooling fluid. Thus, the minimization of peak temperatures and gradients within batteries allow increased power and energy densities unencumbered by thermal limitations.

Fuller, Thomas F. (Georgia Institute of Technology, Atlanta, GA); Bandhauer, Todd (Georgia Institute of Technology, Atlanta, GA); Garimella, Srinivas (Georgia Institute of Technology, Atlanta, GA)

2012-01-01T23:59:59.000Z

267

Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for In-situ Characterization of Mixed Wastes  

SciTech Connect (OSTI)

Required characterizations of the DOE's transuranic (TRU) and mixed wastes (MW) before disposing and treatment of the wastes are currently costly and have lengthy turnaround. Research toward developing faster and more sensitive characterization and analysis tools to reduce costs and accelerate throughputs is therefore desirable. This project is aimed at the development of electrochemical sensors, specific to toxic transition metals, uranium, and technetium, that can be integrated into the portable sensor systems. This system development will include fabrication and performance evaluation of electrodes as well as understanding of electrochemically active sites on the electrodes specifically designed for toxic metals, uranium and technetium detection. Subsequently, these advanced measurement units will be incorporated into a microfluidic prototype specifically designed and fabricated for field-deployable characterizations of such species.

Yuehe Lin; Glen E. Fryxell; Wassana Yantasee; Guodong Liu; Zheming Wang

2006-06-01T23:59:59.000Z

268

Electrochromic polyaniline/graphite oxide nanocomposites with endured electrochemical energy storage  

E-Print Network [OSTI]

Electrochromic polyaniline/graphite oxide nanocomposites with endured electrochemical energy February 2013 Keywords: Polyaniline nanocomposite film Electropolymerization Electrochromism a b s t r a c films for electrochromic displays and electrochemical energy storage devices applications were

Guo, John Zhanhu

269

Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial  

E-Print Network [OSTI]

Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial electrolysis cell Roland D. Cusick*, Mark L. Ullery, Brian A. Dempsey, Bruce E. Logan Department of Civil January 2014 Available online 6 February 2014 Keywords: Microbial electrolysis cell Electrochemical

270

Center for Nanostructured Biomimetic Interfaces Integrated Electrochemical and Optical Methods for Studying TRPV Channel Proteins  

E-Print Network [OSTI]

Center for Nanostructured Biomimetic Interfaces Integrated Electrochemical and Optical Methods Ofoli, Ilsoon Lee, Mark Worden and Donna Wang* Department of Chemical Engineering and Materials Science: Structural Biology of Membrane Proteins ·Measure protein activity in lipid bilayer -Electrochemical methods

271

Preparation and electrochemical investigation of Li2CoPO4F cathode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electrochemical investigation of Li2CoPO4F cathode material forlithium-ion batteries. Preparation and electrochemical investigation of Li2CoPO4F cathode material forlithium-ion...

272

Equipment specifications for an electrochemical fuel reprocessing plant  

SciTech Connect (OSTI)

Electrochemical reprocessing is a technique used to chemically separate and dissolve the components of spent nuclear fuel, in order to produce new metal fuel. There are several different variations to electrochemical reprocessing. These variations are accounted for by both the production of different types of spent nuclear fuel, as well as different states and organizations doing research in the field. For this electrochemical reprocessing plant, the spent fuel will be in the metallurgical form, a product of fast breeder reactors, which are used in many nuclear power plants. The equipment line for this process is divided into two main categories, the fuel refining equipment and the fuel fabrication equipment. The fuel refining equipment is responsible for separating out the plutonium and uranium together, while getting rid of the minor transuranic elements and fission products. The fuel fabrication equipment will then convert this plutonium and uranium mixture into readily usable metal fuel.

Hemphill, Kevin P [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

273

Electrochemical corrosion rate probes for high temperature energy applications  

SciTech Connect (OSTI)

Electrochemical corrosion rate (ECR) probes were constructed and exposed along with mass loss coupons in a N2/O2/CO2/H2O environment to determine ECR probe operating characteristics. Temperatures ranged from 450 to 800 C and both ECR probes and mass loss coupons were coated with ash. Results are presented in terms of the probe response to temperature, the measured zero baseline, and the quantitative nature of the probes. The effect of Stern-Geary constant and the choice of electrochemical technique used to measure the corrosion rate are also discussed. ECR probe corrosion rates were a function of time, temperature, and process environment and were found to be quantitative for some test conditions. Measured Stern-Geary constants averaged 0.0141 V/decade and the linear polarization technique was found to be more quantitative than the electrochemical noise technique.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Cayard, M.S. (InterCorr International Inc.); Eden, D.A. (InterCorr International Inc.)

2004-01-01T23:59:59.000Z

274

Synergistic Effect of Fullerene-Capped Gold Nanoparticles on Graphene Electrochemical Supercapacitors  

E-Print Network [OSTI]

Hybrid Filmsfor Supercapacitors,” Journal of PhysicalGraphene Electrochemical Supercapacitors Virginia Yong * ,Nanoparticles; Graphene; Supercapacitors; Energy Storage;

Yong, Virginia; Hahn, H. Thomas

2013-01-01T23:59:59.000Z

275

Nonlinear electrochemical relaxation around conductors Kevin T. Chu1,2  

E-Print Network [OSTI]

­5 , but electrochemical relaxation is also being increas- ingly exploited in colloids and microfluidics 6 . For ex- ample

Chu, Kevin T.

276

Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for in Situ Characterization of Mixed Wastes  

SciTech Connect (OSTI)

Portable Analyzer Based on Microfluidic/Nanoengineered Electrochemical Sensors for in Situ Characterization of Mixed Wastes PI: Dr. Joseph Wang (In Collaboration with the PNNL PI Dr. Y. Lin). Objective of Research: This research effort aims at developing a portable analytical system for fast, sensitive, and inexpensive, on-site monitoring of toxic transition metals and radionuclides in contaminated DOE Sites. The portable devices will be based on Microscale Total Analytical systems ( -TAS) or 'Lab-on-a-chip' in combination with electrochemical (stripping-voltammetric) sensors. The resulting microfluidics/electrochemical sensor system would allow testing for toxic metals to be performed more rapidly, inexpensively, and reliably in a field setting. Progress Summary/Accomplishments: This report summarizes the ASU activity over the second year of the project. In accordance to our original objectives our studies have focused on various fundamental and practical aspects of sensing and microchip devices for monitoring metal contaminants. As described in this section, we have made a substantial progress, and introduced effective routes for improving the on-site detection of toxic metals and for interfacing microchips with the real world. This activity has already resulted in 7 research papers (published or in press in major international journals). The electrochemical sensors being developed rely on the highly sensitive adsorptive stripping voltammetry (AdSV) technique to detect metal ions of interest to the DOE, particularly uranium and chromium. Traditionally, AdSV measurements of U and Cr require the use of mercury electrodes which are not suitable attractive for field deployment. Our initial goal was thus to replace these toxic mercury electrodes with 'environmentally-friendly' sensor materials. In particular, we demonstrated recently that bismuth-film electrodes offer high-quality measurements of heavy metals that compare favorably with that of mercury electrodes. Bismuth is a 'green' element, with very low toxicity, and widespread pharmaceutical use. A major effort of our activity this year has been devoted to the development of a 'mercury-free' uranium sensor based on the bismuth film electrode. Bismuth-coated carbon-fiber electrodes have thus been successfully applied for adsorptive-stripping voltammetric measurements of trace uranium in the presence of the cupferron complexing agent.

Wang, Joseph

2006-06-01T23:59:59.000Z

277

Effect of Pore Morphology on the Electrochemical Properties of Electric Double Layer Carbon Cryogel Supercapacitors  

SciTech Connect (OSTI)

In this study, a group of carbon cryogels have been synthesized using resorcinol formaldehyde as precursors, and altered via catalysis and activation, to obtain varied nanostructures and pore size distributions. To understand the relation between structure and electrochemical properties, an alternate approach to de Levi's cylindrical pore, transmission line method was utilized. Using electrochemical impedance spectroscopy, the capacitor can be studied as a dielectric system composed of a porous electrode and the electrolyte (tetraethylammonium tetrafluoroborate in propylene carbonate). The complex capacitance and power are used to study the behavior of the system below the relaxation frequency f{sub 0} ({var_phi} = -45{sup o}). Therefore, the relaxation of the capacitor system at the low frequency range, f

Garcia, B.B.; Feaver, A.M.; Zhang, Q.; Champion, R.D.; Cao, G.; Fister, T.T.; Nagle, K.P.; Seidler, G.T. (UWASH)

2008-07-28T23:59:59.000Z

278

Nitrogen-doped graphene and its electrochemical applications Yuyan Shao,a  

E-Print Network [OSTI]

Nitrogen-doped graphene and its electrochemical applications Yuyan Shao,a Sheng Zhang,a Mark H the widely-used expensive Pt for oxygen reduction. The excellent electrochemical performance of N-graphene is promising for applications in electrochemical energy devices (fuel cells, metal­air batteries

Aksay, Ilhan A.

279

Minimizing Nonspecific Adsorption in Protein Biosensors that Utilize Electrochemical Impedance Spectroscopy  

E-Print Network [OSTI]

, such as optical and acoustic methods.3-6 In addition, electrochemical biosensors often have lower noise levels are often sensitive to environmental noise. Electrochemical glucose biosensors detect glucose by measuringMinimizing Nonspecific Adsorption in Protein Biosensors that Utilize Electrochemical Impedance

Suni, Ian Ivar

280

Enhanced electrochemical etching of ion irradiated silicon by localized amorphization  

SciTech Connect (OSTI)

A tailored distribution of ion induced defects in p-type silicon allows subsequent electrochemical anodization to be modified in various ways. Here we describe how a low level of lattice amorphization induced by ion irradiation influences anodization. First, it superposes a chemical etching effect, which is observable at high fluences as a reduced height of a micromachined component. Second, at lower fluences, it greatly enhances electrochemical anodization by allowing a hole diffusion current to flow to the exposed surface. We present an anodization model, which explains all observed effects produced by light ions such as helium and heavy ions such as cesium over a wide range of fluences and irradiation geometries.

Dang, Z. Y.; Breese, M. B. H. [Centre for Ion Beam Applications (CIBA), Department of Physics, National University of Singapore Singapore 117542 (Singapore); Lin, Y.; Tok, E. S. [Department of Physics, National University of Singapore, 2 Science Drive 3, Singapore 117542 (Singapore); Vittone, E. [Physics Department, NIS Excellence Centre and CNISM, University of Torino, via Pietro Giuria 1, 10125 Torino (Italy)

2014-05-12T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Electrochemical process and production of novel complex hydrides  

DOE Patents [OSTI]

A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

Zidan, Ragaiy

2013-06-25T23:59:59.000Z

282

Nitrogen-doped Graphene and Its Electrochemical Applications  

SciTech Connect (OSTI)

Nitrogen-doped graphene (N-graphene) is obtained by exposing graphene to nitrogen plasma. N-graphene exhibits much higher electrocatalytic activity toward oxygen reduction and H2O2 reduction than graphene, and much higher durability and selectivity than the widely-used expensive Pt. The excellent electrochemical performance of N-graphene is attributed to nitrogen functional groups and the specific properties of graphene. This indicates that N-graphene is promising for applications in electrochemical energy devices (fuel cells, metal-air batteries) and biosensors.

Shao, Yuyan; Zhang, Sheng; Engelhard, Mark H.; Li, Guosheng; Shao, Guocheng; Wang, Yong; Liu, Jun; Aksay, Ilhan A.; Lin, Yuehe

2010-06-04T23:59:59.000Z

283

Regeneration of anion exchange resins by catalyzed electrochemical reduction  

DOE Patents [OSTI]

Anion exchange resins sorbed with perchlorate may be regenerated by a combination of chemical reduction of perchlorate to chloride using a reducing agent and an electrochemical reduction of the oxidized reducing agent. Transitional metals including Ti, Re, and V are preferred chemical reagents for the reduction of perchlorate to chloride. Complexing agents such as oxalate are used to prevent the precipitation of the oxidized Ti(IV) species, and ethyl alcohol may be added to accelerate the reduction kinetics of perchlorate. The regeneration may be performed by continuously recycling the regenerating solution through the resin bed and an electrochemical cell so that the secondary waste generation is minimized.

Gu, Baohua (Oak Ridge, TN); Brown, Gilbert M. (Knoxville, TN)

2002-01-01T23:59:59.000Z

284

Electrochemical arsenic remediation for rural Bangladesh  

SciTech Connect (OSTI)

Arsenic in drinking water is a major public health problem threatening the lives of over 140 million people worldwide. In Bangladesh alone, up to 57 million people drink arsenic-laden water from shallow wells. ElectroChemical Arsenic Remediation(ECAR) overcomes many of the obstacles that plague current technologies and can be used affordably and on a small-scale, allowing for rapid dissemination into Bangladesh to address this arsenic crisis. In this work, ECAR was shown to effectively reduce 550 - 580 mu g=L arsenic (including both As[III]and As[V]in a 1:1 ratio) to below the WHO recommended maximum limit of 10 mu g=L in synthetic Bangladesh groundwater containing relevant concentrations of competitive ions such as phosphate, silicate, and bicarbonate. Arsenic removal capacity was found to be approximately constant within certain ranges of current density, but was found to change substantially between ranges. In order of decreasing arsenic removal capacity, the pattern was: 0.02 mA=cm2> 0.07 mA=cm2> 0.30 - 1.1 mA=cm2> 5.0 - 100 mA=cm2. Current processing time was found to effect arsenic removal capacity independent of either charge density or current density. Electrode polarization studies showed no passivation of the electrode in the tested range (up to current density 10 mA=cm2) and ruled out oxygen evolution as the cause of decreasing removal capacity with current density. Simple settling and decantation required approximately 3 days to achieve arsenic removal comparable to filtration with a 0.1 mu m membrane. X-ray Absorption Spectroscopy (XAS) showed that (1) there is no significant difference in the arsenic removal mechanism of ECAR during operation at different current densities and (2) the arsenic removal mechanism in ECAR is consistent with arsenate adsorption onto a homogenous Fe(III)oxyhydroxide similar in structure to 2-line ferrihydrite. ECAR effectively reduced high arsenic concentrations (100 - 500 mu g=L) in real Bangladesh tube well water collected from three regions to below the WHO limit of 10 mu g=L. Prototype fabrication and field testing are currently underway.

Addy, Susan Amrose

2009-01-01T23:59:59.000Z

285

CO.sub.2 utilization in electrochemical systems  

SciTech Connect (OSTI)

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Boxley, Chett; Akash, Akash; Zhao, Qiang

2013-01-22T23:59:59.000Z

286

A biofilm microreactor system for simultaneous electrochemical and nuclear  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011A FirstEMSL ShellACalmodulin inU T Hmagnetic

287

Analysis and Simulation of Electrochemical Energy Systems | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment ofEnergy Natural Gas:Austin,AnAn ExplorationLaboratory

288

Analysis and Simulation of Electrochemical Energy Systems | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment ofEnergy Natural Gas:Austin,AnAn ExplorationLaboratoryEnergy 09

289

Final report for contract research on electrochemical capacitors based on conducting polymers, January 15--August 31, 1992  

SciTech Connect (OSTI)

Conducting polymers (CPs) have attracted attention as potentially useful materials for electrochemical capacitors due to their high energy storage capacity and their comparatively low cost. During the course of this research the authors explored a number of poly(heteroaromatic) systems, in conjunction with several nonaqueous electrolytes, that could be used as active materials in electrochemical capacitors. They identified a new configuration for such capacitors based on p- and n-dopable polymers and prepared a number4r of such materials. A new electrolyte, TMATFMS, which facilitates n-doping in these polymers was also synthesized and tested. A patent disclosure on these discoveries has been filed with Mr. Ray Wilson of LANL.

Ferraris, J.P. [Texas Univ., Dallas, TX (United States). Dept. of Chemistry

1992-10-22T23:59:59.000Z

290

EFFECTS OF GAMMA RADIATION ON ELECTROCHEMICAL PROPERTIES OF IONIC LIQUIDS  

SciTech Connect (OSTI)

The electrochemical properties of ionic liquids (ILs) make them attractive for possible replacement of inorganic salts in high temperature molten salt electrochemical processing of nuclear fuel. To be a feasible replacement solvent, ILs need to be stable in moderate and high doses of radiation without adverse chemical and physical effects. Here, we exposed seven different ILs to a 1.2 MGy dose of gamma radiation to investigate their physical and chemical properties as they related to radiological stability. The azolium-based ILs experienced the greatest change in appearance, but these ILs were chemically more stable to gamma radiation than some of the other classes of ILs tested, due to the presence of aromatic electrons in the azolium ring. All the ILs exhibited a decrease in their conductivity and electrochemical window (at least 1.1 V), both of which could affect the utility of ILs in electrochemical processing. The concentration of the irradiation decomposition products was less than 3 mole %, with no impurities detectable using NMR techniques.

Visser, A; Nicholas Bridges, N; Thad Adams, T; John Mickalonis, J; Mark02 Williamson, M

2009-04-21T23:59:59.000Z

291

Electrochemical and Raman measurements on single-walled carbon nanotubes  

E-Print Network [OSTI]

Electrochemical and Raman measurements on single-walled carbon nanotubes M. Stoll a,*, P performed on a carbon nanotube mat as a working electrode using different salt solutions. The gravimetric capacitance of the nanotube material was estimated and its effective surface area was de- termined in a purely

Nabben, Reinhard

292

Raman Measurements on Electrochemically Doped Single-Walled Carbon Nanotubes  

E-Print Network [OSTI]

Raman Measurements on Electrochemically Doped Single-Walled Carbon Nanotubes P. M. Rafailov, M and studied the Raman response of electro- chemically doped single-walled carbon nanotubes (SWNT) using different salt solutions. The fre- quency shift of the radial breathing mode (RBM) and the high-energy mode

Nabben, Reinhard

293

Capacitance studies of cobalt oxide films formed via electrochemical precipitation  

E-Print Network [OSTI]

prepared by electrochemically precipitating the hydroxide and heating it in air to form Co3O4 the need to identify more suitable materials. One promising route is the use of transi- tion metal oxides to batteries, are referred to as Faradaic or pseudocapacitors. However, the high cost of these materials has

Weidner, John W.

294

VLSI POTENTIOSTAT ARRAY FOR DISTRIBUTED ELECTROCHEMICAL NEURAL Abhishek Bandyopadhyay1  

E-Print Network [OSTI]

VLSI POTENTIOSTAT ARRAY FOR DISTRIBUTED ELECTROCHEMICAL NEURAL RECORDING Abhishek Bandyopadhyay1, and digitized by a bank of current-mode delta-sigma analog-to-digital (A/D) converters. First-order noise shaping and 4,096-fold over- sampling provide high signal-to-noise ratio for the low- frequency

Cauwenberghs, Gert

295

Mediated electrochemical oxidation of organic wastes without electrode separators  

DOE Patents [OSTI]

An electrochemical cell/electrolyte/mediator combination is described for the efficient destruction of organic contaminants using metal salt mediators in a sulfuric acid electrolyte, wherein the electrodes and mediator are chosen such that hydrogen gas is produced at the cathode and no cell membrane is required. 3 figs.

Farmer, J.C.; Wang, F.T.; Hickman, R.G.; Lewis, P.R.

1996-05-14T23:59:59.000Z

296

Graphene Based Electrochemical Sensors and Biosensors: Yuyan Shao,a  

E-Print Network [OSTI]

Review Graphene Based Electrochemical Sensors and Biosensors: A Review Yuyan Shao,a Jun Wang,a Hong-mail: Yuehe.lin@pnl.gov Received: November 24, 2009 Accepted: December 23, 2009 Abstract Graphene, emerging of functionalization and mass production). This article selectively reviews recent advances in graphene

Aksay, Ilhan A.

297

Electrochemical treatment of human waste coupled with molecular hydrogen production  

E-Print Network [OSTI]

in a hydrogen fuel cell. Herein, we report on the efficacy of a laboratory-scale wastewater electrolysis cell an electrolysis cell for on-site wastewater treatment coupled with molecular hydrogen production for useElectrochemical treatment of human waste coupled with molecular hydrogen production Kangwoo Cho

Heaton, Thomas H.

298

Computational, electrochemical and {sup 7}Li NMR studies of lithiated disordered carbons electrodes in lithium ion cells.  

SciTech Connect (OSTI)

Disordered carbons that deliver high reversible capacity in electrochemical cells have been synthesized by using inorganic clays as templates to control the pore size and the surface area. The capacities obtained were much higher than those calculated if the resultant carbon had a graphitic-like structure. Computational chemistry was used to investigate the nature of lithium bonding in a carbon lattice unlike graphite. The lithium intercalated fullerene Li{sub n}-C{sub 60} was used as a model for our (non-graphitic) disordered carbon lattice. A dilithium-C{sub 60} system with a charge and multiplicity of (0,1) and a trilithium-C{sub 60} system with a charge and multiplicity of (0,4) were investigated. The spatial distribution of lithium ions in an electrochemical cell containing this novel disordered carbon material was investigated in situ by Li-7 NMR using an electrochemical cell that was incorporated into a toroid cavity nuclear magnetic resonance (NMR) imager. The concentration of solvated Li{sup +} ions in the carbon anode appears to be larger than in the bulk electrolyte, is substantially lower near the copper/carbon interface, and does not change with cell charging.

Sandi, G.; Gerald, R., II; Scanlon, L. G.; Carrado, K. A.; Winans, R. E.

1998-01-07T23:59:59.000Z

299

A MULTI-LENGTH SCALE APPROACH TO CORRELATING SOLID OXIDE FUEL CELL POROUS CATHODE MICROSTRUCTURE TO ELECTROCHEMICAL PERFORMANCE  

E-Print Network [OSTI]

........................................................................................................27 3 COMPREHENSIVE QUANTIFICATION OF POROUS LSCF CATHODE MICROSTRUCTURE AND ELECTROCHEMICAL IMPEDANCE

Florida, University of

300

Local electrochemical functionality in energy storage materials...  

Office of Scientific and Technical Information (OSTI)

devices by scanning probe microscopies: Status and perspectives Re-direct Destination: Energy storage and conversion systems are an integral component of emerging green...

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Electrochemical Membrane for Carbon Dioxide Separation and Power Generation  

SciTech Connect (OSTI)

uelCell Energy, Inc. (FCE) has developed a novel system concept for separation of carbon dioxide (CO2) from greenhouse gas (GHG) emission sources using an electrochemical membrane (ECM). The salient feature of the ECM is its capability to produce electric power while capturing CO2 from flue gas, such as from an existing pulverized coal (PC) plant. Laboratory scale testing of the ECM has verified the feasibility of the technology for CO2 separation from simulated flue gases of PC plants as well as combined cycle power plants and other industrial facilities. Recently, FCE was awarded a contract (DE-FE0007634) from the U.S. Department of Energy to evaluate the use of ECM to efficiently and cost effectively separate CO2 from the emissions of existing coal fired power plants. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from flue gas of an existing PC plant with no more than 35% increase in the cost of electricity (COE) produced by the plant. The specific objectives and related activities planned for the project include: 1) conduct bench scale tests of a planar membrane assembly consisting of ten or more cells of about 0.8 m2 area each, 2) develop the detailed design for an ECM-based CO2 capture system applied to an existing PC plant, and 3) evaluate the effects of impurities (pollutants such as SO2, NOx, Hg) present in the coal plant flue gas by conducting laboratory scale performance tests of the membrane. The results of this project are anticipated to demonstrate that the ECM is an advanced technology, fabricated from inexpensive materials, based on proven operational track records, modular, scalable to large sizes, and a viable candidate for >90% carbon capture from existing PC plants. In this paper, the fundamentals of ECM technology including: material of construction, principal mechanisms of operation, carbon capture test results and the benefits of applications to PC plants will be presented.

Jolly, Stephen; Ghezel-Ayagh, Hossein; Hunt, Jennifer; Patel, Dilip; Steen, William A.; Richardson, Carl F.; Marina, Olga A.

2012-12-28T23:59:59.000Z

302

Electrical modeling of semiconductor bridge (SCB) BNCP detonators with electrochemical capacitor firing sets  

SciTech Connect (OSTI)

In this paper the authors describe computer models that simulate the electrical characteristics and hence, the firing characteristics and performance of a semiconductor bridge (SCB) detonator for the initiation of BNCP [tetraammine-cis-bis (5-nitro-2H-tetrazolato-N{sup 2}) cobalt(III) perchlorate]. The electrical data and resultant models provide new insights into the fundamental behavior of SCB detonators, particularly with respect to the initiation mechanism and the interaction of the explosive powder with the SCB. One model developed, the Thermal Feedback Model, considers the total energy budget for the system, including the time evolution of the energy delivered to the powder by the electrical circuit, as well as that released by the ignition and subsequent chemical reaction of the powder. The authors also present data obtained using a new low-voltage firing set which employed an advanced electrochemical capacitor having a nominal capacitance of 350,000 {micro}F at 9 V, the maximum voltage rating for this particular device. A model for this firing set and detonator was developed by making measurements of the intrinsic capacitance and equivalent series resistance (ESR < 10 m{Omega}) of a single device. This model was then used to predict the behavior of BNCP SCB detonators fired alone, as well as in a multishot, parallel-string configuration using a firing set composed of either a single 9 V electrochemical capacitor or two of the capacitors wired in series and charged to 18 V.

Marx, K.D. [Sandia National Labs., Livermore, CA (United States); Ingersoll, D.; Bickes, R.W. Jr. [Sandia National Labs., Albuquerque, NM (United States)

1998-11-01T23:59:59.000Z

303

The electrochemical performance of ordered mesoporous carbon/nickel compounds composite material for supercapacitor  

SciTech Connect (OSTI)

A series of high performance ordered mesoporous carbon/nickel compounds composites have been synthesized by a combination of incipient wetness impregnation and hydrothermal method for the first time. X-ray diffraction (XRD), N{sub 2} adsorption/desorption isotherms and transmission electron microscopy (TEM) are used to characterize the composites derived at the hydrothermal temperature of 125, 150, 175, 200, 250, 275 and 300 {sup o}C. The formation of nanosized nickel compounds, fully inside the mesopore system, was confirmed with XRD and TEM. An N{sub 2} adsorption/desorption isotherms measurements still revealed mesoporosity for the host/guest compounds. It is noteworthy that an OMC/nickel nitrate hydroxide hydrate composite (OMCN-150) exhibits more excellent performance. Based on the various hydrothermal temperatures of the composite, the capacitance of an OMCN-150 delivering the best electrochemical performance is about 2.4 (5 mV s{sup -1}) and 1.5 (50 mV s{sup -1}) times of the pristine OMC. The capacitance retention of an OMCN-150 is 96.1%, which indicates that the electrochemical performance of the supercapacitor is improved greatly, and represents novel research and significant advances in the field of electrode composite materials for supercapacitor. -- Graphical abstract: A series of high performance nickel compound/ordered mesoporous carbon composites were synthesized by a combination of incipient wetness impregnation and hydrothermal method for the first time. Display Omitted

Feng, Jicheng; Zhao, Jiachang; Tang, Bohejin; Liu, Ping [College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620 (China); Xu, Jingli, E-mail: jinglixu@sues.edu.c [College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620 (China)

2010-12-15T23:59:59.000Z

304

Electrochemical behavior of carbon aerogels derived from different precursors  

SciTech Connect (OSTI)

The ability to tailor the structure and properties of porous carbons has led to their increased use as electrodes in energy storage devices. Our research focuses on the synthesis and characterization of carbon aerogels for use in electrochemical double layer capacitors. Carbon aerogels are formed from the sol-gel polymerization of (1) resorcinol-formaldehyde or (2) phenolic-furfural, followed by supercritical drying from carbon dioxide, and subsequent pyrolysis in an inert atmosphere. These materials can be produced as monoliths, composites, thin films, powders, or microspheres. In all cases, the areogels have an open-cell structure with an ultrafine pore size (<100 nm), high surface area (400-1 100 m{sup 2}/g), and a solid matrix composed of interconnected particles, fibers, or platelets with characteristic dimensions of 10 nm. This paper examines the effects of the carbon precursor and processing conditions on electrochemical performance in aqueous and organic electrolytes.

Pekala, R.W.; Alviso, C.T.; Nielson, J.K.; Tran, T.D. [Lawrence Livermore National Lab., CA (United States); Reynolds, G.M.; Dresshaus, M.S. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Physics

1995-04-01T23:59:59.000Z

305

Electrochemical hydrogen termination of boron-doped diamond  

SciTech Connect (OSTI)

Boron-doped diamond is a promising transducer material for numerous devices which are designed for contact with electrolytes. For optimized electron transfer the surface of diamond needs to be hydrogen terminated. Up to now H-termination of diamond is done by plasma chemical vapor deposition techniques. In this paper, we show that boron-doped diamond can be H-terminated electrochemically by applying negative voltages in acidic solutions. Electrochemical H-termination generates a clean surface with virtually no carbon-oxygen bonds (x-ray photoelectron spectroscopy), a reduced electron affinity (scanning electron microscopy), a highly hydrophobic surface (water contact angle), and a fast electron exchange with Fe(CN){sub 6}{sup -3/-4} (cyclic voltammetry).

Hoffmann, Rene; Kriele, Armin; Obloh, Harald; Hees, Jakob; Wolfer, Marco; Smirnov, Waldemar; Yang Nianjun; Nebel, Christoph E. [Fraunhofer Institute for Applied Solid State Physics (IAF), Tullastrasse 72, Freiburg 79108 (Germany)

2010-08-02T23:59:59.000Z

306

Corrosion protection of ENIG surface finishing using electrochemical methods  

SciTech Connect (OSTI)

Four types of thin film coating were carried out on copper for electronic materials by the electroless plating method at a pH range from 3 to 9. The coating performance was evaluated by electrochemical impedance spectroscopy and potentiodynamic polarization testing in a 3.5 wt.% NaCl solution. In addition, atomic force microscopy and X-ray diffraction were also used to analyze the coating surfaces. The electrochemical behavior of the coatings was improved using the electroless nickel plating solution of pH 5. The electroless nickel/immersion gold on the copper substrate exhibited high protective efficiency, charge transfer resistance and very low porosity, indicating an increase in corrosion resistance. Atomic force microscopy and X-ray diffraction analyses confirmed the surface uniformity and the formation of the crystalline-refined NiP {l_brace}1 2 2{r_brace} phase at pH 5.

Bui, Q.V.; Nam, N.D.; Choi, D.H.; Lee, J.B.; Lee, C.Y. [Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Cheoncheon-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)] [Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Cheoncheon-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kar, A. [National Metallurgical Laboratory (CSIR), Jamshedpur 831007 (India)] [National Metallurgical Laboratory (CSIR), Jamshedpur 831007 (India); Kim, J.G. [Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Cheoncheon-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)] [Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Cheoncheon-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Jung, S.B., E-mail: sbjung@skku.ac.kr [Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Cheoncheon-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)

2010-03-15T23:59:59.000Z

307

Continuous-feed electrochemical cell with nonpacking particulate electrode  

DOE Patents [OSTI]

An electrochemical cell providing full consumption of electrochemically active particles in a nonpacking, electrolyte-permeable bed has a tapered cell cavity bounded by two nonparallel surfaces separated by a distance that promotes bridging of particles across the cavity. The gap/particle size ratio is maintained as the particles are consumed, decrease in size, and travel from the point of entry to the narrower end of the cell. A cell of this configuration supports a bed of low packing density maintained in a dynamic steady state by alternate formation and collapse of particle bridges across the gap and associated voids over the entire active area of the cell. The cell design can be applied to refuelable zinc/air cells and zinc/ferrocyanide storage batteries. 6 figs.

Cooper, J.F.

1995-07-18T23:59:59.000Z

308

Machinability of a Stainless Steel by Electrochemical Discharge Microdrilling  

SciTech Connect (OSTI)

Due to the chemical elements included in their structure for ensuring an increased resistance to the environment action, the stainless steels are characterized by a low machinability when classical machining methods are applied. For this reason, sometimes non-traditional machining methods are applied, one of these being the electrochemical discharge machining. To obtain microholes and to evaluate the machinability by electrochemical discharge microdrilling, test pieces of stainless steel were used for experimental research. The electrolyte was an aqueous solution of sodium silicate with different densities. A complete factorial plan was designed to highlight the influence of some input variables on the sizes of the considered machinability indexes (electrode tool wear, material removal rate, depth of the machined hole). By mathematically processing of experimental data, empirical functions were established both for stainless steel and carbon steel. Graphical representations were used to obtain more suggestive vision concerning the influence exerted by the considered input variables on the size of the machinability indexes.

Coteata, Margareta; Pop, Nicolae; Slatineanu, Laurentiu ['Gheorghe Asachi' Technical University of Iasi, Department of Machine Manufacturing Technology, Blvd. D Mangeron 59A, 700050 Iasi (Romania); Schulze, Hans-Peter [Otto-von-Guericke-University Magdeburg, Institute of Fundamental Electrical Engineering and EMC Universitaetsplatz 2, D-39106 Magdeburg (Germany); Besliu, Irina [University 'Stefan cel Mare' of Suceava, Department of Technologies and Management, Str. Universitatii, 13, 720 229 Suceava (Romania)

2011-05-04T23:59:59.000Z

309

Structures and fabrication techniques for solid state electrochemical devices  

DOE Patents [OSTI]

Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

2012-10-09T23:59:59.000Z

310

Polymer-electrolyte membrane, electrochemical fuel cell, and related method  

DOE Patents [OSTI]

A polymer-electrolyte membrane is presented. The polymer-electrolyte membrane comprises an acid-functional polymer, and an additive incorporated in at least a portion of the membrane. The additive comprises a fluorinated cycloaliphatic additive, a hydrophobic cycloaliphatic additive, or combinations thereof, wherein the additive has a boiling point greater than about 120.degree. C. An electrochemical fuel cell including the polymer-electrolyte membrane, and a related method, are also presented.

Krishnan, Lakshmi; Yeager, Gary William; Soloveichik, Grigorii Lev

2014-12-09T23:59:59.000Z

311

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

1986-01-01T23:59:59.000Z

312

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA); Zymboly, Gregory E. (Penn Hills Township, Allegheny County, PA)

1985-01-01T23:59:59.000Z

313

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

1987-01-01T23:59:59.000Z

314

Structures and fabrication techniques for solid state electrochemical devices  

DOE Patents [OSTI]

Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

2008-04-01T23:59:59.000Z

315

Understanding the operation and use of high temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes were constructed and tested along with mass loss coupons in a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 450 to 600 C. Corrosion rates for ash-covered mild steel, 304L SS, and 316L SS probes using electrochemical techniques were a function of time, temperature, and process environment. Correlation between electrochemical and mass loss corrosion rates was good.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Cayard, Michael S. (InterCorr International Inc.); Eden, David A. (InterCorr International Inc.)

2004-01-01T23:59:59.000Z

316

Electrochemical kinetics of thin film vanadium pentoxide cathodes for lithium batteries  

E-Print Network [OSTI]

Electrochemical experiments were performed to investigate the processing-property-performance relations of thin film vanadium pentoxide cathodes used in lithium batteries. Variations in microstructures were achieved via ...

Mui, Simon C., 1976-

2005-01-01T23:59:59.000Z

317

The Electrochemical Society Interface Fall 2009 53 From Laboratory Breakthrough to Technological Realization  

E-Print Network [OSTI]

The Electrochemical Society Interface · Fall 2009 53 From Laboratory Breakthrough to Technological emissions, suitability to hydrogen, and low noise and mechanical vibrations. Unlike other fuel cells

318

E-Print Network 3.0 - ac impedance electrochemical Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

we use the fractional Fourier transform for the spectral noise impedance. Figure... , "Electrochemical impedance and noise," in ... Source: Chen, YangQuan - Department of...

319

E-Print Network 3.0 - aluminum alloy electrochemical Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: aluminum alloy electrochemical Page: << < 1 2 3 4 5 > >> 1 Reaction of Aluminum with Water to Produce...

320

Thermal and Electrochemical Performance of a High-Temperature Steam Electrolysis Stack  

SciTech Connect (OSTI)

A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of solid-oxide electrolysis cell technology for hydrogen production from steam. We are conducting a progression of electrolysis stack testing activities, at increasing scales, along with a continuation of supporting research activities in the areas of materials development, single-cell testing, detailed computational fluid dynamics (CFD) and systems modeling. This paper will present recent experimental results obtained from testing of planar solid-oxide stacks operating in the electrolysis mode. The hydrogen-production and electrochemical performance of these stacks will be presented, over a range of operating conditions. In addition, internal stack temperature measurements will be presented, with comparisons to computational fluid dynamic predictions.

J. O'Brien; C. Stoots; G. Hawkes; J. Hartvigsen

2006-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Electrochemical flowcell for in-situ investigations by soft x-ray absorption and emission spectroscopy  

SciTech Connect (OSTI)

A new liquid flow-cell designed for electronic structure investigations at the liquid-solid interface by soft X-ray absorption and emission spectroscopy is presented. A thin membrane serves simultaneously as a substrate for the working electrode and solid state samples as well as for separating the liquid from the surrounding vacuum conditions. In combination with counter and reference electrodes this approach allows in-situ studies of electrochemical deposition processes and catalytic reactions at the liquid-solid interface in combination with potentiostatic measurements. As model system in-situ monitoring of the deposition process of Co metal from a 10 mM CoCl{sub 2} aqueous solution by X-ray absorption and emission spectroscopy is presented.

Schwanke, C.; Lange, K. M., E-mail: Kathrin.lange@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Solar Fuels, Albert-Einstein-Straße 15, 12489 Berlin (Germany); Golnak, R.; Xiao, J. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Methods for Material Development, Albert-Einstein-Straße 15, 12489 Berlin (Germany)

2014-10-15T23:59:59.000Z

322

Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for In-situ Characterization of Mixed Wastes  

SciTech Connect (OSTI)

Required characterizations of the DOE's transuranic (TRU) and mixed wastes (MW) before disposing and treatment of the wastes are currently costly and have lengthy turnaround. Research toward developing faster and more sensitive characterization and analysis tools to reduce costs and accelerate throughputs is therefore desirable. This project is aimed at the development of electrochemical sensors, specific to toxic transition metals, uranium, and technetium, that can be integrated into the portable sensor systems. This system development will include fabrication and performance evaluation of electrodes as well as understanding of electrochemically active sites on the electrodes specifically designed for toxic metals, uranium and technetium detection. Subsequently, these advanced measurement units will be incorporated into a microfluidic prototype specifically designed and fabricated for field-deployable characterizations of such species. The electrochemical sensors being invest igated are based on a new class of nanoengineered sorbents, Self-Assembled Monolayer on Mesoporous Supports (SAMMS). SAMMS are highly efficient sorbents due to their interfacial chemistry that can be fine-tuned to selectively sequester a specific target species. Adsorptive stripping voltammetry (AdSV) will be performed on two classes of electrodes: the SAMMS modified carbon paste electrodes, and the SAMMS thin film immobilized on microelectrode arrays. Interfacial chemistry and electrochemistry of metal species on the surfaces of SAMMS-based electrodes will be studied. This fundamental knowledge is required for predicting how the sensors will perform in the real wastes which consist of many interferences/ligands and a spectrum of pH levels. The best electrode for each specific waste constituent will be integrated onto the portable microfluidic platform. Efforts will also be focused on testing the portable microfluidics/electrochemical sensor systems with the selected MW and T RU waste samples at the Hanford site. The outcome of this project will lead to the development of a portable analytical system for in-situ characterization of MW and TRU wastes. The technology will greatly reduce costs and accelerate throughputs for characterizations of MW and TRU wastes.

Lin, Yuehe; Wang, Joseph

2004-06-01T23:59:59.000Z

323

Silicon on insulator achieved using electrochemical etching  

DOE Patents [OSTI]

Bulk crystalline silicon wafers are transferred after the completion of circuit fabrication to form thin films of crystalline circuitry on almost any support, such as metal, semiconductor, plastic, polymer, glass, wood, and paper. In particular, this technique is suitable to form silicon-on-insulator (SOI) wafers, whereby the devices and circuits formed exhibit superior performance after transfer due to the removal of the silicon substrate. The added cost of the transfer process to conventional silicon fabrication is insignificant. No epitaxial, lift-off, release or buried oxide layers are needed to perform the transfer of single or multiple wafers onto support members. The transfer process may be performed at temperatures of 50.degree. C. or less, permits transparency around the circuits and does not require post-transfer patterning. Consequently, the technique opens up new avenues for the use of integrated circuit devices in high-brightness, high-resolution video-speed color displays, reduced-thickness increased-flexibility intelligent cards, flexible electronics on ultrathin support members, adhesive electronics, touch screen electronics, items requiring low weight materials, smart cards, intelligent keys for encryption systems, toys, large area circuits, flexible supports, and other applications. The added process flexibility also permits a cheap technique for increasing circuit speed of market driven technologies such as microprocessors at little added expense.

McCarthy, Anthony M. (Menlo Park, CA)

1997-01-01T23:59:59.000Z

324

Silicon on insulator achieved using electrochemical etching  

DOE Patents [OSTI]

Bulk crystalline silicon wafers are transferred after the completion of circuit fabrication to form thin films of crystalline circuitry on almost any support, such as metal, semiconductor, plastic, polymer, glass, wood, and paper. In particular, this technique is suitable to form silicon-on-insulator (SOI) wafers, whereby the devices and circuits formed exhibit superior performance after transfer due to the removal of the silicon substrate. The added cost of the transfer process to conventional silicon fabrication is insignificant. No epitaxial, lift-off, release or buried oxide layers are needed to perform the transfer of single or multiple wafers onto support members. The transfer process may be performed at temperatures of 50 C or less, permits transparency around the circuits and does not require post-transfer patterning. Consequently, the technique opens up new avenues for the use of integrated circuit devices in high-brightness, high-resolution video-speed color displays, reduced-thickness increased-flexibility intelligent cards, flexible electronics on ultrathin support members, adhesive electronics, touch screen electronics, items requiring low weight materials, smart cards, intelligent keys for encryption systems, toys, large area circuits, flexible supports, and other applications. The added process flexibility also permits a cheap technique for increasing circuit speed of market driven technologies such as microprocessors at little added expense. 57 figs.

McCarthy, A.M.

1997-10-07T23:59:59.000Z

325

Electrochemical synthesis of nanosized hydroxyapatite by pulsed direct current method  

SciTech Connect (OSTI)

Synthesis of nanosized of hydroxyapatite (HA) by electrochemical pulsed direct current (PDC) method has been studied. The aim of this work is to study the influence of various PDC parameters (pH initial, electrode distance, duty cycle, frequency, and amplitude) on particle surface area of HA powders. The electrochemical synthesis was prepared in solution Ca{sup 2+}/EDTA{sup 4?}/PO{sub 4}{sup 3+} at concentration 0.25/0.25/0.15 M for 24 h. The electrochemical cell was consisted of two carbon rectangular electrodes connected to a function generator to produce PDC. There were two treatments for particles after electrosynthesized, namely without aging and aged for 2 days at 40 °C. For both cases, the particles were filtered and washed by demineralized water to eliminate the impurities and unreacted reactants. Then, the particles were dried at 100 °C for 2 days. The dried particles were characterized by X-ray diffraction, surface area analyzer, scanning electron microscopy (SEM), Fourier transform infrared spectra and thermogravimetric and differential thermal analysis. HA particles can be produced when the initial pH > 6. The aging process has significant effect on the produced HA particles. SEM images of HA particles showed that the powders consisted of agglomerates composed of fine crystallites and have morphology plate-like and sphere. The surface area of HA particles is in the range of 25 – 91 m{sup 2}/g. The largest particle surface area of HA was produced at 4 cm electrode distance, 80% cycle duty, frequency 0.1 Hz, amplitude 9 V and with aging process.

Nur, Adrian; Rahmawati, Alifah; Ilmi, Noor Izzati; Affandi, Samsudin; Widjaja, Arief [Departement of Chemical Engineering, Faculty of Industrial Technology, Sepuluh Nopember Institute of Technology, Kampus ITS Sukolilo, Surabaya 60111 (Indonesia)

2014-02-24T23:59:59.000Z

326

Water at an electrochemical interface - a simulation study  

SciTech Connect (OSTI)

The results of molecular dynamics simulations of the properties of water in an aqueous ionic solution close to an interface with a model metallic electrode are described. In the simulations the electrode behaves as an ideally polarizable hydrophilic metal, supporting image charge interactions with charged species, and it is maintained at a constant electrical potential with respect to the solution so that the model is a textbook representation of an electrochemical interface through which no current is passing. We show how water is strongly attracted to and ordered at the electrode surface. This ordering is different to the structure that might be imagined from continuum models of electrode interfaces. Further, this ordering significantly affects the probability of ions reaching the surface. We describe the concomitant motion and configurations of the water and ions as functions of the electrode potential, and we analyze the length scales over which ionic atmospheres fluctuate. The statistics of these fluctuations depend upon surface structure and ionic strength. The fluctuations are large, sufficiently so that the mean ionic atmosphere is a poor descriptor of the aqueous environment near a metal surface. The importance of this finding for a description of electrochemical reactions is examined by calculating, directly from the simulation, Marcus free energy profiles for transfer of charge between the electrode and a redox species in the solution and comparing the results with the predictions of continuum theories. Significant departures from the electrochemical textbook descriptions of the phenomenon are found and their physical origins are characterized from the atomistic perspective of the simulations.

Willard, Adam; Reed, Stewart; Madden, Paul; Chandler, David

2008-08-22T23:59:59.000Z

327

Separation of CO2 from flue gas using electrochemical cells  

SciTech Connect (OSTI)

ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

2010-06-01T23:59:59.000Z

328

Integrated seal for high-temperature electrochemical device  

DOE Patents [OSTI]

The present invention provides electrochemical device structures having integrated seals, and methods of fabricating them. According to various embodiments the structures include a thin, supported electrolyte film with the electrolyte sealed to the support. The perimeter of the support is self-sealed during fabrication. The perimeter can then be independently sealed to a manifold or other device, e.g., via an external seal. According to various embodiments, the external seal does not contact the electrolyte, thereby eliminating the restrictions on the sealing method and materials imposed by sealing against the electrolyte.

Tucker, Michael C; Jacobson, Craig P

2013-07-16T23:59:59.000Z

329

Corner heating in rectangular solid oxide electrochemical cell generators  

DOE Patents [OSTI]

Disclosed is an improvement in a solid oxide electrochemical cell generator 1 having a rectangular design with four sides that meet at corners, and containing multiplicity of electrically connected fuel cells 11, where a fuel gas is passed over one side of said cells and an oxygen containing gas is passed into said cells, and said fuel is burned to form heat, electricity, and an exhaust gas. The improvement comprises passing the exhaust gases over the multiplicity of cells 11 in such a way that more of the heat in said exhaust gases flows at the corners of the generator, such as through channels 19.

Reichner, Philip (Plum Boro, PA)

1989-01-01T23:59:59.000Z

330

Electrochemical and structural characterization of ordered graphite electrodes  

SciTech Connect (OSTI)

Highly oriented pyrolytic graphite (HOPG) was utilized to examine the structure/reactivity relationships for carbon electrodes in a well-defined matter. The basal plane of HOPG is ideal for this type of study due to its well-ordered surface structure. The electrochemical reactivity of basal plane HOPG was determined in terms of adsorption of anthraquinone 2,6-desulfonate ([Gamma][sub 2,6-AQDS]), the heterogeneous electron transfer rate constant of the ferro/ferricyanide redox couple (k[degrees] for Fe(CN)[sup [minus]3/[minus]4][sub 6]) and electrode capacitance (C[degrees]). [Gamma][sub 2,6-AQDS] tracks defects at basal plane HOPG electrodes indicating that the adsorption of 2,6-AQDS is a good marker for defects on the surface of basal plane HOPG. When measured on the same basal plane surface, k[degrees] for Fe(CN)[sup [minus]3/[minus]4][sub 6] and C[degrees] correlate with [Gamma][sub 2,6-AQDS] indicating that all three electrochemical observables are controlled by the same surface variables. This illustrates the importance of surface defects on electrochemical activity at basal plane HOPG electrodes. The correlation between k[degrees] for Fe(CN)[sup [minus]3/[minus]4][sub 6], C[degrees] and [Gamma][sub 2,6-AQDS] enabled the evaluation of these parameters at near-perfect basal plane. The data indicate that basal plane HOPG exhibits anomalously low electrochemical reactivity. An investigation of basal plane HOPG electrodes with scanning tunneling microscopy (STM) revealed that defects, in the form of cleavage steps, cover 1% of the surface for the HOPG sample studied. Atomic scale STM images of step edges revealed that structural defects induce an electronic perturbation of the surface which occupies a significant area near the defect. [Gamma][sub 2,6-AQDS], k[degrees] for Fe(CN)[sup [minus]3/[minus]4][sub 6] and C[degrees] are influenced not only by the structural defect but also by the defect induced electronic perturbation.

McDermott, M.T.

1993-01-01T23:59:59.000Z

331

DOE-EMSP Project Report FY 04: Portable Analyzer Based on Microfluidics/Nanoengineered Electrochemical Sensors for In-situ Characterization of Mixed Wastes  

SciTech Connect (OSTI)

Required characterizations of the DOE's transuranic (TRU) and mixed wastes (MW) before disposing and treatment of the wastes are currently costly and have lengthy turnaround. Research toward developing faster and more sensitive characterization and analysis tools to reduce costs and accelerate throughputs is therefore desirable. This project is aimed at the development of electrochemical sensors, specific to toxic transition metals, uranium, and technetium, that can be integrated into the portable sensor systems. This system development will include fabrication and performance evaluation of electrodes as well as understanding of electrochemically active sites on the electrodes specifically designed for toxic metals, uranium and technetium detection. Subsequently, these advanced measurement units will be incorporated into a microfluidic prototype specifically designed and fabricated for field-deployable characterizations of such species. The electrochemical sensors being investigate d are based on a new class of nanoengineered sorbents, Self-Assembled Monolayer on Mesoporous Supports (SAMMS). SAMMS are highly efficient sorbents due to their interfacial chemistry that can be fine-tuned to selectively sequester a specific target species. Adsorptive stripping voltammetry (AdSV) will be performed on two classes of electrodes: the SAMMS modified carbon paste electrodes, and the SAMMS thin film immobilized on microelectrode arrays. Interfacial chemistry and electrochemistry of metal species on the surfaces of SAMMS-based electrodes will be studied. This fundamental knowledge is required for predicting how the sensors will perform in the real wastes which consist of many interferences/ligands and a spectrum of pH levels. The best electrode for each specific waste constituent will be integrated onto the portable microfluidic platform. Efforts will also be focused on testing the portable microfluidics/electrochemical sensor systems with the selected MW and TRU waste samples at the Hanford site. The outcome of this project will lead to the development of a portable analytical system for in-situ characterization of MW and TRU wastes. The technology will greatly reduce costs and accelerate throughputs for characterizations of MW and TRU wastes.

Lin, Yuehe; Yantasee, Wassana; Fryxell, Glen E.; Wang, Zheming; Wang, Joseph

2004-11-02T23:59:59.000Z

332

ENCH 473 Electrochemical Energy Engineering ENCH 648K Advanced Batteries and Fuel Cells  

E-Print Network [OSTI]

ENCH 473 Electrochemical Energy Engineering ENCH 648K Advanced Batteries and Fuel Cells Spring 2014 Syllabus Course: ENCH 473 Electrochemical Energy Engineering ENCH: 648K Advanced Batteries and Fuel Cells, with emphasis on the principle and performance of batteries, supercapacitors and fuel cells. The objective

Rubloff, Gary W.

333

Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC  

E-Print Network [OSTI]

Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC Anand an electroless deposition process. The electrochemical oxidation behavior of the Co-coated electrodes is similar when compared to bare nickel oxide electrodes in the presence of cathode gas. The solubility decreased

Popov, Branko N.

334

AN ELECTROCHEMICAL INTERFACE FOR INTEGRATED Peter Kim, Neeraj Kohli, Brian Hassler, Nathan Dotson, Andrew Mason,  

E-Print Network [OSTI]

AN ELECTROCHEMICAL INTERFACE FOR INTEGRATED BIOSENSORS Peter Kim, Neeraj Kohli, Brian Hassler, Nathan Dotson, Andrew Mason, R. Mark Worden, and Robert Ofoli Michigan State University East Lansing. Protein-based electrochemical biosensors are ideally suited for this purpose, because they provide

Mason, Andrew

335

Quantification of the electrochemical proton gradient and activation of ATP synthase in leaves  

E-Print Network [OSTI]

Quantification of the electrochemical proton gradient and activation of ATP synthase in leaves Available online 12 April 2008 Keywords: ATP synthase Electrochemical proton gradient Membrane potential We of the ATP synthase (Junge, W., Rumberg, B. and Schröder, H., Eur. J. Biochem. 14 (1970) 575

336

Ultrathin Polypeptide Multilayer Films for the Fabrication of Model Liquid/Liquid Electrochemical Interfaces  

E-Print Network [OSTI]

in ion selective electrodes, and the mechanisms of phase transfer catalysis reactions.1-3 Electrochemical/L electrochemical research has been performed previously in which one of the two phases was replaced by either agar on a graphite electrode immersed in an aqueous solution for the study of electron transfer across this L/L (film

337

Anal. Chem. 1986, 58,239-242 239 for probing diffusion layers in electrochemical processes for  

E-Print Network [OSTI]

Anal. Chem. 1986, 58,239-242 239 for probing diffusion layers in electrochemical processes to the total signal or noise depending on its cor- relation with the excitation beam modulation. For example. R. "Electrochemical Methods"; Wiiey: New York, 1980. (8) Mandelis, A.; Royce, B. S.N. Appl. Opt

Mandelis, Andreas

338

A microfluidic-based electrochemical biochip for label-free diffusion-restricted DNA hybridization analysis  

E-Print Network [OSTI]

A microfluidic-based electrochemical biochip for label-free diffusion-restricted DNA hybridization online 16 May 2012 Keywords: Electrochemical impedance spectroscopy DNA hybridization biosensor Biochip. However, as device footprints decrease and their complexity increase, the signal-to-noise ratio

Ghodssi, Reza

339

Reverse-bias leakage current reduction in GaN Schottky diodes by electrochemical surface treatment  

E-Print Network [OSTI]

Reverse-bias leakage current reduction in GaN Schottky diodes by electrochemical surface treatment Received 15 July 2002; accepted 27 December 2002 An electrochemical surface treatment has been developed to the large power consumption and noise levels that can be present in circuits that incorporate such devices.1

Yu, Edward T.

340

A Novel Multi-Working Electrode Potentiostat for Electrochemical Detection of Metabolites  

E-Print Network [OSTI]

A Novel Multi-Working Electrode Potentiostat for Electrochemical Detection of Metabolites Daniela single-chip and multiplexed read-out circuit for multi-electrode electrochemical sensors, in standard 0-circuited to the reference one, in order to nullify the injected current inside the counter. Low noise and low energy

De Micheli, Giovanni

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Direct growth of nanotubes and graphene nanoflowers on electrochemical platinum electrodes  

E-Print Network [OSTI]

Direct growth of nanotubes and graphene nanoflowers on electrochemical platinum electrodes Irene the possibility of integrating the hybrid electrodes in biochip applications. 1. Introduction Electrochemical the signal-to-noise ratio and reduce the inuence of the solution resistance.2 Monitoring endogenous

De Micheli, Giovanni

342

Current status of environmental, health, and safety issues of electrochemical capacitors for advanced vehicle applications  

SciTech Connect (OSTI)

Electrochemical capacitors are a candidate for traction power assists in hybrid electric vehicles (HEVs). Other advanced automotive applications, while not the primary focus of current development efforts, are also possible. These include load leveling high-energy batteries, power conditioning electronics, electrically hated catalysts, electric power steering, and engine starter power. Higher power and longer cycle life are expected for electrochemical capacitors than for batteries. Evaluation of environmental, health, and safety (EH and S) issues of electrochemical capacitors is an essential part of the development and commercialization of electrochemical capacitors for advanced vehicles. This report provides an initial EH and S assessment. This report presents electrochemical capacitor electrochemistry, materials selection, intrinsic material hazards, mitigation of those hazards, environmental requirements, pollution control options, and shipping requirements. Most of the information available for this assessment pertains to commercial devices intended for application outside the advanced vehicle market and to experiment or prototype devices. Electrochemical capacitors for power assists in HEVs are not produced commercially now. Therefore, materials for advanced vehicle electrochemical capacitors may change, and so would the corresponding EH and S issues. Although changes are possible, this report describes issues for likely electrochemical capacitor designs.

Vimmerstedt, L.J.; Hammel, C.J.

1997-04-01T23:59:59.000Z

343

Electrochemical control of quantum interference in anthraquinone-based molecular switches  

E-Print Network [OSTI]

Electrochemical control of quantum interference in anthraquinone-based molecular switches Troels properties of a recently proposed anthraquinone-based electrochemical switch. Robust conductance on in the anthraquinone but absent in the hydroquinone molecular bridge. A simple explanation of the interference effect

Thygesen, Kristian

344

Embedding Covalency into Metal Catalysts for Efficient Electrochemical Conversion of CO2  

E-Print Network [OSTI]

- throughput screening to propose silver-based catalysts for efficient electrochemical reduction of CO2 to CO. Many researchers anticipate the efficient transformation of CO2 from various emission sources into moreEmbedding Covalency into Metal Catalysts for Efficient Electrochemical Conversion of CO2 Hyung

Goddard III, William A.

345

Electrochemical energy storage device based on carbon dioxide as electroactive species  

DOE Patents [OSTI]

An electrochemical energy storage device comprising a primary positive electrode, a negative electrode, and one or more ionic conductors. The ionic conductors ionically connect the primary positive electrode with the negative electrode. The primary positive electrode comprises carbon dioxide (CO.sub.2) and a means for electrochemically reducing the CO.sub.2. This means for electrochemically reducing the CO.sub.2 comprises a conductive primary current collector, contacting the CO.sub.2, whereby the CO.sub.2 is reduced upon the primary current collector during discharge. The primary current collector comprises a material to which CO.sub.2 and the ionic conductors are essentially non-corrosive. The electrochemical energy storage device uses CO.sub.2 as an electroactive species in that the CO.sub.2 is electrochemically reduced during discharge to enable the release of electrical energy from the device.

Nemeth, Karoly; van Veenendaal, Michel Antonius; Srajer, George

2013-03-05T23:59:59.000Z

346

SERS study of the electrochemical reduction of pyrazine on a silver Alexandre G. Brolo and Donald E. Irish*  

E-Print Network [OSTI]

electrochemically-reduced pyrazine are reported. The spectral ¤ This paper was submitted to mark the 70th birthdaySERS study of the electrochemical reduction of pyrazine on a silver electrode¤ Alexandre G. Brolo, University of W aterloo, W aterloo, ON, Canada, N2L 3G1 The electrochemical reduction of pyrazine (pz

Brolo, Alexandre G.

347

A controlled microfluidic electrochemical lab-on-a-chip for label-free diffusion-restricted DNA hybridization analysis  

E-Print Network [OSTI]

A controlled microfluidic electrochemical lab-on-a-chip for label-free diffusion-restricted DNA hybridization sensing Microfluidics Valve Label-free detection Electrochemical impedance spectroscopy Restricted-of-care. Here, we present a microfluidic LOC, with 3 Ã? 3 arrayed electrochemical sensors for the analysis of DNA

Ghodssi, Reza

348

Vanadium oxide nanodisks: Synthesis, characterization, and electrochemical properties  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Highly crystallined VO{sub 1.6}{center_dot}H{sub 2}O nanodisks have been synthesized by using a novel solid-solution-solid growth process. Black-Right-Pointing-Pointer The nanodisks are assembled from nanoparticles. Black-Right-Pointing-Pointer PEG-4000 plays an important role for the formation of the nanodisks. Black-Right-Pointing-Pointer The as-synthesized nanodisks exhibit good electrochemical behavior. -- Abstract: Highly crystallined VO{sub 1.6}{center_dot}H{sub 2}O nanodisks assembled from nanoparticles have been successfully fabricated under hydrothermal conditions by using bulk V{sub 2}O{sub 5} and Na{sub 2}S{sub 2}O{sub 3} as the starting materials in the presence of surfactant polyethylene glycol 4000 (PEG-4000). The nanodisks have a diameter of 200 nm and thickness of 40 nm. Hollow nanodisks are occasionally observed, which is similar to Chinese ancient copper coins. The formation of nanodisks can be ascribed to a novel solid-solution-solid growth mechanism. Compared with other methods, the solid state transformation method is simple and economic. In addition, the nanodisks exhibit good electrochemical behavior and promising to be used in lithium-ion battery.

Ren, Ling [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)] [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China); Cao, Minhua, E-mail: caomh@bit.edu.cn [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)] [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China); Shi, Shufeng [Department of Chemistry, Northeast Normal University, Changchun 13324 (China)] [Department of Chemistry, Northeast Normal University, Changchun 13324 (China); Hu, Changwen [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)] [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)

2012-01-15T23:59:59.000Z

349

Exploratory Technology Research Program for Electrochemical Energy Storage - Annual Report for 1998  

SciTech Connect (OSTI)

The US Department of Energy's (DOE) Office of Advanced Automotive Technologies conducts research and development on advanced rechargeable batteries for application in electric vehicles (EVs) and hybrid systems. Efforts are focused on advanced batteries that offer the potential for high performance and low life-cycle costs, both of which are necessary to permit significant penetration into commercial markets. DOE battery R and D supports two major programs: the US Advanced Battery Consortium (USABC), which develops advanced batteries for EVS, and the Partnership for a New Generation of Vehicles (PNGV), which seeks to develop passenger vehicles with a fuel economy equivalent to 80 mpg of gasoline. This report describes the activities of the Exploratory Technology Research (ETR) Program, managed by the Lawrence Berkeley National Laboratory (LBNL). The role of the ETR Program is to perform supporting research on the advanced battery systems under development by the USABC and PNGV Programs, and to evaluate new systems with potentially superior performance, durability and/or cost characteristics. The specific goal of the ETR Program is to identify the most promising electrochemical technologies and transfer them to the USABC, the battery industry and/or other Government agencies for further development and scale-up. This report summarizes the research, financial and management activities relevant to the ETR Program in CY 1998. This is a continuing program, and reports for prior years have been published; they are listed at the end of this Program Summary.

Kinoshita, K. (editor)

1999-06-01T23:59:59.000Z

350

Electrochemical properties of all solid state Li/S battery  

SciTech Connect (OSTI)

All-solid-state lithium/sulfur (Li/S) battery is prepared using siloxane cross-linked network solid electrolyte at room temperature. The solid electrolytes show high ionic conductivity and good electrochemical stability with lithium and sulfur. In the first discharge curve, all-solid-state Li/S battery shows three plateau potential regions of 2.4 V, 2.12 V and 2.00 V, respectively. The battery shows the first discharge capacity of 1044 mAh g{sup ?1}-sulfur at room temperature. This first discharge capacity rapidly decreases in 4th cycle and remains at 512 mAh g{sup ?1}-sulfur after 10 cycles.

Yu, Ji-Hyun; Park, Jin-Woo; Wang, Qing; Ryu, Ho-Suk; Kim, Ki-Won [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)] [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of); Ahn, Jou-Hyeon [Department of Chemical and Biological Engineering, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering, Gyeongsang National University, Jinju 660-701 (Korea, Republic of); Kang, Yongku [Korea Research Institute of Chemical Technology, Daejeon 305-600 (Korea, Republic of)] [Korea Research Institute of Chemical Technology, Daejeon 305-600 (Korea, Republic of); Wang, Guoxiu [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of) [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of); School of Chemistry and Forensic Science, University of Technology Sydney, Broadway, Sydney, NSW 2007 (Australia); Ahn, Hyo-Jun, E-mail: ahj@gnu.ac.kr [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)] [School of Materials Science and Engineering, WCUNGB, RIGET, Gyeongsang National University, Jinju 660-701 (Korea, Republic of)

2012-10-15T23:59:59.000Z

351

Method of making an electrolyte for an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN)

1996-01-01T23:59:59.000Z

352

Electrochemical method of producing eutectic uranium alloy and apparatus  

DOE Patents [OSTI]

An apparatus and method for continuous production of liquid uranium alloys through the electrolytic reduction of uranium chlorides. The apparatus includes an electrochemical cell formed from an anode shaped to form an electrolyte reservoir, a cathode comprising a metal, such as iron, capable of forming a eutectic uranium alloy having a melting point less than the melting point of pure uranium, and molten electrolyte in the reservoir comprising a chlorine or fluorine containing salt and uranium chloride. The method of the invention produces an eutectic uranium alloy by creating an electrolyte reservoir defined by a container comprising an anode, placing an electrolyte in the reservoir, the electrolyte comprising a chlorine or fluorine containing salt and uranium chloride in molten form, positioning a cathode in the reservoir where the cathode comprises a metal capable of forming an uranium alloy having a melting point less than the melting point of pure uranium, and applying a current between the cathode and the anode.

Horton, James A. (Livermore, CA); Hayden, H. Wayne (Oakridge, TN)

1995-01-01T23:59:59.000Z

353

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents [OSTI]

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Riley, B.; Szreders, B.E.

1988-04-26T23:59:59.000Z

354

Investigation of Electrochemical Recovery of Zirconium from Spent Nuclear Fuels  

SciTech Connect (OSTI)

This project uses both modeling and experimental studies to design optimal electrochemical technology methods for recovery of zirconium from used nuclear fuel rods for more effective waste management. The objectives are to provide a means of efficiently separating zirconium into metallic high-level waste forms and to support development of a process for decontamination of zircaloy hulls to enable their disposal as low- and intermediate-level waste. Modeling work includes extension of a 3D model previously developed by Seoul National University for uranium electrorefining by adding the ability to predict zirconium behavior. Experimental validation activities include tests for recovery of zirconium from molten salt solutions and aqueous tests using surrogate materials. *This is a summary of the FY 2013 progress for I-NERI project # 2010-001-K provided to the I-NERI office.

Michael Simpson; II-Soon Hwang

2014-06-01T23:59:59.000Z

355

Electro-chemical sensors, sensor arrays and circuits  

DOE Patents [OSTI]

An electro-chemical sensor includes a first electrode, a second electrode spaced apart from the first electrode, and a semiconductor channel in electrical contact with the first and second electrodes. The semiconductor channel includes a trapping material. The trapping material reduces an ability of the semiconductor channel to conduct a current of charge carriers by trapping at least some of the charge carriers to localized regions within the semiconductor channel. The semiconductor channel includes at least a portion configured to be exposed to an analyte to be detected, and the trapping material, when exposed to the analyte, interacts with the analyte so as to at least partially restore the ability of the semiconductor channel to conduct the current of charge carriers.

Katz, Howard E.; Kong, Hoyoul

2014-07-08T23:59:59.000Z

356

Battery paste compositions and electrochemical cells for use therewith  

DOE Patents [OSTI]

An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition are disclosed. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinyl sulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness. 2 figs.

Olson, J.B.

1999-02-16T23:59:59.000Z

357

Method of making an electrolyte for an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C. 9 figs.

Bates, J.B.; Dudney, N.J.

1996-04-30T23:59:59.000Z

358

Electrochemical separation and concentration of hydrogen sulfide from gas mixtures  

DOE Patents [OSTI]

A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4 -- or, in the case of H.sub.2 S, to S--. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

Winnick, Jack (Atlanta, GA); Sather, Norman F. (Naperville, IL); Huang, Hann S. (Darian, IL)

1984-10-30T23:59:59.000Z

359

DEMONSTRATION OF ELECTROCHEMICAL REMEDIATION TECHNOLOGIES-INDUCED COMPLEXATION  

SciTech Connect (OSTI)

The Project Team is submitting this Topical Report on the results of its bench-scale demonstration of ElectroChemical Remediation Technologies (ECRTs) and in particular the Induced Complexation (ECRTs-IC) process for remediation of mercury contaminated soils at DOE Complex sites. ECRTs is an innovative, in-situ, geophysically based soil remediation technology with over 50 successful commercial site applications involving remediation of over two million metric tons of contaminated soils. ECRTs-IC has been successfully used to remediate 220 cu m of mercury-contaminated sediments in the Union Canal, Scotland. In that operation, ECRTs-IC reduced sediment total mercury levels from an average of 243 mg/kg to 6 mg/kg in 26 days of operation. The clean up objective was to achieve an average total mercury level in the sediment of 20 mg/kg.

Barry L. Burks

2002-12-01T23:59:59.000Z

360

Battery paste compositions and electrochemical cells for use therewith  

DOE Patents [OSTI]

An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinylsulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness.

Olson, John B. (Boulder, CO)

1999-12-07T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Battery paste compositions and electrochemical cells for use therewith  

DOE Patents [OSTI]

An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinylsulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness.

Olson, John B. (Boulder, CO)

1999-02-16T23:59:59.000Z

362

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents [OSTI]

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

1989-01-01T23:59:59.000Z

363

Electrochemical method of producing nano-scaled graphene platelets  

DOE Patents [OSTI]

A method of producing nano-scaled graphene platelets with an average thickness smaller than 30 nm from a layered graphite material. The method comprises (a) forming a carboxylic acid-intercalated graphite compound by an electrochemical reaction; (b) exposing the intercalated graphite compound to a thermal shock to produce exfoliated graphite; and (c) subjecting the exfoliated graphite to a mechanical shearing treatment to produce the nano-scaled graphene platelets. Preferred carboxylic acids are formic acid and acetic acid. The exfoliation step in the instant invention does not involve the evolution of undesirable species, such as NO.sub.x and SO.sub.x, which are common by-products of exfoliating conventional sulfuric or nitric acid-intercalated graphite compounds. The nano-scaled platelets are candidate reinforcement fillers for polymer nanocomposites. Nano-scaled graphene platelets are much lower-cost alternatives to carbon nano-tubes or carbon nano-fibers.

Zhamu, Aruna; Jang, Joan; Jang, Bor Z.

2013-09-03T23:59:59.000Z

364

Survey of electrochemical production of inorganic compounds. Final report  

SciTech Connect (OSTI)

The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

Not Available

1980-10-01T23:59:59.000Z

365

Cascade redox flow battery systems  

DOE Patents [OSTI]

A reduction/oxidation ("redox") flow battery system includes a series of electrochemical cells arranged in a cascade, whereby liquid electrolyte reacts in a first electrochemical cell (or group of cells) before being directed into a second cell (or group of cells) where it reacts before being directed to subsequent cells. The cascade includes 2 to n stages, each stage having one or more electrochemical cells. During a charge reaction, electrolyte entering a first stage will have a lower state-of-charge than electrolyte entering the nth stage. In some embodiments, cell components and/or characteristics may be configured based on a state-of-charge of electrolytes expected at each cascade stage. Such engineered cascades provide redox flow battery systems with higher energy efficiency over a broader range of current density than prior art arrangements.

Horne, Craig R.; Kinoshita, Kim; Hickey, Darren B.; Sha, Jay E.; Bose, Deepak

2014-07-22T23:59:59.000Z

366

Use of high-temperature gas-tight electrochemical cells to measure electronic transport and thermodynamics in metal oxides  

SciTech Connect (OSTI)

By using a gas-tight electrochemical cell, the authors can perform high-temperature coulometric titration and measure electronic transport properties to determine the electronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilized zirconia (YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressures (pO{sub 2} = 10{sup {minus}35} to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria (Ca-CeO{sub 2} and CeO{sub 2}), copper oxides, and copper-oxide-based ceramic superconductors, transition metal oxides, SrFeCo{sub 0.5}O{sub x}, and BaTiO{sub 3}.

Park, J.H.; Ma, B.; Park, E.T. [Argonne National Lab., IL (United States). Energy Technology Div.

1997-10-01T23:59:59.000Z

367

Well-defined ultrathin Pd films on Pt(111): electrochemical preparation and interfacial chemistry  

E-Print Network [OSTI]

. In both methods, between the coverage regimes studied, the growth of the Pd films follows the Stranski-Krastanov mechanism. The interfacial electrochemical properties associated with the film-to-bulk transition were characterized by conventional...

Park, Yeon Su

2005-08-29T23:59:59.000Z

368

Electropolymerized Polyaniline Stabilized Tungsten Oxide Nanocomposite Films: Electrochromic Behavior and Electrochemical  

E-Print Network [OSTI]

Electropolymerized Polyaniline Stabilized Tungsten Oxide Nanocomposite Films: Electrochromic. The optical properties and electrochemical capacitive behaviors of the composite films for electrochromic (EC electrochromism at both positive and negative potentials arising from PANI and WO3, respectively. A coloration

Guo, John Zhanhu

369

Electrochemical reduction of nitrates and nitrites in alkaline media in the presence of hexavalent chromium  

E-Print Network [OSTI]

, at the Savannah River Site (SRS) in Aiken, SC, approximately 35 million gallons of highly ra- dioactive waste has be operated on a continuous basis. Keywords: alkaline media, electrochemical reduction, hexavalent chromium

Weidner, John W.

370

Method for transferring thermal energy and electrical current in thin-film electrochemical cells  

DOE Patents [OSTI]

An improved electrochemical generator is disclosed. The electrochemical generator includes a thin-film electrochemical cell which is maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of the cell, conducts current into and out of the cell and also conducts thermal energy between the cell and thermally conductive, electrically resistive material disposed on a vessel wall adjacent the conductor. The thermally conductive, electrically resistive material may include an anodized coating or a thin sheet of a plastic, mineral-based material or conductive polymer material. The thermal conductor is fabricated to include a resilient portion which expands and contracts to maintain mechanical contact between the cell and the thermally conductive material in the presence of relative movement between the cell and the wall structure. The electrochemical generator may be disposed in a hermetically sealed housing.

Rouillard, Roger (Beloeil, CA); Domroese, Michael K. (South St. Paul, MN); Hoffman, Joseph A. (Minneapolis, MN); Lindeman, David D. (Hudson, WI); Noel, Joseph-Robert-Gaetan (St-Hubert, CA); Radewald, Vern E. (Austin, TX); Ranger, Michel (Lachine, CA); Sudano, Anthony (Laval, CA); Trice, Jennifer L. (Eagan, MN); Turgeon, Thomas A. (Fridley, MN)

2003-05-27T23:59:59.000Z

371

Supplementary Information for: Electrochemical struvite precipitation from digestate with a fluidized bed  

E-Print Network [OSTI]

Supplementary Information for: Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial electrolysis cell Roland D. Cusick1,2 , Mark Ullery1 , Brian A. Dempsey1

372

Modeling integrated photovoltaic-electrochemical devices using steady-state equivalent circuits  

E-Print Network [OSTI]

We describe a framework for efficiently coupling the power output of a series-connected string of single-band-gap solar cells to an electrochemical process that produces storable fuels. We identify the fundamental efficiency ...

Winkler, Mark Thomas

373

A multiscale study of atomic interactions in the electrochemical double layer applied to electrocatalysis  

E-Print Network [OSTI]

This work is an integrated study of chemical and electrostatic interactions in the electrochemical double layer, and their significance for accurate prediction of reaction kinetics in electrocatalysis. First, a kinetic ...

Bonnet, Nicéphore

2011-01-01T23:59:59.000Z

374

The hydrothermal synthesis and characterization of olivines and related compounds for electrochemical applications  

E-Print Network [OSTI]

The hydrothermal synthesis and characterization of olivines and related compounds at a low cost is also required. Hydrothermal reactions are one such possibility. A number of pure. When conductive carbons are added to the reaction medium, excellent electrochemical behavior

Suzuki, Masatsugu

375

E-Print Network 3.0 - alkaline permanganate-an electrochemical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for: alkaline permanganate-an electrochemical Page: << < 1 2 3 4 5 > >> 1 The Biocarbon Fuel Cell III Thermodynamics permits the carbon fuel cell, which is a battery that...

376

Batteries and electrochemical energy storage are central to any future alternative energy scenario. Future energy generation  

E-Print Network [OSTI]

Batteries and electrochemical energy storage are central to any future alternative energy scenario. Future energy generation sources are likely to be intermittent, requiring storage capacity energy storage for uninterrupted power supply units, the electrical grid, and transportation. Of all

Kemner, Ken

377

Electrochemical investigations of stable cavitation from bubbles generated during reduction of water  

E-Print Network [OSTI]

Electrochemical investigations of stable cavitation from bubbles generated during reduction April 2014 Keywords: Megasonic cleaning Stable cavitation Microstreaming Hydrogen bubbles Water on wafers without affect- ing the transient cavitation responsible for feature damage. Ã? 2014 Elsevier B

Deymier, Pierre

378

Electrochemical hydrogenation of aromatic compounds chemisorbed at polycrystalline and single-crystal Pd surfaces  

E-Print Network [OSTI]

The chemisorption and electrochemical hydrogenation of hydroquinone (H2Q) at polycrystalline (pc) Pd, well-ordered Pd(100), and Pd-modified Au(hkl) electrodes were studied using a combination of ultra-high vacuum (UHV) surface spectroscopy...

Sanabria-Chinchilla, Jean

2009-06-02T23:59:59.000Z

379

The Electrochemical Society Interface Summer 2010 37 n recent years, energy research has  

E-Print Network [OSTI]

,freeze start,ORR, water management,flooding,poisoning,durability,reliability Solarcells:Efficiency,toxicity, CO, and solarcells electrochemical engineers are listed in Fig. 1.1 The range of length scales

Subramanian, Venkat

380

Silicate electrochemical measurements in seawater: Chemical and analytical aspects towards a reagentless sensor  

E-Print Network [OSTI]

Silicate electrochemical measurements in seawater: Chemical and analytical aspects towards Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex, France Keywords: Molybdenum Silicate Reagentless developed a semi-autonomous method to detect silicate in aqueous samples. Molybdenum oxidation was used

Mailhes, Corinne

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Novel electrochemical method of fast and reproducible fabrication of metallic nanoelectrodes  

SciTech Connect (OSTI)

A novel electrochemical wire etching method of fabrication of ultrasharp nanoelectrodes is reported. Tungsten wires can be sharpened to less than 10 nm tip radius in a reproducible manner in less than 1 min by using controllable hydrodynamic electrolyte flow combined with optimized electrochemical etching parameters. The method relies on the variations of the electric field at the surface of a metal wire, while the electrolyte solution is in motion, rather than on the ionic gradient generated in a static solution.

Silva, E. L., E-mail: elsilva@ua.pt; Silva, R. F.; Oliveira, F. J. [CICECO – Department of Materials and Ceramics Engineering, University of Aveiro, Aveiro (Portugal); Zheludkevich, M. [CICECO – Department of Materials and Ceramics Engineering, University of Aveiro, Aveiro (Portugal); MagIC, Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Max-Planck Str. 1, 21502 Geesthacht (Germany)

2014-09-15T23:59:59.000Z

382

Glass composition and process for sealing void spaces in electrochemical devices  

SciTech Connect (OSTI)

A glass foaming material and method are disclosed for filling void spaces in electrochemical devices. The glass material includes a reagent that foams at a temperature above the softening point of the glass. Expansion of the glass fills void spaces including by-pass and tolerance channels of electrochemical devices. In addition, cassette to cassette seals can also be formed while channels and other void spaces are filled, reducing the number of processing steps needed.

Meinhardt, Kerry D. (Richland, WA); Kirby, Brent W. (Kennewick, WA)

2012-05-01T23:59:59.000Z

383

Preparation and electrochemical properties of lamellar MnO{sub 2} for supercapacitors  

SciTech Connect (OSTI)

Lamellar birnessite-type MnO{sub 2} materials were prepared by changing the pH of the initial reaction system via hydrothermal synthesis. The interlayer spacing of MnO{sub 2} with a layered structure increased gradually when the initial pH value varied from 12.43 to 2.81, while the MnO{sub 2}, composed of {alpha}-MnO{sub 2} and {gamma}-MnO{sub 2}, had a rod-like structure at pH 0.63. Electrochemical studies indicated that the specific capacitance of birnessite-type MnO{sub 2} was much higher than that of rod-like MnO{sub 2} at high discharge current densities due to the lamellar structure with fast intercalation/deintercalation of protons and high utilization of MnO{sub 2}. The initial specific capacitance of MnO{sub 2} prepared at pH 2.81 was 242.1 F g{sup -1} at 2 mA cm{sup -2} in 2 mol L{sup -1} (NH{sub 4}){sub 2}SO{sub 4} aqueous electrolyte. The capacitance increased by about 8.1% of initial capacitance after 200 cycles at a current density of 100 mA cm{sup -2}.

Yan, Jun; Wei, Tong [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Cheng, Jie [Research Institute of Chemical Defense, Beijing 100083 (China)] [Research Institute of Chemical Defense, Beijing 100083 (China); Fan, Zhuangjun, E-mail: fanzhj666@163.com [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Zhang, Milin [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)] [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China)

2010-02-15T23:59:59.000Z

384

Electrochemical control of ion transport through a mesoporous carbon membrane  

SciTech Connect (OSTI)

The transport of fluids through nanometer scale channels typically on the order of 1 -100 nm often exhibit unique properties compared to the bulk fluid. These phenomena occur because the channel dimensions and molecular size become comparable to the range of several important forces including electrostatic and van der Waals forces. Small changes in properties such as the electric double layer or surface charge can significantly affect molecular transport through the channels. Based on these emerging properties, a variety of nanofluidic devices such as nanofluidic transistors, nanofluidic diodes or lab-on-a-chip devices have been developed3-7 with a diverse range of applications including water purification, biomolecular sensing, DNA separation, and rectified ion transport. Nanofluidic devices are typically fabricated using expensive lithography techniques or sacrificial templates. Here we report a carbon-based, three-dimensional nanofluidic transport membrane that enables gated, or on/off, control of the transport of organic molecular species and metal ions using an applied electrical potential. In the absence of an applied potential, both cationic and anionic molecules freely diffuse across the membrane via a concentration gradient. However, when an electrochemical potential is applied, the transport of ions through the membrane is inhibited.

Surwade, Sumedh P [ORNL] [ORNL; Chai, Songhai [ORNL] [ORNL; Choi, Jai-Pil [ORNL] [ORNL; Wang, Xiqing [ORNL] [ORNL; Lee, Jeseung [ORNL] [ORNL; Vlassiouk, Ivan V [ORNL] [ORNL; Mahurin, Shannon Mark [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

2014-01-01T23:59:59.000Z

385

Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication  

SciTech Connect (OSTI)

This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

2014-12-01T23:59:59.000Z

386

Status of the DOE Battery and Electrochemical Technology Program V  

SciTech Connect (OSTI)

The program consists of two activities, Technology Base Research (TBR) managed by the Lawrence Berkeley Laboratory (LBL) and Exploratory Technology Development and Testing (EDT) managed by the Sandia National Laboratories (SNL). The status of the Battery Energy Storage Test (BEST) Facility is presented, including the status of the batteries to be tested. ECS program contributions to the advancement of the lead-acid battery and specific examples of technology transfer from this program are given. The advances during the period December 1982 to June 1984 in the characterization and performance of the lead-acid, iron/nickel-oxide, iron/air, aluminum/air, zinc/bromide, zinc/ferricyanide, and sodium/sulfur batteries and in fuel cells for transport are summarized. Novel techniques and the application of established techniques to the study of electrode processes, especially the electrode/electrolyte interface, are described. Research with the potential of leading to improved ceramic electrolytes and positive electrode container and current-collectors for the sodium/sulfur battery is presented. Advances in the electrocatalysis of the oxygen (air) electrode and the relationship of these advances to the iron/air and aluminum/air batteries and to the fuel cell are noted. The quest for new battery couples and battery materials is reviewed. New developments in the modeling of electrochemical cell and electrode performance with the approaches to test these models are reported.

Roberts, R.

1985-06-01T23:59:59.000Z

387

Electrochemical method of producing eutectic uranium alloy and apparatus  

DOE Patents [OSTI]

An apparatus and method are disclosed for continuous production of liquid uranium alloys through the electrolytic reduction of uranium chlorides. The apparatus includes an electrochemical cell formed from an anode shaped to form an electrolyte reservoir, a cathode comprising a metal, such as iron, capable of forming a eutectic uranium alloy having a melting point less than the melting point of pure uranium, and molten electrolyte in the reservoir comprising a chlorine or fluorine containing salt and uranium chloride. The method of the invention produces an eutectic uranium alloy by creating an electrolyte reservoir defined by a container comprising an anode, placing an electrolyte in the reservoir, the electrolyte comprising a chlorine or fluorine containing salt and uranium chloride in molten form, positioning a cathode in the reservoir where the cathode comprises a metal capable of forming an uranium alloy having a melting point less than the melting point of pure uranium, and applying a current between the cathode and the anode. 2 figures.

Horton, J.A.; Hayden, H.W.

1995-01-10T23:59:59.000Z

388

Electrochemical and spectroelectrochemical properties of polyviologen complex modified electrodes  

SciTech Connect (OSTI)

The electrochemistry and the spectroelectrochemistry of the polymer complex polyviologens-poly(styrenesulfonate) modified electrodes were examined in an aqueous solution. The surface waves observed at -0.65 and -1.20 V vs. SCE were due to reductions of the electrochemical active centers (viologen moieties) in the polymer layer. Excellent stability of the polymer complex modified electrodes was obtained on repeated scanning over the first wave, between +0.5 and -0.8 V vs. SCE, causing only a 5% decrease in the peak height after 100 cycles at a scan rate of 50 mV/s. The redox behavior of Fe(CN)/sub 6//sup 3-/4-/ was examined at the modified electrodes, demonstrating a mediated electron-transfer reaction through the redox centers in the polymer film. The change of the color of the polymer film on electrodes could be seen as red-purple. The absorption coefficient (..cap alpha..) at 560 nm of the polymer film was obtained as 1.7 x 10/sup 4/ cm/sup -1/.

Akahoshi, H.; Toshima, S.; Itaya, K.

1981-04-02T23:59:59.000Z

389

Electrochemical Recovery of Sodium Hydroxide from Alkaline Salt Solution  

SciTech Connect (OSTI)

A statistically designed set of tests determined the effects of current density, temperature, and the concentrations of nitrate/nitrite, hydroxide and aluminate on the recovery of sodium as sodium hydroxide (caustic) from solutions simulating those produced from the Savannah River Site (SRS) In-Tank Precipitation process. These tests included low nitrate and nitrite concentrations which would be produced by electrolytic nitrate/nitrite destruction. The tests used a two compartment electrochemical cell with a Nafion Type 324 ion-exchange membrane. Caustic was successfully recovered from the waste solutions. Evaluation of the testing results indicated that the transport of sodium across the membrane was not significantly affected by any of the varied parameters. The observed variance in the sodium flux is attributed to experimental errors and variations in the performance characteristics of individual pieces of the organic-based Nafion membrane.Additional testing is recommended to determine the maximum current density, to evaluate the chemical durability of the organic membrane as a function of current density and to compare the durability and performance characteristics of the organic-based Nafion membrane with that of other commercially available organic membranes and the inorganic class of membranes under development by Ceramatec and PNNL.

Hobbs, D.T. [Westinghouse Savannah River Company, AIKEN, SC (United States); Edwards, T.B.

1996-10-01T23:59:59.000Z

390

Electrochemical Testing of Ni-Cr-Mo-Gd Alloys  

SciTech Connect (OSTI)

The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

T. E. Lister; R. E. Mizia; H. Tian

2005-10-01T23:59:59.000Z

391

Double Layer Formation and Cation Pseudo-Intercalation Supercapacitor Carbon Nanotube Composite Electrodes With Enhanced Electrochemical Performances.  

E-Print Network [OSTI]

??Among electrochemical energy storage solutions, redox-free supercapacitors exhibit the highest power densities and best cycle life, easily reaching over one million cycles. Despite these attributes,… (more)

Rangom, Yverick

2015-01-01T23:59:59.000Z

392

doi: 10.1149/2.028208jes 2012, Volume 159, Issue 8, Pages A1351-A1359.J. Electrochem. Soc.  

E-Print Network [OSTI]

to an electrochemical double layer capacitance (EDLC) negative electrode for an aqueous sodium hybrid battery layer capacitance (EDLC) electrode, typically found in su- percapacitors. Aqueous sodium hybrid devices

Litster, Shawn

393

Journal of The Electrochemical Society, 147 (12) 4485-4493 (2000) 4485 S0013-4651(00)08-104-0 CCC: $7.00 The Electrochemical Society, Inc.  

E-Print Network [OSTI]

poten- tially replace the internal combustion engine for transportation be- cause they are clean, quiet: $7.00 © The Electrochemical Society, Inc. Proton exchange membrane fuel cell (PEMFC) engines can of future fuel cell engines. Performance of a fuel cell is measured by its current-voltage rela- tion (i

Wang, Chao-Yang

394

Journal of The Electrochemical Society, 147 (12) 4507-4511 (2000) 4507 S0013-4651(99)09-102-8 CCC: $7.00 The Electrochemical Society, Inc.  

E-Print Network [OSTI]

: $7.00 © The Electrochemical Society, Inc. Hydrogen embrittlement is a serious concern that can limit-3 Hydrogen embrittlement occurs as a result of hydrogen evolution on the surface of the specimen via the usage of various metals and alloys in different aqueous environ- ments. Hydrogen ingress into the metal

Popov, Branko N.

395

Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O$_2$ battery capacity  

E-Print Network [OSTI]

Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge facing nonaqueous Li-O$_2$ batteries is the electronically insulating nature of the primary discharge product, lithium peroxide, which passivates the battery cathode as it is formed, leading to low ultimate cell capacities. Recently, strategies to enhance solubility to circumvent this issue have been reported, but rely upon electrolyte formulations that further decrease the overall electrochemical stability of the system, thereby deleteriously affecting battery rechargeability. In this study, we report that a significant enhancement (greater than four-fold) in Li-O$_2$ cell capacity is possible by appropriately selecting the salt anion in the electrolyte solution. Using $^7$Li nuclear magnetic resonance and modeling, we confirm that this improvement is a result of enhanced Li...

Burke, Colin M; Khetan, Abhishek; Viswanathan, Venkatasubramanian; McCloskey, Bryan D

2015-01-01T23:59:59.000Z

396

Electrochemical Processes for In-Situ Treatment of Contaminated Soils - Final Report - 09/15/1996 - 01/31/2001  

SciTech Connect (OSTI)

This project will study electrochemical processes for the in situ treatment of soils contaminated by mixed wastes, i.e., organic and inorganic. Soil samples collected form selected DOE waste sites will be characterized for specific organic and metal contaminants and hydraulic permeability. The soil samples are then subject to desorption experiments under various physical-chemical conditions such as pH and the presence of surfactants. Batch electro-osmosis experiments will be conducted to study the transport of contaminants in the soil-water systems. Organic contaminants that are released from the soil substrate will be treated by an advanced oxidation process, i.e., electron-Fantan. Finally, laboratory reactor integrating the elector-osmosis and elector-Fantan processes will be used to study the treatment of contaminated soil in situ.

Huang, Chin-Pao

2001-05-31T23:59:59.000Z

397

Enhanced molten salt purification by electrochemical methods: feasibility experiments with flibe  

SciTech Connect (OSTI)

Molten salts are considered within the Very High Temperature Reactor program as heat transfer media because of their intrinsically favorable thermo-physical properties at temperatures starting from 300 C and extending up to 1200 C. In this context two main applications of molten salt are considered, both involving fluoride-based materials: as primary coolants for a heterogeneous fuel reactor core and as secondary heat transport medium to a helium power cycle for electricity generation or other processing plants, such as hydrogen production. The reference design concept here considered is the Advanced High Temperature Reactor (AHTR), which is a large passively safe reactor that uses solid graphite-matrix coated-particle fuel (similar to that used in gas-cooled reactors) and a molten salt primary and secondary coolant with peak temperatures between 700 and 1000 C, depending upon the application. However, the considerations included in this report apply to any high temperature system employing fluoride salts as heat transfer fluid, including intermediate heat exchangers for gas-cooled reactor concepts and homogenous molten salt concepts, and extending also to fast reactors, accelerator-driven systems and fusion energy systems. The most important initial requirement for heat transfer test of molten salt systems is the establishment of reference coolant materials to use in the experiments. An earlier report produced within the same project (INL/EXT-10-18297) highlighted how thermo-physical properties of the materials that directly impact the heat transfer behavior are strongly correlated to the of composition and impurities concentration of the melt. It is therefore essential to establish laboratory techniques that can measure the melt composition, and to develop purification methods that would allow the production of large quantities of coolant with the desired purity. A companion report titled ‘An experimental test plan for the characterization of molten salt thermo-chemistry properties in heat transport systems’ describes the options available to reach such objectives and contains extended references to published work. The report highlights how electrochemical methods are the most promising techniques for the development of instrumentation aimed at the measurement of melts composition and for enhanced purification systems. The purpose of this work is to summarize preliminary experimental activities performed at the INL Safety and Tritium Applied Research facility in support of the development of electrochemistry based instrumentation and purification systems. The experiments have been focused on the LiF-BeF2 eutectic (67 and 33 mol%, respectively), also known as flibe.

Alan K Wertsching; Brandon S Grover; Pattrick Calderoni

2010-09-01T23:59:59.000Z

398

alloy-liquid lithium systems: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

do Nascimento Jr; J. R. De Medeiros 2001-11-28 6 A Mathematical Model for a Lithium-Ion BatteryElectrochemical Capacitor Hybrid System Energy Storage, Conversion and Utilization...

399

Advanced Electrochemical Technologies for Hydrogen Production by Alternative Thermochemical Cycles  

SciTech Connect (OSTI)

Hydrogen fuel is a potentially major solution to the problem of climate change, as well as addressing urban air pollution issues. But a key future challenge for hydrogen as a clean energy carrier is a sustainable, low-cost method of producing it in large capacities. Most of the world�s hydrogen is currently derived from fossil fuels through some type of reforming processes. Nuclear hydrogen production is an emerging and promising alternative to the reforming processes for carbon-free hydrogen production in the future. This report presents the main results of a research program carried out by a NERI Consortium, which consisted of Penn State University (PSU) (lead), University of South Carolina (USC), Tulane University (TU), and Argonne National Laboratory (ANL). Thermochemical water decomposition is an emerging technology for large-scale production of hydrogen. Typically using two or more intermediate compounds, a sequence of chemical and physical processes split water into hydrogen and oxygen, without releasing any pollutants externally to the atmosphere. These intermediate compounds are recycled internally within a closed loop. While previous studies have identified over 200 possible thermochemical cycles, only a few have progressed beyond theoretical calculations to working experimental demonstrations that establish scientific and practical feasibility of the thermochemical processes. The Cu-Cl cycle has a significant advantage over other cycles due to lower temperature requirements - around 530 oC and below. As a result, it can be eventually linked with the Generation IV thermal power stations. Advantages of the Cu-Cl cycle over others include lower operating temperatures, ability to utilize low-grade waste heat to improve energy efficiency, and potentially lower cost materials. Another significant advantage is a relatively low voltage required for the electrochemical step (thus low electricity input). Other advantages include common chemical agents and reactions going to completion without side reactions, and lower demands on materials of construction. Three university research groups from PSU, USC, and TU as well as a group from ANL have been collaborating on the development of enabling technologies for the Cu-Cl cycle, including experimental work on the Cu-Cl cycle reactions, modeling and simulation, and particularly electrochemical reaction for hydrogen production using a CuCl electrolyzer. The Consortium research was distributed over the participants and organized in the following tasks: (1) Development of CuCl electrolyzer (PSU), (2) Thermodynamic modeling of anolyte solution (PSU), (3) Proton conductive membranes for CuCl electrolysis (PSU), (4) Development of an analytical method for online analysis of copper compounds in highly concentrated aqueous solutions (USC), (5) Electrodialysis as a means for separation and purification of the streams exiting the electrolyzer in the Cu-Cl cycle (USC), (6) Development of nanostructured electrocatalysts for the Cu-Cl electrolysis (USC), (7) Cu-Cl electrolyzer modeling (USC), (8) Aspen Plus modeling of the Cu-Cl thermochemical cycle (TU), (9) International coordination of research on the development of the Cu-Cl thermochemical cycle (ANL). The results obtained in the project clearly demonstrate that the Cu-Cl alternative thermochemical cycle is a promising and viable technology to produce hydrogen efficiently.

The Pennsylvania State Univeristy: Serguei Lvov, Mike Chung, Mark Fedkin, Victor Balashov, Elena, Chalkova, Nikolay Akinfiev; University of South Carolina: Carol Stork, Thomas Davis, Francis Gadala-Maria, Thomas Stanford, John Weidner; Tulane University: Victor Law, John Prindle; ANL: Michele Lewis

2011-01-06T23:59:59.000Z

400

D6 Journal of The Electrochemical Society, 160 (1) D6-D9 (2013) 0013-4651/2013/160(1)/D6/4/$28.00 The Electrochemical Society  

E-Print Network [OSTI]

and electrochemical properties of the coatings is studied. The electrochemical activity of the material is found current values, marked amounts of lithium charge are observed to interchange with the material owing- calation process. Consequently, a large surface area, providing for ease of interaction

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

System and method for detecting gas  

DOE Patents [OSTI]

A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

Chow, Oscar Ken (Simsbury, CT); Moulthrop, Lawrence Clinton (Windsor, CT); Dreier, Ken Wayne (Madison, CT); Miller, Jacob Andrew (Dexter, MI)

2010-03-16T23:59:59.000Z

402

Electrochemical Polishing Applications and EIS of a Novel Choline Chloride-Based Ionic Liquid  

SciTech Connect (OSTI)

Minimal surface roughness is a critical feature for high-field superconducting radio frequency (SRF) cavities used to engineer particle accelerators. Current methods for polishing Niobium cavities typically utilize solutions containing a mixture of concentrated sulfuric and hydrofluoric acid. Polishing processes such as these are effective, yet there are many hazards and costs associated with the use (and safe disposal) of the concentrated acid solutions. An alternative method for electrochemical polishing of the cavities was explored using a novel ionic liquid solution containing choline chloride. Potentiostatic electrochemical impedance spectroscopy (EIS) was used to analyze the ionic polishing solution. Final surface roughness of the Nb was found to be comparable to that of the acid-polishing method, as assessed by atomic force microscopy (AFM). This indicates that ionic liquid-based electrochemical polishing of Nb is a viable replacement for acid-based methods for preparation of SRF cavities.

Wixtrom, Alex I. [Christopher Newport University, Newport News, VA (United States); Buhler, Jessica E. [Christopher Newport University, Newport News, VA (United States); Reece, Charles E. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Abdel-Fattah, Tarek M. [Christopher Newport University, Newport News, VA (United States)

2013-06-01T23:59:59.000Z

403

In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01.  

E-Print Network [OSTI]

In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01. MATHEMATICAL MODELING OF LIQUID-FEED DIRECT METHANOL FUEL CELLS Z. H. Wang and C. Y. Wang Electrochemical methanol fuel cells (DMFC). Diffusion and convection of both gas and liquid phases are considered

Wang, Chao-Yang

404

Lithium-Ion battery State of Charge estimation with a Kalman Filter based on a electrochemical model  

E-Print Network [OSTI]

Lithium-Ion battery State of Charge estimation with a Kalman Filter based on a electrochemical state of charge (SOC). In this paper an averaged electrochemical Lithium-ion battery model suitable-Volmer current and the solid concentration at the interface with the electrolyte and (ii) the battery current

Stefanopoulou, Anna

405

Volume 149, number 5,6 CHEMICAL PHYSICS LETTERS 2 September 1988 ULTRAHIGH VACUUM AND ELECTROCHEMICAL CO-CHARACTERIZATION STUDIES  

E-Print Network [OSTI]

AND ELECTROCHEMICAL CO-CHARACTERIZATION STUDIES OF Cu ON Ru(OOO1)* E.M. STUVE `, J.W. ROGERS Jr., D. INGERSOLL, D.W. GOODMAN, M.L. THOMAS Sandia National Laboratories, Albuquerque, NM87185, USA and Mark T. PAFFETT Los quantities of Cu on a Ru(0001) substrate was studied both in ultrahigh vacuum (UHV) and in an electrochemical

Goodman, Wayne

406

Direct Electrochemical Regeneration of Enzymatically Active 1,4-NADH Using a Nickel Modified Glassy Carbon Electrode  

E-Print Network [OSTI]

Direct Electrochemical Regeneration of Enzymatically Active 1,4- NADH Using a Nickel Modified enzymatically active 1,4- NADH in a batch electrochemical reactor at different electrolysis potentials. 1m was regenerated at -1.5VMSE In comparison with bare GCE, almost the same percentage of enzymatically active 1

Barthelat, Francois

407

Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications  

E-Print Network [OSTI]

Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed : 10.1149/2.064209jes #12;Over the past 15 years, Li-ion batteries have received much attention

Paris-Sud XI, Université de

408

Boosting the voltage of a salinity-gradient-power electrochemical cell by means of complex-forming solutions  

E-Print Network [OSTI]

the diaphragm constitutes a waste of free energy, which impairs the voltage generation of the concentration cell-based light-emitting electrochemical cells J. Appl. Phys. 116, 104504 (2014); 10.1063/1.4895060 Decoupled luminance decay and voltage drift in polymer light-emitting electrochemical cells: Forward bias vs. reverse

Carati, Andrea

409

Speaker biographies for the Fuel Cell Technologies Program Webinar titled Hydrogen Production by PEM Electrolysis … Spotlight on Giner and Proton  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartmentScoping StudyEnergy SouthDepartment|

410

Measuring individual overpotentials in an operating solid-oxide electrochemical cell  

E-Print Network [OSTI]

We use photo-electrons as a non-contact probe to measure local electrical potentials in a solid-oxide electrochemical cell. We characterize the cell in operando at near-ambient pressure using spatially-resolved X-ray photoemission spectroscopy. The overpotentials at the interfaces between the Ni and Pt electrodes and the yttria-stabilized zirconia (YSZ) electrolyte are directly measured. The method is validated using electrochemical impedance spectroscopy. Using the overpotentials, which characterize the cell's inefficiencies, we compare without ambiguity the electro-catalytic efficiencies of Ni and Pt, finding that on both metals H2O splitting proceeds more rapidly than H2 oxidation.

Gabaly, Farid El; McDaniel, Anthony H; Farrow, Roger L; Linne, Mark A; Hussain, Zahid; Bluhm, Hendrik; Liu, Zhi; McCarty, Kevin F

2010-01-01T23:59:59.000Z

411

Method of bonding an interconnection layer on an electrode of an electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell containing an air electrode, contacting electrolyte and electronically conductive interconnection layer, and a fuel electrode, has the interconnection layer attached by: (A) applying a thin, closely packed, discrete layer of LaCrO[sub 3] particles, doped with an element selected from the group consisting of Ca, Sr, Co, Ba, Mg and their mixtures on a portion of the air electrode, and then (B) electrochemical vapor depositing a dense skeletal structure between and around the doped LaCrO[sub 3] particles. 2 figs.

Pal, U.B.; Isenberg, A.O.; Folser, G.R.

1992-01-14T23:59:59.000Z

412

Synthesis of Ru/multiwalled carbon nanotubes by microemulsion for electrochemical supercapacitor  

SciTech Connect (OSTI)

An efficient way to decorate multiwalled carbon nanotubes with Ru had been developed. In this method, Ru nanoparticles were prepared by water-in-oil reverse microemulsion, and the produced Ru anchored on MWCNTs. Transmission electron microscopy (TEM) result showed that RuO{sub 2} nanoparticles had the uniform size distribution after electrochemical oxidation. Energy dispersive X-rays (EDX) spectra elucidated the presence of ruthenium oxide in the as-prepared composites after electrochemical oxidation. Cyclic voltammetry result demonstrated that a specific capacitance of deposited ruthenium oxide electrode was significantly greater than that of the pristine MWCNTs electrode in the same medium.

Yan Shancheng; Qu Peng; Wang Haitao; Tian Tian [State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Si Pai Lou 2, Nanjing 210096 (China); Xiao Zhongdang [State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Si Pai Lou 2, Nanjing 210096 (China)], E-mail: zdxiao@seu.edu.cn

2008-10-02T23:59:59.000Z

413

Papers Based Electrochemical Biosensors: From Test Strips to Paper-Based Microfluidics  

SciTech Connect (OSTI)

Papers based biosensors such as lateral flow test strips and paper-based microfluidic devices (or paperfluidics) are inexpensive, rapid, flexible, and easy-to-use analytical tools. An apparent trend in their detection is to interpret sensing results from qualitative assessment to quantitative determination. Electrochemical detection plays an important role in quantification. This review focuses on electrochemical (EC) detection enabled biosensors. The first part provides detailed examples in paper test strips. The second part gives an overview of paperfluidics engaging EC detections. The outlook and recommendation of future directions of EC enabled biosensors are discussed in the end.

Liu, Bingwen; Du, Dan; Hua, Xin; Yu, Xiao-Ying; Lin, Yuehe

2014-05-08T23:59:59.000Z

414

Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste  

SciTech Connect (OSTI)

Various forms of general and localized corrosion represent principal threats to the integrity of DOE liquid waste storage tanks. These tanks, which are of a single wall or double wall design, depending upon their age, are fabricated from welded carbon steel and contain a complex waste-form comprised of NaOH and NaNO{sub 3}, along with trace amounts of phosphate, sulfate, carbonate, and chloride. Because waste leakage can have a profound environmental impact, considerable interest exists in predicting the accumulation of corrosion damage, so as to more effectively schedule maintenance and repair. The different tasks that are being carried out under the current program are as follows: (1) Theoretical and experimental assessment of general corrosion of iron/steel in borate buffer solutions by using electrochemical impedance spectroscopy (EIS), ellipsometry and XPS techniques; (2) Development of a damage function analysis (DFA) which would help in predicting the accumulation of damage due to pitting corrosion in an environment prototypical of DOE liquid waste systems; (3) Experimental measurement of crack growth rate, acoustic emission signals and coupling currents for fracture in carbon and low alloy steels as functions of mechanical (stress intensity), chemical (conductivity), electrochemical (corrosion potential, ECP), and microstructural (grain size, precipitate size, etc) variables in a systematic manner, with particular attention being focused on the structure of the noise in the current and its correlation with the acoustic emissions; (4) Development of fracture mechanisms for carbon and low alloy steels that are consistent with the crack growth rate, coupling current data and acoustic emissions; (5) Inserting advanced crack growth rate models for SCC into existing deterministic codes for predicting the evolution of corrosion damage in DOE liquid waste storage tanks; (6) Computer simulation of the anodic and cathodic activity on the surface of the steel samples in order to exactly predict the corrosion mechanisms; (7) Wavelet analysis of EC noise data from steel samples undergoing corrosion in an environment similar to that of the high level waste storage containers, to extract data pertaining to general, pitting and stress corrosion processes, from the overall data. The Point Defect Model (PDM) is directly applied as the theoretical assessment method for describing the passive film formed on iron/steels. The PDM is used to describe general corrosion in the passive region of iron. In addition, previous work suggests that pit formation is due to the coalescence of cation vacancies at the metal/film interface which would make it possible to use the PDM parameters to predict the onset of pitting. This previous work suggests that once the critical vacancy density is reached, the film ruptures to form a pit. Based upon the kinetic parameters derived for the general corrosion case, two parameters relating to the cation vacancy formation and annihilation can be calculated. These two parameters can then be applied to predict the transition from general to pitting corrosion for iron/mild steels. If cation vacancy coalescence is shown to lead to pitting, it can have a profound effect on the direction of future studies involving the onset of pitting corrosion. The work has yielded a number of important findings, including an unequivocal demonstration of the role of chloride ion in passivity breakdown on nickel in terms of cation vacancy generation within the passive film, the first detection and characterization of individual micro fracture events in stress corrosion cracking, and the determination of kinetic parameters for the generation and annihilation of point defects in the passive film on iron. The existence of coupling between the internal crack environment and the external cathodic environment, as predicted by the coupled environment fracture model (CEFM), has also been indisputably established for the AISI 4340/NaOH system. It is evident from the studies that analysis of coupling current noise is a very sensitive tool f

Digby D. Macdonald; Brian M. Marx; Sejin Ahn; Julio de Ruiz; Balaji Soundararaja; Morgan Smith; and Wendy Coulson

2008-01-15T23:59:59.000Z

415

Matthieu Dubarry Matthieu Dubarry Cyril Cyril TruchotTruchot Bor Yann LiawBor Yann Liaw Electrochemical Power Systems Laboratory (EPSL)Electrochemical Power Systems Laboratory (EPSL)  

E-Print Network [OSTI]

) 95623362336 Wind and Solar Energy ForecastWind and Solar Energy Forecast "Concerning Carbon" Symposium What site is the best for energy harvesting? What Turbine/Panels size will be needed? Short term Energy Institute Hawaii Natural Energy Institute ·· SOEST SOEST ·· University of Hawaii University

416

Electrochemical separation of aluminum from uranium for research reactor spent nuclear fuel applications.  

SciTech Connect (OSTI)

Researchers at Argonne National Laboratory (ANL) are developing an electrorefining process to treat aluminum-based spent nuclear fuel by electrochemically separating aluminum from uranium. The aluminum electrorefiner is modeled after the high-throughput electrorefiner developed at ANL. Aluminum is electrorefined, using a fluoride salt electrolyte, in a potential range of -0.1 V to -0.2 V, while uranium is electrorefined in a potential range of -0.3 V to -0.4 V; therefore, aluminum can be selectively separated electrochemically from uranium. A series of laboratory-scale experiments was performed to demonstrate the aluminum electrorefining concept. These experiments involved selecting an electrolyte (determining a suitable fluoride salt composition); selecting a crucible material for the electrochemical cell; optimizing the operating conditions; determining the effect of adding alkaline and rare earth elements to the electrolyte; and demonstrating the electrochemical separation of aluminum from uranium, using a U-Al-Si alloy as a simulant for aluminum-based spent nuclear fuel. Results of the laboratory-scale experiments indicate that aluminum can be selectively electrotransported from the anode to the cathode, while uranium remains in the anode basket.

Slater, S. A.; Willit, J. L.; Gay, E. C.; Chemical Engineering

1999-01-01T23:59:59.000Z

417

Science Highlight December 2010 Electrochemical Surface Science: Hard X-rays Probe Fuel Cell Model Catalyst  

E-Print Network [OSTI]

Science Highlight ­ December 2010 Electrochemical Surface Science: Hard X-rays Probe Fuel Cell. Proton exchange membrane fuel cells (PEMFCs) are promising power sources since they can generate distribution network. Large-scale deployment of fuel cells, however, has been hampered by cost and performance

Wechsler, Risa H.

418

Electrochemical method for defect delineation in silicon-on-insulator wafers  

DOE Patents [OSTI]

An electrochemical method for defect delineation in thin-film SOI or SOS wafers in which a surface of a silicon wafer is electrically connected so as to control the voltage of the surface within a specified range, the silicon wafer is then contacted with an electrolyte, and, after removing the electrolyte, defects and metal contamination in the silicon wafer are identified.

Guilinger, Terry R. (Albuquerque, NM); Jones, Howland D. T. (Albuquerque, NM); Kelly, Michael J. (Albuquerque, NM); Medernach, John W. (Albuquerque, NM); Stevenson, Joel O. (Albuquerque, NM); Tsao, Sylvia S. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

419

The Electrochemical Society Interface Fall 2001 21 Emerging Nanoscience and Functional Artificial Nanoarchitectures  

E-Print Network [OSTI]

The Electrochemical Society Interface · Fall 2001 21 Emerging Nanoscience and Functional Artificial of new and better nanoscience and the development of new and better nanotechnology. Many of the architects of new nanoscience and nanotech- nology (e.g., condensed-matter physicists, molecular biologists

420

Synthesis and electrochemical characterization of highly monodisperse dendrimer-templated monolayer protected clusters  

E-Print Network [OSTI]

investigated the electrochemical properties of Au, Pd and PdAu monolayer-protected clusters (MPCs), prepared by dendrimer-templating and subsequent extraction, are described. Purification of the extracted Au, Pd and PdAu nanoparticles was not required to obtain...

Kim, Yong-Gu

2006-04-12T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Comparison study of biomimetic strontium-doped calcium phosphate coatings by electrochemical deposition and air plasma  

E-Print Network [OSTI]

Comparison study of biomimetic strontium-doped calcium phosphate coatings by electrochemical April 2012 Ã? Springer Science+Business Media, LLC 2012 Abstract In this study, strontium-doped calcium of the strontium-doped calcium phosphate coatings were evaluated using bone cell culture using MC3T3-E1 osteoblast

Meng, Yizhi

422

Green synthesis of graphene nanosheets/ZnO composites and electrochemical properties  

SciTech Connect (OSTI)

A green and facile approach was demonstrated to prepare graphene nanosheets/ZnO (GNS/ZnO) composites for supercapacitor materials. Glucose, as a reducing agent, and exfoliated graphite oxide (GO), as precursor, were used to synthesize GNS, then ZnO directly grew onto conducting graphene nanosheets as electrode materials. The small ZnO particles successfully anchored onto graphene sheets as spacers to keep the neighboring sheets separate. The electrochemical performances of these electrodes were analyzed by cyclic voltammetry, electrochemical impedance spectrometry and chronopotentiometry. Results showed that the GNS/ZnO composites displayed superior capacitive performance with large capacitance (62.2 F/g), excellent cyclic performance, and maximum power density (8.1 kW/kg) as compared with pure graphene electrodes. Our investigation highlight the importance of anchoring of small ZnO particles on graphene sheets for maximum utilization of electrochemically active ZnO and graphene for energy storage application in supercapacitors. - Graphical abstract: Glucose was used to synthesize GNS, then ZnO directly grew onto conducting graphene nanosheets as electrode materials for supercapacitor. Results showed that the composites have superior capacitive performance. Highlights: > Graphene nanosheets were synthesized via using glucose as a reducing agent. > The reductant and the oxidized product are environmentally friendly. > ZnO grew onto conducting graphene sheets keeping neighboring sheets separate. > The structure improves the contact between the electrode and the electrolyte. > Results showed that these composites have good electrochemical property.

Wang Jun, E-mail: zhqw1888@sohu.com [College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin 150001 (China); Gao Zan [College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin 150001 (China); Li Zhanshuang; Wang Bin; Yan Yanxia; Liu Qi [College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Mann, Tom [Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin 150001 (China); Zhang Milin [College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001 (China); Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin 150001 (China); Jiang Zhaohua [College of Chemical Engineering, Harbin Institute of Technology, Harbin 150001 (China)

2011-06-15T23:59:59.000Z

423

Homogeneous, dual layer, solid state, thin film deposition for structural and/or electrochemical characteristics  

DOE Patents [OSTI]

Solid state, thin film, electrochemical devices (10) and methods of making the same are disclosed. An exemplary device 10 includes at least one electrode (14) and an electrolyte (16) deposited on the electrode (14). The electrolyte (16) includes at least two homogenous layers of discrete physical properties. The two homogenous layers comprise a first dense layer (15) and a second porous layer (16).

Pitts, J. Roland; Lee, Se-Hee; Tracy, C. Edwin; Li, Wenming

2014-04-08T23:59:59.000Z

424

Production of Oxygen Gas and Liquid Metal by Electrochemical Decomposition of Molten Iron Oxide  

E-Print Network [OSTI]

on the moon and on Mars for the generation of oxygen along with the production of structural metalsProduction of Oxygen Gas and Liquid Metal by Electrochemical Decomposition of Molten Iron Oxide) is the electrolytic decomposition of a metal oxide, most preferably into liquid metal and oxygen gas. The successful

Sadoway, Donald Robert

425

Alternative Electrochemical Salt Waste Forms, Summary of FY/CY2011 Results  

SciTech Connect (OSTI)

This report summarizes the 2011 fiscal+calendar year efforts for developing waste forms for a spent salt generated in reprocessing nuclear fuel with an electrochemical separations process. The two waste forms are tellurite (TeO2-based) glasses and sol-gel-derived high-halide mineral analogs to stable minerals found in nature.

Riley, Brian J.; McCloy, John S.; Crum, Jarrod V.; Rodriguez, Carmen P.; Windisch, Charles F.; Lepry, William C.; Matyas, Josef; Westman, Matthew P.; Rieck, Bennett T.; Lang, Jesse B.; Pierce, David A.

2011-12-01T23:59:59.000Z

426

Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent  

E-Print Network [OSTI]

Electrochemical studies of moderately boron doped polycrystalline diamond in non-aqueous solvent being marketed [83,84]. The first paper on the electrochemistry of boron doped polycrystalline diamond The electrochemistry of boron doped diamond is currently an active field of research. In the majority of studies

Bristol, University of

427

Electrochemical gating of individual single-wall carbon nanotubes observed by electron transport measurements and resonant  

E-Print Network [OSTI]

, the Fermi energy of a nanotube can be changed, as ions from the solution accu- mulate on the surface gating of nanotubes has been shown previously to effectively shift the Fermi energy of semiconducting with the laser energy, we can observe the Raman spectrum from a single SWNT.7 Electrochemical gating of nanotubes

428

Materials Development for Improved Efficiency of Hydrogen Production by Steam Electrolysis and Thermochemical-Electrochemical Processes  

E-Print Network [OSTI]

as potential sources of hydrogen for the "hydrogen economy". One of these hydrogen production processesMaterials Development for Improved Efficiency of Hydrogen Production by Steam Electrolysis-electrochemical hydrogen production cycle that produces hydrogen from water, also using heat from a nuclear reactor

Yildiz, Bilge

429

Estimation of CO concentration in high temperature PEM fuel cells using electrochemical impedance spectroscopy  

E-Print Network [OSTI]

Estimation of CO concentration in high temperature PEM fuel cells using electrochemical impedance (Numbers are presented in Tian et al. (2010)) and cost effectiveness (Price development for Fuel Cells / grid during the test. Efforts have been made in increasing operating temperatures of PEM fuel cells

Berning, Torsten

430

Electrochemical Characterization of Liquid Phase Exfoliated Two-Dimensional Layers of Molybdenum Disulfide  

E-Print Network [OSTI]

Electrochemical Characterization of Liquid Phase Exfoliated Two- Dimensional Layers of Molybdenum of molybdenum disulfide (MoS2) obtained by liquid phase exfoliation of bulk MoS2 powder in 1-dodecyl-2-pyrrolidinone. The specific capacitances of the exfoliated flakes obtained using a 6 M KOH aqueous solution

431

Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries  

E-Print Network [OSTI]

on larger scales. Im- provement of the safety of lithium-ion batteries must occur if they are to be utilized in aqueous cells. However, the choice of a suitable anode material for an aqueous lithium-ion battery is moreSynthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium

Cui, Yi

432

Hexavalent chromium synthesized polyaniline nanostructures: Magnetoresistance and electrochemical energy storage behaviors  

E-Print Network [OSTI]

energy storage behaviors Hongbo Gu a,b,1 , Huige Wei a,c,1 , Jiang Guo a,1 , Neel Haldolaarachige d 2013 Keywords: Polyaniline Magnetoresistance Energy storage a b s t r a c t In this work, the oxidant was analyzed by the wave-function shrinkage model. The electrochemical energy storage was investigated using

Guo, John Zhanhu

433

ALUMINUM-BRIDGED BISGLYOXIMATO COBALT COMPLEXES: SYNTHESIS AND ELECTROCHEMICAL PROTON REDUCTION PROPERTIES  

E-Print Network [OSTI]

194 CHAPTER 6 ALUMINUM-BRIDGED BISGLYOXIMATO COBALT COMPLEXES: SYNTHESIS AND ELECTROCHEMICAL PROTON diglyoximato complexes connected by one or two aluminum bridges are described. The aluminum centers that the number of aluminum bridges and the nature of the substituents on the phenoxide ligands significantly

Winfree, Erik

434

Synthesis and characterization of a nanocomposite of goethite nanorods and reduced graphene oxide for electrochemical capacitors  

SciTech Connect (OSTI)

We report a one-step synthesis of a nanocomposite of goethite ({alpha}-FeOOH) nanorods and reduced graphene oxide (RGO) using a solution method in which ferrous cations serve as a reducing agent of graphite oxide (GO) to graphene and a precursor to grow goethite nanorods. As-prepared goethite nanorods have an average length of 200 nm and a diameter of 30 nm and are densely attached on both sides of the RGO sheets. The electrochemical properties of the nanocomposite were characterized by cyclic voltammetry (CV) and chronopotentiometry (CP) charge-discharge tests. The results showed that goethite/RGO composites have a high electrochemical capacitance of 165.5 F g{sup -1} with an excellent recycling capability making the material promising for electrochemical capacitors. - Graphical abstract: The reduced graphene oxide sheets are decorated with goethite nanorods. The as-prepared composite exhibits a high electrochemical capacitance with good recycling capability, which is promising for supercapacitor applications. Higlights: Black-Right-Pointing-Pointer Ferrous ions act as reductant of graphite oxide and precursor of goethite nanorods. Black-Right-Pointing-Pointer Goethite nanorods are attached on both sides of the reduced graphene oxide sheets. Black-Right-Pointing-Pointer Composite exhibits a high specific capacitance and a good recycling capability. Black-Right-Pointing-Pointer Composite is promising for supercapacitor applications.

Shou Qingliang [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Cheng Jipeng, E-mail: chengjp@zju.edu.cn [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Zhang Li, E-mail: lizhang@ethz.ch [Institute of Robotics and Intelligent Systems, ETH Zurich, CH-8092 Zurich (Switzerland); Nelson, Bradley J. [Institute of Robotics and Intelligent Systems, ETH Zurich, CH-8092 Zurich (Switzerland); Zhang Xiaobin [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027 (China)

2012-01-15T23:59:59.000Z

435

Algorithm Development for Electrochemical Impedance Spectroscopy Diagnostics in PEM Fuel Cells  

E-Print Network [OSTI]

Algorithm Development for Electrochemical Impedance Spectroscopy Diagnostics in PEM Fuel Cells Abstract The purpose of this work is to develop algorithms to identify fuel cell faults using-board fuel cell diagnostic hardware. Impedance can identify faults that cannot be identified solely by a drop

Victoria, University of

436

J. Electrochem. Soc., in press (1998) Micro-Macroscopic Coupled Modeling of Batteries and Fuel Cells  

E-Print Network [OSTI]

to simulate batteries and fuel cells was described. The model is capable of incorporating interfacial non1 J. Electrochem. Soc., in press (1998) Micro-Macroscopic Coupled Modeling of Batteries and Fuel Cells Part 2. Application to Nickel-Cadmium and Nickel-Metal Hydride Cells W.B. Gu and C.Y. Wang 1

Wang, Chao-Yang

437

J. Electrochem. Soc., in press (1998) MicroMacroscopic Coupled Modeling of Batteries and Fuel Cells  

E-Print Network [OSTI]

to simulate batteries and fuel cells was described. The model is capable of incorporating interfacial non1 J. Electrochem. Soc., in press (1998) Micro­Macroscopic Coupled Modeling of Batteries and Fuel Cells Part 2. Application to Nickel­Cadmium and Nickel­Metal Hydride Cells W.B. Gu and C.Y. Wang 1

Wang, Chao-Yang

438

An electrochemically reduced graphite-cobalt compound : synthesis and magnetic study  

E-Print Network [OSTI]

direct intercalation of transition metals into graphite. One of the reasons could be the very high to metal- carbides formation than G.I.C.'s. Only indirect pre- paration methods have been described by many authors mostly consisting on a chemical [2-7] or electrochemical [8-10] reduction of the transition metal

Paris-Sud XI, Université de

439

In Situ Tribo-Electrochemical Characterization of Diamond-Containing Materials  

E-Print Network [OSTI]

diamond carbon (sp^(3)) to amorphous carbon (sp^(2)) is confirmed by Raman spectroscopy in the diamond composite. The surface roughness of the diamond grits was found to be greatly reduced due to wear. A tribo-electrochemical method is developed to in situ...

Xiao, Huaping

2014-07-31T23:59:59.000Z

440

Development of a Novel Electrochemical Method to Deposit High Corrosion Resistant Silicate Layers on Metal  

E-Print Network [OSTI]

Development of a Novel Electrochemical Method to Deposit High Corrosion Resistant Silicate Layers LLC, Moberly, Missouri 65270, USA A novel method for electrodepositing silicates on metallic on galvanized steel. The silicate layer was deposited cathodically from a bath containing PQ Corporation N

Popov, Branko N.

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Effective Panchromatic Sensitization of Electrochemical Solar Cells: Strategy and Organizational Rules for Spatial Separation of  

E-Print Network [OSTI]

Effective Panchromatic Sensitization of Electrochemical Solar Cells: Strategy and Organizational efficiencies. In only a few cases, however, have significant overall improvements been obtained. In most other (JSC = 14.6 mA cm-2 ) and double the efficiency of randomly mixed dyes, once the dyes were optimally

442

TAS-2013-0043 1 Abstract--Fuel cells are electrochemical energy converters  

E-Print Network [OSTI]

of the perfectly direct current relies upon a fuel cell fed by hydrogen. The main advantages to be taken from fuelTAS-2013-0043 1 Abstract--Fuel cells are electrochemical energy converters which allow generation. Fuel cells are then by essence low voltage sources , so that for most practical applications

Boyer, Edmond

443

CONTROLLED PART-TO-SUBSTRATE MICRO-ASSEMBLY VIA ELECTROCHEMICAL MODULATION OF SURFACE ENERGY  

E-Print Network [OSTI]

the hydro- phobicity of the binding sites between micro-parts and substrates. Active assembly sites consistCONTROLLED PART-TO-SUBSTRATE MICRO-ASSEMBLY VIA ELECTROCHEMICAL MODULATION OF SURFACE ENERGY-2500, USA ABSTRACT A process designed for repeated parallel micro- assembly has been achieved by controlling

444

A round robin evaluation of the corrosiveness of wet residential insulation by electrochemical measurements  

SciTech Connect (OSTI)

The results of a round cabin evaluation of the use of an electrochemical method of calculating the corrosion rate of low carbon steel in environments related to cellulosic building insulations are reported. Environments included the leachate from a wet cellulosic insulation and solutions based on pure and commercial grades of borax, ammonium sulfate and aluminum sulfate. The pH values of these environments were in the range of 2.5 to 9.5. Electrochemical measurements were made using a direct reading corrosion rate instrument. The calculated corrosion rates were compared with those determined directly by weight loss measurements. Electrochemical measurements were made over a period of 48 hours and weight loss exposures were for two weeks. Poor agreement was observed for the corrosion rates determined electrochemically and the values were consistently larger than those based on weight loss. Reasons proposed for these results included the complex nature of the corrosion product deposits and the control these deposits have on oxygen diffusion to the metal interface. Both factors influence the validity of the calculation of the corrosion rate by the direct reading instrument. It was concluded that development of a viable electrochemical method of general applicability to the evaluation of the corrosiveness of wet residential building thermal insulations were doubtful. Because of the controlling influence of dissolved oxygen on the corrosion rate in the insulation leachate, an alternate evaluation method is proposed in which a thin steel specimen is partially immersed in wet insulation for three weeks. The corrosiveness of the wet insulation is evaluated in terms of the severity of attack near the metal-air-wet insulation interface. With thin metal specimens, complete penetration along the interface is proposed as a pass/fail criterion. An environment of sterile cotton wet with distilled water is proposed as a comparative standard. 9 refs., 2 figs., 3 tabs.

Stansbury, E.E. (Stansbury (E.E.), Knoxville, TN (United States))

1991-10-01T23:59:59.000Z

445

Modeling and simulations of electrical energy storage in electrochemical capacitors  

E-Print Network [OSTI]

energy storage systems (EES) have been the subject of intense study as they constitute an essential element in the development of sustainable energy

Wang, Hainan

2013-01-01T23:59:59.000Z

446

624 Electrochemical and Solid-State Letters, 2 (12) 624-626 (1999) S1099-0062(99)07-005-4 CCC: $7.00 The Electrochemical Society, Inc.  

E-Print Network [OSTI]

624 Electrochemical and Solid-State Letters, 2 (12) 624-626 (1999) S1099-0062(99)07-005-4 CCC: $7.00 © The Electrochemical Society, Inc. A NiFeMo Electroplating Bath for Micromachined Structures William P. Taylor,a,*,c Michael Schneider,b,* Henry Baltes,b,* and Mark G. Allena,z aGeorgia Institute of Technology, School

447

Proceedings of the 31. intersociety energy conversion engineering conference. Volume 2: Conversion technologies, electro-chemical technologies, Stirling engines, thermal management  

SciTech Connect (OSTI)

The 148 papers contained in Volume 2 are arranged topically as follows -- (A) Conversion Technologies: Superconductivity applications; Advanced cycles; Heat engines; Heat pumps; Combustion and cogeneration; Advanced nuclear reactors; Fusion Power reactors; Magnetohydrodynamics; Alkali metal thermal to electric conversion; Thermoelectrics; Thermionic conversion; Thermophotovoltaics; Advances in electric machinery; and Sorption technologies; (B) Electrochemical Technologies: Terrestrial fuel cell technology; and Batteries for terrestrial power; (C) Stirling Engines: Stirling machine analysis; Stirling machine development and testing; and Stirling component analysis and testing; (D) Thermal Management: Cryogenic heat transfer; Electronic components and power systems; Environmental control systems; Heat pipes; Numeric analysis and code verification; and Two phase heat and mass transfer. Papers within the scope of the data base have been processed separately.

Chetty, P.R.K.; Jackson, W.D.; Dicks, E.B. [eds.

1996-12-31T23:59:59.000Z

448

Kinetic Effects of the Electrochemical Proton Gradient on Plastoquinone Reduction at the Qi Site of the Cytochrome  

E-Print Network [OSTI]

Kinetic Effects of the Electrochemical Proton Gradient on Plastoquinone Reduction at the Qi Site- bonylcyanide p-(trifluoromethoxy)phenylhydrazone (FCCP) revealed a marked inhibition of the cytochrome b6

449

Structural and Electrochemical Characterization of Binary, Ternary, and Quaternary Platinum Alloy Catalysts for Methanol Electro-oxidation1  

E-Print Network [OSTI]

Structural and Electrochemical Characterization of Binary, Ternary, and Quaternary Platinum Alloy methanol fuel cells (DMFC's) at 60 °C show that the best Pt-Ru-Os-Ir compositions are markedly superior

450

Three-Dimensionally Ordered Macroporous Li4Ti5O12: Effect of Wall Structure on Electrochemical Properties  

E-Print Network [OSTI]

Three-Dimensionally Ordered Macroporous Li4Ti5O12: Effect of Wall Structure on Electrochemical, and the materials evaluated in lithium ion battery cells. The 3DOM architecture was found to markedly improve

Poeppelmeier, Kenneth R.

451

Growth and Electrochemical Properties of Single-Crystalline V2O5 Nanorod Arrays Katsunori TAKAHASHI1;2  

E-Print Network [OSTI]

-dimensional nanostructures, such as nanowires, nano- rods, and hollow tubes.3­7) Template-based synthesis is one of the most intercalation. The relationships between electrochemical property, nano- and microstructure, and growth

Cao, Guozhong

452

A novel way of detecting transient cavitation near a solid surface during megasonic cleaning using electrochemical impedance spectroscopy  

E-Print Network [OSTI]

A novel way of detecting transient cavitation near a solid surface during megasonic cleaning using Keywords: Megasonic cleaning Transient cavitation Acoustic streaming Microelectrode Electrochemical to transient cavitation. Development of a method to monitor transient cavitation events in solutions irradiated

Deymier, Pierre

453

Electrochemical Behavior and Li Diffusion Study of LiCoO? Thin Film Electrodes Prepared by PLD  

E-Print Network [OSTI]

Preferred c-axis oriented LiCoO? thin films were prepared on the SiO?/Si (SOS) substrates by pulsed laser deposition (PLD). Thin film electrodes without carbon and binder are ideal samples to study the electrochemical ...

Xia, H.

454

Electrochemical Waves on Patterned Surfaces: Propagation through Narrow Gaps and Konstantin Agladze, Stephanie Thouvenel-Romans, and Oliver Steinbock*  

E-Print Network [OSTI]

Electrochemical Waves on Patterned Surfaces: Propagation through Narrow Gaps and Channels propagation through narrow gaps and long channels. In channels, the wave velocity decreases with decreasing dynamically similar phenomena such as propagating fronts, target patterns, and rotating spiral waves. Pattern

Steinbock, Oliver

455

Three-Dimensional Thermal-Electrochemical Coupled Model for Spirally Wound Large-Format Lithium-Ion Batteries (Presentation)  

SciTech Connect (OSTI)

This presentation discusses the behavior of spirally wound large-format Li-ion batteries with respect to their design. The objectives of the study include developing thermal and electrochemical models resolving 3-dimensional spirally wound structures of cylindrical cells, understanding the mechanisms and interactions between local electrochemical reactions and macroscopic heat and electron transfers, and developing a tool and methodology to support macroscopic designs of cylindrical Li-ion battery cells.

Lee, K. J.; Smith K.; Kim, G. H.

2011-04-01T23:59:59.000Z

456

Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices  

DOE Patents [OSTI]

The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

2010-11-23T23:59:59.000Z

457

Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices  

DOE Patents [OSTI]

The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

2010-03-02T23:59:59.000Z

458

A comparison of the electrochemical behavior of carbon aerogels and activated carbon fiber cloths  

SciTech Connect (OSTI)

Electrochemical capacitative behavior of carbon aerogels and commercial carbon fiber cloths was studied in 5M KOH, 3M sulfuric acid, and 0.5M tetrethylammonium tetrafluoroborate/propylene carbonate electrolytes. The resorcinol-formaldehyde based carbon aerogels with a range of denisty (0.2-0.85 g/cc) have open-cell structures with ultrafine pore sizes (5-50 nm), high surface area (400-700 m{sup 2}/g), and a solid matrix composed of interconnected particles or fibers with characteristic diameters of 10 nm. The commercial fiber cloths in the density range 0.2-04g/cc have high surface areas (1000-2500 m{sup 2}/g). The volumetric capacitances of high-density aerogels are shown to be comparable to or exceeding those from activated carbon fibers. Electrochemical behavior of these materials in various electrolytes is compared and related to their physical properties.

Tran, T.D.; Alviso, C.T.; Hulsey, S.S.; Nielsen, J.K.; Pekala, R.W.

1996-05-10T23:59:59.000Z

459

Demonstrating Dynamic Wireless Charging of an Electric Vehicle - The benefit of Electrochemical Capacitor Smoothing  

SciTech Connect (OSTI)

The wireless charging of an electric vehicle (EV) while it is in motion presents challenges in terms of low-latency communications for roadway coil excitation sequencing and maintenance of lateral alignment, plus the need for power-flow smoothing. This article summarizes the experimental results on power smoothing of in-motion wireless EV charging performed at the Oak Ridge National Laboratory (ORNL) using various combinations of electrochemical capacitors at the grid side and in the vehicle. Electrochemical capacitors of the symmetric carbon carbon type from Maxwell Technologies comprised the in-vehicle smoothing of wireless charging current to the EV battery pack. Electro Standards Laboratories (ESL) fabricated the passive and active parallel lithium-capacitor (LiC) unit used to smooth the grid-side power. The power pulsation reduction was 81% on the grid by the LiC, and 84% on the vehicle for both the LiC and the carbon ultracapacitors (UCs).

Miller (JNJ), John M. [JNJ-Miller PLC] [JNJ-Miller PLC; Onar, Omer C [ORNL] [ORNL; White, Cliff P [ORNL] [ORNL; Campbell, Steven L [ORNL] [ORNL; Coomer, Chester [ORNL] [ORNL; Seiber, Larry Eugene [ORNL] [ORNL; Sepe, Raymond B [ORNL] [ORNL; Steyerl, Anton [ORNL] [ORNL

2014-01-01T23:59:59.000Z

460

Direct electrochemical conversion of carbon anode fuels in molton salt media  

SciTech Connect (OSTI)

We are conducting research into the direct electrochemical conversion of reactive carbons into electricity--with experimental evidence of total efficiencies exceeding 80% of the heat of combustion of carbon. Together with technologies for extraction of reactive carbons from broad based fossil fuels, direct carbon conversion addresses the objectives of DOE's ''21st Century Fuel Cell'' with exceptionally high efficiency (>70% based on standard heat of reaction, {Delta}H{sub std}), as well as broader objectives of managing CO{sub 2} emissions. We are exploring the reactivity of a wide range of carbons derived from diverse sources, including pyrolyzed hydrocarbons, petroleum cokes, purified coals and biochars, and relating their electrochemical reactivity to nano/microstructural characteristics.

Cherepy, N; Krueger, R; Cooper, J F

2001-01-17T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Method of enhancing the wettability of boron nitride for use as an electrochemical cell separator  

DOE Patents [OSTI]

A felt or other fabric of boron nitride suitable for use as an interelecte separator within an electrochemical cell is wetted with a solution containing a thermally decomposable organic salt of an alkaline earth metal. An aqueous solution of magnesium acetate is the preferred solution for this purpose. After wetting the boron nitride, the solution is dried by heating at a sufficiently low temperature to prevent rapid boiling and the creation of voids within the separator. The dried material is then calcined at an elevated temperature in excess of 400.degree. C. to provide a coating of an oxide of magnesium on the surface of the boron nitride fibers. A fabric or felt of boron nitride treated in this manner is easily wetted by molten electrolytic salts, such as the alkali metal halides or alkaline earth metal halides, that are used in high temperature, secondary electrochemical cells.

McCoy, Lowell R. (Woodland Hills, CA)

1982-01-01T23:59:59.000Z

462

Method of enhancing the wettability of boron nitride for use as an electrochemical cell separator  

DOE Patents [OSTI]

A felt or other fabric of boron nitride suitable for use as an interelectrode separator within an electrochemical cell is wetted with a solution containing a thermally decomposable organic salt of an alkaline earth metal. An aqueous solution of magnesium acetate is the preferred solution for this purpose. After wetting the boron nitride, the solution is dried by heating at a sufficiently low temperature to prevent rapid boiling and the creation of voids within the separator. The dried material is then calcined at an elevated temperature in excess of 400/sup 0/C to provide a coating of an oxide of magnesium on the surface of the boron nitride fibers. A fabric or felt of boron nitride treated in this manner is easily wetted by molten electrolytic salts, such as the alkali metal halides or alkaline earth metal halides, that are used in high temperature, secondary electrochemical cells.

McCoy, L.R.

1981-01-23T23:59:59.000Z

463

Method and apparatus for capacitive deionization and electrochemical purification and regeneration of electrodes  

DOE Patents [OSTI]

An electrically regeneratable electrochemical cell (30) for capacitive deionization and electrochemical purification and regeneration of electrodes includes two end plates (31, 32), one at each end of the cell (30). A new regeneration method is applied to the cell (30) which includes slowing or stopping the purification cycle, electrically desorbing contaminants and removing the desorbed contaminants. The cell (30) further includes a plurality of generally identical double-sided intermediate electrodes (37-43) that are equidistally separated from each other, between the two end electrodes (35, 36). As the electrolyte enters the cell, it flows through a continuous open serpentine channel (65-71) defined by the electrodes, substantially parallel to the surfaces of the electrodes. By polarizing the cell (30), ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes. The cell (30) is regenerated electrically to desorb such previously removed ions.

Tran, Tri D. (Livermore, CA); Farmer, Joseph C. (Tracy, CA); Murguia, Laura (Manteca, CA)

2001-01-01T23:59:59.000Z

464

Thermal management systems and methods  

DOE Patents [OSTI]

A thermal management system for a vehicle includes a heat exchanger having a thermal energy storage material provided therein, a first coolant loop thermally coupled to an electrochemical storage device located within the first coolant loop and to the heat exchanger, and a second coolant loop thermally coupled to the heat exchanger. The first and second coolant loops are configured to carry distinct thermal energy transfer media. The thermal management system also includes an interface configured to facilitate transfer of heat generated by an internal combustion engine to the heat exchanger via the second coolant loop in order to selectively deliver the heat to the electrochemical storage device. Thermal management methods are also provided.

Gering, Kevin L.; Haefner, Daryl R.

2006-12-12T23:59:59.000Z

465

The effect of hydrocarbons on the electrochemical potential across porous media  

E-Print Network [OSTI]

and potential across porous media containing hydro- carbons. To fill this need, research was uruiegtaken with the objective to measure the electrochemical potential across porous media at various hydrocarbon saturations, and to correlate any significant... Central Scientific Co. Megavac vacuum pump, capable of reducing the pressure to . 000i mm of mercury. Centrifuge Water saturation was controlled in each sample by means of an International Equipment Co. Model CAK Centrifuge shown in Figure 6. A...

McCall, Charles Mark

1970-01-01T23:59:59.000Z

466

Mediated electrochemical oxidation of organic wastes using a Co(III) mediator in a neutral electrolyte  

DOE Patents [OSTI]

An electrochemical cell with a Co(III) mediator and neutral pH anolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the cobalt mediator oxidizes the organics and insoluble radioactive species and is regenerated at the anode until all organics are converted to carbon dioxide and destroyed. The neutral electrolyte is non-corrosive, and thus extends the lifetime of the cell and its components.

Balazs, G. Bryan (Livermore, CA); Lewis, Patricia R. (Livermore, CA)

1999-01-01T23:59:59.000Z

467

Electrochemical evaluation of LiCoO2 synthesized by decomposition and intercalation of hydroxides  

E-Print Network [OSTI]

in commercial lithi- um-ion battery manufacturing [4±6]. Synthesis of LiCoO2 is typically carried out by a solid-state March 1998; accepted in revised form 19 May 1998 LiCoO2 has been synthesized by a solid-state synthesis the electrochemical perfor- mance. In a previous paper [13], we reported a new solid- state reaction method that can

Sadoway, Donald Robert

468

ELECTROCHEMICAL CORROSION STUDIES CORE 308 SEGMENTS 14R1 & 14R2 TANK 241-AY-102  

SciTech Connect (OSTI)

This document reports the results of electrochemical corrosion tests on AS1S Grade 60 carbon steel coupons exposed to tank 241-AY-102 sludge under conditions similar to those near the bottom of the tank. The tests were performed to evaluate the corrosive behavior of the waste in contact with sludge that does not meet the chemistry control limits of Administrative Control (AC) 5.15, Corrosion Mitigation Program.

DUNCAN JB; COOKE GA

2003-10-30T23:59:59.000Z

469

Mediated electrochemical oxidation of organic wastes using a Co(III) mediator in a neutral electrolyte  

DOE Patents [OSTI]

An electrochemical cell with a Co(III) mediator and neutral pH anolyte provides efficient destruction of organic and mixed wastes. The organic waste is concentrated in the anolyte reservoir, where the cobalt mediator oxidizes the organics and insoluble radioactive species and is regenerated at the anode until all organics are converted to carbon dioxide and destroyed. The neutral electrolyte is non-corrosive, and thus extends the lifetime of the cell and its components. 2 figs.

Balazs, G.B.; Lewis, P.R.

1999-07-06T23:59:59.000Z

470

Synthesis and electrochemical capacitance of long tungsten oxide nanorod arrays grown vertically on substrate  

SciTech Connect (OSTI)

Highlights: ? Growth of long amorphous tungsten oxide nanorods on a substrate. ? Formation of single-crystalline tungsten oxide nanorods by a heat-treatment. ? High electrochemical pseudocapacitance of 2.8 mF cm{sup ?2}. ? Excellent cyclability of psuedocapacitance up to 1000 cycles. -- Abstract: Long tungsten oxide nanorods are vertically grown on Al/W/Ti coated silicon substrates using a two-step anodization process. The first anodization of the Al film forms a mesh-like mask of anodic aluminum oxide, and the second anodization of the W film results in the formation of a buffer layer, a bottom nanorod, and a top nanorod of amorphous tungsten oxide. A pore-widening process prior to the second anodization leads to the enhancement of nanorod length above approximately 500 nm. After a heat-treatment, the tungsten oxide nanorods are crystallized to form a single crystalline structure while the buffer layer forms a polycrystalline structure. The crystalline tungsten oxide nanorods show a cyclic voltammogram retaining the quasi-rectangular shape of an electrochemically reversible faradaic redox reaction, i.e., a typical pseudocapacitive behavior. The maximum electrochemical capacitance per apparent surface area reaches approximately 2.8 mF cm{sup ?2} at the voltage scan rate of 20 mV s{sup ?1}, and the excellent cyclability of charge–discharge process is maintained up to 1000 cycles.

Park, Sun Hwa [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of)] [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of); Kim, Young Heon; Lee, Tae Geol; Shon, Hyun Kyong [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of)] [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Park, Hyun Min [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of) [Department of Nanomaterials Science and Engineering, University of Science and Technology, Daejeon 305-350 (Korea, Republic of); Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Song, Jae Yong, E-mail: jysong@kriss.re.kr [Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of); Department of Nano Science, University of Science and Technology, Daejeon 305-350 (Korea, Republic of)

2012-11-15T23:59:59.000Z

471

Highly Quantitative Electrochemical Characterization of Non-Aqueous Electrolytes & Solid Electrolyte Interphases  

SciTech Connect (OSTI)

The methods to measure solid electrolyte interphase (SEI) electrochemical properties and SEI formation capability of non-aqueous electrolyte solutions are not adequately addressed in the literature. And yet, there is a strong demand in new electrolyte generations that promote stabilized SEIs and have an influence to resolve safety, calendar life and other limitations of Li-ion batteries. To fill this gap, in situ electrochemical approach with new descriptive criteria for highly quantitative characterization of SEI and electrolytes is proposed. These criteria are: SEI formation capacity, SEI corrosion rate, SEI maintenance rate, and SEI kinetic stability. These criteria are associated with battery parameters like irreversible capacity, self-discharge, shelf-life, power, etc. Therefore, they are especially useful for electrolyte development and standard fast screening, allowing a skillful approach to narrow down the search for the best electrolyte. The characterization protocol also allows retrieving information on interfacial resistance for SEI layers and the electrochemical window of electrolytes, the other important metrics of characterization. The method validation was done on electrolyte blends containing phosphazenes, developed at Idaho National Laboratory, as 1.2M LiPF6 [80 % EC-MEC (2:8) (v/v) + 20% Phosphazene variety] (v/v), which were targeted for safer electrolyte variations.

Sergiy V. Sazhin; Kevin L. Gering; Mason K. Harrup; Harry W. Rollins

2012-10-01T23:59:59.000Z

472

Real-time studies of battery electrochemical reactions inside a transmission electron microscope.  

SciTech Connect (OSTI)

We report the development of new experimental capabilities and ab initio modeling for real-time studies of Li-ion battery electrochemical reactions. We developed three capabilities for in-situ transmission electron microscopy (TEM) studies: a capability that uses a nanomanipulator inside the TEM to assemble electrochemical cells with ionic liquid or solid state electrolytes, a capability that uses on-chip assembly of battery components on to TEM-compatible multi-electrode arrays, and a capability that uses a TEM-compatible sealed electrochemical cell that we developed for performing in-situ TEM using volatile battery electrolytes. These capabilities were used to understand lithiation mechanisms in nanoscale battery materials, including SnO{sub 2}, Si, Ge, Al, ZnO, and MnO{sub 2}. The modeling approaches used ab initio molecular dynamics to understand early stages of ethylene carbonate reduction on lithiated-graphite and lithium surfaces and constrained density functional theory to understand ethylene carbonate reduction on passivated electrode surfaces.

Leung, Kevin; Hudak, Nicholas S.; Liu, Yang; Liu, Xiaohua H.; Fan, Hongyou; Subramanian, Arunkumar; Shaw, Michael J.; Sullivan, John Patrick; Huang, Jian Yu

2012-01-01T23:59:59.000Z

473

The thermodynamics of proton hydration and the electrochemical surface potential of water  

SciTech Connect (OSTI)

The free energy change for transferring a single ion across the water liquid/vapor interface includes an electrochemical surface potential contribution. Since this potential is not directly accessible to thermodynamic measurement, several extra-thermodynamic approaches have been employed to infer its sign and magnitude, with a resulting wide spread of values. Here, we examine further the thermodynamics of proton hydration and the electrochemical surface potential of water along three directions: (1) a basic relation of interfacial electrostatics and experimental results on ion distributions near a water/organic interface are employed to infer a solvent contribution to the electrochemical surface potential, (2) a re-analysis is performed of the existing bulk and cluster ion hydration data, and (3) extensive computational modeling is conducted to examine the size dependence of hydration enthalpy differences for the NaF ion pair between the small cluster and the converged bulk limits. The computational studies include classical polarizable models and high-level quantum chemical methods. The new theoretical analysis of existing experimental data and the combined classical/quantum modeling lead to results consistent with our previously derived proton hydration quantities.

Pollard, Travis P. [Department of Chemistry, University of Cincinnati, Cincinnati, Ohio 45221 (United States); Beck, Thomas L. [Department of Chemistry, University of Cincinnati, Cincinnati, Ohio 45221 (United States); Department of Physics, University of Cincinnati, Cincinnati, Ohio 45221 (United States)

2014-11-14T23:59:59.000Z

474

Report on the source of the electrochemical impedance on cermet inert anodes  

SciTech Connect (OSTI)

the Inert Electrode Program at Pacific Northwest Laboratory (PNL) is supported by the Office of Industrial Processes of the US Department of Energy and is aimed at improving the energy efficiency of Hall-Heroult cells through the development of inert anodes. The inert anodes currently under study are composed of a cermet material of the general composition NiO-NiFe{sub 2}O{sub 4}-Cu. The program has three primary objectives: (a) to evaluate the anode material in a scaled-up, pilot cell facility, (b) to investigate the mechanisms of the electrochemical reactions at the anode surface, and (c) to develop sensors for monitoring anode and/or electrolyte conditions. This report covers the results of a portion of the studies on anode reaction mechanisms. The electrochemical impedances of cermet inert anodes in alumina-saturated molten cryolite as a function of frequency, current density, and time indicated that a significant component of the impedance is due to the gas bubbles produced at the anode during electrolysis. The data also showed a connection between surface structure and impedance that appears to be related to the effects of surface structure on bubble flow. Given the results of this work, it is doubtful that a resistive film contributes significantly to the electrochemical impedances on inert anodes. Properties previously assigned to such a film are more likely due to the bubbles and those factors that affect the properties and dynamics of the bubbles at the anode surface. 12 refs., 16 figs., 3 tabs.

Windisch, C.F. Jr.; Stice, N.D.

1991-02-01T23:59:59.000Z

475

ORIGINAL PAPER Electrochemical reduction of oxygen with iron phthalocyanine  

E-Print Network [OSTI]

bio- fuel cells) has been increasing [1­6]. The common point for all the biological systems is need Recent interest in electricity production using microbial fuel cells makes it important to better applications in neutral media. Keywords Microbial fuel cells Á Oxygen reduction Á Iron phthalocyanine Á Redox

476

Electrochemically Mediated Separation for Carbon Capture Michael C. Sterna  

E-Print Network [OSTI]

change [1]. Since the industrial revolution, fossil fuels have become the primary energy source potential for facilitating CO2 capture at industrial-scale carbon emitters; however, the total operational of installing an electrically driven separation system would also allow its application to other industrial

477

Thermal-fluid and electrochemical modeling and performance study of a planar solid oxide electrolysis cell : analysis on SOEC resistances, size, and inlet flow conditions.  

SciTech Connect (OSTI)

Argonne National Laboratory and Idaho National Laboratory researchers are analyzing the electrochemical and thermal-fluid behavior of solid oxide electrolysis cells (SOECs) for high temperature steam electrolysis using computational fluid dynamics (CFD) techniques. The major challenges facing commercialization of steam electrolysis technology are related to efficiency, cost, and durability of the SOECs. The goal of this effort is to guide the design and optimization of performance for high temperature electrolysis (HTE) systems. An SOEC module developed by FLUENT Inc. as part of their general CFD code was used for the SOEC analysis by INL. ANL has developed an independent SOEC model that combines the governing electrochemical mechanisms based on first principals to the heat transfer and fluid dynamics in the operation of SOECs. The ANL model was embedded into the commercial STAR-CD CFD software, and is being used for the analysis of SOECs by ANL. The FY06 analysis performed by ANL and reported here covered the influence of electrochemical properties, SOEC component resistances and their contributing factors, SOEC size and inlet flow conditions, and SOEC flow configurations on the efficiency and expected durability of these systems. Some of the important findings from the ANL analysis are: (1) Increasing the inlet mass flux while going to larger cells can be a compromise to overcome increasing thermal and current density gradients while increasing the cell size. This approach could be beneficial for the economics of the SOECs; (2) The presence of excess hydrogen at the SOEC inlet to avoid Ni degradation can result in a sizeable decrease in the process efficiency; (3) A parallel-flow geometry for SOEC operation (if such a thing be achieved without sealing problems) yields smaller temperature gradients and current density gradients across the cell, which is favorable for the durability of the cells; (4) Contact resistances can significantly influence the total cell resistance and cell temperatures over a large range of operating potentials. Thus it is important to identify and avoid SOEC stack conditions leading to such high resistances due to poor contacts.

Yildiz, B.; Smith, J.; Sofu, T.; Nuclear Engineering Division

2008-06-25T23:59:59.000Z

478

Electrochemical investigation of the energetics of particulate titanium dioxide photocatalysts. The methyl viologen-acetate system  

SciTech Connect (OSTI)

Addition of methyl viologen (MV/sup 2 +/) enhances the anodic currents observed for TiO/sub 2/ suspensions under illumination by trapping of photogenerated electrons with formation of MV/sup +/. The magnitude of the photocurrent depends upon the relative location of the semiconductor Fermi level and E/sub redox/ of the MV/sup 2 +//MV/sup +/.couple. The location of the Fermi level in the anatase powders was estimated as -0.05 V vs. NHE (pH 0) based on the observed variation of photocurrent with pH. The shift in the quasi-Fermi level with light intensity is also discussed.

Ward, M.D.; White, J.R.; Bard, A.J.

1983-01-12T23:59:59.000Z

479

Design of a Safeguards Instrument for Plutonium Quantification in an Electrochemical Refining System  

E-Print Network [OSTI]

There has been a strong international interest in using pyroprocessing to close the fast nuclear reactor fuel cycle and reprocess spent fuel efficiently. To commercialize pyroprocessing, safeguards technologies are required to be developed...

Le Coq, Annabelle G

2013-06-25T23:59:59.000Z

480

Electrochemical impedance spectroscopy system and methods for determining spatial locations of defects  

DOE Patents [OSTI]

A method and apparatus for determining spatial locations of defects in a material are described. The method includes providing a plurality of electrodes in contact with a material, applying a sinusoidal voltage to a select number of the electrodes at a predetermined frequency, determining gain and phase angle measurements at other of the electrodes in response to applying the sinusoidal voltage to the select number of electrodes, determining impedance values from the gain and phase angle measurements, computing an impedance spectrum for an area of the material from the determined impedance values, and comparing the computed impedance spectrum with a known impedance spectrum to identify spatial locations of defects in the material.

Glenn, David F.; Matthern, Gretchen E.; Propp, W. Alan; Glenn, Anne W.; Shaw, Peter G.

2006-08-08T23:59:59.000Z

Note: This page contains sample records for the topic "giner electrochemical systems" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

A mathematical model for a parallel plate electrochemical reactor, CSTR, and associated recirculation system  

E-Print Network [OSTI]

0. 5 0. 5 0. 5 0. 5 0. 438 0 0. 233 0. 1144 Component H CI C Q. C I CuCI ' T = 298. 15K Reaction 1 (j = 1) 0 0 0 -2 0 2 1 1 0 -1 0 1 Reaction 2 (j = 2) po 0 0 0 3 3 0 -1 0 1 0 0 0 Pcataoee = 0 V S = 0. 1 cm W =' 10 cm Component...CI+, feed 5flCCuCl, feed j53] 2RCSTR, CuC'le, feed = 2~CCuC I+, feed 54l RCS TR, Be, feed [55', v, here k is the reaction rate constant and is chosen arbitrary. Replacing the reaction term. Rc s T R, , f ?d. in Eq. j51i for each species involved with its...

Nguyen, Trung Van

2012-06-07T23:59:59.000Z

482

In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution  

SciTech Connect (OSTI)

A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

2010-03-31T23:59:59.000Z

483

IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 51, NO. 5, OCTOBER 2004 1103 An Electrochemical-Based Fuel-Cell Model Suitable  

E-Print Network [OSTI]

IEEE TRANSACTIONS ON INDUSTRIAL ELECTRONICS, VOL. 51, NO. 5, OCTOBER 2004 1103 An Electrochemical, automotive, and stationary applications. In particular, proton exchange membrane FCs (PEMFCs) are considered

Simões, Marcelo Godoy

484

Electrochemical NOx Sensor for Monitoring Diesel Emissions | Department of  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.Program - LibbyofThisStatementNOTElectricity Transmission SystemEnergy

485

Sensitive Electrochemical Detection of Enzymatically-generated Thiocholine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) SrEvaluating theDepartment of Energy SenatorDepartmentat

486

Sensitive electrochemical detection of horseradish peroxidase at disposable  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) SrEvaluating theDepartment ofscreen-printed carbon electrode.

487

Sequential Injection/Electrochemical Immunoassay for Quantifying the  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) SrEvaluatingconstruction is13, 2013| OSTI, US

488

Commissioning Measurements and Experience Obtained from the Installation of a Fissile Mass Flow monitor in the URAL Electrochemical Integrated Plant (UEIP) in Novouralsk  

SciTech Connect (OSTI)

The Blend Down Monitoring System (BDMS) equipment sent earlier to the Ural Electrochemical Integrated Plant (UEIP) at Novouralsk, Russia, was installed and implemented successfully on February 2, 1999. The BDMS installation supports the highly enriched uranium (HEU) Transparency Implementation Program for material subject to monitoring under the HEU purchase agreement between the United States of America (USA) and the Russian Federation (RF). The BDMS consists of the Oak Ridge National Laboratory (ORNL) Fissile (uranium-235) Mass Flow Monitor (FMFM) and the Los Alamos National Laboratory (LANL) Enrichment Monitor (EM). Two BDMS?s for monitoring the Main and Reserve HEU blending process lines were installed at UEIP. Independent operation of the FMFM Main and FMFM Reserve was successfully demonstrated for monitoring the fissile mass flow as well as the traceability of HEU to the product low enriched uranium. The FMFM systems failed when both systems were activated during the calibration phase due to a synchronization problem between the systems. This operational failure was caused by the presence of strong electromagnetic interference (EMI) in the blend point. The source-modulator shutter motion of the two FMFM systems was not being properly synchronized because of EMI producing a spurious signal on the synchronization cable connecting the two FMFM cabinets. The signature of this failure was successfully reproduced at ORNL after the visit. This unexpected problem was eliminated by a hardware modification and software improvements during a recent visit (June 9-11, 1999) to UEIP, and both systems are now operating as expected.

March-Leuba, J.; Mastal, E.; Powell, D.; Sumner, J.; Uckan, T.; Vines, V.

1999-07-25T23:59:59.000Z

489

Electrochemical Energy Storage Technologies and the Automotive Industry  

ScienceCinema (OSTI)

The first portion of the lecture will relate global energy challenges to trends in personal transportation. Following this introduction, a short overview of technology associated with lithium ion batteries for traction applications will be provided. Last, I shall present new research results that enable adaptive characterization of lithium ion cells. Experimental and modeling results help to clarify the underlying electrochemistry and system performance. Specifically, through chemical modification of the electrodes, it is possible to place markers within the electrodes that signal the state of charge of a battery through abrupt voltage changes during cell operation, thereby allowing full utilization of the battery in applications. In closing, I shall highlight some promising materials research efforts that are expected to lead to substantially improved battery technology

Mark Verbrugge

2010-01-08T23:59:59.000Z

490

Determination of Electrochemical Performance and Thermo-Mechanical-Chemical Stability of SOFCs from Defect Modeling  

SciTech Connect (OSTI)

This research was focused on two distinct but related issues. The first issue concerned using defect modeling to understand the relationship between point defect concentration and the electrochemical, thermo-chemical and mechano-chemical properties of typical solid oxide fuel cell (SOFC) materials. The second concerned developing relationships between the microstructural features of SOFC materials and their electrochemical performance. To understand the role point defects play in ceramics, a coherent analytical framework was used to develop expressions for the dependence of thermal expansion and elastic modulus on point defect concentration in ceramics. These models, collectively termed the continuum-level electrochemical model (CLEM), were validated through fits to experimental data from electrical conductivity, I-V characteristics, elastic modulus and thermo-chemical expansion experiments for (nominally pure) ceria, gadolinia-doped ceria (GDC) and yttria-stabilized zirconia (YSZ) with consistently good fits. The same values for the material constants were used in all of the fits, further validating our approach. As predicted by the continuum-level electrochemical model, the results reveal that the concentration of defects has a significant effect on the physical properties of ceramic materials and related devices. Specifically, for pure ceria and GDC, the elastic modulus decreased while the chemical expansion increased considerably in low partial pressures of oxygen. Conversely, the physical properties of YSZ remained insensitive to changes in oxygen partial pressure within the studied range. Again, the findings concurred exactly with the predictions of our analytical model. Indeed, further analysis of the results suggests that an increase in the point defect content weakens the attractive forces between atoms in fluorite-structured oxides. The reduction treatment effects on the flexural strength and the fracture toughness of pure ceria were also evaluated at room temperature. The results reveal that the flexural strength decreases significantly after heat treatment in very low oxygen partial pressure environments; however, in contrast, fracture toughness is increased by 30-40% when the oxygen partial pressure was decreased to 10{sup -20} to 10{sup -22} atm range. Fractographic studies show that microcracks developed at 800 oC upon hydrogen reduction are responsible for the decreased strength. To understand the role of microstructure on electrochemical performance, electrical impedance spectra from symmetric LSM/YSZ/LSM cells was de-convoluted to obtain the key electrochemical components of electrode performance, namely charge transfer resistance, surface diffusion of reactive species and bulk gas diffusion through the electrode pores. These properties were then related to microstructural features, such as triple-phase boundary length and tortuosity. From these experiments we found that the impedance due to oxygen adsorption obeys a power law with pore surface area, while the impedance due to charge transfer is found to obey a power-law with respect to triple phase boundary length. A model based on kinetic theory explaining the power-law relationships observed was then developed. Finally, during our EIS work on the symmetric LSM/YSZ/LSM cells a technique was developed to improve the quality of high-frequency impedance data and their subsequent de-convolution.

Eric Wachsman; Keith L. Duncan

2006-09-30T23:59:59.000Z

491

Electrochemical detection of leukemia oncogenes using enzyme-loaded carbon nanotube labels  

SciTech Connect (OSTI)

Here we describe an ultrasensitive electrochemical nucleic acids assay amplified by carbon nanotubes (CNTs)-based labels for the detection of human acute lymphocytic leukemia (ALL) related p185 BCR-ABL fusion transcript. The carboxylated CNTs were functionalized with horseradish peroxidase (HRP) molecules and target-specific detection probes (DP) via diimide-activated amidation, and used to label and amplify target hybridization signal. The activity of captured HRP was monitored by square-wave voltammetry measuring the electroactive enzymatic product in the presence of 2-aminophenol and hydrogen peroxide substrate solution. The effect of DP and HRP loading of the CNT-based labels on its signal-to-noise ratio of electrochemical detection was studied systematically for the first time. Under optimized conditions, the signal-amplified assay achieved a detection limit of 83 fM targets oligonuecleotides and a 4-order wide dynamic range of target concentration. The resulting assay allowed a robust discrimination between the perfect match and a three-base mismatch sequence. When subjected to full-length (491 bp) DNA oncogene, the approach demonstrated a detection limit of approximately 33 pg of the target gene. The high sensitivity and specificity of assay enabled PCR-free detection of target transcripts in as little as 65 ng of mRNA extracted from positive ALL cell lines SUP-B15, in comparison to those obtained from negative cell lines HL-60. The approach holds promise for simple, low cost and ultrasensitive electrochemical nucleic acids detection in portable devices, point-of-care and early disease diagnostic applications.

Lee, Ai Cheng; Du, Dan; Chen, Baowei; Heng, Chew-Kiat; Lim, Tit-Meng; Lin, Yuehe

2014-09-07T23:59:59.000Z

492

Novel concepts in electrochemical solar cells. Quarterly technical progress report, December 15, 1980-March 15, 1981  

SciTech Connect (OSTI)

During the past quarter, the following areas were emphasized: (a) characterization of redox couples with very positive potentials in room-temperature AlCl/sub 3/-BPC electrolytes and comparison of the electrochemical behavior of decamethyl ferrocene in these electrolytes with the previously-studied ferrocene/ferricenium ion couple, (b) photoelectrochemical characterization of CdSe thin-film anodes in aqueous polysulfide electrolytes and (c) refinement of the admittance measurement technique for extraction of Mott-Schottky parameters. The results of research in these areas are detailed in turn below.

Not Available

1981-01-01T23:59:59.000Z

493

Comparison of the electrochemical properties of several commercial graphites with a templated disordered carbon  

SciTech Connect (OSTI)

A templated carbon was prepared by the pyrolysis of pyrene impregnated into pillared clay (PILC). The electrochemical performance of this was evaluated with the goal of using this material as an anode in Li-ion cells. The reversible capacity was measured as a function of C rate and the cycling characteristics were determined for various intercalation protocols. The performance of this material was compared to that of several commercial graphites tested under the same conditions. The PILC carbon shows great promise as a Li-ion anode if the fade and first-cycle losses can be controlled.

Guidotti, R. A.; Reinhardt, F. W.; Sandi, G.

2000-04-11T23:59:59.000Z

494

Comparison of the electrochemical properties of several commercial graphites with a templated disordered carbon  

SciTech Connect (OSTI)

A templated carbon was prepared by the pyrolysis of pyrene impregnated into pillared clay (PILC). The electrochemical performance of this was evaluated with the goal of using this material as an anode in Li-ion cells. The reversible capacity was measured as a function of C rate and the cycling characteristics were determined for various intercalation protocols. The performance of this material was compared to that of several commercial graphites tested under the same conditions. The PILC carbon shows great promise as a Li-ion anode if the fade and first-cycle losses can be controlled.