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1

Cation Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV Economics By BuildingCategory: Wind,000Cation

2

Cation geothermometry in oil field waters  

SciTech Connect (OSTI)

The assumptions used in the development of cation ratio geothermometers are: (1) the ratios of the cations are controlled by cation exchange between solid silicate phases, (2) aluminum is conserved in the solid phases, and (3) neither hydrogen ions nor CO[sub 2] enter into the net reactions. These assumptions do not apply to oilfield waters where organic species are present and commonly abundant. Nine different published cation geothermometers of Na/K, Na-K-Ca, Na-K-Ca-Mg, and Mg/Li were applied to 309 water samples from both oilfield and geothermal wells. None of the cation geothermometers predicted consistent or accurate temperatures for the oilfield waters. Plots of measured v. predicted temperature for oilfield water samples gave correlation coefficients of less than 0.35. In contrast, those same plots for geothermal water samples within the same temperature range gave correlation coefficients between 0.45 and 0.95. This analysis suggests that the presence of organic species exerts a strong control on the cation ratios. Organic species form complexes of varying stability with the cations. This, in turn, changes the relative concentrations of the cations in solution over that which is expected when cation exchange between silicate phases controls the ratios. Organic complexes also strongly affect pH and P[sub CO[sub 2

Smith, L.K.; Dunn, T.L.; Surdam, R.C. (Univ. of Wyoming, Laramie, WY (United States))

1992-01-01T23:59:59.000Z

3

Improvements in geothermometry. Final technical report  

SciTech Connect (OSTI)

The following are covered: the basis of the Na-K-Ca geothermometer, geothermometry via model calculations, non ideality and complexing, and experimental calibration.

Potter, J.; Dibble, W.; Parks, G.; Nur, A.

1982-07-01T23:59:59.000Z

4

Multicomponent Equilibrium Models for Testing Geothermometry Approaches  

SciTech Connect (OSTI)

Geothermometry is an important tool for estimating deep reservoir temperature from the geochemical composition of shallower and cooler waters. The underlying assumption of geothermometry is that the waters collected from shallow wells and seeps maintain a chemical signature that reflects equilibrium in the deeper reservoir. Many of the geothermometers used in practice are based on correlation between water temperatures and composition or using thermodynamic calculations based a subset (typically silica, cations or cation ratios) of the dissolved constituents. An alternative approach is to use complete water compositions and equilibrium geochemical modeling to calculate the degree of disequilibrium (saturation index) for large number of potential reservoir minerals as a function of temperature. We have constructed several “forward” geochemical models using The Geochemist’s Workbench to simulate the change in chemical composition of reservoir fluids as they migrate toward the surface. These models explicitly account for the formation (mass and composition) of a steam phase and equilibrium partitioning of volatile components (e.g., CO2, H2S, and H2) into the steam as a result of pressure decreases associated with upward fluid migration from depth. We use the synthetic data generated from these simulations to determine the advantages and limitations of various geothermometry and optimization approaches for estimating the likely conditions (e.g., temperature, pCO2) to which the water was exposed in the deep subsurface. We demonstrate the magnitude of errors that can result from boiling, loss of volatiles, and analytical error from sampling and instrumental analysis. The estimated reservoir temperatures for these scenarios are also compared to conventional geothermometers. These results can help improve estimation of geothermal resource temperature during exploration and early development.

Cooper, D. Craig; Carl D. Palmer; Robert W. Smith; Travis L. McLing

2013-02-01T23:59:59.000Z

5

A new illite geothermometer  

SciTech Connect (OSTI)

Sericite, either as illite or illite/smectite, is ubiquitous in geothermal systems. Theoretical Ca- and Na-smectite contents of non-expanding geothermal sericites have been calculated from published electron microprobe analyses. Geothermal sericites can be modeled as solid solutions of muscovite and smectite. For those sericites that fit the model, the amount of smectite in solid solution is related to temperature by the expression TºC = 1000/(0.45LogX{sub smectite} + 2.38) – 273. The temperature dependence of illite interlayer chemistry suggests a related temperature dependence of the K, Na and Ca content of geothermal fluids. The original data used by Fournier and Truesdell (1973) to derive the empirical Na-K-Ca geothermometer for geothermal fluids can be modeled equally well by an equation incorporating the equilibrium constant for the reaction of smectite to illite: T ºC = 1.145*10{sup 3}/([0.35LogNa + 0.175LogCa – 0.75LogK] + 1.51) – 273, where the concentration units are molalities. This supports the hypothesis that illite and illite/smectite are important controls on the concentrations of Na, K and Ca in geothermal fluids.

Ballantyne, Judith M.; Moore, Joseph N.

1988-01-01T23:59:59.000Z

6

Geothermometry | Open Energy Information  

Open Energy Info (EERE)

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7

Multicomponent Geothermometers | Open Energy Information  

Open Energy Info (EERE)

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8

Improvements in geothermometry. Final technical report. Rev  

SciTech Connect (OSTI)

Alkali and alkaline earth geothermometers are useful for estimating geothermal reservoir temperatures, though a general theoretical basis has yet to be established and experimental calibration needs improvement. Equilibrium cation exchange between feldspars provided the original basis for the Na-K and Na-K-Ca geothermometers (Fournier and Truesdell, 1973), but theoretical, field and experimental evidence prove that neither equilibrium nor feldspars are necessary. Here, evidence is summarized in support of these observations, concluding that these geothermometers can be expected to have a surprisingly wide range of applicability, but that the reasons behind such broad applicability are not yet understood. Early experimental work proved that water-rock interactions are slow at low temperatures, so experimental calibration at temperatures below 150/sup 0/ is impractical. Theoretical methods and field data were used instead for all work at low temperatures. Experimental methods were emphasized for temperatures above 150/sup 0/C, and the simplest possible solid and solution compositions were used to permit investigation of one process or question at a time. Unexpected results in experimental work prevented complete integration of the various portions of the investigation.

Potter, J.; Dibble, W.; Parks, G.; Nur, A.

1982-08-01T23:59:59.000Z

9

Geothermometry At Lassen Volcanic National Park Area (Janik ...  

Open Energy Info (EERE)

sample taken had a pH of 8.35 and contained 2100 ppm Cl and 0.55 ppm NH3. Ratios of Na+K+ and Na+Cl remained nearly constant throughout the flow test. Cation geothermometers...

10

Evaluation Of Chemical Geothermometers For Calculating Reservoir...  

Open Energy Info (EERE)

Geothermometers For Calculating Reservoir Temperatures At Nevada Geothermal Power Plants Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper:...

11

An experimental investigation into the effects of fluid composition on certain geothermometry methods  

E-Print Network [OSTI]

at the lower temperatures, and 5) thermal waters do not mix with shallower, cooler ground water. Silica geothermometer The dissolved silica content of geothermal water is used in geothermometry because silica is present in most geologic settings... that the time required to attain equilibrium was 100 hours at 200 C and from four to sixteen hours at 0 360 C. Work at lower temperatures (25 C, 60 -100 C) was done by van Lier, de Bruyn, and Overbeek (1960) using finely ground quartz particles...

Pope, Leslie Anne

1985-01-01T23:59:59.000Z

12

Integrated Chemical Geothermometry System for Geothermal Exploration  

Broader source: Energy.gov (indexed) [DOE]

interpretations) * Reduce exploration and development costs Innovation * Numerical optimization of multicomponent chemical geothermometry at multiple locations * Integration with...

13

Geothermometry At Central Nevada Seismic Zone Region (Shevenell...  

Open Energy Info (EERE)

ENERGYGeothermal Home Exploration Activity: Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De Rocher, 2005) Exploration Activity Details Location...

14

Cation Geothermometers At Lightning Dock Geothermal Area (Witcher, 2006) |  

Open Energy Info (EERE)

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15

Geothermometry At Long Valley Caldera Geothermal Area (Farrar...  

Open Energy Info (EERE)

Home Exploration Activity: Geothermometry At Long Valley Caldera Geothermal Area (Farrar, Et Al., 2003) Exploration Activity Details Location Long Valley Caldera Geothermal...

16

Geothermometry At Nevada Test And Training Range Area (Sabin...  

Open Energy Info (EERE)

Nevada Test And Training Range Area (Sabin, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nevada Test And...

17

Category:Liquid Geothermometry | Open Energy Information  

Open Energy Info (EERE)

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18

Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...  

Open Energy Info (EERE)

Basis Temperature estimation of valley-fill hydrothermal reservoir Notes Si, Na-K, & Na-K-Ca geothermometry estimates yielded a reservoir temperature range of 97 to 188...

19

Microbial impacts on geothermometry temperature predictions  

SciTech Connect (OSTI)

Conventional geothermometry approaches assume that the composition of a collected water sample originating in a deep geothermal reservoir still reflects chemical equilibration of the water with the deep reservoir rocks. However, for geothermal prospecting samples whose temperatures have dropped to <120°C, temperature predictions may be skewed by the activity of microorganisms; microbial metabolism can drastically and rapidly change the water’s chemistry. We hypothesize that knowledge of microbial impacts on exploration sample geochemistry can be used to constrain input into geothermometry models and thereby improve the reliability of reservoir temperature predictions. To evaluate this hypothesis we have chosen to focus on sulfur cycling, because of the significant changes in redox state and pH associated with sulfur chemistry. Redox and pH are critical factors in defining the mineral-fluid equilibria that form the basis of solute geothermometry approaches. Initially we are developing assays to detect the process of sulfate reduction, using knowledge of genes specific to sulfate reducing microorganisms. The assays rely on a common molecular biological technique known as quantitative polymerase chain reaction (qPCR), which allows estimation of the number of target organisms in a particular sample by enumerating genes specific to the organisms rather than actually retrieving and characterizing the organisms themselves. For quantitation of sulfate reducing genes using qPCR, we constructed a plasmid (a piece of DNA) containing portions of two genes (known as dsrA and dsrB) that are directly involved with sulfate reduction and unique to sulfate reducing microorganisms. Using the plasmid as well as DNA from other microorganisms known to be sulfate reducers or non-sulfate reducers, we developed qPCR protocols and showed the assay’s specificity to sulfate reducers and that a qPCR standard curve using the plasmid was linear over >5 orders of magnitude. As a first test with actual field samples, the assay was applied to DNA extracted from water collected at springs located in and around the town of Soda Springs, Idaho. Soda Springs is located in the fold and thrust belt on the eastern boundary of the track of the Yellowstone Hotspot, where a deep carbon dioxide source believed to originate from Mississippian limestone contacts acidic hydrothermal fluids at depth. Both sulfate and sulfide have been measured in samples collected previously at Soda Springs. Preliminary results indicate that sulfate reducing genes were present in each of the samples tested. Our work supports evaluation of the potential for microbial processes to have altered water chemistry in geothermal exploration samples.

Yoshiko Fujita; David W. Reed; Kaitlyn R. Nowak; Vicki S. Thompson; Travis L. McLing; Robert W. Smith

2013-02-01T23:59:59.000Z

20

Geothermometry At Neal Hot Springs Geothermal Area (U.S. Geothermal...  

Open Energy Info (EERE)

DOE-funding Unknown Exploration Basis Geothermometry analysis was done on geothermal fluids from the first production well to estimate the reservoirs temperature at deeper...

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Cation Uptake and Allocation by Red Pine Seedlings under Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient Stress in a Column Growth Experiment. Cation Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient...

22

Silica Geothermometers | Open Energy Information  

Open Energy Info (EERE)

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23

Comproportionation of Cationic and Anionic Tungsten Complexes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comproportionation of Cationic and Anionic Tungsten Complexes Having an N-Heterocyclic Carbene Ligand to Give the Isolable 17 Comproportionation of Cationic and Anionic Tungsten...

24

Cationic electrodepositable coating composition comprising lignin  

SciTech Connect (OSTI)

A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

Fenn, David; Bowman, Mark P; Zawacky, Steven R; Van Buskirk, Ellor J; Kamarchik, Peter

2013-07-30T23:59:59.000Z

25

Geology, hydrothermal petrology, stable isotope geochemistry, and fluid inclusion geothermometry of LASL geothermal test well C/T-1 (Mesa 31-1), East Mesa, Imperial Valley, California, USA  

SciTech Connect (OSTI)

Borehole Mesa 31-1 (LASL C/T-1) is an 1899-m (6231-ft) deep well located in the northwestern part of the East Mesa Geothermal Field. Mesa 31-1 is the first Calibration/Test Well (C/T-1) in the Los Alamos Scientific Laboratory (LASL), Geothermal Log Interpretation Program. The purpose of this study is to provide a compilation of drillhole data, drill cuttings, well lithology, and formation petrology that will serve to support the use of well LASL C/T-1 as a calibration/test well for geothermal logging. In addition, reviews of fluid chemistry, stable isotope studies, isotopic and fluid inclusion geothermometry, and the temperature log data are presented. This study provides the basic data on the geology and hydrothermal alteration of the rocks in LASL C/T-1 as background for the interpretation of wireline logs.

Miller, K.R.; Elders, W.A.

1980-08-01T23:59:59.000Z

26

Polyelectrolyte Condensation Induced by Linear Cations  

E-Print Network [OSTI]

We examine the role of the condensing agent in the formation of polyelectrolyte bundles, via grand-canonical Monte Carlo simulations. Following recent experiments we use linear, rigid divalent cations of various lengths to induce condensation. Our results clarify and explain the experimental results for short cations. For longer cations we observe novel condensation behavior owing to alignment of the cations. We also study the role of the polyelectrolyte surface charge density, and find a nonmonotonic variation in bundle stability. This nonmonotonicity captures two trends that have been observed in separate experiments.

Camilo Guáqueta; Erik Luijten

2007-09-21T23:59:59.000Z

27

Liquid Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(Monaster And Coolbaugh, 2007)is 109.Lindley,Lipscomb County,

28

Gas Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6TheoreticalFuelCell Energy IncFORTechnologyGammaGary2008)

29

Isotope Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place: EdenOverview OfIowa/Incentives < IowaOpen

30

Automatically generating information from a Z speci cation to support the Classi cation Tree  

E-Print Network [OSTI]

Automatically generating information from a Z speci#12;cation to support the Classi#12;cation Tree, Brunel University, Uxbridge, Middlesex, UB8 3PH, UK 2 DaimlerChrysler AG, Research Information. The Classi#12;cation Tree Method provides a exible basis for systematic testing. Traditionally

Singer, Jeremy

31

Method for encapsulating and isolating hazardous cations, medium for encapsulating and isolating hazardous cations  

DOE Patents [OSTI]

A method for encapsulating hazardous cations is provided comprising supplying a pretreated substrate containing the cations; contacting the substrate with an organo-silane compound to form a coating on the substrate; and allowing the coating to cure. A medium for containing hazardous cations is also provided, comprising a substrate having ion-exchange capacity and a silane-containing coating on the substrate.

Wasserman, Stephen R. (Darien, IL); Anderson, Kenneth B. (Lisle, IL); Song, Kang (Woodridge, IL); Yuchs, Steven E. (Naperville, IL); Marshall, Christopher L. (Naperville, IL)

1998-01-01T23:59:59.000Z

32

Hybrid Automata: An Algorithmic Approach to the Speci cation and Veri cation of  

E-Print Network [OSTI]

Hybrid Automata: An Algorithmic Approach to the Speci cation and Veri cation of Hybrid Systems1 of hybrid automata as a model and speci cation language for hybrid systems. Hybrid automatacan be viewed erential equations. We show that many of the examples considered in the workshop can be de ned by hybrid

Henzinger, Thomas A.

33

Category:Silica Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to:ListsGeothermalpower.jpg

34

Evaluation Of Chemical Geothermometers For Calculating Reservoir  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformationexplains a4 ClimateEtrionPower Pvt LtdA

35

Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1  

E-Print Network [OSTI]

Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1 , David Nowak2 assistant, Coq, for the speci cation and the veri cation of co-inductive properties of the well-known steam cation tools. Keywords: synchronous programming, theorem proving, the steam- boiler problem. 1

Boyer, Edmond

36

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid Based Redox Flow Battery Electrolytes. Abstract: The Vanadium (V) cation structures in mixed acid based...

37

Are the Radical Centers in Peptide Radical Cations Mobile? The...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Radical Centers in Peptide Radical Cations Mobile? The Generation, Tautomerism, and Dissociation of Isomeric ? Are the Radical Centers in Peptide Radical Cations Mobile?...

38

Cationic Ruthenium Catalysts for Olefin Hydrovinylation  

E-Print Network [OSTI]

CATIONIC RUTHENIUM CATALYSTS FOR OLEFIN HYDROVINYLATION A Thesis by RICHARD P. SANCHEZ, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 2009 Major Subject: Chemistry CATIONIC RUTHENIUM CATALYSTS FOR OLEFIN HYDROVINYLATION A Thesis by RICHARD P. SANCHEZ, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Sanchez, Richard P., Jr

2010-01-14T23:59:59.000Z

39

Method for encapsulating and isolating hazardous cations, medium for encapsulating and isolating hazardous cations  

DOE Patents [OSTI]

A method for encapsulating hazardous cations is provided comprising supplying a pretreated substrate containing the cations; contacting the substrate with an organo-silane compound to form a coating on the substrate; and allowing the coating to cure. A medium for containing hazardous cations is also provided, comprising a substrate having ion-exchange capacity and a silane-containing coating on the substrate. 3 figs.

Wasserman, S.R.; Anderson, K.B.; Song, K.; Yuchs, S.E.; Marshall, C.L.

1998-04-28T23:59:59.000Z

40

Cationic Hyperbranched Poly(amino ester): A Novel Class of DNA Condensing Molecule with Cationic  

E-Print Network [OSTI]

molecules.3 It is generally accepted that the high transfection efficiency of PEI or PAMAM comparedCationic Hyperbranched Poly(amino ester): A Novel Class of DNA Condensing Molecule with Cationic to utilize these highly branched molecules in a variety of applications involving combinatorial chemistry

Park, Jong-Sang

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objective of this project is to make use of products obtained from renewable plant sources as monomers for the direct production of polymers which can be used for a wide range of plastic applications. In this report is described progress in the synthesis and polymerization of cationically polymerizable monomers and oligomers derived from botanical oils, terpenes, natural rubber, and lignin. Nine different botanical oils were obtained from various sources, characterized and then epoxidized. Their photopolymerization was carried out using cationic photoinitiators and the mechanical properties of the resulting polymers characterized. Preliminary biodegradation studies are being conducted on the photopolymerized films from several of these oils. Limonene was cationically polymerized to give dimers and the dimers epoxidized to yield highly reactive monomers suitable for coatings, inks and adhesives. The direct phase transfer epoxidation of squalene and natural rubber was carried out. The modified rubbers undergo facile photocrosslinking in the presence of onium salts to give crosslinked elastomers. 12 refs., 3 figs., 10 tabs.

Crivello, J.V.

1991-10-01T23:59:59.000Z

42

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year's research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

43

Process and apparatus for the production of Bi-213 cations  

DOE Patents [OSTI]

A process for producing substantially impurity-free Bi-213 cations is disclosed. An aqueous acid feed solution containing Ac-225 cations is contacted with an ion exchange medium to bind the Ac-225 cations and form an Ac-225-laden ion exchange medium. The bound Ac-225 incubates on the ion exchange medium to form Bi-213 cations by radioactive decay. The Bi-213 cations are then recovered from the Ac-225-laden ion exchange medium to form a substantially impurity-free aqueous Bi-213 cation acid solution. An apparatus for carrying out this process is also disclosed. 7 figs.

Horwitz, E.P.; Hines, J.J.; Chiarizia, R.; Dietz, M.

1998-12-29T23:59:59.000Z

44

Distributed Controller Synthesis for Local Speci cations  

E-Print Network [OSTI]

| and a speci#12;cation, say, a temporal logic formula. The plant is viewed as an existing program which speci Institute of Technology, Atlanta, USA (On leave from Chennai Mathematical Institute, Chennai, India) thiagu as a temporal logic formula, whether there exists a program for the system such that no matter how

Parthasarathy, Madhusudan

45

E-Print Network 3.0 - alkaline earth cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the cation (alkaline, rare earth... to the cation size. Knowing that the size of rare earth elements and alkaline cations decreases in the following... of results on tungstate...

46

Functional and Structural Characterization of Cation/H+ Antiporters  

E-Print Network [OSTI]

are important elements in mediating the intracellular sequestration of these cations. CAXs (for CAtion eXchanger) are members of a multigene family and appear to predominately reside on vacuoles. Defining CAX regulation and substrate specificity have been aided...

Manohar, Murli

2012-07-16T23:59:59.000Z

47

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

48

Specific Cation Effects in Biological Systems: Thermodynamic and Spectroscopic Insights  

E-Print Network [OSTI]

. More polarizable cations, however, can solvate the hydrophobic moieties and somewhat counter the salting-out effect of the chloride anion. More charged and hydrated ions like lithium and divalent cations showed a weak interaction to the amide moiety...

Kherb, Jaibir

2012-02-14T23:59:59.000Z

49

The effect of various cropping systems upon organic matter, total nitrogen, cation exchange capacity, exchangeable cations, conductivity and reaction  

E-Print Network [OSTI]

&IBRARY A 4 N COLLEGE OF TEXAS THE EFFECT OF VARIOUS CROPPING SYSTEMS UPON ORGANIC MATTER, TOTAL NITROGEN, CATION EXCHANGE CAPACITY, EXCHANGEABLE CATIONS, CONDUCTIVITY AND REACTION. A Thesis By MOHAMMAD ABDUL MANNAN Submitted...

Mannan, Mohammad Abdul

1958-01-01T23:59:59.000Z

50

Alkaline earth cation extraction from acid solution  

DOE Patents [OSTI]

An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

2003-01-01T23:59:59.000Z

51

Low cation coordination in oxide melts  

SciTech Connect (OSTI)

The complete set of Faber-Ziman partial pair distribution functions for a rare earth oxide liquid were measured for the first time by combining aerodynamic levitation, neutron diffraction, high energy x-ray diffraction and isomorphic substitution using Y2 O3 and Ho2 O3 melts. The average Y- O coordination is measured to be 5.5(2), which is significantly less than the octahedral coordination of crystalline Y2 O3 (or Ho2 O3 ). Investigation of high temperature La2 O3 , ZrO2 , SiO2 , and Al2 O3 melts by x-ray diffraction and molecular dynamics simulations also show lower-than-crystal cation- oxygen coordination. These measurements suggest a general trend towards lower M-O coordination compared to their crystalline counterparts. It is found that this coordination number drop is larger for lower field strength, larger radius cations and is negligible for high field strength (network forming) cations. These findings have broad implications for predicting the local structure and related physical properties of metal-oxide melts and oxide glasses.

Skinner, Lawrie [State University of New York, Stony Brook] [State University of New York, Stony Brook; Benmore, Chris J [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Du, Jincheng [University of North Texas] [University of North Texas; Weber, Richard [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Neuefeind, Joerg C [ORNL] [ORNL; Tumber, Sonia [Materials Development, Inc., Evanston, IL] [Materials Development, Inc., Evanston, IL; Parise, John B [Stony Brook University (SUNY)] [Stony Brook University (SUNY)

2014-01-01T23:59:59.000Z

52

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

O'Neill, Malcolm A. (Winterville, GA); Pellerin, Patrice J. M. (Montpellier, FR); Warrenfeltz, Dennis (Athens, GA); Vidal, Stephane (Combaillaux, FR); Darvill, Alan G. (Athens, GA); Albersheim, Peter (Athens, GA)

1999-01-01T23:59:59.000Z

53

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

1999-03-02T23:59:59.000Z

54

active cation transport: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of hexadecyltrimethylammonium (HDTMA into surface water is a major cause of lake Eutrophication 2. Removal of surfactants from waste water Li, Zhaohui 7 Cationic Amino Acid...

55

Diffusion and selective transport of alkali cations on cation-exchange membrane  

SciTech Connect (OSTI)

The diffusion coefficients and selective transport for alkali metal cations through a charged polysulfonated ICE-450 ion-exchange membrane were measured as a function of pH at 25{degrees}C. The permeability and diffusion coefficients were found to increase in the sequence Cs{sup +} {ge} K{sup +} {ge} Na{sup +} {ge} Li{sup +}. The relationship between the permeability and the diffusion coefficients, and the hydrated radii of cations in the membrane were shown. This sequence was also explained by considering the hydration of ions in the membrane. The selectivity transport of K-Na and K-Li binary systems at various pH gradients through the membrane were also investigated under various conditions. In the selective transport of metal ions, the selectivity depended on both the hydrated ionic size and the interaction between the fixed groups in the membrane and the metal ions.

Ersoez, M. [Selcuk Univ., Konya (Turkey)

1995-11-01T23:59:59.000Z

56

CSE647: Testing and Veri cation (Fall 2000) Scott Stoller  

E-Print Network [OSTI]

CSE647: Testing and Veri#12;cation (Fall 2000) Scott Stoller Exam For every problem, you must whether it is possible, based only on the given information about S, to conclude that the speci#12;ed set is persistent in the speci#12;ed state. Your answer must be yes or no, followed by a justi#12;cation. Use

Stoller, Scott

57

Charge Density of Divalent Metal Cations Determines RNA Stability  

E-Print Network [OSTI]

determined by a combination of counterion charge and the packing efficiency of condensed cations that depends RNAs that have regions of high negative potential interact even more strongly with counterions than of the phosphate charge arises from nonspecific condensation of counterions.4,10 The ionic radius of a metal cation

Thirumalai, Devarajan

58

Functional Speci cation of Real-Time and Hybrid Systems ?  

E-Print Network [OSTI]

of embedded real-time systems in a physical environment. Recently, a number of description and spec- i cationSys" and by BMW (Bay- erische Motoren Werke AG). #12;slight modi cations must be carried through, so, or sent to, the environment. Therefore, every channel re ects an input or output communication history

59

Integrated Chemical Geothermometry System for Geothermal Exploration...  

Broader source: Energy.gov (indexed) [DOE]

geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids. tracersspycherintegratedchemical.pdf More Documents & Publications Integrated...

60

Integrated Chemical Geothermometry System for Geothermal Exploration  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Geothermometry (Klein, 2007) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJump

62

Geothermal: Sponsored by OSTI -- Improved Geothermometry Through  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite--FORRemarks IGPPS Days Program

63

Category:Gas Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascade SierraStatusGeothermalpower.jpgGas Flux

64

Category:Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,Areas Jump to:

65

Category:Isotope Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,Areas

66

Classi cation of Carbide Distributions using Scale-Space Methods Classi cation of Carbide Distributions using Scale  

E-Print Network [OSTI]

Classi cation of Carbide Distributions using Scale-Space Methods #12;Classi cation of Carbide-structure of the steel, which in turn in uences the mechanical properties. Speci - cally, the distribution of carbide is essential, since cracks propagate within the carbide agglomerations. In current quality control

Lindeberg, Tony

67

Effects of Cesium Cations in Lithium Deposition via Self-Healing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cesium Cations in Lithium Deposition via Self-Healing Electrostatic Shield Mechanism. Effects of Cesium Cations in Lithium Deposition via Self-Healing Electrostatic Shield...

68

Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrolytes. Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium Redox Flow Battery Electrolytes. Abstract: The Vanadium (III) cation structure in mixed acid based...

69

Cation Transport in Polymer Electrolytes: A Microscopic Approach  

E-Print Network [OSTI]

A microscopic theory for cation diffusion in polymer electrolytes is presented. Based on a thorough analysis of molecular dynamics simulations on PEO with LiBF$_4$ the mechanisms of cation dynamics are characterised. Cation jumps between polymer chains can be identified as renewal processes. This allows us to obtain an explicit expression for the lithium ion diffusion constant D_{Li} by invoking polymer specific properties such as the Rouse dynamics. This extends previous phenomenological and numerical approaches. In particular, the chain length dependence of D_{Li} can be predicted and compared with experimental data. This dependence can be fully understood without referring to entanglement effects.

A. Maitra; A. Heuer

2007-05-11T23:59:59.000Z

70

Method for the chromatographic separation of cations from aqueous samples  

DOE Patents [OSTI]

An extraction chromatographic material is described for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support. 7 figs.

Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.

1997-07-29T23:59:59.000Z

71

Method for the chromatographic separation of cations from aqueous samples  

DOE Patents [OSTI]

An extraction chromatographic material is described for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methane-diphosphonic acid on an inert particulate support. 7 figs.

Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.

1998-12-22T23:59:59.000Z

72

Chemical Geothermometers And Mixing Models For Geothermal Systems | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV2009Information17.3180919°,Faults In Utah

73

In situ remediation process using divalent metal cations  

DOE Patents [OSTI]

An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

2004-12-14T23:59:59.000Z

74

Comparison of Cation Adsorption by Isostructural Rutile and Cassiterite  

SciTech Connect (OSTI)

Macroscopic net proton charging curves for powdered rutile and cassiterite specimens with the (110) Crystal face predominant, as a function of pH in RbCl and NaCl solutions, trace SrCl2 in NaCl, and trace ZnCl2 in NaCl and Na Triflate solutions, are compared to corresponding molecular-level information obtained from static DFT optimizations and classical MD simulations, as well as synchrotron X-ray methods. The similarities and differences in the macroscopic charging behavior of rutile and cassiterite largely reflect the cation binding modes observed at the molecular level. Cation adsorption is primarily inner-sphere on both isostructural (110) surfaces, despite predictions that outer-sphere binding should predominate on low bulk dielectric constant oxides such as cassiterite ( bulk 11). Inner-sphere adsorption is also significant for Rb and Na on neutral surfaces, whereas Cl- binding is predominately outer-sphere. As negative surface charge increases, relatively more Rb , Na , and especially Sr2 are bound in highly desolvated tetradentate fashion on the rutile (110) surface, largely accounting for enhanced negative charge development relative to cassiterite. Charging curves in the presence of Zn2 are very steep but similar for both oxides, reflective of Zn2 hydrolysis (and accompanying proton release) during the adsorption process, and the similar binding modes for ZnOH on both surfaces. These results suggest that differences in cation adsorption between high and low bulk dielectric constant oxides are more subtly related to the relative degree of cation desolvation accompanying inner-sphere binding (i.e., more tetradentate binding on rutile), rather than distinct inner- and outer-sphere adsorption modes. Cation desolvation may be favored at the rutile (110) surface in part because inner-sphere water molecules are bound further from and less tightly than on the cassiterite (110) surface. Hence, their removal upon inner-sphere cation binding is relatively more favorable.

Machesky, Michael L. [Illinois State Water Survey, Champaign, IL; Wesolowski, David J [ORNL; Rosenqvist, Jorgen K [ORNL; Predota, M. [University of South Bohemia, Czech Republic; Vlcek, Lukas [ORNL; Ridley, Moira K [ORNL; Kohli, V [Oak Ridge National Laboratory (ORNL); Zhang, Zhan [Argonne National Laboratory (ANL); Fenter, Paul [Argonne National Laboratory (ANL); Cummings, Peter T [ORNL; Lvov, Serguei N. [Pennsylvania State University; Fedkin, Mark V [ORNL; Rodriguez-Santiago, V [Oak Ridge National Laboratory (ORNL); Kubicki, James D. [Pennsylvania State University; Bandura, Andrei V. [St. Petersburg State University, St. Petersburg, Russia

2011-01-01T23:59:59.000Z

75

Cationically polymerizable monomers derived from renewable sources. Annual performance report  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year`s research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

76

Towards an Algebraic Speci cation of the Java Virtual Machine  

E-Print Network [OSTI]

Towards an Algebraic Speci cation of the Java Virtual Machine K Stephenson Department of Computer of the architecture of an abstract and simpli ed version of the Java Virtual Machine JVM. This concentration on the implementation-independent features of the machine allows us to build a clean and easily comprehensible model

Grant, P. W.

77

SHORT COMMUNICATION An In Situ Silver Cationization Method  

E-Print Network [OSTI]

desorption of perflu- orinated polyethers (PFPEs), and used a second laser to ablate a plume of metal ions the forma- tion of metal ion adducts by mixing metal salts into the matrix they used to perform SIMS [5 from the sample substrate to form metal cation adducts [7]. Kahr and Wilkins used a layer of silver

de Vries, Mattanjah S.

78

Steam boiler control speci cation problem: A TLA solution  

E-Print Network [OSTI]

Steam boiler control speci cation problem: A TLA solution Frank Le ke and Stephan Merz Institut fur of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi- cal state of the steam boiler and the model maintained by the controller and discuss

79

Compilation of quasi-destructive uni cation of type feature structures  

E-Print Network [OSTI]

on the LIGHT system concerns its extension so to achieve compilation of destructive uni#12;cation of FSs #18;a two stages. First, during uni#12;cation, modi#12;ed nodes in the two (rooted) FSs are marked so

Bennett, Brandon

80

Factors Affecting the Fragmentation of Peptide Ions: Metal Cationization and Fragmentation Timescale  

E-Print Network [OSTI]

cation and in assessing differences in the fragmentation pattern as a result of this binding site. An interesting observation from these studies reveals abundant x-type fragment ions occurring from the fragmentation of alkali-metal cationized peptides...

Kmiec, Kevin

2012-10-19T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations  

DOE Patents [OSTI]

A cationic metallocene complex with trisperfluorobiphenyl borate is described for use as a polymerization catalyst. 7 figs.

Marks, T.J.; Chen, Y.X.

1999-01-05T23:59:59.000Z

82

An Algebraic Speci cation of the Steam-Boiler Control System  

E-Print Network [OSTI]

An Algebraic Speci#12;cation of the Steam-Boiler Control System Michel Bidoit 1 , Claude Chevenier describe how to derive an algebraic speci#12;cation of the Steam-Boiler Control System starting from to specify the detection of the steam-boiler fail- ures. Finally we discuss validation and veri#12;cation

Bidoit, Michel

83

PHYSICAL REVIEW B 88, 174102 (2013) Positron lifetime measurements of hydrogen passivation of cation vacancies  

E-Print Network [OSTI]

of cation vacancies in yttrium aluminum oxide garnets F. A. Selim,1,* C. R. Varney,1 M. C. Tarun,1 M. C; published 4 November 2013) A charge compensation mechanism is proposed for cation vacancy defects in complex trapping was detected in samples grown in H2. This is attributed to decoration of cation vacancies

McCluskey, Matthew

84

E-Print Network 3.0 - activated cation currents Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Generating Test Data from SOFL Speci cations A. Je erson O utt ISSE ... Source: Offutt, Jeff - Department of Computer Science, George Washington University Collection: Computer...

85

E-Print Network 3.0 - abts radical cation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

abts radical cation Page: << < 1 2 3 4 5 > >> 1 2-Aminobenzothiazole degradation by free and Ca-alginate immobilized cells of Rhodococcus rhodochrous Summary: , Chisinau,...

86

Ultrafast Extreme Ultraviolet Induced Isomerization of Acetylene Cations  

SciTech Connect (OSTI)

Ultrafast isomerization of acetylene cations ([HC = CH]{sup +}) in the low-lying excited A{sup 2}{Sigma}{sub g}{sup +} state, populated by the absorption of extreme ultraviolet (XUV) photons (38 eV), has been observed at the Free Electron Laser in Hamburg, (FLASH). Recording coincident fragments C{sup +} + CH{sub 2}{sup +} as a function of time between XUV-pump and -probe pulses, generated by a split-mirror device, we find an isomerization time of 52 {+-} 15 fs in a kinetic energy release (KER) window of 5.8 < KER < 8 eV, providing clear evidence for the existence of a fast, nonradiative decay channel.

Jiang, Y.; Rudenko, Artem; Herrwerth, O.; Foucar, L.; Kurka, M.; Kuhnel, K.; Lezius, M.; Kling, Matthias; van Tilborg, Jeroen; Belkacem, Ali; Ueda, K.; Dusterer, S.; Treusch, R.; Schroter, Claus-Dieter; Moshammer, Robbert; Ullrich, Joachim

2011-06-17T23:59:59.000Z

87

Lithium-cation conductivity and crystal structure of lithium diphosphate  

SciTech Connect (OSTI)

The electrical conductivity of lithium diphosphate Li{sub 4}P{sub 2}O{sub 7} has been measured and jump-like increasing of ionic conductivity at 913 K has been found. The crystal structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction at 300–1050 K. At 913 K low temperature triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one, space group P2{sub 1}/n, a=8.8261(4) Å, b=5.2028(4) Å, c=13.3119(2) Å, ?=104.372(6)°. The migration maps of Li{sup +} cations based on experimental data implemented into program package TOPOS have been explored. It was found that lithium cations in both low- and high temperature forms of Li{sub 4}P{sub 2}O{sub 7} migrate in three dimensions. Cross sections of the migrations channels extend as the temperature rises, but at the phase transition point have a sharp growth showing a strong “crystal structure – ion conductivity” correlation. -- Graphical abstract: Crystal structure of Li{sub 4}P{sub 2}O{sub 7} at 950 K. Red balls represent oxygen atoms; black lines show Li{sup +} ion migration channels in the layers perpendicular to [001] direction. Highlights: • Structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction. • At 913 K triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one. • The migration maps of Li{sup +} implemented into program package TOPOS have been explored. • Cross sections of the migrations channels at the phase transition have a sharp growth.

Voronin, V.I., E-mail: voronin@imp.uran.ru [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Sherstobitova, E.A. [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Blatov, V.A., E-mail: blatov@samsu.ru [Samara Center for Theoretical Materials Science (SCTMS), Samara State University, Ac.Pavlov Street 1, 443011 Samara (Russian Federation); Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia); Shekhtman, G.Sh., E-mail: shekhtman@ihte.uran.ru [Institute of High Temperature Electrochemistry Urals Branch RAS, Akademicheskaya 20, 620990 Ekaterinburg (Russian Federation)

2014-03-15T23:59:59.000Z

88

Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented  

E-Print Network [OSTI]

Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented Executable the steam boiler control speci cation problem to il- lustrate how the evolving algebra approach to the speci, in June 1995, to control the Karlsruhe steam boiler simulator satisfactorily. The abstract machines

Börger, Egon

89

Composing Speci cations using Communication Helen Treharne, Steve Schneider, and Marchia Bramble  

E-Print Network [OSTI]

CSPto enable controlled interaction between B machines. This illustrates how B machines are essential abstract speci cation described in CSP. This allows safety and liveness properties to be established for combinations of communicating B machines. Keywords: B-Method, CSP, Composing Speci cations, Combining

Doran, Simon J.

90

Advanced inverse techniques for the design of directional solidi cation processes  

E-Print Network [OSTI]

Advanced inverse techniques for the design of directional solidi cation processes Nicholas Zabaras methodologies for thermal process design can be developed using inverse problem theory. Such techniques the problem of designing the mold cooling/heating conditions such that stable solidi cation growth is obtained

Zabaras, Nicholas J.

91

Logic Based Approaches to Work ow Modeling and Veri cation 1 Saikat Mukherjee, Hasan Davulcu, Michael Kifer, Pinar Senkul,  

E-Print Network [OSTI]

Contents Logic Based Approaches to Work ow Modeling and Veri#12;cation 1 Saikat Mukherjee, Hasan : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 37 #12; #12; Logic-Based Approaches to Work ow Modeling and Veri#12;cation Saikat Mukherjee, 1 Hasan

Yang, Guizhen

92

Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjets  

E-Print Network [OSTI]

of the interaction of the carboxylate with lithium; this isinteraction strengths of the monovalent cations of sodium, potassium, and lithiumlithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

Uejio, Janel S.

2008-01-01T23:59:59.000Z

93

Pinning lattice: Effect of rhenium doping on the microstructural evolution from Tl-2212 to Hg-1212 films during cation exchange  

E-Print Network [OSTI]

In a cation exchange process developed recently by some of us, epitaxial HgBa2CaCu2O6 films can be obtained by diffusing volatile Tl cations out of, and simultaneously diffusing Hg cations into, the crystalline lattice of ...

Wu, Judy; Zhao, H.

2004-08-15T23:59:59.000Z

94

Cation disorder in high dose neutron irradiated spinel  

SciTech Connect (OSTI)

The crystal structures of MgAl{sub 2}O{sub 4} spinel single crystals irradiated to high neutron fluences (>5{center_dot}10{sup 26} n/m{sup 2} (E{sub n}>0.1 MeV)), were examined by neutron diffraction. Crystal structure refinement of the highest dose sample indicated that the average scattering strength of the tetrahedral crystal sites decreased by {approximately}20% while increasing by {approximately}8% on octahedral sites. Since the neutron scattering length for Mg is considerably larger than for Al, this result is consistent with site exchange between Mg{sup 2+} ions on tetrahedral sites and Al{sup 3+} ions on octahedral sites. Least squares refinements also indicated that in all irradiated samples, at least 35% of Mg{sup 2+} and Al{sup 3+} ions in the crystal experienced disordering replacements. This retained dpa on the cation sublattices is the largest retained damage ever measured in an irradiated spinel material.

Sickafus, K.E.; Larson, A.C.; Yu, N.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hollenberg, G.W.; Garner, F.A. [Pacific Northwest Lab., Richland, WA (United States); Bradt, R.C. [Univ. of Nevada, Reno, NV (United States)

1994-06-01T23:59:59.000Z

95

Cation disorder in high-dose, neutron-irradiated spinel  

SciTech Connect (OSTI)

The objective of this effort is to determine whether MgAl{sub 2}O{sub 4} spinel is a suitable ceramic for fusion applications. Here, the crystal structures of MgAl{sub 2}O{sub 4} spinel single crystals irradiated to high neutron fluences [>5{center_dot}10{sup 26} n/m{sup 2} (E{sub n} > 0.1 MeV)] were examined by neutron diffraction. Crystal structure refinement of the highest dose sample indicated that the average scattering strength of the tetrahedral crystal sites decreased by {approximately} 20% while increasing by {approximately} 8% on octahedral sites. Since the neutron scattering length for Mg is considerably larger than for Al, this results is consistent with site exchange between Mg{sup 2+} ions on tetrahedral sites and Al{sup 3+} ions on octahedral sites. Least-squares refinements also indicated that, in all irradiated samples, at least 35% of Mg{sup 2+} and Al{sup 3+} ions in the crystal experienced disordering replacements. This retained dpa on the cation sublattices is the largest retained damage ever measured in an irradiated spinel material.

Sickafus, K.E.; Larson, A.C.; Yu, N.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hollenberg, G.W.; Garner, F.A. [Pacific Northwest Lab., Richland, WA (United States); Bradt, R.C. [Univ. of Nevada, Reno, NV (United States)

1994-08-01T23:59:59.000Z

96

Geothermometry At Long Valley Caldera Geothermal Area (Mariner...  

Open Energy Info (EERE)

L. Sorey, Robert H. Mariner, Alfred H. Truesdell (1979) Chemical and Isotopic Prediction of Aquifer Temperatures in the Geothermal System at Long Valley, California Michael...

97

Geochemistry And Geothermometry Of Spring Water From The Blackfoot...  

Open Energy Info (EERE)

for eight springs along the Corral Creek drainage. The springs along Corral Creek have Na-K-Ca temperatures that average 354C, a direct result of high potassium concentrations in...

98

Geothermometry At Long Valley Caldera Geothermal Area (McKenzie...  

Open Energy Info (EERE)

1971) prior to analysis by mass spectrometry. Water samples were analyzed for their oxygen isotope ratios using the carbon dioxide-equilibration method. Waters analyzed from the...

99

Geothermometry At Long Valley Caldera Geothermal Area (Sorey...  

Open Energy Info (EERE)

studies, and seem to prove useful in most cases (Flexser, 1991; Goff et al., 1991; Smith and Suemnicht, 1991). Results from these studies are also summarized in Sorey et al....

100

Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward...  

Open Energy Info (EERE)

Area. References S. H. Ward, W. T. Parry, W. P. Nash, W. R. Sill, K. L. Cook, R. B. Smith, D. S. Chapman, F. H. Brown, J. A. Whelan, J. R. Bowman (1978) A Summary of the...

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Colorado thermal spring water geothermometry (public dataset) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreisVolcanicPowerRaft River 5Courts Jump to:Information

102

Geothermometry At Akutan Fumaroles Area (Kolker, Et Al., 2010) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergy Information

103

Geothermometry At Blackfoot Reservoir Area (Hutsinpiller & Parry, 1985) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergy

104

Geothermometry At Blue Mountain Geothermal Area (Casteel, Et Al., 2010) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergyOpen Energy

105

Geothermometry At Buffalo Valley Hot Springs Area (Laney, 2005) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergyOpen

106

Geothermometry At Central Nevada Seismic Zone Region (Laney, 2005) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergyOpenEnergy

107

Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey

108

Geothermometry At Chena Geothermal Area (Kolker, 2008) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformation 2008)

109

Geothermometry At Coso Geothermal Area (1978) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformationEnergy

110

Geothermometry At Fort Bliss Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformationEnergyFishFort

111

Geothermometry At Hot Springs Ranch Area (Szybinski, 2006) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot Springs Ranch

112

Geothermometry At Kawaihae Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot Springs

113

Geothermometry At Kilauea East Rift Geothermal Area (Thomas, 1986) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot SpringsEnergy

114

Geothermometry At Lahaina-Kaanapali Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot

115

Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) | Open

116

Geothermometry At Lassen Volcanic National Park Area (Thompson, 1985) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) | OpenOpen

117

Geothermometry At Long Valley Caldera Geothermal Area (Farrar, Et Al.,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) |

118

Geothermometry At Long Valley Caldera Geothermal Area (Mariner & Willey,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) |1976) |

119

Geothermometry At Lualualei Valley Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010)

120

Geothermometry At New River Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation| Open EnergyNew

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward, Et Al.,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation|Open1978) | Open

122

Geothermometry At The Needles Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -Information Shevenell, Et Al.,The

123

Geothermometry At Yellowstone Region (Fournier, 1979) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -Information

124

Isotope Geothermometry At Lightning Dock Geothermal Area (Witcher, 2006) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429 Throttled (botOpen Energy Information 2006) Jump to: navigation, search

125

Improved Geothermometry Through Multivariate Reaction Path Modeling and  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Department-2023Department ofSmartMethod forEvaluation of

126

Geochemistry And Geothermometry Of Spring Water From The Blackfoot  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6TheoreticalFuelCellGemini SolarAssetsof Thermal

127

Geothermometry At Alum Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourage the<Geothermal/PowerUse)DOE

128

Geothermometry At Coso Geothermal Area (1980) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourage

129

Geothermometry At Raft River Geothermal Area (1980) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformation Desert

130

Geothermometry At Silver Peak Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchToInformation Edmiston & Benoit,

131

Potential Modulated Intercalation of Alkali Cations into Metal Hexacyanoferrate Coated Electrodes  

SciTech Connect (OSTI)

Nickel hexacyanoferrate is a polynuclear inorganic ion intercalation material that loads (intercalates) and elutes (deintercalates) alkali cations from its structure when electrochemically reduced and oxidized, respectively. Nickel hexacyanoferrrate (NiHCF) is known to preferentially intercalate cesium over all other alkali cations, thus providing a basis for a separation scheme that can tackle DOE's radiocesium contamination problem. This program studied fundamental issues in alkalization intercalation and deintercalation in nickel hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties from cation mixtures, (2) enhancing ion exchange capacities, and (3) and understanding the electrochemically-switched ion exchange process (ESIX).

Daniel T. Schwartz; Bekki Liu; Marlina Lukman; Kavita M. Jeerage; William A. Steen; Haixia Dai; Qiuming Yu; J. Antonio Medina

2002-02-18T23:59:59.000Z

132

Cation exchange at the secondary building units of metal–organic frameworks  

E-Print Network [OSTI]

Cation exchange is an emerging synthetic route for modifying the secondary building units (SBUs) of metal–organic frameworks (MOFs). This technique has been used extensively to enhance the properties of nanocrystals and ...

Brozek, Carl Kavanaugh

133

A Reduction for Automated Veri cation of Authentication Scott D. Stoller  

E-Print Network [OSTI]

A Reduction for Automated Veri cation of Authentication Protocols Scott D. Stoller Computer Science of those case studies were not rigorously justi ed. Reduction theorems are needed, which show

Stoller, Scott

134

The effect of trivalent cations on the major lower mantle silicates  

E-Print Network [OSTI]

I have investigated the effect of composition, especially ferric iron and aluminum, on the equations of state and phase stability of perovskite and post-perovskite. The presence of trivalent cations decreases the bulk ...

Catalli, Krystle Carina

2011-01-01T23:59:59.000Z

135

NMR Studies of Heat-Induced Transitions in Structure and Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Structure and Cation Binding Environments of a Strontium-Saturated Swelling Mica. Abstract: In this work we combined Al, Si, F, and Na magic-angle spinning (MAS) nuclear...

136

Identi cation Tasking and Networking (ITN) Model For The FBI's Integrated Automated  

E-Print Network [OSTI]

Identi cation Tasking and Networking (ITN) Model For The FBI's Integrated Automated Fingerprint September 29, 1994 Abstract This document describes the model developed for the ITN/FBI using the SES

Murphy, John

137

ADVANCES IN HYDROGEOCHEMICAL INDICATORS FOR THE DISCOVERY OF NEW GEOTHERMAL RESOURCES IN THE GREAT BASIN, USA  

SciTech Connect (OSTI)

This report summarizes the results of Phase I work for a go/no go decision on Phase II funding. In the first objective, we assessed the extent to which fluid-mineral equilibria controlled deep water compositions in geothermal systems across the Great Basin. Six systems were evaluated: Beowawe; Desert Peak; Dixie Valley; Mammoth; Raft River; Roosevelt. These represent a geographic spread of geothermal resources, in different geological settings and with a wide range of fluid compositions. The results were used for calibration/reformulation of chemical geothermometers that reflect the reservoir temperatures in producing reservoirs. In the second objective, we developed a reactive -transport model of the Desert Peak hydrothermal system to evaluate the processes that affect reservoir fluid geochemistry and its effect on solute geothermometry. This included testing geothermometry on “reacted” thermal water originating from different lithologies and from near-surface locations where the temperature is known from the simulation. The integrated multi-component geothermometer (GeoT, relying on computed mineral saturation indices) was tested against the model results and also on the systems studied in the first objective.

Simmons, Stuart F [Colorado School of Mines; Spycher, Nicolas [Lawrence Berkeley National Laboratory; Sonnenthal, Eric [Lawrence Berkeley National Laboratory; Dobson, Patrick [Lawrence Berkeley National Laboratory

2013-05-20T23:59:59.000Z

138

Colloid Facilitated Transport of Radioactive Cations in the Vadose Zone: Field Experiments Oak Ridge  

SciTech Connect (OSTI)

The overarching goal of this study was to improve understanding of colloid-facilitated transport of radioactive cations through unsaturated soils and sediments. We conducted a suite of laboratory experiments and field experiments on the vadose-zone transport of colloids, organic matter, and associated contaminants of interest to the U.S. Department of Energy (DOE). The laboratory and field experiments, together with transport modeling, were designed to accomplish the following detailed objectives: 1. Evaluation of the relative importance of inorganic colloids and organic matter to the facilitation of radioactive cation transport in the vadose zone; 2. Assessment of the role of adsorption and desorption kinetics in the facilitated transport of radioactive cations in the vadose zone; 3. Examination of the effects of rainfall and infiltration dynamics and in the facilitated transport of radioactive cations through the vadose zone; 4. Exploration of the role of soil heterogeneity and preferential flow paths (e.g., macropores) on the facilitated transport of radioactive cations in the vadose zone; 5. Development of a mathematical model of facilitated transport of contaminants in the vadose zone that accurately incorporates pore-scale and column-scale processes with the practicality of predicting transport with readily available parameters.

James E. Saiers

2012-09-20T23:59:59.000Z

139

Mathematical Modeling of Cation Contamination in a Proton-exchange Membrane  

SciTech Connect (OSTI)

Transport phenomena in an ion-exchange membrane containing both H+ and K+ are described using multicomponent diffusion equations (Stefan-Maxwell). A model is developed for transport through a Nafion 112 membrane in a hydrogen-pump setup. The model results are analyzed to quantify the impact of cation contamination on cell potential. It is shown that limiting current densities can result due to a decrease in proton concentration caused by the build-up of contaminant ions. An average cation concentration of 30 to 40 percent is required for appreciable effects to be noticed under typical steady-state operating conditions.

Weber, Adam; Delacourt, Charles

2008-09-11T23:59:59.000Z

140

Radiation induced redox reactions and fragmentation of constituent ions in ionic liquids II. Imidazolium cations.  

SciTech Connect (OSTI)

In part 1 of this study, radiolytic degradation of constituent anions in ionic liquids (ILs) was examined. The present study continues the themes addressed in part 1 and examines the radiation chemistry of 1,3-dialkyl substituted imidazolium cations, which currently comprise the most practically important and versatile class of ionic liquid cations. For comparison, we also examined 1,3-dimethoxy- and 2-methyl-substituted imidazolium and 1-butyl-4-methylpyridinium cations. In addition to identification of radicals using electron paramagnetic resonance spectroscopy (EPR) and selective deuterium substitution, we analyzed stable radiolytic products using {sup 1}H and {sup 13}C nuclear magnetic resonance (NMR) and tandem electrospray ionization mass spectrometry (ESMS). Our EPR studies reveal rich chemistry initiated through 'ionization of the ions': oxidation and the formation of radical dications in the aliphatic arms of the parent cations (leading to deprotonation and the formation of alkyl radicals in these arms) and reduction of the parent cation, yielding 2-imidazolyl radicals. The subsequent reactions of these radicals depend on the nature of the IL. If the cation is 2-substituted, the resulting 2-imidazolyl radical is relatively stable. If there is no substitution at C(2), the radical then either is protonated or reacts with the parent cation forming a C(2)-C(2) {sigma}{sigma}*-bound dimer radical cation. In addition to these reactions, when methoxy or C{sub {alpha}}-substituted alkyl groups occupy the N(1,3) positions, their elimination is observed. The elimination of methyl groups from N(1,3) was not observed. Product analyses of imidazolium liquids irradiated in the very-high-dose regime (6.7 MGy) reveal several detrimental processes, including volatilization, acidification, and oligomerization. The latter yields a polymer with m/z of 650 {+-} 300 whose radiolytic yield increases with dose (0.23 monomer units per 100 eV for 1-methyl-3-butylimidazolium trifluorosulfonate). Gradual generation of this polymer accounts for the steady increase in the viscosity of the ILs upon irradiation. Previous studies at lower dose have missed this species due to its wide mass distribution (stretching out to m/z 1600) and broad NMR lines, which make it harder to detect at lower concentrations. Among other observed changes is the formation of water immiscible fractions in hydrophilic ILs and water miscible fractions in hydrophobic ILs. The latter is due to anion fragmentation. The import of these observations for use of ILs as extraction solvents in nuclear cycle separations is discussed.

Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Hatcher, J.; Wishart, J. (Chemical Sciences and Engineering Division); (BNL)

2011-04-14T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Criteria for Generating Speci cation-based Tests A. Je erson O utt and Yiwei Xiong Shaoying Liu  

E-Print Network [OSTI]

- ria o er testers ways to decide what test inputs to use during testing, making it more likely presents a model for developing test in- puts from state-based speci cations, and formal crite- riaCriteria for Generating Speci cation-based Tests A. Je erson O utt and Yiwei Xiong Shaoying Liu

Offutt, Jeff

142

FLUORINATED HYDROXYTELECHELIC POLYBUTADIENE AS ADDITIVE IN CATIONIC PHOTOPOLYMERIZATION OF AN EPOXY RESIN  

E-Print Network [OSTI]

OF AN EPOXY RESIN B. Ameduri 1 , R. Bongiovanni2 , M. Sangermano2 , A. Priola2 1 Ingénierie et Architectures in original formulations to enable the UV cationic polymerization of a telechelic diepoxy cycloaliphatic resin) values showing a surface modification of the epoxy based system. Indeed, great modifications were noted

Paris-Sud XI, Université de

143

High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators  

DOE Patents [OSTI]

A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

Janke, C.J.; Lopata, V.J.; Havens, S.J.; Dorsey, G.F.; Moulton, R.J.

1999-03-02T23:59:59.000Z

144

CO adsorption-desorption properties of cation-exchanged NaX zeolite and supported ruthenium  

SciTech Connect (OSTI)

The binding states of carbon monoxide over cation-exchanged NaX zeolites and over corresponding Ru-containing samples have been investigated using thermal desorption spectroscopy. Exchange of sodium with cations such as Li{sup +}, Ca{sup 2+}, Mg{sup 2+}, and La{sup 3+} gave rise to additional CO adsorption states, a higher isosteric heat of CO adsorption, an increased density of acid sites, and an increased amount of adsorbed CO, depending on the nature and ionic radius of the charge-balancing cation. The charge-balancing cations at the zeolite surface (e.g., Ca{sub 2+}, La{sup 3+}) function as additional CO adsorption sites in conjunction with surface acid centers (e.g., the Al{sup 3+} center) and metal sites. In addition to surface sites, CO is also found to be held in structural cavities and macropores of the zeolite matrix. The programmed heating of both the metal-free and Ru-containing zeolites subsequent to room temperature CO adsorption gave desorption peaks due to release of CO at temperatures less than {approximately}500 K while the higher temperature peaks were constituted mainly of CO{sub 2}. Electron spectroscopy results have revealed that the exposure of these samples to CO and subsequent thermal treatment resulted in the formation of surface carbonaceous species. The nature of CO adsorption states giving rise to CO{sub 2} formation is discussed.

Gupta, N.M.; Kamble, V.S.; Rao, K.A.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1989-12-01T23:59:59.000Z

145

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory  

E-Print Network [OSTI]

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory Ricardo B. Metz Department of Chemistry, University of Massachusetts, Amherst, MA 01003 USA Abstract Gas such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

Metz, Ricardo B.

146

Calcium and Strontium Hexaluminates: NMR Evidence that "Pentacoordinate" Cation Sites Are Four-Coordinated  

E-Print Network [OSTI]

LETTERS Calcium and Strontium Hexaluminates: NMR Evidence that "Pentacoordinate" Cation Sites, strontium hexaluminate (SrAl12O19, "SA6") and calcium hexaluminate (CaAl12O19, "CA6," synthetic hibonite, not dynamical, disorder among these sites. Introduction Calcium and strontium hexaluminates (CaAl12O19, "CA6

Puglisi, Joseph

147

A Fuzzy Neural Network Approach Based on Dirichlet Tesselations for Nearest Neighbor Classi cation of  

E-Print Network [OSTI]

-mail: andreas@theseas.ntua.gr Abstract A neural network classi er using fuzzy set representation of pattern concerning di cult recognition problems show that the proposed approach is very successful in applying fuzzy sets to pattern classi cation. 1 Introduction Several models have been developed during the last years

Blekas, Konstantinos

148

Solidi cation of a high-Reynolds-number ow in laser percussion drilling  

E-Print Network [OSTI]

Solidi#12;cation of a high-Reynolds-number ow in laser percussion drilling W. R. Smith y and R. M laser percussion drilling. 1 Introduction Laser percussion drilling is used to machine gas turbine with conventional mechanical drills. The term percussion refers to the repeated operation of the laser in short

Eindhoven, Technische Universiteit

149

Spectroscopic signatures of proton transfer dynamics in the water dimer cation  

SciTech Connect (OSTI)

Using full dimensional EOM-IP-CCSD/aug-cc-pVTZ potential energy surfaces, the photoelectron spectrum, vibrational structure, and ionization dynamics of the water dimer radical cation, (H2O)+2, were computed. We also report an experimental photoelectron spectrum which is derived from photoionization efficiency measurements and compares favorably with the theoretical spectrum. The vibrational structure is also compared with the recent experimental work of Gardenier et al. [J. Phys. Chem. A 113, 4772 (2009)] and the recent theoretical calculations by Cheng et al. [J. Phys. Chem. A 113 13779 (2009)]. A reduced dimensionality nuclear Hamiltonian was used to compute the ionization dynamics for both the ground state and first excited state of the cation. The dynamics show markedly different behavior and spectroscopic signatures depending on which state of the cation is accessed by the ionization. Ionization to the ground-state cation surface induces a hydrogen transfer which is complete within 50 femtoseconds, whereas ionization to the first excited state results in a much slower process.

Kamarchik, Eugene; Kostko, Oleg; Bowman, Joel M.; Ahmed, Musahid; Krylov, Anna I.

2009-12-21T23:59:59.000Z

150

Synthesis and Reversible Reductive Coupling of Cationic, Dinitrogen-Derived Diazoalkane Complexes  

E-Print Network [OSTI]

A series of cationic diazoalkane complexes [4-RC6H4C(H)NNMo(N[t-Bu]Ar)3][AlCl4] 4-RC subscript 6 H subscript 4 C(H)NNMo(N[t-Bu]Ar) subscript 3] [AlCl subscript 4

Curley, John J.

151

Evaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture  

E-Print Network [OSTI]

anthro- pogenic sources.1 Carbon capture and sequestration (CCS) has been proposed as a means of limitingEvaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture Tae the impact of rising concentrations of atmo- spheric carbon dioxide on climate change continue to mount

152

The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain  

E-Print Network [OSTI]

The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain K. S. Madsen1 has investigated the effect of Mn on 1 H MR spectroscopy using an in vivo Mn-enhanced optic tract into a stereotactic device. Images and 1 H MR spectra were acquired using a Varian 4.7T animal scanner together

153

AMAST '96, July 1-5, 1996, Munich, Germany Formal Veri cation of Signal Programs  

E-Print Network [OSTI]

to a Power Transformer Station Controller? Michel Le Borgne, Herve Marchand, Eric Rutten IRISA / INRIA cation of the automatic circuit breaking control system of an electric power transformer station is double:protecting the components of the transformer itself, and minimizing the defect in the distribution

Paris-Sud XI, Université de

154

Syst. Biol. 49(4):617627, 2000 Quanti cation of Homoplasy for Nucleotide Transitions and  

E-Print Network [OSTI]

Syst. Biol. 49(4):617­627, 2000 Quanti cation of Homoplasy for Nucleotide Transitions Science Park, New Haven, CT 06511, USA; E-mail: s.stanley@genaissance.com Abstract.--Nucleotide used in molecular systematics, where homoplasy in nucleotide characters may be abundant because

Sorenson, Michael

155

oligomeric and polymeric DNA Large electrostatic differences in the binding thermodynamics of a cationic peptide to  

E-Print Network [OSTI]

oligomeric and polymeric DNA Large electrostatic differences in the binding thermodynamics electrostatic differences in the binding thermodynamics of a cationic peptide to oligomeric and polymeric DNA binding to polymeric and oligomeric DNA are not equivalent because of long-range electrostatic effects

Lohman, Timothy M.

156

High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators  

DOE Patents [OSTI]

A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

Janke, Christopher J. (Powell, TN); Lopata, Vincent J. (Manitoba, CA); Havens, Stephen J. (Knoxville, TN); Dorsey, George F. (Farragut, TN); Moulton, Richard J. (Lafayette, CA)

1999-01-01T23:59:59.000Z

157

Analysis of Mixture Models using Expected Posterior Priors, with Application to Classi cation  

E-Print Network [OSTI]

of Gamma Ray Bursts Jos#19;e M. P#19;erez and James O. Berger #3; Abstract Consider observations the number of components is unknown. An appli- cation is considered involving Gamma Ray Bursts, modeled is considered in section 4 in the determination of the number of classes of Gamma Ray Bursts (Meegan et al

West, Mike

158

Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides  

SciTech Connect (OSTI)

A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2012-12-15T23:59:59.000Z

159

Neutralization of Methyl Cation via Chemical Reactions in Low-Energy Ion-Surface  

E-Print Network [OSTI]

with Fluorocarbon and Hydrocarbon Self-Assembled Monolayer Films A´ rpa´d Somogyi, Darrin L. Smith, and Vicki H-surface collisions of methyl cation at hydrocarbon and fluorocarbon self- assembled monolayer (SAM) surfaces produce with hydrocarbon and fluorocarbon SAMs occurs by concerted chemical reactions, i.e., that neutralization

Wysocki, Vicki H.

160

New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers...  

Open Energy Info (EERE)

errors (2-3%) than for the original equation (5-29%). Authors Surendra P. Verma and Edgar Santoyo Published Journal Journal of Volcanology and Geothermal Research, 1997 DOI Not...

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Application Of An Artificial Neural Network Model To A Na-K Geothermometer  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300Algoil JumpAltergyExperimentsInformationAnuvuCommissionArea, Japan |Of||

162

New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's HeatMexico: EnergyMithunCenter Jump to:2Harvest Jump to: navigation,Detection

163

A New Improved Na-K Geothermometer By Artificial Neural Networks | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 SouthWater Rights, Substantive(Sichuan, Sw China)|EnergyApproach ToMap

164

An Empirical Na-K-Ca Geothermometer For Natural Waters | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300Algoil JumpAltergy SystemsAmericanAmphenolInformation Embarrassment

165

Semantics of Architectural Speci cations in CASL Lutz Schroder 1 , Till Mossakowski 1 , Andrzej Tarlecki 2;3 , Bartek Klin 4 , and  

E-Print Network [OSTI]

at various levels in an institution-independent fashion. Introduction A common feature of present-day algebraic speci#12;cation languages (see e.g. [Wir86,EM85,GHG + 93,CoFI96,SW99]) is the provision;cations at various levels. We use a simple subset of Casl architectural speci#12;cations, which

Schröder, Lutz

166

Communication: CO oxidation by silver and gold cluster cations: Identification of different active oxygen species  

SciTech Connect (OSTI)

The oxidation of carbon monoxide with nitrous oxide on mass-selected Au{sub 3}{sup +} and Ag{sub 3}{sup +} clusters has been investigated under multicollision conditions in an octopole ion trap experiment. The comparative study reveals that for both gold and silver cations carbon dioxide is formed on the clusters. However, whereas in the case of Au{sub 3}{sup +} the cluster itself acts as reactive species that facilitates the formation of CO{sub 2} from N{sub 2}O and CO, for silver the oxidized clusters Ag{sub 3}O{sub x}{sup +} (n= 1-3) are identified as active in the CO oxidation reaction. Thus, in the case of the silver cluster cations N{sub 2}O is dissociated and one oxygen atom is suggested to directly react with CO, whereas a second kind of oxygen strongly bound to silver is acting as a substrate for the reaction.

Popolan, Denisia M.; Bernhardt, Thorsten M. [Institute of Surface Chemistry and Catalysis, University of Ulm, Albert-Einstein-Allee 47, 89069 Ulm (Germany)

2011-03-07T23:59:59.000Z

167

Aza Cope Rearrangement of Propargyl Enammonium Cations Catalyzed By a Self-Assembled `Nanozyme  

SciTech Connect (OSTI)

The tetrahedral [Ga{sub 4}L{sub 6}]{sup 12-} assembly (L = N,N-bis(2,3-dihydroxybenzoyl)-1,5-diaminonaphthalene) encapsulates a variety of cations, including propargyl enammonium cations capable of undergoing the aza Cope rearrangement. For propargyl enammonium substrates that are encapsulated in the [Ga{sub 4}L{sub 6}]{sup 12-} assembly, rate accelerations of up to 184 are observed when compared to the background reaction. After rearrangement, the product iminium ion is released into solution and hydrolyzed allowing for catalytic turnover. The activation parameters for the catalyzed and uncatalyzed reaction were determined, revealing that a lowered entropy of activation is responsible for the observed rate enhancements. The catalyzed reaction exhibits saturation kinetics; the rate data obey the Michaelis-Menten model of enzyme kinetics, and competitive inhibition using a non-reactive guest has been demonstrated.

Hastings, Courntey J.; Fiedler, Dorothea; Bergman, Robert G.; Raymond, Kenneth N.

2008-02-27T23:59:59.000Z

168

Metal cation/anion adsorption on calcium carbonate: Implications to metal ion concentrations in groundwater  

SciTech Connect (OSTI)

This chapter evaluates the sorption behavior of metallic ions on specimen calcite as a basis for determining the importance of calcite relative to other subsurface sorbents, such as layer silicates and oxides, in controlling metal ion concentration in calcareous groundwaters. A review of the literature shows the sorption of both metallic cations and anions on calcite over ranges in pH and CO{sub 2} partial pressure to be consistent with a surface-exchange process where cations exchange with surface Ca and anions exchange with surface CO{sub 3}. A general surface-exchange model was developed to account for the effects of Ca and CO{sub 3} concentrations, pH, and calcite surface area on cation and anion sorption onto calcite. The model was applied to recently developed experimental sorption data of Zn and SeO{sub 3} on specimen calcite in equilibrium CaCO{sub 3}(aq) suspensions. The surface-exchange model was able to describe the effects of pH on both cation and anion sorption, and provided good predictions of the effects of variable CO{sub 2}(g) pressure on Zn sorption and of PO{sub 4} on SeO{sub 3} sorption. The surface-exchange model, combined with sorption constants for other phases, was used to calculate Cd sorption to a hypothetical aquifer material containing a mixture of sorbents. The sorbent concentrations were fixed to those expected in groundwater zones. The multi-sorbent calculation documented the importance of calcite as a sorbent for metallic ions in groundwater.93 refs., 18 figs., 5 tabs.

Zachara, J.M.; Cowan, C.E.; Resch, C.T.

1990-05-01T23:59:59.000Z

169

Structural Consequences of Anionic Host-Cationic Guest Interactions in a Supramolecular Assembly  

SciTech Connect (OSTI)

The molecular structure of the self-assembled supramolecular assembly [M{sub 4}L{sub 6}]{sup 12-} has been explored with different metals (M = Ga{sup III}, Fe{sup III}, Ti{sup IV}) and different encapsulated guests (NEt{sub 4}{sup +}, BnNMe{sub 3}{sup +}, Cp{sub 2}Co{sup +}, Cp*{sub 2}Co{sup +}) by X-ray crystallography. While the identity of the metal ions at the vertices of the M{sub 4}L{sub 6} structure is found to have little effect on the assembly structure, encapsulated guests significantly distort the size and shape of the interior cavity of the assembly. Cations on the exterior of the assembly are found to interact with the assembly through either {pi}-{pi}, cation-{pi}, or CH-{pi} interactions. In some cases, the exterior guests interact with only one assembly, but cations with the ability to form multiple {pi}-{pi} interactions are able to interact with adjacent assemblies in the crystal lattice. The solvent accessible cavity of the assembly is modeled using the rolling probe method and found to range from 253-434 {angstrom}{sup 3}, depending on the encapsulated guest. Based on the volume of the guest and the volume of the cavity, the packing coefficient for each host-guest complex is found to range from 0.47-0.67.

Pluth, Michael D.; Johnson, Darren W.; Szigethy, Geza; Davis, Anna V.; Teat, Simon J.; Oliver, Allen G.; Bergman, Robert G.; Raymond, Kenneth N.

2008-07-09T23:59:59.000Z

170

Infrared spectroscopy of the acetyl cation and its protonated ketene isomer  

SciTech Connect (OSTI)

[C{sub 2},H{sub 3},O]{sup +} ions are generated with a pulsed discharge in a supersonic expansion containing methyl acetate or acetone. These ions are mass selected and their infrared spectra are recorded via laser photodissociation and the method of argon tagging. Computational chemistry is employed to investigate structural isomers and their spectra. The acetyl cation (CH{sub 3}CO{sup +}) is the global minimum and protonated ketene (CH{sub 2}COH{sup +}) is the next lowest energy isomer (+176.2 kJ/mol). When methyl acetate is employed as the precursor, the infrared spectrum reveals that only the acetyl cation is formed. Partially resolved rotational structure reveals rotation about the C{sub 3} axis. When acetone is used as the precursor, acetyl is still the most abundant cation, but there is also a minor component of protonated ketene. Computations reveal a significant barrier to interconversion between the two isomers (+221 kJ/mol), indicating that protonated ketene must be obtained via kinetic trapping. Both isomers may be present in interstellar environments, and their implications for astrochemistry are discussed.

Mosley, J. D.; Young, J. W.; Duncan, M. A. [Department of Chemistry, University of Georgia, Athens, Georgia 30602 (United States)

2014-07-14T23:59:59.000Z

171

Use of MgO doped with a divalent or trivalent metal cation for removing arsenic from water  

DOE Patents [OSTI]

Systems and methods for use of magnesium hydroxide, either directly or through one or more precursors, doped with a divalent or trivalent metal cation, for removing arsenic from drinking water, including water distribution systems. In one embodiment, magnesium hydroxide, Mg(OH).sub.2 (a strong adsorbent for arsenic) doped with a divalent or trivalent metal cation is used to adsorb arsenic. The complex consisting of arsenic adsorbed on Mg(OH).sub.2 doped with a divalent or trivalent metal cation is subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems. In another embodiment, magnesium oxide, MgO, is employed, which reacts with water to form Mg(OH).sub.2. The resulting Mg(OH).sub.2 doped with a divalent or trivalent metal cation, then adsorbs arsenic, as set forth above. The method can also be used to treat human or animal poisoning with arsenic.

Moore, Robert C; Holt-Larese, Kathleen C; Bontchev, Ranko

2013-08-13T23:59:59.000Z

172

Relating the Expression of Soil Redoximorphic Features to Soil Texture, pH, and Cation Exchange Capacity  

E-Print Network [OSTI]

Three laboratory studies were performed to elucidate the influence of soil texture, pH, and cation exchange capacity (CEC) on the concentration of ferrous Fe in soil solution and the resulting expression of soil redoximorphic features...

Mersmann, Ryan S.

2010-01-14T23:59:59.000Z

173

Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium  

SciTech Connect (OSTI)

An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.

Marcalo, Joaquim; Gibson, John K.

2009-08-10T23:59:59.000Z

174

Compound and Elemental Analysis At Lassen Volcanic National Park...  

Open Energy Info (EERE)

sample taken had a pH of 8.35 and contained 2100 ppm Cl and 0.55 ppm NH3. Ratios of Na+K+ and Na+Cl remained nearly constant throughout the flow test. Cation geothermometers...

175

The cation inversion and magnetization in nanopowder zinc ferrite obtained by soft mechanochemical processing  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Nano powder of ZnFe{sub 2}O{sub 4} prepared by a soft mechanochemical route after 18 h milling. • Phase formation controlled by XRD, Raman spectroscopy and magnetic measurements. • Size, strain and cation inversion degree determined by Rietveld refinement. • We were able to estimate the degree of inversion at most 0.348 and 0.4. • Obtained extremely high values of saturation magnetizations at T = 4.5 K. - Abstract: Two zinc ferrite nanoparticle materials were prepared by the same method – soft mechanochemical synthesis, but starting from different powder mixtures: (1) Zn(OH){sub 2}/?-Fe{sub 2}O{sub 3} and (2) Zn(OH){sub 2}/Fe(OH){sub 3}. In both cases a single phase system was obtained after 18 h of milling. The progress of the synthesis was controlled by X-ray diffractometry (XRD), Raman spectroscopy, TEM and magnetic measurements. Analysis of the XRD patterns by Rietveld refinement allowed determination of the cation inversion degree for both obtained single phase ZnFe{sub 2}O{sub 4} samples. The sample obtained from mixture (1) has the cation inversion degree 0.3482 and the sample obtained from mixture (2) 0.400. Magnetization measurements were confirmed that the degrees of the inversion were well estimated. Comparison with published data shows that used method of synthesis gives nano powder samples with extremely high values of saturation magnetizations: sample (1) 78.3 emu g{sup ?1} and sample (2) 91.5 emu g{sup ?1} at T = 4.5 K.

Milutinovi?, A. [Institute of Physics, University of Belgrade, Pregrevica 118, Zemun, Belgrade (Serbia); Lazarevi?, Z., E-mail: lzorica@yahoo.com [Institute of Physics, University of Belgrade, Pregrevica 118, Zemun, Belgrade (Serbia); Jovaleki?, ?. [Institute for Multidisciplinary Research, University of Belgrade, Belgrade (Serbia); Kuryliszyn-Kudelska, I. [Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warsaw (Poland); Rom?evi?, M.; Kosti?, S.; Rom?evi?, N. [Institute of Physics, University of Belgrade, Pregrevica 118, Zemun, Belgrade (Serbia)

2013-11-15T23:59:59.000Z

176

Cation-Bonding and Protonation of the Fe[subscript 4]-Square Cluster  

SciTech Connect (OSTI)

The synthesis and characterization of discrete, molecular iron-oxo clusters is pursued in the interest of molecular magnets, bioinspired materials and models for the geochemical aqueous-mineral interface. Iron-oxo clusters are challenging to synthesize in water, due to the extremely acidic and reactive nature of dissolved iron species, and thus require chelating ligands to passivate and neutralize the cluster surface. The 2-hydroxy-1,3-N,N,N',N'-diamino-propanetetraacetic acid (HPDTA) ligand has been used to isolate several Al and Fe cluster geometries, including the square clusters Fe{sub 4}(HPDTA){sub 2} and Al{sub 4}(HPDTA){sub 2}. While prior reports on the Fe{sub 4}(HPDTA){sub 2} cluster have focused on the magnetic properties, no solution characterization has been carried out. Using electrospray ionization mass-spectrometry (ESI-MS) we show this anionic Fe{sub 4}(HPDTA){sub 2} cluster can be dissolved intact in water, and recrystallized with virtually any metal as a countercation. The bonding of the metal cation to the square face of the cluster trends with ionic radii of the cations, as shown by structural characterization of Fe{sub 4}(HPDTA){sub 2} with Li{sup +}, Na{sup +}, Cs{sup +}, Mg{sup 2+}, Ba{sup 2+}, La{sup 3+}, Eu{sup 3+}, and Zn{sup 2+}. This trend is similar to that observed for association of cations on metal oxide surfaces in the environment. Furthermore, protonation of the bridging oxo ligands of this series of Fe{sub 4}(HPDTA){sub 2} clusters is variable (0, 1, or 2 protons), and structures as a function of protonation is discussed. This paper, largely structural in nature, sets the foundation for future aqueous phase studies of iron-oxo molecular clusters as models for the oxide-water interface in the natural aqueous environment.

Hou, Yu; Rodriguez, Mark A.; Nyman, May (Sandia)

2012-04-30T23:59:59.000Z

177

Retention of anhydrous ammonia as influenced by clay mineral types, cations, temperature and moisture  

E-Print Network [OSTI]

to various temperature levels . . . . . ~ 20 5a 6. 70 Ammoni. a retained sxuressed as psr cent of cation-exchange capacity for olays treated with anhydrous ammonia prior to heating to various temperature levels . ~. . . . . . ~ ~ . 21 Ammonia retained... encountered in the use of anhydrous ammoni. . . REVIEW OF LITER4TURE Some of the early work with anhydx ous ammonia was done by anderson, et al. (2), and Enderson and Eattson (3). St that t1ms anhydrous ammonia as sn inorganic source of nitrogen fertiliaer...

McBee, George G

1956-01-01T23:59:59.000Z

178

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wongchang

2014-05-13T23:59:59.000Z

179

Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph  

E-Print Network [OSTI]

, provisions were made for collecting samples of any gas produced. The irradiated resin was exposed to total 7 8 8 accumulations of 1. 0129X10 , 1. 0215XIO , and 5. 0168X10 Rads in three separate runs. It should be noted that the same amount of demineral.... (December 1977) Albert Antonio Freitag, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. James 8. Smathers Amberlite 200 cation exchange resin was irradiated by gamma 7 8 radiation to doses of 10 to 5X10 Rads. Results of the analysis...

Freitag, Albert Antonio

1977-01-01T23:59:59.000Z

180

Diffusion of cations in chromia layers grown on iron-base alloys  

SciTech Connect (OSTI)

Diffusion of the cations Cr, Fe, Mn, and Ni in Cr{sub 2}O{sub 3} has been investigated at 1,173 K. The diffusion measurements were performed on chromia layers grown on the model alloys Fe-20Cr and Fe-20Cr-12Ni in order to consider effects of small amounts of dissolved alien cations in Cr{sub 2}O{sub 3}. The samples were diffusion annealed in H{sub 2}-H{sub 2}O at an oxygen partial pressure close to the Cr{sub 2}O{sub 3}/Cr equilibrium. For all tracers the lattice-diffusion coefficients are 3-5 orders of magnitude smaller than the grain-boundary diffusion coefficients. The lattice diffusivity of Mn is about two orders of magnitude greater than the other lattice-diffusion coefficients, especially in Cr{sub 2}O{sub 3} grown on Fe-20Cr-12Ni. The values of the diffusion coefficients for Cr, Fe, and Ni are in the same range. Diffusion of the tracers in Cr{sub 2}O{sub 3} grown on different alloys did not show significant differences with the exception of Mn.

Lobnig, R.E.; Hennesen, K.; Grabke, H.J. (Max-Planck Inst. fur Eisenforschung, Duesseldorf (West Germany)); Schmidt, H.P.

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Modeling cation diffusion in compacted water-saturatedNa-bentonite at low ionic strength  

SciTech Connect (OSTI)

Sodium bentonites are used as barrier materials for the isolation of landfills and are under consideration for a similar use in the subsurface storage of high-level radioactive waste. The performance of these barriers is determined in large part by molecular diffusion in the bentonite pore space. We tested two current models of cation diffusion in bentonite against experimental data on the relative apparent diffusion coefficients of two representative cations, sodium and strontium. On the 'macropore/nanopore' model, solute molecules are divided into two categories, with unequal pore-scale diffusion coefficients, based on location: in macropores or in interlayer nanopores. On the 'surface diffusion' model, solute molecules are divided into categories based on chemical speciation: dissolved or adsorbed. The macropore/nanopore model agrees with all experimental data at partial montmorillonite dry densities ranging from 0.2 (a dilute bentonite gel) to 1.7 kg dm{sup -3} (a highly compacted bentonite with most of its pore space located in interlayer nanopores), whereas the surface diffusion model fails at partial montmorillonite dry densities greater than about 1.2 kg dm{sup -3}.

Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

2007-08-28T23:59:59.000Z

182

An infrared spectroscopy study of carbon monoxide adsorption on. alpha. -chromia surfaces: Probing oxidation states of coordinatively unsaturated surface cations  

SciTech Connect (OSTI)

CO adsorption on thermoevacuated, H{sub 2}-reduced and O{sub 2}-treated {alpha}-chromia surfaces was studied by IR spectroscopy in the temperature range 77-298 K. Coordinatively unsaturated (cus) Cr{sup 3+} cation sites, probably in 3-coordinate and to a much lesser extent 5-coordinate states, are the adsorption sites on H{sub 2}-reduced {alpha}-Cr{sub 2}O{sub 3}. The surface containing excess oxygen also exposes cus Cr{sup 4+} and Cr{sup 5+} sites. An empirical procedure is described which permits the determination of oxidation state and coordination number of the cus surface sites. This procedure is based on a correlation between C-O stretching frequency and electric field strength exerted by the cation. The latter is calculated from Pauling's strength of the electrostatic bond and effective ionic radii, both of which take the cation coordination into account.

Zaki, M.I.; Knoezinger, H. (Universitaet Muenchen (West Germany))

1989-10-01T23:59:59.000Z

183

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wonchang

2010-05-18T23:59:59.000Z

184

Phenolic cation-exchange resin material for recovery of cesium and strontium. [Patent application  

DOE Patents [OSTI]

A phenolic cation exchange resin with a chelating group has been prepared by reacting resorcinol with iminodiacetic acid in the presence of formaldehyde at a molar ratio of about 1:1:6. The material is highly selective for the simultaneous recovery of both cesium and strontium from aqueous alkaline solutions, such as, aqueous alkaline nuclear wate solutions. The organic resins are condensation polymers of resorcinol and formaldehyde with attached chelating groups. The column performance of the resins compares favorably with that of commercially available resins for either cesium or strontium removal. By combining Cs/sup +/ and Sr/sup 2 +/ removal in the same bed, the resins allow significant reduction of the size and complexity of facilities for processing nuclear waste.

Ebra, M.A.; Wallace, R.M.

1982-05-05T23:59:59.000Z

185

Phenolic cation exchange resin material for recovery of cesium and strontium  

DOE Patents [OSTI]

A phenolic cation exchange resin with a chelating group has been prepared by reacting resorcinol with iminodiacetic acid in the presence of formaldehyde at a molar ratio of about 1:1:6. The material is highly selective for the simultaneous recovery of both cesium and strontium from aqueous alkaline solutions, such as, aqueous alkaline nuclear waste solutions. The organic resins are condensation polymers of resorcinol and formaldehyde with attached chelating groups. The column performance of the resins compares favorably with that of commercially available resins for either cesium or strontium removal. By combining Cs.sup.+ and Sr.sup.2+ removal in the same bed, the resins allow significant reduction of the size and complexity of facilities for processing nuclear waste.

Ebra, Martha A. (Aiken, SC); Wallace, Richard M. (Aiken, SC)

1983-01-01T23:59:59.000Z

186

Cationic quaternization of cellulose with methacryloyloxy ethyl trimethyl ammonium chloride via ATRP method  

SciTech Connect (OSTI)

The synthesis of a cationic cellulose copolymer from cellulose macro-initiator (MCC-BiB) and quaternary compound monomer (METMA) via atom transfer radical polymerization (ATRP) was studied. By using dimethylformamide (DMF), the optimum condition for successful synthesis was at the mole ratio of MCC-BIB:Catalyst:METMA = 1:1:26. The highest copolymer recovery was 93.2 % for 6 h and at 40°C. The copolymer was insoluble in weak polar solvents such as THF and DMF but soluble in methanol and water. The chemistry of cellulose copolymer was confirmed by the FTIR and TGA in which the METMA monomer was used as a reference. The absence of CC bond in the CiB-g-METMA spectrum indicated that graft copolymerization occurred.

Supeno [Cenderawasih University, Jayapura, Papua, Indonesia and School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Daik, Rusli, E-mail: rusli@ukm.edu.my [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); El-Sheikh, Said M. [Nano-Structured Materials Division, Advanced Materials Department, Central Metallurgical Research and Development Institute, Cairo (Egypt)

2014-09-03T23:59:59.000Z

187

Cation self-diffusion in Fe/sub 2/O/sub 3/  

SciTech Connect (OSTI)

Self-diffusion of /sup 59/Fe in single crystals of Fe/sub 2/O/sub 3/ parallel to the c-axis has been measured as a function of temperature (1150 to 1340/sup 0/C) and oxygen partial pressure (2 x 10/sup -3/) less than or equal to Po/sub 2/ less than or equal to 1 atm). The oxygen partial pressure dependence of the diffusivity indicates that cation self-diffusion occurs by an interstitial-type mechanism. The simultaneous diffusion of /sup 52/Fe and /sup 59/Fe has been measured in Fe/sub 2/O/sub 3/ at 1251/sup 0/C and Po/sub 2/ = 1.91 x 10/sup -2/ atm. The small value of the isotope effect (f..delta..K = 0.067 +- 0.016) is consistent with diffusion of Fe ions by an interstitially mechanism.

Hoshino, K.; Peterson, N.L.

1984-01-01T23:59:59.000Z

188

Optical and electronic properties of mixed Ag-Au tetramer cations  

SciTech Connect (OSTI)

We present experimental and theoretical studies of the optical response of mixed Ag {sub n} Au {sub 4?n}{sup +} (n=1–3) clusters in the photon energy range ?? = 1.9–3.5 eV. Absorption spectra are recorded by a newly built longitudinal molecular beam depletion spectroscopy apparatus providing lower limits to absolute photodissociation cross sections. The experimental data are compared to optical response calculations in the framework of long-range corrected time-dependent density functional theory with initial cluster geometries obtained by the unbiased Birmingham Cluster Genetic Algorithm coupled with density functional theory. Experiments and excited state calculations shed light on the structural and electronic properties of the mixed Ag-Au tetramer cations.

Shayeghi, A., E-mail: shayeghi@cluster.pc.chemie.tu-darmstadt.de; Schäfer, R. [Eduard-Zintl-Institut, Technische Universität Darmstadt, Alarich-Weiss-Straße 8, 64287 Darmstadt (Germany)] [Eduard-Zintl-Institut, Technische Universität Darmstadt, Alarich-Weiss-Straße 8, 64287 Darmstadt (Germany); Heard, C. J.; Johnston, R. L. [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)] [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

2014-02-07T23:59:59.000Z

189

Ion-exchange selectivities of periderm and cuticular membranes toward alkali cations  

SciTech Connect (OSTI)

The ion-exchange selectivities of lithium, sodium, potassium, and cesium on isolated potato periderm (Solanum tuberosum) and pear fruit cuticular membranes were investigated; the general order of preference both for cation selectivities and ion-exchange capacities was lithium > sodium > potassium > cesium. The potato periderm and pear fruit cuticular membranes exhibited a behavior typical of ion-exchange resins of the weak acid type. At constant pH 7, the ion-exchange capacities of periderm and cuticular membranes increased with hydrated ionic radius, and also with increasing pH and neutral salt concentration, and decreased with crystal ionic radius. Counterion selectivities also exhibited the same behavior. The ion-exchange properties are discussed in terms of the structure and function of potato periderm and pear fruit cuticular membranes.

Ersoz, M. [Univ. of Selcuk, Konya (Turkey); Duncan, H.J. [Univ. of Glasgow, Scotland (United Kingdom)

1994-08-01T23:59:59.000Z

190

Self-Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity  

SciTech Connect (OSTI)

Six hexanuclear clusters of 4f and 5f elements were synthesized by room-temperature slow concentration experiments. Cerium(IV), thorium(IV), and plutonium(IV) each form two different hexanuclear clusters, among which the cerium and plutonium clusters are isotypic, whereas the thorium clusters show more diversity. The change in ionic radii of approximately 0.08 Å between these different metal ions tunes the cavity size so that NH{sub 4}{sup +} (1.48 Å) has the right dimensions to assemble the cerium and plutonium clusters, whereas Cs{sup +} (1.69 Å) is necessary to assemble the thorium clusters. If these cations are not used in the reactions, only amorphous material is obtained.

Diwu, J.; Good, Justin J.; DiStefano, Victoria H.; Albrecht-Schmitt, Thomas E.

2011-01-01T23:59:59.000Z

191

Influence of relaxation transitions on radiation-initiated cationic graft polymerization. [Gamma radiation  

SciTech Connect (OSTI)

Radiation grafting of vinyl n-butyl ether (VBE) to polyvinyl chloride (PVC) over a broad temperature range was investigated. The relaxation transitions in the PVC/VBE system were also determined. Grafting of vinyl alkyl ethers proceeds entirely by a cationic mechanism in a reaction medium that has been dried to a water concentration no greater than 0.1-1.0 ppm. In this connection, the diffusion properties of water in the temperature region were studied. Commercial films of unplasticized PVC (thickness 200 M); were subjected to swelling in two systems: in a 50% solution of VBE in benzene at 25/sup 0/C, and in the pure monomer at 40/sup 0/C. The reaction mixtures were first dried over metallic sodium in a deaerated atmosphere. The specimens were irradiated in a Co gamma-radiation unit to a dose of 10 kGy at a dose rate of 3 Gy/sec. The first reaction mixture was investigated over a range of temperatures from -60/sup 0/ to +70/sup 0/C, and the second from -15/sup 0/ to +50/sup 0/C. The degree of grafting was determined from the increase in weight of the original ungrafted film. The temperature was held to within +/-1/sup 0/C. The relaxation transitions in the swollen polymer systems were determined by two methods, thermostimulated current (TSC) and thermomechanics (TM). It was found that in the region of the glass transition of a swollen PVC-VBE system, radiation-initiated cationic graft polymerization proceeds at a maximal rate, and there are changes in state of the water molecules (the agents of breaking the ion reaction chain) and in their diffusion properties within the matrix.

Kudryavtsev, V.N.; Kabanov, V.Ya.; Chalykh, A.E.; Spitsyn, V.I.

1982-05-01T23:59:59.000Z

192

Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R. Krueger, S. Vyas,a  

E-Print Network [OSTI]

Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R The nuclear magnetic resonance NMR spectra for the I=3/2 23 Na cation dissolved into filamentous bacteriophage the 23 Na nuclear quadrupole moment and the electric field gradient produced by the negatively charged Pf

Augustine, Mathew P.

193

JOURNAL DE PHYSIQUE Colloque C1, suppliment au no 4, Tome 38, Avril 1977, page C1-207 KINETICS OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES  

E-Print Network [OSTI]

OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES V. A. M. BRABERS and J. KLERK Department of Physics distribution des ions Mg2+et Fe3+sur les sites tetrakdriques et octakdriquesde ferrites de magnesium est Ctudi properties of ferrites. The cation distribution in magnesium ferrite has been studied by various authors

Boyer, Edmond

194

Mechanism of Cation Exchange Process for Epitaxy of Superconducting HgBa2CaCu2O6 Films and Passive Microwave Devices  

E-Print Network [OSTI]

cations into, the lattice of epitaxial Tl2Ba2CaCu2O8 (Tl-2212) or TlBa2CaCu2O7 (Tl-1212) precursor films. Aiming at the remained issues in understanding the mechanism of the cation exchange (CE) process, this thesis work has studied the reversibility of CE...

Zhao, Hua

2007-12-17T23:59:59.000Z

195

Element-and site-specific oxidation state and cation distribution in manganese ferrite films by diffraction anomalous fine structure  

E-Print Network [OSTI]

Element- and site-specific oxidation state and cation distribution in manganese ferrite films Received 2 April 2008; accepted 9 July 2008; published online 8 August 2008 Epitaxial manganese ferrite.1063/1.2969406 Spinel ferrites represent an important class of materials that provide high permeability, moderate

Haskel, Daniel

196

Changes in Sea-Level associated with Modi cations of the Mass Balance of the Greenland and Antarctic  

E-Print Network [OSTI]

Changes in Sea-Level associated with Modi cations of the Mass Balance of the Greenland and Antarctic Ice Sheets over the 21st Century V eronique Bugnion Abstract Changes in runo from Greenland for estimating melting and runo . All models are solved on 20 and 40 km grids respectively for Greenland

197

Heating-Induced Micelle to Vesicle Transition in the Cationic-Anionic Surfactant Systems: Comprehensive Study and Understanding  

E-Print Network [OSTI]

Heating-Induced Micelle to Vesicle Transition in the Cationic-Anionic Surfactant Systems, 2004; In Final Form: January 6, 2005 Heating-induced micelle to vesicle transition (MVT), which has classes: Class A and B. Heating-induced MVT was observed in Class A at certain total surfactant

Huang, Jianbin

198

An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao*  

E-Print Network [OSTI]

An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao the performance of anion exchange membrane (AEM) direct ethanol fuel cells (DEFCs) is that state-of-the-art AEMs exchange membrane direct ethanol fuel cells (AEM- DEFCs) have received ever-increasing attention, mainly

Zhao, Tianshou

199

Nuevos materiales basados en cationes alcalinotrreos, reutilizables y de muy bajo coste con un elevado poder cataltico y de sorcin  

E-Print Network [OSTI]

. Estos materiales, que respetan el medio ambiente, de bajo costo, fácil fabricación y estabilidad térmica ambiente. La alta acidez Lewis de los cationes alcalinotérreos proporciona a los catalizadores sitios muy actualmente a nivel industrial (compuestos de metales preciosos) · son reutilizables · tienen un menor impacto

200

Computational study of the energetics of charge and cation mixing in U1-xCexO?  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The formalism of electronic density-functional theory (DFT), with Hubbard-U corrections (DFT+U), is employed in a computational study of the energetics of fluorite-structured U1-xCexO? mixtures. The computational approach makes use of a procedure which facilitates convergence of the calculations to multiple self-consistent DFT+U solutions for a given cation arrangement, corresponding to different charge states for the U and Ce ions in several prototypical cation arrangements. Results indicate a significant dependence of the structural and energetic properties on the nature of both charge and cation ordering. With the effective Hubbard-U parameters that reproduce well the measured oxidation-reduction energies for urania and ceria, we find that charge transfer between U?? and Ce?? ions, leading to the formation of U?? and Ce³?, gives rise to an increase in the mixing energy in the range of 4–14 kJ/mol of the formula unit, depending on the nature of the cation ordering. The results suggest that although charge transfer between uranium and cerium ions is disfavored energetically, it is likely to be entropically stabilized at the high temperatures relevant to the processing and service of urania-based solid solutions.

Hanken, B. E.; Stanek, C. R.; Grønbech-Jensen, N.; Asta, M.

2011-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Atomistic Studies of Cation Transport in Tetragonal ZrO2 During Zirconium Corrosion  

SciTech Connect (OSTI)

Zirconium alloys are the major fuel cladding materials in current reactors. The water-side corrosion is one of the major degradation mechanisms of these alloys. During corrosion the transport of oxidizing species in zirconium dioxide (ZrO2) determines the corrosion kinetics. Previously it has been argued that the outward diffusion of cation ions is important for forming protective oxides. In this work, the migration of Zr defects in tetragonal ZrO2 is studied with temperature accelerated dynamics and molecular dynamics simulations. The results show that Zr interstitials have anisotropic diffusion and migrate preferentially along the [001] or c direction in tetragonal ZrO2. The compressive stresses can increase the Zr interstitial migration barrier significantly. The migration barriers of some defect clusters can be much lower than those of point defects. The migration of Zr interstitials at some special grain boundaries is much slower than in a bulk oxide. The implications of these atomistic simulation results in the Zr corrosion are discussed.

Xian-Ming Bai; Yongfeng Zhang; Michael R. Tonks

2013-10-01T23:59:59.000Z

202

Energy/structure database of all proteinogenic amino acids and dipeptides without and with divalent cations  

E-Print Network [OSTI]

We present a structural data set of the 20 proteinogenic amino acids and their amino-methylated and acetylated (capped) dipeptides. Different protonation states of the backbone (uncharged and zwitterionic) were considered for the amino acids as well as varied side chain protonation states. Furthermore, we studied amino acids and dipeptides in complex with divalent cations (Ca2+, Ba2+, Sr2+, Cd2+, Pb2+, and Hg2+). The database covers the conformational hierarchies of 280 systems in a wide relative energy range of up to 4 eV (390 kJ/mol), summing up to an overall of 45,892 stationary points on the respective potential-energy surfaces. All systems were calculated on equal first-principles footing, applying density-functional theory in the generalized gradient approximation corrected for long-range van der Waals interactions. We show good agreement to available experimental data for gas-phase ion affinities. Our curated data can be utilized, for example, for a wide comparison across chemical space of the building...

Ropo, Matti; Blum, Volker

2015-01-01T23:59:59.000Z

203

Millisecond Kinetics of Nanocrystal Cation Exchange UsingMicrofluidic X-ray Absorption Spectroscopy  

SciTech Connect (OSTI)

We describe the use of a flow-focusing microfluidic reactorto measure the kinetics of theCdSe-to-Ag2Se nanocrystal cation exchangereaction using micro-X-ray absorption spectroscopy (mu XAS). The smallmicroreactor dimensions facilitate the millisecond mixing of CdSenanocrystal and Ag+ reactant solutions, and the transposition of thereaction time onto spatial coordinates enables the in situ observation ofthe millisecond reaction with mu XAS. XAS spectra show the progression ofCdSe nanocrystals to Ag2Se over the course of 100 ms without the presenceof long-lived intermediates. These results, along with supporting stoppedflow absorption experiments, suggest that this nanocrystal cationexchange reaction is highly efficient and provide insight into how thereaction progresses in individual particles. This experiment illustratesthe value and potential of in situ microfluidic X-ray synchrotrontechniques for detailed studies of the millisecond structuraltransformations of nanoparticles and other solution-phase reactions inwhich diffusive mixing initiates changes in local bond structures oroxidation states.

Chan, Emory M.; Marcus, Matthew A.; Fakra, Sirine; Elnaggar,Mariam S.; Mathies, Richard A.; Alivisatos, A. Paul

2007-05-07T23:59:59.000Z

204

Synthesis and chemistry of cationic d sup 0 metal alkyl complexes  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-01-01T23:59:59.000Z

205

Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water  

SciTech Connect (OSTI)

Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

B. Widman

2003-01-01T23:59:59.000Z

206

CATIONIC SHELL CROSSLINKED NANOPARTICLES AS INTRACELLULAR DELIVERY VEHICLES FOR THE DIAGNOSIS AND TREATMENT OF ACUTE LUNG INJURY  

E-Print Network [OSTI]

started in my organic chemistry classroom, as I watched Dr. David Bergbreiter talk about this intriguing subject. I would like to thank him for he was always there helping his students and encouraging us to think beyond the books. Dr. Bergbreiter... CATIONIC SHELL CROSSLINKED NANOPARTICLES AS INTRACELLULAR DELIVERY VEHICLES FOR THE DIAGNOSIS AND TREATMENT OF ACUTE LUNG INJURY Majors: Chemistry Biomedical Science April 2011 Submitted...

Florez, Stephanie

2011-08-08T23:59:59.000Z

207

Synthesis of magnetite-porphyrin nanocomposite and its application as a novel magnetic adsorbent for removing heavy cations  

SciTech Connect (OSTI)

Graphical abstract: Magnetite-porphyrin nanocomposite (MPNC) as a novel magnetic adsorbent for removing heavy cations was synthesized. - Highlights: • Nanosized Fe{sub 3}O{sub 4} was prepared by hydrothermal reaction of iron salt in alkaline media. • The synthesized magnetite and nanocomposite had soft ferromagnetic property. • Magnetic nanocomposite as a novel magnetic adsorbent for heavy cations was prepared. • Satisfactory separation from solutions in the order of Pb{sup 2+} > Cd{sup 2+} > Hg{sup 2+} was obtained. - Abstract: Magnetite-porphyrin nanocomposite (MPNC) was synthesized as a novel magnetic adsorbent for removing heavy cations. Firstly, we prepared nano-sized magnetite using a simple hydrothermal route. The synthesis of nanoscaled magnetite was carried out through reaction between iron source and various amines. In this paper, we studied effective parameters in controlling shape and size of nanoscaled magnetite. These parameters were presence of alkaline, reaction time, kind of amine and iron salt. Morphology, particle size and magnetic properties of the nanoscaled magnetite were obtained by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier transform infrared (FT-IR), diffuse reflectance spectra (DRS) and vibrating sample magnetometer (VSM). Our study showed that the synthesized magnetite from reaction between FeSO{sub 4} and hydrazinum hydrate has spherical shape. The synthesized magnetite was a nanosized compound and used for preparation of magnetite-porphyrin nanocomposite. The synthesized magnetite-porphyrin hybrid material had magnetic property and was used as magnetic adsorbent for removing heavy cations of water. Satisfactory separation from solutions in the order of Pb{sup 2+} > Cd{sup 2+} > Hg{sup 2+} was obtained.

Bakhshayesh, Sara, E-mail: s_bakhshayesh@yahoo.com; Dehghani, Hossein, E-mail: dehghani@kashanu.ac.ir

2013-07-15T23:59:59.000Z

208

G en eralisation de th eor emes inductifs pour la v eri cation d'architectures r eguli eres  

E-Print Network [OSTI]

G#19;en#19;eralisation de th#19;eor#18;emes inductifs pour la v#19;eri#12;cation d'architectures r, preuve qui n#19;e- cessite fr#19;equemment une phase de g#19;en#19;eralisation de th#19;eor#18;emes. Nous proposons une m#19;ethode de g#19;en#19;eralisation qui permet de produire le th#19;eor#18;eme g#19;en#19

Pierre, Laurence

209

Novel localization of OCTN1, an organic cation/carnitine transporter, to mammalian mitochondria  

SciTech Connect (OSTI)

Carnitine is a zwitterion essential for the {beta}-oxidation of fatty acids. We report novel localization of the organic cation/carnitine transporter, OCTN1, to mitochondria. We made GFP- and RFP-human OCTN1 cDNA constructs and showed expression of hOCTN1 in several transfected mammalian cell lines. Immunostaining of GFP-hOCTN1 transfected cells with different intracellular markers and confocal fluorescent microscopy demonstrated mitochondrial expression of OCTN1. There was striking co-localization of an RFP-hOCTN1 fusion protein and a mitochondrial-GFP marker construct in transfected MEF-3T3 and no co-localization of GFP-hOCTN1 in transfected human skin fibroblasts with other intracellular markers. L-[{sup 3}H]Carnitine uptake in freshly isolated mitochondria of GFP-hOCTN1 transfected HepG2 demonstrated a K {sub m} of 422 {mu}M and Western blot with an anti-GFP antibody identified the expected GFP-hOCTN1 fusion protein (90 kDa). We showed endogenous expression of native OCTN1 in HepG2 mitochondria with anti-GST-hOCTN1 antibody. Further, we definitively confirmed intact L-[{sup 3}H]carnitine uptake (K {sub m} 1324 {mu}M), solely attributable to OCTN1, in isolated mitochondria of mutant human skin fibroblasts having <1% of carnitine acylcarnitine translocase activity (alternate mitochondrial carnitine transporter). This mitochondrial localization was confirmed by TEM of murine heart incubated with highly specific rabbit anti-GST-hOCTN1 antibody and immunogold labeled goat anti-rabbit antibody. This suggests an important yet different role for OCTN1 from other OCTN family members in intracellular carnitine homeostasis.

Lamhonwah, Anne-Marie [Division of Neurology, Department of Pediatrics, Hospital for Sick Children and Department of Laboratory Medicine and Pathobiology, University of Toronto, Toronto, Ont., M5G 1X8 (Canada); Tein, Ingrid [Division of Neurology, Department of Pediatrics, Hospital for Sick Children and Department of Laboratory Medicine and Pathobiology, University of Toronto, Toronto, Ont., M5G 1X8 (Canada)]. E-mail: ingrid.tein@sickkids.ca

2006-07-14T23:59:59.000Z

210

Rovibronically selected and resolved two-color laser photoionization and photoelectron study of nickel carbide cation  

SciTech Connect (OSTI)

We have performed a two-color laser photoionization and photoelectron study of nickel carbide (NiC) and its cation (NiC{sup +}). By preparing NiC in a single rovibronic level of an intermediate vibronic state via visible laser excitation prior to ultraviolet laser photoionization, we have measured the photoionization efficiency spectrum of NiC near its ionization threshold, covering the formation of NiC{sup +}(X {sup 2}{Sigma}{sup +};v{sup +}=0-3). We have also obtained well-resolved rotational transitions for the v{sup +}=0 and 1 vibrational bands of the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The assignment of rotational transitions observed between the neutral NiC intermediate state and the NiC{sup +} ion ground state has allowed the direct determination of a highly precise value for the ionization energy of NiC, IE(NiC)=67 525.1{+-}0.5 cm{sup -1} (8.372 05{+-}0.000 06 eV). This experiment also provides reliable values for the vibrational spacing [{Delta}G(1/2)=859.5{+-}0.5 cm{sup -1}], rotational constants (B{sub e}{sup +}=0.6395{+-}0.0018 cm{sup -1} and {alpha}{sub e}{sup +}=0.0097{+-}0.0009 cm{sup -1}), and equilibrium bond distance (r{sub e}{sup +}=1.628 A) for the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The experimental results presented here are valuable for benchmarking the development of more reliable ab initio quantum computation procedures for energetic and spectroscopic calculations of transition metal-containing molecules.

Chang, Yih Chung [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China); Shi Xiaoyu; Ng, C. Y. [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Lau, Kai-Chung [Department of Biology and Chemistry, City University of Hong Kong, Kowloon (Hong Kong); Yin Qingzhu [Department of Geology, University of California, Davis, Davis, California 95616 (United States); Liou, H. T. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China)

2010-08-07T23:59:59.000Z

211

Problems of trace element ratios and geothermometry in a gravel geothermal-aquifer system  

SciTech Connect (OSTI)

A Tertiary-age, block-faulted basin in which a Pleistocene gravel bed acts as a confined aquifer and permits the lateral dispersion of the geothermal fluids is studied. Basic data on geology and trace element holes presented previously are reproduced along with fluoride data. Evaluation of the phenomena in this system was attempted using a dissolved silica-enthalpy graph. A chalcedomy curve is also plotted. An enthalpy versus chloride plot suggests that either conductive cooling occurs before mixing or that higher chloride content background waters are available for mixing. (MHR)

Sonderegger, J.L.; Donovan, J.J.; Ruscetta, C.A.; Foley, D. (eds.)

1981-05-01T23:59:59.000Z

212

Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain, Idaho using Multicomponent Geothermometry  

SciTech Connect (OSTI)

The U.S. Geological survey has estimated that there are up to 4,900 MWe of undiscovered geothermal resources and 92,000 MWe of enhanced geothermal potential within the state of Idaho. Of particular interest are the resources of the Eastern Snake River Plain (ESRP) which was formed by volcanic activity associated with the relative movement of the Yellowstone Hot Spot across the state of Idaho. This region is characterized by a high geothermal gradient and thermal springs occurring along the margins of the ESRP. Masking much of the deep thermal potential of the ESRP is a regionally extensive and productive cold-water aquifer. We have undertaken a study to infer the temperature of the geothermal system hidden beneath the cold-water aquifer of the ESRP. Our approach is to estimate reservoir temperatures from measured water compositions using an inverse modeling technique (RTEst) that calculates the temperature at which multiple minerals are simultaneously at equilibrium while explicitly accounting for the possible loss of volatile constituents (e.g., CO2), boiling and/or water mixing. In the initial stages of this study, we apply the RTEst model to water compositions measured from a limited number of wells and thermal springs to estimate the regionally extensive geothermal system in the ESRP.

Ghanashyam Neupane; Earl D. Mattson; Travis L. McLing; Carl D. Palmer; Robert W. Smith; Thomas R. Wood

2014-02-01T23:59:59.000Z

213

Geothermometry At Clear Lake Area (Thompson, Et Al., 1992) | Open Energy  

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214

Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) | Open  

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215

Geothermometry At Fish Lake Valley Area (DOE GTP) | Open Energy Information  

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216

Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open  

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217

Geothermometry At Long Valley Caldera Geothermal Area (McKenzie &  

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218

Geothermometry At Long Valley Caldera Geothermal Area (Sorey, Et Al., 1991)  

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219

Geothermometry At Mt St Helens Area (Shevenell & Goff, 1995) | Open Energy  

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220

Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004)  

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221

Geothermometry At Northern Basin & Range Region (Cole, 1983) | Open Energy  

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222

Geothermometry At Northern Basin & Range Region (Laney, 2005) | Open Energy  

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223

Geothermometry At Nw Basin & Range Region (Laney, 2005) | Open Energy  

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224

Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher, 2005) |  

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225

Geothermometry At Reese River Area (Henkle & Ronne, 2008) | Open Energy  

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226

Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation|Open1978) |

227

Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005) | Open Energy  

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228

Geothermometry At Teels Marsh Area (Coolbaugh, Et Al., 2006) | Open Energy  

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229

Geothermometry At Teels Marsh Area (Shevenell, Et Al., 2008) | Open Energy  

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230

Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) | Open Energy  

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231

Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell, 2006) |  

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232

Geothermometry At Walker-Lane Transitional Zone Region (Laney, 2005) | Open  

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233

Geothermometry At Walker-Lane Transitional Zone Region (Shevenell & De  

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234

Geothermometry At Desert Queen Area (Garchar & Arehart, 2008) | Open Energy  

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235

Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl, Et Al.,  

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236

Geothermometry At Neal Hot Springs Geothermal Area (U.S. Geothermal Inc.,  

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237

Geothermometry At Rhodes Marsh Area (Coolbaugh, Et Al., 2006) | Open Energy  

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238

Geothermometry At Rhodes Marsh Area (Shevenell, Et Al., 2008) | Open Energy  

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239

Geothermometry At Salt Wells Area (Coolbaugh, Et Al., 2006) | Open Energy  

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240

Geothermometry At Salt Wells Area (Edmiston & Benoit, 1984) | Open Energy  

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Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

New iodocuprates(I) with N-heterocyclic molecules as the cations  

SciTech Connect (OSTI)

Under the hydrothermal conditions, the reactions between CuI, KI and bp/bpp (bp=4,4?-bipiperidine, bpp=1,3-bis(4-piperidyl)propane) in an acidic alcohol solution produced three new organically templated iodocuprates(I) as [H{sub 2}bp]{sub 2}[Cu{sub 2}I{sub 6}] 1, [tmbp][Cu{sub 2}I{sub 4}] 2 and [tmbpp] 2 [Cu{sub 4}I{sub 8}]·2H{sub 2}O 3 (tmbp{sup 2+}=N,N,N?,N?-tetramethyl-4,4?-bipiperidinium; tmbpp{sup 2+}=N,N,N?,N?-tetramethyl-1,3-bis(4-piperidyl)propane dication). X-ray analysis revealed that (i) tmbp{sup 2+} and tmbpp{sup 2+} in compounds 2 and 3 originated from the complete N-alklation of bp/bpp with CH{sub 3}OH; (ii) templated by H{sub 2}bp{sup 2+}, the inorganic anion [Cu{sub 2}I{sub 6}]{sup 2?} of 1 possesses a dinuclear structure, whereas templated by tmbp{sup 2+}, the inorganic anion [Cu{sub 2}I{sub 4}]{sup 2?} of 2 exhibits a one-dimensional (1D) chain structure; (iii) templated by tmbpp{sup 2+}, the inorganic anion [Cu{sub 4}I{sub 8}]{sup 4?} of 3 shows a cubane-like structure modified by four terminal I{sup ?} ions. The photoluminescence analysis indicates that compounds 1 and 2 emit blue light, while compound 3 emits green light. - Graphical abstract: By employing hydrothermal in situ N-alkylation of bp/bpp with CH{sub 3}OH, three new organically templated iodocuprates(I) were obtained. Display Omitted - Highlights: • Three new organically templated iodocuprates(I) were reported. • Cations tmbp{sup 2+} and tmbpp{sup 2+} originated from in situ alkylation of bp/bpp with CH{sub 3}OH. • H{sup +} and I{sup ?} play a key role in alkylation of bp/bpp with CH{sub 3}OH. • Photoluminescence emission for iodocuprates(I) is related to Cu···Cu interaction.

Zhao, Jin-Jing [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Zhang, Xiao [State Key Lab of Urban Water Resource and Environment (SKLUWRE) and Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang 150080 (China); Wang, Yan-Ning; Jia, Hong-Li [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Yu, Jie-Hui, E-mail: jhyu@jlu.edu.cn [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Xu, Ji-Qing, E-mail: xjq@mail.jlu.edu.cn [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China)

2013-11-15T23:59:59.000Z

242

Gram-scale separation of curium from americium using alpha-hydroxyisobutyric acid in high-pressure cation columns  

SciTech Connect (OSTI)

Quantities of heavy element (americium and curium) up to 2.3 g have been successfully separated by chromatographic elution from cation resin using alpha-hydroxyisobutyrate in equipment originally designed for decigram-scale separations of /sup 252/Cf and heavier elements. The high-pressure ion exchange process was reliable and relatively easy to operate. Overall curium recoveries of 80 to 90% were readily achieved with decontamination from americium by factors of 400 to 500. The product and waste streams are both in forms readily coupled to further processing steps.

Bigelow, J.E.; Benker, D.E.; Chattin, F.R.; King, L.J.; Knauer, J.B.; Ross, R.G.; Stacy, R.G.; Wiggins, J.T.

1984-01-01T23:59:59.000Z

243

Influence of Heteroanion and Ammonium Cation Size on the Composition and Gas-Phase Fragmentation of Polyoxovanadates  

SciTech Connect (OSTI)

This paper describes the results of a systematic experimental investigation of the influence of different size cationic ammonium ligands and heteroanions on the composition, ionic charge state and gas-phase fragmentation pathways of anionic polyoxovanadates synthesized in solution. Four separate solutions of olyoxometalates (POMs) were prepared using all possible combinations of the tetraethylammonium [(C2H5)4N+] ligand, chloride (Cl-) heteroanion, tetrabutylammonium [(C4H9)4N+] ligand and acetate (CH3CO2-) heteroanion. Employing electrospray ionization combined with high-resolution mass spectrometry (ESI-MS) we demonstrate that POM solutions synthesized using the small [(C2H5)4N+] ligand and Cl-heteroanion are composed predominately of large doubly and triply charged chlorine containing clusters with a size distribution centered at fourteen vanadium atoms. POM solutions prepared using the Cl- anion and [(C4H9)4N+] ligand are shown to contain slightly larger clusters with fifteen and sixteen vanadium atoms, thereby indicating that the size of the cationic ammonium ligand exerts only a weak influence on the polymerization of polyoxovanadates. POM solutions prepared using (C2H5)4NCl and (C4H9)4NCl also produced peaks consistent with the attachment of one and two ammonium cations to the larger clusters. Solutions prepared using the large CH3CO2 - heteroanion, in contrast, are demonstrated to contain much smaller singly and doubly *Manuscript Click here to view linked References 2 charged clusters with a size distribution centered at six vanadium atoms. In addition, while incorporation of one and two ammonium ligands into the smaller clusters was observed, no POMs containing the CH3CO2 - heteroanion were identified. The gas-phase fragmentation pathways of representative POMs containing one and two ammonium ligands were examined using collision induced dissociation (CID) and mass spectrometry. Similar primary fragmentation pathways involving partial loss of a ligand -[(CxHy)3N+ x = 2,4; y = 5,9] were observed for clusters containing both one and two ligands largely independent of the size, composition and charge state of the precursor ion. The [(C4H9)4N+] ligand was found to exhibit stronger interactions with the core of the POMs resulting in higher abundances of fragment ions containing (C4H9) units compared to (C2H5) units from [(C2H5)4N+]. These results provide fundamental insight into the interactions between anionic metal oxide clusters, heteroanions and cationic ammonium ligands that are responsible for the size and composition controlled synthesis of POMs in solution.

Johnson, Grant E.; Al Hasan, Naila M.; Laskin, Julia

2013-11-15T23:59:59.000Z

244

Combined Quantum Chemical/Raman Spectroscopic Analyses of Li+ Cation Solvation: Cyclic Carbonate Solvents - Ethylene Carbonate and Propylene Earbonate  

SciTech Connect (OSTI)

Combined computational/Raman spectroscopic analyses of ethylene carbonate (EC) and propylene carbonate (PC) solvation interactions with lithium salts are reported. It is proposed that previously reported Raman analyses of (EC)n-LiX mixtures have utilized faulty assumptions. In the present studies, density functional theory (DFT) calculations have provided corrections in terms of both the scaling factors for the solvent's Raman band intensity variations and information about band overlap. By accounting for these factors, the solvation numbers obtained from two different EC solvent bands are in excellent agreement with one another. The same analysis for PC, however, was found to be quite challenging. Commercially available PC is a racemic mixture of (S)- and (R)-PC isomers. Based upon the quantum chemistry calculations, each of these solvent isomers may exist as multiple conformers due to a low energy barrier for ring inversion, making deconvolution of the Raman bands daunting and inherently prone to significant error. Thus, Raman spectroscopy is able to accurately determine the extent of the EC...Li+ cation solvation interactions using the provided methodology, but a similar analysis of PC...Li+ cation solvation results in a significant underestimation of the actual solvation numbers.

Allen, Joshua L.; Borodin, Oleg; Seo, D. M.; Henderson, Wesley A.

2014-12-01T23:59:59.000Z

245

Self-Assembly of Nanostructured, Complex, Multi-cation Films via Spontaneous Phase Separation and Strain-driven Ordering  

SciTech Connect (OSTI)

Spontaneous self-assembly of a multi-cation nanophase in another multi-cation matrix phase is a promising bottom-up approach to fabricate novel, nanocomposite structures for a range of applications. In an effort to understand the mechanisms for such self-assembly, we report on complimentary experimental and theoretical studies to first understand and then control or guide the self-assembly of insulating BaZrO3 (BZO) nanodots within REBa2Cu3O7- (RE=rare earth elements including Y, REBCO) superconducting films. It was determined that the strain field developed around BZO nanodots embedded in REBCO matrix is a key driving force dictating the self-assembly of BZO nanodots along REBCO c-axis. The size selection and spatial ordering of BZO self-assembly were simulated using thermodynamic and kinetic models. The BZO self-assembly was controllable by tuning the interphase strain field. REBCO superconducting films with BZO defects arrays self-assembled to align in both vertical (REBCO c-axis) and horizontal (REBCO ab-planes) directions, resulted in the maximized pinning and Jc performance for all field angles with smaller angular Jc anisotropy. The work has broad implications for fabrication of controlled self-assembled nanostructures for a range of applications via strain-tuning.

Goyal, Amit [ORNL; Wee, Sung Hun [ORNL; Stocks, George Malcolm [ORNL; Zuev, Yuri L [ORNL; More, Karren Leslie [ORNL; Meng, Jianyong [ORNL; Zhong, Jianxin [ORNL

2013-01-01T23:59:59.000Z

246

Effects of In{sub 3+} substitution on structural properties, cation distribution and Mössbauer spectra of CoFe{sub 2}O{sub 4} ferrite  

SciTech Connect (OSTI)

The use of non-destructive, high resolution technique namely Mössbauer spectroscopy is discussed in detail for the investigation of structural and magnetic properties of Fe based indium substituted cobalt ferrites. The polycrystalline samples of CoFe{sub 2?x}In{sub x}O{sub 4} (x = 0.2, 0.6) were prepared by double sintering solid state reaction method. To ensure a single phase formation of the as prepared samples the X-ray diffraction (XRD) data of the powdered samples was Rietveld refined using Fd3m space group. An excellent agreement is obtained between the integrated intensity ratios of 57 Fe spectra at A- and B-sites and those calculated on the basis of cation distribution the cation distribution obtained data analysis. The results of Mössbauer spectra and cation distribution are also correlated well with magnetization versus applied field (M-H) study.

Kumar, Ravi, E-mail: ranade65@gmail.com [Centre for Material Science and Engineering, National Institute of Technology Hamirpur (H.P.)-177005 (India); Pandit, Rabia; Sharma, K. K.; Kaur, Pawanpreet [Department of Physics, National Institute of Technology Hamirpur (H.P.)-177005 (India)

2014-04-24T23:59:59.000Z

247

UV-vis spectra of singlet state cationic polycyclic aromatic hydrocarbons: Time-dependent density functional theory study  

SciTech Connect (OSTI)

A theoretical study of singlet state cations of polycyclic aromatic hydrocarbons is performed. Appropriate symmetry suitable for further calculations is chosen for each of the systems studied. The excitation states of such species are obtained by the time dependent density functional theory (TD-DFT) method. The computations are performed using both Pople and electronic response properties basis sets. The results obtained with the use of different basis sets are compared. The electronic transitions are described and the relationships for the lowest-lying transitions states of different species are found. The properties of in-plane and out-of-plane transitions are also delineated. The TD-DFT results are compared with the experimental data available.

Dominikowska, Justyna, E-mail: justyna@uni.lodz.pl; Domagala, Malgorzata; Palusiak, Marcin [Department of Theoretical and Structural Chemistry, University of ?ód?, Pomorska 163/165, 90-236 ?ód? (Poland)] [Department of Theoretical and Structural Chemistry, University of ?ód?, Pomorska 163/165, 90-236 ?ód? (Poland)

2014-01-28T23:59:59.000Z

248

Veri cation of Embedded Reactive Fi o Systems Frdric Herbreteau 1,2 , Franck Cassez 1 , Alain Finkel 3 , Olivier Roux 1  

E-Print Network [OSTI]

in the Electre [8] reactive language. A major #12; 2 F. Herbreteau and al. feature of this languageVeri#28;cation of Embedded Reactive Fi#27;o Systems Frédéric Herbreteau 1,2 , Franck Cassez 1 ERL, 253 Cory Hall, University of California, Berkeley, CA 94720, USA Abstract. Reactive Fi#27;o

Sutre, Grégoire

249

Influence of Cationic Precursors on CdS Quantum-Dot-Sensitized Solar Cell Prepared by Successive Ionic Layer Adsorption and  

E-Print Network [OSTI]

as 15% was achieved for perovskite-sensitized solar cells.7 As a derivative of dye-sensitized solarInfluence of Cationic Precursors on CdS Quantum-Dot-Sensitized Solar Cell Prepared by Successive (QDs) onto porous oxide films for quantum-dot-sensitized solar cell (QDSC) applications. In this work

Cao, Guozhong

250

Cation Intermixing And Electronic Deviations At The Insulating LaCrO3/SrTiO3(001) Interface  

SciTech Connect (OSTI)

The interface between polar perovskite LaCrO3 (LCO) and non-polar SrTiO3(001) (STO), grown by molecular beam epitaxy, is examined using a combination of electron microscopy, spectroscopy, and Rutherford backscattering spectrometry. The LCO/STO(001) interface is insulating, a potential counter example for the claim that polar/nonpolar perovskite interfaces should be conductive by virtue of an electronic reconstruction to alleviate the polar discontinuity. The A-site cations of these ABO3 perovskites are found to diffuse across the interface to a greater extent than the B-site cations, based on high angle annular dark field scanning transmission electron microscopy (HAADF-STEM), energy dispersive x-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS). The B-site cation valences are shown to be partially reduced near the interface by analysis of EELS near-edge structures. The location and direction of these electronic modifications do not intuitively compensate the charge imbalance imposed by uneven cation inter-diffusion, and yet both the film and interface are insulating. These results highlight the importance of both the physical and electronic structure of such complex interfaces in determining their characteristics. Furthermore, the extent of inter-diffusion is shown to increase with increasing LCO film thickness, suggesting a potential mechanism behind the critical thickness for interfacial conductivity in other polar/non-polar oxide systems, and a fundamental limitation on the formation of abrupt interfaces in LCO/STO(001).

Colby, Robert J.; Qiao, Liang; Zhang, Hongliang; Shutthanandan, V.; Ciston, Jim; Kabius, Bernd C.; Chambers, Scott A.

2013-10-29T23:59:59.000Z

251

A Two-Step Fuzzy-Bayesian Classi cation for High Dimensional Data Mostafa G.-H. Mostafa, Timothy C. P erkins, and Aly A. F arag  

E-Print Network [OSTI]

algorithms are presente don simulated and real remote sensing multispectral data. The results show- spectral imaging in remote sensing and magnetic reso- nance imaging (MRI) in medical imaging are examples of suc h modalities.Classi cation of such data is an in- tensive research area in both remote sensing

Farag, Aly A.

252

Temperature and magnetic field dependent optical spectral weight in the cation-deficient colossal-magnetoresistance material La0.936Mn0.982O3  

E-Print Network [OSTI]

with the general arguments, a broad peak has been observed in 1 various Mn-based CMR materials by several groupsTemperature and magnetic field dependent optical spectral weight in the cation-deficient colossal on single-crystal samples as a function of temperature and at zero and 0.5 T magnetic fields

Homes, Christopher C.

253

Responses of soil carbon, nitrogen and cations to the frequency and seasonality of prescribed burning in a Cape Cod oak-pine forest  

E-Print Network [OSTI]

, such as combinations of fire with mechanical treatments (e.g., soil scarification) to further promote grasses and forbsResponses of soil carbon, nitrogen and cations to the frequency and seasonality of prescribed disturbance regime of oak and pine forests that occupy sandy soils of the coastal outwash plain

Schweik, Charles M.

254

Condensation Reactions between 1,3-Butadiene Radical Cation and Acetylene in the Gas Guy Bouchoux,*, Minh Tho Nguyen, and Jean-Yves Salpin,  

E-Print Network [OSTI]

Condensation Reactions between 1,3-Butadiene Radical Cation and Acetylene in the Gas Phase Guy, with neutral acetylene C2H2, 2. Experiments conducted in the gas phase and under low pressure in an FT-ICR mass spectrometer show that the reaction leads to C6H7 + ions. Complete analysis of the experimental data reveals

Nguyen, Minh Tho

255

Water Structure at the Air-Aqueous Interface of Divalent Cation and Nitrate Solutions Man Xu, Rick Spinney, and Heather C. Allen*  

E-Print Network [OSTI]

Water Structure at the Air-Aqueous Interface of Divalent Cation and Nitrate Solutions Man Xu, Rick, Columbus, Ohio 43210 ReceiVed: July 24, 2008; ReVised Manuscript ReceiVed: December 4, 2008 The water surface structure of aqueous magnesium, calcium, and strontium nitrate solutions with six to seven water

256

Coverage Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-selected Ions  

SciTech Connect (OSTI)

The ionic charge state of monodisperse cationic gold clusters on surfaces may be controlled by selecting the coverage of mass-selected ions soft landed onto a substrate. Polydisperse diphosphine-capped gold clusters were synthesized in solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine in the presence of 1,3-bis(diphenylphosphino)propane. The polydisperse gold clusters were introduced into the gas phase by electrospray ionization and mass selection was employed to select a multiply charged cationic cluster species (Au11L53+, m/z = 1409, L = 1,3-bis(diphenylphosphino)propane) which was delivered to the surfaces of four different self-assembled monolayers on gold (SAMs) at coverages of 1011 and 1012 clusters/mm2. Employing the spatial profiling capabilities of in-situ time-of-flight secondary ion mass spectrometry (TOF-SIMS) it is shown that, in addition to the chemical functionality of the monolayer (as demonstrated previously: ACS Nano, 2012, 6, 573) the coverage of cationic gold clusters on the surface may be used to control the distribution of ionic charge states of the soft-landed multiply charged clusters. In the case of a 1H,1H,2H,2H-perfluorodecanethiol SAM (FSAM) almost complete retention of charge by the deposited Au11L53+ clusters was observed at a lower coverage of 1011 clusters/mm2. In contrast, at a higher coverage of 1012 clusters/mm2, pronounced reduction of charge to Au11L52+ and Au11L5+ was observed on the FSAM. When soft landed onto 16- and 11-mercaptohexadecanoic acid surfaces on gold (16,11-COOH-SAMs), the mass-selected Au11L53+ clusters exhibited partial reduction of charge to Au11L52+ at lower coverage and additional reduction of charge to both Au11L52+ and Au11L5+ at higher coverage. The reduction of charge was found to be more pronounced on the surface of the shorter (thinner) C11 than the longer (thicker) C16-COOH-SAM. On the surface of the 1-dodecanethiol (HSAM) monolayer, the most abundant charge state was found to be Au11L52+ at lower coverage and Au11L5+ at higher coverage, respectively. A coverage-dependent electron tunneling mechanism is proposed to account for the observed reduction of charge of mass-selected multiply charged gold clusters soft landed on SAMs. The results demonstrate that one of the critical parameters that influence the chemical and physical properties of supported metal clusters, ionic charge state, may be controlled by selecting the coverage of charged species soft landed onto surfaces.

Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

2012-11-29T23:59:59.000Z

257

Location and valence state of strontium cations on the framework of a carbon dioxide selective porous silicoaluminophosphate  

SciTech Connect (OSTI)

A Sr{sup 2+}-SAPO-34 material that displays superior CO2 adsorption selectivity and capacity was characterized via XPS and UV-vis spectroscopy to elucidate the valence state of strontium cations and framework silicon environment. Most importantly, the location of the strontium has been estimated from a Rietveld refinement analysis of synchrotron diffraction data. The XPS analysis indicated that the apparent valence state of the strontium is less than 2, an indication of its interaction with the large anionic framework. Furthermore, UV-vis tests pointed to changes in the silicon environment, plausibly related to this valence state or framework faulting. For the refinement, the analysis found that strontium occupied two unique sites: a site Sr1 slightly displaced from six-membered rings and a site Sr2 positioned at the top or bottom of the eight-membered rings. The latter position favors the interaction of the alkaline earth metal with CO{sub 2}, probably resulting in an enhanced electric field-quadrupole moment interaction.

Zhang, Li; Rivera-Ramos, Milton E.; Hernández-Maldonado, Arturo J. (Puerto Rico) [Puerto Rico

2014-05-28T23:59:59.000Z

258

Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect (OSTI)

In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

2004-03-29T23:59:59.000Z

259

The use Na, Li, K cations for modification of ZSM-5 zewolite to control hydrocarbon cold-start emission  

SciTech Connect (OSTI)

This paper addresses the problem of controlling hydrocarbon emissions from cold-start of engines by investigating the adsorbents which could adsorb the hydrocarbons at cold temperatures and hold them to 250-300 ?. The materials, that has been studied, are based on the modification of ZSM-5 (SiO{sub 2}/Al{sub 2}O{sub 3} = 35) zeolite with Li, K, Na cations. It has been shown that the introduction of Li, Na and K in an amount that is equivalent to the content of Al in zeolite results in occurrence of toluene temperature desorption peaks at high-temperatures. The toluene temperature desorption curves for 5%Li-ZSM-5 and 2.3%Na-ZSM-5 zeolites are identical and have peak toluene desorption rate between 200 to 400 ?. Upon analysis of toluene adsorption isotherms for 2.3%Na-ZSM-5 and 5%Li-ZSM-5, it was concluded that the toluene diffusion inside of the modified zeolites channels is extremely slow and the sorption capacity of 2.3%Na-ZSM-5 is higher than with 5%Li-ZSM-5. The 2.3%Na-ZSM-5 didn't change toluene temperature programmed desorption (TPD) rate of curve after the treatment in environment with 10% ?{sub 2}? at 750-800 ? for about 28 h. The 2.3%Na-ZSM-5 zeolite is very promising as adsorbent to control the cold-start hydrocarbon emissions.

Golubeva V.; Rohatgi U.; Korableva, A.; Anischenko, O.; Kustov, L.; Nissenbaum, V; Viola, M.B.

2012-08-29T23:59:59.000Z

260

Synthesis and chemistry of cationic d{sup 0} metal alkyl complexes. Progress report, July 1988--May 1991  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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261

Adsorption and desorption kinetics of cesium in an organic matter-rich soil saturated with different cations  

SciTech Connect (OSTI)

The fallout from nuclear weapons tests conducted on Bikini Atoll Island in 1954 resulted in contamination of soil with Cesium 137. To develop effective regimes for decontaminating the Bikini Atoll soil, the exchange of Cs for K, Na, and other cations on the soil must be understood. Samples of soils made homoionic with K, Na, or Ca were reacted with solutions containing Cs ions, and the quantities of Cs sorbed and the rates of exchange were measured. The samples were then reacted with solutions containing K, Na, or Ca, and the quantities of Cs desorbed and the rates of exchange were again measured. Samples made homoionic with Na had a greater ion exchange capacity than samples made homoionic with K, and, in both cases, the ion exchange capacity increased with the organic matter content of the soil. For samples pretreated with Ca, the ion exchange capacity is not related in a simple way to the organic matter content. The kinetics were assessed by plotting the rate of exchange vs. the time and vs. the quantity exchanged. A first-order equation was obeyed during most of the run in Cs desorption experiments and during a limited part of the run in Cs adsorption experiments. An increase in the rate of Cs exchange was observed at the beginning of the experiments especially for Cs adsorption. This increase is presumably due to an increase of the ionic strength of the liquid phase during the exchange process. 33 refs., 9 figs., 2 tabs.

Aharoni, C. (Technion-Israel Inst. of Technology, Haifa (Israel)); Pasricha, N.S. (Punjab Agricultural Univ., Ludihana (India)); Sparks, D.L. (Univ. of Delaware, Newark, DE (United States))

1993-10-01T23:59:59.000Z

262

Cation distribution in Ni{sub 1?x}Zn{sub x}Fe{sub 2}O{sub 4} using X-ray absorption spectroscopy  

SciTech Connect (OSTI)

Spinel ferrite samples of Ni{sub 1?x}Zn{sub x}Fe{sub 2}O{sub 4} (for x=0.2, 0.4, 0.5, 0.6 and 0.8) nanoparticles prepared by a novel chemical synthesis method have been characterized by X-ray Absorption Spectroscopy (XAS) technique to investigate the distribution of cations in the unit cell. XANES region clearly shows that as Ni concentration increases, the pre-edge feature, which is a characteristic of tetrahedral coordination of Fe, is enhanced. A quantitative determination of the relative occupancy of iron cation in the octahedral and tetrahedral sites of the spinel structure was obtained from EXAFS data analysis. It has been found that as atomic fraction of Ni is increased from 0.2 to 0.8, Fe occupancy at tetrahedral to octahedral sites is increased from 13:87 and to 39:61.

Yadav, A. K., E-mail: akyadav@barc.gov.in; Jha, S. N.; Bhattacharyya, D.; Sahoo, N. K. [Atomic and Molecular Physics Division, Bhabha Atomic Research Centre, Mumbai - 400094 (India); Jadhav, J.; Biswas, S. [Department of Physics, The LNM Institute of Information Technology, Jaipur-302031 (India)

2014-04-24T23:59:59.000Z

263

Biomass production, forage quality, and cation uptake of Quail bush, four-wing saltbush, and seaside barley irrigated with moderately saline-sodic water  

SciTech Connect (OSTI)

The study reported here investigated capacity of Atriplex lentiformis (Torr.) S. Wats. (Quail bush), Atriplex X aptera A. Nels. (pro sp.) (Wytana four-wing saltbush), and Hordeum marinum Huds. (seaside barley) to produce biomass and crude protein and take up cations when irrigated with moderately saline-sodic water, in the presence of a shallow water table. Water tables were established at 0.38, 0.76, and 1.14m below the surface in sand-filled columns. The columns were then planted to the study species. Study plants were irrigated for 224 days; irrigation water was supplied every 7 days equal to water lost to evapotranspiration (ET) plus 100mL (the volume of water removed in the most previous soil solution sampling). Water representing one of two irrigation sources was used: Powder River (PR) or coalbed natural gas (CBNG) wastewater. Biomass production did not differ significantly between water quality treatments but did differ significantly among species and water table depth within species. Averaged across water quality treatments, Hordeum marinum produced 79% more biomass than A. lentiformis and 122% more biomass than Atriplex X aptera, but contained only 11% crude protein compared to 16% crude protein in A. lentiformis and 14% crude protein in Atriplex X aptera. Atriplex spp. grown in columns with the water table at 0.38m depth produced more biomass, took up less calcium on a percentage basis, and took up more sodium on a percentage basis than when grown with the water table at a deeper depth. Uptake of cations by Atriplex lentiformis was approximately twice the uptake of cations by Atriplex X aptera and three times that of H. marinum. After 224 days of irrigation, crop growth, and cation uptake, followed by biomass harvest, EC and SAR of shallow groundwater in columns planted to A. lentiformis were less than EC and SAR of shallow ground water in columns planted to either of the other species.

Bauder, J.W.; Browning, L.S.; Phelps, S.D.; Kirkpatrick, A.D. [Montana State University, Bozeman, MT (United States)

2008-07-01T23:59:59.000Z

264

Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion  

SciTech Connect (OSTI)

Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

Mohanty, Debasish [ORNL; Li, Jianlin [ORNL; Abraham, Daniel P [Argonne National Laboratory (ANL); Huq, Ashfia [ORNL; Payzant, E Andrew [ORNL; Wood III, David L [ORNL; Daniel, Claus [ORNL

2014-01-01T23:59:59.000Z

265

A new, definitive analysis of a very old spectrum: The highly perturbed A [superscript 2]?[subscript u]–X [superscript]2?[subscript g] band system of the chlorine cation (Cl[+ over 2])  

E-Print Network [OSTI]

The laser-induced fluorescencespectrum of jet-cooled chlorine cation has been recorded in the 500?312 nm region with high sensitivity and rigorous vibrational and spin-orbit cooling. More than 80 bands of the highly ...

Gharaibeh, Mohammed A.

266

The cyclopropyl cation  

E-Print Network [OSTI]

. , ~99' 1 (1932) ~ NHH N N02 H01, HHO CH2=CH-CH2-OH studying the phenolysis of various l, l-dichlorooyclopro- panes (Q) in phenol-sodium phenoxide solutions, G. C. Robin- son found no evidence for products containing a cyclo- prooane. The products...

Hampton, Loyd Ernest

1969-01-01T23:59:59.000Z

267

EMSL - cation migration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at http:www.emsl.pnl.govemslweb Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mö http:...

268

cation migration | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mössbauer Spectroscopic Study. Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mö Abstract: A...

269

Structure of gramicidin D-RbCl complex at atomic resolution from low-temperature synchrotron data: interactions of double-stranded gramicidin channel contents and cations with channel wall  

SciTech Connect (OSTI)

Gramicidin D (gD) is a naturally occurring ionophoric antibiotic that forms membrane channels specific for monovalent cations. The crystal structure of the RbCl complex of gD has been determined at 1.14 {angstrom} resolution from low-temperature (100 K) synchrotron-radiation data with a final R of 16%. The structure was refined with anisotropic temperature factors for all non-H atoms and with partial occupancies for many of them. The asymmetric unit in the crystal contains four crystallographically independent molecules that form two right-handed antiparallel double-stranded dimers. There are seven distinct rubidium-binding sites in each dimeric channel. The occupancy factors of Rb cations are between 0.11 and 0.35 and the total ion contents of the two crystallographically independent channels are 1.59 and 1.22 ions, respectively. Although each channel is 'chemically symmetrical', the side-chain conformations, the distributions of rubidium cations and their binding sites in the two independent channels are not. Cations are 'coordinated' by delocalized {pi}-electrons of three to five carbonyl groups that together with peptide backbone chains form the gramicidin channel walls. The water:cation ratio in the channel interior is four or five:one, and five or six waters separate Rb cations during their passage through the channel.

Glówka, M.L.; Olczak, A.; Bojarska, J.; Szczesio, M.; Duax, W.L.; Burkhart, B.M.; Pangborn, W.A.; Langs, D.A.; Wawrzak, Z. (Poland); (NWU); (Hauptman)

2010-03-05T23:59:59.000Z

270

Poly(pyridine)ruthenium(II)-photoinduced redox reactions of bipyridinium cations, poly(pyridine)rhodium complexes, and osmium ammines  

SciTech Connect (OSTI)

The quenching of *RuL/sub 3//sup 2 +/ (L is a 2,2'-bipyridine or 1,10-phenanthroline derivative) emissions by three classes of oxidants Q has been examined. The results are discussed in terms of the Marcus electron-transfer model recast in a preequilibrium formalism. Substituted bipyridinium cations (methyl viologen and related compounds) undergo thermodynamically favorable reduction with a driving force ranging from 0.1 to 0.7 eV and rate constants in the range (0.4-2.0) x 10/sup 9/ M/sup -1/s/sup -1/, consistent with a diffusion rate constant of 2.0 x 10/sup 9/ M/sup -1/s/sup -1/ and an exchange rate constant of approx.10/sup 6/ M/sup -1/s/sup -1/ for the Q-Q couples. The yields of the separated redox products RuL/sub 3//sup 3 +/ and Q/sup -/ (typically 0.1 mol einstein/sup -1/ per quenching act) require K/sub 30/, the ''intramolecular'' back-reaction rate constant (to re-form ground-state RuL/sub 3//sup 2 +/ and Q), to be (2-4) x 10/sup 10/ s/sup -1/. Since K/sub 30/ increases weakly with driving force in this series, there is no evidence for inverted behavior despite the fact the ..delta..G/sup 0//sub 30/ is approx.-2 eV. With Q = Rh(4,4'-(CH/sub 3/)/sub 2/bpy)/sub 3//sup 3 +/, the quenching rate constants, k/sub q/ = (0.001-1.0) x 10/sup 9/ M/sup -1/s/sup -1/, exhibit a great sensitivity to the reducing power of *RuL/sub 3//sup 2 +/ and have been fitted to k/sub 11/ approx. = 2 x 10/sup 9/ M/sup -1/s/sup -1/ and E/sup 0//sub Q,Q/sup -// = -0.97 V for the RhL/sub 3//sup 3 +/-RhL/sub 3//sup 2 +/ couple. This E/sup 0/ value is strikingly similar to that (-0.9 V vs. aqueous SCE) obtained via cyclic voltammetry in acetonitrile. The cyclic voltammetry of the RhL/sub 3//sup 3 +/ complexes in water has been reexamined, and it is concluded that the irreversibility observed is due to ligand loss from rhodium(I).

Creutz, C.; Keller, A.D.; Sutin, N.; Zipp, A.P.

1982-06-30T23:59:59.000Z

271

Selectivity Control in Synergistic Liquid-Liquid Anion Exchange of Univalent Anions via Structure-Specific Cooperativity between Quaternary Ammonium Cations and Anion Receptors  

SciTech Connect (OSTI)

Two anion receptors enhance liquid-liquid anion exchange when added to quaternary alkylammonium chloride anion exchangers, but with a striking dependence upon the structure of the alkylammonium cation. Two anion receptors were investigated, meso-octamethylcalix[4]pyrrole (C4P) and the bisthiourea tweezer 1,1'-(propane-1,3-diyl)bis(3-(4-sec-butylphenyl)thiourea (BTU). C4P has the unique ability in its cone anion-binding conformation to accept an appropriately sized electropositive species in the resulting cup formed by its four electron-rich pyrrole groups, while BTU is not expected to be predisposed for a specific host-guest interaction with the quaternary ammonium cations. It was therefore hypothesized that synergism between C4P and methyltri(C8,10)alkylammonium chloride (Aliquat 336) would be uniquely pronounced owing to insertion of the methyl group of the Aliquat cation into the C4P cup, and we present herein data supporting this expectation. While synergism is comparatively weak for both exchangers with the BTU receptor, synergism between C4P and Aliquat 336 is indeed so strong that anion exchange prefers chloride over more extractable nitrate and trifluoroacetate, effectively overcoming the ubiquitous Hofmeister bias. A thermochemical analysis of synergistic anion exchange has been provided for the first time, unraveling the observed selectivity behavior and resulting in the estimation of binding constants for C4P with the ion pairs of A336+ with Cl , Br , OAcF3 , NO3 , and I . The uniquely strong positive cooperativity between A336 and C4P underscores the advantage of a supramolecular approach in the design of synergistic anion exchange systems.

Borman, Christopher J [ORNL; Bonnesen, Peter V [ORNL; Moyer, Bruce A [ORNL

2012-01-01T23:59:59.000Z

272

Coadsorption of sulfate/bisulfate anions with Hg cations during Hg underpotential deposition on Au(111): An in situ x-ray diffraction study  

SciTech Connect (OSTI)

The first stage of mercury underpotential deposition on Au(111) electrodes in 0.10 M H{sub 2}SO{sub 4} containing 1.0 mM Hg{sup 2+} has been studied by synchrotron X-ray scattering techniques including grazing incidence X-ray diffraction and specular crystal truncation rod measurements. An ordered coadsorbed structure of sulfate/bisulfate anions and Hg cations was found at potentials between the first and second Hg UPD peaks (+0.80 V > E > +0.88 V vs Ag/AgCl(3 M KCl)). The coadsorption structure was found to consist of a compressed Hg honeycomb lattice with the honeycomb centers occupied by sulfate or bisulfate anions. The compression of the lattice is likely due to the formation of mercurous (Hg{sub 2}{sup 2+}) ions which have a much shorter Hg-Hg distance than that in frozen bulk Hg crystals. The net charge transferred under the first Hg UPD peak suggests that the chemical state of the species in the coadsorbed structure is likely Hg{sub 2}SO{sub 4}. Our results indicate that both the chemical state of the mercury cations and the nature of the anions are important in the resulting electrodeposited structures. 38 refs., 8 figs., 1 tab.

Li, J.; Abruna, H.D. [Cornell Univ., Ithaca, NY (United States)] [Cornell Univ., Ithaca, NY (United States)

1997-01-09T23:59:59.000Z

273

Photoionization of cold gas phase coronene and its clusters: Autoionization resonances in monomer, dimer, and trimer and electronic structure of monomer cation  

SciTech Connect (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are key species encountered in a large variety of environments such as the Interstellar Medium (ISM) and in combustion media. Their UV spectroscopy and photodynamics in neutral and cationic forms are important to investigate in order to learn about their structure, formation mechanisms, and reactivity. Here, we report an experimental photoelectron-photoion coincidence study of a prototypical PAH molecule, coronene, and its small clusters, in a molecular beam using the vacuum ultraviolet (VUV) photons provided by the SOLEIL synchrotron facility. Mass-selected high resolution threshold photoelectron (TPES) and total ion yield spectra were obtained and analyzed in detail. Intense series of autoionizing resonances have been characterized as originating from the monomer, dimer, and trimer neutral species, which may be used as spectral fingerprints for their detection in the ISM by VUV absorption spectroscopy. Finally, a full description of the electronic structure of the monomer cation was made and discussed in detail in relation to previous spectroscopic optical absorption data. Tentative vibrational assignments in the near-threshold TPES spectrum of the monomer have been made with the support of a theoretical approach based on density functional theory.

Bréchignac, Philippe, E-mail: philippe.brechignac@u-psud.fr; Falvo, Cyril; Parneix, Pascal; Pino, Thomas; Pirali, Olivier [Institut des Sciences Moléculaires d’Orsay, CNRS UMR8214, Univ Paris-Sud, F-91405 Orsay (France); Garcia, Gustavo A.; Nahon, Laurent [Synchrotron SOLEIL, L’Orme des Merisiers, Saint-Aubin, B.P. 48, F-91192 Gif-sur-Yvette (France); Joblin, Christine; Kokkin, Damian; Bonnamy, Anthony [IRAP, Université de Toulouse 3 - CNRS, 9 Av. Colonel Roche, B.P. 44346, F-31028 Toulouse Cedex 4 (France); Mulas, Giacomo [INAF - Osservatorio Astronomico di Cagliari, via della scienza 5, I-09047 Selargius (Italy)

2014-10-28T23:59:59.000Z

274

Novel chemically stable Ba3Ca1.18Nb1.82-xYxO9- proton conductor: improved proton conductivity through tailored cation ordering  

SciTech Connect (OSTI)

Simple perovskite-structured proton conductors encounter significant challenges to simultaneously achieving excellent chemical stability and proton conductivity that are desirable for many important applications in energy conversion and storage. This work demonstrates that Y-doped complex-perovskite-structured Ba3Ca1.18Nb1.82 xYxO9 materials possess both improved proton conductivity and exceptional chemical stability. Neutron powder diffraction refinement revealed a Fm3 m perovskite-structure and increased oxygen vacancy concentration due to the Y doping. High-resolution TEM analysis confirmed the perturbation of the B site cation ordering in the structure for the Ba3Ca1.18Nb1.82 xYxO9 materials. Such combined effects led to improved proton conductivity with a value of 5.3 10 3 S cm 1 at 600 C for Ba3Ca1.18Nb1.52Y0.3O9 (BCNY0.3), a value 2.4 times higher compared with that of the undoped Ba3Ca1.18Nb1.82O9 . The Ba3Ca1.18Nb1.82 xYxO9 materials showed remarkable chemical stability toward water and demonstrated no observable reactions to CO2 exposure. Ionic transport number studies showed that BCNY0.3 had predominantly proton conduction below 600 C. Solid oxide fuel cells using BCNY0.3 as an electrolyte demonstrated cell power output of 103 mW cm 2 at 750 C. These results suggest that a doping strategy that tailors the cation ordering in complex perovskites provides a new direction in the search for novel proton conducting ceramics.

Wang, Siwei [University of South Carolina, Columbia] [University of South Carolina, Columbia; Chen, Yan [ORNL] [ORNL; Fang, Shumin [University of South Carolina, Columbia] [University of South Carolina, Columbia; Zhang, Lingling [University of South Carolina, Columbia] [University of South Carolina, Columbia; Tang, Ming [Los Alamos National Laboratory (LANL)] [Los Alamos National Laboratory (LANL); An, Ke [ORNL] [ORNL; Brinkman, Dr. Kyle S. [Savannah River National Laboratory (SRNL), Aiken, S.C.] [Savannah River National Laboratory (SRNL), Aiken, S.C.; Chen, Fanglin [University of South Carolina, Columbia] [University of South Carolina, Columbia

2014-01-01T23:59:59.000Z

275

Appearedin Proc. ACM Software Testing Analysis and Veri cation Symp. TAV3-SIGSOFT89, pp. 179-186, Dec. 1989. 1 Estimating the Number of Test Cases Required to Satisfy the All-du-paths  

E-Print Network [OSTI]

discriminating structural testing crite- ria are based on data ow analysis. Rapps and Weyuker de ne a familyAppearedin Proc. ACM Software Testing Analysis and Veri cation Symp. TAV3-SIGSOFT89, pp. 179-186, Dec. 1989. 1 Estimating the Number of Test Cases Required to Satisfy the All-du-paths Testing

Bieman, James M.

276

Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps  

SciTech Connect (OSTI)

Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

2011-01-01T23:59:59.000Z

277

Communication: Two-step explosion processes of highly charged fullerene cations C{sub 60}{sup q+} (q = 20–60)  

SciTech Connect (OSTI)

To establish the fundamental understanding of the fragmentation dynamics of highly positive charged nano- and bio-materials, we carried out on-the-fly classical trajectory calculations on the fragmentation dynamics of C{sub 60}{sup q+} (q = 20–60). We used the UB3LYP/3-21G level of density functional theory and the self-consistent charge density-functional based tight-binding theory. For q ? 20, we found that a two-step explosion mechanism governs the fragmentation dynamics: C{sub 60}{sup q+} first ejects singly and multiply charged fast atomic cations C{sup z+} (z ? 1) via Coulomb explosions on a timescale of 10 fs to stabilize the remaining core cluster. Thermal evaporations of slow atomic and molecular fragments from the core cluster subsequently occur on a timescale of 100 fs to 1 ps. Increasing the charge q makes the fragments smaller. This two-step mechanism governs the fragmentation dynamics in the most likely case that the initial kinetic energy accumulated upon ionization to C{sub 60}{sup q+} by ion impact or X-ray free electron laser is larger than 100 eV.

Yamazaki, Kaoru; Nakamura, Takashi; Kanno, Manabu; Kono, Hirohiko, E-mail: hirokiko-kono@m.tohoku.ac.jp [Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578 (Japan); Niitsu, Naoyuki [Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578 (Japan); Nanosystem Research Institute (NRI), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Ueda, Kiyoshi [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577 (Japan)

2014-09-28T23:59:59.000Z

278

Elucidating the mechanism behind the stabilization of multi-charged metal cations in water: A case study of the electronic states of microhydrated Mg2+, Ca2+ and Al3+”  

SciTech Connect (OSTI)

Metal atoms typically have second and higher ionization potentials (IPs) that are larger than the IP of water, resulting in the Coulombic explosion of the first few [M(H2O)n]+q (q ? 2) clusters as the M+ + (H2O)n + or MOH+ + H3O+(H2O)n energy levels are energetically more stable than the M2+ + (H2O)n ones for small n. We present a theoretical analysis of the various electronic states correlating with the above channels that are involved in the sequential hydration of the Ca2+, Mg2+ and Al3+ cations with up to six water molecules that, for the first time, quantifies their relative shift with the degree of solvation accounting for the observed stabilization of those multi-charged metal cations in an aqueous solution. *

Miliordos, Evangelos; Xantheas, Sotiris S.

2014-04-21T23:59:59.000Z

279

High affinity capture and concentration of quinacrine in polymorphonuclear neutrophils via vacuolar ATPase-mediated ion trapping: Comparison with other peripheral blood leukocytes and implications for the distribution of cationic drugs  

SciTech Connect (OSTI)

Many cationic drugs are concentrated in acidic cell compartments due to low retro-diffusion of the protonated molecule (ion trapping), with an ensuing vacuolar and autophagic cytopathology. In solid tissues, there is evidence that phagocytic cells, e.g., histiocytes, preferentially concentrate cationic drugs. We hypothesized that peripheral blood leukocytes could differentially take up a fluorescent model cation, quinacrine, depending on their phagocytic competence. Quinacrine transport parameters were determined in purified or total leukocyte suspensions at 37 °C. Purified polymorphonuclear leukocytes (PMNLs, essentially neutrophils) exhibited a quinacrine uptake velocity inferior to that of lymphocytes, but a consistently higher affinity (apparent K{sub M} 1.1 vs. 6.3 ?M, respectively). However, the vacuolar (V)-ATPase inhibitor bafilomycin A1 prevented quinacrine transport or initiated its release in either cell type. PMNLs capture most of the quinacrine added at low concentrations to fresh peripheral blood leukocytes compared with lymphocytes and monocytes (cytofluorometry). Accumulation of the autophagy marker LC3-II occurred rapidly and at low drug concentrations in quinacrine-treated PMNLs (significant at ? 2.5 ?M, ? 2 h). Lymphocytes contained more LAMP1 than PMNLs, suggesting that the mass of lysosomes and late endosomes is a determinant of quinacrine uptake V{sub max}. PMNLs, however, exhibited the highest capacity for pinocytosis (uptake of fluorescent dextran into endosomes). The selectivity of quinacrine distribution in peripheral blood leukocytes may be determined by the collaboration of a non-concentrating plasma membrane transport mechanism, tentatively identified as pinocytosis in PMNLs, with V-ATPase-mediated concentration. Intracellular reservoirs of cationic drugs are a potential source of toxicity (e.g., loss of lysosomal function in phagocytes). - Highlights: • Quinacrine is concentrated in acidic organelles via V-ATPase-mediated ion trapping. • Human peripheral blood leukocytes capture and concentrate quinacrine. • Polymorphonuclear leukocytes do so with higher apparent affinity. • Polymorphonuclear are also more competent than lymphocytes for pinocytosis.

Roy, Caroline; Gagné, Valérie; Fernandes, Maria J.G.; Marceau, François, E-mail: francois.marceau@crchul.ulaval.ca

2013-07-15T23:59:59.000Z

280

Photochemical generation of alkyl radicals and their reactions with methyl viologen radical cation and with transition-metal complexes in aqueous solution  

SciTech Connect (OSTI)

The irradiation of aqueous solutions of RCo((14)aneN{sub 4})(H{sub 2}O){sup 2+} (R = CH{sub 3}, C{sub 2}H{sub 5}, 1-C{sub 3}H{sub 7}, CH{sub 2}Cl, CH{sub 2}Br, CH{sub 2}OCH{sub 3}) with visible light, {lambda} {le} 400 nm, results in the homolysis of the cobalt-carbon bond. These complexes are quite unreactive toward a variety of dealkylating and redox reagents and thus represent a convenient source of small unstabilized carbon-centered radicals in the presence of potential substrates. The radicals react rapidly with the methyl viologen radical cation, k{sub MB} = (1-2) {times} 10{sup 9} M{sup {minus}1} s{sup {minus}1}. The kinetics of the formation of RCr{sup 2+} and RCo((14)aneN{sub 4})(H{sub 2}O){sup 2+} in the reactions of radicals with Cr{sup 2+} and Co((14)aneN{sub 4})(H{sub 2}O){sub 2}{sup 2+}, respectively, were studied by using MV{sup +} as a probe. The respective rate constants have values k{sub Cr} = (1.9-2.4) {times} 10{sup 8} M{sup {minus}1} s{sup {minus}1} and k{sub Co} = (1-2) {times} 10{sup 7} M{sup {minus}1} s{sup {minus}1} for all the radicals examined. 36 refs., 2 figs., 1 tab.

Bakac, A.; Espenson, J.H. (Iowa State Univ., Ames (USA))

1989-10-04T23:59:59.000Z

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281

Site occupancy and cation binding states in reduced polycrystalline Sr{sub x}Ba{sub 1?x}Nb{sub 2}O{sub 6}  

SciTech Connect (OSTI)

Site occupancy and cation binding states in the proposed thermoelectric n-type oxide Sr{sub x}Ba{sub 1?x}Nb{sub 2}O{sub 6} (SBN100x) were investigated using X-ray photoelectron spectroscopy (XPS). Sr 3d XPS spectra from unreduced polycrystalline SBN100x with various compositions contained two distinct spin-orbit doublets corresponding to Sr occupying either A1 or A2 positions in the SBN lattice; the higher binding energy state was associated with Sr ions at A2 sites, presumably due to their increased coordination over Sr at A1 sites. To gain insight into optimizing the thermoelectric properties of reduced SBN, sintered SBN50 specimens were reduced in Ar/H{sub 2} or N{sub 2}/H{sub 2} ambient. A decrease in the average Nb valence was observed in Nb 3d photoemission through the growth of low-binding energy components after reduction in either environment; evidence of surface NbN formation was apparent with longer reducing times in N{sub 2}/H{sub 2}. Both the single-component Ba 3d emission and the A2 component of the Sr 3d spectra show shifting to lower binding energy as the reduction time is increased, supporting the hypothesis of preferential oxygen vacancy formation adjacent to A2 sites. X-ray diffraction patterns revealed the formation of NbO{sub 2} in both reducing environments; in the case of extended reduction in N{sub 2}/H{sub 2}, NbO{sub 2} is gradually converted to NbN phases. Given the known properties of metallic NbN and semiconducting NbO{sub 2}, the findings obtained here may be used to maximize the thermoelectric performance of SBN via the fabrication of composite structures containing both NbO{sub 2} and NbN.

Dandeneau, Christopher S., E-mail: dandec@u.washington.edu; Yang, YiHsun; Ohuchi, Fumio S. [Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States)] [Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195 (United States); Krueger, Benjamin W.; Olmstead, Marjorie A. [Department of Physics, University of Washington, Seattle, Washington 98195 (United States)] [Department of Physics, University of Washington, Seattle, Washington 98195 (United States); Bordia, Rajendra K. [Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States)] [Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States)

2014-03-10T23:59:59.000Z

282

Does fluoride disrupt hydrogen bond network in cationic lipid bilayer? Time-dependent fluorescence shift of Laurdan and molecular dynamics simulations  

SciTech Connect (OSTI)

Time-dependent fluorescence shift (TDFS) of Laurdan embedded in phospholipid bilayers reports on hydration and mobility of the phospholipid acylgroups. Exchange of H{sub 2}O with D{sub 2}O prolongs the lifetime of lipid-water and lipid-water-lipid interactions, which is reflected in a significantly slower TDFS kinetics. Combining TDFS measurements in H{sub 2}O and D{sub 2}O hydrated bilayers with atomistic molecular dynamics (MD) simulations provides a unique tool for characterization of the hydrogen bonding at the acylgroup level of lipid bilayers. In this work, we use this approach to study the influence of fluoride anions on the properties of cationic bilayers composed of trimethylammonium-propane (DOTAP). The results obtained for DOTAP are confronted with those for neutral phosphatidylcholine (DOPC) bilayers. Both in DOTAP and DOPC H{sub 2}O/D{sub 2}O exchange prolongs hydrogen-bonding lifetime and does not disturb bilayer structure. These results are confirmed by MD simulations. TDFS experiments show, however, that for DOTAP this effect is cancelled in the presence of fluoride ions. We interpret these results as evidence that strongly hydrated fluoride is able to steal water molecules that bridge lipid carbonyls. Consequently, when attracted to DOTAP bilayer, fluoride disrupts the local hydrogen-bonding network, and the differences in TDFS kinetics between H{sub 2}O and D{sub 2}O hydrated bilayers are no longer observed. A distinct behavior of fluoride is also evidenced by MD simulations, which show different lipid-ion binding for Cl{sup ?} and F{sup ?}.

Pokorna, Sarka; Jurkiewicz, Piotr; Hof, Martin, E-mail: martin.hof@jh-inst.cas.cz [J. Heyrovský Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic v.v.i., Dolejskova 3, 18223 Prague 8 (Czech Republic); Vazdar, Mario [Division of Organic Chemistry and Biochemistry, Rudjer Boškovi? Institute, P.O.B. 180, HR-10002 Zagreb (Croatia); Cwiklik, Lukasz [J. Heyrovský Institute of Physical Chemistry of the Academy of Sciences of the Czech Republic v.v.i., Dolejskova 3, 18223 Prague 8 (Czech Republic); Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 16610 Prague 6 (Czech Republic); Jungwirth, Pavel [Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, Flemingovo nám. 2, 16610 Prague 6 (Czech Republic); Department of Physics, Tampere University of Technology, P.O. Box 692, FI-33101 Tampere (Finland)

2014-12-14T23:59:59.000Z

283

High cation transport polymer electrolyte  

DOE Patents [OSTI]

A solid state ion conducting electrolyte and a battery incorporating same. The electrolyte includes a polymer matrix with an alkali metal salt dissolved therein, the salt having an anion with a long or branched chain having not less than 5 carbon or silicon atoms therein. The polymer is preferably a polyether and the salt anion is preferably an alkyl or silyl moiety of from 5 to about 150 carbon/silicon atoms.

Gerald, II, Rex E. (Brookfield, IL); Rathke, Jerome W. (Homer Glen, IL); Klingler, Robert J. (Westmont, IL)

2007-06-05T23:59:59.000Z

284

Identi cation of Physical Models  

E-Print Network [OSTI]

of building components. The work is related to a CEC research project called #12;PASSYS Passive Solar Components and Systems Testing, on testing of building components related to passive solar energy is thought to be on experiment design for dynamical systems and on the implementation of the methods for es

285

Effect of electrolytes and temperature on dications and radical cations of carotenoids: Electrochemical, optical absorption, and high-performance liquid chromatography studies  

SciTech Connect (OSTI)

The effect of supporting electrolytes and temperature on the behavior of dications and radical cations of carotenoids is studied. Cyclic voltammograms (CVs) of canthaxanthin (I) at 23 and {minus}25 C show that Car{sup sm{underscore}bullet+} of I has similar stability during the time of the CV scan, when using tetrabutylammonium perchlorate (TBAPC), tetrabutylammonium tetrafluoroborate (TBATFB), or tetrabutylammonium hexafluorophosphate (TBAHFP) as supporting electrolyte. However, the stability of Car{sup 2+} decreases when using TBAPC or TBATFB; {beta}-carotene (II) shows similar behavior. The CV of I at {minus}25 C shows a strong cathodic wave (wave 6) near {minus}0.15 V (vs Ag) with an intensity about half that of the neutral oxidation wave when TBAPC or TBATFB is the supporting electrolyte. When TBAHFP is used, wave 6 (ca. {minus}0.05 V vs Ag) is ca. 8 times weaker than when TBAPC or TBATFB is used. This wave results from the reduction of a species that may be a decay product of Car{sup 2+} of I. Results show that these electrolytes commonly used in electrochemical studies may affect the studied systems to different extents. In simultaneous bulk electrolysis (BE) and optical absorption spectroscopic measurements, the absorption band of Car{sup 2+} of I in the presence of 0.1 M TBAHFP can be observed by lowering the BE temperature to {minus}20 C. In the presence of 0.1 M TBAPC or TBATFB, this band is not observed, even at {minus}50 C. Isomerization of neutral I (as shown by HPLC and its blue absorption band shift) is observed only when the Car{sup 2+} absorption band is absent during BE. This observation, along with an increase of the neutral absorption band after stopping BE, suggests that the equilibrium Car + Car{sup 2+} {r{underscore}equilibrium} 2Car{sup {sm{underscore}bullet}+} is shifted to the left because Car{sup 2+} decays more quickly than Car{sup {sm{underscore}bullet}+} in the presence of electrolyte and this is a major path for formation of cis neutral species from cis Car{sup {sm{underscore}bullet}+}. The optical absorption of Car{sup 2+} of I at 18 C in the presence of 0.1 M TBAHFP is obtained, which suggests that Car{sup 2+} of I is not as unstable at room temperature in the presence of TBAHFP as was thought before.

He, Z.; Kispert, L.D.

1999-11-25T23:59:59.000Z

286

Structural evolution of the double perovskites Sr{sub 2}B'UO{sub 6} (B' = Mn, Fe, Co, Ni, Zn) upon reduction: Magnetic behavior of the uranium cations  

SciTech Connect (OSTI)

Highlights: {yields} Evolution of the double perovskites Sr{sub 2}B'UO{sub 6} upon reduction were studied by XRPD. {yields} Orthorhombic (Pnma) disordered perovskites SrB'{sub 0.5-x}U{sub 0.5+x}O{sub 3} were obtained at 900 {sup o}C. {yields} U{sup 5+/4+} and Zn{sup 2+} cations are distributed at random over the octahedral positions. {yields} AFM ordering for the perovskite with B' = Zn appears below 30 K. -- Abstract: We describe the preparation of five perovskite oxides obtained upon reduction of Sr{sub 2}B'UO{sub 6} (B' = Mn, Fe, Co, Ni, Zn) with H{sub 2}/N{sub 2} (5%/95%) at 900 {sup o}C during 8 h, and their structural characterization by X-ray powder diffraction (XRPD). During the reduction process there is a partial segregation of the elemental metal when B' = Co, Ni, Fe, and the corresponding B'O oxide when B' = Mn, Zn. Whereas the parent, oxygen stoichiometric double perovskites Sr{sub 2}B'UO{sub 6} are long-range ordered concerning B' and U cations. The crystal structures of the reduced phases, SrB'{sub 0.5-x}U{sub 0.5+x}O{sub 3} with 0.37 < x < 0.27, correspond to simple, disordered perovskites; they are orthorhombic, space group Pnma (No. 62), with a full cationic disorder at the B site. Magnetic measurements performed on the phase with B' = Zn, indicate uncompensated antiferromagnetic ordering of the U{sup 5+}/U{sup 4+} sublattice below 30 K.

Pinacca, R.M., E-mail: rmp@unsl.edu.ar [Area de Quimica General e Inorganica 'Dr. Gabino F. Puelles', Departamento de Quimica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Viola, M.C.; Pedregosa, J.C. [Area de Quimica General e Inorganica 'Dr. Gabino F. Puelles', Departamento de Quimica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina)] [Area de Quimica General e Inorganica 'Dr. Gabino F. Puelles', Departamento de Quimica, Facultad de Quimica, Bioquimica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Carbonio, R.E. [INFIQC (CONICET), Departamento de Fisicoquimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Ciudad Universitaria, X5000HUA Cordoba (Argentina)] [INFIQC (CONICET), Departamento de Fisicoquimica, Facultad de Ciencias Quimicas, Universidad Nacional de Cordoba, Ciudad Universitaria, X5000HUA Cordoba (Argentina); Lope, M.J. Martinez; Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid (Spain)] [Instituto de Ciencia de Materiales de Madrid, C.S.I.C., Cantoblanco, 28049 Madrid (Spain)

2011-11-15T23:59:59.000Z

287

Cation ordering transformations in Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3}-BaZrO{sub 3} perovskite solid solutions  

SciTech Connect (OSTI)

The effect of the substitution of BaZrO{sub 3} on the cation ordering in Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3} was studied using TEM and X-ray and neutron diffraction. Almost no solubility of Zr was found in the 1:2 ordered, trigonal structure of the Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3} end-member (P{bar 3}m1), and a transformation to a 1:1 ordered, cubic (Fm{bar 3}m) phase with a = 2a{sub per} occurs for substitution levels between {approximately}10 and 25 mol% BaZrO{sub 3}. The structure of this Ba({beta}{prime}{sub 1/2}{beta}{double_prime}{sub 1/2})O{sub 3}-type phase consists of two distinct octahedral sites, {beta}{prime} and {beta}{double_prime}. The occupancies of the two cation positions, refined using the Rietveld method, were found to be consistent with a random site model in which {beta}{double_prime} is occupied by Ta, and {beta}{prime} by a random distribution of the remaining cations. The homogeneity range of the 1:1 solid solutions predicted by this model, Ba{l_brace}[Mg{sub (2{minus}y)/3} Ta{sub (1{minus}2y)/3} Zr{sub y}]{sub 1/2}[Ta]{sub 1/2}{r_brace}O{sub 3} (0.0 < y {le} 0.5), is in excellent agreement with that observed experimentally.

Chai, L.; Akbas, M.A.; Davies, P.K. [Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering] [Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering; Parise, J.B. [Univ. of New York, Stony Brook, NY (United States). Dept. of Earth and Space Sciences] [Univ. of New York, Stony Brook, NY (United States). Dept. of Earth and Space Sciences

1997-09-01T23:59:59.000Z

288

Comproportionation of Cationic and Anionic Tungsten Complexes Having an N-Heterocyclic Carbene Ligand to Give the Isolable 17-Electron Tungsten Radical, CpW(CO)2(IMes)•  

SciTech Connect (OSTI)

A series consisting of a tungsten anion, radical and cation, supported by the N-heterocyclic carbene IMes (1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) and spanning formal oxidation states W(0), W(I) and W(II), has been synthesized, isolated, and characterized. Reaction of the hydride CpW(CO)2(IMes)H with KH and 18 crown 6 gives the tungsten anion [CpW(CO)2(IMes)]-[K(18 crown 6)]+. The crystal structure of this complex shows that the K+ interacts not only with the oxygen atoms in the crown ether, but also with the carbonyl oxygens. The electrochemical oxidation of [CpW(CO)2(IMes)]- in acetonitrile is fully reversible (E½ = ?1.65 V vs Cp2Fe+•/0) at all scan rates, indicating that CpW(CO)2(IMes)• is a persistent radical. Hydride transfer from CpW(CO)2(IMes)H to Ph3C+PF6 affords [cis-CpW(CO)2(IMes)(MeCN)]+PF6 . Comproportionation of [CpW(CO)2(IMes)]- with [CpW(CO)2(IMes)(MeCN)]+ gives the 17-electron tungsten radical CpW(CO)2(IMes)•. This complex shows paramagnetically shifted resonances in 1H NMR spectra and has been characterized by IR spectroscopy, low-temperature EPR spectroscopy, and X-ray diffraction. CpW(CO)2(IMes)• is very stable with respect to disproportionation and dimerization. NMR studies of degenerate electron transfer between CpW(CO)2(IMes)• and [CpW(CO)2(IMes)]- are reported. DFT calculations were carried out on CpW(CO)2(IMes)H, as well as on related complexes bearing NHC ligands with N,N´ substituents Me [CpW(CO)2(IMe)H] or H [CpW(CO)2(IH)H] to compare to the experimentally studied IMes complexes with mesityl substituents. These calculations reveal W H homolytic bond dissociation energies (BDEs) to decrease with increasing steric bulk of the NHC ligand, from 67 for CpW(CO)2(IH)H to 64 for CpW(CO)2(IMe)H to 63 kcal/mol for CpW(CO)2(IMes)H. The calculated spin density at W for CpW(CO)2(IMes)• is 0.63. The W radicals CpW(CO)2(IMe)• and CpW(CO)2(IH)• are calculated to form weak W W bonds. The weakly bonded complexes [CpW(CO)2(IMe)]2 and [CpW(CO)2(IH)]2, are predicted to have W-W BDEs of 6 and 18 kcal/mol, respectively, and to dissociate readily to the W-centered radicals CpW(CO)2(IMe)• and CpW(CO)2(IH)•. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Roberts, John A.; Franz, James A.; van der Eide, Edwin F.; Walter, Eric D.; Petersen, Jeffrey L.; DuBois, Daniel L.; Bullock, R. Morris

2011-09-21T23:59:59.000Z

289

Flexibility of the zeolite RHO framework. In situ X-ray and neutron powder structural characterization of cation-exchanged BePO and BeAsORHO analogs  

SciTech Connect (OSTI)

This is an extensive study of the non-aluminosilicate analogs of the zeolite RHO. This molecular sieve is of great interest commercially because of its catalytic properties. In the absence of rigid supporting structural subunits (smaller cages or channels), the aluminosilicate RHO exhibits atypical framework flexibility with large displacivere arrangements. The beryllophosphate and beryalloarsenate analogs are easily synthesized under very mild reaction conditions and therefore maybe of interest for inexpensive and rapid commercial production. However,t hey have decreased thermal stability. In an effort to increase thermal stability and explore framework flexibility, we have synthesized and characterized a series of analogs of the non-aluminosilicate RHO framework. All materials crystallize in the space group I23, ranging from a = 13.584-(2) A for Li-BePO RHO to a = 14.224(4) A for Ba-RbBeAsO RHO for hydrated phases. The extra framework cations are distributed over the double 8-ring, single 8-ring, and two single 6-ring sites. Partially and fully dehydrated phases were also studied for changes in framework stability. Predictive trends based on the type of cation exchanged into the framework were determined by {sup 9}Be and {sup 31}P MAS NMR. 50 refs., 8 figs., 6 tabs.

Nenoff, T.M. [Univ. of California, Santa Barbara, CA (United States)] [Univ. of California, Santa Barbara, CA (United States); Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Jones, G.A.; Galya, L.G.; Corbin, D.R.; Stucky, G.D. [DuPont Co., Wilmington, DE (United States)] [DuPont Co., Wilmington, DE (United States)

1996-08-15T23:59:59.000Z

290

Learning Assumptions for Compositional Veri cation  

E-Print Network [OSTI]

that the property is either true or false in the system. We have imple- mented our approach in the LTSA tool

Pasareanu, Corina

291

Veri cation of Automated Vehicle Protection Systems  

E-Print Network [OSTI]

such as PRT 2000TM, a system currently being developed at Raytheon. Due to their safety critical nature, PRT]. Raytheon engineers are currently working on the design and development of a new PRT system called PRT 2000-4033 and F19628-95-C-0118. zNorman M Delisle@ccmail.ed.ray.com. Raytheon Company, 1001 Boston Post Road

Lynch, Nancy

292

Characterization of cation environments in polycrystalline forsterite...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

forsterite by Mg-25 MAS, MQMAS, and QCPMG NMR . Abstract: Forsterite (Mg2SiO4) is a silicate mineral frequently studied in the Earth sciences as it has a simple crystal structure...

293

Geothermal Site Assessment Using the National Geothermal Data...  

Open Energy Info (EERE)

a database user can identify Hawthorne-area thermal anomalies several ways: through spatial interpolation of database geothermometry, temperature gradient calculations, and...

294

GTO2015DBm  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

"Known Geothermal Resource Areas" in Southern Idaho and Eastern Oregon Patrick Dobson, LBNL & Rob Podgorney, INL Improved Geothermometry Through Multivariate Reaction Path...

295

Geothermal: Sponsored by OSTI -- GeoT User's Guide: A Computer...  

Office of Scientific and Technical Information (OSTI)

Program for Multicomponent Geothermometry and Geochemical Speciation, Version 1.4 Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us HomeBasic Search...

296

E-Print Network 3.0 - argentina petrology geochronology Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

8 Project EARTH-12-MPS1: Constraining channel flow and exhumation in the central Nepal Himalaya Summary: , geothermometry, phase-diagram and thermal modelling, and...

297

Two cation exchange models for direct and inverse modelling of solution major cation composition in  

E-Print Network [OSTI]

the relative amount of Na+ , K+ , Ca2+ , Mg2+ in solution: NaX + K+ KX + Na+ KNa/K Reaction 1 2 NaX + Ca2+ CaX

Paris-Sud XI, Université de

298

Cation Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |withzeolite: an in

299

Cation-Cation Interactions in [(UO2)2(OH)n](4-n) Complexes. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |withzeolite:

300

Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 Resource ProgramEnergy Innovation PortalRolandsaturated

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
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301

Geothermal reservoir temperatures estimated from the oxygen isotope...  

Open Energy Info (EERE)

drillholes have been tested as a geothermometer in three areas of the western United States. Limited analyses of spring and borehole fluids and existing experimental rate...

302

Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...  

Open Energy Info (EERE)

drillholes have been tested as a geothermometer in three areas of the western United States. Limited analyses of spring and borehole fluids and existing experimental rate...

303

The Multilevel Classi cation Problem and a Monotonicity Hint  

E-Print Network [OSTI]

of mild heart attack symptoms might convey quite a bit of information about the nature of severe heart attack symptoms. For example, if we know the cholesterol level of mild heart attack victims, it is reasonable to guess that the cholesterol level of severe heart attack victims should be higher. Ignoring

Magdon-Ismail, Malik

304

Laboratoire d'Identifi-cation et de modlisa-  

E-Print Network [OSTI]

Génie minéral, �cole Mohammadia d'ingénieurs, BP 765, Rabat-Agdal, MAROC Mohamed Faouzi et Abdelkader nappe phréatique des Beni-Amir (Tadla, Maroc) Les contacts IngénieriesN°27­p.23à36 Septembre2001 L e périmètre des Béni-Amir (Tadla) est l'un des plus anciens périmètres irrigués du Maroc. Sa première mise en

Boyer, Edmond

305

Ultrafast Extreme Ultraviolet Induced Isomerization of Acetylene Cations  

E-Print Network [OSTI]

PHYSICAL REVIEW LETTERS PRL 105, 263002 (2010) week endingAmerican Physical Society PRL 105, 263002 (2010) PHYSICALcould not be distinguished. PRL 105, 263002 (2010) PHYSICAL

Jiang, Y.

2012-01-01T23:59:59.000Z

306

Synthesis, characterization, anion complexation and electrochemistry of cationic Lewis acids  

E-Print Network [OSTI]

. Further reduction of 27• results in the formation of the borataalkene derivative [27]-, which features a formal B=C double bond. The structural changes accompanying the stepwise population of the B-C ?-bond are also determined, and this sequential...

Chiu, Ching-Wen

2009-05-15T23:59:59.000Z

307

The Cation-Interaction Stabilizing Interaction Between a  

E-Print Network [OSTI]

, 1814; Dougherty, et al. Science 1993 261, 1708. #12;The Electrostatic Model sp2 carbon is more Electrostatic Model sp2 carbon is more electronegative than hydrogen ab initio calculated electrostatic protein-coupled receptors for ACh, dopamine, epinephrine ... Cys-loop receptors bin

Stoltz, Brian M.

308

Phylogenetic Relationships within Cation Transporter Families of Arabidopsis1  

E-Print Network [OSTI]

, Michael W. Persans6 , David E. Salt6,7 *, Sun A Kim8 , and Mary Lou Guerinot8 Division of Biology, Cell

Sze, Heven

309

The Impacts of Cation Stoichiometry and Substrate Surface Quality...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dependent on our ability to controllably synthesize these materials in thin-fi lm form. Structure-property relationships are intimately tied to fi lm and interface...

310

Formal Development and Veri cation of Approximation Algorithms Using Auxiliary  

E-Print Network [OSTI]

Berghammer 1 and Markus Muller-Olm 2 1 Institut fur Informatik und Praktische Mathematik Universitat Kiel

Müller-Olm, Markus

311

HEAVY GOLD CLUSTER BEAMS production and identi cation  

E-Print Network [OSTI]

. This method is based on the acceleration of the clusters to high energy (MeV) and on the measurement, after to select heavy Aun cluster beams for applications at low energy (keV) in mass spectrometry. 1. Introduction, with a multianode detector 7], the number of constituents coming out of the foil. High energy clusters, accelerated

Boyer, Edmond

312

Synthesis of Cationic Extended Frameworks for Anion-Based Applications  

E-Print Network [OSTI]

low-activity waste (LAW) to separate the nuclear waste intolow-activity waste (LAW) to separate the nuclear waste into

Fei, Honghan

2012-01-01T23:59:59.000Z

313

Statistical Control of RBF-like Networks for Classi cation  

E-Print Network [OSTI]

by Platt in the main idea of the expanding the net- work. The statistical novel criterion is used The University of She eld, UK, e-mail: visakan@acse.shef.ac.uk Abstract. Incremental Net Pro (IncNet Pro. The architecture of the net is based on RBF networks. Extended Kalman Filter algorithm and its new fast version

Jankowski, Norbert

314

Characterization of Selective Binding of Alkali Cations with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

comprises a main chamber, detector, liquid microjet, skimmer, liquid nitrogen traps, turbo pumps, and a differential pump section (not shown here). A density functional theory...

315

Safety Veri cation for Automated Platoon A Case Study  

E-Print Network [OSTI]

appears in the motion of the cars. The combina- tion forms a hybrid system of considerable complexity that operate the vehicles, plus communication channels, is modeled formally, using the hybrid input cars operate under partial or total computer control.An important new e ort in this area

Lynch, Nancy

316

Synthesis of Cationic Extended Frameworks for Anion-Based Applications  

E-Print Network [OSTI]

11 Solid-State Dye-Sensitized Solar Cells from Polymer11. Solid-State Dye-Sensitized Solar Cells from Polymerof Gratzel type dye-sensitized solar cells and the Honda–

Fei, Honghan

2012-01-01T23:59:59.000Z

317

Characterizations of Cation/H+ Antiporters from Arabidopsis and Zebrafish  

E-Print Network [OSTI]

, Pittman et al., 2004). Although deletion of VCX1 does not cause considerable Ca2+ sensitivity, the deletion of both PMC1 and VCX1 genes leads to a greater sensitivity to Ca2+ than the loss of either gene alone, (Pozos et al., 1996) and Vcx1p is required...

Mei, Hui

2010-07-14T23:59:59.000Z

318

ammonium cations exert: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ground-water contamination, and natural remediation contributed to understanding of water-supply sustainability, ground-watersurface-water interactionsDetermination of the (...

319

Isolation of Two Agostic Isomers of an Organometallic Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

doi:10.1002anie.201305032 Authors: der van P Yang RM Bullock Capabilities: NMR and EPR Facility: Virtual Tour Science Theme: Biosystem Dynamics & Design Terrestrial &...

320

acyl pyridinium cation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 129 Visual Exploration of Uncertainty in...

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

alkali metal cations: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 279 Visual Exploration of Uncertainty in...

322

alkali metal cation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 279 Visual Exploration of Uncertainty in...

323

Combining Lazy Narrowing and Simpli cation ? Michael Hanus  

E-Print Network [OSTI]

with a complete operational semantics are based on narrowing. In order to avoid useless computations and to deal was supported in part by the German Ministry for Research and Technology (BMFT) under grant ITS 9103. Similarly to pure functional programming, such a lazy strat- egy avoids some useless steps in comparison

Hanus, Michael

324

Synthesis of Cationic Extended Frameworks for Anion-Based Applications  

E-Print Network [OSTI]

Tool. Utrecht, The Netherland, 2007. Darab, J. G. ; Smith,Tool. Utrecht, The Netherland, 2007. Cheetham, A. K. ; Rao,Tool. Utrecht, The Netherland, 2007. Darab, J. G. ; Smith,

Fei, Honghan

2012-01-01T23:59:59.000Z

325

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User Group and User ExecutiveCentralDepartmentSynchrotron

326

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User Group and User

327

Cation Defects and Conductivity in Transparent Oxides. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |with ZnO

328

Cation Intermixing And Electronic Deviations At The Insulating  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |with

329

Cation dopant distributions in nanostructures of transition-metal doped  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |withzeolite: an

330

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheir Atmospheric Impacts. | EMSL Organic

331

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheir Atmospheric Impacts. | EMSL

332

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheir Atmospheric Impacts. | EMSLCharacterization of

333

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheir Atmospheric Impacts. | EMSLCharacterization

334

Characterization of cation environments in polycrystalline forsterite by  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheir Atmospheric Impacts. |Characterization

335

Charge Localization in Cation-Sulfate Complexes: Implications for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheir AtmosphericAnalysisVents Using1

336

The University of California, Irvine The Department of Edu cation  

E-Print Network [OSTI]

is a useful tool for facilitating targeted instruction. In response to this demand for diagnostic tools Education Unhinging the Instructional Potential of a Language Test: Examining the Validity of a Large

Rose, Michael R.

337

Photoabsorption spectrum of helium trimer cation—Theoretical modeling  

SciTech Connect (OSTI)

The photoabsorption spectrum of He{sub 3}{sup +} is calculated for two semiempirical models of intracluster interactions and compared with available experimental data reported in the middle UV range [H. Haberland and B. von Issendorff, J. Chem. Phys. 102, 8773 (1995)]. Nuclear delocalization effects are investigated via several approaches comprising quantum samplings using either exact or approximate (harmonic) nuclear wavefunctions, as well as classical samplings based on the Monte Carlo methodology. Good agreement with the experiment is achieved for the model by Knowles et al., [Mol. Phys. 85, 243 (1995); Mol. Phys. 87, 827 (1996)] whereas the model by Calvo et al., [J. Chem. Phys. 135, 124308 (2011)] exhibits non-negligible deviations from the experiment. Predictions of far UV absorption spectrum of He{sub 3}{sup +}, for which no experimental data are presently available, are reported for both models and compared to each other as well as to the photoabsorption spectrum of He{sub 2}{sup +}. A simple semiempirical point-charge approximation for calculating transition probabilities is shown to perform well for He{sub 3}{sup +}.

Kalus, René [Centre of Excellence IT4Innovations and Department of Applied Mathematics, VSB-Technical University of Ostrava, 17. listopadu 15, 708 33 Ostrava (Czech Republic)] [Centre of Excellence IT4Innovations and Department of Applied Mathematics, VSB-Technical University of Ostrava, 17. listopadu 15, 708 33 Ostrava (Czech Republic); Karlický, František [Regional Centre of Advanced Technologies and Materials and Department of Physical Chemistry, Faculty of Science, Palacký University, T?. 17. listopadu 12, 771 46 Olomouc (Czech Republic)] [Regional Centre of Advanced Technologies and Materials and Department of Physical Chemistry, Faculty of Science, Palacký University, T?. 17. listopadu 12, 771 46 Olomouc (Czech Republic); Lepetit, Bruno [Laboratoire Collisions Agrégats Réactivité, IRSAMC and UMR5589 du CNRS, Université de Toulouse, UPS, 118 route de Narbonne, 31062 Toulouse Cedex (France)] [Laboratoire Collisions Agrégats Réactivité, IRSAMC and UMR5589 du CNRS, Université de Toulouse, UPS, 118 route de Narbonne, 31062 Toulouse Cedex (France); Paidarová, Ivana [J. Heyrovský Institute of Physical Chemistry, ASCR, v.v.i., Dolejškova 3, 182 23 Praha (Czech Republic)] [J. Heyrovský Institute of Physical Chemistry, ASCR, v.v.i., Dolejškova 3, 182 23 Praha (Czech Republic); Gadea, Florent Xavier [Laboratoire de Chimie et de Physique Quantiques, IRSAMC and UMR5626 du CNRS, Université de Toulouse, UPS, 118 route de Narbonne, 31062 Toulouse Cedex (France)] [Laboratoire de Chimie et de Physique Quantiques, IRSAMC and UMR5626 du CNRS, Université de Toulouse, UPS, 118 route de Narbonne, 31062 Toulouse Cedex (France)

2013-11-28T23:59:59.000Z

338

Cationic Main Group Compounds as Water Compatible Small Anion Receptors  

E-Print Network [OSTI]

acidity and fluoride affinity of the phosphonium boranes [13]+, [15]+, [16]+ and [17]+.* 0 0.6 3.5 4.5 5.5 6.5 7.5 8.5 9.5 pH Ab so rba nc e 3.5 5.5 7.5 9.5 0 0.6 Ab so rb an ce pH B P O H R Cpd pKR+ K (M -1) Me [13]+ 7.3 840 Et...-on sensors for cyanide anions Para-phenylene ammonium and phosphonium boranes display an even higher affinity for cyanide than fluoride ions. Indeed, while [12]+ does not show any affinity for fluoride anions in H2O/DMSO (6:4, v/v, HEPES 6 mM, pH 7...

Leamer, Lauren Anne

2013-05-06T23:59:59.000Z

339

The Impacts of Cation Stoichiometry and Substrate Surface Quality on  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 and NbSe2DifferentThe FiveD. TheNucleation, Structure,

340

The Impacts of Cation Stoichiometry and Substrate Surface Quality on  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 and NbSe2DifferentThe FiveD. TheNucleation,

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Two different cationic positions in Cu-SSZ-13? . | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof Energy Two CompaniesTwo Studies Reveal DetailsTwo

342

Coverage Dependent Charge Reduction of Cationic Gold Clusters on Surfaces  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases on &gamma;-Al2O3. |ID#:SynchrotronComplexes:4anPrepared Using

343

Comproportionation of Cationic and Anionic Tungsten Complexes Having an  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New SubstationCleanCommunity InvolvementCompositional VariationCompressed

344

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions andData andFleetEngineering Of Radiation Tolerant SiliconStudied

345

Study of Ion Specific Interactions of Alkali Cations with Dicarboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline Gallium Oxide ThinIon Cooling and Ejection from Two Stage

346

Is Dissociation of Peptide Radical Cations an Ergodic Process? | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign In About | Careers

347

Isolation of Two Agostic Isomers of an Organometallic Cation: Different  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign In About

348

ENERGY COMMISSION APPL.lCATION FOR SOURCE MATERIAL LICENSE  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$0.C. 20545*. . : '* FEB1 Rev.DATAEL- 019 MDP-02

349

EURIS, a Speci cation Method for Distributed Interlockings  

E-Print Network [OSTI]

system; UniS- pec 1 Introduction The control and management of a railway system consists of three is a medium between the infrastructure at the one side, and the logistic layer and its interfaces at the other side. Part of the checks on safety may be performed in the logistic layer, but the ultimate

Grant, P. W.

350

Cationic disorder and Mn{sup 3+}/Mn{sup 4+} charge ordering in the B? and B? sites of Ca{sub 3}Mn{sub 2}NbO{sub 9} perovskite: a comparison with Ca{sub 3}Mn{sub 2}WO{sub 9}  

SciTech Connect (OSTI)

We describe the preparation, crystal structure determination, magnetic and transport properties of two novel Mn-containing perovskites, with a different electronic configuration for Mn atoms located in B site. Ca{sub 3}Mn{sup 3+}{sub 2}WO{sub 9} and Ca{sub 3}Mn{sup 3+/4+}{sub 2}NbO{sub 9} were synthesized by standard ceramic procedures; the crystallographic structure was studied from X-ray powder diffraction (XRPD) and neutron powder diffraction (NPD). Both phases exhibit a monoclinic symmetry (S.G.: P2{sub 1}/n); Ca{sub 3}Mn{sub 2}WO{sub 9} presents a long-range ordering over the B sites, whereas Ca{sub 3}Mn{sub 2}NbO{sub 9} is strongly disordered. By “in-situ” NPD, the temperature evolution of the structure study presents an interesting evolution in the octahedral size (?Mn–O?) for Ca{sub 3}Mn{sub 2}NbO{sub 9}, driven by a charge ordering effect between Mn{sup 3+} and Mn{sup 4+} atoms, related to the anomaly observed in the transport measurements at T?160 K. Both materials present a magnetic order below T{sub C}=30 K and 40 K for W and Nb materials, respectively. The magneto-transport measurements display non-negligible magnetoresistance properties in the paramagnetic regime. - Graphical abstract: Comparison between the octahedron size and the magnetic behaviour for Ca{sub 3}Mn{sub 2}NbO{sub 9} in the temperature region where the charge and magnetic order occur. Display Omitted - Highlights: • Two novel Mn-containing double perovskites were obtained by solid-state reactions. • Both double perovskites are monoclinic (P2{sub 1}/n) determined by XRPD and NPD. • Ca{sub 3}Mn{sub 2}WO{sub 9} contains Mn{sup 3+} while Ca{sub 3}Mn{sub 2}NbO{sub 9} includes mixed-valence cations Mn{sup 3+}/Mn{sup 4+}. • Ca{sub 3}Mn{sub 2}NbO{sub 9} presents a charge-ordering effect between Mn{sup 3+} and Mn{sup 4+} evidenced by NPD. • The magnetic and transport studies evidenced the charge ordering in Ca{sub 3}Mn{sub 2}NbO{sub 9}.

López, C.A., E-mail: calopez@unsl.edu.ar [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Saleta, M.E. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Pedregosa, J.C. [INTEQUI-Área de Química General e Inorgánica “Dr. G. F. Puelles”, Facultad de Química, Bioquímica y Farmacia, Universidad Nacional de San Luis, Chacabuco y Pedernera, 5700 San Luis (Argentina); Sánchez, R.D. [Centro Atómico Bariloche, Comisión Nacional de Energía Atómica and Instituto Balseiro, Universidad Nacional de Cuyo, 8400S.C. de Bariloche, Río Negro (Argentina); Alonso, J.A. [Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, E-28049 Madrid (Spain); and others

2014-02-15T23:59:59.000Z

351

Favorable Geochemistry from Springs and Wells in COlorado  

SciTech Connect (OSTI)

Citation Information: Originator: Geothermal Development Associates, Reno Nevada Originator: United States Geological Survey (USGS) Originator: Colorado Geological Survey Publication Date: 2012 Title: Favorable Geochemistry Edition: First Publication Information: Publication Place: Reno Nevada Publisher: Geothermal Development Associates, Reno, Nevada Description: This layer contains favorable geochemistry for high-temperature geothermal systems, as interpreted by Richard "Rick" Zehner. The data is compiled from the data obtained from the USGS. The original data set combines 15,622 samples collected in the State of Colorado from several sources including 1) the original Geotherm geochemical database, 2) USGS NWIS (National Water Information System), 3) Colorado Geological Survey geothermal sample data, and 4) original samples collected by R. Zehner at various sites during the 2011 field season. These samples are also available in a separate shapefile FlintWaterSamples.shp. Data from all samples were reportedly collected using standard water sampling protocols (filtering through 0.45 micron filter, etc.) Sample information was standardized to ppm (micrograms/liter) in spreadsheet columns. Commonly-used cation and silica geothermometer temperature estimates are included. Spatial Domain: Extent: Top: 4515595.841032 m Left: 149699.513964 m Right: 757959.309388 m Bottom: 4104156.435530 m Contact Information: Contact Organization: Geothermal Development Associates, Reno, Nevada Contact Person: Richard “Rick” Zehner Address: 3740 Barron Way City: Reno State: NV Postal Code: 89511 Country: USA Contact Telephone: 775-737-7806 Spatial Reference Information: Coordinate System: Universal Transverse Mercator (UTM) WGS’1984 Zone 13N False Easting: 500000.00000000 False Northing: 0.00000000 Central Meridian: -105.00000000 Scale Factor: 0.99960000 Latitude of Origin: 0.00000000 Linear Unit: Meter Datum: World Geodetic System 1984 (WGS ’1984) Prime Meridian: Greenwich Angular Unit: Degree Digital Form: Format Name: Shape file

Zehner, Richard E.

2012-02-01T23:59:59.000Z

352

Charge trapping by anionic quinones electrostatically bound to a highly charged cationic quinone-viologen polymer or a cationic poly(3-viologen-thiophene)  

SciTech Connect (OSTI)

Charge associated with quinone reduction is trapped at low pH in systems composed of sulfonated anthraquinones electrostatically bound to a polymer derived from a monomer consisting of a quinone unit flanked by two viologen units. Each monomer repeat unit carries 6 equiv of positive charge which can be charge compensated by monosulfonated anthraquinone to yield a quinone-viologen ratio of nearly 7:2. At low pH, electrostatic binding is persistent, and the amount of trapped charge is 90% of the theoretical maximum. Some of the electrostatically bound quinine can be replaced with Fe(CN)[sub 6][sup 3[minus

Hable, C.T.; Crooks, R.M.; Valentine, J.R.; Giasson, R.; Wrighton, M.S. (Massachusetts Inst. of Technology, Cambridge (United States))

1993-06-03T23:59:59.000Z

353

Mobility of singly-charged lanthanide cations in rare gases: Theoretical assessment of the state specificity  

SciTech Connect (OSTI)

High quality, ab initio calculations are reported for the potential energy curves governing the interactions of four singly-charged lanthanide ions (Yb{sup +}, Eu{sup +}, Lu{sup +}, and Gd{sup +}) with the rare gases (RG = He–Xe). Scalar-relativistic coupled cluster calculations are used for the first three S-state ions, but for Gd{sup +}({sup 10}D°) it is necessary to take the interaction anisotropy into account with the help of the multi-reference technique. The potential energy curves are used to determine the ion mobility and other transport properties describing the motion of the ions through the dilute RG, both as functions of the temperature, T, in the low-field limit, and at fixed T as functions of the ratio of the electrostatic field strength to the gas number density, E/N. The calculated mobilities are in good agreement with the very limited experimental data that have become available recently. The calculations show a pronounced dependence of the transport properties on the electronic configuration of the ion, as well as a significant effect of the spin-orbit coupling on the transport properties of the Gd{sup +} ion, and predict that state-specific mobilities could be detectable in Gd{sup +}–RG experiments.

Buchachenko, Alexei A., E-mail: alexei@classic.chem.msu.su [Institute of Problems of Chemical Physics RAS, Chernogolovka, Moscow District 142432, Russia and Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow 119991 (Russian Federation); Viehland, Larry A., E-mail: viehland@chatham.edu [Science Department, Chatham University, Pittsburgh, Pennsylvania 15232 (United States)

2014-03-21T23:59:59.000Z

354

Low dimensionality spectral sensing for low cost material discrimination and identi cation  

E-Print Network [OSTI]

.6 Light Emitting Diodes as Detectors . . . . . . . . . . . . . . . . . . . . . . . . . . 32 3.7 Other

Bove Jr., V. Michael

355

Special Effect of -Cyclodextrin on the Aggregation Behavior of Mixed Cationic/Anionic Surfactant Systems  

E-Print Network [OSTI]

and a following micelle-to-vesicle transition, which in turn greatly influences the viscosity and absorbance can be employed to load substances into the inner pool of the vesicles or to reconstitute membrane, metal ions, or organic additives,10 they are rather system-dependent and do not follow a general rule

Huang, Jianbin

356

Spectroscopic characterization of water-soluble cationic porphyrins in sol–gel silica matrices and coatings  

E-Print Network [OSTI]

range up to 10?5 M. The deviation from the linearity of Beer–Lambert law starts with porphyrin concentration about 5×10?6 M. The dimerization constants were estimated. The similar dependence could be observed for the aerogels and the solid thin films. © 2002 Elsevier Science B.V. All rights reserved.

Joanna Dargiewicz; Magdalena Makarska

2001-01-01T23:59:59.000Z

357

ANION AND CATION CHANNELS IN THE THYLAKOID MEMBRANE 1.1. Pottosin & G. Schonknecht  

E-Print Network [OSTI]

. The open probability of a particular ion channel was calculated as the relative time spent in the open.5 in the bath, in the patch pipette 100 rnM KCl was substituted by 15 rnM KCl). Under these conditions the net current through a permselective ion channel at zero voltage has an amplitude different from zero. The sign

Schönknecht, Gerald

358

Enhanced Charge-Transfer Kinetics by Anion Surface Modi cation of Kyu-Sung Park,,  

E-Print Network [OSTI]

electric vehicles o er not only a distributed energy store, which can make the cost of battery storage more

Henkelman, Graeme

359

StrainBased In Situ Study of Anion and Cation Insertion into...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrodes with Different Pore Sizes Jennifer M. Black , Guang Feng ,* Pasquale F. Fulvio , Patrick C. Hillesheim , Sheng Dai , Yury Gogotsi , Peter T. Cummings , Sergei V....

360

Can Research on Science Learnin2-and Instruction Inform Standards for Science Ed~cation'.)'~  

E-Print Network [OSTI]

that we believe can mform the reform process. In particular. to reach all science students and also impart;Linn er a:-; A broad xray of organizations are parnciping in an effort to reform science education-based reform with the refoms of the 1 9 6 0 ' ~\\re discuss; (a) science course goals. t b) the social nature

Boyer, Edmond

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Antimicrobial Activity of Cationic Antiseptics in Layer-by-Layer Thin Film Assemblies  

E-Print Network [OSTI]

Layer-by-layer (LbL) assembly has proven to be a powerful technique for assembling thin films with a variety of properties including electrochromic, molecular sensing, oxygen barrier, and antimicrobial. LbL involves the deposition of alternating...

Dvoracek, Charlene M.

2010-07-14T23:59:59.000Z

362

Allene and pentatetraene cations as models for intramolecular charge transfer: Vibronic coupling Hamiltonian and conical intersections  

E-Print Network [OSTI]

The vibrational energy level structure of various ionized and neutral molecules has been studied by valence photo of the ab initio adiabatic potential energy surfaces along all nuclear degrees of freedom, including points and use the more involved third-order algebraic diagrammatic construction method to include intersections

Markmann, Andreas

363

Lubricants or lubricant additives composed of ionic liquids containing ammonium cations  

DOE Patents [OSTI]

A lubricant or lubricant additive is an ionic liquid alkylammonium salt. The alkylammonium salt has the structure R.sub.xNH.sub.(4-x).sup.+,[F.sub.3C(CF.sub.2).sub.yS(O).sub.2].sub.2N.sup- .- where x is 1 to 3, R is independently C.sub.1 to C.sub.12 straight chain alkyl, branched chain alkyl, cycloalkyl, alkyl substituted cycloalkyl, cycloalkyl substituted alkyl, or, optionally, when x is greater than 1, two R groups comprise a cyclic structure including the nitrogen atom and 4 to 12 carbon atoms, and y is independently 0 to 11. The lubricant is effective for the lubrication of many surfaces including aluminum and ceramics surfaces.

Qu, Jun (Knoxville, TN) [Knoxville, TN; Truhan, Jr.,; John J. (Cookeville, TN) [Cookeville, TN; Dai, Sheng (Knoxville, TN) [Knoxville, TN; Luo, Huimin (Knoxville, TN) [Knoxville, TN; Blau, Peter J. (Knoxville, TN) [Knoxville, TN

2010-07-13T23:59:59.000Z

364

E-Print Network 3.0 - alkaline-earth metal cations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

K. (2002): A novel group of alkaline earth metal amides: synthesis... ): Not just heavy "Grignards": Recent advances in the organometallic chemistry of the alkaline earth...

365

Photoinduced Electron Transfer Reactions of Highly Conjugated Thiophenes for Initiation of Cationic Polymerization and Conjugated  

E-Print Network [OSTI]

of Polymer Science and Technology, Department of Chemistry, The Center for Solar Energy Research, and microlithography due to several advantages.4 Onium salts such as iodonium,5 sulfonium,6 phosphonium,7 ammonium,8

Turro, Nicholas J.

366

Neutral and Cationic Main Group Lewis Acids - Synthesis, Anion Complexation and Redox Properties  

E-Print Network [OSTI]

,8- naphthalenediyl scaffold. After discovering a route to a new dilithio reagent, silicon based derivatives featuring R3Si-F->CR3 + and R3C-H->SiFR3 interactions of 2.703(2) and 2.32(2) Angstrom respectively were successfully synthesized and fully characterized...

Dorsey, Christopher L.

2010-07-14T23:59:59.000Z

367

ELSEVIER Chemical Physics 189 ( 1994) 335-341 Absorption spectra of conjugated hydrocarbon cation chains  

E-Print Network [OSTI]

&H: systems (k = 4-16) isolated in neon matrices at 5 K have been measured in the visible and near infrared by waveguide (as displayed) or by a single-reflection Fourier- transform technique. of H

Maier, John Paul

368

Tracking transmitter-gated P2X cation channel activation in vitro and in vivo  

E-Print Network [OSTI]

channels that show calcium fluxes. We genetically engineered rat P2X receptors to carry calcium sensors, comprising the Cys-loop, glutamate and P2X receptor families1, collectively underlie excitatory fast synaptic

Newman, Eric A.

369

High-Temperature Elasticity, Cation Disorder and Magnetic Transition in Magnesioferrite  

SciTech Connect (OSTI)

The elastic moduli of magnesioferrite spinel, MgFe2O4, and their temperature dependence have been determined for the first time by ultrasonic measurements on a polycrystalline specimen. The measurements were carried out at 300 MPa and to 700 C in a gas-medium high-pressure apparatus. On heating, both the elastic bulk (K S) and shear (G) moduli decrease linearly to 350 C. By combining with extant thermal-expansion data, the values for the room-temperature K S and G, and their temperature derivatives are as follows: K 0 = 176.3(7) GPa, G 0 = 80.1(2) GPa, ({partial_derivative}K S/{partial_derivative}T) P = -0.032(3) GPa K-1 and ({partial_derivative}G/{partial_derivative}T) P = -0.012(1) GPa K-1. Between 350 and 400 C, there are abrupt increases of 1.4% in both of the elastic moduli; these closely coincide with the magnetic Curie transition that was observed by thermal analyses at about 360 C.

Antao,S.; Jackson, I.; Li, B.; Kung, J.; Chen, J.; Hassan, I.; Liebermann, R.; Parise, J.

2007-01-01T23:59:59.000Z

370

E-Print Network 3.0 - alcali metal cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vincent J. Camobreco... 161:740-750 1996 ABSTRACT Soils accumulate heavy metals when sewage sludge is applied to land... -borne metals could represent if mobilized, many...

371

E-Print Network 3.0 - acidic cation-exchange resin Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine 7 2114 J. Phys. Chem. 1989, 93, 2114-2180 FKN mechanism of the BZ reaction (expanded "Oregonator") Summary: -Zhabotinsky (BZ) reaction in which the ferroin catalyst...

372

Classi cation and Characterization of Objects from the GALEX and SDSS surveys  

E-Print Network [OSTI]

internal re- lease, matched to the SDSS catalogs in the overlapping regions, to classify objects@ipac.caltech.edu) 9 Laboratory for Astronomy and Solar Physics, NASA Goddard Space Flight Center, Greenbelt, MD 20771

Bianchi, Luciana

373

Summer school MOVEP 2002 MOdelling and VEri cation of parallel Processes  

E-Print Network [OSTI]

checking and program analysis", Markus Mueller-Olm (University of Dortmund) 2. \\Model checking in#12;nite

Ryan, Mark

374

E-Print Network 3.0 - aqueous solution cation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mountain Project, US EPA Collection: Environmental Sciences and Ecology 9 Definitions CaX(s) + 90 Summary: adsorption reaction in which an aqueous species exchanges with an...

375

Towards automatic cell identi cation in DIC microscopy , C.A. Glasbey2y  

E-Print Network [OSTI]

1998. Journal of Microscopy, 192, 186-193. #12;a b c Figure 1: DIC microscope images: a Chlorella algal

Stone, J. V.

376

Accurate and Reliable Cancer Classi cation Based on Pathway-Markers and Subnetwork-Markers  

E-Print Network [OSTI]

patients. In fact, gene markers identified in independent studies often do not coincide with each other, suggesting that many of the predicted markers may have no biological significance and may be simply artifacts of the analyzed dataset. To nd more...

Su, Junjie

2012-02-14T23:59:59.000Z

377

E-Print Network 3.0 - antimonate cation exchanger Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

resembled that of arsenate with an initial linear ac- cumulation Source: Hammock, Bruce D. - Department of Entomology, University of California, Davis Collection:...

378

Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy  

E-Print Network [OSTI]

spectra measured for aqueous formate and acetate solutions containing lithium, sodium, and potassium 290 eV clearly indicate a preferential interaction of sodium versus potassium, which was less apparent interactions aqueous systems The discovery of the selective interactions between simple ions and proteins dates

Cohen, Ronald C.

379

On the classi cation of nuclear C -algebras Marius Dadarlat S ren Eilers  

E-Print Network [OSTI]

, 1991. [24] G.G. Kasparov, Hilbert C #3; -modules: Theorems of Stinespring and Voiculescu, J. Operator

Eilers, Søren

380

Interactions between acidic polysaccharides and trivalent cations: their effect on intestinal dietary cholesterol absorption  

E-Print Network [OSTI]

of alum (baking powder), (200 mg Al), a quick bread made with alum and a pectin preserve. Analyses of the serum cholesterol snd triglyceride concentzations were run on a Technicon SNAC System 18 provided by Dr, F. Gyorkey at the V ~ A. Hosp1tal...

Bradbury, Elizabeth Louise

1978-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Maximizing gene delivery efficiencies of cationic helical polypeptides via balanced membrane penetration and cellular targeting  

E-Print Network [OSTI]

/parallel synthesis that creates a large library of materials and allows identification of the best. Gabrielson, Hua Lu, Jianjun Cheng* Department of Materials Science and Engineering, University of Illinois of the gene cargos, it meanwhile causes severe associated cytotoxicities [7e9]. Excessive positive charges can

Cheng, Jianjun

382

E-Print Network 3.0 - aromatic hydrocarbon cations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

... Source: Canberra, University of - Institute for Applied Ecology Collection: Environmental Sciences and Ecology 6 Dr. Shu Tao, ProfessorEnvironmental Geography and...

383

Characterization of plant cation/h+ antiporters and how they can impact nutrition  

E-Print Network [OSTI]

modulation by Ca 2+ or metabolites (Davenport, 2002). In Arabidopsis, approximately 20 GLRs were identified with homology to animal GLRs (Lacombe et al., 2001). The general structure of GLR contains two glutamate binding domains and a PM signal sequence.... There are 3 main groups of GLRs: GLR1, GLR2 and GLR3. Within each of these groups different loci are given different names. For example, previous names like GLR2 and GLR6 are now termed AtGLR3.1 and AtGLR3.5 (Lacombe et al., 2001). This nomenclature...

Morris, James Larry

2009-05-15T23:59:59.000Z

384

Interactive, Domain-Independent Identi cation and Summarization of Topically Related News  

E-Print Network [OSTI]

selects a single news story from a news Web site. Our system then searches other live sources of news. In addition, our system automatically locates topically-related stories on a large number of real-time search engines. 2 The NewsInEssence System 2.1 Topic-focused search Overview. Our system's topic-focused search

Radev, Dragomir R.

385

of the high-temperature structural modifi-cations of iron between 30 and 60 GPa.  

E-Print Network [OSTI]

. Geophys. Res., in press. 2. J. M. Brown and R. G. McQueen, ibid. 91, 7485 (1986). 3. R. Boehler, Geophys, 1312 (1993); S. K. Saxena et al., ibid. 269, 1703 (1995). 5. C. S. Yoo, J. Akella, A. J. Campbell, H. K)]. 8. As mentioned in previous reports [D. L. Heinz, Geo- phys. Res. Lett. 17, 1161 (1990); see (6

Madariaga, Raúl

386

The Role of Basis Set Superposition Error in Water Addition Reactions to Ln(III) Cations  

SciTech Connect (OSTI)

Our goal in this work was to characterize the importance of basis set superposition error (BSSE) in the reaction energetics of water addition to highly charged metal ions that exhibit strong ion-dipole interactions with water. The gas phase water addition reactions, M(H?O)³+N + H?O ? M(H?O)³+N ? ? [M = La(III), Lu(III); N = 0–8] have been studied, with a particular emphasis on a posteriori methods for calculating BSSE and its constituent energetic components as a function of M(H?O) ³+N cluster size and water basis set. Because of accumulation of BSSE within the subclusters in the reaction series, the successive reaction counterpoise method for determining the BSSE correction interaction energies is advocated.

Kvamme, Brandon; Wander, Matthew C F.; Clark, Aurora E.

2009-06-01T23:59:59.000Z

387

Journal of Contemporary Water researCh & eduCationUCOWR Geomorphology and Restoration Ecology  

E-Print Network [OSTI]

Ecology David R. Montgomery Quaternary Research Center and Department of Earth & Space Sciences University of restoration ecology? I have struggled with this question over the past of the potential for geomorphology to contribute to restoration ecology requires conceptual and educational shifts

Montgomery, David R.

388

III Fiuiice 4 (1994) 443-455 MARCH 1994, PAGE 443 CIM~,f,cation  

E-Print Network [OSTI]

-i-I 81.60J 81.70 82.30 Etude des paramktres de vieillissement d'un systkme d'isolation film PETP, prd,enient lePETP) et'humiditd apparait comme le facteur Ie plu~ important de ddgradation du PETP. Abstract. A study of polyethylene

Paris-Sud XI, Université de

389

a-site cation ordering: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 102 Visual Exploration of Uncertainty in...

390

a-site cation deficiency: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 87 Visual Exploration of Uncertainty in...

391

Role of Specific Cations and Water Entropy on the Stability of Branched DNA Motif Structures  

E-Print Network [OSTI]

energy barrier is dominated by entropic effects that result from the decreased surface area, Bangalore, India 560012 Division of Immunology, Beckman Research Institute of the City of Hope, Duarte computer simulations in explicit water and salt on a model TWJ and use free energy calculations to quantify

Goddard III, William A.

392

Paramagnetic Suseptibilities and Electronic Structure of Aqueous Cations of Elements 92 to 95  

E-Print Network [OSTI]

plutonium, and americium solutions was dissolution of aplu- The neptunium and americium solutions were assayed byThe neptunium and americium were available for this study

Howland, Jerome J.; Calvin, Melvin

2008-01-01T23:59:59.000Z

393

E-Print Network 3.0 - actinide iii cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Actinide(III) 2.26x10-7 log f(CO2) -5.50 Actinide(IV) 5.66x10... Actinide(III) case: Americium in WIPP Brine 12;Figure 2 Actinide(V) case: Neptunium in WIPP Brine 12... November...

394

E-Print Network 3.0 - anion-cation permeability correlates Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering 16 1 Copyright 2010 by ASME Proceedings of ASME 2010 3rd Joint US-European Fluids Engineering Summer Meeting and 8th Summary: orientations, they proposed two...

395

Analysis of Mixture Models using Expected Posterior Priors, with Application to Classi cation  

E-Print Network [OSTI]

of Gamma Ray Bursts Jos#19;e M. P#19;erez and James O. Berger #3; Abstract Consider observations when the number of components is un- known. An application is considered involving Gamma Ray Bursts of the number of classes of Gamma Ray Bursts (Meegan et al. , 1995). 1.1 Notation Consider the #12;nite mixture

Berger, Jim

396

New electrolyte systems for capillary zone electrophoresis of metal cations and non-ionic organic compounds  

SciTech Connect (OSTI)

Excellent separations of metal ions can be obtained very quickly by capillary electrophoresis provided a weak complexing reagent is incorporated into the electrolyte to alter the effective mobilities of the sample ions. Indirect photometric detection is possible by also adding a UV-sensitive ion to the electrolyte. Separations are described using phthalate, tartrate, lactate or hydroxyisobutyrate as the complexing reagent. A separation of twenty-seven metal ions was achieved in only 6 min using a lactate system. A mechanism for the separation of lanthanides is proposed for the hydroxyisobutyrate system.

Shi, Y.

1995-06-19T23:59:59.000Z

397

E-Print Network 3.0 - actinide metal cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluorescence image... , cwalsby@sfu.ca Anticancer Metallodrugs. A number of transition-metal containing compounds have shown high Source: Simon Fraser University, School of...

398

Z .Chemical Geology 158 1999 189202 Bacterial effects on the mobilization of cations from a weathered  

E-Print Network [OSTI]

. The mobility of the Pb associated with these iron oxides was less than that of other heavy metals that were .matrix Wang et al., 1995 . Irreversible sorption or precipitation of heavy metals onto subsurface min toxicity of the metal remains. Metal release is likel

Dorn, Ron

399

Stabilization of the aspartate 15- alanine mutant of Ribonuclease T1 by cation binding  

E-Print Network [OSTI]

studies (Yutani et al. , 1987; Matsumura et al. , 1988a, b; Eriksson et al. , 1992; Kellis et al. , 1989; Shortie et al. , 1990; Sandberg & Terwiliger, 1991), in which a larger side-chain was replaced by one that is smaller. He concluded...

Farag, Deborah June

1993-01-01T23:59:59.000Z

400

E-Print Network 3.0 - advanced nano-composite cation-exchanger...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of deformation and damage evolution from DD simulations; Application of the CREEP code to ODS and nano-composited Source: Ghoniem, Nasr M. - Department of Materials...

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Cation Movements during Dehydration and NO2 Desorption in a Ba-Y,FAU  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |withzeolite: an in situ

402

Cationic Liposome-Microtuble Complexes: Lipid-Protein Bio-Nanotubles with  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . |withzeolite:Open or

403

Probing water properties and cationic exchange in calcium-silicate-hydrate : an atomistic modeling study  

E-Print Network [OSTI]

Two problems related to the assessment of the performance of cementitious materials in the nuclear fuel cycle are investigated by means of atomistic simulations. The first is the structural and dynamic nature of water ...

Youssef, Mostafa Youssef Mahmoud

2010-01-01T23:59:59.000Z

404

Atomistic Study of Doped BaCeO3: Dopant Site-Selectivity and Cation Nonstoichiometry  

E-Print Network [OSTI]

of Technology, Pasadena, California 91125, and Materials Chemistry Group, Chemistry DiVision, Uni, the trivalent dopants are assumed to occupy the Ce4+ -site, which introduces oxygen vacancies partitioning over both Ba and Ce sites. Such partitioning reduces the concentration of oxygen vacancies, which

Haile, Sossina M.

405

Evaluation of the field-scale cation exchange capacity of Hanford sediments  

E-Print Network [OSTI]

Richland, WA: CH2M Hill Hanford Group, Inc. Lichtner, P.C. &A.R. 2003. Estimation of Hanford SX tank waste compositionsS. 2003. Cesium migration in Hanford sediments: a multisite

Steefel, C.I.

2003-01-01T23:59:59.000Z

406

Ordering of cations in the voids of the anionic framework of the crystal structure of catapleiite  

SciTech Connect (OSTI)

The pseudohexagonal crystal structure of the mineral catapleiite Na{sub 1.5}Ca{sub 0.2}[ZrSi{sub 3}(O,OH){sub 9}] {center_dot} 2(H{sub 2}O,F) from the Zhil'naya Valley in the central part of the Khibiny alkaline massif (Kola Peninsula, Russia) is studied by X-ray diffraction (XCalibur-S diffractometer, R = 0.0346): a = 20.100(4), b = 25.673(5), and c = 14.822(3) A; space group Fdd2, Z = 32, and {rho}{sub calcd} = 2.76 g/cm{sup 3}. Fluorine atoms substituting part of H{sub 2}O molecules in open channels of the crystal structure have been found for the first time in the catapleiite composition by microprobe analysis. The pattern of distribution of Na and Ca atoms over the voids of the mixed anionic framework consisting of Zr-octahedra and three-membered rings of Si-tetrahedra accounts for the pronounced pseudoperiodicity along the a and c axes of the pseudohexagonal unit cell and for the lowering of crystal symmetry to the orthorhombic one. It is shown that part of the hydrogen atoms of water molecules is statistically disordered; their distribution correlates with the pattern of the population of large eight-vertex polyhedra by Na and Ca atoms.

Yakubovich, O. V., E-mail: yakubol@geol.msu.ru [Moscow State University, Faculty of Geology (Russian Federation); Karimova, O. V. [Russian Academy of Sciences, Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry (Russian Federation); Ivanova, A. G. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Yapaskurt, V. O. [Moscow State University, Faculty of Geology (Russian Federation); Chukanov, N. V. [Russian Academy of Sciences, Institute of the Problems of Chemical Physics (Russian Federation); Kartashov, P. M. [Russian Academy of Sciences, Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry (Russian Federation)

2013-05-15T23:59:59.000Z

407

The Effect of Temperature, Cations, and Number of Acyl Chains on the  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 and NbSe2Different Impacts of SO2Lamellar to

408

Role of cation choice in the radiation tolerance of pyrochlores. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 Resource ProgramEnergy InnovationSludgeWater in Methanolcation

409

Fragmentation of alpha-Radical Cations of Arginine-Containing Peptides. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds" Give FormsEnergy-ResolvedFormation.

410

Enhancing Cation-Exchange Capacity of Biochar for Soil Amendment and Global  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia NanoparticlesSmartAffects the Future Energy Mixmodifications .Carbon

411

Effects of Cesium Cations in Lithium Deposition via Self-Healing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed NewcatalystNeutronEnvironmentZIRKLE FRUITYearEffect0/2002 Yun

412

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles asSecond stage of the longwave ICRCCM3:ElseBased Redox

413

NMR Studies of Heat-Induced Transitions in Structure and Cation Binding  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Opticalhttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifAEnergy2014 SolidGoldEMSL

414

Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium Redox Flow  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutronStrategicOur MissionStructure and ReceptorStructure

415

Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutronStrategicOurStructureSurvivorBacterial(Fe3O4)

416

Are the Radical Centers in Peptide Radical Cations Mobile? The Generation,  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone by E-mailRadioimmunotherapyArchiveAre Earths Rare?

417

Synthesis, Characterization, to application of water soluble and easily removable cationic pressure sensitive adhesives  

SciTech Connect (OSTI)

In recent years, the world has expressed an increasing interest in the recycling of waste paper to supplement the use of virgin fiber as a way to protect the environment. Statistics show that major countries are increasing their use of recycled paper. For example, in 1991 to 1996, the U.S. increased its recovered paper utilization rate from 31% to 39%, Germany went from 50% to 60%, the UK went from 60% to 70%, France increased from 46% to 49%, and China went from 32% to 35% [1]. As recycled fiber levels and water system closures both increase, recycled product quality will need to improve in order for recycled products to compete with products made from virgin fiber [2]. The use of recycled fiber has introduced an increasing level of metal, plastic, and adhesive contamination into the papermaking process which has added to the complexity of the already overwhelming task of providing a uniform and clean recycle furnish. The most harmful of these contaminates is a mixture of adhesives and polymeric substances that are commonly known as stickies. Stickies, which enter the mill with the pulp furnish, are not easily removed from the repulper and become more difficult the further down the system they get. This can be detrimental to the final product quality. Stickies are hydrophobic, tacky, polymeric materials that are introduced into the papermaking system from a mixture of recycled fiber sources. Properties of stickies are very similar to the fibers used in papermaking, viz. size, density, hydrophobicity, and electrokinetic charge. This reduces the probability of their removal by conventional separation processes, such as screening and cleaning, which are based on such properties. Also, their physical and chemical structure allows for them to extrude through screens, attach to fibers, process equipment, wires and felts. Stickies can break down and then reagglomerate and appear at seemingly any place in the mill. When subjected to a number of factors including changes in pH, temperature, concentration, charge, and shear forces, stickies can deposit [3]. These deposits can lead to decreased runnability, productivity and expensive downtime. If the stickie remains in the stock, then machine breaks can be common. Finally, if the stickie is not removed or deposited, it will either leave in the final product causing converting and printing problems or recirculate within the mill. It has been estimated that stickies cost the paper industry between $600 and $700 million a year due to the cost of control methods and lost production attributed to stickies [3]. Also, of the seven recycling mills opened in the United States between 1994 and 1997, four have closed citing stickies as the main reason responsible for the closure [4]. Adhesives are widely used throughout the paper and paperboard industry and are subsequently found in the recycled pulp furnish. Hodgson stated that even the best stock preparation process can only remove 99% of the contaminants, of which the remaining 1% is usually adhesives of various types which are usually 10-150 microns in effective diameter [5]. The large particles are removed by mechanical means such as cleaners and screens, and the smaller, colloidal particles can be removed with washing. The stickies that pass through the cleaning and screening processes cause 95% of the problems associated with recycling [6]. The cleaners will remove most of the stickies that have a density varying from the pulp slurry ({approx}1.0 g/cm3) and will accept stickies with densities ranging from 0.95-1.05 g/cm3 [2]. The hydrophobicity of the material is also an important characteristic of the stickie [7]. The hydrophobicity causes the stickies to agglomerate with other hydrophobic materials such as other stickies, lignin, and even pitch. The tacky and viscous nature of stickies contributes to many product and process problems, negatively affecting the practicality of recycled fiber use. The source of stickies that evade conventional removal techniques are usually synthetic polymers, including acrylates, styrene butadiene rub

Institute of Paper Science Technology

2004-01-30T23:59:59.000Z

418

Delivery of cationic polymer-siRNA nanoparticles for gene therapies in neural regeneration  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Nogo receptor can inhibit growth of injured axons, thus affecting neural regeneration. Black-Right-Pointing-Pointer The delivery of siRNA is crucial to inhibit NgR expression in NSCs. Black-Right-Pointing-Pointer Non-viral vector PEG-PEI condensed siRNA targeting NgR into nanoscale particles. Black-Right-Pointing-Pointer PEG-PEI/siRNA at N/P = 15 displayed high transfection efficiency and low cytotoxicity. Black-Right-Pointing-Pointer PEG-PEI has great potential in carrying siRNA to diminish the gene expression in NSCs. -- Abstract: The therapeutic applications of neural stem cells (NSCs) have potential to promote recovery in many obstinate diseases in central nervous system. Regulation of certain gene expressions using siRNA may have significant influence on the fate of NSC. To achieve the optimum gene silencing effect of siRNA, non-viral vector polyethylene glycol-polyethyleneimine (PEG-PEI) was investigated in the delivery of siRNA to NSCs. The characteristics of PEG-PEI/siRNA polyplexes were detected by scanning electron microscopy (SEM). The effects of nanoparticles on cell viability were measured via CCK-8 assay. In addition, the transfection efficiency was evaluated by fluorescence microscope and flow cytometry, and real-time PCR and Western Blot were employed to detect the gene inhibition effect of siRNA delivered by PEG-PEI. The SEM micrographs showed that PEG-PEI could condense siRNA to form diffuse and spherical nanoparticles. The cytotoxicity of PEG-PEI/siRNA nanocomplexes (N/P = 15) was significantly lower when compared with that of Lipofectamine 2000/siRNA (P < 0.05). Moreover, the highest transfection efficiency of PEG-PEI/siRNA nanoparticles was obtained at an N/P ratio of 15, which was better than that achieved in the transfection using Lipofectamine 2000 (P < 0.05). Finally, the gene knockdown effect of PEG-PEI/siRNA nanoparticles was verified at the levels of mRNA and protein. These results suggest that PEG-PEI may potentially be used as a siRNA delivery vector for neural regeneration therapy.

Liang, Yanran [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China)] [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China); Liu, Zhonglin, E-mail: zhonglinliu@126.com [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China)] [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China); Shuai, Xintao; Wang, Weiwei [School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China (China)] [School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China (China); Liu, Jun [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China)] [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China); Bi, Wei [Department of Neurology, The First Affiliated Hospital of Jinan University, No. 613, West Huangpu Road, Guangzhou 510630, People's Republic of China (China)] [Department of Neurology, The First Affiliated Hospital of Jinan University, No. 613, West Huangpu Road, Guangzhou 510630, People's Republic of China (China); Wang, Chuanming; Jing, Xiuna; Liu, Yunyun [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China)] [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China); Tao, Enxiang, E-mail: taoenxiang@yahoo.com.cn [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China)] [Department of Neurology, Sun Yat-Sen Memorial Hospital of Sun Yat-Sen University, No. 107, West Yanjiang Road, Guangzhou 510120, People's Republic of China (China)

2012-05-18T23:59:59.000Z

419

E-Print Network 3.0 - alkaline cations complexation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

treatment in aerobic ponds and wetlands. RAPS ... Source: Kirby, Carl S. - Department of Geology, Bucknell University Collection: Geosciences 19 Simulation of reactive transport...

420

Experimental determination of CePO4 and YPO4 solubilities in H2ONaF at 800C and 1 GPa: implications for rare earth  

E-Print Network [OSTI]

: implications for rare earth element transport in high-grade metamorphic fluids P. TROPPER1 , 2 , C. E. MANNING2. They host signifi- cant rare earth elements (REE) and are useful for geochronology and geothermometry, so that Y, and by extension heavy rare earth elements (HREE), can be fractionated from LREE in fluorine

Manning, Craig

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Chemical, multi-isotopic (Li-B-Sr-U-H-O) and thermal characterization of Triassic formation waters from the Paris Basin  

E-Print Network [OSTI]

of around 45 to 50°C. The study of uranium activity ratios for these Triassic formation waters allows us, uranium isotopes, oxygen isotopes, hydrogen isotopes, geothermometry, Trias, Paris Basin 1 hal-00563924,version1-7Feb2011 Author manuscript, published in "Chemical Geology 283, 3-4 (2011) 226-241" DOI : 10

Boyer, Edmond

422

PROCEEDINGS, Twenty-Seventh Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 28-30, 2002  

E-Print Network [OSTI]

probably by the drilling fluid. When applied on all these fluids, numerous chemical geothermometers yield. On the three bore-holes drilled by CFG in this area, only the bore-hole located more at north (Californie bore-hole) and near the old LA-101 bore- hole, indicated the presence of inflows of hot fluid close to 90°C starting

Boyer, Edmond

423

Proceedings World Geothermal Congress 2005 Antalya, Turkey, 24-29 April 2005  

E-Print Network [OSTI]

Proceedings World Geothermal Congress 2005 Antalya, Turkey, 24-29 April 2005 1 Geothermal: Martinique, geothermal exploration, thermal springs, soil gas profiles, chemical geothermometers ABSTRACT in starting again geothermal research on the Martinique island, in the Lesser Antilles. The first works, which

Paris-Sud XI, Université de

424

The solubility of natural quartz sand at 100?C, and 150?C, 345 bars: an experimental investigation in a flow-through hydrothermal system  

E-Print Network [OSTI]

geothermometers and mixing for geothermal systems. Geothermi cs 5, 41-50. Foumier R. O. and Potter R. W. II (1982) An equation correlating the solubility of quartz in water from 25' to 900' C at pressures up to 10, 000 bars, Geochim. Cosrnochim. Acta 46, 1969...

Burns, Gregory Lee

2012-06-07T23:59:59.000Z

425

Quantitative evaluation of ammonium hydrosulfide reagent for precipitation of group II cations at 1.0 molar hydrogen ion concentration and for separation of group II and group III cations  

E-Print Network [OSTI]

UapARY IL R M COLLEGE QF 'NXAS QUkPgXgATXVQ KVMUA~~XOR QP ~ZQEXgi, i SXBQGBQLPX9g ~+MB% VM PKB&PXMTXQB 0L' 6~'QGP XX QgpVXohs ki , ? ? X~9- ~@ -BX386GM XQ'N OG@QRSPMgXM 489- PQB 8EP~ZXON OP 93GUP XX AN@. QBOQP XXX gAPX~ Subeitte@ to the Gza...'Sf'@&" nial, ". '; . - ' ~, . 'i '-' Ga4%e5. '884'cjoy'e7:g'i '' Gepppg +~eexL$4;, Cvg'egg. , Qat 9:e@-. 't~eg j~tyli6y'. : a4 '%~5'8': Bj ~jjen, " '. , fleXL . Qp@C'83@XagXCXk+ 4 'h. 0' 5 s. I' i. . ; 4;-I '+. 4. ', '+, h, , . . . ' g4 , V, : ' '. Preen...

Ramsey, Jerry Warren

1958-01-01T23:59:59.000Z

426

Long-term land cover dynamics by multi-temporal classi cation across the Landsat-5 record  

E-Print Network [OSTI]

to a spatio-temporally distributed reference sam- ple and applied the model to 55 Landsat-5 images covering-term series of Landsat images will provide increasingly robust, reliable records for a growing scienti c user Elsevier Inc. All rights reserved. 1. Introduction The Landsat satellites have imaged Earth's terrestrial

Song, Conghe

427

Classi cation of invariant solutions of the full Boltzmann Yu.N.Grigoryev y , S.V.Meleshko z  

E-Print Network [OSTI]

known BKW{solution of the spatially homogeneous Boltzmann equation was found by this way. The approach

Meleshko, Sergey V.

428

Determinative Role of Exchange Cation and Charge Density of Smectites on their Adsorption Capacity and Affinity for Aflatoxin B1  

E-Print Network [OSTI]

Bentonite clays have long been used as additives in animal feed, aiming to improve pellet quality and prevent caking. Certain bentonites are also capable of deactivating aflatoxin B_(1) (AfB_(1)) in feed by adsorption, therefore, detoxifying...

Liu, Lian

2013-08-14T23:59:59.000Z

429

Mixed cation phases in sputter deposited HfO{sub 2}-TiO{sub 2} nanolaminates  

SciTech Connect (OSTI)

Nanolaminate HfO{sub 2}-TiO{sub 2} films are grown by reactive sputter deposition on unheated fused SiO{sub 2}, sequentially annealed at 573 to 973 K, and studied by x-ray diffraction. A nanocrystalline structure of orthorhombic (o) HfTiO{sub 4} adjacent to an interface followed by monoclinic (m) Hf{sub 1-x}Ti{sub x}O{sub 2} is identified. m-Hf{sub 1-x}Ti{sub x}O{sub 2}, a metastable phase, is isomorphous with m-HfO{sub 2} and a high pressure phase, m-HfTiO{sub 4}. A Vegard's law analysis shows that the Ti atomic fraction in m-Hf{sub 1-x}Ti{sub x}O{sub 2} is much greater than Ti equilibrium solubility in m-HfO{sub 2}. A space group-subgroup argument proposes that m-Hf{sub 1-x}Ti{sub x}O{sub 2} arises from an o/m-HfTiO{sub 4} second order phase transition to accommodate the larger Hf atom.

Cisneros-Morales, M. C.; Aita, C. R. [Advanced Coatings Experimental Laboratory, College of Engineering and Applied Science, University of Wisconsin-Milwaukee, P.O. Box 784, Milwaukee, Wisconsin 53201 (United States)

2008-07-14T23:59:59.000Z

430

Identification and Characterization of Vnx1p, a Novel Type of Vacuolar Monovalent Cation/H Antiporter of  

E-Print Network [OSTI]

Leterrier , Mark Yeager§ , and Eduardo Blumwald1 From the Department of Plant Sciences, University on the electrochemical potential gradient of H generated by the action of the V-type H -ATPase. The presence of Vnx1p of sodium ions (Km 16 mM) by using the electrochemical proton gradient generated by the V-type H -ATPase

Blumwald, Eduardo

431

A Novel, Modification-Dependent ATP-Binding Aptamer Selected from an RNA Library Incorporating a Cationic Functionality  

E-Print Network [OSTI]

A Novel, Modification-Dependent ATP-Binding Aptamer Selected from an RNA Library Incorporating this library yielded a novel receptor that binds ATP under physiological pH and salt conditions in a manner structure model for the ATP binding site were obtained by the analysis of functional sequences selected from

Heller, Eric

432

MacroCapTM SP is a cation exchanger designed for the purification of large biomolecules such as polyethylene  

E-Print Network [OSTI]

such as polyethylene glycol (PEG)-modified proteins (i.e., PEGylated proteins) that are intended for use

Lebendiker, Mario

433

Revisiting the localization of Zn2+ cations sorbed on pathological apatite calcifications made through X-ray absorption spectroscopy  

E-Print Network [OSTI]

bones Accepted in Osteoporosis International F. E. Sowrey,to characterise bones Osteoporosis International, in press.such as arthrosis or osteoporosis [3]. Of note, among the

Bazin, D.

2010-01-01T23:59:59.000Z

434

Double Layer Formation and Cation Pseudo-Intercalation Supercapacitor Carbon Nanotube Composite Electrodes With Enhanced Electrochemical Performances.  

E-Print Network [OSTI]

??Among electrochemical energy storage solutions, redox-free supercapacitors exhibit the highest power densities and best cycle life, easily reaching over one million cycles. Despite these attributes,… (more)

Rangom, Yverick

2015-01-01T23:59:59.000Z

435

Morphological stability and metabolic activity of rice (Oryza sativa L.) protoplasts in media supplemented with polyamines and divalent cations  

E-Print Network [OSTI]

of variance for different chemicals on the effects of time, level and time x level interaction on mozphological stability 22 IV 14 C-Histidine uptake by protoplasts incubated under various treatment levels . . . . . . . . . . . . . . . 30 Result... tendency, Spermidine TABLE IV 14 C-Histidine uptake by protoplasts incubated under various treatment levels (cpm/100ul), Mean of 2 observations. Treatment Incubation Time (Hours) 12 18 24 Cadaverine lmM 10mM 20mM 47 50 44 299 709 545 1758...

Adhikary, Bharat Raj

1979-01-01T23:59:59.000Z

436

Extended Near-Infrared Resonance Raman Investigations of an Organic Mixed-Valence System: Diazatetracyclodiene Radical Cation  

E-Print Network [OSTI]

Extended Near-Infrared Resonance Raman Investigations of an Organic Mixed-Valence System near-infrared region show that six modes are coupled to the intramolecular charge-transfer transition transfer (IVCT) absorption bands in the red to near- infrared region of the spectrum, which are, at least

437

Water-Chemistry Evolution and Modeling of Radionuclide Sorption and Cation Exchange during Inundation of Frenchman Flat Playa  

SciTech Connect (OSTI)

Atmospheric tests and other experiments with nuclear materials were conducted on the Frenchman Flat playa at the Nevada National Security Site, Nye County, Nevada; residual radionuclides are known to exist in Frenchman Flat playa soils. Although the playa is typically dry, extended periods of winter precipitation or large single-event rainstorms can inundate the playa. When Frenchman Flat playa is inundated, residual radionuclides on the typically dry playa surface may become submerged, allowing water-soil interactions that could provide a mechanism for transport of radionuclides away from known areas of contamination. The potential for radionuclide transport by occasional inundation of the Frenchman Flat playa was examined using geographic information systems and satellite imagery to delineate the timing and areal extent of inundation; collecting water samples during inundation and analyzing them for chemical and isotopic content; characterizing suspended/precipitated materials and archived soil samples; modeling water-soil geochemical reactions; and modeling the mobility of select radionuclides under aqueous conditions. The physical transport of radionuclides by water was not evaluated in this study. Frenchman Flat playa was inundated with precipitation during two consecutive winters in 2009-2010 and 2010-2011. Inundation allowed for collection of multiple water samples through time as the areal extent of inundation changed and ultimately receded. During these two winters, precipitation records from a weather station in Frenchman Flat (Well 5b) provided information that was used in combination with geographic information systems, Landsat imagery, and image processing techniques to identify and quantify the areal extent of inundation. After inundation, water on the playa disappeared quickly, for example, between January 25, 2011 and February 10, 2011, a period of 16 days, 92 percent of the areal extent of inundation receded (2,062,800 m2). Water sampling provided valuable information about chemical processes occurring during inundation as the water disappeared. Important observations from water-chemistry analyses included: 1) total dissolved solids (TDS) and chloride ion (Cl-) concentrations were very low (TDS: < 200 mg/L and Cl-: < 3.0 mg/L, respectively) for all water samples regardless of time or areal extent; 2) all dissolved constituents were at concentrations well below what might be expected for evaporating shallow surface waters on a playa, even when 98 to 99 percent of the water had disappeared; 3) the amount of evaporation for the last water samples collected at the end of inundation, estimated with the stable isotopic ratios ?2H or ?18O, was approximately 60 percent; and 4) water samples analyzed by gamma spectroscopy did not show any man-made radioactivity; however, the short scanning time (24 hours) and relative chemical diluteness of the water samples (TDS ranged between 39 and 190 mg/L) may have contributed to none being detected. Additionally, any low-energy beta emitting radionuclides would not have been detected by gamma spectroscopy. From these observations, it was apparent that a significant portion of water on the playa did not evaporate, but rather infiltrated into the subsurface (approximately 40 percent). Consistent with this water chemistry-based conclusion is particle-size analysis of two archived Frenchman Flat playa soils samples, which showed low clay content in the near surface soil that also suggested infiltration. Infiltration of water from the playa during inundation into the subsurface does not necessarily imply that groundwater recharge is occurring, but it does provide a mechanism for moving residual radionuclides downward into the subsurface of Frenchman Flat playa. Water-mineral geochemical reactions were modeled so that changes in the water chemistry could be identified and the extent of reactions quantified. Geochemical modeling showed that evaporation; equilibrium with atmospheric carbon dioxide and calcite; dissolution of sodium chloride, gypsum, and composite volcanic g

Hershey, Ronald; Cablk, Mary; LeFebre, Karen; Fenstermaker, Lynn; Decker, David

2013-08-01T23:59:59.000Z

438

Cation Influx in Single Ovarian (Granulosa) Cells: Recruitment as a Cellular Mechanism of LH-[Ca 2 ? ] i Dose Response*  

E-Print Network [OSTI]

The gonadotropic hormones, LH and FSH, activate adenylyl cyclase in their respective target cells and thereby initiate many biochemical responses. In addition to stimulating cAMP production, both LH and FSH promote agonist-specific increases in the cytoplasmic concentration of free calcium ions ([Ca 2 ? ] i) in gonadal cells. Here, we have applied single cell fluorescence video microscopy with the Ca 2 ?-sensitive dye fura-2 to investigate the mechanism(s) by which LH induces a rise in the [Ca 2 ? ] i in individual (swine) granulosa cells collected from single Graafian follicles. Stimulation with LH induced a rapid onset, biphasic, spike- and plateau-like [Ca 2 ? ] i signal in responsive granulosa cells. The cellular mechanisms mediating this biphasic LH-stimulated increase in [Ca 2 ? ] i were examined by external Ca 2 ? removal and via the manganese (Mn 2 ? ) quench technique, which showed that LH triggers initial intracellular Ca 2 ? mobilization

Jorge A. Flores; Claudia Aguirre; Om P. Sharma; Johannes D. Veldhuis

439

The interrelations of mineral colloids and sodium chloride as measured by pH, conductivity, and water-soluble cations  

E-Print Network [OSTI]

?nos material, then any endothermic or exothermic re- action vill appear on the dehydratfon curve shoving the temperature differences as a function of the tenperature of the reference notarial. Page (43)x and Eendricks and Alexander {19) described equipnent... (exothermic) and a deflection in the opposite direction is noted on the gslvancmeter. Ths deflection on the galvancseter is proportional to e. m. f. created which is dependent upce the amount of heat abaca'bed or liberated in the sample being idcntif ied...

Crozier, Baalis B

1952-01-01T23:59:59.000Z

440

Dependence of Electronic Structure of SrRuO3 and the Degree of Correlation on Cation Off-Stoichiometry  

SciTech Connect (OSTI)

We have grown and studied high quality SrRuO{sub 3} films grown by MBE as well as PLD. By changing the oxygen activity during deposition we were able to make SrRuO{sub 3} samples that were stoichiometric (low oxygen activity) or with ruthenium vacancies (high oxygen activity). Samples with strontium vacancies were found impossible to produce since the ruthenium would precipitate out as RuO{sub 2}. The volume of the unit cell of SrRuO{sub 3} becomes larger as more ruthenium vacancies are introduced. The residual resistivity ratio (RRR) and room temperature resistivity were found to systematically depend on the volume of the unit cell and therefore on the amount of ruthenium vacancies. The RRR varied from {approx}30 for stoichiometric samples to less than two for samples that were very ruthenium poor. The room temperature resistivity varied from 190 {micro}{Omega} cm for stoichoimetric samples to over 300 {micro}{Omega} cm for very ruthenium poor samples. UPS spectra show a shift of weight from the coherent peak to the incoherent peak around the Fermi level when samples have more ruthenium vacancies. Core level XPS spectra of the ruthenium 3d lines show a strong screened part in the case of stoichiometric samples. This screened part disappears when ruthenium vacancies are introduced. Both the UPS and the XPS results are consistent with the view that correlation increases as the amount of ruthenium vacancies increase.

Siemons, W.

2011-08-19T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

AMENDMENT OF SOLlClTATlONlMODlFlCATION OF CONTRACT 1 I . CONTR"CT ID CODE  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNational NuclearhasAdministration77 Sandia National005-2010 or 1l PAGEMI54 I(

442

H2O and Cation Structure and Dynamics in Expandable Clays: 2H and 39K NMR  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky LearningGetGraphene'sEMSLonly)EnergyP.Oc t o b

443

AMENDMENT OF SOLIr ATI ON/MODIFI CATION OF CONTRACT 1. CONTRACT ID CODE PAGE OF PAGES  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011Astudies smartHistory:CONTR.l\CT 2.152.CNRCSOLIr

444

Search for variation of fundamental constants: Strong enhancements in $X^2\\Pi$ cations of dihalogens and hydrogen halides  

E-Print Network [OSTI]

We propose to use diatomic molecular ions to search for strongly enhanced effects of variation of fundamental constants. The relative enhancement occurs in transitions between nearly degenerate levels of different nature. Since the trapping techniques for molecular ions have already been developed, the molecules HBr$^+$, HI$^+$, Br$^+_2$, I$^+_2$, IBr$^+$, ICl$^+$, and IF$^+$ are very promising candidates for such future studies.

Pasteka, L F; Flambaum, V V; Schwerdtfeger, P

2015-01-01T23:59:59.000Z

445

A Four-Coordinate Fe(III) Porphyrin Cation Ming Fang, Scott R. Wilson, and Kenneth S. Suslick*  

E-Print Network [OSTI]

porphyrin5 (5,10,15,20-tetrakis(2,6-dihydroxyphenyl)porphyrin with triisopropyl chlorosilane using imidazole synthesis of the pure complexes, which show very different chemical shifts and have different spin states

Suslick, Kenneth S.

446

Geradora de Energia Eletrica Alegrete GEEA | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -InformationGeothermometry

447

Gering, Nebraska: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -InformationGeothermometryNebraska:

448

Thermal extraction analysis of five Los Azufres production wells  

SciTech Connect (OSTI)

Thermal energy extraction from five wells supplying 5-MWe wellhead generators in three zones of the Los Azufres geothermal field has been examined from production and chemical data compiled over 14-years of operation. The data, as annual means, are useful in observing small-scale changes in reservoir performance with continuous production. The chemical components are chloride for quality control and the geothermometer elements for reservoir temperatures. The flowrate and fluid enthalpy data are used to calculate the thermal extraction rates. Integration of these data provides an estimate of the total energy extracted from the zone surrounding the well. The combined production and chemical geothermometer data are used to model the produced fluid as coming from just-penetrating wells for which the annual produced mass originates from a series of concentric hemispheric shells moving out into the reservoir. Estimates are made of the drawdown distance into the reservoir and the far-field conditions.

Kruger, Paul; Quijano, Luis

1995-01-26T23:59:59.000Z

449

Low-temperature geothermal assessment of the Santa Clara and Virgin River Valleys, Washington County, Utah  

SciTech Connect (OSTI)

Exploration techniques included the following: (1) a temperature survey of springs, (2) chemical analyses and calculated geothermometer temperatures of water samples collected from selected springs and wells, (3) chemical analyses and calculated geothermometer temperatures of spring and well water samples in the literature, (4) thermal gradients measured in accessible wells, and (5) geology. The highest water temperature recorded in the St. George basin is 42/sup 0/C at Pah Tempe Hot Springs. Additional spring temperatures higher than 20/sup 0/C are at Veyo Hot Spring, Washington hot pot, and Green Spring. The warmest well water in the study area is 40/sup 0/C in Middleton Wash. Additional warm well water (higher than 24.5/sup 0/C) is present north of St. George, north of Washington, southeast of St. George, and in Dameron Valley. The majority of the Na-K-Ca calculated reservoir temperatures range between 30/sup 0/ and 50/sup 0/C. Anomalous geothermometer temperatures were calculated for water from Pah Tempe and a number of locations in St. George and vicinity. In addition to the known thermal areas of Pah Tempe and Veyo Hot Spring, an area north of Washington and St. George is delineated in this study to have possible low-temperature geothermal potential.

Budding, K.E.; Sommer, S.N.

1986-01-01T23:59:59.000Z

450

E-Print Network 3.0 - alkaline earth lithium Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the cation (alkaline, rare earth... to the cation size. Knowing that the size of rare earth elements and alkaline cations decreases in the following... of results on tungstate...

451

Computer Modeling Illuminates Degradation Pathways of  

E-Print Network [OSTI]

Computer Modeling Illuminates Degradation Pathways of Cations in Alkaline Membrane Fuel Cells Cation degradation insights obtained by computational modeling could result in better performance are effective in increasing cation stability. With the help of computational modeling, more cations are being

452

Dr. Ing. /PhD / Dr.techn. Students supervised by Signe Kjelstrup 1. Torleif Holt, Transport and equilibrium properties of a cation exchange membrane (1983)  

E-Print Network [OSTI]

, (1996) 6. Magnar Ottøy, Mass and heat transfer in ion-exchange membranes (1996) 7. Belinda Flem, Peltier in the Polymer Electrolyte Membrane Fuel Cell (2007) 17. Isabella Inzoli, Coupled transports of heat and massDr. Ing. /PhD / Dr.techn. Students supervised by Signe Kjelstrup 1. Torleif Holt, Transport

Kjelstrup, Signe

453

Pt/[Fe]ZSM-5 modified by Na and Cs cations: an active and selective catalyst for dehydrogenation of n-alkanes to n-alkenes  

E-Print Network [OSTI]

-flow hydro- dynamics. Samples (0.1 g, 180­250 mm diameter pellets) were treated in 40% H2 (Praxair, 99.999%, 0.20 cm3 s21 ) in He (Praxair, 99.999%, 0.30 cm3 s21 ) at 673 K for 2 h. Reactant and product

Iglesia, Enrique

454

60 CommuniCations oF the aCm | APRIL 2011 | vOL. 54 | nO. 4 contributed articles  

E-Print Network [OSTI]

, we can use procedural techniques and/or energy optimization to build automated visualization. Such visualizations help analysts quickly find patterns lurking within large data sets and help audiences quickly understand complex ideas. Over the past two decades a number of books10,15,18,23 have collected examples

O'Brien, James F.

455

Automatic Classi cation of Subdwarf Spectra using a Neural Network C. Winter 1 , C.S. Je ery 1 and J.S. Drilling 2  

E-Print Network [OSTI]

1 and J.S. Drilling 2 1 Armagh Observatory, College Hill, Armagh BT61 9DG, N. Ireland 2 Dept@arm.ac.uk, drilling@rouge.phys.lsu.edu Abstract We apply a multilayer feed-forward back propagation arti#12;cial neural network to a sample of 380 subdwarf spectra classi#12;ed by Drilling et al. (2002), showing

Jeffery, Simon

456

Syntheses and characterization of energetic compounds constructed from alkaline earth metal cations (Sr and Ba) and 1,2-bis(tetrazol-5-yl)ethane  

SciTech Connect (OSTI)

Two new energetic compounds, [M(BTE)(H{sub 2}O){sub 5}]{sub n} (M=Sr(1), Ba(2)) [H{sub 2}BTE=1,2-bis(tetrazol-5-yl)ethane], have been hydrothermally synthesized and structurally characterized. Single-crystal X-ray diffraction analyses reveal that they are isomorphous and exhibit 2D (4,4) net framework, generated by 4-connected Sr{sub 2}(H{sub 2}O){sub 10}/Ba{sub 2}(H{sub 2}O){sub 10} SBUs linked up by two independent binding modes of H{sub 2}BTE, and the resulting 2D structure is interconnected by hydrogen-bond and strong face to face {pi}-{pi} stacking interactions between two tetrazole rings to lead to a 3D supramolecular architecture. DSC measurements show that they have significant catalytic effects on thermal decomposition of ammonium perchlorate. Moreover, the photoluminescence properties, thermogravimetric analyses, and flame colors of the as-prepared compounds are also investigated in this paper. - Graphical abstract: Two novel 2D isomorphous alkaline earth metal complexes were assembled by 4-connected Sr{sub 2}(H{sub 2}O){sub 10}/Ba{sub 2}(H{sub 2}O){sub 10} SBUs and two independent binding modes of H{sub 2}BTE ligands, and the catalytic performances toward thermal decomposition of ammonium perchlorate and photoluminescent properties of them were investigated. Highlights: > Two novel alkaline earth energetic coordination polymers have been prepared.{yields} Both structures are layered based on 4-connected Sr{sub 2}(H{sub 2}O){sub 10}/Ba{sub 2}(H{sub 2}O){sub 10} SBUs and two distinct H{sub 2}BTE coordination modes.{yields} The dehydrated products of the compounds possess good thermostability and significant catalytic effects on thermal decomposition of AP.

Xia Zhengqiang [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069 (China); Chen Sanping, E-mail: sanpingchen@126.com [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069 (China); Wei Qing, E-mail: weiqq@126.com [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069 (China); Qiao Chengfang [Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, Shaanxi 710069 (China)

2011-07-15T23:59:59.000Z

457

Neutral and Cationic Vanadium Bisimido Complexes: Their Synthesis, Characterization, and Application in the Binding, Activation, and Catalytic Functionalization of Small Molecules  

E-Print Network [OSTI]

point of comparison is the V(III) (PNP ipr )VTe(CNXyl)2 (PNP ipr = N(2-PiPr 2 -4- methylphenyl) 2 ), which possessof 2164 cm -1 , and (PNP ipr )VTe(CNXyl) 2 has stretching

La Pierre, Henry Storms

2011-01-01T23:59:59.000Z

458

Regional scale effects of base cation fertilization on Norway spruce and European beech stands situated on acid brown soils: soil and foliar chemistry  

E-Print Network [OSTI]

net N transformations in Norway spruce (Picea abies (L. )Vascular tissue anatomy of Norway spruce needles and twigsnutrient imbalances in Norway spruce, Ecol. Bull. 44 (

Misson, Laurent

2001-01-01T23:59:59.000Z

459

Electrochemistry and photocurrents of the tris(bipyridine)ruthenium(II) and methyl viologen cations immobilized in carrageenan hydrogel. [tris(2,2'-bipyridine)ruthenium(II)  

SciTech Connect (OSTI)

A procedure for immobilization of both a photochromophore, tris(2,2{prime}-bipyridine)ruthenium(II) (Ru(bpy){sub 3}{sup 2+}), and a quencher, methyl viologen (MV{sup 2+}), within a carrageenan hydrogel matrix at an electrode surface is described. Ru(bpy){sub 3}{sup 2+} and MV{sup 2+} exhibited diffusion coefficients that ranged from 10{sup {minus} 7} to 10{sup {minus} 6} cm{sup 2}/s in the hydrogel, which represents an improvement over other immobilization matrices. Photolysis of the resulting hydrogel surface modified electrodes gave rise to a significant photocurrent which depended on the concentrations of Ru(bpy){sub 3}{sup 2+}, MV{sup 2+}, and triethanolamine and resulted in a maximum value of 12 {mu}A/cm{sup 2} after the hydrogel was cured with a solution containing 5 mM Ru(bpy){sub 3}{sup 2+} and 50 mM MV{sup 2+}. The photocurrent was the result of reoxidation of MV{sup +} at the electrode surface following reduction of MV{sup 2+} by photoexcited Ru(bpy){sub 3}{sup 2+}. The quenching rate constant of Ru(bpy){sub 3}{sup 2+} by MV{sup 2+} in the hydrogel was 4.2 {times} 10{sup 8} M{sup {minus}1} s{sup {minus}1}. The photocurrent action spectrum was consistent with Ru(bpy){sub 3}{sup 2+} acting as the photochromophore. Offsetting the potential of the hydrogel electrode verified the role of the MV{sup 2+}/{sup +} redox couple as the source of the current.

Rillema, D.P.; Edwards, A.K. (Univ., of North Carolina, Charlotte (United States)); Perine, S.C.; Crumbliss, A.L. (Duke Univ., Durham, NC (United States))

1991-11-13T23:59:59.000Z

460

Synthesis of metal-metal oxide catalysts and electrocatalysts using a metal cation adsorption/reduction and adatom replacement by more noble ones  

DOE Patents [OSTI]

The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen. The invention also relates to methods of making the metal-metal oxide composites.

Adzic, Radoslav; Vukmirovic, Miomir; Sasaki, Kotaro

2010-04-27T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

JOURNAL DE PHYSIQUE Colloque C7, supplement au n 12, Tome 37, Decembre 1976, page C7-359 CATIONIC HEATS OF TRANSPORT AND VACANCY LIFETIMES  

E-Print Network [OSTI]

HEATS OF TRANSPORT AND VACANCY LIFETIMES IN SINGLE CRYSTALS OF SODIUM CHLORIDE AND POTASSIUM CHLORIDE A on resistance along with corresponding driving forces provides a means for estimation of vacancy lifetimes of this experimental work. Theory. -- In a material at equilibrium, vacancies are produced and annihilated at a rate

Paris-Sud XI, Université de

462

Pysico-chemical properties of hydrophobic ionic liquids containing 1-octylpyridinium, 1-octyl-2-methylpyridinium or 1-octyl-4-methylpyridinium cations  

E-Print Network [OSTI]

respectively, in acetonitrile at 70 °C. All syntheses werepurity), and 50 mL acetonitrile. After cooling to room98 % purity), and 25 mL acetonitrile. After cooling to room

Papaiconomou, Nicolas; Salminen, Justin; Lee, Jong-Min; Prausnitz, John M.

2006-01-01T23:59:59.000Z

463

Formation and Characterization of Acetonitrile N-Methylide [CH3CNCH2]+ and N-Methylketenimine [CH3NCCH2]+ Radical Cations in the Gas Phase  

E-Print Network [OSTI]

Formation and Characterization of Acetonitrile N-Methylide [CH3CNCH2]·+ and N-Methylketenimine [CH3 Palaiseau Cedex, France ReceiVed: July 24, 1997; In Final Form: NoVember 4, 1997 Acetonitrile N by ion-molecule reactions between ionized cyclobutanone or ionized ketene and acetonitrile or methyl

Nguyen, Minh Tho

464

Aqueous Transition Metal Cations as Impurities in a Wide Gap Oxide: The Cu^2+/Cu^1+ and Ag^2+/Ag^1+ Redox Couples Revisited  

E-Print Network [OSTI]

of 10ps. The longitudinal relaxation is more than a magnitude faster. Results and analysis Gas-phase Table 1 lists the calculated M-O bond lengths in the four gas-phase complexes we have investigated (see fig. 1). One can see that for the same number... containing a fraction of Hartree-Fock exchange. These calculations make use of recent progress in DFTMD technology enabling us to include sp core polarization and Hartree-Fock exchange in condensed phase model systems. Keywords Aqueous redox chemistry...

Liu, Xiandong; Cheng, Jun; Sprik, Michiel

2014-11-11T23:59:59.000Z

465

To appear in Proceedings, International Symposium on Requirements Engineering, York, England, March 26-27, 1995 1 Consistency Checking of SCR-Style Requirements Speci cations  

E-Print Network [OSTI]

; a submarine communications system 12 ; and safety- critical components of two nuclear power plants to describe the functional requirements of software un- ambiguously and concisely 13, 14 , the SCR method has of avionics and space applications 7, 8 . While the above applications of SCR rely on man- ual techniques, e

466

Formation of anions and cations via a binary-encounter process in OH$^+$ + Ar collisions: the role of dissociative excitation and statistical aspects  

E-Print Network [OSTI]

Molecular fragmentation leading to the formation of negatively and positively charged hydrogen ions in 7-keV OH$^+$ + Ar collisions is investigated experimentally. The most striking finding is that negative and positive hydrogen ions are emitted with very similar angular dependences. Also, the kinetic energy distribution of the H$^+$ fragment shows strong similarities with that of the ejected H$^-$ ion. The kinematics of the emitted H core is found to be essentially driven by its scattering on the atomic target. However, in addition to this binary-encounter process, dissociative electronic excitation of the molecular projectile has to be invoked to explain the observed fragmentation patterns. Though the electron capture process is complex, it is shown that the relative population of the different final charge states of the outgoing fragments can be described by simple statistical laws.

Lattouf, E; Chesnel, J -Y; Kovács, S T S; Bene, E; Herczku, P; Huber, B A; Méry, A; Poully, J -C; Rangama, J; Sulik, B

2015-01-01T23:59:59.000Z

467

Photodegradation of oligomeric polyesters containing anthraquinone and 1,2-diamine units. Single electron transfer induced cation radical bond cleavage in the solid state  

SciTech Connect (OSTI)

Oligomeric polyesters containing light-absorbing anthraquinone electron acceptor chromophores and fragmentable 1,2-diamine donors have been synthesized. Irradiation with [lambda] [ge] 340 nm in solution or as solid films results in photooxidative C-C bond cleavage of the 1,2-diamine units yielding essentially the same products in either case. The solid state photodegradation reaction was monitored using size exclusion chromatography and was found to be substantially less efficient than the corresponding solution reaction. This is attributed to an inefficient forward electron transfer step and the possibility of an induced reversibility of the fragmentation. The efficiency of photodegradation is suggested to be dependent on the donor/acceptor orientations in the solid state. 49 refs., 11 figs., 1 tab.

Leon, J.W.; Whitten, D.G. (Univ. of Rochester, NY (United States))

1995-03-01T23:59:59.000Z

468

Category:Lists for Companies | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,AreasFluidGeothermometry Jump

469

Category:Lists for Incentive Types | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,AreasFluidGeothermometry

470

Alaska Open-file Report 144 Assessment of Thermal Springs Sites Aleutian Arc, Atka Island to Becherof Lake -- Preliminary Results and Evaluation  

SciTech Connect (OSTI)

Twenty of more than 30 thermal spring areas reported to exist in the Aleutian arc extending from Atka Island to Becherof Lake were investigated during July and August, 1980. Thermal activity of three of these sites had diminished substantially or no longer existed. At least seven more sites where thermal-spring activity is probable or certain were not visited because of their remoteness or because of time constraints. The existence of several other reported thermal spring sites could not be verified; these sites are considered questionable. On the basis of geothermometry, subsurface reservoir temperatures in excess of 150 C are estimated for 10 of the thermal spring sites investigated. These sites all occur in or near regions of Recent volcanism. Five of the sites are characterized by fumaroles and steaming ground, indicating the presence of at least a shallow vapor-dominated zone. Two, the Makushin Valley and Glacier Valley thermal areas, occur on the flanks of active Mukushin Volcano located on Unalaska Island, and may be connected to a common source of heat. Gas geothermometry suggests that the reservoir feeding the Kliuchef thermal field, located on the flanks of Kliuchef volcano of northeast Atka Island, may be as high as 239 C.

Motyka, R.J.; Moorman, M.A.; Liss, S.A.

1981-12-01T23:59:59.000Z

471

Implications of thermal events on thrust emplacement sequence in the Appalachian fold and thrust belt: Some new vitrinite reflectance data  

SciTech Connect (OSTI)

Interpretation of existing geothermometry data combined with new vitrinite reflectance data, within the framework of a detailed composite tectonic setting, elucidates the evolution of structural sequencing of thrust sheets during the Alleghanian event in the Valley and Ridge Province in Virginia. That the Pulaski thrust sheet preceded the Saltville thrust sheet in the emplacement sequence, and that both reached thermal maxima prior to, or during, respective emplacement may be inferred from vitrinite and other geothermometry data. In contrast, the Narrows and St. Clair thrust sheets probably each attained their thermal maximum after emplacement. New vitrinite reflectance data are consistent with CAI and other temperature-sensitive information heretofore ascertained in the Valley and Ridge Province and support previously established maximum temperatures of ca. 200C for strata of the Saltville thrust sheet as young as Mississippian. R{sub max} values from Mississippian coals in the Price Formation of the Saltville sheet, beneath but near the Pulaski thrust, range from 1.61% to 2.60%. At the structural front of the fold and thrust belt, a single Mississippian coal sample from the Bluefield Formation yields an R{sub max} value of 1.35%. Those coals showing highest R{sub max} values are more intensely fractured with secondary minerals filling the fractures. Warm fluids introduced during tectonic events may have played at least as important a role as that of combined stratigraphic and tectonic burial.

Lewis, S.E.; Hower, J.C. (Montana Tech, Butte (USA))

1990-11-01T23:59:59.000Z

472

Pulsed discharge nozzle cavity ringdown spectroscopy of cold polycyclic aromatic hydrocarbon ions  

E-Print Network [OSTI]

absorption spectra of the naphthalene (C10H8 ) and acenaphthene (C12H10) cations have been measured cation along with the gas-phase vibronic absorption spectrum of the cold acenaphthene cation are reported

473

Microbial carbonates: the geological record of calcied bacterialalgal mats and biolms  

E-Print Network [OSTI]

and/or HCO3 ± by cyanobacteria, and ammoni®cation, denitri®cation and sulphate reduction by other

Riding, Robert

474

Ways of Knowing and Inclusive Management Practices  

E-Print Network [OSTI]

plant diversi? cation and composting. Certi? cation stance,farmers’ practice of composting, which the regulationsbuilding blocks, research composting processes, such as

Feldman, Martha S; Khademian, Anne M; Ingram, Helen; Schneider, Anne S

2006-01-01T23:59:59.000Z

475

Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. Abstract: Molecular simulation techniques...

476

E-Print Network 3.0 - alkaline earth chlorides Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of the alkaline earth cations, magnesium, calcium, and barium on the dissolution kinetics of quartz PATRICIAM... and alkaline earth cations in near-neutralpH solutions. We...

477

Forecasting Dangerous Inmate Misconduct: An Applications of Ensemble Statistical Procedures  

E-Print Network [OSTI]

of Ensemble Statistical Procedures ? Richard A. Berk Brianpopular classi?cation procedures do no better than theand employ classi?cation procedures that identify inmates

Richard A. Berk; Brian Kriegler; Jong-Ho Baek

2011-01-01T23:59:59.000Z

478

Debt financing and the dynamics of agency costs  

E-Print Network [OSTI]

III.B.3 Econometric Speci?cation . . . . . . . . . . III.Cand Cointegration,” Econometric Theory, 21(4), 795–837. Bvariable construction and econometric speci?cation. Section

Cao, Bolong

2006-01-01T23:59:59.000Z

479

E-Print Network 3.0 - alkaline earth transition Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various alkaline cations in order... to the cation size. Knowing that the size of rare earth elements and ... Source: Ecole Polytechnique, Centre de mathmatiques Collection:...

480

E-Print Network 3.0 - ammonium hydroxides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of catalyst with ionomer will be important 12;Mechanical Stability... ) Cation design R4N+ ???? 12;Families of cations Ammoniums Guanadiniums Sulfoniums ...

Note: This page contains sample records for the topic "geothermometry cation geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Influence of the Electron-Cation Interaction on Electron Mobility in Dye-Sensitized ZnO and TiO2 Nanocrystals: A Study Using Ultrafast Terahertz Spectroscopy  

E-Print Network [OSTI]

understood key processes in dye-sensitized solar cells. We have employed time-resolved spectroscopies by electrical techniques. The operation of a dye-sensitized solar cell relies on the efficient electron are not necessarily connected, and that charge transport in the sensitized solar cell material can differ from

KuÂ?el, Petr

482

Novel -Distonic Radical Cations [CnH2n+2S]+ (n ) 2, 3) Formed upon Decarbonylation of Ionized S-Alkyl Thioformates: A Mass Spectrometric and ab Initio Study  

E-Print Network [OSTI]

ions. Strong evidence for the distonic nature of the fragment ions derived from 2-7·+ has been obtained to intense peaks corresponding to H2S·+ and ionized olefins. Portions of the potential energy surface related explored in the gas phase by a variety of mass spectral methods.2,3 In particular, the -distonic isomer

Nguyen, Minh Tho

483

Optical amplification in disordered electrooptic Tm{sup 3+} and Ho{sup 3+} codoped lanthanum-modified lead zirconate titanate ceramics and study of spectroscopy and communication between cations  

SciTech Connect (OSTI)

Rare earth doped electro-optic (EO) ceramics of lanthanum-modified lead zirconate titanate (PLZT) are promising in building multifunctional optical devices, by taking advantage of both EO effect and optical activity. In this work, the combination of the measured spectra of absorption and photoluminescence, the fluorescent decay, the calculated Judd-Ofelt parameters, and measured single pass gain in Tm{sup 3+}, Ho{sup 3+} codoped PLZT ceramics have marked them out as promising gain media in building electrically controllable lasers/optical amplifiers and other multifunctional devices. Optical energy storage was also observed in the optical amplification dynamics.

Zhao, Hua; Zhang, Kun; Xu, Long; Sun, Fankui; Zhang, Jingwen, E-mail: jingwenz@gmail.com [Department of Physics, Harbin Institute of Technology, Harbin 150001 (China); Chen, Xuesheng [Department of Physics and Astronomy, Wheaton College, Norton Massachusetts 02766 (United States); Li, Kewen K. [Boston Applied Technologies, Inc., Woburn, Massachusetts 01801 (United States)

2014-02-21T23:59:59.000Z

484

Isomerization of Acetonitrile N-Methylide [CH3CNCH2]+ and N-Methylketenimine [CH3NCCH2]+ Radical Cations in the Gas Phase: Theoretical Study of the [C3,H5,N]+  

E-Print Network [OSTI]

Isomerization of Acetonitrile N-Methylide [CH3CNCH2]·+ and N-Methylketenimine [CH3NCCH2]·+ Radical(d,p) basis set show that acetonitrile N-methylide [CH3CNCH2]·+, a·+, and N-methylketenimine [CH3NCCH2]·+, b with acetonitrile and methyl isocyanide to generate acetonitrile N-methylide [CH3-CtN-CH2]·+, a·+, and N

Nguyen, Minh Tho

485

Courses: Education: Special Education (EDSP) Page 305Sonoma State University 2014-2015 Catalog edSp 422 CoLLABorAtiVe pArtnerSHipS And SpeCiAL eduCAtion (4)  

E-Print Network [OSTI]

Credential Program or permission of the instructor. edSp 422A CASe MAnAgeMent And trAnSition pLAnning in Spe and collaboration skills necessary for effective case management and transition planning for individuals case management and transition planning for individuals with exceptional needs. Emphasis is placed

Ravikumar, B.

486

Investigations of low-temperature geothermal potential in New York State  

SciTech Connect (OSTI)

Temperature gradient map and published heat flow data indicate a possible potential for a geothermal resource in western and central New York State. A new analysis of bottom-hole temperature data for New York State confirms the existence of three positive gradient anomalies: the East Aurora, Cayuga, and Elmira anomalies, with gradients as high as 32/sup 0/C/km, 36/sup 0/C/km, and 36/sup 0/C/km, respectively. Ground waters from two of these anomalies are enriched in silica relative to surrounding areas. Heat flows based on silica geothermometry are 50 to 70 mWm/sup -2/ for the anomalies and 41.4 mWm/sup -2/ for bordering regional flux. A correlation between Bouguer gravity anomalies and the temperature gradient map suggests that the geothermal anomalies may occur above radioactive granites in the basement.

Hodge, D.S.; De Rito, R.; Hifiker, K.; Morgan, P.; Swanberg, C.A.

1981-09-01T23:59:59.000Z

487

ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT 1979  

E-Print Network [OSTI]

photovoltaic appli- cations and their unique properties as amorphous materials. The amorphous silicon hydrogen

Cairns, E.J.

2010-01-01T23:59:59.000Z

488

Effects of Temporal Wind Patterns on the Value of Wind-Generated Electricity in California and the Northwest  

E-Print Network [OSTI]

Laboratory, private communi- cation, March 12, 2004. WECC, "WECC 2006 Power Supply Assessment," Western Electricity

Wiser, Ryan H

2008-01-01T23:59:59.000Z

489

Transport Equations for Semiconductors Prof. Dr. Ansgar Jungel  

E-Print Network [OSTI]

- cations have been invented; for instance, semiconductor lasers, solar cells, light-emitting diodes (LED

Jüngel, Ansgar

490

Assessment of Potential Aquatic Herbicide Impacts to California Aquatic Ecosystems  

E-Print Network [OSTI]

association with herbicide appli- cations. Applications of acrolein, copper sulfate, chelated copper, diquat

491

Journal of Catalysis 182, 117128 (1999) Article ID jcat.1998.2312, available online at http://www.idealibrary.com on  

E-Print Network [OSTI]

dehydrogenation and naphthene dehydrogenation steps occur on the Ga cations. They suggested that all other

Iglesia, Enrique

492

An evaluation of the geothermal potential of the Tecuamburro Volcano area of Guatemala  

SciTech Connect (OSTI)

Radiometric ages indicate that the Tecuamburro Volcano and three adjacent lava domes grew during the last 38,300 years, and that a 360-m-wide phreatic crater, Laguna Ixpaco, was formed near the base of these domes about 2900 years ago. Laguna Ixpaco is located within the Chupadero crater, from which pyroxene pumice deposits were erupted 38,300 years ago. Thus, the likelihood is great for a partly molten or solid-but-still-hot near-surface intrusion beneath the area. Fumaroles and hot springs issue locally from the Tecuamburro volcanic complex and near Laguna Ixpaco. Analyses of gas and fluid samples from these and other nearby thermal manifestations yield chemical-geothermometer temperatures of about 150{degree} to 300{degree}C, with the highest temperatures at Ixpaco. The existence of a commercial-grade geothermal reservoir beneath the Ixpaco area seems likely. 84 refs., 70 figs., 12 tabs.

Heiken, G.; Duffield, W. (eds.)

1990-09-01T23:59:59.000Z

493

Anisotropic Structure and Transport in Self-Assembled Layered Polymer-Clay Nanocomposites  

E-Print Network [OSTI]

and electrostatic interactions. The films were characterized using ellipsometry, profilometry, X-ray photon associates with alkali cations through ion-dipole interactions, and cation mobility is influenced by local montmorillonite alone. Adding a lithium saltsuchaslithiumperchloratecanimprovetheroom-temperature conductivity

Sadoway, Donald Robert

494

X-ray Absorption Spectroscopy of Biologically Relevant Systems  

E-Print Network [OSTI]

of the interaction of the carboxylate with lithium; this isinteractions of carboxylate with the monovalent cations lithium,lithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

Uejio, Janel Sunayo

2010-01-01T23:59:59.000Z

495

Metal interactions and activities of truncated and extended hammerhead ribozyme constructs  

E-Print Network [OSTI]

The hammerhead ribozyme (HHRz) catalyzes a site-specific phosphodiester bond cleavage reaction that is enhanced by the presence of metal cations. Metal cations are thought to aid in the folding and possibly the catalytic mechanism of this ribozyme...

Osborne, Edith Marie

2007-04-25T23:59:59.000Z

496

Cutting tools and wear resistant articles and material for same  

DOE Patents [OSTI]

A ceramic having a relatively high proportion of an alpha prime SiAlON phase and exhibiting high hardness and toughness. In a particularly preferred embodiment, a cation of Gd is used as a modifying cation.

Tien, Tseng-Ying (Ann Arbor, MI); Huang, Zhen-Kun (Ann Arbor, MI)

2000-01-01T23:59:59.000Z

497

The economics of real estate brokerage and contracts  

E-Print Network [OSTI]

from data limitaions and econometric speci?cation errors ofData limitations and econometric speci?cation issues inHsieh and Moretti’s econometric model su?ers from severe

Wignall, Christopher David

2009-01-01T23:59:59.000Z

498

Metal-phosphate binders  

DOE Patents [OSTI]

A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

2009-05-12T23:59:59.000Z

499

The role of biomass in California's hydrogen economy  

E-Print Network [OSTI]

technologies, gasi?cation and biogas reforming. Gasi?cation55% conversion ef?ciency. Biogas, a methane-rich gas, can beanaerobic digestion. Biogas, land?ll gas, and wastewater

Parker, Nathan C; Ogden, Joan; Fan, Yueyue

2009-01-01T23:59:59.000Z

500

DOI: 10.1002/chem.201303086 Comparison of Gas Sorption Properties of Neutral and Anionic Metal  

E-Print Network [OSTI]

of the stronger interaction of the gas molecules with the anionic framework and the ammoni- um cations included

Paik Suh, Myunghyun